WorldWideScience

Sample records for temperature thermal storage

  1. Low temperature thermal-energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Segaser, C.S.; Christian, J.E.

    1979-03-01

    This report evaluates currently available techniques and estimated costs of low temperature thermal energy storage (TES) devices applicable to Integrated Community Energy Systems (ICES) installations serving communities ranging in size from approximately 3000 (characterized by an electrical load requirement of 2 MWe) to about 100,000 population (characterized by an electrical load requirement of 100 MWe). Thermal energy in the form of either hotness or coldness can be stored in a variety of media as sensible heat by virtue of a change in temperature of the material, or as latent heat of fusion in which the material changes from the liquid phase to the solid phase at essentially a constant temperature. Both types of material are considered for TES in ICES applications.

  2. Investigation of lithium sulphate for high temperature thermal energy storage

    Science.gov (United States)

    Bayon, Alicia; Liu, Ming; Bruno, Frank; Hinkley, Jim

    2017-06-01

    Lithium sulphate (Li2SO4) was evaluated as a solid-solid PCM material to be coupled with concentrated solar power (CSP) technologies. The energy is stored in a cubic crystalline phase that is formed at temperatures above 576°C and can potentially be discharged at temperatures as low as 150°C, providing both sensible and latent thermal energy storage in a hybrid sensible-latent system. These operational conditions are appropriate for current CSP technologies based on subcritical steam Rankine power cycles. Results from thermal cycling experiments in air showed no change in energy storage capacity after 15 cycles. There was up to a 5% reduction in latent thermal capacity and 0.95% in total thermal capacity after 150 cycles in air. In our paper, we evaluate a hybrid sensible-latent thermal energy storage system based on lithium sulphate from an economic and technical performance point of view, demonstrating its potential as a high temperature thermal energy storage material.

  3. High temperature latent heat thermal energy storage to augment solar thermal propulsion for microsatellites

    Science.gov (United States)

    Gilpin, Matthew R.

    Solar thermal propulsion (STP) offers an unique combination of thrust and efficiency, providing greater total DeltaV capability than chemical propulsion systems without the order of magnitude increase in total mission duration associated with electric propulsion. Despite an over 50 year development history, no STP spacecraft has flown to-date as both perceived and actual complexity have overshadowed the potential performance benefit in relation to conventional technologies. The trend in solar thermal research over the past two decades has been towards simplification and miniaturization to overcome this complexity barrier in an effort finally mount an in-flight test. A review of micro-propulsion technologies recently conducted by the Air Force Research Laboratory (AFRL) has identified solar thermal propulsion as a promising configuration for microsatellite missions requiring a substantial Delta V and recommended further study. A STP system provides performance which cannot be matched by conventional propulsion technologies in the context of the proposed microsatellite ''inspector" requiring rapid delivery of greater than 1500 m/s DeltaV. With this mission profile as the target, the development of an effective STP architecture goes beyond incremental improvements and enables a new class of microsatellite missions. Here, it is proposed that a bi-modal solar thermal propulsion system on a microsatellite platform can provide a greater than 50% increase in Delta V vs. chemical systems while maintaining delivery times measured in days. The realization of a microsatellite scale bi-modal STP system requires the integration of multiple new technologies, and with the exception of high performance thermal energy storage, the long history of STP development has provided "ready" solutions. For the target bi-modal STP microsatellite, sensible heat thermal energy storage is insufficient and the development of high temperature latent heat thermal energy storage is an enabling

  4. Experimental measurements of thermal properties of high-temperature refractory materials used for thermal energy storage

    Science.gov (United States)

    El-Leathy, Abdelrahman; Jeter, Sheldon; Al-Ansary, Hany; Abdel-Khalik, Said; Golob, Matthew; Danish, Syed Noman; Saeed, Rageh; Djajadiwinata, Eldwin; Al-Suhaibani, Zeyad

    2016-05-01

    This paper builds on studies conducted on thermal energy storage (TES) systems that were built as a part of the work performed for a DOE-funded SunShot project titled "High Temperature Falling Particle Receiver". In previous studies, two small-scale TES systems were constructed for measuring heat loss at high temperatures that are compatible with the falling particle receiver concept, both of which had shown very limited heat loss. Through the course of those studies, it became evident that there was a lack of information about the thermal performance of some of the insulating refractory materials used in the experiments at high temperatures, especially insulating firebrick and perlite concrete. This work focuses on determining the thermal conductivities of those materials at high temperatures. The apparatus consists of a prototype cylindrical TES bin built with the same wall construction used in previous studies. An electric heater is placed along the centerline of the bin, and thermocouples are used to measure temperature at the interfaces between all layers. Heat loss is measured across one of the layers whose thermal conductivity had already been well established using laboratory experiments. This value is used to deduce the thermal conductivity of other layers. Three interior temperature levels were considered; namely, 300°C, 500°C, and 700°C. Results show that the thermal conductivity of insulating firebrick remains low (approximately 0.22 W/m.K) at an average layer temperature as high as 640°C, but it was evident that the addition of mortar had an impact on its effective thermal conductivity. Results also show that the thermal conductivity of perlite concrete is very low, approximately 0.15 W/m.K at an average layer temperature of 360°C. This is evident by the large temperature drop that occurs across the perlite concrete layer. These results should be useful for future studies, especially those that focus on numerical modeling of TES bins.

  5. Temperature Distribution and Thermal Performance of an Aquifer Thermal Energy Storage System

    Science.gov (United States)

    Ganguly, Sayantan

    2017-04-01

    Energy conservation and storage has become very crucial to make use of excess energy during times of future demand. Excess thermal energy can be captured and stored in aquifers and this technique is termed as Aquifer Thermal Energy Storage (ATES). Storing seasonal thermal energy in water by injecting it into subsurface and extracting in time of demand is the principle of an ATES system. Using ATES systems leads to energy savings, reduces the dependency on fossil fuels and thus leads to reduction in greenhouse gas emission. This study numerically models an ATES system to store seasonal thermal energy and evaluates the performance of it. A 3D thermo-hydrogeological numerical model for a confined ATES system is presented in this study. The model includes heat transport processes of advection, conduction and heat loss to confining rock media. The model also takes into account regional groundwater flow in the aquifer, geothermal gradient and anisotropy in the aquifer. Results show that thermal injection into the aquifer results in the generation of a thermal-front which grows in size with time. Premature thermal-breakthrough causes thermal interference in the system when the thermal-front reaches the production well and consequences in the fall of system performance and hence should be avoided. This study models the transient temperature distribution in the aquifer for different flow and geological conditions. This may be effectively used in designing an efficient ATES project by ensuring safety from thermal-breakthrough while catering to the energy demand. Based on the model results a safe well spacing is proposed. The thermal energy discharged by the system is determined and strategy to avoid the premature thermal-breakthrough in critical cases is discussed. The present numerical model is applied to simulate an experimental field study which is found to approximate the field results quite well.

  6. High temperature thermal storage for solar gas turbines using encapsulated phase change materials

    CSIR Research Space (South Africa)

    Klein, P

    2014-01-01

    Full Text Available The development of high temperature thermal storage systems is required to increase the solar share of solar-hybrid gas turbine cycles. This paper proposes a pressurised packed bed of Encapsulated Phase Change Materials (EPCM) as a thermal storage...

  7. Thermal energy storage

    Science.gov (United States)

    1980-01-01

    The planning and implementation of activities associated with lead center management role and the technical accomplishments pertaining to high temperature thermal energy storage subsystems are described. Major elements reported are: (1) program definition and assessment; (2) research and technology development; (3) industrial storage applications; (4) solar thermal power storage applications; and (5) building heating and cooling applications.

  8. Parametric analysis of a high temperature packed bed thermal storage design for a solar gas turbine

    CSIR Research Space (South Africa)

    Klein, P

    2015-08-01

    Full Text Available The development of a high temperature Thermal Energy Storage (TES) system will allow for high solar shares in Solar Gas Turbine (SGT) plants. In this research a pressurised storage solution is proposed that utilises a packed bed of alumina spheres...

  9. Low temperature thermal energy storage: a state-of-the-art survey

    Energy Technology Data Exchange (ETDEWEB)

    Baylin, F.

    1979-07-01

    The preliminary version of an analysis of activities in research, development, and demonstration of low temperature thermal energy storage (TES) technologies having applications in renewable energy systems is presented. Three major categories of thermal storage devices are considered: sensible heat; phase change materials (PCM); and reversible thermochemical reactions. Both short-term and annual thermal energy storage technologies based on prinicples of sensible heat are discussed. Storage media considered are water, earth, and rocks. Annual storage technologies include solar ponds, aquifers, and large tanks or beds of water, earth, or rocks. PCM storage devices considered employ salt hydrates and organic compounds. The sole application of reversible chemical reactions outlined is for the chemical heat pump. All program processes from basic research through commercialization efforts are investigated. Nongovernment-funded industrial programs and foreign efforts are outlined as well. Data describing low temperature TES activities are presented also as project descriptions. Projects for all these programs are grouped into seven categories: short-term sensible heat storage; annual sensible heat storage; PCM storage; heat transfer and exchange; industrial waste heat recovery and storage; reversible chemical reaction storage; and models, economic analyses, and support studies. Summary information about yearly funding and brief descriptions of project goals and accomplishments are included.

  10. Temperature dependency of the thermal conductivity of porous heat storage media

    Science.gov (United States)

    Hailemariam, Henok; Wuttke, Frank

    2017-10-01

    Analyzing the variation of thermal conductivity with temperature is vital in the design and assessment of the efficiency of sensible heat storage systems. In this study, the temperature variation of the thermal conductivity of a commercial cement-based porous heat storage material named - Füllbinder L is analyzed in saturated condition in the temperature range between 20 to 70°C (water based storage) with a steady state thermal conductivity and diffusivity meter. A considerable decrease in the thermal conductivity of the saturated sensible heat storage material upon increase in temperature is obtained, resulting in a significant loss of system efficiency and slower loading/un-loading rates, which when unaccounted for can lead to the under-designing of such systems. Furthermore, a new empirical prediction model for the estimation of thermal conductivity of cement-based porous sensible heat storage materials and naturally occurring crystalline rock formations as a function of temperature is proposed. The results of the model prediction are compared with the experimental results with satisfactory results.

  11. High-temperature thermal storage systems for advanced solar receivers materials selections

    Science.gov (United States)

    Wilson, D. F.; Devan, J. H.; Howell, M.

    1990-01-01

    Advanced space power systems that use solar energy and Brayton or Stirling heat engines require thermal energy storage (TES) systems to operate continuously through periods of shade. The receiver storage units, key elements in both Brayton and Stirling systems, are designed to use the latent heat of fusion of phase-change materials (PCMs). The power systems under current consideration for near-future National Aeronautics and Space Administration space missions require working fluid temperatures in the 1100 to 1400 K range. The PCMs under current investigation that gave liquid temperatures within this range are the fluoride family of salts. However, these salts have low thermal conductivity, which causes large temperature gradients in the storage systems. Improvements can be obtained, however, with the use of thermal conductivity enhancements or metallic PCMs. In fact, if suitable containment materials can be found, the use of metallic PCMs would virtually eliminate the orbit associated temperature variations in TES systems. The high thermal conductivity and generally low volume change on melting of germanium and alloys based on silicon make them attractive for storage of thermal energy in space power systems. An approach to solving the containment problem, involving both chemical and physical compatibility, preparation of NiSi/NiSi2, and initial results for containment of germanium and NiSi/NiSi2, are presented.

  12. System analysis of central receiver concepts with high temperature thermal energy storages: Receiver technologies and storage cycles

    Science.gov (United States)

    Steiner, Peter; Schwaiger, Karl; Haider, Markus; Walter, Heimo

    2017-06-01

    Reducing the levelized cost of electricity for solar thermal electricity (STE) plants is the most important challenge of this technology. A bottleneck at state of the art STE plants is the heat storage medium (HSM) with its temperature limits. To replace the commonly used molten salt, particles like quartz sand or corundum, enabling temperatures up to 1000 °C, are proposed as new HSM. The temperature raise leads to economical challenges, which have to be analyzed more in detail. In this work two STE plant concepts based on particles as HSM are introduced and discussed to outline advantages and issues concerning this technology.

  13. Seasonal thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Allen, R.D.; Kannberg, L.D.; Raymond, J.R.

    1984-05-01

    This report describes the following: (1) the US Department of Energy Seasonal Thermal Energy Storage Program, (2) aquifer thermal energy storage technology, (3) alternative STES technology, (4) foreign studies in seasonal thermal energy storage, and (5) economic assessment.

  14. Metal matrix-metal nanoparticle composites with tunable melting temperature and high thermal conductivity for phase-change thermal storage.

    Science.gov (United States)

    Liu, Minglu; Ma, Yuanyu; Wu, Hsinwei; Wang, Robert Y

    2015-02-24

    Phase-change materials (PCMs) are of broad interest for thermal storage and management applications. For energy-dense storage with fast thermal charging/discharging rates, a PCM should have a suitable melting temperature, large enthalpy of fusion, and high thermal conductivity. To simultaneously accomplish these traits, we custom design nanocomposites consisting of phase-change Bi nanoparticles embedded in an Ag matrix. We precisely control nanoparticle size, shape, and volume fraction in the composite by separating the nanoparticle synthesis and nanocomposite formation steps. We demonstrate a 50-100% thermal energy density improvement relative to common organic PCMs with equivalent volume fraction. We also tune the melting temperature from 236-252 °C by varying nanoparticle diameter from 8.1-14.9 nm. Importantly, the silver matrix successfully prevents nanoparticle coalescence, and no melting changes are observed during 100 melt-freeze cycles. The nanocomposite's Ag matrix also leads to very high thermal conductivities. For example, the thermal conductivity of a composite with a 10% volume fraction of 13 nm Bi nanoparticles is 128 ± 23 W/m-K, which is several orders of magnitude higher than typical thermal storage materials. We complement these measurements with calculations using a modified effective medium approximation for nanoscale thermal transport. These calculations predict that the thermal conductivity of composites with 13 nm Bi nanoparticles varies from 142 to 47 W/m-K as the nanoparticle volume fraction changes from 10 to 35%. Larger nanoparticle diameters and/or smaller nanoparticle volume fractions lead to larger thermal conductivities.

  15. Numerical simulation of a high temperature thermal storage unit for solar gas turbine applications

    CSIR Research Space (South Africa)

    Klein, P

    2010-09-01

    Full Text Available The implementation of thermal storage systems allows concentrating solar power plants to generate predictable power delivery to the grid by mitigating the variability of solar energy supply. However, while thermal storage solutions exist for Rankine...

  16. Development and Performance Evaluation of High Temperature Concrete for Thermal Energy Storage for Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Selvam, R. Panneer; Hale, Micah; Strasser, Matt

    2013-03-31

    Thermal energy can be stored by the mechanism of sensible or latent heat or heat from chemical reactions. Sensible heat is the means of storing energy by increasing the temperature of the solid or liquid. Since the concrete as media cost per kWhthermal is $1, this seems to be a very economical material to be used as a TES. This research is focused on extending the concrete TES system for higher temperatures (500 °C to 600 °C) and increasing the heat transfer performance using novel construction techniques. To store heat at high temperature special concretes are developed and tested for its performance. The storage capacity costs of the developed concrete is in the range of $0.91-$3.02/kWhthermal. Two different storage methods are investigated. In the first one heat is transported using molten slat through a stainless steel tube and heat is transported into concrete block through diffusion. The cost of the system is higher than the targeted DOE goal of $15/kWhthermal. The increase in cost of the system is due to stainless steel tube to transfer the heat from molten salt to the concrete blocks.The other method is a one-tank thermocline system in which both the hot and cold fluid occupy the same tank resulting in reduced storage tank volume. In this model, heated molten salt enters the top of the tank which contains a packed bed of quartzite rock and silica sand as the thermal energy storage (TES) medium. The single-tank storage system uses about half the salt that is required by the two-tank system for a required storage capacity. This amounts to a significant reduction in the cost of the storage system. The single tank alternative has also been proven to be cheaper than the option which uses large concrete modules with embedded heat exchangers. Using computer models optimum dimensions are determined to have an round trip efficiency of 84%. Additionally, the cost of the structured concrete thermocline configuration provides the TES

  17. Encapsulation of High Temperature Phase Change Materials for Thermal Energy Storage

    Science.gov (United States)

    Nath, Rupa

    Thermal energy storage is a major contributor to bridge the gap between energy demand (consumption) and energy production (supply) by concentrating solar power. The utilization of high latent heat storage capability of phase change materials is one of the keys to an efficient way to store thermal energy. However, some of the limitations of the existing technology are the high volumetric expansion and low thermal conductivity of phase change materials (PCMs), low energy density, low operation temperatures and high cost. The present work deals with encapsulated PCM system, which operates at temperatures above 500°C and takes advantage of the heat transfer modes at such high temperatures to overcome the aforementioned limitations of PCMs. Encapsulation with sodium silicate coating on preformed PCM pellets were investigated. A low cost, high temperature metal, carbon steel has been used as a capsule for PCMs with a melting point above 500° C. Sodium silicate and high temperature paints were used for oxidation protection of steel at high temperatures. The emissivity of the coatings to enhance heat transfer was investigated.

  18. State of the art on high temperature thermal energy storage for power generation. Part 1. Concepts, materials and modellization

    Energy Technology Data Exchange (ETDEWEB)

    Gil, Antoni; Medrano, Marc; Martorell, Ingrid; Cabeza, Luisa F. [GREA Innovacio Concurrent, Universitat de Lleida, Pere de Cabrera s/n, 25001-Lleida (Spain); Lazaro, Ana; Dolado, Pablo; Zalba, Belen [Instituto de Investigacion en Ingenieria de Aragon, I3A, Grupo de Ingenieria Termica y Sistemas Energeticos (GITSE), Dpto. Ingenieria Mecanica, Area de Maquinas y Motores Termicos, Universidad de Zaragoza, Campus Politecnico Rio Ebro, Edificio ' Agustin de Betancourt' , Maria de Luna s/n, 50018 Zaragoza (Spain)

    2010-01-15

    Concentrated solar thermal power generation is becoming a very attractive renewable energy production system among all the different renewable options, as it has have a better potential for dispatchability. This dispatchability is inevitably linked with an efficient and cost-effective thermal storage system. Thus, of all components, thermal storage is a key one. However, it is also one of the less developed. Only a few plants in the world have tested high temperature thermal energy storage systems. In this paper, the different storage concepts are reviewed and classified. All materials considered in literature or plants are listed. And finally, modellization of such systems is reviewed. (author)

  19. High-temperature acquifer thermal storage and underground heat storage; IEA ECES Annex 12: Hochtemperatur-Erdwaermesonden- und Aquiferwaermespeicher

    Energy Technology Data Exchange (ETDEWEB)

    Sanner, B.; Knoblich, K. [Giessen Univ. (Germany). Inst. fuer Angewandte Geowissenschaften; Koch, M.; Adinolfi, M. [Stuttgart Univ. (Germany). Inst. fuer Siedlungswasserbau, Wasserguete und Abfallwirtschaft

    1998-12-31

    Heat storage is essential for the reconciliation of heat supply and demand. The earth has already proved to be an excellent medium for storing large amounts of heat over longer periods of time, for instance during the cold and hot season. The efficiency of the storage is the better the lower storage losses are at high temperature levels. Unfortunately this can not be easily achieved. While thermal underground stores, which are widely used for cold storage, have proved to perform quite well at temperatures between 10 C - 40 C, it has been rather difficult to achieve similar results at higher temperatures up to 150 C as test and demonstration plants of the 1980s proved. This issue has again attracted so much interest that the IEA launched a project on high temperature underground storage in December 1998. (orig.) [Deutsch] Waermespeicherung ist von entscheidender Bedeutung, wenn es darum geht, ein Waermeangebot mit einer Waermenachfrage zeitlich zur Deckung zu bringen. Der Untergrund hat sich schon seit vielen Jahren als ein geeignetes Medium erwiesen, groessere Waermepumpen ueber laengere Zeitraeume wie etwa die kalten und warmen Jahreszeiten zu speichern. Die Effizienz eines solchen Speichers steigt mit der Hoehe des erreichten Temperaturniveaus und mit sinkenden Speicherverlusten, was leider eher gegenlaeufige Erscheinungen sind. Waehrend thermische Untergrundspeicher im Temperaturbereich von 10-40 C inzwischen erfolgreich demonstriert wurden und vor allem zur Kaeltespeicherung auch bereits vielfach eingesetzt werden, haben hoehere Temperaturen bis etwa 150 C in den Versuchs- und Demonstrationsanlagen der 80er Jahre vielfaeltige Probleme bereitet. Im Gefolge eines erneuten Interesses an unterirdischer thermischer Energiespeicherung wurde im Dezember 1997 ein Vorhaben des IEA Energiespeicherprogramms zu Untergrund-Waermespeichern hoeherer Temperatur eingerichtet. (orig.)

  20. Thermal behavior of latent thermal energy storage unit using two phase change materials: Effects of HTF inlet temperature

    Directory of Open Access Journals (Sweden)

    Fouzi Benmoussa

    2017-09-01

    Full Text Available This work presents a numerical study of the thermal behavior of shell-and-tube latent thermal energy storage (LTES unit using two phase change materials (PCMs. The heat transfer fluid (HTF flow through the inner tube and transfer the heat to PCMs. First, a mathematical model is developed based on the enthalpy formulation and solved through the governing equations. Second, the effects of HTF inlet temperature on the unsteady temperature evolution of PCMs, the total energy stored evolution as well as the total melting time is studied. Numerical results show that for all HTF inlet temperature, melting rate of PCM1 is the fastest and that of PCM2 is the slowest; increasing the HTF inlet temperature considerably increases the temperature evolution of PCMs. The maximum energy stored is observed in PCM2 with high melting temperature and high specific heat; heat storage capacity is large for high HTF inlet temperature. When the HTF inlet temperature increases from 338 K to 353 K, decreasing degree of melting time of PCM2 is the biggest from 1870 s to 490 s, which reduces about 73.8%; decreasing degree of melting time of PCM1 is the smallest from 530 s to 270 s, which reduces about 49.1%.

  1. Impacts of convection on high-temperature aquifer thermal energy storage

    Science.gov (United States)

    Beyer, Christof; Hintze, Meike; Bauer, Sebastian

    2016-04-01

    Seasonal subsurface heat storage is increasingly used in order to overcome the temporal disparities between heat production from renewable sources like solar thermal installations or from industrial surplus heat and the heat demand for building climatisation or hot water supply. In this context, high-temperature aquifer thermal energy storage (ATES) is a technology to efficiently store and retrieve large amounts of heat using groundwater wells in an aquifer to inject or withdraw hot or cold water. Depending on the local hydrogeology and temperature amplitudes during high-temperature ATES, density differences between the injected hot water and the ambient groundwater may induce significant convective flow components in the groundwater flow field. As a consequence, stored heat may accumulate at the top of the storage aquifer which reduces the heat recovery efficiency of the ATES system. Also, an accumulation of heat at the aquifer top will induce increased emissions of heat to overlying formations with potential impacts on groundwater quality outside of the storage. This work investigates the impacts of convective heat transport on the storage efficiency of a hypothetical high-temperature ATES system for seasonal heat storage as well as heat emissions to neighboring formations by numerical scenario simulations. The coupled groundwater flow and heat transport code OpenGeoSys is used to simulate a medium scale ATES system operating in a sandy aquifer of 20 m thickness with an average groundwater temperature of 10°C and confining aquicludes at top and bottom. Seasonal heat storage by a well doublet (i.e. one fully screened "hot" and "cold" well, respectively) is simulated over a period of 10 years with biannual injection / withdrawal cycles at pumping rates of 15 m³/h and for different scenarios of the temperature of the injected water (20, 35, 60 and 90 °C). Simulation results show, that for the simulated system significant convective heat transport sets in when

  2. Low-Temperature Thermal Energy Storage Program. Annual progress report, October 1977--September 1978

    Energy Technology Data Exchange (ETDEWEB)

    Brunton, G.D.; Eissenberg, D.M.; Kedl, R.J.

    1979-05-01

    The Low-Temperature Thermal Energy Storage (LTTES) Program is part of a national effort to develop means for reducing United States dependence on oil and natural gas as primary energy sources. To this end, LTTES addresses the development of advanced sensible and latent heat storage technologies that permit substitution by solar or off-peak electrical energies or permit conservation by recovery and reuse of waste heat. Emphasis is on applying these technologies to heating and cooling of buildings. As the LTTES program continued to mature, a number of technologies were identified for development emphasis, including (1) seasonal storage of hot and cold water from waste or natural sources in aquifers, (2) short-term or daily storage of heat or coolness from solar or off-peak electrical sources in phase-change materials, and (3) recovery and reuse of rejected industrial heat through thermal storage. These areas have been further divided into three major and four minor activities; significant accomplishments are reported for each.

  3. Evaluation of bioactive compounds of black mulberry juice after thermal, microwave, ultrasonic processing, and storage at different temperatures.

    Science.gov (United States)

    Jiang, Bo; Mantri, Nitin; Hu, Ya; Lu, Jiayin; Jiang, Wu; Lu, Hongfei

    2015-07-01

    The effect of different sterilization methods (thermal, microwave, and ultrasonic processing) on the main bioactive compounds and antioxidant activity of black mulberry juice during selected storage time (8 days) and temperatures (5, 15, and 25 ℃) was investigated. The antioxidant activity of thermal-treated juice depleted with storage time, whilst both ultrasound- and microwave-treated juices showed transient increase in antioxidant activity during the first 2 days that later decreased with storage time. Lower temperature storage preserved more bioactive compounds and antioxidant activity, especially in ultrasound sterilized samples. The activation energy values were 15.99, 13.07, and 12.81 kJ/mol for ultrasonic, microwave, and thermal pasteurization processes, respectively. In general, ultrasound-sterilized samples showed higher total phenolics, anthocyanin, and antioxidant activity compared to the microwave- and thermal-processed juice during the storage time especially at lower temperatures. © The Author(s) 2014.

  4. Temperature-induced plasticity in membrane and storage lipid composition: thermal reaction norms across five different temperatures.

    Science.gov (United States)

    Van Dooremalen, Coby; Koekkoek, Jacco; Ellers, Jacintha

    2011-02-01

    Temperature is a key environmental factor inducing phenotypic plasticity in a wide range of behavioral, morphological, and life history traits in ectotherms. The strength of temperature-induced responses in fitness-related traits may be determined by plasticity of the underlying physiological or biochemical traits. Lipid composition may be an important trait underlying fitness response to temperature, because it affects membrane fluidity as well as availability of stored energy reserves. Here, we investigate the effect of temperature on lipid composition of the springtail Orchesella cincta by measuring thermal reaction norms across five different temperatures after four weeks of cold or warm acclimation. Fatty acid composition in storage and membrane lipids showed a highly plastic response to temperature, but the responses of single fatty acids revealed deviations from the expectations based on HVA theory. We found an accumulation of C(18:2n6) and C(18:3n3) at higher temperatures and the preservation of C(20:4n6) across temperatures, which is contrary to the expectation of decreased unsaturation at higher temperatures. The thermal response of these fatty acids in O. cincta differed from the findings in other species, and therefore shows there is interspecific variation in how single fatty acids contribute to HVA. Future research should determine the consequences of such variation in terms of costs and benefits for the thermal performance of species. Copyright © 2010 Elsevier Ltd. All rights reserved.

  5. Thermal energy storage devices, systems, and thermal energy storage device monitoring methods

    Science.gov (United States)

    Tugurlan, Maria; Tuffner, Francis K; Chassin, David P.

    2016-09-13

    Thermal energy storage devices, systems, and thermal energy storage device monitoring methods are described. According to one aspect, a thermal energy storage device includes a reservoir configured to hold a thermal energy storage medium, a temperature control system configured to adjust a temperature of the thermal energy storage medium, and a state observation system configured to provide information regarding an energy state of the thermal energy storage device at a plurality of different moments in time.

  6. Direct-contact high-temperature thermal energy storage heat exchanger

    Science.gov (United States)

    Alario, J. P.; Brown, R.

    1983-09-01

    A 10 kWh scale model high temperature direct contact latent heat exchange thermal energy storage system was fabricated. A research program was structured in three separate phases: (1) the inspection and evaluation of the original hardware, which suffered extensive corrosion and damage in a previous experimental program; (2) redesign and fabrication of a modified system, and (3) detailed test evaluation. In phase 1, the design was modified to eliminate previous deficiencies. Phase 2 entailed component procurement and fabrication, system assembly, and instrumentation. The results for the design and fabrication phases of the program are presented.

  7. Phase changing nanocomposites for low temperature thermal energy storage and release

    Directory of Open Access Journals (Sweden)

    A. Dorigato

    2017-09-01

    Full Text Available The aim of this paper is to develop new elastomeric phase change materials (PCM for the thermal energy storage/release below room temperature. In particular, poly(cyclooctene (PCO/paraffin blends filled with various concentrations of carbon nanotubes (CNTs, were prepared by a melt compounding process. The microstructural, thermo-mechanical and electrical properties of the resulting materials were investigated. The microstructure of these materials was characterized by the presence of paraffin domains inside the PCO, and CNTs were located only inside the paraffin domains in forms of aggregated clusters. DSC tests evidenced the existence of two distinct crystallization peaks at –10 and at 6 °C, respectively associated to the paraffin and the PCO phases, indicating that both the polymeric constituents are thermally active below room temperature. Moreover, CNT addition did not substantially alter the melting/crystallization properties of the material. Noticeable improvements of the mechanical properties and of the electrical conductivity with respect to the neat PCO/paraffin blend could be obtained upon CNT addition, and also thermal conductivity/diffusivity values were considerably enhanced above the percolation threshold. Finite element modeling demonstrated the efficacy of the prepared nanocomposites for applications in the thermal range from –30 to 6 °C.

  8. Single bi-temperature thermal storage tank for application in solar thermal plant

    Science.gov (United States)

    Litwin, Robert Zachary; Wait, David; Lancet, Robert T.

    2017-05-23

    Thermocline storage tanks for solar power systems are disclosed. A thermocline region is provided between hot and cold storage regions of a fluid within the storage tank cavity. One example storage tank includes spaced apart baffles fixed relative to the tank and arranged within the thermocline region to substantially physically separate the cavity into hot and cold storage regions. In another example, a flexible baffle separated the hot and cold storage regions and deflects as the thermocline region shifts to accommodate changing hot and cold volumes. In yet another example, a controller is configured to move a baffle within the thermocline region in response to flow rates from hot and cold pumps, which are used to pump the fluid.

  9. Evaluation of annual efficiencies of high temperature central receiver concentrated solar power plants with thermal energy storage.

    Energy Technology Data Exchange (ETDEWEB)

    Ehrhart, Brian David; Gill, David Dennis

    2013-07-01

    The current study has examined four cases of a central receiver concentrated solar power plant with thermal energy storage using the DELSOL and SOLERGY computer codes. The current state-of-the-art base case was compared with a theoretical high temperature case which was based on the scaling of some input parameters and the estimation of other parameters based on performance targets from the Department of Energy SunShot Initiative. This comparison was done for both current and high temperature cases in two configurations: a surround field with an external cylindrical receiver and a north field with a single cavity receiver. There is a fairly dramatic difference between the design point and annual average performance, especially in the solar field and receiver subsystems, and also in energy losses due to the thermal energy storage being full to capacity. Additionally, there are relatively small differences (<2%) in annual average efficiencies between the Base and High Temperature cases, despite an increase in thermal to electric conversion efficiency of over 8%. This is due the increased thermal losses at higher temperature and operational losses due to subsystem start-up and shut-down. Thermal energy storage can mitigate some of these losses by utilizing larger thermal energy storage to ensure that the electric power production system does not need to stop and re-start as often, but solar energy is inherently transient. Economic and cost considerations were not considered here, but will have a significant impact on solar thermal electric power production strategy and sizing.

  10. Microencapsulation of metal-based phase change material for high-temperature thermal energy storage.

    Science.gov (United States)

    Nomura, Takahiro; Zhu, Chunyu; Sheng, Nan; Saito, Genki; Akiyama, Tomohiro

    2015-03-13

    Latent heat storage using alloys as phase change materials (PCMs) is an attractive option for high-temperature thermal energy storage. Encapsulation of these PCMs is essential for their successful use. However, so far, technology for producing microencapsulated PCMs (MEPCMs) that can be used above 500°C has not been established. Therefore, in this study, we developed Al-Si alloy microsphere MEPCMs covered by α-Al2O3 shells. The MEPCM was prepared in two steps: (1) the formation of an AlOOH shell on the PCM particles using a boehmite treatment, and (2) heat-oxidation treatment in an O2 atmosphere to form a stable α-Al2O3 shell. The MEPCM presented a melting point of 573°C and latent heat of 247 J g(-1). The cycling performance showed good durability. These results indicated the possibility of using MEPCM at high temperatures. The MEPCM developed in this study has great promise in future energy and chemical processes, such as exergy recuperation and process intensification.

  11. High Temperature Latent Heat Thermal Energy Storage to Augment Solar Thermal Propulsion for Microsatellites

    Science.gov (United States)

    2015-08-30

    heat of fusion . In this work, boron is considered a long-term high performance solution and silicon is presented as a near term development target with... conceptual studies. However, there have been no thorough investigations due to the absence of existing research in addition to cost and schedule constraints...driven by a nuclear thermal energy source. Zubrin et al. proposed a “bi-modal” approach which modified an existing 40 kWe nuclear-thermionic reactor

  12. High Temperature Latent Heat Thermal Energy Storage to Augment Solar Thermal Propulsion for Microsatellites

    Science.gov (United States)

    2014-03-01

    assumptions of  iso thermal test sections  were inaccurate • Demonstrated shielding efficiency of approx.  55% with hand polished aluminum shields • Must...Calculations TWO IMPULSE ONE PERIGEE BURN ONE APOGEE BURN TIW > 0.01 .. ’• ’ \\ ’ ’ ’ • (!),/ LEO TO GEO 14000 ~ I!N < 17000 FPS TRIP TIME < DAY...I MULTI I MPU SE MORE THAN ONf PER I GEE BURNS AND PWRE THAN ON£ nlNSERTJON" BURNS NEAR FINAL APOGEE LEO TO GEO 14000 ~ /lV ~ 19200 FPS TRIP

  13. High temperature storage loop :

    Energy Technology Data Exchange (ETDEWEB)

    Gill, David Dennis; Kolb, William J.

    2013-07-01

    A three year plan for thermal energy storage (TES) research was created at Sandia National Laboratories in the spring of 2012. This plan included a strategic goal of providing test capability for Sandia and for the nation in which to evaluate high temperature storage (>650ÀC) technology. The plan was to scope, design, and build a flow loop that would be compatible with a multitude of high temperature heat transfer/storage fluids. The High Temperature Storage Loop (HTSL) would be reconfigurable so that it was useful for not only storage testing, but also for high temperature receiver testing and high efficiency power cycle testing as well. In that way, HTSL was part of a much larger strategy for Sandia to provide a research and testing platform that would be integral for the evaluation of individual technologies funded under the SunShot program. DOEs SunShot program seeks to reduce the price of solar technologies to 6/kWhr to be cost competitive with carbon-based fuels. The HTSL project sought to provide evaluation capability for these SunShot supported technologies. This report includes the scoping, design, and budgetary costing aspects of this effort

  14. Selection of high temperature thermal energy storage materials for advanced solar dynamic space power systems

    Science.gov (United States)

    Lacy, Dovie E.; Coles-Hamilton, Carolyn; Juhasz, Albert

    1987-01-01

    Under the direction of NASA's Office of Aeronautics and Technology (OAST), the NASA Lewis Research Center has initiated an in-house thermal energy storage program to identify combinations of phase change thermal energy storage media for use with a Brayton and Stirling Advanced Solar Dynamic (ASD) space power system operating between 1070 and 1400 K. A study has been initiated to determine suitable combinations of thermal energy storage (TES) phase change materials (PCM) that result in the smallest and lightest weight ASD power system possible. To date the heats of fusion of several fluoride salt mixtures with melting points greater than 1025 K have been verified experimentally. The study has indicated that these salt systems produce large ASD systems because of their inherent low thermal conductivity and low density. It is desirable to have PCMs with high densities and high thermal conductivities. Therefore, alternate phase change materials based on metallic alloy systems are also being considered as possible TES candidates for future ASD space power systems.

  15. Direct-contact high-temperature thermal energy storage heat exchanger. Final subcontract report

    Energy Technology Data Exchange (ETDEWEB)

    Alario, J.; Brown, R.

    1983-09-01

    A 10-kWh scale model high-temperature direct-contact latent-heat-exchange thermal energy storage system was designed and fabricated. A research program was structured in three separate phases to permit: Phase I - the inspection and evaluation of the origin al hardware, which suffered extensive corrosion and damage in a previous experimental program; Phase II - redesign and fabrication of a modified system; and Phase III - detailed test evaluation. On the basis of the findings in Phase I, the design was modified to eliminate previous deficiencies. A test plan was also prepared that contained detailed information concerning instrumentation (type and location), measured parameters, and equipment operating procedures. Phase II entailed component procurement and fabrication, system assembly, and instrumentation. At the end of Phase II, the system was in a ready-for-test condition but the program was terminated before the start of the Phase III test evaluation. Since testing was never implemented, this report presents only the results for the design and fabrication phases of the program.

  16. METHOD OF CALCULATION OF THE NON-STATIONARY TEMPERATURE FIELD INSIDE OF THERMAL PACKED BED ENERGY STORAGE

    Directory of Open Access Journals (Sweden)

    Ermuratschii V.V.

    2014-04-01

    Full Text Available e paper presents a method of the approximate calculation of the non-stationary temperature field inside of thermal packed bed energy storages with feasible and latent heat. Applying thermoelectric models and computational methods in electrical engineering, the task of computing non-stationary heat transfer is resolved with respect to third type boundary conditions without applying differential equations of the heat transfer. For sub-volumes of the energy storage the method is executed iteratively in spatiotemporal domain. Single-body heating is modeled for each sub-volume, and modeling conditions are assumed to be identical for remained bod-ies, located in the same sub-volume. For each iteration step the boundary conditions will be represented by re-sults at the previous step. The fulfillment of the first law of thermodynamics for system “energy storage - body” is obtained by the iterative search of the mean temperature of the energy storage. Under variable boundary con-ditions the proposed method maybe applied to calculating temperature field inside of energy storages with packed beds consisted of solid material, liquid and phase-change material. The method may also be employed to compute transient, power and performance characteristics of packed bed energy storages.

  17. More with thermal energy storage. Report 6. High temperature storage. Overview of knowledge and results of measurements with regard to high temperature storage systems. Final report; Meer met bodemenergie. Rapport 6. Hogetemperatuuropslag. Kennisoverzicht en praktijkmetingen rondom hogetemperatuuropslagsystemen. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Drijver, B. [IF Technology, Arnhem (Netherlands)

    2012-03-30

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. This report includes the results of research in the field of high temperature heat storage. Residual heat, which comes available in the summer can be used for heating purposes in the winter. To realize that heat can be stored temporarily. It appears that the subsurface can be used, which has resulted in a strong growth of heat and cold storage systems [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water- en energieketen?; (3) Is het mogelijk om meerdere doelstellingen tegelijk te verwezenlijken door slimme combinaties te maken? Het

  18. Electricity storage using a thermal storage scheme

    Science.gov (United States)

    White, Alexander

    2015-01-01

    The increasing use of renewable energy technologies for electricity generation, many of which have an unpredictably intermittent nature, will inevitably lead to a greater demand for large-scale electricity storage schemes. For example, the expanding fraction of electricity produced by wind turbines will require either backup or storage capacity to cover extended periods of wind lull. This paper describes a recently proposed storage scheme, referred to here as Pumped Thermal Storage (PTS), and which is based on "sensible heat" storage in large thermal reservoirs. During the charging phase, the system effectively operates as a high temperature-ratio heat pump, extracting heat from a cold reservoir and delivering heat to a hot one. In the discharge phase the processes are reversed and it operates as a heat engine. The round-trip efficiency is limited only by process irreversibilities (as opposed to Second Law limitations on the coefficient of performance and the thermal efficiency of the heat pump and heat engine respectively). PTS is currently being developed in both France and England. In both cases, the schemes operate on the Joule-Brayton (gas turbine) cycle, using argon as the working fluid. However, the French scheme proposes the use of turbomachinery for compression and expansion, whereas for that being developed in England reciprocating devices are proposed. The current paper focuses on the impact of the various process irreversibilities on the thermodynamic round-trip efficiency of the scheme. Consideration is given to compression and expansion losses and pressure losses (in pipe-work, valves and thermal reservoirs); heat transfer related irreversibility in the thermal reservoirs is discussed but not included in the analysis. Results are presented demonstrating how the various loss parameters and operating conditions influence the overall performance.

  19. Integrated Thermal Energy Storage

    OpenAIRE

    Kopko, William L.

    2016-01-01

    Integrated Thermal Energy Storage (ITES) is a novel concept in improving cooling performance of air-conditioning systems at peak-load conditions. In contrast to conventional chilled-water or ice storage, it uses stored chilled water to subcool condenser refrigerant liquid instead of supplying cooling directly to a cooling load. For typical R-134a and R-410A systems, subcooling increases capacity by approximately .5 to .7%/°F (~.9 to 1.3 %/K) without increasing compressor input power. Even l...

  20. Local Thermal Insulating Materials For Thermal Energy Storage ...

    African Journals Online (AJOL)

    Thermal insulation is one of the most important components of a thermal energy storage system. In this paper the thermal properties of selected potential local materials which can be used for high temperature insulation are presented. Thermal properties of seven different samples were measured. Samples consisted of: ...

  1. Thermal energy storage apparatus, controllers and thermal energy storage control methods

    Science.gov (United States)

    Hammerstrom, Donald J.

    2016-05-03

    Thermal energy storage apparatus, controllers and thermal energy storage control methods are described. According to one aspect, a thermal energy storage apparatus controller includes processing circuitry configured to access first information which is indicative of surpluses and deficiencies of electrical energy upon an electrical power system at a plurality of moments in time, access second information which is indicative of temperature of a thermal energy storage medium at a plurality of moments in time, and use the first and second information to control an amount of electrical energy which is utilized by a heating element to heat the thermal energy storage medium at a plurality of moments in time.

  2. Capital cost expenditure of high temperature latent and sensible thermal energy storage systems

    Science.gov (United States)

    Jacob, Rhys; Saman, Wasim; Bruno, Frank

    2017-06-01

    In the following study cost estimates have been undertaken for an encapsulated phase change material (EPCM) packed bed, a packed bed thermocline and a traditional two-tank molten salt system. The effect of various heat transfer fluids (air and molten salt), system configuration (cascade vs one PCM, and direct vs indirect) and temperature difference (ΔT = 100-500 °C) on the cost estimate of the system was also investigated. Lastly, the storage system boundary was expanded to include heat exchangers, pumps and fans, and heat tracing so that a thorough cost comparison could be undertaken. The results presented in this paper provide a methodology to quickly compare various systems and configurations while providing design limits for the studied technologies.

  3. Geological exploration for a high-temperature aquifer thermal energy storage (HT-ATES) system: a case study from Oman

    Science.gov (United States)

    Winterleitner, Gerd; Schütz, Felina; Huenges, Ernst

    2017-04-01

    , as second potential storage horizon, were deposited in a carbonate ramp setting. Individual facies belts extend over kilometres and thus horizontal reservoir connectivity is expected to be good with minor facies variability. Thin-section analyses point to the fossil-rich sections with high porosities and permeabilities and thus good storage qualities. Fluid flow and thermal modelling indicate that both potential storage horizons show good to very good storage characteristics but also have challenges such as reservoir heterogeneity and connectivity. In particular the tilting of the thermocline, specific to high-temperature systems poses a major challenge. We investigated scenarios to counterbalance the distortion of the subsurface heat-plume, which includes adjustments of the salinity contrast between injected and aquifer fluid to prohibit buoyancy-driven flow. Additionally, geological structures ("HT-ATES traps" e.g.: fault structures) were modelled in detail in order to analyse their suitability as high-temperature storage system. First results show that an effective HT-ATES trap is necessary in the alluvial fan system in order to keep in control of the heat-plume. Salinity adjustments are sufficient in the carbonate-dominated sequences where vertical permeability contrasts are higher and constitute natural vertical flow barriers.

  4. Body Temperature Controlled Optical and Thermal Information Storage Light Scattering Display with Fluorescence Effect and High Mechanical Strength.

    Science.gov (United States)

    Chen, Si; Tong, Xiaoqian; He, Huiwen; Ma, Meng; Shi, Yanqin; Wang, Xu

    2017-04-05

    A kind of body temperature controlled optical and thermal information storage light scattering display based on super strong liquid crystalline physical gel with special "loofah-like gel network" was successfully prepared. Such liquid crystal (LC) gel was obtained by mixing a dendritic gelator (POSS-G1-BOC), an azobenzene compound (2Azo2), and a phosphor tethered liquid crystalline host (5CB), which could show its best contrast ratio at around human body temperature under UV light because of the phosphor's fluorescence effect. The gel also has quite strong mechanical strength, which could be used in wearable device field especially under sunlight, even under the forcing conditions as harsh as being centrifuged for 10 min at the speed of 2000 r/min. The whole production process of such a display is quite simple and could lead to displays at any size through noncontact writing. We believe it will have wide applications in the future.

  5. Geomechanical characterization of the Upper Carboniferous under thermal stress for the evaluation of a High Temperature - Mine Thermal Energy Storage (HT-MTES)

    Science.gov (United States)

    Hahn, Florian; Brüggemann, Nina; Bracke, Rolf; Alber, Michael

    2017-04-01

    The goal of this R&D project is to create a technically and economically feasible conceptual model for a High Temperature - Mine Thermal Energy Storage (HT-MTES) for the energetic reuse of a mine on the example of the Prosper-Haniel coal mine in Bottrop, Germany. This project is funded by the "Initiative Energy Storage" program of the German Federal Ministries BMWi, BMU and BMBF. At the end of 2018, the last operative coal mine in North Rhine-Westphalia, Germany (Prosper-Haniel), is going to be closed down, plugged and abandoned. Large amounts of subsurface infrastructures, resembled mainly by open parts of former galleries and mining faces are going to be flooded, after the mine is closed down and therefore have the potential to become an enormous geothermal reservoir for a seasonal heat storage. During the summer non-used (waste) heat from solar thermal power plants, garbage incineration, combined heat and power plants (CHP) or industrial production processes can be stored within dedicated drifts of the mine. During the winter season, this surplus heat can be extracted and directly utilized in commercial and/or residential areas. For the evaluation of such a HT-MTES within a former coal mine, the corresponding geomechanical parameters of the Upper Carboniferous under thermal stress needs to be evaluated. Therefore the main rock types of the Upper Carboniferous (claystone, siltstone and sandstone) are subject to a geomechanical characterization before and after thermal cyclic loadings of temperatures up to 200 °C. The samples have been collected directly from the coal mine Prosper-Haniel within a depth range of 1000 - 1200 m. Unconfined compressive and tensile strengths, as well as triaxial tests were performed at room temperature. Furthermore, a range of petrophysical properties like density, thin-section analysis and P-wave velocities were determined. First results show an indication that the overall strength properties of the samples are not effected by

  6. Dehydration/hydration of granular beds for thermal storage applications: A combined NMR and temperature study

    NARCIS (Netherlands)

    Donkers, P.A.J.; Pel, L.; Adan, O.C.G.

    2017-01-01

    For heat/cold storage systems a granular bed of salt hydrates is studied during dehydration/hydration. The water density in these beds are measured with help of NMR. Diffusion based dehydration of a granular bed of Na2SO4·10H2O is shown to be internally limited as larger grains dehydrate faster than

  7. On vacuum-insulated thermal storage

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, Benjamin [Georg-Simon-Ohm Univ. of Applied Sciences, Nuernberg (Germany); Technische Univ. Muenchen (Germany). Inst. of Resource and Energy Technology; Hofbeck, Klaus [Georg-Simon-Ohm Univ. of Applied Sciences, Nuernberg (Germany)

    2011-07-01

    Nowadays, the insulation for thermal energy storage (TES) is not as good as it should be. One reason for this is the higher investment cost for better insulation. Nevertheless, most of the recent studies show that the thermal losses of long-term storage have been underestimated. Therefore, recent research studies have focused on vacuum-insulated thermal storage. There are two common concepts with regard to the use of vacuum insulation for thermal storage. On the one hand, the Center for Applied Energy Research (ZAE) in Munich uses an evacuated double vessel filled with pearlite. On the other hand, the Ohm University uses vacuum insulation panels (VIP). Both the insulation concepts are based on the Knudsen effect. Thus, the thermal conductivity is lowered by a factor of 6-10, when compared with the conventional insulation materials, such as EPS, XPS, or mineral wool. Both the concepts are adoptions of the existing insulation applications. The filled double vessel tank is already being used for cryogenic storage for liquid gases. Furthermore, VIPs are being used to insulate passive houses. However, the use of vacuum insulation for thermal energy storage causes different problems due to higher temperatures and moisture. Nevertheless, vacuum insulations are a promising solution for small thermal long-tenn storage. This study presents the first state-of-the-art review on vacuum-insulated thermal tanks.

  8. The use of salinity contrast for density difference compensation to improve the thermal recovery efficiency in high-temperature aquifer thermal energy storage systems

    Science.gov (United States)

    van Lopik, Jan H.; Hartog, Niels; Zaadnoordijk, Willem Jan

    2016-08-01

    The efficiency of heat recovery in high-temperature (>60 °C) aquifer thermal energy storage (HT-ATES) systems is limited due to the buoyancy of the injected hot water. This study investigates the potential to improve the efficiency through compensation of the density difference by increased salinity of the injected hot water for a single injection-recovery well scheme. The proposed method was tested through numerical modeling with SEAWATv4, considering seasonal HT-ATES with four consecutive injection-storage-recovery cycles. Recovery efficiencies for the consecutive cycles were investigated for six cases with three simulated scenarios: (a) regular HT-ATES, (b) HT-ATES with density difference compensation using saline water, and (c) theoretical regular HT-ATES without free thermal convection. For the reference case, in which 80 °C water was injected into a high-permeability aquifer, regular HT-ATES had an efficiency of 0.40 after four consecutive recovery cycles. The density difference compensation method resulted in an efficiency of 0.69, approximating the theoretical case (0.76). Sensitivity analysis showed that the net efficiency increase by using the density difference compensation method instead of regular HT-ATES is greater for higher aquifer hydraulic conductivity, larger temperature difference between injection water and ambient groundwater, smaller injection volume, and larger aquifer thickness. This means that density difference compensation allows the application of HT-ATES in thicker, more permeable aquifers and with larger temperatures than would be considered for regular HT-ATES systems.

