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Sample records for theoretical combustion performance

  1. Theoretical Adiabatic Temperature and Chemical Composition of Sodium Combustion Flame

    International Nuclear Information System (INIS)

    Okano, Yasushi; Yamaguchi, Akira

    2003-01-01

    Sodium fire safety analysis requires fundamental combustion properties, e.g., heat of combustion, flame temperature, and composition. We developed the GENESYS code for a theoretical investigation of sodium combustion flame.Our principle conclusions on sodium combustion under atmospheric air conditions are (a) the maximum theoretical flame temperature is 1950 K, and it is not affected by the presence of moisture; the uppermost limiting factor is the chemical instability of the condensed sodium-oxide products under high temperature; (b) the main combustion product is liquid Na 2 O in dry air condition and liquid Na 2 O with gaseous NaOH in moist air; and (c) the chemical equilibrium prediction of the residual gaseous reactants in the flame is indispensable for sodium combustion modeling

  2. Theoretical studies of combustion dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Bowman, J.M. [Emory Univ., Atlanta, GA (United States)

    1993-12-01

    The basic objectives of this research program are to develop and apply theoretical techniques to fundamental dynamical processes of importance in gas-phase combustion. There are two major areas currently supported by this grant. One is reactive scattering of diatom-diatom systems, and the other is the dynamics of complex formation and decay based on L{sup 2} methods. In all of these studies, the authors focus on systems that are of interest experimentally, and for which potential energy surfaces based, at least in part, on ab initio calculations are available.

  3. Experimental, theoretical, and numerical studies of small scale combustion

    Science.gov (United States)

    Xu, Bo

    Recently, the demand increased for the development of microdevices such as microsatellites, microaerial vehicles, micro reactors, and micro power generators. To meet those demands the biggest challenge is obtaining stable and complete combustion at relatively small scale. To gain a fundamental understanding of small scale combustion in this thesis, thermal and kinetic coupling between the gas phase and the structure at meso and micro scales were theoretically, experimentally, and numerically studied; new stabilization and instability phenomena were identified; and new theories for the dynamic mechanisms of small scale combustion were developed. The reduction of thermal inertia at small scale significantly reduces the response time of the wall and leads to a strong flame-wall coupling and extension of burning limits. Mesoscale flame propagation and extinction in small quartz tubes were theoretically, experimentally and numerically studied. It was found that wall-flame interaction in mesoscale combustion led to two different flame regimes, a heat-loss dominant fast flame regime and a wall-flame coupling slow flame regime. The nonlinear transition between the two flame regimes was strongly dependent on the channel width and flow velocity. It is concluded that the existence of multiple flame regimes is an inherent phenomenon in mesoscale combustion. In addition, all practical combustors have variable channel width in the direction of flame propagation. Quasi-steady and unsteady propagations of methane and propane-air premixed flames in a mesoscale divergent channel were investigated experimentally and theoretically. The emphasis was the impact of variable cross-section area and the flame-wall coupling on the flame transition between different regimes and the onset of flame instability. For the first time, spinning flames were experimentally observed for both lean and rich methane and propane-air mixtures in a broad range of equivalence ratios. An effective Lewis number

  4. Fuel Combustion and Engine Performance | Transportation Research | NREL

    Science.gov (United States)

    Fuel Combustion and Engine Performance Fuel Combustion and Engine Performance Photo of a gasoline emissions in advanced engine technologies. Photo by Dennis Schroeder, NREL NREL's combustion research and combustion and engine research activities include: Developing experimental and simulation research platforms

  5. Internal combustion engine exhaust pipe flow simulation. Part I: theoretical aspects

    Directory of Open Access Journals (Sweden)

    Juan Miguel Mantilla

    2009-01-01

    Full Text Available Unsteady gas flow theory can be used for simulating a spark ignition internal combustion engine’s exhaust system, using pressure waves. The method explained here is based on the discretization of interpolated spaces (called meshes which are located throughout the whole length of the exhaust pipe, irrespective of its form or size. The most important aspects of this theory are theoretically explored, such as pressure wave movement and shock and their application to cases found in real engines’ exhaust pipes. This work also considers how the simulation must be made, based on the previous exploration. The results (presented as e- quations in this first paper show the great influence exerted by pressure wave movement on flow through the engine and there- fore on its final performance.

  6. Signal correlations in biomass combustion. An information theoretic analysis

    Energy Technology Data Exchange (ETDEWEB)

    Ruusunen, M.

    2013-09-01

    Increasing environmental and economic awareness are driving the development of combustion technologies to efficient biomass use and clean burning. To accomplish these goals, quantitative information about combustion variables is needed. However, for small-scale combustion units the existing monitoring methods are often expensive or complex. This study aimed to quantify correlations between flue gas temperatures and combustion variables, namely typical emission components, heat output, and efficiency. For this, data acquired from four small-scale combustion units and a large circulating fluidised bed boiler was studied. The fuel range varied from wood logs, wood chips, and wood pellets to biomass residue. Original signals and a defined set of their mathematical transformations were applied to data analysis. In order to evaluate the strength of the correlations, a multivariate distance measure based on information theory was derived. The analysis further assessed time-varying signal correlations and relative time delays. Ranking of the analysis results was based on the distance measure. The uniformity of the correlations in the different data sets was studied by comparing the 10-quantiles of the measured signal. The method was validated with two benchmark data sets. The flue gas temperatures and the combustion variables measured carried similar information. The strongest correlations were mainly linear with the transformed signal combinations and explicable by the combustion theory. Remarkably, the results showed uniformity of the correlations across the data sets with several signal transformations. This was also indicated by simulations using a linear model with constant structure to monitor carbon dioxide in flue gas. Acceptable performance was observed according to three validation criteria used to quantify modelling error in each data set. In general, the findings demonstrate that the presented signal transformations enable real-time approximation of the studied

  7. A reduced theoretical model for estimating condensation effects in combustion-heated hypersonic tunnel

    Science.gov (United States)

    Lin, L.; Luo, X.; Qin, F.; Yang, J.

    2018-03-01

    As one of the combustion products of hydrocarbon fuels in a combustion-heated wind tunnel, water vapor may condense during the rapid expansion process, which will lead to a complex two-phase flow inside the wind tunnel and even change the design flow conditions at the nozzle exit. The coupling of the phase transition and the compressible flow makes the estimation of the condensation effects in such wind tunnels very difficult and time-consuming. In this work, a reduced theoretical model is developed to approximately compute the nozzle-exit conditions of a flow including real-gas and homogeneous condensation effects. Specifically, the conservation equations of the axisymmetric flow are first approximated in the quasi-one-dimensional way. Then, the complex process is split into two steps, i.e., a real-gas nozzle flow but excluding condensation, resulting in supersaturated nozzle-exit conditions, and a discontinuous jump at the end of the nozzle from the supersaturated state to a saturated state. Compared with two-dimensional numerical simulations implemented with a detailed condensation model, the reduced model predicts the flow parameters with good accuracy except for some deviations caused by the two-dimensional effect. Therefore, this reduced theoretical model can provide a fast, simple but also accurate estimation of the condensation effect in combustion-heated hypersonic tunnels.

  8. Theoretical and experimental studies on emissions from wood combustion

    Energy Technology Data Exchange (ETDEWEB)

    Skreiberg, Oeyvind

    1997-12-31

    This thesis discusses experiments on emissions from wood log combustion and single wood particle combustion, both caused by incomplete combustion and emissions of nitric and nitrous oxide, together with empirical and kinetic NO{sub x} modelling. Experiments were performed in three different wood stoves: a traditional stove, a staged air stove and a stove equipped with a catalytic afterburner. Ideally, biomass fuel does not give a net contribution to the greenhouse effect. However, incomplete combustion was found to result in significant greenhouse gas emissions. Empirical modelling showed the excess air ratio and the combustion chamber temperature to be the most important input variables controlling the total fuel-N to NO{sub x} conversion factor. As the result of an international round robin test of a wood stove equipped with a catalytic afterburner, particle emission measurements were found to be the best method to evaluate the environmental acceptability of the tested stove, since the particle emission level was least dependent of the national standards, test procedures and calculation procedures used. In batch single wood particle combustion experiments on an electrically heated small-scale fixed bed reactor the fuel-N to NO conversion factor varied between 0.11-0.86 depending on wood species and operating conditions. A parameter study and homogeneous kinetic modelling on a plug flow reactor showed that, depending on the combustion compliance in question, there is an optimum combination of primary excess air ratio, temperature and residence time that gives a maximum conversion of fuel-N to N{sub 2}. 70 refs., 100 figs., 26 tabs.

  9. Consequences of sludge composition on combustion performance derived from thermogravimetry analysis

    Energy Technology Data Exchange (ETDEWEB)

    Li, Meiyan; Xiao, Benyi; Wang, Xu; Liu, Junxin, E-mail: jxliu@rcees.ac.cn

    2015-01-15

    Highlights: • Volatiles, particularly proteins, play a key role in sludge combustion. • Sludge combustion performance varies with different sludge organic concentrations. • Carbohydrates significantly affect the combustion rate in the second stage. • Combustion performance of digested sludge is more negative compared with others. - Abstract: Wastewater treatment plants produce millions of tons of sewage sludge. Sewage sludge is recognized as a promising feedstock for power generation via combustion and can be used for energy crisis adaption. We aimed to investigate the quantitative effects of various sludge characteristics on the overall sludge combustion process performance. Different types of sewage sludge were derived from numerous wastewater treatment plants in Beijing for further thermogravimetric analysis. Thermogravimetric–differential thermogravimetric curves were used to compare the performance of the studied samples. Proximate analytical data, organic compositions, elementary composition, and calorific value of the samples were determined. The relationship between combustion performance and sludge composition was also investigated. Results showed that the performance of sludge combustion was significantly affected by the concentration of protein, which is the main component of volatiles. Carbohydrates and lipids were not correlated with combustion performance, unlike protein. Overall, combustion performance varied with different sludge organic composition. The combustion rate of carbohydrates was higher than those of protein and lipid, and carbohydrate weight loss mainly occurred during the second stage (175–300 °C). Carbohydrates have a substantial effect on the rate of system combustion during the second stage considering the specific combustion feature. Additionally, the combustion performance of digested sewage sludge is more negative than the others.

  10. Consequences of sludge composition on combustion performance derived from thermogravimetry analysis

    International Nuclear Information System (INIS)

    Li, Meiyan; Xiao, Benyi; Wang, Xu; Liu, Junxin

    2015-01-01

    Highlights: • Volatiles, particularly proteins, play a key role in sludge combustion. • Sludge combustion performance varies with different sludge organic concentrations. • Carbohydrates significantly affect the combustion rate in the second stage. • Combustion performance of digested sludge is more negative compared with others. - Abstract: Wastewater treatment plants produce millions of tons of sewage sludge. Sewage sludge is recognized as a promising feedstock for power generation via combustion and can be used for energy crisis adaption. We aimed to investigate the quantitative effects of various sludge characteristics on the overall sludge combustion process performance. Different types of sewage sludge were derived from numerous wastewater treatment plants in Beijing for further thermogravimetric analysis. Thermogravimetric–differential thermogravimetric curves were used to compare the performance of the studied samples. Proximate analytical data, organic compositions, elementary composition, and calorific value of the samples were determined. The relationship between combustion performance and sludge composition was also investigated. Results showed that the performance of sludge combustion was significantly affected by the concentration of protein, which is the main component of volatiles. Carbohydrates and lipids were not correlated with combustion performance, unlike protein. Overall, combustion performance varied with different sludge organic composition. The combustion rate of carbohydrates was higher than those of protein and lipid, and carbohydrate weight loss mainly occurred during the second stage (175–300 °C). Carbohydrates have a substantial effect on the rate of system combustion during the second stage considering the specific combustion feature. Additionally, the combustion performance of digested sewage sludge is more negative than the others

  11. Internal combustion engine exhaust pipe flow simulation. Part I: theoretical aspects

    OpenAIRE

    Juan Miguel Mantilla; Camilo Andrés Falla; Jorge Arturo Gómez

    2010-01-01

    Unsteady gas flow theory can be used for simulating a spark ignition internal combustion engine’s exhaust system, using pressure waves. The method explained here is based on the discretization of interpolated spaces (called meshes) which are located throughout the whole length of the exhaust pipe, irrespective of its form or size. The most important aspects of this theory are theoretically explored, such as pressure wave movement and shock and their application to cases found in re...

  12. Internal combustion engine exhaust pipe flow simulation. Part I: theoretical aspects

    OpenAIRE

    Juan Miguel Mantilla; Camilo Andrés Falla; Jorge Arturo Gómez

    2009-01-01

    Unsteady gas flow theory can be used for simulating a spark ignition internal combustion engine’s exhaust system, using pressure waves. The method explained here is based on the discretization of interpolated spaces (called meshes) which are located throughout the whole length of the exhaust pipe, irrespective of its form or size. The most important aspects of this theory are theoretically explored, such as pressure wave movement and shock and their application to cases found in real engines’...

  13. Theoretical modeling of combustion characteristics and performance parameters of biodiesel in DI diesel engine with variable compression ratio

    Energy Technology Data Exchange (ETDEWEB)

    Al-Dawody, Mohamed F.; Bhatti, S.K. [Department of Mechanical Engineering, Andhra University (India)

    2013-07-01

    Increasing of costly and depleting fossil fuels are prompting researchers to use edible as well as non-edible vegetable oils as a promising alternative to petro-diesel fuels. A comprehensive computer code using ''Quick basic'' language was developed for the diesel engine cycle to study the combustion and performance characteristics of a single cylinder, four stroke, direct injection diesel engine with variable compression ratio. The engine operates on diesel fuel and 20% (mass basis) of biodiesel (derived from soybean oil) blended with diesel. Combustion characteristics such as cylinder pressure, heat release fraction, heat transfer and performance characteristics such as brake power; and brake specific fuel consumption (BSFC) were analyzed. On the basis of the first law of thermodynamics the properties at each degree crank angle was calculated. Wiebe function is used to calculate the instantaneous heat release rate. The computed results are validated through the results obtained in the simulation Diesel-rk software.

  14. Effects of increased small-scale biomass combustion on local air quality - A theoretical dispersion modelling study

    International Nuclear Information System (INIS)

    Boman, C.

    1997-01-01

    The decided phasing out of nuclear power and the goal of reducing CO 2 emissions from fossil fuels causes a substantial estimated increase in the use of biomass fuels for energy production. Thus, a significant shift from small scale heating generated by electricity or fuel oil to biomass fuels is desirable. If a drastic deterioration of the local air quality is to be avoided, a reduction of today's emission limits is necessary. The objective of this report was therefore to describe the use of biomass fuels and small scale pellet fuel combustion, to make a theoretical study of the effects of increased pellets heating on the air quality in a residential area, and to discuss necessary emission limits for small biomass fuel plants. The general description is based on literature studies. In the theoretical study, several different dispersion model calculations were performed using the computer program Dispersion 1.1.0. The contents of tar and total hydrocarbons (THC) in the air were calculated for different scenarios with conversion from electricity to pellets and with different pellet plant performance. A sensitivity analysis was performed with additional variables and dispersion calculations according to an underlying statistical experimental design. The modeling and design computer program MODDE was used to facilitate design, evaluation and illustration of the calculated results. The results show that a substantial increase in the use of small scale pellets heating with worst calculated plant performance, will lead to a drastic increase of the content of hydrocarbons in the air. Thus, with best available performance, the content only increases marginally. Conversion from electricity to pellets, plant performance and time of year were the most influential variables. Also conversion from wood to pellets showed a significant effect, despite the small number of wood heated houses within the studied area. If a significant deterioration of the air quality is to be avoided

  15. ANALYSIS OF INTERNAL COMBUSTION ENGINE WITH A NEW CONCEPT OF POROUS MEDIUM COMBUSTION FOR THE FUTURE CLEAN ENGINE

    Directory of Open Access Journals (Sweden)

    Ashok A Dhale

    2010-01-01

    Full Text Available At present, the emissions of internal combustion engine can only be improved by catalytic treatments of the exhaust gases. Such treatments, however, result in high costs and relatively low conversion efficiency. This suggests that a new combustion technique should be developed to yield improved primary combustion processes inside the engine with drastically reduced exhaust gas emissions. To fulfill all requirements, Dr. Franz Drust has proposed a new combustion concept to perform homogenous combustion in internal combustion engines. This concept used the porous medium combustion technique and is called "PM-engine". It is shown that the PM combustion technique can be applied to internal combustion engines. Theoretical considerations are presented for internal combustion engines, indicating that an overall improvement in thermal efficiency can be achieved for the PM-engine. This is explained and general performance of the new PM-engines is demonstrated for a single cylinder, water cooled, direct injection diesel engine. Verification of experiments at primary stage is described that were carried out as a part of the present study.

  16. The effect of insulated combustion chamber surfaces on direct-injected diesel engine performance, emissions, and combustion

    Science.gov (United States)

    Dickey, Daniel W.; Vinyard, Shannon; Keribar, Rifat

    1988-01-01

    The combustion chamber of a single-cylinder, direct-injected diesel engine was insulated with ceramic coatings to determine the effect of low heat rejection (LHR) operation on engine performance, emissions, and combustion. In comparison to the baseline cooled engine, the LHR engine had lower thermal efficiency, with higher smoke, particulate, and full load carbon monoxide emissions. The unburned hydrocarbon emissions were reduced across the load range. The nitrous oxide emissions increased at some part-load conditions and were reduced slightly at full loads. The poor LHR engine performance was attributed to degraded combustion characterized by less premixed burning, lower heat release rates, and longer combustion duration compared to the baseline cooled engine.

  17. Effect of flame-tube head structure on combustion chamber performance

    Science.gov (United States)

    Gu, Minqqi

    1986-01-01

    The experimental combustion performance of a premixed, pilot-type flame tube with various head structures is discussed. The test study covers an extensive area: efficiency of the combustion chamber, quality of the outlet temperature field, limit of the fuel-lean blowout, ignition performance at ground starting, and carbon deposition. As a result of these tests, a nozzle was found which fits the premixed pilot flame tube well. The use of this nozzle optimized the performance of the combustion chamber. The tested models had premixed pilot chambers with two types of air-film-cooling structures, six types of venturi-tube structures, and secondary fuel nozzles with two small spray-cone angles.

  18. Impact of higher n-butanol addition on combustion and performance of GDI engine in stoichiometric combustion

    International Nuclear Information System (INIS)

    Chen, Zheng; Yang, Feng; Xue, Shuo; Wu, Zhenkuo; Liu, Jingping

    2015-01-01

    Highlights: • Effects of 0–50% n-butanol addition on GDI engine are experimentally studied. • Higher n-butanol fractions increase combustion pressure and fasten burning rate. • Higher n-butanol fractions increase BSFC but improve BTE. • Higher n-butanol fractions enhance combustion stability but increase knock intensity. • Higher n-butanol fractions reduce exhaust temperature and NOx emissions. - Abstract: An experimental study was carried out on a turbocharged gasoline direct injection (GDI) engine fueled by n-butanol/gasoline blends. Effects of n-butanol percents (15%, 30%, and 50%) on combustion and performance of the engine operating on stoichiometric combustion condition were discussed and also compared with pure gasoline in this paper. The results indicate that n-butanol/gasoline blends increase combustion pressure and pressure rise rate, fasten burning rate, and shorten ignition delay and combustion duration, as compared to pure gasoline. Moreover, these trends are impacted more evidently with increased n-butanol fraction in the blends. In addition, higher n-butanol percent of gasoline blends increase combustion temperature but decrease the temperature in the later stage of expansion stroke, which contributes to the control of exhaust temperature at high-load. With regards to engine performance, higher n-butanol percent in the blends results in increased brake specific fuel consumption (BSFC) and higher brake thermal efficiency (BTE). However, higher n-butanol addition helps to improve combustion stability but shows slightly higher knock possibility in high-load. In that case, the knock trend could be weakened by retarding ignition timing. Moreover, higher n-butanol addition significantly decreases NOx emissions, but it increases CO emissions obviously.

  19. Effects of backing board materials on wood combustion performance

    Science.gov (United States)

    Mathew J. Hagge; Kenneth M. Bryden; Mark A. Dietenberger

    2004-01-01

    Cone calorimeter tests show that backing board materials do not affect the ignition time, initial heat release rate, or the total heat released of combustion for redwood slabs. However, it has been observed that backing board materials alter combustion performance by altering the secondary heat release peak observed when the pyrolysis reaction front nears the unheated...

  20. A numerical study on the effect of various combustion bowl parameters on the performance, combustion, and emission behavior on a single cylinder diesel engine.

    Science.gov (United States)

    Balasubramanian, Dhinesh; Sokkalingam Arumugam, Sabari Rajan; Subramani, Lingesan; Joshua Stephen Chellakumar, Isaac JoshuaRamesh Lalvani; Mani, Annamalai

    2018-01-01

    A numerical study was carried out to study the effect of various combustion bowl parameters on the performance behavior, combustion characteristics, and emission magnitude on a single cylinder diesel engine. A base combustion bowl and 11 different combustion bowls were created by varying the aspect ratio, reentrancy ratio, and bore to bowl ratio. The study was carried out at engine rated speed and a full throttle performance condition, without altering the compression ratio. The results revealed that the combustion bowl parameters could have a huge impact on the performance behavior, combustion characteristics, and emission magnitude of the engine. The bowl parameters, namely throat diameter and toroidal radius, played a crucial role in determining the performance behavior of the combustion bowls. It was observed that the combustion bowl parameters, namely central pip distance, throat diameter, and bowl depth, also could have an impact on the combustion characteristics. And throat diameter and toroidal radius, central pip distance, and toroidal corner radius could have a consequent effect on the emission magnitude of the engine. Of the different combustion bowls tested, combustion bowl 4 was preferable to others owing to the superior performance of 3% of higher indicated mean effective pressure and lower fuel consumption. Interestingly, trade-off for NO x emission was higher only by 2.85% compared with the base bowl. The sensitivity analysis proved that bowl depth, bowl diameter, toroidal radius, and throat diameter played a vital role in the fuel consumption parameter and emission characteristics even at the manufacturing tolerance variations.

  1. Residential Electrostatic Precipitator - Performance at efficient and poor combustion conditions

    Energy Technology Data Exchange (ETDEWEB)

    Baefver, Linda; Yngvesson, Johan; Niklasson, Fredrik

    2012-07-01

    The performance of a pilot residential electrostatic precipitator R{sub E}SP (Applied Plasma Physics AS), was investigated at laboratory. Measurements of TSP (Total Suspended Particles), content of organic and elemental carbon, and mass size distribution of particles upstream and downstream of ESP were performed. Values for PM1 (particles < 1 {mu}m) were calculated from the particle size distributions. Concentrations and size distributions with respect to particle numbers were measured in separate tests. Gas concentrations, temperatures and boiler parameters were also measured. The TSP concentrations upstream of the R{sub E}SP were varied in range of 15-390 mg/m{sub N}{sup 3}. Up to concentrations of about 300 mg/m{sub N}{sup 3}, the TSP-concentrations out from the ESP were less than 20 mg/m{sub N}{sup 3}, which is well below the German emission limit for wood stoves. The removal efficiencies with respect to mass were about 87% at efficient combustion and 93% at poor combustion. Corresponding values with respect to number concentrations were about 97% at efficient combustion and almost 99% at poor combustion. The better performance at poor combustion may be explained by lower flue gas temperature, leading to longer residence time in the ESP. High removal efficiencies were also found with respect to particulate organic and elemental carbon.

  2. Experimental Investigation and High Resolution Simulation of In-Situ Combustion Processes

    Energy Technology Data Exchange (ETDEWEB)

    Margot Gerritsen; Tony Kovscek

    2008-04-30

    This final technical report describes work performed for the project 'Experimental Investigation and High Resolution Numerical Simulator of In-Situ Combustion Processes', DE-FC26-03NT15405. In summary, this work improved our understanding of in-situ combustion (ISC) process physics and oil recovery. This understanding was translated into improved conceptual models and a suite of software algorithms that extended predictive capabilities. We pursued experimental, theoretical, and numerical tasks during the performance period. The specific project objectives were (i) identification, experimentally, of chemical additives/injectants that improve combustion performance and delineation of the physics of improved performance, (ii) establishment of a benchmark one-dimensional, experimental data set for verification of in-situ combustion dynamics computed by simulators, (iii) develop improved numerical methods that can be used to describe in-situ combustion more accurately, and (iv) to lay the underpinnings of a highly efficient, 3D, in-situ combustion simulator using adaptive mesh refinement techniques and parallelization. We believe that project goals were met and exceeded as discussed.

  3. Investigation of combustion and thermodynamic performance of a lean burn catalytic combustion gas turbine system

    International Nuclear Information System (INIS)

    Yin Juan; Weng Yiwu

    2011-01-01

    The goals of this research were to investigate the combustion and thermodynamic performance of a lean burn catalytic combustion gas turbine. The characteristics of lean burn catalytic combustion were investigated by utilising 1D heterogeneous plug flow model which was validated by experiments. The effects of operating parameters on catalytic combustion were numerically analysed. The system models were built in ASPEN Plus and three independent design variables, i.e. compressor pressure ratio (PR), regenerator effectiveness (RE) and turbine inlet temperature (TIT) were selected to analyse the thermodynamic performance of the thermal cycle. The main results show that: simulations from 1D heterogeneous plug flow model can capture the trend of catalytic combustion and describe the behavior of the catalytic monolith in detail. Inlet temperature is the most significant parameter that impacts operation of the catalytic combustor. When TIT and RE are constant, the increase of PR results in lowering the inlet temperature of the catalytic combustor, which results in decreasing methane conversion. The peak thermal efficiency and the optimal PR at a constant TIT increase with the increase of TIT; and at the constant PR, the thermal efficiency increases with the increase of TIT. However, with lower TIT conditions, the optimal PR and the peak efficiency at a constant TIT of the LBCCGT cycle are relative low to that of the conventional cycle. When TIT and PR are constant, the decrease of RE may result in lower methane conversion. The influences of RE on the methane conversion and the thermal efficiency are more significant at higher PRs. The higher thermal efficiency for the lower RE is achieved at lower PR.

  4. Effect of Chamber Pressurization Rate on Combustion and Propagation of Solid Propellant Cracks

    Science.gov (United States)

    Yuan, Wei-Lan; Wei, Shen; Yuan, Shu-Shen

    2002-01-01

    area of the propellant grain satisfies the designed value. But cracks in propellant grain can be generated during manufacture, storage, handing and so on. The cracks can provide additional surface area for combustion. The additional combustion may significantly deviate the performance of the rocket motor from the designed conditions, even lead to explosive catastrophe. Therefore a thorough study on the combustion, propagation and fracture of solid propellant cracks must be conducted. This paper takes an isolated propellant crack as the object and studies the effect of chamber pressurization rate on the combustion, propagation and fracture of the crack by experiment and theoretical calculation. deformable, the burning inside a solid propellant crack is a coupling of solid mechanics and combustion dynamics. In this paper, a theoretical model describing the combustion, propagation and fracture of the crack was formulated and solved numerically. The interaction of structural deformation and combustion process was included in the theoretical model. The conservation equations for compressible fluid flow, the equation of state for perfect gas, the heat conducting equation for the solid-phase, constitutive equation for propellant, J-integral fracture criterion and so on are used in the model. The convective burning inside the crack and the propagation and fracture of the crack were numerically studied by solving the set of nonlinear, inhomogeneous gas-phase governing equations and solid-phase equations. On the other hand, the combustion experiments for propellant specimens with a precut crack were conducted by RTR system. Predicted results are in good agreement with experimental data, which validates the reasonableness of the theoretical model. Both theoretical and experimental results indicate that the chamber pressurization rate has strong effects on the convective burning in the crack, crack fracture initiation and fracture pattern.

  5. Combustion and co-combustion of biomass in a bubbling fluidized bed boiler

    NARCIS (Netherlands)

    Khan, A.A.

    2007-01-01

    This PhD dissertation concerns the study of different aspects of biomass (co)-combustion in small-scale fluidized bed boilers for heat generation. The most renowned gaseous emissions from fluidized bed combustion, namely, CO and NO, are investigated with the help of experimental and theoretical

  6. Meta-control of combustion performance with a data mining approach

    Science.gov (United States)

    Song, Zhe

    Large scale combustion process is complex and proposes challenges of optimizing its performance. Traditional approaches based on thermal dynamics have limitations on finding optimal operational regions due to time-shift nature of the process. Recent advances in information technology enable people collect large volumes of process data easily and continuously. The collected process data contains rich information about the process and, to some extent, represents a digital copy of the process over time. Although large volumes of data exist in industrial combustion processes, they are not fully utilized to the level where the process can be optimized. Data mining is an emerging science which finds patterns or models from large data sets. It has found many successful applications in business marketing, medical and manufacturing domains The focus of this dissertation is on applying data mining to industrial combustion processes, and ultimately optimizing the combustion performance. However the philosophy, methods and frameworks discussed in this research can also be applied to other industrial processes. Optimizing an industrial combustion process has two major challenges. One is the underlying process model changes over time and obtaining an accurate process model is nontrivial. The other is that a process model with high fidelity is usually highly nonlinear, solving the optimization problem needs efficient heuristics. This dissertation is set to solve these two major challenges. The major contribution of this 4-year research is the data-driven solution to optimize the combustion process, where process model or knowledge is identified based on the process data, then optimization is executed by evolutionary algorithms to search for optimal operating regions.

  7. Thermogravimetric investigation on the degradation properties and combustion performance of bio-oils.

    Science.gov (United States)

    Ren, Xueyong; Meng, Jiajia; Moore, Andrew M; Chang, Jianmin; Gou, Jinsheng; Park, Sunkyu

    2014-01-01

    The degradation properties and combustion performance of raw bio-oil, aged bio-oil, and bio-oil from torrefied wood were investigated through thermogravimetric analysis. A three-stage process was observed for the degradation of bio-oils, including devolatilization of the aqueous fraction and light compounds, transition of the heavy faction to solid, and combustion of carbonaceous residues. Pyrolysis kinetics parameters were calculated via the reaction order model and 3D-diffusion model, and combustion indexes were used to qualitatively evaluate the thermal profiles of tested bio-oils for comparison with commercial oils such as fuel oils. It was found that aged bio-oil was more thermally instable and produced more combustion-detrimental carbonaceous solid. Raw bio-oil and bio-oil from torrefied wood had comparable combustion performance to fuel oils. It was considered that bio-oil has a potential to be mixed with or totally replace the fuel oils in boilers. Copyright © 2013 Elsevier Ltd. All rights reserved.

  8. Characterisation and prediction of deposits in biomass co-combustion

    NARCIS (Netherlands)

    Tortosa Masiá, A.A.

    2010-01-01

    This PhD thesis deals with the theoretical, experimental and modeling work which was performed to study deposition during biomass and waste co-combustion in pulverised coal facilities. Fossil fuels dominate the current energy scenario. Increasing concerns about fossil fuels availability and about

  9. Theoretical studies of oxides relevant to the combustion of fossil fuels

    Science.gov (United States)

    Hicks, Jason Michael

    : adsorption isotherms, Gibbs free energy, enthalpy, entropy and desorption free energy. It was found that, when the maximum loading was compared to the regeneration costs, IRMOF-10 had the best performance, followed by IRMOF-8 then IRMOF-1. During the combustion of coal, not only is CO2 produced, but also the trace elements of arsenic and selenium escape into the environment though this process. Both arsenic and selenium are known to have a harmful effects on the environment and human health. Arsenic is also known to poison the catalytic converter used in selective catalytic reduction of NOx . These trace elements have been found on fly ash or in the hot flue gases released into the atmosphere. In flue gases they most often exist as oxides. There have been many experimental and a few theoretical studies on the monomeric oxides, AsOx and SeOx, where x = 1, 2, or 3. However, little is known concerning the corresponding dimeric oxides, As2Ox and Se2Ox, where x = 3 or 5, though these compounds are expected from their similarities to nitrogen and sulfur chemistry, respectively. From an experimental perspective, they are very challenging to study due to the high temperatures, complex environments and low concentrations needed for a direct study of the form and structures of the dimeric oxides. From a theoretical perspective, they can be challenging to study due to their multireference character and the need for both dynamic and non-dynamic electron correlation due to bonds forming and breaking during isomerization. However, high level multireference ab initio methods which account for both dynamic and non-dynamic electron correlation can be used. In the work contained in this thesis, GVVPT2 and CR-CC(2,3) were used to study the relative stabilities of all relevant isomers and transition states of As2Ox and Se2Ox. The structures used where generated through DFT using the B3LYP functional. Not only were plausible stationary points located for all species, it was further confirmed

  10. The scaling of performance and losses in miniature internal combustion engines

    Science.gov (United States)

    Menon, Shyam Kumar

    Miniature glow ignition internal combustion (IC) piston engines are an off--the--shelf technology that could dramatically increase the endurance of miniature electric power supplies and the range and endurance of small unmanned air vehicles provided their overall thermodynamic efficiencies can be increased to 15% or better. This thesis presents the first comprehensive analysis of small (system is developed that is capable of making reliable measurements of engine performance and losses in these small engines. Methodologies are also developed for measuring volumetric, heat transfer, exhaust, mechanical, and combustion losses. These instruments and techniques are used to investigate the performance of seven single-cylinder, two-stroke, glow fueled engines ranging in size from 15 to 450 g (0.16 to 7.5 cm3 displacement). Scaling rules for power output, overall efficiency, and normalized power are developed from the data. These will be useful to developers of micro-air vehicles and miniature power systems. The data show that the minimum length scale of a thermodynamically viable piston engine based on present technology is approximately 3 mm. Incomplete combustion is the most important challenge as it accounts for 60-70% of total energy losses. Combustion losses are followed in order of importance by heat transfer, sensible enthalpy, and friction. A net heat release analysis based on in-cylinder pressure measurements suggest that a two--stage combustion process occurs at low engine speeds and equivalence ratios close to 1. Different theories based on burning mode and reaction kinetics are proposed to explain the observed results. High speed imaging of the combustion chamber suggests that a turbulent premixed flame with its origin in the vicinity of the glow plug is the primary driver of combustion. Placing miniature IC engines on a turbulent combustion regime diagram shows that they operate in the 'flamelet in eddy' regime whereas conventional--scale engines operate

  11. Theoretical Rocket Performance of Liquid Methane with Several Fluorine-Oxygen Mixtures Assuming Frozen Composition

    Science.gov (United States)

    Gordon, Sanford; Kastner, Michael E

    1958-01-01

    Theoretical rocket performance for frozen composition during expansion was calculated for liquid methane with several fluorine-oxygen mixtures for a range of pressure ratios and oxidant-fuel ratios. The parameters included are specific impulse, combustion-chamber temperature, nozzle-exit temperature molecular weight, characteristic velocity, coefficient of thrust, ratio of nozzle-exit area to throat area, specific heat at constant pressure, isentropic exponent, viscosity, and thermal conductivity. The maximum calculated value of specific impulse for a chamber pressure of 600 pounds per square inch absolute (40.827atm) and an exit pressure of 1 atmosphere is 315.3 for 79.67 percent fluorine in the oxidant.

  12. An experimental and theoretical investigation of a fuel system tuner for the suppression of combustion driven oscillations

    Science.gov (United States)

    Scarborough, David E.

    Manufacturers of commercial, power-generating, gas turbine engines continue to develop combustors that produce lower emissions of nitrogen oxides (NO x) in order to meet the environmental standards of governments around the world. Lean, premixed combustion technology is one technique used to reduce NOx emissions in many current power and energy generating systems. However, lean, premixed combustors are susceptible to thermo-acoustic oscillations, which are pressure and heat-release fluctuations that occur because of a coupling between the combustion process and the natural acoustic modes of the system. These pressure oscillations lead to premature failure of system components, resulting in very costly maintenance and downtime. Therefore, a great deal of work has gone into developing methods to prevent or eliminate these combustion instabilities. This dissertation presents the results of a theoretical and experimental investigation of a novel Fuel System Tuner (FST) used to damp detrimental combustion oscillations in a gas turbine combustor by changing the fuel supply system impedance, which controls the amplitude and phase of the fuel flowrate. When the FST is properly tuned, the heat release oscillations resulting from the fuel-air ratio oscillations damp, rather than drive, the combustor acoustic pressure oscillations. A feasibility study was conducted to prove the validity of the basic idea and to develop some basic guidelines for designing the FST. Acoustic models for the subcomponents of the FST were developed, and these models were experimentally verified using a two-microphone impedance tube. Models useful for designing, analyzing, and predicting the performance of the FST were developed and used to demonstrate the effectiveness of the FST. Experimental tests showed that the FST reduced the acoustic pressure amplitude of an unstable, model, gas-turbine combustor over a wide range of operating conditions and combustor configurations. Finally, combustor

  13. E25 stratified torch ignition engine performance, CO_2 emission and combustion analysis

    International Nuclear Information System (INIS)

    Rodrigues Filho, Fernando Antonio; Moreira, Thiago Augusto Araujo; Valle, Ramon Molina; Baêta, José Guilherme Coelho; Pontoppidan, Michael; Teixeira, Alysson Fernandes

    2016-01-01

    Highlights: • A torch ignition engine prototype was built and tested. • Significant reduction of BSFC was achieved due to the use of the torch ignition system. • Low cyclic variability characterized the lean combustion process of the torch ignition engine prototype. • The torch ignition system allowed an average reduction of 8.21% at the CO_2 specific emissions. - Abstract: Vehicular emissions significantly increase atmospheric air pollution and the greenhouse effect. This fact associated with the fast growth of the global motor vehicle fleet demands technological solutions from the scientific community in order to achieve a decrease in fuel consumption and CO_2 emission, especially of fossil fuels to comply with future legislation. To meet this goal, a prototype stratified torch ignition engine was designed from a commercial baseline engine. In this system, the combustion starts in a pre-combustion chamber where the pressure increase pushes the combustion jet flames through a calibrated nozzle to be precisely targeted into the main chamber. These combustion jet flames are endowed with high thermal and kinetic energy being able to promote a stable lean combustion process. The high kinetic and thermal energy of the combustion jet flame results from the load stratification. This is carried out through direct fuel injection in the pre-combustion chamber by means of a prototype gasoline direct injector (GDI) developed for low fuel flow rate. During the compression stroke, lean mixture coming from the main chamber is forced into the pre-combustion chamber and, a few degrees before the spark timing, fuel is injected into the pre-combustion chamber aiming at forming a slightly rich mixture cloud around the spark plug which is suitable for the ignition and kernel development. The performance of the torch ignition engine running with E25 is presented for different mixture stratification levels, engine speed and load. The performance data such as combustion phasing

  14. Influence of moist combustion gas on performance of a sub-critical turbine

    International Nuclear Information System (INIS)

    Yang Wenbin; Su Ming

    2005-01-01

    In the HAT cycle, as the absolute humidity of the moist combustion gas increases, the performance of the turbine will also change. In this paper, one model to calculate the thermodynamic properties of the moist combustion gas is introduced, and another model to calculate the performance of the turbine is formulated based on the equations of one dimensional flow. Using these models with the geometric parameters of the turbine fixed, at the design working condition, the performance of the turbine is calculated and analyzed for different absolute humidities. Finally, some conclusions about the turbine performance are presented

  15. A comprehensive study of combustion products generated from pulverized peat combustion in the furnace of BKZ-210-140F steam boiler

    Science.gov (United States)

    Kuzmin, V. A.; Zagrai, I. A.

    2017-11-01

    The experimental and theoretical study of combustion products has been carried out for the conditions of pulverized peat combustion in BKZ-210-140F steam boiler. Sampling has been performed in different parts of the boiler system in order to determine the chemical composition, radiative properties and dispersity of slag and ash particles. The chemical composition of particles was determined using the method of x-ray fluorescence analysis. Shapes and sizes of the particles were determined by means of electron scanning microscopy. The histograms and the particle size distribution functions were computed. The calculation of components of the gaseous phase was based on the combustion characteristics of the original fuel. The software package of calculation of thermal radiation of combustion products from peat combustion was used to simulate emission characteristics (flux densities and emissivity factors). The dependence of emission characteristics on the temperature level and on the wavelength has been defined. On the basis of the analysis of emission characteristics the authors give some recommendations how to determine the temperature of peat combustion products in the furnace of BKZ-210-140F steam boiler. The findings can be used to measure the combustion products temperature, support temperature control in peat combustion and solve the problem of boiler furnace slagging.

  16. Recent Trends in the Production, Combustion and Modeling of Furan-Based Fuels

    Directory of Open Access Journals (Sweden)

    Mazen A. Eldeeb

    2018-02-01

    Full Text Available There is growing interest in the use of furans, a class of alternative fuels derived from biomass, as transportation fuels. This paper reviews recent progress in the characterization of its combustion properties. It reviews their production processes, theoretical kinetic explorations and fundamental combustion properties. The theoretical efforts are focused on the mechanistic pathways for furan decomposition and oxidation, as well as the development of detailed chemical kinetic models. The experiments reviewed are mostly concerned with the temporal evolutions of homogeneous reactors and the propagation of laminar flames. The main thrust in homogeneous reactors is to determine global chemical time scales such as ignition delay times. Some studies have adopted a comparative approach to bring out reactivity differences. Chemical kinetic models with varying degrees of predictive success have been established. Experiments have revealed the relative behavior of their combustion. The growing body of literature in this area of combustion chemistry of alternative fuels shows a great potential for these fuels in terms of sustainable production and engine performance. However, these studies raise further questions regarding the chemical interactions of furans with other hydrocarbons. There are also open questions about the toxicity of the byproducts of combustion.

  17. Performance of a supercharged direct-injection stratified-charge rotary combustion engine

    Science.gov (United States)

    Bartrand, Timothy A.; Willis, Edward A.

    1990-01-01

    A zero-dimensional thermodynamic performance computer model for direct-injection stratified-charge rotary combustion engines was modified and run for a single rotor supercharged engine. Operating conditions for the computer runs were a single boost pressure and a matrix of speeds, loads and engine materials. A representative engine map is presented showing the predicted range of efficient operation. After discussion of the engine map, a number of engine features are analyzed individually. These features are: heat transfer and the influence insulating materials have on engine performance and exhaust energy; intake manifold pressure oscillations and interactions with the combustion chamber; and performance losses and seal friction. Finally, code running times and convergence data are presented.

  18. Combustion performance evaluation of air staging of palm oil blends.

    Science.gov (United States)

    Mohd Jaafar, Mohammad Nazri; Eldrainy, Yehia A; Mat Ali, Muhammad Faiser; Wan Omar, W Z; Mohd Hizam, Mohd Faizi Arif

    2012-02-21

    The problems of global warming and the unstable price of petroleum oils have led to a race to develop environmentally friendly biofuels, such as palm oil or ethanol derived from corn and sugar cane. Biofuels are a potential replacement for fossil fuel, since they are renewable and environmentally friendly. This paper evaluates the combustion performance and emission characteristics of Refined, Bleached, and Deodorized Palm Oil (RBDPO)/diesel blends B5, B10, B15, B20, and B25 by volume, using an industrial oil burner with and without secondary air. Wall temperature profiles along the combustion chamber axis were measured using a series of thermocouples fitted axially on the combustion chamber wall, and emissions released were measured using a gas analyzer. The results show that RBDPO blend B25 produced the maximum emission reduction of 56.9% of CO, 74.7% of NOx, 68.5% of SO(2), and 77.5% of UHC compared to petroleum diesel, while air staging (secondary air) in most cases reduces the emissions further. However, increasing concentrations of RBDPO in the blends also reduced the energy released from the combustion. The maximum wall temperature reduction was 62.7% for B25 at the exit of the combustion chamber.

  19. Performance Evaluation of a High Bandwidth Liquid Fuel Modulation Valve for Active Combustion Control

    Science.gov (United States)

    Saus, Joseph R.; DeLaat, John C.; Chang, Clarence T.; Vrnak, Daniel R.

    2012-01-01

    At the NASA Glenn Research Center, a characterization rig was designed and constructed for the purpose of evaluating high bandwidth liquid fuel modulation devices to determine their suitability for active combustion control research. Incorporated into the rig s design are features that approximate conditions similar to those that would be encountered by a candidate device if it were installed on an actual combustion research rig. The characterized dynamic performance measures obtained through testing in the rig are planned to be accurate indicators of expected performance in an actual combustion testing environment. To evaluate how well the characterization rig predicts fuel modulator dynamic performance, characterization rig data was compared with performance data for a fuel modulator candidate when the candidate was in operation during combustion testing. Specifically, the nominal and off-nominal performance data for a magnetostrictive-actuated proportional fuel modulation valve is described. Valve performance data were collected with the characterization rig configured to emulate two different combustion rig fuel feed systems. Fuel mass flows and pressures, fuel feed line lengths, and fuel injector orifice size was approximated in the characterization rig. Valve performance data were also collected with the valve modulating the fuel into the two combustor rigs. Comparison of the predicted and actual valve performance data show that when the valve is operated near its design condition the characterization rig can appropriately predict the installed performance of the valve. Improvements to the characterization rig and accompanying modeling activities are underway to more accurately predict performance, especially for the devices under development to modulate fuel into the much smaller fuel injectors anticipated in future lean-burning low-emissions aircraft engine combustors.

  20. Oxyfuel combustion using a catalytic ceramic membrane reactor

    Energy Technology Data Exchange (ETDEWEB)

    Tan, Xiaoyao; Li, K. [Department of Chemical Engineering, Imperial College London, University of London, South Kensington, London SW7 2AZ (United Kingdom); Thursfield, A.; Metcalfe, I.S. [School of Chemical Engineering and Advanced Materials, Newcastle University, Newcastle upon Tyne, NE1 7RU (United Kingdom)

    2008-02-29

    Membrane catalytic combustion (MCC) is an environmentally friendly technique for heat and power generation from methane. This work demonstrates the performances of a MCC perovskite hollow fibre membrane reactor for the catalytic combustion of methane. The ionic-electronic La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3-{alpha}} (LSCF6428) mixed conductor, in the form of an oxygen-permeable hollow fibre membrane, has been prepared successfully by means of a phase-inversion spinning/sintering technique. For this process polyethersulfone (PESf) was used as a binder, N-methyl-2-pyrrollidone (NMP) as solvent and polyvinylpyrrolidone (PVP, K16-18) as an additive. With the prepared LSCF6428 hollow fibre membranes packed with catalyst, hollow fibre membrane reactors (HFMRs) have been assembled to perform the catalytic combustion of methane. A simple mathematical model that combines the local oxygen permeation rate with approximate catalytic reaction kinetics has been developed and can be used to predict the performance of the HFMRs for methane combustion. The effects of operating temperature and methane and air feed flow rates on the performance of the HFMR have been investigated both experimentally and theoretically. Both the methane conversion and oxygen permeation rate can be improved by means of coating platinum on the air side of the hollow fibre membranes. (author)

  1. International evaluation of the programme on engine-related combustion

    Energy Technology Data Exchange (ETDEWEB)

    Arcoumanis, D [Imperial College, London (United Kingdom); Greenhalgh, D [Cranfield Univ. (United Kingdom); Magnusson, B F [Norwegian Univ. of Science and Technology, Trondheim (Norway); Peters, N [Institut fuer Technische Mechanik, RWTH Aachen (Germany)

    1996-11-01

    The 12 projects in the engine related combustion programme cover the entire range from fundamental and theoretical aspects of combustion to more applied subjects such as engine control. The common denominator in the programme clearly is the internal combustion engine, both the reciprocating as well as the gas turbine engine. Such a large coverage by a relatively small number of projects necessarily leads to an isolation of some of the projects in terms of their subject as well as the methodology that is used. On the other hand, all the research areas of interest in combustion technology are represented by at least one of the projects. These are: mathematical and numerical methods in combustion; modelling of turbulent combustion; laser diagnostics of flows with combustion; studies of engine performance and their control; semi-empirical model development for practical applications. As a conclusion, the evaluation committee believes that the programme is well balanced between fundamental and applied projects. It covers the entire range of modern methodologies that are used on the international level and thereby contributes to the application and further development of these research tools in Sweden

  2. Effect of excess air on second-generation PFB combustion plant performance and economics

    International Nuclear Information System (INIS)

    Robertson, A.; Garland, R.; Newby, R.; Rehmat, A.; Rubow, L.; Bonk, D.

    1990-01-01

    This paper presents a conceptual design of a 1.4-MPa (14-atm) coal-fired second-generation pressurized fluidized bed (PFB) combustion plant and identifies the performance and economic changes that result as the excess air and thus gas turbine-to-steam turbine power ratio, is changed. The performance of these plants, another second- generation PFB combustion plant, and a conventional pulverized-coal (PC)-fired plant with wet limestone flue gas desulfurization is compared. Depending upon the conditions selected, the PFB combustion plant can achieve a 45 percent efficiency (based on the higher heating value of the coal used as fuel) and a cost of electricity at least 20 percent lower than that of the conventional PC-fired plant

  3. Experimental and theoretical analysis of the combustion process at low loads of a diesel natural gas dual-fuel engine

    International Nuclear Information System (INIS)

    Li, Weifeng; Liu, Zhongchang; Wang, Zhongshu

    2016-01-01

    To construct an effective method to analyze the combustion process of dual fuel engines at low loads, effects of combustion boundaries on the combustion process of an electronically controlled diesel natural gas dual-fuel engine at low loads were investigated. Three typical combustion modes, including h, m and n, appeared under different combustion boundaries. In addition, the time-sequenced characteristic and the heat release rate-imbalanced characteristic were found in the dual fuel engine combustion process. To quantify these characteristics, two quantitative indicators, including the TSC (time-sequenced coefficient) and the HBC (HRR-balanced coefficient) were defined. The results show that increasing TSC and HBC can decrease HC (hydrocarbon) emissions and improve the BTE (brake thermal efficiency) significantly. The engine with the n combustion mode can obtain the highest BTE and the lowest HC emissions, followed by m, and then h. However, the combustion process of the engine will deteriorate sharply if boundary conditions are not strictly controlled in the n combustion mode. Based on the n combustion mode, advancing the start of diesel injection significantly, using large EGR (exhaust gas recirculation) rate and appropriately intake throttling can effectively reduce HC emissions and improve the BTE of dual fuel engines at low loads with relatively high natural gas PES (percentage energy substitution). - Highlights: • We reported three typical combustion modes of a dual-fuel engine at low loads. • Time-sequenced characteristic was put forward and qualified. • HRR-imbalanced characteristic was put forward and qualified. • Three combustion modes appeared as equivalence ratio/diesel injection timing varied. • The engine performance varied significantly with different combustion mode.

  4. Reduced Gravity Studies of Soret Transport Effects in Liquid Fuel Combustion

    Science.gov (United States)

    Shaw, Benjamin D.

    2004-01-01

    Soret transport, which is mass transport driven by thermal gradients, can be important in practical flames as well as laboratory flames by influencing transport of low molecular weight species (e.g., monatomic and diatomic hydrogen). In addition, gas-phase Soret transport of high molecular weight fuel species that are present in practical liquid fuels (e.g., octane or methanol) can be significant in practical flames (Rosner et al., 2000; Dakhlia et al., 2002) and in high pressure droplet evaporation (Curtis and Farrell, 1992), and it has also been shown that Soret transport effects can be important in determining oxygen diffusion rates in certain classes of microgravity droplet combustion experiments (Aharon and Shaw, 1998). It is thus useful to obtain information on flames under conditions where Soret effects can be clearly observed. This research is concerned with investigating effects of Soret transport on combustion of liquid fuels, in particular liquid fuel droplets. Reduced-gravity is employed to provide an ideal (spherically-symmetrical) experimental model with which to investigate effects of Soret transport on combustion. The research will involve performing reduced-gravity experiments on combustion of liquid fuel droplets in environments where Soret effects significantly influence transport of fuel and oxygen to flame zones. Experiments will also be performed where Soret effects are not expected to be important. Droplets initially in the 0.5 to 1 mm size range will be burned. Data will be obtained on influences of Soret transport on combustion characteristics (e.g., droplet burning rates, droplet lifetimes, gas-phase extinction, and transient flame behaviors) under simplified geometrical conditions that are most amenable to theoretical modeling (i.e., spherical symmetry). The experiments will be compared with existing theoretical models as well as new models that will be developed. Normal gravity experiments will also be performed.

  5. Turbulent Combustion Modeling Advances, New Trends and Perspectives

    CERN Document Server

    Echekki, Tarek

    2011-01-01

    Turbulent combustion sits at the interface of two important nonlinear, multiscale phenomena: chemistry and turbulence. Its study is extremely timely in view of the need to develop new combustion technologies in order to address challenges associated with climate change, energy source uncertainty, and air pollution. Despite the fact that modeling of turbulent combustion is a subject that has been researched for a number of years, its complexity implies that key issues are still eluding, and a theoretical description that is accurate enough to make turbulent combustion models rigorous and quantitative for industrial use is still lacking. In this book, prominent experts review most of the available approaches in modeling turbulent combustion, with particular focus on the exploding increase in computational resources that has allowed the simulation of increasingly detailed phenomena. The relevant algorithms are presented, the theoretical methods are explained, and various application examples are given. The book ...

  6. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.; Vedharaj, S.; An, Yanzhao; Dawood, Alaaeldin; Izadi Najafabadi, Mohammad; Somers, Bart; Johansson, Bengt

    2017-01-01

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON

  7. Numerical Investigation on Aerodynamic and Combustion Performance of Chevron Mixer Inside an Afterburner.

    Science.gov (United States)

    Yong, Shan; JingZhou, Zhang; Yameng, Wang

    2014-11-01

    To improve the performance of the afterburner for the turbofan engine, an innovative type of mixer, namely, the chevron mixer, was considered to enhance the mixture between the core flow and the bypass flow. Computational fluid dynamics (CFD) simulations investigated the aerodynamic performances and combustion characteristics of the chevron mixer inside a typical afterburner. Three types of mixer, namely, CC (chevrons tilted into core flow), CB (chevrons tilted into bypass flow), and CA (chevrons tilted into core flow and bypass flow alternately), respectively, were studied on the aerodynamic performances of mixing process. The chevrons arrangement has significant effect on the mixing characteristics and the CA mode seems to be advantageous for the generation of the stronger streamwise vortices with lower aerodynamic loss. Further investigations on combustion characteristics for CA mode were performed. Calculation results reveal that the local temperature distribution at the leading edge section of flame holder is improved under the action of streamwise vortices shedding from chevron mixers. Consequently, the combustion efficiency increased by 3.5% compared with confluent mixer under the same fuel supply scheme.

  8. Carbohydrate-Assisted Combustion Synthesis To Realize High-Performance Oxide Transistors.

    Science.gov (United States)

    Wang, Binghao; Zeng, Li; Huang, Wei; Melkonyan, Ferdinand S; Sheets, William C; Chi, Lifeng; Bedzyk, Michael J; Marks, Tobin J; Facchetti, Antonio

    2016-06-08

    Owing to high carrier mobilities, good environmental/thermal stability, excellent optical transparency, and compatibility with solution processing, thin-film transistors (TFTs) based on amorphous metal oxide semiconductors (AOSs) are promising alternatives to those based on amorphous silicon (a-Si:H) and low-temperature (IGZO) TFTs suffer from low carrier mobilities and/or inferior bias-stress stability versus their sputtered counterparts. Here we report that three types of environmentally benign carbohydrates (sorbitol, sucrose, and glucose) serve as especially efficient fuels for IGZO film combustion synthesis to yield high-performance TFTs. The results indicate that these carbohydrates assist the combustion process by lowering the ignition threshold temperature and, for optimal stoichiometries, enhancing the reaction enthalpy. IGZO TFT mobilities are increased to >8 cm(2) V(-1) s(-1) on SiO2/Si gate dielectrics with significantly improved bias-stress stability. The first correlations between precursor combustion enthalpy and a-MO densification/charge transport are established.

  9. Combustion: an oil spill mitigation tool

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-11-01

    The technical feasibility of using combustion as an oil spill mitigation tool was studied. Part I of the two-part report is a practical guide oriented toward the needs of potential users, while Part II is the research or resource document from which the practical guidance was drawn. The study included theoretical evaluations of combustion of petroleum pool fires under the effects of weathering and an oil classification system related to combustion potential. The theoretical analysis of combustion is balanced by practical experience of oil burning and case history information. Decision elements are provided which can be used as a guide for technical evaluations of a particular oil spill situation. The rationale for assessing technical feasibility is given in the context of other alternatives available for response to an oil spill. A series of research and technology development concepts are included for future research. The ethics of using oil burning are discussed as issues, concerns, and tradeoffs. A detailed annotated bibliography is appended along with a capsule review of a decade of oil burning studies and other support information.

  10. Combustion stratification for naphtha from CI combustion to PPC

    NARCIS (Netherlands)

    Vallinayagam, R.; Vedharaj, S.; An, Y.; Dawood, A.; Izadi Najafabadi, M.; Somers, L.M.T.; Johansson, B.H.

    2017-01-01

    This study demonstrated the change in combustion homogeneity from conventional diesel combustion via partially premixed combustion towards HCCI. Experiments are performed in an optical diesel engine at a speed of 1200 rpm with diesel fuel. Single injection strategy is employed and the fuel is

  11. Co-combustion performance of coal with rice husks and bamboo

    Energy Technology Data Exchange (ETDEWEB)

    Kwong, P.C.W.; Chao, C.Y.H.; Wang, J.H.; Cheung, C.W.; Kendall, G. [Hong Kong University of Science & Technology, Kowloon (China). Dept. of Mechanical Engineering

    2007-11-15

    Biomass has been regarded as an important form of renewable energy due to the reduction of greenhouse gas emission such as carbon dioxide. An experimental study of co-combustion of coal and biomass was performed in a laboratory-scale combustion facility. Rice husks and bamboo were the selected biomass fuels in this study due to their abundance in the Asia-Pacific region. Experimental parameters including the biomass blending ratio in the fuel mixture, relative moisture content and biomass grinding size were investigated. Both energy release data and pollutant emission information were obtained. Due to the decrease in the heating value from adding biomass in the fuel mixture, the combustion temperature and energy output from the co-firing process were reduced compared with coal combustion. On the other hand, gaseous pollutant emissions including carbon monoxide (CO), carbon dioxide (CO{sub 2}), nitrogen oxides (NOx) and sulfur dioxide (SO{sub 2}) were reduced and minimum energy-based emission factors were found in the range of 10-30% biomass blending ratio. With an increase in the moisture content in the biomass, decreases in combustion temperature, SO{sub 2}, NOx and CO{sub 2} emissions were observed, while an increase in CO emissions was found. It has also been observed that chemical kinetics may play an important role compared to mass diffusion in the co-firing process and the change in biomass grinding size does not have much effect on the fuel burning rate and pollutant emissions tinder the current experimental conditions.

  12. Large-scale hydrogen combustion experiments: Volume 2, Data plots: Final report

    International Nuclear Information System (INIS)

    Thompson, R.T.; Torok, R.C.; Randall, D.S.; Sullivan, J.S.; Thompson, L.B.; Haugh, J.J.

    1988-10-01

    Forty large-scale experiments to investigate the combustion behavior of hydrogen during postulated degraded core accidents were conducted in a 16 m (52 ft) diameter sphere. The performance of safety related equipment and cable also was examined. Combustion was initiated by thermal igniters in both premixed hydrogen air-steam atmospheres and during the continuous injection of hydrogen and steam. The effects of steam, igniter location, water sprays, fans and injection rates were studied. Measurements were made of gas concentrations, combustion pressures, temperatures and heat fluxes. Burn fractions and flame speeds also were determined. Near-infrared seeing cameras permitted direct observation of the hydrogen burns. Combustion pressures and temperatures in premixed atmospheres with hydrogen concentrations up to 13 vol% (steam saturated) were less than the theoretical maximum values. Multiple deflagrations were not encountered during continuous hydrogen injection with pre-activated igniters. Moderate pressure rises resulted from diffusion flames. These flames generally were found above the source. Combustion results have been compared to smaller scale experiments. Several safety related equipment items exhibited degraded performance after a number of tests. Most cable samples passed their electrical checks at the end of the test series. These experiments confirm the effectiveness of the deliberate ignition approach to controlling hydrogen. They also provide data for validating computer codes used to predict hydrogen combustion during degraded core accidents, and for assessing the performance of safety related equipment in such environments

  13. Reducing emissions from diesel combustion

    International Nuclear Information System (INIS)

    Anon.

    1992-01-01

    This paper contains information dealing with engine design to reduce emissions and improve or maintain fuel economy. Topics include: Observation of High Pressure Fuel Spray with Laser Light Sheet Method; Determination of Engine Cylinder Pressures from Crankshaft Speed Fluctuations; Combustion Similarity for Different Size Diesel Engines: Theoretical Prediction and Experimental Results; Prediction of Diesel Engine Particulate Emission During Transient Cycles; Characteristics and Combustibility of Particulate Matter; Dual-Fuel Diesel Engine Using Butane; Measurement of Flame Temperature Distribution in D.I. Diesel Engine with High Pressure Fuel Injection: and Combustion in a Small DI Diesel Engine at Starting

  14. Combustion performance of an aluminum melting furnace operating with liquid fuel

    Energy Technology Data Exchange (ETDEWEB)

    Nieckele, Angela Ourivio; Naccache, Monica Feijo; Gomes, Marcos Sebastiao de P. [Pontificia Universidade Catolica (PUC-Rio), Rio de Janeiro, RJ (Brazil). Dept. de Engenharia Mecanica], E-mails: nieckele@puc-rio.br, naccache@puc-rio.br, mspgomes@puc-rio.br

    2010-10-15

    The characteristics associated with the delivery of the fuel to be used as the energy source in any industrial combustion equipment are of extreme importance, as for example, in improving the performance of the combustion process and in the preservation of the equipment. A clean and efficient combustion may be achieved by carefully selecting the fuel and oxidant, as well as the operational conditions of the delivery system for both. In the present work, numerical simulations were carried out using the commercial code FLUENT for analyzing some of the relevant operational conditions inside an aluminum reverb furnace employing liquid fuel and air as the oxidant. Different fuel droplets sizes as well as inlet droplet stream configurations were examined. These characteristics, associated with the burner geometry and the fuel dispersion and delivery system may affect the flame shape, and consequently the temperature and the heat flux distribution within the furnace. Among the results obtained in the simulations, it was shown the possible damages to the equipment, which may occur as a result of the combustion process, if the flame is too long or too intense and concentrated. (author)

  15. Theoretical Study for The Influence of Biodiesel Addition on The Combustion, Performance and Emissions Parameters of Single Cylinder Diesel Engine

    Directory of Open Access Journals (Sweden)

    Mohamed F. Al-Dawody

    2017-08-01

    Full Text Available This study examines the characteristics of combustion, performance and emission of constant speed compression ignition engine fed with different percentages of diesel fuel and rapeseed methyl ester (RME on a volume basis by using the well-known software simulation Diesel-RK. As the percentage of RME increased, the maximal pressure is noticed to be closer to top dead center (TDC. It was found that 47.27 %, 81.06 %, 82.56 % and 93.36 % reduction in the Bosch smoke number is obtainable with 10% RME, 20% RME, 50% RME and 100% RME respectively, compared with ordinary diesel. The blends of RME are noticed to emit higher NOx emissions. The result signals that 10% RME is the promising ratio of blending which reports less performance variations and reduced carbon emissions as well. The effect of variable injection timings is studied to moderate biodiesel NOx effects on the 10% RME and 18 degree crank angle before top dead center (BTDC was recorded as the advisable injection timing which gives a promising reduction in NOx emissions.

  16. Theoretical study of the combustion de pellets of biomass coming from the sugar cane

    International Nuclear Information System (INIS)

    Verdecia Torres, David; Macías Socarrás, Idalberto; Gaskins Espinosa, Benjamín Gabriel

    2012-01-01

    In the follow work they are an a examinations of the kinetic quimestry of the combustions process, we obtain the combustions time in functions of the kinetic combustions model and we made a experiment design for determinations of the theory's mathematics models in that process. (author)

  17. Numerical study of influence of biofuels on the combustion characteristics and performance of aircraft engine system

    International Nuclear Information System (INIS)

    Zhou, Li; Liu, Zeng-wen; Wang, Zhan-xue

    2015-01-01

    The atomization and combustion flowfield of the combustion chamber with swirl-nozzle were simulated using different biofuels; the thermodynamic cycle of the aircraft engine system were also analyzed, influences of biofuels on the combustion characteristics and performance of aircraft engine system were explored. Results show that viscosity and caloric value are key factors affecting the atomization and combustion characteristics of biofuels, and then dominate the distribution of the temperature and NO concentration. Due to the characteristic of low viscosity and low caloric value for biofuels adopted, the biofuels accumulate near the head of combustion chamber, and the corresponding NO emission is lower than that it has for conventional kerosene. When biofuels with low caloric value are used under the operation condition which is same as the condition for the conventional kerosene, lower turbine inlet temperature, lower thrust and higher specific fuel consumption would be achieved for the aircraft engine. - Highlights: • Influences of biofuels properties on combustion characteristic are explored. • Effects of biofuels on cycle parameters of aircraft engine are discussed. • Viscosity and caloric value are key factors affecting combustion of biofuels. • NO emission becomes lower when biofuels with low caloric value is adopted. • The performance of aircraft engine becomes worse for biofuels with low caloric value.

  18. Effects of oxygen enriched combustion on pollution and performance characteristics of a diesel engine

    Directory of Open Access Journals (Sweden)

    P. Baskar

    2016-03-01

    Full Text Available Oxygen enriched combustion is one of the attractive combustion technologies to control pollution and improve combustion in diesel engines. An experimental test was conducted on a single cylinder direct injection diesel engine to study the impact of oxygen enrichment on pollution and performance parameters by increasing the oxygen concentration of intake air from 21 to 27% by volume. The tests results show that the combustion process was improved as there is an increase in thermal efficiency of 4 to 8 percent and decrease in brake specific fuel consumption of 5 to 12 percent. There is also a substantial decrease in unburned hydro carbon, carbon mono-oxide and smoke density levels to the maximum of 40, 55 and 60 percent respectively. However, there is a considerable increase in nitrogen oxide emissions due to increased combustion temperature and extra oxygen available which needs to be addressed.

  19. 40 CFR 60.1025 - Do subpart E new source performance standards also apply to my municipal waste combustion unit?

    Science.gov (United States)

    2010-07-01

    ... standards also apply to my municipal waste combustion unit? 60.1025 Section 60.1025 Protection of... NEW STATIONARY SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which... municipal waste combustion unit? If this subpart AAAA applies to your municipal waste combustion unit, then...

  20. Improved Economic Performance of Municipal Solid Waste Combustion Plants by Model Based Combustion Control

    NARCIS (Netherlands)

    Leskens, M.

    2013-01-01

    The combustion of municipal solid waste (MSW) is used for its inertisation, reduction of its volume and the conversion of its energy content into heat and/or electricity. Operation and control of modern large scale MSW combustion (MSWC) plants is determined by economic and environmental objectives

  1. Performance, combustion and emission analysis of mustard oil biodiesel and octanol blends in diesel engine

    Science.gov (United States)

    Devarajan, Yuvarajan; Munuswamy, Dinesh Babu; Nagappan, Beemkumar; Pandian, Amith Kishore

    2018-01-01

    Biodiesels from the mustard oil promise to be an alternative to the conventional diesel fuel due to their similarity in properties. Higher alcohols are added to neat Mustard oil biodiesel (M100) to vary the properties of biodiesel for improving its combustion, emission and performance characteristics. N-Octanol has the ability to act as an oxygen buffer during combustion which contributes to the catalytic effect and accelerates the combustion process. N-Octanol is dispersed to neat Mustard oil biodiesel in the form of emulsions at different dosage levels of 10, 20 and 30% by volume. Three emulsion fuels prepared for engine testing constitutes of 90% of biodiesel and 10% of n-Octanol (M90O10), 80% of biodiesel and 20% of n-Octanol (M80O20) and 70% of biodiesel and 30% of n-Octanol (M70O30) by volume respectively. AVL 5402 diesel engine is made to run on these fuels to study the effect of n-Octanol on combustion, emission and performance characteristics of the mustard oil biodiesel. Experimental results show that addition of n-octanol has a positive effect on performance, combustion and emission characteristics owing to its inbuilt oxygen content. N-octanol was found to be the better oxidizing catalyst as it was more effective in reducing HC and CO emissions. A significant reduction in NOx emission was found when fuelled with emulsion techniques. The blending of n-octanol to neat Mustard oil biodiesel reduces the energy and fuel consumption and a marginal increase in brake thermal efficiency. Further, n-octanol also reduces the ignition delay and aids the combustion.

  2. Performance, combustion and emission analysis of mustard oil biodiesel and octanol blends in diesel engine

    Science.gov (United States)

    Devarajan, Yuvarajan; Munuswamy, Dinesh Babu; Nagappan, Beemkumar; Pandian, Amith Kishore

    2018-06-01

    Biodiesels from the mustard oil promise to be an alternative to the conventional diesel fuel due to their similarity in properties. Higher alcohols are added to neat Mustard oil biodiesel (M100) to vary the properties of biodiesel for improving its combustion, emission and performance characteristics. N-Octanol has the ability to act as an oxygen buffer during combustion which contributes to the catalytic effect and accelerates the combustion process. N-Octanol is dispersed to neat Mustard oil biodiesel in the form of emulsions at different dosage levels of 10, 20 and 30% by volume. Three emulsion fuels prepared for engine testing constitutes of 90% of biodiesel and 10% of n-Octanol (M90O10), 80% of biodiesel and 20% of n-Octanol (M80O20) and 70% of biodiesel and 30% of n-Octanol (M70O30) by volume respectively. AVL 5402 diesel engine is made to run on these fuels to study the effect of n-Octanol on combustion, emission and performance characteristics of the mustard oil biodiesel. Experimental results show that addition of n-octanol has a positive effect on performance, combustion and emission characteristics owing to its inbuilt oxygen content. N-octanol was found to be the better oxidizing catalyst as it was more effective in reducing HC and CO emissions. A significant reduction in NOx emission was found when fuelled with emulsion techniques. The blending of n-octanol to neat Mustard oil biodiesel reduces the energy and fuel consumption and a marginal increase in brake thermal efficiency. Further, n-octanol also reduces the ignition delay and aids the combustion.

  3. NEDO project reports. High performance industrial furnace development project - High temperature air combustion

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-21

    For the purpose of reducing energy consumption, a NEDO project 'Developmental research on high efficiency industrial furnaces' was carried out from FY 1993 to FY 1999 by The Japan Industrial Furnaces Manufacturers Association, and the paper outlined the details of the project. Industrial furnaces handled in this R and D can bring 30% reduction of the energy consumption and approximately 50% NOx reduction, and were given the 9th Nikkei global environmental technology prize. In the study of combustion phenomena of high temperature air combustion, the paper arranged characteristics of flame, the base of gaseous fuel flame, the base of liquid fuel flame, the base of solid fuel flame, etc. Concerning high temperature air combustion models for simulation, fluid dynamics and heat transfer models, and reaction and NOx models, etc. As to impacts of high temperature air combustion on performance of industrial furnaces, energy conservation, lowering of pollution, etc. In relation to a guide for the design of high efficiency industrial furnaces, flow charts, conceptual design, evaluation method for heat balance and efficiency using charts, combustion control system, applicability of high efficiency industrial furnaces, etc. (NEDO)

  4. NEDO project reports. High performance industrial furnace development project - High temperature air combustion

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2000-03-21

    For the purpose of reducing energy consumption, a NEDO project 'Developmental research on high efficiency industrial furnaces' was carried out from FY 1993 to FY 1999 by The Japan Industrial Furnaces Manufacturers Association, and the paper outlined the details of the project. Industrial furnaces handled in this R and D can bring 30% reduction of the energy consumption and approximately 50% NOx reduction, and were given the 9th Nikkei global environmental technology prize. In the study of combustion phenomena of high temperature air combustion, the paper arranged characteristics of flame, the base of gaseous fuel flame, the base of liquid fuel flame, the base of solid fuel flame, etc. Concerning high temperature air combustion models for simulation, fluid dynamics and heat transfer models, and reaction and NOx models, etc. As to impacts of high temperature air combustion on performance of industrial furnaces, energy conservation, lowering of pollution, etc. In relation to a guide for the design of high efficiency industrial furnaces, flow charts, conceptual design, evaluation method for heat balance and efficiency using charts, combustion control system, applicability of high efficiency industrial furnaces, etc. (NEDO)

  5. Experimental study on combustion modes and thrust performance of a staged-combustor of the scramjet with dual-strut

    Science.gov (United States)

    Yang, Qingchun; Chetehouna, Khaled; Gascoin, Nicolas; Bao, Wen

    2016-05-01

    To enable the scramjet operate in a wider flight Mach number, a staged-combustor with dual-strut is introduced to hold more heat release at low flight Mach conditions. The behavior of mode transition was examined using a direct-connect model scramjet experiment along with pressure measurements. The typical operating modes of the staged-combustor are analyzed. Fuel injection scheme has a significant effect on the combustor operating modes, particularly for the supersonic combustion mode. Thrust performances of the combustor with different combustion modes and fuel distributions are reported in this paper. The first-staged strut injection has a better engine performance in the operation of subsonic combustion mode. On the contrast, the second-staged strut injection has a better engine performance in the operation of supersonic combustion mode.

