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Sample records for thermal absorption cross

  1. Effective thermal neutron absorption cross section for heterogeneous mixture

    International Nuclear Information System (INIS)

    Gabanska, B.; Igielski, A.; Krynicka-Drozdowicz, E.; Woznicka, U.

    1989-01-01

    The first estimations (basing on Umiastowski's theory) of the influence of the sample heterogeneity of the effective thermal neutron absorption cross section were compared with the results obtained for the homogeneous mixture which components and concentration were the same as those of the heterogeneous sample. An experiment was prepared to determine how good this estimate is. Three artificial heterogeneous cylindrical samples (2R = H = 9 cm) were manufactured from pure silver cylinders embedded in plexiglass, keeping the Ag content and varying the size of cylinders (2R = H = 1.0 cm, 0.6 cm and 0.4 cm). Calculations performed show that the experimental effect of the sample heterogeneity can be significant. 5 figs., 5 tabs, 11 refs. (author)

  2. The poisoning of samples by elements with high thermal neutron absorption cross section

    International Nuclear Information System (INIS)

    Tran Dai Nghiep; Nguyen Duc Kien; Tran Van Vuong; Nguyen Thanh Hung

    1990-01-01

    The macroscopic thermal neutron absorption cross section for small samples was calculated in framework of diffusion theory and poisoning technique. The theoretical formulae agree with the experimental data. (author). 6 refs., 3 figs

  3. The concept of measurement of thermal neutron absorption cross section in small samples

    International Nuclear Information System (INIS)

    Czubek, J.A.

    1980-01-01

    Theoretical principles of the method of measurement of the absorption cross section for thermal neutrons are presented in the one velocity approach. In consecutive measurements the sample investigated is enveloped in shells of a known moderator of varying thickness and irradiated with the pulsed beam of fast neutrons. The die-away rate of thermal neutrons escaping from such a system is measured. The absorption cross section of the unknown sample is found as the intersection of the experimental curve (die-away rate viz. thickness of the moderator) with the theoretical one calculated for the case of the zero value of the material buckling of the sample. (author)

  4. Measurement of the thorium absorption cross section shape near thermal energy (LWBR development program)

    International Nuclear Information System (INIS)

    Green, L.

    1976-11-01

    The shape of the thorium absorption cross section near thermal energies was investigated. This shape is dominated by one or more negative energy resonances whose parameters are not directly known, but must be inferred from higher energy data. Since the integral quantity most conveniently describing the thermal cross section shape is the Westcottg-factor, effort was directed toward establishing this quantity to high precision. Three nearly independent g-factor estimates were obtained from measurements on a variety of foils in three different neutron spectra provided by polyethylene-moderated neutrons from a 252 Cf source and from irradiations in the National Bureau of Standards ''Standard Thermal Neutron Density.'' The weighted average of the three measurements was 0.993 +- 0.004. This is in good agreement with two recent evaluations and supports the adequacy of the current cross section descriptions

  5. The correlations between natural elements (K, U, Th) concentrations and thermal neutron absorption cross-section value (Σa) for rock samples of Carpatia area

    International Nuclear Information System (INIS)

    Swakon, J.; Cywicka-Jakiel, T.; Drozdowicz, E.; Gabanska, B.; Loskiewicz, J.; Woznicka, U.

    1991-01-01

    The paper presents a study of correlations between concentrations of potassium, uranium and thorium and thermal neutron absorption cross section in rock samples. This knowledge of correlation should help in recognizing the expansion ways and accumulation places of the elements responsible of high thermal neutron absorption cross section in some geological environments. The correlations show the existence of connections between the thermal neutron absorption cross section value and natural radioactivity elements concentration in rocks. The results confirm the existence of correlations between natural radioactive elements concentrations (particularly thorium) and thermal neutron absorption cross - section value in some rocks. (author). 12 refs, 23 figs, 6 tabs

  6. Pile oscillator measurements of thermal absorption cross sections of Al, Mg, Fe and Cu

    International Nuclear Information System (INIS)

    Carre, J.C.; Vidal, R.

    1964-01-01

    The phase oscillation technique used at ZOE has the property of reducing of a marked factor the effect of neutron scattering by the sample. The absorption cross sections of poorly absorbing and highly scattering materials have been measured; for neutrons of 2,200 m/s, the following values are obtained: 229 ± 3 mb for Al; 64.2 ± 1.5 mb for Mg, 2.53 ± 0.03 b for Fe and 3.74 ± 0.04 b for Cu. (authors) [fr

  7. Determination of the thermal neutron absorption cross section for rock samples by a single measurement of the time decay constant

    International Nuclear Information System (INIS)

    Krynicka, E.

    1993-01-01

    A calibration method for the determination of the thermal neutron macroscopic mass absorption cross section for rock samples is presented. The standard deviation of the final results is discussed in detail. A big advantage of the presented method is that the calibration curves have been found using the results obtained for a variety of natural rock samples of different stratigraphies and lithologies measured by Czubek's methods. An important part of the paper is a through analysis of the standard deviation of the final result. (author). 13 refs, 11 figs, 5 tabs

  8. Xenon poisoning method for the determination of the average thermal neutron flux, macroscopic fission and total absorption cross sections

    International Nuclear Information System (INIS)

    Durmayaz, A.; Sisman, A.; Cetin Sisman, F.; Yavuz, H.

    1997-01-01

    The paper presents the xenon poisoning method as an experimental way to determine the average thermal neutron flux (anti φ), the average macroscopic fission cross section (anti Σ f ) and the average total macroscopic absorption cross section (anti Σ a ) together with the reactivity change due to the 135 Xe poisoning. The predictions for the reactivity change due to the 135 Xe poisoning are in good agreement with the results of the experiments. The results of anti φ, anti Σ f and anti Σ a obtained by using the xenon poisoning method are also in satisfactorily agreement with the predictions of TRIGAP and WIMS-D/4 computer codes. The temperature coefficients of the reactivity for the fuel and tank water have also been determined experimentally during this study. (orig.) [de

  9. Thermal neutron absorption cross-section measured on rock samples and brines in the Institute of Nuclear Physics

    International Nuclear Information System (INIS)

    Czubek, J.A.; Drozdowicz, K.; Krynicka-Drozdowicz, E.; Igielski, A.; Woznicka, U.

    1983-01-01

    In consecutive measurements the rock sample (having a fixed and well known shape -in our case it is a sphere or a cylinder and the sample is powdered or liquid) is enveloped in shells of a plexiglass moderator (the neutron parameters of which are known) of variable thickness and irradiated with the pulsed beam of fast neutrons. The die-away rate of thermal neutrons escaping from the whole system is measured. The absorption cross-section of the sample is found as the intersection of the experimental curve (i.e. die -away rate vs thickness of the moderator) with the theoretical one. The theoretical curve is calculated for a given moderator under the assumption of a constant value of the neutron flux inside the sample. This method is independent of the value of the transport cross-section of the sample. It has been checked on artificial materials with a well known elemental composition (liquid or solid) and on the natural brines and rock samples (basalts and dolomite). A special method of calculation of the variance of the measurement has been established. It is based on the multiple computer simulations of all experimental data used in the computation. The one standard deviation of our methods is of the order of 1 up to 3 capture units (1 c.u. = 10 -3 cm -1 ). The volume of the sample needed is of the order of 500ccm. (author)

  10. Thermal neutron absorption borehole logging

    International Nuclear Information System (INIS)

    Flaum, C.

    1982-01-01

    A method is described of quantitatively determining the macroscopic thermal neutron cross-section of a geological formation traversed by a borehole by measuring the flux of both thermal and epithermal neutrons following the irradiation of the formation with neutrons from a continuous source in a neutron sonde. (U.K.)

  11. Accuracy of the thermal neutron absorption cross section measurements (based on examples of selected pulsed beam methods); Dokladnosc pomiarow przekroju czynnego absorpcji neutronow termicznych (na przykladzie wybranych metod impulsowych)

    Energy Technology Data Exchange (ETDEWEB)

    Krynicka, E. [The H. Niewodniczanski Inst. of Nuclear Physics, Cracow (Poland)

    1997-12-31

    The problem of accuracy of the thermal neutron macroscopic absorption cross section determination is discussed on examples of selected measurement methods which use non-stationary neutron fields. The computer simulation method elaborated by the author is presented as a procedure for estimating the standard deviation of the measured absorption cross section. The computer simulation method presented can be easily utilized to estimate the accuracy of measurement of various physical magnitudes. (author) 46 refs, 3 figs, 1 tab

  12. The Absorption Refrigerator as a Thermal Transformer

    Science.gov (United States)

    Herrmann, F.

    2009-01-01

    The absorption refrigerator can be considered a thermal transformer, that is, a device that is analogous to the electric transformer. The analogy is based on the correspondence between the extensive quantities, entropy and electric charge and the intensive variables, temperature and electric potential. (Contains 1 footnote and 6 figures.)

  13. Determination of the stimulated emission cross section of neodymium glasses by measurement of the absorption from the thermally populated /sup 4/I/sub 11/2/ levels

    Energy Technology Data Exchange (ETDEWEB)

    Ageeva, L.E.; Brachovskaya, N.B.; Lunter, S.G.; Przhevuskii, A.K.; Tolstoi, M.N.

    1977-11-01

    The temperature dependence of the intensity of the absorption band corresponding to the /sup 4/I/sub 11/2/..-->../sup 4/F/sub 3/2/ transition was measured for the neodymium glasses GLS-3 (silicate) and GLS-24 (phosphate) in the range of 300-720/sup 0/K. The data were used to calculate the stimulated emission cross sections sigma/sub 0/=1.7 x 10/sup -20/ cm/sup 2/ (GLS-2, GLS-3) and sigma/sub 0/=3.3 x 10/sup -20/ cm/sup 2/ (GLS-21, -22, -23, -24). This investigation, together with a comparison with the results of measuring the cross section sigma/sub 0/ by other spectroscopic methods, suggested that the integrated intensity of the /sup 4/F/sub 3/2/..-->../sup 4/I/sub 11/2/ transition was practically unaffected by a considerable variation in the populations of the levels governing the fine structure. It was found by two independent methods that the absorption of Nd/sup 3 +/ ions at 1.06 ..mu.. at T=300/sup 0/K was 3 x 10/sup -4/ cm/sup -1/ (GLS-3) and 6 x 10/sup -4/ cm/sup -1/ (GLS-24).

  14. Non thermal cyclotron emission and absorption

    International Nuclear Information System (INIS)

    Rax, J.M.

    1984-08-01

    The problem of emission and absorption in an inhomogeneous, anisotropic plasma out of thermal equilibrium is investigated. We explicitly construct the Green function of the Maxwell equations in the eikonal approximation. Then, considering the fluctuating microcurrents associated with the non thermal component of the electronic population, we give the general expressions for the source function and the optical depth. The theory is then applied to a tokamak plasma whose current is generated by lower-hybrid waves and to the final stage of the Parail-Pogutse instability

  15. Nonlinear Absorptions in Liquids Studied by Laser - Anharmonic Thermal Gratings.

    Science.gov (United States)

    Zhu, Xiao-Rong

    In an absorbing medium, nonlinear absorption at a crossed-beam interference pattern creates, through absorptive heating, a temperature modulation containing harmonics of the spatial frequency of the excitation interference pattern, and the temperature dependence of the refractive index then results in an anharmonic volume index grating. A probe beam incident at the Bragg angle for a given spatial harmonic grating will produce a single diffraction order. By measuring the excitation intensity dependence of diffraction efficiencies at several Bragg angles, one can distinguish between various mechanisms of nonlinear absorption. In this dissertation, nonlinear absorption by organic molecules in liquids, with a focus on the sequential two-step absorption, has been studied by a laser-induced anharmonic thermal grating techniques. The nonlinear absorption of all-trans- beta-carotene, a biologically important natural product, in liquids is first investigated, and the results indicate that nonlinear absorption of beta -carotene in hexane is caused by the excited-state absorption, and while the saturation observed in chloroform is due to formation of a long-lived photoisomer. The effect of photoisomerization on saturated absorption of the cyanine laser dye DODCI in alcohols is then examined. It is found that the weaker absorption by the photoisomer and reverse -photoisomerization have made saturation of optical absorption of DODCI difficult. A general numerical method is developed for the first time to treat rigorously the problem of diffraction from anharmonic Gaussian volume gratings. It shows that the previously developed quasi-plane wave approximation (QPWA) theory is valid only at the weak saturation limit for a saturation absorption model. Finally, anomalous dependence of diffraction intensities on the excitation intensity for two tricarbocyanine dyes is observed. A careful analysis shows that it is caused by diffraction from multiple thermal gratings with a 180^ circ

  16. On sound absorption and thermal properties of non-wovens

    Directory of Open Access Journals (Sweden)

    Chen Jin-Jing

    2015-01-01

    Full Text Available Non-woven is widely used as auxiliary materials of automobile industry due to its excellent sound absorption capability and good thermal property. The paper concludes that its density greatly affects sound absorption and thermal resistance, and an aluminum evaporated film can enhance the thermal resistance.

  17. On sound absorption and thermal properties of non-wovens

    OpenAIRE

    Chen Jin-Jing; Yu Hong-Qin; Guo Zheng; You Jin-Zhang; Song Wen-Fang

    2015-01-01

    Non-woven is widely used as auxiliary materials of automobile industry due to its excellent sound absorption capability and good thermal property. The paper concludes that its density greatly affects sound absorption and thermal resistance, and an aluminum evaporated film can enhance the thermal resistance.

  18. Temperature dependence of the HNO3 UV absorption cross sections

    Science.gov (United States)

    Burkholder, James B.; Talukdar, Ranajit K.; Ravishankara, A. R.; Solomon, Susan

    1993-01-01

    The temperature dependence of the HNO3 absorption cross sections between 240 and 360 K over the wavelength range 195 to 350 nm has been measured using a diode array spectrometer. Absorption cross sections were determined using both (1) absolute pressure measurements at 298 K and (2) a dual absorption cell arrangement in which the absorption spectrum at various temperatures is measured relative to the room temperature absorption spectrum. The HNO3 absorption spectrum showed a temperature dependence which is weak at short wavelengths but stronger at longer wavelengths which are important for photolysis in the lower stratosphere. The 298 K absorption cross sections were found to be larger than the values currently recommended for atmospheric modeling (DeMore et al., 1992). Our absorption cross section data are critically compared with the previous measurements of both room temperature and temperature-dependent absorption cross sections. Temperature-dependent absorption cross sections of HNO3 are recommended for use in atmospheric modeling. These temperature dependent HNO3 absorption cross sections were used in a two-dimensional dynamical-photochemical model to demonstrate the effects of the revised absorption cross sections on loss rate of HNO3 and the abundance of NO2 in the stratosphere.

  19. Seasonal Solar Thermal Absorption Energy Storage Development.

    Science.gov (United States)

    Daguenet-Frick, Xavier; Gantenbein, Paul; Rommel, Mathias; Fumey, Benjamin; Weber, Robert; Gooneseker, Kanishka; Williamson, Tommy

    2015-01-01

    This article describes a thermochemical seasonal storage with emphasis on the development of a reaction zone for an absorption/desorption unit. The heat and mass exchanges are modelled and the design of a suitable reaction zone is explained. A tube bundle concept is retained for the heat and mass exchangers and the units are manufactured and commissioned. Furthermore, experimental results of both absorption and desorption processes are presented and the exchanged power is compared to the results of the simulations.

  20. Standard Practice for Evaluating Solar Absorptive Materials for Thermal Applications

    CERN Document Server

    American Society for Testing and Materials. Philadelphia

    2007-01-01

    1.1 This practice covers a testing methodology for evaluating absorptive materials used in flat plate or concentrating collectors, with concentrating ratios not to exceed five, for solar thermal applications. This practice is not intended to be used for the evaluation of absorptive surfaces that are (1) used in direct contact with, or suspended in, a heat-transfer liquid, (that is, trickle collectors, direct absorption fluids, etc.); (2) used in evacuated collectors; or (3) used in collectors without cover plate(s). 1.2 Test methods included in this practice are property measurement tests and aging tests. Property measurement tests provide for the determination of various properties of absorptive materials, for example, absorptance, emittance, and appearance. Aging tests provide for exposure of absorptive materials to environments that may induce changes in the properties of test specimens. Measuring properties before and after an aging test provides a means of determining the effect of the exposure. 1.3 Th...

  1. Using lamb waves tomonitor moisture absorption thermally fatigues composite laminates

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Jae Sun; Cho, Youn Ho [School of Mechanical Engineering, Pusan National University, Busan (Korea, Republic of)

    2016-06-15

    Nondestructive evaluation for material health monitoring is important in aerospace industries. Composite laminates are exposed to heat cyclic loading and humid environment depending on flight conditions. Cyclic heat loading and moisture absorption may lead to material degradation such as matrix breaking, debonding, and delamination. In this paper, the moisture absorption ratio was investigated by measuring the Lamb wave velocity. The composite laminates were manufactured and subjected to different thermal aging cycles and moisture absorption. For various conditions of these cycles, not only changes in weight and also ultrasonic wave velocity were measured, and the Lamb wave velocity at various levels of moisture on a carbon-epoxy plate was investigated. Results from the experiment show a linear correlation between moisture absorption ratio and Lamb wave velocity at different thermal fatigue stages. The presented method can be applied as an alternative solution in the online monitoring of composite laminate moisture levels in commercial flights.

  2. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Science.gov (United States)

    Han, Dongxiao; Meng, Zhaoguo; Wu, Daxiong; Zhang, Canying; Zhu, Haitao

    2011-07-01

    In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  3. Thermal properties of carbon black aqueous nanofluids for solar absorption

    Directory of Open Access Journals (Sweden)

    Han Dongxiao

    2011-01-01

    Full Text Available Abstract In this article, carbon black nanofluids were prepared by dispersing the pretreated carbon black powder into distilled water. The size and morphology of the nanoparticles were explored. The photothermal properties, optical properties, rheological behaviors, and thermal conductivities of the nanofluids were also investigated. The results showed that the nanofluids of high-volume fraction had better photothermal properties. Both carbon black powder and nanofluids had good absorption in the whole wavelength ranging from 200 to 2,500 nm. The nanofluids exhibited a shear thinning behavior. The shear viscosity increased with the increasing volume fraction and decreased with the increasing temperature at the same shear rate. The thermal conductivity of carbon black nanofluids increased with the increase of volume fraction and temperature. Carbon black nanofluids had good absorption ability of solar energy and can effectively enhance the solar absorption efficiency.

  4. Absorption in Sport: A Cross-Validation Study

    Science.gov (United States)

    Koehn, Stefan; Stavrou, Nektarios A. M.; Cogley, Jeremy; Morris, Tony; Mosek, Erez; Watt, Anthony P.

    2017-01-01

    Absorption has been identified as readiness for experiences of deep involvement in the task. Conceptually, absorption is a key psychological construct, incorporating experiential, cognitive, and motivational components. Although, no operationalization of the construct has been provided to facilitate research in this area, the purpose of this research was the development and examination of the psychometric properties of a sport-specific measure of absorption that evolved from the use of the modified Tellegen Absorption Scale (MODTAS; Jamieson, 2005) in mainstream psychology. The study aimed to provide evidence of the psychometric properties, reliability, and validity of the Measure of Absorption in Sport Contexts (MASCs). The psychometric examination included a calibration sample from Scotland and a cross-validation sample from Australia using a cross-sectional design. The item pool was developed based on existing items from the modified Tellegen Absorption Scale (Jamieson, 2005). The MODTAS items were reworded and translated into a sport context. The Scottish sample consisted of 292 participants and the Australian sample of 314 participants. Congeneric model testing and confirmatory factor analysis for both samples and multi-group invariance testing across samples was used. In the cross-validation sample the MASC subscales showed acceptable internal consistency and construct reliability (≥0.70). Excellent fit indices were found for the final 18-item, six-factor measure in the cross-validation sample, χ(120)2 = 197.486, p sport-specific measure of absorption. The MASC provides rich research opportunities in sport psychology that can enhance the theoretical understanding between absorption and related constructs and facilitate future intervention studies. PMID:28883802

  5. Temperature-dependent absorption cross sections for hydrogen peroxide vapor

    Science.gov (United States)

    Nicovich, J. M.; Wine, P. H.

    1988-01-01

    Relative absorption cross sections for hydrogen peroxide vapor were measured over the temperature ranges 285-381 K for lambda = 230 nm-295 nm and 300-381 K for lambda = 193 nm-350 nm. The well established 298 K cross sections at 202.6 and 228.8 nm were used as an absolute calibration. A significant temperature dependence was observed at the important tropospheric photolysis wavelengths lambda over 300 nm. Measured cross sections were extrapolated to lower temperatures, using a simple model which attributes the observed temperature dependence to enhanced absorption by molecules possessing one quantum of O-O stretch vibrational excitation. Upper tropospheric photodissociation rates calculated using the extrapolated cross sections are about 25 percent lower than those calculated using currently recommended 298 K cross sections.

  6. Estimation of the Human Absorption Cross Section Via Reverberation Models

    DEFF Research Database (Denmark)

    Steinböck, Gerhard; Pedersen, Troels; Fleury, Bernard Henri

    2018-01-01

    and compare the obtained results to those of Sabine's model. We find that the absorption by persons is large enough to be measured with a wideband channel sounder and that estimates of the human absorption cross section differ for the two models. The obtained values are comparable to values reported...... in the literature. We also suggest the use of controlled environments with low average absorption coefficients to obtain more reliable estimates. The obtained values can be used to predict the change of reverberation time with persons in the propagation environment. This allows prediction of channel characteristics...... relevant in communication systems, e.g. path loss and rms delay spread, for various population densities....

  7. Emission and absorption cross section of thulium doped silica fibers

    DEFF Research Database (Denmark)

    Agger, Søren Dyøe; Povlsen, Jørn Hedegaard

    2006-01-01

    A thorough investigation of the emission and absorption spectra of the (F-3(4),H-3(6)) band in thulium doped silica fibers has been performed. All the basic parameters of thulium in silica have been extracted with the purpose of further analysis in laser and amplifier simulations. The experimental...... methods used to obtain the scaled cross sections have been carefully selected in order to avoid problems associated with calibrated measurements and knowledge of the radiative lifetime. The values of the absorption cross sections agree well with previously reported values, however the peak emission...

  8. The absorption of thermal radiation by water films

    International Nuclear Information System (INIS)

    Pearson, K.G.; Elliott, D.

    1977-04-01

    Except at the shortest wavelengths (i.e. <2μm) liquid water is relatively opaque to thermal radiation. It is also a poor reflector, reflecting back only about 2% of normal incident radiation. It is shown that when radiation falls on a plane water surface from a parallel heated surface about 93.5% of the incident radiation enters the surface, the remaining 6.5% being reflected back to the source. It is also shown that, for source temperatures up to the maximum of interest in reactor safety studies, a large fraction of the thermal radiation which enters the water is absorbed on passing through a distance approaching 0.5 mm. Since liquid water films of such thickness can be expected to exist on the pressure tubes of an SGHWR following a loss of coolant accident it follows that, irrespective of the condition of the pressure tube wall, the absorptivity of the pressure tubes will in effect be about 0.9. Data are presented for experiments performed to determine the absorptivity of water films on a polished surface whose dry absorptivity was measured to be 0.18. The presence of the water film, of estimated thickness 0.3 mm, increased the absorptivity of the surface to a value close to unity. (author)

  9. Scattering and absorption differential cross sections for double ...

    Indian Academy of Sciences (India)

    The scattering and absorption differential cross sections for nonlinear QED process such as double photon Compton scattering have been measured as a function of independent final photon energy. The incident gamma photons are of 0.662 MeV in energy as produced by an 8 Ci137Cs radioactive source and thin ...

  10. Scattering and absorption differential cross sections for double ...

    Indian Academy of Sciences (India)

    absorption differential cross sections agree with theory within experimental estimated error. Keywords. ... have been given in a previous paper [2] to which we refer for literature on the theoretical studies on this process ... thick iron and 1 mm thick aluminium, with iron facing lead to absorb K x-rays emitted by lead shielding.

  11. Mid-IR Absorption Cross-Section Measurements of Hydrocarbons

    KAUST Repository

    Alrefae, Majed Abdullah

    2013-05-01

    Laser diagnostics are fast-response, non-intrusive and species-specific tools perfectly applicable for studying combustion processes. Quantitative measurements of species concentration and temperature require spectroscopic data to be well-known at combustion-relevant conditions. Absorption cross-section is an important spectroscopic quantity and has direct relation to the species concentration. In this work, the absorption cross-sections of basic hydrocarbons are measured using Fourier Transform Infrared (FTIR) spectrometer, tunable Difference Frequency Generation laser and fixed wavelength helium-neon laser. The studied species are methane, methanol, acetylene, ethylene, ethane, ethanol, propylene, propane, 1-butene, n-butane, n-pentane, n-hexane, and n-heptane. The Fourier Transform Infrared (FTIR) spectrometer is used for the measurements of the absorption cross-sections and the integrated band intensities of the 13 hydrocarbons. The spectral region of the spectra is 2800 – 3400 cm-1 (2.9 – 3.6 μm) and the temperature range is 673 – 1100 K. These valuable data provide huge opportunities to select interference-free wavelengths for measuring time-histories of a specific species in a shock tube or other combustion systems. Such measurements can allow developing/improving chemical kinetics mechanisms by experimentally determining reaction rates. The Difference Frequency Generation (DFG) laser is a narrow line-width, tunable laser in the 3.35 – 3.53 μm wavelength region which contains strong absorption features for most hydrocarbons due to the fundamental C-H vibrating stretch. The absorption cross-sections of propylene are measured at seven different wavelengths using the DFG laser. The temperature range is 296 – 460 K which is reached using a Reflex Cell. The DFG laser is very attractive for kinetic studies in the shock tube because of its fast time response and the potential possibility of making species-specific measurements. The Fixed wavelength

  12. Gigahertz-peaked Spectra Pulsars and Thermal Absorption Model

    Energy Technology Data Exchange (ETDEWEB)

    Kijak, J.; Basu, R.; Lewandowski, W.; Rożko, K. [Janusz Gil Institute of Astronomy, University of Zielona Góra, ul. Z. Szafrana 2, PL-65-516 Zielona Góra (Poland); Dembska, M., E-mail: jkijak@astro.ia.uz.zgora.pl [DLR Institute of Space Systems, Robert-Hooke-Str. 7 D-28359 Bremen (Germany)

    2017-05-10

    We present the results of our radio interferometric observations of pulsars at 325 and 610 MHz using the Giant Metrewave Radio Telescope. We used the imaging method to estimate the flux densities of several pulsars at these radio frequencies. The analysis of the shapes of the pulsar spectra allowed us to identify five new gigahertz-peaked spectra (GPS) pulsars. Using the hypothesis that the spectral turnovers are caused by thermal free–free absorption in the interstellar medium, we modeled the spectra of all known objects of this kind. Using the model, we were able to put some observational constraints on the physical parameters of the absorbing matter, which allows us to distinguish between the possible sources of absorption. We also discuss the possible effects of the existence of GPS pulsars on future search surveys, showing that the optimal frequency range for finding such objects would be from a few GHz (for regular GPS sources) to possibly 10 GHz for pulsars and radio magnetars exhibiting very strong absorption.

  13. Modeling the thermal absorption factor of photovoltaic/thermal combi-panels

    International Nuclear Information System (INIS)

    Santbergen, R.; Zolingen, R.J.Ch. van

    2006-01-01

    In a photovoltaic/thermal combi-panel solar cells generate electricity while residual heat is extracted to be used for tap water heating or room heating. In such a panel the entire solar spectrum can be used in principle. Unfortunately long wavelength solar irradiance is poorly absorbed by the semiconductor material in standard solar cells. A computer model was developed to determine the thermal absorption factor of crystalline silicon solar cells. It was found that for a standard untextured solar cell with a silver back contact a relatively large amount of long wavelength irradiance is lost by reflection resulting in an absorption factor of only 74%. The model was then used to investigate ways to increase this absorption factor. One way is absorbing long wavelength irradiance in a second absorber behind a semi-transparent solar cell. According to the model this will increase the total absorption factor to 87%. The second way is to absorb irradiance in the back contact of the solar cell by using rough interfaces in combination with a non-standard metal as back contact. Theoretically the absorption factor can then be increased to 85%

  14. Measurement of thermal neutron capture cross section

    International Nuclear Information System (INIS)

    Huang Xiaolong; Han Xiaogang; Yu Weixiang; Lu Hanlin; Zhao Wenrong

    2001-01-01

    The thermal neutron capture cross sections of 71 Ga(n, γ) 72 Ga, 94 Zr(n, γ) 95 Zr and 191 Ir(n, γ) 192 Ir m1+g,m2 reactions were measured by using activation method and compared with other measured data. Meanwhile the half-life of 72 Ga was also measured. The samples were irradiated with the neutron in the thermal column of heavy water reactor of China Institute of Atomic Energy. The activities of the reaction products were measured by well-calibrated Ge(Li) detector

  15. Two Photon Absorption Cross-Section Of New Fluophore Compounds

    Science.gov (United States)

    El-Nadi, Lotfia; Farag, Ahmad M.; El-Sherbiny, Ashraf; Gamal, Yosr E.

    2005-03-01

    This study is a continuation of previous work carried by our group to synthesize and develop new fluophore compounds that could be used in fluorescence light microscopy for imaging biological molecules. Marking biological cells by such fluophores allow real time observation of single molecules. We synthesized and determined the absorption and emission spectra of the following new fluophores: ( L1 ) 4-Amino-2-oxo-2H-pyrido[1,2-a]pyrimidine-3-carbothioic phenyl-amide. ( L9 ) 3-(2-benzenesulfonyl-3-dimethylamino acryloyl) coumarine. ( L11 ) 1-(4-bromophenyle)-4-(coumarin-3-carbonyl)-1H-pyrazole- 3 - carboxylic acid ethyl ester. The absorption spectra are found to peak at wavelengths 285, 358 and 370 nm. [for (L1)], 285, 320 and 360 nm. [for (L9)] and 285 and 360 nm. [for (L11)] Emission lines are observed at 486 nm., 430 nm. and 470 nm for ( L1 ), (L9) and (L11), respectively. These emission lines peaked when (L1), (L9) and (L11) were excited by 370,366 and 360 nm, respectively. This means that all three fluophores could be excited by two photon absorption (TPA) from IR laser of wavelength 730+- 10 nm. or three photon absorption (THPA) of IR laser at 1064+-20 nm. nearly without tuning. Multiphoton excitation of fluophors marking biological samples is advantageous over single photon excitation. The (TPA) and (THPA) fluorescent intensities have been measured for the three fluophors in DMF solution at different concentrations using both 90 femtosecond Ti-sapphire laser at powers up to 250 MW and 7 nanosecond Nd:YAG laser up to 10 MW. The estimated (TPA) cross-sections are of the order of 10-39 cm2 / photon and the (THPA) cross-sections are less by a factor more than 10 times that of (TPA).

  16. Thermal Analyse sof Cross-Linked Polyethylene

    Directory of Open Access Journals (Sweden)

    Radek Polansky

    2007-01-01

    Full Text Available The paper summarizes results obtained during the structural analyses measurements (Differential Scanning Calorimetry DSC, Thermogravimetry TG, Thermomechanical analysis TMA and Fourier transform infrared spectroscopy FT-IR. The samples of cross-linked polyethylene cable insulation were tested via these analyses. The DSC and TG were carried out using simultaneous thermal analyzer TA Instruments SDT Q600 with connection of Fourier transform infrared spectrometer Nicolet 380. Thermomechanical analysis was carried out by TMA Q400EM TA Instruments apparatus.

  17. Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides

    DEFF Research Database (Denmark)

    Pu, Minhao; Chen, Yaohui; Yvind, Kresten

    2014-01-01

    Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects.......Influence of thermal effects induced by nonlinear absorption on four-wave mixing in silicon waveguides is investigated. A conversion bandwidth reduction up to 63% is observed in simulation due to the thermal effects....

  18. Thermal Analysis of a Solar Powered Absorption Cooling System with Fully Mixed Thermal Storage at Startup

    Directory of Open Access Journals (Sweden)

    Camelia Stanciu

    2017-01-01

    Full Text Available A simple effect one stage ammonia-water absorption cooling system fueled by solar energy is analyzed. The considered system is composed by a parabolic trough collector concentrating solar energy into a tubular receiver for heating water. This is stored in a fully mixed thermal storage tank and used in the vapor generator of the absorption cooling system. Time dependent cooling load is considered for the air conditioning of a residential two-storey house. A parametric study is performed to analyze the operation stability of the cooling system with respect to solar collector and storage tank dimensions. The results emphasized that there is a specific storage tank dimension associated to a specific solar collector dimension that could ensure the longest continuous startup operation of the cooling system when constant mass flow rates inside the system are assumed.

  19. Analytical Absorption Cross-Section for Photon by a Hydrogen 2s Atom

    International Nuclear Information System (INIS)

    Ndinya, Boniface Otieno; Okeyo, Stephen Onyango

    2011-01-01

    We calculate the absorption cross-section for photon by a hydrogen 2s atom using the quantum-classical approximation for the total photo cross-section of many electron atoms. With the application of the first-order term of the Baker-Hausdorf expansion, the absorption cross-section for the hydrogen 2s atom decreases to a minimum, the Cooper pair minimum, at low photon energy. Such a minimum is absent in the exact absorption cross-section for photon by a hydrogen 2s atom. We have extended the calculation for the absorption cross-section of the hydrogen 2s atom using the quantum-classical approximation for the total photo cross-section of many electron to include the second-order term of the Baker-Hausdorf expansion and observed a great reduction in the dip associated with the Cooper pair minimum at the zero crossing. (atomic and molecular physics)

  20. Model for forecasting of monthly average insulation at ground level taking into account the radiation absorption losses crossing atmosphere in the thermal solar applications; Modelo de previsao da insolacao media mensal ao nivel do solo levando em conta a perda por absorcao na atmosfera em aplicacoes solares termicas

    Energy Technology Data Exchange (ETDEWEB)

    Camargo, J.C.; Apolinario, F.R.; Silva, E.P. da [Universidade Estadual de Campinas, SP (Brazil). Lab. de Hidrogenio]. E-mails: joaoc@fem.unicamp.br; rezende@ifi.unicamp.br; lh2ennio@ifi.unicamp.br

    2000-07-01

    The use of the solar energy, for thermal or photovoltaic ends, depends basically on the amount of radiation that reaches the ground in the place where desires to carry through this use, defining the necessary area of the collectors, or panels, that in turn are the main components of the final cost of the system and, therefore, of the viability or not on its use. The incident radiation in the terrestrial surface is minor that one reaches the top of the atmosphere due to the absorption and dispersion factors. The objective of this work is to present a model of forecast the monthly average radiation for ends of use in systems of flat solar collectors for heating water, in the city of Campinas - Sao Paulo, Brazil. This work has been developed by the Hydrogen Laboratory of the Institute of Physics of the UNICAMP, being also used for other applications with solar energy. Based in the radiation data, taken from a local station, a theoretical study was developed to calculate a parameter of loss of radiation when this cross the atmosphere. This Kt loss factor, has basic importance for the knowledge of the effective available energy for use. With this data it is possible to determine, on the basis of the incident radiation in the top of the atmosphere, the value of the radiation on a surface. (author)

  1. Absorption coefficient of nearly transparent liquids measured using thermal lens spectrometry

    Directory of Open Access Journals (Sweden)

    H.Cabrera

    2006-01-01

    Full Text Available We use an optimized pump-probe mode-mismatched thermal lens scheme to determine the optical absorption coefficient and thermal diffusivity of ethanol, benzene, acetone, methanol, toluene and chloroform. In this scheme the excitation beam is focused in the presence of a collimated probe beam. The agreement between experimentally obtained results and values reported in the literature is good.

  2. Microscopic cross-section measurements by thermal neutron activation

    International Nuclear Information System (INIS)

    Avila L, J.

    1987-08-01

    Microscopic cross sections measured by thermal neutron activation using RP-0 reactor at the Peruvian Nuclear Energy Institute. The method consists in measuring microscopic cross section ratios through activated samples, requiring being corrected in thermal and epithermal energetic range by Westcott formalism. Furthermore, the comptage ratios measured for each photopeak to its decay fraction should be normalized from interrelation between both processes above, activation microscopic cross sections are obtained

  3. Thermal conductivity of carbon nanotube cross-bar structures

    International Nuclear Information System (INIS)

    Evans, William J; Keblinski, Pawel

    2010-01-01

    We use non-equilibrium molecular dynamics (NEMD) to compute the thermal conductivity (κ) of orthogonally ordered cross-bar structures of single-walled carbon nanotubes. Such structures exhibit extremely low thermal conductivity in the range of 0.02-0.07 W m -1 K -1 . These values are five orders of magnitude smaller than the axial thermal conductivity of individual carbon nanotubes, and are comparable to the thermal conductivity of still air.

  4. Energy-absorption capability and scalability of square cross section composite tube specimens

    Science.gov (United States)

    Farley, Gary L.

    1987-01-01

    Static crushing tests were conducted on graphite/epoxy and Kevlar/epoxy square cross section tubes to study the influence of specimen geometry on the energy-absorption capability and scalability of composite materials. The tube inside width-to-wall thickness (W/t) ratio was determined to significantly affect the energy-absorption capability of composite materials. As W/t ratio decreases, the energy-absorption capability increases nonlinearly. The energy-absorption capability of Kevlar epoxy tubes was found to be geometrically scalable, but the energy-absorption capability of graphite/epoxy tubes was not geometrically scalable.

  5. Quasinormal modes, stability analysis and absorption cross section for 4-dimensional topological Lifshitz black hole

    International Nuclear Information System (INIS)

    Gonzalez, P.A.; Moncada, Felipe; Vasquez, Yerko

    2012-01-01

    We study scalar perturbations in the background of a topological Lifshitz black hole in four dimensions. We compute analytically the quasinormal modes and from these modes we show that topological Lifshitz black hole is stable. On the other hand, we compute the reflection and transmission coefficients and the absorption cross section and we show that there is a range of modes with high angular momentum which contributes to the absorption cross section in the low frequency limit. Furthermore, in this limit, we show that the absorption cross section decreases if the scalar field mass increases, for a real scalar field mass. (orig.)

  6. Quasinormal modes, stability analysis and absorption cross section for 4-dimensional topological Lifshitz black hole

    Energy Technology Data Exchange (ETDEWEB)

    Gonzalez, P.A. [Universidad Central de Chile, Escuela de Ingenieria Civil en Obras Civiles, Facultad de Ciencias Fisicas y Matematicas, Santiago (Chile); Universidad Diego Portales, Santiago (Chile); Moncada, Felipe; Vasquez, Yerko [Universidad de La Frontera, Departamento de Ciencias Fisicas, Facultad de Ingenieria, Ciencias y Administracion, Temuco (Chile)

    2012-12-15

    We study scalar perturbations in the background of a topological Lifshitz black hole in four dimensions. We compute analytically the quasinormal modes and from these modes we show that topological Lifshitz black hole is stable. On the other hand, we compute the reflection and transmission coefficients and the absorption cross section and we show that there is a range of modes with high angular momentum which contributes to the absorption cross section in the low frequency limit. Furthermore, in this limit, we show that the absorption cross section decreases if the scalar field mass increases, for a real scalar field mass. (orig.)

  7. Two-photon absorption cross section of magnetite nanoparticles in magnetic colloids and thin films

    Science.gov (United States)

    Espinosa, D.; Gonçalves, E. S.; Figueiredo Neto, A. M.

    2017-01-01

    We present z-scan measurements of magnetic nanoparticles made from magnetite in both thin film form and colloidal solutions. In order to avoid heating and, thus, spurious effects that could lead to misinterpretation of the z-scan results, an electro-mechanical shutter was added along the beam path in order to guarantee samples thermal relaxation. Two photon absorption coefficient β and nonlinear refractive index n2 were measured as a function of concentration N of absorbing units (Fe3O4). Our magnetite samples presented n 2 ≈ - 1.5 × 10 - 14 cm 2 / W , similar to that of the liquid carrier, for concentrations below 2 × 10 20 cm - 3 . n2 increases, in absolute value, to about - 10 × 10 - 14 cm 2 / W for a sample three times more concentrated and then decreases with N until about - 7 × 10 - 14 cm 2 / W for the most concentrated sample. β presented a linear dependence with N and the two-photon absorption cross section σ 2 PA was calculated, resulting in σ 2 PA = 50 ( 2 ) GM for magnetite nanoparticles.

  8. Aerosol absorption measurement with a sinusoidal phase modulating fiber optic photo thermal interferometer

    Science.gov (United States)

    Li, Shuwang; Shao, Shiyong; Mei, Haiping; Rao, Ruizhong

    2016-10-01

    Aerosol light absorption plays an important role in the earth's atmosphere direct and semi-direct radiate forcing, simultaneously, it also has a huge influence on the visibility impairment and laser engineering application. Although various methods have been developed for measuring aerosol light absorption, huge challenge still remains in precision, accuracy and temporal resolution. The main reason is that, as a part of aerosol light extinction, aerosol light absorption always generates synchronously with aerosol light scattering, and unfortunately aerosol light scattering is much stronger in most cases. Here, a novel photo-thermal interferometry is proposed only for aerosol absorption measurement without disturbance from aerosol scattering. The photo-thermal interferometry consists of a sinusoidal phase-modulating single mode fiber-optic interferometer. The thermal dissipation, caused by aerosol energy from photo-thermal conversion when irritated by pump laser through interferometer, is detected. This approach is completely insensitive to aerosol scattering, and the single mode fiber-optic interferometer is compact, low-cost and insensitive to the polarization shading. The theory of this technique is illustrated, followed by the basic structure of the sinusoidal phase-modulating fiber-optic interferometer and demodulation algorithms. Qualitative and quantitative analysis results show that the new photo-thermal interference is a potential approach for aerosol absorption detection and environmental pollution detection.

  9. The Role of Cross-Cultural Absorptive Capacity in the Effectiveness of In-Country Cross-Cultural Training

    Science.gov (United States)

    Tarique, Ibraiz; Caligiuri, Paula

    2009-01-01

    Based on the theory of absorptive capacity, this study examines the following question. In the context of cross-cultural training, can the amount of previously accumulated cultural knowledge affect the ability of a trainee to absorb further learning about a new culture, thus enhancing total knowledge and presumably cross-cultural adjustment?…

  10. Derivation of water vapour absorption cross-sections in the red region

    Science.gov (United States)

    Lal, M.; Chakrabarty, D. K.

    1994-01-01

    Absorption spectrum in 436 to 448 nm wavelength region gives NO2 and O3 column densities. This spectrum can also give H2O column density. The spectrum in the range of 655 to 667 nm contains absorption due to NO3 and H2O. Combining the absorption spectra in the wavelength ranges of 436 to 448 and 655 to 667 nm, water vapor absorption cross-sections in this range comes out to be of the order of 2.0 x 10(exp -24) cm(exp -2).

  11. Absorption cross-section measurements of methane, ethane, ethylene and methanol at high temperatures

    KAUST Repository

    Alrefae, Majed

    2014-09-01

    Mid-IR absorption cross-sections are measured for methane, ethane, ethylene and methanol over 2800-3400 cm-1 (2.9-3.6 μm) spectral region. Measurements are carried out using a Fourier-Transform-Infrared (FTIR) spectrometer with temperatures ranging 296-1100 K and pressures near atmospheric. As temperature increases, the peak cross-sections decrease but the wings of the bands increase as higher rotational lines appear. Integrated band intensity is also calculated over the measured spectral region and is found to be a very weak function of temperature. The absorption cross-sections of the relatively small fuels studied here show dependence on the bath gas. This effect is investigated by studying the variation of absorption cross-sections at 3.392 μm using a HeNe laser in mixtures of fuel and nitrogen, argon, or helium. Mixtures of fuel with He have the highest value of absorption cross-sections followed by Ar and N2. Molecules with narrow absorption lines, such as methane and methanol, show strong dependence on bath gas than molecules with relatively broader absorption features i.e. ethane and ethylene. © 2014 Elsevier Inc. All rights reserved.

  12. A Model For The Absorption Of Thermal Radiation By Gold-Black

    OpenAIRE

    Quinlan, Brendan Robert

    2015-01-01

    The work presented here addresses an important topic in thermal radiation detection when gold-black is used as an absorber. Sought is a model to simulate the absorption of thermal radiation by gold-black. Fractal geometry is created to simulate the topology of gold-black. Then electrical circuits based on the topology are identified that capture the physics of the interaction between the gold-black material and incident electro-magnetic radiation. Parameters of the model are then adj...

  13. Updated ozone absorption cross section will reduce air quality compliance

    Directory of Open Access Journals (Sweden)

    E. D. Sofen

    2015-12-01

    et al. (2015 as 1.8 % smaller than the accepted value (Hearn, 1961 used for the preceding 50 years. Thus, ozone measurements that applied the older cross section systematically underestimate the amount of ozone in air. We correct the reported historical surface data from North America and Europe and find that this modest change in cross section has a significant impact on the number of locations that are out of compliance with air quality regulations if the air quality standards remain the same. We find 18, 23, and 20 % increases in the number of sites that are out of compliance with current US, Canadian, and European ozone air quality health standards for the year 2012. Should the new cross-section value be applied, it would impact attainment of air quality standards and compliance with relevant clean air acts, unless the air quality target values themselves were also changed proportionately. We draw attention to how a small change in gas metrology has a global impact on attainment and compliance with legal air quality standards. We suggest that further laboratory work to evaluate the new cross section is needed and suggest three possible technical and policy responses should the new cross section be adopted.

  14. Using Thermal Infrared Absorption and Emission to Determine Trace Gases

    Science.gov (United States)

    Clerbaux, Cathy; Drummond, James R.; Flaud, Jean-Marie; Orphal, Johannes

    The light emerging from the top of the atmosphere in the greater part of the infrared region is thermal radiation from the Earth's surface. The resultant spectra obtained depend on the temperature difference between the emitting feature and absorbing gas. In this region the greenhouse gases, carbon dioxide, CO2, methane, CH4, ozone, O3, and water, H2O, are observed as well as carbon monoxide, CO, a product indicative of fossil fuel combustion, methanol, CH3OH, from biomass burning, and ammonia, NH3, from agriclulture. Chapter 3 describes the techniques for retrieving atmospheric abundances of these and other species from a number of satellite instruments, and concludes with suggestions for future developments.

  15. Cross-plane thermal conductivity of tungsten diselenide

    Energy Technology Data Exchange (ETDEWEB)

    Norouzzadeh, Payam; Singh, David J. [Department of Physics and Astronomy, University of Missouri-Columbia, Columbia, MO (United States)

    2017-03-15

    The cross-plane thermal conductivity of WSe{sub 2} is investigated using reverse nonequilibrium molecular dynamics (RNEMD) and a recently developed Stillinger-Weber potential. It is found that the cross-plane thermal conductivity of WSe{sub 2} is strongly size dependent and saturates around 80 layers. Moreover, it is shown that even at 1000 K, ordered crystalline WSe{sub 2} does not reach the phonon glass-like limit in the cross-plane direction. (copyright 2017 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  16. Photoreactivities and thermal properties of psoralen cross-links

    International Nuclear Information System (INIS)

    Yeung, A.T.; Jones, B.K.; Chu, C.T.

    1988-01-01

    The authors have studied the photoreaction of 8-methoxypsoralen (8-MOP), 4,5',8-trimethylpsoralen (TMP), and 4'-(hydroxymethyl)-4,5',8-trimethylpsoralen (HMT) with a pair of 18-base-long oligonucleotides in which a 14-base region is complementary. Only one 5'TpA site, favored for both monoadduct and cross-link formation with psoralen, is present in this oligonucleotide pair. They have used this model system to demonstrate, for the first time, strand specificity in the photoreaction of psoralen with DNA. They found that the two types of cross-links which form at this site have large differences in thermal stabilities. In addition, the denaturation of each cross-links isomer duplex occurred in at least three stages, which can be visualized as three bands in thermal equilibrium under the conditions of a denaturing polyacrylamide gel. This novel observation suggests that there are several domains differing in thermal stability in a psoralen cross-link

  17. Simultaneous Absorptance and Thermal-Diffusivity Determination of Optical Components with Laser Calorimetry Technique

    Science.gov (United States)

    Wang, Yanru; Li, Bincheng

    2012-11-01

    The laser calorimetry (LCA) technique is used to determine simultaneously the absorptances and thermal diffusivities of optical components. An accurate temperature model, in which both the finite thermal conductivity and the finite sample size are taken into account, is employed to fit the experimental temperature data measured with an LCA apparatus for a precise determination of the absorptance and thermal diffusivity via a multiparameter fitting procedure. The uniqueness issue of the multiparameter fitting is discussed in detail. Experimentally, highly reflective (HR) samples prepared with electron-beam evaporation on different substrates (BK7, fused silica, and Ge) are measured with LCA. For the HR-coated sample on a fused silica substrate, the absorptance is determined to be 15.4 ppm, which is close to the value of 17.6 ppm, determined with a simplified temperature model recommended in the international standard ISO11551. The thermal diffusivity is simultaneously determined via multiparameter fitting to be approximately 6.63 × 10-7 m2 · s-1 with a corresponding square variance of 4.8 × 10-4. The fitted thermal diffusivity is in reasonably good agreement with the literature value (7.5 × 10-7 m2 · s -1). Good agreement is also obtained for samples with BK7 and Ge substrates.

  18. The determination of thermal neutron cross section of 81Br

    International Nuclear Information System (INIS)

    Kovacs, Luciana; Zamboni, Cibele B.; Dalaqua Junior, Leonardo

    2009-01-01

    In this investigation several standard materials were used to determine the thermal neutron cross section of 81 Br. This nuclear parameter is an important data to perform several quantitative investigations, mainly in medical area. In other to confirm and to reduce the uncertainty, a new measurement was preformed using thermal neutron at IEA-R1 nuclear reactor of IPEN/CNEN-SP. The result obtained is compatible with the tabulated value and present small uncertainly. (author)

  19. The Tsallis Statistics applied to the calculation of absorption cross section of 238U, 232Th and 240Pu isotopes

    International Nuclear Information System (INIS)

    Guedes, Guilherme; Gonçalves, Alessandro C.; Palma, Daniel A.P.

    2017-01-01

    The thermal agitation movement in the reactor core is adequately represented by the microscopic cross section of the neutron-nucleus interaction through the Doppler broadening function. In the last decades several researches had been done on fundamentals and applications of generalized statistical theories based on quasi-Maxwellian distribution of probabilities. In this paper the effect of taking into account the non extensive Tsallis statistics in the evaluation of the absorption cross section in 3-dimension is discussed. In this context, it is obtained an integral form for a generalized Doppler broadening function in the scope of the single-level formalism given by the Bethe-Placzek approximations. This new function reproduces the well-established conventional Doppler broadening function on the limit when q removes the deformation. Numerical tests were carried out and by varying the q parameter it was possible to study the range of values where the effect is appreciable. (author)

  20. Diaryl-substituted norbornadienes with red-shifted absorption for molecular solar thermal energy storage.

    Science.gov (United States)

    Gray, Victor; Lennartson, Anders; Ratanalert, Phasin; Börjesson, Karl; Moth-Poulsen, Kasper

    2014-05-25

    Red-shifting the absorption of norbornadienes (NBDs), into the visible region, enables the photo-isomerization of NBDs to quadricyclanes (QCs) to be driven by sunlight. This is necessary in order to utilize the NBD-QC system for molecular solar thermal (MOST) energy storage. Reported here is a study on five diaryl-substituted norbornadienes. The introduced aryl-groups induce a significant red-shift of the UV/vis absorption spectrum of the norbornadienes, and device experiments using a solar-simulator set-up demonstrate the potential use of these compounds for MOST energy storage.

  1. Thermal performance modeling of cross-flow heat exchangers

    CERN Document Server

    Cabezas-Gómez, Luben; Saíz-Jabardo, José Maria

    2014-01-01

    This monograph introduces a numerical computational methodology for thermal performance modeling of cross-flow heat exchangers, with applications in chemical, refrigeration and automobile industries. This methodology allows obtaining effectiveness-number of transfer units (e-NTU) data and has been used for simulating several standard and complex flow arrangements configurations of cross-flow heat exchangers. Simulated results have been validated through comparisons with results from available exact and approximate analytical solutions. Very accurate results have been obtained over wide ranges

  2. Volumetric Heat Generation and Consequence Raise in Temperature Due to Absorption of Neutrons from Thermal up to 14.9 MeV Energies

    CERN Document Server

    Massoud, E

    2003-01-01

    In this work, the heat generation rate and the consequence rise in temperature due to absorption of all neutrons from thermal energies (E<0.025) up to 14.9 MeV in water, paraffin wax, ordinary concrete and heavy concrete and heavy concrete as some selected hydrogenous materials are investigated. The neutron flux distributions are calculated by both ANISN-code and three group method in which the fast neutrons are expressed by the removal cross section concept while the other two groups (epithermal and thermal) are treated by the diffusion equation. The heat generation can be calculated from the neutron macroscopic absorption of each material or mixture multiplied by the corresponding neutron fluxes. The rise in temperature is then calculated by using both of the heat generation and the thermal conductivity of the selected materials. Some results are compared with the available experimental and theoretical data and a good agreement is achieved.

  3. The effect of background absorption on the compound cross-section in resonance scattering

    International Nuclear Information System (INIS)

    Frenkel, A.

    1976-01-01

    The effect of channel-channel correlations in the compound cross-section is studied in a model of a resonance above a compound background characterized by equal absorption in all open channels. A general rule which cannot be derived from unitarity alone is proved for the fluctuating cross-section. It provides new understanding of level-level correlations in scattering through compound nucleus states. (author)

  4. A LiBr-H2O Absorption Refrigerator Incorporating a Thermally Activated Solution Pumping Mechanism

    OpenAIRE

    Ian W. Eames

    2017-01-01

    This paper provides an illustrated description of a proposed LiBr-H2O vapour absorption refrigerator which uses a thermally activated solution pumping mechanism that combines controlled variations in generator vapour pressure with changes it produces in static-head pressure difference to circulate the absorbent solution between the generator and absorber vessels. The proposed system is different and potentially more efficient than a bubble pump system previously proposed and avoids the need f...

  5. Quantitative comparisons of absorption cross-section spectra and integrated intensities of HFC-143a

    International Nuclear Information System (INIS)

    Le Bris, Karine; Graham, Laura

    2015-01-01

    The integrated absorption cross-sections of HFC-143a (CH 3 CF 3 ) differ substantially in the literature. This leads to an important uncertainty on the value of the radiative efficiency of this molecule. The ambiguity on the absorption cross-sections of HFC-143a is highlighted by the existence of two significantly different datasets in the HITRAN database. To solve the issue, we performed high-resolution Fourier transform infrared laboratory measurements of HFC-13a and compared the spectra with the two HITRAN datasets and with the data from the Pacific Northwest National Laboratory (PNNL). The experimental methods and data analysis techniques are examined and typical sources of errors are discussed. The integrated intensities of the main bands are compared to other literature values. It was found that the integrated absorption cross-section values in the highest range – around 13.8×10 −17 cm.molecule −1 in the 570–1500 cm −1 spectral band – show the most consistency between authors. - Highlights: • Large discrepancies exist between authors on the absorption spectra of HFC-143a. • We present new cross-section spectra of a pure vapour at 263, 273 and 283 K. • The data were compared to literature values. • Total integrated intensities in the highest range are the most consistent. • The radiative efficiency of HFC-143a should be revised upward

  6. UV absorption cross-sections of phenol and naphthalene at temperatures up to 500 degrees C

    DEFF Research Database (Denmark)

    Grosch, Helge; Sárossy, Zsuzsa; Egsgaard, Helge

    2015-01-01

    Absorption cross-sections and their temperature dependency, especially in the UV spectral range, of organic compounds such as phenol and naphthalene are of great interest in atmospheric research and high temperature processes. Due to the challenges of producing premixed gases of known concentration...

  7. Changes of the absorption cross section of Si nanocrystals with temperature and distance

    Czech Academy of Sciences Publication Activity Database

    Greben, M.; Khoroshyy, Petro; Gutsch, S.; Hiller, D.; Zacharias, M.; Valenta, J.

    2017-01-01

    Roč. 8, Nov 6 (2017), s. 2315-2323 ISSN 2190-4286 Institutional support: RVO:61388963 Keywords : absorption cross section * average lifetime * nanocrystal distance * photoluminescence decay * silicon nanocrystals Subject RIV: CF - Physical ; Theoretical Chemistry OBOR OECD: Physical chemistry Impact factor: 3.127, year: 2016 https://www.beilstein-journals.org/bjnano/articles/8/231

  8. Systematic determination of absolute absorption cross-section of individual carbon nanotubes.

    Science.gov (United States)

    Liu, Kaihui; Hong, Xiaoping; Choi, Sangkook; Jin, Chenhao; Capaz, Rodrigo B; Kim, Jihoon; Wang, Wenlong; Bai, Xuedong; Louie, Steven G; Wang, Enge; Wang, Feng

    2014-05-27

    Optical absorption is the most fundamental optical property characterizing light-matter interactions in materials and can be most readily compared with theoretical predictions. However, determination of optical absorption cross-section of individual nanostructures is experimentally challenging due to the small extinction signal using conventional transmission measurements. Recently, dramatic increase of optical contrast from individual carbon nanotubes has been successfully achieved with a polarization-based homodyne microscope, where the scattered light wave from the nanostructure interferes with the optimized reference signal (the reflected/transmitted light). Here we demonstrate high-sensitivity absorption spectroscopy for individual single-walled carbon nanotubes by combining the polarization-based homodyne technique with broadband supercontinuum excitation in transmission configuration. To our knowledge, this is the first time that high-throughput and quantitative determination of nanotube absorption cross-section over broad spectral range at the single-tube level was performed for more than 50 individual chirality-defined single-walled nanotubes. Our data reveal chirality-dependent behaviors of exciton resonances in carbon nanotubes, where the exciton oscillator strength exhibits a universal scaling law with the nanotube diameter and the transition order. The exciton linewidth (characterizing the exciton lifetime) varies strongly in different nanotubes, and on average it increases linearly with the transition energy. In addition, we establish an empirical formula by extrapolating our data to predict the absorption cross-section spectrum for any given nanotube. The quantitative information of absorption cross-section in a broad spectral range and all nanotube species not only provides new insight into the unique photophysics in one-dimensional carbon nanotubes, but also enables absolute determination of optical quantum efficiencies in important

  9. Thermal frequency shift and tunable microwave absorption in BiFeO3 family

    Science.gov (United States)

    Li, Yong; Fang, Xiaoyong; Cao, Maosheng

    2016-04-01

    Tunable frequency is highly sought-after task of researcher, because of the potential for applications in selecting frequency, absorber, imaging and biomedical diagnosis. Here, we report the original observation of thermal frequency shift of dielectric relaxation in La/Nd doped BiFeO3 (BFO) in X-band from 300 to 673 K. It exhibits an unexpected result: the relaxation shifts to lower frequency with increasing temperature. The relaxation maximally shifts about a quarter of X-band. The nonlinear term of lattice vibration plays an important role in the frequency shift. The frequency shift leads to tuning microwave absorption, which almost covers the whole X-band by changing temperature. Meanwhile, the great increase of dielectric loss of La/Nd doped BFO due to thermal excited electron hopping enhances microwave absorption above ~460 and ~480 K, respectively. The microwave absorption of La/Nd doped BFO surpasses -20 dB at 673 K, and the minimum reflection loss of La doped BFO reaches -39 dB. These results open a new pathway to develop BFO-based materials in electromagnetic functional materials and devices for tunable frequency, stealth and thermal imaging at long wavelength.

  10. VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres

    Directory of Open Access Journals (Sweden)

    Venot Olivia

    2014-02-01

    Full Text Available Ultraviolet (UV absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm. Within the studied range of temperature, the CO2 cross section can vary by more than two orders of magnitude. This, in particular, makes the absorption of CO2 significant up to wavelengths as high as 230 nm, while it is negligible above 200 nm at 300 K. To investigate the influence of these new data on the photochemistry of exoplanets, we implemented the measured cross section into a 1D photochemical model. The model predicts that accounting for this temperature dependency of CO2 cross section can affect the computed abundances of NH3, CO2, and CO by one order of magnitude in the atmospheres of hot Jupiter and hot Neptune.

  11. Thermal Neutron Capture Cross Sections of the PalladiumIsotopes

    Energy Technology Data Exchange (ETDEWEB)

    Firestone, R.B.; Krticka, M.; McNabb, D.P.; Sleaford, B.; Agvaanluvsan, U.; Belgya, T.; Revay, Zs.

    2006-07-17

    Precise gamma-ray thermal neutron capture cross sectionshave been measured at the Budapest Reactor for all elements withZ=1-83,92 except for He and Pm. These measurements and additional datafrom the literature been compiled to generate the Evaluated Gamma-rayActivation File (EGAF), which is disseminated by LBNL and the IAEA. Thesedata are nearly complete for most isotopes with Z<20 so the totalradiative thermal neutron capture cross sections can be determineddirectly from the decay scheme. For light isotopes agreement with therecommended values is generally satisfactory although large discrepanciesexist for 11B, 12,13C, 15N, 28,30Si, 34S, 37Cl, and 40,41K. Neutroncapture decay data for heavier isotopes are typically incomplete due tothe contribution of unresolved continuum transitions so only partialradiative thermal neutron capture cross sections can be determined. Thecontribution of the continuum to theneutron capture decay scheme arisesfrom a large number of unresolved levels and transitions and can becalculated by assuming that the fluctuations in level densities andtransition probabilities are statistical. We have calculated thecontinuum contribution to neutron capture decay for the palladiumisotopes with the Monte Carlo code DICEBOX. These calculations werenormalized to the experimental cross sections deexciting low excitationlevels to determine the total radiative thermal neutron capture crosssection. The resulting palladium cross sections values were determinedwith a precision comparable to the recommended values even when only onegamma-ray cross section was measured. The calculated and experimentallevel feedings could also be compared to determine spin and parityassignments for low-lying levels.

  12. Revised ultraviolet absorption cross sections of H2CO for the HITRAN database

    International Nuclear Information System (INIS)

    Chance, K.; Orphal, J.

    2011-01-01

    A revised set of temperature-dependent absorption cross sections for ultraviolet (UV) measurements of formaldehyde (H 2 CO) has been derived from two existing sets of laboratory cross sections, one using a Fourier transform spectrometer (FTS), and one using a grating instrument. This is conducted to satisfy the recommendation of the HITRAN Advisory Committee to provide a dataset with the spectral resolution and wavelength calibration of Fourier transform spectrometer measurements with the better intensity calibration that the grating measurements obtained. The re-scaled cross sections are now in the HITRAN database, and are recommended for use in atmospheric measurements and modeling, including photolysis calculations.

  13. Elastic and absorption cross sections for electron-hydroxyl radical collisions

    International Nuclear Information System (INIS)

    Sobrinho, A.M.C.; Lozano, N.B.H.; Lee, M.-T.

    2004-01-01

    In this work, we report a theoretical study on electron collisions with OH radicals in the low and intermediate energy ranges. Calculated elastic differential, integral, and momentum-transfer cross sections as well as grand-total (elastic + inelastic) and total absorption cross sections for electron-OH collisions are reported in the 1-500-eV range. A complex optical potential composed by static, exchange, correlation-polarization plus absorption contributions, derived from a fully molecular wave function, is used to describe the interaction dynamics. The Schwinger variational iterative method combined with the distorted-wave approximation is applied to calculate scattering amplitudes. Present calculated results are compared with the existing data for electron-OH scattering in the literature. Also, comparison made between our calculated cross sections for elastic scattering with the theoretical and experimental results for electron-H 2 O collisions has revealed remarkable similarity even at incident energies as low as 2 eV

  14. O2 absorption cross sections /187-225 nm/ from stratospheric solar flux measurements

    Science.gov (United States)

    Herman, J. R.; Mentall, J. E.

    1982-10-01

    The absorption cross sections of molecular oxygen are calculated in the wavelength range from 187 to 230 nm from solar flux measurements obtained within the stratosphere. Within the Herzberg continuum wavelength region the molecular oxygen cross sections are found to be about 30% smaller than the laboratory results of Shardanand and Rao (1977) from 200 to 210 nm and about 50% smaller than those of Hasson and Nicholls (1971). At wavelengths longer than 210 nm the cross sections agree with those of Shardanand and Rao. The effective absorption cross sections of O2 in the Schumann-Runge band region from 187 to 200 nm are calculated and compared to the empirical fit given by Allen and Frederick (1982). The calculated cross sections indicate that the transmissivity of the atmosphere may be underestimated by the use of the Allen and Frederic cross sections between 195 and 200 nm. The ozone column content between 30 and 40 km and the relative ozone cross sections are determined from the same solar flux data set.

  15. Study of thermal treatments and irradiation on natural amethyst by optical absorption

    International Nuclear Information System (INIS)

    Dotto, C.T.

    1987-01-01

    Thermal treatment effects on the samples of amethyst from Minas Gerais and Rio Grande do Sul, through optical absorption measurements, are studied. The effects of cobalt 60 gama ray radiation on the amethyst from Minas Gerais through optical absorption measurements, are studied. The optical absorption spectra shows a basic line and bands in 10,500 cm -1 (k), in 18,300 cm -1 (θ) and in 28,000 cm -1 (ζ). The correlation between thermal treatment effects and radiation effects shows that the θ and ζ bands belongs to a same center and the k band to another center. The basic line vanishes by thermal treatments at 270 0 C. The analyses of the isothermal treatment decay and dose-curve reveal a complex kinetics, suggesting that the kinetic mechanisms involve the electron (s) and hole (s) migration in the lattice. The amethyst from Minas Gerais after being discolored at 470 0 C and irradiated again shows that the optical absorption bands don't recover the original absorbance, suggesting the existence of iron diffusion mechanisms in the lattice. After being isothermally annealed the amethyst from Rio Grande do Sul above 400 0 C temperature yield a yellow-brown color, probably due to the formation of Fe 2 O 3 precipitate. We suggest the this formation is due to iron diffusion and pre-existent oxygen vacancies. This model is reinforced through the observation the amethyst from Minas Gerais, isothermally treated at 470 0 C in highly reducing, also gets a yellow-brown color. (author) [pt

  16. UV absorption cross-sections of selected sulfur-containing compounds at temperatures up to 500°C

    DEFF Research Database (Denmark)

    Grosch, Helge; Fateev, Alexander; Clausen, Sønnik

    2015-01-01

    The temperature dependence of the ultraviolet absorption cross-sections of three different sulfur containing compounds, hydrogen sulfide (H2S), carbon disulfide (CS2) and carbonyl sulfide (OCS), are presented between 200nm and 360nm at a resolution of 0.018nm. The absorption cross-sections for ea...

  17. Determination of absorption coefficient based on laser beam thermal blooming in gas-filled tube.

    Science.gov (United States)

    Hafizi, B; Peñano, J; Fischer, R; DiComo, G; Ting, A

    2014-08-01

    Thermal blooming of a laser beam propagating in a gas-filled tube is investigated both analytically and experimentally. A self-consistent formulation taking into account heating of the gas and the resultant laser beam spreading (including diffraction) is presented. The heat equation is used to determine the temperature variation while the paraxial wave equation is solved in the eikonal approximation to determine the temporal and spatial variation of the Gaussian laser spot radius, Gouy phase (longitudinal phase delay), and wavefront curvature. The analysis is benchmarked against a thermal blooming experiment in the literature using a CO₂ laser beam propagating in a tube filled with air and propane. New experimental results are presented in which a CW fiber laser (1 μm) propagates in a tube filled with nitrogen and water vapor. By matching laboratory and theoretical results, the absorption coefficient of water vapor is found to agree with calculations using MODTRAN (the MODerate-resolution atmospheric TRANsmission molecular absorption database) and HITRAN (the HIgh-resolution atmospheric TRANsmission molecular absorption database).

