[Anniversary of the medical department of the Federal Office for Safe Storage and Destruction of Chemical Weapons].

Science.gov (United States)

Kuz'menko, I E

2013-01-01

The article is devoted to the process of formation and development of CW destruction management system and medical support of professional activities of personnel. Founders of Medical department of the Federal Directorate for Safe Storage and Destruction of Chemical Weapons are presented. Main principles and ways of working of medical department in specific conditions are covered.

Comparison of Short-Term Estrogenicity Tests for Identification of Hormone-Disrupting Chemicals

DEFF Research Database (Denmark)

Andersen, Helle Raun; Andersson, Anna-Maria; Arnold, Steven F.

1999-01-01

The aim of this study was to compare results obtained by eight different short-term assays of estrogenlike actions of chemicals conducted in 10 different laboratories in five countries. Twenty chemicals were selected to represent direct-acting estrogens, compounds with estrogenic metabolites, est...

Comparison of short-term estrogenicity tests for identification of hormone-disrupting chemicals

DEFF Research Database (Denmark)

Andersen, H R; Andersson, A M; Arnold, S F

1999-01-01

The aim of this study was to compare results obtained by eight different short-term assays of estrogenlike actions of chemicals conducted in 10 different laboratories in five countries. Twenty chemicals were selected to represent direct-acting estrogens, compounds with estrogenic metabolites, est...

Complete long-term corrosion protection with chemical vapor deposited graphene

DEFF Research Database (Denmark)

Yu, Feng; Camilli, Luca; Wang, Ting

2018-01-01

Despite numerous reports regarding the potential of graphene for corrosion protection, examples of chemical vapor deposited (CVD) graphene-based anticorrosive coatings able to provide long-term protection (i.e. several months) of metals have so far been absent. Here, we present a polymer-graphene......Despite numerous reports regarding the potential of graphene for corrosion protection, examples of chemical vapor deposited (CVD) graphene-based anticorrosive coatings able to provide long-term protection (i.e. several months) of metals have so far been absent. Here, we present a polymer......-graphene hybrid coating, comprising two single layers of CVD graphene sandwiched by three layers of polyvinyl butyral, which provides complete corrosion protection of commercial aluminum alloys even after 120 days of exposure to simulated seawater. The essential role played by graphene in the hybrid coating...

Changes in chemical quality indices during long-term storage of palm-olein oil under heated storage and transport-type conditions

CSIR Research Space (South Africa)

Van der Merwe, GH

2004-01-15

Full Text Available of Food and Agriculture J Sci Food Agric 84:52?58 (online: 2003) DOI: 10.1002/jsfa.1609 Changes in chemical quality indices during long-term storage of palm-olein oil under heated storage and transport-type conditions Gretel H van der Merwe,1asteriskmath... Lourens M du Plessis1 and John RN Taylor2 1CSIR Bio/Chemtek, PO Box 395, Pretoria 0001, South Africa 2Department of Food Science, University of Pretoria, Pretoria 0002, South Africa Abstract: Six quality indices, namely free fatty acids (FFA), peroxide...

Analysis of accident sequences and source terms at treatment and storage facilities for waste generated by US Department of Energy waste management operations

Energy Technology Data Exchange (ETDEWEB)

Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.; Folga, S.; Policastro, A.; Freeman, W.; Jackson, R.; Mishima, J.; Turner, S.

1996-12-01

This report documents the methodology, computational framework, and results of facility accident analyses performed for the US Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies assessed, and the resultant radiological and chemical source terms evaluated. A personal-computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for the calculation of human health risk impacts. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated, and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. Key assumptions in the development of the source terms are identified. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also discuss specific accident analysis data and guidance used or consulted in this report.

21 CFR 1300.02 - Definitions relating to listed chemicals.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 9 2010-04-01 2010-04-01 false Definitions relating to listed chemicals. 1300.02 Section 1300.02 Food and Drugs DRUG ENFORCEMENT ADMINISTRATION, DEPARTMENT OF JUSTICE DEFINITIONS § 1300.02 Definitions relating to listed chemicals. (a) Any term not defined in this part shall have the...

Nuclear magnetic resonance in chemical department of the Exact Science Institute of the Minas Gerais Federal University

International Nuclear Information System (INIS)

Veloso, D.P.

1989-01-01

The specifications for acquisition of pulsed NMR spectrometer by chemical department of Minas Gerais Federal University are described. The researches carried out using the NMR spectrometer are presented as well as installation and operation of NMR equipments. (M.C.K.)

Modelling of chemical evolution of low pH cements at long term

International Nuclear Information System (INIS)

El Bitouri, Y.; Buffo-Lacarriere, L.; Sellier, A.; Bourbon, X.

2015-01-01

In the context of the underground radioactive waste repository, low-pH cements were developed to reduce interactions between concrete and clay barrier. These cements contain high proportions of mineral additions like silica fume, fly ash or blast furnace slag for example. The high ratio of cement replacement by pozzolanic additions allows to reduce the pH by a global reduction of Ca/Si ratio of the hydrates (according to the one observed on CEM I pastes). In order to predict the short term development of the hydration for each component of this cement, a multiphasic hydration model, previously developed, is used. The model predicts the evolution of hydration degree of each anhydrous phase and consequently the quantity of each hydrate in paste (CH, aluminates, CSH with different Ca/Si ratios). However, this model is not suitable to determine the long term mineralogical and chemical evolution of the material, due to the internal change induced by chemical imbalance between initial hydrates. In order to evaluate the chemical characteristics of low pH cement based materials, and thus assess its chemical stability in the context of radioactive waste storage, a complementary model of chemical evolution at long term is proposed. This original model is based on 'solid-solution' principles. It assumes that the microdiffusion of calcium plays a major role to explain how the different Ca/Si ratio of initial C-S-H tends together toward a medium stabilized value. The main mechanisms and full development of the model equations are presented first. Next, a comparison of the model with experimental data issue from EDS (Energy Dispersive X-ray Spectroscopy) analysis on low pH cement allows to test the model. (authors)

Chemicals from Biomass: A Market Assessment of Bioproducts with Near-Term Potential

Energy Technology Data Exchange (ETDEWEB)

Biddy, Mary J. [National Renewable Energy Lab. (NREL), Golden, CO (United States); Scarlata, Christopher [National Renewable Energy Lab. (NREL), Golden, CO (United States); Kinchin, Christopher [National Renewable Energy Lab. (NREL), Golden, CO (United States)

2016-03-23

Production of chemicals from biomass offers a promising opportunity to reduce U.S. dependence on imported oil, as well as to improve the overall economics and sustainability of an integrated biorefinery. Given the increasing momentum toward the deployment and scale-up of bioproducts, this report strives to: (1) summarize near-term potential opportunities for growth in biomass-derived products; (2) identify the production leaders who are actively scaling up these chemical production routes; (3) review the consumers and market champions who are supporting these efforts; (4) understand the key drivers and challenges to move biomass-derived chemicals to market; and (5) evaluate the impact that scale-up of chemical strategies will have on accelerating the production of biofuels.

Environmental evaluation of alternatives for long-term management of Defense high-level radioactive wastes at the Idaho Chemical Processing Plant

Energy Technology Data Exchange (ETDEWEB)

1982-09-01

The U.S. Department of Energy (DOE) is considering the selection of a strategy for the long-term management of the defense high-level wastes at the Idaho Chemical Processing Plant (ICPP). This report describes the environmental impacts of alternative strategies. These alternative strategies include leaving the calcine in its present form at the Idaho National Engineering Laboratory (INEL), or retrieving and modifying the calcine to a more durable waste form and disposing of it either at the INEL or in an offsite repository. This report addresses only the alternatives for a program to manage the high-level waste generated at the ICPP. 24 figures, 60 tables.

Environmental evaluation of alternatives for long-term management of Defense high-level radioactive wastes at the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

1982-09-01

The U.S. Department of Energy (DOE) is considering the selection of a strategy for the long-term management of the defense high-level wastes at the Idaho Chemical Processing Plant (ICPP). This report describes the environmental impacts of alternative strategies. These alternative strategies include leaving the calcine in its present form at the Idaho National Engineering Laboratory (INEL), or retrieving and modifying the calcine to a more durable waste form and disposing of it either at the INEL or in an offsite repository. This report addresses only the alternatives for a program to manage the high-level waste generated at the ICPP. 24 figures, 60 tables

Chemical sensors technology development planning workshop

Energy Technology Data Exchange (ETDEWEB)

Bastiaans, G.J.; Haas, W.J. Jr.; Junk, G.A. [eds.

1993-03-01

The workshop participants were asked to: (1) Assess the current capabilities of chemical sensor technologies for addressing US Department of Energy (DOE) Environmental Restoration and Waste Management (EM) needs; (2) Estimate potential near term (one to two years) and intermediate term (three to five years) capabilities for addressing those needs; and (3) Generate a ranked list of specific recommendations on what research and development (R&D) should be funded to provide the necessary capabilities. The needs were described in terms of two pervasive EM problems, the in situ determination of chlorinated volatile organic compounds (VOCs), and selected metals in various matrices at DOE sites. The R&D recommendations were to be ranked according to the estimated likelihood that the product technology will be ready for application within the time frame it is needed and the estimated return on investment. The principal conclusions and recommendations of the workshop are as follows: Chemical sensors capable of in situ determinations can significantly reduce analytical costs; Chemical sensors have been developed for certain VOCs in gases and water but none are currently capable of in situ determination of VOCs in soils; The DOE need for in situ determination of metals in soils cannot be addressed with existing chemical sensors and the prospects for their availability in three to five years are uncertain; Adaptation, if necessary, and field application of laboratory analytical instruments and those few chemical sensors that are already in field testing is the best approach for the near term; The chemical sensor technology development plan should include balanced support for near- and intermediate-term efforts.

Chemical sensors technology development planning workshop

International Nuclear Information System (INIS)

Bastiaans, G.J.; Haas, W.J. Jr.; Junk, G.A.

1993-03-01

The workshop participants were asked to: (1) Assess the current capabilities of chemical sensor technologies for addressing US Department of Energy (DOE) Environmental Restoration and Waste Management (EM) needs; (2) Estimate potential near term (one to two years) and intermediate term (three to five years) capabilities for addressing those needs; and (3) Generate a ranked list of specific recommendations on what research and development (R ampersand D) should be funded to provide the necessary capabilities. The needs were described in terms of two pervasive EM problems, the in situ determination of chlorinated volatile organic compounds (VOCs), and selected metals in various matrices at DOE sites. The R ampersand D recommendations were to be ranked according to the estimated likelihood that the product technology will be ready for application within the time frame it is needed and the estimated return on investment. The principal conclusions and recommendations of the workshop are as follows: Chemical sensors capable of in situ determinations can significantly reduce analytical costs; Chemical sensors have been developed for certain VOCs in gases and water but none are currently capable of in situ determination of VOCs in soils; The DOE need for in situ determination of metals in soils cannot be addressed with existing chemical sensors and the prospects for their availability in three to five years are uncertain; Adaptation, if necessary, and field application of laboratory analytical instruments and those few chemical sensors that are already in field testing is the best approach for the near term; The chemical sensor technology development plan should include balanced support for near- and intermediate-term efforts

21 CFR 1310.21 - Sale by Federal departments or agencies of chemicals which could be used to manufacture...

Science.gov (United States)

2010-04-01

... chemicals which could be used to manufacture controlled substances. 1310.21 Section 1310.21 Food and Drugs... manufacture controlled substances. (a) A Federal department or agency may not sell from the stocks of the... Administration, could be used in the manufacture of a controlled substance, unless the Administrator certifies in...

Building LGBTQ-Inclusive Chemical Engineering Classrooms and Departments

Science.gov (United States)

Butterfield, Anthony; McCormick, Alon; Farrell, Stephanie

2018-01-01

Despite recent advances in LGBTQ+ (lesbian, gay, bisexual, transgender, and queer) equality in the United States and in many countries around the globe, LGBTQ+ students on college campuses still experience bias, hostility and discrimination. Engineering departments on campus in particular have been slower than other departments to respond to…

Use of short-term test systems for the prediction of the hazard represented by potential chemical carcinogens

Energy Technology Data Exchange (ETDEWEB)

Glass, L.R.; Jones, T.D.; Easterly, C.E.; Walsh, P.J.

1990-10-01

It has been hypothesized that results from short-term bioassays will ultimately provide information that will be useful for human health hazard assessment. Historically, the validity of the short-term tests has been assessed using the framework of the epidemiologic/medical screens. In this context, the results of the carcinogen (long-term) bioassay is generally used as the standard. However, this approach is widely recognized as being biased and, because it employs qualitative data, cannot be used to assist in isolating those compounds which may represent a more significant toxicologic hazard than others. In contrast, the goal of this research is to address the problem of evaluating the utility of the short-term tests for hazard assessment using an alternative method of investigation. Chemicals were selected mostly from the list of carcinogens published by the International Agency for Research on Carcinogens (IARC); a few other chemicals commonly recognized as hazardous were included. Tumorigenicity and mutagenicity data on 52 chemicals were obtained from the Registry of Toxic Effects of Chemical Substances (RTECS) and were analyzed using a relative potency approach. The data were evaluated in a format which allowed for a comparison of the ranking of the mutagenic relative potencies of the compounds (as estimated using short-term data) vs. the ranking of the tumorigenic relative potencies (as estimated from the chronic bioassays). Although this was a preliminary investigation, it offers evidence that the short-term tests systems may be of utility in ranking the hazards represented by chemicals which may contribute to increased carcinogenesis in humans as a result of occupational or environmental exposures. 177 refs., 8 tabs.

Use of short-term test systems for the prediction of the hazard represented by potential chemical carcinogens

International Nuclear Information System (INIS)

Glass, L.R.; Jones, T.D.; Easterly, C.E.; Walsh, P.J.

1990-10-01

It has been hypothesized that results from short-term bioassays will ultimately provide information that will be useful for human health hazard assessment. Historically, the validity of the short-term tests has been assessed using the framework of the epidemiologic/medical screens. In this context, the results of the carcinogen (long-term) bioassay is generally used as the standard. However, this approach is widely recognized as being biased and, because it employs qualitative data, cannot be used to assist in isolating those compounds which may represent a more significant toxicologic hazard than others. In contrast, the goal of this research is to address the problem of evaluating the utility of the short-term tests for hazard assessment using an alternative method of investigation. Chemicals were selected mostly from the list of carcinogens published by the International Agency for Research on Carcinogens (IARC); a few other chemicals commonly recognized as hazardous were included. Tumorigenicity and mutagenicity data on 52 chemicals were obtained from the Registry of Toxic Effects of Chemical Substances (RTECS) and were analyzed using a relative potency approach. The data were evaluated in a format which allowed for a comparison of the ranking of the mutagenic relative potencies of the compounds (as estimated using short-term data) vs. the ranking of the tumorigenic relative potencies (as estimated from the chronic bioassays). Although this was a preliminary investigation, it offers evidence that the short-term tests systems may be of utility in ranking the hazards represented by chemicals which may contribute to increased carcinogenesis in humans as a result of occupational or environmental exposures. 177 refs., 8 tabs

Analysis of accident sequences and source terms at treatment and storage facilities for waste generated by US Department of Energy waste management operations. Volume 1: Sections 1-9

International Nuclear Information System (INIS)

Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.; Folga, S.; Policastro, A.; Freeman, W.; Jackson, R.; Mishima, J.; Turner, S.

1996-12-01

This report documents the methodology, computational framework, and results of facility accident analyses performed for the US Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies assessed, and the resultant radiological and chemical source terms evaluated. A personal-computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for the calculation of human health risk impacts. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated, and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. Key assumptions in the development of the source terms are identified. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also discuss specific accident analysis data and guidance used or consulted in this report

Report by the AERES on the unit: Fuel Study Department (DEC) under the supervision of the establishments and bodies: Atomic Energy and Alternative Energies Commission (CEA); Rapport de l'AERES sur l'unite: Departement d'Etudes des Combustibles (DEC) sous tutelle des etablissements et organismes: Commissariat a l'Energie Atomique et aux Energies Alternatives (CEA)

Energy Technology Data Exchange (ETDEWEB)

NONE

2011-03-15

This report is a kind of audit report on a research laboratory, the DEC (Departement d'Etudes des Combustibles, Fuel Study Department) which comprises four departments: a department of analysis and characterization of fuel behaviour (SA3C) which comprises four laboratories, a Plutonium, Uranium and Minor Actinides department (SPUA) which comprises four laboratories, a department for the investigation and simulation of fuel behaviour (four laboratories) and the Leca-Star department (3 laboratories and a project group). The authors discuss an assessment of the whole unit activities in terms of strengths and opportunities, aspects to be improved, risks and recommendations, productions and publications on different themes (fundamental research on fuels, fuel design, fabrications, characterizations and property measurements, experimental irradiations, characterization of irradiated fuels and chemical and radio-chemical analysis, modelling and simulation). A more detailed assessment is presented for each theme in terms of scientific quality, influence and attractiveness (awards, recruitment capacity, capacity to obtain financing and to tender, participation to international programs), strategy and governance, and project

Report by the AERES on the unit: Fuel Study Department (DEC) under the supervision of the establishments and bodies: Atomic Energy and Alternative Energies Commission (CEA)

International Nuclear Information System (INIS)

2011-03-01

This report is a kind of audit report on a research laboratory, the DEC (Departement d'Etudes des Combustibles, Fuel Study Department) which comprises four departments: a department of analysis and characterization of fuel behaviour (SA3C) which comprises four laboratories, a Plutonium, Uranium and Minor Actinides department (SPUA) which comprises four laboratories, a department for the investigation and simulation of fuel behaviour (four laboratories) and the Leca-Star department (3 laboratories and a project group). The authors discuss an assessment of the whole unit activities in terms of strengths and opportunities, aspects to be improved, risks and recommendations, productions and publications on different themes (fundamental research on fuels, fuel design, fabrications, characterizations and property measurements, experimental irradiations, characterization of irradiated fuels and chemical and radio-chemical analysis, modelling and simulation). A more detailed assessment is presented for each theme in terms of scientific quality, influence and attractiveness (awards, recruitment capacity, capacity to obtain financing and to tender, participation to international programs), strategy and governance, and project

Short and long-term mortality of patients presenting with bleeding events to the Emergency Department.

Science.gov (United States)

Conti, Alberto; Renzi, Noemi; Molesti, Daniele; Bianchi, Simone; Bogazzi, Irene; Bongini, Giada; Pepe, Giuseppe; Frosini, Fabiana; Bertini, Alessio; Santini, Massimo

2017-12-01

Death of patients presenting with bleeding events to the Emergency Department still represent a major problem. We sought to analyze clinical characteristics associated with worse outcomes including short- and long-term death, beyond antithombotic treatment strategy. Patients presenting with any bleeding events during 2016-2017years were enrolled. Clinical parameters, site of bleeding, major bleeding, ongoing anti-thrombotic treatment strategy and death were collected. Hard 5:1 propensity score matching was performed to adjust dead patients in baseline characteristics. Endpoints were one-month and one-year death. Out of 166,000 visits to the Emergency Department, 3.050 patients (1.8%) were enrolled and eventually 429 were analyzed after propensity. Overall, anticoagulants or antiplatelets were given to 234(54%). Major bleeding account for 111(26%) patients, without differences between those taking anticoagulants or antiplatelets versus others. Death at one-month and one-year was 26(6%) and 72(17%), respectively. Independent predictors of one-month death were major bleeding (Odds Ratio, OR 26, pbleeding (OR 7, pbleeding where higher than others (pbleeding and age (0.75 and 0.72, respectively) over others; pbleeding events, death rate was driven by major bleeding on short-term and older age on long-term. Among dead patients mortality was approximately 40% on one-month; 60% in older patients, and 80% in female gender. Copyright © 2017 Elsevier Inc. All rights reserved.

Dual simulation of the massless lattice Schwinger model with topological term and non-zero chemical potential

Science.gov (United States)

Göschl, Daniel

2018-03-01

We discuss simulation strategies for the massless lattice Schwinger model with a topological term and finite chemical potential. The simulation is done in a dual representation where the complex action problem is solved and the partition function is a sum over fermion loops, fermion dimers and plaquette-occupation numbers. We explore strategies to update the fermion loops coupled to the gauge degrees of freedom and check our results with conventional simulations (without topological term and at zero chemical potential), as well as with exact summation on small volumes. Some physical implications of the results are discussed.

Materials Safety Data Sheets: the basis for control of toxic chemicals

Energy Technology Data Exchange (ETDEWEB)

Ketchen, E.E.; Porter, W.E.

1979-09-01

The Material Safety Data Sheets contained in this volume are the basis for the Toxic Chemical Control Program developed by the Industrial Hygiene Department, Health Division, ORNL. The three volumes are the update and expansion of ORNL/TM-5721 and ORNL/TM-5722 Material Safety Data Sheets: The Basis for Control of Toxic Chemicals, Volume I and Volume II. As such, they are a valuable adjunct to the data cards issued with specific chemicals. The chemicals are identified by name, stores catalog number where appropriate, and sequence numbers from the NIOSH Registry of Toxic Effects of Chemical Substances, 1977 Edition, if available. The data sheets were developed and compiled to aid in apprising the employees of hazards peculiar to the handling and/or use of specific toxic chemicals. Space limitation necessitate the use of descriptive medical terms and toxicological abbreviations. A glossary and an abbreviation list were developed to define some of those sometimes unfamiliar terms and abbreviations. The page numbers are keyed to the catalog number in the chemical stores at ORNL.

Military chemical warfare agent human subjects testing: part 2--long-term health effects among participants of U.S. military chemical warfare agent testing.

Science.gov (United States)

Brown, Mark

2009-10-01

Military chemical warfare agent testing from World War I to 1975 produced thousands of veterans with concerns about how their participation affected their health. A companion article describes the history of these experiments, and how the lack of clinical data hampers evaluation of long-term health consequences. Conversely, much information is available about specific agents tested and their long-term health effects in other populations, which may be invaluable for helping clinicians respond effectively to the health care and other needs of affected veterans. The following review describes tested agents and their known long-term health consequences. Although hundreds of chemicals were tested, they fall into only about a half-dozen pharmaceutical classes, including common pharmaceuticals; anticholinesterase agents including military nerve agents and pesticides; anticholinergic glycolic acid esters such as atropine; acetylcholine reactivators such as 2-PAM; psychoactive compounds including cannabinoids, phencyclidine, and LSD; and irritants including tear gas and riot control agents.

A Qualitative Evaluation of Instructors' Exam Questions at a Primary Education Department in Terms of Certain Variables

Science.gov (United States)

Demir, Mehmet Kaan; Eryaman, Mustafa Yunus

2012-01-01

The purpose of this qualitative research study is to analyze instructors' exam questions at a Primary Education Department in terms of the exam's period, the comprehensibility of the instructions, cognitive level, and the appropriateness to the critical thinking. This qualitative study is based on document analysis method. 100 randomly selected…

Chemical gas sensors and the characterization, monitoring and sensor technology needs of the US Department of Energy

International Nuclear Information System (INIS)

Bastiaans, G.J.; Haas, W.J. Jr.; Junk, G.A.

1993-01-01

The Office of Technology Development within the Dept. of Energy (DOE) has the responsibility of providing new technologies to aid the environmental restoration and waste management (ER/WM) activities of the DOE. There is a perception that application and judicious development of chemical sensor technologies could result in large cost savings and reduced risk to the health and safety of ER/WM personnel. A number of potential gas sensor applications which exist within DOE ER/WM operations are described. The capabilities of several chemical sensor technologies and their potential to meet the needs of ER/WM applications in the present or near term future are discussed

Chemistry and Materials Science Department annual report, 1988--1989

Energy Technology Data Exchange (ETDEWEB)

Borg, R.J.; Sugihara, T.T.; Cherniak, J.C.; Corey, C.W. [eds.

1989-12-31

This is the first annual report of the Chemistry & Materials Science (C&MS) Department. The principal purpose of this report is to provide a concise summary of our scientific and technical accomplishments for fiscal years 1988 and 1989. The report is also tended to become part of the archival record of the Department`s activities. We plan to publish future editions annually. The activities of the Department can be divided into three broad categories. First, C&MS staff are assigned by the matrix system to work directly in a program. These programmatic assignments typically involve short deadlines and critical time schedules. A second category is longer-term research and development in technologies important to Laboratory programs. The focus and direction of this technology-base work are generally determined by programmatic needs. Finally, the Department manages its own research program, mostly long-range in outlook and basic in orientation. These three categories are not mutually exclusive but form a continuum of technical activities. Representative examples of all three are included in this report. The principal subject matter of this report has been divided into six sections: Innovations in Analysis and Characterization, Advanced Materials, Metallurgical Science and Technology, Surfaces and Interfaces, Energetic Materials and Chemical Synthesis, and Energy-Related Research and Development.

Long-term pulmonary complications of chemical weapons exposure in former poison gas factory workers.

Science.gov (United States)

Nishimura, Yoshifumi; Iwamoto, Hiroshi; Ishikawa, Nobuhisa; Hattori, Noboru; Horimasu, Yasushi; Ohshimo, Shinichiro; Fujitaka, Kazunori; Kondo, Keiichi; Hamada, Hironobu; Awai, Kazuo; Kohno, Nobuoki

2016-07-01

Sulfur mustard (SM) and lewisite are vesicant chemical warfare agents that can cause skin blistering and chronic lung complications. During 1929-1945, a Japanese factory produced poisonous gases, which included SM, lewisite and other chemical weapons. The aim of this study was to investigate the chest computed tomography (CT) findings among long-term survivors who worked at this factory. During 2009-2012, we evaluated chest CT findings from 346 long-term survivors who worked at the poison gas factory. Skin lesions were used as an indicator of significant exposure to vesicant agents. Among the 346 individuals, 53 (15%) individuals experienced skin lesions while working at the factory, and chest CT revealed abnormal findings in 179 individuals (52%). Emphysema was the most common CT finding and was observed in 75 individuals (22%), while honeycombing was observed in 8 individuals (2%). Emphysema and honeycombing were more prevalent among individuals with skin lesions, compared to individuals without skin lesions. Multivariate analyses revealed significant associations between the presence of emphysema and skin lesions (p = 0.008). Among individuals who never smoked, individuals with skin lesions (n = 26) exhibited a significantly higher rate of emphysema, compared to individuals without skin lesions (n = 200) (35% versus 7%, respectively; p chemical warfare agents.

Department of Energy depleted uranium recycle

International Nuclear Information System (INIS)

Kosinski, F.E.; Butturini, W.G.; Kurtz, J.J.

1994-01-01

With its strategic supply of depleted uranium, the Department of Energy is studying reuse of the material in nuclear radiation shields, military hardware, and commercial applications. the study is expected to warrant a more detailed uranium recycle plan which would include consideration of a demonstration program and a program implementation decision. Such a program, if implemented, would become the largest nuclear material recycle program in the history of the Department of Energy. The bulk of the current inventory of depleted uranium is stored in 14-ton cylinders in the form of solid uranium hexafluoride (UF 6 ). The radioactive 235 U content has been reduced to a concentration of 0.2% to 0.4%. Present estimates indicate there are about 55,000 UF 6 -filled cylinders in inventory and planned operations will provide another 2,500 cylinders of depleted uranium each year. The United States government, under the auspices of the Department of Energy, considers the depleted uranium a highly-refined strategic resource of significant value. A possible utilization of a large portion of the depleted uranium inventory is as radiation shielding for spent reactor fuels and high-level radioactive waste. To this end, the Department of Energy study to-date has included a preliminary technical review to ascertain DOE chemical forms useful for commercial products. The presentation summarized the information including preliminary cost estimates. The status of commercial uranium processing is discussed. With a shrinking market, the number of chemical conversion and fabrication plants is reduced; however, the commercial capability does exist for chemical conversion of the UF 6 to the metal form and for the fabrication of uranium radiation shields and other uranium products. Department of Energy facilities no longer possess a capability for depleted uranium chemical conversion

The Department of Energy/American Chemical Society Summer School in Nuclear and Radiochemistry at San Jose State University

International Nuclear Information System (INIS)

Kinard, W.F.; Silber, H.B.

2005-01-01

A Summer School in Nuclear Chemistry sponsored by the U. S. Department of Energy and the American Chemical Society has been held at San Jose State University for the past 20 years. The intent of the program is to introduce outstanding college students to the field of nuclear and radiochemistry with the goal that some of these students will consider careers on nuclear science. The program features radiochemistry experiments along with radiation safety training, guest lectures by well known nuclear scientists and field trips to nuclear chemistry facilities in the San Francisco area. (author)

Comment on the Long-Term Chemical and Mineralogical Stability of the Buffer

International Nuclear Information System (INIS)

Arthur, Randy; Apted, Mick; Stenhouse, Mike

2005-03-01

This report examines concepts and data that SKB may use to assess the long-term chemical and mineralogical evolution of bentonite barriers in a KBS-3 repository for spent nuclear fuel. Three interrelated topics are considered: mineral chemistry of the smectite clays; thermodynamic stability of the smectite clays; and bentonite-water interactions during the early thermal period of repository evolution. Smectites are complex solid solutions having variable compositions resulting from ionic substitutions on exchange, octahedral and tetrahedral sites in the crystalline lattice. Although little is known about the mechanisms and rates of reactions involving the latter two sites, abundant observational evidence from natural systems suggests that such reactions could occur to an appreciable extent in the buffer over the million year time frame being considered for an intact canister. We are not aware of any efforts in SKB's current modeling strategy to account for such reactions, and therefore question whether the strategy is appropriate for modeling the long-term chemical evolution of the buffer and associated potential effects on the desirable physical and rheological properties of this barrier material. The variable chemistry of smectites affects their thermodynamic stability. Models of smectite-water equilibria use either a fixed stoichiometric composition to approximate representative smectite varieties, or account for compositional variations using solid solution models and ideal mixing relations among thermodynamic components. In either case the thermodynamic properties of a specific smectite composition or of individual solid-solution components must usually be estimated. Recent reports suggest that SKB will not account explicitly for the thermodynamic properties of smectite in its models of bentonite-water interactions. Rather, the models will assume that this clay mineral has a fixed, though unspecified, composition representing an ion-exchanger phase. This phase

Long-term Chemical Characterization of Submicron Aerosol Particles in the Amazon Forest - ATTO Station

Science.gov (United States)

Carbone, S.; Brito, J.; Rizzo, L. V.; Holanda, B. A.; Cirino, G. G.; Saturno, J.; Krüger, M. L.; Pöhlker, C.; Ng, N. L.; Xu, L.; Andreae, M. O.; Artaxo, P.

2015-12-01

The study of the chemical composition of aerosol particles in the Amazon forest represents a step forward to understand the strong coupling between the atmosphere and the forest. For this reason submicron aerosol particles were investigated in the Amazon forest, where biogenic and anthropogenic aerosol particles coexist at the different seasons (wet/dry). The measurements were performed at the ATTO station, which is located about 150 km northeast of Manaus. At ATTO station the Aerosol chemical speciation monitor (ACSM, Aerodyne) and the Multiangle absorption photometer (MAAP, Thermo 5012) have been operated continuously from March 2014 to July 2015. In this study, long-term measurements (near-real-time, ~30 minutes) of PM1 chemical composition were investigated for the first time in this environment.The wet season presented lower concentrations than the dry season (~5 times). In terms of chemical composition, both seasons were dominated by organics (75 and 63%) followed by sulfate (11 and 13%). Nitrate presented different ratio values between the mass-to-charges 30 to 46 (main nitrate fragments) suggesting the presence of nitrate as inorganic and organic nitrate during both seasons. The results indicated that about 75% of the nitrate signal was from organic nitrate during the dry season. In addition, several episodes with elevated amount of chloride, likely in the form of sea-salt from the Atlantic Ocean, were observed during the wet season. During those episodes, chloride comprised up to 7% of the PM1. During the dry season, chloride was also observed; however, with different volatility, which suggested that Chloride was present in different form and source. Moreover, the constant presence of sulfate and BC during the wet season might be related to biomass burning emissions from Africa. BC concentration was 2.5 times higher during the dry season. Further characterization of the organic fraction was accomplished with the positive matrix factorization (PMF), which

77 FR 74685 - Chemical Facility Anti-Terrorism Standards (CFATS) Chemical-Terrorism Vulnerability Information...

Science.gov (United States)

2012-12-17

... DEPARTMENT OF HOMELAND SECURITY [Docket No. DHS-2012-0057] Chemical Facility Anti-Terrorism Standards (CFATS) Chemical- Terrorism Vulnerability Information (CVI) AGENCY: National Protection and...: Comments that include trade secrets, confidential commercial or financial information, Chemical-terrorism...

78 FR 16698 - Chemical Facility Anti-Terrorism Standards (CFATS) Chemical-Terrorism Vulnerability Information...

Science.gov (United States)

2013-03-18

... DEPARTMENT OF HOMELAND SECURITY [Docket No. DHS-2012-0057] Chemical Facility Anti-Terrorism Standards (CFATS) Chemical- Terrorism Vulnerability Information (CVI) AGENCY: National Protection and... notice is also soliciting comments concerning the Information Collection Request, Chemical Facility Anti...

Progress report 1989-1990. Reactors Chemistry Department

International Nuclear Information System (INIS)

1991-01-01

This paper presents a review of the activities performed by the Reactors Chemistry Department of the Argentine National Atomic Energy Commission during 1989-1990. This department provides scientific-technical services and assistance in all chemical problems related to design, construction, commissioning and decommissioning of nuclear power plants

Workplace Skills Taught in a Simulated Analytical Department

Science.gov (United States)

Sonchik Marine, Susan

2001-11-01

Integration of workplace skills into the academic setting is paramount for any chemical technology program. In addition to the expected chemistry content, courses must build proficiency in oral and written communication skills, computer skills, laboratory safety, and logical troubleshooting. Miami University's Chemical Technology II course is set up as a contract analytical laboratory. Students apply the advanced sampling techniques, quality assurance, standard methods, and statistical analyses they have studied. For further integration of workplace skills, weekly "department meetings" are held where the student, as members of the department, report on their work in process, present completed projects, and share what they have learned and what problems they have encountered. Information is shared between the experienced members of the department and those encountering problems or starting a new project. The instructor as department manager makes announcements, reviews company and department status, and assigns work for the coming week. The department members report results to clients in formal reports or in short memos. Factors affecting the success of the "department meeting" approach include the formality of the meeting room, use of an official agenda, the frequency, time, and duration of the meeting, and accountability of the students.

Evolution of sorption properties in large-scale concrete structures accounting for long-term physical-chemical concrete degradation - 59297

International Nuclear Information System (INIS)

Perko, Janez; Jacques, Diederik; Mallants, Dirk; Seetharam, Suresh

2012-01-01

Long-term safety of radioactive waste disposal facilities relies on the longevity of natural or engineered barriers designed to minimize the migration of contaminants from the facility into the environment. Especially near surface disposal facilities, such as planned by ONDRAF/NIRAS for the Dessel site in Belgium, long-term safety relies almost exclusively on the containment ability of the engineered barriers (EB) with concrete being the most important EB material used. Concrete is preferred over other materials mainly due to its favourable chemical properties resulting in a high chemical retention capacity, and owing to its good hydraulic isolation properties. However, due to the long time frames typically involved in safety assessment, the chemical, physical and mechanical properties of concrete evolve in time. The alterations in concrete mineralogy also cause changes in pH and sorption behaviour for many radionuclides during chemical degradation processes. Application of dynamic sorption of concrete requires an adequate knowledge of long-term concrete degradation processes, knowledge of the effect of changing mineralogy to sorption of radionuclides and knowledge of large-scale system behaviour over time. Moreover, when applied to safety assessment models, special attention is required to assure robustness and transparency of the implementation. The discussion in this paper focuses on the sorption properties of concrete; selection of data, rescaling issues and on the hypotheses used to build a robust and yet transparent dynamic model for large-scale concrete structures for assessing the long-term performance. In this paper we summarize the steps required for the appropriate use of sorption values for large-scale cementitious components accounting for long-term concrete degradation in safety assessment studies. Four steps were recognized through the safety assessment in the framework of the license application for the near-surface disposal facility in Dessel

Protecting Contract Workers: Case Study of the US Department of Energy’s Nuclear and Chemical Waste Management

Science.gov (United States)

Gochfeld, Michael; Mohr, Sandra

2007-01-01

Increased reliance on subcontractors in all economic sectors is a serious occupational health and safety challenge. Short-term cost savings are offset by long-term liability. Hiring subcontractors brings specialized knowledge but also young, inexperienced, inadequately trained workers onto industrial and hazardous waste sites, which leads to increased rates of accidents and injuries. Reliable data on subcontractor occupational health and safety programs and performance are sparse. The US Department of Energy has an excellent safety culture on paper, but procurement practices and contract language deliver a mixed message—including some safety disincentives. Its biphasic safety outcome data are consistent with underreporting by some subcontractors and underachievement by others. These observations are relevant to the private and public sectors. Occupational health and safety should be viewed as an asset, not merely a cost. PMID:17666686

Long-term degradation of chemical structures and mechanical properties in polyethylene induced by ion-beam irradiation

International Nuclear Information System (INIS)

Oka, T.; Hama, Y.

2004-01-01

The long-term degradation in polyethylene irradiated with ion beams was studied. We found the changes of the chemical structures and the mechanical properties with time storage. S-PE has a good resistance to ion-beam irradiation because the crystallinity and density were very low. (author)

Chemical mode control in nuclear power plant decommissioning during operation of technologies in individual radioactive waste processing plants

International Nuclear Information System (INIS)

Horvath, J.; Dugovic, L.

1999-01-01

Sewage treatment of nuclear power plant decommissioning is performed by system of sewage concentration in evaporator with formation of condensed rest, it means radioactive waste concentrate and breeding steam. During sewage treatment plant operation department of chemical mode performs chemical and radiochemical analysis of sewage set for treatment, chemical and radiochemical analysis of breeding steam condensate which is after final cleaning on ionization filter and fulfilling the limiting conditions released to environment; chemical and radiochemical analysis of heating steam condensate which is also after fulfilling the limiting conditions released to environment. Condensed radioactive concentrate is stored in stainless tanks and later converted into easy transportable and chemically stable matrix from the long term storage point of view in republic storage Mochovce. The article also refer to bituminous plant, vitrification plant, swimming pool decontamination plant of long term storage and operation of waste processing plant Bohunice

Chemical term correspondence between Japanese and American chemistry textbooks. II. Nippon to America no kagaku kyokasho ni okeru kagaku yogo no taio. II

Energy Technology Data Exchange (ETDEWEB)

Kakihara, S. (Hiroshima University, Hiroshima (Japan))

1991-06-10

This is a study on how chemical terms used in Japanese chemistry textbooks correspond to those in American textbooks. Examples in which English and Japanese chemical terms do not correspond are divided into 4 groups, and points to be noticed are described. As references, two kinds of most popular textbooks in the U.S. and three kinds of Japanese textbooks are mainly used. When chemical terms in either of American or Japanese textbooks do not correspond to or were not found in the other textbooks, several kinds of other dictionaries and textbooks are also investigated. As a result, it is found that there are some English terms which are apt to be mistranslated into Japanese. Some of English translations established in dictionaries and textbooks in Japan are not found in American textbooks. In the same way, some English terms often used in American textbooks do not appear in Japanese textbooks and dictionaries. These examples and notes seem to be useful for reading American textbooks or writing English abstracts of papers on chemistry. 16 refs.

Department of Chemistry, progress report

International Nuclear Information System (INIS)

1989-05-01

The research activities in Department of Chemistry during the last 3 years from 1986 to 1988 were compiled. The researches and works of Department of Chemistry are mainly those concerned with important basic matters and items which are committed to the further development of the nuclear fuels and materials, to the establishment of the nuclear fuel cycle, and to the acquisition of data for the environmental safety studies. Intensive efforts were also made on chemical analysis service of various fuels and nuclear materials. (author)

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Chemical Engineering Department, Engineering Faculty, Ferdowsi University of Mashhad, Mashhad, Iran; Department of Chemistry, Simon Fraser University, Burnaby, BC, Canada; School of Chemical Engineering- University College of Engineering-University of Tehran, Tehran, Iran; School of Chemistry- University ...

Progress report 1981-1982. Reactor Chemistry Department

International Nuclear Information System (INIS)

1983-08-01

Review of the activities performed by the Reactor Chemistry Department of the National Atomic Energy Commission of Argentina during 1981-1982. This Department provides services and assistance in all matters related to water chemistry and nuclear reactors chemistry, in all their phases: design, construction, commissioning and decommissioning. During this period, the following tasks were performed: study of the metallic oxide-water interphases; determination of the goethite and magnetite surficial charges; synthesis of the monodispersed nickel ferrites; study of the iron oxides dissolution mechanism in presence of different complexing agents; chemical decontamination of structural metals; thermodynamics of the water-nitrogen system; physico-chemical studies of aqueous solutions at high temperatures; hydrothermal decomposition of ionic exchange resines and study of the equilibria of the anionic exchange for the chemistry of pressurized reactor's primary loops. The appendix includes information on the Reactor Chemistry Department staff, its publications, services, seminars, courses and conferences performed during 1981-1982. (R.J.S.) [es

Frequent Prescribed Burning as a Long-term Practice in Longleaf Pine Forests Does Not Affect Detrital Chemical Composition.

Science.gov (United States)

Coates, T Adam; Chow, Alex T; Hagan, Donald L; Wang, G Geoff; Bridges, William C; Dozier, James H

2017-09-01

The O horizon, or detrital layer, of forest soils is linked to long-term forest productivity and health. Fuel reduction techniques, such as prescribed fire, can alter the thickness and composition of this essential ecosystem component. Developing an understanding of the changes in the chemical composition of forest detritus due to prescribed fire is essential for forest managers and stakeholders seeking sustainable, resilient, and productive ecosystems. In this study, we evaluated fuel quantity, fuel structure, and detrital chemical composition in longleaf pine ( Miller) forests that have been frequently burned for the last 40 yr at the Tom Yawkey Wildlife Center in Georgetown, SC. Our results suggest that frequent prescribed fire reduces forest fuel quantity ( burned detritus. Our burning activities varied in the short term, consisting of annual dormant, annual growing, and biennial dormant season burns. Seasonal distinctions were present for fuel quantity and vertical fuel structure, but these differences were not noted for the benzene/phenol ratio. These results are significant as more managers consider burning existing longleaf stands while determining effective management practices for longleaf stands yet to be established. Managers of such stands can be confident that frequent, low-intensity, low-severity prescribed burns in longleaf pine forests do little to affect the long-term chemical composition of forest detritus. Copyright © by the American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America, Inc.

Long-Term Surveillance and Maintenance Plan for the U.S. Department of Energy Amchitka, Alaska, Site

Energy Technology Data Exchange (ETDEWEB)

None

2008-09-01

This Long-Term Surveillance and Maintenance Plan describes how the U.S. Department of Energy (DOE) intends to fulfill its mission to maintain protection of human health and the environment at the Amchitka, Alaska, Site1. Three underground nuclear tests were conducted on Amchitka Island. The U.S. Department of Defense, in conjunction with the U.S. Atomic Energy Commission (AEC), conducted the first nuclear test (Long Shot) to provide data that would improve the United States' capability of detecting underground nuclear explosions. The second nuclear test (Milrow) was a weapons-related test conducted by AEC as a means to study the feasibility of detonating a much larger device. The final nuclear test (Cannikin), the largest United States underground test, was a weapons-related test. Surface disturbances associated with these tests have been remediated. However, radioactivity remains deep below the surface, contained in and around the test cavities, for which no feasible remediation technology has been identified. In 2006, the groundwater model (Hassan et al. 2002) was updated using 2005 data collected by the Consortium for Risk Evaluation with Stakeholder Participation. Model simulation results indicate there is no breakthrough or seepage of radionuclides into the marine environment within 2,000 years. The Amchitka conceptual model is reasonable; the flow and transport simulation is based on the best available information and data. The simulation results are a quantitative prediction supported by the best available science and technology. This Long-Term Surveillance and Maintenance Plan is an additional step intended for the protection of human health and the environment. This plan may be modified from time to time in the future consistent with the mission to protect human health

Impacts on health and safety from transfer/consolidation of nuclear materials and hazardous chemicals

International Nuclear Information System (INIS)

Gallucci, R.H.V.

1994-11-01

Environmental restoration plans at the US Department of Energy (USDOE) Hanford Site calls for transfer/consolidation of ''targets/threats,'' namely nuclear materials and hazardous chemicals. Reductions in the health and safety hazards will depend on the plans implemented. Pacific Northwest Laboratory (PNL) estimated these potential impacts, assuming implementation of the current reference plan and employing ongoing risk and safety analyses. The results indicated the potential for ''significant'' reductions in health and safety hazards in the long term (> 25 years) and a potentially ''noteworthy'' reduction in health hazard in the short term (≤ 25 years)

Long-Term Coffee Monoculture Alters Soil Chemical Properties and Microbial Communities.

Science.gov (United States)

Zhao, Qingyun; Xiong, Wu; Xing, Yizhang; Sun, Yan; Lin, Xingjun; Dong, Yunping

2018-04-17

Long-term monoculture severely inhibits coffee plant growth, decreases its yield and results in serious economic losses in China. Here, we selected four replanted coffee fields with 4, 18, 26 and 57 years of monoculture history in Hainan China to investigate the influence of continuous cropping on soil chemical properties and microbial communities. Results showed long-term monoculture decreased soil pH and organic matter content and increased soil EC. Soil bacterial and fungal richness decreased with continuous coffee cropping. Principal coordinate analysis suggested monoculture time was a major determinant of bacterial and fungal community structures. Relative abundances of bacterial Proteobacteria, Bacteroidetes and Nitrospira and fungal Ascomycota phyla decreased over time. At genus level, potentially beneficial microbes such as Nitrospira and Trichoderma, significantly declined over time and showed positive relationships with coffee plant growth in pots. In conclusion, continuous coffee cropping decreased soil pH, organic matter content, potentially beneficial microbes and increased soil EC, which might lead to the poor growth of coffee plants in pots and decline of coffee yields in fields. Thus, developing sustainable agriculture to improve soil pH, organic matter content, microbial activity and reduce the salt stress under continuous cropping system is important for coffee production in China.

Health and environmental effects of complex chemical mixtures: proceedings

Energy Technology Data Exchange (ETDEWEB)

1985-01-01

The Office of Health and Environmental Research (OHER) of the Department of Energy supports a broad long-term research program on human health and environmental effects from potential exposure to energy-related complex chemical mixtures. The program seeks basic mechanistic data on the effects of complex mixtures at the cellular, molecular, and whole animal levels to aid in predicting human health effects and seeks ecological data on biological and physical transformations in the mixtures, concentrations of the mixtures in various compartments of the environment, and potential routes for human exposure to these mixtures (e.g., food chain). On June 17-18, 1985, OHER held its First Annual Technical Meeting on the Complex Chemical Mixtures Program in Chicago, IL. The primary purpose of the meeting was to enable principal investigators to report the research status and accomplishments of ongoing complex chemical mixture studies supported by OHER. To help focus future research directions round table discussions were conducted.

Annual report 1985 Chemistry Department

International Nuclear Information System (INIS)

1987-01-01

This annual report describes the activities carried out in 1985 by the Chemistry Department in the following fields: Chemistry, Inorganic Chemistry, Physicochemistry (Interphases, Surfaces), General Chemical Analysis, Active Materials Analysis, X Ray Fluorescence Analysis, Mass Spectroscopy (Isotopic Analysis, Instrumentation) and Optical Spectroscopy. A list of publications is enclosed. (M.E.L.) [es

78 FR 55326 - Determinations Regarding Use of Chemical Weapons in Syria Under the Chemical and Biological...

Science.gov (United States)

2013-09-10

... DEPARTMENT OF STATE [Public Notice 8460] Determinations Regarding Use of Chemical Weapons in Syria Under the Chemical and Biological Weapons Control and Warfare Elimination Act of 1991 AGENCY: Bureau of... Government has determined on August 2, pursuant to Section 306(a) of the Chemical and Biological Weapons...

Environmental/chemical thesaurus

International Nuclear Information System (INIS)

Shriner, C.R.; Dailey, N.S.; Jordan, A.C.; Miller, K.C.; Owens, E.T.; Rickert, L.W.

1978-06-01

The Environmental/Chemical Thesaurus approaches scientific language control problems from a multidisciplinary view. The Environmental/Biomedical Terminology Index (EBTI) was used as a base for the present thesaurus. The Environmental/Chemical Thesaurus, funded by the Environmental Protection Agency, used as its source of new terms those major terms found in 13 Environmental Protection Agency data bases. The scope of this thesaurus includes not only environmental and biomedical sciences, but also the physical sciences with emphasis placed on chemistry. Specific chemical compounds are not included; only classes of chemicals are given. To adhere to this level of classification, drugs and pesticides are identified by class rather than by specific chemical name. An attempt was also made to expand the areas of sociology and economics. Terminology dealing with law, demography, and geography was expanded. Proper names of languages and races were excluded. Geographic terms were expanded to include proper names for oceans, continents, major lakes, rivers, and islands. Political divisions were added to allow for proper names of countries and states. With such a broad scope, terminology for specific sciences does not provide for indexing to the lowest levels in plant, animal, or chemical classifications

Environmental/chemical thesaurus

Energy Technology Data Exchange (ETDEWEB)

Shriner, C.R.; Dailey, N.S.; Jordan, A.C.; Miller, K.C.; Owens, E.T.; Rickert, L.W.