  6. Impact of CO_2-enriched combustion air on micro-gas turbine performance for carbon capture

    International Nuclear Information System (INIS)

    Best, Thom; Finney, Karen N.; Ingham, Derek B.; Pourkashanian, Mohamed

    2016-01-01

    Power generation is one of the largest anthropogenic greenhouse gas emission sources; although it is now reducing in carbon intensity due to switching from coal to gas, this is only part of a bridging solution that will require the utilization of carbon capture technologies. Gas turbines, such as those at the UK Carbon Capture Storage Research Centre's Pilot-scale Advanced CO_2 Capture Technology (UKCCSRC PACT) National Core Facility, have high exhaust gas mass flow rates with relatively low CO_2 concentrations; therefore solvent-based post-combustion capture is energy intensive. Exhaust gas recirculation (EGR) can increase CO_2 levels, reducing the capture energy penalty. The aim of this paper is to simulate EGR through enrichment of the combustion air with CO_2 to assess changes to turbine performance and potential impacts on complete generation and capture systems. The oxidising air was enhanced with CO_2, up to 6.29%vol dry, impacting mechanical performance, reducing both engine speed by over 400 revolutions per minute and compression temperatures. Furthermore, it affected complete combustion, seen in changes to CO and unburned hydrocarbon emissions. This impacted on turbine efficiency, which increased specific fuel consumption (by 2.9%). CO_2 enhancement could therefore result in significant efficiency gains for the capture plant. - Highlights: • Experimental investigation of the impact of exhaust gas recirculation (EGR) on GT performance. • Combustion air was enhanced with CO_2 to simulate EGR. • EGR impact was ascertained by CO and unburned hydrocarbon changes. • Primary factor influencing performance was found to be oxidiser temperature. • Impact of CO_2 enhancement on post-combustion capture efficiency.

  7. Development of High Efficiency Clean Combustion Engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines

    Energy Technology Data Exchange (ETDEWEB)

    Marriott, Craig; Gonzalez, Manual; Russell, Durrett

    2011-06-30

    This report summarizes activities related to the revised STATEMENT OF PROJECT OBJECTIVES (SOPO) dated June 2010 for the Development of High-Efficiency Clean Combustion engine Designs for Spark-Ignition and Compression-Ignition Internal Combustion Engines (COOPERATIVE AGREEMENT NUMBER DE-FC26-05NT42415) project. In both the spark- (SI) and compression-ignition (CI) development activities covered in this program, the goal was to develop potential production-viable internal combustion engine system technologies that both reduce fuel consumption and simultaneously met exhaust emission targets. To be production-viable, engine technologies were also evaluated to determine if they would meet customer expectations of refinement in terms of noise, vibration, performance, driveability, etc. in addition to having an attractive business case and value. Prior to this activity, only proprietary theoretical / laboratory knowledge existed on the combustion technologies explored The research reported here expands and develops this knowledge to determine series-production viability. Significant SI and CI engine development occurred during this program within General Motors, LLC over more than five years. In the SI program, several engines were designed and developed that used both a relatively simple multi-lift valve train system and a Fully Flexible Valve Actuation (FFVA) system to enable a Homogeneous Charge Compression Ignition (HCCI) combustion process. Many technical challenges, which were unknown at the start of this program, were identified and systematically resolved through analysis, test and development. This report documents the challenges and solutions for each SOPO deliverable. As a result of the project activities, the production viability of the developed clean combustion technologies has been determined. At this time, HCCI combustion for SI engines is not considered production-viable for several reasons. HCCI combustion is excessively sensitive to control variables

  8. Optical Tomography in Combustion

    DEFF Research Database (Denmark)

    Evseev, Vadim

    spectral measurements at several line-of-sights with a view to applications for tomographic measurements on full-scale industrial combustion systems. The system was successfully applied on industrial scale for simultaneous fast exhaust gas temperature measurements in the three optical ports of the exhaust......D project, it was also important to investigate the spectral properties of major combustion species such as carbon dioxide and carbon monoxide in the infrared range at high temperatures to provide the theoretical background for the development of the optical tomography methods. The new software....... JQSRT 113 (2012) 2222, 10.1016/j.jqsrt.2012.07.015] included in the PhD thesis as an attachment. The knowledge and experience gained in the PhD project is the first important step towards introducing the advanced optical tomography methods of combustion diagnostics developed in the project to future...

  9. Turbine Burners: Turbulent Combustion of Liquid Fuels

    National Research Council Canada - National Science Library

    Sirignano, William A; Liu, Feng; Dunn-Rankin, Derek

    2006-01-01

    The proposed theoretical/computational and experimental study addresses the vital two-way coupling between combustion processes and fluid dynamic phenomena associated with schemes for burning liquid...

  10. Kinetics of coal combustion: Part 3, Mechanisms and kinetics of char combustion

    Energy Technology Data Exchange (ETDEWEB)

    Gavalas, G. R.; Flagan, R. C. [California Inst. of Tech., Pasadena, CA (USA)

    1988-09-01

    This report summarizes a three-year research program aimed at developing this level of understanding of char combustion through a combination of detailed analysis of chars as produced during devolatilization and as they evolve during oxidation, and theoretical studies of the porous microstructures and of pore diffusion and reaction within the coal particles. A small number of coals have been studied in detail, namely a HVA bituminous (PSOC 1451), a sub-bituminous (PSOC 1488), and a lignite (PSOC 1443). Chars have been generated from size-classified samples of these coals by pyrolysis in an inert atmosphere in a drop tube furnace. The chars were then characterized both chemically and physically. Subsequent oxidation studies were performed on these chars. 42 refs., 54 figs., 4 tabs.

  11. Coal combustion aerothermochemistry research. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Witte, A.B.; Gat, N.; Denison, M.R.; Cohen, L.M.

    1980-12-15

    On the basis of extensive aerothermochemistry analyses, laboratory investigations, and combustor tests, significant headway has been made toward improving the understanding of combustion phenomena and scaling of high swirl pulverized coal combustors. A special attempt has been made to address the gap between scientific data available on combustion and hardware design and scaling needs. Both experimental and theoretical investigations were conducted to improve the predictive capability of combustor scaling laws. The scaling laws derived apply to volume and wall burning of pulverized coal in a slagging high-swirl combustor. They incorporate the findings of this investigation as follows: laser pyrolysis of coal at 10/sup 6/ K/sec and 2500K; effect of coal particle shape on aerodynamic drag and combustion; effect of swirl on heat transfer; coal burnout and slag capture for 20 MW/sub T/ combustor tests for fine and coarse coals; burning particle trajectories and slag capture; particle size and aerodynamic size; volatilization extent and burnout fraction; and preheat level. As a result of this work, the following has been gained: an increased understanding of basic burning mechanisms in high-swirl combustors and an improved model for predicting combustor performance which is intended to impact hardware design and scaling in the near term.

  12. Combustion-assisted laser cutting of a difficult-to-machine superalloy

    International Nuclear Information System (INIS)

    Molian, P.A.

    1992-01-01

    In laser cutting, the largest single application of lasers in manufacturing, the assist gas plays an important role in affecting the cutting performance. The assist gas is usually oxygen or an inert gas. In this paper acetylene and oxygen was employed to create combustion reactions during CO 2 laser cutting that enabled an improvement in the cutting speed, and cut quality of a difficult-to-machine superalloy. A comparison with laser cutting of a plain carbon steel under identical conditions was also made to determine the usefulness of combustion energy. Results indicate that both cutting speed and quality are enhanced by the reduction in the viscosity of slag formed during cutting (which assisted in ejection of the slag through the bottom of the kerf) due to the heat released by the acetylene burning inside the kerf. Correlations of experimental data with a theoretical model provided the influence of combustion power and gas-flow power on the cutting phenomena

  13. Staged, High-Pressure Oxy-Combustion Technology: Development and Scale-Up

    Energy Technology Data Exchange (ETDEWEB)

    Axelbaum, Richard [Washington Univ., St. Louis, MO (United States); Kumfer, Benjamin [Washington Univ., St. Louis, MO (United States); Gopan, Akshay [Washington Univ., St. Louis, MO (United States); Yang, Zhiwei [Washington Univ., St. Louis, MO (United States); Phillips, Jeff [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Pint, Bruce [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

    2017-12-29

    The immediate need for a high efficiency, low cost carbon capture process has prompted the recent development of pressurized oxy-combustion. With a greater combustion pressure the dew point of the flue gas is increased, allowing for effective integration of the latent heat of flue gas moisture into the Rankine cycle. This increases the net plant efficiency and reduces costs. A novel, transformational process, named Staged, Pressurized Oxy-Combustion (SPOC), achieves additional step changes in efficiency and cost reduction by significantly reducing the recycle of flue gas. The research and development activities conducted under Phases I and II of this project (FE0009702) include: SPOC power plant cost and performance modeling, CFD-assisted design of pressurized SPOC boilers, theoretical analysis of radiant heat transfer and ash deposition, boiler materials corrosion testing, construction of a 100 kWth POC test facility, and experimental testing. The results of this project have advanced the technology readiness level (TRL) of the SPOC technology from 1 to 5.

  14. Combustion and environmental performance of clean coal end products

    Energy Technology Data Exchange (ETDEWEB)

    Skodras, G.; Sakellaropoulos, G. [Centre for Research and Technology, Hellas, Ptolemaidas-Kozanis, Ptolemaida (Greece). Inst. for Solid Fuel Technolgy and Applications]|[Aristotle Univ. of Thessaloniki, Thessaloniki (Greece). Dept. of Chemical Engineering, Chemical Process Engineering Lab]|[Chemical Process Engineering Research Inst., Thessaloniki (Greece). Lab. of Solid Fuels and Environment; Someus, E. [Thermal Desorption Technology Group (Greece); Grammelis, P.; Amarantos, P.S. [Centre for Research and Technology, Hellas, Ptolemaidas-Kozanis, Ptolemaida (Greece). Inst. for Solid Fuel Technolgy and Applications; Palladas, A.; Basinas, P.; Natas, P.; Prokopidou, M.; Diamantopoulou, I.; Sakellaropoulos, G. [Aristotle Univ. of Thessaloniki, Thessaloniki (Greece). Dept. of Chemical Engineering, Chemical Process Engineering Lab

    2006-07-01

    Clean and affordable power production is needed in order to achieve sustainable economic development. This paper focused on clean coal technologies in which coal-fired power plants are used in conjunction with large amounts of renewable energy sources to offer a high level of process safety and long term management of all residual operation streams. Thermal Desorption Recycle-Reduce-Reuse Technology (TDT-3R) was described as being a promising solid fuel pretreatment process for clean energy production up to 300 MWe capacities. TDT-3R is based on low temperature carbonisation fuel pre-treatment principles, which produce cleansed anthracite type fuels from coal and other carbonaceous material such as biomass and organic wastes. The combustion efficiency of such clean coals and the environmental performance of the TDT-3R process were investigated in this study via pilot scale tests of clean fuel production. Tests included flue gas emissions monitoring, raw fuel and product characterisation and thermogravimetric tests, polychlorinated dibenzo-p-dioxins and dibenzo-furans, and heavy metals analyses, and toxicity tests. Raw material included coal and biomass, such as willow, straw and demolition wood. The fuels were heated in a rotary kiln operating at 550 degrees C under slightly vacuum conditions. Clean coals were tested either alone or in conjunction with biomass fuels in a pilot scale combustion facility at Dresden, Germany. The clean coal samples were shown to have higher fixed carbon and ash content and lower volatiles compared to the respective raw coal samples. The major advantage of the TDT-3R process is the production of fuels with much lower pollutants content. Low nitrogen, sulphur, chlorine and heavy metal contents result in produced fuels that have excellent environmental performance, allow boiler operation in higher temperatures and overall better efficiency. Moreover, the use of clean fuels reduces deposition problems in the combustion chamber due to the

  15. Influence of Coal Quality on Combustion Performance

    DEFF Research Database (Denmark)

    Lans, Robert Pieter Van Der; Glarborg, Peter; Dam-Johansen, Kim

    1998-01-01

    mixing pattern on NO formation under these conditions. Emissions from the opposed fired plant with all combustion air introduced through the burners could only be qualitatively reproduced by the pilot furnace. Under single stage conditions the test rig provided higher NO levels. Carbon in ash levels did...... not show any correlation between the coals and the furnaces. An engineering, mathematical model has been developed describing radiation heat transfer and coal combustion in full scale furnaces. The model has been validated against measured temperatures and the amount of carbon in fly ash. The model...

  16. Studies in combustion dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Koszykowski, M.L. [Sandia National Laboratories, Livermore, CA (United States)

    1993-12-01

    The goal of this program is to develop a fundamental understanding and a quantitative predictive capability in combustion modeling. A large part of the understanding of the chemistry of combustion processes comes from {open_quotes}chemical kinetic modeling.{close_quotes} However, successful modeling is not an isolated activity. It necessarily involves the integration of methods and results from several diverse disciplines and activities including theoretical chemistry, elementary reaction kinetics, fluid mechanics and computational science. Recently the authors have developed and utilized new tools for parallel processing to implement the first numerical model of a turbulent diffusion flame including a {open_quotes}full{close_quotes} chemical mechanism.

  17. Performance and combustion characteristics of direct-injection stratified-charge rotary engines

    Science.gov (United States)

    Nguyen, Hung Lee

    1987-01-01

    Computer simulations of the direct-injection stratified-charge (DISC) Wankel engine have been used to calculate heat release rates and performance and efficiency characteristics of the 1007R engine. Engine pressure data have been used in a heat release analysis to study the effects of heat transfer, leakage, and crevice flows. Predicted engine performance data are compared with experimental test data over a range of engine speeds and loads. An examination of methods to improve the performance of the Wankel engine with faster combustion, reduced leakage, higher compression ratio, and turbocharging is presented.

  18. Experimental and theoretical analysis of cell module output performance for a thermophotovoltaic system

    International Nuclear Information System (INIS)

    Xu, Xiaojie; Ye, Hong; Xu, Yexin; Shen, Mingrong; Zhang, Xiaojing; Wu, Xi

    2014-01-01

    Highlights: • An accurate theoretical model for thermophotovoltaic system is constructed. • Parallel connected module is superior if radiator temperature is uneven. • Series connected module is superior if cell temperature is uneven. • Short circuit current of series module rises when the shunt resistance decreases. • Fill factor is not always accurate to evaluate the module performance. - Abstract: An experimental thermophotovoltaic (TPV) system with a cylindrical-geometry radiator was established to test the output performances of modules under different conditions. The results demonstrate that the output performance of a cell module decreases when the combustion power increases because of the uneven temperature of the radiator or cells. On this basis, a theoretical model for a TPV system was constructed to compare the performance under different conditions of the series-connected (SC) module and the parallel-connected (PC) module, and was verified by the experimental results. The influences of the temperature gradient of the radiator or the cell module, and the series and shunt resistance of the TPV cell on the module performance were analyzed in detail. The results demonstrate that the PC module can effectively reduce the mismatch loss of output power caused by the uneven radiator temperature. The PC module, for instance, has a maximum output power of 2.54 times higher than that of the SC module when the radiator temperature difference is 500 K. However, the output performance of the module connected in series is superior to the PC module while the cell temperature is non-uniform. The output power of the SC module is 9.93% higher than that of the PC module at the cell temperature difference of 125 K. The short circuit current of the SC module is sensitive to the series and shunt resistance if the radiator temperature distribution is non-uniform. As the shunt resistance falls from ∞ to 0.5 Ω, the current varies from 1.757 A to 4.488 A when the

  19. An experimental investigation of concentrated slop combustion characteristics in cyclone furnace

    Science.gov (United States)

    Panpokha, Suphaopich; Wongwuttanasatian, Tanakorn; Tangchaichit, Kiatfa

    2018-02-01

    Slop is a by-product in alcoholic industries requiring costly waste management. An idea of using slop as a fuel in a boiler for the industries was proposed. Due to high content of ash, a cyclone furnace was designed to combust the slop. This study aims to examine the concentrated slop combustion in a designed cyclone furnace, consisting of combustion temperature and exhaust gases. The tests were carried out under 4 different air-fuel ratios. Fuels injected into the furnace were 3 g/s of concentrated slop and 1 g/s of diesel. The air-fuel ratios were corresponding to 100, 120, 140 and 160 percent theoretical air. The results demonstrated that combustion of concentrated slop can gave temperature of 800-1000°C and a suitable theoretical air was 100%-120%, because the combustion temperature was higher than that of other cases. In cyclone combustion, excess air is not recommended because it affects a reduction in overall temperature inside the cyclone furnace. It is expected that utilization of the concentrated slop (by-product) will be beneficial in the development of green and zero waste factory.

  20. Combustion, emission and engine performance characteristics of used cooking oil biodiesel - A review

    Energy Technology Data Exchange (ETDEWEB)

    Enweremadu, C.C. [Department of Mechanical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa); Rutto, H.L. [Department of Chemical Engineering, Vaal University of Technology, Private Bag X021, Vanderbijlpark 1900 (South Africa)

    2010-12-15

    As the environment degrades at an alarming rate, there have been steady calls by most governments following international energy policies for the use of biofuels. One of the biofuels whose use is rapidly expanding is biodiesel. One of the economical sources for biodiesel production which doubles in the reduction of liquid waste and the subsequent burden of sewage treatment is used cooking oil (UCO). However, the products formed during frying, such as free fatty acid and some polymerized triglycerides, can affect the transesterification reaction and the biodiesel properties. This paper attempts to collect and analyze published works mainly in scientific journals about the engine performance, combustion and emissions characteristics of UCO biodiesel on diesel engine. Overall, the engine performance of the UCO biodiesel and its blends was only marginally poorer compared to diesel. From the standpoint of emissions, NOx emissions were slightly higher while un-burnt hydrocarbon (UBHC) emissions were lower for UCO biodiesel when compares to diesel fuel. There were no noticeable differences between UCO biodiesel and fresh oil biodiesel as their engine performances, combustion and emissions characteristics bear a close resemblance. This is probably more closely related to the oxygenated nature of biodiesel which is almost constant for every biodiesel (biodiesel has some level of oxygen bound to its chemical structure) and also to its higher viscosity and lower calorific value, which have a major bearing on spray formation and initial combustion. (author)

  1. The effect of the composition of hydrocarbon streams on physical properties and HCCI combustion performance

    Energy Technology Data Exchange (ETDEWEB)

    Gieleciak, R. [National Centre for Upgrading Technology, Devon, AB (Canada); Natural Resources Canada, Devon, AB (Canada). CanmetENERGY

    2009-07-01

    Advanced combustion engines have been developed in tandem with evolving fuels and combustion strategies. Advanced analytical methods such as NMR and two dimensional gas chromatography (2D-GC) are also becoming both more powerful and easier to use. Statistical analysis can be used to link the very complex fuel analysis data sets from these methods to fuel chemistry, fuel properties and engine performance. This poster highlighted a study that applied an advanced statistical analysis technique to 2D-GC data for 17 oil sands derived fuels and correlated results to measured fuel chemical/physical properties, and then to HCCI engine performance. In the HCCI mode, ignition occurs by compression of the homogeneous fuel/air mixture. Advanced combustion strategies must satisfy the need for high efficiency, low emissions, and drivability. The 2D-GC was shown to be an emerging analytical technique which separates compounds in fuels to enable the identification of individual compounds and group compounds by chemistry and boiling points. The Q(2d)RPR technique allows correlations to be developed between the 2D-GC data and fuel chemical / physical properties and engine performance data. tabs., figs.

  2. Engine combustion network (Ecn) : characterization and comparison of boundary conditions for different combustion vessels

    NARCIS (Netherlands)

    Meijer, M.; Somers, L.M.T.; Johnson, J.; Naber, J.; Lee, S.Y.; Malbec, L.M.; Bruneaux, G.; Pickett, L.M.; Bardi, M.; Payri, R.; Bazyn, T.

    2012-01-01

    The Engine Combustion Network (ECN) is a worldwide group of institutions using combustion vessels and/or performing computational fluid dynamics (CFD) simulation, whose aim is to advance the state of spray and combustion knowledge at engine-relevant conditions. A key activity is the use of spray

  3. Four-Stroke, Internal Combustion Engine Performance Modeling

    Science.gov (United States)

    Wagner, Richard C.

    In this thesis, two models of four-stroke, internal combustion engines are created and compared. The first model predicts the intake and exhaust processes using isentropic flow equations augmented by discharge coefficients. The second model predicts the intake and exhaust processes using a compressible, time-accurate, Quasi-One-Dimensional (Q1D) approach. Both models employ the same heat release and reduced-order modeling of the cylinder charge. Both include friction and cylinder loss models so that the predicted performance values can be compared to measurements. The results indicate that the isentropic-based model neglects important fluid mechanics and returns inaccurate results. The Q1D flow model, combined with the reduced-order model of the cylinder charge, is able to capture the dominant intake and exhaust fluid mechanics and produces results that compare well with measurement. Fluid friction, convective heat transfer, piston ring and skirt friction and temperature-varying specific heats in the working fluids are all shown to be significant factors in engine performance predictions. Charge blowby is shown to play a lesser role.

  4. Fuels and Combustion | Transportation Research | NREL

    Science.gov (United States)

    Fuels and Combustion Fuels and Combustion This is the March 2015 issue of the Transportation and , combustion strategy, and engine design hold the potential to maximize vehicle energy efficiency and performance of low-carbon fuels in internal combustion engines with a whole-systems approach to fuel chemistry

  5. COMBUSTION AND PERFORMANCE CHARACTERISTICS OF A SMALL SPARK IGNITION ENGINE FUELLED WITH HCNG

    Directory of Open Access Journals (Sweden)

    A. SONTHALIA

    2015-04-01

    Full Text Available Due to environmental concerns and fossil fuel depletion, large scale researches were carried out involving the use of natural gas in internal combustion engines. Natural gas is a clean burning fuel that is available from large domestic natural reserve. When it is used as a fuel in SI engines, it reduces emissions to meet EURO-III norms with carburettors and EURO-IV norms with manifold injection. Countries like India with fewer natural fossil fuel reserves depend heavily on oil imported from Middle East Asian countries and on the other hand combustion of fossil fuel has negative impact on air quality in urban areas. Use of CNG as a fuel in internal combustion engines can reduce the intensiveness of these pervasive problems. The performance of CNG can further be improved by addition of small percentages of hydrogen to it to overcome the drawbacks like lower energy density of the fuel, drop in engine power and engine out exhaust emissions. When hydrogen is added to CNG it is called as Hythane or Hydrogen enriched Compressed Natural Gas (HCNG. This can be considered as a first step towards promotion of hydrogen in automobiles. In this study, the effects of mixing hydrogen with CNG on a small air cooled four stroke SI engine’s performance, emissions and heat release rate was analyzed. A comparison of performance and emission by running engine separately on gasoline, hydrogen, CNG and HCNG was done. The results show a significant decrease in HC, CO and NOx emissions and marginal increase in specific energy consumption when fuelled with HCNG.

  6. Robust active combustion control for the optimization of environmental performance and energy efficiency

    Science.gov (United States)

    Demayo, Trevor Nat

    Criteria pollutant regulations, climate change concerns, and energy conservation efforts are placing strict constraints in the design and operation of advanced, stationary combustion systems. To ensure minimal pollutant emissions and maximal efficiency at every instant of operation while preventing reaction blowout, combustion systems need to react and adapt in real-time to external changes. This study describes the development, demonstration, and evaluation of a multivariable feedback control system, designed to maximize the performance of natural gas-fired combustion systems. A feedback sensor array was developed to monitor reaction stability and measure combustion performance as a function of NOx, CO, and O, emissions. Acoustic and UV chemiluminescent emissions were investigated for use as stability indicators. Modulated signals of CH* and CO2* chemiluminescence were found to correlate well with the onset of lean blowout. A variety of emissions sensors were tested and evaluated, including conventional CEMS', micro-fuel cells, a zirconia NOx transducer, and a rapid response predictive NOx sensor based on UV flame chemiluminescence. A dual time-scale controller was designed to actively optimize operating conditions by maximizing a multivariable performance function J using a linear direction set search algorithm. The controller evaluated J under slow, quasi steady-state conditions, while dynamically monitoring the reaction zone at high speed for pre-blowout instabilities or boundary condition violations. To establish the input control parameters, two burner systems were selected: a 30 kW air-swirl, generic research burner, and a 120 kW scaled, fuel-staged, industrial boiler burner. The parameters, chosen to most affect burner performance, consisted of air swirl intensity and excess air for the generic burner, and fuel-staging and excess air for the boiler burner. A set of optimization parameters was also established to ensure efficient and deterministic

  7. Combustion Stratification for Naphtha from CI Combustion to PPC

    KAUST Repository

    Vallinayagam, R.

    2017-03-28

    This study demonstrates the combustion stratification from conventional compression ignition (CI) combustion to partially premixed combustion (PPC). Experiments are performed in an optical CI engine at a speed of 1200 rpm for diesel and naphtha (RON = 46). The motored pressure at TDC is maintained at 35 bar and fuelMEP is kept constant at 5.1 bar to account for the difference in fuel properties between naphtha and diesel. Single injection strategy is employed and the fuel is injected at a pressure of 800 bar. Photron FASTCAM SA4 that captures in-cylinder combustion at the rate of 10000 frames per second is employed. The captured high speed video is processed to study the combustion homogeneity based on an algorithm reported in previous studies. Starting from late fuel injection timings, combustion stratification is investigated by advancing the fuel injection timings. For late start of injection (SOI), a direct link between SOI and combustion phasing is noticed. At early SOI, combustion phasing depends on both intake air temperature and SOI. In order to match the combustion phasing (CA50) of diesel, the intake air temperature is increased to 90°C for naphtha. The combustion stratification from CI to PPC is also investigated for various level of dilution by displacing oxygen with nitrogen in the intake. The start of combustion (SOC) was delayed with the increase in dilution and to compensate for this, the intake air temperature is increased. The mixture homogeneity is enhanced for higher dilution due to longer ignition delay. The results show that high speed image is initially blue and then turned yellow, indicating soot formation and oxidation. The luminosity of combustion images decreases with early SOI and increased dilution. The images are processed to generate the level of stratification based on the image intensity. The level of stratification is same for diesel and naphtha at various SOI. When O concentration in the intake is decreased to 17.7% and 14

  8. Dynamic estimator for determining operating conditions in an internal combustion engine

    Science.gov (United States)

    Hellstrom, Erik; Stefanopoulou, Anna; Jiang, Li; Larimore, Jacob

    2016-01-05

    Methods and systems are provided for estimating engine performance information for a combustion cycle of an internal combustion engine. Estimated performance information for a previous combustion cycle is retrieved from memory. The estimated performance information includes an estimated value of at least one engine performance variable. Actuator settings applied to engine actuators are also received. The performance information for the current combustion cycle is then estimated based, at least in part, on the estimated performance information for the previous combustion cycle and the actuator settings applied during the previous combustion cycle. The estimated performance information for the current combustion cycle is then stored to the memory to be used in estimating performance information for a subsequent combustion cycle.

  9. Second law comparison of oxy-fuel combustion and post-combustion carbon dioxide separation

    International Nuclear Information System (INIS)

    Simpson, Adam P.; Simon, A.J.

    2007-01-01

    To define 2nd law efficiency targets for novel separation technologies, a simplified model of a power plant with two forms of CO 2 capture was developed. In this investigation, oxy-fuel combustion and post-combustion CO 2 separation were compared on an exergetic basis. Using exergy balances and black-box models of power plant components, multiple scenarios were run to determine the impact of plant configuration and separation unit efficiency on overall plant performance. Second law efficiency values from the literature were used to set the baseline performance of various CO 2 separation configurations. Assumed advances in 2nd law efficiency were used to determine the potential for overall system performance improvement. It was found that the 2nd law efficiency of air separation must reach a critical value before the thermodynamics of oxy-fuel combustion become favorable. Changes in operating equivalence ratio significantly move the tipping-point between post-combustion and oxy-fuel strategies

  10. Effects of setting new source performance standards for fluidized-bed combustion systems

    Energy Technology Data Exchange (ETDEWEB)

    1978-02-01

    This study was undertaken for the US Environmental Protection Agency to examine the potential consequences of revisions in New Source Performance Standards (NSPS) on fluidized-bed combustor-based steam electric generators of greater than 250,000,000 Btu. A study of the appropriateness and differential effects of alternate regulatory approaches to the standards-setting process was made. Problems dealing with an emerging technology such as fluidized-bed combustion were emphasized. Finally, an examination was made of the potential benefits of fluidized-bed combustion (FBC) systems relative to conventional coal-fired systems equipped with scrubbers. Information is included on the relative advantages and disadvantages of utility-sized fluidized-bed combustors, the technical consequences of NSPS alternatives, policy implications concerning NSPS for steam-electric generators, and cost models for atmospheric and pressurized FBC systems. (LCL)

  11. Research on combustion of black-liquor drops

    International Nuclear Information System (INIS)

    Macek, A.

    1999-01-01

    Black liquor, the major by-product of the kraft process for production of pulp, is one of the most important industrial fuels. It is burned in recovery boilers in the form of large spray drops (mm), with the objective of simultaneous recovery of heat and chemicals (sodium and sulfur). Even though black-liquor combustion in boilers has been practised for over half a century, research efforts toward improvement of combustion efficiency and abatement of environmental emissions are much more recent. The present paper addresses a specific aspect of that research, namely, elucidation of processes which occur during combustion of black-liquor drops in boiler-gas streams. The paper (a) gives a brief description of the kraft process, (b) reviews the experimental and theoretical (modeling) research advances on combustion of kraft-liquor drops during the 1980s and 1990s, (c) re-examines the results of an earlier combustion study in which black-liquor drops were observed in free flight at temperatures near those in recovery boilers, and (d) recommends input for the modeling of in-flight combustion of kraft-liquor drops in recovery boilers. (author)

  12. Analysis of combustion performance and emission of extended expansion cycle and iEGR for low heat rejection turbocharged direct injection diesel engines

    Directory of Open Access Journals (Sweden)

    Shabir Mohd F.

    2014-01-01

    Full Text Available Increasing thermal efficiency in diesel engines through low heat rejection concept is a feasible technique. In LHR engines the high heat evolution is achieved by insulating the combustion chamber surfaces and coolant side of the cylinder with partially stabilized zirconia of 0.5 mm thickness and the effective utilization of this heat depend on the engine design and operating conditions. To make the LHR engines more suitable for automobile and stationary applications, the extended expansion was introduced by modifying the inlet cam for late closing of intake valve through Miller’s cycle for extended expansion. Through the extended expansion concept the actual work done increases, exhaust blow-down loss reduced and the thermal efficiency of the LHR engine is improved. In LHR engines, the formation of nitric oxide is more, to reduce the nitric oxide emission, the internal EGR is incorporated using modified exhaust cam with secondary lobe. Modifications of gas exchange with internal EGR resulted in decrease in nitric oxide emissions. In this work, the parametric studies were carried out both theoretically and experimentally. The combustion, performance and emission parameters were studied and were found to be satisfactory.

  13. Electrochemical Performance of LixMn2-yFeyO4-zClz Synthesized Through In-Situ Glycine Nitrate Combustion

    Science.gov (United States)

    2016-06-13

    Electrochemical Performance of LixMn2-yFeyO4-zClz Synthesized Through In-Situ Glycine Nitrate Combustion Ashley L. Ruth, Paula C. Latorre, and...sites as well as the formation of Mn3+ ions via the Jahn- Teller effect. The use of the glycine nitrate combustion synthesis produces small particles at...advantage of submicron ceramic synthesis, namely the glycine nitrate combustion process (GNP), we propose the capability for in-situ B-site doping

  14. Combustion physics

    Science.gov (United States)

    Jones, A. R.

    1985-11-01

    Over 90% of our energy comes from combustion. By the year 2000 the figure will still be 80%, even allowing for nuclear and alternative energy sources. There are many familiar examples of combustion use, both domestic and industrial. These range from the Bunsen burner to large flares, from small combustion chambers, such as those in car engines, to industrial furnaces for steel manufacture or the generation of megawatts of electricity. There are also fires and explosions. The bountiful energy release from combustion, however, brings its problems, prominent among which are diminishing fuel resources and pollution. Combustion science is directed towards finding ways of improving efficiency and reducing pollution. One may ask, since combustion is a chemical reaction, why physics is involved: the answer is in three parts. First, chemicals cannot react unless they come together. In most flames the fuel and air are initially separate. The chemical reaction in the gas phase is very fast compared with the rate of mixing. Thus, once the fuel and air are mixed the reaction can be considered to occur instantaneously and fluid mechanics limits the rate of burning. Secondly, thermodynamics and heat transfer determine the thermal properties of the combustion products. Heat transfer also plays a role by preheating the reactants and is essential to extracting useful work. Fluid mechanics is relevant if work is to be performed directly, as in a turbine. Finally, physical methods, including electric probes, acoustics, optics, spectroscopy and pyrometry, are used to examine flames. The article is concerned mainly with how physics is used to improve the efficiency of combustion.

  15. Supersonic Combustion of Hydrogen Jets System in Hypersonic Stream

    International Nuclear Information System (INIS)

    Zhapbasbaev, U.K.; Makashev, E.P.

    2003-01-01

    The data of calculated theoretical investigations of diffusive combustion of plane supersonic hydrogen jets in hypersonic stream received with Navier-Stokes parabola equations closed by one-para metrical (k-l) model of turbulence and multiply staged mechanism of hydrogen oxidation are given. Combustion mechanisms depending on the operating parameters are discussing. The influences of air stream composition and ways off fuel feed to the length of ignition delay and level quantity of hydrogen bum-out have been defined. The calculated theoretical results of investigations permit to make the next conclusions: 1. The diffusive combustion of the system of plane supersonic hydrogen jets in hypersonic flow happens in the cellular structures with alternation zones of intensive running of chemical reactions with their inhibition zones. 2. Gas dynamic and heat Mach waves cause a large - scale viscous formation intensifying mixing of fuel with oxidizer. 3. The system ignition of plane supersonic hydrogen jets in hypersonic airy co-flow happens with the formation of normal flame front of hydrogen airy mixture with transition to the diffusive combustion. 4. The presence of active particles in the flow composition initiates the ignition of hydrogen - airy mixture, provides the intensive running of chemical reactions and shortens the length of ignition delay. 5. The supersonic combustion of hydrogel-airy mixture is characterized by two zones: the intensive chemical reactions with an active energy heat release is occurring in the first zone and in the second - a slow hydrogen combustion limited by the mixing of fuel with oxidizer. (author)

  16. Spray-combustion synthesis: efficient solution route to high-performance oxide transistors.

    Science.gov (United States)

    Yu, Xinge; Smith, Jeremy; Zhou, Nanjia; Zeng, Li; Guo, Peijun; Xia, Yu; Alvarez, Ana; Aghion, Stefano; Lin, Hui; Yu, Junsheng; Chang, Robert P H; Bedzyk, Michael J; Ferragut, Rafael; Marks, Tobin J; Facchetti, Antonio

    2015-03-17

    Metal-oxide (MO) semiconductors have emerged as enabling materials for next generation thin-film electronics owing to their high carrier mobilities, even in the amorphous state, large-area uniformity, low cost, and optical transparency, which are applicable to flat-panel displays, flexible circuitry, and photovoltaic cells. Impressive progress in solution-processed MO electronics has been achieved using methodologies such as sol gel, deep-UV irradiation, preformed nanostructures, and combustion synthesis. Nevertheless, because of incomplete lattice condensation and film densification, high-quality solution-processed MO films having technologically relevant thicknesses achievable in a single step have yet to be shown. Here, we report a low-temperature, thickness-controlled coating process to create high-performance, solution-processed MO electronics: spray-combustion synthesis (SCS). We also report for the first time, to our knowledge, indium-gallium-zinc-oxide (IGZO) transistors having densification, nanoporosity, electron mobility, trap densities, bias stability, and film transport approaching those of sputtered films and compatible with conventional fabrication (FAB) operations.

  17. PARTITIONING OF THE REFRACTORY METALS, NICKEL AND CHROMIUM, IN COMBUSTION SYSTEMS

    Science.gov (United States)

    The partitioning of nickel (Ni) and Chromium (Cr) in combustion systems was investigated theoretically and experimentally. In comparison to other volatile and semi-volatile metals, both Ni and Cr are usually considered to be refractory (non-volatile). Theoretical predictions ba...

  18. Ab initio quantum chemistry for combustion

    International Nuclear Information System (INIS)

    Page, M.; Lengsfield, B.H.

    1991-01-01

    Advances in theoretical and computational methods, coupled with the rapid development of powerful and inexpensive computers, fuel the current rapid development in computational quantum chemistry (QC). Nowhere is this more evident than in the areas of QC most relevant to combustion: the description of bond breaking and rate phenomena. although the development of faster computers with larger memories has had a major impact on the scope of problems that can be addressed with QC, the development of new theoretical techniques and capabilities is responsible for adding new dimensions in QC and has paved the way for the unification of QC electronic structure calculations with statistical and dynamical models of chemical reactions. These advances will be stressed in this chapter. This paper describes past accomplishments selectively to set the stage for discussion of ideas or techniques that we believe will have significant impact on combustion research. Thus, the focus of the chapter is as much on the future as it is on the past

  19. Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

    KAUST Repository

    An, Yanzhao

    2017-09-23

    In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

  20. Numerical simulation of combustion and soot under partially premixed combustion of low-octane gasoline

    KAUST Repository

    An, Yanzhao; Jaasim, Mohammed; Vallinayagam, R.; Vedharaj, S.; Im, Hong G.; Johansson, Bengt.

    2017-01-01

    In-cylinder combustion visualization and engine-out soot particle emissions were investigated in an optical diesel engine fueled with low octane gasoline. Single injection strategy with an early injection timing (−30 CAD aTDC) was employed to achieve partially premixed combustion (PPC) condition. A high-speed color camera was used to record the combustion images for 150 cycles. The regulated emission of carbon dioxide, carbon monoxide, nitrogen oxides and soot mass concentration were measured experimentally. Full cycle engine simulations were performed using CONVERGE™ and the simulation results matched with the experimental results. The in-cylinder soot particle evolution was performed by coupling a reduced toluene reference fuel mechanism including the PAHs formation/oxidation reactions with particulate size mimic model. The results showed that PPC presents typical stratified combustion characteristics, which is significantly different from the conventional diesel spray-driven combustion. The in-cylinder temperature and equivalence ratio overlaid with soot-NO formation regime revealed that PPC operating condition under study mostly avoided the main sooting conditions throughout the entire combustion. The evaluation of temperature distribution showed formaldehyde could be regarded as an indicator for low temperature reactions, while hydroxyl group represents the high temperature reactions. Soot evolution happened during the combustion process, hydroxyl radicals promoted the soot oxidation.

  1. Fundamental Study of Single Biomass Particle Combustion

    DEFF Research Database (Denmark)

    Momenikouchaksaraei, Maryam

    This thesis is a comprehensive study of single biomass particle combustion. The effect of particle shape and size and operating conditions on biomass conversion characteristics were investigated experimentally and theoretically. The experimental samples were divided in two groups: particles...... well-defined conditions, and the complete combustion processes were recorded as video sequences by a CCD camera installed in the set-up. One of the project objectives is to simulate conditions reasonably close to the conditions in a power plant boiler, i.e., reasonably high temperatures (up to 1600°C...

  2. Development of a Premixed Combustion Capability for Scramjet Combustion Experiments

    Science.gov (United States)

    Rockwell, Robert D.; Goyne, Christopher P.; Rice, Brian E.; Chelliah, Harsha; McDaniel, James C.; Edwards, Jack R.; Cantu, Luca M. L.; Gallo, Emanuela C. A.; Cutler, Andrew D.; Danehy, Paul M.

    2015-01-01

    Hypersonic air-breathing engines rely on scramjet combustion processes, which involve high speed, compressible, and highly turbulent flows. The combustion environment and the turbulent flames at the heart of these engines are difficult to simulate and study in the laboratory under well controlled conditions. Typically, wind-tunnel testing is performed that more closely approximates engine testing rather than a careful investigation of the underlying physics that drives the combustion process. The experiments described in this paper, along with companion data sets being developed separately, aim to isolate the chemical kinetic effects from the fuel-air mixing process in a dual-mode scramjet combustion environment. A unique fuel injection approach is taken that produces a nearly uniform fuel-air mixture at the entrance to the combustor. This approach relies on the precombustion shock train upstream of the dual-mode scramjet combustor. A stable ethylene flame anchored on a cavity flameholder with a uniformly mixed combustor inflow has been achieved in these experiments allowing numerous companion studies involving coherent anti-Stokes Raman scattering (CARS), particle image velocimetry (PIV), and planar laser induced fluorescence (PLIF) to be performed.

  3. Experimental investigation on combustion performance of cavity-strut injection of supercritical kerosene in supersonic model combustor

    Science.gov (United States)

    Sun, Ming-bo; Zhong, Zhan; Liang, Jian-han; Wang, Hong-bo

    2016-10-01

    Supersonic combustion with cavity-strut injection of supercritical kerosene in a model scramjet engine was experimentally investigated in Mach 2.92 facility with the stagnation temperatures of approximately 1430 K. Static pressure distribution in the axial direction was determined using pressure transducers installed along the centerline of the model combustor top walls. High speed imaging camera was used to capture flame luminosity and combustion region distribution. Multi-cavities were used to and stabilize the combustion in the supersonic combustor. Intrusive injection by thin struts was used to enhance the fuel-air mixing. Supercritical kerosene at temperatures of approximately 780 K and various pressures was prepared using a heat exchanger driven by the hot gas from a pre-burner and injected at equivalence ratios of approximately 1.0. In the experiments, combustor performances with different strut injection schemes were investigated and compared to direct wall injection scheme based on the measured static pressure distributions, the specific thrust increments and the images obtained by high-speed imaging camera. The experimental results showed that the injection by thin struts could obtain an enhanced mixing in the field but could not acquire a steady flame when mixing field cannot well match cavity separation region. There is no significant difference on performance between different schemes since the unsteady intermittent and oscillating flame leads to no actual combustion efficiency improvement.

  4. Combustion characteristics of SMX and SMX based propellants

    Science.gov (United States)

    Reese, David A.

    This work investigates the combustion of the new solid nitrate ester 2,3-hydroxymethyl-2,3-dinitro-1,4-butanediol tetranitrate (SMX, C6H 8N6O16). SMX was synthesized for the first time in 2008. It has a melting point of 85 °C and oxygen balance of 0% to CO 2, allowing it to be used as an energetic additive or oxidizer in solid propellants. In addition to its neat combustion characteristics, this work also explores the use of SMX as a potential replacement for nitroglycerin (NG) in double base gun propellants and as a replacement for ammonium perchlorate in composite rocket propellants. The physical properties, sensitivity characteristics, and combustion behaviors of neat SMX were investigated. Its combustion is stable at pressures of up to at least 27.5 MPa (n = 0.81). The observed flame structure is nearly identical to that of other double base propellant ingredients, with a primary flame attached at the surface, a thick isothermal dark zone, and a luminous secondary flame wherein final recombination reactions occur. As a result, the burning rate and primary flame structure can be modeled using existing one-dimensional steady state techniques. A zero gas-phase activation energy approximation results in a good fit between modeled and observed behavior. Additionally, SMX was considered as a replacement for nitroglycerin in a double base propellant. Thermochemical calculations indicate improved performance when compared with the common double base propellant JA2 at SMX loadings above 40 wt-%. Also, since SMX is a room temperature solid, migration may be avoided. Like other nitrate esters, SMX is susceptible to decomposition over long-term storage due to the presence of excess acid in the crystals; the addition of stabilizers (e.g., derivatives of urea) during synthesis should be sufficient to prevent this. the addition of Both unplasticized and plasticized propellants were formulated. Thermal analysis of unplasticized propellant showed a distinct melt

  5. Spark Ignition Engine Combustion, Performance and Emission Products from Hydrous Ethanol and Its Blends with Gasoline

    Directory of Open Access Journals (Sweden)

    Musaab O. El-Faroug

    2016-11-01

    Full Text Available This paper reviews the serviceability of hydrous ethanol as a clean, cheap and green renewable substitute fuel for spark ignition engines and discusses the comparative chemical and physical properties of hydrous ethanol and gasoline fuels. The significant differences in the properties of hydrous ethanol and gasoline fuels are sufficient to create a significant change during the combustion phase of engine operation and consequently affect the performance of spark-ignition (SI engines. The stability of ethanol-gasoline-water blends is also discussed. Furthermore, the effects of hydrous ethanol, and its blends with gasoline fuel on SI engine combustion characteristics, cycle-to-cycle variations, engine performance parameters, and emission characteristics have been highlighted. Higher water solubility in ethanol‑gasoline blends may be obviously useful and suitable; nevertheless, the continuous ability of water to remain soluble in the blend is significantly affected by temperature. Nearly all published engine experimental results showed a significant improvement in combustion characteristics and enhanced engine performance for the use of hydrous ethanol as fuel. Moreover, carbon monoxide and oxides of nitrogen emissions were also significantly decreased. It is also worth pointing out that unburned hydrocarbon and carbon dioxide emissions were also reduced for the use of hydrous ethanol. However, unregulated emissions such as acetaldehyde and formaldehyde were significantly increased.

  6. Development of an empirical correlation for combustion durations in spark ignition engines

    International Nuclear Information System (INIS)

    Bayraktar, Hakan; Durgun, Orhan

    2004-01-01

    Development of an empirical correlation for combustion duration is presented. For this purpose, the effects of variations in compression ratio engine speed, fuel/air equivalence ratio and spark advance on combustion duration have been determined by means of a quasi-dimensional SI engine cycle model previously developed by the authors. Burn durations at several engine operating conditions were calculated from the turbulent combustion model. Variations of combustion duration with each operating parameter obtained from the theoretical results were expressed by second degree polynomial functions. By using these functions, a general empirical correlation for the burn duration has been developed. In this correlation, the effects of engine operating parameters on combustion duration were taken into account. Combustion durations predicted by means of this correlation are in good agreement with those obtained from experimental studies and a detailed combustion model

  7. Laboratory evaluation of the particle size effect on the performance of an elastomeric half-mask respirator against ultrafine combustion particles.

    Science.gov (United States)

    He, Xinjian; Grinshpun, Sergey A; Reponen, Tiina; Yermakov, Michael; McKay, Roy; Haruta, Hiroki; Kimura, Kazushi

    2013-08-01

    This study quantified the particle size effect on the performance of elastomeric half-mask respirators, which are widely used by firefighters and first responders exposed to combustion aerosols. One type of elastomeric half-mask respirator equipped with two P-100 filters was donned on a breathing manikin while challenged with three combustion aerosols (originated by burning wood, paper, and plastic). Testing was conducted with respirators that were fully sealed, partially sealed (nose area only), or unsealed to the face of a breathing manikin to simulate different faceseal leakages. Three cyclic flows with mean inspiratory flow (MIF) rates of 30, 85, and 135 L/min were tested for each combination of sealing condition and combustion material. Additional testing was performed with plastic combustion particles at other cyclic and constant flows. Particle penetration was determined by measuring particle number concentrations inside and outside the respirator with size ranges from 20 to 200 nm. Breathing flow rate, particle size, and combustion material all had significant effects on the performance of the respirator. For the partially sealed and unsealed respirators, the penetration through the faceseal leakage reached maximum at particle sizes >100 nm when challenged with plastic aerosol, whereas no clear peaks were observed for wood and paper aerosols. The particles aerosolized by burning plastic penetrated more readily into the unsealed half-mask than those aerosolized by the combustion of wood and paper. The difference may be attributed to the fact that plastic combustion particles differ from wood and paper particles by physical characteristics such as charge, shape, and density. For the partially sealed respirator, the highest penetration values were obtained at MIF = 85 L/min. The unsealed respirator had approximately 10-fold greater penetration than the one partially sealed around the bridge of the nose, which indicates that the nose area was the primary leak

  8. On the high-temperature combustion of n-butanol: Shock tube data and an improved kinetic model

    KAUST Repository

    Vasu, Subith S.; Sarathy, Mani

    2013-01-01

    The combustion of n-butanol has received significant interest in recent years, because of its potential use in transportation applications. Researchers have extensively studied its combustion chemistry, using both experimental and theoretical

  9. Fast Reacting Nano Composite Energetic Materials: Synthesis and Combustion Characterization

    Science.gov (United States)

    2015-08-24

    nanoenergetic composites finding extensive use in ordnance and industrial applications, because of its high heat of combustion (~32 kJ/g) (S. H. Fischer ...2011. Farley, Cory. "Reactions of Aluminum with Halogen Containing Oxides." Dissertation. Lubbock, TX, May 2013. Gesner, Jeff , Michelle Pantoya, and...characteristics of novel hybrid nanoenergetic formulations." Combustion and Flame 158 (2011): 964- 978. S. H. Fischer , M. C. Grubelich. "Theoretical

  10. Researches concerning the use of mixed Hydrogen in the combustion of dense biomass

    International Nuclear Information System (INIS)

    Negreanu, Gabriel-Paul; Mihaescu, Lucian; Pisa, Ionel; Berbece, Viorel; Lazaroiu, Gheorghe

    2014-01-01

    The paper deals with theoretical basis and experimental tests of mixed hydrogen diffusion in the dense system of biomass. Research regarding hydrogen diffusion in the porous system of biomass is part of wider research focusing on using hydrogen as an active medium for solid biomass combustion. In parallel with hydrogen diffusion in solid biomass, tests regarding biomass combustion previously subjected to a hydrogen flux will be carried out. Keywords: biomass, hydrogen diffusion, combustion, experimental tests

  11. Performance, Emissions and Combustion Characteristics of a Single Cylinder Diesel Engine Fuelled with Blends of Jatropha Methyl Ester and Diesel

    Directory of Open Access Journals (Sweden)

    Debasish Padhee

    2014-05-01

    Full Text Available In order to meet the energy requirements, there has been growing interest in alternative fuels like biodiesels, ethyl alcohol, biogas, hydrogen and producer gas to provide a suitable diesel substitute for internal combustion engines. An experimental investigation was performed to study the performance, emissions and combustion characteristics of diesel engine fuelled with blends of Jatropha methyl ester and diesel. In the present work three different fuel blends of Jatropha methyl ester (B10, B20, B40 and B100 were used. The increments in load on the engine increase the brake thermal efficiency, exhaust gas temperature and lowered the brake specific fuel consumption. The biodiesel blends produce lower carbon monoxide & unburned hydrocarbon emission and higher carbon dioxide & oxides of nitrogen than neat diesel fuel. From the results it was observed that the ignition delays decreased with increase in concentration of biodiesel in biodiesel blends with diesel. The combustion characteristics of single-fuel for biodiesel and diesel have similar combustion pressure and HRR patterns at different engine loads but it was observed that the peak cylinder pressure and heat release rate were lower for biodiesel blends compared to those of diesel fuel combustion.

  12. Investigation on the lean combustion performance of a hydrogen-enriched n-butanol engine

    International Nuclear Information System (INIS)

    Zhang, Bo; Ji, Changwei; Wang, Shuofeng

    2017-01-01

    Highlights: • H_2 addition avails improving thermal efficiency of n-butanol engines. • Lean burn limit of n-butanol engine is extended by H_2 addition. • H_2 addition shortens the n-butanol engine combustion duration. • HC and CO from the n-butanol engine are decreased by H_2 addition. - Abstract: n-Butanol is a feasible fuel candidate for spark-ignition engines. The current paper carried out an experiment to explore effects of hydrogen addition on further improving the performance of a n-butanol engine under the part load and lean conditions. Within the test, the engine intake pressure and speed were respectively kept at 61.5 kPa and 1400 rpm. The volumetric fractions of hydrogen in the total intake gas (hydrogen + air) were constrained at 0 and 3%, respectively. Under a certain hydrogen blending level, the global excess air ratio of in-cylinder charge which was changed from the stoichiometric to near the lean burn limit was adjusted by varying the n-butanol injection duration. The experimental results confirmed that the brake thermal efficiency was heightened and the lean burn limit was extended after the hydrogen addition. Besides, compared with the pure n-butanol combustion, the hydrogen enrichment enables the engine to gain dropped ignition delay and rapid combustion duration. Moreover, CO and HC from the pure n-butanol engine were reduced by the hydrogen addition. NOx were generally reduced when the excess air ratio was raised. This suggested that NOx from the hydrogen-enriched butanol engine could also be controlled by lean combustion.

  13. Theoretical energy release of thermites, intermetallics, and combustible metals

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, S.H.; Grubelich, M.C.

    1998-06-01

    Thermite (metal oxide) mixtures, intermetallic reactants, and metal fuels have long been used in pyrotechnic applications. Advantages of these systems typically include high energy density, impact insensitivity, high combustion temperature, and a wide range of gas production. They generally exhibit high temperature stability, and possess insensitive ignition properties. In this paper, the authors review the applications, benefits, and characteristics of thermite mixtures, intermetallic reactants, and metal fuels. Calculated values for reactant density, heat of reaction (per unit mass and per unit volume), and reaction temperature (without and with consideration of phase changes and the variation of specific heat values) are tabulated. These data are ranked in several ways, according to density, heat of reaction, reaction temperature, and gas production.

  14. Effect of hydrogen-diesel combustion on the performance and combustion parameters of a dual fuelled diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Bose, P.K.; Banerjee, Rahul; Deb, Madhujit [Mechanical Engineering Department, National Institute of Technology, Agartala, Tripura-799055 (India)

    2013-07-01

    Petroleum crude is expected to remain main source of transport fuels at least for the next 20 to 30 years. The petroleum crude reserves however, are declining and consumption of transport fuels particularly in the developing countries is increasing at high rates. Severe shortage of liquid fuels derived from petroleum may be faced in the second half of this century. In this paper, experiments are performed in a fur stroke, single cylinder, compression ignition diesel engine with dual fuel mode. Diesel and hydrogen are used as pilot liquid and primary gaseous fuel, respectively. The objective of this study is to find out the effects on combustion and performance parameters observed at diesel hydrogen fuel mixture for all the different loadings (2kg,4kg,6kg,8kg,10kg and 12kg) in the engine.

  15. The Effects of Sooting and Radiation on Droplet Combustion

    Science.gov (United States)

    Lee, Kyeong-Ook; Manzello, Samuel L.; Choi, Mun Young

    1997-01-01

    The burning of liquid hydrocarbon fuels accounts for a significant portion of global energy production. With predicted future increases in demand and limited reserves of hydrocarbon fuel, it is important to maximize the efficiency of all processes that involve conversion of fuel. With the exception of unwanted fires, most applications involve introduction of liquid fuels into an oxidizing environment in the form of sprays which are comprised of groups of individual droplets. Therefore, tremendous benefits can result from a better understanding of spray combustion processes. Yet, theoretical developments and experimental measurements of spray combustion remains a daunting task due to the complex coupling of a turbulent, two-phase flow with phase change and chemical reactions. However, it is recognized that individual droplet behavior (including ignition, evaporation and combustion) is a necessary component for laying the foundation for a better understanding of spray processes. Droplet combustion is also an ideal problem for gaining a better understanding of non-premixed flames. Under the idealized situation producing spherically-symmetric flames (produced under conditions of reduced natural and forced convection), it represents the simplest geometry in which to formulate and solve the governing equations of mass, species and heat transfer for a chemically reacting two phase flow with phase change. The importance of this topic has promoted extensive theoretical investigations for more than 40 years.

  16. Wood combustion and NOx formation control

    International Nuclear Information System (INIS)

    Tewksbury, C.

    1991-01-01

    The control of wood combustion on stoker fed grates for optimum efficiency and the limiting of NO x (oxides of nitrogen) formation are not necessarily contradictory. This paper presents a matrix of air/fuel ratio control options, then discusses simple on-line monitoring techniques and the importance of operator training and alertness. The significance of uniform fuel feed and air distribution is emphasized. The relationships between combustion control and NO x formation are outlined both in theory and as tested. The experience of the McNeil Generating Station (the largest wood-fired, single boiler, stoker grate, utility electric generating station in the world) is used to demonstrate the theoretical principles. It has been observed that NO x emissions firing 100% whole tree chips with moisture contents as low as 40% by weight can be as low as 0.13 lb/MMBtu (MMBtu = 10 6 Btu) while still achieving a boiler efficiency in the range of 68% to 73% (in the high end of the design range) without the use of post-combustion treatment or flue gas recirculation (FGR). Problems of combustion and emissions control at steaming rates other than normal full-load are also examined. 2 figs., 4 tabs

  17. Influence of injector technology on injection and combustion development - Part 2: Combustion analysis

    Energy Technology Data Exchange (ETDEWEB)

    Payri, R.; Salvador, F.J.; Gimeno, J.; Morena, J. de la [CMT-Motores Termicos, Universidad Politecnica de Valencia, Camino de Vera s/n, E-46022 (Spain)

    2011-04-15

    The influence of injection technology on the fuel-air mixing process and the combustion development are analyzed by means of visualization techniques. For this purpose, two injectors (one solenoid and one piezoelectric) are characterized using an optical accessible two stroke engine. Visualization of liquid penetration has allowed the measurement of the stabilized liquid length, which is related with the efficiency of fuel-air mixing process. A theoretical derivation is used in order to relate this liquid length with chamber conditions, as well as to make a temporal analysis of these phenomena. After this, natural flame emission and chemiluminescence techniques are carried out. These results indicate that the piezoelectric system has a more efficient fuel-air mixing and combustion, reducing the characteristic times as well as soot formation. Finally, a correlation for the ignition delay of the two systems is obtained. (author)

  18. Analysis of the performance, emission and combustion characteristics of a turbocharged diesel engine fuelled with Jatropha curcas biodiesel-diesel blends using kernel-based extreme learning machine.

    Science.gov (United States)

    Silitonga, Arridina Susan; Hassan, Masjuki Haji; Ong, Hwai Chyuan; Kusumo, Fitranto

    2017-11-01

    The purpose of this study is to investigate the performance, emission and combustion characteristics of a four-cylinder common-rail turbocharged diesel engine fuelled with Jatropha curcas biodiesel-diesel blends. A kernel-based extreme learning machine (KELM) model is developed in this study using MATLAB software in order to predict the performance, combustion and emission characteristics of the engine. To acquire the data for training and testing the KELM model, the engine speed was selected as the input parameter, whereas the performance, exhaust emissions and combustion characteristics were chosen as the output parameters of the KELM model. The performance, emissions and combustion characteristics predicted by the KELM model were validated by comparing the predicted data with the experimental data. The results show that the coefficient of determination of the parameters is within a range of 0.9805-0.9991 for both the KELM model and the experimental data. The mean absolute percentage error is within a range of 0.1259-2.3838. This study shows that KELM modelling is a useful technique in biodiesel production since it facilitates scientists and researchers to predict the performance, exhaust emissions and combustion characteristics of internal combustion engines with high accuracy.

  19. A novel split cycle internal combustion engine with integral waste heat recovery

    International Nuclear Information System (INIS)

    Dong, Guangyu; Morgan, Robert; Heikal, Morgan

    2015-01-01

    Highlights: • A novel engine thermodynamic cycle is proposed. • Theoretical analysis is applied to identify the key parameters of the thermodynamic cycle. • The key stages of the split cycle are analysed via one-dimensional modelling work. • The effecting mechanism of the split cycle efficiency is analysed. - Abstract: To achieve a step improvement in engine efficiency, a novel split cycle engine concept is proposed. The engine has separate compression and combustion cylinders and waste heat is recovered between the two. Quasi-isothermal compression of the charge air is realised in the compression cylinder while isobaric combustion of the air/fuel mixture is achieved in the combustion cylinder. Exhaust heat recovery between the compression and combustion chamber enables highly efficient recovery of waste heat within the cycle. Based on cycle analysis and a one-dimensional engine model, the fundamentals and the performance of the split thermodynamic cycle is estimated. Compared to conventional engines, the compression work can be significantly reduced through the injection of a controlled quantity of water in the compression cylinder, lowering the gas temperature during compression. Thermal energy can then be effectively recovered from the engine exhaust in a recuperator between the cooled compressor cylinder discharge air and the exhaust gas. The resulting hot high pressure air is then injected into a combustor cylinder and mixed with fuel, where near isobaric combustion leads to a low combustion temperature and reduced heat transferred from the cylinder wall. Detailed cycle simulation indicates a 32% efficiency improvement can be expected compared to the conventional diesel engines.

  20. Factors affecting the amounts of emissions arising from fluidized bed combustion of solid fuels

    International Nuclear Information System (INIS)

    Horbaj, P.

    1996-01-01

    The factors affecting the amounts of nitrogen oxides (NO x ) and sulfur oxides (SO x , i.e. SO 2 + SO 3 ) formed during fluidized bed combustion of fossil fuels are analyzed using both theoretical concepts and experimental data. The factors treated include temperature, excess air, fuel parameters, pressure, degree of combustion gas recycling, combustion distribution along the combustion chamber height, and sulfur trapping processes for NO x , and the Ca/S ratio, fluidized layer height and fluidization rate, granulometry and absorbent type, fluidized layer temperature, and pressure during combustion for SO x . It is concluded that fluidized bed boilers are promising power generating facilities, mitigating the environmental burden arising from fossil fuel combustion. (P.A.). 12 figs., 9 refs

  1. Combustion of environmentally altered molybdenum trioxide nanocomposites

    Energy Technology Data Exchange (ETDEWEB)

    Moore, Kevin; Pantoya, Michelle L. [Mechanical Engineering Department, Texas Tech University, 2500 Broadway, Lubbock, TX 79409 (United States)

    2006-06-15

    Nanocomposite thermite mixtures are currently under development for many primer applications due to their high energy densities, high ignition sensitivity, and low release of toxins into the environment. However, variability and inconsistencies in combustion performance have not been sufficiently investigated. Environmental interactions with the reactants are thought to be a contributing factor to these variabilities. Combustion velocity experiments were conducted on aluminum (Al) and molybdenum trioxide (MoO{sub 3}) mixtures to investigate the role of environmental interactions such as light exposure and humidity. While the Al particles were maintained in an ambient, constant environment, the MoO{sub 3} particles were exposed to UV or fluorescent light, and highly humid environments. Results show that UV and fluorescent lighting over a period of days does not significantly contribute to performance deterioration. However, a humid environment severely decreases combustion performance if the oxidizer particles are not heat-treated. Heat treatment of the MoO{sub 3} greatly increases the material's ability to resist water absorption, yielding more repeatable combustion performance. This work further quantifies the role of the environment in the decrease of combustion performance of nanocomposites over time. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  2. Effect of using hydrogen in the power and performance of an internal combustion engine

    Directory of Open Access Journals (Sweden)

    Edwin Tamayo

    2016-12-01

    Full Text Available This study analyzed the real working parameters of an Otto cycle internal combustion engine, using as fuel hydrogen plus gasoline. Two stoichiometric equations were determined. In the first equation, the reagents are octane and air, in the second equation was added the quantity of 3.86 H2 moles obtained from a hydrogen cell. Two sets of equations, for consumption and power, were determined from the chemical equations, working at the conditions of Quito: altitude 2850 msnm, 72.794 kPa of atmospheric pressure and 300 K of temperature. A single cylinder engine powered with hydrogen plus gasoline was used for getting real data of engine power, using mixtures of air-gasoline and hydrogen; the theoretical power without H2 was 3.91 HP and with H2 5.41 HP, it increased 27.1%, the real power is 3.78 HP without H2 and 4.66 HP with H2, it increased 16.7%. Theoretical fuel consumption is 401.61 g/kWh and addition of H2 is less to 373.52 g/kWh, the actual consumption that indicates the manufacturer is 395 g/kWh.

  3. Ameliorer les performances environnementales des centrales a charbon pulverise via la co-combustion de combustible derive de dechets

    Science.gov (United States)

    Vekemans, Odile Geraldine

    interactions between ReEF(TM) components take place during its devolatilization. During the second step of this study, performances of the co-firing of coal and sorbent are compared to that of co-combustion of coal and ReEF(TM) without sorbent. This is carried out in a reactor specially build for this study, capable of reproducing the contact mode between gas and particles, the concentrations, the temperature gradient and the pressure typical of pulverized coal boiler. SO2 emissions reduction around 20% are observed in presence of CaCO3 and of Ca(OH)2 compared to the coal baseline, reduction that generally increased with the increase of sorbent molar ratio compared to sulfur (also called stoic). As for the co-combustion of 20%th of ReEF(TM) and coal, a SO2 emission reduction around 20% is also measured, with no clear effect of ReEF(TM) composition (fiber to plastic ratio). On the other hand, the HCl level that is negligible during coal combustion with and without sorbent, reaches around 20ppm in presence of ReEF(TM), and increases proportionally with the ReEF(TM) plastic content. The first step of this work consists in the study of the co-combustion of coal and ReEF(TM) containing limestone (CaCO3), a mix of sodium bicarbonate (NaHCO3) and limestone, as well as a mix of trona (Na2CO3.NaHCO3.H2O) and limestone. The amount of sorbent in the ReEF(TM) as well as the feeding parameters are adjusted to reach a 20%th feeding of ReEF(TM) compared to coal, to inject sorbents at a stoic of 1, 2 and 2.5 and to obtain Na/Ca molar ratios of 0, 0.1 with trona and NaHCO3, and 0.5 with NaHCO 3 only. Globally, as in the case of sorbent alone, the increase of the total stoic of the feed leads to increased SO2 capture. For a given stoic, to combine waste and limestone in the ReEF(TM), compared to using limestone alone, allows to reach higher levels of SO2 emissions reduction. The combination of sodium-based and calcium-based sorbent even leads to record SO2 emissions reduction of more than 50

  4. Free Energy and Internal Combustion Engine Cycles

    OpenAIRE

    Harris, William D.

    2012-01-01

    The performance of one type (Carnot) of Internal Combustion Engine (ICE) cycle is analyzed within the framework of thermodynamic free energies. ICE performance is different from that of an External Combustion Engine (ECE) which is dictated by Carnot's rule.

  5. Methane combustion over lanthanum-based perovskite mixed oxides

    Energy Technology Data Exchange (ETDEWEB)

    Arandiyan, Hamidreza [New South Wales Univ., Sydney (Australia). School of Chemical Engineering

    2015-11-01

    This book presents current research into the catalytic combustion of methane using perovskite-type oxides (ABO{sub 3}). Catalytic combustion has been developed as a method of promoting efficient combustion with minimum pollutant formation as compared to conventional catalytic combustion. Recent theoretical and experimental studies have recommended that noble metals supported on (ABO{sub 3}) with well-ordered porous networks show promising redox properties. Three-dimensionally ordered macroporous (3DOM) materials with interpenetrated and regular mesoporous systems have recently triggered enormous research activity due to their high surface areas, large pore volumes, uniform pore sizes, low cost, environmental benignity, and good chemical stability. These are all highly relevant in terms of the utilization of natural gas in light of recent catalytic innovations and technological advances. The book is of interest to all researchers active in utilization of natural gas with novel catalysts. The research covered comes from the most important industries and research centers in the field. The book serves not only as a text for researcher into catalytic combustion of methane, 3DOM perovskite mixed oxide, but also explores the field of green technologies by experts in academia and industry. This book will appeal to those interested in research on the environmental impact of combustion, materials and catalysis.

  6. Quantitative Measurement of Oxygen in Microgravity Combustion

    Science.gov (United States)

    Silver, Joel A.

    1997-01-01

    A low-gravity environment, in space or in ground-based facilities such as drop towers, provides a unique setting for studying combustion mechanisms. Understanding the physical phenomena controlling the ignition and spread of flames in microgravity has importance for space safety as well as for better characterization of dynamical and chemical combustion processes which are normally masked by buoyancy and other gravity-related effects. Due to restrictions associated with performing measurements in reduced gravity, diagnostic methods which have been applied to microgravity combustion studies have generally been limited to capture of flame emissions on film or video, laser Schlieren imaging and (intrusive) temperature measurements using thermocouples. Given the development of detailed theoretical models, more sophisticated diagnostic methods are needed to provide the kind of quantitative data necessary to characterize the properties of microgravity combustion processes as well as provide accurate feedback to improve the predictive capabilities of the models. When the demands of space flight are considered, the need for improved diagnostic systems which are rugged, compact, reliable, and operate at low power becomes apparent. The objective of this research is twofold. First, we want to develop a better understanding of the relative roles of diffusion and reaction of oxygen in microgravity combustion. As the primary oxidizer species, oxygen plays a major role in controlling the observed properties of flames, including flame front speed (in solid or liquid flames), extinguishment characteristics, flame size and flame temperature. The second objective is to develop better diagnostics based on diode laser absorption which can be of real value in both microgravity combustion research and as a sensor on-board Spacelab as either an air quality monitor or as part of a fire detection system. In our prior microgravity work, an eight line-of-sight fiber optic system measured

  7. Influence of process parameters on coal combustion performance. Review, experiments and engineering modeling

    Energy Technology Data Exchange (ETDEWEB)

    Lans, R.P. van der

    1997-04-01

    The objective of this study is to improve the understanding of nitrogen oxide formation and carbon burnout during the combustion of pulverized coal, and to contribute to addressing the potential of chemical engineering models for the prediction of furnace temperatures, NO emissions and the amount of carbon in ash. To this purpose, the effect of coal quality on NO and burnout has been investigated experimentally, a radiation heat balance has been developed based on a simple chemical engineering methodology, and a mixing study has been conducted in order to describe the near burner macro mixing in terms of a reactor configuration. The influence of coal type and process conditions on NO formation and carbon burnout has been investigated experimentally in a 400 MW{sub e} corner fired boiler with over fire air, a 350 MW{sub e} opposed fired boiler, and in a 160 kW{sub t} pilot scale test rig. Three different coals were fired in each of the furnaces as part of the activities in group 3 of the European Union JOULE 2 Extension project `Atmospheric Pressure Combustion of Pulverized Coal and Coal Based Blends for Power Generation`. On the pilot scale test both single stage and air staged tests were performed. A simple, one-dimensional combustion and radiation heat transfer model has been developed for the furnace of full scale boilers. The model has been applied to the two boilers mentioned above, and is validated against measured temperatures and carbon in ash concentrations. A mixing study has been performed in order to initiate an investigation of the potential of chemical engineering models to predict NO from pulverized fuel burners. (EG) 11 refs.

  8. COMBUSTION SIMULATION IN A SPARK IGNITION ENGINE CYLINDER: EFFECTS OF AIR-FUEL RATIO ON THE COMBUSTION DURATION

    Directory of Open Access Journals (Sweden)

    Nureddin Dinler

    2010-01-01

    Full Text Available Combustion is an important subject of internal combustion engine studies. To reduce the air pollution from internal combustion engines and to increase the engine performance, it is required to increase combustion efficiency. In this study, effects of air/fuel ratio were investigated numerically. An axisymmetrical internal combustion engine was modeled in order to simulate in-cylinder engine flow and combustion. Two dimensional transient continuity, momentum, turbulence, energy, and combustion equations were solved. The k-e turbulence model was employed. The fuel mass fraction transport equation was used for modeling of the combustion. For this purpose a computational fluid dynamics code was developed by using the finite volume method with FORTRAN programming code. The moving mesh was utilized to simulate the piston motion. The developed code simulates four strokes of engine continuously. In the case of laminar flow combustion, Arrhenius type combustion equations were employed. In the case of turbulent flow combustion, eddy break-up model was employed. Results were given for rich, stoichiometric, and lean mixtures in contour graphs. Contour graphs showed that lean mixture (l = 1.1 has longer combustion duration.

  9. Combustion synthesis of graphene and ultracapacitor performance

    Indian Academy of Sciences (India)

    Graphene sheets are synthesized by a simple method starting from graphitic oxide as a precursor. Reaction of graphitic oxide at 250 °C with a combustion mixture of urea and ammonium nitrate results in the formation of thin graphene sheets. Graphene formation is characterized by XRD, TGA, XPS and TEM. Graphene ...

