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Sample records for tertiary lacustrine source

  1. Geochemical characteristics of Tertiary saline lacustrine oils in the Western Qaidam Basin, northwest China

    International Nuclear Information System (INIS)

    Zhu Yangming; Weng Huanxin; Su Aiguo; Liang Digang; Peng Dehua

    2005-01-01

    Based on the systematic analyses of light hydrocarbon, saturate, aromatic fractions and C isotopes of over 40 oil samples along with related Tertiary source rocks collected from the western Qaidam basin, the geochemical characteristics of the Tertiary saline lacustrine oils in this region was investigated. The oils are characterized by bimodal n-alkane distributions with odd-to-even (C 11 -C 17 ) and even-to-odd (C 18 -C 28 ) predominance, low Pr/Ph (mostly lower than 0.6), high concentration of gammacerane, C 35 hopane and methylated MTTCs, reflecting the high salinity and anoxic setting typical of a saline lacustrine depositional environment. Mango's K 1 values in the saline oils are highly variable (0.99-1.63), and could be associated with the facies-dependent parameters such as Pr/Ph and gammacerane indexes. Compared with other Tertiary oils, the studied Tertiary saline oils are marked by enhanced C 28 sterane abundance (30% or more of C 27 -C 29 homologues), possibly derived from halophilic algae. It is noted that the geochemical parameters of the oils in various oilfields exhibit regular spatial changes, which are consistent with the depositional phase variations of the source rocks. The oils have uncommon heavy C isotopic ratios (-24%o to -26%o) and a flat shape of the individual n-alkane isotope profile, and show isotopic characteristics similar to marine organic matter. The appearance of oleanane and high 24/(24 + 27)-norcholestane ratios (0.57-0.87) in the saline oils and source rocks confirm a Tertiary organic source

  2. Characterization of Tertiary Catalan lacustrine oil shales: Discovery of extremely organic sulphur-rich Type I kerogens

    Science.gov (United States)

    Sinninghe Damsté, Jaap S.; de las Heras, F. Xavier C.; van Bergen, Pim F.; de Leeuw, Jan W.

    1993-01-01

    The kerogens of three Tertiary Catalan lacustrine oil shales were analyzed by light microscopy, flash pyrolysis-gas chromatography-mass spectrometry, and bulk composition methods (elemental analysis, Rock Eval pyrolysis). Two of the three kerogens (Ribesalbes and Campins) are extremely rich in organic sulphur (atomic S org/C ratio > 0.04) and hydrogen (atomic ratio H/C ratio > 1.5) and are, consequently, classified as Type I-S kerogens. Very characteristic distribution patterns of flash pyrolysis products (e.g., alkan-9- and -10-ones, alkadienes) of the Ribesalbes kerogen revealed that it is predominantly composed of fossilized organic matter of the freshwater alga Botryococcus braunii. These two findings demonstrate that sulphurization of organic matter may also occur in lacustrine sediments provided that sulphate is supplied by external sources. Data on the third kerogen sample (Cerdanya) suggest that the freshwater alga Pediastrum may contain a (partly) aromatic biomacromolecule that is selectively preserved upon diagenesis. These findings testify to the large variability in palaeodepositional conditions in lacustrine environments. A comparison of the biomarker composition of the extract of the Ribesalbes oil shale with the kerogen composition indicate that biomarkers often cannot be used to assess the major sources of organic matter in such settings. A similar conclusion can be drawn from a comparison of literature data concerning the Messel Oil Shale.

  3. Characterisation of Tertiary Catalan lacustrine oil shales: Discovery of extremely organic sulphur-rich type I kerogens

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Las Heras, F.X.C. de; Bergen, P.F. van; Leeuw, J.W. de

    1993-01-01

    The kerogens of three Tertiary Catalan lacustrine oil shales were analyzed by light microscopy, flash pyrolysis-gas chromatography-mass spectrometry, and bulk composition methods (elemental analysis, Rock Eval pyrolysis). Two of the three kerogens (Ribesalbes and Campins) are extremely rich in

  4. Characterization of Tertiary Catalan lacustrine oil shales: Discovery of extrmely organic sulphur-rich Type I kerogens

    Energy Technology Data Exchange (ETDEWEB)

    Sinninghe Damste, J.S.; Heras, F.X.C. De Las; Bergen, P.F. Van; Leeuw, J.W. De (Delft Univ. of Technology (Netherlands))

    1993-01-01

    The kerogens of three Tertiary Catalan lacustrine oil shales were analyzed by light microscopy, flash pyrolysis-gas chromatography-mass spectrometry, and bulk composition methods (elemental analysis, Rock Eval pyrolysis). Two of the three kerogens (Ribesalbes and Campins) are extremely rich in organic sulfur (atomic S[sub org]/C ratio > 0.04) and hydrogen (atomic ratio H/C ratio > 1.5) and are, consequently, classified as Type I-S kerogens. Very characteristic distribution patterns of flash pyrolysis products (e.g., alkan-9- and -10-ones, alkadienes) of the Ribesalbes kerogen revealed that it is predominantly composed of fossilized organic matter of the freshwater alga Botryococcus braunii. These two findings demonstrate that sulfurization of organic matter may also occur in lacustrine sediments provided that sulfate is supplied by external sources. Data on the third kerogen sample (Cerdanya) suggest that the freshwater alga Pediastrum may contain a (partly) aromatic biomacromolecule that is selectively preserved upon diagenesis. These findings testify to the large variability in palaeodepositional conditions in lacutrine environments. A comparison of the biomarker composition of the extract of the Ribesalbes oil shale with the kerogen composition indicate that biomarkers often cannot be used to assess the major sources of organic matter in such settings. A similar conclusion can be drawn from a comparison of literature data concerning the Messel Oil Shale. 75 refs., 18 figs., 7 tabs.

  5. Organic compositions of lacustrine source rocks in Jiyang super-depression and its implication to petroleum geology

    Institute of Scientific and Technical Information of China (English)

    2006-01-01

    The compositions of organic matter in four immature source rocks from Tertiary strata of Jiyang super-depression, the most typical continental rift subsidence basin in East China, have been studied by different extracting methods with CHCl3, MAC and CS2/NMP, respectively. The results suggest that there are great differences among the chemical compositions of organic matter in the source rocks derived from different depositional environments. About 79% of all the organic matter exists by non- covalent bond in the Es4 source rocks which were deposited under the saline lacustrine, indicating that its organic matter is not the real kerogen, but mainly composed of soluble organic matter which is easy to generate hydrocarbon at lower temperature. This is why the immature oils were derived from Es4 source rocks in Dongying depression. In contrast, around 60% of organic matter exists by covalent bond in Es3 source rocks which were deposited under the deep brackish-fresh lacustrine, showing that Es3 source rocks are mainly composed of kerogen producing mature hydrocarbon at higher temperature. The thermal simulation experiments, upon the remaining solid source rocks which were sequentially extracted by the three solvents, have been carried out. The chloroform extracts from the simulation product have been compared with the other three solvent extracts gained at room temperature. It is obvious that remarkable odd/even predominance (OEP) is mainly the characteristic of soluble organic matter; phytane mostly exists in the soluble organic matter by means of non-covalent bonds and characteristics of soluble organic matter are similar to these in immature oils produced in Jiyang super-depression.

  6. Free and sulphurized hopanoids and highly branched isoprenoids in immature lacustrine oil shales

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Las Heras, F.X.C. de; Grimalt, J.O.; Lopez, J.F.; Albaiges, J.; Leeuw, J.W. de

    1997-01-01

    A study of the solvent extracts of four samples from two immature oil shales from Tertiary lacustrine basins, Ribesalbes and Campins (southern European rift system), deposited under reducing conditions, has allowed the identification of S-containing hopanoids and novel highly branched isoprenoids

  7. Molecular isotopic characterisation of hydrocarbon biomarkers in Palaeocene-Eocene evaporitic, lacustrine source rocks from the Jianghan Basin, China

    NARCIS (Netherlands)

    Sinninghe Damsté, J.S.; Grice, Kliti; Schouten, S.; Peters, Kenneth E.

    1998-01-01

    Immature organic matter in lacustrine source rocks from the Jianghan Basin, eastern China, was studied for distributions and stable carbon isotopic compositions (13C) of hydrocarbon biomarkers. All of the bitumens contain isorenieratane (13C ca. −17 ) indicating the presence of Chlorobiaceae, and

  8. Sources and proxy potential of long chain alkyl diols in lacustrine environments

    Science.gov (United States)

    Rampen, Sebastiaan W.; Datema, Mariska; Rodrigo-Gámiz, Marta; Schouten, Stefan; Reichart, Gert-Jan; Sinninghe Damsté, Jaap S.

    2014-11-01

    Long chain 1,13- and 1,15-alkyl diols form the base of a number of recently proposed proxies used for climate reconstruction. However, the sources of these lipids and environmental controls on their distribution are still poorly constrained. We have analyzed the long chain alkyl diol (LCD) composition of cultures of ten eustigmatophyte species, with three species from different families grown at various temperatures, to identify the effect of species composition and growth temperature on the LCD distribution. The results were compared with the LCD distribution of sixty-two lake surface sediments, and with previously reported LCD distributions from marine environments. The different families within the Eustigmatophyceae show distinct LCD patterns, with the freshwater family Eustigmataceae most closely resembling LCD distributions in both marine and lake environments. Unlike the other two eustigmatophyte families analyzed (Monodopsidaceae and Goniochloridaceae), C28 and C30 1,13-alkyl diols and C30 and C32 1,15-alkyl diols are all relatively abundant in the family Eustigmataceae, while the mono-unsaturated C32 1,15-alkyl diol was below detection limit. In contrast to the marine environment, LCD distributions in lakes did not show a clear relationship with temperature. The Long chain Diol Index (LDI), a proxy previously proposed for sea surface temperature reconstruction, showed a relatively weak correlation (R2 = 0.33) with mean annual air temperature used as an approximation for annual mean surface temperature of the lakes. A much-improved correlation (R2 = 0.74, p-value cultures of the family Eustigmataceae, suggesting that algae belonging to this family have an important role as a source for LCDs in lacustrine environments, or, alternatively, that the main sources of LCDs are similarly affected by temperature as the Eustigmataceae. The results suggest that LCDs may have the potential to be applicable as a palaeotemperature proxy for lacustrine environments

  9. Mineral Trends in Early Hesperian Lacustrine Mudstone at Gale Crater, Mars

    Science.gov (United States)

    Rampe, E. B.; Ming, D. W.; Grotzinger, J. P.; Morris, R. V.; Blake, D. F.; Vaniman, D. T.; Bristow, T. F.; Morrison, S. M.; Yen, A. S.; Chipera, S. J.; hide

    2017-01-01

    The Mars Science Laboratory Curiosity rover landed in Gale crater in August 2012 to study the layered sediments of lower Aeolis Mons (i.e., Mount Sharp), which have signatures of phyllosilicates, hydrated sulfates, and iron oxides in orbital visible/near-infrared observations. The observed mineralogy within the stratigraphy, from phyllosilicates in lower units to sulfates in higher units, suggests an evolution in the environments in which these secondary phases formed. Curiosity is currently investigating the sedimentary structures, geochemistry, and mineralogy of the Murray formation, the lowest exposed unit of Mount Sharp. The Murray formation is dominated by laminated lacustrine mudstone and is approx.200 m thick. Curiosity previously investigated lacustrine mudstone early in the mission at Yellowknife Bay, which represents the lowest studied stratigraphic unit. Here, we present the minerals identified in lacus-trine mudstone from Yellowknife Bay and the Murray formation. We discuss trends in mineralogy within the stratigraphy and the implications for ancient lacustrine environments, diagenesis, and sediment sources.

  10. Lacustrine-humate model for primary uranium ore deposits, Grants Uranium Region, New Mexico

    International Nuclear Information System (INIS)

    Turner-Peterson, C.E.

    1985-01-01

    Two generations of uranium ore, primary and redistributed, occur in fluvial sandstones of the Upper Jurassic Morrison Formation in the San Juan basin; the two stages of ore formation can be related to the hydrologic history of the basin. Primary ore formed soon after Morrison deposition, in the Late Jurassic to Early Cretaceous, and a model, the lacustrine-humate model, is offered that views primary mineralization as a diagenetic event related to early pore fluid evolution. The basic premise is that the humate, a pore-filling organic material closely associated with primary ore, originated as humic acids dissolved in pore waters of greenish-gray lacustrine mudstones deposited in the mud-flat facies of the Brushy Basin Member and similar K shale beds in the Westwater Canyon Member. During compaction associated with early burial, formation water expelled from lacustrine mudstone units carried these humic acids into adjacent sandstone beds where the organics precipitated, forming the humate deposits that concentrated uranium. During the Tertiary, much later in the hydrologic history of the basin, when Jurassic sediments were largely compacted, oxygenated ground water flowed basinward from uplifted basin margins. This invasion of Morrison sandstone beds by oxidizing ground waters redistributed uranium from primary ores along redox boundaries, forming ore deposits that resemble roll-front-type uranium ores. 11 figures

  11. Trace fossil analysis of lacustrine facies and basins

    Science.gov (United States)

    Buatois, L.A.; Mangano, M.G.

    1998-01-01

    Two ichnofacies are typical of lacustrine depositional systems. The Scoyenia ichnofacies characterizes transitional terrestrial/nonmarine aquatic substrates, periodically inundated or desiccated, and therefore is commonly present in lake margin facies. The Mermia ichnofacies is associated with well oxygenated, permanent subaqueous, fine-grained substrates of hydrologically open, perennial lakes. Bathymetric zonations within the Mermia ichnofacies are complicated by the wide variability of lacustrine systems. Detected proximal-distal trends are useful within particular lake basins, but commonly difficult to extrapolate to other lakes. Other potential ichnofacies include the typically marine Skolithos ichnofacies for high-energy zones of lakes and substrate-controlled, still unnamed ichnofacies, associated to lake margin deposits. Trace fossils are useful for sedimentologic analysis of event beds. Lacustrine turbidites are characterized by low-diversity suites, reflecting colonization by opportunistic organisms after the turbidite event. Underflow current beds record animal activity contemporaneous with nearly continuous sedimentation. Ichnologic studies may also help to distinguish between marine and lacustrine turbidites. Deep-marine turbidites host the Nereites ichnofacies that consists of high diversity of ornate grazing traces and graphoglyptids, recording highly specialized feeding strategies developed to solve the problem of the scarcity of food in the deep sea. Deep lacustrine environments contain the Mermia ichnofacies, which is dominated by unspecialized grazing and feeding traces probably related to the abundance and accessibility of food in lacustrine systems. The lower diversity of lacustrine ichnofaunas in comparison with deep-sea assemblages more likely reflects lower species diversity as a consequence of less stable conditions. Increase of depth and extent of bioturbation through geologic time produced a clear signature in the ichnofabric record of

  12. Branched GDGTs in Lacustrine Environments: Tracing Allochthonous and Autochthonous Sources Using Compound-Specific Stable Carbon Isotope Analysis

    Science.gov (United States)

    Weber, Y.; S Sinninghe Damsté, J.; Lehmann, M. F.; Niemann, H.; Schubert, C. J.

    2015-12-01

    Branched glycerol dialkyl glycerol tetraethers (brGDGTs) are bacterial membrane lipids that are ubiquitous in soils and peat, as well as in sediments of lakes, rivers and coastal marine environments. It has been found that the distribution of brGDGTs changes systematically with ambient temperature and pH, attesting to their potential as proxy indicators for paleoclimatic reconstruction. In lacustrine sedimentary archives, brGDGTs can originate from two sources: (1) allochthonous soil organic matter and (2) autochthonous brGDGTs produced within the lake system, both of which display fairly distinct temperature-brGDGT relationships. Until now, disentangling the relative contribution of these sources was impossible, complicating the use of brGDGTs for quantitative paleotemperature reconstructions. BrGDGTs in soils display a narrow range with respect to their stable carbon isotope composition (δ13C), generally between -27 and -30 ‰, whereas we recently found contrasting δ13C values as low as -43 ‰ to -46 ‰ for brGDGTs in sediments of a small Alpine lake. To trace the origin of this distinct isotope signal, we determined the 13C content of brGDGTs in suspended particulate matter (SPM) from the water column of Lake Lugano (Switzerland). The δ13C of SPM-derived brGDGTs decreased systematically from -34 ‰ in the mixolimnion to -41 ‰ in the anoxic monimolimnion of Lake Lugano, providing evidence for aquatic in situ production of 13C-depleted brGDGT. In order to study whether the negative δ13C offset of water column- vs. soil-derived brGDGTs may serve as an indicator for lacustrine brGDGT production, we also analyzed surface sediments from 36 lakes across the Alpine Region. In most (~85 %) of the studied lake sediments, the δ13C of brGDGTs ranged between -34 ‰ and -45 ‰, indicating predominance or a substantial contribution of aquatically produced brGDGTs. However, in some lakes (~15 %) δ13C values between -27 ‰ and -30 ‰ suggest a mainly

  13. A Middle-Upper Miocene fluvial-lacustrine rift sequence in the Song Ba Rift, Vietnam

    DEFF Research Database (Denmark)

    Lars H., Nielsen; Henrik I., Petersen; Nguyen D., Dau

    2007-01-01

    The small Neogene Krong Pa graben is situated within the continental Song Ba Rift, which is bounded by strike-slip faults that were reactivated as extensional faults in Middle Miocene time. The 500 m thick graben-fill shows an overall depositional development reflecting the structural evolution...... subsidence rate and possibly a higher influx of water from the axial river systems the general water level in the graben rose and deep lakes formed. High organic preservation in the lakes prompted the formation of two excellent oil-prone lacustrine source-rock units. In the late phase of the graben...... as carrier beds, whereas the braided fluvial sandstones and conglomerates along the graben margins may form reservoirs. The Krong Pa graben thus contains oil-prone lacustrine source rocks, effective conduits for generated hydrocarbons and reservoir sandstones side-sealed by the graben faults toward...

  14. Shahejie-Shahejie/Guantao/Wumishan and Carboniferous/Permian Coal-Paleozoic Total Petroleum Systems in the Bohaiwan Basin, China (based on geologic studies for the 2000 World Energy Assessment Project of the U.S. Geological Survey)

    Science.gov (United States)

    Ryder, Robert T.; Qiang, Jin; McCabe, Peter J.; Nuccio, Vito F.; Persits, Felix

    2012-01-01

    This report discusses the geologic framework and petroleum geology used to assess undiscovered petroleum resources in the Bohaiwan basin province for the 2000 World Energy Assessment Project of the U.S. Geological Survey. The Bohaiwan basin in northeastern China is the largest petroleum-producing region in China. Two total petroleum systems have been identified in the basin. The first, the Shahejie&ndashShahejie/Guantao/Wumishan Total Petroleum System, involves oil and gas generated from mature pods of lacustrine source rock that are associated with six major rift-controlled subbasins. Two assessment units are defined in this total petroleum system: (1) a Tertiary lacustrine assessment unit consisting of sandstone reservoirs interbedded with lacustrine shale source rocks, and (2) a pre-Tertiary buried hills assessment unit consisting of carbonate reservoirs that are overlain unconformably by Tertiary lacustrine shale source rocks. The second total petroleum system identified in the Bohaiwan basin is the Carboniferous/Permian Coal–Paleozoic Total Petroleum System, a hypothetical total petroleum system involving natural gas generated from multiple pods of thermally mature coal beds. Low-permeability Permian sandstones and possibly Carboniferous coal beds are the reservoir rocks. Most of the natural gas is inferred to be trapped in continuous accumulations near the center of the subbasins. This total petroleum system is largely unexplored and has good potential for undiscovered gas accumulations. One assessment unit, coal-sourced gas, is defined in this total petroleum system.

  15. Nanometer-Scale Pore Characteristics of Lacustrine Shale, Songliao Basin, NE China.

    Directory of Open Access Journals (Sweden)

    Min Wang

    Full Text Available In shale, liquid hydrocarbons are accumulated mainly in nanometer-scale pores or fractures, so the pore types and PSDs (pore size distributions play a major role in the shale oil occurrence (free or absorbed state, amount of oil, and flow features. The pore types and PSDs of marine shale have been well studied; however, research on lacustrine shale is rare, especially for shale in the oil generation window, although lacustrine shale is deposited widely around the world. To investigate the relationship between nanometer-scale pores and oil occurrence in the lacustrine shale, 10 lacustrine shale core samples from Songliao Basin, NE China were analyzed. Analyses of these samples included geochemical measurements, SEM (scanning electron microscope observations, low pressure CO2 and N2 adsorption, and high-pressure mercury injection experiments. Analysis results indicate that: (1 Pore types in the lacustrine shale include inter-matrix pores, intergranular pores, organic matter pores, and dissolution pores, and these pores are dominated by mesopores and micropores; (2 There is no apparent correlation between pore volumes and clay content, however, a weak negative correlation is present between total pore volume and carbonate content; (3 Pores in lacustrine shale are well developed when the organic matter maturity (Ro is >1.0% and the pore volume is positively correlated with the TOC (total organic carbon content. The statistical results suggest that oil in lacustrine shale mainly occurs in pores with diameters larger than 40 nm. However, more research is needed to determine whether this minimum pore diameter for oil occurrence in lacustrine shale is widely applicable.

  16. Source of sulphur in the Ebro Basin (Northern Spain). Tertiary nonmarine evaporite deposits as evidenced by sulphur isotopes

    International Nuclear Information System (INIS)

    Birnbaum, S.J.; Coleman, D.

    1979-01-01

    The Ebro Basin is an intermontane basin, located in northern Spain, filled with Tertiary (largely Oligocene and Miocene) elastic and chemical deposits. Sulphur isotopes are utilized to determine the source of sulphur in the sulphate deposits (predominantly gypsum with accessory thenardite, mirabolite and epsomite). Data obtained from Tertiary gypsum rocks produce a range of delta 34 S values from +9.16% to + 14.02% with a mean of +13.61%. Data obtained from Triassic gypsum rocks (in source area) produce a range from +13.73% to +15.14%, with a mean of +14.66%. Values for Tertiary marine water range from +18% to +24%. These data indicate a nonmarine origin for sulpur within the Tertiary sulphate rocks. The contribution of Triassic sulphur to the groundwater system, plus varying degrees of dilution by isotopically lighter (atmospheric and sulphide) sulphur, best explains the isotopic ratios observed in the Tertiary Basin deposits. (Auth.)

  17. Investigation of the radioactive and heavy metal pollution of the danube Delta lacustrine sediments and soil

    International Nuclear Information System (INIS)

    Dinescu, L.C.; Ciortea, C.; Fluerasu, D.; Stoica, P.; Duliu, O.G.; Stoica, P.

    2005-01-01

    Results obtained for five lacustrine sediment cores and three soil samples, collected in 1996 from Danube Delta, by using INAA, ICP-MS, and TTPIXE analytical methods, are presented. The measured vertical profiles identified as possible pollutants the following elements: Al, Cu, Zn, As, Ag, Cd, In, Sn, Sb, Hg, Tl, Pb, and Bi. In the sediment cores, the determined elements, except V and Ni, show near-surface enrichment relative to the lower part (1.3-3 enrichment factor, except 5 - 7 for Cd and Hg). In some few cases, As, Cd, Cu, Cr, Mn, and Pb exceeded the minimum threshold of safety defined by the Romanian legislation. For soil samples, increased (1.5-3 times) values at surface in comparison with the 30 cm depth was also found, but values much lower compared to lacustrine sediments, indicating the riverine transport as the main source of heavy-metal near-surface contamination of the lacustrine sediments

  18. Fluvial to Lacustrine Facies Transitions in Gale Crater, Mars

    Science.gov (United States)

    Sumner, Dawn Y.; Williams, Rebecca M. E.; Schieber, Juergen; Palucis, Marisa C.; Oehler, Dorothy Z.; Mangold, Nicolas; Kah, Linda C.; Gupta, Sanjeev; Grotzinger, John P.; Grant, John A., III; hide

    2015-01-01

    NASA's Curiosity rover has documented predominantly fluvial sedimentary rocks along its path from the landing site to the toe of the Peace Vallis alluvial fan (0.5 km to the east) and then along its 8 km traverse across Aeolis Palus to the base of Aeolis Mons (Mount Sharp). Lacustrine facies have been identified at the toe of the Peace Vallis fan and in the lowermost geological unit exposed on Aeolis Mons. These two depositional systems provide end members for martian fluvial/alluvial-lacustrine facies models. The Peace Vallis system consisted of an 80 square kilometers alluvial fan with decimeter-thick, laterally continuous fluvial sandstones with few sedimentary structures. The thin lacustrine unit associated with the fan is interpreted as deposited in a small lake associated with fan runoff. In contrast, fluvial facies exposed over most of Curiosity's traverse to Aeolis Mons consist of sandstones with common dune-scale cross stratification (including trough cross stratification), interbedded conglomerates, and rare paleochannels. Along the southwest portion of the traverse, sandstone facies include south-dipping meter-scale clinoforms that are interbedded with finer-grained mudstone facies, interpreted as lacustrine. Sedimentary structures in these deposits are consistent with deltaic deposits. Deltaic deposition is also suggested by the scale of fluvial to lacustrine facies transitions, which occur over greater than 100 m laterally and greater than 10 m vertically. The large scale of the transitions and the predicted thickness of lacustrine deposits based on orbital mapping require deposition in a substantial river-lake system over an extended interval of time. Thus, the lowermost, and oldest, sedimentary rocks in Gale Crater suggest the presence of substantial fluvial flow into a long-lived lake. In contrast, the Peace Vallis alluvial fan onlaps these older deposits and overlies a major unconformity. It is one of the youngest deposits in the crater, and

  19. Molecular biomarkers for sources of organic matter in lacustrine sediments in a subtropical lake in China.

    Science.gov (United States)

    Wang, Yan-Hua; Yang, Hao; Chen, Xia; Zhang, Ji-Xiang; Ou, Jie; Xie, Biao; Huang, Chang-Chun

    2013-05-01

    N-alkanes distributions and stable isotopic compositions (δ(13)C and δ(15)N) in the lacustrine sediments of Shijiu lake were measured to assess whether biological source information was recorded in the molecular biomarker. Results showed regular unimodal n-alkanes distribution in range of C16-C33 with strong predominance of odd-numbered n-alkanes, maximizing at C29. The δ(15)N for SON were uniformly low, ranging from -6.7‰ to 3.8‰ and C/N ratios ranged from 6.6 to 10.0, suggesting that most of organic matter was influenced by terrestrial characteristics of the watershed. The δ(13)C for C27 to C31n-alkanes and for SOC varied from -32.9‰ to -26.6‰ and -23.4‰ to -21.6‰, respectively, falling within the range of corresponding n-alkanes in leaves mainly from C3 land plants. The values of C/N, CPI, OEP, ACL and C27/C31 exhibit similar temporal changes with the primary production, showing enhanced eutrophication resulted from increased anthropogenic activities in Shijiu lake from 1852 to 2010. Copyright © 2013 Elsevier Ltd. All rights reserved.

  20. Chapter D: With or Without Salt-a Comparison of Marine and Continental-Lacustrine Diatomite Deposits

    Science.gov (United States)

    Moyle, Phillip R.; Dolley, Thomas P.

    2003-01-01

    Diatoms in sedimentary deposits of marine and continental, especially lacustrine, origin have similar nutrient (for example, phosphate, nitrate, and silica) and light requirements; however, their geologic ranges and physiographic environments vary. Marine diatoms range in age from Early Cretaceous to Holocene, and continental diatoms range in age from Eocene to Holocene; however, most commercial diatomites, both marine and lacustrine, were deposited during the Miocene. Marine deposits of commercial value generally accumulated along continental margins with submerged coastal basins and shelves where wind-driven boundary currents provided the nutrient-rich upwelling conditions capable of supporting a productive diatom habitat. Commercial freshwater diatomite deposits occur in volcanic terrains associated with events that formed sediment-starved drainage basins, such as the Basin and Range Province, particularly in Nevada. Marine habitats generally are characterized by stable conditions of temperature, salinity, pH, nutrients, and water currents, in contrast to lacustrine habitats, which are characterized by wide variations in these conditions. Marine deposits generally are of higher quality and contain larger resources, owing to their greater areal extent and thickness, whereas most of the world's known diatomites are of lacustrine origin. Both types of deposit are commonly mined by open-pit methods and subjected to processing designed to remove organic matter, CO2, pore water, and inorganic contaminants in order to produce purified products. The highest quality diatomites, predominantly from marine sources, are used in filtration, although both types of deposit produce filter grades, and additional end uses include fillers, additives, absorbents, and abrasives.

  1. Regional paleohydrologic and paleoclimatic settings of wetland/lacustrine depositional systems in the Morrison Formation (Upper Jurassic), Western Interior, USA

    Science.gov (United States)

    Dunagan, S.P.; Turner, C.E.

    2004-01-01

    During deposition of the Upper Jurassic Morrison Formation, water that originated as precipitation in uplands to the west of the Western Interior depositional basin infiltrated regional aquifers that underlay the basin. This regional groundwater system delivered water into the otherwise dry continental interior basin where it discharged to form two major wetland/lacustrine successions. A freshwater carbonate wetland/lacustrine succession formed in the distal reaches of the basin, where regional groundwater discharged into the Denver-Julesburg Basin, which was a smaller structural basin within the more extensive Western Interior depositional basin. An alkaline-saline wetland/lacustrine complex (Lake T'oo'dichi') formed farther upstream, where shallower aquifers discharged into the San Juan/Paradox Basin, which was another small structural basin in the Western Interior depositional basin. These were both wetlands in the sense that groundwater was the major source of water. Input from surface and meteoric water was limited. In both basins, lacustrine conditions developed during episodes of increased input of surface water. Inclusion of wetlands in our interpretation of what had previously been considered largely lacustrine systems has important implications for paleohydrology and paleoclimatology. The distal carbonate wetland/lacustrine deposits are well developed in the Morrison Formation of east-central Colorado, occupying a stratigraphic interval that is equivalent to the "lower" Morrison but extends into the "upper" Morrison Formation. Sedimentologic, paleontologic, and isotopic evidence indicate that regional groundwater discharge maintained shallow, hydrologically open, well oxygenated, perennial carbonate wetlands and lakes despite the semi-arid climate. Wetland deposits include charophyte-rich wackestone and green mudstone. Lacustrine episodes, in which surface water input was significant, were times of carbonate and siliciclastic deposition in scarce deltaic

  2. Metal complexation capacity of Antarctic lacustrine sediments.

    Science.gov (United States)

    Alberti, Giancarla; Mussi, Matteo; Quattrini, Federico; Pesavento, Maria; Biesuz, Raffaela

    2018-04-01

    The purpose of this study is to implement a work that is a part of a project funded by the Italian National Antarctic Research Program (PNRA, Piano Nazionale di Ricerche in Antartide) within the main thematic focus "Chemical Contamination-Global Change". This research was devoted to detect and characterize micro and nano components with strong complexing capability towards metal ions at trace level in sea water, lakes and lacustrine sediments, sampled during the XXII expedition of PNRA. In particular, in the present work, the sorption complexation capacity of an Antarctic lacustrine sediments toward Cu(II) and Pb(II) is described. The characterization of the sorption was undertaken, studying kinetics and isotherm profiles. The lake here considered is Tarn Flat in the area of Terra Nova Bay. The sorption equilibria of Cu(II) and Pb(II) on the lacustrine sediments were reached in about 10 h, and they were best modelled by the Langmuir equation. Preliminary, to establish if the data here obtained were consistent with those reported for the same area in other expeditions, a common multivariate techniques, namely the principal component analysis (PCA), was applied and finally the consistency of the data has been confirmed. Copyright © 2018 Elsevier Ltd. All rights reserved.

  3. Drowning unconformity of lacustrine rift basins: A case study from the Dongying Sag in Bohai Bay Basin, China

    Science.gov (United States)

    Chen, R.; Fan, J.

    2015-12-01

    The concept of drowning unconformity of lacustrine rift basins was proposed in this paper. This paper utilized 3D seismic data, well-log and the principles methods associated with structural geology, sedimentology and geochemistry, to analyze the drowning unconformity and discuss the origins of drowning unconformity in Dongying Sag in Bohai Bay Basin.Researching on it is not only important for a better understanding of tectonic evolution, palaeogeography and sedimentation of hydrocarbon source rocks, but also a vital guiding significance for the exploration of beach-bar sandstone reservoirs and shale oil.1. The concept of drowning unconformity of lacustrine rift basins is defined. With the consequences of rapid tectonic subsidence in basin, the sharp rise of lake-level and the increased rate of accommodation(A) in basin exceeded the rate of sediment supply(S),namely A>>S, the basin suddenly transformed into deep-water settings from shallow-water settings with sudden change of sediment transport and sediment dispersal patterns. 2.The sequence surface between Sha4 and Sha3 Member of Shahejie Formation is the drowning unconformity(43.5Ma). There are the sedimentary association of the reefs in shallow lacustrine, beach-bar sandstones and glutenite fan bodies under the surface. By contrast, there are the sedimentary association of deep-lake oil shales and shales over the surface. The drowning unconformity in Dongying Sag is a tectonic revolution surface which is changed from extensional tectonics to transtensional tectonics and it is also the surface of discontinuity from shallow lacustrine to deep lacustrine. The responses to sudden changes appeared in the parameters of geophysics, geochemistry and paleontology. 3. With the penetration of India into Asia plate in NNE trending,the subduction zones of Pacific Plate retreated. It caused the rapid downwelling of asthenospheric mantle, followed by the extensive drowning unconformity.

  4. Geochemical characteristics of Holocene laminated sapropel (unit II) and underlying lacustrine unit III in the Black Sea

    Science.gov (United States)

    Dean, Walter E.; Arthur, Michael A.

    2011-01-01

    eg 1 of the 1988 R/V Knorr expeditions to the Black Sea recovered 90 gravity and box cores. The longest recovery by gravity cores was about 3 meters, with an average of about 2.5 meters, recovering all of the Holocene and upper Pleistocene sections in the Black Sea. During the latest Pleistocene glaciation, sea level dropped below the 35-meters-deep Bosporus outlet sill of the Black Sea. Therefore throughout most of its history the Black Sea was a lake, and most of its sediments are lacustrine. The oldest sediments recovered (older than 8,000 calendar years) consist of massive to coarsely banded lacustrine calcareous clay designated as lithologic Unit III, generally containing less than 1 percent organic carbon (OC). The base of overlying Unit II marks the first incursion of Mediterranean seawater into the Black Sea, and the onset of bottom-water anoxia about 7,900 calendar years. Unit II contains as much as 15 percent OC in cores from the deepest part of the Black Sea (2,200 meters). The calcium carbonate (CaCO3) remains of the coccolith Emiliania huxleyi form the distinctive white laminae of overlying Unit I. The composition of Unit III and Unit II sediments are quite different, reflecting different terrigenous clastic sources and increased contributions from hydrogenous and biogenic components in anoxic Unit II sapropel. In Unit II, positive covariance between OC and three trace elements commonly concentrated in OC-rich sediments where sulfate reduction has occurred (molybdenum, nickel, and vanadium) and a nutrient (phosphorus) suggest a large marine source for these elements although nickel and vanadium also have a large terrigenous clastic source. The marine sources may be biogenic or hydrogenous. A large biogenic source is also suggested for copper and cobalt. Because abundant pyrite forms in the water column and sediments of the Black Sea, we expected to find a large hydrogenous iron component, but a strong covariance of iron with aluminum suggests that the

  5. Index to Marine and Lacustrine Geological Samples (IMLGS)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The Index to Marine and Lacustrine Geological Samples (IMLGS) describes and provides access to ocean floor and lakebed rock and sediment samples curated by...

  6. Sulfur Geochemistry of a Lacustrine Record from Taiwan Reveals Enhanced Marine Aerosol Input during the Early Holocene.

    Science.gov (United States)

    Ding, Xiaodong; Li, Dawei; Zheng, Liwei; Bao, Hongyan; Chen, Huei-Fen; Kao, Shuh-Ji

    2016-12-12

    Lacustrine record of marine aerosol input has rarely been documented. Here, we present the sulfur geochemistry during the last deglaciation and early Holocene of a sediment core retrieved from the Dongyuan Lake in southern Taiwan. An unusually high sulfur peak accompanying pyrite presence is observed at 10.5 ka BP. Such high sulfur content in lacustrine record is unusual. The δ 34 S of sulfur varied from +9.5 to + 17.1‰ with two significant positive shifts at 10.5 and 9.4 ka BP. The sources of sulfur and potential processes involving the sulfur isotope variation including bacterial sulfate reduction, volcanic emissions, in-catchment sulfide oxidation and marine aerosol input are discussed. Enhanced marine aerosol input is the most likely explanation for such sulfur peaks and δ 34 S shifts. The positive δ 34 S shifts appeared concurrently with the maximum landslide events over Taiwan resulted from enhanced typhoon activities. The synchronicity among records suggests that increased typhoon activities promoted sea spray, and consequently enhanced the marine aerosol input with 34 S-enriched sulfate. Our sulfur geochemistry data revealed sea spray history and marine influence onto terrestrial environment at coastal regions. Wider coverage of spatial-temporal lacustrine sulfur geochemistry record is needed to validate the applicability of sulfur proxy in paleoenvironmental research.

  7. Predominance of even carbon-numbered n-alkanes from lacustrine sediments in Linxia Basin, NE Tibetan Plateau: Implications for climate change

    International Nuclear Information System (INIS)

    Wang Yongli; Fang Xiaomin; Zhang Tongwei; Li Yuanmao; Wu Yingqin; He Daxiang; Wang Youxiao

    2010-01-01

    Research highlights: → This study reports the first observation of predominant even carbon-numbered n-alkanes of sediments in the continuous lacustrine-sedimentary section (Maogou) from the Late Miocene to the Early Pliocene (13-4.4 Ma) in the Linxia Basin, NE Tibetan Plateau. → Certain types of special autochthonous bacteria are a possible source for the special distribution of even carbon-numbered n-alkanes in lacustrine sediments. → These bacteria may have a high production rate in weak oxic-anoxic and arid depositional environments, in which a variety of geochemical parameters have recorded palaeoclimate change. → A close correspondence among the low ratio of n-C 27 /n-C 31 , the heavy δ 13 C values of TOC and a strong even carbon-number predominance (low OEP 16-20 values) from approximately 6.5 to 4.4 Ma and at approximately 8 Ma in the studied section suggests that n-alkanes with a high predominance of even carbon-numbers may be treated as geochemical proxies for arid climate. - Abstract: This study reports the first observation of predominant even C-numbered n-alkanes from sediments in the continuous lacustrine-sedimentary section (Maogou) from the Late Miocene to the Early Pliocene (13-4.4 Ma) in the Linxia Basin, NE Tibetan Plateau. The n-alkanes showed a bimodal distribution that is characterised by a centre at n-C 16 -n-C 20 with maximum values at n-C 18 and n-C 27 -n-C 31 as well as at n-C 29 . The first mode shows a strong even C-number predominance (OEP 16-20 0.34-0.66). In contrast, the second mode has a strong odd C-number predominance (OEP 27-31 1.20-2.45). Certain types of special autochthonous bacteria are a possible source for this distribution of even C-numbered n-alkanes in lacustrine sediments. These bacteria may have a high production rate in weak oxic-anoxic and arid depositional environments, in which a variety of geochemical parameters have recorded palaeoclimate change.

  8. Deformation of ``Villafranchian'' lacustrine sediments in the Chisone Valley (Western Alps, Italy)

    Science.gov (United States)

    Collo, Giovanni; Giardino, Marco

    1997-09-01

    The Chisone Valley is located in the internal NW Alps, in the Pinerolese District, an area characterized by present low to medium seismicity. Fine-grained sediments (sand, silt and clay with interbedded gravel) crop out in the lower Chisone Valley: they were first interpreted as glaciolacustrine deposits, and then as a lacustrine infilling of the valley floor probably due to differential uplifting of the valley mouth. Review of this data, together with new field and palynological observations, lead us to refer the lacustrine deposits to approximately the Lower Pleistocene (Villafranchian). In many outcrops, the lacustrine deposits show strong soft-sediment deformation such as convolute laminations, water-escape structures and disrupted beds, some of them associated with folds and faults (cm to dm in size); only two sites show metric to decametric folds and faults trending E-W and N-S. Detailed structural analysis conducted along a recently exposed section (Rio Gran Dubbione site) shows several soft-sediment deformation features on the limbs of mesoscale folds. Because of their intimate structural association, the origin of these minor structures seems to be connected to synsedimentary activity on reverse and normal faults (m to dm in size) affecting the lacustrine deposits in the same locality. Soft-sediment deformation features can be interpreted as possible paleoseismites. If so, the present seismicity of the Pinerolese District, which is the major area of such activity in NW Italy, cannot be considered an isolated episode in the geological evolution of the region; even if there is no supporting evidence for continuous seismicity, the deformations in the lacustrine sediments of the Chisone Valley testify to Early Pleistocene seismic activity, probably related to the recent tectonic evolution of the internal side of the NW Alps.

  9. Mapping sediment–landform assemblages to constrain lacustrine sedimentation in a glacier-fed lake catchment in northwest Spitsbergen

    OpenAIRE

    Bilt, Willem van der; Balascio, Nicholas L.; Bakke, Jostein

    2015-01-01

    Changes in the deposition of fine-grained rock-flour in glacier-fed lakes reflect glacier variability. This meltwater-driven signal is, however, often overprinted by other processes. To constrain the signature of lacustrine sedimentation, we mapped the catchment of glacier-fed Lake Hajeren in northwest Spitsbergen, identifying sediment sources and linking them to surface processes. To this end, we employed a combined approach of aerial image interpretation and field mapping. Our map comprises...

  10. Archive of Geosample Data and Information from the University of Minnesota National Lacustrine Core Repository (LacCore)

    Data.gov (United States)

    National Oceanic and Atmospheric Administration, Department of Commerce — The National Lacustrine Core Repository (LacCore), operated by the University of Minnesota is a partner in the Index to Marine and Lacustrine Geological Samples...

  11. Development and Rainfed Paddy Soils Potency Derived From Lacustrine Material in Paguyaman, Gorontalo

    OpenAIRE

    Nurdin

    2011-01-01

    Rainfed paddy soils that are derived from lacustrine and include of E4 agroclimatic zone have many unique properties and potentially for paddy and corn plantations. This sreseach was aimed to: (1) study the soil development of rainfed paddy soils derived from lacustrine and (2) evaluate rainfed paddy soils potency for paddy and corn in Paguyaman. Soil samples were taken from three profiles according to toposequent, and they were analyzed in laboratory. Data were analyzed with descripti...

  12. Organic petrological and organic geochemical characterisation of the Tertiary coal-bearing sequence of Batu Arang, Selangor, Malaysia

    Science.gov (United States)

    Wan Hasiah, Abdullah; Abolins, Peter

    1998-08-01

    The Tertiary coal-bearing sequence at Batu Arang in Selangor, Peninsular Malaysia consists of a sandstone-coal-oil shale facies assemblage. A detailed organic petrological and organic geochemical study was carried out on several organic-rich sediments from this sequence. The oil shales are dominated by Botryococcus-derived telalginite and Pediastrum-derived lamalginite. The coals, hypautochthonous in origin, are mainly duroclarite-type, although other minor microlithotypes also occur. Alginite is not observed in the coals, but other liptinitic constituents are very common, particularly thin-walled cutinite and sporinite. The oil shales and the coals are thermally immature. This immaturity has a considerable influence on the biomarker distributions, particularly so on the triterpanes which are dominated by C 31αβ 22R and C 30ββ compounds. Interestingly, for Tertiary aged sediments of continental origin, the diagnostic biomarker compounds such as 18 α(H)-oleanane and bicadinanes, normally linked to the higher land plant group of angiosperms, are not observed in the samples analysed. Tricyclic terpanes occur only in very low relative abundance or are virtually absent. A clear distinction, however, in the biomarker distributions of the shales and the coals/carbargilite can be made based upon the distribution of C 27-C 29 regular steranes: the shales, with a source input being predominantly planktonic algae, are dominated by 5 α(H),14 α(H),17 α(H) 20R cholestane, while the coals/carbargilites, with a source input consisting mainly of higher plant material, are dominated by 5 α(H),14 α(H),17 α(H) 20R ethyl cholestane. The depositional environment of the Batu Arang coal-bearing sequence is interpreted as varying from an alluvial flood plain peat-swamp to fluvio-lacustrine depositional setting.

  13. Predominance of even carbon-numbered n-alkanes from lacustrine sediments in Linxia Basin, NE Tibetan Plateau: Implications for climate change

    Energy Technology Data Exchange (ETDEWEB)

    Wang Yongli [Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 730000 (China)] [Institute of Tibetan and Plateau Research, Chinese Academy of Sciences, Beijing 100085 (China); Fang Xiaomin, E-mail: fangxm@itpcas.ac.cn [Institute of Tibetan and Plateau Research, Chinese Academy of Sciences, Beijing 100085 (China)] [Key Laboratory of Western Resources and Environment of Education Ministry, College at Earth and Environment Sciences, University of Lanzhou, Lanzhou 730000 (China); Zhang Tongwei [Key Laboratory of Western Resources and Environment of Education Ministry, College at Earth and Environment Sciences, University of Lanzhou, Lanzhou 730000 (China); Li Yuanmao; Wu Yingqin; He Daxiang; Wang Youxiao [Key Laboratory of Petroleum Resources Research, Institute of Geology and Geophysics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2010-10-15

    Research highlights: {yields} This study reports the first observation of predominant even carbon-numbered n-alkanes of sediments in the continuous lacustrine-sedimentary section (Maogou) from the Late Miocene to the Early Pliocene (13-4.4 Ma) in the Linxia Basin, NE Tibetan Plateau. {yields} Certain types of special autochthonous bacteria are a possible source for the special distribution of even carbon-numbered n-alkanes in lacustrine sediments. {yields} These bacteria may have a high production rate in weak oxic-anoxic and arid depositional environments, in which a variety of geochemical parameters have recorded palaeoclimate change. {yields} A close correspondence among the low ratio of n-C{sub 27}/n-C{sub 31}, the heavy {delta}{sup 13}C values of TOC and a strong even carbon-number predominance (low OEP{sub 16-20} values) from approximately 6.5 to 4.4 Ma and at approximately 8 Ma in the studied section suggests that n-alkanes with a high predominance of even carbon-numbers may be treated as geochemical proxies for arid climate. - Abstract: This study reports the first observation of predominant even C-numbered n-alkanes from sediments in the continuous lacustrine-sedimentary section (Maogou) from the Late Miocene to the Early Pliocene (13-4.4 Ma) in the Linxia Basin, NE Tibetan Plateau. The n-alkanes showed a bimodal distribution that is characterised by a centre at n-C{sub 16}-n-C{sub 20} with maximum values at n-C{sub 18} and n-C{sub 27}-n-C{sub 31} as well as at n-C{sub 29}. The first mode shows a strong even C-number predominance (OEP{sub 16-20} 0.34-0.66). In contrast, the second mode has a strong odd C-number predominance (OEP{sub 27-31} 1.20-2.45). Certain types of special autochthonous bacteria are a possible source for this distribution of even C-numbered n-alkanes in lacustrine sediments. These bacteria may have a high production rate in weak oxic-anoxic and arid depositional environments, in which a variety of geochemical parameters have recorded

  14. Large Scale Cooling in Tertiary Central Europe as inferred by the MBT/CBT Paleothermometer

    Science.gov (United States)

    Bauersachs, T.; Schouten, S.; Schwark, L.

    2011-12-01

    Earth's climate experienced dramatic changes throughout the last 65 Ma. Starting at the Paleocene/Eocene thermal maximum, the global climate underwent a gradual cooling that eventually resulted in the glaciations in the Neogene. Most reconstructions of climate variability are derived from the marine realm using global deep sea oxygen isotope curves or molecular paleotemperature proxies. In contrast, only little information on the changes of the continental climate is available, which is mainly due to a lack of continuous high resolution records and suitable quantitative temperature proxies. The MBT/CBT paleothermometer is a novel temperature proxy based on temperature-driven changes in the branched glycerol dialkyl glycerol tetraether (GDGT) content of soil-living bacteria. These changes have been demonstrated to correlate well with ambient air temperature and the MBT/CBT proxy has thus been used to reconstruct paleotemperature records of terrestrial as well as coastal marine sediments (1). In this study, we employed the MBT/CBT paleothermometer on a number of maar lake deposits that - due to their exceptional well preserved organic matter content and finely-laminated sediments - comprise excellent archives of a continental climate. The analysed lacustrine deposits were all situated in the middle European Tertiary volcanic belt and ranged in age from the Early Eocene to the Late Oligocene, allowing for the detailed reconstruction of climate evolution of the Central European continent. Calculated mean annual air temperatures (MAAT) of the Messel oil shale, deposited during the Eocene climate optimum, averaged at 25 °C. This agrees well with previous temperature estimates based on paleontological observations, suggesting a paratropical climate in Eocene Central Europe with an average air temperature of ca. 25-30 °C (2). In contrast, to the green house period of the Early Eocene, the climate of the Oligocene was significantly cooler reflected by low MAAT of 8-15

  15. Survey on the consumptions of energy sources in the tertiary sector in Italy in 1999

    International Nuclear Information System (INIS)

    Iorio, G.; Perrella, G.; Ballin, M.

    2001-01-01

    This report has the aim to introduce the results of the sampling survey performed to determinate the consumption of energy sources (electricity, natural gas, fuel oil, diesel oil, etc.) in the tertiary sector. The energy consumptions report to 1999 and they are disaggregated for typology of use: energy consumptions for productive uses, for production of energy and for traction. The economic energy intensive activities have represented the nucleus of the survey. Particular attention has been devoted to the production of energy and the consumption of heat [it

  16. Paleoclimate cycles and tectonic controls on fluvial, lacustrine, and eolian strata in upper Triassic Chinle Formation, San Juan basin

    Energy Technology Data Exchange (ETDEWEB)

    Dubiel, R.F. (Geological Survey, Denver, CO (USA))

    1989-09-01

    Sedimentologic study of the Upper Triassic Chinle Formation in the San Juan basin (SJB) indicates that Late Triassic paleoclimate and tectonic movements influenced the distribution of continental lithofacies. The Shinarump, Monitor Butte, and Petrified Forest Members in the lower part of the Chinle consist of complexly interfingered fluvial, floodplain, marsh, and lacustrine rocks; the Owl Rock and Rock Point Members in the upper part consists of lacustrine-basin and eolian sandsheet strata. Facies analysis, vertebrate and invertebrate paleontology, and paleoclimate models demonstrate that the Late Triassic was dominated by tropical monsoonal circulation, which provided abundant precipitation interspersed with seasonally dry periods. Owl Rock lacustrine strata comprise laminated limestones that reflect seasonal monsoonal precipitation and larger scale, interbedded carbonates and fine-grained clastics that represent longer term, alternating wet and dry climatic cycles. Overlying Rock Point eolian sand-sheet and dune deposits indicate persistent alternating but drier climatic cyclicity. Within the Chinle, upward succession of lacustrine, alternating lacustrine/eolian sand-sheet, and eolian sand-sheet/dune deposits reflects an overall decrease in precipitation due to the northward migration of Pangaea out of low latitudes dominated by monsoonal circulation.

  17. STRATIGRAPHIC EVOLUTION, PALEOENVIRONMENTS AND HYDROCARBON POTENTIALS OF THE BENUE/DAHOMEY BASINS, NIGERIAN AND POTIGUAR/CEARA BASINS, NE BRAZIL

    International Nuclear Information System (INIS)

    Akande, S.O; Adekeye, O.A.; Oj, O.J; Erdtmann, B.D.; Koutsokous, E.I.

    2004-01-01

    The stratigraphy, facies relationship and paleoenvironment of selected West African and the Brazillian rift basins permit the recognition of at least two major petroleum systems apart from the prolific Niger Delta petroleum system. The Lower Cretaceous fluivio-lacustrine petroleum system and Upper Cretaceous to Lower Tertiary, marine dominated petroleum system. Our combined studies of the stratigraphic, structural framework, paleoenvironment and time-space relationships of the petroleum systems in the Benue/Dahomey and the Potiguar/Ceara basins indicated that rifting and subsequent drifting during the opening of the South Atlantic controlled subsidence, sediment deposition and facies associations in individual basins. Whereas in the Potiguar/Ceara basins, the best developed source rocks are within the Neomacin-Aptian fluvio- lacustrine sequence of the Pendencia and Alagamar Formations which generated reserved hydrocarbon in the Acu Formation, empirical evidence for this petroleum system in the contiguous Benue/Dahomey basins are only based on the geochemical characteristics of the lower parts of the Bima Formation and the Abeokuta Group. In contrast, the Upper Cretaceous-Lower Tertiary marine petroleum system, which is constrained by poor development of reservoirs in the Potiguar/Ceara basin is productive in the Benue/Dahomey basins where source rocks, reservoir and sealing facies occur at this interval. Considering the recent hydrocarbon discoveries of the East Niger basin, the Doba (southern Chad), the Muglad basin (southern Sudan) sourced from the fluvio-lacustrine rift sequences, we suggest that this petroleum system needs more detailed exploration and has some potentials in the Benue/Dahomey frontier basins

  18. Petrophysical characterization of the lacustrine sediment succession drilled in Lake El'gygytgyn, Far East Russian Arctic

    Directory of Open Access Journals (Sweden)

    A. C. Gebhardt

    2013-08-01

    Full Text Available Seismic profiles of Far East Russian Lake El'gygytgyn, formed by a meteorite impact some 3.6 million years ago, show a stratified sediment succession that can be separated into subunits Ia and Ib at approximately 167 m below lake floor (=~3.17 Ma. The upper (Ia is well-stratified, while the lower is acoustically more massive and discontinuous. The sediments are intercalated with frequent mass movement deposits mainly in the proximal areas, while the distal region is almost free of such deposits at least in the upper part. In spring 2009, a long core drilled in the lake center within the framework of the International Continental Scientific Drilling Program (ICDP penetrated the entire lacustrine sediment succession down to ~320 m below lake floor and about 200 m farther into the meteorite-impact-related bedrock. Downhole logging data down to 390 m below lake floor show that the bedrock and the lacustrine part differ significantly in their petrophysical characteristics. The contact between the bedrock and the lacustrine sediments is not abrupt, but rather transitional with a variable mixture of impact-altered bedrock clasts in a lacustrine matrix. Physical and chemical proxies measured on the cores can be used to divide the lacustrine part into five different statistical clusters. These can be plotted in a redox-condition vs. input-type diagram, with total organic carbon content and magnetic susceptibility values indicating anoxic or oxic conditions and with the Si / Ti ratio representing more clastic or more biogenic input. Plotting the clusters in this diagram allows identifying clusters that represent glacial phases (cluster I, super interglacials (cluster II, and interglacial phases (clusters III and IV.

  19. Lacustrine Environment Reservoir Properties on Sandstone Minerals and Hydrocarbon Content: A Case Study on Doba Basin, Southern Chad

    Science.gov (United States)

    Sumery, N. F. Mohd; Lo, S. Z.; Salim, A. M. A.

    2017-10-01

    The contribution of lacustrine environment as the hydrocarbon reservoir has been widely known. However, despite its growing importance, the lacustrine petroleum geology has received far less attention than marine due to its sedimentological complexity. This study therefore aims in developing an understanding of the unique aspects of lacustrine reservoirs which eventually impacts the future exploration decisions. Hydrocarbon production in Doba Basin, particularly the northern boundary, for instance, has not yet succeeded due to the unawareness of its depositional environment. The drilling results show that the problems were due to the: radioactive sand and waxy oil/formation damage, which all are related to the lacustrine depositional environment. Detailed study of geological and petrophysical integration on wireline logs and petrographic thin sections analysis of this environment helps in distinguishing reservoir and non-reservoir areas and determining the possible mechanism causing the failed DST results. The interpretations show that the correlation of all types> of logs and rho matrix analysis are capable in identifying sand and shale bed despite of the radioactive sand present. The failure of DST results were due to the presence of arkose in sand and waxy oil in reservoir bed. This had been confirmed by the petrographic thin section analysis where the arkose has mineral twinning effect indicate feldspar and waxy oil showing bright colour under fluorescent light. Understanding these special lacustrine environment characteristics and features will lead to a better interpretation of hydrocarbon prospectivity for future exploration.

  20. Highly calcareous lacustrine soils in the Great Konya Basin, Turkey

    NARCIS (Netherlands)

    Meester, de T.

    1971-01-01

    The Great Konya Basin is in the south of the Central Anatolian Plateau in Turkey. It is a depression without outlet to the sea. The central part of the Basin is the floor of a former Pleistocene lake, the Ancient Konya Lake. This area, called the Lacustrine
    Plain, has highly calcareous

  1. Small-scale lacustrine drifts in Lake Champlain, Vermont

    Science.gov (United States)

    Manley, Patricia L.; Manley, T.O.; Hayo, Kathryn; Cronin, Thomas

    2012-01-01

    High resolution CHIRP (Compressed High Intensity Radar Pulse) seismic profiles reveal the presence of two lacustrine sediment drifts located in Lake Champlain's Juniper Deep. Both drifts are positive features composed of highly laminated sediments. Drift B sits on a basement high while Drift A is built on a trough-filling acoustically-transparent sediment unit inferred to be a mass-transport event. These drifts are oriented approximately north–south and are parallel to a steep ridge along the eastern shore of the basin. Drift A, located at the bottom of a structural trough, is classified as a confined, elongate drift that transitions northward to become a system of upslope asymmetric mudwaves. Drift B is perched atop a structural high to the west of Drift A and is classified as a detached elongate drift. Bottom current depositional control was investigated using Acoustic Doppler Current Profilers (ADCPs) located across Drift A. Sediment cores were taken at the crest and at the edges of the Drift A and were dated. Drift source, deposition, and evolution show that these drifts are formed by a water column shear with the highest deposition occurring along its crest and western flank and began developing circa 8700–8800 year BP.

  2. AMS radiocarbon dating of lacustrine sediment from an impact crater in northeastern China

    Energy Technology Data Exchange (ETDEWEB)

    Liu, K.X. [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Chen, M., E-mail: mchen@gig.ac.cn [Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Ding, X.F.; Fu, D.P. [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Ding, P. [State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Shen, C.D., E-mail: cdshen@gig.ac.cn [State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China); Xiao, W.S. [Key Laboratory of Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, 510640 Guangzhou (China)

    2013-01-15

    In order to investigate the origin and age of a bowl-shaped crater with 1.8 km diameter in northeastern China, a core drilling about 110 m in total was carried out in 2009 at the center of the crater. A 106-m-thick unit of lacustrine sediment is revealed under a surface layer of about 1 m of yellow soil. The impact origin has been confirmed based on geological analysis. In this paper, we report the AMS {sup 14}C dating results of lacustrine sediment. The data suggest that the meteorite impact in Xiuyan happened more than 50,000 years ago and a two-section linear relationship of {sup 14}C ages with the depth shows a stable sediment environment through the two time stages.

  3. The Upper Jurassic Stanleyville Group of the eastern Congo Basin: An example of perennial lacustrine system

    Science.gov (United States)

    Caillaud, Alexis; Blanpied, Christian; Delvaux, Damien

    2017-08-01

    The intracratonic Congo Basin, located in the Democratic Republic of Congo (DRC), is the largest sedimentary basin of Africa. The Jurassic strata outcrop along its eastern margin, south of Kisangani (formerly Stanleyville). In the last century, the Upper Jurassic Stanleyville Group was described as a lacustrine series containing a thin basal marine limestone designed as the ;Lime Fine; beds. Since the proposal of this early model, the depositional environment of the Stanleyville Group, and especially the possible marine incursion, has been debated, but without re-examining the existing cores, outcrop samples and historical fossils from the type location near Kisangani that are available at the Royal Museum for Central Africa (MRAC/KMMA, Tervuren, Belgium). In order to refine the former sedimentology, a series of nine exploration cores drilled in the Kisangani sub-basin have been described. This study aims at integrating sedimentary facies in existing sedimentary models and to discuss the hypothesis of the presence of Kimmeridgian marine deposits along the Congo River near Kisangani, a region which lies in the middle of the African continent. Eight facies have been identified, which permit a reinterpretation of the depositional environment and paleogeography of the Stanleyville Group. The base of the Stanleyville Group is interpreted to represent a conglomeratic fluvial succession, which filled an inherited Triassic paleotopography. Above these conglomerates, a transition to a typically lacustrine system is interpreted, which includes: (1) a basal profundal, sublittoral (brown to dark fine-grained siltstones with microbial carbonates, i.e., the ;Lime Fine; beds) and littoral lacustrine series; covered by (2) a sublittoral to profundal interval (brown to dark organic-rich, fine-grained siltstones), which corresponds to the maximum extent of the paleo-lake; and, finally (3) a shallow lacustrine series (greenish calcareous siltstones and sandstones with red siltstones

  4. Volcanogenic Fluvial-Lacustrine Environments in Iceland and Their Utility for Identifying Past Habitability on Mars

    Directory of Open Access Journals (Sweden)

    Claire Cousins

    2015-02-01

    Full Text Available The search for once-habitable locations on Mars is increasingly focused on environments dominated by fluvial and lacustrine processes, such as those investigated by the Mars Science Laboratory Curiosity rover. The availability of liquid water coupled with the potential longevity of such systems renders these localities prime targets for the future exploration of Martian biosignatures. Fluvial-lacustrine environments associated with basaltic volcanism are highly relevant to Mars, but their terrestrial counterparts have been largely overlooked as a field analogue. Such environments are common in Iceland, where basaltic volcanism interacts with glacial ice and surface snow to produce large volumes of meltwater within an otherwise cold and dry environment. This meltwater can be stored to create subglacial, englacial, and proglacial lakes, or be released as catastrophic floods and proglacial fluvial systems. Sedimentary deposits produced by the resulting fluvial-lacustrine activity are extensive, with lithologies dominated by basaltic minerals, low-temperature alteration assemblages (e.g., smectite clays, calcite, and amorphous, poorly crystalline phases (basaltic glass, palagonite, nanophase iron oxides. This paper reviews examples of these environments, including their sedimentary deposits and microbiology, within the context of utilising these localities for future Mars analogue studies and instrument testing.

  5. Volcanogenic fluvial-lacustrine environments in iceland and their utility for identifying past habitability on Mars.

    Science.gov (United States)

    Cousins, Claire

    2015-02-16

    The search for once-habitable locations on Mars is increasingly focused on environments dominated by fluvial and lacustrine processes, such as those investigated by the Mars Science Laboratory Curiosity rover. The availability of liquid water coupled with the potential longevity of such systems renders these localities prime targets for the future exploration of Martian biosignatures. Fluvial-lacustrine environments associated with basaltic volcanism are highly relevant to Mars, but their terrestrial counterparts have been largely overlooked as a field analogue. Such environments are common in Iceland, where basaltic volcanism interacts with glacial ice and surface snow to produce large volumes of meltwater within an otherwise cold and dry environment. This meltwater can be stored to create subglacial, englacial, and proglacial lakes, or be released as catastrophic floods and proglacial fluvial systems. Sedimentary deposits produced by the resulting fluvial-lacustrine activity are extensive, with lithologies dominated by basaltic minerals, low-temperature alteration assemblages (e.g., smectite clays, calcite), and amorphous, poorly crystalline phases (basaltic glass, palagonite, nanophase iron oxides). This paper reviews examples of these environments, including their sedimentary deposits and microbiology, within the context of utilising these localities for future Mars analogue studies and instrument testing.

  6. Sedimentary basin analysis and petroleum potential of the Cretaceous and Tertiary strata in Korea.

    Energy Technology Data Exchange (ETDEWEB)

    Son, Jin-Dam; Kwak, Young-Hoon; Bong, Pil-Yoon [Korea Institute of Geology Mining and Materials, Taejon (KR)] (and others)

    1999-12-01

    Since 1992 sedimentary basin analysis to assess petroleum potential of the Cretaceous and Tertiary strata in the Korean onshore and continental shelf have been carried out. The Cretaceous non-marine strata mainly occupy the Gyeongsang Basin in southeastern part of the Korean Peninsula and small basins such as Haenam and Gyeokpo depressions in western coastal areas. The Tertiary strata are mostly distributed in Domi, Cheju, Socotra subbasins, and Okinawa Trough in the South Continental Shelf, and Kunsan and Heuksan basins in the West. The basin evolution and petroleum potential for each basins are characterized as follow. The Cretaceous Gyeongsang sediments were deposited in three subbasins including Milyang, Euisung and Yongyang subbasins. The black shales in Nakdong and Jinju formations are interpreted to contain abundant organic matter during the deposition, thermal maturity reaching up to the zone of dry gas formation. Because porosity and permeability are too low, the sandstones can act as a tight gas reservoir rather than conventional oil and gas reservoir. The latest Cretaceous strata of Haenam and Kyeokpo depressions in western coastal area are correlated into the Yuchon Volcanic Group of the Gyeongsang Basin. Petroleum potential of the Early Cretaceous basin in the West Continental Shelf could be relatively high in terms of sedimentary basin filled with thick lacustrine sediments. The Kunsan basin in the West Continental Shelf originated in the Early Cretaceous time expanded during the Paleocene time followed by regional erosion at the end of Paleocene on which Neogene sediment have been accumulated. The Paleocene-Eocene sublacustrine shales may play an major role as a source and cap rocks. South Continental Shelf Basin is subdivided by Cheju subbasin in the center, Socotra Subbasin to the west, Domi Subbasin to the northeast and Okinawa Trough to the East. The potential hydrocarbon traps associated with anticline, titled fault blocks, fault, unconformity

  7. A note on coarse-grained gravity-flow deposits within proterozoic lacustrine sedimentary rocks, Transvaal sequence, South Africa

    Science.gov (United States)

    Eriksson, P. G.

    A widely developed, thin, coarse-matrix conglomerate occurs within early Proterozoic lacustrine mudrocks in the Transvaal Sequence, South Africa. The poorly sorted tabular chert clasts, alternation of a planar clast fabric with disorientated zones, plus normal and inverse grading in the former rock type suggest deposition by density-modified grain-flow and high density turbidity currents. The lower fan-delta slope palæenvironment inferred for the conglomerate is consistent with the lacustrine interpretation for the enclosing mudrock facies. This intracratonic setting contrasts with the marine environment generally associated with density-modified grain-flow deposits.

  8. Yb(OTf){sub 3}-catalyzed one-pot three component synthesis for tertiary amines

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Bum Seok; Kim, Ji Hye; Nam, Tae Kyu; Jang, Doo Ok [Dept. of Chemistry, Yonsei University, Wonju (Korea, Republic of)

    2015-07-15

    Tertiary amine functionality is found in many natural bioactive products such as alkaloids, amino acids, nucleic acids, pharmaceuticals, and agrochemicals. Tertiary amines have also been used as building blocks for nitrogen-containing organic compounds and synthetic polymers. A one-pot method for direct reductive amination of aldehydes has been developed to synthesize tertiary amines using HMDS as a nitrogen source in the presence of Yb(OTf ){sub 3}. With a stoichiometric amount of HMDS, the reaction afforded the desired tertiary amines without competitive reduction of the parent carbonyl compounds. This reaction offers a convenient and efficient protocol for synthesizing aromatic and aliphatic tertiary amines under mild reaction conditions.

  9. The Alleret Maar lacustrine sequence (French Massif Central): a 150 ka long early-middle Pleistocene continental paleoenvironmental record.

    Science.gov (United States)

    Nomade, S.; Pastre, J.; Guillou, H.; Gauthier, A.; Scaillet, S.

    2008-12-01

    Lacustrine maar sequences of the French Massif Central are of great interest for paleoclimatic and paleoenvironmental reconstructions of mid-latitudes Quaternary continental environments. In particular, the western Velay region yields exceptional sequences spanning the last 450 ka (Reille et al., J. Quat. Sci. 2000). However, older sequences remain largely unknown despite the presence of interbedded alkaline tephras allowing precise absolute radiochronological control of many lacustrine squences. The Alleret maar is a 1500 m wide phreatomagmatic crater that provides a long lacustrine sequence (41 m). The upper part of this sequence (AL2 core, 14.6 m) was studied between 2005 and 2006 (Pastre et al., C. R. Acad Sci, 2007). A 39Ar/40Ar date (557 ± 5ka) obtained from an interbedded tephra layer located at 7m as well as the associated pollen data attribute the beginning of this sequence to the MIS 15. Thanks to the AL3 core recovered in 2005 (40.6 m, CNRS Meudon) several new tephra layers were discovered in the bottom part of this lacustrine sequence. Three new 39Ar/40Ar ages (single crystal analyses) from trachytic tephra layers were obtained at the LSCE Argon Laboratory (France). These layers are located at -30.2, -36.2 and -39.2m. Ages obtained relative to the ACR-2 flux standard (1,201Ma, Kuiper et al., Science, 2008) range from 692 ± 6 ka (MSWD: 2.3, n=18) for the youngest (-30.2m) to 726 ± 9Ka Ka (MSWD: 2.2, n=12) for the lowest tephra located at -39.2m. These new dates indicate a relatively homogeneous deposition rate of 3.5cm/ka and that the last 10 meters cover the MIS 17-MIS18 period. According to these current radiochronological data the complete lacustrine sequence last more than 150ka. Ongoing sedimentary and pollen studies will allow to extend the paleoenvironmental and paleoclimatic records of the French Massif Central towards the beginning of the early middle Pleistocene.