  9. COSTS OF THERMAL ENERGY STORAGE TECHNOLOGIES

    Directory of Open Access Journals (Sweden)

    Debrayan Bravo Hidalgo

    2017-10-01

    Full Text Available Thermal accumulation facilities allow energy to be available in the absence of sunlight. This fact reduces the difficulty of the intermittence in the incidence of the king star in our planet. Thermal accumulation technology also contributes to smooth the fluctuations in energy demand during different times of the day. This contribution identifies the nations with the most favorable research results in this area; as well as the main research lines that are being developed today. A compendium of various thermal energy storage materials, their current costs per unit mass, and their physical properties are presented. Techniques for implementing thermal accumulation technologies can be classified as areas of high, medium and low temperature. In the high temperature area, inorganic materials such as nitrate salts are the most widely used thermal energy storage materials, while in the medium and lower temperature areas; organic materials such as commercial paraffin are more common. Currently, one of the research trends in this area are the projects aimed at optimizing the chemical and physical characteristics of thermal storage materials, because the success of any thermos-energetic storage technology has a strong dependence on the cost of the materials selected for thermal storage.

  10. Parametric analysis of a high temperature packed bed thermal storage design for a solar gas turbine

    CSIR Research Space (South Africa)

    Klein, P

    2015-08-01

    Full Text Available , conductive and radiative heat transfer mechanisms and is validated against high temperature experimental data from a laboratory scale test facility. The validated model is further utilised to conduct a parametric design study of a nominal six hour TES (1:55MW...

  11. Temperature-induced plasticity in membrane and storage lipid composition: Thermal reaction norms across five different temperatures.

    NARCIS (Netherlands)

    van Dooremalen, J.A.; Koekkoek, J.; Ellers, J.

    2011-01-01

    Temperature is a key environmental factor inducing phenotypic plasticity in a wide range of behavioral, morphological, and life history traits in ectotherms. The strength of temperature-induced responses in fitness-related traits may be determined by plasticity of the underlying physiological or

  12. Temperature-induced plasticity in membrane and storage lipid composition: Thermal reaction norms across five different temperatures

    NARCIS (Netherlands)

    Dooremalen, van C.; Koekkoek, J.; Ellers, J.

    2011-01-01

    Temperature is a key environmental factor inducing phenotypic plasticity in a wide range of behavioral, morphological, and life history traits in ectotherms. The strength of temperature-induced responses in fitness-related traits may be determined by plasticity of the underlying physiological or

  13. Biogeochemical aspects of aquifer thermal energy storage

    NARCIS (Netherlands)

    Brons, H.J.

    1992-01-01

    During the process of aquifer thermal energy storage the in situ temperature of the groundwater- sediment system may fluctuate significantly. As a result the groundwater characteristics can be considerably affected by a variety of chemical, biogeochemical and microbiological

  14. Micro-scale thermal imaging of CO2 absorption in the thermochemical energy storage of Li metal oxides at high temperature

    Science.gov (United States)

    Morikawa, Junko; Takasu, Hiroki; Zamengo, Massimiliano; Kato, Yukitaka

    2017-05-01

    Li-Metal oxides (typical example: lithium ortho-silicate Li4SiO4) are regarded as a novel solid carbon dioxide CO2 absorbent accompanied by an exothermic reaction. At temperatures above 700°C the sorbent is regenerated with the release of the captured CO2 in an endothermic reaction. As the reaction equilibrium of this reversible chemical reaction is controllable only by the partial pressure of CO2, the system is regarded as a potential candidate for chemical heat storage at high temperatures. In this study, we applied our recent developed mobile type instrumentation of micro-scale infrared thermal imaging system to observe the heat of chemical reaction of Li4SiO4 and CO2 at temperature higher than 600°C or higher. In order to quantify the micro-scale heat transfer and heat exchange in the chemical reaction, the superimpose signal processing system is setup to determine the precise temperature. Under an ambient flow of carbon dioxide, a powder of Li4SiO4 with a diameter 50 micron started to shine caused by an exothermic chemical reaction heat above 600°C. The phenomena was accelerated with increasing temperature up to 700°C. At the same time, the reaction product lithium carbonate (Li2CO3) started to melt with endothermic phase change above 700°C, and these thermal behaviors were captured by the method of thermal imaging. The direct measurement of multiple thermal phenomena at high temperatures is significant to promote an efficient design of chemical heat storage materials. This is the first observation of the exothermic heat of the reaction of Li4SiO4 and CO2 at around 700°C by the thermal imaging method.

  15. More with thermal energy storage. Report 8. Autonomous heating. Autonomous development of ground temperature. Final report; Meer met bodemenergie. Rapport 8. Autonome opwarming. Autonome ontwikkeling bodemtemperatuur. Eindrapport

    Energy Technology Data Exchange (ETDEWEB)

    Drijver, B. [IF Technology, Arnhem (Netherlands)

    2012-03-30

    The project More With Thermal Energy Storage (MMB, abbreviated in Dutch) focuses on knowledge gaps and potential opportunities regarding open systems. The main questions to be answered are: (1) What effects (hydrological, thermal, microbiological and chemical) occur in the soil system by application of thermal energy storage; (2) Which technical options are available for a sustainable integration of thermal energy storage in the water and energy chain?; (3) Is it possible to achieve multiple objectives by using smart combinations? The project is organized in different work packages. In work package 2, the effects of individual and collective thermal energy storage storage systems on subsoils and the environment are determined. In work package 3 the opportunities for thermal energy storage and soil remediation are examined, while in work package 4 the focus is on new sustainable combinations of heat and cold storage. Work package 1 is the umbrella part where communication and policy of and participation in MMB are the main subjects. This report contains an analysis of the thermal impact of climate change and urbanization on the soil temperature. Attention is paid to the autonomous heating of the subsurface that occurred since 1900 and that still may be expected up to 2040. A distinction is made between rural areas, where only the climate change plays a role, and urban areas, where the UHI effect (Urban Heat Island) is of importance [Dutch] Het project Meer Met Bodemenergie (MMB) richt zich op het invullen van kennisleemtes en mogelijke kansen ten aanzien van open systemen. De belangrijkste vragen waarop het onderzoeksprogramma MMB antwoord geeft zijn: (1) Welke effecten (hydrologisch, thermisch, microbiologisch en chemisch) treden op in het bodemsysteem bij toepassing van bodemenergie?; (2) Welke technische mogelijkheden zijn er voor het duurzaam inpassen van bodem-energie in de water- en energieketen?; (3) Is het mogelijk om meerdere doelstellingen tegelijk te

  16. High Temperature Aquifer Storage

    Science.gov (United States)

    Ueckert, Martina; Niessner, Reinhard; Baumann, Thomas

    2016-04-01

    Combined heat and power generation (CHP) is highly efficient because excess heat is used for heating and/or process energy. However, the demand of heat energy varies considerably throughout the year while the demand for electrical energy is rather constant. It seems economically and ecologically highly beneficial for municipalities and large power consumers such as manufacturing plants to store excess heat in groundwater aquifers and to recuperate this energy at times of higher demand. Within the project High Temperature Aquifer Storage, scientists investigate storage and recuperation of excess heat energy into the bavarian Malm aquifer. Apart from high transmissivity and favorable pressure gradients, the hydrochemical conditions are crucial for long-term operation. An enormous technical challenge is the disruption of the carbonate equilibrium - modeling results indicated a carbonate precipitation of 10 - 50 kg/d in the heat exchangers. The test included five injection pulses of hot water (60 °C up to 110 °C) and four tracer pulses, each consisting of a reactive and a conservative fluorescent dye, into a depth of about 300 m b.s.l. resp. 470 m b.s.l. Injection and production rates were 15 L/s. To achieve the desired water temperatures, about 4 TJ of heat energy were necessary. Electrical conductivity, pH and temperature were recorded at a bypass where also samples were taken. A laboratory container at the drilling site was equipped for analysing the concentration of the dyes and the major cations at sampling intervals of down to 15 minutes. Additional water samples were taken and analysed in the laboratory. The disassembled heat exchanger prooved that precipitation was successfully prevented by adding CO2 to the water before heating. Nevertheless, hydrochemical data proved both, dissolution and precipitation processes in the aquifer. This was also suggested by the hydrochemical modelling with PhreeqC and is traced back to mixture dissolution and changing

  17. Thermal energy storage for smart grid applications

    Science.gov (United States)

    Al-Hallaj, Said; Khateeb, Siddique; Aljehani, Ahmed; Pintar, Mike

    2018-01-01

    Energy consumption for commercial building cooling accounts for 15% of all commercial building's electricity usage [1]. Electric utility companies charge their customers time of use consumption charges (/kWh) and additionally demand usage charges (/kW) to limit peak energy consumption and offset their high operating costs. Thus, there is an economic incentive to reduce both the electricity consumption charges and demand charges by developing new energy efficient technologies. Thermal energy storage (TES) systems using a phase change material (PCM) is one such technology that can reduce demand charges and shift the demand from on-peak to off-peak rates. Ice and chilled water have been used in thermal storage systems for many decades, but they have certain limitations, which include a phase change temperature of 0 degrees Celsius and relatively low thermal conductivity in comparison to other materials, which limit their applications as a storage medium. To overcome these limitations, a novel phase change composite (PCC) TES material was developed that has much higher thermal conductivity that significantly improves the charge / discharge rate and a customizable phase change temperature to allow for better integration with HVAC systems. Compared to ice storage, the PCC TES system is capable of very high heat transfer rate and has lower system and operational costs. Economic analysis was performed to compare the PCC TES system with ice system and favorable economics was proven. A 4.5 kWh PCC TES prototype system was also designed for testing and validation purpose.

  18. Medium Deep High Temperature Heat Storage

    Science.gov (United States)

    Bär, Kristian; Rühaak, Wolfram; Schulte, Daniel; Welsch, Bastian; Chauhan, Swarup; Homuth, Sebastian; Sass, Ingo

    2015-04-01

    Heating of buildings requires more than 25 % of the total end energy consumption in Germany. Shallow geothermal systems for indirect use as well as shallow geothermal heat storage systems like aquifer thermal energy storage (ATES) or borehole thermal energy storage (BTES) typically provide low exergy heat. The temperature levels and ranges typically require a coupling with heat pumps. By storing hot water from solar panels or thermal power stations with temperatures of up to 110 °C a medium deep high temperature heat storage (MDHTS) can be operated on relatively high temperature levels of more than 45 °C. Storage depths of 500 m to 1,500 m below surface avoid conflicts with groundwater use for drinking water or other purposes. Permeability is typically also decreasing with greater depth; especially in the crystalline basement therefore conduction becomes the dominant heat transport process. Solar-thermal charging of a MDHTS is a very beneficial option for supplying heat in urban and rural systems. Feasibility and design criteria of different system configurations (depth, distance and number of BHE) are discussed. One system is designed to store and supply heat (300 kW) for an office building. The required boreholes are located in granodioritic bedrock. Resulting from this setup several challenges have to be addressed. The drilling and completion has to be planned carefully under consideration of the geological and tectonical situation at the specific site.

  19. Electric thermal storage demonstration program

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and on affiliate in Rhode Island, responded to a DOE request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. This report discusses the demonstration of ETS equipment at four member light departments.

  20. Electric thermal storage demonstration program

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and on affiliate in Rhode Island, responded to a DOE request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. This report discusses the demonstration of ETS equipment at four member light departments.

  1. Electric thermal storage demonstration program

    Energy Technology Data Exchange (ETDEWEB)

    1992-01-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and one affiliate in Rhode Island, responded to a Department of Energy request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. In this progress report, cost savings at Bolyston light department is discussed. (JL)

  2. Electric thermal storage demonstration program

    Energy Technology Data Exchange (ETDEWEB)

    1992-02-01

    In early 1989, MMWEC, a joint action agency comprised of 30 municipal light departments in Massachusetts and one affiliate in Rhode Island, responded to a Department of Energy request to proposal for the Least Cost Utility Planning program. The MMWEC submission was for the development of a program, focused on small rural electric utilities, to promote the use of electric thermal storage heating systems in residential applications. In this progress report, cost savings at Bolyston light department is discussed. (JL)

  3. Optimization of air conditioning systems utilizing low temperature thermal storage; Optimizacion de sistemas de acondicionamiento de aire utilizando sistemas de almacenamiento termico de baja temperatura

    Energy Technology Data Exchange (ETDEWEB)

    Contreras Ramirez, J.; Dorantes Rodriguez, R. [Departamento de Energia, Universidad Autonoma Metropolitana - Unidad Azcapotzalco, Mexico, D. F. (Mexico)

    1997-12-31

    In the last few years the different projects on the saving and efficient use of energy in the tertiary sector have been demonstrating the existing great potential in the air conditioning systems and equipment, whose intensive use is due to the predominance of hot and dry and hot and humid climate prevailing in a large part of the Mexican territory. Without any doubts one of the most serious problems facing the complex management and optimization of these systems is related to the variability of the thermal load and the regulation possibilities of the thermal machines, so as to attain, along the day an appropriate use and optimization of the total installed load, with the best possible economic benefits. Among the strategies that allow the optimization of the installed capacity and the variability of the thermal load is the low temperature thermal storage, for instance, the storage of ice, which is produced and stored to be used when the cooling machines are in standby in order to use this stored energy during the peak hours and during the normal operation of the equipment, but diminishing in a significant amount the electrical demand of the system to satisfy the thermal load with a combination thermal storage-cooling machine. This paper presents some case histories and the type of thermal storage commonly used; a methodology is discussed that allows to determine technically as well as economically the size of a thermal storage room. Some problems in the control and operation of these thermal systems are also presented. [Espanol] En los ultimos anos los diversos proyectos sobre ahorro y uso eficiente de la energia en el sector terciario han venido mostrando el gran potencial existente en los sistemas y equipos de aire acondicionado, cuyo uso intensivo se debe al predominio de los climas calidos seco y calido humedo en buena parte del territorio nacional. Sin lugar a dudas uno de los problemas mas serios que enfrenta la compleja gestion y optimizacion de estos

  4. Fuel Temperature Fluctuations During Storage

    Science.gov (United States)

    Levitin, R. E.; Zemenkov, Yu D.

    2016-10-01

    When oil and petroleum products are stored, their temperature significantly impacts how their properties change. The paper covers the problem of determining temperature fluctuations of hydrocarbons during storage. It provides results of the authors’ investigations of the stored product temperature variations relative to the ambient temperature. Closeness and correlation coefficients between these values are given. Temperature variations equations for oil and petroleum products stored in tanks are deduced.

  5. Thermal energy storage in phase change material

    Science.gov (United States)

    White, P.; Buchlin, J. M.

    1982-03-01

    The present study deals with an experimental investigation of low temperature thermal storage based on macroencapsulation of Phase Change Material (PCM). The storage performance capabilities of capsule bed, tube bank and tubular single-pass heat exchanger are compared. The tests are conducted on the VKI Solar Utility Network (SUN) which is a closed loop facility designed to study air heating systems. An original data acquisition chain based on two conversing microprocessors is developed to carry out mass flow, pressure drop and temperature measurements. The experimental results are interpreted on the basis of comparison with numerical predictions and they allow to draw the following conclusions. Each type of matrix has its own range of operation for practical application but from a heat transfer standpoint, the PCM capsule packing unit is strongly recommended. It is suggested to extend this investigation to the effect of Reynolds number to find optimum range for thermomechanical efficiency.

  6. Solar energy thermalization and storage device

    Science.gov (United States)

    McClelland, J.F.

    A passive solar thermalization and thermal energy storage assembly which is visually transparent is described. The assembly consists of two substantial parallel, transparent wall members mounted in a rectangular support frame to form a liquid-tight chamber. A semitransparent thermalization plate is located in the chamber, substantially paralled to and about equidistant from the transparent wall members to thermalize solar radiation which is stored in a transparent thermal energy storage liquid which fills the chamber. A number of the devices, as modules, can be stacked together to construct a visually transparent, thermal storage wall for passive solar-heated buildings.

  7. Thermal energy storage in granular deposits

    Science.gov (United States)

    Ratuszny, Paweł

    2017-10-01

    Energy storage technology is crucial for the development of the use of renewable energy sources. This is a substantial constraint, however it can, to some extent, be solved by storing energy in its various forms: electrical, mechanical, chemical and thermal. This article presents the results of research in thermal properties of granular deposits. Correlation between temperature changes in the stores over a period of time and their physical properties has been studied. The results of the research have practical application in designing thermal stores based on bulk materials and ground deposits. Furthermore, the research results are significant for regeneration of the lower ground sources for heat pumps and provide data for designing ground heat exchangers for ventilation systems.

  8. Aquifer thermal energy storage. International symposium: Proceedings

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-05-01

    Aquifers have been used to store large quantities of thermal energy to supply process cooling, space cooling, space heating, and ventilation air preheating, and can be used with or without heat pumps. Aquifers are used as energy sinks and sources when supply and demand for energy do not coincide. Aquifer thermal energy storage may be used on a short-term or long-term basis; as the sole source of energy or as a partial storage; at a temperature useful for direct application or needing upgrade. The sources of energy used for aquifer storage are ambient air, usually cold winter air; waste or by-product energy; and renewable energy such as solar. The present technical, financial and environmental status of ATES is promising. Numerous projects are operating and under development in several countries. These projects are listed and results from Canada and elsewhere are used to illustrate the present status of ATES. Technical obstacles have been addressed and have largely been overcome. Cold storage in aquifers can be seen as a standard design option in the near future as it presently is in some countries. The cost-effectiveness of aquifer thermal energy storage is based on the capital cost avoidance of conventional chilling equipment and energy savings. ATES is one of many developments in energy efficient building technology and its success depends on relating it to important building market and environmental trends. This paper attempts to provide guidance for the future implementation of ATES. Individual projects have been processed separately for entry onto the Department of Energy databases.

  9. Aquifer Thermal Energy Storage for Seasonal Thermal Energy Balance

    Science.gov (United States)

    Rostampour, Vahab; Bloemendal, Martin; Keviczky, Tamas

    2017-04-01

    Aquifer Thermal Energy Storage (ATES) systems allow storing large quantities of thermal energy in subsurface aquifers enabling significant energy savings and greenhouse gas reductions. This is achieved by injection and extraction of water into and from saturated underground aquifers, simultaneously. An ATES system consists of two wells and operates in a seasonal mode. One well is used for the storage of cold water, the other one for the storage of heat. In warm seasons, cold water is extracted from the cold well to provide cooling to a building. The temperature of the extracted cold water increases as it passes through the building climate control systems and then gets simultaneously, injected back into the warm well. This procedure is reversed during cold seasons where the flow direction is reversed such that the warmer water is extracted from the warm well to provide heating to a building. From the perspective of building climate comfort systems, an ATES system is considered as a seasonal storage system that can be a heat source or sink, or as a storage for thermal energy. This leads to an interesting and challenging optimal control problem of the building climate comfort system that can be used to develop a seasonal-based energy management strategy. In [1] we develop a control-oriented model to predict thermal energy balance in a building climate control system integrated with ATES. Such a model however cannot cope with off-nominal but realistic situations such as when the wells are completely depleted, or the start-up phase of newly installed wells, etc., leading to direct usage of aquifer ambient temperature. Building upon our previous work in [1], we here extend the mathematical model for ATES system to handle the above mentioned more realistic situations. Using our improved models, one can more precisely predict system behavior and apply optimal control strategies to manage the building climate comfort along with energy savings and greenhouse gas reductions

  10. Fluoride salts as phase change materials for thermal energy storage in the temperature range 1000-1400 K

    Science.gov (United States)

    Misra, Ajay K.

    1988-01-01

    Eutectic compositions and congruently melting intermediate compounds in binary and ternary fluoride salt systems were characterized for potential use as latent heat of fusion phase change materials to store thermal energy in the temperature range 1000-1400 K. The melting points and eutectic compositions for many systems with published phase diagrams were experimentally verified and new eutectic compositions having melting points between 1000 and 1400 K were identified. Heats of fusion of several binary and ternary eutectics and congruently melting compounds were experimentally measured by differential scanning calorimetry. For a few systems in which heats of mixing in the melts have been measured, heats of fusion of the eutectics were calculated from thermodynamic considerations and good agreement was obtained between the measured and calculated values. Several combinations of salts with high heats of fusion per unit mass (greater than 0.7 kJ/g) have been identified for possible use as phase change materials in advanced solar dynamic space power applications.

  11. Economic feasibility of thermal energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Habeebullah, B.A. [Faculty of Engineering, King Abdulaziz University, Jeddah (Saudi Arabia)

    2007-07-01

    This paper investigates the economic feasibility of both building an ice thermal storage and structure a time of rate tariff for the unique air conditioning (A/C) plant of the Grand Holy Mosque of Makkah, Saudi Arabia. The features of the building are unique where the air-conditioned 39,300 m{sup 2} zone is open to the atmosphere and the worshippers fully occupy the building five times a day, in addition hundreds of thousands of worshippers attend the blessed weekend's prayer at noontime, which escalates the peak electricity load. For economic analysis, the objective function is the daily electricity bill that includes the operation cost and the capital investment of the ice storage system. The operation cost is function of the energy imported for operating the plant in which the tariff structure, number of operating hours and the ambient temperature are parameters. The capital recovery factor is calculated for 10% interest rate and payback period of 10 years. Full and partial load storage scenarios are considered. The results showed that with the current fixed electricity rate (0.07 $/kWh), there is no gain in introducing ice storage systems for both storage schemes. Combining energy storage and an incentive time structured rate showed reasonable daily bill savings. For base tariff of 0.07 $/kWh during daytime operation and 0.016 $/kWh for off-peak period, savings were achieved for full load storage scenario. Different tariff structure is discussed and the break-even nighttime rate was determined (varies between 0.008 and 0.03 $/kWh). Partial load storage scenario showed to be unattractive where the savings for the base structured tariff was insignificant. (author)

  12. Buffer thermal energy storage for an air Brayton solar engine

    Science.gov (United States)

    Strumpf, H. J.; Barr, K. P.

    1981-01-01

    The application of latent-heat buffer thermal energy storage to a point-focusing solar receiver equipped with an air Brayton engine was studied. To demonstrate the effect of buffer thermal energy storage on engine operation, a computer program was written which models the recuperator, receiver, and thermal storage device as finite-element thermal masses. Actual operating or predicted performance data are used for all components, including the rotating equipment. Based on insolation input and a specified control scheme, the program predicts the Brayton engine operation, including flows, temperatures, and pressures for the various components, along with the engine output power. An economic parametric study indicates that the economic viability of buffer thermal energy storage is largely a function of the achievable engine life.

  13. Metal hydrides for concentrating solar thermal power energy storage

    Science.gov (United States)

    Sheppard, D. A.; Paskevicius, M.; Humphries, T. D.; Felderhoff, M.; Capurso, G.; Bellosta von Colbe, J.; Dornheim, M.; Klassen, T.; Ward, P. A.; Teprovich, J. A.; Corgnale, C.; Zidan, R.; Grant, D. M.; Buckley, C. E.

    2016-04-01

    The development of alternative methods for thermal energy storage is important for improving the efficiency and decreasing the cost of concentrating solar thermal power. We focus on the underlying technology that allows metal hydrides to function as thermal energy storage (TES) systems and highlight the current state-of-the-art materials that can operate at temperatures as low as room temperature and as high as 1100 °C. The potential of metal hydrides for thermal storage is explored, while current knowledge gaps about hydride properties, such as hydride thermodynamics, intrinsic kinetics and cyclic stability, are identified. The engineering challenges associated with utilising metal hydrides for high-temperature TES are also addressed.

  14. Thermal performance and heat transport in aquifer thermal energy storage

    NARCIS (Netherlands)

    Sommer, W.T.; Doornenbal, P.J.; Drijver, B.C.; Gaans, van P.F.M.; Leusbrock, I.; Grotenhuis, J.T.C.; Rijnaarts, H.H.M.

    2014-01-01

    Aquifer thermal energy storage (ATES) is used for seasonal storage of large quantities of thermal energy. Due to the increasing demand for sustainable energy, the number of ATES systems has increased rapidly, which has raised questions on the effect of ATES systems on their surroundings as well as

  15. Enhanced thermal conductivity of waste sawdust-based composite phase change materials with expanded graphite for thermal energy storage

    National Research Council Canada - National Science Library

    Yang, Haiyue; Wang, Yazhou; Liu, Zhuangchao; Liang, Daxin; Liu, Feng; Zhang, Wenbo; Di, Xin; Wang, Chengyu; Ho, Shih-Hsin; Chen, Wei-Hsin

    2017-01-01

    .... In particular, the application of phase change materials (PCMs) is considered as an effective and efficient approach to thermal energy storage because of the high latent heat storage capacity at small temperature intervals...

  16. Heat transfer and thermal storage in fixed and fluidized beds of phase change materials

    OpenAIRE

    Izquierdo Barrientos, Maria Asunción

    2016-01-01

    Mención Internacional en el título de doctor Thermal energy storage is a key technology for energy conservation since many energy sources are intermittent in nature. Latent heat storage is considered one of the most efficient ways of storing thermal energy because, unlike sensible heat storage, it provides a high-energy storage density with a small temperature swing. There are available many storage techniques, including sensible and latent heat storage or a combination of b...

  17. Local Thermal Insulating Materials For Thermal Energy Storage

    African Journals Online (AJOL)

    Unknown User

    1. Introduction. It is necessary to use thermal insulating materials around thermal energy storage systems to minimize heat losses from the systems [1]. There are varieties of insulating materials which come in various forms like loose fill, rigid boards, pipe and foam. The thermal insulation is provided by embedding insulation ...

  18. Commercialization of aquifer thermal energy storage technology

    Energy Technology Data Exchange (ETDEWEB)

    Hattrup, M.P.; Weijo, R.O.

    1989-09-01

    Pacific Northwest Laboratory (PNL) conducted this study for the US Department of Energy's (DOE) Office of Energy Storage and Distribution. The purpose of the study was to develop and screen a list of potential entry market applications for aquifer thermal energy storage (ATES). Several initial screening criteria were used to identify promising ATES applications. These include the existence of an energy availability/usage mismatch, the existence of many similar applications or commercial sites, the ability to utilize proven technology, the type of location, market characteristics, the size of and access to capital investment, and the number of decision makers involved. The in-depth analysis identified several additional screening criteria to consider in the selection of an entry market application. This analysis revealed that the best initial applications for ATES are those where reliability is acceptable, and relatively high temperatures are allowable. Although chill storage was the primary focus of this study, applications that are good candidates for heat ATES were also of special interest. 11 refs., 3 tabs.

  19. Thermal Storage Properties of Molten Nitrate Salt-Based Nanofluids with Graphene Nanoplatelets

    National Research Council Canada - National Science Library

    Xie, Qiangzhi; Zhu, Qunzhi; Li, Yan

    2016-01-01

    .... For both solar salt and resultant nanofluids, differential scanning calorimetry was employed to measure the thermal storage properties, including characteristic temperatures of phase change, startup...

  20. Lightweight Thermal Storage Heat Exchangers Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This SBIR proposal aims to develop thermal energy storage heat exchangers that are significantly lighter and higher conductance than the present art which involves...

  1. Optimization of the level and range of working temperature of the PCM in the gypsum-microencapsulated PCM thermal energy storage unit for summer conditions in Central Poland

    Science.gov (United States)

    Łapka, P.; Jaworski, M.

    2017-10-01

    In this paper thermal energy storage (TES) unit in a form of a ceiling panel made of gypsum-microencapsulated PCM composite with internal U-shaped channels was considered and optimal characteristics of the microencapsulated PCM were determined. This panel may be easily incorporated into, e.g., an office or residential ventilation system in order to reduce daily variations of air temperature during the summer without additional costs related to the consumption of energy for preparing air parameters to the desired level. For the purpose of the analysis of heat transfer in the panel, a novel numerical simulator was developed. The numerical model consists of two coupled parts, i.e., the 1D which deals with the air flowing through the U-shaped channel and the 3D which deals with heat transfer in the body of the panel. The computational tool was validated based on the experimental study performed on the special set-up. Using this tool an optimization of parameters of the gypsum-microencapsulated PCM composite was performed in order to determine its most appropriate properties for the application under study. The analyses were performed for averaged local summer conditions in Warsaw, Poland.

  2. A Comprehensive Review of Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Ioan Sarbu

    2018-01-01

    Full Text Available Thermal energy storage (TES is a technology that stocks thermal energy by heating or cooling a storage medium so that the stored energy can be used at a later time for heating and cooling applications and power generation. TES systems are used particularly in buildings and in industrial processes. This paper is focused on TES technologies that provide a way of valorizing solar heat and reducing the energy demand of buildings. The principles of several energy storage methods and calculation of storage capacities are described. Sensible heat storage technologies, including water tank, underground, and packed-bed storage methods, are briefly reviewed. Additionally, latent-heat storage systems associated with phase-change materials for use in solar heating/cooling of buildings, solar water heating, heat-pump systems, and concentrating solar power plants as well as thermo-chemical storage are discussed. Finally, cool thermal energy storage is also briefly reviewed and outstanding information on the performance and costs of TES systems are included.

  3. FFTF vertical sodium storage tank preliminary thermal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Irwin, J.J.

    1995-02-21

    In the FFTF Shutdown Program, sodium from the primary and secondary heat transport loops, Interim Decay Storage (IDS), and Fuel Storage Facility (FSF) will be transferred to four large storage tanks for temporary storage. Three of the storage tanks will be cylindrical vertical tanks having a diameter of 28 feet, height of 22 feet and fabricated from carbon steel. The fourth tank is a horizontal cylindrical tank but is not the subject of this report. The storage tanks will be located near the FFTF in the 400 Area and rest on a steel-lined concrete slab in an enclosed building. The purpose of this work is to document the thermal analyses that were performed to ensure that the vertical FFTF sodium storage tank design is feasible from a thermal standpoint. The key criterion for this analysis is the time to heat up the storage tank containing frozen sodium at ambient temperature to 400 F. Normal operating conditions include an ambient temperature range of 32 F to 120 F. A key parameter in the evaluation of the sodium storage tank is the type of insulation. The baseline case assumed six inches of calcium silicate insulation. An alternate case assumed refractory fiber (Cerablanket) insulation also with a thickness of six inches. Both cases assumed a total electrical trace heat load of 60 kW, with 24 kW evenly distributed on the bottom head and 36 kW evenly distributed on the tank side wall.

  4. The impact of low-temperature seasonal aquifer thermal energy storage (SATES) systems on chlorinated solvent contaminated groundwater: Modeling of spreading and degradation

    Science.gov (United States)

    Zuurbier, Koen G.; Hartog, Niels; Valstar, Johan; Post, Vincent E. A.; van Breukelen, Boris M.

    2013-04-01

    Groundwater systems are increasingly used for seasonal aquifer thermal energy storage (SATES) for periodic heating and cooling of buildings. Its use is hampered in contaminated aquifers because of the potential environmental risks associated with the spreading of contaminated groundwater, but positive side effects, such as enhanced contaminant remediation, might also occur. A first reactive transport study is presented to assess the effect of SATES on the fate of chlorinated solvents by means of scenario modeling, with emphasis on the effects of transient SATES pumping and applicable kinetic degradation regime. Temperature effects on physical, chemical, and biological reactions were excluded as calculations and initial simulations showed that the small temperature range commonly involved (ΔT < 15 °C) only caused minor effects. The results show that a significant decrease of the contaminant mass and (eventually) plume volume occurs when degradation is described as sediment-limited with a constant rate in space and time, provided that dense non-aqueous phase liquid (DNAPL) is absent. However, in the presence of DNAPL dissolution, particularly when the dissolved contaminant reaches SATES wells, a considerably larger contaminant plume is created, depending on the balance between DNAPL dissolution and mass removal by degradation. Under conditions where degradation is contaminant-limited and degradation rates depend on contaminant concentrations in the aquifer, a SATES system does not result in enhanced remediation of a contaminant plume. Although field data are lacking and existing regulatory constraints do not yet permit the application of SATES in contaminated aquifers, reactive transport modeling provides a means of assessing the risks of SATES application in contaminated aquifers. The results from this study are considered to be a first step in identifying the subsurface conditions under which SATES can be applied in a safe or even beneficial manner.

  5. Experimental investigation into a packed bed thermal storage solution for solar gas turbine systems

    CSIR Research Space (South Africa)

    Klein, P

    2013-09-01

    Full Text Available High temperature thermal storage in randomly packed beds of ceramic particles is proposed as an effective storage solution for Solar Gas Turbine (SGT) cycles in the near term. Numerical modelling of these systems allows for optimised thermal storage...

  6. Vacuum evacuated thermal storage in Sengenthal

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, B.; Hofbeck, K. [Georg-Simon-Ohm Hochschule Nuernberg (Germany). Fakultaet Allgemeinwissenschaften; Faulstich, M. [Technische Univ. Muenchen (Germany). Lehrstuhl fuer Rohstoff- und Energietechnologie

    2010-07-01

    This paper describes a vacuum insulated and stratified thermal hot water storage which will be built in Sengenthal in March 2011. The thermal storage is loaded with different types of renewable energy sources, especially firewood and solar thermal energy. With the high efficient tank it is possible to reduce the carbon dioxide emission by 90% and reduce the thermal losses of the storage by 80%. Within the project in Sengenthal the vacuum evacuated storage saves expectedly about 7.500 Euro fuel costs each year without regarding the advance in prices. This fact is caused by the substitution of a gas boiler by using the described tank as a buffer tank within a local heating plant which is covered by a firewood boiler. The concrete problem of the local heating plant was the fact that the power of the firewood boiler is too low to cover the demand of a new building. Without the described thermal storage with vacuum insulation there would be a need of an additional gas boiler. (orig.)

  7. Novel Thermal Storage Technologies for Concentrating Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Neti, Sudhakar [Lehigh Univ., Bethlehem, PA (United States). Mechanical Engineering and Mechanics; Oztekin, Alparslan [Lehigh Univ., Bethlehem, PA (United States); Chen, John [Lehigh Univ., Bethlehem, PA (United States); Tuzla, Kemal [Lehigh Univ., Bethlehem, PA (United States); Misiolek, Wojciech [Lehigh Univ., Bethlehem, PA (United States)

    2013-06-20

    The technologies that are to be developed in this work will enable storage of thermal energy in 100 MWe solar energy plants for 6-24 hours at temperatures around 300°C and 850°C using encapsulated phase change materials (EPCM). Several encapsulated phase change materials have been identified, fabricated and proven with calorimetry. Two of these materials have been tested in an airflow experiment. A cost analysis for these thermal energy storage systems has also been conducted that met the targets established at the initiation of the project.

  8. Metal hydride-based thermal energy storage systems

    Science.gov (United States)

    Vajo, John J.; Fang, Zhigang

    2017-10-03

    The invention provides a thermal energy storage system comprising a metal-containing first material with a thermal energy storage density of about 1300 kJ/kg to about 2200 kJ/kg based on hydrogenation; a metal-containing second material with a thermal energy storage density of about 200 kJ/kg to about 1000 kJ/kg based on hydrogenation; and a hydrogen conduit for reversibly transporting hydrogen between the first material and the second material. At a temperature of 20.degree. C. and in 1 hour, at least 90% of the metal is converted to the hydride. At a temperature of 0.degree. C. and in 1 hour, at least 90% of the metal hydride is converted to the metal and hydrogen. The disclosed metal hydride materials have a combination of thermodynamic energy storage densities and kinetic power capabilities that previously have not been demonstrated. This performance enables practical use of thermal energy storage systems for electric vehicle heating and cooling.

  9. Aquifer thermal energy (heat and chill) storage

    Energy Technology Data Exchange (ETDEWEB)

    Jenne, E.A. (ed.)

    1992-11-01

    As part of the 1992 Intersociety Conversion Engineering Conference, held in San Diego, California, August 3--7, 1992, the Seasonal Thermal Energy Storage Program coordinated five sessions dealing specifically with aquifer thermal energy storage technologies (ATES). Researchers from Sweden, The Netherlands, Germany, Switzerland, Denmark, Canada, and the United States presented papers on a variety of ATES related topics. With special permission from the Society of Automotive Engineers, host society for the 1992 IECEC, these papers are being republished here as a standalone summary of ATES technology status. Individual papers are indexed separately.

  10. Solar applications of thermal energy storage. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Lee, C.; Taylor, L.; DeVries, J.; Heibein, S.

    1979-01-01

    A technology assessment is presented on solar energy systems which use thermal energy storage. The study includes characterization of the current state-of-the-art of thermal energy storage, an assessment of the energy storage needs of solar energy systems, and the synthesis of this information into preliminary design criteria which would form the basis for detailed designs of thermal energy storage. (MHR)

  11. The Development of an INL Capability for High Temperature Flow, Heat Transfer, and Thermal Energy Storage with Applications in Advanced Small Modular Reactors, High Temperature Heat Exchangers, Hybrid Energy Systems, and Dynamic Grid Energy Storage C

    Energy Technology Data Exchange (ETDEWEB)

    Sun, Xiaodong [The Ohio State Univ., Columbus, OH (United States); Zhang, Xiaoqin [The Ohio State Univ., Columbus, OH (United States); Kim, Inhun [The Ohio State Univ., Columbus, OH (United States); O' Brien, James [Idaho National Lab. (INL), Idaho Falls, ID (United States); Sabharwall, Piyush [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-10-01

    The overall goal of this project is to support Idaho National Laboratory in developing a new advanced high temperature multi fluid multi loop test facility that is aimed at investigating fluid flow and heat transfer, material corrosion, heat exchanger characteristics and instrumentation performance, among others, for nuclear applications. Specifically, preliminary research has been performed at The Ohio State University in the following areas: 1. A review of fluoride molten salts’ characteristics in thermal, corrosive, and compatibility performances. A recommendation for a salt selection is provided. Material candidates for both molten salt and helium flow loop have been identified. 2. A conceptual facility design that satisfies the multi loop (two coolant loops [i.e., fluoride molten salts and helium]) multi purpose (two operation modes [i.e., forced and natural circulation]) requirements. Schematic models are presented. The thermal hydraulic performances in a preliminary printed circuit heat exchanger (PCHE) design have been estimated. 3. An introduction of computational methods and models for pipe heat loss analysis and cases studies. Recommendations on insulation material selection have been provided. 4. An analysis of pipe pressure rating and sizing. Preliminary recommendations on pipe size selection have been provided. 5. A review of molten fluoride salt preparation and chemistry control. An introduction to the experience from the Molten Salt Reactor Experiment at Oak Ridge National Laboratory has been provided. 6. A review of some instruments and components to be used in the facility. Flowmeters and Grayloc connectors have been included. This report primarily presents the conclusions drawn from the extensive review of literatures in material selections and the facility design progress at the current stage. It provides some useful guidelines in insulation material and pipe size selection, as well as an introductory review of facility process and components.

  12. High Density Thermal Energy Storage with Supercritical Fluids

    Science.gov (United States)

    Ganapathi, Gani B.; Wirz, Richard

    2012-01-01

    A novel approach to storing thermal energy with supercritical fluids is being investigated, which if successful, promises to transform the way thermal energy is captured and utilized. The use of supercritical fluids allows cost-affordable high-density storage with a combination of latent heat and sensible heat in the two-phase as well as the supercritical state. This technology will enhance penetration of several thermal power generation applications and high temperature water for commercial use if the overall cost of the technology can be demonstrated to be lower than the current state-of-the-art molten salt using sodium nitrate and potassium nitrate eutectic mixtures.

  13. FFTF horizontal sodium storage tank preliminary thermal analysis

    Energy Technology Data Exchange (ETDEWEB)

    Irwin, J.J.

    1995-02-21

    In the FFTF Shutdown Program, sodium from the primary and secondary heat transport loops, Interim Decay Storage (IDS), and Fuel Storage Facility (FSF) will be transferred to four large storage tanks for temporary storage. Three of the drain tanks will be cylindrical vertical tanks having a diameter of 28 feet, height of 22 feet and fabricated from carbon steel. The vertical tanks were the subject of a previous report and are not the subject of this report. The fourth tank is a horizontal cylindrical tank 18 feet in diameter, having an overall length of 31 feet and fabricated from carbon steel. The purpose of this work is to document the thermal analyses that were performed to ensure that the FFTF horizontal sodium storage tank design is feasible from a thermal standpoint. The key criterion for this analysis is the time to heat up the storage tank containing frozen sodium at ambient temperature to 400 F. Normal operating conditions include an ambient temperature range of 32 F to 120 F. A key parameter in the evaluation of the sodium drain tank is the type of insulation. The baseline case assumed four inches of calcium silicate insulation. An alternate case assumed refractory fiber (Cerablanket) insulation also with a thickness of four inches. Both cases assumed a total electrical trace heat load of 60 kW, evenly distributed on the tank heads and on the tank side wall (cylinder).

  14. Growth and inactivation of Salmonella at low refrigerated storage temperatures and thermal inactivation on raw chicken meat and laboratory media: mixed effect meta-analysis.

    Science.gov (United States)

    Smadi, Hanan; Sargeant, Jan M; Shannon, Harry S; Raina, Parminder

    2012-12-01

    Growth and inactivation regression equations were developed to describe the effects of temperature on Salmonella concentration on chicken meat for refrigerated temperatures (⩽10°C) and for thermal treatment temperatures (55-70°C). The main objectives were: (i) to compare Salmonella growth/inactivation in chicken meat versus laboratory media; (ii) to create regression equations to estimate Salmonella growth in chicken meat that can be used in quantitative risk assessment (QRA) modeling; and (iii) to create regression equations to estimate D-values needed to inactivate Salmonella in chicken meat. A systematic approach was used to identify the articles, critically appraise them, and pool outcomes across studies. Growth represented in density (Log10CFU/g) and D-values (min) as a function of temperature were modeled using hierarchical mixed effects regression models. The current meta-analysis analysis found a significant difference (P⩽0.05) between the two matrices - chicken meat and laboratory media - for both growth at refrigerated temperatures and inactivation by thermal treatment. Growth and inactivation were significantly influenced by temperature after controlling for other variables; however, no consistent pattern in growth was found. Validation of growth and inactivation equations against data not used in their development is needed. Copyright © 2012 Ministry of Health, Saudi Arabia. Published by Elsevier Ltd. All rights reserved.

  15. TEMPERATURE DEPENDENCE OF THE THERMAL ...

    African Journals Online (AJOL)

    Thermal conductivity values, in the temperature range 300 – 1200 K, have been measured in air and at atmospheric pressure for a Kenyan kaolinite refractory with 0% - 50% grog proportions. The experimental thermal conductivity values were then compared with those calculated using the Zumbrunnen et al [1] and the ...

  16. Eutectic mixtures of some fatty acids for latent heat storage: Thermal properties and thermal reliability with respect to thermal cycling

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ahmet [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey)]. E-mail: asari@gop.edu.tr

    2006-06-15

    Accelerated thermal cycle tests have been conducted to study the change in melting temperatures and latent heats of fusion of the eutectic mixtures of lauric acid (LA)-myristic acid (MA), lauric acid (LA)-palmitic acid (PA) and myristic acid (MA)-stearic acid (SA) as latent heat storage materials. The thermal properties of these materials were determined by the differential scanning calorimetry (DSC) analysis method. The thermal reliability of the eutectic mixtures after melt/freeze cycles of 720, 1080 and 1460 was also evaluated using the DSC curves. The accelerated thermal cycle tests indicate that the melting temperatures usually tend to decrease, and the variations in the latent heats of fusion are irregular with increasing number of thermal cycles. Moreover, the probable reasons for the change in thermal properties of the eutectic mixtures after repeated thermal cycles were investigated. Fourier Transform Infrared (FT-IR) spectroscopic analysis indicates that the accelerated melt/freeze processes do not cause any degradation in the chemical structure of the mixtures. The change in thermal properties of the eutectic mixtures with increasing number of thermal cycles is only because of the presence of certain amounts of impurities in the fatty acids used in their preparation. It is concluded that the tested eutectic mixtures have reasonable thermal properties and thermal reliability as phase change materials (PCMs) for latent heat storage in any solar heating applications that include a four year utilization period.

  17. Experimental study of influence of inlet geometry on thermal stratification in thermal energy storage during charging process

    Directory of Open Access Journals (Sweden)

    Švarc Petr

    2014-03-01

    Full Text Available Various analyses of charging processes of real single-medium thermal energy storage were applied in this work. Two different inlet geometries of direct intakes into thermal energy storage were investigated for the process of charging in Richardson numbers 0.4 and 15. Temperature distributions for both cases are shown and compared in selected time steps. Several simple methods for assessment of an ability to maintain and support thermal stratification during charging processes were compared with exergy analysis.

  18. Spent fuel dry storage technology development: thermal evaluation of sealed storage cask containing spent fuel

    Energy Technology Data Exchange (ETDEWEB)

    Schmitten, P.F.; Wright, J.B.

    1980-08-01

    A PWR spent fuel assembly was encapsulated inside the E-MAD Hot Bay and placed in a instrumented above surface storage cell during December 1978 for thermal testing. Instrumentation provided to measure canister, liner and concrete temperatures consisted of thermocouples which were inserted into tubes on the outside of the canister and liner and in three radial positions in the concrete. Temperatures from the SSC test assembly have been recorded throughout the past 16 months. Canister and liner temperatures have reached their peak values of 200{sup 0}F and 140{sup 0}F, respectively. Computer predictions of the transient and steady-state temperatures show good agreement with the test data.

  19. Graphene Thermal Properties: Applications in Thermal Management and Energy Storage

    Directory of Open Access Journals (Sweden)

    Jackie D. Renteria

    2014-11-01

    Full Text Available We review the thermal properties of graphene, few-layer graphene and graphene nanoribbons, and discuss practical applications of graphene in thermal management and energy storage. The first part of the review describes the state-of-the-art in the graphene thermal field focusing on recently reported experimental and theoretical data for heat conduction in graphene and graphene nanoribbons. The effects of the sample size, shape, quality, strain distribution, isotope composition, and point-defect concentration are included in the summary. The second part of the review outlines thermal properties of graphene-enhanced phase change materials used in energy storage. It is shown that the use of liquid-phase-exfoliated graphene as filler material in phase change materials is promising for thermal management of high-power-density battery parks. The reported experimental and modeling results indicate that graphene has the potential to outperform metal nanoparticles, carbon nanotubes, and other carbon allotropes as filler in thermal management materials.

  20. Characterization of Encapsulated Phase Change Materials for Thermal Energy Storage

    Science.gov (United States)

    Zhao, Weihuan

    Solar energy is receiving a lot of attentions at present since it is a kind of clean, renewable and sustainable energy. A major limitation however is that it is available for only about 2,000 hours a year in many places. One way to improve this situation is to use thermal energy storage (TES) system for the off hours. A novel method to store solar energy for large scale energy usage is using high melting temperature encapsulated phase change materials (EPCMs). The present work is a study of thermal energy storage systems with phase change materials (PCMs). It is hoped that this work is to help understand the storage capability and heat transfer processes in the EPCM capsules in order to help design large EPCM based thermoclines. A calorimeter system was built to test the energy stored in EPCM capsules and examine the storage capabilities and potential for storage deterioration in EPCM capsules to determine the types of EPCMs suitable for TES. To accomplish this, the heat transfer performances of the EPCMs are studied in detail. Factors which could affect the heat transfer performance including the properties of materials, the sizes of capsules, the types of heat transfer fluids, the gravity effect of solid PCM, the buoyancy-driven convection in the molten PCM, void space inside the capsule are given attention. Understanding these characteristics for heat transfer process could help build the EPCM based thermoclines to make energy storage economical for solar energy and other applications.

  1. Concentrated Solar Power Gas Turbine Hybrid with Thermal Storage

    OpenAIRE

    Wallentinsen, Bård Sve

    2016-01-01

    Concentrated Solar Power (CSP) technology and shows promise for large-scale renewable electric power generation. CSP is suitable for development in conjunction with other technologies, and this thesis examines the combination of CSP technology with natural gas turbines in order to boost operating temperatures and efficiencies in a resulting solar hybrid gas turbine (SHGT) power plant. Thermal energy storage and a bottoming cycle are included in the design to increase both performance and rene...

  2. Survey of solar thermal energy storage subsystems for thermal/electric applications

    Energy Technology Data Exchange (ETDEWEB)

    Segaser, C. L.

    1978-08-01

    A survey of the current technology and estimated costs of subsystems for storing the thermal energy produced by solar collectors is presented. The systems considered were capable of producing both electricity and space conditioning for three types of loads: a single-family detached residence, an apartment complex of 100 units, and a city of 30,000 residents, containing both single-family residences and apartments. Collector temperatures will be in four ranges: (1) 100 to 250/sup 0/F (used for space heating and single-cycle air conditioners and organic Rankine low-temperature turbines); (2) 300 to 400/sup 0/F (used for dual-cycle air conditioners and low-temperature turbines); (3) 400 to 600/sup 0/F (using fluids from parabolic trough collectors to run Rankine turbines); (4) 800 to 1000/sup 0/F (using fluids from heliostats to run closed-cycle gas turbines and steam Rankine turbines). The solar thermal energy subsystems will require from 60 to 36 x 10/sup 5/ kWhr (2.05 x 10/sup 5/ to 1.23 x 10/sup 10/ Btu) of thermal storage capacity. In addition to sensible heat and latent heat storage materials, several other media were investigated as potential thermal energy storage materials, including the clathrate and semiclathrate hydrates, various metal hydrides, and heat storage based on inorganic chemical reactions.

