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Sample records for theoretical vibrational frequencies

  1. Theoretical molecular structure, vibrational frequencies and NMR ...

    African Journals Online (AJOL)

    Theoretical results have been successfully compared with available experimental data in the literature. Regarding the calculations, 2mpe-4bb prefers enol-imine form and DFT method is superior to HF approach except for predicting bond lengths. KEY WORDS: Schiff bases, Normal mode frequencies, HF, DFT, NMR. Bull.

  2. Vibrational frequency fluctuations of ionic vibrational probe in water: Theoretical study with molecular dynamics simulation

    Science.gov (United States)

    Okuda, Masaki; Higashi, Masahiro; Ohta, Kaoru; Saito, Shinji; Tominaga, Keisuke

    2017-09-01

    The vibrational dynamics of SCN- in H2O are theoretically investigated by molecular dynamics simulations. Based on the vibrational solvatochromism theory, we calculate the frequency-frequency time correlation function of the SCN anti-symmetric stretching mode, which is characterized by time constants of 0.13 and 1.41 ps. We find that the frequency fluctuation is almost determined by the electrostatic interaction from the water molecules in the first-hydration shell. The collective dynamics of the water molecules in the first-hydration shell is found to be similar to that of bulk water, though the hydrogen bond between the ion and water molecule is very strong.

  3. Orientations of nonlocal vibrational modes from combined experimental and theoretical sum frequency spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Chase, Hilary M.; Chen, Shunli; Fu, Li; Upshur, Mary Alice; Rudshteyn, Benjamin; Thomson, Regan J.; Wang, Hong-Fei; Batista, Victor S.; Geiger, Franz M.

    2017-09-01

    Inferring molecular orientations from vibrational sum frequency generation (SFG) spectra is challenging in polarization combinations that result in low signal intensities, or when the local point group symmetry approximation fails. While combining experiments with density functional theory (DFT) could overcome this problem, the scope of the combined method has yet to be established. Here, we assess its feasibility of determining the distributions of molecular orientations for one monobasic ester, two epoxides and three alcohols at the vapor/fused silica interface. We find that molecular orientations of nonlocal vibrational modes cannot be determined using polarization-resolved SFG measurements alone.

  4. Theoretical study of sum-frequency vibrational spectroscopy on limonene surface

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Ren-Hui, E-mail: zrh@iccas.ac.cn; Liu, Hao; Jing, Yuan-Yuan; Wang, Bo-Yang; Shi, Qiang [Beijing National Laboratory for Molecular Sciences, State Key Laboratory for Structural Chemistry of Unstable and Stable Species, Institute of Chemistry, Chinese Academy of Sciences, Zhongguancun, Beijing 100190 (China); Wei, Wen-Mei [Department of Chemistry, College of Basic Medicine, Anhui Medical University, Hefei, Anhui 230032 (China)

    2014-03-14

    By combining molecule dynamics (MD) simulation and quantum chemistry computation, we calculate the surface sum-frequency vibrational spectroscopy (SFVS) of R-limonene molecules at the gas-liquid interface for SSP, PPP, and SPS polarization combinations. The distributions of the Euler angles are obtained using MD simulation, the ψ-distribution is between isotropic and Gaussian. Instead of the MD distributions, different analytical distributions such as the δ-function, Gaussian and isotropic distributions are applied to simulate surface SFVS. We find that different distributions significantly affect the absolute SFVS intensity and also influence on relative SFVS intensity, and the δ-function distribution should be used with caution when the orientation distribution is broad. Furthermore, the reason that the SPS signal is weak in reflected arrangement is discussed.

  5. Theoretical molecular structure, vibrational frequencies and NMR investigations of 2-[(1E-2-aza-2-(5-methyl(2-pyridylethenyl]-4-bromobenzen-1-ol

    Directory of Open Access Journals (Sweden)

    Cemal Parlak

    2012-08-01

    Full Text Available The normal mode frequencies and corresponding vibrational assignments, 1H and 13C NMR chemical shifts and structural parameters (bond lengths, bond and dihedral angles of 2-[(1E-2-aza-2-(5-methyl(2-pyridylethenyl]-4-bromobenzen-1-ol (2mpe-4bb Schiff base compound have been theoretically examined by means of Hartree-Fock (HF and Becke-3-Lee-Yang-Parr (B3LYP density functional methods with 6-31G(d and 6-311++G(d,p basis sets. Furthermore, reliable vibrational assignments have made on the basis of potential energy distribution (PED calculated and the thermodynamics functions, highest occupied and lowest unoccupied molecular orbitals (HOMO and LUMO of 2mpe-4bb have been predicted. Theoretical results have been successfully compared with available experimental data in the literature. Regarding the calculations, 2mpe-4bb prefers enol-imine form and DFT method is superior to HF approach except for predicting bond lengths.DOI: http://dx.doi.org/10.4314/bcse.v26i2.11

  6. An oxorhenium complex bearing a chiral cyclohexane-1-olato-2-thiolato ligand: Synthesis, stereochemistry, and theoretical study of parity violation vibrational frequency shifts.

    Science.gov (United States)

    Saleh, Nidal; Bast, Radovan; Vanthuyne, Nicolas; Roussel, Christian; Saue, Trond; Darquié, Benoît; Crassous, Jeanne

    2017-11-15

    In our effort towards measuring the parity violation energy difference between two enantiomers, a simple chiral oxorhenium complex 5 bearing enantiopure 2-mercaptocyclohexan-1-ol has been prepared as a potential candidate species. Vibrational circular dichroism revealed a chiral environment surrounding the rhenium atom, even though the rhenium is not a stereogenic center itself, and enabled to assign the (1S,2S)-(-) and (1R,2R)-(+) absolute configuration for 5. For both compound 5 and complex 4, previously studied by us and bearing a propane-2-olato-3-thiolato ligand, relativistic calculations predict parity violating vibrational frequency differences of a few hundreds of millihertz, above the expected sensitivity attainable by a molecular beam Ramsey interferometer that we are constructing. © 2017 Wiley Periodicals, Inc.

  7. Vibrational and theoretical study of selected diacetylenes.

    Science.gov (United States)

    Roman, Maciej; Baranska, Malgorzata

    2013-11-01

    Six commonly used disubstituted diacetylenes with short side-chains (RCCCCR, where R=CH2OH, CH2OPh, C(CH3)2OH, C(CH3)3, Si(CH3)3, and Ph) were analyzed using vibrational spectroscopy and quantum-chemical calculations to shed new light on structural and spectroscopic properties of these compounds. Prior to that the conformational analysis of diacetylenes was performed to search the Potential Energy Surface for low-energy minima. Theoretical investigations were followed by the potential energy distribution (PED) analysis to gain deeper insight into FT-Raman and FT-IR spectra that, in some cases, were recorded for the first time for the studied compounds. The analysis was focused mainly on spectral features of the diacetylene system sensitive to the substitution. Shifts of the characteristic bands and changes in bond lengths were observed when changing the substituent. Furthermore, Fermi resonance was observed in the vibrational spectra of some diacetylenes. FT-IR spectra were measured by using two methods, i.e. transmission (with KBr substrate) and Attenuated Total Reflection (ATR), showing the latter adequate and fast tool for IR measurements of diacetylenes. Additionally, Surface Enhanced Raman Spectroscopy (SERS) was applied for phenyl derivative for the first time to study its interaction with metallic nanoparticles that seems to be perpendicular. Copyright © 2013 Elsevier B.V. All rights reserved.

  8. Vibration modes and frequencies of structures

    Science.gov (United States)

    Durling, R. J.; Kvaternik, R. G.

    1980-01-01

    SUDAN, Substructuring in Direct Analysis, analyzes natural modes and frequencies of vibration of structural systems. Based on direct method of analysis that employs substructures methodology, program is used with structures that may be represented as equivalent system of beam, springs, and rigid bodies.

  9. Geometry optimization and vibrational frequencies of tetracene ...

    African Journals Online (AJOL)

    Tetracene is an organic semiconductor with chemical formula C18H12 used in organic field effecttransistor (OFET) and organic light emitting diode (OLED). In this work, the molecular geometry (optimized bond lengths and bond angles), vibrational frequencies and intensities, HOMO-LUMO Energy gap and Atomic charge ...

  10. Nonlinear frequency response analysis of structural vibrations

    Science.gov (United States)

    Weeger, Oliver; Wever, Utz; Simeon, Bernd

    2014-12-01

    In this paper we present a method for nonlinear frequency response analysis of mechanical vibrations of 3-dimensional solid structures. For computing nonlinear frequency response to periodic excitations, we employ the well-established harmonic balance method. A fundamental aspect for allowing a large-scale application of the method is model order reduction of the discretized equation of motion. Therefore we propose the utilization of a modal projection method enhanced with modal derivatives, providing second-order information. For an efficient spatial discretization of continuum mechanics nonlinear partial differential equations, including large deformations and hyperelastic material laws, we employ the concept of isogeometric analysis. Isogeometric finite element methods have already been shown to possess advantages over classical finite element discretizations in terms of higher accuracy of numerical approximations in the fields of linear vibration and static large deformation analysis. With several computational examples, we demonstrate the applicability and accuracy of the modal derivative reduction method for nonlinear static computations and vibration analysis. Thus, the presented method opens a promising perspective on application of nonlinear frequency analysis to large-scale industrial problems.

  11. Theoretical analysis and experimental measurement for resonant vibration of piezoceramic circular plates.

    Science.gov (United States)

    Huang, Chi-Hung; Lin, Yu-Chih; Ma, Chien-Ching

    2004-01-01

    Based on the electroelastic theory for piezoelectric plates, the vibration characteristics of piezoceramic disks with free-boundary conditions are investigated in this work by theoretical analysis, numerical simulation, and experimental measurement. The resonance of thin piezoceramic disks is classified into three types of vibration modes: transverse, tangential, and radial extensional modes. All of these modes are investigated in detail. Two optical techniques, amplitude-fluctuation electronic speckle pattern interferometry (AF-ESPI) and laser Doppler vibrometer (LDV), are used to validate the theoretical analysis. Because the clear fringe patterns are shown only at resonant frequencies, both the resonant frequencies and the corresponding mode shapes are obtained experimentally at the same time by the proposed AF-ESPI method. Good quality of the interferometric fringe patterns for both the transverse and extensional vibration mode shapes are demonstrated. The resonant frequencies of the piezoceramic disk also are measured by the conventional impedance analysis. Both theoretical and experimental results indicate that the transverse and tangential vibration modes cannot be measured by the impedance analysis, and only the resonant frequencies of extensional vibration modes can be obtained. Numerical calculations based on the finite element method also are performed, and the results are compared with the theoretical analysis and experimental measurements. It is shown that the finite element method (FEM) calculations and the experimental results agree fairly well for the resonant frequencies and mode shapes. The resonant frequencies and mode shapes predicted by theoretical analysis and calculated by finite element method are in good agreement, and the difference of resonant frequencies for both results with the thickness-to-diameter (h/D) ratios, ranging from 0.01 to 0.1, are presented.

  12. theoretical molecular structure, vibrational frequencies and nmr

    African Journals Online (AJOL)

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    Pandeya, S.N.; Sriram, D.; Nath, G.; De Clercq, E. IL Farmaco 1999, 54, 624. 7. Samadhiya, S.; Halve, A., Orient. J. Chem. 2001, 17, 119. 8. Garnovskii, A.D.; Nivorozhkin, A.L.; Minkin, V.I., Coord. Chem. Rev. 1993, 126, 1. 9. Dal, H.; Süzen, Y.; Şahin, E. Spectrochim. Acta A 2007, 67, 808. 10. Rauhut, G.; Pulay, P. J. Phys.

  13. Energetics, structures, vibrational frequencies, vibrational absorption, vibrational circular dichroism and Raman intensities of Leu-enkephalin

    DEFF Research Database (Denmark)

    Jalkanen, Karl J.

    2003-01-01

    Here we present several low energy conformers of Leu-enkephalin (LeuE) calculated with the density functional theory using the Becke 3LYP hybrid functional and the 6-31G* basis set. The structures, conformational energies, vibrational frequencies, vibrational absorption (VA) intensities......, vibrational circular dichroism (VCD) intensities and Raman scattering intensities are reported for the conformers of LeuE which are expected to be populated at room temperature. The species of LeuE-present in non-polar solvents is the neutral non-ionic species with the NH2 and CO2H groups, in contrast...... to the zwitterionic neutral species with the NH3+ and CO2- groups which predominates in aqueous solution and in the crystal. All of our attempts to find the zwitterionic species in the isolated state failed, with the result that a hydrogen atom from the positively charged N-terminus ammonium group transferred either...

  14. Driving an Active Vibration Balancer to Minimize Vibrations at the Fundamental and Harmonic Frequencies

    Science.gov (United States)

    Holliday, Ezekiel S. (Inventor)

    2014-01-01

    Vibrations of a principal machine are reduced at the fundamental and harmonic frequencies by driving the drive motor of an active balancer with balancing signals at the fundamental and selected harmonics. Vibrations are sensed to provide a signal representing the mechanical vibrations. A balancing signal generator for the fundamental and for each selected harmonic processes the sensed vibration signal with adaptive filter algorithms of adaptive filters for each frequency to generate a balancing signal for each frequency. Reference inputs for each frequency are applied to the adaptive filter algorithms of each balancing signal generator at the frequency assigned to the generator. The harmonic balancing signals for all of the frequencies are summed and applied to drive the drive motor. The harmonic balancing signals drive the drive motor with a drive voltage component in opposition to the vibration at each frequency.

  15. Multiaxial vibration fatigue-A theoretical and experimental comparison

    Science.gov (United States)

    Mršnik, Matjaž; Slavič, Janko; Boltežar, Miha

    2016-08-01

    Random vibration excitation is a common cause of failure, especially if natural dynamics is excited. The high-cycle vibration-fatigue analysis typically requires the structural dynamics analysis, the response analysis and the fatigue analysis. The material parameters (S-N curve) are obtained at uniaxial stress state. However, in real structures the stress state is rarely uniaxial and the direct application of the S-N curve is difficult. The stress tensor is reduced to a more manageable representation using a multiaxial criterion. In this study, maximum normal stress, maximum shear stress, maximum normal-and-shear stress, C-S criterion, Projection-by- Projection and the Preumont and Piéfort criterion for multiaxial stress state are compared theoretically and experimentally. The crack location and the time-to-failure were compared. The time-to-failure was found relatively accurate with all multiaxial criteria; however, the crack-location estimation was found not to be accurate enough for either of the compared criteria. The study proves the applicability of the vibration-fatigue analysis procedure on real vibrating structures with rich structural dynamics. Random vibration excitation is a common cause of failure, especially if natural dynamics is excited. The high-cycle vibration-fatigue analysis typically requires the structural dynamics analysis, the response analysis and the fatigue analysis. The material parameters (S-N curve) are obtained at uniaxial stress state. However, in real structures the stress state is rarely uniaxial and the direct application of the S-N curve is difficult. The stress tensor is reduced to a more manageable representation using a multiaxial criterion. In this study, maximum normal stress, maximum shear stress, maximum normaland-shear stress, C-S criterion, Projection-by-Projection and the Preumont and Piéfort criterion for multiaxial stress state are compared theoretically and experimentally. The crack location and the time

  16. High frequency vibration characteristics of electric wheel system under in-wheel motor torque ripple

    Science.gov (United States)

    Mao, Yu; Zuo, Shuguang; Wu, Xudong; Duan, Xianglei

    2017-07-01

    With the introduction of in-wheel motor, the electric wheel system encounters new vibration problems brought by motor torque ripple excitation. In order to analyze new vibration characteristics of electric wheel system, torque ripple of in-wheel motor based on motor module and vector control system is primarily analyzed, and frequency/order features of the torque ripple are discussed. Then quarter vehicle-electric wheel system (QV-EWS) dynamics model based on the rigid ring tire assumption is established and the main parameters of the model are identified according to tire free modal test. Modal characteristics of the model are further analyzed. The analysis indicates that torque excitation of in-wheel motor is prone to arouse horizontal vibration, in which in-phase rotational, anti-phase rotational and horizontal translational modes of electric wheel system mainly participate. Based on the model, vibration responses of the QV-EWS under torque ripple are simulated. The results show that unlike vertical low frequency (lower than 20 Hz) vibration excited by road roughness, broadband torque ripple will arouse horizontal high frequency (50-100 Hz) vibration of electric wheel system due to participation of the three aforementioned modes. To verify the theoretical analysis, the bench experiment of electric wheel system is conducted and vibration responses are acquired. The experiment demonstrates the high frequency vibration phenomenon of electric wheel system and the measured order features as well as main resonant frequencies agree with simulation results. Through theoretical modeling, analysis and experiments this paper reveals and explains the high frequency vibration characteristics of electric wheel system, providing references for the dynamic analysis, optimal design of QV-EWS.

  17. Hydrogen Bonding and Vibrational Spectroscopy: A Theoretical Study

    Science.gov (United States)

    Chaban, Galina M.

    2005-01-01

    Effects of hydrogen bonding on vibrational spectra are studied for several hydrogen-bonded complexes, in which hydrogen bonding ranges from weak (25 kcal/mol). The systems studied include complexes of inorganic acids and salts with water and ammonia, as well as complexes of several organic molecules (nitriles and amino acids) with water. Since anharmonic effects are very strong in hydrogen-bonded systems, anharmonic vibrational frequencies and infrared intensities are computed using the correlation-corrected vibrational self-consistent field (CC-VSCF) method with ab initio potential surfaces at the MP2 and CCSD(T) levels. The most common spectral effects induced by hydrogen bonding are red shifts of stretching vibrational frequencies ranging from approx.200/cm to over 2000/cm and significant increases of infrared intensities for those bonds that participate in hydrogen bonding. However, some systems (e.g. nitrile-water complexes) exhibit shifts in the opposite direction (to the blue) upon formation of hydrogen bonds.

  18. Lattice vibrational modes and their frequency shifts in semiconductor nanowires.

    Science.gov (United States)

    Yang, Li; Chou, M Y

    2011-07-13

    We have performed first-principles calculations to study the lattice vibrational modes and their Raman activities in silicon nanowires (SiNWs). Two types of characteristic vibrational modes are examined: high-frequency optical modes and low-frequency confined modes. Their frequencies have opposite size dependence with a red shift for the optical modes and a blue shift for the confined modes as the diameter of SiNWs decreases. In addition, our calculations show that these vibrational modes can be detected by Raman scattering measurements, providing an efficient way to estimate the size of SiNWs.

  19. Vibrational spectra, theoretical calculations, and structure of 4-silaspiro(3,3)heptane.

    Science.gov (United States)

    Ocola, Esther J; Medders, Cross; Cooke, Joel M; Laane, Jaan

    2014-09-15

    Theoretical computations have been carried out for 4-silaspiro(3,3)heptane (SSH) in order to calculate its structure and vibrational spectra. SSH was found to have two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. The puckering and tilting reduce the D2d symmetry to C2. Nonetheless, the vibrational assignments can be done quite well on the basis of D2d symmetry. This is confirmed by the fact that all but the lowest E vibrations show insignificant splitting into A and B modes of C2 symmetry. However, the observed splittings of the lowest frequency modes do confirm the lower conformational symmetry. The calculated infrared and Raman spectra were compared to the experimental spectra collected for the vapor, liquid, and solid states, and the agreement is excellent. Copyright © 2014 Elsevier B.V. All rights reserved.

  20. Vibrational spectra, theoretical calculations, and structure of 4-silaspiro(3,3)heptane

    Science.gov (United States)

    Ocola, Esther J.; Medders, Cross; Cooke, Joel M.; Laane, Jaan

    2014-09-01

    Theoretical computations have been carried out for 4-silaspiro(3,3)heptane (SSH) in order to calculate its structure and vibrational spectra. SSH was found to have two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. The puckering and tilting reduce the D2d symmetry to C2. Nonetheless, the vibrational assignments can be done quite well on the basis of D2d symmetry. This is confirmed by the fact that all but the lowest E vibrations show insignificant splitting into A and B modes of C2 symmetry. However, the observed splittings of the lowest frequency modes do confirm the lower conformational symmetry. The calculated infrared and Raman spectra were compared to the experimental spectra collected for the vapor, liquid, and solid states, and the agreement is excellent.

  1. Carbon Nanotube-Based Nanomechanical Sensor: Theoretical Analysis of Mechanical and Vibrational Properties

    Directory of Open Access Journals (Sweden)

    Toshiaki Natsuki

    2017-08-01

    Full Text Available This paper reviews the recent research of carbon nanotubes (CNTs used as nanomechanical sensing elements based mainly on theoretical models. CNTs have demonstrated considerable potential as nanomechanical mass sensor and atomic force microscope (AFM tips. The mechanical and vibrational characteristics of CNTs are introduced to the readers. The effects of main parameters of CNTs, such as dimensions, layer number, and boundary conditions on the performance characteristics are investigated and discussed. It is hoped that this review provides knowledge on the application of CNTs as nanomechanical sensors and computational methods for predicting their properties. Their theoretical studies based on the mechanical properties such as buckling strength and vibration frequency would give a useful reference for designing CNTs as nanomechanical mass sensor and AFM probes.

  2. THE THEORETICAL FOUNDATIONS OF VIBRATION DAMPERS BY ROLLING FRICTION

    Directory of Open Access Journals (Sweden)

    L. M. Bondarenko

    2015-06-01

    Full Text Available Purpose. There are some unresolved issues in vibration damping – the lack of engineering calculations for the vibration dampers by rolling friction; the absence of evidence of their application appropriateness. Considering this fact, the authors suggest to prove that the dampers based on rolling friction, are similar in rate of oscillation damping by hydraulic shock absorbers. At the same time, they are easier for the hydraulic design, and easily amenable to manual adjustment, both in automatic and manual mode. Methodology. Fixed techniques of practice in order to determine amplitudes of the oscillations of a shock absorber led to a predetermined result and will apply this theory in the calculation of other vibration dampers. Findings. Analysis of the formulas and graphs leads to the following conclusions and recommendations: 1 the nature of the oscillation damping at vibration dampers by rolling friction is close to their decay in the viscous resistance; 2 when conducting the necessary experiments the shock absorber rolling can be recommended as alternatives to hydraulic ones. The research results of this task will help implement the new trend in reduction of dynamic loads in vehicles. Originality. With the help of theoretical curves to determine the coefficients of rolling friction the dependences for determining the amplitudes of the oscillations in the vertical movement of cargo were obtained. At the same time, the previously proposed analytical dependence for determining the coefficient of rolling friction contains only conventional mechanical constants of the contacting bodies and there geometrical dimensions. Practical value. Due to the existing well-known disadvantages of hydraulic shock absorbers it would be logical to apply shock absorbers that are technologically convenient in manufacturing and easy to adjust the damping rate. The proposed theory can be used in the design of shock absorbers rolling as an alternative to the hydraulic

  3. An experimental-theoretical study of free vibrations of plates on elastic point supports

    Science.gov (United States)

    Leuner, T. R.

    1974-01-01

    A theoretical and experimental study is made to investigate the effect on plate vibrations of varying the stiffness of corner elastic point supports. An experiment is conducted in which the bending stiffness of horizontal beams is used to support a square plate at its four corners. The stiffness of these supports can be varied over such a range that the plate fundamental frequency is lowered to 40% of the rigid support frequency. The variation with support stiffness of the frequencies of the first eight plate modes is measured and is compared with results from a theoretical model in which a Rayleigh-Ritz analysis is used which approximates the plate mode shapes as products of free-free beam modes. The elastic point supports are modeled both as massless translational springs and springs with tip masses, which are included to better represent the experimental supports.

  4. Theoretical methods for small-molecule ro-vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Lodi, Lorenzo; Tennyson, Jonathan, E-mail: j.tennyson@ucl.ac.u [University College London, Department of Physics and Astronomy, Gower Street, London WC1E 6BT (United Kingdom)

    2010-07-14

    The solution of the first principle equations of quantum mechanics provides an increasingly accurate and predictive approach for solving problems involving atoms and small molecules. A general introduction to the methods used for the ab initio calculation of rotational-vibrational spectra of small molecules is presented, with a strong focus on triatomic systems. The use of multi-reference electronic structure methods to compute molecular potential-energy and dipole-moment surfaces is discussed. Issues related to the construction of such surfaces and the inclusion of corrections due to relativistic and non-Born-Oppenheimer effects are reviewed. The derivation of exact, internal-coordinate nuclear-motion-effective Hamiltonians and their solution using a discrete-variable representation are discussed. Sample results for the water molecules are used throughout the tutorial to illustrate the theoretical and numerical issues in such calculations. (phd tutorial)

  5. Capacitance-Based Frequency Adjustment of Micro Piezoelectric Vibration Generator

    Directory of Open Access Journals (Sweden)

    Xinhua Mao

    2014-01-01

    Full Text Available Micro piezoelectric vibration generator has a wide application in the field of microelectronics. Its natural frequency is unchanged after being manufactured. However, resonance cannot occur when the natural frequencies of a piezoelectric generator and the source of vibration frequency are not consistent. Output voltage of the piezoelectric generator will sharply decline. It cannot normally supply power for electronic devices. In order to make the natural frequency of the generator approach the frequency of vibration source, the capacitance FM technology is adopted in this paper. Different capacitance FM schemes are designed by different locations of the adjustment layer. The corresponding capacitance FM models have been established. Characteristic and effect of the capacitance FM have been simulated by the FM model. Experimental results show that the natural frequency of the generator could vary from 46.5 Hz to 42.4 Hz when the bypass capacitance value increases from 0 nF to 30 nF. The natural frequency of a piezoelectric vibration generator could be continuously adjusted by this method.

  6. Low-frequency vibration control of floating slab tracks using dynamic vibration absorbers

    Science.gov (United States)

    Zhu, Shengyang; Yang, Jizhong; Yan, Hua; Zhang, Longqing; Cai, Chengbiao

    2015-09-01

    This study aims to effectively and robustly suppress the low-frequency vibrations of floating slab tracks (FSTs) using dynamic vibration absorbers (DVAs). First, the optimal locations where the DVAs are attached are determined by modal analysis with a finite element model of the FST. Further, by identifying the equivalent mass of the concerned modes, the optimal stiffness and damping coefficient of each DVA are obtained to minimise the resonant vibration amplitudes based on fixed-point theory. Finally, a three-dimensional coupled dynamic model of a metro vehicle and the FST with the DVAs is developed based on the nonlinear Hertzian contact theory and the modified Kalker linear creep theory. The track irregularities are included and generated by means of a time-frequency transformation technique. The effect of the DVAs on the vibration absorption of the FST subjected to the vehicle dynamic loads is evaluated with the help of the insertion loss in one-third octave frequency bands. The sensitivities of the mass ratio of DVAs and the damping ratio of steel-springs under the floating slab are discussed as well, which provided engineers with the DVA's adjustable room for vibration mitigation. The numerical results show that the proposed DVAs could effectively suppress low-frequency vibrations of the FST when tuned correctly and attached properly. The insertion loss due to the attachment of DVAs increases as the mass ratio increases, whereas it decreases with the increase in the damping ratio of steel-springs.

  7. Vibrational and theoretical studies of a sesquiterpene lactone, 11αH-dihydrozaluzanin E

    Science.gov (United States)

    Molina, José R.; Finetti, Mariela; Díaz, Oscar J.; de la Fuente, Juana R.; Jubert, Alicia

    2008-03-01

    Infrared vibrational spectrum of 11αH-dihydrozaluzanin E has been measured at room temperature and it was analyzed theoretically by means of ab initio calculations. The conformational space of the compound has been scanned using molecular dynamics and complemented with functional density calculations that optimize the geometry of the lowest-energy conformers of each species as obtained in the simulations. The vibrational frequencies were assigned using functional density calculations. The Molecular Electrostatic Potential Map (MEP) was obtained and analyzed. Coupling constants were calculated at ab initio level and by means of the Karplus-Calculator method and via the MestRe-J Program, chemical shifts were also calculated at ab initio level and all the results were compared with respect to experimental data. Conclusions are reported on the stereochemistry of the molecule.

  8. Theoretical and experimental study of the vibrational excitations in ethane monolayers adsorbed on graphite (0001) surfaces

    DEFF Research Database (Denmark)

    Hansen, Flemming Yssing; Taub, H.

    1987-01-01

    The collective vibrational excitations of two different crystalline monolayer phases of ethane (C2H6) adsorbed on the graphite (0001) surface have been investigated theoretically and experimentally. The monolayer phases studied are the commensurate 7/8 ×4 structure in which the ethane molecules lie...... on their side in a herringbone arrangement and the commensurate 7/8 × 7/8 structure in which the molecules stand on-end with the C–C bond perpendicular to the surface. Semiempirical atom–atom potentials have been used to model the intermolecular and molecule–substrate interactions in calculations...... of the observed vibrational modes. Moreover, they suggest that an important feature of the herringbone phase dynamics is a coupling of the lowest-frequency librational mode to the vibratory mode perpendicular to the surface. Calculations of the phonon dispersion relations, the phonon density of states...

  9. Low-frequency vibration measurement by a dual-frequency DBR fiber laser

    Science.gov (United States)

    Zhang, Bing; Cheng, Linghao; Liang, Yizhi; Jin, Long; Guo, Tuan; Guan, Bai-Ou

    2017-09-01

    A dual-frequency distributed Bragg reflector (DBR) fiber laser based sensor is demonstrated for low-frequency vibration measurement through the Doppler effect. The response of the proposed sensor is quite linear and is much higher than that of a conventional accelerometer. The proposed sensor can work down to 1 Hz with high sensitivity. Therefore, the proposed sensor is very efficient in low-frequency vibration measurement.

  10. The influence of high-frequency vibrations on derailment stability coefficient of cars at wheel flange climbing on the rail

    Directory of Open Access Journals (Sweden)

    N. Bezrukavyy

    2013-08-01

    Full Text Available Purpose. Taking into account the traffic safety priority on the railway transport the search of factors promoting increase of derailment stability coefficient is an actual task. Purpose of the paper is the influence researches of the high-frequency vibrations on the train traffic safety parameter. In this case the special form of the wheel rim, at which its rigidity changes according to the harmonious law, was considered as a source of vibrations. Methodology. For the analysis of the vibration influence on the change of friction coefficient values the methods of so called vibrational mechanics were used. For determination of vibration amplitudes through moving the wheel flange points the finite-elements method was also used in the paper. Findings. During calculations it was established that the derailment stability coefficient to a great extent depends on the friction coefficient between wheel and rail. The paper shows that the friction coefficient in turn is influenced by the high-frequency vibrations. The form of the wheel rim was considered as a vibration source and the parameters characterizing vibration were calculated. It was given the quantitative estimation of the friction coefficient change under the vibration influence. It was also scientifically based the high-frequency vibration influence on the derailment stability coefficient. Originality. The paper proved the possibility of high-frequency vibration influence on the derailment stability coefficient. The studies theoretically substantiated the traffic safety increase in the presence of vibrations in the contact area of the wheel flange with the rail caused by special form of the wheel disc. Practical value. It is shown that the use of undulating wheel disc form do not constitute a threat to the traffic safety, and the availability of high-frequency vibration can reduce the derailment probability.

  11. Vibrational frequencies in Car-Parrinello molecular dynamics.

    Science.gov (United States)

    Ong, Sheau Wei; Tok, Eng Soon; Kang, Hway Chuan

    2010-12-07

    Car-Parrinello molecular dynamics (CPMD) are widely used to investigate the dynamical properties of molecular systems. An important issue in such applications is the dependence of dynamical quantities such as molecular vibrational frequencies upon the fictitious orbital mass μ. Although it is known that the correct Born-Oppenheimer dynamics are recovered at zero μ, it is not clear how these dynamical quantities are to be rigorously extracted from CPMD calculations. Our work addresses this issue for vibrational frequencies. We show that when the system is sufficiently close to the ground state the calculated ionic vibrational frequencies are ω(M) = ω(0M)[1 -C(μ/M)] for small μ/M, where ω(0M) is the Born-Oppenheimer ionic frequency, M the ionic mass, and C a constant that depends upon the ion-orbital coupling force constants. Our analysis also provides a quantitative understanding of the orbital oscillation amplitudes, leading to a relationship between the adiabaticity of a system and the ion-orbital coupling constants. In particular, we show that there is a significant systematic dependence of calculated vibrational frequencies upon how close the CPMD trajectory is to the Born-Oppenheimer surface. We verify our analytical results with numerical simulations for N(2), Sn(2), and H/Si(100)-(2×1).

  12. Effect of vibration frequency on biopsy needle insertion force.

    Science.gov (United States)

    Tan, Lei; Qin, Xuemei; Zhang, Qinhe; Zhang, Hongcai; Dong, Hongjian; Guo, Tuodang; Liu, Guowei

    2017-05-01

    Needle insertion is critical in many clinical medicine procedures, such as biopsy, brachytherapy, and injection therapy. A platform with two degrees of freedom was set up to study the effect of vibration frequency on needle insertion force. The gel phantom deformation at the needle cutting edge and the Voigt model are utilized to develop a dynamic model to explain the relationship between the insertion force and needle-tip velocity. The accuracy of this model was verified by performing needle insertions into phantom gel. The effect of vibration on insertion force can be explained as the vibration increasing the needle-tip velocity and subsequently increasing the insertion force. In a series of needle insertion experiments with different vibration frequencies, the peak forces were selected for comparison to explore the effect of vibration frequency on needle insertion force. The experimental results indicate that the insertion force at 500Hz increases up to 17.9% compared with the force at 50Hz. Copyright © 2017 IPEM. Published by Elsevier Ltd. All rights reserved.

  13. Gearbox Vibration Signal Amplitude and Frequency Modulation

    Directory of Open Access Journals (Sweden)

    Fakher Chaari

    2012-01-01

    Full Text Available Gearboxes usually run under fluctuating load conditions during service, however most of papers available in the literature describe models of gearboxes under stationary load conditions. Main task of published papers is fault modeling for their detection. Considering real situation from industry, the assumption of stationarity of load conditions cannot be longer kept. Vibration signals issued from monitoring in maintenance operations differ from mentioned models (due to load non-stationarity and may be difficult to analyze which lead to erroneous diagnosis of the system. The objective of this paper is to study the influence of time varying load conditions on a gearbox dynamic behavior. To investigate this, a simple spur gear system without defects is modeled. It is subjected to a time varying load. The speed-torque characteristic of the driving motor is considered. The load variation induces speed variation, which causes a variation in the gearmesh stiffness period. Computer simulation shows deep amplitude modulations with sidebands that don't differ from those obtained when there is a defective tooth. In order to put in evidence the time varying load effects, Short Time Fourier Transform and then Smoothed Wigner-Ville distribution are used. Results show that the last one is well suited for the studied case.

  14. Structure, isomerism, and vibrational assignment of aluminumtrifluoroacetylacetonate. An experimental and theoretical study

    Science.gov (United States)

    Afzali, R.; Vakili, M.; Boluri, E.; Tayyari, S. F.; Nekoei, A.-R.; Hakimi-Tabar, M.; Darugar, V.

    2018-02-01

    An interpretation of the experimental IR and Raman spectra of Aluminum (III) trifluoroacetylacetonate (Al(TFAA)3) complex, which were synthesized by us, is first reported here. The charge distribution, isomerism, strength of metal‑oxygen binding and vibrational spectral properties for this complex structure were theoretically investigated through population analysis, geometry optimization and harmonic frequency calculations, performed at B3LYP/6-311G* level of theory. In the population analysis, two different approaches reffered to as ;Atoms in molecules (AIM);, and ;Natural Bond Orbital (NBO); were used. According to the calculation resuls, the energy difference between the cis and trans isomers of Al(TFAA)3 is very small and indicates that both isomers coexist in the sample in comparable proportions. Comparison of the calculated frequency and intensity data with the observed IR and Raman spectra of the complex has supported this conclusion. On the other hand, comparison of the structural and vibrational spectral data of Al(TFAA)3, which were experimentally measured and calculated at B3LYP/6-311G* level, with the corresponding data of Aluminum acetylacetonate (Al(AA)3) has revealed the effects of CF3 substitution on the structural and vibrational spectral data associated with the CH3 groups in the complex structure.

  15. Analysis of vibration frequency in transversely-isotropic semilinear ...

    African Journals Online (AJOL)

    Analysis of vibration frequency in transversely-isotropic semilinear elastic thin plate. AP Akinola, BA Olokuntoye, OO Fadodun, AS Botokinni. Abstract. No Abstract. Full Text: EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT · AJOL African Journals Online. HOW TO USE ...

  16. Analysis of vibration frequency in transversely-isototropic semilinear ...

    African Journals Online (AJOL)

    Analysis of vibration frequency in transversely-isototropic semilinear elastic thin plate. A.P. Akinola, B.A. Olokuntoye, O.O. Fadodun, A.S. Borokinni. Abstract. No Abstract. Full Text: EMAIL FREE FULL TEXT EMAIL FREE FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT · AJOL African Journals Online.

  17. Vibrational echo spectral observables and frequency fluctuations of ...

    Indian Academy of Sciences (India)

    Home; Journals; Journal of Chemical Sciences; Volume 129; Issue 7. Vibrational echo spectral observables and frequency fluctuations of hydration shell water around a fluoride ion from first principles simulations. DEEPAK OJHA AMALENDU CHANDRA. REGULAR ARTICLE Volume 129 Issue 7 July 2017 pp 1069-1080 ...

  18. Vibrational echo spectral observables and frequency fluctuations of ...

    Indian Academy of Sciences (India)

    Deepak Ojha

    Vibrational echo; frequency fluctuations; hydration shell water; fluoride ion; ab initio molecular dynamics. 1. Introduction. Ions dissolved in liquid water play important roles in several chemical and biological processes.1,2 Simi- larly, water molecules in aqueous ionic solutions exhibit different dynamics in comparison to pure ...

  19. Nonlinear Vibration of Oscillation Systems using Frequency-Amplitude Formulation

    Directory of Open Access Journals (Sweden)

    A. Fereidoon

    2012-01-01

    Full Text Available In this paper we study the periodic solutions of free vibration of mechanical systems with third and fifth-order nonlinearity for two examples using He's Frequency-Amplitude Formulation (HFAF.The effectiveness and convenience of the method is illustrated in these examples. It will be shown that the solutions obtained with current method have a fabulous conformity with those achieved from time marching solution. HFAF is easy with powerful concepts and the high accuracy, so it can be found widely applicable in vibrations, especially strong nonlinearity oscillatory problems.

  20. Theoretical study of molecular structures, vibrational and NMR spectra on azobenzene derivatives

    Science.gov (United States)

    Karakaya, M.; Ucun, F.

    2014-02-01

    In this study, we have calculated the most stable tautomeric forms and their ground state conformers of 2,4-dihydroxyazobenzene and 2,4-dihydroxy-6-methyl-4'-nitroazobenzene molecules. Calculations show that the most preferential tautomeric forms of these molecules are azo form for 2,4-dihydroxyazobenzene and hydrazo form for 2,4-dihydroxy-6-methyl-4'-nitroazobenzene. Vibrational frequencies, 1H and 13C NMR shifts of ground state conformers of stable tautomeric forms of the molecules have been calculated by using density functional theory-B3LYP method with 6-311G(d,p) basis set. All assignments of theoretical frequencies have been performed by potential energy distribution analysis. Calculated spectral results are in a good agreement with the corresponding experimental data.

  1. Frequency Identification of Vibration Signals Using Video Camera Image Data

    Directory of Open Access Journals (Sweden)

    Chia-Hung Wu

    2012-10-01

    Full Text Available This study showed that an image data acquisition system connecting a high-speed camera or webcam to a notebook or personal computer (PC can precisely capture most dominant modes of vibration signal, but may involve the non-physical modes induced by the insufficient frame rates. Using a simple model, frequencies of these modes are properly predicted and excluded. Two experimental designs, which involve using an LED light source and a vibration exciter, are proposed to demonstrate the performance. First, the original gray-level resolution of a video camera from, for instance, 0 to 256 levels, was enhanced by summing gray-level data of all pixels in a small region around the point of interest. The image signal was further enhanced by attaching a white paper sheet marked with a black line on the surface of the vibration system in operation to increase the gray-level resolution. Experimental results showed that the Prosilica CV640C CMOS high-speed camera has the critical frequency of inducing the false mode at 60 Hz, whereas that of the webcam is 7.8 Hz. Several factors were proven to have the effect of partially suppressing the non-physical modes, but they cannot eliminate them completely. Two examples, the prominent vibration modes of which are less than the associated critical frequencies, are examined to demonstrate the performances of the proposed systems. In general, the experimental data show that the non-contact type image data acquisition systems are potential tools for collecting the low-frequency vibration signal of a system.

  2. Vibration modes of injured spine at resonant frequencies under vertical vibration.

    Science.gov (United States)

    Guo, Li-Xin; Zhang, Ming; Zhang, Yi-Min; Teo, Ee-Chon

    2009-09-01

    A detailed three-dimensional finite element model of the spine segment T12-Pelvis was developed to investigate dynamic characteristics of whole lumbar spine with injured cases. This study investigates the motion mechanism of the human lumbar spine and the effect of component injuries on adjacent spinal components under whole body vibration. Several investigations have analyzed the influence of injured spines on adjacent spinal components under static loadings. However, it is not clear how the spine injury affects dynamic characteristics of whole lumbar spine and adjacent components of the injured segment under vibration. The T12-Pelvis model was used to obtain the modal vibration modes of the spine at resonant frequencies. Injury conditions of the spine were simulated and tested, including denucleation and/or facetectomy with removal of capsular ligaments. The results indicate the first-order vertical resonant frequency of the intact model is 7.21 Hz. After the denucleation at L4-L5, it decreases by more than 4% compared with the intact condition. All the injured conditions including disc injury and ligament injury decrease the resonant frequency of the spine. Due to the denucleation at L4-L5 the anteroposterior displacements of the vertebrae from L2 to L5 decrease and the vertical displacements of the vertebrae from L1 to L4 increase under vibration. The denucleation also decreases the rotational deformations of the vertebrae from L1 to L5. The material property sensitivity analysis shows intervertebral discs have a dominating effect on variation of vertical resonant frequency of the spine. The denucleation may decrease cushioning effects of adjacent motion segments at the injured level under vibration. The injured condition may increase the vertical displacement amplitudes of the spine above the injured level. All the injured conditions may decrease the resonant frequency of the spine system.

  3. A Sub-Hertz, Low-Frequency Vibration Isolation Platform

    Science.gov (United States)

    Ortiz, Gerardo, G.; Farr, William H.; Sannibale, Virginio

    2011-01-01

    One of the major technical problems deep-space optical communication (DSOC) systems need to solve is the isolation of the optical terminal from vibrations produced by the spacecraft navigational control system and by the moving parts of onboard instruments. Even under these vibration perturbations, the DSOC transceivers (telescopes) need to be pointed l000 fs of times more accurately than an RF communication system (parabolic antennas). Mechanical resonators have been extensively used to provide vibration isolation for groundbased, airborne, and spaceborne payloads. The effectiveness of these isolation systems is determined mainly by the ability of designing a mechanical oscillator with the lowest possible resonant frequency. The Low-Frequency Vibration Isolation Platform (LFVIP), developed during this effort, aims to reduce the resonant frequency of the mechanical oscillators into the sub-Hertz region in order to maximize the passive isolation afforded by the 40 dB/decade roll-off response of the resonator. The LFVIP also provides tip/tilt functionality for acquisition and tracking of a beacon signal. An active control system is used for platform positioning and for dampening of the mechanical oscillator. The basic idea in the design of the isolation platform is to use a passive isolation strut with an approximately equal to 100-mHz resonance frequency. This will extend the isolation range to lower frequencies. The harmonic oscillator is a second-order lowpass filter for mechanical disturbances. The resonance quality depends on the dissipation mechanisms, which are mainly hysteretic because of the low resonant frequency and the absence of any viscous medium. The LFVIP system is configured using the well-established Stewart Platform, which consists of a top platform connected to a base with six extensible struts (see figure). The struts are attached to the base and to the platform via universal joints, which permit the extension and contraction of the struts. The

  4. Adaptive Semiactive Cable Vibration Control: A Frequency Domain Perspective

    Directory of Open Access Journals (Sweden)

    Z. H. Chen

    2017-01-01

    Full Text Available An adaptive solution to semiactive control of cable vibration is formulated by extending the linear quadratic Gaussian (LQG control from time domain to frequency domain. Frequency shaping is introduced via the frequency dependent weights in the cost function to address the control effectiveness and robustness. The Hilbert-Huang transform (HHT technique is further synthesized for online tuning of the controller gain adaptively to track the cable vibration evolution, which also obviates the iterative optimal gain selection for the trade-off between control performance and energy in the conventional time domain LQG (T-LQG control. The developed adaptive frequency-shaped LQG (AF-LQG control is realized by collocated self-sensing magnetorheological (MR dampers considering the nonlinear damper dynamics for force tracking control. Performance of the AF-LQG control is numerically validated on a bridge cable transversely attached with a self-sensing MR damper. The results demonstrate the adaptivity in gain tuning of the AF-LQG control to target for the dominant cable mode for vibration energy dissipation, as well as its enhanced control efficacy over the optimal passive MR damping control and the T-LQG control for different excitation modes and damper locations.

  5. Vibration of Cracked Circular Plates at Resonance Frequencies

    Science.gov (United States)

    HUANG, CHI-HUNG; MA, CHIEN-CHING

    2000-09-01

    It is well known that the presence of cracks will affect the dynamic characteristics of the vibrating plate. Such a problem is complicated because it combines the field of vibration analysis and fracture mechanics. In this study, an optical system called the AF-ESPI method with the out-of-plane displacement measurement is employed to investigate the vibration characteristics of a free circular plate with a radial crack emanating from the edge. The boundary conditions along the circular edge are free. As compared with the film recording and optical reconstruction procedures used for holographic interferometry, the interferometric fringes of AF-ESPI are produced instantly by a video recording system. Based on the fact that clear fringe patterns will appear only at resonant frequencies, both resonant frequencies and corresponding mode shapes can be obtained experimentally at the same time by the proposed AF-ESPI method. Numerical finite element calculations are also performed and the results are compared with the experimental measurements. Good agreements are obtained for both results. The vibrating mode shapes obtained in this study can be classified into two types, symmetric and antisymmetric modes with respect to the crack line. The influence of crack length on resonant frequencies is also investigated in terms of the dimensionless frequency parameter (λ2) versus crack length ratio (a/D). We find that if the crack face displacement is out of phase, i.e., the antisymmetric type, a large value of stress intensity factor may be induced and the cracked circular plate will be dangerous, from the fracture mechanics point of view. However, there are some resonant frequencies for which the crack face displacements are completely in phase, i.e., the symmetric type, which yields a zero stress intensity factor and the cracked plate will be safe.

  6. Beyond local group modes in vibrational sum frequency generation.

    Science.gov (United States)

    Chase, Hilary M; Psciuk, Brian T; Strick, Benjamin L; Thomson, Regan J; Batista, Victor S; Geiger, Franz M

    2015-04-09

    We combine deuterium labeling, density functional theory calculations, and experimental vibrational sum frequency generation spectroscopy into a form of "counterfactual-enabled molecular spectroscopy" for producing reliable vibrational mode assignments in situations where local group mode approximations are insufficient for spectral interpretation and vibrational mode assignments. We demonstrate the method using trans-β-isoprene epoxydiol (trans-β-IEPOX), a first-generation product of isoprene relevant to atmospheric aerosol formation, and one of its deuterium-labeled isotopologues at the vapor/silica interface. We use our method to determine that the SFG responses that we obtain from trans-β-IEPOX are almost exclusively due to nonlocal modes involving multiple C-H groups oscillating at the same frequency as one vibrational mode. We verify our assignments using deuterium labeling and use DFT calculations to predict SFG spectra of additional isotopologues that have not yet been synthesized. Finally, we use our new insight to provide a viable alternative to molecular orientation analysis methods that rely on local mode approximations in cases where the local mode approximation is not applicable.

  7. Internal resonance and low frequency vibration energy harvesting

    Science.gov (United States)

    Yang, Wei; Towfighian, Shahrzad

    2017-09-01

    A nonlinear vibration energy harvester with internal resonance is presented. The proposed harvester consists of two cantilevers, each with a permanent magnet on its tip. One cantilever has a piezoelectric layer at its base. When magnetic force is applied this two degrees-of-freedom nonlinear vibration system shows the internal resonance phenomenon that broadens the frequency bandwidth compared to a linear system. Three coupled partial differential equations are obtained to predict the dynamic behavior of the nonlinear energy harvester. The perturbation method of multiple scales is used to solve equations. Results from experiments done at different vibration levels with varying distances between the magnets validate the mathematical model. Experiments and simulations show the design outperforms the linear system by doubling the frequency bandwidth. Output voltage for frequency response is studied for different system parameters. The optimal load resistance is obtained for the maximum power in the internal resonance case. The results demonstrate that a design combining internal resonance and magnetic nonlinearity improves the efficiency of energy harvesting.

  8. An Impact-Based Frequency Up-Converting Hybrid Vibration Energy Harvester for Low Frequency Application

    Directory of Open Access Journals (Sweden)

    Zhenlong Xu

    2017-11-01

    Full Text Available In this paper, a novel impact-based frequency up-converting hybrid energy harvester (FUCHEH was proposed. It consisted of a piezoelectric cantilever beam and a driving beam with a magnetic tip mass. A solenoid coil was attached at the end of the piezoelectric beam. This innovative configuration amplified the relative motion velocity between magnet and coil, resulting in an enhancement of the induced electromotive force in the coil. An electromechanical coupling model was developed and a numerical simulation was performed to study the principle of impact-based frequency up-converting. A prototype was fabricated and experimentally tested. The time-domain and frequency-domain analyses were performed. Fast Fourier transform (FFT analysis verified that fundamental frequencies and coupled vibration frequency contributes most of the output voltage. The measured maximum output power was 769.13 µW at a frequency of 13 Hz and an acceleration amplitude of 1 m/s2, which was 3249.4%- and 100.6%-times larger than that of the frequency up-converting piezoelectric energy harvesters (FUCPEH and frequency up-converting electromagnetic energy harvester (FUCEMEH, respectively. The root mean square (RMS voltage of the piezoelectric energy harvester subsystem (0.919 V was more than 16 times of that of the stand-alone PEH (0.055 V. This paper provided a new scheme to improve generating performance of the vibration energy harvester with high resonant frequency working in the low-frequency vibration environment.

  9. Multiple vibrations measurement using phase-sensitive OTDR merged with Mach-Zehnder interferometer based on frequency division multiplexing.

    Science.gov (United States)

    He, Haijun; Shao, Li-Yang; Luo, Bin; Li, Zonglei; Zou, Xihua; Zhang, Zhiyong; Pan, Wei; Yan, Lianshan

    2016-03-07

    A novel measurement scheme for multiple high-frequency vibrations has been demonstrated by combining phase-sensitive optical time domain reflectometry (Ф-OTDR) and Mach-Zehnder interferometer (MZI) based on frequency division multiplexing. The light source is directly launched into the MZI structure, while it was modulated by an acoustic optical modulator (AOM) with a frequency shift of 200 MHz for the Ф-OTDR part. The vibration frequency is obtained by demodulating the interference signal obtained by the MZI structure, while the vibration position is located by Ф-OTDR system. The spatial resolution of 10m is obtained over 3 km sensing fiber. And the detectable vibration frequency reaches up to 40 kHz. Compared to the previous schemes, this system works without dead zone in the detectable frequency range. Furthermore, the frequency spectrum mapping method has been adopted to determine multiple high-frequency vibrations simultaneously. The experimental results prove the concept and match well with the theoretical analysis.

  10. Long-range vibration sensor based on correlation analysis of optical frequency-domain reflectometry signals.

    Science.gov (United States)

    Ding, Zhenyang; Yao, X Steve; Liu, Tiegen; Du, Yang; Liu, Kun; Han, Qun; Meng, Zhuo; Chen, Hongxin

    2012-12-17

    We present a novel method to achieve a space-resolved long- range vibration detection system based on the correlation analysis of the optical frequency-domain reflectometry (OFDR) signals. By performing two separate measurements of the vibrated and non-vibrated states on a test fiber, the vibration frequency and position of a vibration event can be obtained by analyzing the cross-correlation between beat signals of the vibrated and non-vibrated states in a spatial domain, where the beat signals are generated from interferences between local Rayleigh backscattering signals of the test fiber and local light oscillator. Using the proposed technique, we constructed a standard single-mode fiber based vibration sensor that can have a dynamic range of 12 km and a measurable vibration frequency up to 2 kHz with a spatial resolution of 5 m. Moreover, preliminarily investigation results of two vibration events located at different positions along the test fiber are also reported.

  11. High Frequency Longitudinal Damped Vibrations of a Cylindrical Ultrasonic Transducer

    Directory of Open Access Journals (Sweden)

    Mihai Valentin Predoi

    2014-01-01

    Full Text Available Ultrasonic piezoelectric transducers used in classical nondestructive testing are producing in general longitudinal vibrations in the MHz range. A simple mechanical model of these transducers would be very useful for wave propagation numerical simulations, avoiding the existing complicated models in which the real components of the transducer are modeled by finite elements. The classical model for longitudinal vibrations is not adequate because the generated longitudinal wave is not dispersive, the velocity being the same at any frequency. We have adopted the Rayleigh-Bishop model, which avoids these limitations, even if it is not converging to the first but to the second exact longitudinal mode in an elastic rod, as obtained from the complicated Pochhammer-Chree equations. Since real transducers have significant vibrations damping, we have introduced a damping term in the Rayleigh-Bishop model, increasing the imaginary part and keeping almost identical real part of the wavenumber. Common transducers produce amplitude modulated signals, completely attenuated after several periods. This can be modeled by two close frequencies, producing a “beat” phenomenon, superposed on the high damping. For this reason, we introduce a two-rod Rayleigh-Bishop model with damping. Agreement with measured normal velocity on the transducer free surface is encouraging for continuation of the research.

  12. A Novel Dual–Parallelogram Passive Rocking Vibration Isolator: A Theoretical Investigation and Experiment

    Directory of Open Access Journals (Sweden)

    Shuai Wang

    2017-04-01

    Full Text Available Vibration isolators with quasi-zero stiffness (QZS perform well for low- or ultra-low-frequency vibration isolation. This paper proposes a novel dual-parallelogram passive rocking vibration isolator with QZS that could effectively attenuate in-plane disturbances with low-frequency vibration. First, a kinematic model of the proposed vibration isolator was established and four linear spring configuration schemes were developed to implement the QZS. Next, an optimal scheme with good high-static-low-dynamic stiffness (HSLDS performance was obtained through comparison and analysis, and used as a focus for the QZS model. Subsequently, a dynamic model-based Lagrangian equation that considered the spring stiffness and damping and the influence of the payload gravity center on the vibration isolation system was developed, and an average approach was used to analyze the vibration transmissibility. Finally, the prototype and test system were constructed. A comparison of the simulation and experimental results showed that this novel passive rocking vibration isolator could bolster a heavy payload. Experimentally, the vibration amplitude decreased by 53% and 86% under harmonic disturbances of 0.08 Hz and 0.35 Hz, respectively, suggesting the great practical applicability of this presented vibration isolator.

  13. Synthesis, experimental and theoretical vibrational studies of 1 ...

    Indian Academy of Sciences (India)

    M Drai

    DMPrIM. +][(CF3SO2)2N. −]). The under- standing of the vibrational structures is important to explain the influence of the methyl group at C2 posi- tion (effect of methylation) between the two synthesized. ILs. For this purpose, experimental and ...

  14. Experimental and theoretical investigation of passive damping concepts for member forced and free vibration

    Science.gov (United States)

    Razzaq, Zia; Mykins, David W.

    1987-01-01

    Potential passive damping concepts for use in space structures are identified. The effectiveness of copper brush, wool swab, and silly putty in chamber dampers is investigated through natural vibration tests on a tubular aluminum member. The member ends have zero translation and possess partial rotational restraints. The silly putty in chamber dampers provide the maximum passive damping efficiency. Forced vibration tests are then conducted with one, two, and three damper chambers containing silly putty. Owing to the limitation of the vibrator used, the performance of these dampers could not be evaluated experimentally until the forcing function was disengaged. Nevertheless, their performance is evaluated through a forced dynamic finite element analysis conducted as a part of this investigation. The theoretical results based on experimentally obtained damping ratios indicate that the passive dampers are considerably more effective under member natural vibration than during forced vibration. Also, the maximum damping under forced vibration occurs at or near resonance.

  15. Nature of the Frequency Shift of Hydrogen Valence Vibrations

    CERN Document Server

    Zhyganiuk, I V

    2015-01-01

    The physical nature of a frequency shift of hydrogen valence vibrations in a water molecule due to its interaction with neighbor molecules has been studied. Electrostatic forces connected with the multipole moments of molecules are supposed to give a dominating contribution to the intermolecular interaction. The frequency shift was calculated in the case where two neighbor molecules form a dimer. The obtained result is in qualitative agreement with the frequency shifts observed for water vapor, hexagonal ice, and liquid water, as well as for aqueous solutions of alcohols. This fact testifies to the electrostatic nature of H-bonds used to describe both the specific features of the intermolecular interaction in water and the macroscopic properties of the latter.

  16. Theoretical study of the infrared frequencies of crystalline methyl acetate under interstellar medium conditions

    Science.gov (United States)

    Narayanan, Radhika; Inomata, Kensuke; Gopakumar, Geetha; Sivaraman, Bhalamurugan; Zempo, Yasunari; Hada, Masahiko

    2016-01-01

    Identification of methyl acetate in the interstellar medium (ISM) and its spectroscopic studies have prompted us to investigate the structure of crystalline methyl acetate using numerical calculations. Here, we present a theoretical study of the structure of crystalline methyl acetate and its isotopologues and compare the calculated infrared (IR) spectra with the available experimental data. The optimized structure and vibrational properties were calculated using SIESTA software at 0 K. In the optimization process, the Perdew-Burke-Ernzerhof functional and conjugate gradient methods were used with double zeta polarization basis functions. After optimization of the periodic structure, the vibrational frequencies and normal modes were calculated within the harmonic approximation. Using the calculated results, we refine the mode assignments of experimental work on crystalline methyl acetate and determine the low frequency modes (below 650 cm- 1). To investigate the accuracy of the pseudopotential and confirm the IR frequencies, we performed molecular calculations using a periodic model of methyl acetate and its isotopologues using SIESTA and compared them with results obtained from Gaussian 09 (all electron method) calculations. Finally, we assigned the vibrational modes of crystalline CD3-COO-CH3 and CH3-COO-CD3, for which experimental data are not available in the crystalline phase under ISM conditions. For all of the calculation methods, the IR vibrational modes of molecular and crystalline methyl acetate and its isotopologues were in good agreement with the available experimental data and predict the unavailable values.

  17. High force vibration testing with wide frequency range

    Science.gov (United States)

    Romero, Edward F.; Jepsen, Richard A.; Gregory, Danny Lynn

    2013-04-02

    A shaker assembly for vibration testing includes first and second shakers, where the first shaker includes a piezo-electric material for generating vibration. A support structure permits a test object to be supported for vibration of the test object by both shakers. An input permits an external vibration controller to control vibration of the shakers.

  18. Review of sensors for low frequency seismic vibration measurement

    CERN Document Server

    Collette, C; Janssens, S; Artoos, K; Guinchard, M; Hauviller, C

    2011-01-01

    The objective of this report is to review the main different types of sensors used to measure seismic vibrations at low frequencies. After some basic background preliminaries, the main different types of relative measurements are first reviewed. Then, the following inertial sensors are treated: geophones, accelerometers and broadband seismometers. For each of these sensors, the basic working principle is explained, along with the main performances limitations. Each section ends with a tentative comparison of some commercial products, far from being exhaustive, but hopefully representative of the average characteristics of each family of sensors. The report finishes with a brief discussion on the modelling and measurement of the sensor noise

  19. Frequency Up-Converted Low Frequency Vibration Energy Harvester Using Trampoline Effect

    Science.gov (United States)

    Ju, S.; Chae, S. H.; Choi, Y.; Jun, S.; Park, S. M.; Lee, S.; Lee, H. W.; Ji, C.-H.

    2013-12-01

    This paper presents a non-resonant vibration energy harvester based on magnetoelectric transduction mechanism and mechanical frequency up-conversion using trampoline effect. The harvester utilizes a freely movable spherical permanent magnet which bounces off the aluminum springs integrated at both ends of the cavity, achieving frequency up-conversion from low frequency input vibration. Moreover, bonding method of magnetoelectric laminate composite has been optimized to provide higher strain to piezoelectric material and thus obtain a higher output voltage. A proof-of-concept energy harvesting device has been fabricated and tested. Maximum open-circuit voltage of 11.2V has been obtained and output power of 0.57μW has been achieved for a 50kΩ load, when the fabricated energy harvester was hand-shaken.

  20. Distributed measurement of acoustic vibration location with frequency multiplexed phase-OTDR

    Science.gov (United States)

    Iida, Daisuke; Toge, Kunihiro; Manabe, Tetsuya

    2017-07-01

    All-fiber distributed vibration sensing is attracting attention in relation to structural health monitoring because it is cost effective, offers high coverage of the monitored area and can detect various structural problems. And in particular the demand for high-speed vibration sensing operating at more than 10 kHz has increased because high frequency vibration indicates high energy and severe trouble in the monitored object. Optical fiber vibration sensing with phase-sensitive optical time domain reflectometry (phase-OTDR) has long been studied because it can be used for distributed vibration sensing in optical fiber. However, pulse reflectometry such as OTDR cannot measure high-frequency vibration whose cycle is shorter than the repetition time of the OTDR. That is, the maximum detectable frequency depends on fiber length. In this paper, we describe a vibration sensing technique with frequency-multiplexed OTDR that can detect the entire distribution of a high-frequency vibration thus allowing us to locate a high-speed vibration point. We can measure the position, frequency and dynamic change of a high-frequency vibration whose cycle is shorter than the repetition time. Both frequency and position are visualized simultaneously for a 5-km fiber with an 80-kHz frequency response and a 20-m spatial resolution.

  1. Instantaneous pair theory for high-frequency vibrational energy relaxation in fluids

    Science.gov (United States)

    Larsen, Ross E.; Stratt, Richard M.

    1999-01-01

    Notwithstanding the long and distinguished history of studies of vibrational energy relaxation, exactly how it is that high frequency vibrations manage to relax in a liquid remains somewhat of a mystery. Both experimental and theoretical approaches seem to say that there is a natural frequency range associated with intermolecular motion in liquids, typically spanning no more than a few hundred cm-1. Landau-Teller-type theories explain rather easily how a solvent can absorb any vibrational energy within this "band," but how is it that molecules can rid themselves of superfluous vibrational energies significantly in excess of these values? In this paper we develop a theory for such processes based on the idea that the crucial liquid motions are those that most rapidly modulate the force on the vibrating coordinate — and that by far the most important of these motions are those involving what we have called the mutual nearest neighbors of the vibrating solute. Specifically, we suggest that whenever there is a single solvent molecule sufficiently close to the solute that the solvent and solute are each other's nearest neighbors, then the instantaneous scattering dynamics of the solute-solvent pair alone suffices to explain the high-frequency relaxation. This highly reduced version of the dynamics has implications for some of the previous theoretical formulations of this problem. Previous instantaneous-normal-mode theories allowed us to understand the origin of a band of liquid frequencies, and even had some success in predicting relaxation within this band, but lacking a sensible picture of the effects of liquid anharmonicity on dynamics, were completely unable to treat higher frequency relaxation. When instantaneous-normal-mode dynamics is used to evaluate the instantaneous pair theory, though, we end up with a multiphonon picture of the relaxation which is in excellent agreement with the exact high-frequency dynamics — suggesting that the critical anharmonicity

  2. Deviations of frequency and the mode of vibration of commercially available whole-body vibration training devices.

    Science.gov (United States)

    Kaeding, T S

    2015-06-01

    Research in the field of whole body vibration (WBV) training and the use of it in practice might be hindered by the fact that WBV training devices generate and transmit frequencies and/or modes of vibration which are different to preset adjustments. This research project shall clarify how exact WBV devices apply the by manufacturer information promised preset frequency and mode of vibration. Nine professional devices for WBV training were tested by means of a tri-axial accelerometer. The accelerations of each device were recorded under different settings with a tri-axial accelerometer. Beneath the measurement of different combinations of preset frequency and amplitude the repeatability across 3 successive measurements with the same preset conditions and one measurement under loaded condition were carried out. With 3 exceptions (both Board 3000 & srt medical PRO) we did not find noteworthy divergences between preset and actual applied frequencies. In these 3 devices we found divergences near -25%. Loading the devices did not affect the applied frequency or mode of vibration. There were no important divergences measurable for the applied frequency and mode of vibration regarding repeatability. The results of our measurements cannot be generalized as we only measured one respectively at most two devices of one model in terms of a random sample. Based on these results we strongly recommend that user in practice and research should analyse their WBV training devices regarding applied frequency and mode of vibration.

  3. Natural vibration frequencies of horizontal tubes partially filled with liquid

    Science.gov (United States)

    Santisteban Hidalgo, Juan Andrés; Gama, Antonio Lopes; Moreira, Roger Matsumoto

    2017-11-01

    This work presents an experimental and numerical study on the flexural vibration of horizontal circular tubes partially filled with liquid. The tube is configured as a free-free beam with attention being directed to the case of small amplitudes of transverse oscillation whereas the axial movements of the tube and liquid are disregarded. At first vertical and horizontal polarizations of the flexural tube are investigated experimentally for different amounts of filling liquid. In contrast with the empty and fully-filled tubes, it is observed that natural frequencies of the vertical and horizontal polarizations are different due to asymmetry induced by the liquid layer, which acts like an added mass. Less mass of liquid is added to the tube when oscillating horizontally; as a consequence, eigenfrequencies for the horizontal polarization are found to be greater than the case of the vertically polarized tube. A simple method to calculate the natural vibration frequencies using coefficients of added mass of liquid is proposed. It is shown that the added mass coefficient increases with the liquid's level and viscosity. At last a numerical investigation of the interaction between the liquid and the tube is carried out by solving in two-dimensions the full Navier-Stokes equations via a finite volume method, with the free-surface flow being modeled with a homogeneous multiphase Eulerian-Eulerian fluid approach. Vertical and horizontal polarizations are imposed to the tube with pressure and shear stresses being determined numerically to assess the liquid's forcing onto the tube's wall. The coefficient of added mass of liquid is then estimated by the ratio between the resulting force and the acceleration imposed to the wall. A good agreement is found between experimental and numerical results, especially for the horizontally oscillating tube. It is also shown that viscosity can noticeably affect the added mass coefficients, particularly at low filling levels.

  4. Smart nanocoated structure for energy harvesting at low frequency vibration

    Science.gov (United States)

    Sharma, Sudhanshu

    Increasing demands of energy which is cleaner and has an unlimited supply has led development in the field of energy harvesting. Piezoelectric materials can be used as a means of transforming ambient vibrations into electrical energy that can be stored and used to power other devices. With the recent surge of micro scale devices, piezoelectric power generation can provide a convenient alternative to traditional power sources. In this research, a piezoelectric power generator composite prototype was developed to maximize the power output of the system. A lead zirconate titanate (PZT) composite structure was formed and mounted on a cantilever bar and was studied to convert vibration energy of the low range vibrations at 30 Hz--1000 Hz. To improve the performance of the PZT, different coatings were made using different percentage of Ferrofluid (FNP) and Zinc Oxide nanoparticles (ZnO) and binder resin. The optimal coating mixture constituent percentage was based on the performance of the composite structure formed by applying the coating on the PZT. The fabricated PZT power generator composite with an effective volume of 0.062 cm3 produced a maximum of 44.5 μW, or 0.717mW/cm3 at its resonant frequency of 90 Hz. The optimal coating mixture had the composition of 59.9%FNP + 40% ZnO + 1% Resin Binder. The coating utilizes the opto-magneto-electrical properties of ZnO and Magnetic properties of FNP. To further enhance the output, the magneto-electric (ME) effect was increased by subjecting the composite to magnetic field where coating acts as a magnetostrictive material. For the effective volume of 0.0062 cm 3, the composite produced a maximum of 68.5 μW, or 1.11mW/cm 3 at its resonant frequency of 90 Hz at 160 gauss. The optimal coating mixture had the composition of 59.9% FNP + 40% ZnO + 1% Resin Binder. This research also focused on improving the efficiency of solar cells by utilizing the magnetic effect along with gas plasma etching to improve the internal reflection

  5. Damping heat coefficient - Theoretical and experimental research on a vibrating beam

    Science.gov (United States)

    Mihalec, Marko; Javh, Jaka; Cianetti, Filippo; Moretti, Michele; Rossi, Gianluca; Slavič, Janko; Boltežar, Miha

    2017-07-01

    Vibrating systems dissipate their vibrational energy through different mechanisms, commonly referred to as damping. Damping converts the vibrational energy into other forms, such as heat and sound radiation. Heating of the material is often assumed to be one of the biggest drains of energy; however, the measurable temperature increase is at the level of milli Kelvin and hard to measure. This research introduces a damping heat coefficient, the coefficient of total dissipated energy that is converted into heat. Using this coefficient, the expected temperature change of a beam is theoretically related to its damping ratio. In addition, the damping heat coefficient is determined experimentally by measuring the temperature increase of a vibrating beam. Based on modal damping, it is shown that different amounts of energy are dissipated at different parts of the structure. The numerical heat model was experimentally confirmed.

  6. High Frequency Vibration Based Fatigue Testing of Developmental Alloys

    Science.gov (United States)

    Holycross, Casey M.; Srinivasan, Raghavan; George, Tommy J.; Tamirisakandala, Seshacharyulu; Russ, Stephan M.

    Many fatigue test methods have been previously developed to rapidly evaluate fatigue behavior. This increased test speed can come at some expense, since these methods may require non-standard specimen geometry or increased facility and equipment capability. One such method, developed by George et al, involves a base-excited plate specimen driven into a high frequency bending resonant mode. This resonant mode is of sufficient frequency (typically 1200 to 1700 Hertz) to accumulate 107 cycles in a few hours. One of the main limitations of this test method is that fatigue cracking is almost certainly guaranteed to be surface initiated at regions of high stress. This brings into question the validity of the fatigue test results, as compared to more traditional uniaxial, smooth-bar testing, since high stresses are subjecting only a small volume to fatigue damage. This limitation also brings into question the suitability of this method to screen developmental alloys, should their initiation life be governed by subsurface flaws. However, if applicable, the rapid generation of fatigue data using this method would facilitate faster design iterations, identifying more quickly, material and manufacturing process deficiencies. The developmental alloy used in this study was a powder metallurgy boron-modified Ti-6Al-4V, a new alloy currently being considered for gas turbine engine fan blades. Plate specimens were subjected to fully reversed bending fatigue. Results are compared with existing data from commercially available Ti-6Al-4V using both vibration based and more traditional fatigue test methods.

  7. Frequencies in the Vibration Induced by the Rotor Stator Interaction in a Centrifugal Pump Turbine

    DEFF Research Database (Denmark)

    Rodriguez, Cristian; Egusquiza, Eduard; Santos, Ilmar

    2007-01-01

    The highest vibration levels in large pump turbines are, in general, originated in the rotor stator interaction (RSI). This vibration has specific characteristics that can be clearly observed in the frequency domain: harmonics of the moving blade passing frequency and a particular relationship am...