1978-06-01

The Environmental/Chemical Thesaurus approaches scientific language control problems from a multidisciplinary view. The Environmental/Biomedical Terminology Index (EBTI) was used as a base for the present thesaurus. The Environmental/Chemical Thesaurus, funded by the Environmental Protection Agency, used as its source of new terms those major terms found in 13 Environmental Protection Agency data bases. The scope of this thesaurus includes not only environmental and biomedical sciences, but also the physical sciences with emphasis placed on chemistry. Specific chemical compounds are not included; only classes of chemicals are given. To adhere to this level of classification, drugs and pesticides are identified by class rather than by specific chemical name. An attempt was also made to expand the areas of sociology and economics. Terminology dealing with law, demography, and geography was expanded. Proper names of languages and races were excluded. Geographic terms were expanded to include proper names for oceans, continents, major lakes, rivers, and islands. Political divisions were added to allow for proper names of countries and states. With such a broad scope, terminology for specific sciences does not provide for indexing to the lowest levels in plant, animal, or chemical classifications.

Replacing tedium with transformation: Why the US Department of Energy needs to change the way it conducts long-term R and D

International Nuclear Information System (INIS)

Sovacool, Benjamin K.

2008-01-01

To avoid promoting technologies that merely produce incremental change, the US Department of Energy needs to establish a new organization designed to focus on transformational R and D projects. From its inception in 1977, the US Department of Energy (DOE) has been responsible for maintaining the nation's nuclear stockpile, leading the country in terms of basic research, setting national energy goals, and managing thousands of individual programs. Despite these responsibilities, however, the DOE research and development (R and D) model does not appear to offer the nation an optimal strategy for assessing long-term energy challenges. American energy policy continues to face constraints related to an overly rigid management structure and loss of mission within the DOE, layers of stove-piping within and between the national laboratories, and inadequate public and private funding for energy R and D. To address these concerns, an independent organization dedicated to transformative, creative energy R and D is required

Survey and discussion of models applicable to the transport and fate thrust area of the Department of Energy Chemical and Biological Nonproliferation Program

Energy Technology Data Exchange (ETDEWEB)

NONE

1997-09-01

The availability and easy production of toxic chemical and biological agents by domestic and international terrorists pose a serious threat to US national security, especially to civilian populations in and around urban areas. To address this threat, the Department of Energy (DOE) has established the Chemical and Biological Nonproliferation Program (CBNP) with the goal of focusing the DOE`s technical resources and expertise on capabilities to deny, deter, mitigate and respond to clandestine releases of chemical and biological agents. With the intent to build on DOE core competencies, the DOE has established six technology thrust areas within the CBNP Program: Biological Information Resources; Point Sensor Systems; Stand-off Detection; Transport and Fate; Decontamination; and Systems Analysis and Integration. The purpose of the Transport and Fate Thrust is to accurately predict the dispersion, concentration and ultimate fate of chemical and biological agents released into the urban and suburban environments and has two major goals: (1) to develop an integrated and validated state-of-the-art atmospheric transport and fate modeling capability for chemical and biological agent releases within the complex urban environment from the regional scale down to building and subway interiors, and (2) to apply this modeling capability in a broad range of simulation case studies of chemical and biological agent release scenarios in suburban, urban and confined (buildings and subways) environments and provide analysis for the incident response user community. Sections of this report discuss subway transport and fate models; buildings interior transport and fate modeling; models for flow and transport around buildings; and local-regional meteorology and dispersion models.

Some chemical and physico-mechanical properties of pear cultivars

African Journals Online (AJOL)

STORAGESEVER

2009-02-18

Feb 18, 2009 ... carried out at the Biological Material Laboratory in Agricultural. Machinery Department and Fruit Science Laboratory in Horticulture. Department of Ataturk University, Erzurum, Turkey. Chemical analysis. All chemical properties of the pear cultivars were investigated on randomly selected fifty fruit samples.

Nonradioactive Environmental Emissions Chemical Source Term for the Double-Shell Tank (DST) Vapor Space During Waste Retrieval Operations

International Nuclear Information System (INIS)

MAY, T.H.

2000-01-01

A nonradioactive chemical vapor space source term for tanks on the Phase 1 and the extended Phase 1 delivery, storage, and disposal mission was determined. Operations modeled included mixer pump operation and DST waste transfers. Concentrations of ammonia, specific volatile organic compounds, and quantitative volumes of aerosols were estimated

76 FR 34732 - Privacy Act of 1974; Department of Homeland Security/National Protection and Programs Directorate...

Science.gov (United States)

2011-06-14

... 1974; Department of Homeland Security/National Protection and Programs Directorate--002 Chemical... Homeland Security/National Protection and Programs Directorate--002 Chemical Facility Anti-Terrorism.... 552a, the Department of Homeland Security (DHS)/National Protection and Programs Directorate (NPPD...

Successful peroral endoscopic myotomy performed in Endoscopy Department as a radical, long-term treatment for esophageal achalasia – the Greek experience

Directory of Open Access Journals (Sweden)

Eleftheriadis N

2017-02-01

Full Text Available Nikolas Eleftheriadis,1,2 Eleni Damianos Eleftheriadou2 1Endoscopy Department, Gastroenterology Unit, Metropolitan Hospital Athens, 2Medical School, Aristotle University of Thessaloniki, Thessaloniki, Greece Introduction: Peroral endoscopic myotomy (POEM has been considered as a minimal-invasive, innovative technique for long-term treatment of all types of esophageal achalasia and other esophageal motility disorders.Patients and methods: We report on 20 consecutive Greek patients with manometrically proved esophageal achalasia (14 patients with type I, 4 with type II, 2 with type III, and 4 with sigmoid esophagus, with an age range of 32–92 years, mean age 59 years, 12 males, successfully treated by POEM from 2013 to 2015. The Eckardt score was 7–12 (type III. Seventeen (85% POEM procedures were performed in the Endoscopy Department, according to a previous study. During POEM, CO2 insufflation was mandatory, while the Triangle Tip knife was the only knife used in all procedures. Eckardt score, esophagogram and manometry before and after performing POEM were used for evaluation of our results. The follow-up period was 6 months to 3 years.Results: Selective circular myotomy, 10–13 cm in length, was successfully completed in all patients without severe acute or late complications. Three patients (15% showed moderate pneumomediastinum and pneumoperitoneum, which was successfully managed by abdominal needle drainage during the procedure. One patient showed mild pleural collection, and in one patient the clip–endoloop technique was used to successfully close the mucosal entry after the completion of POEM. The outcome was uneventful without any further clinical consequences. No other short- or long-term serious complications were reported. Patients were discharged after 1–3 days of hospitalization. Six months to 3 years after the POEM procedure, all patients were alive; the majority (90% had complete clinical improvement, while two patients

Human biomonitoring after chemical incidents and during short-term maintenance work as a tool for exposure analysis and assessment.

Science.gov (United States)

Bader, M; Van Weyenbergh, T; Verwerft, E; Van Pul, J; Lang, S; Oberlinner, C

2014-12-15

Human biomonitoring (HBM) is frequently used for the analysis and assessment of exposure to chemicals under routine working conditions. In recent years, HBM has also been applied to monitor the exposure of the general population, and of emergency responders in the aftermath of chemical incidents. Two examples of targeted HBM programs in the chemical industry are described and discussed in this paper: (1) analysis and assessment of the exposure of firefighters and chemical workers after the spill of p-chloroaniline from a burning chemical barrel, and (2) biomonitoring of maintenance workers potentially exposed to benzene during regular turnarounds. The results of these investigations underline that human biomonitoring contributes substantially to comprehensive exposure analyses, human health risk assessments and communication. In addition, regular HBM surveillance and feedback can assist in the continuous improvement of workplace safety measures and exposure control. In conclusion, data on accidental or short-term exposure to hazardous chemicals are an important source of information for the further development of limit and assessment values, the validation of biomarkers and of targeted HBM programs for both routine monitoring and disaster management. Copyright © 2014 Elsevier Ireland Ltd. All rights reserved.

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Department of Chemistry and Chemical Engineering, Hefei Normal University, Hefei 230061, China; Food and Drug Department, Qingyuan Polytechnic, Qingyuan 511510, P. R. China; Department of City Science, The City Vocational College of Jiangsu, Nanjing 210017, China; Department of Science and Technology, ...

Department of Defense Dictionary of Military and Associated Terms

Science.gov (United States)

2016-02-15

via an aeromedical evacuation system or system echelon. (JP 4-02) aeronautical chart — A specialized representation of mapped features of the Earth...blisters the skin. Also called vesicant agent. (JP 3-11) blood agent — A chemical compound, including the cyanide group, that affects bodily functions...combat and operational stress — The expected and predictable emotional , intellectual, physical, and/or behavioral reactions of an individual who has

Biosynthetic hydrogels--studies on chemical and physical characteristics on long-term cellular response for tissue engineering.

Science.gov (United States)

Thankam, Finosh Gnanaprakasam; Muthu, Jayabalan

2014-07-01

Biosynthetic hydrogels can meet the drawbacks caused by natural and synthetic ones for biomedical applications. In the current article we present a novel biosynthetic alginate-poly(propylene fumarate) copolymer based chemically crosslinked hydrogel scaffolds for cardiac tissue engineering applications. Partially crosslinked PA hydrogel and fully cross linked PA-A hydrogel scaffolds were prepared. The influence of chemical and physical (morphology and architecture of hydrogel) characteristics on the long term cellular response was studied. Both these hydrogels were cytocompatible and showed no genotoxicity upon contact with fibroblast cells. Both PA and PA-A were able to resist deleterious effects of reactive oxygen species and sustain the viability of L929 cells. The hydrogel incubated oxidative stress induced cells were capable of maintaining the intra cellular reduced glutathione (GSH) expression to the normal level confirmed their protective effect. Relatively the PA hydrogel was found to be unstable in the cell culture medium. The PA-A hydrogel was able to withstand appreciable cyclic stretching. The cyclic stretching introduced complex macro and microarchitectural features with interconnected pores and more structured bound water which would provide long-term viability of around 250% after the 24th day of culture. All these qualities make PA-A hydrogel form a potent candidate for cardiac tissue engineering. © 2013 Wiley Periodicals, Inc.

Long-term fertilization alters chemically-separated soil organic carbon pools: Based on stable C isotope analyses

Science.gov (United States)

Dou, Xiaolin; He, Ping; Cheng, Xiaoli; Zhou, Wei

2016-01-01

Quantification of dynamics of soil organic carbon (SOC) pools under the influence of long-term fertilization is essential for predicting carbon (C) sequestration. We combined soil chemical fractionation with stable C isotope analyses to investigate the C dynamics of the various SOC pools after 25 years of fertilization. Five types of soil samples (0-20, 20-40 cm) including the initial level (CK) and four fertilization treatments (inorganic nitrogen fertilizer, IN; balanced inorganic fertilizer, NPK; inorganic fertilizer plus farmyard manure, MNPK; inorganic fertilizer plus corn straw residue, SNPK) were separated into recalcitrant and labile fractions, and the fractions were analysed for C content, C:N ratios, δ13C values, soil C and N recalcitrance indexes (RIC and RIN). Chemical fractionation showed long-term MNPK fertilization strongly increased the SOC storage in both soil layers (0-20 cm = 1492.4 gC m2 and 20-40 cm = 1770.6 gC m2) because of enhanced recalcitrant C (RC) and labile C (LC). The 25 years of inorganic fertilizer treatment did not increase the SOC storage mainly because of the offsetting effects of enhanced RC and decreased LC, whereas no clear SOC increases under the SNPK fertilization resulted from the fast decay rates of soil C.

Annual report 1988 Chemistry Department

International Nuclear Information System (INIS)

Funck, J.; Neve Larsen, Aa.; Larsen, E.; Nielsen, O.J.

1989-05-01

This report contains a brief survey of the main activities in the Chemistry Department. The names and abstracts of all articles and reports published and lectures given in 1988 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, chemical reactivity, mineral processing, and general. (author)

Annual report 1989 Chemistry Department

International Nuclear Information System (INIS)

Funck, J.; Neve Larsen, Aa.; Larsen, E.; Nielsen, O.J.

1990-03-01

This report contains a brief survey of the main activities in the Chemistry Department. The names and abstracts of all articles and reports published and lectures given in 1989 are presented. The facilities and equipment are mentioned briefly. The activities are divided into the following groups: radioisotope chemistry, analytical- and organic chemistry, environmental chemistry, polymer chemistry, chemical reactivity, mineral processing, and general. (author)

Teaching Chemical Engineers about Teaching

Science.gov (United States)

Heath, Daniel E.; Hoy, Mary; Rathman, James F.; Rohdieck, Stephanie

2013-01-01

The Chemical and Biomolecular Engineering Department at The Ohio State University in collaboration with the University Center for the Advancement of Teaching developed the Chemical Engineering Mentored Teaching Experience. The Mentored Teaching Experience is an elective for Ph.D. students interested in pursuing faculty careers. Participants are…

Chemicals Industry Vision

Energy Technology Data Exchange (ETDEWEB)

none,

1996-12-01

Chemical industry leaders articulated a long-term vision for the industry, its markets, and its technology in the groundbreaking 1996 document Technology Vision 2020 - The U.S. Chemical Industry. (PDF 310 KB).

Analysis of accident sequences and source terms at waste treatment and storage facilities for waste generated by U.S. Department of Energy Waste Management Operations, Volume 1: Sections 1-9

International Nuclear Information System (INIS)

Mueller, C.; Nabelssi, B.; Roglans-Ribas, J.

1995-04-01

This report documents the methodology, computational framework, and results of facility accident analyses performed for the U.S. Department of Energy (DOE) Waste Management Programmatic Environmental Impact Statement (WM PEIS). The accident sequences potentially important to human health risk are specified, their frequencies are assessed, and the resultant radiological and chemical source terms are evaluated. A personal computer-based computational framework and database have been developed that provide these results as input to the WM PEIS for calculation of human health risk impacts. The methodology is in compliance with the most recent guidance from DOE. It considers the spectrum of accident sequences that could occur in activities covered by the WM PEIS and uses a graded approach emphasizing the risk-dominant scenarios to facilitate discrimination among the various WM PEIS alternatives. Although it allows reasonable estimates of the risk impacts associated with each alternative, the main goal of the accident analysis methodology is to allow reliable estimates of the relative risks among the alternatives. The WM PEIS addresses management of five waste streams in the DOE complex: low-level waste (LLW), hazardous waste (HW), high-level waste (HLW), low-level mixed waste (LLMW), and transuranic waste (TRUW). Currently projected waste generation rates, storage inventories, and treatment process throughputs have been calculated for each of the waste streams. This report summarizes the accident analyses and aggregates the key results for each of the waste streams. Source terms are estimated and results are presented for each of the major DOE sites and facilities by WM PEIS alternative for each waste stream. The appendices identify the potential atmospheric release of each toxic chemical or radionuclide for each accident scenario studied. They also provide discussion of specific accident analysis data and guidance used or consulted in this report

Local chemical potential, local hardness, and dual descriptors in temperature dependent chemical reactivity theory.

Science.gov (United States)

Franco-Pérez, Marco; Ayers, Paul W; Gázquez, José L; Vela, Alberto

2017-05-31

In this work we establish a new temperature dependent procedure within the grand canonical ensemble, to avoid the Dirac delta function exhibited by some of the second order chemical reactivity descriptors based on density functional theory, at a temperature of 0 K. Through the definition of a local chemical potential designed to integrate to the global temperature dependent electronic chemical potential, the local chemical hardness is expressed in terms of the derivative of this local chemical potential with respect to the average number of electrons. For the three-ground-states ensemble model, this local hardness contains a term that is equal to the one intuitively proposed by Meneses, Tiznado, Contreras and Fuentealba, which integrates to the global hardness given by the difference in the first ionization potential, I, and the electron affinity, A, at any temperature. However, in the present approach one finds an additional temperature-dependent term that introduces changes at the local level and integrates to zero. Additionally, a τ-hard dual descriptor and a τ-soft dual descriptor given in terms of the product of the global hardness and the global softness multiplied by the dual descriptor, respectively, are derived. Since all these reactivity indices are given by expressions composed of terms that correspond to products of the global properties multiplied by the electrophilic or nucleophilic Fukui functions, they may be useful for studying and comparing equivalent sites in different chemical environments.

After laparoscopic Heller myotomy, do emergency department visits or readmissions predict poor long-term outcomes?

Science.gov (United States)

Ross, Sharona; Villadolid, Desiree; Al-Saadi, Sam; Boyle, Robert; Cowgill, Sarah M; Rosemurgy, Alexander

2008-12-01

Laparoscopic Heller myotomy is a first-line treatment for achalasia. To improve outcomes after myotomy and to determine if poor early results predict later outcomes, emergency department (ED) visits and readmissions within 60 days following laparoscopic Heller myotomy were studied. Since 1992, 352 patients have undergone laparoscopic Heller myotomy and are followed through a prospectively maintained registry. Causes of ED visits and readmissions within 60 days after myotomy were determined. Patients scored their symptoms of achalasia before myotomy and at last follow-up; scores were compared to determine if the reasons leading to ED visits and/or readmissions impacted long-term outcome after myotomy. Fourteen (4%) patients had ED visits, and 18 (5%) patients had readmissions within 60 days following myotomy. Sixty-four percent of ED visits were for dysphagia/vomiting and 36% were for abdominal/chest pain, while 37% of readmissions were for dysphagia/vomiting. Pneumonia was complicated by empyema in four patients, all without leaks; two patients expired. Despite ED visits/readmissions, achalasia symptom (e.g., dysphagia, regurgitation, choking, heartburn, and chest pain) frequency and severity scores improved after myotomy (p Heller myotomy. ED visits were generally due to complaints related to achalasia or edema after myotomy, while readmissions were generally related to complications of operative intervention or chronic ill health. Despite ED visits or readmissions early after myotomy, symptoms of achalasia are well palliated by myotomy long-term.

Annual Report 1998: Chemical Structure and Dynamics

Energy Technology Data Exchange (ETDEWEB)

SD Colson; RS McDowell

1999-05-10

The Chemical Structure and Dynamics (CS&D) program is a major component of the William R. Wiley Environmental Molecular Sciences Labo- ratory (EMSL), developed by Pacific Northwest National Laboratory (PNNL) to provide a state-of- the-art collaborative facility for studies of chemical structure and dynamics. We respond to the need for a fundamental, molecular-level understanding of chemistry at a wide variety of environmentally important interfaces by (1) extending the experimental characterization and theoretical description of chemical reactions to encompass the effects of condensed media and interfaces; (2) developing a multidisciplinary capability for describing interracial chemical processes within which the new knowledge generated can be brought to bear on complex phenomena in envi- ronmental chemistry and in nuclear waste proc- essing and storage; and (3) developing state-of- the-art analytical methods for characterizing com- plex materials of the types found in stored wastes and contaminated soils, and for detecting and monitoring trace atmospheric species. Our program aims at achieving a quantitative understanding of chemical reactions at interfaces and, more generally, in condensed media, compa- rable to that currently available for gas-phase reactions. This understanding will form the basis for the development of a priori theories for pre- dicting macroscopic chemical behavior in con- densed and heterogeneous media, which will add significantly to the value of field-scale envi- ronmental models, predictions of short- and long- term nuclear waste storage stabilities, and other areas related to the primary missions of the U.S. Department of Energy (DOE).

Central Safety Department, annual report 1987

International Nuclear Information System (INIS)

Kiefer, H.; Koenig, L.A.

1988-02-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The r+d work concentrates on the following aspects: physical and chemical behaviour of biologically particularly active radionuclides, behaviour of HT in the air/plan/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1987 routine tasks and reports about results of investigations and developments of the working groups of the Department. (orig./HP) [de

RxTerms

Data.gov (United States)

U.S. Department of Health & Human Services — RxTerms is a drug interface terminology derived from RxNorm for prescription writing or medication history recording (e.g. in e-prescribing systems, PHRs). RxTerms...

Improving short-term air quality predictions over the U.S. using chemical data assimilation

Science.gov (United States)

Kumar, R.; Delle Monache, L.; Alessandrini, S.; Saide, P.; Lin, H. C.; Liu, Z.; Pfister, G.; Edwards, D. P.; Baker, B.; Tang, Y.; Lee, P.; Djalalova, I.; Wilczak, J. M.

2017-12-01

State and local air quality forecasters across the United States use air quality forecasts from the National Air Quality Forecasting Capability (NAQFC) at the National Oceanic and Atmospheric Administration (NOAA) as one of the key tools to protect the public from adverse air pollution related health effects by dispensing timely information about air pollution episodes. This project funded by the National Aeronautics and Space Administration (NASA) aims to enhance the decision-making process by improving the accuracy of NAQFC short-term predictions of ground-level particulate matter of less than 2.5 µm in diameter (PM2.5) by exploiting NASA Earth Science Data with chemical data assimilation. The NAQFC is based on the Community Multiscale Air Quality (CMAQ) model. To improve the initialization of PM2.5 in CMAQ, we developed a new capability in the community Gridpoint Statistical Interpolation (GSI) system to assimilate Terra/Aqua Moderate Resolution Imaging Spectroradiometer (MODIS) aerosol optical depth (AOD) retrievals in CMAQ. Specifically, we developed new capabilities within GSI to read/write CMAQ data, a forward operator that calculates AOD at 550 nm from CMAQ aerosol chemical composition and an adjoint of the forward operator that translates the changes in AOD to aerosol chemical composition. A generalized background error covariance program called "GEN_BE" has been extended to calculate background error covariance using CMAQ output. The background error variances are generated using a combination of both emissions and meteorological perturbations to better capture sources of uncertainties in PM2.5 simulations. The newly developed CMAQ-GSI system is used to perform daily 24-h PM2.5 forecasts with and without data assimilation from 15 July to 14 August 2014, and the resulting forecasts are compared against AirNOW PM2.5 measurements at 550 stations across the U. S. We find that the assimilation of MODIS AOD retrievals improves initialization of the CMAQ model

Successful peroral endoscopic myotomy performed in Endoscopy Department as a radical, long-term treatment for esophageal achalasia - the Greek experience.

Science.gov (United States)

Eleftheriadis, Nikolas; Eleftheriadou, Eleni Damianos

2017-01-01

Peroral endoscopic myotomy (POEM) has been considered as a minimal-invasive, innovative technique for long-term treatment of all types of esophageal achalasia and other esophageal motility disorders. We report on 20 consecutive Greek patients with manometrically proved esophageal achalasia (14 patients with type I, 4 with type II, 2 with type III, and 4 with sigmoid esophagus), with an age range of 32-92 years, mean age 59 years, 12 males, successfully treated by POEM from 2013 to 2015. The Eckardt score was 7-12 (type III). Seventeen (85%) POEM procedures were performed in the Endoscopy Department, according to a previous study. During POEM, CO 2 insufflation was mandatory, while the Triangle Tip knife was the only knife used in all procedures. Eckardt score, esophagogram and manometry before and after performing POEM were used for evaluation of our results. The follow-up period was 6 months to 3 years. Selective circular myotomy, 10-13 cm in length, was successfully completed in all patients without severe acute or late complications. Three patients (15%) showed moderate pneumomediastinum and pneumoperitoneum, which was successfully managed by abdominal needle drainage during the procedure. One patient showed mild pleural collection, and in one patient the clip-endoloop technique was used to successfully close the mucosal entry after the completion of POEM. The outcome was uneventful without any further clinical consequences. No other short- or long-term serious complications were reported. Patients were discharged after 1-3 days of hospitalization. Six months to 3 years after the POEM procedure, all patients were alive; the majority (90%) had complete clinical improvement, while two patients with sigmoid-type achalasia showed moderate-to-significant clinical improvement. Erosive esophagitis was reported in 15%. Our results are in accordance with international data, and proved the safety and efficacy of the POEM technique for radical long-term treatment of all

PROBLEMS OF IT DEPARTMENT IN A MEDICAL UNIVERSITY

Directory of Open Access Journals (Sweden)

V. Ya Gelman

2017-01-01

Full Text Available The aim of the study is the analysis of the problems faced by heads and staff of IT departments in medical universities. Methodology and research methods. The methods involve expert estimation, analysis and generalization of practical work experience of IT departments. Results and scientific novelty. The main aspects and specifics of professional activity of IT departments of modern medical schools are designated. The approaches to the definition of the hierarchy of goals in the professional activities of the department, as well as quantitative and qualitative indicators that assess the effectiveness of their achievements are analyzed. The contradictions arising between long-term and short-term goals of the IT department are highlighted. The main challenges which heads of IT departments can deal with in the course of day-to-day management work planning are described. The problems arising in educational, educational-methodical and scientific work of department, in its economic activity, solution of personnel affairs, and aspects of material support are considered. The possible solutions to these problems are proposed. Practical significance. The results of the analysis, proposed approaches and practical recommendations will enable to better organize the work of the IT department in a medical school. The advantage of the proposed approaches consists in their versatility: with some adjustment, they can be used by other departments, regardless of the specifics and the type of educational institution.

46 CFR 154.1145 - Dry chemical supply.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Dry chemical supply. 154.1145 Section 154.1145 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SAFETY STANDARDS... Firefighting System: Dry Chemical § 154.1145 Dry chemical supply. (a) A vessel with a cargo carrying capacity...

Board on chemical sciences and technology

International Nuclear Information System (INIS)

1991-01-01

The Board on Chemical Sciences and Technology organizes and provides direction for standing and ad-hoc committees charged with addressing specific issues relevant to the continued health of the chemical sciences and technology community. Studies currently under the oversight of the BCST include a major survey of the chemical sciences, a complementary survey of chemical engineering, an examination of the problems of biohazards in the laboratory, and an analysis of the roots and magnitude of the problem of obsolescent facilities for research and teaching in departments in the chemical sciences and engineering. The Board continues to respond to specific agency requests for program assessments and advice. BCST members are designated to serve as liaison with major federal agencies or departments that support research in order to help identify ways for the Board to assist these organizations. The BCST maintains close contact with professional societies and non-governmental organizations that share the Board's concern for the health of chemical sciences and technology. Individual Board members are assigned responsibility for liaison with the American Chemical Society, the American Institute of Chemical Engineers, the American Society of Biological Chemists, the Council for Chemical Research, the NAS Chemistry and Biochemistry Sections, and the National Academy of Engineering. In the past few years, the Board has served as a focus and a forum for a variety of issues that relate specifically to the health of chemistry

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Department of Chemistry, SPW Degree and PG College, Tirupati, Andhra Pradesh 517 502, India; Chemical Research Department, R&D Centre, API Division, Micro Labs Ltd., Jigani-Bommasandra Link Road, Bangalore, Karnataka 560 105, India; Department of Chemistry, Sri Venkateswara University, Tirupati, Andhra ...

Long-term measurement of aerosol chemical composition in Athens, Greece.

Science.gov (United States)

Paraskevopoulou, Despina; Liakakou, Eleni; Theodosi, Christina; Gerasopoulos, Evangelos; Mihalopoulos, Nikolaos

2014-05-01

The collection of our samples was conducted for a period of five years (2008 - 2013) in Athens, Greece. The site is situated at the premises of the National Observatory of Athens on Penteli Hill, northeast Athens suburbs, and is considered an urban background station. The aim of our study was a first long-term estimation of the chemical mass closure of aerosol. For the purposes of the study, we applied three filter samplers during the sampling period: two Partisol FRM Model 2000 air samplers (one of them collecting PM10 and the other PM2.5 fractions of aerosol) and one Dichotomous Partisol auto-sampler (with PM2.5 and PM2.5-10 inlet). Aerosols were collected on Whatman QM-A quartz fiber filters and the mass of the collected samples was estimated by weighing the pre-combusted filters before and after sampling, under controlled conditions, using a microbalance. All quartz filters were analysed for organic (OC) and elemental carbon (EC) by a thermal - optical transmission technique. The concentration of water soluble organic carbon (WSOC) was defined for each filter using a total organic carbon analyzer, while the content in main water soluble ions (Cl-, Br-, NO-3, SO4-2, PO4-3, C2O4-2, NH4+, K+, Na+, Mg+2, Ca+2) was determined by ion chromatography. Additionally the filters were analyzed for trace metals by inductively coupled plasma optical emission spectrometry (ICP-OES). Aerosol chemical mass closure calculations were conducted for the PM2.5 fraction. The area of Athens is characterized by aged aerosol that can originate from the marine boundary layer, the European mainland and occasionally from North African desert areas. The contribution of dust and particulate organic matter on PM levels was estimated taking into consideration the location of the sampling site, while identification and evaluation of sources was performed. Additionally, non-sea salt concentrations of the main ions were estimated to complete the chemical closure in the extended area. According to

A long-term variation of chemical composition in precipitation

International Nuclear Information System (INIS)

Yoshioka, Ryuma; Okimura, Takashi; Okumura, Takenobu

1991-01-01

Precipitation samples are collected at the six localities in the southwestern Japan weekly or monthly over a long period of time (1978-1989) in order to estimate chemical weathering rates and amount of weathered materials through chemical composition in natural waters. Major chemical composition is determined for the precipitation samples. Together with the data available in the literature, the following characteristics are recognized : 1) Most pH values fall in the narrow range of 4.4 to 5.4, 2) Systematic variations in pH values are observed among the precipitation samples of different geologic environments, 3) pH values become almost constant from 1984 to 1989, 4) NO 3 - concentrations gradually decrease to an almost constant value with time, and 5) ΔSO 4 2- concentrations gradually have a tendency to decrease from 1978 to 1985. The mechanism of phenomena described above is also presented. (author)

Some comments on misuse of terms related to chemical analysis

International Nuclear Information System (INIS)

Steinnes, E.

2007-01-01

Complet text of publication follows. I have been involved in scientific studies involving chemical analysis for more than 49 years. Over this period I have observed an increasing tendency to incorrect use of terms 'analysis' and 'determination' and the corresponding verbum forms. According to correct terminology in English, samples are analyzed, analytes (e.g., trace elements) are determined. However, too often expressions such as 'analysis of copper in blood' are seen in the literature, especially in papers written by non-chemists. The reason why I am raising this point at the present time in that I observed the problem in several recent titles of papers published over the last few years in the Journal of Radioanalytical and Nuclear Chemistry: Preconcentration and neutron activation analysis of thorium and uranium in natural waters. Use of activated carbon as pre-separation agent in NAA of selenium, cobalt and iodine. Recent developments in the analysis of transuranics (Np, Pu, Am) in sea water. Automated radiochemical analysis of total 99 Tc in aged nuclear waste processing streams. Photon activation analysis of carbon in glasses for fiber amplifiers by using the flow method for the rapid separation of 11 C. Preconcentration neutron activation analysis of lanthanides by cloudpoint extraction using PAN. Analysis of the chemical elements in leaves infected by fumagina by X-ray fluorescence technique. Rapid method for 226 Ra and 228 Ra analysis in water samples. The above list is far from exhaustive. I believe that this incorrect use of terminology should be avoided at least in the titles of scientific papers, in Journal of Radioanalytical and Nuclear Chemistry as well as in other scientific journals. In some of the above cases replacing 'of' with 'for the determination of', or just with 'for', would have solved the problem. In other cases it would be preferable to reverse the order of words in the sentence, such as e.g., 'Determination of selenium, cobalt and

Long-term monitored catchments in Norway - a hydrologic and chemical evaluation -

Energy Technology Data Exchange (ETDEWEB)

Lydersen, E

1994-10-20

About 20 years ago, long-term monitoring of small Norwegian catchments were initiated, because of increasing concern regarding acidification of surface water and damage to fish populations. Long range transported air pollutants were considered to be the major acidification factor and so both precipitation and runoff chemistry were included in the monitoring programme. This report contains a thorough hydrologic and chemical evaluation of precipitation and runoff water separately as well as relationships between precipitation chemistry and runoff chemistry. The data comes from four catchments: Birkenes, Storgama, Langtjern and Kaarvatn. The chapters are (1) Sampling and analysis, (2) Description of the catchments, (3) Hydrology, (4) Chemistry, with subsections on wet deposition, dry deposition, concentration of marine compounds with distance from the sea, acid precipitation, runoff chemistry, sulphuric acid and other acidifying compounds, acid neutralizing capacity, and aluminium, (5) Time trends in precipitation and runoff chemistry. The time trends are evaluated in relation to the declining emissions of sulphur compounds in Europe since the late seventies. 134 refs., 213 figs., 54 tabs.

Budgeting in an imaging Department

International Nuclear Information System (INIS)

Nyalla, A. M.

2006-01-01

budgeting form an integral part of an imaging department. It is a plan to cope with necessary expenses in the future. It involves identifying the needs and income sources required to cover the needs.Covers specific items and time-usually a year and is expressed in monetary terms. The micro budget is put in the macro budget of the hospital. defines financial support for the department. Considers: a fiscal year, projection of patients, types of examinations, type of equipment, monetary exchange, and inflation rate

Short-term response of Holcus lanatus L. (Common Velvetgrass) to chemical and manual control at Yosemite National Park, USA

Science.gov (United States)

Jones, Laura J.; Ostoja, Steven M.; Brooks, Matthew L.; Hutten, Martin

2015-01-01

One of the highest priority invasive species at both Yosemite and Sequoia and Kings Canyon national parks is Holcus lanatus L. (common velvetgrass), a perennial bunchgrass that invades mid-elevation montane meadows. Despite velvetgrass being a high priority species, there is little information available on control techniques. The goal of this project was to evaluate the short-term response of a single application of common chemical and manual velvetgrass control techniques. The study was conducted at three montane sites in Yosemite National Park. Glyphosate spot-spray treatments were applied at 0.5, 1.0, 1.5, and 2.0% concentrations, and compared with hand pulling to evaluate effects on cover of common velvetgrass, cover of other plant species, and community species richness. Posttreatment year 1 cover of common velvetgrass was 12.1% ± 1.6 in control plots, 6.3% ± 1.5 averaged over the four chemical treatments (all chemical treatments performed similarly), and 13.6% ± 1.7 for handpulled plots. This represents an approximately 50% reduction in common velvetgrass cover in chemically- treated plots recoded posttreatment year 1 and no statistically significant reduction in hand pulled plots compared with controls. However, there was no treatment effect in posttreatment year 2, and all herbicide application rates performed similarly. In addition, there were no significant treatment effects on nontarget species or species richness. These results suggest that for this level of infestation and habitat type, (1) one year of hand pulling is not an effective control method and (2) glyphosate provides some level of control in the short-term without impact to nontarget plant species, but the effect is temporary as a single year of glyphosate treatment is ineffective over a two-year period.

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

1 V Ferretti2. Department of Chemistry and Centre of Advanced Studies in Chemistry, Panjab University, Chandigarh 160 014, India; Center for Structural Diffractometry and Department of Chemical and Pharmaceutical Sciences, University of ...

Progress report 1983-1984 Reactor Chemistry Department

International Nuclear Information System (INIS)

1985-11-01

Description of the activity developed by the Reactor Chemistry Department of the National Atomic Energy Commission during the period 1983-1984 in its four divisions: Chemical Control; Moderator and Refrigerant Chemistry; Radiation Chemistry and Nuclear Power Plant's Service. A list of the publications made by the personnel during this period is also included. (M.E.L.) [es

Short-Term and Long-Term Biological Effects of Chronic Chemical Contamination on Natural Populations of a Marine Bivalve.

Directory of Open Access Journals (Sweden)

Marine Breitwieser

Full Text Available Understanding the effects of chronic chemical contamination on natural populations of marine organisms is complex due to the combined effects of different types of pollutants and environmental parameters that can modulate the physiological responses to stress. Here, we present the effects of a chronic contamination in a marine bivalve by combining multiple approaches that provide information on individual and population health. We sampled variegated scallops (Mimachlamys varia at sites characterized by different contaminants and contamination levels to study the short and long-term (intergenerational responses of this species to physiological stress. We used biomarkers (SOD, MDA, GST, laccase, citrate synthase and phosphatases as indicators of oxidative stress, immune system alteration, mitochondrial respiration and general metabolism, and measured population genetic diversity at each site. In parallel, concentration of 14 trace metals and 45 organic contaminants (PAHs, PCBs, pesticides in tissues were measured. Scallops were collected outside and during their reproductive season to investigate temporal variability in contaminant and biomarker levels. Our analyses revealed that the levels of two biomarkers (Laccase-type phenoloxidase and malondialdehyde were significantly correlated with Cd concentration. Additionally, we observed significant seasonal differences for four of the five biomarkers, which is likely due to the scallop reproductive status at time of sampling. As a source of concern, a location that was identified as a reference site on the basis of inorganic contaminant levels presented the same level of some persistent organic pollutants (DDT and its metabolites than more impacted sites. Finally, potential long-term effects of heavy metal contamination were observed for variegated scallops as genetic diversity was depressed in the most polluted sites.

Short-Term and Long-Term Biological Effects of Chronic Chemical Contamination on Natural Populations of a Marine Bivalve.

Science.gov (United States)

Breitwieser, Marine; Viricel, Amélia; Graber, Marianne; Murillo, Laurence; Becquet, Vanessa; Churlaud, Carine; Fruitier-Arnaudin, Ingrid; Huet, Valérie; Lacroix, Camille; Pante, Eric; Le Floch, Stéphane; Thomas-Guyon, Hélène

2016-01-01

Understanding the effects of chronic chemical contamination on natural populations of marine organisms is complex due to the combined effects of different types of pollutants and environmental parameters that can modulate the physiological responses to stress. Here, we present the effects of a chronic contamination in a marine bivalve by combining multiple approaches that provide information on individual and population health. We sampled variegated scallops (Mimachlamys varia) at sites characterized by different contaminants and contamination levels to study the short and long-term (intergenerational) responses of this species to physiological stress. We used biomarkers (SOD, MDA, GST, laccase, citrate synthase and phosphatases) as indicators of oxidative stress, immune system alteration, mitochondrial respiration and general metabolism, and measured population genetic diversity at each site. In parallel, concentration of 14 trace metals and 45 organic contaminants (PAHs, PCBs, pesticides) in tissues were measured. Scallops were collected outside and during their reproductive season to investigate temporal variability in contaminant and biomarker levels. Our analyses revealed that the levels of two biomarkers (Laccase-type phenoloxidase and malondialdehyde) were significantly correlated with Cd concentration. Additionally, we observed significant seasonal differences for four of the five biomarkers, which is likely due to the scallop reproductive status at time of sampling. As a source of concern, a location that was identified as a reference site on the basis of inorganic contaminant levels presented the same level of some persistent organic pollutants (DDT and its metabolites) than more impacted sites. Finally, potential long-term effects of heavy metal contamination were observed for variegated scallops as genetic diversity was depressed in the most polluted sites.

Central Safety Department. Annual report 1986

International Nuclear Information System (INIS)

Kiefer, H.; Koenig, L.A.

1987-03-01

The Safety Officer and the Security Officer are responsible for radiation protection and technical safety, both conventional and nuclear, for the physical protection as well as the safeguards of nuclear materials and radioactive substances within the Kernforschungszentrum Karlsruhe GmbH (KfK). To fulfill these functions they rely on the assistance of the Central Safety Department. The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The r+d work concentrates on the following aspects: physical and chemical behavior of biologically particularly active radionuclides, behavior of HT in the air/plant/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. The report gives details of the different duties, indicates the results of 1986 routine tasks and reports about results of investigations and developments of the working groups of the Department. (orig.) [de

History of Korean Chemical Society for 50 years

International Nuclear Information System (INIS)

1999-05-01

This book records the history of Korean Chemical Society from 1946 to 1996, which is divided into five chapters. The first chapter breaks the history into periodic characteristics. The second chapter introduces committee and executive office like chemical education committee and international cooperation committee. The third chapter lists the department of KCS such as departments of organic chemistry, inorganic chemistry, industrial chemistry, biochemistry and physical chemistry. The fourth chapter reports each branch of KCS. The last chapter has a chronological table and articles of association and organizations.

A Decade of Improvements for Solid Oxide Electrolysis Cells. Long-Term Degradation Rate from 40%/Kh to 0.4 % Kh

DEFF Research Database (Denmark)

Hauch, Anne; Brodersen, Karen; Chen, Ming

2016-01-01

Solid oxide electrolysis cells (SOEC) have the potential for efficient large-scale conversion from electrical energy to chemical energy stored in fuels, such as hydrogen or synthetic hydrocarbon fuels by use of well-known catalysis processes. Key issues for the break-through of this technology...... are to provide inexpensive, reliable, high performing and long-term stable SOEC for stack and system applications. At DTU Energy (formerly Department of Fuel Cells and Solid State Chemistry, Risø National Laboratory), research within SOEC for more than a decade has led to long-term degradation rates on cell...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Author Affiliations. PRANJAL SAIKIA1 ABU T MIAH1 PARTHA P DAS2. Department of Applied Sciences (Chemical Science Division), GUIST, Gauhati University, Guwahati 781 014, Assam, India; Department of Physics, NIT Karnataka, Surathkal, Mangalore 575 025, Karnataka, India ...

Department of Chemistry Progress Report (January 1989 - December 1991)

International Nuclear Information System (INIS)

1992-03-01

The research activities in Department of Chemistry during the last 3 years from 1989 to 1991 were compiled. The researches and works of Department of Chemistry are mainly those concerned with important basic matters and items which are committed to further development of nuclear fuels and materials, to establishment of the nuclear fuel cycle, and to new development of advanced nuclear researches such as laser, ion-beam and photo-chemistry. Intensive efforts were also made on chemical analysis service of various fuels and nuclear materials. (author)

Chemical Carcinogenesis Research Information System (CCRIS)

Data.gov (United States)

U.S. Department of Health & Human Services — The CCRIS database contains chemical records with carcinogenicity, mutagenicity, tumor promotion, and tumor inhibition test results. CCRIS provides historical...

Idaho Chemical Processing Plant Process Efficiency improvements

International Nuclear Information System (INIS)

Griebenow, B.

1996-03-01

In response to decreasing funding levels available to support activities at the Idaho Chemical Processing Plant (ICPP) and a desire to be cost competitive, the Department of Energy Idaho Operations Office (DOE-ID) and Lockheed Idaho Technologies Company have increased their emphasis on cost-saving measures. The ICPP Effectiveness Improvement Initiative involves many activities to improve cost effectiveness and competitiveness. This report documents the methodology and results of one of those cost cutting measures, the Process Efficiency Improvement Activity. The Process Efficiency Improvement Activity performed a systematic review of major work processes at the ICPP to increase productivity and to identify nonvalue-added requirements. A two-phase approach was selected for the activity to allow for near-term implementation of relatively easy process modifications in the first phase while obtaining long-term continuous improvement in the second phase and beyond. Phase I of the initiative included a concentrated review of processes that had a high potential for cost savings with the intent of realizing savings in Fiscal Year 1996 (FY-96.) Phase II consists of implementing long-term strategies too complex for Phase I implementation and evaluation of processes not targeted for Phase I review. The Phase II effort is targeted for realizing cost savings in FY-97 and beyond

Annual report 1988 of the Central Safety Department

International Nuclear Information System (INIS)

Koelzer, W.; Urban, M.

1989-04-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The r+d work concentrates on the following aspects: physical and chemical behavior of biologically particularly active radionuclides, behavior of tritium in the air/plant/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1988 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of the Table of Contents and of Chapter 1 describing the duties and organization of the Central Safety Department. (orig./HP) [de

Annual report 1991 of the Central Safety Department

International Nuclear Information System (INIS)

Koelzer, W.

1992-04-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The research and development work concentrates on the following aspects: Physical and chemical behavior of trace elements in the environment, behavior of tritium in the air/plant/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1989 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of the Table of Contents and of Chapter 1 describing the duties and organization of the Central Safety Department. (orig.) [de

Annual report 1990 of the Central Safety Department

International Nuclear Information System (INIS)

Koelzer, W.; Urban, M.

1991-04-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The research and development work concentrates on the following aspects: Physical and chemical behavior of trace elements in the environment, behavior of tritium in the air/plant/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1989 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of the Table of Contents and of Chapter 1 describing the duties and organization of the Central Safety Department. (orig.) [de

Chemical Sciences Division: Annual report 1992

International Nuclear Information System (INIS)

1993-10-01

The Chemical Sciences Division (CSD) is one of twelve research Divisions of the Lawrence Berkeley Laboratory, a Department of Energy National Laboratory. The CSD is composed of individual groups and research programs that are organized into five scientific areas: Chemical Physics, Inorganic/Organometallic Chemistry, Actinide Chemistry, Atomic Physics, and Physical Chemistry. This report describes progress by the CSD for 1992. Also included are remarks by the Division Director, a description of work for others (United States Office of Naval Research), and appendices of the Division personnel and an index of investigators. Research reports are grouped as Fundamental Interactions (Photochemical and Radiation Sciences, Chemical Physics, Atomic Physics) or Processes and Techniques (Chemical Energy, Heavy-Element Chemistry, and Chemical Engineering Sciences)

INSPACE CHEMICAL PROPULSION SYSTEMS AT NASA's MARSHALL SPACE FLIGHT CENTER: HERITAGE AND CAPABILITIES

Science.gov (United States)

McRight, P. S.; Sheehy, J. A.; Blevins, J. A.

2005-01-01

NASA s Marshall Space Flight Center (MSFC) is well known for its contributions to large ascent propulsion systems such as the Saturn V rocket and the Space Shuttle external tank, solid rocket boosters, and main engines. This paper highlights a lesser known but very rich side of MSFC-its heritage in the development of in-space chemical propulsion systems and its current capabilities for spacecraft propulsion system development and chemical propulsion research. The historical narrative describes the flight development activities associated with upper stage main propulsion systems such as the Saturn S-IVB as well as orbital maneuvering and reaction control systems such as the S-IVB auxiliary propulsion system, the Skylab thruster attitude control system, and many more recent activities such as Chandra, the Demonstration of Automated Rendezvous Technology (DART), X-37, the X-38 de-orbit propulsion system, the Interim Control Module, the US Propulsion Module, and multiple technology development activities. This paper also highlights MSFC s advanced chemical propulsion research capabilities, including an overview of the center s Propulsion Systems Department and ongoing activities. The authors highlight near-term and long-term technology challenges to which MSFC research and system development competencies are relevant. This paper concludes by assessing the value of the full range of aforementioned activities, strengths, and capabilities in light of NASA s exploration missions.

Long-Term Effects of Chemical Warfare on Post-traumatic Stress Disorder, Depression, and Chronic Medical Conditions in Veterans.

Science.gov (United States)

Safi-Aghdam, Hamideh; Shafie, Mehrzad; Khoshdel, Alireza; Moazen-Zadeh, Ehsan; Avakh, Farhad; Rahmani, Arash

2018-04-24

We investigated the association between exposure to chemical warfare and chronic mental/physical conditions. This was a secondary analysis of data from a case-control study on Iranian male veterans. Participants with neuropsychiatric disorders other than depressive/anxiety disorders, anatomical defects, or malignancies were excluded. Compared to non-exposed veterans, exposed veterans demonstrated significantly higher odds of PTSD [OR (95% CI) = 5.23 (1.98-13.85)], hypertension [OR (95% CI) = 5.57 (1.68-18.48)], coronary heart disease [OR (95% CI) = 6.8 (1.62-28.49)], and diabetes [OR (95% CI) = 3.88 (1.35-11.16)], and marginally higher odds of moderate to severe depressive symptoms [OR (95% CI) = 2.21 (0.93-5.28)]. This study provides preliminary evidence on association of exposure to chemical warfare with long-term mental disorders as well as chronic medical conditions.

Probabilistic consequence model of accidenal or intentional chemical releases.

Energy Technology Data Exchange (ETDEWEB)

Chang, Y.-S.; Samsa, M. E.; Folga, S. M.; Hartmann, H. M.

2008-06-02

In this work, general methodologies for evaluating the impacts of large-scale toxic chemical releases are proposed. The potential numbers of injuries and fatalities, the numbers of hospital beds, and the geographical areas rendered unusable during and some time after the occurrence and passage of a toxic plume are estimated on a probabilistic basis. To arrive at these estimates, historical accidental release data, maximum stored volumes, and meteorological data were used as inputs into the SLAB accidental chemical release model. Toxic gas footprints from the model were overlaid onto detailed population and hospital distribution data for a given region to estimate potential impacts. Output results are in the form of a generic statistical distribution of injuries and fatalities associated with specific toxic chemicals and regions of the United States. In addition, indoor hazards were estimated, so the model can provide contingency plans for either shelter-in-place or evacuation when an accident occurs. The stochastic distributions of injuries and fatalities are being used in a U.S. Department of Homeland Security-sponsored decision support system as source terms for a Monte Carlo simulation that evaluates potential measures for mitigating terrorist threats. This information can also be used to support the formulation of evacuation plans and to estimate damage and cleanup costs.

Chemical Product Design

DEFF Research Database (Denmark)

Gani, Rafiqul

2004-01-01

This paper highlights for a class of chemical products, the design process, their design with respect to the important issues, the need for appropriate tools and finally, lists some of the challenges and opportunities for the process systems engineering (PSE)/computer-aided process engineering...... (CAPE) community. The chemical products considered belong to the following types: chemical/biochemical/agrochemical products, coatings and solvents, food (nutraceuticals), HIM (household, industrial and institutional), personal care, pharmaceuticals and drugs. The challenges and opportunities...... are highlighted in terms of the needs for multi-level modeling with emphasis on property models that are suitable for computer-aided applications, flexible solution strategies that are able to solve a large range of chemical product design problems and finally, a systems chemical product design framework...