  10. Modeling and Simulation on NOx and N2O Formation in Co-combustion of Low-rank Coal and Palm Kernel Shell

    Directory of Open Access Journals (Sweden)

    Mahidin Mahidin

    2012-12-01

    Full Text Available NOx and N2O emissions from coal combustion are claimed as the major contributors for the acid rain, photochemical smog, green house and ozone depletion problems. Based on the facts, study on those emissions formation is interest topic in the combustion area. In this paper, theoretical study by modeling and simulation on NOx and N2O formation in co-combustion of low-rank coal and palm kernel shell has been done. Combustion model was developed by using the principle of chemical-reaction equilibrium. Simulation on the model in order to evaluate the composition of the flue gas was performed by minimization the Gibbs free energy. The results showed that by introduced of biomass in coal combustion can reduce the NOx concentration in considerably level. Maximum NO level in co-combustion of low-rank coal and palm kernel shell with fuel composition 1:1 is 2,350 ppm, low enough compared to single low-rank coal combustion up to 3,150 ppm. Moreover, N2O is less than 0.25 ppm in all cases. Keywords: low-rank coal, N2O emission, NOx emission, palm kernel shell

  11. Comprehensive investigation of process characteristics for oxy-steam combustion power plants

    International Nuclear Information System (INIS)

    Jin, Bo; Zhao, Haibo; Zou, Chun; Zheng, Chuguang

    2015-01-01

    Highlights: • Oxy-steam combustion exhibits better performance than oxy-CO 2 combustion. • Cost of electricity in oxy-steam combustion is 6.62% less than oxy-CO 2 combustion. • The increase of oxygen concentration in oxidant can improve its system performance. • The decrease of excess oxygen coefficient can be helpful for its system performance. • Integration with solar technology can enhance its thermodynamic performance. - Abstract: Oxy-steam combustion, as an alternative option of oxy-fuel combustion technology, is considered as a promising CO 2 capture technology for restraining CO 2 emissions from power plants. To attain its comprehensive process characteristics, process simulation, thermodynamic assessment, and sensitivity analysis for oxy-steam combustion pulverized-coal-fired power plants are investigated whilst its corresponding CO 2 /O 2 recycled combustion (oxy-CO 2 combustion) power plant is served as the base case for comparison. Techno-economic evaluation and integration with solar parabolic trough collectors are also discussed to justify its economic feasibility and improve its thermodynamic performance further, respectively. It is found that oxy-steam combustion exhibits better performance than oxy-CO 2 combustion on both thermodynamic and economic aspects, in which the cost of electricity decreases about 6.62% whilst the net efficiency and exergy efficiency increase about 0.90 and 1.01 percentage points, respectively. The increment of oxygen concentration in oxidant (20–45 mol.%) and decrease of excess oxygen coefficient (1.01–1.09) in a certain range are favorable for improving oxy-steam combustion system performance. Moreover, its thermodynamic performance can be improved when considering solar parabolic trough collectors for heating recycled water, even though its cost of electricity increases about 2 $/(MW h)

  12. Transient flow combustion

    Science.gov (United States)

    Tacina, R. R.

    1984-01-01

    Non-steady combustion problems can result from engine sources such as accelerations, decelerations, nozzle adjustments, augmentor ignition, and air perturbations into and out of the compressor. Also non-steady combustion can be generated internally from combustion instability or self-induced oscillations. A premixed-prevaporized combustor would be particularly sensitive to flow transients because of its susceptability to flashback-autoignition and blowout. An experimental program, the Transient Flow Combustion Study is in progress to study the effects of air and fuel flow transients on a premixed-prevaporized combustor. Preliminary tests performed at an inlet air temperature of 600 K, a reference velocity of 30 m/s, and a pressure of 700 kPa. The airflow was reduced to 1/3 of its original value in a 40 ms ramp before flashback occurred. Ramping the airflow up has shown that blowout is more sensitive than flashback to flow transients. Blowout occurred with a 25 percent increase in airflow (at a constant fuel-air ratio) in a 20 ms ramp. Combustion resonance was found at some conditions and may be important in determining the effects of flow transients.

  13. In-cylinder diesel spray combustion simulations using parallel computation: A performance benchmarking study

    International Nuclear Information System (INIS)

    Pang, Kar Mun; Ng, Hoon Kiat; Gan, Suyin

    2012-01-01

    Highlights: ► A performance benchmarking exercise is conducted for diesel combustion simulations. ► The reduced chemical mechanism shows its advantages over base and skeletal models. ► High efficiency and great reduction of CPU runtime are achieved through 4-node solver. ► Increasing ISAT memory from 0.1 to 2 GB reduces the CPU runtime by almost 35%. ► Combustion and soot processes are predicted well with minimal computational cost. - Abstract: In the present study, in-cylinder diesel combustion simulation was performed with parallel processing on an Intel Xeon Quad-Core platform to allow both fluid dynamics and chemical kinetics of the surrogate diesel fuel model to be solved simultaneously on multiple processors. Here, Cartesian Z-Coordinate was selected as the most appropriate partitioning algorithm since it computationally bisects the domain such that the dynamic load associated with fuel particle tracking was evenly distributed during parallel computations. Other variables examined included number of compute nodes, chemistry sizes and in situ adaptive tabulation (ISAT) parameters. Based on the performance benchmarking test conducted, parallel configuration of 4-compute node was found to reduce the computational runtime most efficiently whereby a parallel efficiency of up to 75.4% was achieved. The simulation results also indicated that accuracy level was insensitive to the number of partitions or the partitioning algorithms. The effect of reducing the number of species on computational runtime was observed to be more significant than reducing the number of reactions. Besides, the study showed that an increase in the ISAT maximum storage of up to 2 GB reduced the computational runtime by 50%. Also, the ISAT error tolerance of 10 −3 was chosen to strike a balance between results accuracy and computational runtime. The optimised parameters in parallel processing and ISAT, as well as the use of the in-house reduced chemistry model allowed accurate

  14. Numerical Study on the Performance Characteristics of Hydrogen Fueled Port Injection Internal Combustion Engine

    OpenAIRE

    Rosli A. Bakar; Mohammed K. Mohammed; M. M. Rahman

    2009-01-01

    This study was focused on the engine performance of single cylinder hydrogen fueled port injection internal combustion engine. GT-Power was utilized to develop the model for port injection engine. One dimensional gas dynamics was represented the flow and heat transfer in the components of the engine model. The governing equations were introduced first, followed by the performance parameters and model description. Air-fuel ratio was varied from stoichiometric limit to a lean limit and the rota...

  15. LES and RANS modeling of pulverized coal combustion in swirl burner for air and oxy-combustion technologies

    International Nuclear Information System (INIS)

    Warzecha, Piotr; Boguslawski, Andrzej

    2014-01-01

    Combustion of pulverized coal in oxy-combustion technology is one of the effective ways to reduce the emission of greenhouse gases into the atmosphere. The process of transition from conventional combustion in air to the oxy-combustion technology, however, requires a thorough investigations of the phenomena occurring during the combustion process, that can be greatly supported by numerical modeling. The paper presents the results of numerical simulations of pulverized coal combustion process in swirl burner using RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) methods for turbulent flow. Numerical simulations have been performed for the oxyfuel test facility located at the Institute of Heat and Mass Transfer at RWTH Aachen University. Detailed analysis of the flow field inside the combustion chamber for cold flow and for the flow with combustion using different numerical methods for turbulent flows have been done. Comparison of the air and oxy-coal combustion process for pulverized coal shows significant differences in temperature, especially close to the burner exit. Additionally the influence of the combustion model on the results has been shown for oxy-combustion test case. - Highlights: • Oxy-coal combustion has been modeled for test facility operating at low oxygen ratio. • Coal combustion process has been modeled with simplified combustion models. • Comparison of oxy and air combustion process of pulverized coal has been done. • RANS (Reynolds-averaged Navier–Stokes equations) and LES (large Eddy simulation) results for pulverized coal combustion process have been compared

  16. Oxygen enriched combustion system performance study. Phase 2: 100 percent oxygen enriched combustion in regenerative glass melters, Final report

    Energy Technology Data Exchange (ETDEWEB)

    Tuson, G.B.; Kobayashi, H.; Campbell, M.J.

    1994-08-01

    The field test project described in this report was conducted to evaluate the energy and environmental performance of 100% oxygen enriched combustion (100% OEC) in regenerative glass melters. Additional objectives were to determine other impacts of 100% OEC on melter operation and glass quality, and to verify on a commercial scale that an on-site Pressure Swing Adsorption oxygen plant can reliably supply oxygen for glass melting with low electrical power consumption. The tests constituted Phase 2 of a cooperative project between the United States Department of Energy, and Praxair, Inc. Phase 1 of the project involved market and technical feasibility assessments of oxygen enriched combustion for a range of high temperature industrial heating applications. An assessment of oxygen supply options for these applications was also performed during Phase 1, which included performance evaluation of a pilot scale 1 ton per day PSA oxygen plant. Two regenerative container glass melters were converted to 100% OEC operation and served as host sites for Phase 2. A 75 ton per day end-fired melter at Carr-Lowrey Glass Company in Baltimore, Maryland, was temporarily converted to 100% OEC in mid- 1990. A 350 tpd cross-fired melter at Gallo Glass Company in Modesto, California was rebuilt for permanent commercial operation with 100% OEC in mid-1991. Initially, both of these melters were supplied with oxygen from liquid storage. Subsequently, in late 1992, a Pressure Swing Adsorption oxygen plant was installed at Gallo to supply oxygen for 100% OEC glass melting. The particular PSA plant design used at Gallo achieves maximum efficiency by cycling the adsorbent beds between pressurized and evacuated states, and is therefore referred to as a Vacuum/Pressure Swing Adsorption (VPSA) plant.

  17. Combustion kinetics and reaction pathways

    Energy Technology Data Exchange (ETDEWEB)

    Klemm, R.B.; Sutherland, J.W. [Brookhaven National Laboratory, Upton, NY (United States)

    1993-12-01

    This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

  18. Annual Report: Advanced Combustion (30 September 2012)

    Energy Technology Data Exchange (ETDEWEB)

    Hawk, Jeffrey [NETL; Richards, George

    2012-09-30

    The Advanced Combustion Project addresses fundamental issues of fire-side and steam-side corrosion and materials performance in oxy-fuel combustion environments and provides an integrated approach into understanding the environmental and mechanical behavior such that environmental degradation can be ameliorated and long-term microstructural stability, and thus, mechanical performance can lead to longer lasting components and extended power plant life. The technical tasks of this effort are Oxy-combustion Environment Characterization, Alloy Modeling and Life Prediction, and Alloy Manufacturing and Process Development.

  19. Multi-stage combustion using nitrogen-enriched air

    Science.gov (United States)

    Fischer, Larry E.; Anderson, Brian L.

    2004-09-14

    Multi-stage combustion technology combined with nitrogen-enriched air technology for controlling the combustion temperature and products to extend the maintenance and lifetime cycles of materials in contact with combustion products and to reduce pollutants while maintaining relatively high combustion and thermal cycle efficiencies. The first stage of combustion operates fuel rich where most of the heat of combustion is released by burning it with nitrogen-enriched air. Part of the energy in the combustion gases is used to perform work or to provide heat. The cooled combustion gases are reheated by additional stages of combustion until the last stage is at or near stoichiometric conditions. Additional energy is extracted from each stage to result in relatively high thermal cycle efficiency. The air is enriched with nitrogen using air separation technologies such as diffusion, permeable membrane, absorption, and cryogenics. The combustion method is applicable to many types of combustion equipment, including: boilers, burners, turbines, internal combustion engines, and many types of fuel including hydrogen and carbon-based fuels including methane and coal.

  20. Methane combustion in various regimes: First and second thermodynamic-law comparison between air-firing and oxyfuel condition

    International Nuclear Information System (INIS)

    Liu, Yaming; Chen, Sheng; Liu, Shi; Feng, Yongxin; Xu, Kai; Zheng, Chuguang

    2016-01-01

    MILD oxyfuel combustion has been attracting increasing attention as a promising clean combustion technology. How to design a pathway to reach MILD oxyfuel combustion regime and what can provide a theoretical guide to design such a pathway are two critical questions that need to be answered. So far there has been no open literature on these issues. A type of combustion regime classification map proposed in our previous work, based on the so-called ”Hot Diluted Diffusion Ignition” (HDDI) configuration, is adopted here as a simple but useful tool to solve these problems. Firstly, we analyze comprehensively the influences of various dilution atmosphere and fuel type on combustion regimes. The combustion regime classification maps are made out according to the analyses. In succession, we conduct a comparison between the map in air-firing condition and its oxyfuel counterpart. With the aid of the second thermodynamic-law analysis on the maps, it is easy to identify the major contributors to entropy generation in various combustion regimes in advance, which is crucial for combustion system optimization. Moreover, we find that, for the first time, a combustion regime classification map also may be used as a safety indicator. With the aid of these maps, some conclusions in previous publications can be explained more straightforwardly. - Highlights: • Analyze the influences of different fuels and dilution atmosphere on combustion regimes for the first time. • Provide a theoretical guide for practical operation to establish MILD oxyfuel combustion for the first time. • A new finding to expand the purposes of combustion regime maps for practical operation and combustion optimization.

  1. Numerical analysis on the combustion and emission characteristics of forced swirl combustion system for DI diesel engines

    International Nuclear Information System (INIS)

    Su, LiWang; Li, XiangRong; Zhang, Zheng; Liu, FuShui

    2014-01-01

    Highlights: • A new combustion system named FSCS for DI diesel engines was proposed. • Fuel/air mixture formation was improved for the application of FSCS. • The FSCS showed a good performance on emission characteristics. - Abstract: To optimize the fuel/air mixture formation and improve the environmental effect of direct injection (DI) diesel engines, a new forced swirl combustion system (FSCS) was proposed concerned on unique design of the geometric shape of the combustion chamber. Numerical simulation was conducted to verify the combustion and emission characteristics of the engines with FSCS. The fuel/air diffusion, in-cylinder velocity distribution, turbulent kinetic energy and in-cylinder temperature distribution were analyzed and the results shown that the FSCS can increase the area of fuel/air diffusion and improve the combustion. The diesel engine with FSCS also shown excellent performance on emission. At full load condition, the soot emission was significantly reduced for the improved fuel/air mixture formation. There are slightly difference for the soot and NO emission between the FSCS and the traditional omega combustion system at lower load for the short penetration of the fuel spray

  2. Atmospheric fluidized bed coal combustion research, development and application

    CERN Document Server

    Valk, M

    1994-01-01

    The use of fluidized bed coal combustion technology has been developed in the past decade in The Netherlands with a view to expanding the industrial use of coal as an energy supply. Various research groups from universities, institutes for applied science and from boiler industries participated and contributed to this research area. Comprehensive results of such recent experimentation and development work on atmospheric fluidized bed combustion of coal are covered in this volume. Each chapter, written by an expert, treats one specific subject and gives both the theoretical background as well a

  3. A comparison of SAR ATR performance with information theoretic predictions

    Science.gov (United States)

    Blacknell, David

    2003-09-01

    Performance assessment of automatic target detection and recognition algorithms for SAR systems (or indeed any other sensors) is essential if the military utility of the system / algorithm mix is to be quantified. This is a relatively straightforward task if extensive trials data from an existing system is used. However, a crucial requirement is to assess the potential performance of novel systems as a guide to procurement decisions. This task is no longer straightforward since a hypothetical system cannot provide experimental trials data. QinetiQ has previously developed a theoretical technique for classification algorithm performance assessment based on information theory. The purpose of the study presented here has been to validate this approach. To this end, experimental SAR imagery of targets has been collected using the QinetiQ Enhanced Surveillance Radar to allow algorithm performance assessments as a number of parameters are varied. In particular, performance comparisons can be made for (i) resolutions up to 0.1m, (ii) single channel versus polarimetric (iii) targets in the open versus targets in scrubland and (iv) use versus non-use of camouflage. The change in performance as these parameters are varied has been quantified from the experimental imagery whilst the information theoretic approach has been used to predict the expected variation of performance with parameter value. A comparison of these measured and predicted assessments has revealed the strengths and weaknesses of the theoretical technique as will be discussed in the paper.

  4. Combustion, performance, and emission characteristics of low heat rejection engine operating on various biodiesels and vegetable oils

    International Nuclear Information System (INIS)

    Abedin, M.J.; Masjuki, H.H.; Kalam, M.A.; Sanjid, A.; Ashraful, A.M.

    2014-01-01

    Highlights: • Combustion, performance, and emissions of low heat rejection engine are studied. • Comparative assessment is carried out for different fuels and coating materials. • Alternative coating materials are suggested for engine. • Thermal efficiency is increased and fuel consumption is decreased for all fuels. • Exhaust emissions have improved except nitrogen oxides emission. - Abstract: Internal combustion engine with its combustion chamber walls insulated by thermal barrier coating materials is referred to as low heat rejection engine or LHR engine. The main purpose of this concept is to reduce engine coolant heat losses, hence improve engine performance. Most of the researchers have reported that the thermal coating increases thermal efficiency, and reduces exhaust emissions. In contrast to the above expectations, a few researchers reported that almost there was no improvement in thermal efficiency. This manuscript investigates the contradictory results in order to find out the exact scenario. A wide range of coating materials has been studied in order to justify their feasibility of implementation in engine. The influence of coating material, thickness, and technique on engine performance and emissions has been studied critically to accelerate the LHR engine evolution. The objectives of higher thermal efficiency, improved fuel economy, and lower emissions are accomplishable but much more investigations with improved engine modification, and design are required to explore full potentiality of LHR engine

  5. Compositional Effects of Gasoline Fuels on Combustion, Performance and Emissions in Engine

    KAUST Repository

    Ahmed, Ahfaz; Waqas, Muhammad; Naser, Nimal; Singh, Eshan; Roberts, William L.; Chung, Suk-Ho; Sarathy, Mani

    2016-01-01

    to interpret differences in combustion behavior of gasoline fuels that show similar knock characteristics in a cooperative fuel research (CFR) engine, but may behave differently in direct injection spark ignition (DISI) engines or any other engine combustion

  6. Effects of stepwise gas combustion on NOx generation

    International Nuclear Information System (INIS)

    Woperane Seredi, A.; Szepesi, E.

    1999-01-01

    To decrease NO x emission from gas boilers, the combustion process of gas has been modified from continuous combustion to step-wise combustion. In this process the combustion temperature, the temperature peaks in the flame, the residence time of combustion products in the high-temperature zone and the oxygen partial pressure are changed advantageously. Experiments were performed using multistage burners, and the NO x emission was recorded. It was found that the air factor of the primary combustion space has a determining effect on the NO x reduction. (R.P.)

  7. Numerical analysis for controlling mixture heterogeneity to reduce abrupt combustion in diesel PCCI combustion

    Energy Technology Data Exchange (ETDEWEB)

    Nishiwaki, Kazuie [Ritsumeikan University (Japan); Kojima, Takafumi [Takamatsu National College of Technology (Japan)

    2010-07-01

    In the energy sector, stringent regulations have been implemented on combustion emissions in order to address health and environmental concerns and help improve air quality. A novel combustion mode, premixed charge compression ignition (PCCI), can improve the emissions performance of an engine over that of conventional diesel. The aim of this research is to develop a model to analyze the mixture formation in the PCCI combustion mode. A numerical model was developed and was applied to an engine and the results were compared to experimental results. It was found that the model results are in agreement with the experimental results. This paper presented a novel LES computer model and demonstrated that it is efficient in predicting the mixture formation in the PCCI combustion mode.

  8. A review of active control approaches in stabilizing combustion systems in aerospace industry

    Science.gov (United States)

    Zhao, Dan; Lu, Zhengli; Zhao, He; Li, X. Y.; Wang, Bing; Liu, Peijin

    2018-02-01

    Self-sustained combustion instabilities are one of the most plaguing challenges and problems in lean-conditioned propulsion and land-based engine systems, such as rocket motors, gas turbines, industrial furnace and boilers, and turbo-jet thrust augmenters. Either passive or active control in open- or closed-loop configurations can be implemented to mitigate such instabilities. One of the classical disadvantages of passive control is that it is only implementable to a designed combustor over a limited frequency range and can not respond to the changes in operating conditions. Compared with passive control approaches, active control, especially in closed-loop configuration is more adaptive and has inherent capacity to be implemented in practice. The key components in closed-loop active control are 1) sensor, 2) controller (optimization algorithm) and 3) dynamic actuator. The present work is to outline the current status, technical challenges and development progress of the active control approaches (in open- or closed-loop configurations). A brief description of feedback control, adaptive control, model-based control and sliding mode control are provided first by introducing a simplified Rijke-type combustion system. The modelled combustion system provides an invaluable platform to evaluate the performance of these feedback controllers and a transient growth controller. The performance of these controllers are compared and discussed. An outline of theoretical, numerical and experimental investigations are then provided to overview the research and development progress made during the last 4 decades. Finally, potential, challenges and issues involved with the design, application and implementation of active combustion control strategies on a practical engine system are highlighted.

  9. A Theoretical Evaluation of Secondary Atomization Effects on Engine Performance for Aluminum Gel Propellants

    Science.gov (United States)

    Mueller, D. C.; Turns, S. R.

    1994-01-01

    A one-dimensional model of a gel-fueled rocket combustion chamber has been developed. This model includes the processes of liquid hydrocarbon burnout, secondary atomization. aluminum ignition, and aluminum combustion. Also included is a model of radiative heat transfer from the solid combustion products to the chamber walls. Calculations indicate that only modest secondary atomization is required to significantly reduce propellant burnout distances, aluminum oxide residual size and radiation heat wall losses. Radiation losses equal to approximately 2-13 percent of the energy released during combustion were estimated. A two-dimensional, two-phase nozzle code was employed to estimate radiation and nozzle two-phase flow effects on overall engine performance. Radiation losses yielded a 1 percent decrease in engine I(sub sp). Results also indicate that secondary atomization may have less effect on two-phase losses than it does on propellant burnout distance and no effect if oxide particle coagulation and shear induced droplet breakup govern oxide particle size. Engine I(sub sp) was found to decrease from 337.4 to 293.7 seconds as gel aluminum mass loading was varied from 0-70 wt percent. Engine I(sub sp) efficiencies, accounting for radiation and two-phase flow effects, on the order of 0.946 were calculated for a 60 wt percent gel, assuming a fragmentation ratio of 5.

  10. Heavy metals behaviour during mono-combustion and co-combustion of sewage sludge

    Energy Technology Data Exchange (ETDEWEB)

    Lopes, M. Helena; Abelha, Pedro; Olieveira, J.F. Santos; Gulyurtlu, Ibrahim; Cabrita, Isabel [INETI-DEECA, Lisboa (Portugal)

    2005-03-01

    This paper presents the study of the combustion of granular dry sewage sludge performed on a pilot fluidized bed system. The results of mono-combustion of sludge and co-combustion with coal were compared with those of coal combustion for ash partitioning, the formation of gaseous pollutants and heavy metals behaviour. It was found that the mineral matter of sludge was essentially retained as bottom ashes. The production of fines ashes was small during the mono-combustion due to the tendency of coal to produce fine ashes which also contained unburned char. The degree of heavy metal volatilization was found to be slightly higher during co-combustion than in mono-combustion; however, most of them were retained in ashes and their emissions were found to be below the regulated levels. Hg was completely volatilized; however, during combustion trials involving coal it was captured by cyclone ashes at temperatures below 300 deg C. During sludge mono-combustion the retention of Hg in cyclone ashes containing low LOI was not enough to decrease emissions below the regulated levels; hence, it is necessary to install dedicated flue gas treatment for Hg removal. The leachability and ecotoxicity of sludge and ashes was compared with the new regulatory limits for landfill disposal in the EU. It was found that the release of organic matter and heavy metals found in the sludge was low from granular bed ashes; hence, except for sulphate release, bed ashes were converted into inert and non-ecotoxic materials. Ashes from test with limestone and cyclone ashes seemed to be more problematic because of pH effects and contamination with steel corrosion products. The recovery and reutilization of sludge bed ashes could, therefore, be possible, as long as the release of sulphate do not interfere with the process.

  11. Theoretical studies of chemical reaction dynamics

    Energy Technology Data Exchange (ETDEWEB)

    Schatz, G.C. [Argonne National Laboratory, IL (United States)

    1993-12-01

    This collaborative program with the Theoretical Chemistry Group at Argonne involves theoretical studies of gas phase chemical reactions and related energy transfer and photodissociation processes. Many of the reactions studied are of direct relevance to combustion; others are selected they provide important examples of special dynamical processes, or are of relevance to experimental measurements. Both classical trajectory and quantum reactive scattering methods are used for these studies, and the types of information determined range from thermal rate constants to state to state differential cross sections.

  12. Construction of combustion models for rapeseed methyl ester bio-diesel fuel for internal combustion engine applications.

    Science.gov (United States)

    Golovitchev, Valeri I; Yang, Junfeng

    2009-01-01

    Bio-diesel fuels are non-petroleum-based diesel fuels consisting of long chain alkyl esters produced by the transesterification of vegetable oils, that are intended for use (neat or blended with conventional fuels) in unmodified diesel engines. There have been few reports of studies proposing theoretical models for bio-diesel combustion simulations. In this study, we developed combustion models based on ones developed previously. We compiled the liquid fuel properties, and the existing detailed mechanism of methyl butanoate ester (MB, C(5)H(10)O(2)) oxidation was supplemented by sub-mechanisms for two proposed fuel constituent components, C(7)H(16) and C(7)H(8)O (and then, by mp2d, C(4)H(6)O(2) and propyne, C(3)H(4)) to represent the combustion model for rapeseed methyl ester described by the chemical formula, C(19)H(34)O(2) (or C(19)H(36)O(2)). The main fuel vapor thermal properties were taken as those of methyl palmitate C(19)H(36)O(2) in the NASA polynomial form of the Burcat database. The special global reaction was introduced to "crack" the main fuel into its constituent components. This general reaction included 309 species and 1472 reactions, including soot and NO(x) formation processes. The detailed combustion mechanism was validated using shock-tube ignition-delay data under diesel engine conditions. For constant volume and diesel engine (Volvo D12C) combustion modeling, this mechanism could be reduced to 88 species participating in 363 reactions.

  13. Straw combustion on slow-moving grates

    DEFF Research Database (Denmark)

    Kær, Søren Knudsen

    2005-01-01

    Combustion of straw in grate-based boilers is often associated with high emission levels and relatively poor fuel burnout. A numerical grate combustion model was developed to assist in improving the combustion performance of these boilers. The model is based on a one-dimensional ‘‘walking......-column’’ approach and includes the energy equations for both the fuel and the gas accounting for heat transfer between the two phases. The model gives important insight into the combustion process and provides inlet conditions for a computational fluid dynamics analysis of the freeboard. The model predictions...... indicate the existence of two distinct combustion modes. Combustion air temperature and mass flow-rate are the two parameters determining the mode. There is a significant difference in reaction rates (ignition velocity) and temperature levels between the two modes. Model predictions were compared...

  14. Combustion

    CERN Document Server

    Glassman, Irvin

    2008-01-01

    Combustion Engineering, a topic generally taught at the upper undergraduate and graduate level in most mechanical engineering programs, and many chemical engineering programs, is the study of rapid energy and mass transfer usually through the common physical phenomena of flame oxidation. It covers the physics and chemistry of this process and the engineering applications-from the generation of power such as the internal combustion automobile engine to the gas turbine engine. Renewed concerns about energy efficiency and fuel costs, along with continued concerns over toxic and particulate emissions have kept the interest in this vital area of engineering high and brought about new developments in both fundamental knowledge of flame and combustion physics as well as new technologies for flame and fuel control. *New chapter on new combustion concepts and technologies, including discussion on nanotechnology as related to combustion, as well as microgravity combustion, microcombustion, and catalytic combustion-all ...

  15. Comparison of catalytic converter performance in internal combustion engine fueled with Ron 95 and Ron 97 gasoline

    Science.gov (United States)

    Leman, A. M.; Rahman, Fakhrurrazi; Jajuli, Afiqah; Feriyanto, Dafit; Zakaria, Supaat

    2017-09-01

    Generating ideal stability between engine performance, fuel consumption and emission is one of the main challenges in the automotive industry. The characteristics of engine combustion and creation of emission might simply change with different types of operating parameters. This study aims in investigating the relationship between two types of fuels on the performance and exhaust emission of internal combustion engine using ceramic and metallic catalytic converters. Experimental tests were performed on Mitsubishi 4G93 engine by applying several ranges of engine speeds to determine the conversion of pollutant gases released by the engine. The obtained results specify that the usage of RON 97 equipped with metallic converters might increase the conversion percentage of 1.31% for CO and 126 ppm of HC gases. The metallic converters can perform higher conversion compared to ceramic because in the high space velocities, metallic has higher surface geometry area and higher amount of transverse Peclet number (Pi). Ceramic converters achieved conversion at 2496 ppm of NOx gas, which is higher than the metallic converter.

  16. Combustion

    CERN Document Server

    Glassman, Irvin

    1997-01-01

    This Third Edition of Glassman's classic text clearly defines the role of chemistry, physics, and fluid mechanics as applied to the complex topic of combustion. Glassman's insightful introductory text emphasizes underlying physical and chemical principles, and encompasses engine technology, fire safety, materials synthesis, detonation phenomena, hydrocarbon fuel oxidation mechanisms, and environmental considerations. Combustion has been rewritten to integrate the text, figures, and appendixes, detailing available combustion codes, making it not only an excellent introductory text but also an important reference source for professionals in the field. Key Features * Explains complex combustion phenomena with physical insight rather than extensive mathematics * Clarifies postulates in the text using extensive computational results in figures * Lists modern combustion programs indicating usage and availability * Relates combustion concepts to practical applications.

  17. Assessment of Literature Related to Combustion Appliance Venting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, Vi H. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Singer, Brett C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Stratton, Chris [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Wray, Craig P. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

    2012-06-01

    In many residential building retrofit programs, air tightening to increase energy efficiency is constrained by concerns about related impacts on the safety of naturally vented combustion appliances. Tighter housing units more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spillage. Several test methods purportedly assess the potential for depressurization-induced backdrafting and spillage, but these tests are not robustly reliable and repeatable predictors of venting performance, in part because they do not fully capture weather effects on venting performance. The purpose of this literature review is to investigate combustion safety diagnostics in existing codes, standards, and guidelines related to combustion appliances. This review summarizes existing combustion safety test methods, evaluations of these test methods, and also discusses research related to wind effects and the simulation of vent system performance. Current codes and standards related to combustion appliance installation provide little information on assessing backdrafting or spillage potential. A substantial amount of research has been conducted to assess combustion appliance backdrafting and spillage test methods, but primarily focuses on comparing short-term (stress) induced tests and monitoring results. Monitoring, typically performed over one week, indicated that combinations of environmental and house operation characteristics most conducive to combustion spillage were rare. Research, to an extent, has assessed existing combustion safety diagnostics for house depressurization, but the objectives of the diagnostics, both stress and monitoring, are not clearly defined. More research is also needed to quantify the frequency of test “failure” occurrence throughout the building stock and assess the statistical effects of weather (especially wind) on house depressurization and in turn on combustion appliance venting

  18. Theoretical and observational assessments of flare efficiencies

    International Nuclear Information System (INIS)

    Leahey, D.M.; Preston, K.; Strosher, M.

    2000-01-01

    During the processing of hydrocarbon materials, gaseous wastes are flared in an effort to completely burn the waste material and therefore leave behind very little by-products. Complete combustion, however is rarely successful because entrainment of air into the region of combusting gases restricts flame sizes to less than optimum values. The resulting flames are often too small to dissipate the amount of heat associated with complete (100 per cent) combustion efficiency. Flaring, therefore, often results in emissions of gases with more complex molecular structures than just carbon dioxide and water. Polycyclic aromatic hydrocarbons and volatile organic compounds which are indicative of incomplete combustion are often associated with flaring. This theoretical study of flame efficiencies was based on the knowledge of the full range of chemical reactions and associated kinetics. In this study, equations developed by Leahey and Schroeder were used to estimate flame lengths, areas and volumes as functions of flare stack exit velocity, stoichiometric mixing ratio and wind speed. This was followed by an estimate of heats released as part of the combustion process. This was derived from the knowledge of the flame dimensions together with an assumed flame temperature of 1200 K. Combustion efficiencies were then obtained by taking the ratio of estimated actual heat release values to those associated with complete combustion. It was concluded that combustion efficiency decreases significantly with wind speed increases from 1 to 6 m/s. After that initial increase, combustion efficiencies level off at values between 10 to 15 per cent. Propane and ethane were found to burn more efficiently than methane or hydrogen sulfide. 24 refs., 4 tabs., 1 fig., 1 append

  19. Toxic combustion products from pesticide fires. Executive summary

    NARCIS (Netherlands)

    Molag, M.; Bartelds, H.; Weger, D. de

    1992-01-01

    In order to obtain reliable data on the generation of toxic combustion products and to get more insight into the risks of fires in pesticide warehouses TNO performed the research project 'Toxic combustion products from pesticide fires'. The following research activities have been performed during

  20. Environmental Performance of Hypothetical Canadian Pre-Combustion Carbon Dioxide Capture Processes Using Life-Cycle Techniques

    Directory of Open Access Journals (Sweden)

    Lakkana Piewkhaow

    2016-03-01

    Full Text Available The methodology of life-cycle assessment was applied in order to evaluate the environmental performance of a hypothetical Saskatchewan lignite-fueled Integrated Gasification Combined Cycle (IGCC electricity generation, with and without pre-combustion carbon dioxide (CO2 capture from a full life-cycle perspective. The emphasis here is placed on environmental performance associated with air contaminants of the comparison between IGCC systems (with and without CO2 capture and a competing lignite pulverized coal-fired electricity generating station in order to reveal which technology offers the most positive environmental effects. Moreover, ambient air pollutant modeling was also conducted by using American Meteorological Society/Environmental Protection Agency Regulatory Model (AERMOD air dispersion modeling to determine the ground-level concentration of pollutants emitted from four different electricity generating stations. This study assumes that all stations are located close to Estevan. The results showed a significant reduction in greenhouse gas (GHG emissions and acidification potential by applying both post-combustion and pre-combustion CO2 capture processes. The GHG emissions were found to have reduced by 27%–86%, and IGCC systems were found to compare favorably to pulverized coal systems. However, in other environmental impact categories, there are multiple environmental trade-offs depending on the capture technology used. In the case of post-combustion capture, it was observed that the environmental impact category of eutrophication potential, summer smog, and ozone depletion increased due to the application of the CO2 capture process and the surface mining coal operation. IGCC systems, on the other hand, showed the same tendency as the conventional coal-fired electricity generation systems, but to a lesser degree. This is because the IGCC system is a cleaner technology that produces lower pollutant emission levels than the electricity

  1. Chemistry and radiation in oxy-fuel combustion

    DEFF Research Database (Denmark)

    Yin, Chungen; Rosendahl, Lasse; Kær, Søren Knudsen

    2011-01-01

    In order to investigate the role of combustion chemistry and radiation heat transfer in oxy-fuel combustion modeling, a computational fluid dynamics (CFD) modeling study has been performed for two different oxy-fuel furnaces. One is a lab-scale 0.8MW oxy-natural gas flame furnace whose detailed in....... Among the key issues in combustion modeling, e.g., mixing, radiation and chemistry, this paper derives useful guidelines on radiation and chemistry implementation for reliable CFD analyses of oxy-fuel combustion, particularly for industrial applications....

  2. COMBUSTION OF BIOMASS AND CHARCOAL MADE FROM BABASSU NUTSHELL

    Directory of Open Access Journals (Sweden)

    Thiago de Paula Protásio

    2017-03-01

    Full Text Available In recent years, studies have examined the use of lignocellulosic wastes for energy generation. However, there is a lack of information on the combustibility of the residual biomass, especially the bark and charcoal of babassu nut. In this study, thermogravimetric analysis (TGA, differential thermal analysis (DTA and differential scanning calorimetry (DSC were used to achieve the following objectives: to evaluate the combustion of the residual biomass from the babassu nut; to evaluate the combustion of charcoal produced from this biomass, considering different final carbonization temperatures; and to determine the effect of the final carbonization temperature on the thermal stability of charcoal and on its performance in combustion. Thermal analyses were performed in synthetic air. In order to evaluate the characteristics of charcoal combustion and fresh biomass, the ignition temperature (Ti, the burnout temperature (Tf, characteristic combustion index (S, ignition index (Di, time corresponding to the maximum combustion rate (tp, and ignition time (tig were considered. The combustion of the babassu nutshell occurred in three phases and it was observed that this lignocellulosic material is suitable for the direct generation of heat. The increase in the final carbonization temperature caused an increase in the ignition temperature, as well as in the burnout temperature, the ignition time and the time corresponding to the maximum combustion rate. The results indicate that the increase in the carbonization temperature causes a decrease in combustion reactivity and, consequently, the charcoals produced at lower temperatures are easier to ignite and exhibit better performance in ignition.

  3. Cylinder pressure, performance parameters, heat release, specific heats ratio and duration of combustion for spark ignition engine

    Energy Technology Data Exchange (ETDEWEB)

    Shehata, M.S. [Mechanical Engineering Technology Department, Higher Institute of Technology, Banha University, 4Zagalol Street, Benha, Galubia 1235 Z (Egypt)

    2010-12-15

    An experimental work were conducted for investigating cylinder pressure, performance parameters, heat release, specific heat ratio and duration of combustion for multi cylinder spark ignition engine (SIE). Ccylinder pressure was measured for gasoline, kerosene and Liquefied Petroleum Gases (LPG) separately as a fuel for SIE. Fast Fourier Transformations (FFT) was used to cylinder pressure data transform from time domain into frequency domain to develop empirical correlation for calculating cylinder pressures at different engine speeds and different fuels. In addition, Inverse Fast Fourier Transformations (IFFT) was used to cylinder pressure reconstruct into time domain. The results gave good agreement between the measured cylinder pressure and the reconstructed cylinder pressure in time domain with different engine speeds and different fuels. The measured cylinder pressure and hydraulic dynamotor were the source of data for calculating engine performance parameters. First law of thermodynamics and single zone heat release model with temperature dependant specific heat ratio {gamma}(T) were the main tools for calculating heat release and heat transfer to cylinder walls. Third order empirical correlation for calculating {gamma}(T) was one of the main gains of the present study. The correlation gave good agreement with other researchers with wide temperatures range. For kerosene, cylinder pressure is higher than for gasoline and LPG due to high volumetric efficiency where kerosene density (mass/volume ratio) is higher than gasoline and LPG. In addition, kerosene heating value is higher than gasoline that contributes in heat release rate and pressure increases. Duration of combustion for different engine speeds was determined using four different methods: (I) Mass fuel burnt, (II) Entropy change, (III) Temperature dependant specific heat ratio {gamma}(T), and (IV) Logarithmic scale of (P and V). The duration of combustion for kerosene is smaller than for gasoline and

  4. Cylinder pressure, performance parameters, heat release, specific heats ratio and duration of combustion for spark ignition engine

    International Nuclear Information System (INIS)

    Shehata, M.S.

    2010-01-01

    An experimental work were conducted for investigating cylinder pressure, performance parameters, heat release, specific heat ratio and duration of combustion for multi cylinder spark ignition engine (SIE). Ccylinder pressure was measured for gasoline, kerosene and Liquefied Petroleum Gases (LPG) separately as a fuel for SIE. Fast Fourier Transformations (FFT) was used to cylinder pressure data transform from time domain into frequency domain to develop empirical correlation for calculating cylinder pressures at different engine speeds and different fuels. In addition, Inverse Fast Fourier Transformations (IFFT) was used to cylinder pressure reconstruct into time domain. The results gave good agreement between the measured cylinder pressure and the reconstructed cylinder pressure in time domain with different engine speeds and different fuels. The measured cylinder pressure and hydraulic dynamotor were the sours of data for calculating engine performance parameters. First law of thermodynamics and single zone heat release model with temperature dependant specific heat ratio γ(T) were the main tools for calculating heat release and heat transfer to cylinder walls. Third order empirical correlation for calculating γ(T) was one of the main gains of the present study. The correlation gave good agreement with other researchers with wide temperatures range. For kerosene, cylinder pressure is higher than for gasoline and LPG due to high volumetric efficiency where kerosene density (mass/volume ratio) is higher than gasoline and LPG. In addition, kerosene heating value is higher than gasoline that contributes in heat release rate and pressure increases. Duration of combustion for different engine speeds was determined using four different methods: (I) Mass fuel burnt, (II) Entropy change, (III) Temperature dependant specific heat ratio γ(T), and (IV) Logarithmic scale of (P and V). The duration of combustion for kerosene is smaller than for gasoline and LPG due to high

  5. Simulation of lean premixed turbulent combustion

    International Nuclear Information System (INIS)

    Bell, J; Day, M; Almgren, A; Lijewski, M; Rendleman, C; Cheng, R; Shepherd, I

    2006-01-01

    There is considerable technological interest in developing new fuel-flexible combustion systems that can burn fuels such as hydrogen or syngas. Lean premixed systems have the potential to burn these types of fuels with high efficiency and low NOx emissions due to reduced burnt gas temperatures. Although traditional Scientific approaches based on theory and laboratory experiment have played essential roles in developing our current understanding of premixed combustion, they are unable to meet the challenges of designing fuel-flexible lean premixed combustion devices. Computation, with its ability to deal with complexity and its unlimited access to data, has the potential for addressing these challenges. Realizing this potential requires the ability to perform high fidelity simulations of turbulent lean premixed flames under realistic conditions. In this paper, we examine the specialized mathematical structure of these combustion problems and discuss simulation approaches that exploit this structure. Using these ideas we can dramatically reduce computational cost, making it possible to perform high-fidelity simulations of realistic flames. We illustrate this methodology by considering ultra-lean hydrogen flames and discuss how this type of simulation is changing the way researchers study combustion

  6. Investigation the performance of 0-D and 3-d combustion simulation softwares for modelling HCCI engine with high air excess ratios

    Directory of Open Access Journals (Sweden)

    Gökhan Coşkun

    2017-10-01

    Full Text Available In this study, performance of zero and three dimensional simulations codes that used for simulate a homogenous charge compression ignition (HCCI engine fueled with Primary Reference Fuel PRF (85% iso-octane and 15% n-heptane were investigated. 0-D code, called as SRM Suite (Stochastic Reactor Model which can simulate engine combustion by using stochastic reactor model technique were used. Ansys-Fluent which can simulate computational fluid dynamics (CFD was used for 3-D engine combustion simulations. Simulations were evaluated for both commercial codes in terms of combustion, heat transfer and emissions in a HCCI engine. Chemical kinetic mechanisms which developed by Tsurushima including 33 species and 38 reactions for surrogate PRF fuel were used for combustion simulations. Analysis showed that both codes have advantages over each other.

  7. Combustion engineering

    CERN Document Server

    Ragland, Kenneth W

    2011-01-01

    Introduction to Combustion Engineering The Nature of Combustion Combustion Emissions Global Climate Change Sustainability World Energy Production Structure of the Book   Section I: Basic Concepts Fuels Gaseous Fuels Liquid Fuels Solid Fuels Problems Thermodynamics of Combustion Review of First Law Concepts Properties of Mixtures Combustion StoichiometryChemical EnergyChemical EquilibriumAdiabatic Flame TemperatureChemical Kinetics of CombustionElementary ReactionsChain ReactionsGlobal ReactionsNitric Oxide KineticsReactions at a Solid SurfaceProblemsReferences  Section II: Combustion of Gaseous and Vaporized FuelsFlamesLaminar Premixed FlamesLaminar Flame TheoryTurbulent Premixed FlamesExplosion LimitsDiffusion FlamesGas-Fired Furnaces and BoilersEnergy Balance and EfficiencyFuel SubstitutionResidential Gas BurnersIndustrial Gas BurnersUtility Gas BurnersLow Swirl Gas BurnersPremixed-Charge Engine CombustionIntroduction to the Spark Ignition EngineEngine EfficiencyOne-Zone Model of Combustion in a Piston-...

  8. Combustion performance, flame, and soot characteristics of gasoline–diesel pre-blended fuel in an optical compression-ignition engine

    International Nuclear Information System (INIS)

    Jeon, Joonho; Lee, Jong Tae; Kwon, Sang Il; Park, Sungwook

    2016-01-01

    Highlights: • Gasoline–diesel pre-blended fuel was investigated in an optical direct-injection diesel engine. • KIVA3V-CHEMKIN code modeled blended fuel spray and combustion with discrete multi-component model. • Flame and soot characteristics in the combustion chamber were shown by optical kits. • Combustion performance and soot emissions for gasoline–diesel blended fuel were discussed. - Abstract: Among the new combustion technologies available for internal combustion engines to enhance performance and reduce exhausted emissions, the homogeneous charge compression ignition method is one of the most effective strategies for the compression-ignition engine. There are some challenges to realize the homogeneous charge compression ignition method in the compression-ignition engine. The use of gasoline–diesel blended fuel has been suggested as an alternative strategy to take advantages of homogeneous charge compression ignition while overcoming its challenges. Gasoline and diesel fuels are reference fuels for the spark-ignition and compression-ignition engines, respectively, both of which are widely used. The application of both these fuels together in the compression-ignition engine has been investigated using a hybrid injection system combining port fuel injection (gasoline) and direct injection (diesel); this strategy is termed reactivity controlled compression ignition. However, the pre-blending of gasoline and diesel fuels for direct injection systems has been rarely studied. For the case of direct injection of pre-blended fuel into the cylinder, various aspects of blended fuels should be investigated, including their spray breakup, fuel/air mixing, combustion development, and emissions. In the present study, the use of gasoline–diesel pre-blended fuel in an optical single-cylinder compression-ignition engine was investigated under various conditions of injection timing and pressure. Furthermore, KIVA-3V release 2 code was employed to model the

  9. Experimental studies on the combustion characteristics and performance of a direct injection engine fueled with biodiesel/diesel blends

    International Nuclear Information System (INIS)

    Qi, D.H.; Chen, H.; Geng, L.M.; Bian, Y. ZH.

    2010-01-01

    Biodiesel is an alternative diesel fuel that can be produced from different kinds of vegetable oils. It is an oxygenated, non-toxic, sulphur-free, biodegradable, and renewable fuel and can be used in diesel engines without significant modification. However, the performance, emissions and combustion characteristics will be different for the same biodiesel used in different types of engine. In this study, the biodiesel produced from soybean crude oil was prepared by a method of alkaline-catalyzed transesterification. The effects of biodiesel addition to diesel fuel on the performance, emissions and combustion characteristics of a naturally aspirated DI compression ignition engine were examined. Biodiesel has different properties from diesel fuel. A minor increase in brake specific fuel consumption (BSFC) and decrease in brake thermal efficiency (BTE) for biodiesel and its blends were observed compared with diesel fuel. The significant improvement in reduction of carbon monoxide (CO) and smoke were found for biodiesel and its blends at high engine loads. Hydrocarbon (HC) had no evident variation for all tested fuels. Nitrogen oxides (NOx) were slightly higher for biodiesel and its blends. Biodiesel and its blends exhibited similar combustion stages to diesel fuel. The use of transesterified soybean crude oil can be partially substituted for the diesel fuel at most operating conditions in terms of the performance parameters and emissions without any engine modification.

  10. Technical and environmental performance of 10 kW understocker boiler during combustion of biomass and conventional fuels

    Science.gov (United States)

    Junga, Robert; Wzorek, Małgorzata; Kaszubska, Mirosława

    2017-10-01

    This paper treats about the impact fuels from biomass wastes and coal combustion on a small boiler operation and the emission of pollutants in this process. Tests were performed in laboratory conditions on a water boiler with retort furnace and the capacity of 10 kW. Fuels from sewage sludge and agriculture wastes (PBZ fuel) and a blend of coal with laying hens mature (CLHM) were taken into account. The results in emission changes of NOx, CO2, CO and SO2 and operating parameters of the tested boiler during combustion were investigated. The obtained results were compared with corresponding results of flame coal (GFC). Combustion of the PBZ fuel turned out to be a stable process in the tested boiler but the thermal output has decreased in about 30% compared to coal combustion, while CO and NOx emission has increased. Similar effect was observed when 15% of the poultry litter was added to the coal. In this case thermal output has also decreased (in about 20%) and increase of CO and NOx emission was observed. As a conclusion, it can be stated that more effective control system with an adaptive air regulation and a modified heat exchanger could be useful in order to achieve the nominal power of the tested boiler.

  11. Technical and environmental performance of 10 kW understocker boiler during combustion of biomass and conventional fuels

    Directory of Open Access Journals (Sweden)

    Junga Robert

    2017-01-01

    Full Text Available This paper treats about the impact fuels from biomass wastes and coal combustion on a small boiler operation and the emission of pollutants in this process. Tests were performed in laboratory conditions on a water boiler with retort furnace and the capacity of 10 kW. Fuels from sewage sludge and agriculture wastes (PBZ fuel and a blend of coal with laying hens mature (CLHM were taken into account. The results in emission changes of NOx, CO2, CO and SO2 and operating parameters of the tested boiler during combustion were investigated. The obtained results were compared with corresponding results of flame coal (GFC. Combustion of the PBZ fuel turned out to be a stable process in the tested boiler but the thermal output has decreased in about 30% compared to coal combustion, while CO and NOx emission has increased. Similar effect was observed when 15% of the poultry litter was added to the coal. In this case thermal output has also decreased (in about 20% and increase of CO and NOx emission was observed. As a conclusion, it can be stated that more effective control system with an adaptive air regulation and a modified heat exchanger could be useful in order to achieve the nominal power of the tested boiler.

  12. Infrared monitoring of combustion

    International Nuclear Information System (INIS)

    Bates, S.C.; Morrison, P.W. Jr.; Solomon, P.R.

    1991-01-01

    In this paper, the use of Fourier Transform Infrared (FT-IR) spectroscopy for combustion monitoring is described. A combination of emission, transmission, and reflection FT-IR spectroscopy yields data on the temperature and composition of the gases, surfaces and suspended particles in the combustion environment. Detection sensitivity of such trace exhaust gases as CO, CO 2 , SO 2 , NO x , and unburned hydrocarbons is at the ppm level. Tomographic reconstruction converts line-of-sight measurements into spatially resolved temperature and concentration data. Examples from various combustion processes are used to demonstrate the capabilities of the technique. Industrial measurements are described that have been performed directly in the combustion zone and in the exhaust duct of a large chemical recovery boiler. Other measurements of hot slag show how FT-IR spectroscopy can determine the temperature and optical properties of surfaces. In addition, experiments with water droplets show that transmission FT-IR data yield spectra that characterize particle size and number density

  13. Multi-objective optimization of combustion, performance and emission parameters in a jatropha biodiesel engine using Non-dominated sorting genetic algorithm-II

    Science.gov (United States)

    Dhingra, Sunil; Bhushan, Gian; Dubey, Kashyap Kumar

    2014-03-01

    The present work studies and identifies the different variables that affect the output parameters involved in a single cylinder direct injection compression ignition (CI) engine using jatropha biodiesel. Response surface methodology based on Central composite design (CCD) is used to design the experiments. Mathematical models are developed for combustion parameters (Brake specific fuel consumption (BSFC) and peak cylinder pressure (Pmax)), performance parameter brake thermal efficiency (BTE) and emission parameters (CO, NO x , unburnt HC and smoke) using regression techniques. These regression equations are further utilized for simultaneous optimization of combustion (BSFC, Pmax), performance (BTE) and emission (CO, NO x , HC, smoke) parameters. As the objective is to maximize BTE and minimize BSFC, Pmax, CO, NO x , HC, smoke, a multiobjective optimization problem is formulated. Nondominated sorting genetic algorithm-II is used in predicting the Pareto optimal sets of solution. Experiments are performed at suitable optimal solutions for predicting the combustion, performance and emission parameters to check the adequacy of the proposed model. The Pareto optimal sets of solution can be used as guidelines for the end users to select optimal combination of engine output and emission parameters depending upon their own requirements.

  14. INVESTIGATION OF COMBUSTION, PERFORMANCE AND EMISSION CHARACTERISTICS OF SPARK IGNITION ENGINE FUELLED WITH BUTHANOL – GASOLINE MIXTURE AND A HYDROGEN ENRICHED AIR

    Directory of Open Access Journals (Sweden)

    Alfredas Rimkus

    2016-09-01

    Full Text Available In this study, spark ignition engine fuelled with buthanol-gasoline mixture and a hydrogen-enriched air was investigated. Engine performance, emissions and combustion characteristics were investigated with different buthanol (10% and 20% by volume gasoline mixtures and additionally supplied oxygen and hydrogen (HHO gas mixture (3.6 l/min in the sucked air. Hydrogen, which is in the HHO gas, improves gasoline and gasoline-buthanol mixture combustion, increases indicated pressure during combustion phase and decreases effective specific fuel consumption. Buthanol addition decreases the rate of heat release, the combustion temperature and pressure are lower which have an influence on lower nitrous oxide (NOx emission in exhaust gases. Buthanol lowers hydrocarbon (HC formation, but it increases carbon monoxide (CO concentration and fuel consumption. Combustion process analysis was carried out using AVL BOOST software. Experimental research and combustion process numerical simulation showed that using balanced buthanol and hydrogen addition, optimal efficient and ecological parameters could be achieved when engine is working with optimal spark timing, as it would work on gasoline fuel.

  15. Investigation of the effects of renewable diesel fuels on engine performance, combustion, and emissions

    KAUST Repository

    Ogunkoya, Dolanimi

    2015-01-01

    A study was undertaken to investigate renewable fuels in a compression-ignition internal combustion engine. The focus of this study was the effect of newly developed renewable fuels on engine performance, combustion, and emissions. Eight fuels were investigated, and they include diesel, jet fuel, a traditional biodiesel (fatty acid methyl ester: FAME), and five next generation biofuels. These five fuels were derived using a two-step process: hydrolysis of the oil into fatty acids (if necessary) and then a thermo-catalytic process to remove the oxygen via a decarboxylation reaction. The fuels included a fed batch deoxygenation of canola derived fatty acids (DCFA), a fed batch deoxygenation of canola derived fatty acids with varying amounts of H2 used during the deoxygenation process (DCFAH), a continuous deoxygenation of canola derived fatty acids (CDCFA), fed batch deoxygenation of lauric acid (DLA), and a third reaction to isomerize the products of the deoxygenated canola derived fatty acid alkanes (IPCF). Diesel, jet fuel, and biodiesel (FAME) have been used as benchmarks for comparing with the newer renewable fuels. The results of the experiments show slightly lower mechanical efficiency but better brake specific fuel consumption for the new renewable fuels. Results from combustion show shorter ignition delays for most of the renewable (deoxygenated) fuels with the exception of fed batch deoxygenation of lauric acid. Combustion results also show lower peak in-cylinder pressures, reduced rate of increase in cylinder pressure, and lower heat release rates for the renewable fuels. Emission results show an increase in hydrocarbon emissions for renewable deoxygenated fuels, but a general decrease in all other emissions including NOx, greenhouse gases, and soot. Results also demonstrate that isomers of the alkanes resulting from the deoxygenation of the canola derived fatty acids could be a potential replacement to conventional fossil diesel and biodiesel based on the

  16. SPECIFIC FEATURES OF THE OXYFUEL COMBUSTION CONDITIONS IN A BUBBLING FLUIDIZED BED

    Directory of Open Access Journals (Sweden)

    Pavel Skopec

    2016-08-01

    Full Text Available Oxyfuel combustion is a promising approach for capturing CO2 from power plants. This technology produces a flue gas with a high concentration of CO2. Our paper presents a verification of the oxyfuel combustion conditions in a bubbling fluidized bed combustor. It presents a theoretical analysis of oxyfuel combustion and makes a comparison with combustion using air. It is important to establish a proper methodology for stoichiometric calculations and for computing the basic characteristic fluidization properties. The methodology presented here has been developed for general purposes, and can be applied to calculations for combustion with air and with oxygen-enriched air, and also for full oxyfuel conditions. With this methodology, we can include any water vapour condensation during recirculation of the flue gas when dry flue gas recirculation is used. The paper contains calculations for a lignite coal, which is taken as a reference fuel for future research and for the experiments.

  17. Co-combustion of anthracite coal and wood pellets: Thermodynamic analysis, combustion efficiency, pollutant emissions and ash slagging.

    Science.gov (United States)

    Guo, Feihong; Zhong, Zhaoping

    2018-08-01

    This work presents studies on the co-combustion of anthracite coal and wood pellets in fluidized bed. Prior to the fluidized bed combustion, thermogravimetric analysis are performed to investigate the thermodynamic behavior of coal and wood pellets. The results show that the thermal decomposition of blends is divided into four stages. The co-firing of coal and wood pellets can promote the combustion reaction and reduce the emission of gaseous pollutants, such as SO 2 and NO. It is important to choose the proportion of wood pellets during co-combustion due to the low combustion efficiency caused by large pellets with poor fluidization. Wood pellets can inhibit the volatilization of trace elements, especially for Cr, Ni and V. In addition, the slagging ratio of wood pellets ash is reduced by co-firing with coal. The research on combustion of coal and wood pellets is of great significance in engineering. Copyright © 2018 Elsevier Ltd. All rights reserved.

  18. Design of the steam generator in an energy conversion system based on the aluminum combustion with water

    International Nuclear Information System (INIS)

    Mercati, Stefano; Milani, Massimo; Montorsi, Luca; Paltrinieri, Fabrizio

    2012-01-01

    Highlights: ► Development of a numerical approach for the analysis of a co-generation system based on the aluminum water reaction. ► Construction of system operating maps for estimating the system behavior. ► Comparison of two different designs of the steam generator for the system. ► Definition of the operating range where each configuration provides the best performance. -- Abstract: The paper shows the preliminary design of the superheated steam generator to be used in a novel hydrogen production and energy conversion system based on the combustion of aluminum particles with water. The system is aimed at producing hydrogen and pressurized superheated steam, using the heat released by the Al–H 2 O reaction. The interest on this type of technology arises because of the possibility of obtaining hydrogen with very low pollutant and greenhouse gas emissions, compared to the traditional hydrogen production systems, such as the steam reforming from methane. The analysis of the combustion chamber and the heat recovery system is carried out by means of a lumped and distributed parameter numerical approach. The multi phase and gas mixture theoretical principles are used both to characterize the mass flow rate and the heat release in the combustion chamber and within the heat exchangers in order to relate the steam generator performance to the system operating parameters. Finally, the influence of the steam generator performance on the whole energy conversion system behavior is addressed, with particular care to the evaluation of the total power and efficiency variation with the combustion parameters.

  19. Combustion instability modeling and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States)] [and others

    1995-10-01

    It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. Clearly, the key to successful gas turbine development is based on understanding the effects of geometry and operating conditions on combustion instability, emissions (including UHC, CO and NO{sub x}) and performance. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors.

  20. Combustion

    CERN Document Server

    Glassman, Irvin

    1987-01-01

    Combustion, Second Edition focuses on the underlying principles of combustion and covers topics ranging from chemical thermodynamics and flame temperatures to chemical kinetics, detonation, ignition, and oxidation characteristics of fuels. Diffusion flames, flame phenomena in premixed combustible gases, and combustion of nonvolatile fuels are also discussed. This book consists of nine chapters and begins by introducing the reader to heats of reaction and formation, free energy and the equilibrium constants, and flame temperature calculations. The next chapter explores the rates of reactio

  1. Research Combustion Laboratory (RCL)

    Data.gov (United States)

    Federal Laboratory Consortium — The Research Combustion Laboratory (RCL) develops aerospace propulsion technology by performing tests on propulsion components and materials. Altitudes up to 137,000...

  2. Combustion instability modeling and analysis

    Energy Technology Data Exchange (ETDEWEB)

    Santoro, R.J.; Yang, V.; Santavicca, D.A. [Pennsylvania State Univ., University Park, PA (United States); Sheppard, E.J. [Tuskeggee Univ., Tuskegee, AL (United States). Dept. of Aerospace Engineering

    1995-12-31

    It is well known that the two key elements for achieving low emissions and high performance in a gas turbine combustor are to simultaneously establish (1) a lean combustion zone for maintaining low NO{sub x} emissions and (2) rapid mixing for good ignition and flame stability. However, these requirements, when coupled with the short combustor lengths used to limit the residence time for NO formation typical of advanced gas turbine combustors, can lead to problems regarding unburned hydrocarbons (UHC) and carbon monoxide (CO) emissions, as well as the occurrence of combustion instabilities. The concurrent development of suitable analytical and numerical models that are validated with experimental studies is important for achieving this objective. A major benefit of the present research will be to provide for the first time an experimentally verified model of emissions and performance of gas turbine combustors. The present study represents a coordinated effort between industry, government and academia to investigate gas turbine combustion dynamics. Specific study areas include development of advanced diagnostics, definition of controlling phenomena, advancement of analytical and numerical modeling capabilities, and assessment of the current status of our ability to apply these tools to practical gas turbine combustors. The present work involves four tasks which address, respectively, (1) the development of a fiber-optic probe for fuel-air ratio measurements, (2) the study of combustion instability using laser-based diagnostics in a high pressure, high temperature flow reactor, (3) the development of analytical and numerical modeling capabilities for describing combustion instability which will be validated against experimental data, and (4) the preparation of a literature survey and establishment of a data base on practical experience with combustion instability.

  3. A theoretical approach for energy saving in industrial steam boilers

    International Nuclear Information System (INIS)

    Sabry, T.I.; Mohamed, N.H.; Elghonimy, A.M.

    1993-01-01

    Optimization of the performance characteristics of such a steam boiler has been analyzed theoretically. Suitable thermodynamic relations have been utilized here to construct a computer model that would carry out the boiler performance characteristics at different operating parameters (e.g.; amount of excess air, fuel type, rate of blowdown preheating of combustion air and flow gases temperature). The results demonstrate that this computer model is to be used successfully in selecting the different operating parameters of the steam boiler at variant loads considering the best economical operation. Besides, this model can be used to investigate the sensitivity of the performance characteristics to the deviation of the boiler operating parameters from their optimum values. It was found also that changing the operating parameters beside the type of fuel in a boiler affects its performance characteristics. 3 figs

  4. SO2 emission reducing by Ca(OH)2 using at combustion of coal from East-Maritsa basin

    International Nuclear Information System (INIS)

    Batov, S.; Gadzhanov, P.; Popov, D.; Panchev, T.; Mikhajlov, Ya.; Shushulov, D.; Grozev, A.

    1997-01-01

    The 'Maritsa-Iztok' coal field contains about 65% of the lignite and 57% of the Bulgarian coal resources.The 'Maritsa-Iztok' lignite coal have a low combustion temperature and high concentration of ashes, moisture and sulfur. The concentration of sulphur oxides emitted is about 800 000 t per year, which is among the highest concentrations for Europe. In order to reduce the sulphur concentration, theoretical and experimental studies have been performed. A determination of the efficiency of some new methods for SO 2 reduction has been done. In this paper the results from experiments using Ca(OH) 2 as reagent, are presented. The experimental facility is a non-cooled combustion chamber which provides the same conditions as in the lignite coal boilers. In the experiments ground and dried lignite coal have been used. The controlled values are O 2 , CO, NO x , SO 2 , as well as the temperature of the hot and cold air and the combustion products after the cooler and absorber. Four different technologies have been performed. The first is adding of Ca(OH) 2 which give about 30% maximal SO 2 reducing for grain size 45μm and Ca/S=1.6. The obtaining of this small size is now difficult. The second technology is introduction of Ca(OH) 2 in the combustion chamber at a temperature 900-1050 o C. The cleaning efficiency is about 48.5% for the optimal concentration of the additive. As a washing of the combustion product with water in the absorber after the desulfurization. The second phase give 20% additional cleaning. Thus the total cleaning effect is 65-70%. The third method used lime washing of the combustion products. For the Bulgarian coal with a great S content it is the most suitable method. It gives a SO 2 cleaning up to 95%. Lime wash with pH=12.3 has been used with various amounts of the reagent. Experiments with different amounts of lime wash and different quality of the coal are performed and the specific reagent consumption has been determined

  5. 78 FR 54606 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2013-09-05

    ... Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines AGENCY... hazardous air pollutants for stationary reciprocating internal combustion engines and the standards of performance for stationary internal combustion engines. Subsequently, the EPA received three petitions for...

  6. Improved Modeling of Finite-Rate Turbulent Combustion Processes in Research Combustors

    Science.gov (United States)

    VanOverbeke, Thomas J.

    1998-01-01

    The objective of this thesis is to further develop and test a stochastic model of turbulent combustion in recirculating flows. There is a requirement to increase the accuracy of multi-dimensional combustion predictions. As turbulence affects reaction rates, this interaction must be more accurately evaluated. In this work a more physically correct way of handling the interaction of turbulence on combustion is further developed and tested. As turbulence involves randomness, stochastic modeling is used. Averaged values such as temperature and species concentration are found by integrating the probability density function (pdf) over the range of the scalar. The model in this work does not assume the pdf type, but solves for the evolution of the pdf using the Monte Carlo solution technique. The model is further developed by including a more robust reaction solver, by using accurate thermodynamics and by more accurate transport elements. The stochastic method is used with Semi-Implicit Method for Pressure-Linked Equations. The SIMPLE method is used to solve for velocity, pressure, turbulent kinetic energy and dissipation. The pdf solver solves for temperature and species concentration. Thus, the method is partially familiar to combustor engineers. The method is compared to benchmark experimental data and baseline calculations. The baseline method was tested on isothermal flows, evaporating sprays and combusting sprays. Pdf and baseline predictions were performed for three diffusion flames and one premixed flame. The pdf method predicted lower combustion rates than the baseline method in agreement with the data, except for the premixed flame. The baseline and stochastic predictions bounded the experimental data for the premixed flame. The use of a continuous mixing model or relax to mean mixing model had little effect on the prediction of average temperature. Two grids were used in a hydrogen diffusion flame simulation. Grid density did not effect the predictions except

  7. Pulsating combustion - Combustion characteristics and reduction of emissions

    Energy Technology Data Exchange (ETDEWEB)

    Lindholm, Annika

    1999-11-01

    In the search for high efficiency combustion systems pulsating combustion has been identified as one of the technologies that potentially can meet the objectives of clean combustion and good fuel economy. Pulsating combustion offers low emissions of pollutants, high heat transfer and efficient combustion. Although it is an old technology, the interest in pulsating combustion has been renewed in recent years, due to its unique features. Various applications of pulsating combustion can be found, mainly as drying and heating devices, of which the latter also have had commercial success. It is, however, in the design process of a pulse combustor, difficult to predict the operating frequency, the heat release etc., due to the lack of a well founded theory of the phenomenon. Research concerning control over the combustion process is essential for developing high efficiency pulse combustors with low emissions. Natural gas fired Helmholtz type pulse combustors have been the experimental objects of this study. In order to investigate the interaction between the fluid dynamics and the chemistry in pulse combustors, laser based measuring techniques as well as other conventional measuring techniques have been used. The experimental results shows the possibilities to control the combustion characteristics of pulsating combustion. It is shown that the time scales in the large vortices created at the inlet to the combustion chamber are very important for the operation of the pulse combustor. By increasing/decreasing the time scale for the large scale mixing the timing of the heat release is changed and the operating characteristics of the pulse combustor changes. Three different means for NO{sub x} reduction in Helmholtz type pulse combustors have been investigated. These include exhaust gas recirculation, alteration of air/fuel ratio and changed inlet geometry in the combustion chamber. All used methods achieved less than 10 ppm NO{sub x} emitted (referred to stoichiometric

  8. CFD analysis of premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber

    International Nuclear Information System (INIS)

    Gera, B.; Singh, R.K.; Vaze, K.K.

    2014-01-01

    Premixed hydrogen/air combustion in an upright, rectangular shaped combustion chamber has been performed numerically using commercial CFD code CFD-ACE+. The combustion chamber had dimensions 1 m X 0.024 m X 1 m. Simulations were carried out for 10% (v/v) hydrogen concentration for which experimental results were available. Effect of different boundary condition and ignition position on flame propagation was studied. Time dependent flame propagation in the chamber was predicted by CFD code. The computed transient flame propagation in the chamber was in good agreement with experimental results. The present work demonstrated that the available commercial CFD codes are capable of modeling hydrogen deflagration in a realistic manner. (author)

  9. Experimental investigation on the effect of intake air temperature and air-fuel ratio on cycle-to-cycle variations of HCCI combustion and performance parameters

    Energy Technology Data Exchange (ETDEWEB)

    Maurya, Rakesh Kumar; Agarwal, Avinash Kumar [Engine Research Laboratory, Department of Mechanical Engineering, Indian Institute of Technology Kanpur, Kanpur 208016 (India)

    2011-04-15

    Combustion in HCCI engines is a controlled auto ignition of well-mixed fuel, air and residual gas. Since onset of HCCI combustion depends on the auto ignition of fuel/air mixture, there is no direct control on the start of combustion process. Therefore, HCCI combustion becomes unstable rather easily, especially at lower and higher engine loads. In this study, cycle-to-cycle variations of a HCCI combustion engine fuelled with ethanol were investigated on a modified two-cylinder engine. Port injection technique is used for preparing homogeneous charge for HCCI combustion. The experiments were conducted at varying intake air temperatures and air-fuel ratios at constant engine speed of 1500 rpm and P-{theta} diagram of 100 consecutive combustion cycles for each test conditions at steady state operation were recorded. Consequently, cycle-to-cycle variations of the main combustion parameters and performance parameters were analyzed. To evaluate the cycle-to-cycle variations of HCCI combustion parameters, coefficient of variation (COV) of every parameter were calculated for every engine operating condition. The critical optimum parameters that can be used to define HCCI operating ranges are 'maximum rate of pressure rise' and 'COV of indicated mean effective pressure (IMEP)'. (author)

  10. Quasi-dimensional modeling of a fast-burn combustion dual-plug spark-ignition engine with complex combustion chamber geometries

    International Nuclear Information System (INIS)

    Altın, İsmail; Bilgin, Atilla

    2015-01-01

    This study builds on a previous parametric investigation using a thermodynamic-based quasi-dimensional (QD) cycle simulation of a spark-ignition (SI) engine with dual-spark plugs. The previous work examined the effects of plug-number and location on some performance parameters considering an engine with a simple cylindrical disc-shaped combustion chamber. In order to provide QD thermodynamic models applicable to complex combustion chamber geometries, a novel approach is considered here: flame-maps, which utilizes a computer aided design (CAD) software (SolidWorks). Flame maps are produced by the CAD software, which comprise all the possible flame radiuses with an increment of one-mm between them, according to the spark plug positions, spark timing, and piston position near the top dead center. The data are tabulated and stored as matrices. Then, these tabulated data are adapted to the previously reported cycle simulation. After testing for simple disc-shaped chamber geometries, the simulation is applied to a real production automobile (Honda-Fit) engine to perform the parametric study. - Highlights: • QD model was applied in dual plug engine with complex realistic combustion chamber. • This method successfully modeled the combustion in the dual-plug Honda-Fit engine. • The same combustion chamber is tested for various spark plug(s) locations. • The centrally located single spark-plug results in the fastest combustion

  11. Development and validation of a multi-zone combustion model for performance and nitric oxide formation in syngas fueled spark ignition engine

    International Nuclear Information System (INIS)

    Rakopoulos, C.D.; Michos, C.N.

    2008-01-01

    The development of a zero-dimensional, multi-zone combustion model is presented for predicting the performance and nitric oxide (NO) emissions of a spark ignition (SI) engine. The model is validated against experimental data from a multi-cylinder, four-stroke, turbocharged and aftercooled, SI gas engine running with syngas fuel. This alternative fuel, the combustible part of which consists mainly of CO and H 2 with the rest containing non-combustible gases, has been recently identified as a promising substitute of fossil fuels in view of environmentally friendly engine operation. The basic concept of the model is the division of the burned gas into several distinct zones, unlike the simpler two-zone models, for taking into account the temperature stratification of the burned mixture during combustion. This is especially important for accurate NO emissions predictions, since NO formation is strongly temperature dependent. The multi-zone formulation provides the chemical species concentrations gradient existing in the burned zones, as well as the relative contribution of each burned zone to the total in-cylinder NO formation. The burning rate required as input to the model is expressed as a Wiebe function, fitted to experimentally derived burn rates. All model's constants are calibrated at one operating point and then kept unchanged. Zone-resolved combustion related information is obtained, assisting in the understanding of the complex phenomena occurring during combustion in SI engines. Combustion characteristics of the lean-burn gas engine tested are provided for the complete load range, aiding the interpretation of its performance and knocking tendency. Computed NO emissions from the multi-zone model for various values of the engine load (i.e. air-fuel ratios) are presented and found to be in good agreement with the respective experimental ones, providing confidence for the predictive capability of the model. The superiority of the multi-zone model over its two

  12. Establishment of Combustion Model for Isooctane HCCI Marine Diesel Engine and Research on the Combustion Characteristic

    Directory of Open Access Journals (Sweden)

    Li Biao

    2016-01-01

    Full Text Available The homogeneous charge compression ignition (HCCI combustion mode applied in marine diesel engine is expected to be one of alternative technologies to decrease nitrogen oxide (NOX emission and improve energy utilization rate. Applying the chemical-looping combustion (CLC mechanism inside the cylinder, a numerical study on the HCCI combustion process is performed taking a marine diesel engine as application object. The characteristic feature of combustion process is displayed. On this basis, the formation and emission of NOX are analyzed and discussed. The results indicate that the HCCI combustion mode always exhibit two combustion releasing heats: low-temperature reaction and high-temperature reaction. The combustion phase is divided into low-temperature reaction zone, high-temperature reaction zone and negative temperature coefficient (NTC zone. The operating conditions of the high compression ratio, high intake air temperature, low inlet pressure and small excess air coefficient would cause the high in-cylinder pressure which often leads engine detonation. The low compression ratio, low intake air temperature and big excess air coefficient would cause the low combustor temperature which is conducive to reduce NOX emissions. These technological means and operating conditions are expected to meet the NOX emissions limits in MARPOL73/78 Convention-Annex VI Amendment.