  18. On the contradiction between the microscopic and integral data for fast neutron absorption cross-section for 238U nuclei

    International Nuclear Information System (INIS)

    Van'kov, A.A.

    1994-01-01

    The contradiction between a measured integral neutron absorption cross-section averaged over a fast reactor spectrum and the corresponding value which was calculated with the use of evaluated microscopic cross-sections and a theoretical neutron spectrum has been investigated. The possible systematic error of a correction factor which takes into account multiple resonance neutron scattering in samples used in the measurement of the absorption cross-section is investigated. It is proposed that this error may be one of the main reason for the contradiction mentioned above which arises in the measurement of the 236 U neutron absorption cross-section. (author). 13 refs, 3 figs

  19. Thermal neutron scattering cross sections of beryllium and magnesium oxides

    International Nuclear Information System (INIS)

    Al-Qasir, Iyad; Jisrawi, Najeh; Gillette, Victor; Qteish, Abdallah

    2016-01-01

    Highlights: • Neutron thermalization in BeO and MgO was studied using Ab initio lattice dynamics. • The BeO phonon density of states used to generate the current ENDF library has issues. • The BeO cross sections can provide a more accurate ENDF library than the current one. • For MgO an ENDF library is lacking: a new accurate one can be built from our results. • BeO is a better filter than MgO, especially when cooled down to 77 K. - Abstract: Alkaline-earth beryllium and magnesium oxides are fundamental materials in nuclear industry and thermal neutron scattering applications. The calculation of the thermal neutron scattering cross sections requires a detailed knowledge of the lattice dynamics of the scattering medium. The vibrational properties of BeO and MgO are studied using first-principles calculations within the frame work of the density functional perturbation theory. Excellent agreement between the calculated phonon dispersion relations and the experimental data have been obtained. The phonon densities of states are utilized to calculate the scattering laws using the incoherent approximation. For BeO, there are concerns about the accuracy of the phonon density of states used to generate the current ENDF/B-VII.1 libraries. These concerns are identified, and their influences on the scattering law and inelastic scattering cross section are analyzed. For MgO, no up to date thermal neutron scattering cross section ENDF library is available, and our results represent a potential one for use in different applications. Moreover, the BeO and MgO efficiencies as neutron filters at different temperatures are investigated. BeO is found to be a better filter than MgO, especially when cooled down, and cooling MgO below 77 K does not significantly improve the filter’s efficiency.

  20. Predicting Shielding Effectiveness of Populated Enclosures Using Absorption Cross Section of PCBs

    OpenAIRE

    Parker, Sarah L; Flintoft, Ian D; Marvin, Andy C; Dawson, John F; Bale, Simon J; Robinson, Martin P; Ye, Ming; Wan, Changyong; Zhang, Mengze

    2016-01-01

    Shielding effectiveness (SE) is an important measure of how well an enclosure reduces the electromagnetic (EM) field incident upon it. Commonly, when the shielding effectiveness of an enclosure is stated it is for the case when the enclosure is empty. Including contents such as printed circuit boards (PCBs) in the enclosure will affect the shielding effectiveness as the PCB absorbs EM energy. One technique of determining how much energy a PCB absorbs is to measure its absorption cross section...

  1. Hydrogen peroxide vapor cross sections: A flow cell study using laser absorption in the near infrared

    Science.gov (United States)

    Rhodes, B. L.; Ronney, P. D.; DeSain, J. D.

    2018-01-01

    The absorption spectra of vapors of concentrated hydrogen peroxide/water mixtures (without a carrier gas) were characterized at wavelengths from 1390 to 1470 nm utilizing a near-infrared diode laser. Low pressures were employed to examine these spectral features near the Doppler-broadened limit. An advantageous portion of the spectra near 1420 nm containing several distinct H2O2 peaks and one well-known H2O peak (for calibration) was identified and the cross-sections of these peaks determined. These cross section values can be employed to measure vapor-phase concentrations of H2O2 in propulsion, atmospheric chemistry, and sterilization applications.

  2. Effects of water-absorption and thermal drift on a polymeric photonic crystal slab sensor

    DEFF Research Database (Denmark)

    Sørensen, Kristian Tølbøl; Ingvorsen, Charlotte Bonde; Nielsen, Line Hagner

    2018-01-01

    of resonant reflection during absorption, by monitoring the release of water using ellipsometry, and by rigorous coupled-wave analysis (RCWA). The approach presented here enables monitoring of water uptake and thermal fluctuations, for drift-free, high-performance operation of a polymeric PCS sensor....... with additional challenges, besides those relating to temperature-variations, which must be considered in any refractive index based method: The polymeric waveguide core was found to swell by ?0.3% as water absorbed into the waveguide core over ?1.5 h. This was investigated by monitoring the wavelength...

  3. Moisture absorption characteristics of the Orbiter thermal protection system and methods used to prevent water ingestion

    Science.gov (United States)

    Schomburg, C.; Dotts, R. L.; Tillian, D. J.

    1983-01-01

    The Space Shuttle Orbiter's silica tile Thermal Protection System (TPS) is beset by the moisture absorption problems inherently associated with low density, highly porous insulation systems. Attention is presently given to the comparative success of methods for the minimization and/or prevention of water ingestion by the TPS tiles, covering the development of water-repellent agents and their tile application techniques, flight test program results, and materials improvements. The use of external films for rewaterproofing of the TPS tiles after each mission have demonstrated marginal to unacceptable performance. By contrast, a tile interior waterproofing agent has shown promise.

  4. Research of waste heat energy efficiency for absorption heat pump recycling thermal power plant circulating water

    Science.gov (United States)

    Zhang, Li; Zhang, Yu; Zhou, Liansheng; E, Zhijun; Wang, Kun; Wang, Ziyue; Li, Guohao; Qu, Bin

    2018-02-01

    The waste heat energy efficiency for absorption heat pump recycling thermal power plant circulating water has been analyzed. After the operation of heat pump, the influences on power generation and heat generation of unit were taken into account. In the light of the characteristics of heat pump in different operation stages, the energy efficiency of heat pump was evaluated comprehensively on both sides of benefits belonging to electricity and benefits belonging to heat, which adopted the method of contrast test. Thus, the reference of energy efficiency for same type projects was provided.

  5. Pressure Measurement in Supersonic Air Flow by Differential Absorptive Laser-Induced Thermal Acoustics

    Science.gov (United States)

    Hart, Roger C.; Herring, Gregory C.; Balla, Robert J.

    2007-01-01

    Nonintrusive, off-body flow barometry in Mach-2 airflow has been demonstrated in a large-scale supersonic wind tunnel using seedless laser-induced thermal acoustics (LITA). The static pressure of the gas flow is determined with a novel differential absorption measurement of the ultrasonic sound produced by the LITA pump process. Simultaneously, stream-wise velocity and static gas temperature of the same spatially-resolved sample volume were measured with this nonresonant time-averaged LITA technique. Mach number, temperature and pressure have 0.2%, 0.4%, and 4% rms agreement, respectively, in comparison with known free-stream conditions.

  6. Mercury speciation in environmental solid samples using thermal release technique with atomic absorption detection

    Energy Technology Data Exchange (ETDEWEB)

    Shuvaeva, Olga V. [Institute of Inorganic Chemistry, Academician Lavrent' ev Prospect 3, 630090 Novosbirsk (Russian Federation)], E-mail: olga@che.nsk.su; Gustaytis, Maria A.; Anoshin, Gennadii N. [Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug Prospect 3, 630090 Novosibirsk (Russian Federation)

    2008-07-28

    A sensitive and very simple method for determination of mercury species in solid samples has been developed involving thermal release analysis in combination with atomic absorption (AAS) detection. The method allows determination of mercury(II) chloride, methylmercury and mercury sulfide at the level of 0.70, 0.35 and 0.20 ng with a reproducibility of the results of 14, 25 and 18%, respectively. The accuracy of the developed assay has been estimated using certified reference materials and by comparison of the results with those of an independent method. The method has been applied for Hg species determination in original samples of lake sediments and plankton.

  7. Effect of drying method on mechanical, thermal and water absorption properties of enzymatically crosslinked gelatin hydrogels

    Directory of Open Access Journals (Sweden)

    RAYSSA C. SIMONI

    Full Text Available ABSTRACT Enzymatically crossliked gelatin hydrogel was submitted to two different drying methods: air drying and freeze drying. The resulting polymeric tridimensional arrangement (compact or porous, respectively led to different thermal and swelling properties. Significant differences (p < 0.05 on thermal and mechanical characteristics as well as swelling in non-enzymatic gastric and intestinal simulated fluids (37 ºC were detected. Water absorption data in such media was modelled according to Higuchi, Korsmeyer-Peppas, and Peppas-Sahlin equations. Freeze dried hydrogel showed Fickian diffusion behavior while air dried hydrogels presented poor adjustment to Higuchi model suggesting the importance of the relaxation mechanism at the beginning of swelling process. It was possible to conclude that the same gelatin hydrogel may be suitable to different applications depending on the drying process used.

  8. Investigation of anisotropic thermal transport in cross-linked polymers

    Science.gov (United States)

    Simavilla, David Nieto

    Thermal transport in lightly cross-linked polyisoprene and polybutadine subjected to uniaxial elongation is investigated experimentally. We employ two experimental techniques to assess the effect that deformation has on this class of materials. The first technique, which is based on Forced Rayleigh Scattering (FRS), allows us to measure the two independent components of the thermal diffusivity tensor as a function of deformation. These measurements along with independent measurements of the tensile stress and birefringence are used to evaluate the stress-thermal and stress-optic rules. The stress-thermal rule is found to be valid for the entire range of elongations applied. In contrast, the stress-optic rule fails for moderate to large stretch ratios. This suggests that the degree of anisotropy in thermal conductivity depends on both orientation and tension in polymer chain segments. The second technique, which is based on infrared thermography (IRT), allows us to measure anisotropy in thermal conductivity and strain induced changes in heat capacity. We validate this method measurements of anisotropic thermal conductivity by comparing them with those obtained using FRS. We find excellent agreement between the two techniques. Uncertainty in the infrared thermography method measurements is estimated to be about 2-5 %. The accuracy of the method and its potential application to non-transparent materials makes it a good alternative to extend current research on anisotropic thermal transport in polymeric materials. A second IRT application allows us to investigate the dependence of heat capacity on deformation. We find that heat capacity increases with stretch ratio in polyisoprene specimens under uniaxial extension. The deviation from the equilibrium value of heat capacity is consistent with an independent set of experiments comparing anisotropy in thermal diffusivity and conductivity employing FRS and IRT techniques. We identify finite extensibility and strain

  9. Shape dependency of the extinction and absorption cross sections of dust aerosols modeled as randomly oriented spheroids

    Directory of Open Access Journals (Sweden)

    R. Wagner

    2011-09-01

    Full Text Available We present computational results on the shape dependency of the extinction and absorption cross sections of dustlike aerosol particles that were modeled as randomly oriented spheroids. Shape dependent variations in the extinction cross sections are largest in the size regime that is governed by the interference structure. Elongated spheroids best fitted measured extinction spectra of re-dispersed Saharan dust samples. For dust particles smaller than 1.5 μm in diameter and low absorption potential, shape effects on the absorption cross sections are very small.

  10. Optical Absorption and Photo-Thermal Conversion Properties of CuO/H2O Nanofluids.

    Science.gov (United States)

    Wang, Liangang; Wu, Mingyan; Wu, Daxiong; Zhang, Canying; Zhu, Qunzhi; Zhu, Haitao

    2015-04-01

    Stable CuO/H2O nanofluids were synthesized in a wet chemical method. Optical absorption property of CuO/H2O nanofluids was investigated with hemispheric transmission spectrum in the wavelength range from 200 nm to 2500 nm. Photo-thermal conversion property of the CuO/H2O nanofluids was studied with an evaluation system equipped with an AUT-FSL semiconductor/solid state laser. The results indicate that CuO/H2O nanofluids have strong absorption in visible light region where water has little absorption. Under the irradiation of laser beam with a wavelength of 635 nm and a power of 0.015 W, the temperature of CuO/H2O nanofluids with 1.0% mass fraction increased by 5.6 °C within 40 seconds. Furthermore, the temperature elevation of CuO/H2O nanofluids was proved to increase with increasing mass fractions. On the contrast, water showed little temperature elevation under the identical conditions. The present work shows that the CuO/H2O nanofluids have high potential in the application as working fluids for solar utilization purpose.

  11. Thermal neutron cross section measurements for technetium-99

    International Nuclear Information System (INIS)

    Yates, M.A.; Schroeder, N.C.; Fowler, M.M.

    1993-01-01

    Technetium, because of its long half-like (213,000 years) and ability to migrate in the environment, is a primary contributor to the long-term radioactivity related risk associated with geologic nuclear waste disposal. One proposal for converting technetium to an environmentally benign element investigating transmutation with an accelerator-based system, (i.e., Accelerator Transmutation of Waste, ATW). Planning for efficient processing of technetium through the transmuter will require knowledge of the thermal neutron cross section for the 99 Tc (n,γ) 100 Tc reaction. The authors have recently remeasured this cross section. Weighed aliquots (19-205 μg) of a NIST traceable 99 Tc standard were irradiated for 30-150 sec using the pneumatic open-quotes rabbitclose quotes system of LANL's Omega West Reactor. The two gamma rays from the 15.7-sec half-life product were measured immediately after irradiation on a high-resolution Ge detector. Thermal fluxes were measured using gold foils and Cd wrapped gold foils. The observation cross section is 19 ± 1 b. This agrees well with the 1977 value but has half the uncertainty

  12. Compton energy-absorption scattering cross-sections for H, C, N, O, P, Ca and assessment of doppler broadening

    CERN Document Server

    Rao, D V; Brunetti, A; Gigante, G E

    2003-01-01

    Total Compton, individual shell and Compton energy-absorption scattering cross-sections are evaluated in the energy region 0.005 to 10 MeV for H, C. N, O. P and Ca. Compton energy absorption cross-sections deviate numerically with available values. The cause of the numerical discrepancies are not fully understood but can be attributed to Doppler broadening of the Compton scattered photons through a given angle. (authors)

  13. Thermal properties, curing characteristics and water absorption of soybean oil-based thermoset

    Directory of Open Access Journals (Sweden)

    2011-06-01

    Full Text Available Epoxidized soybean oil (ESO was successfully thermal-cured by using methylhexahydrophthalic anhydride (MHHPA curing agent, in the presence of tetraethylammonium bromide (TEAB catalyst of varied concentration (0.3–0.8 phr. The polyesterification process of ESO thermoset was proven and supported by Fourier transforms infrared spectroscopy (FTIR and gas chromatography-mass spectroscopy analysis (GC-MS. A possible chemical reaction of the MHHPA, TEAB and ESO was proposed based on the experimental work. Differential scanning calorimetry (DSC and dynamic mechanical analysis (DMA revealed that there is a positive relationship between the degree of conversion and crosslink density of ESO thermoset with TEAB concentration. The kinetics of water absorption of the ESO thermoset were found to conform to Fickian law behavior.

  14. Improved Neutron Capture Cross Section Measurements with the n_TOF Total Absorption Calorimeter

    CERN Document Server

    Mendoza, E; Perkowski, J; Andriamonje, S; Carrapico, C; Moinul, M; Vannini, G; Quesada, J M; Harrisopulos, S; Milazzo, P M; Berthier, B; Lozano, M; Krticka, M; Domingo-Pardo, C; Nolte, R; Chiaveri, E; Saarmento, H; Jericha, E; Ferrari, A; Massimi, C; Giubrone, G; Avrigeanu, V; Martinez, T; Guerrero, C; Andrzejewski, J; Karadimos, D; Mengoni, A; Ganesan, S; Vlachoudis, V; Becares, V; Cortes, G; Variale, V; Losito, H; Calvino, F; Kappeler, F; Gunsing, F; Gramegna, F; Colonna, N; Marrone, S; Pavlik, A; Berthoumieux, E; Paradela, C; Mastinu, P F; Vaz, P; Tassan-Got, L; Kadi, Y; Tarrio, D; Cano-Ott, D; Brugger, M; Wallner, A; Audouin, L; Fernandez-Ordonez, M; Becvar, F; Goncalves, I F; Cerutti, F; Ventura, A; Mosconi, M; Tagliente, G; Duran, I; Casado, A; Ioannides, K; Weiss, C; Mirea, M; Gomez-Hornillos, M B; Vlastou, R; Calviani, M; Lederer, C; Gonzalez-Romero, E; Marganiec, J; Vidriales, J J; Lebbos, E; Leeb, H; Heil, M; Dillmann, I; Tain, J L; Belloni, F

    2011-01-01

    The n\\_TOF collaboration operates a Total Absorption Calorimeter (TAC) {[}1] for measuring neutron capture cross-sections of low-mass and/or radioactive samples. The results obtained with the TAC have led to a substantial improvement of the capture cross sections of (237)Np and (240)Pu {[}2]. The experience acquired during the first measurements has allowed us to optimize the performance of the TAC and to improve the capture signal to background ratio, thus opening the way to more complex and demanding measurements on rare radioactive materials. The new design has been reached by a series of detailed Monte Carlo simulations of complete experiments and dedicated test measurements. The new capture setup will be presented and the main achievements highlighted.

  15. A LiBr-H2O Absorption Refrigerator Incorporating a Thermally Activated Solution Pumping Mechanism

    Directory of Open Access Journals (Sweden)

    Ian W. Eames

    2017-02-01

    Full Text Available This paper provides an illustrated description of a proposed LiBr-H2O vapour absorption refrigerator which uses a thermally activated solution pumping mechanism that combines controlled variations in generator vapour pressure with changes it produces in static-head pressure difference to circulate the absorbent solution between the generator and absorber vessels. The proposed system is different and potentially more efficient than a bubble pump system previously proposed and avoids the need for an electrically powered circulation pump found in most conventional LiBr absorption refrigerators. The paper goes on to provide a sample set of calculations that show that the coefficient of performance values of the proposed cycle are similar to those found for conventional cycles. The theoretical results compare favourably with some preliminary experimental results, which are also presented for the first time in this paper. The paper ends by proposing an outline design for an innovative steam valve, which is a key component needed to control the solution pumping mechanism.

  16. High resolution absorption cross-sections and band oscillator strengths of the Schumann-Runge absorption bands of isotopic oxygen, (0-16)(0-18), at 79 K

    Science.gov (United States)

    Yoshino, K.; Freeman, D. E.; Esmond, J. R.; Friedman, R. S.; Parkinson, W. H.

    1989-01-01

    Cross-sections of (0-16)(0-18) at 79 K have been obtained from photoabsorption measurements on mixtures of (0-16)2, (0-18)2, and (0-16)(0-18) at various pressures throughout the wavelength region 180.5-195.3 nm with a 6.65 m photoelectric scanning spectrometer equipped with a 2400 lines/mm grating and having an instrumental width (FWHM) of 0.0013 nm. The measured absorption cross-sections of the (0-16)(0-18) Schumann-Runge bands (11.0)-(3.0) are independent of the instrumental width. The measured cross-sections are presented graphically.

  17. Absorption cross-sections of ozone in the ultraviolet and visible spectral regions: Status report 2015

    Science.gov (United States)

    Orphal, Johannes; Staehelin, Johannes; Tamminen, Johanna; Braathen, Geir; De Backer, Marie-Renée; Bais, Alkiviadis; Balis, Dimitris; Barbe, Alain; Bhartia, Pawan K.; Birk, Manfred; Burkholder, James B.; Chance, Kelly; von Clarmann, Thomas; Cox, Anthony; Degenstein, Doug; Evans, Robert; Flaud, Jean-Marie; Flittner, David; Godin-Beekmann, Sophie; Gorshelev, Viktor; Gratien, Aline; Hare, Edward; Janssen, Christof; Kyrölä, Erkki; McElroy, Thomas; McPeters, Richard; Pastel, Maud; Petersen, Michael; Petropavlovskikh, Irina; Picquet-Varrault, Benedicte; Pitts, Michael; Labow, Gordon; Rotger-Languereau, Maud; Leblanc, Thierry; Lerot, Christophe; Liu, Xiong; Moussay, Philippe; Redondas, Alberto; Van Roozendael, Michel; Sander, Stanley P.; Schneider, Matthias; Serdyuchenko, Anna; Veefkind, Pepijn; Viallon, Joële; Viatte, Camille; Wagner, Georg; Weber, Mark; Wielgosz, Robert I.; Zehner, Claus

    2016-09-01

    The activity "Absorption Cross-Sections of Ozone" (ACSO) started in 2008 as a joint initiative of the International Ozone Commission (IO3C), the World Meteorological Organization (WMO) and the IGACO ("Integrated Global Atmospheric Chemistry Observations") O3/UV subgroup to study, evaluate, and recommend the most suitable ozone absorption cross-section laboratory data to be used in atmospheric ozone measurements. The evaluation was basically restricted to ozone absorption cross-sections in the UV range with particular focus on the Huggins band. Up until now, the data of Bass and Paur published in 1985 (BP, 1985) are still officially recommended for such measurements. During the last decade it became obvious that BP (1985) cross-section data have deficits for use in advanced space-borne ozone measurements. At the same time, it was recognized that the origin of systematic differences in ground-based measurements of ozone required further investigation, in particular whether the BP (1985) cross-section data might contribute to these differences. In ACSO, different sets of laboratory ozone absorption cross-section data (including their dependence on temperature) of the group of Reims (France) (Brion et al., 1993, 1998, 1992, 1995, abbreviated as BDM, 1995) and those of Serdyuchenko et al. (2014), and Gorshelev et al. (2014), (abbreviated as SER, 2014) were examined for use in atmospheric ozone measurements in the Huggins band. In conclusion, ACSO recommends: The spectroscopic data of BP (1985) should no longer be used for retrieval of atmospheric ozone measurements. For retrieval of ground-based instruments of total ozone and ozone profile measurements by the Umkehr method performed by Brewer and Dobson instruments data of SER (2014) are recommended to be used. When SER (2014) is used, the difference between total ozone measurements of Brewer and Dobson instruments are very small and the difference between Dobson measurements at AD and CD wavelength pairs are diminished

  18. Corneal Absorption of a New Riboflavin-Nanostructured System for Transepithelial Collagen Cross-Linking

    Science.gov (United States)

    Bottos, Katia M.; Oliveira, Anselmo G.; Bersanetti, Patrícia A.; Nogueira, Regina F.; Lima-Filho, Acácio A. S.; Cardillo, José A.; Schor, Paulo; Chamon, Wallace

    2013-01-01

    Corneal collagen cross-linking (CXL) has been described as a promising therapy for keratoconus. According to standard CXL protocol, epithelium should be debrided before treatment to allow penetration of riboflavin into the corneal stroma. However, removal of the epithelium can increase procedure risks. In this study we aim to evaluate stromal penetration of a biocompatible riboflavin-based nanoemulsion system (riboflavin-5-phosphate and riboflavin-base) in rabbit corneas with intact epithelium. Two riboflavin nanoemulsions were developed. Transmittance and absorption coefficient were measured on corneas with intact epithelia after 30, 60, 120, 180, and 240 minutes following exposure to either the nanoemulsions or standard 0.1% or 1% riboflavin-dextran solutions. For the nanoemulsions, the epithelium was removed after measurements to assure that the riboflavin had passed through the hydrophobic epithelium and retained within the stroma. Results were compared to de-epithelialized corneas exposed to 0.1% riboflavin solution and to the same riboflavin nanoemulsions for 30 minutes (standard protocol). Mean transmittance and absorption measured in epithelialized corneas receiving the standard 0.1% riboflavin solution did not reach the levels found on the debrided corneas using the standard technique. Neither increasing the time of exposure nor the concentration of the riboflavin solution from 0.1% to 1% improved riboflavin penetration through the epithelium. When using riboflavin-5-phosphate nanoemulsion for 240 minutes, we found no difference between the mean absorption coefficients to the standard cross-linking protocol (p = 0.54). Riboflavin nanoemulsion was able to penetrate the corneal epithelium, achieving, after 240 minutes, greater stromal concentration when compared to debrided corneas with the standard protocol (p = 0.002). The riboflavin-5-phosphate nanoemulsion diffused better into the stroma than the riboflavin-base nanoemulsion. PMID:23785497

  19. Determination of Scattering and Absorption Coefficients for Plasma-Sprayed Yttria-Stabilized Zirconia Thermal Barrier Coatings at Elevated Temperatures

    Science.gov (United States)

    Eldridge, Jeffrey I.; Spuckler, Charles M.; Markham, James R.

    2009-01-01

    The temperature dependence of the scattering and absorption coefficients for a set of freestanding plasma-sprayed 8 wt% yttria-stabilized zirconia (8YSZ) thermal barrier coatings (TBCs) was determined at temperatures up to 1360 C in a wavelength range from 1.2 micrometers up to the 8YSZ absorption edge. The scattering and absorption coefficients were determined by fitting the directional-hemispherical reflectance and transmittance values calculated by a four-flux Kubelka Munk method to the experimentally measured hemispherical-directional reflectance and transmittance values obtained for five 8YSZ thicknesses. The scattering coefficient exhibited a continuous decrease with increasing wavelength and showed no significant temperature dependence. The scattering is primarily attributed to the relatively temperature-insensitive refractive index mismatch between the 8YSZ and its internal voids. The absorption coefficient was very low (less than 1 per centimeter) at wavelengths between 2 micrometers and the absorption edge and showed a definite temperature dependence that consisted of a shift of the absorption edge to shorter wavelengths and an increase in the weak absorption below the absorption edge with increasing temperature. The shift in the absorption edge with temperature is attributed to strongly temperature-dependent multiphonon absorption. While TBC hemispherical transmittance beyond the absorption edge can be predicted by a simple exponential decrease with thickness, below the absorption edge, typical TBC thicknesses are well below the thickness range where a simple exponential decrease in hemispherical transmittance with TBC thickness is expected. [Correction added after online publication August 11, 2009: "edge to a shorter wavelengths" has been updated as edge to shorter wavelengths."

  20. Heavy nuclei resonant absorption in heterogeneous lattices. III - Self-shielding qualification in the thermal range

    International Nuclear Information System (INIS)

    Tellier, Henry; Van Der Gucht, Catherine; Mengelle, Stephane; Coste, Mireille; Andrieux, Chantal

    1995-03-01

    With the new self-shielding formalism which is implemented in the transport code APOLLO2, it is possible to compute the heavy nuclei absorption in a fuel element as a function of space and energy, for both epithermal and thermal ranges. The purpose of this study is the self-shielding qualification for the thermal range resonances of importance in reactor physics. For this, we made, in a source calculation, a comparison between the APOLLO2 results and the ones of a continuous energy calculation and of a very fine mesh multigroup computation. In the case of plutonium 240, plutonium 242 and indium 115, the agreements between the three calculations are very satisfactory for a homogeneous medium as well as for the heterogeneous geometry of a pressurized water reactor cell. In any case the difference between the self-shielding computation and the reference ones is lower than one per cent. Transposed to a reactor core, this discrepancy leads to a negligible reactivity effect. (author) [fr

  1. The determination of kinetic parameters of LiF : Mg,Ti from thermal decaying curves of optical absorption bands

    CERN Document Server

    Yazici, A N

    2003-01-01

    In this paper, the thermal bleaching curves (TBCs) of specific optical absorption bands of LiF : Mg,Ti were measured as a function of temperature. The TBCs obtained were analysed to extract the kinetic parameters (the thermal activation energy (E) and the frequency factor (s)) of some TL glow peaks of LiF : Mg,Ti on the basis of the developed first-order kinetic model over a specified temperature region.

  2. Thermal Performance Analysis of Staging Effect of Solar Thermal Absorber with Cross Design

    International Nuclear Information System (INIS)

    Amir Abdul Razak; Zafri Azran Abdul Majid; Mohd Hafidz Ruslan; Kamaruzzaman Sopian

    2015-01-01

    The type and shape of solar thermal absorber materials will impact on the operating temperature and thermal energy storage effect of a solar air thermal collector. For a standard flat-plate design, energy gain can be increased by expanding the thermal absorber area along the collector plane, subject to area limitation. This paper focuses on the staging effect of a metal hollow square rod absorber of aluminium, stainless steel, and a combination of the two with a cross design, for the heat gain and temperature characteristics of a solar air collector. Experiments were carried out with three cross design set-ups, with 30 minutes of heating and cooling, phase, respectively, under 485 W/ m 2 solar irradiance value, and at a constant air speed at 0.38 m/ s. One set aluminium set-up delivered the highest output temperature of 41.8 degree Celsius, followed by two-sets aluminium and one aluminium set + one stainless steel set at 39.3 and 38.2 degree Celsius, respectively. The lowest peak temperature is recorded on three sets of the aluminium absorber at 35 degree Celsius. The bi-metallic set-up performed better than the two aluminium set-up where each set-up obtained a temperature drop against heat gain gradient value of -0.4186 degree Celsius/ W and -0.4917 degree Celsius/ W, respectively. Results concluded that by increasing the number of sets, the volume and surface areas of the absorber material are also increased, and lead to a decrease in peak temperature output for each increase of sets. (author)

  3. Thermal modeling of a novel thermosyphonic waste heat absorption system for internal combustion engines

    International Nuclear Information System (INIS)

    Nwosu, Paul Nwachukwu; Nuutinen, Mika; Larmi, Martti

    2014-01-01

    This paper investigates a thermal system that absorbs waste heat from an internal combustion (IC) engine in order to raise the temperature of a working fluid to a saturated state using thermosyphonic flow, non-intrusive of the engine operations. The absorbed heat is rejected to an enclosed space, suitable for in-transit drying. The thermal system comprises a cross-flow heat exchanger connected to a radiator which preheats the working fluid from an insulated (storage) tank. The preheated fluid flows through a radiant heat absorber which absorbs radiant heat from the exhaust manifold. To ensure that the system efficiently performs, a temperature differential is maintained by the heated space while the fluid is cyclically delivered to the tank. The system’s operations are described using a novel flow cycle, and the results indicate a significant heat recovery potential. - Highlights: • This paper investigates a thermal system that absorbs waste heat from an internal combustion (IC) engine. • The absorbed heat is used to raise the temperature of a working fluid employing thermosyphonic flow. • The preheated fluid flows through a radiant heat absorber which absorbs radiant heat from the exhaust manifold. • To ensure that the system efficiently performs, a temperature differential is maintained by a heated space. • The system's operations are described using a novel flow cycle

  4. VUV-absorption cross section of carbon dioxide from 150 to 800 K and applications to warm exoplanetary atmospheres

    Science.gov (United States)

    Venot, O.; Bénilan, Y.; Fray, N.; Gazeau, M.-C.; Lefèvre, F.; Es-sebbar, Et.; Hébrard, E.; Schwell, M.; Bahrini, C.; Montmessin, F.; Lefèvre, M.; Waldmann, I. P.

    2018-01-01

    Context. Most exoplanets detected so far have atmospheric temperatures significantly higher than 300 K. Often close to their star, they receive an intense UV photons flux that triggers important photodissociation processes. The temperature dependency of vacuum ultraviolet (VUV) absorption cross sections are poorly known, leading to an undefined uncertainty in atmospheric models. Similarly, data measured at low temperatures similar to those of the high atmosphere of Mars, Venus, and Titan are often lacking. Aims: Our aim is to quantify the temperature dependency of the VUV absorption cross sections of important molecules in planetary atmospheres. We want to provide high-resolution data at temperatures prevailing in these media, and a simple parameterisation of the absorption in order to simplify its use in photochemical models. This study focuses on carbon dioxide (CO2). Methods: We performed experimental measurements of CO2 absorption cross sections with synchrotron radiation for the wavelength range (115-200 nm). For longer wavelengths (195-230 nm), we used a deuterium lamp and a 1.5 m Jobin-Yvon spectrometer. We used these data in our one-dimensional (1D) thermo-photochemical model in order to study their impact on the predicted atmospheric compositions. Results: The VUV absorption cross section of CO2 increases with the temperature. The absorption we measured at 150 K seems to be close to the absorption of CO2 in the fundamental ground state. The absorption cross section can be separated into two parts: a continuum and a fine structure superimposed on the continuum. The variation in the continuum of absorption can be represented by the sum of three Gaussian functions. Using data at high temperature in thermo-photochemical models significantly modifies the abundance and the photodissociation rates of many species in addition to CO2, such as methane and ammonia. These deviations have an impact on synthetic transmission spectra, leading to variations of up to 5 ppm

  5. Comparison of x-ray absorption spectra between water and ice: New ice data with low pre-edge absorption cross-section

    Energy Technology Data Exchange (ETDEWEB)

    Sellberg, Jonas A.; Nilsson, Anders [Department of Physics, AlbaNova University Center, Stockholm University, S-106 91 Stockholm (Sweden); SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Kaya, Sarp [SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Segtnan, Vegard H. [SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Nofima AS, N-1430 Ås (Norway); Chen, Chen [SUNCAT Center for Interface Science and Catalysis, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025 (United States); Department of Chemistry, Stanford University, Stanford, California 94305 (United States); Tyliszczak, Tolek [Advanced Light Source, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Ogasawara, Hirohito; Nordlund, Dennis [Stanford Synchrotron Radiation Lightsource, SLAC National Accelerator Laboratory, P.O. Box 20450, Stanford, California 94309 (United States); Pettersson, Lars G. M. [Department of Physics, AlbaNova University Center, Stockholm University, S-106 91 Stockholm (Sweden)

    2014-07-21

    The effect of crystal growth conditions on the O K-edge x-ray absorption spectra of ice is investigated through detailed analysis of the spectral features. The amount of ice defects is found to be minimized on hydrophobic surfaces, such as BaF{sub 2}(111), with low concentration of nucleation centers. This is manifested through a reduction of the absorption cross-section at 535 eV, which is associated with distorted hydrogen bonds. Furthermore, a connection is made between the observed increase in spectral intensity between 544 and 548 eV and high-symmetry points in the electronic band structure, suggesting a more extended hydrogen-bond network as compared to ices prepared differently. The spectral differences for various ice preparations are compared to the temperature dependence of spectra of liquid water upon supercooling. A double-peak feature in the absorption cross-section between 540 and 543 eV is identified as a characteristic of the crystalline phase. The connection to the interpretation of the liquid phase O K-edge x-ray absorption spectrum is extensively discussed.

  6. Planetary gamma-ray spectroscopy: the effects of hydrogen absorption cross-section of the gamma-ray spectrum

    International Nuclear Information System (INIS)

    Lapides, J.R.

    1981-01-01

    The gamma-ray spectroscopy of planet surfaces is one of several possible methods that are useful in determining the elemental composition of planet surfaces from orbiting spacecraft. This has been demonstrated on the Apollos 15 and 16 missions as well as the Soviet Mars-5 mission. Planetary gamma-ray emission is primarily the result of natural radioactive decay and cosmic-ray and solar-flare-induced nuclear reactions. Secondary neutron reactions play a large role in the more intense gamma-ray emission. The technique provides information on the elemental composition of the top few tens of centimeters of the planet surface. Varying concentrations of hydrogen and compositional variations that alter the macroscopic thermal-neutron absorption cross section have a significant effect on the neutron flux in the planet surface and therefore also on the gamma-ray emission from the surface. These effects have been systematically studied for a wide range of possible planetary compositions that include Mercury, the moon, Mars, the comets, and the asteroids. The problem of the Martian atmosphere was also investigated. The results of these calculations, in which both surface neutron fluxes and gamma-ray emission fluxes were determined, were used to develop general procedures for obtaining planet compositions from the gamma-ray spectrum. Several changes have been suggested for reanalyzing the Apollos 15 and 16 gamma-ray results. In addition, procedures have been suggested that can be applied to neutron-gamma techniques in mineral and oil exploration

  7. Structural, thermal and optical absorption features of heavy metal oxides doped tellurite rich glasses

    Directory of Open Access Journals (Sweden)

    Kawa M. Kaky

    Full Text Available In order to improve tellurite glass stability to be applicable for optical fiber amplifier applications, glasses with the composition of (70 − xTeO2. (10ZnO. (10WO3. (5Na2O. (5TiO2. (xBi2O3 (x = 1, 2, 3, 4, and 5 mol% have been produced and characterized using the related methods. Structural properties were investigated using X-ray diffraction (XRD which confirms the non-crystalline structure and scanning electron microscopy (SEM micrographs also confirm the XRD results. The energy dispersive X-ray (EDX analysis profiles show that all the mentioned elements are present in the prepared glasses. Following the IR spectra, all the tellurium bonds such as stretching vibrations of TeO4 tbp and TeO3/TeO3+1 unit are revealed. Raman spectra confirm the presence of different functional groups, actually, it shows bands mainly in four spectral regions: R1 (65–150 cm−1, R2 (280–550 cm−1, R3 (880–950 cm−1 and R4 (916–926 cm−1 and the identified bands are assigned to respective molecular groups. The thermal study was carried out using Differential scanning calorimetry (DSC which indicates good thermal stability of the synthesized glasses with increasing Bi concentration. From the optical absorption spectra, we evaluated cut-off edge wavelengths and found increasing cutoff wavelength with an increase in Bi2O3 concentration. In the UV–Visible region, optical band gap energy and allowed transitions were investigated using three methods; direct, indirect, and absorption spectrum fitting (ASF, and band gaps from indirect and ASF were matched. Keywords: Tellurite glasses, XRD, FT-IR, Raman, TGA/DSC

  8. High resolution absorption cross-sections and band oscillator strengths of the Schumann-Runge absorption bands of isotopic oxygen, (O-18)2, at 79 K

    Science.gov (United States)

    Yoshino, K.; Freeman, D. E.; Esmond, J. R.; Friedman, R. S.; Parkinson, W. H.

    1988-01-01

    Cross-sections of (O-18)2 at 79 K have been obtained from photoabsorption measurements at various pressures throughout the wavelength region 177.8-197.8 nm with a 6.65 m photoelectric scanning spectrometer equipped with a 2400 lines/mm grating and having an instrumental width (FWHM) of 0.0013 nm. The measured absorption cross-sections of the Schumann-Runge bands (14,0) through (2,0) are, with the exception of the (12,0) band, independent of the instrumental width. The measured cross-sections are presented graphically here and are available at wavenumber intervals of about 0.1/cm as numerical compilations stored on magnetic tape. Band oscillator strengths of those bands have been determined by direct numerical integration of the measured absolute cross-sections and are in excellent agreement with these theoretically calculated values.

  9. Determination of absorption cross-section of Si nanocrystals by two independent methods based on either absorption or luminescence

    Czech Academy of Sciences Publication Activity Database

    Valenta, J.; Greben, M.; Remeš, Zdeněk; Gutsch, S.; Hiller, D.; Zacharias, M.

    2016-01-01

    Roč. 102, č. 2 (2016), 1-5, č. článku 023102. ISSN 0003-6951 R&D Projects: GA ČR(CZ) GA14-05053S; GA MŠk(CZ) LD14011 Institutional support: RVO:68378271 Keywords : photoluminescence * absorption spectroscopy * photothermal spectroscopy * semiconductors * nanocrystals Subject RIV: BM - Solid Matter Physics ; Magnetism Impact factor: 3.411, year: 2016

  10. Thermally activated superradiance and intersystem crossing in the water-soluble chlorophyll binding protein.

    Science.gov (United States)

    Renger, T; Madjet, M E; Müh, F; Trostmann, I; Schmitt, F-J; Theiss, C; Paulsen, H; Eichler, H J; Knorr, A; Renger, G

    2009-07-23

    The crystal structure of the class IIb water-soluble chlorophyll binding protein (WSCP) from Lepidium virginicum is used to model linear absorption and circular dichroism spectra as well as excited state decay times of class IIa WSCP from cauliflower reconstituted with chlorophyll (Chl) a and Chl b. The close agreement between theory and experiment suggests that both types of WSCP share a common Chl binding motif, where the opening angle between pigment planes in class IIa WSCP should not differ by more than 10 degrees from that in class IIb. The experimentally observed (Schmitt et al. J. Phys. Chem. B 2008, 112, 13951) decrease in excited state lifetime of Chl a homodimers with increasing temperature is fully explained by thermally activated superradiance via the upper exciton state of the dimer. Whereas a temperature-independent intersystem crossing (ISC) rate is inferred for WSCP containing Chl a homodimers, that of WSCP with Chl b homodimers is found to increase above 100 K. Our quantum chemical/electrostatic calculations suggest that a thermally activated ISC via an excited triplet state T4 is responsible for the latter temperature dependence.

  11. UV absorption cross-sections of phenol and naphthalene at temperatures up to 500 °C

    Science.gov (United States)

    Grosch, H.; Sárossy, Z.; Egsgaard, H.; Fateev, A.

    2015-05-01

    Absorption cross-sections and their temperature dependency, especially in the UV spectral range, of organic compounds such as phenol and naphthalene are of great interest in atmospheric research and high temperature processes. Due to the challenges of producing premixed gases of known concentration, it is difficult to determine absorption cross-sections in experiments, especially at higher temperatures. In this paper, a gas flow of nitrogen with a stable but unknown concentration of phenol or naphthalene is produced, and their UV absorption spectra between 195 and 350 nm have been measured at higher resolution than before (0.019 nm) in a hot gas flow cell at temperatures of up to 500 °C/773 K. A Petersen column is used to sample the organic compounds in the gas mixture to determine their concentration by GC-MS. The absorption cross-sections are calculated with the use of the Lambert-Beer law. Consequently, the absorption cross-sections for phenol and naphthalene at room temperature, 423 K, 573 K and 773 K in the range of 195-360 nm are presented in this study.

  12. The Tsallis Statistics applied to the calculation of absorption cross section of {sup 238}U, {sup 232}Th and {sup 240}Pu isotopes

    Energy Technology Data Exchange (ETDEWEB)

    Guedes, Guilherme, E-mail: gguedes.cefet@gmail.com [Centro Federal de Educacao Tecnologica Celso Suckow da Fonseca (CEFET-RJ), Nova Friburgo, RJ (Brazil); Gonçalves, Alessandro C., E-mail: alessandrocgnuclear@gmail.com [Coordenacao de Pos-Graduacao e Pesquisa de Engenharia (COPPE/UFRJ), Rio de Janeiro, RJ (Brazil); Palma, Daniel A.P., E-mail: dapalma@cnen.gov.br [Comissão Nacional de Energia Nuclear (CNEN), Rio de Janeiro, RJ (Brazil)

    2017-07-01

    The thermal agitation movement in the reactor core is adequately represented by the microscopic cross section of the neutron-nucleus interaction through the Doppler broadening function. In the last decades several researches had been done on fundamentals and applications of generalized statistical theories based on quasi-Maxwellian distribution of probabilities. In this paper the effect of taking into account the non extensive Tsallis statistics in the evaluation of the absorption cross section in 3-dimension is discussed. In this context, it is obtained an integral form for a generalized Doppler broadening function in the scope of the single-level formalism given by the Bethe-Placzek approximations. This new function reproduces the well-established conventional Doppler broadening function on the limit when q removes the deformation. Numerical tests were carried out and by varying the q parameter it was possible to study the range of values where the effect is appreciable. (author)

  13. In-plane and cross-plane thermal conductivities of molybdenum disulfide

    International Nuclear Information System (INIS)

    Ding, Zhiwei; Pei, Qing-Xiang; Zhang, Yong-Wei; Jiang, Jin-Wu

    2015-01-01

    We investigate the in-plane and cross-plane thermal conductivities of molybdenum disulfide (MoS 2 ) using non-equilibrium molecular dynamics simulations. We find that the in-plane thermal conductivity of monolayer MoS 2 is about 19.76 W mK −1 . Interestingly, the in-plane thermal conductivity of multilayer MoS 2 is insensitive to the number of layers, which is in strong contrast to the in-plane thermal conductivity of graphene where the interlayer interaction strongly affects the in-plane thermal conductivity. This layer number insensitivity is attributable to the finite energy gap in the phonon spectrum of MoS 2 , which makes the phonon–phonon scattering channel almost unchanged with increasing layer number. For the cross-plane thermal transport, we find that the cross-plane thermal conductivity of multilayer MoS 2 can be effectively tuned by applying cross-plane strain. More specifically, a 10% cross-plane compressive strain can enhance the thermal conductivity by a factor of 10, while a 5% cross-plane tensile strain can reduce the thermal conductivity by 90%. Our findings are important for thermal management in MoS 2 based nanodevices and for thermoelectric applications of MoS 2 . (paper)

  14. Late Lutetian Thermal Maximum—Crossing a Thermal Threshold in Earth's Climate System?

    Science.gov (United States)

    Westerhold, T.; Röhl, U.; Donner, B.; Frederichs, T.; Kordesch, W. E. C.; Bohaty, S. M.; Hodell, D. A.; Laskar, J.; Zeebe, R. E.

    2018-01-01

    Recognizing and deciphering transient global warming events triggered by massive release of carbon into Earth's ocean-atmosphere climate system in the past are important for understanding climate under elevated pCO2 conditions. Here we present new high-resolution geochemical records including benthic foraminiferal stable isotope data with clear evidence of a short-lived (30 kyr) warming event at 41.52 Ma. The event occurs in the late Lutetian within magnetochron C19r and is characterized by a ˜2°C warming of the deep ocean in the southern South Atlantic. The magnitudes of the carbon and oxygen isotope excursions of the Late Lutetian Thermal Maximum are comparable to the H2 event (53.6 Ma) suggesting a similar response of the climate system to carbon cycle perturbations even in an already relatively cooler climate several million years after the Early Eocene Climate Optimum. Coincidence of the event with exceptionally high insolation values in the Northern Hemisphere at 41.52 Ma might indicate that Earth's climate system has a thermal threshold. When this tipping point is crossed, rapid positive feedback mechanisms potentially trigger transient global warming. The orbital configuration in this case could have caused prolonged warm and dry season leading to a massive release of terrestrial carbon into the ocean-atmosphere system initiating environmental change.

  15. Thermal Boundary Layer Effects on Line-of-Sight Tunable Diode Laser Absorption Spectroscopy (TDLAS) Gas Concentration Measurements.

    Science.gov (United States)

    Qu, Zhechao; Werhahn, Olav; Ebert, Volker

    2018-01-01

    The effects of thermal boundary layers on tunable diode laser absorption spectroscopy (TDLAS) measurement results must be quantified when using the line-of-sight (LOS) TDLAS under conditions with spatial temperature gradient. In this paper, a new methodology based on spectral simulation is presented quantifying the LOS TDLAS measurement deviation under conditions with thermal boundary layers. The effects of different temperature gradients and thermal boundary layer thickness on spectral collisional widths and gas concentration measurements are quantified. A CO 2 TDLAS spectrometer, which has two gas cells to generate the spatial temperature gradients, was employed to validate the simulation results. The measured deviations and LOS averaged collisional widths are in very good agreement with the simulated results for conditions with different temperature gradients. We demonstrate quantification of thermal boundary layers' thickness with proposed method by exploitation of the LOS averaged the collisional width of the path-integrated spectrum.

  16. Stack emission monitoring using non-dispersive infrared spectroscopy with an optimized nonlinear absorption cross interference correction algorithm

    Directory of Open Access Journals (Sweden)

    Y. W. Sun

    2013-08-01

    Full Text Available In this paper, we present an optimized analysis algorithm for non-dispersive infrared (NDIR to in situ monitor stack emissions. The proposed algorithm simultaneously compensates for nonlinear absorption and cross interference among different gases. We present a mathematical derivation for the measurement error caused by variations in interference coefficients when nonlinear absorption occurs. The proposed algorithm is derived from a classical one and uses interference functions to quantify cross interference. The interference functions vary proportionally with the nonlinear absorption. Thus, interference coefficients among different gases can be modeled by the interference functions whether gases are characterized by linear or nonlinear absorption. In this study, the simultaneous analysis of two components (CO2 and CO serves as an example for the validation of the proposed algorithm. The interference functions in this case can be obtained by least-squares fitting with third-order polynomials. Experiments show that the results of cross interference correction are improved significantly by utilizing the fitted interference functions when nonlinear absorptions occur. The dynamic measurement ranges of CO2 and CO are improved by about a factor of 1.8 and 3.5, respectively. A commercial analyzer with high accuracy was used to validate the CO and CO2 measurements derived from the NDIR analyzer prototype in which the new algorithm was embedded. The comparison of the two analyzers show that the prototype works well both within the linear and nonlinear ranges.

  17. Monte Carlo testing of new cross section data sets for thermal and intermediate highly enriched uranium critical assemblies

    International Nuclear Information System (INIS)

    Weinman, J.P.

    1998-06-01

    The purpose of this study is to investigate the eigenvalue sensitivity to new 235 U, hydrogen, and oxygen cross section data sets by comparing RACER Monte Carlo calculations for several thermal and intermediate spectrum critical experiments. The new 235 U library (Version 107) was derived by L. Leal and H. Derrien by fitting differential experimental data for 235 U while constraining the fit to match experimental capture and fission resonance integrals and Maxwellian averaged thermal K1 (v fission minus absorption). The new hydrogen library (Version 45) consists of the ENDF/B-VI release 3 data with a 332.0 mb 2,200 m/s cross section which replaces the value of 332.6 mb in the current library. The new oxygen library (Version 39) is based on a recent evaluation of 16 O by E. Caro. Nineteen Oak Ridge and Rocky Flats thermal solution benchmark critical assemblies that span a range of hydrogen-to- 235 U (H/U) concentrations (2,052 to 27.1) and above-thermal neutron leakage fractions (0.555 to 0.011) were analyzed. In addition, three intermediate spectrum critical assemblies (UH3-UR, UH3-NI, and HISS-HUG) were studied

  18. Study of the Photodegradation Process of Vitamin E Acetate by Optical Absorption, Fluorescence, and Thermal Lens Spectroscopy

    Science.gov (United States)

    Tiburcio-Moreno, J. A.; Marcelín-Jiménez, G.; Leanos-Castaneda, O. L.; Yanez-Limon, J. M.; Alvarado-Gil, J. J.

    2012-11-01

    The stability of vitamin E acetate exposed to ultraviolet (UV) light was studied using three spectroscopic methods. An ethanol solution of vitamin E acetate was treated with either UVC light (254 nm) or UVA light (366 nm) during a period of 10 min followed by a study of UV-Vis optical absorption, then by fluorescence spectroscopy excitation by UV radiation at either 290 nm or 368 nm and, finally the solution was studied by thermal lens spectroscopy. Immediately, the same solution of vitamin E acetate was subjected to the UV irradiation process until completion of six periods of irradiation and measurements. UVC light treatment induced the appearance of a broad absorption band in the range of 310 nm to 440 nm with maximum absorbance at 368 nm, which progressively grew as the time of the exposure to UVC light increases. In contrast, UVA light treatment did not affect the absorption spectra of vitamin E acetate. Fluorescence spectra of the vitamin E acetate (without UV light treatment) showed no fluorescence when excited with 368 nm while exciting with 290 nm, an intense and broad emission band (300 nm to 440 nm) with a maximum at 340 nm appeared. When vitamin E acetate was treated with UVC light, this emission band progressively decreased as the time of the UVC light irradiation grew. No signal from UV-untreated vitamin E acetate could be detected by the thermal lens method. Interestingly, as the time of the UVC light treatment increased, the thermal lens signal progressively grew. Additional experiments performed to monitor the time evolution of the process during continuous UVC treatment of the vitamin E acetate using thermal lens spectroscopy exhibited a progressive increase of the thermal lens signal reaching a plateau at about 8000 s. This study shows that the vitamin E acetate is stable when it is irradiated with UVA light, while the irradiation with UVC light induces the formation of photodegradation products. Interestingly, this photodegradation process using

  19. Application of neutron absorption method of the analysis on thermal neutrons for the control of substances and products containing boron in a nuclear power engineering and industry

    International Nuclear Information System (INIS)

    Chuev, A.G.; Kiryanov, G.I.; Shagov, S.V.; Shtan, A.S.; Titov, V.V.

    2002-01-01

    Nuclear physical methods of analysis using the absorption effect of ionising radiation should satisfy the following requirements for industrial practice. First, the ionising radiation should have a high penetrating ability in the environment examined to ensure a representative nature of the data and reliability of the analysis. Secondly, the absorption degree of radiation should be sufficient to maintain the sensitivity and accuracy of the measurements. In addition, to keep the necessary selectivity, the neutron absorption analysis on thermal neutrons is applied on chemical elements and their isotopes with an anomalously high absorption cross section about 10 2 - 10 4 barn. To such elements belong Gd, Sm, B, Cd, Hg and others. Based on the exponential law of absorption for thermal neutrons, an analytical expression was obtained for the concentration of the element analyzed in dependence on the flow of the elapsed neutrons. A number of interfering factors such as the matrix effect of the filling agent, scattering of neutrons, dispersion of the density and of the temperature of the environment, and background radiation have to be taken into account. Owing to the difference between the experimental calibration dependence and the exponential one, the methods of its mathematical approximation, for example, polynomial function and partially hyperbolic one are considered. The scheme realisation of the method is feasible in geometry 'on passage' and 'on reflection' of the neutron flow. Radionuclide Pu-Be sources are preferred as the neutron sources based on nuclear reactions of the (α,n) type. Detectors used for registration of slow neutrons are gas discharge corona 3 He-filled counters. Hydrogen-containing substances with good scattering properties are utilised as the fast neutron moderators. The neutron absorption method has found wide application in the nuclear power engineering and atomic industry. This method is intended for continuous automatic monitoring of

  20. Characterization of Thermal Cross-talk in a γ-ray Microcalorimeter Array

    International Nuclear Information System (INIS)

    Jethava, N.; Ullom, J. N.; Bennett, D. A.; Irwin, K. D.; Horansky, R. D.; Beall, J. A.; Hilton, G. C.; Vale, L. R.; Hoover, A.; Bacrania, M. K.; Rabin, M. W.

    2009-01-01

    We present experimental data describing cross-talk within an array of gamma-ray microcalorimeters during gamma-ray irradiation. The microcalorimeters consist of Mo/Cu transition-edge sensors (TESs) with attached Sn absorbers. We observe both thermal and electrical cross-talk with peak cross-talk amplitudes as large as 0.4%. We have developed an analytical model for thermal cross-talk and make a preliminary comparison to data. Cross-talk must be understood and minimized for high resolution spectroscopy at high input count rates.

  1. Absorption and Emission Spectroscopic Investigation of Thermal Dynamics and Photo-Dynamics of the Rhodopsin Domain of the Rhodopsin-Guanylyl Cyclase from the Nematophagous Fungus Catenaria anguillulae

    Directory of Open Access Journals (Sweden)

    Alfons Penzkofer

    2017-10-01

    Full Text Available The rhodopsin-guanylyl cyclase from the nematophagous fungus Catenaria anguillulae belongs to a recently discovered class of enzymerhodopsins and may find application as a tool in optogenetics. Here the rhodopsin domain CaRh of the rhodopsin-guanylyl cyclase from Catenaria anguillulae was studied by absorption and emission spectroscopic methods. The absorption cross-section spectrum and excitation wavelength dependent fluorescence quantum distributions of CaRh samples were determined (first absorption band in the green spectral region. The thermal stability of CaRh was studied by long-time attenuation measurements at room temperature (20.5 °C and refrigerator temperature of 3.5 °C. The apparent melting temperature of CaRh was determined by stepwise sample heating up and cooling down (obtained apparent melting temperature: 62 ± 2 °C. The photocycle dynamics of CaRh was investigated by sample excitation to the first inhomogeneous absorption band of the CaRhda dark-adapted state around 590 nm (long-wavelength tail, 530 nm (central region and 470 nm (short-wavelength tail and following the absorption spectra development during exposure and after exposure (time resolution 0.0125 s. The original protonated retinal Schiff base PRSBall-trans in CaRhda photo-converted reversibly to protonated retinal Schiff base PRSBall-trans,la1 with restructured surroundings (CaRhla1 light-adapted state, slightly blue-shifted and broadened first absorption band, recovery to CaRhda with time constant of 0.8 s and deprotonated retinal Schiff base RSB13-cis (CaRhla2 light-adapted state, first absorption band in violet to near ultraviolet spectral region, recovery to CaRhda with time constant of 0.35 s. Long-time light exposure of light-adapted CaRhla1 around 590, 530 and 470 nm caused low-efficient irreversible degradation to photoproducts CaRhprod. Schemes of the primary photocycle dynamics of CaRhda and the secondary photocycle dynamics of CaRhla1 are developed.

  2. Multi-wavelength thermal-lens spectrometry for high-accuracy measurements of absorptivities and quantum yields of photodegradation of a hemoprotein–lipid complex

    Directory of Open Access Journals (Sweden)

    Kseniya Tishchenko

    2017-09-01

    Full Text Available Accurate measurements of absorptivities and quantum yields of biochemical species under various conditions are an important task of applied photonics and analytical chemistry. In this work, we provide a comparison of the capabilities of thermal-lens spectrometry to measure these parameters of various samples. Measurements of relevant model substances, biologically active substituted 2-thiohydantoins and their complexes of copper(I,II and heme proteins (forms of hemoglobin and cytochrome c, showed negligible differences in apparent molar absorptivities for thermal-lens spectrometry and optical-absorption (spectrophotometric data. The values for tabletop and microscale thermal-lens measurements under batch conditions differ insignificantly. The precision of measurements of molar absorptivities by thermal-lens spectrometry is no less than in the case of spectrophotometry or the precision is even higher in the cases of low absorptivities. For cardiolipin–cytochrome c-NO complex, the difference between absorptivity values calculated from thermal-lens data and acquired by spectrophotometry is significant due to complex photodegradation. The quantum yield of its photolysis reaction calculated from optical absorption and thermal-lens data altogether at two wavelengths for 0.4–360 s of the reaction, 0.46 ± 0.04, was estimated.

  3. Preliminary investigation of biological resistance, water absorption and swelling of thermally compressed pine wood panels

    Science.gov (United States)

    Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel Arango; Carol A. Clausen; Frederick Green

    2008-01-01

    Wood can be modified by compressive, thermal and chemical treatments. Compression of wood under thermal conditions is resulted in densification of wood. This study evaluated decay and termite resistance of thermally compressed pine wood panels at either 5 or 7 MPa and at either 120 or 150°C for one hour. The process caused increases in density and decreases in...

  4. Thermal Conductance in Cross-linked Polymers: Effects of Non-Bonding Interactions.

    Science.gov (United States)

    Rashidi, Vahid; Coyle, Eleanor J; Sebeck, Katherine; Kieffer, John; Pipe, Kevin P

    2017-05-04

    Weak interchain interactions have been considered to be a bottleneck for heat transfer in polymers, while covalent bonds are believed to give a high thermal conductivity to polymer chains. For this reason, cross-linkers have been explored as a means to enhance polymer thermal conductivity; however, results have been inconsistent. Some studies show an enhancement in the thermal conductivity for polymers upon cross-linking, while others show the opposite trend. In this work we study the mechanisms of heat transfer in cross-linked polymers in order to understand the reasons for these discrepancies, in particular examining the relative contributions of covalent (referred to here as "bonding") and nonbonding (e.g., van der Waals and electrostatic) interactions. Our results indicate cross-linkers enhance thermal conductivity primarily when they are short in length and thereby bring polymer chains closer to each other, leading to increased interchain heat transfer by enhanced nonbonding interactions between the chains (nonbonding interactions being highly dependent on interchain distance). This suggests that enhanced nonbonding interactions, rather than thermal pathways through cross-linker covalent bonds, are the primary transport mechanism by which thermal conductivity is increased. We further illustrate this by showing that energy from THz acoustic waves travels significantly faster in polymers when nonbonding interactions are included versus when only covalent interactions are present. These results help to explain prior studies that measure differing trends in thermal conductivity for polymers upon cross-linking with various species.

  5. Developing a vacuum thermal stripping - acid absorption process for ammonia recovery from anaerobic digester effluent.

    Science.gov (United States)

    Ukwuani, Anayo T; Tao, Wendong

    2016-12-01

    To prevent acetoclastic methanogens from ammonia inhibition in anaerobic digestion of protein-rich substrates, ammonia needs to be removed or recovered from digestate. This paper presents an innovative ammonia recovery process that couples vacuum thermal stripping with acid absorption. Ammonia is stripped out of digestate boiling at a temperature below the normal boiling point due to vacuum. Stripped ammonia is absorbed to a sulfuric acid solution, forming ammonium sulfate crystals as a marketable product. Three common types of digestate were found to have boiling point temperature-vacuum curves similar to water. Seven combinations of boiling temperature and vacuum (50 °C 16.6 kPa, 58 °C 20.0 kPa, 65 °C 25.1 kPa, 70 °C 33.6 kPa, 80 °C 54.0 kPa, 90 °C 74.2 kPa, and 100 °C 101.3 kPa) were tested for batch stripping of ammonia in dairy manure digestate. 93.3-99.9% of ammonia was stripped in 3 h. The Lewis-Whitman model fitted ammonia stripping process well. Ammonia mass transfer coefficient was significantly higher at boiling temperature 65-100 °C and vacuum pressure 25.1-101.3 kPa than 50-58 °C and 16.6-20.0 kPa. The low ammonia saturation concentrations (0-24 mg N/L) suggested a large driving force to strip ammonia. The optimum boiling point temperature - vacuum pressure for ammonia recovery in a recirculation line of a mesophilic digester was 65 °C and 25.1 kPa, at which the ammonia mass transfer coefficient was as high as 37.3 mm/h. Installation of a demister and liquid trap could avoid negative effects of higher stripping temperature and stronger vacuum on formation of ammonium sulfate crystals. Pilot tests demonstrated that high-purity ammonium sulfate crystals could be produced by controlling sulfuric acid content and maintaining acid solution saturated with ammonium sulfate. Although volatile organic compounds such as cyclohexene were found in the final acid solutions, no volatile organic compounds were found in the recovered

  6. Framing the performance of heat absorption/generation and thermal radiation in chemically reactive Darcy-Forchheimer flow

    Directory of Open Access Journals (Sweden)

    T. Hayat

    Full Text Available The present work aims to report the consequences of heterogeneous-homogeneous reactions in Darcy-Forchheimer flow of Casson material bounded by a nonlinear stretching sheet of variable thickness. Nonlinear stretched surface with variable thickness is the main agent for MHD Darcy-Forchheimer flow. Impact of thermal radiation and non-uniform heat absorption/generation are also considered. Flow in porous space is characterized by Darcy-Forchheimer flow. It is assumed that the homogeneous process in ambient fluid is governed by first order kinetics and the heterogeneous process on the wall surface is given by isothermal cubic autocatalator kinetics. The governing nonlinear ordinary differential equations are solved numerically. Effects of physical variables such as thickness, Hartman number, inertia and porous, radiation, Casson, heat absorption/generation and homogeneous-heterogeneous reactions are investigated. The variations of drag force (skin friction and heat transfer rate (Nusselt numberfor different interesting variables are plotted and discussed. Keywords: Casson fluid, Variable sheet thickness, Darcy-Forchheimer flow, Homogeneous-heterogeneous reactions, Heat generation/absorption, Thermal radiation

  7. Optical absorption study of radiation and thermal effects in Brazilian samples of spodumene

    International Nuclear Information System (INIS)

    Isotani, S.; Fujii, A.T.; Antonini, R.; Furtado, W.

    1988-03-01

    A detailed analysis of the optical absorption spectra of five varieties of Brazilian spodumene is presented. The samples were submitted to heat treatments and irradiated with gamma rays, x radiation, electrons and ultraviolet light. (M.C.K.) [pt

  8. Measurement of the effective thermal cross section of {sup 134}Cs by triple neutron capture reaction

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, Shoji; Harada, Hideo; Katoh, Toshio [Power Reactor and Nuclear Fuel Development Corp., Tokai, Ibaraki (Japan). Tokai Works; Hatsukawa, Yuichi; Shinohara, Nobuo; Hata, Kentaro; Kobayashi, Katsutoshi; Motoishi, Shoji; Tanase, Masakazu

    1998-03-01

    The effective thermal cross section ({sigma}{sub eff}) of the {sup 134}Cs(n,{gamma}){sup 135}Cs reaction was measured by the activation method and the {gamma}-ray spectroscopic method in order to obtain fundamental data for research on the transmutation of nuclear wastes. The effective thermal cross section of the reaction {sup 134}Cs(n,{gamma}){sup 135}Cs was found to be 140.6{+-}8.5 barns. (author)

  9. Fire exposed steel columns with a thermal gradient over the cross-section

    NARCIS (Netherlands)

    Ojeda, O.D.; Maljaars, J.; Abspoel, R.

    2016-01-01

    Thermal gradients often occur in fire exposed structures. This paper considers thermal gradients over the cross-section of steel columns. By means of finite element simulations, the paper demonstrates that these gradients reduce the fiexural buckling resistance of the columns. This is due to the

  10. Heat dissipation by blood circulation and airway tissue heat absorption in a canine model of inhalational thermal injury.

    Science.gov (United States)

    Wan, Jiangbo; Zhang, Guoan; Qiu, Yuxuan; Wen, Chunquan; Fu, Tairan

    2016-05-01

    This study aimed to further explore heat dissipation by blood circulation and airway tissue heat absorption in an inhalational thermal injury model. Twelve adult male Beagle dogs were divided into four groups to inhale heated air for 10min: the control group, group I (100.5°C), group II (161.5°C), and group III (218°C). The relative humidity and temperature of the inhaled heated air were measured in the heating tube and trachea, as were blood temperatures and flow velocities in both common jugular veins. Formulas were used to calculate the total heat quantity reduction of the heated air, heat dissipation by the blood, and airway tissue heat absorption. The blood temperatures of both the common jugular veins increased by 0.29°C±0.07°C to 2.96°C±0.24°C and the mean blood flow volume after injury induction was about 1.30-1.74 times greater than before injury induction. The proportions of heat dissipated by the blood and airway tissue heat absorption were 68.92%±14.88% and 31.13%±14.87%, respectively. The heat dissipating ability of the blood circulation was demonstrated and improved upon along with tissue heat absorption owing to increased regional blood flow. Copyright © 2015 Elsevier Ltd and ISBI. All rights reserved.

  11. MEASUREMENTS OF THE ABSORPTION AND SCATTERING CROSS SECTIONS FOR THE INTERACTION OF SOLAR ACOUSTIC WAVES WITH SUNSPOTS

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Hui [National Astronomical Observatories, Chinese Academy of Sciences, Beijing, 200012 (China); Chou, Dean-Yi, E-mail: chou@phys.nthu.edu.tw [Physics Department, National Tsing Hua University, Hsinchu, Taiwan (China)

    2016-05-01

    The solar acoustic waves are modified by the interaction with sunspots. The interaction can be treated as a scattering problem: an incident wave propagating toward a sunspot is scattered by the sunspot into different modes. The absorption cross section and scattering cross section are two important parameters in the scattering problem. In this study, we use the wavefunction of the scattered wave, measured with a deconvolution method, to compute the absorption cross section σ {sub ab} and the scattering cross section σ {sub sc} for the radial order n = 0–5 for two sunspots, NOAA 11084 and NOAA 11092. In the computation of the cross sections, the random noise and dissipation in the measured acoustic power are corrected. For both σ {sub ab} and σ {sub sc}, the value of NOAA 11092 is greater than that of NOAA 11084, but their overall n dependence is similar: decreasing with n . The ratio of σ {sub ab} of NOAA 11092 to that of NOAA 11084 approximately equals the ratio of sunspot radii for all n , while the ratio of σ {sub sc} of the two sunspots is greater than the ratio of sunspot radii and increases with n . This suggests that σ {sub ab} is approximately proportional to the sunspot radius, while the dependence of σ {sub sc} on radius is faster than the linear increase.

  12. Decay and termite resistance, water absorption and swelling of thermally compressed wood panels

    Science.gov (United States)

    Oner Unsal; S. Nami Kartal; Zeki Candan; Rachel A. Arango; Carol A. Clausen; Frederick Green

    2009-01-01

    This study evaluated decay and termite resistance of thermally compressed pine wood panels under pressure at either 5 or 7 MPa and either 120 or 150 °C for 1 h. Wood specimens from the panels were exposed to laboratory decay resistance by using the wood degrading fungi, Gloeophyllum trabeum and Trametes versicolor. The thermal compression process caused increases in...