  3. Advanced phase change composite by thermally annealed defect-free graphene for thermal energy storage.

    Science.gov (United States)

    Xin, Guoqing; Sun, Hongtao; Scott, Spencer Michael; Yao, Tiankai; Lu, Fengyuan; Shao, Dali; Hu, Tao; Wang, Gongkai; Ran, Guang; Lian, Jie

    2014-09-10

    Organic phase change materials (PCMs) have been utilized as latent heat energy storage and release media for effective thermal management. A major challenge exists for organic PCMs in which their low thermal conductivity leads to a slow transient temperature response and reduced heat transfer efficiency. In this work, 2D thermally annealed defect-free graphene sheets (GSs) can be obtained upon high temperature annealing in removing defects and oxygen functional groups. As a result of greatly reduced phonon scattering centers for thermal transport, the incorporation of ultralight weight and defect free graphene applied as nanoscale additives into a phase change composite (PCC) drastically improve thermal conductivity and meanwhile minimize the reduction of heat of fusion. A high thermal conductivity of the defect-free graphene-PCC can be achieved up to 3.55 W/(m K) at a 10 wt % graphene loading. This represents an enhancement of over 600% as compared to pristine graphene-PCC without annealing at a comparable loading, and a 16-fold enhancement than the pure PCM (1-octadecanol). The defect-free graphene-PCC displays rapid temperature response and superior heat transfer capability as compared to the pristine graphene-PCC or pure PCM, enabling transformational thermal energy storage and management.

  4. Preparation, thermal properties and thermal reliability of microencapsulated n-eicosane as novel phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Alkan, Cemil; Sari, Ahmet; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey)

    2011-01-15

    This study deals with preparation, characterization, thermal properties and thermal reliability of n-eicosane microcapsules as novel phase change material (PCM) for thermal energy storage. The microcapsulated PCMs were prepared by coating n-eicosane with polymethylmethacrylate (PMMA) shell. Fourier transform infrared (FT-IR), scanning electron microscope (SEM) and particle size distribution (PSD) analysis were used to characterize the PMMA/eicosane microcapsules as microcapsulated PCMs. The PSD analysis indicated that the average diameter of microcapsules was found to be 0.70 {mu}m under the stirring speed of 2000 rpm. Thermal properties and thermal reliability of the microcapsules were determined using differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA) methods. From DSC analysis, the melting and freezing temperatures and the latent heats of the microcapsules were measured as 35.2 C and 34.9 C, 84.2 and -87.5 J/g, respectively. TGA analysis indicated that PMMA/eicosane microcapsules degrade in three steps at considerably high temperatures. Accelerated thermal cycling tests have been also applied to show the thermal reliability of the microcapsules. All results showed that thermal properties make the PMMA/eicosane microcapsules potential PCM for thermal energy storage. (author)

  5. Thermal performance sensitivity studies in support of material modeling for extended storage of used nuclear fuel

    Energy Technology Data Exchange (ETDEWEB)

    Cuta, Judith M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Suffield, Sarah R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fort, James A. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Adkins, Harold E. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2013-08-15

    The work reported here is an investigation of the sensitivity of component temperatures of a storage system, including fuel cladding temperatures, in response to age-related changes that could degrade the design-basis thermal behavior of the system. The purpose of these sensitivity studies is to provide a realistic example of how changes in the physical properties or configuration of the storage system components can affect temperatures and temperature distributions. The magnitudes of these sensitivities can provide guidance for identifying appropriate modeling assumptions for thermal evaluations extending long term storage out beyond 50, 100, 200, and 300 years.

  6. Study on Tetradecane Nanoemulsion for Thermal Energy Transportation and Storage

    Science.gov (United States)

    Fumoto, Koji; Kawaji, Masahiro; Kawanami, Tsuyoshi

    Phase change emulsion (PCE) is a novel fluid used for heat storage and transfer. It has the following characteristics: higher apparent specific heat and higher heat transfer ability in the phase-change temperature range as compared to the conventional single-phase heat transfer fluids. In particular, oil-in-water (O/W) emulsions are latent heat storage materials that have low melting points, thus offering attractive opportunities for heat transfer enhancement and thermal energy transportation and storage. In this paper, milky white oil-in-water emulsions have been formed using water, Tween 80, Span 80, and tetradecane by low-energy emulsification methods (e.g., the phase inversion temperature (PIT) method). The relations between the component ratios of the emulsions and both the particle diameters and the stability of the resulting emulsions have been determined by dynamic light scattering (DLS) and vibration viscometry. The results show that the apparent viscosity of the nanoemulsion is lower than that of an emulsion, which was prepared with the same mixing ratio of surfactant and concentration of phase change material. Moreover, the surfactant concentration is found to contribute to the stability of the phase change nanoemulsion. Results indicate that the phase change nanoemulsion is a promising material for thermal storage applications.

  7. Evaluation of thermal energy storage materials for advanced compressed air energy storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Zaloudek, F.R.; Wheeler, K.R.; Marksberry, L.

    1983-03-01

    Advanced Compressed-Air Energy Storage (ACAS) plants have the near-term potential to reduce the fuel consumption of compressed-air plants from 33 to 100%, depending upon their design. Fuel is saved by storing some or all of the heat of compression as sensible heat which is subsequently used to reheat the compressed air prior to expansion in the turbine generator. The thermal storage media required for this application must be low cost and durable. The objective of this project was to screen thermal store materials based on their thermal cycle durability, particulate formation and corrosion resistant characteristics. The materials investigated were iron oxide pellets, Denstone pebbles, cast-iron balls, and Dresser basalt rock. The study specifically addressed the problems of particle formation and thermal ratcheting of the materials during thermal cycling and the chemical attack on the materials by the high temperature and moist environment in an ACAS heat storage bed. The results indicate that from the durability standpoint Denstone, cast iron containing 27% or more chromium, and crushed Dresser basalt would possibly stand up to ACAS conditions. If costs are considered in addition to durability and performance, the crushed Dresser basalt would probably be the most desirable heat storage material for adiabatic and hybrid ACAS plants, and more in-depth longer term thermal cycling and materials testing of Dresser basalt is recommended. Also recommended is the redesign and costing analysis of both the hybrid and adiabatic ACAS facilities based upon the use of Dresser basalt as the thermal store material.

  8. Thermal Impact of Medium Deep Borehole Thermal Energy Storage on the Shallow Subsurface

    Science.gov (United States)

    Welsch, Bastian; Schulte, Daniel O.; Rühaak, Wolfram; Bär, Kristian; Sass, Ingo

    2017-04-01

    Borehole heat exchanger arrays are a well-suited and already widely applied method for exploiting the shallow subsurface as seasonal heat storage. However, in most of the populated regions the shallow subsurface also comprises an important aquifer system used for drinking water production. Thus, the operation of shallow geothermal heat storage systems leads to a significant increase in groundwater temperatures in the proximity of the borehole heat exchanger array. The magnitude of the impact on groundwater quality and microbiology associated with this temperature rise is controversially discussed. Nevertheless, the protection of shallow groundwater resources has priority. Accordingly, water authorities often follow restrictive permission policies for building such storage systems. An alternative approach to avoid this issue is the application of medium deep borehole heat exchanger arrays instead of shallow ones. The thermal impact on shallow aquifers can be significantly reduced as heat is stored at larger depth. Moreover, it can be further diminished by the installation of a thermally insulating materials in the upper section of the borehole heat exchangers. Based on a numerical simulation study, the advantageous effects of medium deep borehole thermal energy storage are demonstrated and quantified. A finite element software is used to model the heat transport in the subsurface in 3D, while the heat transport in the borehole heat exchangers is solved analytically in 1D. For this purpose, an extended analytical solution is implemented, which also allows for the consideration of a thermally insulating borehole section.

  9. Phase change thermal energy storage material

    Science.gov (United States)

    Benson, David K.; Burrows, Richard W.

    1987-01-01

    A thermal energy storge composition is disclosed. The composition comprises a non-chloride hydrate having a phase change transition temperature in the range of 70.degree.-95.degree. F. and a latent heat of transformation of at least about 35 calories/gram.

  10. Second law characterization of stratified thermal storage tanks

    Energy Technology Data Exchange (ETDEWEB)

    Fraidenraich, N [Departamento de Energia Nuclear-UFPE (Brazil)

    2000-07-01

    It is well known that fluid stratification in thermal storage tanks improves the overall performance of solar thermal systems, when compared with systems operating with uniform fluid temperature. From the point of view of the first law of thermodynamics, no difference exists between storage tanks with the same mass and average temperature, even if they have different stratified thermal structures. Nevertheless, the useful thermal energy that can be obtained from them might differ significantly. In this work, we derive an expression able to characterize the stratified configuration of thermal fluid. Using results obtained by thermodynamics of irreversible processes, the procedure adopted consists in calculating the maximum work available from the tank's thermal layer is able to develop. We arrive, then, at a dimensionless expression, the stratification parameter (SP), which depends on the mass fraction and absolute temperature of each thermal layer as well as the thermal fluid average temperature. Numerical examples for different types of tank stratification are given and it is verified that the expression obtained is sensitive to small differences in the reservoir thermal configuration. For example a thermal storage with temperatures equal to 74 Celsius degrees, 64 Celsius degrees and 54 Celsius degrees, with its mass equally distributed along the tank yields, for the parameter SP, a figure equal to 0.000294. On the other hand a storage tank with the same average temperature but with different layer's temperatures 76 Celsius degrees, 64 and 52 Celsius degrees, also with uniform mass distribution, yields for SP a value equal to quantitative evaluation of the stratification structure of thermal reservoirs. [Spanish] Es bien conocido que la estratificacion fluida en tanques de almacenamiento termico mejora el rendimiento total de los sistemas termicos solares en comparacion con sistemas que operan con temperatura uniforme del fluido. Desde el punto de vista

  11. Residential Solar-Based Seasonal Thermal Storage Systems in Cold Climates: Building Envelope and Thermal Storage

    OpenAIRE

    Alexandre Hugo; Radu Zmeureanu

    2012-01-01

    The reduction of electricity use for heating and domestic hot water in cold climates can be achieved by: (1) reducing the heating loads through the improvement of the thermal performance of house envelopes, and (2) using solar energy through a residential solar-based thermal storage system. First, this paper presents the life cycle energy and cost analysis of a typical one-storey detached house, located in Montreal, Canada. Simulation of annual energy use is performed using the TRNSYS softwar...

  12. Concrete thermal energy storage for steam generation: A numerical investigation

    DEFF Research Database (Denmark)

    Singh, Shobhana; Sørensen, Kim

    2017-01-01

    Establishing enhancement methods to develop cost-effective thermal energy storage technology requires a detailed analysis. In this paper, a numerical investigation of the concrete based thermal energy storage system is carried out. The storage system consists of a heat transfer fluid flowing insi...

  13. Temperature distribution and thermal stress

    Indian Academy of Sciences (India)

    The minimum stress and minimum stress difference are shown in equal double pumping. 4. Conclusion. In the present work, the temperature distribution and thermal stress of the actual double-end-pumped Nd:YVO4 cubic crystal have been discussed. The results show that by considering the input power as a constant, the ...

  14. Cyclic high temperature heat storage using borehole heat exchangers

    Science.gov (United States)

    Boockmeyer, Anke; Delfs, Jens-Olaf; Bauer, Sebastian

    2016-04-01

    The transition of the German energy supply towards mainly renewable energy sources like wind or solar power, termed "Energiewende", makes energy storage a requirement in order to compensate their fluctuating production and to ensure a reliable energy and power supply. One option is to store heat in the subsurface using borehole heat exchangers (BHEs). Efficiency of thermal storage is increasing with increasing temperatures, as heat at high temperatures is more easily injected and extracted than at temperatures at ambient levels. This work aims at quantifying achievable storage capacities, storage cycle times, injection and extraction rates as well as thermal and hydraulic effects induced in the subsurface for a BHE storage site in the shallow subsurface. To achieve these aims, simulation of these highly dynamic storage sites is performed. A detailed, high-resolution numerical simulation model was developed, that accounts for all BHE components in geometrical detail and incorporates the governing processes. This model was verified using high quality experimental data and is shown to achieve accurate simulation results with excellent fit to the available experimental data, but also leads to large computational times due to the large numerical meshes required for discretizing the highly transient effects. An approximate numerical model for each type of BHE (single U, double U and coaxial) that reduces the number of elements and the simulation time significantly was therefore developed for use in larger scale simulations. The approximate numerical model still includes all BHE components and represents the temporal and spatial temperature distribution with a deviation of less than 2% from the fully discretized model. Simulation times are reduced by a factor of ~10 for single U-tube BHEs, ~20 for double U-tube BHEs and ~150 for coaxial BHEs. This model is then used to investigate achievable storage capacity, injection and extraction rates as well as induced effects for

  15. Residential Solar-Based Seasonal Thermal Storage Systems in Cold Climates: Building Envelope and Thermal Storage

    Directory of Open Access Journals (Sweden)

    Alexandre Hugo

    2012-10-01

    Full Text Available The reduction of electricity use for heating and domestic hot water in cold climates can be achieved by: (1 reducing the heating loads through the improvement of the thermal performance of house envelopes, and (2 using solar energy through a residential solar-based thermal storage system. First, this paper presents the life cycle energy and cost analysis of a typical one-storey detached house, located in Montreal, Canada. Simulation of annual energy use is performed using the TRNSYS software. Second, several design alternatives with improved thermal resistance for walls, ceiling and windows, increased overall air tightness, and increased window-to-wall ratio of South facing windows are evaluated with respect to the life cycle energy use, life cycle emissions and life cycle cost. The solution that minimizes the energy demand is chosen as a reference house for the study of long-term thermal storage. Third, the computer simulation of a solar heating system with solar thermal collectors and long-term thermal storage capacity is presented. Finally, the life cycle cost and life cycle energy use of the solar combisystem are estimated for flat-plate solar collectors and evacuated tube solar collectors, respectively, for the economic and climatic conditions of this study.

  16. Lowering the cost of large-scale energy storage: High temperature adiabatic compressed air energy storage

    Directory of Open Access Journals (Sweden)

    B. Cárdenas

    2017-06-01

    Full Text Available Compressed air energy storage is an energy storage technology with strong potential to play a significant role in balancing energy on transmission networks, owing to its use of mature technologies and low cost per unit of storage capacity. Adiabatic compressed air energy storage (A-CAES systems typically compress air from ambient temperature in the charge phase and expand the air back to ambient temperature in the discharge phase. This papers explores the use of an innovative operating scheme for an A-CAES system aimed at lowering the total cost of the system for a given exergy storage capacity. The configuration proposed considers preheating of the air before compression which increases the fraction of the total exergy that is stored in the form of high-grade heat in comparison to existing designs in which the main exergy storage medium is the compressed air itself. Storing a high fraction of the total exergy as heat allows reducing the capacity of costly pressure stores in the system and replacing it with cheaper thermal energy stores. Additionally, a configuration that integrates a system based on the aforementioned concept with solar thermal power or low-medium grade waste heat is introduced and thoroughly discussed.

  17. Numerical model for the thermal behavior of thermocline storage tanks

    Science.gov (United States)

    Ehtiwesh, Ismael A. S.; Sousa, Antonio C. M.

    2017-10-01

    Energy storage is a critical factor in the advancement of solar thermal power systems for the sustained delivery of electricity. In addition, the incorporation of thermal energy storage into the operation of concentrated solar power systems (CSPs) offers the potential of delivering electricity without fossil-fuel backup even during peak demand, independent of weather conditions and daylight. Despite this potential, some areas of the design and performance of thermocline systems still require further attention for future incorporation in commercial CSPs, particularly, their operation and control. Therefore, the present study aims to develop a simple but efficient numerical model to allow the comprehensive analysis of thermocline storage systems aiming better understanding of their dynamic temperature response. The validation results, despite the simplifying assumptions of the numerical model, agree well with the experiments for the time evolution of the thermocline region. Three different cases are considered to test the versatility of the numerical model; for the particular type of a storage tank with top round impingement inlet, a simple analytical model was developed to take into consideration the increased turbulence level in the mixing region. The numerical predictions for the three cases are in general good agreement against the experimental results.

  18. Testing of High Thermal Cycling Stability of Low Strength Concrete as a Thermal Energy Storage Material

    Directory of Open Access Journals (Sweden)

    Chao Wu

    2016-09-01

    Full Text Available Concrete has the potential to become a solution for thermal energy storage (TES integrated in concentrating solar power (CSP systems due to its good thermal and mechanical properties and low cost of material. In this study, a low strength concrete (C20 is tested at high temperatures up to 600 °C. Specimens are thermally cycled at temperatures in the range of 400–300 °C, 500–300 °C, and 600–300 °C, which TES can reach in operation. For comparison, specimens also cycled at temperature in the range of 400–25 °C (room temperature, 500–25 °C, and 600–25 °C. It is found from the test results that cracks are not observed on the surfaces of concrete specimens until the temperature is elevated up to 500 °C. There is mechanical deterioration of concrete after exposure to high temperature, especially to high thermal cycles. The residual compressive strength of concrete after 10 thermal cycles between 600 °C and 300 °C is about 58.3%, but the specimens remain stable without spalling, indicating possible use of low strength concrete as a TES material.

  19. Molten salt thermal energy storage systems. Project 8981, final report

    Energy Technology Data Exchange (ETDEWEB)

    Maru, H.C.; Dullea, J.F.; Kardas, A.; Paul, L.

    1978-03-01

    The feasibility of storing thermal energy at temperatures of 450/sup 0/ to 535/sup 0/C (850/sup 0/ to 1000/sup 0/F) in the form of latent heat of fusion has been examined for over 30 inorganic salts and salt mixtures. Alkali carbonate mixtures are attractive as phase-change storage materials in this temperature range because of their relatively high storage capacity and thermal conductivity, moderate cost, low volumetric expansion upon melting, low corrosivity, and good chemical stability. An equimolar mixture of Li/sub 2/CO/sub 3/ and K/sub 2/CO/sub 3/, which melts at 505/sup 0/C with a latent heat of 148 Btu/lb, was chosen for experimental study. The cyclic charge/discharge behavior of laboratory- and engineering-scale systems was determined and compared with predictions based on a mathematical heat-transfer model that was developed during this program. The thermal performance of one engineering-scale unit remained very stable during 1400 hours of cyclic operation. Several means of improving heat conduction through the solid salt were explored. Areas requiring further investigation have been identified.

  20. Integrated assessment of variable density-viscosity groundwater flow for a high temperature mono-well aquifer thermal energy storage (HT-ATES) system in a geothermal reservoir

    NARCIS (Netherlands)

    Zeghici, Răzvan Mihai; Oude Essink, Gualbert H P; Hartog, Niels; Sommer, Wijbrand

    2015-01-01

    The use of groundwater systems for heat storage increasingly gains interest among water managers, policy makers and researchers as a way to increase the efficiency of energy production and to allow the re-use of waste heat. Typically, mono-well storage systems are thought to require the use of

  1. Integrated assessment of variable density-viscosity groundwater flow for a high temperature mono-well aquifer thermal energy storage (HT-ATES) system in a geothermal reservoir

    NARCIS (Netherlands)

    Zeghici, Răzvan Mihai; Oude Essink, Gualbert H.P.; Hartog, Niels; Sommer, Wijb

    2015-01-01

    The use of groundwater systems for heat storage increasingly gains interest among water managers, policy makers and researchers as a way to increase the efficiency of energy production and to allow the re-use of waste heat. Typically, mono-well storage systems are thought to require the use of

  2. Evaluation of thermal-storage concepts for solar cooling applications

    Science.gov (United States)

    Hughes, P. J.; Morehouse, J. H.; Choi, M. K.; White, N. M.; Scholten, W. B.

    1981-10-01

    Various configuration concepts for utilizing thermal energy storage to improve the thermal and economic performance of solar cooling systems for buildings were analyzed. The storge concepts evaluated provide short-term thermal storge via the bulk containment of water or salt hydrates. The evaluations were made for both residential-size cooling systems (3-ton) and small commercial-size cooling systems (25-ton). The residential analysis considers energy requirements for space heating, space cooling and water heating, while the commercial building analysis is based only on energy requirements for space cooling. The commercial building analysis considered a total of 10 different thermal storage/solar systems, 5 each for absorption and Rankine chiller concepts. The residential analysis considered 4 thermal storage/solar systems, all utilizing an absorption chiller. The trade-offs considered include: cold-side versus hot-side storage, single vs multiple stage storage, and phase-change vs sensible heat storage.

  3. Storage phosphors for thermal neutron detection

    Energy Technology Data Exchange (ETDEWEB)

    Sidorenko, A.V. E-mail: asidore@iri.tudelft.nl; Bos, A.J.J.; Dorenbos, P.; Le Masson, N.J.M.; Rodnyi, P.A.; Eijk, C.W.E. van; Berezovskaya, I.V.; Dotsenko, V.P

    2002-06-21

    The commercial BaFBr:Eu{sup 2+}{center_dot}Gd{sub 2}O{sub 3} image plate (IP) is used nowadays for thermal neutron detection. However, it is rather sensitive to {gamma}-ray background, which can deteriorate the image quality. We focused our research on the development of new types of storage phosphors with the general formula M{sub 2}B{sub 5}O{sub 9}Br:Ce{sup 3+} (M=Sr, Ca). Neutron detection is based on the {sup 10}B(n,{alpha}) reaction. The advantages of this system are the low Z{sub eff}, and the 40 times higher energy deposition resulting from the neutron capture reaction in comparison with that in the commercial IP. Here we present storage and spectroscopic properties of a series of newly synthesized haloborates. Comparative measurements with commercial IPs were done under neutron and {beta} irradiation. A satisfying light output of optically stimulated luminescence was achieved upon neutron irradiation.

  4. Composite materials for thermal energy storage

    Science.gov (United States)

    Benson, David K.; Burrows, Richard W.; Shinton, Yvonne D.

    1986-01-01

    The present invention discloses composite material for thermal energy storage based upon polyhydric alcohols, such as pentaerythritol, trimethylol ethane (also known as pentaglycerine), neopentyl glycol and related compounds including trimethylol propane, monoaminopentaerythritol, diamino-pentaerythritol and tris(hydroxymethyl)acetic acid, separately or in combinations, which provide reversible heat storage through crystalline phase transformations. These phase change materials do not become liquid during use and are in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, porous rock, and mixtures thereof. Particulate additions, such as aluminum or graphite powders, as well as metal and carbon fibers can also be incorporated therein. Particulate and/or fibrous additions can be introduced into molten phase change materials which can then be cast into various shapes. After the phase change materials have solidified, the additions will remain dispersed throughout the matrix of the cast solid. The polyol is in contact with at least one material selected from the group consisting of metals, carbon siliceous, plastic, cellulosic, natural fiber, artificial fiber, concrete, gypsum, and mixtures thereof.

  5. Storage phosphors for thermal neutron detection

    CERN Document Server

    Sidorenko, A V; Dorenbos, P; Le Masson, N J M; Rodnyi, P A; Eijk, C W E; Berezovskaya, I V; Dotsenko, V P

    2002-01-01

    The commercial BaFBr:Eu sup 2 sup +centre dot Gd sub 2 O sub 3 image plate (IP) is used nowadays for thermal neutron detection. However, it is rather sensitive to gamma-ray background, which can deteriorate the image quality. We focused our research on the development of new types of storage phosphors with the general formula M sub 2 B sub 5 O sub 9 Br:Ce sup 3 sup + (M=Sr, Ca). Neutron detection is based on the sup 1 sup 0 B(n,alpha) reaction. The advantages of this system are the low Z sub e sub f sub f , and the 40 times higher energy deposition resulting from the neutron capture reaction in comparison with that in the commercial IP. Here we present storage and spectroscopic properties of a series of newly synthesized haloborates. Comparative measurements with commercial IPs were done under neutron and beta irradiation. A satisfying light output of optically stimulated luminescence was achieved upon neutron irradiation.

  6. Advanced Thermal Storage for Central Receivers with Supercritical Coolants

    Energy Technology Data Exchange (ETDEWEB)

    Kelly, Bruce D.

    2010-06-15

    The principal objective of the study is to determine if supercritical heat transport fluids in a central receiver power plant, in combination with ceramic thermocline storage systems, offer a reduction in levelized energy cost over a baseline nitrate salt concept. The baseline concept uses a nitrate salt receiver, two-tank (hot and cold) nitrate salt thermal storage, and a subcritical Rankine cycle. A total of 6 plant designs were analyzed, as follows: Plant Designation Receiver Fluid Thermal Storage Rankine Cycle Subcritical nitrate salt Nitrate salt Two tank nitrate salt Subcritical Supercritical nitrate salt Nitrate salt Two tank nitrate salt Supercritical Low temperature H2O Supercritical H2O Two tank nitrate salt Supercritical High temperature H2O Supercritical H2O Packed bed thermocline Supercritical Low temperature CO2 Supercritical CO2 Two tank nitrate salt Supercritical High temperature CO2 Supercritical CO2 Packed bed thermocline Supercritical Several conclusions have been drawn from the results of the study, as follows: 1) The use of supercritical H2O as the heat transport fluid in a packed bed thermocline is likely not a practical approach. The specific heat of the fluid is a strong function of the temperatures at values near 400 °C, and the temperature profile in the bed during a charging cycle is markedly different than the profile during a discharging cycle. 2) The use of supercritical CO2 as the heat transport fluid in a packed bed thermocline is judged to be technically feasible. Nonetheless, the high operating pressures for the supercritical fluid require the use of pressure vessels to contain the storage inventory. The unit cost of the two-tank nitrate salt system is approximately $24/kWht, while the unit cost of the high pressure thermocline system is nominally 10 times as high. 3) For the supercritical fluids, the outer crown temperatures of the receiver tubes are in the range of 700 to 800 °C. At temperatures of 700 °C and above

  7. Thermal Energy Storage technical progress report, April 1984-March 1985

    Energy Technology Data Exchange (ETDEWEB)

    Martin, J.F.

    1986-01-01

    Progress in the development of Thermal Energy Storage (TES) technology under the Oak Ridge National Laboratory Thermal Energy Storage Program for the period April 1984-March 1985 is reported. The program goals and project structure are presented. Each of the areas of TES research active in the program is discussed, and a discussion of technology efforts is included.

  8. Development of thermal energy storage materials for biomedical applications.

    Science.gov (United States)

    Shukla, A; Sharma, Atul; Shukla, Manjari; Chen, C R

    2015-01-01

    The phase change materials (PCMs) have been utilized widely for solar thermal energy storage (TES) devices. The quality of these materials to remain at a particular temperature during solid-liquid, liquid-solid phase transition can also be utilized for many biomedical applications as well and has been explored in recent past already. This study reports some novel PCMs developed by them, along with some existing PCMs, to be used for such biomedical applications. Interestingly, it was observed that the heating/cooling properties of these PCMs enhance the quality of a variety of biomedical applications with many advantages (non-electric, no risk of electric shock, easy to handle, easy to recharge thermally, long life, cheap and easily available, reusable) over existing applications. Results of the present study are quite interesting and exciting, opening a plethora of opportunities for more work on the subject, which require overlapping expertise of material scientists, biochemists and medical experts for broader social benefits.

  9. Thermal-Responsive Polymers for Enhancing Safety of Electrochemical Storage Devices.

    Science.gov (United States)

    Yang, Hui; Leow, Wan Ru; Chen, Xiaodong

    2018-01-24

    Thermal runway constitutes the most pressing safety issue in lithium-ion batteries and supercapacitors of large-scale and high-power density due to risks of fire or explosion. However, traditional strategies for averting thermal runaway do not enable the charging-discharging rate to change according to temperature or the original performance to resume when the device is cooled to room temperature. To efficiently control thermal runaway, thermal-responsive polymers provide a feasible and reversible strategy due to their ability to sense and subsequently act according to a predetermined sequence when triggered by heat. Herein, recent research progress on the use of thermal-responsive polymers to enhance the thermal safety of electrochemical storage devices is reviewed. First, a brief discussion is provided on the methods of preventing thermal runaway in electrochemical storage devices. Subsequently, a short review is provided on the different types of thermal-responsive polymers that can efficiently avoid thermal runaway, such as phase change polymers, polymers with sol-gel transitions, and polymers with positive temperature coefficients. The results represent the important development of thermal-responsive polymers toward the prevention of thermal runaway in next-generation smart electrochemical storage devices. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Integration of Decentralized Thermal Storages Within District Heating (DH) Networks

    Science.gov (United States)

    Schuchardt, Georg K.

    2016-12-01

    Thermal Storages and Thermal Accumulators are an important component within District Heating (DH) systems, adding flexibility and offering additional business opportunities for these systems. Furthermore, these components have a major impact on the energy and exergy efficiency as well as the heat losses of the heat distribution system. Especially the integration of Thermal Storages within ill-conditioned parts of the overall DH system enhances the efficiency of the heat distribution. Regarding an illustrative and simplified example for a DH system, the interactions of different heat storage concepts (centralized and decentralized) and the heat losses, energy and exergy efficiencies will be examined by considering the thermal state of the heat distribution network.

  11. An Isotope-Powered Thermal Storage unit for space applications

    Science.gov (United States)

    Lisano, Michael E.; Rose, M. F.

    An Isotope-Powered Thermal Storage Unit (ITSU), that would store and utilize heat energy in a 'pulsed' fashion in space operations, is described. Properties of various radioisotopes are considered in conjunction with characteristics of thermal energy storage materials, to evaluate possible implementation of such a device. The utility of the unit is discussed in light of various space applications, including rocket propulsion, power generation, and spacecraft thermal management.

  12. Modelling and monitoring of Aquifer Thermal Energy Storage : impacts of soil heterogeneity, thermal interference and bioremediation

    NARCIS (Netherlands)

    Sommer, W.T.

    2015-01-01

    Modelling and monitoring of Aquifer Thermal Energy Storage Impacts of heterogeneity, thermal interference and bioremediation Wijbrand Sommer
    PhD thesis, Wageningen University, Wageningen, NL (2015)
    ISBN 978-94-6257-294-2 Abstract Aquifer thermal energy storage (ATES) is

  13. Numerical Modeling of a Shallow Borehole Thermal Energy Storage System

    Science.gov (United States)

    Catolico, N.; Ge, S.; Lu, N.; McCartney, J. S.

    2014-12-01

    Borehole thermal energy storage (BTES) combined with solar thermal energy harvesting is an economic technological system to garner and store energy as well as an environmentally-sustainable alternative for the heating of buildings. The first community-scale BTES system in North America was installed in 2007 in the Drake Landing Solar Community (DLSC), about 35 miles south of Calgary, Canada. The BTES system involves direct circulation of water heated from solar thermal panels in the summer into a storage tank, after which it is circulate within an array of 144 closed-loop geothermal heat exchangers having a depth of 35 m and a spacing of 2.5 m. In the winter the circulation direction is reversed to supply heat to houses. Data collection over a six year period indicates that this system can supply more than 90% of the winter heating energy needs for 52 houses in the community. One major challenge facing the BTES system technology is the relatively low annual efficiency, i.e., the ratio of energy input and output is in the range of 15% to 40% for the system in Drake Landing. To better understand the working principles of BTES and to improve BTES performance for future applications at larger scales, a three-dimensional transient coupled fluid and heat transfer model is established using TOUGH2. The time-dependent injection temperatures and circulation rate measured over the six years of monitoring are used as model input. The simulations are calibrated using soil temperature data measured at different locations over time. The time-dependent temperature distributions within the borehole region agree well with the measured temperatures for soil with an intrinsic permeability of 10e-19 m2, an apparent thermal conductivity of 2.03 W/m°C, and a volumetric heat capacity of 2.31 MJ/m-3°C. The calibrated model serves as the basis for a sensitivity analysis of soil and operational parameters on BTES system efficiency preformed with TOUGH2. Preliminary results suggest 1) BTES

  14. Food storage temperatures monitored at retail

    Directory of Open Access Journals (Sweden)

    Eleonora Sarno

    2013-04-01

    Full Text Available Aim of the present work is to report data concerning the maintenance of the cold chain by retail food business operators. A total of 401 refrigerators and 105 freezers from 112 retails (big, medium, small size were monitored for display temperatures. In addition, the surface temperature of 341 stored food products was recorded. Storage temperatures were respected in the majority of retail markets, with the exception of small retails, where cold chain was not respected. Among all food samples, yogurt was stored at temperature higher than law limits. Our findings show that retailers, in particular those from small markets, are not always familiar with cold chain maintenance. In our opinion, much more attention should be paid in keeping food at cold temperature in order to ensure food safety.

  15. High Efficiency and Low Cost Thermal Energy Storage System

    Energy Technology Data Exchange (ETDEWEB)

    Sienicki, James J. [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Lv, Qiuping [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Moisseytsev, Anton [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division; Bucknor, Matthew [Argonne National Lab. (ANL), Argonne, IL (United States). Nuclear Engineering Division

    2017-09-29

    BgtL, LLC (BgtL) is focused on developing and commercializing its proprietary compact technology for processes in the energy sector. One such application is a compact high efficiency Thermal Energy Storage (TES) system that utilizes the heat of fusion through phase change between solid and liquid to store and release energy at high temperatures and incorporate state-of-the-art insulation to minimize heat dissipation. BgtL’s TES system would greatly improve the economics of existing nuclear and coal-fired power plants by allowing the power plant to store energy when power prices are low and sell power into the grid when prices are high. Compared to existing battery storage technology, BgtL’s novel thermal energy storage solution can be significantly less costly to acquire and maintain, does not have any waste or environmental emissions, and does not deteriorate over time; it can keep constant efficiency and operates cleanly and safely. BgtL’s engineers are experienced in this field and are able to design and engineer such a system to a specific power plant’s requirements. BgtL also has a strong manufacturing partner to fabricate the system such that it qualifies for an ASME code stamp. BgtL’s vision is to be the leading provider of compact systems for various applications including energy storage. BgtL requests that all technical information about the TES designs be protected as proprietary information. To honor that request, only non-proprietay summaries are included in this report.

  16. Heat exchange studies on coconut oil cells as thermal energy storage for room thermal conditioning

    Science.gov (United States)

    Sutjahja, I. M.; Putri, Widya A.; Fahmi, Z.; Wonorahardjo, S.; Kurnia, D.

    2017-07-01

    As reported by many thermal environment experts, room air conditioning might be controlled by thermal mass system. In this paper we discuss the performance of coconut oil cells as room thermal energy storage. The heat exchange mechanism of coconut oil (CO) which is one of potential organic Phase Change Material (PCM) is studied based on the results of temperature measurements in the perimeter and core parts of cells. We found that the heat exchange performance, i.e. heat absorption and heat release processes of CO cells are dominated by heat conduction in the sensible solid from the higher temperature perimeter part to the lower temperature core part and heat convection during the solid-liquid phase transition and sensible liquid phase. The capability of heat absorption as measured by the reduction of air temperature is not influenced by CO cell size. Besides that, the application of CO as the thermal mass has to be accompanied by air circulation to get the cool sensation of the room’s occupants.

  17. Evaluation of solar thermal storage for base load electricity generation

    Directory of Open Access Journals (Sweden)

    Adinberg R.

    2012-10-01

    Full Text Available In order to stabilize solar electric power production during the day and prolong the daily operating cycle for several hours in the nighttime, solar thermal power plants have the options of using either or both solar thermal storage and fossil fuel hybridization. The share of solar energy in the annual electricity production capacity of hybrid solar-fossil power plants without energy storage is only about 20%. As it follows from the computer simulations performed for base load electricity demand, a solar annual capacity as high as 70% can be attained by use of a reasonably large thermal storage capacity of 22 full load operating hours. In this study, the overall power system performance is analyzed with emphasis on energy storage characteristics promoting a high level of sustainability for solar termal electricity production. The basic system parameters, including thermal storage capacity, solar collector size, and annual average daily discharge time, are presented and discussed.

  18. Low temperature liquefied gas storage tank

    Energy Technology Data Exchange (ETDEWEB)

    Noma, T.; Hayakawa, K.; Nagao, O.; Okano, I.; Teramoto, R.; Kurihara, T.; Kakano, K.; Okamoto, T.

    1974-07-30

    The inner wall of Hitachi's improved liquefied gas storage tank is made up of multi-layer panels, each panel made liquid-tight by bonding a low-temperature-resistant metal sheet (such as aluminum or stainless steel or a synthetic resin film) to both sides of a plywood core consisting of numerous veneers. These veneers are then bonded to the liquid-tight membranes to serve as heat-shock-absorbing layers.

  19. Storage temperature affects fruit quality attributes of Ber ( Ziziphus ...

    African Journals Online (AJOL)

    The quality of Jujube or Ber (Ziziphus mauritiana Lamk.) fruits after harvest depends on storage conditions used. In this study, different storage temperatures and durations were evaluated to determine the appropriate storage conditions of fresh fruits of Z. mauritiana. Three storage temperature levels, low (5oC), intermediate ...

  20. Thermal storage/discharge performances of Cu-Si alloy for solar thermochemical process

    Science.gov (United States)

    Gokon, Nobuyuki; Yamaguchi, Tomoya; Cho, Hyun-seok; Bellan, Selvan; Hatamachi, Tsuyoshi; Kodama, Tatsuya

    2017-06-01

    The present authors (Niigata University, Japan) have developed a tubular reactor system using novel "double-walled" reactor/receiver tubes with carbonate molten-salt thermal storage as a phase change material (PCM) for solar reforming of natural gas and with Al-Si alloy thermal storage as a PCM for solar air receiver to produce high-temperature air. For both of the cases, the high heat capacity and large latent heat (heat of solidification) of the PCM phase circumvents the rapid temperature change of the reactor/receiver tubes at high temperatures under variable and uncontinuous characteristics of solar radiation. In this study, we examined cyclic properties of thermal storage/discharge for Cu-Si alloy in air stream in order to evaluate a potentiality of Cu-Si alloy as a PCM thermal storage material. Temperature-increasing performances of Cu-Si alloy are measured during thermal storage (or heat-charge) mode and during cooling (or heat-discharge) mode. A oxidation state of the Cu-Si alloy after the cyclic reaction was evaluated by using electron probe micro analyzer (EPMA).

  1. Evaluation of stratified thermal-storage system for Oliver Springs Elementary School

    Science.gov (United States)

    Reid, R. L.; Bedinger, A. F. G.

    1982-08-01

    The thermal storage system at the Oliver Springs Elementary School consists of three cast-in-place concrete water storage tanks, each approximately 2956 ft(3) and using a flexible membrane device to resist temperature blending. The membrane can float up and down to suit variable conditions. The design goals of the heat recovery and thermal energy storage are to minimize the need to purchase energy for space heating, cooling, and water heating and to minimize electrical demand. The system is described and the history of the project is briefly reviewed. The automatic data acquisition system and the data analysis are also briefly discussed.

  2. Seasonal thermal energy storage in shallow geothermal systems: thermal equilibrium stage

    Directory of Open Access Journals (Sweden)

    Nowamooz Hossein

    2016-01-01

    Full Text Available This paper is dedicated to the study of seasonal heat storage in shallow geothermal installations in unsaturated soils for which hydrothermal properties such as degree of saturation and thermal conductivity vary with time throughout the profile. In the model, a semi-analytical model which estimates time-spatial thermal conductivity is coupled with a 2D cylindrical heat transfer modeling using finite difference method. The variation of temperature was obtained after 3 heating and cooling cycles for the different types of loads with maximum thermal load of qmax = 15 W.m−1 with variable angular frequency (8 months of heating and 4 months of cooling.and constant angular frequency (6 months of heating and 6 months of cooling to estimate the necessary number of cycles to reach the thermal equilibrium stage. The results show that we approach a thermal equilibrium stage where the same variation of temperature can be observed in soils after several heating and cooling cycles. Based on these simulations, the necessary number of cycles can be related to the total applied energy on the system and the minimum number of cycles is for a system with the total applied energy of 1.9qmax.

  3. Composite Materials for Thermal Energy Storage: Enhancing Performance through Microstructures

    Science.gov (United States)

    Ge, Zhiwei; Ye, Feng; Ding, Yulong

    2014-01-01

    Chemical incompatibility and low thermal conductivity issues of molten-salt-based thermal energy storage materials can be addressed by using microstructured composites. Using a eutectic mixture of lithium and sodium carbonates as molten salt, magnesium oxide as supporting material, and graphite as thermal conductivity enhancer, the microstructural development, chemical compatibility, thermal stability, thermal conductivity, and thermal energy storage performance of composite materials are investigated. The ceramic supporting material is essential for preventing salt leakage and hence provides a solution to the chemical incompatibility issue. The use of graphite gives a significant enhancement on the thermal conductivity of the composite. Analyses suggest that the experimentally observed microstructural development of the composite is associated with the wettability of the salt on the ceramic substrate and that on the thermal conduction enhancer. PMID:24591286

  4. Second law optimization of a sensible heat thermal energy storage system with a distributed storage element

    Energy Technology Data Exchange (ETDEWEB)

    Taylor, M.J.

    1986-07-01

    This numerical study defined the behavior of a sensible heat thermal energy storage system whose physical design and operation had been optimized to minimize the production of thermodynamic irreversibilities. It included the effects of transient conduction within the storage material. A dimensionless set of governing equations was defined for a complete storage-removal cycle that included the effects of entropy generation due to convection and viscous effects in the flowing fluid, two-dimensional transient conduction within the storage material, and to convection due to the discharged hot fluid coming to equilibrium with the environment during the storage period. A computer program was written to solve this equation set and this program was in turn controlled by a sophisticated optimization routine to determine a dimensionless storage time, flow channel half-height, and heat transfer coefficient that resulted in a minimum amount of availability destruction. The results of this analysis showed that entropy generation within the storage material due to transient conduction was a major contributor to the total thermal irreversibilities associated with the operation of a sensible heat thermal energy storage system. For the counterflow configuration and over the range of design variables examined, material entropy generation accounted for between 26% and 60% of the total thermal availability destruction that occurred during a complete storage-removal cycle. It was also shown that the storage material aspect ratio had a significant impact on the optimum design of a storage system. Its influence was second only to the fluid mass velocity.

  5. Analysis of regenerative thermal storage geometries for solar gas turbines

    CSIR Research Space (South Africa)

    Klein, P

    2014-08-01

    Full Text Available Ceramic heat regenerators are suited to providing thermal storage for concentrating solar power stations based on a recuperated gas turbine cycle. Randomly packed beds of spheres and saddles; honeycombs and checker bricks were identified...

  6. On the Behavior of Different PCMs in a Hot Water Storage Tank against Thermal Demands

    Directory of Open Access Journals (Sweden)

    Jacobo Porteiro

    2016-03-01

    Full Text Available Advantages, such as thermal storage improvement, are found when using PCMs (Phase Change Materials in storage tanks. The inclusion of three different types of materials in a 60 l test tank is studied. Two test methodologies were developed, and four tests were performed following each methodology. A thermal analysis is performed to check the thermal properties of each PCM. The distributions of the water temperatures inside the test tanks are evaluated by installing four Pt-100 sensors at different heights. A temperature recovery is observed after exposing the test tank to an energy demand. An energetic analysis that takes into account the energy due to the water temperature, the energy due to the PCM and the thermal loss to the ambient environment is also presented. The percentage of each PCM that remains in the liquid state after the energy demand is obtained.

  7. Hot Thermal Storage in a Variable Power, Renewable Energy System

    Science.gov (United States)

    2014-06-01

    commercially proven and available energy collection, conversion , and storage systems and equipment. Chapter IV presents a method for innovative integration of...molten salt. On a grid scale, off-peak electricity, converted by ohmic heating, and thermal energy from a concentrated solar power ( CSP ) plant...renewable generation system with heat storage. It reviews the available energy sources as well as methods for energy conversion and storage. A

  8. Thermal Shield and Reactor Structure Temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Collier, A.R.

    2001-07-31

    The purpose of this report is to present reactor structure and thermal shield temperature data taken during P-3 and P-5 cycles and compare them with design calculations in order to predict temperatures at higher power levels.

  9. Clay facial masks: physicochemical stability at different storage temperatures.

    Science.gov (United States)

    Zague, Vivian; de Almeida Silva, Diego; Baby, André Rolim; Kaneko, Telma Mary; Velasco, Maria Valéria Robles

    2007-01-01

    Clay facial masks--formulations that contain a high percentage of solids dispersed in a liquid vehicle--have become of special interest due to specific properties presented by clays, such as particle size, cooling index, high adsorption capacity, and plasticity. Although most of the physicochemical properties of clay dispersions have been studied, specific aspects concerning the physicochemical stability of clay mask products remain unclear. This work aimed at investigating the accelerated physicochemical stability of clay mask formulations stored at different temperatures. Formulations were subjected to centrifuge testing and to thermal treatment for 15 days, during which temperature was varied from -5.0 degrees to 45.0 degrees C. The apparent viscosity and visual aspect (homogeneity) of all formulations were affected by temperature variation, whereas color, odor, and pH value remained unaltered. These results, besides the estimation of physicochemical stability under aging, can be useful in determining the best storage conditions for clay-based formulations.

  10. Ternary mixture of fatty acids as phase change materials for thermal energy storage applications

    Directory of Open Access Journals (Sweden)

    Karunesh Kant

    2016-11-01

    Full Text Available The present study deals with the development of ternary mixtures of fatty acids for low temperature thermal energy storage applications. The commercial grade fatty acids such as Capric Acid (CA, Lauric Acid (LA, Palmitic Acid (PA and Stearic Acid (SA, have been used to prepare stable, solid–liquid phase change material (PCM for the same. In this regard, a series of ternary mixture i.e. CA–LA–SA (CLS and CA–PA–SA (CPS have been developed with different weight percentages. Thermal characteristics of these developed ternary mixture i.e. melting temperature and latent heat of fusion have been measured by using Differential Scanning Calorimeter (DSC technique. The synthesized materials are found to have melting temperature in the range of 14–21 °C (along with adequate amount of latent heat of fusion, which may be quite useful for several low temperature thermal energy storage applications.

  11. Enhancing the thermal response of latent heat storage systems

    Energy Technology Data Exchange (ETDEWEB)

    Bugaje, I.M. [Ahmadu Bello Univ., Zaria (Nigeria)

    1997-07-01

    This paper reports experiments carried out to investigate methods of enhancing the thermal response of paraffin wax heat storage tubes by incorporation of aluminium thermal conductivity promoters of various designs into the body of the wax. Heating and cooling runs were carried out and phase change times determined. It was found that the phase change time reduced significantly by orders of up to 2.2 in energy storage (heating) and 4.2 in energy recovery (cooling). Internal fins performed much better than the star matrices and expanded aluminium performed better than promoters made from aluminium sheet metal in both storage and recovery of heat. (author)

  12. Advanced latent heat of fusion thermal energy storage for solar power systems

    Science.gov (United States)

    Phillips, W. M.; Stearns, J. W.

    1985-01-01

    The use of solar thermal power systems coupled with thermal energy storage (TES) is being studied for both terrestrial and space applications. In the case of terrestrial applications, it was found that one or two hours of TES could shift the insolation peak (solar noon) to coincide with user peak loads. The use of a phase change material (PCM) is attractive because of the higher energy storage density which can be achieved. However, the use of PCM has also certain disadvantages which must be addressed. Proof of concept testing was undertaken to evaluate corrosive effects and thermal ratcheting effects in a slurry system. It is concluded that the considered alkali metal/alkali salt slurry approach to TES appears to be very viable, taking into account an elimination of thermal ratcheting in storage systems and the reduction of corrosive effects. The approach appears to be useful for an employment involving temperatures applicable to Brayton or Stirling cycles.

  13. Aquifer thermal energy storage reference manual: seasonal thermal energy storage program

    Energy Technology Data Exchange (ETDEWEB)

    Prater, L.S.

    1980-01-01

    This is the reference manual of the Seasonal Thermal Energy Storage (STES) Program, and is the primary document for the transfer of technical information of the STES Program. It has been issued in preliminary form and will be updated periodically to include more technical data and results of research. As the program progresses and new technical data become available, sections of the manual will be revised to incorporate these data. This primary document contains summaries of: the TRW, incorporated demonstration project at Behtel, Alaska, Dames and Moore demonstration project at Stony Brook, New York, and the University of Minnesota demonstration project at Minneapolis-St. Paul, Minnesota; the technical support programs including legal/institutional assessment; economic assessment; environmental assessment; field test facilities; a compendia of existing information; numerical simulation; and non-aquifer STES concepts. (LCL)

  14. Active thermal isolation for temperature responsive sensors

    Science.gov (United States)

    Martinson, Scott D. (Inventor); Gray, David L. (Inventor); Carraway, Debra L. (Inventor); Reda, Daniel C. (Inventor)

    1994-01-01

    A temperature responsive sensor is located in the airflow over the specified surface of a body and is maintained at a constant temperature. An active thermal isolator is located between this temperature responsive sensor and the specified surface of the body. The temperature of this isolator is controlled to reduce conductive heat flow from the temperature responsive sensor to the body. This temperature control includes: (1) operating the isolator at the same temperature as the constant temperature of the sensor and (2) establishing a fixed boundary temperature which is either less than or equal to or slightly greater than the sensor constant temperature.

  15. Integration of Decentralized Thermal Storages Within District Heating (DH Networks

    Directory of Open Access Journals (Sweden)

    Schuchardt Georg K.

    2016-12-01

    Full Text Available Thermal Storages and Thermal Accumulators are an important component within District Heating (DH systems, adding flexibility and offering additional business opportunities for these systems. Furthermore, these components have a major impact on the energy and exergy efficiency as well as the heat losses of the heat distribution system. Especially the integration of Thermal Storages within ill-conditioned parts of the overall DH system enhances the efficiency of the heat distribution. Regarding an illustrative and simplified example for a DH system, the interactions of different heat storage concepts (centralized and decentralized and the heat losses, energy and exergy efficiencies will be examined by considering the thermal state of the heat distribution network.