Board on chemical sciences and technology

International Nuclear Information System (INIS)

1991-01-01

The Board on Chemical Sciences and Technology organizes and provides direction for standing and ad hoc committees charged with addressing specific issues relevant to the continued health of the chemical sciences and technology community. Studies currently under the oversight of the BCST include a major survey of chemical engineering, an examination of the problems of biohazards in the laboratory, and an analysis of the roots and magnitude of the problem of obsolescent facilities for research and teaching in departments in the chemical sciences and engineering. The Board continues to respond to specific agency requests for program assessments and advice. BCST members are designated to serve as liaison with major federal agencies or departments that support research in order to help identify ways for the board to assist the these organizations. The BCST also maintains close contact with professional societies and nongovernmental organizations that share the Board's concern for the health of chemical sciences and technology. Individual Board members are assigned responsibility for liaison with the American Chemical Society, the American Institute of Chemical Engineers, the American Society of Biological Chemists, the Council for Chemical Research, the Chemistry and Biochemistry Sections of the National Academy of Sciences (NAS), and the National Academy of Engineering (NAE). In the past few years, the Board has served as a focus and a forum for a variety of issues that relate specifically to the health of chemistry. A sampling of these concerns include: industry-university cooperation; basic research funding in DOD, DOE, NIH, and NSF; basic research in the chemistry of life processes; basic research in biochemical engineering; basic research in the science and technology of new materials; and undergraduate education in chemistry and chemical engineering

32 CFR 701.27 - FOIA fee terms location.

Science.gov (United States)

2010-07-01

... 32 National Defense 5 2010-07-01 2010-07-01 false FOIA fee terms location. 701.27 Section 701.27... AND OFFICIAL RECORDS AVAILABILITY OF DEPARTMENT OF THE NAVY RECORDS AND PUBLICATION OF DEPARTMENT OF THE NAVY DOCUMENTS AFFECTING THE PUBLIC FOIA Definitions and Terms § 701.27 FOIA fee terms location...

Strategic Planning and the Long-term R&D Plan

International Nuclear Information System (INIS)

Cooley, J.

2015-01-01

The Department of Safeguards of the International Atomic Energy Agency implements a structured strategic planning process to ensure that safeguards will continue to be both effective and efficient in the future. This process provides the Department with a comprehensive and coherent planning framework for the short (2 years), medium (6 years) and long (12 years) term. The Department's suite of planning documents includes a long-term strategic plan and an associated long-term research and development plan as well as a biennial development and implementation support programme. The Department's Long-Term Strategic Plan 2012-2023 addresses the conceptual framework for safeguards implementation, legal authority, technical capabilities (expertise, equipment and infrastructure) and the human and financial resources necessary for Agency verification activities. As research and development (R&D) are essential to meet the safeguards needs of the future, the Department-s Long-Term R&D Plan 2012-2023 is designed to support the Long-Term Strategic Plan 2012-2023 by setting out the capabilities that the Department needs to achieve its strategic objectives, and key milestones towards achieving those capabilities for which Member State R&D support is needed. The Long-Term R&D Plan 2012-2023 addresses the Department's R&D requirements in areas such as safeguards concepts and approaches; detection of undeclared nuclear material and activities; safeguards equipment and communication; information technology, collection, analysis and security; analytical services; new mandates; and training. Long-term capabilities discussed in the presentation include deployed systems (e.g., equipment at facilities); analytical (e.g., sample analysis), operational (e.g., staff expertise and skills) and readiness (e.g., safeguarding new types of facilities) capabilities. To address near-term development objectives and support the implementation of its verification activities as well as to

Bio-based chemicals - green, but also sustainable?

DEFF Research Database (Denmark)

Ögmundarson, Ólafur; Herrgard, Markus; Förster, Jochen

For almost two decades, the chemical industry has put great effort into developing bio-chemicals,among others to fight global warming caused by greenhouse gas emissions, one of the biggest threats that are faced by our society today. To facilitate a growing and versatile bio-based chemical...... production, the US Department of Energy proposed in 2004 a list of 12 building block chemicals which can either be converged through biological or chemical conversions. Moving toward more bio-based chemicals, the chemical industry does not only claim to reduce climate change impacts, but also...... that they are increasing overall sustainability in chemical production. Whether such claims are justifiable is unclear. When sustainability of bio-based polymer production is assessed, various environmental trade-offs occur that need to be considered. It is not enough to claim that a bio-chemical is sustainable...

31 CFR 598.309 - Narcotic drug; controlled substance; listed chemical.

Science.gov (United States)

2010-07-01

...; listed chemical. 598.309 Section 598.309 Money and Finance: Treasury Regulations Relating to Money and... SANCTIONS REGULATIONS General Definitions § 598.309 Narcotic drug; controlled substance; listed chemical. The terms narcotic drug, controlled substance, and listed chemical have the meanings given those terms...

6 CFR 27.200 - Information regarding security risk for a chemical facility.

Science.gov (United States)

2010-01-01

... chemical facility. 27.200 Section 27.200 Domestic Security DEPARTMENT OF HOMELAND SECURITY, OFFICE OF THE SECRETARY CHEMICAL FACILITY ANTI-TERRORISM STANDARDS Chemical Facility Security Program § 27.200 Information regarding security risk for a chemical facility. (a) Information to determine security risk. In order to...

Supplemental analysis of accident sequences and source terms for waste treatment and storage operations and related facilities for the US Department of Energy waste management programmatic environmental impact statement

International Nuclear Information System (INIS)

Folga, S.; Mueller, C.; Nabelssi, B.; Kohout, E.; Mishima, J.

1996-12-01

This report presents supplemental information for the document Analysis of Accident Sequences and Source Terms at Waste Treatment, Storage, and Disposal Facilities for Waste Generated by US Department of Energy Waste Management Operations. Additional technical support information is supplied concerning treatment of transuranic waste by incineration and considering the Alternative Organic Treatment option for low-level mixed waste. The latest respirable airborne release fraction values published by the US Department of Energy for use in accident analysis have been used and are included as Appendix D, where respirable airborne release fraction is defined as the fraction of material exposed to accident stresses that could become airborne as a result of the accident. A set of dominant waste treatment processes and accident scenarios was selected for a screening-process analysis. A subset of results (release source terms) from this analysis is presented

Short-term Effect of Fine Particulate Matter on Children?s Hospital Admissions and Emergency Department Visits for Asthma: A Systematic Review and Meta-analysis

OpenAIRE

Lim, Hyungryul; Kwon, Ho-Jang; Lim, Ji-Ae; Choi, Jong Hyuk; Ha, Mina; Hwang, Seung-Sik; Choi, Won-Jun

2016-01-01

Objectives: No children-specified review and meta-analysis paper about the short-term effect of fine particulate matter (PM2.5) on hospital admissions and emergency department visits for asthma has been published. We calculated more precise pooled effect estimates on this topic and evaluated the variation in effect size according to the differences in study characteristics not considered in previous studies. Methods: Two authors each independently searched PubMed and EMBASE for relevant studi...

NIF: Impacts of chemical accidents and comparison of chemical/radiological accident approaches

International Nuclear Information System (INIS)

Lazaro, M.A.; Policastro, A.J.; Rhodes, M.

1996-01-01

The US Department of Energy (DOE) proposes to construct and operate the National Ignition Facility (NIF). The goals of the NIF are to (1) achieve fusion ignition in the laboratory for the first time by using inertial confinement fusion (ICF) technology based on an advanced-design neodymium glass solid-state laser, and (2) conduct high-energy-density experiments in support of national security and civilian applications. The primary focus of this paper is worker-public health and safety issues associated with postulated chemical accidents during the operation of NIF. The key findings from the accident analysis will be presented. Although NIF chemical accidents will be emphasized, the important differences between chemical and radiological accident analysis approaches and the metrics for reporting results will be highlighted. These differences are common EIS facility and transportation accident assessments

Integrative Chemical-Biological Read-Across Approach for Chemical Hazard Classification

Science.gov (United States)

Low, Yen; Sedykh, Alexander; Fourches, Denis; Golbraikh, Alexander; Whelan, Maurice; Rusyn, Ivan; Tropsha, Alexander

2013-01-01

Traditional read-across approaches typically rely on the chemical similarity principle to predict chemical toxicity; however, the accuracy of such predictions is often inadequate due to the underlying complex mechanisms of toxicity. Here we report on the development of a hazard classification and visualization method that draws upon both chemical structural similarity and comparisons of biological responses to chemicals measured in multiple short-term assays (”biological” similarity). The Chemical-Biological Read-Across (CBRA) approach infers each compound's toxicity from those of both chemical and biological analogs whose similarities are determined by the Tanimoto coefficient. Classification accuracy of CBRA was compared to that of classical RA and other methods using chemical descriptors alone, or in combination with biological data. Different types of adverse effects (hepatotoxicity, hepatocarcinogenicity, mutagenicity, and acute lethality) were classified using several biological data types (gene expression profiling and cytotoxicity screening). CBRA-based hazard classification exhibited consistently high external classification accuracy and applicability to diverse chemicals. Transparency of the CBRA approach is aided by the use of radial plots that show the relative contribution of analogous chemical and biological neighbors. Identification of both chemical and biological features that give rise to the high accuracy of CBRA-based toxicity prediction facilitates mechanistic interpretation of the models. PMID:23848138

The Short-Term Effect of Chest Physiotherapy on Spirometric Indices in Chemical Warfare Victims Exposed to Mustard Gas

Directory of Open Access Journals (Sweden)

A Abedi

2008-12-01

Full Text Available ABCTRACT Introduction & Objective: Chronic respiratory diseases are the most prevalent late sequels of sulfur mustard gas injury among Iranian chemical warfare victims. Chest physiotherapy is one of the useful methods in care, cure and infection prevention of these patients. The aim of this study was to determine the short-term effect of chest physiotherapy on spirometric indices in chemical warfare victims exposed to sulfur mustard gas. Materials & Methods: In this study, 27 of the chemical warfare victims with respiratory diseases were selected. Chest physiotherapy including postural drainage percussion and vibration were used in four positions for all patients. Pulmonary function test (PFT was obtained before (baseline, immediately and 20 minute after the chest physiotherapy. The SPSS software was used for the data analysis of the collected data. Results: Results of this study showed the significant effect (p<0.01 of chest physiotherapy upon forced expiratory volume in first second (FEV1 (baseline mean, 44.19 immediately after intervention mean 47.3 and 20 minute after intervention mean 48.3 and forced vital capacity (FVC (baseline mean, 69.37 immediately after intervention mean, 73.67 20 minute after intervention 75.74. Chest physiotherapy had significant effect (p<0.01 in asthmatic bronchitis group and also had significant effect (p<0.05 in both severe and moderate groups. Conclusion: Chest physiotherapy was able to improve pulmonary function test indices in chemical warfare victims suffering from respiratory problems. The effect on asthmatic bronchitis group, as well as both severe and moderate groups, was significant.

Chemical Applications of Second Harmonic Rayleigh Scattering ...

Indian Academy of Sciences (India)

Chemical Applications of Second Harmonic Rayleigh Scattering Puspendu Kumar Das Department of Inorganic and Physical Chemistry Indian Institute of Science Bangalore 560012, India pkdas@ipc.iisc.ernet.in.

PHYSICO-CHEMICAL CHARACTERISTICS OF MESUA FERREA ...

African Journals Online (AJOL)

a

2Department of Chemistry, Rajshahi University of Engineering and ... Studies on the physico-chemical characteristics of seed oils of Mesua ferrea collected ..... Sarkar, Subodh Kumar M.Phil Thesis, Rajshahi University, Bangladesh; 2001; p 91 ...

32 CFR 701.41 - FOIA fee terms.

Science.gov (United States)

2010-07-01

... 32 National Defense 5 2010-07-01 2010-07-01 false FOIA fee terms. 701.41 Section 701.41 National... OFFICIAL RECORDS AVAILABILITY OF DEPARTMENT OF THE NAVY RECORDS AND PUBLICATION OF DEPARTMENT OF THE NAVY DOCUMENTS AFFECTING THE PUBLIC FOIA Fees § 701.41 FOIA fee terms. (a) Direct costs means those expenditures...

Research activities in the Radioactive Waste Management Department of IFIN-HH, Bucharest

International Nuclear Information System (INIS)

Dragolici, F.; Lungu, L.; Nicu, M.; Rotarescu, Gh. C. Turcanu

2001-01-01

The research activities developed in the frame of Radioactive Waste Management Department are focused on processing low activity liquid wastes obtained from chemical precipitation and their conditioning. In cementation procedure, the chemical composition and the mixing proportion of the sludge and concentrates affects both the cement components hydrolysis and the reactions of the metastable hydrating components, as well as, the mechanical and chemical withstand of the solidified cement matrix. Generally, the study of the precipitation products as well as of their behavior during cementation and long term disposal is extremely difficult due to the system complexity (composition and structure of the phases) and to the lack of non-destructive analytical methods. For a detailed characterization of the precipitates and cemented matrices a study was carried out concerning the X-ray diffraction method application (as a complementary method to the Moessbauer spectroscopy). The following systems were considered: - Fe precipitates obtained from low-level radioactive waste processing; - structure modification determined by the foreign cations in Fe oxo-hydroxides; precipitation processes with alternate or simultaneous presence of bi- and tri-valent Fe ions; - the influence of precipitation procedure upon decontamination factors; - dried and hydrated cement systems; - cementing the sludge chemical components; - the influence of organic complexation agents upon the structure and performances of cemented matrices; - the influence of mineral additives upon the concrete; - cemented waste stability in real and simulated disposal conditions. The Moessbauer investigation on ferrous species obtained by precipitation system showed that the Fe compound obtained by the rapid neutralization (as the case is of aqueous radioactive waste processing) have a structure slightly different as compared with the Fe oxo-hydroxides prepared by slow addition of reactants. Also, studies were conducted

Chemical contaminants on DOE lands and selection of contaminant mixtures for subsurface science research

Energy Technology Data Exchange (ETDEWEB)

Riley, R.G.; Zachara, J.M. [Pacific Northwest Lab., Richland, WA (United States)

1992-04-01

This report identifies individual contaminants and contaminant mixtures that have been measured in the ground at 91 waste sites at 18 US Department of Energy (DOE) facilities within the weapons complex. The inventory of chemicals and mixtures was used to identify generic chemical mixtures to be used by DOE`s Subsurface Science Program in basic research on the subsurface geochemical and microbiological behavior of mixed contaminants (DOE 1990a and b). The generic mixtures contain specific radionuclides, metals, organic ligands, organic solvents, fuel hydrocarbons, and polychlorinated biphenyls (PCBs) in various binary and ternary combinations. The mixtures are representative of in-ground contaminant associations at DOE facilities that are likely to exhibit complex geochemical behavior as a result of intercontaminant reactions and/or microbiologic activity stimulated by organic substances. Use of the generic mixtures will focus research on important mixed contaminants that are likely to be long-term problems at DOE sites and that will require cleanup or remediation. The report provides information on the frequency of associations among different chemicals and compound classes at DOE waste sites that require remediation.

Local Government Implementation of Long-Term Stewardship at Two DOE Facilities

Energy Technology Data Exchange (ETDEWEB)

John Pendergrass; Roman Czebiniak; Kelly Mott; Seth Kirshenberg; Audrey Eidelman; Zachary Lamb; Erica Pencak; Wendy Sandoz

2003-08-13

The Department of Energy (DOE) is responsible for cleaning up the radioactive and chemical contamination that resulted from the production of nuclear weapons. At more than one hundred sites throughout the country DOE will leave some contamination in place after the cleanup is complete. In order to protect human health and the environment from the remaining contamination DOE, U.S. Environmental Protection Agency (EPA), state environmental regulatory agencies, local governments, citizens and other entities will need to undertake long-term stewardship of such sites. Long-term stewardship includes a wide range of actions needed to protect human health in the environment for as long as the risk from the contamination remains above acceptable levels, such as barriers, caps, and other engineering controls and land use controls, signs, notices, records, and other institutional controls. In this report the Environmental Law Institute (ELI) and the Energy Communities Alliance (ECA) examine how local governments, state environmental agencies, and real property professionals implement long-term stewardship at two DOE facilities, Losa Alamos National Laboratory and Oak Ridge Reservation.

Long-term pavement performance compliance with Department of Transportation information dissemination quality guidelines

Science.gov (United States)

2008-11-01

This document provides information on the compliance of the LTPP program with the guidelines the Department of Transportation (DOT) issued Information Dissemination Quality Guidelines (IDQG). These guidelines were developed in response to requirement...

Chemical leasing in the context of sustainable chemistry.

Science.gov (United States)

Moser, Frank; Karavezyris, Vassilios; Blum, Christopher

2015-05-01

Chemical leasing is a new and innovative approach of selling chemicals. It aims at reducing the risks emanating from hazardous substances and ensuring long-term economic success within a global system of producing and using chemicals. This paper explores how, through chemical leasing, the consumption of chemicals, energy, resources and the generation of related wastes can be reduced. It also analyses the substitution of hazardous chemicals as a tool to protect environmental, health and safety and hence ensure compliance with sustainability criteria. For this, we are proposing an evaluation methodology that seeks to provide an answer to the following research questions: (1) Does the application of chemical leasing promote sustainability in comparison to an existing chemicals production and management system? 2. If various chemical leasing project types are envisaged, which is the most promising in terms of sustainability? The proposed methodology includes a number of basic goals and sub-goals to assess the sustainability for eight different chemical leasing case studies that have been implemented both at the local and the national levels. The assessment is limited to the relative assessment of specific case studies and allows the comparisons of different projects in terms of their relative contribution to sustainable chemistry. The findings of our assessment demonstrate that chemical leasing can be regarded as promoting sustainable chemistry in five case studies with certainty. However, on the grounds of our assessment, we cannot conclude with certainty that chemical leasing has equivalent contribution to sustainable chemistry in respect of three further case studies.

Nuclear Targeting Terms for Engineers and Scientists

Energy Technology Data Exchange (ETDEWEB)

St Ledger, John W. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

2017-02-01

The Department of Defense has a methodology for targeting nuclear weapons, and a jargon that is used to communicate between the analysts, planners, aircrews, and missile crews. The typical engineer or scientist in the Department of Energy may not have been exposed to the nuclear weapons targeting terms and methods. This report provides an introduction to the terms and methodologies used for nuclear targeting. Its purpose is to prepare engineers and scientists to participate in wargames, exercises, and discussions with the Department of Defense. Terms such as Circular Error Probable, probability of hit and damage, damage expectancy, and the physical vulnerability system are discussed. Methods for compounding damage from multiple weapons applied to one target are presented.

Department of Material Studies - Overview

International Nuclear Information System (INIS)

Werner, Z.

2009-01-01

Full text: The technology of modifying surfaces of technological materials by means of continuous and pulsed energy and particle beams has been intensely studied for more than 20 years. In some fields, it is currently utilized on a wide scale in industry. Continuous or pulsed ion and plasma beams play a significant role among various approaches used in this area. The research carried by Department P-IX is centered on applications of our two ion implantation facilities (ion implanters) of different kinds and unique sources of high-intensity intense plasma pulses, operated by the Department of Plasma Physics. The Department cooperates closely with Forschungszentrum Rossendorf (FZR, Dresden, Germany) in the field of analytical ion beam techniques and the use of unique ion implantation facilities. The main objectives of the Department are: · the search for new ways of modifying the surface properties of solid materials by means of continuous or pulsed ion and plasma beams and · the implementation of ion implantation techniques in national industries as a method of improving the lifetime of machine parts and tools utilized in industry. In 2008, research was focused on: · ion implantation/plasma treatment of ceramics aimed at improving their wettability in ceramic-metal joints, · ion beam synthesis and plasma pulse activation of superconducting MgB 2 phases, · cobalt and zirconium inclusions in conducting layers produced in oxide insulators (Al 2 O 3 ) by ion implantation and thermal annealing. Research was conducted in cooperation with Department P-V of IPJ, Institute of Nuclear Chemistry and Technology (Warsaw), Warsaw University of Technology, Institute of Technology of Materials for Electronics (Warsaw), Institute of Molecular Physics, Polish Academy of Sciences (Poznan), Institute of Chemical Physics PAS and Forschungszentrum Rossendorf FZR (Dresden, Germany), as well as with some industrial companies. (author)

Chemical-induced Vitiligo

Science.gov (United States)

Harris, John E.

2016-01-01

Synopsis Chemical-induced depigmentation of the skin has been recognized for over 75 years, first as an occupational hazard but then extending to those using household commercial products as common as hair dyes. Since their discovery, these chemicals have been used therapeutically in patients with severe vitiligo to depigment their remaining skin and improve their appearance. The importance of recognizing this phenomenon was highlighted during an outbreak of vitiligo in Japan during the summer of 2013, when over 16,000 users of a new skin lightening cosmetic cream developed skin depigmentation at the site of contact with the cream and many in remote areas as well. Depigmenting chemicals appear to be analogs of the amino acid tyrosine that disrupt melanogenesis and result in autoimmunity and melanocyte destruction. Because chemical-induced depigmentation is clinically and histologically indistinguishable from non-chemically induced vitiligo, and because these chemicals appear to induce melanocyte autoimmunity, this phenomenon should be known as “chemical-induced vitiligo”, rather than less accurate terms that have been previously used. PMID:28317525

Chemical safety management in WIP, Kalpakkam - an overview

International Nuclear Information System (INIS)

Das, Biplab; Ravi, K.V.

2016-01-01

Nuclear Waste Management necessitates several chemicals for its process. Many of them are substantially hazardous to health, if exposed. Our department takes utmost care in transport, storing and handling of chemicals. We must put maximum efforts to prevent spillage or leak of chemicals and prevent any exposure to employees, but once it occurs, safety of the employees depend on our quick and appropriate response. Therefore, periodical review of the chemical risk needs to be done to ensure that the steps taken by the plant are in place. Purpose of this paper is to assess the overall chemical management system of this plant to ensure the prevention of any untoward incident arising from chemicals. (author)

A scalable machine-learning approach to recognize chemical names within large text databases

Directory of Open Access Journals (Sweden)

Wren Jonathan D

2006-09-01

Full Text Available Abstract Motivation The use or study of chemical compounds permeates almost every scientific field and in each of them, the amount of textual information is growing rapidly. There is a need to accurately identify chemical names within text for a number of informatics efforts such as database curation, report summarization, tagging of named entities and keywords, or the development/curation of reference databases. Results A first-order Markov Model (MM was evaluated for its ability to distinguish chemical names from words, yielding ~93% recall in recognizing chemical terms and ~99% precision in rejecting non-chemical terms on smaller test sets. However, because total false-positive events increase with the number of words analyzed, the scalability of name recognition was measured by processing 13.1 million MEDLINE records. The method yielded precision ranges from 54.7% to 100%, depending upon the cutoff score used, averaging 82.7% for approximately 1.05 million putative chemical terms extracted. Extracted chemical terms were analyzed to estimate the number of spelling variants per term, which correlated with the total number of times the chemical name appeared in MEDLINE. This variability in term construction was found to affect both information retrieval and term mapping when using PubMed and Ovid.

Approaches to accident analysis in recent US Department of Energy environmental impact statements

International Nuclear Information System (INIS)

Mueller, C.; Folga, S.; Nabelssi, B.

1996-01-01

A review of accident analyses in recent US Department of Energy (DOE) Environmental Impact Statements (EISs) was conducted to evaluate the consistency among approaches and to compare these approaches with existing DOE guidance. The review considered several components of an accident analysis: the overall scope, which in turn should reflect the scope of the EIS; the spectrum of accidents considered; the methods and assumptions used to determine frequencies or frequency ranges for the accident sequences; and the assumption and technical bases for developing radiological and chemical atmospheric source terms and for calculating the consequences of airborne releases. The review also considered the range of results generated with respect to impacts on various worker and general populations. In this paper, the findings of these reviews are presented and methods recommended for improving consistency among EISs and bringing them more into line with existing DOE guidance

HMI Radiation Chemistry Department. Scientific report 1985

International Nuclear Information System (INIS)

1985-01-01

Results of the R and D activities of the Radiation Chemistry Department, Hahn-Meitner-Institut, are reported, primarily dealing with the following subjects: a) Interface processes and energy conversion; b) Pulsed radiolysis and kinematics; c) Insulating materials and polymers. Activities belonging to group (a) above include the development of photosensitive materials for energy conversion, photovoltaic solar cells, light-induced hydrogen liberation, and inclusion reactions, model experiments studying photoactive interfaces, rapid kinematic measurements at interfaces after laser-induced excitation, surface preparation of amorphous silicon and its effects on electronic properties, photochemical reactions and catalysts. Work performed in group (b) above included studies into various chemical reactions involving radicals, and on interactions between atoms, ions, molecules and molecular clusters induced by low-energy collisions. Group (c) above all performed studies into the physical and chemical elementary processes induced by high-energy radiation, light and UV light, especially in electronegative gases. Further activities in this group included photochemical and radiation chemical investigations on polymers. The report lists publications and lectures prepared by H.M.I. members and guest scientists in the year 1985. (RB) [de

1978 annual report of the safety department

International Nuclear Information System (INIS)

Kiefer, H.; Koelzer, W.

1979-04-01

The Safety Officer and the Security Officer, respectively, are responsible for radiation protection and technical safety, both conventional and nuclear, for the physical protection as well as the security of nuclear materials and radioactive substances within the Kernforschungszentrum Karlsruhe GmbH. (KfK). To fulfill these functions they rely on the assitance of the Safety Department. The duties of this Department cover tasks relative to radiation protection, safety and security on behalf of the institutes and departments of KfK and environmental monitoring for the whole Karlsruhe Nuclear Research Center as well as research and development work, mainly performed under the Nuclear Safety Project and the Nuclear Safeguards Project. The centers of interest of r and d activities are: investigation of the atmospheric diffusion of nuclear pollutants on the micro- and meso-scales, evaluation of the radiological consequences of accidents in reactors under probabilistic aspects, studies of the physical and chemical behavior of radionuclides with particularly high biological effectiveness in the environment, implementation of nuclear fuel safequarding systems, improvements in radiation protection measurement technology. This report gives details of the different duties, indicates the results of 1978 routine tasks, and reports about new results of investigations and developments of the working groups of the Department. (orig.) [de

Annual Report 1979 of the Safety Department

International Nuclear Information System (INIS)

Kiefer, H.; Koelzer, W.; Koenig, L.A.

1980-04-01

The Safety Officer and the Security Officer, respectively, are responsible for radiation protection and technical safety, both conventional and nuclear, for the physical protection as well as the security of nuclear materials and radioactive substances within the Kernforschungszentrum Karlsruhe GmbH. (KfK). To fulfill these functions they rely on the assistance of the Safety Department. The duties of this Department cover tasks relative to radiation protection, safety and security on behalf of the institutes and departments of KfK and environmental monitoring for the whole Karlsruhe Nuclear Research Center as well as research and development work, mainly performed under the Nuclear Safety Project and the Nuclear Safeguards Project. The centers of interest of r and d activities are: investigation of the atmospheric diffusion of nuclear pollutants on the micro- and meso-scales, evaluation of the radiological consequences of accidents in reactors under probabilistic aspects, studies of the physical and chemical behavior of radionuclides with particularly high biological effectiveness in the environment, implemantation of nuclear fuel safeguarding systems, improvements in radiation protection measurement technology. This report gives details of the different duties, indicates the results of 1979 routine tasks, and reports about results of investigations and developments of the working groups of the Department. (orig.) [de

Nuclear Research Center Karlsruhe, Central Safety Department. Annual report 1992

International Nuclear Information System (INIS)

Koelzer, W.

1993-05-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The research and development work concentrates on the following aspects: Physical and chemical behavior of trace elements in the environment, biophysics of multicellular systems, behavior of tritium in the air/soil-plant system, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1992 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of Chapter 1 describing the duties and organization of the Central Safety Department. (orig.) [de

Department of Mining and Geotechnics – 50 th Anniversary

Directory of Open Access Journals (Sweden)

Ïurove Juraj

2002-12-01

Full Text Available The Mining faculty of the Technical High School in Košice (now BERG Faculty of the Technical University of Košice was found in 1952. In the first years this school consisted only of three Faculties, namely the Faculty of Mining, Faculty of Metallurgy and Faculty of Mechanical Engineering with few of Departments. Teaching and research activities at the Mining Faculty from begining has been based on the staff members of the Mining Department (now Department of Mining and Geotechnics. During the last 50 years Department of Mining has been growing in terms of the number of subject, laboratories, staff members, students etc., and finished their diploma in total 1101 mining engineers At the begin of this period Department was ment to meet the needs of the Slovak mineral industry relating to the education of engineers and research works in the following areas:,underground mining of mineral deposits, open pit mine, stability problems , rock mechanics, design and construction of mines, but now also in computing and information technologies. At present the Department offers courses in various fields of mining and geotechnics, which cover a very wide range of technical problems arising in mining industry and geotechnical praxis, including rescue, fire and safety course. Full-time study at the Department takes five years and leads to a Master´s degree of mining engineering. The study program comprises also an obligatory practical work. The students´practical training is usually divided into 2 terms each of 2-3 weeks duration. In the last semester the students are preparing their Master´s degree thesis.

31. Introduction with adjacent production of foundry and rolling department of electrolysis shop

International Nuclear Information System (INIS)

Ivanov, A.V.

1993-01-01

The introduction with adjacent production of foundry and rolling department of electrolysis shop was conducted. The foundry machine was described. The chemical properties of aluminium for ferrous alloy production were defined.

21 CFR 864.1850 - Dye and chemical solution stains.

Science.gov (United States)

2010-04-01

... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Dye and chemical solution stains. 864.1850 Section 864.1850 Food and Drugs FOOD AND DRUG ADMINISTRATION, DEPARTMENT OF HEALTH AND HUMAN SERVICES (CONTINUED) MEDICAL DEVICES HEMATOLOGY AND PATHOLOGY DEVICES Biological Stains § 864.1850 Dye and chemical...

Antarctic environmental specimen bank. A tool for chemical monitoring

Energy Technology Data Exchange (ETDEWEB)

Soggia, F.; Dalla Riva, S.; Abelmoschi, M.L.; Frache, R. [Genoa Univ., Genoa (Italy). Dipt. di Chimica e Chimica Industriale

2000-02-01

The work illustrates the project on Antarctic Environmental Specimen Bank (BCAA), which is an integral part of the Italian project on the micropollutants chemistry (sector on chemical contamination of the Italian Antarctic Research program, PNRA), begun in 1994 when the BCAA was installed in the department of chemistry and industrial chemistry (Genoa University, Italy). Its objective underlines an emphasis on environmental chemistry and the establishment of baselines similar to the approaches followed by the other environmental specimen banks, begun at the end of Sixties with the aim of long-term storage of representative environmental specimens in order to study the presence and the evolution of dangerous substances, but focus on the chemical characterization of samples. [Italian] Il lavoro illustra le finalita' del Progetto su una Banca Campioni Ambientali Antartici (BCAA), che e' parte integrante del progetto Chmica dei microinquinannti del Settore Contaminazione chimica del Programma Nazionale di ricerche in Antartide (ONRA), nata nel 1994 presso il dipartimento di chimicia e chimica industriale dell'universita' di Genova. A differenza di altri progetti internazionali che enfatizzano gli aspetti biologici, ecologici e medici, il progetto BCAA enfatizza la chimica ambientale.

Nuclear, biological and chemical contamination survivability of Army material

International Nuclear Information System (INIS)

Feeney, J.J.

1987-01-01

Army Regulation (AR) 70-71, Nuclear, Biological and Chemical (NBC) Contamination Survivability of Army Material, published during 1984, establishes Army policy and procedures for the development and acquisition of material to ensure its survivablility and sustainability on the NBC-contaminated battlefield. This regulation defines NBC contamination as a term that includes both the individual and collective effects of residual radiological, biological, and chemical contamination. AR 70-71 applies to all mission-essential equipment within the Army. NBC contamination survivability is the capability of a system and its crew to withstand an NBC-contaminated environment, including decontamination, without losing the ability to accomplish the assigned mission. Characteristics of NBC contamination survivability are decontaminability, hardness, and compatability. These characteristics are engineering design criteria which are intended for use only in a developmental setting. To comply with AR 70-71, each mission-essential item must address all three criteria. The Department of Defense (DOD) has published a draft instruction addressing acquisition of NBC contamination survivable systems. This instruction will apply throughout DOD to those programs, systems and subsystems designated by the Secretary of Defense as major systems acquisition programs and to those non-major systems that have potential impact on critical functions

42 CFR 57.316 - What additional Department regulations apply to schools?

Science.gov (United States)

2010-10-01

... schools? 57.316 Section 57.316 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN... STUDENT LOANS Nursing Student Loans § 57.316 What additional Department regulations apply to schools? Participating schools are advised that in addition to complying with the terms and conditions of these...

Annual progress report of the Department of Solid State Physics 1 January -31 December 1994

International Nuclear Information System (INIS)

Lindgaard, P.-A.; Bechgaard, K.; Clausen, K.N.; Feidenhans'l, R.; Johannsen, I.

1995-01-01

Research in the department is concerned with 'Materials with Distinct Physical and Chemical Properties'. The principal activities of the department in the period from 1 January to 31 December, 1994, are presented in this Progress Report. Neutron and x-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T c superconductivity, phase transitions in model systems, precipitation phenomena, and nano-scale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. Related to these problems there is work going on in theory, Monte Carlo simulations, and methods of data analysis. (au) (3 tabs., 116 ills., 181 refs.)

U.S. Department of Energy Workers' mental models of radiation and chemical hazards in the workplace

International Nuclear Information System (INIS)

Quadrel, M.J.; Blanchard, K.A.; Lundgren, R.E.; McMakin, A.H.; Mosley, M.T.; Strom, D.J.

1994-05-01

A pilot study was performed to test the mental models methodology regarding knowledge and perceptions of U.S. Department of Energy contractor radiation workers about ionizing radiation and hazardous chemicals. The mental models methodology establishes a target population's beliefs about risks and compares them with current scientific knowledge. The ultimate intent is to develop risk communication guidelines that address information gaps or misperceptions that could affect decisions and behavior. In this study, 15 radiation workers from the Hanford Site in Washington State were interviewed about radiation exposure processes and effects. Their beliefs were mapped onto a science model of the same topics to see where differences occurred. In general, workers' mental models covered many of the high-level parts of the science model but did not have the same level of detail. The following concepts appeared to be well understood by most interviewees: types, form, and properties of workplace radiation; administrative and physical controls to reduce radiation exposure risk; and the relationship of dose and effects. However, several concepts were rarely mentioned by most interviewees, indicating potential gaps in worker understanding. Most workers did not discuss the wide range of measures for neutralizing or decontaminating individuals following internal contamination. Few noted specific ways of measuring dose or factors that affect dose. Few mentioned the range of possible effects, including genetic effects, birth defects, or high dose effects. Variables that influence potential effects were rarely discussed. Workers rarely mentioned how basic radiation principles influenced the source, type, or mitigation of radiation risk in the workplace

Insights into the mechanisms on chemical reactions: reaction paths for chemical reactions

International Nuclear Information System (INIS)

Dunning, T.H. Jr.; Rosen, E.; Eades, R.A.

1987-01-01

We report reaction paths for two prototypical chemical reactions: Li + HF, an electron transfer reaction, and OH + H 2 , an abstraction reaction. In the first reaction we consider the connection between the energetic terms in the reaction path Hamiltonian and the electronic changes which occur upon reaction. In the second reaction we consider the treatment of vibrational effects in chemical reactions in the reaction path formalism. 30 refs., 9 figs

United States Department of Energy Nuclear Materials Stewardship

International Nuclear Information System (INIS)

Newton, J. W.

2002-01-01

The Department of Energy launched the Nuclear Materials Stewardship Initiative in January 2000 to accelerate the work of achieving integration and cutting long-term costs associated with the management of the Department's nuclear materials, with the principal focus on excess materials. Management of nuclear materials is a fundamental and enduring responsibility that is essential to meeting the Department's national security, nonproliferation, energy, science, and environmental missions into the distant future. The effective management of nuclear materials is important for a set of reasons: (1) some materials are vital to our national defense; (2) the materials pose physical and security risks; (3) managing them is costly; and (4) costs are likely to extend well into the future. The Department currently manages nuclear materials under eight programs, with offices in 36 different locations. Through the Nuclear Materials Stewardship Initiative, progress was during calendar year 20 00 in achieving better coordination and integration of nuclear materials management responsibilities and in evaluating opportunities to further coordinate and integrate cross-program responsibilities for the treatment, storage, and disposition of excess nuclear materials. During CY 2001 the Departmental approach to nuclear materials stewardship changed consistent with the business processes followed by the new administration. This paper reports on the progress of the Nuclear Materials Stewardship Initiative in evaluating and implementing these opportunities, and the remaining challenges in integrating the long-term management of nuclear materials

Chemical Processing Division monthly report, January 1966

Energy Technology Data Exchange (ETDEWEB)

Reed, P.E.

1966-02-21

This report, from the Chemical Processing Department at HAPO for January 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee relations.

Federal agencies active in chemical industry-related research and development

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-09-29

The Energy Policy Act of 1992 calls for a program to further the commercialization of renewable energy and energy efficient technologies for the industrial sector.. The primary objective of the Office of Industrial Technologies Chemical Industry Team is to work in partnership with the US chemical industry to maximize economic, energy, and environmental benefits through research and development of innovative technologies. This document was developed to inventory organizations within the federal government on current chemical industry-related research and development. While an amount of funding or number of projects specifically relating to chemical industry research and development was not defined in all organizations, identified were about 60 distinct organizations representing 7 cabinet-level departments and 4 independent agencies, with research efforts exceeding $3.5 billion in fiscal year 1995. Effort were found to range from less than $500 thousand per year at the Departments of Agriculture and the Interior to over $100 million per year at the Departments of Commerce, Defense, Energy, and Health and Human Services and the National Aeronautics and Space Administration. The total number of projects in these programs exceeded 10,000. This document is complete to the extent that agencies volunteered information. Additions, corrections, and changes are encouraged and will be incorporated in future revisions.

Overview of the US Department of Energy Light Water Reactor Sustainability Program

International Nuclear Information System (INIS)

McCarthy, K.A.; Williams, D.L.; Reister, R.

2012-01-01

The US Department of Energy Light Water Reactor Sustainability (LWRS) Program is focused on enabling the long-term operation of US commercial power plants. Decisions on life extension will be made by commercial power plant owners - the information provided by the research and development activities in the LWRS Program will reduce the uncertainty (and therefore the risk) associated with making those decisions. The LWRS Program encompasses two facets of long-term operation: (1) manage the aging of plant systems, structures, and components so that nuclear power plant lifetimes can be extended and the plants can continue to operate safely, efficiently, and economically; and (2) provide science-based solutions to the nuclear industry that support implementation of performance improvement technologies. An important aspect of the Light Water Reactor Sustainability Program is partnering with industry and the Nuclear Regulatory Commission to support and conduct the long-term research needed to inform major component refurbishment and replacement strategies, performance enhancements, plant license extensions, and age-related regulatory oversight decisions. The Department of Energy research, development, and demonstration role focuses on aging phenomena and issues that require long-term research and/or unique Department of Energy laboratory expertise and facilities and are applicable to all operating reactors. This paper provides an overview of the Department of Energy Light Water Reactor Sustainability Program, including vision, goals, and major deliverables. (author)

Origin of the chemical elements

Energy Technology Data Exchange (ETDEWEB)

Tayler, R J [Sussex Univ., Brighton (UK). Astronomy Centre

1984-11-08

An account is first given of the observed chemical composition of objects in the Universe (Sun, Solar System, stars, gas clouds) and of important variations of composition from object to object. The initial composition is then discussed in terms of the Hot Big Bang cosmological theory, and the different types of nuclear reaction which are believed to have occurred in stars and to have modified this composition are considered. Finally, an account is given of the interpretation of the present observations in terms of the initial chemical composition and of galactic and stellar formation and evolution.

Chemical Facility Security: Regulation and Issues for Congress

National Research Council Canada - National Science Library

Shea, Dana A; Tatelman, Todd B

2007-01-01

The Department of Homeland Security (DHS) has proposed security regulations for chemical facilities, implementing the statutory authority granted in the Homeland Security Appropriations Act, 2007 (P.L...

HMI Department of Radiation Chemistry: Results of scientific activities in 1984

International Nuclear Information System (INIS)

1985-01-01

In the radiation chemistry department of the Hahn-Meitner-Institute in Berlin, 4 subjects are treated largely the progress of which made in 1984 is herein reported: 1) Interface processes and energy conversion (reaction pathways of photoinduced charge carriers and their in energy conversion mechanisms); 2) Pulse radiolysis (generation and investigation of shortlived chemically quick-reacting particles); 3) Kinematics (reciprocal action with ion, atom and molecule collisions; clarification of the dynamics of chemical reactions; 4) Insulators and plastics/physical and chemical primary processes when these materials are subjected to high-energy radiation, light or UV light). A list of publications and lectures is added to complement the description of results gained from R and D work. (BR) [de

42 CFR 57.216 - What additional Department regulations apply to schools?

Science.gov (United States)

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false What additional Department regulations apply to schools? 57.216 Section 57.216 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN... schools? (a) Participating schools are advised that in addition to complying with the terms and conditions...

Science framework for conservation and restoration of the sagebrush biome: Linking the Department of the Interior’s Integrated Rangeland Fire Management Strategy to long-term strategic conservation actions

Science.gov (United States)

J.C. Chambers; J.L. Beck; J.B. Bradford; J. Bybee; S. Campbell; J. Carlson; T.J. Christiansen; K.J. Clause; G. Collins; M.R. Crist; J.B. Dinkins; K.E. Doherty; F. Edwards; S. Espinosa; K.A. Griffin; P. Griffin; J.R. Haas; S.E. Hanser; D.W. Havlina; K.F. Henke; J.D. Hennig; L.A. Joyce; F.M. Kilkenny; S.M. Kulpa; L.L. Kurth; J.D. Maestas; M. Manning; K.E. Mayer; B.A. Mealor; C. McCarthy; M. Pellant; M.A. Perea; K.L. Prentice; D.A. Pyke; L.A. Wiechman; A. Wuenschel

2017-01-01

The Science Framework is intended to link the Department of the Interior’s Integrated Rangeland Fire Management Strategy with long-term strategic conservation actions in the sagebrush biome. The Science Framework provides a multiscale approach for prioritizing areas for management and determining effective management strategies within the sagebrush biome. The emphasis...

Directory of Analytical Methods, Department 1820

International Nuclear Information System (INIS)

Whan, R.E.

1986-01-01

The Materials Characterization Department performs chemical, physical, and thermophysical analyses in support of programs throughout the Laboratories. The department has a wide variety of techniques and instruments staffed by experienced personnel available for these analyses, and we strive to maintain near state-of-the-art technology by continued updates. We have prepared this Directory of Analytical Methods in order to acquaint you with our capabilities and to help you identify personnel who can assist with your analytical needs. The descriptions of the various capabilities are requester-oriented and have been limited in length and detail. Emphasis has been placed on applications and limitations with notations of estimated analysis time and alternative or related techniques. A short, simplified discussion of underlying principles is also presented along with references if more detail is desired. The contents of this document have been organized in the order: bulky analysis, microanalysis, surface analysis, optical and thermal property measurements

Metallurgy Department progress report for the period 1 January to 31 December 1985

International Nuclear Information System (INIS)

Schroeder Pedersen, A.; Bilde Soerensen, J.B.

1986-04-01

The activities of the Metallurgy department at Risoe during 1985 are described. The work is presented in four chapters: General Materials Research, Technology and Materials Development, Chemical and Electrochemical Energy Research and Development, and Fuel elements. A survey is given of the Department's participation in international collaboration and of its activities within education and training. A list (with abstracts) of publications and lectures by the staff during 1985 is included. (author)

Metallurgy Department progress report for the period 1 January to 31 December 1986

International Nuclear Information System (INIS)

Schroeder Pedersen, A.; Bilde-Soerensen, J.B.

1987-04-01

The activities of the Metallurgy Department at Risoe during 1986 are described. The work is presented in four chapters: General Materials Research, Technology and Materials Development, Chemical and Electrochemical Energy Research and Development, and Fuel Elements. A survey is given of the Department's participation in international collaboration and of its activities within education and training. A list (with abstracts) of publications and lectures by the staff during 1986 is included. (editors)

7 CFR 46.43 - Terms construed.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing Practices), DEPARTMENT OF AGRICULTURE MARKETING OF PERISHABLE AGRICULTURAL COMMODITIES REGULATIONS (OTHER THAN RULES OF PRACTICE) UNDER THE PERISHABLE AGRICULTURAL COMMODITIES ACT, 1930 Trade Terms and...

Chemically induced immunotoxicity in a medium-term multiorgan bioassay for carcinogenesis with Wistar rats

International Nuclear Information System (INIS)

Spinardi-Barbisan, Ana Lucia Tozzi; Kaneno, Ramon; Barbisan, Luis Fernando; Viana de Camargo, Joao Lauro; Rodrigues, Maria Aparecida Marchesan

2004-01-01

A variety of chemicals can adversely affect the immune system and influence tumor development. The modifying potential of chemical carcinogens on the lymphoid organs and cytokine production of rats submitted to a medium-term initiation-promotion bioassay for carcinogenesis was investigated. Male Wistar rats were sequentially initiated with N-nitrosodiethylamine (DEN), N-methyl-N-nitrosourea (MNU), N-butyl-N-(4hydroxybutyl)nitrosamine (BBN), dihydroxy-di-n-propylnitrosamine (DHPN), and 1,2-dimethylhydrazine (DMH) during 4 weeks. Two initiated groups received phenobarbital (PB) or 2-acetylaminofluorene (2-AAF) for 25 weeks and two noninitiated groups received only PB or 2-AAF. A nontreated group was used as control. Lymphohematopoietic organs, liver, kidneys, lung, intestines, and Zymbal's gland were removed for histological analysis. Interleukin (IL)-2, IL-12, interferon gamma (IFN-γ), tumor necrosis factor alpha (TNF-α), IL-10, and transforming growth factor beta1 (TGF-β1) levels were determined by ELISA in spleen cell culture supernatants. At the fourth week, exposure to the initiating carcinogens resulted in cell depletion of the thymus, spleen and bone marrow, and impairment of IL-2, IL-12, and IFN-γ production. However, at the 30th week, no important alterations were observed both in lymphoid organs and cytokine production in the different groups. The results indicate that the initiating carcinogens used in the present protocol exert toxic effects on the lymphoid organs and affect the production of cytokines at the initiation step of carcinogenesis. This early and reversible depression of the immune surveillance may contribute to the survival of initiated cells facilitating the development of future neoplasia

Integrated chemical plants at the pulp mill

Energy Technology Data Exchange (ETDEWEB)

Ehtonen, P.; Hurme, M.; Jaervelaeinen, M.

1995-12-31

The goal of this paper is to present how the chemical plants can be integrated to the pulp mill. The integration renders possible to balance the chemical consumptions. The total mass balance of a pulp mill with the incoming fuel material and the outgoing waste and flue gases are discussed. The balance figures are presented for the chemicals of the modern fibre line, which will produce fully bleached softwood pulp with an improved effluent quality. The main benefits are lower chemical and transportation costs. The principal over-all plant process block diagrams and process descriptions are presented. The presented info system provides real time information on process and production status at overall mill and department levels. (author)

Ca isotopes, chemical weathering, and geomorphic controls on long-term climate

Science.gov (United States)

Moore, J.; Jacobson, A. D.; Holmden, C. E.; Craw, D.

2009-12-01

Calcium isotope geochemistry (δ44Ca) offers a unique opportunity to directly quantify proportions of riverine Ca originating from silicate versus carbonate weathering, which is essential for understanding how geomorphic processes affecting landscape evolution, such as tectonic uplift and glaciation, influence the long-term cycling of atmospheric CO2. We measured the elemental and δ44Ca chemistry of river and rock samples from the New Zealand Southern Alps. In combination with our geochemical data, we used runoff and suspended sediment fluxes to elucidate relationships between chemical weathering, mechanical erosion, and long-term climate. The S. Alps have uniform bedrock chemistry but significant tectonic and climatic gradients. West of the main topographic divide, watersheds drain schist and experience high runoff, uplift, and erosion rates. East of the main divide, watersheds drain greywacke or schist and experience lower runoff, uplift, and erosion rates. Glaciated watersheds with high erosion rates are present throughout the mountain range. Both schist and greywacke contain up to 3% metamorphic and hydrothermal calcite. Waters exhibit two-component mixing between calcite and silicate end-members when plotted as δ44Ca versus Ca/Sr. Scatter about the mixing curve is generally smaller than the analytical uncertainty of the measurements and likely reflects variability of the end-member compositions rather than fractionation. We used the mixing relationships to calculate percentages of Ca from silicate weathering. Rivers draining greywacke average 27.6% of Ca from silicate weathering with glaciated and non-glaciated watersheds yielding 41.8 and 19.5%, respectively. Rivers draining schist average 9.8% with glaciated and non-glaciated watersheds yielding 17.7 and 3.9%, respectively. Although Ca fluxes are larger west of the main divide where erosion and runoff are higher, the percentage of Ca from silicate weathering is smaller. Hence, long-term atmospheric CO2

Annual report 1985 of the KfK Central Safety Department

International Nuclear Information System (INIS)

Kiefer, H.; Koelzer, W.; Koenig, L.A.