  8. Micro-scale piezoelectric vibration energy harvesting: From fixed-frequency to adaptable-frequency devices

    Science.gov (United States)

    Miller, Lindsay Margaret

    hundred milliwatts and are falling steadily as improvements are made, it is feasible to use energy harvesting to power WSNs. This research begins by presenting the results of a thorough survey of ambient vibrations in the machine room of a large campus building, which found that ambient vibrations are low frequency, low amplitude, time varying, and multi-frequency. The modeling and design of fixed-frequency micro scale energy harvesters are then presented. The model is able to take into account rotational inertia of the harvester's proof mass and it accepts arbitrary measured acceleration input, calculating the energy harvester's voltage as an output. The fabrication of the micro electromechanical system (MEMS) energy harvesters is discussed and results of the devices harvesting energy from ambient vibrations are presented. The harvesters had resonance frequencies ranging from 31 - 232 Hz, which was the lowest reported in literature for a MEMS device, and produced 24 pW/g2 - 10 nW/g2 of harvested power from ambient vibrations. A novel method for frequency modification of the released harvester devices using a dispenser printed mass is then presented, demonstrating a frequency shift of 20 Hz. Optimization of the MEMS energy harvester connected to a resistive load is then presented, finding that the harvested power output can be increased to several microwatts with the optimized design as long as the driving frequency matches the harvester's resonance frequency. A framework is then presented to allow a similar optimization to be conducted with the harvester connected to a synchronously switched pre-bias circuit. With the realization that the optimized energy harvester only produces usable amounts of power if the resonance frequency and driving frequency match, which is an unrealistic situation in the case of ambient vibrations which change over time and are not always known a priori, an adaptable-frequency energy harvester was designed. The adaptable-frequency harvester

  9. Ab Initio Potential Energy Surfaces and the Calculation of Accurate Vibrational Frequencies

    Science.gov (United States)

    Lee, Timothy J.; Dateo, Christopher E.; Martin, Jan M. L.; Taylor, Peter R.; Langhoff, Stephen R. (Technical Monitor)

    1995-01-01

    Due to advances in quantum mechanical methods over the last few years, it is now possible to determine ab initio potential energy surfaces in which fundamental vibrational frequencies are accurate to within plus or minus 8 cm(exp -1) on average, and molecular bond distances are accurate to within plus or minus 0.001-0.003 Angstroms, depending on the nature of the bond. That is, the potential energy surfaces have not been scaled or empirically adjusted in any way, showing that theoretical methods have progressed to the point of being useful in analyzing spectra that are not from a tightly controlled laboratory environment, such as vibrational spectra from the interstellar medium. Some recent examples demonstrating this accuracy will be presented and discussed. These include the HNO, CH4, C2H4, and ClCN molecules. The HNO molecule is interesting due to the very large H-N anharmonicity, while ClCN has a very large Fermi resonance. The ab initio studies for the CH4 and C2H4 molecules present the first accurate full quartic force fields of any kind (i.e., whether theoretical or empirical) for a five-atom and six-atom system, respectively.

  10. Numerical Analysis of the Influence of Low Frequency Vibration on Bubble Growth.

    Science.gov (United States)

    Han, D; Kedzierski, Mark A

    2017-01-01

    Numerical simulation of bubble growth during pool boiling under the influence of low frequency vibration was performed to understand the influence of common vibrations such as those induced by wind, highway transportation, and nearby mechanical devices on the performance of thermal systems that rely on boiling. The simulations were done for saturated R123 boiling at 277.6 K with a 15 K wall superheat. The numerical volume-of-fluid method (fixed grid) was used to define the liquid-vapor interface. The basic bubble growth characteristics including the bubble departure diameter and the bubble departure time were determined as a function of the bubble contact angle (20°-80°), the vibration displacement (10 µm-50 µm), the vibration frequency (5 Hz-25 Hz), and the initial vibration direction (positive or negative). The bubble parameters were shown to be strongly dependent on the bubble contact angle at the surface. For example, both the bubble departure diameter and the bubble departure time increased with the contact angle. At the same vibration frequency and the initial vibration direction, the bubble departure diameter and the bubble departure time both decreased with increasing vibration displacement. In addition, the vibration frequency had a greater effect on the bubble growth characteristics than did the vibration displacement. The vibration frequency effect was strongly influenced by the initial vibration direction. The pressure contour, the volume fraction of vapor phase, the temperature profile, and the velocity vector were investigated to understand these dynamic bubble behaviors. The limitation of the computational fluid dynamics approach was also described.

  11. An Information-Theoretic Approach for Indirect Train Traffic Monitoring Using Building Vibration

    Directory of Open Access Journals (Sweden)

    Susu Xu

    2017-05-01

    Full Text Available This paper introduces an indirect train traffic monitoring method to detect and infer real-time train events based on the vibration response of a nearby building. Monitoring and characterizing traffic events are important for cities to improve the efficiency of transportation systems (e.g., train passing, heavy trucks, and traffic. Most prior work falls into two categories: (1 methods that require intensive labor to manually record events or (2 systems that require deployment of dedicated sensors. These approaches are difficult and costly to execute and maintain. In addition, most prior work uses dedicated sensors designed for a single purpose, resulting in deployment of multiple sensor systems. This further increases costs. Meanwhile, with the increasing demands of structural health monitoring, many vibration sensors are being deployed in commercial buildings. Traffic events create ground vibration that propagates to nearby building structures inducing noisy vibration responses. We present an information-theoretic method for train event monitoring using commonly existing vibration sensors deployed for building health monitoring. The key idea is to represent the wave propagation in a building induced by train traffic as information conveyed in noisy measurement signals. Our technique first uses wavelet analysis to detect train events. Then, by analyzing information exchange patterns of building vibration signals, we infer the category of the events (i.e., southbound or northbound train. Our algorithm is evaluated with an 11-story building where trains pass by frequently. The results show that the method can robustly achieve a train event detection accuracy of up to a 93% true positive rate and an 80% true negative rate. For direction categorization, compared with the traditional signal processing method, our information-theoretic approach reduces categorization error from 32.1 to 12.1%, which is a 2.5× improvement.

  12. Theoretical analysis based on fundamental functions of thin plate and experimental measurement for vibration characteristics of a plate coupled with liquid

    Science.gov (United States)

    Liao, Chan-Yi; Wu, Yi-Chuang; Chang, Ching-Yuan; Ma, Chien-Ching

    2017-04-01

    This study combined theoretical, experimental, and numerical analysis to investigate the vibration characteristics of a thin rectangular plate positioned horizontally at the bottom of a rectangular container filled with liquid. Flow field pressure was derived using an equation governing the behavior of incompressible fluids. Analytic solutions to vibrations in a thin plate in air served as the fundamental function of the thin plate coupled with liquid. We then used liquid pressure, and the out-of-plane deflection of the thin plate for the construction of frequency response functions for the analysis of vibration characteristics in the liquid-plate coupling system. Two experimental methods were employed to measure the vibration characteristics of the thin plate immersed in water. The first involved using sensors of polyvinylidene difluoride (PVDF) to measure transient signals of fluid-plate system subjected an impact at the thin plate. These were then converted to the frequency domain in order to obtain the resonant frequencies of the fluid-plate coupling system. The second method was amplitude-fluctuation electronic speckle pattern interferometry (AF-ESPI), which was used to measure the dynamic characteristics of the thin plate in the flow field. This method was paired with the image processing techniques, temporal speckle pattern interferometry (TSPI) and temporal standard deviation (TSTD), to obtain clear mode shapes of the thin plate and resonant frequencies. Comparison of the results from theoretical analysis, finite element method, and experimental measurements confirmed the accuracy of our theoretical analysis, which was superior to the conventional approach based on beam mode shape functions. The experimental methods proposed in this study can be used to measure the resonant frequencies of underwater thin plates, and clear mode shapes can be obtained using AF-ESPI. Our results indicate that the resonant frequencies of thin plates underwater are lower than

  13. Effect of Frequency and Vibration Time on Shaker Performance for Mechanized Harvesting of Orange (Thomson cultivar

    Directory of Open Access Journals (Sweden)

    H Ghorbanpour

    2012-09-01

    Full Text Available Manual citrus harvesting is commonly performing hard, expensive and time consuming. In this study, a factorial experiment with a completely randomized design in three replications was performed to find out the effect of frequency (three levels of 5, 7.5 and 10 Hz, vibration time (three levels of 10, 15 and 20 seconds on harvesting capacity and losses of Thomson cultivar of orange. The results indicated that the effect of frequency and vibration time was significant (P≤0.01 on the harvesting capacity and losses, but their interaction effects weren’t significant. The harvesting capacity significantly increased by increasing frequency, and the highest harvesting capacity was 62.8 % at 10 Hz frequency. Although the harvesting capacity increased by increasing the vibration time, but there was no significant difference in vibration times between 15 and 20 seconds at 10 Hz frequency. Also the fruit loss was increased by increasing the vibration time. Due to these reasons, frequency of 10 Hz and vibration time of 15 seconds were selected as the most suitable condition for mechanized harvesting of this cultivar of orange. Finally a linear mathematical model was developed based on the frequency and vibration time for the harvesting capacity and fruit loss of Thomson cultivar of orange.

  14. Older Age Is Associated with Lower Optimal Vibration Frequency in Lower-Limb Muscles During Whole-Body Vibration.

    Science.gov (United States)

    Carlucci, Flaminia; Orlando, Giorgio; Haxhi, Jonida; Laudani, Luca; Giombini, Arrigo; Macaluso, Andrea; Pigozzi, Fabio; Sacchetti, Massimo

    2015-07-01

    The aim of this study was to compare the optimal vibration frequency (OVF), which corresponds to maximal electromyographic muscle response during whole-body vibration, between young, middle-aged, and older women in four muscles of the lower-limbs. OVF was measured as the frequency corresponding to maximal root mean square of the surface electromyogram (RMSmax) during a continuous incremental protocol, with a succession of vibration frequencies from 20 to 55 Hz (A = 2 mm), on the vastus lateralis, vastus medialis, rectus femoris, and gastrocnemius lateralis muscles of the dominant lower-limb. Seventy-eight women were divided into three age groups, that is, young, 21.6 ± 2.4 yrs; middle aged, 43.0 ± 5.2 yrs; and older, 74.2 ± 6.0 yrs. OVF in the vastus medialis was lower in the older women than in the middle-aged and young women, whereas OVF in the vastus lateralis was lower in the older than in the young women. There were no differences in OVF between muscles within each group. RMSmax was higher in the older than in the young women in all muscles. Age range should be taken into consideration when determining OVF because it decreases with age. Properly individualizing the vibration protocol might greatly influence neuromuscular effects of vibration training.

  15. Molecular structures and vibrational frequencies of xanthine and its methyl derivatives (caffeine and theobromine) by ab initio Hartree-Fock and density functional theory calculations

    Science.gov (United States)

    Ucun, Fatih; Sağlam, Adnan; Güçlü, Vesile

    2007-06-01

    The molecular structures, vibrational frequencies and corresponding vibrational assignments of xanthine and its methyl derivatives (caffeine and theobromine) have been calculated using ab initio Hartree-Fock (HF) and density functional theory (B3LYP) methods with 6-31G(d, p) basis set level. The calculations were utilized to the CS symmetries of the molecules. The obtained vibrational frequencies and optimised geometric parameters (bond lengths and bond angles) were seen to be well agreement with the experimental data. The used scale factors which have been obtained the ratio of the frequency values of the strongest peaks in the calculated and experimental spectra seem to cause the gained vibrations well corresponding to the experimental ones. Theoretical infrared intensities and Raman activities are also reported.

  16. Contact area affects frequency-dependent responses to vibration in the peripheral vascular and sensorineural systems.

    Science.gov (United States)

    Krajnak, Kristine; Miller, G R; Waugh, Stacey

    2018-01-01

    Repetitive exposure to hand-transmitted vibration is associated with development of peripheral vascular and sensorineural dysfunctions. These disorders and symptoms associated with it are referred to as hand-arm vibration syndrome (HAVS). Although the symptoms of the disorder have been well characterized, the etiology and contribution of various exposure factors to development of the dysfunctions are not well understood. Previous studies performed using a rat-tail model of vibration demonstrated that vascular and peripheral nervous system adverse effects of vibration are frequency-dependent, with vibration frequencies at or near the resonant frequency producing the most severe injury. However, in these investigations, the amplitude of the exposed tissue was greater than amplitude typically noted in human fingers. To determine how contact with vibrating source and amplitude of the biodynamic response of the tissue affects the risk of injury occurring, this study compared the influence of frequency using different levels of restraint to assess how maintaining contact of the tail with vibrating source affects the transmission of vibration. Data demonstrated that for the most part, increasing the contact of the tail with the platform by restraining it with additional straps resulted in an enhancement in transmission of vibration signal and elevation in factors associated with vascular and peripheral nerve injury. In addition, there were also frequency-dependent effects, with exposure at 250 Hz generating greater effects than vibration at 62.5 Hz. These observations are consistent with studies in humans demonstrating that greater contact and exposure to frequencies near the resonant frequency pose the highest risk for generating peripheral vascular and sensorineural dysfunction.

  17. Theoretical Vibration Analysis Regarding Excitation due to Elliptical Shaft Journals in Sleeve Bearings of Electrical Motors

    OpenAIRE

    Ulrich Werner

    2012-01-01

    This paper shows a theoretical vibration analysis regarding excitation due to elliptical shaft journals in sleeve bearings of electrical motors, based on a simplified rotordynamic model. It is shown that elliptical shaft journals lead to kinematic constraints regarding the movement of the shaft journals on the oil film of the sleeve bearings and therefore to an excitation of the rotordynamic system. The solution of the linear differential equation system leads to the mathematical description ...

  18. Electromyographic assessment of muscle fatigue during isometric vibration training at varying frequencies.

    Science.gov (United States)

    Mischi, M; Rabotti, C; Cardinale, M

    2010-01-01

    Resistance exercise is essential to improve or maintain muscle performance. Vibration training has been suggested as an alternative option for muscle conditioning, aiming especially at improving muscle strength and power. Several studies link the effects of vibration training to enhanced neuromuscular stimulation, measured by electromyography (EMG) and typically ascribed to involuntary reflex mechanisms. However, the underlying mechanisms are still unclear, limiting the use of vibration training. This paper proposes additional methods to analyze the mechanisms involved in vibration training. A dedicated measurement setup was realized to relate vibration parameters to muscle fatigue in the biceps brachii. Fatigue is estimated by EMG mean frequency and conduction velocity assessments as well as by maximum voluntary contraction (MVC) force measurements. A modified maximum likelihood algorithm is proposed for the conduction velocity estimation based on high-density EMG recording. Five volunteers performed four isometric contractions of 50 s at 80% MVC with no vibration (control) and with superimposed vibration at 20, 30, and 40 Hz. Fatigue was estimated from the decay of force, EMG mean frequency, and EMG conduction velocity. 30-Hz vibrations represented the most fatiguing stimulus. Our preliminary results also show a better correlation between force and conduction velocity decay than between force and mean frequency decay, indicating the former as a better EMG indicator of fatigue. The proposed methods provide important advancements for the analysis of vibration exercise and guidance towards the definition of optimal training protocols.

  19. Low-frequency wideband vibration energy harvesting by using frequency up-conversion and quin-stable nonlinearity

    Science.gov (United States)

    Wang, Chen; Zhang, Qichang; Wang, Wei

    2017-07-01

    This work presents models and experiments of an impact-driven and frequency up-converted wideband piezoelectric-based vibration energy harvester with a quintuple-well potential induced by the combination effect of magnetic nonlinearity and mechanical piecewise-linearity. Analysis shows that the interwell motions during coupled vibration period enable to increase electrical power output in comparison to conventional frequency up-conversion technology. Besides, the quintuple-well potential with shallower potential wells could extend the harvester's operating bandwidth to lower frequencies. Experiments demonstrate our proposed approach can dramatically boost the measured power of the energy harvester as much as 35 times while its lower cut-off frequency is two times lower than that of a conventional counterpart. These results reveal our proposed approach shows promise for powering portable wireless smart devices from low-intensity, low-frequency vibration sources.

  20. Diagnosis of industrial gearboxes condition by vibration and time-frequency, scale-frequency, frequency-frequency analysis

    Directory of Open Access Journals (Sweden)

    P. Czech

    2012-10-01

    Full Text Available In the article methods of vibroacoustic diagnostics of high-power toothed gears are described. It is shown below, that properly registered and processed acoustic signal or vibration signal may serve as an explicitly interpreted source of diagnostic symptoms. The presented analysis were based on vibration signals registered during the work of the gear of a rolling stand working in Katowice Steel Plant (presently one of the branches of Mittal Steel Poland JSC.

  1. Observation of the low frequency vibrational modes of bacteriophage M13 in water by Raman spectroscopy

    Directory of Open Access Journals (Sweden)

    Tsen Shaw-Wei D

    2006-09-01

    Full Text Available Abstract Background Recently, a technique which departs radically from conventional approaches has been proposed. This novel technique utilizes biological objects such as viruses as nano-templates for the fabrication of nanostructure elements. For example, rod-shaped viruses such as the M13 phage and tobacco mosaic virus have been successfully used as biological templates for the synthesis of semiconductor and metallic nanowires. Results and discussion Low wave number (≤ 20 cm-1 acoustic vibrations of the M13 phage have been studied using Raman spectroscopy. The experimental results are compared with theoretical calculations based on an elastic continuum model and appropriate Raman selection rules derived from a bond polarizability model. The observed Raman mode has been shown to belong to one of the Raman-active axial torsion modes of the M13 phage protein coat. Conclusion It is expected that the detection and characterization of this low frequency vibrational mode can be used for applications in nanotechnology such as for monitoring the process of virus functionalization and self-assembly. For example, the differences in Raman spectra can be used to monitor the coating of virus with some other materials and nano-assembly process, such as attaching a carbon nanotube or quantum dots.

  2. Investigation into high-frequency-vibration assisted micro-blanking of pure copper foils

    Directory of Open Access Journals (Sweden)

    Wang Chunju

    2015-01-01

    Full Text Available The difficulties encountered during the manufacture of microparts are often associated with size effects relating to material, process and tooling. Utilizing acoustoplastic softening, achieved through a high-frequency vibration assisted micro-blanking process, was introduced to improve the surface finish in micro-blanking. A frequency of 1.0 kHz was chosen to activate the longitudinal vibration mode of the horn tip, using a piezoelectric actuator. A square hole with dimensions of 0.5 mm × 0.5 mm was made, successfully, from a commercial rolled T2 copper foil with 100 μm in thickness. It was found that the maximum blanking force could be reduced by 5% through utilizing the high-frequency vibration. Proportion of the smooth, burnished area in the cut cross-section increases with an increase of the plasticity to fracture, under the high-frequency vibration, which suggests that the vibration introduced is helpful for inhibiting evolution of the crack due to its acoustoplastic softening effect. During blanking, roughness of the burnished surface could be reduced by increasing the vibration amplitude of the punch, which played a role as surface polishing. The results obtained suggest that the high-frequency vibration can be adopted in micro-blanking in order to improve quality of the microparts.

  3. Structure-borne sound structural vibrations and sound radiation at audio frequencies

    CERN Document Server

    Cremer, L; Petersson, Björn AT

    2005-01-01

    Structure-Borne Sound"" is a thorough introduction to structural vibrations with emphasis on audio frequencies and the associated radiation of sound. The book presents in-depth discussions of fundamental principles and basic problems, in order to enable the reader to understand and solve his own problems. It includes chapters dealing with measurement and generation of vibrations and sound, various types of structural wave motion, structural damping and its effects, impedances and vibration responses of the important types of structures, as well as with attenuation of vibrations, and sound radi

  4. Modelling of tuning of an ultra low frequency Roberts Linkage vibration isolator

    Energy Technology Data Exchange (ETDEWEB)

    Dumas, Jean-Charles, E-mail: jcdumas@physics.uwa.edu.a [School of Physics, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia); Ju Li; Blair, David G. [School of Physics, University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia)

    2010-08-09

    We present an analytical model for a Roberts Linkage used as an ultra low frequency vibration isolator. The Roberts Linkage is a structure that simulates a very long radius conical pendulum, at a relatively small height. We show through an analytical solution that it is possible to independently tune the centre of percussion and the resonant frequency for arbitrary geometrical configurations. The result is shown to provide a practical tuning solution, which achieves near ideal vibration isolation.

  5. Modelling of tuning of an ultra low frequency Roberts Linkage vibration isolator

    Science.gov (United States)

    Dumas, Jean-Charles; Ju, Li; Blair, David G.

    2010-08-01

    We present an analytical model for a Roberts Linkage used as an ultra low frequency vibration isolator. The Roberts Linkage is a structure that simulates a very long radius conical pendulum, at a relatively small height. We show through an analytical solution that it is possible to independently tune the centre of percussion and the resonant frequency for arbitrary geometrical configurations. The result is shown to provide a practical tuning solution, which achieves near ideal vibration isolation.

  6. Analysis of muscle fatigue induced by isometric vibration exercise at varying frequencies.

    Science.gov (United States)

    Mischi, M; Rabotti, C; Cardinale, M

    2012-01-01

    An increase in neuromuscular activity, measured by electromyography (EMG), is usually observed during vibration exercise. The underlying mechanisms are however unclear, limiting the possibilities to introduce and exploit vibration training in rehabilitation programs. In this study, a new training device is used to perform vibration exercise at varying frequency and force, therefore enabling the analysis of the relationship between vibration frequency and muscle fatigue. Fatigue is estimated by maximum voluntary contraction measurement, as well as by EMG mean-frequency and conduction-velocity analysis. Seven volunteers performed five isometric contractions of the biceps brachii with a load consisting of a baseline of 80% of their maximum voluntary contraction (MVC), with no vibration and with a superimposed 20, 30, 40, and 50 Hz vibrational force of 40 N. Myoelectric and mechanical fatigue were estimated by EMG analysis and by assessment of the MVC decay, respectively. A dedicated motion artifact canceler, making use of accelerometry, is proposed to enable accurate EMG analysis. Use of this canceler leads to better interpolation of myoelectric fatigue trends and to better correlation between mechanical and myoelectric fatigue. In general, our results suggest vibration at 30 Hz to be the most fatiguing exercise. These results contribute to the analysis of vibration exercise and motivate further research aiming at improved training protocols.

  7. Electrostatic energy harvesting device with dual resonant structure for wideband random vibration sources at low frequency.

    Science.gov (United States)

    Zhang, Yulong; Wang, Tianyang; Zhang, Ai; Peng, Zhuoteng; Luo, Dan; Chen, Rui; Wang, Fei

    2016-12-01

    In this paper, we present design and test of a broadband electrostatic energy harvester with a dual resonant structure, which consists of two cantilever-mass subsystems each with a mass attached at the free edge of a cantilever. Comparing to traditional devices with single resonant frequency, the proposed device with dual resonant structure can resonate at two frequencies. Furthermore, when one of the cantilever-masses is oscillating at resonance, the vibration amplitude is large enough to make it collide with the other mass, which provides strong mechanical coupling between the two subsystems. Therefore, this device can harvest a decent power output from vibration sources at a broad frequency range. During the measurement, continuous power output up to 6.2-9.8 μW can be achieved under external vibration amplitude of 9.3 m/s2 at a frequency range from 36.3 Hz to 48.3 Hz, which means the bandwidth of the device is about 30% of the central frequency. The broad bandwidth of the device provides a promising application for energy harvesting from the scenarios with random vibration sources. The experimental results indicate that with the dual resonant structure, the vibration-to-electricity energy conversion efficiency can be improved by 97% when an external random vibration with a low frequency filter is applied.

  8. The Possible Interstellar Anion CH2CN-: Spectroscopic Constants, Vibrational Frequencies, and Other Considerations

    Science.gov (United States)

    Fortenberry, Ryan C.; Crawford, T. Daniel; Lee, Timothy J.

    2012-01-01

    The A 1B1 interstellar band. However, this particular molecular system has not been detected in the interstellar medium even though the related cyanomethyl radical and the isoelectronic ketenimine molecule have been found. In this study we are employing the use of proven quartic force elds and second-order vibrational perturbation theory to compute accurate spectroscopic constants and fundamental vibrational frequencies for X 1A0 CH2CN?? in order to assist in laboratory studies and astronomical observations. Keywords: Astrochemistry, ISM: molecular anions, Quartic force elds, Rotational constants, Vibrational frequencies

  9. Theoretical Vibration Analysis Regarding Excitation due to Elliptical Shaft Journals in Sleeve Bearings of Electrical Motors

    Directory of Open Access Journals (Sweden)

    Ulrich Werner

    2012-01-01

    Full Text Available This paper shows a theoretical vibration analysis regarding excitation due to elliptical shaft journals in sleeve bearings of electrical motors, based on a simplified rotordynamic model. It is shown that elliptical shaft journals lead to kinematic constraints regarding the movement of the shaft journals on the oil film of the sleeve bearings and therefore to an excitation of the rotordynamic system. The solution of the linear differential equation system leads to the mathematical description of the movement of the rotor mass, the shaft journals, and the sleeve bearing housings. Additionally the relative movements between the shaft journals and the bearing housings are deduced, as well as the bearing housing vibration velocities. The presented simplified rotordynamic model can also be applied to rotating machines, other than electrical machines. In this case, only the electromagnetic spring value cm has to be put to zero.

  10. Theoretical structural and vibrational study of 5-trifluoromethyluracil. A comparison with uracil

    Energy Technology Data Exchange (ETDEWEB)

    Rudyk, Roxana; Ramos, María E.; Checa, María A.; Brandán, Silvia A. [Cátedra de Química General, Instituto de Química Inorgánica, Facultad de Bioquímica, Química y Farmacia, Universidad Nacional de Tucumán, Ayacucho 471,(4000), San Miguel de Tucumán, Tucum and #x00E1 (Argentina); Chamorro, Eduardo E. [Facultad de Ciencias Exactas, Universidad Andrés Bello, Avda. República 275, 8370146, Santiago (Chile)

    2014-10-06

    In the present work, a comparative study on the structural and vibrational properties of the 5-trifluoromethyluracil (TFMU) derivative with those corresponding to uracil in gas and aqueous solution phases was performed combining the available H{sup 1}-NMR, C{sup 13}-NMR, F{sup 19}-NMR and FTIR spectra with Density Functional Theory (DFT) calculations. Three stable conformers were theoretically determined in both media by using the hybrid B3LYP/6-31G* method. The solvent effects were simulated by means of the self-consistent reaction field (SCRF) method employing the integral equation formalism variant (IEFPCM). Complete assignments of the vibrational spectra in both phases were performed combining the internal coordinates analysis and the DFT calculations with the Scaled Quantum Mechanics Force Field (SQMFF) methodology. The atomic charges, bond orders, solvation energies, dipole moments, molecular electrostatic potentials and force constants parameters were calculated for the three conformers of TFMU in gas phase and aqueous solution.

  11. A theoretical study of vibrational properties of neutral and cationic B12 clusters

    Science.gov (United States)

    Lau, Kah Chun; Deshpande, Mrinalini; Pandey, Ravindra

    Calculations based on density functional theory predict the ground state of B12 and B +12 to be a convex planar configuration with C1 symmetry. A small ionization-induced structural change in B12 is also predicted. It is suggested that multicentered bonds together with delocalized charge density are dominant factors in stabilizing the planar configuration over 3D configuration for B12 and B +12. The calculated vibrational frequencies lie in the range of 200-1328 cm-1 in which the high-frequency modes are associated with asymmetric stretching of the boron atoms located at the cluster surface. The infrared spectra of both neutral and cationic B12 show similar infrared active modes in the high-frequency region, but different modes in the low-frequency region due to dissimilar atomic charges in the cationic B12. The combined effect of charge delocalization and reduced dimensionality is reflected in the calculated static dipole polarizability of these clusters.

  12. Bandwidth Widening of Piezoelectric Cantilever Beam Arrays by Mass-Tip Tuning for Low-Frequency Vibration Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Eduard Dechant

    2017-12-01

    Full Text Available Wireless sensor networks usually rely on internal permanent or rechargeable batteries as a power supply, causing high maintenance efforts. An alternative solution is to supply the entire system by harvesting the ambient energy, for example, by transducing ambient vibrations into electric energy by virtue of the piezoelectric effect. The purpose of this paper is to present a simple engineering approach for the bandwidth optimization of vibration energy harvesting systems comprising multiple piezoelectric cantilevers (PECs. The frequency tuning of a particular cantilever is achieved by changing the tip mass. It is shown that the bandwidth enhancement by mass tuning is limited and requires several PECs with close resonance frequencies. At a fixed frequency detuning between subsequent PECs, the achievable bandwidth shows a saturation behavior as a function of the number of cantilevers used. Since the resonance frequency of each PEC is different, the output voltages at a particular excitation frequency have different amplitudes and phases. A simple power-transfer circuit where several PECs with an individual full wave bridge rectifier are connected in parallel allows one to extract the electrical power close to the theoretical maximum excluding the diode losses. The experiments performed on two- and three-PEC arrays show reasonable agreement with simulations and demonstrate that this power-transfer circuit additionally influences the frequency dependence of the harvested electrical power.

  13. Estimation of the running speed and bearing defect frequencies of an induction motor from vibration data

    Science.gov (United States)

    Ocak, Hasan; Loparo, Kenneth A.

    2004-05-01

    This paper presents two separate algorithms for estimating the running speed and the bearing key frequencies of an induction motor using vibration data. Bearing key frequencies are frequencies at which roller elements pass over a defect point. Most frequency domain-based bearing fault detection and diagnosis techniques (e.g. envelope analysis) rely on vibration measurements and the bearing key frequencies. Thus, estimation of the running speed and the bearing key frequencies are required for failure detection and diagnosis. The paper also incorporates the estimation algorithms with the most commonly used bearing fault detection technique, high-frequency demodulation, to detect bearing faults. Experimental data were used to verify the validity of the algorithms. Data were collected through an accelerometer measuring the vibration from the drive-end ball bearing of an induction motor (Reliance Electric 2HP IQPreAlert)-driven mechanical system. Both inner and outer race defects were artificially introduced to the bearing using electrical discharge machining. A linear vibration model was also developed for generating simulated vibration data. The simulated data were also used to validate the performance of the algorithms. The test results proved the algorithms to be very reliable.

  14. DIAGNOSIS SHAFT BEARINGS NODE KNIFE CUTTER FOR LOW-FREQUENCY VIBRATION

    Directory of Open Access Journals (Sweden)

    S. T. Antipov

    2015-01-01

    Full Text Available The currently used system of preventive maintenance is not effective enough. Vibration diagnostics is one of the modern methods of non-destructive testing equipment components, allowing to define the appearance of defects in the early stages. The paper identifies the main areas of research, as well as selected research object, selected non-destructive testing method for efficiently determining the actual state of dynamically operating equipment. Is a schematic of vibration sensors. Measuring point vibration parameters were determined experimentally based on the conditions for obtaining the most informative vibroacoustic signal. Determine the behavior of the cutter under which minimizes the occurrence of a wide range of fluctuations that affects the accuracy of the measurements. For vibration analysis method was chosen direct spectral analysis, which involves the detection of repetitive vibrations. Presented graphically vibration spectra and spectra of vibration signals. Analysis of a wide range of vibration spectrum allowed to allocate land on which showed a significant increase in the values of vibration. Processing of the selected portion of the spectrum has led to the conclusion that in the bearing, shock pulses are in contact with each rolling body shell, and as a result, a number of harmonics in the individual frequencies. Was made a comparative analysis of the spectra of working with a defective bearing bearing on the same frequencies and determine the average increase in the values of vibration. Spectral analysis is an effective method to determine not only the extent of the defect and its location, but also allows you to effectively predict its development. The results may be useful for specialists involved in vibration diagnostics, calculation and design of rotary machines.

  15. A smart and self-sufficient frequency tunable vibration energy harvester

    Science.gov (United States)

    Eichhorn, C.; Tchagsim, R.; Wilhelm, N.; Woias, P.

    2011-10-01

    We present a piezoelectric energy-harvesting system, which is able to self-tune its resonance frequency in an energy-autonomous way, in order to extend its efficient operation over a large frequency range. The system consists of a resonant and frequency-tunable piezoelectric generator and a control unit. In predefined temporal intervals, the control unit analyzes the ambient vibration frequency, decides whether an adjustment of the generator's resonance frequency is necessary or not and delivers the appropriate voltage to a piezoelectric actuator which alters the generator's mechanical stiffness to tune its resonance frequency. The control unit has been optimized to an ultralow power consumption which means that up to 90% of the harvested energy can be fed to the powered electrical load, which could be an embedded system. With frequency-tunable generators, the application range of vibration energy harvesters can be extended to environments with a non-constant vibration frequency, like e.g. the surface of an engine with a varying number of revolutions per minute. Furthermore, the presented system opens the door to off-the-shelf solutions for environments with constant but uncommon vibration frequencies. With the smart tuning algorithm presented in this work, our system is even able to compensate typical weak points of piezoelectrically tunable harvesters, like e.g. hysteresis effects, the temperature dependence of the mechanical stiffness and aging effects.

  16. Frequency characteristics of human muscle and cortical responses evoked by noisy Achilles tendon vibration.

    Science.gov (United States)

    Mildren, Robyn L; Peters, Ryan M; Hill, Aimee J; Blouin, Jean-Sébastien; Carpenter, Mark G; Inglis, J Timothy

    2017-05-01

    Noisy stimuli, along with linear systems analysis, have proven to be effective for mapping functional neural connections. We explored the use of noisy (10-115 Hz) Achilles tendon vibration to examine somatosensory reflexes in the triceps surae muscles in standing healthy young adults ( n = 8). We also examined the association between noisy vibration and electrical activity recorded over the sensorimotor cortex using electroencephalography. We applied 2 min of vibration and recorded ongoing muscle activity of the soleus and gastrocnemii using surface electromyography (EMG). Vibration amplitude was varied to characterize reflex scaling and to examine how different stimulus levels affected postural sway. Muscle activity from the soleus and gastrocnemii was significantly correlated with the tendon vibration across a broad frequency range (~10-80 Hz), with a peak located at ~40 Hz. Vibration-EMG coherence positively scaled with stimulus amplitude in all three muscles, with soleus displaying the strongest coupling and steepest scaling. EMG responses lagged the vibration by ~38 ms, a delay that paralleled observed response latencies to tendon taps. Vibration-evoked cortical oscillations were observed at frequencies ~40-70 Hz (peak ~54 Hz) in most subjects, a finding in line with previous reports of sensory-evoked γ-band oscillations. Further examination of the method revealed 1 ) accurate reflex estimates could be obtained with vibration; 2 ) responses did not habituate over 2 min of exposure; and importantly, 3 ) noisy vibration had a minimal influence on standing balance. Our findings suggest noisy tendon vibration is an effective novel approach to characterize somatosensory reflexes during standing. NEW & NOTEWORTHY We applied noisy (10-115 Hz) vibration to the Achilles tendon to examine the frequency characteristics of lower limb somatosensory reflexes during standing. Ongoing muscle activity was coherent with the noisy vibration (peak coherence ~40 Hz), and

  17. Electrostatics determine vibrational frequency shifts in hydrogen bonded complexes.

    Science.gov (United States)

    Dey, Arghya; Mondal, Sohidul Islam; Sen, Saumik; Ghosh, Debashree; Patwari, G Naresh

    2014-12-14

    The red-shifts in the acetylenic C-H stretching vibration of C-H∙∙∙X (X = O, N) hydrogen-bonded complexes increase with an increase in the basicity of the Lewis base. Analysis of various components of stabilization energy suggests that the observed red-shifts are correlated with the electrostatic component of the stabilization energy, while the dispersion modulates the stabilization energy.

  18. The effects of low-frequency vibrations on hepatic profile of blood

    Science.gov (United States)

    Damijan, Z.

    2008-02-01

    Body vibrations training has become popular in sports training, fitness activity, it is still a rare form of physical rehabilitation.. Vibrations are transmitted onto the whole body or some body parts of an exercising person via a vibration platform subjected to mechanical vertical vibrations. During the training session a participant has to maintain his body position or do exercises that engage specific muscles whilst vibrations of the platform are transmitted onto the person's body. This paper is the continuation of the earlier study covering the effects of low-frequency vibrations on selected physiological parameters of the human body. The experiments were conducted to find the answer to the question if vibration exposure (total duration of training sessions 6 hours 20 min) should produce any changes in hepatic profile of blood. Therefore a research program was undertaken at the University of Science and Technology AGH UST to investigate the effects of low-frequency vibration on selected parameters of hepatic profile of human blood. Cyclic fluctuations of bone loading were induced by the applied harmonic vibration 3.5 Hz and amplitude 0.004 m. The experiments utilizing two vibrating platforms were performed in the Laboratory of Structural Acoustics and Biomedical Engineering AGH-UST. The applied vibrations were harmless and not annoying, in accordance with the standard PN-EN ISO 130901-1, 1998. 23 women volunteers had 19 sessions on subsequent working days, at the same time of day. during the tests the participants remained in the standing position, passive. The main hypothesis has it that short-term low-frequency vibration exposure might bring about the changes of the hepatic profile of blood, including: bilirubin (BILIRUBIN), alkaline phosphatase (Alp), alanine aminotransferase (ALT), aspartate aminotransferase (AST) and albumin (ALBUMIN) levels. Research data indicate the low-frequency vibrations exposure produces statistically significant decrease of

  19. Individual Optimal Frequency in Whole-Body Vibration: Effect of Protocol, Joint Angle, and Fatiguing Exercise.

    Science.gov (United States)

    Carlucci, Flaminia; Felici, Francesco; Piccinini, Alberto; Haxhi, Jonida; Sacchetti, Massimo

    2016-12-01

    Carlucci, F, Felici, F, Piccinini, A, Haxhi, J, and Sacchetti, M. Individual optimal frequency in whole-body vibration: effect of protocol, joint angle, and fatiguing exercise. J Strength Cond Res 30(12): 3503-3511, 2016-Recent studies have shown the importance of individualizing the vibration intervention to produce greater effects on the neuromuscular system in less time. The purpose of this study was to assess the individual optimal vibration frequency (OVF) corresponding to the highest muscle activation (RMSmax) during vibration at different frequencies, comparing different protocols. Twenty-nine university students underwent 3 continuous (C) and 2 random (R) different vibrating protocols, maintaining a squat position on a vibration platform. The C protocol lasted 50 seconds and involved the succession of ascending frequencies from 20 to 55 Hz, every 5 seconds. The same protocol was performed twice, having the knee angle at 120° (C) and 90° (C90), to assess the effect of joint angle and after a fatiguing squatting exercise (CF) to evaluate the influence of fatigue on OVF assessment. In the random protocols, vibration time was 20 seconds with a 2-minute (R2) and a 4-minute (R4) pauses between tested frequencies. Muscle activation and OVF values did not differ significantly in the C, R2, and R4 protocols. RMSmax was higher in C90 (p fatiguing exercise had no effect on OVF. In conclusion, the shorter C protocol produced similar myoelectrical activity in the R2 and the R4 protocols, and therefore, it could be equally valid in identifying the OVF with considerable time efficiency. Knee joint angle and fatiguing exercise had an effect on surface electromyography response during vibration but did not affect OVF identification significantly.

  20. Molecular structure, vinyl rotation barrier, and vibrational dynamics of 2,6-dichlorostyrene. A theoretical and experimental research.

    Science.gov (United States)

    Ceacero-Vega, Antonio A; Ruiz, Tomas Peña; Gómez, Manuel Fernández; Roldán, José M Granadino; Navarro, Amparo; Fernández-Liencres, M Paz; Jayasooriya, Upali A

    2007-07-19

    The molecular structure of 2,6-dichlorostyrene has been analyzed at MP2 and DFT levels using different basis sets concluding in a nonplanar geometry. The influence of either the level of theory or the nature of the substituent has been assessed. The vinyl-phenyl torsion barrier has also been investigated as a function of level of theory. The ultimate factors responsible for the torsion barrier have been studied using two different partitioning schemes, i.e., the total electronic potential energy and the natural bond orbital, NBO. A topological analysis of the electron density within the atom-in-molecule, AIM, theory predicts soft intramolecular chlorine (ring)-hydrogen (vinyl) contacts when the system becomes planar. A first complete vibrational study has been performed using theoretical data and experimental vibrational frequencies from IR, Raman and, for the first time, inelastic neutron scattering, INS, spectra. The new assignment proposed is based on a scaled quantum mechanical, SQM, force field and the wavenumber linear scaling, WLS, approach.

  1. A Stepwise Optimal Design of a Dynamic Vibration Absorber with Tunable Resonant Frequency

    Directory of Open Access Journals (Sweden)

    Jiejian DI

    2014-08-01

    Full Text Available A new kind of dynamic vibration absorber (DVA with tunable resonant frequency is presented. The kinematics differential equation about it is built and the stepwise optimization is performed. Firstly, four main system parameters involving the ratios of mass m, natural frequency f, vibration frequency g and damping z are solved by small-step-search method to obtain optimal steady state amplitude. Secondly, the sizing optimization of the dynamic vibration absorber is proceeded to search an optimal damping effect based on the optimal parameters (g, m, z, f. And such the damping effect is simulated in a flat structure, and the results show that the working frequency band and damping effect of the DVA after optimization won 20 % of the effect of ascension compared with that before optimization.

  2. Influence of low-frequency vibration on the erythrocytes acid resistance

    Directory of Open Access Journals (Sweden)

    O. I. Dotsenko

    2011-02-01

    Full Text Available The influence of low-frequency vibration (frequency range 8–32 Hz, amplitudes 0.5 ± 0.04 and 0.9 ± 0.08 mm on the erythrocytes’ acid resistance was studied. The kinetics of various hemolysis stages was investigated. The time-frequency dependences of the kinetics constants of hemolysis stages were obtained and discussed. It was shown that 8–16 Hz vibration with the 0.5 mm amplitude and 8 Hz with 0.9 mm causes destructive reorganizations of a cytoplasm’s water-protein structure. It leads to decrease in a permeability barrier for a hemolytic agent. As a result of oxidizing stress the vibration in the frequency range of 20–32 Hz causes the modifying reactions leading to the aggregation of cellular proteins and, in particular, the band 3 protein.

  3. Protonated Nitrous Oxide, NNOH(+): Fundamental Vibrational Frequencies and Spectroscopic Constants from Quartic Force Fields

    Science.gov (United States)

    Huang, Xinchuan; Fortenberry, Ryan C.; Lee, Timothy J.

    2013-01-01

    The interstellar presence of protonated nitrous oxide has been suspected for some time. Using established high-accuracy quantum chemical techniques, spectroscopic constants and fundamental vibrational frequencies are provided for the lower energy O-protonated isomer of this cation and its deuterated isotopologue. The vibrationally-averaged B0 and C0 rotational constants are within 6 MHz of their experimental values and the D(subJ) quartic distortion constants agree with experiment to within 3%. The known gas phase O-H stretch of NNOH(+) is 3330.91 cm(exp-1), and the vibrational configuration interaction computed result is 3330.9 cm(exp-1). Other spectroscopic constants are also provided, as are the rest of the fundamental vibrational frequencies for NNOH(+) and its deuterated isotopologue. This high-accuracy data should serve to better inform future observational or experimental studies of the rovibrational bands of protonated nitrous oxide in the ISM and the laboratory.

  4. Low-frequency, broadband vibration energy harvester using coupled oscillators and frequency up-conversion by mechanical stoppers

    Science.gov (United States)

    Dechant, Eduard; Fedulov, Feodor; Chashin, Dmitrii V.; Fetisov, Leonid Y.; Fetisov, Yuri K.; Shamonin, Mikhail

    2017-06-01

    The frequencies of ambient vibrations are often low (below 30 Hz). A broadband (3 dB bandwidth is larger than 10 Hz at an acceleration amplitude of 9.81 m s-2) vibration based energy harvester is proposed for transducing mechanical energy at such low frequencies into electrical energy. The mechanical setup converts low frequency mechanical vibrations into high frequency resonance oscillations of the transducer. This conversion is done by mechanical impacts on two mechanical stoppers. The originality of the presented design is that both low-frequency and high-frequency oscillators are permanently mechanically coupled. In the equivalent mechanical circuit, this coupling is achieved by connecting the ends of the stiff spring to both seismic masses, whereas one seismic mass (collison member) is also attached to the soft spring used as the constitutive element of a low-frequency oscillator. Further, both mechanical oscillators are not realized as conventional cantilever beams. In particular, the high frequency oscillator with the natural frequency of 340 Hz is a disc-shaped diaphragm with attached piezoelectric elements and a seismic mass. It is shown that it is possible to convert mechanical vibrations with acceleration amplitude of 9.81 m s-2 in the region between approximately 7 and 25 Hz into electrical power larger than 0.1 mW with the maximum value of 0.8 mW. A simplified mathematical model based on piecewise linear coupled oscillators shows good agreement with experimental results. The ways to enhance the performance of the harvester and improve agreement with experiments are discussed.

  5. Modelling of Mechanical Coupling for Piezoelectric Energy Harvester Adapted to Low-Frequency Vibration

    Science.gov (United States)

    Untoro, T.; Viridi, S.; Suprijanto; Ekawati, E.

    2017-07-01

    In our previous work, we have developed a mechanical coupling for energy harvester from vibration source. This energy harvester uses piezoelectric with additional cantilever beam and permanent magnets. Our work proposed alternative scheme of mechanical coupling for tune the vibration input into resonant frequency of piezoelectric. Based on the experiment, correlation between the length of cantilever beam and the output power also evaluated. In this paper, we try to modelling our work into mathematical model and apply it to some case study. For example application, we apply our energy harvester system to generate electrical energy to enlighten the street. The human footsteps can be used as vibration source to generate electrical energy.

  6. Measurement of Mechatronic Property of Biological Gel with Micro-Vibrating Electrode at Ultrasonic Frequency

    Directory of Open Access Journals (Sweden)

    Shigehiro Hashimoto

    2008-10-01

    Full Text Available A measurement system has been designed with a micro-vibrating electrode at ultrasonic frequency to measure local impedance of biological gel in vitro. The designed system consists of two electrodes, where one of the electrodes vibrates with a piezoelectric actuator. The component of variation at impedance between two electrodes with vibration of one electrode is analyzed at the corresponding spectrum. The manufactured system was applied to measure impedance of a physiological saline solution, a potassium chloride solution, a dextran aqueous solution, and an egg. The experimental results show that the designed system is effective to measure local mechatronic property of biological gel.

  7. Effect of different vibration frequencies on heart rate variability and driving fatigue in healthy drivers.

    Science.gov (United States)

    Jiao, Kun; Li, Zengyong; Chen, Ming; Wang, Chengtao; Qi, Shaohua

    2004-04-01

    This investigation was to assess the effect of different vibration frequencies on heart rate variability (HRV) and driving fatigue in healthy subjects during simulated driving, by the use of power spectrum analysis and subjective evaluation. Sixty healthy subjects (29.6+/-3.3 years) were randomly divided into three groups, A, B and C, and the subjects of each group participated in the simulated driving for 90 min with vertical sinusoidal vibration (acceleration 0.05 g) of 1.8 Hz (group A), 6 Hz (group B) and no vibration (group C), respectively. Low-frequency (LF) and high-frequency (HF) components of HRV, reflecting sympathetic and parasympathetic activities, and the LF:HF ratio, indicating sympathovagal balance, were measured throughout all periods. All indices of HRV were calculated in the pre-experiment period, mid-experiment period and end-experiment period, and were analyzed by repeated measures analysis of variance. Subjective responses to a questionnaire were obtained after the simulated task for the three groups. Significant differences in all indices of HRV were observed between different experiment periods and between any two groups. The ratings of subjective fatigue exhibited significant differences between any two groups. The drivers' fatigue ratings were associated with vibration frequencies in simulated driving. The study quantitatively demonstrated that different effects on autonomic nerve activities were induced by different vibration frequencies.

  8. Low frequency vibrations induce malformations in two aquatic species in a frequency-, waveform-, and direction-specific manner.

    Directory of Open Access Journals (Sweden)

    Laura N Vandenberg

    Full Text Available Environmental toxicants such as industrial wastes, air particulates from machinery and transportation vehicles, and pesticide run-offs, as well as many chemicals, have been widely studied for their effects on human and wildlife populations. Yet other potentially harmful environmental pollutants such as electromagnetic pulses, noise and vibrations have remained incompletely understood. Because developing embryos undergo complex morphological changes that can be affected detrimentally by alterations in physical forces, they may be particularly susceptible to exposure to these types of pollutants. We investigated the effects of low frequency vibrations on early embryonic development of two aquatic species, Xenopus laevis (frogs and Danio rerio (zebrafish, specifically focusing on the effects of varying frequencies, waveforms, and applied direction. We observed treatment-specific effects on the incidence of neural tube defects, left-right patterning defects and abnormal tail morphogenesis in Xenopus tadpoles. Additionally, we found that low frequency vibrations altered left-right patterning and tail morphogenesis, but did not induce neural tube defects, in zebrafish. The results of this study support the conclusion that low frequency vibrations are toxic to aquatic vertebrates, with detrimental effects observed in two important model species with very different embryonic architectures.

  9. Vibration characteristics of composite piezoceramic plates at resonant frequencies: experiments and numerical calculations.

    Science.gov (United States)

    Huang, C H; Ma, C C

    2001-07-01

    The experimental measurement of the resonant frequencies for the piezoceramic material is generally performed by impedance analysis. In this paper, we employ an optical interferometry method called the amplitude-fluctuation electronic speckle pattern interferometry (AF-ESPI) to investigate the vibration characteristics of piezoceramic/aluminum laminated plates. The AF-ESPI is a powerful tool for the full-field, noncontact, and real-time measurement method of surface displacement for vibrating bodies. As compared with the conventional film recording and optical reconstruction procedures used for holographic interferometry, the interferometric fringes of AF-ESPI are produced instantly by a video recording system. Because the clear fringe patterns measured by the AF-ESPI method will be shown only at resonant frequencies, both the resonant frequencies and corresponding vibration mode shapes are obtained experimentally at the same time. Excellent quality of the interferometric fringe patterns for both the in-plane and out-of-plane vibration mode shapes are demonstrated. Two different configurations of piezoceramic/aluminum laminated plates, which exhibit different vibration characteristics because of the polarization direction, are investigated in detail. From experimental results, we find that some of the out-of-plane vibration modes (Type A) with lower resonant frequencies cannot be measured by the impedance analysis; however, all of the vibration modes of piezoceramic/aluminum laminated plates can be obtained by the AF-ESPI method. Finally, the numerical finite element calculations are also performed, and the results are compared with the experimental measurements. Excellent agreements of the resonant frequencies and mode shapes are obtained for both results.

  10. An analytical model for a piezoelectric vibration energy harvester with resonance frequency tunability

    Directory of Open Access Journals (Sweden)

    Yun Wang

    2015-06-01

    Full Text Available This article conceptually proposes a new method to tune the resonance frequency of piezoelectric vibration energy harvesters, in which the supporting position of the vibrator can be adjusted for frequency tuning. The corresponding analytical model is established to predict the performances of the harvester based on the principles of energy. First, the equivalent stiffness and mass of the vibrator in bending mode are derived explicitly for the different supporting positions. A simple analysis method is then established for the frequency, output voltage, and output power. Finally, some numerical examples are given to demonstrate the presented method. The results are also compared with those by finite element method and good agreement is observed.

  11. Experimental investigation on low-frequency vibration assisted micro-WEDM of Inconel 718

    Directory of Open Access Journals (Sweden)

    Deepak Rajendra Unune

    2017-02-01

    Full Text Available The micro-wire electric discharge machining (micro-WEDM has emerged as the popular micromachining processes for fabrication of micro-features. However, the low machining rate and poor surface finish are restricting wide applications of this process. Therefore, in this study, an attempt was made to improve machining rate of micro-WEDM with low-frequency workpiece vibration assistance. The gap voltage, capacitance, feed rate and vibrational frequency were chosen as control factors, whereas, the material removal rate (MRR and kerf width were selected as performance measures while fabricating microchannels in Inconel 718. It was observed that in micro-WEDM, the capacitance is the most significant factor affecting both MRR and kerf width. It was witnessed that the low-frequency workpiece vibration improves the performance of micro-WEDM by improving the MRR due to enhanced flushing conditions and reduced electrode-workpiece adhesion.

  12. Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: vibrations and structure of its excited S(1)(π,π(*)) electronic state.

    Science.gov (United States)

    Shin, Hee Won; Ocola, Esther J; Kim, Sunghwan; Laane, Jaan

    2014-01-21

    The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S1(π,π(*)) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S0 and S1(π,π(*)) electronic states. In each case the decreased π bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S0 and S1(π,π(*)) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S1(π,π(*)) excited state.

  13. Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: Vibrations and structure of its excited S{sub 1}(π,π{sup *}) electronic state

    Energy Technology Data Exchange (ETDEWEB)

    Shin, Hee Won; Ocola, Esther J.; Laane, Jaan, E-mail: laane@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States); Kim, Sunghwan [National Center for Biotechnology Information, National Library of Medicine, National Institutes of Health, Department of Health and Human Services, 8600 Rockville Pike, Bethesda, Maryland 20894 (United States)

    2014-01-21

    The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S{sub 1}(π,π{sup *}) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S{sub 0} and S{sub 1}(π,π{sup *}) electronic states. In each case the decreased π bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S{sub 0} and S{sub 1}(π,π{sup *}) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S{sub 1}(π,π{sup *}) excited state.

  14. Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: Vibrations and structure of its excited S1(π,π*) electronic state

    Science.gov (United States)

    Shin, Hee Won; Ocola, Esther J.; Kim, Sunghwan; Laane, Jaan

    2014-01-01

    The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S1(π,π*) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S0 and S1(π,π*) electronic states. In each case the decreased π bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S0 and S1(π,π*) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S1(π,π*) excited state. PMID:25669377

  15. Fluorescence excitation and ultraviolet absorption spectra and theoretical calculations for benzocyclobutane: Vibrations and structure of its excited S1(π,π*) electronic state

    Science.gov (United States)

    Shin, Hee Won; Ocola, Esther J.; Kim, Sunghwan; Laane, Jaan

    2014-01-01

    The fluorescence excitation spectra of jet-cooled benzocyclobutane have been recorded and together with its ultraviolet absorption spectra have been used to assign the vibrational frequencies for this molecule in its S1(π,π*) electronic excited state. Theoretical calculations at the CASSCF(6,6)/aug-cc-pVTZ level of theory were carried out to compute the structure of the molecule in its excited state. The calculated structure was compared to that of the molecule in its electronic ground state as well as to the structures of related molecules in their S0 and S1(π,π*) electronic states. In each case the decreased π bonding in the electronic excited states results in longer carbon-carbon bonds in the benzene ring. The skeletal vibrational frequencies in the electronic excited state were readily assigned and these were compared to the ground state and to the frequencies of five similar molecules. The vibrational levels in both S0 and S1(π,π*) states were remarkably harmonic in contrast to the other bicyclic molecules. The decreases in the frequencies of the out-of-plane skeletal modes reflect the increased floppiness of these bicyclic molecules in their S1(π,π*) excited state.

  16. Peculiarities of the Third Natural Frequency Vibrations of a Cantilever for the Improvement of Energy Harvesting

    Directory of Open Access Journals (Sweden)

    Vytautas Ostasevicius

    2015-05-01

    Full Text Available This paper focuses on several aspects extending the dynamical efficiency of a cantilever beam vibrating in the third mode. A few ways of producing this mode stimulation, namely vibro-impact or forced excitation, as well as its application for energy harvesting devices are proposed. The paper presents numerical and experimental analyses of novel structural dynamics effects along with an optimal configuration of the cantilever beam. The peculiarities of a cantilever beam vibrating in the third mode are related to the significant increase of the level of deformations capable of extracting significant additional amounts of energy compared to the conventional harvester vibrating in the first mode. Two types of a piezoelectric vibrating energy harvester (PVEH prototype are analysed in this paper: the first one without electrode segmentation, while the second is segmented using electrode segmentation at the strain nodes of the third vibration mode to achieve effective operation at the third resonant frequency. The results of this research revealed that the voltage generated by any segment of the segmented PVEH prototype excited at the third resonant frequency demonstrated a 3.4–4.8-fold increase in comparison with the non-segmented prototype. Simultaneously, the efficiency of the energy harvester prototype also increased at lower resonant frequencies from 16% to 90%. The insights presented in the paper may serve for the development and fabrication of advanced piezoelectric energy harvesters which would be able to generate a considerably increased amount of electrical energy independently of the frequency of kinematical excitation.

  17. A Theoretical and Experimental Investigation on Free Vibration Vehavior of a Cantilever Beam with a Breathing Crack

    Directory of Open Access Journals (Sweden)

    M. Rezaee

    2012-01-01

    Full Text Available In this paper the free nonlinear vibration behavior of a cracked cantilever beam is investigated both theoretically and experimentally. For simplicity, the dynamic behavior of a cracked beam vibrating at its first mode is simulated using a simple single degree of freedom lumped parameter system. The time varying stiffness is modeled using a harmonic function. The governing equation of motion is solved by a perturbation method – the method of Multiple Scales.

  18. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Kyung Ho; Kim, Young-Cheol [Department of System Dynamics, Korea Institute of Machinery and Materials, 156 Gajeongbuk-Ro, Yuseong-Gu, Daejeon 305-343 (Korea, Republic of); Kim, Jae Eun, E-mail: jekim@cu.ac.kr [School of Mechanical and Automotive Engineering, Catholic University of Daegu, 13-13 Hayang-Ro, Hayang-Eup, Gyeongsan-Si, Gyeongsangbuk-Do 712-702 (Korea, Republic of)

    2014-10-15

    While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm{sup 3}, which was designed for a target frequency of as low as 100 Hz.

  19. A small-form-factor piezoelectric vibration energy harvester using a resonant frequency-down conversion

    Directory of Open Access Journals (Sweden)

    Kyung Ho Sun

    2014-10-01

    Full Text Available While environmental vibrations are usually in the range of a few hundred Hertz, small-form-factor piezoelectric vibration energy harvesters will have higher resonant frequencies due to the structural size effect. To address this issue, we propose a resonant frequency-down conversion based on the theory of dynamic vibration absorber for the design of a small-form-factor piezoelectric vibration energy harvester. The proposed energy harvester consists of two frequency-tuned elastic components for lowering the first resonant frequency of an integrated system but is so configured that an energy harvesting beam component is inverted with respect to the other supporting beam component for a small form factor. Furthermore, in order to change the unwanted modal characteristic of small separation of resonant frequencies, as is the case with an inverted configuration, a proof mass on the supporting beam component is slightly shifted toward a second proof mass on the tip of the energy harvesting beam component. The proposed small-form-factor design capability was experimentally verified using a fabricated prototype with an occupation volume of 20 × 39 × 6.9 mm3, which was designed for a target frequency of as low as 100 Hz.

  20. Crystal growth, vibrational, optical, thermal and theoretical studies of a nonlinear optical material: 2-Methyl 3,5-dinitrobenzoic acid

    Energy Technology Data Exchange (ETDEWEB)

    Sangeetha, K. [Department of Physics, Sri Sarada College for Women, Salem-16 (India); Guru Prasad, L. [Department of Science & Humanities, M. Kumarasamy College of Engineering, Karur (India); Mathammal, R. [Department of Physics, Sri Sarada College for Women, Salem-16 (India)

    2016-11-15

    Single crystals of 2-methyl 3,5-dinitro benzoic acid with reasonable size have been grown by slow evaporation solution growth method using ethanol as solvent. Quantum chemical calculation of 2-methyl 3,5-Dinitro benzoic acid was carried out by using DFT/B3LYP/6-31+G(d,p) method. The powder X-ray diffraction pattern was recorded and indexed. Both the experimental and theoretical vibrational spectrum validates the presence of functional groups. Polarizability, first order hyperpolarizability and the electric dipole moment values have been computed theoretically. The {sup 1}H and {sup 13}C NMR chemical shift of the molecule was calculated and compared with experimental results. TG/DSC analysis has been employed to understand the thermal and physio-chemical stability of the title compound. Frequency conversion property of the crystal was tested by Kurtz and Perry method. Optical absorption behavior of the grown crystal was examined by recording the optical spectrum and band gap energy was also estimated. The calculated HOMO and LUMO energy shows the charge transfer nature of the molecule.

  1. Broadband electromagnetic power harvester from vibrations via frequency conversion by impact oscillations

    Energy Technology Data Exchange (ETDEWEB)

    Yuksek, N. S.; Almasri, M. [Electrical and Computer Engineering, University of Missouri, Columbia, Missouri 65211 (United States); Feng, Z. C. [Mechanical and Aerospace Engineering, University of Missouri, Columbia, Missouri 65211 (United States)

    2014-09-15

    In this paper, we propose an electromagnetic power harvester that uses a transformative multi-impact approach to achieve a wide bandwidth response from low frequency vibration sources through frequency-up conversion. The device consists of a pick-up coil, fixed at the free edge of a cantilever beam with high resonant frequency, and two cantilever beams with low excitation frequencies, each with an impact mass attached at its free edge. One of the two cantilevers is designed to resonate at 25 Hz, while the other resonates at 50 Hz within the range of ambient vibration frequency. When the device is subjected to a low frequency vibration, the two low-frequency cantilevers responded by vibrating at low frequencies, and thus their thick metallic masses made impacts with the high resonance frequency cantilever repeatedly at two locations. This has caused it along with the pick-up coil to oscillate, relative to the permanent magnet, with decaying amplitude at its resonance frequency, and results in a wide bandwidth response from 10 to 63 Hz at 2 g. A wide bandwidth response between 10–51 Hz and 10–58 Hz at acceleration values of 0.5 g and 2 g, respectively, were achieved by adjusting the impact cantilever frequencies closer to each other (25 Hz and 45 Hz). A maximum output power of 85 μW was achieved at 5 g at 30 Hz across a load resistor, 2.68 Ω.

  2. Dual resonant structure for energy harvesting from random vibration sources at low frequency

    Directory of Open Access Journals (Sweden)

    Shanshan Li

    2016-01-01

    Full Text Available We introduce a design with dual resonant structure which can harvest energy from random vibration sources at low frequency range. The dual resonant structure consists of two spring-mass subsystems with different frequency responses, which exhibit strong coupling and broad bandwidth when the two masses collide with each other. Experiments with piezoelectric elements show that the energy harvesting device with dual resonant structure can generate higher power output than the sum of the two separate devices from random vibration sources.

  3. A semi-continuum model on vibration frequency of silicon nanowires in <111> orientation

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Hong, E-mail: h-yu@seu.edu.cn; Chen, Hong-Bo [Key Lab of MEMS of Ministry of Education, Nanjing, Jiangsu, 210096 (China)

    2016-06-15

    In this article, a new semi-continuum model is built to describe the fundamental vibration frequency of the silicon nanowires in <111> orientation. The Keating potential model and the discrete nature in the width and the thickness direction of the silicon nanowires in <111> orientation are applied in the new semi-continuum model. Based on the Keating model and the principle of conservation of energy, the vibration frequency of the silicon nanowires with the triangle, the rhombus, and the hexagon cross sections are derived. It is indicated that the calculation results based on this new model are accordant with the simulation results of the software based on molecular dynamics (MD).

  4. An induction motor model for high-frequency torsional vibration analysis

    Science.gov (United States)

    Widdle, R. D.; Krousgrill, C. M.; Sudhoff, S. D.

    2006-03-01

    High-frequency torsional oscillations of a 50 horsepower (hp) induction motor are investigated up to approximately 30 kHz. It is experimentally determined that torsional oscillations, due to the switching harmonics of the motor drive, contribute significantly to the torsional oscillation of the output shaft. Two torsional vibration models are developed. One model assumes the rotor to be rigid, while the other has a compliant rotor. The compliant model allows for greater transmission of high-frequency oscillations, and a better prediction of the measured output shaft vibration.

  5. Vibration Mode Observation of Piezoelectric Disk-type Resonator by High Frequency Laser Doppler Vibrometer

    Science.gov (United States)

    Matsumura, Takeshi; Esashi, Masayoshi; Harada, Hiroshi; Tanaka, Shuji

    For future mobile phones based on cognitive radio technology, a compact multi-band RF front-end architecture is strongly required and an integrated multi-band RF filter bank is a key component in it. Contour-mode resonators are receiving increased attention for a multi-band filter solution, because its resonant frequency is mainly determined by its size and shape, which are defined by lithography. However, spurious responses including flexural vibration are also excited due to its thin structure. To improve resonator performance and suppress spurious modes, visual observation with a laser probe system is very effective. In this paper, we have prototyped a mechanically-coupled disk-array filter, which consists of a Si disk and 2 disk-type resonators of higher-order wine-glass mode, and observed its vibration modes using a high-frequency laser-Doppler vibrometer (UHF-120, Polytec, Inc.). As a result, it was confirmed that higher order wine-glass mode vibration included a compound displacement, and that its out-of-plane vibration amplitude was much smaller than other flexural spurious modes. The observed vibration modes were compared with FEM (Finite Element Method) simulation results. In addition, it was also confirmed that the fabrication error, e.g. miss-alignment, induced asymmetric vibration.

  6. Relationship Between Psychomotor Efficiency and Sensation Seeking of People Exposed to Noise and Low Frequency Vibration Stimuli

    Science.gov (United States)

    Korchut, Aleksander; Kowalska-Koczwara, Alicja; Romanska – Zapała, Anna; Stypula, Krzysztof

    2017-10-01

    At the workplace of the machine operator, low frequency whole body and hand- arm vibrations are observed. They occur together with noise. Whole body vibration in the range of 3-25 Hz are detrimental to the human body due to the location of the resonant frequency of large organs of the human body in this range. It can be assumed that for this reason people working every day in such conditions can have reduced working efficiency. The influence of low frequency vibration and noise on the human body leads to both physiological and functional changes. The result of the impact of noise and vibration stimuli depends largely on the specific characteristics of the objects, which include among other personality traits, temperament and emotional factor. The pilot study conducted in the laboratory was attended by 30 young men. The aim of the study was to look for correlations between the need for stimulation of the objects and their psychomotor efficiency in case of vibration exposure and vibration together with noise exposure in variable conditions task. The need for stimulation of the objects as defined in the study is based on theoretical assumptions of one dimensional model of temperament developed by Marvin Zuckerman. This theory defines the need for stimulation as the search for different, new, complex and intense sensations, as well as the willingness to take risks. The aim of research was to verify if from four factors such as: the search for adventure and horror, sensation seeking, disinhibition and susceptibility to boredom, we can choose the ones that in conjunction with varying operating conditions, may significantly determine the efficiency of the task situation. The objects performed the test evaluation of their motor skills which consisted in keeping the cursor controlled by a joystick through the path. The number of exceeds of the cursor beyond the path and its maximum deviation was recorded. The collected data were used to determine the correlation between the

  7. Tunable Digital Metamaterial for Broadband Vibration Isolation at Low Frequency.

    Science.gov (United States)

    Wang, Ziwei; Zhang, Quan; Zhang, Kai; Hu, Gengkai

    2016-11-01

    A 3D-printed digital metamaterial embedded with electromagnets is fabricated. Switching electromagnets between the attaching (1 bit) and detaching (0 bit) modes activates different waveguides in the metamaterial. The underlying mechanism is investigated theoretically and experimentally. The hierarchical assemblies of unit cells, mimicking digital bits, allow programmable broadening of the bandgap of the metamaterial. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  8. Vibrational algorithms for quantitative crystallographic analyses of hydroxyapatite-based biomaterials: I, theoretical foundations.

    Science.gov (United States)

    Pezzotti, Giuseppe; Zhu, Wenliang; Boffelli, Marco; Adachi, Tetsuya; Ichioka, Hiroaki; Yamamoto, Toshiro; Marunaka, Yoshinori; Kanamura, Narisato

    2015-05-01

    The Raman spectroscopic method has quantitatively been applied to the analysis of local crystallographic orientation in both single-crystal hydroxyapatite and human teeth. Raman selection rules for all the vibrational modes of the hexagonal structure were expanded into explicit functions of Euler angles in space and six Raman tensor elements (RTE). A theoretical treatment has also been put forward according to the orientation distribution function (ODF) formalism, which allows one to resolve the statistical orientation patterns of the nm-sized hydroxyapatite crystallite comprised in the Raman microprobe. Close-form solutions could be obtained for the Euler angles and their statistical distributions resolved with respect to the direction of the average texture axis. Polarized Raman spectra from single-crystalline hydroxyapatite and textured polycrystalline (teeth enamel) samples were compared, and a validation of the proposed Raman method could be obtained through confirming the agreement between RTE values obtained from different samples.

  9. Optical and vibrational properties of phosphorylcholine-based contact lenses-Experimental and theoretical investigations

    Science.gov (United States)

    Filipecka, Katarzyna; Miedziński, Rafał; Sitarz, Maciej; Filipecki, Jacek; Makowska-Janusik, Małgorzata

    2017-04-01

    The Raman, MIR and UV-vis spectroscopy have been used to characterize Omafilcon A material constructing the one of the Proclear family contact lenses. The Omafilcon A is hydrogel material composed of 2-hydroxyethyl methacrylate (HEMA) and 2-methacryloyloxyethyl phosphorylcholine (PC) polymers crosslinked with ethyleneglycol dimethacrylate (EGDMA). Vibrational and electronic properties of the Omafilcon A material were also investigated by quantum chemical calculations. Experimentally obtained Raman, MIR and optical spectra were compared to the theoretical ones calculated applying RHF and DFT methodology. The quantum chemical calculations were performed for isolated monomers of lenses compounds as well as for their dimers and trimers to elucidate the effect of Omafilcon A polymerization and the role of an individual components.

  10. Active Mechanisms of Vibration Encoding and Frequency Filtering in Central Mechanosensory Neurons.

    Science.gov (United States)

    Azevedo, Anthony W; Wilson, Rachel I

    2017-10-11

    To better understand biophysical mechanisms of mechanosensory processing, we investigated two cell types in the Drosophila brain (A2 and B1 cells) that are postsynaptic to antennal vibration receptors. A2 cells receive excitatory synaptic currents in response to both directions of movement: thus, twice per vibration cycle. The membrane acts as a low-pass filter, so that voltage and spiking mainly track the vibration envelope rather than individual cycles. By contrast, B1 cells are excited by only forward or backward movement, meaning they are sensitive to vibration phase. They receive oscillatory synaptic currents at the stimulus frequency, and they bandpass filter these inputs to favor specific frequencies. Different cells prefer different frequencies, due to differences in their voltage-gated conductances. Both Na + and K + conductances suppress low-frequency synaptic inputs, so cells with larger voltage-gated conductances prefer higher frequencies. These results illustrate how membrane properties and voltage-gated conductances can extract distinct stimulus features into parallel channels. Copyright © 2017 Elsevier Inc. All rights reserved.

  11. Detailed Vibration Analysis of Pinion Gear with Time-Frequency Methods

    Science.gov (United States)

    Mosher, Marianne; Pryor, Anna H.; Lewicki, David G.