  16. Hydration of Magnesium Carbonate in a Thermal Energy Storage Process and Its Heating Application Design

    Directory of Open Access Journals (Sweden)

    Rickard Erlund

    2018-01-01

    Full Text Available First ideas of applications design using magnesium (hydro carbonates mixed with silica gel for day/night and seasonal thermal energy storage are presented. The application implies using solar (or another heat source for heating up the thermal energy storage (dehydration unit during daytime or summertime, of which energy can be discharged (hydration during night-time or winter. The applications can be used in small houses or bigger buildings. Experimental data are presented, determining and analysing kinetics and operating temperatures for the applications. In this paper the focus is on the hydration part of the process, which is the more challenging part, considering conversion and kinetics. Various operating temperatures for both the reactor and the water (storage tank are tested and the favourable temperatures are presented and discussed. Applications both using ground heat for water vapour generation and using water vapour from indoor air are presented. The thermal energy storage system with mixed nesquehonite (NQ and silica gel (SG can use both low (25–50% and high (75% relative humidity (RH air for hydration. The hydration at 40% RH gives a thermal storage capacity of 0.32 MJ/kg while 75% RH gives a capacity of 0.68 MJ/kg.

  17. Technical and economic feasibility of thermal energy storage. Annual report

    Energy Technology Data Exchange (ETDEWEB)

    Glenn, D.R.

    1976-02-01

    This study provides a first-look at the system elements involved in: (1) creating a market; (2) understanding and deriving the requirements; (3) performing analytical effort; (4) specifying equipment; and (5) synthesizing applications for a thermal energy storage (TES) function. The work reviews implicated markets, energy consumption patterns, TES technologies, and applications. Further, several concepts are developed and evaluated in some detail. Key findings are: (1) there are numerous technical opportunities for TES in the residential and industrial market sectors; (2) apart from sensible heat storage and transfer, significant R and D is required to fully exploit the superior heat densities of latent heat-based TES systems, particularly at temperatures above 600/sup 0/F; (3) industrial energy conservation can be favorably impacted by TES where periodic or batch-operated unit functions characterize product manufacturing processes, i.e. bricks, steel, and ceramics; and (4) a severe data shortage exists for describing energy consumption rates in real time as related to plant process operations--a needed element in designing TES systems.

  18. Experimental Study on Melting and Solidification of Phase Change Material Thermal Storage

    Science.gov (United States)

    Ambarita, H.; Abdullah, I.; Siregar, C. A.; Siregar, R. E. T.; Ronowikarto, A. D.

    2017-03-01

    Melting and solidification process of Phase Change Materials (PCMs) are investigated experimentally. The tested PCMs are Paraffin wax and Steric acid which typically used for solar water heater. The objective is to explore the characteristics of the PCM when it is being melted and solidified. The experiments are performed in a glass box. One side of the box wall is heated while the opposite wall is kept constant and other walls are insulated. Temperature of the heated wall are kept constant at 80°C, 85°C, and 90°C, respectively. Every experiment is carried out for 600 minutes. Temperatures are recorded and the melting and solidification processes are pictured by using camera. The results show that the melting process starts from the upper part of the thermal storage. In the solidification process, it starts from the lower part of the thermal storage. As a thermal energy storage, Paraffin wax is better than Steric acid. This is because Paraffin wax can store more energy. At heat source temperature of 90°C, thermal energy stored by Paraffin wax and Stearic acid is 61.84 kJ and 57.39 kJ, respectively. Thus it is better to used Paraffin wax in the solar water heater as thermal energy storage.

  19. Thermal energy storage for low grade heat in the organic Rankine cycle

    Science.gov (United States)

    Soda, Michael John

    Limits of efficiencies cause immense amounts of thermal energy in the form of waste heat to be vented to the atmosphere. Up to 60% of unrecovered waste heat is classified as low or ultra-low quality, making recovery difficult or inefficient. The organic Rankine cycle can be used to generate mechanical power and electricity from these low temperatures where other thermal cycles are impractical. A variety of organic working fluids are available to optimize the ORC for any target temperature range. San Diego State University has one such experimental ORC using R245fa, and has been experimenting with multiple expanders. One limitation of recovering waste heat is the sporadic or cyclical nature common to its production. This inconsistency makes sizing heat recovery ORC systems difficult for a variety of reasons including off-design-point efficiency loss, increased attrition from varying loads, unreliable outputs, and overall system costs. Thermal energy storage systems can address all of these issues by smoothing the thermal input to a constant and reliable level and providing back-up capacity for times when the thermal input is deactivated. Multiple types of thermal energy storage have been explored including sensible, latent, and thermochemical. Latent heat storage involves storing thermal energy in the reversible phase change of a phase change material, or PCM, and can have several advantages over other modalities including energy storage density, cost, simplicity, reliability, relatively constant temperature output, and temperature customizability. The largest obstacles to using latent heat storage include heat transfer rates, thermal cycling stability, and potentially corrosive PCMs. Targeting 86°C, the operating temperature of SDSU's experimental ORC, multiple potential materials were explored and tested as potential PCMs including Magnesium Chloride Hexahydrate (MgCl2˙6H2O), Magnesium Nitrate Hexahydrate (Mg(NO3)2˙6H 2O), montan wax, and carnauba wax. The

  20. Review of simulation techniques for aquifer thermal energy storage (ATES)

    Energy Technology Data Exchange (ETDEWEB)

    Mercer, J.W.; Faust, C.R.; Miller, W.J.; Pearson, F.J. Jr.

    1981-03-01

    The storage of thermal energy in aquifers has recently received considerable attention as a means to conserve and more efficiently use energy supplies. The analysis of aquifer thermal energy storage (ATES) systems will rely on the results from mathematical and geochemical models. Therefore, the state-of-the-art models relevant to ATES was reviewed and evaluated. These models describe important processes active in ATES including ground-water flow, heat transport (heat flow), solute transport (movement of contaminants), and geochemical reactions. In general, available models of the saturated ground-water environment are adequate to address most concerns associated with ATES; that is, design, operation, and environmental assessment. In those cases where models are not adequate, development should be preceded by efforts to identify significant physical phenomena and relate model parameters to measurable quantities. Model development can then proceed with the expectation of an adequate data base existing for the model's eventual use. Review of model applications to ATES shows that the major emphasis has been on generic sensitivity analysis and site characterization. Assuming that models are applied appropriately, the primary limitation on model calculations is the data base used to construct the model. Numerical transport models are limited by the uncertainty of subsurface data and the lack of long-term historical data for calibration. Geochemical models are limited by the lack of thermodynamic data for the temperature ranges applicable to ATES. Model applications undertaken with data collection activities on ATES sites should provide the most important contributions to the understanding and utilization of ATES. Therefore, the primary conclusion of this review is that model application to field sites in conjunction with data collection activities is essential to the development of this technology.

  1. An evaluation of thermal energy storage options for precooling gas turbine inlet air

    Science.gov (United States)

    Antoniak, Z. I.; Brown, D. R.; Drost, M. K.

    1992-12-01

    Several approaches have been used to reduce the temperature of gas turbine inlet air. One of the most successful uses off-peak electric power to drive vapor-compression-cycle ice makers. The ice is stored until the next time high ambient temperature is encountered, when the ice is used in a heat exchanger to cool the gas turbine inlet air. An alternative concept would use seasonal thermal energy storage to store winter chill for inlet air cooling. The objective of this study was to compare the performance and economics of seasonal thermal energy storage in aquifers with diurnal ice thermal energy storage for gas turbine inlet air cooling. The investigation consisted of developing computer codes to model the performance of a gas turbine, energy storage system, heat exchangers, and ancillary equipment. The performance models were combined with cost models to calculate unit capital costs and levelized energy costs for each concept. The levelized energy cost was calculated for three technologies in two locations (Minneapolis, Minnesota and Birmingham, Alabama). Precooling gas turbine inlet air with cold water supplied by an aquifer thermal energy storage system provided lower cost electricity than simply increasing the size of the turbine for meteorological and geological conditions existing in the Minneapolis vicinity. A 15 to 20 percent cost reduction resulted for both 0.05 and 0.2 annual operating factors. In contrast, ice storage precooling was found to be between 5 and 20 percent more expensive than larger gas turbines for the Minneapolis location. In Birmingham, aquifer thermal energy storage precooling was preferred at the higher capacity factor and ice storage precooling was the best option at the lower capacity factor. In both cases, the levelized cost was reduced by approximately 5 percent when compared to larger gas turbines.

  2. A predictive model for smart control of a domestic heat pump and thermal storage

    NARCIS (Netherlands)

    van Leeuwen, Richard Pieter; Gebhardt, I.; de Wit, J.B.; Smit, Gerardus Johannes Maria

    The purpose of this paper is to develop and validate a predictive model of a thermal storage which is charged by a heat pump and used for domestic hot water supply. The model is used for smart grid control purposes and requires measurement signals of flow and temperature at the inlet and outlet of

  3. Technical and economic feasibility of thermal storage. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Shelpuk, B.; Joy, P.; Crouthamel, M.

    1977-06-01

    The technical and economic feasibility of various thermal energy storage alternatives is determined by comparing the system performance and annualized cost which result from each storage alternative operating with the same solar collector model, the same building load model, and the same heating system and controls model. Performance and cost calculations are made on the basis of an hour-by-hour time step using actual weather bureau data for Albuquerque, N. M., and New York City for a single six-month heating season. The primary approach to comparing various storage alternatives is to allow the collector area and storage mass to vary until a minimum cost combination is achieved. In the Albuquerque location collector area of 325 ft/sup 2/, water storage mass of 12.5 lb/ft/sup 2/ of collector area, and phase change mass of 6.25 lb/ft/sup 2/ of collector area results in minimum cost systems, each of which delivers about 50% of the total building demand. The primary conclusion is that, using current costs for materials and containers, water is the cheapest storage alternative for heating applications in both Albuquerque and New York City. The cost of containing or encapsulating phase change materials, coupled with their small system performance advantage, is the main reason for this conclusion. The use of desiccant materials for thermal storage is considered to be impractical due to irreversibilities in thermal cycling.

  4. Thermoelectric cooling in combination with photovoltaics and thermal energy storage

    Directory of Open Access Journals (Sweden)

    Skovajsa Jan

    2017-01-01

    Full Text Available The article deals with the use of modern technologies that can improve the thermal comfort in buildings. The article describes the usage of thermal energy storage device based on the phase change material (PCM. The technology improves the thermal capacity of the building and it is possible to use it for active heating and cooling. It is designed as a “green technology” so it is able to use renewable energy sources, e.g., photovoltaic panels, solar thermal collectors, and heat pump. Moreover, an interesting possibility is the ability to use thermal energy storage in combination with a photovoltaic system and thermoelectric coolers. In the research, there were made measurements of the different operating modes and the results are presented in the text.

  5. Thermal Energy Storage in Phase Change Material.

    Science.gov (United States)

    1982-03-01

    model mathematically the performance of the heat storage unit. Second, there is the need to devise low-cost encansulation methods. Finally there is the...8217ekTI microroce ssr to the Pet romodore comuter . There a softwar- prrr’i’ in 1, iin, thl ca!flration curv- for th! thermocot’Ir es m ahes thp final

  6. Utility-controlled customer-side thermal-energy-storage tests: heat storage

    Energy Technology Data Exchange (ETDEWEB)

    Rizy, D.T.

    1982-02-01

    Customer-side thermal energy storage has been identified as a load-management option available to the electric utility industry. The tests described here are part of the US DOE national program for the research, development, and demonstration of electric load management using utility-controlled customer-side thermal energy storage for residential load management. Five heat storage tests are described in order to: collect reliable load-research data; delineate and solve installation problems; establish maintainability; determine customer and utility acceptance; and generate cost data to determine the potential of utility-controlled customer-side storage as a load-management option. The results are expected to assist the utility industry in making local load-management decisions and to assist DOE in establishing research and development priorities in load management. The utilities tested four types of heat storage systems: central ceramic brick; concrete slab; heat pump with storage; and pressurized hot water storage. Results of installing and operating the storage systems indicate that these residential heat storage systems are not fully commercial in their present state for use as a load-management option and the technology requires further development. Also, the numerous operational problems experienced by the utilities and high costs of installing and maintaining the storage equipment resulted in poor acceptance of the technology by the utilities and customers.

  7. Investigation of In–48Sn as a phase change material candidate for thermal storage applications

    Directory of Open Access Journals (Sweden)

    Mawire Ashmore

    2017-01-01

    Full Text Available Latent heat storage systems provide large thermal storage densities for solar energy storage for various domestic and industrial applications. In–48Sn, an alloy of indium and tin a lead-free solder is investigated as a phase change material (PCM in latent heat storage systems for heating applications. Results obtained from differential scanning calorimetry indicate that the alloy is useful in storing sensible heat beyond its melting temperature as it exhibits very little decomposition up to 400 °C. Though In–48Sn possesses a low latent heat of fusion, its high density allows for a larger thermal storage mass. The behaviour of In–48Sn in a 50 mm aluminium spherical capsule during charging and discharging cycles is investigated using sunflower oil as the heat transfer fluid (HTF at flow rates of 3, 6, 9 and 12 ml/s. The influence of the charging temperature on the charging characteristics of the encapsulated PCM is also investigated. The average charging and discharging rates of the encapsulated PCM show an increase with an increase in the HTF flow rate. The HTF temperature determines the maximum temperature attained by the PCM and thus the total energy stored by the encapsulated PCM. In–48Sn shows good potential as a PCM in a spherical aluminium capsule for packed bed domestic heat storage systems.

  8. Preliminary survey and evaluation of nonaquifer thermal energy storage concepts for seasonal storage

    Energy Technology Data Exchange (ETDEWEB)

    Blahnik, D.E.

    1980-11-01

    Thermal energy storage enables the capture and retention of heat energy (or cold) during one time period for use during another. Seasonal thermal energy storage (STES) involves a period of months between the input and recovery of energy. The purpose of this study was to make a preliminary investigation and evaluation of potential nonaquifer STES systems. Current literature was surveyed to determine the state of the art of thermal energy storage (TES) systems such as hot water pond storage, hot rock storage, cool ice storage, and other more sophisticated concepts which might have potential for future STES programs. The main energy sources for TES principally waste heat, and the main uses of the stored thermal energy, i.e., heating, cooling, and steam generation are described. This report reviews the development of sensible, latent, and thermochemical TES technologies, presents a preliminary evaluation of the TES methods most applicable to seasonal storage uses, outlines preliminary conclusions drawn from the review of current TES literature, and recommends further research based on these conclusions. A bibliography of the nonaquifer STES literature review, and examples of 53 different TES concepts drawn from the literature are provided. (LCL)

  9. Strategies for commercializing customer thermal-energy storage. [64 references

    Energy Technology Data Exchange (ETDEWEB)

    Nelson, S.H.

    1976-12-01

    This report presents strategies for commercializing customer thermal storage. Four storage techniques are evaluated: space heating, air conditioning, hot-water heating, and interruptible hot-water heating. The storage systems involved store off-peak electric energy for thermal applications during peak load hours. Analyses of both storage techniques and principal parties affected by storage indicate four barriers: the absence of (1) commercially available air conditioning storage devices, (2) appropriate rates, (3) information on both rates and devices, and (4) widespread utility support. Development of appropriate rates is the key to commercialization. The criteria used to evaluate rate types are: maximum combined utility and customer benefits, ease of commercialization, and practical feasibility. Four rate types--demand charges, time-of-use rates, and two forms of load management rates (a monthly credit and an off-peak discount)--plus the possibility of utility ownership are considered. The best rate types for each storage option are: for hot-water heating, a monthly credit for allowing utility interruptions or an off-peak price discount for storage; for space heating, an off-peak discount contingent upon meeting utility requirements; and for air conditioning, an off-peak discount plus monthly credit.

  10. Thermal storage in a heat pump heated living room floor for urban district power balancing - effects on thermal comfort, energy loss and costs for residents

    NARCIS (Netherlands)

    van Leeuwen, Richard Pieter; de Wit, J.B.; Fink, J.; Smit, Gerardus Johannes Maria

    2014-01-01

    For the Dutch smart grid demonstration project Meppelenergie, the effects of controlled thermal energy storage within the floor heating structure of a living room by a heat pump are investigated. Storage possibilities are constrained by room operative and floor temperatures. Simulations indicate

  11. Thermal and Performance Analysis of a Photovoltaic Module with an Integrated Energy Storage System

    Directory of Open Access Journals (Sweden)

    Manel Hammami

    2017-10-01

    Full Text Available This paper is proposing and analyzing an electric energy storage system fully integrated with a photovoltaic PV module, composed by a set of lithium-iron-phosphate (LiFePO4 flat batteries, which constitutes a generation-storage PV unit. The batteries were surface-mounted on the back side of the PV module, distant from the PV backsheet, without exceeding the PV frame size. An additional low-emissivity sheet was introduced to shield the batteries from the backsheet thermal irradiance. The challenge addressed in this paper is to evaluate the PV cell temperature increase, due to the reduced thermal exchanges on the back of the module, and to estimate the temperature of the batteries, verifying their thermal constraints. Two one-dimensional (1D thermal models, numerically implemented by using the thermal library of Simulink-Matlab accounting for all the heat exchanges, are here proposed: one related to the original PV module, the other related to the portion of the area of the PV module in correspondence of the proposed energy-storage system. Convective and radiative coefficients were then calculated in relation to different configurations and ambient conditions. The model validation has been carried out considering the PV module to be at the nominal operating cell temperature (NOCT, and by specific experimental measurements with a thermographic camera. Finally, appropriate models were used to evaluate the increasing cell batteries temperature in different environmental conditions.

  12. Flexible operation of thermal plants with integrated energy storage technologies

    Science.gov (United States)

    Koytsoumpa, Efthymia Ioanna; Bergins, Christian; Kakaras, Emmanouil

    2017-08-01

    The energy system in the EU requires today as well as towards 2030 to 2050 significant amounts of thermal power plants in combination with the continuously increasing share of Renewables Energy Sources (RES) to assure the grid stability and to secure electricity supply as well as to provide heat. The operation of the conventional fleet should be harmonised with the fluctuating renewable energy sources and their intermittent electricity production. Flexible thermal plants should be able to reach their lowest minimum load capabilities while keeping the efficiency drop moderate as well as to increase their ramp up and down rates. A novel approach for integrating energy storage as an evolutionary measure to overcome many of the challenges, which arise from increasing RES and balancing with thermal power is presented. Energy storage technologies such as Power to Fuel, Liquid Air Energy Storage and Batteries are investigated in conjunction with flexible power plants.

  13. Storage of low grade solar thermal energy by adsorption of organics

    Science.gov (United States)

    Kohler, Tobias; Müller, Karsten

    2017-06-01

    In this work the efficiency of new systems for adsorptive energy storage for low grade solar thermal energy is evaluated. They are based on different adsorption systems with alcohols as adsorbates on activated carbon as adsorbent. They showed superior storage characteristics compared to the reference working pair water / zeolite 13X. The maximum efficiencies of the systems methanol and ethanol on activated carbon lie in the same range as the efficiency of the reference pair, but are reached at lower regeneration temperatures. Therefore, these systems are perfectly suited for the storage of low grad heat from collector types like the flat-plate collector or vacuum-collectors.

  14. STP-ECRTS - THERMAL AND GAS ANALYSES FOR SLUDGE TRANSPORT AND STORAGE CONTAINER (STSC) STORAGE AT T PLANT

    Energy Technology Data Exchange (ETDEWEB)

    CROWE RD; APTHORPE R; LEE SJ; PLYS MG

    2010-04-29

    The Sludge Treatment Project (STP) is responsible for the disposition of sludge contained in the six engineered containers and Settler tank within the 105-K West (KW) Basin. The STP is retrieving and transferring sludge from the Settler tank into engineered container SCS-CON-230. Then, the STP will retrieve and transfer sludge from the six engineered containers in the KW Basin directly into a Sludge Transport and Storage Containers (STSC) contained in a Sludge Transport System (STS) cask. The STSC/STS cask will be transported to T Plant for interim storage of the STSC. The STS cask will be loaded with an empty STSC and returned to the KW Basin for loading of additional sludge for transportation and interim storage at T Plant. CH2MHILL Plateau Remediation Company (CHPRC) contracted with Fauske & Associates, LLC (FAI) to perform thermal and gas generation analyses for interim storage of STP sludge in the Sludge Transport and Storage Container (STSCs) at T Plant. The sludge types considered are settler sludge and sludge originating from the floor of the KW Basin and stored in containers 210 and 220, which are bounding compositions. The conditions specified by CHPRC for analysis are provided in Section 5. The FAI report (FAI/10-83, Thermal and Gas Analyses for a Sludge Transport and Storage Container (STSC) at T Plant) (refer to Attachment 1) documents the analyses. The process considered was passive, interim storage of sludge in various cells at T Plant. The FATE{trademark} code is used for the calculation. The results are shown in terms of the peak sludge temperature and hydrogen concentrations in the STSC and the T Plant cell. In particular, the concerns addressed were the thermal stability of the sludge and the potential for flammable gas mixtures. This work was performed with preliminary design information and a preliminary software configuration.

  15. Numerical Simulation of the Thermal Performance of a Dry Storage Cask for Spent Nuclear Fuel

    Directory of Open Access Journals (Sweden)

    Heui-Yung Chang

    2018-01-01

    Full Text Available In this study, the heat flow characteristics and thermal performance of a dry storage cask were investigated via thermal flow experiments and a computational fluid dynamics (CFD simulation. The results indicate that there are many inner circulations in the flow channel of the cask (the channel width is 10 cm. These circulations affect the channel airflow efficiency, which in turn affects the heat dissipation of the dry storage cask. The daily operating temperatures at the top concrete lid and the upper locations of the concrete cask are higher than those permitted by the design specification. The installation of the salt particle collection device has a limited negative effect on the thermal dissipation performance of the dry storage cask.

  16. Flexible composite material with phase change thermal storage

    Science.gov (United States)

    Buckley, Theresa M. (Inventor)

    2001-01-01

    A highly flexible composite material having a flexible matrix containing a phase change thermal storage material. The composite material can be made to heat or cool the body or to act as a thermal buffer to protect the wearer from changing environmental conditions. The composite may also include an external thermal insulation layer and/or an internal thermal control layer to regulate the rate of heat exchange between the composite and the skin of the wearer. Other embodiments of the PCM composite also provide 1) a path for evaporation or direct absorption of perspiration from the skin of the wearer for improved comfort and thermal control, 2) heat conductive pathways within the material for thermal equalization, 3) surface treatments for improved absorption or rejection of heat by the material, and 4) means for quickly regenerating the thermal storage capacity for reuse of the material. Applications of the composite materials are also described which take advantage of the composite's thermal characteristics. The examples described include a diver's wet suit, ski boot liners, thermal socks, ,gloves and a face mask for cold weather activities, and a metabolic heating or cooling blanket useful for treating hypothermia or fever patients in a medical setting and therapeutic heating or cooling orthopedic joint supports.

  17. Test facility of thermal storage equipment for space power generation

    Science.gov (United States)

    Inoue, T.; Nakagawa, M.; Mochida, Y.; Ohtomo, F.; Shimizu, K.; Tanaka, K.; Abe, Y.; Nomura, O.; Kamimoto, M.

    A thermal storage equipment test facility has been built in connection with developing solar dynamic power systems (SDPSs). The test facility consists of a recuperative closed Brayton cycle system (CBC), with a mixture of helium and xenon with a molecular weight of 39.9 serving as the working fluid. CBC has been shown to be the most attractive power generation system among several types of SDPSs because of its ability to meet the required high power demand and its thermal efficiency, about 30 percent. The authors present a description of this test facility and give results of the preliminary test and the first-stage test with heat storage equipment.

  18. Thermal energy storage for CSP (Concentrating Solar Power

    Directory of Open Access Journals (Sweden)

    Py Xavier

    2017-01-01

    Full Text Available The major advantage of concentrating solar power before photovoltaic is the possibility to store thermal energy at large scale allowing dispatchability. Then, only CSP solar power plants including thermal storage can be operated 24 h/day using exclusively the solar resource. Nevertheless, due to a too low availability in mined nitrate salts, the actual mature technology of the two tanks molten salts cannot be applied to achieve the expected international share in the power production for 2050. Then alternative storage materials are under studies such as natural rocks and recycled ceramics made from industrial wastes. The present paper is a review of those alternative approaches.

  19. Thermal energy storage for CSP (Concentrating Solar Power)

    Science.gov (United States)

    Py, Xavier; Sadiki, Najim; Olives, Régis; Goetz, Vincent; Falcoz, Quentin

    2017-07-01

    The major advantage of concentrating solar power before photovoltaic is the possibility to store thermal energy at large scale allowing dispatchability. Then, only CSP solar power plants including thermal storage can be operated 24 h/day using exclusively the solar resource. Nevertheless, due to a too low availability in mined nitrate salts, the actual mature technology of the two tanks molten salts cannot be applied to achieve the expected international share in the power production for 2050. Then alternative storage materials are under studies such as natural rocks and recycled ceramics made from industrial wastes. The present paper is a review of those alternative approaches.

  20. MGS SAMPLER THERMAL EMISSION SPECTROMETER GLOBAL TEMPERATURE

    Data.gov (United States)

    National Aeronautics and Space Administration — This archive contains Thermal Emission Spectrometer (TES) 25-micron global surface temperature data, collected during the ANS portion of the Mars Global Surveyor...

  1. High Temperature Fiberoptic Thermal Imaging System Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed Phase 1 program will fabricate and demonstrate a small diameter single fiber endoscope that can perform high temperature thermal imaging in a jet engine...

  2. Design and installation manual for thermal energy storage

    Science.gov (United States)

    Cole, R. L.; Nield, K. J.; Rohde, R. R.; Wolosewicz, R. M.

    1980-01-01

    The design and installation of thermal energy storage in active solar systems is discussed. Both air based and liquid based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to latent heat storage include properties of phase change materials, sizing the storage unit, insulating the storage unit, available systems, and cost. Topics relevant to heating domestic water include safety, single-, and dual-tank systems, domestic water heating with air and liquid based space heating systems, and stand alone domestics hot water systems. Also examined are common problems with storage systems and their solutions, heat transfer fluid properties, economic insulation thickness, heat exchanger sizing, and sample specifications for heat exchangers, wooden rock bins, steel tanks, concrete tanks, and fiberglass reinforced plastic tanks.

  3. A solar air collector with integrated latent heat thermal storage

    Science.gov (United States)

    Charvat, Pavel; Ostry, Milan; Mauder, Tomas; Klimes, Lubomir

    2012-04-01

    Simulations of the behaviour of a solar air collector with integrated latent heat thermal storage were performed. The model of the collector was created with the use of coupling between TRNSYS 17 and MATLAB. Latent heat storage (Phase Change Material - PCM) was integrated with the solar absorber. The model of the latent heat storage absorber was created in MATLAB and the model of the solar air collector itself was created in TRNSYS with the use of TYPE 56. The model of the latent heat storage absorber allows specification of the PCM properties as well as other parameters. The simulated air collector was the front and back pass collector with the absorber in the middle of the air cavity. Two variants were considered for comparison; the light-weight absorber made of sheet metal and the heat-storage absorber with the PCM. Simulations were performed for the climatic conditions of the Czech Republic (using TMY weather data).

  4. Measuring nanowire thermal conductivity at high temperatures

    Science.gov (United States)

    Wang, Xiaomeng; Yang, Juekuan; Xiong, Yucheng; Huang, Baoling; Xu, Terry T.; Li, Deyu; Xu, Dongyan

    2018-02-01

    This work extends the micro-thermal-bridge method for thermal conductivity measurements of nanowires to high temperatures. The thermal-bridge method, based on a microfabricated device with two side-by-side suspended membranes with integrated platinum resistance heaters/thermometers, has been used to determine thermal conductivity of various nanowires/nanotubes/nanoribbons at relatively low temperatures. However, to date, thermal conductivity characterization of nanowires at temperatures above 600 K has seldom been reported presumably due to several technical difficulties including the instability of the microfabricated thermometers, radiation heat loss, and the effect of the background conductance on the measurement. Here we report on our attempt to address the aforementioned challenges and demonstrate thermal conductivity measurement of boron nanoribbons up to 740 K. To eliminate high temperature resistance instability, the device is first annealed at 1023 K for 5 min in an argon atmosphere. Two radiation shields are installed in the measurement chamber to minimize radiation heat loss from the measurement device to the surroundings; and the temperature of the device at each set point is calibrated by an additional thermocouple directly mounted on the chip carrier. The effect of the background conductance is eliminated by adopting a differential measurement scheme. With all these modifications, we successfully measured the thermal conductivity of boron nanoribbons over a wide temperature range from 27 K to 740 K. The measured thermal conductivity increases monotonically with temperature and reaches a plateau of ~2.5 W m‑1 K‑1 at approximately 400 K, with no clear signature of Umklapp scattering observed in the whole measurement temperature range.

  5. Materials compatibility issues related to thermal energy storage for a space solar dynamic power system

    Science.gov (United States)

    Faget, N. M.

    1986-01-01

    Attention is given to results obtained to date in developmental investigations of a thermal energy storage (TES) system for the projected NASA Space Station's solar dynamic power system; these tests have concentrated on issues related to materials compatibility for phase change materials (PCMs) and their containment vessels' materials. The five PCMs tested have melting temperatures that correspond to the operating temperatures of either the Brayton or Rankine heat engines, which were independently chosen for their high energy densities.

  6. Preparation, thermal properties and thermal reliabilities of microencapsulated n-octadecane with acrylic-based polymer shells for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Xiaolin [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Haidian District, Beijing 100084 (China); Song, Guolin; Chu, Xiaodong; Li, Xuezhu [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Tang, Guoyi, E-mail: tanggy@tsinghua.edu.cn [Advanced Materials Institute and Clearer Production Key Laboratory, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055 (China); Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Tsinghua University, Haidian District, Beijing 100084 (China)

    2013-01-10

    Highlights: Black-Right-Pointing-Pointer n-Octadecane was encapsulated by p(butyl methacrylate) (PBMA) and p(butyl acrylate). Black-Right-Pointing-Pointer Microcapsules using divinylbenzene as crosslinking agent have better quality. Black-Right-Pointing-Pointer Microcapsule with butyl methacrylate-divinylbenzene has highest latent heat. Black-Right-Pointing-Pointer Microcapsule with butyl methacrylate-divinylbenzene has greatest thermal stability. Black-Right-Pointing-Pointer Phase change temperatures and enthalpies of the microcapsules varied little after thermal cycle. - Abstract: Microencapsulation of n-octadecane with crosslinked p(butyl methacrylate) (PBMA) and p(butyl acrylate) (PBA) as shells for thermal energy storage was carried out by a suspension-like polymerization. Divinylbenzene (DVB) and pentaerythritol triacrylate (PETA) were employed as crosslinking agents. The surface morphologies of the microencapsulated phase change materials (microPCMs) were studied by scanning electron microscopy (SEM). Thermal properties, thermal reliabilities and thermal stabilities of the as-prepared microPCMs were investigated by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The microPCMs prepared by using DVB exhibit greater heat capacities and higher thermal stabilities compared with those prepared by using PETA. The thermal resistant temperature of the microPCM with BMA-DVB polymer was up to 248 Degree-Sign C. The phase change temperatures and latent heats of all the as-prepared microcapsules varied little after 1000 thermal cycles.

  7. Storage temperature affects fruit quality attributes of Ber (Ziziphus ...

    African Journals Online (AJOL)

    STORAGESEVER

    2008-09-03

    Sep 3, 2008 ... Fruit utilization is affected by quality attributes and shelf life. The quality of Jujube or Ber (Ziziphus mauritiana Lamk.) fruits after harvest depends on storage conditions used. In this study, different storage temperatures and durations were evaluated to determine the appropriate storage conditions of.

  8. Investigation of solid nitrogen for cryogenic thermal storage in superconducting cable terminations for enhanced resiliency

    Science.gov (United States)

    Suttell, N.; Zhang, Z.; Kweon, J.; Nes, T.; Kim, C. H.; Pamidi, S.; Ordonez, J. C.

    2017-12-01

    Low heat capacity of helium makes the helium gas cooled high temperature superconducting (HTS) power devices susceptible to large temperature rises during unexpected heat loads such as electrical faults or cryogenic system failures. Cryogenic thermal storage in the form of solid nitrogen designed in the terminations is explored as a means to increase the thermal stability and operational time of HTS power cables in the event of unexpected heat loads. An external tank containing activated charcoal is used as an adsorption buffer tank for nitrogen gas. The use of activated charcoal minimizes the volume of the buffer tank and prevents pressure rises during melting and boiling of the solid nitrogen. Calculations of the cryogenic thermal storage needed and a description of the experimental setup used to understand the design constraints are discussed.

  9. Effects of radiant temperature on thermal comfort

    Energy Technology Data Exchange (ETDEWEB)

    Atmaca, Ibrahim; Kaynakli, Omer; Yigit, Abdulvahap [Uludag University, Bursa (Turkey). Faculty of Engineering and Architecture, Department of Mechanical Engineering

    2007-09-15

    The aim of this paper is to investigate the local differences between body segments caused by high radiant temperature, and to analyze the interior surface temperatures for different wall and ceiling constructions with their effect on thermal comfort. For the segment-wise thermal interactions between human body and its surrounding, simulations have been conducted by appropriately modifying Gagge 2-node model to multi-segment case to demonstrate the local differences. Simulation results are found to be in good agreement with experimental and simulation results reported in the literature. To calculate the interior surface temperatures of the wall and ceiling, the sol-air temperature approach is used for convenience. It is shown in the paper that the body segments close the relatively hot surfaces are more affected than others and interior surface temperatures of un-insulated walls and ceilings exposed to a strong solar radiation reach high levels, all of which cause thermal discomfort for the occupants in buildings. (author)

  10. Modeling Pumped Thermal Energy Storage with Waste Heat Harvesting

    Science.gov (United States)

    Abarr, Miles L. Lindsey

    This work introduces a new concept for a utility scale combined energy storage and generation system. The proposed design utilizes a pumped thermal energy storage (PTES) system, which also utilizes waste heat leaving a natural gas peaker plant. This system creates a low cost utility-scale energy storage system by leveraging this dual-functionality. This dissertation first presents a review of previous work in PTES as well as the details of the proposed integrated bottoming and energy storage system. A time-domain system model was developed in Mathworks R2016a Simscape and Simulink software to analyze this system. Validation of both the fluid state model and the thermal energy storage model are provided. The experimental results showed the average error in cumulative fluid energy between simulation and measurement was +/- 0.3% per hour. Comparison to a Finite Element Analysis (FEA) model showed PTES) that uses ammonia as the working fluid. This analysis focused on the effects of hot thermal storage utilization, system pressure, and evaporator/condenser size on the system performance. This work presents the estimated performance for a proposed baseline Bot-PTES. Results of this analysis showed that all selected parameters had significant effects on efficiency, with the evaporator/condenser size having the largest effect over the selected ranges. Results for the baseline case showed stand-alone energy storage efficiencies between 51 and 66% for varying power levels and charge states, and a stand-alone bottoming efficiency of 24%. The resulting efficiencies for this case were low compared to competing technologies; however, the dual-functionality of the Bot-PTES enables it to have higher capacity factor, leading to 91-197/MWh levelized cost of energy compared to 262-284/MWh for batteries and $172-254/MWh for Compressed Air Energy Storage.

  11. Thermal enhancement of charge and discharge cycles for adsorbed natural gas storage

    KAUST Repository

    Rahman, Kazi Afzalur

    2011-07-01

    The usage of adsorbed natural gas (ANG) storage is hindered by the thermal management during the adsorption and desorption processes. An effective thermal enhancement is thus essential for the development of the ANG technology and the motivation for this study is the investigation of a gas storage system with internal thermal control. We employed a fin-tube type heat exchanger that is placed in a pressurized cylinder. A distributed-parameter model is used for the theoretical modeling and simulations are conducted at assorted charging and discharging conditions. These studies included the transient thermal behaviours of the elements within the ANG-charged cylinder and parameters such as pressure and temperature profiles of adsorbent have been obtained during charge and discharge cycles, and results are compared with a conventional compressed methane vessel. © 2011 Elsevier Ltd. All rights reserved.

  12. A method to determine stratification efficiency of thermal energy storage processes independently from storage heat losses

    DEFF Research Database (Denmark)

    Haller, M.Y.; Yazdanshenas, Eshagh; Andersen, Elsa

    2010-01-01

    A new method for the calculation of a stratification efficiency of thermal energy storages based on the second law of thermodynamics is presented. The biasing influence of heat losses is studied theoretically and experimentally. Theoretically, it does not make a difference if the stratification...... efficiency is calculated based on entropy balances or based on exergy balances. In practice, however, exergy balances are less affected by measurement uncertainties, whereas entropy balances can not be recommended if measurement uncertainties are not corrected in a way that the energy balance of the storage...... directly, and a tank-in-tank system whose outer tank is charged and the inner tank is discharged thereafter. The new method has a great potential for the comparison of the stratification efficiencies of thermal energy storages and storage components such as stratifying devices....

  13. Active thermal isolation for temperature responsive sensors

    Science.gov (United States)

    Martinson, Scott D. (Inventor); Gray, David L. (Inventor); Carraway, Debra L. (Inventor); Reda, Daniel C. (Inventor)

    1994-01-01

    The detection of flow transition between laminar and turbulent flow and of shear stress or skin friction of airfoils is important in basic research for validation of airfoil theory and design. These values are conventionally measured using hot film nickel sensors deposited on a polyimide substrate. The substrate electrically insulates the sensor and underlying airfoil but is prevented from thermally isolating the sensor by thickness constraints necessary to avoid flow contamination. Proposed heating of the model surface is difficult to control, requires significant energy expenditures, and may alter the basic flow state of the airfoil. A temperature responsive sensor is located in the airflow over the specified surface of a body and is maintained at a constant temperature. An active thermal isolator is located between this temperature responsive sensor and the specific surface of the body. The total thickness of the isolator and sensor avoid any contamination of the flow. The temperature of this isolator is controlled to reduce conductive heat flow from the temperature responsive sensor to the body. This temperature control includes (1) operating the isolator at the same temperature as the constant temperature of the sensor; and (2) establishing a fixed boundary temperature which is either less than or equal to, or slightly greater than the sensor constant temperature. The present invention accordingly thermally isolates a temperature responsive sensor in an energy efficient, controllable manner while avoiding any contamination of the flow.

  14. Combination of aquifer thermal energy storage and enhanced bioremediation

    NARCIS (Netherlands)

    Ni, Zhuobiao; Gaans, van Pauline; Rijnaarts, Huub; Grotenhuis, Tim

    2018-01-01

    Interest in the combination concept of aquifer thermal energy storage (ATES) and enhanced bioremediation has recently risen due to the demand for both renewable energy technology and sustainable groundwater management in urban areas. However, the impact of enhanced bioremediation on ATES is not

  15. Life cycle analysis of underground thermal energy storage

    NARCIS (Netherlands)

    Tomasetta, Camilla; van Ree, Derk; Griffioen, Jasper

    2015-01-01

    Underground Thermal Energy Storage (UTES) systems are used to buffer the seasonal difference between heat and cold supply and demand and, therefore, represent an interesting option to conserve energy. Even though UTES are considered environmental friendly solutions they are not completely free of

  16. Central receiver solar thermal power system, Phase 1. CDRL Item 2. Pilot plant preliminary design report. Volume V. Thermal storage subsystem. [Sensible heat storage using Caloria HT43 and mixture of gravel and sand

    Energy Technology Data Exchange (ETDEWEB)

    Hallet, Jr., R. W.; Gervais, R. L.

    1977-10-01

    The proposed 100-MWe Commercial Plant Thermal Storage System (TSS) employs sensible heat storage using dual liquid and solid media for the heat storage in each of four tanks, with the thermocline principle applied to provide high-temperature, extractable energy independent of the total energy stored. The 10-MW Pilot Plant employs a similar system except uses only a single tank. The high-temperature organic fluid Caloria HT43 and a rock mixture of river gravel and No. 6 silica sand were selected for heat storage in both systems. The system design, installation, performance testing, safety characteristics, and specifications are described in detail. (WHK)

  17. Experiences in heat pumps combined with thermal storage for buildings in Japan

    Energy Technology Data Exchange (ETDEWEB)

    Hino, T. [Kajima Technical Research Institute, Tokyo (Japan)

    1996-11-01

    The mechanism, application, and benefits of thermal energy storage in Japan were explored. Thermal energy storage has had a long history in Japan, although ice storage buildings are a more recent innovation. There was evidence in the 1980s of industry reluctance to adopt ice storage, it being regarded as a poor performer, however, in more recent years this appears to be changing towards greater acceptance, driven by the proliferation of office automation machinery in buildings, and a corresponding decrease in heating loads. Various ice storage systems were briefly reviewed. The traditional direct-expansion static-ice system was considered superior to more modern systems because it consumes less energy while making ice, and because thermal resistance can be reduced if thinner tubes are used. Evaporating temperatures not lower than -5 degrees C were observed in a system developed as part of a solar-assisted air source. The coefficient of performance was further improved by decreasing the condensing temperature using ambient-energy radiators. The direct contact ice generator, which has the highest heat transfer without costly ice making heat exchangers, also looks very promising, and is generating considerable interest. 4 refs., 7 figs.

  18. Thermal Analysis of a Thermal Energy Storage Unit to Enhance a Workshop Heating System Driven by Industrial Residual Water

    Directory of Open Access Journals (Sweden)

    Wenqiang Sun

    2017-02-01

    Full Text Available Various energy sources can be used for room heating, among which waste heat utilization has significantly improved in recent years. However, the majority of applicable waste heat resources are high-grade or stable thermal energy, while the low-grade or unstable waste heat resources, especially low-temperature industrial residual water (IRW, are insufficiently used. A thermal energy storage (TES unit with paraffin wax as a phase change material (PCM is designed to solve this problem in a pharmaceutical plant. The mathematical models are developed to simulate the heat storage and release processes of the TES unit. The crucial parameters in the recurrence formulae are determined: the phase change temperature range of the paraffin wax used is 47 to 56 °C, and the latent heat is 171.4 kJ/kg. Several thermal behaviors, such as the changes of melting radius, solidification radius, and fluid temperature, are simulated. In addition, the amount of heat transferred, the heat transfer rate, and the heat storage efficiency are discussed. It is presented that the medicine production unit could save 10.25% of energy consumption in the investigated application.

  19. Effect of different storage temperatures on bacterial spoilage of ...

    African Journals Online (AJOL)

    This study determined the bacterial organisms associated with Oreochromis niloticus spoilage at two storage temperatures (6 and 20°C) and also assessed the ability of the individual bacterial isolates to cause spoilage at the two storage temperatures. Bacteriological analysis revealed the association of five bacteria ...

  20. Thermal conductivity enhancement of phase change materials for thermal energy storage: A review

    Energy Technology Data Exchange (ETDEWEB)

    Fan, Liwu; Khodadadi, J.M. [Department of Mechanical Engineering, Auburn University, 270 Ross Hall, Auburn, AL 36849-5341 (United States)

    2011-01-15

    A review of experimental/computational studies to enhance the thermal conductivity of phase change materials (PCM) that were conducted over many decades is presented. Thermal management of electronics for aeronautics and space exploration appears to be the original intended application, with later extension to storage of thermal energy for solar thermal applications. The present review will focus on studies that concern with positioning of fixed, stationary high conductivity inserts/structures. Copper, aluminum, nickel, stainless steel and carbon fiber in various forms (fins, honeycomb, wool, brush, etc.) were generally utilized as the materials of the thermal conductivity promoters. The reviewed research studies covered a variety of PCM, operating conditions, heat exchange and thermal energy storage arrangements. The energy storage vessels included isolated thermal storage units (rectangular boxes, cylindrical and annular tubes and spheres) and containers that transferred heat to a moving fluid medium passing through it. A few studies have focused on the marked role of flow regimes that are formed due to the presence of thermally unstable fluid layers that in turn give rise to greater convective mixing and thus expedited melting of PCM. In general, it can be stated that due to utilization of fixed high conductivity inserts/structures, the conducting pathways linking the hot and cold ends must be minimized. (author)

  1. Thermal management technology for hydrogen storage: Fullerene option

    Energy Technology Data Exchange (ETDEWEB)

    Wang, J.C.; Chen, F.C.; Murphy, R.W. [Oak Ridge National Lab., TN (United States)

    1996-10-01

    Fullerenes are selected as the first option for investigating advanced thermal management technologies for hydrogen storage because of their potentially high volumetric and gravimetric densities. Experimental results indicate that about 6 wt% of hydrogen (corresponding to C{sub 60}H{sub 48}) can be added to and taken out of fullerenes. A model assuming thermally activated hydrogenation and dehydrogenation processes was developed to explain the experimental findings. The activation energies were estimated to be 100 and 160 kJ/mole (1.0 and 1.6 eV/H{sub 2}) for the hydrogenation and dehydrogenation processes, respectively. The difference is interpreted as the heat released during hydrogenation. There are indications that the activation energies and the heat of hydrogenation can be modified by the use of catalysts. Preliminary hydrogen storage simulations for a conceptually simple device were performed. A 1-m long hollow metal cylinder with an inner diameter of 0.02 m was assumed to be filled with fullerene powders. The results indicate that the thermal diffusivity of the fullerenes controls the hydrogenation and dehydrogenation rates. The rates can be significantly modified by changing the thermal diffusivity of the material inside the cylinder, e.g., by incorporating a metal mesh. Results from the simulation suggest that thermal management is essential for efficient hydrogen storage devices using fullerenes. While the preliminary models developed in this study explain some of the observation, more controlled experiments, rigorous model development, and physical property determinations are needed for the development of practical hydrogen storage devices. The use of catalysts to optimize the hydrogen storage characteristics of fullerenes also needs to be pursued. Future cooperative work between Oak Ridge National Laboratory (ORNL) and Material & Electrochemical Research Corporation (MER) is planned to address these needs.

  2. Summary Report for Concentrating Solar Power Thermal Storage Workshop: New Concepts and Materials for Thermal Energy Storage and Heat-Transfer Fluids, May 20, 2011

    Energy Technology Data Exchange (ETDEWEB)

    Glatzmaier, G.

    2011-08-01

    This document summarizes a workshop on thermal energy storage for concentrating solar power (CSP) that was held in Golden, Colorado, on May 20, 2011. The event was hosted by the U.S. Department of Energy (DOE), the National Renewable Energy Laboratory, and Sandia National Laboratories. The objective was to engage the university and laboratory research communities to identify and define research directions for developing new high-temperature materials and systems that advance thermal energy storage for CSP technologies. This workshop was motivated, in part, by the DOE SunShot Initiative, which sets a very aggressive cost goal for CSP technologies -- a levelized cost of energy of 6 cents per kilowatt-hour by 2020 with no incentives or credits.

  3. Temperature distributions in trapezoidal built in storage solar water heaters with/without phase change materials

    Energy Technology Data Exchange (ETDEWEB)

    Tarhan, Sefa; Yardim, M. Hakan [Department of Farm Machinery, Faculty of Agriculture, Gaziosmanpasa University, Tasliciftlik Yerleskesi, 60240 Tokat (Turkey); Sari, Ahmet [Department of Chemistry, Faculty of Arts and Sciences, Gaziosmanpasa University, Tasliciftlik Yerleskesi, 60240 Tokat (Turkey)

    2006-09-15

    Built in storage solar water heaters (BSSWHs) have been recognized for their more compact constructions and faster solar gain than conventional solar water heaters, however, their water temperatures quickly go down during the cooling period. A trapezoidal BSSWH without PCM storage unit was used as the control heater (reference) to investigate the effect of two differently configured PCM storage units on the temperature distributions in water tanks. In the first design, myristic acid was filled into the PCM storage tank, which also served as an absorbing plate. In the second design, lauric acid was filled into the PCM storage tank, which also served as a baffle plate. The water temperature changes were followed by five thermocouples placed evenly and longitudinally into each of the three BSSWHs. The effects of the PCMs on the water temperature distributions depended on the configuration of the PCM storage unit and the longitudinal position in the water tanks. The use of lauric acid lowered the values of the peak temperatures by 15% compared to the control heater at the upper portion of the water tanks because of the low melting temperature of lauric acid, but it did not have any consistent effect on the retention of the water temperatures during the cooling period. The ability of the myristic acid storage unit to retain the water temperatures got more remarkable, especially at the middle portion of the water tank. The myristic acid storage increased the dip temperatures by approximately 8.8% compared to the control heater. In conclusion, lauric acid storage can be used to stabilize the water temperature during the day time, while the myristic acid storage unit can be used as a thermal barrier against heat loss during the night time because of its relatively high melting temperature and low heat conduction coefficient in its solid phase. The experimental results have also indicated that the thermal characteristics of the PCM and the configuration of the PCM storage

  4. Design and installation manual for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Cole, R L; Nield, K J; Rohde, R R; Wolosewicz, R M

    1980-01-01

    The purpose of this manual is to provide information on the design and installation of thermal energy storage in active solar systems. It is intended for contractors, installers, solar system designers, engineers, architects, and manufacturers who intend to enter the solar energy business. The reader should have general knowledge of how solar heating and cooling systems operate and knowledge of construction methods and building codes. Knowledge of solar analysis methods such as f-Chart, SOLCOST, DOE-1, or TRNSYS would be helpful. The information contained in the manual includes sizing storage, choosing a location for the storage device, and insulation requirements. Both air-based and liquid-based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to latent heat storage include properties of phase-change materials, sizing the storage unit, insulating the storage unit, available systems, and cost. Topics relevant to heating domestic water include safety, single- and dual-tank systems, domestic water heating with air- and liquid-based space heating systems, and stand alone domestics hot water systems. Several appendices present common problems with storage systems and their solutions, heat transfer fluid properties, economic insulation thickness, heat exchanger sizing, and sample specifications for heat exchangers, wooden rock bins, steel tanks, concrete tanks, and fiberglass-reinforced plastic tanks.