  13. Thermal stability, swelling behavior and CO 2 absorption properties of Nanoscale Ionic Materials (NIMs)

    KAUST Repository

    Andrew Lin, Kun-Yi

    2014-11-11

    © The Royal Society of Chemistry 2015. Nanoscale Ionic Materials (NIMs) consist of a nanoscale core, a corona of charged brushes tethered on the surface of the core, and a canopy of the oppositely charged species linked to the corona. Unlike conventional polymeric nanocomposites, NIMs can display liquid-like behavior in the absence of solvents, have a negligible vapor pressure and exhibit unique solvation properties. These features enable NIMs to be a promising CO2 capture material. To optimize NIMs for CO2 capture, their structure-property relationships were examined by investigating the roles of the canopy and the core in their thermal stability, and thermally- and CO2-induced swelling behaviors. NIMs with different canopy sizes and core fractions were synthesized and their thermal stability as well as thermally- and CO2-induced swelling behaviors were determined using thermogravimetry, and ATR FT-IR and Raman spectroscopies. It was found that the ionic bonds between the canopy and the corona, as well as covalent bonds between the corona and the core significantly improved the thermal stability compared to pure polymer and polymer/nanofiller mixtures. A smaller canopy size and a larger core fraction led to a greater enhancement in thermal stability. This thermal stability enhancement was responsible for the long-term thermal stability of NIMs over 100 temperature swing cycles. Owing to their ordered structure, NIMs swelled less when heated or when they adsorbed CO2 compared to their corresponding polymers. This journal is

  14. INTER, ENDF/B Thermal Cross-Sections, Resonance Integrals, G-Factors Calculation

    International Nuclear Information System (INIS)

    Dunford, Charles L.

    2007-01-01

    1 - Description of program or function: INTER calculates thermal cross sections, g-factors, resonance integrals, fission spectrum averaged cross sections and 14.0 MeV (or other energy) cross sections for major reactions in an ENDF-6 or ENDF-5 format data file. Version 7.01 (Jan 2005): set success flag after return from beginning. 2 - Method of solution: INTER performs integrations by using the trapezoidal rule

  15. High Ultraviolet Absorption in Colloidal Gallium Nanoparticles Prepared from Thermal Evaporation

    Directory of Open Access Journals (Sweden)

    Flavio Nucciarelli

    2017-07-01

    Full Text Available New methods for the production of colloidal Ga nanoparticles (GaNPs are introduced based on the evaporation of gallium on expendable aluminum zinc oxide (AZO layer. The nanoparticles can be prepared in aqueous or organic solvents such as tetrahydrofuran in order to be used in different sensing applications. The particles had a quasi mono-modal distribution with diameters ranging from 10 nm to 80 nm, and their aggregation status depended on the solvent nature. Compared to common chemical synthesis, our method assures higher yield with the possibility of tailoring particles size by adjusting the deposition time. The GaNPs have been studied by spectrophotometry to obtain the absorption spectra. The colloidal solutions exhibit strong plasmonic absorption in the ultra violet (UV region around 280 nm, whose width and intensity mainly depend on the nanoparticles dimensions and their aggregation state. With regard to the colloidal GaNPs flocculate behavior, the water solvent case has been investigated for different pH values, showing UV-visible absorption because of the formation of NPs clusters. Using discrete dipole approximation (DDA method simulations, a close connection between the UV absorption and NPs with a diameter smaller than ~40 nm was observed.

  16. Sensitivity of LWR fuel cycle costs to uncertainties in detailed thermal cross sections

    International Nuclear Information System (INIS)

    Ryskamp, J.M.; Becker, M.; Harris, D.R.

    1979-01-01

    Cross sections averaged over the thermal energy (< 1 or 2 eV) group have been shown to have an important economic role for light-water reactors. Cost implications of thermal cross section uncertainties at the few-group level were reported earlier. When it has been determined that costs are sensitive to a specific thermal-group cross section, it becomes desirable to determine how specific energy-dependent cross sections influence fuel cycle costs. Multigroup cross-section sensitivity coefficients vary with fuel exposure. By changing the shape of a cross section displayed on a view-tube through an interactive graphics system, one can compute the change in few-group cross section using the exposure dependent sensitivity coefficients. With the changed exposure dependent few-group cross section, a new fuel cycle cost is computed by a sequence of batch depletion, core analysis, and fuel batch cost code modules. Fuel cycle costs are generally most sensitive to cross section uncertainties near the peak of the hardened Maxwellian flux

  17. The direct determination of HgS by thermal desorption coupled with atomic absorption spectrometry

    Czech Academy of Sciences Publication Activity Database

    Coufalík, Pavel; Zvěřina, O.; Komárek, J.

    2016-01-01

    Roč. 118, APR (2016), s. 1-5 ISSN 0584-8547 Institutional support: RVO:68081715 Keywords : mercury * HgS * thermal desorption Subject RIV: CB - Analytical Chemistry, Separation Impact factor: 3.241, year: 2016

  18. Cross-spectrum Measurement of Thermal-noise Limited Oscillators

    OpenAIRE

    Hati, Archita; Nelson, Craig W.; Howe, David A.

    2015-01-01

    Cross-spectrum analysis is a commonly-used technique for the detection of phase and amplitude noise of a signal in the presence of interfering noise. It extracts the desired correlated noise from two time series in the presence of uncorrelated interfering noise. Recently, we demonstrated that the phase-inversion (anti-correlation) effect due to AM noise leakage can cause complete or partial collapse of the cross-spectral function. In this paper, we discuss the newly discovered effect of anti-...

  19. Directional Thermal Emission and Absorption from Surface Microstructures in Metalized Plastics

    Science.gov (United States)

    2013-09-01

    directional thermal emitter with enhanced surface durability due to its extended metal deposition thickness. 1.3.3 Dual-Cavity-Width Structure Design...crystals. The definition is applied to one-dimensionally periodic stacks, two-dimensionally periodic slabs , and three- dimensionally periodic complex...sufficiently to significantly effect the film durability and thermal conductivity, the profile of the cavity begins to change shape. Although a case

  20. Effect of Simulant Type on the Absorptance and Emittance of Dusted Thermal Control Surfaces in a Simulated Lunar Environment

    Science.gov (United States)

    Gaier, James R.

    2010-01-01

    During the Apollo program the effects of lunar dust on thermal control surfaces was found to be more significant than anticipated, with several systems overheating due to deposition of dust on them. In an effort to reduce risk to future missions, a series of tests has been initiated to characterize the effects of dust on these surfaces, and then to develop technologies to mitigate that risk. Given the variations in albedo across the lunar surface, one variable that may be important is the darkness of the lunar dust, and this study was undertaken to address that concern. Three thermal control surfaces, AZ-93 white paint and AgFEP and AlFEP second surface mirrors were dusted with three different lunar dust simulants in a simulated lunar environment, and their integrated solar absorptance ( ) and thermal emittance ( ) values determined experimentally. The three simulants included JSC-1AF, a darker mare simulant, NU-LHT-1D, a light highlands simulant, and 1:1 mixture of the two. The response of AZ-93 was found to be slightly more pronounced than that of AgFEP. The increased with fractional dust coverage in both types of samples by a factor of 1.7 to 3.3, depending on the type of thermal control surface and the type of dust. The of the AZ-93 decreased by about 10 percent when fully covered by dust, while that of AgFEP increased by about 10 percent. It was found that / varied by more than a factor of two depending on the thermal control surface and the darkness of the dust. Given that the darkest simulant used in this study may be lighter than the darkest dust that could be encountered on the lunar surface, it becomes apparent that the performance degradation of thermal control surfaces due to dust on the Moon will be strongly dependent on the and of the dust in the specific locality

  1. Thermal conductivity prediction of magnetic composite sheet for near-field electromagnetic absorption

    International Nuclear Information System (INIS)

    Lee, Joonsik; Nam, Baekil; Ko, Frank K.; Kim, Ki Hyeon

    2015-01-01

    The magnetic composite sheets were designed by using core-shell structured magnetic fillers instead of uncoated magnetic fillers to resolve concurrently the electromagnetic interference and thermal radiation problems. To predict the thermal conductivity of composite sheet, we calculated the thermal conductivity of the uncoated magnetic fillers and core-shell structured fillers. And then, the thermal conductivity of the magnetic composites sheet filled with core-shell structured magnetic fillers was calculated and compared with that of the uncoated magnetic fillers filled in composite sheet. The magnetic core and shell material are employed the typical Fe-Al-Si flake (60 μm × 60 μm × 1 μm) and 250 nm-thick AlN with high thermal conductivity, respectively. The longitudinal thermal conductivity of the core-shell structured magnetic composite sheet (2.45 W/m·K) enhanced about 33.4% in comparison with that of uncoated magnetic fillers (1.83 W/m·K) for the 50 vol. % magnetic filler in polymer matrix

  2. Absorption spectrum and absorption cross sections of the 2ν1 band of HO2 between 20 and 760 Torr air in the range 6636 and 6639 cm-1

    Science.gov (United States)

    Assaf, Emmanuel; Liu, Lu; Schoemaecker, Coralie; Fittschen, Christa

    2018-05-01

    The absorption spectrum of HO2 radicals has been measured in the range 6636-6639 cm-1 at several pressures between 20 and 760 Torr of air. Absolute absorption cross sections of the strongest line at around 6638.2 cm-1 have been determined from kinetic measurements, taking advantage of the well known rate constant of the self-reaction. Peak absorption cross sections of 22.6, 19.5, 14.4, 7.88, 5.12 and 3.23 × 10-20 cm2 were obtained at 20, 50, 100, 200, 400 and 760 Torr, respectively. By fitting these data, an empirical expression has been obtained for the absorption cross section of HO2 in the range 20-760 Torr air: σ6638.2cm-1 = 1.18 × 10-20 + (2.64 × 10-19 × (1-exp (-63.1/p (Torr))) cm2.

  3. On the treatment of resonance cross sections in thermal reactor ...

    African Journals Online (AJOL)

    This paper discusses the mathematical models and methods used for calculating resonance cross sections in the resonance region of the neutron energy spectrum. Particular attention has been paid to the treatment outlined in the WIMSD/4 version of the WIMS lattice transport code. The significance of the resonance ...

  4. A New Cross-Shaped Graphite Furnace with Ballast Body for Reduction of Interferences in Atomic Absorption Spectrometry

    Directory of Open Access Journals (Sweden)

    A. A. Asweisi

    2010-01-01

    Full Text Available A new crossed graphite furnace for atomic absorption spectrometry (GFAAS was designed and installed in heated graphite atomizer (HGA500 combined with Perkin-Elmer spectrometer (AAS1100. The Tungsten ballast body was inserted inside one part of the crossed furnace in a way perpendicular to light path. The analyzed sample was injected manually on the ballast body inside the cross and pushed into the measuring zone using the original inner and additional purge gas. The sample was adsorbed strongly on the ballast and evaporated and transferred with different rates at different temperatures during the temperature program allowing the separation of analyte and matrix signals. Analysis of middle volatile element such as copper and manganese in standard urine sample (seronorm 2525 showed complete separation of analyte and background signals with good sensitivity and repeatability.

  5. Temperature-dependent absorption cross-section measurements of 1-butene (1-C4H8) in VUV and IR

    KAUST Repository

    Es-sebbar, Et-touhami

    2013-01-01

    Vacuum ultraviolet (VUV) and infrared (IR) absorption cross-section measurements of 1-butene (1-C4H8; CH2=CHCH2CH3; Butylene) are reported over the temperature range of 296-529K. The VUV measurements are performed between 115 and 205nm using synchrotron radiation as a tunable VUV light source. Fourier Transform Infrared (FTIR) spectroscopy is employed to measure absorption cross-section and band strengths in the IR region between 1.54 and 25μm (~6500-400cm-1). The measured room-temperature VUV and IR absorption cross-sections are compared with available literature data and are found to be in good agreement. The oscillator strength for the electronic transition (A1A\\'→X1A\\') around 150-205nm is determined to be 0.32±0.01.The gas temperature has a strong effect on both VUV and IR spectra. Measurements made in the VUV region show that the peak value of the band cross-section decreases and the background continuum increases with increasing gas temperature. This behavior is due to a change in the rotational and vibrational population distribution of 1-butene molecule. Similar changes in rotational population are observed in the IR spectra. Moreover, variation of the IR spectra with temperature is used to measure the enthalpy difference between syn and skew conformations of 1-butene and is found to be 0.24±0.03. kcal/mol, which is in excellent agreement with values reported in the literature. The measurements reported in this work will provide the much-needed spectroscopic information for the development of high-temperature quantitative diagnostics in combustion applications and validation of atmospheric chemistry models of extra-solar planets. © 2012 Elsevier Ltd.

  6. THOR: thermal cross section generation code using ENDF/B data

    International Nuclear Information System (INIS)

    Andrews, J.B. II; Hassan, N.M.; Wittkopf, W.A.

    1975-12-01

    THOR processes ENDF/B data files to produce a master thermal library containing multigroup cross sections, scattering kernels, and slowing-down source distributions for use in thermal spectrum calculations. The thermal energy range may be described by up to 80 energy groups, and a weighting spectrum may be either input or calculated by the program for use in obtaining average group coefficients. Resonance contributions to the thermal cross sections are added to the appropriate smooth cross sections to obtain the cross section for each reaction type. Scattering kernels may be produced using either thermal neutron scattering law data or free gas scattering law data, depending on the form of the data present on the ENDF/B data file for the material. Slowing-down source distributions are calculated for each material assuming a 1/E neutron flux in the epithermal energy range. The master thermal library produced by THOR may contain up to 100 materials with coefficient data present at a maximum of 25 temperatures for each material

  7. Zinc absorption from milk is affected by dilution but not by thermal processing, and milk enhances absorption of Zinc from high-phytate rice in young dutch women

    NARCIS (Netherlands)

    Talsma, Elise F.; Moretti, Diego; Ly, Sou Chheng; Dekkers, Renske; Heuvel, van den Ellen G.H.M.; Fitri, Aditia; Boelsma, Esther; Stomph, Tjeerd Jan; Zeder, Christophe; Melse-Boonstra, Alida

    2017-01-01

    Background: Milk has been suggested to increase zinc absorption. The effect of processing and the ability of milk to enhance zinc absorption from other foods has not been measured directly in humans. Objective: We aimed to assess zinc absorption from 1) milk undergoing various processing and

  8. Absorption enhancement by matching the cross-section of plasmonic nanowires to the field structure of tightly focused beams.

    Science.gov (United States)

    Normatov, Alexander; Spektor, Boris; Leviatan, Yehuda; Shamir, Joseph

    2011-04-25

    Nanostructured materials, designed for enhanced light absorption, are receiving increased scientific and technological interest. In this paper we propose a physical criterion for designing the cross-sectional shape of plasmonic nanowires for improved absorption of a given tightly focused illumination. The idea is to design a shape which increases the matching between the nanowire plasmon resonance field and the incident field. As examples, we design nanowire shapes for two illumination cases: a tightly focused plane wave and a tightly focused beam containing a line singularity. We show that properly shaped and positioned silver nanowires that occupy a relatively small portion of the beam-waist area can absorb up to 65% of the total power of the incident beam.

  9. Status of measured neutron cross sections of transactinium isotopes for thermal reactors

    International Nuclear Information System (INIS)

    Benjamin, R.W.

    1976-01-01

    Experimentally determined neutron cross sections, resonance parameters, and the average number of neutrons per fission for neutron-induced fission of actinide nuclides in the production chains associated with thermal and near-thermal reactors are summarized and compared with user requests for experimental data. The primary fertile and fissile isotopes 232 Th, 233 U, 235 U, 238 U, and 239 Pu are excluded from this survey. Integral data, i.e., spectrum-averaged thermal cross sections and resonance integrals, are included, but the emphasis is placed on energy-dependent differential cross sections because of their general utility with any specified neutron energy spectrum. Included with the data summaries are an extensive survey of the literature through August 1975, brief descriptions of measurements known to be in progress or firmly planned for the immediate future, and recommendations for needed measurements. (author)

  10. Status of measured neutron cross sections of transactinium isotopes for thermal reactors

    International Nuclear Information System (INIS)

    Benjamin, R.W.

    1975-01-01

    Experimentally determined neutron cross sections, resonance parameters, and the average number of neutrons per fission for neutron-induced fission of actinide nuclides in the production chains associated with thermal and near-thermal reactors are summarized and compared with user requests for experimental data. The primary fertile and fissile isotopes 232 Th, 233 U, 235 U, 238 U, and 239 Pu are excluded from this survey. Integral data, i.e., spectrum-averaged thermal cross sections and resonance integrals, are included, but the emphasis is placed on energy-dependent differential cross sections because of their general utility with any specified neutron energy spectrum. Included with the data summaries are an extensive survey of the literature through August 1975, brief descriptions of measurements known to be in progress or firmly planned for the immediate future, and recommendations for needed measurements. (3 figures, 5 tables)

  11. TEMPEST-2, Thermalization Program for Neutron Spectra and Multigroup Cross-Sections

    International Nuclear Information System (INIS)

    Gowins, G.

    1984-01-01

    Description of problem or function: TEMPEST2 is a neutron thermalization program based upon the Wigner-Wilkins approximation for light moderators and the Wilkins approximation for heavy moderators. A Maxwellian distribution may also be used. The model used may be selected as a function of energy. The second-order differential equations are integrated directly rather than transformed to the Riccati equation. The program provides microscopic and macroscopic cross-section averages over the thermal neutron spectrum

  12. Effect of thermal radiation and suction on convective heat transfer of nanofluid along a wedge in the presence of heat generation/absorption

    Energy Technology Data Exchange (ETDEWEB)

    Kasmani, Ruhaila Md; Bhuvaneswari, M. [Centre for Foundation Studies in Science, University of Malaya, 50603 Kuala Lumpur (Malaysia); Sivasankaran, S.; Siri, Zailan [Institute of Mathematical Science, University of Malaya, 50603 Kuala Lumpur (Malaysia)

    2015-10-22

    An analysis is presented to find the effects of thermal radiation and heat generation/absorption on convection heat transfer of nanofluid past a wedge in the presence of wall suction. The governing partial differential equations are transformed into a system of ordinary differential equations using similarity transformation. The resulting system is solved numerically using a fourth-order Runge–Kutta method with shooting technique. Numerical computations are carried out for different values of dimensionless parameters to predict the effects of wedge angle, thermophoresis, Brownian motion, heat generation/absorption, thermal radiation and suction. It is found that the temperature increases significantly when the value of the heat generation/absorption parameter increases. But the opposite observation is found for the effect of thermal radiation.

  13. Thermal-neutron fission cross section of 26. 1-min /sup 235/U/sup m/

    Energy Technology Data Exchange (ETDEWEB)

    Talbert W.L. Jr.; Starner, J.W.; Estep, R.J.; Balestrini, S.J.; Attrep M. Jr.; Efurd, D.W.; Roensch, F.R.

    1987-11-01

    The thermal-neutron fission cross section of /sup 235/U/sup m/ has been measured relative to the ground-state cross section. A rapid radiochemical separation procedure was developed to provide sizeable (10/sup 10/ to 10/sup 11/ atom) samples that were reasonably free of the parent /sup 239/Pu. From a series of eight measurements, the value of 1.42 +- 0.04 was obtained for the ratio sigma/sub m//sigma/sub g/.

  14. Monte Carlo simulations of the detailed iron absorption line profiles from thermal winds in X-ray binaries

    Science.gov (United States)

    Tomaru, Ryota; Done, Chris; Odaka, Hirokazu; Watanabe, Shin; Takahashi, Tadayuki

    2018-05-01

    Blueshifted absorption lines from highly ionized iron are seen in some high inclination X-ray binary systems, indicating the presence of an equatorial disc wind. This launch mechanism is under debate, but thermal driving should be ubiquitous. X-ray irradiation from the central source heats disc surface, forming a wind from the outer disc where the local escape velocity is lower than the sound speed. The mass-loss rate from each part of the disc is determined by the luminosity and spectral shape of the central source. We use these together with an assumed density and velocity structure of the wind to predict the column density and ionization state, then combine this with a Monte Carlo radiation transfer to predict the detailed shape of the absorption (and emission) line profiles. We test this on the persistent wind seen in the bright neutron star binary GX 13+1, with luminosity L/LEdd ˜ 0.5. We approximately include the effect of radiation pressure because of high luminosity, and compute line features. We compare these to the highest resolution data, the Chandra third-order grating spectra, which we show here for the first time. This is the first physical model for the wind in this system, and it succeeds in reproducing many of the features seen in the data, showing that the wind in GX13+1 is most likely a thermal-radiation driven wind. This approach, combined with better streamline structures derived from full radiation hydrodynamic simulations, will allow future calorimeter data to explore the detail wind structure.

  15. Monte-Carlo simulations of the detailed iron absorption line profiles from thermal winds in X-ray binaries

    Science.gov (United States)

    Tomaru, Ryota; Done, Chris; Odaka, Hirokazu; Watanabe, Shin; Takahashi, Tadayuki

    2018-02-01

    Blue-shifted absorption lines from highly ionised iron are seen in some high inclination X-ray binary systems, indicating the presence of an equatorial disc wind. This launch mechanism is under debate, but thermal driving should be ubiquitous. X-ray irradiation from the central source heats disc surface, forming a wind from the outer disc where the local escape velocity is lower than the sound speed. The mass loss rate from each part of the disc is determined by the luminosity and spectral shape of the central source. We use these together with an assumed density and velocity structure of the wind to predict the column density and ionisation state, then combine this with a Monte-Carlo radiation transfer to predict the detailed shape of the absorption (and emission) line profiles. We test this on the persistent wind seen in the bright neutron star binary GX 13+1, with luminosity L/LEdd ˜ 0.5. We approximately include the effect of radiation pressure because of high luminosity, and compute line features. We compare these to the highest resolution data, the Chandra third order grating spectra, which we show here for the first time. This is the first physical model for the wind in this system, and it succeeds in reproducing many of the features seen in the data, showing that the wind in GX13+1 is most likely a thermal-radiation driven wind. This approach, combined with better streamline structures derived from full radiation hydrodynamic simulations, will allow future calorimeter data to explore the detail wind structure.

  16. Unsteady Sisko magneto-nanofluid flow with heat absorption and temperature dependent thermal conductivity: A 3D numerical study

    Science.gov (United States)

    Khan, Masood; Ahmad, Latif; Gulzar, M. Mudassar

    2018-03-01

    The impact of temperature dependent thermal conductivity and convective surface conditions on unsteady 3D Sisko nanofluid flow over a stretching surface is studied in the presence of heat generation/absorption and magnetic field. The numerical solution of nonlinear coupled equations has been carried out to explore the properties of different physical profiles of the fluid flow with varying of parameters. Specifically, the application of generalized Biot numbers and heat generation/absorption parameter in the sketching of temperature and concentration profiles are explored. The effect of all three parameters is noticed in the increasing order for shear thinning (0 1) fluids. Moreover, the influence of Biot number γ1 on heat and mass transfer rates, are found in the enhancement and diminishing conducts respectively, in both cases of shear thinning as well as shear thickening fluids and a reverse trend is observed with the variation of Biot number γ2 . Additionally, the present results are validated through skin friction, heat and mass transfer rate values with the comparable values in the existing previous values.

  17. MERCURY QUANTIFICATION IN SOILS USING THERMAL DESORPTION AND ATOMIC ABSORPTION SPECTROMETRY: PROPOSAL FOR AN ALTERNATIVE METHOD OF ANALYSIS

    Directory of Open Access Journals (Sweden)

    Liliane Catone Soares

    2015-08-01

    Full Text Available Despite the considerable environmental importance of mercury (Hg, given its high toxicity and ability to contaminate large areas via atmospheric deposition, little is known about its activity in soils, especially tropical soils, in comparison with other heavy metals. This lack of information about Hg arises because analytical methods for determination of Hg are more laborious and expensive compared to methods for other heavy metals. The situation is even more precarious regarding speciation of Hg in soils since sequential extraction methods are also inefficient for this metal. The aim of this paper is to present a technique of thermal desorption associated with atomic absorption spectrometry, TDAAS, as an efficient tool for quantitative determination of Hg in soils. The method consists of the release of Hg by heating, followed by its quantification by atomic absorption spectrometry. It was developed by constructing calibration curves in different soil samples based on increasing volumes of standard Hg2+ solutions. Performance, accuracy, precision, and quantification and detection limit parameters were evaluated. No matrix interference was detected. Certified reference samples and comparison with a Direct Mercury Analyzer, DMA (another highly recognized technique, were used in validation of the method, which proved to be accurate and precise.

  18. Thermal frequency shift and tunable microwave absorption in BiFeO3 family

    OpenAIRE

    Li, Yong; Fang, Xiaoyong; Cao, Maosheng

    2016-01-01

    Tunable frequency is highly sought-after task of researcher, because of the potential for applications in selecting frequency, absorber, imaging and biomedical diagnosis. Here, we report the original observation of thermal frequency shift of dielectric relaxation in La/Nd doped BiFeO3 (BFO) in X-band from 300 to 673?K. It exhibits an unexpected result: the relaxation shifts to lower frequency with increasing temperature. The relaxation maximally shifts about a quarter of X-band. The nonlinear...

  19. Semi-Empirical Validation of the Cross-Band Relative Absorption Technique for the Measurement of Molecular Mixing Ratios

    Science.gov (United States)

    Pliutau, Denis; Prasad, Narasimha S

    2013-01-01

    Studies were performed to carry out semi-empirical validation of a new measurement approach we propose for molecular mixing ratios determination. The approach is based on relative measurements in bands of O2 and other molecules and as such may be best described as cross band relative absorption (CoBRA). . The current validation studies rely upon well verified and established theoretical and experimental databases, satellite data assimilations and modeling codes such as HITRAN, line-by-line radiative transfer model (LBLRTM), and the modern-era retrospective analysis for research and applications (MERRA). The approach holds promise for atmospheric mixing ratio measurements of CO2 and a variety of other molecules currently under investigation for several future satellite lidar missions. One of the advantages of the method is a significant reduction of the temperature sensitivity uncertainties which is illustrated with application to the ASCENDS mission for the measurement of CO2 mixing ratios (XCO2). Additional advantages of the method include the possibility to closely match cross-band weighting function combinations which is harder to achieve using conventional differential absorption techniques and the potential for additional corrections for water vapor and other interferences without using the data from numerical weather prediction (NWP) models.

  20. Modeling the thermo-acoustic effects of thermal-dependent speed of sound and acoustic absorption of biological tissues during focused ultrasound hyperthermia.

    Science.gov (United States)

    López-Haro, S A; Gutiérrez, M I; Vera, A; Leija, L

    2015-10-01

    To evaluate the effects of thermal dependence of speed of sound (SOS) and acoustic absorption of biological tissues during noninvasive focused ultrasound (US) hyperthermia therapy. A finite element (FE) model was used to simulate hyperthermia therapy in the liver by noninvasive focused US. The model consisted of an ultrasonic focused transducer radiating a four-layer biological medium composed of skin, fat, muscle, and liver. The acoustic field and temperature distribution along the layers were obtained after 15 s of hyperthermia therapy using the bio-heat equation. The model solution was found with and without the thermal dependence of SOS and acoustic absorption of biological tissues. The inclusion of the thermal dependence of the SOS generated an increment of 0.4 mm in the longitudinal focus axis of the acoustic field. Moreover, results indicate an increment of the hyperthermia area (zone with temperature above 43 °C), and a maximum temperature difference of almost 3.5 °C when the thermal dependence of absorption was taken into account. The increment of the achieved temperatures at the treatment zone indicated that the effects produced by the thermal dependence of SOS and absorption must be accounted for when planning hyperthermia treatment in order to avoid overheating undesired regions.

  1. Temperature-dependent cross sections of O2-O2 collision-induced absorption resonances at 477 and 577nm

    International Nuclear Information System (INIS)

    Sneep, Maarten; Ityaksov, Dmitry; Aben, Ilse; Linnartz, Harold; Ubachs, Wim

    2006-01-01

    Two collision-induced absorption features of oxygen have been investigated by means of the laser-based cavity ring-down technique at pressures between 0 and 1000hPa and at temperatures in the range 184-294K. Peak cross sections, resonance widths and integrated cross sections, as well as spectral profiles, have been determined for the broad O 2 -O 2 resonances centered at 477 and 577nm. Results are compared with previous measurements to establish an updated temperature dependence for the cross sections of both resonances, yielding integrated cross sections, that exhibit a minimum near 200K and that increase in a near-linear fashion in the atmospherically relevant range of 200-300K. A significant increase in the widths of the resonance profiles upon temperature increase is firmly established. Parameters and temperature-dependent trends for the shape and strengths of the resonances are produced, that can be implemented in cloud retrieval in atmospheric Earth observation

  2. Measurements of thermal neutron capture cross sections for some FP nuclides

    International Nuclear Information System (INIS)

    Nakamura, Shoji; Furutaka, Kazuyoshi; Harada, Hideo; Katoh, Toshio

    1999-01-01

    The thermal neutron capture cross sections (σ 0 ) and the resonance integrals (I 0 ) of some FP elements, such as 80 Se, 94 Zr, 124 Sn, 127 I and 133 Cs, were measured by the activation and γ-ray spectroscopic method. (author)

  3. Pickering emulsions stabilized by whey protein nanoparticles prepared by thermal cross-linking

    NARCIS (Netherlands)

    Wu, Jiande; Shi, Mengxuan; Li, Wei; Zhao, Luhai; Wang, Ze; Yan, Xinzhong; Norde, Willem; Li, Yuan

    2015-01-01

    A Pickering (o/w) emulsion was formed and stabilized by whey protein isolate nanoparticles (WPI NPs). Those WPI NPs were prepared by thermal cross-linking of denatured WPI proteins within w/o emulsion droplets at 80. °C for 15. min. During heating of w/o emulsions containing 10% (w/v) WPI

  4. Absorption fluids data survey

    Science.gov (United States)

    Macriss, R. A.; Zawacki, T. S.

    Development of improved data for the thermodynamic, transport and physical properties of absorption fluids were studied. A specific objective of this phase of the study is to compile, catalog and coarse screen the available US data of known absorption fluid systems and publish it as a first edition document to be distributed to manufacturers, researchers and others active in absorption heat pump activities. The methodology and findings of the compilation, cataloguing and coarse screening of the available US data on absorption fluid properties and presents current status and future work on this project are summarized. Both in house file and literature searches were undertaken to obtain available US publications with pertinent physical, thermodynamic and transport properties data for absorption fluids. Cross checks of literature searches were also made, using available published bibliographies and literature review articles, to eliminate secondary sources for the data and include only original sources and manuscripts. The properties of these fluids relate to the liquid and/or vapor state, as encountered in normal operation of absorption equipment employing such fluids, and to the crystallization boundary of the liquid phase, where applicable. The actual data were systematically classified according to the type of fluid and property, as well as temperature, pressure and concentration ranges over which data were available. Data were sought for 14 different properties: Vapor-Liquid Equilibria, Crystallization Temperature, Corrosion Characteristics, Heat of Mixing, Liquid-Phase-Densities, Vapor-Liquid-Phase Enthalpies, Specific Heat, Stability, Viscosity, Mass Transfer Rate, Heat Transfer Rate, Thermal Conductivity, Flammability, and Toxicity.

  5. Measurement of the multi-TeV neutrino interaction cross-section with IceCube using Earth absorption

    Science.gov (United States)

    Aartsen, M. G.; Hill, G. C.; Kyriacou, A.; Robertson, S.; Wallace, A.; Whelan, B. J.; Ackermann, M.; Bernardini, E.; Blot, S.; Bradascio, F.; Bretz, H.-P.; Brostean-Kaiser, J.; Franckowiak, A.; Jacobi, E.; Karg, T.; Kintscher, T.; Kunwar, S.; Nahnhauer, R.; Satalecka, K.; Spiering, C.; Stachurska, J.; Stasik, A.; Strotjohann, N. L.; Terliuk, A.; Usner, M.; van Santen, J.; Adams, J.; Bagherpour, H.; Aguilar, J. A.; Ansseau, I.; Heereman, D.; Meagher, K.; Meures, T.; O'Murchadha, A.; Pinat, E.; Raab, C.; Ahlers, M.; Koskinen, D. J.; Larson, M. J.; Medici, M.; Rameez, M.; Ahrens, M.; Bohm, C.; Dumm, J. P.; Finley, C.; Flis, S.; Hultqvist, K.; Walck, C.; Zoll, M.; Al Samarai, I.; Bron, S.; Carver, T.; Christov, A.; Montaruli, T.; Altmann, D.; Anton, G.; Glüsenkamp, T.; Katz, U.; Kittler, T.; Tselengidou, M.; Andeen, K.; Plum, M.; Anderson, T.; Delaunay, J. J.; Dunkman, M.; Eller, P.; Huang, F.; Keivani, A.; Lanfranchi, J. L.; Pankova, D. V.; Teši´, G.; Turley, C. F.; Weiss, M. J.; Argüelles, C.; Axani, S.; Collin, G. H.; Conrad, J. M.; Moulai, M.; Auffenberg, J.; Brenzke, M.; Glauch, T.; Haack, C.; Kalaczynski, P.; Koschinsky, J. P.; Leuermann, M.; Rädel, L.; Reimann, R.; Rongen, M.; Sälzer, T.; Schoenen, S.; Schumacher, L.; Stettner, J.; Vehring, M.; Vogel, E.; Wallraff, M.; Waza, A.; Wiebusch, C. H.; Bai, X.; Barron, J. P.; Giang, W.; Grant, D.; Kopper, C.; Moore, R. W.; Nowicki, S. C.; Herrera, S. E. Sanchez; Sarkar, S.; Wandler, F. D.; Weaver, C.; Wood, T. R.; Woolsey, E.; Yanez, J. P.; Barwick, S. W.; Yodh, G.; Baum, V.; Böser, S.; di Lorenzo, V.; Eberhardt, B.; Ehrhardt, T.; Köpke, L.; Krückl, G.; Momenté, G.; Peiffer, P.; Sandroos, J.; Steuer, A.; Wiebe, K.; Bay, R.; Filimonov, K.; Price, P. B.; Woschnagg, K.; Beatty, J. J.; Tjus, J. Becker; Bos, F.; Eichmann, B.; Kroll, M.; Schöneberg, S.; Tenholt, F.; Becker, K.-H.; Bindig, D.; Helbing, K.; Hickford, S.; Hoffmann, R.; Lauber, F.; Naumann, U.; Pollmann, A. Obertacke; Soldin, D.; Benzvi, S.; Cross, R.; Berley, D.; Blaufuss, E.; Cheung, E.; Felde, J.; Friedman, E.; Hellauer, R.; Hoffman, K. D.; Maunu, R.; Olivas, A.; Schmidt, T.; Song, M.; Sullivan, G. W.; Besson, D. Z.; Binder, G.; Klein, S. R.; Miarecki, S.; Palczewski, T.; Tatar, J.; Börner, M.; Fuchs, T.; Hünnefeld, M.; Meier, M.; Menne, T.; Pieloth, D.; Rhode, W.; Ruhe, T.; Sandrock, A.; Schlunder, P.; Soedingrekso, J.; Werthebach, J.; Bose, D.; Dujmovic, H.; in, S.; Jeong, M.; Kang, W.; Kim, J.; Rott, C.; Botner, O.; Burgman, A.; Hallgren, A.; Pérez de Los Heros, C.; Unger, E.; Bourbeau, J.; Braun, J.; Casey, J.; Chirkin, D.; Day, M.; Desiati, P.; Díaz-Vélez, J. C.; Fahey, S.; Ghorbani, K.; Griffith, Z.; Halzen, F.; Hanson, K.; Hokanson-Fasig, B.; Hoshina, K.; Jero, K.; Karle, A.; Kauer, M.; Kelley, J. L.; Kheirandish, A.; Liu, Q. R.; Luszczak, W.; Mancina, S.; McNally, F.; Merino, G.; Schneider, A.; Tobin, M. N.; Tosi, D.; Ty, B.; Vandenbroucke, J.; Wandkowsky, N.; Wendt, C.; Westerhoff, S.; Wille, L.; Wolf, M.; Wood, J.; Xu, D. L.; Yuan, T.; Brayeur, L.; Casier, M.; de Clercq, C.; de Vries, K. D.; de Wasseige, G.; Kunnen, J.; Lünemann, J.; Maggi, G.; Toscano, S.; van Eijndhoven, N.; Clark, K.; Classen, L.; Kappes, A.; Coenders, S.; Huber, M.; Krings, K.; Rea, I. C.; Resconi, E.; Turcati, A.; Cowen, D. F.; de André, J. P. A. M.; Deyoung, T.; Hignight, J.; Lennarz, D.; Mahn, K. B. M.; Micallef, J.; Neer, G.; Rysewyk, D.; Dembinski, H.; Evenson, P. A.; Gaisser, T. K.; Gonzalez, J. G.; Koirala, R.; Pandya, H.; Seckel, D.; Stanev, T.; Tilav, S.; De Ridder, S.; Labare, M.; Ryckbosch, D.; van Driessche, W.; Vanheule, S.; Vraeghe, M.; de With, M.; Hebecker, D.; Kolanoski, H.; Fazely, A. R.; Ter-Antonyan, S.; Xu, X. W.; Gallagher, J.; Gerhardt, L.; Goldschmidt, A.; Nygren, D. R.; Przybylski, G. T.; Stezelberger, T.; Stokstad, R. G.; Ishihara, A.; Kim, M.; Kuwabara, T.; Lu, L.; Mase, K.; Relich, M.; Stößl, A.; Yoshida, S.; Japaridze, G. S.; Jones, B. J. P.; Kiryluk, J.; Lesiak-Bzdak, M.; Niederhausen, H.; Xu, Y.; Kohnen, G.; Kopper, S.; Nakarmi, P.; Pepper, J. A.; Toale, P. A.; Williams, D. R.; Kowalski, M.; Kurahashi, N.; Relethford, B.; Richman, M.; Wills, L.; Madsen, J.; Seunarine, S.; Spiczak, G. M.; Maruyama, R.; Rawlins, K.; Sarkar, S.; Sutherland, M.; Taboada, I.; Tung, C. F.; IceCube Collaboration

    2017-11-01

    Neutrinos interact only very weakly, so they are extremely penetrating. The theoretical neutrino-nucleon interaction cross-section, however, increases with increasing neutrino energy, and neutrinos with energies above 40 teraelectronvolts (TeV) are expected to be absorbed as they pass through the Earth. Experimentally, the cross-section has been determined only at the relatively low energies (below 0.4 TeV) that are available at neutrino beams from accelerators. Here we report a measurement of neutrino absorption by the Earth using a sample of 10,784 energetic upward-going neutrino-induced muons. The flux of high-energy neutrinos transiting long paths through the Earth is attenuated compared to a reference sample that follows shorter trajectories. Using a fit to the two-dimensional distribution of muon energy and zenith angle, we determine the neutrino-nucleon interaction cross-section for neutrino energies 6.3-980 TeV, more than an order of magnitude higher than previous measurements. The measured cross-section is about 1.3 times the prediction of the standard model, consistent with the expectations for charged- and neutral-current interactions. We do not observe a large increase in the cross-section with neutrino energy, in contrast with the predictions of some theoretical models, including those invoking more compact spatial dimensions or the production of leptoquarks. This cross-section measurement can be used to set limits on the existence of some hypothesized beyond-standard-model particles, including leptoquarks.

  6. Effect of thermal treatment on the electrochemical hydrogen absorption of ZrCrNi alloy

    Energy Technology Data Exchange (ETDEWEB)

    Ruiz, F.C.; Peretti, H.A.; Corso, H.L [Centro Atomico Bariloche, Comision Nacional de Energia Atomica, Bariloche (Argentina); Visintin, A.; Real, S.G.; Castro, E.B.; Triaca, W.E. [Univ. Nacional de La Plata, La Plata (Argentina). Inst. de Investigaciones Fisiquimicas Teoricas y Aplicadas

    2006-07-01

    The catalytic effect of the secondary phases contained in a ZrCrNi alloy on its electrochemical properties was investigated. The purpose of the study was to improve the performance of Ni-MH battery electrodes. Four samples of the alloy were given annealing treatments at T=1250 K at variable times to obtain different concentrations of the secondary phases. Phase structure, morphology, and composition were studied using X-ray diffraction; radiation; scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS) microanalysis. Results of the study were compatible with the presence of a major AB{sub 2} phase of C15 structure and the co-existence of C14 and C15 structures in both the as-melted and annealed alloys. The effect of the annealing in the ZrCrNi alloy resulted in a remarkable reduction of the discharge capacity and activation that was attributed to the dissolution of the secondary phases. The major catalytic effect was associated with the Zr{sub 8}Ni{sub 21} phase, by increasing the discharge capacity and favouring the activation. It was concluded that the presence of the catalytic phase in the alloy increased the hydrogen absorption capacity of the electrode due to an enhancement of the hydrogen production by electrolysis on the metal/catalytic phase and electrolyte interface. 6 refs., 1 fig.

  7. Total absorption and photoionization cross sections of water vapor between 100 and 1000 A

    Science.gov (United States)

    Haddad, G. N.; Samson, J. A. R.

    1986-01-01

    Absolute photoabsorption and photoionization cross sections of water vapor are reported at a large number of discrete wavelengths between 100 and 1000 A with an estimate error of + or - 3 percent in regions free from any discrete structure. The double ionization chamber technique utilized is described. Recent calculations are shown to be in reasonable agreement with the present data.

  8. Measuring Thermal Conductivity and Moisture Absorption of Cryo-Insulation Materials

    Science.gov (United States)

    Lambert, Michael A.

    1998-01-01

    NASA is seeking to develop thermal insulation material systems suitable for withstanding both extremely high temperatures encountered during atmospheric re-entry heating and aero- braking maneuvers, as well as extremely low temperatures existing in liquid fuel storage tanks. Currently, materials used for the high temperature insulation or Thermal Protection System (TPS) are different from the low temperature, or cryogenic insulation. Dual purpose materials are necessary to the development of reusable launch vehicles (RLV). The present Space Shuttle (or Space Transportation System, STS) employs TPS materials on the orbiter and cryo-insulation materials on the large fuel tank slung under the orbiter. The expensive fuel tank is jettisoned just before orbit is achieved and it burns up while re-entering over the Indian Ocean. A truly completely reusable launch vehicle must store aR cryogenic fuel internally. The fuel tanks will be located close to the outer surface. In fact the outer skin of the craft will probably also serve as the fuel tank enclosure, as in jet airliners. During a normal launch the combined TPS/cryo-insulation system will serve only as a low temperature insulator, since aerodynamic heating is relatively minimal during ascent to orbit. During re-entry, the combined TPS/cryo-insulation system will serve only as a high temperature insulator, since all the cryogenic fuel will have been expended in orbit. However, in the event of an.aborted launch or a forced/emergency early re-entry, the tanks will still contain fuel, and the TPS/cryo-insulation will have to serve as both low and high temperature insulation. Also, on long duration missions, such as to Mars, very effective cryo-insulation materials are needed to reduce bod off of liquid propellants, thereby reducing necessary tankage volume, weight, and cost. The conventional approach to obtaining both low and high temperature insulation, such as is employed for the X-33 and X-34 spacecraft, is to use

  9. Effect of AgCl NPs: Physical, thermal, absorption and luminescence properties

    Science.gov (United States)

    Nurhafizah, H.; Rohani, M. S.

    2017-06-01

    Silver nanoparticles (AgCl NPs) are embedded in Er3+/Nd3+ co-doped lithium niobate tellurite glasses of the form (68-x)TeO2-15Li2CO3-15Nb2O5-1Er2O3-1Nd2O3-(x)AgCl with x = 1,2 and 3 mol% via conventional melt-quenching technique. The physical properties such as density, ionic packing density, refractive index and electronic polarizability are computed utilizing the usual method. The existence of AgCl NPs with an average size of 3.7 nm is confirmed using TEM analysis. Moreover, the thermal stability and Hruby criterion of the glass decreases as the AgCl NPs content increases. The direct optical band gap are found decrease as the AgCl NPs content increase, but both indirect optical band gap and Urbach energy are found increases as AgCl NPs content increases. The luminescence spectra shows two strong emission which is the purple emission at 436 nm and red emission at 724 nm which also been observed has strong quenching due to the AgCl NPs, Er3+/Nd3+ dopant and modifier, lithium niobate which possessed magnetic penetration. These glass compositions may be potential for various applications such as solid state devices including laser.

  10. An expression for the atomic fluorescence and thermal-emission intensity under conditions of near saturation and arbitrary self-absorption

    NARCIS (Netherlands)

    Omenetto, N.; Winefordner, J.D.; Alkemade, C.T.J.

    An expression for the effect of self-absorption on the fluorescence and thermal emission intensities is derived by taking into account stimulated emission. A simple, idealized case is considered, consisting of a two level atomic system, in a flame, homogeneous with respect to temperature and

  11. Characterization of Thermally Cross-Linkable Hollow Fiber Membranes for Natural Gas Separation

    KAUST Repository

    Chen, Chien-Chiang

    2013-01-23

    The performance of thermally cross-linkable hollow fiber membranes for CO2/CH4 separation and the membrane stability against CO2 plasticization was investigated. The fiber membranes were thermally cross-linked at various conditions. Cross-linking temperature was found to have a significant effect, while shorter soak time and the presence of trace oxidizer (O2 or N2O) had a negligible effect. The cross-linked fibers were tested using high CO2 content feeds (50-70% CO2) at a variety of feed pressures (up to 1000 psia), temperatures, and permeate pressures (up to 100 psia) to evaluate membrane performance under various realistic operating conditions. The results demonstrated that cross-linking improves membrane selectivity and effectively eliminates swelling-induced hydrocarbon loss at high pressures. Excellent stability under aggressive feeds (with CO2 partial pressure up to 700 psia) suggests that cross-linked hollow fiber membranes have great potential for use in diverse aggressive applications, even beyond the CO2/CH4 example explored in this work. © 2012 American Chemical Society.

  12. Thermal/chemical degradation of ceramic cross-flow filter materials

    Energy Technology Data Exchange (ETDEWEB)

    Alvin, M.A.; Lane, J.E.; Lippert, T.E.

    1989-11-01

    This report summarizes the 14-month, Phase 1 effort conducted by Westinghouse on the Thermal/Chemical Degradation of Ceramic Cross-Flow Filter Materials program. In Phase 1 expected filter process conditions were identified for a fixed-bed, fluid-bed, and entrained-bed gasification, direct coal fired turbine, and pressurized fluidized-bed combustion system. Ceramic cross-flow filter materials were also selected, procured, and subjected to chemical and physical characterization. The stability of each of the ceramic cross-flow materials was assessed in terms of potential reactions or phase change as a result of process temperature, and effluent gas compositions containing alkali and fines. In addition chemical and physical characterization was conducted on cross-flow filters that were exposed to the METC fluid-bed gasifier and the New York University pressurized fluidized-bed combustor. Long-term high temperature degradation mechanisms were proposed for each ceramic cross-flow material at process operating conditions. An experimental bench-scale test program is recommended to be conducted in Phase 2, generating data that support the proposed cross-flow filter material thermal/chemical degradation mechanisms. Papers on the individual subtasks have been processed separately for inclusion on the data base.

  13. Radiative efficiencies and global warming potentials using theoretically determined absorption cross-sections for several hydrofluoroethers (HFEs) and hydrofluoropolyethers (HFPEs)

    International Nuclear Information System (INIS)

    Bravo, Ivan; Marston, George; Nutt, David R.; Shine, Keith P.

    2011-01-01

    Integrated infrared cross-sections and wavenumber positions for the vibrational modes of a range of hydrofluoroethers (HFEs) and hydrofluoropolyethers (HFPEs) have been calculated. Spectra were determined using a density functional method with an empirically derived correction for the wavenumbers of band positions. Radiative efficiencies (REs) were determined using the Pinnock et al. method and were used with atmospheric lifetimes from the literature to determine global warming potentials (GWPs). For the HFEs and the majority of the molecules in the HG series HFPEs, theoretically determined absorption cross-sections and REs lie within ca. 10% of those determined using measured spectra. For the larger molecules in the HG series and the HG' series of HFPEs, agreement is less good, with theoretical values for the integrated cross-sections being up to 35% higher than the experimental values; REs are up to 45% higher. Our method gives better results than previous theoretical approaches, because of the level of theory chosen and, for REs, because an empirical wavenumber correction derived for perfluorocarbons is effective in predicting the positions of C-F stretching frequencies at around 1250 cm -1 for the molecules considered here.

  14. Simultaneous measurement of thermal diffusivity and effective infrared absorption coefficient in IR semitransparent and semiconducting n-CdMgSe crystals using photothermal radiometry

    Energy Technology Data Exchange (ETDEWEB)

    Pawlak, M., E-mail: mpawlak@fizyka.umk.pl [Institute of Physics, Faculty of Physics, Astronomy and Informatics, Nicolaus Copernicus University, Grudziądzka 5/7, Toruń (Poland); Maliński, M. [Department of Electronics and Computer Science, Koszalin University of Technology, 2 Śniadeckich St., Koszalin 75-453 (Poland)

    2015-01-10

    Highlights: • The new method of determination of the effective infrared absorption coefficient is presented. • The method can be used for transparent samples for the excitation radiation. • The effect of aluminum foil on the PTR signal in a transmission configuration is discussed. - Abstract: In this paper we propose a new procedure of simultaneous estimation of the effective infrared optical absorption coefficient and the thermal diffusivity of solid state samples using the photothermal infrared radiometry method in the transmission configuration. The proposed procedure relies on the analysis of the frequency dependent signal obtained from the samples covered with thin aluminum foil. This method can be applied for both optically opaque and transparent samples. The proposed method is illustrated with the results of the thermal diffusivity and the effective IR absorption coefficient obtained for several Cd{sub 1−x}Mg{sub x}Se crystals.

  15. On the performance of heat absorption/generation and thermal stratification in mixed convective flow of an Oldroyd-B fluid

    Directory of Open Access Journals (Sweden)

    Tasawar Hayat

    2017-12-01

    Full Text Available This investigation explores the thermally stratified stretchable flow of an Oldroyd-B material bounded by a linear stretched surface. Heat transfer characteristics are addressed through thermal stratification and heat generation/absorption. Formulation is arranged for mixed convection. Application of suitable transformations provides ordinary differential systems through partial differential systems. The homotopy concept is adopted for the solution of nonlinear differential systems. The influence of several arising variables on velocity and temperature is addressed. Besides this, the rate of heat transfer is calculated and presented in tabular form. It is noticed that velocity and Nusselt number increase when the thermal buoyancy parameter is enhanced. Moreover, temperature is found to decrease for larger values of Prandtl number and heat absorption parameter. Comparative analysis for limiting study is performed and excellent agreement is found.

  16. Thermal design of lithium bromide-water solution vapor absorption cooling system for indirect evaporative cooling for IT pod

    Science.gov (United States)

    Sawant, Digvijay Ramkrishna

    Nowadays with increase use of internet, mobile there is increase in heat which ultimately increases the efficient cooling system of server room or IT POD. Use of traditional ways of cooling system has ultimately increased CO2 emission and depletion of CFC's are serious environmental issues which led scientific people to improve cooling techniques and eliminate use of CFC's. To reduce dependency on fossil fuels and 4environmental friendly system needed to be design. For being utilizing low grade energy source such as solar collector and reducing dependency on fossil fuel vapour absorption cooling system has shown a great driving force in today's refrigeration systems. This LiBr-water aabsorption cooling consists of five heat exchanger namely: Evaporator, Absorber, Solution Heat Exchanger, Generator, Condenser. The thermal design was done for a load of 23 kW and the procedure was described in the thesis. There are 120 servers in the IT POD emitting 196 W of heat each on full load and some of the heat was generated by the computer placed inside the IT POD. A detailed procedure has been discussed. A excel spreadsheet was to prepared with varying tube sizes to see the effect on flows and ultimately overall heat transfer coefficient.

  17. Thermal characteristics and mass absorption efficiency of carbonaceous aerosol measured during a post-harvest burning period

    Science.gov (United States)

    Batmunkh, T.; Kim, Y. J.; Cayetano, M. G.; Lee, K.; Kim, K.; Park, K.

    2012-12-01

    In order to better understand the characteristics of carbonaceous aerosol time-resolved OC, EC, and BC were measured by a Sunset OC/EC analyzer and an Aethalometer, respectively, during a post-harvest burning period from November 22 to December 20, 2011 at a sub-urban site in Gwangju, Korea. OC and EC were analyzed by the thermal-optical transmittance (TOT) method with NIOSH temperature protocol. The spectral light absorption coefficient (babs) was determined based on the Aethalometer data. Overall average OC and EC concentrations were found to be 5.0±2.4 ugC/ m3 and 1.5±0.9 ugC/ m3, respectively for the sampling period. On average, babs at seven Aethalometer wavelengths was found to be 38.4±27.8 Mm-1, 24.3±17.8 Mm-1, 20.8±15.4 Mm-1, 17.9±13.3 Mm-1, 14.9±11.1 Mm-1, 9.9±7.4 Mm-1, and 8.8±6.6 Mm-1 at 370 nm, 470 nm, 520 nm, 590 nm, 660 nm, 880 nm, and 950 nm, respectively. Clear diurnal variations with morning (7:00 AM~9:00 AM) and evening (7:00 PM~11:00 PM) peaks were observed for OC, EC, and babs mostly due to local burning activities. Based on the 4-day back-trajectory analyses conducted using the HYSPLIT model. Event cases were classified into four categories, based on the 4-day air mass back trajectories, as Clean(C), Stagnant(ST), Continental(CC), and Local Burning(LB) events. In order to better investigate the characteristics of atmospheric carbonaceous aerosol, thermal evolution patterns of carbonaceous aerosol measured by the Sunset analyzer were characterized as OC1, OC2, and EC, which were detected in temperature steps of 600 C, 840 C in an non-oxidizing atmosphere, and 870 C in an oxidizing atmosphere, respectively. High ratio of OC2/OC1; 1.39~1.41 was observed in the evening 9:00~11:00 PM due to local burning event. Concentration of OC2 was higher up to 1.4 times than that of OC1 for the LB cases, showing that higher molecular weight fraction of organic aerosol was dominant for the time. As expected, higher correlation was found between EC and

  18. Effect of thermal radiation on free convection flow and heat transfer over a truncated cone in the presence of pressure work and heat generation/absorption

    Directory of Open Access Journals (Sweden)

    Elbashbeshy E.M.A.

    2016-01-01

    Full Text Available Effect of heat generation or absorption and thermal radiation on free convection flow and heat transfer over a truncated cone in the presence of pressure work is considered. The governing boundary layer equations are reduced to non-similarity boundary layer equations and solved numerically by using Mathematica technique. Comparisons with previously published work on special cases of the problem are performed and the results are found to be in excellent agreement. The solutions are presented in terms of local skin friction, local Nusselt number, velocity and temperature profiles for values of Prandtl number, pressure work parameter, radiation parameter and heat generation or absorption parameter.

  19. Measurement of the fission cross-section of 235U and 239Pu for thermal neutrons

    International Nuclear Information System (INIS)

    Fraysse, G.; Prosdocimi, A.; Netter, F.; Samour, C.

    1965-01-01

    Improved techniques of fast detection have been applied for determining the fission cross-sections of 235 U and 239 Pu with reference to the absorption cross-section of Boron. Monochromatic neutron beams of 0.0322 eV, 0.0626 eV and 0.275 eV have been employed. Use has been made of a Xe-filled gaseous scintillator and of a low-geometry solid state ion chamber. Both measured alpha and fission rates. The results at the reference energy of 0.0253 eV are: (σ F ) 0 235 U = 588 ± 10 barns (σ F ) 0 239 Pu = 738 ± 7 barns. (authors) [fr

  20. Size- and Wavelength-Dependent Two-Photon Absorption Cross-Section of CsPbBr3 Perovskite Quantum Dots

    NARCIS (Netherlands)

    Chen, Junsheng; Zidek, Karel; Chabera, Pavel; Liu, Dongzhou; Cheng, Pengfei; Nuuttila, Lauri; Al-Marri, Mohammed J.; Lehtivuori, Heli; Messing, Maria E.; Han, Keli; Zheng, Kaibo; Pullerits, Tonu

    2017-01-01

    All-inorganic colloidal perovskite quantum dots (QDs) based on cesium, lead, and halide have recently emerged as promising light emitting materials. CsPbBr3 QDs have also been demonstrated as stable two-photon-pumped lasing medium. However, the reported two photon absorption (TPA) cross sections for

  1. Study on the Cross Plane Thermal Transport of Polycrystalline Molybdenum Nanofilms by Applying Picosecond Laser Transient Thermoreflectance Method

    Directory of Open Access Journals (Sweden)

    Tingting Miao

    2014-01-01

    Full Text Available Thin metal films are widely used as interconnecting wires and coatings in electronic devices and optical components. Reliable thermophysical properties of the films are required from the viewpoint of thermal management. The cross plane thermal transport of four polycrystalline molybdenum nanofilms with different thickness deposited on glass substrates has been studied by applying the picosecond laser transient thermoreflectance technique. The measurement is performed by applying both front pump-front probe and rear pump-front probe configurations with high quality signal. The determined cross plane thermal diffusivity of the Mo films greatly decreases compared to the corresponding bulk value and tends to increase as films become thicker, exhibiting significant size effect. The main mechanism responsible for the thermal diffusivity decrease of the present polycrystalline Mo nanofilms is the grain boundary scattering on the free electrons. Comparing the cross plane thermal diffusivity and inplane electrical conductivity indicates the anisotropy of the transport properties of the Mo films.

  2. Thermal radiation and heat generation/absorption effects on viscoelastic double-diffusive convection from an isothermal sphere in porous media

    Directory of Open Access Journals (Sweden)

    S. Abdul Gaffar

    2015-09-01

    Full Text Available Buoyancy-driven convective heat and mass transfer in boundary layer flow of a viscoelastic Jeffrey fluid from a permeable isothermal sphere embedded in a porous medium is studied. Thermal radiation flux and heat generation/absorption are also incorporated in the model. A non-Darcy drag force model is employed to simulate the effects of linear porous media drag and second order Forchheimer drag. The Rosseland diffusion algebraic approximation is utilized to simulate thermal radiation effects. The non-dimensionalized boundary layer equations are solved using implicit, finite-difference scheme. The influence of Darcy number (Da, Deborah number (De, ratio of relaxation to retardation times (λ, radiation parameter (F, Forchheimer inertial parameter (Λ and heat generation/absorption parameter (Δ, on normalized velocity, temperature, concentration, skin friction, heat and mass transfer rates are also studied. The present study has applications in the storage of nuclear waste materials.

  3. Zinc Absorption from Milk Is Affected by Dilution but Not by Thermal Processing, and Milk Enhances Absorption of Zinc from High-Phytate Rice in Young Dutch Women.

    Science.gov (United States)

    Talsma, Elise F; Moretti, Diego; Ly, Sou Chheng; Dekkers, Renske; van den Heuvel, Ellen Ghm; Fitri, Aditia; Boelsma, Esther; Stomph, Tjeerd Jan; Zeder, Christophe; Melse-Boonstra, Alida

    2017-06-01

    Background: Milk has been suggested to increase zinc absorption. The effect of processing and the ability of milk to enhance zinc absorption from other foods has not been measured directly in humans. Objective: We aimed to assess zinc absorption from 1 ) milk undergoing various processing and preparatory steps and 2 ) from intrinsically labeled high-phytate rice consumed with milk or water. Methods: Two randomized crossover studies were conducted in healthy young women [age:18-25 y; body mass index (in kg/m 2 ): 20-25]: 1 ) a milk study ( n = 19) comparing the consumption of 800 mL full-fat ultra-high temperature (UHT) milk [heat-treated milk (HTM)], full-fat UHT milk diluted 1:1 with water [heat-treated milk and water (MW)], water, or unprocessed (raw) milk (UM), each extrinsically labeled with 67 Zn, and 2 ) a rice study ( n = 18) comparing the consumption of 90 g intrinsically 67 Zn-labeled rice with 600 mL of water [rice and water (RW)] or full-fat UHT milk [rice and milk (RM)]. The fractional absorption of zinc (FAZ) was measured with the double-isotope tracer ratio method. In vitro, we assessed zinc extraction from rice blended into water, UM, or HTM with or without phytate. Results: FAZ from HTM was 25.5% (95% CI: 21.6%, 29.4%) and was not different from UM (27.8%; 95% CI: 24.2%, 31.4%). FAZ from water was higher (72.3%; 95% CI: 68.7%, 75.9%), whereas FAZ from MW was lower (19.7%; 95% CI: 17.5%, 21.9%) than HTM and UM (both P zinc from rice with HTM than from rice with water at various phytate concentrations. Conclusions: Milk enhanced human FAZ from high-phytate rice by 62% compared with water. Diluting milk with water decreases its absorption-enhancing proprieties, whereas UHT processing does not. This trial was registered at the Dutch trial registry as NTR4267 (http://www.trialregister.nl/trialreg/admin/rctview.asp?TC=4267). © 2017 American Society for Nutrition.

  4. Bioinspired composites from cross-linked galactoglucomannan and microfibrillated cellulose: Thermal, mechanical and oxygen barrier properties.

    Science.gov (United States)

    Oinonen, Petri; Krawczyk, Holger; Ek, Monica; Henriksson, Gunnar; Moriana, Rosana

    2016-01-20

    In this study, new wood-inspired films were developed from microfibrillated cellulose and galactoglucomannan-lignin networks isolated from chemothermomechanical pulping side streams and cross-linked using laccase enzymes. To the best of our knowledge, this is the first time that cross-linked galactoglucomannan-lignin networks have been used for the potential development of composite films inspired by woody-cell wall formation. Their capability as polymeric matrices was assessed based on thermal, structural, mechanical and oxygen permeability analyses. The addition of different amounts of microfibrillated cellulose as a reinforcing agent and glycerol as a plasticizer on the film performances was evaluated. In general, an increase in microfibrillated cellulose resulted in a film with better thermal, mechanical and oxygen barrier performance. However, the presence of glycerol decreased the thermal stability, stiffness and oxygen barrier properties of the films but improved their elongation. Therefore, depending on the application, the film properties can be tailored by adjusting the amounts of reinforcing agent and plasticizer in the film formulation. Copyright © 2015 Elsevier Ltd. All rights reserved.

  5. Determination of the Moessbauer absorption cross section and reconstruction of hyperfine field distribution by the maximum entropy method

    Energy Technology Data Exchange (ETDEWEB)

    Satula, D; Szymanski, K; Dobrzynski, L, E-mail: satula@alpha.uwb.edu.p [Faculty of Physics, University of Bialystok, 41 Lipowa Street, 15-424 Bialystok (Poland)

    2010-07-28

    Determination of the Moessbauer absorption cross section, {sigma}(E), and accurate reconstruction of the hyperfine field distributions of the invar alloy, Fe{sub 64}Ni{sub 36}, by the maximum entropy method (MEM) is presented. The procedure consists of three steps: deconvolution of the Moessbauer spectra with the instrumental resolution function using MEM, nonlinear transformation of the deconvoluted spectrum into {sigma}(E), and reconstruction of the hyperfine field distribution. In order to test the procedure of the deconvolution and correction for thickness effect, several simulated spectra with thickness parameter 1 < t < 50 and different values of Lorentzian FWHM of the source and absorber were analyzed. It is shown that the procedure of the deconvolution and extraction of {sigma}(E) works well for spectra whose lines contain at least five experimental points per FWHM. Reconstructed distributions of hyperfine field parameters, based on the extracted Moessbauer cross section of the Fe-Ni invar alloy, measured with and without application of an external magnetic field, are discussed. The reconstruction has been made to test the earlier postulated non-collinear ferromagnetic state of invar without referring to any specific model in the analysis of the Moessbauer results. It is shown that marginal probability distribution of hyperfine magnetic field consists of the main maximum at about 28 T and a broad tail extending down to 5 T. Observed isomer shift of the main maximum is small and positive. The isomer shift decreases with magnetic field and attains negative values at the lowest fields. It is shown that the magnetic texture parameter does not depend on the hyperfine magnetic field. One thus concludes that in the invar Ni-Fe alloys, in contrast to some theoretical predictions, there is no evidence for different arrangements of the iron magnetic moments as a function of the magnetic hyperfine field.

  6. T-junction cross-flow mixing with thermally driven density stratification

    Energy Technology Data Exchange (ETDEWEB)

    Kickhofel, John, E-mail: jkickhofel@gmail.com [Laboratory of Nuclear Energy Systems, ETH Zurich, Sonneggstrasse 3, 8057 Zurich (Switzerland); Prasser, Horst-Michael, E-mail: prasser@lke.mavt.ethz.ch [Laboratory of Nuclear Energy Systems, ETH Zurich, Sonneggstrasse 3, 8057 Zurich (Switzerland); Selvam, P. Karthick, E-mail: karthick.selvam@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany); Laurien, Eckart, E-mail: eckart.laurien@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany); Kulenovic, Rudi, E-mail: rudi.kulenovic@ike.uni-stuttgart.de [Institute of Nuclear Technology and Energy Systems (IKE), University of Stuttgart, Pfaffenwaldring 31, 70569 Stuttgart (Germany)

    2016-12-01

    Highlights: • Mesh sensor for realistic nuclear thermal hydraulic scenarios is demonstrated. • Flow temperature behavior across a wide range of Richardson numbers measured. • Upstream stratified flow in the T-junction results in a thermal shock scenario. • Large, stable near-wall thermal gradients exist in spite of turbulent flows. - Abstract: As a means of further elucidating turbulence- and stratification-driven thermal fatigue in the vicinity of T-junctions in nuclear power plants, a series of experiments have been conducted at the high temperature high pressure fluid–structure interaction T-junction facility of the University of Stuttgart with novel fluid measurement instrumentation. T-junction mixing with large fluid temperature gradients results in complex flow behavior, the result of density driven effects. Deionized water mixing at temperature differences of up to 232 K at 7 MPa pressure have been investigated in a T-junction with main pipe diameter 71.8 mm and branch line diameter 38.9 mm. The experiments have been performed with fixed flow rates of 0.4 kg/s in the main pipe and 0.1 kg/s in the branch line. A novel electrode-mesh sensor compatible with the DN80 PN100 pipeline upstream and downstream of the T-junction has been utilized as a temperature sensor providing a high density information in the pipe cross-section in both space and time. Additionally, in-flow and in-wall thermocouples quantify the damping of thermal fluctuations by the wall material. The results indicate that large inflow temperature differences lead to strong turbulence damping, and ultimately stable stratification extending both downstream and upstream of the T-junction resulting in large local thermal gradients.

  7. Numerical investigation of MHD free convection flow of a non-Newtonian fluid past an impulsively started vertical plate in the presence of thermal diffusion and radiation absorption

    Directory of Open Access Journals (Sweden)

    M. Umamaheswar

    2016-09-01

    Full Text Available A numerical investigation is carried out on an unsteady MHD free convection flow of a well-known non-Newtonian visco elastic second order Rivlin-Erickson fluid past an impulsively started semi-infinite vertical plate in the presence of homogeneous chemical reaction, thermal radiation, thermal diffusion, radiation absorption and heat absorption with constant mass flux. The presence of viscous dissipation is also considered at the plate under the influence of uniform transverse magnetic field. The flow is governed by a coupled nonlinear system of partial differential equations which are solved numerically by using finite difference method. The effects of various physical parameters on the flow quantities viz. velocity, temperature, concentration, Skin friction, Nusselt number and Sherwood number are studied numerically. The results are discussed with the help of graphs. We observed that the velocity decreases with an increase in magnetic field parameter, Schmidt number, and Prandtl number while it increases with an increase in Grashof number, modified Grashof number, visco-elastic parameter and Soret number. Temperature increases with an increase in radiation absorption parameter, Eckert number and visco-elastic parameter while it decreases with increasing values of radiation parameter, Prandtl number and heat absorption parameter. Concentration increases with increase in Soret number while it decreases with an increase in Schmidt number and chemical reaction parameter.