    2003-01-01

    In this paper, the authors show a detailed analysis of the vibration signal from the destructive testing of a spiral bevel gear and pinion pair containing seeded faults. The vibration signal is analyzed in the time domain, frequency domain and with four time-frequency transforms: the Short Time Frequency Transform (STFT), the Wigner-Ville Distribution with the Choi-Williams kernel (WV-CW), the Continuous Wavelet' Transform (CWT) and the Discrete Wavelet Transform (DWT). Vibration data of bevel gear tooth fatigue cracks, under a variety of operating load levels and damage conditions, are analyzed using these methods. A new metric for automatic anomaly detection is developed and can be produced from any systematic numerical representation of the vibration signals. This new metric reveals indications of gear damage with all of the time-frequency transforms, as well as time and frequency representations, on this data set. Analysis with the CWT detects changes in the signal at low torque levels not found with the other transforms. The WV-CW and CWT use considerably more resources than the STFT and the DWT. More testing of the new metric is needed to determine its value for automatic anomaly detection and to develop fault detection methods for the metric.

  12. Effects of low frequency vibration of a limb

    Science.gov (United States)

    Agarwal, G. C.; Gottlieb, G. L.

    1975-01-01

    Low frequency oscillations were applied on the ankle joint in plantarflexion/dorsiflexion rotation using a torque motor. The torque, the angular rotation and the evoked electromyogram from the gastronemius soleus and the anterior tibial muscles were recorded. Significant nonlinearities were observed in the angular rotation from 8 to 12 Hz. The following methods are used for data analysis: (1) Two cycle averaged response; (2) Fourier transform; and (3) Fourier analysis at the driving frequency. Important observations are: (1) resonance near 6 to 8 Hz; (2) slowly increasing amplitudes of oscillation near resonance; (3) self sustaining oscillations after the motor is turned off, particularly in the fatigued limb; and (4) distortion of angular rotation during which there are spontaneous recurrences of oscillation at the driving frequency.

  13. First-principles calculations on anharmonic vibrational frequencies of polyethylene and polyacetylene in the Gamma approximation.

    Science.gov (United States)

    Keçeli, Murat; Hirata, So; Yagi, Kiyoshi

    2010-07-21

    The frequencies of the infrared- and/or Raman-active (k=0) vibrations of polyethylene and polyacetylene are computed by taking account of the anharmonicity in the potential energy surfaces (PESs) and the resulting phonon-phonon couplings explicitly. The electronic part of the calculations is based on Gaussian-basis-set crystalline orbital theory at the Hartree-Fock and second-order Møller-Plesset (MP2) perturbation levels, providing one-, two-, and/or three-dimensional slices of the PES (namely, using the so-called n-mode coupling approximation with n=3), which are in turn expanded in the fourth-order Taylor series with respect to the normal coordinates. The vibrational part uses the vibrational self-consistent field, vibrational MP2, and vibrational truncated configuration-interaction (VCI) methods within the Gamma approximation, which amounts to including only k=0 phonons. It is shown that accounting for both electron correlation and anharmonicity is essential in achieving good agreement (the mean and maximum absolute deviations less than 50 and 90 cm(-1), respectively, for polyethylene and polyacetylene) between computed and observed frequencies. The corresponding values for the calculations including only one of such effects are in excess of 120 and 300 cm(-1), respectively. The VCI calculations also reproduce semiquantitatively the frequency separation and intensity ratio of the Fermi doublet involving the nu(2)(0) fundamental and nu(8)(pi) first overtone in polyethylene.

  14. Theoretical Investigation of C-H Vibrational Spectroscopy. 1. Modeling of Methyl and Methylene Groups of Ethanol with Different Conformers.

    Science.gov (United States)

    Wang, Lin; Ishiyama, Tatsuya; Morita, Akihiro

    2017-09-14

    A flexible and polarizable molecular model of ethanol is developed to extend our investigation of thermodynamic, structural, and vibrational properties of the liquid and interface. A molecular dynamics (MD) simulation with the present model confirmed that this model well reproduces a number of properties of liquid ethanol, including density, heat of vaporization, surface tension, molecular dipole moment, and trans/gauche ratio. In particular, the present model can describe vibrational IR, Raman, and sum frequency generation (SFG) spectra of ethanol and partially deuterated analogues with reliable accuracy. The improved accuracy is largely attributed to proper modeling of the conformational dependence and the intramolecular couplings including Fermi resonance in C-H vibrations. Precise dependence of torsional motions is found to be critical in representing vibrational spectra of the C-H bending. This model allows for further vibrational analysis of complicated alkyl groups widely observed in various organic molecules with MD simulation.

  15. Modeling Carbon Dioxide Vibrational Frequencies in Ionic Liquids: II. Spectroscopic Map.

    Science.gov (United States)

    Daly, Clyde A; Berquist, Eric J; Brinzer, Thomas; Garrett-Roe, Sean; Lambrecht, Daniel S; Corcelli, Steven A

    2016-12-15

    The primary challenge for connecting molecular dynamics (MD) simulations to linear and two-dimensional infrared measurements is the calculation of the vibrational frequency for the chromophore of interest. Computing the vibrational frequency at each time step of the simulation with a quantum mechanical method like density functional theory (DFT) is generally prohibitively expensive. One approach to circumnavigate this problem is the use of spectroscopic maps. Spectroscopic maps are empirical relationships that correlate the frequency of interest to properties of the surrounding solvent that are readily accessible in the MD simulation. Here, we develop a spectroscopic map for the asymmetric stretch of CO2 in the 1-butyl-3-methylimidazolium hexafluorophosphate ([C4C1im][PF6]) ionic liquid (IL). DFT is used to compute the vibrational frequency of 500 statistically independent CO2-[C4C1im][PF6] clusters extracted from an MD simulation. When the map was tested on 500 different CO2-[C4C1im][PF6] clusters, the correlation coefficient between the benchmark frequencies and the predicted frequencies was R = 0.94, and the root-mean-square error was 2.7 cm-1. The calculated distribution of frequencies also agrees well with experiment. The spectroscopic map required information about the CO2 angle, the electrostatics of the surrounding solvent, and the Lennard-Jones interaction between the CO2 and the IL. The contribution of each term in the map was investigated using symmetry-adapted perturbation theory calculations.

  16. Compact and Low-Frequency Vibration Energy Scavenger using the longitudinal excitation of a piezoelectric bar

    Science.gov (United States)

    Colin, M.; Mortier, Q.; Basrour, S.; Bencheikh, N.

    2013-12-01

    This paper introduces an innovative architecture of a piezoelectric harvester, which enables harvesting vibration energy at low frequency using the {33}-transduction mode of a piezoelectric element. Unlike cantilevers integrating ferroelectric material combined with interdigitated electrodes, the concept that we propose is based on the elongation/compression excitation of a piezoelectric bar.

  17. High frequency vibration conditioning stimulation centrally reduces myoelectrical manifestation of fatigue in healthy subjects.

    Science.gov (United States)

    Casale, Roberto; Ring, Haim; Rainoldi, Alberto

    2009-10-01

    Vibration conditioning has been adopted as a tool to improve muscle force and reduce fatigue onset in various rehabilitation settings. This study was designed to asses if high frequency vibration can induce some conditioning effects detectable in surface EMG (sEMG) signal; and whether these effects are central or peripheral in origin. 300 Hz vibration was applied for 30 min during 5 consecutive days, to the right biceps brachii muscle of 10 healthy males aged from 25 to 50 years. sEMG was recorded with a 16 electrode linear array placed on the skin overlying the vibrated muscle. The test protocol consisted of 30% and 60% maximal voluntary contraction (MVC) as well as involuntary (electrically elicited) contractions before and after treatment. No statistically significant differences were found between PRE and POST vibration conditioning when involuntary stimulus-evoked contraction and 30% MVC were used. Significant differences in the initial values and rates of change of muscle fibre conduction velocity were found only at 60% MVC. 300 Hz vibration did not induce any peripheral changes as demonstrated by the lack of differences when fatigue was electrically induced. Differences were found only when the muscle was voluntarily fatigued at 60% MVC suggesting a modification in the centrally driven motor unit recruitment order, and interpreted as an adaptive response to the reiteration of the vibratory conditioning.

  18. An experimental and theoretical study of the synthesis and vibrational spectroscopy of triacetone triperoxide (TATP)

    Science.gov (United States)

    Pacheco-Londono, Leonardo C.; Pena, Alvaro J.; Primera-Pedrozo, Oliva M.; Hernandez-Rivera, Samuel P.; Mina, Nairmen; Garcia, Rafael; Chamberlain, R. Thomas; Lareau, Richard T.

    2004-09-01

    Non nitrogen containing, organic peroxides explosives Triacetone triperoxide and diacetone diperoxide have been prepared in the laboratory in order to study various aspects of their synthesis and their experimental and theoretical spectroscopic characteristics. By using different proportions of acetone/hydrogen peroxide (Ac/H2O2), sulfuric, hydrochloric and methanosulfuric acids as catalyzers, it was possible to obtain both compounds in a rapid and simple form. Raman, IR spectroscopy, and GC-MS were used in order to determine the precursors, intermediates and final analytes. Experiments and theoretical studies using density functional theory (DFT) have been used in the elucidation step of the mechanism of the synthesis of the so called "transparent" explosives. The B3LYP functional with the 6-31G** basis set was used to carry out the electronic structure calculation of the intermediates and internal rotations and vibrations of TATP. Raman spectra of solid TATP and FTIR spectra of gas TATP, were recorded in order to assign the experimental spectra. Although full agreement with experiment was not obtained, spectral features of the main TATP bands were assigned.

  19. Photoisomerization of stilbene - a theoretical study of deuteration shifts and limited internal vibrational redistribution

    Science.gov (United States)

    Nordholm, Sture

    1989-10-01

    Very detailed experimental studies of the isomerization of trans-stilbene in the S 1 excited electronic state show features which are not readily explained by current theory, e.g., of RRKM type. In this work the deuteration shifts seen in the series C 14H 12, C 14H 10D 2, C 14D 10H 2, C 14D 12, where in the middle two species the ethylenic bridge positions are listed last, are investi RRKM theory modified so as to allow for a finite energy transfer rate between a critical oscillator and the remaining modes of the molecule. Vibrational frequencies are estimated on the basis of experimental results for the ground state molecule with the help of a product rule for deuteration shifts.

  20. Vibrational sum frequency spectroscopy studies at solid/liquid interfaces : Influence of the experimental geometry in the spectral shape and enhancement

    OpenAIRE

    Liljeblad, Jonathan F.D.; Tyrode, Eric

    2012-01-01

    The influence of the experimental geometry, specifically the angles of incidence (AOI) of the exciting beams, on the enhancement of the vibrational sum frequency spectroscopy (VSFS) spectra has been systematically investigated, particularly when approaching total internal reflection (TIR) conditions. Theoretical simulations of the spectral intensity as a function of the AOI and infrared wavelength at three different polarization combinations were critically compared to experimental data obtai...

  1. Influence of Temperature on Vibrational Frequency of Graphene Sheet Used as Nano-Scale Sensing

    Directory of Open Access Journals (Sweden)

    Toshiaki Natsuki

    2017-01-01

    Full Text Available In this study, the vibrational properties of single- and double-layer graphene sheets (GSs with attached nanoparticles are analyzed based on the nonlocal elasticity theory. The potential applications of atomic-scale mass sensing are presented using GSs with simply supported boundary condition. The frequency equation for GSs with an attached nanoparticle is derived to investigate the vibration frequency of the GSs under thermal environment. Using the proposed model, the relationship between the frequency shifts of graphene-based mass sensor and the attached nanoparticles is obtained. The nonlocal effect and the temperature dependence on the variation of frequency shifts with the attached nanomass and the positions on the GS are investigated and discussed in detail. The obtained results show that the nanomass can be easily detected by using GS resonator which provides a highly sensitive nanomechanical element in sensor systems. The vibrational frequency shift of GS increases with increasing the temperature dependence. The double-layer GSs (DLGSs have higher sensitivity than the single-layer GSs (SLGSs due to high frequency shifts.

  2. Non-linear Vibration of Oscillation Systems using Frequency-Amplitude Formulation

    DEFF Research Database (Denmark)

    Fereidoon, A.; Ghadimi, M.; Barari, Amin

    2012-01-01

    In this paper we study the periodic solutions of free vibration of mechanical systems with third and fifthorder nonlinearity for two examples using He’s Frequency Amplitude Formulation (HFAF).The effectiveness and convenience of the method is illustrated in these examples. It will be shown...... that the solutions obtained with current method have a fabulous conformity with those achieved from time marching solution. HFAF is easy with powerful concepts and the high accuracy, so it can be found widely applicable in vibrations, especially strong nonlinearity oscillatory problems....

  3. In vivo measurement of basilar membrane vibration in the unopened chinchilla cochlea using high frequency ultrasound.

    Science.gov (United States)

    Landry, Thomas G; Bance, Manohar L; Leadbetter, Jeffrey; Adamson, Robert B; Brown, Jeremy A

    2017-06-01

    The basilar membrane and organ of Corti in the cochlea are essential for sound detection and frequency discrimination in normal hearing. There are currently no methods used for real-time high resolution clinical imaging or vibrometry of these structures. The ability to perform such imaging could aid in the diagnosis of some pathologies and advance understanding of the causes. It is demonstrated that high frequency ultrasound can be used to measure basilar membrane vibrations through the round window of chinchilla cochleas in vivo. The basic vibration characteristics of the basilar membrane agree with previous studies that used other methods, although as expected, the sensitivity of ultrasound was not as high as optical methods. At the best frequency for the recording location, the average vibration velocity amplitude was about 4 mm/s/Pa with stimulus intensity of 50 dB sound pressure level. The displacement noise floor was about 0.4 nm with 256 trial averages (5.12 ms per trial). Although vibration signals were observed, which likely originated from the organ of Corti, the spatial resolution was not adequate to resolve any of the sub-structures. Improvements to the ultrasound probe design may improve resolution and allow the responses of these different structures to be better discriminated.

  4. Elastic Metamaterial Insulator for Broadband Low-Frequency Flexural Vibration Shielding

    Science.gov (United States)

    Oh, Joo Hwan; Qi, Shuibao; Kim, Yoon Young; Assouar, Badreddine

    2017-11-01

    Achieving stop band over broadband at low-frequency range has remained a great scientific challenge in spite of various efforts made using metamaterials or other technologies. In this work, we propose an idea that creates a stop band for broadband at low-frequency range. The dual mechanism of shear stiffening and rotation softening is initiated here to achieve a broad stop band at low-frequency range. Through analytical, numerical, and experimental studies, we reveal the underlying physical mechanism and confirm the effectiveness of this metamaterial on vibration shielding for flexural elastic wave covering 235 to 4520 Hz. This work opens an avenue for the development of elastic metamaterials with performance and functionalities that are highly desirable in many fields such as vibration shielding.

  5. Coupled analysis of multi-impact energy harvesting from low-frequency wind induced vibrations

    Science.gov (United States)

    Zhu, Jin; Zhang, Wei

    2015-04-01

    Energy need from off-grid locations has been critical for effective real-time monitoring and control to ensure structural safety and reliability. To harvest energy from ambient environments, the piezoelectric-based energy-harvesting system has been proven very efficient to convert high frequency vibrations into usable electrical energy. However, due to the low frequency nature of the vibrations of civil infrastructures, such as those induced from vehicle impacts, wind, and waves, the application of a traditional piezoelectric-based energy-harvesting system is greatly restrained since the output power drops dramatically with the reduction of vibration frequencies. This paper focuses on the coupled analysis of a proposed piezoelectric multi-impact wind-energy-harvesting device that can effectively up-convert low frequency wind-induced vibrations into high frequency ones. The device consists of an H-shape beam and four bimorph piezoelectric cantilever beams. The H-shape beam, which can be easily triggered to vibrate at a low wind speed, is originated from the first Tacoma Narrows Bridge, which failed at wind speeds of 18.8 m s-1 in 1940. The multi-impact mechanism between the H-shape beam and the bimorph piezoelectric cantilever beams is incorporated to improve the harvesting performance at lower frequencies. During the multi-impact process, a series of sequential impacts between the H-shape beam and the cantilever beams can trigger high frequency vibrations of the cantilever beams and result in high output power with a considerably high efficiency. In the coupled analysis, the coupled structural, aerodynamic, and electrical equations are solved to obtain the dynamic response and the power output of the proposed harvesting device. A parametric study for several parameters in the coupled analysis framework is carried out including the external resistance, wind speed, and the configuration of the H-shape beam. The average harvested power for the piezoelectric cantilever

  6. Occurrence of fatigue induced by a whole-body vibration session is not frequency dependent.

    Science.gov (United States)

    Zory, Raphael F; Raphael, Zory F; Aulbrook, Wesley; Wesley, Aulbrook; Keir, Daniel A; Daniel, Keir A; Serresse, Olivier; Olivier, Serresse

    2013-09-01

    The aim of this study was to determine whether neuromuscular adaptations (magnitude and location) induced by isometric exercise performed on an oscillating platform are dependent on whole-body vibration (WBV) frequency. Eleven young men performed 4 separate fatigue sessions of static squatting exercise at 3 frequencies of WBV (V20, V40, and V60) and 1 session without vibration (V0). Isometric torque and electromyographic activity of the vastus lateralis, rectus femoris, and biceps femoris were recorded during maximal voluntary and evoked contractions of the knee extensor muscles before and after each fatigue session to examine both peripheral and central adaptations. Isometric torque decreased significantly after each of the 4 frequency sessions (V0: -9.4 ± 6.1%, p = 0.003; V20: -8.1 ± 9.9%, p = 0.010; V40: -11.9 ± 12.7%, p = 0.011; and V60: -7.8 ± 9.2%, p = 0.001, respectively), but this reduction was not significantly different between frequencies. The torque produced by evoked contraction significantly decreased from pre-exercise values after each session (V0: -14.9 ± 15.6%, p = 0.012; V20: -15.8 ± 16.4%, p = 0.010; V40: -21.0 ± 14.3%, p = 0.004; and V60: -17.3 ± 11.6%, p = 0.005, respectively); however, there was no effect of vibration frequency. In both conditions, the maximal voluntary contraction torque reduction observed was mainly attributable to peripheral fatigue and was not because of central modifications of the neuromuscular system. The present study demonstrates that the frequency of vibration does not significantly influence the magnitude and location of neuromuscular fatigue, suggesting that adding WBV to static squat exercise (on a vertically oscillating platform) does not provide an additional training stimulus.

  7. Theory and experiment research for ultra-low frequency maglev vibration sensor

    Energy Technology Data Exchange (ETDEWEB)

    Zheng, Dezhi; Liu, Yixuan, E-mail: xuan61x@163.com; Guo, Zhanshe; Fan, Shangchun [School of Instrument Science and Opto-electronics Engineering, Beihang University, Beijing 100191 (China); Zhao, Xiaomeng [Laser Medicine Laboratory, Institute of Biomedical Engineering, Chinese Academy of medical Sciences and Peking Union Medical College, Tianjin 300192 (China)

    2015-10-15

    A new maglev sensor is proposed to measure ultra-low frequency (ULF) vibration, which uses hybrid-magnet levitation structure with electromagnets and permanent magnets as the supporting component, rather than the conventional spring structure of magnetoelectric vibration sensor. Since the lower measurement limit needs to be reduced, the equivalent bearing stiffness coefficient and the equivalent damping coefficient are adjusted by the sensitivity unit structure of the sensor and the closed-loop control system, which realizes both the closed-loop control and the solving algorithms. A simple sensor experimental platform is then assembled based on a digital hardware system, and experimental results demonstrate that the lower measurement limit of the sensor is increased to 0.2 Hz under these experimental conditions, indicating promising results of the maglev sensor for ULF vibration measurements.

  8. Wide operation frequency band magnetostrictive vibration power generator using nonlinear spring constant by permanent magnet

    Science.gov (United States)

    Furumachi, S.; Ueno, T.

    2016-04-01

    We study magnetostrictive vibration based power generator using iron-gallium alloy (Galfenol). The generator is advantages over conventional, such as piezoelectric material in the point of high efficiency highly robust and low electrical impedance. Generally, the generator exhibits maximum power when its resonant frequency matches the frequency of ambient vibration. In other words, the mismatch of these frequencies results in significant decrease of the output. One solution is making the spring characteristics nonlinear using magnetic force, which distorts the resonant peak toward higher or lower frequency side. In this paper, vibrational generator consisting of Galfenol plate of 6 by 0.5 by 13 mm wound with coil and U shape-frame accompanied with plates and pair of permanent magnets was investigated. The experimental results show that lean of resonant peak appears attributed on the non-linear spring characteristics, and half bandwidth with magnets is 1.2 times larger than that without. It was also demonstrated that the addition of proof mass is effective to increase the sensitivity but also the bandwidth. The generator with generating power of sub mW order is useful for power source of wireless heath monitoring for bridge and factory machine.

  9. Time-frequency vibration analysis for the detection of motor damages caused by bearing currents

    Science.gov (United States)

    Prudhom, Aurelien; Antonino-Daviu, Jose; Razik, Hubert; Climente-Alarcon, Vicente

    2017-02-01

    Motor failure due to bearing currents is an issue that has drawn an increasing industrial interest over recent years. Bearing currents usually appear in motors operated by variable frequency drives (VFD); these drives may lead to common voltage modes which cause currents induced in the motor shaft that are discharged through the bearings. The presence of these currents may lead to the motor bearing failure only few months after system startup. Vibration monitoring is one of the most common ways for detecting bearing damages caused by circulating currents; the evaluation of the amplitudes of well-known characteristic components in the vibration Fourier spectrum that are associated with race, ball or cage defects enables to evaluate the bearing condition and, hence, to identify an eventual damage due to bearing currents. However, the inherent constraints of the Fourier transform may complicate the detection of the progressive bearing degradation; for instance, in some cases, other frequency components may mask or be confused with bearing defect-related while, in other cases, the analysis may not be suitable due to the eventual non-stationary nature of the captured vibration signals. Moreover, the fact that this analysis implies to lose the time-dimension limits the amount of information obtained from this technique. This work proposes the use of time-frequency (T-F) transforms to analyse vibration data in motors affected by bearing currents. The experimental results obtained in real machines show that the vibration analysis via T-F tools may provide significant advantages for the detection of bearing current damages; among other, these techniques enable to visualise the progressive degradation of the bearing while providing an effective discrimination versus other components that are not related with the fault. Moreover, their application is valid regardless of the operation regime of the machine. Both factors confirm the robustness and reliability of these tools

  10. Gel performance in rheology and profile control under low-frequency vibration: coupling application of physical and chemical EOR techniques.

    Science.gov (United States)

    Zheng, Li Ming; Pu, Chun Sheng; Liu, Jing; Ma, Bo; Khan, Nasir

    2017-01-01

    Flowing gel plugging and low-frequency vibration oil extraction technology have been widely applied in low-permeability formation. High probability of overlapping in action spheres of two technologies might lead to poor operating efficiency during gel injection. Study on flowing gel rheological properties under low-frequency vibration was essential, which was carried out indoor with viscosity measurement. Potential dynamic mechanisms were analyzed for the rheological variation. Under low-frequency vibration, gel rheological properties were found to be obviously influenced, with vibration delaying gel cross-linking in induction period, causing a two-stage gel viscosity change in acceleration period, and decreasing gel strength in stable period. Surface of gel system under vibration presented different fluctuating phenomenon from initial harmonic vibrating to heterogeneous fluctuating (droplet separation might appear) to final harmonic vibrating again. Dynamic displacement in unconsolidated sand pack revealed that low-frequency vibration during gel injection might be a measure to achieve deep profile control, with the gel injection depth increased by 65.8 % compared with the vibration-free sample. At last, suggestions for field test were given in the paper to achieve lower injection friction and better gel plugging efficiency.

  11. Three-dimensional piezoelectric vibration energy harvester using spiral-shaped beam with triple operating frequencies

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Nian; Yang, Jin, E-mail: yangjin@cqu.edu.cn; Yu, Qiangmo; Zhao, Jiangxin; Liu, Jun; Wen, Yumei; Li, Ping [Department of Optoelectronic Engineering, Chongqing University, Chongqing 400044 (China)

    2016-01-15

    This work has demonstrated a novel piezoelectric energy harvester without a complex structure and appended component that is capable of scavenging vibration energy from arbitrary directions with multiple resonant frequencies. In this harvester, a spiral-shaped elastic thin beam instead of a traditional thin cantilever beam was adopted to absorb external vibration with arbitrary direction in three-dimensional (3D) spaces owing to its ability to bend flexibly and stretch along arbitrary direction. Furthermore, multiple modes in the elastic thin beam contribute to a possibility to widen the working bandwidth with multiple resonant frequencies. The experimental results show that the harvester was capable of scavenging the vibration energy in 3D arbitrary directions; they also exhibited triple power peaks at about 16 Hz, 21 Hz, and 28 Hz with the powers of 330 μW, 313 μW, and 6 μW, respectively. In addition, human walking and water wave energies were successfully converted into electricity, proving that our harvester was practical to scavenge the time-variant or multi-directional vibration energies in our daily life.

  12. Sparse Representation Based Frequency Detection and Uncertainty Reduction in Blade Tip Timing Measurement for Multi-Mode Blade Vibration Monitoring

    Science.gov (United States)

    Pan, Minghao; Yang, Yongmin; Guan, Fengjiao; Hu, Haifeng; Xu, Hailong

    2017-01-01

    The accurate monitoring of blade vibration under operating conditions is essential in turbo-machinery testing. Blade tip timing (BTT) is a promising non-contact technique for the measurement of blade vibrations. However, the BTT sampling data are inherently under-sampled and contaminated with several measurement uncertainties. How to recover frequency spectra of blade vibrations though processing these under-sampled biased signals is a bottleneck problem. A novel method of BTT signal processing for alleviating measurement uncertainties in recovery of multi-mode blade vibration frequency spectrum is proposed in this paper. The method can be divided into four phases. First, a single measurement vector model is built by exploiting that the blade vibration signals are sparse in frequency spectra. Secondly, the uniqueness of the nonnegative sparse solution is studied to achieve the vibration frequency spectrum. Thirdly, typical sources of BTT measurement uncertainties are quantitatively analyzed. Finally, an improved vibration frequency spectra recovery method is proposed to get a guaranteed level of sparse solution when measurement results are biased. Simulations and experiments are performed to prove the feasibility of the proposed method. The most outstanding advantage is that this method can prevent the recovered multi-mode vibration spectra from being affected by BTT measurement uncertainties without increasing the probe number. PMID:28758952

  13. Atropisomerism at C ̶ N bonds: Structural conformations and vibrational spectral study of Iminothiazoline Derivatives with density functional theoretical optimizations

    Directory of Open Access Journals (Sweden)

    F.Z. MIMOUNI

    2013-03-01

    Full Text Available The isolation of the pair atropisomers of the both iminothiazoline derivatives and the spectroscopic analytical of the compound have been computed using B3LYP/6-31G(d,p level to derive the equilibrium geometry, conformational stability, molecular orbital energies and vibrational frequencies was studied in this paper.

  14. Development of Low Frequency Vibration Method of Direct-Write Deposition Relevant to Layer Manufacturing Application

    Directory of Open Access Journals (Sweden)

    Susilo Widyanto

    2010-10-01

    Full Text Available The research of deposition process is the first step in development process of multi materials selective laser sintering. The deposition process enables to settle multi materials powder in horizontal formation on one layer. In this research we use low frequency (70 - 200Hz to vibrate a hopper nozzle in which powder is settled. The research method consists of two steps, the first step is to determine flow-ability parameters and the second is to join flow ability parameter with other parameters such that the line width can be controlled. The results show that the line width depends on uniformity of particle size, particle size, frequency of vibration, deposition gap, particle shape and feed-rate of hopper-nozzle.

  15. A utility piezoelectric energy harvester with low frequency and high-output voltage: Theoretical model, experimental verification and energy storage

    Directory of Open Access Journals (Sweden)

    Guangyi Zhang

    2016-09-01

    Full Text Available In this paper, a utility piezoelectric energy harvester with low frequency and high-output voltage is presented. Firstly, the harvester’s three theoretical models are presented, namely the static model, the quasi static model and the dynamic vibration model. By analyzing the influence of the mass ratio of the mass block to the beam on output characteristics of the harvester, we compare the quasi static model and the dynamic vibration model and then define their applicable ranges. Secondly, simulation and experiments are done to verify the models, using the harvester with PZT-5H piezoelectric material, which are proved to be consistent with each other. The experimental results show that the output open-circuit voltage and the output power can reach up to 86.36V and 27.5mW respectively. The experiments are conducted when this harvester system is excited by the first modal frequency (58.90Hz with the acceleration 10m/s2. In this low frequency vibration case, it is easy to capture the energy in the daily environment. In addition, LTC 3588-1 chip (Linear Technology Corporation is used as the medium energy circuit to transfer charges from the PZT-5H electrode to the 0.22F 5V super capacitor and ML621 rechargeable button battery. For this super-capacitor, it takes about 100min for the capacitor voltage to rise from 0V to 3.6V. For this button battery, it takes about 200min to increase the battery voltage from 2.5V to 3.48V.

  16. Vibrational characteristics of FRP-bonded concrete interfacial defects in a low frequency regime

    Science.gov (United States)

    Cheng, Tin Kei; Lau, Denvid

    2014-04-01

    As externally bonded fiber-reinforced polymer (FRP) is a critical load-bearing component of strengthened or retrofitted civil infrastructures, the betterment of structural health monitoring (SHM) methodology for such composites is imperative. Henceforth the vibrational characteristics of near surface interfacial defects involving delamination and trapped air pockets at the FRP-concrete interface are investigated in this study using a finite element approach. Intuitively, due to its lower interfacial stiffness compared with an intact interface, a damaged region is expected to have a set of resonance frequencies different from an intact region when excited by acoustic waves. It has been observed that, when excited acoustically, both the vibrational amplitudes and frequency peaks in the response spectrum of the defects demonstrate a significant deviation from an intact FRP-bonded region. For a thin sheet of FRP bonded to concrete with sizable interfacial defects, the fundamental mode under free vibration is shown to be relatively low, in the order of kHz. Due to the low resonance frequencies of the defects, the use of low-cost equipment for interfacial defect detection via response spectrum analysis is highly feasible.

  17. Low-frequency vibration treatment of bone marrow stromal cells induces bone repair in vivo

    Directory of Open Access Journals (Sweden)

    Shengwei He

    2017-01-01

    Full Text Available Objective(s:To study the effect of low-frequency vibration on bone marrow stromal cell differentiation and potential bone repair in vivo. Materials and Methods:Forty New Zealand rabbits were randomly divided into five groups with eight rabbits in each group. For each group, bone defects were generated in the left humerus of four rabbits, and in the right humerus of the other four rabbits. To test differentiation, bones were isolated and demineralized, supplemented with bone marrow stromal cells, and implanted into humerus bone defects. Varying frequencies of vibration (0, 12.5, 25, 50, and 100 Hz were applied to each group for 30 min each day for four weeks. When the bone defects integrated, they were then removed for histological examination. mRNA transcript levels of runt-related transcription factor 2, osteoprotegerin, receptor activator of nuclear factor k-B ligan, and pre-collagen type 1 a were measured. Results:Humeri implanted with bone marrow stromal cells displayed elevated callus levels and wider, more prevalent, and denser trabeculae following treatment at 25 and 50 Hz. The mRNA levels of runt-related transcription factor 2, osteoprotegerin, receptor activator of nuclear factor k-B ligand, and pre-collagen type 1 a were also markedly higher following 25 and 50 Hz treatment. Conclusion:Low frequency (25–50 Hz vibration in vivo can promote bone marrow stromal cell differentiation and repair bone injury.

  18. Theoretical Study of Amplitude Modulation Application during Radio Frequency Electrocoagulation

    Directory of Open Access Journals (Sweden)

    V. A. Karpuhin

    2015-01-01

    Full Text Available This article concerns the investigation results of influence of the amplitude-modulated acting signal parameters on the thermoelectric characteristics of biological tissues for a specified geometry of the working electrode section during RF mono-polar electrocoagulation. The geometric model ‘electrode - a biological tissue’ was suggested to study the distribution of power and temperature fields in biological tissue during mono-polar coagulation. The model of biological tissue is represented as a cylinder and the needle electrode is an ellipsoid immersed in the biological tissue. The heat and quasi-electrostatics equations are used as a mathematical model. These equations are solved in Comsol Multiphysics environment.As a result, we have got the following findings: the technique of calculating parameters of the PAM acting signal which has a fixed carrier frequency for the needle electrode of a specified geometry and the immersion depth in biological tissues is suggested. Parameters of PAM signal are determined for this electrode geometry. These parameters provide a 60 ... 80°C heating range of biological tissues near the working part of the tool for different amplitudes of acting signal during RF coagulation. It has been found out that both the temperature and the relaxation frequency of biological tissue depend on exposure time for the needle electrode of a specified geometry and immersion depth of the working part of tool into biological tissue.It is shown that the relaxation frequency of the biological tissue, subjected to the radiofrequency pulses, linearly depends on its heating temperature and can be used as a numerical criterion for maintaining the specified temperature conditions. It is found that the relaxation frequency of the biological tissue depends on the contact area of the tool working part and biological tissues. To reduce this dependence it is necessary to provide automatic current control of the output action.

  19. Effects of vibration frequency on vibration-assisted nano-scratch process of mono-crystalline copper via molecular dynamics simulation

    Directory of Open Access Journals (Sweden)

    Bo Zhu

    2016-03-01

    Full Text Available It has always been a critical issue to understand the material removal behavior of Vibration-Assisted Machining (VAM, especially on atomic level. To find out the effects of vibration frequency on material removal response, a three-dimensional molecular dynamics (MD model has been established in this research to investigate the effects of scratched groove, crystal defects on the surface quality, comparing with the Von Mises shear strain and tangential force in simulations during nano-scratching process. Comparisons are made among the results of simulations from different vibration frequency with the same scratching feed, depth, amplitude and crystal orientation. Copper potential in this simulation is Embedded-Atom Method (EAM potential. Interaction between copper and carbon atoms is Morse potential. Simulational results show that higher frequency can make groove smoother. Simulation with high frequency creates more dislocations to improve the machinability of copper specimen. The changing frequency does not have evident effects on Von Mises shear strain. Higher frequency can decrease the tangential force to reduce the consumption of cutting energy and tool wear. In conclusion, higher vibration frequency in VAM on mono-crystalline copper has positive effects on surface finish, machinablility and tool wear reduction.

  20. Algorithm for the calculation of vibration inherent frequencies bending from two-shafts transmission

    Directory of Open Access Journals (Sweden)

    Grigore Jan-Cristian

    2017-01-01

    Full Text Available The operation of the speed shaft transmissions at or near the natural frequency of the pulses at the resonance phenomenon leads to bending, when the amplitude of the oscillations increases sharply, causing deterioration or complete destruction thereof. To avoid system resonance operation is necessary to know the most accurate values its pulsations and taking appropriate constructive measures to avoid overlapping with disturbing frequency harmonics (operating speeds.This paper presents an algorithm for calculating the pulsation and vibration modes in bending, and based on numerical simulations performed on a real two-shafts transmission and will draw conclusions drawn diagrams.

  1. Conformational energetics and low-frequency vibrations of cyclohexene and its oxygen analogs

    Science.gov (United States)

    Ocola, Esther J.; Brito, Teresa; McCann, Kathleen; Laane, Jaan

    2010-08-01

    Ab initio and DFT calculations with MP2/cc-pVTZ and B3LYP/cc-pVTZ basis sets have been carried out for cyclohexene and four of its oxygen analogs. All of the molecules possess a twisted structure while the bent forms represent saddle points in two-dimensional surfaces. The structures, relative energies, and frequencies for the lowest energy vibrations of the twisted, bent, and planar forms were calculated and compared to experimental results. The calculated results agree very well with the microwave data but the computed barriers are somewhat less than those based on low-frequency infrared data.

  2. Bi-resonant structure with piezoelectric PVDF films for energy harvesting from random vibration sources at low frequency

    DEFF Research Database (Denmark)

    Liang, Shanshan; Crovetto, Andrea; Peng, Zhuoteng

    2016-01-01

    and experiments with piezoelectric elements show that the energy harvesting device with the bi-resonant structure can generate higher power output than that of the sum of the two separate devices from random vibration sources at low frequency, and hence significantly improves the vibration-to- electricity...

  3. Effect of vibration frequency on microstructure and performance of high chromium cast iron prepared by lost foam casting

    Directory of Open Access Journals (Sweden)

    Wen-qi Zou

    2016-07-01

    Full Text Available In the present research, high chromium cast irons (HCCIs were prepared using the lost foam casting (LFC process. To improve the wear resistance of the high chromium cast irons (HCCIs, mechanical vibration was employed during the solidification of the HCCIs. The effects of vibration frequency on the microstructure and performance of the HCCIs under as-cast, as-quenched and as-tempered conditions were investigated. The results indicated that the microstructures of the LFC-produced HCCIs were refined due to the introduction of mechanical vibration, and the hardness was improved compared to that of the alloy without vibration. However, only a slight improvement in hardness was found in spite of the increase of vibration frequency. In contrast, the impact toughness of the as-tempered HCCIs increased with an increase in the vibration frequency. In addition, the wear resistance of the HCCIs was improved as a result of the introduction of vibration and increased with an increase in the vibration frequency.

  4. Comparison of resonance frequencies between normal and tangential vibration modes of graphene-nanoribbon-resonators.

    Science.gov (United States)

    Kwon, Oh Kuen; Hwang, Ho Jung; Park, Jungcheol

    2013-12-01

    We investigate tunable graphene-nanoribbon (GNR)-resonators actuated in the tangential direction, and their properties are compared to those actuated in the normal direction, via classical molecular dynamics simulations. These GNR-resonators can be tuned both by the initial strain and the gate. The relationships between the frequency-versus-gate and the initial strain in this work are in good agreement with those in previous experimental works. With increasing initial strain, the resonance frequencies are greatly upshifted, whereas the tunable ranges in frequency are greatly decreased. The tunability in the dynamic operating range decreases with increasing initial strain. For very small strains, the GNR-resonators have large dynamic operating ranges in the normal vibration mode, and for large strains, the GNR-resonators have higher operating frequencies in the tangential vibration mode. The resonance frequencies are estimated by a classical continuum model, with tension acting on the GNR-resonators consisting of both initial tension by initial strain and induced tension by gate actuating.

  5. Vibration sensor data denoising using a time-frequency manifold for machinery fault diagnosis.

    Science.gov (United States)

    He, Qingbo; Wang, Xiangxiang; Zhou, Qiang

    2013-12-27

    Vibration sensor data from a mechanical system are often associated with important measurement information useful for machinery fault diagnosis. However, in practice the existence of background noise makes it difficult to identify the fault signature from the sensing data. This paper introduces the time-frequency manifold (TFM) concept into sensor data denoising and proposes a novel denoising method for reliable machinery fault diagnosis. The TFM signature reflects the intrinsic time-frequency structure of a non-stationary signal. The proposed method intends to realize data denoising by synthesizing the TFM using time-frequency synthesis and phase space reconstruction (PSR) synthesis. Due to the merits of the TFM in noise suppression and resolution enhancement, the denoised signal would have satisfactory denoising effects, as well as inherent time-frequency structure keeping. Moreover, this paper presents a clustering-based statistical parameter to evaluate the proposed method, and also presents a new diagnostic approach, called frequency probability time series (FPTS) spectral analysis, to show its effectiveness in fault diagnosis. The proposed TFM-based data denoising method has been employed to deal with a set of vibration sensor data from defective bearings, and the results verify that for machinery fault diagnosis the method is superior to two traditional denoising methods.

  6. Whole Body Vibration at Different Exposure Frequencies: Infrared Thermography and Physiological Effects

    Directory of Open Access Journals (Sweden)

    Anelise Sonza

    2015-01-01

    Full Text Available The aim of this study was to investigate the effects of whole body vibration (WBV on physiological parameters, cutaneous temperature, tactile sensitivity, and balance. Twenty-four healthy adults (25.3±2.6 years participated in four WBV sessions. They spent 15 minutes on a vibration platform in the vertical mode at four different frequencies (31, 35, 40, and 44 Hz with 1 mm of amplitude. All variables were measured before and after WBV exposure. Pressure sensation in five anatomical regions and both feet was determined using Von Frey monofilaments. Postural sway was measured using a force plate. Cutaneous temperature was obtained with an infrared camera. WBV influences the discharge of the skin touch-pressure receptors, decreasing sensitivity at all measured frequencies and foot regions (P≤0.05. Regarding balance, no differences were found after 20 minutes of WBV at frequencies of 31 and 35 Hz. At 40 and 44 Hz, participants showed higher anterior-posterior center of pressure (COP velocity and length. The cutaneous temperature of the lower limbs decreased during and 10 minutes after WBV. WBV decreases touch-pressure sensitivity at all measured frequencies 10 min after exposure. This may be related to the impaired balance at higher frequencies since these variables have a role in maintaining postural stability. Vasoconstriction might explain the decreased lower limb temperature.

  7. Vibration Frequencies Extraction of the Forth Road Bridge Using High Sampling GPS Data

    Directory of Open Access Journals (Sweden)

    Jian Wang

    2016-01-01

    Full Text Available This paper proposes a scheme for vibration frequencies extraction of the Forth Road Bridge in Scotland from high sampling GPS data. The interaction between the dynamic response and the ambient loadings is carefully analysed. A bilinear Chebyshev high-pass filter is designed to isolate the quasistatic movements, the FFT algorithm and peak-picking approach are applied to extract the vibration frequencies, and a GPS data accumulation counter is suggested for real-time monitoring applications. To understand the change in the structural characteristics under different loadings, the deformation results from three different loading conditions are presented, that is, the ambient circulation loading, the strong wind under abrupt wind speed change, and the specific trial with two 40 t lorries passing the bridge. The results show that GPS not only can capture absolute 3D deflections reliably, but also can be used to extract the frequency response accurately. It is evident that the frequencies detected using the filtered deflection time series in different direction show quite different characteristics, and more stable results can be obtained from the height displacement time series. The frequency responses of 0.105 and 0.269 Hz extracted from the lateral displacement time series correlate well with the data using height displacement time series.

  8. Electrostatic MEMS vibration energy harvester for HVAC applications with impact-based frequency up-conversion

    Science.gov (United States)

    Oxaal, J.; Hella, M.; Borca-Tasciuc, D.-A.

    2016-12-01

    This paper reports on electrostatic MEMS vibration energy harvesters with gap-closing interdigitated electrodes, designed for and tested on HVAC air ducts. The harvesters were fabricated on SOI wafers with 200 µm device layer using a custom microfabrication process. Designs with aspects ratio (electrodes’ gap versus depth) of 10 and 20 were implemented, while the overall footprint was approximately 1 cm  ×  1 cm in both cases. In order to enhance the power output, a dual-level physical stopper system was designed to control the minimum gap between the electrodes, which is a key parameter in the conversion process. The dual-level stopper utilizes cantilever beams to absorb a portion of the impact energy as the electrodes approach the impact point, and a film of parylene with nanometer thickness deposited on the electrode sidewalls. The parylene layer defines the absolute minimum gap and provides electrical insulation. The fabricated devices were first tested on a vibration shaker to characterize the resonant behavior. Devices with aspect ratio 10 were found to exhibit frequency up-conversion, which enhances the amount of converted power. Devices with both aspect ratios were found to exhibits spring hardening due to impact with the stoppers and spring softening behavior at increasing voltage bias. The highest power measured on shaker table for sinusoidal vibrations was 3.13 µW (includes enhancement due to frequency up-conversion driven by impact) for aspect ratio 10, and 0.166 µW for aspect ratio 20. The corresponding dimensional figure-of-merit, defined as the power output normalized to vibration acceleration and frequency, squared voltage and device mass, was in the range of 10 · 10-8 m V-2 for both devices, about an order of magnitude higher than state-of-the-art. Testing was carried out on HVAC air duct vibrating with an RMS acceleration of 155 mg RMS, a primary frequency of 60 Hz and a PSD of 7.15 · 10-2 g2 Hz-1. The peak power measured was

  9. a Hamiltonian to Obtain a Global Frequency Analysis of all the Vibrational Bands of Ethane

    Science.gov (United States)

    Moazzen-Ahmadi, Nasser; Norooz Oliaee, Jalal

    2016-06-01

    The interest in laboratory spectroscopy of ethane stems from the desire to understand the methane cycle in the atmospheres of planets and their moons and from the importance of ethane as a trace species in the terrestrial atmosphere. Solar decomposition of methane in the upper part of these atmospheres followed by a series of reactions leads to a variety of hydrocarbon compounds among which ethane is often the second most abundant species. Because of its high abundance, ethane spectra have been measured by Voyager and Cassini in the regions around 30, 12, 7, and 3 μm. Therefore, a complete knowledge of line parameters of ethane is crucial for spectroscopic remote sensing of planetary atmospheres. Experimental characterization of torsion-vibration states of ethane lying below 1400 cm-1 have been made previously, but extension of the Hamiltonian model for treatment of the strongly perturbed νb{8} fundamental and the complex band system of ethane in the 3 micron region requires careful examination of the operators for many new torsionally mediated vibration-rotation interactions. Following the procedures outlined by Hougen, we have re-examined the transformation properties of the total angular momentum, the translational and vibrational coordinates and momenta of ethane, and for vibration-torsion-rotation interaction terms constructed by taking products of these basic operators. It is found that for certain choices of phase, the doubly degenerate vibrational coordinates with and symmetry can be made to transform under the group elements in such a way as to yield real matrix elements for the torsion-vibration-rotation couplings whereas other choices of phase may require complex algebra. In this talk, I will discuss the construction of a very general torsion-vibration-rotation Hamiltonian for ethane, as well as the prospect for using such a Hamiltonian to obtain a global frequency analysis (based in large part on an extension of earlier programs and ethane fits^a from

  10. Analysis of Vibration Exercise at Varying Frequencies by Different Fatigue Estimators.

    Science.gov (United States)

    Xu, Lin; Rabotti, Chiara; Mischi, Massimo

    2016-12-01

    Vibration exercise (VE) has been suggested to improve muscle strength and power performance, due to enhanced neuromuscular demand. However, understanding of the most appropriate VE protocols is lacking, limiting the optimal use of VE in rehabilitation programs. In this study, the fatiguing effect of vibration at different frequencies was investigated by employing a force-modulation VE system. Twenty volunteers performed 12-s isometric contractions of the biceps brachii with a load consisting of a baseline force of 80% of their maximum voluntary contraction (MVC) and a superimposed sinusoidal force at 0 (control condition with no vibration), 20, 30, and 40 Hz. Mechanical fatigue was estimated by assessment of MVC decay after each task while myoelectric fatigue was estimated by analysis of multichannel electromyography (EMG) signals recorded during VE. EMG conduction velocity, spectral compression, power, and fractal dimension were estimated as indicators of myoelectric fatigue. Our results suggest vibration, in particular at 30 Hz, to produce a larger degree of fatigue as compared to control condition. These results motivate further research aiming at introducing VE in rehabilitation programs with improved training protocols.

  11. Sum Frequency Generation Vibrational Spectroscopy of Adsorbed Amino Acids, Peptides and Proteins of Hydrophilic and Hydrophobic Solid-Water Interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Holinga IV, George Joseph [Univ. of California, Berkeley, CA (United States)

    2010-09-01

    Sum frequency generation (SFG) vibrational spectroscopy was used to investigate the interfacial properties of several amino acids, peptides, and proteins adsorbed at the hydrophilic polystyrene solid-liquid and the hydrophobic silica solid-liquid interfaces. The influence of experimental geometry on the sensitivity and resolution of the SFG vibrational spectroscopy technique was investigated both theoretically and experimentally. SFG was implemented to investigate the adsorption and organization of eight individual amino acids at model hydrophilic and hydrophobic surfaces under physiological conditions. Biointerface studies were conducted using a combination of SFG and quartz crystal microbalance (QCM) comparing the interfacial structure and concentration of two amino acids and their corresponding homopeptides at two model liquid-solid interfaces as a function of their concentration in aqueous solutions. The influence of temperature, concentration, equilibration time, and electrical bias on the extent of adsorption and interfacial structure of biomolecules were explored at the liquid-solid interface via QCM and SFG. QCM was utilized to quantify the biological activity of heparin functionalized surfaces. A novel optical parametric amplifier was developed and utilized in SFG experiments to investigate the secondary structure of an adsorbed model peptide at the solid-liquid interface.

  12. Vibration Modes at Terahertz and Infrared Frequencies of Ionic Liquids Consisting of an Imidazolium Cation and a Halogen Anion.

    Science.gov (United States)

    Yamada, Toshiki; Tominari, Yukihiro; Tanaka, Shukichi; Mizuno, Maya; Fukunaga, Kaori

    2014-11-17

    The terahertz and infrared frequency vibration modes of room-temperature ionic liquids with imidazolium cations and halogen anions were extensively investigated. There is an intermolecular vibrational mode between the imidazolium ring of an imidazolium cation, a halogen atomic anion with a large absorption coefficient and a broad bandwidth in the low THz frequency region (13-130 cm(-1)), the intramolecular vibrational modes of the alkyl-chain part of an imidazolium cation with a relatively small absorption coefficient in the mid THz frequency region (130-500 cm(-1)), the intramolecular skeletal vibrational modes of an imidazolium ring affected by the interaction between the imidazolium ring, and a halogen anion with a relatively large absorption coefficient in a high THz frequency region (500-670 cm(-1)). Interesting spectroscopic features on the interaction between imidazolium cations and halogen anions was also obtained from spectroscopic studies at IR frequencies (550-3300 cm(-1)). As far as the frequency of the intermolecular vibrational mode is concerned, we found the significance of the reduced mass in determining the intermolecular vibration frequency.

  13. Vibration Attenuation of Plate Using Multiple Vibration Absorbers

    Directory of Open Access Journals (Sweden)

    Zaman Izzuddin

    2014-07-01

    Full Text Available Vibrations are undesired phenomenon and it can cause harm, distress and unsettling influence to the systems or structures, for example, aircraft, automobile, machinery and building. One of the approach to limit this vibration by introducing passive vibration absorber attached to the structure. In this paper, the adequacy of utilizing passive vibration absorbers are investigated. The vibration absorber system is designed to minimize the vibration of a thin plate fixed along edges. The plate’s vibration characteristics, such as, natural frequency and mode shape are determined using three techniques: theoretical equations, finite element (FE analysis and experiment. The results demonstrate that the first four natural frequencies of fixed-fixed ends plate are 48, 121, 193 and 242 Hz, and these results are corroborated well with theoretical, FE simulation and experiment. The experiment work is further carried out with attached single and multiple vibration absorbers onto plate by tuning the absorber’s frequency to match with the excitation frequency. The outcomes depict that multiple vibration absorbers are more viable in lessening the global structural vibration.

  14. Composite 3D-printed metastructures for low-frequency and broadband vibration absorption

    Science.gov (United States)

    Matlack, Kathryn H.; Bauhofer, Anton; Krödel, Sebastian; Palermo, Antonio; Daraio, Chiara

    2016-07-01

    Architected materials that control elastic wave propagation are essential in vibration mitigation and sound attenuation. Phononic crystals and acoustic metamaterials use band-gap engineering to forbid certain frequencies from propagating through a material. However, existing solutions are limited in the low-frequency regimes and in their bandwidth of operation because they require impractical sizes and masses. Here, we present a class of materials (labeled elastic metastructures) that supports the formation of wide and low-frequency band gaps, while simultaneously reducing their global mass. To achieve these properties, the metastructures combine local resonances with structural modes of a periodic architected lattice. Whereas the band gaps in these metastructures are induced by Bragg scattering mechanisms, their key feature is that the band-gap size and frequency range can be controlled and broadened through local resonances, which are linked to changes in the lattice geometry. We demonstrate these principles experimentally, using advanced additive manufacturing methods, and inform our designs using finite-element simulations. This design strategy has a broad range of applications, including control of structural vibrations, noise, and shock mitigation.

  15. The influence of vibrations of polyatomic molecules on dipole moment and static dipole polarizability: theoretical study

    Science.gov (United States)

    Sharipov, Alexander S.; Loukhovitski, Boris I.; Starik, Alexander M.

    2017-08-01

    Dipole moment and static dipole polarizability surfaces for 50 polyatomic molecules, that are important for material science, combustion, and atmospheric chemistry, are explored in the vicinity of their equilibrium nuclear configurations by using density functional theory. The effective values of dipole moment and static polarizability of these molecules in individual vibrational states are determined using the calculated data on the electric properties and potential energy surfaces. Special attention is paid to the effect of the zero-point vibrations on the electric properties. The simple approximation scheme, allowing low-cost estimation of the zero-point vibrational corrections to polarizability, applicable for wide range of polyatomic compounds, are developed on the basis of the obtained data. The influence of the excitation of vibrational states on the dipole moment and dipole polarizability of polyatomic molecules are discussed with respect to the possible change of some important properties of molecular gases, such as refractive index, diffusion coefficients, and rates of chemical reactions.

  16. Time-domain filtered-x-Newton narrowband algorithms for active isolation of frequency-fluctuating vibration

    Science.gov (United States)

    Li, Yan; He, Lin; Shuai, Chang-geng; Wang, Fei

    2016-04-01

    A time-domain filtered-x Newton narrowband algorithm (the Fx-Newton algorithm) is proposed to address three major problems in active isolation of machinery vibration: multiple narrowband components, MIMO coupling, and amplitude and frequency fluctuations. In this algorithm, narrowband components are extracted by narrowband-pass filters (NBPF) and independently controlled by multi-controllers, and fast convergence of the control algorithm is achieved by inverse secondary-path filtering of the extracted sinusoidal reference signal and its orthogonal component using L×L numbers of 2nd-order filters in the time domain. Controller adapting and control signal generation are also implemented in the time domain, to ensure good real-time performance. The phase shift caused by narrowband filter is compensated online to improve the robustness of control system to frequency fluctuations. A double-reference Fx-Newton algorithm is also proposed to control double sinusoids in the same frequency band, under the precondition of acquiring two independent reference signals. Experiments are conducted with an MIMO single-deck vibration isolation system on which a 200 kW ship diesel generator is mounted, and the algorithms are tested under the vibration alternately excited by the diesel generator and inertial shakers. The results of control over sinusoidal vibration excited by inertial shakers suggest that the Fx-Newton algorithm with NBPF have much faster convergence rate and better attenuation effect than the Fx-LMS algorithm. For swept, frequency-jumping, double, double frequency-swept and double frequency-jumping sinusoidal vibration, and multiple high-level harmonics in broadband vibration excited by the diesel generator, the proposed algorithms also demonstrate large vibration suppression at fast convergence rate, and good robustness to vibration with frequency fluctuations.

  17. Theoretical Prediction of Vibrational Circular Dichroism of Hexoses in Linear Form

    Science.gov (United States)

    1992-06-01

    D. Zeroka, G. R. Famini , J. 0. Jensen, A. H. Carrieri, and C. F. Chabalowski, Theoreti- cal Prediction of Vibrational Circular Dichroism Spectra...Jensen, A. H. Carrieri, G. R. Famini , and C. F. Chabalowski, Theoreti- cal Prediction of Vibrational Circular Dichroism Spectra of Sugars, Summer 1990 U.S...1983), Chapter 3. 15. J. M. Leonard and G. R. Famini , A User’s Guide to the Molecular Modelling, Analysis, Display System (MMADS)", 2" ed., CRDEC-TR

  18. Energy Expenditure and Substrate Oxidation in Response to Side-Alternating Whole Body Vibration across Three Commonly-Used Vibration Frequencies.

    Directory of Open Access Journals (Sweden)

    Elie-Jacques Fares

    Full Text Available There is increasing recognition about the importance of enhancing energy expenditure (EE for weight control through increases in low-intensity physical activities comparable with daily life (1.5-4 METS. Whole-body vibration (WBV increases EE modestly and could present both a useful adjuvant for obesity management and tool for metabolic phenotyping. However, it is unclear whether a "dose-response" exists between commonly-used vibration frequencies (VF and EE, nor if WBV influences respiratory quotient (RQ, and hence substrate oxidation. We aimed to investigate the EE-VF and RQ-VF relationships across three different frequencies (30, 40, and 50Hz.EE and RQ were measured in 8 healthy young adults by indirect calorimetry at rest, and subsequently during side-alternating WBV at one of 3 VFs (30, 40, and 50 Hz. Each frequency was assessed over 5 cycles of intermittent WBV (30s vibration/30s rest, separated by 5 min seated rest. During the WBV participants stood on the platform with knees flexed sufficiently to maintain comfort, prevent transmission of vibration to the upper body, and minimise voluntary physical exertion. Repeatability was assessed across 3 separate days in a subset of 4 individuals. In order to assess any sequence/habituation effect, an additional group of 6 men underwent 5 cycles of intermittent WBV (30s vibration/30s rest at 40 Hz, separated by 5 min seated rest.Side-alternating WBV increased EE relative to standing, non-vibration levels (+36%, p<0.001. However, no differences in EE were observed across VFs. Similarly, no effect of VF on RQ was found, nor did WBV alter RQ relative to standing without vibration.No relationship could be demonstrated between EE and VF in the range of 30-50Hz, and substrate oxidation did not change in response to WBV. Furthermore, the thermogenic effect of intermittent WBV, whilst robust, was quantitatively small (<2 METS.

  19. Acid-hemolytic stability of erythrocytes of intense erythropoiesis under conditions of low-frequency vibration

    Directory of Open Access Journals (Sweden)

    O. I. Dotsenko

    2014-04-01

    Full Text Available This paper deals with the peculiarities of functioning of murine erythron system under vibrational stress on the basis of experimental data about erythrocytes acid resistance. Experiments were made on the outbred male mice at about one age and weight that were maintained in vivarium conditions on usual diet. Animals were divided into 5 groups. Animals of 1–4 groups were exposed to daily thirty-minute vibration at frequencies of 8, 16, 24 and 32 Hz respectively, with amplitude of 0.8 ±0.12 mmduring 14 days. Animal exposure to vibration was provided by the electromechanical converter connected to the generator of low frequency signals. The fifth group of animals was not exposed to vibration and it was used as a control. Kinetic dependences of acid hemolysis of erythrocytes was registered daily, from the 1st to the 5th day, and further at the 7th, 9th and 14th days of experiment. Blood for analysis was taken from tail veins in 15–20 min after stopping of vibration. As the basic indicators characterizing resistance of erythrocytes to the hemolytic agent influence we used the hemolysis rate constant, i.e. the value inverse to cell half-life time. For analysis of acid erythrograms we also used such indicators as hemolysis duration, maximum erythrogram’s time and width of the interval of erythrocyte group dominating in the population. We processed the results of research statistically. The study showed that acid resistance of erythrocytes decreased during the first five days of vibration influence at frequencies of 8–16 Hz. Besides, erythrocytes were divided into fractions that indicated the erythrocytes aging and strengthening of the population heterogeneity. On the fifth day of 16 Hz influence the emission of reticulocytes was recorded. At 8 Hz influence these processes were registered on the 7th day of the experiment. During the subsequent days the hemolysis curves were slightly displaced in relation to the control. Increase in hemolysis

  20. Theoretical estimation of the vibrational temperatures of N2 molecules in the ionosphere and in the laboratory simulated plasma

    Science.gov (United States)

    Kalpuri, K. S.; Oyama, K.-I.

    1991-06-01

    The vibrational temperature of excited nitrogen molecules (N2) are estimated theoretically for the case of ionosphere as well as for the lab simulated plasma, considering the various chemical reactions leading to the production and loss of N2 molecules. It was found that even in the case when quenching of the excited molecules by O and CO2 is considered, the vibrational temperature, T sub v, is higher than the neutral temperature, T sub n, below about 105 km but the difference decreases and about 120 km, the value of T sub v is less than T sub n. However, for no quenching case, the vibrational temperature can be as high as 1600 K at 150 km. The vibrational temperature for the lab simulated plasma on the other hand was found to be high (1500 K or more), the absolute value being dependent upon the concentration of O2 in the gas mixture taken and the intensity of UV light used for excitation of nitrogen molecules.

  1. Analytical Expressions for Frequency and Buckling of Large Amplitude Vibration of Multilayered Composite Beams

    Directory of Open Access Journals (Sweden)

    R. A. Jafari-Talookolaei

    2011-01-01

    Full Text Available The aim of this paper is to present analytical and exact expressions for the frequency and buckling of large amplitude vibration of the symmetrical laminated composite beam (LCB with simple and clamped end conditions. The equations of motion are derived by using Hamilton's principle. The influences of axial force, Poisson effect, shear deformation, and rotary inertia are taken into account in the formulation. First, the geometric nonlinearity based on the von Karman's assumptions is incorporated in the formulation while retaining the linear behavior for the material. Then, the displacement fields used for the analysis are coupled using the equilibrium equations of the composite beam. Substituting this coupled displacement fields in the potential and kinetic energies and using harmonic balance method, we obtain the ordinary differential equation in time domain. Finally, applying first order of homotopy analysis method (HAM, we get the closed form solutions for the natural frequency and deflection of the LCB. A detailed numerical study is carried out to highlight the influences of amplitude of vibration, shear deformation and rotary inertia, slenderness ratios, and layup in the case of laminates on the natural frequency and buckling load.

  2. Vapor-phase Raman spectra, theoretical calculations, and the vibrational and structural properties of cis- and trans-stilbene.

    Science.gov (United States)

    Egawa, Toru; Shinashi, Kiyoaki; Ueda, Toyotoshi; Ocola, Esther J; Chiang, Whe-Yi; Laane, Jaan

    2014-02-13

    The vapor-phase Raman spectra of cis- and trans-stilbene have been collected at high temperatures and assigned. The low-frequency skeletal modes were of special interest. The molecular structures and vibrational frequencies of both molecules have also been obtained using MP2/cc-pVTZ and B3LYP/cc-pVTZ calculations, respectively. The two-dimensional potential map for the internal rotations around the two Cphenyl-C(═C) bonds of cis-stilbene was generated by using a series of B3LYP/cc-pVTZ calculations. It was confirmed that the molecule has only one conformer with C2 symmetry. The energy level calculation with a two-dimensional Hamiltonian was carried out, and the probability distribution for each level was obtained. The calculation revealed that the "gearing" internal rotation in which the two phenyl rings rotate with opposite directions has a vibrational frequency of 26 cm(-1), whereas that of the "antigearing" internal rotation in which the phenyl rings rotate with the same direction is about 52 cm(-1). In the low vibrational energy region the probability distribution for the gearing internal rotation is similar to that of a one-dimensional harmonic oscillator, and in the higher region the motion behaves like that of a free rotor.

  3. Vibrational frequencies of anti-diabetic drug studied by terahertz time-domain spectroscopy

    Science.gov (United States)

    Du, S. Q.; Li, H.; Xie, L.; Chen, L.; Peng, Y.; Zhu, Y. M.; Li, H.; Dong, P.; Wang, J. T.

    2012-04-01

    By using terahertz time-domain spectroscopy, the absorption spectra of seven anti-diabetic pills have been investigated. For gliquidone, glipizide, gliclazide, and glimepiride, an obvious resonance peak is found at 1.37 THz. Furthermore, to overcome the limit of density functional theory that can analyze the normal mode frequencies of the ground state of organic material, we also present a method that relies on pharmacophore recognition, from which we can obtain the resonance peak at 1.37 THz can be attributed to the vibration of sulfonylurea group. The results indicate that the veracity of density functional theory can be increased by combining pharmacophore recognition.

  4. A piezoelectric pulse generator for low frequency non-harmonic vibration

    Science.gov (United States)

    Jiang, Hao; Yeatman, Eric M.

    2013-12-01

    This paper reports a new piezoelectric prototype for pulse generation by energy harvesting from low frequency non-harmonic vibration. The pulse generator presented here consists of two parts: the electromechanical part and the load circuit. A metal rolling rod is used as the proof mass, moving along the substrate to achieve both actuating of the piezoelectric cantilever by magnetic coupling and self-synchronous switching of the circuit. By using this new approach, the energy from the piezoelectric transduction mechanism is regulated simultaneously when it is extracted. This allows a series of tuneable pulses to be generated, which can be applied to self-powered RF wireless sensor network (WSN) nodes.

  5. Non-Seismology Seismology: Using QuakeCatchers to Analyze the Frequency of Bridge Vibrations

    Science.gov (United States)

    Courtier, A. M.; Constantin, C.; Wilson, C. F.

    2013-12-01

    We conducted an experiment to test the feasibility of measuring seismic waves generated by traffic near James Madison University. We used QuakeCatcher seismometers (originally designed for passive seismic measurement) to measure vibrations associated with traffic on a wooden bridge as well as a nearby concrete bridge. This experiment was a signal processing exercise for a student research project and did not draw any conclusions regarding bridge safety or security. The experiment consisted of two temporary measurement stations comprised of a laptop computer and a QuakeCatcher - a small seismometer that plugs directly into the laptop via a USB cable. The QuakeCatcher was taped to the ground at the edge of the bridge to achieve good coupling, and vibrational events were triggered repeatedly with a control vehicle to accumulate a consistent dataset of the bridge response. For the wooden bridge, the resulting 'seismograms' were converted to Seismic Analysis Code (SAC) format and analyzed in MATLAB. The concrete bridge did not generate vibrations significant enough to trigger the recording mechanism on the QuakeCatchers. We will present an overview of the experimental design and frequency content of the traffic patterns, as well as a discussion of the instructional benefits of using the QuakeCatcher sensors in this non-traditional setting.

  6. An approach to compatible multiple nonlinear vibrational spectroscopy measurements using a commercial sum frequency generation system.

    Science.gov (United States)

    Ye, Shuji; Wei, Feng

    2011-06-21

    In this paper, we designed a compatible multiple nonlinear vibrational spectroscopy system that can be used for recording infrared-visible sum frequency generation vibrational spectra (SFG) and infrared-infrared-visible three-pump-field four-wave-mixing (IIV-TPF-FWM) spectra using a commercial EKSPLA SFG system. This is the first time IIV-TPF-FWM signals were obtained using picosecond laser pulses. We have applied this compatible system to study the surface and vibrational structures of riboflavin molecules (also known as vitamin B2). The SFG spectra of eight polarization combinations have non-vanishing signals. The signals with incoming s-polarized IR are relatively weaker than the signals with incoming p-polarized IR. Under the double resonant conditions, the SFG signals of the conjugated tricyclic ring are greatly enhanced. For the IIV-TPF-FWM spectra with incoming p-polarized IR, only the sspp and pppp polarization combinations have non-vanishing signals. The IIV-TPF-FWM spectra show a very strong peak at 1585 cm(-1) that is mainly dominated by the N(5)-C(4a) stretch. The method developed in this study will be helpful for researchers, either using a home-built or commercial (EKSPLA) SFG system, to obtain independent and complementary measurements for SFG spectroscopy and more detailed structural information of interfacial molecules.

  7. Low resonance frequency vibration affects strength of paretic and non-paretic leg differently in patients with stroke.

    Science.gov (United States)

    Tihanyi, J; Di Giminiani, R; Tihanyi, T; Gyulai, G; Trzaskoma, L; Horváth, M

    2010-06-01

    The objective of the study was to investigate the chronic effect of low frequency whole body vibration (WBV) on isometric and eccentric strength of knee extensors with different force exertion capacity. It was hypothesized that (1) four-week WBV intervention with the low frequency domain would enhance muscle strength and (2) the improvement would be more pronounced in the weaker muscle. To test our hypothesis twenty patients with acute stroke were recruited. Ten patients were randomly assigned to vibration and the remaining ten patients served for control.The patients in the vibration group received WBV with 20 Hz frequency three times per week standing on a vibration platform in half squat position meanwhile flexing and extending the joints and placing the weight from one leg to the other. Knee extensor strength was determined under isometric and eccentric contraction before and after WBV intervention. Myoelectrical activity (EMG) of the vastus lateralis muscle was also measured.Significant improvement was revealed in the vibration group only. The maximum isometric torque and EMG activity increased significantly for both paretic and non-paretic leg, but the improvement was threefold greater in the vibration group. No significant alteration was found in rate of torque development. Maximum eccentric torque and EMG increased significantly for the paretic leg only. Mechanical work enhanced significantly in the paretic side only.The results of our study indicate that the selection of the effective vibration frequency depends upon the physical condition of neuromuscular system. Low vibration frequency intervention can increase the strength in weak muscles due to neuromuscular impairment and restricted physical activity.

  8. Comparative Study of Time-Frequency Decomposition Techniques for Fault Detection in Induction Motors Using Vibration Analysis during Startup Transient

    Directory of Open Access Journals (Sweden)

    Paulo Antonio Delgado-Arredondo

    2015-01-01

    Full Text Available Induction motors are critical components for most industries and the condition monitoring has become necessary to detect faults. There are several techniques for fault diagnosis of induction motors and analyzing the startup transient vibration signals is not as widely used as other techniques like motor current signature analysis. Vibration analysis gives a fault diagnosis focused on the location of spectral components associated with faults. Therefore, this paper presents a comparative study of different time-frequency analysis methodologies that can be used for detecting faults in induction motors analyzing vibration signals during the startup transient. The studied methodologies are the time-frequency distribution of Gabor (TFDG, the time-frequency Morlet scalogram (TFMS, multiple signal classification (MUSIC, and fast Fourier transform (FFT. The analyzed vibration signals are one broken rotor bar, two broken bars, unbalance, and bearing defects. The obtained results have shown the feasibility of detecting faults in induction motors using the time-frequency spectral analysis applied to vibration signals, and the proposed methodology is applicable when it does not have current signals and only has vibration signals. Also, the methodology has applications in motors that are not fed directly to the supply line, in such cases the analysis of current signals is not recommended due to poor current signal quality.

  9. Theoretical studies on the molecular structure, conformational preferences, topological and vibrational analysis of allicin

    Science.gov (United States)

    Durlak, Piotr; Berski, Sławomir; Latajka, Zdzisław

    2016-01-01

    The molecular structure, conformational preferences, topological and vibrational analysis of allicin has been investigated at two different approaches. Calculations have been carried out on static (DFT and MP2) levels with an assortment of Dunning's basis sets and dynamic CPMD simulations. In this both case within the isolated molecule approximation. The results point out that at least twenty different conformers coexist on the PES as confirmed by the flexible character of this molecule. The topological analysis of ELF showed very similar nature of the Ssbnd S and Ssbnd O bonds. The infrared spectrum has been calculated, and a comparative vibrational analysis has been performed.

  10. Energy Expenditure and Substrate Oxidation in Response to Side-Alternating Whole Body Vibration across Three Commonly-Used Vibration Frequencies.