  5. Basic Considerations for Dry Storage of Spent Nuclear Fuels and Revisited CFD Thermal Analysis on the Concrete Cask

    Energy Technology Data Exchange (ETDEWEB)

    Noh, Jae Soo [ACT Co. Ltd., Daejeon (Korea, Republic of); Park, Younwon; Song, Sub Lee [BEES Inc., Daejeon (Korea, Republic of); Kim, Hyeun Min [KAIST, Daejeon (Korea, Republic of)

    2016-10-15

    The integrity of storage facility and also of the spent nuclear fuel itself is considered very important. Storage casks can be located in a designated area on a site or in a designated storage building. A number of different designs for dry storage have been developed and used in different countries. Dry storage system was classified into two categories by IAEA. One is container including cask and silo, the other one is vault. However, there is various way of categorization for dry storage system. Dry silo and cask are usually classified separately, so the dry storage system can be classified into three different types. Furthermore, dry cask storage can be categorized into two types based on the type of the materials, concrete cask and metal cask. In this paper, the design characteristics of dry storage cask are introduced and computational fluid dynamics (CFD) based thermal analysis for concrete cask is revisited. Basic principles for dry storage cask design were described. Based on that, thermal analysis of concrete dry cask was introduced from the study of H. M. Kim et al. From the CFD calculation, the temperature of concrete wall was maintained under the safety criteria. From this fundamental analysis, further investigations are expected. For example, thermal analysis on the metal cask, thermal analysis on horizontally laid spent nuclear fuel assemblies for transportation concerns, and investigations on better performance of natural air circulation in dry cask can be promising candidates.

  6. Improved Thermal-Insulation Systems for Low Temperatures

    Science.gov (United States)

    Fesmire, James E.; Augustynowicz, Stanislaw D.

    2003-01-01

    Improved thermal-insulation materials and structures and the techniques for manufacturing them are undergoing development for use in low-temperature applications. Examples of low-temperature equipment for which these thermal insulation systems could provide improved energy efficiency include storage tanks for cryogens, superconducting electric-power-transmission equipment, containers for transport of food and other perishable commodities, and cold boxes for low-temperature industrial processes. These systems could also be used to insulate piping used to transfer cryogens and other fluids, such as liquefied natural gas, refrigerants, chilled water, crude oil, or low-pressure steam. The present thermal-insulation systems are layer composites based partly on the older class of thermal-insulation systems denoted generally as multilayer insulation (MLI). A typical MLI structure includes an evacuated jacket, within which many layers of radiation shields are stacked or wrapped close together. Low-thermal-conductivity spacers are typically placed between the reflection layers to keep them from touching. MLI can work very well when a high vacuum level (less than 10(exp-4) torr) is maintained and utmost care is taken during installation, but its thermal performance deteriorates sharply as the pressure in the evacuated space rises into the soft vacuum range [pressures greater than 0.1 torr (greater than 13 Pa)]. In addition, the thermal performance of MLI is extremely sensitive to mechanical compression and edge effects and can easily decrease from one to two orders of magnitude from its ideal value even when the MLI is kept under high vacuum condition. The present thermal-insulation systems are designed to perform well under soft vacuum level, in particular the range of 1 to 10 torr. They are also designed with larger interlayer spacings to reduce vulnerability to compression (and consequent heat leak) caused by installation and use. The superiority of these systems is the

  7. Thermal reservoir sizing for adiabatic compressed air energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Kere, Amelie; Goetz, Vincent; Py, Xavier; Olives, Regis; Sadiki, Najim [Perpignan Univ. (France). PROMES CNRS UPR 8521; Mercier-Allart, Eric [EDF R et D, Chatou (France)

    2012-07-01

    Despite the operation of the two existing industrial facilities to McIntosh (Alabama), and for more than thirty years, Huntorf (Germany), electricity storage in the form of compressed air in underground cavern (CAES) has not seen the development that was expected in the 80s. The efficiency of this form of storage was with the first generation CAES, less than 50%. The evolving context technique can significantly alter this situation. The new generation so-called Adiabatic CAES (A-CAES) is to retrieve the heat produced by the compression via thermal storage, thus eliminating the necessity of gas to burn and would allow consideration efficiency overall energy of the order of 70%. To date, there is no existing installation of A-CAES. Many studies describe the principal and the general working mode of storage systems by adiabatic compression of air. So, efficiencies of different configurations of adiabatic compression process were analyzed. The aim of this paper is to simulate and analyze the performances of a thermal storage reservoir integrated in the system and adapted to the working conditions of a CAES.

  8. High temperature active heat exchanger research for latent heat storage

    Science.gov (United States)

    Alario, J.; Haslett, R.

    1982-02-01

    An active heat exchange method in a latent heat (salt) thermal energy storage system that prevents a low conductivity solid salt layer from forming on heat transfer surfaces was developed. An evaluation of suitable media with melting points in the temperature range of interest (250 to 400 C) limited the candidates to molten salts from the chloride, hydroxide and nitrate families, based on high storage capacity, good corrosion characteristics and availability in large quantities at reasonable cost. The specific salt recommended for laboratory tests was a choride eutectic (20.5KCL o 24.5NaCL o 55.MgCl2% by wt.), with a nominal melting point of 385 C. Various active heat exchange concepts were given a technical and economic comparison to a passive tube shell design for a reference application (300 MW sub t for 6 hours). Test hardware was then built for the most promising concept: a direct contact heat exchanger in which molten salt droplets are injected into a cooler counter flowing stream of liquid metal carrier fluid (lead/Bismuth).

  9. Performance of Portable Ventilators Following Storage at Temperature Extremes.

    Science.gov (United States)

    Blakeman, Thomas C; Rodriquez, Dario; Britton, Tyler J; Johannigman, Jay A; Petro, Michael C; Branson, Richard D

    2016-05-01

    In the current theater of operation, medical devices are often shipped and stored at ambient conditions. The effect of storage at hot and cold temperature extremes on ventilator performance is unknown. We evaluated three portable ventilators currently in use or being evaluated for use by the Department of Defense (731, Impact Instrumentation; T1, Hamilton Medical; and Revel, CareFusion) at temperature extremes in a laboratory setting. The ventilators were stored at temperatures of 60°C and -35°C for 24 hours and were allowed to acclimate to room temperature for 30 minutes before evaluation. The T1 required an extra 15 to 30 minutes of acclimation to room temperature before the ventilator would deliver breaths. All delivered tidal volumes at room temperature and after storage at temperature extremes were less than the ±10% American Society for Testing and Materials standard with the Revel. Delivered tidal volumes at the pediatric settings were less than the ±10% threshold after storage at both temperatures and at room temperature with the 731. Storage at extreme temperature affected the performance of the portable ventilators tested. This study showed that portable ventilators may need an hour or more of acclimation time at room temperature after storage at temperature extremes to operate as intended. Reprint & Copyright © 2016 Association of Military Surgeons of the U.S.

  10. Simulation of thermal effects during high and low frequency gas storage operations in porous formations

    Science.gov (United States)

    Tilmann Pfeiffer, Wolf; Wang, Bo; Bauer, Sebastian

    2017-04-01

    Increasing the share of energy production from renewable sources will result in shortages in power supply on various timescales and magnitudes. Besides other options, porous media storage of chemical energy in the form of gases such as hydrogen (H2) or synthetic methane (CH4) as well as mechanical energy, i.e. in the form of a compressed air energy storage (CAES) could be employed to mitigate such shortages. A key difference between these storage options are the potential storage operation schemes in which they are used as a result of the different effective energy density in the subsurface. While CAES would most likely be employed in a high flow rate, high frequency storage scheme with daily cycles, H2 and CH4 storage sites are also suitable for longer, up to seasonal, withdrawal cycles with a lower periodicity. The aim of this work is to compare different thermal effects as a result of H2, CH4, and compressed air energy storage operations. Besides advective-conductive heat transport in the fluid and solid phases, also the Joule-Thomson effect as a result of gas flow through the porous formation is analysed for the different storage options. For this the Joule-Thomson effect is implemented in the open source simulation software OpenGeoSys and numerical simulations of the different storage options are performed. For the simulations, synthetic but realistically parameterized storage sites are used. Besides using OpenGeoSys, the simulations are also compared to results obtained with the ECLIPSE reservoir simulator (© Schlumberger). The simulations show that the heat introduced into the system by the gas injections is transported away from the injection wells mainly through heat conduction. Thus, the thermal perturbation is also present in the caprocks above and below the storage formation. Because of the low heat capacity of the injected gas, thermal effects are confined to the near well region. Temperature changes of more than 1 K are thus found within the first

  11. Spatial and temporal modeling of sub- and supercritical thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Tse, LA; Ganapathi, GB; Wirz, RE; Lavine, AS

    2014-05-01

    This paper describes a thermodynamic model that simulates the discharge cycle of a single-tank thermal energy storage (TES) system that can operate from the two-phase (liquid-vapor) to supercritical regimes for storage fluid temperatures typical of concentrating solar power plants. State-of-the-art TES design utilizes a two-tank system with molten nitrate salts; one major problem is the high capital cost of the salts (International Renewable Energy Agency, 2012). The alternate approach explored here opens up the use of low-cost fluids by considering operation at higher pressures associated with the two-phase and supercritical regimes. The main challenge to such a system is its high pressures and temperatures which necessitate a relatively high-cost containment vessel that represents a large fraction of the system capital cost. To mitigate this cost, the proposed design utilizes a single-tank TES system, effectively halving the required wall material. A single-tank approach also significantly reduces the complexity of the system in comparison to the two-tank systems, which require expensive pumps and external heat exchangers. A thermodynamic model is used to evaluate system performance; in particular it predicts the volume of tank wall material needed to encapsulate the storage fluid. The transient temperature of the tank is observed to remain hottest at the storage tank exit, which is beneficial to system operation. It is also shown that there is an optimum storage fluid loading that generates a given turbine energy output while minimizing the required tank wall material. Overall, this study explores opportunities to further improve current solar thermal technologies. The proposed single-tank system shows promise for decreasing the cost of thermal energy storage. (C) 2014 Elsevier Ltd. All rights reserved.

  12. Thermal Stratification in Small Solar Domestic Storage Tanks caused by Draw-offs

    DEFF Research Database (Denmark)

    Jordan, Ulrike; Furbo, Simon

    2005-01-01

    in the storage tank. Furthermore, for theoretical investigations of the flow patterns in the storage tank, calculations were carried out by means of the Computational Fluid Dynamics (CFD) tool Fluent. Based on the experimental and theoretical results, the sizes of fully mixed zones in the bottom part...... behaviour is not taken into account sufficiently. Two typical Danish domestic water storage tanks, each with a volume of about 150 l, were investigated. In both tanks the inlet pipes are placed at the bottom and hot water is drawn from the upper part of tank. Above the inlet pipes, differently shaped plates...... are placed in order to reduce the mixing of the incoming cold water with the warmer storage water. To measure the thermal stratification thermocouples were placed in a vertical glass tube inside the tank. Measurements were carried out with different draw-off volumes, flow rates, and initial temperatures...

  13. THERMAL STRATIFICATION IN SOLAR DOMESTIC STORAGE TANKS CAUSED BY DRAW-OFFS

    DEFF Research Database (Denmark)

    Jordan, Ulrike; Furbo, Simon

    2003-01-01

    in the storage tank. Furthermore, for theoretical investigations of the flow patterns in the storage tank, calculations were carried out by means of the Computational Fluid Dynamics (CFD) tool Fluent. Based on the experimental and theoretical results, the sizes of fully mixed zones in the bottom part...... behaviour is not taken into account sufficiently. Two typical Danish domestic water storage tanks, each with a volume of about 150 l, were investigated. In both tanks the inlet pipes are placed at the bottom and hot water is drawn from the upper part of tank. Above the inlet pipes, differently shaped plates...... are placed in order to reduce the mixing of the incoming cold water with the warmer storage water. To measure the thermal stratification thermocouples were placed in a vertical glass tube inside the tank. Measurements were carried out with different draw-off volumes, flow rates, and initial temperatures...

  14. Advanced concepts in ground thermal energy storage systems

    Science.gov (United States)

    Woods, Kevin David

    In recent years, ground thermal energy storage has become a topic of interest in the energy community for solar thermal energy storage systems, ground sourced heat pump systems, and data center thermal management systems due to an increase in the energy efficiency of such systems utilizing the ground as a thermal reservoir. The most common method for transferring thermal energy to the ground formation is the geothermal borehole. This dissertation presents the state of the art in geothermal borehole modeling and derives novel analytical functions to model advanced concepts concerning their operation. The novel solutions derived allow a geothermal borehole designer to better understand and design ground energy storage systems. The state of the art in geothermal borehole modeling is the stationary line source solution which is limited to boreholes operating without groundwater flow. Novel solutions for modeling a geothermal borehole with groundwater advection are presented through derivation of a transient moving line source solution as well as a transient moving cylindrical surface source solution. These solutions are applied to model a specific type of open loop geothermal borehole called a standing column well with groundwater advection and are compared to empirical and numerical data for validation. The dissertation then moves into derivation of a property determination method for geothermal boreholes with groundwater advection. The traditional property determination method used to obtain ground formation properties is based on the stationary transient line source method and fails in the presence of groundwater flow. The proposed novel property determination method calculates the thermal conductivity, thermal diffusivity, and superficial flow velocity of groundwater within a ground formation. These methods and solutions are novel tools allowing for geothermal borehole designers to grasp a better understanding of the systems they are designing as well as open other

  15. Nanoparticles for heat transfer and thermal energy storage

    Science.gov (United States)

    Singh, Dileep; Cingarapu, Sreeram; Timofeeva, Elena V.; Moravek, Michael

    2015-07-14

    An article of manufacture and method of preparation thereof. The article of manufacture and method of making the article includes an eutectic salt solution suspensions and a plurality of nanocrystalline phase change material particles having a coating disposed thereon and the particles capable of undergoing the phase change which provides increase in thermal energy storage. In addition, other articles of manufacture can include a nanofluid additive comprised of nanometer-sized particles consisting of copper decorated graphene particles that provide advanced thermal conductivity to heat transfer fluids.

  16. Residential thermal storage by water encapsulation in stud wall cavities

    Energy Technology Data Exchange (ETDEWEB)

    Turner, R.H.; Harris, G.P.; Kiley, M.N.; Cengel, Y.A. (Univ. of Nevada, Reno, NV (United States). Dept. of Mechanical Engineering)

    1992-01-01

    Thermal storage in wall cavities of standard stick frame housing was investigated. Possible applications relate to electric utility time of use charging, or solar hot air charging. Various thermal storage methods were surveyed, and water stored in the stud cavities was selected. Air was used to charge the encapsulated water. Exterior and interior walls were investigated. Experimental tests were run on full size wall cavities, for both heating and cooling runs. Experimental results were compared and validated with a mathematical model predicting the system performance. Results show that the rate of heat lost by the system while charging is greater than while discharging. The exterior walls performed best in terms of speed of charging, and the maximum charge held. The best charging efficiency was achieved for the lowest air flow rate while charging. Universal curves that describe the basic system responses were developed.

  17. Study on effectiveness of continuous solar dryer integrated with desiccant thermal storage for drying cocoa beans

    OpenAIRE

    Dina, Sari Farah; Ambarita, Himsar; Farel H. Napitupulu; Kawai, Hideki

    2015-01-01

    The main objective is to assess effectiveness of continuous solar dryer integrated with desiccant thermal storage for drying cocoa beans. Two type of desiccants were tested, molecular sieve 13× (Na86 [(AlO2)86·(SiO2)106]·264H2O) as an adsorbent type and CaCl2 as an absorbent type. The results revealed that during sunshine hours, the maximum temperature within the drying chamber varied from 40 °C to 54 °C. In average, it was 9–12 °C higher than ambient temperature. These temperatures are very ...

  18. From Molecular Electronics to Solar Thermal Energy Storage

    DEFF Research Database (Denmark)

    Olsen, Stine Tetzschner

    The Sun's signicant resource potential provides a solution for the world's increasing energy demand in a sustainable and responsible manner. However, the intrinsic property of the on-o cycles of the solar irradiation, i.e. daynight, sunny-cloudy, and summer-winter, constitutes a signicant challenge...... for the utilization of solar energy. An eective technology for storing the solar energy is required. This thesis focuses on solar thermal energy storage in molecules, since it oers a very compact and eective storage method. The rst chapter after the introduction of the thesis, chapter two, introduces the fundamental...... properties of the molecule, i.e. the electronic behaviour of the molecule in dierent environments, which is a key property for investigations of solar energy storage. The main focus of the research is on the electron transport in the Coulomb blockade regime. The third chapter goes into the challenge...

  19. Coupling Geothermal Heat Pumps with Underground Seasonal Thermal Energy Storage

    Science.gov (United States)

    2017-03-21

    United States (US). It also created the US’s only known active “full” ( warm and cold) Aquifer Thermal Energy Storage (ATES) system. This...systems in the U.S. are not designed to achieve. Deliberately engineered UTES systems not only allow for the waste heat of cooling systems and the...Ingenieure (Largest Engineering Association in Western Europe) VAV Variable Air Volume vii Page Intentionally Left

  20. Performance maps for the control of thermal energy storage

    DEFF Research Database (Denmark)

    Finck, Christian; Li, Rongling; Zeiler, Wim

    2017-01-01

    Predictive control in building energy systems requires the integration of the building, building system, and component dynamics. The prediction accuracy of these dynamics is crucial for practical applications. This paper introduces performance maps for the control of water tanks, phase change...... material tanks, and thermochemical material tanks. The results show that these performance maps can fully account for the dynamics of thermal energy storage tanks....

  1. Assessment of cool thermal storage strategies in Kuwait

    OpenAIRE

    Sebzali, Mohamed

    2006-01-01

    The extensive use of air conditioning for indoor cooling in offices and large commercial buildings in Kuwait represents a major part of the power and electricity consumption in that country. The main objective of this research was to investigate ice and chilled water cool thermal storage technologies and operating strategies for air conditioning. This was motivated by the extreme climatic conditions in Kuwait and the necessity to reduce both maximum power demand and energy cons...

  2. Initial Investigation of a Novel Thermal Storage Concept as Part of a Renewable Energy System

    Science.gov (United States)

    2013-06-01

    Thickness (m) Heat Generation Rate (w/m3) Materia 1 Name Thermal BC Type Temperature (k) Heat Flux (w/m2) report Convective Heat Transfer ...The ice storage makes the system grid-independent, and in addition, commercial chillers can be readily purchased, transferred to, and set up in...thickness affected the solidification process. A secondary goal was to use the heat transfer rate and the solidification rate of ice to determine

  3. Development of Hollow Steel Ball Macro-Encapsulated PCM for Thermal Energy Storage Concrete

    OpenAIRE

    Zhijun Dong; Hongzhi Cui; Waiching Tang; Dazhu Chen; Haibo Wen

    2016-01-01

    The application of thermal energy storage with phase change materials (PCMs) for energy efficiency of buildings grew rapidly in the last few years. In this research, octadecane paraffin was served as a PCM, and a structural concrete with the function of indoor temperature control was developed by using a macro-encapsulated PCM hollow steel ball (HSB). The macro-encapsulated PCM-HSB was prepared by incorporation of octadecane into HSBs through vacuum impregnation. Test results showed that the ...

  4. Microencapsulated n-octacosane as phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ahmet; Alkan, Cemil; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey); Uzun, Orhan [Department of Physics, Gaziosmanpasa University, 60240 Tokat (Turkey)

    2009-10-15

    This study deals with preparation and characterization of polymethylmetracrylate (PMMA) microcapsules containing n-octacosane as phase change material for thermal energy storage. The surface morphology, particle size and particle size distribution (PSD) were studied by scanning electron microscopy (SEM). The chemical characterization of PMMA/octacosane microcapsules was made by FT-IR spectroscopy method. Thermal properties and thermal stability of microencapsulated octacosane were determined using differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). The melting and freezing temperatures and the latent heats of the microencapsulated octacosane as PCM were measured as 50.6 and 53.2 C, 86.4 and -88.5 J/g, respectively, by DSC analysis. TGA analysis indicated that the microencapsulated octacosane degrade in two steps and had good chemical stability. Thermal cycling test shows that the microcapsules have good thermal reliability with respect to the accelerated thermal cycling. Based on the results, it can be considered that the microencapsulated octacosane have good energy storage potential. (author)

  5. Enhanced mechanical, thermal, and electric properties of graphene aerogels via supercritical ethanol drying and high-temperature thermal reduction.

    Science.gov (United States)

    Cheng, Yehong; Zhou, Shanbao; Hu, Ping; Zhao, Guangdong; Li, Yongxia; Zhang, Xinghong; Han, Wenbo

    2017-05-03

    Graphene aerogels with high surface areas, ultra-low densities and thermal conductivities have been prepared to exploit their wide applications from pollution adsorption to energy storage, supercapacitor, and thermal insulation. However, the low mechanical properties, poor thermal stability and electric conductivity restrict these aerogels' applications. In this paper, we prepared mechanically strong graphene aerogels with large BET surface areas, low thermal conductivities, high thermal stability and electric conductivities via hydrothermal reduction and supercritical ethanol drying. Annealing at 1500 °C resulted in slightly increased thermal conductivity and further improvement in mechanical properties, oxidation temperature and electric conductivity of the graphene aerogel. The large BET surface areas, together with strong mechanical properties, low thermal conductivities, high thermal stability and electrical conductivities made these graphene aerogels feasible candidates for use in a number of fields covering from batteries to sensors, electrodes, lightweight conductor and insulation materials.

  6. Electrothermal efficiency, temperature and thermal conductivity of ...

    Indian Academy of Sciences (India)

    A study was made to evaluate the electrothermal efficiency of a DC arc plasma torch and temperature and thermal conductivity of plasma jet in the torch. The torch was operated at power levels from 4 to 20 kW in non-transferred arc mode. The effect of nitrogen in combination with argon as plasma gas on the above ...

  7. Electrothermal efficiency, temperature and thermal conductivity of ...

    Indian Academy of Sciences (India)

    Abstract. A study was made to evaluate the electrothermal efficiency of a DC arc plasma torch and temperature and thermal conductivity of plasma jet in the torch. The torch was operated at power levels from 4 to 20 kW in non-transferred arc mode. The effect of nitrogen in combination with argon as plasma gas on the above ...

  8. Effect of cold temperature storage on the quality attributes of ...

    African Journals Online (AJOL)

    The effect of cold temperature storage on the quality attributes of pawpaw and guava leathers was evaluated. Pawpaw leather was significantly higher than guava leather in calorific content, water activity, pH and total mould count throughout the duration of storage. However Guava leather was higher in texture. Sensory ...

  9. Design and Thermal Analysis of a Solar Powered Cold Storage ...

    African Journals Online (AJOL)

    The paper considers the storage of 1000 kg of oranges at a temperature conservation of 1oC with a requirement of 85% to 90% and air circulation velocity of' 0.3 m/s in the Ware house. Based on the temperature of utilisation, the paper discusses the physiro-chemical problems inherent with a phase change material for a ...

  10. Study on effectiveness of continuous solar dryer integrated with desiccant thermal storage for drying cocoa beans

    Directory of Open Access Journals (Sweden)

    Sari Farah Dina

    2015-03-01

    Full Text Available The main objective is to assess effectiveness of continuous solar dryer integrated with desiccant thermal storage for drying cocoa beans. Two type of desiccants were tested, molecular sieve 13× (Na86 [(AlO286·(SiO2106]·264H2O as an adsorbent type and CaCl2 as an absorbent type. The results revealed that during sunshine hours, the maximum temperature within the drying chamber varied from 40 °C to 54 °C. In average, it was 9–12 °C higher than ambient temperature. These temperatures are very suitable for drying cocoa beans. During off-sunshine hours, humidity of air inside the drying chamber was lower than ambient because of the desiccant thermal storage. Drying times for intermittent directs sun drying, solar dryer integrated with adsorbent, and solar dryer integrated with absorbent were 55 h, 41 h, and 30 h, respectively. Specific energy consumptions for direct sun drying, solar dryer integrated with adsorbent, and solar dryer integrated with absorber were 60.4 MJ/kg moist, 18.94 MJ/kg moist, and 13.29 MJ/kg moist, respectively. The main conclusion can be drawn here is that a solar dryer integrated with desiccant thermal storage makes drying using solar energy more effective in term of drying time and specific energy consumption.

  11. Novel Molten Salts Thermal Energy Storage for Concentrating Solar Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Reddy, Ramana G. [Univ. of Alabama, Tuscaloosa, AL (United States)

    2013-10-23

    The explicit UA program objective is to develop low melting point (LMP) molten salt thermal energy storage media with high thermal energy storage density for sensible heat storage systems. The novel Low Melting Point (LMP) molten salts are targeted to have the following characteristics: 1. Lower melting point (MP) compared to current salts (<222ºC) 2. Higher energy density compared to current salts (>300 MJ/m3) 3. Lower power generation cost compared to current salt In terms of lower power costs, the program target the DOE's Solar Energy Technologies Program year 2020 goal to create systems that have the potential to reduce the cost of Thermal Energy Storage (TES) to less than $15/kWh-th and achieve round trip efficiencies greater than 93%. The project has completed the experimental investigations to determine the thermo-physical, long term thermal stability properties of the LMP molten salts and also corrosion studies of stainless steel in the candidate LMP molten salts. Heat transfer and fluid dynamics modeling have been conducted to identify heat transfer geometry and relative costs for TES systems that would utilize the primary LMP molten salt candidates. The project also proposes heat transfer geometry with relevant modifications to suit the usage of our molten salts as thermal energy storage and heat transfer fluids. The essential properties of the down-selected novel LMP molten salts to be considered for thermal storage in solar energy applications were experimentally determined, including melting point, heat capacity, thermal stability, density, viscosity, thermal conductivity, vapor pressure, and corrosion resistance of SS 316. The thermodynamic modeling was conducted to determine potential high temperature stable molten salt mixtures that have thermal stability up to 1000 °C. The thermo-physical properties of select potential high temperature stable (HMP) molten salt mixtures were also experimentally determined. All the salt mixtures align with the

  12. Effects of storage temperature and extension media on motility of ...

    African Journals Online (AJOL)

    ADEYEYE

    2016-07-26

    Jul 26, 2016 ... Keywords: Egg-yolk citrate, Goat-milk citrate, Motility, Semen ... milk, skin and other products), has been adjudged ... detrimental effect on sperm cells (Purdy, 2006). ... motility at two different storage temperature in an.

  13. Application of nanomaterials in solar thermal energy storage

    Science.gov (United States)

    Shamshirgaran, Seyed Reza; Khalaji Assadi, Morteza; Viswanatha Sharma, Korada

    2017-12-01

    Solar thermal conversion technology harvests the sun's energy, rather than fossil fuels, to generate low-cost, low/zero-emission energy in the form of heating, cooling or electrical form for residential, commercial, and industrial sectors. The advent of nanofluids and nanocomposites or phase change materials, is a new field of study which is adapted to enhance the efficiency of solar collectors. The concepts of thermal energy storage technologies are investigated and the role of nanomaterials in energy conversion is discussed. This review revealed that although the exploitation of nanomaterials will boost the performance of solar collectors almost in all cases, this would be accompanied by certain challenges such as production cost, instability, agglomeration and erosion. Earlier studies have dealt with the enhancement of thermal conductivity and heat capacity; however, less attention has been given to the facing challenges. Moreover, no exact criteria can be found for the selection of appropriate nanomaterials and their properties for a specific application. In most research studies, the nanoparticles' material and properties have not been selected based on estimated values so that all the aspects of desired application could be considered simultaneously. The wide spread use of nanomaterials can lead to cost effective solutions as well. Therefore, it seems there should be a sense of techno-economic optimization in exploiting nanomaterials for solar thermal energy storage applications. The optimization should cover the key parameters, particularly nanoparticle type, size, loading and shape which depends on the sort of application and also dispersion technology.

  14. Quality of Cultured Wader Pari During Storage at Different Temperature

    OpenAIRE

    Almira Islamei Pratiwi; Amir Husni; Siti Ari Budhiyanti; Bambang Retno Aji

    2017-01-01

    Rasbora lateristriata is one Indonesian freshwater fish consumed by society as a source of animal protein. Like fish in general, rasbora is considered as perishable food, so it is necessary to apply a proper storage technique, one of which is cold storage. The purpose of this study was to determine the proper storage temperature of the rasbora in the storage of freezer, chiller and ice. The raw materials used was rasbora in size of 2 grams/fish. The Wader was caught then pondered (2,1 kg). Ra...

  15. PHASE CHANGE MATERIALS IN FLOOR TILES FOR THERMAL ENERGY STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Douglas C. Hittle

    2002-10-01

    Passive solar systems integrated into residential structures significantly reduce heating energy consumption. Taking advantage of latent heat storage has further increased energy savings. This is accomplished by the incorporation of phase change materials into building materials used in passive applications. Trombe walls, ceilings and floors can all be enhanced with phase change materials. Increasing the thermal storage of floor tile by the addition of encapsulated paraffin wax is the proposed topic of research. Latent heat storage of a phase change material (PCM) is obtained during a change in phase. Typical materials use the latent heat released when the material changes from a liquid to a solid. Paraffin wax and salt hydrates are examples of such materials. Other PCMs that have been recently investigated undergo a phase transition from one solid form to another. During this process they will release heat. These are known as solid-state phase change materials. All have large latent heats, which makes them ideal for passive solar applications. Easy incorporation into various building materials is must for these materials. This proposal will address the advantages and disadvantages of using these materials in floor tile. Prototype tile will be made from a mixture of quartz, binder and phase change material. The thermal and structural properties of the prototype tiles will be tested fully. It is expected that with the addition of the phase change material the structural properties will be compromised to some extent. The ratio of phase change material in the tile will have to be varied to determine the best mixture to provide significant thermal storage, while maintaining structural properties that meet the industry standards for floor tile.

  16. High efficiency thermal storage system for solar plants (HELSOLAR). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Villarroel, Eduardo; Fernandez-Pello, Carlos; Lenartz, Jeff; Parysek, Karen

    2013-02-27

    The project objective was to develop a high temperature Thermal Storage System (TES) based on graphite and able to provide both economical and technical advantages with respect to existing solutions contributing to increase the share of Concentrated Solar Plants (CSP). One of the main disadvantages of most of the renewable energy systems is their dependence to instantaneous irradiation and, thus, lack of predictability. CSP plants with thermal storage have proved to offer a good solution to this problem although still at an elevated price. The identification of alternative concepts able to work more efficiently would help to speed up the convergence of CSP towards grid parity. One way to reduce costs is to work in a range of temperatures higher than those allowed by the actual molten salt systems, currently the benchmark for TES in CSP. This requires the use of alternative energy storage materials such as graphite, as well as the utilization of Heat Transfer Fluids (HTF) other than molten salts or organic oils. The main technical challenges identified are derived from the high temperatures and significant high pressures, which pose risks such as potential graphite and insulation oxidation, creep, fatigue, corrosion and stress-corrosion in the pipes, leakages in the joints, high blower drivers’ electrical power consumption, thermal compatibility or relative deformations of the different materials. At the end, the main challenge of the project, is to identify a technical solution able to overcome all these problems but still at a competitive cost when compared to already existing thermal storage solutions. Special attention is given to all these issues during this project.

  17. Preparation, characterization, and thermal properties of microencapsulated phase change material for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Alkan, Cemil; Sari, Ahmet; Karaipekli, Ali [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey); Uzun, Orhan [Department of Physics, Gaziosmanpasa University, 60240 Tokat (Turkey)

    2009-01-15

    This study is focused on the preparation, characterization, and determination of thermal properties of microencapsulated docosane with polymethylmethacrylate (PMMA) as phase change material for thermal energy storage. Microencapsulation of docosane has been carried out by emulsion polymerization. The microencapsulated phase change material (MEPCM) was characterized using scanning electron microscopy (SEM) and Fourier transform infrared (FT-IR) spectroscopy. Thermal properties and thermal stability of MEPCM were measured by differential scanning calorimetry (DSC) and thermal gravimetric analysis (TGA). DSC analysis indicated that the docosane in the microcapsules melts at 41.0 C and crystallizes at 40.6 C. It has latent heats of 54.6 and -48.7 J/g for melting and crystallization, respectively. TGA showed that the MEPCM degraded in three distinguishable steps and had good chemical stability. Accelerated thermal cycling tests also indicated that the MEPCM had good thermal reliability. Based on all these results, it can be concluded that the microencapsulated docosane as MEPCMs have good potential for thermal energy storage purposes such as solar space heating applications. (author)

  18. Final Report-- A Novel Storage Method for Concentrating Solar Power Plants Allowing Storage at High Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Morris, Jeffrey F.

    2014-09-29

    The main objective of the proposed work was the development and testing of a storage method that has the potential to fundamentally change the solar thermal industry. The development of a mathematical model that describes the phenomena involved in the heat storage and recovery was also a main objective of this work. Therefore, the goal was to prepare a design package allowing reliable scale-up and optimization of design.

  19. Thermal geometry from CFT at finite temperature

    Energy Technology Data Exchange (ETDEWEB)

    Gan, Wen-Cong, E-mail: ganwencong@gmail.com [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China); Shu, Fu-Wen, E-mail: shufuwen@ncu.edu.cn [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China); Wu, Meng-He, E-mail: menghewu.physik@gmail.com [Department of Physics, Nanchang University, Nanchang 330031 (China); Center for Relativistic Astrophysics and High Energy Physics, Nanchang University, Nanchang 330031 (China)

    2016-09-10

    We present how the thermal geometry emerges from CFT at finite temperature by using the truncated entanglement renormalization network, the cMERA. For the case of 2d CFT, the reduced geometry is the BTZ black hole or the thermal AdS as expectation. In order to determine which spacetimes prefer to form, we propose a cMERA description of the Hawking–Page phase transition. Our proposal is in agreement with the picture of the recent proposed surface/state correspondence.

  20. Thermal geometry from CFT at finite temperature

    Directory of Open Access Journals (Sweden)

    Wen-Cong Gan

    2016-09-01

    Full Text Available We present how the thermal geometry emerges from CFT at finite temperature by using the truncated entanglement renormalization network, the cMERA. For the case of 2d CFT, the reduced geometry is the BTZ black hole or the thermal AdS as expectation. In order to determine which spacetimes prefer to form, we propose a cMERA description of the Hawking–Page phase transition. Our proposal is in agreement with the picture of the recent proposed surface/state correspondence.

  1. Quality of Cultured Wader Pari During Storage at Different Temperature

    Directory of Open Access Journals (Sweden)

    Almira Islamei Pratiwi

    2017-04-01

    Full Text Available Rasbora lateristriata is one Indonesian freshwater fish consumed by society as a source of animal protein. Like fish in general, rasbora is considered as perishable food, so it is necessary to apply a proper storage technique, one of which is cold storage. The purpose of this study was to determine the proper storage temperature of the rasbora in the storage of freezer, chiller and ice. The raw materials used was rasbora in size of 2 grams/fish. The Wader was caught then pondered (2,1 kg. Rasbora was split into three different storages those were freezer (-20°C, chiller (4°C, and ice (10°C. The study design used a completely randomized design with storage temperature factors and the duration of storage with three treatments and three replications. Observations were made on days 0, 5, 10, 15, 20, 25, and 30 include TPC test, TVB, pH and organoleptic. The results showed that treatment of freezer, chiller, and ice storage were able to inhibit decay until the 40th day, 13th day, and day 2, repectivelly. Thus, the freezer storage (-20° C provides more effective in inhibiting decay by TPC, TVB, pH and organoleptic.

  2. Solid state phase change materials for thermal energy storage in passive solar heated buildings

    Science.gov (United States)

    Benson, D. K.; Christensen, C.

    1983-11-01

    A set of solid state phase change materials was evaluated for possible use in passive solar thermal energy storage systems. The most promising materials are organic solid solutions of pentaerythritol, pentaglycerine and neopentyl glycol. Solid solution mixtures of these compounds can be tailored so that they exhibit solid-to-solid phase transformations at any desired temperature within the range from less than 25 deg to 188 deg. Thermophysical properties such as thermal conductivity, density and volumetric expansion were measured. Computer simulations were used to predict the performance of various Trombe wall designs incorporating solid state phase change materials. Optimum performance was found to be sensitive to the choice of phase change temperatures and to the thermal conductivity of the phase change material. A molecular mechanism of the solid state phase transition is proposed and supported by infrared spectroscopic evidence.

  3. A thermal storage capacity market for non dispatchable renewable energies

    Science.gov (United States)

    Bennouna, El Ghali; Mouaky, Ammar; Arrad, Mouad; Ghennioui, Abdellatif; Mimet, Abdelaziz

    2017-06-01

    Due to the increasingly high capacity of wind power and solar PV in Germany and some other European countries and the high share of variable renewable energy resources in comparison to fossil and nuclear capacity, a power reserve market structured by auction systems was created to facilitate the exchange of balance power capacities between systems and even grid operators. Morocco has a large potential for both wind and solar energy and is engaged in a program to deploy 2000MW of wind capacity by 2020 and 3000 MW of solar capacity by 2030. Although the competitiveness of wind energy is very strong, it appears clearly that the wind program could be even more ambitious than what it is, especially when compared to the large exploitable potential. On the other hand, heavy investments on concentrated solar power plants equipped with thermal energy storage have triggered a few years ago including the launching of the first part of the Nour Ouarzazate complex, the goal being to reach stable, dispatchable and affordable electricity especially during evening peak hours. This paper aims to demonstrate the potential of shared thermal storage capacity between dispatchable and non dispatchable renewable energies and particularly CSP and wind power. Thus highlighting the importance of a storage capacity market in parallel to the power reserve market and the and how it could enhance the development of both wind and CSP market penetration.

  4. Building Climate Energy Management in Smart Thermal Grids via Aquifer Thermal Energy Storage Systems

    NARCIS (Netherlands)

    Rostampour, Vahab; Jaxa-Rozen, M.; Bloemendal, J.M.; Keviczky, T.

    2016-01-01

    This paper proposes a building energy management framework, described by mixed logical dynamical systems due to operating constraints and logic rules, together with an aquifer thermal energy storage (ATES) model. We develop a deterministic model predictive control strategy to meet building

  5. Thermal transfer performance of a spherical encapsulated PEG 6000-based composite for thermal energy storage

    Czech Academy of Sciences Publication Activity Database

    Anghel, E.M.; Pavel, P.M.; Constantinescu, M.; Petrescu, S.; Atkinson, I.; Buixaderas, Elena

    2017-01-01

    Roč. 208, Sep (2017), s. 1222-1231 ISSN 0306-2619 Grant - others:AV ČR(CZ) AR-17-02 Program:Bilaterální spolupráce Institutional support: RVO:68378271 Keywords : phase change materials * thermal energy storage * modeling Subject RIV: CF - Physical ; Theoretical Chemistry Impact factor: 7.182, year: 2016

  6. Investigation of the charge boost technology for the efficiency increase of closed sorption thermal energy storage systems

    Science.gov (United States)

    Rohringer, C.; Engel, G.; Köll, R.; Wagner, W.; van Helden, W.

    2017-10-01

    The inclusion of solar thermal energy into energy systems requires storage possibilities to overcome the gap between supply and demand. Storage of thermal energy with closed sorption thermal energy systems has the advantage of low thermal losses and high energy density. However, the efficiency of these systems needs yet to be increased to become competitive on the market. In this paper, the so-called “charge boost technology” is developed and tested via experiments as a new concept for the efficiency increase of compact thermal energy storages. The main benefit of the charge boost technology is that it can reach a defined state of charge for sorption thermal energy storages at lower temperature levels than classic pure desorption processes. Experiments are conducted to provide a proof of principle for this concept. The results show that the charge boost technology does function as predicted and is a viable option for further improvement of sorption thermal energy storages. Subsequently, a new process application is developed by the author with strong focus on the utilization of the advantages of the charge boost technology over conventional desorption processes. After completion of the conceptual design, the theoretical calculations are validated via experiments.

  7. Operating results of a thermocline thermal energy storage included in a parabolic trough mini power plant

    Science.gov (United States)

    Fasquelle, Thomas; Falcoz, Quentin; Neveu, Pierre; Lecat, Florent; Boullet, Nicolas; Flamant, Gilles

    2017-06-01

    A thermocline thermal energy storage tank consists in using one single tank to store sensible heat. At almost any time, three zones coexist in the tank: a hot fluid zone at the top, a cold fluid zone at the bottom, and an intermediate zone called thermocline. Filling the tank with solid materials enables to reduce cost and to maintain the thermal stratification during stand-by periods. The present paper deals with a 230 kWh experimental thermocline tank that is included into a 150 kWth parabolic trough mini power plant. The heat transfer fluid is a non-pressurized synthetic oil (dibenzyltoluene) that flows through alumina spheres in the storage tank. The solid materials are contained into baskets in order to facilitate their removing and replacement. Thermocouples measure temperature along the center of the cylinder and along its radius. It is therefore possible to study the thermocline behavior thanks to the measured temperature profiles. A typical charge, a typical discharge and a stand-by process are presented and storage performances are discussed. The behavior of the tank in a dynamic system is also considered, by analyzing a typical day of solar production and storage of the energy surplus.

  8. Smart Polyacrylonitrile (PAN) Nanofibers with Thermal Energy Storage and Retrieval Functionality

    Science.gov (United States)

    Cherry, De'Andre James

    Phase change materials (PCMs) are generally substances with a high heat of fusion in the process of solid to liquid phase change. The nature of PCMs make them efficient materials to store and retrieve large amounts of thermal energy. Presently, high efficiency thermal energy storage/retrieval in applications where flexibility and space saving are required, such as smart textiles, still remains as a challenge. In this study, lauric acid (LA) and myristic acid (MA) were combined to prepare a specific binary fatty acid eutectic (LA-MA) with a melting point near the operating body temperature of a human being and then encapsulated in polyacrylonitrile (PAN) nanofibers through the electrospinning technique. Functionalized PCM-enhanced PAN nanofibers containing LA-MA at 30%, 50%, 70% and 100% of the weight of the PAN were successfully synthesized. The morphological structures and thermal energy storage capacity of the PCM-enhanced PAN nanofibers were characterized by electron microscopy (EM) and differential scanning calorimetry (DSC). The novel PCM-enhanced PAN nanofibers maintained their cylindrical fiber morphology after multiple heating-cooling cycles and retained their latent heat storage functionality. Thus, it is envisioned that the prepared PCM-enhanced PAN nanofibers will find use in applications such as smart textiles where temperature regulation functionality is required.

  9. Thermal Storage Capacity and Night Ventilation Performance of a Solar Chimney Combined with Different PCMs

    Directory of Open Access Journals (Sweden)

    Jun Lu

    2017-01-01

    Full Text Available Thermal storage capacity and airflow rate of a solar chimney combined with different PCMs are numerically studied during nighttime. PCMs with phase change temperatures of 38°C, 44°C, 50°C, and 63°C are selected in this numerical study. Results show that the maximum average ventilation rate of 610 kg/m2 and maximum thermal storage of 4750 kJ/m2 are achieved at the phase change temperature of 38°C. However, for phase change temperature of 63°C, night ventilation does not occur under the identical conditions. The findings reveal that a lower phase change temperature can increase the chargeability (and therefore the dischargeability of a solar chimney, since a higher phase change temperature demands higher solar radiation intensity and longer charging time for a solar chimney. For PCM with a phase change temperature of 44°C, most of the heat stored in PCM is lost to ambient through glass cover by radiation and only a small portion is used for heating the air within air channel.

  10. Solar Thermal Energy Storage in a Photochromic Macrocycle.

    Science.gov (United States)

    Vlasceanu, Alexandru; Broman, Søren L; Hansen, Anne S; Skov, Anders B; Cacciarini, Martina; Kadziola, Anders; Kjaergaard, Henrik G; Mikkelsen, Kurt V; Nielsen, Mogens Brøndsted

    2016-07-25

    The conversion and efficient storage of solar energy is recognized to hold significant potential with regard to future energy solutions. Molecular solar thermal batteries based on photochromic systems exemplify one possible technology able to harness and apply this potential. Herein is described the synthesis of a macrocycle based on a dimer of the dihydroazulene/vinylheptafulvene (DHA/VHF) photo/thermal couple. By taking advantage of conformational strain, this DHA-DHA macrocycle presents an improved ability to absorb and store incident light energy in chemical bonds (VHF-VHF). A stepwise energy release over two sequential ring-closing reactions (VHF→DHA) combines the advantages of an initially fast discharge, hypothetically addressing immediate energy consumption needs, followed by a slow process for consistent, long-term use. This exemplifies another step forward in the molecular engineering and design of functional organic materials towards solar thermal energy storage and release. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Solar-thermal conversion and thermal energy storage of graphene foam-based composites.

    Science.gov (United States)

    Zhang, Lianbin; Li, Renyuan; Tang, Bo; Wang, Peng

    2016-08-14

    Among various utilizations of solar energy, solar-thermal conversion has recently gained renewed research interest due to its extremely high energy efficiency. However, one limiting factor common to all solar-based energy conversion technologies is the intermittent nature of solar irradiation, which makes them unable to stand-alone to satisfy the continuous energy need. Herein, we report a three-dimensional (3D) graphene foam and phase change material (PCM) composite for the seamlessly combined solar-thermal conversion and thermal storage for sustained energy release. The composite is obtained by infiltrating the 3D graphene foam with a commonly used PCM, paraffin wax. The high macroporosity and low density of the graphene foam allow for high weight fraction of the PCM to be incorporated, which enhances the heat storage capacity of the composite. The interconnected graphene sheets in the composite provide (1) the solar-thermal conversion capability, (2) high thermal conductivity and (3) form stability of the composite. Under light irradiation, the composite effectively collects and converts the light energy into thermal energy, and the converted thermal energy is stored in the PCM and released in an elongated period of time for sustained utilization. This study provides a promising route for sustainable utilization of solar energy.

  12. Solar-thermal conversion and thermal energy storage of graphene foam-based composite

    KAUST Repository

    Zhang, Lianbin

    2016-07-11

    Among various utilizations of solar energy, solar-thermal conversion has recently gained renewed research interest due to its extremely high energy efficiency. However, one limiting factor common to all solar-based energy conversion technologies is the intermittent nature of solar irradiation, which makes them unable to stand-alone to satisfy continuous energy need. Herein, we report a three-dimensional (3D) graphene foam and phase change material (PCM) composite for the seamlessly combined solar-thermal conversion and thermal storage for sustained energy release. The composite is obtained by infiltrating the 3D graphene foam with a commonly used PCM, paraffin wax. The high macroporosity and low density of the graphene foam allow for high weight fraction of the PCM to be incorporated, which enhances heat storage capacity of the composite. The interconnected graphene sheets in the composite provide (1) the solar-thermal conversion capability, (2) high thermal conductivity and (3) form stability of the composite. Under light irradiation, the composite effectively collects and converts the light energy into thermal energy, and the converted thermal energy is stored in the PCM and released in an elongated period of time for sustained utilization. This study provides a promising route for sustainable utilization of solar energy.

  13. Investigation of Transient, Turbulent Natural Convection in Vertical Tubes for Thermal Energy Storage in Supercritical CO2

    Science.gov (United States)

    Baghaei Lakeh, Reza; Lavine, Adrienne S.; Kavehpour, H. Pirouz; Wirz, Richard E.

    2013-11-01

    Heat transfer can be a limiting factor in the operation of thermal energy storage, including sensible heat and latent heat storage systems. Poor heat transfer between the energy storage medium and the container walls impairs the functionality of the thermal storage unit by requiring excessively long times to charge or discharge the system. In this study, the effect of turbulent, unsteady buoyancy-driven flow on heat transfer in vertical storage tubes containing supercritical CO2 as the storage medium is investigated computationally. The heat transfer from a constant-temperature wall to the storage fluid is studied during the charge cycle. The results of this study show that turbulent natural convection dominates the heat transfer mechanism and significantly reduces the required time for charging compared to pure conduction. Changing the L/D ratio of the storage tube has a major impact on the charge time. The charge time shows a decreasing trend with RaL. The non-dimensional model of the problem shows that Nusselt number and non-dimensional mean temperature of the storage fluid in different configurations of the tube is a function Buoyancy-Fourier number defined as of FoL * RaLm* L/D. This study was supported by award No. DE-AR0000140 granted by U.S. Department of Energy under Advanced Research Projects Agency - Energy (ARPA-E) and by award No. 5660021607 granted by Southern California Gas Company.

  14. Design and installation manual for thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Cole, R L; Nield, K J; Rohde, R R; Wolosewicz, R M [eds.

    1979-02-01

    The purpose for this manual is to provide information on the design and installation of thermal energy storage in solar heating systems. It is intended for contractors, installers, solar system designers, engineers, architects, and manufacturers who intend to enter the solar energy business. The reader should have general knowledge of how solar heating systems operate and knowledge of construction methods and building codes. Knowledge of solar analysis methods such as f-chart, SOLCOST, DOE-1, or TRNSYS would be helpful. The information contained in the manual includes sizing storage, choosing a location for the storage device, and insulation requirements. Both air-based and liquid-based systems are covered with topics on designing rock beds, tank types, pump and fan selection, installation, costs, and operation and maintenance. Topics relevant to heating domestic water include safety, single- and dual-tank systems, domestic water heating with air- and liquid-based space heating system, and stand-alone domestic hot water systems. Several appendices present common problems with storage systems and their solutions, heat transfer fluid properties, heat exchanger sizing, and sample specifications for heat exchangers, wooden rock bins, steel tanks, concrete tanks, and fiberglass-reinforced plastic tanks.

  15. Thermal fuse for high-temperature batteries

    Science.gov (United States)

    Jungst, Rudolph G.; Armijo, James R.; Frear, Darrel R.

    2000-01-01

    A thermal fuse, preferably for a high-temperature battery, comprising leads and a body therebetween having a melting point between approximately 400.degree. C. and 500.degree. C. The body is preferably an alloy of Ag--Mg, Ag--Sb, Al--Ge, Au--In, Bi--Te, Cd--Sb, Cu--Mg, In--Sb, Mg--Pb, Pb--Pd, Sb--Zn, Sn--Te, or Mg--Al.

  16. Experimental and numerical investigation of a packed-bed thermal energy storage device

    Science.gov (United States)

    Yang, Bei; Wang, Yan; Bai, Fengwu; Wang, Zhifeng

    2017-06-01

    This paper presents a pilot-scale setup built to study a packed bed thermal energy storage device based on ceramic balls randomly poured into a cylindrical tank while using air as heat transfer fluid. Temperature distribution of ceramic balls throughout the packed bed is investigated both experimentally and numerically. Method of characteristic is adopted to improve the numerical computing efficiency, and mesh independence is verified to guarantee the accuracy of numerical solutions and the economy of computing time cost at the same time. Temperature in tests is as high as over 600 °C, and modeling prediction shows good agreements with experimental results under various testing conditions when heat loss is included and thermal properties of air are considered as temperature dependent.