1986-04-01

The Central Safety Department is responsible for handling all problems of radiation protection, safety and security of the institutes and departments of the Karlsruhe Nuclear Research Center, for waste water activity measurements and environmental monitoring of the whole area of the Center, and for research and development work mainly focusing on nuclear safety and radiation protection measures. The r+d work concentrates on the following aspects: physical and chemical behavior of biologically particularly active radionuclides, behavior of HT in the air/plant/soil system, biophysics of multicellular systems, improvement in radiation protection measurement and personnel dosimetry. This report gives details of the different duties, indicates the results of 1985 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of the Table of Contents and of Chapter 1 describing the duties and organization of the Central Safety Department. (orig./HP) [de

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 1997

Energy Technology Data Exchange (ETDEWEB)

R. C. Bartholomay (USGS); L. M. Williams (USGS); L. J. Campbell (Idaho Department of Water Resources)

1998-12-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled 18 sites as part of the fourth round of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. Water samples were collected and analyzed for selected radiochemical and chemical constituents. The samples were collected from seven domestic wells, six irrigation wells, two springs, one dairy well, one observation well, and one stock well. Two quality-assurance samples also were collected and analyzed. None of the radiochemical or chemical constituents exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide- and inorganic-constituent concentrations were greater than their respective reporting levels.

Forecasting the Emergency Department Patients Flow.

Science.gov (United States)

Afilal, Mohamed; Yalaoui, Farouk; Dugardin, Frédéric; Amodeo, Lionel; Laplanche, David; Blua, Philippe

2016-07-01

Emergency department (ED) have become the patient's main point of entrance in modern hospitals causing it frequent overcrowding, thus hospital managers are increasingly paying attention to the ED in order to provide better quality service for patients. One of the key elements for a good management strategy is demand forecasting. In this case, forecasting patients flow, which will help decision makers to optimize human (doctors, nurses…) and material(beds, boxs…) resources allocation. The main interest of this research is forecasting daily attendance at an emergency department. The study was conducted on the Emergency Department of Troyes city hospital center, France, in which we propose a new practical ED patients classification that consolidate the CCMU and GEMSA categories into one category and innovative time-series based models to forecast long and short term daily attendance. The models we developed for this case study shows very good performances (up to 91,24 % for the annual Total flow forecast) and robustness to epidemic periods.

Planning for the Transition to Long-Term Stewardship at Three U.S. Department of Energy-Chicago Operations Office Facilities

International Nuclear Information System (INIS)

Moos, L. P.; Ditmars, J. D.; Heston, S. L.; Granzen, G. A.; Holzemer, M. J.; Bennett, D. B.

2003-01-01

This paper describes a pilot study that resulted in the generation of draft planning documents for the upcoming transition from remediation construction to long-term stewardship at three national laboratories managed by the U.S. Department of Energy (DOE)-Chicago Operations Office (CH). The remediation construction work at these facilities is being completed under the DOE's Office of Environmental Management (EM) Program. Once the remediation is complete, the responsibility for long-term stewardship (LTS) of the closed waste sites is expected to be transferred to the DOE organization responsible for managing each of the three facilities (i.e., the site landlord). To prepare for this transfer, an extensive planning effort is required. This pilot study utilized the DOE guidance in effect at the time to (1) develop a series of documents identifying applicable requirements that the LTS Programs will need to satisfy, issues that need to be resolved before the transfer can proceed, and criteria to be used to determine when active remediation is complete and a given site is ready for transfer to the LTS Program; (2) examine alternate structures for possible LTS Programs; and (3) develop draft LTS Implementation Plans. This advanced planning effort yielded a number of observations and lessons learned that are applicable to any facility approaching the end of its remediation construction phase

Chemical cosmology

CERN Document Server

Boeyens, Jan CA

2010-01-01

The composition of the most remote objects brought into view by the Hubble telescope can no longer be reconciled with the nucleogenesis of standard cosmology and the alternative explanation, in terms of the LAMBDA-Cold-Dark-Matter model, has no recognizable chemical basis. A more rational scheme, based on the chemistry and periodicity of atomic matter, opens up an exciting new interpretation of the cosmos in terms of projective geometry and general relativity. The response of atomic structure to environmental pressure predicts non-Doppler cosmical redshifts and equilibrium nucleogenesis by alp

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 125; Issue 5 ... achieved by threecomponent condensation of corresponding ketones and aldehydes, ... Laboratory of Organic Chemistry Research, Department of Organic Chemistry, ...

Annual progress report of the Department of Solid State Physics 1 January -31 December 1996

Energy Technology Data Exchange (ETDEWEB)

Joergensen, M; Bechgaard, K; Clausen, K N; Feidenhans` l, R; Johannsen, I

1997-01-01

Research in the department is concerned with `Materials with Distinct Physical and Chemical Properties`. The principal activities of the department in the period from 1 January to 31 December, 1996, are presented in this Progress Report. Neutron and x-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T{sub c} superconductivity, phase transitions in model systems, precipitation phenomena, and nano-scale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. Related to these problems there is work going on in theory, Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au) 6 tabs., 144 ills., 197 refs.

Annual progress report of the Department of Solid State Physics 1 January - 31 December 1995

International Nuclear Information System (INIS)

Joergensen, M.; Bechgaard, K.; Clausen, K.N.; Feidenhans'l, R.; Johannsen, I.

1996-01-01

Research in the department is concerned with 'Materials with Distinct Physical and Chemical Properties'. The principal activities of the department in the period from 1 January to 31 December, 1995, are presented in this Progress Report. Neutron and x-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T c superconductivity, phase transitions in model systems, precipitation phenomena, and nano-scale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. Related to these problems there is work going on in theory, Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au) 5 tabs., 135 ills., 163 refs

Annual progress report of the Department of Solid State Physics 1 January - 31 December 1995

Energy Technology Data Exchange (ETDEWEB)

Joergensen, M; Bechgaard, K; Clausen, K N; Feidenhans` l, R; Johannsen, I [eds.

1996-01-01

Research in the department is concerned with `Materials with Distinct Physical and Chemical Properties`. The principal activities of the department in the period from 1 January to 31 December, 1995, are presented in this Progress Report. Neutron and x-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T{sub c} superconductivity, phase transitions in model systems, precipitation phenomena, and nano-scale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. Related to these problems there is work going on in theory, Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au) 5 tabs., 135 ills., 163 refs.

Annual progress report of the Department of Solid State Physics 1 January -31 December 1996

International Nuclear Information System (INIS)

Joergensen, M.; Bechgaard, K.; Clausen, K.N.; Feidenhans'l, R.; Johannsen, I.

1997-01-01

Research in the department is concerned with 'Materials with Distinct Physical and Chemical Properties'. The principal activities of the department in the period from 1 January to 31 December, 1996, are presented in this Progress Report. Neutron and x-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T c superconductivity, phase transitions in model systems, precipitation phenomena, and nano-scale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. Related to these problems there is work going on in theory, Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au) 6 tabs., 144 ills., 197 refs

Chemical Processing Division monthly report, November 1966

Energy Technology Data Exchange (ETDEWEB)

Reed, P.E.

1966-12-21

This report, from the Chemical Processing Department at HAPO for November 1966, discusses the following: Production operation; Purex and Redox operation; Finished products operation; maintenance; Financial operations; facilities engineering; research; and employee-relations, and waste management.

Annual report 1982 of the Central Safety Department

International Nuclear Information System (INIS)

Kiefer, H.; Koelzer, W.; Koenig, L.A.

1983-04-01

The Safety Officer and the Security Officer are responsible for radiation protection and technical safety, both conventional and nuclear, for the physical protection as well as the safeguards of nuclear materials and radioactive substances within the Kernforschungszentrum Karlsruhe GmbH (KfK). To fulfill these functions they rely on the assistance of the Safety Department. The duties of this Department cover tasks relative to radiation protection, safety and security on behalf of the institutes and departments of KfK and environmental monitoring for the whole Karlsruhe Nuclear Research Center as well as research and development work, mainly performed under the Nuclear Safety Project. The centers of interest of r + d activities are: investigation of the atmospheric diffusion of nuclear pollutants on the micro- and meso-scales, evaluation of the radiological consequences of accidents in reactors under probabilistic aspects, studies of the physical and chemical behavior of radionuclides with particularly high biological effectiveness in the environment, improvements in radiation protection measurement technology. This report gives details of the different duties, indicates the results of 1982 routine tasks and reports about results of investigations and developments of the working groups of the Department. The reader is referred to the English translation of the Table of Contents and of Chapter 1 describing the duties and organization of the Central Safety Department. (orig.) [de

Chemical sensors

International Nuclear Information System (INIS)

Hubbard, C.W.; Gordon, R.L.

1987-05-01

The revolution in analytical chemistry promised by recent developments in the field of chemical sensors has potential for significant positive impact on both research and production activities conducted by and for the Department of Energy. Analyses which were, in the past, performed only with a roomful of expensive equipment can now be performed with miniature solid-state electronic devices or small optical probes. Progress in the development of chemical sensors has been rapid, and the field is currently growing at a great rate. In accordance, Pacific Northwest Laboratory initiated a survey of recent literature so that contributors to active programs in research on analytical methods could be made aware of principles and applications of this new technology. This report presents the results of that survey. The sensors discussed here are divided into three types: micro solid-state devices, optical sensors, and piezoelectric crystal devices. The report is divided into three corresponding sections. The first section, ''Micro Solid-State Devices,'' discusses the design, operation, and application of electronic sensors that are produced in much the same way as standard solid-state electronic devices. The second section, ''Optrodes,'' covers the design and operation of chemical sensors that use fiber optics to detect chemically induced changes in optical properties. The final section, ''Piezoelectric Crystal Detectors,'' discusses two types of chemical sensors that depend on the changes in the properties of an oscillating piezoelectric crystal to detect the presence of certain materials. Advantages and disadvantages of each type of sensor are summarized in each section

The Lattice Compatibility Theory LCT: Physical and Chemical Arguments from the Growth Behavior of Doped Compounds in terms of Bandgap Distortion and Magnetic Effects

Directory of Open Access Journals (Sweden)

K. Boubaker

2013-01-01

Full Text Available Physical and chemical arguments for the recently discussed materials-related Lattice Compatibility Theory are presented. The discussed arguments are based on some differences of Mn ions incorporation kinetics inside some compounds. These differences have been evaluated and quantified in terms of alteration of bandgap edges, magnetic patterns, and Faraday effect.

Semi-annual report of the Mineral Technology Department from CDTN - July to December 1988

International Nuclear Information System (INIS)

Coelho, S.V.; Fernandes, M.D.; Golcalves, J.R.; Murta, R.L.L.

1989-01-01

The activities developed by the Mineral Technology Department of CDTN during 1988, in the area of chemical analysis, mineralogy, petrography and studies about mineral characterization are described. (E.G.) [pt

Chemical hardness and density functional theory

Indian Academy of Sciences (India)

Unknown

RALPH G PEARSON. Chemistry Department, University of California, Santa Barbara, CA 93106, USA. Abstract. The concept of chemical hardness is reviewed from a personal point of view. Keywords. Hardness; softness; hard & soft acids bases (HSAB); principle of maximum hardness. (PMH) density functional theory (DFT) ...

Recycling and surplus chemical programs

International Nuclear Information System (INIS)

Harper, T.J.

1993-05-01

In 1988, 45 years of defense production came to a close at the US Department of Energy (DOE) Hanford Site. The mission of the Hanford Site was formally changed to environmental restoration and remediation. Westinghouse Hanford Company (WHC) is the management and operations (M ampersand O) contractor leading the cleanup. Within the framework of future Site cleanup, Hanford recycling and surplus chemical programs are making a viable contribution today to waste minimization, diversion of materials from the waste stream, and setting a standard for future operations. This paper focuses on two successful efforts: paper recycling and surplus chemical sales

A New Paradigm for Chemical Engineering?

DEFF Research Database (Denmark)

Gani, Rafiqul

evidence of this change comes from the jobs taken by graduating chemical engineering professionals in North America, Europe, and some of the Asian countries. In terms of where the graduating chemical engineers are going to work, a clear shift from the commodity chemical industry to the product oriented...... businesses has been observed. There is an increasing trend within the chemical industry to focus on products and the sustainable processes that can make them. Do these changes point to a paradigm shift in chemical engineering as a discipline? Historically, two previous paradigm shifts in chemical engineering...... corresponded to major shifts in chemical engineering as a discipline, which affected not only the education of chemical engineers, but also the development of chemical engineering as a discipline. Has the time come for a new paradigm shift that will prepare the current and future chemical engineering graduates...

Semiannual Report of the Chemistry Department, June--November 1966; Rapport semestriel du departement de chimie, juin--novembre 1966

Energy Technology Data Exchange (ETDEWEB)

NONE

1967-07-01

This semiannual report of the Chemistry Department of the Cea of Fontenay-aux Roses, presents in its first part researches on the chemical analysis, the treatment of fairly and slightly active effluents, the uranium treatment, studies on electrometallurgy, studies on corrosion and studies on filtration and elimination on sea water of hard compounds. The second part is devoted to the study of aqueous reprocessing of irradiated fuels (laboratory and pilot plant), anhydrous reprocessing, actinides elements isotopes preparation and study, fission products concentrated solution vitrification study and fundamental studies on acid-base properties. (A.L.B.)

Reciprocal Allocation Method in Service Departments. The Case of a Production Enterprise

Science.gov (United States)

Papaj, Ewelina

2017-12-01

The main aim of this article is to indicate the role of reciprocal allocation method in the process of costs calculation. In the environment of nowadays companies, often taking very complex organisational forms, the existence of service departments becomes of great importance. Although, as far as management accounting processes are concerned, which lead to identifying the product cost, the service departments' costs come out to be of minor importance. This article means to prove that the service departments' costs and their reliable settlement are a desirable source of information about the products. This work consists of two parts. First of them features theoretical considerations and a critical analysis of subject literature. In the latter part, the service departments' costs calculation will be presented, basing on reciprocal services in a production enterprise from chemical industry.

Aerosol Chemical Speciation Monitor (ACSM) Instrument Handbook

Energy Technology Data Exchange (ETDEWEB)

Watson, Thomas B. [Brookhaven National Lab. (BNL), Upton, NY (United States)

2017-08-15

The Aerodyne Aerosol Chemical Speciation Monitor (ACSM) measures particle mass loading and chemical composition in real time for non-refractory sub-micron aerosol particles. The ACSM is designed for long-term unattended deployment and routine monitoring applications.

An investigation on the chemical stability and a novel strategy for long-term stabilization of diphenylalanine nanostructures in aqueous solution

Directory of Open Access Journals (Sweden)

H. Nezammahalleh

2015-01-01

Full Text Available The stability of diphenylalanine (FF microwires and microtubes in phosphate buffer solution was investigated and a novel strategy was developed for their chemical stabilization. This stability investigation was carried out by optical microscopy and by high performance liquid chromatography (HPLC. These microstructures dissolve in the solution depending upon their degree of FF saturation. The dissolution mechanisms of the structures in kinetically limited processes were found by accurately fitting the experimental dissolution data to a theoretical kinetic equation. The dissolution data were well fitted to the particular Avrami-Erofe’ev kinetic expression (R2 > 0.98. These findings suggest that the structures can be stabilized by a decrease in the hydration of the constituent molecules thorough a chemical conformational induced transition upon heat treatment. The stable microtubes were fabricated in a novel three step procedure consisting of the reduction of silver ions in unstable FF microtubes by a citrate reductant, the stabilization by chemical conformational induced transition upon heat treatment, and the consequent oxidation of the reduced silver by a persulfate oxidant. These materials were characterized by electron microscopy and powder X-ray diffraction techniques. The long-term stability of both structures was also confirmed by optical microscopy and HPLC.

7 CFR 28.950 - Terms defined.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing..., TESTING, AND STANDARDS Cotton Fiber and Processing Tests Definitions § 28.950 Terms defined. As used... Agricultural Marketing Service of the U.S. Department of Agriculture. (c) Administrator. The Administrator of...

Effect of irradiation and chemical composition on deformation and fracture of steel of OH16N15 type during long-term test

International Nuclear Information System (INIS)

Averin, S.A.; Deniskin, Yu.S.; Shushlebin, V.V.; Panchenko, V.L.

1992-01-01

Thermal and radiation creep, as well as long-term strength of an austenitic stainless steel were investigated as a function of sulphur content and niobium addition. Interrelation between the grain boundary sleep and the intergranular fracture, and an important role of the surface in the nucleation and propagation of crack were revealed by quantitative structural and fractographic studies. Irradiation and chemical composition were found to influence these processes

The assessment of treated wastewater quality and the effects of mid-term irrigation on soil physical and chemical properties (case study: Bandargaz-treated wastewater)

Science.gov (United States)

Kaboosi, Kami

2017-09-01

This study was conducted to investigate the characteristics of inflow and outflow wastewater of the Bandargaz wastewater treatment plant on the basis of the data collection of operation period and the samples taken during the study. Also the effects of mid-term use of the wastewater for irrigation (from 2005 to 2013) on soil physical and chemical characteristics were studied. For this purpose, 4 samples were taken from the inflow and outflow wastewater and 25 quality parameters were measured. Also, the four soil samples from a depth of 0-30 cm of two rice field irrigated with wastewater in the beginning and middle of the planting season and two samples from one adjacent rice field irrigated with fresh water were collected and their chemical and physical characteristics were determined. Average of electrical conductivity, total dissolved solids, sodium adsorption ratio, chemical oxygen demand and 5 days biochemical oxygen demand in treated wastewater were 1.35 dS/m, 707 ppm, 0.93, 80 ppm and 40 ppm, respectively. Results showed that although some restrictions exist about chlorine and bicarbonate, the treated wastewater is suitable for irrigation based on national and international standards and criteria. In comparison with fresh water, the mid-term use of wastewater caused a little increase of soil salinity. However, it did not lead to increase of soil salinity beyond rice salinity threshold. Also, there were no restrictions on soil in the aspect of salinity and sodium hazard on the basis of many irrigated soil classifications. In comparison with fresh water, the mid-term use of wastewater caused the increase of total N, absorbable P and absorbable K in soil due to high concentration of those elements in treated wastewater.

Assessing the Higher National Diploma Chemical Engineering programme in Ghana: students' perspective

Science.gov (United States)

Boateng, Cyril D.; Cudjoe Bensah, Edem; Ahiekpor, Julius C.

2012-05-01

Chemical engineers have played key roles in the growth of the chemical and allied industries in Ghana but indigenous industries that have traditionally been the domain of the informal sector need to be migrated to the formal sector through the entrepreneurship and innovation of chemical engineers. The Higher National Diploma Chemical Engineering programme is being migrated from a subject-based to a competency-based curriculum. This paper evaluates the programme from the point of view of students. Data were drawn from a survey conducted in the department and were analysed using SPSS. The survey involved administering questionnaires to students at all levels in the department. Analysis of the responses indicated that the majority of the students had decided to pursue chemical engineering due to the career opportunities available. Their knowledge of the programme learning outcomes was, however, poor. The study revealed that none of the students was interested in developing indigenous industries.

Some concepts in condensed phase chemical kinetics

International Nuclear Information System (INIS)

Adelman, S.A.

1986-01-01

Some concepts in condensed phase chemical kinetics which have emerged from a recent rigorous statistical mechanical treatment of condensed phase chemical reaction dynamics (S.A. Adelman, Adv. Chem. Phys.53:61 (1983)) are discussed in simple physical terms

Potential long-term chemical effects of diesel fuel emissions on a mining environment: A preliminary assessment based on data from a deep subsurface tunnel at Rainer Mesa, Nevada test site

Energy Technology Data Exchange (ETDEWEB)

Meike, A.; Bourcier, W.L.; Alai, M. [and others

1995-09-01

The general purpose of the Yucca Mountain Site Characterization Project (YMSCP) Introduced Materials Task is to understand and predict potential long-term modifications of natural water chemistry related to the construction and operation of a radioactive waste repository that may significantly affect performance of the waste packages. The present study focuses on diesel exhaust. Although chemical information on diesel exhaust exists in the literature, it is either not explicit or incomplete, and none of it establishes mechanisms that might be used to predict long-term behavior. In addition, the data regarding microbially mediated chemical reactions are not well correlated with the abiotic chemical data. To obtain some of the required long-term information, we chose a historical analog: the U12n tunnel at Rainier Mesa, Nevada Test Site. This choice was based on the tunnel`s extended (30-year) history of diesel usage, its geological similarity to Yucca Mountain, and its availability. The sample site within the tunnel was chosen based on visual inspection and on information gathered from miners who were present during tunnel operations. The thick layer of dark deposit at that site was assumed to consist primarily of rock powder and diesel exhaust. Surface samples and core samples were collected with an intent to analyze the deposit and to measure potential migration of chemical components into the rock. X-ray diffraction (XRD), x-ray fluorescence (XRF), scanning electron microscopy (SEM) with energy dispersive spectra (EDS) analysis, secondary-ion mass spectrometry (SIMS), and Fourier transform infrared (FTIR) analysis were used to measure both spatial distribution and concentration for the wide variety of chemical components that were expected based on our literature survey.

Potential long-term chemical effects of diesel fuel emissions on a mining environment: A preliminary assessment based on data from a deep subsurface tunnel at Rainer Mesa, Nevada test site

International Nuclear Information System (INIS)

Meike, A.; Bourcier, W.L.; Alai, M.

1995-09-01

The general purpose of the Yucca Mountain Site Characterization Project (YMSCP) Introduced Materials Task is to understand and predict potential long-term modifications of natural water chemistry related to the construction and operation of a radioactive waste repository that may significantly affect performance of the waste packages. The present study focuses on diesel exhaust. Although chemical information on diesel exhaust exists in the literature, it is either not explicit or incomplete, and none of it establishes mechanisms that might be used to predict long-term behavior. In addition, the data regarding microbially mediated chemical reactions are not well correlated with the abiotic chemical data. To obtain some of the required long-term information, we chose a historical analog: the U12n tunnel at Rainier Mesa, Nevada Test Site. This choice was based on the tunnel's extended (30-year) history of diesel usage, its geological similarity to Yucca Mountain, and its availability. The sample site within the tunnel was chosen based on visual inspection and on information gathered from miners who were present during tunnel operations. The thick layer of dark deposit at that site was assumed to consist primarily of rock powder and diesel exhaust. Surface samples and core samples were collected with an intent to analyze the deposit and to measure potential migration of chemical components into the rock. X-ray diffraction (XRD), x-ray fluorescence (XRF), scanning electron microscopy (SEM) with energy dispersive spectra (EDS) analysis, secondary-ion mass spectrometry (SIMS), and Fourier transform infrared (FTIR) analysis were used to measure both spatial distribution and concentration for the wide variety of chemical components that were expected based on our literature survey

Stochastic thermodynamics and entropy production of chemical reaction systems

Science.gov (United States)

Tomé, Tânia; de Oliveira, Mário J.

2018-06-01

We investigate the nonequilibrium stationary states of systems consisting of chemical reactions among molecules of several chemical species. To this end, we introduce and develop a stochastic formulation of nonequilibrium thermodynamics of chemical reaction systems based on a master equation defined on the space of microscopic chemical states and on appropriate definitions of entropy and entropy production. The system is in contact with a heat reservoir and is placed out of equilibrium by the contact with particle reservoirs. In our approach, the fluxes of various types, such as the heat and particle fluxes, play a fundamental role in characterizing the nonequilibrium chemical state. We show that the rate of entropy production in the stationary nonequilibrium state is a bilinear form in the affinities and the fluxes of reaction, which are expressed in terms of rate constants and transition rates, respectively. We also show how the description in terms of microscopic states can be reduced to a description in terms of the numbers of particles of each species, from which follows the chemical master equation. As an example, we calculate the rate of entropy production of the first and second Schlögl reaction models.

A proposed chemical mechanism for biological phosphate removal ...

African Journals Online (AJOL)

DRINIE

2003-04-02

Apr 2, 2003 ... Water Utilisation Division, Department of Chemical Engineering, University of ... wastewater reacts with orthophosphate under anaerobic conditions to make ... role of acetates and other short-chain carbon compounds in bio-.

Technology for the long-term management of defense HLW at the Idaho Chemical Processing Plant

International Nuclear Information System (INIS)

Staples, B.A.; Berreth, J.R.; Knecht, D.A.

1986-01-01

The Defense Waste Management Plan of June 1983 includes a reference plan for the long-term management of Idaho Chemical Processing Plant (ICPP) high-level waste (HLW), with a goal of disposing of the annual output in 500 canisters a year by FY-2008. Based on the current vitrification technology, the ICPP base-glass case would produce 1700 canisters per year after FY-2007. Thus, to meet the DWMP goal processing steps including fuel dissolution, waste treatment, and waste immobilization are being studied as areas where potential modifications could result in HLW volume reductions for repository disposal. It has been demonstrated that ICPP calcined wastes can be densified by hot isostatic pressing to multiphase ceramic forms of high loading and density. Conversion of waste by hot isostatic pressing to these forms has the potential of reducing the annual ICPP waste production to volumes near those of the goal of the DWMP. This report summarizes the laboratory-scale information currently available on the development of these forms

Short- and Long-Term Prognostic Utility of the HEART Score in Patients Evaluated in the Emergency Department for Possible Acute Coronary Syndrome.

Science.gov (United States)

Jain, Tarun; Nowak, Richard; Hudson, Michael; Frisoli, Tiberio; Jacobsen, Gordon; McCord, James

2016-06-01

The HEART score is a risk-stratification tool that was developed and validated for patients evaluated for possible acute coronary syndrome (ACS) in the emergency department (ED). We sought to determine the short-term and long-term prognostic utility of the HEART score. A retrospective single-center analysis of 947 patients evaluated for possible ACS in the ED in 1999 was conducted. Patients were followed for major adverse cardiac events (MACEs) at 30 days: death, acute myocardial infarction, or revascularization procedure. All-cause mortality was assessed at 5 years. The HEART score was compared with the Thrombolysis in Myocardial Infarction (TIMI) score. At 30 days, 14% (135/947) of patients had an MACE: 48 deaths (5%), 84 acute myocardial infarctions (9%), and 48 (5%) revascularization procedures. The MACE rate in patients with HEART score ≤3 was 0.6% (1/175) involving a revascularization procedure, 9.5% (53/557) in patients with HEART score between 4 and 6, and 38% (81/215) with HEART score ≥7. The C-statistic for the HEART score was 0.82 and 0.68 for the TIMI score for predicting 30-day MACE (P < 0.05). Patients with HEART score ≤3 had lower 5-year mortality rate compared with those with TIMI score of 0 (10.6% vs. 20.5%, P = 0.02). The HEART score is a valuable risk-stratification tool in predicting not only short-term MACE but also long-term mortality in patients evaluated for possible ACS in the ED. The HEART score had a superior prognostic value compared with the TIMI score.

7 CFR 28.2 - Terms defined.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture AGRICULTURAL MARKETING SERVICE (Standards, Inspections, Marketing..., TESTING, AND STANDARDS Regulations Under the United States Cotton Standards Act Definitions § 28.2 Terms... to act for the Secretary. (e) Service. The Agricultural Marketing Service of the U.S. Department of...

Long-term high-level waste technology program

International Nuclear Information System (INIS)

1980-04-01

The Department of Energy (DOE) is conducting a comprehensive program to isolate all US nuclear wastes from the human environment. The DOE Office of Nuclear Energy - Waste (NEW) has full responsibility for managing the high-level wastes resulting from defense activities and additional responsiblity for providing the technology to manage existing commercial high-level wastes and any that may be generated in one of several alternative fuel cycles. Responsibilities of the Three Divisions of DOE-NEW are shown. This strategy document presents the research and development plan of the Division of Waste Products for long-term immobilization of the high-level radioactive wastes resulting from chemical processing of nuclear reactor fuels and targets. These high-level wastes contain more than 99% of the residual radionuclides produced in the fuels and targets during reactor operations. They include essentially all the fission products and most of the actinides that were not recovered for use

Chemical evolutionary games.

Science.gov (United States)

Aristotelous, Andreas C; Durrett, Richard

2014-05-01

Inspired by the use of hybrid cellular automata in modeling cancer, we introduce a generalization of evolutionary games in which cells produce and absorb chemicals, and the chemical concentrations dictate the death rates of cells and their fitnesses. Our long term aim is to understand how the details of the interactions in a system with n species and m chemicals translate into the qualitative behavior of the system. Here, we study two simple 2×2 games with two chemicals and revisit the two and three species versions of the one chemical colicin system studied earlier by Durrett and Levin (1997). We find that in the 2×2 examples, the behavior of our new spatial model can be predicted from that of the mean field differential equation using ideas of Durrett and Levin (1994). However, in the three species colicin model, the system with diffusion does not have the coexistence which occurs in the lattices model in which sites interact with only their nearest neighbors. Copyright © 2014 Elsevier Inc. All rights reserved.

Consequence and Resilience Modeling for Chemical Supply Chains

Science.gov (United States)

Stamber, Kevin L.; Vugrin, Eric D.; Ehlen, Mark A.; Sun, Amy C.; Warren, Drake E.; Welk, Margaret E.

2011-01-01

The U.S. chemical sector produces more than 70,000 chemicals that are essential material inputs to critical infrastructure systems, such as the energy, public health, and food and agriculture sectors. Disruptions to the chemical sector can potentially cascade to other dependent sectors, resulting in serious national consequences. To address this concern, the U.S. Department of Homeland Security (DHS) tasked Sandia National Laboratories to develop a predictive consequence modeling and simulation capability for global chemical supply chains. This paper describes that capability , which includes a dynamic supply chain simulation platform called N_ABLE(tm). The paper also presents results from a case study that simulates the consequences of a Gulf Coast hurricane on selected segments of the U.S. chemical sector. The case study identified consequences that include impacted chemical facilities, cascading impacts to other parts of the chemical sector. and estimates of the lengths of chemical shortages and recovery . Overall. these simulation results can DHS prepare for and respond to actual disruptions.

Fission-product source terms

International Nuclear Information System (INIS)

Lorenz, R.A.

1981-01-01

This presentation consists of a review of fission-product source terms for light water reactor (LWR) fuel. A source term is the quantity of fission products released under specified conditions that can be used to calculate the consequences of the release. The source term usually defines release from breached fuel-rod cladding but could also describe release from the primary coolant system, the reactor containment shell, or the site boundary. The source term would be different for each locality, and the chemical and physical forms of the fission products could also differ

Long-term cloud condensation nuclei number concentration, particle number size distribution and chemical composition measurements at regionally representative observatories

Science.gov (United States)

Schmale, Julia; Henning, Silvia; Decesari, Stefano; Henzing, Bas; Keskinen, Helmi; Sellegri, Karine; Ovadnevaite, Jurgita; Pöhlker, Mira L.; Brito, Joel; Bougiatioti, Aikaterini; Kristensson, Adam; Kalivitis, Nikos; Stavroulas, Iasonas; Carbone, Samara; Jefferson, Anne; Park, Minsu; Schlag, Patrick; Iwamoto, Yoko; Aalto, Pasi; Äijälä, Mikko; Bukowiecki, Nicolas; Ehn, Mikael; Frank, Göran; Fröhlich, Roman; Frumau, Arnoud; Herrmann, Erik; Herrmann, Hartmut; Holzinger, Rupert; Kos, Gerard; Kulmala, Markku; Mihalopoulos, Nikolaos; Nenes, Athanasios; O'Dowd, Colin; Petäjä, Tuukka; Picard, David; Pöhlker, Christopher; Pöschl, Ulrich; Poulain, Laurent; Prévôt, André Stephan Henry; Swietlicki, Erik; Andreae, Meinrat O.; Artaxo, Paulo; Wiedensohler, Alfred; Ogren, John; Matsuki, Atsushi; Yum, Seong Soo; Stratmann, Frank; Baltensperger, Urs; Gysel, Martin

2018-02-01

Aerosol-cloud interactions (ACI) constitute the single largest uncertainty in anthropogenic radiative forcing. To reduce the uncertainties and gain more confidence in the simulation of ACI, models need to be evaluated against observations, in particular against measurements of cloud condensation nuclei (CCN). Here we present a data set - ready to be used for model validation - of long-term observations of CCN number concentrations, particle number size distributions and chemical composition from 12 sites on 3 continents. Studied environments include coastal background, rural background, alpine sites, remote forests and an urban surrounding. Expectedly, CCN characteristics are highly variable across site categories. However, they also vary within them, most strongly in the coastal background group, where CCN number concentrations can vary by up to a factor of 30 within one season. In terms of particle activation behaviour, most continental stations exhibit very similar activation ratios (relative to particles > 20 nm) across the range of 0.1 to 1.0 % supersaturation. At the coastal sites the transition from particles being CCN inactive to becoming CCN active occurs over a wider range of the supersaturation spectrum. Several stations show strong seasonal cycles of CCN number concentrations and particle number size distributions, e.g. at Barrow (Arctic haze in spring), at the alpine stations (stronger influence of polluted boundary layer air masses in summer), the rain forest (wet and dry season) or Finokalia (wildfire influence in autumn). The rural background and urban sites exhibit relatively little variability throughout the year, while short-term variability can be high especially at the urban site. The average hygroscopicity parameter, κ, calculated from the chemical composition of submicron particles was highest at the coastal site of Mace Head (0.6) and lowest at the rain forest station ATTO (0.2-0.3). We performed closure studies based on κ-Köhler theory

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

2. Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, School of Chemistry and Chemical Engineering, Huaiyin Normal University, Huai'an 223300, P R China; Department of Chemistry, Science College, Yanbian University, ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Author Affiliations. Reza Fareghi-Alamdari1 Mohsen Golestanzadeh1 Farima Agend1 Negar Zekri1. Department of Chemistry and Chemical Engineering, Malek-Ashtar University of Technology, Tehran, 16765-3454, I. R. Iran ...

International Journal of Biological and Chemical Sciences: Editorial ...

African Journals Online (AJOL)

The International Journal of Biological and Chemical Sciences (IJBCS) is a journal ... IJBCS publishes original research papers, critical up-to-date and concise ... Department of Biomedical Sciences, College of Osteopathic Medicine, Ohio ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 126; Issue 1 ... Centre for Nanotechnology Research, VIT University, Vellore 632 014, India; Department of ... Nissan Technology & Business Center India (P) Ltd., Chennai 603002, India ...

15 CFR 710.6 - Relationship between the Chemical Weapons Convention Regulations and the Export Administration...

Science.gov (United States)

2010-01-01

... INDUSTRY AND SECURITY, DEPARTMENT OF COMMERCE CHEMICAL WEAPONS CONVENTION REGULATIONS GENERAL INFORMATION AND OVERVIEW OF THE CHEMICAL WEAPONS CONVENTION REGULATIONS (CWCR) § 710.6 Relationship between the Chemical Weapons Convention Regulations and the Export Administration Regulations, the International...

Long term physical and chemical stability of polyelectrolyte multilayer membranes

NARCIS (Netherlands)

de Grooth, Joris; Haakmeester, Brian; Wever, Carlos; Potreck, Jens; de Vos, Wiebe Matthijs; Nijmeijer, Dorothea C.

2015-01-01

This work presents a detailed investigation into the long term stability of polyelectrolyte multilayer (PEM) modified membranes, a key factor for the application of these membranes in water purification processes. Although PEM modified membranes have been frequently investigated, their long term

Geomatic techniques for assessing ecological and health risk at U.S. Department of Energy facilities

International Nuclear Information System (INIS)

Regens, J.L.; White, L.; Albers, B.J.; Purdy, C.

1994-01-01

Hazardous substances, including radionuclides, heavy metals, and chlorinated hydrocarbons, pose unique challenges in terms of environmental restoration and waste management, especially in aquatic environments. When stored, used or disposed of improperly, hazardous materials including transuranic wastes, high level wastes, low level wastes, greater than class C wastes, mixed wastes or chemical wastes can contaminate an array of environmental receptors ranging from soils, sediments, groundwater to surface water. Depending on the specific hazardous substance and site attributes, assessing ecological and health risk as a basis for environmental restoration and waste management can be a complex, problematic activity. This is basis for environmental restoration and waste management can be a complex, problematic activity. This is particularly true for the major Defense Programs facilities managed by the U.S. Department of Energy (DOE). The Environmental Restoration (ER) program of DOE was initiated in 1987 to consolidate and coordinate those regulatory activities designed to identify and remediate sites at installations contaminated with radioactive, chemical or mixed wastes. To supply the tools necessary for defining, describing, and characterizing the nature of contaminants within the DOE complex and identifying alternative post-remediation land use options, DOE has implemented a program for the research and development of spatial data technologies to aid in assessing ecological and health risk

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 125; Issue 6 ... friendly deprotection of acetonides and cleavage of acetals and ketones has been ... Department of Organic Chemistry, Indian Association for the Cultivation of Science, ...

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 1998

Energy Technology Data Exchange (ETDEWEB)

R. C. Bartholomay; B. V. Twining (USGS); L. J. Campbell (Idaho Department of Water Resources)

1999-06-01

The U.S. Geological Survey and the Idaho Department of Water Resources, in cooperation with the U.S. Department of Energy, sampled 18 sites as part of the fourth round of a long-term project to monitor water quality of the Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. The samples were analyzed for selected radiochemical and chemical constituents. The samples were collected from 2 domestic wells, 12 irrigation wells, 2 stock wells, 1 spring, and 1 public supply well. Two quality-assurance samples also were collected and analyzed. None of the reported radiochemical or chemical constituent concentrations exceeded the established maximum contaminant levels for drinking water. Many of the radionuclide- and inorganic-constituent concentrations were greater than the respective reporting levels. Most of the organic-constituent concentrations were less than the reporting levels.

National Agricultural Library | United States Department of Agriculture

Science.gov (United States)

Skip to main content Home National Agricultural Library United States Department of Agriculture Ag Terms of Service Frequently Asked Questions Policies and Documentation Ag Data Commons Monthly Metrics News Contact Us Search  Log inRegister Home Home About Policies and Documentation Ag Data Commons

Chemical effects in the mine structure

International Nuclear Information System (INIS)

1992-02-01

The main objective of the workshop was to bring together, and get talking to each other, long-term safety modellers, geochemical modellers and experimenters working in the field of chemical effects, and to give an insight into their respective activity areas and problem constellations. Lectures on the following subjects were given: modelling of chemical effects in long-term safety analysis; influence of brines; corrosion experiments; sorption experiments; actinide chemistry experiments; geochemical modelling; requirements of safety analyses and geochemical modelling. The workshop concluded with a detailed discussion of the subjects raised and of interdisciplinary aspects. (orig./DG) [de

Nigerian Journal of Chemical Research: Advanced Search

African Journals Online (AJOL)

PROMOTING ACCESS TO AFRICAN RESEARCH ... Nigerian Journal of Chemical Research: Advanced Search ... containing either term; e.g., education OR research; Use parentheses to create more complex queries; e.g., .... and Applied Sciences, Nigerian Journal of Biotechnology, Nigerian Journal of Chemical Research ...

Mutagenicity of chemicals in genetically modified animals

NARCIS (Netherlands)

Willems MI; van Benthem J; LEO

2001-01-01

The strategy for assessing human health risks of chemicals consists of a large number of tests in different research disciplines. Tests include acute and chronic toxicity, genotoxicity, reproduction toxicity and carcinogenicity. Genotoxic properties of chemicals are assessed in short-term in vitro

Model abstraction addressing long-term simulations of chemical degradation of large-scale concrete structures

International Nuclear Information System (INIS)

Jacques, D.; Perko, J.; Seetharam, S.; Mallants, D.

2012-01-01

This paper presents a methodology to assess the spatial-temporal evolution of chemical degradation fronts in real-size concrete structures typical of a near-surface radioactive waste disposal facility. The methodology consists of the abstraction of a so-called full (complicated) model accounting for the multicomponent - multi-scale nature of concrete to an abstracted (simplified) model which simulates chemical concrete degradation based on a single component in the aqueous and solid phase. The abstracted model is verified against chemical degradation fronts simulated with the full model under both diffusive and advective transport conditions. Implementation in the multi-physics simulation tool COMSOL allows simulation of the spatial-temporal evolution of chemical degradation fronts in large-scale concrete structures. (authors)

Department of Defense Chemical and Biological Defense Program. Volume I: Annual Report to Congress

Science.gov (United States)

2002-04-01

nerve agents. * Identified specific gene products that are either enhanced or depressed in the brain following low-level chemical warfare nerve agent...with ample time to properly treat for injury. This model was used to determine that N- acetylcysteine given intraperitoneally increased survival rates in

7 CFR 1210.322 - Term of office.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE WATERMELON RESEARCH AND PROMOTION PLAN Watermelon Research and Promotion Plan National Watermelon Promotion Board § 1210.322 Term of...

Long term effects of chemical weapons on health in Kurdistan of Iraq

International Nuclear Information System (INIS)

Dizaye, K.

2009-01-01

Extensive exposure to chemical weapons such as mustard gas, nerve gas and cyanide caused high mortality, morbidity, injuries, and chronic side effects in vital organs, especially the respiratory tract. Chemical weapons were heavily used by Iraq against Iranian soldiers between 1984-1986. Then, against the Iraqi Kurd in Sheikh Wasan and Balisan valley, during April 1987 and in Halabja on 18th March 1988. Reports suggested that as many as 2.9 percent of the Kurdish population have been exposed to chemical weapon at some level. This case report describes a Kurdish lady who was exposed to mustard gas during a chemical attack in sheikh Wasan in Iraq. A thirty two years old woman wearing black clothes presented to our center at 1999 complaining from shortness of breath (SOB). Her condition started 12 years ago when the Iraqi Government attacked her village Sheikh Wasan by Chemical weapons which included Mustard gas and nerve gases such as Sarin, Tabun and VX in April 1987. She described how the gas smelled like garlic as it spread over the village. During the attack she suffered from sever SOB, cough, skin burn and eyes irritation and lacrimation. After several days of being without medical care, she received some medical attention by local medical staff at the area because the Iraqi authorities at that time refused and prohibited them from management at the major hospitals. After several days when she returned back to her home she found that several members of her family have died during the exposure to chemical gases. Among the dead people were her husband, her son, her brother in addition to other second and third degree relatives. Since that time she suffered from repeated attacks of cough and SOB and wheezing that were increased by exertion and cold exposure. The attacks were more sever with time and the SOB has interfered with her daily activity and even lastly she was suffering from SOB at rest and during sleep that made her unable to sleep lying down. Moreover

10 CFR 905.31 - Term.

Science.gov (United States)

2010-01-01

... 10 Energy 4 2010-01-01 2010-01-01 false Term. 905.31 Section 905.31 Energy DEPARTMENT OF ENERGY ENERGY PLANNING AND MANAGEMENT PROGRAM Power Marketing Initiative § 905.31 Term. Western will extend resource commitments for 20 years from the date existing contracts expire to existing customers with long...

Factors Associated With the Trend of Physical and Chemical Restraint Use Among Long-Term Care Facility Residents in Hong Kong: Data From an 11-Year Observational Study.

Science.gov (United States)

Lam, Kuen; Kwan, Joseph S K; Wai Kwan, Chi; Chong, Alice M L; Lai, Claudia K Y; Lou, Vivian W Q; Leung, Angela Y M; Liu, Justina Y W; Bai, Xue; Chi, Iris

2017-12-01

Negative effects of restraint use have been well-documented. However, the prevalence of restraints use has been high in long-term care facilities in Hong Kong compared with other countries and this goes against the basic principles of ethical and compassionate care for older people. The present study aimed to review the change in the prevalence of physical and chemical restraint use in long-term care facilities (LTCFs) over a period of 11 years in Hong Kong and to identify the major factors associated with their use. This is an observational study with data obtained from the Hong Kong Longitudinal Study on LTCF Residents between 2005 and 2015. Trained assessors (nurses, social workers, and therapists) used the Minimum Data Set Resident Assessment Instrument to collect the data from 10 residential LTCFs. Physical restraint was defined as the use of any of the following: full bedside rails on all open sides of bed, other types of bedside rails used, trunk restraint, limb restraint, or the use of chair to prevent rising during the past 7 days. Chemical restraint was defined as the use of any of the following medications: antipsychotic, antianxiety, or hypnotic agents during past 7 days, excluding elder residents with a diagnosis of psychiatric illness. Annual prevalence of restraint use over 11 years and factors that were associated with the use of physical and chemical restraints. We analyzed the data for 2896 older people (978 male individuals, mean age = 83.3 years). Between 2005 and 2015, the prevalence of restraint use was as follows: physical restraint use increased from 52.7% to 70.2%; chemical restraint use increased from 15.9% to 21.78%; and either physical or chemical restraint use increased from 57.9% to 75.7%. Physical restraint use was independently associated with older age, impaired activities of daily living or cognitive function, bowel and bladder incontinence, dementia, and negative mood. Chemical restraint use was independently associated

75 FR 68370 - Agency Information Collection Activities: Office of Infrastructure Protection; Chemical Security...

Science.gov (United States)

2010-11-05

... DEPARTMENT OF HOMELAND SECURITY National Protection and Programs Directorate [Docket No. DHS-2010-0071] Agency Information Collection Activities: Office of Infrastructure Protection; Chemical Security...: The Department of Homeland Security (DHS), National Protection and Programs Directorate (NPPD), Office...

Reactivity of Dual-Use Decontaminants with Chemical Warfare Agents

Science.gov (United States)

2016-07-01

REACTIVITY OF DUAL-USE DECONTAMINANTS WITH CHEMICAL WARFARE AGENTS ECBC-TR-1384... Decontaminants with Chemical Warfare Agents 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) Willis, Matthew P...extraction) of chemical warfare agents from materials. 15. SUBJECT TERMS GD HD Decontamination Hazard mitigation VX Chemical warfare agent Liquid-phase

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 113; Issue 3 ... reaction with methyl vinyl ketone (MVK) and S-proline in the absence of solvents. ... Department of Organic Chemistry, University of Madras, Guindy Campus, Chennai 600 ...

The Effect of Detergent Effluent on the Physico-Chemical ...

African Journals Online (AJOL)

MICHAEL HORSFALL

2Department of Biological Sciences, Federal University of Agriculture, Abeokuta, Nigeria ... KEYWORDS: Physico-chemical characteristics, Osere stream, Plankon and Diversity ... stream is the main sources of water for most domestic.

The understanding of the R7T7 glass blocks long term behavior: chemical and transport coupling in fractured media

International Nuclear Information System (INIS)

Chomat, L.

2008-04-01

The long term behavior of nuclear waste glass blocks depends highly on chemical reactions which occur at the surface in contact with water. Studies carried out on inactive fractured glass blocks show that fracture networks play a significant part in reactive surface area. Nevertheless, the complexity of results interpretation, due to a weak knowledge of fracture networks and local lixiviation conditions, does not allow us to comprehend the physical and chemical mechanisms involved. Model cracks are a key step to study chemical and transport coupling in fractured media. Crack lixiviation in aggressive conditions (pH≥11) show that the crack's position (horizontal or vertical) determines the dominant transport mechanism (respectively diffusion or convection induced by gravity). This gravity driven flow seems to be negligible in lower pH conditions. The convective velocity is estimated by a 1D model of reactive transport. Two other parameters are studied: the influence of thermal gradient and the influence of interconnected cracks on alteration. A strong retroactive effect of convection, due to thermal gradient, on the alteration kinetic is observed inside the crack. These works lead to a complete alteration experiment of a 163 crack network subject to a thermal gradient. The use of the geochemical software, HYTEC, within the framework of this study shows the potential of the software which is however limited by the kinetics law used. (author)

Chemical evolution of galaxies

CERN Document Server

Matteucci, Francesca

2012-01-01

The term “chemical evolution of galaxies” refers to the evolution of abundances of chemical species in galaxies, which is due to nuclear processes occurring in stars and to gas flows into and out of galaxies. This book deals with the chemical evolution of galaxies of all morphological types (ellipticals, spirals and irregulars) and stresses the importance of the star formation histories in determining the properties of stellar populations in different galaxies. The topic is approached in a didactical and logical manner via galaxy evolution models which are compared with observational results obtained in the last two decades: The reader is given an introduction to the concept of chemical abundances and learns about the main stellar populations in our Galaxy as well as about the classification of galaxy types and their main observables. In the core of the book, the construction and solution of chemical evolution models are discussed in detail, followed by descriptions and interpretations of observations of ...

7 CFR 1219.35 - Term of office.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS... years, except the members of the initial Board shall serve terms as follows: Four members and four alternates shall serve for two-year terms; four members and four alternates shall serve for three-year terms...

7 CFR 1207.321 - Term of office.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE POTATO RESEARCH AND PROMOTION PLAN Potato Research and Promotion Plan National Potato Promotion Board § 1207.321 Term of office. (a) The...

7 CFR 1260.142 - Term of office.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE BEEF PROMOTION AND RESEARCH Beef Promotion and Research Order Cattlemen's Beef Promotion and Research Board § 1260.142 Term of office. (a...

30 CFR 75.1101-15 - Construction of dry powder chemical systems.

Science.gov (United States)

2010-07-01

... 30 Mineral Resources 1 2010-07-01 2010-07-01 false Construction of dry powder chemical systems. 75.1101-15 Section 75.1101-15 Mineral Resources MINE SAFETY AND HEALTH ADMINISTRATION, DEPARTMENT OF LABOR...-15 Construction of dry powder chemical systems. (a) Each self-contained dry powder system shall be...

Model tool to describe chemical structures in XML format utilizing structural fragments and chemical ontology.