  8. Thermal neutron capture cross section of chromium, vanadium, titanium and nickel isotopes

    International Nuclear Information System (INIS)

    Venturini, L.; Pecequilo, B.R.S.

    1990-04-01

    The thermal neutron cross section of chromium, vanadium, titanium and nickel can be determined by measuring the pair spectrum of prompt gamma-rays emitted targets of these elements are irradiated by a thermal neutron beam. Such measurements were carried out by irradiating the natural element mixed with a nitrogen standard (melamine) in the tangential beam hole of the IEA-R1 research reactor. The pair spectrometer efficiency calibration curve in the 1.5 to 11 MeV energy range was performed with a melamine plus ammonium chloride mixed target. The cross section was calculated for the most prominent gamma transitions of each isotope, using nitrogen as standard and averaged over the obtained values. The resulting mean cross sections are as follows: (13.4 ± 0.7)b for 50 Cr, (0.79 ± 0,02)b for 52 Cr, (18.1 ± 0,7)b for 53 Cr, (4.9 ± 0.2)b for 51 V, (8.4 ± 0.1)b for 48 Ti, (4.41 ± 0.08)b 58 Ni, (2.54 ± 0.07)b for 60 Ni, (15.2 ± 0.5)b for 62 Ni and (1.6 ± 0.1) for 64 Ni. (author) [pt

  9. Employing X-ray absorption technique for better detector resolution and measurement of low cross-section events

    Science.gov (United States)

    Sharma, Gaurav; Puri, Nitin K.; Kumar, Pravin; Nandi, T.

    2018-03-01

    The versatility of X-ray absorption technique is experimentally employed for enhancing the detector resolution and to rejuvenate the low probable transitions obscured in the pile-up region, during a beam-foil spectroscopy experiment. The multiple aluminum absorber layers (10 μm each) are used to suppress the pile-up contribution drastically and to restore a weak transition which is about 1.38 × 104 times weaker than a one-electron-one-photon transitions viz. Kα and Khα. The weak line is possibly originating from a two-electron-one-photon transition in He-like Ti. Further, the transitions, which were obscured in the spectra due to high intensity ratio, are revived by dissimilar line intensity attenuation using this technique. The measured lifetimes of Kα line with and without intensity attenuation match well within error bar. The present technique finds potential implications in understanding the structure of multiple-core-vacant ions and other low cross section processes in ion-solid collisions.

  10. Determination of the Mössbauer absorption cross section and reconstruction of hyperfine field distribution by the maximum entropy method.

    Science.gov (United States)

    Satuła, D; Szymański, K; Dobrzyński, L

    2010-07-28

    Determination of the Mössbauer absorption cross section, σ(E), and accurate reconstruction of the hyperfine field distributions of the invar alloy, Fe(64)Ni(36), by the maximum entropy method (MEM) is presented. The procedure consists of three steps: deconvolution of the Mössbauer spectra with the instrumental resolution function using MEM, nonlinear transformation of the deconvoluted spectrum into σ(E), and reconstruction of the hyperfine field distribution. In order to test the procedure of the deconvolution and correction for thickness effect, several simulated spectra with thickness parameter 1 invar alloy, measured with and without application of an external magnetic field, are discussed. The reconstruction has been made to test the earlier postulated non-collinear ferromagnetic state of invar without referring to any specific model in the analysis of the Mössbauer results. It is shown that marginal probability distribution of hyperfine magnetic field consists of the main maximum at about 28 T and a broad tail extending down to 5 T. Observed isomer shift of the main maximum is small and positive. The isomer shift decreases with magnetic field and attains negative values at the lowest fields. It is shown that the magnetic texture parameter does not depend on the hyperfine magnetic field. One thus concludes that in the invar Ni-Fe alloys, in contrast to some theoretical predictions, there is no evidence for different arrangements of the iron magnetic moments as a function of the magnetic hyperfine field.

  11. Thermal-hydraulically corrected neutron cross-sections for PWR reactors

    Energy Technology Data Exchange (ETDEWEB)

    Santiago, Daniela M.N.; Alvim, Antonio C.M.; Silva, Fernando C., E-mail: dsantiago@con.ufrj.b, E-mail: alvim@con.ufrj.b, E-mail: fernando@con.ufrj.b [Universidade Federal do Rio de Janeiro (PEN/COPPE/UFRJ), RJ (Brazil). Coordenacao dos Programas de Pos-Graduacao de Engenharia. Programa de Engenharia Nuclear

    2011-07-01

    Reactor core simulation codes ought to have a thermal-hydraulics feedback module. This module calculates, among other effects, the fuel temperature thermal-hydraulics feedback, that corrects neutron cross sections. In the nodal code developed at PEN/COPPE/UFRJ, the fuel temperature is obtained through an empirical model. This work presents a physical model to calculate this temperature. A finite volume technique was used to discretize the equation for temperature distribution, while the moderator coefficient of heat transfer was calculated using ASME routines, appended to the developed code. This model allows calculation of an average radial temperature per node, since the thermal-hydraulic feedback must follow the conditions imposed by the nodal code. The results obtained were compared with the ones obtained by the empirical model. The results show that, for fuel elements near core periphery, the empirical model overestimates the temperature in the fuel, as compared to our model, which may indicate that the physical model is more appropriate to calculate the thermal-hydraulic feedback temperatures. (author)

  12. Thermal-hydraulic feedback model to calculate the neutronic cross-section in PWR reactions

    International Nuclear Information System (INIS)

    Santiago, Daniela Maiolino Norberto

    2011-01-01

    In neutronic codes,it is important to have a thermal-hydraulic feedback module. This module calculates the thermal-hydraulic feedback of the fuel, that feeds the neutronic cross sections. In the neutronic co de developed at PEN / COPPE / UFRJ, the fuel temperature is obtained through an empirical model. This work presents a physical model to calculate this temperature. We used the finite volume technique of discretized the equation of temperature distribution, while calculation the moderator coefficient of heat transfer, was carried out using the ASME table, and using some of their routines to our program. The model allows one to calculate an average radial temperature per node, since the thermal-hydraulic feedback must follow the conditions imposed by the neutronic code. The results were compared with to the empirical model. Our results show that for the fuel elements near periphery, the empirical model overestimates the temperature in the fuel, as compared to our model, which may indicate that the physical model is more appropriate to calculate the thermal-hydraulic feedback temperatures. The proposed model was validated by the neutronic simulator developed in the PEN / COPPE / UFRJ for analysis of PWR reactors. (author)

  13. Thermal flexural analysis of cross-ply laminated plates using trigonometric shear deformation theory

    Directory of Open Access Journals (Sweden)

    Yuwaraj Marotrao Ghugal

    Full Text Available Thermal stresses and displacements for orthotropic, two-layer antisymmetric, and three-layer symmetric square cross-ply laminated plates subjected to nonlinear thermal load through the thickness of laminated plates are presented by using trigonometric shear deformation theory. The in-plane displacement field uses sinusoidal function in terms of thickness co-ordinate to include the shear deformation effect. The theory satisfies the shear stress free boundary conditions on the top and bottom surfaces of the plate. The present theory obviates the need of shear correction factor. Governing equations and boundary conditions of the theory are obtained using the principle of virtual work. The validity of present theory is verified by comparing the results with those of classical plate theory and first order shear deformation theory and higher order shear deformation theory.

  14. Unsteady optical and thermal behaviour of crossed compound parabolic concentrator with solar cell

    OpenAIRE

    Li, Wenguang; Paul, Manosh C.; Sellami, Nazmi; Mallick, Tapas K.; Knox, Andrew R.

    2015-01-01

    In reality, a solar panel with concentrator is\\ud subject to variable sunlight radiation, wind\\ud speed and environmental air temperature in a\\ud day, accordingly the solar output power is\\ud changed in a wide range of 2W-13W, causing\\ud a degraded electric performance [1-3]. Thus it\\ud is necessary to characterise optical and\\ud thermal behaviour of a crossed compound\\ud parabolic concentrator (CCPC) with solar cell\\ud in its design stage to optimise its configuration.\\ud Presently, the CCPC...

  15. Cross-protection between controlled acid-adaptation and thermal inactivation for 48 Escherichia coli strains.

    Science.gov (United States)

    Haberbeck, Leticia Ungaretti; Wang, Xiang; Michiels, Chris; Devlieghere, Frank; Uyttendaele, Mieke; Geeraerd, Annemie H

    2017-01-16

    Given the importance of pH reduction and thermal treatment in food processing and food preservation strategies, the cross-protection between acid adaptation and subsequent thermal inactivation for 48 Escherichia coli strains was investigated. Those strains were selected among 188 E. coli strains according to their odds of growth under low pH conditions as determined by Haberbeck et al. (2015) [Haberbeck, L.U., Oliveira, R.C., Vivijs, B., Wenseleers, T., Aertsen, A., Michiels, C., Geeraerd, A.H., 2015. Variability in growth/no growth boundaries of 188 different Escherichia coli strains reveals that approximately 75% have a higher growth probability under low pH conditions than E. coli O157:H7 strain ATCC 43888. Food Microbiol. 45, 222-230]. E. coli cells were acid and nonacid-adapted during overnight growth in controlled acidic pH (5.5) and neutral pH (7.0), respectively, in buffered Lysogenic Broth (LB). Then, they were heat inactivated at 58°C in non-buffered LB adjusted to pH6.2 and 7.0. Thus, four conditions were tested in total by combining the different pH values during growth/thermal inactivation: 5.5/6.2, 5.5/7.0, 7.0/6.2 and 7.0/7.0. Acid adaptation in buffered LB at pH5.5 increased the heat resistance of E. coli strains in comparison with nonacid-adaptation at pH7.0. For instance, the median D 58 -value of strains inactivated at pH7.0 was approximately 6 and 4min for acid-adapted and nonacid-adapted strains, respectively. For the nonacid-adapted strains, the thermal inactivation at pH6.2 and 7.0 was not significantly (p=0.06) different, while for the acid-adapted strains, the thermal treatment at pH6.2 showed a higher heat resistance than at pH7.0. The correlation between the odds of growth under low pH previously determined and the heat resistance was significant (pcoli O157:H7 (ATCC 43888) showed D 58 -values between 1.2 and 3.1min. In summary, results clearly showed that adaptation of E. coli cells to constant acidic pH results in cross

  16. Measurement of {sup 238}Np fission cross-section by neutrons near thermal point (preliminary results)

    Energy Technology Data Exchange (ETDEWEB)

    Abramo; vich, S.N.; Andreev, M.F.; Bol`shakov, Y.M. [Institute of Experimental Physics, Arzamas (Russian Federation)] [and others

    1995-10-01

    Measurements have been carried out of {sup 238}Np fission cross-section by thermal neutrons. The isotope {sup 238}Np was built up through the reaction {sup 238}U(p,n) on an electrostatic accelerator. Extraction and cleaning of the sample were done by ion-exchange chromatography. Fast neutrons were generated on the electrostatic accelerator through the reaction {sup 9}Be(d,n); a polyethylene block was used to slow down neutrons. Registration of fission fragments was performed with dielectric track detectors. Suggesting that the behavior of {sup 238}Np and {sup 238}U. Westscott`s factors are indentical the fission cross-section of {sup 238}Np was obtained: {sigma}{sub fo}=2110 {plus_minus} 75 barn.

  17. Neutron-capture-activation cross sections of 9496Zr and 98100Mo at thermal and 30 keV energy

    International Nuclear Information System (INIS)

    Wyrick, J.M.; Poenitz, W.P.

    1982-01-01

    Neutron-capture cross sections of 94 96 Zr and 98 100 Mo were measured relative to the standard-capture cross section of gold at thermal and 30 keV neutron energies using the activation technique. The reported values are based upon available decay-scheme information

  18. Evaluation of thermal neutron cross-sections and resonance integrals of protactinium, americium, curium, and berkelium isotopes

    International Nuclear Information System (INIS)

    Belanova, T.S.

    1994-12-01

    Data on the thermal neutron fission and capture cross-sections as well as their corresponding resonance integrals are reviewed and analysed. The data are classified according to the form of neutron spectra under investigation. The weighted mean values of the cross-sections and resonance integrals for every type of neutron spectra were adopted as evaluated data. (author). 87 refs, 2 tabs

  19. Multifunctional polymethylsilsesquioxane (PMSQ) surfaces prepared by electrospinning at the sol-gel transition: superhydrophobicity, excellent solvent resistance, thermal stability and enhanced sound absorption property.

    Science.gov (United States)

    Xiang, Haifan; Zhang, Liang; Wang, Zhen; Yu, Xiaolan; Long, Yuhua; Zhang, Xiaoli; Zhao, Ning; Xu, Jian

    2011-07-01

    Multifunctional superhydrophobic polymethylsilsesquioxane (PMSQ) surfaces with excellent solvent resistance, thermal stability and enhanced sound absorption property were manufactured by electrospinning. The surfaces with various hierarchical morphologies and hydrophobicity were obtained by electrospinning at the different stages of sol-gel transition of PMSQ prepolymer solution. At the stage with a proper viscosity the superhydrophobic PMSQ surface with a contact angle as high as 151° and a sliding angle as low as 8° was prepared. Due to the excellent thermal stability and solvent resistance properties of the cured PMSQ, the resultant surfaces remain superhydrophobicity after thermal treatment at 300 °C and immersion into many solvents. Additionally, an enhanced acoustical performance and ultra water repellency were obtained simultaneously when the traditional acoustical sponge was decorated with the electrospun PMSQ superhydrophobic surface. The robust superhydrophobic PMSQ surfaces may promise practical applications in many fields. Copyright © 2011 Elsevier Inc. All rights reserved.

  20. Novel thermally cross-linked polyimide membranes for ethanol dehydration via pervaporation

    KAUST Repository

    Xu, Sheng

    2015-12-01

    © 2015 Elsevier B.V. In this work, two novel carboxyl-containing polyimides, 2,2\\'-bis(3,4-dicarboxyphenyl) hexafluoropropane dianhydride-4,4\\'-diaminodiphenylmethane/3,5-diaminobenzoic acid (6FDA-MDA/DABA, FMD) and 3,3\\',4,4\\'-benzophenone tetracarboxylic dianhydride-4,4\\'-diaminodiphenylmethane/3,5-diaminobenzoic acid (BTDA-MDA/DABA, BMD), are synthesized via chemical and thermal imidization methods, respectively, and employed as pervaporation membranes for ethanol dehydration. Chemical structures of the two polyimides are examined by FTIR and TGA to confirm the successful synthesis. A post thermal treatment of the polyimide membranes with the temperature range of 250 to 400. °C is applied, and its effects on the membrane morphology and separation performance are studied and characterized by FTIR, TGA, WXRD, solubility and sorption test. It is believed that the thermal treatment of the carboxyl-containing polyimide membrane at a relative low temperature only leads to the physical annealing, while it may cause the decarboxylation-induced cross-linking at a higher temperature. In addition, the operation temperature in pervaporation is also varied and shown to be an important factor to affect the final membrane performance. Performance benchmarking shows that the developed polyimide membranes both have superior pervaporation performance to most other flat-sheet dense membranes. This work is believed to shed useful insights on polyimide membranes for pervaporation applications.

  1. Performance analysis of single stage libr-water absorption machine operated by waste thermal energy of internal combustion engine: Case study

    Science.gov (United States)

    Sharif, Hafiz Zafar; Leman, A. M.; Muthuraman, S.; Salleh, Mohd Najib Mohd; Zakaria, Supaat

    2017-09-01

    Combined heating, cooling, and power is also known as Tri-generation. Tri-generation system can provide power, hot water, space heating and air -conditioning from single source of energy. The objective of this study is to propose a method to evaluate the characteristic and performance of a single stage lithium bromide-water (LiBr-H2O) absorption machine operated with waste thermal energy of internal combustion engine which is integral part of trigeneration system. Correlations for computer sensitivity analysis are developed in data fit software for (P-T-X), (H-T-X), saturated liquid (water), saturated vapor, saturation pressure and crystallization temperature curve of LiBr-H2O Solution. Number of equations were developed with data fit software and exported into excel work sheet for the evaluation of number of parameter concerned with the performance of vapor absorption machine such as co-efficient of performance, concentration of solution, mass flow rate, size of heat exchangers of the unit in relation to the generator, condenser, absorber and evaporator temperatures. Size of vapor absorption machine within its crystallization limits for cooling and heating by waste energy recovered from exhaust gas, and jacket water of internal combustion engine also presented in this study to save the time and cost for the facilities managers who are interested to utilize the waste thermal energy of their buildings or premises for heating and air conditioning applications.

  2. Mass energy-absorption coefficients and average atomic energy-absorption cross-sections for amino acids in the energy range 0.122-1.330 MeV

    Energy Technology Data Exchange (ETDEWEB)

    More, Chaitali V., E-mail: chaitalimore89@gmail.com; Lokhande, Rajkumar M.; Pawar, Pravina P., E-mail: pravinapawar4@gmail.com [Department of physics, Dr. Babasaheb Ambedkar Marathwada University, Aurangabad 431004 (India)

    2016-05-06

    Mass attenuation coefficients of amino acids such as n-acetyl-l-tryptophan, n-acetyl-l-tyrosine and d-tryptophan were measured in the energy range 0.122-1.330 MeV. NaI (Tl) scintillation detection system was used to detect gamma rays with a resolution of 8.2% at 0.662 MeV. The measured attenuation coefficient values were then used to determine the mass energy-absorption coefficients (σ{sub a,en}) and average atomic energy-absorption cross sections (μ{sub en}/ρ) of the amino acids. Theoretical values were calculated based on XCOM data. Theoretical and experimental values are found to be in good agreement.

  3. Organic, cross-linking, and shape-stabilized solar thermal energy storage materials: A reversible phase transition driven by broadband visible light

    International Nuclear Information System (INIS)

    Wang, Yunming; Tang, Bingtao; Zhang, Shufen

    2014-01-01

    Graphical abstract: Organic shape-stabilized solar thermal energy storage materials (OCSPCMs) with broadband harvesting for visible light were obtained by crosslinking and color matching, which provided a new platform for improving the efficiency of solar radiation utilization. - Highlights: • Novel phase change materials (OCSPCMs) were obtained by crosslinking and color matching. • The η of the OCSPCM was higher than 0.74 (visible light from 400 nm to 700 nm). • The phase change latent heats of the OCSPCMs were more than 120 J/g. • The OCSPCM has excellent form-stable effect during phase change process. - Abstract: Broadband visible sunlight usage and shape-stabilized effect were achieved using organic, cross-linking, and shape-stabilized phase-changed materials (OCSPCMs) with broadband visible light absorption, which were obtained by cross-linking reticulation and color matching (yellow, red, and blue) according to solar irradiation energy density. The obtained OCSPCMs exhibited excellent form-stable phase-change energy storage and broadband visible light-harvesting. Under broadband irradiation (from 400 nm to 700 nm), the light-to-heat conversion and the thermal energy storage efficiency (η > 0.74) of the OCSPCMs were significantly improved upon solar irradiation by color matching compared with those of OCSPCMs with single-band selective absorption of visible light (yellow, red, or blue). Differential scanning calorimetric results indicated that the phase change temperatures and latent heats of OCSPCMs ranged from 32.6 °C to 60.2 °C and from 120.1 J/g to 132.7 J/g, respectively. The novel materials show a reversible (more than 200 cycles) phase transition via ON/OFF switching of visible light irradiation

  4. Thermal annealing and UV irradiation effects on structure, morphology, photoluminescence and optical absorption spectra of EDTA-capped ZnS nanoparticles

    Science.gov (United States)

    Osman, M. A.; Othman, A. A.; El-Said, Waleed A.; Abd-Elrahim, A. G.; Abu-sehly, A. A.

    2016-02-01

    Monodispersed ZnS nanoparticles (NPs) were prepared by the chemical precipitation method. Thermally induced structural, morphological and optical changes have been investigated using x-ray diffraction, high-resolution transmission electron microscopy, optical absorption, photoluminescence (PL), and Fourier transform infrared and Raman spectroscopy. It was found that D increases with increasing annealing temperature (T a). The onset of the ZnS phase transition from cubic to hexagonal structure takes place at 400 °C, while cubic ZnS transforms into hexagonal ZnO via thermal oxidation in air at 600 °C. It is also noted that increasing T a results in the red shift of the optical band gap (E\\text{g}\\text{opt} ) and the thermal bleaching of exciton absorption. The PL spectrum of as-prepared ZnS nanopowder shows UV emission bands at 363 and 395 nm and blue and green emission at 438 and 515 nm, respectively. With increasing T a up to 500 °C, these bands were quenched and red-shifted. In addition, the UV irradiation effects on colloidal ZnS NPs were investigated. UV irradiation at a dose  ZnS NPs was discussed and an energy band diagram was proposed.

  5. Thermal neutron capture cross sections resonance integrals and g-factors

    CERN Document Server

    Mughabghab, S F

    2003-01-01

    The thermal radiative capture cross sections and resonance integrals of elements and isotopes with atomic numbers from 1 to 83 (as well as sup 2 sup 3 sup 2 Th and sup 2 sup 3 sup 8 U) have been re-evaluated by taking into consideration all known pertinent data published since 1979. This work has been undertaken as part of an IAEA co-ordinated research project on 'Prompt capture gamma-ray activation analysis'. Westcott g-factors for radiative capture cross sections at a temperature of 300K were computed by utilizing the INTER code and ENDF-B/VI (Release 8) library files. The temperature dependence of the Westcott g-factor is illustrated for sup 1 sup 1 sup 3 Cd, sup 1 sup 2 sup 4 Xe and sup 1 sup 5 sup 7 Gd at temperatures of 150, 294 and 400K. Comparisons have also been made of the newly evaluated capture cross sections of sup 6 Li, sup 7 Li, sup 1 sup 2 C and sup 2 sup 0 sup 7 Pb with those determined by the k sub 0 method.

  6. Direct Determination of Absolute Absorption Cross Sections at the L-Edge of Dilute Mn Complexes in Solution Using a Transmission Flatjet.

    Science.gov (United States)

    Kubin, Markus; Guo, Meiyuan; Ekimova, Maria; Baker, Michael L; Kroll, Thomas; Källman, Erik; Kern, Jan; Yachandra, Vittal K; Yano, Junko; Nibbering, Erik T J; Lundberg, Marcus; Wernet, Philippe

    2018-04-10

    The 3d transition metals play a pivotal role in many charge transfer processes in catalysis and biology. X-ray absorption spectroscopy at the L-edge of metal sites probes metal 2p-3d excitations, providing key access to their valence electronic structure, which is crucial for understanding these processes. We report L-edge absorption spectra of Mn II (acac) 2 and Mn III (acac) 3 complexes in solution, utilizing a liquid flatjet for X-ray absorption spectroscopy in transmission mode. With this, we derive absolute absorption cross-sections for the L-edge transitions with peak magnitudes as large as 12 and 9 Mb for Mn II (acac) 2 and Mn III (acac) 3 , respectively. We provide insight into the electronic structure with ab initio restricted active space calculations of these L-edge transitions, reproducing the experimental spectra with excellent agreement in terms of shapes, relative energies, and relative intensities for the two complexes. Crystal field multiplet theory is used to assign spectral features in terms of the electronic structure. Comparison to charge transfer multiplet calculations reveals the importance of charge transfer in the core-excited final states. On the basis of our experimental observations, we extrapolate the feasibility of 3d transition metal L-edge absorption spectroscopy using the liquid flatjet approach in probing highly dilute biological solution samples and possible extensions to table-top soft X-ray sources.

  7. High-precision Measurement of the 238U(n,γ) Cross Section with the Total Absorption Calorimeter (TAC) at n_TOF, CERN

    CERN Document Server

    Wright, T; Billowes, J; Ware, T; Cano-Ott, D; Mendoza, E; Massimi, C; Mingrone, F; Gunsing, F; Berthoumieux, E; Lampoudis, C; Altstadt, S; Andrzejewski, J; Audouin, L; Barbagallo, M; Bécares, V; Bečvář, F; Belloni, F; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Colonna, N; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Domingo-Pardo, C; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Giubrone, G; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Käppeler, F; Karadimos, D; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krtička, M; Kroll, J; Langer, C; Lederer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Meaze, M; Mengoni, A; Milazzo, P M; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Tagliente, G; Tain, J L; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Weigand, M; Weiß, C; Žugec, P

    2014-01-01

    The neutron capture cross section of U-238 is fundamental to the design and operation of current reactors and future fast nuclear reactors, and thus must be measured to a high level of accuracy. An experiment has been performed at the CERN n TOF facility using a 4 pi Total Absorption Calorimeter (TAC) to measure the capture cross section in the resolved resonance region between 1 eV and 25 keV. A preliminary analysis of the TAC data is presented with particular emphasis to the experimental background in this energy region of interest.

  8. Size- and Wavelength-Dependent Two-Photon Absorption Cross-Section of CsPbBr3 Perovskite Quantum Dots.

    Science.gov (United States)

    Chen, Junsheng; Žídek, Karel; Chábera, Pavel; Liu, Dongzhou; Cheng, Pengfei; Nuuttila, Lauri; Al-Marri, Mohammed J; Lehtivuori, Heli; Messing, Maria E; Han, Keli; Zheng, Kaibo; Pullerits, Tõnu

    2017-05-18

    All-inorganic colloidal perovskite quantum dots (QDs) based on cesium, lead, and halide have recently emerged as promising light emitting materials. CsPbBr 3 QDs have also been demonstrated as stable two-photon-pumped lasing medium. However, the reported two photon absorption (TPA) cross sections for these QDs differ by an order of magnitude. Here we present an in-depth study of the TPA properties of CsPbBr 3 QDs with mean size ranging from 4.6 to 11.4 nm. By using femtosecond transient absorption (TA) spectroscopy we found that TPA cross section is proportional to the linear one photon absorption. The TPA cross section follows a power law dependence on QDs size with exponent 3.3 ± 0.2. The empirically obtained power-law dependence suggests that the TPA process through a virtual state populates exciton band states. The revealed power-law dependence and the understanding of TPA process are important for developing high performance nonlinear optical devices based on CsPbBr 3 nanocrystals.

  9. Numerical solution of Williamson fluid flow past a stretching cylinder and heat transfer with variable thermal conductivity and heat generation/absorption

    Directory of Open Access Journals (Sweden)

    M. Y. Malik

    2016-03-01

    Full Text Available In this article, Williamson fluid flow and heat transfer over a stretching cylinder is discussed. The thermal conductivity is assumed to be vary linearly with temperature. Heat generation/absorption effects are also taken into account. Modeled partial differential equations are converted into ordinary differential form by using appropriate transformations. Shooting method in conjunction with Runge-Kutta-Fehlberg method is used to find the solution of the problem. Moreover, the effects of different flow parameters γ, λ, ϵ, β and Pr on velocity and temperature profiles are shown graphically. Local Nusselt number and skin friction coefficient are shown in tabular and graphical form.

  10. Water absorption and viscosity behaviour of thermally stable novel graft copolymer of carboxymethyl cellulose and poly(sodium 1-hydroxy acrylate).

    Science.gov (United States)

    Kumar, Bijender; Negi, Yuvraj Singh

    2018-02-01

    A novel thermally stable hydrolysed carboxymethyl cellulose-g-poly(sodium 1-hydroxy acrylate) i.e. CMC-g-PNaHA graft copolymer was synthesized from the CMC and vinyl monomer 5-methylene-2-isopropyl-1,3-dioxolan-4-one (MD) in an aqueous medium using an initiator followed by transformation of resulting CMC-g-PMD via alkaline hydrolysis. The graft copolymerization is confirmed by the Fourier transform infrared spectroscopy (FT-IR), Nuclear magnetic resonance spectroscopy (NMR) and X-ray diffractometer (XRD). The influence of the CMC and PNaHA content on the properties of the resulting hydrolysed CMC-g-PNaHA graft copolymer was investigated. In comparison with the PNaHA polymer, the resulted hydrolysed CMC-g-PNaHA grafted copolymer has improved thermal stability, water absorption properties, viscosity and weight-average molecular weight. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. UV Absorption Cross Sections of Nitrous Oxide (N2O) and Carbon Tetrachloride (CCl4) Between 210 and 350 K and the Atmospheric Implications

    Science.gov (United States)

    Carlon, Nabilah Rontu; Papanastasiou, Dimitrios K.; Fleming, Eric L.; Jackman, Charles H.; Newman, Paul A.; Burkholder, James B.

    2010-01-01

    Absorption cross sections of nitrous oxide (N2O) and carbon tetrachloride (CCl4) are reported at five atomic UV lines (184.95, 202.548, 206.200, 213.857, and 228.8 nm) at 27 temperatures in the range 210-350 K. In addition, UV absorption spectra of CCl4 are reported between 200-235 nm as a function of temperature (225-350 K). The results from this work are critically compared with results from earlier studies. For N2O, the present results are in good agreement with the current JPL recommendation enabling a reduction in the estimated uncertainty in the N2O atmospheric photolysis rate. For CCl4, the present cross section results are systematically greater than the current recommendation at the reduced temperatures most relevant to stratospheric photolysis. The new cross sections result in a 5-7% increase in the modeled CCl4 photolysis loss, and a slight decrease in the stratospheric lifetime, from 51 to 50 years, for present day conditions. The corresponding changes in modeled inorganic chlorine and ozone in the stratosphere are quite small. A CCl4 cross section parameterization for use in 37 atmospheric model calculations is presented.

  12. Revisiting the U-238 thermal capture cross section and gamma-raymission probabilities from Np-239 decay

    Energy Technology Data Exchange (ETDEWEB)

    Trkov, A.; Molnar, G.L.; Revay, Zs.; Mughabghab, S.F.; Firestone,R.B.; Pronyaev, V.G.; Nichols, A.L.; Moxon, M.C.

    2005-03-03

    The precise value of the thermal capture cross section of238U is uncertain, and evaluated cross sections from various sourcesdiffer by more than their assigned uncertainties. A number of theoriginal publications have been reviewed to assess the discrepant data,corrections were made for more recent standard cross sections andotherconstants, and one new measurement was analyzed. Due to the strongcorrelations in activation measurements, the gamma-ray emissionprobabilities from the beta decay of 239Np were also analyzed. As aresult of the analysis, a value of 2.683 +- 0.012 barns was derived forthe thermal capture cross section of 238U. A new evaluation of thegamma-ray emission probabilities from 239Np decay was alsoundertaken.

  13. Thermal-neutron fission cross section of 26.1-min /sup 235/U/sup m/

    International Nuclear Information System (INIS)

    Talbert, W.L. Jr.; Starner, J.W.; Estep, R.J.; Balestrini, S.J.; Attrep, M. Jr.; Efurd, D.W.; Roensch, F.R.

    1987-01-01

    The thermal-neutron fission cross section of /sup 235/U/sup m/ has been measured relative to the ground-state cross section. A rapid radiochemical separation procedure was developed to provide sizeable (10/sup 10/ to 10/sup 11/ atom) samples that were reasonably free of the parent /sup 239/Pu. From a series of eight measurements, the value of 1.42 +- 0.04 was obtained for the ratio σ/sub m//σ/sub g/

  14. Carbon-Starvation Induces Cross-Resistance to Thermal, Acid, and Oxidative Stress in Serratia marcescens

    Science.gov (United States)

    Pittman, Joseph R.; Kline, La’Kesha C.; Kenyon, William J.

    2015-01-01

    The broad host-range pathogen Serratia marcescens survives in diverse host and non-host environments, often enduring conditions in which the concentration of essential nutrients is growth-limiting. In such environments, carbon and energy source starvation (carbon-starvation) is one of the most common forms of stress encountered by S. marcescens. Related members of the family Enterobacteriaceae are known to undergo substantial changes in gene expression and physiology in response to the specific stress of carbon-starvation, enabling non-spore-forming cells to survive periods of prolonged starvation and exposure to other forms of stress (i.e., starvation-induced cross-resistance). To determine if carbon-starvation also results in elevated levels of cross-resistance in S. marcescens, both log-phase and carbon-starved cultures, depleted of glucose before the onset of high cell-density stationary-phase, were grown in minimal media at either 30 °C or 37 °C and were then challenged for resistance to high temperature (50 °C), low pH (pH 2.8), and oxidative stress (15 mM H2O2). In general, carbon-starved cells exhibited a higher level of resistance to thermal stress, acid stress, and oxidative stress compared to log-phase cells. The extent of carbon-starvation-induced cross-resistance was dependent on incubation temperature and on the particular strain of S. marcescens. In addition, strain- and temperature-dependent variations in long-term starvation survival were also observed. The enhanced stress-resistance of starved S. marcescens cells could be an important factor in their survival and persistence in many non-host environments and within certain host microenvironments where the availability of carbon sources is suboptimal for growth. PMID:27682115

  15. Carbon-Starvation Induces Cross-Resistance to Thermal, Acid, and Oxidative Stress in Serratia marcescens

    Directory of Open Access Journals (Sweden)

    Joseph R. Pittman

    2015-10-01

    Full Text Available The broad host-range pathogen Serratia marcescens survives in diverse host and non-host environments, often enduring conditions in which the concentration of essential nutrients is growth-limiting. In such environments, carbon and energy source starvation (carbon-starvation is one of the most common forms of stress encountered by S. marcescens. Related members of the family Enterobacteriaceae are known to undergo substantial changes in gene expression and physiology in response to the specific stress of carbon-starvation, enabling non-spore-forming cells to survive periods of prolonged starvation and exposure to other forms of stress (i.e., starvation-induced cross-resistance. To determine if carbon-starvation also results in elevated levels of cross-resistance in S. marcescens, both log-phase and carbon-starved cultures, depleted of glucose before the onset of high cell-density stationary-phase, were grown in minimal media at either 30 °C or 37 °C and were then challenged for resistance to high temperature (50 °C, low pH (pH 2.8, and oxidative stress (15 mM H2O2. In general, carbon-starved cells exhibited a higher level of resistance to thermal stress, acid stress, and oxidative stress compared to log-phase cells. The extent of carbon-starvation-induced cross-resistance was dependent on incubation temperature and on the particular strain of S. marcescens. In addition, strain- and temperature-dependent variations in long-term starvation survival were also observed. The enhanced stress-resistance of starved S. marcescens cells could be an important factor in their survival and persistence in many non-host environments and within certain host microenvironments where the availability of carbon sources is suboptimal for growth.

  16. High temperature infrared absorption cross sections of methane near 3.4 μm in Ar and CO2 mixtures

    Science.gov (United States)

    Koroglu, Batikan; Neupane, Sneha; Pryor, Owen; Peale, Robert E.; Vasu, Subith S.

    2018-02-01

    The absorption cross-sections of CH4 at two wavelengths in the mid-IR region: λpeak = 3403.4 nm and λvalley = 3403.7 nm were measured. Data were taken using three different compositions of non-reactive gas mixtures comprising CH4/Ar/CO2 between 700 methane cross section measurements were performed using a Fourier transform infrared spectrometer and the cascade laser to gain a better insight into the changes of the line shapes in various bath gasses (Ar, CO2, and N2). An application of the high-temperature cross-section data was demonstrated to determine the concentration of methane during oxy-methane combustion in a mixture of CO2, O2, and Ar. Current measurements will be valuable addition to the spectroscopy database for methane- an important fuel used for power generation and heating around the world.

  17. Mono- and diglycerides improve lutein absorption in healthy adults: a randomised, double-blind, cross-over, single-dose study.

    Science.gov (United States)

    Marriage, Barbara J; Williams, Jennifer A; Choe, Yong S; Maki, Kevin C; Vurma, Mustafa; DeMichele, Stephen J

    2017-11-01

    With the association between increased carotenoid intake and lower risk of chronic diseases, the absorption of lutein from the diet becomes an important factor in its delivery and physiological action. The primary objective of this study was to gain an understanding of how a new formulation technology (mixture of mono- and diglycerides (MDG)), affected lutein absorption. Subjects (n 24) were randomised in a cross-over, double-blind study to receive a single dose of 6 mg lutein (FloraGLO 20 %) provided as capsules containing either high-oleic safflower (SAF) oil or a MDG oil. Subjects receiving a single dose of lutein in MDG showed a significantly greater change from baseline (0 h) to 4, 6, 8, 12, 24, 48 and 336 h (Plutein at 48 and 336 h (Plutein in SAF. Analysis of the 48 h absorption kinetics of lutein showed that the time to peak level of lutein (12 h) was the same for SAF and MDG groups, but the change in plasma lutein at 12 and 48 h were 129 and 320 % higher, respectively, for MDG compared with SAF. This difference continued as the adjusted AUC 0-48 and 0-336 h for the MDG group was 232 and 900 % higher, respectively, v. SAF. The study data show that by changing the lipid that is combined with a lutein supplement results in significant increases in lutein absorption in healthy adults.

  18. Impact of thermal and organic acid treatment of feed on apparent ileal mineral absorption, tibial and liver mineral concentration, and tibia quality in broilers.

    Science.gov (United States)

    Hafeez, A; Mader, A; Boroojeni, F Goodarzi; Ruhnke, I; Röhe, I; Männer, K; Zentek, J

    2014-07-01

    Minerals play an important role for growth and bone stability in broilers. Thermal treatment and inclusion of organic acids in feed may affect the mineral absorption and tibial quality in broilers. The study was conducted to investigate the effect of thermal processing of feed including pelleting (P), long-term conditioning at 85°C (L), and expanding at 130°C (E) without and with 1.5% of an acid mixture containing 64% formic and 25% propionic acid on the apparent ileal absorption (AIA) of calcium, phosphorus, magnesium, potassium, sodium, iron, copper, manganese, and zinc, their concentrations in liver and tibia, as well as various tibial quality parameters in broilers. In total, 480 one-day-old Cobb broiler chicks were assigned using a completely randomized design with a 3 × 2 factorial arrangement. The ileal digesta, liver, and tibia were collected at d 35. The AIA of calcium and sodium was improved in group E compared with L (P ≤ 0.02 and P ≤ 0.01). Group P and E showed higher AIA for potassium than L (P ≤ 0.01). Bone ash content was increased in group E compared with L (P ≤ 0.04). The BW to bone weight ratio was lower and tibial zinc content was higher in group P compared with E (P ≤ 0.05). Tibial iron content was higher in group L than E (P ≤ 0.03). Acid addition did not affect AIA, mineral content in tibia, or tibial quality parameters. Thermal and acid treatment did not affect mineral concentrations in the liver, except an inconsistent interaction effect for DM content and sodium (P ≤ 0.03 and P ≤ 0.04, respectively). In conclusion, long-term thermal treatment reduced AIA of some minerals compared with short-term thermal treatments, but had no impact on tibia composition. Acid inclusion had no effect on AIA of minerals and tibia quality. Thermal treatment and the use of organic acids can therefore be considered as safe with regard to their impact on bone development in broilers. © 2014 Poultry Science Association Inc.

  19. Investigation of Water Absorption and Diffusion in Microparticles Containing Xylitol to Provide a Cooling Effect by Thermal Analysis

    Science.gov (United States)

    Salaün, F.; Bedek, G.; Devaux, E.; Dupont, D.; Deranton, D.

    2009-08-01

    Polyurethane microparticles containing xylitol as a sweat sensor system were prepared by interfacial polymerization. The structural and thermal properties of the resultant microparticles were studied. The surface morphology and chemical structure of microparticles were investigated using an optical microscope (OM) and a Fourier-transform infrared spectroscope (FTIR), respectively. The thermal properties of samples were investigated by thermogravimetric analysis (TGA) and by differential scanning calorimetry (DSC). Thus, two types of microparticles were synthesized by varying the percentage of monomers introduced. The obtained morphology is directly related to the synthesis conditions. DSC analysis indicated that the mass content of crystalline xylitol was up to 63.8 %, which resulted in a high enthalpy of dilution of 127.7 J · g-1. Furthermore, the water release rate monitored by TGA analysis was found to be faster from the microparticles than from raw xylitol. Thus, the microparticles could be applied for thermal energy storage and moisture sensor enhancement.

  20. On the thermally-induced residual stresses in thick fiber-thermoplastic matrix (PEEK) cross-ply laminated plates

    Science.gov (United States)

    Hu, Shoufeng; Nairn, John A.

    1992-01-01

    An analytical method for calculating thermally-induced residual stresses in laminated plates is applied to cross-ply PEEK laminates. We considered three cooling procedures: slow cooling (uniform temperature distribution); convective and radiative cooling; and rapid cooling by quenching (constant surface temperature). Some of the calculated stresses are of sufficient magnitude to effect failure properties such as matrix microcracking.

  1. Thermal behavior of J-aggregates in a Langmuir-Blodgett film of pure merocyanine dye investigated by UV-visible and IR absorption spectroscopy.

    Science.gov (United States)

    Hirano, Yoshiaki; Tateno, Shinsuke; Maio, Ari; Ozaki, Yukihiro

    2009-03-05

    We have characterized the structure of J-aggregate in a Langmuir-Blodgett film of pure merocyanine dye (MS18) fabricated under an aqueous subphase containing a cadmium ion (Cd2+) and have investigated its thermal behavior by UV-visible and IR absorption spectroscopy in the range from 25 to 250 degrees C with a continuous scan. The results of both UV-visible and IR absorption spectra indicate that temperature-dependent changes in the MS18 aggregation state in the pure MS18 system are closely and mildly linked with the MS18 intramolecular charge transfer and the behavior of the packing, orientation, conformation, and thermal mobility of MS18 hydrocarbon chain, respectively. The J-aggregate in the pure MS18 system dissociates from 25 to 150 degrees C, and the dissociation temperature at 150 degrees C is higher by 50 degrees C than that in the previous MS18- arachidic acid (C20) binary system. The lower dissociation temperature in the binary system originates from the fact that temperature-dependent structural disorder of cadmium arachidate (CdC20), being phase-separated from MS18, has an influence on the dissociation of J-aggregate. From 160 to 180 degrees C, thermally induced blue-shifted bands, caused by the oligomeric MS18 aggregation, appear at around 520 nm in the pure MS18 system by contraries, regardless of the lack of driving force by the melting phenomenon of CdC20. The temperature at which the 520 nm bands occur is in good agreement with the melting point (160 degrees C) of hydrocarbon chain in MS18 with Cd2+, whereas its chromophore part is clearly observed to melt near 205 degrees C by UV-visible spectra. Therefore, it is suggested that the driving force that induces the 520 nm band in the pure MS18 system arises from the partial melting of hydrocarbon chain in MS18 with Cd2+.

  2. A randomised cross-over trial in healthy adults indicating improved absorption of omega-3 fatty acids by pre-emulsification

    Directory of Open Access Journals (Sweden)

    Tang James

    2007-01-01

    Full Text Available Abstract Background The health benefits of increased intakes of omega-3 fatty acids are well established but palatability often presents a problem. The process of emulsification is used in the food industry to provide a wider spectrum of use, often with the result of increased consumption. Moreover, as emulsification is an important step in the digestion and absorption of fats, the pre-emulsification process may enhance digestion and absorption. In this study the levels of plasma fatty acid and triacylglycerol (TAG following the ingestion of either an oil mixture or an emulsified oil mixture have been compared. Methods In this randomised cross-over study, 13 volunteers received the oil mixture and 11 received the oil emulsion as part of an otherwise fat free meal. Blood samples were collected at 0, 1.5, 3, 4.5, 6, 7.5 and 9 hours after ingestion of oil, separated and stored at -20°C. Plasma triacylglycerols were assessed spectrophotometrically and fatty acids were determined by gas chromatography. Following a washout period of twenty days the procedure was repeated with the assignments reversed. Results The postprandial plasma TAG and the C18:3 (n-6, C18:3(n-3, C20:5(n-3 and C22:6 (n-3 polyunsaturated fatty acid (PUFA levels for the emulsified oil group were increased significantly (P = 0.0182; P = 0.0493; P = 0.0137; P Conclusion Pre-emulsification of an oil mixture prior to ingestion increases the absorption of longer chain more highly unsaturated fatty acids (especially eicosapentaenoic acid and docosahexaenoic acid but does not affect absorption of shorter chain less saturated fatty acids, suggesting that pre-emulsification of fish oils may be a useful means of boosting absorption of these beneficial fatty acids. Trial registration: Current Controlled Trials ISRCTN43202606

  3. Line strengths, A-factors and absorption cross-sections for fine structure lines in multiplets and hyperfine structure components in lines in atomic spectrometry - a user's guide

    International Nuclear Information System (INIS)

    Axner, Ove; Gustafsson, Joergen; Omenetto, Nicolo; Winefordner, James D.

    2004-01-01

    This work summarizes and elucidates a number of fundamental concepts in atomic spectrometry regarding the 'strengths' of transitions between various energy levels and states in atoms. Although several of the expressions and rules for line strengths of transitions reported here can be found, in one way or another, in various books dealing with atomic structure, atomic spectrometry or quantum mechanics, the treatment in such books can be variously complex and difficult to follow for a non-experienced reader. In addition, detailed information about transition-specific 'strengths' of transitions used to be restricted to line strengths, whereas most experiments rather need transition-specific A-factors or transition-specific absorption cross-sections. This work therefore aims at pointing out the most important aspects of the concept of 'strengths' of transitions between various energy levels and states in atoms by presenting explicit expressions for not only relative and absolute line strengths but also oscillator strengths (f-values), A-factors and absorption cross-sections, for transitions between fine structure levels within a multiplet as well as for hyperfine structure components within a line (i.e. between hyperfine structure levels), including their mutual relations, in a consistent and user-friendly manner. The work also recapitulates the most important summation rules for line strengths, oscillator strengths (f-values), A-factors and absorption cross-sections for lines within multiplets and hyperfine structure components within lines. Many of the expressions are illustrated with clear and intelligible examples. For the sake of clarity and completeness, the work also comprises a short review of the nomenclature for atomic structure and transitions

  4. Thermal radiation and heat generation/absorption aspects in third grade magneto-nanofluid over a slendering stretching sheet with Newtonian conditions

    Science.gov (United States)

    Qayyum, Sajid; Hayat, Tasawar; Alsaedi, Ahmed

    2018-05-01

    Mathematical modeling for magnetohydrodynamic (MHD) radiative flow of third grade nano-material bounded by a nonlinear stretching sheet with variable thickness is introduced. The sheet moves with nonlinear velocity. Definitions of thermal radiation and heat generation/absorption are utilized in the energy expression. Intention in present investigation is to develop a model for nanomaterial comprising Brownian motion and thermophoresis phenomena. Newtonian conditions for heat and mass species are imposed. Governing equations of the locally similar flow are attempted through a homotopic technique and behaviors of involved variables on the flow fields are displayed graphically. It is revealed that increasing values of thermal conjugate variable corresponds to high temperature. Numerical investigation are explored to obtain the results of skin friction coefficient and local Nusselt and Sherwood numbers. It is revealed that velocity field reduces in the frame of magnetic variable while reverse situation is observed due to mixed convection parameter. Here qualitative behaviors of thermal field and heat transfer rate are opposite for thermophoresis variable. Moreover nanoparticle concentration and local Sherwood number via Brownian motion parameter are opposite.

  5. Thermal diffusion of chlorine in uranium dioxide studied by secondary ion mass spectrometry and X-ray absorption spectroscopy

    Science.gov (United States)

    Pipon, Y.; Toulhoat, N.; Moncoffre, N.; Raimbault, L.; Scheidegger, A. M.; Farges, F.; Carlot, G.

    2007-05-01

    In a nuclear reactor, 35Cl present as an impurity in the nuclear fuel is activated by thermal neutron capture. During interim storage or geological disposal of the nuclear fuel, 36Cl may be released from the fuel to the geo/biosphere and contribute significantly to the 'instant release fraction'. In order to elucidate the diffusion mechanisms, both irradiation and thermal effects must be assessed. This paper deals with the thermal diffusion of chlorine in depleted UO2. For this purpose, sintered UO2 pellets were implanted with 37Cl at an ion fluence of 1013 cm-2 and successively annealed in the 1175-1475 K temperature range. The implanted chlorine is used to simulate the behaviour of the displaced one due to recoil and to interactions with the fission fragments during reactor operation. The behaviour of the pristine and the implanted chlorine was investigated during thermal annealing. SIMS and μ-XAS (at the Cl-K edge) analyses show that: the thermal migration of implanted chlorine becomes significant at 1275 K; this temperature and the calculated activation energy of 4.3 eV points out the great ability of chlorine to migrate in UO2 at relatively low temperatures, the behaviour of the implanted chlorine which aggregates into 'hot spots' during annealing before its effusion is clearly different from that of the pristine one which remains homogenously distributed after annealing, the 'hot spot' and the pristine chlorine seem to be in different structural environments. Both types of chlorine are assumed to have a valence state of -I, the comparison between an U2O2Cl5 reference compound and the pristine chlorine environment shows a contribution of the U2O2Cl5 to the pristine chlorine.

  6. Thermal diffusion of chlorine in uranium dioxide studied by secondary ion mass spectrometry and X-ray absorption spectroscopy

    International Nuclear Information System (INIS)

    Pipon, Y.; Toulhoat, N.; Moncoffre, N.; Raimbault, L.; Scheidegger, A.M.; Farges, F.; Carlot, G.

    2007-01-01

    In a nuclear reactor, 35 Cl present as an impurity in the nuclear fuel is activated by thermal neutron capture. During interim storage or geological disposal of the nuclear fuel, 36 Cl may be released from the fuel to the geo/biosphere and contribute significantly to the 'instant release fraction'. In order to elucidate the diffusion mechanisms, both irradiation and thermal effects must be assessed. This paper deals with the thermal diffusion of chlorine in depleted UO 2 . For this purpose, sintered UO 2 pellets were implanted with 37 Cl at an ion fluence of 10 13 cm -2 and successively annealed in the 1175-1475K temperature range. The implanted chlorine is used to simulate the behaviour of the displaced one due to recoil and to interactions with the fission fragments during reactor operation. The behaviour of the pristine and the implanted chlorine was investigated during thermal annealing. SIMS and μ-XAS (at the Cl-K edge) analyses show that: (1) the thermal migration of implanted chlorine becomes significant at 1275K; this temperature and the calculated activation energy of 4.3eV points out the great ability of chlorine to migrate in UO 2 at relatively low temperatures; (2) the behaviour of the implanted chlorine which aggregates into 'hot spots' during annealing before its effusion is clearly different from that of the pristine one which remains homogenously distributed after annealing; (3) the 'hot spot' and the pristine chlorine seem to be in different structural environments. Both types of chlorine are assumed to have a valence state of -I; (4) the comparison between an U 2 O 2 Cl 5 reference compound and the pristine chlorine environment shows a contribution of the U 2 O 2 Cl 5 to the pristine chlorine

  7. Kinetics of the gas phase reaction OH+NO(+M)->HONO(+M) and the determination of the UV absorption cross sections of HONO

    DEFF Research Database (Denmark)

    Pagsberg, P.; Bjergbakke, E.; Ratajczak, E.

    1997-01-01

    with total pressures in the range 10-1000 mbar at 298 K. The pressure dependence of the rate coefficient was studied by time-resolved UV and IR spectroscopy. By analysis of the fall-off curve we have derived a value for the limiting low pressure rate constant k(0)/[SF6] = (1.5 +/- 0.1) X 10(-30) cm(6......) molecule(-1) has been determined for the strongest band of HONO located at 354.2 nm. Differential absorption cross sections to be used for field measurements of HONO were also investigated. (C) 1997 Elsevier Science B.V....

  8. Determination of light-absorbing layers at inner capillary surface by cw excitation crossed-beam thermal-lens spectrometry.

    Science.gov (United States)

    Nedosekin, D A; Faubel, W; Proskurnin, M A; Pyell, U

    2009-05-15

    A thermal-lens spectrometric unit suitable for selective quantitative measurements of light-absorbing layers adsorbed onto the inner surface of a quartz glass capillary is described. The quantitative description of the thermal-lens signal generated in a quartz glass capillary with a light-absorbing layer at the inner surface of capillary is developed, which is based on the description for the thermal-lens experiment in the layered solids presented elsewhere. The accuracy of calculations is demonstrated by the comparison of predicted results with the experimental data and those predicted by the conventional theory. The data achieved prove the accuracy of calculations both for the time dependent thermal-lens signal and for the lock-in amplifier signal under variation of the spectrometer configuration for capillaries having an adsorbed layer. The proposed technique is used for the investigation of chromate/2,10-ionene and 4-aminoazobenzene adsorption at capillary walls. The estimates of the minimum light absorption detectable at capillary walls are at a level of 1 x 10(-5) abs. units; the linear range of the thermal-lens signal from the inner surface layer no less than three orders of magnitude is predicted.

  9. Measurement of thermal neutron cross section for {sup 241}Am(n,f) reaction

    Energy Technology Data Exchange (ETDEWEB)

    Kobayashi, Katsuhei; Yamamoto, Shuji; Fujita, Yoshiaki [Kyoto Univ., Kumatori, Osaka (Japan). Research Reactor Inst.; Miyoshi, Mitsuharu; Kimura, Itsuro; Kanno, Ikuo; Shinohara, Nobuo

    1997-03-01

    Making use of a standard neutron spectrum field with a pure Maxwellian distribution, the thermal neutron cross section for the {sup 241}Am(n,f) reaction has been measured relative to the reference value of 586.2b for the {sup 235U}(n,f) reaction. For the present measurement, electrodeposited layers of {sup 241}Am and {sup 235}U have been employed as back-to-back type double fission chambers. The present result at neutron energy of 0.0253 eV is 3.15 {+-} 0.097b. The ENDF/B-VI data is in good agreement with the present value, while the JENDL-3.2 data is lower by 4.2%. The evaluated data in JEF-2.2 and by Mughabghab are higher by 0.9% and 1.6%, respectively than the present result. The ratios of the earlier experimental data to the present value are distributed between 0.89 and 1.02. (author)

  10. Analysis of {sup 209} Bi and {sup 238} U photofission cross section in the quasi-deuteron region of photonuclear absorption

    Energy Technology Data Exchange (ETDEWEB)

    Tavares, O.A.P. [Centro Brasileiro de Pesquisas Fisicas (CBPF), Rio de Janeiro, RJ (Brazil); Terranova, M.L. [Istituto Nazionale di Fisica Nucleare, Rome (Italy)

    1992-12-31

    An analysis of the photofission reactions in the quasi-deuteron energy range of photonuclear absorption ({approx} 30-140 MeV) has been performed for {sup 209} Bi and {sup 238} U nuclei. Experimental cross section data available in the literature have been compared with calculated values obtained from a model in which the incoming photon is assumed to be absorbed by a neutron-proton pair (Levinger`s quasi-deuteron photoabsorption), followed by a mechanism of evaporation-fission competition for the excited residual nuclei. The model has been shown to reproduce the main experimental features of {sup 209} Bi and {sup 238} U photofission cross section, although unexplained differences still remain in the case of {sup 238} U-fission by 30-50 MeV incident photons. (author). 49 refs, 10 figs, 2 tabs.

  11. Consumption of organic diets does not affect intake and absorption of zinc and copper in men-evidence from two cross-over trials

    DEFF Research Database (Denmark)

    Mark, Alicja Budek; Kápolna, Emese; Laursen, Kristian H.

    2013-01-01

    diets on intake and absorption of zinc and copper in men. Two double-blinded, cross-over, intervention trials (3 dietary periods of 12 days with 2-week-long wash-out) were performed in 2008 (n = 17) and 2009 (n = 16) in young men. The diets were based on 9 crops grown in rigidly controlled organic......Agricultural methods may affect the nutritional composition of plants and cause complex changes in the food matrix. Whether this affects the dietary absorption of minerals that are important for maintaining health thorough life remains unclear. We compared the effects of organic and conventional......; 12.35 ± 0.47 mg per 10 MJ and 44.6% ± 12.1, respectively) and copper (overall mean ± SD; 2.12 ± 0.28 mg per 10 MJ and 41.2% ± 13.2, respectively) were not different between the organic and conventional diets. The growing season had no effect on zinc intake and absorption, but the copper intake...

  12. Effects of Thermal Radiation on Mixed Convection Flow of a Micropolar Fluid from an Unsteady Stretching Surface with Viscous Dissipation and Heat Generation/Absorption

    Directory of Open Access Journals (Sweden)

    Khilap Singh

    2016-01-01

    Full Text Available A numerical model is developed to examine the effects of thermal radiation on unsteady mixed convection flow of a viscous dissipating incompressible micropolar fluid adjacent to a heated vertical stretching surface in the presence of the buoyancy force and heat generation/absorption. The Rosseland approximation is used to describe the radiative heat flux in the energy equation. The model contains nonlinear coupled partial differential equations which have been converted into ordinary differential equation by using the similarity transformations. The dimensionless governing equations for this investigation are solved by Runge-Kutta-Fehlberg fourth fifth-order method with shooting technique. Numerical solutions are then obtained and investigated in detail for different interesting parameters such as the local skin-friction coefficient, wall couple stress, and Nusselt number as well as other parametric values such as the velocity, angular velocity, and temperature.

  13. Golden-rule approach to the soft-x-ray-absorption problem. V. Thermal broadening and comparison with experiments in quantum wells

    Science.gov (United States)

    Ohtaka, K.; Tanabe, Y.

    1989-02-01

    Exact spectra of photon emission and absorption are given for the Mahan-Nozières-De Dominicis (MND) Hamiltonian in the finite-temperature case. Besides infrared divergence, existence of a bound state and relaxation shift of the threshold energy are rigorously taken into account. We discuss in detail the interplay between the infrared divergence and thermal broadening and examine how the results in the ladder approximation are improved by the exact treatment. Based on the numerical results, quantitative comparison with recent experiments for quantum wells with ɛF=200 K and 4.2 Kvalue for the lifetime of a core hole is assumed, the MND Hamiltonian is capable of yielding a line shape in fairly good agreement with the experiments. For the emission spectra, however, the agreement is worse and it seems that some dissipative mechanism operating prior to photon emission has to be included.

  14. Reciprocal crosses between two populations of Trissolcus vassilievi (Mayr) (Hymenoptera: Scelionidae) reveal maternal effects on thermal phenotypes.

    Science.gov (United States)

    Iranipour, S; BenaMolaei, P; Asgari, S; Michaud, J P

    2015-06-01

    The egg parasitoid Trissolcus vassilievi (Mayr) (Hymenoptera: Scelionidae) is a significant natural enemy of the sunn pest, Eurygaster integriceps Puton (Hemiptera: Scutelleridae), the most important pest of wheat in Iran. This study examined the developmental time and egg-to-adult survival of two geographically separate populations of T. vassilievi on two corresponding host populations at five constant temperatures ranging from 15.0 to 35.0 ± 1°C. No wasps of either population emerged at 15.0°C and the temperature threshold for development was similar between populations, ranging from 13.1 ± 0.3 to 13.8 ± 0.4°C for males and 12.2 ± 0.1 to 12.6 ± 0.1°C for females, but the thermal constant varied with gender and parasitoid population. Development of wasps from the colder Tabriz location was slower, with thermal constants for males and females of 172.6 ± 3.1 and 204.1 ± 1.2 degree-days, respectively, compared to Varamin wasps with 164.7 ± 3.0 and 195.6 ± 1.3 degree-days, respectively. Based on genetic inheritance patterns, reciprocal crosses between the two populations were expected to result in females with thermal phenotypes intermediate to their parental populations, and males that resembled their mothers. However, female progeny of crosses more closely resembled their maternal population, indicating a maternal effect on thermal phenotype. Furthermore, the magnitude of the maternal effect on the thermal constant was asymmetric and was more strongly expressed by Varmin than Tabriz females. These results suggest the possibility of using selective crosses between wasp populations, in combination with artificial selection in the laboratory, to tune the thermal phenotype of parasitoids to specific regions prior to augmentative releases.

  15. Highly sensitive measurement in two-photon absorption cross section and investigation of the mechanism of two-photon-induced polymerization

    International Nuclear Information System (INIS)

    Lu Youmei; Hasegawa, Fuyuki; Goto, Takamichi; Ohkuma, Satoshi; Fukuhara, Setsuko; Kawazu, Yukie; Totani, Kenro; Yamashita, Takashi; Watanabe, Toshiyuki

    2004-01-01

    A novel two-photon initiator, 4,4'-bis[4-(di-n-butylamino)styryl]-benzene with the side-group methyl (Me) (abbreviated as Chromophore 1), was synthesized in comparison with the chromophore with the side group methoxy (MeO) (abbreviated as Chromophore 2). Femtosecond laser-induced fluorescence intensity was used to evaluate two-photon absorption (TPA) cross section, δ, by means of a charge-coupled device, USB-2000 (abbreviated as CCD). Results showed that changing the side group from Me to MeO led to a significant red-shift of the two-photon absorption ( 2 λ max ). However, the microstructures obtained by two-photon-induced polymerization (TPIP) demonstrated that the sensitivities of Chromophore 1 increased despite a two-fold decrease in the two-photon cross section δ max, relative to Chromophore 2. Correlated with the appearance that the long-lived charge transfer emission of the chromophore in the monomer bulk, we suggest that the intramolecular charge transfer (intra-CT) takes place within the excited dye. Then intermolecular charge transfer was successive as a result of the formation of an exciplex between the dye and the monomer. The Me group was favorable for the intra-CT, relative to MeO, which contributed to the enhancement of the sensitivity of TPIP

  16. Effects of Starvation and Thermal Stress on the Thermal Tolerance of Silkworm, Bombyx mori: Existence of Trade-offs and Cross-Tolerances.

    Science.gov (United States)

    Mir, A H; Qamar, A

    2017-09-27

    Organisms, in nature, are often subjected to multiple stressors, both biotic and abiotic. Temperature and starvation are among the main stressors experienced by organisms in their developmental cycle and the responses to these stressors may share signaling pathways, which affects the way these responses are manifested. Temperature is a major factor governing the performance of ectothermic organisms in ecosystems worldwide and, therefore, the thermal tolerance is a central issue in the thermobiology of these organisms. Here, we investigated the effects of starvation as well as mild heat and cold shocks on the thermal tolerance of the larvae of silkworm, Bombyx mori (Linnaeus). Starvation acted as a meaningful or positive stressor as it improved cold tolerance, measured as chill coma recovery time (CCRT), but, at the same time, it acted as a negative stressor and impaired the heat tolerance, measured as heat knockdown time (HKT). In the case of heat tolerance, starvation negated the positive effects of both mild cold as well as mild heat shocks and thus indicated the existence of trade-off between these stressors. Both mild heat and cold shocks improved the thermal tolerance, but the effects were more prominent when the indices were measured in response to a stressor of same type, i.e., a mild cold shock improved the cold tolerance more than the heat tolerance and vice versa. This improvement in thermal tolerance by both mild heat as well as cold shocks indicated the possibility of cross-tolerance between these stressors.

  17. The Effects of CaCO3 Coated Wood Free Paper Usage as Filler on Water Absorption, Mechanical and Thermal Properties of Cellulose-High Density Polyethylene Composites

    Directory of Open Access Journals (Sweden)

    Emrah PEŞMAN

    2016-11-01

    Full Text Available In this study some physical, mechanical and thermal characteristics of high density polyethylene (HDPE and CaCO3 coated/pigmented wood free paper fiber composites were investigated. The fillers used in this study were uncoated cellulose, 5.8 %, 11.5 %, 16.5 % and 23.1 % CaCO3 coated wood free paper fibers. Each filler type was mixed with HDPE at 40% by weight fiber loading. In this case, the ratio of CaCO3 in plastic composites were calculated as 0 %, 2.3 %, 4.6 %, 6.6 % and 9.2 % respectively. Increased CaCO3 ratio improved the moisture resistant, flexural and tensile strength of cellulose-HDPE composites. However, the density of the cellulose-HDPE composites increased with CaCO3 addition. Energy Dispersive Spectroscopy on Scanning Electron Microscope analysis demonstrated the uniform distribution of CaCO3 and cellulose fiber in plastic matrix. In addition, the thermal properties of fiber plastic composites were investigated. The results of Differential scanning calorimetry analysis revealed that the crystallinity of the samples decreased with increasing CaCO3 content. Consequently, this work showed that CaCO3 coated waste paper fibers could be used as reinforcing filler against water absorption in thermoplastic matrix.DOI: http://dx.doi.org/10.5755/j01.ms.22.4.14222

  18. Averaged electron collision cross sections for thermal mixtures of β-alanine conformers in the gas phase

    Science.gov (United States)

    Fujimoto, Milton M.; de Lima, Erik V. R.; Tennyson, Jonathan

    2017-10-01

    A theoretical study of elastic electron scattering by gas-phase amino acid molecule β-alanine (NH2-CH2-CH2-COOH) is presented. R-matrix calculations are performed for each of the ten lowest-lying, thermally-accessible conformers of β-alanine. Eigenphase sums, resonance features, differential and integral cross sections are computed for each conformer. The positions of the low-energy shape resonance associated with the unoccupied {π }* orbital of the -COOH group are found to vary from 2.5 to 3.3 eV and the resonance widths from 0.2 to 0.5 eV depending on the conformation. The temperature-dependent population ratios are derived, based on temperature-corrected Gibbs free energies. Averaged cross sections for thermal mixtures of the 10 conformers are presented. A comparison with previous results for the α-alanine isomer is also presented.

  19. Viscous Dissipation and Thermal Radiation effects in MHD flow of Jeffrey Nanofluid through Impermeable Surface with Heat Generation/Absorption

    Science.gov (United States)

    Sharma, Kalpna; Gupta, Sumit

    2017-06-01

    This paper investigates steady two dimensional flow of an incompressible magnetohydrodynamic (MHD) boundary layer flow and heat transfer of nanofluid over an impermeable surface in presence of thermal radiation and viscous dissipation. By using similarity transformation, the arising governing equations of momentum, energy and nanoparticle concentration are transformed into coupled nonlinear ordinary differential equations, which are than solved by homotopy analysis method (HAM). The effect of different physical parameters, namely, Prandtl number Pr, Eckert number Ec, Magnetic parameter M, Brownian motion parameter Nb, Thermophoresis parameter Nt, Lewis parameter Le and Radiation parameter Rd on the velocity, temperature and concentration profiles along with the Nusselt number and skin friction coefficient are discussed graphically and in tabular form in details. The present results are also compared with existing limiting solutions.

  20. Metal/dielectric thermal interfacial transport considering cross-interface electron-phonon coupling: Theory, two-temperature molecular dynamics, and thermal circuit

    Science.gov (United States)

    Lu, Zexi; Wang, Yan; Ruan, Xiulin

    2016-02-01

    The standard two-temperature equations for electron-phonon coupled thermal transport across metal/nonmetal interfaces are modified to include the possible coupling between metal electrons with substrate phonons. The previous two-temperature molecular dynamics (TT-MD) approach is then extended to solve these equations numerically at the atomic scale, and the method is demonstrated using Cu/Si interface as an example. A key parameter in TT-MD is the nonlocal coupling distance of metal electrons and nonmetal phonons, and here we use two different approximations. The first is based on Overhauser's "joint-modes" concept, while we use an interfacial reconstruction region as the length scale of joint region rather than the phonon mean-free path as in Overhauser's original model. In this region, the metal electrons can couple to the joint phonon modes. The second approximation is the "phonon wavelength" concept where electrons couple to phonons nonlocally within the range of one phonon wavelength. Compared with the original TT-MD, including the cross-interface electron-phonon coupling can slightly reduce the total thermal boundary resistance. Whether the electron-phonon coupling within the metal block is nonlocal or not does not make an obvious difference in the heat transfer process. Based on the temperature profiles from TT-MD, we construct a new mixed series-parallel thermal circuit. We show that such a thermal circuit is essential for understanding metal/nonmetal interfacial transport, while calculating a single resistance without solving temperature profiles as done in most previous studies is generally incomplete. As a comparison, the simple series circuit that neglects the cross-interface electron-phonon coupling could overestimate the interfacial resistance, while the simple parallel circuit in the original Overhauser's model underestimates the total interfacial resistance.