  17. Basic Research on a Latent Heat Thermal Energy Storage by Direct Contact Melting and Soldification

    Science.gov (United States)

    Saito, Akihiro; Saito, Akio; Utaka, Yoshio; Okuda, Kenichi; Katayama, Kozo

    A basic experimental research on a latent heat thermal energy storage system , utilizing a simple and effective heat exchange mechanism by a direct contact between the phase change material (PCM) and the heat transfer fluid (HTF), was shown. Discharging experiments on direct contact latent heat thermal energy reservoir using n-Eicosane as the PCM and water as the HTF, were performed, based on the conditions obtained in previous report. Then, operating conditions for suitable discharging process were searched from the experimental results (outlet water temperature response and local temperature response in the reservoir). Moreover, solidification mechanisms of PCM, which had been presumed in previous report, were confirmed from these experimental results, and the simple physical model on direct contact heat exchange in the reservoir was proposed. Then, the outlet water temperature response by this model was compared with the experimental results.

  18. Biomass ignition in mills and storages – is it explained by conventional thermal ignition theory?

    DEFF Research Database (Denmark)

    Schwarzer, Lars; Jensen, Peter Arendt; Glarborg, Peter

    Self-ignition temperatures determined in the framework of conventional thermal ignition theory does not explain why biomass is much more susceptible to spontaneous ignition in power plant mills or storages. Examining the onset of reactions at low temperatures may provide a better understanding...... of the process, which can then be incorporated into refined models of self-ignition for biomass and other organic solids. In the present study, the slow, transient heating of several lignocellulosic biomasses and a bituminous coal from ambient temperature to around 300° C were investigated in a lab scale tube......, suggesting that a heterogeneous oxidation is the dominating mechanism in self-ignition. It could also be shown that both mechanisms compete for reactive material. While oxidation was exothermic, pyrolysis was largely thermally neutral in these experiments. Reaction behavior was seen to depend highly...

  19. Thermal energy storage for a space solar dynamic power system

    Science.gov (United States)

    Faget, N. M.; Fraser, W. M., Jr.; Simon, W. E.

    1985-01-01

    In the past, NASA has employed solar photovoltaic devices for long-duration missions. Thus, the Skylab system has operated with a silicon photovoltaic array and a nickel-cadmium electrochemical system energy storage system. Difficulties regarding the employment of such a system for the larger power requirements of the Space Station are related to a low orbit system efficiency and the large weight of the battery. For this reason the employment of a solar dynamic power system (SDPS) has been considered. The primary components of an SDPS include a concentrating mirror, a heat receiver, a thermal energy storage (TES) system, a thermodynamic heat engine, an alternator, and a heat rejection system. The heat-engine types under consideration are a Brayton cycle engine, an organic Rankine cycle engine, and a free-piston/linear-alternator Stirling cycle engine. Attention is given to a system description, TES integration concepts, and a TES technology assessment.

  20. Dynamic modeling of a solar receiver/thermal energy storage system based on a compartmented dense gas fluidized bed

    Science.gov (United States)

    Solimene, Roberto; Chirone, Roberto; Chirone, Riccardo; Salatino, Piero

    2017-06-01

    Fluidized beds may be considered a promising option to collection and storage of thermal energy of solar radiation in Concentrated Solar Power (CSP) systems thanks to their excellent thermal properties in terms of bed-to-wall heat transfer coefficient and thermal diffusivity and to the possibility to operate at much higher temperature. A novel concept of solar receiver for combined heat and power (CHP) generation consisting of a compartmented dense gas fluidized bed has been proposed to effectively accomplish three complementary tasks: collection of incident solar radiation, heat transfer to the working fluid of the thermodynamic cycle and thermal energy storage. A dynamical model of the system laid the basis for optimizing collection of incident radiative power, heat transfer to the steam cycle, storage of energy as sensible heat of bed solids providing the ground for the basic design of a 700kWth demonstration CSP plant.

  1. Accelerated Thermal Cycling Test of Microencapsulated Paraffin Wax/Polyaniline Made by Simple Preparation Method for Solar Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Mohammad Mehrali

    2013-04-01

    Full Text Available Microencapsulated paraffin wax/polyaniline was prepared using a simple in situ polymerization technique, and its performance characteristics were investigated. Weight losses of samples were determined by Thermal Gravimetry Analysis (TGA. The microencapsulated samples with 23% and 49% paraffin showed less decomposition after 330 °C than with higher percentage of paraffin. These samples were then subjected to a thermal cycling test. Thermal properties of microencapsulated paraffin wax were evaluated by Differential Scanning Calorimeter (DSC. Structure stability and compatibility of core and coating materials were also tested by Fourier transform infrared spectrophotometer (FTIR, and the surface morphology of the samples are shown by Field Emission Scanning Electron Microscopy (FESEM. It has been found that the microencapsulated paraffin waxes show little change in the latent heat of fusion and melting temperature after one thousand thermal recycles. Besides, the chemical characteristics and structural profile remained constant after one thousand thermal cycling tests. Therefore, microencapsulated paraffin wax/polyaniline is a stable material that can be used for thermal energy storage systems.

  2. PRELIMINARY REPORT: EFFECTS OF IRRADIATION AND THERMAL EXPOSURE ON ELASTOMERIC SEALS FOR CASK TRANSPORTATION AND STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Verst, C.; Skidmore, E.; Daugherty, W.

    2014-05-30

    A testing and analysis approach to predict the sealing behavior of elastomeric seal materials in dry storage casks and evaluate their ability to maintain a seal under thermal and radiation exposure conditions of extended storage and beyond was developed, and initial tests have been conducted. The initial tests evaluate the aging response of EPDM elastomer O-ring seals. The thermal and radiation exposure conditions of the CASTOR® V/21 casks were selected for testing as this cask design is of interest due to its widespread use, and close proximity of the seals to the fuel compared to other cask designs leading to a relatively high temperature and dose under storage conditions. A novel test fixture was developed to enable compression stress relaxation measurements for the seal material at the thermal and radiation exposure conditions. A loss of compression stress of 90% is suggested as the threshold at which sealing ability of an elastomeric seal would be lost. Previous studies have shown this value to be conservative to actual leakage failure for most aging conditions. These initial results indicate that the seal would be expected to retain sealing ability throughout extended storage at the cask design conditions, though longer exposure times are needed to validate this assumption. The high constant dose rate used in the testing is not prototypic of the decreasingly low dose rate that would occur under extended storage. The primary degradation mechanism of oxidation of polymeric compounds is highly dependent on temperature and time of exposure, and with radiation expected to exacerbate the oxidation.

  3. Thermal Storage Power Balancing with Model Predictive Control

    DEFF Research Database (Denmark)

    Halvgaard, Rasmus; Poulsen, Niels Kjølstad; Madsen, Henrik

    2013-01-01

    The method described in this paper balances power production and consumption with a large number of thermal loads. Linear controllers are used for the loads to track a temperature set point, while Model Predictive Control (MPC) and model estimation of the load behavior are used for coordination...

  4. Influence of Drying Temperature and Storage Duration on Fissuring ...

    African Journals Online (AJOL)

    Moisture and temperature gradients induce the development of fissures during drying of paddy kernels. This affects the milling quality of the paddy and eventually reduces the head rice yield. To this effect, a study was conducted to investigate the influence of drying temperature and storage duration on the cracking ...

  5. Thermal energy storage systems using fluidized bed heat exchangers

    Science.gov (United States)

    Ramanathan, V.; Weast, T. E.; Ananth, K. P.

    1980-01-01

    The viability of using fluidized bed heat exchangers (FBHX) for thermal energy storage (TES) in applications with potential for waste heat recovery was investigated. Of the candidate applications screened, cement plant rotary kilns and steel plant electric arc furnaces were identified, via the chosen selection criteria, as having the best potential for successful use of FBHX/TES system. A computer model of the FBHX/TES systems was developed and the technical feasibility of the two selected applications was verified. Economic and tradeoff evaluations in progress for final optimization of the systems and selection of the most promising system for further concept validation are described.

  6. Bibliography of the seasonal thermal energy storage library

    Energy Technology Data Exchange (ETDEWEB)

    Prater, L.S.; Casper, G.; Kawin, R.A.

    1981-08-01

    The Main Listing is arranged alphabetically by the last name of the first author. Each citation includes the author's name, title, publisher, publication date, and where applicable, the National Technical Information Service (NTIS) number or other document number. The number preceding each citation is the identification number for that document in the Seasonal Thermal Energy Storage (STES) Library. Occasionally, one or two alphabetic characters are added to the identification number. These alphabetic characters indicate that the document is contained in a collection of papers, such as the proceedings of a conference. An Author Index and an Identification Number Index are included. (WHK)

  7. Literature review of market studies of thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Hattrup, M.P.

    1988-02-01

    This report presents the results of a review of market studies of thermal energy storage (TES). This project was conducted by Pacific Northwest Laboratory (PNL) for the US Department of Energy (DOE). PNL staff reviewed and consolidated the findings of existing TES market studies conducted in the industrial, commercial, and residential sectors. The purpose of this project was to review and assess previous work and to use the information obtained to help provide direction for future technology transfer planning activities and to identify additional economic research needed within those three sectors. 37 refs.

  8. Thermal energy storage for industrial waste heat recovery

    Science.gov (United States)

    Hoffman, H. W.; Kedl, R. J.; Duscha, R. A.

    1978-01-01

    The potential is examined for waste heat recovery and reuse through thermal energy storage in five specific industrial categories: (1) primary aluminum, (2) cement, (3) food processing, (4) paper and pulp, and (5) iron and steel. Preliminary results from Phase 1 feasibility studies suggest energy savings through fossil fuel displacement approaching 0.1 quad/yr in the 1985 period. Early implementation of recovery technologies with minimal development appears likely in the food processing and paper and pulp industries; development of the other three categories, though equally desirable, will probably require a greater investment in time and dollars.

  9. Solar-thermal-energy collection/storage-pond system

    Science.gov (United States)

    Blahnik, D.E.

    1982-03-25

    A solar thermal energy collection and storage system is disclosed. Water is contained, and the water surface is exposed directly to the sun. The central part of an impermeable membrane is positioned below the water's surface and above its bottom with a first side of the membrane pointing generally upward in its central portion. The perimeter part of the membrane is placed to create a watertight boundary separating the water into a first volume which is directly exposable to the sun and which touches the membranes first side, and a second volumn which touches the membranes second side. A salt is dissolved in the first water volume.

  10. Thermal Evaluation of Storage Rack with an Advanced Neutron Absorber during Normal Operation

    Energy Technology Data Exchange (ETDEWEB)

    Lee, Hee-Jae; Kim, Mi-Jin; Sohn, Dong-Seong [UNIST, Ulsan (Korea, Republic of)

    2016-10-15

    The storage capacity of the domestic wet storage site is expected to reach saturation from Hanbit in 2024 to Sin-wolseong in 2038 and accordingly management alternatives are urgently taken. Since installation of the dense rack is considered in the short term, it is necessary to urgently develop an advanced neutron absorber which can be applied to a spent nuclear fuel storage facility. Neutron absorber is the material for controlling the reactivity. A material which has excellent thermal neutron absorption ability, high strength and corrosion resistance must be selected as the neutron absorber. Existing neutron absorbers are made of boron which has a good thermal absorption ability such as BORAL and METAMIC. However, possible problems have been reported in using the boron-based neutron absorber for wet storage facility. Gadolinium is known to have higher neutron absorption cross-section than that of boron. And the strength of duplex stainless steel is about 1.5 times higher than stainless steel 304 which has been frequently used as a structural material. Therefore, duplex stainless steel which contains gadolinium is in consideration as an advanced neutron absorber. Temperature distribution is shown in figure 4. In pool bottom region near the inlet shows a relatively low tendency and heat generated from the fuel assemblies is transmitted to the pool upper region by the vertical flow. Also, temperature gradient appear in rack structures for the axial direction and temperature is uniformly distributed in the pool upper region. Table 1 presents the calculated results. The maximum temperature is 306.63K and does not exceed the 333.15K (60℃). The maximum temperature of the neutron absorber is 306.48K.

  11. Building Energy Storage Panel Based on Paraffin/Expanded Perlite: Preparation and Thermal Performance Study

    Directory of Open Access Journals (Sweden)

    Xiangfei Kong

    2016-01-01

    Full Text Available This study is focused on the preparation and performance of a building energy storage panel (BESP. The BESP was fabricated through a mold pressing method based on phase change material particle (PCMP, which was prepared in two steps: vacuum absorption and surface film coating. Firstly, phase change material (PCM was incorporated into expanded perlite (EP through a vacuum absorption method to obtain composite PCM; secondly, the composite PCM was immersed into the mixture of colloidal silica and organic acrylate, and then it was taken out and dried naturally. A series of experiments, including differential scanning calorimeter (DSC, scanning electron microscope (SEM, best matching test, and durability test, have been conducted to characterize and analyze the thermophysical property and reliability of PCMP. Additionally, the thermal performance of BESP was studied through a dynamic thermal property test. The results have showed that: (1 the surface film coating procedure can effectively solve the leakage problem of composite phase change material prepared by vacuum impregnation; (2 the optimum adsorption ratio for paraffin and EP was 52.5:47.5 in mass fraction, and the PCMP has good thermal properties, stability, and durability; and (3 in the process of dynamic thermal performance test, BESP have low temperature variation, significant temperature lagging, and large heat storage ability, which indicated the potential of BESP in the application of building energy efficiency.

  12. Building Energy Storage Panel Based on Paraffin/Expanded Perlite: Preparation and Thermal Performance Study.

    Science.gov (United States)

    Kong, Xiangfei; Zhong, Yuliang; Rong, Xian; Min, Chunhua; Qi, Chengying

    2016-01-25

    This study is focused on the preparation and performance of a building energy storage panel (BESP). The BESP was fabricated through a mold pressing method based on phase change material particle (PCMP), which was prepared in two steps: vacuum absorption and surface film coating. Firstly, phase change material (PCM) was incorporated into expanded perlite (EP) through a vacuum absorption method to obtain composite PCM; secondly, the composite PCM was immersed into the mixture of colloidal silica and organic acrylate, and then it was taken out and dried naturally. A series of experiments, including differential scanning calorimeter (DSC), scanning electron microscope (SEM), best matching test, and durability test, have been conducted to characterize and analyze the thermophysical property and reliability of PCMP. Additionally, the thermal performance of BESP was studied through a dynamic thermal property test. The results have showed that: (1) the surface film coating procedure can effectively solve the leakage problem of composite phase change material prepared by vacuum impregnation; (2) the optimum adsorption ratio for paraffin and EP was 52.5:47.5 in mass fraction, and the PCMP has good thermal properties, stability, and durability; and (3) in the process of dynamic thermal performance test, BESP have low temperature variation, significant temperature lagging, and large heat storage ability, which indicated the potential of BESP in the application of building energy efficiency.

  13. Reducing the Cost of Thermal Energy Storage for Parabolic Trough Solar Power Plants

    Energy Technology Data Exchange (ETDEWEB)

    Gawlik, Keith

    2013-06-25

    Thermal energy storage systems using phase change materials were evaluated for trough systems that use oil, steam, and high temperature salts as heat transfer fluids. A variety of eutectic salts and metal alloys were considered as phase change materials in a cascaded arrangement. Literature values of specific heat, latent heat, density, and other thermophysical properties were used in initial analyses. Testing laboratories were contracted to measure properties for candidate materials for comparison to the literature and for updating the models. A TRNSYS model from Phase 1 was further developed for optimizing the system, including a novel control algorithm. A concept for increasing the bulk thermal conductivity of the phase change system was developed using expanded metal sheets. Outside companies were contracted to design and cost systems using platecoil heat exchangers immersed in the phase change material. Laboratory evaluations of the one-dimensional and three-dimensional behavior of expanded metal sheets in a low conductivity medium were used to optimize the amount of thermal conductivity enhancement. The thermal energy storage systems were compared to baseline conventional systems. The best phase change system found in this project, which was for the high temperature plant, had a projected cost of $25.2 per kWhth, The best system also had a cost that was similar to the base case, a direct two-tank molten salt system.

  14. Building Energy Storage Panel Based on Paraffin/Expanded Perlite: Preparation and Thermal Performance Study

    Science.gov (United States)

    Kong, Xiangfei; Zhong, Yuliang; Rong, Xian; Min, Chunhua; Qi, Chengying

    2016-01-01

    This study is focused on the preparation and performance of a building energy storage panel (BESP). The BESP was fabricated through a mold pressing method based on phase change material particle (PCMP), which was prepared in two steps: vacuum absorption and surface film coating. Firstly, phase change material (PCM) was incorporated into expanded perlite (EP) through a vacuum absorption method to obtain composite PCM; secondly, the composite PCM was immersed into the mixture of colloidal silica and organic acrylate, and then it was taken out and dried naturally. A series of experiments, including differential scanning calorimeter (DSC), scanning electron microscope (SEM), best matching test, and durability test, have been conducted to characterize and analyze the thermophysical property and reliability of PCMP. Additionally, the thermal performance of BESP was studied through a dynamic thermal property test. The results have showed that: (1) the surface film coating procedure can effectively solve the leakage problem of composite phase change material prepared by vacuum impregnation; (2) the optimum adsorption ratio for paraffin and EP was 52.5:47.5 in mass fraction, and the PCMP has good thermal properties, stability, and durability; and (3) in the process of dynamic thermal performance test, BESP have low temperature variation, significant temperature lagging, and large heat storage ability, which indicated the potential of BESP in the application of building energy efficiency. PMID:28787870

  15. Energy storage via high temperature superconductivity (SMES)

    Energy Technology Data Exchange (ETDEWEB)

    Mikkonen, R. [Tampere Univ. of Technology (Finland)

    1998-10-01

    The technology concerning high temperature superconductors (HTS) is matured to enabling different kind of prototype applications including SMES. Nowadays when speaking about HTS systems, attention is focused on the operating temperature of 20-30 K, where the critical current and flux density are fairly close to 4.2 K values. In addition by defining the ratio of the energy content of a novel HTS magnetic system and the required power to keep the system at the desired temperature, the optimum settles to the above mentioned temperature range. In the frame of these viewpoints a 5 kJ HTS SMES system has been designed and tested at Tampere University of Technology with a coil manufactured by American Superconductor (AMSC). The HTS magnet has inside and outside diameters of 252 mm and 317 mm, respectively and axial length of 66 mm. It operates at 160 A and carries a total of 160 kA-turns to store the required amount of energy. The effective magnetic inductance is 0.4 H and the peak axial field is 1.7 T. The magnet is cooled to the operating temperature of 20 K with a two stage Gifford-McMahon type cryocooler with a cooling power of 60 W at 77 K and 8 W at 20 K. The magnetic system has been demonstrated to compensate a short term loss of power of a sensitive consumer

  16. Investigation of metal fluoride thermal energy storage materials: availability, cost, and chemistry. Final report, July 15, 1976--December 15, 1976

    Energy Technology Data Exchange (ETDEWEB)

    Eichelberger, J.L.

    1976-12-01

    Storage of thermal energy in the 400 to 1000/sup 0/C range is attracting increasing consideration for use in solar power, central power, vehicular, and commercial process systems. This study investigates the practicality of using metal fluorides as the heat storage medium. The projected availability of metal fluorides has been studied and is shown to be adequate for widespread thermal storage use. Costs are projected and discussed in relation to thermal energy storage applications. Phase diagrams, heats of fusion, heat capacities, vapor pressures, toxicity, stability, volume changes, thermal conductivities, fusion kinetics, corrosion, and container materials of construction for a wide range of fluorides have been examined. Analyses of these data in consideration of thermal energy storage requirements have resulted in selection of the most cost-effective fluoride mixture for each of 23 temperature increments between 400 and 1000/sup 0/C. Thermo-physical properties of these 23 materials are presented. Comparison of fluoride with non-fluoride materials shows that the fluorides are suitable candidates for high temperature applications on the bases of cost, heat capacity/unit volume, heat capacity/unit weight, corrosive properties, and availability.

  17. Phase Change Material Systems for High Temperature Heat Storage.

    Science.gov (United States)

    Perraudin, David Y S; Binder, Selmar R; Rezaei, Ehsan; Ortonaa, Alberto; Haussener, Sophia

    2015-01-01

    Efficient, cost effective, and stable high-temperature heat storage material systems are important in applications such as high-temperature industrial processes (metal processing, cement and glass manufacturing, etc.), or electricity storage using advanced adiabatic compressed air energy storage. Incorporating phase change media into heat storage systems provides an advantage of storing and releasing heat at nearly constant temperature, allowing steady and optimized operation of the downstream processes. The choice of, and compatibility of materials and encapsulation for the phase change section is crucial, as these must guarantee good and stable performance and long lifetime at low cost. Detailed knowledge of the material properties and stability, and the coupled heat transfer, phase change, and fluid flow are required to allow for performance and lifetime predictions. We present coupled experimental-numerical techniques allowing prediction of the long-term performance of a phase change material-based high-temperature heat storage system. The experimental investigations focus on determination of material properties (melting temperature, heat of fusion, etc.) and phase change material and encapsulation interaction (stability, interface reactions, etc.). The computational investigations focus on an understanding of the multi-mode heat transfer, fluid flow, and phase change processes in order to design the material system for enhanced performance. The importance of both the experimental and numerical approaches is highlighted and we give an example of how both approaches can be complementarily used for the investigation of long-term performance.

  18. Developing a Cost Model and Methodology to Estimate Capital Costs for Thermal Energy Storage

    Energy Technology Data Exchange (ETDEWEB)

    Glatzmaier, G.

    2011-12-01

    This report provides an update on the previous cost model for thermal energy storage (TES) systems. The update allows NREL to estimate the costs of such systems that are compatible with the higher operating temperatures associated with advanced power cycles. The goal of the Department of Energy (DOE) Solar Energy Technology Program is to develop solar technologies that can make a significant contribution to the United States domestic energy supply. The recent DOE SunShot Initiative sets a very aggressive cost goal to reach a Levelized Cost of Energy (LCOE) of 6 cents/kWh by 2020 with no incentives or credits for all solar-to-electricity technologies.1 As this goal is reached, the share of utility power generation that is provided by renewable energy sources is expected to increase dramatically. Because Concentrating Solar Power (CSP) is currently the only renewable technology that is capable of integrating cost-effective energy storage, it is positioned to play a key role in providing renewable, dispatchable power to utilities as the share of power generation from renewable sources increases. Because of this role, future CSP plants will likely have as much as 15 hours of Thermal Energy Storage (TES) included in their design and operation. As such, the cost and performance of the TES system is critical to meeting the SunShot goal for solar technologies. The cost of electricity from a CSP plant depends strongly on its overall efficiency, which is a product of two components - the collection and conversion efficiencies. The collection efficiency determines the portion of incident solar energy that is captured as high-temperature thermal energy. The conversion efficiency determines the portion of thermal energy that is converted to electricity. The operating temperature at which the overall efficiency reaches its maximum depends on many factors, including material properties of the CSP plant components. Increasing the operating temperature of the power generation

  19. Design of Particle-Based Thermal Energy Storage for a Concentrating Solar Power System

    Energy Technology Data Exchange (ETDEWEB)

    Ma, Zhiwen [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Zhang, Ruichong [Colorado School of Mines; Sawaged, Fadi [Colorado School of Mines

    2017-06-03

    Solid particles can operate at higher temperature than current molten salt or oil, and they can be a heat-transfer and storage medium in a concentrating solar power (CSP) system. By using inexpensive solid particles and containment material for thermal energy storage (TES), the particle-TES cost can be significantly lower than other TES methods such as a nitrate-salt system. The particle-TES system can hold hot particles at more than 800 degrees C with high thermal performance. The high particle temperatures increase the temperature difference between the hot and cold particles, and they improve the TES capacity. The particle-based CSP system is able to support high-efficiency power generation, such as the supercritical carbon-dioxide Brayton power cycle, to achieve >50% thermal-electric conversion efficiency. This paper describes a solid particle-TES system that integrates into a CSP plant. The hot particles discharge to a heat exchanger to drive the power cycle. The returning cold particles circulate through a particle receiver to absorb solar heat and charge the TES. This paper shows the design of a particle-TES system including containment silos, foundation, silo insulation, and particle materials. The analysis provides results for four TES capacities and two silo configurations. The design analysis indicates that the system can achieve high thermal efficiency, storage effectiveness (i.e., percentage usage of the hot particles), and exergetic efficiency. An insulation method for the hot silo was considered. The particle-TES system can achieve high performance and low cost, and it holds potential for next-generation CSP technology.

  20. Evaluation of solar thermal storages with quantitative flow visualisation

    Energy Technology Data Exchange (ETDEWEB)

    Logie, W.; Frank, E.; Luzzi, A.

    2008-07-15

    The non-intrusive Quantitative Flow Visualisation (QFV) Techniques of Particle Imaging Velocimetry (PIV) and Laser Induced Fluorescence (LIF) have been evaluated in the context of experimental investigations on solar Thermal Energy Storages (TES). Much competence and experience has been gained in the integration of these powerful yet complex and time consuming flow analysis methods into the realm of laboratory experimentation. In addition to gathering experience in the application of QFV techniques, a number of charging and discharging variations were considered in light of exergetic evaluation for the influence they have on the ability of a TES to stratify. The contemporary awareness that poorly chosen pitch to diameter ratios by the design of immersed coil heat exchangers leads to a reduction in heat exchange and an increase in mixing phenomenon has been confirmed. The observation of two combitank (combined domestic hot water and space heating) configurations has shown that free convective heat transfer forces in the form of mixing energy play a significant role in the stratification efficiency of thermal energy storages. (author)

  1. Thermal energy storage in the form of heat or cold with using of the PCM-based accumulation panels

    Directory of Open Access Journals (Sweden)

    Skovajsa Jan

    2016-01-01

    Full Text Available This article describes the usage of thermal energy storage in the form of heat and cold with an adaptation of the special device which is composed of the thermal panels. These panels are based on the phase change materials (PCM for normal inner environment temperature in buildings. The energy for the thermal energy storage is possible to get from built-in electric heating foil or from the tube heat exchanger, which is build in the thermal panels. This technology is able to use renewable energy sources, for example, solar thermal collectors and air-to-water heat pump as a source of heat for heating of the hot water tank. In the cooling mode, there is able to use the heat pump or photovoltaics panels in combination with thermoelectric coolers for cooling.

  2. The spoilage of air-packaged broiler meat during storage at normal and fluctuating storage temperatures.

    Science.gov (United States)

    Zhang, Q Q; Han, Y Q; Cao, J X; Xu, X L; Zhou, G H; Zhang, W Y

    2012-01-01

    Bacterial diversity and the major flora present on air-packaged broiler meat during storage at normal (4°C) and fluctuating storage temperatures (0-4°C and 4-10°C) were investigated using culture-dependent and culture-independent approaches. Culture-dependent analysis revealed that the growth of microflora was retarded when broiler meat was stored at lower temperatures (0-4°C). Denaturing gradient gel electrophoresis profiles showed that Staphylococcus spp., Pseudomonas spp., Acinetobacter spp., Carnobacterium spp., Aeromonas spp., and Weissella spp. were the dominant bacteria throughout all storage conditions. Enterobacteriaceae only appeared in samples subjected to storage with high temperature abuse, whereas Shewanella spp. and Psychrobacter spp. were only detected in samples stored below 4°C. Our results provide evidence that, compared with storage at a standard fixed temperature (4°C), fluctuations in temperatures induce a more complex bacterial diversity in the air-packaged broiler.

  3. Experimental and theoretic investigations of thermal behavior of a seasonal water pit heat storage

    DEFF Research Database (Denmark)

    Fan, Jianhua; Huang, Junpeng; Chatzidiakos, Angelos

    Seasonal heat storages are considered essential for district heating systems because they offer flexibility for the system to integrate different fluctuating renewable energy sources. Water pit thermal storages (PTES) have been successfully implemented in solar district heating plants in Denmark...

  4. Thermal energy storage with geothermal triplet for space heating and cooling

    Science.gov (United States)

    Bloemendal, Martin; Hartog, Niels

    2017-04-01

    Many governmental organizations and private companies have set high targets in avoiding CO2 emissions and reducing energy (Kamp, 2015; Ministry-of-Economic-affairs, 2016). ATES systems use groundwater wells to overcome the discrepancy in time between the availability of heat (during summer) and the demand for heat (during winter). Aquifer Thermal Energy Storage is an increasingly popular technique; currently over 2000 ATES systems are operational in the Netherlands (Graaf et al., 2016). High temperature ATES may help to improve performance of these conventional ATES systems. ATES systems use heat pumps to get the stored heat to the required temperature for heating of around 40-50°C and to produce the cold water for cooling in summer. These heat pumps need quite a lot of power to run; on average an ATES system produces 3-4 times less CO2 emission compared to conventional. Over 60% of those emission are accounted for by the heat pump (Dekker, 2016). This heat pump power consumption can be reduced by utilizing other sources of sustainable heat and cooling capacity for storage in the subsurface. At such operating temperatures the required storage temperatures do no longer match the return temperatures in the building systems. Therefore additional components and an additional well are required to increase the groundwater temperature in summer (e.g. solar collectors) and decrease it in winter (e.g. dry coolers). To prevent "pollution" of the warm and cold well return water from the building can be stored in a third well until weather conditions are suitable for producing the required storage temperature. Simulations and an economical evaluation show great potential for this type of aquifer thermal energy storage; economic performance is better than normal ATES while the emissions are reduce by a factor ten. At larger temperature differences, also the volume of groundwater required to pump around is much less, which causes an additional energy saving. Research now

  5. Optically-controlled long-term storage and release of thermal energy in phase-change materials.

    Science.gov (United States)

    Han, Grace G D; Li, Huashan; Grossman, Jeffrey C

    2017-11-13

    Thermal energy storage offers enormous potential for a wide range of energy technologies. Phase-change materials offer state-of-the-art thermal storage due to high latent heat. However, spontaneous heat loss from thermally charged phase-change materials to cooler surroundings occurs due to the absence of a significant energy barrier for the liquid-solid transition. This prevents control over the thermal storage, and developing effective methods to address this problem has remained an elusive goal. Herein, we report a combination of photo-switching dopants and organic phase-change materials as a way to introduce an activation energy barrier for phase-change materials solidification and to conserve thermal energy in the materials, allowing them to be triggered optically to release their stored latent heat. This approach enables the retention of thermal energy (about 200 J g(-1)) in the materials for at least 10 h at temperatures lower than the original crystallization point, unlocking opportunities for portable thermal energy storage systems.

  6. Salmonella survival during thermal dehydration of fresh garlic and storage of dehydrated garlic products.

    Science.gov (United States)

    Zhang, Hongmei; Qi, Yan; Wang, Lei; Zhang, Shaokang; Deng, Xiangyu

    2017-12-18

    Salmonella survival was characterized and modeled during thermal dehydration of fresh garlic and storage of dehydrated garlic products. In our experiments that simulated commercial dehydration processing at 80±5°C, moderate level of Salmonella contamination (4-5logCFU/g) on fresh garlic was reduced below the enumeration limit (1.7logCFU/g) after 4.5h of dehydration and not detectable by culture enrichment after 7h. With high level of contamination (7-8logCFU/g), the Salmonella population persisted at 3.6logCFU/g after 8h of processing. By increasing the dehydration temperature to 90±5°C, the moderate and high levels of initial Salmonella load on fresh garlic dropped below the enumeration limit after 1.5 and 3.75h of processing and became undetectable by culture enrichment after 2.5 and 6h, respectively. During the storage of dried garlic products, Salmonella was not able to grow under all tested combinations of temperature (25 and 35°C) and water activity (0.56-0.98) levels, suggesting active inhibition. Storage temperature played a primary role in determining Salmonella survival on dehydrated garlic flakes. Under a typical storage condition at 25°C and ambient relative humidity, Salmonella could persist over months with the population gradually declining (4.3 log reduction over 88days). Granular size of dehydrated garlic had an impact on Salmonella survival, with better survival of the pathogen observed in bigger granules. At the early stage of dehydrated garlic storage (until 7days), rising water activity appeared to initially promote but then inhibited Salmonella survival, resulting in a water activity threshold at 0.73 where Salmonella displayed strongest persistence. However, this phenomenon was less apparent during extended storage (after 14days). Copyright © 2017 Elsevier B.V. All rights reserved.

  7. Solar dryer with thermal storage and biomass-backup heater

    Energy Technology Data Exchange (ETDEWEB)

    Madhlopa, A. [Department of Physics and Biochemical Sciences, Malawi Polytechnic, P/Bag 303, Blantyre 3 (Malawi); Ngwalo, G. [Department of Mechanical Engineering, Malawi Polytechnic, P/Bag 303, Blantyre 3 (Malawi)

    2007-04-15

    An indirect type natural convection solar dryer with integrated collector-storage solar and biomass-backup heaters has been designed, constructed and evaluated. The major components of the dryer are biomass burner (with a rectangular duct and flue gas chimney), collector-storage thermal mass and drying chamber (with a conventional solar chimney). The thermal mass was placed in the top part of the biomass burner enclosure. The dryer was fabricated using simple materials, tools and skills, and it was tested in three modes of operation (solar, biomass and solar-biomass) by drying twelve batches of fresh pineapple (Ananas comosus), with each batch weighing about 20 kg. Meteorological conditions were monitored during the dehydration process. Moisture and vitamin C contents were determined in both fresh and dried samples. Results show that the thermal mass was capable of storing part of the absorbed solar energy and heat from the burner. It was possible to dry a batch of pineapples using solar energy only on clear days. Drying proceeded successfully even under unfavorable weather conditions in the solar-biomass mode of operation. In this operational mode, the dryer reduced the moisture content of pineapple slices from about 669 to 11% (db) and yielded a nutritious dried product. The average values of the final-day moisture-pickup efficiency were 15%, 11% and 13% in the solar, biomass and solar-biomass modes of operation respectively. It appears that the solar dryer is suitable for preservation of pineapples and other fresh foods. Further improvements to the system design are suggested. (author)

  8. THERMAL ENERGY STORAGE PROPERTIES OF FORMSTABLE PARAFFIN/RECYCLE BLOCK CONCRETE COMPOSITE PHASE CHANGE MATERIAL

    Directory of Open Access Journals (Sweden)

    PATTARAPORN SUTTAPHAKDEE

    2017-01-01

    Full Text Available In this research, the form-stable composite phase change material was developed by incorporating paraffin on recycle block concrete (RB through the vacuum impregnation method. The compatibility and thermal properties of RB impregnated with paraffin ranging from 0-35 wt% were characterized by Fourier transform infrared spectroscopy (FTIR and differential scanning calorimetry (DSC. Results revealed that paraffin was uniformly absorbed in RB with a good physical compatibility. The optimum adsorption ratio of paraffin in RB was 25 wt% which produced phase transition temperature of 52.85 OC and latent heat of 30.98 J/g. The obtained form-stable paraffin/RB composite PCM had proper latent heat and phase transition temperature and can be applied for thermal energy storage applications such as solar heating and cooling in buildings.

  9. A Survey on an Ice Thermal Storage System and a Study on an Operation Scheme for a Performance Optimization

    Energy Technology Data Exchange (ETDEWEB)

    Kim, In Soo [Korea Energy Management Corporation, Yongin (Korea)

    2001-02-01

    Because the composition of an ice thermal storage system is more complicated than the existing freezer for air conditioning, the excellent air conditioning effect cannot be made with as low as a cost in the early stage of installing if the system is not correctly understood and properly maintained through all the process, from a selection of the system to an installation and operation. However, most ice thermal storage systems do not perform the specific operation suitable for the features of the system under the uncontrolled program, so most freezers is operating on the condition that the efficiency declines to more than 30% compared with a regular efficiency. The systematic management by the thermal storage rate is not also being made. To optimize the efficiency of an ice thermal storage system, the management ability should be improved through educating field managers, and professionals in design and operation fields should regularly and continuously manage the system through performing a complete A/S. To maximize the retrenchment of the electricity demand through optimizing the system, the parallel operation of an ice thermal storage system in the peak time should be controlled by discounting a rate and enlarging the difference of an extra rate between late-night time and daytime. In addition to that, to prevent the inefficiency operation due to a negligent management in most ice thermal storage systems and promote the activation of spreading ice thermal storage systems as an electricity saving equipment, the systematic supplement that connects the efficiency of room temperature (RT/m{sup 3}.hr) to a rebate, a regular education for system managers, and the technical supports should be made. 17 figs., 7 tabs.

  10. Multiple sample setup for testing the hydrothermal stability of adsorbents in thermal energy storage applications

    Science.gov (United States)

    Fischer, Fabian; Laevemann, Eberhard

    2015-06-01

    Thermal energy storage based on adsorption and desorption of water on an adsorbent can achieve high energy storage densities. Many adsorbents lose adsorption capacity when operated under unfavourable hydrothermal conditions during adsorption and desorption. The stability of an adsorbent against stressing hydrothermal conditions is a key issue for its usability in adsorption thermal energy storage. We built an experimental setup that simultaneously controls the hydrothermal conditions of 16 samples arranged in a matrix of four temperatures and four water vapour pressures. This setup allows the testing of potential adsorbents between temperatures of 50 °C and 350 °C and water vapour pressures of up to 32 kPa. A measurement procedure that allows the detection of the hydrothermal stability of an adsorbent after defined time spans has been designed. We verified the functionality of the multiple sample measurements with a microporous adsorbent, a zeolite NaMSX. The hydrothermal stability of this zeolite is tested by water uptake measurements. A standard deviation lower than 1% of the 16 samples for detecting the hydrothermal stability enables setting different conditions in each sample cell. Further, we compared the water uptake measurements by measuring their adsorption isotherms with the volumetric device BELSORP Aqua 3 from Bel Japan.

  11. Thermal Analysis of a Solar Powered Absorption Cooling System with Fully Mixed Thermal Storage at Startup

    Directory of Open Access Journals (Sweden)

    Camelia Stanciu

    2017-01-01

    Full Text Available A simple effect one stage ammonia-water absorption cooling system fueled by solar energy is analyzed. The considered system is composed by a parabolic trough collector concentrating solar energy into a tubular receiver for heating water. This is stored in a fully mixed thermal storage tank and used in the vapor generator of the absorption cooling system. Time dependent cooling load is considered for the air conditioning of a residential two-storey house. A parametric study is performed to analyze the operation stability of the cooling system with respect to solar collector and storage tank dimensions. The results emphasized that there is a specific storage tank dimension associated to a specific solar collector dimension that could ensure the longest continuous startup operation of the cooling system when constant mass flow rates inside the system are assumed.

  12. Temperature-dependent thermal properties of spark plasma sintered alumina

    Directory of Open Access Journals (Sweden)

    Saheb Nouari

    2017-01-01

    Full Text Available In this work, we report temperature-dependent thermal properties of alumina powder and bulk alumina consolidated by spark plasma sintering method. The properties were measured between room temperature and 250ºC using a thermal constants analyzer. Alumina powder had very low thermal properties due to the presence of large pores and absence of bonding between its particles. Fully dense alumina with a relative density of 99.6 % was obtained at a sintering temperature of 1400°C and a holding time of 10 min. Thermal properties were found to mainly dependent on density. Thermal conductivity, thermal diffusivity, and specific heat of the fully dense alumina were 34.44 W/mK, 7.62 mm2s-1, and 1.22 J/gK, respectively, at room temperature. Thermal conductivity and thermal diffusivity decreased while specific heat increased with the increase in temperature from room temperature to 250ºC.

  13. Parametric study of thermal storage containing rocks or fluid filled cans for solar heating and cooling, phase 2

    Science.gov (United States)

    Saha, H.

    1981-01-01

    The test data and an analysis of the heat transfer characteristics of a solar thermal energy storage bed utilizing water filled cans and standard bricks as energy storage medium are presented. This experimental investigation was initiated to find a usable heat intensive solar thermal storage device other than rock storage and water tank. Four different sizes of soup cans were stacked in a chamber in three different arrangements-vertical, horizontal, and random. Air is used as transfer medium for charging and discharge modes at three different mass flow rates and inlet air temperature respectively. These results are analyzed and compared, which show that a vertical stacking and medium size cans with Length/Diameter (L/D) ratio close to one have better average characteristics of heat transfer and pressure drop.

  14. Thermal energy storage using Prestressed Cast Iron Vessels (PCIV). Final report

    Energy Technology Data Exchange (ETDEWEB)

    Gilli, P.V.; Beckmann, G.; Schilling, F.E.

    1977-06-01

    The wide-spread application of thermal energy and high-pressure air storage to electric power generation has so far been hampered by the lack of large high-pressure storage vessels of reasonable cost. Welded steel vessels are too expensive for this purpose. However, the Prestressed Cast Iron Vessel (PCIV), developed as a nuclear reactor pressure vessel by Siempelkamp Giesserei KG of Krefeld, FRG, has the potential of complying with these requirements. Applications of the PCIV include: high-pressure air storage for the quick start-up of open cycle gas turbines; pressurized high-temperature sensible heat storage by means of solids with a gaseous heat transfer medium for closed cycle gas turbines of future solar power stations; and pressurized hot water storage for nuclear, solar, or coal-fired steam power plants, employing either separate peaking turbines or overloadable main turbine sets. A reference PCIV of 8000 m/sup 3/, 275/sup 0/C, with hot going walls and cold going tendons was developed, designed, and stress-analysed. A parametric study showed that pressures between 4 and 8 MPa and L/D ratios larger than 4 should be optimal. Cost of the reference vessel is about $10,000,000 or 33 to 50 $/kWh electric energy stored. Cost of peak power will be from 30 to 100 mills/kWh, depending on many parameters.

  15. Optimization of a class of latent thermal energy storage systems with multiple phase-change materials

    Energy Technology Data Exchange (ETDEWEB)

    Aceves, S.M. [Lawrence Livermore National Lab., CA (United States); Nakamura, H. [Daido Inst. of Tech., Nagoya (Japan). Dept. of Mechanical Engineering; Reistad, G.M. [Oregon State Univ., Corvallis, OR (United States). Dept. of Mechanical Engineering; Martinez-Frias, J. [Centro de Ingenieria y Desarollo Industrial, Queretaro (Mexico)

    1998-02-01

    This paper presents an analysis of a class of latent thermal energy storage (LTES) system. The analysis is based on a simplified model that allows the system performance to be evaluated in terms of a small set of parameters, while still retaining the main thermodynamic aspects associated with their operation. This analysis therefore permits the broad-based application potential of these systems to be viewed. The paper also discusses the applicability of the model to practical systems. This paper analyzes LTES with multiple energy storage cells and multiple phase-change materials (PCMs). The most general case of infinite energy storage cells and PCMs is solved, for the charge process only, as well as for the overall charge-discharge process. The results yield the optimum phase change temperature, expressed as a continuous function of position along the LTES. The method is equally applicable to the case of a finite number of storage cells. An example of the application of the method to this case is also included. The results show the optimum phase change temperatures for each of the problems being considered, along with the corresponding optimum exergetic efficiencies. The solutions to the optimization problems are surprisingly simple to express, considering the difficulty of the problems, and indicate the potential advantages of using LTES with multiple PCMs.

  16. Optimization of Storage Temperature for Cultured ARPE-19 Cells

    Directory of Open Access Journals (Sweden)

    Lara Pasovic

    2013-01-01

    Full Text Available Purpose. The establishment of future retinal pigment epithelium (RPE replacement therapy is partly dependent on the availability of tissue-engineered RPE cells, which may be enhanced by the development of suitable storage methods for RPE. This study investigates the effect of different storage temperatures on the viability, morphology, and phenotype of cultured RPE. Methods. ARPE-19 cells were cultured under standard conditions and stored in HEPES-buffered MEM at nine temperatures (4°C, 8°C, 12°C, 16°C, 20°C, 24°C, 28°C, 32°C, and 37°C for seven days. Viability and phenotype were assessed by a microplate fluorometer and epifluorescence microscopy, while morphology was analyzed by scanning electron microscopy. Results. The percentage of viable cells preserved after storage was highest in the 16°C group (48.7%±9.8%; P<0.01 compared to 4°C, 8°C, and 24°C–37°C; P<0.05 compared to 12°C. Ultrastructure was best preserved at 12°C, 16°C, and 20°C. Expression of actin, ZO-1, PCNA, caspase-3, and RPE65 was maintained after storage at 16°C compared to control cells that were not stored. Conclusion. Out of nine temperatures tested between 4°C and 37°C, storage at 12°C, 16°C, and 20°C was optimal for maintenance of RPE cell viability, morphology, and phenotype. The preservation of RPE cells is critically dependent on storage temperature.

  17. Influence of storage temperatures on physicochemical sensory and ...

    African Journals Online (AJOL)

    Storage stability of mango pulp (Mp) was determined at room (r) 25 to 35°C and refrigerated (ref) 4°C with the addition of potassium sorbate (PS), sodium benzoate (SB) and potassium metabisulphite (PMS). The statistical analysis viz factorial analysis and least significant square design (LSD) verified the temperatures effect ...

  18. Effect of home-refrigerator storage temperature on tomato quality

    NARCIS (Netherlands)

    Farneti, B.; Zhang, W.; Witkowska, I.M.; Woltering, E.J.

    2010-01-01

    Postharvest storage, handling and distribution of fruit at low temperatures is the most common and manageable approach to control ripening and subsequent deterioration and to maximize product shelf-life. However, tomatoes, as many other subtropical fruits, are susceptible to develop symptoms of

  19. Recommended temperature and relative humidity for storage of ...

    African Journals Online (AJOL)

    Post-harvest treatment and proper handling is essential so that the flowers can maintain their quality during marketing and exporting. This review aims to gives information on the storage temperature used in postharvest handling of tropical flowers of Brazil. This review provides detailed specifications and recommendations ...

  20. Effects of storage temperature on the quantity and integrity of ...

    African Journals Online (AJOL)

    Effects of storage temperature on the quantity and integrity of genomic DNA extracted from mice tissues: A comparison of recovery methods. ... and NucleoSpin® Blood and Tissue kit found to be appropriate for yielding high quantity of gDNA, with the Chelex®100 method yielding a greater quantity (P < 0.045) than the kit.

  1. Influence of different storage times and temperatures on blood gas ...

    African Journals Online (AJOL)

    The present study was designed to investigate the effects of storage temperature and time on blood gas and acid-base balance of ovine venous blood. Ten clinically healthy sheep were used in this study. A total number of 30 blood samples, were divided into three different groups, and were stored in a refrigerator adjusted ...

  2. Whey protein concentrate storage at elevated temperature and humidity

    Science.gov (United States)

    Dairy processors are finding new export markets for whey protein concentrate (WPC), a byproduct of cheesemaking, but they need to know if full-sized bags of this powder will withstand high temperature and relative humidity (RH) levels during unrefrigerated storage under tropical conditions. To answ...

  3. Effects of temperature, light, desiccation and cold storage on ...

    African Journals Online (AJOL)

    ... on the seeds desiccated to 5.4 ± 0.1% moisture content. These results suggest an intermediate seed storage behaviour. For germplasm long-term conservation purpose, a cryopreservation investigation was proposed. Key words: Seed, desiccation tolerance, low temperature tolerance, germination, Sophora tonkinensis.

  4. Thermal stress analysis of the fuel storage facility

    Energy Technology Data Exchange (ETDEWEB)

    Chen, W.W.

    1991-12-01

    This paper presents the results of a nonlinear finite-element analysis to determine the structural integrity of the walls of the nuclear fuel storage room in the Radio Isotope Power System Facility of the Fuels and Materials Examination Facility (FMEF) Project. The analysis was performed to assess the effects of thermal loading on the walls that would result from a loss-of-cooling accident. The results obtained from using the same three-dimensional finite-element model with different types of elements, the eight-node brick element and the nonlinear concrete element, and the calculated results using the analytical solutions, are compared. The concrete responses in terms of octahedral normal and shearing stresses are described. The crack and crush states of the concrete were determined on the basis of multiaxial failure criteria.

  5. Development of Hollow Steel Ball Macro-Encapsulated PCM for Thermal Energy Storage Concrete.

    Science.gov (United States)

    Dong, Zhijun; Cui, Hongzhi; Tang, Waiching; Chen, Dazhu; Wen, Haibo

    2016-01-19

    The application of thermal energy storage with phase change materials (PCMs) for energy efficiency of buildings grew rapidly in the last few years. In this research, octadecane paraffin was served as a PCM, and a structural concrete with the function of indoor temperature control was developed by using a macro-encapsulated PCM hollow steel ball (HSB). The macro-encapsulated PCM-HSB was prepared by incorporation of octadecane into HSBs through vacuum impregnation. Test results showed that the maximum percentage of octadecane carried by HSBs was 80.3% by mass. The macro-encapsulated PCM-HSB has a latent heat storage capacity as high as 200.5 J/g. The compressive strength of concrete with macro-encapsulated PCM-HSB at 28 days ranged from 22 to 40 MPa. The indoor thermal performance test revealed that concrete with macro-encapsulated octadecane-HSB was capable of reducing the peak indoor air temperature and the fluctuation of indoor temperature. It can be very effective in transferring the heating and cooling loads away from the peak demand times.

  6. Development of Hollow Steel Ball Macro-Encapsulated PCM for Thermal Energy Storage Concrete

    Directory of Open Access Journals (Sweden)

    Zhijun Dong

    2016-01-01

    Full Text Available The application of thermal energy storage with phase change materials (PCMs for energy efficiency of buildings grew rapidly in the last few years. In this research, octadecane paraffin was served as a PCM, and a structural concrete with the function of indoor temperature control was developed by using a macro-encapsulated PCM hollow steel ball (HSB. The macro-encapsulated PCM-HSB was prepared by incorporation of octadecane into HSBs through vacuum impregnation. Test results showed that the maximum percentage of octadecane carried by HSBs was 80.3% by mass. The macro-encapsulated PCM-HSB has a latent heat storage capacity as high as 200.5 J/g. The compressive strength of concrete with macro-encapsulated PCM-HSB at 28 days ranged from 22 to 40 MPa. The indoor thermal performance test revealed that concrete with macro-encapsulated octadecane-HSB was capable of reducing the peak indoor air temperature and the fluctuation of indoor temperature. It can be very effective in transferring the heating and cooling loads away from the peak demand times.