  10. Reconstruction of a saline, lacustrine carbonate system (Priabonian, St-Chaptes Basin, SE France): Depositional models, paleogeographic and paleoclimatic implications

    Science.gov (United States)

    Lettéron, Alexandre; Hamon, Youri; Fournier, François; Séranne, Michel; Pellenard, Pierre; Joseph, Philippe

    2018-05-01

    A 220-m thick carbonate-dominated succession has been deposited in shallow-water, saline lake environments during the early to middle Priabonian (MP17A-MP18 mammal zones) in the Saint-Chaptes Basin (south-east France). The palaeoenvironmental, paleoclimatic and palaeogeographic significance of such saline lake carbonates has been deciphered on the basis of a multi-proxy analyses including: 1) depositional and diagenetic features; 2) biological components (molluscs, benthic foraminifera, characean gyrogonites, spores and pollens); 3) carbon and oxygen stable isotopes; 4) trace elements; and 5) clay mineralogy. Five stages of lacustrine system evolution have been identified: 1) fresh-water closed lake under dry climate (unit U1); 2) fresh to brackish water lacustrine deltaic system with a mixed carbonate-siliciclastic sedimentation under relatively wet climatic conditions (unit U2); 3) salt-water lacustrine carbonate system under humid climatic setting (unit U3); 4) evaporitic lake (unit U4); and 5) closed lake with shallow-water carbonate sedimentation under subtropical to Mediterranean climate with dry seasons (unit U5). Upper Eocene aridification is evidenced to have started as early as the earliest Priabonian (unit U1: MP17A mammal zone). A change from humid to dryer climatic conditions is recorded between units U3 and U4. The early to middle Priabonian saline lake is interpreted as an athalassic (inland) lake that have been transiently connected with neighboring salt lakes influenced by seawater and/or fed with sulfates deriving from recycling of evaporites. Maximum of connection with neighboring saline lakes (Mormoiron Basin, Camargue and Central grabens, Hérault Basin) likely occurred during unit U3 and at the base of unit U5. The most likely sources of salts of these adjacent basins are: 1) Triassic evaporites derived from salt-diapirs (Rhône valley) or from paleo-outcrops located east of the Durance fault or offshore in the Gulf of Lion; or 2) marine

  11. Observations on the relation between lacustrine facies and uranium deposits in continental sediments

    International Nuclear Information System (INIS)

    Noble, E.A.

    1981-01-01

    A recent sedimentological concept and approach in the evaluation of lacustrine deposition environments for their geological uranium potential are described. The presence of certain types of limonite seems to be a key factor in the process of leaching, the formation of pyrite and the precipitation of uranium. (author)

  12. Knowledge and perception of plastic surgery among tertiary ...

    African Journals Online (AJOL)

    2015-10-16

    Oct 16, 2015 ... tertiary education students in Enugu, South‑East. Nigeria. CM Isiguzo ..... This finding should be a motivation for plastic surgeons who have private ... population of this country some of whom travel abroad to source for these ...

  13. The microfauna assemblages as indicators of paleoenvironmental changes in the Miocene fluvial- lacustrine cycles (NE Duero Basin, Spain

    Directory of Open Access Journals (Sweden)

    A. Herrero-Hernández

    2016-11-01

    Full Text Available The siliclastic and carbonate deposits are interbedded in the Villadiego area (Miocene, NE Duero Basin. They have been subdivided into two high-rank depositional sequences: DDS and CDS. The sedimentary analysis of these units and the study of the microfauna content, mainly ostracods, led to the identification of lacustrine-fluvial interaction systems. The sedimentary characteristics reveal the existence of fluvial systems of gravel, flood plains and lacustrine systems that were interconnected and intimately related in north-south direction. In the sedimentological analysis, thirteen types of fluvial and lacustrine lithofacies and six genetic facies associations were recognized. The top of DDS is the result of lake level risings. The CDS shows a deepening-shallowing cycle. The ostracod micropaleontological analysis of the sediments have been studied, with the aim of reconstructing the palaeoenvironmental evolution of this area. These microfauna assemblages integrated with the analysis of the sedimentary facies allowed to conclude the existence of lakes with a water-bearing level of few tens of meters. A change in the chemical conditions of the waters, which evolved from oligohaline and carbonated to mesohaline and sulphated is concluded.

  14. Lacustrine sedimentation and facies model for the last 45,000 yr in Chalco basin. Central Mexico

    Science.gov (United States)

    Ortega, B.; Lozano, S.; Caballero, M.; Herrera, D.

    2013-05-01

    Chalco basin in central Mexico (19° 15' N, 98° 58' W, 2200 m asl) is one of the most detailed lake sediment sequence analyzed in Mexico for paleoclimatic and paleoenvironmental studies. In this former lake, five drill cores up to 27 m depth were recovered in 1987-1989 by the UNAM team, and three cores covering most of the former sequence were obtained in 2008 and 2011. The upper 27 m of the Chalco lacustrine sequence contains the record of the last 45 kyr climate history in the northern American tropics. The active tectonic and volcanic setting of Chalco Lake in the Trans-Mexican Volcanic Belt, provides an opportunity to evaluate environmental (volcanic + tectonic vs. climatic) controls on lacustrine sedimentation. The establishment of a detailed time scale by 14C in pollen extracts provides an accurate chronological control. The stratigraphical and sedimentological analyses presented here provided the recognition of depositional environments and the architecture of the upper lacustrine succession. Sedimentary facies were defined on the basis of sedimentological descriptions, microscopic observation and compositional analyses. According to compositional criteria, facies were identified and groped into two main categories according to compositional criteria: 1) detrital and volcaniclastic, and 2) biogenic facies. The clastic facies includes massive to laminated, silty and clayey sediments composed of clay minerals, feldspars, amphiboles with minor amounts of quartz, opaque minerals and calcite. Diatoms are the most common biological remains in all the clastic facies. Most of the volcaniclastic deposits correspond to fall-out deposits, some of them of well documented eruptions of the nearby large stratovolcanoes Popocatepetl and Nevado de Toluca, which in turn serve as stratigraphical markers. The biogenic facies are massive to finely laminated diatom ooze and ostracod ooze layers. The sedimentary architecture of the lacustrine succession has been controlled by

  15. Mechanosensory based orienting behaviors in fluvial and lacustrine populations of mottled sculpin (Cottus bairdi)

    Science.gov (United States)

    Sheryl Coombs; Gary D. Grossman

    2006-01-01

    We compared prey-orienting and rheotactic behaviors in a fluvial (Coweeta Creek) and lacustrine (Lake Michigan) population of mottled sculpin. Blinded sculpin from both populations exhibited unconditioned, mechanosensory based rheotaxis to low velocity flows. Whereas Lake Michigan sculpin generally showed increasing levels of positive rheotaxis to increasing velocities...

  16. Devonian lacustrine shore zone architecture imaged with ground penetrating radar

    DEFF Research Database (Denmark)

    Andrews, Steven D.; Moreau, Julien; Archer, Stuart

    . The shore zone sandstones overlie playa facies which contain abundant desiccation horizons, reflecting the most arid phase in the climatically controlled lacustrine cycle. As climatic conditions ameliorated the rejuvenation of fluvial systems resulted in the transport of sand out into the basin. Initial...... deposition was limited to intermittent events where sediment was laid down on a water saturated substrate. Some of these may have occurr­­­ed subaqueously as small scale turbidity flows. High resolution fluctuations in lake level resulted in periodic short lived reworking events along the lake margin which...

  17. Lacustrine-fluvial interactions in Australia's Riverine Plains

    Science.gov (United States)

    Kemp, Justine; Pietsch, Timothy; Gontz, Allen; Olley, Jon

    2017-06-01

    Climatic forcing of fluvial systems has been a pre-occupation of geomorphological studies in Australia since the 1940s. In the Riverine Plain, southeastern Australia, the stable tectonic setting and absence of glaciation have combined to produce sediment loads that are amongst the lowest in the world. Surficial sediments and landforms exceed 140,000 yr in age, and geomorphological change recorded in the fluvial, fluvio-lacustrine and aeolian features have provided a well-studied record of Quaternary environmental change over the last glacial cycle. The region includes the Willandra Lakes, whose distinctive lunette lakes preserve a history of water-level variations and ecological change that is the cornerstone of Australian Quaternary chronostratigraphy. The lunette sediments also contain an ancient record of human occupation that includes the earliest human fossils yet found on the Australian continent. To date, the lake-level and palaeochannel records in the Lachlan-Willandra system have not been fully integrated, making it difficult to establish the regional significance of hydrological change. Here, we compare the Willandra Lakes environmental record with the morphology and location of fluvial systems in the lower Lachlan. An ancient channel belt of the Lachlan, Willandra Creek, acted as the main feeder channel to Willandra Lakes before channel avulsion caused the lakes to dry out in the late Pleistocene. Electromagnetic surveys, geomorphological and sedimentary evidence are used to reconstruct the evolution of the first new channel belt following the avulsion. Single grain optical dating of floodplain sediments indicates that sedimentation in the new Middle Billabong Palaeochannel had commenced before 18.4 ± 1.1 ka. A second avulsion shifted its upper reaches to the location of the present Lachlan River by 16.2 ± 0.9 ka. The timing of these events is consistent with palaeohydrological records reconstructed from Willandra Lakes and with the record of

  18. Spatial distribution of saline water and possible sources of intrusion ...

    African Journals Online (AJOL)

    The spatial distribution of saline water and possible sources of intrusion into Lekki lagoon and transitional effects on the lacustrine ichthyofaunal characteristics were studied during March, 2006 and February, 2008. The water quality analysis indicated that, salinity has drastically increased recently in the lagoon (0.007 to ...

  19. Performance evaluation of nitrogen isotope ratio determination in marine and lacustrine sediments: An inter-laboratory comparison

    NARCIS (Netherlands)

    Bahlmann, E.; Bernasconi, S.M.; Bouillon, S.; Houtekamer, M.J.; Korntheuer, M.; Langenberg, F.; Mayr, C.; Metzke, M.; Middelburg, J.J.; Nagel, B.; Struck, U.; Voß, M.; Emeis, K.C.

    2010-01-01

    Nitrogen isotopes of organic matter are increasingly studied in marine biogeochemistry and geology, plant and animal ecology, and paleoceanography. Here, we present results of an inter-laboratory test on determination of nitrogen isotope ratios in marine and lacustrine sediments. Six different

  20. REE in some tertiary volcanic complexes in the Republic of Macedonia

    International Nuclear Information System (INIS)

    Tasev, Goran; Serafimovski, Todor

    2009-01-01

    Petrological and geochemical features of the Tertiary magmatic rocks from the Republic of Macedonia were subject of study in this paper. The latest K-Ar, 87 Sr/ 86 Sr, and REE data for samples from Kratovo- Zletovo, Sasa-Toranica and Damjan-Buchim ore districts are presented. Whole rock XRF analyses confirmed host rock composition as dacites, quartz-latites, trachyandesites, rhyolites and rhyodacites. Absolute age determinations by the K-Ar dating method have shown ages range from 31 to 14 Ma confirming Oligocene-Miocene age as previously determined by relative methods. Determinations of 87 Sr/ 86 Sr ratios (0.70504 to 0.71126) suggest material is sourced from the contact zone between the lower crust and upper mantle where contamination of primary melt occurred. New REE data including negative Eu anomalies along with previously determined La/Yb ratios ranging from 13.3 to 43.0 (Serafimovski 1990) confirm inferred material source. These new data reconfirm previous results, provide insight into the Tertiary magmatic history of the district, and suggest the exact origin of the material that produced the Tertiary magmatic rocks.

  1. An Innovation Systems Perspectives on Tertiary-Level Agricultural ...

    African Journals Online (AJOL)

    This paper examines how tertiary-level agricultural education in sub-Saharan Africa can contribute to agricultural development beyond its current role as a source of technical training. The paper draws on data and information gathered from semistructured key informant interviews conducted in late 2006 in and around Addis ...

  2. Evolution of tertiary intermontane fluvial system of Powder River Basin, Wyoming and Montana

    International Nuclear Information System (INIS)

    Flores, R.M.; Ethridge, F.G.

    1985-01-01

    Exploration and development of economic coal and uranium deposits of the Tertiary Fort Union and Wasatch Formations provided data related to the evolution of depositional systems in the Powder River Basin. In ascending order, the Paleocene Fort Union Formation consists of the Tullock, Lebo, and Tongue River Members. The overlying Eocene Wasatch Formation consists of the conglomeratic Kingsbury and Moncrief Members and laterally equivalent finer grained deposits. Evolution of fluvial deposition in the basin was determined from sandstone percent maps. A high proportion of sandstones in the Tullock Member and combined Tongue River Member and Wasatch Formation formed in interconnected east-west and north-south belts. The east-west belts represent alluvial fans, as well as braided and meandering tributary streams. The north-south belts reflect meandering and anastomosing trunk streams fed by basin margin tributaries. The sandstones of the Lebo Shale show east-west trends and represent deposits of fluvio-deltaic systems that filled a western, closed-lacustrine basin. The lake in this basin may have formed during localized subsidence along the Buffalo deep fault. These contrasting styles of fluvial deposition were largely controlled by extrabasinal and intrabasinal tectonics associated with Laramide orogeny

  3. Uranium and diagenesis in evaporitic lacustrine mudstone of the Oligocene White River Group, Dawes County, Nebraska. Bulletin

    International Nuclear Information System (INIS)

    Dickinson, K.A.

    1991-01-01

    The Oligocene White River Group consists of the Chadron and the overlying Brule Formations in northwestern Nebraska. The Chadron Formation consists of alluvial and colluvial vitric mudstone beds, but in addition contains white persistent layers (purplish-white layers) that probably resulted from soil formation on vitric parent material. West of the current study area a basal sandstone facies of the Chadron is host rock for the Crow Butte uranium deposit. The Brule, which consists mostly of pedogenically altered alluvial and fluvial vitric mudstone deposits, contains a uraniferous lacustrine facies northwest of Chadron, Nebraska. Detrital minerals in rocks of the White River Group include quartz, feldspar, volcanic glass, smectite, and illite. Chemical precipitate minerals in the lacustrine facies are calcite, dolomite, and gypsum. Authigenic minerals include calcite, dolomite, gypsum, smectite, opal, chalcedony, together with oxidized uranium minerals

  4. Analysis of the variation of the compressibility index (Cc of volcanic clays and its application to estimate subsidence in lacustrine areas

    Directory of Open Access Journals (Sweden)

    D. Carreón-Freyre

    2015-11-01

    Full Text Available An analysis of the deformation conditions of lacustrine materials deposited at three sites in the volcanic valley of the Mexico City is presented. Currently geotechnical studies assume that compressibility of granular materials decreases in depth due to the lithostatic load. That means that the deeper the sample the more rigid is supposed to be, this assumption should be demonstrated by a decreased Compression Index (Cc in depth. Studies indicate that Mexico City clays exhibit brittle behaviour, and have high water content, low shear strength and variable Cc values. Furthermore, groundwater withdrawal below the city causes a differential decrease in pore pressure, which is related to the physical properties of granular materials (hydraulic conductivity, grain size distribution and conditions of formation. Our results show that Cc for fine grain materials (lacustrine can be vertically variable, particularly when soils and sediments are the product of different volcanic materials. Lateral and vertical variations in the distribution of the fluvio-lacustrine materials, especially in basins with recent volcanic activity, may be assessed by Cc index variations. These variations can also be related to differential deformation, nucleation and propagation of fractures and need to be considered when modelling land subsidence.

  5. Chronology of Late Saalian and Middle Weichselian episodes of ice-free lacustrine sedimentation recorded in the Arumetsa section, southwestern Estonia

    Directory of Open Access Journals (Sweden)

    Maris Rattas

    2010-06-01

    Full Text Available The information obtained from a 21 m thick open-pit section of silty-clayey sediments in the Arumetsa bedrock valley, southwestern Estonia, revealed that lacustrine to glaciolacustrine sedimentation at the site started prior to 151 ka ago and lasted to about the end of marine isotope stage 6 (MIS6 at 130 ka. Further down from the 151 ka age-level to the bottom of the buried valley there are ca 60 m of lacustrine fine-grained sediments, the age of which remains still unclear. The Late Saalian sediments at Arumetsa are discordantly overlain by Middle Weichselian clay, silt and sand, deposited between ca 44 and 37 ka ago. As testified by optically stimulated luminescence (OSL ages, and pollen and diatom record, the Middle Weichselian fine-grained sediments contain redeposited Holsteinian but no Eemian pollen, and have not been fully bleached during deposition. Chronological, microfossil and sedimentological data show two hiatuses in the Arumetsa section. The first hiatus has left no sedimentary evidence for the period between ca 130 ka and 44 ka ago (MIS5 to older half of MIS3. The younger hiatus from ca 37 to 22 ka occurs between the Middle Weichselian lacustrine silt and the Late Weichselian till layer on top of the section.

  6. Palaeoenvironmental implications of a Holocene sequence of lacustrine-peat sediments from the desert-loess transitional zone in Northern China

    Science.gov (United States)

    Jia, Feifei; Lu, Ruijie; Liu, Xiaokang; Zhao, Chao; Lv, Zhiqiang; Gao, Shangyu

    2018-05-01

    A high-resolution lacustrine-peat record from the desert-loess transitional zone in Northern China was obtained to reconstruct Holocene environmental change in the region. AMS 14C dates are used to provide a chronology. The results indicate that the site was a desert environment before 12.2 cal kyr BP, and was then occupied by a paleolake which started to shrink, with a wetland occurring from 6.2 to 3.0 cal kyr BP. Subsequently, the site became a seasonally water-filled depression. Based on the lithology and measurements of grain size and total organic carbon content, the climate changed from arid to humid at 12.2 cal kyr BP, and became more humid after 8.3 cal kyr BP. From 6.2 to 3.0 cal kyr BP, precipitation decreased but the climate remained at an optimum. After 3.0 cal kyr BP, the climate was dry overall but with several humid intervals. A comparison of paleoclimatic records from lacustrine and aeolian deposits from the region reveals a discrepancy about the nature of the early Holocene climate, and we conclude that this is because lacustrine sediments responded more sensitively to precipitation than aeolian deposits when the temperature was low. The environmental evolution of the region was synchronous with changes in the Asian summer monsoon (ASM), but temperature also played a key role in the early Holocene.

  7. Detailed north-south cross section showing environments of deposition, organic richness, and thermal maturities of lower Tertiary rocks in the Uinta Basin, Utah

    Science.gov (United States)

    Johnson, Ronald C.

    2014-01-01

    The Uinta Basin of northeast Utah has produced large amounts of hydrocarbons from lower Tertiary strata since the 1960s. Recent advances in drilling technologies, in particular the development of efficient methods to drill and hydraulically fracture horizontal wells, has spurred renewed interest in producing hydrocarbons from unconventional low-permeability dolomite and shale reservoirs in the lacustrine, Eocene Green River Formation. The Eocene Green River Formation was deposited in Lake Uinta, a long-lived saline lake that occupied the Uinta Basin, the Piceance Basin to the east, and the intervening Douglas Creek arch. The focus of recent drilling activity has been the informal Uteland Butte member of the Green River Formation and to a much lesser extent the overlying R-0 oil shale zone of the Green River Formation. Initial production rates ranging from 500 to 1,500 barrels of oil equivalent per day have been reported from the Uteland Butte member from horizontal well logs that are as long as 4,000 feet (ft);. The cross section presented here extends northward from outcrop on the southern margin of the basin into the basin’s deep trough, located just south of the Uinta Mountains, and transects the area where this unconventional oil play is developing. The Monument Butte field, which is one of the fields located along this line of section, has produced hydrocarbons from conventional sandstone reservoirs in the lower part of the Green River Formation and underlying Wasatch Formation since 1981. A major fluvial-deltaic system entered Lake Uinta from the south, and this new line of section is ideal for studying the effect of the sediments delivered by this drainage on hydrocarbon reservoirs in the Green River Formation. The cross section also transects the Greater Altamont-Bluebell field in the deepest part of the basin, where hydrocarbons have been produced from fractured, highly overpressured marginal lacustrine and fluvial reservoirs in the Green River, Wasatch

  8. Luminescence dating of the lacustrine record of Vršac (Carpathian Basin, Serbia) - implications for a palaeoenvironmetal reconstruction

    Science.gov (United States)

    Klasen, N.; Zeeden, C.; Markovic, S.; Fischer, P.; Lehmkuhl, F.; Schulte, P.; Bösken, J.; Hambach, U.; Vött, A.

    2017-12-01

    The Carpathian Basin is one of the key areas to investigate the influence of the continental, Mediterranean and Atlantic climate interaction over Europe. The available Upper Pleistocene and Holocene geoarchives in the region are mainly loess-paleosol records. Long lacustrine records are sparse and do not always span the whole last glacial cycle. In the area around Vršac, we drilled a 10 m core to contribute to the palaeoenvironmental reconstruction of the Carpathian Basin. Electrical Resistivity Tomography (ERT) was used to find the best-suited drilling location. We applied luminescence and radiocarbon dating, because a robust chronology is important for the interpretation of the sedimentary record. Pulsed OSL measurements were carried out to identify the best sampling positions. We expect runoff from the catchment being the main source of the lacustrine sediments, because coarse fluvial input is absent. Knowledge about the depositional conditions is important in luminescence dating to evaluate partial bleaching prior to deposition, which may cause age overestimation. Therefore, we compared infrared stimulated luminescence (IRSL) signals with post infrared infrared stimulated luminescence (pIRIR) signals, which bleach at different rates. Estimation of a representative water content has major influence on the age estimate, but remains challenging in luminescence dating. We measured the present day water content as well as the saturation water content, to account for variations over time. Luminescence and radiocarbon ages differ greatly from each other. According to the laboratory experiments, luminescence dating was reliable and we conclude that radiocarbon ages were underestimated because of an intrusion of younger organic material. The initial results demonstrated the potential of the drill core. Integrating more proxy data will be useful to enhance the importance of the geoarchive at Vršac for a better understanding of the last glacial cycle in the Carpathian

  9. Genesis and distribution pattern of carbonate cements in lacustrine deep-water gravity-flow sandstone reservoirs in the third member of the Shahejie Formation in the Dongying Sag, Jiyang Depression, Eastern China

    DEFF Research Database (Denmark)

    Yang, Tian; Cao, Yingchang; Friis, Henrik

    2018-01-01

    The lacustrine deep-water gravity-flow sandstone reservoirs in the third member of the Shahejie Formation are the main exploration target for hydrocarbons in the Dongying Sag, Eastern China. Carbonate cementation is responsible for much of the porosity and permeability reduction in the lacustrine...

  10. A Habitable Fluvio-Lacustrine Environment at Yellowknife Bay, Gale Crater, Mars

    Science.gov (United States)

    Grotzinger, J. P.; Sumner, D. Y.; Kah, L. C.; Stack, K.; Gupta, S.; Edgar, L.; Rubin, D.; Lewis, K.; Schieber, J.; Mangold, N.; Milliken, R.; Conrad, P. G.; DesMarais, D.; Farmer, J.; Siebach, K.; Calef, F.; Hurowitz, J.; McLennan, S. M.; Ming, D.; Vaniman, D.; Crisp, J.; Vasavada, A.; Edgett, K. S.; Malin, M.; Blake, D.; Gellert, R.; Mahaffy, P.; Wiens, R. C.; Maurice, S.; Grant, J. A.; Wilson, S.; Anderson, R. C.; Beegle, L.; Arvidson, R.; Hallet, B.; Sletten, R. S.; Rice, M.; Bell, J.; Griffes, J.; Ehlmann, B.; Anderson, R. B.; Bristow, T. F.; Dietrich, W. E.; Dromart, G.; Eigenbrode, J.; Fraeman, A.; Hardgrove, C.; Herkenhoff, K.; Jandura, L.; Kocurek, G.; Lee, S.; Leshin, L. A.; Leveille, R.; Limonadi, D.; Maki, J.; McCloskey, S.; Meyer, M.; Minitti, M.; Newsom, H.; Oehler, D.; Okon, A.; Palucis, M.; Parker, T.; Rowland, S.; Schmidt, M.; Squyres, S.; Steele, A.; Stolper, E.; Summons, R.; Treiman, A.; Williams, R.; Yingst, A.; MSL Science Team; Kemppinen, Osku; Bridges, Nathan; Johnson, Jeffrey R.; Cremers, David; Godber, Austin; Wadhwa, Meenakshi; Wellington, Danika; McEwan, Ian; Newman, Claire; Richardson, Mark; Charpentier, Antoine; Peret, Laurent; King, Penelope; Blank, Jennifer; Weigle, Gerald; Li, Shuai; Robertson, Kevin; Sun, Vivian; Baker, Michael; Edwards, Christopher; Farley, Kenneth; Miller, Hayden; Newcombe, Megan; Pilorget, Cedric; Brunet, Claude; Hipkin, Victoria; Léveillé, Richard; Marchand, Geneviève; Sánchez, Pablo Sobrón; Favot, Laurent; Cody, George; Flückiger, Lorenzo; Lees, David; Nefian, Ara; Martin, Mildred; Gailhanou, Marc; Westall, Frances; Israël, Guy; Agard, Christophe; Baroukh, Julien; Donny, Christophe; Gaboriaud, Alain; Guillemot, Philippe; Lafaille, Vivian; Lorigny, Eric; Paillet, Alexis; Pérez, René; Saccoccio, Muriel; Yana, Charles; Armiens-Aparicio, Carlos; Rodríguez, Javier Caride; Blázquez, Isaías Carrasco; Gómez, Felipe Gómez; Gómez-Elvira, Javier; Hettrich, Sebastian; Malvitte, Alain Lepinette; Jiménez, Mercedes Marín; Martínez-Frías, Jesús; Martín-Soler, Javier; Martín-Torres, F. Javier; Jurado, Antonio Molina; Mora-Sotomayor, Luis; Caro, Guillermo Muñoz; López, Sara Navarro; Peinado-González, Verónica; Pla-García, Jorge; Manfredi, José Antonio Rodriguez; Romeral-Planelló, Julio José; Fuentes, Sara Alejandra Sans; Martinez, Eduardo Sebastian; Redondo, Josefina Torres; Urqui-O'Callaghan, Roser; Mier, María-Paz Zorzano; Chipera, Steve; Lacour, Jean-Luc; Mauchien, Patrick; Sirven, Jean-Baptiste; Manning, Heidi; Fairén, Alberto; Hayes, Alexander; Joseph, Jonathan; Sullivan, Robert; Thomas, Peter; Dupont, Audrey; Lundberg, Angela; Melikechi, Noureddine; Mezzacappa, Alissa; DeMarines, Julia; Grinspoon, David; Reitz, Günther; Prats, Benito; Atlaskin, Evgeny; Genzer, Maria; Harri, Ari-Matti; Haukka, Harri; Kahanpää, Henrik; Kauhanen, Janne; Paton, Mark; Polkko, Jouni; Schmidt, Walter; Siili, Tero; Fabre, Cécile; Wray, James; Wilhelm, Mary Beth; Poitrasson, Franck; Patel, Kiran; Gorevan, Stephen; Indyk, Stephen; Paulsen, Gale; Bish, David; Gondet, Brigitte; Langevin, Yves; Geffroy, Claude; Baratoux, David; Berger, Gilles; Cros, Alain; d'Uston, Claude; Forni, Olivier; Gasnault, Olivier; Lasue, Jérémie; Lee, Qiu-Mei; Meslin, Pierre-Yves; Pallier, Etienne; Parot, Yann; Pinet, Patrick; Schröder, Susanne; Toplis, Mike; Lewin, Éric; Brunner, Will; Heydari, Ezat; Achilles, Cherie; Sutter, Brad; Cabane, Michel; Coscia, David; Szopa, Cyril; Robert, François; Sautter, Violaine; Le Mouélic, Stéphane; Nachon, Marion; Buch, Arnaud; Stalport, Fabien; Coll, Patrice; François, Pascaline; Raulin, François; Teinturier, Samuel; Cameron, James; Clegg, Sam; Cousin, Agnès; DeLapp, Dorothea; Dingler, Robert; Jackson, Ryan Steele; Johnstone, Stephen; Lanza, Nina; Little, Cynthia; Nelson, Tony; Williams, Richard B.; Jones, Andrea; Kirkland, Laurel; Baker, Burt; Cantor, Bruce; Caplinger, Michael; Davis, Scott; Duston, Brian; Fay, Donald; Harker, David; Herrera, Paul; Jensen, Elsa; Kennedy, Megan R.; Krezoski, Gillian; Krysak, Daniel; Lipkaman, Leslie; McCartney, Elaina; McNair, Sean; Nixon, Brian; Posiolova, Liliya; Ravine, Michael; Salamon, Andrew; Saper, Lee; Stoiber, Kevin; Supulver, Kimberley; Van Beek, Jason; Van Beek, Tessa; Zimdar, Robert; French, Katherine Louise; Iagnemma, Karl; Miller, Kristen; Goesmann, Fred; Goetz, Walter; Hviid, Stubbe; Johnson, Micah; Lefavor, Matthew; Lyness, Eric; Breves, Elly; Dyar, M. Darby; Fassett, Caleb; Edwards, Laurence; Haberle, Robert; Hoehler, Tori; Hollingsworth, Jeff; Kahre, Melinda; Keely, Leslie; McKay, Christopher; Bleacher, Lora; Brinckerhoff, William; Choi, David; Dworkin, Jason P.; Floyd, Melissa; Freissinet, Caroline; Garvin, James; Glavin, Daniel; Harpold, Daniel; Martin, David K.; McAdam, Amy; Pavlov, Alexander; Raaen, Eric; Smith, Michael D.; Stern, Jennifer; Tan, Florence; Trainer, Melissa; Posner, Arik; Voytek, Mary; Aubrey, Andrew; Behar, Alberto; Blaney, Diana; Brinza, David; Christensen, Lance; DeFlores, Lauren; Feldman, Jason; Feldman, Sabrina; Flesch, Gregory; Jun, Insoo; Keymeulen, Didier; Mischna, Michael; Morookian, John Michael; Pavri, Betina; Schoppers, Marcel; Sengstacken, Aaron; Simmonds, John J.; Spanovich, Nicole; Juarez, Manuel de la Torre; Webster, Christopher R.; Yen, Albert; Archer, Paul Douglas; Cucinotta, Francis; Jones, John H.; Morris, Richard V.; Niles, Paul; Rampe, Elizabeth; Nolan, Thomas; Fisk, Martin; Radziemski, Leon; Barraclough, Bruce; Bender, Steve; Berman, Daniel; Dobrea, Eldar Noe; Tokar, Robert; Cleghorn, Timothy; Huntress, Wesley; Manhès, Gérard; Hudgins, Judy; Olson, Timothy; Stewart, Noel; Sarrazin, Philippe; Vicenzi, Edward; Bullock, Mark; Ehresmann, Bent; Hamilton, Victoria; Hassler, Donald; Peterson, Joseph; Rafkin, Scot; Zeitlin, Cary; Fedosov, Fedor; Golovin, Dmitry; Karpushkina, Natalya; Kozyrev, Alexander; Litvak, Maxim; Malakhov, Alexey; Mitrofanov, Igor; Mokrousov, Maxim; Nikiforov, Sergey; Prokhorov, Vasily; Sanin, Anton; Tretyakov, Vladislav; Varenikov, Alexey; Vostrukhin, Andrey; Kuzmin, Ruslan; Clark, Benton; Wolff, Michael; Botta, Oliver; Drake, Darrell; Bean, Keri; Lemmon, Mark; Schwenzer, Susanne P.; Lee, Ella Mae; Sucharski, Robert; Hernández, Miguel Ángel de Pablo; Ávalos, Juan José Blanco; Ramos, Miguel; Kim, Myung-Hee; Malespin, Charles; Plante, Ianik; Muller, Jan-Peter; Navarro-González, Rafael; Ewing, Ryan; Boynton, William; Downs, Robert; Fitzgibbon, Mike; Harshman, Karl; Morrison, Shaunna; Kortmann, Onno; Williams, Amy; Lugmair, Günter; Wilson, Michael A.; Jakosky, Bruce; Balic-Zunic, Tonci; Frydenvang, Jens; Jensen, Jaqueline Kløvgaard; Kinch, Kjartan; Koefoed, Asmus; Madsen, Morten Bo; Stipp, Susan Louise Svane; Boyd, Nick; Campbell, John L.; Perrett, Glynis; Pradler, Irina; VanBommel, Scott; Jacob, Samantha; Owen, Tobias; Savijärvi, Hannu; Boehm, Eckart; Böttcher, Stephan; Burmeister, Sönke; Guo, Jingnan; Köhler, Jan; García, César Martín; Mueller-Mellin, Reinhold; Wimmer-Schweingruber, Robert; Bridges, John C.; McConnochie, Timothy; Benna, Mehdi; Franz, Heather; Bower, Hannah; Brunner, Anna; Blau, Hannah; Boucher, Thomas; Carmosino, Marco; Atreya, Sushil; Elliott, Harvey; Halleaux, Douglas; Rennó, Nilton; Wong, Michael; Pepin, Robert; Elliott, Beverley; Spray, John; Thompson, Lucy; Gordon, Suzanne; Ollila, Ann; Williams, Joshua; Vasconcelos, Paulo; Bentz, Jennifer; Nealson, Kenneth; Popa, Radu; Moersch, Jeffrey; Tate, Christopher; Day, Mackenzie; Francis, Raymond; McCullough, Emily; Cloutis, Ed; ten Kate, Inge Loes; Scholes, Daniel; Slavney, Susan; Stein, Thomas; Ward, Jennifer; Berger, Jeffrey; Moores, John E.

    2014-01-01

    The Curiosity rover discovered fine-grained sedimentary rocks, which are inferred to represent an ancient lake and preserve evidence of an environment that would have been suited to support a martian biosphere founded on chemolithoautotrophy. This aqueous environment was characterized by neutral pH, low salinity, and variable redox states of both iron and sulfur species. Carbon, hydrogen, oxygen, sulfur, nitrogen, and phosphorus were measured directly as key biogenic elements; by inference, phosphorus is assumed to have been available. The environment probably had a minimum duration of hundreds to tens of thousands of years. These results highlight the biological viability of fluvial-lacustrine environments in the post-Noachian history of Mars.

  11. Stereoinversion of tertiary alcohols to tertiary-alkyl isonitriles and amines.

    Science.gov (United States)

    Pronin, Sergey V; Reiher, Christopher A; Shenvi, Ryan A

    2013-09-12

    The SN2 reaction (bimolecular nucleophilic substitution) is a well-known chemical transformation that can be used to join two smaller molecules together into a larger molecule or to exchange one functional group for another. The SN2 reaction proceeds in a very predictable manner: substitution occurs with inversion of stereochemistry, resulting from the 'backside attack' of the electrophilic carbon by the nucleophile. A significant limitation of the SN2 reaction is its intolerance for tertiary carbon atoms: whereas primary and secondary alcohols are viable precursor substrates, tertiary alcohols and their derivatives usually either fail to react or produce stereochemical mixtures of products. Here we report the stereochemical inversion of chiral tertiary alcohols with a nitrogenous nucleophile facilitated by a Lewis-acid-catalysed solvolysis. The method is chemoselective against secondary and primary alcohols, thereby complementing the selectivity of the SN2 reaction. Furthermore, this method for carbon-nitrogen bond formation mimics a putative biosynthetic step in the synthesis of marine terpenoids and enables their preparation from the corresponding terrestrial terpenes. We expect that the general attributes of the methodology will allow chiral tertiary alcohols to be considered viable substrates for stereoinversion reactions.

  12. Geomorphic Drainage Capture Recorded by Oxygen Isotopes of Green River Formation Lacustrine Mudstone, Eocene, Wyoming

    Science.gov (United States)

    Doebbert, A. C.; Booth, A. L.; Carroll, A.; Chamberlain, C.; Rhodes, M.

    2005-12-01

    The isotopic composition of cement and other meteoric precipitates are increasingly being used to interpret orogenic uplift histories, based on the relationship between altitude and rainwater δ18O. However, other variables such as changing regional drainage patterns may also affect the downstream composition of surface waters, especially when multiple drainages commingle in a lake. The Green River Formation contains some of the best documented lacustrine deposits in the world, making it ideal for examining such issues. Carbonate mudstone in balanced-fill facies of the lower LaClede Bed averages 3.41‰ (PDB), and records a deep, saline to brackish lake that fluctuated near its sill. In contrast, overfilled facies of the upper LaClede Bed record a freshwater lake, and δ18O reaches values as low as -9.72‰. This transition occurred shortly after deposition of the Analcite Tuff at 48.94 ± 0.12 Ma (Smith et al., 2003), and was geologically abrupt. Based on 40Ar/39Ar-calibrated sediment accumulation rates it required no more than 200-300 ky. An almost identical transition occurs in two cores separated by about 30 km, making local diagenesis an unlikely cause. The magnitude of δ18O change is similar to that in some uplift studies, but its rapidity virtually excludes uplift as a controlling mechanism. Instead, we propose that both the change in sedimentation and the sharp decrease in δ18O are the result of a drainage capture event. The addition of a new drainage to the basin may have adjusted isotopic values in two ways: by introducing runoff with relatively low δ18O, and by decreasing residence time (and therefore evaporation) of lake water. Decreasing 87Sr/86Sr across the same transition suggests that the newly added waters may have been sourced from rising volcanic topography to the north in the Absaroka province. Although this rising topography allows for the possibility of some uplift component, the rate of change in lacustrine δ18O is consistent with

  13. Ecological state of the Romanian Black Sea littoral lacustrine ecosystems

    Science.gov (United States)

    Gomoiu, M.-T.

    2009-04-01

    The author uses the results of his own researches as well as data from specialty literature to assess the ecological state of some typical lacustrine ecosystems considered, about 50 years ago, of major importance by their functions, services and researches, for the human populations in the settlements nearby. Based on this assessment the author recommends a few criteria which can be taken into account when programs of integrated management of these coastal ecosystems are initiated. The paper focuses on the study cases regarding the following major ecosystems: 1. Razelm-Sinoie Lagoon Complex - tightly linked to the Danube River and Delta systems, 2. Taşaul Lake - interfered in the last two decades by a branch of the DanubeRiver - Black Sea Canal and 3. Techirghiol Lake - for a long time under the sea level, a hyperhaline lake with therapeutic, sapropelic mud, disturbed by huge quantities of freshwaters infiltrated from the irrigation system. At present, the state of the lacustrine ecosystems at the Romanian Black Sea Coast can be characterized, mainly, by the following aspects: · Increase in the quantities of nutrients and chemical toxicants; · Rise in the level and frequency of eutrophication and pollution phenomena; · Drastic reduction of specific diversity; · Simplification of communities' structure - biocoenosis homogeneity; · Decrease in numerical abundance and biomass of benthic populations and consequently, low biofilter power by the decrease of the filter-feeder populations; · Worsening of the qualitative and the quantitative state of the biological benthic resources; · Thriving opportunistic forms (e.g. the worms causing sediment bioturbation); · Invasion by some exotic species, with harmful, unexpected consequences; · All populations undergo quantitative fluctuations; · Decrease in the fish population and in the use values of lacustrine assets, with strong impact on the welfare of the human society. Almost all pressure forms associated with the

  14. Secondary and tertiary hyperparathyroidism.

    Science.gov (United States)

    Jamal, Sophie A; Miller, Paul D

    2013-01-01

    We reviewed the etiology and management of secondary and tertiary hyperparathyroidism. Secondary hyperparathyroidism is characterized by an increase in parathyroid hormone (PTH) that is appropriate and in response to a stimulus, most commonly low serum calcium. In secondary hyperparathyroidism, the serum calcium is normal and the PTH level is elevated. Tertiary hyperparathyroidism is characterized by excessive secretion of PTH after longstanding secondary hyperparathyroidism, in which hypercalcemia has ensued. Tertiary hyperparathyroidism typically occurs in men and women with chronic kidney disease usually after kidney transplant. The etiology and treatment of secondary hyperparathyroidism is relatively straightforward whereas data on the management of tertiary hyperparathyroidism is limited to a few small trials with short follow-up. Copyright © 2013 The International Society for Clinical Densitometry. Published by Elsevier Inc. All rights reserved.

  15. Truce with oxygen - A naerobiosis outcompete aerobiosis in the Antarctic lacustrine bacteria

    Digital Repository Service at National Institute of Oceanography (India)

    LokaBharathi, P.A.; Nair, S.; DeSouza, M.J.B.D.; Chandramohan, D.

    . All colonies that were not black by sulfide precipitation were counted as FB. The anaerobic CFU were AnB, FB, SRB, and TDLO. The plates were incubated at 8–10° C for 10–20 days and the tubes for ca 30 days. All samples have been analysed... aerobiosis in the Antarctic lacustrine bacteria Page 3 of 5 file://C:\\My Documents\\articles23.htm 2/11/05 sulfide (63–188 ppm) at 5° C for 16 h and the viability estimated using Kogure’s method10,11. Viability is expressed as percentage of total viable...

  16. Favorability for uranium in tertiary sedimentary rocks, southwestern Montana

    International Nuclear Information System (INIS)

    Wopat, M.A.; Curry, W.E.; Robins, J.W.; Marjaniemi, D.K.

    1977-10-01

    Tertiary sedimentary rocks in the basins of southwestern Montana were studied to determine their favorability for potential uranium resources. Uranium in the Tertiary sedimentary rocks was probably derived from the Boulder batholith and from silicic volcanic material. The batholith contains numerous uranium occurrences and is the most favorable plutonic source for uranium in the study area. Subjective favorability categories of good, moderate, and poor, based on the number and type of favorable criteria present, were used to classify the rock sequences studied. Rocks judged to have good favorability for uranium deposits are (1) Eocene and Oligocene strata and undifferentiated Tertiary rocks in the western Three Forks basin and (2) Oligocene rocks in the Helena basin. Rocks having moderate favorability consist of (1) Eocene and Oligocene strata in the Jefferson River, Beaverhead River, and lower Ruby River basins, (2) Oligocene rocks in the Townsend and Clarkston basins, (3) Miocene and Pliocene rocks in the Upper Ruby River basin, and (4) all Tertiary sedimentary formations in the eastern Three Forks basin, and in the Grasshopper Creek, Horse Prairie, Medicine Lodge Creek, Big Sheep Creek, Deer Lodge, Big Hole River, and Bull Creek basins. The following have poor favorability: (1) the Beaverhead Conglomerate in the Red Rock and Centennial basins, (2) Eocene and Oligocene rocks in the Upper Ruby River basin, (3) Miocene and Pliocene rocks in the Townsend, Clarkston, Smith River, and Divide Creek basins, (4) Miocene through Pleistocene rocks in the Jefferson River, Beaverhead River, and Lower Ruby River basins, and (5) all Tertiary sedimentary rocks in the Boulder River, Sage Creek, Muddy Creek, Madison River, Flint Creek, Gold Creek, and Bitterroot basins

  17. Architecture and reservoir quality of low-permeable Eocene lacustrine turbidite sandstone from the Dongying Depression, East China

    Science.gov (United States)

    Munawar, Muhammad Jawad; Lin, Chengyan; Chunmei, Dong; Zhang, Xianguo; Zhao, Haiyan; Xiao, Shuming; Azeem, Tahir; Zahid, Muhammad Aleem; Ma, Cunfei

    2018-05-01

    The architecture and quality of lacustrine turbidites that act as petroleum reservoirs are less well documented. Reservoir architecture and multiscale heterogeneity in turbidites represent serious challenges to production performance. Additionally, establishing a hierarchy profile to delineate heterogeneity is a challenging task in lacustrine turbidite deposits. Here, we report on the turbidites in the middle third member of the Eocene Shahejie Formation (Es3), which was deposited during extensive Middle to Late Eocene rifting in the Dongying Depression. Seismic records, wireline log responses, and core observations were integrated to describe the reservoir heterogeneity by delineating the architectural elements, sequence stratigraphic framework and lithofacies assemblage. A petrographic approach was adopted to constrain microscopic heterogeneity using an optical microscope, routine core analyses and X-ray diffraction (XRD) analyses. The Es3m member is interpreted as a sequence set composed of four composite sequences: CS1, CS2, CS3 and CS4. A total of forty-five sequences were identified within these four composite sequences. Sand bodies were mainly deposited as channels, levees, overbank splays, lobes and lobe fringes. The combination of fining-upward and coarsening-upward lithofacies patterns in the architectural elements produces highly complex composite flow units. Microscopic heterogeneity is produced by diagenetic alteration processes (i.e., feldspar dissolution, authigenic clay formation and quartz cementation). The widespread kaolinization of feldspar and mobilization of materials enhanced the quality of the reservoir by producing secondary enlarged pores. In contrast, the formation of pore-filling authigenic illite and illite/smectite clays reduced its permeability. Recovery rates are higher in the axial areas and smaller in the marginal areas of architectural elements. This study represents a significant insight into the reservoir architecture and

  18. Tephras in lacustrine sediments of the Sarliève marsh (French Massif Central): age and preservation

    Science.gov (United States)

    Fourmont, Agathe; Macaire, Jean-Jacques; Bréhéret, Jean-Gabriel; Argant, Jacqueline; Prat, Béatrice; Vernet, Gérard

    2006-12-01

    The Sarliève marsh sediments (Massif Central, France) contain two tephras. The first tephra [ 13.7±0.4ka(2δ), ca. 12 000 BP], regionally well known, enables to date the beginning of lacustrine infill to the Lateglacial. The second tephra, the 'tephra de Sarliève', the emitting volcano of which is unknown, would be dated to around the Early Subboreal from pollen data. This occurrence, after the discovery of the 'tephra de Beaunit', emphasizes that volcanic eruption(s) occurred in the 'Chaîne des Puys' or in the volcanic Cézallier more than 1000 years after the last known eruption (Pavin) in the 'Chaîne des Puys' at around 6.6/6.7 ka (5800/5900 BP). In the Sarliève piles, these tephras, well preserved in thick and more silicated deposits of deltas, were not observed in carbonated basin sediments where they were altered. The abundance of authigenic zeolites formed during the Lateglacial in restricted depocentre lacustrine waters allows us to detect initial CF1 tephra occurrence. To cite this article: A. Fourmont et al., C. R. Geoscience 338 (2006).

  19. PHYSIOLOGICALLY BASED PHARMACOKINETIC MODEL FOR HUMAN EXPOSURES TO METHYL TERTIARY-BUTYL ETHER

    Science.gov (United States)

    Humans can be exposed by inhalation, ingestion, or dermal absorption to methyl tertiary-butyl ether (MTBE), an oxygenated fuel additive, from contaminated water sources. The purpose of this research was to develop a physiologically based pharmacokinetic model describing in human...

  20. Organic sedimentation in modern lacustrine systems: A case study from Lake Malawi, East Africa

    Science.gov (United States)

    Ellis, Geoffrey S.; Barry J. Katz,; Christopher A. Scholz,; Peter K. Swart,

    2015-01-01

    This study examines the relationship between depositional environment and sedimentary organic geochemistry in Lake Malawi, East Africa, and evaluates the relative significance of the various processes that control sedimentary organic matter (OM) in lacustrine systems. Total organic carbon (TOC) concentrations in recent sediments from Lake Malawi range from 0.01 to 8.80 wt% and average 2.83 wt% for surface sediments and 2.35 wt% for shallow core sediments. Hydrogen index (HI) values as determined by Rock-Eval pyrolysis range from 0 to 756 mg HC g−1 TOC and average 205 mg HC g−1 TOC for surface sediments and 228 mg HC g−1 TOC for shallow core samples. On average, variations in primary productivity throughout the lake may account for ~33% of the TOC content in Lake Malawi sediments (as much as 1 wt% TOC), and have little or no impact on sedimentary HI values. Similarly, ~33% to 66% of the variation in TOC content in Lake Malawi sediments appears to be controlled by anoxic preservation of OM (~1–2 wt% TOC), although some component of the water depth–TOC relationship may be due to physical sediment transport processes. Furthermore, anoxic preservation has a minimal effect on HI values in Lake Malawi sediments. Dilution of OM by inorganic sediment may account for ~16% of variability in TOC content in Lake Malawi sediments (~0.5 wt% TOC). The effect of inputs of terrestrial sediment on the organic character of surface sediments in these lakes is highly variable, and appears to be more closely related to the local depositional environment than the regional flux of terrestrial OM. Total nitrogen and TOC content in surface sediments collected throughout the lake are found to be highly correlated (r2 = 0.95), indicating a well-homogenized source of OM to the lake bottom. The recurring suspension and deposition of terrestrial sediment may account for significant amounts of OM deposited in offshore regions of the lake. This process effectively separates denser

  1. Disentangling natural and anthropogenic signals in lacustrine records: An example from the Ilan Plain, NE Taiwan

    Directory of Open Access Journals (Sweden)

    Jyh-Jaan Huang

    2016-11-01

    Full Text Available The impact of human activities has been increasing to a degree where humans now outcompete many natural processes. When interpreting environmental and climatic changes recorded in natural archives on historical time scales, it is therefore important to be able to disentangle the relative contribution of natural and anthropogenic processes. Lake Meihua on the Ilan Plain in northeastern Taiwan offers a particularly suitable opportunity to test how human activities known from historical records can be recorded in lacustrine sediment. For this purpose, three cores from Lake Meihua have been studied by a multiproxy approach, providing the first decadal-resolution lacustrine records covering the past 150 years in Taiwan. Profiles of excess 210Pb, 137Cs and 239,240Pu from two short cores (MHL-09-01 and MHL-11-02 allowed a precise chronology to be established. The presence of a yellow, earthy layer with lower levels of organic material coincide with the record of land development associated with the construction of the San-Chin-Gong Temple during AD 1970-1982. Furthermore, in the lower part of the cores, the upwards increasing trend of inc/coh, TOC, TOC/TN, and grain size, coupled with the palynological data (increase of Alnus, Mallotus, Trema and herbs from the nearby core MHL-5A with radiocarbon chronology, suggest that the area surrounding the lake has been significantly affected by agricultural activities since the arrival of Chinese settlers around ~AD 1874. In sum, this study demonstrates that this suite of lacustrine sediments in northeastern Taiwan has recorded human activities in agreement with historical documents, and that different human activities will leave distinct sedimentological, geochemical, and palynological signatures in the sedimentary archives. Therefore, multiproxy reconstructions are important to capture the complex nature of human-environmental interactions. A better understanding of the weathering and erosion response to human

  2. Disentangling natural and anthropogenic signals in lacustrine records: An example from the Ilan Plain, NE Taiwan

    Science.gov (United States)

    Huang, Jyh-Jaan; Huh, Chih-An; Wei, Kuo-Yen; Löwemark, Ludvig; Lin, Shu-Fen; Liao, Wen-Hsuan; Yang, Tien-Nan; Song, Sheng-Rong; Lee, Meng-Yang; Su, Chih-Chieh; Lee, Teh-Quei

    2016-11-01

    The impact of human activities has been increasing to a degree where humans now outcompete many natural processes. When interpreting environmental and climatic changes recorded in natural archives on historical time scales, it is therefore important to be able to disentangle the relative contribution of natural and anthropogenic processes. Lake Meihua on the Ilan Plain in northeastern Taiwan offers a particularly suitable opportunity to test how human activities known from historical records can be recorded in lacustrine sediment. For this purpose, three cores from Lake Meihua have been studied by a multiproxy approach, providing the first decadal-resolution lacustrine records covering the past 150 years in Taiwan. Profiles of excess 210Pb, 137Cs and 239,240Pu from two short cores (MHL-09-01 and MHL-11-02) allowed a precise chronology to be established. The presence of a yellow, earthy layer with lower levels of organic material coincide with the record of land development associated with the construction of the San-Chin-Gong Temple during AD 1970-1982. Furthermore, in the lower part of the cores, the upwards increasing trend of inc/coh, TOC, TOC/TN, and grain size, coupled with the palynological data (increase of Alnus, Mallotus, Trema and herbs) from the nearby core MHL-5A with radiocarbon chronology, suggest that the area surrounding the lake has been significantly affected by agricultural activities since the arrival of Chinese settlers around AD 1874. In sum, this study demonstrates that this suite of lacustrine sediments in northeastern Taiwan has recorded human activities in agreement with historical documents, and that different human activities will leave distinct sedimentological, geochemical, and palynological signatures in the sedimentary archives. Therefore, multiproxy reconstructions are important to capture the complex nature of human-environmental interactions. A better understanding of the weathering and erosion response to human activities can

  3. The relationship between humans and climate across the North Atlantic: what can lacustrine biomarkers tell us?

    Science.gov (United States)

    de Wet, G.; Castañeda, I. S.; Bradley, R. S.; Small, G.; Barrasso, T.

    2016-12-01

    While climate change has been implicated in the colonization/population dynamics of the North Atlantic region, researchers in many cases are forced to compare archaeological data with distant paleoclimate records, making these linkages tenuous. Our research utilizes novel organic biomarkers in lacustrine sediments to produce paired paleoclimate and human occupancy reconstructions to better address questions surrounding human migration and climate change. Here we present preliminary results from two prominent locations in the history of the European colonization of the North Atlantic. The first, carried out on the Norse "Eastern Settlement" in Southern Greenland, attempts to answer the long-standing question of whether climate change caused the demise of the colony in the 1400s C.E. Second, we use similar techniques to search for evidence of the first peopling of the Faroe Islands, a highly debated topic. The use of lacustrine biomarkers allows for numerous aspects of both paleoclimate and human presence in a catchment to be reconstructed. We reconstruct paleotemperatures using branched glycerol dialkyl glycerol tetraethers (brGDGTs) and alkenones (the UK37 Index), when present. Additionally, will analyze the difference in the hydrogen isotopic composition of long and short-chain plant leaf waxes as a proxy for lake water balance. Human occupancy in the region is investigated using fecal sterols and stanols, primarily created by the breakdown of cholesterol. Some of these compounds, such as coprostanol (the dominant sterol in human waste), provide strong evidence of human settlements and have been identified in some of our lake records. Our preliminary results suggest that temperatures were increasing in SW Greenland during the period when the Norse are thought to have died out, potentially challenging the long-standing view of climate deterioration being the primary cause of their demise. Primary productivity biomarkers from lake Eidisvatnet, in the Faroe Islands

  4. Holocene environmental changes in northern Lebanon as inferred from a multiproxy study on lacustrine-palustrine sediment

    Science.gov (United States)

    Vidal, Laurence; Jenna, Hage-Hassen; Demory, François; Develle, Anne-Lise; van Campo, Elise; Elias, Ata

    2016-04-01

    The reconstruction of the Levantine post-glacial environmental evolution is essential to understand the interactions between variability of regional water cycle, dynamics of the global climate, and cultural evolution. We present a paleolacustrine record from the karstic Yammouneh basin (34.06N-34.09N; 36.0E-36.03E, 1360 m a.s.l.), located on the eastern flank of Mount Lebanon (northern Levant). Holocene sediments (retrieved from gully and a trenbch) (1.5 to 3.6 m thick) consist of pale lacustrine chalk interrupted by an ash layer and remarkable centimetric beds of ocher to dark brown silty clays used, in addition to 14C ages, as stratigraphical markers. Lacustrine biogenic remains are diversified and abundant (ostracods, gastropods, charophytes, chlorophyceae, plant debris…) all reflecting a freswater, generally shallow waterbody. We analysed the sediment mineralogy and geochemistry, TOM contents, magnetic properties, pollen and calcite oxygen isotope composition derived from ostracod shells. These sequences are compared to former data from 2 trenches and 1 core collected in different points of the basin (Daeron et al., 2007; Develle et al., 2009, 2010). A total of 42 AMS 14C dating (partly carbonized wood) provide a solid chronology from the YD to present. Results reveal the following main features : 1- intervals dominated by authigenic calcite suggest that the major water supply was the karstic springs, which still deliver Ca-rich water and low surface runoff; 2- the lake oxygen isotope composition has been impacted by the source isotope composition throughout the Holocene and by increased inland rainfall during the early Holocene; 3- a decideous oak forest, implying much more soil water availability than today, was developed around the lake from ca. 11.5 to 9.5 kyr (the very bad pollen preservation after 8.3 kyr reflects oxidation or frequent oscillations of the water level); 4- four paleosols evidenced from lithofacies and magnetic properties are identified

  5. Regional chemostratigraphic key horizons in the macrofossil-barren siliciclastic lower Miocene lacustrine sediments (Most Basin, Eger Graben, Czech Republic)

    Czech Academy of Sciences Publication Activity Database

    Matys Grygar, Tomáš; Mach, K.

    2013-01-01

    Roč. 88, č. 3 (2013), s. 557-571 ISSN 1214-1119 R&D Projects: GA ČR(CZ) GAP210/11/1357 Institutional support: RVO:61388980 Keywords : Most Basin * Burdigalian * chemostratigraphy * proxy analyses * lacustrine sediments Subject RIV: DD - Geochemistry Impact factor: 1.495, year: 2013

  6. Sedimentological reservoir characteristics of the Paleocene fluvial/lacustrine Yabus Sandstone, Melut Basin, Sudan

    Science.gov (United States)

    Mahgoub, M. I.; Padmanabhan, E.; Abdullatif, O. M.

    2016-11-01

    Melut Basin in Sudan is regionally linked to the Mesozoic-Cenozoic Central and Western African Rift System (CWARS). The Paleocene Yabus Formation is the main oil producing reservoir in the basin. It is dominated by channel sandstone and shales deposited in fluvial/lacustrine environment during the third phase of rifting in the basin. Different scales of sedimentological heterogeneities influenced reservoir quality and architecture. The cores and well logs analyses revealed seven lithofacies representing fluvial, deltaic and lacustrine depositional environments. The sandstone is medium to coarse-grained, poorly to moderately-sorted and sub-angular to sub-rounded, arkosic-subarkosic to sublitharenite. On the basin scale, the Yabus Formation showed variation in sandstone bodies, thickness, geometry and architecture. On macro-scale, reservoir quality varies vertically and laterally within Yabus Sandstone where it shows progressive fining upward tendencies with different degrees of connectivity. The lower part of the reservoir showed well-connected and amalgamated sandstone bodies, the middle to the upper parts, however, have moderate to low sandstone bodies' connectivity and amalgamation. On micro-scale, sandstone reservoir quality is directly affected by textures and diagenetic changes such as compaction, cementation, alteration, dissolution and kaolinite clays pore fill and coat all have significantly reduced the reservoir porosity and permeability. The estimated porosity in Yabus Formation ranges from 2 to 20% with an average of 12%; while permeability varies from 200 to 500 mD and up to 1 Darcy. The understanding of different scales of sedimentological reservoir heterogeneities might contribute to better reservoir quality prediction, architecture, consequently enhancing development and productivity.

  7. Development and Rainfed Paddy Soils Potency Derived from Lacustrine Material in Paguyaman, Gorontalo

    Directory of Open Access Journals (Sweden)

    Nurdin

    2011-09-01

    Full Text Available Rainfed paddy soils that are derived from lacustrine and include of E4 agroclimatic zone have many unique properties and potentially for paddy and corn plantations. This sreseach was aimed to: (1 study the soil development of rainfed paddy soils derived from lacustrine and (2 evaluate rainfed paddy soils potency for paddy and corn in Paguyaman. Soil samples were taken from three profiles according to toposequent, and they were analyzed in laboratory. Data were analyzed with descriptive-quantitative analysis. Furthermore, assessment on rainfed paddy soils potency was conducted with land suitability analysis using parametric approach. Results indicate that all pedon had evolved with B horizons structurization. However, pedon located on the summit slope was more developed and intensely weathered than those of the shoulder and foot slopes.The main pedogenesis in all pedons were through elluviation, illuviation, lessivage, pedoturbation, and gleization processes. The main factors of pedogenesis were climate, age (time and topography factors. Therefore, P1 pedons are classified as Ustic Endoaquerts, fine, smectitic, isohypertermic; P2 as Vertic Endoaquepts, fine, smectitic, isohypertermic; and P3 as Vertic Epiaquepts, fine, smectitic, isohypertermic. Based on the potentials of the land, the highest of land suitability class (LSC of land utilization type (LUT local paddy was highly suitable (S1, while the lowest one was not suitable with nutrient availability as the limiting factor (Nna. The highest LCS of paddy-corn LUT was marginally suitable with water availability as the limiting factor (S3wa, while the lower LSC was not suitable with nutrient availabily as the limiting factor (Nna.

  8. The organic matter of the Potosi basin (Cordillera Oriental, Bolivia) during the Upper Cretaceous-Lower tertiary: stratigraphic and palaeogeographic data

    Energy Technology Data Exchange (ETDEWEB)

    Blanc-Valleron, M.M.; Rouchy, J.M. (Centre National de la Recherche Scientifique (CNRS), 75 - Paris (France)); Schuler, M.; Rauscher, R. (Strasbourg-1 Univ., 67 (France)); Camoin, G. (Aix-Marseille-1 Univ., 13 - Marseille (France))

    1994-12-01

    Palynological and Rock-Eval pyrolysis studies of the Chaunaca and El Molino Fm (Santonian to Thanetian, Cordillera Oriental, Bolivia) indicate that some facies have economic significance as potential oil source rocks. The occurrence of Pediastrum and Azolla testify a lacustrine environment. In the Upper Molino, the environmental interpretation of an almost monospecific association of dinocysts is discussed. The presence of Apectodinium quinquelatum indicates that the age of the upper part of the Upper El Molino Fm is likely to be Upper Thanetian. (authors). 22 refs., 5 figs.

  9. Uranium occurrences in the surficial deposits of Southern Africa

    International Nuclear Information System (INIS)

    Hambleton-Jones, B.B.

    1982-01-01

    This paper outlines the geology of the Tertiary to Recent(10 to 0,1 Ma) surficial uranium deposits in South West Africa/Namibia and South Africa. They occur mainly in the Namib Desert to the east of Walvis Bay in South West Africa/Namibia and in the north-western Cape Province of South Africa. All the deposits can be classified as fluviatile, lacustrine/pan, or pedogenic types. The economic potential of the surficial uranium deposits in the north-western Cape is insignificant compared with their South West African/Namibian counterparts. Most of the deposits occur in gypsiferous fluviatile gravels and lacustrine/pan sediments. The largest of the deposits is a lacustrinal, peat-rich, diatomaceous earth type. The mechanisms for the precipitation of the uranium are discussed

  10. Volcanic influence of Mt. Fuji on the watershed of Lake Motosu and its impact on the lacustrine sedimentary record

    Science.gov (United States)

    Lamair, Laura; Hubert-Ferrari, Aurélia; Yamamoto, Shinya; El Ouahabi, Meriam; Vander Auwera, Jacqueline; Obrochta, Stephen; Boes, Evelien; Nakamura, Atsunori; Fujiwara, Osamu; Shishikura, Masanobu; Schmidt, Sabine; Siani, Giuseppe; Miyairi, Yosuke; Yokoyama, Yusuke; De Batist, Marc; Heyvaert, Vanessa M. A.; QuakeRecNankai Team

    2018-01-01

    Lacustrine sediments are particularly sensitive to modifications within the lake catchment. In a volcanic area, sedimentation rates are directly affected by the history of the volcano and its eruptions. Here, we investigate the impact of Mt. Fuji Volcano (Japan) on Lake Motosu and its watershed. The lacustrine infill is studied by combining seismic reflection profiles and sediment cores. We show evidence of changes in sedimentation patterns during the depositional history of Lake Motosu. The frequency of large mass-transport deposits recorded within the lake decreases over the Holocene. Before 8000 cal yr BP, large sublacustrine landslides and turbidites were filling the lacustrine depression. After 8000 cal yr BP, only one large sublacustrine landslide was recorded. The change in sedimentation pattern coincides with a change in sediment accumulation rate. Over the last 8000 cal yr BP, the sediment accumulation rate was not sufficient enough to produce large sublacustrine slope failures. Consequently, the frequency of large mass-transport deposits decreased and only turbidites resulting from surficial slope reworking occurred. These constitute the main sedimentary infill of the deep basin. We link the change in sediment accumulation rate with (i) climate and vegetation changes; and (ii) the Mt. Fuji eruptions which affected the Lake Motosu watershed by reducing its size and strongly modified its topography. Moreover, this study highlights that the deposition of turbidites in the deep basin of Lake Motosu is mainly controlled by the paleobathymetry of the lakefloor. Two large mass-transport deposits, occurring around 8000 cal yr BP and 2000 cal yr BP respectively, modified the paleobathymetry of the lakefloor and therefore changed the turbidite depositional pattern of Lake Motosu.

  11. Audit of the referred patients to a tertiary centre: a tool for need ...

    African Journals Online (AJOL)

    Audit of the referred patients to a tertiary centre: a tool for need assessment. ... Open Access DOWNLOAD FULL TEXT ... There was no statistical significance between fetal and maternal outcome and the source of referral (P> 0.05). The reason ...

  12. An Investigation of Trace Elements in Marine and Lacustrine Deposits by Means of a Neutron Activation Method

    Energy Technology Data Exchange (ETDEWEB)

    Landstroem, O; Samsahl, K; Wenner, C G

    1967-10-15

    A neutron activation method for multi-elemental analysis was applied to argillaceous deposits from the Viskan Valley on the Swedish West Coast, an area in which transgressions and regressions of the sea have occurred during the postglacial time. These changes between fresh-water and marine stages are well known from earlier geologic investigations. Analysis could therefore be performed of samples of known marine (brackish) and lacustrine origin. In a preliminary test on four samples, taken from two marine layers and two lacustrine layers, altogether 30 elements were quantitatively determined, namely As, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hf, Hg, La, Lu, Mn, Na, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, W, Yb, Zn and Zr. Several elements showed a difference in concentration between the marine and the fresh-water layers. Br, Hg, Mn, Se, As and Sb were more thoroughly investigated in three boreholes from different sections of the valley. Br and Se had high means in the most pronounced marine samples of the fiord deposits. Moreover, Mn showed a fourfold increase just in the transition stage between the older sea fiord and the older lage stage.

  13. An Investigation of Trace Elements in Marine and Lacustrine Deposits by Means of a Neutron Activation Method

    International Nuclear Information System (INIS)

    Landstroem, O.; Samsahl, K.; Wenner, C.G.

    1967-10-01

    A neutron activation method for multi-elemental analysis was applied to argillaceous deposits from the Viskan Valley on the Swedish West Coast, an area in which transgressions and regressions of the sea have occurred during the postglacial time. These changes between fresh-water and marine stages are well known from earlier geologic investigations. Analysis could therefore be performed of samples of known marine (brackish) and lacustrine origin. In a preliminary test on four samples, taken from two marine layers and two lacustrine layers, altogether 30 elements were quantitatively determined, namely As, Br, Ca, Ce, Co, Cr, Cs, Eu, Fe, Ga, Hf, Hg, La, Lu, Mn, Na, Rb, Sb, Sc, Se, Sm, Sr, Ta, Tb, Th, U, W, Yb, Zn and Zr. Several elements showed a difference in concentration between the marine and the fresh-water layers. Br, Hg, Mn, Se, As and Sb were more thoroughly investigated in three boreholes from different sections of the valley. Br and Se had high means in the most pronounced marine samples of the fiord deposits. Moreover, Mn showed a fourfold increase just in the transition stage between the older sea fiord and the older lage stage

  14. Origin of a Tertiary oil from El Mahafir wildcat & geochemical correlation to some Muglad source rocks, Muglad basin, Sudan

    Science.gov (United States)

    Fadul Abul Gebbayin, Omer. I. M.; Zhong, Ningning; Ali Ibrahim, Gulfan; Ali Alzain, Mohamed

    2018-01-01

    Source rock screening analysis was performed on four stratigraphic units from the Muglad basin namely; Abu Gabra, Zarqa, Ghazal, and Baraka formations using pyrolysis and Vitrinite Reflectance (Ro). Results, integrated with the chromatographic and isotopic data from these rocks extracts and a Tertiary oil from El Mahafir-1 wild cat, were used to determine the origin of the oil. A good organic source within the Middle Abu Gabra Formation is observed in wells El Toor-6 and Neem Deep-1 (TOC, 1.0-2.0% & S2 5.0-10.0 mg C/g rock), with mixed kerogens I, II, & III, and thermally mature (% Ro = 0.74-0.94). The Campanian-Early Maastrichtian sequence, i.e. Zarqa and Ghazal formations are generally poor (TOC, diversity, both in space and time and is characterized by dominant algal input at some areas and or stratigraphic intervals [Elevated tricyclics, higher C29/C30 hopanes (0.5-1.14), and relatively low Gammacerane indices (4.6-14.4)], while mixed with abundant terrigenous material at others. A direct correlation between El Mahafir oil and the Abu Gabra extracts is thus inferred based on: its mixed organic source nature, oxic to sub-oxic depositional environment (Pr/Ph 1.22), relatively low C29/C30 hopanes (0.54), low C28 steranes (29%), and a high gammacerane index (20.5). This is largely supported by the maturity modeling results which suggest generation is only from the Abu Gabra at this location.