  1. Solvent-resistant organic transistors and thermally stable organic photovoltaics based on cross-linkable conjugated polymers

    KAUST Repository

    Kim, Hyeongjun

    2012-01-10

    Conjugated polymers, in general, are unstable when exposed to air, solvent, or thermal treatment, and these challenges limit their practical applications. Therefore, it is of great importance to develop new materials or methodologies that can enable organic electronics with air stability, solvent resistance, and thermal stability. Herein, we have developed a simple but powerful approach to achieve solvent-resistant and thermally stable organic electronic devices with a remarkably improved air stability, by introducing an azide cross-linkable group into a conjugated polymer. To demonstrate this concept, we have synthesized polythiophene with azide groups attached to end of the alkyl chain (P3HT-azide). Photo-cross-linking of P3HT-azide copolymers dramatically improves the solvent resistance of the active layer without disrupting the molecular ordering and charge transport. This is the first demonstration of solvent-resistant organic transistors. Furthermore, the bulk-heterojunction organic photovoltaics (BHJ OPVs) containing P3HT-azide copolymers show an average efficiency higher than 3.3% after 40 h annealing at an elevated temperature of 150 °C, which represents one of the most thermally stable OPV devices reported to date. This enhanced stability is due to an in situ compatibilizer that forms at the P3HT/PCBM interface and suppresses macrophase separation. Our approach paves a way toward organic electronics with robust and stable operations. © 2011 American Chemical Society.

  2. Biobased chitosan/polybenzoxazine cross-linked films: preparation in aqueous media and synergistic improvements in thermal and mechanical properties.

    Science.gov (United States)

    Alhwaige, Almahdi A; Agag, Tarek; Ishida, Hatsuo; Qutubuddin, Syed

    2013-06-10

    A novel class of polymer blends has been prepared from main-chain-type benzoxazine polymer (MCBP) and chitosan (CTS), a modified biomacromolecule. A water-soluble, main-chain-type benzoxazine polymer, MCBP(BA-tepa), was synthesized from the reaction of bisphenol A (BA), tetraethylenepentamine (TEPA) and formalin. The structure of the MCBP(BA-tepa) was confirmed by proton nuclear magnetic resonance spectroscopy ((1)H NMR) and Fourier transform infrared spectroscopy (FT-IR). The polymer blends were prepared by mixing MCBP(BA-tepa) and CTS in aqueous acetic acid solution (1%). The CTS/MCBP(BA-tepa) films are cross-linked by thermal treatment via the ring-opening polymerization of benzoxazine structures in the main chain to produce an AB-cross-linked network. Differential scanning calorimetry (DSC) and FT-IR were used to study the effects of CTS on the polymerization behavior of benzoxazine. Hydrogen bonding between polybenzoxazine and CTS structures was also observed. The mechanical and thermal properties of cross-linked CTS/MCBP(BA-tepa) films were evaluated, and the results showed unusual levels of synergism. In particular, the tensile strength and thermal stability were significantly enhanced in a nonlinear fashion.

  3. Investigating cluster astrophysics and cosmology with cross-correlation of the thermal Sunyaev-Zel'dovich effect and weak lensing

    Science.gov (United States)

    Osato, Ken; Flender, Samuel; Nagai, Daisuke; Shirasaki, Masato; Yoshida, Naoki

    2018-03-01

    Recent detections of the cross-correlation of the thermal Sunyaev-Zel'dovich (tSZ) effect and weak gravitational lensing (WL) enable unique studies of cluster astrophysics and cosmology. In this work, we present constraints on the amplitude of the non-thermal pressure fraction in galaxy clusters, α0, and the amplitude of the matter power spectrum, σ8, using measurements of the tSZ power spectrum from Planck, and the tSZ-WL cross-correlation from Planck and the Red Cluster Sequence Lensing Survey. We fit the data to a semi-analytic model with the covariance matrix using N-body simulations. We find that the tSZ power spectrum alone prefers σ8 ˜ 0.85 and a large fraction of non-thermal pressure (α0 ˜ 0.2-0.3). The tSZ-WL cross-correlation on the other hand prefers a significantly lower σ8 ˜ 0.6 and low α0 ˜ 0.05. We show that this tension can be mitigated by allowing for a steep slope in the stellar mass-halo mass relation, which would cause a reduction of the gas in low-mass haloes. In such a model, the combined data prefer σ8 ˜ 0.7 and α0 ˜ 0.2, consistent with predictions from hydrodynamical simulations.

  4. Laser produced ionization of alcali-atoms through three-photon absorption: comparison between experimental and theoretical cross sections

    International Nuclear Information System (INIS)

    Laplanche, G.; Flank, Y.; Jaouen, M.; Rachman, A.

    1977-01-01

    Three-photon ionization cross-sections of alkali atoms for linearly and circularly polarized light have been calculated in the electric dipole approximation. The infinite summations over the complete set of unperturbed atomic states, appearing when Nth-order time-dependent perturbation theory is applied, have been calculated by using the Green's function formalism and the quantum defect method. The theoretical results are compared with the values experimentally obtained by Cervenan, Chan and Isenor [fr

  5. Physical, thermal, structural and optical absorption studies of vanadyl doped magnesium oxy-chloride bismo-borate glasses

    Directory of Open Access Journals (Sweden)

    M.S. Dahiya

    2015-06-01

    Full Text Available Oxy-chloride bismuth-borate glasses with composition xMgCl2·(30 − xMgO·20Bi2O3·50B2O3 containing 2 mol% doping of V2O5 (x = 12, 15, 20, 25 and 30 are prepared by melt-quenching technique. The structural, thermal and optical behaviors are explained by analyzing the data obtained from density (D, molar volume (Vm, theoretical optical basicity (Λth, differential scanning calorimetry (DSC, FTIR and UV–vis results. A decrease in D and increase in Vm (except for sample MBV3 for which D is maximum on increasing chloride content suggests the formation of non-bridging oxygen atoms. Maximum glass transition temperature (Tg and crystallization temperature (Tx have been observed for sample MBV3. The glass stability (S and stability ratio (S/Tg have been calculated from the values of Tg and Tx and both are having maximum values for sample MBV3. Study of the FTIR spectra in the mid-IR range reveals the presence of both triangular and tetrahedral coordinated boron. The optical studies through UV–vis spectral analysis show non-sharp edge. The optical band gap (Eg is also maximum for sample MBV3.

  6. Flexural Properties of PVC/Bamboo Composites under Static and Dynamic-Thermal Conditions: Effects of Composition and Water Absorption

    Directory of Open Access Journals (Sweden)

    Shahril Anuar Bahari

    2017-01-01

    Full Text Available Polyvinyl chloride (PVC/bamboo composites have been prepared and assessed for their use in interior and exterior load-bearing applications. PVC composites were formed by compounding PVC with different bamboo particle sizes and loadings. The mechanical properties of these composites were determined at both ambient and elevated temperatures and after long-term water soaking. Analysis revealed that bamboo incorporation improved the PVC composite flexural modulus which was also observed with dynamic mechanical-thermal analysis on heating composites to ca. 70°C. Addition of 25% and 50% bamboo particles increases flexural modulus by 80% with dependency on whether fine (<75 μm or coarse (<1 mm particles were used. On water soaking to saturation, composites had water weight uptakes of 10%, with reduced flexural properties obtained for all water-soaked composites. Nonetheless, the results of this study show that PVC/bamboo composites achieve the minimum flexural performance of ASTM D 6662, indicating potential for their use in exterior applications.

  7. Magnetic and power absorption measurements on iron oxide nanoparticles synthesized by thermal decomposition of Fe(acac)3

    Science.gov (United States)

    Jović Orsini, N.; Babić-Stojić, B.; Spasojević, V.; Calatayud, M. P.; Cvjetićanin, N.; Goya, G. F.

    2018-03-01

    Iron oxide magnetic nanoparticles with diameters d, 7 nm ≤ d ≤ 12 nm, were synthesized by thermal decomposition of Fe(acac)3. Different experimental conditions, keeping constant concetration of Fe ions in solvent, showed that the heating rates is the most important parameter determining the final particle size. Use of two different solvents, 1-eicosene and 1-octadecene, yielded similar nanoparticle sizes (7.1 nm ≤ d ≤ 7.5 nm), but different magnetic anisotropies. All samples were superparamagnetic at room temperature. Spin disordering was inferred in samples coated with trioctylphosphine oxide (TOPO) co-ligand in addition to oleic acid and oleyamine. The heating ability of ∼12 nm-sized nanoparticles dispersed in hexane under alternating magnetic fields (3.98 kA/m ≤ H0 ≤ 23.87 kA/m; 229.3 kHz ≤ f ≤ 828 kHz) has been studied, finding a nearly quadratic dependence upon H0, as expected from the linear response theory.

  8. The Scaled SLW model of gas radiation in non-uniform media based on Planck-weighted moments of gas absorption cross-section

    Science.gov (United States)

    Solovjov, Vladimir P.; Andre, Frederic; Lemonnier, Denis; Webb, Brent W.

    2018-02-01

    The Scaled SLW model for prediction of radiation transfer in non-uniform gaseous media is presented. The paper considers a new approach for construction of a Scaled SLW model. In order to maintain the SLW method as a simple and computationally efficient engineering method special attention is paid to explicit non-iterative methods of calculation of the scaling coefficient. The moments of gas absorption cross-section weighted by the Planck blackbody emissive power (in particular, the first moment - Planck mean, and first inverse moment - Rosseland mean) are used as the total characteristics of the absorption spectrum to be preserved by scaling. Generalized SLW modelling using these moments including both discrete gray gases and the continuous formulation is presented. Application of line-by-line look-up table for corresponding ALBDF and inverse ALBDF distribution functions (such that no solution of implicit equations is needed) ensures that the method is flexible and efficient. Predictions for radiative transfer using the Scaled SLW model are compared to line-by-line benchmark solutions, and predictions using the Rank Correlated SLW model and SLW Reference Approach. Conclusions and recommendations regarding application of the Scaled SLW model are made.

  9. Filter-based measurements of UV-vis mass absorption cross sections of organic carbon aerosol from residential biomass combustion: Preliminary findings and sources of uncertainty

    Science.gov (United States)

    Pandey, Apoorva; Pervez, Shamsh; Chakrabarty, Rajan K.

    2016-10-01

    Combustion of solid biomass fuels is a major source of household energy in developing nations. Black (BC) and organic carbon (OC) aerosols are the major PM2.5 (particulate matter with aerodynamic diameter smaller than 2.5 μm) pollutants co-emitted during burning of these fuels. While the optical nature of BC is well characterized, very little is known about the properties of light-absorbing OC (LAOC). Here, we report our preliminary findings on the mass-based optical properties of LAOC emitted from the combustion of four commonly used solid biomass fuels - fuel-wood, agricultural residue, dung-cake, and mixed - in traditional Indian cookstoves. As part of a pilot field study conducted in central India, PM2.5 samples were collected on Teflon filters and analyzed for their absorbance spectra in the 300-900 nm wavelengths at 1 nm resolution using a UV-Visible spectrophotometer equipped with an integrating sphere. The mean mass absorption cross-sections (MAC) of the emitted PM2.5 and OC, at 550 nm, were 0.8 and 0.2 m2 g-1, respectively, each with a factor of ~2.3 uncertainty. The mean absorption Ångström exponent (AǺE) values for PM2.5 were 3±1 between 350 and 550 nm, and 1.2±0.1 between 550 and 880 nm. In the 350-550 nm range, OC had an AǺE of 6.3±1.8. The emitted OC mass, which was on average 25 times of the BC mass, contributed over 50% of the aerosol absorbance at wavelengths smaller than 450 nm. The overall OC contribution to visible solar light (300-900 nm) absorption by the emitted particles was 26-45%. Our results highlight the need to comprehensively and accurately address: (i) the climatic impacts of light absorption by OC from cookstove emissions, and (ii) the uncertainties and biases associated with variability in biomass fuel types and combustion conditions, and filter-based measurement artifacts during determination of MAC values.

  10. Methods for calculating group cross sections for doubly heterogeneous thermal reactor systems

    International Nuclear Information System (INIS)

    Stamatelatos, M.G.; LaBauve, R.J.

    1977-01-01

    The report discusses methods used at LASL for calculating group cross sections for doubly heterogeneous HTGR systems of the General Atomic design. These cross sections have been used for the neutronic safety analysis calculations of such HTGR systems at various points in reactor lifetime (e.g., beginning-of-life, end-of-equilibrium cycle). They were also compared with supplied General Atomic cross sections generated with General Atomic codes. The overall agreement between the LASL and the GA cross sections has been satisfactory

  11. First remote sensing measurements of ClOOCl along with ClO and ClONO2 in activated and deactivated Arctic vortex conditions using new ClOOCl IR absorption cross sections

    Directory of Open Access Journals (Sweden)

    M. Birk

    2010-02-01

    Full Text Available Active chlorine species play a dominant role in the catalytic destruction of stratospheric ozone in the polar vortices during the late winter and early spring seasons. Recently, the correct understanding of the ClO dimer cycle was challenged by the release of new laboratory absorption cross sections (Pope et al., 2007 yielding significant model underestimates of observed ClO and ozone loss (von Hobe et al., 2007. Under this aspect, nocturnal Arctic stratospheric limb emission measurements carried out by the balloon version of the Michelson Interferometer for Passive Atmospheric Sounding (MIPAS-B from Kiruna (Sweden on 11 January 2001 and 20/21 March 2003 have been reanalyzed with regard to the chlorine reservoir species ClONO2 and the active species, ClO and ClOOCl (Cl2O2. New laboratory measurements of IR absorption cross sections of ClOOCl for various temperatures and pressures allowed for the first time the retrieval of ClOOCl mixing ratios from remote sensing measurements. High values of active chlorine (ClOx of roughly 2.3 ppbv at 20 km were observed by MIPAS-B in the cold mid-winter Arctic vortex on 11 January 2001. While nighttime ClOOCl shows enhanced values of nearly 1.1 ppbv at 20 km, ClONO2 mixing ratios are less than 0.1 ppbv at this altitude. In contrast, high ClONO2 mixing ratios of nearly 2.4 ppbv at 20 km have been observed in the late winter Arctic vortex on 20 March 2003. No significant ClOx amounts are detectable on this date since most of the active chlorine has already recovered to its main reservoir species ClONO2. The observed values of ClOx and ClONO2 are in line with the established polar chlorine chemistry. The thermal equilibrium constants between the dimer formation and its dissociation, as derived from the balloon measurements, are on the lower side of reported data and in good agreement with values recommended by von Hobe et al. (2007. Calculations with the ECHAM/MESSy Atmospheric Chemistry model (EMAC using

  12. Determination of the thermal neutron induced O-17(n,alpha) C-14 reaction cross section

    NARCIS (Netherlands)

    Wagemans, J; Wagemans, C; Bieber, R; Geltenbort, P

    1998-01-01

    The. O-17(n(th),alpha)C-14 reaction cross section was determined at the high flux reactor of the ILL in Grenoble relative to the known N-14(n(th),p)C-14 cross section. For the flux calibration measurements, N-14(2) from the air was used. The O-17(n,alpha) measurements were performed with several

  13. Effect of U-238 and U-235 cross sections on nuclear characteristics of fast and thermal reactors

    Energy Technology Data Exchange (ETDEWEB)

    Akie, Hiroshi; Takano, Hideki [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Kaneko, Kunio

    1997-03-01

    Benchmark calculation has been made for fast and thermal reactors by using ENDF/B-VI release 2(ENDF/B-VI.2) and JENDL-3.2 nuclear data. Effective multiplication factors (k{sub eff}s) calculated for fast reactors calculated with ENDF/B-VI.2 becomes about 1% larger than the results with JENDL-3.2. The difference in k{sub eff} is caused mainly from the difference in inelastic scattering cross section of U-238. In all thermal benchmark cores, ENDF/B-VI.2 gives smaller multiplication factors than JENDL-3.2. In U-235 cores, the difference is about 0.3%dk and it becomes about 0.6% in TCA U cores. The difference in U-238 data is also important in thermal reactors, while there are found 0.1-0.3% different v values of U isotopes in thermal energy between ENDF/B-VI.2 and JENDL-3.2. (author)

  14. Hydrogels Prepared from Cross-Linked Nanofibrillated Cellulose

    Science.gov (United States)

    Sandeep S. Nair; J.Y. Zhu; Yulin Deng; Arthur J. Ragauskas

    2014-01-01

    Nanocomposite hydrogels were developed by cross-linking nanofibrillated cellulose with poly(methyl vinyl ether-co-maleic acid) and polyethylene glycol. The cross-linked hydrogels showed enhanced water absorption and gel content with the addition of nanocellulose. In addition, the thermal stability, mechanical strength, and modulus increased with an increase in the...

  15. A Method to Measure Thermal Deformation of Superconducting Magnet Cross Sections

    CERN Document Server

    Grau-Carles, A; Todesco, Ezio; Tommasini, D; Siegel, N

    1999-01-01

    The precision measurement of the cable positioning in superconducting coils is of great interest both at room and liquid nitrogen temperatures because mechanical and thermal deformations affect the quality of the magnetic field. The paper describes a new two-coordinate measuring device, which is able to obtain scanned images of flat composite samples at liquid nitrogen temperature. The sample is cooled at 77 K into a flat quartz tray to permit the optical access to the sample from the bottom. The comparison of the images taken at room and liquid nitrogen temperatures by a high-resolution flatbed scanner gives the thermal contraction of the components.

  16. In situ thermally cross-linked polyacrylonitrile as binder for high-performance silicon as lithium ion battery anode.

    Science.gov (United States)

    Shen, Lanyao; Shen, Lian; Wang, Zhaoxiang; Chen, Liquan

    2014-07-01

    Electrode integrity and electric contact between particles and between particle and current collector are critical for electrochemical performance, especially for that of electrode materials with large volume change during cycling and with poor electric conductivity. We report on the in situ thermally cross-linked polyacrylonitrile (PAN) as a binder for silicon-based anodes of lithium-ion batteries. The electrode delivers excellent cycle life and rate capability with a reversible capacity of about 1450 mA h g(-1) even after 100 cycles. The improved electrochemical performance of such silicon electrodes is attributed to heat-treatment-induced cross-linking and the formation of conjugated PAN. These findings open new avenues to explore other polymers for both anode and cathode electrodes of rechargeable batteries. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  17. Phonon-engineered thermal transport in Si wires with constant and periodically modulated cross-sections: A crossover between nano- and microscale regimes

    Science.gov (United States)

    Cocemasov, A. I.; Nika, D. L.; Fomin, V. M.; Grimm, D.; Schmidt, O. G.

    2015-07-01

    The transition between nanoscale and microscale thermal transport regime at room temperature in silicon wires with constant and periodically modulated cross-section is theoretically investigated. Extrapolating the calculated thermal conductivity from the nano- to micrometer range, we find the characteristic dimensions of the wires where a crossover between nanoscale and microscale thermal transport occurs. This crossover is observed in both generic (smooth) and cross-section-modulated wires. In case of smooth silicon wires, we reveal a strong dependence of the crossing point position on the boundary roughness. For silicon wires with weak boundary roughness, the crossover occurs at cross-sections ˜60 nm × 300 nm, while for very rough boundaries it occurs at cross-sections ˜150 nm × 750 nm. In case of the periodically modulated wires, the crossover between nano- and microscale regimes occurs at typical cross-sections ˜120 nm × 120 nm of the narrow segment, and it is almost independent of boundary roughness. A strong distinction from the case of smooth wires is attributed (i) to the different trends at the nanometer scale, wherefrom the extrapolation was performed, and (ii) to the different phonon-boundary scattering due to the specific geometry. For modulated silicon wires, the influence of modulation thickness, modulation length, and cross-sectional area on the phonon thermal conductivity at the room temperature is analyzed. A possibility of thermal transport engineering in cross-section-modulated wires by resizing them is revealed in both nano- and microscale regimes. The presented results pave the way towards a better understanding of thermal transport reduction in Si nanowires with engineered diameter modulations and shed light on the crossover between nano- and microscale regimes of thermal transport.

  18. Photoneutron cross sections measurements in 13C with thermal neutron capture gamma-rays

    International Nuclear Information System (INIS)

    Semmler, Renato; Carbonari, Artur W.; Terremoto, Luis A.A.; Goncalez, Odair L.

    2007-01-01

    Photoneutrons cross sections measurements of 13 C have been obtained in energy interval between 5,3 and 10,8 MeV, using neutron capture gamma-rays with high resolution in energy (3 - 21 eV), produced by 21 target materials, placed inside a tangential beam port, near the core of the IPEN/CNEN-SP IEA-R1 (2MW) research reactor. The sample have been irradiated inside a 4p geometry neutron detector system 'Long Counter', 520,5 cm away from the capture target. The capture gamma-ray flux was determined by means of the analysis of the gamma spectrum obtained by using a Ge(Li) solid-state detector (EG and G ORTEC, 25 cm 3 , 5%), previously calibrated with capture gamma-rays from a standard target of Nitrogen (Melamine). The neutron photoproduction cross section has been measured for each target capture gamma-ray spectrum (compound cross section). A methodology for unfolding the set of experimental compound cross sections, have been used in order to obtain the cross sections at specific excitation energy values (principal gamma lines energies of the capture targets). The cross sections were compared with experimental data, reported by other authors, using different gamma-ray sources. A good agreement was observed between in this work and reported in the literature. (author)

  19. Photoneutron cross sections measurements in {sup 13}C with thermal neutron capture gamma-rays

    Energy Technology Data Exchange (ETDEWEB)

    Semmler, Renato; Carbonari, Artur W.; Terremoto, Luis A.A. [Instituto de Pesquisas Energeticas e Nucleares (IPEN/CNEN-SP), Sao Paulo, SP (Brazil)]. E-mails: rsemmler@ipen.br; carbonar@ipen.br; laaterre@ipen.br; Goncalez, Odair L. [Centro Tecnico Aeroespacial (CTA-IEAv), Sao Jose dos Campos, SP (Brazil). Inst. de Estudos Avancados]. E-mail: odairl@ieav.cta.br

    2007-07-01

    Photoneutrons cross sections measurements of {sup 13}C have been obtained in energy interval between 5,3 and 10,8 MeV, using neutron capture gamma-rays with high resolution in energy (3 - 21 eV), produced by 21 target materials, placed inside a tangential beam port, near the core of the IPEN/CNEN-SP IEA-R1 (2MW) research reactor. The sample have been irradiated inside a 4p geometry neutron detector system 'Long Counter', 520,5 cm away from the capture target. The capture gamma-ray flux was determined by means of the analysis of the gamma spectrum obtained by using a Ge(Li) solid-state detector (EG and G ORTEC, 25 cm{sup 3}, 5%), previously calibrated with capture gamma-rays from a standard target of Nitrogen (Melamine). The neutron photoproduction cross section has been measured for each target capture gamma-ray spectrum (compound cross section). A methodology for unfolding the set of experimental compound cross sections, have been used in order to obtain the cross sections at specific excitation energy values (principal gamma lines energies of the capture targets). The cross sections were compared with experimental data, reported by other authors, using different gamma-ray sources. A good agreement was observed between in this work and reported in the literature. (author)

  20. Average absorption cross-section of the human body measured at 1-12 GHz in a reverberant chamber: results of a human volunteer study.

    Science.gov (United States)

    Flintoft, I D; Robinson, M P; Melia, G C R; Marvin, A C; Dawson, J F

    2014-07-07

    The electromagnetic absorption cross-section (ACS) averaged over polarization and angle-of-incidence of 60 ungrounded adult subjects was measured at microwave frequencies of 1-12 GHz in a reverberation chamber. Average ACS is important in non-ionizing dosimetry and exposure studies, and is closely related to the whole-body averaged specific absorption rate (WBSAR). The average ACS was measured with a statistical uncertainty of less than 3% and high frequency resolution for individuals with a range of body shapes and sizes allowing the statistical distribution of WBSAR over a real population with individual internal and external morphologies to be determined. The average ACS of all subjects was found to vary from 0.15 to 0.4 m(2); for an individual subject it falls with frequency over 1-6 GHz, and then rises slowly over the 6-12 GHz range in which few other studies have been conducted. Average ACS and WBSAR are then used as a surrogate for worst-case ACS/WBSAR, in order to study their variability across a real population compared to literature results from simulations using numerical phantoms with a limited range of anatomies. Correlations with body morphological parameters such as height, mass and waist circumference have been investigated: the strongest correlation is with body surface area (BSA) at all frequencies above 1 GHz, however direct proportionality to BSA is not established until above 5 GHz. When the average ACS is normalized to the BSA, the resulting absorption efficiency shows a negative correlation with the estimated thickness of subcutaneous body fat. Surrogate models and statistical analysis of the measurement data are presented and compared to similar models from the literature. The overall dispersion of measured average WBSAR of the sample of the UK population studied is consistent with the dispersion of simulated worst-case WBSAR across multiple numerical phantom families. The statistical results obtained allow the calibration of human

  1. Thermal neutron diffusion parameters in homogeneous mixtures

    International Nuclear Information System (INIS)

    Drozdowicz, K.; Krynicka, E.

    1995-01-01

    A physical background is presented for a computer program which calculates the thermal neutron diffusion parameters for homogeneous mixtures of any compounds. The macroscopic absorption, scattering and transport cross section of the mixture are defined which are generally function of the incident neutron energy. The energy-averaged neutron parameters are available when these energy dependences and the thermal neutron energy distribution are assumed. Then the averaged diffusion coefficient and the pulsed thermal neutron parameters (the absorption rare and the diffusion constant) are also defined. The absorption cross section is described by the 1/v law and deviations from this behaviour are considered. The scattering cross section can be assumed as being almost constant in the thermal neutron region (which results from the free gas model). Serious deviations are observed for hydrogen atoms bound in molecules and a special study in the paper is devoted to this problem. A certain effective scattering cross section is found in this case on a base of individual exact data for a few hydrogenous media. Approximations assumed for the average cosine of the scattering angle are also discussed. The macroscopic parameters calculated are averaged over the Maxwellian energy distribution for the thermal neutron flux. An information on the input data for the computer program is included. (author). 10 refs, 4 figs, 5 tabs

  2. Neutron capture cross section standards for BNL 325, Fourth Edition

    International Nuclear Information System (INIS)

    Holden, N.E.

    1981-01-01

    This report evaluates the experimental data and recommends values for the thermal neutron cross sections and resonance integrals for the neutron capture reactions: 55 Mn(n,γ), 59 Co(n,γ) and 197 Au(n,γ). The failure of lithium and boron as standards due to the natural variation of the absorption cross sections of these elements is discussed. The Westcott convention, which describes the neutron spectrum as a thermal Maxwellian distribution with an epithermal component, is also discussed

  3. Aging Mechanisms and Nondestructive Aging Indicator of Filled Cross-linked Polyethylene (XLPE) Exposed to Simultaneous Thermal and Gamma Radiation

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Shuaishuai; Fifield, Leonard S.; Bowler, Nicola

    2018-04-11

    Aging mechanisms and a nondestructive aging indicator of filled cross-linked polyethylene (XLPE) cable insulation material used in nuclear power plants (NPPs) are studied. Using various material characterization techniques, likely candidates and functions for the main additives in a commercial filled-XLPE insulation material have been identified. These include decabromodiphenyl ether and Sb2O3 as flame retardants, ZnS as white pigment and polymerized 1,2-dihydro-2,2,4-trimethylquinoline as antioxidant. Gas chromatography-mass spectrometry, differential scanning calorimetry, oxidation induction time and measurements of dielectric loss tangent are utilized to monitor property changes as a function of thermal and radiation exposure of the cable material. Small-molecular-weight hydrocarbons are evolve with gamma radiation aging at 90 °C. The level of antioxidant decreases with aging by volatilization and chemical reaction with free radicals. Thermal aging at 90 °C for 25 days or less causes no observable change to the cross-linked polymer structure. Gamma radiation causes damage to crystalline polymer regions and introduces defects. Dielectric loss tangent is shown to be an effective and reliable nondestructive indicator of the aging severity of the filled-XLPE insulation material.

  4. Relevance of body size and shell colouration for thermal absorption and heat loss in white garden snails, Theba pisana (Helicidae), from Northern France.

    Science.gov (United States)

    Knigge, Thomas; Di Lellis, Maddalena A; Monsinjon, Tiphaine; Köhler, Heinz-R

    2017-10-01

    The internal temperature of land snails depends on environmental factors, such as exposure to electromagnetic radiation and airflow as well as biotic factors including shell size, shell colouration and thickness or the resting position of the snail. In controlled field experiments, we quantified heating by thermal absorption of light and airflow-induced heat loss in the white garden snail, Theba pisana, from Normandy, France. Heating experiments revealed a significant positive relation of the internal body temperature with illumination period, shell temperature and air temperature at different times of day. The size of the snails was negatively related with both of the given illumination times: smaller animals heated up stronger than larger ones. The temperature at the surface of the shell significantly depended on the illumination period and the time of day. An AIC-based quality assessment of multiple linear modelling showed that, for explaining both shell surface and internal temperature of the soft body, several factors, i.e., exposure time, daytime, shell size and colouration contributed to the best models, respectively. Similarly, heat loss of the soft body after and during exposure of the snails to sunlight by a constant airflow depended on the initial body temperature, shell size, colouration and ambient air temperature. Our study revealed also the importance of both shell size and colouration for the loss of body temperature under natural conditions: small and banded animals that had heated up to temperatures above 30°C cooled down faster than large and un-banded ones. Copyright © 2017 Elsevier Ltd. All rights reserved.

  5. Method validation for control determination of mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry.

    Science.gov (United States)

    Torres, Daiane Placido; Martins-Teixeira, Maristela Braga; Cadore, Solange; Queiroz, Helena Müller

    2015-01-01

    A method for the determination of total mercury in fresh fish and shrimp samples by solid sampling thermal decomposition/amalgamation atomic absorption spectrometry (TDA AAS) has been validated following international foodstuff protocols in order to fulfill the Brazilian National Residue Control Plan. The experimental parameters have been previously studied and optimized according to specific legislation on validation and inorganic contaminants in foodstuff. Linearity, sensitivity, specificity, detection and quantification limits, precision (repeatability and within-laboratory reproducibility), robustness as well as accuracy of the method have been evaluated. Linearity of response was satisfactory for the two range concentrations available on the TDA AAS equipment, between approximately 25.0 and 200.0 μg kg(-1) (square regression) and 250.0 and 2000.0 μg kg(-1) (linear regression) of mercury. The residues for both ranges were homoscedastic and independent, with normal distribution. Correlation coefficients obtained for these ranges were higher than 0.995. Limits of quantification (LOQ) and of detection of the method (LDM), based on signal standard deviation (SD) for a low-in-mercury sample, were 3.0 and 1.0 μg kg(-1), respectively. Repeatability of the method was better than 4%. Within-laboratory reproducibility achieved a relative SD better than 6%. Robustness of the current method was evaluated and pointed sample mass as a significant factor. Accuracy (assessed as the analyte recovery) was calculated on basis of the repeatability, and ranged from 89% to 99%. The obtained results showed the suitability of the present method for direct mercury measurement in fresh fish and shrimp samples and the importance of monitoring the analysis conditions for food control purposes. Additionally, the competence of this method was recognized by accreditation under the standard ISO/IEC 17025.

  6. A Method to Measure Thermal Deformation of Superconducting Magnet Cross Sections

    OpenAIRE

    Grau-Carles, A; García-Tabarés, L; Todesco, Ezio; Tommasini, D; Siegel, N

    1999-01-01

    The precision measurement of the cable positioning in superconducting coils is of great interest both at room and liquid nitrogen temperatures because mechanical and thermal deformations affect the quality of the magnetic field. The paper describes a new two-coordinate measuring device, which is able to obtain scanned images of flat composite samples at liquid nitrogen temperature. The sample is cooled at 77 K into a flat quartz tray to permit the optical access to the sample from the bottom....

  7. Neutron scattering and absorption properties

    Energy Technology Data Exchange (ETDEWEB)

    Holden, N.E.

    1993-12-01

    The Table in this report presents an evaluated set of values for the experimental quantities, which characterize the properties for scattering and absorption of neutrons. The neutron cross section is given for room temperature neutrons, 20.43{degree}C, corresponds to a thermal neutron energy of 0.0253 electron volts (eV) or a neutron velocity of 2200 meters/second. The neutron resonance integral is defined over the energy range from 0.5 eV to 0.1 {times} 10{sup 6} eV, or 0.1 MeV. A list of the major references used is given below. The literature cutoff data is October 1993. Uncertainties are given in parentheses. Parentheses with two or more numbers indicate values to the excited states(s) and to the ground state of the product nucleus.

  8. Unsteady thermal field in bars of doubly connected cross section with heat generation

    International Nuclear Information System (INIS)

    Ercoli, L.; Laura, P.A.A.; Grossi, R.O.; Sanchez Sarmiento, G.

    1985-01-01

    The title problem is approximately solved by means of a variational formulation. It is shown that in the case of complicated boundary shapes of the cross section, the technique of conformal mapping is, sometimes, quite advantageous. The analytical predictions are compared with the results obtained by means of the finite element method and, in general, good engineering agreement is shown to exist. (orig.)

  9. Ultrasonic absorption

    International Nuclear Information System (INIS)

    Beyer, R.T.

    1985-01-01

    The paper reviews studies of ultrasonic absorption in liquid alkali metals. The experimental methods to measure the absorption coefficients are briefly described. Experimental results reported for the liquid metals: sodium, potassium, rubidium and caesium, at medium temperatures, are presented, as well as data for liquid alloys. Absorption losses due to the presence of an external magnetic field, and the effects of viscosity on the absorption in metals, are both discussed. (U.K.)

  10. Measurement of the neutron capture cross section of the fissile isotope 235U with the CERN n{sub T}OF Total Absorption Calorimeter and fission tagging based on micromegas detectors

    Energy Technology Data Exchange (ETDEWEB)

    Balibrea, J.; Mendoza, E.; Cano-Ott, D.; Berthomieux, E.; Guerrero, C.; TOF Collaboration

    2015-07-01

    The future nuclear technologies require accurate nuclear data on neutron-induced capture cross sections and α ratios of fissile isotopes. The measurement of their cross section present several difficulties, most of them related to the larger fission γ-ray background competing with the weaker γ-ray cascades from the capture reactions used as signal. A specific setup was used for the measurement of 235U capture cross section at the CERN n{sub T}OF facility in 2012. The setup consists of a set of micromegas fission detectors surrounding the 235U samples all placed inside a segmented BaF2 Total Absorption Calorimeter. (Author)

  11. Thermal neutron capture cross section for Fe-56(n,gamma)

    Czech Academy of Sciences Publication Activity Database

    Firestone, R. B.; Belgya, T.; Krtička, M.; Bečvář, F.; Szentmiklosi, L.; Tomandl, Ivo

    2017-01-01

    Roč. 95, č. 1 (2017), č. článku 014328. ISSN 2469-9985 R&D Projects: GA ČR GA13-07117S; GA MŠk LM2015056 Institutional support: RVO:61389005 Keywords : neutron cross section * gamma gamma-coincidence data Subject RIV: BG - Nuclear, Atomic and Molecular Physics, Colliders OBOR OECD: Nuclear physics Impact factor: 3.820, year: 2016

  12. Starburst triarylamine donor-acceptor-donor quadrupolar derivatives based on cyano-substituted diphenylaminestyrylbenzene: tunable aggregation-induced emission colors and large two-photon absorption cross sections.

    Science.gov (United States)

    Wang, Bing; Wang, Yaochuan; Hua, Jianli; Jiang, Yihua; Huang, Jinhai; Qian, Shixiong; Tian, He

    2011-02-25

    In this work, we have developed a new class of aggregation-induced emission (AIE) active compounds, in which three electron-donating diphenylamine, phenothiazine, or carbazole groups are connected to the 1, 4-positions of the benzene through bis(α-cyano-4-diphenylaminostyryl) conjugation bridges to form three triarylamine quadrupolar derivatives (3 a-c). Their one- and two-photon absorption properties have been investigated. The two-photon absorption (2PA) cross sections measured by the open-aperture Z-scan technique were determined to be 1016, 1484, and 814 GM for 3 a-c, respectively. From this result, the high 2PA properties of these molecules are attributed to the extended π system and enhanced intramolecular charge transfer from the starburst triarylamine to the cyano group. Moreover, cyano-substituted diphenylamine styrylbenzene (CNDPASB)-based compounds are very weakly fluorescent in THF, but their intensities increase by almost 230, 70, and 5 times, respectively, in water/THF (v/v 90 %) mixtures, in which they exhibit strongly enhanced red, orange, and deep yellow fluorescence emissions, respectively. This result indicates that the intramolecular vibration and rotation of these dyes is considerably restricted in nano-aggregates formed in water, leading to significant increases in fluorescence. It was found that the color tuning of the CNDPASB-based compounds could be conveniently accomplished by changing the starburst triarylamine donor moiety. Multilayer electroluminescence devices with TPBI (2,2',2''-(benzene-1,3,5-triyl)-tri(1-phenyl-1H-benzimidazole)) electron-transporting layers have been made, with 3 a and 3 c as a non-doping red-yellow emitter. The preliminary results for these multilayer devices show a maximum efficiency of 0.25 %, and electroluminescence (EL) wavelengths around 568 nm. The excellent 2PA and AIE properties of these compounds make them potential materials for biophotonic applications. Copyright © 2011 WILEY

  13. High-resolution cross-borehole thermal tracer testing in granite: preliminary field results

    Science.gov (United States)

    Brixel, Bernard; Klepikova, Maria; Jalali, Mohammadreza; Amann, Florian; Loew, Simon

    2017-04-01

    Understanding how heat is transported, stored and exchanged across fractured media is becoming increasingly relevant in our society, as manifested from the growing popularity of modern technologies relying on the subsurface to either source or store heat. One good example is the utilization of heat from deep hydrothermal or petrothermal systems to generate electricity for base load power generation, a technology also known as deep geothermal energy (DGE). While very attractive in principle, the number of geothermal fields producing economical levels of electricity to this day is still very limited - largely due to the difficulty of either locating deep reservoirs that are both sufficiently hot and permeable or, in the absence of the latter, creating them. In this context, the Swiss Competence Center for Energy Research - Supply of Electricity (SCCER - SoE) is carrying out an in situ stimulation and circulation (ISC) experiment at the Grimsel Test Site (GTS), an underground rock lab located in the Aar massif, in the Swiss Alps. The circulation experiment planned for the post-stimulation phase represents one of the key components of this experimental research program, and the outcome of this test is expected to ultimately provide key insights in the factors controlling the performance of enhanced geothermal reservoirs. Therefore, to support the design of this experiment, short-term thermal tracer tests (TTT) were conducted with the objective to (i) assess the feasibility of conducting TTTs in a relatively intact granite (where fluid flow is controlled by a limited number of discrete fractures); (ii) determine optimal experimental setups; and to ultimately (iii) monitor thermal breakthroughs at high spatial and temporal resolution, providing insights on heat transport and complementing the characterization of hydrogeological conditions carried out through conventional means (e.g. hydraulic and/or solute tracer tests). Presented herein are the results of a 10-day

  14. Measurements of thermal fission and capture cross sections of minor actinides within the Mini-INCA project

    International Nuclear Information System (INIS)

    Bringer, O.; Chabod, S.; Dupont, E.; Letourneau, A.; Panebianco, S.; Veyssiere, Ch.; Oriol, L.; Chartier, F.; Mutti, P.; AlMahamid, I.

    2008-01-01

    In the framework of nuclear waste transmutation studies, the Mini-INCA project has been initiated at Cea/DSM to determine optimal conditions for transmutation and incineration of Minor Actinides in high intensity neutron fluxes in the thermal region. Our experimental tool is based on alpha- and gamma-spectroscopy of irradiated samples and microscopic fission-chambers. It can provide both microscopic information on nuclear reactions (total and partial cross sections for neutron capture and/or fission reactions) and macroscopic information on transmutation and incineration potentials. The 232 Th, 237 Np, 241 Am, and 244 Cm transmutation chains have been explored in details, showing some discrepancies in comparison with evaluated data libraries but in overall good agreement with recent experimental data. (authors)

  15. Measurements of thermal neutron cross section and resonance integral for the 237Np(n,γ)238Np reaction

    International Nuclear Information System (INIS)

    Kobayashi, Katsuhei; Yamanaka, Akihiro; Kimura, Itsuro

    1994-01-01

    Making use of a standard neutron spectrum field with a pure Maxwellian distribution at the heavy water thermal neutron facility of the Kyoto University Reactor (KUR), the thermal neutron cross section for the 237 Np(n,γ) 238 Np reaction was measured by the activation method, using a high purity Ge detector. The result is 158 ± 3 b, which is obtained relative to the reference value of 98.65 ± 0.09 b for the 197 Au(n,γ) 198 Au reaction. The present value is lower by about 13% than that of the ENDF/B-VI data. The data given by Mughabghab and obtained from JENDL-3 are larger by 11 to 14% than the present measurement. The resonance integral for the 237 Np(n,γ) 238 Np reaction was measured with a 1/E standard neutron spectrum in the cavity of the central graphite reflector region between the two-divided cores of the Kinki University Reactor (UTR-KINK), relative to the reference value of 1,550 ± 28 b for the 197 Au(n,γ) 198 Au reaction. By defining the Cd cut-off energy as 0.5 eV, the present resonance integral is 652 ± 24 b, which is in good agreement with the JENDL-3, ENDF/B-VI and Mughabghab data. However, most of the old experimental data are, in general, larger by 24 to 38% than the present measurement

  16. A experimental system for the checking of the absorption of E.C.A.G. graphite

    International Nuclear Information System (INIS)

    Raievski, V.; Vidal, R.

    1958-01-01

    A system is described for measuring the mean absorption cross section in thermal neutrons of graphite. This system consists of a graphite stack containing a Ra-Be source and a BF3 counter. A cavity in the stack receives the graphite to be studied or the graphite standard. By comparing the counting rates their absorption ratio can be deduced. The measurement is performed on graphite rods which have been machined before being placed in the pile. It provides the possibility of detecting over a batch of 1 ton of graphite, in a single measurement, a difference in absorption of 0.1 milli barn. (author) [fr

  17. Comparative investigation of thermal and mechanical properties of cross-linked epoxy polymers with different curing agents by molecular dynamics simulation.

    Science.gov (United States)

    Jeyranpour, F; Alahyarizadeh, Gh; Arab, B

    2015-11-01

    Molecular dynamics (MD) simulations were carried out to predict the thermal and mechanical properties of the cross-linked epoxy system composed of DGEBA resin and the curing agent TETA. To investigate the effects of curing agents, a comprehensive and comparative study was also performed on the thermal and mechanical properties of DGEBA/TETA and DGEBA/DETDA epoxy systems such as density, glass transition temperature (Tg), coefficient of thermal expansion (CTE) and elastic properties of different cross-linking densities and different temperatures. The results indicated that the glass transition temperature of DGEBA/TETA system calculated through density-temperature data, ∼ 385-395 °K, for the epoxy system with the cross-linking density of 62.5% has a better agreement with the experimental value (Tg, ∼ 400 °K) in comparison to the value calculated through the variation of cell volume in terms of temperature, 430-440 °K. They also indicated that CTE related parameters and elastic properties including Young, Bulk, and shear's moduli, and Poisson's ratio have a relative agreement with the experimental results. Comparison between the thermal and mechanical properties of epoxy systems of DGEBA/TETA and DGEBA/DETDA showed that the DGEBA/DETDA has a higher Tg in all cross linking densities than that of DGEBA/TETA, while higher mechanical properties was observed in the case of DGEBA/TETA in almost all cross linking densities. Copyright © 2015 Elsevier Inc. All rights reserved.

  18. Monte Carlo cross section testing for thermal and intermediate 235U/238U critical assemblies, ENDF/B-V vs ENDF/B-VI

    International Nuclear Information System (INIS)

    Weinman, J.P.

    1997-06-01

    The purpose of this study is to investigate the eigenvalue sensitivity to changes in ENDF/B-V and ENDF/B-VI cross section data sets by comparing RACER vectorized Monte Carlo calculations for several thermal and intermediate spectrum critical experiments. Nineteen Oak Ridge and Rocky Flats thermal solution benchmark critical assemblies that span a range of hydrogen-to- 235 U (H/U) concentrations (2052 to 27.1) and above-thermal neutron leakage fractions (0.555 to 0.011) were analyzed. In addition, three intermediate spectrum critical assemblies (UH3-UR, UH3-NI, and HISS-HUG) were studied

  19. Effective cross section values for well-moderated thermal reactor spectra

    Energy Technology Data Exchange (ETDEWEB)

    Westcott, C.H

    1970-11-15

    This document replaces the earlier versions (CRRP-680 and CRRP-787) and now employs the {sigma} (E) information contained in Supplement 1 (1960) of the 2nd edition of BNL-325 and other data privately collected to a cut-off date of April 1, 1960. The compilation is also enlarged to include higher temperatures (thus superseding CRRP-862) and for the first time also includes s-factors calculated using the epithermal cut-off functions exhibiting a maximum at just above the cut-off energy, which have recently been indicated by Swedish and U.K. measurements, as well as by analysis of some calculated spectra. As in the earlier compilation, the notation of the author's Geneva Conference (1958) paper is used, the effective cross section {sigma} being given in terms of the 2200 m/sec. value {sigma}{sub o} by the relation {sigma} {sigma}{sub o} (g + rs), where g and s are the factors listed in this compilation and r is a measure of the proportion of epithermal neutrons in the reactor spectrum. (author)

  20. Quantum Absorption Refrigerator

    Science.gov (United States)

    Levy, Amikam; Kosloff, Ronnie

    2012-02-01

    A quantum absorption refrigerator driven by noise is studied with the purpose of determining the limitations of cooling to absolute zero. The model consists of a working medium coupled simultaneously to hot, cold, and noise baths. Explicit expressions for the cooling power are obtained for Gaussian and Poisson white noise. The quantum model is consistent with the first and second laws of thermodynamics. The third law is quantified; the cooling power Jc vanishes as Jc∝Tcα, when Tc→0, where α=d+1 for dissipation by emission and absorption of quanta described by a linear coupling to a thermal bosonic field, where d is the dimension of the bath.

  1. Thermal behavior of J-aggregates in mixed Langmuir-Blodgett films composed of merocyanine dye and deuterated arachidic acid investigated by UV-visible and infrared absorption spectroscopy.

    Science.gov (United States)

    Hirano, Yoshiaki; Tateno, Shinsuke; Ozaki, Yukihiro

    2007-06-19

    We have investigated the thermal behavior of J-aggregates in the mixed Langmuir-Blodgett (LB) films composed of the merocyanine dye (MS18)-deuterated arachidic acid (C20-d) binary system in the temperature range from 25 to 250 degrees C by means of UV-visible and IR transmission absorption spectroscopy. The temperature-dependent variations in both UV-visible and IR absorption spectra indicate that the MS18 aggregation states are linked with the MS18 intramolecular charge transfer and the behavior of the packing, orientation, conformation, and thermal mobility of the MS18 hydrocarbon chain. The J-aggregate formed at 25 degrees C in the mixed LB films dissociates in the temperature range from 25 to 110 degrees C, which is mainly ascribed to the increase in the thermal mobility of MS18 hydrocarbon chain and the dissociation of the chelation by a cadmium ion to the MS18 keto group. A thermally induced blue-shifted band appears at around 515 nm from 110 to 160 degrees C. This band is attributed to oligomeric aggregation with side-by-side alignment of the MS18 transition dipole moments on the basis of the shift to a higher-energy side, broadening, and temporary increment of the MS18 intramolecular charge transfer of the band. Consequently, the appearance of the thermally induced blue-shifted band indicates the possibility that the MS18 aggregation states can be controlled from the red shift to the blue shift by the annealing method adopted in the present study.

  2. Absorption studies

    International Nuclear Information System (INIS)

    Ganatra, R.D.

    1992-01-01

    Absorption studies were once quite popular but hardly anyone does them these days. It is easier to estimate the blood level of the nutrient directly by radioimmunoassay (RIA). However, the information obtained by estimating the blood levels of the nutrients is not the same that can be obtained from the absorption studies. Absorption studies are primarily done to find out whether some of the essential nutrients are absorbed from the gut or not and if they are absorbed, to determine how much is being absorbed. In the advanced countries, these tests were mostly done to detect pernicious anaemia where vitamin B 12 is not absorbed because of the lack of the intrinsic factor in the stomach. In the tropical countries, ''malabsorption syndrome'' is quire common. In this condition, several nutrients like fat, folic acid and vitamin B 12 are not absorbed. It is possible to study absorption of these nutrients by radioisotopic absorption studies

  3. Measurement of the thermal neutron capture cross section and the resonance integral of the {sup 109}Ag(n,{gamma}){sup 110m}Ag reaction

    Energy Technology Data Exchange (ETDEWEB)

    Nakamura, S.; Wada, H.; Furutaka, K.; Harada, H.; Katoh, T. [Japan Nuclear Cycle Development Inst., Tokai Works, Tokai, Ibaraki (Japan)

    2001-03-01

    The thermal neutron capture cross section ({sigma}{sub 0}) and the resonance integral (I{sub 0}) of the {sup 109}Ag(n,{gamma}) reaction were measured by the activation and {gamma}-ray spectroscopic methods to develop a neutron flux monitor for the long irradiation. (author)

  4. Measurement of the thermal neutron capture cross section and the resonance integral of the 109Ag(n,γ)110mAg reaction

    International Nuclear Information System (INIS)

    Nakamura, S.; Wada, H.; Furutaka, K.; Harada, H.; Katoh, T.

    2001-01-01

    The thermal neutron capture cross section (σ 0 ) and the resonance integral (I 0 ) of the 109 Ag(n,γ) reaction were measured by the activation and γ-ray spectroscopic methods to develop a neutron flux monitor for the long irradiation. (author)

  5. Absorption of water vapour in the falling film of water-(LiBr + LiI + LiNO{sub 3} + LiCl) in a vertical tube at air-cooling thermal conditions

    Energy Technology Data Exchange (ETDEWEB)

    Bourouis, Mahmoud; Valles, Manel; Medrano, Marc; Coronas, Alberto [Centro de Innovacion Tecnologica en Revalorizacion Energetica y Refrigeracion, CREVER, Universitat Rovira i Virgili, Autovia de Salou, s/n, 43006, Tarragona (Spain)

    2005-05-01

    In air-cooled water-LiBr absorption chillers the working conditions in the absorber and condenser are shifted to higher temperatures and concentrations, thereby increasing the risk of crystallisation. To develop this technology, two main problems are to be addressed: the availability of new salt mixtures with wider range of solubility than water-LiBr, and advanced absorber configurations that enable to carry out simultaneously an appropriate absorption process and an effective air-cooling. One way of improving the solubility of LiBr aqueous solutions is to add other salts to create multicomponent salt solutions. The aqueous solution of the quaternary salt system (LiBr + LiI + LiNO{sub 3} + LiCl) presents favourable properties required for air-cooled absorption systems: less corrosive and crystallisation temperature about 35 K lower than that of water-LiBr.This paper presents an experimental study on the absorption of water vapour over a wavy laminar falling film of an aqueous solution of (LiBr + LiI + LiNO{sub 3} + LiCl) on the inner wall of a water-cooled smooth vertical tube. Cooling water temperatures in the range 30-45 C were selected to simulate air-cooling thermal conditions. The results are compared with those obtained in the same experimental set-up with water-LiBr solutions.The control variables for the experimental study were: absorber pressure, solution Reynolds number, solution concentration and cooling water temperature. The parameters considered to assess the absorber performance were: absorber thermal load, mass absorption flux, degree of subcooling of the solution leaving the absorber, and the falling film heat transfer coefficient.The higher solubility of the multicomponent salt solution makes possible the operation of the absorber at higher salt concentration than with the conventional working fluid water-LiBr. The absorption fluxes achieved with water-(LiBr + LiI + LiNO{sub 3} + LiCl) at a concentration of 64.2 wt% are around 60 % higher than

  6. Measurement of the thermal cross section of the reaction 64Zn(n,γ)65Zn in a mixed neutron flux

    International Nuclear Information System (INIS)

    Dorval, E. L; Arribere, M. A; Ribeiro Guevara, S

    2006-01-01

    Zinc is an element that is present in a great variety of biological and geological samples.For its determination by Instrumental Neutron Activation Analysis, the reaction 64 Z n(n,γ) 6 5Zn is used, due to the long half life of the reaction product, the target's bigger isotopic abundance, and an easily measurable 1115 keV main gamma line.In a recent evaluation of thermal cross sections and resonance integrals, a thermal cross section value that is 44.7% bigger than the previous evaluation has been published by the same reference.This difference is not within reported uncertainties.Besides, the relative uncertainty of the new evaluation is much bigger than the one corresponding to the previous evaluation.The adoption of the thermal cross section corresponding to different evaluations may imply, in the case of an irradiation in the peripheral I 6 position at the R A-6 reactor, discrepancies of about 43% in the calculated concentrations.These inconsistencies were evident during the irradiation of certified standard materials.This motivated the measurement of the thermal cross section for the reaction 64 Z n(n,γ) 6 5Zn in the I 6 position at the R A-6 reactor.For the analysis of results, a code was written in order to calculate correction factors from an accurate characterization of the neutron spectrum.The thermal cross section value of the reaction 64 Z n(n,γ) 6 5Zn measured is (0.76± 0.03) b [es

  7. Folate absorption

    International Nuclear Information System (INIS)

    Baker, S.J.

    1976-01-01

    Folate is the generic term given to numerous compounds of pteroic acid with glutamic acid. Knowledge of absorption is limited because of the complexities introduced by the variety of compounds and because of the inadequacy of investigational methods. Two assay methods are in use, namely microbiological and radioactive. Techniques used to study absorption include measurement of urinary excretion, serum concentration, faecal excretion, intestinal perfusion, and haematological response. It is probably necessary to test absorption of both pteroylmonoglutamic acid and one or more polyglutamates, and such tests would be facilitated by availability of synthesized compounds labelled with radioactive tracers at specifically selected sites. (author)

  8. Absorption cooling device. Absorptions-Kuehlvorrichtung

    Energy Technology Data Exchange (ETDEWEB)

    Bourne, J.; Vardi, I.; Kimchi, Y.; Ben-Dror, J.

    1980-03-25

    The invention concerns improvements of absorption refrigerators, where a lithium chloride or lithium bromide/water cycle is used. According to the invention an inner separating or dividing structure between different functional parts of a machine of this type is provided. The structure contains two sections of wall, which are separated from one another by a suitable space, in order to achieve thermal insulation. This air space is provided with an opening in the direction towards the inside of the container and the opening is shielded to prevent the entry of liquids (in liquid or spray form).

  9. Narrative absorption

    DEFF Research Database (Denmark)

    Narrative Absorption brings together research from the social sciences and Humanities to solve a number of mysteries: Most of us will have had those moments, of being totally absorbed in a book, a movie, or computer game. Typically we do not have any idea about how we ended up in such a state. Nor...... do we fully realize how we might have changed as we return for the fictional worlds we have visited. The feeling of being absorbed is one of the most illusive and transient feelings, but also one that motivates audiences to spend considerable amounts of time in narrative worlds, and one...... that is central to our understanding of the effects of narratives on beliefs and behavior. Key specialists inform the reader of this book about the nature of the peculiar state of consciousness during episodes of absorption, the perception of absorption in history, the role of absorption in meaningful experiences...

  10. Measurement of the neutron capture cross section of the fissile isotope 235U with the CERN n_TOF total absorption calorimeter and a fission tagging based on micromegas detectors

    Directory of Open Access Journals (Sweden)

    Balibrea-Correa J.

    2017-01-01

    Full Text Available The accuracy on neutron capture cross section of fissile isotopes must be improved for the design of future nuclear systems such as Gen-IV reactors and Accelerator Driven Systems. The High Priority Request List of the Nuclear Energy Agency, which lists the most important nuclear data requirements, includes also the neutron capture cross sections of fissile isotopes such as 233,235U and 239,241Pu. A specific experimental setup has been used at the CERN n_TOF facility for the measurement of the neutron capture cross section of 235U by a set of micromegas fission detectors placed inside a segmented BaF2 Total Absorption Calorimeter.

  11. Multifunctional hybrids for electromagnetic absorption

    Energy Technology Data Exchange (ETDEWEB)

    Huynen, I. [Research Center in Micro and Nanoscopic Materials and Electronic Devices, CeRMiN, Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Information and Communications Technologies, Electronics and Applied Mathematics (ICTEAM), Microwave Laboratory, Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Quievy, N. [Institute of Condensed Matter and Nanosciences (IMCN), Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Bailly, C. [Research Center in Micro and Nanoscopic Materials and Electronic Devices, CeRMiN, Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Institute of Condensed Matter and Nanosciences (IMCN), Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Institute of Mechanics, Materials and Civil Engineering (iMMC), Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Bollen, P. [Information and Communications Technologies, Electronics and Applied Mathematics (ICTEAM), Microwave Laboratory, Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Institute of Condensed Matter and Nanosciences (IMCN), Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Institute of Mechanics, Materials and Civil Engineering (iMMC), Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Detrembleur, C. [Center for Education and Research on Macromolecules (CERM), University of Liege, Sart-Tilman B6a, 4000 Liege (Belgium); Eggermont, S.; Molenberg, I. [Information and Communications Technologies, Electronics and Applied Mathematics (ICTEAM), Microwave Laboratory, Universite catholique de Louvain, B-1348 Louvain-la-Neuve (Belgium); Thomassin, J.M.; Urbanczyk, L. [Center for Education and Research on Macromolecules (CERM), University of Liege, Sart-Tilman B6a, 4000 Liege (Belgium)

    2011-05-15

    Highlights: > EM absorption requires low dielectric constant and {approx}1 S/m electrical conductivity. > New hybrids were processed with CNT-filled polymer foam inserted in Al honeycomb. > The EM absorption in the GHz range is superior to any known material. > A closed form model is used to guide the design of the hybrid. > The architectured material is light with potential for thermal management. - Abstract: Electromagnetic (EM) interferences are ubiquitous in modern technologies and impact on the reliability of electronic devices and on living cells. Shielding by EM absorption, which is preferable over reflection in certain instances, requires combining a low dielectric constant with high electrical conductivity, which are antagonist properties in the world of materials. A novel class of hybrid materials for EM absorption in the gigahertz range has been developed based on a hierarchical architecture involving a metallic honeycomb filled with a carbon nanotube-reinforced polymer foam. The waveguide characteristics of the honeycomb combined with the performance of the foam lead to unexpectedly large EM power absorption over a wide frequency range, superior to any known material. The peak absorption frequency can be tuned by varying the shape of the honeycomb unit cell. A closed form model of the EM reflection and absorption provides a tool for the optimization of the hybrid. This designed material sets the stage for a new class of sandwich panels combining high EM absorption with mass efficiency, stiffness and thermal management.

  12. Multifunctional hybrids for electromagnetic absorption

    International Nuclear Information System (INIS)

    Huynen, I.; Quievy, N.; Bailly, C.; Bollen, P.; Detrembleur, C.; Eggermont, S.; Molenberg, I.; Thomassin, J.M.; Urbanczyk, L.

    2011-01-01

    Highlights: → EM absorption requires low dielectric constant and ∼1 S/m electrical conductivity. → New hybrids were processed with CNT-filled polymer foam inserted in Al honeycomb. → The EM absorption in the GHz range is superior to any known material. → A closed form model is used to guide the design of the hybrid. → The architectured material is light with potential for thermal management. - Abstract: Electromagnetic (EM) interferences are ubiquitous in modern technologies and impact on the reliability of electronic devices and on living cells. Shielding by EM absorption, which is preferable over reflection in certain instances, requires combining a low dielectric constant with high electrical conductivity, which are antagonist properties in the world of materials. A novel class of hybrid materials for EM absorption in the gigahertz range has been developed based on a hierarchical architecture involving a metallic honeycomb filled with a carbon nanotube-reinforced polymer foam. The waveguide characteristics of the honeycomb combined with the performance of the foam lead to unexpectedly large EM power absorption over a wide frequency range, superior to any known material. The peak absorption frequency can be tuned by varying the shape of the honeycomb unit cell. A closed form model of the EM reflection and absorption provides a tool for the optimization of the hybrid. This designed material sets the stage for a new class of sandwich panels combining high EM absorption with mass efficiency, stiffness and thermal management.

  13. A measuring method of photo-electric cross section. Application to high-Z elements between 40 keV and 220 keV. Measurement of K absorption edge energy of Au, Th, U, Pu

    International Nuclear Information System (INIS)

    Chartier, J.-L.

    1977-09-01

    This study first describes a bent crystal monochromator developed for the production of monochromatic beams in a continuous energy range from 30 to 250 keV; it is completed by a metrological application of the device (determination of K absorption edge energy of Au, Th, U, Pu). A method and the associated experimental procedure were developed to measure the photo-electric cross section for high-Z elements; the results are presented with a relative uncertainty ranging between 3 and 6%. Finally, the experimental values are compared with values calculated from theories using self-consistent potential models [fr

  14. Ultra-violet absorption cross sections of isotopically substituted nitrous oxide species: 14N14NO, 15N14NO, 14N15NO and 15N15NO

    Directory of Open Access Journals (Sweden)

    P. von Hessberg

    2004-01-01

    Full Text Available The isotopically substituted nitrous oxide species 14N14NO, 15N14NO, 14N15NO and 15N15NO were investigated by ultra-violet (UV absorption spectroscopy. High precision cross sections were obtained for the wavelength range 181 to 218nm at temperatures of 233 and 283K. These data are used to calculate photolytic isotopic fractionation constants as a function of wavelength. The fractionation constants were used in a three-dimensional chemical transport model in order to simulate the actual fractionation of N2O in the stratosphere, and the results were found to be in good agreement with field studies.

  15. Micro-scale thermal imaging of CO2 absorption in the thermochemical energy storage of Li metal oxides at high temperature

    Science.gov (United States)

    Morikawa, Junko; Takasu, Hiroki; Zamengo, Massimiliano; Kato, Yukitaka

    2017-05-01

    Li-Metal oxides (typical example: lithium ortho-silicate Li4SiO4) are regarded as a novel solid carbon dioxide CO2 absorbent accompanied by an exothermic reaction. At temperatures above 700°C the sorbent is regenerated with the release of the captured CO2 in an endothermic reaction. As the reaction equilibrium of this reversible chemical reaction is controllable only by the partial pressure of CO2, the system is regarded as a potential candidate for chemical heat storage at high temperatures. In this study, we applied our recent developed mobile type instrumentation of micro-scale infrared thermal imaging system to observe the heat of chemical reaction of Li4SiO4 and CO2 at temperature higher than 600°C or higher. In order to quantify the micro-scale heat transfer and heat exchange in the chemical reaction, the superimpose signal processing system is setup to determine the precise temperature. Under an ambient flow of carbon dioxide, a powder of Li4SiO4 with a diameter 50 micron started to shine caused by an exothermic chemical reaction heat above 600°C. The phenomena was accelerated with increasing temperature up to 700°C. At the same time, the reaction product lithium carbonate (Li2CO3) started to melt with endothermic phase change above 700°C, and these thermal behaviors were captured by the method of thermal imaging. The direct measurement of multiple thermal phenomena at high temperatures is significant to promote an efficient design of chemical heat storage materials. This is the first observation of the exothermic heat of the reaction of Li4SiO4 and CO2 at around 700°C by the thermal imaging method.

  16. Exergy based parametric analysis of a combined reheat regenerative thermal power plant and water–LiBr vapor absorption refrigeration system

    International Nuclear Information System (INIS)

    Gogoi, T.K.; Talukdar, K.

    2014-01-01

    Highlights: • Exergy analysis of a combined power–absorption cooling system is provided. • Exergetic efficiency of the power cycle and absorption cooling system are calculated. • Irreversibility in each component and total system irreversibility are calculated. • Effect of operating parameters on exergetic performance and irreversibility is analyzed. • Optimum operating parameters are identified based on energy and exergy based results. - Abstract: In this paper, exergy analysis of a combined reheat regenerative steam turbine (ST) based power cycle and water–LiBr vapor absorption refrigeration system (VARS) is presented. Exergetic efficiency of the power cycle and VARS, energy utilization factor (EUF) of the combined system (CS) and irreversibility in each system component are calculated. The effect of fuel flow rate, boiler pressure, cooling capacity and VARS components’ temperature on performance, component and total system irreversibility is analyzed. The second law based results indicate optimum performance at 150 bar boiler pressure and VARS generator, condenser, evaporator and absorber temperature of 80 °C, 37.5 °C, 15 °C and 35 °C respectively. The present exergy based results conform well to the first law based results obtained in a previous analysis done on the same combined system. Irreversibility distribution among various power cycle components shows the highest irreversibility in the cooling tower. Irreversibility of the exhaust flue gas leaving the boiler and the boiler are the next major contributors. Among the VARS components, exergy destruction in the generator is the highest followed by irreversibility contribution of the absorber, condenser and the evaporator

  17. Measurement of the neutron capture cross section of the fissile isotope $^{235}$U with the CERN n_TOF Total Absorption Calorimeter and a fission tagging based on micromegas detectors

    CERN Document Server

    Mendoza, E; Cano-Ott, D; Guerrero, C; Berthoumieux, E; Altstadt, S; Andrzejewski, J; Audouin, L; Barbagallo, M; Bécares, V; Becvár, F; Belloni, F; Billowes, J; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Colonna, N; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Domingo-Pardo, C; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Giubrone, G; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Gunsing, F; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Käppeler, F; Karadimos, D; Kawano, T; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krticka, M; Kroll, J; Langer, C; Lampoudis, C; Leal-Cidoncha, E; Lederer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Massimi, C; Meaze, M; Mengoni, A; Milazzo, P M; Mingrone, F; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Stetcu, I; Sabaté, M; Tagliente, G; Tain, J L; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Ware, T; Weigand, M; Weiss, C; Wright, T; Zugec, P

    2014-01-01

    Actual and future nuclear technologies require more accurate nuclear data on the (n, $\\gamma$) cross sections and $\\alpha$-ratios of fissile isotopes. Their measurement presents several difficulties, mainly related to the strong fission $\\gamma$-ray background competing with the weaker $\\gamma$-ray cascades used as the experimental signature of the (n, $\\gamma$) process. A specific setup has been used at the CERN n_TOF facility in 2012 for the measurement of the (n,$\\gamma$ ) cross section and $\\alpha$- ratios of fissile isotopes and used for the case of the $^{235}$U isotope. The setup consists in a set of micromegas fission detectors surrounding $^{235}$U samples and placed inside the segmented BaF$_2$ Total Absorption Calorimeter.