  7. Hydrogen storage by adsorption on activated carbon: Investigation of the thermal effects during the charging process

    Energy Technology Data Exchange (ETDEWEB)

    Hermosilla-Lara, G. [Laboratoire d' Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311-Universite Paris 13, 93430 Villetaneuse (France); Laboratoire des Ecoulements Geophysiques et Industriels, BP 53, 38041 Grenoble Cedex 9 (France); Momen, G.; Le Neindre, B.; Hassouni, K. [Laboratoire d' Ingenierie des Materiaux et des Hautes Pressions, CNRS UPR 1311-Universite Paris 13, 93430 Villetaneuse (France); Marty, P.H. [Laboratoire des Ecoulements Geophysiques et Industriels, BP 53, 38041 Grenoble Cedex 9 (France)

    2007-07-15

    This paper presents an investigation of the thermal effects during high-pressure charging of a packed bed hydrogen storage tank. The studied column is packed with activated IRH3 carbon, which has an average surface area of 2600m{sup 2}g{sup -1} and is fed with hydrogen or helium from an external high-pressure source. The temperature at six locations in the storage tank and the pressure value at the bottom of the tank are recorded during the charging stage. Several experiments were carried out to investigate the effect of the initial flow rate on the temperature field in the reservoir and on the duration of the charging process. A study of the respective contribution of adsorption and mechanical dissipation effects to the thermal phenomena is done in the case of hydrogen. Experimental results are compared to those obtained with the commercial code Fluent. A fair agreement is found when comparing typical pressure and temperature evolutions during the tank filling. (author)

  8. Temperature Sensitive Nanocapsule of Complex Structural Form for Methane Storage

    Directory of Open Access Journals (Sweden)

    Suyetin MV

    2009-01-01

    Full Text Available Abstract The processes of methane adsorption, storage and desorption by the nanocapsule are investigated with molecular-dynamic modeling method. The specific nanocapsule shape defines its functioning uniqueness: methane is adsorbed under 40 MPa and at normal temperature with further blocking of methane molecules the K@C601+ endohedral complex in the nanocapsule by external electric field, the storage is performed under normal external conditions, and methane desorption is performed at 350 K. The methane content in the nanocapsule during storage reaches 11.09 mass%. The nanocapsule consists of tree parts: storage chamber, junction and blocking chamber. The storage chamber comprises the nanotube (20,20. The blocking chamber is a short nanotube (20,20 with three holes. The junction consists of the nanotube (10,10 and nanotube (8,8; moreover, the nanotube (8,8 is connected with the storage chamber and nanotube (10,10 with the blocking chamber. The blocking chamber is opened and closed by the transfer of the K@C60 1+ endohedral complex under electrostatic field action.

  9. Active heat exchange: System development for latent heat thermal energy storage

    Science.gov (United States)

    Alario, J.; Haslett, R.

    1981-03-01

    An active heat exchange method in a latent heat (salt) thermal energy storage system that prevents a low conductivity solid salt layer from forming on heat transfer surfaces was developed. An evaluation of suitable media with melting points in the temperature range of interest (250 to 400 C) limited the candidates to molten salts from the chloride, hydroxide, and nitrate families, based on high storage capacity, good corrosion characteristics, and availability in large quantities at reasonable cost. The specific salt recommended for laboratory tests was a choride eutectic (20.5KCl, 24.5NaCl, 55.0MgCl2 percent by wt.), with a nominal melting point of 385 C.

  10. Phase change material solidification in a finned cylindrical shell thermal energy storage: An approximate analytical approach

    Directory of Open Access Journals (Sweden)

    Mosaffa Amirhossein

    2013-01-01

    Full Text Available Results are reported of an investigation of the solidification of a phase change material (PCM in a cylindrical shell thermal energy storage with radial internal fins. An approximate analytical solution is presented for two cases. In case 1, the inner wall is kept at a constant temperature and, in case 2, a constant heat flux is imposed on the inner wall. In both cases, the outer wall is insulated. The results are compared to those for a numerical approach based on an enthalpy method. The results show that the analytical model satisfactory estimates the solid-liquid interface. In addition, a comparative study is reported of the solidified fraction of encapsulated PCM for different geometric configurations of finned storage having the same volume and surface area of heat transfer.

  11. High resolution numerical modelling of high temperature heat storage in geological media

    Science.gov (United States)

    Boockmeyer, Anke; Bauer, Sebastian

    2014-05-01

    Increasing use of energy stemming from renewable sources, such as wind or solar power plants, requires development of new and improvement of existing energy storage options on different time scales. One potential storage option is high temperature heat storage with temperatures of up to 100°C in the geological subsurface using borehole heat exchanger (BHE). Numerical scenario simulations are performed to assess feasibility and storage capacity and, furthermore, to predict the effects induced. To allow for accurate and reliable results, the BHE must be represented correctly and realistic in the numerical model. Therefore, a detailed model of a single BHE and the surrounding aquifer, accounting for the full geometry and component parametrisation (circulating working fluid, pipe and grout), is set up. This model setup is used to simulate an experimental data set from a laboratory sandbox by Beier et al. (2011), containing an 18 m long single U-tube BHE centered horizontally along it. Temperature curves observed in different radial distances as well as at the pipe outflow can be matched well with the model setup used, which is thus verified. Potential geological formations for high temperature heat storage are located in greater depths below fresh water aquifers that are used for drinking water. Therefore, the above model is adapted to represent a 100 m long vertical double U-tube BHE placed in an average depth of 500 m. The processes of heat transport and groundwater flow are coupled by water density and viscosity, which both depend on pressure and temperature. A sensitivity study is done to quantify the effects of the thermal parameters of grout and aquifer on the amount of heat stored and the temperature distribution in the aquifer. It was found that the amount of heat stored through the BHE is most sensitive to the heat conductivity of the aquifer. Increasing the aquifer heat conductivity by 50 % increases the amount of heat stored in the numerical model by 30

  12. Technical and economic feasibility of thermal energy storage. Thermal energy storage application to the brick/ceramic industry. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Glenn, D.R.

    1976-10-01

    An initial project to study the technical and economic feasibility of thermal energy storage (TES) in the three major consumer markets, namely, the residential, commercial and industrial sectors is described. A major objective of the study was to identify viable TES applications from which a more concise study could be launched, leading to a conceptual design and in-depth validation of the TES energy impacts. This report documents one such program. The brick/ceramic industries commonly use periodic kilns which by their operating cycle require time-variant energy supply and consequently variable heat rejection. This application was one of the numerous TES opportunities that emerged from the first study, now available from the ERDA Technical Information Center, Oak Ridge, Tennessee, identified as Report No. COO-2558-1.

  13. Mars Propellant Liquefaction and Storage Performance Modeling using Thermal Desktop with an Integrated Cryocooler Model

    Science.gov (United States)

    Desai, Pooja; Hauser, Dan; Sutherlin, Steven

    2017-01-01

    NASAs current Mars architectures are assuming the production and storage of 23 tons of liquid oxygen on the surface of Mars over a duration of 500+ days. In order to do this in a mass efficient manner, an energy efficient refrigeration system will be required. Based on previous analysis NASA has decided to do all liquefaction in the propulsion vehicle storage tanks. In order to allow for transient Martian environmental effects, a propellant liquefaction and storage system for a Mars Ascent Vehicle (MAV) was modeled using Thermal Desktop. The model consisted of a propellant tank containing a broad area cooling loop heat exchanger integrated with a reverse turbo Brayton cryocooler. Cryocooler sizing and performance modeling was conducted using MAV diurnal heat loads and radiator rejection temperatures predicted from a previous thermal model of the MAV. A system was also sized and modeled using an alternative heat rejection system that relies on a forced convection heat exchanger. Cryocooler mass, input power, and heat rejection for both systems were estimated and compared against sizing based on non-transient sizing estimates.

  14. Investigation of small scale solar concentration parabolic dish with heat storage: (low to medium temperature application

    Energy Technology Data Exchange (ETDEWEB)

    Madessa, Habtamu Bayera

    2012-07-01

    This PhD thesis focuses on the development and testing of a small scale concentrating parabolic dish with heat storage for low to medium temperature applications. The system consists of a parabolic dish solar concentrator that concentrates solar radiation, a fibrous mat solar absorber that captures concentrated solar rays and converts them to thermal energy and a packed bed with pebble rock as a thermal energy storage unit. This research has targeted several issues in which there is a lack of knowledge on small scale concentrating solar energy technologies, with the work summarized in eight papers. Paper 1 concerns experimental measurement of the dynamic temperature profiles along a rock bed heat storage unit during thermal charging and degradation. The study examined both finned and non-finned types of rock bed storages. The effects of the long fins. which are incorporated to transport heat from the bottom to the top surface of the heat storage, were investigated in relation to temperature distribution. As an extension of Paper 1, the performance of a rock bed fitted with long fins was studied as a heat storage unit and a cooking device. The bed charging efficiency, as well as the capacity to store thermal energy and extract heat for boiling of water was discussed. Paper 3 describes the implemention of a 1D numerical model in the MATLAB environment to simulate the transient temperature profiles of rock bed heat storage units. Conservation equations were formulated for the air, rock pebble and fins. The equations were solved on a staggered grid, and the model predicts the experimental results reasonably well. The thesis also investigates two types of volumetric solar absorbers (a fibrous wire mesh and a ceramic) that could be incorporated with a small scale solar concentrating parabolic dish system. Both the fibrous mesh and ceramic type absorbers display a better performance, as discussed in Paper 4. Another contribution of the PhD work is to investigate a 1D sun

  15. Analysis of Large- Capacity Water Heaters in Electric Thermal Storage Programs

    Energy Technology Data Exchange (ETDEWEB)

    Cooke, Alan L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Anderson, David M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Winiarski, David W. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Carmichael, Robert T. [Cadeo Group, Washington D. C. (United States); Mayhorn, Ebony T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Fisher, Andrew R. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-03-17

    This report documents a national impact analysis of large tank heat pump water heaters (HPWH) in electric thermal storage (ETS) programs and conveys the findings related to concerns raised by utilities regarding the ability of large-tank heat pump water heaters to provide electric thermal storage services.

  16. An improved method for upscaling borehole thermal energy storage using inverse finite element modelling

    DEFF Research Database (Denmark)

    Tordrup, Karl Woldum; Poulsen, Søren Erbs; Bjørn, Henrik

    2017-01-01

    Dimensioning of large-scale borehole thermal energy storage (BTES) is inherently uncertain due to the natural variability of thermal conductivity and heat capacity in the storage volume. We present an improved method for upscaling a pilot BTES to full scale and apply the method to an operational...

  17. IEA SHC Task 42 / ECES Annex 29 - Working Group B: Applications of Compact Thermal Energy Storage

    NARCIS (Netherlands)

    Helden, W. van; Yamaha, M.; Rathgeber, C.; Hauer, A.; Huaylla, F.; Le Pierrès, N.; Stutz, B.; Mette, B.; Dolado, P.; Lazaro, A.; Mazo, J.; Dannemand, M.; Furbo, S.; Campos-Celador, A.; Diarce, G.; Cuypers, R.; König-Haagen, A.; Höhlein, S.; Brüggemann, D.; Fumey, B.; Weber, R.; Köll, R.; Wagner, W.; Daguenet-Frick, X.; Gantenbein, P.; Kuznik, F.

    2016-01-01

    The IEA joint Task 42 / Annex 29 is aimed at developing compact thermal energy storage materials and systems. In Working Group B, experts are working on the development of compact thermal energy storage applications, in the areas cooling, domestic heating and hot water and industry. The majority of

  18. Solar Pilot Plant, Phase I. Preliminary design report. Volume V. Thermal storage subsystem. CDRL item 2

    Energy Technology Data Exchange (ETDEWEB)

    None

    1977-05-01

    Design, specifications, and diagrams for the thermal storage subsystem for the 10-MW pilot tower focus power plant are presented in detail. The Honeywell thermal storage subsystem design features a sensible heat storage arrangement using proven equipment and materials. The subsystem consists of a main storage containing oil and rock, two buried superheater tanks containing inorganic salts (Hitec), and the necessary piping, instrumentation, controls, and safety devices. The subsystem can provide 7 MW(e) for three hours after twenty hours of hold. It can be charged in approximately four hours. Storage for the commercial-scale plant consists of the same elements appropriately scaled up. Performance analysis and tradeoff studies are included.

  19. Thermal energy storage system using phase change materials: Constant heat source

    Directory of Open Access Journals (Sweden)

    Reddy Meenakshi R.

    2012-01-01

    Full Text Available The usage of phase change materials (PCM to store the heat in the form of latent heat is increased, because large quantity of thermal energy is stored in smaller volumes. In the present experimental investigation paraffin and stearic acid are employed as PCMs in thermal energy storage (TES system to store the heat as sensible and latent heat also. A constant heat source is used to supply heat transfer fluid (HTF at constant temperature to the TES system. In the TES system PCMs are stored in the form of spherical capsules of 38 mm diameter made of high density poly ethylene (HDPE. The results of the investigation are related to the charging time and recovery of stored energy from the TES system.

  20. A temperature dependent slip factor based thermal model for friction ...

    Indian Academy of Sciences (India)

    This paper proposes a new slip factor based three-dimensional thermal model to predict the temperature distribution during friction stir welding of 304L stainless steel plates. The proposed model employs temperature and radius dependent heat source to study the thermal cycle, temperature distribution, power required, the ...

  1. A temperature dependent slip factor based thermal model for friction ...

    Indian Academy of Sciences (India)

    Abstract. This paper proposes a new slip factor based three-dimensional thermal model to predict the temperature distribution during friction stir welding of 304L stainless steel plates. The proposed model employs temperature and radius dependent heat source to study the thermal cycle, temperature distribution, power ...

  2. Performance Evaluation of Various Phase Change Materials for Thermal Energy Storage of A Solar Cooker via Numerical Simulation

    Directory of Open Access Journals (Sweden)

    Dede Tarwidi

    2016-11-01

    Full Text Available In this paper, thermal performance of various phase change materials (PCMs used as thermal energy storage in a solar cooker has been investigated numerically. Heat conduction equations in cylindrical domain are used to model heat transfer of the PCMs. Mathematical model of phase change problem in the PCM storage encompasses heat conduction equations in solid and liquid region separated by moving solid-liquid interface. The phase change problem is solved by reformulating heat conduction equations with emergence of moving boundary into an enthalpy equation. Numerical solution of the enthalpy equation is obtained by implementing Godunov method and verified by analytical solution of one-dimensional case. Stability condition of the numerical scheme is also discussed. Thermal performance of various PCMs is evaluated via the stored energy and temperature history. The simulation results show that phase change material with the best thermal performance during the first 2.5 hours of energy extraction is shown by erythritol. Moreover, magnesium chloride hexahydrate can maintain temperature of the PCM storage in the range of 110-116.7°C for more than 4 hours while magnesium nitrate hexahydrate is effective only for one hour with the PCM storage temperature around 121-128°C. Among the PCMs that have been tested, it is only erythritol that can cook 10 kg of the loaded water until it reaches 100°C for about 3.5 hours. Article History: Received June 22nd 2016; Received in revised form August 26th 2016; Accepted Sept 1st 2016; Available online How to Cite This Article: Tarwidi, D., Murdiansyah, D.T, Ginanja, N. (2016 Performance Evaluation of Various Phase Change Materials for Thermal Energy Storage of A Solar Cooker via Numerical Simulation. Int. Journal of Renewable Energy Development, 5(3, 199-210. http://dx.doi.org/10.14710/ijred.5.3.199-210

  3. Program definition and assessment overview. [for thermal energy storage project management

    Science.gov (United States)

    Gordon, L. H.

    1980-01-01

    The implementation of a program level assessment of thermal energy storage technology thrusts for the near and far term to assure overall coherent energy storage program is considered. The identification and definition of potential thermal energy storage applications, definition of technology requirements, and appropriate market sectors are discussed along with the necessary coordination, planning, and preparation associated with program reviews, workshops, multi-year plans and annual operating plans for the major laboratory tasks.

  4. Research and Development for Novel Thermal Energy Storage Systems (TES) for Concentrating Solar Power (CSP)

    Energy Technology Data Exchange (ETDEWEB)

    Faghri, Amir; Bergman, Theodore L; Pitchumani, Ranga

    2013-09-26

    The overall objective was to develop innovative heat transfer devices and methodologies for novel thermal energy storage systems for concentrating solar power generation involving phase change materials (PCMs). Specific objectives included embedding thermosyphons and/or heat pipes (TS/HPs) within appropriate phase change materials to significantly reduce thermal resistances within the thermal energy storage system of a large-scale concentrating solar power plant and, in turn, improve performance of the plant. Experimental, system level and detailed comprehensive modeling approaches were taken to investigate the effect of adding TS/HPs on the performance of latent heat thermal energy storage (LHTES) systems.

  5. Thermocline thermal storage systems for concentrated solar power plants: One-dimensional numerical model and comparative analysis

    DEFF Research Database (Denmark)

    Modi, Anish; Pérez-Segarra, Carlos David

    2014-01-01

    Concentrated solar power plants have attracted increasing interest from researchers and governments all over the world in recent years. An important part of these plants is the storage system which improves dispatchability and makes the plant more reliable. In this paper, a one...... designing the power cycle for concentrated solar power applications. It was also observed that the cycle durations and the time required to attain cyclic conditions are highly sensitive to not only the storage temperature difference, but also the cut-off temperature difference. © 2013 Elsevier Ltd.......-dimensional transient mathematical model for a single-tank thermocline thermal energy storage system is presented. The model used temperature dependent correlations to obtain the thermophysical properties for the heat transfer fluid and considered heat loss through the tank wall. The effect of variation in important...

  6. Buffer storage of thermal energy using the reaction heat of the system calcium oxide/calcium hydroxide

    Science.gov (United States)

    Lehmann, B.

    1986-12-01

    The reaction heat of the system CaO/Ca(OH)2 was investigated as storage effect for thermal energy. The heat from the chemical system is used as a buffer facility for thermal energy, i.e., sensible heat is stored without thermal losses to the environment. In the forward reaction by adding water to the CaO, sensible heat is released, which can be used for heating houses or water, and for generation of steam for industrial purposes. The necessary heat to be fed to the Ca(OH)2 in order to run the reaction inversely can be supplied by solar collector, high temperature reactors, geothermal energy, or combustion of wastes. Heat at temperatures less than 450 C has to be furnished for the loading phase of the reaction. The discharging reaction delivers temperatures up to 400 C. A gas loop was designed, built, and operated to test this kind of heat storage. The quantities which determine the storage and release of energy were deduced and documented. Pressure drops and storage mass behavior are discussed.

  7. Thermal stability, storage and release of proteins with tailored fit in silica

    Science.gov (United States)

    Chen, Yun-Chu; Smith, Tristan; Hicks, Robert H.; Doekhie, Aswin; Koumanov, Francoise; Wells, Stephen A.; Edler, Karen J.; van den Elsen, Jean; Holman, Geoffrey D.; Marchbank, Kevin J.; Sartbaeva, Asel

    2017-04-01

    Biological substances based on proteins, including vaccines, antibodies, and enzymes, typically degrade at room temperature over time due to denaturation, as proteins unfold with loss of secondary and tertiary structure. Their storage and distribution therefore relies on a “cold chain” of continuous refrigeration; this is costly and not always effective, as any break in the chain leads to rapid loss of effectiveness and potency. Efforts have been made to make vaccines thermally stable using treatments including freeze-drying (lyophilisation), biomineralisation, and encapsulation in sugar glass and organic polymers. Here for the first time we show that proteins can be enclosed in a deposited silica “cage”, rendering them stable against denaturing thermal treatment and long-term ambient-temperature storage, and subsequently released into solution with their structure and function intact. This “ensilication” method produces a storable solid protein-loaded material without the need for desiccation or freeze-drying. Ensilication offers the prospect of a solution to the “cold chain” problem for biological materials, in particular for vaccines.

  8. Numerical thermal back-calculation of the Kerava Solar Village underground thermal energy storage

    OpenAIRE

    Oosterbaan, Harm; Janiszewski, Mateusz; Uotinen, Lauri; Siren, Topias; Rinne, Mikael

    2017-01-01

    With increasing pressure to reduce the fraction of energy coming from fossil fuels, there is an increased need for research into feasible, and sustainable energy sources, such as solar energy. The problem with solar energy is the mismatch between supply and demand, and so the energy needs to be stored. This research paper is a part of the project titled “Tackling the Challenges of a Solar-Community Concept in High Latitudes”, and aims in helping to design a thermal energy storage system for s...

  9. Heat conductivity of high-temperature thermal insulators

    Science.gov (United States)

    Kharlamov, A. G.

    The book deals essentially with the mechanisms of heat transfer by conduction, convection, and thermal radiation in absorbing and transmitting media. Particular attention is given to materials for gas-cooled reactor systems, the temperature dependent conductivities of high-temperature insulations in vacuum, and the thermal conductivities of MgO, Al2O3, ZrO2, and other powders at temperatures up to 2000 C. The thermal conductivity of pyrolitic graphite and graphite foam are studied.

  10. Evaluation of thermal energy storage for the proposed Twin Cities District Heating system. [using cogeneration heat production and aquifiers for heat storage

    Science.gov (United States)

    Meyer, C. F.

    1980-01-01

    The technical and economic feasibility of incorporating thermal energy storage components into the proposed Twin Cities District heating project was evaluated. The technical status of the project is reviewed and conceptual designs of district heating systems with and without thermal energy storage were compared in terms of estimated capital requirements, fuel consumption, delivered energy cost, and environmental aspects. The thermal energy storage system is based on cogeneration and the storage of heat in aquifers.

  11. influence of storage temperatures on physicochemical sensory and ...

    African Journals Online (AJOL)

    E-Shop

    2012-02-14

    Feb 14, 2012 ... values for pH decreased from 4.34 (T0) to 3.20 (T7r) during 60 and 3.00 (T2ref) in 90 days of storage. Less decrease was observed in pH for temperatures effect on treatments in refrigerated samples, T5ref, T3ref and T7ref having values 4.26 and 4.24. According to overall treatment means, T5 showed less ...

  12. Phase change material for temperature control and material storage

    Science.gov (United States)

    Wessling, Jr., Francis C. (Inventor); Blackwood, James M. (Inventor)

    2011-01-01

    A phase change material comprising a mixture of water and deuterium oxide is described, wherein the mole fraction of deuterium oxide is selected so that the mixture has a selected phase change temperature within a range between 0.degree. C. and 4.degree. C. The mixture is placed in a container and used for passive storage and transport of biomaterials and other temperature sensitive materials. Gels, nucleating agents, freezing point depression materials and colorants may be added to enhance the characteristics of the mixture.

  13. Reactive transport modeling of thermal column experiments to investigate the impacts of aquifer thermal energy storage on groundwater quality.

    Science.gov (United States)

    Bonte, Matthijs; Stuyfzand, Pieter J; Breukelen, Boris M van

    2014-10-21

    Aquifer thermal energy storage (ATES) systems are increasingly being used to acclimatize buildings and are often constructed in aquifers used for drinking water supply. This raises the question of potential groundwater quality impact. Here, we use laboratory column experiments to develop and calibrate a reactive transport model (PHREEQC) simulating the thermally induced (5-60 °C) water quality changes in anoxic sandy sediments. Temperature-dependent surface complexation, cation-exchange, and kinetic dissolution of K-feldspar were included in the model. Optimization results combined with an extensive literature survey showed surface complexation of (oxy)anions (As, B, and PO4) is consistently exothermic, whereas surface complexation of cations (Ca and Mg) and cationic heavy metals (Cd, Pb, and Zn) is endothermic. The calibrated model was applied to simulate arsenic mobility in an ATES system using a simple yet powerful mirrored axi-symmetrical grid. Results showed that ATES mobilizes arsenic toward the fringe of the warm water bubble and the center of the cold water bubble. This transient redistribution of arsenic causes its aqueous concentrations in the cold and warm groundwater bubbles to become similar through multiple heating cycles, with a final concentration depending on the average injection temperature of the warm and cold ATES wells.

  14. A numerical study of latent thermal energy storage in a phase change material/carbon panel

    Energy Technology Data Exchange (ETDEWEB)

    Mekaddem, Najoua, E-mail: mekaddem.najoua@gmail.com; Ali, Samia Ben, E-mail: samia.benali@enig.rnu.tn; Hannachi, Ahmed, E-mail: ahmed.hannachi@enig.rnu.tn [Research Laboratory of Process Engineering and Industrial Systems, National Engineering School of Gabes (Tunisia); Mazioud, Atef, E-mail: mazioud@u-pec.fr [IUT Senart, Department of Industrial Engineering and Maintenance, University Paris-Est (France)

    2016-07-25

    To reduce the energetic dependence of building, it has become necessary to explore and develop new materials promoting energy conservation. Because of their high storage capacity, phase change materials (PCMs) are efficient to store thermal energy. In this paper, a 3D model was studied for simulation of energy storing cycles to predict the performances of PCM loaded panels. Carbon was used as supporting material for the PCM. The simulation was based on the enthalpy method using Ansys Fluent software. The panel was exposed to a daily heat flow including the effects of convection and radiation. The results show that the temperature decreased of approximately 2.5°C with a time shift about 2 hours. The steady state was reached after four cycles. Thus, after four cycles the PCM showed its effects on the temperature conditioning.

  15. Characteristics of large thermal energy storage systems in Poland

    Science.gov (United States)

    Zwierzchowski, Ryszard

    2017-11-01

    In District Heating Systems (DHS) there are significant fluctuations in demand for heat by consumers during both the heating and the summer seasons. These variations are considered primarily in the 24-hour time horizon. These problems are aggravated further if the DHS is supplied by a CHP plant, because fluctuations in heat demand adversely affect to a significant degree the stable production of electricity at high overall efficiency. Therefore, introducing Thermal Energy Storage (TES) would be highly recommended on these grounds alone. The characteristics of Large (i.e. over 10 000 m3) TES in operation in Poland are presented. Information is given regarding new projects (currently in design or construction) that apply TES technology in DHS in Poland. The paper looks at the methodology used in Poland to select the TES system for a particular DHS, i.e., procedure for calculating capacity of the TES tank and the system to prevent water stored in the tank from absorbing oxygen from atmospheric air. Implementation of TES in DHS is treated as a recommended technology in the Polish District Heating sector. This technology offers great opportunities to improve the operating conditions of DHS, cutting energy production costs and emissions of pollutants to the atmosphere.

  16. Expected benefits of federally-funded thermal energy storage research

    Energy Technology Data Exchange (ETDEWEB)

    Spanner, G.E.; Daellenbach, K.K.; Hughes, K.R.; Brown, D.R.; Drost, M.K.

    1992-09-01

    Pacific Northwest Laboratory (PNL) conducted this study for the Office of Advanced Utility Concepts of the US Department of Energy (DOE). The objective of this study was to develop a series of graphs that depict the long-term benefits of continuing DOE`s thermal energy storage (TES) research program in four sectors: building heating, building cooling, utility power production, and transportation. The study was conducted in three steps- The first step was to assess the maximum possible benefits technically achievable in each sector. In some sectors, the maximum benefit was determined by a ``supply side`` limitation, and in other sectors, the maximum benefit is determined by a ``demand side`` limitation. The second step was to apply economic cost and diffusion models to estimate the benefits that are likely to be achieved by TES under two scenarios: (1) with continuing DOE funding of TES research, and (2) without continued funding. The models all cover the 20-year period from 1990 to 2010. The third step was to prepare graphs that show the maximum technical benefits achievable, the estimated benefits with TES research funding, and the estimated benefits in the absence of TES research funding. The benefits of federally-funded TES research are largely in four areas: displacement of primary energy, displacement of oil and natural gas, reduction in peak electric loads, and emissions reductions.

  17. Relationship of regional water quality to aquifer thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Allen, R.D.

    1983-11-01

    Ground-water quality and associated geologic characteristics may affect the feasibility of aquifer thermal energy storage (ATES) system development in any hydrologic region. This study sought to determine the relationship between ground-water quality parameters and the regional potential for ATES system development. Information was collected from available literature to identify chemical and physical mechanisms that could adversely affect an ATES system. Appropriate beneficiation techniques to counter these potential geochemical and lithologic problems were also identified through the literature search. Regional hydrology summaries and other sources were used in reviewing aquifers of 19 drainage regions in the US to determine generic geochemical characteristics for analysis. Numerical modeling techniques were used to perform geochemical analyses of water quality from 67 selected aquifers. Candidate water resources regions were then identified for exploration and development of ATES. This study identified six principal mechanisms by which ATES reservoir permeability may be impaired: (1) particulate plugging, (2) chemical precipitation, (3) liquid-solid reactions, (4) formation disaggregation, (5) oxidation reactions, and (6) biological activity. Specific proven countermeasures to reduce or eliminate these effects were found. Of the hydrologic regions reviewed, 10 were identified as having the characteristics necessary for ATES development: (1) Mid-Atlantic, (2) South-Atlantic Gulf, (3) Ohio, (4) Upper Mississippi, (5) Lower Mississippi, (6) Souris-Red-Rainy, (7) Missouri Basin, (8) Arkansas-White-Red, (9) Texas-Gulf, and (10) California.

  18. Characteristics of large thermal energy storage systems in Poland

    Directory of Open Access Journals (Sweden)

    Zwierzchowski Ryszard

    2017-01-01

    Full Text Available In District Heating Systems (DHS there are significant fluctuations in demand for heat by consumers during both the heating and the summer seasons. These variations are considered primarily in the 24-hour time horizon. These problems are aggravated further if the DHS is supplied by a CHP plant, because fluctuations in heat demand adversely affect to a significant degree the stable production of electricity at high overall efficiency. Therefore, introducing Thermal Energy Storage (TES would be highly recommended on these grounds alone. The characteristics of Large (i.e. over 10 000 m3 TES in operation in Poland are presented. Information is given regarding new projects (currently in design or construction that apply TES technology in DHS in Poland. The paper looks at the methodology used in Poland to select the TES system for a particular DHS, i.e., procedure for calculating capacity of the TES tank and the system to prevent water stored in the tank from absorbing oxygen from atmospheric air. Implementation of TES in DHS is treated as a recommended technology in the Polish District Heating sector. This technology offers great opportunities to improve the operating conditions of DHS, cutting energy production costs and emissions of pollutants to the atmosphere.

  19. Ontogenetic thermal tolerance and performance of ectotherms at variable temperatures

    National Research Council Canada - National Science Library

    Cavieres, G; Bogdanovich, J. M; Bozinovic, F

    2016-01-01

    .... Additionally, in constant and variable climatic scenarios, flies shifted to the right the optimum temperature but the maximum performance decreased only in flies reared on high temperatures and high thermal variability...

  20. Thermal Degradation of Streptomycin Residues in Honey During Storage

    Directory of Open Access Journals (Sweden)

    Monica Cristina Cara

    2013-01-01

    Full Text Available In Europe there is an increasing emphasis on the quality control of honey, especially on maximum limits of veterinary drug residues (particularly antibiotics permitted in it. Streptomycin is an aminoglycoside antibiotic used in apiculture to protect bees against a variety of brood diseases. Romanian authorities have included it in the National Monitoring Program for honey manufacturers. In this study, an enzyme-linked immunosorbent assay (ELISA screening test was validated as a detection method of streptomycin residues in honey. The ELISA experimental results were compared to those obtained by using an HPLC method. The values generated by the two methods were very close to each other. This fact certifies that ELISA method can be successfully used for quantitative detection of the amount of streptomycin in honey samples. Following validation, three types of honey (polyfloral, lime and acacia were analyzed for streptomycin content after exposure to 4, 22, 30, 40 or 70 °C for 20 weeks. The results show that streptomycin mass fraction decreased with time and with the increase of temperature in all honey samples. The data collected were used to fit a second-order multiple linear regression model for predicting the degradation of streptomycin in honey samples as a function of temperature and storage period. Values of the calculated statistical indicators confirm a good predictive capability of mathematical and statistical models.

  1. Storage effects on anthocyanins, phenolics and antioxidant activity of thermally processed conventional and organic blueberries.

    Science.gov (United States)

    Syamaladevi, Roopesh M; Andrews, Preston K; Davies, Neal M; Walters, Thomas; Sablani, Shyam S

    2012-03-15

    Consumer demand for products rich in phytochemicals is increasing as a result of greater awareness of their potential health benefits. However, processed products are stored for long-term and the phytochemicals are susceptible to degradation during storage. The objective of this study was to assess the storage effects on phytochemicals in thermally processed blueberries. Thermally processed canned berries and juice/puree were analysed for phytochemicals during their long-term storage. The phytochemical retention of thermally processed blueberries during storage was not influenced by production system (conventional versus organic). During 13 months of storage, total anthocyanins, total phenolics and total antioxidant activity in canned blueberry solids decreased by up to 86, 69 and 52% respectively. In canned blueberry syrup, total anthocyanins and total antioxidant activity decreased by up to 68 and 15% respectively, while total phenolic content increased by up to 117%. Similar trends in phytochemical content were observed in juice/puree stored for 4 months. The extent of changes in phytochemicals of thermally processed blueberries during storage was significantly influenced by blanching. Long-term storage of thermally processed blueberries had varying degrees of influence on degradation of total anthocyanins, total phenolics and total antioxidant activity. Blanching before thermal processing helped to preserve the phytochemicals during storage of blueberries. Copyright © 2011 Society of Chemical Industry.

  2. Applications of thermal energy storage to process heat storage and recovery in the paper and pulp industry

    Science.gov (United States)

    Carr, J. H.; Hurley, P. J.; Martin, P. J.

    1978-01-01

    Applications of Thermal Energy Storage (TES) in a paper and pulp mill power house were studied as one approach to the transfer of steam production from fossil fuel boilers to waste fuel of (hog fuel) boilers. Data from specific mills were analyzed, and various TES concepts evaluated for application in the process steam supply system. Constant pressure and variable pressure steam accumulators were found to be the most attractive storage concepts for this application.

  3. Experimental and Numerical Study of Effect of Thermal Management on Storage Capacity of the Adsorbed Natural Gas Vessel

    KAUST Repository

    Ybyraiymkul, Doskhan

    2017-07-08

    One of the main challenges in the adsorbed natural gas (ANG) storage system is the thermal effect of adsorption, which significantly lowers storage capacity. These challenges can be solved by efficient thermal management system. In this paper, influence of thermal management on storage capacity of the ANG vessel was studied experimentally and numerically. 3D numerical model was considered in order to understand heat transfer phenomena and analyze influence of thermal control comprehensively. In addition, a detailed 2D axisymmetric unit cell model of adsorbent layer with heat exchanger was developed, followed by optimization of heat exchanging device design to minimize volume occupied by fins and tubes. Heat transfer, mass transfer and adsorption kinetics, which occur in ANG vessel during charging process, are accounted for in models. Nelder-Mead method is implemented to obtain the geometrical parameters, which lead to the optimal characteristics of heat exchange. A new optimized configuration of ANG vessel was developed with compact heat exchanger. Results show that storage capacity of the ANG vessel increased significantly due to lowering of heat exchanger volume for 3 times from 13.5% to 4.3% and effective temperature control.

  4. Thermochemical Characterizations of Novel Vermiculite-LiCl Composite Sorbents for Low-Temperature Heat Storage

    Directory of Open Access Journals (Sweden)

    Yannan Zhang

    2016-10-01

    Full Text Available To store low-temperature heat below 100 °C, novel composite sorbents were developed by impregnating LiCl into expanded vermiculite (EVM in this study. Five kinds of composite sorbents were prepared using different salt concentrations, and the optimal sorbent for application was selected by comparing both the sorption characteristics and energy storage density. Textural properties of composite sorbents were obtained by extreme-resolution field emission scanning electron microscopy (ER-SEM and an automatic mercury porosimeter. After excluding two composite sorbents which would possibly exhibit solution leakage in practical thermal energy storage (TES system, thermochemical characterizations were implemented through simulative sorption experiments at 30 °C and 60% RH. Analyses of thermogravimetric analysis/differential scanning calorimetry (TGA/DSC curves indicate that water uptake of EVM/LiCl composite sorbents is divided into three parts: physical adsorption of EVM, chemical adsorption of LiCl crystal, and liquid–gas absorption of LiCl solution. Energy storage potential was evaluated by theoretical calculation based on TGA/DSC curves. Overall, EVMLiCl20 was selected as the optimal composite sorbent with water uptake of 1.41 g/g, mass energy storage density of 1.21 kWh/kg, and volume energy storage density of 171.61 kWh/m3.

  5. Experimental Determination of in Situ Utilization of Lunar Regolith for Thermal Energy Storage

    Science.gov (United States)

    Richter, Scott W.

    1993-01-01

    A Lunar Thermal Energy from Regolith (LUTHER) experiment has been designed and fabricated at the NASA Lewis Research Center to determine the feasibility of using lunar soil as thermal energy storage media. The experimental apparatus includes an alumina ceramic canister (25.4 cm diameter by 45.7 cm length) which contains simulated lunar regolith, a heater (either radiative or conductive), 9 heat shields, a heat transfer cold jacket, and 19 type B platinum rhodium thermocouples. The simulated lunar regolith is a basalt, mined and processed by the University of Minnesota, that closely resembles the lunar basalt returned to earth by the Apollo missions. The experiment will test the effects of vacuum, particle size, and density on the thermophysical properties of the regolith. The properties include melt temperature (range), specific heat, thermal conductivity, and latent heat of storage. Two separate tests, using two different heaters, will be performed to study the effect of heating the system using radiative and conductive heat transfer. The physical characteristics of the melt pattern, material compatibility of the molten regolith, and the volatile gas emission will be investigated by heating a portion of the lunar regolith to its melting temperature (1435 K) in a 10(exp -4) pascal vacuum chamber, equipped with a gas spectrum analyzer. A finite differencing SINDA model was developed at NASA Lewis Research Center to predict the performance of the LUTHER experiment. The analytical results of the code will be compared with the experimental data generated by the LUTHER experiment. The code will predict the effects of vacuum, particle size, and density has on the heat transfer to the simulated regolith.

  6. University of Minnesota aquifer thermal energy storage (ATES) project report on the third long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Uebel, M.H.; Delin, G.N.; Eisenreich, S.J.; Sterling, R.L.

    1994-12-01

    The University of Minnesota aquifer thermal energy storage (ATES) system has been operated as a field test facility (FTF) since 1982. The objectives were to design, construct, and operate the facility to study the feasibility of high-temperature ATES in a confined aquifer. Four short-term and two long-term cycles were previously conducted, which provided a greatly increased understanding of the efficiency and geochemical effects of high-temperature aquifer thermal energy storage. The third long-term cycle (LT3) was conducted to operate the ATES system in conjunction with a real heating load and to further study the geochemical impact that heated water storage had on the aquifer. For LT3, the source and storage wells were modified so that only the most permeable portion, the Ironton-Galesville part, of the Franconia-Ironton-Galesville aquifer was used for storage. This was expected to improve storage efficiency by reducing the surface area of the heated volume and simplify analysis of water chemistry results by reducing the number of aquifer-related variables which need to be considered. During LT3, a total volume of 63.2 {times} 10{sup 3} m {sup 3} of water was injected at a rate of 54.95 m{sup 3}/hr into the storage well at a mean temperature of 104.7{degrees}C. Tie-in to the reheat system of the nearby Animal Sciences Veterinary Medicine (ASVM) building was completed after injection was completed. Approximately 66 percent (4.13 GWh) of the energy added to the aquifer was recovered. Approximately 15 percent (0.64 GWh) of the usable (10 building. Operations during heat recovery with the ASVM building`s reheat system were trouble-free. Integration into more of the ASVM (or other) building`s mechanical systems would have resulted in significantly increasing the proportion of energy used during heat recovery.

  7. Thermophysical parameters of coconut oil and its potential application as the thermal energy storage system in Indonesia

    Science.gov (United States)

    Putri, Widya A.; Fahmi, Zulfikar; Sutjahja, I. M.; Kurnia, D.; Wonorahardjo, S.

    2016-08-01

    The high consumption of electric energy for room air conditioning (AC) system in Indonesia has driven the research of potential thermal energy storage system as a passive temperature controller. The application of coconut oil (CO) as the potential candidate for this purpose has been motivated since its working temperature just around the human thermal comfort zone in the tropical area as Indonesia. In this research we report the time-dependent temperature data of CO, which is adopting the T-history method. The analysis of the data revealed a set of thermophysical parameters, consist of the mean specific heats of the solid and liquid, as well as the latent heat of fusion for the phase change transition. The performance of CO to decrease the air temperature was measured in the thermal chamber. From the results it is shown that the latent phase of CO related to the solid-liquid phase transition show the highest capability in heat absorption, directly showing the potential application of CO as thermal energy storage system in Indonesia.

  8. Numerical Analysis of Shell-and-Tube Type Latent Thermal Energy Storage Performance with Different Arrangements of Circular Fins

    Directory of Open Access Journals (Sweden)

    Sebastian Kuboth

    2017-02-01

    Full Text Available Latent thermal energy storage (LTS systems are versatile due to their high-energy storage density within a small temperature range. In shell-and-tube type storage systems fins can be used in order to achieve enhanced charging and discharging power. Typically, circular fins are evenly distributed over the length of the heat exchanger pipe. However, it is yet to be proven that this allocation is the most suitable for every kind of system and application. Consequently, within this paper, a simulation model was developed in order to examine the effect of different fin distributions on the performance of shell-and-tube type latent thermal storage units at discharge. The model was set up in MATLAB Simulink R2015b (The MathWorks, Inc., Natick, MA, USA based on the enthalpy method and validated by a reference model designed in ANSYS Fluent 15.0 (ANSYS, Inc., Canonsburg, PA, USA. The fin density of the heat exchanger pipe was increased towards the pipe outlet. This concentration of fins was implemented linearly, exponentially or suddenly with the total number of fins remaining constant during the variation of fin allocations. Results show that there is an influence of fin allocation on storage performance. However, the average storage performance at total discharge only increased by three percent with the best allocation compared to an equidistant arrangement.

  9. Ice Thermal Storage Systems for LWR Supplemental Cooling and Peak Power Shifting

    Energy Technology Data Exchange (ETDEWEB)

    Haihua Zhao; Hongbin Zhang; Phil Sharpe; Blaise Hamanaka; Wei Yan; WoonSeong Jeong

    2010-06-01

    Availability of enough cooling water has been one of the major issues for the nuclear power plant site selection. Cooling water issues have frequently disrupted the normal operation at some nuclear power plants during heat waves and long draught. The issues become more severe due to the new round of nuclear power expansion and global warming. During hot summer days, cooling water leaving a power plant may become too hot to threaten aquatic life so that environmental regulations may force the plant to reduce power output or even temporarily to be shutdown. For new nuclear power plants to be built at areas without enough cooling water, dry cooling can be used to remove waste heat directly into the atmosphere. However, dry cooling will result in much lower thermal efficiency when the weather is hot. One potential solution for the above mentioned issues is to use ice thermal storage systems (ITS) that reduce cooling water requirements and boost the plant’s thermal efficiency in hot hours. ITS uses cheap off-peak electricity to make ice and uses those ice for supplemental cooling during peak demand time. ITS is suitable for supplemental cooling storage due to its very high energy storage density. ITS also provides a way to shift large amount of electricity from off peak time to peak time. Some gas turbine plants already use ITS to increase thermal efficiency during peak hours in summer. ITSs have also been widely used for building cooling to save energy cost. Among three cooling methods for LWR applications: once-through, wet cooling tower, and dry cooling tower, once-through cooling plants near a large water body like an ocean or a large lake and wet cooling plants can maintain the designed turbine backpressure (or condensation temperature) during 99% of the time; therefore, adding ITS to those plants will not generate large benefits. For once-through cooling plants near a limited water body like a river or a small lake, adding ITS can bring significant economic

  10. The Role of Soya Oil Ester in Water-Based PCM for Low Temperature Cool Energy Storage

    Directory of Open Access Journals (Sweden)

    I. M. Rasta

    2016-01-01

    Full Text Available This study focuses on the preparation of the water-based phase change material (PCM with very small soya oil solution for low temperature latent heat thermal energy storage (LHTES. Soya oil ester is soluble very well in water and acts as nucleating agent for a novel solid-liquid PCM candidate that is suitable for low temperature cool storage in the range between −9°C and −6°C. Thermal energy storage properties of the water with very small soya oil ester solution were measured by T-history method. The experimental results show that very small amount of soya oil ester in water can lower the freezing point and trigger ice nucleation for elimination of the supercooling degree. The phase transition temperatures of the water-based PCMs with soya oil as nucleate agent were lower than those of individual water. The thermal properties make it potential PCM for LHTES systems used in low temperature cool energy storage applications.

  11. Optimum Temperature and Thermal Stability of Crude Polyphenol ...

    African Journals Online (AJOL)

    Bello & Sule: Optimum Temperature and Thermal Stability of Crude Polyphenol Oxidase from some Common Fruits. 30. DISCUSSION. Temperature is one of the factors that affect the rate of an enzyme catalyzed reaction (Martin, 2006). Optimum temperature is the temperature at which an enzyme shows its highest catalytic ...

  12. Modeling and testing of cryo-adsorbent hydrogen storage tanks with improved thermal isolation

    Science.gov (United States)

    Raymond, Alexander William; Reiter, Joseph

    2012-06-01

    One storage concept for hydrogen-fueled vehicles is physical adsorption of hydrogen at cryogenic temperatures (nominally 80 K). During long idle periods, parasitic heat transfer from the environment induces desorption to the tank void volume. This desorption increases tank pressure such that it must be vented. To reduce the amount of fuel lost to venting, parasitic heating is minimized using multi-layer vacuum insulation and thermally isolating structures. A model is developed to predict the amount of conduction through structural supports and hydrogen lines, radiation through multi-layer insulation, and rarified gas conduction in the vacuum jacket of a tank sized for adsorption storage. The model reveals that conduction through structural supports is significant for cases of interest. Thus, two structural support architectures are compared: one utilizing G-10 CR composite and another involving KevlarTM cable. The structural members are sized to support comparable inertial loadings; the overall parasitic heat transfer is found to be as much as 38 percent less for the KevlarTM design. A lumped-parameter tank simulation is used to relate parasitic heat transfer to dormancy time and venting rate. The results of thermal testing of a sub-scale tank simulator are compared with model predictions.

  13. Thermal insulation and body temperature wearing a thermal swimsuit during water immersion.

    Science.gov (United States)

    Wakabayashi, Hitoshi; Hanai, Atsuko; Yokoyama, Shintaro; Nomura, Takeo

    2006-09-01

    This study evaluated the effects of a thermal swimsuit on body temperatures, thermoregulatory responses and thermal insulation during 60 min water immersion at rest. Ten healthy male subjects wearing either thermal swimsuits or normal swimsuits were immersed in water (26 degrees C or 29 degrees C). Esophageal temperature, skin temperatures and oxygen consumption were measured during the experiments. Metabolic heat production was calculated from oxygen consumption. Heat loss from skin to the water was calculated from the metabolic heat production and the change in mean body temperature during water immersion. Total insulation and tissue insulation were estimated by dividing the temperature difference between the esophagus and the water or the esophagus and the skin with heat loss from the skin. Esophageal temperature with a thermal swimsuit was higher than that with a normal swimsuit at the end of immersion in both water temperature conditions (pthermal swimsuit than with a normal swimsuit in both water temperatures (pinsulation with the thermal swimsuit was higher than that with a normal swimsuit due to insulation of the suit at both water temperatures (pinsulation was similar in all four conditions, but significantly higher with the thermal swimsuit in both water temperature conditions (pthermal swimsuit. A thermal swimsuit can increase total insulation and reduce heat loss from the skin. Therefore, subjects with thermal swimsuits can maintain higher body temperatures than with a normal swimsuit and reduce shivering thermo-genesis.

  14. APPLICATIONS OF THERMAL ENERGY STORAGE TO WASTE HEAT RECOVERY IN THE FOOD PROCESSING INDUSTRY, Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Lundberg, W. L.; Christenson, James A.

    1979-07-31

    A project is discussed in which the possibilities for economical waste heat recovery and utilization in the food industry were examined. Waste heat availability and applications surveys were performed at two manufacturing plants engaged in low temperature (freezing) and high temperature (cooking, sterilizing, etc.) food processing. The surveys indicate usable waste heat is available in significant quantities which could be applied to existing, on-site energy demands resulting in sizable reductions in factory fuel and energy usage. At the high temperature plant, the energy demands involve the heating of fresh water for boiler make-up, for the food processes and for the daily clean-up operation. Clean-up poses an opportunity for thermal energy storage since waste heat is produced during the one or two production shifts of each working day while the major clean-up effort does not occur until food production ends. At the frozen food facility, the clean-up water application again exists and, in addition, refrigeration waste heat could also be applied to warm the soil beneath the ground floor freezer space. Systems to recover and apply waste heat in these situations were developed conceptually and thermal/economic performance predictions were obtained. The results of those studies indicate the economics of waste heat recovery can be attractive for facilities with high energy demand levels. Small factories, however, with relatively low energy demands may find the economics marginal although, percentagewise, the fuel and energy savings are appreciable.

  15. A Study of Solar Thermal Propulsion System Enhancement via Thermal Storage and Thermal-electric Conversion

    Science.gov (United States)

    2010-03-24

    material. Molybdenum has a thermal conductivity of 138 W/mK, while rheniums is much lower at 39.6 W/mK 2 . Zirconium Boride (ZrB2) and Hafnium Boride ...14,000 Iridium 77 2739 213 147 $42,000 Niobium 41 2750 323 53.7 $170 Molybdenum 42 2896 390 138 $100 The materials listed in Table 1 do not...this paper, several materials with melting points above 3000 K are boride compounds and several of those that are not borides contain elements which

  16. DETERMINATION OF TEMPERATURE DISTRIBUTION FOR ANNULAR FINS WITH TEMPERATURE DEPENDENT THERMAL CONDUCTIVITY BY HPM

    Directory of Open Access Journals (Sweden)

    Davood Domairry Ganji

    2011-01-01

    Full Text Available In this paper, homotopy perturbation method has been used to evaluate the temperature distribution of annular fin with temperature-dependent thermal conductivity and to determine the temperature distribution within the fin. This method is useful and practical for solving the nonlinear heat transfer equation, which is associated with variable thermal conductivity condition. The homotopy perturbation method provides an approximate analytical solution in the form of an infinite power series. The annular fin heat transfer rate with temperature-dependent thermal conductivity has been obtained as a function of thermo-geometric fin parameter and the thermal conductivity parameter describing the variation of the thermal conductivity.