  15. Lacustrine wetland in an agricultural catchment: nitrogen removal and related biogeochemical processes

    Directory of Open Access Journals (Sweden)

    R. Balestrini

    2008-03-01

    Full Text Available The role of specific catchment areas, such as the soil-river or lake interfaces, in removing or buffering the flux of N from terrestrial to aquatic ecosystems is globally recognized but the extreme variability of microbiological and hydrological processes make it difficult to predict the extent to which different wetlands function as buffer systems. In this paper we evaluate the degree to which biogeochemical processes in a lacustrine wetland are responsible for the nitrate removal from ground waters feeding Candia Lake (Northern Italy. A transect of 18 piezometers was installed perpendicular to the shoreline, in a sub-unit formed by 80 m of poplar plantation, close to a crop field and 30 m of reed swamp. The chemical analysis revealed a drastic NO3-N ground water depletion from the crop field to the lake, with concentrations decreasing from 15–18 mg N/l to the detection limit within the reeds. Patterns of Cl, SO42–, O2, NO2-N, HCO3 and DOC suggest that the metabolic activity of bacterial communities, based on the differential use of electron donors and acceptors in redox reactions is the key function of this system. The significant inverse relationship found between NO3-N and HCO3 is a valuable indicator of the denitrification activity. The pluviometric regime, the temperature, the organic carbon availability and the hydrogeomorphic properties are the main environmental factors affecting the N transformations in the studied lacustrine ecosystem.

  16. Economics of Tertiary Education - Challenges and dynamics of the public tertiary education in Albania

    Directory of Open Access Journals (Sweden)

    Gledian Llatja

    2016-07-01

    Full Text Available The tertiary education is a critic mechanism for the socio-economic progress, for individuals who aspire a brighter future and it is also considered an important catalyzer of the economic mobility (Department of Treasury and Department of Education, 2012, 2. Based on the positive role and impact that the tertiary education has on the sustainable development, President Obama once stated that it is of damage to treat education as a luxurious public service. In line with the general considerations about the tertiary education in the U.S. the parallel comparison with Albania comes as a direct interpretation of utopia in the education policy-making. As policies are usually drafted based on data and findings, in the case of Albania there is a lack of data on expenses on tertiary education as share of GDP. This stands also for the main limitation of the paper.

  17. Greigite formed in early Pleistocene lacustrine sediments from the Heqing Basin, southwest China, and its paleoenvironmental implications

    Science.gov (United States)

    Qiang, Xiaoke; Xu, Xinwen; Zhao, Hui; Fu, Chaofeng

    2018-05-01

    The ferrimagnetic iron sulfide greigite (Fe3S4) occurs widely in sulfidic lacustrine and marine sedimentary environments. Knowledge of its formation and persistence is important for both magnetostratigraphic and paleoenvironmental studies. Although the formation mechanism of greigite has been widely demonstrated, the sedimentary environments associated with greigite formation in lakes, especially on relatively long timescales, are poorly understood. A long and continuous sequence of Pleistocene lacustrine sediments was recovered in the Heqing drill core from southwestern China, which provides an outstanding record of continental climate and environment. Integrated magnetic, geochemical, and paleoclimatic analysis of the lacustrine sequence provides an opportunity to improve our understanding of the environmental controls on greigite formation. Rock magnetic and scanning electron microscope analyses of selected samples from the core reveal that greigite is present in the lower part of the core (part 1, 665.8-372.5 m). Greigite occurs throughout this interval and is the dominant magnetic mineral, irrespective of the climatic state. The magnetic susceptibility (χ) record, which is mainly controlled by the concentration of greigite, matches well with variations in the Indian Summer Monsoon (ISM) index and total organic carbon (TOC) content, with no significant time lag. This indicates that the greigite formed during early diagenesis. In greigite-bearing intervals, with the χ increase, Bc value increase and tends to be stable at about 50 mT. Therefore, we suggest that χ values could estimate the variation of greigite concentration approximately in the Heqing core. Greigite favored more abundant in terrigenous-rich and organic-poor layers associated with weak summer monsoon which are characterized by high χ values, high Fe content, high Rb/Sr ratio and low TOC content. Greigite enhancement can be explained by variations in terrigenous inputs. Our studies demonstrate

  18. Lacustrine Records of Holocene Mountain Glacier Fluctuations from Western Greenland

    Science.gov (United States)

    Schweinsberg, A.; Briner, J. P.; Bennike, O.

    2014-12-01

    Recent studies have focused on documenting fluctuations of the Greenland Ice Sheet margin throughout the Holocene but few data exist that constrain past changes of local glaciers independent of the ice sheet. Our research combines proglacial lake sediment analysis with cosmogenic 10Be dating of Holocene moraines and radiocarbon dating of ice-cap-killed vegetation with an overall objective to use this multi-proxy approach to generate a detailed record of the coupled climate-glacier system through the Holocene. Here, we present lacustrine records of mountain glacier variability from continuous pro-glacial lake sediment sequences recovered from two glaciated catchments in northeastern Nuussuaq, western Greenland. We use radiocarbon-dated sediments from Sikuiui and Pauiaivik lakes to reconstruct the timing of advance and retreat of local glaciers. Sediments were characterized with magnetic susceptibility (MS), gamma density, Itrax XRF and visible reflectance spectroscopy at 0.2 cm intervals and sediment organic matter at 0.5 cm intervals. Basal radiocarbon ages provide minimum-age constraints on deglaciation from Sikuiui and Pauiaivik lakes of ~9.6 and 8.7 ka, respectively. Organic-rich gyttja from deglaciation until ~5.0 ka in Pauiaivik Lake suggests minimal glacial extent there while slightly elevated MS values from ~9.0 - 7.0 ka in Sikuiui Lake may reflect early Holocene glacial advances. Minerogenic sediment input gradually increases starting at ~5.0 ka in Pauiaivik Lake, which we interpret as the onset of Neoglaciation in the catchment. Furthermore, a distinct episode of enhanced glacial activity from ~4.0 - 2.2 ka in Sikuiui Lake may be correlative to a period of persistent snowline lowering evidenced by radiocarbon dates of ice-killed vegetation from nearby ice cap margins. Results from these lacustrine records and our ice-killed vegetation dataset suggest a middle Holocene onset of Neoglaciation ~5.0 - 4.0 ka in this region. We are supplementing these records

  19. Chemical Properties, Decomposition, and Methane Production of Tertiary Relict Plant Litters: Implications for Atmospheric Trace Gas Production in the Early Tertiary

    Science.gov (United States)

    Yavitt, J. B.; Bartella, T. M.; Williams, C. J.

    2006-12-01

    Throughout the early Tertiary (ca. 65-38 Ma) Taxodiaceae-dominated (redwood) wetland forests occupied the high latitudes and were circumpolar in their distribution. Many of these forests had high standing biomass with moderate primary productivity. The geographic extent and amount of Tertiary coals and fossil forests throughout Arctic Canada suggests large areas of wetland forests that may have cycled substantial quantities of carbon, particularly methane until they were replaced by cold tolerant Pinus, Picea, and Larix following climatic cooling associated with the Terminal Eocene Event. To test this hypothesis we compared physiochemical properties, decomposition, and trace gas production of litter from extant Metasequoia, Pinus, Picea, and Larix. Initial results from plantation-grown trees indicate Metasequoia litter is a better source of labile organic substrate than pinaceous litter. Metasequoia litter contained the least lignin and highest amounts of water-soluble compounds of the four litter types studied. Analysis of the lignin structure using cupric oxide oxidation indicates that Metasequoia lignin is enriched in 4'-hydroxyacetophenone and 4'- Hydroxy-3'-methoxyacetophenone relative to the pinaceous litter. In a 12-month decomposition study using litterbags, average litter mass loss was greater for Metasequoia litter (62%) compared to the pinaceous species (50%). Moreover, Metasequoia litter incubated under anoxic conditions produced nearly twice as much CO2 (ca. 4.2 umol/g.day) and CH4 (2.1 umol/g.day) as the pinaceous litter (2.4 umol/g.day for CO2; 1.2 umol/g.day for CH4). Our results support the idea of greater decomposability and palatability of Metasequoia litter as compared to Larix, Picea, or Pinus. Provided that the biochemical properties of Metasequoia have remained relatively stable through geologic time, it appears that early Tertiary Metasequoia-dominated wetland forests may have had higher microbial driven trace gas production than the

  20. Tertiary climatic fluctuations and methods of analysis of tertiary floras

    Science.gov (United States)

    Wolfe, J.A.

    1971-01-01

    On theoretical grounds, an analysis of the physiognomy of a Tertiary leaf assemblage is more direct and reliable than a circuitous floristic analysis in assigning thermal regimes to fossil assemblages. Using primarily foliar physiognomy and secondarily floristic composition, it can be shown that: (1) some middle latitude Tertiary assemblages probably lived under meteoroligically tropical climates; (2) a major and rapid climatic deterioration occurred in the Oligocene; and (3) a major climatic fluctuation probably occurred in the Late Eocene. These analyses thus substantiate the conclusions of several other paleobotanists regarding climatic fluctuations. Recent criticisms of these analyses are shown to be invalid and to be based largely on misinterpretations. ?? 1971.

  1. Hydrochemical synthesis Northern Switzerland: tertiary- and Malm-aquifers

    International Nuclear Information System (INIS)

    Schmassmann, H.; Kullin, M.; Wexsteen, P.

    1990-05-01

    This Tertiary-Malm synthesis represents the first part of an overall hydrochemical synthesis of deep groundwaters in Northern Switzerland and adjacent areas. The investigation is mainly based on data from Nagra deep boreholes, from Nagra regional programme as well as from external sources. The first part provides a hydrogeological overview including a brief description of the aquifer rocks. A compilation of all existing hydraulic potential data is given and discussed for Northern Switzerland, Bodensee area and western Swabian Alb. In the Molasse Basin, hydrochemical and isotope analyses allowed a distinction of three main water types positioned one upon another: calcium-magnesium-bicarbonate groundwaters, sodium-bicarbonate and sodium-chloride deep groundwaters. Hydrochemical and isotopegeochemical details of these three water types comprise the major part of this report. Unlike the other two water types, the calcium-magnesium-bicarbonate groundwaters also include shallow waters with considerable tritium activities, indicating a mean residence time of less than 35 years. The spacial distribution of these three water types are demonstrated and different secular flow models in the Tertiary-Malm Aquifer group are discussed. (author) figs., tabs., 194 refs

  2. Biostratigraphical correlation of a new interglacial lacustrine deposit from Lind, western Jutland, Denmark

    DEFF Research Database (Denmark)

    Odgaard, Bent Vad; Krohn, Charlotte Fog; Kronborg, Christian

    2008-01-01

    and animal macrofossils and two cores were secured from the central part of the basin where the lacustrine deposits have a thickness of about 15 m. The stratigraphy of the deposit can be subdivided into unit A: a lake marl (4 m) superimposed by 3 metres of diatomite and sealed by a thin diamicton. On top...... of unit A follows unit B: 4 metres of gyttja, calcareous at the basal part and sealed by 40 cm of clay. Finally unit C on top of unit B is represented by 1.5 metres of gyttja. The pollen record of unit A can be correlated to the classical Danish record from the nearby Harreskov site (Andersen 1965...

  3. Palaeoenvironments during MIS 3 and MIS 2 inferred from lacustrine intercalations in the loess-palaeosol sequence at Bobingen (southern Germany)

    Science.gov (United States)

    Mayr, Christoph; Matzke-Karasz, Renate; Stojakowits, Philipp; Lowick, Sally E.; Zolitschka, Bernd; Heigl, Tanja; Mollath, Richard; Theuerkauf, Marian; Weckend, Marc-Oliver; Bäumler, Rupert; Gregor, Hans-Joachim

    2017-12-01

    Recently exposed loess-palaeosol sequences in the northern Alpine foreland close to Bobingen (southern Germany) were investigated with a multi-proxy approach combining isotopic, geochemical, lithological, and micropalaeontological methods. Luminescence ages date the sections into the Middle and Upper Würmian periods corresponding to Marine Isotope Stages 3 and 2. A gleyic soil horizon at the base was dated to 45 ka and provided a palynoflora dominated by Poaceae, Cyperaceae, and Pinus, as well as frequent aquatic taxa. Lacustrine conditions prevailed after the gley formation until 30 ka, providing a comparatively diverse lacustrine fauna dominated by aquatic gastropods and the ostracod species Candona candida. At the transition to the Upper Würm, climatic conditions became harsh, indicated by accelerated deposition of more coarse-grained loess, organic geochemical indicators, and scarceness of biotic remains. Two tundra-gley horizons in the Upper Würm point to short phases of climatic amelioration with higher humidity also evidenced by reoccurrence of ostracod and aquatic gastropod remains. We propose that these climatic ameliorations were coincident with the Greenland interstadials 4 and 2.

  4. The lacustrine sediment record of Oberwinkler Maar (Eifel, Germany): Chironomid and macro-remain-based inferences of environmental changes during Oxygen Isotope Stage 3

    NARCIS (Netherlands)

    Engels, S.; Bohncke, S.J.P.; Heiri, O.; Schaber, K.; Sirocko, F.

    2008-01-01

    The lacustrine record of Oberwinkler Maar (Eifel, Germany) is the northernmost continuous record documenting the Weichselian Pleniglacial in central Europe - a period characterized by multiple abrupt climate oscillations known as the Dansgaard/Oeschger cycles. Here, the results of a high-resolution

  5. A comparison of geochemical features of extracts from coal-seams source rocks with different polarity solvents

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Jianping; Deng, Chunping; Wang, Huitong

    2009-02-15

    There exists a great difference in group-type fractions and biomarker distributions of chloroform extracts from coals and coal-seams oils, which makes the source identification of coal-seams oils in sedimentary basins rather difficult. The experiment, in which four different polarity solvents, n-hexane, benzene, dichloromethane and chloroform, were used to extract 9 coal-seams source rocks and 3 typical lacustrine source rocks, showed that the yield of extracts increased gradually with increasing solvent polarity. The distribution features of their n-alkanes, isoprenoids and sterane and terpane biomarkers remained, in general, similar, showing no distinct enrichment or depletion for a certain fraction by any solvent. The compositional analysis on n-hexane and chloroform extracts showed that the absolute amount (concentration) of biomarkers was relatively low for the n-hexane extract but comparatively high for the chloroform extract, this difference became great among coal-seams source rocks but small among lacustrine mudstones. The statistical analysis on the relative amount of the 18 major biomarkers in n-hexane and chloroform extracts from 10 source rock samples showed that extracts with a proportional error for the same biomarker of less than 5% (including the analytical error) accounted for 84% while those with a proportional error over 10% amounted to below 5%. This suggested that the outcome of oil-source correlation made by these biomarkers will be independent of variations in amounts of saturates and biomarkers arising from solvent polarity. Therefore, biomarkers obtained from organic-rich source rocks including coals by the extraction with the commonly used chloroform solvent can be applied for the oilsource correlation of coal-seams petroliferous basins.

  6. Soft-sediment deformation structures in cores from lacustrine slurry deposits of the Late Triassic Yanchang Fm. (central China

    Directory of Open Access Journals (Sweden)

    Yang Renchao

    2016-09-01

    Full Text Available The fine-grained autochthonous sedimentation in the deep part of a Late Triassic lake was frequently interrupted by gravity-induced mass flows. Some of these mass flows were so rich in water that they must have represented slurries. This can be deduced from the soft-sediment deformation structures that abound in cores from these lacustrine deposits which constitute the Yanchang Fm., which is present in the Ordos Basin (central China.

  7. Cryptosporidium and Giardia removal by secondary and tertiary wastewater treatment.

    Science.gov (United States)

    Taran-Benshoshan, Marina; Ofer, Naomi; Dalit, Vaizel-Ohayon; Aharoni, Avi; Revhun, Menahem; Nitzan, Yeshayahu; Nasser, Abidelfatah M

    2015-01-01

    Wastewater disposal may be a source of environmental contamination by Cryptosporidium and Giardia. This study was conducted to evaluate the prevalence of Cryptosporidium oocysts and Giardia cysts in raw and treated wastewater effluents. A prevalence of 100% was demonstrated for Giardia cysts in raw wastewater, at a concentration range of 10 to 12,225 cysts L(-1), whereas the concentration of Cryptosporidium oocysts in raw wastewater was 4 to 125 oocysts L(-1). The removal of Giardia cysts by secondary and tertiary treatment processes was greater than those observed for Cryptosporidium oocysts and turbidity. Cryptosporidium and Giardia were present in 68.5% and 76% of the tertiary effluent samples, respectively, at an average concentration of 0.93 cysts L(-1) and 9.94 oocysts L(-1). A higher detection limit of Cryptosporidium oocysts in wastewater was observed for nested PCR as compared to immune fluorescent assay (IFA). C. hominis was found to be the dominant genotype in wastewater effluents followed by C. parvum and C. andersoni or C. muris. Giardia was more prevalent than Cryptosporidium in the studied community and treatment processes were more efficient for the removal of Giardia than Cryptosporidium. Zoonotic genotypes of Cryptosporidium were also present in the human community. To assess the public health significance of Cryptosporidium oocysts present in tertiary effluent, viability (infectivity) needs to be assessed.

  8. Late Tertiary and Quaternary geology of the Tecopa basin, southeastern California

    Energy Technology Data Exchange (ETDEWEB)

    Hillhouse, J.W.

    1987-12-31

    Stratigraphic units in the Tecopa basin, located in southeastern California, provide a framework for interpreting Quaternary climatic change and tectonism along the present Amargosa River. During the late Pliocene and early Pleistocene, a climate that was appreciably wetter than today`s sustained a moderately deep lake in the Tecopa basin. Deposits associated with Lake Tecopa consists of lacustrine mudstone, conglomerate, volcanic ash, and shoreline accumulations of tufa. Age control within the lake deposits is provided by air-fall tephra that are correlated with two ash falls from the Yellowstone caldera and one from the Long Valley caldera. Lake Tecopa occupied a closed basin during the latter part, if not all, of its 2.5-million-year history. Sometime after 0.5 m.y. ago, the lake developed an outlet across Tertiary fanglomerates of the China Ranch Beds leading to the development of a deep canyon at the south end of the basin and establishing a hydrologic link between the northern Amargosa basins and Death Valley. After a period of rapid erosion, the remaining lake beds were covered by alluvial fans that coalesced to form a pediment in the central part of the basin. Holocene deposits consist of unconsolidated sand and gravel in the Amargosa River bed and its deeply incised tributaries, a small playa near Tecopa, alluvial fans without pavements, and small sand dunes. The pavement-capped fan remnants and the Holocene deposits are not faulted or tilted significantly, although basins to the west, such as Death Valley, were tectonically active during the Quaternary. Subsidence of the western basins strongly influenced late Quaternary rates of deposition and erosion in the Tecopa basin.

  9. Sources for sedimentary bacteriohopanepolyols as revealed by 16S rDNA stratigraphy.

    Science.gov (United States)

    Coolen, Marco J L; Talbot, Helen M; Abbas, Ben A; Ward, Christopher; Schouten, Stefan; Volkman, John K; Damsté, Jaap S Sinninghe

    2008-07-01

    Bacteriohopanoids are widespread lipid biomarkers in the sedimentary record. Many aerobic and anaerobic bacteria are potential sources of these lipids which sometimes complicates the use of these biomarkers as proxies for ecological and environmental changes. Therefore, we applied preserved 16S ribosomal RNA genes to identify likely Holocene biological sources of bacteriohopanepolyols (BHPs) in the sulfidic sediments of the permanently stratified postglacial Ace Lake, Antarctica. A suite of intact BHPs were identified, which revealed a variety of structural forms whose composition differed through the sediment core reflecting changes in bacterial populations induced by large changes in lake salinity. Stable isotopic compositions of the hopanols formed from periodic acid-cleaved BHPs, showed that some were substantially depleted in (13)C, indicative of their methanotrophic origin. Using sensitive molecular tools, we found that Type I and II methanotrophic bacteria (respectively Methylomonas and Methylocystis) were unique to the oldest lacustrine sediments (> 9400 years BP), but quantification of fossil DNA revealed that the Type I methanotrophs, including methanotrophs related to methanotrophic gill symbionts of deep-sea cold-seep mussels, were the main precursors of the 35-amino BHPs (i.e. aminopentol, -tetrol and -triols). After isolation of the lake approximately 3000 years ago, one Type I methanotroph of the 'methanotrophic gill symbionts cluster' remained the most obvious source of aminotetrol and -triol. We, furthermore, identified a Synechococcus phylotype related to pelagic freshwater strains in the oldest lacustrine sediments as a putative source of 2-methylbacteriohopanetetrol (2-Me BHT). This combined application of advanced geochemical and paleogenomical tools further refined our knowledge about Holocene biogeochemical processes in Ace Lake.

  10. Linking groundwater dissolved organic matter to sedimentary organic matter from a fluvio-lacustrine aquifer at Jianghan Plain, China by EEM-PARAFAC and hydrochemical analyses.

    Science.gov (United States)

    Huang, Shuang-bing; Wang, Yan-xin; Ma, Teng; Tong, Lei; Wang, Yan-yan; Liu, Chang-rong; Zhao, Long

    2015-10-01

    The sources of dissolved organic matter (DOM) in groundwater are important to groundwater chemistry and quality. This study examined similarities in the nature of DOM and investigated the link between groundwater DOM (GDOM) and sedimentary organic matter (SOM) from a lacustrine-alluvial aquifer at Jianghan Plain. Sediment, groundwater and surface water samples were employed for SOM extraction, optical and/or chemical characterization, and subsequent fluorescence excitation-emission matrix (EEM) and parallel factor analyses (PARAFAC). Spectroscopic properties of bulk DOM pools showed that indices indicative of GDOM (e.g., biological source properties, humification level, aromaticity and molecule mobility) varied within the ranges of those of two extracted end-members of SOM: humic-like materials and microbe-associated materials. The coexistence of PARAFAC compositions and the sustaining internal relationship between GDOM and extracted SOM indicate a similar source. The results from principal component analyses with selected spectroscopic indices showed that GDOM exhibited a transition trend regarding its nature: from refractory high-humification DOM to intermediate humification DOM and then to microbe-associated DOM, with decreasing molecular weight. Correlations of spectroscopic indices with physicochemical parameters of the groundwater suggested that GDOM was released from SOM and was modified by microbial diagenetic processes. The current study demonstrated the associations of GDOM with SOM from a spectroscopic viewpoint and provided new evidence supporting SOM as the source of GDOM. Copyright © 2015 Elsevier B.V. All rights reserved.

  11. Diversification Management at Tertiary Education Level: A Review

    Science.gov (United States)

    Takwate, Kwaji Tizhe

    2016-01-01

    This paper examines the concept of management of diversification at tertiary education level in view of the growth of national secondary education system which vested high scramble for tertiary education was made in relation to question of access and expansion. This paper examines management of diversification at tertiary education level as a…

  12. Impacts of shore expansion and catchment characteristics on lacustrine thermokarst records in permafrost lowlands, Alaska Arctic Coastal Plain

    Science.gov (United States)

    Lenz, Josefine; Jones, Benjamin M.; Wetterich, Sebastian; Tjallingii, Rik; Fritz, Michael; Arp, Christopher D.; Rudaya, Natalia; Grosse, Guido

    2016-01-01

    Arctic lowland landscapes have been modified by thermokarst lake processes throughout the Holocene. Thermokarst lakes form as a result of ice-rich permafrost degradation, and they may expand over time through thermal and mechanical shoreline erosion. We studied proximal and distal sedimentary records from a thermokarst lake located on the Arctic Coastal Plain of northern Alaska to reconstruct the impact of catchment dynamics and morphology on the lacustrine depositional environment and to quantify carbon accumulation in thermokarst lake sediments. Short cores were collected for analysis of pollen, sedimentological, and geochemical proxies. Radiocarbon and 210Pb/137Cs dating, as well as extrapolation of measured historic lake expansion rates, were applied to estimate a minimum lake age of ~1400 calendar years BP. The pollen record is in agreement with the young lake age as it does not include evidence of the “alder high” that occurred in the region ~4000 cal yr BP. The lake most likely initiated from a remnant pond in a drained thermokarst lake basin (DTLB) and deepened rapidly as evidenced by accumulation of laminated sediments. Increasing oxygenation of the water column as shown by higher Fe/Ti and Fe/S ratios in the sediment indicate shifts in ice regime with increasing water depth. More recently, the sediment source changed as the thermokarst lake expanded through lateral permafrost degradation, alternating from redeposited DTLB sediments, to increased amounts of sediment from eroding, older upland deposits, followed by a more balanced combination of both DTLB and upland sources. The characterizing shifts in sediment sources and depositional regimes in expanding thermokarst lakes were, therefore, archived in the thermokarst lake sedimentary record. This study also highlights the potential for Arctic lakes to recycle old carbon from thawing permafrost and thermokarst processes.

  13. Climatic instability before the Miocene Climatic Optimum reflected in a Central European lacustrine record from the Most Basin in the Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Matys Grygar, Tomáš; Hošek, Michal; Mach, K.; Schnabl, Petr; Martinez, M.

    2017-01-01

    Roč. 485, NOV (2017), s. 930-945 ISSN 0031-0182 R&D Projects: GA ČR(CZ) GA16-00800S Institutional support: RVO:61388980 ; RVO:67985831 Keywords : Chemostratigraphy * Cyclostratigraphy * Lacustrine * Magnetostratigraphy * MCO * Siliciclastic Subject RIV: DD - Geochemistry; DB - Geology ; Mineralogy (GLU-S) OBOR OECD: Geology Impact factor: 2.578, year: 2016

  14. Chapter F: Preliminary Bibliography of Lacustrine Diatomite Deposits in the Western United States and Related Topics

    Science.gov (United States)

    Bolm, Karen S.; Wallace, Alan R.; Moyle, Phillip R.; Bliss, James D.; Orris, Greta J.

    2003-01-01

    Introduction As part of the assessment of lacustrine diatomite resources in the Western United States (fig. 1), U.S. Geological Survey (USGS) project members conducted a review of literature relating to the formation, location, and nature of deposits in the study area. This preliminary bibliography consists of selected publications to identify, locate, and describe the deposits to be studied, to characterize common geologic factors about the deposits, and to better understand the factors that control their formation, preservation, or destruction. The bibliography also serves as a resource for other workers to research the topic. References included in the preliminary bibliography were gathered by searching existing bibliographic data bases and library collections. Project researchers also contributed references that they found during the course of their work. This bibliography should be considered a working document that will grow as research and literature searches continue. Clearly, many significant publications may be missing from this preliminary list; therefore, USGS staff members intend to issue a revised bibliography as project work progresses. To assure completeness, input from other researchers and industry is welcome. Although the focus of this bibliography is lacustrine diatomite deposits of the Western United States, additional references that provide a foundation of knowledge for the study of diatomites, diatoms, and diatom-related processes (ecology, geology, geochemistry) and for the uses and behavior of diatomite have also been included. An index of keywords has been added to this bibliography, designed to help the user locate reports by topic or by geographic location. The letter 'A' following a number indicates that the report referenced is an abstract.

  15. Lacustrine basin evolution and coal accumulation of the Middle Jurassic in the Saishiteng coalfield, northern Qaidam Basin, China

    Directory of Open Access Journals (Sweden)

    Meng Li

    2016-07-01

    Full Text Available Based on an extensive borehole survey of the Middle Jurassic coal-bearing sequences in the Saishiteng coalfield, northern Qaidam Basin (NQB, a total of 20 rock types and 5 sedimentary facies were identified, including braided river, meandering river, braided delta, meandering river delta, and lacustrine facies. The distribution of rock types and sedimentary facies contributed to the reconstruction of three periods' sedimentary facies maps of the Middle Jurassic in the Saishiteng coalfield, namely, the Dameigou age, the early Shimengou age and the late Shimengou age. That also provided the basis for the development of a three-stage depositional model of the Middle Jurassic in the NQB, indicating the lacustrine basin of the NQB in the Dameigou age and early Shimengou age were corresponding to an overfill basin, and that in the late Shimengou age was related to a balanced-fill basin. The analysis of the stability and structure of coal seams based on sedimentary facies maps showed that the preferred coal-forming facies in the Saishiteng coalfield were inter-delta bay and interdistributary bay of lower delta plain in the Dameigou age. In particular, the swamps that developed on the subaqueous palaeohigh favored the development of thick coal seams. Thus, minable coal seams may also be found along the Pingtai palaeohigh in the western part of the Saishiteng coalfield.

  16. Changing Destinations: Ideal Attraction and Actual Movement of Cross-Border Tertiary Students from Mainland China

    Science.gov (United States)

    Ghazarian, Peter G.

    2014-01-01

    Globalization has driven growth in the market for cross-border students. Mainland China, with a burgeoning economy and the largest national population, has become an important source of cross-border students. This study identifies ideal attraction in mainland China to destinations for cross-border tertiary education, as expressed by ideal first…

  17. Types of soft-sediment deformation structures in a lacustrine Ploužnice member (Stephanian, Gzhelian, Pennsylvanian, Bohemian Massif), their timing, and possible trigger mechanism

    Czech Academy of Sciences Publication Activity Database

    Stárková, M.; Martínek, K.; Mikuláš, Radek; Rosenau, N.

    2015-01-01

    Roč. 104, č. 5 (2015), s. 1277-1298 ISSN 1437-3254 Institutional support: RVO:67985831 Keywords : soft-sediment deformation structures * bioturbation * early diagenetic carbonate * lacustrine facies * Bohemian Massif * Stephanian C * Krkonoše Piedmont Basin Subject RIV: DB - Geology ; Mineralogy Impact factor: 2.133, year: 2015

  18. Seepage characteristics of the second tertiary combined model

    Directory of Open Access Journals (Sweden)

    Huan ZHAO

    2015-08-01

    Full Text Available The second tertiary combined model experiment zone has been developed in Block B, Field L. The percolation feature of the second tertiary combined develop model shows great importance to rational and efficient development of the reservoir. In order to clearly illuminate its percolation feature, the typical reservoir numerical model is built by Eclipse, which is a reservoir numerical simulation software. The percolation features of original and added perforation interval under the second tertiary combined model are studied, and the variation features of general water-cut, recovery percentage, wellbore pressure, reservoir pressure and water saturation on condition of higher injection rate under the second tertiary combined model are analyzed. The research indicates that the second tertiary combined enhances the recovery of remaining oil on top of thick reservoir by developing and enhancing original perforation interval under water drive, then improves development results by polymer flooding, and gains higher recovery rate by synthetic action of water driver and polymer flooding.

  19. Maintenance management sourcing strategies and the condition of ...

    African Journals Online (AJOL)

    In the face of the deplorable state of buildings across the various tertiary institutions in Nigeria, the need to deploy appropriate maintenance management strategy cannot be overemphasized. However, sourcing decision for maintenance services remains a tough one for decision makers as different sourcing option suit ...

  20. EXPLORING THE TERTIARY EFL STUDENTS' ACADEMIC WRITING COMPETENCIES

    Directory of Open Access Journals (Sweden)

    Aunurrahman Aunurrahman

    2017-05-01

    Full Text Available For tertiary English as a Foreign Language (EFL students, academic writing is not an easy task. It requires knowledge of the academic writing genres with their particular linguistic features. Moreover, academic writing demands good critical thinking. This research aims to explore the students' academic writing competencies that also focus on critical thinking. The research involved thirty-six first-year tertiary EFL students from a regular class of a private university in Pontianak, West Kalimantan, Indonesia. The source for data collection was the students’ texts. Three texts were selected and the students were categorized into low, medium, and high levels of writing achievement. The text analysis utilized functional grammar rooted in systemic functional linguistics (Emilia, 2014. The analysis shows that the students, regardless of their levels of writing achievement, have little control over the schematic structure and linguistic features of an argumentative writing. The text analysis also shows that the students’ texts have some limitations as regards their critical thinking capacity. Still, a few examples of academic language were detected in the texts. The findings suggest that the lecturer should incorporate explicit teaching and cooperative learning activities to alleviate the students' difficulties and develop their academic writing and critical thinking capacity.

  1. SECTORAL ANALYSIS: GROWTH ACCOUNTING OF TERTIARY INDUSTRIES

    Directory of Open Access Journals (Sweden)

    Yahya Z. ALSHEHHI

    2017-08-01

    Full Text Available The tertiary sector is one of the modern styles of economic systems in view of the share it occupies in the field of production as well as employment occupied share. Hence, just like other lands, the UAE, witnessed an economic structural change similar to developed and developing nations, where the tertiary industries contributed 55.4% in 2015 to total country’s income. The empirical study aimed to analyze the contribution portion of growth in the tertiary industries through using the growth accounting framework in time-series from 1990 to 2015. The empirical study found that most of the industries contributed significantly to the growth of the tertiary sector. The contribution shares of growth due to labor and capital varied among industries. The main observed results show that there was a vice versa relationship between TFP performance and the size of labor, where the TFP positively corresponded with the decline in the size of labor specifically from 2010-2015.

  2. Late Holocene monsoon climate as evidenced by proxy records from a lacustrine sediment sequence in western Guangdong, South China

    Science.gov (United States)

    Zhong, Wei; Cao, jiayuan; Xue, Jibin; Ouyang, Jun; Tang, Xiaohong; Yin, Huanling; Liao, Congyun; Long, Kun

    2014-02-01

    The study of a 300-cm-thick exposed lacustrine sediment section in the Hedong village in Zhaoqing area which is located in sub-tropical west Guangdong Province in South China, demonstrates that the lacustrine sedimentary sequence possibly contains evidence for exploring variation of Asian monsoon climate. Multi-proxy records, including the humification intensity, total organic carbon, and grain size fractions, reveal a general trend towards dry and cold conditions in the late Holocene that this is because of a decrease in solar insolation on an orbital scale. Three intensified Asian summer monsoon (ASM) intervals (˜3300-3000 cal yr BP, ˜2600-1600 cal yr BP, and ˜900-600 cal yr BP), and three weakened ASM intervals (˜4000-3300 cal yr BP, ˜3000-2600 cal yr BP, and ˜1600-900 cal yr BP) are identified. Our humification record (HDcal) shows a good correlation on multi-centennial scale with the tree ring Δ14C record, a proxy of solar activity. A spectral analysis of HDcal reveals four significant cycles, i.e., ˜1250 yr, 300 yr, 110 yr, and 70 yr, and most of these cycles are related to the solar activity. Our findings indicate that solar output and oceanic-atmospheric circulation probably have influenced the late Holocene climate variability in the study region.

  3. Angola: source rock control for Lower Congo Coastal and Kwanza Basin petroleum systems

    Energy Technology Data Exchange (ETDEWEB)

    Burwood, R. [Fina Exploration Ltd, Epsom (United Kingdom)

    1999-07-01

    The purpose of this paper is to provide an overview of petroleum occurrence and provenance for the 1000 km West African Atlantic Margin from Cabinda to mid-Angola. Over this margin the Lower Congo Coastal and Kwanza provinces cumulatively account for reserves of c. 6 gigabarrels oil recoverable (GBOR). These are dominantly reservoired in Pinda carbonate traps of the former basin. However, with production from a range of aggradational wedge, carbonate platform and pre-salt reservoirs, a diversity in oil character presupposes complex hydrocarbon habitats charged by multiple sourcing. Each of these two major Atlantic margin salt basins constitutes a different, source rock driven, hydrocarbon habitat. As classic passive margin pull-apart basins, Early Cretaceous initiated rift events (Pre-rift, Syn-rift I, II, etc.) evolved into the drift phase opening of the southern Atlantic. A striking feature of this progression was widespread evaporite deposition of the Aptian Loeme salt. This separates two distinct sedimentary and tectonic domains of the Pre- and Post-Salt. The core Lower Congo Coastal habitat is dominated by the Pre-Salt Bucomazi Formation sourced 'poly' petroleum system. These lacustrine, often super-rich, sediments reveal considerable organofacies variation between their basin fill (Syn-rift I) and sheet drape (Syn-rift II) development, accounting for the compositional diversity in their progenic petroleums. Of crucial impact is a cognate diversity in their kerogen kinetic behaviour. This controls the conditions and timing of generation and realization of charge potential. With the Lower Congo Coastal habitat extending southwards towards the Ambriz Spur, the Bucomazi facies proper appears restricted to the northern and deeper proto-lake trend. Over the more weakly subsident margins such troughs host inferior sheet drape potential. Elswhere, Upper Cretaceous-Palaeogene marine clastic Iabe Formation sourced petroleum systems are hydrocarbon productive

  4. In-situ monitoring of deformation of clayey and volcanic sequences in the lacustrine plain of Iztapalapa, Mexico City

    Science.gov (United States)

    Carreon-Freyre, D.; Cerca, M.; Barrientos, B.; Gutierrez, R.; Blancas, D.

    2012-12-01

    Major cities of Central Mexico with lowering of land elevation problems are located in inter-volcanic and fault bounded basins within the central Trans-Mexican Volcanic Belt (TMVB). The most representative and studied case of ground deformation is Mexico City, where the Iztapalapa Municipality presents the highest population density. This area is located over the geological contact between the "Sierra de Santa Catarina" volcanic range and a lacustrine plain. Filling of lacustrine basins includes silty and clayey sediments as well as pyroclastic deposits (coarse and fine grained) and volcanic rocks layers. We used Ground Penetrating Radar (GPR) and MASW prospection to evaluate contrasts in the physical properties of fine grained soils and identify geometry of the deformational features and implemented a mechanical system for in situ monitoring in fractured sites. Deformational features in this basin reflect an interplay between the geological history (depositional conditions), load history, seismic activity, and faulting. Plastic mechanical behaviour predominates in these clayey sediments and differential deformation locally triggers brittle fracturing and/or subsidence of the surface. In this work we present the results of monitoring and characterization of ground deformation and fracturing in different sequences, our results show a dynamic interplay between the mechanisms of ground fracturing and the stress history of sedimentary sequences. Relating the mechanical behaviour of the studied sequences with variations of physical and geological properties should be taken into account to estimate land level lowering and risk of fracturing for urban development planning.

  5. Earthquake-induced soft-sediment deformation structures in Late Pleistocene lacustrine deposits of Issyk-Kul lake (Kyrgyzstan)

    Science.gov (United States)

    Gladkov, A. S.; Lobova, E. U.; Deev, E. V.; Korzhenkov, A. M.; Mazeika, J. V.; Abdieva, S. V.; Rogozhin, E. A.; Rodkin, M. V.; Fortuna, A. B.; Charimov, T. A.; Yudakhin, A. S.

    2016-10-01

    This paper discusses the composition and distribution of soft-sediment deformation structures induced by liquefaction in Late Pleistocene lacustrine terrace deposits on the southern shore of Issyk-Kul Lake in the northern Tien Shan mountains of Kyrgyzstan. The section contains seven deformed beds grouped in two intervals. Five deformed beds in the upper interval contain load structures (load casts and flame structures), convolute lamination, ball-and-pillow structures, folds and slumps. Deformation patterns indicate that a seismic trigger generated a multiple slump on a gentle slope. The dating of overlying subaerial deposits suggests correlation between the deformation features and strong earthquakes in the Late Pleistocene.

  6. Analysis of soft-sediment deformation structures in Neogene fluvio-lacustrine deposits of Çaybağı Formation, Eastern Turkey

    Science.gov (United States)

    Koç Taşgin, Calibe; Türkmen, İbrahim

    2009-06-01

    During the Neogene, both strike-slip and extensional regimes coexisted in eastern Turkey and, a number of fault-bounded basins associated with the East Anatolian Fault System developed. The Çaybağı Formation (Late Miocene-Early Pliocene) deposited in one of these basins consists of fluvio-lacustrine deposits. Numerous soft-sediment deformation structures are encountered in this formation, particularly in conglomerates, medium- to coarse-grained tuffaceous sandstones and claystones: folded structures (slumps, convolute laminations, and simple recumbent folds), water-escape structures (intruded sands, internal cusps, interpenetrative cusps and sand volcanoes), and load structures (load casts, pseudonodules, flame structures, and pillow structures). These structures are produced by liquefaction and/or fluidization of the unconsolidated sediments during a seismic shock. Consequently, the existence of seismically-induced deformation structures in the Çaybağı Formation and the association with a Neogene intraformational unconformity, growth faults, and reverse faults in the Çaybağı basin attest to the tectonic activity in this area during the Late Miocene and Early Pliocene. The East Anatolian Fault System, in particular the Uluova fault zone, is the most probable seismogenic source. Earthquakes with a magnitude of over 5 in the Richter scale can be postulated.

  7. Lower Cretaceous Source Rock and its Implication for the Gulf of Guinea Petroleum System

    International Nuclear Information System (INIS)

    Frost, B.R.; Griffith, R.C.

    2002-01-01

    Current petroleum system models for the Gulf of Guinea propose Tertiary-age deltaic organic material as the principal source for the hydrocarbons found there. Although previous workers recognized numerous difficulties and inconsistencies, no alternative model has been resented to adequately explain the complete petroleum system. We propose that the principal source rock for the Gulf of Guinea system occurs in upper lower Cretaceous-age shales at the rift-drift transition. Tertiary loading and the consequent maturation of this lower Cretaceous source rock can explain the controls on tap formation, reservoir distribution and hydrocarbon types found in the Gulf of Guinea

  8. Distinguishing megathrust from intraplate earthquakes using lacustrine turbidites (Laguna Lo Encañado, Central Chile)

    Science.gov (United States)

    Van Daele, Maarten; Araya-Cornejo, Cristian; Pille, Thomas; Meyer, Inka; Kempf, Philipp; Moernaut, Jasper; Cisternas, Marco

    2017-04-01

    One of the main challenges in seismically active regions is differentiating paleo-earthquakes resulting from different fault systems, such as the megathrust versus intraplate faults in subductions settings. Such differentiation is, however, key for hazard assessments based on paleoseismic records. Laguna Lo Encañado (33.7°S; 70.3°W; 2492 m a.s.l.) is located in the Central Chilean Andes, 50 km east of Santiago de Chile, a metropole with about 7,000,000 inhabitants. During the last century the study area experienced 3 large megathrust earthquakes (1906, 1985 and 2010) and 2 intraplate earthquakes (1945 and 1958) (Lomnitz, 1960). While the megathrust earthquakes cause Modified Mercalli Intensities (MMIs) of VI to VII at the lake (Van Daele et al., 2015), the intraplate earthquakes cause peak MMIs up to IX (Sepúlveda et al., 2008). Here we present a turbidite record of Laguna Lo Encañado going back to 1900 AD. While geophysical data (3.5 kHz subbottom seismic profiles and side-scan sonar data) provides a bathymetry and an overview of the sedimentary environment, we study 15 short cores in order to understand the depositional processes resulting in the encountered lacustrine turbidites. All mentioned earthquakes triggered turbidites in the lake, which are all linked to slumps in proximal areas, and are thus resulting from mass wasting of the subaquatic slopes. However, turbidites linked to the intraplate earthquakes are additionally covered by turbidites of a finer-grained, more clastic nature. We link the latter to post-seismic erosion of onshore landslides, which need higher MMIs to be triggered than subaquatic mass movements (Howarth et al., 2014). While intraplate earthquakes can cause MMIs up to IX and higher, megathrust earthquakes do not cause sufficiently high MMIs at the lake to trigger voluminous onshore landslides. Hence, the presence of these post-seismic turbidites allows to distinguish turbidites triggered by intraplate earthquakes from those

  9. Preliminary study of the favorability for uranium in selected areas in the Basin and Range Province, Nevada

    International Nuclear Information System (INIS)

    Cupp, G.M.; Leedom, S.H.; Mitchell, T.P.; Kiloh, K.D.; Horton, R.C.

    1977-10-01

    Six uranium areas in Nevada were examined in a reconnaissance fashion to determine their favorability for uranium deposits. The favorable areas are: Virgin Valley, Humboldt County; northern Reese River Valley, Lander County; East Walker River, Lyon County; and Coaldale, Esmeralda County. Areas judged to be unfavorable are: Carol ''R'' prospect, Garfield Hills, Mineral County; and Meadow Valley (Panaca), Lincoln County. In the Virgin Valley area, the Canyon Rhyolite Formation contains as much as 27 ppM U 3 O 8 and is an excellent source rock. Uranium deposits in the underlying Virgin Valley Formation are small, but larger deposits may exist. The northern portion of the Reese River Valley contains several small uranium deposits but none of mineable grade or size. Rhyolitic volcanic rocks in the area contain above-average amounts of uranium, and larger deposits may lie beneath these potential source rocks. The East Walker River area may be part of a larger uranium province. Intrusive and extrusive rocks in the area contain above-average amounts of uranium, and low-grade supergene deposits were found. Large areas of potential source rocks and host rocks, and two small uranium deposits, were found in the Coaldale area. Many rhyolite plugs were also found. The Carol ''R'' prospect is an isolated uranium occurrence in Tertiary lacustrine rocks. Uranium deposits in Meadow Valley are in the Panaca Formation, a Pliocene lacustrine formation of varied lithology. The uranium deposits are small and low grade. It is unlikely that large-grade deposits will be found in this area

  10. Coal depositional models in some tertiary and cretaceous coal fields in the US western interior

    Energy Technology Data Exchange (ETDEWEB)

    Flores, R M

    1979-12-01

    Detailed stratigraphic and sedimentological studies of the Tertiary Tongue River Member of the Fort Union Formation in the Powder River Basin, Wyoming, and the Cretaceous Blackhawk Formation and Star Point Sandstone in the Wasatch Plateau, Utah, indicate that the depositional environments of coal played a major role in controlling coal thickness, lateral continuity, potential minability, and type of floor and roof rocks. The potentially minable, thick coal beds of the Tongue River Member were primarily formed in long-lived floodbasin backswamps of upper alluvial plain environment. Avulsion of meandering fluvial channels contributed to the erratic lateral extent of coals in this environment. Laterally extensive coals formed in floodbasin backswamps of a lower alluvial plain environment; however, interruption by overbank and crevasse-splay sedimentation produced highly split and merging coal beds. Lacustrine sedimentation common to the lower alluvial plain, similar to the lake-covered lower alluvial valley of the Atchafalaya River Basin, is related to a high-constructive delta. In contrast to these alluvial coals are the deltaic coal deposits of the Blackhawk Formation. The formation consists of three coal populations: upper delta plain, lower delta plain, and back-barrier. Coals of the lower delta plain are thick and laterally extensive, in contrast to those of the upper delta plain and back-barrier, which contain abundant, very thin and laterally discontinuous carbonaceous shale partings. The reworking of the delta-front sediments of the Star Point Sandstone suggests that the Blackhawk-Star Point delta was a high-destructive system. 1 figure, 1 table.

  11. Forensic analysis of tertiary-butyl alcohol (TBA) detections in a hydrocarbon-rich groundwater basin.

    Science.gov (United States)

    Quast, Konrad W; Levine, Audrey D; Kester, Janet E; Fordham, Carolyn L

    2016-04-01

    Tertiary-butyl alcohol (TBA), a high-production volume (HPV) chemical, was sporadically detected in groundwater and coalbed methane (CBM) wells in southeastern Colorado's hydrocarbon-rich Raton Basin. TBA concentrations in shallow water wells averaged 75.1 μg/L, while detections in deeper CBM wells averaged 14.4 μg/L. The detection of TBA prompted a forensic investigation to try to identify potential sources. Historic and recent data were reviewed to determine if there was a discernable pattern of TBA occurrence. Supplemental samples from domestic water wells, monitor wells, CBM wells, surface waters, and hydraulic fracturing (HF) fluids were analyzed for TBA in conjunction with methyl tertiary-butyl ether (MTBE) and ethyl tertiary-butyl ether (ETBE), proxies for evidence of contamination from reformulated gasoline or associated oxygenates. Exploratory microbiological sampling was conducted to determine if methanotrophic organisms co-occurred with TBA in individual wells. Meaningful comparisons of historic TBA data were limited due to widely varying reporting limits. Mapping of TBA occurrence did not reveal any spatial patterns or physical associations with CBM operations or contamination plumes. Additionally, TBA was not detected in HF fluids or surface water samples. Given the widespread use of TBA in industrial and consumer products, including water well completion materials, it is likely that multiple diffuse sources exist. Exploratory data on stable isotopes, dissolved gases, and microbial profiling provide preliminary evidence that methanotrophic activity may be producing TBA from naturally occurring isobutane. Reported TBA concentrations were significantly below a conservative risk-based drinking water screening level of 8000 μg/L derived from animal toxicity data.

  12. Tertiary Education in the Czech Republic: The Pathway to Change

    Science.gov (United States)

    Pesik, Richard; Gounko, Tatiana

    2011-01-01

    This article analyzes recent policy proposals to reform Czech tertiary education. A brief overview of the evolution of Czech tertiary education presents the background against which emerging policy trends in education are examined. We relate the changes in tertiary education to the policy framework and recommendations of the OECD, underpinned by…

  13. 2. Tertiary Foraminifera

    NARCIS (Netherlands)

    Umbgrove, J.H.F.

    1931-01-01

    In his review of the palaeozoology of Java, K. Martin could in 1919, record 49 foraminifera from tertiary strata of Java, on the strength of a critical study of the existant literature, and especially on the strength of his own studies and knowledge of the above mentioned fossils (Bibl. 49). In

  14. Limits and opportunities of marketeering tertiary education in post-colonial Zimbabwe

    OpenAIRE

    Patrick Sibanda

    2016-01-01

    This paper intended to assess the impact of marketeering tertiary education in Zimbabwe. The paper revealed that marketeering of tertiary education in Zimbabwe has drastically impacted on access to higher education and training. Poor and vulnerable students have found it difficult to access tertiary education due to escalating commercialized fees. Literature indicates that, even in developed countries like UK, marketeering tertiary education has led to decreased enrolments, diminishing prospe...

  15. Empirical quantification of lacustrine groundwater discharge - different methods and their limitations

    Science.gov (United States)

    Meinikmann, K.; Nützmann, G.; Lewandowski, J.

    2015-03-01

    Groundwater discharge into lakes (lacustrine groundwater discharge, LGD) can be an important driver of lake eutrophication. Its quantification is difficult for several reasons, and thus often neglected in water and nutrient budgets of lakes. In the present case several methods were applied to determine the expansion of the subsurface catchment, to reveal areas of main LGD and to identify the variability of LGD intensity. Size and shape of the subsurface catchment served as a prerequisite in order to calculate long-term groundwater recharge and thus the overall amount of LGD. Isotopic composition of near-shore groundwater was investigated to validate the quality of catchment delineation in near-shore areas. Heat as a natural tracer for groundwater-surface water interactions was used to find spatial variations of LGD intensity. Via an analytical solution of the heat transport equation, LGD rates were calculated from temperature profiles of the lake bed. The method has some uncertainties, as can be found from the results of two measurement campaigns in different years. The present study reveals that a combination of several different methods is required for a reliable identification and quantification of LGD and groundwater-borne nutrient loads.

  16. Geochemical characteristics of Lower Jurassic source rocks in the Zhongkouzi Basin

    Science.gov (United States)

    Niu, Haiqing; Han, Xiaofeng; Wei, Jianshe; Zhang, Huiyuan; Wang, Baowen

    2018-01-01

    Zhongkouzi basin is formed in Mesozoic and Cenozoic and developed on the Hercynian folded belt, the degree of exploration for oil and gas is relatively low hitherto. In order to find out the geochemical characteristics of the source rocks and the potentials for hydrocarbon generation. The research result shows that by analysis the geochemical characteristics of outcrop samples and new core samples in Longfengshan Group, Longfengshan Group are most developed intervals of favorable source rocks. They are formed in depression period of the basin when the sedimentary environments is salt water lacustrine and the water is keeping stable; The organic matter abundance is middle-higher, the main kerogen type is II1-II2 and few samples act as III type, The organic matter maturity is low maturity to medium maturity. The organic matter maturity of the source rock from eastern part of the basin is higher than in the western region. The source rock of Longfengshan Group are in the hydrocarbon generation threshold. The great mass of source rocks are matured and in the peak stage of oil generation.

  17. Mixed La-Li heterobimetallic complexes for tertiary nitroaldol resolution.

    Science.gov (United States)

    Tosaki, Shin-ya; Hara, Keiichi; Gnanadesikan, Vijay; Morimoto, Hiroyuki; Harada, Shinji; Sugita, Mari; Yamagiwa, Noriyuki; Matsunaga, Shigeki; Shibasaki, Masakatsu

    2006-09-13

    A kinetic resolution of tertiary nitroaldols derived from simple ketones is described. Mixed BINOL/biphenol La-Li heterobimetallic complexes gave the best selectivity in retro-nitroaldol reactions of racemic tertiary nitroaldols. By using a mixture of La-Li3-(1a)3 complex (LLB 2a) and La-Li3-(1b)3 (LLB* 2b) complex in a ratio of 2/1, chiral tertiary nitroaldols were obtained in 80-97% ee and 30-47% recovery yield.

  18. Massification and Quality Assurance in Tertiary Education: The ...

    African Journals Online (AJOL)

    The study sets out to examine massification and its impact on quality assurance in tertiary education and the extent to which lecturer–student ratio, adequacy of infrastructure and pedagogical resources affect quality in tertiary institutions. Two research questions and one hypothesis were posed to guide the investigation.

  19. Geophysical imaging of the lacustrine sediments deposited in the La Calderilla Volcanic Caldera (Gran Canaria Island, Spain) for paleoclimate research

    Science.gov (United States)

    Himi, Mahjoub; Rodríguez-González, Alejandro; Criado, Constantino; Tapias, Josefina C.; Ravazzi, Cesare; Pérez-Torrado, Francisco; Casas, Albert

    2016-04-01

    The discovery of well-preserved maar structures is important not only for studying the eruptive activity and formation of volcanoes, but also for paleoclimate research, since laminated maar lake sediments may contain very detailed archives of climate and environmental history. Maars are a singular type of volcanic structure generated by explosive phreatomagmatic eruptions as a result of interaction between rising magma and groundwater. This kind of structures are characterised by circular craters, often filled with water and/or lacustrine sediments and surrounded by a ring of pyroclastic deposits.Recently a borehole was drilled at the bottom of La Calderilla volcanic complex which penetrated about 8.7 m in its sedimentary sequence and paleobotanical study has supplied the first evidence of paleoenvironmental evolution during the Holocene on the Gran Canaria Island. This survey, however, did not penetrate into the substrate because the total thickness of the sedimentary fill was unknown. Since the age of formation of La Calderilla volcanic complex based on K/Ar dating is about 85,000 years (Upper Pleistocene), the possibility of its sedimentary fill extends beyond of the Holocene is extremely attractive, since, for example, there are few paleoenvironmental data regarding how much the last glaciation that affected the Canary Islands. In these circumstances, the knowledge of the total thickness of the lacustrine sediments is crucial to design a deeper borehole in the next future. Therefore, the subsurface characterisation provided by geophysics is essential for determining thickness and geometry of the sedimentary filling. Multielectrode ERT method was used to obtain five 2-D resistivity cross-sections into La Calderilla volcanic caldera. An Iris Syscal Pro resistivity system with 48 electrodes connected to a 94 m long cable (2m electrode spacing) in Wenner-Schlumberger configuration for an investigation depth of about 20 m. Data quality (q Current injected was

  20. Quality and petrographic characteristics of the lacustrine Ermenek coal (early Miocene), Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Demirel, I.H.; Karayigit, A.I. [Hacettepe Univ., Beytepe-Ankara (Turkey). Dept. of Geological Engineering

    1999-05-01

    The early Miocene Yenimahalle Formation including alluvial-lacustrine sediments and a mineable coal steam with an average of 5 m in thickness rests unconformably upon the basement and is also unconformably overlain by marine limestones of the middle-late Miocene Mut Formation in the Ermenek coal basin. The coal basin in the present study has been subdivided into two areas, Canakci and Pamuklu-Tepebasi, which are separated by the basement and a fault, in order to determine coal properties in detail. The investigated subbituminous coals with an average of 0.40%Ro huminite reflectance often contain gastropod shells (Planorbidae) which commonly maintain the original aragonite and calcite composition. The coals have similar chemical properties and petrographic composition in the two areas, but their sulphur contents are clearly different. In the Canakci area the coals on an air-dried basis contain distinctly less total sulphur (avg. 1.3%) and organic sulphur contents (0.13--0.15%) than in the Pamuklu-Tepebasi area (avg. 4.5% and 4.25%, respectively). This difference is interpreted to be controlled by mire chemistry and sedimentation during peat formation.

  1. Challenges with Tertiary-Level Mechatronic Fluid Power

    DEFF Research Database (Denmark)

    Dransfield, Peter; Conrad, Finn

    1996-01-01

    As authors we take the view that mechatronics, as it relates to fluid power, has three levels which we designate as primary, secondary and tertiary. A brief review of the current status of fluid power, hydraulic and pneumatic, and of electronic control of it is presented and discussed. The focus...... is then on tertiary-level mechatronic fluid power and the challenges to it being applied successfully....

  2. Diagenetic variation at the lamina scale in lacustrine organic-rich shales: Implications for hydrocarbon migration and accumulation

    Science.gov (United States)

    Liang, Chao; Cao, Yingchang; Liu, Keyu; Jiang, Zaixing; Wu, Jing; Hao, Fang

    2018-05-01

    Lacustrine carbonate-rich shales are well developed within the Mesozoic-Cenozoic strata of the Bohai Bay Basin (BBB) of eastern China and across southeast Asia. Developing an understanding of the diagenesis of these shales is essential to research on mass balance, diagenetic fluid transport and exchange, and organic-inorganic interactions in black shales. This study investigates the origin and distribution of authigenic minerals and their diagenetic characteristics, processes, and pathways at the scale of lacustrine laminae within the Es4s-Es3x shale sequence of the BBB. The research presented in this study is based on thin sections, field emission scanning electron microscope (FESEM) and SEM-catholuminescence (CL) observations of well core samples combined with the use of X-ray diffraction (XRD), energy dispersive spectroscopy, electron microprobe analysis, and carbon and oxygen isotope analyses performed using a laser microprobe mass spectrometer. The dominant lithofacies within the Es4s-Es3x sequence are a laminated calcareous shale (LCS-1) and a laminated clay shale (LCS-2). The results of this study show that calcite recrystallization1 is the overarching diagenetic process affecting the LCS-1, related to acid generation from organic matter (OM) thermal evolution. This evolutionary transition is the key factor driving the diagenesis of this lithofacies, while the transformation of clay minerals is the main diagenetic attribute of the LCS-2. Diagenetic differences occur within different laminae and at variable locations within the same lamina level, controlled by variations in mineral composition and the properties of laminae interfaces. The diagenetic fluid migration scale is vertical and responses (dissolution and replacement) are limited to individual laminae, between zero and 100 μm in width. In contrast, the dominant migration pathway for diagenetic fluid is lateral, along the abrupt interfaces between laminae boundaries, which leads to the vertical

  3. Sedimentology and Reservoir Characteristics of Early Cretaceous Fluvio-Deltaic and Lacustrine Deposits, Upper Abu Gabra Formation, Sufyan Sub-basin, Muglad Rift Basin, Sudan

    Science.gov (United States)

    Yassin, Mohamed; Abdullatif, Osman; Hariri, Mustafa

    2017-04-01

    Sufyan Sub-basin is an East-West trending Sub-basin located in the northwestern part of the Muglad Basin (Sudan), in the eastern extension of the West and Central Africa Rift System (WCARS). The Early Cretaceous Abu Gabra Formation considered as the main source rock in the Muglad Basin. In Sufyan Sub-basin the Early Cretaceous Upper Abu Gabra Formation is the main oil-producing reservoir. It is dominated by sandstone and shales deposited in fluvio-deltaic and lacustrine environment during the first rift cycle in the basin. Depositional and post-depositional processes highly influenced the reservoir quality and architecture. This study investigates different scales of reservoir heterogeneities from macro to micro scale. Subsurface facies analysis was analyzed based on the description of six conventional cores from two wells. Approaches include well log analysis, thin sections and scanning electron microscope (SEM) investigations, grain-size, and X-ray diffraction (XRD) analysis of the Abu Gabra sandstone. The cores and well logs analyses revealed six lithofacies representing fluvio-deltaic and lacustrine depositional environment. The sandstone is medium to coarse-grained, poorly to moderately sorted and sub-angular to subrounded, Sub-feldspathic arenite to quartz arenite. On macro-scale, reservoir quality varies within Abu Gabra reservoir where it shows progressive coarsening upward tendencies with different degrees of connectivity. The upper part of the reservoir showed well connected and amalgamated sandstone bodies, the middle to lower parts, however, have moderate to low sandstone bodies' connectivity and amalgamation. On micro-scale, sandstone reservoir quality is directly affected by textures and diagenesis.The XRD and SEM analyses show that kaolinite and chlorite clay are the common clay minerals in the studied samples. Clay matrix and quartz overgrowth have significantly reduced the reservoir porosity and permeability, while the dissolution of feldspars

  4. Crime and Crime Management in Nigeria Tertiary Institutions

    Science.gov (United States)

    Adebanjo, Margaret Adewunmi

    2014-01-01

    This paper examines crime and its management in Nigerian tertiary institutions. Tertiary institutions today have become arenas for crime activities such as rape, cultism, murder, theft, internet fraud, drug abuse, and examination malpractices. This paper delves into what crime is, and its causes; and the positions of the law on crime management.…

  5. 10 CFR 212.78 - Tertiary incentive crude oil.

    Science.gov (United States)

    2010-01-01

    ... 10 Energy 3 2010-01-01 2010-01-01 false Tertiary incentive crude oil. 212.78 Section 212.78 Energy DEPARTMENT OF ENERGY OIL MANDATORY PETROLEUM PRICE REGULATIONS Producers of Crude Oil § 212.78 Tertiary incentive crude oil. Annual prepaid expenses report. By January 31 of each year after 1980, the project...

  6. Long-term behaviour of {sup 137}Cs in the lacustrine ecosystem of lake Viverone; Il comportamento a lungo termine del {sup 137}Cs nell`ecosistema lacustre del lago di Viverone

    Energy Technology Data Exchange (ETDEWEB)

    Spezzano, P.; Cerea, E.; Massironi, L.; Olivetta, A.; Bortoluzzi, S.; Nocente, M.; Berton, G. [ENEA, Centro Ricerche Saluggia, Vercelli (Italy). Dip. Ambiente

    1998-12-31

    For the evaluation of long term behaviour of {sup 137}Cs in a lacustrine ecosystem, for ten years after the Chernobyl nuclear accident several experimental studies have been conducted in the Viverone lake, a small, eutrophic, monomictic lake situated between Turin and Vercelli, in North-West Italy. Radiocaesium activities were measured in different components of the ecosystem, i.e. soil, water, sediment and biotas, and have been related with main environmental physico-chemical parameters. Changes in radiocaesium content with time provided information about transfer processes of this radionuclide into the lacustrine ecosystem. Levels of {sup 137}Cs in lake water after several years from deposition can be ascribed to the migration from catchment basin and to the remobilization from bottom sediments. However, experimental results do not allow to ascertain which of these two factors prevails over the other.

  7. Implementing Open Source Platform for Education Quality Enhancement in Primary Education: Indonesia Experience

    Science.gov (United States)

    Kisworo, Marsudi Wahyu

    2016-01-01

    Information and Communication Technology (ICT)-supported learning using free and open source platform draws little attention as open source initiatives were focused in secondary or tertiary educations. This study investigates possibilities of ICT-supported learning using open source platform for primary educations. The data of this study is taken…

  8. Tertiary Technical Education and Youth Integration in Brazil, Colombia and Mexico

    Directory of Open Access Journals (Sweden)

    Claudia Jacinto

    2014-11-01

    Full Text Available Vocational training versus a traditional university education. This chapter seeks to answer the question of whether ‘tertiary technical education’ has contributed to increasing economic and social opportunity for young people in Latin America, using three case studies from Brazil, Colombia and Mexico. It examines the extent to which tertiary technical education has contributed towards democratising access to education through institutional diversification, expanded enrolment and, at least theoretically, improved access to quality employment. The analysis shows that tertiary technical education has contributed to widening of opportunities by offering an alternative form of education to new generations of young people. Tertiary technical education is more accessible, shorter in duration, has a vocational orientation, and tends to be cheaper than a university education. However, the case studies also reveal that while a tertiary technical education diploma is an asset for young people seeking employment, it nonetheless does not have the same perceived value as a traditional university education. Available data appear to indicate that graduates of tertiary technical education earn less on average than university graduates and face several challenges in the labour market. Furthermore, the studies reveal that despite the presence of highly regarded tertiary technical education institutions in all three countries, these carry less prestige and status than universities.

  9. Tertiary recovery and tritide injection equipment

    International Nuclear Information System (INIS)

    Li Lin

    1989-01-01

    The exploitation of an oil field is a continously developing process, undergoing seveal stages, such as the low production, the high production, the stable production and the decline. The tertiary recovery is an important means of the enhanced oil recovery. Since the object of the tertiary recovery is to treat the oil in micropores which is difficult to be produced, it is more necessary to know further the reservoir. Tritide can be used as a tracer and is an ideal marker of knowing the reservoir and the state of the fluid movement. The paper presents the tritide injection equipment

  10. Paleo and present-day chemical weathering in lacustrine and riverine sediments in Northern Patagonia, Argentina

    Energy Technology Data Exchange (ETDEWEB)

    Roman Ross, Gabriela [Comision Nacional de Energia Atomica, San Carlos de Bariloche (Argentina). Centro Atomico Bariloche. Lab. de Analisis por Activacion Neutronica; Arribere, Maria A.; Guevara, Sergio Ribeiro [Universidad Nacional de Cuyo, XX (Argentina)

    1996-07-01

    Neutron activation analysis was used to study the abundance, distribution and fraction of REE (Rare Earth Elements) and diagnostic elements (Th, Co, Cr, Sc, Rb, Sr) in sediments from Mascardi lake and Upper Manso river. The local weathering patterns of this watershed show a strong influence of volcanic rocks with a selective mobilization of the more soluble elements. These patterns are very similar to those observed in a sedimentary lacustrine core from Mascardi lake. Paleolimnological record indicates a change in local fluxes of water and sediments, and an increase in organic matter content since the last full-glacial maximum. However, the chemical composition of the sedimentary inputs has not changed significantly during the last 14000 years. Our data support the hypothesis that present-day and Holocene chemical weathering have similar characteristics. All of the above conclusions are based on geochemical parameters only. (author)

  11. Paleo and present-day chemical weathering in lacustrine and riverine sediments in Northern Patagonia, Argentina

    International Nuclear Information System (INIS)

    Roman Ross, Gabriela

    1996-01-01

    Neutron activation analysis was used to study the abundance, distribution and fraction of REE (Rare Earth Elements) and diagnostic elements (Th, Co, Cr, Sc, Rb, Sr) in sediments from Mascardi lake and Upper Manso river. The local weathering patterns of this watershed show a strong influence of volcanic rocks with a selective mobilization of the more soluble elements. These patterns are very similar to those observed in a sedimentary lacustrine core from Mascardi lake. Paleolimnological record indicates a change in local fluxes of water and sediments, and an increase in organic matter content since the last full-glacial maximum. However, the chemical composition of the sedimentary inputs has not changed significantly during the last 14000 years. Our data support the hypothesis that present-day and Holocene chemical weathering have similar characteristics. All of the above conclusions are based on geochemical parameters only. (author)

  12. Total petroleum systems of the Pelagian Province, Tunisia, Libya, Italy, and Malta; the Bou Dabbous, Tertiary and Jurassic-Cretaceous composite

    Science.gov (United States)

    Klett, T.R.