  18. Measurement of the Neutron Capture Cross Section of the Fissile Isotope 235U with the CERN n_TOF Total Absorption Calorimeter and a Fission Tagging Based on Micromegas Detectors

    CERN Document Server

    Balibrea, J; Cano-Ott, D; Guerrero, C; Berthoumieux, E; Altstadt, S; Andrzejewski, J; Audouin, L; Barbagallo, M; Bécares, V; Bečvář, F; Belloni, F; Billowes, J; Boccone, V; Bosnar, D; Brugger, M; Calviani, M; Calviño, F; Carrapiço, C; Cerutti, F; Chiaveri, E; Chin, M; Colonna, N; Cortés, G; Cortés-Giraldo, M A; Diakaki, M; Domingo-Pardo, C; Duran, I; Dressler, R; Dzysiuk, N; Eleftheriadis, C; Ferrari, A; Fraval, K; Ganesan, S; García, A R; Giubrone, G; Gómez-Hornillos, M B; Gonçalves, I F; González-Romero, E; Griesmayer, E; Gunsing, F; Gurusamy, P; Jenkins, D G; Jericha, E; Kadi, Y; Käppeler, F; Karadimos, D; Kawano, T; Kivel, N; Koehler, P; Kokkoris, M; Korschinek, G; Krtička, M; Kroll, J; Langer, C; Lampoudis, C; Lederer, C; Leeb, H; Leong, L S; Losito, R; Manousos, A; Marganiec, J; Martínez, T; Mastinu, P F; Mastromarco, M; Massimi, C; Meaze, M; Mengoni, A; Milazzo, P M; Mingrone, F; Mirea, M; Mondelaers, W; Paradela, C; Pavlik, A; Perkowski, J; Pignatari, M; Plompen, A; Praena, J; Quesada, J M; Rauscher, T; Reifarth, R; Riego, A; Roman, F; Rubbia, C; Sarmento, R; Schillebeeckx, P; Schmidt, S; Schumann, D; Stetcu, I; Sabaté, M; Tagliente, G; Tain, J L; Tarrío, D; Tassan-Got, L; Tsinganis, A; Valenta, S; Vannini, G; Variale, V; Vaz, P; Ventura, A; Versaci, R; Vermeulen, M J; Vlachoudis, V; Vlastou, R; Wallner, A; Ware, T; Weigand, M; Weiß, C; Wright, T J; Žugec, P

    Current and future nuclear technologies require more accurate nuclear data on (n,γ) cross sections and the α-ratios of fissile isotopes. Their measurement presents several difficulties, mainly related to the strong fission γ-ray background competing with the weaker γ-ray cascades used as the experimental signature of the (n,γ) process. A specific setup was used at the CERN n_TOF facility in 2012 for the measurement of the (n,γ) cross section and α-ratios of fissile isotopes and used for the case of the 235U isotope. The setup consists of a set of micromegas fission detectors surrounding the 235U samples all placed inside a segmented BaF2 Total Absorption Calorimeter.

  19. Neutron absorption constraints on the composition of 4 Vesta

    Science.gov (United States)

    Prettyman, Thomas H.; Mittlefehldt, David W.; Yamashita, Naoyuki; Beck, Andrew W.; Feldman, William C.; Hendricks, John S.; Lawrence, David J.; McCoy, Timothy J.; McSween, Harry Y.; Paplowski, Patrick N.; Reedy, Robert C.; Toplis, Michael J.; Le Corre, Lucille; Mizzon, Hugau; Reddy, Vishnu; Titus, Timothy N.; Raymond, Carol A.; Russell, Christopher T.

    2013-01-01

    Global maps of the macroscopic thermal neutron absorption cross section of Vesta's regolith by the Gamma Ray and Neutron Detector (GRaND) on board the NASA Dawn spacecraft provide constraints on the abundance and distribution of Fe, Ca, Al, Mg, and other rock-forming elements. From a circular, polar low-altitude mapping orbit, GRaND sampled the regolith to decimeter depths with a spatial resolution of about 300 km. At this spatial scale, the variation in neutron absorption is about seven times lower than that of the Moon. The observed variation is consistent with the range of absorption for howardite whole-rock compositions, which further supports the connection between Vesta and the howardite, eucrite, and diogenite meteorites. We find a strong correlation between neutron absorption and the percentage of eucritic materials in howardites and polymict breccias, which enables petrologic mapping of Vesta's surface. The distribution of basaltic eucrite and diogenite determined from neutron absorption measurements is qualitatively similar to that indicated by visible and near infrared spectroscopy. The Rheasilvia basin and ejecta blanket has relatively low absorption, consistent with Mg-rich orthopyroxene. Based on a combination of Fe and neutron absorption measurements, olivine-rich lithologies are not detected on the spatial scales sampled by GRaND. The sensitivity of GRaND to the presence of mantle material is described and implications for the absence of an olivine signature are discussed. High absorption values found in Vesta's “dark” hemisphere, where exogenic hydrogen has accumulated, indicate that this region is richer in basaltic eucrite, representative of Vesta's ancient upper crust.

  20. The Performance of a Thermally Cross-Linked Polymer of Intrinsic Microporosity (PIM-1) for Gas Separation

    KAUST Repository

    Alghunaimi, Fahd

    2013-05-01

    Gas transport properties of PIM-1 (the first ladder polymer with intrinsic microporosity) and TC-PIM-1 (thermally cross-linked PIM-1) at 35°C and different pressures were thoroughly studied. The purpose of this study was to evaluate and compare the performance of the TC-PIM-1 membranes with PIM-1 for natural gas separation. The TC-PIM-1 polymer was prepared by post-modification of PIM-1 at 300°C for a period of two days. Sorption isotherms of seven gases, including N2, O2, CH4, CO2, C2H6, C3H8 and n-C4H10, were determined for PIM-1 and TC-PIM-1 using the dual-volume barometric sorption technique at 35°C at different pressures. The sorption isotherms followed the dual-mode sorption model, which is typical for glassy polymers. Moreover, permeability (P) of eight gases, including He, H2, N2, O2, CH4, CO2, C3H8 and n-C4H10, were determined for PIM-1 and TC-PIM-1 at 35°C and 2.0 atm. Furthermore, average diffusion coefficients (D ̅) were calculated from the permeability and solubility data for all tested gases for both polymers. The sorption (S), permeability (P) and average diffusion coefficients (D ̅) for the TC-PIM-1 membrane exhibited lower values than the PIM-1 membrane. However, the TC-PIM-1 membrane showed exceptional gas separation performance. The TC-PIM-1 membrane had a helium (He) permeability of 1218 barrer with He/CH4 and He/N2 ideal selectivities of 27.1 and 23.9 respectively, and carbon dioxide (CO2) permeability of 1088 barrer with CO2/CH4 and CO2/N2 ideal selectivities of 24.2 and 21.3 respectively. Additionally, the TC-PIM-1 membrane showed a hydrogen (H2) permeability of 2452 barrer with an ideal H2/CH4 selectivity of 54.5.

  1. Negative induced absorption and negative index of refraction for iron doped potash-alumina-borate glasses subjected to thermal-radiation treatment

    Science.gov (United States)

    Salakhitdinov, Amritdin; Ibragimova, Elvira; Salakhitdinova, Maysara

    2018-02-01

    This work experimentally revealed, that 60Co-gamma-irradiation of potash-alumina-borate glasses doped with 1 and 2 mass% of iron oxide to the dose of 1.7 MR in the temperature range of 150-300 °C induced differential optical density changes within - 6 ≤ Δ D ≤ 0 in the wave length range of 300-350 nm, which is characteristic for meta-material. Calculations have shown that variation of optical refraction index within - 0.05 ≤ Δ n ω ≤ 0.05 due to microstructure transformation causes changes in the differential absorption index of the glass - 0.5 < Δ α ω < 0.55.

  2. Effect of carbon nanotube functionalization on mechanical and thermal properties of cross-linked epoxy-carbon nanotube nanocomposites: role of strengthening the interfacial interactions.

    Science.gov (United States)

    Khare, Ketan S; Khabaz, Fardin; Khare, Rajesh

    2014-05-14

    We have used amido-amine functionalized carbon nanotubes (CNTs) that form covalent bonds with cross-linked epoxy matrices to elucidate the role of the matrix-filler interphase in the enhancement of mechanical and thermal properties in these nanocomposites. For the base case of nanocomposites of cross-linked epoxy and pristine single-walled CNTs, our previous work (Khare, K. S.; Khare, R. J. Phys. Chem. B 2013, 117, 7444-7454) has shown that weak matrix-filler interactions cause the interphase region in the nanocomposite to be more compressible. Furthermore, because of the weak matrix-filler interactions, the nanocomposite containing dispersed pristine CNTs has a glass transition temperature (Tg) that is ∼66 K lower than the neat polymer. In this work, we demonstrate that in spite of the presence of stiff CNTs in the nanocomposite, the Young's modulus of the nanocomposite containing dispersed pristine CNTs is virtually unchanged compared to the neat cross-linked epoxy. This observation suggests that the compressibility of the matrix-filler interphase interferes with the ability of the CNTs to reinforce the matrix. Furthermore, when the compressibility of the interphase is reduced by the use of amido-amine functionalized CNTs, the mechanical reinforcement due to the filler is more effective, resulting in a ∼50% increase in the Young's modulus compared to the neat cross-linked epoxy. Correspondingly, the functionalization of the CNTs also led to a recovery in the Tg making it effectively the same as the neat polymer and also resulted in a ∼12% increase in the thermal conductivity of the nanocomposite containing functionalized CNTs compared to that containing pristine CNTs. These results demonstrate that the functionalization of the CNTs facilitates the transfer of both mechanical load and thermal energy across the matrix-filler interface.

  3. Thermal evolution of Lower Paleozoic sedimentary successions from organic and inorganic studies: the case history of the Holy Cross Mountains (central Poland)

    Science.gov (United States)

    Trolese, Matteo; Stefano Celano, Antonio; Corrado, Sveva; Caricchi, Chiara; Schito, Andrea; Aldega, Luca

    2015-04-01

    The rapid increase in shale gas production in the USA has triggered a growing interest in unconventional resources in Eastern and Northern Europe. In this framework, the potential shale gas reserves in Poland are the most promising in Europe, extending from the Baltic Sea to the Ukraine border. In this area, the Baltic, Podlasie and Lublin basins have already become objective of shale gas exploration and the Holy Cross Mountains (HCM, Central Poland) represents the outcropping analog of the buried targeted Lower Paleozoic successions, providing a unique opportunity to study and assess source rock potential. In this work, we provide new thermal maturity data of Paleozoic rocks exposed in the HCM. A multi-method approach, coupling organic matter/graptolites (i.e., marine organoclasts) optical analysis and X-ray diffraction of clay-sized fraction of sediments, was applied to constrain the burial - thermal evolution of the sedimentary succession. The investigated area of the HCM includes two different tectonic blocks: the Łysogóry region to the North and the Kielce region to the South, separated by the Holy Cross Fault (HCF). lllite content in mixed layer illite-smectite determinations and vitrinite/graptolites reflectance measurements (Roeq%), performed on samples (Cambrian - Devonian) collected from both the regions, show a substantial difference between the two blocks in terms of thermal maturity and burial history. Roeq% values in the southern block range from 0.5% to 1.0%, with few exceptions, indicating early to mid-mature stage of hydrocarbon generation. Samples collected in the northern block show much higher values, mainly from 1.2% up to 1.7%, representative of the gas generation window. The I-S ordering type also shows relevant differences in the two blocks. In the southern block, mixed-layered clay minerals varies from R1 (short-range) to R3 (long-range), whereas R3 structures are recorded in the northern block. Vitrinite reflectance and mixed-layer I

  4. Measurement of the rate of hydrogen peroxide thermal decomposition in a shock tube using quantum cascade laser absorption near 7.7 μm

    KAUST Repository

    Sajid, Muhammad Bilal

    2013-10-24

    Hydrogen peroxide (H2O2) is formed during hydrocarbon combustion and controls the system reactivity under intermediate temperature conditions. Here, we measured the rate of hydrogen peroxide decomposition behind reflected shock waves using midinfrared absorption of H2O 2 near 7.7 μm. We performed the experiments in diluted H 2O2/Ar mixtures between 930 and 1235 K and at three different pressures (1, 2, and 10 atm). Under these conditions, the decay of hydrogen peroxide is sensitive only to the decomposition reaction rate, H 2O2 + M → 2OH + M (k1). The second-order rate coefficient at low pressures (1 and 2 atm) did not exhibit any pressure dependence, suggesting that the reaction was in the low-pressure limit. The rate data measured at 10 atm exhibited falloff behavior. The measured decomposition rates can be expressed in Arrhenius forms as follows: k1(1 and 2 atm)=10(16.29±0.12)× exp (-21993±301/T)(cm 3 mol -1s-1) k1(10 atm)=10(15.24±0.10)× exp (-19955±247/T)(cm 3 mol -1s-1) © 2013 Wiley Periodicals, Inc.

  5. Thermal neutron capture cross-section measurements of 243Am and 242Pu using the new mini-INCA α- and γ-spectroscopy station

    International Nuclear Information System (INIS)

    Marie, F.; Letourneau, A.; Fioni, G.; Deruelle, O.; Veyssiere, Ch.; Faust, H.; Mutti, P.; AlMahamid, I.; Muhammad, B.

    2006-01-01

    In the framework of the Mini-INCA project, dedicated to the study of Minor Actinide transmutation process in high neutron fluxes, an α- and γ-spectroscopy station has been developed and installed at the High Flux Reactor of the Laue-Langevin Institut. This set-up allows short irradiations as well as long irradiations in a high quasi-thermal neutron flux and post-irradiation spectroscopy analysis. It is well suited to measure precisely, in reference to 59 Co cross-section, neutron capture cross-sections, for all the actinides, in the thermal energy region. The first measurements using this set-up were done on 243 Am and 242 Pu isotopes. Cross-section values, at E n =0.025eV, were found to be (81.8+/-3.6)b for 243 Am and (22.5+/-1.1)b for 242 Pu. These values differ from evaluated data libraries by a factor of 9% and 17%, respectively, but are compatible with the most recent measurements, validating by the way the experimental apparatus

  6. Cellulose as an adhesion agent for the synthesis of lignin aerogel with strong mechanical performance, Sound-absorption and thermal Insulation.

    Science.gov (United States)

    Wang, Chao; Xiong, Ye; Fan, Bitao; Yao, Qiufang; Wang, Hanwei; Jin, Chunde; Sun, Qingfeng

    2016-08-26

    The lignin aerogels that are both high porosity and compressibility would have promising implications for bioengineering field to sound-adsorption and damping materials; however, creating this aerogel had a challenge to adhesive lignin. Here we reported cellulose as green adhesion agent to synthesize the aerogels with strong mechanical performance. Our approach-straightforwardly dissolved in ionic liquids and simply regenerated in the deionized water-causes assembly of micro-and nanoscale and even molecule level of cellulose and lignin. The resulting lignin aerogels exhibit Young's modulus up to 25.1 MPa, high-efficiency sound-adsorption and excellent thermal insulativity. The successful synthesis of this aerogels developed a path for lignin to an advanced utilization.

  7. Equilibrium crossing exhibited by an ethynylhelicene (M)-nonamer during random-coil-to-double-helix thermal transition in solution.

    Science.gov (United States)

    Miyagawa, Masamichi; Yagi, Atsushi; Shigeno, Masanori; Yamaguchi, Masahiko

    2014-11-28

    The structural change between the random-coil and the double-helix of an ethynylhelicene (M)-nonamer during heating crosses equilibrium. This is a phenomenon where a chemical reaction crosses equilibrium and returns to equilibrium. It is due to an accelerated rate of formation of the double-helix by self-catalysis and an equilibrium shift.

  8. Thermal behavior of H-aggregate in a mixed Langmuir-Blodgett film of merocyanine dye, arachidic acid, and n-octadecane ternary system investigated by UV-visible and IR absorption spectroscopy.

    Science.gov (United States)

    Hirano, Yoshiaki; Tateno, Shinsuke; Yamashita, Yoshihide; Ozaki, Yukihiro

    2008-11-13

    We have investigated the thermal behavior of H-aggregate in a mixed Langmuir-Blodgett (LB) film of the merocyanine dye (MS18)-arachidic acid (C20)- n-octadecane (AL18) ternary system by means of UV-visible and IR absorption spectroscopy in the range from 25 to 250 degrees C with a continuous scan. The results of both UV-visible and IR spectra indicate that the temperature-dependent variation in MS 18 aggregation state is linked not only with the degree of intramolecular charge transfer and the behavior of packing, orientation, conformation, and thermal mobility of the MS18 hydrocarbon chain but also with the presence and absence of AL18. The H-aggregate dissociates from 25 up to 50 degrees C, which is caused by the AL18 evaporation from the mixed LB film and the increment of thermal mobility of the MS18 hydrocarbon chain. From 110 to 160 degrees C, blue-shifted bands, attributed to the oligomeric MS18 aggregation, appear near 515 nm in the MS18-C 20-AL18 ternary system as well. The temperature at which the 515 nm band occurs is identical for both present ternary system and previously investigated MS18-deuterated arachidic acid (C20- d) binary system, and it is in good agreement with the melting point (110 degrees C) of cadmium arachidate (CdC20). Therefore, it is indicated that the driving force which induces the 515 nm band comes from the melting phenomenon of CdC20 molecules which are phase-separated from MS 18 molecules in as-deposited LB films.

  9. The total collision cross section of Ar-Ar as a function of velocity in the thermal range

    International Nuclear Information System (INIS)

    Linse, C.A.; Biesen, J.J.H. van den; Meijdenberg, C.J.N. van den

    1977-01-01

    To describe the Ar-Ar interaction several potentials have been proposed. These potentials have been derived starting from different bulk property data as well as spectroscopic and differential cross section data. The measurements of the glory structure in the total cross section as performed by Bredewout (1976) provided in principle an essential test for the existing potentials. However, the overall energy dependence of the measured cross sections was not in agreement with the theoretically predicted C 6 and C 8 values. Therefore new measurements were performed with improved angular and velocity resolution. There are still differences between the results of the measured and calculated cross sections. However, the energy dependence of the cross section remains within the limits to be expected from the theoretical predictions. (Auth.)

  10. Compression-absorption (resorption) refrigerating machinery. Modeling of reactors; Machine frigorifique a compression-absorption (resorption). Modelisation des reacteurs

    Energy Technology Data Exchange (ETDEWEB)

    Lottin, O.; Feidt, M.; Benelmir, R. [LEMTA-UHP Nancy-1, 54 - Vandoeuvre-les-Nancy (France)

    1997-12-31

    This paper is a series of transparencies presenting a comparative study of the thermal performances of different types of refrigerating machineries: di-thermal with vapor compression, tri-thermal with moto-compressor, with ejector, with free piston, adsorption-type, resorption-type, absorption-type, compression-absorption-type. A prototype of ammonia-water compression-absorption heat pump is presented and modeled. (J.S.)

  11. Method development for the control determination of mercury in seafood by solid-sampling thermal decomposition amalgamation atomic absorption spectrometry (TDA AAS).

    Science.gov (United States)

    Torres, D P; Martins-Teixeira, M B; Silva, E F; Queiroz, H M

    2012-01-01

    A very simple and rapid method for the determination of total mercury in fish samples using the Direct Mercury Analyser DMA-80 was developed. In this system, a previously weighted portion of fresh fish is combusted and the released mercury is selectively trapped in a gold amalgamator. Upon heating, mercury is desorbed from the amalgamator, an atomic absorption measurement is performed and the mercury concentration is calculated. Some experimental parameters have been studied and optimised. In this study the sample mass was about 100.0 mg. The relative standard deviation was lower than 8.0% for all measurements of solid samples. Two calibration curves against aqueous standard solutions were prepared through the low linear range from 2.5 to 20.0 ng of Hg, and the high linear range from 25.0 to 200.0 ng of Hg, for which a correlation coefficient better than 0.997 was achieved, as well as a normal distribution of the residuals. Mercury reference solutions were prepared in 5.0% v/v nitric acid medium. Lyophilised fish tissues were also analysed; however, the additional procedure had no advantage over the direct analysis of the fresh fish, and additionally increased the total analytical process time. A fish tissue reference material, IAEA-407, was analysed and the mercury concentration was in agreement with the certified value, according to the t-test at a 95% confidence level. The limit of quantification (LOQ), based on a mercury-free sample, was 3.0 µg kg(-1). This LOQ is in accordance with performance criteria required by the Commission Regulation No. 333/2007. Simplicity and high efficiency, without the need for any sample preparation procedure, are some of the qualities of the proposed method.

  12. Influence of thermal radiation and heat generation/absorption on MHD heat transfer flow of a micropolar fluid past a wedge considering hall and ion slip currents

    Directory of Open Access Journals (Sweden)

    Uddin Ziya

    2014-01-01

    Full Text Available In this paper a numerical model is developed to examine the effect of thermal radiation on magnetohydrodynamic heat transfer flow of a micropolar fluid past a non-conducting wedge in presence of heat source/sink. In the model it is assumed that the fluid is viscous, incompressible and electrically conducting. The Hall and ion slip effects have also been taken into consideration. The model contains highly non-linear coupled partial differential equations which have been converted into ordinary differential equation by using the similarity transformations. These equations are then solved numerically by Shooting technique along with the Runge-Kutta-Fehlberg integration scheme for entire range of parameters with appropriate boundary conditions. The effects of various parameters involved in the problem have been studied with the help of graphs. Numerical values of skin friction coefficients and Nusselt number are presented in tabular form. The results showed that the micropolar fluids are better to reduce local skin drag as compared to Newtonian fluids and the presence of heat sink increases the heat transfer rate.

  13. Determination of the neutron resonance parameters for 206Pb and of the thermal neutron capture cross section for 206Pb and 209Bi

    International Nuclear Information System (INIS)

    Borella, A.

    2005-01-01

    response of the C6D6 detector. The analysis of the capture data allows the determination of the capture area of the resonances. In Chapter 4 we determine the thermal capture cross section for 206 Pb(n, γ) and 209 Bi(n, γ) from measurements at the cold neutron beam of the Budapest Neutron Centre. The thermal cross sections for neutron capture to the ground state 210g Bi(n, γ) and to the isomeric state 210m Bi(n, γ) have also been measured. These values complement the resonance parameters and produce a consistent description of the total and capture cross section at thermal energy and in the resolved resonance region. Chapter 5 contains the discussion of the results of this work. The statistical properties of the 206 Pb resonance parameters are described. The consistency of the resonance parameters and the thermal neutron capture cross section for 206 Pb and 209 Bi is discussed. The resulting MAC for 206 Pb is given and the impact on the termination of the s-process is described. Finally, general conclusions are presented

  14. Thermal conductivity studies of a polyurea cross-linked silica aerogel-RTV 655 compound for cryogenic propellant tank applications in space

    Science.gov (United States)

    Sabri, F.; Marchetta, J.; Smith, K. M.

    2013-10-01

    Silica-based aerogel is an ideal thermal insulator with a makeup of up to 99% air associated with the highly porous nature of this material. Polyurea cross-linked silica aerogel (PCSA) has superior mechanical properties compared to the native aerogels yet retains the highly porous open pore network and functions as an ideal thermal insulator with added load-bearing capability necessary for some applications. Room temperature vulcanizing rubber-RTV 655—is a space qualified elastomeric thermal insulator and encapsulant with high radiation and temperature tolerance as well as chemical resistance. Storage and transport of cryogenic propellant liquids is an integral part of the success of future space exploratory missions and is an area under constant development. Limitations and shortcomings of current cryogenic tank materials and insulation techniques such as non-uniform insulation layers, self-pressurization, weight and durability issues of the materials used, has motivated the quest for alternative materials. Both RTV 655 and PCSA are promising space qualified materials with unique and tunable microscopic and macroscopic properties making them attractive candidates for this study. In this work, the effect of PCSA geometry and volume concentration on the thermal behavior of RTV 655—PCSA compound material has been investigated at room temperature and at a cryogenic temperature. Macroscopic and microscopic PCSA material was encapsulated at increasing concentrations in an RTV 655 elastomeric matrix. The effect of pulverization on the nanopores of PCSA as a method for creating large quantities of homogeneous PCSA microparticles has also been investigated and is reported. The PCSA volume concentrations ranged between 22% and 75% for both geometries. Thermal conductivity measurements were performed based on the steady state transient plane source method.

  15. Studies of the thermal and mechanical properties of poly(urethane-siloxane)s cross-linked by hyperbranched polyesters

    Czech Academy of Sciences Publication Activity Database

    Džunuzović, J. V.; Pergal, M. V.; Poreba, Rafal; Ostojić, S.; Lazić, N.; Špírková, Milena; Jovanović, S.

    2012-01-01

    Roč. 51, č. 33 (2012), s. 10824-10832 ISSN 0888-5885 R&D Projects: GA ČR GAP108/10/0195 Institutional research plan: CEZ:AV0Z40500505 Institutional support: RVO:61389013 Keywords : poly urethane * mechanical properties * thermal properties Subject RIV: CD - Macromolecular Chemistry Impact factor: 2.206, year: 2012

  16. Thermal and rotational effect on giant dipole resonances in rotating nuclei at high temperature

    International Nuclear Information System (INIS)

    Sugawara-Tanabe, Kazuko; Tanabe, Kosai.

    1986-01-01

    Microscopic calculations are carried out for the giant dipole resonances excited on the thermal high spin states in 162 Er and 166 Er based on the thermal linear response theory with realistic forces and large single-particle space. The dynamical strength function is compared with the experimental γ-ray absorption cross section. The general trend that the resonance energy decreases and the resonance width increases with increasing angular momentum and temperature is well reproduced by the calculations. (author)

  17. Burn-up physics in a coupled Hammer-Technion/Cinder-2 system and ENDF/B-V aggregate fission product thermal cross section validation

    International Nuclear Information System (INIS)

    Santos, A. dos.

    1990-01-01

    The new methodology developed in this work has the following purposes: a) to implement a burnup capability into the HAMMER-TECHNION/9/computer code by using the CINDER-2/10/computer code to perform the transmutation analysis for the actinides and fission products; b) to implement a reduced version of the CINDER-2 fission product chain structure to treat explicity nearly 99% of all original CINDER-2 fission product absorption in a typical PWR unit cell; c) to treat the effect of the fission product neutron absorption in an unit cell in a multigroup basis; d) to develop a tentative validation procedure for the ENOF/C-V stable and long-lived fission product nuclear data based on the available experimental data/11-14/. The analysis will be performed by using the reduce chain in the coupled system CINDER-2 to generate the time dependent effective four group cross sections for actinides and fission products and CINDER-2 to perform the complete transmutation analysis with its built-in chain structure. (author)

  18. Neutron method and apparatus for determining total cross-section

    International Nuclear Information System (INIS)

    Flaum, C.

    1984-01-01

    This invention relates to the determination of the macroscopic neutron absorption cross section of the geological formation surrounding a borehole. The method comprises passing a logging sonde through the borehole while continuously irradiating the formation with neutrons. The radiation emanating from the formation is monitored to generate a first signal indicative of thermal neutrons and a second signal indicative of epithermal neutrons. Output signals are generated indicative of the spatial distribution of thermal and epithermal neutrons, and are combined to generate a signal representative of the macroscopic neutron absorption cross section of the formation. The apparatus comprises a logging sonde adapted for movement through the borehole and carrying a neutron source; detector means on the sonde for monitoring radiation emanating from the formation to generate signals indicative of thermal and epithermal neutrons; means for generating output signals indicative of the spatial distribution of thermal and epithermal neutrons; and means for combining the two output signals to generate a signal indicative of the macroscopic neutron absorption cross section of the material

  19. Influence of thermal post-curing on the degradation of a cross-linked polybenzimidazole-based membrane for high temperature polymer electrolyte membrane fuel cells

    Science.gov (United States)

    Ossiander, T.; Perchthaler, M.; Heinzl, C.; Scheu, C.

    2014-12-01

    The lifetime stability of membranes is one of the main requirements regarding reliability of high temperature polymer electrolyte membrane fuel cells. The present work has improved durability under cycled operation by thermal post-curing of cross-linked polybenzimidazole (PBI)-based membranes. The membranes were dried over 1, 2 and 3 h at 250 °C under air. Ex-situ experiments proved an increase in stability by post-curing. The liquid uptake and swelling in phosphoric acid increased with longer curing periods. The effect of thermal treatments on cycle stability, lifetime and begin-of-life performance of the membrane electrode assemblies (MEAs) was investigated. Longer post-curing periods of the membranes had no influence on the MEAs' begin-of-life performance and constant current behavior over 2300 h. However, the 3 h post-cured MEAs showed enhanced cycle stability. Post-mortem analysis was carried out to identify the occurring degradation mechanisms. While a significant loss of phosphoric acid and a reduction of electrochemical surface activity on the cathode were observed for both post-cured MEAs, the 3 h dried membrane sample had a significantly higher resistance against pinhole formation during the long term test. Altogether, this work presents thermal post-curing as a promising method for the reduction of degradation determining effects in fuel cell membranes.

  20. $J/\\psi$ Absorption in Heavy Ion Collisions

    CERN Document Server

    Maiani, Luciano; Polosa, Antonio; Riquer, V

    2004-01-01

    We present a new calculation of the pi-J/psi dissociation cross sections within the Constituent Quark-Meson Model recently introduced. To discuss the absorption of J/psi in heavy-ion collisions, we assume the J/psi to be produced inside a thermalized pion gas, as discussed by Bjorken, and introduce the corrections due to absorption by nuclear matter as well. We fit the absorption length of the J/psi to the data obtained at the CERN SPS by the NA50 Collaboration for Pb-Pb collisions. Collisions of lower centrality allow us to determine the temperature and the energy density of the pion gas. For both these quantities we find values close to those indicated by lattice gauge calculations for the transition to a quark-gluon plasma. A simple extrapolation to more central collisions, which takes into account the increase of the energy deposited due to the increased nucleon flux, fails to reproduce the break in J/psi absorption indicated by NA50, thus lending support to the idea that an unconfined quark-gluon phase m...

  1. Ultrasonic absorption in solid specimens

    International Nuclear Information System (INIS)

    Siwabessy, P.J. W.; Stewart, G.A.

    1996-01-01

    As part of a project to measure the absorption of high frequency (50 - 500 kHz) sonar signals in warm sea-water, a laboratory apparatus has been constructed and tested against room temperature distilled water and various solutions of MgSO 4 (chemical relaxation of MgSO 4 is the major contribution to absorption below 200 kHz). The technique involves monitoring the decay of an acoustic signal for different sizes of vessels of water suspended in an evacuated chamber. So far, all containing vessels used have been spherical in shape. Extrapolation of the results to infinite volume yields the absorption due to the water alone. In order to accommodate variations in temperature and pressure, and to make the system more robust (e.g. for ship deck usage), it is desirable to employ stainless steel vessels. However, it was found that the quality of the data was greatly improved when pyrex glass spheres were used. The stainless steel spheres were manufactured by welding together mechanically spun hemispheres. The linear frequency dependence characteristic of acoustic absorption in solids was observed (in contrast to the quadratic frequency dependence of acoustic absorption in water), and the acoustic absorption was found to depend strongly on the thermal history of the steel

  2. A frame work for heat generation/absorption and modified homogeneous–heterogeneous reaction in flow based on non-Darcy–Forchheimer medium

    Directory of Open Access Journals (Sweden)

    Tasawar Hayat

    2018-04-01

    Full Text Available The present work aims to report the consequences of Darcy–Forchheimer medium in flow of Cross fluid model toward a stretched surface. Flow in porous space is categorized by Darcy–Forchheimer medium. Further heat transfer characteristics are examined via thermal radiation and heat generation/absorption. Transformation procedure is used. The arising system of nonlinear ordinary differential equations is solved numerically by means of shooting method. The effects of different flow variables on velocity, temperature, concentration, skin friction, and heat transfer rate are discussed. The obtained outcomes show that velocity was enhanced with the increase in the Weissenberg number but decays with increase in the porosity parameter and Hartman number. Temperature field is boosted by thermal radiation and heat generation; however, it decays with the increase in the Prandtl number. Keywords: Cross Fluid, Heat Generation/Absorption, Homogeneous–Heterogeneous Reactions, Non-Darcy–Forchheimer Medium, Thermal Radiation

  3. Organic-inorganic hybrid gels for the selective absorption of oils from water.

    Science.gov (United States)

    Ozan Aydin, Gulsah; Bulbul Sonmez, Hayal

    2016-06-01

    Organic-inorganic hybrid gels were synthesized by the condensation of a linear aliphatic diol (1,8-octanediol) and altering the chain length of the alkyltriethoxysilanes (from ethyltriethoxysilane to hexadecyltrimethoxysilane) through a bulk polymerization process without using any initiator, activator, catalyst, or solvent for the selective removal of oils from water. Fourier transform infrared spectroscopy (FTIR) and solid-state (13)C and (29)Si cross-polarization magic-angle spinning nuclear magnetic resonance (CPMAS NMR) were used for the structural analysis of hybrid gels. Thermal properties of the hybrid gels were determined by thermogravimetric analysis (TGA). Oil absorbency of organic-inorganic hybrid gels was determined by oil absorption tests. The results showed that hybrid gels have high and fast absorption capacities and excellent reusability. Good selectivity, high thermal stability, low density, and excellent recyclability for the oil removal give the material potential applications.

  4. Investigations into solar powered diffusion-absorption cooling machines

    OpenAIRE

    Jakob, Uli

    2005-01-01

    Solar thermal driven or assisted absorption cooling machines are gaining increasing importance due to the continually growing demand for airconditioning in domestic housing as well as office and hotel buildings. Presently there are no thermally driven absorption cooling machines available on the market that can provide a smaller cooling capacity than 10kW for cooling buildings. For this reason, two single-effect solar heated ammonia/water (NHJlH20) Diffusion-Absorption Co...

  5. Edible films developed from carboxylic acid cross-linked sesame protein isolate: barrier, mechanical, thermal, crystalline and morphological properties.

    Science.gov (United States)

    Sharma, Loveleen; Sharma, Harish Kumar; Saini, Charanjiv Singh

    2018-02-01

    Films were developed from sesame protein crosslinked with three different carboxylic acids (malic acid, citric acid and succinic acid) at 1, 3 and 5% (w/w, on protein isolate basis). The effect of crosslinking on physical, mechanical, thermal and morphological properties was studied. Succinic acid crosslinked films exhibited least water vapor permeability the highest tensile strength and overall showed superlative properties among other films. X-ray diffraction showed single main crystalline reflection at 20° indicating amorphous structure of films. DSC curves of films indicated single melting peak in the range of 103-161 °C. All films exhibited weight loss in three stages. FTIR exhibited peak at 1700 cm -1 confirming crosslinking reaction between carboxylic acids and protein. Crosslinked films were compact, nonporous and smooth as compared to film from native sesame protein isolate.

  6. Constraining galaxy cluster velocity field with the thermal Sunyaev-Zel'dovich and kinematic Sunyaev-Zel'dovich cross-bispectrum

    Science.gov (United States)

    Hurier, G.

    2017-08-01

    The Sunyaev-Zel'dovich (SZ) effects are produced by the interaction of cosmic microwave background (CMB) photons with the ionized and diffuse gas of electrons inside galaxy clusters integrated along the line of sight. The two main effects are the thermal SZ (tSZ) produced by thermal pressure inside galaxy clusters and the kinematic SZ (kSZ) produced by peculiar motion of galaxy clusters compared to CMB rest-frame. The kSZ effect is particularly challenging to measure as it follows the same spectral behavior as the CMB, and consequently cannot be separated from the CMB using spectral considerations. In this paper, we explore the feasibility of detecting the kSZ through the computation of the tSZ-CMB-CMB cross-correlation bispectrum for current and future CMB experiments. We conclude that the next generation of CMB experiments will offer the possibility to detect the tSZ-kSZ-kSZ bispectrum at high signal-to-noise ration (S/N). This measurement will constraints the intra-cluster dynamics and the velocity field of galaxy cluster that is extremely sensitive to the growth rate of structures and thus to dark energy properties. Additionally, we also demonstrate that the tSZ-kSZ-kSZ bispectrum can be used to break the degeneracies between the mass-observable relation and the cosmological parameters to set tight constraints, up to 4%, on the Y - M relation calibration.

  7. MS-Xα calculation of the elastic electron scattering cross sections and x-ray absorption spectra of CX4 and SiX4 (X = H,F,Cl)

    International Nuclear Information System (INIS)

    Tossell, J.A.; Davenport, J.W.

    1984-01-01

    Multiple scattering Xα bound state and continuum calculations are used to study low energy elastic electron scattering cross sections and pre-edge features in the x-ray absorption spectra (XAS) of (C,Si)X 4 , X = H,F,Cl. Maxima in the electron scattering cross section are predicted to occur at energies below 4 eV in the t 2 channel for CF 4 , CCl 4 , SiH 4 , and SiCl 4 . These maxima can be assigned to final state orbitals which are bound in XAS and well localized in space and a quantitative correspondence of such scattering ''resonance'' energies and XAS energies may be obtained using the transition state approach. For CH 4 and SiF 4 even those bound state orbitals giving the greatest XAS intensity are very diffuse, being essentially of Rydberg character. Broad electron scattering maxima are found at energies above 4 eV in these molecules which cannot be directly associated with the bound state orbitals dominating the XAS. The results thus establish that low energy electron scattering resonances and pre-edge XAS are closely related only for orbitals bound and reasonably well localized in XAS. The MS-Xα results almost always reproduce experimental trends along the molecular series but quantitative discrepancies from experiment are sometimes substantial, particularly for the broad high energy scattering maxima in CH 4 . The narrow t 2 resonance calculated for CF 4 is found to vary greatly in position and intensity as the C--F distance is varied by small amounts but the stronger, broader t 2 resonance in SiH 4 is little affected by bond distance variation

  8. Water flow experiment using the PIV technique and the thermal hydraulic analysis on the cross-flow type mercury target model with the blade flow distributors

    International Nuclear Information System (INIS)

    Haga, Katsuhiro; Terada, Atsuhiko; Kaminaga, Masanori; Hino, Ryutaro

    2000-01-01

    The flow patterns in the mock-up model of the cross-flow type mercury target were measured using the PIV (particle image velocimetry) technique under water flow conditions at room temperature. The experimental results were compared with the analytical results conducted with the thermal hydraulic analysis code, STAR-CD. As a result, it was confirmed experimentally that the cross-flow could be realized in most of the proton beam path area, where the removal of the high density heat is important, with the proper flow rate distribution along the proton beam path. The analytical result showed the good correspondence to the experimental result. Then the mercury flow field and the temperature distribution were analyzed taking the volumetric heat generation by the spallation reaction into consideration. The volumetric heat generation calculated for the proton beam energy and power of 1.5 GeV and 5 MW were assumed in the analysis. The mercury flow analysis showed that the maximum mercury temperature less than the design criteria of 300degC can be attained with the inlet mercury velocity of more than 1.1 m/s and that the recirculation flow seen in the rear of the proton beam path is considered to cause no excessive temperature rise. (author)

  9. 26Al(n,p)26Mg and 26Al(n,α)23Na cross sections from thermal energy to approximately 50 keV

    International Nuclear Information System (INIS)

    Koehler, P.E.; Gledenov, Yu.M.; Popov, Yu.P.

    1993-01-01

    Understanding the origin of 26 Al is important because it is one of the very few radioactive products of stellar nucleosynthesis to be observed directly by γ-ray telescopes. 26 Al has also been observed indirectly as a 26 Mg anomaly in some meterorites. The 26 Al(n,p) 26 Mg and 26 Al(n,α) 23 Na reactions are thought to be the major means for the destruction of 26 Al in some astrophysical environments, so a knowledge of the cross sections for these reactions is important for a better understanding of the origin of 26 Al. The authors have measured the 26 Al(n,p 1 ) 26 Mg and 26 Al(n,α 0 ) 23 Na cross sections from thermal energy to approximately 50 keV. Most of this energy range has not been explored by previous measurements. The measurements were made at the white neutron source of the Manuel Lujan, Jr. Neutron Scattering Center (LANSCE) using a ΔE-E solid-state detector telescope. Several resonances were observed. This data will be compared to previous measurements and the effect of the new data on the calculated nucleosynthesis of 26 Al will be discussed

  10. Thermal-hydraulic design of cross-flow type mercury target for JAERI/KEK joint project

    International Nuclear Information System (INIS)

    Kaminaga, Masanori; Terada, Atsuhiko; Haga, Katsuhiro; Kinoshita, Hidetaka; Hino, Ryutaro

    2001-01-01

    The Japan Atomic Energy Research Institute (JAERI) and the High Energy Accelerator Research Organization (KEK) are promoting a plan to construct a neutron scattering facility. In the facility, 1 MW pulsed proton beam from a high-intensity proton accelerator will be injected into a mercury target in order to produce high-intensity neutrons for use in the fields of life and material sciences. In the spallation mercury target system design, an integrated structure of target vessel with a safety hull was proposed to ensure the safety and to collect mercury in case of mercury leakage caused by the target beam window failure. The inner structure arrangement of the mercury target vessel was determined based on the thermal hydraulic analytical results of 3 GeV, 1 MW proton beam injection. The safety hull consists of vessels for helium and heavy water. The vessels for mercury target, helium and heavy water will be connected each other by reinforcement ribs mounted on the surface of each vessel. From the structural analyses, the structural integrity of the safety hull would be maintained under the static pressure of 0.5 MPa. (author)

  11. Field Measurements of Water Continuum and Water Dimer Absorption by Active Long Path Differential Optical Absorption Spectroscopy (DOAS)

    OpenAIRE

    Lotter, Andreas

    2006-01-01

    Water vapor plays an important role in Earth's radiative budget since water molecules strongly absorb the incoming solar shortwave and the outgoing thermal infrared radiation. Superimposed on the water monomer absorption, a water continuum absorption has long been recognized, but its true nature still remains controversial. On the one hand, this absorption is explained by a deformation of the line shape of the water monomer absorption lines as a consequence of a molecular collision. One the o...

  12. Nonlinear Optical Absorption and Refraction Study of Metallophthalocyanine Dyes.

    Science.gov (United States)

    Wei, Tai-Huei

    Metallophthalocyanines and related conjugated ring molecules have attracted recent interest because, as confined, reduced-dimensionality (2D) delocalized electronic systems, large electronic nonlinearities are expected. This has led to interest in: (1) developing a fundamental understanding of the mechanisms which contribute to the nonlinear optical response, (2) obtaining well defined and accurate measurements of the refractive and absorptive contributions to the observed nonlinearities, and (3) identifying means of enhancing and maximizing the nonlinear susceptibilities. This dissertation deals with the characterization of the nonlinear absorption and refraction of two representative metallophthalocyanine dyes: chloro aluminum phthalocyanine dissolved in methanol, referred to as CAP, and a silicon naphthalocyanine derivative dissolved in toluene, referred to as SiNc. Using the Z -scan technique, the experiments are performed on both the picosecond and nanosecond timescales at a wavelength of 0.532 mum. The Z-scan technique separates nonlinear absorption and nonlinear refraction by measuring both the total transmittance and far field axial transmittance of a focused Gaussian beam as a function of the position (z) of the material relative to the beam waist. In the picosecond regime, Z-scan experiments using pulses of different widths indicate that both nonlinear absorption and refraction are fluence dependent. Therefore, we determine the dominant nonlinearities are excited state absorption (ESA) and excited state refraction (ESR). Through nanosecond Z-scan measurements, we see additional nonlinear absorption and nonlinear refraction. By power limiting measurements using single picosecond pulses and trains of picosecond pulses separated by 7 nanosecond, this additional nonlinear absorption is determined due to intersystem crossing to the triplet state with subsequent triplet state ESA. Therefore, a five state model is used to explain the nonlinear absorption. On the

  13. Analysis of simultaneous thermal/gamma radiation aging of cross-linked polyethylene (XLPE) insulation—interim status report

    Energy Technology Data Exchange (ETDEWEB)

    Fifield, Leonard S. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Correa, Miguel [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2017-06-16

    Cross-linked polyethylene (XLPE) is the most common cable insulation found in nuclear containment, and is therefore a priority material for investigation of long term aging effect from elevated temperature combined with gamma radiation exposure. Prior work has identified the possibility of anomalous aging behavior in XLPE such as the inverse temperature effect in which radiation exposure is more damaging at lower temperatures than at higher temperatures. We explored simultaneous aging of XLPE insulation from modern Firewall® III nuclear cables at 60, 90, and 115 °C, at gamma dose rates from 116 to 540 Gy/h, for exposure periods up to 25 d. XLPE samples exposed in this way were characterized using the percent gel and uptake factor method. For the conditions and material examine, degradation behavior was seen to track proportionally with increasing temperature, rather than to exhibit greater degradation at lower temperatures. Ongoing work including similar aging at 25 °C and characterization of the XLPE samples using other methods will further elucidate these initial results

  14. Precision atomic beam density characterization by diode laser absorption spectroscopy

    International Nuclear Information System (INIS)

    Oxley, Paul; Wihbey, Joseph

    2016-01-01

    We provide experimental and theoretical details of a simple technique to determine absolute line-of-sight integrated atomic beam densities based on resonant laser absorption. In our experiments, a thermal lithium beam is chopped on and off while the frequency of a laser crossing the beam at right angles is scanned slowly across the resonance transition. A lock-in amplifier detects the laser absorption signal at the chop frequency from which the atomic density is determined. The accuracy of our experimental method is confirmed using the related technique of wavelength modulation spectroscopy. For beams which absorb of order 1% of the incident laser light, our measurements allow the beam density to be determined to an accuracy better than 5% and with a precision of 3% on a time scale of order 1 s. Fractional absorptions of order 10 −5 are detectable on a one-minute time scale when we employ a double laser beam technique which limits laser intensity noise. For a lithium beam with a thickness of 9 mm, we have measured atomic densities as low as 5 × 10 4 atoms cm −3 . The simplicity of our technique and the details we provide should allow our method to be easily implemented in most atomic or molecular beam apparatuses.

  15. Precision atomic beam density characterization by diode laser absorption spectroscopy.

    Science.gov (United States)

    Oxley, Paul; Wihbey, Joseph

    2016-09-01

    We provide experimental and theoretical details of a simple technique to determine absolute line-of-sight integrated atomic beam densities based on resonant laser absorption. In our experiments, a thermal lithium beam is chopped on and off while the frequency of a laser crossing the beam at right angles is scanned slowly across the resonance transition. A lock-in amplifier detects the laser absorption signal at the chop frequency from which the atomic density is determined. The accuracy of our experimental method is confirmed using the related technique of wavelength modulation spectroscopy. For beams which absorb of order 1% of the incident laser light, our measurements allow the beam density to be determined to an accuracy better than 5% and with a precision of 3% on a time scale of order 1 s. Fractional absorptions of order 10 -5 are detectable on a one-minute time scale when we employ a double laser beam technique which limits laser intensity noise. For a lithium beam with a thickness of 9 mm, we have measured atomic densities as low as 5 × 10 4 atoms cm -3 . The simplicity of our technique and the details we provide should allow our method to be easily implemented in most atomic or molecular beam apparatuses.

  16. Optical absorption in irradiated natural beryl

    International Nuclear Information System (INIS)

    Isotani, S.; Dias, O.L.; Albuquerque, A.R.P.L.

    1983-10-01

    Three species of beryl irradiated with γ-rays of 60 Co were studied by optical absorption. One became yellow and the other two Maxixe's blue. The effects of heat treatments were determined by the thermal isochronal decays of the optical absorption bands. Activation energies and frequency factor were obtained through the first order process kinetic model. Discussions lend us to assign for the UV band-edge the model of absorption by a hole center stabilized by a Fe 2+ (substituting Al 3+ ) ion in a neighbour oxygen. (Author) [pt

  17. Evolution of absorption machines; Evolution des machines a absorption

    Energy Technology Data Exchange (ETDEWEB)

    Soide, I.; Klemsdal, E. [Gaz de France (GDF), 75 - Paris (France); Le Goff, P.; Hornut, J.M. [LSGC-ENSIC, 54 - Nancy (France)

    1997-12-31

    Most of todays absorption air-conditioning machineries use the lithium bromide-water pair. The most performing can operate at a 150-160 deg. C, the temperature being limited by the corrosion resistance of metals with respect to LiBr solutions. Also, there is a revival of interest for water-ammonia systems. These systems require the use of a rectification column which reduces the coefficient of performance. Higher thermal performances are reached with hydrocarbon pairs and ternary mixtures (water-methanol-LiBr etc..). This paper presents different schemes of refrigerating heat pumps based on these different systems. (J.S.)

  18. Continuum and discrete pulsed cavity ring down laser absorption spectra of Br2 vapor.

    Science.gov (United States)

    Sharma, Ramesh C; Huang, Hong-Yi; Chuang, Wang-Ting; Lin, King-Chuen

    2005-07-01

    The absorption cross-sections at room temperature are reported for the first time, of Br2 vapor in overlapping bound-free and bound-bound transition of A(3)pi1u Br2. We obtained discrete absorption cross-section in the rotational structure, the continuum absorption cross-sections, and were also able to measure the absorption cross-section in separate contribution of A(3)pi1u Br2. The absorption cross-sections are increasing with increasing excitation energy in the wavelength region 510-535 nm.

  19. Single-photon absorption by single photosynthetic light-harvesting complexes

    Science.gov (United States)

    Chan, Herman C. H.; Gamel, Omar E.; Fleming, Graham R.; Whaley, K. Birgitta

    2018-03-01

    We provide a unified theoretical approach to the quantum dynamics of absorption of single photons and subsequent excitonic energy transfer in photosynthetic light-harvesting complexes. Our analysis combines a continuous mode -photon quantum optical master equation for the chromophoric system with the hierarchy of equations of motion describing excitonic dynamics in presence of non-Markovian coupling to vibrations of the chromophores and surrounding protein. We apply the approach to simulation of absorption of single-photon coherent states by pigment–protein complexes containing between one and seven chromophores, and compare with results obtained by excitation using a thermal radiation field. We show that the values of excitation probability obtained under single-photon absorption conditions can be consistently related to bulk absorption cross-sections. Analysis of the timescale and efficiency of single-photon absorption by light-harvesting systems within this full quantum description of pigment–protein dynamics coupled to a quantum radiation field reveals a non-trivial dependence of the excitation probability and the excited state dynamics induced by exciton–phonon coupling during and subsequent to the pulse, on the bandwidth of the incident photon pulse. For bandwidths equal to the spectral bandwidth of Chlorophyll a, our results yield an estimation of an average time of ∼0.09 s for a single chlorophyll chromophore to absorb the energy equivalent of one (single-polarization) photon under irradiation by single-photon states at the intensity of sunlight.

  20. Thermal expansion absorbing structure for pipeline

    International Nuclear Information System (INIS)

    Nagata, Takashi; Yamashita, Takuya.

    1995-01-01

    A thermal expansion absorbing structure for a pipeline is disposed to the end of pipelines to form a U-shaped cross section connecting a semi-circular torus shell and a short double-walled cylindrical tube. The U-shaped longitudinal cross-section is deformed in accordance with the shrinking deformation of the pipeline and absorbs thermal expansion. Namely, since the central lines of the outer and inner tubes of the double-walled cylindrical tube deform so as to incline, when the pipeline is deformed by thermal expansion, thermal expansion can be absorbed by a simple configuration thereby enabling to contribute to ensure the safety. Then, the entire length of the pipeline can greatly be shortened by applying it to the pipeline disposed in a high temperature state compared with a method of laying around a pipeline using only elbows, which has been conducted so far. Especially, when it is applied to a pipeline for an FBR-type reactor, the cost for the construction of a facility of a primary systems can greater be reduced. In addition, it can be applied to a pipeline for usual chemical plants and any other structures requiring absorption of deformation. (N.H.)

  1. Nutrition and magnesium absorption

    OpenAIRE

    Brink, E.J.

    1992-01-01

    The influence of various nutrients present in dairy products and soybean-based products on absorption of magnesium has been investigated. The studies demonstrate that soybean protein versus casein lowers apparent magnesium absorption in rats through its phytate component. However, true magnesium absorption was neither affected by soybean protein in the diet nor by supplemental phytate. The inhibitory influence of soybean protein and phytate on apparent magnesium absorption was found ...

  2. Phytases for Improved Iron Absorption

    DEFF Research Database (Denmark)

    Nielsen, Anne Veller Friis; Nyffenegger, Christian; Meyer, Anne S.

    2014-01-01

    Microbial phytases (EC 3.1.3.8) catalyse dephosphorylation of phytic acid, which is the primary storage compound for phosphorous in cereal kernels. The negatively charged phosphates in phytic acid chelate iron (Fe3+) and thus retards iron bioavailability in humans 1. Supplementation of microbial...... phytase can improve iron absorption from cereal-based diets 2. In order for phytase to catalyse iron release in vivo the phytase must be robust to low pH and proteolysis in the gastric ventricle. Our work has compared the robustness of five different microbial phytases, evaluating thermal stability...

  3. Absorption and excretion tests

    International Nuclear Information System (INIS)

    Berberich, R.

    1988-01-01

    The absorption and excretion of radiopharmaceuticals is still of interest in diagnostic investigations of nuclear medicine. In this paper the most common methods of measuring absorption and excretion are described. The performance of the different tests and their standard values are discussed. More over the basic possibilities of measuring absorption and excretion including the needed measurement equipments are presented. (orig.) [de

  4. Plasma Sprayed Coatings for RF Wave Absorption

    Czech Academy of Sciences Publication Activity Database

    Nanobashvili, S.; Matějíček, Jiří; Žáček, František; Stöckel, Jan; Chráska, Pavel; Brožek, Vlastimil

    307-311, - (2002), s. 1334-1338 ISSN 0022-3115 Grant - others:COST(XE) Euratom DV4/04(TWO) Institutional research plan: CEZ:AV0Z2043910 Keywords : boron carbide, thermal spray coatings, fusion materials, RF wave absorption Subject RIV: JK - Corrosion ; Surface Treatment of Materials Impact factor: 1.730, year: 2002

  5. Chemical cross-linked polyvinyl alcohol/cellulose nanocrystal composite films with high structural stability by spraying Fenton reagent as initiator.

    Science.gov (United States)

    Song, Meili; Yu, Houyong; Gu, Jiping; Ye, Shounuan; Zhou, Yuwei

    2018-02-20

    Cross-linked polyvinyl alcohol (PVA) composite films with high structural stability were prepared by free radical copolymerization between cellulose nanocrystal (CNC) and maleic anhydride (MAH) modified PVA through spraying Fenton free radical as initiator. The influence of chemical cross-linked and physical network structure on mechanical, thermal and water absorption properties of the composite films were investigated. Compared to PVA and PVA/CNC composite film, significant improvements in the mechanical, thermal and water uptake properties of the cross-linked composite film were found. The tensile strength of the cross-linked composite film was enhanced from 23.1MPa (neat PVA film) and 32.6MPa (PVA/CNC-10%) to 42.5MPa, and the maximum thermal degradation temperature was increased from 266.8°C and 281.2°C to 366.7°C (cross-linked composite film). Besides, the water absorption was reduced from 385.9% and 220.6% to 175.7% for cross-linked composite film. It indicates that compared with physical network structure in PVA/CNC composite film, the multiple cross-linked networks showed excellent thermal stability, resistance of water swelling and structural stability at the same CNC loading level. Thus, the PVA/CNC composite film with the multiple cross-linked network shows greater property reinforcements. Copyright © 2018 Elsevier B.V. All rights reserved.

  6. Calcium absorption and achlorhydria

    International Nuclear Information System (INIS)

    Recker, R.R.

    1985-01-01

    Defective absorption of calcium has been thought to exist in patients with achlorhydria. The author compared absorption of calcium in its carbonate form with that in a pH-adjusted citrate form in a group of 11 fasting patients with achlorhydria and in 9 fasting normal subjects. Fractional calcium absorption was measured by a modified double-isotope procedure with 0.25 g of calcium used as the carrier. Mean calcium absorption (+/- S.D.) in the patients with achlorhydria was 0.452 +/- 0.125 for citrate and 0.042 +/- 0.021 for carbonate (P less than 0.0001). Fractional calcium absorption in the normal subjects was 0.243 +/- 0.049 for citrate and 0.225 +/- 0.108 for carbonate (not significant). Absorption of calcium from carbonate in patients with achlorhydria was significantly lower than in the normal subjects and was lower than absorption from citrate in either group; absorption from citrate in those with achlorhydria was significantly higher than in the normal subjects, as well as higher than absorption from carbonate in either group. Administration of calcium carbonate as part of a normal breakfast resulted in completely normal absorption in the achlorhydric subjects. These results indicate that calcium absorption from carbonate is impaired in achlorhydria under fasting conditions. Since achlorhydria is common in older persons, calcium carbonate may not be the ideal dietary supplement

  7. Thermal neutron diffusion cooling coefficient for plexiglass

    International Nuclear Information System (INIS)

    Drozdowicz, K.

    1992-08-01

    The thermal neutron diffusion cooling coefficient is a macroscopic material parameter. It is needed for description of the decay of the thermal neutron pulse in a medium and gives information of the diffusion cooling of the thermal neutron spectrum in a bounded volume. Experimental results from various measurements for plexiglass are overviewed in the paper. A method for theoretical, exact calculation of the parameter is presented. The formula utilizes some other thermal neutron parameters and a cooling function, i.e. the function which describes the deviation of the neutron spectrum in a bounded system from the distribution in an infinite one. The energy dependence of the function is obtained numerically from relations which results from the eigenvalue problem of the scattering operator when both the decay constant and the spectrum of the thermal neutron flux are developed on powers of the geometrical buckling. The case of a 1/ν absorption cross section is considered. The calculation utilizes a synthetic scattering function elaborated for hydrogenous media by GRANADA (1985). The influence of some quantities used in the calculation on the final result is investigated. The obtained value of the diffusion cooling coefficient for plexiglass is C = 6514 cm 4 s -1 at the temperature of 20 degrees C. The uncertainty is estimated to be ± 100 cm 4 s -1 within the physical model of the scattering kernel used. (au)

  8. Up-Conversion Intersystem Crossing Rates in Organic Emitters for Thermally Activated Delayed Fluorescence: Impact of the Nature of Singlet vs Triplet Excited States

    KAUST Repository

    Samanta, Pralok Kumar

    2017-02-28

    The rates for up-conversion intersystem crossing (UISC) from the T1 state to the S1 state are calculated for a series of organic emitters with an emphasis on thermally activated delayed fluorescence (TADF) materials. Both the spin-orbit coupling and the energy difference between the S1 and T1 states (ΔEST) are evaluated, at the density functional theory (DFT) and time-dependent DFT levels. The calculated UISC rates and ΔEST values are found to be in good agreement with available experimental data. Our results underline that small ΔEST values and sizable spin-orbit coupling matrix elements have to be simultaneously realized in order to facilitate UISC and ultimately TADF. Importantly, the spatial separation of the highest occupied and lowest unoccupied molecular orbitals of the emitter, a widely accepted strategy for the design of TADF molecules, does not necessarily lead to a sufficient reduction in ΔEST; in fact, either a significant charge-transfer (CT) contribution to the T1 state or a minimal energy difference between the local-excitation and charge-transfer triplet states is required to achieve a small ΔEST. Also, having S1 and T1 states of a different nature is found to strongly enhance spin-orbit coupling, which is consistent with the El-Sayed rule for ISC rates. Overall, our results indicate that having either similar energies for the local-excitation and charge-transfer triplet states or the right balance between a substantial CT contribution to T1 and somewhat different natures of the S1 and T1 states, paves the way toward UISC enhancement and thus TADF efficiency improvement.

  9. Performance Analysis of Solution Transportation Absorption Chiller

    Science.gov (United States)

    Kiani, Behdad; Hamamoto, Yoshinori; Akisawa, Atsushi; Kashiwagi, Takao

    Thermally activated advanced absorption cycles are considered promising candidates to replace CFCs, HCFCs and HFCs for residential and commercial applications. In such absorption systems, it is desirable to utilize the waste heat from industries for heating and cooling applications in commercial and residential sectors. For this purpose, it is necessary to transport energy over some distance because the waste heat source and demand are generally located apart from each other. Transportation of steam, hot water or chilled water requires high construction costs for insulation. There is an efficient method of energy transportation using absorption system called “ Solution Transportation Absorption System (STA)”. The solution is transported at an ambient temperature so that tube-insulations not required. This paper shows the simulation of the abovementioned system and the optimal result, using mathematical optimization. The optimum system with industry‧s waste heat utilization is obtained. At the end, the effect on the pollution emission and energy conservation is obtained.

  10. Thermal neutron spectra measurements in IEAR-1 Reactor, by using a crystal spectrometer

    International Nuclear Information System (INIS)

    Fulfaro, R.; Figueiredo Neto, A.M.; Stasiulevicius, E.; Vinhas, L.A.

    1975-01-01

    The thermal neutron spectrum of the IEN Argonauta reactor has been measured in the wavelength from 0.7 to 1.9A, using a neutron crystal spectrometer. An aluminium single crystal, in transmission, was used as monochromator. The aluminium crystal reflectivity employed in the analysis of the data was calculated for the first five permitted orders. An effective absorption coefficient of the crystal was used to perform the calculations instead of the macroscopic cross section of the element

  11. [Study on lead absorption in pumpkin by atomic absorption spectrophotometry].

    Science.gov (United States)

    Li, Zhen-Xia; Sun, Yong-Dong; Chen, Bi-Hua; Li, Xin-Zheng

    2008-07-01

    A study was carried out on the characteristic of lead absorption in pumpkin via atomic absorption spectrophotometer. The results showed that lead absorption amount in pumpkin increased with time, but the absorption rate decreased with time; And the lead absorption amount reached the peak in pH 7. Lead and cadmium have similar characteristic of absorption in pumpkin.

  12. Nonlinear absorption, optical limiting behavior and structural study of a new chalcone derivative-1-(3, 4-dimethylphenyl)-3-[4(methylsulfanyl) phenyl] prop-2-en-1-one

    Science.gov (United States)

    Chandra Shekhara Shetty, T.; Raghavendra, S.; Chidan Kumar, C. S.; Dharmaprakash, S. M.

    2016-03-01

    A new third order nonlinear optical (NLO) organic material-1-(3, 4-dimethylphenyl)-3-[4(methylsulfanyl) phenyl] prop-2-en-1-one (4DPMS) belonging to chalcone family has been crystallized in acetone solution. The 4DPMS crystals are characterized by CHNS analysis, FTIR, UV-visible spectral and thermal techniques. The single crystal X-ray diffraction study reveals that 4DPMS crystallizes in monoclinic system with P21/n space group. The linear optical absorption spectrum revealed that the 4DPMS crystals are transparent in the entire visible region. Thermogravimetric data shows absence of phase transition before melting point and from differential scanning calorimetry analysis the melting point of the crystal is found to be 106 °C. Third order nonlinear absorption and optical limiting experiment on 4DPMS was carried out using open aperture Z-scan technique with Nd: YAG laser operating at 532 nm. It was found that the calculated values of excited state absorption cross section for 4DPMS molecules is much greater than the ground state absorption cross section. A decrease in effective nonlinear absorption coefficient was observed with increase in the input irradiance of laser. The observed optical limiting property in 4DPMS is attributed to reverse saturable absorption.

  13. Absorption heat pumps

    International Nuclear Information System (INIS)

    Formigoni, C.

    1998-01-01

    A brief description of the difference between a compression and an absorption heat pump is made, and the reasons why absorption systems have spread lately are given. Studies and projects recently started in the field of absorption heat pumps, as well as criteria usually followed in project development are described. An outline (performance targets, basic components) of a project on a water/air absorption heat pump, running on natural gas or LPG, is given. The project was developed by the Robur Group as an evolution of a water absorption refrigerator operating with a water/ammonia solution, which has been on the market for a long time and recently innovated. Finally, a list of the main energy and cost advantages deriving from the use of absorption heat pumps is made [it

  14. Total cross section measurement of radioactive isotopes with a thin beam neutron spectrometer

    International Nuclear Information System (INIS)

    Razbudej, V.F.; Vertebnyj, V.P.; Padun, G.S.; Muravitskij, A.V.

    1975-01-01

    The method for measuring the neutron total cross sections of radioactive isotopes by a time-of-flight spectrometer with a narrow (0.17 mm in diameter) beam of thermal neutrons is described. The distinguishing feature of this method is the use of capillary samples with a small amount of substance (0.05-1.0 mg). The energy range is 0.01-0.3 eV. The total cross sections of irradiated samples of sub(153)Eu and sub(151)Eu are measured. From them are obtained the cross sections of sub(152)Eu (Tsub(1/2)=12.4 g) and of sub(154)E (Tsub(1/2)=8.6 yr); they equal 11400+-1400 and 1530+-190 barn at E=0.0253 eV. The cross section of the sub(152)Eu absorption for the thermal spectrum (T=333 K) is determined by the activation method; it is 8900+-1200 barn

  15. On pair-absorption in intrinsic vapours

    International Nuclear Information System (INIS)

    Hotop, R.; Niemax, K.; Schlueter, D.

    1982-01-01

    The bound-state pair-absorption bands Cs(6 2 S 1 sub(/) 2 ) + Cs(6 2 S 1 sub(/) 2 ) + hν → Cs(5 2 D 5 sub(/) 2 sub(,) 3 sub(/) 2 ) + Cs(6 2 P 1 sub(/) 2 ) and the K-K continuum-state pair-absorptions in the wavelength region 2.350 <= lambda <= 2.850 Angstroem have been investigated experimentally. In the case of the bound-state pair-absorption bands a theoretical approach for the absorption cross section at the band centre is given which is in good agreement with the experimental observation. Differences between our and the theoretical formulas given by the Stanford group are discussed. (orig.)

  16. Organizational forms and knowledge absorption

    Directory of Open Access Journals (Sweden)

    Radovanović Nikola

    2016-01-01

    Full Text Available Managing the entire portion of knowledge in an organization is a challenging task. At the organizational level, there can be enormous quantities of unknown, poorly valued or inefficiently applied knowledge. This is normally followed with the underdeveloped potential or inability of organizations to absorb knowledge from external sources. Facilitation of the efficient internal flow of knowledge within the established communication network may positively affect organizational capacity to absorb or identify, share and subsequently apply knowledge to commercial ends. Based on the evidences that the adoption of different organizational forms affects knowledge flows within an organization, this research analyzed the relationship between common organizational forms and absorptive capacity of organizations. In this paper, we test the hypothesis stating that the organizational structure affects knowledge absorption and exploitation in the organization. The methodology included quantitative and qualitative research method based on a questionnaire, while the data has been statistically analyzed and the hypothesis has been tested with the use of cross-tabulation and chi-square tests. The findings suggest that the type of organizational form affects knowledge absorption capacity and that having a less formalized and more flexible structure in an organization increases absorbing and exploiting opportunities of potentially valuable knowledge.

  17. Solar absorption surface panel

    Science.gov (United States)

    Santala, Teuvo J.

    1978-01-01

    A composite metal of aluminum and nickel is used to form an economical solar absorption surface for a collector plate wherein an intermetallic compound of the aluminum and nickel provides a surface morphology with high absorptance and relatively low infrared emittance along with good durability.

  18. Nutrition and magnesium absorption

    NARCIS (Netherlands)

    Brink, E.J.

    1992-01-01

    The influence of various nutrients present in dairy products and soybean-based products on absorption of magnesium has been investigated. The studies demonstrate that soybean protein versus casein lowers apparent magnesium absorption in rats through its phytate component. However, true

  19. Zeeman atomic absorption spectroscopy

    International Nuclear Information System (INIS)

    Loos-Vollebregt, M.T.C. de.

    1980-01-01

    A new method of background correction in atomic absorption spectroscopy has recently been introduced, based on the Zeeman splitting of spectral lines in a magnetic field. A theoretical analysis of the background correction capability observed in such instruments is presented. A Zeeman atomic absorption spectrometer utilizing a 50 Hz sine wave modulated magnetic field is described. (Auth.)

  20. Thermal Anemometry Grid Sensor

    OpenAIRE

    Arlit, Martin; Schleicher, Eckhard; Hampel, Uwe

    2017-01-01

    A novel thermal anemometry grid sensor was developed for the simultaneous measurement of cross-sectional temperature and axial velocity distribution in a fluid flow. The sensor consists of a set of platinum resistors arranged in a regular grid. Each platinum resistor allows the simultaneous measurement of fluid temperature via electrical resistance and flow velocity via constant voltage thermal anemometry. Cross-sectional measurement was enabled by applying a special multiplexing-excitation s...

  1. Electronic states of Ne2+, Ar2+, Kr2+, and Xe2+. II. Absorption cross sections for the 1(1/2)/sub u/→1(3/2)/sub g/, 1(1/2)/sub g/, 2(1/2)/sub g/ transitions

    International Nuclear Information System (INIS)

    Wadt, W.R.