Science.gov (United States)

Sankar, Punnaivanam; Alain, Krief; Aghila, Gnanasekaran

2010-05-24

We have developed a model structure-editing tool, ChemEd, programmed in JAVA, which allows drawing chemical structures on a graphical user interface (GUI) by selecting appropriate structural fragments defined in a fragment library. The terms representing the structural fragments are organized in fragment ontology to provide a conceptual support. ChemEd describes the chemical structure in an XML document (ChemFul) with rich semantics explicitly encoding the details of the chemical bonding, the hybridization status, and the electron environment around each atom. The document can be further processed through suitable algorithms and with the support of external chemical ontologies to generate understandable reports about the functional groups present in the structure and their specific environment.

Revisiting the chemical reactivity indices as the state function derivatives. The role of classical chemical hardness

Energy Technology Data Exchange (ETDEWEB)

Malek, Ali; Balawender, Robert, E-mail: rbalawender@ichf.edu.pl [Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, PL-01-224 Warsaw (Poland)

2015-02-07

The chemical reactivity indices as the equilibrium state-function derivatives are revisited. They are obtained in terms of the central moments (fluctuation formulas). To analyze the role of the chemical hardness introduced by Pearson [J. Am. Chem. Soc. 105, 7512 (1983)], the relations between the derivatives up to the third-order and the central moments are obtained. As shown, the chemical hardness and the chemical potential are really the principal indices of the chemical reactivity theory. It is clear from the results presented here that the chemical hardness is not the derivative of the Mulliken chemical potential (this means also not the second derivative of the energy at zero-temperature limit). The conventional quadratic dependence of energy, observed at finite temperature, reduces to linear dependence on the electron number at zero-temperature limit. The chemical hardness plays a double role in the admixture of ionic states to the reference neutral state energy: it determines the amplitude of the admixture and regulates the damping of its thermal factor.

Revisiting the chemical reactivity indices as the state function derivatives. The role of classical chemical hardness

International Nuclear Information System (INIS)

Malek, Ali; Balawender, Robert

2015-01-01

The chemical reactivity indices as the equilibrium state-function derivatives are revisited. They are obtained in terms of the central moments (fluctuation formulas). To analyze the role of the chemical hardness introduced by Pearson [J. Am. Chem. Soc. 105, 7512 (1983)], the relations between the derivatives up to the third-order and the central moments are obtained. As shown, the chemical hardness and the chemical potential are really the principal indices of the chemical reactivity theory. It is clear from the results presented here that the chemical hardness is not the derivative of the Mulliken chemical potential (this means also not the second derivative of the energy at zero-temperature limit). The conventional quadratic dependence of energy, observed at finite temperature, reduces to linear dependence on the electron number at zero-temperature limit. The chemical hardness plays a double role in the admixture of ionic states to the reference neutral state energy: it determines the amplitude of the admixture and regulates the damping of its thermal factor

Limits of the comparison between radiological and chemical hazards

International Nuclear Information System (INIS)

Maximilien, R.; Bounolleau, B.

2003-01-01

The primary reason for comparing radiological and chemical hazards is, in the absence of knowledge of similarities between underlying mechanisms, the comparability of the methods used to evaluate their long-term consequences, especially at low doses: carcinogenicity, mutagenicity and effects on reproduction. For radiations, the evaluation is performed above all in terms of risk quantification while for chemicals hazard identification is the main concern. (authors)

46 CFR 153.933 - Chemical protective clothing.

Science.gov (United States)

2010-10-01

... 46 Shipping 5 2010-10-01 2010-10-01 false Chemical protective clothing. 153.933 Section 153.933 Shipping COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) CERTAIN BULK DANGEROUS CARGOES SHIPS... Protective Clothing”, Third Edition, 1987, available from the American Conference of Governmental Industrial...

Scientific Services Department

International Nuclear Information System (INIS)

SSD in the South Western Region employs more than 200 people, of which 90% are scientists or engineers. Their purpose is to understand and clarify the extensive technical issues which arise during the operation of many different types of plant spread over a wide area of Southern England and South Wales. Priority is given to work in terms of its potential value to the Board. This brochure illustrates some aspects of the work of SSD. Based at Regional Headquarters in Bristol, the Department undertakes 'on site' inspection followed by more thorough laboratory examinations for the diagnosis of faults, and carries out selected research activities. Most of this effort is directed towards the three nuclear sites and four large conventional power stations in the Region. (author)

78 FR 3289 - Department Regulatory Agenda; Semiannual Summary

Science.gov (United States)

2013-01-15

... things, this Web site provides a report, updated monthly, on the status of the DOT significant... rulemaking in the Agenda and facilitate tracing further action on the issue; (13) whether the action is... Department's enforcement policy with respect to Web site disclosure of code-share and long term wet lease...

Radiation Dose Measurement Using Chemical Dosimeters

International Nuclear Information System (INIS)

Lee, Min Sun; Kim, Eun Hee; Kim, Yu Ri; Han, Bum Soo

2010-01-01

The radiation dose can be estimated in various ways. Dose estimates can be obtained by either experiment or theoretical analysis. In experiments, radiation impact is assessed by measuring any change caused by energy deposition to the exposed matter, in terms of energy state (physical change), chemical production (chemical change) or biological abnormality (biological change). The chemical dosimetry is based on the implication that the energy deposited to the matter can be inferred from the consequential change in chemical production. The chemical dosimetry usually works on the sample that is an aqueous solution, a biological matter, or an organic substance. In this study, we estimated absorbed doses by quantitating chemical changes in matter caused by radiation exposure. Two different chemical dosimeters, Fricke and ECB (Ethanol-Chlorobenzene) dosimeter, were compared in several features including efficacy as dose indicator and effective dose range

Long-term study of an estuarine mudflat subjected to petro-chemical discharges

International Nuclear Information System (INIS)

McLusky, D.A.; Martins, T.

1998-01-01

The Kinneil intertidal area, situated in the middle reaches of the Forth estuary, eastern Scotland, has been subject to the effects of industrial discharges, principally from petro-chemical industries (oil refinery and chemical works) since the 1920s. The intertidal fauna has been studied annually since 1976 using consistent methodology. The study continues, now providing over 20 yrs of data. During the study period the discharges from the industrial sources have been reduced substantially through a combination of plant closure and modernization and the installation of effluent treatment works. Furthermore, the River Avon which flows across the area has experienced substantial improvements in water quality, attributed to improvements in waste treatment works at localities upstream from the estuarine site. Overall, however, the clearest trends have been increases in diversity, expressed either as mean number of species per station, or as diversity indices. These increases in diversity are shown to be a clear community response to the improvements made to the petro-chemical wastes discharged to the area. (author)

Department of Clinical Investigation Annual Research Progress Report, Fiscal Year 1985,

Science.gov (United States)

1985-10-01

Kolina JS: Infantile Infectious Sacroilitis. Ped Radiology 15(6):403-05, 1985. DEPARTMENT OF SURGERY Publications: * Arciero RA, Shishido NS, Parr...Dependent Diabetic and Chronic Cardiac Disease in Children and Adolescents. National Academy of Neuropsychologists, 17 Oct 85, Philadelphia, PA. DEPARTMENT...Effect of Rapid, Short Term Blood Glucose Control on 100 " #83/37 Leukocyte Function in Diabetic Patients (0) * TREECE, G.L. Treatment of Graves

Is ionizing radiation regulated more stringently than chemical carcinogens

International Nuclear Information System (INIS)

Travis, C.C.; Pack, S.R.; Hattemer-Frey, H.A.

1989-01-01

It is widely believed that United States government agencies regulate exposure to ionizing radiation more stringently than exposure to chemical carcinogens. It is difficult to verify this perception, however, because chemical carcinogens and ionizing radiation are regulated using vastly different strategies. Chemical carcinogens are generally regulated individually. Regulators consider the risk of exposure to one chemical rather than the cumulative radiation exposure from all sources. Moreover, standards for chemical carcinogens are generally set in terms of quantities released or resultant environmental concentrations, while standards for ionizing radiation are set in terms of dose to the human body. Since chemicals and ionizing radiation cannot be compared on the basis of equal dose to the exposed individual, standards regulating chemicals and ionizing radiation cannot be compared directly. It is feasible, however, to compare the two sets of standards on the basis of equal risk to the exposed individual, assuming that standards for chemicals and ionizing radiation are equivalent if estimated risk levels are equitable. This paper compares risk levels associated with current standards for ionizing radiation and chemical carcinogens. The authors do not attempt to determine whether either type of risk is regulated too stringently or not stringently enough but endeavor only to ascertain if ionizing radiation is actually regulated more strictly than chemical carcinogens

Surface chemical problems in coal flotation

Science.gov (United States)

Taylor, S. R.; Miller, K. J.; Deurbrouck, A. W.

1981-02-01

As the use of coal increases and more fine material is produced by mining and processing, the need for improved methods of coal beneficiation increases. While flotation techniques can help meet these needs, the technique is beset with many problems. These problems involve surface chemical and interfacial properties of the coal-mineral-water slurry systems used in coal flotation. The problems associated with coal flotation include non-selectivity, inefficient reagent utilization, and excessive variablity of results. These problems can be broadely classified as a lack of predictability. The present knowledge of coal flotation is not sufficient, in terms of surface chemical parameters, to allow prediction of the flotation response of a given coal. In this paper, some of the surface chemical properties of coal and coal minerals that need to be defined will be discussed in terms of the problems noted above and their impact on coal cleaning.

Consequences of peritonism in an emergency department setting

DEFF Research Database (Denmark)

Bjørsum-Meyer, Thomas; Schmidt, Thomas A.

2013-01-01

Background: In patients who were referred to the emergency department (ED) with abdominal pain, it is crucial to determine the presence of peritonism to allow for appropriate handling and subsequent referral to stationary departments. We aimed to assess the incidence of perceived peritonism...... on the patients with abdominal pain. Following a physical examination, the patients with abdominal pain were divided into those who had clinical signs of peritonism and those who did not. Results: Among the 1,270 patients admitted to the ED, 10% had abdominal pain. In addition, 41% of these patients were found...... to have signs indicative of peritonism, and 90% were admitted to the Department of Surgery (DS). Also, 24% of those patients with signs of peritonism and admission to the DS underwent surgical intervention in terms of laparotomy/laparoscopy. Five of the patients without peritonism underwent surgery...

A gradual change between methanogenesis and sulfidogenesis during a long-term UASB treatment of sulfate-rich chemical wastewater.

Science.gov (United States)

Wu, Jiang; Niu, Qigui; Li, Lu; Hu, Yong; Mribet, Chaimaa; Hojo, Toshimasa; Li, Yu-You

2018-04-25

The competition between methane-producing archaea and sulfate-reducing bacteria is an important topic in anaerobic wastewater treatment. In this study, an Up-flow Anaerobic Sludge Blanket Reactor (UASB) was operated for 330 days to evaluate the treatment performance of sulfate-rich wastewater. The effects of competition change between methane production and sulfate reduction on the organic removal efficiency, methane production, and electrons allocation were investigated. Synthetic wastewater was composed of ethanol and acetate with a chemical oxygen demand (COD)/SO 4 2- of 1.0. As a result, the COD removal efficiency achieved in long-term treatment was higher than 90%. During the initial stage, methane production was the dominant reaction. Sulfate-reducing bacteria (SRB) could only partially oxidize ethanol to acetate, and methane-producing archaea (MPA) utilized acetate for methane production. Methane production declined gradually over the long-term operation, whereas the sulfate-reducing efficiency increased. However, UASB performed well throughout the experiment because there was no significant inhibition. After the complete reduction of the sulfate, MPA converted the remaining COD into methane. Copyright © 2018 Elsevier B.V. All rights reserved.

Changes in the chemical composition of the light crude by short-term weathering

International Nuclear Information System (INIS)

Luo, X.; Ma, Q.M.

2006-01-01

In the event of an oil spill, it is important to unambiguously identify the oil and link it to the known source in order to determine environmental impact and legal liability. The fate and behaviour of spilled oil depends on several physical, chemical and biological factors such as evaporation, dissolution, microbial degradation and photooxidation. The chemical composition of the spilled oil changes with weathering. The changes can have a significant effect on the oil's toxicity and can add to the difficulty of identifying spilled oil. This paper presents the results of changes in chemical composition of light crude oil by weathering under natural environmental conditions. Oil samples were analyzed on a gas chromatograph equipped with a mass selective detector. Light crude oil was obtained from the oil cabin of a tanker which spilled oil near the Dalian Sea near China in April 2005. It was shown that the saturated hydrocarbons of light crude oil distribute between n-C 8 and n-C 23 . The most abundant n-alkanes are found in the n-C 10 to n-C 16 . The main chemical compositions of the light crude oil are the n-alkanes and the isoprenoids. The aromatic compounds are subordinate chemical compositions of the light crude oil. A simulated weathering experiment showed that less than n-C 12 of the n-alkanes, toluene, 1,3-dimethyl benzene is lost after 1 day of weathering. The n-C 13 , n-C 14 , naphthalene and 2-methyl-naphthalene are lost on the fifth day of weathering. N-C 15 alkane composition indicates some weatherproof capability. The ratios of n-C 17 /pristine and n-C 18 /phytane were unchanged and useful in identifying the source of the light crude oil during the first 8-day weathering period. By the twenty-first day of weathering, the chemical composition underwent extreme alteration, and the source of the pollution could not be determined by the ratios of pristine/phytane. 12 refs., 3 tabs., 7 figs

Time series modelling and forecasting of emergency department overcrowding.

Science.gov (United States)

Kadri, Farid; Harrou, Fouzi; Chaabane, Sondès; Tahon, Christian

2014-09-01

Efficient management of patient flow (demand) in emergency departments (EDs) has become an urgent issue for many hospital administrations. Today, more and more attention is being paid to hospital management systems to optimally manage patient flow and to improve management strategies, efficiency and safety in such establishments. To this end, EDs require significant human and material resources, but unfortunately these are limited. Within such a framework, the ability to accurately forecast demand in emergency departments has considerable implications for hospitals to improve resource allocation and strategic planning. The aim of this study was to develop models for forecasting daily attendances at the hospital emergency department in Lille, France. The study demonstrates how time-series analysis can be used to forecast, at least in the short term, demand for emergency services in a hospital emergency department. The forecasts were based on daily patient attendances at the paediatric emergency department in Lille regional hospital centre, France, from January 2012 to December 2012. An autoregressive integrated moving average (ARIMA) method was applied separately to each of the two GEMSA categories and total patient attendances. Time-series analysis was shown to provide a useful, readily available tool for forecasting emergency department demand.

Long-term cloud condensation nuclei number concentration, particle number size distribution and chemical composition measurements at regionally representative observatories

Directory of Open Access Journals (Sweden)

J. Schmale

2018-02-01

Full Text Available Aerosol–cloud interactions (ACI constitute the single largest uncertainty in anthropogenic radiative forcing. To reduce the uncertainties and gain more confidence in the simulation of ACI, models need to be evaluated against observations, in particular against measurements of cloud condensation nuclei (CCN. Here we present a data set – ready to be used for model validation – of long-term observations of CCN number concentrations, particle number size distributions and chemical composition from 12 sites on 3 continents. Studied environments include coastal background, rural background, alpine sites, remote forests and an urban surrounding. Expectedly, CCN characteristics are highly variable across site categories. However, they also vary within them, most strongly in the coastal background group, where CCN number concentrations can vary by up to a factor of 30 within one season. In terms of particle activation behaviour, most continental stations exhibit very similar activation ratios (relative to particles  > 20 nm across the range of 0.1 to 1.0 % supersaturation. At the coastal sites the transition from particles being CCN inactive to becoming CCN active occurs over a wider range of the supersaturation spectrum. Several stations show strong seasonal cycles of CCN number concentrations and particle number size distributions, e.g. at Barrow (Arctic haze in spring, at the alpine stations (stronger influence of polluted boundary layer air masses in summer, the rain forest (wet and dry season or Finokalia (wildfire influence in autumn. The rural background and urban sites exhibit relatively little variability throughout the year, while short-term variability can be high especially at the urban site. The average hygroscopicity parameter, κ, calculated from the chemical composition of submicron particles was highest at the coastal site of Mace Head (0.6 and lowest at the rain forest station ATTO (0.2–0.3. We performed closure

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Author Affiliations. Fang Dong1 Jiang Chenning1 Zhu Ting1 Yang Jinming1. Department of Pharmaceutical Engineering, School of Chemistry and Chemical Engineering, Yancheng Teachers University, 50 Kai Fang Da Dao, Yancheng 224002, Jiangsu, P. R. China ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 119; Issue 5. Controlling dynamics in diatomic systems ... Department of Chemistry, Panjab University, Chandigarh 160 014; Center for Computational Natural Sciences and Bioinformatics, International Institute of Information Technology, Hyderabad 500 032 ...

32 CFR 99.9 - Terms of indemnification.

Science.gov (United States)

2010-07-01

... 32 National Defense 1 2010-07-01 2010-07-01 false Terms of indemnification. 99.9 Section 99.9 National Defense Department of Defense OFFICE OF THE SECRETARY OF DEFENSE PERSONNEL, MILITARY AND CIVILIAN PROCEDURES FOR STATES AND LOCALITIES TO REQUEST INDEMNIFICATION § 99.9 Terms of indemnification. The terms of...

Possible Long Term Effects of Chemical Warfare Using Visual Evoked Potentials

Directory of Open Access Journals (Sweden)

Abbas Riazi

2014-09-01

Full Text Available Some studies have already addressed the effects of occupational organic solvent exposure on the visually evoked potentials (VEPs. Visual system is an important target for Sulphur Mustard (SM toxicity. A number of Iranian victims of Sulphur Mustard (SM agent were apprehensive about the delay effect of SM on their vision and a possible delay effect of SM on their visual cortex. This investigation was performed on 34 individuals with a history of chemical exposure and a control group of 15 normal people. The Toennies electro-diagnosis device was used and its signals were saved as the latencies. The mean of N75, N140 and P100 of victims of chemical warfare (VCWs and control group indicated no significant results (P>0.05. The VCWs did not show any visual symptoms and there was no clear deficit in their VEPs.

Recommended inorganic chemicals for calibration

International Nuclear Information System (INIS)

Moody, J.R.; Greenberg, R.R.; Pratt, K.W.; Rains, T.C.

1988-01-01

All analytical techniques depend on the use of calibration chemicals to relate analyte concentration to an instrumental parameter. A fundamental component in the preparation of calibration solutions is the weighing of a pure chemical or metal before preparing a solution standard. The analyst must be assured that the purity, stoichiometry, and assay of the chemical are known. These terms have different meanings, and each has an important influence. This report is intended to assist the analyst in the selection and use of chemical standards for instrumental calibration. Purity, stoichiometry, and preparation of solutions for different purposes are discussed, and a critical evaluation of the best materials available for each element is presented for use in preparing solutions or calibration standards. Information on the chemical form, source, purity, drying, and appropriate precautions is given. In some cases, multiple sources or chemical forms are available. Certain radioactive elements, the transuranic elements, and the noble gases are not considered

Department of Radiation Detectors: Overview

International Nuclear Information System (INIS)

Piekoszewski, J.

1998-01-01

(full text) Work carried out in 1997 in the Department of Radiation Detectors concentrated on three subjects: (i) Semiconductor Detectors (ii) X-ray Tube Generators (iii) Material Modification using Ion and Plasma Beams. Semiconductor detectors: Semiconductor detectors of ionizing radiation are among the basic tools utilized in such fields of research and industry as nuclear physics, high energy physics, medical (oncology) radiotherapy, radiological protection, environmental monitoring, energy dispersive X-ray fluorescence non-destructive analysis of chemical composition, nuclear power industry. The Department all objectives are: - search for new types of detectors, - adapting modern technologies (especially of industrial microelectronics) to detector manufacturing, - producing unique detectors tailored for physics experiments, - manufacturing standard detectors for radiation measuring instruments, - scientific development of the staff. These 1997 objectives were accomplished particularly by: - research on unique detectors for nuclear physics (e.g. transmission type Si(Li) detectors with extremely thin entrance and exit window), - development of technology of high-resistivity (HRSi) silicon detectors and thermoelectric cooling systems (KBN grant), - study of the applicability of industrial planar technology in producing detectors, - manufacturing detectors developed in previous years, re-generating and servicing customer detectors of various origin. In accomplishing of the above, the Department cooperated with interested groups of physicists from our Institute (P-I and P-II Departments), Warsaw University, Warsaw Heavy Ion Laboratory and with some technology Institutes based in Warsaw (ITME, ITE). Some detectors and services have been delivered to customers on a commercial basis. X-Rat tube generators: The Department conducts research on design and technology of producing X-ray generators based on X-ray tubes of special construction. In 1997, work on a special

7 CFR 2201.19 - Loan terms.

Science.gov (United States)

2010-01-01

... 7 Agriculture 15 2010-01-01 2010-01-01 false Loan terms. 2201.19 Section 2201.19 Agriculture Regulations of the Department of Agriculture (Continued) LOCAL TELEVISION LOAN GUARANTEE BOARD LOCAL TELEVISION LOAN GUARANTEE PROGRAM-PROGRAM REGULATIONS Loan Guarantees § 2201.19 Loan terms. (a) All Loans...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Author Affiliations. Hong-Wen Gao1 Fa-Shui Hong2 Qing-Song Ye2. School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P. R. China; Department of Biological Science, Huaibei Coal Teachers College, Huaibei 235000, P. R. China ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 128; Issue 10 ... using the 6-31G(d,p) basis set reveal a qualitative trend in the relative affinity of ... Department of Chemistry, Indian Institute of Science Education and Research Mohali, ...

78 FR 39337 - Importer of Controlled Substances, Notice of Application, Boehringer Ingelheim Chemicals

Science.gov (United States)

2013-07-01

... DEPARTMENT OF JUSTICE Drug Enforcement Administration Importer of Controlled Substances, Notice of Application, Boehringer Ingelheim Chemicals Pursuant to Title 21 Code of Federal Regulations 1301.34(a), this is notice that on May 31, 2013, Boehringer Ingelheim Chemicals, 2820 N. Normandy Drive, Petersburg...

77 FR 43861 - Importer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals

Science.gov (United States)

2012-07-26

... DEPARTMENT OF JUSTICE Drug Enforcement Administration Importer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals Pursuant to Title 21 Code of Federal Regulations 1301.34(a), this is notice that on June 8, 2012, Boehringer Ingelheim Chemicals, Inc., 2820 N. Normandy Drive...

Research and Applications of Chemical Sciences in Forestry: Proceedings of the 4th Southern Station Chemical Sciences Meeting

Science.gov (United States)

J.A. Vozzo; [Compiler

1994-01-01

This proceedings is the result of 65 scientists representing 34 facilities reported in 28 presentations. As titled, Research and Applications of Chemical Sciences in Forestry, the contributors represent academic, basic, and applied researchers from universities and U.S. Department of Agriculture. Their presence and experience represent a significant showing toward...

Measuring the efficiency of dental departments in medical centers: a nonparametric analysis approach.

Science.gov (United States)

Wang, Su-Chen; Tsai, Chi-Cheng; Huang, Shun-Te; Hong, Yu-Jue

2002-12-01

Data envelopment analysis (DEA), a cross-sectional study design based on secondary data analysis, was used to evaluate the relative operational efficiency of 16 dental departments in medical centers in Taiwan in 1999. The results indicated that 68.7% of all dental departments in medical centers had poor performance in terms of overall efficiency and scale efficiency. All relatively efficient dental departments were in private medical centers. Half of these dental departments were unable to fully utilize available medical resources. 75.0% of public medical centers did not take full advantage of medical resources at their disposal. In the returns to scale, 56.3% of dental departments in medical centers exhibited increasing returns to scale, due to the insufficient scale influencing overall hospital operational efficiency. Public medical centers accounted for 77.8% of the institutions affected. The scale of dental departments in private medical centers was more appropriate than those in public medical centers. In the sensitivity analysis, the numbers of residents, interns, and published papers were used to assess teaching and research. Greater emphasis on teaching and research in medical centers has a large effect on the relative inefficiency of hospital operation. Dental departments in private medical centers had a higher mean overall efficiency score than those in public medical centers, and the overall efficiency of dental departments in non-university hospitals was greater than those in university hospitals. There was no information to evaluate the long-term efficiency of each dental department in all hospitals. A different combination of input and output variables, using common multipliers for efficiency value measurements in DEA, may help establish different pioneering dental departments in hospitals.

Chemical dependency and adolescent self-esteem.

Science.gov (United States)

Wasson, D; Anderson, M A

1995-08-01

The purpose of this descriptive study is to determine whether self-esteem differs between chemically dependent adolescents and adolescents from the general high school population. The Self-Esteem Inventory (Coopersmith, 1987) was completed by 119 adolescents (31 inpatient, 31 aftercare, and 57 general high school students) aged 13 to 18. Findings suggest that inpatient, chemically dependent adolescents have lower self-esteem than the other two groups. For the chemically dependent adolescent, nursing case management with communication among and between health care providers, school professionals, and family may facilitate successful, long-term recovery. For adolescents at risk for development of chemical dependence, nursing health promotion behaviors, such as early assessment and implementation of self-esteem-building activities, may assist in prevention of chemical dependency.

Collectively Improving Our Teaching: Attempting Biology Department-Wide Professional Development in Scientific Teaching

Science.gov (United States)

Owens, Melinda T.; Trujillo, Gloriana; Seidel, Shannon B.; Harrison, Colin D.; Farrar, Katherine M.; Benton, Hilary P.; Blair, J. R.; Boyer, Katharyn E.; Breckler, Jennifer L.; Burrus, Laura W.; Byrd, Dana T.; Caporale, Natalia; Carpenter, Edward J.; Chan, Yee-Hung M.; Chen, Joseph C.; Chen, Lily; Chen, Linda H.; Chu, Diana S.; Cochlan, William P.; Crook, Robyn J.; Crow, Karen D.; de la Torre, José R.; Denetclaw, Wilfred F.; Dowdy, Lynne M.; Franklin, Darleen; Fuse, Megumi; Goldman, Michael A.; Govindan, Brinda; Green, Michael; Harris, Holly E.; He, Zheng-Hui; Ingalls, Stephen B.; Ingmire, Peter; Johnson, Amber R. B.; Knight, Jonathan D.; LeBuhn, Gretchen; Light, Terrye L.; Low, Candace; Lund, Lance; Márquez-Magaña, Leticia M.; Miller-Sims, Vanessa C.; Moffatt, Christopher A.; Murdock, Heather; Nusse, Gloria L.; Parker, V. Thomas; Pasion, Sally G.; Patterson, Robert; Pennings, Pleuni S.; Ramirez, Julio C.; Ramirez, Robert M.; Riggs, Blake; Rohlfs, Rori V.; Romeo, Joseph M.; Rothman, Barry S.; Roy, Scott W.; Russo-Tait, Tatiane; Sehgal, Ravinder N. M.; Simonin, Kevin A.; Spicer, Greg S.; Stillman, Jonathon H.; Swei, Andrea; Timpe, Leslie C.; Vredenburg, Vance T.; Weinstein, Steven L.; Zink, Andrew G.; Kelley, Loretta A.; Domingo, Carmen R.; Tanner, Kimberly D.

2018-01-01

Many efforts to improve science teaching in higher education focus on a few faculty members at an institution at a time, with limited published evidence on attempts to engage faculty across entire departments. We created a long-term, department-wide collaborative professional development program, Biology Faculty Explorations in Scientific Teaching…

The role of BNDES' Energy Department (DEENE) on natural gas area

International Nuclear Information System (INIS)

Drummond, P.H.; Abreu Filho, J. de

1988-01-01

This work describes the activities of BNDES' Energy Department (DEENE) as the main financing agent of the brazilian energy sector, with particular emphasis on natural gas - which has not played an important role yet, despite DEENE's disposition and expectancy in participating of projects in this area. The work also outlines the department's plan at short and medium term concerning natural gas, and presents the Bank's financing conditions to this sector. (author)

76 FR 68809 - Bureau of International Security and Nonproliferation; Termination of Chemical and Biological...

Science.gov (United States)

2011-11-07

..., Office of Missile, Biological, and Chemical Nonproliferation, Bureau of International Security and... DEPARTMENT OF STATE [Public Notice: 7678] Bureau of International Security and Nonproliferation; Termination of Chemical and Biological Weapons (CBW) Proliferation Sanctions Against a Foreign Person AGENCY...

Intentional and unintentional poisoning in Pakistan: a pilot study using the Emergency Departments surveillance project.

Science.gov (United States)

Khan, Nadeem; Pérez-Núñez, Ricardo; Shamim, Nudrat; Khan, Uzma; Naseer, Naureen; Feroze, Asher; Razzak, Junaid; Hyder, Adnan A

2015-01-01

Acute poisoning is one of the most common reasons for emergency department visits around the world. In Pakistan, the epidemiological data on poisoning is limited due to an under developed poison information surveillance system. We aim to describe the characteristics associated with intentional and unintentional poisoning in Pakistan presenting to emergency departments. The data was extracted from the Pakistan National Emergency Department Surveillance (Pak-NEDS) which was an active surveillance conducted between November 2010 and March 2011. All patients, regardless of age, who presented with poisoning to any of Pakistan's seven major tertiary care centers' emergency departments, were included. Information about patient demographics, type of poisoning agent, reason for poisoning and outcomes were collected using a standard questionnaire. Acute poisoning contributed to 1.2% (n = 233) of patients with intentional and unintentional injuries presenting to EDs of participating centers. Of these, 68% were male, 54% were aged 19 to 44 and 19% were children and adolescents (<18 years). Types of poisoning included chemical/gas (43.8%), drug/medicine (27%), alcohol (16.7%) and food/plant (6%). In half of all patients the poisoning was intentional. A total of 11.6% of the patients were admitted and 6.6% died. Poisoning causes more morbidity and mortality in young adults in Pakistan compared to other age groups, half of which is intentional. Improving mental health, regulatory control for hazardous chemicals and better access to care through poison information centers and emergency departments will potentially help control the problem.

Conception and syllabus on radiochemistry and radioecology principles for general student groups of a university chemical department

International Nuclear Information System (INIS)

Bogdanov, R.V.

1994-01-01

The problem of basic principles of selecting materials for general courses on diverse subjects in chemical science is discussed. Relying on certain general rules and proceeding from specificity of radiochemistry, the author suggests a variant of syllabus including radiochemical and radioecological blocks intented for 48 academic hours. In methodical respect emphasis is made on theoretical material presentation in close combination with various nuclear methods used in chemical studies. 6 refs., 1 fig

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 112; Issue 3. Steric control of the coordination mode of thiosemicarbazone ligands, synthesis, structure ... Author Affiliations. Falguni Basuli1 Samaresh Bhattacharya1. Department of Chemistry, Inorganic Chemistry Section, Jadavpur University, Calcutta 700 032, India ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

... Kathmandu, Nepal; Department of Inorganic and Physical Chemistry, Indian Institute of Science, Bengaluru 560012, India. Dates. Manuscript received: 9 October 2014; Manuscript revised: 31 January 2015; Accepted: 3 February 2015. Supplementary Material. supp7.doc. Journal of Chemical Sciences. Current Issue : Vol.

Curriculum Assessment as a Direct Tool in ABET Outcomes Assessment in a Chemical Engineering Programme

Science.gov (United States)

Abu-Jdayil, Basim; Al-Attar, Hazim

2010-01-01

The chemical engineering programme at the United Arab Emirates University is designed to fulfil the Accreditation Board for Engineering and Technology (ABET) (A-K) EC2000 criteria. The Department of Chemical & Petroleum Engineering has established a well-defined process for outcomes assessment for the chemical engineering programme in order to…

Efficacy of a tool to predict short-term mortality in older people presenting at emergency departments: Protocol for a multi-centre cohort study.

Science.gov (United States)

Cardona, Magnolia; Lewis, Ebony T; Turner, Robin M; Alkhouri, Hatem; Asha, Stephen; Mackenzie, John; Perkins, Margaret; Suri, Sam; Holdgate, Anna; Winoto, Luis; Chang, Chan-Wei; Gallego-Luxan, Blanca; McCarthy, Sally; Kristensen, Mette R; O'Sullivan, Michael; Skjøt-Arkil, Helene; Ekmann, Anette A; Nygaard, Hanne H; Jensen, Jonas J; Jensen, Rune O; Pedersen, Jonas L; Breen, Dorothy; Petersen, John A; Jensen, Birgitte N; Mogensen, Christian Backer; Hillman, Ken; Brabrand, Mikkel

Prognostic uncertainty inhibits clinicians from initiating timely end-of-life discussions and advance care planning. This study evaluates the efficacy of the CriSTAL (Criteria for Screening and Triaging to Appropriate aLternative care) checklist in emergency departments. Prospective cohort study of patients aged ≥65 years with any diagnosis admitted via emergency departments in ten hospitals in Australia, Denmark and Ireland. Electronic and paper clinical records will be used to extract risk factors such as nursing home residency, physiological deterioration warranting a rapid response call, personal history of active chronic disease, history of hospitalisations or intensive care unit admission in the past year, evidence of proteinuria or ECG abnormalities, and evidence of frailty to be concurrently measured with Fried Score and Clinical Frailty Scale. Patients or their informal caregivers will be contacted by telephone around three months after initial assessment to ascertain survival, self-reported health, post-discharge frailty and health service utilisation since discharge. Logistic regression and bootstrapping techniques and AUROC curves will be used to test the predictive accuracy of CriSTAL for death within 90 days of admission and in-hospital death. The CriSTAL checklist is an objective and practical tool for use in emergency departments among older patients to determine individual probability of death in the short-term. Its validation in this cohort is expected to reduce clinicians' prognostic uncertainty on the time to patients' death and encourage timely end-of-life conversations to support clinical decisions with older frail patients and their families about their imminent or future care choices. Copyright © 2018 Elsevier B.V. All rights reserved.

Volume 10 No. 2 February 2010 2124 CHEMICAL COMPOSITION ...

African Journals Online (AJOL)

2010-02-02

Feb 2, 2010 ... Dept of Food Science and Post Harvest Technology, University of Hawassa, Ethiopia. 2. Department of Chemical ... Wine is an alcoholic beverage produced by the fermentation of the ..... Management, 2nd edition. Gaitherburg ...

Long-term manure amendments and chemical fertilizers enhanced soil organic carbon sequestration in a wheat (Triticum aestivum L.)-maize (Zea mays L.) rotation system.

Science.gov (United States)

Zhang, Shuiqing; Huang, Shaomin; Li, Jianwei; Guo, Doudou; Lin, Shan; Lu, Guoan

2017-06-01

The carbon sequestration potential is affected by cropping system and management practices, but soil organic carbon (SOC) sequestration potential under fertilizations remains unclear in north China. This study examined SOC change, total C input to soil and, via integration of these estimates over years, carbon sequestration efficiency (CSE, the ratio of SOC change over C input) under no fertilization (control), chemical nitrogen fertilizer alone (N) or combined with phosphorus and potassium fertilizers (NP, NK, PK and NPK), or chemical fertilizers combined with low or high (1.5×) manure input (NPKM and 1.5NPKM). Results showed that, as compared with the initial condition, SOC content increased by 0.03, 0.06, 0.05, 0.09, 0.16, 0.26, 0.47 and 0.68 Mg C ha -1 year -1 under control, N, NK, PK, NP, NPK, NPKM and 1.5NPKM treatments respectively. Correspondingly, the C inputs of wheat and maize were 1.24, 1.34, 1.55, 1.33, 2.72, 2.96, 2.97 and 3.15 Mg ha -1 year -1 respectively. The long-term fertilization-induced CSE showed that about 11% of the gross C input was transformed into SOC pool. Overall, this study demonstrated that decade-long manure input combined with chemical fertilizers can maintain high crop yield and lead to SOC sequestration in north China. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

Accident simulation in a chemical process facility at the Savannah River Site

International Nuclear Information System (INIS)

Hope, E.P.

1993-01-01

The US Department of Energy requires Westinghouse Savannah River Company to safely operate the chemical separations facilities at the Savannah River Site (SRS). As part of the safety analysis program, simulation of a proposed frame waste recovery (FWR) system is needed to determine the possible accident consequences that may affect public safety. This paper details the simulation process for the proposed frame waste recovery process and describes the analytical tools used in order to make estimates of accident consequences. Since the process in question has been operated, historical data and statistics about its operation are available. Software tools have been developed to allow analysis of the frame waste recovery system, including the generation of system specific dose conversion factors for a number of unique situations. Accident scenarios involving spilled liquid material are analyzed and account for the specific floor geometry of the facility. Confinement and filtration systems are considered. Analysis of source terms is a limiting factor which affects the entire evaluation process. In the past, facility source terms were generally constant with occasional variations from established patterns. As new site missions unfold, significant variations in source terms can be expected. The impact of these variations on the safety analysis is discussed

Assessment of Chemical and Radiological Vulnerabilities

International Nuclear Information System (INIS)

SETH, S.S.

2000-01-01

Following the May 14, 1997 chemical explosion at Hanford's Plutonium Reclamation Facility, the Department of Energy Richland Operations Office and its prime contractor, Fluor Hanford, Inc., completed an extensive assessment to identify and address chemical and radiological safety vulnerabilities at all facilities under the Project Hanford Management Contract. This was a challenging undertaking because of the immense size of the problem, unique technical issues, and competing priorities. This paper focuses on the assessment process, including the criteria and methodology for data collection, evaluation, and risk-based scoring. It does not provide details on the facility-specific results and corrective actions, but discusses the approach taken to address the identified vulnerabilities

Risk Assessment and Management for Long-Term Storage of CO2 in Geologic Formations — United States Department of Energy R&D

Directory of Open Access Journals (Sweden)

Dawn Deel

2007-02-01

Full Text Available Concern about increasing atmospheric concentrations of carbon dioxide (CO2 and other greenhouse gases (GHG and their impact on the earth's climate has grown significantly over the last decade. Many countries, including the United States, wrestle with balancing economic development and meeting critical near-term environmental goals while minimizing long-term environmental risks. One promising solution to the buildup of GHGs in the atmosphere, being pursued by the U.S. Department of Energy's (DOE National Energy Technology Laboratory (NETL and its industrial and academic partners, is carbon sequestration—a process of permanent storage of CO2 emissions in underground geologic formations, thus avoiding CO2 release to the atmosphere. This option looks particularly attractive for point source emissions of GHGs, such as fossil fuel fired power plants. CO2 would be captured, transported to a sequestration site, and injected into an appropriate geologic formation. However, sequestration in geologic formations cannot achieve a significant role in reducing GHG emissions unless it is acceptable to stakeholders, regulators, and the general public, i.e., unless the risks involved are judged to be acceptable. One tool that can be used to achieve acceptance of geologic sequestration of CO2 is risk assessment, which is a proven method to objectively manage hazards in facilities such as oil and natural gas fields, pipelines, refineries, and chemical plants. Although probabilistic risk assessment (PRA has been applied in many areas, its application to geologic CO2 sequestration is still in its infancy. The most significant risk from geologic carbon sequestration is leakage of CO2. Two types of CO2 releases are possible—atmospheric and subsurface. High concentrations of CO2 caused by a release to the atmosphere would pose health risks to humans and animals, and any leakage of CO2 back into the atmosphere negates the effort expended to sequester the CO2

More Thoughts about Names in Nursing: Colleges, Schools, Divisions, Departments, and Journals.

Science.gov (United States)

Fawcett, Jacqueline

2016-01-01

This essay addresses the names used for nursing academic units and journals. Discussion focuses on questions about nursing (or nursology) as a health profession and the redundancy of combining the term, nursing, with terms about health used by many colleges, schools, divisions, and departments, as well as by some journals. © The Author(s) 2015.

Short-term versus long-term contracting for uranium enrichment services

International Nuclear Information System (INIS)

Rudy, G.P.

1990-01-01

The US Department of Energy (US DOE) is the world's largest and most experienced supplier of uranium enrichment services. Through the late 1970s and early 1980s, emerging market forces transformed what was once a monopoly into a highly competitive industry. In the early 1980's the DOE lost market share. But as we enter the 1990s, new market forces have emerged. The US DOE believes a responsible balance between long-term and short-term contracting will be the key to success and the key to assuring the long-term health and reliability of the nuclear fuel industry. The US DOE intends to be in this nuclear business for a long time and will continue to offer reliable and responsive services second to none

Long-Term Stewardship Program Science and Technology Requirements

Energy Technology Data Exchange (ETDEWEB)

Joan McDonald

2002-09-01

Many of the United States’ hazardous and radioactively contaminated waste sites will not be sufficiently remediated to allow unrestricted land use because funding and technology limitations preclude cleanup to pristine conditions. This means that after cleanup is completed, the Department of Energy will have long-term stewardship responsibilities to monitor and safeguard more than 100 sites that still contain residual contamination. Long-term stewardship encompasses all physical and institutional controls, institutions, information, and other mechanisms required to protect human health and the environment from the hazards remaining. The Department of Energy Long-Term Stewardship National Program is in the early stages of development, so considerable planning is still required to identify all the specific roles and responsibilities, policies, and activities needed over the next few years to support the program’s mission. The Idaho National Engineering and Environmental Laboratory was tasked with leading the development of Science and Technology within the Long-Term Stewardship National Program. As part of that role, a task was undertaken to identify the existing science and technology related requirements, identify gaps and conflicts that exist, and make recommendations to the Department of Energy for future requirements related to science and technology requirements for long-term stewardship. This work is summarized in this document.

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

... XIONG1 WEIHUA ZHU1 HEMING XIAO1. Institute for Computation in Molecular and Materials Science and Department of Chemistry, School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China; School of Materials Science and Engineering, Nanjing Institute of Technology, ...

75 FR 2445 - Chemical Facility Anti-Terrorism Standards

Science.gov (United States)

2010-01-15

... include trade secrets, confidential commercial information, Chemical-terrorism Vulnerability Information... and submit an online data collection (the Top-Screen) to DHS. The Department uses the facility's Top... required to submit Top-Screens. See 72 FR 65397-65398. \\2\\ Among other things, the November 2007 rule...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Keywords. Hardness; softness; hard & soft acids bases (HSAB); principle of maximum hardness (PMH) density functional theory (DFT). Abstract. The concept of chemical hardness is reviewed from a personal point of view. Author Affiliations. Ralph G Pearson1. Chemistry Department, University of California, Santa Barbara, ...

Chemical process hazards analysis

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-02-01

The Office of Worker Health and Safety (EH-5) under the Assistant Secretary for the Environment, Safety and Health of the US Department (DOE) has published two handbooks for use by DOE contractors managing facilities and processes covered by the Occupational Safety and Health Administration (OSHA) Rule for Process Safety Management of Highly Hazardous Chemicals (29 CFR 1910.119), herein referred to as the PSM Rule. The PSM Rule contains an integrated set of chemical process safety management elements designed to prevent chemical releases that can lead to catastrophic fires, explosions, or toxic exposures. The purpose of the two handbooks, ``Process Safety Management for Highly Hazardous Chemicals`` and ``Chemical Process Hazards Analysis,`` is to facilitate implementation of the provisions of the PSM Rule within the DOE. The purpose of this handbook ``Chemical Process Hazards Analysis,`` is to facilitate, within the DOE, the performance of chemical process hazards analyses (PrHAs) as required under the PSM Rule. It provides basic information for the performance of PrHAs, and should not be considered a complete resource on PrHA methods. Likewise, to determine if a facility is covered by the PSM rule, the reader should refer to the handbook, ``Process Safety Management for Highly Hazardous Chemicals`` (DOE- HDBK-1101-96). Promulgation of the PSM Rule has heightened the awareness of chemical safety management issues within the DOE. This handbook is intended for use by DOE facilities and processes covered by the PSM rule to facilitate contractor implementation of the PrHA element of the PSM Rule. However, contractors whose facilities and processes not covered by the PSM Rule may also use this handbook as a basis for conducting process hazards analyses as part of their good management practices. This handbook explains the minimum requirements for PrHAs outlined in the PSM Rule. Nowhere have requirements been added beyond what is specifically required by the rule.

Teaching Chemical Equilibrium with the Jigsaw Technique

Science.gov (United States)

Doymus, Kemal

2008-01-01

This study investigates the effect of cooperative learning (jigsaw) versus individual learning methods on students' understanding of chemical equilibrium in a first-year general chemistry course. This study was carried out in two different classes in the department of primary science education during the 2005-2006 academic year. One of the classes…

77 FR 43863 - Manufacturer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals Inc.

Science.gov (United States)

2012-07-26

... DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals Inc. Pursuant to Sec. 1301.33(a), Title 21 of the Code of Federal Regulations (CFR), this is notice that on June 8, 2012, Boehringer Ingelheim Chemicals...

78 FR 39340 - Manufacturer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals, Inc.

Science.gov (United States)

2013-07-01

... DEPARTMENT OF JUSTICE Drug Enforcement Administration Manufacturer of Controlled Substances; Notice of Application; Boehringer Ingelheim Chemicals, Inc. Pursuant to Sec. 1301.33(a), Title 21 of the Code of Federal Regulations (CFR), this is notice that on May 31, 2013, Boehringer Ingelheim Chemicals...

Assessment of chemical loadings to Newark Bay, New Jersey from petroleum and hazardous chemical accidents occurring from 1986 to 1991

International Nuclear Information System (INIS)

Gunster, D.G.; Bonnevie, N.L.; Gillis, C.A.; Wenning, R.J.

1993-01-01

Newark Bay, New Jersey, is particularly vulnerable to ecological damage from accidental petroleum and chemical spills due to the enclosed nature of the bay and the large volume of chemical and petroleum commerce within the region. A review of the New Jersey Department of Environmental Protection and Energy's database of hazardous chemical spills in New Jersey waterways was conducted to determine the frequency and volume of chemical and petroleum spills in Newark Bay and its major tributaries. Accidents reported from 1986 to 1991 were extracted from the database and summarized. The compilation of records indicated that 1400 incidents, resulting in the release of more than 18 million gallons of hazardous materials to the estuary had been reported to state officials. The bulk of the chemicals released to the aquatic environment were petroleum products, specifically No. 2 Fuel Oil (4,636,512 gallons) and No. 6 Fuel Oil (12,600,683 gallons). The majority of the reported incidents occurred in the Arthur Kill and its tributaries. The results indicate that accidental discharge of petroleum and other hazardous chemicals to Newark Bay represents a significant ongoing source of chemical pollution

The Influence of Physico-Chemical and Ecological Factors on the ...

African Journals Online (AJOL)

Dell-User

Nigerian Journal of Chemical Research. Vol. 18, 2013 ... 1Department of Applied Science, College of Science and Technology, Kaduna Polytechnic, Kaduna. ... considered to affect the ecology of ... mapped with a handheld global positioning.

7 CFR 1221.104 - Term of office.

Science.gov (United States)

2010-01-01

... Regulations of the Department of Agriculture (Continued) AGRICULTURAL MARKETING SERVICE (MARKETING AGREEMENTS... INFORMATION ORDER Sorghum Promotion, Research, and Information Order Sorghum Promotion, Research, and Information Board § 1221.104 Term of office. (a) The term of office for the representatives of the Board shall...

Chemicals in material cycles

DEFF Research Database (Denmark)

Pivnenko, Kostyantyn; Eriksson, Eva; Astrup, Thomas Fruergaard

2015-01-01

Material recycling has been found beneficial in terms of resource and energy performance and is greatly promoted throughout the world. A variety of chemicals is used in materials as additives and data on their presence is sparse. The present work dealt with paper as recyclable material and diisob...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Author Affiliations. P Natarajan1 P Paul1 2 T Dhanasekaran1 H Prakash1. Department of Inorganic Chemistry and National Centre for Ultrafast Processes, University of Madras, Chennai 600 025, India; Catalysis Division, Central Salt and Marine Chemicals Research Institute, Bhavnagar 364 002, India ...

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

Home; Journals; Journal of Chemical Sciences; Volume 128; Issue 1 ... Ruthenium(II) complexes (1-3) bearing bis-phenolate--heterocyclic carbene ligand were synthesized in good yields by the reaction of imidazolinium proligand (HL) with ... Department of Chemistry, Periyar University, Salem 636 011, Tamil Nadu, India ...

Annual progress report of the Department of Solid State Physics 1 January - 31 December 1993

International Nuclear Information System (INIS)

Skov Pedersen, J.; Almdal, K.; Feidenhans'l, R.; Clausen, K.N.; Bechgaard, K.

1994-01-01

Research in the department is concerned with ''Materials with Distinct Physical and Chemical Properties''. The principal activities of the department in the period from 1 January, to 31 December, 1993, are presented in this Progress Report. Neutrons and X-ray diffraction techniques are used to study a wide variety of problems in condensed matter physics and include: two- and three-dimensional structures, magnetic ordering, heavy fermions, high T c superconductivity, phase transitions in model systems, precipitation phenomena, and nanoscale structures in various materials. The research in chemistry includes chemical synthesis and physico-chemical investigations of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface modified polymers, and supramolecular structures. This report is organized in 13 categories with the following headings: Theory, Monte Carlo simulations, and methods of data analysis. Magnetic structures, magnetic phase transitions, and spin dynamics. High T c superconductivity. Structures and structural phase transitions. Inclusions and precipitates in alloys and metals. Interaction of particles and photons with surfaces. Surfaces, interfaces, and amorphous structures. Langmuir films. Polymers. Molecular science. Microemulsions and biological systems. Instrument developments. Other activities. (au) (4 tabs., 109 ills., 168 refs.)