    Science.gov (United States)

    Fares, Elie-Jacques; Charrière, Nathalie; Montani, Jean-Pierre; Schutz, Yves; Dulloo, Abdul G; Miles-Chan, Jennifer L

    2016-01-01

    There is increasing recognition about the importance of enhancing energy expenditure (EE) for weight control through increases in low-intensity physical activities comparable with daily life (1.5-4 METS). Whole-body vibration (WBV) increases EE modestly and could present both a useful adjuvant for obesity management and tool for metabolic phenotyping. However, it is unclear whether a "dose-response" exists between commonly-used vibration frequencies (VF) and EE, nor if WBV influences respiratory quotient (RQ), and hence substrate oxidation. We aimed to investigate the EE-VF and RQ-VF relationships across three different frequencies (30, 40, and 50Hz). EE and RQ were measured in 8 healthy young adults by indirect calorimetry at rest, and subsequently during side-alternating WBV at one of 3 VFs (30, 40, and 50 Hz). Each frequency was assessed over 5 cycles of intermittent WBV (30s vibration/30s rest), separated by 5 min seated rest. During the WBV participants stood on the platform with knees flexed sufficiently to maintain comfort, prevent transmission of vibration to the upper body, and minimise voluntary physical exertion. Repeatability was assessed across 3 separate days in a subset of 4 individuals. In order to assess any sequence/habituation effect, an additional group of 6 men underwent 5 cycles of intermittent WBV (30s vibration/30s rest) at 40 Hz, separated by 5 min seated rest. Side-alternating WBV increased EE relative to standing, non-vibration levels (+36%, pvibration. No relationship could be demonstrated between EE and VF in the range of 30-50Hz, and substrate oxidation did not change in response to WBV. Furthermore, the thermogenic effect of intermittent WBV, whilst robust, was quantitatively small (<2 METS).

  11. Fast vibrational calculation of anharmonic OH-stretch frequencies for two low-energy noradrenaline conformers

    Science.gov (United States)

    Benoit, David M.

    2008-12-01

    We introduce a new reduced-coupling technique to accelerate direct calculations of a selected number of vibrational frequencies in large molecular systems. Our method combines the advantages of the single-to-all correlation-corrected vibrational self-consistent field (STA-CC-VSCF) approach [D. M. Benoit, J. Chem. Phys. 125, 244110 (2006)] with those of the fast-CC-VSCF technique [D. M. Benoit, J. Chem. Phys. 120, 562 (2004)] and allows the ab initio calculation of only the relevant parts of the required potential energy surface (PES). We demonstrate, using a set of five aliphatic alcohol molecules, that the new fast-STA-CC-VSCF method is accurate and leads to very substantial time gains for the computations of the PES. We then use the fast-STA-CC-VSCF method to accelerate the computation of the OH-stretch and NH-stretch frequencies of the two lowest-energy conformers of noradrenaline, namely, AG1a and GG1a. Our new approach enables us to run the calculation 89 times faster than the standard CC-VSCF technique and makes it possible to use a high-level MP2/TZP description of the PES. We demonstrate that the influence of the strong mode-mode couplings is crucial for a realistic description of the particular OH-stretch vibrational signature of each conformer. Finally, of the two possible low-energy conformers, we identify AG1a as the one most likely to have been observed in the experiments of Snoek et al. [Mol. Phys. 101, 1239 (2003)].

  12. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Energy Technology Data Exchange (ETDEWEB)

    Li, Pengwei, E-mail: lipengwei@tyut.edu.cn; Wang, Yanfen; Luo, Cuixian; Li, Gang; Hu, Jie; Zhang, Wendong [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Liu, Ying [MicroNano System Research Center of College of Information Engineering and Key Lab of Advanced Transducers and Intelligent Control System of the Ministry of Education, Taiyuan University of Technology, Taiyuan 030024, Shanxi (China); Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China); Liu, Wei [Baicheng Ordnance Test Center of China, Baicheng 137000, Jilin (China)

    2015-04-15

    As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams) show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  13. Low-frequency and wideband vibration energy harvester with flexible frame and interdigital structure

    Directory of Open Access Journals (Sweden)

    Pengwei Li

    2015-04-01

    Full Text Available As an alternative to traditional cantilever beam structures and their evolutions, a flexible beam based, interdigital structure, vibration energy harvester has been presented and investigated. The proposed interdigital-shaped oscillator consists of a rectangular flexible frame and series of cantilever beams interdigitally bonded to it. In order to achieve low frequency and wide-bandwidth harvesting, Young’s modulus of materials, frame size and the amount of the cantilevers have been studied systematically. The measured frequency responses of the designed device (PDMS frame, quintuple piezoelectric cantilever beams show a 460% increase in bandwidth below 80Hz. When excited at an acceleration of 1.0 g, the energy harvester achieves to a maximum open-circuit voltage of 65V, and the maximum output power 4.5 mW.

  14. Natural frequency and vibration analysis of jacket type foundation for offshore wind power

    Science.gov (United States)

    Hung, Y.-C.; Chang, Y.-Y.; Chen, S.-Y.

    2017-12-01

    There are various types of foundation structure for offshore wind power, engineers may assess the condition of ocean at wind farm, and arrange the transportation, installation of each structure members, furthermore, considering the ability of manufacture steel structure as well, then make an optimum design. To design jacket offshore structure, unlike onshore cases, offshore structure also need to estimate the wave excitation effect. The aim of this paper is to study the difference of natural frequency between different kinds of structural stiffness and discuss the effect of different setting of boundary condition during analysis, besides, compare this value with the natural frequency of sea wave, in order to avoid the resonance effect. In this paper, the finite element analysis software ABAQUS is used to model and analyze the natural vibration behavior of the jacket structure.

  15. Matrix effect on vibrational frequencies: Experiments and simulations for HCl and HNgCl (Ng = Kr and Xe)

    Energy Technology Data Exchange (ETDEWEB)

    Kalinowski, Jaroslaw; Räsänen, Markku; Lignell, Antti; Khriachtchev, Leonid, E-mail: leonid.khriachtchev@helsinki.fi [Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014 (Finland); Gerber, R. Benny [Department of Chemistry, University of Helsinki, P.O. Box 55, FI-00014 (Finland); Department of Physical Chemistry, Hebrew University, Jerusalem 91904, Israel and Department of Chemistry, University of California, Irvine, California 92697 (United States)

    2014-03-07

    We study the environmental effect on molecules embedded in noble-gas (Ng) matrices. The experimental data on HXeCl and HKrCl in Ng matrices is enriched. As a result, the H−Xe stretching bands of HXeCl are now known in four Ng matrices (Ne, Ar, Kr, and Xe), and HKrCl is now known in Ar and Kr matrices. The order of the H−Xe stretching frequencies of HXeCl in different matrices is ν(Ne) < ν(Xe) < ν(Kr) < ν(Ar), which is a non-monotonous function of the dielectric constant, in contrast to the “classical” order observed for HCl: ν(Xe) < ν(Kr) < ν(Ar) < ν(Ne). The order of the H−Kr stretching frequencies of HKrCl is consistently ν(Kr) < ν(Ar). These matrix effects are analyzed theoretically by using a number of quantum chemical methods. The calculations on these molecules (HCl, HXeCl, and HKrCl) embedded in single Ng{sup ′} layer cages lead to very satisfactory results with respect to the relative matrix shifts in the case of the MP4(SDQ) method whereas the B3LYP-D and MP2 methods fail to fully reproduce these experimental results. The obtained order of frequencies is discussed in terms of the size available for the Ng hydrides in the cages, probably leading to different stresses on the embedded molecule. Taking into account vibrational anharmonicity produces a good agreement of the MP4(SDQ) frequencies of HCl and HXeCl with the experimental values in different matrices. This work also highlights a number of open questions in the field.

  16. A first principles theoretical study of vibrational spectral diffusion and hydrogen bond dynamics in aqueous ionic solutions: D2O in hydration shells of Cl(-) ions.

    Science.gov (United States)

    Mallik, Bhabani S; Semparithi, A; Chandra, Amalendu

    2008-11-21

    A theoretical study of vibrational spectral diffusion and hydrogen bond dynamics in aqueous ionic solutions is presented from first principles without employing any empirical potential models. The present calculations are based on ab initio molecular dynamics for trajectory generation and wavelet analysis of the simulated trajectories for time dependent frequency calculations. Results are obtained for two different deuterated aqueous solutions: the first one is a relatively dilute solution of a single Cl(-) ion and the second one is a concentrated solution of NaCl ( approximately 3M) dissolved in liquid D(2)O. It is found that the frequencies of OD bonds in the anion hydration shell, i.e., those which are hydrogen bonded to the chloride ion, have a higher stretch frequency than those in the bulk water. Also, on average, the frequencies of hydration shell OD modes are found to increase with increase in the anion-water hydrogen bond distance. On the dynamical side, when the vibrational spectral diffusion is calculated exclusively for the hydration shell water molecules in the first solution, the dynamics reveals three time scales: a short-time relaxation ( approximately 200 fs) corresponding to the dynamics of intact ion-water hydrogen bonds, a slower relaxation ( approximately 3 ps) corresponding to the lifetimes of chloride ion-water hydrogen bonds, and another longer-time constant ( approximately 20 ps) corresponding to the escape dynamics of water from the anion hydration shell. Existence of such three time scales for hydration shell water molecules was also reported earlier for water containing a single iodide ion using classical molecular dynamics [B. Nigro et al., J. Phys. Chem. A 110, 11237 (2006)]. Hence, the present study confirms the basic results of this earlier work using a different methodology. However, when the vibrational spectral diffusion is calculated over all the OD modes, only two time scales of approximately 150 fs and approximately 2.7 ps are

  17. Delays of stimulus-frequency otoacoustic emissions and cochlear vibrations contradict the theory of coherent reflection filtering

    NARCIS (Netherlands)

    Siegel, JH; Cerka, AJ; Recio-Spinoso, A; Temchin, AN; van Dijk, P; Ruggero, MA

    2005-01-01

    When stimulated by tones, the ear appears to emit tones of its own, stimulus-frequency otoacoustic emissions (SFOAEs). SFOAEs were measured in 17 chinchillas and their group delays were compared with a place map of basilar-membrane vibration group delays measured at the characteristic frequency. The

  18. A Large Span Crossbeam Vibration Frequencies Analysis Based on an Analogous Beam Method

    Directory of Open Access Journals (Sweden)

    Zhifeng Liu

    2013-01-01

    Full Text Available The novel method of an analogous beam is studied, which the flexural rigidity and mass per unit length correspond was described as the reciprocal of the mass per unit and the reciprocal of the flexural rigidity of the beam. It is shown that both beams possess the same natural frequencies of flexural vibration. In order to approximate calculation of these frequencies, the continuously distributed mass of the original beam is substituted for a number of concentrated masses. The analogous beam then becomes a chain of rigid links connected by pins and equipped with springs restraining the relative rotation of adjacent links. The equations of motion for the analogous beam can be solved by a procedure which consists of assuming a value for the natural frequency and calculating the deflections successively from one end of the beam to the other. Under normal circumstances, there will be a certain error, and one boundary condition will not be satisfied. The procedure is repeated with different values of the frequency until the error is removed. The method is illustrated by an example of a Crossbeam for which the fundamental frequency is found.

  19. Effect of higher frequency components and duration of vibration on bone tissue alterations in the rat-tail model

    Science.gov (United States)

    PEELUKHANA, Srikara V.; GOENKA, Shilpi; KIM, Brian; KIM, Jay; BHATTACHARYA, Amit; STRINGER, Keith F.; BANERJEE, Rupak K.

    2015-01-01

    To formulate more accurate guidelines for musculoskeletal disorders (MSD) linked to Hand-Arm Vibration Syndrome (HAVS), delineation of the response of bone tissue under different frequencies and duration of vibration needs elucidation. Rat-tails were vibrated at 125 Hz (9 rats) and 250 Hz (9 rats), at 49 m/s2, for 1D (6 rats), 5D (6 rats) and 20D (6 rats); D=days (4 h/d). Rats in the control group (6 rats for the vibration groups; 2 each for 1D, 5D, and 20D) were left in their cages, without being subjected to any vibration. Structural and biochemical damages were quantified using empty lacunae count and nitrotyrosine signal-intensity, respectively. One-way repeated-measure mixed-model ANOVA at p<0.05 level of significance was used for analysis. In the cortical bone, structural damage quantified through empty lacunae count was significant (p<0.05) at 250 Hz (10.82 ± 0.66) in comparison to the control group (7.41 ± 0.76). The biochemical damage was significant (p<0.05) at both the 125 Hz and 250 Hz vibration frequencies. The structural damage was significant (p<0.05) at 5D for cortical bone while the trabecular bone showed significant (p<0.05) damage at 20D time point. Further, the biochemical damage increased with increase in the duration of vibration with a significant (p<0.05) damage observed at 20D time point and a near significant change (p=0.08) observed at 5D time point. Structural and biochemical changes in bone tissue are dependent upon higher vibration frequencies of 125 Hz, 250 Hz and the duration of vibration (5D, 20D). PMID:25843564

  20. Theoretical approaches to study the vibrational predissociation of van der Waals molecules

    OpenAIRE

    Delgado Barrio, Gerardo; Serna, S.; Miret-Artés, Salvador; Roncero, Octavio; Campos-Martínez, José; Villarreal, Pablo

    1992-01-01

    Different approaches are presented for the study of vibrational predissociation of triatomic van der Waals molecules. These methods are applied to the study of the He-I2 when I2 is excited to the B electronic state. The applicability of these methods is discussed in detail by comparing with 'exact' quantum results.

  1. Time-frequency analysis of DC bias vibration of transformer core on the basis of Hilbert–Huang transform

    Directory of Open Access Journals (Sweden)

    Xingmou Liu

    2016-01-01

    Full Text Available This paper presents a time–frequency analysis of the vibration of transformer under direct current (DC bias through Hilbert–Huang transform (HHT. First, the theory of DC bias for the transformer was analyzed. Next, the empirical mode decomposition (EMD process, which is the key in HHT, was introduced. The results of EMD, namely, intrinsic mode functions (IMFs, were calculated and summed by Hilbert transform(HT to obtain time-dependent series in a 2D time–frequency domain. Lastly, a test system of vibration measurement for the transformer was set up. Three direction (x, y, and z axes components of core vibration were measured. Decomposition of EMD and HHT spectra showed that vibration strength increased, and odd harmonics were produced with DC bias. Results indicated that HHT is a viable signal processing tool for transformer health monitoring.

  2. Theoretical and experimental study of the light deflection by a frequency modulated ultrasonic wave

    Science.gov (United States)

    Guessoum, A.; Laouar, N.; Ferria, K.

    2017-12-01

    A formula that describes angular excursion variation of an acousto-optical deflector is theoretically demonstrated and experimentally confirmed. This deflector is obtained using a laser beam interaction with a frequency modulated ultrasonic sinusoidal wave in a liquid medium. The obtained results show that each diffracted order position varies sinusoidally around its central position, in the same rhythm as the modulating signal. Moreover, the scanning frequency of the diffraction order increases linearly according to the modulating signal frequency. Furthermore, the increase in the frequency excursion leads to the increase of the angular excursion. All the theoretical results are confirmed experimentally. Finally, the frequency modulation index has been easily obtained with good precision using experimental measurements of the diffracted order angular excursion.

  3. CONTRIBUTIONS TO THE STUDY OF THE VIBRATIONS FREQUENCY OF THE DRILL TOOL IN THE PROCESS OF MANUFACTURING THE BRONZE MATERIALS

    Directory of Open Access Journals (Sweden)

    Cosmin-Mihai MIRIŢOIU

    2013-05-01

    Full Text Available In this paper we present the experimental testings used to study the vibration of the drill tool, during the drilling of the bronze products. We have used the experimental setup presented in Miriţoiu (2013[1]. In this paper the vibrations are analyzed during the drilling on the universal lathe machines. The main purpose of to find a correlation between the cutting speed and the frequency of the vibration by using the experimental results and the regression analysis

  4. Collective excitations in liquid DMSO : FIR spectrum, Low frequency vibrational density of states and ultrafast dipolar solvation dynamics

    OpenAIRE

    Hazra, Milan; Bagchi, Biman

    2016-01-01

    Valuable dynamical and structural information about neat liquid DMSO at ambient conditions can be obtained through study of low frequency vibrations in the far infrared (FIR), that is, terahertz regime. For DMSO, collective excitations as well as single molecule stretches and bends have been measured by different kinds of experiments such as OHD-RIKES and terahertz spectroscopy. In the present work we investigate the intermolecular vibrational spectrum of DMSO through three different computat...

  5. Recording of unexpectedly high frequency vibrations of blood vessel walls in experimental arteriovenous fistulae of rabbits using a laser vibrometer.

    Science.gov (United States)

    Stehbens, W E; Liepsch, D W; Poll, A; Erhardt, W

    1995-01-01

    Because arteriovenous fistulae are associated with a palpable thrill and an audible murmur, the vibrational activity of the blood vessel walls about experimental arteriovenous fistulae in rabbits was investigated using, for the first time, a high-resolution laser vibrometer. Frequencies of mural vibrations up to 2200 Hz were recorded at different sites about the fistulae. The relationship of this vibratory activity of blood vessel walls to physiological and pathological conditions warrants further investigation.

  6. Theoretical study on cation-anion interaction and vibrational spectra of 1-allyl-3-methylimidazolium-based ionic liquids.

    Science.gov (United States)

    Xuan, Xiaopeng; Guo, Meng; Pei, Yuanchao; Zheng, Yong

    2011-05-01

    In order to deepen the understanding of the cation-anion interaction in ionic liquids, the structures of cation, anions, and cation-anion ion-pairs of 1-allyl-3-methylimidazolium-based ionic liquids are optimized using density functional theory (DFT), and their most stable geometries are discussed. The structural parameters, hydrogen bonds and interaction energies of 1-allyl-3-methylimidazolium dicyanamide ([Amim]DCA), 1-allyl-3-methylimidazolium chloride ([Amim]Cl), 1-allyl-3-methylimidazolium formate ([Amim]FmO) and 1-allyl-3-methylimidazolium acetate ([Amim]AcO) ion pairs are studied. The vibrational frequencies of [Amim]DCA and [Amim]Cl have been calculated and scaled values have been compared with experimental FT-IR and FT-Raman spectra. The complete assignments were performed on the basis of the potential energy distribution (PED) of the vibrational modes. Copyright © 2011 Elsevier B.V. All rights reserved.

  7. A novel scheme for the discrete prediction of high-frequency vibration response: Discrete singular convolution-mode superposition approach

    Science.gov (United States)

    Seçgin, Abdullah; Saide Sarıgül, A.

    2009-03-01

    This study introduces a novel scheme for the discrete high-frequency forced vibration analysis based on discrete singular convolution (DSC) and mode superposition (MS) approaches. The accuracy of the DSC-MS is validated for thin beams and plates by comparing with available analytical solutions. The performance of the DSC-MS is evaluated by predicting spatial distribution and discrete frequency spectra of the vibration response of thin plates with two different boundary conditions. The frequency spectra of the time-harmonic excitation forces are in the form of ideal and band-limited white noise so that the natural modes in the frequency band are provoked. The solution exposes high-frequency response behaviour definitely. Therefore, it is hoped with this paper to contribute the studies on the treatment of uncertainties in the high-frequency design applications.

  8. Experimental and theoretical model of reactivity and vibrational detection modes of triacetone triperoxide (TATP) and homologues

    Science.gov (United States)

    Pacheco-Londono, Leonardo C.; Primera-Pedrozo, Oliva M.; Hernandez-Rivera, Samuel P.

    2004-12-01

    Fully optimized molecular geometry, parameters of reactivity and vibrational spectra of triacetone triperoxide (TATP) and homologue organic peroxides were calculated using B3LYP/6-31G(d,p) method within the Density Functional Theory formalism. Infrared and Raman Spectroscopy were utilized to obtain vibrational spectra of the energetic compound. The model consists in the relation found between the Raman Shift location of the important symmetric stretch ν(O-O) of the organic peroxides and the reactivity of the organic peroxides. A good correlation between the band location in the series studied and the x-y plane polarizability component and the ionization energy was found. Gas phase IR absorption of TATP in air was used for developing stand-off detection schemes of the important organic peroxide in air. The sublimation properties of TATP were measured using two methods: Grazing Angle Probe-Fiber Coupled FTIR and gravimetric on stainless steel surfaces. Sublimation rates, loading concentration values and absorbance band areas were measured and modeled using the persistent IR vibrational signature of the ν(C-O) mode.

  9. Structural, vibrational and theoretical studies of anilinium trichloroacetate: new hydrogen bonded molecular crystal with nonlinear optical properties.

    Science.gov (United States)

    Tanak, H; Pawlus, K; Marchewka, M K; Pietraszko, A

    2014-01-24

    In this work, we report a combined experimental and theoretical study on molecular structure, vibrational spectra and NBO analysis of the potential nonlinear optical (NLO) material anilinium trichloroacetate. The FT-IR and FT-Raman spectra of the compound have been recorded together between 4000-80 cm(-1) and 3600-80 cm(-1) regions, respectively. The compound crystallizes in the noncentrosymmetric space group of monoclinic system. The optimized molecular structure, vibrational wavenumbers, IR intensities and Raman activities have been calculated by using density functional method (B3LYP) with 6-311++G(d,p) as higher basis set. The obtained vibrational wavenumbers and optimized geometric parameters were seen to be in good agreement with the experimental data. DSC measurements on powder samples do not indicate clearly on the occurrence of phase transitions in the temperature 113-293 K. The Kurtz and Perry powder reflection technique appeared to be very effective in studies of second-order nonlinear optical properties of the molecule. The non-linear optical properties are also addressed theoretically. The predicted NLO properties of the title compound are much greater than ones of urea. In addition, DFT calculations of the title compound, molecular electrostatic potential, frontier orbitals and thermodynamic properties were also performed at 6-311++G(d,p) level of theory. For title crystal the SHG efficiency was estimated by Kurtz-Perry method to be d(eff)=0.70 d(eff) (KDP). Copyright © 2013 Elsevier B.V. All rights reserved.

  10. Anharmonic vibrational and electronic spectral study of 2-amino-4-hydroxy-6-methylpyrimidine: A combined experimental (FTIR, FT-Raman, UV-Vis) and theoretical (DFT, MP2) approach

    Science.gov (United States)

    Faizan, Mohd; Bhat, Sheeraz Ahmad; Alam, Mohammad Jane; Afroz, Ziya; Ahmad, Shabbir

    2017-11-01

    A combined experimental and theoretical study of the structure, vibrational spectra and electronic spectra of 2-amino-4-hydroxy-6-methylpyrimidine in the ground electronic state are reported. Anharmonic frequencies for the most stable conformer have been simulated using GVPT2, VSCF and PT2-VSCF methods with potential energy surface calculated using MP2 and DFT level of theory with 6-311G(d,p) basis set. The vibrational spectra (FTIR and FT-Raman) are interpreted in terms of fundamental, combination and overtone bands. It is found that the experimental and the VPT2 computed frequencies are in well agreement. The experimental and the calculated UV-Vis spectrum in gas and ethanol solvent are found comparable. Furthermore, HOMO-LUMO analysis, NLO, MEP, and natural charges of the molecule are also reported.

  11. Sum Frequency Generation Vibrational Spectroscopy of Colloidal Platinum Nanoparticle Catalysts: Disordering versus Removal of Organic Capping

    KAUST Repository

    Krier, James M.

    2012-08-23

    Recent work with nanoparticle catalysts shows that size and shape control on the nanometer scale influences reaction rate and selectivity. Sum frequency generation (SFG) vibrational spectroscopy is a powerful tool for studying heterogeneous catalysis because it enables the observation of surface intermediates during catalytic reactions. To control the size and shape of catalytic nanoparticles, an organic ligand was used as a capping agent to stabilize nanoparticles during synthesis. However, the presence of an organic capping agent presents two major challenges in SFG and catalytic reaction studies: it blocks a significant fraction of active surface sites and produces a strong signal that prevents the detection of reaction intermediates with SFG. Two methods for cleaning Pt nanoparticles capped with poly (vinylpyrrolidone) (PVP) are examined in this study: solvent cleaning and UV cleaning. Solvent cleaning leaves more PVP intact and relies on disordering with hydrogen gas to reduce the SFG signal of PVP. In contrast, UV cleaning depends on nearly complete removal of PVP to reduce SFG signal. Both UV and solvent cleaning enable the detection of reaction intermediates by SFG. However, solvent cleaning also yields nanoparticles that are stable under reaction conditions, whereas UV cleaning results in aggregation during reaction. The results of this study indicate that solvent cleaning is more advantageous for studying the effects of nanoparticle size and shape on catalytic selectivity by SFG vibrational spectroscopy. © 2012 American Chemical Society.

  12. Analysis of subsystem randomness effects on the mid-frequency vibrations of built-up structures

    Science.gov (United States)

    Ji, Lin; Huang, Zhenyu

    2013-06-01

    The paper concerns the analysis of subsystem randomness effects on the mid-frequency vibration responses of built-up systems. The system model considered, in the first instance, is a long-wavelength finite element (FE) subsystem connected with a short-wavelength statistical energy analysis (SEA) subsystem via discrete couplings. The randomness effects of the SEA subsystem on both the displacement response of the FE subsystem and the energy response of the SEA subsystem are then investigated under the frame of the hybrid FE/SEA theory [P. Shorter, R. Langley, Vibro-acoustic analysis of complex systems, Journal of Sound and Vibration, 288 (2005) 669-700]. It is found that the subsystem randomness effects may be well indicated by a dimensionless parameter α, which is a function of the number of coupling points, the dynamic mismatch between the FE and SEA subsystems and the modal overlap factor of the SEA subsystem. The smaller the value of α is, the more insignificant the randomness effects are. As a result, a so-called "α-criterion" is derived which states that, if a built-up structure satisfies the condition of α≪1, the randomness effects of the SEA subsystem can be neglected. In this case, the SEA subsystem can be simply treated as an infinite (or semi-infinite as appropriate) structure regardless of its mode count being sufficiently high or not. Numerical examples are presented to illustrate the validity of the present theory.

  13. Experimental Raman and IR spectral and theoretical studies of vibrational spectrum and molecular structure of Pantothenic acid (vitamin B5)

    Science.gov (United States)

    Srivastava, Mayuri; Singh, N. P.; Yadav, R. A.

    2014-08-01

    Vibrational spectrum of Pantothenic acid has been investigated using experimental IR and Raman spectroscopies and density functional theory methods available with the Gaussian 09 software. Vibrational assignments of the observed IR and Raman bands have been proposed in light of the results obtained from computations. In order to assign the observed IR and Raman frequencies the potential energy distributions (PEDs) have also been computed using GAR2PED software. Optimized geometrical parameters suggest that the overall symmetry of the molecule is C1. The molecule is found to possess eight conformations. Conformational analysis was carried out to obtain the most stable configuration of the molecule. In the present paper the vibrational features of the lowest energy conformer C-I have been studied. The two methyl groups have slightly distorted symmetries from C3V. The acidic Osbnd H bond is found to be the smallest one. To investigate molecular stability and bond strength we have used natural bond orbital analysis (NBO). Charge transfer occurs in the molecule have been shown by the calculated highest occupied molecular orbital-lowest unoccupied molecular orbital (HOMO-LUMO) energies. The mapping of electron density iso-surface with electrostatic potential (ESP), has been carried out to get the information about the size, shape, charge density distribution and site of chemical reactivity of the molecule.

  14. Stability of high-frequency periodic motions of a heavy rigid body with a horizontally vibrating suspension point

    Science.gov (United States)

    Belichenko, M. V.

    2016-11-01

    The motion of a heavy rigid body one of whose points (the suspension point) executes horizontal harmonic high-frequency vibrations with small amplitude is considered. The problem of existence of high-frequency periodic motions with period equal to the period of the suspension point vibrations is considered. The stability conditions for the revealed motions are obtained in the linear approximation. The following three special cases of mass distribution in the body are considered; a body whose center of mass lies on the principal axis of inertia, a body whose center of mass lies in the principal plane of inertia, and a dynamically symmetric body.

  15. Structure of the ethylammonium nitrate surface: an X-ray reflectivity and vibrational sum frequency spectroscopy study.

    Science.gov (United States)

    Niga, Petru; Wakeham, Deborah; Nelson, Andrew; Warr, Gregory G; Rutland, Mark; Atkin, Rob

    2010-06-01

    X-ray reflectivity and vibrational sum frequency spectroscopy are used to probe the structure of the ethylammonium nitrate (EAN)-air interface. X-ray reflectivity reveals that the EAN-air interface is structured and consists of alternating nonpolar and charged layers that extend 31 A into the bulk. Vibrational sum frequency spectroscopy reveals interfacial cations have their ethyl moieties oriented toward air, with the CH(3) C(3) axis positioned approximately 36.5 degrees from interface normal. This structure is invariant between 15 and 51 degrees C. On account of its molecular symmetry, the orientation of the nitrate anion cannot be determined with certainty.

  16. A study of the eigenvectors of the low-frequency vibrational modes in crystalline adenosine via high pressure Raman spectroscopy.

    Science.gov (United States)

    Lee, Scott A; Pinnick, David A; Anderson, A

    2014-12-01

    High-pressure Raman spectroscopy has been used to study the eigenvectors and eigenvalues of the vibrational modes of crystalline adenosine at 295 K by evaluating the logarithmic derivative of the vibrational frequency with respect to pressure: [Formula: see text]. Crystalline samples of molecular materials such as adenosine will have vibrational modes that are localized within a molecular unit ("internal" modes) as well as modes in which the molecular units vibrate against each other ("external" modes). The value of the logarithmic derivative is found to be a diagnostic probe of the nature of the eigenvector of the vibrational modes. Stretching modes which are predominantly internal to the molecule have low logarithmic derivatives while external modes have higher logarithmic derivatives. Particular interest is paid to the low-frequency (≤150 cm(-1)) modes. Based on the pressure dependence of its logarithmic derivative, a mode near 49 cm(-1) is identified as internal mode. The other modes below 400 cm(-1) have pressure dependences of their logarithmic derivatives consistent with being either (1) modes which are mainly external, meaning that the molecules of the unit cell vibrate against each other in translational or librational motions (or linear combinations thereof), or (2) torsional or bending modes involving a large number of atoms, mainly within a molecule. The modes above 400 cm(-1) all have pressure dependences of their logarithmic derivatives consistent with being mainly internal modes.

  17. The effects of whole-body vibration on the Wingate test for anaerobic power when applying individualized frequencies.

    Science.gov (United States)

    Surowiec, Rachel K; Wang, Henry; Nagelkirk, Paul R; Frame, Jeffrey W; Dickin, D Clark

    2014-07-01

    Recently, individualized frequency (I-Freq) has been introduced with the notion that athletes may elicit a greater reflex response at differing levels (Hz) of vibration. The aim of the study was to evaluate acute whole-body vibration as a feasible intervention to increase power in trained cyclists and evaluate the efficacy of using I-Freq as an alternative to 30Hz, a common frequency seen in the literature. Twelve highly trained, competitive male cyclists (age, 29.9 ± 10.0 years; body height, 175.4 ± 7.8 cm; body mass, 77.3 ± 13.9 kg) participated in the study. A Wingate test for anaerobic power was administered on 3 occasions: following a control of no vibration, 30 Hz, or I-freq. Measures of peak power, average power (AP), and the rate of fatigue were recorded and compared with the vibration conditions using separate repeated measures analysis of variance. Peak power, AP, and the rate of fatigue were not significantly impacted by either the 30 Hz or I-Freq vibration interventions (p > 0.05). Given the trained status of the individuals in this study, the ability to elicit an acute response may have been muted. Future studies should further refine the vibration parameters used and assess changes in untrained or recreationally trained populations.

  18. Note: A kinematic shaker system for high amplitude, low frequency vibration testing.

    Science.gov (United States)

    Swaminathan, Anand; Poese, Matthew E; Smith, Robert W M; Garrett, Steven L

    2015-11-01

    This note describes a shaker system capable of high peak-velocity, large amplitude, low frequency, near-sinusoidal excitation that has been constructed and employed in experiments on the inhibition of Rayleigh-Bénard convection using acceleration modulation. The production of high peak-velocity vibration is of interest in parametric excitation problems of this type and reaches beyond the capabilities of standard electromagnetic shakers. The shaker system described employs a kinematic linkage to two counter-rotating flywheels, driven by a variable-speed electrical motor, producing peak-to-peak displacements of 15.24 cm to a platform mounted on two guide rails. In operation, this shaker has been demonstrated to produce peak speeds of up to 3.7 m/s without failure.

  19. Sum Frequency Generation Vibrational Spectroscopy of Pyridine Hydrogenation on Platinum Nanoparticles

    Energy Technology Data Exchange (ETDEWEB)

    Bratlie, Kaitlin M.; Komvopoulos, Kyriakos; Somorjai, Gabor A.

    2008-02-22

    Pyridine hydrogenation in the presence of a surface monolayer consisting of cubic Pt nanoparticles stabilized by tetradecyltrimethylammonium bromide (TTAB) was investigated by sum frequency generation (SFG) vibrational spectroscopy using total internal reflection (TIR) geometry. TIR-SFG spectra analysis revealed that a pyridinium cation (C{sub 5}H{sub 5}NH{sup +}) forms during pyridine hydrogenation on the Pt nanoparticle surface, and the NH group in the C{sub 5}H{sub 5}NH{sup +} cation becomes more hydrogen bound with the increase of the temperature. In addition, the surface coverage of the cation decreases with the increase of the temperature. An important contribution of this study is the in situ identification of reaction intermediates adsorbed on the Pt nanoparticle monolayer during pyridine hydrogenation.

  20. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Science.gov (United States)

    Sharpes, Nathan; Abdelkefi, Abdessattar; Priya, Shashank

    2015-08-01

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm2 area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  1. Coupled rotor-fuselage vibration reduction with multiple frequency blade pitch control

    Science.gov (United States)

    Papavassiliou, I.; Friedmann, P. P.; Venkatesan, C.

    1991-01-01

    A nonlinear coupled rotor/flexible fuselage analysis has been developed and used to study the effects of higher harmonic blade pitch control on the vibratory hub loads and fuselage acceleration levels. Previous results, obtained with this model have shown that conventional higher harmonic control (HHC) inputs aimed at hub shear reduction cause an increase in the fuselage accelerations and vice-versa. It was also found that for simultaneous reduction of hub shears and fuselage accelerations, a pitch input representing a combination of two higher harmonic components of different frequencies was needed. Subsequently, it was found that this input could not be implemented through a conventional swashplate. This paper corrects a mistake originally made in the representation of the multiple frequency pitch input and shows that such a pitch input can be only implemented in the rotating reference frame. A rigorous mathematical solution is found, for the pitch input in the rotating reference frame, which produces simultaneous reduction of hub shears and fuselage acceleration. New insight on vibration reduction in coupled rotor/fuselage systems is obtained from the sensitivity of hub shears to the frequency and amplitude of the open loop HHC signal in the rotating reference frame. Finally the role of fuselage flexibility in this class of problems is determined.

  2. Fundamental Frequencies of Vibration of Footbridges in Portugal: From In Situ Measurements to Numerical Modelling

    Directory of Open Access Journals (Sweden)

    C. S. Oliveira

    2014-01-01

    Full Text Available Since 1995, we have been measuring the in situ dynamic characteristics of different types of footbridges built in Portugal (essentially steel and precast reinforced concrete decks with single spans running from 11 to 110 m long, using expedite exciting and measuring techniques. A database has been created, containing not only the fundamental dynamic characteristics of those structures (transversal, longitudinal, and vertical frequencies but also their most important geometric and mechanical properties. This database, with 79 structures organized into 5 main typologies, allows the setting of correlations of fundamental frequencies as a negative power function of span lengths L  (L-0.6 to L-1.4. For 63 footbridges of more simple geometry, it was possible to obtain these correlations by typology. A few illustrative cases representing the most common typologies show that linear numerical models can reproduce the in situ measurements with great accuracy, not only matching the frequencies of vibration but also the amplitudes of motion caused by several pedestrian load patterns.

  3. Accurate Lineshapes from Sub-1 cm-1 Resolution Sum Frequency Generation Vibrational Spectroscopy of α-Pinene at Room Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Mifflin, Amanda L.; Velarde Ruiz Esparza, Luis A.; Ho, Junming; Psciuk, Brian; Negre, Christian; Ebben, Carlena J.; Upshur, Mary Alice; Lu, Zhou; Strick, Benjamin; Thomson, Regan; Batista, Victor; Wang, Hongfei; Geiger, Franz M.

    2015-02-26

    Room temperature sub-wavenumber high-resolution broadband sum frequency generation (HR-BB-SFG) spectra of the common terpene (+)-α-pinene reveal ten peaks in the C–H stretching region. The spectral resolution exceeds that of Fourier transform infrared, femtosecond stimulated Raman, and traditional BB-SFG and scanning SFG spectroscopy of the same molecule. Experiment and simulation show the spectral lineshapes to be accurate. Homogeneous vibrational decoherence lifetimes of up to 1.7 psec are assigned to specific oscillators and compare favorably to lifetimes computed from density functional tight binding molecular dynamics calculations, while phase-resolved spectra yield orientation information for them. We propose the new spectroscopy as an attractive alternative to time-resolved vibrational spectroscopy or heterodyne-detection schemes for studying vibrational energy relaxation and vibrational coherences in molecules.

  4. Influence of high-frequency vibrations on the onset of convection in a two-layer system

    Science.gov (United States)

    Zenkovskaya, Svetlana M.; Novosiadliy, Vasili A.

    2008-03-01

    This Note deals with the influence of high-frequency translational oscillations on the onset of convection in a two-layer system of weakly heterogeneous immiscible fluids with deformable interface. The averaging method is applied to the generalized Oberbeck-Boussinesq equations. Vibration-generated forces and tensions appear as the result. A transition to the Oberbeck-Boussinesq approximation is made in the averaged equations. Analysis of averaged equations leads to the following conclusions. Horizontal vibrations are obtained not influencing the onset of convection, and in the cases of other directions the influence of vibration is determined by a single parameter, depending on velocity amplitude and direction. Vibration is shown to generate effective surface tension, smoothing the interface. Critical parameters are calculated for the case of homogeneous fluids. To cite this article: S.M. Zenkovskaya, V.A. Novosiadliy, C. R. Mecanique 336 (2008).

  5. Analytical Harmonic Vibrational Frequencies for the Green Fluorescent Protein Computed with ONIOM: Chromophore Mode Character and Its Response to Environment.

    Science.gov (United States)

    Thompson, Lee M; Lasoroski, Aurélie; Champion, Paul M; Sage, J Timothy; Frisch, Michael J; van Thor, Jasper J; Bearpark, Michael J

    2014-02-11

    A systematic comparison of different environmental effects on the vibrational modes of the 4-hydroxybenzylidene-2,3-dimethylimidazolinone (HBDI) chromophore using the ONIOM method allows us to model how the molecule's spectroscopic transitions are modified in the Green Fluorescent Protein (GFP). ONIOM(QM:MM) reduces the expense of normal mode calculations when computing the majority of second derivatives only at the MM level. New developments described here for the efficient solution of the CPHF equations, including contributions from electrostatic interactions with environment charges, mean that QM model systems of ∼100 atoms can be embedded within a much larger MM environment of ∼5000 atoms. The resulting vibrational normal modes, their associated frequencies, and dipole derivative vectors have been used to interpret experimental difference spectra (GFPI2-GFPA), chromophore vibrational Stark shifts, and changes in the difference between electronic and vibrational transition dipoles (mode angles) in the protein environment.

  6. Design of serial linkage-type vibration energy harvester with three resonant frequencies

    Science.gov (United States)

    Kim, Hyun Soo; Kim, Jun Woo; Park, Shi-Baek; Choi, Yong Je

    2017-11-01

    This paper presents a new design method of a planar 3 degrees-of-freedom(DOF) serial linkage-type vibration energy harvester with a single proof mass. The harvester is designed to generate electrical power at equally spaced three target resonant frequencies which can be chosen arbitrarily. For given target frequencies and a proof mass, the design method involves (1) the determination of the stiffness matrix, (2) the synthesis of the stiffness by means of a parallel connection of three line springs and (3) its conversion into a 3DOF device connected serially by torsional springs. The torsional springs are realized by the flexible hinge joints and the polyvinylidene fluoride(PVDF) films are attached on the joints. Upon determination of the desired stiffness matrix, the SQP algorithm is utilized to find the optimum locations and spring constants of the serial hinge joints for the minimum difference among three electrical power peaks. The FEM analysis and experiments are conducted to verify the proposed design method. Three measured resonant power peaks occur at 24.7, 30.4 and 33.6 Hz comparing to the target frequencies of 25, 30 and 35 Hz. The normalized maximum power of 14.5 {{uW}}/{({{{ms}}}-2)}2 is generated at 24.7 Hz. The experimental results also demonstrate that the harvester can generate at least 18.6% of the peak power throughout the frequency range from 23.1 to 36.5 Hz, which ensures consistently acquirable power within the operating frequency range by virtue of the coupled effect of a serial linkage-type structure.

  7. Investigation of polyvinylidene fluoride (PVDF) films in identifying high-frequency vibration modes of flexible plates.

    Science.gov (United States)

    Chuang, Kuo-Chih; Liou, Hong-Cin; Ma, Chien-Ching

    2014-06-01

    Compared with piezoelectric ceramics such as lead zirconate titanate (PZT) ceramics, the low density and high compliance of the PVDF films make them a more suitable choice in modal testing, especially for detecting high-frequency modes in flexible or inflatable structures. In this work, dynamic sensing performances of PVDF films for flexible structures in modal testing are examined, with considerations including the repeatability of the impact source, the accuracy of the sensing responses, and the influences of the nodal lines on the frequency spectra of the transient responses. Two flexible plates with different boundary conditions and thickness are considered. Experimental results, compared with FEM computations or theoretical predictions, demonstrate the excellent dynamic sensing performance of the PVDF film in modal testing applications, especially for identification of high-frequency modes on flexible structures.

  8. Using frequency response functions to manage image degradation from equipment vibration in the Daniel K. Inouye Solar Telescope

    Science.gov (United States)

    McBride, William R.; McBride, Daniel R.

    2016-08-01

    The Daniel K Inouye Solar Telescope (DKIST) will be the largest solar telescope in the world, providing a significant increase in the resolution of solar data available to the scientific community. Vibration mitigation is critical in long focal-length telescopes such as the Inouye Solar Telescope, especially when adaptive optics are employed to correct for atmospheric seeing. For this reason, a vibration error budget has been implemented. Initially, the FRFs for the various mounting points of ancillary equipment were estimated using the finite element analysis (FEA) of the telescope structures. FEA analysis is well documented and understood; the focus of this paper is on the methods involved in estimating a set of experimental (measured) transfer functions of the as-built telescope structure for the purpose of vibration management. Techniques to measure low-frequency single-input-single-output (SISO) frequency response functions (FRF) between vibration source locations and image motion on the focal plane are described. The measurement equipment includes an instrumented inertial-mass shaker capable of operation down to 4 Hz along with seismic accelerometers. The measurement of vibration at frequencies below 10 Hz with good signal-to-noise ratio (SNR) requires several noise reduction techniques including high-performance windows, noise-averaging, tracking filters, and spectral estimation. These signal-processing techniques are described in detail.

  9. Rovibrational spectroscopic constants and fundamental vibrational frequencies for isotopologues of cyclic and bent singlet HC{sub 2}N isomers

    Energy Technology Data Exchange (ETDEWEB)

    Inostroza, Natalia; Fortenberry, Ryan C.; Lee, Timothy J. [NASA Ames Research Center, Moffett Field, CA 94035-1000 (United States); Huang, Xinchuan, E-mail: Timothy.J.Lee@nasa.gov [SETI Institute, 189 Bernardo Avenue, Suite 100, Mountain View, CA 94043 (United States)

    2013-12-01

    Through established, highly accurate ab initio quartic force fields, a complete set of fundamental vibrational frequencies, rotational constants, and rovibrational coupling and centrifugal distortion constants have been determined for both the cyclic 1 {sup 1} A' and bent 2 {sup 1} A' DCCN, H{sup 13}CCN, HC{sup 13}CN, and HCC{sup 15}N isotopologues of HCCN. Spectroscopic constants are computed for all isotopologues using second-order vibrational perturbation theory (VPT2), and the fundamental vibrational frequencies are computed with VPT2 and vibrational configuration interaction (VCI) theory. Agreement between VPT2 and VCI results is quite good, with the fundamental vibrational frequencies of the bent isomer isotopologues in accord to within a 0.1-3.2 cm{sup –1} range. Similar accuracies are present for the cyclic isomer isotopologues. The data generated here serve as a reference for astronomical observations of these closed-shell, highly dipolar molecules using new, high-resolution telescopes and as reference for laboratory studies where isotopic labeling may lead to elucidation of the formation mechanism for the known interstellar molecule: X {sup 3} A' HCCN.

  10. Low intensity, high frequency vibration training to improve musculoskeletal function in a mouse model of Duchenne muscular dystrophy.

    Directory of Open Access Journals (Sweden)

    Susan A Novotny

    Full Text Available The objective of the study was to determine if low intensity, high frequency vibration training impacted the musculoskeletal system in a mouse model of Duchenne muscular dystrophy, relative to healthy mice. Three-week old wildtype (n = 26 and mdx mice (n = 22 were randomized to non-vibrated or vibrated (45 Hz and 0.6 g, 15 min/d, 5 d/wk groups. In vivo and ex vivo contractile function of the anterior crural and extensor digitorum longus muscles, respectively, were assessed following 8 wks of vibration. Mdx mice were injected 5 and 1 days prior to sacrifice with Calcein and Xylenol, respectively. Muscles were prepared for histological and triglyceride analyses and subcutaneous and visceral fat pads were excised and weighed. Tibial bones were dissected and analyzed by micro-computed tomography for trabecular morphometry at the metaphysis, and cortical geometry and density at the mid-diaphysis. Three-point bending tests were used to assess cortical bone mechanical properties and a subset of tibiae was processed for dynamic histomorphometry. Vibration training for 8 wks did not alter trabecular morphometry, dynamic histomorphometry, cortical geometry, or mechanical properties (P ≥ 0.34. Vibration did not alter any measure of muscle contractile function (P ≥ 0.12; however the preservation of muscle function and morphology in mdx mice indicates vibration is not deleterious to muscle lacking dystrophin. Vibrated mice had smaller subcutaneous fat pads (P = 0.03 and higher intramuscular triglyceride concentrations (P = 0.03. These data suggest that vibration training at 45 Hz and 0.6 g did not significantly impact the tibial bone and the surrounding musculature, but may influence fat distribution in mice.

  11. Structural, Vibrational, and Electronic Properties of the Glucoalkaloid Strictosidine: A Combined Experimental and Theoretical Study

    Directory of Open Access Journals (Sweden)

    Renyer Alves Costa

    2016-01-01

    Full Text Available A detailed structural analysis and spectral behavior of the glucoalkaloid strictosidine, a precursor of all monoterpene indole alkaloids, are discussed. The experimental NMR, FTIR, and UV results were compared to the theoretical DFT spectra calculated by Becke using the three-parameter Lee-Yang-Parr (B3LYP function with 6-31G(d and 6-311++G(2d,p basis sets. The theoretical geometry optimization data were compared with the X-ray data for precursors and similar structures in the associated literature. The similarity between the theoretical and experimental coupling constants values made it possible to affirm the values of dihedral angles and their configuration, reinforcing findings from previous stereochemical studies. Theoretical UV analysis agreed well with the measured experimental data, with bands assigned. Calculated HOMO/LUMO gaps show low excitation energy for strictosidine, justifying its stability and reaction kinetics. The molecular electrostatic potential map shows opposite potentials regions that form hydrogen bonds that stabilize the dimeric form, which were confirmed by excellent agreement of the dimeric form theoretical wavenumbers with the experimental IR spectrum. ESI-MS/MS data revealed patterns for the fragmentation of the protonated strictosidine molecule outlined by an NBO study.

  12. Fin whale sound reception mechanisms: skull vibration enables low-frequency hearing.

    Directory of Open Access Journals (Sweden)

    Ted W Cranford

    Full Text Available Hearing mechanisms in baleen whales (Mysticeti are essentially unknown but their vocalization frequencies overlap with anthropogenic sound sources. Synthetic audiograms were generated for a fin whale by applying finite element modeling tools to X-ray computed tomography (CT scans. We CT scanned the head of a small fin whale (Balaenoptera physalus in a scanner designed for solid-fuel rocket motors. Our computer (finite element modeling toolkit allowed us to visualize what occurs when sounds interact with the anatomic geometry of the whale's head. Simulations reveal two mechanisms that excite both bony ear complexes, (1 the skull-vibration enabled bone conduction mechanism and (2 a pressure mechanism transmitted through soft tissues. Bone conduction is the predominant mechanism. The mass density of the bony ear complexes and their firmly embedded attachments to the skull are universal across the Mysticeti, suggesting that sound reception mechanisms are similar in all baleen whales. Interactions between incident sound waves and the skull cause deformations that induce motion in each bony ear complex, resulting in best hearing sensitivity for low-frequency sounds. This predominant low-frequency sensitivity has significant implications for assessing mysticete exposure levels to anthropogenic sounds. The din of man-made ocean noise has increased steadily over the past half century. Our results provide valuable data for U.S. regulatory agencies and concerned large-scale industrial users of the ocean environment. This study transforms our understanding of baleen whale hearing and provides a means to predict auditory sensitivity across a broad spectrum of sound frequencies.

  13. Fin whale sound reception mechanisms: skull vibration enables low-frequency hearing.

    Science.gov (United States)

    Cranford, Ted W; Krysl, Petr

    2015-01-01

    Hearing mechanisms in baleen whales (Mysticeti) are essentially unknown but their vocalization frequencies overlap with anthropogenic sound sources. Synthetic audiograms were generated for a fin whale by applying finite element modeling tools to X-ray computed tomography (CT) scans. We CT scanned the head of a small fin whale (Balaenoptera physalus) in a scanner designed for solid-fuel rocket motors. Our computer (finite element) modeling toolkit allowed us to visualize what occurs when sounds interact with the anatomic geometry of the whale's head. Simulations reveal two mechanisms that excite both bony ear complexes, (1) the skull-vibration enabled bone conduction mechanism and (2) a pressure mechanism transmitted through soft tissues. Bone conduction is the predominant mechanism. The mass density of the bony ear complexes and their firmly embedded attachments to the skull are universal across the Mysticeti, suggesting that sound reception mechanisms are similar in all baleen whales. Interactions between incident sound waves and the skull cause deformations that induce motion in each bony ear complex, resulting in best hearing sensitivity for low-frequency sounds. This predominant low-frequency sensitivity has significant implications for assessing mysticete exposure levels to anthropogenic sounds. The din of man-made ocean noise has increased steadily over the past half century. Our results provide valuable data for U.S. regulatory agencies and concerned large-scale industrial users of the ocean environment. This study transforms our understanding of baleen whale hearing and provides a means to predict auditory sensitivity across a broad spectrum of sound frequencies.

  14. Fin Whale Sound Reception Mechanisms: Skull Vibration Enables Low-Frequency Hearing

    Science.gov (United States)

    Cranford, Ted W.; Krysl, Petr

    2015-01-01

    Hearing mechanisms in baleen whales (Mysticeti) are essentially unknown but their vocalization frequencies overlap with anthropogenic sound sources. Synthetic audiograms were generated for a fin whale by applying finite element modeling tools to X-ray computed tomography (CT) scans. We CT scanned the head of a small fin whale (Balaenoptera physalus) in a scanner designed for solid-fuel rocket motors. Our computer (finite element) modeling toolkit allowed us to visualize what occurs when sounds interact with the anatomic geometry of the whale’s head. Simulations reveal two mechanisms that excite both bony ear complexes, (1) the skull-vibration enabled bone conduction mechanism and (2) a pressure mechanism transmitted through soft tissues. Bone conduction is the predominant mechanism. The mass density of the bony ear complexes and their firmly embedded attachments to the skull are universal across the Mysticeti, suggesting that sound reception mechanisms are similar in all baleen whales. Interactions between incident sound waves and the skull cause deformations that induce motion in each bony ear complex, resulting in best hearing sensitivity for low-frequency sounds. This predominant low-frequency sensitivity has significant implications for assessing mysticete exposure levels to anthropogenic sounds. The din of man-made ocean noise has increased steadily over the past half century. Our results provide valuable data for U.S. regulatory agencies and concerned large-scale industrial users of the ocean environment. This study transforms our understanding of baleen whale hearing and provides a means to predict auditory sensitivity across a broad spectrum of sound frequencies. PMID:25633412

  15. Calculation and analysis of the harmonic vibrational frequencies in molecules at extreme pressure: Methodology and diborane as a test case

    Science.gov (United States)

    Cammi, R.; Cappelli, C.; Mennucci, B.; Tomasi, J.

    2012-10-01

    We present a new quantum chemical method for the calculation of the equilibrium geometry and the harmonic vibrational frequencies of molecular systems in dense medium at high pressures (of the order of GPa). The new computational method, named PCM-XP, is based on the polarizable continuum model (PCM), amply used for the study of the solvent effects at standard condition of pressure, and it is accompanied by a new method of analysis for the interpretation of the mechanisms underpinning the effects of pressure on the molecular geometries and the harmonic vibrational frequencies. The PCM-XP has been applied at the density functional theory level to diborane as a molecular system under high pressure. The computed harmonic vibrational frequencies as a function of the pressure have shown a satisfactory agreement with the corresponding experimental results, and the parallel application of the method of analysis has reveled that the effects of the pressure on the equilibrium geometry can be interpreted in terms of direct effects on the electronic charge distribution of the molecular solutes, and that the effects on the harmonic vibrational frequencies can be described in terms of two physically distinct effects of the pressure (curvature and relaxation) on the potential energy for the motion of the nuclei.

  16. An Experimental and Theoretical Investigation of a Micromirror Under Mixed-Frequency Excitation

    KAUST Repository

    Ilyas, Saad

    2015-01-12

    We present an experimental and theoretical investigation of a micromachined mirror under a mixed-frequency signal composed of two harmonic ac sources. The micromirror is made of polyimide as the main structural layer. The experimental and theoretical dynamics are explored via frequency sweeps in the desired neighborhoods. One frequency is fixed while the other frequency is swept through a wide range to study the dynamic responses. To simulate the behavior of the micromirror, it is modeled as a single degree of freedom system, where the parameters of the model are extracted experimentally. A good agreement is reported among the simulation results and the experimental data. These responses are studied under different frequencies and input voltages. The results show interesting dynamics, where the system exhibits primary resonance and combination resonances of additive and subtractive type. The mixed excitation is demonstrated as a way to increase the bandwidth of the resonator near primary resonance, which can be promising for resonant sensing applications in the effort to increase the signal-noise ratio over extended frequency range.

  17. Hybrid nanogenerators for low frequency vibration energy harvesting and self-powered wireless locating

    Science.gov (United States)

    Yuan, Ying; Zhang, Hulin; Wang, Jie; Xie, Yuhang; Khan, Saeed Ahmed; Jin, Long; Yan, Zhuocheng; Huang, Long; Pan, Taisong; Yang, Weiqing; Lin, Yuan

    2018-01-01

    Hybrid energy harvesters based on different physical effects is fascinating, but a rational design for multiple energy harvesting is challenging. In this work, a spring-magnet oscillator-based triboelectric-electromagnetic generator (EMG) with a solar cell cap is proposed. A power was produced by a triboelectric nanogenerator (TENG) and an EMG independently or simultaneously by using a shared spring-magnet oscillator. The oscillator configuration enables versatile energy harvesting with the excellent size scalability and self-packaged structure which can perform well at low frequency ranging from 3.5 to 5 Hz. The solar cell cap mounted above the oscillator can harvest solar energy. Under vibrations at the frequency of 4 Hz, the TENG and the EMG produced maximum output power of 5.46 nW cm‑3 and 378.79 μW cm‑3, respectively. The generated electricity by the hybrid nanogenerator can be stored in a capacitor or Li-ion battery, which is capable of powering a wireless locator for real-time locating data reporting to a personal cell phone. The light-weight and handy hybrid nanogenerator can directly light a caution light or play as a portable flashlight by shaking hands at night.

  18. Prediction of high-frequency vibration transmission across coupled, periodic ribbed plates by incorporating tunneling mechanisms.

    Science.gov (United States)

    Yin, Jianfei; Hopkins, Carl

    2013-04-01

    Prediction of structure-borne sound transmission on built-up structures at audio frequencies is well-suited to Statistical Energy Analysis (SEA) although the inclusion of periodic ribbed plates presents challenges. This paper considers an approach using Advanced SEA (ASEA) that can incorporate tunneling mechanisms within a statistical approach. The coupled plates used for the investigation form an L-junction comprising a periodic ribbed plate with symmetric ribs and an isotropic homogeneous plate. Experimental SEA (ESEA) is carried out with input data from Finite Element Methods (FEM). This indicates that indirect coupling is significant at high frequencies where bays on the periodic ribbed plate can be treated as individual subsystems. SEA using coupling loss factors from wave theory leads to significant underestimates in the energy of the bays when the isotropic homogeneous plate is excited. This is due to the absence of tunneling mechanisms in the SEA model. In contrast, ASEA shows close agreement with FEM and laboratory measurements. The errors incurred with SEA rapidly increase as the bays become more distant from the source subsystem. ASEA provides significantly more accurate predictions by accounting for the spatial filtering that leads to non-diffuse vibration fields on these more distant bays.

  19. Vibrationally Excited c-C_3H_2 Re-Visited New Laboratory Measurements and Theoretical Calculations

    Science.gov (United States)

    Gupta, Harshal; Westerfield, J. H.; Baraban, Joshua H.; Changala, Bryan; Thorwirth, Sven; Stanton, John F.; Martin-Drumel, Marie-Aline; Pirali, Olivier; Gottlieb, Carl A.; McCarthy, Michael C.

    2017-06-01

    Cyclopropenylidene, c-C_3H_2, is one of the more abundant organic molecules in the interstellar medium, as evidenced from astronomical detection of its single ^{13}C and both its singly- and doubly-deuterated isotopic species. For this reason, vibrational satellites are of considerable astronomical interest, and were the primary motivation for the earlier laboratory work by Mollaaghababa and co-workers [1]. The recent detection of intense unidentified lines near 18 GHz in a hydrocarbon discharge by FT microwave spectroscopy has spurred a renewed search for the vibrational satellite transitions of c-C_3H_2. Several strong lines have been definitively assigned to the v_6 progression on the basis of follow-up measurements at 3 mm, double resonance and millimeter-wave absorption spectroscopy, and new theoretical calculations using a rovibrational VMP2 method [2] and a high-quality ab initio potential energy surface. The treatment was applied to several excited states as well as the ground state, and included deperturbation of Coriolis interactions. [1] R. Mollaaghababa, C.A. Gottlieb, J. M. Vrtilek, and P. Thaddeus, J. Chem. Phys., 99, 890-896 (1992). [2] P. B. Changala and J. H. Baraban. J. Chem. Phys., 145, 174106 (2016).

  20. Synthesis, crystal structure, vibrational spectra and theoretical calculations of quantum chemistry of a potential antimicrobial Meldrum's acid derivative

    Science.gov (United States)

    Campelo, M. J. M.; Freire, P. T. C.; Mendes Filho, J.; de Toledo, T. A.; Teixeira, A. M. R.; da Silva, L. E.; Bento, R. R. F.; Faria, J. L. B.; Pizani, P. S.; Gusmão, G. O. M.; Coutinho, H. D. M.; Oliveira, M. T. A.

    2017-10-01

    A new derivative of Meldrum's acid 5-((5-chloropyridin-2-ylamino)methylene)-2,2-dimethyl-1,3-dioxane-4,6-dione (CYMM) of molecular formula C12H11ClN2O4 was synthesized and structurally characterized using single crystal X-ray diffraction technique. The vibrational properties of the crystal were studied by Fourier Transform infrared (FT-IR), Fourier Transform Raman (FT-Raman) techniques and theoretical calculations of quantum chemistry using Density functional theory (DFT) and Density functional perturbation theory (DFPT). A comparison with experimental spectra allowed the assignment of all the normal modes. The descriptions of the normal modes were carried by means of potential energy distribution (PED). Additionally, analysis of the antimicrobial activity and antibiotic resistance modulatory activity was carried out to evaluate the antibacterial potential of the CYMM.

  1. Stain-free Histopathology of Basal Cell Carcinoma by Dual Vibration Resonance Frequency CARS Microscopy.

    Science.gov (United States)

    Kiss, Norbert; Krolopp, Ádám; Lőrincz, Kende; Bánvölgyi, András; Szipőcs, Róbert; Wikonkál, Norbert

    2017-11-04

    Basal cell carcinoma (BCC) is the most common malignancy in Caucasians. Nonlinear microscopy has been previously utilized for the imaging of BCC, but the captured images do not correlate with H&E staining. Recently, Freudiger et al. introduced a novel method to visualize tissue morphology analogous to H&E staining, using coherent anti-Stokes Raman scattering (CARS) technique. In our present work, we introduce a novel algorithm to post-process images obtained from dual vibration resonance frequency (DVRF) CARS measurements to acquire high-quality pseudo H&E images of BCC samples. We adapted our CARS setup to utilize the distinct vibrational properties of CH 3 (mainly in proteins) and CH 2 bonds (primarily in lipids). In a narrowband setup, the central wavelength of the pump laser is set to 791 nm and 796 nm to obtain optimal excitation. Due to the partial overlap of the excitation spectra and the 5-10 nm FWHM spectral bandwidth of our lasers, we set the wavelengths to 790 nm (proteins) and 800 nm (lipids). Nonresonant background from water molecules also reduces the chemical selectivity which can be significantly improved if we subtract the DVRF images from each other. As a result, we acquired two images: one for "lipids" and one for" proteins" when we properly set a multiplication factor to minimize the non-specific background. By merging these images, we obtained high contrast H&E "stained" images of BBC's. Nonlinear microscope systems upgraded for real time DVRF CARS measurements, providing pseudo H&E images can be suitable for in vivo assessment of BCC in the future.

  2. Theoretical and experimental investigation into structural and fluid motions at low frequencies in water distribution pipes

    Science.gov (United States)

    Gao, Yan; Liu, Yuyou

    2017-06-01

    Vibrational energy is transmitted in buried fluid-filled pipes in a variety of wave types. Axisymmetric (n = 0) waves are of practical interest in the application of acoustic techniques for the detection of leaks in underground pipelines. At low frequencies n = 0 waves propagate longitudinally as fluid-dominated (s = 1) and shell-dominated (s = 2) waves. Whilst sensors such as hydrophones and accelerometers are commonly used to detect leaks in water distribution pipes, the mechanism governing the structural and fluid motions is not well documented. In this paper, the low-frequency behaviour of the pipe wall and the contained fluid is investigated. For most practical pipework systems, these two waves are strongly coupled; in this circumstance the ratios of the radial pipe wall displacements along with the internal pressures associated with these two wave types are obtained. Numerical examples show the relative insensitivity of the structural and fluid motions to the s = 2 wave for both metallic and plastic pipes buried in two typical soils. It is also demonstrated that although both acoustic and vibration sensors at the same location provide the identical phase information of the transmitted signals, pressure responses have significantly higher levels than acceleration responses, and thus hydrophones are better suited in a low signal-to-noise ratio (SNR) environment. This is supported by experimental work carried out at a leak detection facility. Additional pressure measurements involved excitation of the fluid and the pipe fitting (hydrant) on a dedicated water pipe. This work demonstrates that the s = 1 wave is mainly responsible for the structural and fluid motions at low frequencies in water distribution pipes as a result of water leakage and direct pipe excitation.

  3. Two-dimensional concentrated-stress low-frequency piezoelectric vibration energy harvesters

    Energy Technology Data Exchange (ETDEWEB)

    Sharpes, Nathan [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Abdelkefi, Abdessattar [Department of Mechanical and Aerospace Engineering, New Mexico State University, Las Cruces, New Mexico 88003 (United States); Priya, Shashank [Center for Energy Harvesting Materials and Systems (CEHMS), Virginia Tech, Blacksburg, Virginia 24061 (United States); Bio-Inspired Materials and Devices Laboratory (BMDL), Virginia Tech, Blacksburg, Virginia 24061 (United States)

    2015-08-31

    Vibration-based energy harvesters using piezoelectric materials have long made use of the cantilever beam structure. Surmounting the deficiencies in one-dimensional cantilever-based energy harvesters has been a major focus in the literature. In this work, we demonstrate a strategy of using two-dimensional beam shapes to harvest energy from low frequency excitations. A characteristic Zigzag-shaped beam is created to compare against the two proposed two-dimensional beam shapes, all of which occupy a 25.4 × 25.4 mm{sup 2} area. In addition to maintaining the low-resonance bending frequency, the proposed beam shapes are designed with the goal of realizing a concentrated stress structure, whereby stress in the beam is concentrated in a single area where a piezoelectric layer may be placed, rather than being distributed throughout the beam. It is shown analytically, numerically, and experimentally that one of the proposed harvesters is able to provide significant increase in power production, when the base acceleration is set equal to 0.1 g, with only a minimal change in the resonant frequency compared to the current state-of-the-art Zigzag shape. This is accomplished by eliminating torsional effects, producing a more pure bending motion that is necessary for high electromechanical coupling. In addition, the proposed harvesters have a large effective beam tip whereby large tip mass may be placed while retaining a low-profile, resulting in a low volume harvester and subsequently large power density.

  4. Low-Frequency and Broadband Vibration Energy Harvesting Using Base-Mounted Piezoelectric Transducers.

    Science.gov (United States)

    Koven, Robert; Mills, Matthew; Gale, Richard; Aksak, Burak

    2017-11-01

    Piezoelectric vibration energy harvesters often consist of a cantilevered beam composed of a support layer and one or two piezoelectric layers with a tip mass. While this configuration is advantageous for maximizing electromechanical coupling, the mechanical properties of the piezoelectric material can place limitations on harvester size and resonant frequency. Here, we present numerical and experimental results from a new type of piezoelectric energy harvester in which the mechanical properties and the resonant frequency of the cantilever beam resonator are effectively decoupled from the piezoelectric component. Referred to as a base-mounted piezoelectric (BMP) harvester in this paper, this new design features a piezoelectric transducer mounted beneath the base of the cantilevered beam resonator. The flexibility in the material choice for the cantilever beam resonator means that the resonant frequency and the beam dimensions are essentially free parameters. A prototype made with a 1.6 mm mm mm polyurethane beam, a PZT-5H piezoelectric transducer, and an 8.36-g tip mass is shown to produce an average power of 8.75 and at 45 Hz across a 13.0- load under harmonic base excitations of constant peak acceleration at 0.25 and 1.0-g, respectively. We also show an increase in full-width half-maximum bandwidth approximately from 1.5 to 5.6 Hz using an array of four individual BMP harvesters of similar dimensions with peak power generation of at 37.6 Hz across a 1.934- load at 0.25-g peak base excitation. Finite elements-based numerical simulations are shown to be in reasonable agreement with experimental results, indicating that the harvester behaves like a damped mass-spring system as proposed in this paper. Fabricated using casting and laser machining techniques, this harvester shows potential as a low-cost option for powering small, low-power wireless sensor nodes and other low-power devices.

  5. Theoretical Modelling and Effectiveness Study of Slotted Stand-Off Layer Damping Treatment for Rail Vibration and Noise Control

    Directory of Open Access Journals (Sweden)

    Caiyou Zhao

    2015-01-01

    Full Text Available A promising means of reducing railway noise is to increase the damping of the rail, which decreases the vibration of the rail to reduce noise. To achieve this goal, a slotted stand-off layer damping treatment has been developed, and a compound track model with this treatment is developed for investigating the effectiveness of this treatment in terms of the vibration reduction. Through the dynamic analysis of the track undergoing the slotted stand-off layer damping treatment, some guidelines are proposed on the selection of materials and structure parameters for this treatment. In addition, the prototype of the optimal slotted stand-off layer damping treatment has been built and tested in the laboratory. It is found that the slotted stand-off damping treatment shows significant effects in decreasing the amplitude of the accelerance of the rail and a significant reduction of sound emission reflected as the radiation sound pressure level decreases by 8.2 and 9.4 dB at vertical excitation and lateral excitation, respectively, in the frequency range of 0–4000 Hz.

  6. Experimental Demonstration and Theoretical Analysis of Slow Light in a Semiconductor Waveguide at GHz Frequencies

    DEFF Research Database (Denmark)

    Mørk, Jesper; Kjær, Rasmus; Poel, Mike van der

    2005-01-01

    Experimental demonstration and theoretical analysis of slow light in a semiconductor waveguide at GHz frequencies slow-down of light by a factor of two in a semiconductor waveguide at room temperature with a bandwidth of 16.7 GHz using the effect of coherent pulsations of the carrier density. The......-explained by a model accounting for the absorption saturation in the waveguide, when using a lifetime that depends on the reverse bias....

  7. A handy-motion driven, frequency up-converted hybrid vibration energy harvester using PZT bimorph and nonmagnetic ball

    Science.gov (United States)

    Halim, M. A.; Cho, H. O.; Park, J. Y.

    2014-11-01

    We have presented a frequency up-converted hybrid type (Piezoelectric and Electromagnetic) vibration energy harvester that can be used in powering portable and wearable smart devices by handy motion. A transverse impact mechanism has been employed for frequency up-conversion. Use of two transduction mechanisms increases the output power as well as power density. The proposed device consists of a non-magnetic spherical ball (freely movable at handy motion frequency) to impact periodically on the parabolic top of a piezoelectric (PZT) cantilevered mass by sliding over it, allowing it to vibrate at its higher resonant frequency and generates voltage by virtue of piezoelectric effect. A magnet attached to the cantilever vibrates along with it at the same frequency and a relative motion between the magnet and a coil placed below it, induces emf voltage across the coil terminals as well. A macro-scale prototype of the harvester has been fabricated and tested by handy motion. With an optimum magnet-coil overlap, a maximum 0.98mW and 0.64mW peak powers have been obtained from the piezoelectric and the electromagnetic transducers of the proposed device while shaken, respectively. It offers 84.4μWcm-3 peak power density.

  8. A hybrid single-end-access MZI and Φ-OTDR vibration sensing system with high frequency response

    Science.gov (United States)

    Zhang, Yixin; Xia, Lan; Cao, Chunqi; Sun, Zhenhong; Li, Yanting; Zhang, Xuping

    2017-01-01

    A hybrid single-end-access Mach-Zehnder interferometer (MZI) and phase sensitive OTDR (Φ-OTDR) vibration sensing system is proposed and demonstrated experimentally. In our system, the narrow optical pulses and the continuous wave are injected into the fiber through the front end of the fiber at the same time. And at the rear end of the fiber, a frequency-shift-mirror (FSM) is designed to back propagate the continuous wave modulated by the external vibration. Thus the Rayleigh backscattering signals (RBS) and the back propagated continuous wave interfere with the reference light at the same end of the sensing fiber and a single-end-access configuration is achieved. The RBS can be successfully separated from the interference signal (IS) through digital signal process due to their different intermediate frequency based on frequency division multiplexing technique. There is no influence between these two schemes. The experimental results show 10 m spatial resolution and up to 1.2 MHz frequency response along a 6.35 km long fiber. This newly designed single-end-access setup can achieve vibration events locating and high frequency events response, which can be widely used in health monitoring for civil infrastructures and transportation.

  9. Nonnegative Matrix Factorization of time frequency representation of vibration signal for local damage detection - comparison of algorithms

    Science.gov (United States)

    Wodecki, Jacek

    2018-01-01

    Local damage detection in rotating machine elements is very important problem widely researched in the literature. One of the most common approaches is the vibration signal analysis. Since time domain processing is often insufficient, other representations are frequently favored. One of the most common one is time-frequency representation hence authors propose to separate internal processes occurring in the vibration signal by spectrogram matrix factorization. In order to achieve this, it is proposed to use the approach of Nonnegative Matrix Factorization (NMF). In this paper three NMF algorithms are tested using real and simulated data describing single-channel vibration signal acquired on damaged rolling bearing operating in drive pulley in belt conveyor driving station. Results are compared with filtration using Spectral Kurtosis, which is currently recognized as classical method for impulsive information extraction, to verify the validity of presented methodology.