    1980-01-01

    The lowest three dipole-allowed absorption bands in Ne 2 + , Ar 2 + , Kr 2 + , and Xe 2 + are investigated using ab initio configuration interaction wave functions. Potential curves (reported in paper I) and transition moments (reported here) are obtained for Ar 2 + , Kr 2 + , and Xe 2 + using the POL CI method. By shifting the R/sub e/ of the 1(1/2)/sub u/ state, the theoretical absorption profiles are normalized to the absolute cross sections of Lee and Smith and also Vanderhoff for the 1(1/2)/sub u/→2(1/2)/sub g/ transition at (350.7 and 356.9) nm and 413.1 nm. The resulting absorption profiles are not only in good agreement with the remaining data of Lee and Smith, Vanderhoff, and Hunter for 1(1/2)/sub u/→2(1/2)/sub g/, but are also in good agreement with the experimental data of Lee et al. on the 1(1/2)/sub u/→1(1/2)/sub g/ transition. The absorption profiles for Ne 2 + are based on the ab initio potential curves and transition moments of Cohen and Schneider. The agreement with the few available cross sections of Lee and Smith is excellent. Comparison with the other theoretical calculations of the transition moments reveals the important effects of configuration interaction not included by Stevens et al. and the inaccuracies of the R/2 approximation employed by Michels. Finally, comparison with temperature-dependent studies of Lee and Smith indicates much faster equilibration between the translational and vibrational degrees of freedom in Ne 2 + than Ar 2 +

  2. Study on Scattering and Absorption Properties of Quantum-Dot-Converted Elements for Light-Emitting Diodes Using Finite-Difference Time-Domain Method.

    Science.gov (United States)

    Li, Jiasheng; Tang, Yong; Li, Zongtao; Ding, Xinrui; Yuan, Dong; Yu, Binhai

    2017-11-03

    CdSe/ZnS quantum-dot-converted elements (QDCEs) are good candidates for substituting rare-earth phosphor-converted elements (PCEs) in white light-emitting diodes (LEDs); however, studies on their scattering and absorption properties are scarce, suppressing further increment in the optical and thermal performance of quantum-dot-converted LEDs. Therefore, we introduce the finite-difference time-domain (FDTD) method to achieve the critical optical parameters of QDCEs when used in white LEDs; their scattering cross-section (coefficient), absorption cross-section (coefficient), and scattering phase distributions are presented and compared with those of traditional YAG phosphor-converted elements (PCEs) at varying particle size and concentration. At a commonly used concentration ( < 50 mg / cm 3 ), QDCEs exhibit stronger absorption (tens of millimeters, even for green-to-red-wavelength light) and weaker scattering ( < 1 mm - 1 ) compared to PCEs; the reabsorption, total internal reflection, angular uniformity, and thermal quenching would be more significant concerns for QDCEs. Therefore, the unique scattering and absorption properties of QDCEs should be considered when used in white LEDs. Furthermore, knowledge of these important optical parameters is helpful for beginning a theoretical study on quantum-dot-converted LEDs according to the ray tracing method.

  3. Treating Fibrous Insulation to Reduce Thermal Conductivity

    Science.gov (United States)

    Zinn, Alfred; Tarkanian, Ryan

    2009-01-01

    A chemical treatment reduces the convective and radiative contributions to the effective thermal conductivity of porous fibrous thermal-insulation tile. The net effect of the treatment is to coat the surfaces of fibers with a mixture of transition-metal oxides (TMOs) without filling the pores. The TMO coats reduce the cross-sectional areas available for convection while absorbing and scattering thermal radiation in the pores, thereby rendering the tile largely opaque to thermal radiation. The treatment involves a sol-gel process: A solution containing a mixture of transition-metal-oxide-precursor salts plus a gelling agent (e.g., tetraethylorthosilicate) is partially cured, then, before it visibly gels, is used to impregnate the tile. The solution in the tile is gelled, then dried, and then the tile is fired to convert the precursor salts to the desired mixed TMO phases. The amounts of the various TMOs ultimately incorporated into the tile can be tailored via the concentrations of salts in the solution, and the impregnation depth can be tailored via the viscosity of the solution and/or the volume of the solution relative to that of the tile. The amounts of the TMOs determine the absorption and scattering spectra.

  4. Thermal expansion studies on dysprosium and gadolinium titanates

    International Nuclear Information System (INIS)

    Panneerselvam, G.; Antony, M.P.; Vasudeva Rao, P.R.

    2002-01-01

    Lanthanides and their oxides are considered potential candidates for the use in nuclear reactors as control rod. Dysprosium (Dy) and gadolinium (Gd) have very high absorption cross-section for neutrons. Dysprosium and gadolinium titanates were prepared by ceramic route as well as wet chemical route. The compounds were characterized chemically by using inductively coupled plasma mass spectrometric (ICPMS) technique and by x-ray diffraction (XRD) technique. Thermal expansion coefficient was measured in the temperature range 573 to 1573 K by using high temperature x-ray diffraction technique. (author)

  5. Optical absorption of carbon-gold core-shell nanoparticles

    Science.gov (United States)

    Wang, Zhaolong; Quan, Xiaojun; Zhang, Zhuomin; Cheng, Ping

    2018-01-01

    In order to enhance the solar thermal energy conversion efficiency, we propose to use carbon-gold core-shell nanoparticles dispersed in liquid water. This work demonstrates theoretically that an absorbing carbon (C) core enclosed in a plasmonic gold (Au) nanoshell can enhance the absorption peak while broadening the absorption band; giving rise to a much higher solar absorption than most previously studied core-shell combinations. The exact Mie solution is used to evaluate the absorption efficiency factor of spherical nanoparticles in the wavelength region from 300 nm to 1100 nm as well as the electric field and power dissipation profiles inside the nanoparticles at specified wavelengths (mostly at the localized surface plasmon resonance wavelength). The field enhancement by the localized plasmons at the gold surfaces boosts the absorption of the carbon particle, resulting in a redshift of the absorption peak with increased peak height and bandwidth. In addition to spherical nanoparticles, we use the finite-difference time-domain method to calculate the absorption of cubic core-shell nanoparticles. Even stronger enhancement can be achieved with cubic C-Au core-shell structures due to the localized plasmonic resonances at the sharp edges of the Au shell. The solar absorption efficiency factor can exceed 1.5 in the spherical case and reach 2.3 in the cubic case with a shell thickness of 10 nm. Such broadband absorption enhancement is in great demand for solar thermal applications including steam generation.

  6. Production of a {sup 44} Ti target and its cross section of thermal neutron capture; Producao de um alvo de {sup 44} Ti e sua secao de choque para captura de neutrons termicos

    Energy Technology Data Exchange (ETDEWEB)

    Ejnisman, R

    1993-12-31

    A study of the production of a {sup 44} Ti target was carried out aiming the determination of its thermal neutron capture cross-section. With this purpose, the cross-section of the reaction {sup 45} Sc(p,2 n) {sup 44} Ti was determined in the energies 16-, 18-, 20-22- and 45 MeV. The cross-section of the reactions (p,n) {sup 45} Ti, (p,pn) {sup 44m} Sc, (p,pn) {sup 44g} Sc and (p,p2n){sup 43} Sc were also measured. The results in the low energy region are in good agreement with a previous work by McGee et al. On the other hand, the cross-section at 45 MeV is different from McGee`s result and indicates the existence of an abnormal behavior of the excitation function at higher energies. Furthermore, a radiochemical separation method was developed in order to eliminate Sc from the {sup 44} Ti target which was irradiated with neutrons. It was possible to determine an upper limit for the cross-section of the reaction {sup 44} Ti (n, {gamma}) of 4 x 10{sup 3} b. At last, it is presented a discussion of the results obtained and their possible astrophysical implications. (author) 94 refs.

  7. Uranium absorption study pile

    International Nuclear Information System (INIS)

    Raievski, V.; Sautiez, B.

    1959-01-01

    The report describes a pile designed to measure the absorption of fuel slugs. The pile is of graphite and comprises a central section composed of uranium rods in a regular lattice. RaBe sources and BF 3 counters are situated on either side of the center. A given uranium charge is compared with a specimen charge of about 560 kg, and the difference in absorption between the two noted. The sensitivity of the equipment will detect absorption variations of about a few ppm boron (10 -6 boron per gr. of uranium) or better. (author) [fr

  8. Absorption Of Crushing Energy In Square Composite Tubes

    Science.gov (United States)

    Farley, Gary L.

    1992-01-01

    Report describes investigation of crash-energy-absorbing capabilities of square-cross-section tubes of two matrix/fiber composite materials. Both graphite/epoxy and Kevlar/epoxy tubes crushed in progressive and stable manner. Ratio between width of cross section and thickness of wall determined to affect energy-absorption significantly. As ratio decreases, energy-absorption capability increases non-linearly. Useful in building energy-absorbing composite structures.

  9. A basic study for the boron thermal regeneration system using anion exchange resins

    International Nuclear Information System (INIS)

    Frantiesek, P.; Kotaka, Masahiro; Okamoto, Makoto; Kakihana, Hidetake.

    1979-01-01

    For the boron thermal regeneration system (BTRS), the basic characteristics of commercial anion exchange resin have been investigated on the swelling characteristics, absorption, desorption and temperature coefficient of exchange capacity for boric acid. The equilibrium capacity increases as decrease of temperature and depends strongly on the degrees of cross linking having a maximum point at about 7% of DVB. The temperature coefficient of equilibrium capacity of boric acid is also a function of the concentration of external solution and of the cross linking having a maximum point around 7% of DVB. (author)

  10. Effect of Cross-Linking on the Mechanical and Thermal Properties of Poly(amidoamine Dendrimer/Poly(vinyl alcohol Hybrid Membranes for CO2 Separation

    Directory of Open Access Journals (Sweden)

    Shuhong Duan

    2014-04-01

    Full Text Available Poly(amidoamine (PAMAM dendrimers were incorporated into cross-linked poly(vinyl alcohol (PVA matrix to improve carbon dioxide (CO2 separation performance at elevated pressures. In our previous studies, PAMAM/PVA hybrid membranes showed high CO2 separation properties from CO2/H2 mixed gases. In this study, three types of organic Ti metal compounds were selected as PVA cross-linkers that were used to prepare PAMAM/cross-linked PVA hybrid membranes. Characterization of the PAMAM/cross-linked PVA hybrid membranes was conducted using nanoindentation and thermogravimetric analyses. The effects of the cross-linker and CO2 partial pressure in the feed gas on CO2 separation performance were discussed. H2O and CO2 sorption of the PAMAM/PVA hybrid membranes were investigated to explain the obtained CO2 separation efficiencies.

  11. Effect of Cross-Linking on the Mechanical and Thermal Properties of Poly(amidoamine) Dendrimer/Poly(vinyl alcohol) Hybrid Membranes for CO2 Separation.

    Science.gov (United States)

    Duan, Shuhong; Kai, Teruhiko; Saito, Takashi; Yamazaki, Kota; Ikeda, Kenichi

    2014-04-08

    Poly(amidoamine) (PAMAM) dendrimers were incorporated into cross-linked poly(vinyl alcohol) (PVA) matrix to improve carbon dioxide (CO2) separation performance at elevated pressures. In our previous studies, PAMAM/PVA hybrid membranes showed high CO2 separation properties from CO2/H2 mixed gases. In this study, three types of organic Ti metal compounds were selected as PVA cross-linkers that were used to prepare PAMAM/cross-linked PVA hybrid membranes. Characterization of the PAMAM/cross-linked PVA hybrid membranes was conducted using nanoindentation and thermogravimetric analyses. The effects of the cross-linker and CO2 partial pressure in the feed gas on CO2 separation performance were discussed. H2O and CO2 sorption of the PAMAM/PVA hybrid membranes were investigated to explain the obtained CO2 separation efficiencies.

  12. Solar heating and cooling with absorption refrigeration

    OpenAIRE

    Montlló Casabayó, Gerard

    2010-01-01

    This project is focused on solar heating and cooling installations that use solar thermal energy to produce heat for domestic hot water or space heating, and cooling for air conditioning through absorption refrigeration cycle. The first part of the project is a literature review of said technology. The main components of such installations are described and results and conclusions from existing installations are reviewed. The second part is focused on designing, modelling and simula...

  13. Influence of Sonication on the Stability and Thermal Properties of Al2O3 Nanofluids

    Directory of Open Access Journals (Sweden)

    Monir Noroozi

    2014-01-01

    Full Text Available Nanofluids containing Al2O3 nanoparticles (either 11 or 30 nm in size dispersed in distilled water at low concentrations (0.125–0.5 wt% were prepared using two different ultrasonic devices (a probe and a bath sonicator as the dispersant. The effect of the ultrasonic system on the stability and thermal diffusivity of the nanofluids was investigated. Thermal diffusivity measurements were conducted using a photopyroelectric technique. The dispersion characteristics and morphology of the nanoparticles, as well as the optical absorption properties of the nanofluids, were studied using photon cross correlation spectroscopy with a Nanophox analyzer, transmission electron microscopy, and ultraviolet-visible spectroscopy. At higher particle concentration, there was greater enhancement of the thermal diffusivity of the nanofluids resulting from sonication. Moreover, greater stability and enhancement of thermal diffusivity were obtained by sonicating the nanofluids with the higher power probe sonicator prior to measurement.

  14. Revisiting Absorptive Capacity

    DEFF Research Database (Denmark)

    de Araújo, Ana Luiza Lara; Ulhøi, John Parm; Lettl, Christopher

    learning processes of absorptive capacity, which comprise combinative and adaptive capabilities. Drawing on survey data (n=169), the study concludes that combinative capabilities primarily enhance transformative and exploratory learning processes, while adaptive capabilities strengthen all three learning......Absorptive capacity has mostly been perceived as a 'passive' outcome of R&D investments. Recently, however, a growing interest into its 'proactive' potentials has emerged. This paper taps into this development and proposes a dynamic model for conceptualizing the determinants of the complementary...

  15. Neutron cross-section determination in geological samples (U)

    International Nuclear Information System (INIS)

    Harris, J.M.; McDaniel, P.J.

    1982-01-01

    The Prompt Gamma Neutron Activation Analysis (PGAA) technique yields elemental composition data which can be used to calculate the macroscopic cross section for any sample. The Small Sample Reactivity Measurements (SSRM) technique yields the macroscopic thermal absorption directly. Experimentally, PGAA is somewhat more difficult because of the calibration and data handling than is SSRM. However, SSRM requires a mathematical model of the reactor which means a rather complicated analysis. Once the model and calibration are completed, data analysis is routine. The SSRM technique is production oriented. 9 figures

  16. Sample stacking in CZE using dynamic thermal junctions I. Analytes with low dpKa/dT crossing a single thermally induced pH junction in a BGE with high dpH/dT.

    Science.gov (United States)

    Mandaji, Marcos; Rübensam, Gabriel; Hoff, Rodrigo Barcellos; Hillebrand, Sandro; Carrilho, Emanuel; Kist, Tarso Ledur

    2009-05-01

    The possibility to compress analyte bands at the beginning of CE runs has many advantages. Analytes at low concentration can be analyzed with high signal-to-noise ratios by using the so-called sample stacking methods. Moreover, sample injections with very narrow initial band widths (small initial standard deviations) are sometimes useful, especially if high resolutions among the bands are required in the shortest run time. In the present work, a method of sample stacking is proposed and demonstrated. It is based on BGEs with high thermal sensitive pHs (high dpH/dT) and analytes with low dpK(a)/dT. High thermal sensitivity means that the working pK(a) of the BGE has a high dpK(a)/dT in modulus. For instance, Tris and Ethanolamine have dpH/dT=-0.028/ degrees C and -0.029/ degrees C, respectively, whereas carboxylic acids have low dpK(a)/dT values, i.e. in the -0.002/ degrees C to+0.002/ degrees C range. The action of cooling and heating sections along the capillary during the runs affects also the local viscosity, conductivity, and electric field strength. The effect of these variables on electrophoretic velocity and band compression is theoretically calculated using a simple model. Finally, this stacking method was demonstrated for amino acids derivatized with naphthalene-2,3-dicarboxaldehyde and fluorescamine using a temperature difference of 70 degrees C between two neighbor sections and Tris as separation buffer. In this case, the BGE has a high pH thermal coefficient whereas the carboxylic groups of the analytes have low pK(a) thermal coefficients. The application of these dynamic thermal gradients increased peak height by a factor of two (and decreased the standard deviations of peaks by a factor of two) of aspartic acid and glutamic acid derivatized with naphthalene-2,3-dicarboxaldehyde and serine derivatized with fluorescamine. The effect of thermal compression of bands was not observed when runs were accomplished using phosphate buffer at pH 7 (negative

  17. Thermal Conductivity Measurement and Analysis of Fully Ceramic Microencapsulated fuel

    International Nuclear Information System (INIS)

    Lee, H. G.; Kim, D. J.; Park, J. Y.; Kim, W. J.; Lee, S. J.

    2015-01-01

    FCM nuclear fuel is composed of tristructural isotropic(TRISO) fuel particle and SiC ceramic matrix. SiC ceramic matrix play an essential part in protecting fission product. In the FCM fuel concept, fission product is doubly protected by TRISO coating layer and SiC ceramic matrix in comparison with the current commercial UO2 fuel system of LWR. In addition to a safety enhancement of FCM fuel, thermal conductivity of SiC ceramic matrix is better than that of UO2 fuel. Because the centerline temperature of FCM fuel is lower than that of the current UO2 fuel due to the difference of thermal conductivity of fuel, an operational release of fission products from the fuel can be reduced. SiC ceramic has attracted for nuclear fuel application due to its high thermal conductivity properties with good radiation tolerant properties, a low neutron absorption cross-section and a high corrosion resistance. Thermal conductivity of ceramic matrix composite depends on the thermal conductivity of each component and the morphology of reinforcement materials such as fibers and particles. There are many results about thermal conductivity of fiber-reinforced composite like as SiCf/SiC composite. Thermal conductivity of SiC ceramics and FCM pellets with the volume fraction of TRISO particles were measured and analyzed by analytical models. Polycrystalline SiC ceramics and FCM pellets with TRISO particles were fabricated by hot press sintering with sintering additives. Thermal conductivity of the FCM pellets with TRISO particles of 0 vol.%, 10 vol.%, 20 vol.%, 30 vol.% and 40 vol.% show 68.4, 52.3, 46.8, 43.0 and 34.5 W/mK, respectively. As the volume fraction of TRISO particles increased, the measured thermal conductivity values closely followed the prediction of Maxwell's equation

  18. Vitamin A absorption

    International Nuclear Information System (INIS)

    Baker, S.J.

    1976-01-01

    Investigation of the absorption of vitamin A and related substances is complicated by the multiplicity of forms in which they occur in the diet and by the possibility that they may be subject to different mechanisms of absorption. Present knowledge of these mechanisms is inadequate, especially in the case of carotenoids. Numerous tests of absorption have been developed. The most common has been the biochemical measurement of the rise in plasma vitamin A after an oral dose of retinol or retinyl ester, but standardization is inadequate. Radioisotope tests based upon assay of serum or faecal activity following oral administration of tritiated vitamin A derivaties hold considerable promise, but again standardization is inadequate. From investigations hitherto performed it is known that absorption of vitamin A is influenced by several diseases, although as yet the consistency of results and the correlation with other tests of intestinal function have often been poor. However, the test of vitamin A absorption is nevertheless of clinical importance as a specialized measure of intestinal function. (author)

  19. Atmospheric water vapor absorption at 1.3 microm.

    Science.gov (United States)

    Bragg, S L; Kelley, J D

    1987-02-01

    Absolute absorption cross sections for water vapor and water vapor/air mixtures were measured in a frequency range encompassing that of the chemically pumped atomic iodine laser. Measurements were made with a temperature-controlled multipass absorption cell and a high-resolution Fourier transform spectrometer. The measurements covered a broad range of water vapor and air pressures. Several techniques of data analysis were used, and the absorption cross section of 2 kPa of water vapor in an atmosphere of air was determined to be 1.1 +/- 0.2 x 10(-24) cm(2) . In this paper, an expression is derived which allows estimation of the absorption cross section for any pressure of water vapor and air.

  20. Measurement of the thermal neutron capture cross section and the resonance integral of the sup 1 sup 0 sup 9 Ag(n, gamma) sup 1 sup 1 sup 0 sup m Ag reaction

    CERN Document Server

    Nakamura, S; Shcherbakov, O A; Furutaka, K; Harada, H; Katoh, T

    2003-01-01

    In order to develop a neutron flux monitor for long-term neutron irradiation, the thermal neutron (2,200 m/s neutron) capture cross section (sigma sub 0) and the resonance integral (I sub 0) of the sup 1 sup 0 sup 9 Ag(n, gamma) sup 1 sup 1 sup 0 sup m Ag reaction were measured by the activation and gamma-ray spectroscopic methods. Silver foils were irradiated with and without a Cd shield capsule at the Rikkyo Research Reactor. The Co/Al and Au/Al alloy wires were irradiated together with silver foils in order to monitor the thermal neutron flux and the fraction of the epi-thermal neutron part (Westcott's index). A high purity Ge detector was used for the gamma-ray measurements of the irradiated samples. The sigma sub 0 and the I sub 0 of the sup 1 sup 0 sup 9 Ag(n, gamma) sup 1 sup 1 sup 0 sup m Ag reaction are 4.12+-0.10 b and 67.9+-3.1 b, respectively. The sigma sub 0 is 12% smaller than the tabulated one (4.7+-0.2 b). On the other hand, the I sub 0 is in agreement with the tabulated one (72.3+-4.0 b) with...

  1. Thermal hyperbolic metamaterials.

    Science.gov (United States)

    Guo, Yu; Jacob, Zubin

    2013-06-17

    We explore the near-field radiative thermal energy transfer properties of hyperbolic metamaterials. The presence of unique electromagnetic states in a broad bandwidth leads to super-planckian thermal energy transfer between metamaterials separated by a nano-gap. We consider practical phonon-polaritonic metamaterials for thermal engineering in the mid-infrared range and show that the effect exists in spite of the losses, absorption and finite unit cell size. For thermophotovoltaic energy conversion applications requiring energy transfer in the near-infrared range we introduce high temperature hyperbolic metamaterials based on plasmonic materials with a high melting point. Our work paves the way for practical high temperature radiative thermal energy transfer applications of hyperbolic metamaterials.

  2. ENDF/B-VIII.0: The 8th Major Release of the Nuclear Reaction Data Library with CIELO-project Cross Sections, New Standards and Thermal Scattering Data

    Science.gov (United States)

    Brown, D. A.; Chadwick, M. B.; Capote, R.; Kahler, A. C.; Trkov, A.; Herman, M. W.; Sonzogni, A. A.; Danon, Y.; Carlson, A. D.; Dunn, M.; Smith, D. L.; Hale, G. M.; Arbanas, G.; Arcilla, R.; Bates, C. R.; Beck, B.; Becker, B.; Brown, F.; Casperson, R. J.; Conlin, J.; Cullen, D. E.; Descalle, M.-A.; Firestone, R.; Gaines, T.; Guber, K. H.; Hawari, A. I.; Holmes, J.; Johnson, T. D.; Kawano, T.; Kiedrowski, B. C.; Koning, A. J.; Kopecky, S.; Leal, L.; Lestone, J. P.; Lubitz, C.; Márquez Damián, J. I.; Mattoon, C. M.; McCutchan, E. A.; Mughabghab, S.; Navratil, P.; Neudecker, D.; Nobre, G. P. A.; Noguere, G.; Paris, M.; Pigni, M. T.; Plompen, A. J.; Pritychenko, B.; Pronyaev, V. G.; Roubtsov, D.; Rochman, D.; Romano, P.; Schillebeeckx, P.; Simakov, S.; Sin, M.; Sirakov, I.; Sleaford, B.; Sobes, V.; Soukhovitskii, E. S.; Stetcu, I.; Talou, P.; Thompson, I.; van der Marck, S.; Welser-Sherrill, L.; Wiarda, D.; White, M.; Wormald, J. L.; Wright, R. Q.; Zerkle, M.; Žerovnik, G.; Zhu, Y.

    2018-02-01

    We describe the new ENDF/B-VIII.0 evaluated nuclear reaction data library. ENDF/B-VIII.0 fully incorporates the new IAEA standards, includes improved thermal neutron scattering data and uses new evaluated data from the CIELO project for neutron reactions on 1H, 16O, 56Fe, 235U, 238U and 239Pu described in companion papers in the present issue of Nuclear Data Sheets. The evaluations benefit from recent experimental data obtained in the U.S. and Europe, and improvements in theory and simulation. Notable advances include updated evaluated data for light nuclei, structural materials, actinides, fission energy release, prompt fission neutron and γ-ray spectra, thermal neutron scattering data, and charged-particle reactions. Integral validation testing is shown for a wide range of criticality, reaction rate, and neutron transmission benchmarks. In general, integral validation performance of the library is improved relative to the previous ENDF/B-VII.1 library.

  3. Measurement of thermal neutron cross-section and resonance integral for the 165Ho(n,γ) 166gHo reaction using electron linac-based neutron source

    Science.gov (United States)

    Nguyen, Van Do; Pham, Duc Khue; Kim, Tien Thanh; Kim, Guinyun; Lee, Manwoo; Kim, Kyung Sook; Kang, Heung-Sik; Cho, Moo-Hyun; Ko, In Soo; Namkung, Won

    2011-01-01

    The thermal neutron cross-section and the resonance integral of the 165Ho(n,γ) 166gHo reaction have been measured by the activation method using a 197Au(n,γ) 198Au monitor reaction as a single comparator. The high-purity natural Ho and Au foils with and without a cadmium shield case of 0.5 mm thickness were irradiated in a neutron field of the Pohang neutron facility. The induced activities in the activated foils were measured with a calibrated p-type high-purity Ge detector. The correction factors for the γ-ray attenuation ( Fg), the thermal neutron self-shielding ( Gth), the resonance neutron self-shielding ( Gepi) effects, and the epithermal neutron spectrum shape factor ( α) were taken into account. The thermal neutron cross-section for the 165Ho(n,γ) 166gHo reaction has been determined to be 59.7 ± 2.5 barn, relative to the reference value of 98.65 ± 0.09 barn for the 197Au(n,γ) 198Au reaction. By assuming the cadmium cut-off energy of 0.55 eV, the resonance integral for the 165Ho(n,γ) 166gHo reaction is 671 ± 47 barn, which is determined relative to the reference value of 1550 ± 28 barn for the 197Au(n,γ) 198Au reaction. The present results are, in general, good agreement with most of the previously reported data within uncertainty limits.

  4. Gastrointestinal absorption of plutonium

    International Nuclear Information System (INIS)

    Larsen, R.P.; Oldham, R.D.; Bhattacharyya, M.H.; Moretti, E.S.; Austin, D.J.

    1981-01-01

    An investigation has been made of the effect of the oxidation state of plutonium on its absorption from the gastrointestinal tract. For mice and rats that have been starved prior to gastrointestinal administration, there is no significant difference between the absorption factors for Pu(IV) and Pu(VI). The value obtained for Pu(VI) is an order of magnitude lower than that reported previously. The value obtained for Pu(IV) is two orders of magnitude higher than those reported previously for nitrate solutions and the same as those reported for citrate solutions

  5. Hydrogen absorption in Mg1.95Ti0.05Ni0.95Cu0.05 alloy prepared with mechanical alloying and thermal treatment; Absorcion de hidrogeno en la aleacion Mg1.95Ti0.05Ni0.95Cu0.05 preparada por aleado mecanico y tratamiento termico

    Energy Technology Data Exchange (ETDEWEB)

    Martinez, Juan Bonifacio; Urena Nunez, Fernando [Instituto Nacional de Investigaciones Nucleares, Ocoyoacac, Estado de Mexico (Mexico)]. E-mail: juan.bonifacio@inin.gob.mx

    2009-09-15

    This work presents hydrogen absorption in quaternary alloy Mg1.95Ti0.05Ni0.95Cu0.05 obtained by the mechanical alloying method, followed by thermal treatment in ultra-high pure argon atmosphere. The composition of the phases, microstructure and morphology of ground powders and with thermal treatment were characterized by DRX, SEM/EDS and TEM. After 20 hours of mechanical grinding and recooked at 300 degrees Celsius/1h in argon atmosphere, the quaternary alloy has a Mg{sub 2}Ni crystalline hexagonal structure with a crystallite size under 10 nm. The absorption measurements were performed under a pressure of 0.2 to 1.2 MPa at a temperature of 200 degrees Celsius in a micro-reactor. The quantification of absorption-desorption of hydrogen in the intermetallic was conducted in a TGA-DSC simultaneous calorimeter. Metallic hydride-dehydride powder was characterized with SEM and XRD. [Spanish] En este trabajo se presenta la absorcion de hidrogeno en la aleacion cuaternaria Mg1.95Ti0.05Ni0.95Cu0.05 obtenida por el metodo de aleado mecanico, seguida de tratamiento termico en atmosfera de argon de ultra alta pureza. La composicion de las fases, microestructura y morfologia de los polvos molidos y con tratamiento termico fue caracterizada por DRX, SEM/EDS y TEM. Despues de 20 h de molienda mecanica con recocido a 300 grados Celsios/1h en atmosfera de argon, la aleacion cuaternaria tiene una estructura cristalina hexagonal Mg{sub 2}Ni con tamano de cristalito menor a 10 nm. Las mediciones de absorcion fueron realizadas bajo una presion de 0.2 a 1.2 MPa a una temperatura de 200 grados Celsios en un micro-reactor. La cuantificacion de absorcion-desorcion de hidrogeno en el intermetalico se realizo en un calorimetro simultaneo TGA-DSC. Se determino que la cantidad maxima absorbida de hidrogeno en la aleacion cuaternaria fue de 3.24% en peso cuando la presion fue de 0.8 MPa a dicha temperatura. Polvos metalicos hidrurados-deshidrurados se caracterizaron por SEM y XRD.

  6. Time-resolved X-ray absorption spectroscopy for the study of solid state reactions: synthesis of nanocrystalline barium titanate and thermal decomposition of ammonium hexachlorometallate compounds; Zeitaufgeloeste Roentgenabsorptionspektroskopie zur Untersuchung von Festkoerperreaktionen: Synthese von nanokristallinem Bariumtitanat und thermische Zersetzung von Ammoniumhexachlorometallat-Verbindungen

    Energy Technology Data Exchange (ETDEWEB)

    Rumpf, H.

    2001-07-01

    This report presents investigations on the mechanism of two different types of solid-state reactions: At first, barium titanate nanopowders were prepared through a combined polymerization and pyrolysis of a metallo-organic precursor. The mean particle size d{sub m} could be adjusted by choosing appropriate reaction temperatures and tempering atmospheres. In the present in situ study of this particular solid-phase reaction, X-ray absorption near edge structure (XANES) spectroscopy at the Ti K and Ba L{sub 3}-edges was applied in the preparation route of BaTiO{sub 3} nanopowders. A pronounced distortion of the lattice symmetry was found to occur in very fine BaTiO{sub 3} nanopowders (d{sub m} < 20 nm). Secondly, in situ XANES investigations were carried out at the Cl K, Pd L{sub 3}, Rh L{sub 3}, and Pt L{sub 3}-edges to study the mechanism of the thermal decomposition of ammonium hexachlorometallates. The results exceed structural information obtained by in situ X-ray diffraction methods and thermal analysis. Feff8 multiple scattering simulations have been carried out to disclose new intermediate phases of unknown reference compounds. (orig.)

  7. Measurements of thermal parameters of solar modules

    International Nuclear Information System (INIS)

    Górecki, K; Krac, E

    2016-01-01

    In the paper the methods of measuring thermal parameters of photovoltaic panels - transient thermal impedance and the absorption factor of light-radiation are presented. The manner of realising these methods is described and the results of measurements of the considered thermal parameters of selected photovoltaic panels are presented. The influence of such selected factors as a type of the investigated panel and its mounting manner on transient thermal impedance of the considered panels is also discussed. (paper)

  8. Dynamics of water absorption through superabsorbent polymer

    Science.gov (United States)

    Chang, Sooyoung; Kim, Wonjung

    2017-11-01

    Superabsorbent polymers (SAPs) consist of hydrophilic cross-linked polymer networks that can absorb and retain a great amount of water relative to their own mass, so that they are widely used for disposable diapers and holding soil moisture in agriculture. SAPs are typically available in the form of submillimeter-sized particles, and the water absorption is driven by capillary flows between particles as well as diffusion that entail swelling. Although the control of water absorption of SAPs is important in engineering applications, but the dynamics of water absorption in SAP particles has not been fully understood. We examine the dynamics of the water absorption of sodium polyacrylate, one of the most common SAP. We experimentally measured the water absorption of sodium polyacrylate particles in one-dimensional confined channel. The water flows through the particles were analyzed by capillarity dominant at the early stage and by diffusion involving volume expansion critical at a later stage. The results provide a quantitative basis of the hydrodynamic analysis of the water flow through SAP particles from a macroscopic point of view, facilitating the prediction of water uptake of SAPs in hygienic and agricultural applications. This work was supported by the National Research Foundation of Korea (NRF) Grant funded by the Korea government (MSIP) (No.2015R1A2A2A04006181).

  9. Water flow experiment using the PIV technique and the thermal hydraulic analysis on the cross-flow type mercury target model

    International Nuclear Information System (INIS)

    Haga, Katsuhiro; Terada, Atsuhiko; Kaminaga, Masanori; Hino, Ryutaro

    2001-01-01

    In this study the effectiveness of the cross-flow type mercury target structure was evaluated experimentally and analytically. The average water flow velocity field in the target mock-up model, which was fabricated with plexiglass, was measured at room temperature using the PIV (Particle Image Velocimetry) technique. The water flow analyses were conducted and the analytical results were compared with the experimental results. The experimental results showed that the cross-flow could be realized in the former part of the proton beam path where the heat load by the spallation reaction is large, and the analytical result of the water flow velocity field showed good correspondence to the experimental result in the case of the Reynolds number of more than 4.83 x 10 5 at the model inlet. With these results, the effectiveness of the cross-flow type mercury target structure and the present analysis code system was demonstrated. Then the mercury flow field and the temperature distribution in the target container were analyzed assuming the proton beam energy and power of 3 GeV and 5 MW. The analytical result showed that the cross-flow field of mercury, which is similar to the water flow field, could also be attained. (author)

  10. Investigation Of Thermal Properties Of Naturally Seasoned Dry ...

    African Journals Online (AJOL)

    Steady-state thermal conductivity measurements of naturally seasoned African thorn tree (Macaranga barteri) timer boards were carried out. Other thermal and physical properties such as specific heat capacity, thermal resistivity, density, thermal absorptivity and diffusivity as well as percentage of dead air space (v/v) were ...

  11. Chemical Absorption Materials

    DEFF Research Database (Denmark)

    Thomsen, Kaj

    2011-01-01

    Chemical absorption materials that potentially can be used for post combustion carbon dioxide capture are discussed. They fall into five groups, alkanolamines, alkali carbonates, ammonia, amino acid salts, and ionic liquids. The chemistry of the materials is discussed and advantages and drawbacks...

  12. Neutron resonance absorption theory

    International Nuclear Information System (INIS)

    Reuss, P.

    1991-11-01

    After some recalls on the physics of neutron resonance absorption during their slowing down, this paper presents the main features of the theoretical developments performed by the french school of reactor physics: the effective reaction rate method so called Livolant-Jeanpierre theory, the generalizations carried out by the author, and the probability table method [fr

  13. Hydrolysis Batteries: Generating Electrical Energy during Hydrogen Absorption.

    Science.gov (United States)

    Xiao, Rui; Chen, Jun; Fu, Kai; Zheng, Xinyao; Wang, Teng; Zheng, Jie; Li, Xingguo

    2018-02-19

    The hydrolysis reaction of aluminum can be decoupled into a battery by pairing an Al foil with a Pd-capped yttrium dihydride (YH 2 -Pd) electrode. This hydrolysis battery generates a voltage around 0.45 V and leads to hydrogen absorption into the YH 2 layer. This represents a new hydrogen absorption mechanism featuring electrical energy generation during hydrogen absorption. The hydrolysis battery converts 8-15 % of the thermal energy of the hydrolysis reaction into usable electrical energy, leading to much higher energy efficiency compared to that of direct hydrolysis. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. Radionuclide Absorption Demonstration System

    Data.gov (United States)

    National Aeronautics and Space Administration — After a nuclear thermal rocket (NTR) is test fired, the engine’s reactor is operated in a cool-down mode during which radioactive exhaust by-products continue to be...

  15. Measurement of the Neutron Capture Cross Sections of $^{233}$U, $^{237}$Np, $^{240,242}$Pu, $^{241,243}$Am and $^{245}$Cm with a Total Absorption Calorimeter at n_TOF

    CERN Multimedia

    Beer, H; Wiescher, M; Cox, J; Rapp, W; Embid, M; Dababneh, S

    2002-01-01

    Accurate and reliable neutron capture cross section data for actinides are necessary for the poper design, safety regulation and precise performance assessment of transmutation devices such as Fast Critical Reactors or Accelerator Driven Systems (ADS). The goal of this proposal is the measurement of the neutron capture cross sections of $^{233}$U, $^{237}$Np, $^{240,242}$Pu, $^{241,243}$Am and $^{245}$Cm at n_TOF with an accuracy of 5~\\%. $^{233}$U plays an essential role in the Th fuel cycle, which has been proposed as a safer and cleaner alternative to the U fuel cycle. The capture cross sections of $^{237}$Np,$^{240,242}$Pu, $^{241,243}$Am and $^{245}$Cm play a key role in the design and optimization of a strategy for the Nuclear Waste Transmutation. A high accuracy can be achieved at n_TOF in such measurements due to a combination of features unique in the world: high instantaneous neutron fluence and excellent energy resolution of the facility, innovative Data Acquisition System based on flash ADCs and t...

  16. Plasma-based radar cross section reduction

    CERN Document Server

    Singh, Hema; Jha, Rakesh Mohan

    2016-01-01

    This book presents a comprehensive review of plasma-based stealth, covering the basics, methods, parametric analysis, and challenges towards the realization of the idea. The concealment of aircraft from radar sources, or stealth, is achieved through shaping, radar absorbing coatings, engineered materials, or plasma, etc. Plasma-based stealth is a radar cross section (RCS) reduction technique associated with the reflection and absorption of incident electromagnetic (EM) waves by the plasma layer surrounding the structure. A plasma cloud covering the aircraft may give rise to other signatures such as thermal, acoustic, infrared, or visual. Thus it is a matter of concern that the RCS reduction by plasma enhances its detectability due to other signatures. This needs a careful approach towards the plasma generation and its EM wave interaction. The book starts with the basics of EM wave interactions with plasma, briefly discuss the methods used to analyze the propagation characteristics of plasma, and its generatio...

  17. Multigroup or multipoint thermal neutron data preparation. Programme SIGMA

    International Nuclear Information System (INIS)

    Matausek, M.V.; Kunc, M.

    1974-01-01

    When calculating the space energy distribution of thermal neutrons in reactor lattices, in either the multigroup or the multipoint approximation, it is convenient to divide the problem into two independent parts. Firstly, for all material regions of the given reactor lattice cell, the group or the point values of cross sections, scattering kernel and the outer source of thermal neutrons are calculated by a data preparation programme. These quantities are then used as input, by the programme which solves multigroup or multipoint transport equations, to generate the space energy neutron spectra in the cell considered and to determine the related integral quantities, namely the different reaction rates. The present report deals with the first part of the problem. An algorithm for constructing a set of thermal neutron input data, to be used with the multigroup or multipoint version of the code MULTI /1,2,3/, is presented and the new version of the programme SIGMA /4/, written in FORTRAN IV for the CDC-3600 computer, is described. For a given reactor cell material, composed of a number of different isotopes, this programme calculates the group or the point values of the scattering macroscopic absorption cross section, macroscopic scattering cross section, kernel and the outer source of thermal neutrons. Numerous options are foreseen in the programme, concerning the energy variation of cross sections and a scattering kernel, concerning the weighting spectrum in multigroup scheme or the procedure for constructing the scattering matrix in the multipoint scheme and, finally, concerning the organization of output. The details of the calculational algorithm are presented in Section 2 of the paper. Section 3 contains the description of the programme and the instructions for its use (author)

  18. Detection of O4 absorption around 328 and 419 nm in measured atmospheric absorption spectra

    Directory of Open Access Journals (Sweden)

    J. Lampel

    2018-02-01

    Full Text Available Retrieving the column of an absorbing trace gas from spectral data requires that all absorbers in the corresponding wavelength range are sufficiently well known. This is especially important for the retrieval of weak absorbers, whose absorptions are often in the 10−4 range. Previous publications on the absorptions of the oxygen dimer O2–O2 (or short: O4 list absorption peaks at 328 and 419 nm, for which no spectrally resolved literature cross sections are available. As these absorptions potentially influence the spectral retrieval of various trace gases, such as HCHO, BrO, OClO and IO, their shape and magnitude need to be quantified. We assume that the shape of the absorption peaks at 328 and 419 nm can be approximated by their respective neighbouring absorption peaks. Using this approach we obtain estimates for the wavelength of the absorption and its magnitude. Using long-path differential optical absorption spectroscopy (LP-DOAS observations and multi-axis DOAS (MAX-DOAS observations, we estimate the peak absorption cross sections of O4 to be (1.96  ±  0.20 × 10−47 cm5 molec−2 and determine the wavelength of its maximum at 328.59  ±  0.15 nm. For the absorption at 419.13  ±  0.42 nm a peak O4 cross-section value is determined to be (5.0  ±  3.5 × 10−48 cm5 molec−2.

  19. Quantum absorption refrigerator with trapped ions

    Science.gov (United States)

    Gan, Jaren; Maslennikov, Gleb; Hablützel Marrero, Roland; Ding, Shiqian; Nimmrichter, Stefan; Roulet, Alexandre; Dai, Jibo; Scarani, Valerio; Matsukevich, Dzmitry

    2017-04-01

    We report on an experimental realization of a quantum absorption refrigerator in a system of the three trapped 171Yb+ ions. The normal modes of motion are coupled by a trilinear Hamiltonian a† bc + h . c . and represent ``hot'', ``work'' and ``cold'' bodies of the refrigerator. We investigate the equilibrium properties of the refrigerator, and demonstrate the absorption refrigeration effect with the modes being prepared in thermal states. We also investigate the coherent dynamics and steady state properties of such a system away from equilibrium operation. We compare the cooling capabilities of thermal versus squeezed thermal states prepared in the work mode as a quantum resource for cooling. Finally, we exploit the coherent dynamics of the system and demonstrate single-shot cooling in the refrigerator. By stopping the evolution in the right moment, we show a significant advantage in cooling as compared to both the steady state and equilibrium performance. This research is supported by the National Research Foundation, Prime Minister's Office, Singapore and the Ministry of Education, Singapore under the Research Centres of Excellence programme.

  20. Unsteady MHD Mixed Convection Slip Flow of Casson Fluid over Nonlinearly Stretching Sheet Embedded in a Porous Medium with Chemical Reaction, Thermal Radiation, Heat Generation/Absorption and Convective Boundary Conditions.

    Directory of Open Access Journals (Sweden)

    Imran Ullah

    Full Text Available Numerical results are presented for the effect of first order chemical reaction and thermal radiation on mixed convection flow of Casson fluid in the presence of magnetic field. The flow is generated due to unsteady nonlinearly stretching sheet placed inside a porous medium. Convective conditions on wall temperature and wall concentration are also employed in the investigation. The governing partial differential equations are converted to ordinary differential equations using suitable transformations and then solved numerically via Keller-box method. It is noticed that fluid velocity rises with increase in radiation parameter in the case of assisting flow and is opposite in the case of opposing fluid while radiation parameter has no effect on fluid velocity in the forced convection. It is also seen that fluid velocity and concentration enhances in the case of generative chemical reaction whereas both profiles reduces in the case of destructive chemical reaction. Further, increase in local unsteadiness parameter reduces fluid velocity, temperature and concentration. Over all the effects of physical parameters on fluid velocity, temperature and concentration distribution as well as on the wall shear stress, heat and mass transfer rates are discussed in detail.

  1. Unsteady MHD Mixed Convection Slip Flow of Casson Fluid over Nonlinearly Stretching Sheet Embedded in a Porous Medium with Chemical Reaction, Thermal Radiation, Heat Generation/Absorption and Convective Boundary Conditions.

    Science.gov (United States)

    Ullah, Imran; Bhattacharyya, Krishnendu; Shafie, Sharidan; Khan, Ilyas

    2016-01-01

    Numerical results are presented for the effect of first order chemical reaction and thermal radiation on mixed convection flow of Casson fluid in the presence of magnetic field. The flow is generated due to unsteady nonlinearly stretching sheet placed inside a porous medium. Convective conditions on wall temperature and wall concentration are also employed in the investigation. The governing partial differential equations are converted to ordinary differential equations using suitable transformations and then solved numerically via Keller-box method. It is noticed that fluid velocity rises with increase in radiation parameter in the case of assisting flow and is opposite in the case of opposing fluid while radiation parameter has no effect on fluid velocity in the forced convection. It is also seen that fluid velocity and concentration enhances in the case of generative chemical reaction whereas both profiles reduces in the case of destructive chemical reaction. Further, increase in local unsteadiness parameter reduces fluid velocity, temperature and concentration. Over all the effects of physical parameters on fluid velocity, temperature and concentration distribution as well as on the wall shear stress, heat and mass transfer rates are discussed in detail.

  2. Thermal Anemometry Grid Sensor.

    Science.gov (United States)

    Arlit, Martin; Schleicher, Eckhard; Hampel, Uwe

    2017-07-19

    A novel thermal anemometry grid sensor was developed for the simultaneous measurement of cross-sectional temperature and axial velocity distribution in a fluid flow. The sensor consists of a set of platinum resistors arranged in a regular grid. Each platinum resistor allows the simultaneous measurement of fluid temperature via electrical resistance and flow velocity via constant voltage thermal anemometry. Cross-sectional measurement was enabled by applying a special multiplexing-excitation scheme. In this paper, we present the design and characterization of a prototypical sensor for measurements in a range of very low velocities.

  3. Absorptive Capacity and Diversity

    DEFF Research Database (Denmark)

    Kristinsson, Kári

    international business, organizational economics, strategic management, technology management and last but not least neo-Schumpeterian economics. The goal of this dissertation is to examine what many consider as neglected arguments from the work by Cohen and Levinthal and thereby illuminate an otherwise......One of the most influential contributions to neo-Schumpeterian economics is Cohen and Levinthal‘s papers on absorptive capacity. Since their publication in the late 1980s and early 1990s the concept absorptive capacity has had substantial impact on research in economics and management, including...... overlooked area of research. Although research based on Cohen and Levinthal‘s work has made considerable impact, there is scarcity of research on certain fundamental points argued by Cohen and Levinthal. Among these is the importance of employee diversity as well as the type and nature of interaction between...

  4. Sound absorption of snow

    OpenAIRE

    Maysenhölder, W.; Schneebeli, M.; Zhou, X.; Zhang, T.; Heggli, M.

    2008-01-01

    Recently fallen snow possesses good sound-absorbing properties. This fact is well-known and confirmed by measurements. Is the filigree structure of snowflakes decisive? In principle we know that the sound-absorbing capacity of a porous material is dependent on its structure. But until now the question as to which structural characteristics are significant has been insufficiently answered. Detailed investigations of snow are to explain this fact by precise measurements of the sound absorption,...

  5. Iron absorption studies

    International Nuclear Information System (INIS)

    Ekenved, G.

    1976-01-01

    The main objective of the present work was to study iron absorption from different iron preparations in different types of subjects and under varying therapeutic conditions. The studies were performed with different radioiron isotope techniques and with a serum iron technique. The preparations used were solutions of ferrous sulphate and rapidly-disintegrating tablets containing ferrous sulphate, ferrous fumarate and ferrous carbonate and a slow-release ferrous sulphate tablet of an insoluble matrix type (Duroferon Durules). The serum iron method was evaluated and good correlation was found between the serum iron response and the total amount of iron absorbed after an oral dose of iron given in solution or in tablet form. New technique for studying the in-vivo release properties of tablets was presented. Iron tablets labelled with a radio-isotope were given to healthy subjects. The decline of the radioactivity in the tablets was followed by a profile scanning technique applied to different types of iron tablets. The release of iron from the two types of tablets was shown to be slower in vivo than in vitro. It was found that co-administration of antacids and iron tablets led to a marked reduction in the iron absorption and that these drugs should not be administered sumultaneously. A standardized meal markedly decreased the absorbability of iron from iron tablets. The influence of the meal was more marked with rapidly-disintegrating than with slow-release ferrous sulphate tablets. The absorption from rapidly-disintegrating and slow-release ferrous sulphate tablets was compared under practical clinical conditions during an extended treatment period. The studies were performed in healthy subjects, blood donors and patients with iron deficiency anaemia and it was found that the absorption of iron from the slow-release tablets was significantly better than from the rapidly-disintegrating tablets in all three groups of subjects. (author)

  6. Total Absorption Spectroscopy

    International Nuclear Information System (INIS)

    Rubio, B.; Gelletly, W.

    2007-01-01

    The problem of determining the distribution of beta decay strength (B(GT)) as a function of excitation energy in the daughter nucleus is discussed. Total Absorption Spectroscopy is shown to provide a way of determining the B(GT) precisely. A brief history of such measurements and a discussion of the advantages and disadvantages of this technique, is followed by examples of two recent studies using the technique. (authors)

  7. Cross section for inelastic neutron acceleration by 178Hfm2

    International Nuclear Information System (INIS)

    Karamyan, S.A.; Carroll, J.J.

    2009-01-01

    The scattering of thermal neutrons from isomeric nuclei may include events in which the outgoing neutrons have increased kinetic energy. This process has been called Inelastic Neutron Acceleration (INNA) and occurs when the final nucleus after emission of the neutron is left in a state with lower energy than that of the isomer. The result, therefore, is an induced depletion of the isomeric population to the ground state. A cascade of several gammas must accompany the neutron emission to release the high angular momentum of the initial isomeric state. INNA was previously observed in a few cases and the associated cross sections were only in modest agreement with theoretical estimates. The most recent measurement of an INNA cross section was σ INNA = (258 ± 58) b for neutron scattering by 177 Lu m . In the present work, an INNA cross section of σ INNA = 152 -36 +51 b was deduced from measurements of the total burn-up of the high-spin, four-quasiparticle isomer 178 Hf m2 during irradiation by thermal neutrons. Statistical estimates for the probability of different reaction channels past neutron absorption were used in the analysis, and the deduced σ INNA is compared to the theoretically predicted cross section

  8. Relic Neutrino Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Eberle, b

    2004-01-28

    Resonant annihilation of extremely high-energy cosmic neutrinos on big-bang relic anti-neutrinos (and vice versa) into Z-bosons leads to sizable absorption dips in the neutrino flux to be observed at Earth. The high-energy edges of these dips are fixed, via the resonance energies, by the neutrino masses alone. Their depths are determined by the cosmic neutrino background density, by the cosmological parameters determining the expansion rate of the universe, and by the large redshift history of the cosmic neutrino sources. We investigate the possibility of determining the existence of the cosmic neutrino background within the next decade from a measurement of these absorption dips in the neutrino flux. As a by-product, we study the prospects to infer the absolute neutrino mass scale. We find that, with the presently planned neutrino detectors (ANITA, Auger, EUSO, OWL, RICE, and SalSA) operating in the relevant energy regime above 10{sup 21} eV, relic neutrino absorption spectroscopy becomes a realistic possibility. It requires, however, the existence of extremely powerful neutrino sources, which should be opaque to nucleons and high-energy photons to evade present constraints. Furthermore, the neutrino mass spectrum must be quasi-degenerate to optimize the dip, which implies m{sub {nu}} 0.1 eV for the lightest neutrino. With a second generation of neutrino detectors, these demanding requirements can be relaxed considerably.

  9. Analysis of thermal fluctuations in the semiscale tests to determine flow transit delay times using a transfer function cross-correlation technique

    International Nuclear Information System (INIS)

    Raptis, A.C.; Popper, G.F.

    1977-08-01

    On April 14, 1976, EG and G performed the Semiscale Blowdown 29-1 experiment to try to establish the feasibility of using a transit time flowmeter (TTF) to measure transient blowdown two-phase flow rates. The recorded signals from that experiment were made available to and analyzed by the Argonne National Laboratory using the transfer function cross-correlation technique. The theoretical background for the transfer function method of analysis and the results of the data analysis are presented. Histograms of transit time during the blowdown are shown and topics for further investigation are identified

  10. A numerical study on thermal behavior of a D-type water-cooled steam boiler

    International Nuclear Information System (INIS)

    Moghari, M.; Hosseini, S.; Shokouhmand, H.; Sharifi, H.; Izadpanah, S.

    2012-01-01

    To achieve a precise assessment on thermal performance of a D-type water-cooled natural gas-fired boiler the present paper was aimed at determining temperature distribution of water and flue gas flows in its different heat exchange equipment. Using the zonal method to predict thermal radiation treatment in the boiler furnace and a numerical iterative approach, in which heat and fluid flow relations associated with different heat surfaces in the boiler convective zone were employed to estimate heat transfer characteristics, enabled this numerical study to obtain results in good agreement with experimental data measured in the utility site during steady state operation. A constant flow rate for a natural gas fuel of specified chemical composition was assumed to be mixed with a given excess ratio of air flow at a full boiler load. Significant results attributed to distribution of heat flux on different furnace walls and that of flue gas and water/steam temperature in different convective stages including superheater, evaporating risers and downcomers modules, and economizer were obtained. Besides the rate of heat absorption in every stage and other essential parameters in the boiler design too, inherent thermal characteristics like radiative and convective heat transfer coefficients as well as overall heat transfer conductance and effectiveness of convective stages considered as cross-flow heat exchangers were eventually presented for the given operating condition. - Highlights: ► Detailed distribution of heat flux on all of the boiler furnace walls was obtained. ► Flue gas and water thermal behaviors in different heating sections were evaluated. ► A good agreement was made between numerical results and experimental data. ► Contribution of the boiler furnace to the total thermal absorption was 39%. ► Contribution of the boiler tube banks to the total thermal absorption was 61%.

  11. Infrared multiphoton absorption and decomposition

    International Nuclear Information System (INIS)

    Evans, D.K.; McAlpine, R.D.

    1984-01-01

    The discovery of infrared laser induced multiphoton absorption (IRMPA) and decomposition (IRMPD) by Isenor and Richardson in 1971 generated a great deal of interest in these phenomena. This interest was increased with the discovery by Ambartzumian, Letokhov, Ryadbov and Chekalin that isotopically selective IRMPD was possible. One of the first speculations about these phenomena was that it might be possible to excite a particular mode of a molecule with the intense infrared laser beam and cause decomposition or chemical reaction by channels which do not predominate thermally, thus providing new synthetic routes for complex chemicals. The potential applications to isotope separation and novel chemistry stimulated efforts to understand the underlying physics and chemistry of these processes. At ICOMP I, in 1977 and at ICOMP II in 1980, several authors reviewed the current understandings of IRMPA and IRMPD as well as the particular aspect of isotope separation. There continues to be a great deal of effort into understanding IRMPA and IRMPD and we will briefly review some aspects of these efforts with particular emphasis on progress since ICOMP II. 31 references

  12. Effect of an Opaque Reflecting Layer on the Thermal Behavior of a Thermal Barrier Coating

    Science.gov (United States)

    Spuckler, Charles M.

    2007-01-01

    A parametric study using a two-flux approximation of the radiative transfer equation was performed to examine the effects of an opaque reflective layer on the thermal behavior of a typical semitransparent thermal barrier coating on an opaque substrate. Some ceramic materials are semitransparent in the wavelength ranges where thermal radiation is important. Even with an opaque layer on each side of the semitransparent thermal barrier coating, scattering and absorption can have an effect on the heat transfer. In this work, a thermal barrier coating that is semitransparent up to a wavelength of 5 micrometers is considered. Above 5 micrometers wavelength, the thermal barrier coating is opaque. The absorption and scattering coefficient of the thermal barrier was varied. The thermal behavior of the thermal barrier coating with an opaque reflective layer is compared to a thermal barrier coating without the reflective layer. For a thicker thermal barrier coating with lower convective loading, which would be typical of a combustor liner, a reflective layer can significantly decrease the temperature in the thermal barrier coating and substrate if the scattering is weak or moderate and for strong scattering if the absorption is large. The layer without the reflective coating can be about as effective as the layer with the reflective coating if the absorption is small and the scattering strong. For low absorption, some temperatures in the thermal barrier coating system can be slightly higher with the reflective layer. For a thin thermal barrier coating with high convective loading, which would be typical of a blade or vane that sees the hot sections of the combustor, the reflective layer is not as effective. The reflective layer reduces the surface temperature of the reflective layer for all conditions considered. For weak and moderate scattering, the temperature of the TBC-substrate interface is reduced but for strong scattering, the temperature of the substrate is increased

  13. Total Cross-Sections of U, UO{sub 2} and ThO{sub 2} for Thermal and Subthermal Neutrons

    Energy Technology Data Exchange (ETDEWEB)

    Beshai, S.F. [IAEA-fellow from Atomic Energy Establishment (Egypt)

    1966-03-15

    The total neutron cross-sections of U, UO{sub 2} and ThO{sub 2} have been measured from 0.0045 eV to 0.028 eV, using the time-of-flight technique. The samples were measured at 20 deg C. ThO{sub 2} was also measured at 750 deg C. The neutron source was the reactor Rl, Stockholm. The experimental results presented as graphs in the report show in detail the influence of Bragg scattering. The results further show that the increase of the temperature for the ThO{sub 2} sample gives an increase in the cross-section. The work also contains some calculations of the position in energy of Bragg edges for the three materials. These calculations show a very good agreement with the experiments. For uranium metal some calculations have been carried out also for the height ({sigma}{sup g}{sub hkl}) of the edges The agreement with the experiments is reasonable.

  14. Acoustic absorption behaviour of an open-celled aluminium foam

    International Nuclear Information System (INIS)

    Han Fusheng; Seiffert, Gary; Zhao Yuyuan; Gibbs, Barry

    2003-01-01

    Metal foams, especially close-celled foams, are generally regarded as poor sound absorbers. This paper studies the sound absorption behaviour of the open-celled Al foams manufactured by the infiltration process, and the mechanisms involved. The foams show a significant improvement in sound absorption compared with close-celled Al foams, because of their high flow resistance. The absorption performance can be further enhanced, especially at low frequencies, if the foam panel is backed by an appropriate air gap. Increasing the air-gap depth usually increases both the height and the width of the absorption peak and shifts the peak towards lower frequencies. The foam samples with the smallest pore size exhibit the best absorption capacities when there is no air gap, whereas those with medium pore sizes have the best overall performance when there is an air gap. The typical maximum absorption coefficient, noise reduction coefficient and half-width of the absorption peak are 0.96-0.99, 0.44-0.62 and 1500-3500 Hz, respectively. The sound dissipation mechanisms in the open-celled foams are principally viscous and thermal losses when there is no air-gap backing and predominantly Helmholtz resonant absorption when there is an air-gap backing

  15. Detailed north-south cross section showing environments of deposition, organic richness, and thermal maturities of lower Tertiary rocks in the Uinta Basin, Utah

    Science.gov (United States)

    Johnson, Ronald C.

    2014-01-01

    The Uinta Basin of northeast Utah has produced large amounts of hydrocarbons from lower Tertiary strata since the 1960s. Recent advances in drilling technologies, in particular the development of efficient methods to drill and hydraulically fracture horizontal wells, has spurred renewed interest in producing hydrocarbons from unconventional low-permeability dolomite and shale reservoirs in the lacustrine, Eocene Green River Formation. The Eocene Green River Formation was deposited in Lake Uinta, a long-lived saline lake that occupied the Uinta Basin, the Piceance Basin to the east, and the intervening Douglas Creek arch. The focus of recent drilling activity has been the informal Uteland Butte member of the Green River Formation and to a much lesser extent the overlying R-0 oil shale zone of the Green River Formation. Initial production rates ranging from 500 to 1,500 barrels of oil equivalent per day have been reported from the Uteland Butte member from horizontal well logs that are as long as 4,000 feet (ft);. The cross section presented here extends northward from outcrop on the southern margin of the basin into the basin’s deep trough, located just south of the Uinta Mountains, and transects the area where this unconventional oil play is developing. The Monument Butte field, which is one of the fields located along this line of section, has produced hydrocarbons from conventional sandstone reservoirs in the lower part of the Green River Formation and underlying Wasatch Formation since 1981. A major fluvial-deltaic system entered Lake Uinta from the south, and this new line of section is ideal for studying the effect of the sediments delivered by this drainage on hydrocarbon reservoirs in the Green River Formation. The cross section also transects the Greater Altamont-Bluebell field in the deepest part of the basin, where hydrocarbons have been produced from fractured, highly overpressured marginal lacustrine and fluvial reservoirs in the Green River, Wasatch

  16. Restricted mass energy absorption coefficients for use in dosimetry

    International Nuclear Information System (INIS)

    Brahme, A.

    1977-02-01

    When matter is irradiated by a photon beam the fraction of energy absorbed locally in some region Rsub(Δ) (where the size of the region Rsub(Δ) is related to the range of secondary electrons of some restriction energy Δ) is expressed by the restricted mass energy absorption coefficient. In this paper an example is given of how restricted mass energy absorption coefficients can be calculated from existing differential photon interaction cross sections. Some applications of restricted mass absorption coefficients in dosimetry are also given. (B.D.)

  17. The effect of cholestyramine and activated charcoal on glipizide absorption.

    Science.gov (United States)

    Kivistö, K T; Neuvonen, P J

    1990-01-01

    1. The interference of cholestyramine and activated charcoal with the absorption of glipizide was studied. 2. In a cross-over study comprising three phases, single doses of cholestyramine (8 g), activated charcoal (8 g) or water only were given to six healthy volunteers together with a single dose of glipizide. 3. The absorption of glipizide was moderately (29%, P less than 0.01) reduced by cholestyramine and greatly reduced (81%, P less than 0.01) by activated charcoal. 4. If cholestyramine and glipizide are used concomitantly, glipizide should be taken 1-2 h beforehand. In acute glipizide overdosage, activated charcoal can be used to reduce absorption. PMID:2271372

  18. investigating water absorption and thickness swelling tendencies of ...

    African Journals Online (AJOL)

    HOD

    INVESTIGATING WATER ABSORPTION AND THICKNESS SWELLING TENDENCIES OF POLYMERIC COMPOSITE … O. Adekomaya & K. Adama. Nigerian Journal of Technology,. Vol. 37, No. 1, January 2018. 169. Table 2: Physical and thermal properties of epoxy resin materials (Adapted from manufacturer data sheet).

  19. Study of coupled heat and mass transfer during absorption of ...

    Indian Academy of Sciences (India)

    Mayer et al (1987) concluded from their numerical investigation that an excellent heat and mass transfer inside the reaction bed, good thermal contact of the bed material to the bed wall, and high external heat transfer coefficients were the important parameters to make the hydrogen absorption/desorption reaction efficient.

  20. Non-perturbative measurement of cross-field thermal diffusivity reduction at the O-point of 2/1 neoclassical tearing mode islands in the DIII-D tokamak

    Energy Technology Data Exchange (ETDEWEB)

    Bardóczi, L.; Rhodes, T. L.; Carter, T. A.; Crocker, N. A.; Peebles, W. A. [University of California Los Angeles, Los Angeles, California 90095 (United States); Grierson, B. A. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

    2016-05-15

    Neoclassical tearing modes (NTMs) often lead to the decrease of plasma performance and can lead to disruptions, which makes them a major impediment in the development of operating scenarios in present toroidal fusion devices. Recent gyrokinetic simulations predict a decrease of plasma turbulence and cross-field transport at the O-point of the islands, which in turn affects the NTM dynamics. In this paper, a heat transport model of magnetic islands employing spatially non-uniform cross-field thermal diffusivity (χ{sub ⊥}) is presented. This model is used to derive χ{sub ⊥} at the O-point from electron temperature data measured across 2/1 NTM islands in DIII-D. It was found that χ{sub ⊥} at the O-point is 1 to 2 orders of magnitude smaller than the background plasma transport, in qualitative agreement with gyrokinetic predictions. As the anomalously large values of χ{sub ⊥} are often attributed to turbulence driven transport, the reduction of the O-point χ{sub ⊥} is consistent with turbulence reduction found in recent experiments. Finally, the implication of reduced χ{sub ⊥} at the O-point on NTM dynamics was investigated using the modified Rutherford equation that predicts a significant effect of reduced χ{sub ⊥} at the O-point on NTM saturation.

  1. Thermal decomposition of ammonium hexachloroosmate

    DEFF Research Database (Denmark)

    Asanova, T I; Kantor, Innokenty; Asanov, I. P.

    2016-01-01

    Structural changes of (NH4)2[OsCl6] occurring during thermal decomposition in a reduction atmosphere have been studied in situ using combined energy-dispersive X-ray absorption spectroscopy (ED-XAFS) and powder X-ray diffraction (PXRD). According to PXRD, (NH4)2[OsCl6] transforms directly...

  2. Absorption heat pumps

    Science.gov (United States)

    Huhtinen, M.; Heikkilae, M.; Andersson, R.

    1987-03-01

    The aim of the study was to analyze the technical and economic feasibility of absorption heat pumps in Finland. The work was done as a case study: the technical and economic analyses have been carried out for six different cases, where in each the suitable size and type of the heat pump plant and the auxiliary components and connections were specified. The study also detailed the costs concerning the procurement, installation and test runs of the machinery, as well as the savings in energy costs incurred by the introduction of the plant. Conclusions were drawn of the economic viability of the applications studied. The following cases were analyzed: heat recovery from flue gases and productin of district heat in plants using peat, natural gas, and municipal wastes as a fuel. Heat recovery in the pulp and paper industry for the upgrading of pressure of secondary steam and for the heating of white liquor and combustion and drying the air. Heat recovery in a peat-fulled heat and power plant from flue gases that have been used for the drying of peat. According to the study, the absorption heat pump suits best to the production of district heat, when the heat source is the primary energy is steam produced by the boiler. Included in the flue as condensing is the purification of flue gases. Accordingly, benefit is gained on two levels in thick applications. In heat and power plants the use of absorption heat pumps is less economical, due to the fact that the steam used by the pump reduces the production of electricity, which is rated clearly higher than heat.

  3. Rapidly variable relatvistic absorption

    Science.gov (United States)

    Parker, M.; Pinto, C.; Fabian, A.; Lohfink, A.; Buisson, D.; Alston, W.; Jiang, J.

    2017-10-01

    I will present results from the 1.5Ms XMM-Newton observing campaign on the most X-ray variable AGN, IRAS 13224-3809. We find a series of nine absorption lines with a velocity of 0.24c from an ultra-fast outflow. For the first time, we are able to see extremely rapid variability of the UFO features, and can link this to the X-ray variability from the inner accretion disk. We find a clear flux dependence of the outflow features, suggesting that the wind is ionized by increasing X-ray emission.

  4. Geospatial Absorption and Regional Effects

    Directory of Open Access Journals (Sweden)

    IOAN MAC

    2009-01-01

    Full Text Available The geospatial absorptions are characterized by a specific complexity both in content and in their phenomenological and spatial manifestation fields. Such processes are differentiated according to their specificity to pre-absorption, absorption or post-absorption. The mechanisms that contribute to absorption are extremely numerous: aggregation, extension, diffusion, substitution, resistivity (resilience, stratification, borrowings, etc. Between these mechanisms frequent relations are established determining an amplification of the process and of its regional effects. The installation of the geographic osmosis phenomenon in a given territory (a place for example leads to a homogenization of the geospatial state and to the installation of the regional homogeneity.

  5. Absorptive form factors for high-energy electron diffraction

    International Nuclear Information System (INIS)

    Bird, D.M.; King, Q.A.