Mesotherapy, Microneedling, and Chemical Peels.

Science.gov (United States)

Lee, Johnson C; Daniels, Mark A; Roth, Malcolm Z

2016-07-01

Mesotherapy, microneedling, and chemical peels are minimally invasive techniques used to combat facial aging. Chemical peeling is one of the oldest methods of facial rejuvenation. By using different chemicals in various combinations, strengths, and application techniques, plastic surgeons can tailor a patient's treatment for optimal, safe, and consistent results. Mesotherapy and microneedling have emerged in the plastic surgery literature with increasingly complex indications. Both techniques have increased in popularity although research into efficacy and long-term results is lagging. With a thorough understanding of patients and the modalities available, plastic surgeons can use the appropriate minimally invasive technique to provide patients with desired skin changes. Copyright © 2016 Elsevier Inc. All rights reserved.

Photomixotrophic chemical production in cyanobacteria.

Science.gov (United States)

Matson, Morgan M; Atsumi, Shota

2018-04-01

The current global dependence on fossil fuels for both energy and chemical production has spurred concerns regarding long-term resource security and environmental detriments resulting from increased CO 2 levels. Through the installation of exogenous metabolic pathways, engineered cyanobacteria strains can directly fix CO 2 into industrially relevant chemicals currently produced from petroleum. This review highlights some of the studies that have successfully implemented photomixotrophic conditions to increase cyanobacterial chemical production. Supplementation with fixed carbon sources provides additional carbon building blocks and energy to enhance production and occasionally aid in growth. Photomixotrophic production has increased titers up to 5-fold over traditional autotrophic conditions, demonstrating promising applications for future commercialization. Copyright © 2017 Elsevier Ltd. All rights reserved.

Chemical and benthos data collected from CTD, bottle, and other instruments in the Chukchi Sea in 2009-2010 as part of the Chukchi Sea Offshore Monitoring in Drilling Area - Chemical and Benthos (COMIDA-CAB) project (NODC Accession 0095566)

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — This accession contains physical, chemical, and biological data collected during research cruises for the Chukchi Sea Offshore Monitoring in Drilling Area (Chemical...

[Managing the discharge of diabetic patients from the emergency department: a consensus paper].

Science.gov (United States)

Cuervo Pinto, Rafael; Álvarez-Rodríguez, Esther; González Pérez de Villar, Noemí; Artola-Menéndez, Sara; Girbés Borrás, Juan; Mata-Cases, Manel; Galindo Rubio, Mercedes; Puig Larrosa, Juan; Muñoz Albert, Ricardo; Díaz Pérez, José Ángel

2017-10-01

Eighty to 90% of patients attended in emergency departments are discharged to home. Emergency department physicians are therefore responsible for specifying how these patients are treated afterwards. An estimated 30% to 40% of emergency patients have diabetes mellitus that was often decompensated or poorly controlled prior to the emergency. It is therefore necessary to establish antidiabetic treatment protocols that contribute to adequate metabolic control for these patients in the interest of improving the short-term prognosis after discharge. The protocols should also maintain continuity of outpatient care from other specialists and contribute to improving the long-term prognosis. This consensus paper presents the consensus of experts from 3 medical associations whose members are directly involved with treating patients with diabetes. The aim of the paper is to facilitate the assessment of antidiabetic treatment when the patient is discharged from the emergency department and referred to outpatient care teams.

The Frontlines of Medicine Project: a proposal for the standardized communication of emergency department data for public health uses including syndromic surveillance for biological and chemical terrorism.

Science.gov (United States)

Barthell, Edward N; Cordell, William H; Moorhead, John C; Handler, Jonathan; Feied, Craig; Smith, Mark S; Cochrane, Dennis G; Felton, Christopher W; Collins, Michael A

2002-04-01

The Frontlines of Medicine Project is a collaborative effort of emergency medicine (including emergency medical services and clinical toxicology), public health, emergency government, law enforcement, and informatics. This collaboration proposes to develop a nonproprietary, "open systems" approach for reporting emergency department patient data. The common element is a standard approach to sending messages from individual EDs to regional oversight entities that could then analyze the data received. ED encounter data could be used for various public health initiatives, including syndromic surveillance for chemical and biological terrorism. The interlinking of these regional systems could also permit public health surveillance at a national level based on ED patient encounter data. Advancements in the Internet and Web-based technologies could allow the deployment of these standardized tools in a rapid time frame.

Approaches to chemical synthetic biology.

Science.gov (United States)

Chiarabelli, Cristiano; Stano, Pasquale; Anella, Fabrizio; Carrara, Paolo; Luisi, Pier Luigi

2012-07-16

Synthetic biology is first represented in terms of two complementary aspects, the bio-engineering one, based on the genetic manipulation of extant microbial forms in order to obtain forms of life which do not exist in nature; and the chemical synthetic biology, an approach mostly based on chemical manipulation for the laboratory synthesis of biological structures that do not exist in nature. The paper is mostly devoted to shortly review chemical synthetic biology projects currently carried out in our laboratory. In particular, we describe: the minimal cell project, then the "Never Born Proteins" and lastly the Never Born RNAs. We describe and critically analyze the main results, emphasizing the possible relevance of chemical synthetic biology for the progress in basic science and biotechnology. Copyright © 2012 Federation of European Biochemical Societies. Published by Elsevier B.V. All rights reserved.

Department of Radiation Detectors - Overview

International Nuclear Information System (INIS)

Piekoszewski, J.

1997-01-01

Work carried out in 1996 in the Department of Radiation Detectors concentrated on three subjects: (i) Semiconductor Detectors (ii) X-ray Tube Generators (iii) Material Modification Using Ion and Plasma Beams. The Departamental objectives are: a search for new types of detectors, adapting modern technologies (especially of industrial microelectronics) to detector manufacturing, producing unique detectors tailored for physics experiments, manufacturing standard detectors for radiation measuring instruments. These objectives were accomplished in 1996 by: research on unique detectors for nuclear physics (e.g. a spherical set of particle detectors silicon ball), detectors for particle identification), development of technology of high-resistivity silicon detectors HRSi (grant proposal), development of thermoelectric cooling systems (grant proposal), research on p-i-n photodiode-based personal dosimeters, study of applicability of industrial planar technology in producing detectors, manufacturing detectors developed in previous years, re-generating and servicing customer detectors of various origin. The Department conducts research on the design and technology involved in producing X-ray generators based on X-ray tubes of special construction. Various tube models and their power supplies were developed. Some work has also been devoted to the detection and dosimetry of X-rays. X-ray tube generators are applied to non-destructive testing and are components of analytical systems such as: X-ray fluorescence chemical composition analysis, gauges of layer thickness and composition stress measurements, on-line control of processes, others where an X-ray tube may replace a radio-isotope source. In 1996, the Department: reviewed the domestic demand for X-ray generators, developed an X-ray generator for diagnosis of ostheroporosis of human limbs, prepared a grant proposal for the development of a new instrument for radiotherapy, the so-called needle-like X-ray tube. (author)

Department of Radiation Detectors - Overview

Energy Technology Data Exchange (ETDEWEB)

Piekoszewski, J. [Soltan Inst. for Nuclear Studies, Otwock-Swierk (Poland)

1997-12-31

Work carried out in 1996 in the Department of Radiation Detectors concentrated on three subjects: (i) Semiconductor Detectors (ii) X-ray Tube Generators (iii) Material Modification Using Ion and Plasma Beams. The Departamental objectives are: a search for new types of detectors, adapting modern technologies (especially of industrial microelectronics) to detector manufacturing, producing unique detectors tailored for physics experiments, manufacturing standard detectors for radiation measuring instruments. These objectives were accomplished in 1996 by: research on unique detectors for nuclear physics (e.g. a spherical set of particle detectors silicon ball), detectors for particle identification), development of technology of high-resistivity silicon detectors HRSi (grant proposal), development of thermoelectric cooling systems (grant proposal), research on p-i-n photodiode-based personal dosimeters, study of applicability of industrial planar technology in producing detectors, manufacturing detectors developed in previous years, re-generating and servicing customer detectors of various origin. The Department conducts research on the design and technology involved in producing X-ray generators based on X-ray tubes of special construction. Various tube models and their power supplies were developed. Some work has also been devoted to the detection and dosimetry of X-rays. X-ray tube generators are applied to non-destructive testing and are components of analytical systems such as: X-ray fluorescence chemical composition analysis, gauges of layer thickness and composition stress measurements, on-line control of processes, others where an X-ray tube may replace a radio-isotope source. In 1996, the Department: reviewed the domestic demand for X-ray generators, developed an X-ray generator for diagnosis of ostheroporosis of human limbs, prepared a grant proposal for the development of a new instrument for radiotherapy, the so-called needle-like X-ray tube. (author).

Nigerian Journal of Chemical Research 29 Vol. 15, 2010 ...

African Journals Online (AJOL)

Hp

Nigerian Journal of Chemical Research. 29. Vol. 15, 2010. Antibacterial & Antifungal Studies On Some Coordination Compound Of Metals. With Ampicillin. Pranay Guru. Department of Engineering Chemistry, People's College of Research & Technology, Bhopal. (M. P.) India, email:pranayguru@rediffmail.com. ABSTRACT.

Routine blood tests are associated with short term mortality and can improve emergency department triage

DEFF Research Database (Denmark)

Kristensen, Michael; Iversen, Anne Kristine Servais; Gerds, Thomas Alexander

2017-01-01

BACKGROUND: Prioritization of acutely ill patients in the Emergency Department remains a challenge. We aimed to evaluate whether routine blood tests can predict mortality in unselected patients in an emergency department and to compare risk prediction with a formalized triage algorithm. METHODS...... registration. Multiple logistic regressions were used to predict 30-day mortality. Validation was performed by applying the regression models on the 2013 validation cohort. RESULTS: Thirty-day mortality was 5.3%. The routine blood tests had a significantly stronger discriminative value on 30-day mortality...... compared to the formalized triage (AUC 88.1 [85.7;90.5] vs. 63.4 [59.1;67.5], p blood tests was able to identify a larger number of low risk patients (n = 2100, 30-day mortality 0.1% [95% CI 0.0;0.3%]) compared to formalized triage (n = 1591, 2.8% [95% CI 2...

Complexity of chemical graphs in terms of size, branching, and cyclicity.

Science.gov (United States)

Balaban, A T; Mills, D; Kodali, V; Basak, S C

2006-08-01

Chemical graph complexity depends on many factors, but the main ones are size, branching, and cyclicity. Some molecular descriptors embrace together all these three parameters, which cannot then be disentangled. The topological index J (and its refinements that include accounting for bond multiplicity and the presence of heteroatoms) was designed to compensate in a significant measure for graph size and cyclicity, and therefore it contains information mainly on branching. In order to separate these factors, two new indices (F and G) related with J are proposed, which allow to group together graphs with the same size into families of constitutional formulas differing in their branching and cyclicity. A comparison with other topological indices revealed that a few other topological indices vary similarly with index G, notably DN2S4 among the triplet indices, and TOTOP among the indices contained in the Molconn-Z program. This comparison involved all possible chemical graphs (i.e. connected planar graphs with vertex degrees not higher than four) with four through six vertices, and all possible alkanes with four through nine carbon atoms.

Management of chemical disposal in BARC

International Nuclear Information System (INIS)

Shenoy, K.T.; Deolekar, Shailesh

2017-01-01

Most of the activities in BARC are of radiological in nature and are regulated as per Atomic Energy Act 1962. The radioactive waste generated is managed safely as per Atomic Energy (Safe Disposal of Radioactive Waste) Rules, 1987. However, many developmental activities related to nuclear fuel cycle and laboratories, which support the quality control aspects, generate inactive chemical waste. In addition, being multidisciplinary in nature, BARC carries out research in frontiers of chemical science for societal benefit and academic interest. All these scientific activities over the decades have resulted in accumulation of many partially used/surplus laboratory chemicals. These chemicals are in large varieties though small in terms of quantity. Although these chemicals do not have any further utility and commercial value, can add to potential hazards and hence require safe disposal. Considering this, BARC Safety Council(BSC) has re-constituted the 'Advisory Committee for Chemical Disposal (ACCD)' on March 18, 2016

Comparative toxicity of chemicals to earthworms

Energy Technology Data Exchange (ETDEWEB)

Callahan, C.A.; Shirazi, M.A. (Environmental Protection Agency, Corvallis, OR (United States)); Neuhauser, E.F. (Niagara Mohawk Power Corp., Syracuse, NY (United States))

1994-02-01

The concentration-response (mortality) relationships of four species of earthworms, Eisenia fetida (Savigny), Allolobophora tuberculata (Eisen), Eudrilus eugeniae (Kinberg), and Perionyx excavatus (Perrier) are summarized for 62 chemicals and two test protocols. A Weibull function is used to summarize these data for each chemical in terms of sensitivity and toxicity, in addition to the LC50. The estimation of the Weibull parameters a and k summarize the entire concentration-response relationship. This technique should be applicable to a variety of testing protocols with different species whenever the goal is summarizing the shape of the concentration-response curves to fully evaluate chemical impact on organisms. In some cases for these data four orders of magnitude separate LC50s of the soil test and the contact test for the same chemical and species. All four species appear to be similar in range of toxicity and tolerance to these chemicals, suggesting that Eisenia fetida and may be representative of these four species and these chemicals.

The Long-Term Study of Some mechanical and Chemical Properties of Polymer Modified Cement Waste Forms

International Nuclear Information System (INIS)

Shatta, H.A.; Eskander, S.B.

2002-01-01

The present work is a new experimental trend to study the long-term durability of polymer/cement/borate waste forms in storage and disposal sites during the long period of time. The data obtained indicate that all the samples of polymer modified cement waste forms immersed in both distilled and ground water (for more than 2700 days) show a slight increase in the compressive strength values. The chemical stability of the immobilized borate waste forms in distilled and ground water was studied. The cumulative leach fraction in percentage, of Cs-137 isotope from the final solidified waste forms in case of using ground water was lower than that in distilled water for all samples used and the presence of polymer lowered the percent release of radioactive Cs-137 isotope in all samples studied . The leach coefficients (Lc) and the leach indices (Li) of radioactive cesium-137 isotope for cement borate and polymer modified cement waste forms were also calculated. It was found that the leach indices values greater than 6

Chemical Safety Vulnerability Working Group report. Volume 1

Energy Technology Data Exchange (ETDEWEB)

1994-09-01

The Chemical Safety Vulnerability (CSV) Working Group was established to identify adverse conditions involving hazardous chemicals at DOE facilities that might result in fires or explosions, release of hazardous chemicals to the environment, or exposure of workers or the public to chemicals. A CSV Review was conducted in 148 facilities at 29 sites. Eight generic vulnerabilities were documented related to: abandoned chemicals and chemical residuals; past chemical spills and ground releases; characterization of legacy chemicals and wastes; disposition of legacy chemicals; storage facilities and conditions; condition of facilities and support systems; unanalyzed and unaddressed hazards; and inventory control and tracking. Weaknesses in five programmatic areas were also identified related to: management commitment and planning; chemical safety management programs; aging facilities that continue to operate; nonoperating facilities awaiting deactivation; and resource allocations. Volume 1 contains the Executive summary; Introduction; Summary of vulnerabilities; Management systems weaknesses; Commendable practices; Summary of management response plan; Conclusions; and a Glossary of chemical terms.

Chemical Safety Vulnerability Working Group report. Volume 1

International Nuclear Information System (INIS)

1994-09-01

The Chemical Safety Vulnerability (CSV) Working Group was established to identify adverse conditions involving hazardous chemicals at DOE facilities that might result in fires or explosions, release of hazardous chemicals to the environment, or exposure of workers or the public to chemicals. A CSV Review was conducted in 148 facilities at 29 sites. Eight generic vulnerabilities were documented related to: abandoned chemicals and chemical residuals; past chemical spills and ground releases; characterization of legacy chemicals and wastes; disposition of legacy chemicals; storage facilities and conditions; condition of facilities and support systems; unanalyzed and unaddressed hazards; and inventory control and tracking. Weaknesses in five programmatic areas were also identified related to: management commitment and planning; chemical safety management programs; aging facilities that continue to operate; nonoperating facilities awaiting deactivation; and resource allocations. Volume 1 contains the Executive summary; Introduction; Summary of vulnerabilities; Management systems weaknesses; Commendable practices; Summary of management response plan; Conclusions; and a Glossary of chemical terms

Department of Radiation Detectors: Overview

International Nuclear Information System (INIS)

Piekoszewski, J.

1999-01-01

Full text: Work carried out in 1998 in the Department of Radiation Detectors concentrated on three subjects: (i) Semiconductor Detectors (ii) X-ray Tube Generators (iii) Material Modification Using Ion and Plasma Beams. SEMICONDUCTOR DETECTORS: Semiconductor detectors of ionizing radiation are among the basic tools utilized in such fields of research and industry as nuclear physics, high energy physics, medical (oncology) radiotherapy, radiological protection, environmental monitoring, energy dispersive X-ray fluorescence non-destructive analysis of chemical composition, nuclear power industry. The departmental objectives are: a search for new types of detectors; producing unique detectors tailored for physics experiments; manufacturing standard detectors for radiation measuring instruments; scientific development of the staff. These objectives were accomplished in 1998 particularly by: research on unique thin silicon detectors for identification of particles in E-ΔE telescopes, modernization of technology of manufacturing Ge(Li) detectors capable of detecting broader range of gamma energies, manufacturing detectors developed in previous years, re-generating and servicing customer detectors of various origin. In accomplishment of the above the Department co-operated with groups of physicists from IPJ, PAN Institute of Physics (Warsaw), and with some technology Institutes based in Warsaw (ITME, ITE). Some detectors and services have been delivered to customers on a commercial basis. X-Ray TUBE GENERATORS: The Department conducts research on design and technology of manufacturing X-ray generators as well as on imaging and dosimetry of X-ray beams. Various models of special construction X-ray tubes and their power supplies are under construction. In 1998 work concentrated on: completing laboratory equipment for manufacturing X-ray tubes and their components, developing technology of manufacturing X-ray tubes and their components, completing a laboratory set-up with

U.S. Department of Energy Implementation of Chemical Evaluation Requirements for Transuranic Waste Disposal at the Waste Isolation Pilot Plant

Energy Technology Data Exchange (ETDEWEB)

Moon, Alison [USDOE Office of Environmental Management (EM), Washington, DC (United States); Barkley, Michelle [USDOE Office of Environmental Management (EM), Washington, DC (United States); Poppiti, James [USDOE Office of Environmental Management (EM), Washington, DC (United States)

2017-07-01

This report summarizes new controls designed to ensure that transuranic waste disposed at the Waste Isolation Pilot Plant (WIPP) does not contain incompatible chemicals. These new controls include a Chemical Compatibility Evaluation, an evaluation of oxidizing chemicals, and a waste container assessment to ensure that waste is safe for disposal. These controls are included in the Chapter 18 of the Documented Safety Analysis for WIPP (1).

U.S. Department of Energy Implementation of Chemical Evaluation Requirements for Transuranic Waste Disposal at the Waste Isolation Pilot Plant

International Nuclear Information System (INIS)

Moon, Alison; Barkley, Michelle; Poppiti, James

2017-01-01

This report summarizes new controls designed to ensure that transuranic waste disposed at the Waste Isolation Pilot Plant (WIPP) does not contain incompatible chemicals. These new controls include a Chemical Compatibility Evaluation, an evaluation of oxidizing chemicals, and a waste container assessment to ensure that waste is safe for disposal. These controls are included in the Chapter 18 of the Documented Safety Analysis for WIPP (1).

Journal of Chemical Sciences | Indian Academy of Sciences

Indian Academy of Sciences (India)

... Area of Analytical Chemistry, Faculty of Experimental Sciences, University of Huelva, Agrifood Campus of International Excellence, ceiA3. Avd. Tres de Marzo S/N, 21007 Huelva, Spain; Department of Inorganic and Analytical Chemistry, Faculty of Chemical and Pharmaceutical Sciences, University of Chile, P.O. Box 233, ...

A comparison of three-dimensional nonequilibrium solution algorithms applied to hypersonic flows with stiff chemical source terms

Science.gov (United States)

Palmer, Grant; Venkatapathy, Ethiraj

1993-01-01

Three solution algorithms, explicit underrelaxation, point implicit, and lower upper symmetric Gauss-Seidel (LUSGS), are used to compute nonequilibrium flow around the Apollo 4 return capsule at 62 km altitude. By varying the Mach number, the efficiency and robustness of the solution algorithms were tested for different levels of chemical stiffness. The performance of the solution algorithms degraded as the Mach number and stiffness of the flow increased. At Mach 15, 23, and 30, the LUSGS method produces an eight order of magnitude drop in the L2 norm of the energy residual in 1/3 to 1/2 the Cray C-90 computer time as compared to the point implicit and explicit under-relaxation methods. The explicit under-relaxation algorithm experienced convergence difficulties at Mach 23 and above. At Mach 40 the performance of the LUSGS algorithm deteriorates to the point it is out-performed by the point implicit method. The effects of the viscous terms are investigated. Grid dependency questions are explored.

78 FR 17680 - Information Collection Request; Chemical Facility Anti-Terrorism Standards Personnel Surety Program

Science.gov (United States)

2013-03-22

... Total Burden Cost (Capital/Startup) [cir] Estimating Capital Costs for Option 3--Number and Type of High... Department to take advantage of the vetting for terrorist ties already being conducted on affected... Department anticipates that many high-risk chemical facilities will rely on businesses that provide contract...

Chemical treatment of zinc surface and its corrosion inhibition studies

Indian Academy of Sciences (India)

WINTEC

Department of PG Studies and Research in Chemistry, School of Chemical Sciences, Kuvempu University, ... cations and is mainly used for the corrosion protection of ... provide a greater resistance to corrosion, but when exposed to humid ...

Chemical Industry R&D Roadmap for Nanomaterials By Design. From Fundamentals to Function

Energy Technology Data Exchange (ETDEWEB)

none,

2003-12-01

Vision2020 agreed to join NNI and the U.S. Department of Energy's Office of Energy Efficiency and Renewable Energy (DOE/EERE) in sponsoring the "Nanomaterials and the Chemical Industry Roadmap Workshop" on September 30-October 2, 2002. This roadmap, Chemical Industry R&D Roadmap for Nanomaterials By Design: From Fundamentals to Function, is based on the scientific priorities expressed by workshop participants from the chemical industry, universities, and government laboratories.

A review of chemical decontamination systems for nuclear facilities

International Nuclear Information System (INIS)

Chen, L.; Chamberlain, D.B.; Conner, C.; Vandegrift, G.F.

1996-01-01

With the downsizing of the Department of Energy (DOE) complex, many of its buildings and facilities will be decommissioned and dismantled. As part of this decommissioning, some form of decontamination will be required. To develop an appropriate technology for in situ chemical decontamination of equipment interiors in the decommissioning of DOE nuclear facilities, knowledge of the existing chemical decontamination methods is needed. This paper attempts to give an up-to-date review of chemical decontamination methods. This survey revealed that aqueous systems are the most widely used for the decontamination and cleaning of metal surfaces. We have subdivided the aqueous systems by types of chemical solvent: acid, alkaline permanganate, highly oxidizing, peroxide, and proprietary. Two other systems, electropolishing and foams and gels, are also described in this paper

Malnutrition: a highly predictive risk factor of short-term mortality in elderly presenting to the emergency department.

Science.gov (United States)

Gentile, S; Lacroix, O; Durand, A C; Cretel, E; Alazia, M; Sambuc, R; Bonin-Guillaume, S

2013-04-01

To identify independent risk factors of mortality among elderly patients in the 3 months after their visit (T3) to an emergency department (ED). Prospective cohort study. University hospital ED in an urban setting in France. One hundred seventy-three patients aged 75 and older were admitted to the ED over two weeks (18.7% of the 924 ED visits). Of these, 164 patients (94.8%) were included in our study, and 157 (95.7%) of them were followed three months after their ED visit. During the inclusion period (T0), a standardized questionnaire was used to collect data on socio-demographic and environmental characteristics, ED visit circumstances, medical conditions and geriatric assessment including functional and nutritional status. Three months after the ED visits (T3), patients or their caregivers were interviewed to collect data on vital status, and ED return or hospitalization. Among the 157 patients followed at T3, 14.6% had died, 19.9% had repeated ED visits, and 63.1% had been hospitalized. The two independent predictive factors for mortality within the 3 months after ED visit were: malnutrition screened by the Mini Nutritional Assessment short-form (MNA-SF) (OR=20.2; 95% CI: 5.74-71.35; pMalnutrition is the strongest independent risk factor predicting short-term mortality in elderly patients visiting the ED, and it was easily detected by MNA-SF and supported from the ED visit.

Prediction of aged red wine aroma properties from aroma chemical composition. Partial least squares regression models.

Science.gov (United States)

Aznar, Margarita; López, Ricardo; Cacho, Juan; Ferreira, Vicente

2003-04-23

Partial least squares regression (PLSR) models able to predict some of the wine aroma nuances from its chemical composition have been developed. The aromatic sensory characteristics of 57 Spanish aged red wines were determined by 51 experts from the wine industry. The individual descriptions given by the experts were recorded, and the frequency with which a sensory term was used to define a given wine was taken as a measurement of its intensity. The aromatic chemical composition of the wines was determined by already published gas chromatography (GC)-flame ionization detector and GC-mass spectrometry methods. In the whole, 69 odorants were analyzed. Both matrixes, the sensory and chemical data, were simplified by grouping and rearranging correlated sensory terms or chemical compounds and by the exclusion of secondary aroma terms or of weak aroma chemicals. Finally, models were developed for 18 sensory terms and 27 chemicals or groups of chemicals. Satisfactory models, explaining more than 45% of the original variance, could be found for nine of the most important sensory terms (wood-vanillin-cinnamon, animal-leather-phenolic, toasted-coffee, old wood-reduction, vegetal-pepper, raisin-flowery, sweet-candy-cacao, fruity, and berry fruit). For this set of terms, the correlation coefficients between the measured and predicted Y (determined by cross-validation) ranged from 0.62 to 0.81. Models confirmed the existence of complex multivariate relationships between chemicals and odors. In general, pleasant descriptors were positively correlated to chemicals with pleasant aroma, such as vanillin, beta damascenone, or (E)-beta-methyl-gamma-octalactone, and negatively correlated to compounds showing less favorable odor properties, such as 4-ethyl and vinyl phenols, 3-(methylthio)-1-propanol, or phenylacetaldehyde.

33 CFR 149.416 - What are the requirements for a dry chemical fire suppression system?

Science.gov (United States)

2010-07-01

... the requirements for a dry chemical fire suppression system? Each natural gas deepwater port must be... dry chemical fire suppression system? 149.416 Section 149.416 Navigation and Navigable Waters COAST GUARD, DEPARTMENT OF HOMELAND SECURITY (CONTINUED) DEEPWATER PORTS DEEPWATER PORTS: DESIGN, CONSTRUCTION...

A Computer Oriented Scheme for Coding Chemicals in the Field of Biomedicine.

Science.gov (United States)

Bobka, Marilyn E.; Subramaniam, J.B.

The chemical coding scheme of the Medical Coding Scheme (MCS), developed for use in the Comparative Systems Laboratory (CSL), is outlined and evaluated in this report. The chemical coding scheme provides a classification scheme and encoding method for drugs and chemical terms. Using the scheme complicated chemical structures may be expressed…

Semiannual Report of the Chemistry Department, June--November 1966

International Nuclear Information System (INIS)

1967-01-01

This semiannual report of the Chemistry Department of the Cea of Fontenay-aux Roses, presents in its first part researches on the chemical analysis, the treatment of fairly and slightly active effluents, the uranium treatment, studies on electrometallurgy, studies on corrosion and studies on filtration and elimination on sea water of hard compounds. The second part is devoted to the study of aqueous reprocessing of irradiated fuels (laboratory and pilot plant), anhydrous reprocessing, actinides elements isotopes preparation and study, fission products concentrated solution vitrification study and fundamental studies on acid-base properties. (A.L.B.)

Combined chemical and toxicological long-term monitoring for AhR agonists with SPMD-based virtual organisms in drinking water Danjiangkou Reservoir, China.

Science.gov (United States)

Wang, Jingxian; Song, Guoqiang; Li, Aimin; Henkelmann, Bernhard; Pfister, Gerd; Tong, Anthony Z; Schramm, Karl-Werner

2014-08-01

SPMD-based virtual organisms (VOs) were employed for time-integrating, long-term sampling combined biological and chemical analyses for exposure assessment of hydrophobic organic pollutants (HOPs) in a drinking water reservoir, China. The SPMDs were deployed at four and five sites in the Danjiangkou (DJK) reservoir over two periods of 26 and 31 d to sequester the hydrophobic contaminants in water. The chosen bioassay response for the extracts of the SPMDs, the induction of 7-ethoxyresorufin-o-deethylase (EROD) was assayed using a rat hepatoma cell line (H4IIE). The known aryl hydrocarbon receptor (AhR) agonists PAHs and PCBs were analyzed by HRGC/HRMS instrument. The cause-effect relationship between the observed AhR activities and chemical concentrations of detected AhR agonists was examined. The results show that the extracts from the SPMD samples could induce AhR activity significantly, whereas the chemically derived 2,3,7,8-tetrachlorodibenzo-p-dioxin (TCDD) equivalent (TEQcal) was not correlated with the bioassay-derived TCDD equivalent (TEQbio). The known AhR agonists could only account for 2-10% of the observed AhR responses among which the contribution of PCBs could almost be neglected. Unidentified AhR-active compounds represented a greater proportion of the TCDD equivalent (TCDD-EQ) in SPMD samples from DJK. Based on the first assessment, the VO followed by the combination of chemical and biological analyses emerges as a resource efficient water monitoring device in ecotoxicological assessment for toxicologically relevant compounds which are readily available for uptake by resident aquatic biota in drinking water resources. Copyright © 2014 Elsevier Ltd. All rights reserved.

Female Faculty Members in University Chemistry Departments: Observations and Conclusions Based on Site Visits

Science.gov (United States)

Chapman, Sally; Dixon, Felicia F.; Foster, Natalie; Kuck, Valerie J.; McCarthy, Deborah A.; Tooney, Nancy M.; Buckner, Janine P.; Nolan, Susan A.; Marzabadi, Cecilia H.

2011-01-01

Oral interviews in focus groups and written surveys were conducted with 877 men and women, including administrators, faculty members, postdoctoral associates, and graduate students, during one-day site visits to chemistry and chemical engineering departments at 28 Ph.D.-granting institutions. This report is a preliminary review of the perceptions…

From networking to next-working: how an academic department "retreated" and advanced at the same time.

Science.gov (United States)

Yager, Joel; Kenna, Heather; Hantke, Mindy

2015-04-01

Department-wide retreats conducted at periods of transition can enrich and benefit academic departments in several ways. Here, the authors describe the organization, conduct, and immediate outcomes of a department-wide retreat in a university department of psychiatry intended to (1) foster networking and communication among faculty who often work in "silos" and (2) invite the faculty to provide "internal consultations" regarding aspirational strategic goals and recommendations for short-term actionable tactics to address these goals. The retreat featured an evening networking and socializing poster session followed by a day-long event consisting of small group and large group interactive sessions. Participants were 120 faculty members including 44 new and younger faculty members who prepared and presented posters about themselves and their work. A variety of aspirational goals and specific recommendations for follow-up emerged from small groups were discussed in plenary sessions and were subsequently summarized and distributed to the faculty to be addressed by ongoing workgroups. Immediate informal feedback suggests that conducting and acting on recommendations ensuing from academic department retreats can foster at least a short-term sense of shared community and purpose, network faculty, identify commonly held values and aspirational goals, and potentially stimulate formation of innovative affinity groups and collaborations. Longer-term workgroup efforts and outcome assessments are required to assess the enduring results and value of such undertakings.

A vector/parallel method for a three-dimensional transport model coupled with bio-chemical terms

NARCIS (Netherlands)

B.P. Sommeijer (Ben); J. Kok (Jan)

1995-01-01

textabstractA so-called fractional step method is considered for the time integration of a three-dimensional transport-chemical model in shallow seas. In this method, the transport part and the chemical part are treated separately by appropriate integration techniques. This separation is motivated

Critical flux and chemical cleaning-in-place during the long-term operation of a pilot-scale submerged membrane bioreactor for municipal wastewater treatment

KAUST Repository

Wei, Chunhai

2011-01-01

The critical flux and chemical cleaning-in-place (CIP) in a long-term operation of a pilot-scale submerged membrane bioreactor for municipal wastewater treatment were investigated. Steady filtration under high flux (30 L/(m2 h)) was successfully achieved due to effective membrane fouling control by sub-critical flux operation and chemical CIP with sodium hypochlorite (NaClO) in both trans-membrane pressure (TMP) controlling mode (cleaning with high concentration NaClO of 2000-3000 mg/L in terms of effective chorine was performed when TMP rose to 15 kPa) and time controlling mode (cleanings were performed weekly and monthly respectively with low concentration NaClO (500-1000 mg/L) and high concentration NaClO (3000 mg/L)). Microscopic analysis on membrane fibers before and after high concentration NaClO was also conducted. Images of scanning electron microscopy (SEM) and atomic force microscopy (AFM) showed that NaClO CIP could effectively remove gel layer, the dominant fouling under sub-critical flux operation. Porosity measurements indicated that NaClO CIP could partially remove pore blockage fouling. The analyses from fourier transform infrared spectrometry (FTIR) with attenuated total reflectance accessory (ATR) and energy dispersive spectrometer (EDS) demonstrated that protein-like macromolecular organics and inorganics were the important components of the fouling layer. The analysis of effluent quality before and after NaClO CIP showed no obvious effect on effluent quality. © 2010 Elsevier Ltd.

Rational Design of Mixed-Metal Oxides for Chemical Looping Combustion of Coal via Coupled Computational-Experimental Studies

Energy Technology Data Exchange (ETDEWEB)

Mishra, Amit [North Carolina State Univ., Raleigh, NC (United States); Li, Fanxing [North Carolina State Univ., Raleigh, NC (United States); Santiso, Erik [North Carolina State Univ., Raleigh, NC (United States)

2017-09-18

Energy and global climate change are two grand challenges to the modern society. An urgent need exists for development of clean and efficient energy conversion processes. The chemical looping strategy, which utilizes regenerable oxygen carriers (OCs) to indirectly convert carbonaceous fuels via redox reactions, is considered to be one of the more promising approaches for CO2 capture by the U.S. Department of Energy (USDOE). To date, most long-term chemical looping operations were conducted using gaseous fuels, even though direct conversion of coal is more desirable from both economics and CO2 capture viewpoints. The main challenges for direct coal conversion reside in the stringent requirements on oxygen carrier performances. In addition, coal char and volatile compounds are more challenging to convert than gaseous fuels. A promising approach for direct conversion of coal is the so called chemical looping with oxygen uncoupling (CLOU) technique. In the CLOU process, a metal oxide that decomposes at the looping temperature, and releases oxygen to the gas phase is used as the OC. The overarching objective of this project was to discover the fundamental principles for rational design and optimization of oxygen carriers (OC) in coal chemical looping combustion (CLC) processes. It directly addresses Topic Area B of the funding opportunity announcement (FOA) in terms of “predictive description of the phase behavior and mechanical properties” of “mixed metal oxide” based OCs and rational development of new OC materials with superior functionality. This was achieved through studies exploring i) iron-containing mixed-oxide composites as oxygen carriers for CLOU, ii) Ca1-xAxMnO3-δ (A = Sr and Ba) as oxygen carriers for CLOU, iii) CaMn1-xBxO3-δ (B=Al, V, Fe, Co, and Ni) as oxygen carrier for CLOU and iv) vacancy creation energy in Mn-containing perovskites as an indicator chemical looping with oxygen uncoupling.

LICSS - a chemical spreadsheet in microsoft excel.

Science.gov (United States)

Lawson, Kevin R; Lawson, Jonty

2012-02-02

Representations of chemical datasets in spreadsheet format are important for ready data assimilation and manipulation. In addition to the normal spreadsheet facilities, chemical spreadsheets need to have visualisable chemical structures and data searchable by chemical as well as textual queries. Many such chemical spreadsheet tools are available, some operating in the familiar Microsoft Excel environment. However, within this group, the performance of Excel is often compromised, particularly in terms of the number of compounds which can usefully be stored on a sheet. LICSS is a lightweight chemical spreadsheet within Microsoft Excel for Windows. LICSS stores structures solely as Smiles strings. Chemical operations are carried out by calling Java code modules which use the CDK, JChemPaint and OPSIN libraries to provide cheminformatics functionality. Compounds in sheets or charts may be visualised (individually or en masse), and sheets may be searched by substructure or similarity. All the molecular descriptors available in CDK may be calculated for compounds (in batch or on-the-fly), and various cheminformatic operations such as fingerprint calculation, Sammon mapping, clustering and R group table creation may be carried out.We detail here the features of LICSS and how they are implemented. We also explain the design criteria, particularly in terms of potential corporate use, which led to this particular implementation. LICSS is an Excel-based chemical spreadsheet with a difference:• It can usefully be used on sheets containing hundreds of thousands of compounds; it doesn't compromise the normal performance of Microsoft Excel• It is designed to be installed and run in environments in which users do not have admin privileges; installation involves merely file copying, and sharing of LICSS sheets invokes automatic installation• It is free and extensibleLICSS is open source software and we hope sufficient detail is provided here to enable developers to add their

Chemical buffering capacity of clay rock

International Nuclear Information System (INIS)

Beaucaire, C.; Pearson, F.J.; Gautschi, A.

2004-01-01

The long-term performance of a nuclear waste repository is strongly dependent on the chemical properties of the host rock. The host rock establishes the chemical environment that determines such important performance attributes as radionuclide solubilities from the waste and the transport rates from the repository to the accessible environment. Clay-rich rocks are especially favourable host rocks because they provide a strong buffering capacity to resist chemical changes prompted either internally, by reactions of the waste itself and emplacement materials, or externally, by changes in the hydrologic systems surrounding the host rock. This paper will focus on three aspects of the stability of clay-rich host rocks: their ability to provide pCO 2 and redox buffering, and to resist chemical changes imposed by changes in regional hydrology and hydro-chemistry. (authors)

Methodology and computational framework used for the US Department of Energy Environmental Restoration and Waste Management Programmatic Environmental Impact Statement accident analysis

International Nuclear Information System (INIS)

Mueller, C.; Roglans-Ribas, J.; Folga, S.; Huttenga, A.; Jackson, R.; TenBrook, W.; Russell, J.

1994-01-01

A methodology, computational framework, and integrated PC-based database have been developed to assess the risks of facility accidents in support of the US Department of Energy (DOE) Environmental Restoration and Waste Management Programmatic Environmental Impact Statement. The methodology includes the following interrelated elements: (1) screening of storage and treatment processes and related waste inventories to determine risk-dominant facilities across the DOE complex, (2) development and frequency estimation of the risk-dominant sequences of accidents, and (3) determination of the evolution of and final compositions of radiological or chemically hazardous source terms predicted to be released as a function of the storage inventory or treatment process throughput. The computational framework automates these elements to provide source term input for the second part of the analysis which includes (1) development or integration of existing site-specific demographics and meteorological data and calculation of attendant unit-risk factors and (2) assessment of the radiological or toxicological consequences of accident releases to the general public and to the occupational work force

15 CFR 710.1 - Definitions of terms used in the Chemical Weapons Convention Regulations (CWCR).

Science.gov (United States)

2010-01-01

... to on-site verification pursuant to Articles IV, V, and VI of the Convention. Host Team. Means the U... relatively self-contained area, structure or building containing one or more units with auxiliary and..., including carrying out the verification measures delineated in the CWC. Toxic Chemical. Means any chemical...

Role of the Chemical Weapons Convention (CWC) in Combating Chemical Terrorism

International Nuclear Information System (INIS)

Matousek, J.

2007-01-01

Main reason for concluding the CWC was preventing use of CWs in hostilities by state actors. Chemical terrorism is a broader phenomenon involving not only misuse of CWs but also of non-weaponised toxic compounds and intended strikes on industrial and social infrastructures with release of toxic, liquefied and inflammable chemicals. Nevertheless, the CWC is an important instrument in combating the most dangerous forms of international chemical terrorism. The effort of OPCW and mainly of SPs national authorities ensure that chemicals produced for peaceful purposes are not misused, provide some guarantees that terrorists will not be able to acquire or make their own CWs. That is why universality of the CWC and respective national implementation measures including comprehensive legislation are of utmost importance. The enforcement by all countries of the CWCs requirement to make the development, production, stockpiling, transfers and use of CWs illegal for anyone means that terrorist could be put on trial for violating the CWC. The OPCWs expertise and knowledge of CWs, verification regime and the system of assistance and protection under the CWC as a reflection of international co-operation are being put to use to prevent and respond to chemical terrorist strikes and thus considerably diminish their potential consequences. It can be added that pursuant to the UN SC Resolution 1540, all nations are obliged to take actions ensuring that non-State actors cannot develop, produce, use or trade CWs in the terms of the CWC. Current status of implementing the CWC is analysed with special emphasis on prevention of and response to terrorist chemical attacks.(author)

29 CFR 528.2 - Definition of terms.

Science.gov (United States)

2010-07-01

... ESTABLISHMENTS AT SPECIAL MINIMUM WAGE RATES § 528.2 Definition of terms. As used in the regulations contained in... 29 Labor 3 2010-07-01 2010-07-01 false Definition of terms. 528.2 Section 528.2 Labor Regulations Relating to Labor (Continued) WAGE AND HOUR DIVISION, DEPARTMENT OF LABOR REGULATIONS ANNULMENT OR...

Inventory of chemicals used at Hanford Site production plants and support operations (1944-1980)

Energy Technology Data Exchange (ETDEWEB)

Klem, M. J.

1990-04-01

A complete list of chemicals used in the production facilities and support operations of the US Department of Energy Hanford Site is presented to aid development of plans for characterizing the radioactive liquid chemical wastes stored in the 149 single-shell tanks. The complete chemical list is compared to the list provided by the regulatory agencies to identify hazardous chemicals stored in the single-shell tanks. A reduced list has been developed by others and is used to identify the chemical constituents for analysis in the Waste Characterization Plan for the Hanford Site Single-Shell Tanks. The chemical list is based on chemical process flowsheets, essential material consumption records, letters, reports, and other historical data. 14 refs., 36 tabs.

Voluntary cleanup of the Ames chemical disposal site

International Nuclear Information System (INIS)

Taboas, A.L.; Freeman, R.; Peterson, J.

2003-01-01

The U.S. Department of Energy completed a voluntary removal action at the Ames chemical disposal site, a site associated with the early days of the Manhattan Project. It contained chemical and low-level radioactive wastes from development of the technology to extract uranium from uranium oxide. The process included the preparation of a Remedial Investigation, Feasibility Study, Baseline Risk Assessment, and, ultimately, issuance of a Record of Decision. Various stakeholder groups were involved, including members of the regulatory community, the general public, and the landowner, Iowa State University. The site was restored and returned to the landowner for unrestricted use.

Summaries of FY 1982 research in the chemical sciences

Energy Technology Data Exchange (ETDEWEB)

None

1982-09-01

The purpose of this booklet is to help those interested in research supported by the Department of Energy's Division of Chemical Sciences, which is one of six Divisions of the Office of Basic Energy Sciences in the Office of Energy Research. These summaries are intended to provide a rapid means for becoming acquainted with the Chemical Sciences program to members of the scientific and technological public and interested persons in the Legislative and Executive Branches of the Government. Areas of research supported by the Division are to be seen in the section headings, the index and the summaries themselves. Energy technologies which may be advanced by use of the basic knowledge discovered in this program can be seen in the index and again (by reference) in the summaries. The table of contents lists the following: photochemical and radiation sciences; chemical physics; atomic physics; chemical energy; separation and analysis; chemical engineering sciences; offsite contracts; equipment funds; special facilities; topical index; institutional index for offsite contracts; investigator index.

Summaries of FY 1982 research in the chemical sciences

International Nuclear Information System (INIS)

1982-09-01

The purpose of this booklet is to help those interested in research supported by the Department of Energy's Division of Chemical Sciences, which is one of six Divisions of the Office of Basic Energy Sciences in the Office of Energy Research. These summaries are intended to provide a rapid means for becoming acquainted with the Chemical Sciences program to members of the scientific and technological public and interested persons in the Legislative and Executive Branches of the Government. Areas of research supported by the Division are to be seen in the section headings, the index and the summaries themselves. Energy technologies which may be advanced by use of the basic knowledge discovered in this program can be seen in the index and again (by reference) in the summaries. The table of contents lists the following: photochemical and radiation sciences; chemical physics; atomic physics; chemical energy; separation and analysis; chemical engineering sciences; offsite contracts; equipment funds; special facilities; topical index; institutional index for offsite contracts; investigator index

Chemical nature of catalysts of oxide nanoparticles in environment ...

Indian Academy of Sciences (India)

12

Chemical nature of catalysts of oxide nanoparticles in environment prevailing during growth of carbon nanostructures by CCVD. M. Jana*, A. Sil and S. Ray. †. Department of Metallurgical and Materials Engineering. Indian Institute of Technology Roorkee. Roorkee 247 667, India. Present address: *School of Materials ...

Chemical control of blossom blight disease of sarpagandha caused ...

African Journals Online (AJOL)

ONOS

2010-09-20

Sep 20, 2010 ... Chemical control of blossom blight disease of sarpagandha caused by Colletotrichum capsici. R. S. Shukla, Abdul-Khaliq and M. Alam*. Department of Plant Pathology, Central Institute of Medicinal and Aromatic Plants, Council of Scientific and Industrial. Research, P. O. CIMAP, Lucknow–226 015, India.

State waste discharge permit application, 200-E chemical drain field

Energy Technology Data Exchange (ETDEWEB)

1994-06-01

As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect ground would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE 91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. This document presents the State Waste Discharge Permit (SWDP) application for the 200-E Chemical Drain Field. Waste water from the 272-E Building enters the process sewer line directly through a floor drain, while waste water from the 2703-E Building is collected in two floor drains, (north and south) that act as sumps and are discharged periodically. The 272-E and 2703-E Buildings constitute the only discharges to the process sewer line and the 200-E Chemical Drain Field.

State waste discharge permit application, 200-E chemical drain field

International Nuclear Information System (INIS)

1994-06-01

As part of the Hanford Federal Facility Agreement and Consent Order negotiations (Ecology et al. 1994), the US Department of Energy, Richland Operations Office, the US Environmental Protection Agency, and the Washington State Department of Ecology agreed that liquid effluent discharges to the ground on the Hanford Site which affect groundwater or have the potential to affect ground would be subject to permitting under the structure of Chapter 173-216 (or 173-218 where applicable) of the Washington Administrative Code, the State Waste Discharge Permit Program. As a result of this decision, the Washington State Department of Ecology and the US Department of Energy, Richland Operations Office entered into Consent Order No. DE 91NM-177, (Ecology and DOE-RL 1991). The Consent Order No. DE 91NM-177 requires a series of permitting activities for liquid effluent discharges. This document presents the State Waste Discharge Permit (SWDP) application for the 200-E Chemical Drain Field. Waste water from the 272-E Building enters the process sewer line directly through a floor drain, while waste water from the 2703-E Building is collected in two floor drains, (north and south) that act as sumps and are discharged periodically. The 272-E and 2703-E Buildings constitute the only discharges to the process sewer line and the 200-E Chemical Drain Field

ANALYSIS OF RAIN BY WILLIAM SOMERSET MAUGHAM IN TERMS OF POST-COLONIAL TERMS

Directory of Open Access Journals (Sweden)

Şaban KÖKTÜRK

2015-04-01

Full Text Available This study dealt with the analysis of a short story, Rain by William Somerset Maugham in terms of post-colonial terms or elements. Before the analysis, the writer of the book was introduced and then the plot was explained so as to make readers familiar with the short story. In the analysis section, post-colonial elements or related terms such as missionary, colonial authority, the state of being subaltern, Manichean allegory, mimicry, ambivalence, surveillance, imperial hegemony, hybridity, essentialism, monolithic culture, alienation, dislocation, misuse of power, gender difference were analyzed from some of the excerpts whether to see how strong these concepts affect the course of the fiction. The study targeted at showing students of language & literature departments the application of the related terms or elements in such stories.

Thyroid effects of endocrine disrupting chemicals.

Science.gov (United States)

Boas, Malene; Feldt-Rasmussen, Ulla; Main, Katharina M

2012-05-22

In recent years, many studies of thyroid-disrupting effects of environmental chemicals have been published. Of special concern is the exposure of pregnant women and infants, as thyroid disruption of the developing organism may have deleterious effects on neurological outcome. Chemicals may exert thyroid effects through a variety of mechanisms of action, and some animal experiments and in vitro studies have focused on elucidating the mode of action of specific chemical compounds. Long-term human studies on effects of environmental chemicals on thyroid related outcomes such as growth and development are still lacking. The human exposure scenario with life long exposure to a vast mixture of chemicals in low doses and the large physiological variation in thyroid hormone levels between individuals render human studies very difficult. However, there is now reasonably firm evidence that PCBs have thyroid-disrupting effects, and there is emerging evidence that also phthalates, bisphenol A, brominated flame retardants and perfluorinated chemicals may have thyroid disrupting properties. Copyright © 2011 Elsevier Ireland Ltd. All rights reserved.