  10. Impact-based piezoelectric energy harvester for multidimensional, low-level, broadband, and low-frequency vibrations

    Science.gov (United States)

    Zhang, Hongjiang; Jiang, Senlin; He, Xuefeng

    2017-05-01

    This letter proposes an impact-based piezoelectric energy harvester that uses a rolling bead contained in a bracket that is supported by a spring. Under either translational or rotational base excitation, the bead moves within the bracket and collides with piezoelectric cantilevers that are located around the bracket; these collisions cause the piezoelectric beams to vibrate and thus produce electrical outputs. The low rolling friction and the motion amplification effect of the spring make the resulting device suitable for collection of low-level vibration energy. Experiments show that the proposed harvester is promising for use in scavenging of energy from the multidimensional, low-level, broadband, and low-frequency vibrations that occur in natural environments.

  11. Damping of vibrational excitations in glasses at terahertz frequency: The case of 3-methylpentane

    KAUST Repository

    Baldi, Giacomo

    2017-10-24

    We report a compared analysis of inelastic X ray scattering (IXS) and of low frequency Raman data of glassy 3-methylpentane. The IXS spectra have been analysed allowing for the existence of two distinct excitations at each scattering wavevector obtaining a consistent interpretation of the spectra. In particular, this procedure allows us to interpret the linewidth of the modes in terms of a simple model which relates them to the width of the first sharp diffraction peak in the static structure factor. In this model, the width of the modes arises from the blurring of the dispersion curves which increases approaching the boundary of the first pseudo-Brillouin zone. The position of the boson peak contribution to the density of vibrational states derived from the Raman scattering measurements is in agreement with the interpretation of the two excitations in terms of a longitudinal mode and a transverse mode, the latter being a result of the mixed character of the transverse modes away from the center of the pseudo-Brillouin zone.

  12. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane.

    Science.gov (United States)

    Ocola, Esther J; Medders, Cross; Meinander, Niklas; Laane, Jaan

    2014-04-28

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x1 (4) + x2 (4)) - b(x1 (2) + x2 (2)) + cx1 (2)x2 (2), where x1 and x2 are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  13. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane

    Science.gov (United States)

    Ocola, Esther J.; Medders, Cross; Meinander, Niklas; Laane, Jaan

    2014-04-01

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x14 + x24) - b(x12 + x22) + cx12x22, where x1 and x2 are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  14. Vibration characteristics of casing string under the exciting force of an electric vibrator

    Directory of Open Access Journals (Sweden)

    Yiyong Yin

    2017-11-01

    Full Text Available Vibration cementing is a new technique that can significantly improve the bond strength of cementing interface. To popularize this technique, it is necessary to solve the key problem of how to make cementing string generate downhole radial vibration in the WOC stage. For this purpose, an electric vibrator was developed. With this vibrator, electric energy is converted into mechanical energy by means of a high-temperature motor vibration unit. The motor vibration unit rotates the eccentric block through an output shaft to generate an exciting source, which produces an axial-rotating exciting force at the bottom of the casing string. Then, the vibration characteristics of vertical well casing string under the exciting force were analyzed by using the principal coordinate analysis method, and the response model of casing string to an electric vibrator was developed. Finally, the effects of casing string length, exciting force and vibration frequency on the vibration amplitude at the lowermost of the casing string were analyzed based on a certain casing program. It is indicated that the casing string length and the square of vibration frequency are inversely proportional to the vibration amplitude at the lowermost of the casing string, and the exciting force is proportional to the vibration amplitude at the lowermost of the casing string. These research results provide a theoretical support for the application of vibration cementing technology to the cementing sites with different requirements on well depth and amplitude.

  15. Low-frequency vibration isolation in six degrees of freedom: the Hummingbird

    NARCIS (Netherlands)

    Rijnveld, N.; Braber, R. van den; Fraanje, P.R.; Dool, T.C. van den

    2010-01-01

    TNO Science and Industry and MECAL have developed a six degree of freedom vibration isolation system that suppresses both floor vibrations and direct forces on a table top. The achieved reduction of transmissibility and compliance is 40 dB between 1 and 50 Hz in vertical direction, and 30 dB between

  16. Theoretical and applied research on bistable dual-piezoelectric-cantilever vibration energy harvesting toward realistic ambience

    Science.gov (United States)

    Gao, Y.; Leng, Y.; Javey, A.; Tan, D.; Liu, J.; Fan, S.; Lai, Z.

    2016-11-01

    Pink noise, which is similar to realistic ambient noise, is normally used to simulate ambience where a piezoelectric energy harvesting system (PEHS) is set up. However, pink noise with standard spectral representation can only be used to simulate excitations assumed to possess constant intensity, whereas realistic ambient noise normally appears with a random spectrum and varying intensity in terms of different locations and time. The output performance of conventional bistable magnetic repulsive energy harvesters is significantly affected by the ambience intensity. Considering this fact, a model bistable dual-piezoelectric-cantilever energy harvester (DPEH) is developed in this study to achieve optimal broadband energy harvesting under a varying-intensity realistic circumstance. We utilized various realistic ambient conditions as excitations to obtain the DPEH energy harvesting performance for theoretical and applied study. The elastically supported PEHS has been proven to be more adaptive to realistic ambience with significant or medium intensity variation, but is less qualified for realistic ambience with constant intensity compared with the rigidly supported PEHS (RPEHS). Fortunately, the dual-piezoelectric-cantilever energy harvesting system is superior to the RPEHS under all circumstances because the dual-piezoelectric cantilevers are efficiently utilized for electromechanical energy conversion to realize optimal energy harvesting.

  17. Theoretical calculations and vibrational potential energy surface of 4-silaspiro(3,3)heptane

    Energy Technology Data Exchange (ETDEWEB)

    Ocola, Esther J.; Medders, Cross; Laane, Jaan, E-mail: laane@mail.chem.tamu.edu [Department of Chemistry, Texas A and M University, College Station, Texas 77843-3255 (United States); Meinander, Niklas [Department of Military Technology, Finnish National Defence University, P.O. Box 7, 00861 Helsinki (Finland)

    2014-04-28

    Theoretical computations have been carried out on 4-silaspiro(3,3)heptane (SSH) in order to calculate its molecular structure and conformational energies. The molecule has two puckered four-membered rings with dihedral angles of 34.2° and a tilt angle of 9.4° between the two rings. Energy calculations were carried out for different conformations of SSH. These results allowed the generation of a two-dimensional ring-puckering potential energy surface (PES) of the form V = a(x{sub 1}{sup 4} + x{sub 2}{sup 4}) – b(x{sub 1}{sup 2} + x{sub 2}{sup 2}) + cx{sub 1}{sup 2}x{sub 2}{sup 2}, where x{sub 1} and x{sub 2} are the ring-puckering coordinates for the two rings. The presence of sufficiently high potential energy barriers prevents the molecule from undergoing pseudorotation. The quantum states, wave functions, and predicted spectra resulting from the PESs were calculated.

  18. Vibration-Based Structural Health Monitoring: Theoretical Foundations and Experimental Validation on Reinforced Concrete Beams

    Directory of Open Access Journals (Sweden)

    Anthony Nkem Ede

    2015-09-01

    Full Text Available Quick identification of damages in structures is of great importance to engineers. Among the various techniques available for the evaluation of reinforced concrete structural integrity, non-destructive tests method remain a viable one as its use can lead to speedy decisions that bring savings on repairs or replacement of damaged reinforced concrete structures. This research uses modal parameter-based non- destructive tests to assess damages in reinforced concrete beams under static load. Four-point static loadings were applied to the 3 RC beams to induce three damage scenarios. After each static loading, a dynamic test was performed to access the degree of stiffness degradation. Modal frequencies and mode shapes obtained depicts clearly the stiffness degradations of the beams as the severity of damages on the beams became more pronounced. Results obtained showed that the research procedure adopted is a smart approach for damage assessment in reinforced concrete elements.

  19. Density functional theory for prediction of far-infrared vibrational frequencies: molecular crystals of astrophysical interest

    Science.gov (United States)

    Ennis, C.; Auchettl, R.; Appadoo, D. R. T.; Robertson, E. G.

    2017-11-01

    Solid-state density functional theory code has been implemented for the structure optimization of crystalline methanol, acetaldehyde and acetic acid and for the calculation of infrared frequencies. The results are compared to thin film spectra obtained from low-temperature experiments performed at the Australian Synchrotron. Harmonic frequency calculations of the internal modes calculated at the B3LYP-D3/m-6-311G(d) level shows higher deviation from infrared experiment than more advanced theory applied to the gas phase. Importantly for the solid-state, the simulation of low-frequency molecular lattice modes closely resembles the observed far-infrared features after application of a 0.92 scaling factor. This allowed experimental peaks to be assigned to specific translation and libration modes, including acetaldehyde and acetic acid lattice features for the first time. These frequency calculations have been performed without the need for supercomputing resources that are required for large molecular clusters using comparable levels of theory. This new theoretical approach will find use for the rapid characterization of intermolecular interactions and bonding in crystals, and the assignment of far-infrared spectra for crystalline samples such as pharmaceuticals and molecular ices. One interesting application may be for the detection of species of prebiotic interest on the surfaces of Kuiper-Belt and Trans-Neptunian Objects. At such locations, the three small organic molecules studied here could reside in their crystalline phase. The far-infrared spectra for their low-temperature solid phases are collected under planetary conditions, allowing us to compile and assign their most intense spectral features to assist future far-infrared surveys of icy Solar system surfaces.

  20. Low-frequency vibrational excitations in the amorphous and crystalline states of triphenyl phosphite: A neutron and Raman scattering investigation

    Science.gov (United States)

    Hédoux, Alain; Derollez, Patrick; Guinet, Yannick; Dianoux, Albert José; Descamps, Marc

    2001-04-01

    The vibrational density of states in the triphenyl phosphite, measured by inelastic neutron scattering, were obtained during isothermal aging at Ta=210, 213, and 216 K. The low-frequency ωn behavior of the vibrational density of states was observed to be time dependent. This is suggestive of an abortive crystallization process because the ω exponent has not reached the characteristic value of the crystalline state (n=2) at the end of the transformation. The confrontation of inelastic neutron scattering and Raman data in the low-frequency range reveals interesting information about the structural organization in the liquid, the glass, the undercooled liquid, and the glacial state, through the observation of the boson peak.

  1. Theoretical and Experimental Investigations of the Rotor Vibration Amplitude of the Turbocharger and Bearings Temperature

    Directory of Open Access Journals (Sweden)

    E. Zadorozhnaya

    2017-12-01

    Full Text Available One of the most urgent issues of the modern world and domestic automobile and tractor production is the problem of the production of efficient and reliable turbochargers. The rotor bearings largely determine the reliable operation of the turbocharger. By increasing the degree of the forcing of the engine the turbocharger rotor speed and the load increases significantly. Working conditions of bearings also complicated because of the temperature rise. In this case the bearing of the turbine and the compressor bearing works in different thermal conditions. The definition of the thermal state of the bearings can be performed experimentally. However, to perform these studies the sophisticated experimental equipment must be used. Researchers can't perform experiments for each type of turbocharger. Therefore, the applying of the theoretical approaches becomes more relevant. The peculiarity of the considered problem is the design of the bearings, which are made in the form of multilayer bearings with floating rings. Such designs increase the number of the parameters that affect the behaviour of the rotor. For the calculation of the multilayer bearings and turbocharger rotor dynamics a method and calculation algorithm was developed. A plan of the experiment based on the orthogonal central composite plan was drawn up. The regression equations for rotor amplitude and bearing temperature were obtained. As variable parameters the clearances (external and internal, rotor speed, pressure and lubricant temperature were used. The results of the calculation were compared with experimental results obtained at the plant. Non-Newtonian properties of the lubricants were taken into account in the calculations. Comparative results showed good agreement. In this way the resulting function can be applied to studies of the similarly multilayer bearings without complicated experimental studies.

  2. Capturing inhomogeneous broadening of the -CN stretch vibration in a Langmuir monolayer with high-resolution spectra and ultrafast vibrational dynamics in sum-frequency generation vibrational spectroscopy (SFG-VS)

    Energy Technology Data Exchange (ETDEWEB)

    Velarde Ruiz Esparza, Luis A.; Wang, Hongfei

    2013-08-28

    Even though in principle the frequency-domain and time-domain spectroscopic measurement should generate identical information for a given molecular system, inhomogeneous character of surface vibrations in the sum-frequency generation vibrational spectroscopy (SFG-VS) studies has only been studied with the time-domain SFGVS by mapping the decay of the vibrational polarization using ultrafast lasers, due to the lack of SFG vibrational spectra with high enough spectral resolution and accurate enough line shape. Here with recently developed high-resolution broadband SFG-VS (HR-BB-SFG-VS) we show that the inhomogeneous line shape can be obtained in the frequency-domain, for the anchoring CN stretch of the 4-n-octyl-4'-cyanobiphenyl (8CB) Langmuir monolayer at the air-water interface, and that an excellent agreement with the time-domain SFG free-induction-decay (FID) results can be established. We found that the 8CB CN stretch spectrum consists of a single peak centered at 2234.00 + * 0.01 cm-1 with a total line width of 10.9 + - 0.3 cm-1 at half maximum. The Lorentzian contribution accounts only for 4:7 + -0:4 cm-1 to this width and the Gaussian (inhomogeneous) broadening for as much as 8:1+*0:2 cm-1. Polarization analysis of the -CN spectra showed that the -CN group is tilted 57 + - 2 degrees from the surface normal. The large heterogeneity in the -CN spectrum is tentatively attributed to the -CN group interactions with the interfacial water molecules penetrated/accomodated into the 8CB monolayer, a unique phenomenon for the nCB Langmuir monolayers reported previously.

  3. Layer-number dependent high-frequency vibration modes in few-layer transition metal dichalcogenides induced by interlayer couplings

    Science.gov (United States)

    Tan, Qing-Hai; Zhang, Xin; Luo, Xiang-Dong; Zhang, Jun; Tan, Ping-Heng

    2017-03-01

    Two-dimensional transition metal dichalcogenides (TMDs) have attracted extensive attention due to their many novel properties. The atoms within each layer in two-dimensional TMDs are joined together by covalent bonds, while van der Waals interactions combine the layers together. This makes its lattice dynamics layer-number dependent. The evolutions of ultralow frequency ( 50 cm-1) vibration modes in few-layer TMDs and demonstrate how the interlayer coupling leads to the splitting of high-frequency vibration modes, known as Davydov splitting. Such Davydov splitting can be well described by a van der Waals model, which directly links the splitting with the interlayer coupling. Our review expands the understanding on the effect of interlayer coupling on the high-frequency vibration modes in TMDs and other two-dimensional materials. Project supported by the National Basic Research Program of China (No. 2016YFA0301200), the National Natural Science Foundation of China (Nos. 11225421, 11474277, 11434010, 61474067, 11604326, 11574305 and 51527901), and the National Young 1000 Talent Plan of China.

  4. Balancing Vibrations at Harmonic Frequencies by Injecting Harmonic Balancing Signals into the Armature of a Linear Motor/Alternator Coupled to a Stirling Machine

    Science.gov (United States)

    Holliday, Ezekiel S. (Inventor)

    2014-01-01

    Vibrations at harmonic frequencies are reduced by injecting harmonic balancing signals into the armature of a linear motor/alternator coupled to a Stirling machine. The vibrations are sensed to provide a signal representing the mechanical vibrations. A harmonic balancing signal is generated for selected harmonics of the operating frequency by processing the sensed vibration signal with adaptive filter algorithms of adaptive filters for each harmonic. Reference inputs for each harmonic are applied to the adaptive filter algorithms at the frequency of the selected harmonic. The harmonic balancing signals for all of the harmonics are summed with a principal control signal. The harmonic balancing signals modify the principal electrical drive voltage and drive the motor/alternator with a drive voltage component in opposition to the vibration at each harmonic.

  5. Atomization off thin water films generated by high-frequency substrate wave vibrations

    Science.gov (United States)

    Collins, David J.; Manor, Ofer; Winkler, Andreas; Schmidt, Hagen; Friend, James R.; Yeo, Leslie Y.

    2012-11-01

    Generating aerosol droplets via the atomization of thin aqueous films with high frequency surface acoustic waves (SAWs) offers several advantages over existing nebulization methods, particularly for pulmonary drug delivery, offering droplet sizes in the 1-5-μm range ideal for effective pulmonary therapy. Nevertheless, the physics underlying SAW atomization is not well understood, especially in the context of thin liquid film formation and spreading and how this affects the aerosol production. Here, we demonstrate that the film geometry, governed primarily by the applied power and frequency of the SAW, indeed plays a crucial role in the atomization process and, in particular, the size of the atomized droplets. In contrast to the continuous spreading of low surface energy liquids atop similar platforms, high surface energy liquids such as water, in the present case, are found to undergo transient spreading due to the SAW to form a quasisteady film whose height is determined by self-selection of the energy minimum state associated with the acoustic resonance in the film and whose length arises from a competition between acoustic streaming and capillary effects. This is elucidated from a fundamental model for the thin film spreading behavior under SAW excitation, from which we show good agreement between the experimentally measured and theoretically predicted droplet dimension, both of which consistently indicate a linear relationship between the droplet diameter and the mechanical power coupled into the liquid by the SAW (the latter captured by an acoustic Weber number to the two thirds power, and the reciprocal of the SAW frequency).

  6. Theoretical studies on the electronic structure, charge distribution and vibrational spectra of diglyme-M(+)-AsF(6)(-) (M=Li, Na, K).

    Science.gov (United States)

    Pinjari, Rahul V; Joshi, Kaustubh A; Gejji, Shridhar P

    2008-12-01

    Electronic structure and the vibrational spectra of CH(3)(OCH(2)CH(2))(2)OCH(3)-M(+)-AsF(6)(-) (M=Li, Na, K) have been obtained using the density functional theory. Lithium ion exhibits a pentavalent coordination via 3 oxygens from diglyme and two fluorines of AsF(6)(-) whereas Na(+) and K(+) exhibit coordinate number 6 with 3 fluorines of the anion binding to alkali metal in these complexes. Analysis of calculated spectra reveal that the CH(2) wag (840-1120 cm(-1)) vibrations in the complex are sensitive to metal ion coordination. A frequency downshift relative to the free anion has been predicted for the vibrations of AsF(6)(-) anion when the fluorines are directly bonded (denoted by F) to metal ion. Consequent reorganization of electron density in the complex engenders a frequency shift in the opposite direction for As-F vibrations wherein the fluorine atoms are not coordinating to the alkali metal ion. An approach based on the molecular electron density topography coupled with the difference electron density map explains the direction of the frequency shifts of C-O-C and the As-F stretchings compared to those of free diglyme or AsF(6) anion. A new method, which includes the color-mapping function for the difference molecular electron density (MED), superimposed on the bond critical points in MED topography has been suggested to explain the direction of the frequency shifts in a single attempt.

  7. Three-Dimensional Vibration Isolator for Suppressing High-Frequency Responses for Sage III Contamination Monitoring Package (CMP)

    Science.gov (United States)

    Li, Y.; Cutright, S.; Dyke, R.; Templeton, J.; Gasbarre, J.; Novak, F.

    2015-01-01

    The Stratospheric Aerosol and Gas Experiment (SAGE) III - International Space Station (ISS) instrument will be used to study ozone, providing global, long-term measurements of key components of the Earth's atmosphere for the continued health of Earth and its inhabitants. SAGE III is launched into orbit in an inverted configuration on SpaceX;s Falcon 9 launch vehicle. As one of its four supporting elements, a Contamination Monitoring Package (CMP) mounted to the top panel of the Interface Adapter Module (IAM) box experiences high-frequency response due to structural coupling between the two structures during the SpaceX launch. These vibrations, which were initially observed in the IAM Engineering Development Unit (EDU) test and later verified through finite element analysis (FEA) for the SpaceX launch loads, may damage the internal electronic cards and the Thermoelectric Quartz Crystal Microbalance (TQCM) sensors mounted on the CMP. Three-dimensional (3D) vibration isolators were required to be inserted between the CMP and IAM interface in order to attenuate the high frequency vibrations without resulting in any major changes to the existing system. Wire rope isolators were proposed as the isolation system between the CMP and IAM due to the low impact to design. Most 3D isolation systems are designed for compression and roll, therefore little dynamic data was available for using wire rope isolators in an inverted or tension configuration. From the isolator FEA and test results, it is shown that by using the 3D wire rope isolators, the CMP high-frequency responses have been suppressed by several orders of magnitude over a wide excitation frequency range. Consequently, the TQCM sensor responses are well below their qualification environments. It is indicated that these high-frequency responses due to the typical instrument structural coupling can be significantly suppressed by a vibration passive control using the 3D vibration isolator. Thermal and contamination

  8. Vibrational, structural and electronic properties investigation by DFT calculations and molecular docking studies with DNA topoisomerase II of strychnobrasiline type alkaloids: A theoretical approach for potentially bioactive molecules

    Science.gov (United States)

    Costa, Renyer A.; Oliveira, Kelson M. T.; Costa, Emmanoel Vilaça; Pinheiro, Maria L. B.

    2017-10-01

    A combined experimental and theoretical DFT study of the structural, vibrational and electronic properties of strychnobrasiline and 12-hydroxy-10,11-dimethoxystrychnobrasiline is presented using the Becke three-parameter Lee-Yang-Parr function (B3LYP) and 6-311G(2d,p) basis set. The theoretical geometry optimization data were compared with the X-ray data for a similar structure in the associated literature, showing close values. The calculated HOMO-LUMO gap values showed that the presence of substituents in the benzene ring influences the quantum properties which are directly related to the reactive properties. Theoretical UV spectra agreed well with the measured experimental data, with bands assigned. In addition, Natural Bond Orbitals (NBOs), Mapped molecular electrostatic potential surface (MEPS) and NLO calculations were also performed at the same theory level. The theoretical vibrational analysis revealed several characteristic vibrations that may be used as a diagnostic tool for other strychnobrasiline type alkaloids, simplifying their identification and structural characterization. Molecular docking calculations with DNA Topoisomerase II-DNA complex showed binding free energies values of -8.0 and -9.5 kcal/mol for strychnobrasiline and 12-hydroxy-10,11-dimethoxystrychnobrasiline respectively, while for amsacrine, used for the treatment of leukemia, the binding free energy ΔG presented a value of -10.0 kcal/mol, suggesting that strychnobrasiline derivative alkaloids might exhibit an antineoplastic activity.

  9. Vibrational sum‐frequency generation as a probe for composition, chemical reactivity, and film formation dynamics of the sea surface nanolayer

    National Research Council Canada - National Science Library

    Laβ, Kristian; Kleber, Joscha; Friedrichs, Gernot

    2010-01-01

    Vibrational Sum Frequency Generation (VSFG) is a surface sensitive nonlinear laser spectroscopic technique, which has been widely used in physics and physical chemistry to investigate interface processes and heterogeneous chemistry...

  10. Comparisons of the Structure of Water at Neat Oil/Water and Air/Water Interfaces as Determined by Vibrational Sum Frequency Generation

    National Research Council Canada - National Science Library

    Gragson, D

    1997-01-01

    We have employed vibrational sum frequency generation (VSFG) to investigate the structure of water at neat oil/water and air/water interfaces through the OH stretching modes of the interfacial water molecules...

  11. Coherent control of flexural vibrations in dual-nanoweb fibers using phase-modulated two-frequency light

    Science.gov (United States)

    Koehler, J. R.; Noskov, R. E.; Sukhorukov, A. A.; Novoa, D.; Russell, P. St. J.

    2017-12-01

    Coherent control of the resonant response in spatially extended optomechanical structures is complicated by the fact that the optical drive is affected by the backaction from the generated phonons. Here we report an approach to coherent control based on stimulated Raman-like scattering, in which the optical pressure can remain unaffected by the induced vibrations even in the regime of strong optomechanical interactions. We demonstrate experimentally coherent control of flexural vibrations simultaneously along the whole length of a dual-nanoweb fiber, by imprinting steps in the relative phase between the components of a two-frequency pump signal, the beat frequency being chosen to match a flexural resonance. Furthermore, sequential switching of the relative phase at time intervals shorter than the lifetime of the vibrations reduces their amplitude to a constant value that is fully adjustable by tuning the phase modulation depth and switching rate. The results may trigger new developments in silicon photonics, since such coherent control uniquely decouples the amplitude of optomechanical oscillations from power-dependent thermal effects and nonlinear optical loss.

  12. Optimization of linear zigzag insert metastructures for low-frequency vibration attenuation using genetic algorithms

    Science.gov (United States)

    Abdeljaber, Osama; Avci, Onur; Kiranyaz, Serkan; Inman, Daniel J.

    2017-02-01

    Vibration suppression remains a crucial issue in the design of structures and machines. Recent studies have shown that with the use of metamaterial inspired structures (or metastructures), considerable vibration attenuation can be achieved. Optimization of the internal geometry of metastructures maximizes the suppression performance. Zigzag inserts have been reported to be efficient for vibration attenuation. It has also been reported that the geometric parameters of the inserts affect the vibration suppression performance in a complex manner. In an attempt to find out the most efficient parameters, an optimization study has been conducted on the linear zigzag inserts and is presented here. The research reported in this paper aims at developing an automated method for determining the geometry of zigzag inserts through optimization. This genetic algorithm based optimization process searches for optimal zigzag designs which are properly tuned to suppress vibrations when inserted in a specific host structure (cantilever beam). The inserts adopted in this study consist of a cantilever zigzag structure with a mass attached to its unsupported tip. Numerical simulations are carried out to demonstrate the efficiency of the proposed zigzag optimization approach.

  13. Non-Gaussian statistics of amide I mode frequency fluctuation of N-methylacetamide in methanol solution: Linear and nonlinear vibrational spectra

    Science.gov (United States)

    Kwac, Kijeong; Lee, Hochan; Cho, Minhaeng

    2004-01-01

    By carrying out molecular dynamics simulations of an N-methylacetamide (NMA) in methanol solution, the amide I mode frequency fluctuation and hydrogen bonding dynamics were theoretically investigated. Combining an extrapolation formula developed from systematic ab initio calculation studies of NMA-(CH3OH)n clusters with a classical molecular dynamics simulation method, we were able to quantitatively describe the solvatochromic vibrational frequency shift induced by the hydrogen-bonding interaction between NMA and solvent methanol. It was found that the fluctuating amide I mode frequency distribution is notably non-Gaussian and it can be decomposed into two Gaussian peaks that are associated with two distinctively different solvation structures. The ensemble-average-calculated linear response function associated with the IR absorption is found to be oscillating, which is in turn related to the doublet amide I band shape. Numerically calculated infrared absorption spectra are directly compared with experiment and the agreement was found to be excellent. By using the Onsager's regression hypothesis, the rate constants of the interconversion process between the two solvation structures were obtained. Then, the nonlinear response functions associated with two-dimensional infrared pump-probe spectroscopy were simulated. The physics behind the two-dimensional line shape and origin of the cross peaks in the time-resolved pump-probe spectra is explained and the result is compared with 2D spectra experimentally measured recently by Woutersen et al. [S. Woutersen, Y. Mu, G. Stock, and P. Hamm, Chem. Phys. 266, 137 (2001)].

  14. Nonlinear vibration absorption for a flexible arm via a virtual vibration absorber

    Science.gov (United States)

    Bian, Yushu; Gao, Zhihui

    2017-07-01

    A semi-active vibration absorption method is put forward to attenuate nonlinear vibration of a flexible arm based on the internal resonance. To maintain the 2:1 internal resonance condition and the desirable damping characteristic, a virtual vibration absorber is suggested. It is mathematically equivalent to a vibration absorber but its frequency and damping coefficients can be readily adjusted by simple control algorithms, thereby replacing those hard-to-implement mechanical designs. Through theoretical analyses and numerical simulations, it is proven that the internal resonance can be successfully established for the flexible arm, and the vibrational energy of flexible arm can be transferred to and dissipated by the virtual vibration absorber. Finally, experimental results are presented to validate the theoretical predictions. Since the proposed method absorbs rather than suppresses vibrational energy of the primary system, it is more convenient to reduce strong vibration than conventional active vibration suppression methods based on smart material actuators with limited energy output. Furthermore, since it aims to establish an internal vibrational energy transfer channel from the primary system to the vibration absorber rather than directly respond to external excitations, it is especially applicable for attenuating nonlinear vibration excited by unpredictable excitations.

  15. Collective excitations in liquid DMSO : FIR spectrum, Low frequency vibrational density of states and ultrafast dipolar solvation dynamics

    CERN Document Server

    Hazra, Milan

    2016-01-01

    Valuable dynamical and structural information about neat liquid DMSO at ambient conditions can be obtained through study of low frequency vibrations in the far infrared (FIR), that is, terahertz regime. For DMSO, collective excitations as well as single molecule stretches and bends have been measured by different kinds of experiments such as OHD-RIKES and terahertz spectroscopy. In the present work we investigate the intermolecular vibrational spectrum of DMSO through three different computational techniques namely (i) the far-infra red spectrum obtained through Fourier transform of total dipole moment auto time correlation function, (ii) from Fourier transform of the translational and angular velocity time autocorrelation functions and a (iii) quenched normal mode analysis of the parent liquid at 300K. The three spectrum, although exhibit differences among each other, reveal similar features which are in good, semi-quantitative, agreement with experimental results. Study of participation ratio of the density...

  16. Experimental (FT-IR, NMR and UV) and theoretical (M06-2X and DFT) investigation, and frequency estimation analyses on (E)-3-(4-bromo-5-methylthiophen-2-yl)acrylonitrile.

    Science.gov (United States)

    Sert, Yusuf; Balakit, Asim A; Öztürk, Nuri; Ucun, Fatih; El-Hiti, Gamal A

    2014-10-15

    The spectroscopic properties of (E)-3-(4-bromo-5-methylthiophen-2-yl)acrylonitrile have been investigated by FT-IR, UV, (1)H and (13)C NMR techniques. The theoretical vibrational frequencies and optimized geometric parameters (bond lengths and angles) have been calculated using density functional theory (DFT/B3LYP: Becke, 3-parameter, Lee-Yang-Parr) and DFT/M06-2X (the highly parameterized, empirical exchange correlation function) quantum chemical methods with 6-311++G(d,p) basis set by Gaussian 03 software, for the first time. The assignments of the vibrational frequencies have been carried out by potential energy distribution (PED) analysis by using VEDA 4 software. The theoretical optimized geometric parameters and vibrational frequencies were in good agreement with the corresponding experimental data, and with the results in the literature. (1)H and (13)C NMR chemical shifts were calculated by using the gauge-invariant atomic orbital (GIAO) method. The electronic properties, such as excitation energies, oscillator strength wavelengths were performed by B3LYP methods. In addition, the highest occupied molecular orbital (HOMO) and the lowest unoccupied molecular orbital (LUMO) energies and the other related molecular energy values have been calculated and depicted. Copyright © 2014 Elsevier B.V. All rights reserved.

  17. Lateral vibration control of a flexible overcritical rotor via an active gas bearing – Theoretical and experimental comparisons

    DEFF Research Database (Denmark)

    Pierart Vásquez, Fabián Gonzalo; Santos, Ilmar

    2016-01-01

    The lack of damping of radial gas bearings leads to high vibration levels of a rotor supported by this type of bearing when crossing resonant areas. This is even more relevant for flexible rotors, as studied in this work. In order to reduce these high vibration levels, an active gas bearing is pr...

  18. Vibrational Spectroscopy of the CCl[subscript 4] v[subscript 1] Mode: Theoretical Prediction of Isotopic Effects

    Science.gov (United States)

    Gaynor, James D.; Wetterer, Anna M.; Cochran, Rea M.; Valente, Edward J.; Mayer, Steven G.

    2015-01-01

    Raman spectroscopy is a powerful experimental technique, yet it is often missing from the undergraduate physical chemistry laboratory curriculum. Tetrachloromethane (CCl[subscript 4]) is the ideal molecule for an introductory vibrational spectroscopy experiment and the symmetric stretch vibration contains fine structure due to isotopic variations…

  19. Determination of absolute configuration of an isopimarane-type diterpenoid by experimental and theoretical electronic circular dichroism and vibrational circular dichroism

    Science.gov (United States)

    Wang, Zhi-Qiang; Wu, Cheng-Jun; Wang, Zhen-Hui; Huang, Chao; Huang, Jian; Wang, Jin-Hui; Sun, Tie-Min

    2017-10-01

    In this study, the stereochemistry of a new isopimarane-type diterpenoid isolated from the Callicarpa macrophylla Vahl, Callicapene M3, was studied by experimental electronic circular dichroism and vibrational circular dichroism with the aid of TDDFT theoretical calculations. The good consistence between the experimental and simulated circular dichroism has clearly confirmed the absolute configuration of the title compound as (4S, 5S, 9S, 10S, 13S, 14S)-14α-hydroxy-7,15-isopimaradien-18-oic acid.

  20. Determination of vibration frequency depending on abrasive mass flow rate during abrasive water jet cutting

    Czech Academy of Sciences Publication Activity Database

    Hreha, P.; Radvanská, A.; Hloch, Sergej; Peržel, V.; Krolczyk, G.; Monková, K.

    2014-01-01

    Roč. 77, 1-4 (2014), s. 763-774 ISSN 0268-3768 Institutional support: RVO:68145535 Keywords : Abrasive water jet * Abrasive mass flow rate * Vibration Subject RIV: JQ - Machines ; Tools Impact factor: 1.458, year: 2014 http://link.springer.com/article/10.1007%2Fs00170-014-6497-9#page-1

  1. Vibration-induced displacement using high-frequency resonators and friction layers

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    1998-01-01

    A mathematical model is set up to quantify vibration-induced motions of a slider with an imbedded resonator. A simple approximate expression is presented for predicting average velocities of the slider, agreeing fairly well with numerical integration of the full equations of motion. The simple ex...

  2. Natural Frequencies and Modal Damping Ratios Identification of Civil Structures from Ambient Vibration Data

    Directory of Open Access Journals (Sweden)

    Minh-Nghi Ta

    2006-01-01

    Full Text Available Damping is a mechanism that dissipates vibration energy in dynamic systems and plays a key role in dynamic response prediction, vibration control as well as in structural health monitoring during service. In this paper a time domain and a time-scale domain approaches are used for damping estimation of engineering structures, using ambient response data only. The use of tests under ambient vibration is increasingly popular today because they allow to measure the structural response in service. In this paper we consider two engineering structures excited by ambient forces. The first structure is the 310 m tall TV tower recently constructed in the city of Nanjing in China. The second example concerns the Jinma cable-stayed bridge that connects Guangzhou and Zhaoqing in China. It is a single tower, double row cable-stayed bridge supported by 112 stay cables. Ambient vibration of each cable is carried out using accelerometers. From output data only, the modal parameter are extracted using a subspace method and the wavelet transform method.

  3. Effects of cations and cholesterol with sphingomyelin membranes investigated by high-resolution broadband sum frequency vibrational spectroscopy

    Science.gov (United States)

    Zhang, Zhen; Feng, Rong-juan; Li, Yi-yi; Liu, Ming-hua; Guo, Yuan

    2017-08-01

    Sphingomyelin(SM) is specifically enriched in the plasma membrane of mammalian cells. Its molecular structure is compose by N-acyl-Derythro-sphingosylphosphorylcholine. The function of the SM related to membrane signaling and protein trafficking are relied on the interactions of the SM, cations, cholesterol and proteins. In this report, the interaction of three different nature SMs, cations and cholesterol at air/aqueous interfaces studied by high-resolution broadband sum frequency vibrational spectroscopy, respectively. Our results shed lights on understanding the relationship between SMs monolayer, cholesterol and Cations.

  4. Properties of axial or torsional free-vibration frequency of rods

    Science.gov (United States)

    Segenreich, S. A.; Rizzi, P.

    1975-01-01

    The investigation reported shows that for a clamped rod with an odd number of degrees of freedom, the middle frequency is independent of any nonuniformity in the area distribution. The frequencies in the lower half of the spectrum of a rod are found to be conjugate to the frequencies in the upper half. In the case of a design modification which leaves a certain frequency in the lower half spectrum unchanged, the conjugate frequency in the upper half will also remain unchanged.

  5. Molecular orbital studies (hardness, chemical potential, electrophilicity, and first electron excitation), vibrational investigation and theoretical NBO analysis of 2-hydroxy-5-bromobenzaldehyde by density functional method

    Science.gov (United States)

    Nataraj, A.; Balachandran, V.; Karthick, T.

    2013-01-01

    In this work, the vibrational spectral analysis was carried out using Raman and infrared spectroscopy in the range 4000-400 cm-1 and 3500-100 cm-1, respectively, for the 2-hydroxy-5-bromobenzaldehyde (HBB). The experimental spectra were recorded in the solid phase. The fundamental vibrational frequencies and intensity of vibrational bands were evaluated using density functional theory (DFT) with the standard B3LYP/6-311G++(d,p) method and basis set. Normal co-ordinate calculations were performed with the DFT force field corrected by a recommended set of scaling factors yielding fairly good agreement between observed and calculated frequencies. Simulation of infrared and Raman spectra utilizing the results of these calculations led to excellent overall agreement with the observed spectral patterns. The complete assignments were performed on the basis of the potential energy distribution (PED) of the vibrational modes, calculated with scaled quantum mechanics (SQM) method. The optimized geometric parameters (bond lengths and bond angles) were compared with experimental values of related compound. The stability of the molecule arising from hyper conjugative interactions and the charge delocalization has been analyzed using natural bond orbital (NBO) analysis. The directly calculated ionization potential (IP), electron affinity (EA), electronegativity (χ), electrophilicity index (ω), hardness (η), chemical potential (μ), and first electron excitation (τ) are all correlated with the HOMO and LUMO energies with their molecular properties. These show that charge transfer occurs within the molecule. Furthermore, molecular electrostatic potential maps (MESP) of the molecule have been calculated.

  6. Theoretical and Numerical Experiences on a Test Rig for Active Vibration Control of Mechanical Systems with Moving Constraints

    Directory of Open Access Journals (Sweden)

    M. Rinchi

    2004-01-01

    Full Text Available Active control of vibrations in mechanical systems has recently benefited of the remarkable development of robust control techniques. These control techniques are able to guarantee performances in spite of unavoidable modeling errors. They have been successfully codified and implemented for vibrating structures whose uncertain parameters could be assumed to be time-invariant. Unfortunately a wide class of mechanical systems, such as machine tools with carriage motion realized by a ball-screw, are characterized by time varying modal parameters. The focus of this paper is on modeling and controlling the vibrations of such systems. A test rig for active vibration control is presented. An analytical model of the test rig is synthesized starting by design data. Through experimental modal analysis, parametric identification and updating procedures, the model has been refined and a control system has been synthesized.

  7. Development and experimental evaluation of theoretical models for ion cyclotron resonance frequency heating of tokamak plasmas

    Energy Technology Data Exchange (ETDEWEB)

    Mantsinen, M. [Helsinki Univ. of Technology, Espoo (Finland). Dept. of Technical Physics

    1999-06-01

    Heating with electromagnetic waves in the ion cyclotron range of frequencies (ICRF) is a well-established method for auxiliary heating of present-day tokamak plasmas and is envisaged as one of the main heating techniques for the International Thermonuclear Experimental Reactor (ITER) and future reactor plasmas. In order to predict the performance of ICRF heating in future machines, it is important to benchmark present theoretical modelling with experimental results on present tokamaks. This thesis reports on development and experimental evaluation of theoretical models for ICRF heating at the Joint European Torus (JET). Several ICRF physics effects and scenarios have been studied. Direct importance to the ITER is the theoretical analysis of ICRF heating experiments with deuterium-tritium (D-T) plasmas. These experiments clearly demonstrate the potential of ICRF heating for auxiliary heating of reactor plasmas. In particular, scenarios with potential for good bulk ion heating and enhanced D-T fusion reactivity have been identified. Good bulk ion heating is essential for reactor plasmas in order to obtain a high ion temperature and a high fusion reactivity. In JET good bulk ion heating with ICRF waves has been achieved in high-performance discharges by adding ICRF heating to neutral beam injection. In these experiments, as in other JET discharges where damping at higher harmonics of the ion cyclotron frequency takes place, so-called finite Larmor radius (FLR) effects play an important role. Due to FLR effects, the resonating ion velocity distribution function can have a strong influence on the power deposition. Evidence for this effect has been obtained from the third harmonic deuterium heating experiments. Because of FLR effects, the wave-particle interaction can also become weak at certain ion energies, which prevents resonating ions from reaching higher energies. When interacting with the wave, an ion receives not only a change in energy but also a change in

  8. The acute effects of local muscle vibration frequency on peak torque, rate of torque development, and EMG activity.

    Science.gov (United States)

    Pamukoff, Derek N; Ryan, Eric D; Blackburn, J Troy

    2014-12-01

    Vibratory stimuli enhance muscle activity and may be used for rehabilitation and performance enhancement. Efficacy of vibration varies with the frequency of stimulation, but the optimal frequency is unclear. The purpose of this study was to examine the effects of 30 Hz and 60 Hz local muscle vibration (LMV) on quadriceps function. Twenty healthy volunteers (age = 20.4 ± 1.4 years, mass = 68.1 ± 11.0 kg, height = 170.1 ± 8.8 cm, males = 9) participated. Isometric knee extensor peak torque (PT), rate of torque development (RTD), and electromyography (EMG) of the quadriceps were assessed followed by one of the three LMV treatments (30 Hz, 60 Hz, control) applied under voluntary contraction, and again immediately, 5, 15, and 30 min post-treatment in three counterbalanced sessions. Dependent variables were analyzed using condition by time repeated-measures ANOVA. The condition × time interaction was significant for EMG amplitude (p = 0.001), but not for PT (p=0.324) or RTD (p = 0.425). The increase in EMG amplitude following 30 Hz LMV was significantly greater than 60 Hz LMV and control. These findings suggest that 30 Hz LMV may elicit an improvement in quadriceps activation and could be used to treat quadriceps dysfunction resulting from knee pathologies. Copyright © 2014 Elsevier Ltd. All rights reserved.

  9. N-H stretching modes around 3300 wavenumber from peptide backbones observed by chiral sum frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Fu, Li; Wang, Zhuguang; Yan, Elsa C Y

    2014-09-01

    We present a detailed analysis of the molecular origin of the chiral sum frequency generation (SFG) signals of proteins and peptides at interfaces in the N-H stretching vibrational region. The N-H stretching can be a probe for investigating structural and functional properties of proteins, but remains technically difficult to analyze due to the overlapping with the O-H stretching of water molecules. Chiral SFG spectroscopy offers unique tools to study the N-H stretching from proteins at interfaces without interference from the water background. However, the molecular origin of the N-H stretching signals of proteins is still unclear. This work provides a justification of the origin of chiral N-H signals by analyzing the vibrational frequencies, examining chiral SFG theory, studying proton (hydrogen/deuterium) exchange kinetics, and performing optical control experiments. The results demonstrate that the chiral N-H stretching signals at ~3300 cm(-1) originate from the amide group of the protein backbones. This chiral N-H stretching signal offers an in situ, real-time, and background-free probe for interrogating the protein structures and dynamics at interfaces at the molecular level. © 2014 Wiley Periodicals, Inc.

  10. Collective excitations in liquid dimethyl sulfoxide (DMSO): FIR spectrum, low frequency vibrational density of states, and ultrafast dipolar solvation dynamics

    Science.gov (United States)

    Hazra, Milan K.; Bagchi, Biman

    2017-01-01

    Valuable dynamical and structural information about neat liquid DMSO at ambient conditions can be obtained through a study of low frequency vibrations in the far infrared (FIR), that is, terahertz regime. For DMSO, collective excitations as well as single molecule stretches and bends have been measured by different kinds of experiments such as OHD-RIKES and terahertz spectroscopy. In the present work, we investigate the intermolecular vibrational spectrum of DMSO through three different computational techniques namely (i) the far-infrared spectrum obtained through the Fourier transform of total dipole moment auto-time correlation function, (ii) from the Fourier transform of the translational and angular velocity time autocorrelation functions, and (iii) a quenched normal mode analysis of the parent liquid at 300 K. The three spectra, although exhibit differences among each other, reveal similar features which are in good, semi-quantitative, agreement with experimental results. The study of participation ratio of the density of states obtained from the normal mode analysis shows that the broad spectrum around 100 cm-1 involves collective oscillations of 300-400 molecules. Dipolar solvation dynamics exhibit ultrafast energy relaxation with an initial time constant around 157 fs which can be attributed to the coupling to the collective excitations. We compare the properties of DMSO with those of water vis-a-vis the existence of the low frequency collective modes. Last, we find that the collective excitation spectrum exhibits strong temperature dependence.

  11. Collective excitations in liquid dimethyl sulfoxide (DMSO): FIR spectrum, low frequency vibrational density of states, and ultrafast dipolar solvation dynamics.

    Science.gov (United States)

    Hazra, Milan K; Bagchi, Biman

    2017-01-14

    Valuable dynamical and structural information about neat liquid DMSO at ambient conditions can be obtained through a study of low frequency vibrations in the far infrared (FIR), that is, terahertz regime. For DMSO, collective excitations as well as single molecule stretches and bends have been measured by different kinds of experiments such as OHD-RIKES and terahertz spectroscopy. In the present work, we investigate the intermolecular vibrational spectrum of DMSO through three different computational techniques namely (i) the far-infrared spectrum obtained through the Fourier transform of total dipole moment auto-time correlation function, (ii) from the Fourier transform of the translational and angular velocity time autocorrelation functions, and (iii) a quenched normal mode analysis of the parent liquid at 300 K. The three spectra, although exhibit differences among each other, reveal similar features which are in good, semi-quantitative, agreement with experimental results. The study of participation ratio of the density of states obtained from the normal mode analysis shows that the broad spectrum around 100 cm -1 involves collective oscillations of 300-400 molecules. Dipolar solvation dynamics exhibit ultrafast energy relaxation with an initial time constant around 157 fs which can be attributed to the coupling to the collective excitations. We compare the properties of DMSO with those of water vis-a-vis the existence of the low frequency collective modes. Last, we find that the collective excitation spectrum exhibits strong temperature dependence.

  12. The Effects of Vibration Frequencies on Physical, Perceptual and Cognitive Performance

    Science.gov (United States)

    2006-10-01

    l’intégration d’un réseau multicouches de vétronique, dans lequel tous les systèmes pourront être accessibles sur chacun des postes de travail de l’équipe...fournir ainsi un environnement de travail suffisamment stable pour utiliser le réseau de vétronique. Une suspension active absorbe l’énergie dynamique...du sol , l’analyse, puis applique un signal d’énergie équivalent visant à compenser les aspérités du sol , ce qui permet d’amortir les vibrations lors

  13. Experimental and theoretical study of the vibrational spectra of oligoureas: helical versus β-sheet-type secondary structures.

    Science.gov (United States)

    Cavagnat, Dominique; Claudon, Paul; Fischer, Lucile; Guichard, Gilles; Desbat, Bernard

    2011-04-21

    Ab initio calculations of two oligoureas stabilized in helix and sheet organization have been performed. The hydrogen bond distances were found to be almost the same for both structures. The vibrational assignment of the two oligourea structures and the direction of the transition moment of each vibration have been determined. From these results, and using the experimental isotropic optical index determined for one oligourea, we have established the anisotropic infrared optical files for the two structures. Interestingly, most urea absorptions vibrate in only one principal direction. Also, the shift of the carbonyl band is weaker and inverse to what was reported for corresponding protein secondary structures. Finally, simulations of the Polarization Modulation Infrared Reflection Absorption Spectroscopy (PMIRRAS) and Attenuated Reflection Spectroscopy (ATR) infrared spectra demonstrate the possibility to determine the orientation of the oligoureas in thin or ultrathin films, even if in some cases it may be difficult to unambiguously assign their secondary structure.

  14. High frequency stimulation of cardiac myocytes: A theoretical and computational study

    Science.gov (United States)

    Weinberg, Seth H.

    2014-12-01

    High-frequency stimulation (HFS) has recently been identified as a novel approach for terminating life-threatening cardiac arrhythmias. HFS elevates myocyte membrane potential and blocks electrical conduction for the duration of the stimulus. However, low amplitude HFS can induce rapidly firing action potentials, which may reinitiate an arrhythmia. The cellular level mechanisms underlying HFS-induced electrical activity are not well understood. Using a multiscale method, we show that a minimal myocyte model qualitatively reproduces the influence of HFS on cardiac electrical activity. Theoretical analysis and simulations suggest that persistent activation and de-inactivation of ionic currents, in particular a fast inward window current, underlie HFS-induced action potentials and membrane potential elevation, providing hypotheses for future experiments. We derive analytical expressions to describe how HFS modifies ionic current amplitude and gating dynamics. We show how fast inward current parameters influence the parameter regimes for HFS-induced electrical activity, demonstrating how the efficacy of HFS as a therapy for terminating arrhythmias may depend on the presence of pathological conditions or pharmacological treatments. Finally, we demonstrate that HFS terminates cardiac arrhythmias in a one-dimensional ring of cardiac tissue. In this study, we demonstrate a novel approach to characterize the influence of HFS on ionic current gating dynamics, provide new insight into HFS of the myocardium, and suggest mechanisms underlying HFS-induced electrical activity.

  15. A frequency-domain multichannel optimal adaptive algorithm for active control of sound and vibration

    Science.gov (United States)

    Shen, Qun

    A frequency-domain multichannel optimal adaptive algorithm has been described in this paper. The domain multichannel optimal adaptive (FOMA) algorithm is an exact implementation of the multichannel optimal block adaptive (MOBA) algorithm in the frequency domain. It therefore converges to the same optimal solution with the same stability characteristics. The time-varying convergence factor was computed efficiently in the frequency domain to minimize a frequency-domain cost function at each step. The FMOA becomes efficient when the filter order is high. Different updating schemes, from block-by-block to sample-by-sample, can also be implemented with the proposed algorithm.

  16. The Influence of Amplitude- and Frequency-Dependent Stiffness of Rail Pads on the Random Vibration of a Vehicle-Track Coupled System

    Directory of Open Access Journals (Sweden)

    Kai Wei

    2016-01-01

    Full Text Available The nonlinear curves between the external static loads of Thermoplastic Polyurethane Elastomer (TPE rail pads and their compressive deformations were measured. A finite element model (FEM for a rail-fastener system was produced to determine the nonlinear compressive deformations of TPE rail pads and their nonlinear static stiffness under the static vehicle weight and the preload of rail fastener. Next, the vertical vehicle-track coupled model was employed to investigate the influence of the amplitude- and frequency-dependent stiffness of TPE rail pads on the vehicle-track random vibration. It is found that the static stiffness of TPE rail pads ranges from 19.1 to 37.9 kN/mm, apparently different from the classical secant stiffness of 26.7 kN/mm. Additionally, compared with the nonlinear amplitude- and frequency-dependent stiffness of rail pads, the classical secant stiffness would not only severely underestimate the random vibration acceleration levels of wheel-track coupled system at frequencies of 65–150 Hz but also alter the dominant frequency-distribution of vehicle wheel and steel rail. Considering that these frequencies of 65–150 Hz are the dominant frequencies of ground vibration accelerations caused by low-speed railway, the nonlinear amplitude- and frequency-dependent stiffness of rail pads should be taken into account in prediction of environment vibrations due to low-speed railway.

  17. Droplet impact on vibrating superhydrophobic surfaces

    Science.gov (United States)

    Weisensee, Patricia B.; Ma, Jingcheng; Shin, Young Hwan; Tian, Junjiao; Chang, Yujin; King, William P.; Miljkovic, Nenad

    2017-10-01

    Many unanswered questions remain pertaining to droplet dynamics during impact on vibrating surfaces. Using optical high-speed imaging, we investigate the impact dynamics of macroscopic water droplets (≈2.5 mm ) on rigid and elastic superhydrophobic surfaces vibrating at 60-320 Hz and amplitudes of 0.2-2.7 mm. Specifically, we study the influence of the frequency, amplitude, rigidity, and substrate phase at the moment of impact on the contact time of impacting droplets. We show that a critical impact phase exists at which the contact time transitions from a minimum to a maximum greater than the theoretical contact time on a rigid, nonvibrating superhydrophobic surface. For impact at phases higher than the critical phase, contact times decrease until reaching a minimum of half the theoretical contact time just before the critical phase. The frequency of oscillation determines the phase-dependent variability of droplet contact times at different impact phases: higher frequencies (> 120 Hz) show less contact time variability and have overall shorter contact times compared to lower frequencies (60-120 Hz). The amplitude of vibration has little direct effect on the contact time. Through semiempirical modeling and comparison to experiments, we show that phase-averaged contact times can increase or decrease relative to a nonvibrating substrate for low (100 Hz ) vibration frequencies, respectively. This study not only provides new insights into droplet impact physics on vibrating surfaces, but also develops guidelines for the rational design of surfaces to achieve controllable droplet wetting in applications utilizing vibration.

  18. A Group Theoretical and Quantum Chemical Study of Electronic Absorption and Fluorescence, Vibrational Spectra, and Conformations of Trimethine Cyanine Dye Molecules

    Directory of Open Access Journals (Sweden)

    Vita Solomko

    2016-01-01

    Full Text Available The energetic structures and conformations of trimethine cyanine dye molecules were investigated. For research, group theoretical and quantum chemical calculation methods were used. The theoretical group analysis of electronic and vibrational structure of molecules was carried out. Also, the energetic structures and conformations of the molecule of this dye were studied. Research shows that the investigated molecule may reside in three different conformational states, one of which is highly symmetric (symmetry C2v and the other two with low symmetry. The third conformer is characterized by lowering of binding energy of the electronic system by 0.23 eV, and the long-wavelength absorption band is shifted to lower energies. Also the group theoretical analysis of the trimethine cyanine molecule had allowed systematizing the vibrational and electronic quantum transitions and identifying the bands in the absorption spectra. It is shown that the excitation of the molecule in S1-state causes trans-cis-isomerization. The presence of the barrier of ~0.1 eV allows the fluorescence process to compete with isomerization process, but isomerization causes a decrease in the fluorescence quantum yield of the dye.

  19. Design, Simulation, and Optimization of a Frequency-Tunable Vibration Energy Harvester That Uses a Magnetorheological Elastomer

    Directory of Open Access Journals (Sweden)

    Wan Sun

    2015-01-01

    Full Text Available This study focuses on the design, simulation, and load power optimization for the development of a novel frequency-tunable electromagnetic vibrational energy harvester. The unique characteristic of a magnetorheological elastomer (MRE is utilized, that the shear modulus can be varied by changing the strength of an applied magnetic field. The electromagnetic energy harvester is fabricated, the external electric circuit is connected, and the performance is evaluated through a series of experiments. The resonant frequencies and the parasitic damping constant are measured experimentally for different tuning magnet gap distances, which validate the application of the MRE to the development of a frequency-tunable energy harvesting system. The harvested energy of the system is measured by the voltage across the load resistor. The maximum load power is attained by optimizing the external circuit connected to the coil system. The analysis results are presented for harvesting the maximum load power in terms of the coil parameters and external circuit resistance. The optimality of the load resistance is validated by comparing the analytical results with experimental results. The optimal load resistances under various resonance frequencies are also found for the design and composition of the optimal energy harvesting circuit of the energy harvester system.

  20. Use of vibrational spectroscopy to study protein and DNA structure, hydration, and binding of biomolecules: A combined theoretical and experimental approach

    Science.gov (United States)

    Jalkanen, K. J.; Jürgensen, V. Würtz; Claussen, A.; Rahim, A.; Jensen, G. M.; Wade, R. C.; Nardi, F.; Jung, C.; Degtyarenko, I. M.; Nieminen, R. M.; Herrmann, F.; Knapp-Mohammady, M.; Niehaus, T. A.; Frimand, K.; Suhai, S.

    We report on our work with vibrational absorption, vibrational circular dichroism, Raman scattering, Raman optical activity, and surface-enhanced Raman spectroscopy to study protein and DNA structure, hydration, and the binding of ligands, drugs, pesticides, or herbicides via a combined theoretical and experimental approach. The systems we have studied systematically are the amino acids (L-alanine, L-tryptophan, and L-histidine), peptides (N-4271 acetyl L-alanine N?-methyl amide, N-acetyl L-tryptophan N?-methyl amide, N-acetyl L-histidine N?-methyl amide, L-alanyl L-alanine, tri-L-serine, N-acetyl L-alanine L-proline L-tyrosine N?-methyl amide, Leu-enkephalin, cyclo-(gly-L-pro)3, N-acetyl (L-alanine)n N?-methyl amide), 3-methyl indole, and a variety of small molecules (dichlobenil and 2,6-dochlorobenzamide) of relevance to the protein systems under study. We have used molecular mechanics, the SCC-DFTB, SCC-DFTB+disp, RHF, MP2, and DFT methodologies for the modeling studies with the goal of interpreting the experimentally measured vibrational spectra for these molecules to the greatest extent possible and to use this combined approach to understand the structure, function, and electronic properties of these molecules in their various environments. The application of these spectroscopies to biophysical and environmental assays is expanding, and therefore a thorough understanding of the phenomenon from a rigorous theoretical basis is required. In addition, we give some exciting and new preliminary results which allow us to extend our methods to even larger and more complex systems. The work presented here is the current state of the art to this ever and fast changing field of theoretical spectroscopic interpretation and use of VA, VCD, Raman, ROA, EA, and ECD spectroscopies.

  1. Linear response properties required to simulate vibrational spectra of biomolecules in various media: (R)-phenyloxirane (A comparative theoretical and spectroscopic vibrational study)

    DEFF Research Database (Denmark)

    Jalkanen, Karl J.; Jürgensen, Vibeke Würtz; Degtyarenko, I.M.

    2005-01-01

    in understanding the photo induced chemical reactivity observed in many systems. This work is a continuation of our goal to interpret the results of experimental studies on the basis of theoretical results, which can help to understand the structure and function of proteins, other biomolecules and ligands...

  2. Low magnitude high frequency vibration promotes adipogenic differentiation of bone marrow stem cells via P38 MAPK signal.

    Directory of Open Access Journals (Sweden)

    Qian Zhao

    Full Text Available Low magnitude high frequency vibration (LMHFV has been mainly reported for its influence on the musculoskeletal system, particularly the bone tissue. In the bone structure, osteogenic activity is the main focus of study with regards to LMHFV. However, adipogenesis, another important mode of differentiation in the bone marrow cavity that might be affected by LMHFV, is much less researched. Furthermore, the molecular mechanism of how LMHFV influences adipogenesis still needs to be understood. Here, we tested the effect of LMHFV (0.3g, 40 Hz, amplitude: 50μm, 15min/d, on multipotent stem cells (MSCs, which are the common progenitors of osteogenic, chondrogenic, adipogenic and myogenic cells. It is previously shown that LMHFV promotes osteogenesis of MSCs. In this study, we further revealed its effect on adipo-differentiation of bone marrow stem cells (BMSCs and studied the underlying signaling pathway. We found that when treated with LMHFV, the cells showed a higher expression of PPARγ, C/EBPα, adiponectin and showed more oil droplets. After vibration, the protein expression of PPARγ increased, and the phosphorylation of p38 MAPK was enhanced. After treating cells with SB203580, a specific p38 inhibitor, both the protein level of PPARγ illustrated by immunofluorescent staining and the oil droplets number, were decreased. Altogether, this indicates that p38 MAPK is activated during adipogenesis of BMSCs, and this is promoted by LMHFV. Our results demonstrating that specific parameters of LMHFV promotes adipogenesis of MSCs and enhances osteogenesis, highlights an unbeneficial side effect of vibration therapy used for preventing obesity and osteoporosis.

  3. Characterization of the frequency and muscle responses of the lumbar and thoracic spines of seated volunteers during sinusoidal whole body vibration.

    Science.gov (United States)

    Baig, Hassam A; Dorman, Daniel B; Bulka, Ben A; Shivers, Bethany L; Chancey, Valeta C; Winkelstein, Beth A

    2014-10-01

    Whole body vibration has been postulated to contribute to the onset of back pain. However, little is known about the relationship between vibration exposure, the biomechanical response, and the physiological responses of the seated human. The aim of this study was to measure the frequency and corresponding muscle responses of seated male volunteers during whole body vibration exposures along the vertical and anteroposterior directions to define the transmissibility and associated muscle activation responses for relevant whole body vibration exposures. Seated human male volunteers underwent separate whole body vibration exposures in the vertical (Z-direction) and anteroposterior (X-direction) directions using sinusoidal sweeps ranging from 2 to 18 Hz, with a constant amplitude of 0.4 g. For each vibration exposure, the accelerations and displacements of the seat and lumbar and thoracic spines were recorded. In addition, muscle activity in the lumbar and thoracic spines was recorded using electromyography (EMG) and surface electrodes in the lumbar and thoracic region. Transmissibility was determined, and peak transmissibility, displacement, and muscle activity were compared in each of the lumbar and thoracic regions. The peak transmissibility for vertical vibrations occurred at 4 Hz for both the lumbar (1.55 ± 0.34) and thoracic (1.49 ± 0.21) regions. For X-directed seat vibrations, the transmissibility ratio in both spinal regions was highest at 2 Hz but never exceeded a value of 1. The peak muscle response in both spinal regions occurred at frequencies corresponding to the peak transmissibility, regardless of the direction of imposed seat vibration: 4 Hz for the Z-direction and 2-3 Hz for the X-direction. In both vibration directions, spinal displacements occurred primarily in the direction of seat vibration, with little off-axis motion. The occurrence of peak muscle responses at frequencies of peak transmissibility suggests that such

  4. Relationship of the vibrational frequency of the uranyl ion with the uranium electronegativity; Relacion de la frecuencia vibracional del ion uranilo con la electronegatividad del uranio

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez S, A.; Martinez Q, E

    1990-07-15

    It has been demonstrated that the vibrational asymmetric frequency of the uranyl ion, it experiences a consistent spectrochemical displacement with the variations of electronegativity of the uranium in their complexes. The values of the electronegativity of the uranium they were dear by means of calculations that it involves measures of those lengths of the connection uranium-oxygen, obtained by vibrational spectroscopy, effective nuclear charges and the Allred and Rochow equation. The results show the evidence of a natural order that relates to the vibrational frequency with the electronegativity of the uranium atom; settling down that if the electronegativity is graph against it bond length to the oxygen or to it frequency value, a simple relationship is obtained as a form to obtain clear responses in absence of complementary information. (Author)

  5. A Theoretical Framework for Association Studies in F2 Family Pools Using Allele Frequencies from Genotyping-By-Sequencing

    DEFF Research Database (Denmark)

    Janss, Luc L; Ashraf, Bilal H; Greve-Pedersen, Morten

    In Perennial ryegrass breeding, F2's derived from parental crosses are sown in plots and phenotypes and genotypes are obtained as single measurements for the whole F2 family pool. For genotypes this means that quantitative assays must be used to obtain allele frequencies. For this purpose...... a sequencing approach to obtain Single Nucleotide Polymorphisms (SNPs) frequencies is considered here. In this work we develop the theoretical framework to perform association studies using allele frequencies from such F2 family pools. We show that expected allele frequencies in the F2 families will have...... individuals. This effect is caused by extreme families (homozygote x homozygote) being less frequent than extreme (homozygote) individuals. We finally consider the effects of using sequencing to obtain allele frequencies, which will cause inaccuracy in the frequency estimate due to obtaining a limited number...

  6. A second, low-frequency mode of vibration in the intact mammalian cochlea

    Science.gov (United States)

    Lukashkin, Andrei N.; Russell, Ian J.

    2003-03-01

    The mammalian cochlea is a structure comprising a number of components connected by elastic elements. A mechanical system of this kind is expected to have multiple normal modes of oscillation and associated resonances. The guinea pig cochlear mechanics was probed using distortion components generated in the cochlea close to the place of overlap between two tones presented simultaneously. Otoacoustic emissions at frequencies of the distortion components were recorded in the ear canal. The phase behavior of the emissions reveals the presence of a nonlinear resonance at a frequency about a half octave below that of the high-frequency primary tone. The location of the resonance is level dependent and the resonance shifts to lower frequencies with increasing stimulus intensity. This resonance is thought to be associated with the tectorial membrane. The resonance tends to minimize input to the cochlear receptor cells at frequencies below the high-frequency primary and increases the dynamic load to the stereocilia of the receptor cells at the primary frequency when the tectorial membrane and reticular lamina move in counterphase.

  7. O modelo AM1 na previsão de frequências vibracionais The vibration frequencies predicted by the AM1 model

    Directory of Open Access Journals (Sweden)

    João Carlos Silva Ramos

    1999-09-01

    Full Text Available We analyse vibrational frequencies of 168 compounds with the AM1 model concerning its experimentally observed gaseous frequencies. Stretching of CH, NH, OH and CO bonds, its related bending frequencies, and the CC frame movements are the studied vibrations. The results show problems with the AM1 vibrational splittings. Often symmetric stretching frequencies, like in CH3, CH2 and NH3, appear switched with the corresponding antisymmetrical ones. Among the studied vibrations many stretchings are overestimated, while bendings oscillate around experimental values. Fluorine stretchings, NN, OO, CH, double and triples CC bonds and cyclic hydrocarbon breathing modes are always overestimated while torsions, umbrella modes and OH/SH stretching are, in average, underestimated. Graphical analysis show that compounds with the lowest molecular masses are the ones with the largest difference to the experimental values. From our results it is not possible to fit confortably the calculated frequencies by a simple linear relationship of the type, n(obs=a*n(AM1. Better aggreement is obtained when different curves are adjusted for the stretching and bending modes, and when a complete linear function is used. Among our studies the best obtained statistical results are for CH, NH and OH. The conclusions obtained in this work will improve the AM1 calculated frequencies leading to accurate results for these properties.

  8. Case study of system effects on high frequency vibration isolation in aircraft structure

    Science.gov (United States)

    Simmons, William E.; Marshall, Steven E.

    In an attempt to improve isolator selection criteria for use in commercial airplanes, a modeling technique was developed. This technique was used to map the vibrational energy transfer from a resiliently mounted electric motor-driven hydraulic pump (or ACMP) to its foundation, a keel beam in the main wheelwell of a large airplane. The system level parameters that strongly influence mount transmissibility were investigated. Using common elastomeric material properties model, predictions were found to compare favorably to measured transmissibility data. The present study discusses the modeling technique and test data comparison, Potential improvements in isolator performance are evaluated. Isolator properties are then identified whch, when combined with transmissibility data, would enhance the isolator selection process.

  9. Probing the structure and nano-scale mechanical properties of polymer surfaces with scanning force microscopy and sum frequency vibrational spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Gracias, David Hugo [Univ. of California, Berkeley, CA (United States)

    1999-05-01

    Scanning Force Microscopy (SFM) has been used to quantitatively measure the elastic modulus, friction and hardness of polymer surfaces with special emphasis on polyethylene and polypropylene. In the experiments, tips of different radii of curvature ranging from 20 nm to 1000 nm have been used and the high pressure applied by the SFM have been observed to affect the values obtained in the measurements. The contact of the SFM tip with the polymer surface is explained by fitting the experimental curves to theoretical predictions of contact mechanics. Sum Frequency Generation (SFG) Vibrational Spectroscopy has been used to measure vibrational spectra of polymer surfaces in the vibrational range of 2700 to 3100 cm-1. Strong correlations are established between surface chemistry and surface structure as probed by SFG and mechanical properties measured by SFM on the surfaces. In these studies segregation of low surface energy moieties, from the bulk of the polymer to the surface have been studied. It was found that surface segregation occurs in miscible polymer blends and a small concentration of surface active polymer can be used to totally modify the surface properties of the blend. A novel high vacuum SFM was built to do temperature dependent measurements of mechanical changes occurring at the surface of polypropylene during the glass transition of the polymer. Using this instrument the modulus and friction of polypropylene was measured in the range of room temperature to ˜-60°C. An increase in the ordering of the backbone of the polymer chains below the glass transition measured by SFG correlates well with the increase in modulus measured on the same surface with SFM. Friction measurements have been done on polyethylene with three different instruments by applying loads ranging from nN to sub newton i.e. over eight orders of magnitude. Pressure and contact area effects were observed to play a significant role in determining the frictional response of the polymer

  10. The effect of the training with the different combinations of frequency and peak-to-peak vibration displacement of whole-body vibration on the strength of knee flexors and extensors

    Directory of Open Access Journals (Sweden)

    M Stania

    2017-01-01

    Full Text Available Whole-body vibration training has become a popular method used in sports and physiotherapy. The study aimed to evaluate the effect of different vibration frequency and peak-to-peak displacement combinations on men knee flexors and extensors strength in isokinetic conditions. The sample consisted of 49 male subjects randomly allocated to seven comparative groups, six of which exercised on a vibration platform with parameters set individually for the groups. The experimental groups were exposed to vibrations 3 times a week for 4 weeks. The pre- and post- isokinetic strength tests, with the angular velocities of 240°/s and 30°/s, were recorded prior to and 2 days after the training. After 4 weeks of whole-body vibration training, a significant increase was noted regarding the mean values of peak torque, average peak torque and total work for knee flexors at high angular velocity in Groups I (60 Hz/ 4 mm and V (40 Hz/ 2 mm (p<0.05. The mean percentage values of post-training changes to study parameters suggest that the training had the most beneficial effect in Groups I (60 Hz/4 mm and IV (60 Hz/2 mm (p<0.05. Whole-body vibrations during static exercise beneficially affected knee flexor strength profile in young men at high angular velocity. The combinations of 60 Hz/4 mm seem to have the most advantageous effects on muscle strength parameters.

  11. Topology Optimization of Distributed Mass Dampers for Low-frequency Vibration Suppression

    DEFF Research Database (Denmark)

    Jensen, Jakob Søndergaard; Lazarov, Boyan Stefanov

    2007-01-01

    In this paper the method of topology optimization is used to find optimized parameter distributions for a multiple mass damper system with the purpose of minimizing the low-frequency steady-state response of a carrier structure. An effective density model that describes the steady-state effect...... of the dampers is derived based on a continuous approximation of the damper distribution. The dampers are optimized with respect to the point-wise distribution of mass ratio, natural frequency, and damping ratio....

  12. A Practical Method to Increase the Frequency Readability for Vibration Signals

    Directory of Open Access Journals (Sweden)

    Jean Loius Ntakpe

    2016-10-01

    Full Text Available Damage detection and nondestructive evaluation of mechanical and civil engineering structures are nowadays very important to assess the integrity and ensure the reliability of structures. Thus, frequency evaluation becomes a crucial issue, since this modal parameter is mainly used in structural integrity assessment. The herein presented study highligts the possibility of increasing the frequency readability by involving a simple and cost-effective method.

  13. Derivation of Theoretical Formulas of the Frequency Component Contained in the Overvoltage Related to Long EHV Cables

    DEFF Research Database (Denmark)

    Ohno, Teruo; Bak, Claus Leth; Ametani, Akihiro

    2012-01-01

    or frequency scans. In addition, the formulas could eliminate the necessity of building simulation models of some network components. In order to address this need, this paper derives theoretical formulas to find the dominant frequency in long cable energization overvoltages. The accuracy and practical......Recent studies of long extremely high-voltage (EHV) cables show the importance of performing temporary overvoltage analyses. As the switching of EHV cables can trigger temporary overvoltages, it is important to find the dominant frequency component contained in the switching overvoltages...