    1990-01-01

    The thermal diffuse scattering contribution to the absorptive potential in high-energy electron diffraction is calculated in the form of an absorptive contribution to the atomic form factor. To do this, the Einstein model of lattice vibrations is used, with isotropic Debye-Waller factors. The absorptive form factors are calculated as a function of scattering vector s and temperature factor M on a grid which enables polynomial interpolation of the results to be accurate to better than 2% for much of the ranges 0≤Ms 2 ≤6 and 0≤M≤2 A 2 . The computed values, together with an interpolation routine, have been incorporated into a Fortran subroutine which calculates both the real and absorptive form factors for 54 atomic species. (orig.)

  6. X-ray absorption spectroscopy: EXAFS [Extended X-ray Absorption Fine Structure] and XANES [X-ray Absorption Near Edge Structure

    International Nuclear Information System (INIS)

    Alp, E.E.; Mini, S.M.; Ramanathan, M.

    1990-04-01

    The x-ray absorption spectroscopy (XAS) had been an essential tool to gather spectroscopic information about atomic energy level structure in the early decades of this century. It has also played an important role in the discovery and systematization of rare-earth elements. The discovery of synchrotron radiation in 1952, and later the availability of broadly tunable synchrotron based x-ray sources have revitalized this technique since the 1970's. The correct interpretation of the oscillatory structure in the x-ray absorption cross-section above the absorption edge by Sayers et. al. has transformed XAS from a spectroscopic tool to a structural technique. EXAFS (Extended X-ray Absorption Fine Structure) yields information about the interatomic distances, near neighbor coordination numbers, and lattice dynamics. An excellent description of the principles and data analysis techniques of EXAFS is given by Teo. XANES (X-ray Absorption Near Edge Structure), on the other hand, gives information about the valence state, energy bandwidth and bond angles. Today, there are about 50 experimental stations in various synchrotrons around the world dedicated to collecting x-ray absorption data from the bulk and surfaces of solids and liquids. In this chapter, we will give the basic principles of XAS, explain the information content of essentially two different aspects of the absorption process leading to EXAFS and XANES, and discuss the source and samples limitations

  7. The kinetics of Cr layer coated on TiNi films for hydrogen absorption

    Indian Academy of Sciences (India)

    pressure by thermal evaporation on the glass substrate at room temperature. A layer of. Cr of thickness 100 Å was coated on the TiNi thin films. The changing rate of hydrogen absorption increases after Cr layer coating because Cr enhances the catalytic properties of hydrogen absorption in thin films. The rate of hydrogen ...

  8. The absorption spectrum of cis-azobenzene.

    Science.gov (United States)

    Vetráková, Ľubica; Ladányi, Vít; Al Anshori, Jamaludin; Dvořák, Pavel; Wirz, Jakob; Heger, Dominik

    2017-12-06

    Azobenzene is a prototypical photochromic molecule existing in two isomeric forms, which has numerous photochemical applications that rely on a precise knowledge of the molar absorption coefficients (ε). Careful analysis revealed that the previously reported absorption spectra of the "pure" isomers were in fact mutually contaminated by small amounts of the other isomer. Therefore, the absorption spectra of both trans- and cis-azobenzene in methanol were re-determined at temperatures of 5-45 °C. The thermodynamically more stable trans-azobenzene was prepared by warming the solution in the dark. To obtain the spectrum of cis-azobenzene three methods were used, which gave consistent results within the limits of error. The method based on the subtraction of derivative spectra coupled with a global analysis of the spectra recorded during thermal cis-trans isomerization is shown to give slightly more reliable results than the method using isomeric ratios determined by 1 H-NMR. The described methods are readily generalizable to other azobenzene derivatives and to other photochromic systems. The practical implication of the re-determined ε values is demonstrated by a very high precision of spectrophotometric species analysis in azobenzene isomeric mixtures. The new ε values imply that the previously reported quantum yields must be revised.

  9. THERMAL: A routine designed to calculate neutron thermal scattering

    International Nuclear Information System (INIS)

    Cullen, D.E.

    1995-01-01

    THERMAL is designed to calculate neutron thermal scattering that is isotropic in the center of mass system. At low energy thermal motion will be included. At high energies the target nuclei are assumed to be stationary. The point of transition between low and high energies has been defined to insure a smooth transition. It is assumed that at low energy the elastic cross section is constant in the center of mass system. At high energy the cross section can be of any form. You can use this routine for all energies where the elastic scattering is isotropic in the center of mass system. In most materials this will be a fairly high energy

  10. MULTIMAGNON ABSORPTION IN MNF2-OPTICAL ABSORPTION SPECTRUM.

    Science.gov (United States)

    The absorption spectrum of MnF2 at 4.2K in the 3900A region was measured in zero external fields and in high fields. Exciton lines with magnon ...sidebands are observed, accompanied by a large number of weak satellite lines. Results on the exciton and magnon absorptions are similar to those of...McClure et al. The satellite lines are interpreted as being multi- magnon absorptions, and it is possible to fit the energy of all the absorptions with

  11. Analyzing Water's Optical Absorption

    Science.gov (United States)

    2002-01-01

    A cooperative agreement between World Precision Instruments (WPI), Inc., and Stennis Space Center has led the UltraPath(TM) device, which provides a more efficient method for analyzing the optical absorption of water samples at sea. UltraPath is a unique, high-performance absorbance spectrophotometer with user-selectable light path lengths. It is an ideal tool for any study requiring precise and highly sensitive spectroscopic determination of analytes, either in the laboratory or the field. As a low-cost, rugged, and portable system capable of high- sensitivity measurements in widely divergent waters, UltraPath will help scientists examine the role that coastal ocean environments play in the global carbon cycle. UltraPath(TM) is a trademark of World Precision Instruments, Inc. LWCC(TM) is a trademark of World Precision Instruments, Inc.

  12. Atomic absorption spectrometry

    International Nuclear Information System (INIS)

    Haswell, S.J.

    1991-01-01

    Atomic absorption spectroscopy is now well established and widely used technique for the determination of trace and major elements in a wide range analyte types. There have been many advances in the atomic spectroscopy over the last decade and for this reason and to meet the demand, it was felt that there was a need for an updated book. Whilst interest in instrumental design has tended to dominate the minds of the spectrocopist, the analyst concerned with obtaining reliable and representative data, in diverse areas of application, has been diligently modifying and developing sample treatment and instrumental introduction techniques. Such methodology is de fundamental part of analysis and form the basis of the fourteen application chapters of this book. The text focuses in the main on AAS; however, the sample handling techniques described are in many cases equally applicable to ICP-OES and ICP-MS analysis. (author). refs.; figs.; tabs

  13. Aerosol light absorption and its measurement: A review

    International Nuclear Information System (INIS)

    Moosmueller, H.; Chakrabarty, R.K.; Arnott, W.P.

    2009-01-01

    from the thermal radiation emitted by the heated particles. Extinction-minus-scattering techniques have limited sensitivity for measuring aerosol light absorption unless the very long absorption paths of cavity ring-down techniques are used. Systematic errors can be dominated by truncation errors in the scattering measurement for large particles or by subtraction errors for high single scattering albedo particles. Remote sensing techniques are essential for global monitoring of aerosol light absorption. While local column-integrated measurements of aerosol light absorption with sun and sky radiometers are routinely done, global satellite measurements are so far largely limited to determining a semi-quantitative UV absorption index.

  14. comparative study of thermal insulation boards from leaf and bark ...

    African Journals Online (AJOL)

    HOD

    environmentally friendly thermal insulation products. The aim of this study was to compare the performance of insulation boards made from leave and bark fibres of Piliostigma thonningii L.in terms of density, water absorption, apparent thermal conductivity, specific heat and thermal diffusivity. The leave and the bark fibres ...

  15. Nonlinear effects in collective absorption

    International Nuclear Information System (INIS)

    Uenoyama, Takeshi; Mima, Kunioki; Watanabe, Tsuguhiro.

    1981-01-01

    The collective absorption of high intensity laser radiation is analyzed numerically. Density profile modification due to the ponderomotive force associating laser radiation and the excited electron plasma waves is self-consistently taken into account, and the intensity dependences of the absorption efficiency are obtained. In the high intensity regime, the absorption efficiency is found to be strongly enhanced in the plasma without flow, but reduced with supersonic flow. (author)

  16. Atomic absorption spectrophotometry in perspective

    International Nuclear Information System (INIS)

    Soffiantini, V.

    1981-01-01

    Atomic absorption spectrophotometry is essentially an analytical technique used for quantitative trace metal analysis in a variety of materials. The speed and specificity of the technique is its greatest advantage over other analytical techniques. What atomic absorption spectrophotometry can and cannot do and its advantages and disadvantages are discussed, a summary of operating instructions are given, as well as a summary of analytical interferences. The applications of atomic absorption spectrophotometry are also shortly discussed

  17. Thermal Energy Storage in Phase Change Material.

    Science.gov (United States)

    1982-03-01

    Graphs of the exnerimental results follow: tney are groupea in the tree categories: tube cross flow, ricked bed, and tube parallel flow. A. Tube Cross... Riordan , Michael, "Thermal Storage: A Rtsic Guile to the Ptate of the Art", Solar Age, Aril, 1978, P. 10. 5. Telkes, Maria, "Thermal Lner y Storage in

  18. ENDF/B Thermal Data Testing

    CERN Document Server

    McCrosson, F J

    2001-01-01

    The thermal data testing group is concerned with establishing the merit of ENDF/B cross sections for the analysis of thermal systems. The integral experiments used in the testing are designed to analyze each of the phenomena identified in the familiar four-factor formula. For brevity, only the testing of the cross sections in uranium systems is described in this report.

  19. Study on preparation and microwave absorption property of the core-nanoshell composite materials doped with La.

    Science.gov (United States)

    Wei, Liqiu; Che, Ruxin; Jiang, Yijun; Yu, Bing

    2013-12-01

    Microwave absorbing material plays a great role in electromagnetic pollution controlling, electromagnetic interference shielding and stealth technology, etc. The core-nanoshell composite materials doped with La were prepared by a solid-state reaction method, which is applied to the electromagnetic wave absorption. The core is magnetic fly-ash hollow cenosphere, and the shell is the nanosized ferrite doped with La. The thermal decomposition process of the sample was investigated by thermogravimetry and differential thermal analysis. The morphology and components of the composite materials were investigated by the X-ray diffraction analysis, the microstructure was observed by scanning electron microscope and transmission electron microscope. The results of vibrating sample magnetometer analysis indicated that the exchange-coupling interaction happens between ferrite of magnetic fly-ash hollow cenosphere and nanosized ferrite coating, which caused outstanding magnetic properties. The microwave absorbing property of the sample was measured by reflectivity far field radar cross section of radar microwave absorbing material with vector network analyzer. The results indicated that the exchange-coupling interaction enhanced magnetic loss of composite materials. Therefore, in the frequency of 5 GHz, the reflection coefficient can achieve -24 dB. It is better than single material and is consistent with requirements of the microwave absorbing material at the low-frequency absorption. Copyright © 2013 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.

  20. X-ray Absorption Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Yano, Junko; Yachandra, Vittal K.

    2009-07-09

    This review gives a brief description of the theory and application of X-ray absorption spectroscopy, both X-ray absorption near edge structure (XANES) and extended X-ray absorption fine structure (EXAFS), especially, pertaining to photosynthesis. The advantages and limitations of the methods are discussed. Recent advances in extended EXAFS and polarized EXAFS using oriented membranes and single crystals are explained. Developments in theory in understanding the XANES spectra are described. The application of X-ray absorption spectroscopy to the study of the Mn4Ca cluster in Photosystem II is presented.

  1. Thermal comfort

    CSIR Research Space (South Africa)

    Osburn, L

    2010-01-01

    Full Text Available wider range of temperature limits, saving energy while still satisfying the majority of building occupants. It is also noted that thermal comfort varies significantly between individuals and it is generally not possible to provide a thermal environment...

  2. Absorption of a Massive Scalar Field by Wormhole Space-Times

    Science.gov (United States)

    Huang, Hai; Chen, Juhua; Wang, Yongjiu; Jin, Yao

    2017-04-01

    In this paper we consider the problem of the test massive scalar field propagating in the background of a class of wormhole space-times. Basing on the quantum scattering theory, we analyze the Schrödinger-type scalar wave equation and compute transmission coefficients for arbitrary coupling of the field to the background geometry with the WKB approximation. We numerically investigate its absorption cross section and analyze them in the high frequency regime. We find that the absorption cross section oscillates about the geometric optical value and the limit of absorption cross section is uniform in the high frequency regime.

  3. Investigation of thermal stability and spectroscopic properties in Er3+ doped bismuth-boron-germanium glasses

    International Nuclear Information System (INIS)

    Nie Qiuhua; Lu Longjun; Dai Shixun; Xu Tiefeng; Shen Xiang; Zhang Xudong; Liang Xiaowei; Zhang Xianghua

    2007-01-01

    A series of Er 3+ -doped 50Bi 2 O 3 -(50-x)B 2 O 3 -xGeO 2 +0.5 wt% Er 2 O 3 (x=0, 5, 10, 15, 20 mol%) glasses were prepared. The thermal stability, absorption spectra, emission spectra and lifetime of the 4 I 13 / 2 level of Er 3+ ions were measured and studied. It is found that the absorption cross-section of Er 3+ , emission intensity and lifetime of the 4 I 13 / 2 level of Er 3+ increase with increasing GeO 2 content in the glass composition, while the fluorescence full-width at half-maximum (FWHM) at 1.5 μm of Er 3+ is about 79 nm in x=20 mol% glass sample under 970 nm pump. The obtained data suggest that this system glass can be used as a candidate host material for potential broadband optical amplifiers

  4. Absorption and emission properties of photonic crystals and metamaterials

    International Nuclear Information System (INIS)

    Peng, Lili

    2007-01-01

    We study the emission and absorption properties of photonic crystals and metamaterials using Comsol Multiphysics and Ansoft HFSS as simulation tools. We calculate the emission properties of metallic designs using drude model and the results illustrate that an appropriate termination of the surface of the metallic structure can significantly increase the absorption and therefore the thermal emissivity. We investigate the spontaneous emission rate modifications that occur for emitters inside two-dimensional photonic crystals and find the isotropic and directional emissions with respect to different frequencies as we have expected.

  5. Phytases for improved iron absorption

    DEFF Research Database (Denmark)

    Nielsen, Anne Veller Friis; Meyer, Anne S.

    2016-01-01

    Phytase enzymes present an alternative to iron supplements, because they have been shown to improve iron absorption by means of catalysing the degradation of a potent iron absorption inhibitor: phytic acid. Phytic acid is a hexaphosphate of inositol and is particularly prevalent in cereal grains...

  6. Atomic absorption instrument functional description

    International Nuclear Information System (INIS)

    Bystroff, R.I.; Boyle, W.G. Jr.; Barton, G.W. Jr.

    1976-01-01

    This report describes a proposed system for automating atomic absorption analysis. The system consists of two atomic absorption instruments and an automatic sampler that can be attached to either instrument. A computer program controls the sampling and gathers data. The program then uses the data to perform bookkeeping, data processing, and report writing

  7. Optical absorption of irradiated carbohydrates

    International Nuclear Information System (INIS)

    Supe, A.A.; Tiliks, Yu.E.

    1994-01-01

    The optical absorption spectra of γ-irradiated carbohydrates (glucose, lactose, sucrose, maltose, and starch) and their aqueous solutions were studied. The comparison of the data obtained with the determination of the concentrations of molecular and radical products of radiolysis allows the absorption bands with maxima at 250 and 310 nm to be assigned to the radicals trapped in the irradiated carbohydrates

  8. Water absorption in brick masonry

    NARCIS (Netherlands)

    Brocken, H.J.P.; Smolders, H.R.

    1996-01-01

    The water absorption in brick, mortar that was cured separately, and masonry samples was studied using NMR. Models of the moisture transport are usually formulated on the basis of a diffusion equation. In the case of water absorption in separate brick and mortar samples, the moisture diffusivity in

  9. Atmospheric absorption of sound - Update

    Science.gov (United States)

    Bass, H. E.; Sutherland, L. C.; Zuckerwar, A. J.

    1990-01-01

    Best current expressions for the vibrational relaxation times of oxygen and nitrogen in the atmosphere are used to compute total absorption. The resulting graphs of total absorption as a function of frequency for different humidities should be used in lieu of the graph published earlier by Evans et al (1972).

  10. Intestinal Absorption of Thyroid Hormone

    NARCIS (Netherlands)

    N. Kelderman-Bolk (Nienke)

    2015-01-01

    textabstractIn this thesis the treatment of hypothyroidism and absorption of T4 is described from a clinical and basic point of view. Put together the thesis gives insight in the factors influencing LT4 absorption and its results have influenced the timing of LT4 intake.

  11. Thermal radiation antennas made of multilayer structures containing negative index metamaterials

    NARCIS (Netherlands)

    Maksimovic, Milan; Hammer, Manfred; Jaksic, Z.; Greiner, C.M.; Waechter, C.A.

    2008-01-01

    We investigate the thermal antenna behavior of emissive/absorptive substrates coated by passive optical multilayer systems that contain negative refractive index metamaterials (NIM). Spectral and angular distributions of the thermal radiation emittance for periodic defect-containing multilayer with

  12. Optical absorption of silicon nanowires

    International Nuclear Information System (INIS)

    Xu, T.; Lambert, Y.; Krzeminski, C.; Grandidier, B.; Stiévenard, D.; Lévêque, G.; Akjouj, A.; Pennec, Y.; Djafari-Rouhani, B.

    2012-01-01

    We report on simulations and measurements of the optical absorption of silicon nanowires (NWs) versus their diameter. We first address the simulation of the optical absorption based on two different theoretical methods: the first one, based on the Green function formalism, is useful to calculate the scattering and absorption properties of a single or a finite set of NWs. The second one, based on the finite difference time domain (FDTD) method, is well-adapted to deal with a periodic set of NWs. In both cases, an increase of the onset energy for the absorption is found with increasing diameter. Such effect is experimentally illustrated, when photoconductivity measurements are performed on single tapered Si nanowires connected between a set of several electrodes. An increase of the nanowire diameter reveals a spectral shift of the photocurrent intensity peak towards lower photon energies that allow to tune the absorption onset from the ultraviolet radiations to the visible light spectrum.

  13. Absorption coefficients for water vapor at 193 nm from 300 to 1073 K

    Science.gov (United States)

    Kessler, W. J.; Carleton, K. L.; Marinelli, W. J.

    1993-01-01

    Measurements of the water absorption coefficient at 193 nm from 300 to 1073 K are reported. The measurements were made using broadband VUV radiation and a monochromator-based detection system. The water vapor was generated by a saturator and metered into a flowing, 99 cm absorption cell via a water vapor mass flow meter. The 193 nm absorption coefficient measurements are compared to room temperature and high temperature shock tube measurements with good agreement. The absorption can be parameterized by a nu3 vibrational mode reaction coordinate and the thermal population of the nu3 mode.

  14. Role of quasideuteron absorption in the 6Li(π+,pp) reaction at Tπ+=100, 165 MeV

    International Nuclear Information System (INIS)

    Lolos, G.J.; Huber, G.M.; Mathie, E.L.; Naqvi, S.I.; Papandreou, Z.; Ottewell, D.F.; Walden, P.L.; Jones, G.; Aslanoglou, X.; Visschers, J.L.

    1996-01-01

    Differential and total cross sections for π + absorption on 6 Li, leading to the pp+ 4 He g.s. , pp+ 4 He * , and pp+X final states, are presented at incident pion energies of 100 and 165 MeV. We conclude that most of the cross section is confined to the level of coplanarity expected from quasideuteron absorption in the nuclear environment and that the contributions of nonquasideuteron absorption mechanisms are small. copyright 1996 The American Physical Society

  15. Thermionic detection of the ionic fragments of continiuum-state pair absorption systems

    International Nuclear Information System (INIS)

    Hotop, R.; Niemax, K.; Richter, J.; Weber, K.H.

    1981-01-01

    Using a thermionic diode we have detected the ionic fragments formed by associative ionization and dissociation after continuum-state pair absorption processes in Cs-Cs and Cs-K systems. Assuming an ionization probability of unity of the excited species and calibrating the pair absorption bands by taking into account the known photoionization cross section of the atoms we found excellent agreement with data from classical absorption measurements. (orig.)

  16. Manipulation of enhanced absorption with tilted hexagonal boron nitride slabs

    Science.gov (United States)

    Wu, Xiaohu; Fu, Ceji

    2018-04-01

    The wavevector of electromagnetic wave propagation in a hexagonal boron nitride (hBN) slab can be controlled by tilting its optical axis. This property can be used to manipulate the absorption in a hBN slab. By carefully analyzing the dependence of the absorptivity of a thin hBN slab on the tilted angle of its optical axis, we propose a structure that can realize great absorptivity enhancement in a band by stacking hBN slabs of different tilted angles. Our numerical results show that the absorptivity of a structure made of 91 stacked hBN slabs can be achieved higher than 0.94 in the wavenumber range from 1367 to 1580 cm-1 when the tilted angles of the slabs are properly arranged. The strong absorption is attributed to the combination of impedance matching at the slab interfaces and enlarged wavevectors in the slabs. This work reveals a novel way to realize strong absorption with anisotropic materials for applications in areas such as thermal radiative energy harvesting and conversion.

  17. Effect of Mixing State on the Optical Absorption by Black Carbon Containing Particles

    Science.gov (United States)

    Onasch, T. B.; Cappa, C. D.; Forestieri, S.; Lambe, A. T.; Massoli, P.; Olfert, J. S.; Ghazi, R.; Sedlacek, A. J.; Lewis, E. R.; Croasdale, D.; Cummings, M.; Martin, A.; Freedman, A.; Worsnop, D. R.; Davidovits, P.

    2012-12-01

    The positive radiative forcing of black carbon (BC) aerosols may be as large as that of CO2 but remains highly uncertain. Modeling and laboratory studies show that BC-containing aerosols exhibit light absorption enhancements (Eabs) by as much as a factor of two relative to uncoated BC, due to a lensing effect; this effect has been incorporated into several global climate models. Yet contrary to expectations, recent field measurements during NOAA CalNex 2010 and DOE CARES 2010 report low Eabs (coated by hydrophobic dioctyl sebacate (DOS) or hydrophilic sulfuric acid, was conducted as a function of coating thickness and relative humidity. Following coating and size-selection, aerosol mass distributions, size distributions, and mass spectra were measured with a centrifugal particle mass analyzer (CPMA), scanning mobility particle sizer (SMPS), and a soot particle - aerosol mass spectrometer (SP-AMS). Aerosol absorption and extinction were measured with a cavity ring down - photoacoustic aerosol spectrometer (CRD-PAS), and a cavity attenuated phase shift (CAPS) monitor. Eabs was derived as the ratio of absorption cross-sections of coated soot relative to thermally denuded soot. The Eabs of DOS-coated soot increased as a function of coating thickness and were consistent with the Mie theory "core-shell" model. In contrast, as the thickness of sulfuric acid coating and relative humidity were systematically varied we observed enhancements that were significantly lower than the theoretical predictions, similar to that observed in the field measurements. Our measurements suggest this suppressed Eabs may arise from morphological changes and/or phase separations incurred within BC-containing particles for hydrophilic coatings influenced by water vapor.

  18. Design of a thermal waist-pad

    Science.gov (United States)

    Kursun Bahadir, S.; Sahin, U. K.; Acikgoz Tufan, H.

    2017-10-01

    The objective of the current study is designing a thermal waist-pad for people who have backaches with a sandwich-like multi-layered structure. Two model is developed; one is three-layered and second is five-layered with waterproof woven outer layer fabric, Thermolite® knitted fabric (for five-layered structures), wool knitted, polyester nonwoven fabric, polypropylene nonwoven fabric and viscose nonwoven fabric for mid-layer. 10 different structures are designed and produced. All samples are tested for thermal comfort properties of waist-pad. Multi-layer structures were tested, and according to their thermal performance and thermal comfort criteria, all results are evaluated for identifying the best product. These three factors are examined by analysis of thermal conductivity, thermal resistance, thermal absorptivity, relative water vapour/air permeability, water absorption. Highest thermal resistance test result, 150,42 mK/Wm2, is achieved in five-layered sandwich structure with waterproof fabric, Thermolite® fabric, wool based knitted fabric, Thermolite® fabric and waterproof fabric, respectively. Thermal conductivity result of this structure is 46,2 mW/mK, which is one of the lowest results among the alternative structures. Structures with Thermolite® fabric show higher thermal comfort when compared to others.

  19. Scattering and absorption differential cross sections for double ...

    Indian Academy of Sciences (India)

    as double photon Compton scattering have been measured as a function of independent final photon energy. ... of a brass pipe and fitted with aluminium windows on both the ends can be filled with a column of mercury ... thick iron and 1 mm thick aluminium, with iron facing lead to absorb K x-rays emitted by lead shielding.

  20. Epigallocatechin gallate (EGCG) (TEAVIGO™) does not impair nonhaem-iron absorption in man

    NARCIS (Netherlands)

    Ullmann, U.; Haller, J.; Bakker, G.C.M.; Brink, E.J.; Weber, P.

    2005-01-01

    A number of studies have shown that tea catechins can inhibit intestinal iron absorption, mostly iron in the nonhaem form. This randomized, double-blind, placebo-controlled, 3-periods cross-over study examined the degree of inhibition of nonhaem iron absorption by pure crystalline epigallocatechin

  1. Far-wing light absorption induced by resonant or near-resonant collisions

    International Nuclear Information System (INIS)

    Cavalieri, S.; Celli, M.

    1996-01-01

    The authors have studied the absorption of light induced by a resonant or near-resonant collision between two atoms. The calculations have been performed by taking into account also the magnetic sublevels, which makes their theoretical predictions more applicable to realistic cases. Analytical expressions for the far-wing absorption cross-section have been obtained

  2. Absorption of hydrogen in vanadium, enhanced by ion bombardment; Ionenbeschussunterstuetzte Absorption des Wasserstoffs in Vanadium

    Energy Technology Data Exchange (ETDEWEB)

    Paulus, H.; Lammers, M. [Inst. fuer Technologie- und Wissenstransfer, Soest (Germany); Mueller, K.H. [Inst. fuer Technologie- und Wissenstransfer, Soest (Germany)]|[Paderborn Univ. (Gesamthochschule), Soest (Germany). Fachbereich 16 - Elektrische Energietechnik; Kiss, G.; Kemeny, Z. [Technical Univ. Budapest (Hungary)

    1998-12-31

    Prior to hydrogen implantation into vanadium, the vanadium specimen usually is exposed to an activation process and is then heated at 1 atm hydrogen to temperatures between 500 and 600 C, subsequently cooled down in several steps. Within this temperature range, hydrogen solubility increases with declining temperature. A decisive factor determining hydrogen absorption is the fact that at temperatures above 250 C, oxygen desorbs from the material surface and thus no longer inhibits hydrogen absorption. Therefore a different approach was chosen for the experiments reported: Hydrogen absorption under UHV conditions at room temperature. After the usual activation process, the vanadium surface was cleaned by 5 keV Ar{sup +} ion bombardment. Thus oxygen absorption at the specimen surface (and new reactions with oxygen from the remaining gas) could be avoided, or removed. By means of thermal desorption mass spectrometry (TDMS), hydrogen absorption as a function of argon ion dose was analysed. TDMS measurements performed for specimens treated by ion bombardment prior to H{sup 2} exposure showed two H{sup 2} desorption peaks, in contrast to the profiles measured with specimens not exposed to ion bombardment. It is assumed that the ion bombardment disturbs the crystal structure so that further sites for hydrogen absorption are produced. (orig./CB) [Deutsch] Bei der Beladung von Vandium mit Wasserstoff wird ueblicherweise die Probe nach einer Aktivierungsprozedur bei 1 atm Wasserstoff auf Temperaturen im Bereich von 500 bis 600 C hochgeheizt und danach schrittweise abgekuehlt. In diesem Temperaturbereich nimmt die Wasserstoffloeslichkeit mit abnehmender Temperatur zu. Entscheidend fuer die Beladung ist aber auch die Tatsache, dass bei Temperaturen groesser 250 C Sauerstoff von der Oberflaeche desorbiert und dadurch die Absorption von Wasserstoff nicht mehr blockieren kann. Im Rahmen der hier beschriebenen Untersuchungen sollte die Wasserstoffbeladung unter UHV-Bedingungen bei

  3. Subgap Absorption in Conjugated Polymers

    Science.gov (United States)

    Sinclair, M.; Seager, C. H.; McBranch, D.; Heeger, A. J; Baker, G. L.

    1991-01-01

    Along with X{sup (3)}, the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter which will ultimately determine the utility of conjugated polymers in active integrated optical devices. With an absorptance sensitivity of materials. We have used PDS to measure the optical absorption spectra of the conjugated polymers poly(1,4-phenylene-vinylene) (and derivitives) and polydiacetylene-4BCMU in the spectral region from 0.55 eV to 3 eV. Our spectra show that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1 cm{sup {minus}1} to 10 cm{sup {minus}1}. In the region below 1 eV, overtones of C-H stretching modes were observed, indicating that further improvements in transparency in this spectral region might be achieved via deuteration of fluorination.

  4. Sabine absorption coefficients to random incidence absorption coefficients

    DEFF Research Database (Denmark)

    Jeong, Cheol-Ho

    2014-01-01

    into random incidence absorption coefficients for porous absorbers are investigated. Two optimization-based conversion methods are suggested: the surface impedance estimation for locally reacting absorbers and the flow resistivity estimation for extendedly reacting absorbers. The suggested conversion methods...

  5. Performance of direct absorption solar collector with nanofluid mixture

    International Nuclear Information System (INIS)

    Turkyilmazoglu, Mustafa

    2016-01-01

    Highlights: • Neat approximations for temperature and solar collector efficiency are presented. • The non-adiabatic and isothermal base mechanisms optimize the surface absorption. • Heat transferring material at the bottom panel enhances the thermal efficiency. • Isothermal base panel leads to maximum thermal efficiency of the solar receiver. - Abstract: The enhancement of performance by increasing the thermal efficiency of a direct absorption solar collector based on an alumina–water nanofluid is the prime target of the present research. The base panel of the collector channel is subject to either a non adiabatic or an isothermal wall condition both of which introduce two new physical parameters. Analytical solutions for the temperature field are worked out in both cases for a two dimensional steady-state model recently outlined in the literature. The desired increase in the temperature of the heat transferring nanofluid is achieved either by slightly rising the heat transfer coefficient of the bottom panel coating or by prescribing a bottom surface temperature. As a consequence of the increase in the final outlet mean temperature, the solar collector thermal efficiency is found to be enhanced via increasing the new physical parameters as compared to the traditional adiabatic wall case. For instance, 85.63% thermal efficiency of solar collector is achievable for non adiabatic bottom panel by adding suspended aluminum nanoparticles into the pure water. Even better than this, considering isothermal base panels, 100% efficiency is attained more rapidly with lesser base temperatures in the presence of higher nanoparticle volume fractions.

  6. Absorption factor for cylindrical samples

    International Nuclear Information System (INIS)

    Sears, V.F.

    1984-01-01

    The absorption factor for the scattering of X-rays or neutrons in cylindrical samples is calculated by numerical integration for the case in which the absorption coefficients of the incident and scattered beams are not equal. An extensive table of values having an absolute accuracy of 10 -4 is given in a companion report [Sears (1983). Atomic Energy of Canada Limited, Report No. AECL-8176]. In the present paper an asymptotic expression is derived for the absorption factor which can be used with an error of less than 10 -3 for most cases of interest in both neutron inelastic scattering and neutron diffraction in crystals. (Auth.)

  7. Thermal Stress

    Science.gov (United States)

    2011-01-01

    and Science in Sports and Exercise 37: 1328--1334. Coris EE, Ramirez AM, and Van Durme DJ (2004) Heat illness in athletes : The dangerous combination...of heat, humidity and exercise. Sports Medicine 34: 9--16. Gordon CJ and Leon LR (2005) Thermal stress and the physiological response to environmental...code) 2011 Book Chapter-Enc. of Environmental Health Thermal Stress L.R. Leon, C.J. Gordon Thermal and Mountain Medicine Division U.S. Research

  8. Patterning of graphite nanocones for broadband solar spectrum absorption

    Directory of Open Access Journals (Sweden)

    Yaoran Sun

    2015-06-01

    Full Text Available We experimentally demonstrate a broadband vis-NIR absorber consisting of 300-400 nm nanocone structures on highly oriented pyrolytic graphite. The nanocone structures are fabricated through simple nanoparticle lithography process and analyzed with three-dimensional finite-difference time-domain methods. The measured absorption reaches an average level of above 95% over almost the entire solar spectrum and agrees well with the simulation. Our simple process offers a promising material for solar-thermal devices.

  9. Code for three dimensional analysis of thermal birefringence in solid-state lasers

    International Nuclear Information System (INIS)

    Furukawa, Hiroyuki; Yamanaka, Chiyoe; Hiura, Norimitsu; Matsui, Hiroki; Yoshida, Takuji; Kiriyama, Hiromitsu; Yamanaka, Masanobu; Izawa, Yasukazu; Nakai, Sadao

    1999-01-01

    A three dimensional (3D) analysis code of thermal birefringence in solid-state lasers was developed. Basic equations include thermal conduction, absorption of laser energy, thermal stress and thermal birefringence. Relative phase shifts induced by thermal effects measured and obtained by simulation are in good agreement with quantitatively. Edge effects of thermal birefringence are quantitatively estimated by 3D simulation. Those are unable to be estimated by 2D analysis. (author)

  10. Diagnostic potential of cosmic-neutrino absorption spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Barenboim, Gabriela; /Valencia U.; Mena Requejo, Olga; Quigg, Chris; /Fermilab

    2004-12-01

    Annihilation of extremely energetic cosmic neutrinos on the relic-neutrino background can give rise to absorption lines at energies corresponding to formation of the electroweak gauge boson Z{sup 0}. The positions of the absorption dips are set by the masses of the relic neutrinos. Suitably intense sources of extremely energetic (10{sup 21} - 10{sup 25}-eV) cosmic neutrinos might therefore enable the determination of the absolute neutrino masses and the flavor composition of the mass eigenstates. Several factors--other than neutrino mass and composition--distort the absorption lines, however. We analyze the influence of the time-evolution of the relic-neutrino density and the consequences of neutrino decay. We consider the sensitivity of the lineshape to the age and character of extremely energetic neutrino sources, and to the thermal history of the Universe, reflected in the expansion rate. We take into account Fermi motion arising from the thermal distribution of the relic-neutrino gas. We also note the implications of Dirac vs. Majorana relics, and briefly consider unconventional neutrino histories. We ask what kinds of external information would enhance the potential of cosmic-neutrino absorption spectroscopy, and estimate the sensitivity required to make the technique a reality.

  11. Overview of thermal conductivity models of anisotropic thermal insulation materials

    Science.gov (United States)

    Skurikhin, A. V.; Kostanovsky, A. V.

    2017-11-01

    Currently, the most of existing materials and substances under elaboration are anisotropic. It makes certain difficulties in the study of heat transfer process. Thermal conductivity of the materials can be characterized by tensor of the second order. Also, the parallelism between the temperature gradient vector and the density of heat flow vector is violated in anisotropic thermal insulation materials (TIM). One of the most famous TIM is a family of integrated thermal insulation refractory material («ITIRM»). The main component ensuring its properties is the «inflated» vermiculite. Natural mineral vermiculite is ground into powder state, fired by gas burner for dehydration, and its precipitate is then compressed. The key feature of thus treated batch of vermiculite is a package structure. The properties of the material lead to a slow heating of manufactured products due to low absorption and high radiation reflection. The maximum of reflection function is referred to infrared spectral region. A review of current models of heat propagation in anisotropic thermal insulation materials is carried out, as well as analysis of their thermal and optical properties. A theoretical model, which allows to determine the heat conductivity «ITIRM», can be useful in the study of thermal characteristics such as specific heat capacity, temperature conductivity, and others. Materials as «ITIRM» can be used in the metallurgy industry, thermal energy and nuclear power-engineering.

  12. Theoretical calculation of saturated absorption for multilevel atoms

    International Nuclear Information System (INIS)

    O'Kane, T.J.; Scholten, R.E.; Farrell, P.M.

    1998-01-01

    We present the first theoretical saturated absorption spectra for general multi-level atoms, using a model based on extensions of the optical Bloch equations, and using Monte Carlo averaging of the absorption of individual atoms with random trajectories through a standing wave. We are for the first time able to accurately predict the merging of hyperfine and cross-over resonances due to intensity dependent phenomena such as power broadening. Results for 20-level sodium and 24-level rubidium models are presented and compared to experiment, demonstrating excellent agreement

  13. Dynamic model of an autonomous solar absorption refrigerator

    International Nuclear Information System (INIS)

    Ali Fellah; Tahar Khir; Ammar Ben Brahim

    2009-01-01

    The performance analysis of a solar absorption refrigerator operating in an autonomous way is investigated. The water/LiBr machine satisfies the air-conditioning needs along the day. The refrigerator performances were simulated regarding a dynamic model. For the solar driven absorption machines, two applications could be distinguished. The sun provides the thermal part of the useful energy. In this case, it is necessary to use additional energy as the electric one to activate the pumps, the fans and the control system. On the other hand, the sun provides all the necessary energy. Here, both photovoltaic cells and thermal concentrators should be used. The simulation in dynamic regime of the cycle requires the knowledge of the geometric characteristics of every component as the exchange areas and the internal volumes. Real characteristics of a refrigerator available at the applied thermodynamic research unit (ATRU) at the engineers' national school of Gabes are notified. The development of the thermal and matter balances in every component of the cycle has permitted to simulate in dynamic regime the performances of a solar absorption refrigerator operating with the water/LiBr couple for air-conditioning needs. The developed model could be used to perform intermittent refrigeration cycle autonomously driven. (author)

  14. Thermal conductivity and thermal diffusivity

    International Nuclear Information System (INIS)

    Hust, J.G.

    1983-01-01

    This chapter examines the heat transfer properties of solids, with emphasis on the behavior of pure metals and alloys. Topics considered include electronic conduction, magnetic field effects, lattice conduction, measuring methods, specimen size, uncertainty, thermal anchoring, radial heat loss, thermal conductivity apparatus, thermal diffusivity apparatus, empirical correlations, the Wiedemann-Franz-Lorenz law, Matthiessen's rule, low-temperature correlation, predictive techniques, crystalline dielectrics, and disordered dielectrics. The materials examined include copper, aluminium, binary alloys, structural alloys, and structural composites

  15. Phase change material thermal capacitor clothing

    Science.gov (United States)

    Buckley, Theresa M. (Inventor)

    2005-01-01

    An apparatus and method for metabolic cooling and insulation of a user in a cold environment. In its preferred embodiment the apparatus is a highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The apparatus can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The apparatus may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the apparatus also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

  16. Thermal insulation

    International Nuclear Information System (INIS)

    Pinsky, G.P.

    1977-01-01

    Thermal insulation for vessels and piping within the reactor containment area of nuclear power plants is disclosed. The thermal insulation of this invention can be readily removed and replaced from the vessels and piping for inservice inspection, can withstand repeated wettings and dryings, and can resist high temperatures for long periods of time. 4 claims, 3 figures

  17. Optically Transparent Thermally Insulating Silica Aerogels for Solar Thermal Insulation.

    Science.gov (United States)

    Günay, A Alperen; Kim, Hannah; Nagarajan, Naveen; Lopez, Mateusz; Kantharaj, Rajath; Alsaati, Albraa; Marconnet, Amy; Lenert, Andrej; Miljkovic, Nenad

    2018-04-18

    Rooftop solar thermal collectors have the potential to meet residential heating demands if deployed efficiently at low solar irradiance (i.e., 1 sun). The efficiency of solar thermal collectors depends on their ability to absorb incoming solar energy and minimize thermal losses. Most techniques utilize a vacuum gap between the solar absorber and the surroundings to eliminate conduction and convection losses, in combination with surface coatings to minimize reradiation losses. Here, we present an alternative approach that operates at atmospheric pressure with simple, black, absorbing surfaces. Silica based aerogels coated on black surfaces have the potential to act as simple and inexpensive solar thermal collectors because of their high transmission to solar radiation and low transmission to thermal radiation. To demonstrate their heat-trapping properties, we fabricated tetramethyl orthosilicate-based silica aerogels. A hydrophilic aerogel with a thickness of 1 cm exhibited a solar-averaged transmission of 76% and thermally averaged transmission of ≈1% (at 100 °C). To minimize unwanted solar absorption by O-H groups, we functionalized the aerogel to be hydrophobic, resulting in a solar-averaged transmission of 88%. To provide a deeper understanding of the link between aerogel properties and overall efficiency, we developed a coupled radiative-conductive heat transfer model and used it to predict solar thermal performance. Instantaneous solar thermal efficiencies approaching 55% at 1 sun and 80 °C were predicted. This study sheds light on the applicability of silica aerogels on black coatings for solar thermal collectors and offers design priorities for next-generation solar thermal aerogels.

  18. Measurements of the neutron capture cross sections and incineration potentials of minor-actinides in high thermal neutron fluxes: Impact on the transmutation of nuclear wastes; Mesures des sections efficaces de capture et potentiels d'incineration des actinides mineurs dans les hauts flux de neutrons: Impact sur la transmutation des dechets

    Energy Technology Data Exchange (ETDEWEB)

    Bringer, O

    2007-10-15

    This thesis comes within the framework of minor-actinide nuclear transmutation studies. First of all, we have evaluated the impact of minor actinide nuclear data uncertainties within the cases of {sup 241}Am and {sup 237}Np incineration in three different reactor spectra: EFR (fast), GT-MHR (epithermal) and HI-HWR (thermal). The nuclear parameters which give the highest uncertainties were thus highlighted. As a result of fact, we have tried to reduce data uncertainties, in the thermal energy region, for one part of them through experimental campaigns in the moderated high intensity neutron fluxes of ILL reactor (Grenoble). These measurements were focused onto the incineration and transmutation of the americium-241, the curium-244 and the californium-249 isotopes. Finally, the values of 12 different cross sections and the {sup 241}Am isomeric branching ratio were precisely measured at thermal energy point. (author)

  19. Solvent effects on the three-photon absorption of a symmetric charge-transfer molecule.

    Science.gov (United States)

    Lin, Na; Ferrighi, Lara; Zhao, Xian; Ruud, Kenneth; Rizzo, Antonio; Luo, Yi

    2008-04-17

    We present a theoretical study of the solvent-induced three-photon absorption cross section of a highly conjugated fluorene derivative, performed using density functional (DFT) cubic response theory in combination with the polarizable continuum model. The applicability of the often used two-state model is examined by comparison against the full DFT response theory results. It is found that the simplified model performs poorly for the three-photon absorption properties of our symmetric charge-transfer molecule. The dielectric medium enhances the three-photon absorption cross section remarkably. The effects of solvent polarity and geometrical distortions have been carefully examined. A detailed comparison with experiment is presented.

  20. Absorption of cosmic radio noise at different frequencies at Sanae

    International Nuclear Information System (INIS)

    Steyn, T.F.J.

    1983-12-01

    Electron density profiles are simulated as a function of altitude for the D- and E-regions during disturbed ionospheric conditions using auroral absorption data from riometers recording cosmic radio noise at 20, 30 and 51 MHz at Sanae, Antarctica. An elliptical function was used to simulate, as a function of height, the electron density profiles. Using these profiles the measured absorption was calculated by utilizing the Appleton-Hartree treatment for radio waves crossing the ionosphere. The frequency dependence of the riometer absorption is represented by a power law of the frequency: A(f) = C.f -n , and values of n were determined from calculations of the absorptions from the simulated electron density profiles. This power law is a fairly accurate representation in the frequency range 20 to 51 MHz. It appears that the exponent of the power law and the height of maximum absorption are effective parameters to determine the hardness of the energy spectra of precipitating electrons. A method is discussed whereby interferences on the riometer recordings are filtered from the data. Quiet day curves are obtained by the superposition of successive riometer recordings with a period of one sidereal day. A Fourier series is fitted to the points of maximum density to represent the quiet day recordings. Absorption events on day 175 and day 178 (1982) are analized for each riometer frequency, and the hardness of the precipitating electrons is inferred from the n-values of power law presentation. It is shown that the absorption of cosmic radio noise increases by increasing the depth of ionization without increasing the ionization rate (number of electrons /m 3 ) in the upper D-region. This may mean that a hardening of a precipitation spectrum will increase the absorption of cosmic radio noise

  1. KIM, Steady-State Transport for Fixed Source in 2-D Thermal Reactor by Monte-Carlo

    International Nuclear Information System (INIS)

    Cupini, E.; De Matteis, A.; Simonini, R.

    1980-01-01

    1 - Description of problem or function: KIM (K-infinite Monte Carlo) is a program which solves the steady-state linear transport equation for a fixed-source problem (or, by successive fixed-source runs, for the eigenvalue problem) in a two-dimensional infinite thermal reactor lattice. The main quantities computed in some broad energy groups are the following: - Fluxes and cross sections averaged over the region (i.e. a space portion that can be unconnected but contains everywhere the same homogeneous material), grouping of regions, the whole element. - Average absorption and fission rates per nuclide. - Average flux, absorption and production distributions versus energy. 2 - Method of solution: Monte Carlo simulation is used by tracing particle histories from fission birth down through the resonance region until absorption in the thermal range. The program is organised in three sections for fast, epithermal and thermal simulation, respectively; each section implements a particular model for both numerical techniques and cross section representation (energy groups in the fast section, groups or resonance parameters in the epithermal section, points in the thermal section). During slowing down (energy above 1 eV) nuclei are considered as stationary, with the exception of some resonance nuclei whose spacing between resonances is much greater than the resonance width. The Doppler broadening of s-wave resonances of these nuclides is taken into account by computing cross sections at the current neutron energy and at the temperature of the nucleus hit. During thermalization (energy below 1 eV) the thermal motion of some nuclides is also considered, by exploiting scattering kernels provided by the library for light water, heavy water and oxygen at several temperatures. KIM includes splitting and Russian roulette. A characteristic feature of the program is its approach to the lattice geometry. In fact, besides the usual continuous treatment of the geometry using the well

  2. Analysis of peripheral thermal damage after laser irradiation of dentin using polarized light microscopy and synchrotron radiation infrared spectromicroscopy

    Science.gov (United States)

    Dela Rosa, Alfredo; Sarma, Anupama V.; Le, Charles Q.; Jones, Robert S.; Fried, Daniel

    2004-05-01

    It is necessary to minimize peripheral thermal damage during laser irradiation, since thermal damage to collagen and mineral compromises the bond strength to restorative materials in dentin and inhibits healing and osteointegration in bone. The overall objective of this study was to test the hypothesis that lasers resonant to the specific absorption of water, collagen, and hydroxyapatite with pulse durations less than the thermal relaxation times at each respective laser wavelength will efficiently remove dentin with minimal peripheral thermal damage. Precise incisions were produced in 3 x 3 mm2 blocks of human dentin using CO2 (9.6 μm), Er:YSGG (2.79 μm), and Nd:YAG (355 nm) lasers with and without a computer controlled water spray. Polarization-sensitive optical coherence tomography was used to obtain optical cross-sections of each incision to determine the rate and efficiency of ablation. The peripheral thermal damage zone around each incision was analyzed using polarized light microscopy (PLM) and Synchrotron-Radiation Fourier Transform Infrared Spectro-microscopy (SR-FTIR). Thermally induced chemical changes to both mineral and the collagen matrix was observed with SR-FTIR with a 10-μm spatial resolution and those changes were correlated with optical changes observed with PLM. Minimal (alveolar bone.

  3. Thermal systems; Systemes thermiques

    Energy Technology Data Exchange (ETDEWEB)

    Lalot, S. [Valenciennes Univ. et du Hainaut Cambresis, LME, 59 (France); Lecoeuche, S. [Ecole des Mines de Douai, Dept. GIP, 59 - Douai (France)]|[Lille Univ. des Sciences et Technologies, 59 - Villeneuve d' Ascq (France); Ahmad, M.; Sallee, H.; Quenard, D. [CSTB, 38 - Saint Martin d' Heres (France); Bontemps, A. [Universite Joseph Fourier, LEGI/GRETh, 38 - Grenoble (France); Gascoin, N.; Gillard, P.; Bernard, S. [Laboratoire d' Energetique, Explosion, Structure, 18 - Bourges (France); Gascoin, N.; Toure, Y. [Laboratoire Vision et Robotique, 18 - Bourges (France); Daniau, E.; Bouchez, M. [MBDA, 18 - Bourges (France); Dobrovicescu, A.; Stanciu, D. [Bucarest Univ. Polytechnique, Faculte de Genie Mecanique (Romania); Stoian, M. [Reims Univ. Champagne Ardenne, Faculte des Sciences, UTAP/LTM, 51 (France); Bruch, A.; Fourmigue, J.F.; Colasson, S. [CEA Grenoble, Lab. Greth, 38 (France); Bontemps, A. [Universite Joseph Fourier, LEGI/GRETh, 38 - Grenoble (France); Voicu, I.; Mare, T.; Miriel, J. [Institut National des Sciences Appliquees (INSA), LGCGM, IUT, 35 - Rennes (France); Galanis, N. [Sherbrooke Univ., Genie Mecanique, QC (Canada); Nemer, M.; Clodic, D. [Ecole des Mines de Paris, Centre Energetique et Procedes, 75 (France); Lasbet, Y.; Auvity, B.; Castelain, C.; Peerhossaini, H. [Nantes Univ., Ecole Polytechnique, Lab. de Thermocinetiquede Nantes, UMR-CNRS 6607, 44 (France)

    2005-07-01

    the experimental studies about CO{sub 2} boiling flows; evaluation of the thermal response of buildings: dynamical repercussion of the envelope; comparison of irreversibilities in double-effect, double-absorber absorption refrigeration machines; study of a solar diffusion-absorption refrigeration cycle working with hydrocarbons. (J.S.)

  4. Temperature dependence of the ClONO{sub 2} UV absorption spectrum

    Energy Technology Data Exchange (ETDEWEB)

    Burkholder, J.B.; Talukdar, R.K.; Ravishankara, A.R. [Univ. of Colorado, Boulder, CO (United States)

    1994-04-01

    The temperature dependence of the ClONO{sub 2} absorption spectrum has been measured between 220 and 298 K and between 195 and 430 nm using a diode array spectrometer. The absorption cross sections were determined using both: (1) absolute pressure measurements at 296 K and (2) measurements at various temperatures relative to 296 K using a dual absorption cell arrangement. The temperature dependence of the ClONO{sub 2} absorption spectrum shows very broad structure. The amplitude of the temperature dependence relative to that at 296 K is weak at short wavelengths, < 2% at 215 nm and 220 K, but significant at the wavelengths important in the stratosphere, {approximately} 30% at 325 nm and 220 K. The authors ClONO{sub 2} absorption cross section data are in good general agreement with the previous measurements of Molina and Molina.

  5. Temperature dependence of the ClONO2 UV absorption spectrum

    Science.gov (United States)

    Burkholder, James B.; Talukdar, Ranajit K.; Ravishankara, A. R.

    1994-01-01

    The temperature dependence of the ClONO2 absorption spectrum has been measured between 220 and 298 K and between 195 and 430 nm using a diode array spectrometer. The absorption cross sections were determined using both: (1) absolute pressure measurements at 296 K and (2) measurements at various temperatures relative to 296 K using a dual absorption cell arrangement. The temperature dependence of the ClONO2 absorption spectrum shows very broad structure. The amplitude of the temperature dependence relative to that at 296 K is weak at short wavelengths, less than 2% at 215 nm and 220 K, but significant at the wavelengths important in the stratosphere, about 30% at 325 nm and 220 K. Our ClONO2 absorption cross section data are in good general agreement with the previous measurements of Molina and Molina (1979).

  6. An analysis of uncertainties in the reference resonance absorption calculations

    International Nuclear Information System (INIS)

    Milosevic, M.; Pesic, M.

    1997-05-01

    A recently appeared generation of design-oriented methods, which allows to compute the space and energy dependence of the resonant absorption inside the fuel rod, induces a new problem of validation of results obtained with improved resonance treatments, Because no experimental results are available on the spatial and energy distribution of resonance absorption, detailed reference calculations were generated with the continuos-energy Monte Carlo and energy pointwise slowing-down codes. The accuracy of these calculations depends>on various in.fluences. In this paper an analysis of some influences, such as differences ;n nuclear data libraries and philosophy of reproducing the cross section data, is presented. Example application is given for a calculation benchmark that consists of determination of resonance absorption by 238 U in typical PWR pin cell geometry (author)

  7. The effect of exercise on the absorption of inhaled human insulin in healthy volunteers

    DEFF Research Database (Denmark)

    Petersen, Astrid Heide; Kohler, Gerd; Korsatko, Stefan

    2008-01-01

    of exercise on the absorption of inhaled insulin. * In this study in healthy volunteers we found that exercise early after dosing increased absorption (15-20%) of inhaled insulin over the first 2 h after start of exercise, with an approximately 30% increase in maximal insulin concentration, and unchanged...... overall absorption. Aims To investigate the effect of moderate exercise on the absorption of inhaled insulin. Methods A single-centre, randomized, open-label, three-period cross-over trial was carried out in 12 nonsmoking healthy subjects. A dose of 3.5 mg inhaled human insulin was administered via......What is already known about this subject * Exercise is known to affect absorption of other inhaled substances, but so far there are no reports on the effect of exercise on the absorption of inhaled insulin in humans. What this paper adds * This report is the first to investigate the effect...

  8. Transdermic absorption of Melagenina II

    International Nuclear Information System (INIS)

    Hernandez Gonzalez, I.; Martinez Lopez, B.; Ruiz Pena, M.; Caso Pena, R.

    1997-01-01

    The transdermic absorption of Melagenina II (MII) was evaluated. MII was a labelled with 125I by the yodogen method and purified by column chromatography with Sephadex LH-20 in ethanol: water (7:3). In vitro absorption of ( 125I ) - MII thought human skin was carried out in Keshary-Chien modified diffusion cells. Tape stripping method was applied after 24 hours to evaluate the accumulated activity in dermis and epidermis. In vivo assays were performed in Sprague Dawley rats to analyze absorption of MII until 24 hours after a single application and for five days a low penetrability of the drug while in vivo there were not found blood levels significantly greater than zero , nevertheless and important amount of radioactivity was found in feces and urine. The activity was concentrated mainly in the application site in both models

  9. Absorption properties of identical atoms

    International Nuclear Information System (INIS)

    Sancho, Pedro

    2013-01-01

    Emission rates and other optical properties of multi-particle systems in collective and entangled states differ from those in product ones. We show the existence of similar effects in the absorption probabilities for (anti)symmetrized states of two identical atoms. The effects strongly depend on the overlapping between the atoms and differ for bosons and fermions. We propose a viable experimental verification of these ideas. -- Highlights: •The absorption rates of a pair of identical atoms in product and (anti)symmetrized states are different. •The modifications of the optical properties are essentially determined by the overlapping between the atoms. •The absorption properties differ, in some cases, for bosons and fermions

  10. Calcium absorption from fortified ice cream formulations compared with calcium absorption from milk.

    Science.gov (United States)

    van der Hee, Regine M; Miret, Silvia; Slettenaar, Marieke; Duchateau, Guus S M J E; Rietveld, Anton G; Wilkinson, Joy E; Quail, Patricia J; Berry, Mark J; Dainty, Jack R; Teucher, Birgit; Fairweather-Tait, Susan J

    2009-05-01

    Optimal bone mass in early adulthood is achieved through appropriate diet and lifestyle, thereby protecting against osteoporosis and risk of bone fracture in later life. Calcium and vitamin D are essential to build adequate bones, but calcium intakes of many population groups do not meet dietary reference values. In addition, changes in dietary patterns are exacerbating the problem, thereby emphasizing the important role of calcium-rich food products. We have designed a calcium-fortified ice cream formulation that is lower in fat than regular ice cream and could provide a useful source of additional dietary calcium. Calcium absorption from two different ice cream formulations was determined in young adults and compared with milk. Sixteen healthy volunteers (25 to 45 years of age), recruited from the general public of The Netherlands, participated in a randomized, reference-controlled, double-blind cross-over study in which two test products and milk were consumed with a light standard breakfast on three separate occasions: a standard portion of ice cream (60 g) fortified with milk minerals and containing a low level (3%) of butter fat, ice cream (60 g) fortified with milk minerals and containing a typical level (9%) of coconut oil, and reduced-fat milk (1.7% milk fat) (200 mL). Calcium absorption was measured by the dual-label stable isotope technique. Effects on calcium absorption were evaluated by analysis of variance. Fractional absorption of calcium from the 3% butterfat ice cream, 9% coconut oil ice cream, and milk was 26%+/-8%, 28%+/-5%, and 31%+/-9%, respectively, and did not differ significantly (P=0.159). Results indicate that calcium bioavailability in the two calcium-fortified ice cream formulations used in this study is as high as milk, indicating that ice cream may be a good vehicle for delivery of calcium.

  11. Solute dispersion in open channel flow with bed absorption

    Science.gov (United States)

    Wang, Ping; Chen, G. Q.

    2016-12-01

    Reactive solute dispersion is of essential significance in various ecological and environmental applications. It is only qualitatively known that boundary absorption depletes pollutant around the boundary and reduces the concentration nearby. All the existing studies on this topic have been focused on the longitudinally distributed mean concentration, far from enough to fully characterize the transport process with tremendous cross-sectional concentration nonuniformity. This work presents an analytical study of the evolution of two-dimensional concentration distribution for solute dispersion in a laminar open channel flow with bed absorption. The fourth order Aris-Gill expansion proposed in our previous study (Wang and Chen, 2016b) is further extended for the case with bed absorption to cover the transitional effects of skewness and kurtosis. Results reveal the extremely nonuniform cross-sectional concentration distribution, and demonstrate that concentration at the bed instead of the mean should be used for reliable quantification of the absorption flux. The accurate two-dimensional concentration distribution presented in this study brings important environmental implications such as risk assessment associated with peak concentration position and duration of toxic pollutant cloud in open channel waters.

  12. Thermal neutron diffusion parameters dependent on the flux energy distribution in finite hydrogenous media

    International Nuclear Information System (INIS)

    Drozdowicz, K.

    1999-01-01

    Macroscopic parameters for a description of the thermal neutron transport in finite volumes are considered. A very good correspondence between the theoretical and experimental parameters of hydrogenous media is attained. Thermal neutrons in the medium possess an energy distribution, which is dependent on the size (characterized by the geometric buckling) and on the neutron transport properties of the medium. In a hydrogenous material the thermal neutron transport is dominated by the scattering cross section which is strongly dependent on energy. A monoenergetic treatment of the thermal neutron group (admissible for other materials) leads in this case to a discrepancy between theoretical and experimental results. In the present paper the theoretical definitions of the pulsed thermal neutron parameters (the absorption rate, the diffusion coefficient, and the diffusion cooling coefficient) are based on Nelkin's analysis of the decay of a neutron pulse. Problems of the experimental determination of these parameters for a hydrogenous medium are discussed. A theoretical calculation of the pulsed parameters requires knowledge of the scattering kernel. For thermal neutrons it is individual for each hydrogenous material because neutron scattering on hydrogen nuclei bound in a molecule is affected by the molecular dynamics (characterized with internal energy modes which are comparable to the incident neutron energy). Granada's synthetic model for slow-neutron scattering is used. The complete up-dated formalism of calculation of the energy transfer scattering kernel after this model is presented in the paper. An influence of some minor variants within the model on the calculated differential and integral neutron parameters is shown. The theoretical energy-dependent scattering cross section (of Plexiglas) is compared to experimental results. A particular attention is paid to the calculation of the diffusion cooling coefficient. A solution of an equation, which determines the

  13. Investigation of thermal integration between biogas production and upgrading

    International Nuclear Information System (INIS)

    Zhang, Xiaojing; Yan, Jinying; Li, Hailong; Chekani, Shabnam; Liu, Loncheng

    2015-01-01

    Highlights: • Identify thermal characteristics of amine-based biogas upgrading for waste heat recovery. • Identify thermal characteristics of AD biogas production as sink for heat recovery. • Evaluation of thermal integration between biogas production and upgrading to improve overall energy efficiency. • Cost analysis applied for the economic feasibility of the thermal integration. • Using the principles of target design and system integration for connected thermal processes. - Abstract: Thermal integration of anaerobic digestion (AD) biogas production with amine-based chemical absorption biogas upgrading has been studied to improve the overall efficiency of the intergraded system. The thermal characteristics have been investigated for industrial AD raw biogas production and amine-based chemical absorption biogas upgrading. The investigation provides a basic understanding for the possibilities of energy saving through thermal integration. The thermal integration is carried out through well-defined cases based on the thermal characteristics of the biogas production and the biogas upgrading. The following factors are taken into account in the case study: thermal conditions of sub-systems, material and energy balances, cost issues and main benefits. The potential of heat recovery has been evaluated to utilise the waste heat from amine-based upgrading process for the use in the AD biogas production. The results show that the thermal integration has positive effects on improving the overall energy efficiency of the integrated biogas plant. Cost analysis shows that the thermal integration is economically feasible

  14. Aerosol Absorption Measurements in MILAGRO.

    Science.gov (United States)

    Gaffney, J. S.; Marley, N. A.; Arnott, W. P.; Paredes-Miranda, L.; Barnard, J. C.

    2007-12-01

    During the month of March 2006, a number of instruments were used to determine the absorption characteristics of aerosols found in the Mexico City Megacity and nearby Valley of Mexico. These measurements were taken as part of the Department of Energy's Megacity Aerosol Experiment - Mexico City (MAX-Mex) that was carried out in collaboration with the Megacity Interactions: Local and Global Research Observations (MILAGRO) campaign. MILAGRO was a joint effort between the DOE, NSF, NASA, and Mexican agencies aimed at understanding the impacts of a megacity on the urban and regional scale. A super-site was operated at the Instituto Mexicano de Petroleo in Mexico City (designated T-0) and at the Universidad Technologica de Tecamac (designated T-1) that was located about 35 km to the north east of the T-0 site in the State of Mexico. A third site was located at a private rancho in the State of Hidalgo approximately another 35 km to the northeast (designated T-2). Aerosol absorption measurements were taken in real time using a number of instruments at the T-0 and T-1 sites. These included a seven wavelength aethalometer, a multi-angle absorption photometer (MAAP), and a photo-acoustic spectrometer. Aerosol absorption was also derived from spectral radiometers including a multi-filter rotating band spectral radiometer (MFRSR). The results clearly indicate that there is significant aerosol absorption by the aerosols in the Mexico City megacity region. The absorption can lead to single scattering albedo reduction leading to values below 0.5 under some circumstances. The absorption is also found to deviate from that expected for a "well-behaved" soot anticipated from diesel engine emissions, i.e. from a simple 1/lambda wavelength dependence for absorption. Indeed, enhanced absorption is seen in the region of 300-450 nm in many cases, particularly in the afternoon periods indicating that secondary organic aerosols are contributing to the aerosol absorption. This is likely due

  15. Thermally stimulated luminescence studies in combustion ...

    Indian Academy of Sciences (India)

    Wintec

    resonance, photoacoustic studies/optical absorption etc in order to understand the TSL mechanism leading to gene- ration and trapping of defect centres due to ionizing radiation and light emission in aluminum oxide during thermal stimulation. Figure 3 shows the variation of TSL intensity with γ- ray dose in combustion ...

  16. Thermal condensation mode in a dusty plasma

    Indian Academy of Sciences (India)

    associated emission nebula, escapes without being absorbed by the in-falling matter from the accretion disk, the dust grain, depending upon the thermal velocities of the background plasma particles, may pick up between 10 to 100 electronic charges from the ionized gas. [5]. Interstellar dust is heated by the absorption of ...

  17. Fission product data for thermal reactors. Final report. Part I. A data set for EPRI-CINDER using ENDF/B-IV

    International Nuclear Information System (INIS)

    England, T.R.; Wilson, W.B.; Stamatelatos, M.G.

    1976-12-01

    A four-group fission-product neutron absorption library, appropriate for use in thermal reactors, is described. All decay parameters are taken from ENDF/B-IV. The absorption cross sections are also processed from ENDF/B-IV files, first into a 154-group set and subsequently collapsed into the 4-group set described in this report. The decay and cross section data were used to form 84 linear chains in the CINDER code format. These chains contain all significant fission products having half-lives exceeding 4 hours--a total of 186 nuclides. A 12-chain set containing one pseudo-chain for use in spatial depletion calculations is described. This set accurately reproduces the aggregate absorption buildup of the 84 chains. This report describes the chains and processed data, results of comparison calculations for various fuels, and a comparison of calculated temporal fission-product absorption buildup with corresponding results from a long-term fuel irradiation and cooling integral experiment

  18. Sound absorption property of openpore aluminum foams

    OpenAIRE

    WANG Fang; WANG Lu-cai; WU Jian-guo

    2007-01-01

    This paper presents a study on sound absorption property of aluminum foam by evaluating its sound absorption coefficients using standing wave tube method. Experimental results showed that the average values of sound absorption coefficients (over the test frequency range) are all above 0.4, which indicate very good sound absorption property of the aluminum foams. The sound absorption coefficient is affected by frequency and pore structure, and reaches its maximum value at around 1 000 Hz. With...

  19. Cosmological implications of the redshift distribution of QSO absorption systems

    International Nuclear Information System (INIS)

    Khare-Joshi, P.; Perry, J.J.

    1982-01-01

    We have used the observational data on QSO absorption redshifts, as compiled by Perry, Burbidge and Burbidge (1978) (hereafter PB 2 ), Drew (1978) and Weyman et al. (1979) (hereafter W 2 PT), to study various selection effects likely to affect the distribution of absorption redshifts and, then to determine the probable number distribution of absorbers per redshift interval of 0.1, as a function of z. The distribution obtained, assuming all the observed absorption to be intervening, is found to be statistically incompatible with the redshift distribution of galaxies with constant cross-section for any Friedman cosmology with zero cosmological constant and q 0 >= 0. Therefore, in order to eliminate the absorption systems which are plausibly intrinsic, we have applied the criterion suggested by W 2 PT and by the analysis of the distribution of absorption systems as a function of the relative velocity between the emitting and the absorbing gas, for the PB 2 data set; to wit, we have analysed the distributions obtained by assuming that those systems with relative velocity greater than 0.02 c, 0.02 c but not equal to 0.1 c to 0.11 c and 0.06 c respectively, or those systems without O VI and N V lines, are produced by the intervening galaxies. The results are discussed. (author)

  20. Absorption and emission spectroscopic characterisation of 8-amino-riboflavin

    International Nuclear Information System (INIS)

    Tyagi, A.; Zirak, P.; Penzkofer, A.; Mathes, T.; Hegemann, P.; Mack, M.; Ghisla, S.

    2009-01-01

    The flavin dye 8-amino-8-demethyl-D-riboflavin (AF) in the solvents water, DMSO, methanol, and chloroform/DMSO was studied by absorption and fluorescence spectroscopy. The first absorption band is red-shifted compared to riboflavin, and blue-shifted compared to roseoflavin (8-dimethylamino-8-demethyl-D-riboflavin). The fluorescence quantum yield of AF in the studied solvents varies between 20% and 50%. The fluorescence lifetimes were found to be in the 2-5 ns range. AF is well soluble in DMSO, weakly soluble in water and methanol, and practically insoluble in chloroform. The limited solubility causes AF aggregation, which was seen in differences between measured absorption spectra and fluorescence excitation spectra. Light scattering in the dye absorption region is discussed and approximate absorption cross-section spectra are determined from the combined measurement of transmission and fluorescence excitation spectra. The photo-stability of AF was studied by prolonged light exposure. The photo-degradation routes of AF are discussed.