  13. Theoretical Energy Release of Thermites, Intermetallics, and Combustible Metals

    Energy Technology Data Exchange (ETDEWEB)

    Fischer, S.H.; Grubelich, M.C.

    1999-05-14

    Thermite mixtures, intermetallic reactants, and metal fuels have long been used in pyrotechnic applications. Advantages of these systems typically include high energy density, high combustion temperature, and a wide range of gas production. They generally exhibit high temperature stability and possess insensitive ignition properties. For the specific applications of humanitarian demining and disposal of unexploded ordnance, these pyrotechnic formulations offer additional benefits. The combination of high thermal input with low brisance can be used to neutralize the energetic materials in mines and other ordnance without the "explosive" high-blast-pressure events that can cause extensive collateral damage to personnel, facilities, and the environment. In this paper, we review the applications, benefits, and characteristics of thermite mixtures, intermetallic reactants, and metal fuels. Calculated values for reactant density, heat of reaction (per unit mass and per unit volume), and reaction temperature (without and with consideration of phase changes and the variation of specific heat values) are tabulated. These data are ranked in several ways, according to density, heat of reaction, reaction temperature, and gas production.

  14. Novel approaches in advanced combustion characterization of fuels for advanced pressurized combustion

    Energy Technology Data Exchange (ETDEWEB)

    Aho, M.; Haemaelaeinen, J. [VTT Energy (Finland); Joutsenoja, T. [Tampere Univ. of Technology (Finland)

    1996-12-01

    This project is a part of the EU Joule 2 (extension) programme. The objective of the research of Technical Research Centre of Finland (VTT) is to produce experimental results of the effects of pressure and other important parameters on the combustion of pulverized coals and their char derivates. The results can be utilized in modelling of pressurized combustion and in planning pilot-scale reactors. The coals to be studied are Polish hvb coal, French lignite (Gardanne), German anthracite (Niederberg) and German (Goettelbom) hvb coal. The samples are combusted in an electrically heated, pressurized entrained flow reactor (PEFR), where the experimental conditions are controlled with a high precision. The particle size of the fuel can vary between 100 and 300 {mu}m. The studied things are combustion rates, temperatures and sizes of burning single coal and char particles. The latter measurements are performed with a method developed by Tampere University of Technology, Finland. In some of the experiments, mass loss and elemental composition of the char residue are studied in more details as the function of time to find out the combustion mechanism. Combustion rate of pulverized (140-180 {mu}m) Gardanne lignite and Niederberg anthracite were measured and compared with the data obtained earlier with Polish hvb coal at various pressures, gas temperatures, oxygen partial pressures and partial pressures of carbon dioxide in the second working period. In addition, particle temperatures were measured with anthracite. The experimental results were treated with multivariable partial least squares (PLS) method to find regression equation between the measured things and the experimental variables. (author)

  15. Application of pulse combustion technology in spray drying process

    Directory of Open Access Journals (Sweden)

    I. Zbicinski

    2000-12-01

    Full Text Available The paper presents development of valved pulse combustor designed for application in drying process and drying tests performed in a specially built installation. Laser technique was applied to investigate the flow field and structure of dispersed phase during pulse combustion spray drying process. PDA technique was used to determine initial atomization parameters as well as particle size distribution, velocity of the particles, mass concentration of liquid phase in the cross section of spray stream, etc., in the drying chamber during drying tests. Water was used to estimate the level of evaporation and 5 and 10% solutions of sodium chloride to carry out drying tests. The Computational Fluid Dynamics technique was used to perform theoretical predictions of time-dependent velocity, temperature distribution and particle trajectories in the drying chamber. Satisfactory agreement between calculations and experimental results was found in certain regions of the drying chamber.

  16. Numerical investigation of biogas flameless combustion

    International Nuclear Information System (INIS)

    Hosseini, Seyed Ehsan; Bagheri, Ghobad; Wahid, Mazlan Abdul

    2014-01-01

    Highlights: • Fuel consumption decreases from 3.24 g/s in biogas conventional combustion to 1.07 g/s in flameless mode. • The differences between reactants and products temperature intensifies irreversibility in traditional combustion. • The temperature inside the chamber is uniform in biogas flameless mode and exergy loss decreases in this technique. • Low O 2 concentration in the flameless mode confirms a complete and quick combustion process in flameless regime. - Abstract: The purpose of this investigation is to analyze combustion characteristics of biogas flameless mode based on clean technology development strategies. A three dimensional (3D) computational fluid dynamic (CFD) study has been performed to illustrate various priorities of biogas flameless combustion compared to the conventional mode. The effects of preheated temperature and wall temperature, reaction zone and pollutant formation are observed and the impacts of combustion and turbulence models on numerical results are discussed. Although preheated conventional combustion could be effective in terms of fuel consumption reduction, NO x formation increases. It has been found that biogas is not eligible to be applied in furnace heat up due to its low calorific value (LCV) and it is necessary to utilize a high calorific value fuel to preheat the furnace. The required enthalpy for biogas auto-ignition temperature is supplied by enthalpy of preheated oxidizer. In biogas flameless combustion, the mean temperature of the furnace is lower than traditional combustion throughout the chamber. Compared to the biogas flameless combustion with uniform temperature, very high and fluctuated temperatures are recorded in conventional combustion. Since high entropy generation intensifies irreversibility, exergy loss is higher in biogas conventional combustion compared to the biogas flameless regime. Entropy generation minimization in flameless mode is attributed to the uniform temperature inside the chamber

  17. Sorbent control of trace metals in sewage sludge combustion and incineration

    Science.gov (United States)

    Naruse, I.; Yao, H.; Mkilaha, I. S. N.

    2003-05-01

    Coal and wastes combustion have become an important issue not only in terms of energy generation but also environmental conservation. The need for alternative fuels and wastes management has made the two energy sources of importance. However, the utilization of the two is faced with problems of impurity trace metals in the fuel. These metals usually speciate during combustion or incineration leading to generation of fumes and subsequently particles. This paper reports on the study aimed at understanding the speciation of trace metals and their emission from combustion systems as particulates. Experiments carried out using a down-flow furnace and theoretical study carried out using lead, chromium and cadmium as basic metals had shown that their speciation and subsequent emission is controlled by both chemical composition and physical properties of the fuel. The physical and chemical and physical properties of the fuel and their respective compounds and the operating conditions of the incineration and combustion system control the enrichment of the particles with trace metals.

  18. TOPICAL REVIEW: Plasma assisted ignition and combustion

    Science.gov (United States)

    Starikovskaia, S. M.

    2006-08-01

    In recent decades particular interest in applications of nonequilibrium plasma for the problems of plasma-assisted ignition and plasma-assisted combustion has been observed. A great amount of experimental data has been accumulated during this period which provided the grounds for using low temperature plasma of nonequilibrium gas discharges for a number of applications at conditions of high speed flows and also at conditions similar to automotive engines. The paper is aimed at reviewing the data obtained and discusses their treatment. Basic possibilities of low temperature plasma to ignite gas mixtures are evaluated and historical references highlighting pioneering works in the area are presented. The first part of the review discusses plasmas applied to plasma-assisted ignition and combustion. The paper pays special attention to experimental and theoretical analysis of some plasma parameters, such as reduced electric field, electron density and energy branching for different gas discharges. Streamers, pulsed nanosecond discharges, dielectric barrier discharges, radio frequency discharges and atmospheric pressure glow discharges are considered. The second part depicts applications of discharges to reduce the ignition delay time of combustible mixtures, to ignite transonic and supersonic flows, to intensify ignition and to sustain combustion of lean mixtures. The results obtained by different authors are cited, and ways of numerical modelling are discussed. Finally, the paper draws some conclusions on the main achievements and prospects of future investigations in the field.

  19. Combustion stratification study of partially premixed combustion using Fourier transform analysis of OH* chemiluminescence images

    KAUST Repository

    Izadi Najafabadi, Mohammad

    2017-11-06

    A relatively high level of stratification (qualitatively: lack of homogeneity) is one of the main advantages of partially premixed combustion over the homogeneous charge compression ignition concept. Stratification can smooth the heat release rate and improve the controllability of combustion. In order to compare stratification levels of different partially premixed combustion strategies or other combustion concepts, an objective and meaningful definition of “stratification level” is required. Such a definition is currently lacking; qualitative/quantitative definitions in the literature cannot properly distinguish various levels of stratification. The main purpose of this study is to objectively define combustion stratification (not to be confused with fuel stratification) based on high-speed OH* chemiluminescence imaging, which is assumed to provide spatial information regarding heat release. Stratification essentially being equivalent to spatial structure, we base our definition on two-dimensional Fourier transforms of photographs of OH* chemiluminescence. A light-duty optical diesel engine has been used to perform the OH* bandpass imaging on. Four experimental points are evaluated, with injection timings in the homogeneous regime as well as in the stratified partially premixed combustion regime. Two-dimensional Fourier transforms translate these chemiluminescence images into a range of spatial frequencies. The frequency information is used to define combustion stratification, using a novel normalization procedure. The results indicate that this new definition, based on Fourier analysis of OH* bandpass images, overcomes the drawbacks of previous definitions used in the literature and is a promising method to compare the level of combustion stratification between different experiments.

  20. Thermodynamic performance evaluation of combustion gas turbine cogeneration system with reheat

    International Nuclear Information System (INIS)

    Khaliq, A.; Kaushik, S.C.

    2004-01-01

    This communication presents thermodynamic methodology for the performance evaluation of combustion gas turbine cogeneration system with reheat. The energetic and exergetic efficiencies have been defined. The effects of process steam pressure and pinch point temperature used in the design of heat recovery steam generator, and reheat on energetic and exergetic efficiencies have been investigated. From the results obtained in graphs it is observed that the power to heat ratio increases with an increase in pinch point, but the first-law efficiency and second-law efficiency decreases with an increase in pinch point. The power to heat ratio and second-law efficiency increases significantly with increase in process steam pressure, but the first-law efficiency decreases with the same. Results also show that inclusion of reheat, provide significant improvement in electrical power output, process heat production, fuel-utilization (energetic) efficiency and second-law (exergetic) efficiency. This methodology may be quite useful in the selection and comparison of combined energy production systems from thermodynamic performance point of view

  1. Miniaturization limitations of rotary internal combustion engines

    International Nuclear Information System (INIS)

    Wang, Wei; Zuo, Zhengxing; Liu, Jinxiang

    2016-01-01

    Highlights: • Developed a phenomenological model for rotary internal combustion engines. • Presented scaling laws for the performance of micro rotary engines. • Adiabatic walls can improve the cycle efficiency but result in higher charge leakage. • A lower compression ratio can increase the efficiency due to lower mass losses. • Presented possible minimum engine size of rotary internal combustion engines. - Abstract: With the rapid development of micro electro-mechanical devices, the demands for micro power generation systems have significantly increased in recent years. Traditional chemical batteries have energy densities much lower than hydrocarbon fuels, which makes internal-combustion-engine an attractive technological alternative to batteries. Micro rotary internal combustion engine has drawn great attractions due to its planar design, which is well-suited for fabrication in MEMS. In this paper, a phenomenological model considering heat transfer and mass leakage has been developed to investigate effects of engine speed, compression ratio, blow-by and heat transfer on the performance of micro rotary engine, which provide the guidelines for preliminary design of rotary engine. The lower possible miniaturization limits of rotary combustion engines are proposed.

  2. Assessment of Literature Related to Combustion Appliance Venting Systems

    Energy Technology Data Exchange (ETDEWEB)

    Rapp, V. H.; Less, B. D.; Singer, B. C.; Stratton, J. C.; Wray, C. P.

    2015-02-01

    In many residential building retrofit programs, air tightening to increase energy efficiency is often constrained by safety concerns with naturally vented combustion appliances. Tighter residential buildings more readily depressurize when exhaust equipment is operated, making combustion appliances more prone to backdraft or spill combustion exhaust into the living space. Several measures, such as installation guidelines, vent sizing codes, and combustion safety diagnostics, are in place with the intent to prevent backdrafting and combustion spillage, but the diagnostics conflict and the risk mitigation objective is inconsistent. This literature review summarizes the metrics and diagnostics used to assess combustion safety, documents their technical basis, and investigates their risk mitigations. It compiles information from the following: codes for combustion appliance venting and installation; standards and guidelines for combustion safety diagnostics; research evaluating combustion safety diagnostics; research investigating wind effects on building depressurization and venting; and software for simulating vent system performance.

  3. Combustible structural composites and methods of forming combustible structural composites

    Science.gov (United States)

    Daniels, Michael A.; Heaps, Ronald J.; Steffler, Eric D.; Swank, W. David

    2013-04-02

    Combustible structural composites and methods of forming same are disclosed. In an embodiment, a combustible structural composite includes combustible material comprising a fuel metal and a metal oxide. The fuel metal is present in the combustible material at a weight ratio from 1:9 to 1:1 of the fuel metal to the metal oxide. The fuel metal and the metal oxide are capable of exothermically reacting upon application of energy at or above a threshold value to support self-sustaining combustion of the combustible material within the combustible structural composite. Structural-reinforcing fibers are present in the composite at a weight ratio from 1:20 to 10:1 of the structural-reinforcing fibers to the combustible material. Other embodiments and aspects are disclosed.

  4. Performance, emission and combustion analysis of a compression ignition engine using biofuel blends

    Directory of Open Access Journals (Sweden)

    Ors Ilker

    2017-01-01

    Full Text Available This study aimed to investigate the effects on performance, emission, and combustion characteristics of adding biodiesel and bioethanol to diesel fuel. Diesel fuel and blend fuels were tested in a water-cooled compression ignition engine with direct injection. Test results showed that brake specific fuel consumption and volumetric efficiency increased by about 30.6% and 3.7%, respectively, with the addition of bioethanol to binary blend fuels. The results of the blend fuel’s combustion analysis were similar to the diesel fuel’s results. Bioethanol increased maximal in-cylinder pressure compared to biodiesel and diesel fuel at both 1400 rpm and 2800 rpm. Emissions of CO increased by an amount of about 80% for fuels containing a high level of bioethanol when compared to CO emissions for diesel fuel. Using biodiesel, NO emissions increased by an average of 31.3%, HC emissions decreased by an average of 39.25%, and smoke opacity decreased by an average of 6.5% when compared with diesel fuel. In addition, when using bioethanol, NO emissions and smoke opacity decreased by 55% and 17% on average, respectively, and HC emissions increased by an average of 53% compared with diesel fuel.

  5. Performance and combustion analysis of Mahua biodiesel on a single cylinder compression ignition engine using electronic fuel injection system

    Directory of Open Access Journals (Sweden)

    Gunasekaran Anandkumar

    2016-01-01

    Full Text Available In this investigation, experiment is carried out on a 1500 rpm constant speed single cylinder Diesel engine. The test is carried out with Neat diesel, neat biodiesel, and blend B20. The engine considered was run with electronic fuel injection system supported by common rail direct injection to obtain high atomization and effective air utilization inside the combustion chamber. The performance of the engine in terms of break thermal efficiency and brake specific energy consumption was found and compared. The B20 blend shows 1.11% decrease in break thermal efficiency and 3.35% increase in brake specific energy consumption than diesel. The combustion characteristics found are in-cylinder pressure, rate of pressure rise, and heat release rate and compared for peak pressure load to understand the nature of combustion process. For each fuel test run, the maximum peak pressure is observed at part load condition. The rate of change of pressure and heat release rate of diesel is high compared to pure biodiesel and B20 blend. The diffusion combustion is observed to be predominant in case of B100 than B20 and Neat diesel.

  6. On the Experimental and Theoretical Investigations of Lean Partially Premixed Combustion, Burning Speed, Flame Instability and Plasma Formation of Alternative Fuels at High Temperatures and Pressures

    Science.gov (United States)

    Askari, Omid

    This dissertation investigates the combustion and injection fundamental characteristics of different alternative fuels both experimentally and theoretically. The subjects such as lean partially premixed combustion of methane/hydrogen/air/diluent, methane high pressure direct-injection, thermal plasma formation, thermodynamic properties of hydrocarbon/air mixtures at high temperatures, laminar flames and flame morphology of synthetic gas (syngas) and Gas-to-Liquid (GTL) fuels were extensively studied in this work. These subjects will be summarized in three following paragraphs. The fundamentals of spray and partially premixed combustion characteristics of directly injected methane in a constant volume combustion chamber have been experimentally studied. The injected fuel jet generates turbulence in the vessel and forms a turbulent heterogeneous fuel-air mixture in the vessel, similar to that in a Compressed Natural Gas (CNG) Direct-Injection (DI) engines. The effect of different characteristics parameters such as spark delay time, stratification ratio, turbulence intensity, fuel injection pressure, chamber pressure, chamber temperature, Exhaust Gas recirculation (EGR) addition, hydrogen addition and equivalence ratio on flame propagation and emission concentrations were analyzed. As a part of this work and for the purpose of control and calibration of high pressure injector, spray development and characteristics including spray tip penetration, spray cone angle and overall equivalence ratio were evaluated under a wide range of fuel injection pressures of 30 to 90 atm and different chamber pressures of 1 to 5 atm. Thermodynamic properties of hydrocarbon/air plasma mixtures at ultra-high temperatures must be precisely calculated due to important influence on the flame kernel formation and propagation in combusting flows and spark discharge applications. A new algorithm based on the statistical thermodynamics was developed to calculate the ultra-high temperature plasma

  7. Gas pollutants from detonation and combustion of industrial explosives

    Energy Technology Data Exchange (ETDEWEB)

    Campos, J.; Pines, A.; Gois, J.C.; Portugal, A. (University of Coimbra, Coimbra (Portugal). Mechanical Engineering Dept.)

    1993-01-01

    The potential hazards of fumes, from blasting operations in underground mines, have long been recognised. Beyond this normal use of explosives, there are also large amounts of energy substances which cannot be used because their life time is outdated or they are not within the minimal quality requirements. There is a lack of information concerning tests, procedures and theoretical predictions of pollutant concentrations in fumes from detonation and combustion operations with industrial explosives. The most common industrial explosives in Portugal are ammonium nitrate-fuel oil compositions (anfo), and dynamite. Recently, ammonium nitrate based emulsion explosives are more and more used in industrial applications. This paper presents the structure and fundamental thermodynamic equations of THOR computer code to calculate the combustion and detonation products (CO[sub 2], CO, H[sub 2]O, N[sub 2], O[sub 2], H[sub 2], OH, NO, H, N, O, HCN, NH[sub 3], NO[sub 2], N[sub 2]O, CH[sub 4] gases and two kinds of solid carbon - graphite and diamond) for the minimum value of Gibbs free energy, using three well known equations of state - BKW, H9 and H12. Detonation experiments are described and gas analysis discussed. Measured pollutants concentrations (CO, CO[sub 2], NO and NO[sub 2]), as a function of volume of explosion chamber, prove the dependence of expansion mechanisms on CO and NO formation and recombination and validate theoretical predictions. Incineration of explosives in a fluidised bed is described. Products composition from isobare adiabatic combustion of selected explosives has been calculated and correlated with previous calculations for a detonation regime. The obtained results demonstrate the possibility of predicting gas composition of detonation and combustion products of industrial explosives. 22 refs., 14 figs., 1 tab.

  8. Investigation of pressurized combustion and characterization of solid fuels

    Energy Technology Data Exchange (ETDEWEB)

    Aho, M; Haemaelaeinen, J; Paakkinen, K [VTT Energy, Espoo (Finland); Joutsenoja, T [Tampere Univ. of Technology (Finland)

    1997-10-01

    The objective of the research of Technical Research Centre of Finland (VTT) was to produce results of the effects of pressure and other important parameters on the combustion of pulverized coals using both experimental and theoretical methods. The results can be utilized to model pressurized combustion and to plan pilot-scale reactors. The studied coals were Polish hvb coal, French lignite (Gardanne), German anthracite (Niederberg) and German (Goettelborn) hvb coal. In was originally planned to study also a char of one of these coals. However, anthracite was selected instead of char, because the theoretical studies predicted maximum pressure effect to be found for antracite-type coals (with low reactivity and low content of volatiles). The pulverized coal samples were combusted in an electrically heated, pressurized entrained flow reactor (PEFR), where the experimental conditions were controlled with a high precision. The studied particle size fractions were 100-125 Em and 140-180 Am for anthracite and 140-180 {mu}m for the other coals. The studied things were combustion rates and temperatures of burning particles. Two types of sets of experiments were carried out. In the first case, experimental planning was done and the results were handled with multivariable partial least squares (PLS) method. Gas temperature varied from 1073K to 1473K and pressure from 0.2 MPa to 0.8 MPa. The other variables were PO2 and PCO{sub 2}. Some of the experiments were carried out at conditions prevailing during flue gas recirculation (CO{sub 2} concentration was > 20 vol%). In the second case, oxygen concentration was kept constant ( 10 vol%) and pressure was varied from 0.2 MPa to 0.8 MPa with an interval of 0.1 MPa

  9. Effect of co-combustion on the burnout of lignite/biomass blends: a Turkish case study.

    Science.gov (United States)

    Haykiri-Acma, H; Yaman, S

    2008-11-01

    Co-combustion of Turkish Elbistan lignite and woody shells of hazelnut was performed in a TGA up to 1173 K with a heating rate of 20 K/min. SEM images of each fuel revealed the differences in their physical appearances. Hazelnut shell was blended with lignite in the range of 2-20 wt% to observe the co-combustion properties. Maximum burning rates (Rmax), temperatures of the maximum burning rates (T(R-max)), and the final burnout values of the parent samples and the blends were compared. The results were interpreted considering lignite properties and the major biomass ingredients such as cellulosics, hemicellulosics, and lignin. Deviations between the theoretical and experimental burnout values were evaluated at various temperatures. Burnout characteristics of the blends up to 10 wt% were concluded to have a synergistic effect so the addition of hazelnut shell up to 8 wt% provided higher burnouts than the expected theoretical ones, whereas addition of as much as 10 wt% led to a decrease in the burnout. However, the additive effects were more favorable for the blend having a biomass content of 20 wt%. Apparent activation energy, Rmax, and T(R-max), were found to follow the additive behavior for the blend samples.

  10. Effect of co-combustion on the burnout of lignite/biomass blends: A Turkish case study

    Energy Technology Data Exchange (ETDEWEB)

    Haykirl-Acma, H.; Yaman, S. [Istanbul Technical University, Istanbul (Turkey)

    2008-11-15

    Co-combustion of Turkish Elbistan lignite and woody shells of hazelnut was performed in a TGA tip to 1173 K with a heating rate of 20 K/min. SEM images of each fuel revealed the differences in their physical appearances. Hazelnut shell was blended with lignite in the range of 2-20 wt% to observe the co-combustion properties. Maximum burning rates (R{sub max}), temperatures of the maximum burning rates (TR{sub max}), and the final burnout values of the parent samples and the blends were compared. The results were interpreted considering lignite properties and the major biomass ingredients such as cellulosics, hemicellulosics, and lignin. Deviations between the theoretical and experimental burnout values were evaluated at various temperatures. Burnout characteristics of the blends up to 10 wt% were concluded to have a synergistic effect so the addition of hazelnut shell up to 8 wt% provided higher burnouts than the expected theoretical ones, whereas addition of as much as 10 wt% led to a decrease in the burnout. However, the additive effects were more favorable for the blend having a biomass content of 20 wt%. Apparent activation energy, R{sub max} and TR{sub max}, were found to follow the additive behavior for the blend samples.

  11. Comparison of Combustion properties of simulated biogas and methane

    International Nuclear Information System (INIS)

    Diaz Gonzalez, Carlos; Arrieta, Andres Amell; Suarez, Jose Luis

    2009-01-01

    The utilization of new renewable energy sources has been of special interest during the past years, seeking to decrease our dependence on fossil fuels and the corresponding environmental impact derived from their use. The combustion properties of a simulated gas composed of 60% methane and 40% carbon dioxide in volume are determined in this paper by means of calculation algorithms developed by the GASURE team, comparing them to pure methane properties. Furthermore, the effect of these properties on premixed flame characteristic phenomena is demonstrated. These properties were determined by theoretical estimations. The characteristic phenomena (laminar deflagration velocity, flame structure, radiation pattern) are determined experimentally. Results show a high effect of carbon dioxide in the combustion properties and characteristic parameters of a biogas premixed flame such as laminar deflagration velocity, flame structure and gas-methane exchangeability problems. The difference regarding flame structure and combustion properties lead to a difference in radiation pattern of the gases studied.

  12. Comparison of combustion properties of simulated biogas and methane

    International Nuclear Information System (INIS)

    Diaz G, Carlos; Amell, Andres; Suarez, Jose

    2010-01-01

    The utilization of new renewable energy sources has been of special interest during the past years, seeking to decrease our dependence on fossil fuels and the corresponding environmental impact derived from their use. The combustion properties of a simulated gas composed of 60% methane and 40% carbon dioxide in volume are determined in this paper by means of calculation algorithms developed by the GASURE team, comparing them to pure methane properties. Furthermore, the effect of these properties on premixed flame characteristic phenomena is demonstrated. These properties were determined by theoretical estimations. The characteristic phenomena (laminar deflagration velocity, flame structure, radiation pattern) are determined experimentally. Results show a high effect of carbon dioxide in the combustion properties and characteristic parameters of a biogas premixed flame such as laminar deflagration velocity, flame structure and gas-methane exchangeability problems. The difference regarding flame structure and combustion properties lead to a difference in radiation pattern of the gases studied.

  13. Theoretical Model for the Performance of Liquid Ring Pump Based on the Actual Operating Cycle

    Directory of Open Access Journals (Sweden)

    Si Huang

    2017-01-01

    Full Text Available Liquid ring pump is widely applied in many industry fields due to the advantages of isothermal compression process, simple structure, and liquid-sealing. Based on the actual operating cycle of “suction-compression-discharge-expansion,” a universal theoretical model for performance of liquid ring pump was established in this study, to solve the problem that the theoretical models deviated from the actual performance in operating cycle. With the major geometric parameters and operating conditions of a liquid ring pump, the performance parameters such as the actual capacity for suction and discharge, shaft power, and global efficiency can be conveniently predicted by the proposed theoretical model, without the limitation of empiric range, performance data, or the detailed 3D geometry of pumps. The proposed theoretical model was verified by experimental performances of liquid ring pumps and could provide a feasible tool for the application of liquid ring pump.

  14. Computational/experimental studies of isolated, single component droplet combustion

    Science.gov (United States)

    Dryer, Frederick L.

    1993-01-01

    Isolated droplet combustion processes have been the subject of extensive experimental and theoretical investigations for nearly 40 years. The gross features of droplet burning are qualitatively embodied by simple theories and are relatively well understood. However, there remain significant aspects of droplet burning, particularly its dynamics, for which additional basic knowledge is needed for thorough interpretations and quantitative explanations of transient phenomena. Spherically-symmetric droplet combustion, which can only be approximated under conditions of both low Reynolds and Grashof numbers, represents the simplest geometrical configuration in which to study the coupled chemical/transport processes inherent within non-premixed flames. The research summarized here, concerns recent results on isolated, single component, droplet combustion under microgravity conditions, a program pursued jointly with F.A. Williams of the University of California, San Diego. The overall program involves developing and applying experimental methods to study the burning of isolated, single component droplets, in various atmospheres, primarily at atmospheric pressure and below, in both drop towers and aboard space-based platforms such as the Space Shuttle or Space Station. Both computational methods and asymptotic methods, the latter pursued mainly at UCSD, are used in developing the experimental test matrix, in analyzing results, and for extending theoretical understanding. Methanol, and the normal alkanes, n-heptane, and n-decane, have been selected as test fuels to study time-dependent droplet burning phenomena. The following sections summarizes the Princeton efforts on this program, describe work in progress, and briefly delineate future research directions.

  15. Combustion of alternative fuels in vortex trapped combustor

    International Nuclear Information System (INIS)

    Ghenai, Chaouki; Zbeeb, Khaled; Janajreh, Isam

    2013-01-01

    Highlights: ► We model the combustion of alternative fuels in trapped vortex combustor (TVC). ► We test syngas and hydrogen/hydrocarbon mixture fuels. ► We examine the change in combustion performance and emissions of TVC combustor. ► Increasing the hydrogen content of the fuel will increase the temperature and NO x emissions. ► A high combustor efficiency is obtained for fuels with different compositions and LHV. - Abstract: Trapped vortex combustor represents an efficient and compact combustor for flame stability. Combustion stability is achieved through the use of cavities in which recirculation zones of hot products generated by the direct injection of fuel and air are created and acting as a continuous source of ignition for the incoming main fuel–air stream. Computational Fluid Dynamics analysis was performed in this study to test the combustion performance and emissions from the vortex trapped combustor when natural gas fuel (methane) is replaced with renewable and alternative fuels such as hydrogen and synthetic gas (syngas). The flame temperature, the flow field, and species concentrations inside the Vortex Trapped Combustor were obtained. The results show that hydrogen enriched hydrocarbon fuels combustion will result in more energy, higher temperature (14% increase when methane is replaced with hydrogen fuels) and NO x emissions, and lower CO 2 emissions (50% decrease when methane is replaced with methane/hydrogen mixture with 75% hydrogen fraction). The NO x emission increases when the fraction of hydrogen increases for methane/hydrogen fuel mixture. The results also show that the flame for methane combustion fuel is located in the primary vortex region but it is shifted to the secondary vortex region for hydrogen combustion.

  16. Preliminary results on performance testing of a turbocharged rotary combustion engine

    Science.gov (United States)

    Meng, P. R.; Rice, W. J.; Schock, H. J.; Pringle, D. P.

    1982-01-01

    The performance of a turbocharged rotary engine at power levels above 75 kW (100 hp) was studied. A twin rotor turbocharged Mazda engine was tested at speeds of 3000 to 6000 rpm and boost pressures to 7 psi. The NASA developed combustion diagnostic instrumentation was used to quantify indicated and pumping mean effect pressures, peak pressure, and face to face variability on a cycle by cycle basis. Results of this testing showed that a 5900 rpm a 36 percent increase in power was obtained by operating the engine in the turbocharged configuration. When operating with lean carburetor jets at 105 hp (78.3 kW) and 4000 rpm, a brake specific fuel consumption of 0.45 lbm/lb-hr was measured.

  17. Thermodynamic calculation and an experimental study of the combustion synthesis of (Mo{sub 1−x}Nb{sub x})Si{sub 2} (0 ⩽ x ⩽ 1)

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Xiaohong, E-mail: matinbow@163.com; Lu, Qiong; Wu, Guangzhi; Shi, Jialing; Sun, Zhi

    2015-08-25

    Highlights: • (Mo{sub 1−x}Nb{sub x})Si{sub 2} alloys were synthesized by a simple and energy-saving process of SHS. • Theoretical adiabatic temperature of (Mo{sub 1−x}Nb{sub x})Si{sub 2} was calculated for the first time. • The variation of the actual temperature is consistent with theoretical temperature. - Abstract: The theoretical adiabatic temperature of (Mo{sub 1−x}Nb{sub x})Si{sub 2} (0 ⩽ x ⩽ 1) is calculated. The results indicate that the theoretical adiabatic temperature of (Mo{sub 1−x}Nb{sub x})Si{sub 2} increases with an increasing Nb content when (Mo{sub 1−x}Nb{sub x})Si{sub 2} is of a single-phase structure, but decreases with an increasing Nb content when (Mo{sub 1−x}Nb{sub x})Si{sub 2} is of a double-phase structure. All of the temperatures are higher than 1800 K, indicating that (Mo{sub 1−x}Nb{sub x})Si{sub 2} (0 ⩽ x ⩽ 1) can be prepared by the combustion synthesis method. In this work, (Mo{sub 1−x}Nb{sub x})Si{sub 2} (0 ⩽ x ⩽ 1) alloys are successfully synthesized by the combustion synthesis process from elemental powders of Mo, Nb, and Si. The highest combustion temperature and combustion product structure are studied. The results confirm that the variation of the experimental maximum combustion temperature of (Mo{sub 1−x}Nb{sub x})Si{sub 2} is consistent with that of the theoretical adiabatic temperature. The combustion products are non-equilibrium species, and a supersaturated solid solution of C11{sub b} type (Mo{sub 1−x}Nb{sub x})Si{sub 2} forms during combustion synthesis.

  18. Improving of diesel combustion-pollution-fuel economy and performance by gasoline fumigation

    International Nuclear Information System (INIS)

    Şahin, Zehra; Durgun, Orhan

    2013-01-01

    Highlights: • The effects of gasoline fumigation on the engine performance and NO x emission were investigated in Ford XLD 418 T automotive diesel engine. • Gasoline at approximately (2, 4, 6, 8 10, and 12)% (by vol.) ratios was injected into intake air by a carburetor. • GF enhances effective power and reduces brake specific fuel consumption, cost, and NO x emission. - Abstract: One of the most important objectives of the studies worldwide is to improve combustion of diesel engine to meet growing energy needs and to reduce increasing environmental pollution. To accomplish this goal, especially to reduce pollutant emissions, researchers have focused their interest on the field of alternative fuels and alternative solutions. Gasoline fumigation (GF) is one of these alternative solutions, by which diesel combustion, fuel economy, and engine performance are improved, and environmental pollution is decreased. In the fumigation method, gasoline is injected into intake air, either by a carburetor, which main nozzle section is adjustable or by a simple injection system. In the present experimental study, a simple carburetor was used, and the effects of gasoline fumigation at (2, 4, 6, 8, 10, 12)% (by vol.) gasoline ratios on the combustion, NO x emission, fuel economy, and engine performance sophisticatedly investigated for a fully instrumented, four-cylinder, water-cooled indirect injection (IDI), Ford XLD 418 T automotive diesel engine. Tests were conducted for each of the above gasoline fumigation ratios at three different speeds and for (1/1, 3/4, and 1/2) fuel delivery ratios (FDRs). GF test results showed that NO x emission is lower than that of neat diesel fuel (NDF). NO x emission decreases approximately 4.20%, 2.50%, and 9.65% for (1/1, 3/4, and 1/2) FDRs, respectively. Effective power increases approximately 2.38% for 1/1 FDR. At (2500 and 3000) rpms, effective power decreases at low gasoline ratios, but it increases at high gasoline ratios for 3/4 and 1

  19. Scaling of the flow field in a combustion chamber with a gas–gas injector

    International Nuclear Information System (INIS)

    Xiao-Wei, Wang; Guo-Biao, Cai; Ping, Jin

    2010-01-01

    The scaling of the flow field in a gas–gas combustion chamber is investigated theoretically, numerically and experimentally. To obtain the scaling criterion of the gas–gas combustion flowfield, formulation analysis of the three-dimensional (3D) Navier–Stokes equations for a gaseous multi-component mixing reaction flow is conducted and dimensional analysis on the gas–gas combustion phenomena is also carried out. The criterion implies that the size and the pressure of the gas–gas combustion chamber can be changed. Based on the criterion, multi-element injector chambers with different geometric sizes and at different chamber pressures ranging from 3 MPa to 20 MPa are numerically simulated. A multi-element injector chamber is designed and hot-fire tested at five chamber pressures from 1.64 MPa to 3.68 MPa. Wall temperature measurements are used to understand the similarity of combustion flowfields in the tests. The results have verified the similarities between combustion flowfields under different chamber pressures and geometries, with the criterion applied. (geophysics, astronomy and astrophysics)

  20. Optimizing Performance of Combustion Chemistry Solvers on Intel's Many Integrated Core (MIC) Architectures

    Energy Technology Data Exchange (ETDEWEB)

    Sitaraman, Hariswaran [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Grout, Ray W [National Renewable Energy Laboratory (NREL), Golden, CO (United States)

    2017-06-09

    This work investigates novel algorithm designs and optimization techniques for restructuring chemistry integrators in zero and multidimensional combustion solvers, which can then be effectively used on the emerging generation of Intel's Many Integrated Core/Xeon Phi processors. These processors offer increased computing performance via large number of lightweight cores at relatively lower clock speeds compared to traditional processors (e.g. Intel Sandybridge/Ivybridge) used in current supercomputers. This style of processor can be productively used for chemistry integrators that form a costly part of computational combustion codes, in spite of their relatively lower clock speeds. Performance commensurate with traditional processors is achieved here through the combination of careful memory layout, exposing multiple levels of fine grain parallelism and through extensive use of vendor supported libraries (Cilk Plus and Math Kernel Libraries). Important optimization techniques for efficient memory usage and vectorization have been identified and quantified. These optimizations resulted in a factor of ~ 3 speed-up using Intel 2013 compiler and ~ 1.5 using Intel 2017 compiler for large chemical mechanisms compared to the unoptimized version on the Intel Xeon Phi. The strategies, especially with respect to memory usage and vectorization, should also be beneficial for general purpose computational fluid dynamics codes.

  1. Influence of cooled exhaust gas recirculation on performance, emissions and combustion characteristics of LPG fuelled lean burn SI engine

    Science.gov (United States)

    Ravi, K.; Pradeep Bhasker, J.; Alexander, Jim; Porpatham, E.

    2017-11-01

    On fuel perspective, Liquefied Petroleum Gas (LPG) provides cleaner emissions and also facilitates lean burn signifying less fuel consumption and emissions. Lean burn technology can attain better efficiencies and lesser combustion temperatures but this temperature is quite sufficient to facilitate formation of nitrogen oxide (NOx). Exhaust Gas Recirculation (EGR) for NOx reduction has been considered allover but extremely little literatures exist on the consequence of EGR on lean burn LPG fuelled spark ignition (SI) engine. The following research is carried out to find the optimal rate of EGR addition to reduce NOx emissions without settling on performance and combustion characteristics. A single cylinder diesel engine is altered to operate as LPG fuelled SI engine at a compression ratio of 10.5:1 and arrangements to provide different ratios of cooled EGR in the intake manifold. Investigations are done to arrive at optimum ratio of the EGR to reduce emissions without compromising on performance. Significant reductions in NOx emissions alongside HC and CO emissions were seen. Higher percentages of EGR further diluted the charge and lead to improper combustion and thus increased hydrocarbon emissions. Cooled EGR reduced the peak in-cylinder temperature which reduced NOx emissions but lead to misfire at lower lean limits.

  2. IEA combustion agreement : a collaborative task on alternative fuels in combustion

    International Nuclear Information System (INIS)

    Larmi, M.

    2009-01-01

    The focus of the alternative fuels in combustion task of the International Energy Agency is on high efficiency engine combustion, furnace combustion, and combustion chemistry. The objectives of the task are to develop optimum combustion for dedicated fuels by fully utilizing the physical and chemical properties of synthetic and renewable fuels; a significant reduction in carbon dioxide, NOx and particulate matter emissions; determine the minimum emission levels for dedicated fuels; and meet future emission standards of engines without or with minimum after-treatment. This presentation discussed the alternative fuels task and addressed issues such as synthetic fuel properties and benefits. The anticipated future roadmap was presented along with a list of the synthetic and renewable engine fuels to be studied, such as neat oxygenates like alcohols and ethers, biogas/methane and gas combustion, fuel blends, dual fuel combustion, high cetane number diesel fuels like synthetic Fischer-Tropsch diesel fuel and hydrogenated vegetable oil, and low CN number fuels. Implementation examples were also discussed, such as fuel spray studies in optical spray bombs; combustion research in optical engines and combustion chambers; studies on reaction kinetics of combustion and emission formation; studies on fuel properties and ignition behaviour; combustion studies on research engines; combustion optimization; implementing the optimum combustion in research engines; and emission measurements. Overall milestone examples and the overall schedule of participating countries were also presented. figs.

  3. Performance of candidate gas turbine abradeable seal materials in high temperature combustion atmospheres

    Energy Technology Data Exchange (ETDEWEB)

    Simms, N.J. [Cranfield University, Power Generation Technology Centre, Cranfield, Beds, MK43 0AL (United Kingdom); Norton, J.F. [Cranfield University, Power Generation Technology Centre, Cranfield, Beds, MK43 0AL (United Kingdom); Consultant in Corrosion Science and Technology, Hemel Hempstead, Herts HP1 1SR (United Kingdom); McColvin, G. [Siemens Industrial Turbines Ltd., Lincoln, LN5 7FD (United Kingdom)

    2005-11-01

    The development of abradeable gas turbine seals for higher temperature duties has been the target of an EU-funded R and D project, ADSEALS, with the aim of moving towards seals that can withstand surface temperatures as high as {proportional_to} 1100 C for periods of at least 24,000 h. The ADSEALS project has investigated the manufacturing and performance of a number of alternative materials for the traditional honeycomb seal design and novel alternative designs. This paper reports results from two series of exposure tests carried out to evaluate the oxidation performance of the seal structures in combustion gases and under thermal cycling conditions. These investigations formed one part of the evaluation of seal materials that has been carried out within the ADSEALS project. The first series of three tests, carried out for screening purposes, exposed candidate abradeable seal materials to a simulated natural gas combustion environment at temperatures within the range 1050-1150 C in controlled atmosphere furnaces for periods of up to {proportional_to} 2,500 h with fifteen thermal cycles. The samples were thermally cycled to room temperature on a weekly basis to enable the progress of the degradation to be monitored by mass change and visual observation, as well as allowing samples to be exchanged at planned intervals. The honeycombs were manufactured from PM2000 and Haynes 214. The backing plates for the seal constructions were manufactured from Haynes 214. Some seals contained fillers or had been surface treated (e.g. aluminised). The second series of three tests were carried out in a natural gas fired ribbon furnace facility that allowed up to sixty samples of candidate seal structures (including honeycombs, hollow sphere structures and porous ceramics manufactured from an extended range of materials including Aluchrom YHf, PM2Hf, Haynes 230, IN738LC and MarM247) to be exposed simultaneously to a stream of hot combustion gas. In this case the samples were cooled

  4. Studies of MHD generator performance with oxygen enriched coal combustion

    Science.gov (United States)

    Wormhoudt, J.; Yousefian, V.; Kolb, C. E.; Martinez-Sanchez, M.

    1980-07-01

    This paper presents calculations made using the Aerodyne PACKAGE (Plasma Analysis, Chemical Kinetics, and Generator Efficiency) computer code which bear on two questions which arise in connection with choices between oxygen enrichment and air preheating to attain the high combustion temperatures needed for open-cycle, coal-fired MHD power generation. The first question is which method produces the highest enthalpy extraction per unit channel length. The second is, in test facilities intended to study tradeoffs between oxygen enrichment and preheated air, can good generator performance be obtained from the same physical channel for different combustor compositions. The answer to the first question is found to depend on what combustor conditions are taken to be comparable. As for the second question, it is found that operation with channel input from off-design combustor conditions can cause serious problems, which can be partially alleviated by changing the channel load factors.

  5. INVESTIGATION OF COMBUSTION, PERFORMANCE AND EMISSION CHARACTERISTICS OF SPARK IGNITION ENGINE FUELLED WITH BUTHANOL – GASOLINE MIXTURE AND A HYDROGEN ENRICHED AIR

    OpenAIRE

    Alfredas Rimkus; Mindaugas Melaika; Jonas Matijošius; Šarūnas Mikaliūnas; Saugirdas Pukalskas

    2016-01-01

    In this study, spark ignition engine fuelled with buthanol-gasoline mixture and a hydrogen-enriched air was investigated. Engine performance, emissions and combustion characteristics were investigated with different buthanol (10% and 20% by volume) gasoline mixtures and additionally supplied oxygen and hydrogen (HHO) gas mixture (3.6 l/min) in the sucked air. Hydrogen, which is in the HHO gas, improves gasoline and gasoline-buthanol mixture combustion, increases indicated pressure during comb...

  6. Distributed Low Temperature Combustion: Fundamental Understanding of Combustion Regime Transitions

    Science.gov (United States)

    2016-09-07

    behaviour as compared to ethanol. The latter fuel has also been considered along with methane. Work has also been performed on the further assessment of... behaviour as compared to ethanol. The latter fuel has also been considered along with methane. Work has also been performed on the further assess- ment of...identification of various combustion gas states. A range of Damköhler numbers (Da) from the conventional propagating flamelet regime well into the distributed

  7. Higher alcohol–biodiesel–diesel blends: An approach for improving the performance, emission, and combustion of a light-duty diesel engine

    International Nuclear Information System (INIS)

    Imdadul, H.K.; Masjuki, H.H.; Kalam, M.A.; Zulkifli, N.W.M.; Alabdulkarem, Abdullah; Rashed, M.M.; Teoh, Y.H.; How, H.G.

    2016-01-01

    Highlights: • The fuel properties of higher alcohol blended biodiesel were improved. • Higher alcohol shows remarkable increase in the BP, BTE and decrease the BSFC. • Alcohols mixed with biodiesel diminishes HC, CO and smoke significantly. • CO 2 emissions of pentanol blended fuel decreases at maximum speed. • Higher alcohol blended biodiesel showed improved combustion. - Abstract: Pentanol is a long-chain alcohol with five carbons in its molecular structure and is produced from renewable feedstock, which may help to improve the challenging problems of energy security and environmental issues. In this investigation, the performance, emission, and combustion characteristics of a single-cylinder, four-stroke, water-cooled, direct-injection diesel engine were evaluated by using 10%, 15%, and 20% pentanol and Calophyllum inophyllum (CI) biodiesel blends in diesel under different speed conditions. The fuel properties of the blended fuels were measured and compared. Combustion attributes, such as cylinder pressure and heat-release rate, were also analyzed. Results indicated that increasing the proportion of pentanol in biodiesel blends improved the fuel properties compared with 20% blend of CI biodiesel (CI 20). The modified blends of pentanol showed reduced brake-specific fuel consumption with higher brake thermal efficiency and brake power than CI 20. Although the modified test blends showed a slightly higher nitric oxide emission, the carbon monoxide emission and unburned hydrocarbon emission for 15% and 20% blends of pentanol showed even better reduction than CI 20. Smoke emission was also reduced significantly. The carbon dioxide emission of the test blends were reduced at the maximum speed condition compared to CI 20. In terms of combustion, the modified test fuels exhibited a significant improvement, thus indicating better performance and emission. This study concluded that the 15% and 20% blends of biodiesel, diesel, and pentanol can optimize engine

  8. Internal combustion engine using premixed combustion of stratified charges

    Science.gov (United States)

    Marriott, Craig D [Rochester Hills, MI; Reitz, Rolf D [Madison, WI

    2003-12-30

    During a combustion cycle, a first stoichiometrically lean fuel charge is injected well prior to top dead center, preferably during the intake stroke. This first fuel charge is substantially mixed with the combustion chamber air during subsequent motion of the piston towards top dead center. A subsequent fuel charge is then injected prior to top dead center to create a stratified, locally richer mixture (but still leaner than stoichiometric) within the combustion chamber. The locally rich region within the combustion chamber has sufficient fuel density to autoignite, and its self-ignition serves to activate ignition for the lean mixture existing within the remainder of the combustion chamber. Because the mixture within the combustion chamber is overall premixed and relatively lean, NO.sub.x and soot production are significantly diminished.

  9. Compositional Effects of Gasoline Fuels on Combustion, Performance and Emissions in Engine

    KAUST Repository

    Ahmed, Ahfaz

    2016-10-17

    Commercial gasoline fuels are complex mixtures of numerous hydrocarbons. Their composition differs significantly owing to several factors, source of crude oil being one of them. Because of such inconsistency in composition, there are multiple gasoline fuel compositions with similar octane ratings. It is of interest to comparatively study such fuels with similar octane ratings and different composition, and thus dissimilar physical and chemical properties. Such an investigation is required to interpret differences in combustion behavior of gasoline fuels that show similar knock characteristics in a cooperative fuel research (CFR) engine, but may behave differently in direct injection spark ignition (DISI) engines or any other engine combustion modes. Two FACE (Fuels for Advanced Combustion Engines) gasolines, FACE F and FACE G with similar Research and Motor Octane Numbers but dissimilar physical properties were studied in a DISI engine under two sets of experimental conditions; the first set involved early fuel injection to allow sufficient time for fuel-air mixing hence permitting operation similar to homogenous DISI engines, while the second set consists of advance of spark timings to attain MBT (maximum brake torque) settings. These experimental conditions are repeated across different load points to observe the effect of increasing temperature and pressure on combustion and emission parameters. The differences in various engine-out parameters are discussed and interpreted in terms of physical and thermodynamic properties of the fuels.

  10. 77 FR 37361 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-06-21

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines AGENCY: Environmental Protection... Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance...

  11. Fuel and combustion stratification study of Partially Premixed Combustion

    OpenAIRE

    Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

    2016-01-01

    Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a clear definition of “fuel and combustion stratifications” is obvious in literature. Hence, it is difficult to compare stratification levels of different PPC strategies or other combustion concepts. T...

  12. Development of flameless combustion; Desarrollo de la combustion sin flama

    Energy Technology Data Exchange (ETDEWEB)

    Flores Sauceda, M. Leonardo; Cervantes de Gortari, Jaime Gonzalo [Universidad Nacional Autonoma de Mexico, Mexico, D.F. (Mexico)]. E-mail: 8344afc@prodigy.net.mx; jgonzalo@servidor.unam.mx

    2010-11-15

    The paper intends contribute to global warming mitigation joint effort that develops technologies to capture the CO{sub 2} produced by fossil fuels combustion and to reduce emission of other greenhouse gases like the NO{sub x}. After reviewing existing combustion bibliography is pointed out that (a) touches only partial aspects of the collective system composed by Combustion-Heat transfer process-Environment, whose interactions are our primary interest and (b) most specialists think there is not yet a clearly winning technology for CO{sub 2} capture and storage. In this paper the study of combustion is focused as integrated in the aforementioned collective system where application of flameless combustion, using oxidant preheated in heat regenerators and fluent gas recirculation into combustion chamber plus appropriated heat and mass balances, simultaneously results in energy saving and environmental impact reduction. [Spanish] El trabajo pretende contribuir al esfuerzo conjunto de mitigacion del calentamiento global que aporta tecnologias para capturar el CO{sub 2} producido por la combustion de combustibles fosiles y para disminuir la emision de otros gases invernadero como NOx. De revision bibliografica sobre combustion se concluye que (a) trata aspectos parciales del sistema compuesto por combustion-proceso de trasferencia de calor-ambiente, cuyas interacciones son nuestro principal interes (b) la mayoria de especialistas considera no hay todavia una tecnologia claramente superior a las demas para captura y almacenaje de CO{sub 2}. Se estudia la combustion como parte integrante del mencionado sistema conjunto, donde la aplicacion de combustion sin flama, empleando oxidante precalentado mediante regeneradores de calor y recirculacion de gases efluentes ademas de los balances de masa y energia adecuados, permite tener simultaneamente ahorros energeticos e impacto ambiental reducido.

  13. Pilot-scale incineration testing of an oxygen-enhanced combustion system

    International Nuclear Information System (INIS)

    Waterland, L.R.; Lee, J.W.; Staley, L.J.

    1989-01-01

    This paper discusses a series of demonstration tests of the American Combustion, Inc., Thermal Destruction System performed under the Superfund innovative technology evaluation (SITE) program. This oxygen-enhanced combustion system was retrofit to the pilot-scale rotary kiln incinerator at EPA's Combustion Research Facility. This system's performance was tested firing contaminated soil from the Stringfellow Superfund Site, both alone and mixed with a hazardous coal tar waste (decanter tank tar sludge form coking operations - K087). Comparative performance with conventional incinerator operation was tested. Test results show that compliance with the hazardous waste incinerator performance standards of 99.99 percent principal organic hazardous constituent (POHC) destruction and removal efficiency (DRE) and particulate emissions of less than 180 mg/dscm at 7 percent O 2 was achieved for all tests. The Pyretron oxygen-enhanced combustion system allowed in-compliance operation at double the mixed waste feedrate possible with conventional incineration, and with a 60 percent increase in charge weight than possible with conventional incineration

  14. Partially premixed prevalorized kerosene spray combustion in turbulent flow

    Energy Technology Data Exchange (ETDEWEB)

    Chrigui, M.; Ahmadi, W.; Sadiki, A.; Janicka, J. [Institute for Energy and Powerplant Technology, TU Darmstadt, Petersenstr. 30, 64287 Darmstadt (Germany); Moesl, K. [Lehrstuhl fuer Thermodynamik, TU Muenchen, Boltzmannstr. 15, D-85747 Garching (Germany)

    2010-04-15

    A detailed numerical simulation of kerosene spray combustion was carried out on a partially premixed, prevaporized, three-dimensional configuration. The focus was on the flame temperature profile dependency on the length of the pre-vaporization zone. The results were analyzed and compared to experimental data. A fundamental study was performed to observe the temperature variation and flame flashback. Changes were made to the droplet diameter, kerosene flammability limits, a combustion model parameter and the location of the combustion initialization. Investigations were performed for atmospheric pressure, inlet air temperature of 90 C and a global equivalence ratio of 0.7. The simulations were carried out using the Eulerian Lagrangian procedure under a fully two-way coupling. The Bray-Moss-Libby model was adjusted to account for the partially premixed combustion. (author)

  15. Experimental study on combustion of biomass micron fuel (BMF) in cyclone furnace

    International Nuclear Information System (INIS)

    Luo Siyi; Xiao Bo; Hu Zhiquan; Liu Shiming; He Maoyun

    2010-01-01

    Based on biomass micron fuel (BMF) with particle size less than 250 μm, a cyclone combustion concept was presented and a lab-scale cyclone furnace was designed to evaluate the feasibility. The influences of equivalence ration (ER) and particle size of BMF on combustion performance were studied, as well as temperature distribution in the combustion chamber. The results show that BMF combustion in the cyclone furnace is reliable, with rational temperature distribution inside furnace hearth, lower CO emission, soot concentration and C content in ashes. As ER being 1.2, the temperature in the chamber is maximized up to 1200 deg. C. Smaller particles results in better combustion performances.

  16. Improved correlations of hydrogen content versus combustion performance related properties of aviation turbine fuels

    Energy Technology Data Exchange (ETDEWEB)

    Nagpal, J.M.; Sharma, R.L.; Sagu, M.L.; Tiwari, G.B. (Indian Institute of Petroleum, Dehradun (India))

    1994-01-01

    In recent years the hydrogen content of Aviation Fuels has generated considerable interest. Various investigators have suggested correlation of hydrogen content with combustion related properties of aviation turbine fuel (ATF). A suitable threshold value of hydrogen content 13.8 wt% is being considered as a waiver of specifications such as specific energy, aniline gravity product, smoke point, aromatic content, naphthalenes and luminometer number. In the present paper relationship between the hydrogen content and combustion related properties has been examined and improved correlations of hydrogen content with several combustion related properties have been developed by incorporating a characterization factor in the equations. The supporting threshold value of a hydrogen content of 13.8wt% is verified with 25 data points for waiving of combustion properties such as specific energy, aniline gravity product, smoke point and aromatic content from aviation turbine fuel. 6 refs., 12 figs., 2 tabs.

  17. The Role of Trait Emotional Intelligence in Academic Performance: Theoretical Overview and Empirical Update.

    Science.gov (United States)

    Perera, Harsha N

    2016-01-01

    Considerable debate still exists among scholars over the role of trait emotional intelligence (TEI) in academic performance. The dominant theoretical position is that TEI should be orthogonal or only weakly related to achievement; yet, there are strong theoretical reasons to believe that TEI plays a key role in performance. The purpose of the current article is to provide (a) an overview of the possible theoretical mechanisms linking TEI with achievement and (b) an update on empirical research examining this relationship. To elucidate these theoretical mechanisms, the overview draws on multiple theories of emotion and regulation, including TEI theory, social-functional accounts of emotion, and expectancy-value and psychobiological model of emotion and regulation. Although these theoretical accounts variously emphasize different variables as focal constructs, when taken together, they provide a comprehensive picture of the possible mechanisms linking TEI with achievement. In this regard, the article redresses the problem of vaguely specified theoretical links currently hampering progress in the field. The article closes with a consideration of directions for future research.

  18. Measures for a quality combustion (combustion chamber exit and downstream); Mesures pour une combustion de qualite (sortie de chambre de combustion et en aval)

    Energy Technology Data Exchange (ETDEWEB)

    Epinat, G. [APAVE Lyonnaise, 69 (France)

    1996-12-31

    After a review of the different pollutants related to the various types of stationary and mobile combustion processes (stoichiometric, reducing and oxidizing combustion), measures and analyses than may be used to ensure the quality and efficiency of combustion processes are reviewed: opacimeters, UV analyzers, etc. The regulation and control equipment for combustion systems are then listed, according to the generator capacity level

  19. Investigating the effects of LPG on spark ignition engine combustion and performance

    International Nuclear Information System (INIS)

    Bayraktar, Hakan; Durgun, Orhan

    2005-01-01

    A quasi-dimensional spark ignition (SI) engine cycle model is used to predict the cycle, performance and exhaust emissions of an automotive engine for the cases of using gasoline and LPG. Governing equations of the mathematical model mainly consist of first order ordinary differential equations derived for cylinder pressure and temperature. Combustion is simulated as a turbulent flame propagation process and during this process, two different thermodynamic regions consisting of unburned gases and burned gases that are separated by the flame front are considered. A computer code for the cycle model has been prepared to perform numerical calculations over a range of engine speeds and fuel-air equivalence ratios. In the computations performed at different engine speeds, the same fuel-air equivalence ratios are selected for each fuel to make realistic comparisons from the fuel economy and fuel consumption points of view. Comparisons show that if LPG fueled SI engines are operated at the same conditions with those of gasoline fueled SI engines, significant improvements in exhaust emissions can be achieved. However, variations in various engine performance parameters and the effects on the engine structural elements are not promising

  20. Understanding employee motivation and organizational performance: Arguments for a set-theoretic approach

    Directory of Open Access Journals (Sweden)

    Michael T. Lee

    2016-09-01

    Full Text Available Empirical evidence demonstrates that motivated employees mean better organizational performance. The objective of this conceptual paper is to articulate the progress that has been made in understanding employee motivation and organizational performance, and to suggest how the theory concerning employee motivation and organizational performance may be advanced. We acknowledge the existing limitations of theory development and suggest an alternative research approach. Current motivation theory development is based on conventional quantitative analysis (e.g., multiple regression analysis, structural equation modeling. Since researchers are interested in context and understanding of this social phenomena holistically, they think in terms of combinations and configurations of a set of pertinent variables. We suggest that researchers take a set-theoretic approach to complement existing conventional quantitative analysis. To advance current thinking, we propose a set-theoretic approach to leverage employee motivation for organizational performance.

  1. Combustion performance of porous silicon-based energetic composites

    Energy Technology Data Exchange (ETDEWEB)

    Mason, Benjamin Aaron [Los Alamos National Laboratory; Son, Steve F [Los Alamos National Laboratory; Asay, Blaine W [Los Alamos National Laboratory; Cho, Kevin Y [PURDUE UNIV

    2009-01-01

    The combustion performance of oxidizer filled porous silicon(PSi) was studied. PSi samples with diameters of 2.54 cm were fabricated by electrochemical etching. The % porosity of the samples ranged from 55 to 82%. The samples were cut into 3-5 mm strips and filled with the oxidizers NaClO{sub 4} x 1H{sub 2}O, Ca(ClO{sub 4}){sub 2} x 4H{sub 2}O, S and perfluoropolyether (PFPE). The filled PSi was then burned by igniting the sample with a hot NiChrome{trademark} wire. The burns were recorded using high speed photography from which bring rates were calculated. That burning rates showed a strong dependency on quality of the oxidizer loading. The % porosity did not appear to have a direct affect on the burning rates for those studied. PSi loaded with NaClO{sub 4} x 1H{sub 2}O produced burning rates that ranged from 216-349 cm/s. PSi loaded with Ca(ClO{sub 4}){sub x}x 4 H{sub 2}O had burning rates of 154-285 cm/s. An S filled PSi sample burned a rate of 16 to 290 cm/s, and perfluoropolyether loaded PSi burned at a rate of 1.4 cm/s.

  2. Experimental investigation of flash pyrolysis oil droplet combustion

    DEFF Research Database (Denmark)

    Ibrahim, Norazana; Jensen, Peter A.; Dam-Johansen, Kim

    2013-01-01

    at a temperature ranging between 1000 and 1400°C with an initial gas velocity of 1.6 m/s and oxygen concentration of 3%. The evolution of combustion of bio-oil droplets was recorded by a digital video camera. It was observed that the combustion behaviour of pyrolysis oil droplet differ from the heavy oil in terms......The aim of this work is to investigate and compare the combustion behaviour of a single droplet of pyrolysis oil derived from wheat straw and heavy fossil oil in a single droplet combustion chamber. The initial oil droplet diameters were in between 500 μm to 2500 μm. The experiments were performed...

  3. Research of combustion in older generation spark-ignition engines in the condition of use leaded and unleaded petrol

    Directory of Open Access Journals (Sweden)

    Bulatović Željko M.

    2014-01-01

    Full Text Available This paper analyzes the potential problems in the exploitation of the older generation of spark-ignition engines with higher octane number of petrol (unleaded petrol BMB 95 than required (leaded petrol MB 86. Within the experimental tests on two different engines (STEYR-PUCH model 712 and GAZ 41 by applying piezoelectric pressure sensors integrated with the engine spark plugs, acceleration sensors (accelerometers and special electronic block connected with distributor, show that the cumulative first and second theoretical phase of combustion when petrol of higher octane number (BMB 95 is used lasts slightly longer than when the low-octane petrol MB 86 is used. For new petrol (BMB 95 higher optimal angles of pre-ignition have been determined by which better performances of the engine are achieved without a danger of the combustion with detonation (also called knocking.

  4. Synthesis of Diopside by Solution Combustion Process Using Glycine Fuel

    Science.gov (United States)

    Sherikar, Baburao N.; Umarji, A. M.

    Nano ceramic Diopside (CaMgSi2O6) powders are synthesized by Solution Combustion Process(SCS) using Calcium nitrate, Magnesium nitrate as oxidizer and glycine as fuel, fumed silica as silica source. Ammonium nitrate (AN) is used as extra oxidizer. Effect of AN on Diopside phase formation is investigated. The adiabatic flame temperatures are calculated theoretically for varying amount of AN according to thermodynamic concept and correlated with the observed flame temperatures. A “Multi channel thermocouple setup connected to computer interfaced Keithley multi voltmeter 2700” is used to monitor the thermal events during the process. An interpretation based on maximum combustion temperature and the amount of gases produced during reaction for various AN compositions has been proposed for the nature of combustion and its correlation with the characteristics of as synthesized powder. These powders are characterized by XRD, SEM showing that the powders are composed of polycrystalline oxides with crystallite size of 58nm to 74nm.

  5. Environmental performance of the Kvaerner BFB boilers for MSW combustion -- Analysis of gaseous emissions and solid residues

    International Nuclear Information System (INIS)

    Lundberg, M.; Hagman, U.; Andersson, B.A.; Olofsson, J.

    1997-01-01

    Kvaerner Pulping AB (formerly Kvaerner EnviroPower AB) has, due to the stringent demands on emissions performance, developed a state-of-the-art bubbling fluidized bed boiler (BFB) designed for waste fuel firing with very low emissions to the air. A complete evaluation of the environmental performance of the Kvaerner BFB technique for MSW combustion is now possible thanks to a thorough characterization study of the solid residues from the Lidkoeping plant. This paper gives an overall mapping of the emissions performance. Data from the operating plants on solid residue characteristics and leachability, heavy metal and dioxin emissions, nitrogen oxides, carbon monoxide, acid gases, and other emissions to air are presented. Comparisons are made with legislative limits and data from the mass burning technique. It is concluded that the emissions are low compared both with data from traditional mass burn incinerators and with legislative limits in the USA and Europe. Furthermore, the bottom and cyclone ash characteristics are shown not to cause any particular problem from an environmental point of view, and that the leachability is well below the existing legislative limits in Europe and the USA. The results show that fluidized bed combustion of municipal solid waste is a very competitive alternative to the traditional mass burning technique in every respect

  6. Theoretical and experimental investigations on the performance of dual fuel diesel engine with hydrogen and LPG as secondary fuels

    Energy Technology Data Exchange (ETDEWEB)

    Lata, D.B.; Misra, Ashok [Department of Mechanical Engineering, Birla Institute of Technology, Mesra, Ranchi 835215 (India)

    2010-11-15

    The mathematical models to predict pressure, net heat release rate, mean gas temperature, and brake thermal efficiency for dual fuel diesel engine operated on hydrogen, LPG and mixture of LPG and hydrogen as secondary fuels are developed. In these models emphasis have been given on spray mixing characteristics, flame propagation, equilibrium combustion products and in-cylinder processes, which were computed using empirical equations and compared with experimental results. This combustion model predicts results which are in close agreement with the results of experiments conducted on a multi cylinder turbocharged, intercooled gen-set diesel engine. The predictions are also in close agreement with the results on single cylinder diesel engine obtained by other researchers. A reasonable agreement between the predicted and experimental results reveals that the presented model gives quantitatively and qualitatively realistic prediction of in-cylinder processes and engine performances during combustion. (author)

  7. Recent Advances In Science Support For Isolated Droplet Combustion Experiments

    Science.gov (United States)

    Dryer, F. L.; Kazakov, A.; Urban, B. D.; Kroenlein, K.

    2003-01-01

    In a joint program involving Prof. F.A. Williams of the University of California, San Diego and Dr. V. Nayagam of the National Center for Microgravity Research, the combustion characteristics of isolated liquid fuel droplets of n-heptane, n-decane, methanol, methanol-water, ethanol and ethanol-water having initial diameters between about 1 mm and 6 mm continues to be investigated. The objectives of the work are to improve fundamental knowledge of droplet combustion dynamics for pure fuels and fuel-water mixtures through microgravity experiments and theoretical analyses. The Princeton contributions support the engineering design, data analysis, and data interpretation requirements for the study of initially single component, spherically symmetric, isolated droplet combustion studies through experiments and numerical modeling. UCSD contributions are described in a companion communication in this conference. The Princeton effort also addresses the analyses of Fiber Supported Droplet Combustion (FSDC) experiments conducted with the above fuels and collaborative work with others who are investigating droplet combustion in the presence of steady convection. A thorough interpretation of droplet burning behavior for n-heptane and n-decane over a relatively wide range of conditions also involves the influences of sooting on the combustion behavior, and this particular aspect on isolated burning of droplets is under consideration in a collaborative program underway with Drexel University. This collaboration is addressed in another communication at this conference. The one-dimensional, time-dependent, numerical modeling approach that we have continued to evolve for analyzing isolated, quiescent droplet combustion data has been further applied to investigate several facets of isolated droplet burning of simple alcohols, n-heptane, and n-decane. Some of the new results are described below.

  8. Evaluation of self-combustion risk in tire derived aggregate fills.

    Science.gov (United States)

    Arroyo, Marcos; San Martin, Ignacio; Olivella, Sebastian; Saaltink, Maarten W

    2011-01-01

    Lightweight tire derived aggregate (TDA) fills are a proven recycling outlet for waste tires, requiring relatively low cost waste processing and being competitively priced against other lightweight fill alternatives. However its value has been marred as several TDA fills have self-combusted during the early applications of this technique. An empirical review of these cases led to prescriptive guidelines from the ASTM aimed at avoiding this problem. This approach has been successful in avoiding further incidents of self-combustion. However, at present there remains no rational method available to quantify self-combustion risk in TDA fills. This means that it is not clear which aspects of the ASTM guidelines are essential and which are accessory. This hinders the practical use of TDA fills despite their inherent advantages as lightweight fill. Here a quantitative approach to self-combustion risk evaluation is developed and illustrated with a parametric analysis of an embankment case. This is later particularized to model a reported field self-combustion case. The approach is based on the available experimental observations and incorporates well-tested methodological (ISO corrosion evaluation) and theoretical tools (finite element analysis of coupled heat and mass flow). The results obtained offer clear insights into the critical aspects of the problem, allowing already some meaningful recommendations for guideline revision. Copyright © 2011 Elsevier Ltd. All rights reserved.

  9. Low NOx combustion technologies for high-temperature natural gas combustion

    International Nuclear Information System (INIS)

    Flamme, Michael

    1999-01-01

    Because of the high process temperature which is required for some processes like glass melting and the high temperature to which the combustion air is preheated, NOx emission are extremely high. Even at these high temperatures, NOx emissions could be reduced drastically by using advanced combustion techniques such as staged combustion or flame-less oxidation, as experimental work has shown. In the case of oxy-fuel combustion, the NOx emission are also very high if conventional burners are used. The new combustion techniques achieve similar NOx reductions. (author)

  10. Low Temperature Combustion Demonstrator for High Efficiency Clean Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Ojeda, William de

    2010-07-31

    The project which extended from November 2005 to May of 2010 demonstrated the application of Low Temperature Combustion (LTC) with engine out NOx levels of 0.2 g/bhp-hr throughout the program target load of 12.6bar BMEP. The project showed that the range of loads could be extended to 16.5bar BMEP, therefore matching the reference lug line of the base 2007 MY Navistar 6.4L V8 engine. Results showed that the application of LTC provided a dramatic improvement over engine out emissions when compared to the base engine. Furthermore LTC improved thermal efficiency by over 5% from the base production engine when using the steady state 13 mode composite test as a benchmark. The key enablers included improvements in the air, fuel injection, and cooling systems made in Phases I and II. The outcome was the product of a careful integration of each component under an intelligent control system. The engine hardware provided the conditions to support LTC and the controller provided the necessary robustness for a stable combustion. Phase III provided a detailed account on the injection strategy used to meet the high load requirements. During this phase, the control strategy was implemented in a production automotive grade ECU to perform cycle-by-cycle combustion feedback on each of the engine cylinders. The control interacted on a cycle base with the injection system and with the Turbo-EGR systems according to their respective time constants. The result was a unique system that could, first, help optimize the combustion system and maintain high efficiency, and secondly, extend the steady state results to the transient mode of operation. The engine was upgraded in Phase IV with a Variable Valve Actuation system and a hybrid EGR loop. The impact of the more versatile EGR loop did not provide significant advantages, however the application of VVA proved to be an enabler to further extend the operation of LTC and gain considerable benefits in fuel economy and soot reduction. Finally

  11. Combustion instability control in the model of combustion chamber

    International Nuclear Information System (INIS)

    Akhmadullin, A N; Ahmethanov, E N; Iovleva, O V; Mitrofanov, G A

    2013-01-01

    An experimental study of the influence of external periodic perturbations on the instability of the combustion chamber in a pulsating combustion. As an external periodic disturbances were used sound waves emitted by the electrodynamics. The purpose of the study was to determine the possibility of using the method of external periodic perturbation to control the combustion instability. The study was conducted on a specially created model of the combustion chamber with a swirl burner in the frequency range from 100 to 1400 Hz. The study found that the method of external periodic perturbations may be used to control combustion instability. Depending on the frequency of the external periodic perturbation is observed as an increase and decrease in the amplitude of the oscillations in the combustion chamber. These effects are due to the mechanisms of synchronous and asynchronous action. External periodic disturbance generated in the path feeding the gaseous fuel, showing the high efficiency of the method of management in terms of energy costs. Power required to initiate periodic disturbances (50 W) is significantly smaller than the thermal capacity of the combustion chamber (100 kW)

  12. Modeling of the dynamical combustion of explosives: influence of mechanical properties; Modelisation de la combustion dynamique des explodifs: influence des proprietes mecaniques

    Energy Technology Data Exchange (ETDEWEB)

    Picart, D.; Pertuis, C. [CEA Le Ripault, 37 - Tours (France)

    1996-12-31

    Experimental observations performed during the combustion of solid explosives under pressure have shown an unexpected desensitization of the samples when damaged. A simplified method of combustion simulation inside a pressure cell is proposed in this study. The model used is based on the description of the mechanical behaviour of the solid phase. It allows to retrieve the overall experimental results, and in particular the occurrence of anomalous combustion modes. (J.S.) 8 refs.