  14. Equilibrium structure and atomic vibrations of Nin clusters

    Science.gov (United States)

    Borisova, Svetlana D.; Rusina, Galina G.

    2017-12-01

    The equilibrium bond lengths and binding energy, second differences in energy and vibrational frequencies of free clusters Nin (2 ≤ n ≤ 20) were calculated with the use of the interaction potential obtained in the tight-binding approximation (TBA). The results show that the minimum vibration frequency plays a significant role in the evaluation of the dynamic stability of the clusters. A nonmonotonic dependence of the minimum vibration frequency of clusters on their size and the extreme values for the number of atoms in a cluster n = 4, 6, 13, and 19 are demonstrated. This result agrees with the theoretical and experimental data on stable structures of small metallic clusters.

  15. A Novel Tunable Multi-Frequency Hybrid Vibration Energy Harvester Using Piezoelectric and Electromagnetic Conversion Mechanisms

    Directory of Open Access Journals (Sweden)

    Zhenlong Xu

    2016-01-01

    Full Text Available This paper presents a novel tunable multi-frequency hybrid energy harvester (HEH. It consists of a piezoelectric energy harvester (PEH and an electromagnetic energy harvester (EMEH, which are coupled with magnetic interaction. An electromechanical coupling model was developed and numerically simulated. The effects of magnetic force, mass ratio, stiffness ratio, and mechanical damping ratios on the output power were investigated. A prototype was fabricated and characterized by experiments. The measured first peak power increases by 16.7% and 833.3% compared with that of the multi-frequency EMEH and the multi-frequency PEH, respectively. It is 2.36 times more than the combined output power of the linear PEH and linear EMEH at 22.6 Hz. The half-power bandwidth for the first peak power is also broadened. Numerical results agree well with the experimental data. It is indicated that magnetic interaction can tune the resonant frequencies. Both magnetic coupling configuration and hybrid conversion mechanism contribute to enhancing the output power and widening the operation bandwidth. The magnitude and direction of magnetic force have significant effects on the performance of the HEH. This proposed HEH is an effective approach to improve the generating performance of the micro-scale energy harvesting devices in low-frequency range.

  16. Model Predictive Vibration Control Efficient Constrained MPC Vibration Control for Lightly Damped Mechanical Structures

    CERN Document Server

    Takács, Gergely

    2012-01-01

    Real-time model predictive controller (MPC) implementation in active vibration control (AVC) is often rendered difficult by fast sampling speeds and extensive actuator-deformation asymmetry. If the control of lightly damped mechanical structures is assumed, the region of attraction containing the set of allowable initial conditions requires a large prediction horizon, making the already computationally demanding on-line process even more complex. Model Predictive Vibration Control provides insight into the predictive control of lightly damped vibrating structures by exploring computationally efficient algorithms which are capable of low frequency vibration control with guaranteed stability and constraint feasibility. In addition to a theoretical primer on active vibration damping and model predictive control, Model Predictive Vibration Control provides a guide through the necessary steps in understanding the founding ideas of predictive control applied in AVC such as: ·         the implementation of ...

  17. Impact of acoustic airflow on intrasinus drug deposition: New insights into the vibrating mode and the optimal acoustic frequency to enhance the delivery of nebulized antibiotic.

    Science.gov (United States)

    Leclerc, Lara; Merhie, Amira El; Navarro, Laurent; Prévôt, Nathalie; Durand, Marc; Pourchez, Jérémie

    2015-10-15

    We investigated the impact of vibrating acoustic airflow, the high frequency (f≥100 Hz) and the low frequency (f≤45 Hz) sound waves, on the enhancement of intrasinus drug deposition. (81m)Kr-gas ventilation study was performed in a plastinated human cast with and without the addition of vibrating acoustic airflow. Similarly, intrasinus drug deposition in a nasal replica using gentamicin as a marker was studied with and without the superposition of different modes of acoustic airflow. Ventilation experiments demonstrate that no sinus ventilation was observed without acoustic airflow although sinus ventilation occurred whatever the modes of acoustic airflow applied. Intrasinus drug deposition experiments showed that the high frequency acoustic airflow led to 4-fold increase in gentamicin deposition into the left maxillary sinus and to 2-fold deposition increase into the right maxillary sinus. Besides, the low frequency acoustic airflow demonstrated a significant increase of 4-fold and 2-fold in the right and left maxillary sinuses, respectively. We demonstrated the benefit of different modes of vibrating acoustic airflow for maxillary sinus ventilation and intrasinus drug deposition. The degree of gentamicin deposition varies as a function of frequency of the vibrating acoustic airflow and the geometry of the ostia. Copyright © 2015 Elsevier B.V. All rights reserved.

  18. Spatial hearing in Cope’s gray treefrog: II. Frequency-dependent directionality in the amplitude and phase of tympanum vibrations

    Science.gov (United States)

    Lee, Norman; Schrode, Katrina M.; Johns, Anastasia R.; Christensen-Dalsgaard, Jakob; Bee, Mark A.

    2014-01-01

    Anuran ears function as pressure difference receivers, and the amplitude and phase of tympanum vibrations are inherently directional, varying with sound incident angle. We quantified the nature of this directionality for Cope’s gray treefrog, Hyla chrysoscelis. We presented subjects with pure tones, advertisement calls, and frequency-modulated sweeps to examine the influence of frequency, signal level, lung inflation, and sex on ear directionality. Interaural differences in the amplitude of tympanum vibrations were 1–4 dB greater than sound pressure differences adjacent to the two tympana, while interaural differences in the phase of tympanum vibration were similar to or smaller than those in sound phase. Directionality in the amplitude and phase of tympanum vibration were highly dependent on sound frequency, and directionality in amplitude varied slightly with signal level. Directionality in the amplitude and phase of tone- and call-evoked responses did not differ between sexes. Lung inflation strongly affected tympanum directionality over a narrow frequency range that, in females, included call frequencies. This study provides a foundation for further work on the biomechanics and neural mechanisms of spatial hearing in H. chrysoscelis, and lends valuable perspective to behavioral studies on the use of spatial information by this species and other frogs. PMID:24504183

  19. Theoretical study of the dynamics and kinetics of the O + CS → CO + S chemical laser reaction, where CO shows a very high vibrational excitation.

    Science.gov (United States)

    Gamallo, Pablo; Francia, Rafael; Martínez, Rodrigo; Sayós, Ramón; González, Miguel

    2012-12-06

    The dynamics and kinetics of the O((3)P) + CS(X(1)Σ(+)) → CO(X(1)Σ(+)) + S((3)P) chemical laser reaction was studied theoretically in detail for the first time, as a function of collision energy (0.0388-2.0 eV) and rovibrational excitation of CS. This was made using the quasi-classical trajectory (QCT) method and employing the best ab initio analytical ground potential energy surface (1(3)A' PES) available. A broad set of properties was determined, including scalar and vector properties, and the reaction mode. The behaviors observed and the considerable formation of OCS collision complexes were interpreted from some characteristics of the PES (early barrier, shallow minimum in the exit channel, and high exoergicity (mainly channeled into CO vibration; up to ∼81% of the available energy)) and the kinematics. The QCT vibrational and rotational CO populations and the vector properties show a quite good agreement with experiments, but the QCT rate constants disagree. To better account for the kinetics, we performed CASPT2/aug-cc-pVTZ ab initio calculations on the stationary points along the minimum energy path of the ground and first excited (1(3)A'') PESs. The transition state theory, which can be satisfactorily applied here, leads to rate constants (100-2000 K) that are quite close to the measured ones, where comparison is possible (150-300 K). We expect that these results will encourage further theoretical and experimental developments.

  20. Using strong nonlinearity and high-frequency vibrations to control effective mechanical stiffness

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    2008-01-01

    High-frequency excitation (HFE) can be used to change the effective stiffness of an elastic structure, and related quanti-ties such as resonance frequencies, wave speed, buckling loads, and equilibrium states. There are basically two ways to do this: By using parametrical HFE (with or without non...... the method of direct separation of motions with results of a modified multiple scales ap-proach, valid also for strong nonlinearity, the stiffening ef-fect is predicted for a generic 1-dof system, and results are tested against numerical simulation and ((it is planned)) laboratory experiments....

  1. Theory of vibration protection

    CERN Document Server

    Karnovsky, Igor A

    2016-01-01

    This text is an advancement of the theory of vibration protection of mechanical systems with lumped and distributed parameters. The book offers various concepts and methods of solving vibration protection problems, discusses the advantages and disadvantages of different methods, and the fields of their effective applications. Fundamental approaches of vibration protection, which are considered in this book, are the passive, parametric and optimal active vibration protection. The passive vibration protection is based on vibration isolation, vibration damping and dynamic absorbers. Parametric vibration protection theory is based on the Shchipanov-Luzin invariance principle. Optimal active vibration protection theory is based on the Pontryagin principle and the Krein moment method. The book also contains special topics such as suppression of vibrations at the source of their occurrence and the harmful influence of vibrations on humans. Numerous examples, which illustrate the theoretical ideas of each chapter, ar...

  2. Linear- and nonlinear-electromyographic analysis of supracutaneous vibration stimuli of the forearm using diverse frequencies and considering skin physiological properties.

    Science.gov (United States)

    Ko, Chang-Yong; Chang, Yunhee; Kim, Sol-Bi; Kim, Shinki; Kim, Gyoosuk; Ryu, Jeicheong; Mun, Musung

    2014-01-01

    Numerous studies have reported the efficacy of vibration in sensory feedback or substitution devices for users of myoelectric hand prostheses. Although most myoelectric hand prostheses are presently manipulated by a surface electromyogram (sEMG), only a few studies have been conducted on the effect of vibration on an sEMG. This study aimed to determine whether vibration stimulation affects the linear and nonlinear properties of surface electromyography (sEMG) considering the skin properties. The vibration stimuli, with frequencies ranging from 37 to 258 Hz, were applied to the proximal part of the arms of the eight female and seven male subjects. The skinfold thickness, hardness, and vibration threshold at the stimuli loci were measured. The root mean square (rms) and fractal dimension (DF) of the sEMG were measured at a distance of 1 cm in the upward direction from the stimuli loci. Above 223 Hz there were no differences between the rms of the genders in between the vibration stimuli (p > 0.05). Moreover, no differences were observed between the DF of the genders for any frequency (p > 0.05). Above 149 Hz, there were correlations between the rms and the skin hardness in the females. Otherwise, no correlations were observed between the rms and DF and the skin properties in both genders for most of the frequencies (all p > 0.05). These results suggest that vibration stimuli affect the linear properties of the sEMG, but not the nonlinear properties.

  3. Analysis of the dominant vibration frequencies of rail bridges for structure-borne noise using a power flow method

    Science.gov (United States)

    Li, Q.; Wu, D. J.

    2013-09-01

    The use of concrete bridges in urban rail transit systems has raised many concerns regarding low-frequency (20-200 Hz) structure-borne noise due to the vibration of bridges when subjected to moving trains. Understanding the mechanism that determines the dominant frequencies of bridge vibrations is essential for both vibration and noise reduction. This paper presents a general procedure based on the force method to obtain the power flows within a coupled vehicle-track-bridge system, the point mobility of the system and the dynamic interaction forces connecting various components. The general coupling system consists of multi-rigid-bodies for the vehicles, infinite Euler beams representing the rails, two-dimensional or three-dimensional elements of the concrete bridges, and spring-dashpot pairs to model the wheel-rail contacts, the vehicle suspensions, the rail pads and the bridge bearings. The dynamic interaction of the coupled system is solved in the frequency domain by assuming the combined wheel-rail roughness moves forward relative to the stationary vehicles. The proposed procedure is first applied to a rail on discrete supports and then to a real urban rail transit U-shaped concrete bridge. The computed results show that the wheel-rail contact forces, the power flows to the rail/bridge subsystem and the accelerations of the bridge are primarily dominated by the contents around the natural frequency of a single wheel adhered to the elastically supported rail. If the ath node of the mth spring-dashpot pair and the bth node of the nth spring-dashpot pair are connected to the same rigid body, then δmnab(ω) can be expressed as δmnab(ω)=-{(}/{Mlω}, where Ml is the mass of the lth rigid body. If the ath node of the mth spring-dashpot pair and the bth node of the nth spring-dashpot pair are connected to the same infinite rail, δmnab(ω) can be expressed as [8] δmnab(ω)=-j{((e-je)}/{4EIk}, where xm and xn are the x-coordinates of the mth and nth spring

  4. Vibration isolation performance of an ultra-low frequency folded pendulum resonator

    Science.gov (United States)

    Liu, Jiangfeng; Ju, Li; Blair, David G.

    1997-02-01

    We present an analysis of the transfer function of a very low frequency folded pendulum resonator. It is shown that performance depends critically on centre of percussion tuning of the pendulum arms. Experimental measurements of the transfer function are shown to agree well with theory. The isolator achieves 90 dB isolation at 7 Hz.

  5. Design and fabrication of a PZT cantilever for low frequency vibration energy harvesting.

    Science.gov (United States)

    Kim, Moonkeun; Hwang, Beomseok; Min, Nam Ki; Jeong, Jaehwa; Kwon, Kwang-Ho; Park, Kang-Bak

    2011-07-01

    In this study, a PZT cantilever with a Si proof mass is designed and fabricated for a low frequency energy harvesting application. A mathematical model of a multi-layer composite beam was derived and applied in a parametric analysis of the piezoelectric cantilever. Finally, the dimensions of the cantilever were determined for the resonant frequency of the cantilever. Our cantilever design was based on MATLAB and ANSYS simulations. For this simulation, the proof mass volumes were varied from 0 to 0.5 mm3 and resonant frequencies were calculated from 833.5 Hz to 125.5 Hz, respectively. Based on simulation, we fabricated a device with beam dimensions of about 4.10 mm x 0.48 mm x 0.012 mm, and an integrated Si proof mass with dimensions of about 0.481 mm x 0.48 mm x 0.45 mm. The resonant frequency, maximum peak voltage, and highest average power of the cantilever device were 224.8 Hz, 4.8 mV, and 2.24 nW, respectively.

  6. Vibrational power flow and structural intensity: Measurements and limitations at low frequencies

    DEFF Research Database (Denmark)

    Ohlrich, Mogens

    1991-01-01

    The cross-spectral methods and their sensitivity to phase errors are investigated for the two and four-accelerometer arrays. From experiments on a beam structure it is attempted to verify the influence of phase errors and to determine the usable frequency ranges of the two methods. Measurements a...

  7. Using strong nonlinearity and high-frequency vibrations to control effective properties of discrete elastic waveguides

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel; Snaeland, Sveinn Orri

    2008-01-01

    The aim of this article is to investigate how highfrequency (HF) excitation, combined with strong nonlinear elastic material behavior, influences the effective material or structural properties for low-frequency excitation and wave propagation. The HF effects are demonstrated on discrete linear...

  8. Search for the Variation in (mp/me) Using Two Vibrational Transition Frequencies of Molecular Ions

    Science.gov (United States)

    Kajita, Masatoshi

    2017-12-01

    We propose a method to search for the variation in the proton-to-electron mass ratio μ = (mp/me) based on the precise measurement of Q(v') = [f(v') - f(2v')/2]/f(v'), where f(v') is the 16O2+ X2Π 1/2(v,J) = (0,1/2) \\to (v',1/2) transition frequency. Q(v') is proportional to μ-1/2, and it can be measured with an uncertainty of 10-18. This method is also applicable to other molecular transition frequencies (i) J = 0 → 0 or 1/2 → 1/2 transition, (ii) transition between stretched states, and (iii) the same sign for the light shift induced by the clock lasers in f(v') and f(2v').

  9. Random vibration of linear and nonlinear structural systems with singular matrices: A frequency domain approach

    Science.gov (United States)

    Kougioumtzoglou, I. A.; Fragkoulis, V. C.; Pantelous, A. A.; Pirrotta, A.

    2017-09-01

    A frequency domain methodology is developed for stochastic response determination of multi-degree-of-freedom (MDOF) linear and nonlinear structural systems with singular matrices. This system modeling can arise when a greater than the minimum number of coordinates/DOFs is utilized, and can be advantageous, for instance, in cases of complex multibody systems where the explicit formulation of the equations of motion can be a nontrivial task. In such cases, the introduction of additional/redundant DOFs can facilitate the formulation of the equations of motion in a less labor intensive manner. Specifically, relying on the generalized matrix inverse theory, a Moore-Penrose (M-P) based frequency response function (FRF) is determined for a linear structural system with singular matrices. Next, relying on the M-P FRF a spectral input-output (excitation-response) relationship is derived in the frequency domain for determining the linear system response power spectrum. Further, the above methodology is extended via statistical linearization to account for nonlinear systems. This leads to an iterative determination of the system response mean vector and covariance matrix. Furthermore, to account for singular matrices, the generalization of a widely utilized formula that facilitates the application of statistical linearization is proved as well. The formula relates to the expectation of the derivatives of the system nonlinear function and is based on a Gaussian response assumption. Several linear and nonlinear MDOF structural systems with singular matrices are considered as numerical examples for demonstrating the validity and applicability of the developed frequency domain methodology.

  10. The Investigations of Friction under Die Surface Vibration in Cold Forging Process

    DEFF Research Database (Denmark)

    Jinming, Sha

    The objective of this thesis is to fundamentally study the influence of die surface vibration on friction under low frequency in metal forging processes. The research includes vibrating tool system design for metal forming, theoretical and experimental investigations, and finite element simulations...... on die surface vibration in forging process. After a general introduction to friction mechanisms and friction test techniques in metal forming, the application of ultrasonic vibration in metal forming, the influence of sliding velocity on friction is described. Some earlier investigations...... is undergoing vibration. In the experiments, die surface orientation, frequency and amplitude of vibration, vibrating wave form and the direction of vibration has been taken into account as the parameters which influence friction behaviour in forging process. The results reveal that friction could be reduced up...

  11. Forced Vibrations of a Cantilever Beam

    Science.gov (United States)

    Repetto, C. E.; Roatta, A.; Welti, R. J.

    2012-01-01

    The theoretical and experimental solutions for vibrations of a vertical-oriented, prismatic, thin cantilever beam are studied. The beam orientation is "downwards", i.e. the clamped end is above the free end, and it is subjected to a transverse movement at a selected frequency. Both the behaviour of the device driver and the beam's weak-damping…

  12. High Energy Vibration for Gas Piping

    Science.gov (United States)

    Lee, Gary Y. H.; Chan, K. B.; Lee, Aylwin Y. S.; Jia, ShengXiang

    2017-07-01

    In September 2016, a gas compressor in offshore Sarawak has its rotor changed out. Prior to this change-out, pipe vibration study was carried-out by the project team to evaluate any potential high energy pipe vibration problems at the compressor’s existing relief valve downstream pipes due to process condition changes after rotor change out. This paper covers high frequency acoustic excitation (HFAE) vibration also known as acoustic induced vibration (AIV) study and discusses detailed methodologies as a companion to the Energy Institute Guidelines for the avoidance of vibration induced fatigue failure, which is a common industry practice to assess and mitigate for AIV induced fatigue failure. Such detailed theoretical studies can help to minimize or totally avoid physical pipe modification, leading to reduce offshore plant shutdown days to plant shutdowns only being required to accommodate gas compressor upgrades, reducing cost without compromising process safety.

  13. Calculated vibrational frequencies for FeMo-co, the active site of nitrogenase, bearing hydrogen atoms and carbon monoxide.

    Science.gov (United States)

    Dance, Ian

    2011-06-28

    The intramolecular hydrogenation paradigm for the reducing actions of the enzyme nitrogenase postulates that the iron-molybdenum cofactor (FeMo-co, Fe(7)MoS(9)N(homocitrate)) as active site contains H atoms bound to Fe and S during the catalytic cycle, and that these H atoms are the reducing agents. The reduction of N(2) and of all other non-physiological substrates is strongly inhibited by carbon monoxide, except for the formation of H(2) from protons. It has been recently reported that vanadium nitrogenase and modified molybdenum nitrogenase reduce CO to hydrocarbons. Therefore many questions now arise about relationships between CO and H on the nitrogenase cofactors. In order to assist the interpretation of kinetic infrared spectral data, vibrational frequencies and modes have been calculated for a variety of possible structures in which FeMo-co bears H atoms, or CO ligands, or both. Fe-H stretching frequencies occur in the same spectral window as the C-O stretching frequencies, with lesser intensity, and both stretches are strongly coupled in some structures. Symmetrical bridging of CO between two Fe atoms of FeMo-co is destabilised by the presence of other ligands on Fe, and the reason for this is evident. Two results for bound formyl, HCO, are reported. These calculations of reference structures allow some interpretation of existing experimental spectra, but, more significantly, they suggest further kinetic infrared experiments to elucidate the chemical mechanism of catalysis by nitrogenase under normal turnover conditions. This journal is © The Royal Society of Chemistry 2011

  14. Palladium(II) and platinum(II) complexes containing benzimidazole ligands: Molecular structures, vibrational frequencies and cytotoxicity

    Science.gov (United States)

    Abdel Ghani, Nour T.; Mansour, Ahmed M.

    2011-04-01

    (1H-benzimidazol-2-ylmethyl)-(4-methoxyl-phenyl)-amine (L 1), (1H-benzimidazol-2-ylmethyl)-(4-methyl-phenyl)-amine (L 2) and their Pd(II) and Pt(II) complexes have been synthesized as potential anticancer compounds and their structures were elucidated using a variety of physico-chemical techniques. Theoretical calculations invoking geometry optimization, vibrational assignments, 1H NMR, charge distribution and molecular orbital description HOMO and LUMO were done using density functional theory. Natural bond orbital analysis (NBO) method was performed to provide details about the type of hybridization and the nature of bonding in the studied complexes. Strong coordination bonds (LP(1)N11 → σ *(M sbnd Cl22)) and (LP(1)N21 → σ *(M sbnd Cl23)) (M = Pd or Pt) result from donation of electron density from a lone pair orbital on the nitrogen atoms to the acceptor metal molecular orbitals. The experimental results and the calculated molecular parameters revealed square-planar geometries around the metallic centre through the pyridine-type nitrogen of the benzimidazole ring and secondary amino group and two chlorine atoms. The activation thermodynamic parameters were calculated using non-isothermal methods. The synthesized ligands, in comparison to their metal complexes were screened for their antibacterial activity. In addition, the studied complexes showed activity against three cell lines of different origin, breast cancer (MCF-7), Colon Carcinoma (HCT) and human heptacellular carcinoma (Hep-G2) comparable to cis-platin.

  15. Stochastic resonance energy harvesting for a rotating shaft subject to random and periodic vibrations: influence of potential function asymmetry and frequency sweep

    Science.gov (United States)

    Kim, Hongjip; Che Tai, Wei; Zhou, Shengxi; Zuo, Lei

    2017-11-01

    Stochastic resonance is referred to as a physical phenomenon that is manifest in nonlinear systems whereby a weak periodic signal can be significantly amplified with the aid of inherent noise or vice versa. In this paper, stochastic resonance is considered to harvest energy from two typical vibrations in rotating shafts: random whirl vibration and periodic stick-slip vibration. Stick-slip vibrations impose a constant offset in centrifugal force and distort the potential function of the harvester, leading to potential function asymmetry. A numerical analysis based on a finite element method was conducted to investigate stochastic resonance with potential function asymmetry. Simulation results revealed that a harvester with symmetric potential function generates seven times higher power than that with asymmetric potential function. Furthermore, a frequency-sweep analysis also showed that stochastic resonance has hysteretic behavior, resulting in frequency difference between up-sweep and down-sweep excitations. An electromagnetic energy harvesting system was constructed to experimentally verify the numerical analysis. In contrast to traditional stochastic resonance harvesters, the proposed harvester uses magnetic force to compensate the offset in the centrifugal force. System identification was performed to obtain the parameters needed in the numerical analysis. With the identified parameters, the numerical simulations showed good agreement with the experiment results with around 10% error, which verified the effect of potential function asymmetry and frequency sweep excitation condition on stochastic resonance. Finally, attributed to compensating the centrifugal force offset, the proposed harvester generated nearly three times more open-circuit output voltage than its traditional counterpart.

  16. Vibration and acoustic frequency spectra for industrial process modeling using selective fusion multi-condition samples and multi-source features

    Science.gov (United States)

    Tang, Jian; Qiao, Junfei; Wu, ZhiWei; Chai, Tianyou; Zhang, Jian; Yu, Wen

    2018-01-01

    Frequency spectral data of mechanical vibration and acoustic signals relate to difficult-to-measure production quality and quantity parameters of complex industrial processes. A selective ensemble (SEN) algorithm can be used to build a soft sensor model of these process parameters by fusing valued information selectively from different perspectives. However, a combination of several optimized ensemble sub-models with SEN cannot guarantee the best prediction model. In this study, we use several techniques to construct mechanical vibration and acoustic frequency spectra of a data-driven industrial process parameter model based on selective fusion multi-condition samples and multi-source features. Multi-layer SEN (MLSEN) strategy is used to simulate the domain expert cognitive process. Genetic algorithm and kernel partial least squares are used to construct the inside-layer SEN sub-model based on each mechanical vibration and acoustic frequency spectral feature subset. Branch-and-bound and adaptive weighted fusion algorithms are integrated to select and combine outputs of the inside-layer SEN sub-models. Then, the outside-layer SEN is constructed. Thus, ;sub-sampling training examples;-based and ;manipulating input features;-based ensemble construction methods are integrated, thereby realizing the selective information fusion process based on multi-condition history samples and multi-source input features. This novel approach is applied to a laboratory-scale ball mill grinding process. A comparison with other methods indicates that the proposed MLSEN approach effectively models mechanical vibration and acoustic signals.

  17. A Theoretical Estimate for the Frequency of the TNL Oscillator x + x + x^1/3=0

    Science.gov (United States)

    Wilkenson, Dorian; Mickens, Ronald

    2008-10-01

    Truly nonlinear (TNL) oscillators have the property of having no linear approximation at the fixed-point of the modeling differential equation [1]. For a conservative oscillator this means that the fixed-point is a nonlinear center. Another feature of TNL oscillators is that none of the standard perturbation expansion procedures can be applied to calculate analytical approximations to the periodic or oscillator solutions [2]. Using the initial conditions x(0)=A and x(0)=0, we calculate the frequency φ(A) of the equation given in the title for small, 0Journal of Sound and Vibration 292 (2006), 964-968. [0pt] [2] R. E. Mickens, ``Nonlinear Oscillations" (Cambridge University Press, New York, 1981).

  18. Influence of surface micro-beams with large deflection on the resonance frequency of a quartz crystal resonator in thickness-shear mode vibrations

    Directory of Open Access Journals (Sweden)

    Chi Luo

    2017-03-01

    Full Text Available We study the dynamic behavior of a quartz crystal resonator (QCR in thickness-shear vibrations with the upper surface covered by an array of micro-beams (MBs under large deflection. Through taking into account the continuous conditions of shear force and bending moment at the interface of MBs/resonator, dependences of frequency shift of the compound QCR system versus material parameter and geometrical parameter are illustrated in detail for nonlinear and linear vibrations. It is found that the frequency shift produces a little right (left translation for increasing elastic modulus (length/radius ratio of MBs. Moreover, the frequency right (left translation distance caused by nonlinear deformation becomes more serious in the second-order mode than in the first-order one.

  19. Structure and vibrations of 2-fluoro-N-methylaniline in the S0, S1 and D0 states: REMPI and MATI spectroscopy and theoretical calculations

    Science.gov (United States)

    Liu, Sheng; Dai, Wenshuai; Zhang, Lijuan; Cheng, Min; Du, Yikui; Zhu, Qihe

    2017-10-01

    Theoretical calculations predicted that there are only two stable conformers, trans and cis, for 2-fluoro-N-methylaniline (2FNMA) in the S0, S1 and D0 states. Compared to the cis conformer, the trans one is more stable, and has a population more than 99% at room temperature. The optimized molecular skeleton of trans and cis 2FNMA are both non-planar in the S0 state, but planar in the S1 and D0 states. The one-dimensional potential energy surface of 2FNMA in the S0 state is obtained. The Resonance-enhanced two-photon ionization (R2PI) and Mass-analyzed threshold ionization (MATI) spectra of trans 2FNMA are obtained. The first electronic excitation energy (E1) and the adiabatic ionization energy (IE) of trans 2FNMA are determined. The substitution effect on the molecular structures, transition energies and vibrations of 2FNMA are discussed.

  20. Bistability and low-frequency fluctuations in semiconductor lasers with optical feedback: a theoretical analysis

    DEFF Research Database (Denmark)

    Mørk, Jesper; Tromborg, Bjarne; Christiansen, Peter Leth

    1988-01-01

    Near-threshold operation of a semiconductor laser exposed to moderate optical feedback may lead to low-frequency fluctuations. In the same region, a kink is observed in the light-current characteristic. Here it is demonstrated that these nonlinear phenomena are predicted by a noise driven multimode...... traveling-wave model. The dynamics of the low-frequency fluctuations are explained qualitatively in terms of bistability through an iterative description...

  1. Determination of competitive adsorption isotherms applying the nonlinear frequency response method. Part I. Theoretical analysis.

    Science.gov (United States)

    Ilić, Milica; Petkovska, Menka; Seidel-Morgenstern, Andreas

    2009-08-14

    In this work adsorption equilibria of binary mixtures are quantified analyzing the nonlinear frequency response of a chromatographic column. Local partial derivatives of an isotherm model can be estimated for certain steady-states from the low frequency asymptotes of the corresponding frequency response functions (FRFs). The required FRFs correspond to two different compounds and the type of the imposed inlet concentration changes, e.g. periodical inlet concentration changes of only one compound or of both of them. For an accurate determination of isotherm parameters, it is necessary to approach as close as possible the low frequency asymptotic behaviour of these functions. Based on principles valid for the FRFs corresponding to the adsorption of a single solute, frequencies needed to reach the low frequency asymptotes of the functions of interest for estimating competitive isotherms are defined in this paper. The relation between the accuracy of the isotherm parameters determined and numbers and types of periodical inlet concentration changes and steady-states analyzed is also evaluated.

  2. Multimodal Broadband Vibrational Sum Frequency Generation (MM-BB-V-SFG) Spectrometer and Microscope.

    Science.gov (United States)

    Lee, Christopher M; Kafle, Kabindra; Huang, Shixin; Kim, Seong H

    2016-01-14

    A broadband sum frequency generation (BB-SFG) spectrometer with multimodal (MM) capabilities was constructed, which could be routinely reconfigured for tabletop experiments in reflection, transmission, and total internal reflection (TIR) geometries, as well as microscopic imaging. The system was constructed using a Ti:sapphire amplifier (800 nm, pulse width = 85 fs, repetition rate = 2 kHz), an optical parameter amplification (OPA) system for production of broadband IR pulses tunable between 1000 and 4000 cm(-1), and two Fabry-Pérot etalons arranged in series for production of narrowband 800 nm pulses. The key feature allowing the MM operation was the nearly collinear alignment of the visible (fixed, 800 nm) and infrared (tunable, 1000-4000 cm(-1)) pulses which were spatially separated. Physical insights discussed in this paper include the comparison of spectral bandwidth produced with 40 and 85 fs pump beams, the improvement of spectral resolution using etalons, the SFG probe volume in bulk analysis, the normalization of SFG signals, the stitching of multiple spectral segments, and the operation in different modes for air/liquid and adsorbate/solid interfaces, bulk samples, as well as spectral imaging combined with principle component analysis (PCA). The SFG spectral features obtained with the MM-BB-SFG system were compared with those obtained with picosecond-scanning-SFG system and high-resolution BB-SFG system (HR-BB-SFG) for dimethyl sulfoxide, α-pinene, and various samples containing cellulose (purified commercial products, Cladophora cell wall, cotton and flax fibers, and onion epidermis cell wall).

  3. A theoretical study on directivity control of multiple-loudspeaker system with a quadrupole radiation pattern in low frequency range

    Science.gov (United States)

    Irwansyah, Kuse, Naoyuki; Usagawa, Tsuyoshi

    2017-08-01

    Directivity pattern of an ordinary loudspeaker becomes more directive at higher frequencies. However, because a single loudspeaker tends to radiate uniformly in all directions at low frequencies, reverberation from surrounding building walls may affect speech intelligibility when installing a multiple-loudspeaker system at crossroads. As an alternative, a sharply directive sound source is recommended to be used, but in many cases the directivity of an ordinary loudspeaker is less sharp at lower frequencies. Therefore, in order to overcome such a limitation, this paper discusses the possibility of using four loudspeakers under active control to realize a quadrupole radiation pattern in low frequency range. In this study, the radiation pattern of a primary loudspeaker and three secondary loudspeakers has been modelled. By placing the loudspeakers close together in the direction of 0°, 90°, 180°, and 270°, it was theoretically demonstrated that a quadrupole radiation pattern can be shaped in the target frequency range up to 600 Hz by simply controlling the directivity in three of four directions which are 45°, 135°, 225°, and 315°. Although, the radiation pattern model is far from realistic configurations and conditions, it is possible to realize a quadrupole radiation pattern in the low frequency range.

  4. Analysis of algorithms for detection of resonance frequencies in vibration measurements on super heater tubes; Analys av algoritmer foer detektering av resonansfrekvenser i vibrationsmaetningar paa oeverhettartuber

    Energy Technology Data Exchange (ETDEWEB)

    Eriksson, Daniel

    2010-07-01

    Combustion of fuel in thermal power plants emits particles which creates coatings on the super heater tubes. The coatings isolate the tubes and impairs the efficiency of the heat transfer. Cleaning the tubes occurs while the power plant is running but without any knowledge of the actual coating. A change in frequency corresponds to a change in mass of the coatings. This thesis has been focusing in estimating resonance frequencies in vibration measurements made by strain gauges on the tubes. To improve the estimations a target tracking algorithm had been added. The results indicates that it is possible to estimate the resonance frequencies but the algorithms need to be verified on more signals.

  5. Quasi-optical coherence vibration tomography technique for damage detection in beam-like structures based on auxiliary mass induced frequency shift

    Science.gov (United States)

    Zhong, Shuncong; Zhong, Jianfeng; Zhang, Qiukun; Maia, Nuno

    2017-09-01

    A novel quasi-optical coherence vibration tomography (Quasi-OCVT) measurement system suitable for structural damage detection is proposed by taking the concept of two-dimensional optical coherence vibration tomography (2D-OCVT) technique. An artificial quasi-interferogram fringe pattern (QIFP) similar to the interferogram of 2D-OCVT system, as a sensor, was pasted on the surface of a vibrating structure. Image sequences of QIFP were captured by a high-speed camera that worked as a detector. The period density of the imaged QIFP changed due to the structural vibration, from which the vibration information of the structure could be obtained. Noise influence on the measurement accuracy, torsional sensitivity and optical distortion effect of the Quasi-OCVT system were investigated. The efficiency and reliability of the proposed method were demonstrated by applying the system to damage detection of a cracked beam-like structure with a roving auxiliary mass. The roving of the mass along the cracked beam brings about the change of natural frequencies that could be obtained by the Quasi-OCVT technique. Therefore, frequency-shift curves can be achieved and these curves provide additional spatial information for structural damage detection. Same cases were also analyzed by the finite element method (FEM) and conventional accelerometer-based measurement method. Comparisons were carried out among these results. Results obtained by the proposed Quasi-OCVT method had a good agreement with the ones obtained by FEM, from which the damage could be directly detected. However, the results obtained by conventional accelerometer showed misleading ambiguous peaks at damage position owing to the mass effect on the structure, where the damage location cannot be identified confidently without further confirmation. The good performance of the cost-effective Quasi-OCVT method makes it attractive for vibration measurement and damage detection of beam-like structures.

  6. Best Fit and Selection of Theoretical Flood Frequency Distributions Based on Different Runoff Generation Mechanisms

    Directory of Open Access Journals (Sweden)

    Vito Iacobellis

    2010-05-01

    Full Text Available Theoretically derived distributions allow the detection of dominant runoff generation mechanisms as key signatures of hydrologic similarity. We used two theoretically derived distributions of flood peak annual maxima: the first is the “IF” distribution, which exploits the variable source area concept, coupled with a runoff threshold having scaling properties; the second is the Two Component-IF (TCIF distribution, which generalizes the IF distribution, and is based on two different threshold mechanisms, associated with ordinary and extraordinary events, respectively. By focusing on the application of both models to two river basins, of sub-humid and semi-arid climate in Southern Italy, we present an ad hoc procedure for the estimation of parameters and we discuss the use of appropriate techniques for model selection, in the case of nested distributions.

  7. Intermolecular vibrational modes and H-bond interactions in crystalline urea investigated by terahertz spectroscopy and theoretical calculation

    Science.gov (United States)

    Zhao, Yonghong; Li, Zhi; Liu, Jianjun; Hu, Cong; Zhang, Huo; Qin, Binyi; Wu, Yifang

    2018-01-01

    The characteristic absorption spectra of crystalline urea in 0.6-1.8 THz region have been measured by terahertz time-domain spectroscopy at room temperature experimentally. Five broad absorption peaks were observed at 0.69, 1.08, 1.27, 1.47 and 1.64 THz respectively. Moreover, density functional theory (DFT) calculation has been performed for the isolated urea molecule, and there is no infrared intensity in the region below 1.8 THz. This means that single molecule calculations are failure to predict the experimental spectra of urea crystals. To simulate these spectra, calculations on a cluster of seven urea molecules using M06-2X and B3LYP-D3 are performed, and we found that M06-2X perform better. The observed THz vibrational modes are assigned to bending and torsional modes related to the intermolecular H-bond interactions with the help of potential energy distribution (PED) method. Using the reduced-density-gradient (RDG) analysis, the positions and types of intermolecular H-bond interactions in urea crystals are visualized. Therefore, we can confirm that terahertz spectroscopy can be used as an effective means to detect intermolecular H-bond interactions in molecular crystals.

  8. Experimental Investigation of the Effect of Radial Gap and Impeller Blade Exit on Flow-Induced Vibration at the Blade-Passing Frequency in a Centrifugal Pump

    Directory of Open Access Journals (Sweden)

    A. Al-Qutub

    2009-01-01

    Full Text Available It has been recognized that the pressure pulsation excited by rotor-stator interaction in large pumps is strongly influenced by the radial gap between impeller and volute diffusers/tongues and the geometry of impeller blade at exit. This fluid-structure interaction phenomenon, as manifested by the pressure pulsation, is the main cause of flow-induced vibrations at the blade-passing frequency. In the present investigation, the effects of the radial gap and flow rate on pressure fluctuations, vibration, and pump performance are investigated experimentally for two different impeller designs. One impeller has a V-shaped cut at the blade's exit, while the second has a straight exit (without the V-cut. The experimental findings showed that the high vibrations at the blade-passing frequency are primarily raised by high pressure pulsation due to improper gap design. The existence of V-cut at blades exit produces lower pressure fluctuations inside the pump while maintaining nearly the same performance. The selection of proper radial gap for a given impeller-volute combination results in an appreciable reduction in vibration levels.

  9. Vibrational Diver

    Science.gov (United States)

    Kozlov, Victor; Ivanova, Alevtina; Schipitsyn, Vitalii; Stambouli, Moncef

    2014-10-01

    The paper is concerned with dynamics of light solid in cavity with liquid subjected to rotational vibration in the external force field. New vibrational phenomenon - diving of a light cylinder to the cavity bottom is found. The experimental investigation of a horizontal annulus with a partition has shown that under vibration a light body situated in the upper part of the layer is displaced in a threshold manner some distance away from the boundary. In this case the body executes symmetric tangential oscillations. An increase of the vibration intensity leads to a tangential displacement of the body near the external boundary. This displacement is caused by the tangential component of the vibrational lift force, which appears as soon as the oscillations lose symmetry. In this case the trajectory of the body oscillatory motion has the form of a loop. The tangential lift force makes stable the position of the body on the inclined section of the layer and even in its lower part. A theoretical interpretation has been proposed, which explains stabilization of a quasi-equilibrium state of a light body near the cavity bottom in the framework of vibrational hydromechanics.

  10. Analytical and experimental studies of natural vibrations modes of ring-stiffened truncated-cone shells with variable theoretical ring fixity

    Science.gov (United States)

    Naumann, E. C.; Catherines, D. S.; Walton, W. C., Jr.

    1971-01-01

    Experimental and analytical investigations of the vibratory behavior of ring-stiffened truncated-cone shells are described. Vibration tests were conducted on 60 deg conical shells having up to four ring stiffeners and for free-free and clamped-free edge constraints and 9 deg conical shells, for two thicknesses, each with two angle rings and for free-free, free-clamped, and clamped-clamped edge constraints. The analytical method is based on linear thin shell theory, employing the Rayleigh-Ritz method. Discrete rings are represented as composed of one or more segments, each of which is a short truncated-cone shell of uniform thickness. Equations of constraint are used to join a ring and shell along a circumferential line connection. Excellent agreement was obtained for comparisons of experimental and calculated frequencies.

  11. Characterisation of the membrane affinity of an isoniazide peptide conjugate by tensiometry, atomic force microscopy and sum-frequency vibrational spectroscopy, using a phospholipid Langmuir monolayer model.

    Science.gov (United States)

    Hill, Katalin; Pénzes, Csanád Botond; Schnöller, Donát; Horváti, Kata; Bosze, Szilvia; Hudecz, Ferenc; Keszthelyi, Tamás; Kiss, Eva

    2010-10-07

    Tensiometry, sum-frequency vibrational spectroscopy, and atomic force microscopy were employed to assess the cell penetration ability of a peptide conjugate of the antituberculotic agent isoniazide. Isoniazide was conjugated to peptide (91)SEFAYGSFVRTVSLPV(106), a functional T-cell epitope of the immunodominant 16 kDa protein of Mycobacterium tuberculosis. As a simple but versatile model of the cell membrane a phospholipid Langmuir monolayer at the liquid/air interface was used. Changes induced in the structure of the phospholipid monolayer by injection of the peptide conjugate into the subphase were followed by tensiometry and sum-frequency vibrational spectroscopy. The drug penetrated lipid films were transferred to a solid support by the Langmuir-Blodgett technique, and their structures were characterized by atomic force microscopy. Peptide conjugation was found to strongly enhance the cell penetration ability of isoniazide.

  12. Experiments on Suppression of Thermocapillary Oscillations in Sodium Nitrate Floating Half-Zones by High-frequency End-wall Vibrations

    Science.gov (United States)

    Anilkumar, A.; Grugel, R. N.; Bhowmick, J.; Wang, T.

    2004-01-01

    Experiments to suppress thermocapillary oscillations using high-frequency vibrations were carried out in sodium nitrate floating half-zones. Such a half-zone is formed by melting one end of a vertically held sodium nitrate crystal rod in contact with a hot surface at the top. Thermocapillary convection occurs in the melt because of the temperature gradient at the free surface of the melt. In the experiments, when thermocapillary oscillations occurred, the bottom end of the crystal rod was vibrated at a high frequency to generate a streaming flow in a direction opposite to that of the thermocapillary convection. It is observed that, by generating a sufficiently strong streaming flow, the thermocapillary flow can be offset enough such that the associated thermocapillary oscillations can be quenched.

  13. The Role of Symmetric-Stretch Vibration in Asymmetric-Stretch Vibrational Frequency Shift: the Case of 2CH Excitation Infrared Spectra of Acetylene-Hydrogen Van Der Waals Complex

    Science.gov (United States)

    Hou, Dan; Ma, Yong-Tao; Zhang, Xiao-Long; Zhai, Yu; Li, Hui

    2016-06-01

    Direct infrared spectra predictions for van der Waals (vdW) complexes rely on accurate intra-molecular vibrationally excited inter-molecular potential. Due to computational cost increasing with number of freedom, constructing an effective reduced-dimension potential energy surface, which only includes direct relevant intra- molecular modes, is the most feasible way and widely used in the recent potential studies. However, because of strong intra-molecular vibrational coupling, some indirect relevant modes are also play important roles in simulating infrared spectra of vdW complexes. The questions are how many intra-molecular modes are needed, and which modes are most important in determining the effective potential and direct infrared spectra simulations. Here, we explore these issues using a simple, flexible and efficient vibration-averaged approach, and apply the method to vdW complex C_2H_2-H_2. With initial examination of the intra-molecular vibrational coupling, an effective seven-dimensional ab initio potential energy surface(PES) for C_2H_2-H_2, which explicitly takes into account the Q_1,Q_2 symmetric-stretch and Q_3 asymmetric-stretch normal modes of the C_2H_2 monomer, has been generated. Analytic four-dimensional PESs are obtained by least-squares fitting vibrationally averaged interaction energies for νb{3}(C_2H_2)=0 and 1 to the Morse/long-range(MLR) potential function form. We provide the first prediction of the infrared spectra and band origin shifts for C_2H_2-H_2 dimer. We particularly examine the dependence of the symmetric-stretch normal mode on asymmetric-stretch frequency shift for the complex.

  14. Free Vibration Analysis of Rectangular Orthotropic Membranes in Large Deflection

    Directory of Open Access Journals (Sweden)

    Zheng Zhou-Lian

    2009-01-01

    Full Text Available This paper reviewed the research on the vibration of orthotropic membrane, which commonly applied in the membrane structural engineering. We applied the large deflection theory of membrane to derive the governing vibration equations of orthotropic membrane, solved it, and obtained the power series formula of nonlinear vibration frequency of rectangular membrane with four edges fixed. The paper gave the computational example and compared the two results from the large deflection theory and the small one, respectively. Results obtained from this paper provide some theoretical foundation for the measurement of pretension by frequency method; meanwhile, the results provide some theoretical foundation for the research of nonlinear vibration of membrane structures and the response solving of membrane structures under dynamic loads.

  15. Prediction of vibration level in tunnel blasting; Tonneru kusshin happa ni yotte reiki sareru shindo no reberu yosoku ho

    Energy Technology Data Exchange (ETDEWEB)

    Hirata, A. [Kumamoto Industries Univ, Kumamoto (Japan); Yamamoto, M. [Asahi Chemical Industry Co. Ltd., Tokyo (Japan); Inaba, C. [Nishimatsu Construction Co. Ltd., Kanagawa (Japan); Kaneko, K. [Hokkaido Univ (Japan)

    1997-08-01

    For avoiding the generation of public hazard due to ground vibration causes by blasting in tunneling, it is important to devise a blasting method for ensuring the level of the ground vibration caused thereby under a limit, and an exact predication of ground vibration before blasting is desirable. In this study, the characteristics of the ground vibration caused by tunnel blasting are analyzed, and a summary of amplitude spectra calculating method is described. A theoretical analysis method for predicting the vibration level is proposed based on spectrum-multiplicative method. Vibration caused by multistage blasting in tunneling is most strong and deemed as important. When observing the process of elastic wave motion caused by multistage blasting being measured, the process can be divided into three element processes in frequency area as vibration source spectrum, transmission attenuation spectrum and frequency response function vibrating test, and, with the multiplication of them, the amplitude spectra at an observation portion can be estimated. 12 refs., 12 figs.

  16. Theoretical Studies of Low Frequency Instabilities in the Ionosphere. Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Dimant, Y. S.

    2003-08-20

    The objective of the current project is to provide a theoretical basis for better understanding of numerous radar and rocket observations of density irregularities and related effects in the lower equatorial and high-latitude ionospheres. The research focused on: (1) continuing efforts to develop a theory of nonlinear saturation of the Farley-Buneman instability; (2) revision of the kinetic theory of electron-thermal instability at low altitudes; (3) studying the effects of strong anomalous electron heating in the high-latitude electrojet; (4) analytical and numerical studies of the combined Farley-Bunemadion-thermal instabilities in the E-region ionosphere; (5) studying the effect of dust charging in Polar Mesospheric Clouds. Revision of the kinetic theory of electron thermal instability at low altitudes.

  17. Morphological determinants of signal carrier frequency in katydids (Orthoptera): a comparative analysis using biophysical evidence of wing vibration.

    Science.gov (United States)

    Montealegre-Z, F; Ogden, J; Jonsson, T; Soulsbury, C D

    2017-11-01

    Male katydids produce mating calls by stridulation using specialized structures on the forewings. The right wing (RW) bears a scraper connected to a drum-like cell known as the mirror and a left wing (LW) that overlaps the RW and bears a serrated vein on the ventral side, the stridulatory file. Sound is generated with the scraper sweeping across the file, producing vibrations that are amplified by the mirror. Using this sound generator, katydids exploit a range of song carrier frequencies (CF) unsurpassed by any other insect group, with species singing as low as 600 Hz and others as high as 150 kHz. Sound generator size has been shown to scale negatively with CF, but such observations derive from studies based on few species, without phylogenetic control, and/or using only the RW mirror length. We carried out a phylogenetic comparative analysis involving 94 species of katydids to study the relationship between LW and RW components of the sound generator and the CF of the male's mating call, while taking into account body size and phylogenetic relationships. The results showed that CF negatively scaled with all morphological measures, but was most strongly related to components of the sound generation system (file, LW and RW mirrors). Interestingly, the LW mirror (reduced and nonfunctional) predicted CF more accurately than the RW mirror, and body size is not a reliable CF predictor. Mathematical models were verified on known species for predicting CF in species for which sound is unknown (e.g. fossils or museum specimens). © 2017 European Society For Evolutionary Biology. Journal of Evolutionary Biology © 2017 European Society For Evolutionary Biology.

  18. Surface and buried interfacial structures of epoxy resins used as underfills studied by sum frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Vázquez, Anne V; Holden, Brad; Kristalyn, Cornelius; Fuller, Mike; Wilkerson, Brett; Chen, Zhan

    2011-05-01

    Flip chip technology has greatly improved the performance of semiconductor devices, but relies heavily on the performance of epoxy underfill adhesives. Because epoxy underfills are cured in situ in flip chip semiconductor devices, understanding their surface and interfacial structures is critical for understanding their adhesion to various substrates. Here, sum frequency generation (SFG) vibrational spectroscopy was used to study surface and buried interfacial structures of two model epoxy resins used as underfills in flip chip devices, bisphenol A digylcidyl ether (BADGE) and 1,4-butanediol diglycidyl ether (BDDGE). The surface structures of these epoxies were compared before and after cure, and the orientations of their surface functional groups were deduced to understand how surface structural changes during cure may affect adhesion properties. Further, the effect of moisture exposure, a known cause of adhesion failure, on surface structures was studied. It was found that the BADGE surface significantly restructured upon moisture exposure while the BDDGE surface did not, showing that BADGE adhesives may be more prone to moisture-induced delamination. Lastly, although surface structure can give some insight into adhesion, buried interfacial structures more directly correspond to adhesion properties of polymers. SFG was used to study buried interfaces between deuterated polystyrene (d-PS) and the epoxies before and after moisture exposure. It was shown that moisture exposure acted to disorder the buried interfaces, most likely due to swelling. These results correlated with lap shear adhesion testing showing a decrease in adhesion strength after moisture exposure. The presented work showed that surface and interfacial structures can be correlated to adhesive strength and may be helpful in understanding and designing optimized epoxy underfill adhesives.

  19. Nanoscale chemical and mechanical characterization of thin films:sum frequency generation (SFG) vibrational spectroscopy at buriedinterfaces

    Energy Technology Data Exchange (ETDEWEB)

    Kweskin, Sasha Joseph [Univ. of California, Berkeley, CA (United States)

    2006-01-01

    Sum frequency generation (SFG) surface vibrational spectroscopy was used to characterize interfaces pertinent to current surface engineering applications, such as thin film polymers and novel catalysts. An array of advanced surface science techniques like scanning probe microscopy (SPM), x-ray photoelectron spectroscopy (XPS), gas chromatography (GC) and electron microscopy were used to obtain experimental measurements complementary to SFG data elucidating polymer and catalyst surface composition, surface structure, and surface mechanical behavior. Experiments reported in this dissertation concentrate on three fundamental questions: (1) How does the interfacial molecular structure differ from that of the bulk in real world applications? (2) How do differences in chemical environment affect interface composition or conformation? (3) How do these changes correlate to properties such as mechanical or catalytic performance? The density, surface energy and bonding at a solid interface dramatically alter the polymer configuration, physics and mechanical properties such as surface glass transition, adhesion and hardness. The enhanced sensitivity of SFG at the buried interface is applied to three systems: a series of acrylates under compression, the compositions and segregation behavior of binary polymer polyolefin blends, and the changes in surface structure of a hydrogel as a function of hydration. In addition, a catalytically active thin film of polymer coated nanoparticles is investigated to evaluate the efficacy of SFG to provide in situ information for catalytic reactions involving small mass adsorption and/or product development. Through the use of SFG, in situ total internal reflection (TIR) was used to increase the sensitivity of SFG and provide the necessary specificity to investigate interfaces of thin polymer films and nanostructures previously considered unfeasible. The dynamic nature of thin film surfaces is examined and it is found that the non

  20. Vibrational spectra and structures of Ti-N2O and OTi-N2: a combined IR matrix isolation and theoretical study.

    Science.gov (United States)

    Marzouk, Asma; Alikhani, M Esmaïl; Madebène, Bruno; Tremblay, Benoît; Perchard, Jean-Pierre

    2013-02-28

    The reaction of atomic titanium with nitrous oxide has been reinvestigated using matrix isolation in solid neon coupled to infrared spectroscopy and by quantum chemical methods. Our technique of sublimation of Ti atoms from a filament heated at about 1500 °C allowed the formation of three species: one Ti-N(2)O pair of van der Waals (vdW) type characterized by small red shift with respect to N(2)O monomer, and two isomers of OTi-N(2) pair where N(2) is in interaction with the OTi moiety either with end-on or side-on structure. Interconversion between these structures has been performed with several wavelengths. In the visible and near-ultraviolet the conversion vdW → OTi-N(2) (end-on) is observed with characteristic times strongly varying according to the wavelength. In the near-infrared the conversion OTi-N(2) (end-on) → OTi-N(2) (side-on) occurs, the vdW species remaining unchanged. These selectivities allow 8, 6, and 4 vibrational transitions to be assigned for vdW, (3)[OTi(η(1)-NN)] (end-on), and (1)[OTi(η(2)-NN)] (side-on), respectively. Electronic and geometrical structures are also investigated with double-hybrid functionals. It has been shown that the side-on geometry corresponds to the ground state of (1)[OTi(η(2)-NN)] in the singlet electronic state. The theoretical vibrational analysis supports well the experimental attributions.

  1. Research on Free Vibration Frequency Characteristics of Rotating Functionally Graded Material Truncated Conical Shells with Eccentric Functionally Graded Material Stringer and Ring Stiffeners

    Directory of Open Access Journals (Sweden)

    Dao Van Dung

    Full Text Available Abstract In this research work, an exact analytical solution for frequency characteristics of the free vibration of rotating functionally graded material (FGM truncated conical shells reinforced by eccentric FGM stringers and rings has been investigated by the displacement function method. Material properties of shell and stiffeners are assumed to be graded in the thickness direction according to a simple power law distribution. The change of spacing between stringers is considered. Using the Donnell shell theory, Leckhnisky smeared stiffeners technique and taking into account the influences of centrifugal force and Coriolis acceleration the governing equations are derived. For stiffened FGM conical shells, it is difficult that free vibration equations are a couple set of three variable coefficient partial differential equations. By suitable transformations and applying Galerkin method, this difficulty is overcome in the paper. The sixth order polynomial equation for w is obtained and it is used to analyze the frequency characteristics of rotating ES-FGM conical shells. Effects of stiffener, geometrics parameters, cone angle, vibration modes and rotating speed on frequency characteristics of the shell forward and backward wave are discussed in detail. The present approach proves to be reliable and accurate by comparing with published results available in the literature.

  2. Broadband Vibration Attenuation Using Hybrid Periodic Rods

    Directory of Open Access Journals (Sweden)

    S. Asiri

    2008-12-01

    Full Text Available This paper presents both theoretically and experimentally a new kind of a broadband vibration isolator. It is a table-like system formed by four parallel hybrid periodic rods connected between two plates. The rods consist of an assembly of periodic cells, each cell being composed of a short rod and piezoelectric inserts. By actively controlling the piezoelectric elements, it is shown that the periodic rods can efficiently attenuate the propagation of vibration from the upper plate to the lower one within critical frequency bands and consequently minimize the effects of transmission of undesirable vibration and sound radiation. In such a system, longitudinal waves can propagate from the vibration source in the upper plate to the lower one along the rods only within specific frequency bands called the "Pass Bands" and wave propagation is efficiently attenuated within other frequency bands called the "Stop Bands". The spectral width of these bands can be tuned according to the nature of the external excitation. The theory governing the operation of this class of vibration isolator is presented and their tunable filtering characteristics are demonstrated experimentally as functions of their design parameters. This concept can be employed in many applications to control the wave propagation and the force transmission of longitudinal vibrations both in the spectral and spatial domains in an attempt to stop/attenuate the propagation of undesirable disturbances.

  3. Theoretical study of the frequency shift in bimodal FM-AFM by fractional calculus

    Directory of Open Access Journals (Sweden)

    Elena T. Herruzo

    2012-03-01

    Full Text Available Bimodal atomic force microscopy is a force-microscopy method that requires the simultaneous excitation of two eigenmodes of the cantilever. This method enables the simultaneous recording of several material properties and, at the same time, it also increases the sensitivity of the microscope. Here we apply fractional calculus to express the frequency shift of the second eigenmode in terms of the fractional derivative of the interaction force. We show that this approximation is valid for situations in which the amplitude of the first mode is larger than the length of scale of the force, corresponding to the most common experimental case. We also show that this approximation is valid for very different types of tip–surface forces such as the Lennard-Jones and Derjaguin–Muller–Toporov forces.

  4. Theoretical study of the frequency shift in bimodal FM-AFM by fractional calculus.

    Science.gov (United States)

    Herruzo, Elena T; Garcia, Ricardo

    2012-01-01

    Bimodal atomic force microscopy is a force-microscopy method that requires the simultaneous excitation of two eigenmodes of the cantilever. This method enables the simultaneous recording of several material properties and, at the same time, it also increases the sensitivity of the microscope. Here we apply fractional calculus to express the frequency shift of the second eigenmode in terms of the fractional derivative of the interaction force. We show that this approximation is valid for situations in which the amplitude of the first mode is larger than the length of scale of the force, corresponding to the most common experimental case. We also show that this approximation is valid for very different types of tip-surface forces such as the Lennard-Jones and Derjaguin-Muller-Toporov forces.

  5. Energy Finite Element Analysis for Computing the High Frequency Vibration of the Aluminum Testbed Cylinder and Correlating the Results to Test Data

    Science.gov (United States)

    Vlahopoulos, Nickolas

    2005-01-01

    The Energy Finite Element Analysis (EFEA) is a finite element based computational method for high frequency vibration and acoustic analysis. The EFEA solves with finite elements governing differential equations for energy variables. These equations are developed from wave equations. Recently, an EFEA method for computing high frequency vibration of structures either in vacuum or in contact with a dense fluid has been presented. The presence of fluid loading has been considered through added mass and radiation damping. The EFEA developments were validated by comparing EFEA results to solutions obtained by very dense conventional finite element models and solutions from classical techniques such as statistical energy analysis (SEA) and the modal decomposition method for bodies of revolution. EFEA results have also been compared favorably with test data for the vibration and the radiated noise generated by a large scale submersible vehicle. The primary variable in EFEA is defined as the time averaged over a period and space averaged over a wavelength energy density. A joint matrix computed from the power transmission coefficients is utilized for coupling the energy density variables across any discontinuities, such as change of plate thickness, plate/stiffener junctions etc. When considering the high frequency vibration of a periodically stiffened plate or cylinder, the flexural wavelength is smaller than the interval length between two periodic stiffeners, therefore the stiffener stiffness can not be smeared by computing an equivalent rigidity for the plate or cylinder. The periodic stiffeners must be regarded as coupling components between periodic units. In this paper, Periodic Structure (PS) theory is utilized for computing the coupling joint matrix and for accounting for the periodicity characteristics.

  6. Potentially useful to NLO materials: 4-Chloro-3-(trifluoromethyl)aniline, 4-bromo-3-(trifluoromethyl)aniline and 4-fluoro-3-(trifluoromethyl)aniline are combined experimental and theoretical vibrational analysis

    Science.gov (United States)

    Revathi, B.; Balachandran, V.; Raja, B.; Anitha, K.; Kavimani, M.

    2017-08-01

    Primarily, the vibrational analysis of 4-chloro-3-(trifluoromethyl)aniline, 4-bromo-3-(trifluoromethyl)aniline and 4-fluoro-3-(trifluoromethyl)aniline are studied through an experiment by means that of Fourier Transform-Infrared and Fourier Transform-Raman techniques. The electrons both of donating and withdrawing effects on the structure of aniline and effects of substituent positions on the vibrational spectra of the title molecules in compared with similar reasonably molecules have also been illustrated. The details about hyperconjugation interactions, HOMO-LUMO energy gap, molecular electrostatic potential (MEP) surface analysis and thermodynamic functions are expected with the assistance of theoretical density functional theory computations.

  7. Intrinsic Chirality and Prochirality at Air/R-(+)- and S-(-)-Limonene Interfaces: Spectral Signatures with Interference Chiral Sum-Frequency Generation Vibrational Spectroscopy

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Li; Zhang, Yun; Wei, Zhehao; Wang, Hongfei

    2014-06-04

    We report in this work detailed measurements on the chiral and achiral sum-frequency vibrational spectra in the C-H stretching vibration region (2800-3050cm-1) of the air/liquid interfaces of R-limonene and S-limonene, using the recently developed high-resolution broadband sum-frequency generation vibrational spectroscopy (HR-BB-SFG-VS). The achiral SFG spectra of R-limonene and S-limonene, as well as the equal amount (50/50) racemic mixture show that the enantiomers are with the same interfacial orientations. The interference chiral SFG spectra of the limonene enantiomers exhibit spectral signature from chiral response of the Cα-H stretching mode, and spectral signature from prochiral response of the CH2 asymmetric stretching mode, respectively. The chiral spectral feature of the Cα-H stretching mode changes sign from R-limonene to S-limonene, and disappears for the 50/50 racemic mixture. While the prochiral spectral feature of the CH2 asymmetric stretching mode is the same for R-limonene and S-limonene, and also surprisingly remains the same for the 50/50 racemic mixture. These results provided detail information in understanding the structure and chirality of molecular interfaces, and demonstrated the sensitivity and potential of SFG-VS as unique spectroscopic tool for chirality characterization and chiral recognition at the molecular interface.

  8. Optical, microstructural, vibrational, and theoretical studies of p-type SrCu2O2 and BaCu2O2 transparent conductive oxides

    Science.gov (United States)

    Even, J.; Pedesseau, L.; Modreanu, M.; Huyberechts, G.; Servet, B.; Garry, Guy; Chaix-Pluchery, O.; Durand, O.

    2013-03-01

    Transparent conducting metal oxides (TCO) are unusual semiconducting materials displaying transparency to visible light. TCO materials are used for electrostatic shielding, antistatic screens, transparent heating devices, solar cells and even organic light emitting diodes. However, most TCOs are n-type, while p-type TCOs are scarce. SrCu2O2 is a leading candidate as a p-type transparent conductive oxide. In this paper, we report theoretical calculations and experimental studies on the vibrational, optical and microstructural properties of both bulk and thin films of polycrystalline undoped SrCu2O2 obtained by pulsed laser deposition (PLD). Barium doping of the SrCu2O2 by substitution of Sr atoms is also reported. The simulated crystal structures of both SrCu2O2 and BaCu2O2 materials, obtained through a state-of-the-art implementation of the Density functional theory, are compared with experimental X-ray diffraction data of undoped and Ba-doped SrCu2O2 bulk materials. Raman spectra of both SCO and BCO materials are simulated from the derivatives of the dielectric susceptibility and a symmetry analysis of the optical phonon eigenvectors at the Brillouin zone center is proposed. Good agreement with Raman scattering experimental results is demonstrated.

  9. Dependence of the frequency spectrum of small amplitude vibrations superimposed on finite deformations of a nonlinear, cylindrical elastic body on residual stress

    KAUST Repository

    Gorb, Yuliya

    2010-11-01

    We model and analyze the response of nonlinear, residually stressed elastic bodies subjected to small amplitude vibrations superimposed upon large deformations. The problem derives from modeling the use of intravascular ultrasound (IVUS) imaging to interrogate atherosclerotic plaques in vivo in large arteries. The goal of this investigation is twofold: (i) introduce a modeling framework for residual stress that unlike traditional Fung type classical opening angle models may be used for a diseased artery, and (ii) investigate the sensitivity of the spectra of small amplitude high frequency time harmonic vibrations superimposed on a large deformation to the details of the residual stress stored in arteries through a numerical simulation using physiologic parameter values under both low and high blood pressure loadings. The modeling framework also points the way towards an inverse problem using IVUS techniques to estimate residual stress in healthy and diseased arteries. © 2010 Elsevier Ltd. All rights reserved.

  10. Effective properties of mechanical systems under high-frequency excitation at multiple frequencies

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    2008-01-01

    Effects of strong high-frequency excitation at multiple frequencies (multi-HFE) are analyzed for a class of generally nonlinear systems. The effects are illustrated for a simple pendulum system with a vibrating support, and for a parametrically excited flexible beam. For the latter, theoretical...

  11. Computing effective properties of nonlinear structures exposed to strong high-frequency loading at multiple frequencies

    DEFF Research Database (Denmark)

    Thomsen, Jon Juel

    2006-01-01

    Effects of strong high-frequency excitation at multiple frequencies (multi-HFE) are analyzed for a class of generally nonlinear systems. The effects are illustrated for a simple pendulum system with a vibrating support, and for a parametrically excited flexible beam. For the latter, theoretical...

  12. Analysis of motion of inverted pendulum with vibrating suspension axis at low-frequency excitation as an illustration of a new approach for solving equations without explicit small parameter

    DEFF Research Database (Denmark)

    Sorokin, Vladislav

    2014-01-01

    In the classical papers (see, e.g. P.L. Kapitsa, Pendulum with vibrating axis of suspension. Usp. Fiz. Nauk 44 1 (1954) 7-20 (in Russian)) motion of pendulum with vibrating suspension axis was considered in the case when frequency of external loading is much higher than the natural frequency...... of the pendulum in the absence of this loading. The present paper is concerned with the analysis of inverted pendulums motion at unconventional values of parameters. Case when frequency of external loading and the natural frequency of the pendulum in the absence of this loading are of the same order is studied...

  13. Downhole vibration causing a drill collar failure and solutions

    Directory of Open Access Journals (Sweden)

    Quanta Zhu

    2017-03-01

    Full Text Available In large borehole drilling of some blocks or formations, due to serious downhole vibration, fatigue failure of a drill collar occurs frequently and most washouts and fractures are in thread root. An analysis of the above failure shows that the drill collar fatigue failure is caused by the cyclic bending stress due to serious downhole vibration. Therefore, downhole vibration modes were theoretically analyzed in terms of axial vibration, lateral vibration, stick-slip, and the physical model established by the mechanical vibration field. Then the resonance damage caused by the actual different downhole vibrations and its theoretical basis were analyzed; and according to the downhole drill string lateral vibration and whirling law, the best area to ensure drilling parameter stability based on the given boundary conditions was figured out, and the theory was clarified that in the best area of drilling, the maximum ROP will be achieved by maintaining the drill string stable or eliminating the vibration/stick-slip, meanwhile the stress fatigue of BHA will be reduced or eliminated especially for drill collar. Finally, solutions were provided as follows: (1 According to the special BHA, drilling conditions, together with physical and mathematical models listed above, downhole resonance speed and related parameters to be avoided can be easily figured out. It was also clarified that resonance speed is exactly the vibration speed that need to be avoided; and that the resonance frequency can be avoided with software for vibration analysis in BHA design and application at well sites; (2 V-Stab is a new and efficient tool which can reduce or eliminate downhole lateral vibration and stick-slip.

  14. Surface instabilities and reorientation induced by vibration in microgravity conditions

    Science.gov (United States)

    Porter, Jeff; Laverón-Simavilla, Ana; Tinao Perez-Miravete, Ignacio; Fernandez Fraile, Jose Javier; Ezquerro Navarro, Jose Miguel

    2012-07-01

    The behavior of vibrated fluids and, in particular, the surface or interfacial instabilities that commonly arise in these systems have been the subject of continued experimental and theoretical attention since Faraday's seminal experiments in 1831. Both orientation and frequency are critical in determining the response of the fluid to excitation. Low frequencies are associated with sloshing while higher frequencies may generate Faraday waves or cross-waves, depending on whether the axis of vibration is perpendicular or parallel to the interface. In addition, high frequency vibrations are known to produce large scale reorientation of the fluid (vibroequilibria), an effect that becomes especially pronounced in the absence of gravity. We describe the results of investigations conducted at the ESA affiliated Spanish User Support and Operations Centre (E-USOC) on the effect of vibrations on fluid interfaces, particularly the interaction between Faraday waves, which arise in vertically vibrated systems, cross-waves, which are found in horizontally forced systems, and large scale reorientation (vibroequilibria). Ongoing ground experiments utilizing a dual-axis shaker configuration are described, including the effect on pattern formation of varying the two independent forcing frequencies, amplitudes, and phases. Theoretical results, based on the analysis of reduced models, and on numerical simulations, are then described and compared to experiment. Finally, the interest of a corresponding microgravity experiment is discussed and implications for fluid management strategies considered.

  15. The acoustic power of a vibrating clamped circular plate revisited in the wide low frequency range using expansion into the radial polynomials.

    Science.gov (United States)

    Rdzanek, Wojciech P

    2016-06-01

    This study deals with the classical problem of sound radiation of an excited clamped circular plate embedded into a flat rigid baffle. The system of the two coupled differential equations is solved, one for the excited and damped vibrations of the plate and the other one-the Helmholtz equation. An approach using the expansion into radial polynomials leads to results for the modal impedance coefficients useful for a comprehensive numerical analysis of sound radiation. The results obtained are accurate and efficient in a wide low frequency range and can easily be adopted for a simply supported circular plate. The fluid loading is included providing accurate results in resonance.

  16. Landslides in Vibrating Sand-Box; Preliminary Results Reporting Types of Slope-Failure and Apparent Frequency Magnitude (Area) Power Law Relations.

    Science.gov (United States)

    Aharonov, E.; Katz, O.