    2001-01-01

    Undiscovered conventional oil and gas resources were assessed within total petroleum systems of the Pelagian Province (2048) as part of the U.S. Geological Survey World Petroleum Assessment 2000. The Pelagian Province is located mainly in eastern Tunisia and northwestern Libya. Small portions of the province extend into Malta and offshore Italy. Although several petroleum systems may exist, only two ?composite? total petroleum systems were identified. Each total petroleum system comprises a single assessment unit. These total petroleum systems are called the Bou Dabbous?Tertiary and Jurassic-Cretaceous Composite, named after the source-rock intervals and reservoir-rock ages. The main source rocks include mudstone of the Eocene Bou Dabbous Formation; Cretaceous Bahloul, Lower Fahdene, and M?Cherga Formations; and Jurassic Nara Formation. Known reservoirs are in carbonate rocks and sandstone intervals throughout the Upper Jurassic, Cretaceous, and Tertiary sections. Traps for known accumulations include fault blocks, low-amplitude anticlines, high-amplitude anticlines associated with reverse faults, wrench fault structures, and stratigraphic traps. The estimated means of the undiscovered conventional petroleum volumes in total petroleum systems of the Pelagian Province are as follows: [MMBO, million barrels of oil; BCFG, billion cubic feet of gas; MMBNGL, million barrels of natural gas liquids] Total Petroleum System MMBO BCFG MMBNGL Bou Dabbous?Tertiary 667 2,746 64 Jurassic-Cretaceous Composite 403 2,280 27

  13. Sedimentary architecture of a sub-lacustrine debris fan: Eocene Dongying Depression, Bohai Bay Basin, east China

    Science.gov (United States)

    Liu, Jianping; Xian, Benzhong; Wang, Junhui; Ji, Youliang; Lu, Zhiyong; Liu, Saijun

    2017-12-01

    The sedimentary architectures of submarine/sublacustrine fans are controlled by sedimentary processes, geomorphology and sediment composition in sediment gravity flows. To advance understanding of sedimentary architecture of debris fans formed predominantly by debris flows in deep-water environments, a sub-lacustrine fan (Y11 fan) within a lacustrine succession has been identified and studied through the integration of core data, well logging data and 3D seismic data in the Eocene Dongying Depression, Bohai Bay Basin, east China. Six types of resedimented lithofacies can be recognized, which are further grouped into five broad lithofacies associations. Quantification of gravity flow processes on the Y11 fan is suggested by quantitative lithofacies analysis, which demonstrates that the fan is dominated by debris flows, while turbidity currents and sandy slumps are less important. The distribution, geometry and sedimentary architecture are documented using well data and 3D seismic data. A well-developed depositional lobe with a high aspect ratio is identified based on a sandstone isopach map. Canyons and/or channels are absent, which is probably due to the unsteady sediment supply from delta-front collapse. Distributary tongue-shaped debris flow deposits can be observed at different stages of fan growth, suggesting a lobe constructed by debrite tongue complexes. Within each stage of the tongue complexes, architectural elements are interpreted by wireline log motifs showing amalgamated debrite tongues, which constitute the primary fan elements. Based on lateral lithofacies distribution and vertical sequence analysis, it is proposed that lakefloor erosion, entrainment and dilution in the flow direction lead to an organized distribution of sandy debrites, muddy debrites and turbidites on individual debrite tongues. Plastic rheology of debris flows combined with fault-related topography are considered the major factors that control sediment distribution and fan

  14. Solvent effects on the magnetic shielding of tertiary butyl alcohol

    African Journals Online (AJOL)

    )4 and tetramethyl ammonium cation N(CH3)4(+) have also been presented. KEY WORDS: Solvent effects, Magnetic shielding, Tertiary butyl alcohol, Tertiary butyl amine, Continuum solvation calculations, Chemical shift estimation methods

  15. Ensuring Effective Mentoring in Tertiary Institutions in Anambra State ...

    African Journals Online (AJOL)

    This paper concerns itself only with ascertaining the strategies that could ensure effective mentoring in tertiary institutions. The survey method was employed. The study population comprised 78 teacher educators in tertiary institutions in Anambra State. One research question guided the study while one null hypothesis was ...

  16. Quality and petrographic characteristics of the Lacustrine Ermenek Coal (Early Miocene), Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Demirel, I.H.; Karayigit, A.I.

    1999-04-15

    The early Miocene Yenimahalle Formation including alluvial-lacustrine sediments and a mineable coal seam with an average of 5 m in thickness rests unconformably upon the basement and is also unconformably overlain by marine limestones of the middle-late Miocene Mut Formation in the Ermenek coal basin. The coal basin in the present study has been subdivided into two areas, Canakci and Pamuklu-Tepebasi, which are separated by the basement and a fault, in order to determine coal properties in detail. The investigated subbituminous coals with an average of 0.40% Ro huminite reflectance often contain gastropod shells (Planorbidae) which commonly maintain the original aragonite and calcite composition. The coals have similar chemical properties and petrographic composition in the two areas, but their sulphur contents are clearly different. In the Canakci area the coals on an air-dried basis contain distinctly less total sulphur (avg. 1.3%) and organic sulphur contents (0.13 0.15%) than in the Pamuklu-Tepebasi area (avg. 4.5% and 4.25%, respectively). This difference is interpreted to be controlled by mire chemistry and sedimentation during peat formation. (author)

  17. Parathyroid carcinoma in tertiary hyperparathyroidism.

    Science.gov (United States)

    Kim, Byung Seup; Ryu, Han Suk; Kang, Kyung Ho; Park, Sung Jun

    2016-10-01

    Parathyroid carcinoma is a rare disease of unknown etiology. This study presents a case of parathyroid carcinoma in a patient with tertiary hyperparathyroidism. Despite a successful kidney transplantation, the intact parathyroid hormone (iPTH) level of the patient was elevated consistently and could not be controlled by medical therapy. Due to the development of tertiary hyperparathyroidism with bone pain and osteoporosis, subtotal parathyroidectomy was performed 4 months after the kidney transplantation. Histological evaluation revealed that one of four parathyroid lesions was a parathyroid carcinoma, while the others were diffuse hyperplasia. Postoperative laboratory studies indicated a decreased level of iPTH. A positron emission tomography-computed tomography performed 6 months after the operation revealed no evidence of local recurrence or distant metastasis. Copyright © 2013. Published by Elsevier Taiwan.

  18. Spatio-temporal observations of the tertiary ozone maximum

    Directory of Open Access Journals (Sweden)

    V. F. Sofieva

    2009-07-01

    Full Text Available We present spatio-temporal distributions of the tertiary ozone maximum (TOM, based on GOMOS (Global Ozone Monitoring by Occultation of Stars ozone measurements in 2002–2006. The tertiary ozone maximum is typically observed in the high-latitude winter mesosphere at an altitude of ~72 km. Although the explanation for this phenomenon has been found recently – low concentrations of odd-hydrogen cause the subsequent decrease in odd-oxygen losses – models have had significant deviations from existing observations until recently. Good coverage of polar night regions by GOMOS data has allowed for the first time to obtain spatial and temporal observational distributions of night-time ozone mixing ratio in the mesosphere.

    The distributions obtained from GOMOS data have specific features, which are variable from year to year. In particular, due to a long lifetime of ozone in polar night conditions, the downward transport of polar air by the meridional circulation is clearly observed in the tertiary ozone maximum time series. Although the maximum tertiary ozone mixing ratio is achieved close to the polar night terminator (as predicted by the theory, TOM can be observed also at very high latitudes, not only in the beginning and at the end, but also in the middle of winter. We have compared the observational spatio-temporal distributions of the tertiary ozone maximum with that obtained using WACCM (Whole Atmosphere Community Climate Model and found that the specific features are reproduced satisfactorily by the model.

    Since ozone in the mesosphere is very sensitive to HOx concentrations, energetic particle precipitation can significantly modify the shape of the ozone profiles. In particular, GOMOS observations have shown that the tertiary ozone maximum was temporarily destroyed during the January 2005 and December 2006 solar proton events as a result of the HOx enhancement from the increased ionization.

  19. Palaeoenvironmental assessment of Westphalian fluvio-lacustrine deposits of Lorraine (France) using a combination of organic geochemistry and sedimentology

    International Nuclear Information System (INIS)

    Fleck, Stephanie; Michels, Raymond; Izart, Alain; Elie, Marcel; Landais, Patrick

    2001-01-01

    The quality and the quantity of organic carbon preserved in modern and ancient terrestrial sediments is the result of a complex interactions of sedimentological factors, such as in-situ productivity, allochtonous supply of organic matter, oxidation processes, biodegradation and sediment accumulation rates. The study aims at utilizing multidisciplinary information in order to characterize the palaeoenvironment in Westphalian fluvio-lacustrine deposits of the Lorraine Coal Basin (NE France). In this basin, the lack of outcrops is the major difficulty. To compensate for this problem, sedimentology, and molecular geochemistry are combined in order to significantly improve the palaeoenvironmental assessment of the area. Geochemical analyses and sedimentology have been carried out on several core samples of the Saulcy drill hole to evaluate local palaeoenvironmental variability. The lithofacies associations in the Upper Carboniferous of the Lorraine basin suggest an alluvial plain environment without marine incursions. Sedimentological interpretations of the core, as well as comparison with sedimentological models, suggests the recognition of different depositional environments from braided and/or meandering rivers to swamp and lakes. The organic geochemistry is focussed on the recognition of aliphatic hydrocarbons and especially on molecular biomarkers, which provide valuable information about the original organic matter and the transformations that took place during sedimentation and diagenesis. In the Lorraine basin, the botanical variability is high and clearly related to the position of the vegetation communities in the fluvial system. The biomarkers (e.g., diterpanes, steranes) show variations, which can be related to the diversity of this ecosystem. In this study, a reinterpretation of the environmental zonation in the sterane ternary diagram adapted to a fluvio-lacustrine sedimentology is proposed. The correlation between sedimentological and geochemical

  20. Terpenoid composition and class of Tertiary resins from India

    Energy Technology Data Exchange (ETDEWEB)

    Dutta, Suryendu; Mallick, Monalisa; Mathews, Runcie Paul [Department of Earth Sciences, Indian Institute of Technology Bombay, Powai, Mumbai-400076 (India); Bertram, Norbert [LTA-Labor fuer Toxikologie und Analytik, Friedrichshoeher Str. 28, D-53639 Koenigswinter (Germany); Greenwood, Paul F. [John De Laeter Mass Spectrometry and WA Biogeochemitry Centres (M090), The University of Western Australia, 35 Stirling Hwy, Crawley, WA, 6009 (Australia); WA - Organic and Isotope Geochemistry Centre, Curtin University of Technology, Kent St., Bentley 6102 (Australia)

    2009-10-01

    The terpenoid composition and class of Tertiary resins preserved within lignites of Cambay, Kutch and Cauvery Basins of India have been characterized using Pyrolysis-Gas Chromatography-Mass Spectrometry (Py-GC-MS) and Fourier Transform Infrared (FTIR) Spectroscopy. Major pyrolysis products include cadalene-based C{sub 15}-bicyclic sesquiterpenoids with some C{sub 30} and C{sub 31} bicadinanes and bicadinenes typical of Class II or dammar resin. The occurrence of these terpenoids in Early Eocene sediments may extend the first appearance of Dipterocarpaceae angiosperms, the predominant source of this resin class, back to the Early Eocene epoch in India. The same terpenoid biomarkers have been detected in many SE Asian oils reflecting a close source relationship with these resins. Strong CH{sub 3} (1377 cm{sup -} {sup 1}) and other CH{sub x} (3000-2800 and 1460-1450 cm{sup -} {sup 1}) aliphatic absorptions of much larger intensity than the aromatic C = C (1560-1650 cm{sup -} {sup 1}) absorption were detected in the Indian resins by FTIR Spectroscopy, confirming the quantitative significance of the terpenoid pyrolysates. (author)

  1. Determinants of propensity of tertiary agricultural students in Ghana ...

    African Journals Online (AJOL)

    The study aimed to identify factors that affect the decision of tertiary agricultural students in Ghana to enter agribusiness as a self-employment venture after graduation. The results showed that tertiary agricultural students in Ghana were predominantly males with little or no farming background. They had a rather moderate ...

  2. American Tertiary mollusks of the genus Clementia

    Science.gov (United States)

    Woodring, W.P.

    1927-01-01

    Aside from its value as an aid in determining the age of Tertiary beds, the chief interest of the genus Clementia lies in the anomalous features of its present and former distribution. An attempt is made in this paper to trace its geologic history, to point out its paleobiologic significance, and to describe all the known American Tertiary species. The fossils from Colombia used in preparing this report were collected during explorations made under the direction of Dr. 0. B. Hopkins, chief geologist of the Imperial Oil Co. (Ltd.), who kindly donated them to the United States National Museum. Dr. T. Wayland Vaughan, of the Scripps Institution of Oceanography, furnished information relating to specimens collected by him in Mexico. Dr. Bruce L. Clark, of the University of California; Dr. G. Dallas Hanna, of the California Academy of Sciences; Dr. H. A. Pilsbry, of the Philadelphia Academy of Natural Sciences; and Dr. W. D. Matthew, of the American Museum of Natural History, generously loaned type specimens and other material. Doctor Clark and Doctor Hanna also gave information concerning the Tertiary species from California. Mr. Ralph B. Stewart, of the University of California, read the manuscript, and I have taken advantage of his suggestions. I am also indebted to Mr. L. R. Cox, of the British Museum, for information relating to the fossil species from Persia, Zanzibar, and Burma, and to Dr. Axel A. Olsson, of the International Petroleum Co., for data concerning undescribed Tertiary species from Peru.

  3. Climatic and lacustrine morphometric controls of diatom paleoproductivity in a tropical Andean lake

    Science.gov (United States)

    Bao, R.; Hernández, A.; Sáez, A.; Giralt, S.; Prego, R.; Pueyo, J. J.; Moreno, A.; Valero-Garcés, B. L.

    2015-12-01

    The coupling of lake dynamics with catchment biogeochemistry is considered the key element controlling primary production in mountain lakes at time scales of a few decades to millennia, yet little is known on the impacts of the morphometry of lakes throughout their ontogeny. As Lake Chungará (Central Andean Altiplano, northern Chile) experienced long-term lake-level fluctuations that strongly modified its area:volume ratio, it is an ideal system for exploring the relative roles that long-term climatic shifts and lake morphometry play on biosiliceous lacustrine productivity. In this paper, we review previous data on the percent contents of total organic carbon, total inorganic carbon, total nitrogen, total biogenic silica, isotopic composition of organic matter, carbonates, and diatom frustules, as well as data on the abundance of the chlorophycean Botryococcus braunii in this lake for the period 12,400-1300 cal yr BP. We also include new data on organic carbon and biogenic silica mass accumulation rates and the diatom assemblage composition of an offshore core dated using 14C and U/Th. Biosiliceous productivity in Lake Chungará was influenced by shifts in allochthonous nutrient inputs related to variability in precipitation. Humid phases dated at approx. 12,400 to 10,000 and 9600 to 7400 cal yr BP coincide with periods of elevated productivity, whereas decreases in productivity were recorded during arid phases dated at approx. 10,000 to 9600 and 7400 to 3550 cal yr BP (Andean mid-Holocene Aridity Period). However, morphometry-related in-lake controls led to a lack of a linear response of productivity to precipitation variability. During the late Glacial to early Holocene, lowstands facilitated complete water column mixing, prompting episodic massive blooms of a large centric diatom, Cyclostephanos cf. andinus. Thus, moderate productivity could be maintained, regardless of aridity, by this phenomenon of morphometric eutrophy during the early history of the lake

  4. Classification and sedimentary characteristics of lacustrine hyperpycnal channels: Triassic outcrops in the south Ordos Basin, central China

    Science.gov (United States)

    Xian, Benzhong; Wang, Junhui; Gong, Chenglin; Yin, Yu; Chao, Chuzhi; Liu, Jianping; Zhang, Guodong; Yan, Qi

    2018-06-01

    Subaquatic channels are known as active conduits for the delivery of terrigenous sediments into related marine and lacustrine basins, as well as important targets for hydrocarbon exploration. Compared to submarine channels, lacustrine subaqueous channels created by hyperpycnal flows are understudied. Using well-exposed outcrops collected from three different locations in the southern Ordos Basin, central China, morphologies and architecture of a channelized hyperpycnal system were studied and classified. Six facies associations represent sedimentary processes from strong erosion by bedload dominated hyperpycnal flows, to transitional deposition jointly controlled by bedload and suspended-load dominated hyperpycnal flows, finally to deposition from suspended-load dominated hyperpycnal flows. On the basis of channel morphologies, infilling sediments and sedimentary processes, the documented channels can be classified into four main categories, which are erosional, bedload dominated, suspended-load dominated, and depositional channels. In very proximal and very distal locations, erosional channels and depositional channels serve as two end-members, while in middle areas, bedload-dominated channels and suspended-load dominated channels are transitional types. Erosional channels, as a response to strong erosion from bedload dominated hyperpycnal flows on upper slope, were mainly filled by mud interbedded with thin sand beds. As flow energy decreases, bedload dominated channels develop on middle slopes, which are characterized mainly by under- to balanced sediment infillings with cross-bedded sandstones and/or minor massive sandstones. Compared to bedload dominated channels, suspended-load dominated channels mainly develop in deeper water, and were filled mainly by massive or planar-laminated sandstones. Depositional channels, as a response to suspended-load dominated hyperpycnal flows in deep-water areas, are characterized by thin-medium bed classical turbidites with

  5. Record of palaeoenvironmental changes in a Lower Permian organic-rich lacustrine succession: Integrated sedimentological and geochemical study of the Rudník member, Krkonoše Piedmont Basin, Czech Republic

    Czech Academy of Sciences Publication Activity Database

    Martínek, K.; Blecha, M.; Daněk, V.; Franců, J.; Hladíková, J.; Johnová, R.; Uličný, David

    2006-01-01

    Roč. 230, 1/2 (2006), s. 85-128 ISSN 0031-0182 R&D Projects: GA ČR GA205/94/0692 Institutional research plan: CEZ:AV0Z30120515 Keywords : Lower Permian * Bohemian Massif * lacustrine facies Subject RIV: DB - Geology ; Mineralogy Impact factor: 1.822, year: 2006

  6. Assessing the Influence of Advertising on Student Enrolment in Private Tertiary Institutions in Ghana

    Directory of Open Access Journals (Sweden)

    Bede Akorige Atarah

    2014-03-01

    Full Text Available Abstract Private tertiary institutions have increasingly advertised their products in recent years to the general public in Ghana through various media. The desire to find out whether these institutions just copy other business entities blindly or that advertising actually helps in increasing their enrolments led to this study. The main aim of the study was to find out if advertising had an influence on students’ enrolment decision in private tertiary institutions. Two private universities were selected and all the students along with the admission/marketing officers of the institutions were targeted. Structured questionnaires were used to collect data from the students and unstructured interviews were organised to gather data from the admission/marketing officers. Statistical package for social sciences (SPSS was used to analyse the data. The results showed that advertising in addition to serving as a source of information to students also influenced the enrolment decision of some students. There were however other factors that influenced the enrolment decision of students such as family, friends, current students, etc that could be exploited by these institutions to their advantage.

  7. Orbital radar studies of paleodrainages in the central Namib Desert

    Science.gov (United States)

    Lancaster, N.; Schaber, G.G.; Teller, J.T.

    2000-01-01

    Orbital radar images of the central Namib Desert show clearly the extent of relict fluvial deposits associated with former courses of the Tsondab and Kuiseb rivers. South of the Kuiseb River, radar data show the existence of a drainage network developed in calcrete-cemented late Tertiary fluvial deposits. The sand-filled paleovalleys are imaged as radar-dark tones in contrast to the radar-bright interfluves where the calcreted gravels occur. The drainage network developed as a result of local runoff from indurated gravels and channeled surface and subsurface flow to the sites of the many interdune lacustrine deposits found in the area. (C) Elsevier Science Inc., 2000.Orbital radar images of the central Namib Desert show clearly the extent of relict fluvial deposits associated with former courses of the Tsondab and Kuiseb rivers. South of the Kuiseb River, radar data show the existence of a drainage network developed in calcrete-cemented late Tertiary fluvial deposits. The sand-filled paleovalleys are imaged as radar-dark tones in contrast to the radar-bright interfluves where the calcreted gravels occur. The drainage network developed as a result of local runoff from indurated gravels and channeled surface and subsurface flow to the sites of the many interdune lacustrine deposits found in the area.

  8. Literacy Skills Development for Tertiary Institutions: A Case Study of ...

    African Journals Online (AJOL)

    Literacy Skills Development for Tertiary Institutions: A Case Study of the University of Calabar. ... These were drawn from five faculties, namely Education, Social Sciences, Law, Arts and Agriculture. The study observed that there is a ... more literacy skills. Key Words: Literacy skills, university, Nigeria, tertiary institution ...

  9. Millennial-scale climate variations recorded in Early Pliocene colour reflectance time series from the lacustrine Ptolemais Basin (NW Greece)

    Science.gov (United States)

    Steenbrink, J.; Kloosterboer-van Hoeve, M. L.; Hilgen, F. J.

    2003-03-01

    Quaternary climate proxy records show compelling evidence for climate variability on time scales of a few thousand years. The causes for these millennial-scale or sub-Milankovitch cycles are still poorly understood, not least due to the complex feedback mechanisms of large ice sheets during the Quaternary. We present evidence of millennial-scale climate variability in Early Pliocene lacustrine sediments from the intramontane Ptolemais Basin in northwestern Greece. The sediments are well exposed in a series of open-pit lignite mines and exhibit a distinct millennial-scale sedimentary cyclicity of alternating lignites and lacustrine marl beds that resulted from precession-induced variations in climate. The higher-frequency, millennial-scale cyclicity is particularly prominent within the grey-coloured marl segment of individual cycles. A stratigraphic interval of ˜115 ka, covering five precession-induced sedimentary cycles, was studied in nine parallel sections from two open-pit lignite mines located several km apart. High-resolution colour reflectance records were used to quantify the within-cycle variability and to determine its lateral continuity. Much of the within-cycle variability could be correlated between the parallel sections, even in fine detail, which suggests that these changes reflect basin-wide variations in environmental conditions related to (regional) climate fluctuations. Interbedded volcanic ash beds demonstrate the synchronicity of these fluctuations and spectral analysis of the reflectance time series shows a significant concentration of within-cycle variability at periods of ˜11, ˜5.5 and ˜2 ka. The occurrence of variability at such time scales at times before the intensification of the Northern Hemisphere glaciation suggests that they cannot solely have resulted from internal ice-sheet dynamics. Possible candidates include harmonics or combination tones of the main orbital cycles, variations in solar output or periodic motions of the Earth

  10. 14 C dating and isotopic composition of lacustrine sediment in the Vale do Ribeira, south-western Sao Paulo State

    International Nuclear Information System (INIS)

    Saia, Soraya E.M.G.; Pessenda, Luiz C.R.; Gouveia, Susy E.M.; Vidotto, Elaine; Ledru, Marie-Pierre; Karmann, Ivo; Amaral, Paula G.; Bendassoli, Jose A.

    2005-01-01

    This work is part of a multi and interdisciplinary study involving paleoenvironmental records based on systematic and joint actions of pollen, isotopic composition ( 12 C, 13 C and 14 N, 15 N) and 14 C dating of lacustrine sediment. Samplings have been made in the Lagoa Grande located at Parque Estadual de Turismo do Alto Ribeira - PETAR, in the Vale do Ribeira, south-western Sao Paulo state. This integration must improve significantly the studies of vegetation and climate changes that occurred during the Late Pleistocene in the southeastern region of Brazil. The δ 13 C results of lacustrine sediment presented values from -23 to -30 per mille with isotopic tendencies of enrichment-depletion in the whole profile. The highest values of total organic carbon (TOC) and C/N associated with depleted δ 13 C values, were linked to organic matter from C 3 land plant and interpreted as the presence of denser arboreal vegetation around the lake. The smallest values of TOC and C/N associated with enriched δ 13 C values were linked to phytoplanktonic influence and/or the presence of less dense arboreal vegetation around the lake. These fluctuations reflect changes in quality and quantity of sedimentary organic matter linked to vegetation changes and the production of organic matter within the sedimentation basin connected with lake level variations. The combination of C/N and δ 13 C data on a cross-plot diagram shows a general distribution of points lying close to the planktonic (algal) organic matter. However, the scattering of certain points indicates a slight contribution from C 3 land plants. The variations in arboreal pollen (%AP) along the core are characterized by AP values between 40 and 80%. The 14C dating indicated Modern age at the shallow horizons to 1,030 years BP for the deeper horizon. (author)

  11. Corot 310266512: A Light Curve With Primary, Secondary And Tertiary Eclipses

    Directory of Open Access Journals (Sweden)

    Fernández Fernández Javier

    2015-01-01

    Full Text Available We present the photometric study of an interesting target in the CoRoT exoplanet database: CoRoT 310266512. Its light curve shows primary, secondary and tertiary eclipses that suggests the presence of at least three celestial bodies. The primary and secondary eclipses have the same orbital period, 7.42 days, and the tertiary eclipse has an orbital period of 3.27 days. Two of the tertiary eclipses fall within a primary eclipse and a secondary eclipse. The properties of the light curve indicate the presence of two physically separated systems. The primary and secondary eclipses corresponds to a binary system (System I. The tertiary eclipses correspond to a star-planet system or a star-dwarf system (System II. Some parameters of these two systems are obtained from JKTEBOP [1] program.

  12. Effects of Primary, Secondary and Tertiary Education on Conflict Intensity in Africa

    Directory of Open Access Journals (Sweden)

    Julius A. Agbor

    2015-10-01

    Full Text Available This study investigates the impact of different schooling dimensions (primary, secondary and tertiary on the intensity of intra-state conflicts in 25 African states during the period 1989–2008. It uses fixed-effects and Generalized Methods of Moments (GMM estimators in an annualized panel data framework. Parameter estimates suggest the following (1 primary schooling broadly mitigates conflicts in Africa. However, in environments with high natural resource rents, it could ignite conflicts; (2 there is evidence, although not overwhelming, that secondary schooling potentially drives conflicts in Africa. There is also evidence that urbanization potentially drives conflicts in Africa. However, although secondary schooling and urbanization potentially drives conflicts, in environments where secondary schooling (urbanization is high, urbanization (secondary schooling mitigates conflicts; (3 there is no evidence of a strong direct positive impact of tertiary education on conflicts and conditioning on tertiary schooling, income inequality potentially drives conflicts in African states. However, in contexts where income inequality (tertiary schooling is high, tertiary schooling (inequality mitigates conflict. Two important policy implications follow from this study. First, in contexts where income inequality is high (for instance, in South Africa, governments should strive to foster tertiary education in order to reduce conflict. Second, where urbanization rates are high, they should foster both secondary and tertiary education. This study contributes to existing knowledge by clearly demonstrating the utility of distinguishing between different educational dimensions and the contexts wherein they matter for conflict mitigation in Africa.

  13. Academic mentoring and the future of tertiary education in Nigeria ...

    African Journals Online (AJOL)

    Tertiary education is a major outlet for the provision of high manpower for national development. This paper therefore highlighted the challenges of tertiary education in Nigeria, early perspectives of mentoring undergraduates, the rationale for academic mentoring, the role of a mentor, and the role of library as catalyst in the ...

  14. West Hackberry Tertiary Project. Annual report, September 3, 1997--September 2, 1998

    Energy Technology Data Exchange (ETDEWEB)

    Gillham, T.H.

    1997-09-10

    The following report is the Project Management Plan for the fifth year of the West Hackberry Tertiary Project. The West Hackberry Tertiary Project is one of four mid-term projects selected by the United States Department of Energy (DOE) as part of the DOE`s Class 1 Program for the development of advance recovery technologies in fluvial dominated deltaic reservoirs. The West Hackberry Tertiary Project is a field test of the idea that air injection can be combined with the Double Displacement Process to produce a low cost tertiary recovery process which is economic at current oil prices. The Double Displacement Process is the gas displacement of a water invaded oil column for the purpose of recovering tertiary oil by gravity drainage. The Double Displacement Process is based upon the concept that in fields such as West Hackberry waterdrive recoveries are typically 50%-60% of the original oil in place while gravity drainage recoveries average 80%-90% of the original oil in place. Therefore, by injecting a gas into a watered out reservoir, a gas cap will form an additional oil can be recovered due to gravity drainage. Although the Double Displacement Process has been shown to be successful in recovering tertiary oil in other fields, this project will be the first to utilize air injection in the Double Displacement Process. The use of air injection in this process combines the benefits of air`s low cost and universal accessibility with the potential for accelerated oil recovery due to the combustion process. If successful, this project will demonstrate that the use of air injection in the Double Displacement Process will result in an economically viable tertiary process in reservoirs where tertiary oil recovery is presently uneconomical.

  15. Trophic preference and preliminary indication of phylloplane fungal influence on the diet of the non-native Gammarus roeselii Gervais 1835 (Amphipoda, Gammaridae in the sub-lacustrine Ticino river basin (Lombardy, Northern Italy

    Directory of Open Access Journals (Sweden)

    Daniele Paganelli

    2017-03-01

    Full Text Available Gammarids are one of the most successful invaders in freshwater ecosystems due to both their diet plasticity and high reproductive capacity. One such amphipod, Gammarus roeselii, has recently colonised the southern part of the sub-lacustrine Ticino River basin (Northern Italy, where its ecological niche overlaps with the native species Echinogammarus stammeri. In the present paper the food preferences of G. roeselii have been investigated, testing the palatability of different food sources: three macrophytes and three different leaf debris. Moreover, an explorative mycological analysis on the three different leaf debris used in the experiment has been performed. Results of the short-term experiment suggest that aquatic plants are less palatable than allocthonous detritus, probably because they can contain secondary metabolites (i.e. tannins and they have lower nutrient tissues with very high water content. On the contrary, G. roeselii showed a clear preference for the oak leaves, resulted colonized by a more abundant fungal biomass and, therefore, more palatable too.

  16. Tertiary-amine-containing thermo- and pH-sensitive hydrophilic ABA triblock copolymers: effect of different tertiary amines on thermally induced sol-gel transitions.

    Science.gov (United States)

    Henn, Daniel M; Wright, Roger A E; Woodcock, Jeremiah W; Hu, Bin; Zhao, Bin

    2014-03-11

    This Article reports on the synthesis of a series of well-defined, tertiary-amine-containing ABA triblock copolymers, composed of a poly(ethylene oxide) (PEO) central block and thermo- and pH-sensitive outer blocks, and the study of the effect of different tertiary amines on thermally induced sol-gel transition temperatures (T(sol-gel)) of their 10 wt % aqueous solutions. The doubly responsive ABA triblock copolymers were prepared from a difunctional PEO macroinitiator by atom transfer radical polymerization of methoxydi(ethylene glycol) methacrylate and ethoxydi(ethylene glycol) methacrylate at a feed molar ratio of 30:70 with ∼5 mol % of either N,N-diethylaminoethyl methacrylate (DEAEMA), N,N-diisopropylaminoethyl methacrylate, or N,N-di(n-butyl)aminoethyl methacrylate. The chain lengths of thermosensitive outer blocks and the molar contents of tertiary amines were very similar for all copolymers. Using rheological measurements, we determined the pH dependences of T(sol-gel) of 10 wt % aqueous solutions of these copolymers in a phosphate buffer. The T(sol-gel) versus pH curves of all polymers exhibited a sigmoidal shape. The T(sol-gel) increased with decreasing pH; the changes were small on both high and low pH sides. At a specific pH, the T(sol-gel) decreased with increasing the hydrophobicity of the tertiary amine, and upon decreasing pH the onset pH value for the T(sol-gel) to begin to increase noticeably was lower for the more hydrophobic tertiary amine-containing copolymer. In addition, we studied the effect of different tertiary amines on the release behavior of FITC-dextran from 10 wt % micellar gels in an acidic medium at 37 and 27 °C. The release profiles for three studied hydrogels at 37 °C were essentially the same, suggesting that the release was dominated by the diffusion of FITC-dextran. At 27 °C, the release was significantly faster for the DEAEMA-containing copolymer, indicating that both diffusion and gel dissolution contributed to the

  17. Isotopic identification of the source of methane in subsurface sediments of an area surrounded by waste disposal facilities

    International Nuclear Information System (INIS)

    Hackley, K.C.; Liu, C.L.; Trainor, D.

    1999-01-01

    The major source of methane (CH 4 ) in subsurface sediments on the property of a former hazardous waste treatment facility was determined using isotopic analyses measured on CH 4 and associated groundwater. The site, located on an earthen pier built into a shallow wetland lake, has had a history of waste disposal practices and is surrounded by landfills and other waste management facilities. Concentrations of CH 4 up to 70% were found in the headspace gases of several piezometers screened at 3 different depths (ranging from 8 to 17 m) in lacustrine and glacial till deposits. Possible sources of the CH 4 included a nearby landfill, organic wastes from previous impoundments and microbial gas derived from natural organic matter in the sediments.Isotopic analyses included δ 13 C, δD, 14 C, and 3 H on select CH 4 samples and δD and δ 18 O on groundwater samples. Methane from the deepest glacial till and intermediate lacustrine deposits had δ 13 C values from -79 to -82per thousand, typical of natural 'drift gas' generated by microbial CO 2 -reduction. The CH 4 from the shallow lacustrine deposits had δ 13 C values from -63 to -76per thousand, interpreted as a mixture between CH 4 generated by microbial fermentation and the CO 2 -reduction processes within the subsurface sediments. The δD values of all the CH 4 samples were quite negative ranging from -272 to -299per thousand. Groundwater sampled from the deeper zones also showed quite negative δD values that explained the light δD observed for the CH 4 . Radiocarbon analyses of the CH 4 showed decreasing 14 C activity with depth, from a high of 58 pMC in the shallow sediments to 2 pMC in the deeper glacial till. The isotopic data indicated the majority of CH 4 detected in the till deposits of this site was microbial CH 4 generated from naturally buried organic matter within the subsurface sediments. However, the isotopic data of CH 4 from the shallow piezometers was more variable and the possibility of some

  18. Isotopic identification of the source of methane in subsurface sediments of an area surrounded by waste disposal facilities

    Science.gov (United States)

    Hackley, Keith C.; Liu, Chao-Li; Trainor, D.

    1999-01-01

    The major source of methane (CH4) in subsurface sediments on the property of a former hazardous waste treatment facility was determined using isotopic analyses measured on CH4 and associated groundwater. The site, located on an earthen pier built into a shallow wetland lake, has had a history of waste disposal practices and is surrounded by landfills and other waste management facilities. Concentrations of CH4 up to 70% were found in the headspace gases of several piezometers screened at 3 different depths (ranging from 8 to 17 m) in lacustrine and glacial till deposits. Possible sources of the CH4 included a nearby landfill, organic wastes from previous impoundments and microbial gas derived from natural organic matter in the sediments. Isotopic analyses included ??13C, ??D, 14C, and 3H on select CH4 samples and ??D and ??18O on groundwater samples. Methane from the deepest glacial till and intermediate lacustrine deposits had ??13C values from -79 to -82???, typical of natural 'drift gas' generated by microbial CO2-reduction. The CH4 from the shallow lacustrine deposits had ??13C values from -63 to -76???, interpreted as a mixture between CH4 generated by microbial fermentation and the CO2-reduction processes within the subsurface sediments. The ??D values of all the CH4 samples were quite negative ranging from -272 to -299???. Groundwater sampled from the deeper zones also showed quite negative ??D values that explained the light ??D observed for the CH4. Radiocarbon analyses of the CH4 showed decreasing 14C activity with depth, from a high of 58 pMC in the shallow sediments to 2 pMC in the deeper glacial till. The isotopic data indicated the majority of CH4 detected in the fill deposits of this site was microbial CH4 generated from naturally buried organic matter within the subsurface sediments. However, the isotopic data of CH4 from the shallow piezometers was more variable and the possibility of some mixing with oxidized landfill CH4 could not be completely

  19. Hospital-acquired infections in a Nigerian tertiary health facility: An ...

    African Journals Online (AJOL)

    Hospital-acquired infections in a Nigerian tertiary health facility: An audit of surveillance reports. ... This study evaluated the occurrence of HAI in a foremost tertiary health facility over a 5-year period for the purpose of reinforcing control efforts. Materials and Methods: A retrospective survey of records from the infection control ...

  20. Interactive Intranet Portal for effective Management in Tertiary Institution

    OpenAIRE

    Idogho O. Philipa; Akpado Kenneth; James Agajo

    2011-01-01

    Interactive Intranet Portal for effective management in Tertiary Institution is an enhanced and interactive method of managing and processing key issues in Tertiary Institution, Problems of result processing, tuition fee payment, library resources management are analyzed in this work. An interface was generated to handle this problem; the software is an interactive one. Several modules are involved in the paper, like: LIBRARY CONSOLE, ADMIN, STAFF, COURSE REGISTRATION, CHECKING OF RESULTS and...

  1. Assessment Quality in Tertiary Education: An Integrative Literature Review

    OpenAIRE

    Gerritsen-van Leeuwenkamp, Karin; Joosten-ten Brinke, Desirée; Kester, Liesbeth

    2018-01-01

    In tertiary education, inferior assessment quality is a problem that has serious consequences for students, teachers, government, and society. A lack of a clear and overarching conceptualization of assessment quality can cause difficulties in guaranteeing assessment quality in practice. Thus, the aim of this study is to conceptualize assessment quality in tertiary education by providing an overview of the assessment quality criteria, their influences, the evaluation of the assessment quality ...

  2. Tertiary Treatment Process of Preserved Wastewater

    Directory of Open Access Journals (Sweden)

    Wang Qingyu

    2016-01-01

    Full Text Available The effects of the composite coagulants on coagulation sedimentation for the preserved wastewater was investigated by changing the composite coagulant dosages, and the coagulant was composed of polymeric ferric sulfate (PFS, polyaluminium chloride (PAC, and polyaluminum ferric silicate (PAFSC, while the effect of the tertiary treatment process on the preserved wastewater was tested, which was exceeded the standard seriously. The results showed that 400 mg/L was the optimum composite coagulant dosage. The removal rates of salt and sugar were as high as 99.1% and 99.5% respectively, and the removal rates of CODCr and SS were 99.3% and 96.0%, respectively after the preserved wastewater was treated by the tertiary treatment technology, which both reached the primary standard of “The Integrated Wastewater Discharge Standard” (GB8978-1996.

  3. Tertiary syphilis in the lumbar spine: a case report.

    Science.gov (United States)

    Bai, Yang; Niu, Feng; Liu, Lidi; Sha, Hui; Wang, Yimei; Zhao, Song

    2017-07-24

    The incidence of tertiary syphilis involvement in the spinal column with destructive bone lesions is very rare. It is difficult to establish the correct diagnosis from radiographs and histological examination alone. Limited data are available on surgical treatment to tertiary syphilitic spinal lesions. In this article, we report a case of tertiary syphilis in the lumbar spine with osteolytic lesions causing cauda equina compression. A 44-year-old man who suffered with low back pain for 6 months and progressive radiating pain at lower extremity for 1 week. Radiologic findings showed osteolytic lesion and new bone formation in the parts of the bodies of L4 and L5. Serum treponema pallidum hemagglutination (TPHA) test was positive. A surgery of posterior debridement, interbody and posterolateral allograft bone fusion with instrumentation from L3 to S1 was performed. The low back pain and numbness abated after operation. But the follow-up radiographs showed absorption of the bone grafts and failure of instrumentation. A Charcot's arthropathy was formed between L4 and L5. It is challenging to diagnose the tertiary syphilis in the spine. Surgery is a reasonable auxiliary method to antibiotic therapy for patients who suffered with neuropathy. Charcot's arthropathy should be considered as an operative complication.

  4. Analysis of colonoscopic perforations at a local clinic and a tertiary hospital.

    Science.gov (United States)

    Sagawa, Toshihiko; Kakizaki, Satoru; Iizuka, Haruhisa; Onozato, Yasuhiro; Sohara, Naondo; Okamura, Shinichi; Mori, Masatomo

    2012-09-21

    To define the clinical characteristics, and to assess the management of colonoscopic complications at a local clinic. A retrospective review of the medical records was performed for the patients with iatrogenic colon perforations after endoscopy at a local clinic between April 2006 and December 2010. Data obtained from a tertiary hospital in the same region were also analyzed. The underlying conditions, clinical presentations, perforation locations, treatment types (operative or conservative) and outcome data for patients at the local clinic and the tertiary hospital were compared. A total of 10  826 colonoscopies, and 2625 therapeutic procedures were performed at a local clinic and 32  148 colonoscopies, and 7787 therapeutic procedures were performed at the tertiary hospital. The clinic had no perforations during diagnostic colonoscopy and 8 (0.3%) perforations were determined to be related to therapeutic procedures. The perforation rates in each therapeutic procedure were 0.06% (1/1609) in polypectomy, 0.2% (2/885) in endoscopic mucosal resection (EMR), and 3.8% (5/131) in endoscopic submucosal dissection (ESD). Perforation rates for ESD were significantly higher than those for polypectomy or EMR (P hospital. Six perforations occurred with therapeutic endoscopy (perforation rate, 0.08%; 1 per 1298 procedures). Perforation rates for specific procedure types were 0.02% (1 per 5500) for polypectomy, 0.17% (1 per 561) for EMR, 2.3% (1 per 43) for ESD in the tertiary hospital. There were no differences in the perforation rates for each therapeutic procedure between the clinic and the tertiary hospital. The incidence of iatrogenic perforation requiring surgical treatment was quite low in both the clinic and the tertiary hospital. No procedure-related mortalities occurred. Performing closure with endoscopic clipping reduced the C-reactive protein (CRP) titers. The mean maximum CRP titer was 2.9 ± 1.6 mg/dL with clipping and 9.7 ± 6.2 mg/dL without clipping

  5. Pushing the frontiers of atomic models for protein tertiary structure ...

    Indian Academy of Sciences (India)

    as an NP complete or NP hard problem.4,5 This notwith- standing, the dire need for tertiary structures of proteins in drug discovery and other areas6–8 has propelled the development of a multitude of computational recipes. In this article, we focus on ab initio/de novo strategies,. Bhageerath in particular, for protein tertiary ...

  6. Tertiary colleges: a study of perspectives on organizational innovation

    OpenAIRE

    Preedy, Margaret

    1998-01-01

    The purpose of this research study was to explore organisational innovation in education with reference to one particular type of organisation - the tertiary college. The research sought to examine the extent to which the intended objectives for new educational organisations are realised in practice, and how far the goals and ethos which organisational leaders seek to promote are shared by organisational members. The study focused on eleven tertiary colleges, comparing the 'official' view of ...

  7. Rethinking the Tertiary Mathematics Curriculum

    Science.gov (United States)

    Petocz, Peter; Reid, Anna

    2005-01-01

    Mathematics curriculum at the tertiary level is located within a range of social and cultural theories, and is often constructed by academics seeking to promulgate a particular view of mathematics. We argue that such a curriculum should incorporate a real acknowledgement of the different ways in which students understand the nature of mathematics…

  8. General Allylic C–H Alkylation with Tertiary Nucleophiles

    Science.gov (United States)

    2015-01-01

    A general method for intermolecular allylic C–H alkylation of terminal olefins with tertiary nucleophiles has been accomplished employing palladium(II)/bis(sulfoxide) catalysis. Allylic C–H alkylation furnishes products in good yields (avg. 64%) with excellent regio- and stereoselectivity (>20:1 linear:branched, >20:1 E:Z). For the first time, the olefin scope encompasses unactivated aliphatic olefins as well as activated aromatic/heteroaromatic olefins and 1,4-dienes. The ease of appending allyl moieties onto complex scaffolds is leveraged to enable this mild and selective allylic C–H alkylation to rapidly diversify phenolic natural products. The tertiary nucleophile scope is broad and includes latent functionality for further elaboration (e.g., aliphatic alcohols, α,β-unsaturated esters). The opportunities to effect synthetic streamlining with such general C–H reactivity are illustrated in an allylic C–H alkylation/Diels–Alder reaction cascade: a reactive diene is generated via intermolecular allylic C–H alkylation and approximated to a dienophile contained within the tertiary nucleophile to furnish a common tricyclic core found in the class I galbulimima alkaloids. PMID:24641574

  9. General allylic C-H alkylation with tertiary nucleophiles.

    Science.gov (United States)

    Howell, Jennifer M; Liu, Wei; Young, Andrew J; White, M Christina

    2014-04-16

    A general method for intermolecular allylic C-H alkylation of terminal olefins with tertiary nucleophiles has been accomplished employing palladium(II)/bis(sulfoxide) catalysis. Allylic C-H alkylation furnishes products in good yields (avg. 64%) with excellent regio- and stereoselectivity (>20:1 linear:branched, >20:1 E:Z). For the first time, the olefin scope encompasses unactivated aliphatic olefins as well as activated aromatic/heteroaromatic olefins and 1,4-dienes. The ease of appending allyl moieties onto complex scaffolds is leveraged to enable this mild and selective allylic C-H alkylation to rapidly diversify phenolic natural products. The tertiary nucleophile scope is broad and includes latent functionality for further elaboration (e.g., aliphatic alcohols, α,β-unsaturated esters). The opportunities to effect synthetic streamlining with such general C-H reactivity are illustrated in an allylic C-H alkylation/Diels-Alder reaction cascade: a reactive diene is generated via intermolecular allylic C-H alkylation and approximated to a dienophile contained within the tertiary nucleophile to furnish a common tricyclic core found in the class I galbulimima alkaloids.

  10. Holocene glacier fluctuations inferred from lacustrine sediment, Emerald Lake, Kenai Peninsula, Alaska

    Science.gov (United States)

    LaBrecque, Taylor S.; Kaufman, Darrell S.

    2016-01-01

    Physical and biological characteristics of lacustrine sediment from Emerald Lake were used to reconstruct the Holocene glacier history of Grewingk Glacier, southern Alaska. Emerald Lake is an ice-marginal threshold lake, receiving glaciofluvial sediment when Grewingk Glacier overtops the topographic divide that separates it from the lake. Sub-bottom acoustical profiles were used to locate core sites to maximize both the length and resolution of the sedimentary sequence recovered in the 4-m-long cores. The age model for the composite sequence is based on 13 14C ages and a 210Pb profile. A sharp transition from the basal inorganic mud to organic-rich mud at 11.4 ± 0.2 ka marks the initial retreat of Grewingk Glacier below the divide of Emerald Lake. The overlaying organic-rich mud is interrupted by stony mud that records a re-advance between 10.7 ± 0.2 and 9.8 ± 0.2 ka. The glacier did not spill meltwater into the lake again until the Little Ice Age, consistent with previously documented Little Ice Ages advances on the Kenai Peninsula. The retreat of Grewingk Glacier at 11.4 ka took place as temperature increased following the Younger Dryas, and the subsequent re-advance corresponds with a climate reversal beginning around 11 ka across southern Alaska.

  11. [Decomposition model of energy-related carbon emissions in tertiary industry for China].

    Science.gov (United States)

    Lu, Yuan-Qing; Shi, Jun

    2012-07-01

    Tertiary industry has been developed in recent years. And it is very important to find the factors influenced the energy-related carbon emissions in tertiary industry. A decomposition model of energy-related carbon emissions for China is set up by adopting logarithmic mean weight Divisia method based on the identity of carbon emissions. The model is adopted to analyze the influence of energy structure, energy efficiency, tertiary industry structure and economic output to energy-related carbon emissions in China from 2000 to 2009. Results show that the contribution rate of economic output and energy structure to energy-related carbon emissions increases year by year. Either is the contribution rate of energy efficiency or the tertiary industry restraining to energy-related carbon emissions. However, the restrain effect is weakening.

  12. bilingualism in the english of tertiary students: a sine-qua-non

    African Journals Online (AJOL)

    REV YOUNG EZENWA OBIOHA

    questions were used to investigate the effects of Bilingualism on the English of tertiary students. A total of three hundred students from two tertiary institutions were used. ... thoughts, inner feelings, personal psychological ... Chinese migration to the U.S.A (Akindele & ... child is taught Mathematical multiplication and division ...

  13. Epilepsy in Ireland: towards the primary-tertiary care continuum.

    Science.gov (United States)

    Varley, Jarlath; Delanty, Norman; Normand, Charles; Coyne, Imelda; McQuaid, Louise; Collins, Claire; Boland, Michael; Grimson, Jane; Fitzsimons, Mary

    2010-01-01

    Epilepsy is a chronic neurological disease affecting people of every age, gender, race and socio-economic background. The diagnosis and optimal management relies on contribution from a number of healthcare disciplines in a variety of healthcare settings. To explore the interface between primary care and specialist epilepsy services in Ireland. Using appreciative inquiry, focus groups were held with healthcare professionals (n=33) from both primary and tertiary epilepsy specialist services in Ireland. There are significant challenges to delivering a consistent high standard of epilepsy care in Ireland. The barriers that were identified are: the stigma of epilepsy, unequal access to care services, insufficient human resources, unclear communication between primary-tertiary services and lack of knowledge. Improving the management of people with epilepsy requires reconfiguration of the primary-tertiary interface and establishing clearly defined roles and formalised clinical pathways. Such initiatives require resources in the form of further education and training and increased usage of information communication technology (ICT). Epilepsy services across the primary-tertiary interface can be significantly enhanced through the implementation of a shared model of care underpinned by an electronic patient record (EPR) system and information communication technology (ICT). Better chronic disease management has the potential to halt the progression of epilepsy with ensuing benefits for patients and the healthcare system. Copyright 2009 British Epilepsy Association. Published by Elsevier Ltd. All rights reserved.

  14. Tertiary proton diagnostics in future inertial confinement fusion experiments

    International Nuclear Information System (INIS)

    Cremer, S.; Verdon, C.P.; Petrasso, R.D.

    1998-01-01

    Recently, it was proposed to use energetic (up to 31 MeV) tertiary protons produced during the final stage of inertial confinement fusion implosions to measure the fuel areal density of compressed deuterium endash tritium (DT). The method is based on seeding the fuel with 3 He. The reaction of 3 He ions with the energetic knock-on deuterons, produced via the elastic scattering of 14.1 MeV neutrons, is a source of very energetic protons capable of escaping from very large areal density targets. This work presents results of detailed time-dependent Monte Carlo simulations of the nuclear processes involved in producing and transporting these protons through imploding targets proposed for direct-drive experiments on OMEGA [D. K. Bradley et al., Phys. Plasmas 5, 1870 (1998)] and the National Ignition Facility [S. W. Haan et al., Phys. Plasmas 2, 2480 (1995)]. copyright 1998 American Institute of Physics

  15. Recruitment Of International Students Into Cameroon Tertiary ...

    African Journals Online (AJOL)

    Recruitment Of International Students Into Cameroon Tertiary Institutions In The Absence Of International Offices. ... The present system of recruiting international students is haphazardly been handled by ... AJOL African Journals Online.

  16. A retrospective review of snake bite victims admitted in a tertiary ...

    African Journals Online (AJOL)

    Objective: Snake bite remains major public health problem worldwide. We present our experience with cases of snake bites managed in our tertiary care teaching center of South India. Materials and Methods: The details of all patients with snake bite admitted to a tertiary teaching care hospital from 2010 to 2012 were ...

  17. Internships enhancing entrepreneurial intent and self-efficacy: Investigating tertiary-level entrepreneurship education programmes

    Directory of Open Access Journals (Sweden)

    Melodi Botha

    2016-09-01

    Full Text Available Background: Entrepreneurship education interventions are deemed effective when they enhance interns’ entrepreneurial intent (EI and entrepreneurial self-efficacy (ESE. Notwithstanding the emergence of internship as an experiential learning approach in entrepreneurship education, evidence about their potential to foster EI and ESE lacks systemisation. Aim: The aim of this study was to determine whether internships enhance EI and ESE. Furthermore, to what extent South African tertiary institutions include internships in their entrepreneurship and management curricula and the obstacles to such inclusion. Setting: South Africa has made a concerted effort to insert an entrepreneurship component across tertiary curricula. The evolution of this entrepreneurship component to experiential learning approaches is, however, unclear. Methods: A qualitative research approach was followed. Firstly, it reviewed empirical evidence for the positive relationship between internships and EI and ESE. Secondly, it conducted a survey of entrepreneurship and business management programmes at all 23 South African tertiary institutions and content analysed the retrieved information to determine whether such programmes include internships. Finally, 10 experts were interviewed to unveil the constraints inhibiting the inclusion of internships in tertiary curricula. Results: The results revealed empirical support for the positive influence of internships on both EI and ESE. Significant lack of inclusion of internships in tertiary curricula in South Africa emerged, owing mainly to administrative issues, curriculum re-design challenges, and lack of mentoring capacity. Conclusion: Tertiary-level entrepreneurship education programmes should include an internship component. The paper suggested that tertiary institutions pilot-test the inclusion of internships with a small number of students and a selected cohort of small business owners.

  18. Characteristics and risk factors of preterm births in a tertiary center in ...

    African Journals Online (AJOL)

    Characteristics and risk factors of preterm births in a tertiary center in Lagos, Nigeria. ... Introduction: preterm birth is a dire complication of pregnancy that poses ... to a tertiary center for prenatal care in order to significantly reduce adverse birth ...

  19. Analysis of Management Practices in Lagos State Tertiary Institutions through Total Quality Management Structural Framework

    Science.gov (United States)

    AbdulAzeez, Abbas Tunde

    2016-01-01

    This research investigated total quality management practices and quality teacher education in public tertiary institutions in Lagos State. The study was therefore designed to analyse management practices in Lagos state tertiary institutions through total quality management structural framework. The selected public tertiary institutions in Lagos…

  20. Behavior of diatomaceous soil in lacustrine deposits of Bogotá, Colombia

    Directory of Open Access Journals (Sweden)

    Bernardo Caicedo

    2018-04-01

    Full Text Available This work presents a study on the behaviors of diatomaceous soils. Although studies are rarely reported on these soils, they have been identified in Mexico City, the Sea of Japan, the northeast coast of Australia, the equatorial Pacific, and the lacustrine deposit of Bogotá (Colombia, among other locations. Features of this kind of soil include high friction angle, high initial void ratio, high compressibility index, high liquid limit, and low density. Some of these features are counterintuitive from a classical soil mechanics viewpoint. To understand the geotechnical properties of the diatomaceous soil, a comprehensive experimental plan consisting of more than 2400 tests was performed, including physical tests such as grain size distribution, Atterberg limits, density of solid particles, and organic matter content; and mechanical tests such as oedometric compression tests, unconfined compression tests, and triaxial tests. Laboratory tests were complemented with scanning electron microscope (SEM observations to evaluate the microstructure of the soil. The test results show that there is an increase in liquid limit with increasing diatomaceous content, and the friction angle also increases with increasing diatomaceous content. In addition, several practical correlations were proposed for this soil type for shear strength mobilization and intrinsic compression line. Finally, useful correlations were presented, such as the relationship between the state consistency and the undrained shear strength, the friction angle and the liquid limit, the void ratio at 100 kPa and the liquid limit, the plasticity index and the diatomaceous content, among others. Keywords: Diatomaceous soil, Soft soils, Compressibility, Friction angle, Natural soil

  1. Hydrothermal alteration and diagenesis of terrestrial lacustrine pillow basalts: Coordination of hyperspectral imaging with laboratory measurements

    Science.gov (United States)

    Greenberger, Rebecca N.; Mustard, John F.; Cloutis, Edward A.; Mann, Paul; Wilson, Janette H.; Flemming, Roberta L.; Robertson, Kevin M.; Salvatore, Mark R.; Edwards, Christopher S.

    2015-12-01

    We investigate an outcrop of ∼187 Ma lacustrine pillow basalts of the Talcott Formation exposed in Meriden, Connecticut, USA, focusing on coordinated analyses of one pillow lava to characterize the aqueous history of these basalts in the Hartford Basin. This work uses a suite of multidisciplinary measurements, including hyperspectral imaging, other spectroscopic techniques, and chemical and mineralogical analyses, from the microscopic scale up to the scale of an outcrop. The phases identified in the sample are albite, large iron oxides, and titanite throughout; calcite in vesicles; calcic clinopyroxene, aegirine, and Fe/Mg-bearing clay in the rind; and fine-grained hematite and pyroxenes in the interior. Using imaging spectroscopy, the chemistry and mineralogy results extend to the hand sample and larger outcrop. From all of the analyses, we suggest that the pillow basalts were altered initially after emplacement, either by heated lake water or magmatic fluids, at temperatures of at least 400-600 °C, and the calcic clinopyroxenes and aegirine identified in the rind are a preserved record of that alteration. As the hydrothermal system cooled to slightly lower temperatures, clays formed in the rind, and, during this alteration, the sample oxidized to form hematite in the matrix of the interior and Fe3+ in the pyroxenes in the rind. During the waning stages of the hydrothermal system, calcite precipitated in vesicles within the rind. Later, diagenetic processes albitized the sample, with albite replacing plagioclase, lining vesicles, and accreting onto the exterior of the sample. This albitization or Na-metasomatism occurred when the lake within the Hartford Basin evaporated during a drier past climatic era, resulting in Na-rich brines. As Ca-rich plagioclase altered to albite, Ca was released into solution, eventually precipitating as calcite in previously-unfilled vesicles, dominantly in the interior of the pillow. Coordinated analyses of this sample permit

  2. Determination of consumption biogenic solid fuels in the commercial sector, trade, services (tertiary sector). Final report

    International Nuclear Information System (INIS)

    Viehmann, Cornelia; Westerkamp, Tanja; Schwenker, Andre; Schenker, Marian; Thraen, Daniela; Lenz, Volker; Ebert, Marcel

    2012-01-01

    The policy has both national and European level ambitious program aimed at expansion of renewable energy and related to the reduction of greenhouse gas emissions. In the national action plan for renewable energy of the Federal Republic of Germany these goals are defined by 2020. The share of renewable energy in the provision of heat and cold should therefore rise from 6.6% to 15.5% of gross final energy consumption. According to the increasing importance of solar-thermal, near-surface and geothermal heat, the relative share of biomass is decreasing. However biomass makes with those listed in the national action plan with 79% an essential amount in regenerative heat market [BMU 2010]. For the pursuit of goals and reviews, the support measures and packages of measures which are initiated in this context, a regular and timely reporting on the development of the above objectives is mandatory. The diverse and growing reporting requirements such as in the EU directive on the promotion of renewable energy, require, however well-founded knowledge of the sector-specific energy consumption from renewable sources. While the data available for use of biogenic solid fuels in the sectors household and industry has improved significantly in recent years, for the sector commercial sector, trade, services (tertiary sector) reliable figures are still lacking. Against this background, the objective is to present study, in close cooperation with the Federal Environment Agency (UBA), the determination of the final energy consumption biogenic solid fuels in the tertiary sector in Germany for the year 2008. The basis is, in addition to the development of the current knowledge of the energy and heat consumption, the delimitation and characterization of the sector and the development of an extrapolation tools. The demand for this tool is its expandability and update possibility. From the industry-nonspecific and industry-specific input data can be derived, collecting for the extrapolation

  3. Frozen Chirality of Tertiary Aromatic Amides: Access to Enantioenriched Tertiary α-Amino Acid or Amino Alcohol without Chiral Reagent.

    Science.gov (United States)

    Mai, Thi Thoa; Viswambharan, Baby; Gori, Didier; Guillot, Régis; Naubron, Jean-Valère; Kouklovsky, Cyrille; Alezra, Valérie

    2017-04-27

    One of the fundamental and intriguing aspects of life is the homochirality of the essential molecules. In this field, the absolute asymmetric synthesis of α-amino acids is a major challenge. Herein, we report access, by chemical means, to tertiary α-amino acid derivatives in up to 96 % ee without using any chiral reagent. In our strategy, the dynamic axial chirality of tertiary aromatic amides is frozen in a crystal and is responsible for the stereoselectivity of the subsequent steps. Furthermore, we could control the configuration of the final product by manually sorting and selecting the initial crystals. Based on vibrational circular dichroism studies, we could rationalize the observed stereoselectivity. © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. Tertiary classes–after Chern-Simons theory

    Indian Academy of Sciences (India)

    J.N. Iyer Institute of Mathematical Sciences Chennai, India

    2013-11-08

    Nov 8, 2013 ... Euler characteristic class. In early twentieth century, the notion of local product structure, i.e. fiber spaces and their generalizations appeared, in the study of topological spaces (with additional structures). J.N. Iyer. IMSc, Chennai. Tertiary classes–after Chern-Simons theory ...

  5. Evidences of melting of terrestrial sediments and paleoenvironment changes during the Younger Dryas in tectonic lacustrine basins of Transmexican Volcanic Belt, Mexico.

    Science.gov (United States)

    Israde-Alcantara, I.

    2017-12-01

    It is well known in the sedimentary record of several parts of the world that during the Younger Dryas interval (YD) ocurred an abrupt environmental change between 12,900 and 11,700 cal yr BP (10,900 to 10,000 14C BP). In the lacustrine basins this changes are often preserved and in some Mexican lakes this is a distinctive stratigraphic marker for the YD. We analized the proxies of this event in cores of two lakes (Chapala, Cuitzeo) and three trenches of ex-lakes (Acambay,Texcoco and El Cedral). Deposits consist of fine detrital material with often Pleistocene fossil vertebrate assemblages. At the Chapala, Cuitzeo, Acambay, and Tocuila lacustrine environments are found in association with a distinctive dark organic layer showing sharp changes in the diatom, pollen, mineralogical and geochemical record. Includes also microscopic magnetic, Fe-rich spherules, silica melted droplets with aerodynamic shapes (tektites), followed by large amounts of charcoal, and sometimes nanodiamonds (Cuitzeo), that were deposited at the onset of the YD or in the limit Pleistocene-Holocene. These unusual materials are buried more than 2.50 meters and were not observed above or below the Younger Dryas sediments at these sites. The geochemistry of the microspherules indicates that they are not volcanic, anthropogenic or authigenic origin. A very distinctive feature is the shape of the spherules, ovoid, polygonal, filigreed or dendritic indicating melting and quenching infering that are product of an impact event. Their morphologies includes hollow shells caused by de-gassing of elements at very high temperatures causing a flattened side with a "skirt" structure by a high-velocity collision.Our results are consistent with the Firestone hypothesis.

  6. Tertiary Journalism Education: Its Value in Cadet Selection at Metropolitan Media.

    Science.gov (United States)

    Alysen, Barbara

    2001-01-01

    Notes tertiary study in journalism has been a feature of the education of Australian journalists for decades, yet many industry representatives remain skeptical of its value. Finds applicants for entry-level jobs with a tertiary journalism qualification can expect to secure, on average, at least half the available positions in any cadet or trainee…

  7. Transition and Tertiary Education: A Case Study of Mzuzu University, Malawi

    Science.gov (United States)

    Zozie, Paxton Andrew; Kayira, Peter Benwell

    2012-01-01

    This article reviews the role of guidance and counselling in Malawi in reducing dropout and easing the transition of students to tertiary education, as well as in helping them during their time in tertiary education. It begins by identifying key success factors in guidance and counselling services for learners in both developed and developing…

  8. Spatial distribution of saline water and possible sources of intrusion ...

    African Journals Online (AJOL)

    user

    transitional effects on the lacustrine ichthyofaunal characteristics were studied during March, 2006 and ... acidification, heavy metal contamination, organic pollution .... Table 1 shows 18 sampling stations of water samples for salt water.

  9. Sexual harassment in tertiary institutions: A comparative perspective

    Directory of Open Access Journals (Sweden)

    Joseph Janice

    2015-01-01

    Full Text Available Sexual harassment is not a new phenomenon in tertiary institutions. It has been receiving considerable attention in research and the media and public awareness has increased dramatically. However, the term sexual harassment is not used uniformly across the globe because countries have defined it differently. Consequently, prevalence of sexual harassment in education varies across cultures. This paper examines sexual harassment from a comparative perspective. It specifically focuses on the definition of sexual harassment, incidence of sexual harassment of students in tertiary institutions, effects of sexual harassment on victims; and victims’ responses to sexual harassment. It also offers suggestions for curtailing sexual harassment in these institutions.

  10. Radiometric and Instrumental Neutron Activation Analysis (INAA) of environmental specimens: lacustrine sediments from Danube Delta

    International Nuclear Information System (INIS)

    Duliu, Octavian G.

    2002-01-01

    specificity analytical methods such as Instrumental Neutron Activation Analysis (INAA) could evidence more than 40 different elements at concentrations about ppm or lower. Unwanted events as atmospheric nuclear tests and Chernobyl accident discharged a great amount of radioactive 137 Cs that once fixed into sediments represents an excellent tracer for natural processes such as sediment transport, accumulation and redistribution during the last 40-50 years. For multielemental investigation of environmental samples such as soil, sediments, water or various minerals INAA is one of the most suitable technique. Presumably pollutants elements such as Cr, Co, Zn, As, Sb and Br as well as REE that could be easily determined by INAA are helpful indicators of the source as well as of the mechanism of deposition and incorporation of these components. Investigated in correlation with radiocesium distribution as well as some natural trace elements such as REE, Sc or Hf, their vertical profiles in sediments allows a rapid reconstruction of the history of recent pollution processes. Radiometric and INAA measurements have been performed 'in tandem' for sediments collected from different lakes located in both Fluvial (western part) and Fluvio-maritime (eastern part and the Razelm-Sinoe lacustrine complex) sections of the Danube Delta, i.e. Lung, Mesteru, Matita, Furtuna and Merhei as well as Razelm and Leahova, respectively. A review of these investigations concerning the vertical profiles of 4 major elements (Na, K, Ca and Fe), 15 trace elements (Rb, Cs, Ba, Sc, La, Ce, Sm, Eu, Tb, Yb, Lu, Th, U, Hf and Ta) as well as of 6 potential pollutants (Zn, Cr, Co, As, Sb and Br) in four lakes (Lung, Furtuna, Mester and Matita) together with anthropogenic 134 Cs and 137 Cs is presented. All these results reveal the great potential of radiometric as well as INAA in environmental as well as in geological investigations. (author)

  11. The equity imperative in tertiary education: Promoting fairness and efficiency

    Science.gov (United States)

    Salmi, Jamil; Bassett, Roberta Malee

    2014-06-01

    While the share of the tertiary education age cohort (19-25) which is being given the opportunity to study has increased worldwide over the past two decades, this does not in fact translate into reduced inequality. For many young people, especially in the developing world, major obstacles such as disparities in terms of gender, minority population membership or disabilities as well as academic and financial barriers are still standing in their way. The authors of this article propose a conceptual framework to analyse equity issues in tertiary education and document the scope, significance and consequences of disparities in tertiary education opportunities. They throw some light on the main determinants of these inequalities and offer suggestions about effective equity promotion policies directed towards widening participation and improving the chances of success of underprivileged youths in order to create societies which uphold humanistic values.

  12. Auditing surgical service provision at a South African tertiary institution: Implications for the development of district services.

    Science.gov (United States)

    Laing, G L; Skinner, D L; Bruce, J L; Aldous, C; Govindasamy, V; Thomson, S R; Clarke, D L

    2017-11-01

    The optimal management of resources within South African state hospitals has been hampered by a paucity of data due to a lack of robust auditing information systems. This study reviews the use of a Hybrid Electronic Medical Record (HEMR) system to capture and aggregate data pertaining to the inpatient service demands on a South African tertiary surgical service. This dataset was used to analyse the appropriateness of tertiary surgical resource utilisation. The HEMR system was implemented at Greys Hospital, in the city of Pietermaritzburg, Kwa-Zulu Natal, South Africa on 1 January 2013. Inpatient data pertaining to surgical admissions and operative interventions were captured prospectively. Following an 18-month study period, the data were extracted, aggregated and analysed. The district referral hospitals were mapped, and district surgical procedures performed within the tertiary center were identified and quantified. Results: 7314 patients were admitted and managed by the tertiary surgical service during the study period. The median patient age was 33 years (IQR 6.5-42.4 years). 59.7% were male and 40.3% were female. General, trauma and paediatric surgical admissions constituted 54.8%, 28.6% and 16.6% respectively. Emergency admissions constituted 62.4% and elective admissions 37.6%. Referral sources were captured for 6653 (91%) of the cohort. 4338 (65.2%) patients were referred from district hospitals. The district hospital (Northdale) closest to Greys Hospital was responsible for 1675 (25.2%) of surgical referrals. 4174 operative procedures were performed during the study period, 54.7% performed as an emergency, 34.1% electively and 11.2% semi-electively. The median waiting time for emergency operative intervention was 535 minutes (IQR 130-663). A total of 1272 (30.5%) operative procedures performed were assessed as district-level operations. The time intervals of 07:00-07:59 and 17:00-17:59 were identified as the time periods during which the least number of

  13. Preliminary study of the uranium favorability of Mesozoic intrusive and Tertiary volcanic and sedimentary rocks of the Central Mojave Desert, Kern and San Bernardino counties, California

    International Nuclear Information System (INIS)

    Leedom, S.H.; Kiloh, K.D.