  13. Combustion characterization of beneficiated coal-based fuels

    Energy Technology Data Exchange (ETDEWEB)

    Chow, O.K.; Levasseur, A.A.

    1995-11-01

    The Pittsburgh Energy Technology Center (PETC) of the U.S. Department of Energy is sponsoring the development of advanced coal-cleaning technologies aimed at expanding the use of the nation`s vast coal reserves in an environmentally and economically acceptable manner. Because of the lack of practical experience with deeply beneficiated coal-based fuels, PETC has contracted Combustion Engineering, Inc. to perform a multi-year project on `Combustion Characterization of Beneficiated Coal-Based Fuels.` The objectives of this project include: (1) the development of an engineering data base which will provide detailed information on the properties of Beneficiated Coal-Based Fuels (BCs) influencing combustion, ash deposition, ash erosion, particulate collection, and emissions; and (2) the application of this technical data base to predict the performance and economic impacts of firing the BCFs in various commercial boiler designs.

  14. COMBUSTION OPTIMIZATION IN SPARK IGNITION ENGINES

    OpenAIRE

    Barhm Mohamad; Gabor Szebesi; Betti Bollo

    2017-01-01

    The blending technique used in internal combustion engines can reduce emission of toxic exhaust components and noises, enhance overall energy efficiency and reduce fuel costs. The aim of the study was to compare the effects of dual alcohols (methanol and ethanol) blended in gasoline fuel (GF) against performance, combustion and emission characteristics. Problems arise in the fuel delivery system when using the highly volatile methanol - gasoline blends. This problem is reduced by using specia...

  15. Theoretical analysis of ejector refrigeration system performance under overall modes

    International Nuclear Information System (INIS)

    Chen, Weixiong; Shi, Chaoyin; Zhang, Shuangping; Chen, Huiqiang; Chong, Daotong; Yan, Junjie

    2017-01-01

    Highlights: • Real gas theoretical model is used to get ejector performance at critical/sub-critical modes. • The model has a better accuracy against the experiment results compared to ideal gas model. • The overall performances of two refrigerants are analyzed based on the parameter analysis. - Abstract: The ejector refrigeration integrated in the air-conditioning system is a promising technology, because it could be driven by the low grade energy. In the present study, a theoretical calculation based on the real gas property is put forward to estimate the ejector refrigeration system performance under overall modes (critical/sub-critical modes). The experimental data from literature are applied to validate the proposed model. The findings show that the proposed model has higher accuracy compared to the model using the ideal gas law, especially when the ejector operates at sub-critical mode. Then, the performances of the ejector refrigeration circle using different refrigerants are analyzed. R290 and R134a are selected as typical refrigerants by considering the aspects of COP, environmental impact, safety and economy. Finally, the ejector refrigeration performance is investigated under variable operation conditions with R290 and R134a as refrigerants. The results show that the R290 ejector circle has higher COP under critical mode and could operate at low evaporator temperature. However, the performance would decrease rapidly at high condenser temperature. The performance of R134a ejector circle is the opposite, with relatively lower COP, and higher COP at high condenser temperature compared to R290.

  16. Rotary combustion device

    NARCIS (Netherlands)

    2008-01-01

    Rotary combustion device (1) with rotary combustion chamber (4). Specific measures are taken to provide ignition of a combustible mixture. It is proposed that a hollow tube be provided coaxially with the axis of rotation (6), so that a small part of the mixture is guided into the combustion chamber.

  17. Theoretical and experimental studies on combustion of alternative fuels in cement kilns

    International Nuclear Information System (INIS)

    Axelsen, Ernst Petter

    2002-01-01

    In this thesis, the utilization of alternative fuels for NOx reduction by means of reburning and advanced reburning is considered. Laboratory experiments, full-scale experiments and computational fluid dynamic (CFD) simulations are the basis of the thesis. The goal of the work was to characterize alternative fuels used in cement kilns, with focus on the processes taking place in the precalciner of the cement kiln. To facilitate testing under controlled process conditions, a lab-scale circulating fluidized bed combustion (CFBC) reactor was designed and constructed. A co prehensive study on the fluidization regime in CFBC reactors and precalciners was required to ensure and verify that the operational regime in the CFBC reactor was similar to the regime in a precalciner. Different alternative fuels, such as refuse derived fuel, animal meal and solid hazardous waste, were tested in the CFBC reactor, which proved well suited for characterization of alternative fuels and investigations of NOx reduction, even though the operation of a CFBC reactor is quite complex and gives a certain variation in stability. Experiments with and without circulating mass in the CFBC reactor demonstrated the importance of executing the laboratory combustion experiments in an environment similar to that in the full-scale process, i.e. in the precalciner. Animal meal is believed to follow the reduction route of selective non-catalytic r duction or advanced reburning and to have a special capability of reducing NOx during increased NOx concentrations at the reactor inlet. The increased CO emissions during advanced reburning and reburning with animal meal are most likely to be due to the competition for the OH radical during oxidation of CO and of NH 3 . Furthermore, it was shown, for all fuels, that an increased concentration of NOx at the reactor inlet increases the ratio of NOx at the exit and NOx supplied. Full-scale experiments were executed at Norcem's kiln 6 in Brevik, using solid

  18. Theoretical and experimental studies on combustion of alternative fuels in cement kilns

    Energy Technology Data Exchange (ETDEWEB)

    Axelsen, Ernst Petter

    2002-07-01

    In this thesis, the utilization of alternative fuels for NOx reduction by means of reburning and advanced reburning is considered. Laboratory experiments, full-scale experiments and computational fluid dynamic (CFD) simulations are the basis of the thesis. The goal of the work was to characterize alternative fuels used in cement kilns, with focus on the processes taking place in the precalciner of the cement kiln. To facilitate testing under controlled process conditions, a lab-scale circulating fluidized bed combustion (CFBC) reactor was designed and constructed. A co prehensive study on the fluidization regime in CFBC reactors and precalciners was required to ensure and verify that the operational regime in the CFBC reactor was similar to the regime in a precalciner. Different alternative fuels, such as refuse derived fuel, animal meal and solid hazardous waste, were tested in the CFBC reactor, which proved well suited for characterization of alternative fuels and investigations of NOx reduction, even though the operation of a CFBC reactor is quite complex and gives a certain variation in stability. Experiments with and without circulating mass in the CFBC reactor demonstrated the importance of executing the laboratory combustion experiments in an environment similar to that in the full-scale process, i.e. in the precalciner. Animal meal is believed to follow the reduction route of selective non-catalytic r duction or advanced reburning and to have a special capability of reducing NOx during increased NOx concentrations at the reactor inlet. The increased CO emissions during advanced reburning and reburning with animal meal are most likely to be due to the competition for the OH radical during oxidation of CO and of NH{sub 3}. Furthermore, it was shown, for all fuels, that an increased concentration of NOx at the reactor inlet increases the ratio of NOx at the exit and NOx supplied. Full-scale experiments were executed at Norcem's kiln 6 in Brevik, using solid

  19. Theoretical and experimental studies on combustion of alternative fuels in cement kilns

    Energy Technology Data Exchange (ETDEWEB)

    Axelsen, Ernst Petter

    2002-07-01

    In this thesis, the utilization of alternative fuels for NOx reduction by means of reburning and advanced reburning is considered. Laboratory experiments, full-scale experiments and computational fluid dynamic (CFD) simulations are the basis of the thesis. The goal of the work was to characterize alternative fuels used in cement kilns, with focus on the processes taking place in the precalciner of the cement kiln. To facilitate testing under controlled process conditions, a lab-scale circulating fluidized bed combustion (CFBC) reactor was designed and constructed. A co prehensive study on the fluidization regime in CFBC reactors and precalciners was required to ensure and verify that the operational regime in the CFBC reactor was similar to the regime in a precalciner. Different alternative fuels, such as refuse derived fuel, animal meal and solid hazardous waste, were tested in the CFBC reactor, which proved well suited for characterization of alternative fuels and investigations of NOx reduction, even though the operation of a CFBC reactor is quite complex and gives a certain variation in stability. Experiments with and without circulating mass in the CFBC reactor demonstrated the importance of executing the laboratory combustion experiments in an environment similar to that in the full-scale process, i.e. in the precalciner. Animal meal is believed to follow the reduction route of selective non-catalytic r duction or advanced reburning and to have a special capability of reducing NOx during increased NOx concentrations at the reactor inlet. The increased CO emissions during advanced reburning and reburning with animal meal are most likely to be due to the competition for the OH radical during oxidation of CO and of NH{sub 3}. Furthermore, it was shown, for all fuels, that an increased concentration of NOx at the reactor inlet increases the ratio of NOx at the exit and NOx supplied. Full-scale experiments were executed at Norcem's kiln 6 in Brevik, using

  20. Experimental investigation of performance, exhaust emission and combustion parameters of stationary compression ignition engine using ethanol fumigation in dual fuel mode

    International Nuclear Information System (INIS)

    Jamuwa, D.K.; Sharma, D.; Soni, S.L.

    2016-01-01

    Highlights: • Potential of renewable fuels as diesel replacement is being emphasized. • Effect of ethanol fumigation on the performance of diesel engine is investigated. • NOx, CO_2 and smoke decreases with simultaneous increase in HC and CO. • Increase in ignition delay with decrease in combustion duration for ethanol substitution observed. - Abstract: Dwindling reserves and steeply increasing prices of the fossil-fuels, concern over climatic change due to release of anthropogenic greenhouse gases and the strict environmental regulations have motivated the researchers for the search for renewable alternative fuel that has clean burning characteristics and may be produced indigenously. Alcohols, being oxygenated fuel improve the combustion and reduce greenhouse gas emissions, thus enhancing agrarian economies and encouraging national economy as a whole. The objective of this paper is to investigate the thermal performance, exhaust emissions and combustion behaviour of small capacity compression ignition engine using fumigated ethanol. Fumigated ethanol at different flow rates is supplied to the cylinder during suction with the help of a simplified low cost ethanol fuelling system. With ethanol fumigation, brake thermal efficiency decreased upto 11.2% at low loads due to deteriorated combustion, whereas improved combustion increased efficiency up to 6% at higher loads, as compared to pure diesel. Maximum reduction of 22%, 41% and 27% respectively in nitrogen oxide, smoke and carbon-di-oxide emissions with simultaneous increase in hydrocarbon and carbon-mono-oxide emissions upto maximum of 144% and 139% respectively for different rates of ethanol fumigation have been observed, when compared to pure diesel operation. This is due to the changes in physico-chemical properties of air fuel mixture, viz combustion temperature, oxygen concentration, latent heat of vaporisation, fuel distribution, cetane number and ignition delay, that occurred with addition of

  1. Combustion of biodiesel in a large-scale laboratory furnace

    International Nuclear Information System (INIS)

    Pereira, Caio; Wang, Gongliang; Costa, Mário

    2014-01-01

    Combustion tests in a large-scale laboratory furnace were carried out to assess the feasibility of using biodiesel as a fuel in industrial furnaces. For comparison purposes, petroleum-based diesel was also used as a fuel. Initially, the performance of the commercial air-assisted atomizer used in the combustion tests was scrutinized under non-reacting conditions. Subsequently, flue gas data, including PM (particulate matter), were obtained for various flame conditions to quantify the effects of the atomization quality and excess air on combustion performance. The combustion data was complemented with in-flame temperature measurements for two representative furnace operating conditions. The results reveal that (i) CO emissions from biodiesel and diesel combustion are rather similar and not affected by the atomization quality; (ii) NO x emissions increase slightly as spray quality improves for both liquid fuels, but NO x emissions from biodiesel combustion are always lower than those from diesel combustion; (iii) CO emissions decrease rapidly for both liquid fuels as the excess air level increases up to an O 2 concentration in the flue gas of 2%, beyond which they remain unchanged; (iv) NO x emissions increase with an increase in the excess air level for both liquid fuels; (v) the quality of the atomization has a significant impact on PM emissions, with the diesel combustion yielding significantly higher PM emissions than biodiesel combustion; and (vi) diesel combustion originates PM with elements such as Cr, Na, Ni and Pb, while biodiesel combustion produces PM with elements such as Ca, Mg and Fe. - Highlights: • CO emissions from biodiesel and diesel tested are similar. • NO x emissions from biodiesel tested are lower than those from diesel tested. • Diesel tested yields significantly higher PM (particulate matter) emissions than biodiesel tested. • Diesel tested originates PM with Cr, Na, Ni and Pb, while biodiesel tested produces PM with Ca, Mg and Fe

  2. The effects of ethanol addition with waste pork lard methyl ester on performance, emission and combustion characteristics of a diesel engine

    Directory of Open Access Journals (Sweden)

    John Panneer Selvam Dharmaraj

    2014-01-01

    Full Text Available In the recent research, as a result of depletion of world petroleum reserves, considerable attention has been focused on the use of different alternative fuels in diesel engines. The present work aims to ensure the possibility of adding ethanol as an additive with animal fat biodiesel that is tested as an alternative fuel for diesel in a CI engine. In this study, biodiesel is obtained from waste pork lard by base-catalyzed transesterification with methanol when potassium hydroxide as catalyst. 2.5%, 5% and 7.5% by volume of ethanol is blended with neat biodiesel in order to improve performance and combustion characteristics of a diesel engine. The experimental work is carried out in a 3.7 kW, single cylinder, naturally aspirated, water cooled, direct injection diesel engine for different loads and at a constant speed of 1500 rpm. The performance, emission and combustion characteristics of biodiesel-ethanol blends are investigated by comparing them with neat biodiesel and standard diesel. The experimental test results showed that the combustion and performance characteristics improved with the increase in percentage of ethanol addition with biodiesel. When compared to neat biodiesel and standard diesel, an increase in brake thermal efficiency of 5.8% and 4.1% is obtained for BEB7.5 blend at full load of the engine. With the increase in percentage of ethanol fraction in the blends, peak cylinder pressure and the corresponding heat release rate are increased. Biodiesel-ethanol blends exhibit longer ignition delay and shorter combustion duration when compared to neat biodiesel. Optimum reduction in carbon monoxide, unburned hydrocarbon and smoke emission are attained while using BEB5 blend at full load of the engine. However, there is an adverse effect in case of nitrogen oxide emission.

  3. Homogeneous Charge Compression Ignition Combustion of Dimethyl Ether

    DEFF Research Database (Denmark)

    Pedersen, Troels Dyhr

    This thesis is based on experimental and numerical studies on the use of dimethyl ether (DME) in the homogeneous charge compression ignition (HCCI) combustion process. The first paper in this thesis was published in 2007 and describes HCCI combustion of pure DME in a small diesel engine. The tests...... were designed to investigate the effect of engine speed, compression ratio and equivalence ratio on the combustion timing and the engine performance. It was found that the required compression ratio depended on the equivalence ratio used. A lower equivalence ratio requires a higher compression ratio...... before the fuel is burned completely, due to lower in-cylinder temperatures and lower reaction rates. The study provided some insight in the importance of operating at the correct compression ratio, as well as the operational limitations and emission characteristics of HCCI combustion. HCCI combustion...

  4. Explaining the gap between theoretical peak performance and real performance for supercomputer architectures

    International Nuclear Information System (INIS)

    Schoenauer, W.; Haefner, H.

    1993-01-01

    The basic architectures of vector and parallel computers with their properties are presented. Then the memory size and the arithmetic operations in the context of memory bandwidth are discussed. For the exemplary discussion of a single operation micro-measurements of the vector triad for the IBM 3090 VF and the CRAY Y-MP/8 are presented. They reveal the details of the losses for a single operation. Then we analyze the global performance of a whole supercomputer by identifying reduction factors that bring down the theoretical peak performance to the poor real performance. The responsibilities of the manufacturer and of the user for these losses are dicussed. Then the price-performance ratio for different architectures in a snapshot of January 1991 is briefly mentioned. Finally some remarks to a user-friendly architecture for a supercomputer will be made. (orig.)

  5. Low emission turbulent technology for fuel combustion

    International Nuclear Information System (INIS)

    Finker, F. Z.; Kubyshkin, I. B.; Zakharov, B. Yu.; Akhmedov, D. B.; Sobchuk, Ch.

    1997-01-01

    The company 'POLITEKHENERGO' in co-operation and the Russian-Poland firm 'EnergoVIR' have performed investigations for modernization of the current existing boilers. A low emission turbulent technology has been used for the modernization of 10 industrial boilers. The reduction of NO x emissions is based on the following processes: 1) multistage combustion assured by two counter-deviated fluxes; 2) Some of the combustion facilities have an abrupt slope and a reduced air supply which leads to an intense separation of the fuel in the bottom part and a creation of a low-temperature combustion zone where the active restoration of the NO x takes part; 3) The influence of the top high-temperature zone on the NO x formation is small. Thus the 'sandwich' consisting of 'cold' and'hot' combustion layers provides a full rate combustion. This technique permits to: decrease of the NO x and CO x down to the European standard values;increase of the efficiency in 1-2%; obtain a stable coal combustion up to 97-98%; assure the large loading range (30 -100%); modernize and use the old boilers

  6. Study of experimental validation for combustion analysis of GOTHIC code

    International Nuclear Information System (INIS)

    Lee, J. Y.; Yang, S. Y.; Park, K. C.; Jeong, S. H.

    2001-01-01

    In this study, present lumped and subdivided GOTHIC6 code analyses of the premixed hydrogen combustion experiment at the Seoul National University and comparison with the experiment results. The experimental facility has 16367 cc free volume and rectangular shape. And the test was performed with unit equivalence ratio of the hydrogen and air, and with various location of igniter position. Using the lumped and mechanistic combustion model in GOTHIC6 code, the experiments were simulated with the same conditions. In the comparison between experiment and calculated results, the GOTHIC6 prediction of the combustion response does not compare well with the experiment results. In the point of combustion time, the lumped combustion model of GOTHIC6 code does not simulate the physical phenomena of combustion appropriately. In the case of mechanistic combustion model, the combustion time is predicted well, but the induction time of calculation data is longer than the experiment data remarkably. Also, the laminar combustion model of GOTHIC6 has deficiency to simulate combustion phenomena unless control the user defined value appropriately. And the pressure is not a proper variable that characterize the three dimensional effect of combustion

  7. Novel Active Combustion Control Valve

    Science.gov (United States)

    Caspermeyer, Matt

    2014-01-01

    This project presents an innovative solution for active combustion control. Relative to the state of the art, this concept provides frequency modulation (greater than 1,000 Hz) in combination with high-amplitude modulation (in excess of 30 percent flow) and can be adapted to a large range of fuel injector sizes. Existing valves often have low flow modulation strength. To achieve higher flow modulation requires excessively large valves or too much electrical power to be practical. This active combustion control valve (ACCV) has high-frequency and -amplitude modulation, consumes low electrical power, is closely coupled with the fuel injector for modulation strength, and is practical in size and weight. By mitigating combustion instabilities at higher frequencies than have been previously achieved (approximately 1,000 Hz), this new technology enables gas turbines to run at operating points that produce lower emissions and higher performance.

  8. Improving the performance and emission characteristics of a single cylinder diesel engine having reentrant combustion chamber using diesel and Jatropha methyl esters.

    Science.gov (United States)

    Premnath, S; Devaradjane, G

    2015-11-01

    The emissions from the Compression ignition (CI) engines introduce toxicity to the atmosphere. The undesirable carbon deposits from these engines are realized in the nearby static or dynamic systems such as vehicles, inhabitants, etc. The objective of this research work is to improve the performance and emission characteristics of a diesel engine in the modified re-entrant combustion chamber using a diesel and Jatropha methyl ester blend (J20) at three different injection pressures. From the literature, it is revealed that the shape of the combustion chamber and the fuel injection pressure have an impact on the performance and emission parameters of the CI engine. In this work, a re-entrant combustion chamber with three different fuel injection pressures (200, 220 and 240bars) has been used in the place of the conventional hemispherical combustion chamber for diesel and J20. From the experimental results, it is found that the re-entrant chamber improves the brake thermal efficiency of diesel and J20 in all the tested conditions. It is also found that the 20% blend of Jatropha methyl ester showed 4% improvement in the brake thermal efficiency in the re-entrant chamber at the maximum injection pressure. Environmental safety directly relates to the reduction in the undesirable effects on both living and non-living things. Currently environmental pollution is of major concern. Even with the stringent emission norms new methods are required to reduce the harmful effects from automobiles. The toxicity of carbon monoxide (CO) is well known. In the re-entrant combustion chamber, the amount of CO emission is reduced by 26% when compared with the conventional fuel operation of the engine. Moreover, the amount of smoke is reduced by 24% and hydrocarbons (HC) emission by 24%. Thus, the modified re-entrant combustion chamber reduces harmful pollutants such as unburned HC and CO as well as toxic smoke emissions. Copyright © 2015 Elsevier Inc. All rights reserved.

  9. Study of combustion properties of a solid propellant by highly time-resolved passive FTIR

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Liming; Zhang, Lin; Li, Yan; Liu, Bingping; Wang, Junde [Laboratory of Advanced Spectroscopy, Nanjing University of Science and Technology, Nanjing 210014 (China)

    2006-10-15

    With a time resolution of 0.125 s and a spectral resolution of 4 cm{sup -1}, emission spectra of the combustion process of a solid propellant were recorded by highly time-resolved passive FTIR. Some gaseous combustion products, such as H{sub 2}O, CO, CO{sub 2}, NO and HCl, were distinguished by the characteristic emission band of each molecule. The equation for flame temperature calculation based on the diatomic molecule emission fine structure theory was improved through judicious utilization of the spectral running number 'm' which makes the temperature measurement simpler and faster. Some combustion information of the solid propellant had been given including the characteristic spectral profile, the distribution of the absolute spectral energy, the distribution of the combustion flame temperature, and the concentration distributions of HCl and NO versus burning time. The results will provide theoretical and experimental bases for improving the formula and raising combustion efficiency of solid propellant, and developing the design of rocket motor, infrared guidance and antiguidance systems. (Abstract Copyright [2006], Wiley Periodicals, Inc.)

  10. Determination of performance and combustion characteristics of a diesel engine fueled with canola and waste palm oil methyl esters

    Energy Technology Data Exchange (ETDEWEB)

    Ozsezen, Ahmet Necati [Department of Automotive Engineering Technology, Kocaeli University, 41380 Izmit (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Izmit (Turkey); Canakci, Mustafa, E-mail: canakci@kocaeli.edu.t [Department of Automotive Engineering Technology, Kocaeli University, 41380 Izmit (Turkey); Alternative Fuels R and D Center, Kocaeli University, 41040 Izmit (Turkey)

    2011-01-15

    In this study, the performance, combustion and injection characteristics of a direct injection diesel engine have been investigated experimentally when it was fueled with canola oil methyl ester (COME) and waste (frying) palm oil methyl ester (WPOME). In order to determine the performance and combustion characteristics, the experiments were conducted at constant engine speeds under the full load condition of the engine. The results indicated that when the test engine was fueled with WPOME or COME instead of petroleum based diesel fuel (PBDF), the brake power reduced by 4-5%, while the brake specific fuel consumption increased by 9-10%. On the other hand, methyl esters caused reductions in carbon monoxide (CO) by 59-67%, in unburned hydrocarbon (HC) by 17-26%, in carbon dioxide (CO{sub 2}) by 5-8%, and smoke opacity by 56-63%. However, both methyl esters produced more nitrogen oxides (NO{sub x}) emissions by 11-22% compared with those of the PBDF over the speed range.

  11. Determination of performance and combustion characteristics of a diesel engine fueled with canola and waste palm oil methyl esters

    International Nuclear Information System (INIS)

    Ozsezen, Ahmet Necati; Canakci, Mustafa

    2011-01-01

    In this study, the performance, combustion and injection characteristics of a direct injection diesel engine have been investigated experimentally when it was fueled with canola oil methyl ester (COME) and waste (frying) palm oil methyl ester (WPOME). In order to determine the performance and combustion characteristics, the experiments were conducted at constant engine speeds under the full load condition of the engine. The results indicated that when the test engine was fueled with WPOME or COME instead of petroleum based diesel fuel (PBDF), the brake power reduced by 4-5%, while the brake specific fuel consumption increased by 9-10%. On the other hand, methyl esters caused reductions in carbon monoxide (CO) by 59-67%, in unburned hydrocarbon (HC) by 17-26%, in carbon dioxide (CO 2 ) by 5-8%, and smoke opacity by 56-63%. However, both methyl esters produced more nitrogen oxides (NO x ) emissions by 11-22% compared with those of the PBDF over the speed range.

  12. Experimental study on the influence of oxygen content in the combustion air on the combustion characteristics

    International Nuclear Information System (INIS)

    Bělohradský, Petr; Skryja, Pavel; Hudák, Igor

    2014-01-01

    This study was focused on the experimental investigation of the very promising combustion technology called as the oxygen-enhanced combustion (OEC), which uses the oxidant containing higher proportion of oxygen than in the atmospheric air, i.e. more than 21%. The work investigated and compared the characteristics of two OEC methods, namely the premix enrichment and air-oxy/fuel combustion, when the overall oxygen concentration was varied from 21% to 46%. The combustion tests were performed with the experimental two-gas-staged burner of low-NO x type at the burner thermal input of 750 kW for two combustion regimes – one-staged and two-staged combustion. The oxygen concentration in the flue gas was maintained in the neighborhood of 3% vol. (on dry basis). The aim of tests was to assess the impact of the oxidant composition, type of OEC method and fuel-staging on the characteristic combustion parameters in detail. The investigated parameters included the concentration of nitrogen oxides (NO x ) in the flue gas, flue gas temperature, heat flux to the combustion chamber wall, and lastly the stability, shape and dimensions of flame. It was observed that NO x emission is significantly lower when the air-oxy/fuel method is used compared to the premix enrichment method. Moreover, when the fuel was staged, NO x emission was below 120 mg/Nm 3 at all investigated oxygen flow rates. Increasing oxygen concentration resulted in higher heating intensity due to higher concentrations of CO 2 and H 2 O. The available heat at 46% O 2 was higher by 20% compared with that at 21% O 2 . - Highlights: • Premix-enrichment and air-oxy/fuel combustion methods were experimentally studied. • NO x increased sharply as oxygen concentration increased during PE tests. • NO x was below 120 mg/Nm 3 for all investigated oxygen flow rates in AO tests. • Radiative heat transfer was enhanced ca. 20% as O 2 concentration was increased. • OEC flames were observed stable, more luminous and

  13. The energetic performance of a novel hybrid solar thermal and chemical looping combustion plant

    International Nuclear Information System (INIS)

    Jafarian, Mehdi; Arjomandi, Maziar; Nathan, Graham J.

    2014-01-01

    Highlights: • A hybrid solar chemical looping combustion power cycle is reported. • The cycle is studied for two configurations, with and without an after-burner. • The oxygen carrier particles are used as storage medium for solar thermal energy. • Total solar shares of 41.4% and 60% are achieved with and without the after-burner. • Efficiencies of 50% and 44.0% are achieved with and without the after-burner. - Abstract: The overall energetic performance of a gas turbine combined cycle powered by a hybrid cycle between a solar thermal and a chemical looping combustion (CLC) system firing methane is reported for two configurations. In one case, the outlet from the air reactor is fed directly to a gas turbine, while in the other an after-burner, also firing methane, is added to increase the gas turbine inlet temperature. The cycle is simulated using Aspen Plus software for the average diurnal profile of normal irradiance for Port Augusta, South Australia. The first law efficiency, total solar absorption efficiency, average and peak fractional power boosts, total solar share, net solar to electrical efficiency, fraction of pressurised CO 2 , incremental CO 2 avoidance and the exergy efficiency for both cycles are reported. The calculations predict a first law efficiency of 50.0% for the cycle employing an after-burner, compared with 44.0% for that without the after-burner. However, this is achieved at the cost of decreasing the solar share from 60.0%, without the after-burner, to 41.4% with it. Also reported is the sensitivity analysis of performance to variations in key operating parameters. The sensitivity analysis shows that further improvements to the performance of the cycle are possible

  14. Techniques de combustion Combustin Techniques

    Directory of Open Access Journals (Sweden)

    Perthuis E.

    2006-11-01

    Full Text Available L'efficacité d'un processus de chauffage par flamme est étroitement liée à la maîtrise des techniques de combustion. Le brûleur, organe essentiel de l'équipement de chauffe, doit d'une part assurer une combustion complète pour utiliser au mieux l'énergie potentielle du combustible et, d'autre part, provoquer dans le foyer les conditions aérodynamiques les plus propices oux transferts de chaleur. En s'appuyant sur les études expérimentales effectuées à la Fondation de Recherches Internationales sur les Flammes (FRIF, au Groupe d'Étude des Flammes de Gaz Naturel (GEFGN et à l'Institut Français du Pétrole (IFP et sur des réalisations industrielles, on présente les propriétés essentielles des flammes de diffusion aux combustibles liquides et gazeux obtenues avec ou sans mise en rotation des fluides, et leurs répercussions sur les transferts thermiques. La recherche des températures de combustion élevées conduit à envisager la marche à excès d'air réduit, le réchauffage de l'air ou son enrichissement à l'oxygène. Par quelques exemples, on évoque l'influence de ces paramètres d'exploitation sur l'économie possible en combustible. The efficiency of a flame heating process is closely linked ta the mastery of, combustion techniques. The burner, an essential element in any heating equipment, must provide complete combustion sa as to make optimum use of the potential energy in the fuel while, at the same time, creating the most suitable conditions for heat transfers in the combustion chamber. On the basis of experimental research performed by FRIF, GEFGN and IFP and of industrial achievements, this article describesthe essential properties of diffusion flames fed by liquid and gaseous fuels and produced with or without fluid swirling, and the effects of such flames on heat transfers. The search for high combustion temperatures means that consideration must be given to operating with reduced excess air, heating the air or

  15. Effects of ignition parameters on combustion process of a rotary engine fueled with natural gas

    International Nuclear Information System (INIS)

    Fan, Baowei; Pan, Jianfeng; Liu, Yangxian; Zhu, Yuejin

    2015-01-01

    Highlights: • A 3-D simulation model based on the chemical reaction kinetics is established. • The tumble near the trailing spark plug is beneficial for the combustion rate. • The best position of the trailing spark plug is at the rear of the tumble zone. • An increase of the tumble effect time can improve the combustion rate. • Considering the rate of pressure rise, the best ignition timing is 50 °CA (BTDC). - Abstract: The side-ported rotary engine fueled with natural gas is a new, clean, efficient energy system. This work aims to numerically study the performance, combustion and emission characteristics of a side-ported rotary engine fueled with natural gas under different ignition positions and ignition timings. Simulations were performed using multi-dimensional software ANASYS Fluent. On the basis of the software, a three-dimensional dynamic simulation model was established by writing dynamic mesh programs and choosing a detailed reaction mechanism. The three-dimensional dynamic simulation model, based on the chemical reaction kinetics, was also validated by the experimental data. Meanwhile, further simulations were then conducted to investigate how to impact the combustion process by the coupling function between ignition operating parameter and the flow field inside the cylinder. Simulation results showed that in order to improve the combustion efficiency, the trailing spark plug should be located at the rear of the tumble zone and the ignition timing should be advanced properly. This was mainly caused by the trailing spark plug being located at the rear of the tumble zone, as it not only allowed the fuel in the rear of combustion chamber to be burnt without delay, but also permitted the acceleration of the flame propagation by the tumble. Meanwhile, with advanced ignition timing, the time between ignition timing and the timing of the tumble disappearance increased, which led to an increase of the tumble effect time used to improve the combustion

  16. Investigation of bluff-body micro-flameless combustion

    International Nuclear Information System (INIS)

    Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

    2014-01-01

    Highlights: • The temperature uniformity of the micro-flameless combustion increases when a triangular bluff-body is applied. • The velocity and temperature of exhaust gases are higher in micro-flameless combustion compared to the conventional mode. • The rate of fuel–oxidizer consumption in micro-flameless mode is lower than conventional micro-combustion. - Abstract: Characteristics of lean premixed conventional micro-combustion and lean non-premixed flameless regime of methane/air are investigated in this paper by solving three-dimensional governing equations. At moderate equivalence ratio (∅ = 0.5), standard k–ε and the eddy-dissipation concept are employed to simulate temperature distribution and combustion stability of these models. The effect of bluff-body on the temperature distribution of both conventional and flameless mode is developed. The results show that in the premixed conventional micro-combustion the stability of the flame is increased when a triangular bluff-body is applied. Moreover, micro-flameless combustion is more stable when bluff-body is used. Micro-flameless mode with bluff-body and 7% O 2 concentration (when N 2 is used as diluent) illustrated better performance than other cases. The maximum temperature in premixed conventional micro-combustion and micro-flameless combustion was recorded 2200 K and 1520 K respectively. Indeed, the flue gas temperature of conventional mode and flameless combustion was 1300 K and 1500 K respectively. The fluctuation of temperature in the conventional micro-combustor wall has negative effects on the combustor and reduces the lifetime of micro-combustor. However, in the micro-flameless mode, the wall temperature is moderate and uniform. The rate of fuel–oxidizer consumption in micro-flameless mode takes longer time and the period of cylinders recharging is prolonged

  17. Effects of memory rehearsal on driver performance: experiment and theoretical account.

    Science.gov (United States)

    Salvucci, Dario D; Beltowska, Joanna

    2008-10-01

    We report an experiment and a theoretical analysis concerning the effects of an exclusively cognitive task, specifically a memory rehearsal task, on driver performance. Although recent work on driver distraction has elucidated the sometimes significant effects of cognitive processing on driver performance, these studies have typically mixed cognitive with perceptual and motor processing, making it difficult to isolate the effects of cognitive processing alone. We asked participants to drive in a driving simulator during only the rehearsal stage of a serial-recall memory task while we measured their ability to maintain a central lane position and respond to the illumination of a lead vehicle's brake lights. Memory rehearsal significantly affected drivers' steering performance as measured by lateral deviation from lane center, and it also significantly affected drivers' response time to the braking stimulus for the higher load memory task. These results lend support to a theoretical account of cognitive distraction provided by threaded cognition theory in terms of a cognitive bottleneck in procedural processing, and they also suggest that consideration of task urgency may be important in accounting for performance trade-offs among concurrent tasks. The experiment augments the current understanding of cognitive driver distraction and suggests that even exclusively cognitive secondary tasks may sometimes affect driver performance.

  18. Proceedings of IEA combustion 2009 : IEA 31. task leaders meeting on energy conservation and emissions reduction in combustion

    International Nuclear Information System (INIS)

    2009-01-01

    The International Energy Agency (IEA) supports research and development in energy technology. This meeting provided a forum to discuss combustion processes, which is fundamental to achieving further improvements in fuel use efficiency, reducing the production of pollutants such as nitrogen oxides, and facilitating the transition to alternative fuels. The presentations demonstrated recent studies in improving the efficiency and fuel flexibility of automotive engines; improving the performance of industrial furnaces; emissions formation and control mechanisms; and fuel injection and fuel/air mixing. The conference also highlighted studies involving hydrogen combustion, alternative fuels, particulate diagnostics, fuel sprays, gas turbines, and advanced combustion processes such as homogeneous charge compression ignition (HCCI). The sessions were entitled: HCCI fuels; sprays; nanoparticle diagnostics; alternative fuels; hydrogen internal combustion engines; turbines; energy security; and collaborative task planning. All 45 presentations from the conference have been catalogued separately for inclusion in this database. refs., tabs., figs.

  19. Experimental and theoretical analysis of effects of atomic, diatomic and polyatomic inert gases in air and EGR on mixture properties, combustion, thermal efficiency and NOx emissions of a pilot-ignited NG engine

    International Nuclear Information System (INIS)

    Li, Weifeng; Liu, Zhongchang; Wang, Zhongshu; Dou, Huili

    2015-01-01

    Highlights: • The specific heat ratio of the mixture increases with increasing Ar. • The thermal efficiency increases first and then decreases with increasing Ar. • Mechanisms of reducing NOx emissions are different for different dilution gases. • A suitable inert gas should be used to meet different requirements. - Abstract: Argon (Ar), nitrogen (N_2) and carbon dioxide (CO_2), present in exhaust gas recirculation (EGR) and air, are common atomic, diatomic and polyatomic inert gases, separately. As dilution gases, they are always added into the intake charge to reduce nitrogen oxides (NOx) emissions, directly or along with EGR and air. This paper presents the effects of Ar, N_2 and CO_2 on mixture properties, combustion, thermal efficiency and NOx emissions of pilot-ignited natural gas engines. Thermodynamic properties of the air-dilution gas mixture with increasing dilution gases, including density, gas constant, specific heat ratio, specific heat capacity, heat capacity and thermal diffusivity, were analyzed theoretically using thermodynamic relations and ideal gas equations based on experimental results. The thermal and diluent effects of dilution gases on NOx emissions were investigated based on Arrhenius Law and Zeldovich Mechanism, experimentally and theoretically. The experiments were arranged based on an electronically controlled heavy-duty, 6-cylinder, turbocharged, pilot-ignited natural gas engine. The resulted show that adding different inert gases into the intake charge had different influences on the thermodynamic properties of the air-dilution gas mixture. No great change in combustion phase was found with increasing dilution ratio (DR) of Ar, while the flame development duration increased significantly and CA50 moved far away from combustion top dead center (TDC) obviously with increasing DR for both of N_2 and CO_2. Adding Ar was superior in maintaining high thermal efficiencies than CO_2 and N_2, but adding CO_2 was superior in maintaining

  20. Some Factors Affecting Combustion in an Internal-Combustion Engine

    Science.gov (United States)

    Rothrock, A M; Cohn, Mildred

    1936-01-01

    An investigation of the combustion of gasoline, safety, and diesel fuels was made in the NACA combustion apparatus under conditions of temperature that permitted ignition by spark with direct fuel injection, in spite of the compression ratio of 12.7 employed. The influence of such variables as injection advance angle, jacket temperature, engine speed, and spark position was studied. The most pronounced effect was that an increase in the injection advance angle (beyond a certain minimum value) caused a decrease in the extent and rate of combustion. In almost all cases combustion improved with increased temperature. The results show that at low air temperatures the rates of combustion vary with the volatility of the fuel, but that at high temperatures this relationship does not exist and the rates depend to a greater extent on the chemical nature of the fuel.

  1. Reduced NOX combustion method

    International Nuclear Information System (INIS)

    Delano, M.A.

    1991-01-01

    This patent describes a method for combusting fuel and oxidant to achieve reduced formation of nitrogen oxides. It comprises: It comprises: heating a combustion zone to a temperature at least equal to 1500 degrees F.; injecting into the heated combustion zone a stream of oxidant at a velocity within the range of from 200 to 1070 feet per second; injecting into the combustion zone, spaced from the oxidant stream, a fuel stream at a velocity such that the ratio of oxidant stream velocity to fuel stream velocity does not exceed 20; aspirating combustion gases into the oxidant stream and thereafter intermixing the aspirated oxidant stream and fuel stream to form a combustible mixture; combusting the combustible mixture to produce combustion gases for the aspiration; and maintaining the fuel stream substantially free from contact with oxidant prior to the intermixture with aspirated oxidant

  2. Direct synthesis of La9.33Si6O26 ultrafine powder via sol-gel self-combustion method

    International Nuclear Information System (INIS)

    Tian Changan; Liu Junliang; Cai Jun; Zeng Yanwei

    2008-01-01

    Single phase La 9.33 Si 6 O 26 ultrafine powder, as a kind of highly activated precursor to prepare medium-to-low temperature electrolyte for solid oxide fuel cells (SOFCs), has been successfully synthesized via a non-aqueous sol-gel and self-combustion approach from the starting materials: lanthanum nitrate (La(NO 3 ) 3 .6H 2 O), citric acid, ethylene glycol (EG), tetraethyl orthosilicate (TEOS) and ammonium nitrate. The details of gel's self-combustion were investigated by DTA-TG and the structural characterization of as-synthesized powder from self-combustion was performed by XRD and SEM. The results show that La 9.33 Si 6 O 26 single phase of apatite-type crystal structure can be directly synthesized by sol-gel self-combustion method without further calcinations on the condition that the molar ratio (R) of NO 3 - to citric acid and ethylene glycol being 6:1. Such powders composed of well-dispersed particles with an average size of 200 nm and a specific surface area of 5.54 m 2 /g. It can be sintered to 90% of its theoretical density at 1500 deg. C for 10 h, about 200 deg. C lower than the sintering temperature for the powder derived from traditional solid reactions. The sintered material has a thermal expansion coefficient of 9.2 x 10 -6 K -1 between room temperature and 800 deg. C

  3. Development and validation of double and single Wiebe function for multi-injection mode Diesel engine combustion modelling for hardware-in-the-loop applications

    International Nuclear Information System (INIS)

    Maroteaux, Fadila; Saad, Charbel; Aubertin, Fabrice

    2015-01-01

    Highlights: • Modelling of Diesel engine combustion with multi-injection mode was conducted. • Double and single Wiebe correlations for pilot, main and post combustion processes were calibrated. • Ignition delay time correlations have been developed and calibrated using experimental data for each injection. • The complete in-cylinder model has been applied successfully to real time simulations on HiL test bed. - Abstract: The improvement of Diesel engine performances in terms of fuel consumption and pollutant emissions has a huge impact on management system and diagnostic procedure. Validation and testing of engine performances can benefit from the use of theoretical models, for the reduction of development time and costs. Hardware in the Loop (HiL) test bench is a suitable way to achieve these objectives. However, the increasing complexity of management systems rises challenges for the development of very reduced physical models able to run in real time applications. This paper presents an extension of a previously developed phenomenological Diesel combustion model suitable for real time applications on a HiL test bench. In the earlier study, the modelling efforts have been targeted at high engine speeds with a very short computational time window, and where the engine operates with single injection. In the present work, a modelling of in-cylinder processes at low and medium engine speeds with multi-injection is performed. In order to reach an adequate computational time, the combustion progress during the pilot and main injection periods has been treated through a double Wiebe function, while the post combustion period has required a single Wiebe function. This paper describes the basic system models and their calibration and validation against experimental data. The use of the developed correlations of Wiebe coefficients and ignition delay times for each combustion phase, included in the in-cylinder crank angle global model, is applied for the prediction

  4. Heat transfer and combustion in microgravity; Mujuryokuka deno netsukogaku

    Energy Technology Data Exchange (ETDEWEB)

    Ito, K [Hokkaido University, Sapporo (Japan). Faculty of Engineering

    1994-09-05

    Examples of thermal engineering under gravity free state are introduced. When making semiconductor crystals, the thermal conductivity of the molten substance becomes important but in a microgravity environment where the thermal convection is suppressed, this value can be accurately measured. Although there are many unknown points regarding the thermal conductive mechanism of thermal control equipment elements under microgravity, theoretical analysis is being advanced. It is anticipated that the verification of this theory using liquid droplets will be made. The conveying of boiling heat under microgravity is suppressed because the bubbles stick to the heat source. When a non-azeotropic composition is used, Marangoni convection occurs, and the conveying is promoted. Since there is no thermal convection in microgravity combustion, diffusion dominates. In order to make the phenomenon clear, the free-fall tower can be utilized. A liquid droplet flame will become a complete, integrated, spherical flame. Vaporization coefficient and combustion velocity which are impossible to measure on the ground can be measured. In the case of metal fires occuring in space, the movement of metal dominates the combustion. In microgravity, dust coal will float in a stationary state so the process of combustion can be observed. It is believed that the diffusion flame of hydrocarbons will be thicker than the flame on the ground. 11 refs., 4 figs.

  5. AKR1C1 as a Biomarker for Differentiating the Biological Effects of Combustible from Non-Combustible Tobacco Products.

    Science.gov (United States)

    Woo, Sangsoon; Gao, Hong; Henderson, David; Zacharias, Wolfgang; Liu, Gang; Tran, Quynh T; Prasad, G L

    2017-05-03

    Smoking has been established as a major risk factor for developing oral squamous cell carcinoma (OSCC), but less attention has been paid to the effects of smokeless tobacco products. Our objective is to identify potential biomarkers to distinguish the biological effects of combustible tobacco products from those of non-combustible ones using oral cell lines. Normal human gingival epithelial cells (HGEC), non-metastatic (101A) and metastatic (101B) OSCC cell lines were exposed to different tobacco product preparations (TPPs) including cigarette smoke total particulate matter (TPM), whole-smoke conditioned media (WS-CM), smokeless tobacco extract in complete artificial saliva (STE), or nicotine (NIC) alone. We performed microarray-based gene expression profiling and found 3456 probe sets from 101A, 1432 probe sets from 101B, and 2717 probe sets from HGEC to be differentially expressed. Gene Set Enrichment Analysis (GSEA) revealed xenobiotic metabolism and steroid biosynthesis were the top two pathways that were upregulated by combustible but not by non-combustible TPPs. Notably, aldo-keto reductase genes, AKR1C1 and AKR1C2 , were the core genes in the top enriched pathways and were statistically upregulated more than eight-fold by combustible TPPs. Quantitative real time polymerase chain reaction (qRT-PCR) results statistically support AKR1C1 as a potential biomarker for differentiating the biological effects of combustible from non-combustible tobacco products.

  6. Dynamics of Water Absorption and Evaporation During Methanol Droplet Combustion in Microgravity

    Science.gov (United States)

    Hicks, Michael C.; Dietrich, Daniel L.; Nayagam, Vedha; Williams, Forman A.

    2012-01-01

    The combustion of methanol droplets is profoundly influenced by the absorption and evaporation of water, generated in the gas phase as a part of the combustion products. Initially there is a water-absorption period of combustion during which the latent heat of condensation of water vapor, released into the droplet, enhances its burning rate, whereas later there is a water-evaporation period, during which the water vapor reduces the flame temperature suffciently to extinguish the flame. Recent methanol droplet-combustion experiments in ambient environments diluted with carbon dioxide, conducted in the Combustion Integrated Rack on the International Space Station (ISS), as a part of the FLEX project, provided a method to delineate the water-absorption period from the water-evaporation period using video images of flame intensity. These were obtained using an ultra-violet camera that captures the OH* radical emission at 310 nm wavelength and a color camera that captures visible flame emission. These results are compared with results of ground-based tests in the Zero Gravity Facility at the NASA Glenn Research Center which employed smaller droplets in argon-diluted environments. A simplified theoretical model developed earlier correlates the transition time at which water absorption ends and evaporation starts. The model results are shown to agree reasonably well with experiment.

  7. Combustion, performance, and selective catalytic reduction of NOx for a diesel engine operated with combined tri fuel (H_2, CH_4, and conventional diesel)

    International Nuclear Information System (INIS)

    Abu-Jrai, Ahmad M.; Al-Muhtaseb, Ala'a H.; Hasan, Ahmad O.

    2017-01-01

    In this study, the effect of tri fuel (ULSD, H_2, and CH_4) operation under real exhaust gas conditions with different gaseous fuel compositions on the combustion characteristics, engine emissions, and selective catalytic reduction (SCR) after treatment was examined at low, medium, and high engine loads. Pt/Al_2O_3-SCR reactor was used and operated at different exhaust gas temperatures. Results revealed that at low load, the two gaseous fuels (H_2 and CH_4) have the same trend on combustion proccess, where both reduce the in-cylinder pressure and rate of heat release. At the high engine load there was a considerable influence appeared as an increase of the premixed combustion phase and a significant decrease of the total combustion duration. In terms of emissions, it was observed that at high engine load, fuels with high CH_4 content tend to reduce NOx formation, whereas, fuels with high H_2 content tend to reduce PM formation, moreover, combustion of tri fuel with 50:50 fuel mixture resulted in lower BSFC compared to the other ratios and hence, the best engine efficiency. The hydrocarbon-SCR catalyst has shown satisfactory performance in NOx reduction under real diesel exhaust gas in a temperature window of 180–280 °C for all engine loads. - Highlights: • Effect of tri fuel (ULSD, H_2, CH_4) on combustion and engine emissions was examined. • Fuel with high CH_4 content (H50-M50 and H25-M75) tend to reduce NOx formation. • Fuel with high H_2 content (H75-M25 and H50-M50) tend to reduce PM formation. • Increasing the percentage of H_2 in the feed gas improved the NO_x reduction. • The hydrocarbon-SCR catalyst has shown satisfactory performance in NO_x reduction.

  8. Method and device for diagnosing and controlling combustion instabilities in internal combustion engines operating in or transitioning to homogeneous charge combustion ignition mode

    Science.gov (United States)

    Wagner, Robert M [Knoxville, TN; Daw, Charles S [Knoxville, TN; Green, Johney B [Knoxville, TN; Edwards, Kevin D [Knoxville, TN

    2008-10-07

    This invention is a method of achieving stable, optimal mixtures of HCCI and SI in practical gasoline internal combustion engines comprising the steps of: characterizing the combustion process based on combustion process measurements, determining the ratio of conventional and HCCI combustion, determining the trajectory (sequence) of states for consecutive combustion processes, and determining subsequent combustion process modifications using said information to steer the engine combustion toward desired behavior.

  9. Air fuel ratio detector corrector for combustion engines using adaptive neurofuzzy networks

    Directory of Open Access Journals (Sweden)

    Nidhi Arora

    2013-07-01

    Full Text Available A perfect mix of the air and fuel in internal combustion engines is desirable for proper combustion of fuel with air. The vehicles running on road emit harmful gases due to improper combustion. This problem is severe in heavy vehicles like locomotive engines. To overcome this problem, generally an operator opens or closes the valve of fuel injection pump of locomotive engines to control amount of air going inside the combustion chamber, which requires constant monitoring. A model is proposed in this paper to alleviate combustion process. The method involves recording the time-varying flow of fuel components in combustion chamber. A Fuzzy Neural Network is trained for around 40 fuels to ascertain the required amount of air to form a standard mix to produce non-harmful gases and about 12 fuels are used for testing the network’s performance. The network then adaptively determines the additional/subtractive amount of air required for proper combustion. Mean square error calculation ensures the effectiveness of the network’s performance.

  10. Combustion in microgravity: The French contribution

    Science.gov (United States)

    Prud'homme, Roger; Legros, Guillaume; Torero, José L.

    2017-01-01

    Microgravity (drop towers, parabolic flights, sounding rockets and space stations) are particularly relevant to combustion problems given that they show high-density gradients and in many cases weak forced convection. For some configurations where buoyancy forces result in complex flow fields, microgravity leads to ideal conditions that correspond closely to canonical problems, e.g., combustion of a spherical droplet in a far-field still atmosphere, Emmons' problem for flame spreading over a solid flat plate, deflagration waves, etc. A comprehensive chronological review on the many combustion studies in microgravity was written first by Law and Faeth (1994) and then by F.A. Williams (1995). Later on, new recommendations for research directions have been delivered. In France, research has been managed and supported by CNES and CNRS since the creation of the microgravity research group in 1992. At this time, microgravity research and future activities contemplated the following: Droplets: the "D2 law" has been well verified and high-pressure behavior of droplet combustion has been assessed. The studies must be extended in two main directions: vaporization in mixtures near the critical line and collective effects in dense sprays. Flame spread: experiments observed blue flames governed by diffusion that are in accordance with Emmons' theory. Convection-dominated flames showed significant departures from the theory. Some theoretical assumptions appeared controversial and it was noted that radiation effects must be considered, especially when regarding the role of soot production in quenching. Heterogeneous flames: two studies are in progress, one in Poitiers and the other in Marseilles, about flame/suspension interactions. Premixed and triple flames: the knowledge still needs to be complemented. Triple flames must continue to be studied and understanding of "flame balls" still needs to be addressed.

  11. Co-combustion of waste materials using fluidized bed technology

    Energy Technology Data Exchange (ETDEWEB)

    M. Lopes; I. Gulyurtlu; P. Abelha; T. Crujeira; D. Boavida; I. Cabrita [INETI-DEECA, Lisbon (Portugal)

    2004-07-01

    There is growing interest in using renewable fuels in order to sustain the CO{sub 2} accumulation. Several waste materials can be used as coal substitutes as long as they contain significant combustible matter, as for example MSW and sewage sludge. Besides the outcome of the energetic valorization of such materials, combustion must be regarded as a pre-treatment process, contributing to the safe management of wastes. Landfilling is an expensive management option and requires a previous destruction of the organic matter present in residues, since its degradation generates greenhouse gases and produces acidic organic leachates. Fluidized bed combustion is a promising technology for the use of mixtures of coal and combustible wastes. This paper presents INETI's experience in the co-combustion of coal with this kind of residues performed in a pilot fluidized bed. Both the RDF (from MSW and sewage sludge) and sewage sludge combustion problems were addressed, relating the gaseous emissions, the behaviour of metals and the leachability of ashes and a comparison was made between co-combustion and mono-combustion in order to verify the influence of the utilization of coal. 9 refs., 1 fig., 3 tabs.

  12. Performance of calcium manganate as oxygen carrier in chemical looping combustion of biochar in a 10 kW pilot

    International Nuclear Information System (INIS)

    Schmitz, Matthias; Linderholm, Carl Johan

    2016-01-01

    Highlights: • A manganese-based perovskite material was used as oxygen carrier in chemical looping combustion. • The oxygen carrier’s performance was superior to materials previously tested in this reactor throughout the testing period. • Under stable conditions, oxygen demand was as low as 2.1% with a carbon capture efficiency of up to 98%. • No signs of agglomeration were detected. • Gaseous oxygen was released at all relevant fuel reactor temperatures. - Abstract: Chemical looping combustion (CLC) and chemical looping with oxygen uncoupling (CLOU) are carbon capture technologies which achieve gas separation by means of cycling oxidation and reduction of a solid oxygen carrier. In this study, the performance and CLOU properties of an oxygen carrier with perovskite structure, CaMn_0_._9Mg_0_._1O_3_−_δ_, were investigated in a 10 kW pilot. The fuel consisted of biochar with very low sulphur content. Around 37 h of operation with fuel were carried out in the 10 kW chemical looping combustor. Previous operational experience in this unit has been achieved using different natural minerals as oxygen carrier – mainly ilmenite and manganese ore. Parametric studies performed in this work included variation of fuel flow, solids circulation rate, temperature and fluidization gas in the fuel reactor. The oxygen carrier was exposed to a total 73 h of hot fluidization (T > 600 °C). No hard particle agglomerations were formed during the experiments. An oxygen demand as low as 2.1% could be reached under stable operating conditions, with a carbon capture efficiency of up to 98%. CLOU properties were observed at all fuel reactor temperatures, ensuring stable operation even without steam as gasification agent present in the fuel reactor. The results suggest that CaMn_0_._9Mg_0_._1O_3_−_δ is suitable for the use as oxygen carrier in chemical looping combustion of solid biochar and offers higher gas conversion than previously tested materials without CLOU

  13. The Diesel Combustion Collaboratory: Combustion Researchers Collaborating over the Internet

    Energy Technology Data Exchange (ETDEWEB)

    C. M. Pancerella; L. A. Rahn; C. Yang

    2000-02-01

    The Diesel Combustion Collaborator (DCC) is a pilot project to develop and deploy collaborative technologies to combustion researchers distributed throughout the DOE national laboratories, academia, and industry. The result is a problem-solving environment for combustion research. Researchers collaborate over the Internet using DCC tools, which include: a distributed execution management system for running combustion models on widely distributed computers, including supercomputers; web-accessible data archiving capabilities for sharing graphical experimental or modeling data; electronic notebooks and shared workspaces for facilitating collaboration; visualization of combustion data; and video-conferencing and data-conferencing among researchers at remote sites. Security is a key aspect of the collaborative tools. In many cases, the authors have integrated these tools to allow data, including large combustion data sets, to flow seamlessly, for example, from modeling tools to data archives. In this paper the authors describe the work of a larger collaborative effort to design, implement and deploy the DCC.

  14. Hydrogen combustion modelling in large-scale geometries

    International Nuclear Information System (INIS)

    Studer, E.; Beccantini, A.; Kudriakov, S.; Velikorodny, A.

    2014-01-01

    Hydrogen risk mitigation issues based on catalytic recombiners cannot exclude flammable clouds to be formed during the course of a severe accident in a Nuclear Power Plant. Consequences of combustion processes have to be assessed based on existing knowledge and state of the art in CFD combustion modelling. The Fukushima accidents have also revealed the need for taking into account the hydrogen explosion phenomena in risk management. Thus combustion modelling in a large-scale geometry is one of the remaining severe accident safety issues. At present day there doesn't exist a combustion model which can accurately describe a combustion process inside a geometrical configuration typical of the Nuclear Power Plant (NPP) environment. Therefore the major attention in model development has to be paid on the adoption of existing approaches or creation of the new ones capable of reliably predicting the possibility of the flame acceleration in the geometries of that type. A set of experiments performed previously in RUT facility and Heiss Dampf Reactor (HDR) facility is used as a validation database for development of three-dimensional gas dynamic model for the simulation of hydrogen-air-steam combustion in large-scale geometries. The combustion regimes include slow deflagration, fast deflagration, and detonation. Modelling is based on Reactive Discrete Equation Method (RDEM) where flame is represented as an interface separating reactants and combustion products. The transport of the progress variable is governed by different flame surface wrinkling factors. The results of numerical simulation are presented together with the comparisons, critical discussions and conclusions. (authors)

  15. Proceedings of the 2006 Combustion Institute Canadian Section spring technical meeting

    International Nuclear Information System (INIS)

    Devaud, C.; Weckman, E.; Lam, C.; Spike, E.

    2006-01-01

    This conference provided a networking opportunity for academic, government and industrial combustion researchers from across Canada. All aspects of combustion were discussed, particularly those related to new engine technologies that reduce exhaust gas emissions while maintaining performance. Major engine operating and fuelling control parameters that improve combustion efficiency were identified. The conference was divided into several sessions dealing with combustion emissions and pollutants such as soot and particulates; alternative fuels including biofuels and fuel cells; chemical kinetics; droplet and spray combustion; combustion synthesis of materials; detonations, explosions, fires, flammability, flares and incineration; environmental issues and hazard analysis; and, numerical modeling and simulation. The conference featured 61 presentations, of which 39 have been catalogued separately for inclusion in this database

  16. Surface kinetics for catalytic combustion of hydrogen-air mixtures on platinum at atmospheric pressure in stagnation flows

    Science.gov (United States)

    Ikeda, H.; Sato, J.; Williams, F. A.

    1995-03-01

    Experimental studies of the combustion of premixed hydrogen-air mixtures impinging on the surface of a heated platinum plate at normal atmospheric pressure were performed and employed to draw inferences concerning surface reaction mechanisms and rate parameters applicable under practical conditions of catalytic combustion. Plate and gas temperatures were measured by thermocouples, and concentration profiles of major stable species in the gas were measured by gas-chromatographic analyses of samples withdrawn by quartz probes. In addition, ignition and extinction phenomena were recorded and interpreted with the aid of a heat balance at the surface and a previous flow-field analysis of the stagnation-point boundary layer. From the experimental and theoretical results, conclusions were drawn concerning the surface chemical-kinetic mechanisms and values of the elementary rate parameters that are consistent with the observations. In particular, the activation energy for the surface oxidation step H + OH → H 2O is found to be appreciably less at these high surface coverages than in the low-coverage limit.

  17. Oxyfuel combustion for below zero CO{sub 2} emissions

    Energy Technology Data Exchange (ETDEWEB)

    Boeg Toftegaard, M; Hansen, Kim G; Fisker, D [DONG Energy Power, Hvidovre (Denmark); Brix, J; Brun Hansen, B; Putluru, S S.R.; Jensen, Peter Arendt; Glarborg, Peter; Degn Jensen, A [Technical Univ. of Denmark. CHEC Research Centre, Kgs. Lyngby (Denmark); Montgomery, M [Technical Univ. of Denmark. DTU Mechanical Engineering, Kgs. Lyngby (Denmark)

    2011-07-01

    The reduction of CO{sub 2} emissions is of highest concern in relation to limiting the anthropogenic impacts on the environment. Primary focus has gathered on the large point sources of CO{sub 2} emissions constituted by large heat and power stations and other heavy, energy-consuming industry. Solutions are sought which will enable a significant reduction of the anthropogenic CO{sub 2} emissions during the transformation period from the use of fossil fuels to renewable sources of energy. Carbon capture and storage (CCS) has the potential to significantly reduce CO{sub 2} emissions from power stations while allowing for the continuous utilisation of the existing energy producing system in the transformation period. Oxyfuel combustion is one of the possible CCS technologies which show promising perspectives for implementation in industrial scale within a relatively short period of time. Oxyfuel combustion deviates from conventional combustion in air by using a mixture of pure oxygen and recirculated flue gas as the combustion medium thereby creating a flue gas highly concentrated in CO{sub 2} making the capture process economically more feasible compared to technologies with capture from more dilute CO{sub 2} streams. This project has investigated a number of the fundamental and practical issues of the oxyfuel combustion process by experimental, theoretical, and modelling investigations in order to improve the knowledge of the technology. The subjects investigated cover: general combustion characteristics of coal and biomass (straw) and mixtures thereof, formation and emission of pollutants, ash characteristics, flue gas cleaning for SO{sub 2} by wet scrubbing with limestone and for NO{sub x} by selective catalytic reduction (SCR), corrosion of boiler heat transfer surfaces, operation and control of large suspension-fired boilers, and the perspectives for the implementation of oxyfuel combustion s a CO{sub 2} sequestration solution in the Danish power production

  18. Studies of combustion kinetics and mechanisms

    Energy Technology Data Exchange (ETDEWEB)

    Gutman, D. [Catholic Univ. of America, Washington, DC (United States)

    1993-12-01

    The objective of the current research is to gain new quantitative knowledge of the kinetics and mechanisms of polyatomic free radicals which are important in hydrocarbon combustion processes. The special facility designed and built for these (which includes a heatable tubular reactor coupled to a photoionization mass spectrometer) is continually being improved. Where possible, these experimental studies are coupled with theoretical ones, sometimes conducted in collaboration with others, to obtain an improved understanding of the factors determining reactivity. The decomposition of acetyl radicals, isopropyl radicals, and n-propyl radicals have been studied as well as the oxidation of methylpropargyl radicals.

  19. Gasoline Combustion Fundamentals DOE FY17 Report

    Energy Technology Data Exchange (ETDEWEB)

    Ekoto, Isaac W. [Sandia National Lab. (SNL-CA), Livermore, CA (United States)

    2017-11-01

    Advanced automotive gasoline engines that leverage a combination of reduced heat transfer, throttling, and mechanical losses; shorter combustion durations; and higher compression and mixture specific heat ratios are needed to meet aggressive DOE VTP fuel economy and pollutant emission targets. Central challenges include poor combustion stability at low-power conditions when large amounts of charge dilution are introduced and high sensitivity of conventional inductive coil ignition systems to elevated charge motion and density for boosted high-load operation. For conventional spark ignited operation, novel low-temperature plasma (LTP) or pre-chamber based ignition systems can improve dilution tolerances while maintaining good performance characteristics at elevated charge densities. Moreover, these igniters can improve the control of advanced compression ignition (ACI) strategies for gasoline at low to moderate loads. The overarching research objective of the Gasoline Combustion Fundamentals project is to investigate phenomenological aspects related to enhanced ignition. The objective is accomplished through targeted experiments performed in a single-cylinder optically accessible research engine or an in-house developed optically accessible spark calorimeter (OASC). In situ optical diagnostics and ex situ gas sampling measurements are performed to elucidate important details of ignition and combustion processes. Measurements are further used to develop and validate complementary high-fidelity ignition simulations. The primary project audience is automotive manufacturers, Tier 1 suppliers, and technology startups—close cooperation has resulted in the development and execution of project objectives that address crucial mid- to long-range research challenges.

  20. Influence of the combustion chamber during the transient performance of gas turbines; Influencias da camara de combustao durante o transitorio de turbinas a gas

    Energy Technology Data Exchange (ETDEWEB)

    Cunha Alves, M.A. da [Centro Tecnico Aeroespacial, Sao Jose dos Campos, SP (Brazil). Inst. de Pesquisas e Desenvolvimento

    1991-12-31

    It has been realised that heat transfer and others secondary effects have an important influence on the transient performance of a gas turbine, but until very recently, modelling was carried out either assuming adiabatic conditions, or using expedient but unrealistic models to simulate these effects. This work describes the effects of combustion chamber heat storage and of dead time lag of the combustion process, during a gas turbine transient. These effects have been investigated and the analysis has indicated that these effects do not play an important role in the transient performance of the engine analysed, but in certain circumstances they may become important. (author). 5 refs., 4 figs.

  1. Effect of swirl on the performance and combustion of a biogas fuelled spark ignition engine

    International Nuclear Information System (INIS)

    Porpatham, E.; Ramesh, A.; Nagalingam, B.

    2013-01-01

    Highlights: • Tests were conducted on a biogas fuelled SI engine with normal and masked valve. • Improvement in brake power and brake thermal efficiency with masked valve. • Lean misfire limit is extended with enhanced swirl from 0.68 to 0.65. • Enhanced swirl decreases HC level from1530 ppm to 1340 ppm and increases NO emission from 2250 ppm to 3440 ppm. • The reduction in ignition delay and higher heat release rate with enhanced swirl. - Abstract: The influence of swirl on the performance, emissions and combustion in a constant speed Spark Ignition (SI) engine was studied experimentally. A single cylinder diesel engine was modified to operate as a biogas operated spark ignition engine. The engine was operated at 1500 rpm at throttle opening of 25% and 100% at various equivalence ratios. The tests covered a range of equivalence ratios from rich to lean operating limits and also at an optimum compression ratio of 13:1 with normal and masked intake valve to enhance swirl. The spark timing was set to MBT (Minimum advance for Best Torque). It was found that masked valve configuration enhanced the power output and brake thermal efficiency at full throttle. The lean limit of combustion also got extended. Heat release rates indicated enhanced combustion rates with masked valve, which are mainly responsible for the improvement in thermal efficiency. NO level increased with masked valve as compared to normal configuration. The spark timings were to be retarded by about 6 °CA and 4 °CA when compared to normal configuration at 25% and 100% throttle respectively

  2. New class of combustion processes

    International Nuclear Information System (INIS)

    Merzhanov, A.G.; Borovinskaya, I.P.

    1975-01-01

    A short review is given of the results of work carried out since 1967 on studying the combustion processes caused by the interaction of chemical elements in the condensed phase and leading to the formation of refractory compounds. New phenomena and processes are described which are revealed when investigating the combustion of the systems of this class, viz solid-phase combustion, fast combustion in the condensed phase, filtering combustion, combustion in liquid nitrogen, spinning combustion, self-oscillating combustion, and repeated combustion. A new direction in employment of combustion processes is discussed, viz. a self-propagating high-temperature synthesis of refractory nitrides, carbides, borides, silicides and other compounds

  3. Experimental validation for combustion analysis of GOTHIC code in 2-dimensional combustion chamber

    International Nuclear Information System (INIS)

    Lee, J. W.; Yang, S. Y.; Park, K. C.; Jung, S. H.

    2002-01-01

    In this study, the prediction capability of GOTHIC code for hydrogen combustion phenomena was validated with the results of two-dimensional premixed hydrogen combustion experiment executed by Seoul National University. The experimental chamber has about 24 liter free volume (1x0.024x1 m 3 ) and 2-dimensional rectangular shape. The test were preformed with 10% hydrogen/air gas mixture and conducted with combination of two igniter positions (top center, top corner) and two boundary conditions (bottom full open, bottom right half open). Using the lumped parameter and mechanistic combustion model in GOTHIC code, the SNU experiments were simulated under the same conditions. The GOTHIC code prediction of the hydrogen combustion phenomena did not compare well with the experimental results. In case of lumped parameter simulation, the combustion time was predicted appropriately. But any other local information related combustion phenomena could not be obtained. In case of mechanistic combustion analysis, the physical combustion phenomena of gas mixture were not matched experimental ones. In boundary open cases, the GOTHIC predicted very long combustion time and the flame front propagation could not simulate appropriately. Though GOTHIC showed flame propagation phenomenon in adiabatic calculation, the induction time of combustion was still very long compare with experimental results. Also, it was found that the combustion model of GOTHIC code had some weak points in low concentration of hydrogen combustion simulation

  4. Experimental validation of combustion control with multi-pulse fuel injection

    NARCIS (Netherlands)

    Luo, X.; Velayutham, S.; Willems, F.P.T.

    2017-01-01

    Closed-loop combustion control helps to achieve precise fuel injection and robust engine performance against disturbances. The controller design complexity increases greatly with larger number of fuel injection pulses due to the coupled influence of changing individual pulse on the combustion

  5. Combustion characteristics, performance and exhaust emissions of a diesel engine fueled with a waste cooking oil biodiesel mixture

    International Nuclear Information System (INIS)

    Can, Özer

    2014-01-01

    Highlights: • High quality biodiesel fuels can be produced by using different waste cooking oils. • Biodiesel fuel blends (in 5 and 10% vol) can be used without any negative effects. • Effects of biodiesel addition on the combustion and exhaust emissions were investigated. - Abstract: In this study, a mixture of biodiesel fuels produced from two different kinds of waste cooking oils was blended in 5% and 10% with No. 2 diesel fuel. The biodiesel/No. 2 diesel fuel blends were tested in a single-cylinder, direct injection, four-stroke, natural aspirated diesel engine under four different engine loads (BMEP 0.48–0.36–0.24–0.12 MPa) and 2200 rpm engine speed. Despite of the earlier start of injection, the detailed combustion and engine performance results showed that the ignition delay with the biodiesel addition was decreased for the all engine loads with the earlier combustion timings due to higher cetane number of biodiesel fuel. Meanwhile the maximum heat release rate and the in-cylinder pressure rise rate were slightly decreased and the combustion duration was generally increased with the biodiesel addition. However, significant changings were not observed on the maximum in-cylinder pressures. In addition, it was observed that the indicated mean effective pressure values were slightly varied depending on the start of combustion timing and the center of heat release location. It was found that 5% and 10% biodiesel fuel addition resulted in slightly increment on break specific fuel consumption (up to 4%) and reduction on break thermal efficiency (up to 2.8%). The biodiesel additions also increased NO x emissions up to 8.7% and decreased smoke and total hydrocarbon emissions for the all engine loads. Although there were no significant changes on CO emissions at the low and medium engine loads, some reductions were observed at the full engine load. Also, CO 2 emissions were slightly increased for the all engine loads

  6. Numerical analysis of loads effect on combustion performance and NO{sub x} emissions of a 220 MW pulverized coal boiler

    Energy Technology Data Exchange (ETDEWEB)

    Li, Jun; Yang, Weihong; Blasiak, Wlodzimierz [Royal Institute of Technology (KTH), Stockholm (Sweden). Div. of Energy and Furnace Technology; Jankowski, Radoslaw; Kotecki, Michal; Szewczyk, Dariusz [Industrial Combustion Systems (ICS) Company, Poznan (Poland); Brzdekiewicz, Artur [Remak-Rozruch SA, Opole (Poland)

    2013-07-01

    This paper presents numerical study on the combustion performance and NO{sub x} emissions of a 220 MW pulverized coal boiler. Three different loads have been simulated with combusting coal, 200, 170 and 140 MW, respectively. In order to get as precise as possible numerical analysis results, two-step simulation method has been adopted in this work, namely, air supply system simulation and furnace simulation. After air supply system simulation, the results have been taken as the initial and boundary conditions for furnace simulation. The comparison between the measured values and predicted results from 200 MW case shows much better agreement. According to the simulation results, the adopted two-step simulation method is reasonable and suitable for predicting the characters of the flow and combustion process. It is concluded that the distributions of temperature, O{sub 2} and CO concentration inside furnace with different loads shows good similarly. The total NOx emissions decreased with the boiler load reducing, and fuel NO{sub x} has the same trend as total NO{sub x}, and fuel NO{sub x} account for about 66% in total NO{sub x} in all the three cases. More important, thermal NO{sub x} slowly decreased with the rise of boiler load. More detailed results presented in this paper enhance the understanding of combustion processes and complex flow patterns of front-wall pulverized coal boilers.

  7. Investigation of Bio-Diesel Fueled Engines under Low-Temperature Combustion Strategies

    Energy Technology Data Exchange (ETDEWEB)

    Chia-fon F. Lee; Alan C. Hansen

    2010-09-30

    In accordance with meeting DOE technical targets this research was aimed at developing and optimizing new fuel injection technologies and strategies for the combustion of clean burning renewable fuels in diesel engines. In addition a simultaneous minimum 20% improvement in fuel economy was targeted with the aid of this novel advanced combustion system. Biodiesel and other renewable fuels have unique properties that can be leveraged to reduce emissions and increase engine efficiency. This research is an investigation into the combustion characteristics of biodiesel and its impacts on the performance of a Low Temperature Combustion (LTC) engine, which is a novel engine configuration that incorporates technologies and strategies for simultaneously reducing NOx and particulate emissions while increasing engine efficiency. Generating fundamental knowledge about the properties of biodiesel and blends with petroleum-derived diesel and their impact on in-cylinder fuel atomization and combustion processes was an important initial step to being able to optimize fuel injection strategies as well as introduce new technologies. With the benefit of this knowledge experiments were performed on both optical and metal LTC engines in which combustion and emissions could be observed and measured under realistic conditions. With the aid these experiments and detailed combustion models strategies were identified and applied in order to improve fuel economy and simultaneously reduce emissions.