    2004-12-01

    It is recognized that hazardous natural phenomena such as earthquakes, forest fires and landslides often follow a power-law frequency-magnitude relations. Naturally occurring landslides populations, both seismic and hydrologically triggered, show non-cumulative power law frequency-magnitude (area) relations with slope of 2.3-3 for the large landslides part of the population. Numerical simulations of sand pile avalanches obtain a non-cumulative frequency-size distribution which also follows a power-law but with a slope of 1. In this work we study the nature and area distribution of slope failure triggered in a vibrating wet (1%wt) sand box. We used a 28 cubic cm box with sand pile crest resting on the top of one inner face and foot on the opposite face base. Initial slope angle was about 50deg, vibrating frequency 10Hz and individual test duration lasted a few minutes. Three different accelerations directions were tested: vertical, slope perpendicular, and normal horizontal accelerations. Acceleration magnitudes ranged from 0.1 to 1.2g. Slope performance was continuously recorded using a digital video camera. We observed that vertical vibrations larger than 1.0 g, induced mainly a few centimeter wide block-slides and toppling from a step like scarp that migrated up the slope. Block sliding rate was approximately one every few seconds. Final slope cross-section is S shaped with normal faulting at its crest. Final slope angle was about 35deg. Lower accelerations or lower initial slope angles yielded only surface grain flow. Horizontal shaking yielded different behavior: Above a threshold acceleration (0.5g and 0.7g for shaking parallel and normal to slope direction, respectively), surface flow occurred initially. It was followed by a box-wide slump, which first remained coherent and then progressively disintegrated. Lower accelerations or initial slope angle yield only surface grain flow. Finally, the upper surface areas of tens of block-slides induced in the above

  17. Imaging spectroscopy of the missing REMPI bands of methyl radicals: Final touches on all vibrational frequencies of the 3p Rydberg states.

    Science.gov (United States)

    Pan, Huilin; Liu, Kopin

    2018-01-07

    (2 + 1) resonance-enhanced multiphoton ionization (REMPI) detection of methyl radicals, in particular that via the intermediate 3p Rydberg states, has shown to be a powerful method and thus enjoyed a wide range of applications. Methyl has six vibrational modes. Among them-including partially and fully deuterated isotopologs-four out of twenty vibrational frequencies in the intermediate 3p states have so far eluded direct spectroscopic determination. Here, by exploiting the imaging spectroscopy approach to a few judiciously selected chemical reactions, the four long-sought REMPI bands-CHD2(611), CH2D(311), CH2D(511), and CH2D(611)-are discovered, which complete the REMPI identification for probing any vibrational mode of excitation of methyl radical and its isotopologs. These results, in conjunction with those previously reported yet scattered in the literature, are summarized here for ready reference, which should provide all necessary information for further spectral assignments and future studies of chemical dynamics using this versatile REMPI scheme.

  18. Vibrations and reorientations of NH3 molecules in [Mn(NH3)6](ClO4)2 studied by infrared spectroscopy and theoretical (DFT) calculations.

    Science.gov (United States)

    Hetmańczyk, Joanna; Hetmańczyk, Łukasz; Migdał-Mikuli, Anna; Mikuli, Edward

    2015-02-05

    The vibrational and reorientational motions of NH3 ligands and ClO4(-) anions were investigated by Fourier transform middle-infrared spectroscopy (FT-IR) in the high- and low-temperature phases of [Mn(NH3)6](ClO4)2. The temperature dependencies of full width at half maximum (FWHM) of the infrared bands at: 591 and 3385cm(-1), associated with: ρr(NH3) and νas(N-H) modes, respectively, indicate that there exist fast (correlation times τR≈10(-12)-10(-13)s) reorientational motions of NH3 ligands, with a mean values of activation energies: 7.8 and 4.5kJmol(-1), in the phase I and II, respectively. These reorientational motions of NH3 ligands are only slightly disturbed in the phase transition region and do not significantly contribute to the phase transition mechanism. Fourier transform far-infrared and middle-infrared spectra with decreasing of temperature indicated characteristic changes at the vicinity of PT at TC(c)=137.6K (on cooling), which suggested lowering of the crystal structure symmetry. Infrared spectra of [Mn(NH3)6](ClO4)2 were recorded and interpreted by comparison with respective theoretical spectra calculated using DFT method (B3LYP functional, LANL2DZ ECP basis set (on Mn atom) and 6-311+G(d,p) basis set (on H, N, Cl, O atoms) for the isolated equilibrium two models (Model 1 - separate isolated [Mn(NH3)6](2+) cation and ClO4(-) anion and Model 2 - [Mn(NH3)6(ClO4)2] complex system). Calculated optical spectra show a good agreement with the experimental infrared spectra (FT-FIR and FT-MIR) for the both models. Copyright © 2014 Elsevier B.V. All rights reserved.

  19. Theoretical investigation of the infrared spectrum of small polyynes.

    Science.gov (United States)

    Doney, Kirstin D; Zhao, Dongfeng; Stanton, John F; Linnartz, Harold

    2017-11-08

    The full cubic and semidiagonal quartic force fields of acetylene (C2H2), diacetylene (C4H2), triacetylene (C6H2), and tetraacetylene (C8H2) are determined using CCSD(T) (coupled cluster theory with single and double excitations and augmented by a perturbative treatment of triple excitations) in combination with the atomic natural orbital (ANO) basis sets. Application of second-order vibrational perturbation theory (VPT2) results in vibrational frequencies that agree well with the known fundamental and combination band experimental frequencies of acetylene, diacetylene, and triacetylene (average discrepancies are less than 10 cm(-1)). Furthermore, the predicted ground state rotational constants (B0) and vibration-rotation interaction constants (αi) are shown to be consistent with known experimental values. New vibrational frequencies and rotational parameters from the presented theoretical predictions are given for triacetylene and tetraacetylene, which can be used to aid laboratory and astronomical spectroscopic searches for characteristic transitions of these molecules.

  20. Fault diagnosis of planetary gearboxes via torsional vibration signal analysis

    Science.gov (United States)

    Feng, Zhipeng; Zuo, Ming J.

    2013-04-01

    Torsional vibration signals are theoretically free from the amplitude modulation effect caused by time variant vibration transfer paths due to the rotation of planet carrier and sun gear, and therefore their spectral structure are simpler than transverse vibration signals. Thus, it is potentially easy and effective to diagnose planetary gearbox faults via torsional vibration signal analysis. We give explicit equations to model torsional vibration signals, considering both distributed gear faults (like manufacturing or assembly errors) and local gear faults (like pitting, crack or breakage of one tooth), and derive the characteristics of both the traditional Fourier spectrum and the proposed demodulated spectra of amplitude envelope and instantaneous frequency. These derivations are not only effective to diagnose single gear fault of planetary gearboxes, but can also be generalized to detect and locate multiple gear faults. We validate experimentally the signal models, as well as the Fourier spectral analysis and demodulation analysis methods.

  1. DFT studies on the vibrational and electronic spectra of acetylsalicylic acid

    Science.gov (United States)

    Ye, Yunfeng; Tang, Guodong; Han, Yonghong; Culnane, Lance F.; Zhao, Jianyin; Zhang, Yu

    2016-05-01

    The following is a theoretical and experimental study on the vibrational and electronic properties of acetylsalicylic acid (ASA). Vibrational information was obtained by FT-IR and Raman spectroscopy which agree well with harmonic vibrational frequency calculations. The calculations were carried out using density functional theory B3LYP methods with 6-311G** and LANL2DZ basis sets. The vibrational assignments were calculated by Gaussview. Absorption UV-Vis experiments of ASA reveal three maximum peaks at 203, 224 and 277 nm, which are in agreement with calculated electronic transitions using TD-B3LYP/6-311G**.

  2. The study of the effects of mechanical vibration at infrasound frequency on [(3)H]-thymidine incorporation into DNA of E. coli K-12.

    Science.gov (United States)

    Martirosyan, Varsik; Baghdasaryan, Naira; Ayrapetyan, Sinerik

    2013-03-01

    The aim of the present work was to investigate the frequency-dependent effects of mechanical vibration at infrasound frequency (MV at IS frequency or MV) on E. coli K-12 growth by investigating the cell proliferation, using radioactive [(3)H]-thymidine assay. The frequency-dependent effects of MV were shown that it could either stimulate or inhibit the growth of microbes. However, the mechanism through which the MV effects affect the bacterial cells is not clear yet. It was suggested that the aqua medium can serve as a target through which the biological effect of MV on microbes could be realized. To check this hypothesis the frequency-dependent effect (2, 4, 6, 8, 10 Hz) of MV on the bacterial growth in cases of exposure the preliminary treated microbes-free medium and microbes containing medium were studied. It has been shown that MV at 4, 8, and 10 Hz frequency has inhibition effects, while at 2 and 6 Hz has stimulation effects on cell proliferation.

  3. A batch-fabricated electret-biased wideband MEMS vibration energy harvester with frequency-up conversion behavior powering a UHF wireless sensor node

    Science.gov (United States)

    Lu, Y.; O'Riordan, E.; Cottone, F.; Boisseau, S.; Galayko, D.; Blokhina, E.; Marty, F.; Basset, P.

    2016-12-01

    This paper reports a batch-fabricated, low-frequency and wideband MEMS electrostatic vibration energy harvester (e-VEH), which implements corona-charged vertical electrets and nonlinear elastic stoppers. A numeric model is used to perform parametric study, where we observe a wideband bi-modality resulting from nonlinearity. The nonlinear stoppers improve the bandwidth and induce a frequency-up feature at low frequencies. When the e-VEH works with a bias of 45 V, the power reaches a maximum value of 6.6 μW at 428 Hz and 2.0 g rms, and is above 1 μW at 50 Hz. When the frequency drops below 60 Hz, a ‘frequency-up’ conversion behavior is observed with peaks of power at 34 Hz and 52 Hz. The  -3 dB bandwidth is more than 60% of its central frequency, both including and excluding the hysteresis introduced by the nonlinear stoppers. We also perform experiments with wideband Gaussian noise. The device is eventually tested with an RF data transmission setup, where a communication node with an internal temperature sensor is powered. Every 2 min, a data transmission at 868 MHz is performed by the sensor node supplied by the e-VEH, and received at a distance of up to 15 m.

  4. Effects of 18-month low-magnitude high-frequency vibration on fall rate and fracture risks in 710 community elderly--a cluster-randomized controlled trial.

    Science.gov (United States)

    Leung, K S; Li, C Y; Tse, Y K; Choy, T K; Leung, P C; Hung, V W Y; Chan, S Y; Leung, A H C; Cheung, W H

    2014-06-01

    This study is a prospective cluster-randomized controlled clinical trial involving 710 elderly subjects to investigate the long-term effects of low-magnitude high-frequency vibration (LMHFV) on fall and fracture rates, muscle performance, and bone quality. The results confirmed that LMHFV is effective in reducing fall incidence and enhancing muscle performance in the elderly. Falls are direct causes of fragility fracture in the elderly. LMHFV has been shown to improve muscle function and bone quality. This study is to investigate the efficacy of LMHFV in preventing fall and fractures among the elderly in the community. A cluster-randomized controlled trial was conducted with 710 postmenopausal females over 60 years. A total of 364 participants received daily 20 min LMHFV (35 Hz, 0.3 g), 5 days/week for 18 months; 346 participants served as control. Fall or fracture rate was taken as the primary outcome. Also, quadriceps muscle strength, balancing abilities, bone mineral density (BMD), and quality of life (QoL) assessments were done at 0, 9, and 18 months. With an average of 66.0% compliance in the vibration group, 18.6% of 334 vibration group subjects reported fall or fracture incidences compared with 28.7% of 327 in the control (adjusted HR = 0.56, p = 0.001). The fracture rate of vibration and control groups were 1.1 and 2.3 % respectively (p = 0.171). Significant improvements were found in reaction time, movement velocity, and maximum excursion of balancing ability assessment, and also the quadriceps muscle strength (p < 0.001). No significant differences were found in the overall change of BMD. Minimal adverse effects were documented. LMHFV is effective in fall prevention with improved muscle strength and balancing ability in the elderly. We recommend its use in the community as an effective fall prevention program and to decrease related injuries.

  5. Heterogeneous Dynamics of Coupled Vibrations

    NARCIS (Netherlands)

    Cringus, Dan; Jansen, Thomas I. C.; Pshenichnikov, Maxim S.; Schoenlein, RW; Corkum, P; DeSilvestri, S; Nelson, KA; Riedle, E

    2009-01-01

    Frequency-dependent dynamics of coupled stretch vibrations of a water molecule are revealed by 2D IR correlation spectroscopy. These are caused by non-Gaussian fluctuations of the environment around the individual OH stretch vibrations.

  6. Low-frequency vibrational spectrum of molecular nitrogen complex rhenium(1) chloro(dinitrogen) tetrakis(dimethylphenylphosphine)

    Energy Technology Data Exchange (ETDEWEB)

    Kachapina, L.M.; Kichigina, G.A.; Makhaev, V.D.; Borisov, A.P. (AN SSSR, Chernogolovka. Inst. Khimicheskoj Fiziki)

    1981-10-01

    The investigation results of IR and Raman spectra in the region of 600-170 cm/sup -1/ of molecular nitrogen complex-rhenium (1) chloro (dinitrogen) tetrakis (dimethyl-phenylphosphine)- Cl(PMe/sub 2/Ph)/sub 4/ReN/sub 2/ are presented. The IR spectra have been recorded using the ''Perkin-Elmer 325'' spectrophotometer. The samples have been prepared in the form of tablets with KBr (650-400 cm/sup -1/) and CsI (450-200 cm/sup -1/) and suspensions in vaseline oil. The Raman spectra have been measured using the ''Coderg-PHO'' spectrometer with the recording by FEhU-106. The samples have been taken in the form of polycrystals. The lines attributed to the valent vibration of the Re-N bond and deformation vibration of ReNN fragment have been identified in the spectra.

  7. Influence of Low-Frequency Vibration and Modification on Solidification and Mechanical Properties of Al-Si Casting Alloy

    Directory of Open Access Journals (Sweden)

    Vadim Selivorstov

    2017-05-01

    Full Text Available One of the major aims of the modern materials foundry industry is the achievement of advanced mechanical properties of metals, especially of light non-ferrous alloys such as aluminum. Usually an alloying process is applied to obtain the required properties of aluminum alloys. However, the presented work describes an alternative approach through the application of vibration treatment, modification by ultrafine powder and a combination of these two methods. Microstructural studies followed by image analysis revealed the refinement of α-Al grains with an increase in the Si network area around them. As evidence, the improvement of the mechanical properties of Al casting alloy was detected. It was found that the alloys subjected to the vibration treatment displayed an increase in tensile and yield strengths by 20% and 10%, respectively.

  8. Analytical expressions for bulk moduli and frequencies of volumetrical vibrations of fullerenes C20 and C60

    OpenAIRE

    KOVALEV OLEG; KUZKIN VITALY

    2011-01-01

    In the present paper simple analytical expressions connecting bulk moduli for fullerenes C20 and C60 with stiffness of interatomic bond and geometrical characteristics of the fullerenes are derived. Ambiguities related to definition of the bulk modulus are discussed. Nonlinear volumetrical deformation of the fullerenes is considered. Pressure-volume dependence for the fullerenes under volumetrical compression are derived. Simple analytical model for volumetrical vibrations of the fullerenes i...

  9. Tapered Polymer Fiber Sensors for Reinforced Concrete Beam Vibration Detection.

    Science.gov (United States)

    Luo, Dong; Ibrahim, Zainah; Ma, Jianxun; Ismail, Zubaidah; Iseley, David Thomas

    2016-12-16

    In this study, tapered polymer fiber sensors (TPFSs) have been employed to detect the vibration of a reinforced concrete beam (RC beam). The sensing principle was based on transmission modes theory. The natural frequency of an RC beam was theoretically analyzed. Experiments were carried out with sensors mounted on the surface or embedded in the RC beam. Vibration detection results agreed well with Kistler accelerometers. The experimental results found that both the accelerometer and TPFS detected the natural frequency function of a vibrated RC beam well. The mode shapes of the RC beam were also found by using the TPFSs. The proposed vibration detection method provides a cost-comparable solution for a structural health monitoring (SHM) system in civil engineering.

  10. Tapered Polymer Fiber Sensors for Reinforced Concrete Beam Vibration Detection

    Directory of Open Access Journals (Sweden)

    Dong Luo

    2016-12-01

    Full Text Available In this study, tapered polymer fiber sensors (TPFSs have been employed to detect the vibration of a reinforced concrete beam (RC beam. The sensing principle was based on transmission modes theory. The natural frequency of an RC beam was theoretically analyzed. Experiments were carried out with sensors mounted on the surface or embedded in the RC beam. Vibration detection results agreed well with Kistler accelerometers. The experimental results found that both the accelerometer and TPFS detected the natural frequency function of a vibrated RC beam well. The mode shapes of the RC beam were also found by using the TPFSs. The proposed vibration detection method provides a cost-comparable solution for a structural health monitoring (SHM system in civil engineering.

  11. Vibration of imperfect rotating disk

    Directory of Open Access Journals (Sweden)

    Půst L.

    2011-12-01

    Full Text Available This study is concerned with the theoretical and numerical calculations of the flexural vibrations of a bladed disk. The main focus of this study is to elaborate the basic background for diagnostic and identification methods for ascertaining the main properties of the real structure or an experimental model of turbine disks. The reduction of undesirable vibrations of blades is proposed by using damping heads, which on the experimental model of turbine disk are applied only on a limited number of blades. This partial setting of damping heads introduces imperfection in mass, stiffness and damping distribution on the periphery and leads to more complicated dynamic properties than those of a perfect disk. Calculation of FEM model and analytic—numerical solution of disk behaviour in the limited (two modes frequency range shows the splitting of resonance with an increasing speed of disk rotation. The spectrum of resonance is twice denser than that of a perfect disk.

  12. Vibrational frequency analysis, FT-IR, FT-Raman, ab initio, HF and DFT studies, NBO, HOMO-LUMO and electronic structure calculations on pycolinaldehyde oxime

    Science.gov (United States)

    Suvitha, A.; Periandy, S.; Boomadevi, S.; Govindarajan, M.

    2014-01-01

    In this work, the vibrational spectral analysis is carried out by using Raman and infrared spectroscopy in the range 100-4000 cm-1and 50-4000 cm-1, respectively, for pycolinaldehyde oxime (PAO) (C6H6N2O) molecule. The vibrational frequencies have been calculated and scaled values are compared with experimental FT-IR and FT-Raman spectra. The structure optimizations and normal coordinate force field calculations are based on HF and B3LYP methods with 6-311++G(d,p) basis set. The results of the calculation shows excellent agreement between experimental and calculated frequencies in B3LYP/6-311++G(d,p) basis set. The optimized geometric parameters are compared with experimental values of PAO. The non linear optical properties, NBO analysis, thermodynamics properties and mulliken charges of the title molecule are also calculated and interpreted. A study on the electronic properties, such as HOMO and LUMO energies, are performed by time-dependent DFT (TD-DFT) approach. Besides, frontier molecular orbitals (FMO), molecular electrostatic potential (MEP) are performed. The effects due to the substitutions of CHdbnd NOH ring are investigated. The 1H and 13C nuclear magnetic resonance (NMR) chemical shifts of the molecule are calculated by the gauge independent atomic orbital (GIAO) method and compared with experimental results.

  13. Spectral assignment and orientational analysis in a vibrational sum frequency generation study of DPPC monolayers at the air/water interface.

    Science.gov (United States)

    Feng, Rong-Juan; Li, Xia; Zhang, Zhen; Lu, Zhou; Guo, Yuan

    2016-12-28

    The interfacial behavior of the benchmark zwitterionic phospholipid molecule dipalmitoylphosphatidylcholine (DPPC) has been extensively investigated by surface-selective vibrational sum frequency generation spectroscopy (VSFG). However, there is still a lack of agreement between various orientational measurements of phospholipid monolayers at the air/water interface, mainly because of the difficulty in assigning congested VSFG features. In this study, polarization-dependent VSFG measurements reveal a frequency shift between the in-plane and out-of-plane antisymmetric stretching modes of the terminal methyl groups in the DPPC alkyl tails, favoring the model of Cs local symmetry rather than the previously assumed C3v symmetry. Further VSFG experiments of isotopically labeled DPPC successfully capture the vibrational signatures of the glycerol backbone. With the newly derived VSFG polarization selection rules for Cs symmetry and the refreshed spectral assignments, the average tilt angles of the alkyl tail groups, choline headgroup, and glycerol backbone of DPPC molecules can all be determined, showing the powerful capability of VSFG spectroscopy in revealing the structural details at interfaces. The VSFG polarization dependence rules and the orientational analysis procedures developed for Cs symmetry in this work are applicable to other bulky molecules in which the methyl group cannot freely rotate, and they therefore have general applications in future VSFG studies.

  14. Comparative study of time-dependent effects of 4 and 8 Hz mechanical vibration at infrasound frequency on E. coli K-12 cells proliferation.

    Science.gov (United States)

    Martirosyan, Varsik; Ayrapetyan, Sinerik

    2015-01-01

    The aim of the present work is to study the time-dependent effects of mechanical vibration (MV) at infrasound (IS) frequency at 4 and 8 Hz on E. coli K-12 growth by investigating the cell proliferation, using radioactive [(3)H]-thymidine assay. In our previous work it was suggested that the aqua medium can serve as a target through which the biological effect of MV on microbes could be realized. At the same time it was shown that microbes have mechanosensors on the surface of the cells and can sense small changes of the external environment. The obtained results were shown that the time-dependent effects of MV at 4 and 8 Hz frequency could either stimulate or inhibit the growth of microbes depending from exposure time. It more particularly, the invention relates to a method for controlling biological functions through the application of mechanical vibration, thus making it possible to artificially control the functions of bacterial cells, which will allow us to develop method that can be used in agriculture, industry, medicine, biotechnology to control microbial growth.

  15. Sensing Performance Analysis on Quartz Tuning Fork-Probe at the High Order Vibration Mode for Multi-Frequency Scanning Probe Microscopy

    Directory of Open Access Journals (Sweden)

    Xiaofei Zhang

    2018-01-01

    Full Text Available Multi-frequency scanning near-field optical microscopy, based on a quartz tuning fork-probe (QTF-p sensor using the first two orders of in-plane bending symmetrical vibration modes, has recently been developed. This method can simultaneously achieve positional feedback (based on the 1st in-plane mode called the low mode and detect near-field optically induced forces (based on the 2nd in-plane mode called the high mode. Particularly, the high mode sensing performance of the QTF-p is an important issue for characterizing the tip-sample interactions and achieving higher resolution microscopic imaging but the related researches are insufficient. Here, we investigate the vibration performance of QTF-p at high mode based on the experiment and finite element method. The frequency spectrum characteristics are obtained by our homemade laser Doppler vibrometer system. The effects of the properties of the connecting glue layer and the probe features on the dynamic response of the QTF-p sensor at the high mode are investigated for optimization design. Finally, compared with the low mode, an obvious improvement of quality factor, of almost 50%, is obtained at the high mode. Meanwhile, the QTF-p sensor has a high force sensing sensitivity and a large sensing range at the high mode, indicating a broad application prospect for force sensing.

  16. Interfacial Water Structure and Cation Binding with the Dppc Phosphate at Air /aqueous Interfaces Studied by Vibrational Sum Frequency Generation Spectroscopy

    Science.gov (United States)

    Hua, Wei; Allen, Heather C.

    2012-06-01

    Molecular-level knowledge of water structure and cation binding specificity to lipid headgroups at lipid/water interfaces plays a key role in many relevant chemical, biological, and environmental processes. To obtain information on the molecular organization at aqueous interfaces, vibrational sum frequency generation (VSFG) has been applied extensively as an interface-specific technique. Dipalmitoylphosphocholine (DPPC) is a major component of cell membranes and has been used as a proxy for the organic coating on fat-coated aerosols. In the present work, in addition to conventional VSFG studies on cation interaction with the phosphate headgroup moiety of DPPC, we employ phase-sensitive vibrational sum frequency generation (PS-VSFG) to investigate the average direction of the transition dipole moment of interfacial water molecules. The average orientation of water structure at DPPC/water interfaces is inferred. DPPC orients interfacial water molecules on average with their net transition dipole moment pointing towards the surface. The influence of Na+, K+, Mg2+, Ca2+ is identified in regard to interfacial water structure and DPPC headgroup organization. Ca2+ is observed to have greater impact on the water structure and a unique binding affinity to the phosphate headgroup relative to other cations tested. In highly concentrated Ca2+ regimes the already disturbed interfacial hydrogen-bonding network reorganizes to resemble that of the neat salt solution interface.

  17. Sensing Performance Analysis on Quartz Tuning Fork-Probe at the High Order Vibration Mode for Multi-Frequency Scanning Probe Microscopy.

    Science.gov (United States)

    Zhang, Xiaofei; Gao, Fengli; Li, Xide

    2018-01-24

    Multi-frequency scanning near-field optical microscopy, based on a quartz tuning fork-probe (QTF-p) sensor using the first two orders of in-plane bending symmetrical vibration modes, has recently been developed. This method can simultaneously achieve positional feedback (based on the 1st in-plane mode called the low mode) and detect near-field optically induced forces (based on the 2nd in-plane mode called the high mode). Particularly, the high mode sensing performance of the QTF-p is an important issue for characterizing the tip-sample interactions and achieving higher resolution microscopic imaging but the related researches are insufficient. Here, we investigate the vibration performance of QTF-p at high mode based on the experiment and finite element method. The frequency spectrum characteristics are obtained by our homemade laser Doppler vibrometer system. The effects of the properties of the connecting glue layer and the probe features on the dynamic response of the QTF-p sensor at the high mode are investigated for optimization design. Finally, compared with the low mode, an obvious improvement of quality factor, of almost 50%, is obtained at the high mode. Meanwhile, the QTF-p sensor has a high force sensing sensitivity and a large sensing range at the high mode, indicating a broad application prospect for force sensing.

  18. Molecular structure, Normal Coordinate Analysis, harmonic vibrational frequencies, Natural Bond Orbital, TD-DFT calculations and biological activity analysis of antioxidant drug 7-hydroxycoumarin

    Science.gov (United States)

    Sebastian, S.; Sylvestre, S.; Jayarajan, D.; Amalanathan, M.; Oudayakumar, K.; Gnanapoongothai, T.; Jayavarthanan, T.

    2013-01-01

    In this work, we report harmonic vibrational frequencies, molecular structure, NBO and HOMO, LUMO analysis of Umbelliferone also known as 7-hydroxycoumarin (7HC). The optimized geometric bond lengths and bond angles obtained by computation (monomer and dimmer) shows good agreement with experimental XRD data. Harmonic frequencies of 7HC were determined and analyzed by DFT utilizing 6-311+G(d,p) as basis set. The assignments of the vibrational spectra have been carried out with the help of Normal Coordinate Analysis (NCA) following the Scaled Quantum Mechanical Force Field Methodology (SQMFF). The change in electron density (ED) in the σ* and π* antibonding orbitals and stabilization energies E(2) have been calculated by Natural Bond Orbital (NBO) analysis to give clear evidence of stabilization originating in the hyperconjugation of hydrogen-bonded interaction. The energy and oscillator strength calculated by Time-Dependent Density Functional Theory (TD-DFT) complements with the experimental findings. The simulated spectra satisfactorily coincides with the experimental spectra. Microbial activity of studied compounds was tested against Staphylococcus aureus, Streptococcus pyogenes, Bacillus subtilis, Escherichia coli, Psuedomonas aeruginosa, Klebsiella pneumoniae, Proteus mirabilis, Shigella flexneri, Salmonella typhi and Enterococcus faecalis.

  19. Theoretical coupling longitudinal-transverse model and experimental verification of transverse vibration of rope for multi-rope friction hoisting system

    National Research Council Canada - National Science Library

    Juan Wu Ziming Kou

    2016-01-01

    .... The modified Galerkin's method was used to discretize partial differential Eqs. The mine hoisting system was used to the example to analysis the relation between the load, velocity and transverse vibration of rope...

  20. Optomechanical proposal for monitoring microtubule mechanical vibrations

    Science.gov (United States)

    Barzanjeh, Sh.; Salari, V.; Tuszynski, J. A.; Cifra, M.; Simon, C.

    2017-07-01

    Microtubules provide the mechanical force required for chromosome separation during mitosis. However, little is known about the dynamic (high-frequency) mechanical properties of microtubules. Here, we theoretically propose to control the vibrations of a doubly clamped microtubule by tip electrodes and to detect its motion via the optomechanical coupling between the vibrational modes of the microtubule and an optical cavity. In the presence of a red-detuned strong pump laser, this coupling leads to optomechanical-induced transparency of an optical probe field, which can be detected with state-of-the art technology. The center frequency and line width of the transparency peak give the resonance frequency and damping rate of the microtubule, respectively, while the height of the peak reveals information about the microtubule-cavity field coupling. Our method opens the new possibilities to gain information about the physical properties of microtubules, which will enhance our capability to design physical cancer treatment protocols as alternatives to chemotherapeutic drugs.

  1. Frequency tuning and directional sensitivity of tympanal vibrations in the field cricket Gryllus bimaculatus

    DEFF Research Database (Denmark)

    Lankheet, Martin J.; Cerkvenik, Uroš; Larsen, Ole Næsbye

    2017-01-01

    Female field crickets use phonotaxis to locate males by their calling song. Male song production and female behavioural sensitivity form a pair of matched frequency filters, which in Gryllus bimaculatus are tuned to a frequency of about 4.7 kHz. Directional sensitivity is supported by an elaborat...

  2. Low-Magnitude High-Frequency Vibration Accelerated the Foot Wound Healing of n5-streptozotocin-induced Diabetic Rats by Enhancing Glucose Transporter 4 and Blood Microcirculation.

    Science.gov (United States)

    Yu, Caroline Oi-Ling; Leung, Kwok-Sui; Jiang, Jonney Lei; Wang, Tina Bai-Yan; Chow, Simon Kwoon-Ho; Cheung, Wing-Hoi

    2017-09-14

    Delayed wound healing is a Type 2 diabetes mellitus (DM) complication caused by hyperglycemia, systemic inflammation, and decreased blood microcirculation. Skeletal muscles are also affected by hyperglycemia, resulting in reduced blood flow and glucose uptake. Low Magnitude High Frequency Vibration (LMHFV) has been proven to be beneficial to muscle contractility and blood microcirculation. We hypothesized that LMHFV could accelerate the wound healing of n5-streptozotocin (n5-STZ)-induced DM rats by enhancing muscle activity and blood microcirculation. This study investigated the effects of LMHFV in an open foot wound created on the footpad of n5-STZ-induced DM rats (DM_V), compared with no-treatment DM (DM), non-DM vibration (Ctrl_V) and non-DM control rats (Ctrl) on Days 1, 4, 8 and 13. Results showed that the foot wounds of DM_V and Ctrl_V rats were significantly reduced in size compared to DM and Ctrl rats, respectively, at Day 13. The blood glucose level of DM_V rats was significantly reduced, while the glucose transporter 4 (GLUT4) expression and blood microcirculation of DM_V rats were significantly enhanced in comparison to those of DM rats. In conclusion, LMHFV can accelerate the foot wound healing process of n5-STZ rats.

  3. Using high-frequency vibrations and non-linear inclusions to create metamaterials with adjustable effective properties

    DEFF Research Database (Denmark)

    Lazarov, Boyan Stefanov; Thomsen, Jon Juel

    2009-01-01

    We investigate how high-frequency (HF) excitation combined with strongly non-linear elasticity may influence the effective properties for low-frequency wave propagation. The HF effects are demonstrated for linear spring-mass chains with embedded non-linear parts. The investigated mechanical syste...... static displacements and forces can be created by using HF excitation with structures having asymmetric displacement-force characteristics....

  4. Amine Chemistry at Aqueous Interfaces: The Study of Organic Amines in Neutralizing Acidic Gases at an Air/Water Surface Using Vibrational Sum Frequency Spectroscopy

    Science.gov (United States)

    McWilliams, L.; Wren, S. N.; Valley, N. A.; Richmond, G.

    2014-12-01

    Small organic bases have been measured in atmospheric samples, with their sources ranging from industrial processing to animal husbandry. These small organic amines are often highly soluble, being found in atmospheric condensed phases such as fogwater and rainwater. Additionally, they display acid-neutralization ability often greater than ammonia, yet little is known regarding their kinetic and thermodynamic properties. This presentation will describe the molecular level details of a model amine system at the vapor/liquid interface in the presence of acidic gas. We find that this amine system shows very unique properties in terms of its bonding, structure, and orientation at aqueous surfaces. The results of our studies using a combination of computation, vibrational sum frequency spectroscopy, and surface tension will report the properties inherent to these atmospherically relevant species at aqueous surfaces.

  5. Sum frequency generation vibrational spectroscopy (SFG-VS) for complex molecular surfaces and interfaces: Spectral lineshape measurement and analysis plus some controversial issues

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Hong-Fei

    2016-12-01

    Sum-frequency generation vibrational spectroscopy (SFG-VS) was first developed in the 1980s and it has been proven a uniquely sensitive and surface/interface selective spectroscopic probe for characterization of the structure, conformation and dynamics of molecular surfaces and interfaces. In recent years, there has been significant progress in the development of methodology and instrumentation in the SFG-VS toolbox that has significantly broadened the application to complex molecular surfaces and interfaces. In this review, after presenting a unified view on the theory and methodology focusing on the SFG-VS spectral lineshape, as well as the new opportunities in SFG-VS applications with such developments, some of the controversial issues that have been puzzling the community are to be discussed. The aim of this review is to present to the researchers and students interested in molecular surfaces and interfacial sciences up-to-date perspectives complementary to the existing textbooks and reviews on SFG-VS.

  6. Sum Frequency Generation Vibrational Spectroscopy and Kinetic Study of 2-Methylfuran and 2,5-Dimethylfuran Hydrogenation over 7 nm Platinum Cubic Nanoparticles

    KAUST Repository

    Aliaga, Cesar

    2011-04-28

    Sum frequency generation vibrational spectroscopy and kinetic measurements obtained from gas chromatography were used to study the adsorption and hydrogenation of 2-methylfuran (MF) and 2,5-dimethylfuran (DMF) over cubic Pt nanoparticles of 7 nm average size, synthesized by colloidal methods and cleaned by ultraviolet light and ozone treatment. Reactions carried out at atmospheric pressure in the temperature range of 20-120 °C produced dihydro and tetrahydro species, as well as ring-opening products (alcohols) and ring-cracking products, showing high selectivity toward ring opening throughout the entire temperature range. The aromatic rings (MF and DMF) adsorbed parallel to the nanoparticle surface. Results yield insight into various surface reaction intermediates and the reason for the significantly lower selectivity for ring cracking in DMF hydrogenation compared to MF hydrogenation. © 2011 American Chemical Society.

  7. VIBRATION ISOLATION SYSTEM PROBABILITY ANALYSIS

    Directory of Open Access Journals (Sweden)

    Smirnov Vladimir Alexandrovich

    2012-10-01

    Full Text Available The article deals with the probability analysis for a vibration isolation system of high-precision equipment, which is extremely sensitive to low-frequency oscillations even of submicron amplitude. The external sources of low-frequency vibrations may include the natural city background or internal low-frequency sources inside buildings (pedestrian activity, HVAC. Taking Gauss distribution into account, the author estimates the probability of the relative displacement of the isolated mass being still lower than the vibration criteria. This problem is being solved in the three dimensional space, evolved by the system parameters, including damping and natural frequency. According to this probability distribution, the chance of exceeding the vibration criteria for a vibration isolation system is evaluated. Optimal system parameters - damping and natural frequency - are being developed, thus the possibility of exceeding vibration criteria VC-E and VC-D is assumed to be less than 0.04.

  8. Anomalies in the low frequency vibrational density of states for a polymer with intrinsic microporosity - the Boson peak of PIM-1.

    Science.gov (United States)

    Zorn, Reiner; Yin, Huajie; Lohstroh, Wiebke; Harrison, Wayne; Budd, Peter M; Pauw, Brian R; Böhning, Martin; Schönhals, Andreas

    2018-01-17

    Polymers with intrinsic microporosity are promising candidates for the active separation layer in gas separation membranes. Here, the vibrational density of states (VDOS) for PIM-1, the prototypical polymer with intrinsic microporosity, is investigated by means of inelastic neutron scattering. The results are compared to data measured for a more conventional high-performance polyimide used in gas separation membranes (Matrimid). The measured data show the characteristic low frequency excess contribution to VDOS above the Debye sound wave level, generally known as the Boson peak in glass-forming materials. In comparison to the Boson peak of Matrimid, that of PIM-1 is shifted to lower frequencies. This shift is discussed considering the microporous, sponge-like structure of PIM-1 as providing a higher compressibility at the molecular scale than for conventional polymers. For an annealed PIM-1 sample, the Boson peak shifts to higher frequencies in comparison to the un-annealed sample. These changes in the VDOS of the annealed PIM-1 sample are related to changes in the microporous structure as confirmed by X-ray scattering.

  9. Catalyzed hydrogenation of nitrogen and ethylene on metal (Fe, Pt) single crystal surfaces and effects of coadsorption: A sum frequency generation vibrational spectroscopy study

    Energy Technology Data Exchange (ETDEWEB)

    Westerberg, Staffan Per Gustav [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    High-pressure catalytic reactions and associated processes, such as adsorption have been studied on a molecular level on single crystal surfaces. Sum Frequency Generation (SFG) vibrational spectroscopy together with Auger Electron Spectroscopy (AES), Temperature Programmed Desorption (TPD) and Gas Chromatography (GC) were used to investigate the nature of species on catalytic surfaces and to measure the catalytic reaction rates. Special attention has been directed at studying high-pressure reactions and in particular, ammonia synthesis in order to identify reaction intermediates and the influence of adsorbates on the surface during reaction conditions. The adsorption of gases N2, H2, O2 and NH3 that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH2 (~3325 cm-1) and NH (~3235 cm-1) under high pressure of ammonia (200 Torr) on the clean Fe(111) surface. Addition of 0.5 Torr of oxygen to 200 Torr of ammonia does not significantly change the bonding of dissociation intermediates to the surface. However, it leads to a phase change of nearly 180° between the resonant and non-resonant second order non-linear susceptibility of the surface, demonstrated by the reversal of the SFG spectral features. Heating the surface in the presence of 200 Torr ammonia and 0.5 Torr oxygen reduces the oxygen coverage, which can be seen from the SFG spectra as another relative phase change of 180°. The reduction of the oxide is also supported by Auger electron spectroscopy. The result suggests that the phase change of the spectral features could serve as a sensitive indicator of the chemical environment of the adsorbates.

  10. Shaping frequency response of a vibrating plate for passive and active control applications by simultaneous optimization of arrangement of additional masses and ribs. Part II: Optimization

    Science.gov (United States)

    Wrona, Stanislaw; Pawelczyk, Marek

    2016-03-01

    It was shown in Part I that an ability to shape frequency response of a vibrating plate according to precisely defined demands has a very high practical potential. It can be used to improve acoustic radiation of the plate for required frequencies or enhance acoustic isolation of noise barriers and device casings. It can be used for both passive and active control. The proposed method is based on mounting several additional ribs and masses (passive and/or active) to the plate surface at locations followed from an optimisation process. In Part I a relevant model of such structure, as a function of arrangement of the additional elements was derived and validated. The model allows calculating natural frequencies and mode-shapes of the whole structure. The aim of this companion paper, Part II, is to present the second stage of the method. This is an optimization process that results in arrangement of the elements guaranteeing desired plate frequency response, and enhancement of controllability and observability measures. For that purpose appropriate cost functions, and constraints followed from technological feasibility are defined. Then, a memetic algorithm is employed to obtain a numerical solution with parameters of the arrangement. The optimization results are initially presented for simple cases to validate the method. Then, more complex scenarios are analysed with very special demands concerning the frequency response to present the full potential of the method. Subsequently, a laboratory experiment is presented and discussed. Finally, other areas of applications of the proposed method are shown and conclusions for future research are drawn.

  11. Use of vibrational spectroscopy to study protein and DNA structure, hydration, and binding of biomolecules: A combined theoretical and experimental approach

    DEFF Research Database (Denmark)

    Jalkanen, Karl J.; Jürgensen, Vibeke Würtz; Claussen, Anetta

    2006-01-01

    +disp, RHF, MP2, and DFT methodologies for the modeling studies with the goal of interpreting the experimentally measured vibrational spectra for these molecules to the greatest extent possible and to use this combined approach to understand the structure, function, and electronic properties...

  12. Vibrational Probes: From Small Molecule Solvatochromism Theory and Experiments to Applications in Complex Systems.

    Science.gov (United States)

    Błasiak, Bartosz; Londergan, Casey H; Webb, Lauren J; Cho, Minhaeng

    2017-04-18

    The vibrational frequency of a chosen normal mode is one of the most accurately measurable spectroscopic properties of molecules in condensed phases. Accordingly, infrared absorption and Raman scattering spectroscopy have provided valuable information on both distributions and ensemble-average values of molecular vibrational frequencies, and these frequencies are now routinely used to investigate structure, conformation, and even absolute configuration of chemical and biological molecules of interest. Recent advancements in coherent time-domain nonlinear vibrational spectroscopy have allowed the study of heterogeneous distributions of local structures and thermally driven ultrafast fluctuations of vibrational frequencies. To fully utilize IR probe functional groups for quantitative bioassays, a variety of biological and chemical techniques have been developed to site-specifically introduce vibrational probe groups into proteins and nucleic acids. These IR-probe-labeled biomolecules and chemically reactive systems are subject to linear and nonlinear vibrational spectroscopic investigations and provide information on the local electric field, conformational changes, site-site protein contacts, and/or function-defining features of biomolecules. A rapidly expanding library of data from such experiments requires an interpretive method with atom-level chemical accuracy. However, despite prolonged efforts to develop an all-encompassing theory for describing vibrational solvatochromism and electrochromism as well as dynamic fluctuations of instantaneous vibrational frequencies, purely empirical and highly approximate theoretical models have often been used to interpret experimental results. They are, in many cases, based on the simple assumption that the vibrational frequency of an IR reporter is solely dictated by electric potential or field distribution around the vibrational chromophore. Such simplified description of vibrational solvatochromism generally referred to as

  13. Lift Force Acting on Bodies in Viscous Liquid Under Vibration

    Science.gov (United States)

    Schipitsyn, Vitaliy; Ivanova, Alevtina; Vlasova, Olga; Kozlov, Victor

    2014-11-01

    The averaged lift force acting on a rigid body located near the wall of the cavity with a viscous liquid under high-frequency oscillations of various types is studied experimentally and theoretically. The experiments are conducted with cylindrical and rectangular solids. Amplitude and frequency of vibration, viscosity and density of fluid, specific solid size, its density and shape vary. Lift force was measured by the dynamic hanging of the body in the gravity when the body oscillates without touching the cavity walls. The vibrations generate a repulsive force, holding a heavy body above the bottom of the cavity, and the light one at some distance from the ceiling. Lift force changes qualitatively in case of combined translational and rotational oscillations of the cavity containing fluid and solid; it is much greater than at the translational vibrations and appears throughout the entire volume of the liquid. The work contains a theoretical description of the mechanism of lift force generation and the comparison of the experimental and theoretical results. The agreement of the results is found in the limit of high dimensionless frequencies. The considered effects could be interesting for vibrational control of solid inclusions in viscous liquids. Work was done in the framework of the Program of strategic development of PSHPU (project 030-F) and supported by Ministry of Education of Perm Region (project C26/625) and grant 4022.2014.1 (Leading Scientific School).

  14. Detecting Molecular Rotational Dynamics Complementing the Low-Frequency Terahertz Vibrations in a Zirconium-Based Metal-Organic Framework

    Science.gov (United States)

    Ryder, Matthew R.; Van de Voorde, Ben; Civalleri, Bartolomeo; Bennett, Thomas D.; Mukhopadhyay, Sanghamitra; Cinque, Gianfelice; Fernandez-Alonso, Felix; De Vos, Dirk; Rudić, Svemir; Tan, Jin-Chong

    2017-06-01

    We show clear experimental evidence of cooperative terahertz (THz) dynamics observed below 3 THz (˜100 cm-1 ), for a low-symmetry Zr-based metal-organic framework structure, termed MIL-140A [ZrO (O2C-C 6H4-CO2) ]. Utilizing a combination of high-resolution inelastic neutron scattering and synchrotron radiation far-infrared spectroscopy, we measured low-energy vibrations originating from the hindered rotations of organic linkers, whose energy barriers and detailed dynamics have been elucidated via ab initio density functional theory calculations. The complex pore architecture caused by the THz rotations has been characterized. We discovered an array of soft modes with trampolinelike motions, which could potentially be the source of anomalous mechanical phenomena such as negative thermal expansion. Our results demonstrate coordinated shear dynamics (2.47 THz), a mechanism which we have shown to destabilize the framework structure, in the exact crystallographic direction of the minimum shear modulus (Gmin ).

  15. Dynamic stiffness of chemically and physically ageing rubber vibration isolators in the audible frequency range. Part 1: constitutive equations

    Science.gov (United States)

    Kari, Leif

    2017-09-01

    The constitutive equations of chemically and physically ageing rubber in the audible frequency range are modelled as a function of ageing temperature, ageing time, actual temperature, time and frequency. The constitutive equations are derived by assuming nearly incompressible material with elastic spherical response and viscoelastic deviatoric response, using Mittag-Leffler relaxation function of fractional derivative type, the main advantage being the minimum material parameters needed to successfully fit experimental data over a broad frequency range. The material is furthermore assumed essentially entropic and thermo-mechanically simple while using a modified William-Landel-Ferry shift function to take into account temperature dependence and physical ageing, with fractional free volume evolution modelled by a nonlinear, fractional differential equation with relaxation time identical to that of the stress response and related to the fractional free volume by Doolittle equation. Physical ageing is a reversible ageing process, including trapping and freeing of polymer chain ends, polymer chain reorganizations and free volume changes. In contrast, chemical ageing is an irreversible process, mainly attributed to oxygen reaction with polymer network either damaging the network by scission or reformation of new polymer links. The chemical ageing is modelled by inner variables that are determined by inner fractional evolution equations. Finally, the model parameters are fitted to measurements results of natural rubber over a broad audible frequency range, and various parameter studies are performed including comparison with results obtained by ordinary, non-fractional ageing evolution differential equations.

  16. Vibration Properties of a Steel-PMMA Composite Beam

    Directory of Open Access Journals (Sweden)

    Yuyang He

    2015-01-01

    Full Text Available A steel-polymethyl methacrylate (steel-PMMA beam was fabricated to investigate the vibration properties of a one-dimensional phononic crystal structure. The experimental system included an excitation system, a signal acquisition system, and a data analysis and processing system. When an excitation signal was exerted on one end of the beam, the signals of six response points were collected with acceleration sensors. Subsequent signal analysis showed that the beam was attenuated in certain frequency ranges. The lumped mass method was then used to calculate the bandgap of the phononic crystal beam to analyze the vibration properties of a beam made of two different materials. The finite element method was also employed to simulate the vibration of the phononic crystal beam, and the simulation results were consistent with theoretical calculations. The existence of the bandgap was confirmed experimentally and theoretically, which allows for the potential applications of phononic crystals, including wave guiding and filtering, in integrated structures.

  17. Smart paint sensor for monitoring structural vibrations

    Science.gov (United States)

    Al-Saffar, Y.; Aldraihem, O.; Baz, A.

    2012-04-01

    A class of smart paint sensors is proposed for monitoring the structural vibration of beams. The sensor is manufactured from an epoxy resin which is mixed with carbon black nano-particles to make it electrically conducting and sensitive to mechanical vibrations. A comprehensive theoretical and experimental investigation is presented to understand the underlying phenomena governing the operation of this class of paint sensors and evaluate its performance characteristics. A theoretical model is presented to model the electromechanical behavior of the sensor system using molecular theory. The model is integrated with an amplifier circuit in order to predict the current and voltage developed by the paint sensor when subjected to loading. Furthermore, the sensor/amplifier circuit models are coupled with a finite element model of a base beam to which the sensor is bonded. The resulting multi-field model is utilized to predict the behavior of both the sensor and the beam when subjected to a wide variety of vibration excitations. The predictions of the multi-field finite element model are validated experimentally and the behavior of the sensor is evaluated both in the time and the frequency domains. The performance of the sensor is compared with the performance of conventional strain gages to emphasize its potential and merits. The presented techniques are currently being extended to sensors that can monitor the vibration and structural power flow of two-dimensional structures.

  18. Analysis of mechanical vibrations in large vertical pumps: two cases of natural frequency excitations; Analisis de vibraciones mecanicas en grandes bombas verticales: dos casos de excitacion de frecuencias naturales

    Energy Technology Data Exchange (ETDEWEB)

    Ercoli, L.; La Malfa, S. [Consejo Nacional de Investigaciones Cientificas y Tecnicas (CONICET), Bahia Blanca (Argentina). Inst. de Mecanica Aplicada]|[Universidad Tecnologica Nacional (Argentina). Grupo Analisis de Sistemas Mecanicos

    1995-07-01

    This study presents experimental dynamic analysis of two big vertical pumps induced to vibrate due to the excitation of natural frequencies of the structural systems: pump-mounting. It is demonstrated that a proper diagnostic of the working condition avoids unecessary and time-consuming equipment stops, with the consequent saving in the production costs. (author)

  19. Setting up of a theoretical-experimental approach for the measurement of the vibrational impact on cultural heritages due to vehicular traffic

    Directory of Open Access Journals (Sweden)

    Salvatore Barbaro

    2006-02-01

    Full Text Available During the last years, the constant increase of the request for transport by road and by rail, connected to the economic and social development process, has provoked the birth of the phenomenon of the vibrations induced by the means of transports, with the result of stimulating the resident population's curiosity and the technical personnel's interest. Into the historic centres of the towns, it is possible to trace a series of concomitant factors that tend further to increase this process: the road superstructure mostly used in the historical centres are often stony, and their usage is due mainly to aesthetic reasons; the no-measurement or the lack of maintenance are often the causes of high levels of roughness; the buildings set into the historical centres have got a historical-art value of primary importance and some part of them (such as mosaics, pictures, etc. are very sensitive to vibrations, being sticking to the outside walls; According to what said above, the noisy and vibrations provoked by the road traffic are becoming even more one of the main cause of the environmental damage.

  20. Rectangular Parallelepiped Vibration in Plane Strain State

    OpenAIRE

    Hanckowiak, Jerzy

    2004-01-01

    In this paper we present a vibration spectrum of a homogenous parallelepiped (HP) under the action of volume and surface forces resulting from the exponent displacements entering the Fourier transforms. Vibration under the action of axial surface tractions and the free vibration are described separately. A relationship between the high frequency vibration and boundary conditions (BC) is also considered.

  1. High-Pressure Catalytic Reactions of C6 Hydrocarbons on PlatinumSingle-Crystals and nanoparticles: A Sum Frequency Generation VibrationalSpectroscopic and Kinetic Study

    Energy Technology Data Exchange (ETDEWEB)

    Bratlie, Kaitlin [Univ. of California, Berkeley, CA (United States)

    2007-01-01

    Catalytic reactions of cyclohexene, benzene, n-hexane, 2-methylpentane, 3-methylpentane, and 1-hexene on platinum catalysts were monitored in situ via sum frequency generation (SFG) vibrational spectroscopy and gas chromatography (GC). SFG is a surface specific vibrational spectroscopic tool capable of monitoring submonolayer coverages under reaction conditions without gas-phase interference. SFG was used to identify the surface intermediates present during catalytic processes on Pt(111) and Pt(100) single-crystals and on cubic and cuboctahedra Pt nanoparticles in the Torr pressure regime and at high temperatures (300K-450K). At low pressures (<10-6 Torr), cyclohexene hydrogenated and dehydrogenates to form cyclohexyl (C6H11) and π-allyl C6H9, respectively, on Pt(100). Increasing pressures to 1.5 Torr form cyclohexyl, π-allyl C6H9, and 1,4-cyclohexadiene, illustrating the necessity to investigate catalytic reactions at high-pressures. Simultaneously, GC was used to acquire turnover rates that were correlated to reactive intermediates observed spectroscopically. Benzene hydrogenation on Pt(111) and Pt(100) illustrated structure sensitivity via both vibrational spectroscopy and kinetics. Both cyclohexane and cyclohexene were produced on Pt(111), while only cyclohexane was formed on Pt(100). Additionally, π-allyl c-C6H9 was found only on Pt(100), indicating that cyclohexene rapidly dehydrogenates on the (100) surface. The structure insensitive production of cyclohexane was found to exhibit a compensation effect and was analyzed using the selective energy transfer (SET) model. The SET model suggests that the Pt-H system donates energy to the E2u mode of free benzene, which leads to catalysis. Linear C6 (n-hexane, 2-methylpentane, 3-methylpentane, and 1-hexene) hydrocarbons were also investigated in the presence and absence of excess hydrogen on Pt

  2. The effects of two different frequencies of whole-body vibration on knee extensors strength in healthy young volunteers: a randomized trial

    Science.gov (United States)

    Esmaeilzadeh, S.; Akpinar, M.; Polat, S.; Yildiz, A.; Oral, A.

    2015-01-01

    The aim of this study was to investigate the effects of two different frequencies of whole-body vibration (WBV) training on knee extensors muscle strength in healthy young volunteers. Twenty-two eligible healthy untrained young women aged 22-31 years were allocated randomly to the 30-Hz (n=11) and 50-Hz (n=11) groups. They participated in a supervised WBV training program that consisted of 24 sessions on a synchronous vertical vibration platform (peak-to-peak displacement: 2-4 mm; type of exercises: semi-squat, one-legged squat, and lunge positions on right leg; set numbers: 2-24) three times per week for 8 weeks. Isometric and dynamic strength of the knee extensors were measured prior to and at the end of the 8-week training. In the 30-Hz group, there was a significant increase in the maximal voluntary isometric contraction (p=0.039) and the concentric peak torque (p=0.018) of knee extensors and these changes were significant (p<0.05) compared with the 50-Hz group. In addition, the eccentric peak torque of knee extensors was increased significantly in both groups (p<0.05); however, there was no significant difference between the two groups (p=0.873). We concluded that 8 weeks WBV training in 30 Hz was more effective than 50 Hz to increase the isometric contraction and dynamic strength of knee extensors as measured using peak concentric torque and equally effective with 50 Hz in improving eccentric torque of knee extensors in healthy young untrained women. PMID:26636279

  3. Development of Absorbed Blasting Vibration Energy Index for the Evaluation of Human Comfort in Multistorey Buildings

    Directory of Open Access Journals (Sweden)

    Qiang Yao

    2017-01-01

    Full Text Available There have been civil disputes and complaints regarding the negative effects of blasting vibration on buildings around the blasting site. By considering the effect of blasting vibration on a human body as a process of energy transfer and conversion, the human body absorbed blasting vibration energy (ABVE index has been developed for comfort evaluation. Using dynamic monitoring and theoretical analysis, the elevation amplification effect and selective amplification effect on different frequency components of the ABVE have been investigated. The elevation amplification factor and selective amplification coefficients on different frequency components of the ABVE index for a typical 4-storey brick and concrete building have been determined. Based on the results, the magnitude and frequency components of the ABVE index in different parts especially in different storeys for the typical building have been determined. According to the characteristics of human body’s response to vibrations of different frequencies, the frequency-based weighting method of ABVE index has been simplified. By calculating the combined effect of vibrations from all directions, the total human body ABVE and its frequency components at different floors of the building can be determined accurately. This can be used to evaluate the human body comfort against blasting vibration at different floors.

  4. Energy-Saving Vibration Impulse Coal Degradation at Finely Dispersed Coal-Water Slurry Preparation

    Directory of Open Access Journals (Sweden)

    Moiseev V.A.

    2015-01-01

    Full Text Available Theoretical and experimental research results of processes of finely dispersed coal-water slurry preparation for further generation of energetic gas in direct flow and vortex gas generator plants have been presented. It has been stated that frequency parameters of parabolic vibration impulse mill influence degradation degree. Pressure influence on coal parameters in grinding cavity has been proven. Experimental researches have proven efficiency of vibration impulse mill with unbalanced mass vibrator generator development. Conditions of development on intergranular walls of coal cracks have been defined.

  5. Attenuation of cryocooler induced vibration in spaceborne infrared payloads

    Science.gov (United States)

    Veprik, A.; Twitto, A.

    2014-01-01

    Recent advancement of operational responsive space programs calls for a development of compact, reliable, low power and vibration free cryogenic cooling for sophisticated infrared payloads. The refrigeration in a typical closed cycle split Stirling linear cryocooler is achieved by a cyclic compression and expansion of a gaseous working agent due to a synchronized reciprocation of electro-dynamically and pneumatically actuated compressor and expander pistons. Attenuation of the cryocooler induced vibration usually relies on the concept of actively assisted momentum cancellation. In a typical dual-piston compressor this objective is achieved by actively synchronizing the motion of oppositely moving piston assemblies; a typical single-piston expander may be counterbalanced by a motorized counter-balancer. The above approach produces complexity, weight, size, high incurred costs and affects reliability. The authors analyze the case of passive attenuation the vibration export induced by the split Stirling linear cryocooler comprised of inline mounted single-piston compressor and expander. Placement of all the moving components onto a common axis results in a single axis consolidation of vibration export and enables use of single tuned dynamic absorber and low frequency vibration mount. From theoretical analysis and full-scale testing, the performance of such vibration protection arrangement is similar to known systems of active vibration cancellation.

  6. A Novel Wireless and Temperature-Compensated SAW Vibration Sensor

    Directory of Open Access Journals (Sweden)

    Wen Wang

    2014-11-01

    Full Text Available A novel wireless and passive surface acoustic wave (SAW based temperature-compensated vibration sensor utilizing a flexible Y-cut quartz cantilever beam with a relatively substantial proof mass and two one-port resonators is developed. One resonator acts as the sensing device adjacent to the clamped end for maximum strain sensitivity, and the other one is used as the reference located on clamped end for temperature compensation for vibration sensor through the differential approach. Vibration directed to the proof mass flex the cantilever, inducing relative changes in the acoustic propagation characteristics of the SAW travelling along the sensing device, and generated output signal varies in frequency as a function of vibration.  A theoretical mode using the Rayleigh method was established to determine the optimal dimensions of the cantilever beam. Coupling of Modes (COM model was used to extract the optimal design parameters of the SAW devices prior to fabrication. The performance of the developed SAW sensor attached to an antenna towards applied vibration was evaluated wirelessly by using the precise vibration table, programmable incubator chamber, and reader unit.  High vibration sensitivity of ~10.4 kHz/g, good temperature stability, and excellent linearity were observed in the wireless measurements.

  7. FT-Raman and FTIR spectra of photoactive aminobenzazole derivatives in the solid state: A combined experimental and theoretical study

    Energy Technology Data Exchange (ETDEWEB)

    Alves, Rodrigo Martins [Universidade Federal do Pampa, Campus Bagé, Grupo de Pesquisa em Espectroscopia de Materiais Fotônicos, 96400-970 Bagé, RS (Brazil); Rodembusch, Fabiano Severo [Universidade Federal do Rio Grande do Sul, Grupo de Pesquisa em Fotoquímica Orgânica Aplicada, Av. Bento Gonçalves 9500, CEP 91501-970 Porto Alegre, RS (Brazil); Habis, Charles [Northern Virginia Community College, Manassas, VA (United States); Moreira, Eduardo Ceretta, E-mail: eduardomoreira@unipampa.edu.br [Universidade Federal do Pampa, Campus Bagé, Grupo de Pesquisa em Espectroscopia de Materiais Fotônicos, 96400-970 Bagé, RS (Brazil)

    2014-12-15

    This study reports the experimental investigation of two photoactive aminobenzazole derivatives in the solid state by FT-Raman and Infrared Spectroscopies (FTIR) and its comparison with theoretical models. The optimized molecular structure, vibrational frequencies, and corresponding vibrational assignments of these compounds have been investigated experimentally and theoretically using Spanish Initiative for Electronic Simulations with Thousands of Atoms (SIESTA) and Gaussian03 Software Package. The FT-Raman and FTIR spectra were acquired with high resolution and emission frequencies identified by simulating the vibrational modes. The most intense peak observed in the FT-Raman spectra is the in-plane deformation vibrational of O–H bond that could be related to the vibrational region responsible for the stabilization of the enol conformer in the ground state which undergoes ESIPT to form a keto tautomer in the excited state. Additionally, the position of the amino group played an important role on the vibrational characteristics of the studied compounds. Also, the simulations proved to be a good approach in undertaking the FTIR and FT-Raman experiments. The use of graphic correlations helps us to determine the method and basis that best fit the experimental results. - Highlights: • Structural and vibrational properties of two aminobenzazoles were reported. • Comparison between experimental techniques and theoretical models. • The position of the amino group played an important role on the vibrational characteristics of the studied compounds.

  8. Vibrations of rotating machinery

    CERN Document Server

    Matsushita, Osami; Kanki, Hiroshi; Kobayashi, Masao; Keogh, Patrick

    2017-01-01

    This book opens with an explanation of the vibrations of a single degree-of-freedom (dof) system for all beginners. Subsequently, vibration analysis of multi-dof systems is explained by modal analysis. Mode synthesis modeling is then introduced for system reduction, which aids understanding in a simplified manner of how complicated rotors behave. Rotor balancing techniques are offered for rigid and flexible rotors through several examples. Consideration of gyroscopic influences on the rotordynamics is then provided and vibration evaluation of a rotor-bearing system is emphasized in terms of forward and backward whirl rotor motions through eigenvalue (natural frequency and damping ratio) analysis. In addition to these rotordynamics concerning rotating shaft vibration measured in a stationary reference frame, blade vibrations are analyzed with Coriolis forces expressed in a rotating reference frame. Other phenomena that may be assessed in stationary and rotating reference frames include stability characteristic...

  9. Vibrational lineshapes of adsorbates on solid surfaces

    Science.gov (United States)

    Ueba, H.

    A review is presented of the current activity in vibrational spectroscopy of adsorbates on metal surfaces. A brief introduction of the representative spectroscopies is given to demonstrate the rich information contained in vibrational spectra, which are characterized by their intensity, peak position and width. Analysis of vibrational spectra enables us to gain the deep insight into not only the local character of adsorption site or geometry, but also the dynamical interaction between the adsorbates or between the adsorbate and the substrate. Some recent instructive experimental results, mostly of a CO molecule adsorbed on various metal surfaces, are accompanied by the corresponding theoretical recipe for vibrational excitation mechanisms. Wide spread experimental results of the C-O stretching frequency of CO adsorbed on metal surfaces are discussed in terms of the chemical effect involving the static and dynamic charge transfers between the chemisorbed CO and metal, and also of the electrostatic dipole-dipole interaction between the molecules. The central subject of this review is directed to the linshapes characterized by the vibrational relaxation processes of adsorbates. A simple and transparent model is introduced to show that the characteristic decay time of the correlation function for the vibrational coordinates is the key quantity to determine the spectral lineshapes. Recent experimental results focused on a search for an intrinsic broadening mechanism are reviewed in the light of the so-called T1 (energy) and T2 (phase) relaxation processesof the vibrational excited states of adsorbates. Those are the vibrational energy dissipation into the elementary excitation, such as phonons or electron-hole pairs in the metal substrate, and pure dephasing due to the energy exchange with the sorroundings. The change of width and frequency by varying the experimental variables, such as temperature or isotope effect, provides indispensable knowledge for the dynamical

  10. On the influence of freight trains on humans: a laboratory investigation of the impact of nocturnal low frequency vibration and noise on sleep and heart rate.

    Science.gov (United States)

    Smith, Michael G; Croy, Ilona; Ogren, Mikael; Persson Waye, Kerstin

    2013-01-01

    A substantial increase in transportation of goods on railway may be hindered by public fear of increased vibration and noise leading to annoyance and sleep disturbance. As the majority of freight trains run during night time, the impact upon sleep is expected to be the most serious adverse effect. The impact of nocturnal vibration on sleep is an area currently lacking in knowledge. We experimentally investigated sleep disturbance with the aim to ascertain the impact of increasing vibration amplitude. The impacts of various amplitudes of horizontal vibrations on sleep disturbance and heart rate were investigated in a laboratory study. Cardiac accelerations were assessed using a combination of polysomnography and ECG recordings. Sleep was assessed subjectively using questionnaires. Twelve young, healthy subjects slept for six nights in the sleep laboratory, with one habituation night, one control night and four nights with a variation of vibration exposures whilst maintaining the same noise exposure. With increasing vibration amplitude, we found a decrease in latency and increase in amplitude of heart rate as well as a reduction in sleep quality and increase in sleep disturbance. We concluded that nocturnal vibration has a negative impact on sleep and that the impact increases with greater vibration amplitude. Sleep disturbance has short- and long-term health consequences. Therefore, it is necessary to define levels that protect residents against sleep disruptive vibrations that may arise from night time railway freight traffic.

  11. On the influence of freight trains on humans: a laboratory investigation of the impact of nocturnal low frequency vibration and noise on sleep and heart rate.

    Directory of Open Access Journals (Sweden)

    Michael G Smith

    Full Text Available BACKGROUND: A substantial increase in transportation of goods on railway may be hindered by public fear of increased vibration and noise leading to annoyance and sleep disturbance. As the majority of freight trains run during night time, the impact upon sleep is expected to be the most serious adverse effect. The impact of nocturnal vibration on sleep is an area currently lacking in knowledge. We experimentally investigated sleep disturbance with the aim to ascertain the impact of increasing vibration amplitude. METHODOLOGY/PRINCIPAL FINDINGS: The impacts of various amplitudes of horizontal vibrations on sleep disturbance and heart rate were investigated in a laboratory study. Cardiac accelerations were assessed using a combination of polysomnography and ECG recordings. Sleep was assessed subjectively using questionnaires. Twelve young, healthy subjects slept for six nights in the sleep laboratory, with one habituation night, one control night and four nights with a variation of vibration exposures whilst maintaining the same noise exposure. With increasing vibration amplitude, we found a decrease in latency and increase in amplitude of heart rate as well as a reduction in sleep quality and increase in sleep disturbance. CONCLUSIONS/SIGNIFICANCE: We concluded that nocturnal vibration has a negative impact on sleep and that the impact increases with greater vibration amplitude. Sleep disturbance has short- and long-term health consequences. Therefore, it is necessary to define levels that protect residents against sleep disruptive vibrations that may arise from night time railway freight traffic.

  12. Study on Vibration of Heavy-Precision Robot Cantilever Based on Time-varying Glowworm Swarm Optimization Algorithm

    Science.gov (United States)

    Luo, T. H.; Liang, S.; Miao, C. B.

    2017-12-01

    A method of terminal vibration analysis based on Time-varying Glowworm Swarm Optimization algorithm is proposed in order to solve the problem that terminal vibration of the large flexible robot cantilever under heavy load precision.The robot cantilever of the ballastless track is used as the research target and the natural parameters of the flexible cantilever such as the natural frequency, the load impact and the axial deformation is considered. Taking into account the change of the minimum distance between the glowworm individuals, the terminal vibration response and adaptability could meet. According to the Boltzmann selection mechanism, the dynamic parameters in the motion simulation process are determined, while the influence of the natural frequency and the load impact as well as the axial deformation on the terminal vibration is studied. The method is effective and stable, which is of great theoretical basis for the study of vibration control of flexible cantilever terminal.

  13. A Theoretically Consistent Method for Minimum Mean-Square Error Estimation of Mel-Frequency Cepstral Features

    DEFF Research Database (Denmark)

    Jensen, Jesper; Tan, Zheng-Hua

    2014-01-01

    the logarithmic which is usually used for MFCC computation. The proposed method shows estimation performance which is identical to or better than state-of-the-art methods. It further shows comparable ASR performance, where the advantage of being able to use mel-frequency speech features based on a power non......We propose a method for minimum mean-square error (MMSE) estimation of mel-frequency cepstral features for noise robust automatic speech recognition (ASR). The method is based on a minimum number of well-established statistical assumptions; no assumptions are made which are inconsistent with others...

  14. Probing crystal structure and mesoscale assembly of cellulose microfibrils in plant cell walls, tunicate tests, and bacterial films using vibrational sum frequency generation (SFG) spectroscopy.

    Science.gov (United States)

    Lee, Christopher M; Kafle, Kabindra; Park, Yong Bum; Kim, Seong H

    2014-06-14

    This study reports that the noncentrosymmetry and phase synchronization requirements of the sum frequency generation (SFG) process can be used to distinguish the three-dimensional organization of crystalline cellulose distributed in amorphous matrices. Crystalline cellulose is produced as microfibrils with a few nanometer diameters by plants, tunicates, and bacteria. Crystalline cellulose microfibrils are embedded in wall matrix polymers and assembled into hierarchical structures that are precisely designed for specific biological and mechanical functions. The cellulose microfibril assemblies inside cell walls are extremely difficult to probe. The comparison of vibrational SFG spectra of uniaxially-aligned and disordered films of cellulose Iβ nanocrystals revealed that the spectral features cannot be fully explained with the crystallographic unit structure of cellulose. The overall SFG intensity, the alkyl peak shape, and the alkyl/hydroxyl intensity ratio are sensitive to the lateral packing and net directionality of the cellulose microfibrils within the SFG coherence length scale. It was also found that the OH SFG stretch peaks could be deconvoluted to find the polymorphic crystal structures of cellulose (Iα and Iβ). These findings were used to investigate the cellulose crystal structure and mesoscale cellulose microfibril packing in intact plant cell walls, tunicate tests, and bacterial films.

  15. Studies of Heterogeneously Catalyzed Liquid-Phase Alcohol Oxidation on Platinum bySum-frequency Generation Vibrational Spectroscopy and Reaction Rate Measurements

    Energy Technology Data Exchange (ETDEWEB)

    Thompson, Christopher [Univ. of California, Berkeley, CA (United States)

    2014-05-15

    Compared to many branches of chemistry, the molecular level study of catalytically active surfaces is young. Only with the invention of ultrahigh vacuum technology in the past half century has it been possible to carry out experiments that yield useful molecular information about the reactive occurrences at a surface. The reason is two-fold: low pressure is necessary to keep a surface clean for an amount of time long enough to perform an experiment, and most atomic scale techniques that are surface speci c (x-ray photoelectron spectroscopy, electron energy loss spectroscopy, Auger electron spectroscopy, etc.) cannot be used at ambient pressures, because electrons, which act as chemical probes in these techniques, are easily scattered by molecules. Sum-frequency generation (SFG) vibrational spectroscopy is one technique that can provide molecular level information from the surface without the necessity for high vacuum. Since the advent of SFG as a surface spectroscopic tool it has proved its worth in the studies of surface catalyzed reactions in the gas phase, with numerous reactions in the gas phase having been investigated on a multitude of surfaces. However, in situ SFG characterization of catalysis at the solid-liquid interface has yet to be thoroughly pursued despite the broad interest in the use of heterogeneous catalysts in the liquid phase as replacements for homogeneous counterparts. This work describes an attempt to move in that direction, applying SFG to study the solid-liquid interface under conditions of catalytic alcohol oxidation on platinum.

  16. Phase transition behaviors of the supported DPPC bilayer investigated by sum frequency generation (SFG) vibrational spectroscopy and atomic force microscopy (AFM).

    Science.gov (United States)

    Wu, Heng-Liang; Tong, Yujin; Peng, Qiling; Li, Na; Ye, Shen

    2016-01-21

    The phase transition behaviors of a supported bilayer of dipalmitoylphosphatidyl-choline (DPPC) have been systematically evaluated by in situ sum frequency generation (SFG) vibrational spectroscopy and atomic force microscopy (AFM). By using an asymmetric bilayer composed of per-deuterated and per-protonated monolayers, i.e., DPPC-d75/DPPC and a symmetric bilayer of DPPC/DPPC, we were able to probe the molecular structural changes during the phase transition process of the lipid bilayer by SFG spectroscopy. It was found that the DPPC bilayer is sequentially melted from the top (adjacent to the solution) to bottom leaflet (adjacent to the substrate) over a wide temperature range. The conformational ordering of the supported bilayer does not decrease (even slightly increases) during the phase transition process. The conformational defects in the bilayer can be removed after the complete melting process. The phase transition enthalpy for the bottom leaflet was found to be approximately three times greater than that for the top leaflet, indicating a strong interaction of the lipids with the substrate. The present SFG and AFM observations revealed similar temperature dependent profiles. Based on these results, the temperature-induced structural changes in the supported lipid bilayer during its phase transition process are discussed in comparison with previous studies.