    1978-02-01

    Numerous, small, low-grade, supergene uranium deposits are found in Tertiary volcanic and sedimentary rocks in the central Mojave Desert of southern California. Large thorium-to-uranium ratios in samples of Mesozoic intrusive rocks exposed in the area indicate that these rocks have been extensively weathered, eroded, and subsequently leached by ground waters, and that they may have been the primary source of uranium for the deposits. The uranium content of samples of volcanic intrusive and extrusive rocks is average for intermediate to silicic rocks, but samples of basalt flows in the area contain six times the average uranium content of mafic igneous rocks. Devitrified tuffs and tuffaceous sedimentary rocks, interbedded with calcareous units, are additional sources of uranium for supergene uranium deposits found in calcareous units. Uranium is also found in accessory minerals in a few Mesozoic quartz-rich pegmatite dikes. Uranium deposits in the central Mojave Desert have been formed by enrichment during diagenetic replacement of Tertiary carbonate rocks; by supergene enrichment along fractures, joints, and bedding planes in Tertiary volcanic and sedimentary rocks; during formation of Holocene caliche; and by deposition within hydrothermally altered shear zones. Within the area, the diagenetic replacement type of deposit has the greatest potential for large, low-grade uranium occurrences. The other type of uranium deposits are small, erratically distributed, and extensively covered by alluvium

  14. Lithofacies-paleo-geography and uranium sedimentary facies in Hailar basin

    International Nuclear Information System (INIS)

    Qi Fucheng

    1992-01-01

    Cretaceous-Tertiary sedimentary paleo-structure and lithofacies-paleo-geography in Hailar Basin are described. Taking Chenqi coal field as an example, the sedimentary facies pattern of coal-bearing series characterized by alternating sedimentation of fluviatile and lacustrine-swampy facies is reconstructed. It is pointed out that this sedimentary facies not only controls the sedimentation and distribution of syngenetic uranium mineralization, but also is a favourable place that converges uranium-bearing solution and reduces and precipitates uranium for the second time in epigenetic mineralization

  15. Wildfires and animal extinctions at the Cretaceous/Tertiary boundary

    Science.gov (United States)

    Adair, Robert K.

    2010-06-01

    Persuasive models of the ejection of material at high velocities from the Chicxulub asteroid impact marking the Cretaceous/Tertiary boundary have led to the conclusion that upon return, that material, heated in passage through the upper atmosphere, generated a high level of infrared energy density over the Earth's surface. That radiant energy has been considered to be a direct source of universal wildfires, which were presumed to be a major cause of plant and animal species extinctions. The extinction of many animal species, especially the dinosaurs, has also been attributed to the immediate lethal effects of the radiation. I find that the absorption of the radiation by the atmosphere, by cloud formations, and by ejecta drifting in the lower atmosphere reduced the radiation at the surface to a level that cannot be expected to have generated universal fires. Although the reduced radiation will have likely caused severe injuries to many animals, such insults alone seem unlikely to have generated the overall species extinctions that have been deduced.

  16. Learning Enhancement in Tertiary Institutions Using Mobile ...

    African Journals Online (AJOL)

    2012-12-01

    Dec 1, 2012 ... model that is still by far the dominant mode of education and learning in tertiary institutions. In addition to identifying ... education has there been a technology that ..... Determinant of Mobile Learning Acceptance: An Empirical.

  17. Influence Factor of Tertiary Students’ Employability Awareness Adjust Industry 4.0

    Directory of Open Access Journals (Sweden)

    Chun-Mei Chou

    2017-09-01

    Full Text Available This study aims to analyze the correlation (N=621 among tertiary students’ career planning, erecruiting adoption acceptance, and employability awareness in Taiwan. Tertiary students’ perceived career planning includes four factors, namely, self-appraisal, job expectancy, goal selection, and problem solving. E-recruiting adoption acceptance includes four factors, namely, playfulness, ease of use, effectiveness, and usefulness. Employability awareness includes four factors, namely, personal adaptability, employability ambition, career identity, and labour market. Participants responded to a 5-point Likert-type scale for each factor. Analysis was conducted using the structural equation modeling (SEM, and a good model fit was found for both the measurement and structural models. Research findings demonstrate that tertiary students’ career planning significantly and directly influences employability awareness. Career planning significantly and indirectly influences employability awareness by e-recruiting adoption acceptance. Tertiary students’ career planning and e-recruiting adoption acceptance fit the influence model and empirical data of employability awareness. Implications of this study, including the value of student self-assessment of their skills and utility of the e-recruiting to underpin personal career development planning and inform graduate recruitment processes, are discussed and recommendations made.

  18. A theoretical analysis of procurement auctions for tertiary control in Germany

    International Nuclear Information System (INIS)

    Mueller, Gernot; Rammerstorfer, Margarethe

    2008-01-01

    As far as energy policy is concerned, the design of the regulatory framework for energy transmission and distribution is a key issue. Consequently, also the embodiment of balancing power markets drives mainly the effectiveness of political implications for the energy sector. Initially, tertiary control in Germany was solely offered by transmission system operators of the respective power control areas and their associated power plant. The recast of the Energy Industry Act of 2005 led in last consequence to a common procurement auction for the supply of tertiary control, which starts on December 1, 2006. Admittedly, the reform has fallen short of expectations so far, first concerning the intensification of market entry of tertiary control providers as well as the desired decline of the price level. Hence, this article examines the effects of the changeover on observable demand charges. In order to identify attributes of the common procurement auction for tertiary control hampering market entry of providers, giving stimuli to collusion and strategic behavior, reducing intensity of competition and encouraging an upswing of prices, we analyze the design under an auction theoretical approach and deduce empirically whether structural components of the auction design have to be touched up again

  19. A Collaborative Governance Approach to Improving Tertiary Education in Papua New Guinea

    Science.gov (United States)

    Eldridge, Kaye; Larry, Lisa; Baird, Jeanette; Kavanamur, David

    2018-01-01

    Tertiary education in Papua New Guinea (PNG) is in a critical state, as the sector struggles to address increased demand for student places with severely curtailed capacity. Recent thinking about improving public services in PNG has emphasized "whole of sector" or collaborative governance. Such an approach in tertiary education has the…

  20. Tertiary Education and the Crisis of Public Finance

    Directory of Open Access Journals (Sweden)

    Milos Maryska

    2012-04-01

    Full Text Available Turbulent economic environment after overwhelming the last crisis period is typical for present days as well as permanent increasing dependability of all our activities on information and communication technology (ICT. Although the global economic crisis was the reason for disinvestment into ICT in 2009 there is expected that ICT will generate almost 5.8 million new jobs in Europe till year 2013 and they have to be saturated also by adequately qualified ICT specialists.This contribution presents the research in the progress focused on the tertiary education system in the Czech Republic. We are predicting trends in education and especially in ICT education in Europe and in the Czech Republic as well for next ten years. We can expect that future ten years period will be critical not only for the Czech tertiary education system, but also for the Czech Republic because number of ICT students will be decreasing and number of ICT specialist demanded by labor market will be increasing. From macroeconomic point of view we can expect that also state subventions into state governed tertiary education system will decrease in the whole Europe.Some recommendations, proposals and forecasts for further development of education system are presented at the end of this contribution.

  1. The effects of tertiary treated municipal wastewater on fish communities of a small river tributary in Southern Ontario, Canada

    International Nuclear Information System (INIS)

    Brown, Carolyn J.M.; Knight, Brendan W.; McMaster, Mark E.; Munkittrick, Kelly R.; Oakes, Ken D.; Tetreault, Grald R.; Servos, Mark R.

    2011-01-01

    Fish community changes associated with a tertiary treated municipal wastewater effluent outfall in the Speed River, Ontario, Canada, were evaluated at nine sites over two seasons (2008) using standardized electrofishing. Habitat evaluations were conducted to ensure that the riffle sites selected were physically similar. The fish community was dominated by several species of darters that differed in their response to the effluent outfall. There was a significant decrease in Greenside Darter (Etheostoma blennioides) but an increase in Rainbow Darter (E. caeruleum) abundance directly downstream of the outfall. Stable isotope signatures (δ 13 C and δ 15 N), which indicate shifts in energy utilization and flow, increased in Rainbow Darter downstream, but showed no change in Greenside Darter. Rainbow Darter may be exploiting a food source that is not as available at upstream sites giving them a competitive advantage over the Greenside Darter immediately downstream of the outfall. - Highlights: → Fish communities are altered by tertiary treated municipal wastewater exposure. → Relative abundance of the two dominant fish (darter) species changed downstream. → Differing stable isotope signatures in fish suggests shifting energy flow and diet. → The altered environment may allow resilient species a competitive advantage. → The system recovers quickly downstream. - Tertiary treated effluent altered fish community composition in a small receiving stream possibly as a result of altered availability of resources (diet) as indicated by stable isotopes.

  2. Life Cycle Assessment of urban wastewater reuse with ozonation as tertiary treatment

    International Nuclear Information System (INIS)

    Munoz, Ivan; Rodriguez, Antonio; Rosal, Roberto; Fernandez-Alba, Amadeo R.

    2009-01-01

    Life Cycle Assessment has been used to compare different scenarios involving wastewater reuse, with special focus on toxicity-related impact categories. The study is based on bench-scale experiments applying ozone and ozone in combination with hydrogen peroxide to a wastewater effluent from a Spanish sewage treatment plant. Two alternative characterisation models have been used to account for toxicity of chemical substances, namely USES-LCA and EDIP97. Four alternative scenarios have been assessed: wastewater discharge plus desalination supply, wastewater reuse without tertiary treatment, wastewater reuse after applying a tertiary treatment consisting on ozonation, and wastewater reuse after applying ozonation in combination with hydrogen peroxide. The results highlight the importance of including wastewater pollutants in LCA of wastewater systems assessing toxicity, since the contribution of wastewater pollutants to the overall toxicity scores in this case study can be above 90%. Key pollutants here are not only heavy metals and other priority pollutants, but also non-regulated pollutants such as pharmaceuticals and personal care products. Wastewater reuse after applying any of the tertiary treatments considered appears as the best choice from an ecotoxicity perspective. As for human toxicity, differences between scenarios are smaller, and taking into account the experimental and modelling uncertainty, the benefits of tertiary treatment are not so clear. From a global warming potential perspective, tertiary treatments involve a potential 85% reduction of greenhouse gas emissions when compared with desalination

  3. Laboratory test of source encapsulation for decreasing PCB concentrations

    DEFF Research Database (Denmark)

    Kolarik, Barbara; Andersen, Helle Vibeke; Markowicz, Pawel

    2016-01-01

    This study investigates the effect of encapsulation of tertiary PCB sources with PERMASORB™ Adsorber Wallpaper and the surface emissions trap (cTrap) on indoor air concentration of PCBs and on the PCB content in the source. The 40 weeks long laboratory investigation shows reduction of the air...... concentration by approx. 90% for both wallpapers, a level comparable to source removal. The potential for extraction of PCBs from the contaminated materials stays unclear for both wallpapers. The cTrap has shown potential to accumulate PCBs, however the total content of PCB in investigated sources has...... apparently increased. The opposite was observed for the PERMASORB™, where the total PCB content in the sources has decreased, with however only small concentration of PCBs in the wallpaper measured at the end of the experiment....

  4. Geology and mineral deposits of Churchill County, Nevada

    Science.gov (United States)

    Willden, Ronald; Speed, Robert C.

    1974-01-01

    Churchill County, in west-central Nevada, is an area of varied topography and geology that has had a rather small total mineral production. The western part of the county is dominated by the broad low valley of the Carson Sink, which is underlain by deposits of Lake Lahontan. The bordering mountain ranges to the west and south are of low relief and underlain largely by Tertiary volcanic and sedimentary units. Pre-Tertiary rocks are extensively exposed east of the Carson Sink in the Stillwater Range, Clan Alpine Mountains, Augusta Mountains, and New Pass Mountains. The eastern valleys are underlain by Quaternary alluvial and lacustrine deposits contemporaneous with the western deposits of Lake Lahontan. The eastern mountain ranges are more rugged than the western ranges and have higher relief; the eastern valleys are generally narrower.

  5. Petroleum systems of the Malay Basin Province, Malaysia

    Science.gov (United States)

    Bishop, Michele G.

    2002-01-01

    The offshore Malay Basin province is a Tertiary oil and gas province composed of a complex of half grabens that were filled by lacustrine shales and continental clastics.These deposits were overlain by clastics of a large delta system that covered the basin.Delta progradation was interupted by transgressions of the South China Sea to the southeast, which finally flooded the basin to form the Gulf of Thailand.Oil and gas from the Oligocene to Miocene lacustrine shales and Miocene deltaic coals is trapped primarily in anticlines formed by inversion of the half grabens during the late Miocene.Hydrocarbon reserves that have been discovered amount to 12 billion barrels of oil equivalent.The U.S. Geological Survey assessment of the estimated quantities of conventional oil, gas and condensate that have the potential to be added to reserves by the year 2025 for this province is 6.3 billion barrels of oil equivalent (BBOE) (U. S. Geological Survey World Energy Assessment Team, 2000).

  6. Survey on the consumptions of energy sources in the tertiary sector in Italy in 1999; Indagine sui consumi di fonti energetiche nel settore terziario in Italia. Anno 1999

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, G. [ENEA, Funzione Centrale Studi, Centro Ricerche Casaccia, Rome (Italy); Perrella, G. [ENEA, Divisione Promozione degli Usi Efficienti e Diversificazione dell' Energia, Centro Ricerche Casaccia, Rome (Italy); Ballin, M. [Istituto Nazionale di Statistica, Dipt. Statistiche Economiche, Rome (Italy)

    2001-07-01

    This report has the aim to introduce the results of the sampling survey performed to determinate the consumption of energy sources (electricity, natural gas, fuel oil, diesel oil, etc.) in the tertiary sector. The energy consumptions report to 1999 and they are disaggregated for typology of use: energy consumptions for productive uses, for production of energy and for traction. The economic energy intensive activities have represented the nucleus of the survey. Particular attention has been devoted to the production of energy and the consumption of heat. [Italian] Il presente rapporto ha l'obiettivo di presentare i risultati dell'indagine campionaria effettuata per determinare il consumo di fonti energetiche (energia elettrica, gas naturale, olio combustibile, gasolio, ecc.) nel settore terziario. I consumi energetici si riferiscono al 1999 e sono disaggregati per tipologia di utilizzo: consumi energetici per usi produttivi, per produzione di energia e per trazione. Le attivita' economiche ad alta intensita' energetica hanno rappresentato il nucleo dell'indagine. Particolare attenzione e' stata dedicata alla produzione di energia e al consumo di calore.

  7. Survey on the consumptions of energy sources in the tertiary sector in Italy in 1999; Indagine sui consumi di fonti energetiche nel settore terziario in Italia. Anno 1999

    Energy Technology Data Exchange (ETDEWEB)

    Iorio, G [ENEA, Funzione Centrale Studi, Centro Ricerche Casaccia, Rome (Italy); Perrella, G [ENEA, Divisione Promozione degli Usi Efficienti e Diversificazione dell' Energia, Centro Ricerche Casaccia, Rome (Italy); Ballin, M [Istituto Nazionale di Statistica, Dipt. Statistiche Economiche, Rome (Italy)

    2001-07-01

    This report has the aim to introduce the results of the sampling survey performed to determinate the consumption of energy sources (electricity, natural gas, fuel oil, diesel oil, etc.) in the tertiary sector. The energy consumptions report to 1999 and they are disaggregated for typology of use: energy consumptions for productive uses, for production of energy and for traction. The economic energy intensive activities have represented the nucleus of the survey. Particular attention has been devoted to the production of energy and the consumption of heat. [Italian] Il presente rapporto ha l'obiettivo di presentare i risultati dell'indagine campionaria effettuata per determinare il consumo di fonti energetiche (energia elettrica, gas naturale, olio combustibile, gasolio, ecc.) nel settore terziario. I consumi energetici si riferiscono al 1999 e sono disaggregati per tipologia di utilizzo: consumi energetici per usi produttivi, per produzione di energia e per trazione. Le attivita' economiche ad alta intensita' energetica hanno rappresentato il nucleo dell'indagine. Particolare attenzione e' stata dedicata alla produzione di energia e al consumo di calore.

  8. Tertiary instability of zonal flows within the Wigner-Moyal formulation of drift turbulence

    Science.gov (United States)

    Zhu, Hongxuan; Ruiz, D. E.; Dodin, I. Y.

    2017-10-01

    The stability of zonal flows (ZFs) is analyzed within the generalized-Hasegawa-Mima model. The necessary and sufficient condition for a ZF instability, which is also known as the tertiary instability, is identified. The qualitative physics behind the tertiary instability is explained using the recently developed Wigner-Moyal formulation and the corresponding wave kinetic equation (WKE) in the geometrical-optics (GO) limit. By analyzing the drifton phase space trajectories, we find that the corrections proposed in Ref. to the WKE are critical for capturing the spatial scales characteristic for the tertiary instability. That said, we also find that this instability itself cannot be adequately described within a GO formulation in principle. Using the Wigner-Moyal equations, which capture diffraction, we analytically derive the tertiary-instability growth rate and compare it with numerical simulations. The research was sponsored by the U.S. Department of Energy.

  9. Understanding Australian Aboriginal Tertiary Student Needs

    Science.gov (United States)

    Oliver, Rhonda; Rochecouste, Judith; Bennell, Debra; Anderson, Roz; Cooper, Inala; Forrest, Simon; Exell, Mike

    2013-01-01

    Drawing from a study of the experiences of Australian Aboriginal and Torres Strait Islander university students, this paper presents an overview of the specific needs of these students as they enter and progress through their tertiary education. Extracts from a set of case studies developed from both staff and student interviews and an online…

  10. Treatment of self-poisoning at a tertiary level hospital in Bangladesh

    DEFF Research Database (Denmark)

    Verma, Vasundhara; Paul, Sujat; Ghose, Aniruddha

    2017-01-01

    OBJECTIVES: Approximately 10,000 people die from suicide annually in Bangladesh, many from pesticide poisoning. We aimed to estimate financial costs to patients and health services of treating patients with self-poisoning. METHODS: Data on direct costs to families, sources of funds for treatment...... and family wealth were collected prospectively over a one-month period in 2016 at the tertiary Chittagong Medical College Hospital, Bangladesh. Aggregate operational costs to the government were calculated using annual budget, bed occupancy and length-of-stay data. RESULTS: Agrochemicals were the most common...... as organophosphorus poisoning in 17(.) 0% of agrochemical cases resulted in increased cost to patients. Only 51(.) 9% of patients had indicators of wealth; 78(.) 1% borrowed money to cover costs. Conservatively estimated median healthcare costs (US$ 21(.) 30 per patient) were markedly lower than costs to patients...

  11. A high-resolution Early Holocene-late MIS 3 environmental rock- and palaeomagnetic record from Lake Sf. Ana, Carpathian Mts, Romania

    Directory of Open Access Journals (Sweden)

    Daniel VERES

    2014-11-01

    Full Text Available Lacustrine sediments are excellent sources of palaeoenvironmental and palaeoclimatic information because they usually provide continuous and high-resolution records. In centraleastern Europe however lacustrine records that extend beyond the Holocene are rather sparse.Palaeomagnetic records from this region are also insufficiently explored, and usually associated with terrestrial deposits such as loess. In this context, the lacustrine record of Lake Sf. Ana, a volcanic crater lake in the East Carpathians, Romania, provides an important archive for reconstructing past paleomagnetic secular variation in the region from early Holocene to late Marine Isotope Stage (MIS 3.

  12. On Progress of Mass Tertiary Education: Case of Lebanon, Kenya and Oman

    Science.gov (United States)

    Liu, Zhimin; Mutinda, Gladys

    2016-01-01

    Mass higher education is a huge force to be reckoned with and its existence, already in the expansion of tertiary institutions is undeniable. This study will focus on three countries: Lebanon, Kenya and Oman. The purpose of this study is to evaluate mass tertiary education progress in these countries. It will synthesize data results of gross…

  13. First report of tertiary syphilis presenting as lipoatrophic panniculitis in an immunocompetent patient.

    Science.gov (United States)

    Drago, Francesco; Ciccarese, Giulia; Tomasini, Carlo F; Calamaro, Paola; Boggio, Maurizio; Rebora, Alfredo; Parodi, Aurora

    2017-03-01

    We describe herein a woman who developed subcutaneous gummas in her trochanteric regions, bilaterally, although she had been treated for syphilis two decades earlier. Evidence of Treponema pallidum latent late infection was the presence of IgG antibodies against T. pallidum and the positive non-treponemal and treponemal tests. Moreover, immunohistochemical staining for T. pallidum detected some spirochetes close to the atrophic adipocytes allowing the diagnosis of lypo-atrophic panniculitis tertiary syphilis. This is the first case of tertiary syphilis presenting as panniculitis in an immunocompetent patient, demonstrating that subcutaneous fat may be another organ infected in tertiary syphilis.

  14. Enhancing learning in tertiary institutions through multimedia based ...

    African Journals Online (AJOL)

    Enhancing learning in tertiary institutions through multimedia based ... convenient and cost-effective courseware reengineering methodology of our age. ... Also discussed are the reasons for converting classroom courses to e-learning format.

  15. Giving perspective to cliff exposures with ground penetrating radar: Devonian lacustrine shore zone architecture

    Science.gov (United States)

    Andrews, Steven; Moreau, Julien; Archer, Stuart

    2015-04-01

    The orbitally-controlled cyclic lacustrine successions of the Middle Devonian in Northern Scotland contains repeated developments of shore zone sandstones. However, due to the cliff-forming nature of the succession and the attitude of the sections through these sandstones, interpretation of this facies has been problematic. To better understand the shore zone systems, we carried out very high resolution sedimentary logging and constructed photo-panels which were combined with high resolution GPR profiling (250 MHz). To ensure close ties between the sedimentary logs and the GPR data, the cliffs were accessed using rope access techniques while GPR grids were shot directly above. The profiles were shot mainly in the strike direction of what was thought to be the shore elongation every 5-10 m and every 20-30 m in the dip direction. Shore zone systems of 3 different sequences have been imaged for a total of 1155 m of GPR profile collected. This configuration has allowed 3D visualisation of the architecture of the shore zone systems and, in combination with detailed sedimentology, provided insights into the generation of the dynamic shore zone environments. The coastal cliffs of northern Scotland expose sedimentary cycles on average 16-m-thick which record deep lake, perennial lake and playa environments. The shore zone deposits reach 2 to 3.5 m in thickness. Loading and discrete channel forms are recognised in both the GPR data and sedimentary logs through the lower portion of the lake shore zone successions. Up-section the sandstone beds appear to become amalgamated forming subtle low angle accretionary bar complexes which although visible in outcrop, after careful investigation, can be fully visualised and examined in the GPR data. The 3D visualisation allowed mapping the architecture and distribution of the bars . The orientation of these features, recognised from the survey, is consistent with extensive palaeocurrent measurements from oscillation ripples. Further

  16. Past Holocene detritism quantification and modeling from lacustrine archives in order to deconvoluate human-climate interactions on natural ecosystem over long time-scale

    Science.gov (United States)

    Simonneau, Anaëlle; Chapron, Emmanuel; Di Giovanni, Christian; Galop, Didier; Darboux, Frédéric

    2014-05-01

    Water budget is one of the main challenges to paleoclimate researchers in relation to present-day global warming and its consequences for human societies. Associated soil degradation and erosion are thereby becoming a major concern in many parts of the world and more particularly in the Alps. Moreover, humans are considered as geomorphologic agents since few thousand years and it is now recognized that such an impact on natural ecosystem profoundly modified soils properties as well as aquatic ecosystems dynamics over long-term periods. The quantification of such inference over long time-scale is therefore essential to establish new policies to reduce mechanic soil erosion, which is one of the dominant processes in Europe, and anticipate the potential consequences of future climate change on hydric erosion. The mechanical erosion of continental surfaces results from climatic forcing, but can be amplified by the anthropogenic one. We therefore suggest that quantifying and modelling soil erosion processes within comparable Holocene lacustrine archives, allows to estimate and date which and when past human activities have had an impact on soil fluxes over the last 10000 years. Based on the present-day geomorphology of the surrounding watershed and the evolution of the vegetation cover during the Holocene, we develop an interdisciplinary approach combining quantitative organic petrography (i.e. optical characterization and quantification of soil particles within lake sediments) with high-resolution seismic profiling, age-depth models on lacustrine sediment cores and soil erosional susceptibility modeling, in order to estimate the annual volume of soil eroded over the last 10000 years, and in fine to quantify the volume of human-induced soil erosion during the Holocene period. This method is applied to close but contrasted mountainous lacustrine environments from the western French Alps: lakes Blanc Huez and Paladru, sensitive to same climatic influences but where past

  17. Challenges Faced by Key Stakeholders Using Educational Online Technologies in Blended Tertiary Environments

    Science.gov (United States)

    Tuapawa, Kimberley

    2016-01-01

    Traditional learning spaces have evolved into dynamic blended tertiary environments (BTEs), providing a modern means through which tertiary education institutes (TEIs) can augment delivery to meet stakeholder needs. Despite the significant demand for web-enabled learning, there are obstacles concerning the use of EOTs, which challenge the…

  18. Submarine fans and associated deposits in the Lower Tertiary of Guipuzcoa (Northern Spain)

    NARCIS (Netherlands)

    Vliet, van A.

    1982-01-01

    The Lower Tertiary outcrop along the coast of Guipuzcoa, northern Spain, consists exclusively of deep-marine sediments, deposited in a narrow elongated (ESE-WNW) basin. The early Tertiary sedimentary history of this basin can be described in terms of three main phases:

    - a phase of

  19. Molecular data and ecological niche modelling reveal a highly dynamic evolutionary history of the East Asian Tertiary relict Cercidiphyllum (Cercidiphyllaceae).

    Science.gov (United States)

    Qi, Xin-Shuai; Chen, Chen; Comes, Hans Peter; Sakaguchi, Shota; Liu, Yi-Hui; Tanaka, Nobuyuki; Sakio, Hitoshi; Qiu, Ying-Xiong

    2012-10-01

    East Asia's temperate deciduous forests served as sanctuary for Tertiary relict trees, but their ages and response to past climate change remain largely unknown. To address this issue, we elucidated the evolutionary and population demographic history of Cercdiphyllum, comprising species in China/Japan (Cercdiphyllum japonicum) and central Japan (Cercdiphyllum magnificum). Fifty-three populations were genotyped using chloroplast and ribosomal DNA sequences and microsatellite loci to assess molecular structure and diversity in relation to past (Last Glacial Maximum) and present distributions based on ecological niche modelling. Late Tertiary climate cooling was reflected in a relatively recent speciation event, dated at the Mio-/Pliocene boundary. During glacials, the warm-temperate C. japonicum experienced massive habitat losses in some areas (north-central China/north Japan) but increases in others (southwest/-east China, East China Sea landbridge, south Japan). In China, the Sichuan Basin and/or the middle-Yangtze were source areas of postglacial northward recolonization; in Japan, this may have been facilitated through introgressive hybridization with the cool-temperate C. magnificum. Our findings challenge the notion of relative evolutionary and demographic stability of Tertiary relict trees, and may serve as a guideline for assessing the impact of Neogene climate change on the evolution and distribution of East Asian temperate plants. © 2012 The Authors. New Phytologist © 2012 New Phytologist Trust.

  20. Indigenous Students in the Tertiary Education Sector

    Science.gov (United States)

    Bandias, Susan; Fuller, Don; Larkin, Steven

    2014-01-01

    Important recent objectives of indigenous education policy in Australia have been aimed at redressing indigenous economic and social disadvantage through increasing student retention, progression and completion rates in both compulsory and post-compulsory education. The two sectors of the tertiary education system, vocational education and…

  1. Integrated Identity and Access Management System for Tertiary ...

    African Journals Online (AJOL)

    Nigerian Journal of Technology ... identity management and access control and the unavailability of actionable information on pattern of ... This Tertiary Identity and Access Management System (T-IAMS) is a fingerprint biometric database that ...

  2. Sexism and Sexual Harassment in Tertiary Institutions | Akpotor ...

    African Journals Online (AJOL)

    Gender and Behaviour ... Sexual harassment is a recurring decimal in tertiary institutions. The paper therefore investigates the effects of sexual harassment on the academic performance of female students, using Delta State University, Abraka, ...

  3. Tertiary particle physics with ELI: from challenge to chance (Conference Presentation)

    Science.gov (United States)

    Drska, Ladislav

    2017-05-01

    nteraction of high-intensity laser pulses with solid state targets results in generation of intense pulses of secondary particles via electromagnetic interaction : electrons, ions, hard x-rays. The beams of these particles can be used to produce various types of third-generation particles, beyond electromagnetic also other types of fundamental interactions can be involved in this process [1]. As the most interesting tertiary particles could be mentioned positrons, neutron, muons. This paper shall extend our previous analysis of this topic [2]: it discusses selected technical problems of design and realization of applicable sources of these particles and presents some more elaborated proposals for potential meaningful / hopefuly realistic exploitations of this technology. (1)Tertiary Sources (TS) : First Development Steps. This part of the presentation includes the topics as follows: (11) Pulsed positron sources: Verified solutions of laser-driven positron sources [3] [4] [5], development towards applicable facilities. Some unconventional concepts of application of lasers for positron production [6]. Techniques for realization of low/very-low energy positrons. (12) Taylored neutron sources [7]: Neutron sources with demanded space distribution, strongly beamed and isotropic solutions [8] [9]. Neutron generation with taylored energy distribution. Problem of the direct production of neutrons with very low energy [10] [11]. (13) Potential muon sources: Proof-of-principle laser experiment on electron / photon driven muon production [12] [13]. Study of the possibility of effective generation of surface muons. Problems of the production of muons with very low energy. (2) Fundamental & Applied Physics with TS: This part of the talk presents the themes: (21) Diagnostic potential of TS: Lepton emission as a signature of processes in extreme systems. Passive and active diagnostics using positrons, problems of detection and evaluation. Potential diagnostic applications of muons

  4. Formation mechanism of NDMA from ranitidine, trimethylamine, and other tertiary amines during chloramination: a computational study.

    Science.gov (United States)

    Liu, Yong Dong; Selbes, Meric; Zeng, Chengchu; Zhong, Rugang; Karanfil, Tanju

    2014-01-01

    Chloramination of drinking waters has been associated with N-nitrosodimethylamine (NDMA) formation as a disinfection byproduct. NDMA is classified as a probable carcinogen and thus its formation during chloramination has recently become the focus of considerable research interest. In this study, the formation mechanisms of NDMA from ranitidine and trimethylamine (TMA), as models of tertiary amines, during chloramination were investigated by using density functional theory (DFT). A new four-step formation pathway of NDMA was proposed involving nucleophilic substitution by chloramine, oxidation, and dehydration followed by nitrosation. The results suggested that nitrosation reaction is the rate-limiting step and determines the NDMA yield for tertiary amines. When 45 other tertiary amines were examined, the proposed mechanism was found to be more applicable to aromatic tertiary amines, and there may be still some additional factors or pathways that need to be considered for aliphatic tertiary amines. The heterolytic ONN(Me)2-R(+) bond dissociation energy to release NDMA and carbocation R(+) was found to be a criterion for evaluating the reactivity of aromatic tertiary amines. A structure-activity study indicates that tertiary amines with benzyl, aromatic heterocyclic ring, and diene-substituted methenyl adjacent to the DMA moiety are potentially significant NDMA precursors. The findings of this study are helpful for understanding NDMA formation mechanism and predicting NDMA yield of a precursor.

  5. Medical tourism in India: perceptions of physicians in tertiary care hospitals.

    Science.gov (United States)

    Qadeer, Imrana; Reddy, Sunita

    2013-12-17

    Senior physicians of modern medicine in India play a key role in shaping policies and public opinion and institutional management. This paper explores their perceptions of medical tourism (MT) within India which is a complex process involving international demands and policy shifts from service to commercialisation of health care for trade, gross domestic profit, and foreign exchange. Through interviews of 91 physicians in tertiary care hospitals in three cities of India, this paper explores four areas of concern: their understanding of MT, their views of the hospitals they work in, perceptions of the value and place of MT in their hospital and their views on the implications of MT for medical care in the country. An overwhelming majority (90%) of physicians in the private tertiary sector and 74.3 percent in the public tertiary sector see huge scope for MT in the private tertiary sector in India. The private tertiary sector physicians were concerned about their patients alone and felt that health of the poor was the responsibility of the state. The public tertiary sector physicians' however, were sensitive to the problems of the common man and felt responsible. Even though the glamour of hi-tech associated with MT dazzled them, only 35.8 percent wanted MT in their hospitals and a total of 56 percent of them said MT cannot be a public sector priority. 10 percent in the private sector expressed reservations towards MT while the rest demanded state subsidies for MT. The disconnect between their concern for the common man and professionals views on MT was due to the lack of appreciation of the continuum between commercialisation, the denial of resources to public hospitals and shift of subsidies to the private sector. The paper highlights the differences and similarities in the perceptions and context of the two sets of physicians, presents evidence, that questions the support for MT and finally analyzes some key implications of MT on Indian health services, ethical

  6. Medical tourism in india: perceptions of physicians in tertiary care hospitals

    Science.gov (United States)

    2013-01-01

    Senior physicians of modern medicine in India play a key role in shaping policies and public opinion and institutional management. This paper explores their perceptions of medical tourism (MT) within India which is a complex process involving international demands and policy shifts from service to commercialisation of health care for trade, gross domestic profit, and foreign exchange. Through interviews of 91 physicians in tertiary care hospitals in three cities of India, this paper explores four areas of concern: their understanding of MT, their views of the hospitals they work in, perceptions of the value and place of MT in their hospital and their views on the implications of MT for medical care in the country. An overwhelming majority (90%) of physicians in the private tertiary sector and 74.3 percent in the public tertiary sector see huge scope for MT in the private tertiary sector in India. The private tertiary sector physicians were concerned about their patients alone and felt that health of the poor was the responsibility of the state. The public tertiary sector physicians’ however, were sensitive to the problems of the common man and felt responsible. Even though the glamour of hi-tech associated with MT dazzled them, only 35.8 percent wanted MT in their hospitals and a total of 56 percent of them said MT cannot be a public sector priority. 10 percent in the private sector expressed reservations towards MT while the rest demanded state subsidies for MT. The disconnect between their concern for the common man and professionals views on MT was due to the lack of appreciation of the continuum between commercialisation, the denial of resources to public hospitals and shift of subsidies to the private sector. The paper highlights the differences and similarities in the perceptions and context of the two sets of physicians, presents evidence, that questions the support for MT and finally analyzes some key implications of MT on Indian health services, ethical

  7. Misconception of emergency contraception among tertiary school ...

    African Journals Online (AJOL)

    Objective: To assess the degree of awareness and use of emergency contraception among tertiary school students in Akwa Ibom State, Nigeria. Design: A self-administered questionnaire survey. Setting: The Akwa Ibom State Polytechnic, Ikot Osurua, located on the outskirts of Ikot Ekpene local government area between ...

  8. "Community of Practice" as a Framework for Supporting Tertiary Teachers' Informal Workplace Learning

    Science.gov (United States)

    Viskovic, Alison R.

    2005-01-01

    This article discusses aspects of the informal learning of tertiary teachers in a polytechnic, a wananga (Maori tertiary institution) and a university in New Zealand. Case studies showed that they gained their teaching knowledge and skills mainly on the job, through informal, experiential learning, and much less through formal courses,…

  9. Study of tertiary creep instability in several elevated-temperature structural materials

    International Nuclear Information System (INIS)

    Booker, M.K.; Sikka, V.K.

    1978-01-01

    Data for a number of common elevated temperature structural materials have been analyzed to yield mathematical predictions for the time and strain to tertiary creep at various rupture lives and temperatures. Materials examined include types 304 and 316 stainless steel, 2 1/4 Cr-1 Mo steel, alloy 800H, alloy 718, Hastelloy alloy X, and ERNiCr--3 weld metal. Data were typically examined over a range of creep temperatures for rupture lives ranging from less than 100 to greater than 10,000 hours. Within a given material, trends in these quantities can be consistently described, but it is difficult to directly relate the onset of tertiary creep to failure-inducing instabilities. A series of discontinued tests for alloy 718 at 649 and 620 0 C showed that the material fails by intergranular cracking but that no significant intergranular cracking occurs until well after the onset of tertiary creep

  10. System for radiation emergency medicine. Activities of tertiary radiation emergency hospitals

    International Nuclear Information System (INIS)

    Kamiya, Kenji; Tanigawa, Koichi; Hosoi, Yoshio

    2011-01-01

    Japanese system for radiation emergency medicine is primarily built up by Cabinet Nuclear Safety Commission in 2001 based on previous Tokai JCO Accident (1999) and is composed from the primary, secondary and tertiary medical organizations. This paper describes mainly about roles and actions of the tertiary facilities at Fukushima Nuclear Power Plant Accident and tasks to be improved in future. The primary and secondary organizations in the system above are set up in the prefectures with or neighboring the nuclear facility, and tertiary ones, in two parts of western and eastern Japan. The western organization is in Hiroshima University having its cooperating 7 hospitals, and is responsible for such patients as exposed to high dose external radiation, having serious complication, and difficult to treat in the primary/secondary hospitals. The eastern is in National Institute of Radiological Sciences (NIRS) with 6 cooperating hospitals and responsible for patients with internal radiation exposure difficult to treat, with contaminated body surface with difficulty in decontamination and/or with causable of secondary contamination, and difficult to treat in the secondary hospitals. The tertiary organizations have made efforts for the education and training of medical staff, for network construction among the primary, secondary and other medicare facilities, for establishment of transferring system of patients, and for participation to the international network by global organizations like Response Assistance Network (RANET) in International Atomic Energy Agency (IAEA), and Radiation Emergency Preparedness and Network (REMPAN) in World Health Organization (WHO). At the Fukushima Accident, staffs of the two tertiary hospitals began to conduct medicare on site (Mar. 12-) and learned following tasks to be improved in future: the early definition of medicare and its network system, and Emergency Planning Zone (EPZ); urgent evacuation of residents weak to disaster like elderly

  11. Evaluation of a tertiary teledermatology service between peripheral and academic dermatologists in the Netherlands

    NARCIS (Netherlands)

    van der Heijden, Job P.; de Keizer, Nicolette F.; Witkamp, Leonard; Spuls, Phyllis I.

    2014-01-01

    Tertiary teledermatology (TTD)-secondary-care to tertiary-care teleconsultation-is applied rarely compared with the frequently applied secondary teledermatology (primary to secondary care). The objective of this study was to determine the effect of TTD on referrals from peripheral dermatologists to

  12. e-Learning for expanding distance education in tertiary level in Bangladesh: Problems and progress

    Directory of Open Access Journals (Sweden)

    Md. Abdullah Al-Masum

    2013-11-01

    Full Text Available E-learning has broadly become an important enabler to promote distance education (DE and lifelong learning in most of the developed countries, but in Bangladesh it is still a new successful progressive system for the learning communities. Distance education is thought to be introduced as an effective way of educating people of all sections in Bangladesh. Bangladesh Open University (BOU, the only distance education provider in Bangladesh, has been trying to adopt the use of various e-learning materials for its distance delivery. This paper has tried to describe the current progress of quality e-learning for expanding distance education, identifying the major problems of e-learning in distance education at tertiary level in Bangladesh, with special reference to BOU, and finally to put forward some valuable recommendations for solving the problems. The study is based on both primary and secondary sources. It is observed from the research that e-learning is going to ensure its bright prospect as an alternative mode of education at the tertiary level in Bangladesh. There are several problems that are identified and can be mitigated and solved through Information and Communication Technology (ICT development, greater acceptance by learners, and much research in this sector in Bangladesh to face globalization.   DOI: 10.18870/hlrc.v3i4.171

  13. Distinguishing between tertiary and secondary facilities: a case study of cardiac diagnostic-related groups (DRGs).

    Science.gov (United States)

    Rouse, Paul; Arulambalam, Ajit; Correa, Ralph; Ullman, Cornelia

    2010-05-14

    To develop a classification of tertiary cardiac DRGs in order to investigate differences in tertiary/secondary product mix across New Zealand district health boards (DHBs). 67 DRGs from 85,442 cardiac cases were analysed using cost weights and patient comorbidity complexity levels, which were used as a proxy for complexity. The research found high variability of severity within some DRGs. 5 DHBs are the main providers of 27 DRGs which are high cost and identified as tertiary by several ADHB clinicians; the same 5 DHBs have on average higher severity by DRG than the other DHBs. NZ tertiary hospitals have a product mix of DRGs with higher complexity than secondary hospitals. Funding based on case weights needs to recognise the additional resource requirements for this higher complexity.

  14. Oxidation of tertiary homoallylic alcohols by thallium trinitrate: fragmentation versus ring contraction

    International Nuclear Information System (INIS)

    Silva Junior, Luiz F.; Quintiliano, Samir A.P.; Ferraz, Helena M.C.; Santos, Leonardo S.; Eberlin, Marcos N.

    2006-01-01

    The oxidation of tertiary homoallylic alcohols with thallium trinitrate (TTN) was investigated. The alcohols bearing an allylic methyl group lose a molecule of acetone via a fragmentation reaction that leads to isomeric secondary allylic alcohols as major products, together with their corresponding acetylated derivatives. On the other hand, treating analogous tertiary alcohols without the allylic methyl group with TTN gives indans, through a ring contraction reaction. (author)

  15. Positive effects of tertiary centres for amyotrophic lateral sclerosis on outcome and use of hospital facilities.

    Science.gov (United States)

    Chiò, A; Bottacchi, E; Buffa, C; Mutani, R; Mora, G

    2006-08-01

    To evaluate the effects of tertiary centres for amyotrophic lateral sclerosis (ALS) on ALS outcome and the use of hospital facilities. The study was based on the data of an epidemiological, prospective, population-based register on ALS (Piemonte and Valle d'Aosta Register for amyotrophic lateral sclerosis, PARALS). The 221 patients recruited between 1995 and 1996 were prospectively followed up for outcome and use of hospital-based services. In all, 97 patients were followed up by tertiary ALS centres and 124 by general neurological clinics. Patients followed up by tertiary ALS centres were found to be 4 years younger and underwent percutaneous endoscopic gastronomy and non-invasive positive-pressure ventilation more often. Patients followed up by tertiary ALS centres were found to have a considerably longer median survival time (1080 v 775 days), even when stratifying by age, site of onset and respiratory function at diagnosis. In Cox multivariate analysis, attending a tertiary ALS centre was observed to be an independent positive prognostic factor. Moreover, patients attending a tertiary ALS centre were admitted to hospital less often (1.2 v 3.3) and were more frequently admitted for planned interventions. Conversely, patients followed up by general neurological clinics were more frequently admitted for acute events. Also, the hospital stay was considerably shorter for patients attending tertiary ALS centres (5.8 v 12.4 days). Improved survival was seen in patients with ALS attending tertiary ALS centres, independently from all other known prognostic factors, possibly through a better implementation of supportive treatments. Moreover, because of these centres, the hospitalisation rate was markedly reduced, thus offering a cost-effective service to patients with ALS and to the community as a whole.

  16. Modelling the harmonized tertiary Institutions Salary Structure ...

    African Journals Online (AJOL)

    This paper analyses the Harmonized Tertiary Institution Salary Structure (HATISS IV) used in Nigeria. The irregularities in the structure are highlighted. A model that assumes a polynomial trend for the zero step salary, and exponential trend for the incremental rates, is suggested for the regularization of the structure.

  17. Ten years of energy consumption in the tertiary sector

    International Nuclear Information System (INIS)

    Rabai, Yacine

    2012-11-01

    This document presents and comments data regarding electricity consumption by the tertiary sector over the last ten years in France. It notably outlines its strong increase compared to the other sectors (housing, industry, transport, agriculture). It comments the evolution of the energy mix of the tertiary sector (electricity with 47%, gas with 25% and oil with 19% are prevailing). It briefly comments the evolution of energy efficiency within this sector. It indicates and comments the shares of energy consumption, of high voltage electricity and gas consumption by the different sub-sectors (retail, automobile and motorcycle repair, public administration, health and social activity, real estate, specialised, scientific and technical activities, education, and so on)

  18. Hydroecology of Amazonian lacustrine Arcellinida (testate amoebae): A case study from Lake Quistococha, Peru.

    Science.gov (United States)

    Patterson, R Timothy; Huckerby, Gail; Kelly, Thomas J; Swindles, Graeme T; Nasser, Nawaf A

    2015-10-01

    Organic rich sediments were obtained from seven core tops taken in Lake Quistococha, near the city of Iquitos in the Peruvian Amazon. Subsamples from 0 to 4cm depth in each core were analyzed under dissecting light microscopy to carry out the first investigation of Arcellinida (testate lobose amoebae) from a lacustrine environment in this ecologically important region. The fauna was characterized by a low diversity, low abundance community dominated by centropyxids. This fauna is similar to 'stressed' assemblages reported from temperate latitudes, except that test concentrations were two orders of magnitude lower than typical in temperate lakes. Principle arcellinidan stressors in Lake Quistococha likely include the low pH 4 conditions in the lake, and a general lack of suitable minerogenic material to construct tests in the organic rich lake substrate. The low pH conditions are the result of runoff and seepage of water high in dissolved organic carbon from the adjacent similarly low pH 4 terrestrial peatland. The dearth of minerogenic material is the result of the lake being isolated from riverine input for the past ∼2000 years, even during flooding events. Other limiting factors contributing to depressed arcellinidan populations may include nutrient supply, predation pressure, competition, and post-mortem taphonomic factors. Copyright © 2015 Elsevier GmbH. All rights reserved.

  19. managing tertiary institutions for the promotion of lifelong learning

    African Journals Online (AJOL)

    Global Journal

    KEYWORDS: Managing, tertiary institutions, promotion, lifelong learning. INTRODUCTION ... science, medicine and technology towards the ... different environments, whether formal, informal ... schools considering that each day gives birth to.

  20. Tertiary paediatric emergency department use in children and young people with cerebral palsy.

    Science.gov (United States)

    Meehan, Elaine; Reid, Susan M; Williams, Katrina; Freed, Gary L; Babl, Franz E; Sewell, Jillian R; Rawicki, Barry; Reddihough, Dinah S

    2015-10-01

    The aim of this study was to describe the pattern of tertiary paediatric emergency department (ED) use in children and young people with cerebral palsy (CP). A retrospective analysis of ED data routinely collected at the two tertiary paediatric hospitals in Victoria, Australia, cross-matched with the Victorian Cerebral Palsy Register. Data pertaining to the ED presentations of 2183 registered individuals born 1993-2008 were obtained. Between 2008 and 2012, 37% (n = 814) of the CP cohort had 3631 tertiary paediatric ED presentations. Overall, 40% (n = 332) of presenters were residing in inner metropolitan Melbourne; 44% (n = 356) in outer Melbourne; and 13% (n = 108) in regional Victoria. Presenters were more likely than non-presenters to be younger, non-ambulant and have epilepsy. In total, 71% of presentations were triaged as Australasian Triage Scale 1-3 (urgent), and 44% resulted in a hospital admission. Disorders of the respiratory, neurological and gastrointestinal systems, and medical device problems were responsible for 72% of presentations. Many of the tertiary paediatric ED presentations in this group were appropriate based on the high admission rate and the large proportion triaged as urgent. However, there is evidence that some families are bypassing local services and travelling long distances to attend the tertiary paediatric ED, even for less urgent complaints that do not require hospital admission. Alternative pathways of care delivery, and strategies to promote the management of common problems experienced by children and young people with CP in non-paediatric EDs or primary care settings, may go some way towards reducing unnecessary tertiary paediatric ED use in this group. © 2015 The Authors. Journal of Paediatrics and Child Health © 2015 Paediatrics and Child Health Division (Royal Australasian College of Physicians).

  1. Some antarctic lacustrine sediments from northern Victoria Land investigation by Moessbauer spectroscopy, INNA and XRD

    International Nuclear Information System (INIS)

    Stievano, L.; Bertelle, M.; Leotta, G.; Calogero, S.; Constantinescu, S.; Oddone, M.

    1999-01-01

    Fifteen lacustrine sediments, sampled during the 1994-1995 Austral summer in Northern Victoria Land (Antarctica), were characterised by 57 Fe Moessbauer spectroscopy, instrumental neutron activation analysis and X-ray diffraction. These sediments are related to the intrusive rocks from Granite Harbour, to the metamorphic rocks of the Complex of Wilson Terrane and the volcanic rocks from Mc Murdo. The samples contain quartz, alkaline feldspars, plagioclases, amphiboles, biotite, chlorite and muscovite except for the sediments of volcanic origin that contain alkaline feldspars, plagioclases and pyroxenes. The paramagnetic components of the Moessbauer spectra were assigned mainly to the iron sides in biotites except for those displayed from the sediments of volcanic origin assigned mainly to pyroxenes. Moessbauer spectra at room temperature do not display magnetic ordering except for those of the sediments of volcanic origin containing bulk magnetite, hematite and goethite. Moessbauer spectra collected at the liquid helium temperature always exhibit magnetic ordering. This spectral difference has been attributed to the different dimensions of the iron oxide particles in the sediments. The scarce weathering involves a partial transformation of magnetite in hematite and goethite in the sediment of volcanic origin. In the remaining sediments a partial hydrolysis of biotite together with a partial oxidation of iron (II) retained in silicates is present. (authors)

  2. Usability of cerebrospinal fluid biomarkers in a tertiary memory clinic

    DEFF Research Database (Denmark)

    Brandt, C.; Bahl, J.C.; Heegaard, N.H.

    2008-01-01

    AIM: Assays for cerebrospinal fluid (CSF) levels of total tau, phospho-tau protein and beta-amyloid 1-42 have been available for some years. The aim of the study was to assess the usability of these biomarkers in a mixed population of tertiary dementia referral patients in a university-based memory......, the sensitivity of a single abnormal value was between 33 and 66%. The specificity was high except when discriminating AD from amnestic mild cognitive impairment. Two or more abnormal markers further increased the specificity and decreased the sensitivity. CONCLUSION: In a tertiary setting, abnormal CSF biomarker...

  3. Discovery of tertiary sulfonamides as potent liver X receptor antagonists.

    Science.gov (United States)

    Zuercher, William J; Buckholz, Richard G; Campobasso, Nino; Collins, Jon L; Galardi, Cristin M; Gampe, Robert T; Hyatt, Stephen M; Merrihew, Susan L; Moore, John T; Oplinger, Jeffrey A; Reid, Paul R; Spearing, Paul K; Stanley, Thomas B; Stewart, Eugene L; Willson, Timothy M

    2010-04-22

    Tertiary sulfonamides were identified in a HTS as dual liver X receptor (LXR, NR1H2, and NR1H3) ligands, and the binding affinity of the series was increased through iterative analogue synthesis. A ligand-bound cocrystal structure was determined which elucidated key interactions for high binding affinity. Further characterization of the tertiary sulfonamide series led to the identification of high affinity LXR antagonists. GSK2033 (17) is the first potent cell-active LXR antagonist described to date. 17 may be a useful chemical probe to explore the cell biology of this orphan nuclear receptor.

  4. Evolution and perspectives of the regional market of applicants for tertiary education in South Bohemian Region

    Directory of Open Access Journals (Sweden)

    Ladislav Skořepa

    2012-01-01

    Full Text Available The paper summarizes results of the questionnaire surveys among high schools’ students in the Southbohemian Region. These surveys were done in 2008, 2009 and 2011. The aim of this article was to discover attitudes of the students of two terminal years of high schools as well as the students of higher professional schools to the new situation of the services offered by the sphere of tertiary educations. The supply of schools (measured by available capacity to take on students have recently exceeded over the demand of applicants for tertiary education. This is caused by an increase of the education capacity of universities on one hand and by the birth rate deflation affecting the number of graduates from high schools on the other hand. The number of latest graduates from high school is not adequate to the education capacity of universities where the income based on the education activity represents an important part of their revenues. Universities and their faculties in South Bohemia have abolished the traditional entrance exams and some of them accept even one hundred per cents of applicants. This situation resulted in the development of promotional campaign using all traditional promotional tools. Questionnaire surveys have focused on factors of the selection of a university and faculty to apply, the results of studying at the university, sources of information on existing universities and applicants’ expectations from their university studies. The three-year survey allows authors to generalize implications and conclusions for university managers when recruiting graduates. Applicants permanently prefer economic field of study; the main source for them when choosing is Internet and they expect particularly to find better employment and to reach higher remuneration.

  5. Tertiary work-up of apparent treatment-resistant hypertension.

    Science.gov (United States)

    Heimark, Sondre; Eskås, Per Anders; Mariampillai, Julian Eek; Larstorp, Anne Cecilie K; Høieggen, Aud; Fadl Elmula, Fadl Elmula M

    2016-10-01

    Treatment-resistant hypertension (TRH) has regained attention with development of new methods for treatment. However, the prevalence of TRH varies considerably from primary to secondary and tertiary care. We aimed to assess the prevalence of true TRH in a population of patients with apparent TRH in a university hospital setting of tertiary work-up and also investigate reasons for poor BP control and evaluate how work-up can be performed in general practice and secondary care. In this cohort study, we characterize a study population from Oslo Renal Denervation (RDN) Study. Patients (n = 83) were referred for RDN from secondary care. All patients underwent thorough medical investigation and 24-h ambulatory blood pressure measurements (24ABPM) after directly observed therapy (DOT). We then assessed reasons for lack of BP control. Fifty-three of 83 patients did not have true TRH. Main reasons for non-TRH were poor drug adherence (32%), secondary hypertension (30%) and white coat hypertension (15%). Forty-seven percent achieved blood pressure control after DOT with subsequent 24ABPM. There were otherwise no statistically significant differences in patient characteristics between the true TRH and the non-TRH group. Despite being a highly selected cohort referred for tertiary work-up of apparent TRH, BP control was achieved or secondary causes were identified in almost two thirds of the patients. Thorough investigation according to guidelines and DOT with subsequent 24ABPM is needed in work-up of apparent TRH.

  6. Examination of factors predicting secondary students' interest in tertiary STEM education

    Science.gov (United States)

    Chachashvili-Bolotin, Svetlana; Milner-Bolotin, Marina; Lissitsa, Sabina

    2016-02-01

    Based on the Social Cognitive Career Theory (SCCT), the study aims to investigate factors that predict students' interest in pursuing science, technology, engineering, and mathematics (STEM) fields in tertiary education both in general and in relation to their gender and socio-economic background. The results of the analysis of survey responses of 2458 secondary public school students in the fifth-largest Israeli city indicate that STEM learning experience positively associates with students' interest in pursuing STEM fields in tertiary education as opposed to non-STEM fields. Moreover, studying advanced science courses at the secondary school level decreases (but does not eliminate) the gender gap and eliminates the effect of family background on students' interest in pursuing STEM fields in the future. Findings regarding outcome expectations and self-efficacy beliefs only partially support the SCCT model. Outcome expectations and self-efficacy beliefs positively correlate with students' entering tertiary education but did not differentiate between their interests in the fields of study.

  7. Framework of Assessment for the Evaluation of Thinking Skills of Tertiary Level Students

    Science.gov (United States)

    Heng, Chan Swee; Ziguang, Yan

    2015-01-01

    In the 21st century, students are required to master thinking skills in order to deal with many situations that arise in the tertiary environment which later would translate into the workplace. Nowadays, thinking skills play a vital role in tertiary education. To provide an approach for teachers, this paper identifies a 4-step model that can be…

  8. Stratigraphic architecture of a fluvial-lacustrine basin-fill succession at Desolation Canyon, Uinta Basin, Utah: Reference to Walthers’ Law and implications for the petroleum industry

    Science.gov (United States)

    Ford, Grace L.; David R. Pyles,; Dechesne, Marieke

    2016-01-01

    A continuous window into the fluvial-lacustrine basin-fill succession of the Uinta Basin is exposed along a 48-mile (77-kilometer) transect up the modern Green River from Three Fords to Sand Wash in Desolation Canyon, Utah. In ascending order the stratigraphic units are: 1) Flagstaff Limestone, 2) lower Wasatch member of the Wasatch Formation, 3) middle Wasatch member of the Wasatch Formation, 4) upper Wasatch member of the Wasatch Formation, 5) Uteland Butte member of the lower Green River Formation, 6) lower Green River Formation, 7) Renegade Tongue of the lower Green River Formation, 8) middle Green River Formation, and 9) the Mahogany oil shale zone marking the boundary between the middle and upper Green River Formations. This article uses regional field mapping, geologic maps, photographs, and descriptions of the stratigraphic unit including: 1) bounding surfaces, 2) key upward stratigraphic characteristics within the unit, and 3) longitudinal changes along the river transect. This information is used to create a north-south cross section through the basin-fill succession and a detailed geologic map of Desolation Canyon. The cross section documents stratigraphic relationships previously unreported and contrasts with earlier interpretations in two ways: 1) abrupt upward shifts in the stratigraphy documented herein, contrast with the gradual interfingering relationships proposed by Ryder et al., (1976) and Fouch et al., (1994), 2) we document fluvial deposits of the lower and middle Wasatch to be distinct and more widespread than previously recognized. In addition, we document that the Uteland Butte member of the lower Green River Formation was deposited in a lacustrine environment in Desolation Canyon.

  9. Use of Treated Municipal Wastewater as Power Plant Cooling System Makeup Water: Tertiary Treatment versus Expanded Chemical Regimen for Recirculating Water Quality Management

    Energy Technology Data Exchange (ETDEWEB)

    David Dzombak; Radisav Vidic; Amy Landis

    2012-06-30

    Treated municipal wastewater is a common, widely available alternative source of cooling water for thermoelectric power plants across the U.S. However, the biodegradable organic matter, ammonia-nitrogen, carbonate and phosphates in the treated wastewater pose challenges with respect to enhanced biofouling, corrosion, and scaling, respectively. The overall objective of this study was to evaluate the benefits and life cycle costs of implementing tertiary treatment of secondary treated municipal wastewater prior to use in recirculating cooling systems. The study comprised bench- and pilot-scale experimental studies with three different tertiary treated municipal wastewaters, and life cycle costing and environmental analyses of various tertiary treatment schemes. Sustainability factors and metrics for reuse of treated wastewater in power plant cooling systems were also evaluated. The three tertiary treated wastewaters studied were: secondary treated municipal wastewater subjected to acid addition for pH control (MWW_pH); secondary treated municipal wastewater subjected to nitrification and sand filtration (MWW_NF); and secondary treated municipal wastewater subjected nitrification, sand filtration, and GAC adsorption (MWW_NFG). Tertiary treatment was determined to be essential to achieve appropriate corrosion, scaling, and biofouling control for use of secondary treated municipal wastewater in power plant cooling systems. The ability to control scaling, in particular, was found to be significantly enhanced with tertiary treated wastewater compared to secondary treated wastewater. MWW_pH treated water (adjustment to pH 7.8) was effective in reducing scale formation, but increased corrosion and the amount of biocide required to achieve appropriate biofouling control. Corrosion could be adequately controlled with tolytriazole addition (4-5 ppm TTA), however, which was the case for all of the tertiary treated waters. For MWW_NF treated water, the removal of ammonia by

  10. Peracetic acid (PAA) disinfection of primary, secondary and tertiary treated municipal wastewaters.

    Science.gov (United States)

    Koivunen, J; Heinonen-Tanski, H

    2005-11-01

    The efficiency of peracetic acid (PAA) disinfection against enteric bacteria and viruses in municipal wastewaters was studied in pilot-scale. Disinfection pilot-plant was fed with the primary or secondary effluent of Kuopio municipal wastewater treatment plant or tertiary effluent from the pilot-scale dissolved air flotation (DAF) unit. Disinfectant doses ranged from 2 to 7 mg/l PAA in the secondary and tertiary effluents, and from 5 to 15 mg/l PAA in the primary effluents. Disinfection contact times were 4-27 min. Disinfection of secondary and tertiary effluents with 2-7 mg/l PAA and 27 min contact time achieved around 3 log reductions of total coliforms (TC) and enterococci (EC). PAA disinfection also significantly improved the hygienic quality of the primary effluents: 10-15 mg/l PAA achieved 3-4 log reductions of TC and EC, 5 mg/l PAA resulting in below 2 log reductions. F-RNA coliphages were more resistant against the PAA disinfection and around 1 log reductions of these enteric viruses were typically achieved in the disinfection treatments of the primary, secondary and tertiary effluents. Most of the microbial reductions occurred during the first 4-18 min of contact time, depending on the PAA dose and microorganism. The PAA disinfection efficiency remained relatively constant in the secondary and tertiary effluents, despite of small changes of wastewater quality (COD, SS, turbidity, 253.7 nm transmittance) or temperature. The disinfection efficiency clearly decreased in the primary effluents with substantially higher microbial, organic matter and suspended solids concentrations. The results demonstrated that PAA could be a good alternative disinfection method for elimination of enteric microbes from different wastewaters.

  11. High-resolution δ13C record of fossil wood and bulk organic matter from a deep Oligocene lacustrine succession, Bach Long Vi Island, Vietnam

    Science.gov (United States)

    Rizzi, M.; Schovsbo, N. H.; Fyhn, M. B. W.; Korte, C.

    2017-12-01

    We present a high-resolution stable isotope record based on bulk organic matter (δ13Corg) and fossil wood (δ13Cwood) originating from Oligocene deep lacustrine sediments cored on the Bach Long Vi Island, northern Gulf of Tonkin, offshore Vietnam. The sediments are exceptionally well preserved. They are thus excellently suited for a detailed stratigraphical analysis of the stable isotope record and as proxy for environmental and climatic changes within this period. The sediments were deposited in rapid subsiding, narrow and elongated fault-bound graben (Fyhn and Phach, 2015) and are represented by deep pelagic lacustrine organic-rich mud interrupted by numerous density-flow deposits (Hovikoski et al., 2016). The density-flow deposits contain abundant fragments of fossil wood. Therefore it was possible to obtain 262 coalified wood fragments together with 1063 bulk organic samples throughout the span of the core. This allowed to establish a high resolution stable C isotope record (δ13Corg and δ13Cwood). In addition 2464 handheld XRF determinations were carried out to further characterize the depositional environment (Rizzi et al., 2017). The organic carbon isotope trend from the 500 m core succession provides insight into the palaeoenvironmental changes of the lake during the Oligocene. Both, global and local factors control the δ13C variations. The aim of the study is to obtain pure global δ13Corg and δ13Cwood signals that would allow comparison of the studied sediments with coeval syn-rift successions in the South China Sea region and other parts of the world. [1] Fyhn and Phach (2015) Tectonics, 34(2): 290-312. [2] Hovikoski et al. (2016) Journal of Sedimentary Research, 86(8): 982-1007. [3] Rizzi et al. (2017) EGU General Assembly Abstract EGU 2017-17584.

  12. Wind influence on the course of sedimentation processes of the laminated lacustrine sediments of Lake Czechowskie

    Science.gov (United States)

    Wiśniewska, Daria; Kramkowski, Mateusz; Tyszkowski, Sebastian

    2016-04-01

    The studies of the laminated lacustrine sediments play a very important role in the analysis of climate change. They provide valuable information related to the response of the ecosystem to changes in the environment. The condition for the development of the annual lamination is calm sedimentation, which can be compromised by the movement of water caused by waving. The depth to which this movement affects depends on the shape of the lake basin as well as the velocity and direction of the wind. During the study of sedimentary processes of laminated deposits in Lake Czechowskie (Tuchola Forest, North Poland, 53°52'N, 18°14' E, 108 m asl), the following question arose: How strong was the influence of the wind on the processes of lacustrine sedimentation? The key in getting the answers was the use of GIS techniques. Lake Czechowskie has an area of 76.6 hectares; it has two deeps separated by a threshold: a deeper one of 33 m (maximum depth of the basin) in the central-eastern part, and a shallower of 13 m in the western part. The speed of movement of water that is able to move sediment from the bottom of the lake, called the orbital wave velocity, is the basis for the designation of areas where re-suspension takes place. To calculate the wave parameters, the process of mixing, as well as the designation of re-suspension zones, the tool-script Wave Model (Rohweder et al. 2008) in the program ArsGIS 10.1 was used. The input data were wind direction and velocity from the meteorological station of Wirty about 15 km away, bathymetric data from acoustic profiling, and the Maximum Orbital Wave Velocity. The elements taken into account include maximum wind velocity of the multi-year 1996-2013, with particular emphasis on hurricanes Ksawery (December 2013) and Yoda (November 2011), during which wind velocity exceeded 120 km/h. In addition, maximum wind velocity ever recorded in the Polish Lowlands was considered. On the basis of the modelling, the authors delimited the areas

  13. Chapter B: Regional Geologic Setting of Late Cenozoic Lacustrine Diatomite Deposits, Great Basin and Surrounding Region: Overview and Plans for Investigation

    Science.gov (United States)

    Wallace, Alan R.