  8. Enhanced RAMAC performance in subdetonative propulsion mode with semi-combustible projectile

    Energy Technology Data Exchange (ETDEWEB)

    Legendre, J.F.; Giraud, M. [French-German Res. Inst., Saint-Louis (France)

    2000-11-01

    Investigations are carried out at ISL to determine the experimental conditions required to accelerate a projectile in the mass range from 1.5 to 2 kg up to a muzzle velocity of 3 km/s while keeping the maximum acceleration below 40,000 g. Therefore, two smooth-bore ram-accelerators denoted RAMAC 30-II and RAMAC 90, in caliber 30 and 90 mm respectively, are being operated in the thermally choked propulsion mode. Different material configurations for the projectile afterbody have been investigated, while keeping an aluminum nose cone. Besides afterbodies made of aluminum or magnesium alloy only, a third configuration is presented relying on a short magnesium part fitted to the base of an aluminum afterbody. This configuration denoted as ''semi-combustible'' is designed so that magnesium particles are steadily injected and burnt-out within the combustion zone at the base, therefore providing an additional heat release and consequently a significantly greater forward thrust. Experimental results achieved in both 30 and 90 mm along a 300-caliber-long ram-section and using up to three different gaseous mixtures are presented. To date, for a given semi-combustible projectile and an injection velocity into the ram-section of 1380 m/s, a maximum muzzle velocity of 2380 m/s has been achieved in RAMAC 30-II and 2180 m/s in RAMAC 90, the initial projectile mass being 69 g and 1608 g respectively. (orig.)

  9. Preliminary assessment of combustion modes for internal combustion wave rotors

    Science.gov (United States)

    Nalim, M. Razi

    1995-01-01

    Combustion within the channels of a wave rotor is examined as a means of obtaining pressure gain during heat addition in a gas turbine engine. Several modes of combustion are considered and the factors that determine the applicability of three modes are evaluated in detail; premixed autoignition/detonation, premixed deflagration, and non-premixed compression ignition. The last two will require strong turbulence for completion of combustion in a reasonable time in the wave rotor. The compression/autoignition modes will require inlet temperatures in excess of 1500 R for reliable ignition with most hydrocarbon fuels; otherwise, a supplementary ignition method must be provided. Examples of combustion mode selection are presented for two core engine applications that had been previously designed with equivalent 4-port wave rotor topping cycles using external combustion.

  10. Fuel oil combustion with low production of nitrogen oxides; Combustion de combustoleo con baja produccion de oxidos de nitrogeno

    Energy Technology Data Exchange (ETDEWEB)

    Escalera Campoverde, Rogelio [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1998-09-01

    This work presents the results of the theoretical-experimental study of the effects of the secondary air jet directed perpendicularly to the flame axis in the fuel oil combustion in a 500 Kw furnace. The main purpose of this study was to obtain low nitrogen oxides (NO{sub x}) emissions without increasing the CO, which is observed in low NO{sub x} conventional burners. The experimental results showed a significative reduction of the NO{sub x} and of the CO, from 320 to 90 ppm and from 50 ppm to negligible values, respectively. A commercial computational code of fluid dynamics was employed for modeling the combustion in base line conditions, without secondary air and with the injection of secondary air. The experimental results were compared with calculated ones. [Espanol] En este trabajo se presentan los resultados del estudio teorico experimental de los efectos de los chorro de aire secundario dirigidos en forma perpendicular al eje de la flama en la combustion del combustoleo en un horno de 500 kW. El proposito principal del estudio fue obtener bajas emisiones de oxidos de nitrogeno (NO{sub x}) sin incrementar el CO, lo cual se observa en quemadores convencionales de bajo NO{sub x}. Los resultados experimentales demostraron una reduccion significativa del NO{sub x} y del CO: de 320 a 90 ppm y de 50 ppm a valores despreciables, respectivamente. Se empleo un codigo computacional comercial de dinamica de fluidos para modelar la combustion en condiciones de linea base, sin aire secundario, y con la inyeccion del aire secundario. Se comparan resultados experimentales con los calculados.

  11. Effect of flue gas recirculation during oxy-fuel combustion in a rotary cement kiln

    International Nuclear Information System (INIS)

    Granados, David A.; Chejne, Farid; Mejía, Juan M.; Gómez, Carlos A.; Berrío, Ariel; Jurado, William J.

    2014-01-01

    The effect of Flue Gas Recirculation (FGR) during Oxy-Fuel Combustion in a Rotary Cement Kiln was analyzed by using a CFD model applied to coal combustion process. The CFD model is based on 3D-balance equations for mass, species, energy and momentum. Turbulence and radiation model coupled to a chemical kinetic mechanism for pyrolysis processes, gas–solid and gas–gas reactions was included to predicts species and flame temperature distribution, as well as convective and radiation energy fluxes. The model was used to study coal combustion with air and with oxygen for FGR between 30 and 85% as controller parameter for temperature in the process. Flame length effect and heat transfer by convection and radiation to the clinkering process for several recirculation ratios was studied. Theoretical studies predicted a located increase of energy flux and a reduction in flame length with respect to the traditional system which is based on air combustion. The impact of FGR on the oxy-fuel combustion process and different energy scenarios in cement kilns to increase energy efficiency and clinker production were studied and evaluated. Simulation results were in close agreement with experimental data, where the maximum deviation was 7%

  12. A life cycle assessment of environmental performances of two combustion- and gasification-based waste-to-energy technologies.

    Science.gov (United States)

    Arena, Umberto; Ardolino, Filomena; Di Gregorio, Fabrizio

    2015-07-01

    An attributional life cycle analysis (LCA) was developed to compare the environmental performances of two waste-to-energy (WtE) units, which utilize the predominant technologies among those available for combustion and gasification processes: a moving grate combustor and a vertical shaft gasifier coupled with direct melting. The two units were assumed to be fed with the same unsorted residual municipal waste, having a composition estimated as a European average. Data from several plants in operation were processed by means of mass and energy balances, and on the basis of the flows and stocks of materials and elements inside and throughout the two units, as provided by a specific substance flow analysis. The potential life cycle environmental impacts related to the operations of the two WtE units were estimated by means of the Impact 2002+ methodology. They indicate that both the technologies have sustainable environmental performances, but those of the moving grate combustion unit are better for most of the selected impact categories. The analysis of the contributions from all the stages of each specific technology suggests where improvements in technological solutions and management criteria should be focused to obtain further and remarkable environmental improvements. Copyright © 2015 Elsevier Ltd. All rights reserved.

  13. Deconsolidation and combustion performance of thermally consolidated propellants deterred by multi-layers coating

    Directory of Open Access Journals (Sweden)

    Zheng-gang Xiao

    2014-06-01

    Full Text Available Both heating and solvent-spray methods are used to consolidate the standard grains of double-base oblate sphere propellants plasticized with triethyleneglycol dinitrate (TEGDN (TEGDN propellants to high density propellants. The obtained consolidated propellants are deterred and coated with the slow burning multi-layer coating. The maximum compaction density of deterred and coated consolidated propellants can reach up to 1.39 g/cm3. Their mechanic, deconsolidation and combustion performances are tested by the materials test machine, interrupted burning set-up and closed vessel, respectively. The static compression strength of consolidated propellants deterred by multi-layer coating increases significantly to 18 MPa, indicating that they can be applied in most circumstances of charge service. And the samples are easy to deconsolidate in the interrupted burning test. Furthermore, the closed bomb burning curves of the samples indicate a two-stage combustion phenomenon under the condition of certain thickness of coated multi-layers. After the outer deterred multi-layer coating of consolidated samples is finished burning, the inner consolidated propellants continue to burn and breakup into aggregates and grains. The high burning progressivity can be carefully obtained by the smart control of deconsolidation process and duration of consolidated propellants. The preliminary results of consolidated propellants show that a rapid deconsolidation process at higher deconsolidation pressure is presented in the dynamic vivacity curves of closed bomb test. Higher density and higher macro progressivity of consolidated propellants can be obtained by the techniques in this paper.

  14. An improved combustion apparatus for the determination of organically bound tritium in environmental samples

    International Nuclear Information System (INIS)

    Du, Lin; Shan, Jian; Ma, Yu-Hua; Wang, Ling; Qin, Lai-Lai; Pi, Li; Zeng, You-Shi; Xia, Zheng-Hai; Wang, Guang-Hua; Liu, Wei

    2016-01-01

    This paper reports an improved combustion apparatus for the determination of organically bound tritium in environmental samples. The performance of this apparatus including the recovery rate and reproducibility was investigated by combusting lettuce and pork samples. To determine the factors for the different recovery rates of lettuce and pork and investigate whether the samples were completely oxidized, the ashes and exhaust gases produced by the combustion were analyzed. The results indicate that the apparatus showed an excellent performance in the combustion of environmental samples. Thus, the improvements conducted in this study were effective. - Highlights: • Three major improvements were made to develop the combustion apparatus for OBT. • The recovery is higher and more stable than that of current equipment. • Little hydrogen was present in the ashes and exhaust after combustion.

  15. A novel solution combustion synthesis of cobalt oxide nanoparticles as negative-electrode materials for lithium ion batteries

    International Nuclear Information System (INIS)

    Wen Wei; Wu Jinming; Tu Jiangping

    2012-01-01

    Highlights: ► We examine the electrochemical performance of cobalt oxides fabricated by solution combustion synthesis for rechargeable lithium-ion battery applications. ► The additive of NaF in precursor results in an eruption combustion mode. ► The eruption combustion leads to fluffy networks with smaller grains and more macroporous voids. ► The network contributes to higher discharge capacity, higher initial coulombic efficiency, and better cycling performance for rechargeable lithium-ion batteries. - Abstract: Low cost mass production of cobalt oxide nanoparticles with high electrochemical performance is of practical interest for rechargeable lithium-ion batteries. In this report, cobalt oxide nanoparticles were fabricated by solution combustion synthesis, with the introduction of NaF into the precursor to alter the combustion mode. The novel eruption combustion resulted in fluffy networks with smaller particles and more macroporous voids, which contributed to the higher discharge capacity, higher initial coulombic efficiency, and better cycling performance when compared with that achieved by the conventional combustion mode.

  16. Combustion modeling in internal combustion engines

    Science.gov (United States)

    Zeleznik, F. J.

    1976-01-01

    The fundamental assumptions of the Blizard and Keck combustion model for internal combustion engines are examined and a generalization of that model is derived. The most significant feature of the model is that it permits the occurrence of unburned hydrocarbons in the thermodynamic-kinetic modeling of exhaust gases. The general formulas are evaluated in two specific cases that are likely to be significant in the applications of the model.

  17. Oxy-coal Combustion Studies

    Energy Technology Data Exchange (ETDEWEB)

    Wendt, J. [Univ. of Utah, Salt Lake City, UT (United States); Eddings, E. [Univ. of Utah, Salt Lake City, UT (United States); Lighty, J. [Univ. of Utah, Salt Lake City, UT (United States); Ring, T. [Univ. of Utah, Salt Lake City, UT (United States); Smith, P. [Univ. of Utah, Salt Lake City, UT (United States); Thornock, J. [Univ. of Utah, Salt Lake City, UT (United States); Y Jia, W. Morris [Univ. of Utah, Salt Lake City, UT (United States); Pedel, J. [Univ. of Utah, Salt Lake City, UT (United States); Rezeai, D. [Univ. of Utah, Salt Lake City, UT (United States); Wang, L. [Univ. of Utah, Salt Lake City, UT (United States); Zhang, J. [Univ. of Utah, Salt Lake City, UT (United States); Kelly, K. [Univ. of Utah, Salt Lake City, UT (United States)

    2012-01-06

    The objective of this project is to move toward the development of a predictive capability with quantified uncertainty bounds for pilot-scale, single-burner, oxy-coal operation. This validation research brings together multi-scale experimental measurements and computer simulations. The combination of simulation development and validation experiments is designed to lead to predictive tools for the performance of existing air fired pulverized coal boilers that have been retrofitted to various oxy-firing configurations. In addition, this report also describes novel research results related to oxy-combustion in circulating fluidized beds. For pulverized coal combustion configurations, particular attention is focused on the effect of oxy-firing on ignition and coal-flame stability, and on the subsequent partitioning mechanisms of the ash aerosol.

  18. A predictive model of natural gas mixture combustion in internal combustion engines

    Directory of Open Access Journals (Sweden)

    Henry Espinoza

    2007-05-01

    Full Text Available This study shows the development of a predictive natural gas mixture combustion model for conventional com-bustion (ignition engines. The model was based on resolving two areas; one having unburned combustion mixture and another having combustion products. Energy and matter conservation equations were solved for each crankshaft turn angle for each area. Nonlinear differential equations for each phase’s energy (considering compression, combustion and expansion were solved by applying the fourth-order Runge-Kutta method. The model also enabled studying different natural gas components’ composition and evaluating combustion in the presence of dry and humid air. Validation results are shown with experimental data, demonstrating the software’s precision and accuracy in the results so produced. The results showed cylinder pressure, unburned and burned mixture temperature, burned mass fraction and combustion reaction heat for the engine being modelled using a natural gas mixture.

  19. Boiler using combustible fluid

    Science.gov (United States)

    Baumgartner, H.; Meier, J.G.

    1974-07-03

    A fluid fuel boiler is described comprising a combustion chamber, a cover on the combustion chamber having an opening for introducing a combustion-supporting gaseous fluid through said openings, means to impart rotation to the gaseous fluid about an axis of the combustion chamber, a burner for introducing a fluid fuel into the chamber mixed with the gaseous fluid for combustion thereof, the cover having a generally frustro-conical configuration diverging from the opening toward the interior of the chamber at an angle of between 15/sup 0/ and 55/sup 0/; means defining said combustion chamber having means defining a plurality of axial hot gas flow paths from a downstream portion of the combustion chamber to flow hot gases into an upstream portion of the combustion chamber, and means for diverting some of the hot gas flow along paths in a direction circumferentially of the combustion chamber, with the latter paths being immersed in the water flow path thereby to improve heat transfer and terminating in a gas outlet, the combustion chamber comprising at least one modular element, joined axially to the frustro-conical cover and coaxial therewith. The modular element comprises an inner ring and means of defining the circumferential, radial, and spiral flow paths of the hot gases.

  20. Thermodynamic analysis of an absorption refrigeration system used to cool down the intake air in an Internal Combustion Engine

    International Nuclear Information System (INIS)

    Novella, R.; Dolz, V.; Martín, J.; Royo-Pascual, L.

    2017-01-01

    Highlights: • Enough power in the exhaust gases is available to operate the absorption cycle. • Three engine operating points are presented in the article. • Improvement potential up to 4% is possible in the engine indicated efficiency. • Engine indicated efficiency benefit was experimentally confirmed by direct testing. - Abstract: This paper deals with the thermodynamic analysis of an absorption refrigeration cycle used to cool down the temperature of the intake air in an Internal Combustion Engine using as a heat source the exhaust gas of the engine. The solution of ammonia-water has been selected due to the stability for a wide range of operating temperatures and pressures and the low freezing point. The effects of operating temperatures, pressures, concentrations of strong and weak solutions in the absorption refrigeration cycle were examined to achieve proper heat rejection to the ambient. Potential of increasing Internal Combustion Engine efficiency and reduce pollutant emissions was estimated by means of theoretical models and experimental tests. In order to provide boundary conditions for the absorption refrigeration cycle and to simulate its effect on engine performance, a 0D thermodynamic model was used to reproduce the engine performance when the intake air is cooled. Furthermore, a detailed experimental work was carried out to validate the results in real engine operation. Theoretical results show how the absorption refrigeration system decreases the intake air flow temperature down to a temperature around 5 °C and even lower by using the bottoming waste heat energy available in the exhaust gases in a wide range of engine operating conditions. In addition, the theoretical analysis estimates the potential of the strategy for increasing the engine indicated efficiency in levels up to 4% also at the operating conditions under evaluation. Finally, this predicted benefit in engine indicated efficiency has been experimentally confirmed by direct

  1. Pulsed atmospheric fluidized bed combustion

    Energy Technology Data Exchange (ETDEWEB)

    1989-11-01

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  2. Fuel and Additive Characterization for HCCI Combustion

    International Nuclear Information System (INIS)

    Aceves, S M; Flowers, D; Martinez-Frias, J; Espinosa-Loza, F; Pitz, W J; Dibble, R

    2003-01-01

    This paper shows a numerical evaluation of fuels and additives for HCCl combustion. First, a long list of candidate HCCl fuels is selected. For all the fuels in the list, operating conditions (compression ratio, equivalence ratio and intake temperature) are determined that result in optimum performance under typical operation for a heavy-duty engine. Fuels are also characterized by presenting Log(p)-Log(T) maps for multiple fuels under HCCl conditions. Log(p)-Log(T) maps illustrate important processes during HCCl engine operation, including compression, low temperature heat release and ignition. Log(p)-Log(T) diagrams can be used for visualizing these processes and can be used as a tool for detailed analysis of HCCl combustion. The paper also includes a ranking of many potential additives. Experiments and analyses have indicated that small amounts (a few parts per million) of secondary fuels (additives) may considerably affect HCCl combustion and may play a significant role in controlling HCCl combustion. Additives are ranked according to their capability to advance HCCl ignition. The best additives are listed and an explanation of their effect on HCCl combustion is included

  3. Reaction-diffusion pulses: a combustion model

    International Nuclear Information System (INIS)

    Campos, Daniel; Llebot, Josep Enric; Fort, Joaquim

    2004-01-01

    We focus on a reaction-diffusion approach proposed recently for experiments on combustion processes, where the heat released by combustion follows first-order reaction kinetics. This case allows us to perform an exhaustive analytical study. Specifically, we obtain the exact expressions for the speed of the thermal pulses, their maximum temperature and the condition of self-sustenance. Finally, we propose two generalizations of the model, namely, the case of several reactants burning together, and that of time-delayed heat conduction. We find an excellent agreement between our analytical results and simulations

  4. Reaction-diffusion pulses: a combustion model

    Energy Technology Data Exchange (ETDEWEB)

    Campos, Daniel [Grup de FIsica EstadIstica, Dept. de FIsica, Universitat Autonoma de Barcelona, E-08193 Bellaterrra (Spain); Llebot, Josep Enric [Grup de FIsica EstadIstica, Dept. de FIsica, Universitat Autonoma de Barcelona, E-08193 Bellaterrra (Spain); Fort, Joaquim [Dept. de FIsica, Univ. de Girona, Campus de Montilivi, 17071 Girona, Catalonia (Spain)

    2004-07-02

    We focus on a reaction-diffusion approach proposed recently for experiments on combustion processes, where the heat released by combustion follows first-order reaction kinetics. This case allows us to perform an exhaustive analytical study. Specifically, we obtain the exact expressions for the speed of the thermal pulses, their maximum temperature and the condition of self-sustenance. Finally, we propose two generalizations of the model, namely, the case of several reactants burning together, and that of time-delayed heat conduction. We find an excellent agreement between our analytical results and simulations.

  5. Formation of Co2P in the combustion regime

    International Nuclear Information System (INIS)

    Muchaik, S.V.; Dubrov, A.N.; Lynchak, K.A.

    1983-01-01

    Combustion of the system Co-P produces the compounds Co 2 P, CoP and CoP 3 , the first two being producible in the combustion regime, while for synthesis of stoichiometric Co 2 P at normal argon pressure, an original mixture with a certain excess of phosphorus is required. The present experiments were performed with electrolytic cobalt powder and red phosphorus. As the Co-P mixture is diluted by the final product (Co 2 P) there is a decrease in combustion temperature and rate, unaccompanied by any of the anomalies seen with dilution by cobalt. It can be suggested that although the combustion in the Co-P system and, possibly, i-- other phosphide systems, is not gasless in its kinetic aspects the combustion mechanism is similar to that in gasless systems. It is shown that formation of the phosphide Co=3''P and specimens wyth composition Co-Co 2 P in the combustion regime occurs with participation of a lIqui] phase of eutectic composition. Combustion occurs in a self-oscillating regime. The temperature for Co 2 P formation is close to its melting point, and the process activation energy comprises 205 kJ/mole

  6. Construction of a power plant with prototype DLN combustion turbines

    Energy Technology Data Exchange (ETDEWEB)

    Wilkinson, M.L. [CSW Energy, Dallas, TX (United States); Drummond, L.J. [Zurn NEPCO, Redmond, WA (United States)

    1996-12-31

    Design and construction of a power plant is always a difficult process and this is especially true when the main keystone, the combustion turbine engine, is being modified by the manufacturer resulting in numerous changes in the design interfaces. The development of the design and construction of the Orange Cogeneration Facility has been in parallel with major modification of the LM6000 to DLE technology (a Dry Low NO{sub x} combustion system). The Dry Low NO{sub x} Combustion System for a combustion turbine offered a means to reduce water usage, lower Zero Liquid Discharge System operating costs and reduce emissions to meet Florida Department of Environmental Protection requirements. This development was successfully accomplished by Owner, EPC contractor and Combustion Turbine Manufacturer by maintaining flexibility in the design and construction while the design interfaces and performance of the combustion turbines were being finalized.

  7. 77 FR 60341 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-10-03

    ... National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines AGENCY: Environmental Protection... Pollutants for Stationary Reciprocating Internal Combustion Engines to solicit comment on specific issues...

  8. HERCULES Advanced Combustion Concepts Test Facility: Spray/Combustion Chamber

    Energy Technology Data Exchange (ETDEWEB)

    Herrmann, K. [Eidgenoessische Technische Hochschule (ETH), Labor fuer Aerothermochemie und Verbrennungssysteme, Zuerich (Switzerland)

    2004-07-01

    This yearly report for 2004 on behalf of the Swiss Federal Office of Energy (SFOE) at the Laboratory for Aero-thermochemistry and Combustion Systems at the Federal Institute of Technology ETH in Zurich, Switzerland, presents a review of work being done within the framework of HERCULES (High Efficiency R and D on Combustion with Ultra Low Emissions for Ships) - the international R and D project concerning new technologies for ships' diesels. The work involves the use and augmentation of simulation models. These are to be validated using experimental data. The report deals with the development of an experimental set-up that will simulate combustion in large two-stroke diesel engines and allow the generation of reference data. The main element of the test apparatus is a spray / combustion chamber with extensive possibilities for optical observation under variable flow conditions. The results of first simulations confirm concepts and shall help in further work on the project. The potential offered by high-speed camera systems was tested using the institute's existing HTDZ combustion chamber. Further work to be done is reviewed.

  9. Gradual combustion - method for nitrogen oxide suppression during brown coal combustion

    Energy Technology Data Exchange (ETDEWEB)

    Kotler, V.P.; Verzakov, V.N.; Lobov, T.V.

    1990-10-01

    Discusses combustion of brown coal in BKZ-500-140-1 boilers and factors that influence emission of nitrogen oxides. Temperature distribution in the furnace was evaluated. Effects of burner position, burner number and burner type as well as air excess ratio on chemical reactions during brown coal combustion, formation of nitrogen oxides and their emission were comparatively evaluated. Analyses showed that by optimum arrangement of burners and selecting the optimum air excess ratio a part of nitrogen oxides formed during the initial phase of combustion was reduced to molecular nitrogen in the second phase. On the basis of evaluations the following recommendations for furnace design are made: use of straight-flow burners characterized by a reduced mixing ratio with secondary air, parallel arrangement of burners which guarantees mixing of the combustion products from the burners with stable and unstable combustion (products of incomplete coal combustion), reducing the air excess ratio to below 1.0. 5 refs.

  10. Experimental investigations of the effect of pilot injection on performance, emissions and combustion characteristics of Karanja biodiesel fuelled CRDI engine

    International Nuclear Information System (INIS)

    Dhar, Atul; Agarwal, Avinash Kumar

    2015-01-01

    Highlights: • Effect of multiple injections on CRDI engine performance, emission and combustion. • Effect of multiple injections, injection pressures and injection timings on biodiesel. • Lower biodiesel blends showed lower BSCO, BSHC but higher BSNOx emissions. • Maximum cylinder pressure at higher FIP was higher at same SOPI and SOMI. • Combustion duration of KOME50 was higher than mineral diesel. - Abstract: Pilot and post injections are being used in modern diesel engines for improving engine performance in addition to meeting stringent emission norms. Biodiesel produced from different feedstocks is gaining global recognition as partial replacement for mineral diesel in compression ignition (CI) engines. In this study, 10%, 20% and 50% Karanja biodiesel blends were used for investigation of pilot injections, injection pressures and injection timings on biodiesel blends. Experiments were carried out in a single cylinder CRDI research engine in multiple injection mode at 500 and 1000 bar fuel injection pressure (FIP) under varying start of pilot injection (SOPI) and start of main injection (SOMI) timings. Brake specific fuel consumption (BSFC) increased with increasing Karanja biodiesel concentration in test fuels however brake thermal efficiency (BTE) of biodiesel blends was slightly higher than mineral diesel. Lower biodiesel blends showed lower brake specific carbon monoxide (BSCO) and brake specific hydrocarbon (BSHC) emissions than mineral diesel. Brake specific nitrogen oxides (BSNOx) emissions from KOME20 and KOME10 were higher than mineral diesel. Combustion duration of KOME50 was also higher than mineral diesel

  11. Enhancement of exergy efficiency in combustion systems using flameless mode

    International Nuclear Information System (INIS)

    Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

    2014-01-01

    Highlights: • Exergy efficiency in flameless combustion mode is 13% more than conventional combustion. • The maximum exergy efficiency in flameless combustion mode is achieved when oxidizer contains 10% oxygen. • Exergy destruction of flameless combustion is maximized when CO 2 is used for dilution of oxidizer. - Abstract: An exergitic-based analysis of methane (CH 4 ) conventional and flameless combustion in a lab-scale furnace is performed to determine the rate of pollutant formation and the effective potential of a given amount of fuel in the various combustion modes. The effects of inlet air temperature on exergy efficiency and pollutant formation of conventional combustion in various equivalence ratios are analyzed. The rate of exergy destruction in different conditions of flameless combustion (various equivalence ratios, oxygen concentration in the oxidizer and the effects of diluent) are computed using three-dimensional (3D) computational fluid dynamic (CFD). Fuel consumption reduction and exergy efficiency augmentation are the main positive consequences of using preheated air temperature in conventional combustion, however pollutants especially NO x formation increases dramatically. Low and moderate temperature inside the chamber conducts the flameless combustion system to low level pollutant formation. Fuel consumption and exergy destruction reduce drastically in flameless mode in comparison with conventional combustion. Exergy efficiency of conventional and flameless mode is 75% and 88% respectively in stoichiometric combustion. When CO 2 is used for dilution of oxidizer, chemical exergy increases due to high CO 2 concentration in the combustion products and exergy efficiency reduces around 2% compared to dilution with nitrogen (N 2 ). Since the rate of irreversibilities in combustion systems is very high in combined heat and power (CHP) generation and other industries, application of flameless combustion could be effective in terms of pollutant

  12. Nanosafety by design: risks from nanocomposite/nanowaste combustion

    Science.gov (United States)

    Bouillard, Jacques X.; R'Mili, Badr; Moranviller, Daniel; Vignes, Alexis; Le Bihan, Olivier; Ustache, Aurelien; Bomfim, Joao A. S.; Frejafon, Emeric; Fleury, Dominique

    2013-04-01

    Risks associated with the end-of-life of nanomaterials are an issue that needs to be addressed so that the public perception and opinion, with regard to these emerging technological products, can effectively be supported by experimental evidences. In order to find new ecological ways to treat nanoproducts at their end-of-life, a new home-made demonstrator system was setup at INERIS, specifically designed to perform burning tests, coupled to a differential thermal analyzer to monitor the combustion kinetics. To assess nanoobject release during combustion, a high-performance nanocomposite polymer commonly used in the automotive industry, namely the polymeric compound acrylonitrile butadiene styrene matrix mixed with 3 wt% of multiwalled carbon nanotubes (MWCNTs) was tested. To assess the potential release of carbon nanotubes (CNTs) during the combustion with this tool, the particle size distribution in the fumes was measured using an electrical low pressure impactor, and CNTs were collected using an aspiration-based transmission electron microscopy grid sampler. One of primary objective of these preliminary tests described in this study consisted in validating whether CNT fibers can be released in the gas phase during the combustion of a polymeric matrix filled with CNTs. It was found indeed that MWCNT of about 12-nm diameter and 600-nm length can be released in the ambient environment during combustion of 3 % MWCNT ABS. Such information is critical to assess whether a nanoproduct can be deemed to be considered as "nanosafe by design" in its risk assessment.

  13. Nanosafety by design: risks from nanocomposite/nanowaste combustion

    International Nuclear Information System (INIS)

    Bouillard, Jacques X.; R’Mili, Badr; Moranviller, Daniel; Vignes, Alexis; Le Bihan, Olivier; Ustache, Aurelien; Bomfim, Joao A. S.; Frejafon, Emeric; Fleury, Dominique

    2013-01-01

    Risks associated with the end-of-life of nanomaterials are an issue that needs to be addressed so that the public perception and opinion, with regard to these emerging technological products, can effectively be supported by experimental evidences. In order to find new ecological ways to treat nanoproducts at their end-of-life, a new home-made demonstrator system was setup at INERIS, specifically designed to perform burning tests, coupled to a differential thermal analyzer to monitor the combustion kinetics. To assess nanoobject release during combustion, a high-performance nanocomposite polymer commonly used in the automotive industry, namely the polymeric compound acrylonitrile butadiene styrene matrix mixed with 3 wt% of multiwalled carbon nanotubes (MWCNTs) was tested. To assess the potential release of carbon nanotubes (CNTs) during the combustion with this tool, the particle size distribution in the fumes was measured using an electrical low pressure impactor, and CNTs were collected using an aspiration-based transmission electron microscopy grid sampler. One of primary objective of these preliminary tests described in this study consisted in validating whether CNT fibers can be released in the gas phase during the combustion of a polymeric matrix filled with CNTs. It was found indeed that MWCNT of about 12-nm diameter and 600-nm length can be released in the ambient environment during combustion of 3 % MWCNT ABS. Such information is critical to assess whether a nanoproduct can be deemed to be considered as “nanosafe by design” in its risk assessment.

  14. 77 FR 33811 - National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion...

    Science.gov (United States)

    2012-06-07

    ... 63 National Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source Performance Standards for Stationary Internal Combustion Engines; Proposed Rule #0;#0... Emission Standards for Hazardous Air Pollutants for Reciprocating Internal Combustion Engines; New Source...

  15. Oxygenated palm biodiesel: Ignition, combustion and emissions quantification in a light-duty diesel engine

    International Nuclear Information System (INIS)

    Chong, Cheng Tung; Ng, Jo-Han; Ahmad, Solehin; Rajoo, Srithar

    2015-01-01

    Highlights: • Diesel engine test using palm biodiesel and diesel at varying speed and load. • Palm biodiesel shows better performance at late stage of cycle evolution. • Oxygen in palm biodiesel fuel improves local combustion at late stage of combustion. • Emissions of NO are lower at low and medium operating speed for palm biodiesel. • Formulation of trend guide for performance and emissions characteristics for light-duty diesel engines. - Abstract: This paper presents an investigation of oxygenated neat palm biodiesel in a direct injection single cylinder diesel engine in terms of ignition, combustion and emissions characteristics. Conventional non-oxygenated diesel fuel is compared as baseline. The engine testing is performed between the operating speed of 2000–3000 rpm and load of up to 3 bar of brake mean effective pressure. From it, a total of 50 experiment cases are tested to form a comprehensive operational speed-load contour map for ignition and combustion; while various engine-out emissions such as NO, CO, UHCs and CO 2 are compared based on fuel type-speed combinations. The ignition and combustion evolution contour maps quantify the absolute ignition delay period and elucidate the difference between that of palm biodiesel and fossil diesel. Although diesel has shorter ignition delay period by up to 0.6 CAD at 3000 rpm and burns more rapidly at the start of combustion, combustion of palm biodiesel accelerates during the mid-combustion phase and overtakes diesel in the cumulative heat release rates (HRR) prior to the 90% cumulative HRR. This can be attributed to the oxygen contained in palm biodiesel assisting in localized regions of combustion. In terms of performance, the oxygenated nature of palm biodiesel provided mixed performances with improved thermal efficiency and increased brake specific fuel consumption, due to the improved combustion and lower calorific values, respectively. Emission measurements show that NO for palm biodiesel is

  16. An investigation of the engine performance, emissions and combustion characteristics of coconut biodiesel in a high-pressure common-rail diesel engine

    International Nuclear Information System (INIS)

    How, H.G.; Masjuki, H.H.; Kalam, M.A.; Teoh, Y.H.

    2014-01-01

    An experimental investigation on engine performance, emissions, combustion and vibration characteristics with coconut biodiesel fuels was conducted in a high-pressure common-rail diesel engine under five different load operations (0.17, 0.34, 0.52, 0.69 and 0.86 MPa). The test fuels included a conventional diesel fuel and four different fuel blends of coconut biodiesel (B10, B20, B30 and B50). The results showed that biodiesel blended fuels have significant influences on the BSFC (brake specific fuel consumption) and BSEC (brake specific energy consumption) at all engine loads. In general, the use of coconut biodiesel blends resulted in a reduction of BSCO (brake specific carbon monoxide) and smoke emissions regardless of the load conditions. A large reduction of 52.4% in smoke opacity was found at engine load of 0.86 MPa engine load with B50. For combustion characteristics, a slightly shorter ignition delay and longer combustion duration were found with the use of biodiesel blends under all loading operations. It was found that generally the biodiesel blends produced lower peak heat release rate than baseline diesel. The vibration results showed that the largest reduction of 13.7% in RMS (root mean square) of acceleration was obtained with B50 at engine load of 0.86 MPa with respect to the baseline diesel. - Highlights: • The performance, emissions and combustion characteristics of biodiesel were studied. • A tangible increase in BSFC was observed at all engine loads with coconut biodiesel. • A slightly shorter ignition delay was found with the use of biodiesel blends. • The vibrations for coconut biodiesel blends in diesel engine were investigated. • B50 achieved the largest reduction in RMS of acceleration at 0.86 MPa engine load

  17. High-speed combustion diagnostics in a rapid compression machine by broadband supercontinuum absorption spectroscopy.

    Science.gov (United States)

    Werblinski, Thomas; Fendt, Peter; Zigan, Lars; Will, Stefan

    2017-05-20

    The first results under fired internal combustion engine conditions based on a supercontinuum absorption spectrometer are presented and discussed. Temperature, pressure, and water mole fraction are inferred simultaneously from broadband H 2 O absorbance spectra ranging from 1340 nm to 1440 nm. The auto-ignition combustion process is monitored for two premixed n-heptane/air mixtures with 10 kHz in a rapid compression machine. Pressure and temperature levels during combustion exceed 65 bar and 1900 K, respectively. To allow for combustion measurements, the robustness of the spectrometer against beam steering has been improved compared to its previous version. Additionally, the detectable wavelength range has been extended further into the infrared region to allow for the acquisition of distinct high-temperature water transitions located in the P-branch above 1410 nm. Based on a theoretical study, line-of-sight (LOS) effects introduced by temperature stratification on the broadband fitting algorithm in the complete range from 1340 nm to 1440 nm are discussed. In this context, the recorded spectra during combustion were evaluated only within a narrower spectral region exhibiting almost no interference from low-temperature molecules (here, P-branch from 1410 nm to 1440 nm). It is shown that this strategy mitigates almost all of the LOS effects introduced by cold molecules and the evaluation of the spectrum in the entirely recorded wavelength range at engine combustion conditions.

  18. New regulations, combustion, environment: responses for natural gas; Nouvelles reglementations, combustion, environnement: les reponses pour le gaz naturel

    Energy Technology Data Exchange (ETDEWEB)

    Le Peltier-Marc, A. [Gaz de France (GDF), 75 - Paris (France). Direction Commerciale

    1997-12-31

    The impacts of the new French regulations concerning low- to medium-power combustion equipment with regards to their energy sources, energy efficiency and pollution control, on natural gas fired boilers, are discussed: lower pollutant emission limits are set for SO{sub 2}, NO{sub x} and ashes. The decree gives new regulations concerning plant location, combustion control systems, plant monitoring and maintenance, and air pollution control measures such as chimney stack height and emission limits. The French national gas utility promotes environmental high performance boilers

  19. Volatiles combustion in fluidized beds. Final technical report, 4 September 1992--4 June 1995

    Energy Technology Data Exchange (ETDEWEB)

    Pendergrass, R.A. II; Raffensperger, C.; Hesketh, R.P.

    1996-02-29

    The goal of this project is to investigate the conditions in which volatiles will burn within both the dense and freeboard regions of fluidized beds. Experiments using a fluidized bed operated at incipient fluidization are being conducted to characterize the effect of particle surface area, initial fuel concentration, and particle type on the inhibition of volatiles within a fluidized bed. A review of the work conducted under this grant is presented in this Final Technical Report. Both experimental and theoretical work have been conducted to examine the inhibition of the combustion by the fluidized bed material, sand. It has been shown that particulate phase at incipient fluidization inhibits the combustion of propane by free radical destruction at the surface of sand particles within the particulate phase. The implications of these findings is that at bed temperatures lower than the critical temperatures, gas combustion can only occur in the bubble phase or at the top surface of a bubbling fluidized bed. In modeling fluidized bed combustion this inhibition by the particulate phase should be included.

  20. Numerical Analysis on Combustion Characteristic of Leaf Spring Rotary Engine

    Directory of Open Access Journals (Sweden)

    Yan Zhang

    2015-08-01

    Full Text Available The purpose of this paper is to investigate combustion characteristics for rotary engine via numerical studies. A 3D numerical model was developed to study the influence of several operative parameters on combustion characteristics. A novel rotary engine called, “Leaf Spring Rotary Engine”, was used to illustrate the structure and principle of the engine. The aims are to (1 improve the understanding of combustion process, and (2 quantify the influence of rotational speed, excess air ratio, initial pressure and temperature on combustion characteristics. The chamber space changed with crankshaft rotation. Due to the complexity of chamber volume, an equivalent modeling method was presented to simulate the chamber space variation. The numerical simulations were performed by solving the incompressible, multiphase Unsteady Reynolds-Averaged Navier–Stokes Equations via the commercial code FLUENT using a transport equation-based combustion model; a realizable  turbulence model and finite-rate/eddy-dissipation model were used to account for the effect of local factors on the combustion characteristics.

  1. Update on status of fluidized-bed combustion technology

    International Nuclear Information System (INIS)

    Stallings, J.; Boyd, T.; Brown, R.

    1992-01-01

    During the 1980s, fluidized-bed combustion technology has become the dominant technology for solid-fuel-fired power generation systems in the United States. Atmospheric fluidized beds as large as 160 MWe in capacity are now in operation, while pressurized systems reaching 80 MWe have started up in the last year. The commercial status, boiler performance, emissions, and future developments for both atmospheric and pressurized fluidized-bed combustion systems are discussed

  2. Development and test of combustion chamber for Stirling engine heated by natural gas

    Science.gov (United States)

    Li, Tie; Song, Xiange; Gui, Xiaohong; Tang, Dawei; Li, Zhigang; Cao, Wenyu

    2014-04-01

    The combustion chamber is an important component for the Stirling engine heated by natural gas. In the paper, we develop a combustion chamber for the Stirling engine which aims to generate 3˜5 kWe electric power. The combustion chamber includes three main components: combustion module, heat exchange cavity and thermal head. Its feature is that the structure can divide "combustion" process and "heat transfer" process into two apparent individual steps and make them happen one by one. Since natural gas can mix with air fully before burning, the combustion process can be easily completed without the second wind. The flame can avoid contacting the thermal head of Stirling engine, and the temperature fields can be easily controlled. The designed combustion chamber is manufactured and its performance is tested by an experiment which includes two steps. The experimental result of the first step proves that the mixture of air and natural gas can be easily ignited and the flame burns stably. In the second step of experiment, the combustion heat flux can reach 20 kW, and the energy utilization efficiency of thermal head has exceeded 0.5. These test results show that the thermal performance of combustion chamber has reached the design goal. The designed combustion chamber can be applied to a real Stirling engine heated by natural gas which is to generate 3˜5 kWe electric power.

  3. Reflections on the conceptualization and operationalization of a set-theoretic approach to employee motivation and performance research

    Directory of Open Access Journals (Sweden)

    James Christopher Ryan

    2017-01-01

    Full Text Available The current commentary offers a reflection on the conceptualizations of Lee and Raschke's (2016 proposal for a set-theoretic approach to employee motivation and organizational performance. The commentary is informed by the current author's operationalization of set-theoretic research on employee motivation which occurred contemporaneously to the work of Lee and Raschke. Observations on the state of current research on employee motivation, development of motivation theory and future directions of set-theoretic approaches to employee motivation and performance are offered.

  4. Uncertainties in hydrogen combustion

    International Nuclear Information System (INIS)

    Stamps, D.W.; Wong, C.C.; Nelson, L.S.

    1988-01-01

    Three important areas of hydrogen combustion with uncertainties are identified: high-temperature combustion, flame acceleration and deflagration-to-detonation transition, and aerosol resuspension during hydrogen combustion. The uncertainties associated with high-temperature combustion may affect at least three different accident scenarios: the in-cavity oxidation of combustible gases produced by core-concrete interactions, the direct containment heating hydrogen problem, and the possibility of local detonations. How these uncertainties may affect the sequence of various accident scenarios is discussed and recommendations are made to reduce these uncertainties. 40 references

  5. The combustion behavior of diesel/CNG mixtures in a constant volume combustion chamber

    Science.gov (United States)

    Firmansyah; Aziz, A. R. A.; Heikal, M. R.

    2015-12-01

    The stringent emissions and needs to increase fuel efficiency makes controlled auto-ignition (CAI) based combustion an attractive alternative for the new combustion system. However, the combustion control is the main obstacles in its development. Reactivity controlled compression ignition (RCCI) that employs two fuels with significantly different in reactivity proven to be able to control the combustion. The RCCI concept applied in a constant volume chamber fuelled with direct injected diesel and compressed natural gas (CNG) was tested. The mixture composition is varied from 0 - 100% diesel/CNG at lambda 1 with main data collection are pressure profile and combustion images. The results show that diesel-CNG mixture significantly shows better combustion compared to diesel only. It is found that CNG is delaying the diesel combustion and at the same time assisting in diesel distribution inside the chamber. This combination creates a multipoint ignition of diesel throughout the chamber that generate very fast heat release rate and higher maximum pressure. Furthermore, lighter yellow color of the flame indicates lower soot production in compared with diesel combustion.

  6. Combustion characteristics and air pollutant formation during oxy-fuel co-combustion of microalgae and lignite.

    Science.gov (United States)

    Gao, Yuan; Tahmasebi, Arash; Dou, Jinxiao; Yu, Jianglong

    2016-05-01

    Oxy-fuel combustion of solid fuels is seen as one of the key technologies for carbon capture to reduce greenhouse gas emissions. The combustion characteristics of lignite coal, Chlorella vulgaris microalgae, and their blends under O2/N2 and O2/CO2 conditions were studied using a Thermogravimetric Analyzer-Mass Spectroscopy (TG-MS). During co-combustion of blends, three distinct peaks were observed and were attributed to C. vulgaris volatiles combustion, combustion of lignite, and combustion of microalgae char. Activation energy during combustion was calculated using iso-conventional method. Increasing the microalgae content in the blend resulted in an increase in activation energy for the blends combustion. The emissions of S- and N-species during blend fuel combustion were also investigated. The addition of microalgae to lignite during air combustion resulted in lower CO2, CO, and NO2 yields but enhanced NO, COS, and SO2 formation. During oxy-fuel co-combustion, the addition of microalgae to lignite enhanced the formation of gaseous species. Copyright © 2016 Elsevier Ltd. All rights reserved.

  7. Combustion optimization and HCCI modeling for ultra low emission

    Energy Technology Data Exchange (ETDEWEB)

    Koten, Hasan; Yilmaz, Mustafa; Zafer Gul, M. [Marmara University Mechanical Engineering Department (Turkey)], E-mail: hasan.koten@marmara.edu.tr

    2011-07-01

    With the coming shortage of fossil fuels and the rising concerns over the environment it is important to develop new technologies both to reduce energy consumption and pollution at the same time. In the transportation sector, new combustion processes are under development to provide clean diesel combustion with no particulate or NOx emissions. However, these processes have issues such as limited power output, high levels of unburned hydrocarbons, and carbon monoxide emissions. The aim of this paper is to present a methodology for optimizing combustion performance. The methodology consists of the use of a multi-objective genetic algorithm optimization tool; homogeneous charge compression ignition engine cases were studied with the ECFM-3Z combustion model. Results showed that injected fuel mass led to a decrease in power output, a finding which is in keeping with previous research. This paper presented on optimization tool which can be useful in improving the combustion process.

  8. A Computational Fluid Dynamics Study of Turbulence, Radiation, and Combustion Models for Natural Gas Combustion Burner

    Directory of Open Access Journals (Sweden)

    Yik Siang Pang

    2018-01-01

    Full Text Available This paper presents a Computational Fluid Dynamics (CFD study of a natural gas combustion burner focusing on the effect of combustion, thermal radiation and turbulence models on the temperature and chemical species concentration fields. The combustion was modelled using the finite rate/eddy dissipation (FR/EDM and partially premixed flame models. Detailed chemistry kinetics CHEMKIN GRI-MECH 3.0 consisting of 325 reactions was employed to model the methane combustion. Discrete ordinates (DO and spherical harmonics (P1 model were employed to predict the thermal radiation. The gas absorption coefficient dependence on the wavelength is resolved by the weighted-sum-of-gray-gases model (WSGGM. Turbulence flow was simulated using Reynolds-averaged Navier-Stokes (RANS based models. The findings showed that a combination of partially premixed flame, P1 and standard k-ε (SKE gave the most accurate prediction with an average deviation of around 7.8% of combustion temperature and 15.5% for reactant composition (methane and oxygen. The results show the multi-step chemistry in the partially premixed model is more accurate than the two-step FR/EDM. Meanwhile, inclusion of thermal radiation has a minor effect on the heat transfer and species concentration. SKE turbulence model yielded better prediction compared to the realizable k-ε (RKE and renormalized k-ε (RNG. The CFD simulation presented in this work may serve as a useful tool to evaluate a performance of a natural gas combustor. Copyright © 2018 BCREC Group. All rights reserved Received: 26th July 2017; Revised: 9th October 2017; Accepted: 30th October 2017; Available online: 22nd January 2018; Published regularly: 2nd April 2018 How to Cite: Pang, Y.S., Law, W.P., Pung, K.Q., Gimbun, J. (2018. A Computational Fluid Dynamics Study of Turbulence, Radiation, and Combustion Models for Natural Gas Combustion Burner. Bulletin of Chemical Reaction Engineering & Catalysis, 13 (1: 155-169 (doi:10.9767/bcrec

  9. Towards integrating control and information theories from information-theoretic measures to control performance limitations

    CERN Document Server

    Fang, Song; Ishii, Hideaki

    2017-01-01

    This book investigates the performance limitation issues in networked feedback systems. The fact that networked feedback systems consist of control and communication devices and systems calls for the integration of control theory and information theory. The primary contributions of this book lie in two aspects: the newly-proposed information-theoretic measures and the newly-discovered control performance limitations. We first propose a number of information notions to facilitate the analysis. Using those notions, classes of performance limitations of networked feedback systems, as well as state estimation systems, are then investigated. In general, the book presents a unique, cohesive treatment of performance limitation issues of networked feedback systems via an information-theoretic approach. This book is believed to be the first to treat the aforementioned subjects systematically and in a unified manner, offering a unique perspective differing from existing books.

  10. Revisioning Theoretical Framework of Electronic Performance Support Systems (EPSS within the Software Application Examples

    Directory of Open Access Journals (Sweden)

    Dr. Servet BAYRAM,

    2004-04-01

    Full Text Available Revisioning Theoretical Framework of Electronic Performance Support Systems (EPSS within the Software Application Examples Assoc. Prof. Dr. Servet BAYRAM Computer Education & Instructional Technologies Marmara University , TURKEY ABSTRACT EPSS provides electronic support to learners in achieving a performance objective; a feature which makes it universally and consistently available on demand any time, any place, regardless of situation, without unnecessary intermediaries involved in the process. The aim of this review is to develop a set of theoretical construct that provide descriptive power for explanation of EPSS and its roots and features within the software application examples (i.e., Microsoft SharePoint Server”v2.0” Beta 2, IBM Lotus Notes 6 & Domino 6, Oracle 9i Collaboration Suite, and Mac OS X v10.2. From the educational and training point of view, the paper visualizes a pentagon model for the interrelated domains of the theoretical framework of EPSS. These domains are: learning theories, information processing theories, developmental theories, instructional theories, and acceptance theories. This descriptive framework explains a set of descriptions as to which outcomes occur under given theoretical conditions for a given EPSS model within software examples. It summarizes some of the theoretical concepts supporting to the EPSS’ related features and explains how such concepts sharing same features with the example software programs in education and job training.

  11. Mixing and combustion enhancement of Turbocharged Solid Propellant Ramjet

    Science.gov (United States)

    Liu, Shichang; Li, Jiang; Zhu, Gen; Wang, Wei; Liu, Yang

    2018-02-01

    Turbocharged Solid Propellant Ramjet is a new concept engine that combines the advantages of both solid rocket ramjet and Air Turbo Rocket, with a wide operation envelope and high performance. There are three streams of the air, turbine-driving gas and augment gas to mix and combust in the afterburner, and the coaxial intake mode of the afterburner is disadvantageous to the mixing and combustion. Therefore, it is necessary to carry out mixing and combustion enhancement research. In this study, the numerical model of Turbocharged Solid Propellant Ramjet three-dimensional combustion flow field is established, and the numerical simulation of the mixing and combustion enhancement scheme is conducted from the aspects of head region intake mode to injection method in afterburner. The results show that by driving the compressed air to deflect inward and the turbine-driving gas to maintain strong rotation, radial and tangential momentum exchange of the two streams can be enhanced, thereby improving the efficiency of mixing and combustion in the afterburner. The method of injecting augment gas in the transverse direction and making sure the injection location is as close as possible to the head region is beneficial to improve the combustion efficiency. The outer combustion flow field of the afterburner is an oxidizer-rich environment, while the inner is a fuel-rich environment. To improve the efficiency of mixing and combustion, it is necessary to control the injection velocity of the augment gas to keep it in the oxygen-rich zone of the outer region. The numerical simulation for different flight conditions shows that the optimal mixing and combustion enhancement scheme can obtain high combustion efficiency and have excellent applicability in a wide working range.

  12. 40 CFR 60.1010 - Does this subpart apply to my municipal waste combustion unit?

    Science.gov (United States)

    2010-07-01

    ... waste combustion unit? 60.1010 Section 60.1010 Protection of Environment ENVIRONMENTAL PROTECTION AGENCY... Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced After August 30....1010 Does this subpart apply to my municipal waste combustion unit? Yes, if your municipal waste...

  13. Numerical study of the enhancement of combustion performance in a scramjet combustor due to injection of electric-discharge-activated oxygen molecules

    International Nuclear Information System (INIS)

    Starik, A M; Bezgin, L V; Kopchenov, V I; Loukhovitski, B I; Sharipov, A S; Titova, N S

    2013-01-01

    A comprehensive analysis of the efficiency of an approach based on the injection of a thin oxygen stream, subjected to a tailored electric discharge, into a supersonic H 2 –air flow to enhance the combustion performance in the mixing layer and in the scramjet combustor is conducted. It is shown that for such an approach there exist optimal values of reduced electric field E/N and transversal dimension d of the injected oxygen stream, which provide the minimal length of induction zone in the mixing layer. The optimal values of E/N and d depend on air flow parameters and the specific energy put into the oxygen. The injection of a thin oxygen stream (d = 1 mm) subjected to an electric discharge with E/N = 50–100 Td, which produces mostly singlet oxygen O 2 (a  1 Δ g ) and O 2 (b 1 Σ g + ) molecules and atomic oxygen, allows one to arrange stable combustion in a scramjet duct at an extremely low air temperature T air  = 900 K and pressure P air  = 0.3 bar even at a small specific energy put into the oxygen E s  = 0.2 J ncm −3 , and to provide rather high combustion completeness η = 0.73. The advance in the energy released during combustion is much higher (hundred times), in this case, than the energy supplied to the oxygen stream in the electric discharge. This approach also makes it possible to ensure the rather high combustion completeness in the scramjet combustor with reduced length. The main reason for the combustion enhancement of the H 2 –air mixture in the scramjet duct is the intensification of chain-branching reactions due to the injection of a small amount of cold non-equilibrium oxygen plasma comprising highly reactive species, O 2 (a  1 Δ g ) and O 2 (b 1 Σ g + ) molecules and O atoms, into the H 2 –air supersonic flow. (paper)

  14. Combustive management of oil spills

    International Nuclear Information System (INIS)

    1992-01-01

    Extensive experiments with in situ incineration were performed on a desert site at the University of Arizona with very striking results. The largest incinerator, 6 feet in diameter with a 30 foot chimney, developed combustion temperatures of 3000, F, and attendant soot production approximately 1000 times less than that produced by conventional in situ burning. This soot production, in fact, is approximately 30 times less than current allowable EPA standards for incinerators and internal combustion engines. Furthermore, as a consequence of the high temperature combustion, the bum rate was established at a very high 3400 gallons per hour for this particular 6 foot diameter structure. The rudimentary design studies we have carried out relative to a seagoing 8 foot diameter incinerator have predicted that a continuous burn rate of 7000 gallons per hour is realistic. This structure was taken as a basis for operational design because it is compatible with C130 flyability, and will be inexpensive enough ($120,000 per copy) to be stored at those seaside depots throughout the US coast line in which the requisite ancillary equipments (booms, service tugs, etc.) are already deployed. The LOX experiments verified our expectations with respect to combustion of debris and various highly weathered or emulsified oils. We have concluded, however, that the use of liquid oxygen in actual beach clean up is not promising because the very high temperatures associated with this combustion are almost certain to produce environmentally deleterious effects on the beach surface and its immediately sublying structures. However, the use of liquid oxygen augmentation for shore based and flyable incinerators may still play an important role in handing the problem of accumulated debris

  15. Comprehensive study of biodiesel fuel for HSDI engines in conventional and low temperature combustion conditions

    Energy Technology Data Exchange (ETDEWEB)

    Tormos, Bernardo; Novella, Ricardo; Garcia, Antonio; Gargar, Kevin [CMT-Motores Termicos, Universidad Politecnica de Valencia, Valencia, ES, Campus de Vera, s/n, Edificio 6D. Camino de Vera s/n, 46022 Valencia (Spain)

    2010-02-15

    In this research, an experimental investigation has been performed to give insight into the potential of biodiesel as an alternative fuel for High Speed Direct Injection (HSDI) diesel engines. The scope of this work has been broadened by comparing the combustion characteristics of diesel and biodiesel fuels in a wide range of engine loads and EGR conditions, including the high EGR rates expected for future diesel engines operating in the low temperature combustion (LTC) regime. The experimental work has been carried out in a single-cylinder engine running alternatively with diesel and biodiesel fuels. Conventional diesel fuel and neat biodiesel have been compared in terms of their combustion performance through a new methodology designed for isolating the actual effects of each fuel on diesel combustion, aside from their intrinsic differences in chemical composition. The analysis of the results has been sequentially divided into two progressive and complementary steps. Initially, the overall combustion performance of each fuel has been critically evaluated based on a set of parameters used as tracers of the combustion quality, such as the combustion duration or the indicated efficiency. With the knowledge obtained from this previous overview, the analysis focuses on the detailed influence of biodiesel on the different diesel combustion stages known ignition delay, premixed combustion and mixing controlled combustion, considering also the impact on CO and UHC (unburn-hydrocarbons) pollutant emissions. The results of this research explain why the biodiesel fuel accelerates the diesel combustion process in all engine loads and EGR rates, even in those corresponding with LTC conditions, increasing its possibilities as alternative fuel for future DI diesel engines. (author)

  16. Influence of Antioxidant Addition in Jatropha Biodiesel on the Performance, Combustion and Emission Characteristics of a DI Diesel Engine

    Science.gov (United States)

    Arockiasamy, Prabu; Ramachandran Bhagavathiammal, Anand

    2018-04-01

    An experimental investigation is conducted on a single-cylinder DI diesel engine, to evaluate the performance, combustion and emission characteristics of Jatropha biodiesel with the addition of antioxidants namely, Succinimide (C4H5NO2), N,N-Dimethyl p-phenylenediamine dihydrochloride (C8H14Cl2N2) and N-Phenyl- p-phenylenediamine (C6H5NHC6H4NH2) at 500, 1000 and 2000 ppm. The performance, combustion and emission characteristic tests are conducted at a constant speed of 1500 rpm, injection pressure of 215 bar, injection timing of 26° before top dead centre for the nine test fuels and the experimental results are compared with neat diesel and neat biodiesel as base fuels. The experimental results show that the addition of antioxidant in biodiesel suppresses the NO emission by quenching the OH radicals that are produced by the reaction of hydrocarbon radicals with molecular nitrogen. The maximum percentage reduction of NO emission by 5, 6 and 7% are observed for N-Phenyl- p-phenylenediamine, N,N-Dimethyl p-phenylenediamine dihydrochloride and Succinimide blended test fuels at 2000 ppm antioxidant addition with biodiesel.

  17. Fuel and combustion stratification study of Partially Premixed Combustion

    NARCIS (Netherlands)

    Izadi Najafabadi, M.; Dam, N.; Somers, B.; Johansson, B.

    2016-01-01

    Relatively high levels of stratification is one of the main advantages of Partially Premixed Combustion (PPC) over the Homogeneous Charge Compression Ignition (HCCI) concept. Fuel stratification smoothens heat release and improves controllability of this kind of combustion. However, the lack of a

  18. Performance, combustion, and emission characteristics of a diesel engine fueled by biodiesel-diesel mixtures with multi-walled carbon nanotubes additives

    International Nuclear Information System (INIS)

    El-Seesy, Ahmed I.; Abdel-Rahman, Ali K.; Bady, Mahmoud; Ookawara, S.

    2017-01-01

    Highlights: • Considerable improvements in the combustion of JB20D50MWCNTs compared to pure JB20D. • p_m_a_x, dp/dθ_m_a_x and dQg/dθ_m_a_x increased by 7%, 4% and 4%, respectively. • Brake specific fuel consumption decreased by 15%. • NO_x, CO, and UHC reduced by 35%, 50%, and 60%, respectively. • Significant enhancement in all engine performance was achieved at a concentration of 40 mg/l. - Abstract: In this work, the effects of adding Multi-Walled Carbon nanotubes (MWCNTs) to Jojoba methyl ester-diesel blended fuel (JB20D) on performance, combustion and emissions characteristics of a compression-ignition engine were experimentally investigated. The JB20D with 10, 20, 30, 40 and 50 mg/l of MWCNTs were examined at different engine loads and speeds. Compared to pure diesel, the use of JB20D without MWCNTs caused a slight decrease in the engine performance and an increase in the engine emissions at most examined conditions. The MWCNTs–B20D blended fuel attained a maximum increase of 16% in the brake thermal efficiency and a decrease of 15% in the brake specific fuel consumption at the dose level of 50 mg/l compared to JB20D. The MWCNTs-JB20D blended fuel also brought about an enhancement in combustion characteristics where the peak cylinder pressure, the maximum rate of pressure rise and the peak heat release rate were increased by 7%, 4%, and 4%, respectively, at the same dose level. According to the measured emissions, a significant reduction of engine emissions was achieved at the dose level of 20 mg/l, where NO_x, CO, and UHC were reduced by 35%, 50%, and 60%, respectively. According to the obtained results, the recommended concentration of MWCNTs in JB20D was concluded to be 40 mg/l, which could give significant improvements in overall the parameters of engine performance and emissions with a good balance between them.

  19. Large Eddy simulation of turbulent hydrogen-fuelled supersonic combustion in an air cross-flow

    Science.gov (United States)

    Ingenito, A.; Cecere, D.; Giacomazzi, E.

    2013-09-01

    The main aim of this article is to provide a theoretical understanding of the physics of supersonic mixing and combustion. Research in advanced air-breathing propulsion systems able to push vehicles well beyond is of interest around the world. In a scramjet, the air stream flow captured by the inlet is decelerated but still maintains supersonic conditions. As the residence time is very short , the study of an efficient mixing and combustion is a key issue in the ongoing research on compressible flows. Due to experimental difficulties in measuring complex high-speed unsteady flowfields, the most convenient way to understand unsteady features of supersonic mixing and combustion is to use computational fluid dynamics. This work investigates supersonic combustion physics in the Hyshot II combustion chamber within the Large Eddy simulation framework. The resolution of this turbulent compressible reacting flow requires: (1) highly accurate non-dissipative numerical schemes to properly simulate strong gradients near shock waves and turbulent structures away from these discontinuities; (2) proper modelling of the small subgrid scales for supersonic combustion, including effects from compressibility on mixing and combustion; (3) highly detailed kinetic mechanisms (the Warnatz scheme including 9 species and 38 reactions is adopted) accounting for the formation and recombination of radicals to properly predict flame anchoring. Numerical results reveal the complex topology of the flow under investigation. The importance of baroclinic and dilatational effects on mixing and flame anchoring is evidenced. Moreover, their effects on turbulence-scale generation and the scaling law are analysed.

  20. Maximal combustion temperature estimation

    International Nuclear Information System (INIS)

    Golodova, E; Shchepakina, E

    2006-01-01

    This work is concerned with the phenomenon of delayed loss of stability and the estimation of the maximal temperature of safe combustion. Using the qualitative theory of singular perturbations and canard techniques we determine the maximal temperature on the trajectories located in the transition region between the slow combustion regime and the explosive one. This approach is used to estimate the maximal temperature of safe combustion in multi-phase combustion models

  1. Effect of Variant End of Injection Period on Combustion Process of Biodiesel Combustion

    Directory of Open Access Journals (Sweden)

    Khalid Amir

    2016-01-01

    Full Text Available Biodiesel is an alternative fuel as a replacement to the standard diesel fuel in combustion diesel engine. The biodiesel fuel has a significantly influences throughout the combustion process and exhaust emission. The purpose of this research is to investigate the combustion process behavior during the End of Injection (EOI period and operates under variant conditions using Rapid Compression Machine (RCM. Experimental of RCM is used to simulate a combustion process and combustion characteristics of diesel engine combustion. Three types of biodiesel blend which are B5, B10 and B15 were tested at several injection pressures of 80 MPa, 90 MPa and 130 MPa under different ambient temperatures, 750 K to 1100 K. The results of this study showed that the ignition delay slightly reduced with increasing the content of biodiesel blends from B5, B10 and B15 and became more shorten as the injection pressure been enhanced. As the injection pressure increased, the behavior of combustion pressure at end of injection is reduced, radically increased the NOX emission. It is noted that the process of combustion at the end of injection increased as the ambient temperature is rising. In fact, higher initial ambient temperature improved the fuel atomization and mixing process. Under the biodiesel combustion with higher ambient temperature condition, the exhaust emission of CO, O2, and HC became less but increased in NOX emission. Besides, increased in blends of biodiesel ratio are found to enhance the combustion process, resulted a decreased in HC emissions.

  2. Jet plume injection and combustion system for internal combustion engines

    Science.gov (United States)

    Oppenheim, Antoni K.; Maxson, James A.; Hensinger, David M.

    1993-01-01

    An improved combustion system for an internal combustion engine is disclosed wherein a rich air/fuel mixture is furnished at high pressure to one or more jet plume generator cavities adjacent to a cylinder and then injected through one or more orifices from the cavities into the head space of the cylinder to form one or more turbulent jet plumes in the head space of the cylinder prior to ignition of the rich air/fuel mixture in the cavity of the jet plume generator. The portion of the rich air/fuel mixture remaining in the cavity of the generator is then ignited to provide a secondary jet, comprising incomplete combustion products which are injected into the cylinder to initiate combustion in the already formed turbulent jet plume. Formation of the turbulent jet plume in the head space of the cylinder prior to ignition has been found to yield a higher maximum combustion pressure in the cylinder, as well as shortening the time period to attain such a maximum pressure.

  3. Biodesulfurization of coals of different rank: Effect on combustion behavior

    Energy Technology Data Exchange (ETDEWEB)

    Rubiera, F.; Arenillas, A.; Fuente, E.; Pis, J.J. [CSIC, Oviedo (Spain). Inst. Nacional del Carbon; Marteinz, O.; Moran, A. [Univ. de Leon (Spain). Escuela de Ingenieria Tecnica Minera

    1999-02-01

    The emission of sulfur oxides during the combustion of coal is one of the causes, among other air pollution problems, of acid rain. The contribution of coal as the mainstay of power production will be determined by whether its environmental performance is equal or superior to other supply options. In this context, desulfurization of coal before combustion by biological methods was studied. Four Spanish high-sulfur content coals of different rank were inoculated with bacteria isolated from mine-drainage waters and with naturally occurring bacteria inherent in the coals to be treated. Higher levels of desulfurization were obtained in the case of the samples treated with their own accompanying bacteria and when aeration was increased. All the samples were amenable to the biodepyritization processes. However, it is of little value to achieve large sulfur reductions if a decrease in coal combustion performance is obtained in the process. For this reason, a comparison was made between the combustibility characteristics of the original coals and those of the biodesulfurized samples. Results indicated that combustibility was not substantially modified by the overall biological treatment. The benefits of reduced sulfur emissions into the atmosphere ought to be taken into account as part of the general evaluation of the processes.

  4. Path planning during combustion mode switch

    Science.gov (United States)

    Jiang, Li; Ravi, Nikhil

    2015-12-29

    Systems and methods are provided for transitioning between a first combustion mode and a second combustion mode in an internal combustion engine. A current operating point of the engine is identified and a target operating point for the internal combustion engine in the second combustion mode is also determined. A predefined optimized transition operating point is selected from memory. While operating in the first combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion engine to approach the selected optimized transition operating point. When the engine is operating at the selected optimized transition operating point, the combustion mode is switched from the first combustion mode to the second combustion mode. While operating in the second combustion mode, one or more engine actuator settings are adjusted to cause the operating point of the internal combustion to approach the target operating point.

  5. CFD modeling of combustion processes using KIVA3V Code with partially stirred reactor model for turbulence-combustion interactions

    International Nuclear Information System (INIS)

    Jarnicki, R.; Sobiesiak, A.

    2002-01-01

    In order to solve the averaged conservation equations for turbulent reacting flow one is faced with a task of specifying the averaged chemical reaction rate. This is due to turbulence influence on the mean reaction rates that appear in the species concentration Reynolds-averaged equation. In order to investigate the Partially Stirred Reactor (PaSR) combustion model capabilities, a CFD modeling using KIVA3V Code with the PaSR model of two very different combustion processes, was performed. Experimental results were compared with modeling

  6. The development of an electrochemical technique for in situ calibrating of combustible gas detectors

    Science.gov (United States)

    Shumar, J. W.; Lantz, J. B.; Schubert, F. H.

    1976-01-01

    A program to determine the feasibility of performing in situ calibration of combustible gas detectors was successfully completed. Several possible techniques for performing the in situ calibration were proposed. The approach that showed the most promise involved the use of a miniature water vapor electrolysis cell for the generation of hydrogen within the flame arrestor of a combustible gas detector to be used for the purpose of calibrating the combustible gas detectors. A preliminary breadboard of the in situ calibration hardware was designed, fabricated and assembled. The breadboard equipment consisted of a commercially available combustible gas detector, modified to incorporate a water vapor electrolysis cell, and the instrumentation required for controlling the water vapor electrolysis and controlling and calibrating the combustible gas detector. The results showed that operation of the water vapor electrolysis at a given current density for a specific time period resulted in the attainment of a hydrogen concentration plateau within the flame arrestor of the combustible gas detector.

  7. Combustion, detonation, shock waves. Proceedings of the Zel'dovich memorial - International conference on combustion. Volume 1

    International Nuclear Information System (INIS)

    Merzhanov, A.G.; Frolov, S.M.

    1995-01-01

    This book contains lectures by the experts in various fields of modern research in combustion, detonation and shock waves, presented at the Zel'dovich memorial - International conference on combustion dedicated to the 80-th birthday of academician Ya.B. Zel'dovich. There are eight chapters discussing the state-of-the-art in combustion kinetics, ignition and steady-state flame propagation, diffusion and heterogeneous combustion, turbulent combustion, unsteady combustion, detonation, combustion and detonation analogies, intense shock waves and extreme states of matter [ru

  8. Fuels and Combustion

    KAUST Repository

    Johansson, Bengt

    2016-08-17

    This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

  9. Fuels and Combustion

    KAUST Repository

    Johansson, Bengt

    2016-01-01

    This chapter discusses the combustion processes and the link to the fuel properties that are suitable for them. It describes the basic three concepts, including spark ignition (SI) and compression ignition (CI), and homogeneous charge compression ignition (HCCI). The fuel used in a CI engine is vastly different from that in an SI engine. In an SI engine, the fuel should sustain high pressure and temperature without autoignition. Apart from the dominating SI and CI engines, it is also possible to operate with a type of combustion: autoignition. With HCCI, the fuel and air are fully premixed before combustion as in the SI engine, but combustion is started by the increased pressure and temperature during the compression stroke. Apart from the three combustion processes, there are also a few combined or intermediate concepts, such as Spark-Assisted Compression Ignition (SACI). Those concepts are discussed in terms of the requirements of fuel properties.

  10. Ash Deposit Formation and Deposit Properties. A Comprehensive Summary of Research Conducted at Sandia's Combustion Research Facility

    Energy Technology Data Exchange (ETDEWEB)

    Larry L. Baxter

    2000-08-01

    This report summarizes experimental and theoretical work performed at Sandia's Combustion Research Facility over the past eight years on the fate of inorganic material during coal combustion. This work has been done under four broad categories: coal characterization, fly ash formation, ash deposition, and deposit property development. The objective was to provide sufficient understanding of these four areas to be able to predict coal behavior in current and advanced conversion systems. This work has led to new characterization techniques for fuels that provide, for the first time, systematic and species specific information regarding the inorganic material. The transformations of inorganic material during combustion can be described in terms of the net effects of the transformations of these individual species. Deposit formation mechanisms provide a framework for predicting deposition rates for abroad range of particle sizes. Predictions based on these rates many times are quite accurate although there are important exceptions. A rigorous framework for evaluating deposit has been established. Substantial data have been obtained with which to exercise this framework, but this portion of the work is less mature than is any other. Accurate prediction of deposit properties as functions of fuel properties, boiler design, and boiler operating conditions represents the single most critical area where additional research is needed.

  11. On the high-temperature combustion of n-butanol: Shock tube data and an improved kinetic model

    KAUST Repository

    Vasu, Subith S.

    2013-11-21

    The combustion of n-butanol has received significant interest in recent years, because of its potential use in transportation applications. Researchers have extensively studied its combustion chemistry, using both experimental and theoretical methods; however, additional work is needed under specific conditions to improve our understanding of n-butanol combustion. In this study, we report new OH time-history data during the high-temperature oxidation of n-butanol behind reflected shock waves over the temperature range of 1300-1550 K and at pressures near 2 atm. These data were obtained at Stanford University, using narrow-line-width ring dye laser absorption of the R1(5) line of OH near 306.7 nm. Measured OH time histories were modeled using comprehensive n-butanol literature mechanisms. It was found that n-butanol unimolecular decomposition rate constants commonly used in chemical kinetic models, as well as those determined from theoretical studies, are unable to predict the data presented herein. Therefore, an improved high-temperature mechanism is presented here, which incorporates recently reported rate constants measured in a single pulse shock tube [C. M. Rosado-Reyes and W. Tsang, J. Phys. Chem. A 2012, 116, 9825-9831]. Discussions are presented on the validity of the proposed mechanism against other literature shock tube experiments. © 2013 American Chemical Society.