Public Health Departments

Data.gov (United States)

Department of Homeland Security — State and Local Public Health Departments in the United States Governmental public health departments are responsible for creating and maintaining conditions that...

Influence of pH during chemical weathering of bricks: Long term exposure

DEFF Research Database (Denmark)

Rörig-Dalgaard, Inge; Charola, A. Elena

2016-01-01

Within the framework of environmental weathering of bricks in historical structures, this study focuses on new bricks currently employed for restoration projects. The bricks were subjected to an accelerated chemical weathering test by immersion in solutions with pH ranging from 3 to 13 for differ...

Twelfth symposium on biotechnology for fuels and chemicals: Program and abstracts

International Nuclear Information System (INIS)

Scheitlin, F.M.

1990-01-01

This report is the program and abstracts of the twelfth symposium on biotechnology for fuels and chemicals, held on May 7--11, 1990, at Gatlinburg, Tennessee. The symposium, sponsored by the Department of Energy, Oak Ridge National Laboratory, Solar Energy Research Institute, Badger Engineers, Inc., Gas Research Institute, and American Chemical Society, consists of five sessions: Session 1, thermal, chemical, and biological processing; Session 2 and 3, applied biological research; Session 4, bioengineering research; and Session 5, biotechnology, bioengineering, and the solution of environmental problems. It also consists of a poster session of the same five subject categories

Twelfth symposium on biotechnology for fuels and chemicals: Program and abstracts

Energy Technology Data Exchange (ETDEWEB)

Scheitlin, F.M. (ed.)

1990-01-01

This report is the program and abstracts of the twelfth symposium on biotechnology for fuels and chemicals, held on May 7--11, 1990, at Gatlinburg, Tennessee. The symposium, sponsored by the Department of Energy, Oak Ridge National Laboratory, Solar Energy Research Institute, Badger Engineers, Inc., Gas Research Institute, and American Chemical Society, consists of five sessions: Session 1, thermal, chemical, and biological processing; Session 2 and 3, applied biological research; Session 4, bioengineering research; and Session 5, biotechnology, bioengineering, and the solution of environmental problems. It also consists of a poster session of the same five subject categories.

Organic chemicals jeopardize the health of freshwater ecosystems on the continental scale.

Science.gov (United States)

Malaj, Egina; von der Ohe, Peter C; Grote, Matthias; Kühne, Ralph; Mondy, Cédric P; Usseglio-Polatera, Philippe; Brack, Werner; Schäfer, Ralf B

2014-07-01

Organic chemicals can contribute to local and regional losses of freshwater biodiversity and ecosystem services. However, their overall relevance regarding larger spatial scales remains unknown. Here, we present, to our knowledge, the first risk assessment of organic chemicals on the continental scale comprising 4,000 European monitoring sites. Organic chemicals were likely to exert acute lethal and chronic long-term effects on sensitive fish, invertebrate, or algae species in 14% and 42% of the sites, respectively. Of the 223 chemicals monitored, pesticides, tributyltin, polycyclic aromatic hydrocarbons, and brominated flame retardants were the major contributors to the chemical risk. Their presence was related to agricultural and urban areas in the upstream catchment. The risk of potential acute lethal and chronic long-term effects increased with the number of ecotoxicologically relevant chemicals analyzed at each site. As most monitoring programs considered in this study only included a subset of these chemicals, our assessment likely underestimates the actual risk. Increasing chemical risk was associated with deterioration in the quality status of fish and invertebrate communities. Our results clearly indicate that chemical pollution is a large-scale environmental problem and requires far-reaching, holistic mitigation measures to preserve and restore ecosystem health.

42 CFR 84.194 - Filters used with chemical cartridges; location; replacement.

Science.gov (United States)

2010-10-01

...; replacement. 84.194 Section 84.194 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN...; replacement. (a) Particulate matter filters used in conjunction with a chemical cartridge shall be located on... replacement on the cartridge. ...

PETROS - Worldwide Databank of Major Element Chemical Analyses of Igneous Rocks

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — PETROS is a worldwide data bank of major element chemical analyses of igneous rocks compiled for research and teaching purposes by Dr. Felix Mutschler and Staff at...

[Corticosteroid therapy and therapeutic education: experience of an internal medicine department

NARCIS (Netherlands)

Simon, A.; Ane, A.M.; Afroun, A.

2013-01-01

In 2003, we sought to determine what were the needs of patients prescribed with long-term glucocorticoid therapy in our internal medicine department. Following this inventory, we decided to homogenize the medical practices regarding glucocorticoid prescriptions in our institution. We also set up a

Matrix metalloproteinases regulate the formation of dendritic spine head protrusions during chemically induced long-term potentiation.

Directory of Open Access Journals (Sweden)

Zsuzsanna Szepesi

Full Text Available Dendritic spines are are small membranous protrusions that extend from neuronal dendrites and harbor the majority of excitatory synapses. Increasing evidence has shown that matrix metalloproteinases (MMPs, a family of extracellularly acting and Zn(2+-dependent endopeptidases, are able to rapidly modulate dendritic spine morphology. Spine head protrusions (SHPs are filopodia-like processes that extend from the dendritic spine head, representing a form of postsynaptic structural remodeling in response to altered neuronal activity. Herein, we show that chemically induced long-term potentiation (cLTP in dissociated hippocampal cultures upregulates MMP-9 activity that controls the formation of SHPs. Blocking of MMPs activity or microtubule dynamics abolishes the emergence of SHPs. In addition, autoactive recombinant MMP-9, promotes the formation of SHPs in organotypic hippocampal slices. Furthermore, spines with SHPs gained postsynaptic α-amino-3-hydroxyl-5-methyl-4-isoxazole propionic acid (AMPA receptors upon cLTP and the synaptic delivery of AMPA receptors was controlled by MMPs. The present results strongly imply that MMP-9 is functionally involved in the formation of SHPs and the control of postsynaptic receptor distribution upon cLTP.

Department of Training and Consulting - Overview

International Nuclear Information System (INIS)

Dobrzynski, L.

2010-01-01

Full text: The Department of Training and Consulting concentrates on the dissemination of knowledge on radiation phenomena: the origins, applications and health effects of ionizing radiation in particular. Its activity is open to the public. However, the main recipients are students of secondary schools and teachers. During about 12 years of such activity the number of visitors has exceeded 60 000 persons, while during last few years the average number of our visitors varies between 6 000 and 7 000 per year, which shows how much this kind of activity is needed. It should be noted that the term 'visitor' is not the most appropriate, because what the 'visitor' actually experiences in the Department is a series of lectures with demonstrations, visits to the MARIA reactor or regular experimenting in a specially designed Laboratory of Atomic and Nuclear Physics for schools, teachers and university students. The Department organized two permanent exhibitions. One is connected with the nuclear waste treatment and storage, another one displays a large model. 4x4x4 m. of a nuclear reactor of the WWER-type which was about to be installed at Zarnowiec about 20 years ago. The Department is equally active during annual Picnics and Festivals of Science in Warsaw and other Polish towns. Our staff is often asked to deliver lectures outside the Institute for Nuclear Studies, and participates in discussions on problems of teaching, in addition, the Department leads, together with the Institute of Physics of the Polish Academy of Sciences, Warsaw, the annual competition, named '' Physical Paths '', for high-school students. The competition is arranged in three categories: research, demonstration of physical phenomena, and essays on physics and its relation to civilization. This competition particularly stimulates small educational centers in Poland. This year, 2010, the competition was organized for the fifth time. The Department of Training and Consulting arranges regular courses

Proposed Occupational Exposure Limits for Non-Carcinogenic Hanford Waste Tank Vapor Chemicals

International Nuclear Information System (INIS)

Poet, Torka S.; Timchalk, Chuck

2006-01-01

A large number of volatile chemicals have been identified in the headspaces of tanks used to store mixed chemical and radioactive waste at the U.S. Department of Energy (DOE) Hanford Site, and there is concern that vapor releases from the tanks may be hazardous to workers. Contractually established occupational exposure limits (OELs) established by the Occupational Safety and Health Administration (OSHA) and American Conference of Governmental Industrial Hygienists (ACGIH) do not exist for all chemicals of interest. To address the need for worker exposure guidelines for those chemicals that lack OSHA or ACGIH OELs, a procedure for assigning Acceptable Occupational Exposure Limits (AOELs) for Hanford Site tank farm workers has been developed and applied to a selected group of 57 headspace chemicals

Proposed Occupational Exposure Limits for Non-Carcinogenic Hanford Waste Tank Vapor Chemicals

Energy Technology Data Exchange (ETDEWEB)

Poet, Torka S.; Timchalk, Chuck

2006-03-24

A large number of volatile chemicals have been identified in the headspaces of tanks used to store mixed chemical and radioactive waste at the U.S. Department of Energy (DOE) Hanford Site, and there is concern that vapor releases from the tanks may be hazardous to workers. Contractually established occupational exposure limits (OELs) established by the Occupational Safety and Health Administration (OSHA) and American Conference of Governmental Industrial Hygienists (ACGIH) do not exist for all chemicals of interest. To address the need for worker exposure guidelines for those chemicals that lack OSHA or ACGIH OELs, a procedure for assigning Acceptable Occupational Exposure Limits (AOELs) for Hanford Site tank farm workers has been developed and applied to a selected group of 57 headspace chemicals.

Field studies on long term ecosystem consequences of ionising radiation and chemical pollutants (EANOR Project)

Energy Technology Data Exchange (ETDEWEB)

Oughton, D. [Centre for Environmental Radioactivity - CERAD (Norway); Evseeva, T. [Institute of Biology RAS (Russian Federation); Erenturk, S. [Istanbul Technical University (Turkey)

2014-07-01

Chernobyl and other nuclear accidents have demonstrated that high levels of ionizing radiation can result in impacts on plants and animals, however little is known about the long-term effects of chronic exposure on biodiversity or other population and ecosystem level effects. The issue of ecological impact has been addressed after the Fukushima accident, which has raised questions about the impacts of radioactivity not only on human health, but also on wildlife. The overall aim of the EANOR project (2012-2015) is to assess the impacts of chronic exposure to enhanced radioactivity and chemical pollutants by studying the diversity of plant and soil invertebrate populations at two field sites. The first is a radium contaminated site in the Vodny area of the Komi Republic, Russia. Between 1931 and 1956, this was the main location of Soviet radium production. Wastes from the industry caused contamination of the environment, leading to high levels of radionuclides, heavy metals and rare-earth elements in the surroundings. The prolonged exposure of the ecosystem, combined with relatively low human activities, makes the site an excellent field laboratory for investigating the long-term effects of pollution. The second site is metal mining (Fe, Au, Ag, Mn, Mo, Cu, Pb and Zn) and industrial area on the Eastern Black Sea Region, Turkey, having elevated levels of both heavy metals and radionuclides for many decades. Eastern Black Sea Region is a mountainous area covered with dense forests, where numerous rivers and torrents flow through gorges and is characterized by heavy rainfall, humid summers, and mild winters. Based on these conditions, the region is rich in biological diversity. Joint field expeditions have been carried out in 2012 and 2013 with the objective of documenting levels of radionuclides and other chemical contaminants in soils and organisms, and assessing plant and soil invertebrate biodiversity. Measurement of a range of biomarkers, including soil meta

Annual report of department of research reactor, 2000. April 1, 2000 - March 31, 2001

International Nuclear Information System (INIS)

2002-02-01

The Department of Research Reactor is responsible for the operation, Maintenance, utilization of the JRR-3 and the JRR-4 and for the related R and D. Besides RI production including its R and D are carried out. This report describes the activities of the department in fiscal year of 2000 and it also includes some of the technical topics on the works mentioned above. As for the research reactors, we carried out the operation, maintenance, the utilization of irradiation and neutron beam experiments, technical management including fuels and water chemistry, radiation monitoring as related R and D works. RI Production and its R and D works were conducted as well. The international cooperations between the developing countries and the department were also made concerning the operation, utilization and safety analysis for research reactors. Although the term 'JRR-3M' was used to denote the JRR-3M modified 1990 until the 2000 annual report of the Department of Research Reactor, the term 'JRR-3' will be used from this annual report because the JRR-3 has been operated for about 10 years since the modification and is now under further modification and upgrading study. (author)

pyJac: Analytical Jacobian generator for chemical kinetics

Science.gov (United States)

Niemeyer, Kyle E.; Curtis, Nicholas J.; Sung, Chih-Jen

2017-06-01

Accurate simulations of combustion phenomena require the use of detailed chemical kinetics in order to capture limit phenomena such as ignition and extinction as well as predict pollutant formation. However, the chemical kinetic models for hydrocarbon fuels of practical interest typically have large numbers of species and reactions and exhibit high levels of mathematical stiffness in the governing differential equations, particularly for larger fuel molecules. In order to integrate the stiff equations governing chemical kinetics, generally reactive-flow simulations rely on implicit algorithms that require frequent Jacobian matrix evaluations. Some in situ and a posteriori computational diagnostics methods also require accurate Jacobian matrices, including computational singular perturbation and chemical explosive mode analysis. Typically, finite differences numerically approximate these, but for larger chemical kinetic models this poses significant computational demands since the number of chemical source term evaluations scales with the square of species count. Furthermore, existing analytical Jacobian tools do not optimize evaluations or support emerging SIMD processors such as GPUs. Here we introduce pyJac, a Python-based open-source program that generates analytical Jacobian matrices for use in chemical kinetics modeling and analysis. In addition to producing the necessary customized source code for evaluating reaction rates (including all modern reaction rate formulations), the chemical source terms, and the Jacobian matrix, pyJac uses an optimized evaluation order to minimize computational and memory operations. As a demonstration, we first establish the correctness of the Jacobian matrices for kinetic models of hydrogen, methane, ethylene, and isopentanol oxidation (number of species ranging 13-360) by showing agreement within 0.001% of matrices obtained via automatic differentiation. We then demonstrate the performance achievable on CPUs and GPUs using py

37 CFR 1.705 - Patent term adjustment determination.

Science.gov (United States)

2010-07-01

... 37 Patents, Trademarks, and Copyrights 1 2010-07-01 2010-07-01 false Patent term adjustment determination. 1.705 Section 1.705 Patents, Trademarks, and Copyrights UNITED STATES PATENT AND TRADEMARK OFFICE, DEPARTMENT OF COMMERCE GENERAL RULES OF PRACTICE IN PATENT CASES Adjustment and Extension of Patent Term...

Reliability performance testing of totally encapsulating chemical protective suits

International Nuclear Information System (INIS)

Johnson, J.S.; Swearengen, P.M.

1991-01-01

The need to assure a high degree of reliability for totally encapsulating chemical protective (TECP) suits has been recognized by Lawrence Livermore National Laboratory's (LLNL) Hazards Control Department for some time. The following four tests were proposed as necessary to provide complete evaluation of TECP suit performance: 1. Quantitative leak test (ASTM draft), 2. Worst-case chemical exposure test (conceptual), 3. Pressure leak-rate test (complete, ASTM F1057-87), and 4. Chemical leak-rate test (ASTM draft). This paper reports on these tests which should be applied to measuring TECP suit performance in two stages: design qualification tests and field use tests. Test 1, 2, and 3 are used as design qualification tests, and tests 3 and 4 are used as field use tests

Chemical Applications of Second Harmonic Rayleigh Scattering ...

Indian Academy of Sciences (India)

Chemical Applications of Second Harmonic Rayleigh Scattering Puspendu Kumar Das Department of Inorganic and Physical Chemistry Indian Institute of Science Bangalore 560012, India pkdas@ipc.iisc.ernet.in · Slide 2 · Slide 3 · Slide 4 · Slide 5 · Slide 6 · Slide 7 · Slide 8 · Slide 9 · Slide 10 · Slide 11 · Slide 12 · Slide 13.

Chemical and Petrochemical Sector

Energy Technology Data Exchange (ETDEWEB)

NONE

2009-07-01

This publication is a background document on the global chemical and petrochemical sector for the IEA publication Energy Technology Transitions in Industry (IEA, 2009). It provides further, more detailed information on the methodology and data issues for energy efficiency indicators for the sector. The indicators discussed offer insight regarding the energy efficiency improvement potential in the short- to medium-term (by proven technologies).

Incidence and characteristics of chemical burns.

Science.gov (United States)

Koh, Dong-Hee; Lee, Sang-Gil; Kim, Hwan-Cheol

2017-05-01

Chemical burns can lead to serious health outcomes. Previous studies about chemical burns have been performed based on burn center data so these studies have provided limited information about the incidence of chemical burns at the national level. The aim of this study was to evaluate the incidence and characteristics of chemical burns using nationwide databases. A cohort representing the Korean population, which was established using a national health insurance database, and a nationwide workers' compensation database were used to evaluate the incidence and characteristics of chemical burns. Characteristics of the affected body region, depth of burns, industry, task, and causative agents were analyzed from two databases. The incidence of chemical burns was calculated according to employment status. The most common regions involving chemical burns with hospital visits were the skin followed by the eyes. For skin lesions, the hands and wrists were the most commonly affected regions. Second degree burns were the most common in terms of depth of skin lesions. The hospital visit incidence was 1.96 per 10,000 person-year in the general population. The compensated chemical burns incidence was 0.17 per 10,000 person-year. Employees and the self-employed showed a significantly increased risk of chemical burns undergoing hospital visits compared to their dependents. Chemical burns on the skin and eyes are almost equally prevalent. The working environment was associated with increased risk of chemical burns. Our results may aid in estimating the size of the problem and prioritizing prevention of chemical burns. Copyright © 2016 Elsevier Ltd and ISBI. All rights reserved.

Physician Assistants Contribution to Emergency Department Productivity

Directory of Open Access Journals (Sweden)

Christopher Brook, MD

2012-05-01

Full Text Available Introduction: The objective of this report is to determine physician assistant (PA productivity in anacademic emergency department (ED and to determine whether shift length or department censusimpact productivity.Methods: A retrospective chart review was conducted at a tertiary ED during June and July of 2007.Productivity was calculated as the mean number of patients seen each hour. Analysis of variance wasused to compare the productivity of different length shifts, and linear regression analysis was used toassess the relationship between productivity and department volume.Results: One hundred sixty PA shifts were included. Shifts ranged from 4 to 13 hours. Meanproductivity was 1.16 patients per hour (95% confidence interval [CI] ¼ 1.12–1.20. Physicianassistants generated a mean of 2.35 relative value units (RVU per hour (95% CI¼1.98–2.72. Therewas no difference in productivity on different shift lengths (P¼0.73. There was no correlation betweendepartmental census and productivity, with an R2 (statistical term for the coefficient of determination of0.01.Conclusion: In the ED, PAs saw 1.16 patients and generated 2.35 RVUs per hour. The length of theshift did not affect productivity. Productivity did not fluctuate significantly with changing departmentalvolume.

Investigations on the Chemical Degradation of Silver Gelatine Prints

OpenAIRE

Maha Ahmed ALI; Mona Fouad ALI; Mohammed Osama SAKER; Abdel Azez El Bayoumi ABDEL ALEEM; Khaled Ibrahim EL NAGAR

2012-01-01

Photographs are considered composite objects with complex chemical and physical structures. Therefore they are more prone to damage as compared to other objects. Chemical degradation is by far the most common decay form found among photographic collections. This study investigates the chemical degradation of silver gelatin prints (DOP) and the reaction of the image, silver, gelatin, and paper to accelerated aging, to the action of light, and oxidizing gases, in terms of their physical and che...

Acute and Long-Term Impact of Chemical Weapons: Lessons from the Iran-Iraq War.

Science.gov (United States)

Haines, D D; Fox, S C

2014-07-01

Chemical weapons have given the human experience of warfare a uniquely terrifying quality that has inspired a general repugnance and led to periodic attempts to ban their use. Nevertheless, since ancient times, toxic agents have been consistently employed to kill and terrorize target populations. The evolution of these weapons is examined here in ways that may allow military, law enforcement, and scientific professionals to gain a perspective on conditions that, in the past, have motivated their use - both criminally and as a matter of national policy during military campaigns. Special emphasis is placed on the genocidal use of chemical weapons by the regime of Saddam Hussein, both against Iranians and on Kurdish citizens of his own country, during the Iran-Iraq War of 1980-88. The historical development of chemical weapons use is summarized to show how progressively better insight into biochemistry and physiology was adapted to this form of warfare. Major attributes of the most frequently used chemical agents and a description of how they affected military campaigns are explained. Portions of this review describing chemical-casualty care devote particular focus to Iranian management of neurotoxic (nerve) agent casualties due to the unique nature of this experience. Both nerve and blistering "mustard" agents were used extensively against Iranian forces. However, Iran is the only nation in history to have sustained large-scale attacks with neurotoxic weapons. For this reason, an understanding of the successes and failures of countermeasures to nerve-agent use developed by the Iranian military are particularly valuable for future civil defense and military planning. A detailed consideration of these strategies is therefore considered. Finally, the outcomes of clinical research into severe chronic disease triggered by mustard-agent exposure are examined in the context of the potential of these outcomes to determine the etiology of illness among US and Allied veterans

Inorganic chemical composition and chemical reactivity of settled dust generated by the World Trade Center building collapse: Chapter 12

Science.gov (United States)

Plumlee, Geoffrey S.; Hageman, Philip L.; Lamothe, Paul J.; Ziegler, Thomas L.; Meeker, Gregory P.; Theodorakos, Peter M.; Brownfield, Isabelle; Adams, Monique G.; Swayze, Gregg A.; Hoefen, Todd M.; Taggart, Joseph E.; Clark, Roger N.; Wilson, S.; Sutley, Stephen J.

2009-01-01

Samples of dust deposited around lower Manhattan by the September 11, 2001, World Trade Center (WTC) collapse have inorganic chemical compositions that result in part from the variable chemical contributions of concrete, gypsum wallboard, glass fibers, window glass, and other materials contained in the buildings. The dust deposits were also modified chemically by variable interactions with rain water or water used in street washing and fire fighting. Chemical leach tests using deionized water as the extraction fluid show the dust samples can be quite alkaline, due primarily to reactions with calcium hydroxide in concrete particles. Calcium and sulfate are the most soluble components in the dust, but many other elements are also readily leached, including metals such as Al, Sb, Mo Cr, Cu, and Zn. Indoor dust samples produce leachates with higher pH, alkalinity, and dissolved solids than outdoor dust samples, suggesting most outdoor dust had reacted with water and atmospheric carbon dioxide prior to sample collection. Leach tests using simulated lung fluids as the extracting fluid suggest that the dust might also be quite reactive in fluids lining the respiratory tract, resulting in dissolution of some particles and possible precipitation of new phases such as phosphates, carbonates, and silicates. Results of these chemical characterization studies can be used by health scientists as they continue to track and interpret health effects resulting from the short-term exposure to the initial dust cloud and the longer-term exposure to dusts resuspended during cleanup.

Near-Term Electric Vehicle Program. Phase II: Mid-Term Summary Report.

Energy Technology Data Exchange (ETDEWEB)

None

1978-08-01

The Near Term Electric Vehicle (NTEV) Program is a constituent elements of the overall national Electric and Hybrid Vehicle Program that is being implemented by the Department of Energy in accordance with the requirements of the Electric and Hybrid Vehicle Research, Development, and Demonstration Act of 1976. Phase II of the NTEV Program is focused on the detailed design and development, of complete electric integrated test vehicles that incorporate current and near-term technology, and meet specified DOE objectives. The activities described in this Mid-Term Summary Report are being carried out by two contractor teams. The prime contractors for these contractor teams are the General Electric Company and the Garrett Corporation. This report is divided into two discrete parts. Part 1 describes the progress of the General Electric team and Part 2 describes the progress of the Garrett team.

Regulatory impact of nuclear reactor accident source term assumptions. Technical report

International Nuclear Information System (INIS)

Pasedag, W.F.; Blond, R.M.; Jankowski, M.W.

1981-06-01

This report addresses the reactor accident source term implications on accident evaluations, regulations and regulatory requirements, engineered safety features, emergency planning, probabilistic risk assessment, and licensing practice. Assessment of the impact of source term modifications and evaluation of the effects in Design Basis Accident analyses, assuming a change of the chemical form of iodine from elemental to cesium iodide, has been provided. Engineered safety features used in current LWR designs are found to be effective for all postulated combinations of iodine source terms under DBA conditions. In terms of potential accident consequences, it is not expected that the difference in chemical form between elemental iodine and cesium iodide would be significant. In order to account for the current information on source terms, a spectrum of accident scenerios is discussed to realistically estimate the source terms resulting from a range of potential accident conditions

Departments as Agents of Change

Science.gov (United States)

Lagowski, J. J.

1996-07-01

the principal agents for recasting American higher education might appear to some like putting a fox in charge of the chicken coop. For many observers, departments epitomize everything that is wrong with higher education. Departments have come to be viewed as the agents of a discipline that draw faculty attention away from their home institution, and seek to sustain individual privilege at the expense of initiatives designed to enhance learning and teaching. Departments have been portrayed as clans of arrogant experts accountable only to their own personal agendas and to their disciplines. From this rather harsh point of view, departments have become privatized as they and their institutions strive to enhance their reputations through the faculty they hire, often at the expense of undergraduate teaching. Faculty define their interests in increasingly narrow terms, which in turn is often reflected in the courses they teach. As individual courses come to represent the increasingly specialized views of their faculty-owners, the curriculum begins to lose focus and coherence. Thus, the privatization of faculty effort has far-reaching effects on an institution's educational mission. In spite of its apparent flaws, the department, more than any other unit, stands the best chance of providing the basis of change that can renew higher education. Although individual faculty members may find their greatest rewards elsewhere, a department can only be rewarded on the basis of the combined efforts and accomplishments of its collective faculty. This fact alone makes departments an obvious vehicle for change. Furthermore, institutional support for a discipline is focused in the department, as is the institution's responsibility for teaching undergraduates. For a department to compete effectively in the new marketplace, it must ensure that its members remain active scholars who are not only expert in their primary fields, but also open to inter- and cross-disciplinary opportunities

Long-term continuous administration of a hydro-ethanolic extract of ...

African Journals Online (AJOL)

Long-term continuous administration of a hydro-ethanolic extract of Synedrella ... Ghana, P.O Box LG 43, Legon, Accra, Ghana 2Department of Animal Experimentation, Noguchi Memorial. Institute for ..... short-or long-term administration.

Chemical durability of glasses containing radioactive fission product waste

International Nuclear Information System (INIS)

Mendel, J.E.; Ross, W.A.

1974-04-01

Measurements made to determine the chemical durability of glasses for disposal of radioactive waste are discussed. The term glass covers materials varying from true glass with only minute quantities of crystallites, such as insoluble RuO 2 , to quasi glass-ceramics which are mostly crystalline. Chemical durability requirements and Soxhlet extractor leach tests are discussed

Effect of thermal, chemical and thermo-chemical pre-treatments to enhance methane production

Energy Technology Data Exchange (ETDEWEB)

Rafique, Rashad; Nizami, Abdul-Sattar; Murphy, Jerry D.; Kiely, Gerard [Department of Civil and Environmental Engineering, University College Cork (Ireland); Poulsen, Tjalfe Gorm [Department of Biotechnology, Chemistry and Environmental Engineering, Aalborg University (Denmark); Asam, Zaki-ul-Zaman [Department of Civil Engineering, National University of Ireland Galway (Ireland)

2010-12-15

The rise in oil price triggered the exploration and enhancement of various renewable energy sources. Producing biogas from organic waste is not only providing a clean sustainable indigenous fuel to the number of on-farm digesters in Europe, but also reducing the ecological and environmental deterioration. The lignocellulosic substrates are not completely biodegraded in anaerobic digesters operating at commercial scale due to their complex physical and chemical structure, which result in meager energy recovery in terms of methane yield. The focus of this study is to investigate the effect of pre-treatments: thermal, thermo-chemical and chemical pre-treatments on the biogas and methane potential of dewatered pig manure. A laboratory scale batch digester is used for these pre-treatments at different temperature range (25 C-150 C). Results showed that thermo-chemical pretreatment has high effect on biogas and methane potential in the temperature range (25-100 C). Maximum enhancement is observed at 70 C with increase of 78% biogas and 60% methane production. Thermal pretreatment also showed enhancement in the temperature range (50-10 C), with maximum enhancement at 100 C having 28% biogas and 25% methane increase. (author)

Dow's chemical exposure index guide

International Nuclear Information System (INIS)

Marshall, J.T.; Mundt, A.

1995-01-01

A number of events in the 1970's and 1980's impacted the course of process safety. Incidents such as Flixborough, Seveso, Three-Mile Island, and Bhopal are well known throughout industry and are recognized as examples of major disasters. Even though events leading up to these disasters were completely different they had one common element between them: a substance was released from a manufacturing unit, became airborne and presented a hazard of such magnitude as to place the safety of both employees and the surrounding public in jeopardy. As a result, industry became increasingly concerned regarding potential loss, in human and economic terms, as plants and equipment grew in size. The Flixborough incident raised the level of concern for process safety, particularly in terms of the hazards presented by fire and explosion. Seveso and Three-Mile Island emphasized the need to consider far-field exposure. The Bhopal incident created an urgent need to recognize and understand the expected downwind impact of potential releases of acutely toxic substances to the air. In order to meet this need, the Dow Chemical Company, a recognized leader in the area of safety and loss prevention, presented a Chemical Exposure Index in 1986. AIChE has recently published an updated version entitled Dow's Chemical Exposure Index Guide. 7 refs., 5 figs

Military chemical warfare agent human subjects testing: part 1--history of six-decades of military experiments with chemical warfare agents.

Science.gov (United States)

Brown, Mark

2009-10-01

Military chemical warfare agent testing from World War I to 1975 produced thousands of veterans with concerns of possible long-term health consequences. Clinical and research evaluation of potential long-term health effects has been difficult because the exposures occurred decades ago, the identity of troops exposed and exposure magnitudes are uncertain, and acute effects during experiments poorly documented. In contrast, a companion article describes the large amount of information available about the specific agents tested and their long-term health effects. This short history describes U.S. military chemical-agent experiments with human subjects and identifies tested agents. Finally, the demonstrated need to anticipate future health concerns from military personnel involved in such military testing suggests current and future military researchers should be required, by law and regulation, to fully record the identity of those exposed, relevant exposure magnitude, and complete medical information for all subjects. New study protocols and institutional review board approvals for research involving military personnel should reflect this need.

Chemical Dynamics at the Advanced Light Source

International Nuclear Information System (INIS)

Baer, T.; Berrah, N.; Fadley, C.; Moore, C.B.; Neumark, D.M.; Ng, C.Y.; Ruscic, B.; Smith, N.V.; Suits, A.G.; Wodtke, A.M.

1999-01-01

A day-long retreat was held January 15, 1999 to chart the future directions for chemical dynamics studies at the Advanced Light Source. This represents an important period for the Chemical Dynamics Beamline, as the hardware is well-developed, most of the initial experimental objectives have been realized and the mission is now to identify the future scientific priorities for the beamline and attract users of the highest caliber. To this end, we have developed a detailed scientific program for the near term; identified and prioritized the long range scientific opportunities, identified essential new hardware, and outlined an aggressive outreach program to involve the chemical physics community

Metallurgy Department

DEFF Research Database (Denmark)

Risø National Laboratory, Roskilde

The activities of the Metallurgy Department at Risø during 1981 are described. The work is presented in three chapters: General Materials Research, Technology and Materials Development, Fuel Elements. Furthermore, a survey is given of the department's participation in international collaboration...

The Comparison of Emphatic Tendencies of the Management Department Students

Science.gov (United States)

Belli, Emre; Yildirim, Fatih; Naktiyok, Serkan; Gurbuz, Ali; Aydin, Ali Dursun

2015-01-01

The aim of the current research is to make a comparison between the university students majoring at the department of sport management at Kafkas University and Atatürk University in terms of empathy level. For data collection, "Emphatic Tendency Scale", which was developed by Dökmen (1994) and which included 20 items, was administered to…

36 CFR 251.103 - Mediation of term grazing permit disputes.

Science.gov (United States)

2010-07-01

... 36 Parks, Forests, and Public Property 2 2010-07-01 2010-07-01 false Mediation of term grazing... Lands § 251.103 Mediation of term grazing permit disputes. (a) Decisions subject to mediation. In those States with Department of Agriculture certified mediation programs, any holder of a term grazing permit...

Medium and Long-term Opportunities and Risks of the Biotechnological Production of Bulk Chemicals from Renewable Resources. The Potential of White Biotechnology. The BREW Project. Final report

Energy Technology Data Exchange (ETDEWEB)

Patel, M.; Crank, M.; Dornburg, V.; Hermann, B.; Roes, L. [Department of Science, Technology and Society NWS, Utrecht University, Utrecht (Netherlands); Huesing, B. [Fraunhofer Institute for Systems and Innovation Research FhG-ISl, Karlsruhe (Germany); Overbeek, L. [Plant Research International PRI, Wageningen (Netherlands); Terragni, F.; Recchia, E. [CERISS, Centro per I' Educazione, la Ricerca, I' lnformazione su Scienza e Society, Milan (Italy)

2006-09-15

This study investigates the medium and long-term opportunities and risks of the biotechnological production of organic chemicals. The objective is to gain better understanding of the techno-economic and the societal viability of White Biotechnology in the coming decades. The key research questions are which products could be made with White Biotechnology, whether these products can contribute to savings of energy use and greenhouse gas (GHG) emissions, under which conditions the products become economically viable, which risks may originate from the use of genetically modified organisms (GMO) in fermentation and what the public perception is. The main purpose of Chapter 2 is to provide an overview of emerging key White Biotechnology products and to explain which chemicals could be produced on their basis. For a selection of these products, detailed environmental and economic assessments are conducted in Chapter 3 (in specific terms, i.e. per tonne of product). Chapter 3 discusses also the so-called Generic Approach which is the methodology we developed and applied to assess future processes and processes, for which very little information is available. In Chapter 4, three scenario projections are developed for Europe (EU-25), thereby assuming benign, moderate and disadvantageous conditions for bio-based chemicals. The purpose of this chapter is hence to understand to which extent restructuring of the chemical sector might occur under which conditions. In Chapter 5, the risks related to the use of White Biotechnology are addressed. The main purpose of this chapter is to give insight into the main risk components influencing the overall risk and of the knowledge gaps. Both conventional risks (e.g., human toxicity and accidents) and risks related to generic modification (e.g., horizontal gene transfer) are analyzed. Since the public perception may play an important role for the implementation of White Biotechnology on a large scale, these issues are discussed in

Glossary of CERCLA-related terms and acronyms

International Nuclear Information System (INIS)

1991-10-01

This glossary contains CERCLA-related terms that are most often encountered in the US Department of Energy (DOE) Environmental Restoration and Emergency Preparedness activities. Detailed definitions are included for key terms. The definitions included in this glossary are taken from the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), as amended, related federal rulemakings (e.g., 40 CFR 300, National Oil and Hazardous Substances Pollution Contingency Plan), assorted guidance documents prepared by the US Environmental Protection Agency (EPA), and DOE Order 5400.4. The source of each term is noted after the term. Terms presented in this document reflect revised and new definitions published before June 1, 1991. 20 refs

Risk factors associated with short term mortality changes over time, after arrival to the emergency department

DEFF Research Database (Denmark)

Bech, Camilla Nørgaard; Brabrand, Mikkel; Mikkelsen, Søren

2018-01-01

, 0-2 day, 3-7 day and 8-30 day mortality. The degree of acuteness at arrival defined by urgency-level, physician-assisted transfer to the Emergency Department and abnormal vital parameters are associated with 0-2 day mortality. High temperature at arrival shows no association in either mortality...

Dutch chemical producers pledge emissions cuts

International Nuclear Information System (INIS)

Chynoweth, E.; Schoenmakers, J.

1993-01-01

Dutch chemical producers have negotiated a long-term agreement with government ministries to reduce emissions of a wide range of chemicals. Industry association Vereniging van de Nederlandse Chemische Industrie (VNCI; Leidschendam) says implementing the commitment will cost companies Dfl 10 billion ($5.4 billion) between 1993 and 2000. VNCI technical director Wim Quik welcomes the accord, which he describes as a management contract, saying, Rather than have legislation, there is a certain adjustment available. Peter Santen, managing director of midsized chemicals player Cindu Chemicals (Uithoorn, the Netherlands) voices some concern about the details of the accord, but adds, we are flexible in trying to agree with the contents of the covenant [it] is better than having new rules from law. The Dutch government, traditionally eager for consensus, has struck a number of such deals with Dutch industries - including packaging, metal, and tire - to reduce emissions and set up environmental management programs. The effort is based on the government's National Environmental Policy Plans - NMP and NMP Plus. Targets for emissions reduction by the chemical industry were provided by a government-funded environmental research institute

Challenges in reporting on predetermined objectives to the Auditor-General: The case of Limpopo provincial departments

OpenAIRE

Melvin Diedericks

2017-01-01

Limpopo provincial departments like all other South African government departments are required to report on performance against predetermined objectives in terms of Section 40 of the Public Finance Management Act 1 of 1999, read in conjunction with Section 5.1.1 of the Treasury Regulations. The purpose of this article is to report on a study that was undertaken to establish the challenges faced by the Limpopo provincial departments in reporting on performance against predetermined objectives...

Summaries of FY 1979 research in the chemical sciences

Energy Technology Data Exchange (ETDEWEB)

1980-05-01

The purpose of this report is to help those interested in research supported by the Department of Energy's Division of Chemical Sciences, which is one of six Divisions of the Office of Basic Energy Sciences in the Office of Energy Research. Chemists, physicists, chemical engineers and others who are considering the possibility of proposing research for support by this Division wll find the booklet useful for gauging the scope of the program in basic research, and the relationship of their interests to the overall program. These smmaries are intended to provide a rapid means for becoming acquainted with the Chemical Sciences program for members of the scientific and technological public, and interested persons in the Legislative and Executive Branches of the Government, in order to indicate the areas of research supported by the Division and energy technologies which may be advanced by use of basic knowledge discovered in this program. Scientific excellence is a major criterion applied in the selection of research supported by Chemical Sciences. Another important consideration is the identifying of chemical, physical and chemical engineering subdisciplines which are advancing in ways which produce new information related to energy, needed data, or new ideas.

Summaries of FY 1979 research in the chemical sciences

International Nuclear Information System (INIS)

1980-05-01

The purpose of this report is to help those interested in research supported by the Department of Energy's Division of Chemical Sciences, which is one of six Divisions of the Office of Basic Energy Sciences in the Office of Energy Research. Chemists, physicists, chemical engineers and others who are considering the possibility of proposing research for support by this Division wll find the booklet useful for gauging the scope of the program in basic research, and the relationship of their interests to the overall program. These smmaries are intended to provide a rapid means for becoming acquainted with the Chemical Sciences program for members of the scientific and technological public, and interested persons in the Legislative and Executive Branches of the Government, in order to indicate the areas of research supported by the Division and energy technologies which may be advanced by use of basic knowledge discovered in this program. Scientific excellence is a major criterion applied in the selection of research supported by Chemical Sciences. Another important consideration is the identifying of chemical, physical and chemical engineering subdisciplines which are advancing in ways which produce new information related to energy, needed data, or new ideas

Chemical Industry Waste water Treatment

International Nuclear Information System (INIS)

Nasr, F.A.; Doma, H.S.; El-Shafai, S.A.; Abdel-HaJim, H.S.

2004-01-01

Treatment of chemical industrial wastewater from building and construction chemicals factory and plastic shoes manufacturing factory was investigated. The two factories discharge their wastewater into the public sewerage network. The results showed the wastewater discharged from the building and construction chemicals factory was highly contaminated with organic compounds. The average values of COD and BOD were 2912 and 150 mg O 2 /l. Phenol concentration up to 0.3 mg/l was detected. Chemical treatment using lime aided with ferric chloride proved to be effective and produced an effluent characteristics in compliance with Egyptian permissible limits. With respect to the other factory, industrial wastewater was mixed with domestic wastewater in order to lower the organic load. The COD, BOD values after mixing reached 5239 and 2615 mg O 2 /l. The average concentration of phenol was 0.5 mg/l. Biological treatment using activated sludge or rotating biological contactor (RBe) proved to be an effective treatment system in terms of producing an effluent characteristic within the permissible limits set by the law

Session 1984-85. Radioactive waste. Minutes of evidence, Wednesday 23 October 1985. Department of the Environment

International Nuclear Information System (INIS)

1985-01-01

The Environment Select Committee of the House of Commons received a memorandum from the Department of the Environment on radioactive waste and reprocessing, under the headings: long-term management of spent fuel; comparison of wastes arising from reprocessing and storage/disposal of spent fuel; the spent fuel assemblies; waste arising from spent-fuel management at reactor sites; reprocessing wastes; long-term storage and direct disposal of spent fuel; liquid and gaseous discharges; CEGB note on the drying-off and subsequent long term storage of spent magnox fuel. The Minister of the Environment and representatives of the Department of the Environment were examined on the subject of the memorandum. The problems of finding sites suitable for radioactive waste storage/disposal and acceptable to public opinion were discussed. (U.K.)

Glass enamel and glass-ceramic coatings for chemical apparatus

International Nuclear Information System (INIS)

Es'kov, A.S.; Oleinik, M.I.; Shabrova, E.A.

1984-01-01

Among the known anticorrosion coatings used in chemical engineering, glass enamel base coatings are distinguished by such advantages as a high degree of continuity and chemical resistance. The paper describes basic principles for the creation of acid and alkali resistant glass enamel and ceramic coatings for chemical apparatus. As the result of investgations, glass enamel coatings with increased electrical conductivity and also experimental production compositions of chemical, temperature and radiation resistant coatings for protection of chemical equipment of 12Kh18N10T stainless steel have been developed. The coatings have successfully passed testing under service conditions. A new type of coating is short-term glass enamel, which may be recommended for use in chemical machinery manufacturing and other branches of industry in oxidation-free heating and forming of stainless steels

Annual progress report of the Condensed Matter Physics and Chemistry Department. 1 January - 31 December 2000

International Nuclear Information System (INIS)

Lebech, B.

2001-03-01

The Condensed Matter Physics and Chemistry Department is concerned with both fundamental and applied research into the physical and chemical properties of materials. The principal activities in the year 2000 are presented in this progress report. The research in physics is concentrated on neutron and x-ray scattering measurements and the problems studied include two- and three-dimensional structures, magnetic ordering and spin dynamics, superconductivity, phase transitions and nano-scale structures. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface-modified polymers, and supramolecular structures. Theoretical work related to these problems is undertaken, including Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au)

Annual progress report of the Condensed Matter Physics and Chemistry Department. 1 January - 31 December 1999

Energy Technology Data Exchange (ETDEWEB)

Lebech, B [ed.

2000-02-01

The Condensed Matter Physics and Chemistry Department is concerned with both fundamental and applied research into the physical and chemical properties of materials. The principal activities in the year 1999 are presented in this progress report. The research in physics is concentrated on neutron and x-ray scattering measurements and the problems studied include two- and three-dimensional structures, magnetic ordering and spin dynamics, superconductivity, phase transitions and nano-scalestructures. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface-modified polymers, and supramolecular structures. Theoretical work related to these problems is undertaken, including Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au)

Annual progress report of the Condensed Matter Physics and Chemistry Department. 1 January - 31 December 1999

International Nuclear Information System (INIS)

Lebech, B.

2000-02-01

The Condensed Matter Physics and Chemistry Department is concerned with both fundamental and applied research into the physical and chemical properties of materials. The principal activities in the year 1999 are presented in this progress report. The research in physics is concentrated on neutron and x-ray scattering measurements and the problems studied include two- and three-dimensional structures, magnetic ordering and spin dynamics, superconductivity, phase transitions and nano-scale structures. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface-modified polymers, and supramolecular structures. Theoretical work related to these problems is undertaken, including Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au)

Annual progress report of the Condensed Matter Physics and Chemistry Department 1 January - 31 December 1997

International Nuclear Information System (INIS)

Nielsen, M.; Bechgaard, K.; Clausen, K.N.; Feidenhans'l, R.; Johannsen, I.

1998-01-01

The Condensed Matter Physics and Chemistry Department is concerned with both fundamental and applied research into the physical and chemical properties of materials. The principal activities in the year 1997 are presented in this progress report. The research in physics in concentrated on neutron and x-ray scattering measurements and the problems studied include two- and three-dimensional structures, magnetic ordering and spin dynamics, superconductivity, phase transitions and nano-scale structures. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface-modified polymers, and supramolecular structures. Theoretical work related to these problems in undertaken, including Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au)

12 CFR 250.182 - Terms defining competitive effects of proposed mergers.

Science.gov (United States)

2010-01-01

... Department of Justice on the competitive factors involved. Standard descriptive terms are used by the Board, the Federal Deposit Insurance Corporation, and the Comptroller of the Currency. The terms and their...

Advanced chemical analysis service for elements, radionuclides and phases

International Nuclear Information System (INIS)

Sansoni, B.

1986-01-01

A review is given on the structure, organisation and performance of the chemical analysis service of the Central Department for Chemical Analysis at the Kernforschungsanlage Juelich GmbH. The research and development programs together with the infrastructure of the Centre afford to analyse almost all stable elements of the periodical table in almost any material. The corresponding chemical analysis service has been organized according to a new modular system of analytical steps. According to this, the most complicated and, therefore, most general case of an analytical scheme for element and radionuclide analysis in any type of material can be differentiated into about 14 different steps, the modules. They are more or less independent of the special problem. The laboratory is designed and organized according to these steps. (orig./PW) [de

Molecular activation analysis for chemical speciation studies

International Nuclear Information System (INIS)

Chai-Chifang

1998-01-01

The term of Molecular Activation Analysis (MAA) refers to an activation analysis method that is able to provide information about the chemical species of elements in system of interests, though its definition has remained to be assigned. Its development is strongly stimulated by the urgent need to know the chemical species of elements, because the total concentrations are often without any meaning when assessing health or environmental risks of trace elements.In practice, the MAA is a combination of conventional instrumental or radiochemical activation analysis and physical, chemical or biochemical separation techniques. The MAA is able to play a particular role in speciation studies. However, the critical point in the MAA is that it is not permitted to change the primitive chemical species of elements in systems, or the change has to be under control; in the meantime it is not allowed to form the 'new artifact' originally not present in systems. Some practical examples of MAA for chemical species research performed recently in our laboratory will be presented as follows: Chemical species of platinum group elements in sediment; Chemical species of iodine in marine algae; Chemical species of mercury in human tissues; Chemical species of selenium in corn; Chemical species of rare earth elements in natural plant, etc. The merits and limitations of MAA will be described as well. (author)

Annual report of department of research reactor, 2000. April 1, 2000 - March 31, 2001

Energy Technology Data Exchange (ETDEWEB)

NONE

2002-02-01

The Department of Research Reactor is responsible for the operation, Maintenance, utilization of the JRR-3 and the JRR-4 and for the related R and D. Besides RI production including its R and D are carried out. This report describes the activities of the department in fiscal year of 2000 and it also includes some of the technical topics on the works mentioned above. As for the research reactors, we carried out the operation, maintenance, the utilization of irradiation and neutron beam experiments, technical management including fuels and water chemistry, radiation monitoring as related R and D works. RI Production and its R and D works were conducted as well. The international cooperations between the developing countries and the department were also made concerning the operation, utilization and safety analysis for research reactors. Although the term 'JRR-3M' was used to denote the JRR-3M modified 1990 until the 2000 annual report of the Department of Research Reactor, the term 'JRR-3' will be used from this annual report because the JRR-3 has been operated for about 10 years since the modification and is now under further modification and upgrading study. (author)

Dioxin-like chemicals in bivalves and sediment collected from around Australia

Energy Technology Data Exchange (ETDEWEB)

Mueller, J.F.; Muller, R.; Goudkamp, K. [EnTox, The University of Queensland, Brisbane (AU)] (and others)

2004-09-15

The aquatic environment is a significant sink for persistent organic pollutants including dioxin-like chemicals. Besides continuous investigations into sources of higher chlorinated PCDD that have initially been found in soils, and later in dugong and sediments little is known about the levels of dioxin-like chemicals in Australia's aquatic environment. In 2002 the National Dioxin Program (NDP) was commissioned by the Department of Environment and Heritage, Australia. One focus of the NDP was to evaluate background levels of dioxin-like chemicals in Australia's environment. One component of the 'Environmental Levels' project aimed to identify dioxinlike chemicals in the aquatic environment including bivalves collected in both marine, estuarine and freshwater systems. Here we report results from the NDP aquatic study with a particular emphasis on the levels of dioxin-like chemicals in bivalves and sediments respectively in areas from where the bivalves were collected.

Plant Species Rather Than Climate Greatly Alters the Temporal Pattern of Litter Chemical Composition During Long-Term Decomposition

Science.gov (United States)

Li, Yongfu; Chen, Na; Harmon, Mark E.; Li, Yuan; Cao, Xiaoyan; Chappell, Mark A.; Mao, Jingdong

2015-10-01

A feedback between decomposition and litter chemical composition occurs with decomposition altering composition that in turn influences the decomposition rate. Elucidating the temporal pattern of chemical composition is vital to understand this feedback, but the effects of plant species and climate on chemical changes remain poorly understood, especially over multiple years. In a 10-year decomposition experiment with litter of four species (Acer saccharum, Drypetes glauca, Pinus resinosa, and Thuja plicata) from four sites that range from the arctic to tropics, we determined the abundance of 11 litter chemical constituents that were grouped into waxes, carbohydrates, lignin/tannins, and proteins/peptides using advanced 13C solid-state NMR techniques. Decomposition generally led to an enrichment of waxes and a depletion of carbohydrates, whereas the changes of other chemical constituents were inconsistent. Inconsistent convergence in chemical compositions during decomposition was observed among different litter species across a range of site conditions, whereas one litter species converged under different climate conditions. Our data clearly demonstrate that plant species rather than climate greatly alters the temporal pattern of litter chemical composition, suggesting the decomposition-chemistry feedback varies among different plant species.