    2003-01-01

    Freshwater diatomite deposits are present in all of the Western United States, including the Great Basin and surrounding regions. These deposits are important domestic sources of diatomite, and a better understanding of their formation and geologic settings may aid diatomite exploration and land-use management. Diatomite deposits in the Great Basin are the products of two stages: (1) formation in Late Cenozoic lacustrine basins and (2) preservation after formation. Processes that favored long-lived diatom activity and diatomite formation range in decreasing scale from global to local. The most important global process was climate, which became increasingly cool and dry from 15 Ma to the present. Regional processes included tectonic setting and volcanism, which varied considerably both spatially and temporally in the Great Basin region. Local processes included basin formation, sedimentation, hydrology, and rates of processes, including diatom growth and accumulation; basin morphology and nutrient and silica sources were important for robust activity of different diatom genera. Only optimum combinations of these processes led to the formation of large diatomite deposits, and less than optimum combinations resulted in lakebeds that contained little to no diatomite. Postdepositional processes can destroy, conceal, or preserve a diatomite deposit. These processes, which most commonly are local in scale, include uplift, with related erosion and changes in hydrology; burial beneath sedimentary deposits or volcanic flows and tuffs; and alteration during diagenesis and hydrothermal activity. Some sedimentary basins that may have contained diatomite deposits have largely been destroyed or significantly modified, whereas others, such as those in western Nevada, have been sufficiently preserved along with their contained diatomite deposits. Future research on freshwater diatomite deposits in the Western United States and Great Basin region should concentrate on the regional

  14. Stable isotope (δ"1"3C and δ"1"5N) based interpretation of organic matter source and paleoenvironmental conditions in Al-Azraq basin, Jordan

    International Nuclear Information System (INIS)

    Ahmad, Khaldoun; Davies, Caroline

    2017-01-01

    This study examines the stable isotopes of carbon and nitrogen from cored lacustrine sediments of the Al-Azraq, an arid lake basin on the Jordan Plateau. Lacustrine sediments contain valuable records of paleoenvironmental conditions, recording local and regional responses to environmental change. Previous paleo-reconstructions on the Jordan Plateau are based on archaeology, pollen, mineralogy, and stratigraphy. The application of organic geochemistry analyses to these lake sediments identifies multiple sources of organic matter, biological production, and contributes to understanding the paleoenvironments of the Al-Azraq basin during the mid-Pleistocene period. Organic carbon concentration (Corg) provides an overview of the organic matter distribution. Carbon isotopic composition (δ13Corg) and nitrogen isotopic composition (δ15N) are indicators of organic matter sources and paleoproductivity. Magnetic susceptibility (MGSUS) measured the concentration of ferromagnetic minerals and indicated aeolian inputs. Organic geochemistry differentiated five paleoenvironmental zones with specific sources of organic matter, both aquatic and terrestrial. It identified a long period of climate wetter than the present, punctuated by a short intense period of aridity. Diagenesis plays an important role in the decomposition of organic matter and studies indicate this degradation can alter the isotopic signals of organic matter. Analyses of the isotopic signals and statistical analyses demonstrate diagenesis is not a factor in the Al-Azraq sediments in all but Zone 4 of the paleoenvironmental zones. This Zone is defined by less negative carbon isotopic composition and the presence of thick primary gypsum layers, in addition to the influx of high peaks of aeolian sediment as reflected in the magnetic susceptibility data. Stable isotope geochemistry provides detailed information on the paleoenvironments of lake sediments, and is applicable to typically challenging arid basin sediments

  15. Ascertainment bias in dementias: a secondary to tertiary centre analysis in Central Italy and conceptual review.

    Science.gov (United States)

    Bonanni, L; Bontempo, G; Borrelli, I; Bifolchetti, S; Buongarzone, M P; Carlesi, N; Carolei, A; Ciccocioppo, F; Colangelo, U; Colonna, G; Desiderio, M; Ferretti, S; Fiorelli, L; D'Alessio, O; D'Amico, A; D'Amico, M C; De Lucia, R; Del Re, L; Di Blasio, F; Di Giacomo, R; Di Iorio, A; Di Santo, E; Di Giuseppe, M; Felice, N; Litterio, P; Gabriele, A; Mancino, E; Manzoli, L; Maruotti, V; Mearelli, S; Molino, G; Monaco, D; Nuccetelli, F; Onofrj, M; Perfetti, B; Sacchet, C; Sensi, F; Sensi, S; Sucapane, P; Taylor, J P; Thomas, A; Viola, P; Viola, S; Zito, M; Zhuzhuni, H

    2013-06-01

    Ascertainment bias (AB) indicates a bias of an evaluation centre in estimating the prevalence/incidence of a disease due to the specific expertise of the centre. The aim of our study was to evaluate classification of different types of dementia in new cases appearing in secondary and tertiary centres, in order to evidence possible occurrence of AB in the various (secondary to tertiary) dementia centres. To assess the mechanism of AB, the rates of new cases of the different forms of dementia reported by different centres were compared. The centres involved in the study were 11 hospital-based centres including a tertiary centre, located in the University Department of Clinical Neurology. The tertiary centre is endowed with state-of-the-art diagnostic facilities and its scientific production is prominently focused on dementia with Lewy bodies (DLB) thus suggesting the possible occurrence of a bias. Four main categories of dementia were identified: Alzheimer's disease (AD), DLB, fronto-temporal dementia (FTD), vascular dementia (VaD), with other forms in a category apart. The classification rate of new cases of dementia in the tertiary centre was compared with rates reported by secondary centres and rates of recoding were calculated during a follow-up of 2 years. The study classified 2,042 newly diagnosed cases of dementia in a population of 1,370,000 inhabitants of which 315,000 were older than 65. AD was categorized in 48-52 % of cases, DLB in 25-28 %, FTD in 2-4 % and VaD in 17-28 %. During the 2-year follow-up the diagnosis was re-classified in 40 patients (3 %). The rate of recoding was 5 % in the tertiary centre, 2-8 % in referrals from secondary to tertiary centre, 2-10 % in recodings performed in secondary centres and addressed to tertiary centre. Recoding or percentages of new cases of AD or DLB were not different in the comparison between secondary or between secondary and tertiary centres. FTD and VaD were instead significantly recoded. The results

  16. Tertiary Students' ICT Self-Efficacy Beliefs and the Factors Affecting Their ICT-Use

    Science.gov (United States)

    Turel, Vehbi; Calik, Sinan; Doganer, Adem

    2015-01-01

    This study looked at tertiary (i.e. undergraduate /a four-year degree) students' information and communication technology (ICT) self-efficacy beliefs and their level in use of certain common programmes at a newly established (i.e. 2007) university in Turkey in the spring of 2012. The study examined the tertiary students' (a) demographic…

  17. Student Expectations of Tertiary Institutions: A Case Study of the Fiji National University (FNU)

    Science.gov (United States)

    Khan, Shana Nigar

    2012-01-01

    Education is a human right and Fiji's tertiary education board recently declared that all tertiary institutions in Fiji must abide by the framework in order to meet student-customers' needs. The Fiji National University's (FNU's) destiny to be Fiji's leading higher education provider could be a reality if students and staff's expectations are…

  18. A study of structure–activity relationships of commercial tertiary amines for post-combustion CO_2 capture

    International Nuclear Information System (INIS)

    Xiao, Min; Liu, Helei; Idem, Raphael; Tontiwachwuthikul, Paitoon; Liang, Zhiwu

    2016-01-01

    Highlights: • Ethyl group is beneficial for tertiary amines of CO_2 absorption. • The existence of side carbon chain may promote the activity of tertiary amine. • Hydroxyl group reduces the equilibrium CO_2 solubility, k_2 and pKa. • Heterocyclic structure decrease the equilibrium CO_2 solubility, k_2 and pKa. • Hydroxyl group results in higher CO_2 absorption heat. - Abstract: This work examined the relationship between the structure of various commercial tertiary amines and their activity in CO_2 absorption/desorption in terms of rate of CO_2 absorption, equilibrium CO_2 loading, pKa and heat of CO_2 absorption in order to establish possible guidelines for selection of tertiary amine components for amine blends. Results show that any electron donating group linked directly to the nitrogen atom increases their reactivity with CO_2. In addition, the presence of steric hindrance effect and good water solubility also show enhancements in activity. In contrast, the existence of a hydroxyl group leads to a decrease in all the activity of the tertiary amine. The heat of CO_2 absorption of tertiary amines, which is closely related to the regeneration energy, can be reduced by decreasing the number of hydroxyethyl groups or by positing the hydroxyl group at the proper carbon relative to the nitrogen atom.

  19. The consumption of electric power on the tertiary sector - an instrument for economical and social analysis and market studies

    International Nuclear Information System (INIS)

    Villela, L.E.

    1991-04-01

    The main subjective of this thesis is to analyse the effects of the growth of the tertiary sector on the electric power demand. In order to accomplish this goal an economical and social, analysis of the tertiary sector is made to identify its dynamic, its relations with the other sectors of the economy and to describe the methodologies for measuring the overall tertiary production. Afterwards it is made an analysis of the electric power consumption evolution in the tertiary sector, in order to identify the consumption per region of the country, per consumers and tertiary subsectors. It is also analysed the product power intensify and, finally its described the present tariff system. (author)

  20. Forsmark site investigation. Investigation of marine and lacustrine sediment in lakes. Field data 2003

    Energy Technology Data Exchange (ETDEWEB)

    Hedenstroem, Anna [SGU, Uppsala (Sweden)

    2003-04-01

    The aim of this activity is to describe the aerial and stratigraphical distribution of marine and lacustrine sediment i.e. sediment overlaying the glacial till and/or bedrock surface, in lakes in the Forsmark area. The investigation is carried out within areas where mapping of unconsolidated Quaternary deposits is presently carried out. Since small and shallow lakes cover a large part of the region, this work will give important information on the distribution and stratigraphy of sedimentary deposits not included in the regular mapping of unconsolidated Quaternary deposits within the site investigation programme. Samples were also collected for laboratory analyses of grain size distribution, mineralogical composition as well as the total content of C, N and S and calcium carbonate. The analyses will be carried out on selected samples of representative sedimentary units in order to characterise the chemical and physical properties of the unconsolidated deposits. The analytical data will be useful for the hydrogeological modelling and for models of the Quaternary evolution of the area. The mineralogical analyses of clay may provide information on the origin of the clay particles. One stratigraphic sequence from Lake Eckarfjaerden will be stored for later analyses, e.g. pollen analysis. This report includes field data from spring 2003. Together, the field data and the forthcoming results from the laboratory analyses will form the basis for construction of stratigraphical profiles to be presented in a following report in the fall 2003.

  1. Forsmark site investigation. Investigation of marine and lacustrine sediment in lakes. Field data 2003

    International Nuclear Information System (INIS)

    Hedenstroem, Anna

    2003-04-01

    The aim of this activity is to describe the aerial and stratigraphical distribution of marine and lacustrine sediment i.e. sediment overlaying the glacial till and/or bedrock surface, in lakes in the Forsmark area. The investigation is carried out within areas where mapping of unconsolidated Quaternary deposits is presently carried out. Since small and shallow lakes cover a large part of the region, this work will give important information on the distribution and stratigraphy of sedimentary deposits not included in the regular mapping of unconsolidated Quaternary deposits within the site investigation programme. Samples were also collected for laboratory analyses of grain size distribution, mineralogical composition as well as the total content of C, N and S and calcium carbonate. The analyses will be carried out on selected samples of representative sedimentary units in order to characterise the chemical and physical properties of the unconsolidated deposits. The analytical data will be useful for the hydrogeological modelling and for models of the Quaternary evolution of the area. The mineralogical analyses of clay may provide information on the origin of the clay particles. One stratigraphic sequence from Lake Eckarfjaerden will be stored for later analyses, e.g. pollen analysis. This report includes field data from spring 2003. Together, the field data and the forthcoming results from the laboratory analyses will form the basis for construction of stratigraphical profiles to be presented in a following report in the fall 2003

  2. Early Tertiary magmatism and probable Mesozoic fabrics in the Black Mountains, Death Valley, California

    Science.gov (United States)

    Miller, Martin G.; Friedman, Richard M.

    1999-01-01

    We report two early Tertiary U-Pb zircon ages for pegmatite from the Black Mountains of Death Valley, California. These ages, 54.7 ± 0.6 Ma and 56 ± 3 Ma, are unique for much of southeastern California. The samples belong to a pegmatite suite that occupies part of the footwall of the Badwater turtleback, a late Tertiary extensional feature; similar but undated pegmatite intrudes the footwalls of the Copper Canyon and Mormon Point turtlebacks farther south. The pegmatite suite demonstrates that fabric development on the turtlebacks was at least a two-stage process. Fabrics cut by these pegmatites likely formed during the Mesozoic, whereas those that involve them formed during late Tertiary extension.

  3. Water-quality characteristics of quaternary unconsolidated-deposit aquifers and lower tertiary aquifers of the Bighorn Basin, Wyoming and Montana, 1999-2001

    Science.gov (United States)

    Bartos, Timothy T.; Eddy-Miller, Cheryl A.; Norris, Jody R.; Gamper, Merry E.; Hallberg, Laura L.

    2004-01-01

    samples with larger concentrations generally were calcium-sodium-sulfate, calcium-sulfate, or sodium-sulfate-type waters. In the lower Tertiary aquifers, samples with fresh waters generally were sodium-bicarbonate or sodium-bicarbonate-sulfate type waters, whereas samples with larger concentrations were sodium-sulfate or calcium-sodium-sulfate types. Concentrations of most trace elements in both types of aquifers generally were small and most were less than applicable USEPA standards. The trace elements that most often did not meet USEPA secondary drinking-water standards were iron and manganese. In fact, the SMCL for manganese was the most frequently exceeded standard; 68 percent of the samples from the Quaternary aquifers and 31 percent of the samples from the lower Tertiary aquifers exceeded the manganese standard. Geochemical conditions may control manganese in both aquifers as concentrations in Quaternary aquifers were negatively correlated with dissolved oxygen concentrations and concentrations in lower Tertiary aquifers decreased with increasing pH. Elevated nitrate concentrations, in addition to detection of pesticides and VOCs in both aquifers, indicated some effects of human activities on ground-water quality. Nitrate concentrations in 36 percent of the wells in Quaternary aquifers and 28 percent of the wells in lower Tertiary aquifers were greater than 1 mg/L, which may indicate ground-water contamination from human sources. The USEPA drinking-water Maximum Contaminant Level (MCL) for nitrate, 10 mg/L, was exceeded in 8 percent of samples collected from Quaternary aquifers and 3 percent from lower Tertiary aquifers. Nitrate concentrations in Quaternary aquifers were positively correlated with the percentage of cropland and other agricultural land (non-cropland), and negatively correlated with rangeland and riparian land. In the lower Tertiary aquifers, nitrate concentrations only were correlated with the percentage of cropland. Concentratio

  4. Montane pollen from the Tertiary of NW. Borneo

    NARCIS (Netherlands)

    Muller, J.

    1966-01-01

    In NW. Borneo thick series of Tertiary sediments occur which are rich in fossil pollen and spores. The majority of these plant microfossils were derived from the various types of tropical lowland vegetation such as mangrove (Muller, 1964), mixed peat swamp forest and mixed Dipterocarp forest. Some

  5. Secondary and tertiary hyperparathyroidism in chronic kidney disease

    Directory of Open Access Journals (Sweden)

    Lilit V. Egshatyan

    2017-12-01

    Full Text Available In the treatment of secondary hyperparathyroidism of end-stage chronic kidney disease, vitamin D receptor activation and allosteric modulators of the calcium-sensing receptor – inhibit glandular hyperplasia, reduce parathyroid hormone levels, impact on bone turnover and mineral density. But the use of calcimimetic and vitamin D analogs or mimetics did not reduce the need for parathyroidectomy for refractory hyperparathyroidism. The enlarged parathyroid gland and gland nodular transformation became refractory to medical therapy and patient need for parathyroidectomy. Tertiary hyperparathyroidism is a state of excessive secretion of parathyroid hormone after a long period of secondary hyperparathyroidism and renal transplantation. In this article, we present the case of a Caucasian male with chronic kidney disease (end-stage on chronic hemodialysis and after kidney transplantation and different forms of hyperparathyroidism (secondary and tertiary. Our case study shows that only a multi-interventional strategy is likely to be more effective treatment in cases of severe and refractory to medical therapy hyperparathyroidism.

  6. Medical treatment of primary, secondary, and tertiary hyperparathyroidism.

    Science.gov (United States)

    Vestergaard, Peter; Thomsen, Susanna vid Strym

    2011-04-01

    Hyperparathyroidism is a condition with elevated parathyroid hormone (PTH). The increase may be due to a) primary hyperparathyroidism which is caused by adenoma of one or more parathyroid glands or hyperplasia of all four glands, b) secondary hyperparathyroidism, which may be caused by deficiency in vitamin D or uremia, and 3) tertiary hyperparathyroidism, which most often is the result of a long-standing, severe secondary hyperparathyroidism, which has turned autonomous once the cause of the secondary hyperparathyroidism has been removed. Many new treatment options have been introduced in recent years. Cinacalcet is calcium sensing receptor agonist, which by stimulating the receptor decreases PTH and calcium levels. It may be used in primary hyperparathyroidism, secondary hyperparathyroidism caused by uremia, which may not be controlled with calcium and activated vitamin D. It may also be used in tertiary hyperparathyroidism. Newer analogues of vitamin D such as paricalcitol have also been introduced, which may have an advantage over traditional compounds such as alphacalcidol and calcitriol.

  7. The use of tribromoisocyanuric acid to distinguish among primary, secondary and tertiary alcohols

    Energy Technology Data Exchange (ETDEWEB)

    Crespo, Livia T.C., E-mail: livia.vilela@ifrj.edu.br [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Instituto de Quimica. Departamento de Quimica Organica; Instituto Federal de Educacao, Ciencia e Tecnologia do Rio de Janeiro (IF-RJ), Duque de Caxias, RJ (Brazil); Mattos, Marcio C.S. de; Esteves, Pierre M. [Universidade Federal do Rio de Janeiro (UFRJ), RJ (Brazil). Instituto de Quimica. Departamento de Quimica Organica

    2013-09-01

    Primary, secondary and tertiary alcohols can be easily distinguished due to their reactivity towards tribromoisocyanuric acid (TBCA). The test is performed by adding TBCA to the alcohol in a test tube heated in a boiling water bath. Orange color develops in the tube containing the primary alcohol, light yellow is observed in the tube containing the secondary alcohol while the tertiary alcohol results in a colorless mixture. (author)

  8. The use of tribromoisocyanuric acid to distinguish among primary, secondary and tertiary alcohols

    International Nuclear Information System (INIS)

    Crespo, Livia T.C.; Mattos, Marcio C.S. de; Esteves, Pierre M.

    2013-01-01

    Primary, secondary and tertiary alcohols can be easily distinguished due to their reactivity towards tribromoisocyanuric acid (TBCA). The test is performed by adding TBCA to the alcohol in a test tube heated in a boiling water bath. Orange color develops in the tube containing the primary alcohol, light yellow is observed in the tube containing the secondary alcohol while the tertiary alcohol results in a colorless mixture. (author)

  9. The use of tribromoisocyanuric acid to distinguish among primary, secondary and tertiary alcohols

    Directory of Open Access Journals (Sweden)

    Lívia T. C. Crespo

    2013-01-01

    Full Text Available Primary, secondary and tertiary alcohols can be easily distinguished due to their reactivity towards tribromoisocyanuric acid (TBCA. The test is performed by adding TBCA to the alcohol in a test tube heated in a boiling water bath. Orange color develops in the tube containing the primary alcohol, light yellow is observed in the tube containing the secondary alcohol while the tertiary alcohol results in a colorless mixture.

  10. Hydro-climatic changes since 13.000 years B.P. in eastern Tibet and north of Xinjiang (China). Approach using the study of some lacustrine records

    International Nuclear Information System (INIS)

    Assaraj, A.

    1997-01-01

    The aim of this study is to build the chronology of the medium and short term climatic changes that took place during the last glacial and Holocene periods using sedimentological and isotopic data obtained on cores from the Aibi lake (north of Xinjiang, China) and from the Madoi and Donxi lakes (eastern part of the Tibetan plateau). At Aibi, after the chemical, isotopic and physico-chemical characterization of the lake waters, and the sedimentological study of the laminae (granulometry and mineralogy) have been done, the measurements of 18 O and 13 C of the authigenous carbonates and of the thickness variations of laminae have evidenced the seasonal character of the laminae. The spectral analyses of the thickness variations indicate periodicities linked with the quasi-biennial oscillations (2 or 3 years) and with the solar cycles (10-11 years). East of the Tibetan plateau, the sedimentological and isotopic study of the cores from the Madoi and Donxi lakes show more humid and hot climate conditions during the lower and middle Holocene. The sedimentary record of lake Madoi show one or several lacustrine or fluvio-lacustrine phases after 13000-12000 years B.P. A high dryness period took place within the Younger Dryas chrono-zone. Since 10000 year B.P. the 3 lakes are filled with isotopically diluted waters. The last glacial-Holocene transition seems to be very sharp and located around 10000 years B.P. both in northern Xinjiang and eastern Tibet and confirm the results previously obtained in Qinghai and northern-Xinjiang. After the optimum hydrologic phase of the lower and middle Holocene, the come back of dryer conditions started at about 6000 or 5000 years B.P. and hydrological conditions became close to the present day ones since 3000 years B.P. (J.S.)

  11. Palynological and iridium anomalies at Cretaceous-Tertiary boundary, south-central Saskatchewan

    Science.gov (United States)

    Nichols, D.J.; Jarzen, D.M.; Orth, C.J.; Oliver, P.Q.

    1986-01-01

    The Cretaceous-Tertiary boundary in south-central Saskatchewan is marked by coincident anomalies in abundance of iridium and fern spores at the extinction level of a suite of Cretaceous pollen taxa. Evidence of disruption of the terrestrial flora includes the fern-spore abundance anomaly and local extinction of as much as 30 percent of angiosperm species. The reorganized earliest Tertiary flora is made up largely of surviving species that assumed new roles of dominance. Persistence of climatically sensitive taxa across the boundary indicates that if paleoclimate was altered by the terminal Cretaceous event, it returned quickly to the pre-event condition.

  12. Clay minerals behaviour in thin sandy clay-rich lacustrine turbidites (Lake Hazar, Turkey)

    Science.gov (United States)

    El Ouahabi, Meriam; Hubert-Ferrari, Aurelia; Lamair, Laura; Hage, Sophie

    2017-04-01

    Turbidites have been extensively studied in many different areas using cores or outcrop, which represent only an integrated snapshot of a dynamic evolving flow. Laboratory experiments provide the missing relationships between the flow characteristics and their deposits. In particular, flume experiments emphasize that the presence of clay plays a key role in turbidity current dynamics. Clay fraction, in small amount, provides cohesive strength to sediment mixtures and can damp turbulence. However, the degree of flocculation is dependent on factors such as the amount and size of clay particles, the surface of clay particles, chemistry and pH conditions in which the clay particles are dispersed. The present study focuses on thin clayey sand turbidites found in Lake Hazar (Turkey) occurring in stacked thin beds. Depositional processes and sources have been previously studied and three types were deciphered, including laminar flows dominated by cohesion, transitional, and turbulence flow regimes (Hage et al., in revision). For the purpose of determine the clay behavior in the three flow regimes, clay mineralogical, geochemical measurements on the cores allow characterising the turbidites. SEM observations provide further information regarding the morphology of clay minerals and other clasts. The study is particularly relevant given the highly alkaline and saline water of the Hazar Lake. Clay minerals in Hazar Lake sediments include kaolinite (1:1-type), illite and chlorite (2:1-type). Hazar lake water is alkaline having pH around 9.3, in such alkaline environment, a cation-exchange reaction takes place. Furthermore, in saline water (16‰), salts can act as a shield and decrease the repulsive forces between clay particle surfaces. So, pH and salt content jointly impact the behaviour of clays differently. Since the Al-faces of clay structures have a negative charge in basic solutions. At high pH, all kaolinite surfaces become negative-charged, and then kaolinite

  13. Innovating in the Real World: Exploring Institutional Effects on Tertiary Teacher Innovations in New Zealand

    Science.gov (United States)

    Lawrence, Belinda

    2018-01-01

    Innovation is a key goal of many tertiary education and distance learning providers. This research explores how teachers and educational designers across three New Zealand tertiary institutions worked to innovatively achieve teaching goals. A longitudinal design using the Cultural Historical Activity Theory (CHAT) framework explored the influence…

  14. Social Activities and Manifest Anxiety among Freshmen in Tertiary ...

    African Journals Online (AJOL)

    ) in tertiary institutions in Lagos state of Nigeria were analysed to determine the relationship between social activities and manifest anxiety. Social activities in the study were measured in terms of freshmen adjustment to religious activities and ...

  15. Tertiary lymphoid organs in Takayasu Arteritis

    OpenAIRE

    Marc eClement; Marc eClement; Adrien eGaly; Patrick eBruneval; Marion eMorvan; Fabien eHyafil; Fabien eHyafil; Khadija eBenali; Nicoletta ePasi; Lydia eDeschamps; Quentin ePellenc; Quentin ePellenc; Thomas ePapo; Antonino eNicoletti; Antonino eNicoletti

    2016-01-01

    Objective: The role of B cells in the pathogenesis of Takayasu arteritis (TA) is controversial. We aimed to study the presence of tertiary lymphoid organs (TLOs) in the aortic wall of TA patients.Methods: Hematoxylin and eosin–stained sections from aorta specimens from patients with TA were screened for TLOs. The presence of B cell aggregates (CD20), follicular dendritic cells (FDCs, CD21), and high endothelial venules (HEVs, PNAd) was investigated by immunohistochemistry. Immune cells from t...

  16. Tertiary Lymphoid Organs in Takayasu Arteritis

    OpenAIRE

    Clement, Marc; Galy, Adrien; Bruneval, Patrick; Morvan, Marion; Hyafil, Fabien; Benali, Khadija; Pasi, Nicoletta; Deschamps, Lydia; Pellenc, Quentin; Papo, Thomas; Nicoletti, Antonino; Sacre, Karim

    2016-01-01

    Objective The role of B cells in the pathogenesis of Takayasu arteritis (TA) is controversial. We aimed to study the presence of tertiary lymphoid organs (TLOs) in the aortic wall of TA patients. Methods Hematoxylin and eosin-stained sections from aorta specimens from patients with TA were screened for TLOs. The presence of B cell aggregates (CD20), follicular dendritic cells (FDCs, CD21), and high endothelial venules (HEVs, PNAd) was investigated by immunohistochemistry. Immune ce...

  17. Helpless patients' perception of bed-bath in tertiary health ...

    African Journals Online (AJOL)

    Helpless patients' perception of bed-bath in tertiary health institutions in Enugu, Southeast Nigeria. ... Journal Home > Vol 10, No 2 (2005) > ... patients to bed bathing by nurses is a very important aspect of quality assurance in nursing care.

  18. The effect of the development of an emergency transfer system on the travel time to tertiary care centres in Japan

    Directory of Open Access Journals (Sweden)

    Arima Hideaki

    2006-06-01

    Full Text Available Abstract Background In Japan, the emergency medical system is categorized into three levels: primary, secondary, and tertiary, depending on the severity of the condition of the patient. Tertiary care centres accept patients who require 24-h monitoring. In this research, the average travel times (minutes from the centroids of all municipalities in Japan to the nearest tertiary care centre were estimated, using the geographic information system. The systems affecting travel time to tertiary care centres were also examined. Regression analysis was performed to determine the factors affecting the travel time to tertiary care centres, using selected variables representing road conditions and the emergency transfer system. Linear regression analysis was performed to identify specific benchmarks that would be effective in reducing the average travel time to tertiary care centres in prefectures with travel times longer than the average 57 min. Results The mean travel time was 57 min, the range was 83 min, and the standard deviation was 20.4. As a result of multiple regression analysis, average coverage area per tertiary care centre, kilometres of highway road per square kilometre, and population were selected as variables with impact on the average travel time. Based on results from linear regression analysis, benchmarks for the emergency transfer system that would effectively reduce travel time to the mean value of 57 min were identified: 26% pavement ratio of roads (percentage of paved road to general roads, and three tertiary care centres and 108 ambulances. Conclusion Regional gaps in the travel time to tertiary care centres were identified in Japan. The systems we should focus on to reducing travel time were identified. Further reduction of travel time to tertiary care centres can be effectively achieved by improving these specific systems. Linear regression analysis showed that a 26% pavement ratio and three tertiary care centres are beneficial to

  19. Relevance of Donation to Special Federal Tertiary Institution ...

    African Journals Online (AJOL)

    While structured and open-ended interview and relevant documents, including gift and donation files, acquisition records and library accession registers were used to collect data for the study. The population of the study consisted of the Special Federal Tertiary Institution Libraries under study while the subjects of the study ...

  20. Emotional Intelligence and the Conflict Resolution Repertoire of Couples in Tertiary Institutions in Imo State

    Science.gov (United States)

    Nnodum, B. I.; Ugwuegbulam, C. N.; Agbaenyi, I. G.

    2016-01-01

    This study is a descriptive survey that investigated the relationship between emotional intelligence and conflict resolution repertoire of couples in tertiary institutions. A sample of 250 married people were drawn from the population of couples in tertiary institutions in Imo State. Two researcher made and validated instruments were used in…

  1. Late Noachian Icy Highlands climate model: Exploring the possibility of transient melting and fluvial/lacustrine activity through peak annual and seasonal temperatures

    Science.gov (United States)

    Palumbo, Ashley M.; Head, James W.; Wordsworth, Robin D.

    2018-01-01

    The nature of the Late Noachian climate of Mars remains one of the outstanding questions in the study of the evolution of martian geology and climate. Despite abundant evidence for flowing water (valley networks and open/closed basin lakes), climate models have had difficulties reproducing mean annual surface temperatures (MAT) > 273 K in order to generate the ;warm and wet; climate conditions presumed to be necessary to explain the observed fluvial and lacustrine features. Here, we consider a ;cold and icy; climate scenario, characterized by MAT ∼225 K and snow and ice distributed in the southern highlands, and ask: Does the formation of the fluvial and lacustrine features require continuous ;warm and wet; conditions, or could seasonal temperature variation in a ;cold and icy; climate produce sufficient summertime ice melting and surface runoff to account for the observed features? To address this question, we employ the 3D Laboratoire de Météorologie Dynamique global climate model (LMD GCM) for early Mars and (1) analyze peak annual temperature (PAT) maps to determine where on Mars temperatures exceed freezing in the summer season, (2) produce temperature time series at three valley network systems and compare the duration of the time during which temperatures exceed freezing with seasonal temperature variations in the Antarctic McMurdo Dry Valleys (MDV) where similar fluvial and lacustrine features are observed, and (3) perform a positive-degree-day analysis to determine the annual volume of meltwater produced through this mechanism, estimate the necessary duration that this process must repeat to produce sufficient meltwater for valley network formation, and estimate whether runoff rates predicted by this mechanism are comparable to those required to form the observed geomorphology of the valley networks. When considering an ambient CO2 atmosphere, characterized by MAT ∼225 K, we find that: (1) PAT can exceed the melting point of water (>273 K) in

  2. Obesity and associated factors in young adults attending tertiary ...

    African Journals Online (AJOL)

    Obesity and associated factors in young adults attending tertiary institutions ... and associated factors in a group of university undergraduates in south-east Nigeria. ... being a female (X2 = 47.91), first year student (X2 = 41.82), and having high ...

  3. Assessment Quality in Tertiary Education: An Integrative Literature Review

    NARCIS (Netherlands)

    Gerritsen-van Leeuwenkamp, Karin; Joosten-ten Brinke, Desirée; Kester, Liesbeth

    2018-01-01

    In tertiary education, inferior assessment quality is a problem that has serious consequences for students, teachers, government, and society. A lack of a clear and overarching conceptualization of assessment quality can cause difficulties in guaranteeing assessment quality in practice. Thus, the

  4. Optimising Tertiary Student Accommodation within University Neighbourhoods

    OpenAIRE

    Ike, Nnenna; Baldwin, Claudia; Lathouras, Athena

    2017-01-01

    Tertiary students’ activities within neighbourhoods adjacent to universities engender positive and negative impacts that have consequences for neighbourhood sustainability. This might lead to studentification, a process that triggers physical, economic and socio-cultural transformation of university towns. Where non-student residents perceive negative impacts, it can lead to conflict and resentment towards the student population, mistrust between student and local resident groups and a decrea...

  5. Evaluation of the onset of tertiary creep for types 304 and 316 stainless steels

    International Nuclear Information System (INIS)

    Staerk, E.; Picker, C.; Felsen, M.F.

    1989-01-01

    Austenitic stainless steels Types 304 and 316 are used for LMFBR components. Although at high temperature many codes base the allowable stress on the stress rupture strength, some recent codes eg ASME Code Case N47 and RCC-MR also take account of the onset of tertiary creep. In order to examine this latter aspect creep deformation data on Type 304 and Type 316 steel have been collected and analysed. The ratio time to onset of tertiary creep against the time to rupture has been analysed as a function of temperature. At temperatures below 750 0 C the ratio is found to decrease slightly with increasing temperature. Monkman Grant and Lambda relationships have also been investigated. In relation to the ASME S t allowable stress criteria it is shown that below 600 0 C the allowable stress is likely to be governed by the stress rupture strength rather than the onset of tertiary creep criterion. Recommendations are given concerning the determination of the onset of tertiary creep, the fitting of the Leyda/Rowe relationship and a method to compute the maximum allowable stress S t from equation describing the time-temperature dependency of the three constituents of S t

  6. Tandem catalytic allylic amination and [2,3]-Stevens rearrangement of tertiary amines.

    Science.gov (United States)

    Soheili, Arash; Tambar, Uttam K

    2011-08-24

    We have developed a catalytic allylic amination involving tertiary aminoesters and allylcarbonates, which is the first example of the use of tertiary amines as intermolecular nucleophiles in metal-catalyzed allylic substitution chemistry. This process is employed in a tandem ammonium ylide generation/[2,3]-rearrangement reaction, which formally represents a palladium-catalyzed Stevens rearrangement. Low catalyst loadings and mild reaction conditions are compatible with an unprecedented substrate scope for the ammonium ylide functionality, and products are generated in high yields and diastereoselectivities. Mechanistic studies suggested the reversible formation of an ammonium intermediate.

  7. Catahoula Formation as uranium source rock in East Texas

    International Nuclear Information System (INIS)

    Ledger, E.B.; Tieh, T.T.; Rowe, N.W.

    1984-01-01

    The Oligocene-Miocene Catahoula Formation of the Texas Gulf coastal plain is a fluvial and lacustrine volcaniclastic unit composed of normal fluvial material mixed with distal rhyolitic air-fall ash. In the lower Texas Gulf coastal plain, it consists of stream-transported detritus from the volcanic source area in Trans-Pecos Texas and adjacent Mexico. This volcaniclastic component has altered to release uranium to mineralization processes in the lower Gulf Coast, but there has not been uranium production in the middle and upper Gulf Coast. To evaluate the potential of the upper Texas Gulf coastal plain for uranium ore deposits, a geochemical study was undertaken. The Catahoula Formation was analyzed for U, Th, K, Rb, Sr, Zr, and Ti to estimate the nature of volcanic glass and its abundance and alteration. Concentrations from three key outcrops were compared. They were also compared to samples from a volcanic area in Trans-Pecos Texas, which is chemically appropriate as a source for the volcanic material in the Catahoula Formation. In the lower Texas Gulf coastal plain, where uranium is produced, the glassy volcanic material has been pervasively altered, but in the upper coastal plain much glass remains. Because glass alteration is necessary for uranium release and concentration, the potential is low for large, shallow uranium ore bodies in the upper Texas Gulf coastal plain

  8. Constructing Knowledge Societies: New Challenges for Tertiary Education.

    Science.gov (United States)

    Salmi, Jamil

    2003-01-01

    The principal set of challenges facing tertiary education today is that set which links it to the construction of knowledge societies. Governments, the private sector, and the World Bank have specific tasks to perform in meeting these challenges. Countries--depending upon whether or not they are transition economies, low-income countries, or small…

  9. Tertiary Educational Institutions for Teaching, Research and Development

    Science.gov (United States)

    Amoo, Sikiru A.

    2014-01-01

    This paper examines the quality of teaching and research in developing human resources to facilitate the development of tertiary education in the nation. It discusses the challenges and the roles of research in higher education. The author argues that the combination of content and pedagogical knowledge could help to develop human resources for…

  10. Management for the children with otitis media with effusion in the tertiary hospital.

    Science.gov (United States)

    Choung, Yun-Hoon; Shin, You Ree; Choi, Seong Jun; Park, Keehyun; Park, Hun Yi; Lee, Jong Bin; Han, Dong Hee; Kahng, Hison

    2008-12-01

    Recently, new evidence-based recommendations have been introduced for diagnosing and managing otitis media with effusion (OME) in children. However, there are some difficulties to follow the general guidelines in the tertiary hospitals. The purpose is to evaluate the efficiency of antibiotics or antihistamines for treatment of children with OME in the tertiary hospital with a randomized prospective clinical study. Eighty-four children with OME who had been diagnosed in the tertiary hospital were randomized to receive 5 different medications for 2 weeks. We prescribed antibiotics (amoxicillin-clavulanate syrup) in Group I (n=16), antibiotics/steroids (prednisolone) in Group II (n=18), antibiotics/antihistamines (ebastine) in Group III (n=15), antibiotics/steroids/antihistamines in Group IV (n=17), and mucolytics (ivy leaf extract) in Group V (n=17) for control. We followed-up children every 2 weeks and evaluated the state of OME at 3 months. Thirty six (42.9%) of 84 children were resolved within average 6.9 weeks after the treatments. Thirty-six (42.9%) were treated with ventilation tube insertion and 12 patients (14.3%) were observed. There was no difference in the resolution rates of OME among the five different protocols (P>0.05). There was no difference in the resolution rates among groups who used steroids, antihistamines, steroids and antihistamines, or other medications to manage 42 children with allergies (P>0.05). In the tertiary hospital, the cure rate of children with OME was not as high as well-known, and antibiotics or anti-allergic medications were not more effective than control. We may, therefore, need any other guidelines which are different from the previous evidence-based recommendations, including early operation in the tertiary hospitals.

  11. Outbreak of carbapenem-resistant Providencia rettgeri in a tertiary ...

    African Journals Online (AJOL)

    Carbapenem resistance in Enterobacteriaceae is often plasmid mediated, necessitating stringent infection control practices. We describe an outbreak of carbapenem-resistant Providencia rettgeri involving 4 patients admitted to intensive care and high-care units at a tertiary hospital. Clinical and demographic characteristics ...

  12. Defining English Language Proficiency for Malaysian Tertiary Education: Past, Present and Future Efforts

    Directory of Open Access Journals (Sweden)

    Chan Swee Heng

    2012-07-01

    Full Text Available Any attempt to define English language proficiency can never be divorced from the theories that describe the nature of language, language acquisition and human cognition. By virtue of such theories being socially constructed, the descriptions are necessarily value-laden. Thus, a definition of language proficiency can only, at best, be described as developmental, following changes that are linguistic, pragmatic, cultural and political. In defining English proficiency for tertiary education, the context is naturally also linked to the focus on university education. The argument has been that an ‘acceptable’ level of language competence of a university applicant is anything but constant. Tremendous social changes have seen traditional values of elitism in university education giving way to the ‘massification’ of education. As Kaplan and Baldauf (1997:257 affirms, “The principal problem in tertiary education is not declining literacy standards but rather it is about meeting changed societal, cultural and informational requirements and circumstances”. In the light of these changes, this paper attempts to trace influencing factors that help define an ‘acceptable’ level of English proficiency for Malaysian tertiary education. The paper examines past and present efforts of establishing an English language policy and assessment practice for tertiary education, and concludes with some views on future development that could evolve from the current indicative pursuits of establishing language learning and ability.

  13. Impact of domestic and tertiary buildings heating by natural gas in the Italian context

    International Nuclear Information System (INIS)

    Aste, Niccolò; Del Pero, Claudio

    2012-01-01

    Natural Gas (NG) is commonly used for satisfying population needs for heating, domestic hot water production and cooking, particularly in countries where the price of electricity is high. Typically, NG is extensively distributed on urbanized territory and can be exploited by using different technologies. As a consequence, primary energy is usually consumed directly in buildings, allowing high efficiency conversion but also producing pollutants in urban areas. In this paper a comprehensive analysis on NG use in the Italian domestic and tertiary building sector has been carried out, in order to evaluate energy and environmental impact of this fuel on different climatic and geographical contexts, also considering the temporal fluctuation of consumption. The aim of the work is to trace a reliable and up-to-date scenario of NG employment for building heating in Italy, which is one of the EU countries where this source is more widely used. The study was carried out under the research program “Analysis and evaluation of the current status of the reduction measures of environmental impacts due to heating energy consumption in Italy”, funded by the Italian Ministry of Environment. The data presented are an essential basis for the development of building energy efficiency and consumption rationalization policies. - Highlights: ► Detailed assessment of natural gas consumption and emission for residential and tertiary buildings heating in Italy. ► Estimation of the average specific primary energy consumption for households heating in different climatic contexts. ► Nationwide, it is the first study on the whole country with this level of detail.

  14. Adults Studying Pure Mathematics in Adult Tertiary Preparation.

    Science.gov (United States)

    Bennison, Anne

    2002-01-01

    Investigated the experiences of a group of adults enrolled in the Pure Mathematics module of the Certificate IV in Adult Tertiary Preparation in 2000 at one of the Institutes of TAFE in Brisbane, Australia. Classroom learning experiences, exposure to technology, and the impact of returning to study on other facets of students' lives were…

  15. Qualitative and quantitative analysis of Dibenzofuran, Alkyldibenzofurans, and Benzo[b]naphthofurans in crude oils and source rock extracts

    Science.gov (United States)

    Meijun Li,; Ellis, Geoffrey S.

    2015-01-01

    Dibenzofuran (DBF), its alkylated homologues, and benzo[b]naphthofurans (BNFs) are common oxygen-heterocyclic aromatic compounds in crude oils and source rock extracts. A series of positional isomers of alkyldibenzofuran and benzo[b]naphthofuran were identified in mass chromatograms by comparison with internal standards and standard retention indices. The response factors of dibenzofuran in relation to internal standards were obtained by gas chromatography-mass spectrometry analyses of a set of mixed solutions with different concentration ratios. Perdeuterated dibenzofuran and dibenzothiophene are optimal internal standards for quantitative analyses of furan compounds in crude oils and source rock extracts. The average concentration of the total DBFs in oils derived from siliciclastic lacustrine rock extracts from the Beibuwan Basin, South China Sea, was 518 μg/g, which is about 5 times that observed in the oils from carbonate source rocks in the Tarim Basin, Northwest China. The BNFs occur ubiquitously in source rock extracts and related oils of various origins. The results of this work suggest that the relative abundance of benzo[b]naphthofuran isomers, that is, the benzo[b]naphtho[2,1-d]furan/{benzo[b]naphtho[2,1-d]furan + benzo[b]naphtho[1,2-d]furan} ratio, may be a potential molecular geochemical parameter to indicate oil migration pathways and distances.

  16. Pedagogical Study into Tertiary Learning Styles in Vietnam

    Directory of Open Access Journals (Sweden)

    Barry Ramsay

    2016-07-01

    Full Text Available Pedagogical studies for tertiary students in Vietnam are limited and no comparative benchmarking studies with other Asian tertiary students found. As a means to fill this gap and provide a better understanding the following study using Biggs (1987c Study Process Questionnaire (SPQ, a 42-item self-report survey consisting of ratings on a 5-point scale to questions relating to respondents' study motivations and their usual study patterns was conducted with 355 respondents. Findings were consistent with Hong Kong students and supports studies carried out in other countries by Kemper et al. (1989, Kemper and Gow (1991, Niles (1995, Volet and Renshaw (1996, Ramburuth (2001 and Hua, Williams and Hoi (2007. Despite learning in a “rote” manner during their formative years, students have adapted to deeper learning approaches although there is a still a slight but insignificant bias to surface learning. They desire to achieve and get good marks although strategy is limiting their progress. According to Biggs, this is commonly caused by a language problem.

  17. English Textbooks in Parallel-Language Tertiary Education

    OpenAIRE

    Pecorari, D.; Shaw, P.; Irvine, Aileen; Malmstrom, H.

    2011-01-01

    Tertiary education in many countries is increasingly bilingual, with English used in parallel with the national language, particularly as a reading language. This article describes the results of a survey of student attitudes toward, and reading practices regarding, English language textbooks. Over 1,000 students at three Swedish universities responded to a questionnaire asking about their experiences with English textbooks. Textbooks written in English were generally unpopular, and the perce...

  18. The development of the tertiary sector in the economy and the reduction in CO2 emissions

    International Nuclear Information System (INIS)

    Morvan, R.; Hubert, M.; Gregoire, P.; Lowezanin, Ch.

    2004-09-01

    The development of the tertiary sector appears to support sustainable development since it now accounts for almost two thirds of the national economy and is responsible for low CO 2 emission levels. Between 1980 and 1997, CO 2 emissions from the tertiary sector increased by 20 % compared with a 48 % rise in the sector value added. In terms of production, CO 2 levels in the tertiary sector are low, compared with 55 % for the secondary sector (industry). However, when trade between economic activities is taken into account, there is cause to qualify the assessment. This makes it possible to ascertain emissions from the point of view of satisfying final demand for products, and to identify direct and indirect emissions in each branch of activity. Thus, when emissions from certain industrial and agricultural activities are redistributed specifically to branches of activity in the tertiary sector, CO 2 emissions in this sector account for almost one-third of total emissions. (A.L.B.)

  19. Ethyl tertiary-butyl ether: a toxicological review.

    Science.gov (United States)

    McGregor, Douglas

    2007-05-01

    A number of oxygenated compounds (oxygenates) are available for use in gasoline to reduce vehicle exhaust emissions, reduce the aromatic compound content, and avoid the use of organo-lead compounds, while maintaining high octane numbers. Ethyl tertiary-butyl ether (ETBE) is one such compound. The current use of ETBE in gasoline or petrol is modest but increasing, with consequently similar trends in the potential for human exposure. Inhalation is the most likely mode of exposure, with about 30% of inhaled ETBE being retained by the lungs and distributed around the body. Following cessation of exposure, the blood concentration of ETBE falls rapidly, largely as a result of its metabolism to tertiary-butyl alcohol (TBA) and acetaldehyde. TBA may be further metabolized, first to 2-methyl-1,2-propanediol and then to 2-hydroxyisobutyrate, the two dominant metabolites found in urine of volunteers and rats. The rapid oxidation of acetaldehyde suggests that its blood concentration is unlikely to rise above normal as a result of human exposure to sources of ETBE. Single-dose toxicity tests show that ETBE has low toxicity and is essentially nonirritant to eyes and skin; it did not cause sensitization in a maximization test in guinea pigs. Neurological effects have been observed only at very high exposure concentrations. There is evidence for an effect of ETBE on the kidney of rats. Increases in kidney weight were seen in both sexes, but protein droplet accumulation (with alpha(2u)-globulin involvement) and sustained increases in cell proliferation occurred only in males. In liver, centrilobular necrosis was induced in mice, but not rats, after exposure by inhalation, although this lesion was reported in some rats exposed to very high oral doses of ETBE. The proportion of liver cells engaged in S-phase DNA synthesis was increased in mice of both sexes exposed by inhalation. ETBE has no specific effects on reproduction, development, or genetic material. Carcinogenicity studies

  20. Assessment of job satisfaction among health workers in a tertiary ...

    African Journals Online (AJOL)

    Assessment of job satisfaction among health workers in a tertiary hospital in Zaria ... factors affecting job satisfaction and retention of health professionals working in ... help the hospital management to increase their employee's job satisfaction.

  1. Oro-Dental and Maxillofacial Trauma in Epilepsy at a Tertiary ...

    African Journals Online (AJOL)

    Oro-Dental and Maxillofacial Trauma in Epilepsy at a Tertiary Hospital in Lagos. ... Information sought included patient's sociodemographics, type of seizure, ... bones were not so common, all such cases received surgical treatment in hospital.

  2. Thermodynamics and kinetics of RNA tertiary structure formation in the junctionless hairpin ribozyme.

    Science.gov (United States)

    White, Neil A; Hoogstraten, Charles G

    2017-09-01

    The hairpin ribozyme consists of two RNA internal loops that interact to form the catalytically active structure. This docking transition is a rare example of intermolecular formation of RNA tertiary structure without coupling to helix annealing. We have used temperature-dependent surface plasmon resonance (SPR) to characterize the thermodynamics and kinetics of RNA tertiary structure formation for the junctionless form of the ribozyme, in which loops A and B reside on separate molecules. We find docking to be strongly enthalpy-driven and to be accompanied by substantial activation barriers for association and dissociation, consistent with the structural reorganization of both internal loops upon complex formation. Comparisons with the parallel analysis of a ribozyme variant carrying a 2'-O-methyl modification at the self-cleavage site and with published data in other systems reveal a surprising diversity of thermodynamic signatures, emphasizing the delicate balance of contributions to the free energy of formation of RNA tertiary structure. Copyright © 2017 Elsevier B.V. All rights reserved.

  3. Antibiotic use in acute pancreatitis: An audit of current practice in a tertiary centre.

    Science.gov (United States)

    Baltatzis, Minas; Mason, J M; Chandrabalan, Vishnu; Stathakis, Panagiotis; McIntyre, Ben; Jegatheeswaran, Santhalingam; Jamdar, Saurabh; O'Reilly, Derek A; Siriwardena, Ajith K

    Intravenous antibiotic prophylaxis is not recommended in acute pancreatitis. According to current international guidelines antibiotics together with further intervention should be considered in the setting of infected necrosis. Appropriate antibiotic therapy particularly avoiding over-prescription is important. This study examines antibiotic use in acute pancreatitis in a tertiary centre using the current IAP/APA guidelines for reference. Data were collected on a consecutive series of patients admitted with acute pancreatitis over a 12 month period. Data were dichotomized by patients admitted directly to the centre and tertiary transfers. Information was collected on clinical course with specific reference to antibiotic use, episode severity, intervention and outcome. 111 consecutive episodes of acute pancreatitis constitute the reported population. 31 (28%) were tertiary transfers. Overall 65 (58.5%) patients received antibiotics. Significantly more tertiary transfer patients received antibiotics. Mean person-days of antibiotic use was 23.9 (sd 29.7) days in the overall study group but there was significantly more use in the tertiary transfer group as compared to patients having their index admission to the centre (40.9 sd 37.1 vs 10.2 sd 8.9; P < 0.005). Thirty four (44%) of patients with clinically mild acute pancreatitis received antibiotics. There is substantial use of antibiotics in acute pancreatitis, in particular in patients with severe disease. Over-use is seen in mild acute pancreatitis. Better consideration must be given to identification of prophylaxis or therapy as indication. In relation to repeated courses of antibiotics in severe disease there must be clear indications for use. Copyright © 2016 IAP and EPC. Published by Elsevier B.V. All rights reserved.

  4. Stability of fine-grained TT-OSL and post-IR IRSL signals from a c. 1 Ma sequence of aeolian and lacustrine deposits from the Nihewan Basin (northern China)

    DEFF Research Database (Denmark)

    Liu, Jinfeng; Murray, Andrew Sean; Buylaert, Jan-Pieter

    2016-01-01

    We tested the suitability of the fine-grained quartz (4–11 μm) Optical Stimulated Luminescence (OSL) and thermally-transferred OSL (TT-OSL), and the fine-grained polymineral (4–11 μm) post-infrared IRSL (post-IR IRSL or pIRIR) signals for dating samples from aeolian-lacustrine deposits from...... accurate ones; nevertheless, these ages provide the first long series absolute chronology for study of local palaeolithic and geomorphic evolution history aside from the  magnetostratigraphical results available before this research....

  5. TRIGENERATION - A highly energy efficient source for heating, domestic hot water preparation, electricity and air cooling systems for tertiary sector

    International Nuclear Information System (INIS)

    Barbuta, Mariana; Ghitulescu, Mircea; Nicolau, Irina; Athanasovici, Cristian; Constantin, Cristinel; Ivan, Robert

    2004-01-01

    The general concerns relating to sustainable energy development have led to the implementation of certain solutions at the international level that have increased both energy generation and energy consuming processes efficiency. In our country the first steps in this direction have been carried out by the private companies that, after having analyzed the income increase and costs diminishing, have come to the conclusion that a reliable way to save money would be the rational use of the energy resources for utilities. A favorable consequence was the synergetic effect of the measures meant to increase energy efficiency for the energy generation and consumption processes that are also accompanied by benefit effects on the environmental impact by reduction CO 2 emissions. One of the solutions making the utmost of primary energy is the combined heat and power production (co-generation) that has significantly developed in our country within the energy sector as a whole. Co-generation may be considered environmentally friendly because it saves fuel on the one hand and, technologically, generates less emissions as compared to the separate generation of heat and power, on the other hand. The most favorable applications of co-generation at a medium and small scale are in the tertiary sector (hotels, hospitals, and office buildings) where heat consumption is usually high enough and is accompanied by relatively constant electricity consumption. By corroborating the above mentioned facts relating to local cogeneration installation utilization with those relating to the increased need for cooling in the tertiary buildings, a concept named 'TRI-GENERATION' in specialized literature has occurred, representing, in fact, utilization of cogeneration installations for supplying energy to the electricity, heat and cold consumer. Thus, the cogeneration installation utilization time will be practically prolonged over the entire duration of a year a fact that has extremely favorable

  6. Drug Production in Tertiary Health Institutions – Needs, Constraints ...

    African Journals Online (AJOL)

    The use of questionnaires was employed in the study covering all pharmacists in the pharmaceutical services department, pharmacy technicians and quality control technologist in the drug production unit of the hospital. It was unanimously agreed by the respondents that local drug production was necessary in tertiary ...

  7. Sexual behaviours of undergraduates of tertiary institutions in Kwara ...

    African Journals Online (AJOL)

    The study also examined whether or not variables of gender and school type had significant influence on the sexual behaviours of undergraduates of tertiary ... the school counsellors and teachers should provide guidance to students on developmental challenges and help youths to abstain from risky sexual behaviours.

  8. Patient satisfaction in neurological second opinions and tertiary referrals

    NARCIS (Netherlands)

    Wijers, D.; Wieske, L.; Vergouwen, M. D. I.; Richard, E.; Stam, J.; Smets, E. M. A.

    2010-01-01

    Although the number of neurological second opinions (SOs) and tertiary referrals (TRs) is increasing, only little is known about expectations and patient satisfaction in this group of patients. Therefore, the purpose of this study was to explore expectations of patients who get a neurological SO or

  9. Factors affecting utilization of University health services in a tertiary ...

    African Journals Online (AJOL)

    2013-01-16

    Jan 16, 2013 ... Objective: To determine students' perception of health care services provided in a tertiary institution and ... evaluation of health services utilization among students in the .... African culture and health. ... Asian Am Pac Isl J.

  10. THE EFFECTIVENESS OF ONLINE AND OFF LINE WORD OF MOUTH MESSAGES ON TRADITIONAL COURSE CHOICE AT TERTIARY LEVEL

    Directory of Open Access Journals (Sweden)

    N. Serdar SEVER

    2009-01-01

    Full Text Available This study aims to explain how bachelor of communications students who are enrolled to various courses at Anadolu University value word-of-mouth messages in making a course decision. Use of WOM as a marketing tool in tertiary teaching is not a common practice. As elective course numbers increase, students look for alternative avenues and types of information to be sure of making the best possible course selection. The findings of this study indicate that instructors’ previous experiences are not as important as their in-class performances. Another interesting finding of the study is although participants are prone to use internet resources as sources of information; they value the use of computer-mediated and enhanced technologies in teaching. Perhaps the most peculiar finding of the study is senior students are perceived as the most common source of information, and their experiences often seen as a point of reference in choosing a course.

  11. Effect of health education on knowledge and attitude of tertiary ...

    African Journals Online (AJOL)

    Background: In order to make good decisions about their sexual and ... of health education on the knowledge and attitude of tertiary school students towards sexually ... Methods: The study employed a quasi-experimental study design in which ...

  12. Why Do Tertiary Education Graduates Regret Their Study Program? A Comparison between Spain and the Netherlands

    Science.gov (United States)

    Kucel, Aleksander; Vilalta-Bufi, Montserrat

    2013-01-01

    In this paper we investigate the determinants of regret of study program for tertiary education graduates in Spain and the Netherlands. These two countries differ in their educational system in terms of the tracking structure in their secondary education and the strength of their education-labor market linkages in tertiary education. Therefore, by…

  13. A sequence of events across the Cretaceous-Tertiary boundary

    NARCIS (Netherlands)

    Smit, J.; Romein, A.J.T.

    1985-01-01

    The lithological and biological sequence of events across the Cretaceous-Tertiary (K/T), as developed in thick and complete landbased sections and termed the standard K/T event sequence, is also found in many DSDP cores from all over the globe. Microtektite-like spherules have been found in

  14. Utilization of Antihypertensive Drugs: A Comparison of Tertiary and ...

    African Journals Online (AJOL)

    To compare the quality of antihypertensive prescriptions at 2 different health care levels in a hypertensive Nigerian population.We carried out a retrospective comparative analysis of the quality and pattern of antihypertensive and low-dose aspirin prescription in a tertiary and two secondary health care institutions providing ...

  15. Improving listening skills of tertiary level students for effective ...

    African Journals Online (AJOL)

    Listening is essential to the leaming process. Students in tertiary institutions of learning need to acquire effective listening and note-taking skiils in order to benefit from lectures. This paper focused on factors militating against effective listening during lectures such as poor rate of presentation, poor communication skills, ...

  16. Mudflow utilization for construction materials of tertiary irrigation canal lining

    Science.gov (United States)

    Azis, Subandiyah; Kustamar

    2017-11-01

    Mudflow in Siring Village, Sidoarjo Regency, Indonesia, has been in eruption since May 29, 2006. It still shows irregular large bursts which loaded in a sludge reservoir with capacity of 59 million m3. From 2007 until 2015, there were more than 20 studies which concluded that the mudflow could be used as a mixture of building materials. However, the studies were not detailed and needed further research. This research aims to investigate the use of mudflow as tertiary irrigation canal lining material. This research comes with several laboratory tests to obtain a mixture that is solid and water-resistant. The methods that were used are descriptive methods as follows: 1). Sampling of mudflow, to be analyzed in Material Testing Laboratory. 2). Sampling of soil at research site, to be analyzed in Soil Mechanics Laboratory 3). Mixing of materials which are consist of mudflow and other materials and doing strength test in the laboratory. 4). Installation of tertiary irrigation canal lining using materials that have been tested. 5). Observation of lining's strength inactive soil pressure-bearing and its impermeability. It is expected that the results of this research will be applied extensively throughout the tertiary irrigation canals, so mudflow can be utilized as raw materials that are environmentally friendly, which are able to help preserving the environment, also to reduce the removal of sand / rock in the river, which has been used for lining materials, that benefits in preventing damage to the river ecosystem.

  17. Employees' Assessment Of Customer Focus In A Tertiary Hospital In ...

    African Journals Online (AJOL)

    Employees' Assessment Of Customer Focus In A Tertiary Hospital In ... tool 'Are we making progress?' were used by respondents to rate customer focus. ... that they were allowed to take decisions to solve problems for customers (p < 0.001).

  18. The roles of tertiary amine structure, background organic matter and chloramine species on NDMA formation.

    Science.gov (United States)

    Selbes, Meric; Kim, Daekyun; Ates, Nuray; Karanfil, Tanju

    2013-02-01

    N-nitrosodimethylamine (NDMA), a probable human carcinogen, is a disinfection by-product that has been detected in chloraminated and chlorinated drinking waters and wastewaters. Formation mechanisms and precursors of NDMA are still not well understood. The main objectives of this study were to systematically investigate (i) the effect of tertiary amine structure, (ii) the effect of background natural organic matter (NOM), and (iii) the roles of mono vs. dichloramine species on the NDMA formation. Dimethylamine (DMA) and 20 different tertiary aliphatic and aromatic amines were carefully examined based on their functional groups attached to the basic DMA structure. The wide range (0.02-83.9%) of observed NDMA yields indicated the importance of the structure of tertiary amines, and both stability and electron distribution of the leaving group of tertiary amines on NDMA formation. DMA associated with branched alkyl groups or benzyl like structures having only one carbon between the ring and DMA structure consistently gave higher NDMA yields. Compounds with electron withdrawing groups (EWG) reacted preferentially with monochloramine, whereas compounds with electron donating group (EDG) showed tendency to react with dichloramine to form NDMA. When the selected amines were present in NOM solutions, NDMA formation increased for compounds with EWG while decreased for compounds with EDG. This impact was attributed to the competitions between NOM and amines for chloramine species. The results provided additional information to the commonly accepted mechanism for NDMA formation including chloramine species reacting with tertiary amines and the role of the leaving group on overall NDMA conversion. Copyright © 2012 Elsevier Ltd. All rights reserved.

  19. Study on tertiary in-situ leachable uranium mineralization conditions in South Songliao basin

    International Nuclear Information System (INIS)

    Zhang Zhenqiang; Li Guokuan; Zhao Zonghua; Zhang Jingxun

    2001-01-01

    Tertiary in-situ leachable mineralization in Songliao Basin was analyzed in theory in the past. Since 1998, regional investigation at 1:200000 scale has been done with about 120 holes drilled. Based on drill holes recording, section compiling and sample analysis, the authors investigate into the Tertiary in-situ leachable conditions including rock character, sedimentary facies, rock chemistry, organic substances, uranium content, sandstone porosity, sandstone bodies, interlayer oxidation, and hydro-dynamic value. The study would play important role in prospecting for in-situ leachable uranium in South Songliao basin

  20. Patient satisfaction in outpatient healthcare services at secondary level vs. tertiary level

    Directory of Open Access Journals (Sweden)

    Velikj-Stefanovska Vesna

    2014-01-01

    Full Text Available Introduction. Patients satisfaction is a very important part of any clinical practice both for evaluation and improvement of healthcare services. Objective. The aim of this study was to determine patient satisfaction with public outpatient healthcare services at secondary and tertiary level and to assess possible differences between the two levels. Methods. In a quantitative cross-sectional study, a convenient sample of 646 patients who experienced public outpatient healthcare services at the secondary and tertiary level during the last two months were interviewed. Patient satisfaction questionnaires, with statements regarding various aspects of satisfaction, were completed during face-to-face interviews (response rate 84.6%. The research instrument was tested for internal consistency using the Cronbach’s coefficient alpha estimate. Results. The patients were significantly more satisfied in tertiary than in secondary outpatient healthcare facilities in almost all aspects of assessment related to general settings, nurse/administrative staff performance and physician performance (p<0.001. The patients in the secondary healthcare services (SHCS were more satisfied than in the tertiary healthcare services (THCS but only regarding the information on location (83.9% vs.78.3% and possibilities to enter and move inside the department (88.8% vs. 83.3%. Analysis of data for SHCS and THCS showed that there was no significant difference between the mean overall satisfaction scores with regard to patients’ gender, age, marital status, educational level, employment and number of visits. Conclusion. There is a need to improve the current level of patient-provider relationship and communication, as well as that of hospital environment, while special efforts should be made to address the problem of patient waiting time and hospital bureaucracy.

  1. Entrepreneurship Education in Delta State Tertiary Institution as a Means of Achieving National Growth and Development

    Science.gov (United States)

    Osakwe, Regina N.

    2015-01-01

    This study examined entrepreneurship education in Delta Sate tertiary institutions as a means of national growth and development. Two research questions were asked to guide the study. The population comprised all the 1,898 academic staff in eight tertiary institutions in the state. A sample of 800 lecturers was drawn through the multi stage and…

  2. A Comparison of Teacher and Lecturer Perspectives on the Transition from Secondary to Tertiary Mathematics Education

    Science.gov (United States)

    Hong, Ye Yoon; Kerr, Suzanne; Klymchuk, Sergiy; McHardy, Johanna; Murphy, Priscilla; Spencer, Sue; Thomas, Michael O. J.; Watson, Peter

    2009-01-01

    The transition from school to tertiary study of mathematics comes under increasing scrutiny in research. This article reports on some findings from a project analysing the transition from secondary to tertiary education in mathematics. One key variable in this transition is the teacher or lecturer. This article deals with a small part of the data…

  3. The Index to Marine and Lacustrine Geological Samples: Improving Sample Accessibility and Enabling Current and Future Research

    Science.gov (United States)

    Moore, C.

    2011-12-01

    The Index to Marine and Lacustrine Geological Samples is a community designed and maintained resource enabling researchers to locate and request sea floor and lakebed geologic samples archived by partner institutions. Conceived in the dawn of the digital age by representatives from U.S. academic and government marine core repositories and the NOAA National Geophysical Data Center (NGDC) at a 1977 meeting convened by the National Science Foundation (NSF), the Index is based on core concepts of community oversight, common vocabularies, consistent metadata and a shared interface. Form and content of underlying vocabularies and metadata continue to evolve according to the needs of the community, as do supporting technologies and access methodologies. The Curators Consortium, now international in scope, meets at partner institutions biennially to share ideas and discuss best practices. NGDC serves the group by providing database access and maintenance, a list server, digitizing support and long-term archival of sample metadata, data and imagery. Over three decades, participating curators have performed the herculean task of creating and contributing metadata for over 195,000 sea floor and lakebed cores, grabs, and dredges archived in their collections. Some partners use the Index for primary web access to their collections while others use it to increase exposure of more in-depth institutional systems. The Index is currently a geospatially-enabled relational database, publicly accessible via Web Feature and Web Map Services, and text- and ArcGIS map-based web interfaces. To provide as much knowledge as possible about each sample, the Index includes curatorial contact information and links to related data, information and images; 1) at participating institutions, 2) in the NGDC archive, and 3) at sites such as the Rolling Deck to Repository (R2R) and the System for Earth Sample Registration (SESAR). Over 34,000 International GeoSample Numbers (IGSNs) linking to SESAR are

  4. Dynamic response of tertiary systems in structures subjected to base excitation

    International Nuclear Information System (INIS)

    Hernried, A.G.; Kai-sing Lau

    1988-01-01

    The dynamic response of very lightweight equipment (tertiary subsystem) attached to light equipment (secondary subsystem) which in turn is attached to a heavier structure (primary subsystem) that is subjected to ground shock or earthquake excitation is investigated. Both the single-degree-of-freedom and multi-degree-of-freedom subsystem models are considered. The systems are damped as well as undamped, completely detuned (all natural frequencies of the subsystems well spaced), singly tuned (one natural frequency of each subsystem equal or close to one another), or multiply tuned (more than one natural frequency of the subsystems close to each other). Efficient techniques for the determination of the tertiary subsystem response that avoid a computationally intensive numerical integration of the combined system equations are presented. (author)

  5. Sexual Harassment in Tertiary Science: Implications for Gender Equity

    African Journals Online (AJOL)

    The paper focuses on the incidence of sexual harassment in tertiary science education and its attendant effects on students and academics. Data from a survey of six higher institutions comprising two universities, two colleges of education and two polytechnics was used. Results indicate high rate of sexual harassment of ...

  6. Effectiveness of Using Games in Tertiary-Level Mathematics Classrooms

    Science.gov (United States)

    Afari, Ernest; Aldridge, Jill M.; Fraser, Barry J.

    2012-01-01

    The primary focus of this study was to investigate the effectiveness of games when used in tertiary-level mathematics classes in the United Arab Emirates. Our study incorporated a mixed-method approach that involved surveys (to assess students' perceptions of the learning environment and attitudes towards mathematics), interviews, observations of…

  7. Automated Stock Control System for Bookshops in Tertiary Institutions

    African Journals Online (AJOL)

    The recent need for automated stock control system for bookshops in tertiary institutions was generated by unequal availability of books and stiff scarcity of books in some areas while in ... This approach provides for faster response times for users because the database is local to each business unit within the organization.

  8. Assessing Readiness for Integration of Electronic Learning into Business Education Programmes in Tertiary Institutions in Ebonyi State

    Science.gov (United States)

    Nwagwu, Lazarus; Azih, Nonye

    2015-01-01

    The study was conducted to assess readiness for integration of electronic learning into business education programmes in tertiary institutions in Ebonyi State. Two research questions and two hypotheses guided the study. The population was 37 business education lecturers and 748 Business Education Students in tertiary institutions that offer…

  9. Tentorial and dural calcification with tertiary hyperparathyroidism: a rare entity in chronic renal failure

    International Nuclear Information System (INIS)

    Dorenbeck, U.; Bretschneider, T.; Feuerbach, S.; Leingaertner, T.; Kraemer, B.K.

    2002-01-01

    A case of rare calcification of the tentorium cerebelli, the thoracal dura mater of the spine, and the sclera in an adult male patient with tertiary hyperparathyroidism is presented. The often reported feature in the skull is that of a combination of osteopenia and osteosclerosis giving a granular bone texture. Extensive dura calcification with this condition has very rarely been reported. It is the aim of this paper to document the latter in a patient with chronic renal failure and tertiary hyperparathyroidism. (orig.)

  10. Frequency of different valvular lesions of rheumatic heart disease presenting to a tertiary care hospital

    International Nuclear Information System (INIS)

    Rehman, J.U.; Shah, I.

    2015-01-01

    Rheumatic Hearth Disease (RHD) is still prevalent in our country and a great source of morbidity. This study was done with an objective to determine relative frequency of different valvular lesions of RHD presenting in a tertiary care hospital. Methods: This cross sectional study was conducted at the Cardiology Department of Hayatabad Medical Complex, Peshawar. A total of 171 cases of RHD were included through consecutive sampling technique. Results: There were 64.33% females. Mean age was 25.6 ± 6.95 years ranging from 15 to 40 years. The different percentage of valvular lesions in RHD were MR (59.06%), MS (46.78%), AR (43.85%) and mixed lesions (38.59%). Conclusion: Rheumatic heart disease is a very common disease in our community and mitral regurgitation is a predominant lesion at presentation. Females are usually affected more than males. (author)

  11. Sexual harassment in tertiary institutions: A comparative perspective

    OpenAIRE

    Joseph Janice

    2015-01-01

    Sexual harassment is not a new phenomenon in tertiary institutions. It has been receiving considerable attention in research and the media and public awareness has increased dramatically. However, the term sexual harassment is not used uniformly across the globe because countries have defined it differently. Consequently, prevalence of sexual harassment in education varies across cultures. This paper examines sexual harassment from a comparative perspective...

  12. Food Insecurity: Is It an Issue among Tertiary Students?

    Science.gov (United States)

    Gallegos, Danielle; Ramsey, Rebecca; Ong, Kai Wen

    2014-01-01

    Insufficient access to food is known to compromise tertiary studies. Students often belong to groups known to have poor food security such as those renting or relying on government payments. The present study administered a cross-sectional survey incorporating the USDA food security survey module (FSSM) to 810 students at a metropolitan university…

  13. Motivation in vocational education: a reform issue in tertiary ...

    African Journals Online (AJOL)

    Working in a non-motivating environment is a nagging issue in various tertiary institutions in Cross River State .This dampens staff morale a great deal. However, the provision of motivation in work places will be a great boost to staff morale especially in Vocational Education. This paper discusses the meaning of motivation, ...