  17. Water Orientation at Ceramide/Water Interfaces Studied by Heterodyne-Detected Vibrational Sum Frequency Generation Spectroscopy and Molecular Dynamics Simulation

    KAUST Repository

    Adhikari, Aniruddha

    2016-10-10

    Lipid/water interaction is essential for many biological processes. The water structure at the nonionic lipid interface remains little known, and there is no scope of a priori prediction of water orientation at nonionic interfaces, either. Here, we report our study combining advanced nonlinear spectroscopy and molecular dynamics simulation on the water orientation at the ceramide/water interface. We measured χ spectrum in the OH stretch region of ceramide/isotopically diluted water interface using heterodyne-detected vibrational sum-frequency generation spectroscopy and found that the interfacial water prefers an overall hydrogen-up orientation. Molecular dynamics simulation indicates that this preferred hydrogen-up orientation of water is determined by a delicate balance between hydrogen-up and hydrogen-down orientation induced by lipid-water and intralipid hydrogen bonds. This mechanism also suggests that water orientation at neutral lipid interfaces depends highly on the chemical structure of the lipid headgroup, in contrast to the charged lipid interfaces where the net water orientation is determined solely by the charge of the lipid headgroup.

  18. Low energy electron diffraction (LEED) and sum frequency generation (SFG) vibrational spectroscopy studies of solid-vacuum, solid-air and solid-liquid interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Hoffer, Saskia [Univ. of California, Berkeley, CA (United States)

    2002-01-01

    Electron based surface probing techniques can provide detailed information about surface structure or chemical composition in vacuum environments. The development of new surface techniques has made possible in situ molecular level studies of solid-gas interfaces and more recently, solid-liquid interfaces. The aim of this dissertation is two-fold. First, by using novel sample preparation, Low Energy Electron Diffraction (LEED) and other traditional ultra high vacuum (UHV) techniques are shown to provide new information on the insulator/vacuum interface. The surface structure of the classic insulator NaCl has been determined using these methods. Second, using sum frequency generation (SFG) surface specific vibrational spectroscopy studies were performed on both the biopolymer/air and electrode/electrolyte interfaces. The surface structure and composition of polyetherurethane-silicone copolymers were determined in air using SFG, atomic force microscopy (AFM), and X-ray photoelectron spectroscopy (XPS). SFG studies of the electrode (platinum, gold and copper)/electrolyte interface were performed as a function of applied potential in an electrochemical cell.

  19. Surface structures of an amphiphilic tri-block copolymer in air and in water probed using sum frequency generation vibrational spectroscopy.

    Science.gov (United States)

    Kristalyn, Cornelius B; Lu, Xiaolin; Weinman, Craig J; Ober, Christopher K; Kramer, Edward J; Chen, Zhan

    2010-07-06

    Sum frequency generation (SFG) vibrational spectroscopy has been applied to investigate surface structures of an amphiphilic surface-active block copolymer (SABC) film deposited on a CaF(2) substrate, in air and in water in situ. Developed as a surface-active component of an antifouling coating for marine applications, this amphiphilic triblock copolymer contains both hydrophobic fluorinated alkyl groups as well as hydrophilic ethoxy groups. It was found that surface structures of the copolymer film in air and in water cannot be probed directly using the SFG experimental geometry we adopted because SFG signals can be contributed from the polymer/air (or polymer/water) interface as well as the buried polymer/CaF(2) substrate interface. Using polymer films with varied thicknesses, structural information about the polymer surfaces in air and in water can be deduced from the detected SFG signals. With SFG, surface restructuring of this polymer has been observed in water, especially the methyl and methylene groups change orientations upon contact with water. However, the hydrophobic fluoroalkyl group was present on the surface in both air and water, and we believe that it was held near the surface in water by its neighboring ethoxy groups.

  20. Analysis of the SERS spectrum by theoretical methodology: evaluating a classical dipole model and the detuning of the excitation frequency.

    Science.gov (United States)

    Hermida-Ramon, Jose M; Guerrini, Luca; Alvarez-Puebla, Ramon A

    2013-06-06

    Surface-enhanced Raman scattering (SERS) spectroscopy is gaining prominence as one of the most powerful ultradetection techniques. The SERS outcome is essentially a complicated pattern of vibrational bands that allows multiplex analysis but, at the same time, makes difficult the interpretation of unknown analytes or known substances in the presence of complex unknown chemical environments. Herein, we show two computational methods to reproduce the spectral shape of the SERS spectra. The first, based in the modification of the classical dipole model, reproduces with a notable similarity the experimental spectrum excited far to the red of the localized surface plasmon resonance (LSPR). This light and time-efficient model is of great interest to elucidate the orientation of the target on the plasmonic surface or even to accurately identify suspected unknown targets in real samples. However, the experimental SERS spectrum in resonance with the LSPR is also modeled by using a more classical CPHF approach. This method provides also good agreement with the experiment but at the expense of much more computational time.

  1. Field dependence of the magnetic eigenmode frequencies in layered nanowires with ferromagnetic and antiferromagnetic ground states: experimental and theoretical study

    Science.gov (United States)

    Gubbiotti, G.; Nguyen, H. T.; Hiramatsu, R.; Tacchi, S.; Madami, M.; Cottam, M. G.; Ono, T.

    2014-09-01

    The magnetic field dependence of the magnetic eigenmode frequencies in 150 nm wide layered permalloy nanowires (NWs) has been studied by the Brillouin light scattering technique. The NWs have the following layering structure Py(30 nm)/Cu(10 nm)/Py(d)/Cu(10 nm)/Py(30 nm) with fixed thickness of the top and bottom stripe and differ by the thickness d of the middle Py stripe (with d = 15, 30, 60 nm). The magnetic field, applied along the length of the wires, has been swept from positive to negative saturation thus exploring both the ferromagnetic and the antiferromagnetic relative orientation of the magnetization in the middle stripe with respect to the outermost ones. In conjunction with the transition between the two different ground states, the mode frequencies undergo an abrupt variation. Moreover the mode frequencies in the antiferromagnetic state are relatively insensitive to the applied field strength. The experimental results (frequencies versus magnetic field strength) have been successfully interpreted by means of a microscopic (Hamiltonian-based) theory which incorporates both the exchange and dipole-dipole interactions as well as effects of single-ion anisotropy and an external magnetic field applied parallel to the NW axis. This model was extended to account for parallel and antiparallel magnetization orientations in the layered NWs, enabling us to also calculate the probability amplitude of each spin-wave eigenmode at any position in the trilayered NWs.

  2. Development of a semi-active dynamic vibration absorber for longitudinal vibration of propulsion shaft system based on magnetorheological elastomer

    Science.gov (United States)

    Liu, Gaoyu; Lu, Kun; Zou, Donglin; Xie, Zhongliang; Rao, Zhushi; Ta, Na

    2017-07-01

    The control of the longitudinal pulsating force and the vibration generated is very important to improve the stealth performance of a submarine. Magnetorheological elastomer (MRE) is a kind of intelligent composite material, whose mechanical properties can be continuously, rapidly and reversibly controlled by an external magnetic field. It can be used as variable-stiffness components in the design of a semi-active dynamic vibration absorber (SDVA), which is one of the effective means of longitudinal vibration control. In this paper, an SDVA is designed based on the MRE’s magnetic-induced variable stiffness characteristic. Firstly, a mechanical model of the propulsion shaft system with the SDVA is proposed, theoretically discussed and numerically validated. Then, the mechanical performance of the MRE under different magnetic fields is tested. In addition, the magnetic circuit and the overall structure of the SDVA are designed. Furthermore, electromagnetic and thermodynamic simulations are carried out to guarantee the structural design. The frequency shift property of the SDVA is found through dynamic simulations and validated by a frequency shift experiment. Lastly, the vibration absorption capacity of the SDVA is investigated. The results show that the magnetorheological effect of the MRE and the frequency shift of the SDVA are obvious; the SDVA has relatively acceptable vibration absorption capacity.

  3. Vibrations in glasses and Euclidean random matrix theory

    Energy Technology Data Exchange (ETDEWEB)

    Grigera, T.S.; Martin-Mayor, V.; Parisi, G. [Dipartimento di Fisica, Universita di Roma ' La Sapienza' , Rome (Italy); INFN Sezione di Roma - INFM Unita di Roma, Rome (Italy); Verrocchio, P. [Dipartimento di Fisica, Universita di Trento, Povo, Trento (Italy); INFM Unita di Trento, Trento (Italy)

    2002-03-11

    We study numerically and analytically a simple off-lattice model of scalar harmonic vibrations by means of Euclidean random matrix theory. Since the spectrum of this model shares the most puzzling spectral features with the high-frequency domain of glasses (non-Rayleigh broadening of the Brillouin peak, boson peak and secondary peak), Euclidean random matrix theory provides a single and fairly simple theoretical framework for their explanation. (author)

  4. The effects of isomerism on the vibrational spectra and thermodynamic characteristics of biuret in the gas phase

    Science.gov (United States)

    Korolevich, M. V.; Lastochkina, V. A.; Frenkel, M. L.; Kabo, G. Ya.; Zhbankov, R. G.

    1991-03-01

    A theoretical study of the IR spectra of cis- and trans-isomers of biuret, based on coupled calculations of vibrational frequencies as a valence force field approximation and of absorption band intensities by the CNDO/2 method, is reported. Calculated thermodynamic functions for biuret agreed with experimental thermochemical data. For calculating the vibrations of an isolated biuret molecule, the experimental vapour-phase IR absorption spectra were used.

  5. Vibration energy harvesting using piezoelectric unimorph cantilevers with unequal piezoelectric and nonpiezoelectric lengths.

    Science.gov (United States)

    Gao, Xiaotong; Shih, Wei-Heng; Shih, Wan Y

    2010-12-06

    We have examined a piezoelectric unimorph cantilever (PUC) with unequal piezoelectric and nonpiezoelectric lengths for vibration energy harvesting theoretically by extending the analysis of a PUC with equal piezoelectric and nonpiezoelectric lengths. The theoretical approach was validated by experiments. A case study showed that for a fixed vibration frequency, the maximum open-circuit induced voltage which was important for charge storage for later use occurred with a PUC that had a nonpiezoelectric-to-piezoelectric length ratio greater than unity, whereas the maximum power when the PUC was connected to a resistor for immediate power consumption occurred at a unity nonpiezoelectric-to-piezoelectric length ratio.

  6. The classical and theoretical simulation for dominant radiated frequencies of plasma nanowire in presence of a long monopole antenna with long wavelength radiation

    Science.gov (United States)

    Safari, S.; Jazi, B.

    2017-05-01

    A theoretical model based on the classical theory for the simulation of scattering phenomena of long wavelength electromagnetic waves from plasma nanowires is investigated. A line source as a monopole antenna radiator is considered, which radiates with frequency ω in the vicinity of plasma nanowires parallel to the nanowire axis. A mathematical relation for resonance frequency is obtained. It is shown that in the resonance situation, plasma nanowires represent most of the response to the presence of electromagnetic waves. Mathematical computations are done for both the cold and warm approximations of plasma cases. The diagrams of the variation of resonance frequency versus the variation of temperature, geometrical dimension, and carrier density of plasma nanowires are presented. Also, a mathematical relation for subsidiary resonance frequency with considering two line sources with opposite charge is offered. The diagrams of subsidiary resonance frequency versus the variation of temperature, geometrical dimension, and carrier density of plasma nanowires are presented. It is shown that the presented model provides a color diagnostic system for the determination of size, the number, and distribution of nanowires immersed in a fluid based on their temperature and geometrical dimension.

  7. Theoretical study of collinear optical frequency comb generation under multi-wave, transient stimulated Raman scattering in crystals

    Energy Technology Data Exchange (ETDEWEB)

    Smetanin, S N [A M Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

    2014-11-30

    Using mathematical modelling we have studied the conditions of low-threshold collinear optical frequency comb generation under transient (picosecond) stimulated Raman scattering (SRS) and parametric four-wave coupling of SRS components in crystals. It is shown that Raman-parametric generation of an octave-spanning optical frequency comb occurs most effectively under intermediate, transient SRS at a pump pulse duration exceeding the dephasing time by five-to-twenty times. We have found the optimal values of not only the laser pump pulse duration, but also of the Raman crystal lengths corresponding to highly efficient generation of an optical frequency comb from the second anti-Stokes to the fourth Stokes Raman components. For the KGd(WO{sub 4}){sub 2} (high dispersion) and Ba(NO{sub 3}){sub 2} (low dispersion) crystals pumped at a wavelength of 1.064 μm and a pulse duration five or more times greater than the dephasing time, the optimum length of the crystal was 0.3 and 0.6 cm, respectively, which is consistent with the condition of the most effective Stokes – anti-Stokes coupling ΔkL ≈ 15, where Δk is the wave detuning from phase matching of Stokes – anti-Stokes coupling, determined by the refractive index dispersion of the SRS medium. (nonlinear optical phenomena)

  8. Vibrational spectroscopy modeling of a drug in molecular solvents and enzymes

    Science.gov (United States)

    Devereux, Christian J.; Fulfer, Kristen D.; Zhang, Xiaoliu; Kuroda, Daniel G.

    2017-09-01

    Modeling of drugs in enzymes is of immensurable value to many areas of science. We present a theoretical study on the vibrational spectroscopy of Rilpivirine, a HIV reverse transcriptase inhibitor, in conventional solvents and in clinically relevant enzymes. The study is based on vibrational spectroscopy modeling of the drug using molecular dynamics simulations, DFT frequency maps, and theory. The modeling of the infrared lineshape shows good agreement with experimental data for the drug in molecular solvents where the local environment motions define the vibrational band lineshape. On the other hand, the theoretical description of the drug in the different enzymes does not match previous experimental findings indicating that the utilized methodology might not apply to heterogeneous environments. Our findings show that the lack of reproducibility might be associated with the development of the frequency map which does not contain all of the possible interactions observed in such systems.

  9. Vibrational spectra (experimental and theoretical), molecular structure, natural bond orbital, HOMO-LUMO energy, Mulliken charge and thermodynamic analysis of N'-hydroxy-pyrimidine-2-carboximidamide by DFT approach.

    Science.gov (United States)

    Jasmine, N Jeeva; Muthiah, P Thomas; Arunagiri, C; Subashini, A

    2015-06-05

    The FT-IR, FT-Raman, (1)H, (13)C NMR and UV-Visible spectral measurements of N'-hydroxy-pyrimidine-2-carboximidamide (HPCI) and complete analysis of the observed spectra have been proposed. DFT calculation has been performed and the structural parameters of the compound was determined from the optimized geometry with 6-311+G(d,p) basis set and giving energies, harmonic vibrational frequencies and force constants. The results of the optimized molecular structure are presented and compared with the experimental. The geometric parameters, harmonic vibrational frequencies and chemical shifts were compared with the experimental data of the molecule. The title compound, C5H6N4O, is approximately planar, with an angle of 11.04 (15)°. The crystal structure is also stabilized by intermolecular N-H⋯O, N-H⋯N, O-H⋯N, C-H⋯O hydrogen bond and offset π-π stacking interactions. The influences of hydroxy and carboximidamide groups on the skeletal modes and proton chemical shifts have been investigated. Moreover, we have not only simulated highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) but also determined the transition state and band gap. The kinetic, thermodynamic stability and chemical hardness of the molecule have been determined. Complete NBO analysis was also carried out to find out the intermolecular electronic interactions and their stabilization energy. The thermodynamic properties like entropies and their correlations with temperatures were also obtained from the harmonic frequencies of the optimized structure. Copyright © 2015 Elsevier B.V. All rights reserved.

  10. Benchmark Structures and Harmonic Vibrational Frequencies Near the CCSD(T) Complete Basis Set Limit for Small Water Clusters: (H2O)n = 2, 3, 4, 5, 6.

    Science.gov (United States)

    Howard, J Coleman; Tschumper, Gregory S

    2015-05-12

    A series of (H2O)n clusters ranging from the dimer to the hexamer have been characterized with the CCSD(T) and the 2-body:Many-body CCSD(T):MP2 methods near the complete basis set (CBS) limit to generate benchmark-quality optimized structures and harmonic vibrational frequencies for these important systems. Quadruple-ζ correlation-consistent basis sets that augment the O atoms with diffuse functions have been employed in the analytic computation of harmonic vibrational frequencies for the global minima of the dimer, trimer, tetramer, and pentamer as well as the ring, book, cage, and prism isomers of the hexamer. Prior calibration [J. Chem. Phys. 2013, 139, 184113 and J. Chem. Theory Comput. 2014, 10, 5426] suggests that harmonic frequencies computed with this approach will lie within a few cm(-1) of the canonical CCSD(T) CBS limit. These data are used as reference values to gauge the performance of harmonic frequencies obtained with other ab initio methods (e.g., LCCSD(T) and MP2) and water potentials (e.g., TTM3-F and WHBB). This comparison reveals that it is far more challenging to converge harmonic vibrational frequencies for the bound OH stretching modes in these (H2O)n clusters to the CCSD(T) CBS limit than the free OH stretches, the n intramonomer HOH bending modes and even the 6n - 6 intermonomer modes. Deviations associated with the bound OH stretching harmonic frequencies increase rapidly with the size of the cluster for all methods and potentials examined, as do the corresponding frequency shifts relative to the monomer OH stretches.

  11. Vibration characteristics of an ultrasonic transducer of two piezoelectric discs.

    Science.gov (United States)

    Piao, Chunguang; Kim, Jin Oh

    2017-02-01

    This paper considers the influence of the different thickness of the piezoelectric discs used in assembly of an ultrasonic sandwich transducer. The transducer consists of two piezoelectric discs with different thickness between 0 and 2.0mm and with same diameter 28mm. Its vibration characteristics of the radial and axial motions were investigated theoretically and experimentally in axisymmetric vibration modes. Theoretically, the differential equations of piezoelectric motions were solved to produce characteristic equations that provided natural frequencies and mode shapes. The range of the fundamental frequency of radial in-plane mode is 80-360kHz and that of the axial out-of-plane mode is 600-1200kHz. Experimentally, the natural frequencies and the radial in-plane motion were measured using an impedance analyzer and an in-plane laser interferometer, respectively. The results of the theoretical analysis were compared with those of a finite-element analysis and experiments, and the theoretical analysis was verified on the basis of this comparison. It was concluded that the natural frequencies of the radial modes of the transducer were not affected by the stack and thickness of piezoelectric discs; however, those of the thickness modes were affected by the stack and thickness of the piezoelectric discs. Copyright © 2016 Elsevier B.V. All rights reserved.

  12. Theoretical oscillation frequencies for solar-type dwarfs from stellar models with 〈3D〉-atmospheres

    Science.gov (United States)

    Jørgensen, Andreas Christ Sølvsten; Weiss, Achim; Mosumgaard, Jakob Rørsted; Silva Aguirre, Victor; Sahlholdt, Christian Lundsgaard

    2017-12-01

    We present a new method for replacing the outermost layers of stellar models with interpolated atmospheres based on results from 3D simulations, in order to correct for structural inadequacies of these layers. This replacement is known as patching. Tests, based on 3D atmospheres from three different codes and interior models with different input physics, are performed. Using solar models, we investigate how different patching criteria affect the eigenfrequencies. These criteria include the depth, at which the replacement is performed, the quantity, on which the replacement is based, and the mismatch in Teff and log g between the un-patched model and patched 3D atmosphere. We find the eigenfrequencies to be unaltered by the patching depth deep within the adiabatic region, while changing the patching quantity or the employed atmosphere grid leads to frequency shifts that may exceed 1 μHz. Likewise, the eigenfrequencies are sensitive to mismatches in Teff or log g. A thorough investigation of the accuracy of a new scheme, for interpolating mean 3D stratifications within the atmosphere grids, is furthermore performed. Throughout large parts of the atmosphere grids, our interpolation scheme yields sufficiently accurate results for the purpose of asteroseismology. We apply our procedure in asteroseismic analyses of four Kepler stars and draw the same conclusions as in the solar case: Correcting for structural deficiencies lowers the eigenfrequencies, this correction is slightly sensitive to the patching criteria, and the remaining frequency discrepancy between models and observations is less frequency dependent. Our work shows the applicability and relevance of patching in asteroseismology.

  13. Effects of 8 weeks of vibration training at different frequencies (1 or 15 Hz) in senior sportsmen on torque and force development and of 1 year of training on muscle fibers.

    Science.gov (United States)

    Kern, H; Kovarik, J; Franz, C; Vogelauer, M; Löfler, S; Sarabon, N; Grim-Stieger, M; Biral, D; Adami, N; Carraro, U; Zampieri, S; Hofer, Ch

    2010-02-01

    To examine the effects of 8 weeks of vibration training at different frequencies (1 and 15 Hz) on maximal isometric torque and force development in senior sportsmen, and of 1 year of heavy-resistance and vibration trainings on muscle fibers. Seven healthy senior sportsmen (mean age: 69.0 +/- 5.4 years) performed an 8 weeks of strength training of knee extensors. Vibrations were applied vertically to the axis of movement during training. One leg of each subject was trained at a frequency of 1 Hz, while the other leg was trained at 15 Hz. Measures of isometric peak torque (at knee-angles of 60, 90 and 120 degrees ) and force development were recorded before and after training. Four sportsmen continued a year-long heavy-resistance training adding every second week a session of vibration training. After training, muscle biopsies were harvested from their quadriceps muscles and used for structural analyses. Morphometry of muscle fibers was performed by light microscopy. Immunohistochemistry using anti-MHCemb and anti-N-CAM antibodies was performed to measure potential muscle damage. Data from muscle morphometry were compared to that of a series of vastus lateralis biopsies harvested from 12 young sportsmen and four healthy elderly. Our results showed a significant increase in isometric peak torque at both 1 and 15 Hz vibration frequency in all three measured angles of the knee. There was no significant difference between the two frequencies, but we could find a higher increase in percentage of maximum power after the 1 Hz training. The results of force development showed a slight increase at the 1 Hz training in measured time frames from 0 to 50 and 200 ms, without statistical significance. A trend to significance was found at the 1 Hz training at the time window up to 200 ms. The 15 Hz training showed no significant changes of force development. Muscle biopsies show that the muscles of these well trained senior sportsmen contain muscle fibers which are 35% larger than

  14. Radiation impedance and equivalent circuit for piezoelectric ultrasonic composite transducers of vibrational mode-conversion.

    Science.gov (United States)

    Lin, Shuyu

    2012-01-01

    The piezoelectric ultrasonic composite transducer, which can be used in either gas or liquid media, is studied in this paper. The composite transducer is composed of a longitudinal sandwich piezoelectric transducer, a mechanical transformer, and a metal circular plate in flexural vibration. Acoustic radiation is produced by the flexural circular plate, which is excited by the longitudinal sandwich transducer and transformer. Based on the classic flexural theory of plates, the equivalent lumped parameters for a plate in axially symmetric flexural vibration with free boundary conditions are obtained. The radiation impedance of the plate is derived and the relationship between the radiation impedance and the frequency is analyzed. The equivalent circuits for the plate in flexural vibration and the composite transducer are given. The vibrational modes and the harmonic response of the composite piezoelectric transducer are simulated by the numerical method. Based on the theoretical and numerical analysis, two composite piezoelectric ultrasonic transducers are designed and manufactured, their admittance-frequency curves are measured, and the resonance frequency is obtained. The flexural vibrational displacement distribution of the transducer is measured with a laser scanning vibrometer. It is shown that the theoretical results are in good agreement with the measured resonance frequency and the displacement distribution. © 2012 IEEE

  15. A Semi-Analytical Solution for the Thickness-Vibration of Centrally Partially-Electroded Circular AT-Cut Quartz Resonators

    Science.gov (United States)

    Wang, Bin; Dai, Xiaoyun; Zhao, Xintao; Qian, Zhenghua

    2017-01-01

    Vibration frequencies and modes for the thickness-shear vibrations of infinite partially-electroded circular AT-cut quartz plates are obtained by solving the two-dimensional (2D) scalar differential equation derived by Tiersten and Smythe. The Mathieu and modified Mathieu equations are derived from the governing equation using the coordinate transform and the collocation method is used to deal with the boundary conditions. Solutions of the resonant frequencies and trapped modes are validated by those results obtained from COMSOL software. The current study provides a theoretical way for figuring out the vibration analysis of circular quartz resonators. PMID:28783124

  16. Quality Structures, Vibrational Frequencies, and Thermochemistry of the Products of Reaction of BrHg(•) with NO2, HO2, ClO, BrO, and IO.

    Science.gov (United States)

    Jiao, Yuge; Dibble, Theodore S

    2015-10-22

    Quantum chemical calculations have been carried out to investigate the structures, vibrational frequencies, and thermochemistry of the products of BrHg(•) reactions with atmospherically abundant radicals Y(•) (Y = NO2, HO2, ClO, BrO, or IO). The coupled cluster method with single and double excitations (CCSD), combined with relativistic effective core potentials, is used to determine the equilibrium geometries and harmonic vibrational frequencies of BrHgY species. The BrHg-Y bond energies are refined using CCSD with a noniterative estimate of the triple excitations (CCSD(T)) combined with core-valence correlation consistent basis sets. We also assess the performances of various DFT methods for calculating molecular structures and vibrational frequencies of BrHgY species. We attempted to estimate spin-orbit coupling effects on bond energies computed by comparing results from standard and two-component spin-orbit density functional theory (DFT) but obtained unphysical results. The results of the present work will provide guidance for future studies of the halogen-initiated chemistry of mercury.

  17. Vibrational modes of nanolines

    Science.gov (United States)

    Heyliger, Paul R.; Flannery, Colm M.; Johnson, Ward L.

    2008-04-01

    Brillouin-light-scattering spectra previously have been shown to provide information on acoustic modes of polymeric lines fabricated by nanoimprint lithography. Finite-element methods for modeling such modes are presented here. These methods provide a theoretical framework for determining elastic constants and dimensions of nanolines from measured spectra in the low gigahertz range. To make the calculations feasible for future incorporation in inversion algorithms, two approximations of the boundary conditions are employed in the calculations: the rigidity of the nanoline/substrate interface and sinusoidal variation of displacements along the nanoline length. The accuracy of these approximations is evaluated as a function of wavenumber and frequency. The great advantage of finite-element methods over other methods previously employed for nanolines is the ability to model any cross-sectional geometry. Dispersion curves and displacement patterns are calculated for modes of polymethyl methacrylate nanolines with cross-sectional dimensions of 65 nm × 140 nm and rectangular or semicircular tops. The vibrational displacements and dispersion curves are qualitatively similar for the two geometries and include a series of flexural, Rayleigh-like, and Sezawa-like modes. This paper is a contribution of the National Institute of Standards and Technology and is not subject to copyright in the United States.

  18. Concepts for a theoretical and experimental study of lifting rotor random loads and vibrations (further experiments with progressing/regressing rotor flapping modes), Phase 7-C

    Science.gov (United States)

    Hohenemser, K. H.; Crews, S. T.

    1973-01-01

    The experiments with progressing/regressing forced rotor flapping modes have been extended in several directions and the data processing method has been considerably refined. The 16 inch hingeless 2-bladed rotor model was equipped with a new set of high precision blades which removed previously encountered tracking difficulties at high advance ratio, so that tests up to .8 rotor advance ratio could be conducted. In addition to data with 1.20 blade natural flapping frequency data at 1.10 flapping frequency were obtained. Outside the wind tunnel, tests with a ground plate located at different distances below the rotor were conducted while recording the dynamic downflow at a station .2R below the rotor plane with a hot wire anemometer.

  19. Theoretical and Experimental Study of Radial Velocity Generation for Extending Bandwidth of Magnetohydrodynamic Angular Rate Sensor at Low Frequency

    Directory of Open Access Journals (Sweden)

    Yue Ji

    2015-12-01

    Full Text Available The magnetohydrodynamics angular rate sensor (MHD ARS has received much attention for its ultra-low noise in ultra-broad bandwidth and its impact resistance in harsh environments; however, its poor performance at low frequency hinders its work in long time duration. The paper presents a modified MHD ARS combining Coriolis with MHD effect to extend the measurement scope throughout the whole bandwidth, in which an appropriate radial flow velocity should be provided to satisfy simplified model of the modified MHD ARS. A method that can generate radial velocity by an MHD pump in MHD ARS is proposed. A device is designed to study the radial flow velocity generated by the MHD pump. The influence of structure and physical parameters are studied by numerical simulation and experiment of the device. The analytic expression of the velocity generated by the energized current drawn from simulation and experiment are consistent, which demonstrates the effectiveness of the method generating radial velocity. The study can be applied to generate and control radial velocity in modified MHD ARS, which is essential for the two effects combination throughout the whole bandwidth.

  20. A theoretical study on the frequency-dependent electric conductivity of electrolyte solutions. II. Effect of hydrodynamic interaction.

    Science.gov (United States)

    Yamaguchi, T; Matsuoka, T; Koda, S

    2009-03-07

    The theory on the frequency-dependent electric conductivity of electrolyte solutions proposed previously by Yamaguchi et al. [J. Chem. Phys. 127, 234501 (2007)] is extended to include the hydrodynamic interaction between ions. The theory is applied to the aqueous solution of NaCl and the concentration dependence of the conductivity agrees well with that determined by experiments. The effects of the hydrodynamic and relaxation effects are highly nonadditive in the concentrated solution, because the hydrodynamic interaction between ions affects the time-dependent response of the ionic atmosphere. The decrease in the electric conductivity is divided into the contributions of ion pair distribution at various distances. The long-range ionic atmosphere plays a major role at the concentration as low as 0.01 mol/kg, whereas the contribution of the contact ion pair region is important at 1 mol/kg. The magnitude of the contribution of the contact ion pair region is scarcely dependent on the presence of the hydrodynamic interaction. The transport number of cation is calculated to be a decreasing function of concentration as is observed in experiments.

  1. Vibrational spectroscopy of resveratrol

    Science.gov (United States)

    Billes, Ferenc; Mohammed-Ziegler, Ildikó; Mikosch, Hans; Tyihák, Ernő

    2007-11-01

    In this article the authors deal with the experimental and theoretical interpretation of the vibrational spectra of trans-resveratrol (3,5,4'-trihydroxy- trans-stilbene) of diverse beneficial biological activity. Infrared and Raman spectra of the compound were recorded; density functional calculations were carried out resulting in the optimized geometry and several properties of the molecule. Based on the calculated force constants, a normal coordinate analysis yielded the character of the vibrational modes and the assignment of the measured spectral bands.

  2. Vibrational anomalies and marginal stability of glasses

    KAUST Repository

    Marruzzo, Alessia

    2013-01-01

    The experimentally measured vibrational spectrum of glasses strongly deviates from that expected in Debye\\'s elasticity theory: The density of states deviates from Debye\\'s ω2 law ("boson peak"), the sound velocity shows a negative dispersion in the boson-peak frequency regime, and there is a strong increase in the sound attenuation near the boson-peak frequency. A generalized elasticity theory is presented, based on the model assumption that the shear modulus of the disordered medium fluctuates randomly in space. The fluctuations are assumed to be uncorrelated and have a certain distribution (Gaussian or otherwise). Using field-theoretical techniques one is able to derive mean-field theories for the vibrational spectrum of a disordered system. The theory based on a Gaussian distribution uses a self-consistent Born approximation (SCBA),while the theory for non-Gaussian distributions is based on a coherent-potential approximation (CPA). Both approximate theories appear to be saddle-point approximations of effective replica field theories. The theory gives a satisfactory explanation of the vibrational anomalies in glasses. Excellent agreement of the SCBA theory with simulation data on a soft-sphere glass is reached. Since the SCBA is based on a Gaussian distribution of local shear moduli, including negative values, this theory describes a shear instability as a function of the variance of shear fluctuations. In the vicinity of this instability, a fractal frequency dependence of the density of states and the sound attenuation ∝ ω1+a is predicted with a ≲ 1/2. Such a frequency dependence is indeed observed both in simulations and in experimental data. We argue that the observed frequency dependence stems from marginally stable regions in a glass and discuss these findings in terms of rigidity percolation. © 2013 EDP Sciences and Springer.

  3. Experimental and Theoretical Studies of the Vibrational and Electronic Properties of (2E-2-[3-(1H-imidazol-1-yl-1-phenyl-propylidene]-N-phenylhydrazinecarboxamide: An Anticonvulsant Agent

    Directory of Open Access Journals (Sweden)

    Munusamy Govindarajan

    2015-10-01

    Full Text Available In the current investigation, the molecular structure of the anticonvulsant agent (2E-2-[3-(1H-imidazol-1-yl-1-phenylpropylidene]-N-phenylhydrazinecarboxamide ((2E-HIPC was theoretically modelled using ab initio Hartree-Fock (HF and density functional theory (DFT/B3LYP calculations. The Fourier transform (FT infrared and FT-Raman spectra of (2E-HIPC were also recorded, and the observed bands were assigned to the vibrational normal modes. The main functional groups were identified via vibrational analysis, and their absorption bands were assigned. A comparative analysis was performed for the computed and experimental results. Subtle differences were observed between the calculated and experimental UV-Vis spectra. Time-dependent density functional theory (TD-DFT excitation energies were calculated for five excited electronic states. The calculations were applied to simulate the spectra of (2E-HIPC, and these simulated spectra exhibited excellent agreement with the experimental spectra. The DFT/B3LYP/6-311++G(d,p method, after scaling, exhibited better agreement with the experimental values than the results obtained by the HF method. The energy, oscillator strength, and wavelength computed by TD-DFT (IEFPCM are consistent with the experimental results. The molecular electrostatic potential (MEP and frontier molecular orbitals (HOMO-LUMO were also determined to enable prediction of the structural changes and reactive sites. Mulliken population charges of the title molecule were also calculated in the gas phase. The NMR chemical shifts (13C and 1H were calculated using the gauge-including atomic orbital method and the B3LYP/6-311++G(d,p approach and were compared with the experimental values.

  4. Experimental Study of Vibration Isolation Characteristics of a Geometric Anti-Spring Isolator

    Directory of Open Access Journals (Sweden)

    Lixun Yan

    2017-07-01

    Full Text Available In order to realize low-frequency vibration isolation, a novel geometric anti-spring isolator consisting of several cantilever blade springs are developed in this paper. The optimal design parameters of the geometric anti-spring isolator for different nonlinear geometric parameters are theoretically obtained. The transmissibility characteristic of the geometric anti-spring isolator is investigated through mathematical simulation. A geometric anti-spring isolator with a nonlinear geometric parameter of 0.92 is designed and its vibration isolation performance and nonlinearity characteristic is experimentally studied. The experiment results show that the designed isolator has good low-frequency vibration isolation performance, of which the initial isolation frequency is less than 3.6 Hz when the load weight is 21 kg. The jump phenomena of the response of the isolator under linear frequency sweep excitation are observed, and this result demonstrates that the geometric anti-spring isolator has a complex nonlinearity characteristics with the increment of excitation amplitude. This research work provides a theoretical and experimental basis for the application of the nonlinear geometric anti-spring low-frequency passive vibration isolation technology in engineering practice.

  5. Rabi-vibronic resonance with large number of vibrational quanta

    OpenAIRE

    Glenn, R.; Raikh, M. E.

    2011-01-01

    We study theoretically the Rabi oscillations of a resonantly driven two-level system linearly coupled to a harmonic oscillator (vibrational mode) with frequency, \\omega_0. We show that for weak coupling, \\omega_p \\ll \\omega_0, where \\omega_p is the polaronic shift, Rabi oscillations are strongly modified in the vicinity of the Rabi-vibronic resonance \\Omega_R = \\omega_0, where \\Omega_R is the Rabi frequency. The width of the resonance is (\\Omega_R-\\omega_0) \\sim \\omega_p^{2/3} \\omega_0^{1/3} ...

  6. Active and passive vibration isolation in piezoelectric phononic rods with external voltage excitation

    Directory of Open Access Journals (Sweden)

    Qicheng Zhang

    2017-05-01

    Full Text Available Active piezoelectric materials are applied to one-dimensional phononic crystals, for the control of longitudinal vibration propagation both in active and passive modes. Based on the electromechanical coupling between the acoustical vibration and electric field, the electromechanical equivalent method is taken to theoretically predict the transmission spectrum of the longitudinal vibration. It is shown that the phononic rod can suppress the vibration efficiently at the frequencies of interest, by actively optimizing the motions of piezoelectric elements. In an illustrated phononic rod of 11.2cm long, active tunable isolations of more than 20dB at low frequencies (500Hz-14kHz are generated by controlling the excitation voltages of piezoelectric elements. Meanwhile, passive fixed isolation at high frequencies (14k-63kHz are presented by its periodicity characteristics. Finite element simulations and vibration experiments on the rod demonstrate the effectiveness of the approach in terms of its vibration isolation capabilities and tunable characteristics. This phononic rod can be manufactured easily and provides numerous potential applications in designing isolation mounts and platforms.

  7. The origins of vibration theory

    Science.gov (United States)

    Dimarogonas, A. D.

    1990-07-01

    The Ionian School of natural philosophy introduced the scientific method of dealing with natural phenomena and the rigorous proofs for abstract propositions. Vibration theory was initiated by the Pythagoreans in the fifth century BC, in association with the theory of music and the theory of acoustics. They observed the natural frequency of vibrating systems and proved that it is a system property and that it does not depend on the excitation. Pythagoreans determined the fundamental natural frequencies of several simple systems, such as vibrating strings, pipes, vessels and circular plates. Aristoteles and the Peripatetic School founded mechanics and developed a fundamental understanding of statics and dynamics. In Alexandrian times there were substantial engineering developments in the field of vibration. The pendulum as a vibration, and probably time, measuring device was known in antiquity, and was further developed by the end of the first millennium AD.

  8. Frequency and damping ratio assessment of high-rise buildings using an Automatic Model-Based Approach applied to real-world ambient vibration recordings

    Science.gov (United States)

    Nasser, Fatima; Li, Zhongyang; Gueguen, Philippe; Martin, Nadine

    2016-06-01

    This paper deals with the application of the Automatic Model-Based Approach (AMBA) over actual buildings subjected to real-world ambient vibrations. In a previous paper, AMBA was developed with the aim of automating the estimation process of the modal parameters and minimizing the estimation error, especially that of the damping ratio. It is applicable over a single-channel record, has no parameters to be set, and no manual initialization phase. The results presented in this paper should be regarded as further documentation of the approach over real-world ambient vibration signals.

  9. On the mechanical coupling of a fiber optic cable used for distributed acoustic/vibration sensing applications—a theoretical consideration

    Science.gov (United States)

    Reinsch, Thomas; Thurley, Tom; Jousset, Philippe

    2017-12-01

    In recent years, fiber optic cables are increasingly used for the acquisition of dynamic strain changes for seismic surveys. When considering seismic amplitudes, one of the first questions arising is the mechanical coupling between optical fiber and the surrounding medium. Here we analyse the interaction of ground movement with a typical telecom-grade fiber optic cable from an existing telecommunication network deployed in a sand filled trench at the surface. Within the cable, the optical fiber is embedded in a gel-filled plastic tube. We apply Hooke’s law to calculate the stress needed to strain the optical fiber throughout the cable structure. In case the stress magnitude at the cable–sand interface as well as the gel–optical fiber interface is below the yield strength of the respective material, sand and gel, it can be regarded as an elastic medium. Hence, a multilayer radial symmetric model can be used to calculate the coupling of the optical fiber with the surrounding medium. We show that the transfer function has a -3 dB lower cut-off wavelength of about 22 m. The magnitude response of this telecom-grade fiber optic cable is therefore almost perfect at typical low frequency seismic waves. The approach presented here can be applied to various cable designs to estimate the strain transfer between ground movement and an optical fiber.

  10. Resonant vibration control of rotating beams

    DEFF Research Database (Denmark)

    Svendsen, Martin Nymann; Krenk, Steen; Høgsberg, Jan Becker

    2011-01-01

    Rotatingstructures,like e.g.wind turbine blades, may be prone to vibrations associated with particular modes of vibration. It is demonstrated, how this type of vibrations can be reduced by using a collocated sensor–actuator system, governed by a resonant controller. The theory is here demonstrated...... modal connectivity, only very limited modal spill-over is generated. The controller acts by resonance and therefore has only a moderate energy consumption, and successfully reduces modal vibrations at the resonance frequency....

  11. Vibrational relaxation of the bending mode of HDO in liquid D2O.

    Science.gov (United States)

    Bodis, Pavol; Larsen, Olaf F A; Woutersen, Sander

    2005-06-23

    The vibrational relaxation of the bending mode of HDO in liquid D2O has been studied using time-resolved mid-infrared pump-probe spectroscopy. At short delays, the transient spectrum clearly shows the v = 1 --> 2 induced absorption and v = 1 --> 0 bleaching and stimulated emission, whereas at long delays, the transient spectrum is dominated by the spectral changes caused by the temperature increase in the sample after vibrational relaxation. From the decay of the v = 1 --> 2 induced absorption, we obtain an estimate of 390 +/- 50 fs for the vibrational lifetime, in surprisingly good agreement with recent theoretical predictions. In the v = 0 --> 1 frequency region, the decay of the absorption change involves a second, slower component, which suggests that after vibrational relaxation the system is not yet in thermal equilibrium.

  12. Theoretic 3-D study of the high-frequency magnetic moment dynamics in thin ferromagnetic films with in-plane uniaxial anisotropy by considering eddy-current generation

    Science.gov (United States)

    Seemann, K.; Leiste, H.; Krüger, K.

    2012-06-01

    In the present paper, theoretic investigations of polarisation vector precession trajectories represented by a macro spin in ferromagnetic films with in-plane uniaxial anisotropy were realised. For this purpose, the Landau-Lifschitz-Gilbert differential equation (LLG) in combination with the Maxwell equations were solved for three dimensions by considering a linear progression of the magnetisation or polarisation with an external field. The frequency and time dependent polarisation trajectories illustrate how a magnetic moment precesses if effective damping and eddy-currents impacts its motion. For computation, typical parameter values like the saturation polarisation Js=μ0·Ms=1.4 T and in-plane uniaxial anisotropy μ0·Hu=4.5 mT were employed. The main focus of simulation was on the variation of the effective damping parameter αeff between 0.01 and 0.05 and ferromagnetic film thickness tm between 200 nm and 1200 nm. The frequency-dependent calculations were carried out between 50 MHz and 6 GHz. The time-dependent simulations were done for a duration between 5 and 30 ns.

  13. Tissue vibration in prolonged running.

    Science.gov (United States)

    Friesenbichler, Bernd; Stirling, Lisa M; Federolf, Peter; Nigg, Benno M

    2011-01-04

    The impact force in heel-toe running initiates vibrations of soft-tissue compartments of the leg that are heavily dampened by muscle activity. This study investigated if the damping and frequency of these soft-tissue vibrations are affected by fatigue, which was categorized by the time into an exhaustive exercise. The hypotheses were tested that (H1) the vibration intensity of the triceps surae increases with increasing fatigue and (H2) the vibration frequency of the triceps surae decreases with increasing fatigue. Tissue vibrations of the triceps surae were measured with tri-axial accelerometers in 10 subjects during a run towards exhaustion. The frequency content was quantified with power spectra and wavelet analysis. Maxima of local vibration intensities were compared between the non-fatigued and fatigued states of all subjects. In axial (i.e. parallel to the tibia) and medio-lateral direction, most local maxima increased with fatigue (supporting the first hypothesis). In anterior-posterior direction no systematic changes were found. Vibration frequency was minimally affected by fatigue and frequency changes did not occur systematically, which requires the rejection of the second hypothesis. Relative to heel-strike, the maximum vibration intensity occurred significantly later in the fatigued condition in all three directions. With fatigue, the soft tissue of the triceps surae oscillated for an extended duration at increased vibration magnitudes, possibly due to the effects of fatigue on type II muscle fibers. Thus, the protective mechanism of muscle tuning seems to be reduced in a fatigued muscle and the risk of potential harm to the tissue may increase. Copyright © 2010 Elsevier Ltd. All rights reserved.

  14. Theoretic 3-D study of the high-frequency magnetic moment dynamics in thin ferromagnetic films with in-plane uniaxial anisotropy by considering eddy-current generation

    Energy Technology Data Exchange (ETDEWEB)

    Seemann, K., E-mail: klaus.seemann@kit.edu [Karlsruhe Institute of Technology KIT (Campus North), Institute for Applied Materials, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany); Leiste, H.; Krueger, K. [Karlsruhe Institute of Technology KIT (Campus North), Institute for Applied Materials, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)

    2012-06-15

    In the present paper, theoretic investigations of polarisation vector precession trajectories represented by a macro spin in ferromagnetic films with in-plane uniaxial anisotropy were realised. For this purpose, the Landau-Lifschitz-Gilbert differential equation (LLG) in combination with the Maxwell equations were solved for three dimensions by considering a linear progression of the magnetisation or polarisation with an external field. The frequency and time dependent polarisation trajectories illustrate how a magnetic moment precesses if effective damping and eddy-currents impacts its motion. For computation, typical parameter values like the saturation polarisation J{sub s}={mu}{sub 0}{center_dot}M{sub s}=1.4 T and in-plane uniaxial anisotropy {mu}{sub 0}{center_dot}H{sub u}=4.5 mT were employed. The main focus of simulation was on the variation of the effective damping parameter {alpha}{sub eff} between 0.01 and 0.05 and ferromagnetic film thickness t{sub m} between 200 nm and 1200 nm. The frequency-dependent calculations were carried out between 50 MHz and 6 GHz. The time-dependent simulations were done for a duration between 5 and 30 ns. - Highlights: Black-Right-Pointing-Pointer Frequency- and time domain solution of the LLG and Maxwell differential equation. Black-Right-Pointing-Pointer 3D magnetic moment or macro spin trajectories by eddy-current impact. Black-Right-Pointing-Pointer Progression of a magnetic excitation field in thin ferromagnetic films. Black-Right-Pointing-Pointer Transient response evaluation of uniform magnetic moments excited by an r.f. field.

  15. Combined Euler column vibration isolation and energy harvesting

    Science.gov (United States)

    Davis, R. B.; McDowell, M. D.

    2017-05-01

    A new device that combines vibration isolation and energy harvesting is modeled, simulated, and tested. The vibration isolating portion of the device uses post-buckled beams as its spring elements. Piezoelectric film is applied to the beams to harvest energy from their dynamic flexure. The entire device operates passively on applied base excitation and requires no external power or control system. The structural system is modeled using the elastica, and the structural response is applied as forcing on the electric circuit equation to predict the output voltage and the corresponding harvested power. The vibration isolation and energy harvesting performance is simulated across a large parameter space and the modeling approach is validated with experimental results. Experimental transmissibilities of 2% and harvested power levels of 0.36 μW are simultaneously demonstrated. Both theoretical and experimental data suggest that there is not necessarily a trade-off between vibration isolation and harvested power. That is, within the practical operational range of the device, improved vibration isolation will be accompanied by an increase in the harvested power as the forcing frequency is increased.

  16. Whole-body vibration dosage alters leg blood flow

    NARCIS (Netherlands)

    Lythgo, Noel; Eser, Prisca; de Groot, Patricia; Galea, Mary

    The effect of whole-body vibration dosage on leg blood flow was investigated. Nine healthy young adult males completed a set of 14 random vibration and non-vibration exercise bouts whilst squatting on a Galileo 900 plate. Six vibration frequencies ranging from 5 to 30 Hz (5 Hz increments) were used

  17. Vibration analysis on compact car shock absorber

    Science.gov (United States)

    Tan, W. H.; Cheah, J. X.; Lam, C. K.; Lim, E. A.; Chuah, H. G.; Khor, C. Y.

    2017-10-01

    Shock absorber is a part of the suspension system which provides comfort experience while driving. Resonance, a phenomenon where forced frequency is coinciding with the natural frequency has significant effect on the shock absorber itself. Thus, in this study, natural frequencies of the shock absorber in a 2 degree-of-freedom system were investigated using Wolfram Mathematica 11, CATIA, and ANSYS. Both theoretical and simulation study how will the resonance affect the car shock absorber. The parametric study on the performance of shock absorber also had been conducted. It is found that the failure tends to occur on coil sprung of the shock absorber before the body of the shock absorber is fail. From mathematical modelling, it can also be seen that higher vibration level occurred on un-sprung mass compare to spring mass. This is due to the weight of sprung mass which could stabilize as compared with the weight of un-sprung mass. Besides that, two natural frequencies had been obtained which are 1.0 Hz and 9.1 Hz for sprung mass and un-sprung mass respectively where the acceleration is recorded as maximum. In conclusion, ANSYS can be used to validate with theoretical results with complete model in order to match with mathematical modelling.

  18. Monitoring vibrations

    Energy Technology Data Exchange (ETDEWEB)

    Tiryaki, B. [Hacettepe University (Turkey). Dept. of Mining Engineering

    2003-12-01

    The paper examines the prediction and optimisation of machine vibrations in longwall shearers. Underground studies were carried out at the Middle Anatolian Lignite Mine, between 1993 and 1997. Several shearer drums with different pick lacing arrangements were designed and tested on double-ended ranging longwall shearers employed at the mine. A computer program called the Vibration Analysis Program (VAP) was developed for analysing machine vibrations in longwall shearers. Shearer drums that were tested underground, as well as some provided by leading manufacturers, were analyzed using these programs. The results of the experiments and computer analyses are given in the article. 4 refs., 9 figs.

  19. Design and verification of a novel hollow vibrating module for laser machining.

    Science.gov (United States)

    Wang, Zhaozhao; Jang, Seungbong; Kim, EunHee; Jeon, Yongho; Lee, Soo-Hun; Lee, Moon G

    2015-04-01

    If a vibration module is added on laser machining system, the quality of surface finish and aspect ratio on metals can be significantly enhanced. In this study, a single mobility model of vibrating laser along the path of laser beam was put forward. In order to realize the desired unidirectional motion, a resonance type vibration module with optical lens was designed and manufactured. This cylindrical module was composed of curved-beam flexure elements. The cylindrical coordinate system was established to describe the relationship of a curved-beam flexure element's motion and deformation. In addition, the stiffness matrix of the curved-beam element was obtained. Finite element method and dynamical modeling were provided to analyze the resonance frequency and the displacement of the motion. The feasibility of the design was demonstrated with the help of experiments on frequency response. Experimental results show good agreement with theoretical analysis and simulation predictions.

  20. Transverse vibration analysis for piezoceramic rectangular plates using Ritz's method with equivalent constants.

    Science.gov (United States)

    Huang, Chi-Hung; Chen, Yi-Yu

    2006-02-01

    The transverse vibration of piezoceramic rectangular thin plates is investigated theoretically and experimentally using the Ritz's method incorporated with the defined equivalent constants. The equivalent constants are derived by comparing the characteristic equations of transverse resonant frequencies between isotropic and piezoceramic disks. By replacing the Poisson's ratio and flexural rigidity with the equivalent constants, the well-known Ritz's method can be used to investigate the transverse vibration of piezoceramic rectangular plates. Two different types of boundary conditions-clamped-free-free-free (CFFF) and clamped-free-clamped-free (CFCF)-are analyzed in this paper. For the experimental measurement, two optical techniques-amplitude-fluctuation electronic speckle pattern interferometry (AF-ESPI) and laser Doppler vibrometer (LDV)-are used to validate the analytical results. Both the transverse vibration modes and resonant frequencies of piezoceramic rectangular plates are obtained by the AF-ESPI method. Numerical calculations using the finite-element method (FEM) are performed, and the results are compared with the theoretical analysis and experimental measurements. Excellent agreements are obtained for results of both resonant frequencies and mode shapes. According to the theoretical calculations with different equivalent Poisson's ratios, resonant frequency variations versus aspect ratios ranging from 0.1 to 10 also are discussed for the first several modes in the work.

  1. Model Catalysis of Ammonia Synthesis ad Iron-Water Interfaces - ASum Frequency Generation Vibrational Spectroscopic Study of Solid-GasInterfaces and Anion Photoelectron Spectroscopic Study of Selected Anionclusters

    Energy Technology Data Exchange (ETDEWEB)

    Ferguson, Michael James [Univ. of California, Berkeley, CA (United States)

    2005-01-01

    The ammonia synthesis reaction has been studied using single crystal model catalysis combined with sum frequency generation (SFG) vibrational spectroscopy. The adsorption of gases N2, H2, O2 and NH3 that play a role in ammonia synthesis have been studied on the Fe(111) crystal surface by sum frequency generation vibrational spectroscopy using an integrated Ultra-High Vacuum (UHV)/high-pressure system. SFG spectra are presented for the dissociation intermediates, NH2 (~3325 cm-1) and NH (~3235 cm-1) under high pressure of ammonia or equilibrium concentrations of reactants and products on Fe(111) surfaces. Special attention was paid to understand how potassium promotion of the iron catalyst affects the intermediates of ammonia synthesis. An Fe(111) surface promoted with 0.2 monolayers of potassium red shifts the vibrational frequencies of the reactive surface intermediates, NH and NH2, providing evidence for weakened the nitrogen-hydrogen bonds relative to clean Fe(111). Spectral features of these surface intermediates persisted to higher temperatures for promoted iron surfaces than for clean Fe(111) surfaces implying that nitrogen-iron bonds are stronger for the promoted surface. The ratio of the NH to NH2 signal changed for promoted surfaces in the presence of equilibrium concentrations of reactants and products. The order of adding oxygen and potassium to promoted surfaces does not alter the spectra indicating that ammonia induces surface reconstruction of the catalyst to produce the same surface morphology. When oxygen is co-adsorbed with nitrogen, hydrogen, ammonia or potassium on Fe(111), a relative phase shift of the spectra occurs as compared to the presence of adsorbates on clean iron surfaces. Water adsorption on iron was also probed using SFG vibrational spectroscopy. For both H2O and D2O, the only spectral feature was in the range of

  2. Support Effects in Catalysis Studied by in-situ Sum Frequency Generation Vibrational Spectroscopy and in-situ X-Ray Spectroscopies

    Science.gov (United States)

    Kennedy, Griffin John

    Kinetic measurements are paired with in-situ spectroscopic characterization tools to investigate colloidally based, supported Pt catalytic model systems in order to elucidate the mechanisms by which metal and support work in tandem to dictate activity and selectivity. The results demonstrate oxide support materials, while inactive in absence of Pt nanoparticles, possess unique active sites for the selective conversion of gas phase molecules when paired with an active metal catalyst. In order to establish a paradigm for metal-support interactions using colloidally synthesized Pt nanoparticles the ability of the organic capping agent to inhibit reactivity and interaction with the support must first be assessed. Pt nanoparticles capped by poly(vinylpyrrolidone) (PVP), and those from which the PVP is removed by UV light exposure, are investigated for two reactions, the hydrogenation of ethylene and the oxidation of methanol. It is shown that prior to PVP removal the particles are moderately active for both reactions. Following removal, the activity for the two reactions diverges, the ethylene hydrogenation rate increases 10-fold, while the methanol oxidation rate decreases 3-fold. To better understand this effect the capping agent prior to, and the residual carbon remaining after UV treatment are probed by sum frequency generation vibrational spectroscopy. Prior to removal no major differences are observed when the particles are exposed to alternating H2 and O2 environments. When the PVP is removed, carbonaceous fragments remain on the surface that dynamically restructure in H2 and O2. These fragments create a tightly bound shell in an oxygen environment and a porous coating of hydrogenated carbon in the hydrogen environment. Reaction rate measurements of thermally cleaned PVP and oleic acid capped particles show this effect to be independent of cleaning method or capping agent. In all this demonstrates the ability of the capping agent to mediate nanoparticle catalysis

  3. Blade Vibration Measurement System

    Science.gov (United States)

    Platt, Michael J.

    2014-01-01

    The Phase I project successfully demonstrated that an advanced noncontacting stress measurement system (NSMS) could improve classification of blade vibration response in terms of mistuning and closely spaced modes. The Phase II work confirmed the microwave sensor design process, modified the sensor so it is compatible as an upgrade to existing NSMS, and improved and finalized the NSMS software. The result will be stand-alone radar/tip timing radar signal conditioning for current conventional NSMS users (as an upgrade) and new users. The hybrid system will use frequency data and relative mode vibration levels from the radar sensor to provide substantially superior capabilities over current blade-vibration measurement technology. This frequency data, coupled with a reduced number of tip timing probes, will result in a system capable of detecting complex blade vibrations that would confound traditional NSMS systems. The hardware and software package was validated on a compressor rig at Mechanical Solutions, Inc. (MSI). Finally, the hybrid radar/tip timing NSMS software package and associated sensor hardware will be installed for use in the NASA Glenn spin pit test facility.

  4. A novel positioning method for dual Mach-Zehnder interferometric vibration sensor in submarine cable security application

    Science.gov (United States)

    Xie, Shangran; Zhang, Min; Li, Yanhe; Liao, Yanbiao

    2011-05-01

    Dual Mach-Zehnder interferometric vibration sensor is an appropriate solution for submarine cable security application. While in this application the detected vibration signal is always narrow-bandwidth and short-duration subject to environmental constraints, which makes correlation based vibration positioning algorithm a poor robustness to noise. A preprocessing method focusing on expanding signal 3dB bandwidth before correlation is proposed in purpose of reducing ultimate positioning mean square error. A high pass filter is imposed to enhance the weight of high frequency components by attenuating low frequency main lobe. Field test results indicate a significant positioning error reduction when using this novel method as long as the cutoff frequency of high pass filter is selected in a valid region where positive effect of bandwidth extension is larger than effect of SNR reduction, and MSE reduction value in valid region agrees well with theoretical prediction.

  5. Stimulated angiogenesis for fracture healing augmented by low-magnitude, high-frequency vibration in a rat model-evaluation of pulsed-wave doppler, 3-D power Doppler ultrasonography and micro-CT microangiography.

    Science.gov (United States)

    Cheung, Wing-Hoi; Sun, Ming-Hui; Zheng, Yong-Ping; Chu, Winnie Chiu-Wing; Leung, Andraay Hon-Chi; Qin, Ling; Wei, Fang-Yuan; Leung, Kwok-Sui

    2012-12-01

    This study aimed to investigate the mechanism of low-magnitude high-frequency vibration (LMHFV) treatment on angiogenesis and blood flow for enhancement of fracture healing. Nine-month-old ovariectomized (OVX) and sham-operated (Sham) rats received closed fractures creation at the femora and were randomized into LMHFV treatment (Sham-V, OVX-V) or control (Sham-C, OVX-C) groups. Pulsed-wave Doppler indicated an increase in blood flow velocity of the femoral artery at weeks 2 (OVX pair: p = 0.030) and 4 (OVX pair: p = 0.012; Sham pair: p = 0.020) post-treatment. Significantly enhanced vascular volume (VV) at the fracture site in the vibration groups was demonstrated by 3-D high-frequency power Doppler at week 2 (Sham pair: p = 0.021) and micro-computed tomography (microCT) microangiography at weeks 2 (OVX pair: p = 0.009) and 4 (OVX pair: p = 0.034), which echoed the osteogenesis findings by radiographic and microCT analysis. VV in the OVX groups was inferior to the Sham groups. However, OVX-V showed higher percentages of angiogenic enhancement than Sham-V. Despite impaired neo-angiogenesis in osteoporotic fractures, LMHFV could increase blood flow and angiogenesis in both normal and osteoporotic fractures, thus enhancing fracture healing. Copyright © 2012 World Federation for Ultrasound in Medicine & Biology. Published by Elsevier Inc. All rights reserved.

  6. Experimental Research on Vibration Fatigue of CFRP and Its Influence Factors Based on Vibration Testing

    OpenAIRE

    Fan, Zhengwei; Jiang, Yu; Zhang, Shufeng; Chen, Xun

    2017-01-01

    A new research method based on vibration testing for the vibration fatigue of FRP was proposed in this paper. Through the testing on a closed-loop controlled vibration fatigue test system, the vibration fatigue phenomenon of typical carbon-fiber-reinforced plastic (CFRP) cantilevered laminate specimens was carefully studied. Moreover, a method based on the frequency response function was proposed to monitor the fatigue damage accumulation of specimens. On the basis of that, the influence fact...

  7. Reliability Analysis of Random Vibration Transmission Path Systems

    Directory of Open Access Journals (Sweden)

    Wei Zhao

    2017-01-01

    Full Text Available The vibration transmission path systems are generally composed of the vibration source, the vibration transfer path, and the vibration receiving structure. The transfer path is the medium of the vibration transmission. Moreover, the randomness of transfer path influences the transfer reliability greatly. In this paper, based on the matrix calculus, the generalized second moment technique, and the stochastic finite element theory, the effective approach for the transfer reliability of vibration transfer path systems was provided. The transfer reliability of vibration transfer path system with uncertain path parameters including path mass and path stiffness was analyzed theoretically and computed numerically, and the correlated mathematical expressions were derived. Thus, it provides the theoretical foundation for the dynamic design of vibration systems in practical project, so that most random path parameters can be considered to solve the random problems for vibration transfer path systems, which can avoid the system resonance failure.

  8. Transient vibration of wind turbine blades

    Science.gov (United States)

    Li, Yuanzhe; Li, Minghai; Jiang, Feng

    2017-09-01

    This article aims to the transient vibration of wind turbine blades. We firstly introduce transient vibration and previous studies in this area. The report then shows the fundamental equations and derivation of Euler Equation. A 3-D beam are created to compare the analytical and numerical result. In addition we operate the existing result and Patran result of a truncation wedge beam, especially the frequencies of free vibration and transient vibration. Transient vibration cannot be vanished but in some case it can be reduced.

  9. Vibrational spectroscopy of the G...C base pair: Experiment, harmonic and anharmonic calculations, and the nature of the anharmonic couplings

    Czech Academy of Sciences Publication Activity Database

    Brauer, B.; Gerber, R. B.; Kabeláč, Martin; Hobza, Pavel; Bakker, J. M.; Abo-Riziq, A.; Vries de, M. S.

    2005-01-01

    Roč. 109, - (2005), s. 6974-6984 ISSN 1089-5639 Grant - others:NSF(US) CHE-0244341 Institutional research plan: CEZ:AV0Z40550506 Keywords : nucleic acids bases * vibrational spectrum * frequencies anharmonicity Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 2.898, year: 2005

  10. Granular Media-Based Tunable Passive Vibration Suppressor

    Science.gov (United States)

    Dillon, Robert P.; Davis, Gregory L.; Shapiro, Andrew A.; Borgonia, John Paul C.; Kahn, Daniel L.; Boechler, Nicholas; Boechler,, Chiara

    2013-01-01

    and vibration suppression device is composed of statically compressed chains of spherical particles. The device superimposes a combination of dissipative damping and dispersive effects. The dissipative damping resulting from the elastic wave attenuation properties of the bulk material selected for the granular media is independent of particle geometry and periodicity, and can be accordingly designed based on the dissipative (or viscoelastic) properties of the material. For instance, a viscoelastic polymer might be selected where broadband damping is desired. In contrast, the dispersive effects result from the periodic arrangement and geometry of particles composing a linear granular chain. A uniform (monatomic) chain of statically compressed spherical particles will have a low-pass filter effect, with a cutoff frequency tunable as a function of particle mass, elastic modulus, Poisson fs ratio, radius, and static compression. Elastic waves with frequency content above this cutoff frequency will exhibit an exponential decay in amplitude as a function of propagation distance. System design targeting a specific application is conducted using a combination of theoretical, computational, and experimental techniques to appropriately select the particle radii, material (and thus elastic modulus and Poisson fs ratio), and static compression to satisfy estimated requirements derived for shock and/or vibration protection needs under particular operational conditions. The selection of a chain of polymer spheres with an elastic modulus .3 provided the appropriate dispersive filtering effect for that exercise; however, different operational scenarios may require the use of other polymers, metals, ceramics, or a combination thereof, configured as an array of spherical particles. The device is a linear array of spherical particles compressed in a container with a mechanism for attachment to the shock and/or vibration source, and a mechanism for attachment to the article requiring

  11. Analysis on Coupled Vibration of a Radially Polarized Piezoelectric Cylindrical Transducer.

    Science.gov (United States)

    Xu, Jie; Lin, Shuyu; Ma, Yan; Tang, Yifan

    2017-12-08

    Coupled vibration of a radially polarized piezoelectric cylindrical transducer is analyzed with the mechanical coupling coefficient method. The method has been utilized to analyze the metal cylindrical transducer and the axially polarized piezoelectric cylindrical transducer. In this method, the mechanical coupling coefficient is introduced and defined as the stress ratio in different directions. Coupled vibration of the cylindrical transducer is regarded as the interaction of the plane radial vibration of a ring and the longitudinal vibration of a tube. For the radially polarized piezoelectric cylindrical transducer, the radial and longitudinal electric admittances as functions of mechanical coupling coefficients and angular frequencies are derived, respectively. The resonance frequency equations are obtained. The dependence of resonance frequency and mechanical coupling coefficient on aspect ratio is studied. Vibrational distributions on the surfaces of the cylindrical transducer are presented with experimental measurement. On the support of experiments, this work is verified and provides a theoretical foundation for the analysis and design of the radially polarized piezoelectric cylindrical transducer.

  12. Soap film vibration: origin of the dissipation.

    Science.gov (United States)

    Acharige, Sébastien Kosgodagan; Elias, Florence; Derec, Caroline

    2014-11-07

    We investigate the complex dispersion relationship of a transverse antisymmetric wave on a horizontal soap film. Experimentally, the complex wave number k at a fixed forcing frequency is determined by measuring the vibrating amplitude of the soap film: the wavelength (linked to the real part of k) is determined by the spatial variation of the amplitude; the decay length (linked to the imaginary part of k) is determined by analyzing the resonance curves of the vibrating wave as a function of frequency. Theoretically, we compute the complex dispersion relationship taking into account the physical properties of the bulk liquid and gas phase, and of the gas-liquid interfaces. The comparison between the computation (developed to the leading order under our experimental conditions) and the experimental results confirms that the phase velocity is fixed by the interplay between surface tension, and liquid and air inertia, as reported in previous studies. Moreover, we show that the attenuation of the transverse antisymmetric wave originates from the viscous dissipation in the gas phase surrounding the liquid film. This result is an important step in understanding the propagation of an acoustic wave in liquid foam, using a bottom-up approach.

  13. Frequency peaks of tremor, muscle vibration and electromyographic activity at 10 Hz, 20 Hz and 40 Hz during human finger muscle contraction may reflect rhythmicities of central neural firing.

    Science.gov (United States)

    McAuley, J H; Rothwell, J C; Marsden, C D

    1997-05-01

    The output from the central nervous system to muscles may be rhythmic in nature. Previous recordings investigating peripheral manifestations of such rhythmic activity are conflicting. This study attempts to resolve these conflicts by employing a novel arrangement to measure and correlate rhythms in tremor, electromyographic (EMG) activity and muscle vibration sounds during steady index finger abduction. An elastic attachment of the index finger to a strain gauge allowed a strong but relatively unfixed abducting contraction of the first dorsal interosseous (1DI). An accelerometer attached to the end of the finger recorded tremor, surface electrodes over 1DI recorded EMG signals and a heart-sounds monitor placed over 1DI recorded vibration. This arrangement enabled maintenance of a constant overall muscle contraction strength while still allowing measurement of the occurrence of tremulous movements of the finger. Ten normal subjects were studied with the index finger first extended at rest and then contracting 1DI to abduct the index finger against three different steady forces up to 50% of maximal voluntary contraction (MVC). Power spectral analysis of tremor, EMG activity and muscle vibration signals each revealed three frequency peaks occurring together at around 10 Hz, 20 Hz and 40 Hz. Coherence analysis showed that the same three peaks were present in the three signals. Phase analysis indicated a fixed time lag of tremor behind EMG of around 6.5 ms. This is compared with previous measurements of electromechanical delay. Other experiments indicated that the three peaks were of central nervous origin. Introducing mechanical perturbations or extra loading to the finger and making recordings under partial anaesthesia of the hand and forearm demonstrated preservation of all the peaks, suggesting that they did not originate from mechanical resonances or peripheral feedback loop resonances. It is concluded that, at least for a small hand muscle, there exist not one but

  14. Characterization of the molecular structure and mechanical properties of polymer surfaces and protein/polymer interfaces by sum frequency generation vibrational spectroscopy and atomic force microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Koffas, Telly Stelianos [Univ. of California, Berkeley, CA (United States)

    2004-01-01

    Sum frequency generation (SFG) vibrational spectroscopy, atomic force microscopy (AFM), and other complementary surface-sensitive techniques have been used to study the surface molecular structure and surface mechanical behavior of biologically-relevant polymer systems. SFG and AFM have emerged as powerful analytical tools to deduce structure/property relationships, in situ, for polymers at air, liquid and solid interfaces. The experiments described in this dissertation have been performed to understand how polymer surface properties are linked to polymer bulk composition, substrate hydrophobicity, changes in the ambient environment (e.g., humidity and temperature), or the adsorption of macromolecules. The correlation of spectroscopic and mechanical data by SFG and AFM can become a powerful methodology to study and engineer materials with tailored surface properties. The overarching theme of this research is the interrogation of systems of increasing structural complexity, which allows us to extend conclusions made on simpler model systems. We begin by systematically describing the surface molecular composition and mechanical properties of polymers, copolymers, and blends having simple linear architectures. Subsequent chapters focus on networked hydrogel materials used as soft contact lenses and the adsorption of protein and surfactant at the polymer/liquid interface. The power of SFG is immediately demonstrated in experiments which identify the chemical parameters that influence the molecular composition and ordering of a polymer chain's side groups at the polymer/air and polymer/liquid interfaces. In general, side groups with increasingly greater hydrophobic character will be more surface active in air. Larger side groups impose steric restrictions, thus they will tend to be more randomly ordered than smaller hydrophobic groups. If exposed to a hydrophilic environment, such as water, the polymer chain will attempt to orient more of its hydrophilic groups to

  15. Skyrmion Vibration Modes within the Rational Map Ansatz

    OpenAIRE

    Lin, W.T.; Piette, B.

    2008-01-01

    We study the vibration modes of the Skyrme model within the rational map ansatz. We show that the vibrations of the radial profiles and the rational maps are decoupled and we consider explicitly the cases B=1, B=2, and B=4. We then compare our results with the vibration modes obtained numerically by Barnes et al. and show that qualitatively the rational map reproduces the vibration modes obtained numerically but that the vibration frequencies of these modes do not match very well.

  16. Method and apparatus for vibrating a substrate during material formation

    Science.gov (United States)

    Bailey, Jeffrey A [Richland, WA; Roger, Johnson N [Richland, WA; John, Munley T [Benton City, WA; Walter, Park R [Benton City, WA

    2008-10-21

    A method and apparatus for affecting the properties of a material include vibrating the material during its formation (i.e., "surface sifting"). The method includes the steps of providing a material formation device and applying a plurality of vibrations to the material during formation, which vibrations are oscillations having dissimilar, non-harmonic