  12. Advanced coal combustion technologies and their environmental impact

    International Nuclear Information System (INIS)

    Bozicevic, Maja; Feretic, Danilo; Tomsic, Zeljko

    1997-01-01

    Estimations of world energy reserves show that coal will remain the leading primary energy source for electricity production in the foreseeable future. In order to comply with ever stricter environmental regulations and to achieve efficient use of limited energy resources, advanced combustion technologies are being developed. The most promising are the pressurised fluidized bed combustion (PFBC) and the integrated gasification combined cycle (IGCC). By injecting sorbent in the furnace, PFBC removes more than 90 percent of SO 2 in flue gases without additional emission control device. In addition, due to lower combustion temperature, NO x emissions are around 90 percent lower than those from pulverised coal (PC) plant. IGCC plant performance is even more environmentally expectable and its high efficiency is a result of a combined cycle usage. Technical, economic and environmental characteristics of mentioned combustion technologies will be presented in this paper. Comparison of PFBC, IGCC and PC power plants economics and air impact will also be given. (Author)

  13. Catalytic reduction of emissions from small scale wood combustion. State of the art

    Energy Technology Data Exchange (ETDEWEB)

    Hargitai, T.; Silversand, F.A. [Katator AB, Lund (Sweden)

    1998-12-31

    Small-scale combustion of big-fuel often results in excessive emissions of volatile organic compounds (VOC), polyaromatic compounds (PAM) and carbon monoxide (CO). These compounds have a negative impact on human health and urban air quality. The predominant volatile organic compounds present in flue gases from big-fuel combustion are propylene, ethylene, butadiene, methanol, ethanol, methane, phenol and benzene. The poor combustion performance of some wood stoves has in certain cases led to legislation against small-scale combustion of big-fuel in urban areas. Catalytic cleaning is one very efficient way of decreasing the environmental impacts of big-fuel combustion. Several studies concerning catalytic purification of flue gases from big-fuel combustion have been presented over the years. Several problems must be addressed when designing a catalyst for this application: Clogging problems from deposition of ashes and particulates in the catalyst; Catalyst poisoning by sulphur, phosphorus, alkali metals etc.; Catalyst fouling due to deposition of ashes and particulates; Catalyst overheating at high flue-gas temperatures and Poor catalyst performance during start-up Most studies have been focused on monolith-type catalysts and- the conversion of CO, VOC and PAH typically is above 80 %. The observed problems are associated with increased pressure drop due to catalyst clogging and decreased catalyst performance due to fouling and poisoning. In most cases precious metals, preferably Pt. have been used as active combustion catalyst. Precious metals have a high activity for the combustion of CO and hydrocarbons and a fair stability against poisoning with compounds present in flue gases from big-fuel, e.g. sulphur and alkali metals. The majority of the studies on precious metals have been focused on Pt. Rh and Pd, which are especially active in catalytic combustion. Some metal oxides are used in catalytic combustion, especially at low temperatures (e.g. in VOC abatement

  14. Direct Numerical Simulations for Combustion Science: Past, Present, and Future

    KAUST Repository

    Im, Hong G.

    2017-01-01

    Direct numerical simulations (DNS) of turbulent combustion have evolved tremendously in the past decades, thanks to the rapid advances in high performance computing technology. Today’s DNS is capable of incorporating detailed reaction mechanisms and transport properties, with physical parameter ranges approaching laboratory scale flames, thereby allowing direct comparison and cross-validation against laser diagnostic measurements. While these developments have led to significantly improved understanding of fundamental turbulent flame characteristics, there are increasing demands to explore combustion regimes at higher levels of turbulent Reynolds (Re) and Karlovitz (Ka) numbers, with a practical interest in new combustion engines driving towards higher efficiencies and lower emissions. This chapter attempts to provide a brief historical review of the progress in DNS of turbulent combustion during the past decades. Major scientific accomplishments and contributions towards fundamental understanding of turbulent combustion will be summarized and future challenges and research needs will be proposed.

  15. Direct Numerical Simulations for Combustion Science: Past, Present, and Future

    KAUST Repository

    Im, Hong G.

    2017-12-12

    Direct numerical simulations (DNS) of turbulent combustion have evolved tremendously in the past decades, thanks to the rapid advances in high performance computing technology. Today’s DNS is capable of incorporating detailed reaction mechanisms and transport properties, with physical parameter ranges approaching laboratory scale flames, thereby allowing direct comparison and cross-validation against laser diagnostic measurements. While these developments have led to significantly improved understanding of fundamental turbulent flame characteristics, there are increasing demands to explore combustion regimes at higher levels of turbulent Reynolds (Re) and Karlovitz (Ka) numbers, with a practical interest in new combustion engines driving towards higher efficiencies and lower emissions. This chapter attempts to provide a brief historical review of the progress in DNS of turbulent combustion during the past decades. Major scientific accomplishments and contributions towards fundamental understanding of turbulent combustion will be summarized and future challenges and research needs will be proposed.

  16. Selected parameters of maize straw briquettes combustion

    Directory of Open Access Journals (Sweden)

    Kraszkiewicz Artur

    2018-01-01

    Full Text Available An analysis of the process of burning briquettes made of maize straw was performed. A number of traits have been evaluated, including physical characteristics of the fuel through parameters describing combustion kinetics as well as products and combustion efficiency. The study was conducted in a grate boiler, during which the differentiating factor was the air velocity flowing to the boiler. It was observed that the obtained values of the considered parameters were different, particularly temperature of the flue gas and the amount of CO and SO2 in the flue gas.

  17. Application of macro-cellular SiC reactor to diesel engine-like injection and combustion conditions

    Science.gov (United States)

    Cypris, Weclas, M.; Greil, P.; Schlier, L. M.; Travitzky, N.; Zhang, W.

    2012-05-01

    One of novel combustion technologies for low emissions and highly efficient internal combustion engines is combustion in porous reactors (PM). The heat release process inside combustion reactor is homogeneous and flameless resulting in a nearly zero emissions level. Such combustion process, however is non-stationary, is performed under high pressure with requirement of mixture formation directly inside the combustion reactor (high pressure fuel injection). Reactor heat capacity resulting in lowering of combustion temperature as well as internal heat recuperation during the engine cycle changes the thermodynamic conditions of the process as compared to conventional engine. For the present investigations a macro-cellular lattice structure based on silicon carbide (non-foam structure) with 600 vertical cylindrical struts was fabricated and applied to engine-like combustion conditions (combustion chamber). The lattice design with a high porosity > 80% was shaped by indirect three-dimensional printing of a SiC powder mixed with a dextrin binder which also serves as a carbon precursor. In order to perform detailed investigations on low-and high-temperature oxidation processes in porous reactors under engine-like conditions, a special combustion chamber has been built and equipped with a Diesel common-rail injection system. This system simulates the thermodynamic conditions at the time instance of injection onset (corresponding to the nearly TDC of compression in a real engine). Overall analysis of oxidation processes (for variable initial pressure, temperature and air excess ratio) for free Diesel spray combustion and for combustion in porous reactor allows selection of three regions representing different characteristics of the oxidation process represented by a single-step and multi-step reactions Another characteristic feature of investigated processes is reaction delay time. There are five characteristic regions to be selected according to the delay time (t) duration

  18. A new wall function boundary condition including heat release effect for supersonic combustion flows

    International Nuclear Information System (INIS)

    Gao, Zhen-Xun; Jiang, Chong-Wen; Lee, Chun-Hian

    2016-01-01

    Highlights: • A new wall function including heat release effect is theoretically derived. • The new wall function is a unified form holding for flows with/without combustion. • The new wall function shows good results for a supersonic combustion case. - Abstract: A new wall function boundary condition considering combustion heat release effect (denoted as CWFBC) is proposed, for efficient predictions of skin friction and heat transfer in supersonic combustion flows. Based on a standard flow model including boundary-layer combustion, the Shvab–Zeldovich coupling parameters are introduced to derive a new velocity law-of-the-wall including the influence of combustion. For the temperature law-of-the-wall, it is proposed to use the enthalpy–velocity relation, instead of the Crocco–Busemann equation, to eliminate explicit influence of chemical reactions. The obtained velocity and temperature law-of-the-walls constitute the CWFBC, which is a unified form simultaneously holding for single-species, multi-species mixing and multi-species reactive flows. The subsequent numerical simulations using this CWFBC on an experimental case indicate that the CWFBC could accurately reflect the influences on the skin friction and heat transfer by the chemical reactions and heat release, and show large improvements compared to previous WFBC. Moreover, the CWFBC can give accurate skin friction and heat flux for a coarse mesh with y"+ up to 200 for the experimental case, except for slightly larger discrepancy of the wall heat flux around ignition position.

  19. Enhanced efficiency of internal combustion engines by employing spinning gas.

    Science.gov (United States)

    Geyko, V I; Fisch, N J

    2014-08-01

    The efficiency of the internal combustion engine might be enhanced by employing spinning gas. A gas spinning at near sonic velocities has an effectively higher heat capacity, which allows practical fuel cycles, which are far from the Carnot efficiency, to approach more closely the Carnot efficiency. A remarkable gain in fuel efficiency is shown to be theoretically possible for the Otto and Diesel cycles. The use of a flywheel, in principle, could produce even greater increases in efficiency.

  20. Homogeneous charge combustion of aqueous ethanol

    Science.gov (United States)

    2001-02-01

    The goal of this research is to reduce nitrous oxide (NOx) and carbon monoxide (CO) emissions and to retain the performance characteristics of a diesel engine by modifying the in-cylinder combustion process. To accomplish this goal, a direct-injected...

  1. Characterization of Oxy-combustion Impacts in Existing Coal-fired Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Bradley Adams; Andrew Fry; Constance Senior; Hong Shim; Huafeng Wang; Jost Wendt; Christopher Shaddix

    2009-06-30

    This report summarizes Year 1 results of a research program designed to use multi-scale experimental studies and fundamental theoretical models to characterize and predict the impacts of retrofit of existing coal-fired utility boilers for oxy-combustion. Through the course of Year 1 activities, great progress was made toward understanding the issues associated with oxy-combustion retrofit of coal-fired boilers. All four Year 1 milestones and objectives have been, or will be, completed on schedule and within budget. Progress in the four milestone areas may be summarized as follows: • University of Utah has performed size segregated ash composition measurements in the Oxy-Fuel Combustor (OFC). These experiments indicate that oxy-combustion retrofit may impact ash aerosol mineral matter composition. Both flame temperature and flue gas composition have been observed to influence the concentration of calcium, magnesium and iron in the fine particulate. This could in turn impact boiler fouling and slagging. • Sandia National Labs has shown that char oxidation rate is dependent on particle size (for sizes between 60 and 100 microns) by performing fundamental simulations of reacting char particles. These predictions will be verified by making time-resolved optical measurements of char particle temperature, velocity and size in bench-scale experiments before the end of Year 1. • REI and Siemens have completed the design of an oxy-research burner that will be mounted on University of Utah’s pilot-scale furnace, the L1500. This burner will accommodate a wide range of O2, FGR and mixing strategies under conditions relevant for utility boiler operation. Through CFD modeling of the different burner designs, it was determined that the key factor influencing flame stabilization location is particle heat-up rate. The new oxy-research burner and associated equipment is scheduled for delivery before the end of Year 1. • REI has completed a literature survey of slagging and

  2. Theoretical investigations on improving performance of cooling systems for fuel cell vehicles; Theoretische Untersuchungen zur Kuehlleistungssteigerung durch innovative Kuehlsysteme fuer Brennstoffzellen-Elektrofahrzeuge

    Energy Technology Data Exchange (ETDEWEB)

    Reichler, Mark

    2008-04-01

    In this work theoretical investigations are carried out for cooling systems, which are used in fuel cell vehicles. This work focuses mainly on the capability of increasing the heat rejection rate by using new alternative cooling systems and by improving the conventional cooling system. Fuel cell vehicles have a higher demand of heat rejection to the ambient than comparable vehicles with combustion engine. The performance of conventional liquid cooling systems, especially at high loads and high ambient temperatures, is often not sufficient anymore. Hence, cooling systems with improved performance are necessary for fuel cell vehicles. The investigations in this work are based on DaimlerChrysler's ''A-Class'' having a PEM-Fuel Cell system integrated. Specific computational models are developed for radiators and condensers to evaluate the performance of different cooling concepts. The models are validated with experimental data. Based on an intensive investigation in the open literature the state of the art of cooling systems for fuel cell vehicles is depicted. Furthermore new cooling concepts as an alternative to the liquid cooling system are presented. The method of cooling the fuel cell by using two-phase transition shows the greatest capability to increase the cooling performance. Hence, this concept is investigated in detail. Two different concepts with three different refrigerants (R113, R245fa und R236fa) are analyzed. Cooling performance of this concept shows improvement of 18.2 up to 32.6 % compared to the conventional liquid cooling system. Thus, a two phase cooling system represents an alternative cooling system for fuel cell vehicles, which should be closer investigated by experiments. (orig.)

  3. Lump wood combustion process

    Science.gov (United States)

    Kubesa, Petr; Horák, Jiří; Branc, Michal; Krpec, Kamil; Hopan, František; Koloničný, Jan; Ochodek, Tadeáš; Drastichová, Vendula; Martiník, Lubomír; Malcho, Milan

    2014-08-01

    The article deals with the combustion process for lump wood in low-power fireplaces (units to dozens of kW). Such a combustion process is cyclical in its nature, and what combustion facility users are most interested in is the frequency, at which fuel needs to be stoked to the fireplace. The paper defines the basic terms such as burnout curve and burning rate curve, which are closely related to the stocking frequency. The fuel burning rate is directly dependent on the immediate thermal power of the fireplace. This is also related to the temperature achieved in the fireplace, magnitude of flue gas losses and the ability to generate conditions favouring the full burnout of the fuel's combustible component, which, at once ensures the minimum production of combustible pollutants. Another part of the paper describes experiments conducted in traditional fireplaces with a grate, at which well-dried lump wood was combusted.

  4. Experimental study of the effects of natural gas injection timing on the combustion performance and emissions of a turbocharged common rail dual-fuel engine

    International Nuclear Information System (INIS)

    Yang, Bo; Wei, Xing; Xi, Chengxun; Liu, Yifu; Zeng, Ke; Lai, Ming-Chia

    2014-01-01

    Highlights: • Natural gas injection timing has obvious effects on combustion of dual-fuel engine. • Combustion performance is improved with optimized natural gas injection timing. • BSHC and BSCO decreased with retarded natural gas injection timing at low load. • BSNO x increased at part load while reduced at high load with delay N.G. injection. • PM is very low and insensitive to the variation of natural gas injection timing. - Abstract: Natural gas combustion with pilot ignition has been considered to be one of the most promising ways to utilize natural gas in existing diesel engine without serious engine modification and it has been widely researched all over the world. In this study, three experiments of different loads (BMEP 0.240 MPa, 0.480 MPa and 0.767 MPa) were performed on a 2.8 L four-cylinder, natural gas manifold injection dual-fuel engine to investigate the effects of natural gas injection timing on engine combustion performance and emissions. The pilot injection parameters (pilot injection timing and pressure) and natural gas injection pressure remain constant at a speed of 1600 rpm in the experiment. The cylinder pressure, HRR, CoV imep , flame development duration, CA50 and brake thermal efficiency were analyzed. The results indicated that under low and part engine loads, the flame development duration and CA50 can be reduced by properly retarding natural gas injection timing, while the CoV imep increased with retarded natural gas injection timing. As a result, the brake thermal efficiency is increased and the combustion stability slightly deteriorates. Meanwhile, under low and part engine loads, PM emissions in the dual-fuel engine is much lower than that in conventional diesel engines, furthermore, at high load, the PM emissions are near zero. CO and HC emissions are reduced with retarded natural gas injection timing under low and part loads, however, NO x emissions are slightly increased. Under high load, the flame development duration

  5. Efficient low-temperature soot combustion by bimetallic Ag-Cu/SBA-15 catalysts.

    Science.gov (United States)

    Wen, Zhaojun; Duan, Xinping; Hu, Menglin; Cao, Yanning; Ye, Linmin; Jiang, Lilong; Yuan, Youzhu

    2018-02-01

    In this study, the effects of copper (Cu) additive on the catalytic performance of Ag/SBA-15 in complete soot combustion were investigated. The soot combustion performance of bimetallic Ag-Cu/SBA-15 catalysts was higher than that of monometallic Ag and Cu catalysts. The optimum catalytic performance was acquired with the 5Ag 1 -Cu 0.1 /SBA-15 catalyst, on which the soot combustion starts at T ig =225°C with a T 50 =285°C. The temperature for 50% of soot combustion was lower than that of conventional Ag-based catalysts to more than 50°C (Aneggi et al., 2009). Physicochemical characterizations of the catalysts indicated that addition of Cu into Ag could form smaller bimetallic Ag-Cu nanolloy particles, downsizing the mean particle size from 3.7nm in monometallic catalyst to 2.6nm in bimetallic Ag-Cu catalyst. Further experiments revealed that Ag and Cu species elicited synergistic effects, subsequently increasing the content of surface active oxygen species. As a result, the structure modifications of Ag by the addition of Cu strongly intensified the catalytic performance. Copyright © 2017. Published by Elsevier B.V.

  6. Combustion Research Laboratory

    Data.gov (United States)

    Federal Laboratory Consortium — The Combustion Research Laboratory facilitates the development of new combustion systems or improves the operation of existing systems to meet the Army's mission for...

  7. Natural gas combustion and indoor air quality in domestic premises; Combustion du gaz naturel et qualite de l'air a l'interieur des habitations

    Energy Technology Data Exchange (ETDEWEB)

    Occhio, L.; Riva, A. [Snam, (Italy); Canci, F.; Scevarolli, V. [Italgas, Torino (Italy)

    2000-07-01

    Indoor air quality depends on many factors; combustion appliances are one of the sources of emissions inside dwellings. Their installation is regulated by UNI-CIG standards which also establish the ventilation and aeration requirements needed to guarantee the safety and healthiness of the environment. In order to critically evaluate the effect on indoor air quality of using gas appliances under different operational regimes and in different types of building, Snam and Italgas have developed a research project in co-operation with Enitecnologie and Turin Polytechnic, even to provide theoretical and experimental support for standardisation activities. The results of the presented research include experimental measurements made in real buildings, mathematical modelling and analysis of Italian and international literature. The results show that use of combustion appliances has little influence on indoor air quality and does not affect people's health. (authors)

  8. Combustion chemistry and formation of pollutants; Chimie de la combustion et formation des polluants

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-12-31

    This book of proceedings reports on 7 papers on combustion chemistry and formation of pollutants presented during the workshop organized by the `Combustion and Flames` section of the French society of thermal engineers. The chemistry of combustion is analyzed in various situations such as: turbojet engines, spark ignition engines, industrial burners, gas turbines etc... Numerical simulation is used to understand the physico-chemical processes involved in combustion, to describe the kinetics of oxidation, combustion and flame propagation, and to predict the formation of pollutants. (J.S.)

  9. Numerical simulation of turbulent combustion: Scientific challenges

    Science.gov (United States)

    Ren, ZhuYin; Lu, Zhen; Hou, LingYun; Lu, LiuYan

    2014-08-01

    Predictive simulation of engine combustion is key to understanding the underlying complicated physicochemical processes, improving engine performance, and reducing pollutant emissions. Critical issues as turbulence modeling, turbulence-chemistry interaction, and accommodation of detailed chemical kinetics in complex flows remain challenging and essential for high-fidelity combustion simulation. This paper reviews the current status of the state-of-the-art large eddy simulation (LES)/prob-ability density function (PDF)/detailed chemistry approach that can address the three challenging modelling issues. PDF as a subgrid model for LES is formulated and the hybrid mesh-particle method for LES/PDF simulations is described. Then the development need in micro-mixing models for the PDF simulations of turbulent premixed combustion is identified. Finally the different acceleration methods for detailed chemistry are reviewed and a combined strategy is proposed for further development.

  10. Effect of external hot EGR dilution on combustion, performance and particulate emissions of a GDI engine

    International Nuclear Information System (INIS)

    Xie, Fangxi; Hong, Wei; Su, Yan; Zhang, Miaomiao; Jiang, Beiping

    2017-01-01

    Highlights: • Effect of hot EGR on combustion and PN emission is investigated on a GDI engine. • Appropriate addition of hot EGR can reduce fuel consumption, NO_x and PN emission. • Relationship between BSFC and emissions of hot EGR is better than cooled EGR. • Condition with low-medium speeds and medium loads are more suitable for hot EGR. - Abstract: In this paper, an experimental investigation about the influence of hot EGR addition on the engine combustion, performance and particulate number emission was conducted at a spark-ignition gasoline direct injection (GDI) engine. Meanwhile, the different effects between cooled and hot EGR addition methods were compared and the variations of fuel consumption and particle number emissions under six engine operating conditions with different speeds and loads were analyzed. The research result indicated that increasing hot EGR ratio properly with adjustment of ignition timing could effectively improve the relationship among brake-specific fuel consumption (BSFC), NO_x and particle number emissions. When hot EGR ratio increased to 20%, not only BSFC but also the NO_x and particle number emissions were reduced, which were about 7%, 87% and 36% respectively. Compared with cooled EGR, the flame development and propagation speeds were accelerated, and cycle-by-cycle combustion variation decreased with hot EGR. Meanwhile, using hot EGR made the engine realize a better relationship among fuel consumption, NO_x and particle number emissions. The biggest improvements of BSFC, NO_x and particle number emissions were obtained at low-medium speed and medium load engine conditions by hot EGR addition method. While engine speed increased and load decreased, the improvement of engine fuel consumption and emission reduced with hot EGR method.

  11. Theoretical Investigation of Kinetic Processes in Small Radicals of Importance in Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, Millard [Univ. of Maryland, College Park, MD (United States). Dept. of Chemistry and Biochemistry; Dagdigian, Paul J. [Johns Hopkins Univ., Baltimore, MD (United States). Dept. of Chemistry

    2017-12-12

    Our group studies inelastic and reactive collisions of small molecules, focusing on radicals important in combustion environments. The goal is the better understanding of kinetic processes that may be difficult to access experimentally. An essential component is the accurate determination and fitting of potential energy surfaces (PESs). After fitting the ab initio points to obtain global PESs, we treat the dynamics using time-independent (close-coupling) methods. Cross sections and rate constants for collisions of are determined with our Hibridon program suite . We have studied energy transfer (rotationally, vibrationally, and/or electronically inelastic) in small hydrocarbon radicals (CH2 and CH3) and the CN radical. We have made a comparison with experimental measurements of relevant rate constants for collisions of these radicals. Also, we have calculated accurate transport properties using state-of-the-art PESs and to investigate the sensitivity to these parameters in 1-dimensional flame simulations. Of particular interest are collision pairs involving the light H atom.

  12. A spectroscopy study of gasoline partially premixed compression ignition spark assisted combustion

    International Nuclear Information System (INIS)

    Pastor, J.V.; García-Oliver, J.M.; García, A.; Micó, C.; Durrett, R.

    2013-01-01

    Highlights: ► PPC combustion combined with spark assistance and gasoline fuel on a CI engine. ► Chemiluminescence of different chemical species describes the progress of combustion reaction. ► Spectra of a novel combustion mode under SACI conditions is described. ► UV–Visible spectrometry, high speed imaging and pressure diagnostic were employed for analysis. - Abstract: Nowadays many research efforts are focused on the study and development of new combustion modes, mainly based on the use of locally lean air–fuel mixtures. This characteristic, combined with exhaust gas recirculation, provides low combustion temperatures that reduces pollutant formation and increases efficiency. However these combustion concepts have some drawbacks, related to combustion phasing control, which must be overcome. In this way, the use of a spark plug has shown to be a good solution to improve phasing control in combination with lean low temperature combustion. Its performance is well reported on bibliography, however phenomena involving the combustion process are not completely described. The aim of the present work is to develop a detailed description of the spark assisted compression ignition mode by means of application of UV–Visible spectrometry, in order to improve insight on the combustion process. Tests have been performed in an optical engine by means of broadband radiation imaging and emission spectrometry. The engine hardware is typical of a compression ignition passenger car application. Gasoline was used as the fuel due to its low reactivity. Combining broadband luminosity images with pressure-derived heat-release rate and UV–Visible spectra, it was possible to identify different stages of the combustion reaction. After the spark discharge, a first flame kernel appears and starts growing as a premixed flame front, characterized by a low and constant heat-release rate in combination with the presence of remarkable OH radical radiation. Heat release increases

  13. Gas Emissions in Combustion of Biofuel

    Directory of Open Access Journals (Sweden)

    Vitázek Ivan

    2014-10-01

    Full Text Available Nowadays, biomass or more precisely biofuel is more and more being exploited as a substitute for fossil fuels for heating as well as for example for heating a drying environment. This contribution focuses on assessing a heat source by combusting various types of solid biofuels. It is a boiler VIGAS 25 with AK 2000 regulation for heating a family house. Gaseous emissions were measured using a device TESTO 330-2LL. Firewood, peat briquettes, bark briquettes and hardwood briquettes were burnt. Results of experimental measurements concerning the production of gaseous emissions are processed in tables and graphs depending on boiler performance and combustion time.

  14. Twenty-fifth symposium (international) on combustion

    International Nuclear Information System (INIS)

    Anon.

    1994-01-01

    Approximately two-thirds of the papers presented at this conference are contained in this volume. The other one-third appear in special issues of ''Combustion and Flame'', Vol. 99, 1994 and Vol. 100, 1995. Papers are divided into the following sections: Supersonic combustion; Detonations and explosions; Internal combustion engines; Practical aspects of combustion; Incineration and wastes; Sprays and droplet combustion; Coal and organic solids combustion; Soot and polycyclic aromatic hydrocarbons; Reaction kinetics; NO x ; Turbulent flames; Turbulent combustion; Laminar flames; Flame spread, fire and halogenated fire suppressants; Global environmental effects; Ignition; Two-phase combustion; Solid propellant combustion; Materials synthesis; Microgravity; and Experimental diagnostics. Papers have been processed separately for inclusion on the data base

  15. Numerical modeling of sodium fire – Part II: Pool combustion and combined spray and pool combustion

    International Nuclear Information System (INIS)

    Sathiah, Pratap; Roelofs, Ferry

    2014-01-01

    Highlights: • A CFD based method is proposed for the simulation of sodium pool combustion. • A sodium evaporation based model is proposed to model sodium pool evaporation. • The proposed method is validated against sodium pool experiments of Newman and Payne. • The results obtained using the proposed method are in good agreement with the experiments. - Abstract: The risk of sodium-air reaction has received considerable attention after the sodium-fire accident in Monju reactor. The fires resulting from the sodium-air reaction can be detrimental to the safety of a sodium fast reactor. Therefore, predicting the consequences of a sodium fire is important from a safety point of view. A computational method based on CFD is proposed here to simulate sodium pool fire and understand its characteristics. The method solves the Favre-averaged Navier-Stokes equation and uses a non-premixed mixture fraction based combustion model. The mass transfer of sodium vapor from the pool surface to the flame is obtained using a sodium evaporation model. The proposed method is then validated against well-known sodium pool experiments of Newman and Payne. The flame temperature and location predicted by the model are in good agreement with experiments. Furthermore, the trends of the mean burning rate with initial pool temperature and oxygen concentration are captured well. Additionally, parametric studies have been performed to understand the effects of pool diameter and initial air temperature on the mean burning rate. Furthermore, the sodium spray and sodium pool combustion models are combined to simulate simultaneous spray and pool combustion. Simulations were performed to demonstrate that the combined code could be applied to simulate this. Once sufficiently validated, the present code can be used for safety evaluation of a sodium fast reactor

  16. Numerical modeling of sodium fire – Part II: Pool combustion and combined spray and pool combustion

    Energy Technology Data Exchange (ETDEWEB)

    Sathiah, Pratap, E-mail: pratap.sathiah78@gmail.com [Shell Global Solutions Ltd., Brabazon House, Concord Business Park, Threapwood Road, Manchester M220RR (United Kingdom); Roelofs, Ferry, E-mail: roelofs@nrg.eu [Nuclear Research and Consultancy Group (NRG), Westerduinweg 3, 1755ZG Petten (Netherlands)

    2014-10-15

    Highlights: • A CFD based method is proposed for the simulation of sodium pool combustion. • A sodium evaporation based model is proposed to model sodium pool evaporation. • The proposed method is validated against sodium pool experiments of Newman and Payne. • The results obtained using the proposed method are in good agreement with the experiments. - Abstract: The risk of sodium-air reaction has received considerable attention after the sodium-fire accident in Monju reactor. The fires resulting from the sodium-air reaction can be detrimental to the safety of a sodium fast reactor. Therefore, predicting the consequences of a sodium fire is important from a safety point of view. A computational method based on CFD is proposed here to simulate sodium pool fire and understand its characteristics. The method solves the Favre-averaged Navier-Stokes equation and uses a non-premixed mixture fraction based combustion model. The mass transfer of sodium vapor from the pool surface to the flame is obtained using a sodium evaporation model. The proposed method is then validated against well-known sodium pool experiments of Newman and Payne. The flame temperature and location predicted by the model are in good agreement with experiments. Furthermore, the trends of the mean burning rate with initial pool temperature and oxygen concentration are captured well. Additionally, parametric studies have been performed to understand the effects of pool diameter and initial air temperature on the mean burning rate. Furthermore, the sodium spray and sodium pool combustion models are combined to simulate simultaneous spray and pool combustion. Simulations were performed to demonstrate that the combined code could be applied to simulate this. Once sufficiently validated, the present code can be used for safety evaluation of a sodium fast reactor.

  17. Experiential study on temperature and emission performance of micro burner during porous media combustion

    Science.gov (United States)

    Janvekar, Ayub Ahmed; Abdullah, M. Z.; Ahmad, Z. A.; Abas, A.; Ismail, A. K.; Hussien, A. A.; Kataraki, P. S.; Ishak, M. H. H.; Mazlan, M.; Zubair, A. F.

    2018-05-01

    Addition of porous materials in reaction zone give rise to significant improvements in combustion performance. In this work, a dual layered micro porous media burner was tested for stable flame and emissions. Reaction and preheat layer was made up of discrete (zirconia) and foam (porcelain) type of materials respectively. Three different thickness of reaction zone was tested, each with 10, 20 and 30mm. Interestingly, only 20mm thick layer can able to show better thermal efficiency of 72% as compared to 10 and 30mm. Best equivalence ratio came out to be 0.7 for surface and 0.6 for submerged flame conditions. Moreover, emission was continuously monitored to detect presence of NOx and CO, which were under controlled limits.

  18. Preparation of porous Al2O3-Ti-C perform by combustion synthesis

    Directory of Open Access Journals (Sweden)

    K.Granat

    2009-04-01

    Full Text Available Using combustion synthesis porous ceramic preforms for composite reinforcing were produced. Prepared mixture of alumina Saffilfibres, Ti powder and graphite flakes, after drying were placed in waveguide of microwave reactor. Supplied with constant power of 540Wmagnetron ignited and maintained reaction in flowing stream of CO2 gas. Al2O3 fibres should improve preliminary endurance of perform,whereas Ti powder processed to hard titanium carbides and oxides. During microwave heating ignited plasma additionally improveprocess and partly fused metallic Ti. Recorded temperature curves were similar for various samples. The highest synthesis temperature revealed samples containing 10% of Al2O3 , 10% of Ti and 5% of graphite, all percentages atomic. Microscopic observation showed considerable microstructure inhomogeneity of some samples. Both irregular component ordering and partly processed Ti particles inside preform exclude them for subsequent infiltration. Chemical analyze EDS of Ti based compounds partly confirmed work purpose, evidencing presence of Ti oxides and carbides. Independently of graphite content these compounds formed folded strips around solid or empty volume. Depends on CO2 availability, reaction could be slowed down resulting in more compacted Ti compounds. Created as a result of combustion synthesis Ti compound after infiltration with liquid metal properly bounded with the matrix. It could be assumed that redox reaction proceeded and on surface of Ti compound alumina and Al-Ti compounds were created. The preforms of proper strength and homogeneous structure were infiltrated with AlSi7Mg by squeeze casting method. In relation to typical composite reinforced only with fibres no significant increase of defects quantity was observed. Preliminary examination of mechanical properties confirmed that assumed work purpose is reasonable.

  19. Development of a new reduced hydrogen combustion mechanism with NO_x and parametric study of hydrogen HCCI combustion using stochastic reactor model

    International Nuclear Information System (INIS)

    Maurya, Rakesh Kumar; Akhil, Nekkanti

    2017-01-01

    Highlights: • PDF based stochastic reactor model used for study of hydrogen HCCI engine. • New reduced hydrogen combustion mechanism with NOx developed (30 species and 253 reactions). • Mechanism predicts cylinder pressure and captures NO_x emission trend with sufficient accuracy. • Parametric study of hydrogen HCCI engine over wide range of speed and load conditions. • Hydrogen HCCI operating range increases with compression ratio & decreases with engine speed. - Abstract: Hydrogen is a potential alternative and renewable fuel for homogenous charge compression ignition (HCCI) engine to achieve higher efficiency and zero emissions of CO, unburned hydrocarbons as well as other greenhouse gases such as CO_2 and CH_4. In this study, a detailed hydrogen oxidation mechanism with NO_x was developed by incorporating additional species and NO_x reactions to the existing hydrogen combustion mechanism (10 species and 40 reactions). The detailed hydrogen combustion mechanism used in this study consists of 39 species and 311 reactions. A reduced mechanism consisting 30 species and 253 reactions was also developed by using directed relation graph (DRG) method from detailed mechanism. Developed mechanisms were validated with experimental data by HCCI engine simulation using stochastic reactor model. Sensitivity analysis was performed to identify the most important reactions in hydrogen combustion and NO_x formation in HCCI engine. Pathway analysis was also performed to analyze the important reaction pathways at different temperatures. Results revealed that H2 + HO2 [=] H + H2O2 and O2 + NNH [=] N2 + HO2 are the most significant reactions in the hydrogen HCCI combustion and NO_x formation respectively. Detailed parametric study of HCCI combustion was conducted using developed chemical kinetic model. Numerical simulations are performed at different engine operating condition by varying engine speed (1000–3000 rpm), intake air temperature (380–460 K), and compression

  20. High Frequency Combustion Instabilities of LOx/CH4 Spray Flames in Rocket Engine Combustion Chambers

    NARCIS (Netherlands)

    Sliphorst, M.

    2011-01-01

    Ever since the early stages of space transportation in the 1940’s, and the related liquid propellant rocket engine development, combustion instability has been a major issue. High frequency combustion instability (HFCI) is the interaction between combustion and the acoustic field in the combustion

  1. Decrease of noxious emissions in the residual fuel oil combustion; Disminucion de emisiones nocivas en la combustion de aceite combustible residual

    Energy Technology Data Exchange (ETDEWEB)

    Mandoki W, Jorge [Econergia S. de R. L. de C. V. Mexico, D. F. (Mexico)

    1994-12-31

    The residual fuel oil combustion emits noxious substances such as carbonaceous particulate, nitrogen oxides, and sulfur trioxide at unacceptable levels. Water emulsified in the fuel substantially reduces such emissions, achieving besides, in most of the cases, a net saving in the fuel consumption. The beneficial effects are shown in burning the residual fuel oil as a water emulsion, as well as the method to produce an adequate emulsion. The emulsified fuel technology offers a low cost option to reduce air pollution. The fuel oil quality has been declining during the last decades due to: 1. Increase in the production of crude heavy oils, generally with higher content of asphaltens and sulfur. 2. Less availability of vacuum distillation residues due to its conversion into greater value products. 3. More intensive conversion processes such as catalytic cracking, visbreaking, etc. that increase the asphaltenes concentration in the bottoms, causing instability problems. 4. The increase in the vanadium and other metals content as the concentration of asphaltenes increases. The use of emulsified fuel oil provides an efficient and economical method to substantially reduce the noxious emissions to the atmosphere. The emulsion contains water particles in a diameter between 2 and 20 microns, uniformly distributed in the fuel oil, generally in a proportion generally of 5 to 10%; besides, it contains a tensioactive agent to assure a stable emulsion capable of withstanding the shearing forces of the pumping and distribution systems. When the atomized oil drops get into the combustion chamber, the emulsified water flashes into high pressure steam, originating a violent secondary atomization. The effect of this secondary atomization is the rupture of the oil drops of various hundred microns, producing drops of 5 to 15 microns in diameter. Since the necessary time for combustion is an exponential function of the drop diameter, a very substantial improvement in the combustion is

  2. Combustion Research Facility

    Data.gov (United States)

    Federal Laboratory Consortium — For more than 30 years The Combustion Research Facility (CRF) has served as a national and international leader in combustion science and technology. The need for a...

  3. Investigation of micro burner performance during porous media combustion for surface and submerged flames

    Science.gov (United States)

    Janvekar, Ayub Ahmed; Abdullah, M. Z.; Ahmad, Z. A.; Abas, Aizat; Hussien, Ahmed A.; Kataraki, Pramod S.; Mohamed, Mazlan; Husin, Azmi; Fadzli, Khairil

    2018-05-01

    Porous media combustion is considered to be one of the popular choice due to its tremendous advantages. Such type of combustion liberates not only super stable flame but also maintains emissions parameters below thresholds level. Present study incorporates reaction and preheat layer with discrete and foam type of materials respectively. Burner was made to run in ultra-lean mode. Optimum equivalence ratio was found out to be 0.7 for surface flame, while 0.6 during submerged flame condition. Maximum thermal efficiency was noted to be 81%. Finally, emissions parameters where recorded continuously to measure NOx and CO, which were under global limits.

  4. Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

    Science.gov (United States)

    Roberts, Jr., Charles E.; Chadwell, Christopher J.

    2004-09-21

    The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

  5. An experimental investigation into combustion and performance characteristics of an HCCI gasoline engine fueled with n-heptane, isopropanol and n-butanol fuel blends at different inlet air temperatures

    International Nuclear Information System (INIS)

    Uyumaz, Ahmet

    2015-01-01

    Highlights: • Combustion was retarded with the increase of the amount of isopropanol and n-butanol in the test fuels. • Combustion was advanced with the increase of air inlet temperature on HCCI combustion. • Isopropanol seems more suitable fuel due to controlling the HCCI combustion and preventing knocking. • Almost zero NO emissions were measured when alcohol used except for n-heptane and B20 test fuels. - Abstract: An experimental study was conducted in a single cylinder, four stroke port injection Ricardo Hydra test engine in order to determine the effects of pure n-heptane, the blends of n-heptane and n-butanol fuels B20, B30, B40 (including 20%, 30%, 40% n-butanol and 80%, 70%, 60% n-heptane by vol. respectively) and the blends of n-heptane and isopropanol fuels P20, P30, P40 (including 20%, 30%, 40% isopropanol and 80%, 70%, 60% n-heptane by vol. respectively) on HCCI combustion. Combustion and performance characteristics of n-heptane, n-butanol and isopropanol were investigated at constant engine speed of 1500 rpm and λ = 2 in a HCCI engine. The effects of inlet air temperature were also examined on HCCI combustion. The test results showed that the start of combustion was advanced with the increasing of inlet air temperature for all test fuels. Start of combustion delayed with increasing percentage of n-butanol and isopropanol in the test fuels. Knocking combustion was seen with B20 and n-heptane test fuels. Minimum combustion duration was observed in case of using B40. Almost zero NO emissions were measured with test fuels apart from n-heptane and B20. The test results also showed that CO and HC emissions decreased with the increase of inlet air temperature for all test fuels. Isopropanol showed stronger resistance for knocking compared to n-butanol in HCCI combustion due to its higher octane number. It was determined that n-butanol was more advantageous according to isopropanol as thermal efficiency. As a result it was found that the HCCI

  6. Fuel Combustion Laboratory | Transportation Research | NREL

    Science.gov (United States)

    Fuel Combustion Laboratory Fuel Combustion Laboratory NREL's Fuel Combustion Laboratory focuses on designs, using both today's technology and future advanced combustion concepts. This lab supports the combustion chamber platform for fuel ignition kinetics research, was acquired to expand the lab's

  7. Combustion of jojoba methyl ester in an indirect injection diesel engine

    Energy Technology Data Exchange (ETDEWEB)

    Selim, M.Y.E. [United Arab Emirates University, Al-Ain (United Arab Emirates). Mechanical Engineering Dept.; Radwan, M.S.; Elfeky, S.M.S. [Helwan University, Cairo (Egypt). Mechanical Power Engineering Dept.

    2003-07-01

    An experimental investigation has been carried out to examine for the first time the performance and combustion noise of an indirect injection diesel engine running with new fuel derived from pure jojoba oil, jojoba methyl ester, and its blends with gas oil. A Ricardo E6 compression swirl diesel engine was fully instrumented for the measurement of combustion pressure and its rise rate and other operating parameters. Test parameters included the percentage of jojoba methyl ester in the blend, engine speed, load, injection timing and engine compression ratio. Results showed that the new fuel derived from jojoba is generally comparable and a good replacement to gas oil in diesel engine at most engine operating conditions, in terms of performance parameters and combustion noise produced. (author)

  8. Sandia Combustion Research: Technical review

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-07-01

    This report contains reports from research programs conducted at the Sandia Combustion Research Facility. Research is presented under the following topics: laser based diagnostics; combustion chemistry; reacting flow; combustion in engines and commercial burners; coal combustion; and industrial processing. Individual projects were processed separately for entry onto the DOE databases.

  9. Metallic aluminum in combustion; Metalliskt aluminium i foerbraenningen

    Energy Technology Data Exchange (ETDEWEB)

    Backman, Rainer; Berg, Magnus; Bostroem, Dan; Hirota, Catherine; Oehman, Marcus; Oehrstroem, Anna

    2007-06-15

    Although aluminum is easily oxidized and melts at temperatures lower than those common in combustion, it can pass through the combustion chamber almost unscathed. If one performs calculations of thermodynamic equilibriums, conditions under which this could happen are extreme in comparison to those generally found in a furnace. Metallic aluminum may yet be found in rather large concentrations in fly ashes. There are also indications that metallic aluminum is present in deposits inside the furnaces. The objectives for the present investigation are better understanding of the behavior of the metallic aluminum in the fuel when it passes through an incinerator and to suggest counter/measures that deal with the problems associated with it. The target group is primary incineration plants using fuel that contains aluminum foil, for example municipal waste, industrial refuse or plastic reject from cardboard recycling. Combustion experiments were performed in a bench scale reactor using plastic reject obtained from the Fiskeby Board mill. First the gas velocity at which a fraction of the reject hovers was determined for the different fuel fractions, yielding a measure for their propensity to be carried over by the combustion gases. Second fractions rich in aluminum foils were combusted with time, temperature and gas composition as parameters. The partially combusted samples were analyzed using SEM/EDS. The degree of oxidation was determined using TGA/DTA. Reference material from full scale incinerators was obtained by collecting fly ash samples from five plants and analyzing them using XRD and SEM/EDS. The results show that thin aluminum foils may easily be carried over from the furnace. Furthermore, it was very difficult to fully oxidize the metallic flakes. The oxide layer on the surface prevents further diffusion of oxygen to the molten core of the flake. The contribution of these flakes to the build of deposits in a furnace is confirmed by earlier investigations in pilot

  10. Thermal analysis and kinetics of coal during oxy-fuel combustion

    Science.gov (United States)

    Kosowska-Golachowska, Monika

    2017-08-01

    The pyrolysis and oxy-fuel combustion characteristics of Polish bituminous coal were studied using non-isothermal thermogravimetric analysis. Pyrolysis tests showed that the mass loss profiles were almost similar up to 870°C in both N2 and CO2 atmospheres, while further mass loss occurred in CO2 atmosphere at higher temperatures due to char-CO2 gasification. Replacement of N2 in the combustion environment by CO2 delayed the combustion of bituminous coal. At elevated oxygen levels, TG/DTG profiles shifted through lower temperature zone, ignition and burnout temperatures decreased and mass loss rate significantly increased and complete combustion was achieved at lower temperatures and shorter times. Kinetic analysis for the tested coal was performed using Kissinger-Akahira-Sunose (KAS) method. The activation energies of bituminous coal combustion at the similar oxygen content in oxy-fuel with that of air were higher than that in air atmosphere. The results indicated that, with O2 concentration increasing, the activation energies decreased.

  11. Effect of fuel injection pressure and injection timing of Karanja biodiesel blends on fuel spray, engine performance, emissions and combustion characteristics

    International Nuclear Information System (INIS)

    Agarwal, Avinash Kumar; Dhar, Atul; Gupta, Jai Gopal; Kim, Woong Il; Choi, Kibong; Lee, Chang Sik; Park, Sungwook

    2015-01-01

    Highlights: • Effect of FIP on microscopic spray characteristics. • Effect of FIP and SOI timing on CRDI engine performance, emissions and combustion. • Fuel injection duration shortened, peak injection rate increased with increasing FIP. • SMD (D 32 ) and AMD (D 10 ) of fuel droplets decreased for lower biodiesel blends. • Increase in biodiesel blend ratio and FIP, fuel injection duration decreased. - Abstract: In this investigation, effect of 10%, 20% and 50% Karanja biodiesel blends on injection rate, atomization, engine performance, emissions and combustion characteristics of common rail direct injection (CRDI) type fuel injection system were evaluated in a single cylinder research engine at 300, 500, 750 and 1000 bar fuel injection pressures at different start of injection timings and constant engine speed of 1500 rpm. The duration of fuel injection slightly decreased with increasing blend ratio of biodiesel (Karanja Oil Methyl Ester: KOME) and significantly decreased with increasing fuel injection pressure. The injection rate profile and Sauter mean diameter (D 32 ) of the fuel droplets are influenced by the injection pressure. Increasing fuel injection pressure generally improves the thermal efficiency of the test fuels. Sauter mean diameter (D 32 ) and arithmetic mean diameter (D 10 ) decreased with decreasing Karanja biodiesel content in the blend and significantly increased for higher blends due to relatively higher fuel density and viscosity. Maximum thermal efficiency was observed at the same injection timing for biodiesel blends and mineral diesel. Lower Karanja biodiesel blends (up to 20%) showed lower brake specific hydrocarbon (BSHC) and carbon monoxide (BSCO) emissions in comparison to mineral diesel. For lower Karanja biodiesel blends, combustion duration was shorter than mineral diesel however at higher fuel injection pressures, combustion duration of 50% blend was longer than mineral diesel. Up to 10% Karanja biodiesel blends in a CRDI

  12. Control of the low-load region in partially premixed combustion

    Science.gov (United States)

    Ingesson, Gabriel; Yin, Lianhao; Johansson, Rolf; Tunestal, Per

    2016-09-01

    Partially premixed combustion (PPC) is a low temperature, direct-injection combustion concept that has shown to give promising emission levels and efficiencies over a wide operating range. In this concept, high EGR ratios, high octane-number fuels and early injection timings are used to slow down the auto-ignition reactions and to enhance the fuel and are mixing before the start of combustion. A drawback with this concept is the combustion stability in the low-load region where a high octane-number fuel might cause misfire and low combustion efficiency. This paper investigates the problem of low-load PPC controller design for increased engine efficiency. First, low-load PPC data, obtained from a multi-cylinder heavy- duty engine is presented. The data shows that combustion efficiency could be increased by using a pilot injection and that there is a non-linearity in the relation between injection and combustion timing. Furthermore, intake conditions should be set in order to avoid operating points with unfavourable global equivalence ratio and in-cylinder temperature combinations. Model predictive control simulations were used together with a calibrated engine model to find a gas-system controller that fulfilled this task. The findings are then summarized in a suggested engine controller design. Finally, an experimental performance evaluation of the suggested controller is presented.

  13. Natural Ores as Oxygen Carriers in Chemical Looping Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Tian, Hanjing; Siriwardane, Ranjani; Simonyi, Thomas; Poston, James

    2013-08-01

    Chemical looping combustion (CLC) is a combustion technology that utilizes oxygen from oxygen carriers (OC), such as metal oxides, instead of air to combust fuels. The use of natural minerals as oxygen carriers has advantages, such as lower cost and availability. Eight materials, based on copper or iron oxides, were selected for screening tests of CLC processes using coal and methane as fuels. Thermogravimetric experiments and bench-scale fixed-bed reactor tests were conducted to investigate the oxygen transfer capacity, reaction kinetics, and stability during cyclic reduction/oxidation reaction. Most natural minerals showed lower combustion capacity than pure CuO/Fe{sub 2}O{sub 3} due to low-concentrations of active oxide species in minerals. In coal CLC, chryscolla (Cu-based), magnetite, and limonite (Fe-based) demonstrated better reaction performances than other materials. The addition of steam improved the coal CLC performance when using natural ores because of the steam gasification of coal and the subsequent reaction of gaseous fuels with active oxide species in the natural ores. In methane CLC, chryscolla, hematite, and limonite demonstrated excellent reactivity and stability in 50-cycle thermogravimetric analysis tests. Fe{sub 2}O{sub 3}-based ores possess greater oxygen utilization but require an activation period before achieving full performance in methane CLC. Particle agglomeration issues associated with the application of natural ores in CLC processes were also studied by scanning electron microscopy (SEM).

  14. 40 CFR Table 1 to Subpart Kkkk of... - Nitrogen Oxide Emission Limits for New Stationary Combustion Turbines

    Science.gov (United States)

    2010-07-01

    ... Stationary Combustion Turbines 1 Table 1 to Subpart KKKK of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Stationary Combustion Turbines Pt. 60, Subpt. KKKK, Table 1 Table 1 to Subpart KKKK of Part 60—Nitrogen Oxide Emission Limits for New Stationary Combustion Turbines Combustion...

  15. Model predictive control as a tool for improving the process operation of MSW combustion plants

    International Nuclear Information System (INIS)

    Leskens, M.; Kessel, L.B.M. van; Bosgra, O.H.

    2005-01-01

    In this paper a feasibility study is presented on the application of the advanced control strategy called model predictive control (MPC) as a tool for obtaining improved process operation performance for municipal solid waste (MSW) combustion plants. The paper starts with a discussion of the operational objectives and control of such plants, from which a motivation follows for applying MPC to them. This is followed by a discussion on the basic idea behind this advanced control strategy. After that, an MPC-based combustion control system is proposed aimed at tackling a typical MSW combustion control problem and, using this proposed control system, an assessment is made of the improvement in performance that an MPC-based MSW combustion control system can provide in comparison to conventional MSW combustion control systems. This assessment is based on simulations using an experimentally obtained process and disturbance model of a real-life large-scale MSW combustion plant

  16. Effect of hydrogen addition on combustion and emissions performance of a gasoline rotary engine at part load and stoichiometric conditions

    International Nuclear Information System (INIS)

    Ji, Changwei; Su, Teng; Wang, Shuofeng; Zhang, Bo; Yu, Menghui; Cong, Xiaoyu

    2016-01-01

    Highlights: • The performance of a H_2-blended gasoline rotary engine was studied. • The p, Bmep, T_m_a_x and η_b increased after H_2 blending. • Both the CA0-10 and CA10-90 were shortened by the H_2 addition. • H_2 addition resulted in the reduced HC, CO and CO_2 emissions. - Abstract: The rotary engines may encounter high fuel consumption and emissions due to its narrow and long combustion chamber design. The low ignition energy and high flame speed of hydrogen may help improve the combustion of rotary engines. In this paper, a gasoline rotary engine equipped with gasoline and hydrogen injectors was developed to investigate the combustion and emissions of hydrogen-blended gasoline rotary engines. The engine was run at 3000 rpm and a manifolds absolute pressure of 37.5 kPa with the stoichiometric excess air ratio. The spark timing was set to be 25°CA before the top dead center. The engine was first fueled with the pure gasoline and then blended with the hydrogen. The hydrogen volume fractions in the intake were gradually increased from 0% to 5.2%. The results showed that the combustion pressure, brake mean effective pressure, cylinder temperature and thermal efficiency were simultaneously increased after the hydrogen blending. The crank angle of peak pressure was advanced with the hydrogen addition. The hydrogen enrichment was effective on reducing flame development and propagation periods. HC emissions were reduced by 44.8% when the hydrogen volume fraction in the intake was raised from 0% to 5.2%, CO and CO_2 emissions were also reduced after the hydrogen blending.

  17. Fabrication of a Combustion-Reacted High-Performance ZnO Electron Transport Layer with Silver Nanowire Electrodes for Organic Solar Cells.

    Science.gov (United States)

    Park, Minkyu; Lee, Sang-Hoon; Kim, Donghyuk; Kang, Juhoon; Lee, Jung-Yong; Han, Seung Min

    2018-02-28

    Herein, a new methodology for solution-processed ZnO fabrication on Ag nanowire network electrode via combustion reaction is reported, where the amount of heat emitted during combustion was minimized by controlling the reaction temperature to avoid damaging the underlying Ag nanowires. The degree of participation of acetylacetones, which are volatile fuels in the combustion reaction, was found to vary with the reaction temperature, as revealed by thermogravimetric and compositional analyses. An optimized processing temperature of 180 °C was chosen to successfully fabricate a combustion-reacted ZnO and Ag nanowire hybrid electrode with a sheet resistance of 30 Ω/sq and transmittance of 87%. A combustion-reacted ZnO on Ag nanowire hybrid structure was demonstrated as an efficient transparent electrode and electron transport layer for the PTB7-Th-based polymer solar cells. The superior electrical conductivity of combustion-reacted ZnO, compared to that of conventional sol-gel ZnO, increased the external quantum efficiency over the entire absorption range, whereas a unique light scattering effect due to the presence of nanopores in the combustion-derived ZnO further enhanced the external quantum efficiency in the 450-550 nm wavelength range. A power conversion efficiency of 8.48% was demonstrated for the PTB7-Th-based polymer solar cell with the use of a combustion-reacted ZnO/Ag NW hybrid transparent electrode.

  18. Technical and environmental performance of 10 kW understocker boiler during combustion of biomass and conventional fuels

    OpenAIRE

    Junga Robert; Wzorek Małgorzata; Kaszubska Mirosława

    2017-01-01

    This paper treats about the impact fuels from biomass wastes and coal combustion on a small boiler operation and the emission of pollutants in this process. Tests were performed in laboratory conditions on a water boiler with retort furnace and the capacity of 10 kW. Fuels from sewage sludge and agriculture wastes (PBZ fuel) and a blend of coal with laying hens mature (CLHM) were taken into account. The results in emission changes of NOx, CO2, CO and SO2 and operating parameters of the tested...

  19. Heat Transfer to a Thin Solid Combustible in Flame Spreading at Microgravity

    Science.gov (United States)

    Bhattacharjee, S.; Altenkirch, R. A.; Olson, S. L.; Sotos, R. G.

    1991-01-01

    The heat transfer rate to a thin solid combustible from an attached diffusion flame, spreading across the surface of the combustible in a quiescent, microgravity environment, was determined from measurements made in the drop tower facility at NASA-Lewis Research Center. With first-order Arrhenius pyrolysis kinetics, the solid-phase mass and energy equations along with the measured spread rate and surface temperature profiles were used to calculate the net heat flux to the surface. Results of the measurements are compared to the numerical solution of the complete set of coupled differential equations that describes the temperature, species, and velocity fields in the gas and solid phases. The theory and experiment agree on the major qualitative features of the heat transfer. Some fundamental differences are attributed to the neglect of radiation in the theoretical model.

  20. Regenerative heat exchanger for cowper combustion air preheating

    Energy Technology Data Exchange (ETDEWEB)

    Molenaar, R.; Otterbach, G.

    1986-01-13

    The waste gas leaving cowper units at a temperature of 200/sup 0/C to 300/sup 0/C was previously discharged unused into the atmosphere. By providing a suitable heat exchanger, the heat content of the waste gas can be used to preheat the combustion agents of cowpers to an extent allowing both to increase the efficiency of cowpers and to decrease the amount of rich gas required. The operating results confirm to a large extent the theoretical assumptions and calculations. One may therefore expect the entire investment to have been fully redeemed in a little more than two years. (orig.).

  1. The Evaluation of Solid Wastes Reduction with Combustion System in the Combustion Chamber

    International Nuclear Information System (INIS)

    Prayitno; Sukosrono

    2007-01-01

    The evaluation of solid wastes reduction with combustion system is used for weight reduction factor. The evaluation was done design system of combustion chamber furnace and the experiment was done by burning a certain weight of paper, cloth, plastic and rubber in the combustion chamber. The evaluation of paper wastes, the ratio of wastes (paper, cloth, plastic and rubber) against the factor of weight reduction (%) were investigated. The condition was dimension of combustion chamber furnace = 0.6 X 0.9 X 1.20 X 1 m with combustion chamber and gas chamber and reached at the wastes = 2.500 gram, oxygen pressure 0.5 Bar, wastes ratio : paper : cloth : plastic : rubber = 55 : 10 : 30 : 5, the reduction factor = 6.36 %. (author)

  2. Computational combustion and emission analysis of hydrogen-diesel blends with experimental verification

    International Nuclear Information System (INIS)

    Masood, M.; Ishrat, M.M.; Reddy, A.S.

    2007-01-01

    The paper discusses the effect of blending hydrogen with diesel in different proportions on combustion and emissions. A comparative study was carried out to analyze the effect of direct injection of hydrogen into the combustion chamber with that of induction through the inlet manifold for dual fueling. Percentage of hydrogen substitution varied from 20% to 80%, simultaneously reducing the diesel percentages. CFD analysis of dual fuel combustion and emissions were carried out for both the said methods using the CFD software FLUENT, meshing the combustion chamber was carried out using GAMBIT. The standard combustion and emission models were used in the analysis. In the second part of the paper, the effect of angle of injection in both the methods of hydrogen admission, on performance, combustion and emissions were analyzed. The experimental results were compared with that of simulated values and a good agreement between them was noticed. (author)

  3. Stochastic modelling of turbulent combustion for design optimization of gas turbine combustors

    Science.gov (United States)

    Mehanna Ismail, Mohammed Ali

    The present work covers the development and the implementation of an efficient algorithm for the design optimization of gas turbine combustors. The purpose is to explore the possibilities and indicate constructive suggestions for optimization techniques as alternative methods for designing gas turbine combustors. The algorithm is general to the extent that no constraints are imposed on the combustion phenomena or on the combustor configuration. The optimization problem is broken down into two elementary problems: the first is the optimum search algorithm, and the second is the turbulent combustion model used to determine the combustor performance parameters. These performance parameters constitute the objective and physical constraints in the optimization problem formulation. The examination of both turbulent combustion phenomena and the gas turbine design process suggests that the turbulent combustion model represents a crucial part of the optimization algorithm. The basic requirements needed for a turbulent combustion model to be successfully used in a practical optimization algorithm are discussed. In principle, the combustion model should comply with the conflicting requirements of high fidelity, robustness and computational efficiency. To that end, the problem of turbulent combustion is discussed and the current state of the art of turbulent combustion modelling is reviewed. According to this review, turbulent combustion models based on the composition PDF transport equation are found to be good candidates for application in the present context. However, these models are computationally expensive. To overcome this difficulty, two different models based on the composition PDF transport equation were developed: an improved Lagrangian Monte Carlo composition PDF algorithm and the generalized stochastic reactor model. Improvements in the Lagrangian Monte Carlo composition PDF model performance and its computational efficiency were achieved through the

  4. Combustion control and sensors: a review

    International Nuclear Information System (INIS)

    Docquier, N.; Candel, S.

    2002-01-01

    There is an increased interest in the application of control to combustion. The objective is to optimize combustor operation, monitor the process and alleviate instabilities and their severe consequences. One wishes to improve the system performance, for example by reducing the levels of pollutant emissions or by smoothing the pattern factor at the combustor exhaust. In other cases, the aim is to extend the stability domain by reducing the level of oscillation induced by coupling between resonance modes and combustion. As combustion systems have to meet increasingly more demanding air pollution standards, their design and operation becomes more complex. The trend towards reduced NO x levels has led to new developments in different fields. Automotive engines and gas turbine combustors are considered in this article. In the first case, complex exhaust aftertreatment is being applied and dedicated engine control systems are required to ensure and maintain high pollutant conversion efficiency. For gas turbines, premixed combustors, which operate at lower local temperatures than conventional systems have been designed. In both cases, monitoring and control of the operating point of the process have to be achieved with great precision to obtain the full benefits of the NO x reduction scheme. For premixed combustors operating near the lean stability limit, the flame is more susceptible to blowout, oscillation or flashback. Research is now carried out to reduce these dynamical problems with passive and active control methods. In addition to a broad range of fundamental problems raised by Active Combustion Control (ACC) and Operating Point Control (OPC), there are important technological issues. This paper contains a review of some facets of combustion control and focuses on the sensors that take or could take part to combustion control solutions. The current status of ACC and OPC is presented together with the associated control concepts. The state of the art in sensors is

  5. Biofuels combustion.

    Science.gov (United States)

    Westbrook, Charles K

    2013-01-01

    This review describes major features of current research in renewable fuels derived from plants and from fatty acids. Recent and ongoing fundamental studies of biofuel molecular structure, oxidation reactions, and biofuel chemical properties are reviewed, in addition to combustion applications of biofuels in the major types of engines in which biofuels are used. Biofuels and their combustion are compared with combustion features of conventional petroleum-based fuels. Two main classes of biofuels are described, those consisting of small, primarily alcohol, fuels (particularly ethanol, n-butanol, and iso-pentanol) that are used primarily to replace or supplement gasoline and those derived from fatty acids and used primarily to replace or supplement conventional diesel fuels. Research efforts on so-called second- and third-generation biofuels are discussed briefly.

  6. Low emission internal combustion engine

    Science.gov (United States)

    Karaba, Albert M.

    1979-01-01

    A low emission, internal combustion compression ignition engine having a cylinder, a piston movable in the cylinder and a pre-combustion chamber communicating with the cylinder near the top thereof and in which low emissions of NO.sub.x are achieved by constructing the pre-combustion chamber to have a volume of between 70% and 85% of the combined pre-chamber and main combustion chamber volume when the piston is at top dead center and by variably controlling the initiation of fuel injection into the pre-combustion chamber.

  7. Alcohol combustion chemistry

    KAUST Repository

    Sarathy, Mani; Oß wald, Patrick; Hansen, Nils; Kohse-Hö inghaus, Katharina

    2014-01-01

    . While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides

  8. Experimental and theoretical evaluation of the performance of a tar solar water heater

    International Nuclear Information System (INIS)

    Ammari, H.D.; Nimir, Y.L.

    2003-01-01

    The paper presents an experimental and theoretical evaluation of the performance of a tar solar water heater and comparison with that of a conventional type collector. The performance of both collectors is assessed under the same conditions. Both of the collectors have the same surface area and are glazed. The conventional type has the water tubes welded to the absorber plate, whereas in the tar type, the tar acts as an absorber plate that covers the water tubes. The theoretical model for each collector type, with the transient effects taken into account, is based on a control volume and a time base in the related energy equations. By considering a small element of the collector in each case, three partial differential equations were developed for each collector and were solved numerically by the Runge-Kutta method of the fifth order. A good agreement was achieved between the numerical and experimental results for both the conventional and tar collectors, indicating the feasibility of employing the theoretical model in the design of flat plate solar collectors. The results also showed that the conventional collector is more efficient than the tar type during most of the daylight, but the tar collector had the added advantage of better conservation of energy in late afternoon and evening

  9. In-cylinder Combustion and Soot Evolution in the Transition from Conventional CI mode to PPC

    KAUST Repository

    An, Yanzhao

    2018-01-09

    The present study intends to explore the in-cylinder combustion and evolution of soot emission during the transition from conventional compression ignition (CI) combustion to partially premixed combustion (PPC) at low load conditions. In-cylinder combustion images and engine-out emissions were measured in an optical engine fueled with low octane heavy naphtha fuel (RON = 50). Full cycle engine simulations were performed using a three-dimensional computational fluid dynamics code CONVERGETM, coupled with gas phase chemical kinetics, turbulence, and particulate size mimic soot model. The simulations were performed under low load conditions (IMEP ~ 2 to 3 bar) at an engine speed of 1200 rpm. The start of injection (SOI) was advanced from late (-10 CAD aTDC) to early fuel injection timings (-40 CAD aTDC) to realize the combustion transition from CI combustion to PPC. The simulation results of combustion and emission are compared with the experimental results at both CI and PPC combustion modes. The results of the study show a typical low-temperature stratified lean combustion at PPC mode, while high-temperature spray-driven combustion is evident at CI mode. The in-cylinder small intermediates species such as acetylene (C2H2), propargyl (C3H3), cyclopentadienyl (C5H5) and polycyclic aromatic hydrocarbons (PAHs) were significantly suppressed at PPC mode. Nucleation reaction of PAHs collision contributed to main soot mass production. The distribution of soot mass and particle number density was consistent with the distribution of high-temperature zones at CI and PPC combustion modes.

  10. 40 CFR 60.1200 - What are the operating practice requirements for my municipal waste combustion unit?

    Science.gov (United States)

    2010-07-01

    ... requirements for my municipal waste combustion unit? 60.1200 Section 60.1200 Protection of Environment... SOURCES Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is... Good Combustion Practices: Operating Requirements § 60.1200 What are the operating practice...

  11. Diesel oil combustion in fluidized bed; Combustion de aceite diesel en lecho fluidizado

    Energy Technology Data Exchange (ETDEWEB)

    Rodriguez Cazares, Mario [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1992-07-01

    The effect of the fluidized bed depth in the combustion in burning diesel oil in a fluidized bed, was analyzed. A self sustained combustion was achieved injecting the oil with an injector that utilized a principle similar to an automobile carburetor venturi. Three different depths were studied and it was found that the deeper the bed, the greater the combustion efficiency. Combustion efficiencies were attained from 82% for a 100mm bed depth, up to 96% for a 200mm bed depth. The diminution in the efficiency was mainly attributed to unburned hydrocarbons and to the carbon carried over, which was observed in the black smoke at the stack outlet. Other phenomena registered were the temperature gradient between the lower part of the bed and the upper part, caused by the fluidization velocity; additionally it was observed that the air employed for the oil injection (carbureting air) is the most important parameter to attain a complete combustion. [Espanol] Se analizo el efecto de la profundidad del lecho en la combustion al quemar aceite diesel en un lecho fluidizado experimental. Se logro combustion autosostenida inyectando el aceite con un inyector que utilizo un principio similar al venturi del carburador de automovil. Se estudiaron tres diferentes profundidades del lecho y se encontro que a mayor profundidad del lecho, mayor eficiencia de la combustion. Se lograron eficiencias de la combustion desde 82% para el lecho de 100 mm de profundidad hasta 96% para el de 200 mm. La disminucion de la eficiencia se atribuyo, principalmente, a los hidrocarburos no quemados y al carbon arrastrado, lo cual se observo en el humo negro a la salida de la chimenea. Otros fenomenos registrados fueron el gradiente de temperatura entre la parte baja del lecho y la parte superior causado por la velocidad de fluidizacion; ademas, se observo que el aire utilizado para inyectar el aceite (aire de carburacion) es el parametro mas importante para lograr una combustion completa.

  12. Investigation on the co-combustion of low calorific oil shale and its semi-coke by using thermogravimetric analysis

    International Nuclear Information System (INIS)

    Yang, Yu; Lu, Xiaofeng; Wang, Quanhai

    2017-01-01

    Highlights: • The co-combustion characteristic parameters were studied. • The co-combustion of oil shale and semi-coke could be expressed roughly by the addition of individual components. • Activation energy was calculated by Coats-Redfern, distributed activation energy model and Flynn-Wall-Ozawa methods. - Abstract: In the present work, thermogravimetric analysis was employed to investigate co-combustion behaviors of Fushun low calorific oil shale and its semi-coke. The synergy effect was estimated by using the interaction coefficient and the relative error of mean square root. In addition, activation energy was also calculated by means of Coats-Redfern, distributed activation energy model and Flynn-Wall-Ozawa methods. Results indicated that with the increase of oil shale mass fraction and oxygen concentration, combustion characteristics of the samples were improved. And some little interaction did occur during the co-combustion process, but it was relatively slight. Consequently, the co-combustion of oil shale and semi-coke still could be expressed roughly by the addition of individual components of the mixtures. Furthermore, activation energy of the samples decreased slowly at the initial stage attributed to the minerals’ catalytic effects, and in the final stage, it jumped to a high value, suggesting that the burnout of the samples was difficult. Besides, the mix proportion of oil shale which was added to stabilize the combustion in the circulating fluidized bed was also theoretically calculated.

  13. Theoretical Studies of Elementary Hydrocarbon Species and Their Reactions

    Energy Technology Data Exchange (ETDEWEB)

    Allen, Wesley D. [University of Georgia, Department of Chemistry and Center for Computational Quantum Chemistry; Schaefer, Henry F. [University of Georgia, Center for Computational Quantum Chemistry

    2018-04-08

    The research program supported by this DOE grant carried out both methodological development and computational applications of first-principles theoretical chemistry based on quantum mechanical wavefunctions, as directed toward understanding and harnessing the fundamental chemical physics of combustion. To build and refine the world’s database of thermochemistry, spectroscopy, and chemical kinetics, predictive and definitive computational methods are needed that push the envelope of modern electronic structure theory. The application of such methods has been made to gain comprehensive knowledge of the paradigmatic reaction networks by which the n- and i-propyl, t-butyl, and n-butyl radicals are oxidized by O2. Numerous ROO and QOOH intermediates in these R + O2 reaction systems have been characterized along with the interconnecting isomerization transition states and the barriers leading to fragmentation. Other combustion-related intermediates have also been studied, including methylsulfinyl radical, cyclobutylidene, and radicals derived from acetaldehyde and vinyl alcohol. Theoretical advances have been achieved and made available to the scientific community by implementation into PSI4, an open-source electronic structure computer package emphasizing automation, advanced libraries, and interoperability. We have pursued the development of universal explicitly correlated methods applicable to general electronic wavefunctions, as well as a framework that allows multideterminant reference functions to be expressed as a single determinant from quasiparticle operators. Finally, a rigorous analytical tool for correlated wavefunctions has been created to elucidate dispersion interactions, which play essential roles in many areas of chemistry, but whose effects are often masked and enigmatic. Our research decomposes and analyzes the coupled-cluster electron correlation energy in molecular systems as a function of interelectronic distance. Concepts

  14. Polarization (ellipsometric) measurements of liquid condensate deposition and evaporation rates and dew points in flowing salt/ash-containing combustion gases

    Science.gov (United States)

    Seshadri, K.; Rosner, D. E.

    1985-01-01

    An application of an optical polarization technique in a combustion environment is demonstrated by following, in real-time, growth rates of boric oxide condensate on heated platinum ribbons exposed to seeded propane-air combustion gases. The results obtained agree with the results of earlier interference measurements and also with theoretical chemical vapor deposition predictions. In comparison with the interference method, the polarization technique places less stringent requirements on surface quality, which may justify the added optical components needed for such measurements.

  15. Shale oil combustion

    International Nuclear Information System (INIS)

    Al-dabbas, M.A.

    1992-05-01

    A 'coutant' carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs

  16. Shale oil combustion

    Energy Technology Data Exchange (ETDEWEB)

    Al-dabbas, M A

    1992-05-01

    A `coutant` carbon steel combustion chamber cooled by water jacket was conslructed to burn diesel fuel and mixlure of shale oil and diesel fuels. During experimental work nir fuel ratio was determined, temperaturces were measured using Chromel/ Almel thermocouple, finally the gasous combustion product analysis was carricd out using gas chromatograph technique. The constructed combustion chamber was operating salisfactory for several hours of continous work. According to the measurements it was found that: the flame temperature of a mixture of diesel and shale oil fuels was greater than the flame temperature of diesel fuel. and the sulfer emissious of a mixture of diesel and shale oil fuels was higher than that of diesel fuel. Calculation indicated that the dry gas energy loss was very high and the incomplete combustion energy loss very small. (author). 23 refs., 35 figs.

  17. Energy efficiency impact of EGR on organizing clean combustion in diesel engines

    International Nuclear Information System (INIS)

    Divekar, Prasad S.; Chen, Xiang; Tjong, Jimi; Zheng, Ming

    2016-01-01

    Highlights: • Studied EGR impact on efficiency and emissions of diesel and dual-fuel combustion. • Quantified effectiveness of intake dilution for NOx reduction using EGR. • Identified suitable EGR ranges for mitigating emissions–efficiency trade-off. • Developed careful control of intake dilution and in-cylinder excess ratio. • Enabled ultra-low NOx in both diesel and dual-fuel combustion via EGR control. - Abstract: Exhaust gas recirculation (EGR) is a commonly recognized primary technique for reducing NOx emissions in IC engines. However, depending on the extent of its use, the application of EGR in diesel engines is associated with an increase in smoke emissions and a reduction in thermal efficiency. In this work, empirical investigations and parametric analyses are carried out to assess the impact of EGR in attaining ultra-low NOx emissions while minimizing the smoke and efficiency penalties. Two fuelling strategies are studied, namely diesel-only injection and dual-fuel injection. In the dual-fuel strategy, a high volatility liquid fuel is injected into the intake ports, and a diesel fuel is injected directly into the cylinder. The results suggest that the reduction in NOx can be directly correlated with the intake dilution caused by EGR and the correlation is largely independent of the fuelling strategy, the intake boost, and the engine load level. Simultaneously ultra-low NOx and smoke emissions can be achieved at high intake boost and intake dilution levels in the diesel-only combustion strategy and at high ethanol fractions in the dual-fuel strategy. The efficiency penalty associated with EGR is attributed to two primary factors; the combustion off-phasing and the reduction in combustion efficiency. The combustion off-phasing can be minimized by the closed loop control of the diesel injection timing in both the fuelling strategies, whereas the combustion efficiency can be improved by limiting the intake dilution to moderate levels. The

  18. Technology for Transient Simulation of Vibration during Combustion Process in Rocket Thruster

    Science.gov (United States)

    Zubanov, V. M.; Stepanov, D. V.; Shabliy, L. S.