  14. Financial impact of tertiary care in an academic medical center.

    Science.gov (United States)

    Huber, T S; Carlton, L M; O'Hern, D G; Hardt, N S; Keith Ozaki, C; Flynn, T C; Seeger, J M

    2000-06-01

    To analyze the financial impact of three complex vascular surgical procedures to both an academic hospital and a department of surgery and to examine the potential impact of decreased reimbursements. The cost of providing tertiary care has been implicated as one potential cause of the financial difficulties affecting academic medical centers. Patients undergoing revascularization for chronic mesenteric ischemia, elective thoracoabdominal aortic aneurysm repair, and treatment of infected aortic grafts at the University of Florida were compared with those undergoing elective infrarenal aortic reconstruction and carotid endarterectomy. Hospital costs and profit summaries were obtained from the Clinical Resource Management Office. Departmental costs and profit summary were estimated based on the procedural relative value units (RVUs), the average clinical cost per RVU ($33.12), surgeon charges, and the collection rate for the vascular surgery division (30.2%) obtained from the Faculty Group Practice. Surgeon work effort was analyzed using the procedural work RVUs and the estimated total care time. The analyses were performed for all payors and the subset of Medicare patients, and the potential impact of a 15% reduction in hospital and physician reimbursement was analyzed. Net hospital income was positive for all but one of the tertiary care procedures, but net losses were sustained by the hospital for the mesenteric ischemia and infected aortic graft groups among the Medicare patients. In contrast, the estimated reimbursement to the department of surgery for all payors was insufficient to offset the clinical cost of providing the RVUs for all procedures, and the estimated losses were greater for the Medicare patients alone. The surgeon work effort was dramatically higher for the tertiary care procedures, whereas the reimbursement per work effort was lower. A 15% reduction in reimbursement would result in an estimated net loss to the hospital for each of the tertiary

  15. Heavy metal and trace elements in riparian vegetation and macrophytes associated with lacustrine systems in Northern Patagonia Andean Range.

    Science.gov (United States)

    Juárez, Andrea; Arribére, María A; Arcagni, Marina; Williams, Natalia; Rizzo, Andrea; Ribeiro Guevara, Sergio

    2016-09-01

    Vegetation associated with lacustrine systems in Northern Patagonia was studied for heavy metal and trace element contents, regarding their elemental contribution to these aquatic ecosystems. The research focused on native species and exotic vascular plant Salix spp. potential for absorbing heavy metals and trace elements. The native species studied were riparian Amomyrtus luma, Austrocedrus chilensis, Chusquea culeou, Desfontainia fulgens, Escallonia rubra, Gaultheria mucronata, Lomatia hirsuta, Luma apiculata, Maytenus boaria, Myrceugenia exsucca, Nothofagus antarctica, Nothofagus dombeyi, Schinus patagonicus, and Weinmannia trichosperma, and macrophytes Hydrocotyle chamaemorus, Isöetes chubutiana, Galium sp., Myriophyllum quitense, Nitella sp. (algae), Potamogeton linguatus, Ranunculus sp., and Schoenoplectus californicus. Fresh leaves were analyzed as well as leaves decomposing within the aquatic bodies, collected from lakes Futalaufquen and Rivadavia (Los Alerces National Park), and lakes Moreno and Nahuel Huapi (Nahuel Huapi National Park). The elements studied were heavy metals Ag, As, Cd, Hg, and U, major elements Ca, K, and Fe, and trace elements Ba, Br, Co, Cr, Cs, Hf, Na, Rb, Se, Sr, and Zn. Geochemical tracers La and Sm were also determined to evaluate contamination of the biological tissues by geological particulate (sediment, soil, dust) and to implement concentration corrections.

  16. Time Management and Administrative Effectiveness of Kwara State Tertiary Institutions, Nigeria

    Directory of Open Access Journals (Sweden)

    Olasunkanmi Muftau AFOLABI

    2015-02-01

    Full Text Available This study investigated the relationship between time management and administrative effectiveness of Kwara State owned tertiary institutions. The study adopted a descriptive survey of correlational type. Stratified random sampling technique was adopted to select 600 respondents from the sampled institutions. The respondents selected are deans, directors, head of departments, senior lecturers, lecturers, head of the units, class representatives and student’s government executives and the Associations Presidents, secretaries and treasurers. Four research questions and four research hypotheses were generated to guide the study. The instruments staged Time Management for Administrative Effectiveness Questionnaire (TMADEQ was researcher’s self designed instrument. The instrument was validated by the experts in Educational management and psychology. Reliability index of .65 was obtained after subjecting to test-retest method, and using Spearman Ranking order Statistics at .05 significance level. All the research questions were answered using percentages while, Pearson product moment correlation statistics was used to test all the research hypotheses formulated also at .05 significance level. The findings however showed that time allocation, utilization commitment and lapses have high positive significant relationship with the indicators of the administrative effectiveness of Kwara State tertiary institutions. Recommendations was however made that time management skills should be taught as a course in the higher institutions so as to enhance administrative effectiveness in the tertiary institutions and that adequate time should be allocated to every institutional programmes.

  17. Teaching Design in Adolescent Environments: Twinning Secondary and Tertiary Learning Experiences

    Directory of Open Access Journals (Sweden)

    David Jones

    2004-06-01

    Full Text Available Increasingly our landscape architecture teaching and educational pedagogies are facing an internationalisation in approach and expectation. We are positioned within a tertiary learning layer in a tripartite educational system for which each layer assumes certain expectations and outcomes. But their vertical linkages are unclear, and we incorrectly assume continuity of knowledge and skill learning strategies. It is a horizontally stratified teaching setting that we have to work within and while we can think of internationalisation as occurring within our level we need to appreciate that internationalisation is also occurring at the secondary level. This paper discusses the educational environment within which globalisation is occurring, and reviews a project model that builds bridges vertically between secondary and tertiary learning environments. The project displays possibilities in both secondary and tertiary educational sectors, but especially in enhancing and improving the design fluency of our annual incoming cohorts who often possess a naive understanding of built environmental design. Commencing in 1998 as an experimental project, it has been recognised at the South Australian state level as a forward-thinking initiative that has radically transformed secondary school Design teacher's perspectives as to educational possibilities, and substantially matured attitudes to landscape design by both suites of participants. As a consequence, it is an educational project that has experienced requests from numerous secondary schools around the State to participate.

  18. Extraterrestrial cause for the Cretaceous-Tertiary extinction

    International Nuclear Information System (INIS)

    Alvarez, L.W.; Alvarez, W.; Asaro, F.; Michel, H.V.

    1980-01-01

    Platinum metals are depleted in the earth's crust relative to their cosmic abundance; concentrations of these elements in deep-sea sediments may thus indicate influxes of extraterrestrial material. Deep-sea limestones exposed in Italy, Denmark, and New Zealand show iridium increases of about 30, 160, and 20 times, respectively, above the background level at precisely the time of the Cretaceous-Tertiary extinctions, 65 million years ago. Reasons are given to indicate that this iridium is of extraterrestrial origin, but did not come from a nearby supernova. A hypothesis is suggested which accounts for the extinctions and the iridium observations. Impact of a large earth-crossing asteroid would inject about 60 times the object's mass into the atmosphere as pulverized rock; a fraction of this dust would stay in the stratosphere for several years and be distributed worldwide. The resulting darkness would suppress photosynthesis, and the expected biological consequences match quite closely the extinctions observed in the paleontological record. One prediction of this hypothesis has been verified: the chemical composition of the boundary clay, which is thought to come from the stratospheric dust, is markedly different from that of clay mixed with the Cretaceous and Tertiary limestones, which are chemically similar to each other. Four different independent estimates of the diameter of the asteroid give values that lie in the range 10 +- 4 kilometers

  19. Accountability of Tertiary Education at the National Level: A Chimera?

    Science.gov (United States)

    Lindsay, Alan; O'Byrne, Garry

    1979-01-01

    The concept of accountability and its application to Australian higher education are discussed. It is suggested that due to political, financial, and educational characteristics of tertiary education at the national system level there are fundamental and insoluble problems associated with achieving accountability. (SF)

  20. Accessibility of tertiary hospitals in Finland: A comparison of administrative and normative catchment areas.

    Science.gov (United States)

    Huotari, Tiina; Antikainen, Harri; Keistinen, Timo; Rusanen, Jarmo

    2017-06-01

    The determination of an appropriate catchment area for a hospital providing highly specialized (i.e. tertiary) health care is typically a trade-off between ensuring adequate client volumes and maintaining reasonable accessibility for all potential clients. This may pose considerable challenges, especially in sparsely inhabited regions. In Finland, tertiary health care is concentrated in five university hospitals, which provide services in their dedicated catchment areas. This study utilizes Geographic Information Systems (GIS), together with grid-based population data and travel-time estimates, to assess the spatial accessibility of these hospitals. The current geographical configuration of the hospitals is compared to a normative assignment, with and without capacity constraints. The aim is to define optimal catchment areas for tertiary hospitals so that their spatial accessibility is as equal as possible. The results indicate that relatively modest improvements can be achieved in accessibility by using normative assignment to determine catchment areas. Copyright © 2017 Elsevier Ltd. All rights reserved.

  1. Tertiary Institutions, Entrepreneurship Education and Youth Empowerment in Nigeria

    Science.gov (United States)

    Olasunkanmi, Abari Ayodeji; Olufunke, Oyetola Idowu; Adetayo, Okunuga Adedapo

    2013-01-01

    Entrepreneurship Education has recently become a global phenomenon in the development of world youths for self employment and self-reliance. The Nigerian nation cannot afford to be left out and left behind in this new trend in education both at the secondary and tertiary levels. However, while the Universal Basic Education (UBE) curriculum has…

  2. Epidemiology of paediatric poisoning reporting to a tertiary hospital ...

    African Journals Online (AJOL)

    Methods. We conducted a retrospective study from January 2007 to January 2012 at the Komfo Anokye Teaching Hospital, a tertiary hospital in Ghana. Results. Poisoning is a significant health problem in the study area. A total of 253 children reported to the hospital with poisoning over the 61month period, with an average ...

  3. COMPARATIVE STUDY OF TERTIARY WASTEWATER TREATMENT BY COMPUTER SIMULATION

    Directory of Open Access Journals (Sweden)

    Stefania Iordache

    2010-01-01

    Full Text Available The aim of this work is to asses conditions for implementation of a Biological Nutrient Removal (BNR process in theWastewater Treatment Plant (WWTP of Moreni city (Romania. In order to meet the more increased environmentalregulations, the wastewater treatment plant that was studied, must update the actual treatment process and have tomodernize it. A comparative study was undertaken of the quality of effluents that could be obtained by implementationof biological nutrient removal process like A2/O (Anaerobic/Anoxic/Oxic and VIP (Virginia Plant Initiative aswastewater tertiary treatments. In order to asses the efficiency of the proposed treatment schemata based on the datamonitored at the studied WWTP, it were realized computer models of biological nutrient removal configurations basedon A2/O and VIP process. Computer simulation was realized using a well-known simulator, BioWin by EnviroSimAssociates Ltd. The simulation process allowed to obtain some data that can be used in design of a tertiary treatmentstage at Moreni WWTP, in order to increase the efficiency in operation.

  4. Wage Inequalities: A Result of Different Levels and Fields of Tertiary Education?

    Directory of Open Access Journals (Sweden)

    Darjan Petek

    2017-03-01

    Full Text Available In this article we examine the impact of tertiary education on the amounts of wages in Slovenia for 2011. We use micro data from the statistical survey Structure of Earnings Statistics and micro data from the survey of graduates from tertiary education. We found out that there are significant differences in the amounts of wages as regards the level and field of education. Region and activity of the company where the person is employed also plays an important role in wage determination. Also the effects of gender and public/private sector are statistically significant. Using the average wage per hour as dependent variable gives similar results as the average annual wages.

  5. Ectopic pregnancy experience in a tertiary health facility in South ...

    African Journals Online (AJOL)

    Background: Ectopic pregnancy is a life-threatening gynecological emergency, and a significant cause of maternal morbidity and mortality in Nigeria. Objective: To determine the incidence, clinical presentation, risk factors and management outcomes of ectopic pregnancies in a tertiary health facility. Methods: A retrospective ...

  6. 26 CFR 1.193-1 - Deduction for tertiary injectant expenses.

    Science.gov (United States)

    2010-04-01

    ... in which the expenses are paid or incurred. (b) Definitions—(1) Qualified tertiary injectant expenses... Chief Counsel (Technical) for purposes of section 193. (c) Special rules for hydrocarbons—(1) In general. If an injectant contains more than an insignificant amount of recoverable hydrocarbons, the amount...

  7. Induction of secondary and tertiary lymphoid structures in the skin.

    NARCIS (Netherlands)

    Cupedo, T.; Jansen, W.; Kraal, G.; Mebius, R.E.

    2004-01-01

    During embryogenesis a developmental program leading to the formation of lymph nodes and Peyer's patches is initiated. We now show that lymph node-like structures as well as tertiary lymphoid structures can ectopically be induced by intradermal injection of newborn lymph node-derived cells.

  8. Noble metals in cretaceous/tertiary sediments from El Kef

    International Nuclear Information System (INIS)

    Kuslys, M.; Kraehenbuehl, U.

    1983-01-01

    Sediments from El Kef, Tunisia, were analysed by RNAA for Au, Ir and Os. All three elements show a 10-20 fold enrichment at the Cretaceous/Tertiary boundary. This enrichment must be the result of the addition of material with a high concentration of noble metals. It is plausible that this exotic material has an extra-terrestrial origin. (orig.)

  9. Noble metals in Cretaceous/Tertiary sediments from El Kef

    International Nuclear Information System (INIS)

    Kuslys, M.; Kraehenbuehl, U.

    1983-01-01

    Sediments from El Kef, Tunisia, were analysed by RNAA for Au, Ir and Os. All three elements show a 10-20 fold enrichment at the Cretaceous/Tertiary boundary. This enrichment must be the result of the addition of material with a high concentration of noble metals. It is plausible that this exotic material has an extraterrestrial origin. (orig.)

  10. Knowledge, attitude, and infection control practices of two tertiary ...

    African Journals Online (AJOL)

    2014-04-02

    Apr 2, 2014 ... This study assessed the effects of the implementation of the policy in a tertiary hospital in Port Harcourt, ... malpractice suit in developing countries, not only for the ... Infection control policy has however been shown to reduce the burden of ..... SSIs‑activities that mirror the plan‑do‑check‑act that is applied in ...

  11. Counselling for Sustainable Peace in Tertiary Institutions in Nigeria

    Science.gov (United States)

    Nduka-Ozo, Stella Ngozi

    2016-01-01

    This study reviewed the nature of peace in Tertiary Institutions in Nigeria using Ebonyi State University as a case study. The purpose of the study was to review the various factors responsible for lack of peace. The sample was drawn from the three hundred level students of the Faculty of Education. Thirty students were selected from each of the…

  12. The Incidence and Management of Conflicts in Secular and Non-Secular Tertiary Institutions in South West Nigeria

    Science.gov (United States)

    Ayodele, Joseph Babatola; Adewumi, Joseph Olukayode

    2007-01-01

    This paper compared the incidence and management of conflicts in secular and non-secular tertiary institutions in Nigeria. The sample of this study was made of sixty staff, and two hundred and forty students randomly selected each from two secular and two non-secular tertiary institutions in south western Nigeria. A validated questionnaire was…

  13. Impact of tertiary Gleason pattern 5 on prostate cancer aggressiveness: Lessons from a contemporary single institution radical prostatectomy series

    Directory of Open Access Journals (Sweden)

    Zachary B. Koloff

    2015-01-01

    Conclusion: Our results emphasize the importance of TP5 and suggest that criteria for tertiary pattern reporting in prostate cancer should be standardized. Further studies are needed to evaluate the role of tertiary patterns in prognostic models.

  14. Hand hygiene amongst dental professionals in a tertiary dental clinic ...

    African Journals Online (AJOL)

    Objective: To evaluate hand washing attitude and practices among Dentists and Dental Students treating patients in a Nigerian Tertiary Dental Clinic. Materials and Methods: A cross-sectional survey of Dentists and Dental Students treating patients in University of Benin Teaching Hospital was conducted between February ...

  15. An audit of colorectal cancer histopathology reports in a Tertiary ...

    African Journals Online (AJOL)

    Objective: To audit the completeness of histopathologic reports of Colorectal Cancer for prognostic information in a tertiary care hospital in the light of the minimum reporting standards for colorectal cancer resections recently proposed for use in Nigeria. Material and Methods: Twenty–five histopathology reports of colorectal ...

  16. Indications for and outcomes of tertiary referrals in refractive surgery

    NARCIS (Netherlands)

    Patryn, Eliza K.; Vrijman, Violette; Nieuwendaal, Carla P.; van der Meulen, Ivanka J. E.; Mourits, Maarten P.; Lapid-Gortzak, Ruth

    2014-01-01

    To review the spectrum of disease, symptomatology, and management offered to patients referred for a second opinion after refractive surgery. A prospective cohort study was done on all patients referred from October 1, 2006, to September 30, 2011, to a tertiary eye clinic after refractive surgery of

  17. Long-term satisfaction after neurological second opinions and tertiary referrals

    NARCIS (Netherlands)

    Wieske, L.; Richard, E.; Wijers, D.; Stam, J.; Smets, E. M. A.; Vergouwen, M. D. I.

    2011-01-01

    The number of second opinions (SO) and tertiary referrals (TR) in neurology is increasing. Previously, we showed that a day-care admission for neurological SO's and TR's often results in a new diagnosis and/or treatment advice and increases patient satisfaction. However, long-term satisfaction for

  18. Self care activities among patients with diabetes attending a tertiary ...

    African Journals Online (AJOL)

    Self care activities among patients with diabetes attending a tertiary care hospital in Mangalore Karnataka, India. ... Conclusions: Self‑care practices were found to be unsatisfactory in almost all aspects except for blood sugar monitoring and treatment adherence. As these practices are essential for prevention of ...

  19. Depression in pregnancy and the puerperium in a tertiary health ...

    African Journals Online (AJOL)

    BACKGROUND: Depression is common in pregnancy in high-income-countries but rarely spoken about in Nigerian Tertiary Obstetric Centres. OBJECTIVES: This study was conducted to ascertain the prevalence and risk factors for major depression in pregnancy and puerperium at the University of Port Harcourt Teaching ...

  20. Clinical neurophysiology referral patterns to a tertiary hospital--a prospective audit.

    LENUS (Irish Health Repository)

    Renganathan, R

    2012-02-03

    BACKGROUND: Cork University Hospital (CUH) provides a tertiary service for all neurophysiology referrals in the Southern Health Board region. AIM: To ascertain the number, source, symptoms and diagnosis of neurophysiology referrals at CUH. METHODS: We did a prospective audit of the referral patterns to the neurophysiology department over a 12 -week period. RESULTS: Of 635 referrals, 254 had electromyograms (EMG), 359 had electro-encephalograms (EEG), 18 had visual evoked potentials (VEP), three had somato-sensory evoked potentials (SSEP) and one had multiple sleep latency tests (MSLT). We analysed the demographic pattern, reason for referrals, the average waiting time for neurophysiology tests and the patterns of diagnosis in this audit. CONCLUSIONS: Patients from County Cork are making more use of the neurophysiology services than patients from other counties within the Southern Health Board. The average waiting time for an EEG was 32 days and for an EMG was 74 days. However, more than 35% of those patients waiting for an EEG or an EMG had their tests done within four weeks of referral. The appointments of EEG and EMG were assigned on the basis of clinical need.

  1. Measuring case-mix complexity of tertiary care hospitals using DRGs.

    Science.gov (United States)

    Park, Hayoung; Shin, Youngsoo

    2004-02-01

    The objectives of the study were to develop a model that measures and evaluates case-mix complexity of tertiary care hospitals, and to examine the characteristics of such a model. Physician panels defined three classes of case complexity and assigned disease categories represented by Adjacent Diagnosis Related Groups (ADRGs) to one of three case complexity classes. Three types of scores, indicating proportions of inpatients in each case complexity class standardized by the proportions at the national level, were defined to measure the case-mix complexity of a hospital. Discharge information for about 10% of inpatient episodes at 85 hospitals with bed size larger than 400 and their input structure and research and education activity were used to evaluate the case-mix complexity model. Results show its power to predict hospitals with the expected functions of tertiary care hospitals, i.e. resource intensive care, expensive input structure, and high levels of research and education activities.

  2. Synthesis of zinc sulfide by chemical vapor deposition using an organometallic precursor: Di-tertiary-butyl-disulfide

    International Nuclear Information System (INIS)

    Vasekar, Parag; Dhakal, Tara; Ganta, Lakshmikanth; Vanhart, Daniel; Desu, Seshu

    2012-01-01

    Zinc sulfide has gained popularity in the last few years as a cadmium-free heterojunction partner for thin film solar cells and is seen as a good replacement for cadmium sulfide due to better blue photon response and non-toxicity. In this work, zinc sulfide films are prepared using an organic sulfur source. We report a simple and repeatable process for development of zinc sulfide using a cost-effective and less hazardous organic sulfur source. The development of zinc sulfide has been studied on zinc oxide-coated glass where the zinc oxide is converted into zinc sulfide. Zinc oxide grown by atomic layer deposition as well as commercially available zinc oxide-coated glass was used. The zinc sulfide synthesis has been studied and the films are characterized using scanning electron microscopy, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and a UV–VIS spectrophotometer. XRD, XPS and optical characterization confirm the zinc sulfide phase formation. - Highlights: ► Synthesis of ZnS using a less-hazardous precursor, di-tertiary-butyl-disulfide. ► ZnS process optimized for two types of ZnO films. ► Preliminary results for a solar cell show an efficiency of 1.09%.

  3. Tertiary Intratumor Lymphoid Tissue in Colo-Rectal Cancer

    Directory of Open Access Journals (Sweden)

    Federica Marchesi

    2011-12-01

    Full Text Available Ectopic (or tertiary lymphoid tissue develops at sites of inflammation or infection in non lymphoid organs and is associated with chronic inflammation. In colon mucosa, small lymphoid aggregates are already present in homeostatic conditions, as part of the gut-associated lymphoid tissue and play an essential role in the immune response to perturbations of the mucosal microenvironment. Despite the recognized role of inflammation in tumor progression, the presence and biological function of lymphoid tissue in cancer has been poorly investigated. We identified aggregates of lymphocytes resembling tertiary lymphoid tissue in human colorectal cancer specimens; intratumor accumulations of lymphocytes display a high degree of compartmentalization, with B and T cells, mature dendritic cells and a network of CD21+ follicular dendritic cells (FDC. We analyzed the adaptation of colon lymphoid tissue in a murine model of colitis-associated cancer (AOM/DSS. B cell follicle formation increases in the context of the chronic inflammation associated to intestinal neoplasia, in this model. A network of lymphatic and haematic vessels surrounding B cell follicles is present and includes high endothelial venules (HEV. Future task is to determine whether lymphoid tissue contributes to the persistence of the tumor-associated inflammatory reaction, rather than represent a functional immune compartment, potentially participating to the anti tumor response.

  4. Tertiary Intratumor Lymphoid Tissue in Colo-Rectal Cancer

    Energy Technology Data Exchange (ETDEWEB)

    Bergomas, Francesca [Department of Immunology and Inflammation, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Grizzi, Fabio [Laboratory of Molecular Gastroenterology, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Doni, Andrea; Pesce, Samantha [Department of Immunology and Inflammation, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Laghi, Luigi [Laboratory of Molecular Gastroenterology, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Department of Gastroenterology, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Allavena, Paola [Department of Immunology and Inflammation, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Mantovani, Alberto [Department of Immunology and Inflammation, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy); Department of Translational Medicine, University of Milan, Milan 20089 (Italy); Marchesi, Federica, E-mail: federica.marchesi@humanitasresearch.it [Department of Immunology and Inflammation, IRCCS Humanitas Clinical Institute, Via Manzoni 56, 20089 Rozzano, Milan (Italy)

    2011-12-28

    Ectopic (or tertiary) lymphoid tissue develops at sites of inflammation or infection in non lymphoid organs and is associated with chronic inflammation. In colon mucosa, small lymphoid aggregates are already present in homeostatic conditions, as part of the gut-associated lymphoid tissue and play an essential role in the immune response to perturbations of the mucosal microenvironment. Despite the recognized role of inflammation in tumor progression, the presence and biological function of lymphoid tissue in cancer has been poorly investigated. We identified aggregates of lymphocytes resembling tertiary lymphoid tissue in human colorectal cancer specimens; intratumor accumulations of lymphocytes display a high degree of compartmentalization, with B and T cells, mature dendritic cells and a network of CD21{sup +} follicular dendritic cells (FDC). We analyzed the adaptation of colon lymphoid tissue in a murine model of colitis-associated cancer (AOM/DSS). B cell follicle formation increases in the context of the chronic inflammation associated to intestinal neoplasia, in this model. A network of lymphatic and haematic vessels surrounding B cell follicles is present and includes high endothelial venules (HEV). Future task is to determine whether lymphoid tissue contributes to the persistence of the tumor-associated inflammatory reaction, rather than represent a functional immune compartment, potentially participating to the anti tumor response.

  5. Tertiary Intratumor Lymphoid Tissue in Colo-Rectal Cancer

    International Nuclear Information System (INIS)

    Bergomas, Francesca; Grizzi, Fabio; Doni, Andrea; Pesce, Samantha; Laghi, Luigi; Allavena, Paola; Mantovani, Alberto; Marchesi, Federica

    2011-01-01

    Ectopic (or tertiary) lymphoid tissue develops at sites of inflammation or infection in non lymphoid organs and is associated with chronic inflammation. In colon mucosa, small lymphoid aggregates are already present in homeostatic conditions, as part of the gut-associated lymphoid tissue and play an essential role in the immune response to perturbations of the mucosal microenvironment. Despite the recognized role of inflammation in tumor progression, the presence and biological function of lymphoid tissue in cancer has been poorly investigated. We identified aggregates of lymphocytes resembling tertiary lymphoid tissue in human colorectal cancer specimens; intratumor accumulations of lymphocytes display a high degree of compartmentalization, with B and T cells, mature dendritic cells and a network of CD21 + follicular dendritic cells (FDC). We analyzed the adaptation of colon lymphoid tissue in a murine model of colitis-associated cancer (AOM/DSS). B cell follicle formation increases in the context of the chronic inflammation associated to intestinal neoplasia, in this model. A network of lymphatic and haematic vessels surrounding B cell follicles is present and includes high endothelial venules (HEV). Future task is to determine whether lymphoid tissue contributes to the persistence of the tumor-associated inflammatory reaction, rather than represent a functional immune compartment, potentially participating to the anti tumor response

  6. Tuberculosis treatment outcome in a tertiary care setting

    International Nuclear Information System (INIS)

    Bukhary, Zakeya A.; Alrajhi, Abdulrahman A.

    2007-01-01

    The outcome of the chemotherapy for pulmonary, extraplumonary and disseminated tuberculosis is not well documented, especially in developing countries. This study assessed tuberculosis treatment outcome, cure-to-treatment ratio and mortality among all types of tuberculosis patients in a tertiary care setting in Saudi Arabia. All cases diagnosed and treated for active Mycobacterium tuberculosis infection between 1991 and 2000 were included retrospectively. Data collected included type of tuberculosis involvement, treatment outcome, relapse and co-morbidities. Over a ten-year period, 535 case of tuberculosis were diagnosed and treated. Isolated pulmonary tuberculosis was identified in 141 cases (26.4%), extrapulmonary tuberculosis in 339 cases (63.3%). Co-morbidities were noted in 277 (52%) patients. Immunosuppression was found in 181 (34%) cases. The cure rate was 82%. The cure-to-treatment ratio was 86% in extrapulmonary tuberculosis and 65% in disseminated tuberculosis. Overall mortality was 18%. Disseminated tuberculosis had the highest mortality (34.9%), followed by pulmonary (21.8%), the extrapulmonary tuberculosis (13.6%). Forty-seven percent of all mortalities were directly related to tuberculosis. Relapse was documented in 14 out of 349 patients (4%) who had 24 months of follow-up. Despite tertiary care support, complicated tuberculosis carries a high mortality. Earlier diagnosis and complete appropriate chemotherapy are essential for improved outcome. (author)

  7. Gasification of various types of tertiary coals: A sustainability approach

    International Nuclear Information System (INIS)

    Öztürk, Murat; Özek, Nuri; Yüksel, Yunus Emre

    2012-01-01

    Highlights: ► Production energy by burning of coals including high rate of ash and sulfur is harmful to environment. ► Energy production via coal gasification instead of burning is proposed for sustainable approach. ► We calculate exergy and environmental destruction factor of gasification of some tertiary coals. ► Sustainability index, improvement potential of gasification are evaluated for exergy-based approach. - Abstract: The utilization of coal to produce a syngas via gasification processes is becoming a sustainability option because of the availability and the economic relevance of this fossil source in the present world energy scenario. Reserves of coal are abundant and more geographically spread over the world than crude oil and natural gas. This paper focuses on sustainability of the process of coal gasification; where the synthesis gas may subsequently be used for the production of electricity, fuels and chemicals. The coal gasifier unit is one of the least efficient step in the whole coal gasification process and sustainability analysis of the coal gasifier alone can substantially contribute to the efficiency improvement of this process. In order to evaluate sustainability of the coal gasification process energy efficiency, exergy based efficiency, exergy destruction factor, environmental destruction factor, sustainability index and improvement potential are proposed in this paper.

  8. Expanding the Range of the First Step to Success Intervention: Tertiary-Level Support for Children, Teachers, and Families

    Science.gov (United States)

    Frey, Andy J.; Small, Jason W.; Lee, Jon; Walker, Hill M.; Seeley, John R.; Feil, Edward G.; Golly, Annemeike

    2015-01-01

    This study presents the findings of a quasi-experimental feasibility study examining the Tertiary First Step intervention, an enhanced version of the First Step to Success early intervention program. Tertiary FirstStep was developed to engage families more effectively and influence and improve parenting practices for children having challenging…

  9. An assessment on the trustworthiness of engineers in higher tertiary institutions

    Science.gov (United States)

    Ooi Kuan, Tan; Lloyd, Ling; Mou Chuan, Cheng

    2017-10-01

    In Malaysian higher education history, the evolution from public funded to private funded and now to private non profit oriented model has been taking place since 80s. The evolution also demarcated higher learning institution into academic or research based university. As such, postgraduate studies became increasingly competitive in students intake. The evolution also created doubt to the public in term of the quality of postgraduate education offered by different classifications. This study investigates the gender specific perception and trustworthiness of engineering postgraduate students in private non profit oriented higher tertiary institution. An equally divided gender groups of 118 respondents were chosen for the study. Non-parametric statistics were used and the result showed that there was no difference and no correlation of genders in perception on teaching role and trustworthiness among the future engineers in private non profit oriented higher tertiary institution.

  10. Identifying Key Stakeholders in Blended Tertiary Environments: Experts' Perspectives

    Science.gov (United States)

    Tuapawa, Kimberley

    2017-01-01

    Although key stakeholders in blended tertiary environments (BTEs) fulfil an extraordinary role in higher education, significant gaps in knowledge about their identities may be impeding the provision of stakeholder support, limiting their ability to promote effective learning and teaching. As online growth intensifies, it is critical that tertiary…

  11. Patterns of Eye Diseases in Children Visiting a Tertiary Teaching ...

    African Journals Online (AJOL)

    Background: About 19 million children worldwide live with visual impairments resulting from different ocular morbidities. This study aimed to identify the different causes of eye diseases in children visiting a tertiary eye centre at Jimma University Hospital. Methods: We conducted a retrospective review of charts of patients of ...

  12. National Research Priorities for Tertiary Education and Training: 2011-13

    Science.gov (United States)

    National Centre for Vocational Education Research (NCVER), 2010

    2010-01-01

    The objective of a national government-funded research program for tertiary education and training is to support the achievement of major social and economic goals. These include increased opportunities for participation in the labour market, improvements in productivity and enhanced social inclusion. In essence, the overarching lens is to…

  13. Pursuing Discipline and Ethical Issues in Tertiary Institutions in Nigeria

    African Journals Online (AJOL)

    Nekky Umera

    Adeyinka Adeniji - Department of Educational Management & Business. Education ... dealing with the study of what is good and bad, right and wrong and with .... decay, neglect, decadence and crisis that characterize our tertiary institutions .... what happens in most cases is that they get directly involved in the day to day.

  14. Sedimentology and palaeontology of the Upper Jurassic Puesto Almada Member (Cañadón Asfalto Formation, Fossati sub-basin), Patagonia Argentina: Palaeoenvironmental and climatic significance

    Science.gov (United States)

    Cabaleri, Nora G.; Benavente, Cecilia A.; Monferran, Mateo D.; Narváez, Paula L.; Volkheimer, Wolfgang; Gallego, Oscar F.; Do Campo, Margarita D.

    2013-10-01

    Six facies associations are described for the Puesto Almada Member at the Cerro Bandera locality (Fossati sub-basin). They correspond to lacustrine, palustrine, and pedogenic deposits (limestones); and subordinated alluvial fan, fluvial, aeolian, and pyroclastic deposits. The lacustrine-palustrine depositional setting consisted of carbonate alkaline shallow lakes surrounded by flooded areas in a low-lying topography. The facies associations constitute four shallowing upward successions defined by local exposure surfaces: 1) a Lacustrine-Palustrine-pedogenic facies association with a 'conchostracan'-ostracod association; 2) a Palustrine facies association representing a wetland subenvironment, and yielding 'conchostracans', body remains of insects, fish scales, ichnofossils, and palynomorphs (cheirolepidiacean species and ferns growing around water bodies, and other gymnosperms in more elevated areas); 3) an Alluvial fan facies association indicating the source of sediment supply; and 4) a Lacustrine facies association representing a second wetland episode, and yielding 'conchostracans', insect ichnofossils, and a palynoflora mainly consisting of planktonic green algae associated with hygrophile elements. The invertebrate fossil assemblage found contains the first record of fossil insect bodies (Insecta-Hemiptera and Coleoptera) for the Cañadón Asfalto Formation. The succession reflects a mainly climatic control over sedimentation. The sedimentary features of the Puesto Almada Member are in accordance with an arid climatic scenario across the Upper Jurassic, and they reflect a strong seasonality with periods of higher humidity represented by wetlands and lacustrine sediments.

  15. Biomarkers, carbon isotopic composition and source rock potentials of Awgu coals, middle Benue trough, Nigeria

    Science.gov (United States)

    Adedosu, Taofik A.; Sonibare, Oluwadayo O.; Tuo, Jincai; Ekundayo, Olusegun

    2012-05-01

    Coal and carbonaceous shale samples were collected from two boreholes (BH 94 and BH 120) in Awgu formation of Middle Benue Trough, Nigeria. Source rock potentials of the samples were studied using biomarkers and carbon isotopic composition. Biomarkers in the aliphatic fractions in the samples were studied using Gas Chromatography-Mass Spectrometry (GC-MS). The Carbon isotope analysis of individual n-alkanes in the aliphatic fraction was performed using Gas Chromatography-Combustion-Isotope Ratio Mass Spectrometer (GC-IRMS). The abundance of hopanes, homohopanes (C31-C35), and C29 steranes in the samples indicate terrestrial plant, phytoplankton and cyanobacteria contributions to the organic matter that formed the coal. High (Pr/Ph) ratio (3.04-11.07) and isotopic distribution of individual alkanes showed that the samples consisted of mixed terrestrial/marine organic matter deposited under oxic condition in lacustrine-fluvial/deltaic depositional environment. The maturity parameters derived from biomarker distributions showed that the samples are in the main phase of oil window.

  16. Two-year drinking water carcinogenicity study of methyl tertiary-butyl ether (MTBE) in Wistar rats.

    Science.gov (United States)

    Dodd, Darol; Willson, Gabrielle; Parkinson, Horace; Bermudez, Edilberto

    2013-07-01

    Methyl tertiary-butyl ether (MTBE) has been used as a gasoline additive to reduce tailpipe emissions and its use has been discontinued. There remains a concern that drinking water sources have been contaminated with MTBE. A two-year drinking water carcinogenicity study of MTBE was conducted in Wistar rats (males, 0, 0.5, 3, 7.5 mg ml(-1); and females, 0, 0.5, 3, and 15 mg ml(-1)). Body weights were unaffected and water consumption was reduced in MTBE-exposed males and females. Wet weights of male kidneys were increased at the end of two years of exposure to 7.5 mg ml(-1) MTBE. Chronic progressive nephropathy was observed in males and females, was more severe in males, and was exacerbated in the high MTBE exposure groups. Brain was the only tissue with a statistically significant finding of neoplasms. One astrocytoma (1/50) was found in a female rat (15 mg ml(-1)). The incidence of brain astrocytomas in male rats was 1/50, 1/50, 1/50 and 4/50 for the 0, 0.5, 3 and 7.5 mg ml(-1) exposure groups, respectively. This was a marginally significant statistical trend, but not statistically significant when pairwise comparisons were made or when multiple comparisons were taken into account. The incidence of astrocytoma fell within historical control ranges for Wistar rats, and the brain has not been identified as a target organ following chronic administration of MTBE, ethyl tert-butyl ether, or tertiary butyl alcohol (in drinking water) to mice and rats. We conclude that the astrocytomas observed in this study are not associated with exposure to MTBE. Copyright © 2011 John Wiley & Sons, Ltd.

  17. Tertiary Intratumor Lymphoid Tissue in Colo-Rectal Cancer

    OpenAIRE

    Bergomas, Francesca; Grizzi, Fabio; Doni, Andrea; Pesce, Samantha; Laghi, Luigi; Allavena, Paola; Mantovani, Alberto; Marchesi, Federica

    2011-01-01

    Ectopic (or tertiary) lymphoid tissue develops at sites of inflammation or infection in non lymphoid organs and is associated with chronic inflammation. In colon mucosa, small lymphoid aggregates are already present in homeostatic conditions, as part of the gut-associated lymphoid tissue and play an essential role in the immune response to perturbations of the mucosal microenvironment. Despite the recognized role of inflammation in tumor progression, the presence and biological function of ly...

  18. Tertiary Students ’ Entrepreneurship Learning Socialization : Factor Analysis and Structural Equation Modeling

    Directory of Open Access Journals (Sweden)

    Chun- Mei Chou

    2015-09-01

    Full Text Available This study examines 728 tertiary students’ entrepreneurship learning socialization and its influencing factors to serve as a school reference for the development of internship and entrepreneurship education. The results show that students’ internship experience has a significant direct effect on entrepreneurship learning socialization, and entrepreneurship intention has a significant effect on entrepreneurship learning socialization through internship experience. The influence pattern and empirical data of entrepreneurship intention and internship experience on entrepreneurship learning socialization has a good fit. This paper gives an insight from Taiwan tertiary institutions about entrepreneurial learning socialization of students and contributions to them. We describe the development of the influencing factors, discuss its implications for entrepreneurship and internship education, and finally offer suggestions for further entrepreneurship education development.

  19. A Survey of Patients with Oro-Facial tumours in two Tertiary ...

    African Journals Online (AJOL)

    A Survey of Patients with Oro-Facial tumours in two Tertiary Hospitals in Lagos, ... Hence the present study was conducted to assess the care the knowledge, ... might not be unrelated to poor awareness of the tumours in our environment.

  20. Catalyst Deactivation Reactions : The Role of Tertiary Amines Revisited

    NARCIS (Netherlands)

    Novarino, Elena; Rios, Itzel Guerrero; van der Veer, Siebe; Meetsma, Auke; Hessen, Bart; Bouwkamp, Marco W.

    2011-01-01

    Decamethylzirconocene cation [Cp*2ZrMe](+) (2) decomposes in bromobenzene-d(5) solution to generate sigma-aryl species [Cp*Zr-2(2-C6H4Br-kappa Br,C)][B(C6F5)(4)] (3). This a-bond metathesis reaction is catalyzed by tertiary amines via a two-step mechanism, in which the amine acts as a proton relay.

  1. Highly efficient and diastereoselective gold(I)-catalyzed synthesis of tertiary amines from secondary amines and alkynes: substrate scope and mechanistic insights.

    Science.gov (United States)

    Liu, Xin-Yuan; Guo, Zhen; Dong, Sijia S; Li, Xiao-Hua; Che, Chi-Ming

    2011-11-11

    An efficient method for the synthesis of tertiary amines through a gold(I)-catalyzed tandem reaction of alkynes with secondary amines has been developed. In the presence of ethyl Hantzsch ester and [{(tBu)(2)(o-biphenyl)P}AuCl]/AgBF(4) (2 mol %), a variety of secondary amines bearing electron-deficient and electron-rich substituents and a wide range of alkynes, including terminal and internal aryl alkynes, aliphatic alkynes, and electron-deficient alkynes, underwent a tandem reaction to afford the corresponding tertiary amines in up to 99 % yield. For indolines bearing a preexisting chiral center, their reactions with alkynes in the presence of ethyl Hantzsch ester catalyzed by [{(tBu)(2)(o-biphenyl)P}AuCl]/AgBF(4) (2 mol %) afforded tertiary amines in excellent yields and with good to excellent diastereoselectivity. All of these organic transformations can be conducted as a one-pot reaction from simple and readily available starting materials without the need of isolation of air/moisture-sensitive enamine intermediates, and under mild reaction conditions (mostly room temperature and mild reducing agents). Mechanistic studies by NMR spectroscopy, ESI-MS, isotope labeling studies, and DFT calculations on this gold(I)-catalyzed tandem reaction reveal that the first step involving a monomeric cationic gold(I)-alkyne intermediate is more likely than a gold(I)-amine intermediate, a three-coordinate gold(I) intermediate, or a dinuclear gold(I)-alkyne intermediate. These studies also support the proposed reaction pathway, which involves a gold(I)-coordinated enamine complex as a key intermediate for the subsequent transfer hydrogenation with a hydride source, and reveal the intrinsic stereospecific nature of these transformations observed in the experiments. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Regionalised tertiary psychiatric residential facilities.

    Science.gov (United States)

    Lesage, Alain; Groden, David; Goldner, Elliot M; Gelinas, Daniel; Arnold, Leslie M

    2008-01-01

    Psychiatric hospitals remain the main venue for long-term mental health care and, despite widespread closures and downsizing, no country that built asylums in the last century has done away with them entirely--with the recent exception of Italy. Differentiated community-based residential alternatives have been developed over the past decades, with staffing levels that range from full-time professional, to daytime only, to part-time/on-call. This paper reviews the characteristics of community-based psychiatric residential care facilities as an alternative to long-term care in psychiatric hospitals. It describes five factors decision makers should consider: 1. number of residential places needed; 2. staffing levels; 3. physical setting; 4. programming; and 5. governance and financing. In Italy, facilities with full-time professional staff have been developed since the mid-1990s to accommodate the last cohorts of patients discharged from psychiatric hospitals. In the United Kingdom, experiments with hostel wards since the 1980s have shown that home-like, small-scale facilities with intensive treatment and rehabilitation programming can be effective for the most difficult-to-place patients. More recently in Australia, Community Care Units (CCUs) have been applying this concept. In the Canadian province of British Columbia (BC), Tertiary Psychiatric Residential Facilities (TPRFs) have been developed as part of an effort to regionalise health and social services and downsize and ultimately close its only psychiatric hospital. This type of service must be further developed in addition to the need for forensic, acute-care and intermediate-level beds, as well as for community-based care such as assertive community treatment and intensive case management. All these types of services, together with long-term community-based residential care, constitute the elements of a balanced mental health care system. As part of a region's balanced mental health care plan, these Tertiary

  3. Contact allergy to chlorhexidine in a tertiary dermatology clinic in Denmark

    DEFF Research Database (Denmark)

    Opstrup, Morten S; Johansen, Jeanne D; Zachariae, Claus

    2016-01-01

    cause the contact allergy, and whether accidental re-exposure occurs in some patients. OBJECTIVES: To estimate the prevalence of chlorhexidine contact allergy in a tertiary dermatology clinic in Denmark; to investigate whether patch testing with both chlorhexidine diacetate and chlorhexidine digluconate...

  4. Initial Educational Experiences of Tertiary Students. LSAY Briefing Number 14

    Science.gov (United States)

    Hillman, Kylie

    2008-01-01

    This "Briefing" presents information about the initial tertiary education experiences, such as satisfaction with aspects of student life and changes to initial enrolments, of two groups of young people, based on two recent Longitudinal Surveys of Australian Youth (LSAY) research reports. One study focused on the first year experiences of…

  5. Trace element patterns at a non-marine cretaceous-tertiary boundary

    Science.gov (United States)

    Gilmore, J.S.; Knight, J.D.; Orth, C.J.; Pillmore, C.L.; Tschudy, R.H.

    1984-01-01

    At the fossil-pollen-defined Cretaceous-Tertiary boundary in the Raton Basin of New Mexico and Colorado, an iridium abundance anomaly and excess scandium, titanium, and chromium are associated with a thin ash or dust fallout bed (now kaolinitic clay) that was preserved in freshwater coal swamps. ?? 1984 Nature Publishing Group.

  6. Strength and Deformation Properties of Tertiary Clay at Moesgaard Museum

    DEFF Research Database (Denmark)

    Kaufmann, Kristine Lee; Nielsen, Benjaminn Nordahl; Augustesen, Anders Hust

    The tertiary clay at Moesgaard Museum near Aarhus in the eastern part of Jutland in Denmark is a highly plastic, glacially disturbed nappe of Viborg Clay. The clay is characterised as a swelling soil, which could lead to damaging of the building due to additional heave of the soil. To take...

  7. Research Productivity of ]unior Academic Staff at a Tertiary Medical ...

    African Journals Online (AJOL)

    Research Productivity of ]unior Academic Staff at a Tertiary Medical College in South West, Nigeria. OA Lesi, OO Orenuga, A Roberts, OO Abudu. Abstract. No Abstract. Full Text: EMAIL FULL TEXT EMAIL FULL TEXT · DOWNLOAD FULL TEXT DOWNLOAD FULL TEXT · AJOL African Journals Online. HOW TO USE AJOL.

  8. Halitosis amongst students in tertiary institutions in Lagos state.

    Science.gov (United States)

    Arinola, J E; Olukoju, O O

    2012-12-01

    Halitosis is defined as a noticeable unpleasant odor from the mouth. It is a medico-social problem that affects a significant number of people around the world. Research reveals that nearly 50% of the adult population has halitosis. To determine level of awareness of halitosis and prevalence of the condition amongst students in tertiary institutions as a baseline survey. For this project, 100 students from three tertiary institutions in Lagos state were chosen: University of Lagos, Lagos State University, Ojo campus and Yaba College of Technology. A semi-structured questionnaire and practical testing/diagnostic tool were utilized. Data collected was collated and analyzed using Microsoft Excel 2007 and SPSS statistical software. Most of the respondents were single and Christian. Level of awareness of halitosis was high. Results showed that 15%, 2% and 22% from UNILAG, LASU and YCT respectively said they had halitosis. Using the diagnostic tool, 6%, 8% and 2% respectively were positive for halitosis. There is high level of awareness of halitosis among the respondents. The prevalence of the disorder is low, however, it is recommended that enlightenment campaigns be mounted in schools to improve level of awareness and treatment seeking.

  9. Lewis Acid Catalyzed Asymmetric Three-Component Coupling Reaction: Facile Synthesis of α-Fluoromethylated Tertiary Alcohols.

    Science.gov (United States)

    Aikawa, Kohsuke; Kondo, Daisuke; Honda, Kazuya; Mikami, Koichi

    2015-12-01

    A chiral dicationic palladium complex is found to be an efficient Lewis acid catalyst for the synthesis of α-fluoromethyl-substituted tertiary alcohols using a three-component coupling reaction. The reaction transforms three simple and readily available components (terminal alkyne, arene, and fluoromethylpyruvate) to valuable chiral organofluorine compounds. This strategy is completely atom-economical and results in perfect regioselectivities and high enantioselectivities of the corresponding tertiary allylic alcohols in good to excellent yields. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Review of six year cardiovascular mortality at a tertiary hospital in ...

    African Journals Online (AJOL)

    Review of six year cardiovascular mortality at a tertiary hospital in south-east Nigeria. ... E Iheanyi, OM Oghale, K Uwanuruochi, CO Odigwe, A Chuku ... The mean age at death was highest for stroke, 65.0years, likewise the mean duration of ...

  11. Maternal mortality audit in a tertiary health institution in Nigeria ...

    African Journals Online (AJOL)

    Introduction: Nigeria has the second highest number of maternal deaths in the world.The study aimed at determining the causes of and non-obstetric contributors to maternal mortality at a tertiary referral hospital. Materials and Methods: It was a prospective audit of all consecutive maternal deaths in the hospital over a ...

  12. Fuego Volcano eruption (Guatemala, 1974): evidence of a tertiary fragmentation?

    International Nuclear Information System (INIS)

    Brenes-Andre, Jose

    2014-01-01

    Values for mode and dispersion calculated from SFT were analyzed using the SFT (Sequential Fragmentation/Transport) model to Fuego Volcano eruption (Guatemala, 1974). Analysis results have showed that the ideas initially proposed for Irazu, can be applied to Fuego Volcano. Experimental evidence was found corroborating the existence of tertiary fragmentations. (author) [es

  13. Smoke-Free Policies in New Zealand Public Tertiary Education Institutions

    Science.gov (United States)

    Robertson, Lindsay A.; Marsh, L.

    2015-01-01

    The Framework Convention on Tobacco Control mandates the creation of smoke-free environments to protect non-smokers from second-hand smoke and reduce demand for tobacco. We aimed to examine the extent and nature of smoke-free campus policies at tertiary education institutions throughout New Zealand, and examine the policy development process.…

  14. Anti Diabetic Drug Utilization by Elderly Patients in a Tertiary ...

    African Journals Online (AJOL)

    This study is intended to determine the pattern and rational use of drugs in the elderly diabetic patients in a tertiary health care facility in Western Nigeria. ... Metformin was the most commonly prescribed antidiabetic medication for the patients followed by glimepiride (52.8%) (highest within age 50-59 years) and then ...

  15. PASS Student Leader and Mentor Roles: A Tertiary Leadership Pathway

    Science.gov (United States)

    Skalicky, Jane; Caney, Annaliese

    2010-01-01

    In relation to developing leadership skills during tertiary studies, this paper considers the leadership pathway afforded by a Peer Assisted Study Sessions (PASS) program which includes the traditional PASS Leader role and a more senior PASS Mentor role. Data was collected using a structured survey with open-ended questions designed to capture the…

  16. A Conceptual Approach for Blended Leadership for Tertiary Education Institutions

    Science.gov (United States)

    Jones, Sandra; Harvey, Marina; Lefoe, Geraldine

    2014-01-01

    Over the last 20 years, the tertiary education sector has adopted new administrative management approaches, with the aim of improving accountable and strategic focus. Over the same period, the question of how to build leadership capacity to improve learning and teaching and research outcomes has led to discussion on what constitutes academic…

  17. opinions of nigerian students in tertiary institutions on family size

    African Journals Online (AJOL)

    Admin

    The study examined the opinions of Nigerian students in tertiary institutions on their ideal family size. It was conducted among students in four ... opinions of male and female students on family size. KEY WORD: Family Size, Nigerian ... two children per woman, with many couples who desire to remain childless and some ...

  18. An Examination of Tertiary Students' Desire to Found an Enterprise

    Science.gov (United States)

    Birdthistle, Naomi

    2008-01-01

    Purpose: The purpose of this paper is twofold. First, the paper aims to identify and explain the behaviour and intentions of students in their decision to start entrepreneurial activities and establish an enterprise. Second, the paper aims to identify whether students in tertiary level institutions in Ireland display the personality traits of an…

  19. Secondary and Tertiary Hyperparathyroidism, State of the Art Surgical Management

    Science.gov (United States)

    Pitt, Susan C.; Sippel, Rebecca S.

    2010-01-01

    Synopsis This article reviews the current surgical management of patients with secondary and tertiary hyperparathyroidism. The focus is on innovative surgical strategies that have improved the care of these patients over the past 10 to 15 years. Modalities such as intraoperative parathyroid hormone monitoring and radioguided probe utilization are discussed. PMID:19836494

  20. A tertiary care-primary care partnership model for medically complex and fragile children and youth with special health care needs.

    Science.gov (United States)

    Gordon, John B; Colby, Holly H; Bartelt, Tera; Jablonski, Debra; Krauthoefer, Mary L; Havens, Peter

    2007-10-01

    To evaluate the impact of a tertiary care center special needs program that partners with families and primary care physicians to ensure seamless inpatient and outpatient care and assist in providing medical homes. Up to 3 years of preenrollment and postenrollment data were compared for patients in the special needs program from July 1, 2002, through June 30, 2005. A tertiary care center pediatric hospital and medical school serving urban and rural patients. A total of 227 of 230 medically complex and fragile children and youth with special needs who had a wide range of chronic disorders and were enrolled in the special needs program. Care coordination provided by a special needs program pediatric nurse case manager with or without a special needs program physician. Preenrollment and postenrollment tertiary care center resource utilization, charges, and payments. A statistically significant decrease was found in the number of hospitalizations, number of hospital days, and tertiary care center charges and payments, and an increase was found in the use of outpatient services. Aggregate data revealed a decrease in hospital days from 7926 to 3831, an increase in clinic visits from 3150 to 5420, and a decrease in tertiary care center payments of $10.7 million. The special needs program budget for fiscal year 2005 had a deficit of $400,000. This tertiary care-primary care partnership model improved health care and reduced costs with relatively modest institutional support.

  1. Sorption-desorption of imidacloprid onto a lacustrine Egyptian soil and its clay and humic acid fractions.

    Science.gov (United States)

    Kandil, Mahrous M; El-Aswad, Ahmed F; Koskinen, William C

    2015-01-01

    Sorption-desorption of the insecticide imidacloprid 1-[(6-chloro-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimine onto a lacustrine sandy clay loam Egyptian soil and its clay and humic acid (HA) fractions was investigated in 24-h batch equilibrium experiments. Imidacloprid (IMDA) sorption-desorption isotherms onto the three sorbents were found to belong to a non-linear L-type and were best described by the Freundlich model. The value of the IMDA adsorption distribution coefficient, Kd(ads), varied according to its initial concentration and was ranged 40-84 for HA, 14-58 for clay and 1.85-4.15 for bulk soil. Freundlich sorption coefficient, Kf(ads), values were 63.0, 39.7 and 4.0 for HA, clay and bulk soil, respectively. The normalized soil Koc value for imidacloprid sorption was ∼800 indicating its slight mobility in soils. Nonlinear sorption isotherms were indicated by 1/n(ads) values imidacloprid sorption process with all tested sorbents. Gibbs free energy (ΔG) values indicated a spontaneous and physicosorption process for IMDA and a more favorable sorption to HA than clay and soil. In conclusion, although the humic acid fraction showed the highest capacity and affinity for imidacloprid sorption, the clay fraction contributed to approximately 95% of soil-sorbed insecticide. Clay and humic acid fractions were found to be the major two factors controlling IMDA sorption in soils. The slight mobility of IMDA in soils and the hysteresis phenomenon associated with the irreversibility of its sorption onto, mainly, clay and organic matter of soils make its leachability unlikely to occur.

  2. Factors influencing phase-disengagement rates in solvent-extraction systems employing tertiary amine extractants

    International Nuclear Information System (INIS)

    Moyer, B.A.; McDowell, W.J.

    1981-01-01

    The primary purpose of the present investigation was to examine the effects of amine size and structure on phase disengagement. Nine commercial tertiary amines were tested together with four laboratory-quality amines for uranium extraction and both organic-continuous (OC) and aqueous-continuous (AC) phase disengagement under Amex-type conditions. Synthetic acid sulfate solutions with and without added colloidal silica and actual ore leach solutions were used as the aqueous phases. Phase disengagement results were correlated with amine size and branching and solution wetting behavior on a silicate (glass) surface. The results suggest that the performance of some Amex systems may be improved by using branched chain tertiary amine extractants of higher molecular weight than are now normally used

  3. Evaluation of alternate secondary (and tertiary) coolants for the molten-salt breeder reactor

    International Nuclear Information System (INIS)

    Kelmers, A.D.; Baes, C.F.; Bettis, E.S.; Brynestad, J.; Cantor, S.; Engel, J.R.; Grimes, W.R.; McCoy, H.E.; Meyer, A.S.

    1976-04-01

    The three most promising coolant selections for an MSBR have been identified and evaluated in detail from the many coolants considered for application either as a secondary coolant in 1000-MW(e) MSBR configurations using only one coolant, or as secondary and tertiary coolants in an MSBR dual coolant configuration employing two different coolants. These are, as single secondary coolants: (1) a ternary sodium--lithium--beryllium fluoride melt; (2) the sodium fluoroborate--sodium fluoride eutectic melt, the present reference design secondary coolant. In the case of the dual coolant configuration, the preferred system is molten lithium--beryllium fluoride (Li 2 BeF 4 ) as the secondary coolant and helium gas as the tertiary coolant

  4. Analysis of arsenic speciation in mine contaminated lacustrine sediment using selective sequential extraction, HR-ICPMS and TEM

    International Nuclear Information System (INIS)

    Haus, Kelly L.; Hooper, Robert L.; Strumness, Laura A.; Mahoney, J. Brian

    2008-01-01

    In order to determine how As speciation in lacustrine sediment changes as a function of local conditions, sediment cores were taken from three lakes with differing hydrologic regimes and subjected to extensive chemical and TEM analysis. The lakes (Killarney, Thompson and Swan Lakes) are located within the Coeur d' Alene River system (northern Idaho, USA), which has been contaminated with trace metals and As, from over 100 a of sulfide mining. Previous analyses of these lakebed sediments have shown an extensive amount of contaminant metals and As associated with sub-μm grains, making them extremely difficult to analyze using standard methods (scanning electron microscopy, X-ray diffraction). Transmission electron microscopy offers great advantages in spatial resolution and can be invaluable in determining As speciation when combined with other techniques. Data indicate that because of differences in local redox conditions, As speciation and stability is dramatically different in these lakes. Killarney and Thompson Lakes experience seasonal water-level fluctuations due to drawdown on a downstream dam, causing changes in O 2 content in sediment exposed during drawdown. Swan Lake has relatively constant water levels as its only inlet is dammed. Consequently, Killarney and Thompson Lakes show an increase in labile As-bearing phases with depth, while Swan Lake data indicate stable As hosts throughout the sediment profile. Based on these observations it can be stated that As in lakebed sediments is much less mobile, and therefore less bioavailable, when water is kept at a constant level

  5. The relationship between carbonate facies, volcanic rocks and plant remains in a late Palaeozoic lacustrine system (San Ignacio Fm, Frontal Cordillera, San Juan province, Argentina)

    Science.gov (United States)

    Busquets, P.; Méndez-Bedia, I.; Gallastegui, G.; Colombo, F.; Cardó, R.; Limarino, O.; Heredia, N.; Césari, S. N.

    2013-07-01

    The San Ignacio Fm, a late Palaeozoic foreland basin succession that crops out in the Frontal Cordillera (Argentinean Andes), contains lacustrine microbial carbonates and volcanic rocks. Modification by extensive pedogenic processes contributed to the massive aspect of the calcareous beds. Most of the volcanic deposits in the San Ignacio Fm consist of pyroclastic rocks and resedimented volcaniclastic deposits. Less frequent lava flows produced during effusive eruptions led to the generation of tabular layers of fine-grained, greenish or grey andesites, trachytes and dacites. Pyroclastic flow deposits correspond mainly to welded ignimbrites made up of former glassy pyroclasts devitrified to microcrystalline groundmass, scarce crystals of euhedral plagioclase, quartz and K-feldspar, opaque minerals, aggregates of fine-grained phyllosilicates and fiammes defining a bedding-parallel foliation generated by welding or diagenetic compaction. Widespread silicified and silica-permineralized plant remains and carbonate mud clasts are found, usually embedded within the ignimbrites. The carbonate sequences are underlain and overlain by volcanic rocks. The carbonate sequence bottoms are mostly gradational, while their tops are usually sharp. The lower part of the carbonate sequences is made up of mud which appear progressively, filling interstices in the top of the underlying volcanic rocks. They gradually become more abundant until they form the whole of the rock fabric. Carbonate on volcanic sandstones and pyroclastic deposits occur, with the nucleation of micritic carbonate and associated production of pyrite. Cyanobacteria, which formed the locus of mineral precipitation, were related with this nucleation. The growth of some of the algal mounds was halted by the progressive accumulation of volcanic ash particles, but in most cases the upper boundary is sharp and suddenly truncated by pyroclastic flows or volcanic avalanches. These pyroclastic flows partially destroyed the

  6. A Comparative study of early postpartum IUCD insertion to interval IUCD insertion at Tertiary Care Centre

    OpenAIRE

    Roopal, Dr.; Bisht, Vandana

    2018-01-01

    Background: A Comparative study of early postpartum IUCD insertion to interval IUCD insertion at Tertiary Care Centre.Methods: This prospective study was conducted among 100 women at tertiary care centre, Haldwani, Nainital. Patients were divided in to two groups. Group A (n=50)-post placental insertion within 10 minutes of delivery of placenta. Group B (n=50)-Interval insertion after 6 weeks of delivery. Both groups were compared in terms of pain abdomen, bleeding, missing thread, expulsion,...

  7. Historical records of polycyclic aromatic hydrocarbon deposition in a shallow eutrophic lake: Impacts of sources and sedimentological conditions.

    Science.gov (United States)

    Li, Chaocan; Huo, Shouliang; Yu, Zhiqiang; Guo, Wei; Xi, Beidou; He, Zhuoshi; Zeng, Xiangying; Wu, Fengchang

    2016-03-01

    Sediment core samples collected from Lake Chaohu were analyzed for 15 priority polycyclic aromatic hydrocarbons (PAHs) to assess the spatial and temporal distributions of the PAHs during lacustrine sedimentary processes and regional economic development. Assessing the PAH sedimentary records over an approximately 100-year time span, we identified two stages in the PAH inputs and sources (before the 1970s and after the 1970s) in the eastern lake region near a village, whereas three stages (before the 1950s, 1950s-1990s and after the 1990s) were identified in the western lake region near urban and industrial areas. Rapid increases in the PAH depositional fluxes occurred during the second stage due to increased human activities in the Lake Chaohu basin. The composition and isomeric ratios of the PAHs revealed that pyrolysis is the main source of PAHs in this lake. Strong positive relationships between PAH concentration and the total organic carbon concentration, sediment grain size (energy consumption and the levels of urban industrialization and civilization, affect both the composition and abundance of the PAHs. Copyright © 2015. Published by Elsevier B.V.

  8. Tertiary survey in polytrauma patients should be an ongoing process.

    Science.gov (United States)

    Ferree, Steven; Houwert, Roderick M; van Laarhoven, Jacqueline J E M; Smeeing, Diederik P J; Leenen, Luke P H; Hietbrink, Falco

    2016-04-01

    Due to prioritisation in the initial trauma care, non-life threatening injuries can be overlooked or temporally neglected. Polytrauma patients in particular might be at risk for delayed diagnosed injuries (DDI). Studies that solely focus on DDI in polytrauma patients are not available. Therefore the aim of this study was to analyze DDI and determine risk factors associated with DDI in polytrauma patients. In this single centre retrospective cohort study, patients were considered polytrauma when the Injury Severity Score was ≥ 16 as a result of injury in at least 2 body regions. Adult polytrauma patients admitted from 2007 until 2012 were identified. Hospital charts were reviewed to identify DDI. 1416 polytrauma patients were analyzed of which 12% had DDI. Most DDI were found during initial hospital admission after tertiary survey (63%). Extremities were the most affected regions for all types of DDI (78%) with the highest intervention rate (35%). Most prevalent DDI were fractures of the hand (54%) and foot (38%). In 2% of all patients a DDI was found after discharge, consisting mainly of injuries other than a fracture. High energy trauma mechanism (OR 1.8, 95% CI 1.2-2.7), abdominal injury (OR 1.5, 95% CI 1.1-2.1) and extremity injuries found during initial assessment (OR 2.3, 95% CI 1.6-3.3) were independent risk factors for DDI. In polytrauma patients, most DDI were found during hospital admission but after tertiary survey. This demonstrates that the tertiary survey should be an ongoing process and thus repeated daily in polytrauma patients. Most frequent DDI were extremity injuries, especially injuries of the hand and foot. Copyright © 2015 Elsevier Ltd. All rights reserved.

  9. Extent of Information and Communication Technology (ICT) Utilization for Students' Learning in Tertiary Institutions in Ondo State, Nigeria

    Science.gov (United States)

    Victor, Akinfolarin Akinwale; Bolanle, Rufai Rukayat

    2017-01-01

    This study investigated the extent of information and communication technology (ICT) utilization for students' learning in Ondo State tertiary institutions. The research design was descriptive survey. The target population comprises of all students in tertiary institutions of learning in Ondo State. A sample of two hundred (200) undergraduate…

  10. Profile of Microvascular Disease in Type 2 Diabetes in a Tertiary ...

    African Journals Online (AJOL)

    Background: Diabetes mellitus (DM) is a metabolic disorder complicated by microvascular and macrovascular diseases. The clinical profile of these complications has not been adequately studied in many tertiary health care centers in India. Aim: The authors studied the clinical profile of microvascular diabetes ...

  11. Reflections on entrepreneurship education in African tertiary institutions

    Directory of Open Access Journals (Sweden)

    K. Bawuah

    2006-12-01

    Full Text Available It is a well-established fact that several developed economies grew on the back of small businesses and entrepreneurial development. It stands to reason then that the development of Sub-Saharan Africa (SSA can also be catalysed by a rise in the number of entrepreneurs and entrepreneurial activity. In that general regard, this paper sought to investigate the state of entrepreneurship education in Sub-Saharan Africa (SSA. The method adopted in investigating this phenomenon was to critique the existing tertiary education entrepreneurship structures (where these existed at all and to proffer recommendations where anomalies were discovered. It came to light that despite the critical importance of entrepreneurs in the economic development of a nation, Sub-Saharan African (SSA countries have not fully developed strategies to tap this resource. What the countries have, are haphazard policies designed to promote the lesser or uneducated individuals in the informal sector into entrepreneurship. SSA educational leaders must find ways to structure their curricula so that all or most of their students can take courses in entrepreneurship. This is essential for SSA countries in order to move them from their present disadvantaged economic status, to greater economic and social development. A tentative syllabus for African tertiary education is proffered at the end of the article but its robustness needs to be tested.

  12. The Impact of Cooperative Learning on Tertiary EFL Learners' Motivation

    Science.gov (United States)

    Ning, Huiping; Hornby, Garry

    2014-01-01

    This study was aimed at investigating the impact of cooperative learning on the motivation of tertiary English learners. Participants were from two randomly assigned classes at a university in the north of China. A pre-test-post-test control group design was employed to compare the impact of the cooperative learning approach with that of…

  13. An Audit of Otorhinolaryngological Practice in a Tertiary Institution in ...

    African Journals Online (AJOL)

    Background: The Niger Delta University Teaching Hospital (NDUTH) is a young tertiary hospital with recently established department in various specialties. In spite of this it caters for the health needs of a lot of the patients in Bayelsa state and its environs. The aim of this study therefore is to audit the otorhinolaryngological ...

  14. Religious extremism as a challenge to tertiary education in Nigeria ...

    African Journals Online (AJOL)

    Extremists use religion as a shield either for political or economic agenda and manipulate their gullible followers in order to impose their ideology on them. The reality of religious extremism in Nigeria is a challenge to tertiary education to search for a lasting solution that will enable Nigerians overcome the problem and focus ...

  15. Self-Concept as a Correlate of Career Choice of Students in Tertiary ...

    African Journals Online (AJOL)

    concept and career choice of students in Post-Secondary Institutions in Sokoto State. The sample consisted of 300 students (140 males and 160 females) deliberately selected from the population of three tertiary institutions in Sokoto State.

  16. Identification of novel genes associated with renal tertiary lymphoid organ formation in aging mice.

    Science.gov (United States)

    Huang, Yuan; Caputo, Christina R; Noordmans, Gerda A; Yazdani, Saleh; Monteiro, Luiz Henrique; van den Born, Jaap; van Goor, Harry; Heeringa, Peter; Korstanje, Ron; Hillebrands, Jan-Luuk

    2014-01-01

    A hallmark of aging-related organ deterioration is a dysregulated immune response characterized by pathologic leukocyte infiltration of affected tissues. Mechanisms and genes involved are as yet unknown. To identify genes associated with aging-related renal infiltration, we analyzed kidneys from aged mice (≥20 strains) for infiltrating leukocytes followed by Haplotype Association Mapping (HAM) analysis. Immunohistochemistry revealed CD45+ cell clusters (predominantly T and B cells) in perivascular areas coinciding with PNAd+ high endothelial venules and podoplanin+ lymph vessels indicative of tertiary lymphoid organs. Cumulative cluster size increased with age (analyzed at 6, 12 and 20 months). Based on the presence or absence of clusters in male and female mice at 20 months, HAM analysis revealed significant associations with loci on Chr1, Chr2, Chr8 and Chr14 in male mice, and with loci on Chr4, Chr7, Chr13 and Chr14 in female mice. Wisp2 (Chr2) showed the strongest association (P = 5.00×10(-137)) in male mice; Ctnnbip1 (P = 6.42×10(-267)) and Tnfrsf8 (P = 5.42×10(-245)) (both on Chr4) showed the strongest association in female mice. Both Wisp2 and Ctnnbip1 are part of the Wnt-signaling pathway and the encoded proteins were expressed within the tertiary lymphoid organs. In conclusion, this study revealed differential lymphocytic infiltration and tertiary lymphoid organ formation in aged mouse kidneys across different inbred mouse strains. HAM analysis identified candidate genes involved in the Wnt-signaling pathway that may be causally linked to tertiary lymphoid organ formation.