Chemical Hazards and Safety Issues in Fusion Safety Design

International Nuclear Information System (INIS)

Cadwallader, L.C.

2003-01-01

Radiological inventory releases have dominated accident consequences for fusion; these consequences are important to analyze and are generally the most severe result of a fusion facility accident event. However, the advent of, or plan for, large-scale usage of some toxic materials poses the additional hazard of chemical exposure from an accident event. Examples of toxic chemicals are beryllium for magnetic fusion and fluorine for laser fusion. Therefore, chemical exposure consequences must also be addressed in fusion safety assessment. This paper provides guidance for fusion safety analysis. US Department of Energy (DOE) chemical safety assessment practices for workers and the public are reviewed. The US Environmental Protection Agency (EPA) has published some guidance on public exposure to releases of mixtures of chemicals, this guidance has been used to create an initial guideline for treating mixed radiological and toxicological releases in fusion; for example, tritiated hazardous dust from a tokamak vacuum vessel. There is no convenient means to judge the hazard severity of exposure to mixed materials. The chemical fate of mixed material constituents must be reviewed to determine if there is a separate or combined radiological and toxicological carcinogenesis, or if other health threats exist with radiological carcinogenesis. Recommendations are made for fusion facility chemical safety evaluation and safety guidance for protecting the public from chemical releases, since such levels are not specifically identified in the DOE fusion safety standard

Radiochemical and Chemical Constituents in Water from Selected Wells and Springs from the Southern Boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman Area, Idaho, 2002

Science.gov (United States)

Rattray, Gordon W.; Campbell, Linford J.

2004-01-01

The U.S. Geological Survey, Idaho Department of Water Resources, and the State of Idaho INEEL Oversight Program, in cooperation with the U.S. Department of Energy, sampled water from 17 sites as part of the sixth round of a long-term project to monitor water quality of the eastern Snake River Plain aquifer from the southern boundary of the Idaho National Engineering and Environmental Laboratory to the Hagerman area. The samples were collected from eight irrigation wells, three domestic wells, one stock well, one dairy well, one commercial well, one observation well, and two springs and analyzed for selected radiochemical and chemical constituents. One quality-assurance sample, a sequential replicate, also was collected and analyzed. Many of the radionuclide and inorganic-constituent concentrations were greater than the reporting levels and most of the organic-constituent concentrations were less than the reporting levels. However, none of the reported radiochemical- or chemical-constituent concentrations exceeded the maximum contaminant levels for drinking water established by the U.S. Environmental Protection Agency. Statistical evaluation of the replicate sample pair indicated that, with 95 percent confidence, 132 of the 135 constituent concentrations of the replicate pair were equivalent.

Chemical databases evaluated by order theoretical tools.

Science.gov (United States)

Voigt, Kristina; Brüggemann, Rainer; Pudenz, Stefan

2004-10-01

Data on environmental chemicals are urgently needed to comply with the future chemicals policy in the European Union. The availability of data on parameters and chemicals can be evaluated by chemometrical and environmetrical methods. Different mathematical and statistical methods are taken into account in this paper. The emphasis is set on a new, discrete mathematical method called METEOR (method of evaluation by order theory). Application of the Hasse diagram technique (HDT) of the complete data-matrix comprising 12 objects (databases) x 27 attributes (parameters + chemicals) reveals that ECOTOX (ECO), environmental fate database (EFD) and extoxnet (EXT)--also called multi-database databases--are best. Most single databases which are specialised are found in a minimal position in the Hasse diagram; these are biocatalysis/biodegradation database (BID), pesticide database (PES) and UmweltInfo (UMW). The aggregation of environmental parameters and chemicals (equal weight) leads to a slimmer data-matrix on the attribute side. However, no significant differences are found in the "best" and "worst" objects. The whole approach indicates a rather bad situation in terms of the availability of data on existing chemicals and hence an alarming signal concerning the new and existing chemicals policies of the EEC.

Long Term Care Minimum Data Set (MDS)

Data.gov (United States)

U.S. Department of Health & Human Services — The Long-Term Care Minimum Data Set (MDS) is a standardized, primary screening and assessment tool of health status that forms the foundation of the comprehensive...

Results of the 2010 Survey on Teaching Chemical Reaction Engineering

Science.gov (United States)

Silverstein, David L.; Vigeant, Margot A. S.

2012-01-01

A survey of faculty teaching the chemical reaction engineering course or sequence during the 2009-2010 academic year at chemical engineering programs in the United States and Canada reveals change in terms of content, timing, and approaches to teaching. The report consists of two parts: first, a statistical and demographic characterization of the…

NOAA's Office of Response and Restoration: Historical Oil and Chemical Spill Incidents Database

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The Historical Incidents database contains reports and images from oil and chemical spills that occurred between 1968 and 2002. The database includes reports on...

On the transition period from chemical to biological evolution

International Nuclear Information System (INIS)

Chela-Flores, J.

1991-06-01

We discuss the consequences of the hypothesis that biological evolution was contemporary with an important event in chemical evolution, namely, the induction of a small chiral bias by the electroweak neutral interaction, amplified by the Salam enhancement factor, which we discuss in terms of familiar crystallographic terms. (author). 18 refs, 3 tabs

Prediction of Chemical Function: Model Development and ...

Science.gov (United States)

The United States Environmental Protection Agency’s Exposure Forecaster (ExpoCast) project is developing both statistical and mechanism-based computational models for predicting exposures to thousands of chemicals, including those in consumer products. The high-throughput (HT) screening-level exposures developed under ExpoCast can be combined with HT screening (HTS) bioactivity data for the risk-based prioritization of chemicals for further evaluation. The functional role (e.g. solvent, plasticizer, fragrance) that a chemical performs can drive both the types of products in which it is found and the concentration in which it is present and therefore impacting exposure potential. However, critical chemical use information (including functional role) is lacking for the majority of commercial chemicals for which exposure estimates are needed. A suite of machine-learning based models for classifying chemicals in terms of their likely functional roles in products based on structure were developed. This effort required collection, curation, and harmonization of publically-available data sources of chemical functional use information from government and industry bodies. Physicochemical and structure descriptor data were generated for chemicals with function data. Machine-learning classifier models for function were then built in a cross-validated manner from the descriptor/function data using the method of random forests. The models were applied to: 1) predict chemi

Chemical Modification of Uniform Soils and Soils with High/Low Plasticity Index

OpenAIRE

Li, Xuanchi; Tao, Fei; Bobet, Antonio

2015-01-01

Lime and/or cement are used to treat weak subgrade soils during construction of highways. These chemicals are mixed with the soil to improve its workability, compactability and engineering properties. INDOT (Indiana Department of Transportation) has been using chemical modification of native soils for the past 20 years. In fact, 90% of current subgrade is treated, typically with quick lime, lime byproducts or cement. For pavement design, it is customary to not include any improvement of the s...

Future emission scenarios for chemicals that may deplete stratospheric ozone

International Nuclear Information System (INIS)

Hammitt, J.K; Camm, Frank; Mooz, W.E.; Wolf, K.A.; Bamezai, Anil; Connel, P.S.; Wuebbles, D.J.

1990-01-01

Scenarios are developed for long-term future emissions of seven of the most important manmade chemicals that may deplete ozone and the corresponding effect on stratospheric ozone concentrations is calculated using a one-dimensional atmospheric model. The scenarios are based on detailed analysis of the markets for products that use these chemicals and span a central 90% probability interval for the chemicals joint effect on calculated ozone abundance, assuming no additional regulations. (author). 22 refs., 2 figs., 5 tabs

Long-term energy efficiency analysis requires solid energy statistics: The case of the German basic chemical industry

International Nuclear Information System (INIS)

Saygin, D.; Worrell, E.; Tam, C.; Trudeau, N.; Gielen, D.J.; Weiss, M.; Patel, M.K.

2012-01-01

Analyzing the chemical industry’s energy use is challenging because of the sector’s complexity and the prevailing uncertainty in energy use and production data. We develop an advanced bottom-up model (PIE-Plus) which encompasses the energy use of the 139 most important chemical processes. We apply this model in a case study to analyze the German basic chemical industry’s energy use and energy efficiency improvements in the period between 1995 and 2008. We compare our results with data from the German Energy Balances and with data published by the International Energy Agency (IEA). We find that our model covers 88% of the basic chemical industry’s total final energy use (including non-energy use) as reported in the German Energy Balances. The observed energy efficiency improvements range between 2.2 and 3.5% per year, i.e., they are on the higher side of the values typically reported in literature. Our results point to uncertainties in the basic chemical industry’s final energy use as reported in the energy statistics and the specific energy consumption values. More efforts are required to improve the quality of the national and international energy statistics to make them useable for reliable monitoring of energy efficiency improvements of the chemical industry. -- Highlights: ► An advanced model was developed to estimate German chemical industry’s energy use. ► For the base year (2000), model covers 88% of the sector’s total final energy use. ► Sector’s energy efficiency improved between 2.2 and 3.5%/yr between 1995 and 2008. ► Improved energy statistics are required for accurate monitoring of improvements.

9 CFR 318.16 - Pesticide chemicals and other residues in products.

Science.gov (United States)

2010-01-01

..., DEPARTMENT OF AGRICULTURE AGENCY ORGANIZATION AND TERMINOLOGY; MANDATORY MEAT AND POULTRY PRODUCTS INSPECTION... ingredients. Residues of pesticide chemicals, food additives and color additives or other substances in or on ingredients (other than meat, meat byproducts, and meat food products) used in the formulation of products...

Soil chemical properties and legume-cereal rotation benefits in an ...

African Journals Online (AJOL)

This research was conducted at the Department of Soil Science, University of Nigeria Teaching and Research Farm in 2008 and 2009 growing seasons. The objective was to evaluate the effects of edible grain legumes (cowpea and soybean) and velvet-bean/maize rotations on soil chemical properties and the contribution ...

Key formal and legal aspects of acquiring radiopharmaceuticals used in nuclear medicine departments

International Nuclear Information System (INIS)

Kapuscinski, J.

2007-01-01

The article presents the key both Polish and EU legal regulation concerning terms and conditions of acquiring radiopharmaceuticals, i.e. isotope labelled compounds used for diagnostic and/ therapeutic purposes in nuclear medicine departments. The emphasis was put on the requirements regarding provision of the medicaments' safety in broad meaning of the term, which are important factors in providing patients' safety. Legal acts discussed in the article remain valid as of May 2007. (author)

Thermal/chemical degradation of ceramic cross-flow filter materials

Energy Technology Data Exchange (ETDEWEB)

Alvin, M.A.; Lane, J.E.; Lippert, T.E.

1989-11-01

This report summarizes the 14-month, Phase 1 effort conducted by Westinghouse on the Thermal/Chemical Degradation of Ceramic Cross-Flow Filter Materials program. In Phase 1 expected filter process conditions were identified for a fixed-bed, fluid-bed, and entrained-bed gasification, direct coal fired turbine, and pressurized fluidized-bed combustion system. Ceramic cross-flow filter materials were also selected, procured, and subjected to chemical and physical characterization. The stability of each of the ceramic cross-flow materials was assessed in terms of potential reactions or phase change as a result of process temperature, and effluent gas compositions containing alkali and fines. In addition chemical and physical characterization was conducted on cross-flow filters that were exposed to the METC fluid-bed gasifier and the New York University pressurized fluidized-bed combustor. Long-term high temperature degradation mechanisms were proposed for each ceramic cross-flow material at process operating conditions. An experimental bench-scale test program is recommended to be conducted in Phase 2, generating data that support the proposed cross-flow filter material thermal/chemical degradation mechanisms. Papers on the individual subtasks have been processed separately for inclusion on the data base.

78 FR 68461 - Guidance for Industry: Studies To Evaluate the Utility of Anti-Salmonella Chemical Food Additives...

Science.gov (United States)

2013-11-14

... DEPARTMENT OF HEALTH AND HUMAN SERVICES Food and Drug Administration [Docket No. FDA-1994-D-0007] Guidance for Industry: Studies To Evaluate the Utility of Anti- Salmonella Chemical Food Additives in Feeds... Industry: Studies to Evaluate the Utility of Anti-Salmonella Chemical Food Additives in Feeds,'' and is...

Review on technical issues influencing the performance of chemical barriers of TRU waste repository

International Nuclear Information System (INIS)

Fujita, Tomonari; Sugiyama, Daisuke; Tsukamoto, Masaki; Yokoyama, Hayaichi

1997-01-01

Studies of technical issues influencing the performance assessment of TRU waste disposal which is occurred from the nuclear fuel reprocessing were reviewed in related to the development of safety analysis method. Especially, the chemical containment was investigated as a key barrier to radionuclide migration. TRU waste including long-lived radionuclides need long-term performance assessment which could be assumed only by the chemical barrier. The description of technical issues concerned with the performance of TRU waste repository has been divided into the following categories: long-term degradation of cementitious materials as engineered barrier for radionuclide migration, effect of colloids, organic macromolecules and organic degradation products on chemical behavior of radionuclides, gas generation by corrosion of metallic wastes, and effects of microbial activity. Preliminary performance assessment indicated that important factors affecting performance of chemical barriers in near-field were the distribution coefficient and the solubility of radionuclides in near-field groundwater. Therefore, it was identified that key issues associated with performance of chemical barrier were evaluation of (a) the long-term change of distribution coefficient of cementitious material through the degradation under repository condition and (b) chemical speciation change of radionuclides such as increase of solubility by the presence of colloidal-size materials. (author)

U.S. Department of Education FY 2003 Performance and Accountability Report.

Science.gov (United States)

Department of Education, Washington, DC.

This is a report on the progress of the U.S. Department of Education's accounting systems and management controls. Sections include: (1) Management's Discussion and Analysis; (2) Performance Details; (3) Financial Details; and (4) Other Statutorily Required Reports. Five appendixes are included along with a glossary of terms and a list of figures.…

78 FR 31885 - Patent Term Extension

Science.gov (United States)

2013-05-28

... DEPARTMENT OF COMMERCE Patent and Trademark Office Patent Term Extension ACTION: Proposed collection; comment request. SUMMARY: The United States Patent and Trademark Office (USPTO), as part of its... States Patent and Trademark Office, P.O. Box 1450, Alexandria, VA 22313-1450. Federal Rulemaking Portal...

75 FR 20561 - Patent Term Extension

Science.gov (United States)

2010-04-20

... DEPARTMENT OF COMMERCE Patent and Trademark Office Patent Term Extension ACTION: Proposed collection; comment request. SUMMARY: The United States Patent and Trademark Office (USPTO), as part of its... Officer, Office of the Chief Information Officer, United States Patent and Trademark Office, P.O. Box 1450...

Development of Short-term Molecular Thresholds to Predict Long-term Mouse Liver Tumor Outcomes: Phthalate Case Study

Science.gov (United States)

Short-term molecular profiles are a central component of strategies to model health effects of environmental chemicals. In this study, a 7 day mouse assay was used to evaluate transcriptomic and proliferative responses in the liver for a hepatocarcinogenic phthalate, di (2-ethylh...

Assessment of chemical and biochemical stabilization of organic C in soils from the long-term experiments at Rothamsted (UK).

Science.gov (United States)

De Nobili, M; Contin, M; Mahieu, N; Randall, E W; Brookes, P C

2008-01-01

Biological and chemical stabilization of organic C was assessed in soils sampled from the long-term experiments at Rothamsted (UK), representing a wide range of carbon inputs and managements by extracting labile, non-humified organic matter (NH) and humic substances (HS). Four sequentially extracted humic substances fractions of soil organic matter (SOM) were extracted and characterized before and after a 215-day laboratory incubation at 25 degrees C from two arable soils, a woodland soil and an occasionally stubbed soil. The fractions corresponded to biochemically stabilised SOM extracted in 0.5M NaOH (free fulvic acids (FA) and humic acids (HA)) and chemically plus biochemically stabilised SOM extracted from the residue with 0.1M Na4P2O7 plus 0.1M NaOH (bound FA and HA). Our aim was to investigate the effects of chemical and biochemical stabilization on carbon sequestration. The non-humic to humic (NH/H) C ratio separated the soils into two distinct groups: arable soils (unless fertilised with farmyard manure) had an NH/H C ratio between 1.05 and 0.71, about twice that of the other soils (0.51-0.26). During incubation a slow, but detectable, decrease in the NH/H C ratio occurred in soils of C input equivalent or lower to 4Mgha(-1)y(-1), whereas the ratio remained practically constant in the other soils. Before incubation the free to bound humic C ratio increased linearly (R2=0.91) with C inputs in the soils from the Broadbalk experiment and decreased during incubation, showing that biochemical stabilization is less effective than chemical stabilization in preserving humic C. Changes in delta13C and delta15N after incubation were confined to the free FA fractions. The delta13C of free FA increased by 1.48 and 0.80 per thousand, respectively, in the stubbed and woodland soils, indicating a progressive biological transformation. On the contrary, a decrease was observed for the bound FA of both soils. Concomitantly, a Deltadelta15N of up to +3.52 per thousand was

Annual progress report of the Condensed Matter Physics and Chemistry Department 1 January - 31 December 1997

Energy Technology Data Exchange (ETDEWEB)

Nielsen, M; Bechgaard, K; Clausen, K N; Feidenhans` l, R; Johannsen, I [eds.

1998-01-01

The Condensed Matter Physics and Chemistry Department is concerned with both fundamental and applied research into the physical and chemical properties of materials. The principal activities in the year 1997 are presented in this progress report. The research in physics in concentrated on neutron and x-ray scattering measurements and the problems studied include two- and three-dimensional structures, magnetic ordering and spin dynamics, superconductivity, phase transitions and nano-scale structures. The research in chemistry includes chemical synthesis and physico-chemical investigation of small molecules and polymers, with emphasis on polymers with new optical properties, block copolymers, surface-modified polymers, and supramolecular structures. Theoretical work related to these problems in undertaken, including Monte Carlo simulations, computer simulation of molecules and polymers and methods of data analysis. (au). 129 ills., 213 refs.

Chemical evolution and the origin of life: cumulative keyword subject index 1970-1986

Science.gov (United States)

Roy, A. C.; Powers, J. V.; Rummel, J. D. (Principal Investigator)

1990-01-01

This cumulative subject index encompasses the subject indexes of the bibliographies on Chemical Evolution and the Origin of Life that were first published in 1970 and have continued through publication of the 1986 bibliography supplement. Early bibliographies focused on experimental and theoretical material dealing directly with the concepts of chemical evolution and the origin of life, excluding the broader areas of exobiology, biological evolution, and geochemistry. In recent years, these broader subject areas have also been incorporated as they appear in literature searches relating to chemical evolution and the origin of life, although direct attempts have not been made to compile all of the citations in these broad areas. The keyword subject indexes have also undergone an analogous change in scope. Compilers of earlier bibliographies used the most specific term available in producing the subject index. Compilers of recent bibliographies have used a number of broad terms relating to the overall subject content of each citation and specific terms where appropriate. The subject indexes of these 17 bibliographies have, in general, been cumulatively compiled exactly as they originally appeared. However, some changes have been made in an attempt to correct errors, combine terms, and provide more meaningful terms.

Mixed waste chemical compatibility: A testing program for plastic packaging components

International Nuclear Information System (INIS)

Nigrey, P.J.

1995-01-01

The purpose of hazardous and radioactive materials packaging is to enable these materials to be transported without posing a threat to the health or property of the general public. To achieve this aim, regulations in the United States have been written establishing general design requirements for such packagings. While no regulations have been written specifically for mixed waste packaging, regulations for the constituents of mixed wastes, i.e., hazardous and radioactive substances, have been codified by the US Department of Transportation (DOT, 49 CFR 173) and the US Nuclear Regulatory Commission (NRC, 10 CFR 71). The design requirements for both hazardous [49 CFR 173.24 (e)(1)] and radioactive [49 CFR 173.412 (g)] materials packaging specify packaging compatibility, i.e., that the materials of the packaging at sign d any contents be chemically compatible with each other. Furthermore, Type A [49 CFR 173.412 (g)] and Type B (10 CFR 71.43) packaging design requirements stipulate that there be no significant chemical, galvanic, or other reaction between the materials and contents of the package. Based on these requirements, a Chemical Compatibility Testing Program was developed in the Transportation Systems Department at Sandia National Laboratories (SNL). The program attempts to assure any regulatory body that the issue of packaging material compatibility towards hazardous and radioactive materials has been addressed. This program has been described in considerable detail in an internal SNL document, the Chemical Compatibility Test Plan ampersand Procedure Report (Nigrey 1993)

Designing Intelligent Secure Android Application for Effective Chemical Inventory

Science.gov (United States)

Shukran, Mohd Afizi Mohd; Naim Abdullah, Muhammad; Nazri Ismail, Mohd; Maskat, Kamaruzaman; Isa, Mohd Rizal Mohd; Shahfee Ishak, Muhammad; Adib Khairuddin, Muhamad

2017-08-01

Mobile services support various situations in everyday life and with the increasing sophistication of phone functions, the daily life is much more easier and better especially in term of managing tools and apparatus. Since chemical inventory management system has been experiencing a new revolution from antiquated to an automated inventory management system, some additional features should be added in current chemical inventory system. Parallel with the modern technologies, chemical inventory application using smart phone has been developed. Several studies about current related chemical inventory management using smart phone application has been done in this paper in order to obtain an overview on recent studies in smartphone application for chemical inventory system which are needed in schools, universities or other education institutions. This paper also discuss about designing the proposed secure mobile chemical inventory system. The study of this paper can provide forceful review analysis support for the chemical inventory management system related research.

Lattice QCD with chemical potential: Evading the fermion-sign problem

Indian Academy of Sciences (India)

Department of Theoretical Physics, Tata Institute of Fundamental Research, .... baryon and electric charge remain conserved, and only these two chemical potentials ..... of the equation of state also shows a power law behaviour for small n/T 3. In QCD with .... talk of C Schmidt in SEWM 2004 (Helsinki) for more on this topic.

Recognition of chemical entities: combining dictionary-based and grammar-based approaches

Science.gov (United States)

2015-01-01

Background The past decade has seen an upsurge in the number of publications in chemistry. The ever-swelling volume of available documents makes it increasingly hard to extract relevant new information from such unstructured texts. The BioCreative CHEMDNER challenge invites the development of systems for the automatic recognition of chemicals in text (CEM task) and for ranking the recognized compounds at the document level (CDI task). We investigated an ensemble approach where dictionary-based named entity recognition is used along with grammar-based recognizers to extract compounds from text. We assessed the performance of ten different commercial and publicly available lexical resources using an open source indexing system (Peregrine), in combination with three different chemical compound recognizers and a set of regular expressions to recognize chemical database identifiers. The effect of different stop-word lists, case-sensitivity matching, and use of chunking information was also investigated. We focused on lexical resources that provide chemical structure information. To rank the different compounds found in a text, we used a term confidence score based on the normalized ratio of the term frequencies in chemical and non-chemical journals. Results The use of stop-word lists greatly improved the performance of the dictionary-based recognition, but there was no additional benefit from using chunking information. A combination of ChEBI and HMDB as lexical resources, the LeadMine tool for grammar-based recognition, and the regular expressions, outperformed any of the individual systems. On the test set, the F-scores were 77.8% (recall 71.2%, precision 85.8%) for the CEM task and 77.6% (recall 71.7%, precision 84.6%) for the CDI task. Missed terms were mainly due to tokenization issues, poor recognition of formulas, and term conjunctions. Conclusions We developed an ensemble system that combines dictionary-based and grammar-based approaches for chemical named

Recognition of chemical entities: combining dictionary-based and grammar-based approaches.

Science.gov (United States)

Akhondi, Saber A; Hettne, Kristina M; van der Horst, Eelke; van Mulligen, Erik M; Kors, Jan A

2015-01-01

The past decade has seen an upsurge in the number of publications in chemistry. The ever-swelling volume of available documents makes it increasingly hard to extract relevant new information from such unstructured texts. The BioCreative CHEMDNER challenge invites the development of systems for the automatic recognition of chemicals in text (CEM task) and for ranking the recognized compounds at the document level (CDI task). We investigated an ensemble approach where dictionary-based named entity recognition is used along with grammar-based recognizers to extract compounds from text. We assessed the performance of ten different commercial and publicly available lexical resources using an open source indexing system (Peregrine), in combination with three different chemical compound recognizers and a set of regular expressions to recognize chemical database identifiers. The effect of different stop-word lists, case-sensitivity matching, and use of chunking information was also investigated. We focused on lexical resources that provide chemical structure information. To rank the different compounds found in a text, we used a term confidence score based on the normalized ratio of the term frequencies in chemical and non-chemical journals. The use of stop-word lists greatly improved the performance of the dictionary-based recognition, but there was no additional benefit from using chunking information. A combination of ChEBI and HMDB as lexical resources, the LeadMine tool for grammar-based recognition, and the regular expressions, outperformed any of the individual systems. On the test set, the F-scores were 77.8% (recall 71.2%, precision 85.8%) for the CEM task and 77.6% (recall 71.7%, precision 84.6%) for the CDI task. Missed terms were mainly due to tokenization issues, poor recognition of formulas, and term conjunctions. We developed an ensemble system that combines dictionary-based and grammar-based approaches for chemical named entity recognition, outperforming

Summaries of FY 1981 research in the chemical sciences

International Nuclear Information System (INIS)

1981-08-01

The purpose of this booklet is to help those interested in research supported by the Department of Energy's Division of Chemical Sciences, which is one of six Divisions of the Office of Basic Energy Sciences in the Office of Energy Research. Chemists, physicists, chemical engineers and others who are considering the possibility of proposing research for support by this Division will find the booklet useful for gauging the scope of the program in basic research, and the relationship of their interests to the overall program. These summaries are intended to provide a rapid means for becoming acquainted with the Chemical Sciences program to members of the scientific and technological public and interested persons in the Legislative and Executive Branches of the Government. Areas of research supported by the Division are to be seen in the section headings, the index and the summaries themselves. Energy technologies which may be advanced by use of the basic knowledge discovered in this program can be seen in the index and again (by reference) in the summaries. The contents are as follows: DOE laboratires; chemical physics; atomic physics; chemical energy; separations; analysis; chemical engineering sciences; offsite contracts; equipment funds; topical index; institutional index for offsite contracts; and investigator index

Environmental issues and work: women with multiple chemical sensitivities.

Science.gov (United States)

Lipson, Juliene G; Doiron, Nathalie

2006-08-01

Multiple chemical sensitivities (MCS) is an acquired condition in which exposure to low levels of chemicals causes symptoms in multiple organ systems. Some 12%-16% of the U.S. population has some level of chemical sensitivity, 80% of whom are women. Attempts to reduce chemical exposures leads to enormous life difficulties at home, school, and workplace. We base our article on an ethnographic study of MCS in the United States and Canada. We describe here themes related to work issues in terms of a general trajectory of becoming sick from work exposures, coping with toxic physical environments and dealing with coworkers and, when unable to continue working, applying for workers' compensation, or disability status, or both.

42 CFR 93.50 - Special terms.

Science.gov (United States)

2010-10-01

... 42 Public Health 1 2010-10-01 2010-10-01 false Special terms. 93.50 Section 93.50 Public Health PUBLIC HEALTH SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES HEALTH ASSESSMENTS AND HEALTH EFFECTS STUDIES OF HAZARDOUS SUBSTANCES RELEASES AND FACILITIES PUBLIC HEALTH SERVICE POLICIES ON RESEARCH...

32 CFR 701.101 - Privacy program terms and definitions.

Science.gov (United States)

2010-07-01

... from a project on privacy issues, identifying and resolving the privacy risks, and approval by a... 32 National Defense 5 2010-07-01 2010-07-01 false Privacy program terms and definitions. 701.101... DEPARTMENT OF THE NAVY DOCUMENTS AFFECTING THE PUBLIC DON Privacy Program § 701.101 Privacy program terms and...

10 CFR 725.23 - Terms and conditions of access.

Science.gov (United States)

2010-01-01

... warranty or other representation, expressed or implied, (1) with respect to the accuracy, completeness or... 10 Energy 4 2010-01-01 2010-01-01 false Terms and conditions of access. 725.23 Section 725.23 Energy DEPARTMENT OF ENERGY PERMITS FOR ACCESS TO RESTRICTED DATA Permits § 725.23 Terms and conditions...

Modeling the effects of influenza vaccination of health care workers in hospital departments

NARCIS (Netherlands)

van den Dool, C.; Bonten, M. J. M.; Hak, E.; Wallinga, J.

2009-01-01

Nowadays health care worker (HCW) vaccination is widely recommended. Although the benefits of this strategy have been demonstrated in long-term care settings, no studies have been performed in regular hospital departments. We adapt a previously developed model of influenza transmission in a

[Quality Management for Surgeons: The Knowledge of Basic Contexts and Innovative Strategies Promotes the Competitiveness of Clinical Department].

Science.gov (United States)

Hellmann, Wolfgang

2017-12-01

Efficient quality management aiming to achieve high quality in patient care is crucial to the success of a surgery department. This requires the knowledge of relevant terms und contexts of quality management. Implementation remains difficult in the light of demographic change and skills shortage. If a hospital has an efficient internal quality management in place, this should be used as a supplementary instrument. Otherwise it is the (sole) task of a specialist department to ensure quality for patients, employees, and cooperative partners. This paper provides basic knowledge on quality management, risk management, and quality assurance in the context of relevant medical terms. It demonstrates new ways for implementation on the level of a surgery department, and introduces a new model of quality. Georg Thieme Verlag KG Stuttgart · New York.

Coupling of physical erosion and chemical weathering after phases of intense human activity

Science.gov (United States)

Schoonejans, Jerome; Vanacker, Veerle; Opfergelt, Sophie; Ameijeiras-Mariño, Yolanda; Kubik, Peter W.

2014-05-01

Anthropogenic disturbance of natural vegetation profoundly alters the lateral and vertical fluxes of soil nutrients and particles at the land surface. Human-induced acceleration of soil erosion can thereby result in an imbalance between physical erosion, soil production and chemical weathering. The (de-)coupling between physical erosion and chemical weathering in ecosystems with strong anthropogenic disturbances is not yet fully understood, as earlier studies mostly focused on natural ecosystems. In this study, we explore the chemical weathering intensity for four study sites located in the Internal Zone of the Spanish Betic Cordillera. Most of the sites belong to the Nevado-Filabres complex, but are characterized by different rates of long-term exhumation, 10Be catchment-wide denudation and hill slope morphology. Denudation rates are generally low, but show large variation between the three sites (from 23 to 246 mm kyr-1). The magnitude of denudation rates is consistent with longer-term uplift rates derived from marine deposits, fission-track measurements and vertical fault slip rates. Two to three soil profiles were sampled per study site at exposed ridge tops. All soils overly fractured mica schist, and are very thin (< 60cm). In each soil profile, we sampled 5 depth slices, rock fragments and the (weathered) bedrock. In total, 38 soil and 20 rock samples were analyzed for their chemical composition. The chemical weathering intensity is constrained by the Chemical Depletion Fraction that is based on a chemical mass balance approach using Zr as an immobile element. Chemical weathering accounts for 5 to 35% of the total mass lost due to denudation. We observe systematically higher chemical weathering intensities (CDFs) in sites with lower denudation rates (and vice versa), suggesting that weathering is supply-limited. Our measurements of soil elemental losses from 10 soil profiles suggest that the observed variation in chemical weathering is strongly associated

Radiocesium in migratory aquatic game birds using contaminated U.S. Department of Energy reactor-cooling reservoirs: A long-term perspective.

Science.gov (United States)

Kennamer, Robert A; Oldenkamp, Ricki E; Leaphart, James C; King, Joshua D; Bryan, A Lawrence; Beasley, James C

2017-05-01

Low-level releases of radiocesium into former nuclear reactor cooling-reservoirs on the U.S. Department of Energy's Savannah River Site (SRS) in South Carolina, USA, dating primarily to the late 1950s and early 1960s, have allowed examination of long-term contaminant attenuation in biota occupying these habitats. Periodic collections of migratory game birds since the 1970s have documented 137 Cs (radiocesium) activity concentrations in birds of SRS reservoirs, including mainly Par Pond and Pond B. In this study, during 2014 and 2015 we released wild-caught American coots (Fulica americana) and ring-necked ducks (Aythya collaris) onto Pond B. We made lethal collections of these same birds with residence times ranging from 32 to 173 days to examine radiocesium uptake and estimate the rate of natural attenuation. The two species achieved asymptotic whole-body activity concentrations of radiocesium at different times, with ring-necked ducks requiring almost three times longer than the 30-35 days needed by coots. We estimated ecological half-life (T e ) for Pond B coots over a 28-yr period as 16.8 yr (95% CI = 12.9-24.2 yr). Pond B coot T e was nearly four times longer than T e for coots at nearby Par Pond where radiocesium bioavailability had been constrained for decades by pumping of potassium-enriched river water into that reservoir. T e could not be estimated from long-term data for radiocesium in Pond B diving ducks, including ring-necked ducks, likely because of high variability in residence times of ducks on Pond B. Our results highlight the importance: (1) for risk managers to understand site-specific bio-geochemistry of radiocesium for successful implementation of countermeasures at contaminated sites and (2) of residence time as a critical determinant of observed radiocesium activity concentrations in highly mobile wildlife inhabiting contaminated habitats. Copyright © 2017 Elsevier Ltd. All rights reserved.

National Status and Trends: Bioeffects Program - Southwest Puerto Rico Chemical Contaminant Assessment Summary

Data.gov (United States)

National Oceanic and Atmospheric Administration, Department of Commerce — The purpose of the project was to characterize the extent and magnitude of chemical contamination in southwest Puerto Rico, as part of a larger effort to link coral...

History of chemical and biological warfare agents

International Nuclear Information System (INIS)

Szinicz, L.

2005-01-01

Chemical and biological warfare agents constitute a low-probability, but high-impact risk both to the military and to the civilian population. The use of hazardous materials of chemical or biological origin as weapons and for homicide has been documented since ancient times. The first use of chemicals in terms of weapons of mass destruction goes back to World War I, when on April 22, 1915 large amounts of chlorine were released by German military forces at Ypres, Belgium. Until around the 1970s of the 20th century, the awareness of the threat by chemical and biological agents had been mainly confined to the military sector. In the following time, the development of increasing range delivery systems by chemical and biological agents possessors sensitised public attention to the threat emanating from these agents. Their proliferation to the terrorists field during the 1990s with the expanding scale and globalisation of terrorist attacks suggested that these agents are becoming an increasing threat to the whole world community. The following article gives a condensed overview on the history of use and development of the more prominent chemical and biological warfare agents

History of chemical and biological warfare agents.

Science.gov (United States)

Szinicz, L

2005-10-30

Chemical and biological warfare agents constitute a low-probability, but high-impact risk both to the military and to the civilian population. The use of hazardous materials of chemical or biological origin as weapons and for homicide has been documented since ancient times. The first use of chemicals in terms of weapons of mass destruction goes back to World War I, when on April 22, 1915 large amounts of chlorine were released by German military forces at Ypres, Belgium. Until around the 1970s of the 20th century, the awareness of the threat by chemical and biological agents had been mainly confined to the military sector. In the following time, the development of increasing range delivery systems by chemical and biological agents possessors sensitised public attention to the threat emanating from these agents. Their proliferation to the terrorists field during the 1990s with the expanding scale and globalisation of terrorist attacks suggested that these agents are becoming an increasing threat to the whole world community. The following article gives a condensed overview on the history of use and development of the more prominent chemical and biological warfare agents.

Endocrine active chemicals and endocrine disruption in Minnesota streams and lakes: implications for aquatic resources, 1994-2008

Science.gov (United States)

Lee, Kathy E.; Schoenfuss, Heiko L.; Barber, Larry B.; Writer, Jeff H.; Blazer, Vicki; Keisling, Richard L.; Ferrey, Mark L.

2010-01-01

The U.S. Geological Survey, in cooperation with St. Cloud State University, Minnesota Department of Health, Minnesota Pollution Control Agency, Minnesota Department of Natural Resources, Metropolitan Council Environmental Services, and the University of Minnesota, has conducted field monitoring studies and laboratory research to determine the presence of endocrine active chemicals and the incidence of endocrine disruption in Minnesota streams and lakes during 1994–2008. Endocrine active chemicals are chemicals that interfere with the natural regulation of endocrine systems, and may mimic or block the function of natural hormones in fish or other organisms. This interference commonly is referred to as endocrine disruption. Indicators of endocrine disruption in fish include vitellogenin (female egg yolk protein normally expressed in female fish) in male fish, oocytes present in male fish testes, reduced reproductive success, and changes in reproductive behavior.

42 CFR 137.55 - What is the term of a funding agreement?

Science.gov (United States)

2010-10-01

... SERVICE, DEPARTMENT OF HEALTH AND HUMAN SERVICES TRIBAL SELF-GOVERNANCE Funding Agreements Term of A... term mutually agreed to by the parties. Absent notification from an Indian Tribe that it is withdrawing...

Gender Blind, Gender-Lite: A Critique of Gender Equity Approaches in the South African Department of Education

Science.gov (United States)

Dieltiens, Veerle; Unterhalter, Elaine; Letsatsi, Setungoane; North, Amy

2009-01-01

Gender equity is one of the foundational principles of the national Department of Education, but there is not a shared understanding of its meaning. Based on interviews conducted in 2008 with officials in the Department of Education, we argue that there are two basic approaches to gender equity. The first, which we term "gender blind",…

Glossary of CERCLA, RCRA and TSCA related terms and acronyms

International Nuclear Information System (INIS)

1993-10-01

This glossary contains CERCLA, RCRA and TSCA related terms that are most often encountered in the US Department of Energy (DOE) Environmental Restoration and Emergency Preparedness activities. Detailed definitions are included for key terms. The CERCLA definitions included in this glossary are taken from the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA), as amended and related federal rulemakings. The RCRA definitions included in this glossary are taken from the Resource Conservation and Recovery Act (RCRA) and related federal rulemakings. The TSCA definitions included in this glossary are taken from the Toxic Substances and Control Act (TSCA) and related federal rulemakings. Definitions related to TSCA are limited to those sections in the statute and regulations concerning PCBs and asbestos.Other sources for definitions include additional federal rulemakings, assorted guidance documents prepared by the US Environmental Protection Agency (EPA), guidance and informational documents prepared by the US Department of Energy (DOE), and DOE Orders. The source of each term is noted beside the term. Terms presented in this document reflect revised and new definitions published before July 1, 1993

Research on the chemical speciation of actinides

International Nuclear Information System (INIS)

Jung, Euo Chang; Park, K. K.; Cho, H. R.

2010-04-01

A demand for the safe and effective management of spent nuclear fuel and radioactive waste generated from nuclear power plant draws increasing attention with the growth of nuclear power industry. The objective of this project is to establish the basis of research on the actinide chemistry by using advanced laser-based highly sensitive spectroscopic systems. Researches on the chemical speciation of actinides are prerequisite for the development of technologies related to nuclear fuel cycles, especially, such as the safe management of high level radioactive wastes and the chemical examination of irradiated nuclear fuels. For supporting these technologies, laser-based spectroscopies have been performed for the chemical speciation of actinide in an aqueous solutions and the quantitative analysis of actinide isotopes in spent nuclear fuels. In this report, results on the following subjects have been summarized. (1) Development of TRLFS technology for chemical speciation of actinides, (2) Development of LIBD technology for measuring solubility of actinides, (3) Chemical speciation of plutonium complexes by using a LWCC system, (4) Development of LIBS technology for the quantitative analysis of actinides, (5) Development of technology for the chemical speciation of actinides by CE, (6) Evaluation on the chemical reactions between actinides and humic substances, (7) Chemical speciation of actinides adsorbed on metal oxides surfaces, (8) Determination of actinide source terms of spent nuclear fuel

Chemically aged and mixed aerosols over the Central Atlantic Ocean - Potential impacts

NARCIS (Netherlands)

Astitha, M.; Kallos, G.; Spyrou, C.; O'Hirok, W.; Lelieveld, J.; Denier Gon, H.A.C. van der

2010-01-01

Detailed information on the chemical and physical properties of aerosols is important for assessing their role in air quality and climate. This work explores the origin and fate of continental aerosols transported over the Central Atlantic Ocean, in terms of chemical composition, number and size

Accurate quantum chemical calculations

Science.gov (United States)

Bauschlicher, Charles W., Jr.; Langhoff, Stephen R.; Taylor, Peter R.

1989-01-01

An important goal of quantum chemical calculations is to provide an understanding of chemical bonding and molecular electronic structure. A second goal, the prediction of energy differences to chemical accuracy, has been much harder to attain. First, the computational resources required to achieve such accuracy are very large, and second, it is not straightforward to demonstrate that an apparently accurate result, in terms of agreement with experiment, does not result from a cancellation of errors. Recent advances in electronic structure methodology, coupled with the power of vector supercomputers, have made it possible to solve a number of electronic structure problems exactly using the full configuration interaction (FCI) method within a subspace of the complete Hilbert space. These exact results can be used to benchmark approximate techniques that are applicable to a wider range of chemical and physical problems. The methodology of many-electron quantum chemistry is reviewed. Methods are considered in detail for performing FCI calculations. The application of FCI methods to several three-electron problems in molecular physics are discussed. A number of benchmark applications of FCI wave functions are described. Atomic basis sets and the development of improved methods for handling very large basis sets are discussed: these are then applied to a number of chemical and spectroscopic problems; to transition metals; and to problems involving potential energy surfaces. Although the experiences described give considerable grounds for optimism about the general ability to perform accurate calculations, there are several problems that have proved less tractable, at least with current computer resources, and these and possible solutions are discussed.

Cross-coupling effects in chemically non-equilibrium viscous compressible flows

International Nuclear Information System (INIS)

Kustova, E.V.; Giordano, D.

2011-01-01

Graphical abstract: Self-cosistent kinetic-theory description of chemical-reaction rates and mean normal stress in one-temperature viscous compressible gas flows. Reaearch highlights: → In chemically non-equilibrium viscous compressible flows, the rate of each reaction depends on the velocity divergence and rates of all other reactions. → Cross effects between the rates of chemical reactions and normal mean stress can be found in the symmetric form and expressed in terms of the reaction affinities. → In the case of small affinities, the entropy production is unconditionally non-negative; in the case of finite affinities, the entropy production related to the scalar forces has no definite sign. - Abstract: A closed self-consistent description of a one-temperature non-equilibrium reacting flow is presented on the basis of the kinetic theory methods. A general case including internal degrees of freedom, dissociation-recombination and exchange reactions, and arbitrary values of affinities of chemical reactions is considered. Chemical-reaction rates and mean normal stress in viscous compressible flows are studied and a symmetric cross coupling between these terms is found. It is shown that the rate of each chemical reaction and the mean normal stress depend on velocity divergence and affinities of all chemical reactions; the law of mass action is violated in viscous flows. The results obtained in the frame of linear irreversible thermodynamics can be deduced from the proposed model for the particular case of small affinities. The reciprocal Onsager-Casimir relations are verified, the symmetry of kinetic coefficients is demonstrated, and the entropy production in a viscous flow is studied.

Analysis and classification of physical and chemical methods of fuel activation

Directory of Open Access Journals (Sweden)

Fedorchak Viktoriya

2015-12-01

Full Text Available The offered article explores various research studies, developed patents in terms of physical and chemical approaches to the activation of fuel. In this regard, national and foreign researches in the field of fuels activators with different principles of action were analysed, evaluating their pros and cons. The article also intends to classify these methods and compare them regarding diverse desired results and types of fuels used. In terms of physical and chemical influences on fuels and the necessity of making constructive changes in the fuel system of internal combustion engines, an optimal approach was outlined.

Redefining the business process of Department of Food Security and Agriculture in Government of Surabaya City

Science.gov (United States)

Cahyono, H.; Wessiani, N. A.

2018-04-01

Government of Indonesia has been launched the bureaucratic reform program since 2010. One of the action is conducted restructuring organization in all city governments. Department of Food Security and Agriculture in Government of Surabaya City is the result of merger from two Department, namely Bureau of Food Security and Department of Agriculture. This merger makes Department of Food Security and Agriculture to redefine their business process. The new business process is needed to be defined in order to align the new structure with the long term strategic planning of Surabaya City Government. This research aims to redefine the business process of Department of Food Security and Agriculture in Government of Surabaya City. The CIMOSA model is adopted for identifying the activities in the business process. The new business process is important for the department to allocate their resource, mainly the human resource and as the main input for the department to build their standard operating procedure.

The DuPont Conference: Implications for the Chemical Technology Curriculum

Science.gov (United States)

Kenkel, John; Rutledge, Sue; Kelter, Paul B.

1998-05-01

Southeast Community College (SCC) hosted the first DuPont Conference for Chemical Technology Education at its Lincoln, Nebraska campus October 4-6, 1997. The conference brought together fourteen practicing chemists and chemistry technicians and five college and university faculty members for the express purpose of suggesting new laboratory activities that would help relate the real world of work to the education of chemical laboratory technicians in community colleges. Participants included seven men and seven women from DuPont, Procter & Gamble, Eastman Chemical, Eastman Kodak, Dow Chemical, Air Products and Chemicals, Monsanto, Union Carbide, the Nebraska Agriculture Laboratory, and the University of Nebraska Biological Process Development Facility, Department of Food Science. The conference, sponsored by the E. I. DuPont DeNemours & Company through a grant awarded to SCC in June 1997, was intended to help further the goals of the two major projects underway at SCC, funded by the National Science Foundation's Advanced Technological Education Program. These projects, dubbed "Assignment: Chemical Technology I and II", or ACT-I and ACT-II, are curriculum and materials development projects. The invited scientists had between 2 and 32 years of experience that ranged from bench work to management levels. Many are or have been active on the national scene as members and officers of the American Chemical Society's Division of Chemical Technicians and the ACS Committee on Technician Activities.

Sacrificial amphiphiles: Eco-friendly chemical herders as oil spill mitigation chemicals.

Science.gov (United States)

Gupta, Deeksha; Sarker, Bivas; Thadikaran, Keith; John, Vijay; Maldarelli, Charles; John, George

2015-06-01

Crude oil spills are a major threat to marine biota and the environment. When light crude oil spills on water, it forms a thin layer that is difficult to clean by any methods of oil spill response. Under these circumstances, a special type of amphiphile termed as "chemical herder" is sprayed onto the water surrounding the spilled oil. The amphiphile forms a monomolecular layer on the water surface, reducing the air-sea surface tension and causing the oil slick to retract into a thick mass that can be burnt in situ. The current best-known chemical herders are chemically stable and nonbiodegradable, and hence remain in the marine ecosystem for years. We architect an eco-friendly, sacrificial, and effective green herder derived from the plant-based small-molecule phytol, which is abundant in the marine environment, as an alternative to the current chemical herders. Phytol consists of a regularly branched chain of isoprene units that form the hydrophobe of the amphiphile; the chain is esterified to cationic groups to form the polar group. The ester linkage is proximal to an allyl bond in phytol, which facilitates the hydrolysis of the amphiphile after adsorption to the sea surface into the phytol hydrophobic tail, which along with the unhydrolyzed herder, remains on the surface to maintain herding action, and the cationic group, which dissolves into the water column. Eventual degradation of the phytol tail and dilution of the cation make these sacrificial amphiphiles eco-friendly. The herding behavior of phytol-based amphiphiles is evaluated as a function of time, temperature, and water salinity to examine their versatility under different conditions, ranging from ice-cold water to hot water. The green chemical herder retracted oil slicks by up to ~500, 700, and 2500% at 5°, 20°, and 35°C, respectively, during the first 10 min of the experiment, which is on a par with the current best chemical herders in practice.

Long-Term Stability of Oxide Nanowire Sensors via Heavily Doped Oxide Contact.

Science.gov (United States)

Zeng, Hao; Takahashi, Tsunaki; Kanai, Masaki; Zhang, Guozhu; He, Yong; Nagashima, Kazuki; Yanagida, Takeshi

2017-12-22

Long-term stability of a chemical sensor is an essential quality for long-term collection of data related to exhaled breath, environmental air, and other sources in the Internet of things (IoT) era. Although an oxide nanowire sensor has shown great potential as a chemical sensor, the long-term stability of sensitivity has not been realized yet due to electrical degradation under harsh sensing conditions. Here, we report a rational concept to accomplish long-term electrical stability of metal oxide nanowire sensors via introduction of a heavily doped metal oxide contact layer. Antimony-doped SnO 2 (ATO) contacts on SnO 2 nanowires show much more stable and lower electrical contact resistance than conventional Ti contacts for high temperature (200 °C) conditions, which are required to operate chemical sensors. The stable and low contact resistance of ATO was confirmed for at least 1960 h under 200 °C in open air. This heavily doped oxide contact enables us to realize the long-term stability of SnO 2 nanowire sensors while maintaining the sensitivity for both NO 2 gas and light (photo) detections. The applicability of our method is confirmed for sensors on a flexible polyethylene naphthalate (PEN) substrate. Since the proposed fundamental concept can be applied to various oxide nanostructures, it will give a foundation for designing long-term stable oxide nanomaterial-based IoT sensors.