    2018-01-01

    The article describes the technology for simulation of transient combustion processes in the rocket thruster for determination of vibration frequency occurs during combustion. The engine operates on gaseous propellant: oxygen and hydrogen. Combustion simulation was performed using the ANSYS CFX software. Three reaction mechanisms for the stationary mode were considered and described in detail. The way for obtaining quick CFD-results with intermediate combustion components using an EDM model was found. The way to generate the Flamelet library with CFX-RIF was described. A technique for modeling transient combustion processes in the rocket thruster was proposed based on the Flamelet library. A cyclic irregularity of the temperature field like vortex core precession was detected in the chamber. Frequency of flame precession was obtained with the proposed simulation technique.

  19. Analysis the ECFM-3Z Combustion Model for Simulating the Combustion Process and Emission Characteristics in a HSDI Diesel Engine

    Directory of Open Access Journals (Sweden)

    Raouf Mobasheri

    2015-12-01

    Full Text Available An advanced CFD simulation has been performed to analyze the ECFM-3Z (Extended Coherent Flame Model-3Z combustion model for simulating the combustion process and emission characteristics in a high speed direct injection (HSDI diesel engine. A four cylinders, HSDI diesel engine based on a Ford production engine with a 2nd generation Delphi common rail fuel injection system has been modeled in this research. 3D CFD simulation was carried out from intake valve closing (IVC to exhaust valve opening (EVO. A good agreement of calculated and measured in-cylinder pressure trace as well as pollutant formation trends could be observed for all investigated operating points. Based on the confidence gained from validation, the study is extended to evaluate the effect of fuel injection timing on engine performance and emissions. For this purpose, a comprehensive study of the effect of injection timing with respect to performance and emissions has been considered. Three main injection timing, (1 2.65 BTDC, (2 0.65 BTDC and (3 1.35 ATDC, all with 30 crank angle pilot separations has been used to investigate the effect of the injection timing. The results show that the current methodology can be applied as a beneficial tool for analyzing the parameters of the diesel combustion under HSDI operating condition.

  20. Thermogravimetric investigation on characteristic of biomass combustion under the effect of organic calcium compounds.

    Science.gov (United States)

    Zhang, Lihui; Duan, Feng; Huang, Yaji

    2015-01-01

    Experiments were conducted in a thermogravimetric analyzer to investigate thermal behavior of different organic calcium compounds (OCCs) and its blended fuels with three kinds of biomass. The effectiveness of synthesized method for OCC was assessed by the pyrolysis test. Effect of the mole ratio of calcium to sulfur on co-combustion characteristics was studied. Results indicated that preparation method of modified calcium acetate (MCA) had high precision and accuracy. Co-combustion characteristic of OCCs blended with biomass was controlled by OCCs' additive amount and the content of volatile matter which is mainly composed of small hydrocarbon molecules. Combustion performance indexes for peanut shell and wheat straw impregnated by OCCs were improved, however, an inverse trend was found for rice husk because of lower additive amount of OCCs. The blended fuel show higher combustion performance indexes compared with combustion of individual biomass, and these indexes decrease with increases of Ca/S ratio. Copyright © 2014 Elsevier Ltd. All rights reserved.

  1. Investigation of the combustion kinetics and polycyclic aromatic hydrocarbon emissions from polycaprolactone combustion.

    Science.gov (United States)

    Chien, Y C; Yang, S H

    2013-01-01

    Polycaprolactone (PCL) is one of the most attractive biodegradable plastics that has been widely used in medicine and agriculture fields. Because of the large increase in biodegradable plastics usage, the production of waste biodegradable plastics will be increasing dramatically, producing a growing environmental problem. Generally, waste PCL is collected along with municipal solid wastes and then incinerated. This study investigates the combustion kinetics and emission factors of 16 US Environmental Protection Agency (EPA) priority polycyclic aromatic hydrocarbons (PAHs) in the PCL combustion. Experimentally, two reactions are involved in the PCL combustion process, possibly resulting in the emission of carbon dioxide, propanal, protonated caprolactone and very small amounts of PAH produced by incomplete combustion. The intermediate products may continuously be oxidized to form CO2. The emission factors for 16 US EPA priority PAHs are n.d. -2.95 microg/g, which are much lower than those of poly lactic acid and other plastics combustion. The conversion of PCL is 100%. Results from this work suggest that combustion is a good choice for the waste PCL disposal.

  2. Modeling of Supersonic Combustion Systems for Sustained Hypersonic Flight

    Directory of Open Access Journals (Sweden)

    Stephen M. Neill

    2017-11-01

    Full Text Available Through Computational Fluid Dynamics and validation, an optimal scramjet combustor has been designed based on twin-strut Hydrogen injection to sustain flight at a desired speed of Mach 8. An investigation undertaken into the efficacy of supersonic combustion through various means of injection saw promising results for Hydrogen-based systems, whereby strut-style injectors were selected over transverse injectors based on their pressure recovery performance and combustive efficiency. The final configuration of twin-strut injectors provided robust combustion and a stable region of net thrust (1873 kN in the nozzle. Using fixed combustor inlet parameters and injection equivalence ratio, the finalized injection method advanced to the early stages of two-dimensional (2-D and three-dimensional (3-D scramjet engine integration. The overall investigation provided a feasible supersonic combustion system, such that Mach 8 sustained cruise could be achieved by the aircraft concept in a computational design domain.

  3. Analyzing a low NO[sub x] concentric combustion system

    Energy Technology Data Exchange (ETDEWEB)

    Kotler, V.R.; Eremeev, A.V.

    1992-05-01

    Discusses concentric combustion technology developed by Combustion Engineering, Inc. (USA) to reduce NO[sub x] emissions from pulverized coal-fired boilers. The major innovation consists in arranging existing independent secondary air burners into three pairs of concentric combustion burners. Using high-deflection angle concentric combustion burners, higher oxygen concentration near the boiler walls, reduced erosion and lower probability of slag deposition on the heat shield are achieved. The technology was tested at the 165 MW Valmont power plant and 350 MW Cherokee power plant. Reduction of 55.7% (to 0.294 kg/GJ) in NO[sub x] emissions with a boiler efficiency of 86.35% was achieved. Highest NO[sub x] reduction efficiency was observed at full load (highest tertiary air supply). Burner design, performance, relations of NO[sub x] emissions and tertiary air blast as well as fuel entrainment prior to and after upgrading are given. Methods of reducing slag deposition in boilers are considered. 2 refs.

  4. The Multi-User Droplet Combustion Apparatus: the Development and Integration Concept for Droplet Combustion Payloads in the Fluids and Combustion Facility Combustion Integrated Rack

    Science.gov (United States)

    Myhre, C. A.

    2002-01-01

    The Multi-user Droplet Combustion Apparatus (MDCA) is a multi-user facility designed to accommodate four different droplet combustion science experiments. The MDCA will conduct experiments using the Combustion Integrated Rack (CIR) of the NASA Glenn Research Center's Fluids and Combustion Facility (FCF). The payload is planned for the International Space Station. The MDCA, in conjunction with the CIR, will allow for cost effective extended access to the microgravity environment, not possible on previous space flights. It is currently in the Engineering Model build phase with a planned flight launch with CIR in 2004. This paper provides an overview of the capabilities and development status of the MDCA. The MDCA contains the hardware and software required to conduct unique droplet combustion experiments in space. It consists of a Chamber Insert Assembly, an Avionics Package, and a multiple array of diagnostics. Its modular approach permits on-orbit changes for accommodating different fuels, fuel flow rates, soot sampling mechanisms, and varying droplet support and translation mechanisms to accommodate multiple investigations. Unique diagnostic measurement capabilities for each investigation are also provided. Additional hardware provided by the CIR facility includes the structural support, a combustion chamber, utilities for the avionics and diagnostic packages, and the fuel mixing capability for PI specific combustion chamber environments. Common diagnostics provided by the CIR will also be utilized by the MDCA. Single combustible fuel droplets of varying sizes, freely deployed or supported by a tether are planned for study using the MDCA. Such research supports how liquid-fuel-droplets ignite, spread, and extinguish under quiescent microgravity conditions. This understanding will help us develop more efficient energy production and propulsion systems on Earth and in space, deal better with combustion generated pollution, and address fire hazards associated with

  5. Coherent anti-Stokes Raman spectroscopy temperature measurements in an internal combustion engine

    Science.gov (United States)

    Ball, Don; Driver, H. Steve T.; Hutcheon, Richard J.; Lockett, Russel J.; Robertson, Gerald N.

    1994-09-01

    Part of a project to investigate the physics and chemistry of alternative fuels in internal combustion engines is reported. Coherent anti-Stokes Raman spectroscopy (CARS) is used to probe the fuel-air mixture in the cylinder of a Richardo E6 variable compression ratio research engine. The laser system comprises a passively Q- switched single-longitudinal-mode frequency-doubled Nd:YAG laser and a broadband dye laser, both with a pulse length of 15 ns. A crankshaft encoder and electronic delay are used to fire the lasers at specified times during the engine cycle, and CARS spectra are acquired using a 0.75 m spectrometer and a 1024 optical multichannel analyzer. Because of the uncertainties associated with collisional narrowing in the theoretical modeling of high-pressure CARS spectra, temperatures are determined by comparing the engine spectra with a library of experimental CARS spectra from a calibrated high-pressure, high- temperature cell. This purely experimental technique is shown to be superior to two theoretical models under the considered conditions, giving temperatures during the compression stroke of the engine with standard deviations of typically 10 K and a possible systematic error of 15 K. Together with pressure records, this information is used as input data for chemical kinetic modeling of the combustion process.

  6. N2O formation in combustion systems

    International Nuclear Information System (INIS)

    1989-11-01

    The objective of this project is to characterize N 2 O emissions from combustion sources emphasizing N 2 O emissions from post-combustion selective gas phase NO x reduction processes and reburning. The processes to be evaluated include ammonia, urea and cyanuric acid injection and reburning. The project includes pilot-scale testing at two facilities supported by chemical kinetic modeling. Testing will be performed on both a gas-fired plug flow combustor and a pulverized-coal fired combustor. Work performed to date has included the performance of the initial detailed chemical kinetics calculations. These calculations showed that both urea and cyanuric acid produce significant quantities of N 2 O, while NH 3 injection produced negligible amounts. These kinetics data support limited test results reported for cyanuric acid and ammonia injection. Laboratory work to evaluate the selective gas phase NO x reduction processes listed above will begin in the gas-fired facility early in CY 1990. Testing to evaluate reburning at the coal-fired facility is currently planned to be performed in parallel with the testing at the gas-fired facility. Following completion of that work, additional kinetics calculations will be performed

  7. Combustion, cofiring and emissions characteristics of torrefied biomass in a drop tube reactor

    International Nuclear Information System (INIS)

    Ndibe, Collins; Maier, Jörg; Scheffknecht, Günter

    2015-01-01

    The study investigates cofiring characteristics of torrefied biomass fuels at 50% thermal shares with coals and 100% combustion cases. Experiments were carried out in a 20 kW, electrically heated, drop-tube reactor. Fuels used include a range of torrefied biomass fuels, non-thermally treated white wood pellets, a high volatile bituminous coal and a lignite coal. The reactor was maintained at 1200 °C while the overall stoichiometric ratio was kept constant at 1.15 for all combustion cases. Measurements were performed to evaluate combustion reactivity, emissions and burn-out. Torrefied biomass fuels in comparison to non-thermally treated wood contain a lower amount of volatiles. For the tests performed at a similar particle size distribution, the reduced volatile content did not impact combustion reactivity significantly. Delay in combustion was only observed for test fuel with a lower amount of fine particles. The particle size distribution of the pulverised grinds therefore impacts combustion reactivity more. Sulphur and nitrogen contents of woody biomass fuels are low. Blending woody biomass with coal lowers the emissions of SO 2 mainly as a result of dilution. NO X emissions have a more complex dependency on the nitrogen content. Factors such as volatile content of the fuels, fuel type, furnace and burner configurations also impact the final NO X emissions. In comparison to unstaged combustion, the nitrogen conversion to NO X declined from 34% to 9% for air-staged co-combustion of torrefied biomass and hard coal. For the air-staged mono-combustion cases, nitrogen conversion to NO X declined from between 42% and 48% to about 10%–14%. - Highlights: • Impact of torrefaction on cofiring was studied at high heating rates in a drop tube. • Cofiring of torrefied biomasses at high thermal shares (50% and higher) is feasible. • Particle size impacts biomass combustion reactivity more than torrefaction. • In a drop tube reactor, torrefaction has no negative

  8. Theoretical investigation of performance of armchair graphene nanoribbon field effect transistors

    Science.gov (United States)

    Hur, Ji-Hyun; Kim, Deok-Kee

    2018-05-01

    In this paper, we theoretically investigate the highest possible expected performance for graphene nanoribbon field effect transistors (GNRFETs) for a wide range of operation voltages and device structure parameters, such as the width of the graphene nanoribbon and gate length. We formulated a self-consistent, non-equilibrium Green’s function method in conjunction with the Poisson equation and modeled the operation of nanometer sized GNRFETs, of which GNR channels have finite bandgaps so that the GNRFET can operate as a switch. We propose a metric for competing with the current silicon CMOS high performance or low power devices and explain that this can vary greatly depending on the GNRFET structure parameters.

  9. Large-eddy simulation of ethanol spray combustion using a finite-rate combustion model

    Energy Technology Data Exchange (ETDEWEB)

    Li, K.; Zhou, L.X. [Tsinghua Univ., Beijing (China). Dept. of Engineering Mechanics; Chan, C.K. [Hong Kong Polytechnic Univ. (China). Dept. of Applied Mathematics

    2013-07-01

    Large-eddy simulation of spray combustion is under its rapid development, but the combustion models are less validated by detailed experimental data. In this paper, large-eddy simulation of ethanol-air spray combustion was made using an Eulerian-Lagrangian approach, a subgrid-scale kinetic energy stress model, and a finite-rate combustion model. The simulation results are validated in detail by experiments. The LES obtained statistically averaged temperature is in agreement with the experimental results in most regions. The instantaneous LES results show the coherent structures of the shear region near the high-temperature flame zone and the fuel vapor concentration map, indicating the droplets are concentrated in this shear region. The droplet sizes are found to be in the range of 20-100{mu}m. The instantaneous temperature map shows the close interaction between the coherent structures and the combustion reaction.

  10. Impacts of Combustion Conditions and Photochemical Processing on the Light Absorption of Biomass Combustion Aerosol.

    Science.gov (United States)

    Martinsson, J; Eriksson, A C; Nielsen, I Elbæk; Malmborg, V Berg; Ahlberg, E; Andersen, C; Lindgren, R; Nyström, R; Nordin, E Z; Brune, W H; Svenningsson, B; Swietlicki, E; Boman, C; Pagels, J H

    2015-12-15

    The aim was to identify relationships between combustion conditions, particle characteristics, and optical properties of fresh and photochemically processed emissions from biomass combustion. The combustion conditions included nominal and high burn rate operation and individual combustion phases from a conventional wood stove. Low temperature pyrolysis upon fuel addition resulted in "tar-ball" type particles dominated by organic aerosol with an absorption Ångström exponent (AAE) of 2.5-2.7 and estimated Brown Carbon contributions of 50-70% to absorption at the climate relevant aethalometer-wavelength (520 nm). High temperature combustion during the intermediate (flaming) phase was dominated by soot agglomerates with AAE 1.0-1.2 and 85-100% of absorption at 520 nm attributed to Black Carbon. Intense photochemical processing of high burn rate flaming combustion emissions in an oxidation flow reactor led to strong formation of Secondary Organic Aerosol, with no or weak absorption. PM1 mass emission factors (mg/kg) of fresh emissions were about an order of magnitude higher for low temperature pyrolysis compared to high temperature combustion. However, emission factors describing the absorption cross section emitted per kg of fuel consumed (m(2)/kg) were of similar magnitude at 520 nm for the diverse combustion conditions investigated in this study. These results provide a link between biomass combustion conditions, emitted particle types, and their optical properties in fresh and processed plumes which can be of value for source apportionment and balanced mitigation of biomass combustion emissions from a climate and health perspective.

  11. 40 CFR 60.1320 - How do I monitor the load of my municipal waste combustion unit?

    Science.gov (United States)

    2010-07-01

    ... municipal waste combustion unit? 60.1320 Section 60.1320 Protection of Environment ENVIRONMENTAL PROTECTION... of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced After... Monitoring Requirements § 60.1320 How do I monitor the load of my municipal waste combustion unit? (a) If...

  12. Investigation on the Effects of Internal EGR by Variable Exhaust Valve Actuation with Post Injection on Auto-ignited Combustion and Emission Performance

    Directory of Open Access Journals (Sweden)

    Insu Cho

    2018-04-01

    Full Text Available Variable valve mechanisms are usually applied to a gasoline combustion engine to improve its power performance by controlling the amount of intake air according to the operating load. These mechanisms offer one possibility of resolving the conflict of objectives between a further reduction of raw emissions and an improvement in fuel efficiency. In recent years, variable valve control systems have become extremely important in the diesel combustion engine. Importantly, it has been shown that there are several potential benefits of applying variable valve timing (VVT to a compression ignition engine. Valve train variability could offer one option to achieve the reduction goals of engine-out emissions and fuel consumption. The aim of this study was to investigate the effects on part load combustion and emission performance of internal exhaust gas recirculation (EGR by variable exhaust valve lift actuation using a cam-in-cam system, which is an electronically variable valve device with a variable inside cam retarded to about 30 degrees. Numerical simulation based on GT-POWER has been performed to predict the NOx reduction strategy at the part load operating point of 1200 rpm in a four-valve diesel engine. A GT-POWER model of a common-rail direct injection engine with internal EGR was built and verified with experimental data. As a result, large potential for reducing NOx emissions through the use of exhaust valve control has been identified. Namely, it is possible to utilize heat efficiently as recompression of retarded post injection with downscaled specification of the exhaust valve rather than the intake valve, even if the CIC V1 condition with a reduction of the exhaust valve has a higher internal EGR rate of about 2% compared to that of the CIC V2 condition.

  13. Optimization of combustion chamber geometry for stoichiometric diesel combustion using a micro genetic algorithm

    Energy Technology Data Exchange (ETDEWEB)

    Park, Sung Wook

    2010-11-15

    This paper describes the optimization of combustion chamber geometry and engine operating conditions for stoichiometric diesel combustion, targeting lower gross indicated specific fuel consumption. The KIVA code, coupled with a micro genetic algorithm population of nine for each generation was used. The optimization variables were composed of ten variables related to the combustion chamber geometry and engine operating conditions. In addition, an auto mesh generator was developed for generating various kinds of combustion chambers, such as open-crater, re-entrant, deep, and shallow types. In addition, the computational models were validated against the experimental results for a stoichiometric process in terms of the combustion pressure history and emissions. Through the preset optimization, a 35% improvement in the gross indicated that specific fuel consumption was achieved. In addition, the optimization results showed that the optimum engine operating conditions employed a premixed charge compression ignition combustion regime with early injection and a narrow spray included angle. Furthermore, a higher boost pressure was used to prevent fuel film formation. (author)

  14. On the influence of steam on combustion

    NARCIS (Netherlands)

    Derksen, M.A.F.

    2005-01-01

    In this thesis, a numerical simulation study is presented of the influence of steam on premixed and partially premixed combustion. Both laminar (premixed) and turbulent (partially premixed) calculations are presented. The laminar calculations were performed using a detailed chemical mechanism and

  15. Combustion behaviors and kinetics of sewage sludge blended with pulverized coal: With and without catalysts.

    Science.gov (United States)

    Wang, Zhiqiang; Hong, Chen; Xing, Yi; Li, Yifei; Feng, Lihui; Jia, Mengmeng

    2018-04-01

    The combustion behaviors of sewage sludge (SS), pulverized coal (PC), and their blends were studied using a thermogravimetric analyzer. The effect of the mass ratio of SS to PC on the co-combustion characteristics was analyzed. The experiments showed that the ignition performance of the blends improved significantly as the mass percentage of SS increased, but its combustion intensity decreased. The burnout temperature (T b ) and comprehensive combustibility index (S) of the blends were almost unchanged when the mass percentage of SS was less than 10%. However, a high mass percentage of SS (>10%) resulted in a great increase in T b and a notable decrease in S. Subsequently, the effects of different catalysts (CaO, CeO 2 , MnO 2 , and Fe 2 O 3 ) on the combustion characteristics and activation energy of the SS/PC blend were investigated. The four catalysts promoted the release and combustion of volatile matters in the blended fuels and shifted their combustion profiles to a low temperature. In addition, their peak separating tendencies were obvious at 350-550 C, resulting in high peak widths. All the catalysts improved combustion activity of the blended fuel and accelerated fixed carbon combustion, which decreased the ignition temperature and burnout temperature of the fuels. CeO 2 had the best catalytic effects in terms of the comprehensive combustion performance and activation energy, followed closely by Fe 2 O 3 . However, the rare-earth compounds are expensive to be applied in the catalytic combustion process of SS/PC blend at present. Based on both catalytic effects and economy, Fe 2 O 3 was potentially an optimal option for catalytic combustion among the tested catalysts. Copyright © 2018 Elsevier Ltd. All rights reserved.

  16. Pulsed atmospheric fluidized bed combustion. Final report

    Energy Technology Data Exchange (ETDEWEB)

    1989-11-01

    In order to verify the technical feasibility of the MTCI Pulsed Atmospheric Fluidized Bed Combustor technology, a laboratory-scale system was designed, built and tested. Important aspects of the operational and performance parameters of the system were established experimentally. A considerable amount of the effort was invested in the initial task of constructing an AFBC that would represent a reasonable baseline against which the performance of the PAFBC could be compared. A summary comparison of the performance and emissions data from the MTCI 2 ft {times} 2 ft facility (AFBC and PAFBC modes) with those from conventional BFBC (taller freeboard and recycle operation) and circulating fluidized bed combustion (CFBC) units is given in Table ES-1. The comparison is for typical high-volatile bituminous coals and sorbents of average reactivity. The values indicated for BFBC and CFBC were based on published information. The AFBC unit that was designed to act as a baseline for the comparison was indeed representative of the larger units even at the smaller scale for which it was designed. The PAFBC mode exhibited superior performance in relation to the AFBC mode. The higher combustion efficiency translates into reduced coal consumption and lower system operating cost; the improvement in sulfur capture implies less sorbent requirement and waste generation and in turn lower operating cost; lower NO{sub x} and CO emissions mean ease of site permitting; and greater steam-generation rate translates into less heat exchange surface area and reduced capital cost. Also, the PAFBC performance generally surpasses those of conventional BFBC, is comparable to CFBC in combustion and NO{sub x} emissions, and is better than CFBC in sulfur capture and CO emissions even at the scaled-down size used for the experimental feasibility tests.

  17. Exhaust Gas Temperature Measurements in Diagnostics of Turbocharged Marine Internal Combustion Engines Part I Standard Measurements

    Directory of Open Access Journals (Sweden)

    Korczewski Zbigniew

    2015-01-01

    Full Text Available The article discusses the problem of diagnostic informativeness of exhaust gas temperature measurements in turbocharged marine internal combustion engines. Theoretical principles of the process of exhaust gas flow in turbocharger inlet channels are analysed in its dynamic and energetic aspects. Diagnostic parameters are defined which enable to formulate general evaluation of technical condition of the engine based on standard online measurements of the exhaust gas temperature. A proposal is made to extend the parametric methods of diagnosing workspaces in turbocharged marine engines by analysing time-histories of enthalpy changes of the exhaust gas flowing to the turbocompressor turbine. Such a time-history can be worked out based on dynamic measurements of the exhaust gas temperature, performed using a specially designed sheathed thermocouple.

  18. Reaction Mechanisms on Multiwell Potential Energy Surfaces in Combustion (and Atmospheric) Chemistry

    International Nuclear Information System (INIS)

    Osborn, David L.

    2017-01-01

    Chemical reactions occurring on a potential energy surface with multiple wells are ubiquitous in low temperature combustion and the oxidation of volatile organic compounds in earth’s atmosphere. The rich variety of structural isomerizations that compete with collisional stabilization make characterizing such complex-forming reactions challenging. This review describes recent experimental and theoretical advances that deliver increasingly complete views of their reaction mechanisms. New methods for creating reactive intermediates coupled with multiplexed measurements provide many experimental observables simultaneously. Automated methods to explore potential energy surfaces can uncover hidden reactive pathways, while master equation methods enable a holistic treatment of both sequential and well-skipping pathways. Our ability to probe and understand nonequilibrium effects and reaction sequences is increasing. These advances provide the fundamental science base for predictive models of combustion and the atmosphere that are crucial to address global challenges.

  19. Reaction Mechanisms on Multiwell Potential Energy Surfaces in Combustion (and Atmospheric) Chemistry

    Science.gov (United States)

    Osborn, David L.

    2017-05-01

    Chemical reactions occurring on a potential energy surface with multiple wells are ubiquitous in low-temperature combustion and in the oxidation of volatile organic compounds in Earth's atmosphere. The rich variety of structural isomerizations that compete with collisional stabilization makes characterizing such complex-forming reactions challenging. This review describes recent experimental and theoretical advances that deliver increasingly complete views of their reaction mechanisms. New methods for creating reactive intermediates coupled with multiplexed measurements provide many experimental observables simultaneously. Automated methods to explore potential energy surfaces can uncover hidden reactive pathways, and master equation methods enable a holistic treatment of both sequential and well-skipping pathways. Our ability to probe and understand nonequilibrium effects and reaction sequences is increasing. These advances provide the fundamental science base for predictive models of combustion and the atmosphere that are crucial to address global challenges.

  20. Experiment and modeling of low-concentration methane catalytic combustion in a fluidized bed reactor

    International Nuclear Information System (INIS)

    Yang, Zhongqing; Yang, Peng; Zhang, Li; Guo, Mingnv; Ran, Jingyu

    2016-01-01

    Highlights: • The catalytic combustion of 0.15~3 vol. % low concentration methane in a fluidized bed was studied. • A mathematical model was proposed on the basis of gas–solid flow theory. • A comparative analysis of the established model with plug flow, mixed flow and K-L models was carried out. • The axial methane profile along fluidized bed was predicted by using the mathematical model. • The bed temperature has greater impact on methane conversion than fluidized velocity. - Abstract: This study undertakes a theoretical analysis and an experimental investigation into the characteristics of low-concentration methane catalytic combustion in a bubbling fluidized bed reactor using 0.5 wt.% Pd/Al_2O_3 as catalytic particles. A mathematical model is established based on gas–solid flow theory and is used to study the effects of bed temperature and fluidized velocity on methane catalytic combustion, and predict the dimensionless methane concentration axial profile in reactor. It is shown that methane conversion increases with bed temperature, but decreases with increasing fluidized velocity. These theoretical results are found to correlate well with the experimental measurement, with a deviation within 5%. A comparative analysis of the developed model with plug flow, mixed flow and K-L models is also carried out, and this further verifies that the established model better reflects the characteristics of low-concentration methane catalytic combustion in a bubbling fluidized bed. Using this reaction model, it was found that the difference in methane conversion between dense and freeboard zones gradually increases with bed temperature; the dense zone reaction levels off at 650 °C, thereby minimizing the difference between the dense and freeboard regions to around 15%. With an increase in bed temperature, the dimensionless methane concentration in the dense zone decreases exponentially, while in the splash zone, it varies from an exponential decay to a slow

  1. Conjugated heat transfer and temperature distributions in a gas turbine combustion liner under base-load operation

    International Nuclear Information System (INIS)

    Kim, Kyung Min; Yun, Nam Geon; Jeon, Yun Heung; Lee, Dong Hyun; Cho, Yung Hee

    2010-01-01

    Prediction of temperature distributions on hot components is important in development of a gas turbine combustion liner. The present study investigated conjugated heat transfer to obtain temperature distributions in a combustion liner with six combustion nozzles. 3D numerical simulations using FVM commercial codes, Fluent and CFX were performed to calculate combustion and heat transfer distributions. The temperature distributions in the combustor liner were calculated by conjugation of conduction and convection (heat transfer coefficients) obtained by combustion and cooling flow analysis. The wall temperature was the highest on the attachment points of the combustion gas from combustion nozzles, but the temperature gradient was high at the after shell section with low wall temperature

  2. Combustion Performance of a Staged Hybrid Rocket with Boron addition

    Science.gov (United States)

    Lee, D.; Lee, C.

    2018-04-01

    In this paper, the effect of boron on overall system specific impulse was investigated. Additionally, a series of combustion tests was carried out to analyze and evaluate the effect of boron addition on O/F variation and radial temperature profiles. To maintain the hybrid rocket engine advantages, upper limit of boron contents in solid fuel was set to be 10 wt%. The results also suggested that, when adding boron to solid fuel, it helped to provide more uniform radial temperature distribution and also to increase specific impulse by 3.2%.

  3. Measure Guideline: Combustion Safety for Natural Draft Appliances Using Indoor Air

    Energy Technology Data Exchange (ETDEWEB)

    Brand, L.

    2014-04-01

    This measure guideline covers how to assess and carry out the combustion safety procedures for appliances and heating equipment that uses indoor air for combustion in low-rise residential buildings. Only appliances installed in the living space, or in an area freely communicating with the living space, vented alone or in tandem with another appliance are considered here. A separate measure guideline addresses combustion appliances located either within the living space in enclosed closets or side rooms or outside the living space in an adjacent area like an attic or garage that use outdoor air for combustion. This document is for inspectors, auditors, and technicians working in homes where energy upgrades are being conducted whether or not air infiltration control is included in the package of measures being applied. In the indoor combustion air case, guidelines summarized here are based on language provided in several of the codes to establish minimum requirements for the space using simplified prescriptive measures. In addition, building performance testing procedures are provided by testing agencies. The codes in combination with the test procedures offer comprehensive combustion safety coverage to address safety concerns, allowing inexperienced residential energy retrofit inspectors to effectively address combustion safety issues and allow energy retrofits to proceed.

  4. Concept for premixed combustion of hydrogen-containing fuels in gas turbines; Konzept zur vorgemischten Verbrennung wasserstoffhaltiger Brennstoffe in Gasturbinen

    Energy Technology Data Exchange (ETDEWEB)

    Mayer, Christoph

    2012-07-19

    One of the main challenges for future gas turbines and their combustion systems is to provide fuel flexibility. The fuel range is expected to reach from the lowly reactive natural gas to highly reactive hydrogen-containing syngases. The objective of the project in which this work was pursued is to develop such a combustion system. The burner has to ensure premixed operation with an aerodynamically stabilized flame. The focus of this work is on characterizing and optimizing the operational safety of the system, but also on ensuring sufficientmixing and lowemissions. A burner and fuel injection design is achieved that leads not only to emissions far below the permissible values, but also to flashback safety for hydrogen combustion that comes close to the theoretically achievable maximum at atmospheric pressure conditions. In this design flashback due to combustion-induced vortex breakdown and wall boundary layer flashback is avoided. Flashback only takes place when the flow velocity reaches the flame velocity.

  5. Biogas utilization: Experimental investigation on biogas flameless combustion in lab-scale furnace

    International Nuclear Information System (INIS)

    Hosseini, Seyed Ehsan; Wahid, Mazlan Abdul

    2013-01-01

    Highlights: • High costs of biogas purification and low calorific value of biogas are the main obstacles of biogas utilization. • The energy of biogas can be extracted by flameless combustion without any modification in burner or combustion system. • The efficiency of biogas flameless combustion and conventional combustion were 53% and 32% respectively. • The temperature inside the biogas flameless chamber is uniform. • In biogas flameless combustion, NO x and CO 2 formation decrease drastically in comparison with traditional combustion. - Abstract: Biogas generated in the anaerobic digestion of biomass and organic wastes by micro-organisms can be applied for heating, transportation and power generation as a renewable energy source. However, low calorific value (LCV) of biogas is one the most important bottlenecks of biogas conversion into electrical or thermal energy. Indeed, the presence of corrosive gases such as H 2 S and water vapor in biogas components makes some dilemmas in biogas purification and utilization. In order to obtain the efficient biogas utilization method, different biogas resources, physical and chemical properties of biogas and biogas combustion characteristics should be considered. In this paper biogas was utilized in lab-scale flameless combustion furnace and the performance of flameless combustion chamber fueled by biogas has been presented. Results demonstrated that flameless combustion is one of the best feasible strategies for biogas utilization. Uniformity of temperature in the flameless furnace increases the durability of refractory and related equipment. Simplicity of the flameless burner, pollutant formation reduction and fuel consumption decreases are the main causes of biogas flameless combustion supremacy

  6. Fluidized combustion of beds of large, dense particles in reprocessing HTGR fuel

    International Nuclear Information System (INIS)

    Young, D.T.

    1977-03-01

    Fluidized bed combustion of graphite fuel elements and carbon external to fuel particles is required in reprocessing high-temperature gas-cooled reactor (HTGR) cores for recovery of uranium. This burning process requires combustion of beds containing both large particles and very dense particles as well as combustion of fine graphite particles which elutriate from the bed. Equipment must be designed for optimum simplicity and reliability as ultimate operation will occur in a limited access ''hot cell'' environment. Results reported in this paper indicate that successful long-term operation of fuel element burning with complete combustion of all graphite fines leading to a fuel particle product containing <1% external carbon can be performed on equipment developed in this program

  7. Large eddy simulation of turbulent premixed combustion flows over backward facing step

    Energy Technology Data Exchange (ETDEWEB)

    Park, Nam Seob [Yuhan University, Bucheon (Korea, Republic of); Ko, Sang Cheol [Jeju National University, Jeju (Korea, Republic of)

    2011-03-15

    Large eddy simulation (LES) of turbulent premixed combustion flows over backward facing step has been performed using a dynamic sub-grid G-equation flamelet model. A flamelet model for the premixed flame is combined with a dynamic sub-grid combustion model for the filtered propagation of flame speed. The objective of this study is to investigate the validity of the dynamic sub-grid G-equation model in a complex turbulent premixed combustion flow. For the purpose of validating the LES combustion model, the LES of isothermal and reacting shear layer formed at a backward facing step is carried out. The calculated results are compared with the experimental results, and a good agreement is obtained.

  8. Large eddy simulation of turbulent premixed combustion flows over backward facing step

    International Nuclear Information System (INIS)

    Park, Nam Seob; Ko, Sang Cheol

    2011-01-01

    Large eddy simulation (LES) of turbulent premixed combustion flows over backward facing step has been performed using a dynamic sub-grid G-equation flamelet model. A flamelet model for the premixed flame is combined with a dynamic sub-grid combustion model for the filtered propagation of flame speed. The objective of this study is to investigate the validity of the dynamic sub-grid G-equation model in a complex turbulent premixed combustion flow. For the purpose of validating the LES combustion model, the LES of isothermal and reacting shear layer formed at a backward facing step is carried out. The calculated results are compared with the experimental results, and a good agreement is obtained

  9. Combustion synthesis of TiB2-based cermets: modeling and experimental results

    International Nuclear Information System (INIS)

    Martinez Pacheco, M.; Bouma, R.H.B.; Katgerman, L.

    2008-01-01

    TiB 2 -based cermets are prepared by combustion synthesis followed by a pressing stage in a granulate medium. Products obtained by combustion synthesis are characterized by a large remaining porosity (typically 50%). To produce dense cermets, a subsequent densification step is performed after the combustion process and when the reacted material is still hot. To design the process, numerical simulations are carried out and compared to experimental results. In addition, physical and electrical properties of the products related to electrical contact applications are evaluated. (orig.)

  10. Increase in efficiency and reduction of generation cost at hard coal-fired power plants. Post-combustion of combustion residues from co-firing of RDF and biomass during dry ash removal

    Energy Technology Data Exchange (ETDEWEB)

    Baur, Guenter [Magaldi Power GmbH, Esslingen (Germany); Spindeldreher, Olaf [RWE Generation SE, Werne (Germany); RWE Generation SE, Essen (Germany)

    2013-09-01

    Secondary as well as substitute fuels are being used in hard coal-fired power plants to improve efficiency and to enlarge fuel flexibility. However, grinding and firing systems of the existing coal-fired plants are not designed for those co-fuels. Any deterioration of the combustion performance would reduce the power output and increase ash disposal costs by increased content of combustion residues. The application of air-cooled ash removal, with simultaneous and controlled post-combustion of unburned residues on the conveyor belt, enlarges the furnace and maintains combustion efficiency even with different fuel qualities. Plant efficiency can also be increased through heat recovery. (orig.)

  11. DIAGNOSIS OF FAILURE OF COMBUSTION IN THE COMBUSTION CHAMBER WITH A THERMOVISION EQUIPMENT

    Directory of Open Access Journals (Sweden)

    S. V. Vorobiev

    2014-01-01

    Full Text Available The use of thermovision technology to diagnose failure of the combustion flame test tube of the main combustion chamber gas turbine engine is deal with in the article. Join the thermal radiation of the jet of combustion products and the internal elements was carried out using short-wave thermovision system AGA-782 with spectral spectral filters in several ranges from 3.2 to 5.6 microns. Thermovision is mounted on the axis of the flame tube. The output signal was recorded and processed on a computer in real time, allowing monitor the combustion process and the thermal state of the object during the experiment.

  12. High Combustion Research Facility

    Data.gov (United States)

    Federal Laboratory Consortium — At NETL's High-Pressure Combustion Research Facility in Morgantown, WV, researchers can investigate new high-pressure, high-temperature hydrogen turbine combustion...

  13. Isomer-specific combustion chemistry in allene and propyne flames

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, Nils; Miller, James A. [Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551 (United States); Westmoreland, Phillip R. [Department of Chem. Engineering, University of Massachusetts, Amherst, MA 01003 (United States); Kasper, Tina [Combustion Research Facility, Sandia National Laboratories, Livermore, CA 94551 (United States); Department of Chemistry, Bielefeld University, D-33615 Bielefeld (Germany); Kohse-Hoeinghaus, Katharina [Department of Chemistry, Bielefeld University, D-33615 Bielefeld (Germany); Wang, Juan; Cool, Terrill A. [School of Applied and Engineering Physics, Cornell University, Ithaca, NY 14853 (United States)

    2009-11-15

    A combined experimental and modeling study is performed to clarify the isomer-specific combustion chemistry in flames fueled by the C{sub 3}H{sub 4} isomers allene and propyne. To this end, mole fraction profiles of several flame species in stoichiometric allene (propyne)/O{sub 2}/Ar flames are analyzed by means of a chemical kinetic model. The premixed flames are stabilized on a flat-flame burner under a reduced pressure of 25 Torr (=33.3 mbar). Quantitative species profiles are determined by flame-sampling molecular-beam mass spectrometry, and the isomer-specific flame compositions are unraveled by employing photoionization with tunable vacuum-ultraviolet synchrotron radiation. The temperature profiles are measured by OH laser-induced fluorescence. Experimental and modeled mole fraction profiles of selected flame species are discussed with respect to the isomer-specific combustion chemistry in both flames. The emphasis is put on main reaction pathways of fuel consumption, of allene and propyne isomerization, and of isomer-specific formation of C{sub 6} aromatic species. The present model includes the latest theoretical rate coefficients for reactions on a C{sub 3}H{sub 5} potential [J.A. Miller, J.P. Senosiain, S.J. Klippenstein, Y. Georgievskii, J. Phys. Chem. A 112 (2008) 9429-9438] and for the propargyl recombination reactions [Y. Georgievskii, S.J. Klippenstein, J.A. Miller, Phys. Chem. Chem. Phys. 9 (2007) 4259-4268]. Larger peak mole fractions of propargyl, allyl, and benzene are observed in the allene flame than in the propyne flame. In these flames virtually all of the benzene is formed by the propargyl recombination reaction. (author)

  14. Computational Modeling of Turbulent Spray Combustion

    NARCIS (Netherlands)

    Ma, L.

    2016-01-01

    The objective of the research presented in this thesis is development and validation of predictive models or modeling approaches of liquid fuel combustion (spray combustion) in hot-diluted environments, known as flameless combustion or MILD combustion. The goal is to combine good physical insight,

  15. High-performance carbon-coated ZnMn2O4 nanocrystallite supercapacitors with tailored microstructures enabled by a novel solution combustion method

    Science.gov (United States)

    Abdollahifar, Mozaffar; Huang, Sheng-Siang; Lin, Yu-Hsiang; Lin, Yan-Cheng; Shih, Bing-Yi; Sheu, Hwo-Shuenn; Liao, Yen-Fa; Wu, Nae-Lih

    2018-02-01

    Although ZnMn2O4 is widely studied as Li-ion battery anodes, it remains a challenge to tailor suitable microstructures of the oxide for supercapacitor applications. Carbon-coated ZnMn2O4 (C@ZMO) nanocrystallites showing high-performance pseudocapacitor behaviours in neutral aqueous electrolyte are for the first time successfully synthesised via a novel solution combustion process using polyethylene glycol as a multifunctional microstructure-directing agent. Controlling the molecular weight and amount of the polymer in the combustion solution enables the formation of highly-crystalline C@ZMO having substantially higher, by more than 5 folds, specific surface areas with mesoporous structures and conformal carbon coating via the one-pot synthesis process. The resulting C@ZMO supercapacitor electrodes in Na2SO4(aq) electrolyte exhibit ideal capacitive behaviours with specific capacitances up to 150 F g-1 and cycle stability showing no capacitance fade after 10,000 cycles at 60% of full capacity and >99% Coulombic efficiency. This study not only illustrates a new powerful synthesis route capable of producing conductive mesoporous crystalline oxide-based nanomaterials for energy storage applications but also reveals a new class of high-performance pseudocapacitive materials for neutral aqueous electrolytes.

  16. Space Station Freedom combustion research

    Science.gov (United States)

    Faeth, G. M.

    1992-01-01

    Extended operations in microgravity, on board spacecraft like Space Station Freedom, provide both unusual opportunities and unusual challenges for combustion science. On the one hand, eliminating the intrusion of buoyancy provides a valuable new perspective for fundamental studies of combustion phenomena. On the other hand, however, the absence of buoyancy creates new hazards of fires and explosions that must be understood to assure safe manned space activities. These considerations - and the relevance of combustion science to problems of pollutants, energy utilization, waste incineration, power and propulsion systems, and fire and explosion hazards, among others - provide strong motivation for microgravity combustion research. The intrusion of buoyancy is a greater impediment to fundamental combustion studies than to most other areas of science. Combustion intrinsically heats gases with the resulting buoyant motion at normal gravity either preventing or vastly complicating measurements. Perversely, this limitation is most evident for fundamental laboratory experiments; few practical combustion phenomena are significantly affected by buoyancy. Thus, we have never observed the most fundamental combustion phenomena - laminar premixed and diffusion flames, heterogeneous flames of particles and surfaces, low-speed turbulent flames, etc. - without substantial buoyant disturbances. This precludes rational merging of theory, where buoyancy is of little interest, and experiments, that always are contaminated by buoyancy, which is the traditional path for developing most areas of science. The current microgravity combustion program seeks to rectify this deficiency using both ground-based and space-based facilities, with experiments involving space-based facilities including: laminar premixed flames, soot processes in laminar jet diffusion flames, structure of laminar and turbulent jet diffusion flames, solid surface combustion, one-dimensional smoldering, ignition and flame

  17. Nitrogen chemistry in combustion and gasification - mechanisms and modeling

    International Nuclear Information System (INIS)

    Kilpinen, P.; Hupa, M.

    1998-01-01

    The objective of this work has been to increase the understanding of the complex details of gaseous emission formation in energy production techniques based on combustion and/or gasification. The aim has also been to improve the accuracy of mathematical furnace models when they are used for predicting emissions. The main emphasis has been on nitrogen oxides (NO x , N 2 O). The work supports development of cleaner and more efficient combustion technology. The main emphasis has been on combustion systems that are based on fluidized bed technology including both atmospheric and pressurized conditions (BFBC, CFBC, PFBC/G). The work has consisted of advanced theoretical modeling and of experiments in laboratory devices that have partly been made in collaboration with other LIEKKI projects. Two principal modeling tools have been used: detailed homogeneous chemical kinetic modeling and computational fluid dynamic simulation. In this report, the most important results of the following selected items will be presented: (1) Extension of a detailed kinetic nitrogen and hydrocarbon oxidation mechanism into elevated pressure, and parametric studies on: effect of pressure on fuel-nitrogen oxidation under PFBC conditions, effect of pressure on selective non-catalytic NO x reduction under PFBC conditions, effect of different oxidizers on hot-gas cleaning of ammonia by means of selective oxidation in gasification gas. (2) Extension of the above mechanism to include chlorine reactions at atmospheric pressure, and parametric studies on: effect of HCl on CO burn-out in FBC combustion of waste. (3) Development of more accurate emission prediction models: incorporation of more accurate submodels on hydrocarbon oxidation into CFD furnace models, and evaluation of different concepts describing the interaction between turbulence and chemical reaction, development of a mechanistic detailed 1.5-dimensional emission model for circulating fluidized bed combustors. (orig.) 14 refs

  18. Underground treatment of combustible minerals

    Energy Technology Data Exchange (ETDEWEB)

    Sarapuu, E

    1954-10-14

    A process is described for treating oil underground, consisting in introducing several electrodes spaced one from the other in a bed of combustibles underground so that they come in electric contact with this bed of combustibles remaining insulated from the ground, and applying to the electrodes a voltage sufficient to produce an electric current across the bed of combustibles, so as to heat it and create an electric connection between the electrodes on traversing the bed of combustibles.

  19. Combustion Kinetic Studies of Gasolines and Surrogates

    KAUST Repository

    Javed, Tamour

    2016-01-01

    . These measurements were performed in shock tubes and rapid compression machines over a wide range of experimental conditions (650 – 1250 K, 10 – 40 bar) relevant to internal combustion engines. Using the measured the data and chemical kinetic analyses, the surrogate

  20. Advanced Fuels and Combustion Processes for Propulsion

    Science.gov (United States)

    2010-09-01

    production from biomass steam reforming – Conduct a feasibility analysis of the proposed integrated process Energia Technologies - D. Nguyen & K. Parimi...strength foam material development by Ultramet – Combustion experiments performed U. Of Alabama – End-user input provided by Solar Turbines Major

  1. Multitarget global sensitivity analysis of n-butanol combustion.

    Science.gov (United States)

    Zhou, Dingyu D Y; Davis, Michael J; Skodje, Rex T

    2013-05-02

    A model for the combustion of butanol is studied using a recently developed theoretical method for the systematic improvement of the kinetic mechanism. The butanol mechanism includes 1446 reactions, and we demonstrate that it is straightforward and computationally feasible to implement a full global sensitivity analysis incorporating all the reactions. In addition, we extend our previous analysis of ignition-delay targets to include species targets. The combination of species and ignition targets leads to multitarget global sensitivity analysis, which allows for a more complete mechanism validation procedure than we previously implemented. The inclusion of species sensitivity analysis allows for a direct comparison between reaction pathway analysis and global sensitivity analysis.

  2. Modelling of NO formation in the combustion of coal blends

    Energy Technology Data Exchange (ETDEWEB)

    Arenillas, A.; Backreedy, R.I.; Jones, J.M.; Pis, J.J.; Pourkashanian, M.; Rubiera, F.; Williams, A. [CSIC, Instituto Nacional del Carbon, Oviedo (Spain)

    2002-03-01

    Coal blending is becoming of increasing importance in power stations firing pulverised coal as a result of increasing competition, stricter emission legislation and is an attractive way of improving plant economic and combustion performance. Presently, the two general methods used by power station operators to assess or predict the performance of an unknown coal blend to be fired in power station boilers are by the use of experimental large scale rig tests or correlation indices derived from experience of firing other coal blends in the power station environment. The first is expensive and the second is of doubtful accuracy in some cases. This paper evaluates the application of mathematical modelling of the combustion of a series of binary coal blends in the test situation of a drop tube reactor to predict the NO emissions and degree of char burnout. Its applicability to low NOx burners used in power stations is discussed and it is concluded that present mathematical coal combustion models are not developed sufficiently to enable an adequate description of the binary blends and the physical and chemical processes, which may include interactions, during combustion of the blend. This means that accurate predictions cannot be made. 20 refs., 4 figs., 5 tabs.

  3. Chemical Processes Related to Combustion in Fluidised Bed

    Energy Technology Data Exchange (ETDEWEB)

    Steenari, Britt-Marie; Lindqvist, Oliver [Chalmers Univ. of Technology, Goeteborg (Sweden). Dept. of Environmental Inorganic Chemistry

    2002-12-01

    This report covers work that has been carried out in the combustion chemistry group at the Dept. of Environmental Inorganic Chemistry, Chalmers, within the STEM project 12859-1, during the period 2000-07-01 to 2002-06-30. The work was comprised of the following parts: Sulphur chemistry under pressurised and atmospheric conditions; Gas/solid reactions related to sintering and fouling; Chemistry of volatile metals in combustion; Ash leaching properties; Theoretical modelling of the interactions between ions in a solution and mineral surfaces; Some related issues and co-operations with other departments. The work on sulphur chemistry has been a central issue in our group and it has now been finalised with a PhD thesis discussing some aspects of the sulphation of limestone under pressurised conditions. The influence of a number of parameters on the sulphation efficiency was investigated and compared with similar studies under atmospheric conditions. In a special study it was shown that the influence of alternating calcining - non-calcining conditions on the conversion was substantial. In addition, the oxidation of CaS and sulphided limestone was studied and a regeneration method for the sulphide sorbent was proposed. In the project part concerning gas - solid reactions that are relevant to sintering and fouling, the application of an on-line measurement technique for the study of alkali metal capture by kaolin or other sorbents is described. A new reactor set-up has been constructed and the initial results from this set up are promising. The chemistry of cadmium in combustion of MSW and biomass is the object of a PhD project. This work has been concentrated on the task of identifying Cd-compounds in fly ash samples. It has now come to a point where enough data has been collected to make it possible to give an indication about the Cd speciation in some ash types. In MSW ash particles, cadmium seem to occur mainly as chloride, oxide and sulphate. The work will continue

  4. Combustion synthesis of nanocrystalline ceria (CeO2) powders by a dry route

    International Nuclear Information System (INIS)

    Hwang, C.-C.; Huang, T.-H.; Tsai, J.-S.; Lin, C.-S.; Peng, C.-H.

    2006-01-01

    In this study, ceria (CeO 2 ) powders were synthesized with 50 g per batch via a combustion technique using two kinds of starting materials-urea [(NH 2 ) 2 CO] (as a fuel) and ceric ammonium nitrate [Ce(NH 4 ) 2 (NO 3 ) 6 ] (acting as both the source of cerium ion and an oxidizer). The starting materials were mixed thoroughly without adding water, and then ignited in the air at room temperature. It underwent a self-combustion process with a large amount of smoke, a voluminous loose product. The as-synthesized powders were characterized by X-ray diffraction (XRD) analysis, transmission electron microscope (TEM), scanning electron microscope (SEM), CHN elemental analyzer, surface area measurements, and sinterability. Experimental results revealed that the nanocrystalline CeO 2 powders with low impurity content ( 2 /g and ∼25 nm, respectively, through the stoichiometric fuel/oxidizer ratio reaction. The powder, when cold pressed and sintered in the air at 1250 deg. C for 1 h, was measured to attain the sintered density ∼92% of theoretical density having submicron grain size. In addition, the thermal decomposition and combustion process of the reactant mixture were investigated using thermogravimetry (TG), differential scanning calorimetry (DSC), and mass spectrometry (MS) techniques simultaneously. Based on the results of thermal analysis, a possible mechanism concerning the combustion reaction is proposed

  5. Oxy-Combustion Burner and Integrated Pollutant Removal Research and Development Test Facility

    Energy Technology Data Exchange (ETDEWEB)

    Mark Schoenfield; Manny Menendez; Thomas Ochs; Rigel Woodside; Danylo Oryshchyn

    2012-09-30

    A high flame temperature oxy-combustion test facility consisting of a 5 MWe equivalent test boiler facility and 20 KWe equivalent IPR® was constructed at the Hammond, Indiana manufacturing site. The test facility was operated natural gas and coal fuels and parametric studies were performed to determine the optimal performance conditions and generated the necessary technical data required to demonstrate the technologies are viable for technical and economic scale-up. Flame temperatures between 4930-6120F were achieved with high flame temperature oxy-natural gas combustion depending on whether additional recirculated flue gases are added to balance the heat transfer. For high flame temperature oxy-coal combustion, flame temperatures in excess of 4500F were achieved and demonstrated to be consistent with computational fluid dynamic modeling of the burner system. The project demonstrated feasibility and effectiveness of the Jupiter Oxygen high flame temperature oxy-combustion process with Integrated Pollutant Removal process for CCS and CCUS. With these technologies total parasitic power requirements for both oxygen production and carbon capture currently are in the range of 20% of the gross power output. The Jupiter Oxygen high flame temperature oxy-combustion process has been demonstrated at a Technology Readiness Level of 6 and is ready for commencement of a demonstration project.

  6. Hydraulic modelling of the CARA Fuel element; Desarrollo hidraulico del combustible CARA

    Energy Technology Data Exchange (ETDEWEB)

    Brasnarof, Daniel O; Juanico, Luis [Comision Nacional de Energia Atomica, San Carlos de Bariloche (Argentina). Disenios Avanzados y Evaluacion Economica; Giorgi, M [Comision Nacional de Energia Atomica, General San Martin (Argentina). Dept. de Materiales; Ghiselli, Alberto M; Zampach, Ruben; Fiori, Jose M; Yedros, Pablo A [Comision Nacional de Energia Atomica, General San Martin (Argentina). Dept. de Ensayos no Destructivos

    2004-07-01

    The CARA fuel element is been developing by the National Atomic Energy Commission for both Argentinean PHWRs. In order to keep the hydraulic restriction in their fuel channels, one of CARA's goals is to keep its similarity with both present fuel elements. In this paper is presented pressure drop test performed at a low-pressure facility (Reynolds numbers between 5x10{sup 4} and 1,5x10{sup 5}) and rational base models for their spacer grid and rod assembly. Using these models, we could estimate the CARA hydraulic performance in reactor conditions that have shown to be satisfactory. (author) [Spanish] Con el objeto de validar la similitud hidraulica del elemento combustible CARA con los actuales combustibles de Atucha y Embalse, se realizaron ensayos de perdida de carga en el circuito CBP del CAC con un nuevo diseno de separador de mejor desempeno hidraulico. Se presenta aqui el analisis de los mismos, de los cuales se validaron modelos de base racional para estimar las restricciones hidraulicas de los distintos componentes estructurales (separadores, grillas y barras combustibles) en funcion del flujo refrigerante. Se estimo asi la caida de presion del CARA dentro del canal combustible Embalse en condiciones nominales de reactor, siendo la misma similar al del combustible actual de 37 barras. (autor)

  7. Sandia Combustion Research Program

    Energy Technology Data Exchange (ETDEWEB)

    Johnston, S.C.; Palmer, R.E.; Montana, C.A. (eds.)

    1988-01-01

    During the late 1970s, in response to a national energy crisis, Sandia proposed to the US Department of Energy (DOE) a new, ambitious program in combustion research. Shortly thereafter, the Combustion Research Facility (CRF) was established at Sandia's Livermore location. Designated a ''user facility,'' the charter of the CRF was to develop and maintain special-purpose resources to support a nationwide initiative-involving US inventories, industry, and national laboratories--to improve our understanding and control of combustion. This report includes descriptions several research projects which have been simulated by working groups and involve the on-site participation of industry scientists. DOE's Industry Technology Fellowship program, supported through the Office of Energy Research, has been instrumental in the success of some of these joint efforts. The remainder of this report presents results of calendar year 1988, separated thematically into eleven categories. Referred journal articles appearing in print during 1988 and selected other publications are included at the end of Section 11. Our traditional'' research activities--combustion chemistry, reacting flows, diagnostics, engine and coal combustion--have been supplemented by a new effort aimed at understanding combustion-related issues in the management of toxic and hazardous materials.

  8. Ultra-low pollutant emission combustion method and apparatus

    International Nuclear Information System (INIS)

    Khinkis, M.J.

    1992-01-01

    This patent describes a method for ultra-low pollutant emission combustion of fossil fuel. It comprises: introducing into a primary combustion chamber a first fuel portion of about 1 percent to about 20 percent of a total fuel to be combusted; introducing primary combustion air into the primary combustion chamber; introducing a first portion of water into the primary combustion chamber, having a first water heat capacity equivalent to a primary combustion air heat capacity of one of a primary combustion air amount of about 10 percent to about 60 percent of the first stoichiometirc requirement for complete combustion of the first fuel portion and an excess primary combustion air amount of about 20 percent to about 150 percent of the first stoichiometric requirement for complete combustion of the first fuel portion; burning the first fuel portion with the primary combustion air in the primary combustion chamber at a temperature abut 2000 degrees F to about 2700 degrees F producing initial combustion products; passing the initial combustion products into a secondary combustion chamber; introducing into the secondary combustion chamber a second fuel portion of about 80 percent to about 99 percent of the total fuel to be combusted; introducing secondary combustion air into the secondary combustion chamber in an amount of about 105 percent to about 130 percent of a second stoichiometric requirement for complete combustion of the second fuel portion; introducing a second portion of water into the secondary combustion chamber; burning the second fuel portion and any remaining fuel in the initial combustion products; passing the final combustion products into a dilution chamber; introducing dilution air into the dilution chamber; discharging the ultra-low pollutant emission vitiated air form the dilution chamber

  9. Thermal Conductivity of Epoxy Resin Composites Filled with Combustion Synthesized h-BN Particles.

    Science.gov (United States)

    Chung, Shyan-Lung; Lin, Jeng-Shung

    2016-05-20

    The thermal conductivity of epoxy resin composites filled with combustion-synthesized hexagonal boron nitride (h-BN) particles was investigated. The mixing of the composite constituents was carried out by either a dry method (involving no use of solvent) for low filler loadings or a solvent method (using acetone as solvent) for higher filler loadings. It was found that surface treatment of the h-BN particles using the silane 3-glycidoxypropyltrimethoxysilane (GPTMS) increases the thermal conductivity of the resultant composites in a lesser amount compared to the values reported by other studies. This was explained by the fact that the combustion synthesized h-BN particles contain less -OH or active sites on the surface, thus adsorbing less amounts of GPTMS. However, the thermal conductivity of the composites filled with the combustion synthesized h-BN was found to be comparable to that with commercially available h-BN reported in other studies. The thermal conductivity of the composites was found to be higher when larger h-BN particles were used. The thermal conductivity was also found to increase with increasing filler content to a maximum and then begin to decrease with further increases in this content. In addition to the effect of higher porosity at higher filler contents, more horizontally oriented h-BN particles formed at higher filler loadings (perhaps due to pressing during formation of the composites) were suggested to be a factor causing this decrease of the thermal conductivity. The measured thermal conductivities were compared to theoretical predictions based on the Nielsen and Lewis theory. The theoretical predictions were found to be lower than the experimental values at low filler contents ( 60 vol %).

  10. 40 CFR Table 1 to Subpart Aaaa of... - Emission Limits for New Small Municipal Waste Combustion Units

    Science.gov (United States)

    2010-07-01

    ... Waste Combustion Units 1 Table 1 to Subpart AAAA of Part 60 Protection of Environment ENVIRONMENTAL... Standards of Performance for Small Municipal Waste Combustion Units for Which Construction is Commenced... Combustion Units For the following pollutants You must meet thefollowing emission limits a Using the...

  11. LES SOFTWARE FOR THE DESIGN OF LOW EMISSION COMBUSTION SYSTEMS FOR VISION 21 PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    Clifford E. Smith; Steven M. Cannon; Virgil Adumitroaie; David L. Black; Karl V. Meredith

    2005-01-01

    to hundreds of PCs and performing parallel computations with fine grids (millions of cells). Such simulations, performed in a few weeks or less, provide a very cost-effective complement to experimental testing. In 5 years, these same calculations can be performed in 24 hours or less due to the expected increase of computing power and improved numerical techniques. This project was a four-year program. During the first year, the project included the development and implementation of improved chemistry (reduced GRI mechanism), subgrid turbulence (localized dynamic), and subgrid combustion-turbulence interaction (Linear Eddy) models into the CFD-ACE+ code. University expertise (Georgia Tech and University of California, Berkeley) was utilized to help develop and implement these advanced submodels into the unstructured, parallel CFD flow solver, CFD-ACE+. Efficient numerical algorithms that rely on in situ look-up tables or artificial neural networks were implemented for chemistry calculations. In the second year, the combustion LES software was evaluated and validated using experimental data from lab-scale and industrial test configurations. This code testing (i.e., alpha testing) was performed by CFD Research Corporation's engineers. During the third year, six industrial and academic partners used the combustion LES code and exercised it on problems of their choice (i.e., beta testing). Final feedback and optimizations were then implemented into the final release (licensed) version of the combustion LES software to the general public. An additional one-year task was added for the fourth year of this program entitled, ''LES Simulations of SIMVAL Results''. For this task, CFDRC performed LES calculations of selected DoE SIMVAL cases, and compared predictions with measurements from NETL. In addition to comparisons with NOx and CO exit measurements, comparisons were made to measured pressure oscillations. Potential areas of improvement for

  12. Performance analysis of single stage libr-water absorption machine operated by waste thermal energy of internal combustion engine: Case study

    Science.gov (United States)

    Sharif, Hafiz Zafar; Leman, A. M.; Muthuraman, S.; Salleh, Mohd Najib Mohd; Zakaria, Supaat

    2017-09-01

    Combined heating, cooling, and power is also known as Tri-generation. Tri-generation system can provide power, hot water, space heating and air -conditioning from single source of energy. The objective of this study is to propose a method to evaluate the characteristic and performance of a single stage lithium bromide-water (LiBr-H2O) absorption machine operated with waste thermal energy of internal combustion engine which is integral part of trigeneration system. Correlations for computer sensitivity analysis are developed in data fit software for (P-T-X), (H-T-X), saturated liquid (water), saturated vapor, saturation pressure and crystallization temperature curve of LiBr-H2O Solution. Number of equations were developed with data fit software and exported into excel work sheet for the evaluation of number of parameter concerned with the performance of vapor absorption machine such as co-efficient of performance, concentration of solution, mass flow rate, size of heat exchangers of the unit in relation to the generator, condenser, absorber and evaporator temperatures. Size of vapor absorption machine within its crystallization limits for cooling and heating by waste energy recovered from exhaust gas, and jacket water of internal combustion engine also presented in this study to save the time and cost for the facilities managers who are interested to utilize the waste thermal energy of their buildings or premises for heating and air conditioning applications.

  13. TOXIC SUBSTANCES FROM COAL COMBUSTION-A COMPREHENSIVE ASSESSMENT

    Energy Technology Data Exchange (ETDEWEB)

    C.L. Senior; F. Huggins; G.P. Huffman; N. Shah; N. Yap; J.O.L. Wendt; W. Seames; M.R. Ames; A.F. Sarofim; S. Swenson; J.S. Lighty; A. Kolker; R. Finkelman; C.A. Palmer; S.J. Mroczkowski; J.J. Helble; R. Mamani-Paco; R. Sterling; G. Dunham; S. Miller

    2001-06-30

    the speciation of mercury captured on low-temperature sorbents from combustion flue gases and developed XAFS parameters for such analyses. We demonstrated that all mercury sorption processes appeared to involve chemisorption rather than physisorption. This work aimed to develop a model that predicts the vaporization of metals during coal combustion and to incorporate this model into the existing Engineering Model for Ash Formation (EMAF). The model is based on theoretical analysis for metal vaporization, experimental data and data correlations. The existing program, EMAF, was substantially modified to accommodate the vaporization sub-model.

  14. Alcohol combustion chemistry

    KAUST Repository

    Sarathy, Mani

    2014-10-01

    Alternative transportation fuels, preferably from renewable sources, include alcohols with up to five or even more carbon atoms. They are considered promising because they can be derived from biological matter via established and new processes. In addition, many of their physical-chemical properties are compatible with the requirements of modern engines, which make them attractive either as replacements for fossil fuels or as fuel additives. Indeed, alcohol fuels have been used since the early years of automobile production, particularly in Brazil, where ethanol has a long history of use as an automobile fuel. Recently, increasing attention has been paid to the use of non-petroleum-based fuels made from biological sources, including alcohols (predominantly ethanol), as important liquid biofuels. Today, the ethanol fuel that is offered in the market is mainly made from sugar cane or corn. Its production as a first-generation biofuel, especially in North America, has been associated with publicly discussed drawbacks, such as reduction in the food supply, need for fertilization, extensive water usage, and other ecological concerns. More environmentally friendly processes are being considered to produce alcohols from inedible plants or plant parts on wasteland. While biofuel production and its use (especially ethanol and biodiesel) in internal combustion engines have been the focus of several recent reviews, a dedicated overview and summary of research on alcohol combustion chemistry is still lacking. Besides ethanol, many linear and branched members of the alcohol family, from methanol to hexanols, have been studied, with a particular emphasis on butanols. These fuels and their combustion properties, including their ignition, flame propagation, and extinction characteristics, their pyrolysis and oxidation reactions, and their potential to produce pollutant emissions have been intensively investigated in dedicated experiments on the laboratory and the engine scale

  15. NOx Emission Reduction by Oscillating Combustion

    Energy Technology Data Exchange (ETDEWEB)

    John C. Wagner

    2004-03-31

    attributes of oscillating combustion and on the results of an earlier project at GTI and Air Liquide, to determine which applications for oscillating combustion would show the greatest probability for technical success and greatest probability for market acceptability. The market study indicated that furnaces in the steel, glass, and metal melting industries would perform well in both categories. These findings guided the selection of burners for laboratory testing and, with the results of the laboratory testing, guided the selection of field test sites.

  16. NOx Emission Reduction by Oscillating combustion

    Energy Technology Data Exchange (ETDEWEB)

    Institute of Gas Technology

    2004-01-30

    attributes of oscillating combustion and on the results of an earlier project at GTI and Air Liquide, to determine which applications for oscillating combustion would show the greatest probability for technical success and greatest probability for market acceptability. The market study indicated that furnaces in the steel, glass, and metal melting industries would perform well in both categories. These findings guided the selection of burners for laboratory testing and, with the results of the laboratory testing, guided the selection of field test sites.

  17. Numerical study on NO formation in a pulverized coal-fired furnace using oxy-fuel combustion

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Aiyue; Chen, Yuan; Sheng, Changdong [Southeast Univ., Nanjing (China). School of Energy and Environment

    2013-07-01

    Computational fluid dynamics (CFD) approach was employed to numerically investigate NO formation in a 600 MW wall-fired pulverized coal-fired furnace retrofitted for oxy-coal combustion, aimed at the impacts of flue gas recycle ratio, O{sub 2} staging and recycled NO with the recycled flue gas (RFG) on NO formation and emission. An in-house CFD research code for conventional air combustion was developed and extended to simulate O{sub 2}/RFG combustion with specific considerations of the change of gas properties and its impact on coal particle combustion processes. The extended De Soete mechanisms including NO reburning mechanism were applied to describe transformations of fuel nitrogen. It was shown that CFD simulation represented the significant reduction of NO formation during O{sub 2}/RFG combustion compared to that during air combustion. The in-burner and particularly the in-furnace O{sub 2} staging were confirmed still to play very important roles in NO formation control. Changing the recycle ratio had significant impact on the combustion performance and consequently on NO formation and emission. With the combustion performance ensured, decreasing the flue gas recycle ratio or increasing the inlet O{sub 2} concentration of combustion gas led to reduction of NO formation and emission. Although NO formation and emission was found to increase with increasing the inlet NO concentration of combustion gas, CFD simulation indicated that {proportional_to}74% of the inlet NO was reduced in the furnace, consistent with the experimental data reported in the literature. This demonstrated the significant contribution of reburning mechanism to the reduction of the recycled NO in the furnace.

  18. Experimental study of slight temperature rise combustion in trapped vortex combustors for gas turbines

    International Nuclear Information System (INIS)

    Zhang, R.C.; Fan, W.J.; Xing, F.; Song, S.W.; Shi, Q.; Tian, G.H.; Tan, W.L.

    2015-01-01

    Interstage turbine combustion used for improving efficiency of gas turbine was a new type of combustion mode. Operating conditions and technical requirements for this type of combustor were different from those of traditional combustor. It was expected to achieve engineering application in both ground-based and aviation gas turbine in the near future. In this study, a number of modifications in a base design were applied and examined experimentally. The trapped-vortex combustion technology was adopted for flame stability under high velocity conditions, and the preheating-fuel injection technology was used to improve the atomization and evaporation performance of liquid fuel. The experimental results indicated that stable and efficient combustion with slight temperature-rise can be achieved under the high velocity conditions of combustor inlet. Under all experimental conditions, the excess air coefficients of ignition and lean blow-out were larger than 7 and 20, respectively; pollutant emission index of NO x and the maximum wall temperature were below 2.5 g/(kg fuel) and 1050 K, respectively. Moreover, the effects of fuel injection and overall configuration on the combustion characteristics were analyzed in detail. The number increase, area increase and depth increase of fuel injectors had different influences on the stability, combustion characteristic and temperature distribution. - Highlights: • The combustion mode of slight temperature-rise (200 K) was achieved. • Effect of fuel and air injection on stability characteristic was investigated. • Impact of overall configuration on combustion performance was analyzed. • The feasibility of scheme was determined.

  19. Indoor combustion and asthma.

    Science.gov (United States)

    Belanger, Kathleen; Triche, Elizabeth W

    2008-08-01

    Indoor combustion produces both gases (eg, nitrogen dioxide, carbon monoxide) and particulate matter that may affect the development or exacerbation of asthma. Sources in the home include both heating devices (eg, fireplaces, woodstoves, kerosene heaters, flued [ie, vented] or nonflued gas heaters) and gas stoves for cooking. This article highlights the recent literature examining associations between exposure to indoor combustion and asthma development and severity. Since asthma is a chronic condition affecting both children and adults, both age groups are included in this article. Overall, there is some evidence of an association between exposure to indoor combustion and asthma, particularly asthma symptoms in children. Some sources of combustion such as coal stoves have been more consistently associated with these outcomes than other sources such as woodstoves.

  20. Experimental and numerical studies on two-stage combustion of biomass

    Energy Technology Data Exchange (ETDEWEB)

    Houshfar, Eshan

    2012-07-01

    In this thesis, two-stage combustion of biomass was experimentally/numerically investigated in a multifuel reactor. The following emissions issues have been the main focus of the work: 1- NOx and N2O 2- Unburnt species (CO and CxHy) 3- Corrosion related emissions.The study had a focus on two-stage combustion in order to reduce pollutant emissions (primarily NOx emissions). It is well known that pollutant emissions are very dependent on the process conditions such as temperature, reactant concentrations and residence times. On the other hand, emissions are also dependent on the fuel properties (moisture content, volatiles, alkali content, etc.). A detailed study of the important parameters with suitable biomass fuels in order to optimize the various process conditions was performed. Different experimental studies were carried out on biomass fuels in order to study the effect of fuel properties and combustion parameters on pollutant emissions. Process conditions typical for biomass combustion processes were studied. Advanced experimental equipment was used in these studies. The experiments showed the effects of staged air combustion, compared to non-staged combustion, on the emission levels clearly. A NOx reduction of up to 85% was reached with staged air combustion using demolition wood as fuel. An optimum primary excess air ratio of 0.8-0.95 was found as a minimizing parameter for the NOx emissions for staged air combustion. Air staging had, however, a negative effect on N2O emissions. Even though the trends showed a very small reduction in the NOx level as temperature increased for non-staged combustion, the effect of temperature was not significant for NOx and CxHy, neither in staged air combustion or non-staged combustion, while it had a great influence on the N2O and CO emissions, with decreasing levels with increasing temperature. Furthermore, flue gas recirculation (FGR) was used in combination with staged combustion to obtain an enhanced NOx reduction. The