  17. Origin and evolution of Sariñena Lake (central Ebro Basin): A piping-based model

    Science.gov (United States)

    Castañeda, Carmen; Javier Gracia, F.; Rodríguez-Ochoa, Rafael; Zarroca, Mario; Roqué, Carles; Linares, Rogelio; Desir, Gloria

    2017-08-01

    The origin and nature of the numerous lakes in the central Ebro Basin have been interpreted according to the prevailing arid or semiarid conditions, the easily-eroded materials and the solubility of the gypsum- and/or carbonate-rich Tertiary/Cenozoic substratum, involving important dissolution (karstic) and/or aeolian deflation. However, the origin of Sariñena Lake, the largest in the central Ebro Basin, remains unknown since the typical lake-generating processes in the region are not applicable. This work provides significant clues to the genesis and evolution of Sariñena Lake in a regional context. The combination of geomorphological mapping and high resolution LiDAR data together with sedimentological observations, the characterisation of soils and sediments around the lake, and the application of high-resolution geophysical techniques suggest that piping is the major genetic process driving the evolution of the Sariñena depression and lake. Field evidence demonstrates that piping is, at present, the most important erosive process in the region, generating significant collapse and surface lowering. Sariñena Lake is located within a deep endorheic depression excavated from Na-rich Tertiary materials. This work hypothesises that once an early, fluvially-originated palustrine area had developed, the progressive lowering of the regional water table linked to regional fluvial incision favoured the establishment of a hydrological gradient high enough to trigger piping processes within the claystones and siltstones underlying the original palustrine area. The Quaternary evolution of the Sariñena lacustrine basin was then controlled by successive water table fluctuations, linked to different phases of incision and alluvial deposition in the surrounding fluvial systems. All the evidence supporting a piping-related origin for this lake, together with examples of lakes generated by similar processes in different contexts, is used to propose a new genetic type of

  18. Spontaneous quaternary and tertiary T-R transitions of human hemoglobin in molecular dynamics simulation.

    Directory of Open Access Journals (Sweden)

    Jochen S Hub

    2010-05-01

    Full Text Available We present molecular dynamics simulations of unliganded human hemoglobin (Hb A under physiological conditions, starting from the R, R2, and T state. The simulations were carried out with protonated and deprotonated HC3 histidines His(beta146, and they sum up to a total length of 5.6 micros. We observe spontaneous and reproducible T-->R quaternary transitions of the Hb tetramer and tertiary transitions of the alpha and beta subunits, as detected from principal component projections, from an RMSD measure, and from rigid body rotation analysis. The simulations reveal a marked asymmetry between the alpha and beta subunits. Using the mutual information as correlation measure, we find that the beta subunits are substantially more strongly linked to the quaternary transition than the alpha subunits. In addition, the tertiary populations of the alpha and beta subunits differ substantially, with the beta subunits showing a tendency towards R, and the alpha subunits showing a tendency towards T. Based on the simulation results, we present a transition pathway for coupled quaternary and tertiary transitions between the R and T conformations of Hb.

  19. The Equity Imperative in Tertiary Education: Promoting Fairness and Efficiency

    Science.gov (United States)

    Salmi, Jamil; Bassett, Roberta Malee

    2014-01-01

    While the share of the tertiary education age cohort (19-25) which is being given the opportunity to study has increased worldwide over the past two decades, this does not in fact translate into reduced inequality. For many young people, especially in the developing world, major obstacles such as disparities in terms of gender, minority population…

  20. Engineering of Droplet Manipulation in Tertiary Junction Microfluidic Channels

    Science.gov (United States)

    2017-06-30

    mechanics point-of-view, the larger motivation to carry out this research work derives from its application in biomedical engineering for sorting CTCs...AFRL-AFOSR-JP-TR-2017-0055 Engineering of Droplet Manipulation in Tertiary Junction Microfluidic Channels Shalini Gupta INDIAN INSTITUTE OF...2017 2. REPORT TYPE Final 3. DATES COVERED (From - To) 14 May 2015 to 13 Nov 2016 4. TITLE AND SUBTITLE Engineering of Droplet Manipulation in

  1. The search for a source rock for the giant Tar Sand triangle accumulation, southeastern Utah

    Science.gov (United States)

    Huntoon, J.E.; Hansley, P.L.; Naeser, N.D.

    1999-01-01

    A large proportion (about 36%) of the world's oil resource is contained in accumulations of heavy oil or tar. In these large deposits of degraded oil, the oil in place represents only a fraction of what was present at the time of accumulation. In many of these deposits, the source of the oil is unknown, and the oil is thought to have migrated over long distances to the reservoirs. The Tar Sand triangle in southeastern Utah contains the largest tar sand accumulation in the United States, with 6.3 billion bbl of heavy oil estimated to be in place. The deposit is thought to have originally contained 13-16 billion bbl prior to the biodegradation, water washing, and erosion that have taken place since the middle - late Tertiary. The source of the oil is unknown. The tar is primarily contained within the Lower Permian White Rim Sandstone, but extends into permeable parts of overlying and underlying beds. Oil is interpreted to have migrated into the White Rim sometime during the Tertiary when the formation was at a depth of approximately 3500 m. This conclusion is based on integration of fluid inclusion analysis, time-temperature reconstruction, and apatite fission-track modeling for the White Rim Sandstone. Homogenization temperatures cluster around 85-90??C for primary fluid inclusions in authigenic, nonferroan dolomite in the White Rim. The fluid inclusions are associated with fluorescent oil-bearing inclusions, indicating that dolomite precipitation was coeval with oil migration. Burial reconstruction suggests that the White Rim Sandstone reached its maximum burial depth from 60 to 24 Ma, and that maximum burial was followed by unroofing from 24 to 0 Ma. Time-temperature modeling indicates that the formation experienced temperatures of 85-90??C from about 35 to 40 Ma during maximum burial. Maximum formation temperatures of about 105-110??C were reached at about 24 Ma, just prior to unroofing. Thermal modeling is used to examine the history of potential source rocks

  2. Effect of Di-Tertiary Butyl Peroxide on the performance, combustion and emission characteristics of ethanol blended cotton seed methyl ester fuelled automotive diesel engine

    International Nuclear Information System (INIS)

    Kumar, K. Senthil; Raj, R. Thundil Karuppa

    2016-01-01

    Highlights: • Effect of di-tertiary butyl peroxide on ethanol blended biodiesel is investigated. • Cetane enhanced ethanol up to 10% can be blended with cotton seed biodiesel. • Nitrogen oxides emissions are lower for cetane enhanced ethanol biodiesels. • Performance characteristics of cetane improved ethanol biodiesels are reasonable. • Cetane enhanced ethanol blended biodiesel is an promising renewable energy source. - Abstract: An experimental study is carried out to examine and analyze the influence of Di-Tertiary Butyl Peroxide in bioethanol diesel blends on the performance, combustion and emission characteristics in a single cylinder, 4-stroke, naturally aspirated, automotive diesel engine for variable speed at full load conditions. Esterified cotton seed oil of 5% by volume is emulsified with 95% pure diesel to get the base fuel (BE0) for the experiments. Bioethanol diesel blends are produced from base fuel by adding 5% and 10% pure ethanol on a volumetric basis to obtain BE5 and BE10 respectively. The bioethanol fuels are low in Cetane number and hence Di-Tertiary Butyl Peroxide a Cetane enhancer is added by 0.4% by volume to produce BE5CN0.4% and BE10CN0.4% emulsions respectively. It is found from the experiments carried out, that an inverse trend exists between brake thermal efficiency and percentage of ethanol in base fuel. This is due to the lower calorific value of ethanol and an improvement in brake thermal efficiency is observed with ignition improver added blends. The presence of Cetane improver significantly reduced oxides of nitrogen and unburned hydro carbon emissions for overall engine speed and carbon monoxide emissions for low to medium speed range.

  3. Reuse of refinery's tertiary-treated wastewater in cooling towers: microbiological monitoring.

    Science.gov (United States)

    Dos Santos, Vera Lúcia; Veiga, Andréa Azevedo; Mendonça, Rafael Silva; Alves, Andrea Lima; Pagnin, Sérgio; Santiago, Vânia M J

    2015-02-01

    The study was planned to quantify the distribution of bacteria between bulk water and biofilm formed on different materials in an industrial scale cooling tower system of an oil refinery operating with clarified and chlorinated freshwater (CCW) or chlorinated tertiary effluent (TRW) as makeup water. The sessile and planktonic heterotrophic bacteria and Pseudomonas aeruginosa densities were significantly higher in the cooling tower supplied with clarified and chlorinated freshwater (CTCW) (p towers, the biofilm density was higher on the surface of glass slides and stainless steel coupons than on the surface of carbon steel coupons. The average corrosion rates of carbon steel coupons (0.4-0.8 millimeters per year (mpy)) and densities of sessile (12-1.47 × 10(3) colony-forming unit (CFU) cm(-1)) and planktonic (0-2.36 × 10(3) CFU mL(-1)) microbiota remained below of the maximum values of reference used by water treatment companies as indicative of efficient microbial control. These data indicate that the strategies of the water treatment station (WTS) (free chlorine) and industrial wastewater treatment station (IWTS) followed by reverse electrodialysis system (RES) (free chlorine plus chloramine) were effective for the microbiological control of the two makeup water sources.

  4. Mineralogy of Fluvio-Lacustrine Sediments Investigated by Curiosity During the Prime Mission: Implications for Diagenesis

    Science.gov (United States)

    Rampe, Elizabeth B.; Morris, R. V.; Bish, D. L.; Vaniman, D. T.; Bristow, T. F.; Chipera, S. J.; Blake, D. F.; Ming, D. W.; Farmer, J. D.; Morrison, S. M.; hide

    2014-01-01

    The Mars Science Laboratory rover Curiosity investigated sedimentary rocks that were deposited in a diversity of fluvio-lacustrine settings. The entire science payload was employed to characterize the mineralogy and chemistry of the Sheepbed mudstone at Yellowknife Bay and the Windjana sandstone at the Kimberley. Data from the CheMin instrument, a transmission Xray diffractometer, were used to determine the quantitative mineralogy of both samples. The Sheepbed mudstone contains detrital basaltic minerals, calcium sulfates, iron oxides or hydroxides, iron sulfides, trioctahedral smectite, and amorphous material. The mineral assemblage and chemical data from APXS suggest that the trioctahedral smectite and magnetite formed authigenically as a result of alteration of olivine. The apparent lack of higher-grade phyllosilicates (e.g., illite and chlorite) and the presence of anhydrite indicate diagenesis at 50- 80 ºC. The mineralogy of the Windjana sandstone is different than the Sheepbed mudstone. Windjana contains significant abundances of K-feldspar, low- and high-Ca pyroxenes, magnetite, phyllosilicates, and amorphous material. At least two distinct phyllosilicate phases exist: a 10 Å phase and a component that is expanded with a peak at 11.8 Å. The identity of the expanded phase is currently unknown, but could be a smectite with interlayer H2O, and the 10 Å phase could be illite or collapsed smectite. Further work is necessary to characterize the phyllosilicates, but the presence of illite could suggest that Windjana experienced burial diagenesis. Candidates for the cementing agents include fine-grained phyllosilicates, Fe-oxides, and/or amorphous material. Interpretations of CheMin data from the Windjana sandstone are ongoing at the time of writing, but we will present an estimate of the composition of the amorphous material from mass balance calculations using the APXS bulk chemistry and quantitative mineralogy from CheMin.

  5. Educational Online Technologies in Blended Tertiary Environments: A Review of Literature

    Science.gov (United States)

    Tuapawa, Kimberley N.

    2013-01-01

    This is a review of the literature surrounding five popular media-rich educational online technologies (EOTs) currently being used by educationalists to support blended learning within tertiary environments. This review considers the following EOTs: 1) connective media, 2) interactive gaming, 3) virtual worlds, 4) web conferencing and 5) learning…

  6. A Study of Macao Tertiary Students' Language Attitudes after the Handover

    Science.gov (United States)

    Yan, Xi

    2017-01-01

    This study investigates Macao tertiary students' language attitudes under the dynamic interplay of local, national, and global forces. The Portuguese established their settlement at Macao during the mid-sixteenth century and their colonial rule over Macao during the mid-nineteenth century. Macao's sovereignty was transferred to China at midnight…

  7. A study on the utilization of serial resources in selected tertiary ...

    African Journals Online (AJOL)

    A study on the utilization of serial resources in selected tertiary institutions in Ogun State. ... Lagos Journal of Library and Information Science ... Serial resources are publications either in printed form or electronic format issued in successive parts usually having numerical or chronological designations and intended to be ...

  8. Prevalence of obesity among diabetics seen in a tertiary health care ...

    African Journals Online (AJOL)

    Background: Obesity is a leading determinant for diabetes mellitus. The objective of this study was to assess the prevalence of overweight/obesity among diabetic patients seen at a tertiary hospital in South-South Nigeria. Methods: A retrospective study of 244 diabetic patients seen between January 2010 and June 2012.

  9. Ocular disorders in stroke patients in a tertiary hospital in Nigeria

    African Journals Online (AJOL)

    2015-08-06

    Aug 6, 2015 ... Abstract. Background: Stroke is a medical emergency of public health ... Aim: To determine the prevalence of ocular disorders in patients with stroke in a Tertiary Hospital in Nigeria. ... Risk factors include old age, high blood pressure, previous .... such as cataract, refractive errors, and age‑related changes.

  10. Familiarity with Technology among First-Year Students in Rwandan Tertiary Education

    Science.gov (United States)

    Byungura, Jean Claude; Hansson, Henrik; Muparasi, Mugabe; Ruhinda, Ben

    2018-01-01

    The more the students get experienced with technologies, the more the need for tertiary education systems to adopt innovative pedagogical strategies for accommodating different learning needs. Depending on students' prior experience with computer-based tools, they may have different degrees of familiarity with new technologies. At University of…

  11. Tertiary Students' Entrepreneurial Career Intentions of Entrepreneurship-Embedded Internship Programs

    Science.gov (United States)

    Chou, Chun-Mei; Shen, Chien-Hua; Hsiao, Hsi-Chi; Chen, Su-Chang

    2017-01-01

    This study examines 1630 tertiary students in regard to their entrepreneurial career intentions (ECIs) and their influencing factors. The findings may serve as academic reference for the development of entrepreneurship-related education. The results show that students' computer self-efficacy (CSE) has a significant direct effect on ECIs, and…

  12. Patterns of Antimicrobial Prescribing in a Tertiary Care Hospital in Oman

    Directory of Open Access Journals (Sweden)

    Abdulrahman Al-Yamani

    2016-01-01

    Full Text Available Objectives: Antimicrobial stewardship programs have been designed to measure and improve the use of antimicrobials to achieve optimal clinical outcomes and reduce bacterial resistance. The aim of this study was to review patterns of antimicrobial prescribing for hospitalized patients in the acute care setting and assess the appropriateness of antimicrobial use among prescribers in a tertiary care hospital in Oman. Methods: We conducted a retrospective audit of the appropriateness of antimicrobial prescribing in patients admitted to acute care settings in a tertiary care hospital in Oman over a four-week period (1 November to 28 November 2012. The data of all discharged patients were retrieved from the department databases. Patient records and prescriptions were reviewed by an infectious disease consultant. The rationality of antimicrobial use was evaluated, analyzed, and judged based on local standard guidelines and the experience of the evaluating consultant. Results: There were 178 patients discharged from acute medical teams over the study period. Sixty-four percent of the patients received a total of 287 antimicrobial agents during admission. The average number of antimicrobials prescribed per patient in those prescribed antimicrobials was 2.5±1.1. The most commonly prescribed antimicrobial agent was piperacillin/tazobactam. Most patients had infections from gram-negative organisms, and high rates of extended spectrum beta-lactamase producing organisms were observed. Cultures were obtained before antimicrobial initiation in 25% of patients. Variability in antimicrobial selection for common infections was observed. Conclusions: National guidelines for the management of common infections are needed to minimize the overuse and misuse of antimicrobial agents in tertiary care hospitals. A large surveillance study on antimicrobial prescribing appropriateness in different hospital settings is warranted.

  13. IRIS Toxicological Review of Ethyl Tertiary Butyl Ether (ETBE) (Public Comment Draft)

    Science.gov (United States)

    In September 2016, the U.S. Environmental Protection Agency's (USEPA) released the draft Integrated Risk Information System (IRIS) Toxicological Review of Ethyl Tertiary Butyl Ether (ETBE). Consistent with the 2013 IRIS Enhancements, draft IRIS assessments are released prior to e...

  14. Integrated complex care coordination for children with medical complexity: A mixed-methods evaluation of tertiary care-community collaboration

    Directory of Open Access Journals (Sweden)

    Cohen Eyal

    2012-10-01

    Full Text Available Abstract Background Primary care medical homes may improve health outcomes for children with special healthcare needs (CSHCN, by improving care coordination. However, community-based primary care practices may be challenged to deliver comprehensive care coordination to complex subsets of CSHCN such as children with medical complexity (CMC. Linking a tertiary care center with the community may achieve cost effective and high quality care for CMC. The objective of this study was to evaluate the outcomes of community-based complex care clinics integrated with a tertiary care center. Methods A before- and after-intervention study design with mixed (quantitative/qualitative methods was utilized. Clinics at two community hospitals distant from tertiary care were staffed by local community pediatricians with the tertiary care center nurse practitioner and linked with primary care providers. Eighty-one children with underlying chronic conditions, fragility, requirement for high intensity care and/or technology assistance, and involvement of multiple providers participated. Main outcome measures included health care utilization and expenditures, parent reports of parent- and child-quality of life [QOL (SF-36®, CPCHILD©, PedsQL™], and family-centered care (MPOC-20®. Comparisons were made in equal (up to 1 year pre- and post-periods supplemented by qualitative perspectives of families and pediatricians. Results Total health care system costs decreased from median (IQR $244 (981 per patient per month (PPPM pre-enrolment to $131 (355 PPPM post-enrolment (p=.007, driven primarily by fewer inpatient days in the tertiary care center (p=.006. Parents reported decreased out of pocket expenses (p© domains [Health Standardization Section (p=.04; Comfort and Emotions (p=.03], while total CPCHILD© score decreased between baseline and 1 year (p=.003. Parents and providers reported the ability to receive care close to home as a key benefit. Conclusions Complex

  15. Omalizumab use during pregnancy for CIU: a tertiary care experience.

    Science.gov (United States)

    Cuervo-Pardo, L; Barcena-Blanch, M; Radojicic, C

    2016-07-01

    The treatment of antihistamine and steroid resistant Chronic Idiopathic Urticaria (CIU) during pregnancy poses a challenge due to teratogenicity of immunosuppressants. Omalizumab is a recently FDA approved therapy for CIU and is classified as pregnancy category B. We present an initial series of subjects treated at a tertiary care center for antihistamine and steroid resistant CIU with omalizumab who became pregnant during therapy.

  16. Products of the reaction between methylene iodide and tertiary arsines

    International Nuclear Information System (INIS)

    Gigauri, R.D.; Arabuli, L.G.; Machaidze, Z.I.; Rusiya, M.Sh.

    2005-01-01

    Iodides of iodomethylenetrialkyl(aryl) arsonium were synthesized with high yields as a result of interaction between methylene iodide and tertiary arsines. Exchange reactions of the iodides prepared with lead(II) nitrate in water-alcohol solutions gave rise to formation of iodomethylenetrialkyl(aryl) arsonium nitrates. All the products prepared were characterized by data of elementary analysis, IR spectroscopy, conductometry and melting points measurements [ru

  17. Untitled

    African Journals Online (AJOL)

    lacustrine ... The geochemical studies of the Dilbi-Moye Basin indicate an organic richi oilshales .... Long-chain aliphatic (saturates) and alicyclic compounds are abundant in the oilshale ..... to the source from a non-marine-derived organic matter [37].

  18. IRIS Toxicological Review of Ethyl Tertiary Butyl Ether (ETBE) (External Review Draft)

    Science.gov (United States)

    The IRIS Toxicological Review of Ethyl Tertiary Butyl Ether (ETBE) was released for external peer review in June 2017. EPA’s Science Advisory Board’s (SAB) Chemical Assessment Advisory Committee (CAAC) will conduct a peer review of the scientific basis supporting the ETB...

  19. Maternal near miss and mortality in a tertiary care hospital in Rwanda

    NARCIS (Netherlands)

    Rulisa, S.; Umuziranenge, I.; Small, M; van Roosmalen, J.

    2015-01-01

    Background: To determine the prevalence and factors associated with severe ('near miss') maternal morbidity and mortality in the University Teaching Hospital of Kigali - Rwanda. Methods: We performed a cross sectional study of all women admitted to the tertiary care University Hospital in Kigali

  20. [Status of subjective well-being for medical staff in a tertiary hospital].

    Science.gov (United States)

    Deng, Yunlong; Liu, Yan; Xu, Shaorong; Zhao, Min; Li, Junping; Xiong, Yan

    2016-06-28

    To investigate the status of subjective well-being (SWB) for medical staffs who contact with patients directly in a tertiary hospital.
 Staffs from a tertiary hospital in Hunan province were investigated the SWB Scale (SWBS-cc20) from 2012 to 2014.
 The scores of SWB for medical staffs are high (81.67±12.33). Among the 10 sub-dimensions of SWB, medical staffs performed the best in family atmosphere, personal growth, and interpersonal adaptation, while performed the worst in physical health, mental health and material contentment. Title, job nature, education and occupation significantly affected the status of SWB. Staffs who directly connected with patients have less scores of SWB than those who do not (t=-4.80, Pmental health (OR=1.315, 95% CI 1.023 to 1.690, Phealth (OR=1.313, 95% CI 1.029 to 1.677, Pmental health and physical health.

  1. Evaluation of the long-term evolution of the groundwater system in the Mizunami area, Japan

    International Nuclear Information System (INIS)

    Mizuno, Takashi; Milodowski, Antoni E.; Iwatsuki, Teruki

    2011-01-01

    This study aimed to develop a methodology for assessing the evolution of the long-term groundwater system, using fracture-filling calcite. Fracture-filling calcite mineralization in deep (to ca. 1000 m) granitic rocks in Mizunami area, Japan, was studied. Four generations (I to IV) of calcite precipitation can be differentiated based on their paragenetic relationships, morphological and isotopic characteristics. Carbon and oxygen isotopic ratios suggest that the Calcite I is of hydrothermal origin. On the other hand, Calcite II, IV and III were precipitated from freshwater and marine water, respectively. The Mizunami Group strata (Tertiary), which overly the basement Toki granite (Cretaceous), were initially deposited in a lacustrine environment but later became marine. Lacustrine conditions were re-established during the deposition of the upper Seto Group (Quaternary). It is suggested that both of deposition of the marine upper part of the Mizunami Group and the precipitation of Calcite III were possibly related to the same transgression event. This was followed by the precipitation of Calcite IV during subsequent fresh water flushing of the earlier marine groundwater. In summary, integrated morphological, mineralogical, microchemical and isotopic analysis of multilayered calcite fracture mineralization provides valuable information to evaluate the long-term evolution of groundwater system. (author)

  2. Framework of Assessment for the Evaluation of Thinking Skills of Tertiary Level Students

    Directory of Open Access Journals (Sweden)

    Chan Swee Heng

    2015-10-01

    Full Text Available In the 21st century, students are required to master thinking skills in order to deal with many situations that arise in the tertiary environment which later would translate into the workplace. Nowadays, thinking skills play a vital role in tertiary education. To provide an approach for teachers, this paper identifies a 4-step model that can be implemented in test design with reference to Bloom’s Taxonomy for thinking skills. This model illustrates a feasible procedure of test construction built upon existing resource. The procedures can easily be applied to different fields of study. It provides an appropriate way for teachers who may want to add more ideas to their repertoire skills in addressing the learning of HOT (higher-order thinking skills. Keywords: thinking skills, Bloom’s Taxonomy, 4-step model

  3. Geodynamic control of the chemical composition of Tertiary continental arc magmas of Ecuador?

    International Nuclear Information System (INIS)

    Chiaradia, M.; Fontbote, L

    2001-01-01

    Whereas an abundant literature has been produced on the Tertiary magmatism of the Central Andes, no comparable studies exist for the Tertiary continental magmatism of the Northern Andes in general and of Ecuador in particular. In this contribution we present the first extensive data on lead and strontium isotopes of Paleocene to Pliocene magmatic rocks of Ecuador together with their major, trace and rare earth element geochemistry. The main interest of carrying out a geochemical and isotopic investigation on the magmatism of Ecuador is that, different from the Central Andes, Ecuador consists of several accreted terranes both of continental and oceanic affinity. The fragmented nature of the recently assembled crust of Ecuador, composed of lithologies such as Paleozoic schists, Triassic anatexites, and Jurassic metabasalts, could have variably affected the chemistry of the Ecuadorian magmas (au)

  4. Earthquake imprints on a lacustrine deltaic system: The Kürk Delta along the East Anatolian Fault (Turkey)

    KAUST Repository

    Hubert-Ferrari, Auré lia; El-Ouahabi, Meriam; Garcia-Moreno, David; Avsar, Ulas; Altınok, Sevgi; Schmidt, Sabine; Fagel, Nathalie; Ç ağatay, Namık

    2017-01-01

    Deltas contain sedimentary records that are not only indicative of water-level changes, but also particularly sensitive to earthquake shaking typically resulting in soft-sediment-deformation structures. The Kürk lacustrine delta lies at the south-western extremity of Lake Hazar in eastern Turkey and is adjacent to the seismogenic East Anatolian Fault, which has generated earthquakes of magnitude 7. This study re-evaluates water-level changes and earthquake shaking that have affected the Kürk Delta, combining geophysical data (seismic-reflection profiles and side-scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water-level changes provides a temporal framework for the depositional record. In addition to the common soft-sediment deformation documented previously, onland outcrops reveal a record of deformation (fracturing, tilt and clastic dykes) linked to large earthquake-induced liquefactions and lateral spreading. The recurrent liquefaction structures can be used to obtain a palaeoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the East Anatolian Fault. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake indicator. Based on radionuclide dating (Cs and Pb), two major sedimentary events were attributed to the ad 1874 to 1875 East Anatolian Fault earthquake sequence. Their sedimentological characteristics were determined by X-ray imagery, X-ray diffraction, loss-on-ignition, grain-size distribution and geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post-seismic sediment reworking of earthquake-triggered landslides.

  5. Analysis of arsenic speciation in mine contaminated lacustrine sediment using selective sequential extraction, HR-ICPMS and TEM

    Energy Technology Data Exchange (ETDEWEB)

    Haus, Kelly L. [Department of Geology, Phillips 157, University of Wisconsin - Eau Claire, Eau Claire, WI 54702-4004 (United States)], E-mail: khaus@vt.edu; Hooper, Robert L.; Strumness, Laura A.; Mahoney, J. Brian [Department of Geology, Phillips 157, University of Wisconsin - Eau Claire, Eau Claire, WI 54702-4004 (United States)

    2008-04-15

    In order to determine how As speciation in lacustrine sediment changes as a function of local conditions, sediment cores were taken from three lakes with differing hydrologic regimes and subjected to extensive chemical and TEM analysis. The lakes (Killarney, Thompson and Swan Lakes) are located within the Coeur d' Alene River system (northern Idaho, USA), which has been contaminated with trace metals and As, from over 100 a of sulfide mining. Previous analyses of these lakebed sediments have shown an extensive amount of contaminant metals and As associated with sub-{mu}m grains, making them extremely difficult to analyze using standard methods (scanning electron microscopy, X-ray diffraction). Transmission electron microscopy offers great advantages in spatial resolution and can be invaluable in determining As speciation when combined with other techniques. Data indicate that because of differences in local redox conditions, As speciation and stability is dramatically different in these lakes. Killarney and Thompson Lakes experience seasonal water-level fluctuations due to drawdown on a downstream dam, causing changes in O{sub 2} content in sediment exposed during drawdown. Swan Lake has relatively constant water levels as its only inlet is dammed. Consequently, Killarney and Thompson Lakes show an increase in labile As-bearing phases with depth, while Swan Lake data indicate stable As hosts throughout the sediment profile. Based on these observations it can be stated that As in lakebed sediments is much less mobile, and therefore less bioavailable, when water is kept at a constant level.

  6. Earthquake imprints on a lacustrine deltaic system: The Kürk Delta along the East Anatolian Fault (Turkey)

    KAUST Repository

    Hubert-Ferrari, Aurélia

    2017-01-05

    Deltas contain sedimentary records that are not only indicative of water-level changes, but also particularly sensitive to earthquake shaking typically resulting in soft-sediment-deformation structures. The Kürk lacustrine delta lies at the south-western extremity of Lake Hazar in eastern Turkey and is adjacent to the seismogenic East Anatolian Fault, which has generated earthquakes of magnitude 7. This study re-evaluates water-level changes and earthquake shaking that have affected the Kürk Delta, combining geophysical data (seismic-reflection profiles and side-scan sonar), remote sensing images, historical data, onland outcrops and offshore coring. The history of water-level changes provides a temporal framework for the depositional record. In addition to the common soft-sediment deformation documented previously, onland outcrops reveal a record of deformation (fracturing, tilt and clastic dykes) linked to large earthquake-induced liquefactions and lateral spreading. The recurrent liquefaction structures can be used to obtain a palaeoseismological record. Five event horizons were identified that could be linked to historical earthquakes occurring in the last 1000 years along the East Anatolian Fault. Sedimentary cores sampling the most recent subaqueous sedimentation revealed the occurrence of another type of earthquake indicator. Based on radionuclide dating (Cs and Pb), two major sedimentary events were attributed to the ad 1874 to 1875 East Anatolian Fault earthquake sequence. Their sedimentological characteristics were determined by X-ray imagery, X-ray diffraction, loss-on-ignition, grain-size distribution and geophysical measurements. The events are interpreted to be hyperpycnal deposits linked to post-seismic sediment reworking of earthquake-triggered landslides.

  7. Comparison of initial and tertiary centre second opinion reads of multiparametric magnetic resonance imaging of the prostate prior to repeat biopsy

    Energy Technology Data Exchange (ETDEWEB)

    Hansen, Nienke L. [University Hospital RWTH Aachen, Department of Diagnostic and Interventional Radiology, Aachen (Germany); Addenbrooke' s Hospital and University of Cambridge, CamPARI Clinic, Cambridge (United Kingdom); Koo, Brendan C.; Gallagher, Ferdia A. [Addenbrooke' s Hospital and University of Cambridge, CamPARI Clinic, Cambridge (United Kingdom); Addenbrooke' s Hospital and University of Cambridge, Department of Radiology, Cambridge (United Kingdom); Warren, Anne Y. [Addenbrooke' s Hospital and University of Cambridge, CamPARI Clinic, Cambridge (United Kingdom); Addenbrooke' s Hospital, Department of Pathology, Cambridge (United Kingdom); Doble, Andrew; Gnanapragasam, Vincent; Bratt, Ola; Kastner, Christof [Addenbrooke' s Hospital and University of Cambridge, CamPARI Clinic, Cambridge (United Kingdom); Addenbrooke' s Hospital, Department of Urology, Cambridge (United Kingdom); Barrett, Tristan [Addenbrooke' s Hospital and University of Cambridge, CamPARI Clinic, Cambridge (United Kingdom); Addenbrooke' s Hospital and University of Cambridge, Department of Radiology, Cambridge (United Kingdom); University of Cambridge School of Clinical Medicine, Department of Radiology, Box 218, Cambridge (United Kingdom)

    2017-06-15

    To investigate the value of second-opinion evaluation of multiparametric prostate magnetic resonance imaging (MRI) by subspecialised uroradiologists at a tertiary centre for the detection of significant cancer in transperineal fusion prostate biopsy. Evaluation of prospectively acquired initial and second-opinion radiology reports of 158 patients who underwent MRI at regional hospitals prior to transperineal MR/untrasound fusion biopsy at a tertiary referral centre over a 3-year period. Gleason score (GS) 7-10 cancer, positive predictive value (PPV) and negative (NPV) predictive value (±95 % confidence intervals) were calculated and compared by Fisher's exact test. Disagreement between initial and tertiary centre second-opinion reports was observed in 54 % of cases (86/158). MRIs had a higher NPV for GS 7-10 in tertiary centre reads compared to initial reports (0.89 ± 0.08 vs 0.72 ± 0.16; p = 0.04), and a higher PPV in the target area for all cancer (0.61 ± 0.12 vs 0.28 ± 0.10; p = 0.01) and GS 7-10 cancer (0.43 ± 0.12 vs 0.2 3 ± 0.09; p = 0.02). For equivocal suspicion, the PPV for GS 7-10 was 0.12 ± 0.11 for tertiary centre and 0.11 ± 0.09 for initial reads; p = 1.00. Second readings of prostate MRI by subspecialised uroradiologists at a tertiary centre significantly improved both NPV and PPV. Reporter experience may help to reduce overcalling and avoid overtargeting of lesions. (orig.)

  8. Word-of-Mouth amongst Students at a New Zealand Tertiary Institution

    Science.gov (United States)

    Warring, Susan

    2013-01-01

    Purpose: The aim of this case study was to investigate the extent of word-of-mouth influence amongst international students at a New Zealand tertiary institution and to review the literature for a valid and reliable conceptualisation and measurement of word-of-mouth. Design/methodology/approach: Literature suggests that opinion-leading and seeking…

  9. A Price Comparison of Antibiotics in a Tertiary Healthcare Facility in ...

    African Journals Online (AJOL)

    A large proportion of the population in developing countries including Nigeria lacks regular access to medicines for disease treatment. This has been linked to the high cost of these drugs, antibiotics inclusive. We undertook to compare the prices of antibiotics prescribed in the pediatric ward of a tertiary health-care facility in ...

  10. Culture of Safety among Nurses in a Tertiary Teaching Hospital in ...

    African Journals Online (AJOL)

    Purpose: To assess the culture of safety among nurses in a tertiary teaching hospital in Saudi Arabia. Methods: A cross-sectional survey was conducted in King Khaled University Hospital in Riyadh, Saudi Arabia. A random sample of 492 nurses was included in the survey using a pre-validated instrument, Safety Attitudes ...

  11. Effects of Aeration, Vegetation, and Iron Input on Total P Removal in a Lacustrine Wetland Receiving Agricultural Drainage

    Directory of Open Access Journals (Sweden)

    Yuanchun Zou

    2018-01-01

    Full Text Available Utilizing natural wetlands to remove phosphorus (P from agricultural drainage is a feasible approach of protecting receiving waterways from eutrophication. However, few studies have been carried out about how these wetlands, which act as buffer zones of pollutant sinks, can be operated to achieve optimal pollutant removal and cost efficiency. In this study, cores of sediments and water were collected from a lacustrine wetland of Lake Xiaoxingkai region in Northeastern China, to produce a number of lab-scale wetland columns. Ex situ experiments, in a controlled environment, were conducted to study the effects of aeration, vegetation, and iron (Fe input on the removal of total P (TP and values of dissolved oxygen (DO and pH of the water in these columns. The results demonstrated the links between Fe, P and DO levels. The planting of Glyceria spiculosa in the wetland columns was found to increase DO and pH values, whereas the Fe:P ratio was found to inversely correlate to the pH values. The TP removal was the highest in aerobic and planted columns. The pattern of temporal variation of TP removals matched first-order exponential growth model, except for under aerobic condition and with Fe:P ratio of 10:1. It was concluded that Fe introduced into a wetland by either surface runoff or agricultural drainage is beneficial for TP removal from the overlying water, especially during the growth season of wetland vegetation.

  12. Evaluation of the Catahoula Formation as a source rock for uranium mineralization, with emphasis on East Texas

    International Nuclear Information System (INIS)

    Ledger, E.B. Jr.

    1981-01-01

    The Oligocene/Miocene Catahoula Formation of the Texas coastal plain is a fluvial and lacustrine volcaniclastic unit composed of normal fluvial material mixed with distal rhyolitic air-fall ash and, in the lower coastal plain, also stream-transported erosion detritus from the volcanic source area in Trans-Pecos Texas and adjacent northern Mexico, the nearest source of appropriate age and chemical affinity. Pedogenic and shallow-burial alteration of the labile volcanic glass component of the sediment resulted in ubiquitous secondary montmorillonite and solubilization of elements which are mobile in a HCO 3 -rich, near-surface environment. Primary uranium present in the glass at 5 to 6 ppMU was similarly mobilized and, under favorable conditions, accumulated by precipitation of tetravalent uranium phases at sites of lower Eh. Known economic deposits are restricted to the lower coastal plain where there has been uranium production for more than twenty years. Although there are differences between the productive lower coastal plain and the middle and upper as to stratigraphy, mineralogical composition, and weathering history, labile volcaniclastic material and its alteration products are abundant throughout the Catahoula outcrop and shallow subsurface in Texas. To provide a geochemical basis of comparison, samples from the upper, middle, and lower Texas coastal plain and the Trans-Pecos source area were analyzed for uranium, thorium, potassium, rubidium, strontium, zirconium, and titanium. These include both labile and immobile elements. Typical levels of these elements in the source material and relatively unaltered Catahoula volcanic glass allows estimation of uranium loss from highly altered sections based on their immobile element content

  13. Global trends in nuclear education at the tertiary level

    International Nuclear Information System (INIS)

    Kemeny, L.G.

    2001-01-01

    The public perception of nuclear science and engineering and the nuclear industry is today, primarily shaped by radical greens, nuclear-opponents, the media and socio-political opportunists. Only countries with a well diversified tertiary education system embracing all aspects of nuclear science and engineering can counter efficiently the pseudo-science and socio-political manipulation which has severely restricted nuclear energy development over the past three decades. National laboratories alone find this task extremely difficult, if not impossible

  14. The evaluation of tertiary institution service quality using HiEdQUAL ...

    African Journals Online (AJOL)

    One of the most important decisions that affect the future of young students is a decision as regards a Tertiary Institution of choice. In making such a decision, a number of factors are required which include service quality. Service quality consists of different attributes and many of them are intangible and difficult to measure, ...

  15. Nature of work and Librarians' choice of library profession in tertiary ...

    African Journals Online (AJOL)

    The study investigated the nature of work and Librarians' choice of library profession as a career in tertiary institutions in Akwa Ibom and Cross River States of Nigeria . It also investigated nature of work as it relates with librarians' choice of library profession as a career. The survey design was used for the study.

  16. Analysis on sequence stratigraphy and depositional systems of Mangbang formation, upper tertiary in Longchuanjiang basin

    International Nuclear Information System (INIS)

    Sun Zexuan; Yao Yifeng; Chen Yong; Li Guoxin

    2004-01-01

    Longchuanjiang basin is a small Cenozoic intramontane down-faulted basin. This paper, combining the Pliocene structure, the volcanic activities and the sedimentation of the basin, analyses the sequence stratigraphy and the depositional systems of Mangbang formation (the cover of the basin). Based on the analysis of depositional systems of Mangbang formation, the depositional pattern of Pliocene in Longchuanjiang basin is set up. It is suggested that because of the fast accumulation in early down-faulted zone during Pliocene time, the alluvial fan depositional system was dominated at that time. During the middle-late period, the alluvial fan entered the lake forming a combination of fan-fandelta-lacustrine depositional systems. Authors propose a view point that the formation of Mangbang formation sequence was constrained by multistage tectonic movement, and three structural sequences were established, and system tracts were divided. (authors)

  17. Geology of drill hole UE25p No. 1: A test hole into pre-Tertiary rocks near Yucca Mountain, southern Nevada

    International Nuclear Information System (INIS)

    Carr, M.D.; Waddell, S.J.; Vick, G.S.; Stock, J.M.; Monsen, S.A.; Harris, A.G.; Cork, B.W.; Byers, F.M. Jr.

    1986-01-01

    Yucca Mountain in southern Nye County, Nevada, has been proposed as a potential site for the underground disposal of high-level nuclear waste. An exploratory drill hole designated UE25p No. 1 was drilled 3 km east of the proposed repository site to investigate the geology and hydrology of the rocks that underlie the Tertiary volcanic and sedimentary rock sequence forming Yucca Mountain. Silurian dolomite assigned to the Roberts Mountain and Lone Mountain Formations was intersected below the Tertiary section between a depth of approximately 1244 m (4080 ft) and the bottom of the drill hole at 1807 m (5923 ft). These formations are part of an important regional carbonate aquifer in the deep ground-water system. Tertiary units deeper than 1139 m (3733 ft) in drill hole UE25p No. 1 are stratigraphically older than any units previously penetrated by drill holes at Yucca Mountain. These units are, in ascending order, the tuff of Yucca Flat, an unnamed calcified ash-flow tuff, and a sequence of clastic deposits. The upper part of the Tertiary sequence in drill hole UE25p No. 1 is similar to that found in other drill holes at Yucca Mountain. The Tertiary sequence is in fault contact with the Silurian rocks. This fault between Tertiary and Paleozoic rocks may correlate with the Fran Ridge fault, a steeply westward-dipping fault exposed approximately 0.5 km east of the drill hole. Another fault intersects UE25p No. 1 at 873 m (2863 ft), but its surface trace is concealed beneath the valley west of the Fran Ridge fault. The Paintbrush Canyon fault, the trace of which passes less than 100 m (330 ft) east of the drilling site, intersects drill hole UE25p No. 1 at a depth of approximately 78 m (255 ft). The drill hole apparently intersected the west flank of a structural high of pre-Tertiary rocks, near the eastern edge of the Crater Flat structural depression

  18. Evaluating Late Cretaceous OAEs and the influence of marine incursions on organic carbon burial in an expansive East Asian paleo-lake

    Science.gov (United States)

    Jones, Matthew M.; Ibarra, Daniel E.; Gao, Yuan; Sageman, Bradley B.; Selby, David; Chamberlain, C. Page; Graham, Stephan A.

    2018-02-01

    Expansive Late Cretaceous lacustrine deposits of East Asia offer unique stratigraphic records to better understand regional responses to global climate events, such as oceanic anoxic events (OAEs), and terrestrial organic carbon burial dynamics. This study presents bulk organic carbon isotopes (δ13Corg), elemental concentrations (XRF), and initial osmium ratios (187Os/188Os, Osi) from the Turonian-Coniacian Qingshankou Formation, a ∼5 Ma lacustrine mudstone succession in the Songliao Basin of northeast China. A notable δ13Corg excursion (∼ + 2.5‰) in organic carbon-lean Qingshankou Members 2-3 correlates to OAE3 in the Western Interior Basin (WIB) of North America within temporal uncertainty of high-precision age models. Decreases in carbon isotopic fractionation (Δ13C) through OAE3 in the WIB and Songliao Basin, suggest that significantly elevated global rates of organic carbon burial drew down pCO2, likely cooling climate. Despite this, Osi chemostratigraphy demonstrates no major changes in global volcanism or weathering trends through OAE3. Identification of OAE3 in a lake system is consistent with lacustrine records of other OAEs (e.g., Toarcian OAE), and underscores that terrestrial environments were sensitive to climate perturbations associated with OAEs. Additionally, the relatively radiogenic Osi chemostratigraphy and XRF data confirm that the Qingshankou Formation was deposited in a non-marine setting. Organic carbon-rich intervals preserve no compelling Osi evidence for marine incursions, an existing hypothesis for generating Member 1's prolific petroleum source rocks. Based on our results, we present a model for water column stratification and source rock deposition independent of marine incursions, detailing dominant biogeochemical cycles and lacustrine organic carbon burial mechanisms.

  19. The accuracy of nurse performance of the triage process in a tertiary ...

    African Journals Online (AJOL)

    The accuracy of nurse performance of the triage process in a tertiary hospital emergency department in Gauteng Province, South Africa. ... discriminator use, numerical miscalculations and other human errors. Quality control and quality assurance measures must target training in these areas to minimise mis-triage in the ED.

  20. Administrative Strategies of Departmental Heads as Determinants for the Effective Management of Human Resources in Tertiary Institutions in Delta State, Nigeria

    Science.gov (United States)

    Osakwe, Regina N.

    2015-01-01

    This study investigated administrative strategies of departmental heads as determinants of effective management of human resources in tertiary institutions. Four research questions were asked and four hypotheses were formulated to guide the study. As a descriptive survey, the population comprised all the eight tertiary institutions in the state…

  1. Accessibility and Affordability of Tertiary Education in Brazil, Colombia, Mexico and Peru within a Global Context. Policy Research Working Paper 4517

    Science.gov (United States)

    Murakami, Yuki; Blom, Andreas

    2008-01-01

    This paper examines the financing of tertiary education in Brazil, Colombia, Mexico and Peru, comparing the affordability and accessibility of tertiary education with that in high-income countries. To measure affordability, the authors estimate education costs, living costs, grants, and loans. Further, they compute the participation rate,…

  2. Depositional environments and cyclo- and chronostratigraphy of uppermost Carboniferous-Lower Triassic -lacustrine deposits, southern Bogda Mountains, NW China - A terrestrfluvialial paleoclimatic record of mid-latitude NE Pangea

    Science.gov (United States)

    Yang, W.; Feng, Q.; Liu, Yajing; Tabor, N.; Miggins, D.; Crowley, J.L.; Lin, J.; Thomas, S.

    2010-01-01

    Two uppermost Carboniferous–Lower Triassic fluvial–lacustrine sections in the Tarlong–Taodonggou half-graben, southern Bogda Mountains, NW China, comprise a 1834 m-thick, relatively complete sedimentary and paleoclimatic record of the east coast of mid-latitude NE Pangea. Depositional environmental interpretations identified three orders (high, intermediate, and low) of sedimentary cycles. High-order cycles (HCs) have five basic types, including fluvial cycles recording repetitive changes of erosion and deposition and lacustrine cycles recording repetitive environmental changes associated with lake expansion and contraction. HCs are grouped into intermediate-order cycles (ICs) on the basis of systematic changes of thickness, type, and component lithofacies of HCs. Nine low-order cycles (LCs) are demarcated by graben-wide surfaces across which significant long-term environmental changes occurred. A preliminary cyclostratigraphic framework provides a foundation for future studies of terrestrial climate, tectonics, and paleontology in mid-latitude NE Pangea.Climate variabilities at the intra-HC, HC, IC, and LC scales were interpreted from sedimentary and paleosol evidence. Four prominent climatic shifts are present: 1) from the humid–subhumid to highly-variable subhumid–semiarid conditions at the beginning of Sakamarian; 2) from highly-variable subhumid–semiarid to humid–subhumid conditions across the Artinskian-Capitanian unconformity; 3) from humid–subhumid to highly-variable subhumid–semiarid conditions at early Induan; and 4) from the highly-variable subhumid–semiarid to humid–subhumid conditions across the Olenekian-Anisian unconformity. The stable humid–subhumid condition from Lopingian to early Induan implies that paleoclimate change may not have been the cause of the end-Permian terrestrial mass extinction. A close documentation of the pace and timing of the extinction and exploration of other causes are needed. In addition, the

  3. Tertiary education and its association with mental health indicators and educational factors among Arctic young adults: the NAAHS cohort study

    Directory of Open Access Journals (Sweden)

    Elisabeth Valmyr Bania

    2016-09-01

    Full Text Available Background: Completed tertiary education is closely associated with employment and influences income, health and personal well-being. Objective: The purpose of the study is to explore predictors for completed tertiary education among indigenous Sami and non-indigenous young people in relation to mental health indicators and educational factors in sociocultural rural and urban contexts across the Arctic part of Norway. Design: The Norwegian Arctic Adolescent Health Study (NAAHS is a cross-sectional, school-based survey that was conducted in 2003–2005. Of all 5,877 10th graders (aged 15–16 years in north Norway, 83% from all 87 municipalities participated; 450 (9.2% reported indigenous Sami ethnicity, and 304 (6.2% reported Laestadian affiliation. Data from NAAHS were merged with registry data from the National Education Database and Norwegian Patient Register for 3,987 adolescents who gave their consent for follow-up studies. Results: Completion of upper secondary school is the only common predictor of a completed tertiary education degree for both genders. Among females, conduct problems was a significant predictor of lower level education, typically vocational professions, while among males severe mental health problems requiring treatment by the specialist health care system reduced the opportunity to complete tertiary education at intermediate and higher level. Parental higher educational level was associated with less lower education among females and less higher education among males. Men residing in the northernmost and remote areas were less likely to complete education on higher level. Males’ completion of higher level education was strongly but not significantly associated (p=0.057 with higher average marks in lower secondary school. Conclusions: The gender differences found in this study emphasize the need for gender-specific interventions to encourage, support and empower young people to attend and complete tertiary education

  4. Tertiary education and its association with mental health indicators and educational factors among Arctic young adults: the NAAHS cohort study.

    Science.gov (United States)

    Bania, Elisabeth Valmyr; Kvernmo, Siv Eli

    2016-01-01

    Background Completed tertiary education is closely associated with employment and influences income, health and personal well-being. Objective The purpose of the study is to explore predictors for completed tertiary education among indigenous Sami and non-indigenous young people in relation to mental health indicators and educational factors in sociocultural rural and urban contexts across the Arctic part of Norway. Design The Norwegian Arctic Adolescent Health Study (NAAHS) is a cross-sectional, school-based survey that was conducted in 2003-2005. Of all 5,877 10th graders (aged 15-16 years) in north Norway, 83% from all 87 municipalities participated; 450 (9.2%) reported indigenous Sami ethnicity, and 304 (6.2%) reported Laestadian affiliation. Data from NAAHS were merged with registry data from the National Education Database and Norwegian Patient Register for 3,987 adolescents who gave their consent for follow-up studies. Results Completion of upper secondary school is the only common predictor of a completed tertiary education degree for both genders. Among females, conduct problems was a significant predictor of lower level education, typically vocational professions, while among males severe mental health problems requiring treatment by the specialist health care system reduced the opportunity to complete tertiary education at intermediate and higher level. Parental higher educational level was associated with less lower education among females and less higher education among males. Men residing in the northernmost and remote areas were less likely to complete education on higher level. Males' completion of higher level education was strongly but not significantly associated (p=0.057) with higher average marks in lower secondary school. Conclusions The gender differences found in this study emphasize the need for gender-specific interventions to encourage, support and empower young people to attend and complete tertiary education. Young females with conduct

  5. Tertiary education and its association with mental health indicators and educational factors among Arctic young adults: the NAAHS cohort study

    Science.gov (United States)

    Bania, Elisabeth Valmyr; Kvernmo, Siv Eli

    2016-01-01

    Background Completed tertiary education is closely associated with employment and influences income, health and personal well-being. Objective The purpose of the study is to explore predictors for completed tertiary education among indigenous Sami and non-indigenous young people in relation to mental health indicators and educational factors in sociocultural rural and urban contexts across the Arctic part of Norway. Design The Norwegian Arctic Adolescent Health Study (NAAHS) is a cross-sectional, school-based survey that was conducted in 2003–2005. Of all 5,877 10th graders (aged 15–16 years) in north Norway, 83% from all 87 municipalities participated; 450 (9.2%) reported indigenous Sami ethnicity, and 304 (6.2%) reported Laestadian affiliation. Data from NAAHS were merged with registry data from the National Education Database and Norwegian Patient Register for 3,987 adolescents who gave their consent for follow-up studies. Results Completion of upper secondary school is the only common predictor of a completed tertiary education degree for both genders. Among females, conduct problems was a significant predictor of lower level education, typically vocational professions, while among males severe mental health problems requiring treatment by the specialist health care system reduced the opportunity to complete tertiary education at intermediate and higher level. Parental higher educational level was associated with less lower education among females and less higher education among males. Men residing in the northernmost and remote areas were less likely to complete education on higher level. Males’ completion of higher level education was strongly but not significantly associated (p=0.057) with higher average marks in lower secondary school. Conclusions The gender differences found in this study emphasize the need for gender-specific interventions to encourage, support and empower young people to attend and complete tertiary education. Young females with

  6. Pre-Messinian (Sub-Salt Source-Rock Potential on Back-Stop Basins of the Hellenic Trench System (Messara Basin, Central Crete, Greece

    Directory of Open Access Journals (Sweden)

    Maravelis A.

    2016-01-01

    Full Text Available The Greek part of the Mediterranean Ridge suggests, in terms of its hydrocarbon potential, further frontier exploration. The geological similarities between its prolific portions, within the Cyprus and Egyptian Exclusive Economic Zones, indicate possible recoverable natural gas reserves in its Greek portion. Nevertheless it lacks of systematic frontier exploration although direct petroleum indicators occur. Active mud volcanoes on the Mediterranean Ridge, still emitting concurrently gas and gas hydrates, have not been yet assessed even though are strongly related to hydrocarbon occurrence worldwide (Caspian Sea, Gulf of Mexico, Western African Basin, Trinidad-Tobago, the Nile Cone. For this reason, the source rock potential of the Late Miocene lacustrine deposits on a backstop basin of the Hellenic Trench System (Messara Basin, Crete, Greece, was studied. The obtained pyrolysis data indicate that the containing organic matter is present in sufficient abundance and with good enough quality to be regarded as potential source rocks. The observed type III kerogen suggests gas generation potential. Although indications of higher thermal evolution occur the studied rocks suggest low maturation levels. The biogenic gas seeps in the studied research well further demonstrate the regional gas generation potential.

  7. Failure mechanism and supporting measures for large deformation of Tertiary deep soft rock

    Institute of Scientific and Technical Information of China (English)

    Guo Zhibiao; Wang Jiong; Zhang Yuelin

    2015-01-01

    The Shenbei mining area in China contains typical soft rock from the Tertiary Period. As mining depths increase, deep soft rock roadways are damaged by large deformations and constantly need to be repaired to meet safety requirements, which is a great security risk. In this study, the characteristics of deformation and failure of typical roadway were analyzed, and the fundamental reason for the roadway deformation was that traditional support methods and materials cannot control the large deformation of deep soft rock. Deep soft rock support technology was developed based on constant resistance energy absorption using constant resistance large deformation bolts. The correlative deformation mechanisms of surrounding rock and bolt were analyzed to understand the principle of constant resistance energy absorption. The new technology works well on-site and provides a new method for the excavation of roadways in Tertiary deep soft rock.

  8. Organic petrology and geochemistry of mudrocks from the lacustrine Lucaogou Formation, Santanghu Basin, northwest China: Application to lake basin evolution

    Science.gov (United States)

    Hackley, Paul C.; Fishman, Neil; Wu, Tao; Baugher, Gregory

    2016-01-01

    Exploration for tight oil in the frontier Santanghu Basin of northwest China has resulted in recent commercial discoveries sourced from the lacustrine Upper Permian Lucaogou Formation, already considered a “world class source rock” in the Junggar Basin to the west. Here we apply an integrated analytical program to carbonate-dominated mudrocks from the Lucaogou Formation in Santanghu Basin to document the nature of organic matter (OM) in the context of an evolving lake system. The organic-rich samples (TOC 2.8–11.4 wt%; n = 10) were widely spaced from an ~ 200 m cored section, interpreted from textural and mineralogical evidence to document transition from a lower under-filled to an overlying balanced-filled lake. Organic matter is dominated by moderate to strongly fluorescent amorphous material with Type I geochemical signature (HI values 510–755; n = 10) occurring in a continuum from lamellar stringers, 10–20 μm thick, some ≥ 1 mm in length (possible microbial mat; preserved only in lower under-filled section) to finely-disseminated amorphous groundmass intimately intermixed with mineral matrix. Biomarkers for methanotrophs and photosynthetic cyanobacteria indicate a complex microbial consortium. A unicellular prasinophyte green alga(?), similar to Tasmanites in marine rocks, is present as discrete flattened discs 50–100 μm in diameter. Type III OM including vitrinite (some fluorescent) and inertinite also is abundant. Solid bitumen, indicating local kerogen conversion, fills voids and occurs throughout the cored section. Vitrinite reflectance values are 0.47–0.58%, consistent with strong OM fluorescence but may be “suppressed”. Other proxies, e.g., biomarker parameters, indicate the Lucaogou Formation is in the early oil window at this location. On average, slightly more amorphous OM and telalginite are present in the lower section, consistent with a shallow, stratified, saline environment with low sediment dilution. More

  9. Tertiary alphabet for the observable protein structural universe.

    Science.gov (United States)

    Mackenzie, Craig O; Zhou, Jianfu; Grigoryan, Gevorg

    2016-11-22

    Here, we systematically decompose the known protein structural universe into its basic elements, which we dub tertiary structural motifs (TERMs). A TERM is a compact backbone fragment that captures the secondary, tertiary, and quaternary environments around a given residue, comprising one or more disjoint segments (three on average). We seek the set of universal TERMs that capture all structure in the Protein Data Bank (PDB), finding remarkable degeneracy. Only ∼600 TERMs are sufficient to describe 50% of the PDB at sub-Angstrom resolution. However, more rare geometries also exist, and the overall structural coverage grows logarithmically with the number of TERMs. We go on to show that universal TERMs provide an effective mapping between sequence and structure. We demonstrate that TERM-based statistics alone are sufficient to recapitulate close-to-native sequences given either NMR or X-ray backbones. Furthermore, sequence variability predicted from TERM data agrees closely with evolutionary variation. Finally, locations of TERMs in protein chains can be predicted from sequence alone based on sequence signatures emergent from TERM instances in the PDB. For multisegment motifs, this method identifies spatially adjacent fragments that are not contiguous in sequence-a major bottleneck in structure prediction. Although all TERMs recur in diverse proteins, some appear specialized for certain functions, such as interface formation, metal coordination, or even water binding. Structural biology has benefited greatly from previously observed degeneracies in structure. The decomposition of the known structural universe into a finite set of compact TERMs offers exciting opportunities toward better understanding, design, and prediction of protein structure.

  10. Water and rock geochemistry, geologic cross sections, geochemical modeling, and groundwater flow modeling for identifying the source of groundwater to Montezuma Well, a natural spring in central Arizona

    Science.gov (United States)

    Johnson, Raymond H.; DeWitt, Ed; Wirt, Laurie; Arnold, L. Rick; Horton, John D.

    2011-01-01

    The National Park Service (NPS) seeks additional information to better understand the source(s) of groundwater and associated groundwater flow paths to Montezuma Well in Montezuma Castle National Monument, central Arizona. The source of water to Montezuma Well, a flowing sinkhole in a desert setting, is poorly understood. Water emerges from the middle limestone facies of the lacustrine Verde Formation, but the precise origin of the water and its travel path are largely unknown. Some have proposed artesian flow to Montezuma Well through the Supai Formation, which is exposed along the eastern margin of the Verde Valley and underlies the Verde Formation. The groundwater recharge zone likely lies above the floor of the Verde Valley somewhere to the north or east of Montezuma Well, where precipitation is more abundant. Additional data from groundwater, surface water, and bedrock geology are required for Montezuma Well and the surrounding region to test the current conceptual ideas, to provide new details on the groundwater flow in the area, and to assist in future management decisions. The results of this research will provide information for long-term water resource management and the protection of water rights.

  11. The profile of meningitis in a tertiary paediatric hospital in South Africa

    African Journals Online (AJOL)

    Background. Meningitis in children is a major health problem worldwide, leading to high rates of mortality and morbidity. Objectives. To describe the profile of patients treated for meningitis at a leading tertiary paediatric hospital (Red Cross War Memorial Children's Hospital) in South Africa. Methods. This study describes all ...

  12. Synthesis of benzannelated sultams by intramolecular Pd-catalyzed arylation of tertiary sulfonamides

    Directory of Open Access Journals (Sweden)

    Valentin A. Rassadin

    2017-09-01

    Full Text Available A new and efficient approach to five- and six-membered benzannelated sultams by intramolecular C-arylation of tertiary 1-(methoxycarbonylmethanesulfonamides under palladium catalysis is described. In case of the α-toluenesulfonamide derivative, an unexpected formation of a 2,3-diarylindole was observed under the same conditions.

  13. Adapting the Academic Motivation Scale for Use in Pre-Tertiary Mathematics Classrooms

    Science.gov (United States)

    Lim, Siew Yee; Chapman, Elaine

    2015-01-01

    The Academic Motivation Scale (AMS) is a comprehensive and widely used instrument for assessing motivation based on the self-determination theory. Currently, no such comprehensive instrument exists to assess the different domains of motivation (stipulated by the self-determination theory) in mathematics education at the pre-tertiary level (grades…

  14. Characterization of molybdenum interfacial crud in a uranium mill that employs tertiary-amine solvent extraction

    International Nuclear Information System (INIS)

    Moyer, B.; McDowell, W.J.

    1983-01-01

    In the present work, samples of a molybdenum-caused green gummy interfacial crud from an operating western US uranium mill have been physically and chemically examined. Formaton of cruds of this description has been a long-standing problem in the use of tertiary amine solvent extraction for the recovery of uranium from low-grade ores (Amex Process). The crud is essentially an organic-continuous dispersion containing about 10 wt % aqueous droplets and about 37 wt % greenish-yellow crystalline solids suspended in kerosene-amine process solvent. The greenish-yellow crystals were found to be a previously unknown double salt of tertiary amine molybdophosphate with three tertiary amine chlorides having the empirical formula (R 3 NH) 3 [PMo 12 O 40 ].3(R 3 NH)Cl. To confirm the identification of the compound, a pure trioctylamine (TOA) analog was synthesized. In laboratory extraction experiments, it was demonstrated that organic-soluble amine molydophosphate forms slowly upon contact of TOA solvent with dilute sulfuric acid solutions containing low concentrations of molybdate and phosphate. If the organic solutions of amine molybdophosphate were then contacted with aqueous NaCl solutions, a greenish-yellow precipitate of (TOAH) 3 [PMo 12 O 40 ].3(TOAH)Cl formed at the interface. The proposed mechanism for the formation of the crud under process conditions involves build up of molybdenum in the solvent, followed by reaction with extracted phosphate to give dissolved amine molybdophosphate. The amine molybdophosphate then co-crystallizes with amine chloride, formed during the stripping cycle, to give the insoluble double salt, which precipitates as a layer of small particles at the interface. The proposed solution to the problem is the use of branched-chain, instead of straight-chain, tertiary amine extractants under the expectation that branching would increase the solubility of the double salt. 2 figures, 5 tables

  15. Level of health care and services in a tertiary health setting in Nigeria

    African Journals Online (AJOL)

    Level of health care and services in a tertiary health setting in Nigeria. ... Background: There is a growing awareness and demand for quality health care across the world; hence the ... Doctors and nurses formed 64.3% of the study population.

  16. IRIS Toxicological Review of Ethyl Tertiary Butyl Ether (ETBE) (External Review Draft, 2009)

    Science.gov (United States)

    EPA is conducting a peer review and public comment of the scientific basis supporting the human health hazard and dose-response assessment of ethyl tertiary butyl ether (ETBE) that when finalized will appear on the Integrated Risk Information System (IRIS) database.

  17. Intense acidic volcanism at the Cretaceous-Tertiary boundary

    International Nuclear Information System (INIS)

    Javoy, M.; Courtillot, V.

    1989-01-01

    A 87 Sr/ 86 Sr spike in seawater strontium with amplitude 2 x 10 -4 and duration of order 2 Ma is superimposed on longer-term variations at the Cretaceous-Tertiary boundary. The anomaly has been attributed to increased continental runoff due either to meteorite impact-related acid rain or sea-level regression. We speculate here that the spike could have resulted from intense, explosive acid volcanism preceding the development of the Deccan traps. A good model, both in tectonic position and geochemical characteristics, for these as yet elusive acidic products is provided by granites in the Seychelles Islands and particularly Mahe. (orig.)

  18. Neoglacial fluctuations of terrestrial, tidewater, and calving lacustrine glaciers, Blackstone-Spencer Ice Complex, Kenai Mountains, Alaska

    Science.gov (United States)

    Crossen, Kristine June

    1997-12-01

    The glaciers surrounding the Blackstone-Spencer Ice Complex display a variety of termini types: Tebenkov, Spencer, Bartlett, Skookum, Trail, Burns, Shakespeare, Marquette, Lawrence, and Ripon glaciers end in terrestrial margins; Blackstone and Beloit glaciers have tidewater termini; and Portage Glacier has a calving lacustrine margin. In addition, steep temperature and precipitation gradients exist across the ice complex from the maritime environment of Prince William Sound to the colder, drier interior. The Neoglacial history of Tebenkov Glacier, as based on overrun trees near the terminus, shows advances ca. 250- 430 AD (calibrated date), ca. 1215-1275 AD (calibrated date), and ca. 1320-1430 AD (tree ring evidence), all intervals of glacier advance around the Gulf of Alaska. However, two tidewater glaciers in Blackstone Bay retreated from their outermost moraines by 1350 AD, apparently asynchronously with respect to the regional climate signal. The most extensive Kenai Mountain glacier expansions during Neoglaciation occurred in the late Little Ice Age. The outermost moraines are adjacent to mature forest stands and bog peats that yield dates as old as 5,600 BP. Prince William Sound glaciers advanced during two Little Ice Age cold periods, 1380-1680 and 1830-1900 AD. The terrestrial glaciers around the Blackstone-Spencer Ice Complex all built moraines during the 19th century and began retreating between 1875 and 1900 AD. Portage and Burns glaciers began retreating between 1790 and 1810 AD, but their margins remained close to the outermost moraines during the 19th century. Regional glacier fluctuations are broadly synchronous in the Gulf of Alaska region. With the exception of the two tidewater glaciers in Blackstone Bay, all glaciers in the Kenai Mountains, no matter their sizes, altitudes, orientations, or types of margins, retreated at the end of the Little Ice Age. The climate signal, especially temperature, appears to be the strongest control on glacier

  19. Impacts of flamingos on saline lake margin and shallow lacustrine sediments in the Kenya Rift Valley

    Science.gov (United States)

    Scott, Jennifer J.; Renaut, Robin W.; Owen, R. Bernhart

    2012-11-01

    Studies of modern, Holocene, and Pleistocene sediments around saline to hypersaline, alkaline Lake Bogoria and Lake Magadi show that evidence of flamingo activity in marginal areas of these lakes is nearly ubiquitous. Flamingos produce discrete structures such as webbed footprints (~ 9 cm long, ~ 11 cm wide) and nest mounds (~ 30 cm wide, ~ 20 cm high), and they also extensively rework sediments in delta front, delta plain, and shoreline areas. Large (~ 0.5-2 cm in diameter), pinched, 'bubble pores' and ped-like mud clumps are formed by the trampling and churning of wet clay-rich sediments in these settings. Flamingo nest mounds, although superficially similar to some thrombolite mounds, are typically internally structureless, unless formed on pre-existing sediments that preserve internal structures. The flamingo mounds consist of a dense, packed oval-shaped core, a surrounding 'body' of packed sediment, and an external layer with a ped-like texture of clumped mud. The nests may contain open holes from roots or feather shafts incorporated into the nest, and (or) burrows produced once the nests are abandoned. In areas with high densities of flamingos, lake margin sediments may be preferentially compacted, particularly at breeding sites, and become resistant to subaerial erosion and the effects of transgressive ravinement on time scales ranging from seasons to tens of thousands of years. The relatively well-compacted nest mounds and associated sediments also contribute to the stability of delta distributary channels during regressive-transgressive cycles, and can lead to the minor channelization of unconfined flows where currents are diverted around nest mounds. Pleistocene exhumed surfaces of relatively well-indurated lake margin sediments at Lake Bogoria and Lake Magadi that are interpreted as combined regressive and transgressive surfaces (flooding surface/sequence boundary) preserve evidence of flamingo activities, and are overlain by younger, porous lacustrine

  20. (E)-α,β-unsaturated amides from tertiary amines, olefins and CO via Pd/Cu-catalyzed aerobic oxidative N-dealkylation.

    Science.gov (United States)

    Shi, Renyi; Zhang, Hua; Lu, Lijun; Gan, Pei; Sha, Yuchen; Zhang, Heng; Liu, Qiang; Beller, Matthias; Lei, Aiwen

    2015-02-21

    A novel Pd/Cu-catalyzed chemoselective aerobic oxidative N-dealkylation/carbonylation reaction has been developed. Tertiary amines are utilized as a "reservoir" of "active" secondary amines in this transformation, which inhibits the formation of undesired by-products and the deactivation of the catalysts. This protocol allows for an efficient and straightforward construction of synthetically useful and bioactive (E)-α,β-unsaturated amide derivatives from easily available tertiary amines, olefins and CO.