  17. Etanercept (Enbrel® alternative storage at ambient temperature

    Directory of Open Access Journals (Sweden)

    Shannon E

    2017-07-01

    Full Text Available Edel Shannon,1 Joanne Daffy,2 Heather Jones,3 Andrea Paulson,4 Steven M Vicik5 1Global Chemistry, Manufacturing, and Controls Regulatory, 2Contract Operations Quality Assurance, Pfizer Ireland Pharmaceuticals, Clondalkin, Dublin, Ireland; 3Medical Affairs, Pfizer, Collegeville, PA, USA; 4Pharmaceutical Research and Development, 5Global Supply Product Portfolio Management, Pfizer Biotech, Andover, MA, USA Background: Biologic disease-modifying antirheumatic drugs, including tumor necrosis factor inhibitors such as etanercept (Enbrel®, have improved outcomes for patients with rheumatic and other inflammatory diseases, with sustained remission being the optimal goal for patients with rheumatoid arthritis. Flexible and convenient treatment options, compatible with modern lifestyle, are important in helping patients maintain treatment and manage their disease. Etanercept drug product (DP is available in lyophilized powder (Lyo for solution injection, prefilled syringe, and prefilled pen presentations and is typically stored under refrigerated conditions. We aimed to generate a comprehensive analytical data package from stability testing of key quality attributes, consistent with regulatory requirements, to determine whether the product profile of etanercept is maintained at ambient temperature. Methods: Test methods assessing key attributes of purity, quality, potency, and safety were performed over time, following storage of etanercept DP presentations under a range of conditions. Results: Results and statistical analysis from stability testing (based on size exclusion high-performance liquid chromatography, hydrophobic interaction chromatography, and sodium dodecyl sulfate-polyacrylamide gel electrophoresis Coomassie across all etanercept presentations (10 and 25 mg/vial Lyo DP; 25 and 50 mg prefilled syringe DP; 50 mg prefilled pen DP showed key stability-indicating parameters were within acceptable limits through the alternative storage

  18. The pH-dependent thermal and storage stability of glycosylated caseinomacropeptide

    DEFF Research Database (Denmark)

    Siegert, Nadja; Tolkach, Alexander; Kulozik, Ulrich

    2012-01-01

    manufacturing gCMP can be modified due to processing. Processing conditions, which influence the degree of glycosylation of gCMP lead to alterations of bioactivity and techno-functional properties of gCMP and accordingly gCMP-containing products. Hence, gCMP was studied for its glycan stability during heat...... treatment and storage under different pH values. Process stability (preservation of native protein structure in terms of attached glycans) was analysed by quantifying the release of the terminal carbohydrate, N-acetylneuraminic acid (Neu5Ac), from gCMP. The results clearly showed that the thermal stability...... of gCMP is strongly influenced by pH. When the pH was decreased from 7 to 2, reduced stability was found even at low heating temperatures. Minimal destabilisation effects were found at neutral pH. Similar observations were found during storage of gCMP. Neu5Ac was released after six days of storage...

  19. 3D Temperature Distribution Model Based on Thermal Infrared Image

    Directory of Open Access Journals (Sweden)

    Tong Jia

    2017-01-01

    Full Text Available This paper aims to study the construction of 3D temperature distribution reconstruction system based on binocular vision technology. Initially, a traditional calibration method cannot be directly used, because the thermal infrared camera is only sensitive to temperature. Therefore, the thermal infrared camera is calibrated separately. Belief propagation algorithm is also investigated and its smooth model is improved in terms of stereo matching to optimize mismatching rate. Finally, the 3D temperature distribution model is built based on the matching of 3D point cloud and 2D thermal infrared information. Experimental results show that the method can accurately construct the 3D temperature distribution model and has strong robustness.

  20. Modeling of thermal mass energy storage in buildings with phase change materials

    Science.gov (United States)

    Delcroix, Benoit

    Building thermal mass is a key parameter defining the ability of a building to mitigate inside temperature variations and to maintain a better thermal comfort. Increasing the thermal mass of a lightweight building can be achieved by using Phase Change Materials (PCMs). These materials offer a high energy storage capacity (using latent energy) and a nearly constant temperature phase change. They can be integrated conveniently in net-zero energy buildings. The current interest for these buildings and for better power demand management strategies requires accurate transient simulation of heavy and highly insulated slabs or walls with short time-steps (lower than or equal to 5 minutes). This represents a challenge for codes that were mainly developed for yearly energy load calculations with a time-step of 1 hour. It is the case of the TRNSYS building model (called Type 56) which presents limitations when modeling heavy and highly insulated slabs with short time-steps. These limitations come from the method used by TRNSYS for modeling conduction heat transfer through walls which is known as the Conduction Transfer Function (CTF) method. In particular, problems have been identified in the generation of CTF coefficients used to model the walls thermal response. This method is also unable to define layers with variable thermophysical properties, as displayed by PCMs. PCM modeling is further hindered by the limited information provided by manufacturers: physical properties are often incomplete or incorrect. Finally, current models are unable to represent the whole complexity of PCM thermal behavior: they rarely include different properties for melting and solidification (hysteresis); they sometimes take into account variable thermal conductivity; but they never model subcooling effects. All these challenges are tackled in this thesis and solutions are proposed. The first part (chapter 4) focuses on improving the CTF method in TRNSYS through state-space modeling

  1. Seasonal thermal energy storage program. Progress report, January 1980-December 1980

    Energy Technology Data Exchange (ETDEWEB)

    Minor, J.E.

    1981-05-01

    The objectives of the Seasonal Thermal Energy Storage (STES) Program is to demonstrate the economic storage and retrieval of energy on a seasonal basis, using heat or cold available from waste sources or other sources during a surplus period to reduce peak period demand, reduce electric utilities peaking problems, and contribute to the establishment of favorable economics for district heating and cooling systems for commercialization of the technology. Aquifers, ponds, earth, and lakes have potential for seasonal storage. The initial thrust of the STES Program is toward utilization of ground-water systems (aquifers) for thermal energy storage. Program plans for meeting these objectives, the development of demonstration programs, and progress in assessing the technical, economic, legal, and environmental impacts of thermal energy storage are described. (LCL)

  2. Strawberry puree processed by thermal, high pressure, or power ultrasound: Process energy requirements and quality modeling during storage.

    Science.gov (United States)

    Sulaiman, Alifdalino; Farid, Mohammed; Silva, Filipa Vm

    2017-06-01

    Strawberry puree was processed for 15 min using thermal (65 ℃), high-pressure processing (600 MPa, 48 ℃), and ultrasound (24 kHz, 1.3 W/g, 33 ℃). These conditions were selected based on similar polyphenoloxidase inactivation (11%-18%). The specific energies required for the above-mentioned thermal, high-pressure processing, and power ultrasound processes were 240, 291, and 1233 kJ/kg, respectively. Then, the processed strawberry was stored at 3 ℃ and room temperature for 30 days. The constant pH (3.38±0.03) and soluble solids content (9.03 ± 0.25°Brix) during storage indicated a microbiological stability. Polyphenoloxidase did not reactivate during storage. The high-pressure processing and ultrasound treatments retained the antioxidant activity (70%-74%) better than the thermal process (60%), and high-pressure processing was the best treatment after 30 days of ambient storage to preserve antioxidant activity. Puree treated with ultrasound presented more color retention after processing and after ambient storage than the other preservation methods. For the three treatments, the changes of antioxidant activity and total color difference during storage were described by the fractional conversion model with rate constants k ranging between 0.03-0.09 and 0.06-0.22 day - 1, respectively. In resume, high-pressure processing and thermal processes required much less energy than ultrasound for the same polyphenoloxidase inactivation in strawberry. While high-pressure processing retained better the antioxidant activity of the strawberry puree during storage, the ultrasound treatment was better in terms of color retention.

  3. Predicting Formation Damage in Aquifer Thermal Energy Storage Systems Utilizing a Coupled Hydraulic-Thermal-Chemical Reservoir Model

    Science.gov (United States)

    Müller, Daniel; Regenspurg, Simona; Milsch, Harald; Blöcher, Guido; Kranz, Stefan; Saadat, Ali

    2014-05-01

    In aquifer thermal energy storage (ATES) systems, large amounts of energy can be stored by injecting hot water into deep or intermediate aquifers. In a seasonal production-injection cycle, water is circulated through a system comprising the porous aquifer, a production well, a heat exchanger and an injection well. This process involves large temperature and pressure differences, which shift chemical equilibria and introduce or amplify mechanical processes. Rock-fluid interaction such as dissolution and precipitation or migration and deposition of fine particles will affect the hydraulic properties of the porous medium and may lead to irreversible formation damage. In consequence, these processes determine the long-term performance of the ATES system and need to be predicted to ensure the reliability of the system. However, high temperature and pressure gradients and dynamic feedback cycles pose challenges on predicting the influence of the relevant processes. Within this study, a reservoir model comprising a coupled hydraulic-thermal-chemical simulation was developed based on an ATES demonstration project located in the city of Berlin, Germany. The structural model was created with Petrel, based on data available from seismic cross-sections and wellbores. The reservoir simulation was realized by combining the capabilities of multiple simulation tools. For the reactive transport model, COMSOL Multiphysics (hydraulic-thermal) and PHREEQC (chemical) were combined using the novel interface COMSOL_PHREEQC, developed by Wissmeier & Barry (2011). It provides a MATLAB-based coupling interface between both programs. Compared to using COMSOL's built-in reactive transport simulator, PHREEQC additionally calculates adsorption and reaction kinetics and allows the selection of different activity coefficient models in the database. The presented simulation tool will be able to predict the most important aspects of hydraulic, thermal and chemical transport processes relevant to

  4. Detection of comfortable temperature based on thermal events detection indoors

    Science.gov (United States)

    Szczurek, Andrzej; Maciejewska, Monika; Uchroński, Mariusz

    2017-11-01

    This work focussed on thermal comfort as the basis to control indoor conditions. Its objective is a method to determine thermal preferences of office occupants. The method is based on detection of thermal events. They occur when indoor conditions are under control of occupants. Thermal events are associated with the use of local heating/cooling sources which have user-adjustable settings. The detection is based on Fourier analysis of indoor temperature time series. The relevant data is collected by temperature sensor. We achieved thermal events recognition rate of 86 %. Conditions when indoor conditions were beyond control were detected with 95.6 % success rate. Using experimental data it was demonstrated that the method allows to reproduce key elements of temperature statistics associated with conditions when occupants are in control of thermal comfort.

  5. Collection and dissemination of thermal energy storage system information for the pulp and paper industry

    Science.gov (United States)

    Edde, H.

    1981-01-01

    The collection and dissemination of thermal energy storage (TES) system technology for the pulp and paper industry with the intent of reducing fossil fuel usage is discussed. The study plan is described and a description presented of example TES systems.

  6. Innovative Phase Change Thermal Energy Storage Solution for Baseload Power Phase 1 Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Qiu, Songgang

    2013-05-15

    The primary purpose of this project is to develop and validate an innovative, scalable phase change salt thermal energy storage (TES) system that can interface with Infinia’s family of free-piston Stirling engines (FPSE). This TES technology is also appropriate for Rankine and Brayton power converters. Solar TES systems based on latent heat of fusion rather than molten salt temperature differences, have many advantages that include up to an order of magnitude higher energy storage density, much higher temperature operation, and elimination of pumped loops for most of Infinia’s design options. DOE has funded four different concepts for solar phase change TES, including one other Infinia awarded project using heat pipes to transfer heat to and from the salt. The unique innovation in this project is an integrated TES/pool boiler heat transfer system that is the simplest approach identified to date and arguably has the best potential for minimizing the levelized cost of energy (LCOE). The Phase 1 objectives are to design, build and test a 1-hour TES proof-of-concept lab demonstrator integrated with an Infinia 3 kW Stirling engine, and to conduct a preliminary design of a 12-hour TES on-sun prototype.

  7. Reducing Display Bottle Cooler Energy Consumption Using PCM As Active Thermal Storage

    OpenAIRE

    Beek, Marcel van; de Jong, Hans

    2014-01-01

    The final results of an analytical and experimental study in reducing the energy consumption of a display bottle cooler using Phase Change Material (PCM) as an active thermal storage are presented. The objective of the study was to design and built a 350 dm3 glass door bottle cooler having an appliance energy consumption reduction of over 75% compared to state of the art bottle coolers (2010 figures). Calculation results show that active thermal storage using PCM can be effectively applied to...

  8. Applications of thermal energy storage to waste heat recovery in the food processing industry

    Science.gov (United States)

    Wojnar, F.; Lunberg, W. L.

    1980-01-01

    A study to assess the potential for waste heat recovery in the food industry and to evaluate prospective waste heat recovery system concepts employing thermal energy storage was conducted. The study found that the recovery of waste heat in canning facilities can be performed in significant quantities using systems involving thermal energy storage that are both practical and economical. A demonstration project is proposed to determine actual waste heat recovery costs and benefits and to encourage system implementation by the food industry.

  9. Physicochemical Changes and Resistant-Starch Content of Extruded Cornstarch with and without Storage at Refrigerator Temperatures

    Directory of Open Access Journals (Sweden)

    David Neder-Suárez

    2016-08-01

    Full Text Available Effects of extrusion cooking and low-temperature storage on the physicochemical changes and resistant starch (RS content in cornstarch were evaluated. The cornstarch was conditioned at 20%–40% moisture contents and extruded in the range 90–130 °C and at screw speeds in the range 200–360 rpm. The extrudates were stored at 4 °C for 120 h and then at room temperature. The water absorption, solubility index, RS content, viscoelastic, thermal, and microstructural properties of the extrudates were evaluated before and after storage. The extrusion temperature and moisture content significantly affected the physicochemical properties of the extrudates before and after storage. The RS content increased with increasing moisture content and extrusion temperature, and the viscoelastic and thermal properties showed related behaviors. Microscopic analysis showed that extrusion cooking damaged the native starch structure, producing gelatinization and retrogradation and forming RS. The starch containing 35% moisture and extruded at 120 °C and 320 rpm produced the most RS (1.13 g/100 g after to storage at low temperature. Although the RS formation was low, the results suggest that extrusion cooking could be advantageous for RS production and application in the food industry since it is a pollution less, continuous process requiring only a short residence time.

  10. Gas storage cylinder formed from a composition containing thermally exfoliated graphite

    Science.gov (United States)

    Prud'Homme, Robert K. (Inventor); Aksay, Ilhan A. (Inventor)

    2012-01-01

    A gas storage cylinder or gas storage cylinder liner, formed from a polymer composite, containing at least one polymer and a modified graphite oxide material, which is a thermally exfoliated graphite oxide with a surface area of from about 300 m(exp 2)/g to 2600 m(exp 2)2/g.

  11. Silica and alumina nano-enhanced molten salts for thermal energy storage: A comparison

    Science.gov (United States)

    Muñoz-Sánchez, Belén; Nieto-Maestre, Javier; Iparraguirre-Torres, Iñigo; Julià, José Enrique; García-Romero, Ana

    2017-06-01

    The study of more efficient materials for thermal energy storage at high temperatures is a broad field of research. The use of the nanotechnology is a strategy recently considered to enhance the thermal properties of these materials. The nano-enhanced Molten Salts (neMS) are constituted by an inorganic salt where tiny quantities of nanoparticles (NPs) are dispersed. These nanomaterials possess a specific heat higher than that of the salt or the isolated NPs. This phenomenon is not still well understood and great research efforts are needed to describe the interactions on the material at a molecular level. The existence of a nanolayer at the interface between the NPs surface and the molten salt with superior thermal properties is the main mechanism proposed up to now. A high available surface of the NPs promotes the formation of higher quantities of these nanostructures. The available surface depends on the NPs size and shape and is strongly reduced if NPs are agglomerated. We have studied and compared the effect on the specific heat of embedding two different ceramic NPs on molten Solar Salt.

  12. Accelerating Rate Calorimetry Tests of Lithium-Ion Cells Before and After Storage Degradation at High Temperature

    Directory of Open Access Journals (Sweden)

    Mendoza-Hernandez Omar Samuel

    2017-01-01

    Full Text Available Understanding the behavior of Li-ion cells during thermal runaway is critical to evaluate the safety of these energy storage devices under outstanding conditions. Li-ion cells possess a high energy density and are used to store and supply energy to many aerospace applications. Incidents related to the overheating or thermal runaway of these cells can cause catastrophic damages that could end up costly space missions; therefore, thermal studies of Li-ion cells are very important for ensuring safety and reliability of space missions. This work evaluates the thermal behavior of Li-ion cells before and after storage degradation at high temperature using accelerating rate calorimeter (ARC equipment to analyze the thermal behavior of Li-ion cells under adiabatic conditions. Onset temperature points of self-heating and thermal runaway reactions are obtained. The onset points are used to identify non-self-heating, self-heating and thermal runaway regions as a function of state of charge. The results obtained can be useful to develop accurate thermo-electrochemical models of Li-ion cells.

  13. A Novel Modeling of Molten-Salt Heat Storage Systems in Thermal Solar Power Plants

    Directory of Open Access Journals (Sweden)

    Rogelio Peón Menéndez

    2014-10-01

    Full Text Available Many thermal solar power plants use thermal oil as heat transfer fluid, and molten salts as thermal energy storage. Oil absorbs energy from sun light, and transfers it to a water-steam cycle across heat exchangers, to be converted into electric energy by means of a turbogenerator, or to be stored in a thermal energy storage system so that it can be later transferred to the water-steam cycle. The complexity of these thermal solar plants is rather high, as they combine traditional engineering used in power stations (water-steam cycle or petrochemical (oil piping, with the new solar (parabolic trough collector and heat storage (molten salts technologies. With the engineering of these plants being relatively new, regulation of the thermal energy storage system is currently achieved in manual or semiautomatic ways, controlling its variables with proportional-integral-derivative (PID regulators. This makes the overall performance of these plants non optimal. This work focuses on energy storage systems based on molten salt, and defines a complete model of the process. By defining such a model, the ground for future research into optimal control methods will be established. The accuracy of the model will be determined by comparing the results it provides and those measured in the molten-salt heat storage system of an actual power plant.

  14. Glycemic index: effect of food storage under low temperature

    Directory of Open Access Journals (Sweden)

    Marina Cassab Carreira

    2004-08-01

    Full Text Available This study was carried out to evaluate the influence of food storage under low temperature (-20ºC and the resistant starch formation, both on the glycemic index (GI. The GI of only cooked and cooked and stored foods under -20ºC for 30 days was evaluated in short-term tests with humans. Significant increase on the RS content was evidenced for all the stored foods. The food storage resulted in a significant decrease on the GI of beans and chick-peas; the GI of pasta remained the same and the GI of corn meal increased. Thus, the RS formation showed reduced influence on the glycemic index. The storage of starchy foods under low temperature can collaborate to the RS intake but its effect on the GI will depend on the characteristics of the carbohydrates of each food.O estudo foi realizado para avaliar a influência do armazenamento de alimentos sob baixa temperatura e a formação de amido resistente sobre o índice glicêmico (IG. O IG de alimentos cozidos ou cozidos e armazenados a -20ºC por 30 dias foi avaliado em ensaios de curta duração com humanos. Aumento significativo no conteúdo de AR foi evidenciado para todos os alimentos armazenados. O armazenamento dos alimentos resultou em significativa redução no IG do feijão e do grão de bico. O IG do macarrão foi o mesmo e da polenta sofreu aumento. Desta forma, a evidenciada formação de AR mostrou reduzida influência no IG. O armazenamento de alimentos fonte de amido sob baixa temperatura pode colaborar com a ingestão de AR, mas o efeito sobre o IG vai depender das características dos carboidratos de cada alimento.

  15. Cobalt-lanthanum catalyst precursors for ammonia synthesis: determination of calcination temperature and storage conditions

    Directory of Open Access Journals (Sweden)

    Zybert Magdalena

    2017-06-01

    Full Text Available A thermal decomposition of a cobalt-lanthanum catalyst precursor containing a mixture of cobalt and lanthanum compounds obtained by co-precipitation were studied using thermal analysis coupled with mass spectrometry (TG-MS. Studies revealed that the calcination in air at 500°C is sufficient to transform the obtained cobalt precipitate into Co3O4, but it leads to only partial decomposition of lanthanum precipitate. In order to obtain Co/La catalyst precursor containing La2O3 the calcination in air at the temperature about 800°C is required. However, it is unfavorable from the point of view of textural properties of the catalyst precursor. A strong effect of storage conditions on the phase composition of the studied cobalt-lanthanum catalyst precursor, caused by the formation of lanthanum hydroxide and lanthanum carbonates from La2O3 when contacting with air, was observed.

  16. Active heat exchange system development for latent heat thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Alario, J.; Kosson, R.; Haslett, R.

    1980-01-01

    The selection and evaluation phase of a program to develop active heat exchange concepts for latent heat thermal energy storage systems applicable to the utility industry is described. An evaluation of suitable storage media with melting points in the temperature range of interest (250 to 400/sup 0/C) limited the candidates to molten salts from the chloride, hydroxide and nitrate families, based on high storage capacity, good corrosion characteristics and availability in large quantities at reasonable cost. The specific salt recommended for laboratory tests was a chloride eutectic (20.5KCl-24.5NaCl-55.0MgCl/sub 2/% by wt), with a nominal melting point of 385/sup 0/C. Various active heat exchange concepts were identified from among three generic categories: scrapers, agitators/vibrators and slurries. The more practical ones were given a more detailed technical evaluation and an economic comparison with a passive tube-shell design for a reference application (300 MW/sub t/ storage for 6 hours). Two concepts were selected for hardware development: a direct contact heat exchanger in which molten salt droplets are injected into a cooler counterflowing stream of liquid metal carrier fluid, and a rotating drum scraper in which molten salt is sprayed onto the circumference of a rotating drum, which contains the fluid heat sink in an internal annulus near the surface. A fixed scraper blade removes the solidified salt from the surface which has been nickel plated to decrease adhesion forces. In addition to improving performance by providing a nearly constant heat transfer rate during discharge, these active heat exchanger concepts were estimated to cost at least 25% less than the passive tube-shell design.

  17. Preharvest temperature affects chilling injury in dessert bananas during storage.

    Science.gov (United States)

    Bugaud, Christophe; Joannès-Dumec, Charlène; Louisor, Jacques; Tixier, Philippe; Salmon, Frédéric

    2016-05-01

    The effect of temperature on chilling injury during fruit growth was studied in a new banana hybrid CIRAD925 in which seasonal variability in chilling susceptibility was observed when fruits were stored at 13 °C. The relationship between the response to chilling (presence/absence) and the temperature during banana fruit growth was examined with a logistic regression model. An explanatory variable XN , P was defined as the mean temperature during a period, expressed in weeks, which began N week(s) after flowering and lasted P week(s). The model was calibrated with 143 bunches with a green life of 30 ± 5 days and validated with 156 bunches grown in six plots under different growing conditions. Chilling injury was best predicted by the mean temperature during the period beginning 1 week after flowering and lasting 5 weeks (X1,5 ). Above a mean temperature of 24.1 °C in the period concerned, banana fruits had a 95% probability of chilling injury at 13 °C. Below a temperature of 23.4 °C, banana fruits only had a 5% probability of chilling injury. The results provide a tool to predict chilling susceptibility in banana fruit whatever the thermal conditions in tropical regions. © 2015 Society of Chemical Industry. © 2015 Society of Chemical Industry.

  18. Performance of modified greenhouse dryer with thermal energy storage

    Directory of Open Access Journals (Sweden)

    Om Prakash

    2016-11-01

    Full Text Available In this attempt, the main goal is to do annual performance, environomical analysis, energy analysis and exergy analysis of the modified greenhouse dryer (MGD operating under active mode (AM and passive mode (PM. Thermal storage is being applied on the ground of MGD. It is applied in three different ways namely barren floor, floor covered with black PVC sheet (PVC and Black Coated. Experimental study of dryers in no-load conditions reveals that floor covered with a black PVC sheet is more conducive for drying purpose than other floors. The MGD under AM is found to be more effective as compared to PM for tomato and capsicum, which are high moisture content crops. For medium moisture content crop (potato chips, both dryers show relatively similar drying performance. Crops dried inside the greenhouse dryer are found to be more nutrient than open sun dried crops. The payback period of the modified greenhouse dryer under passive mode is found to be 1.11 years. However, for the active mode of the modified greenhouse dryer is only 1.89 years. The embodied energy of the passive mode of the dryer is a 480.277 kWh and 628.73 kWh for the active mode of the dryer. The CO2 emissions per annum for passive and active mode greenhouse dryers are found to be 13.45 kg and 17.6 kg respectively. The energy payback time, carbon mitigation and carbon credit have been calculated based type of crop dried. The range of exergy efficiency is 29%–86% in MGD under PM and 30%–78% in the MGD under AM. The variation of Heat utilization factor (HUF for MGD under PM is 0.12–0.38 and 0.26–0.53 for MGD under AM. The range of co-efficient of performances (COP for MGD under PM is 0.55–0.87 and 0.58–0.73 for MGD under AM.

  19. Impact of thermal energy storage properties on solar dynamic space power conversion system mass

    Science.gov (United States)

    Juhasz, Albert J.; Coles-Hamilton, Carolyn E.; Lacy, Dovie E.

    1987-01-01

    A 16 parameter solar concentrator/heat receiver mass model is used in conjunction with Stirling and Brayton Power Conversion System (PCS) performance and mass computer codes to determine the effect of thermal energy storage (TES) material property changes on overall PCS mass as a function of steady state electrical power output. Included in the PCS mass model are component masses as a function of thermal power for: concentrator, heat receiver, heat exchangers (source unless integral with heat receiver, heat sink, regenerator), heat engine units with optional parallel redundancy, power conditioning and control (PC and C), PC and C radiator, main radiator, and structure. Critical TES properties are: melting temperature, heat of fusion, density of the liquid phase, and the ratio of solid-to-liquid density. Preliminary results indicate that even though overall system efficiency increases with TES melting temperature up to 1400 K for concentrator surface accuracies of 1 mrad or better, reductions in the overall system mass beyond that achievable with lithium fluoride (LiF) can be accomplished only if the heat of fusion is at least 800 kJ/kg and the liquid density is comparable to that of LiF (1800 kg/cu m).

  20. Thermal Emissivity and Cigarette Coal Temperature During Smolder

    Directory of Open Access Journals (Sweden)

    Lyman CS

    2014-12-01

    Full Text Available Coal temperatures affect the burn properties of cigarettes. Thermal imaging was used to determine the average maximum surface coal temperatures during smolder of cigarettes of different tobacco types. The thermal imaging camera was calibrated against a reference blackbody. An emissivity correction was necessary since the set point temperatures of the reference blackbody did not correspond to the measured temperatures of the reference blackbody. A 0.87 camera emissivity was applied to provide accurate coal temperatures at a corrected emissivity of approximately 1. The average maximum surface coal temperatures during smolder of unfiltered single-tobacco-type cigarettes and a commercial blend cigarette were determined (with the camera lens focused parallel to the cigarette, and no discernible differences among them were found. The calculated average maximum surface coal temperature during smolder for all cigarettes was 584 AA± 15 °C. During smolder, thermocouples were used to measure the temperature of the gas phase (along the central axis of coal, and the thermal imaging camera was used to measure the temperature of the solid phase of the coal's surface. Using thermocouples, the peak coal temperatures in the center of the coal during smolder for three filtered single-tobacco-type cigarettes were 736-744 °C. Peak coal temperatures, measured by thermal imaging, on the surface of the coal (with the camera lens focused coaxially with the coal and the ash removed for the same three single-tobacco-type cigarettes had a range of 721-748 °C. There was good correspondence between the two techniques. These results confirm that during smolder the gas-phase temperature inside the coal (as measured with the thermocouple and the solid-phase temperatures beneath the ash (as measured with the camera are in near thermal equilibrium. With proper calibration, a thermal imaging system is a good alternative to thermocouples for measuring cigarette coal

  1. Feasibility study of D-mannitol as phase change material for thermal storage

    Directory of Open Access Journals (Sweden)

    Rocío Bayón

    2017-05-01

    Full Text Available The feasibility of D-mannitol as PCM for latent heat storage has been studied by keeping it melted at 180 ºC in air for up to 16 days. During this period of time, down to 80% initial mass was lost and sample appearance changed to a dark-brown-sticky paste. The strong mass decrease implies that not only water but also carbon containing volatile species are produced. These results indicate that D-mannitol undergoes thermal degradation which can be associated to caramelization processes similar to the ones occurring in sugars. Such processes involve complex reactions like dehydrations, condensations and polymerizations, which lead to a great variety of volatile and non-volatile products. Various characterization techniques have been applied in order to study both kinetics and reaction products. From the kinetic point of view thermal degradation of D-mannitol proceeds much faster and at lower temperatures than predicted by the models found in the literature. In relation to the degradation products, the analyses with liquid chromatography indicate the formation of three compounds although their stoichiometry could not be fully elucidated with the characterization techniques applied in this work. However it seems that some of the products are polymeric species that contain carbonyl groups and that are the responsible for the sample browning, the strong absorption in the 200 nm–500 nm range, the two bands at 1730 cm–1–1645 cm–1 observed in infrared spectra and also for the occurrence of a glass transition. Therefore this study proves that D-mannitol undergoes strong and fast degradation at temperatures close to its melting point which should be enough reason for avoiding its use as PCM in any latent heat storage application unless it is somehow stabilized.

  2. Fluid temperatures: Modeling the thermal regime of a river network

    Science.gov (United States)

    Rhonda Mazza; Ashley Steel

    2017-01-01

    Water temperature drives the complex food web of a river network. Aquatic organisms hatch, feed, and reproduce in thermal niches within the tributaries and mainstem that comprise the river network. Changes in water temperature can synchronize or asynchronize the timing of their life stages throughout the year. The water temperature fluctuates over time and place,...

  3. Effect of storage temperature on the motility of west African dwarf ...

    African Journals Online (AJOL)

    Semen stored under refrigerator has significantly higher value (P<0.01, P<0.05) when compared to semen stored under room temperature. This implies that refrigerator temperature preserved ram sperms motility better than room temperature under the same storage diluent. Keywords: Effect, Storage temperature, Motility, ...

  4. Low-temperature aluminum reduction of graphene oxide, electrical properties, surface wettability, and energy storage applications.

    Science.gov (United States)

    Wan, Dongyun; Yang, Chongyin; Lin, Tianquan; Tang, Yufeng; Zhou, Mi; Zhong, Yajuan; Huang, Fuqiang; Lin, Jianhua

    2012-10-23

    Low-temperature aluminum (Al) reduction is first introduced to reduce graphene oxide (GO) at 100-200 °C in a two-zone furnace. The melted Al metal exhibits an excellent deoxygen ability to produce well-crystallized reduced graphene oxide (RGO) papers with a low O/C ratio of 0.058 (Al-RGO), compared with 0.201 in the thermally reduced one (T-RGO). The Al-RGO papers possess outstanding mechanical flexibility and extremely high electrical conductivities (sheet resistance R(s) ~ 1.75 Ω/sq), compared with 20.12 Ω/sq of T-RGO. More interestingly, very nice hydrophobic nature (90.5°) was observed, significantly superior to the reported chemically or thermally reduced papers. These enhanced properties are attributed to the low oxygen content in the RGO papers. During the aluminum reduction, highly active H atoms from H(2)O reacted with melted Al promise an efficient oxygen removal. This method was also applicable to reduce graphene oxide foams, which were used in the GO/SA (stearic acid) composite as a highly thermally conductive reservoir to hold the phase change material for thermal energy storage. The Al-reduced RGO/SnS(2) composites were further used in an anode material of lithium ion batteries possessing a higher specific capacity. Overall, low-temperature Al reduction is an effective method to prepare highly conductive RGO papers and related composites for flexible energy conversion and storage device applications.

  5. Molten salt thermal energy storage systems: system design. [LiKCO/sub 3/ mixture

    Energy Technology Data Exchange (ETDEWEB)

    Maru, H.C.; Kardas, A.; Huang, V.M.; Dullea, J.F.; Paul, L.; Marianowski, L.G.

    1977-02-01

    A five-task research program aimed at the development of molten salt thermal energy storage systems commenced in June 1976. The first topical report, covering Task 1, the selection of suitable salt systems for storage at 850 to 1000/sup 0/F, was issued in August 1976. It was concluded that a 35 Wt percent Li/sub 2/CO/sub 3/-65 Wt percent K/sub 2/CO/sub 3/ (LiKCO/sub 3/) mixture was most suitable for the purpose. Interrelationships between various design parameters were examined using the available solutions, and an engineering-scale storage unit was designed. This unit has an annular configuration with a 1-ft OD, 1.5-ft high, 2-in. dia heat transfer well. Preliminary experiments on a pilot size (3-in. OD) unit showed that temperature profiles and progress of the solid-liquid interface agreed with those predicted theoretically. Also, no supercooling was observed during cooldown, and the presence of significant convective mixing was indicated by negligible temperature gradients. Use of a lithium aluminate volume-change suppressor was investigated, but it appears to be nonessential because of the low volume-change in the LiKCO/sub 3/ system. Consideration of the relative heat-transfer resistances under practical conditions suggested that the use of a conductivity promoter will enhance the heat-transfer rates, thereby requiring smaller heat-transfer areas. Different configurations and materials were considered for this application; an aluminum wool appears to be most suitable. The corrosion resistance of various construction materials was investigated. Stainless steels and aluminum appear to be suitable construction materials for carbonates in the 850 to 1000/sup 0/F range. Testing of the engineering-scale system (Task 3) and verification of the conclusions derived under Task 2 are in progress.

  6. Methane storage in flexible metal-organic frameworks with intrinsic thermal management

    Science.gov (United States)

    Mason, Jarad A.; Oktawiec, Julia; Taylor, Mercedes K.; Hudson, Matthew R.; Rodriguez, Julien; Bachman, Jonathan E.; Gonzalez, Miguel I.; Cervellino, Antonio; Guagliardi, Antonietta; Brown, Craig M.; Llewellyn, Philip L.; Masciocchi, Norberto; Long, Jeffrey R.

    2015-11-01

    As a cleaner, cheaper, and more globally evenly distributed fuel, natural gas has considerable environmental, economic, and political advantages over petroleum as a source of energy for the transportation sector. Despite these benefits, its low volumetric energy density at ambient temperature and pressure presents substantial challenges, particularly for light-duty vehicles with little space available for on-board fuel storage. Adsorbed natural gas systems have the potential to store high densities of methane (CH4, the principal component of natural gas) within a porous material at ambient temperature and moderate pressures. Although activated carbons, zeolites, and metal-organic frameworks have been investigated extensively for CH4 storage, there are practical challenges involved in designing systems with high capacities and in managing the thermal fluctuations associated with adsorbing and desorbing gas from the adsorbent. Here, we use a reversible phase transition in a metal-organic framework to maximize the deliverable capacity of CH4 while also providing internal heat management during adsorption and desorption. In particular, the flexible compounds Fe(bdp) and Co(bdp) (bdp2- = 1,4-benzenedipyrazolate) are shown to undergo a structural phase transition in response to specific CH4 pressures, resulting in adsorption and desorption isotherms that feature a sharp ‘step’. Such behaviour enables greater storage capacities than have been achieved for classical adsorbents, while also reducing the amount of heat released during adsorption and the impact of cooling during desorption. The pressure and energy associated with the phase transition can be tuned either chemically or by application of mechanical pressure.

  7. Eutectic mixtures of some fatty acids for low temperature solar heating applications: Thermal properties and thermal reliability

    Energy Technology Data Exchange (ETDEWEB)

    Sari, Ahmet [Department of Chemistry, Gaziosmanpasa University, 60240 Tokat (Turkey)]. E-mail: asari@gop.edu.tr

    2005-10-01

    The thermal properties and thermal reliability of the eutectic mixtures of lauric acid-myristic acid (LA-MA), lauric acid-palmitic acid (LA-PA), myristic acid-stearic acid (MA-SA) as phase change material (PCM) were determined after repeated melt/freeze cycles by the method of differential scanning calorimeter (DSC). The DSC thermal analysis results indicate that the binary systems of LA-MA in ratio of 66.0:34.0 wt.%, LA-PA in ratio of 69.0:31.0 wt.% and MA-SA in ratio of 64.0:36.0 wt.% form eutectic mixture with a melting temperature of 34.2 deg. C, 35.2 deg. C and 44.1 deg. C, and with a latent heat of fusion of 166.8 J g{sup -1}, 166.3 J g{sup -1} and 182.4 J g{sup -1}, respectively. The changes in the melting temperatures and the latent heats of fusion are in the range of -0.31 deg. C-0.14 deg. C and 0.9%-2.4% for LA-MA, -0.40 deg. C-0.23 deg. C and 1.5%-3.0% for LA-PA, and 1.11 deg. C-0.26 deg. C and -1.10%-2.2% for MA-SA during the 1460 thermal cycles. Based on the results, it can be concluded that the studied PCMs have good thermal properties and thermal reliability for a four-year energy storage period, which corresponds to 1460 thermal cycles, in terms of the change in their melting temperatures and latent heats of fusion.

  8. Thermal Energy Storage for Space Cooling--Federal Technology Alert

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Daryl R

    2000-12-31

    Cool storage technology can be used to significantly reduce energy costs by allowing energy-intensive, electrically driven cooling equipment to be predominantly operated during off peak hours when electricity rates are lower. This Federal Technology Alert, which is sponsored by DOE's Federal Energy Management Program (FEMP), describes the basic types of cool storage technologies and cooling system integration options. In addition, it defines the savings potential in the federal sector, presents application advice, and describes the performance experience of specific federal users. The results of a case study of a GSA building using cool storage technology are also provided.

  9. Design and fabrication of a direct contact latent thermal energy storage heat exchanger

    Science.gov (United States)

    Alario, J. P.; Brown, R. F.

    1984-06-01

    Originally intended for solar-thermal applications, the present direct contact, latent thermal energy storage heat exchanger has a 10 kW-h storage capacity and a 10 kW heat transfer rate. The inorganic eutectic NaNO3-KNO3 salt is used as the latent energy storage medium, and the liquid metal Pb-Bi eutectic is used as an intermediate heat exchange fluid. The heat exchange mechanism injects molten salt droplets at the bottom of a counterflowing liquid metal column.

  10. Microscale solid-state thermal diodes enabling ambient temperature thermal circuits for energy applications

    KAUST Repository

    Wang, Song

    2017-05-10

    Thermal diodes, or devices that transport thermal energy asymmetrically, analogous to electrical diodes, hold promise for thermal energy harvesting and conservation, as well as for phononics or information processing. The junction of a phase change material and phase invariant material can form a thermal diode; however, there are limited constituent materials available for a given target temperature, particularly near ambient. In this work, we demonstrate that a micro and nanoporous polystyrene foam can house a paraffin-based phase change material, fused to PMMA, to produce mechanically robust, solid-state thermal diodes capable of ambient operation with Young\\'s moduli larger than 11.5 MPa and 55.2 MPa above and below the melting transition point, respectively. Moreover, the composites show significant changes in thermal conductivity above and below the melting point of the constituent paraffin and rectification that is well-described by our previous theory and the Maxwell–Eucken model. Maximum thermal rectifications range from 1.18 to 1.34. We show that such devices perform reliably enough to operate in thermal diode bridges, dynamic thermal circuits capable of transforming oscillating temperature inputs into single polarity temperature differences – analogous to an electrical diode bridge with widespread implications for transient thermal energy harvesting and conservation. Overall, our approach yields mechanically robust, solid-state thermal diodes capable of engineering design from a mathematical model of phase change and thermal transport, with implications for energy harvesting.

  11. Temperature-dependent thermal properties of ex vivo liver undergoing thermal ablation.

    Science.gov (United States)

    Guntur, Sitaramanjaneya Reddy; Lee, Kang Il; Paeng, Dong-Guk; Coleman, Andrew John; Choi, Min Joo

    2013-10-01

    Thermotherapy uses a heat source that raises temperatures in the target tissue, and the temperature rise depends on the thermal properties of the tissue. Little is known about the temperature-dependent thermal properties of tissue, which prevents us from accurately predicting the temperature distribution of the target tissue undergoing thermotherapy. The present study reports the key thermal parameters (specific heat capacity, thermal conductivity and heat diffusivity) measured in ex vivo porcine liver while being heated from 20 ° C to 90 ° C and then naturally cooled down to 20 ° C. The study indicates that as the tissue was heated, all the thermal parameters resulted in plots with asymmetric quasi-parabolic curves with temperature, being convex downward with their minima at the turning temperature of 35-40 ° C. The largest change was observed for thermal conductivity, which decreased by 9.6% from its initial value (at 20 ° C) at the turning temperature (35 ° C) and rose by 45% at 90 ° C from its minimum (at 35 ° C). The minima were 3.567 mJ/(m(3) ∙ K) for specific heat capacity, 0.520 W/(m.K) for thermal conductivity and 0.141 mm(2)/s for thermal diffusivity. The minimum at the turning temperature was unique, and it is suggested that it be taken as a characteristic value of the thermal parameter of the tissue. On the other hand, the thermal parameters were insensitive to temperature and remained almost unchanged when the tissue cooled down, indicating that their variations with temperature were irreversible. The rate of the irreversible rise at 35 ° C was 18% in specific heat capacity, 40% in thermal conductivity and 38.3% in thermal diffusivity. The study indicates that the key thermal parameters of ex vivo porcine liver vary largely with temperature when heated, as described by asymmetric quasi-parabolic curves of the thermal parameters with temperature, and therefore, substantial influence on the temperature distribution of the tissue undergoing

  12. Thermal/oxidation storage stability of bio-diesel fuels

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2009-12-15

    This paper presented the results of a study conducted to determine the effectiveness of antioxidant additives in biodiesel fuel blends in preventing the formation of corrosive acids and deposits that increase wear in engine fuel pumps and fuel injectors. The 12-week storage stability of 54 biodiesel fuels made with canola methyl ester (CME), soybean methyl ester (SME) and tallow methyl ester (TME) was investigated with and without commercially prepared antioxidants. The experimental study investigated the formation of insoluble oxidation products produced in the biodiesel fuels during long-term storage. The Rancimat oxidation stability test was used to assess oxidation stability before and after long-term storage, as well as to assess total insolubles. Filter blocking tendency tests were also conducted. The study demonstrated that the use of antioxidants improved the long-term storage stability of the B5 and B20 CME, SME, and TME biodiesel fuel blends. 18 refs., 4 tabs., 12 figs., 17 appendices.

  13. Experimental Study of Thermal Energy Storage Characteristics using Heat Pipe with Nano-Enhanced Phase Change Materials

    Science.gov (United States)

    Krishna, Jogi; Kishore, P. S.; Brusly Solomon, A.

    2017-08-01

    The paper presents experimental investigations to evaluate thermal performance of heat pipe using Nano Enhanced Phase Change Material (NEPCM) as an energy storage material (ESM) for electronic cooling applications. Water, Tricosane and nano enhanced Tricosane are used as energy storage materials, operating at different heating powers (13W, 18W and 23W) and fan speeds (3.4V and 5V) in the PCM cooling module. Three different volume percentages (0.5%, 1% and 2%) of Nano particles (Al2O3) are mixed with Tricosane which is the primary PCM. This experiment is conducted to study the temperature distributions of evaporator, condenser and PCM during the heating as well as cooling. The cooling module with heat pipe and nano enhanced Tricosane as energy storage material found to save higher fan power consumption compared to the cooling module that utilities only a heat pipe.

  14. Optimization of Norbornadiene Compounds for Solar Thermal Storage by First-Principles Calculations.

    Science.gov (United States)

    Kuisma, Mikael; Lundin, Angelica; Moth-Poulsen, Kasper; Hyldgaard, Per; Erhart, Paul

    2016-07-21

    Molecular photoswitches capable of storing solar energy are interesting candidates for future renewable energy applications. Here, using quantum mechanical calculations, we carry out a systematic screening of crucial optical (solar spectrum match) and thermal (storage energy density) properties of 64 such compounds based on the norbornadiene-quadricyclane system. Whereas a substantial number of these molecules reach the theoretical maximum solar power conversion efficiency, this requires a strong red-shift of the absorption spectrum, which causes undesirable absorption by the photoisomer as well as reduced thermal stability. These compounds typically also have a large molecular mass, leading to low storage densities. By contrast, single-substituted systems achieve a good compromise between efficiency and storage density, while avoiding competing absorption by the photo-isomer. This establishes guiding principles for the future development of molecular solar thermal storage systems. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Impact of size and temperature on thermal expansion of nanomaterials

    Indian Academy of Sciences (India)

    Abstract. A theoretical method has been discussed to study the size dependency of thermal expan- sion of nanomaterials at higher temperature by considering the surface effect. A thermodynamical analysis of the equation of state (EoS) is studied from the knowledge of thermal expansion of nano- materials based on ...

  16. Impact of size and temperature on thermal expansion of nanomaterials

    Indian Academy of Sciences (India)

    A theoretical method has been discussed to study the size dependency of thermal expansion of nanomaterials at higher temperature by considering the surface effect. A thermodynamical analysis of the equation of state (EoS) is studied from the knowledge of thermal expansion of nano-materials based on theoretical ...

  17. Temperature dependence of thermal conductivity of vanadium ...

    Indian Academy of Sciences (India)

    Unknown

    . Cryogenic Engineering .... Thermal conductivity of vanadium substituted BPSCCO system. 441 trical resistivity as well as the small decrease ..... G, Marre D, Putti M and Siri A S 1997 Physica C273 314. Chawlek J M, Uher C, Whitaker J F and ...

  18. Thermal degradation kinetics and solid state, temperature ...

    Indian Academy of Sciences (India)

    WINTEC

    Phenothiazine derivatives belong to a big group of aromatic compounds. These derivatives are substituted in ... Elemental analysis for carbon, hydrogen, nitrogen and sulphur were done using Vario EL III CHNS ... The aim of the kinetic study of thermal analysis data is to find out the most probable kinetic model which best ...

  19. Modeling void growth and movement with phase change in thermal energy storage canisters

    Science.gov (United States)

    Darling, Douglas; Namkoong, David; Skarda, J. Raymond Lee

    1993-01-01

    A scheme was developed to model the thermal hydrodynamic behavior of thermal energy storage salts. The model included buoyancy, surface tension, viscosity, phases change with density difference, and void growth and movement. The energy, momentum, and continuity equations were solved using a finite volume formulation. The momentum equation was divided into two pieces. The void growth and void movement are modeled between the two pieces of the momentum equations. Results showed this scheme was able to predict the behavior of thermal energy storage salts.

  20. Application of thermal and flywheel energy storage in orbiting nuclear burst power systems

    Energy Technology Data Exchange (ETDEWEB)

    Wichner, R.P.; Olszewski, M.

    1987-03-01

    A survey was conducted of currently available thermal energy storage and flywheel energy storage technology and development programs as they may apply to nuclear-based, burst power systems. The manner in which such storage systems may be used in closed cycle, regenerable burst systems is described for a number of cases utilizing the Boiling Potassium Rankine and Dual Loop Lithium Cooled LMRs and the Direct Cycle Brayton HTGR. In general, energy storage devices for such systems enable use of smaller power system components by allowing continuous operation over the duration of both the bursts and the regeneration time. The degree of size reduction depends principally on the required regeneration time.

  1. Distillate yield improvement using a parabolic dish reflector coupled single slope basin solar still with thermal energy storage using beeswax

    Directory of Open Access Journals (Sweden)

    Aondoyila KUHE

    2016-07-01

    Full Text Available A single slope solar still, integrated with latent heat thermal energy storage system coupled to a parabolic concentrator was designed with the aim of improving productivity. 14 kg of beeswax was used as phase change material (PCM between the absorber plate and the bottom of the still to keep the operating temperature of the still high enough to produce distilled water even during the sunset hours. The bottom of the still is covered by 0.2 m aluminum sheet painted black on the side facing the parabolic concentrator to help in absorbing solar radiation reflected from the parabolic concentrator and conducting same to the PCM. To determine the effect of PCM, a solar still without PCM was used to compare with the solar still with PCM. The temperature of water, air temperature, inner surface glass temperature and outer surface glass temperature were measured. Experimental results show that the effect of thermal storage in the parabolic concentrator-coupled single slope solar still increased the productivity by 62%.

  2. Box-Behnken statistical design to optimize thermal performance of energy storage systems

    Science.gov (United States)

    Jalalian, Iman Joz; Mohammadiun, Mohammad; Moqadam, Hamid Hashemi; Mohammadiun, Hamid

    2017-11-01

    Latent heat thermal storage (LHTS) is a technology that can help to reduce energy consumption for cooling applications, where the cold is stored in phase change materials (PCMs). In the present study a comprehensive theoretical and experimental investigation is performed on a LHTES system containing RT25 as phase change material (PCM). Process optimization of the experimental conditions (inlet air temperature and velocity and number of slabs) was carried out by means of Box-Behnken design (BBD) of Response surface methodology (RSM). Two parameters (cooling time and COP value) were chosen to be the responses. Both of the responses were significantly influenced by combined effect of inlet air temperature with velocity and number of slabs. Simultaneous optimization was performed on the basis of the desirability function to determine the optimal conditions for the cooling time and COP value. Maximum cooling time (186 min) and COP value (6.04) were found at optimum process conditions i.e. inlet temperature of (32.5), air velocity of (1.98) and slab number of (7).

  3. Numerical investigation of temperature distribution and thermal performance while charging-discharging thermal energy in aquifer

    NARCIS (Netherlands)

    Ganguly, S.; Mohan Kumar, M.S.; Date, Abhijit; Akbarzadeh, Aliakbar

    2017-01-01

    A three-dimensional (3D) coupled thermo-hydrogeological numerical model for a confined aquifer thermal energy storage (ATES) system underlain and overlain by rock media has been presented in this paper. The ATES system operates in cyclic mode. The model takes into account heat transport processes of

  4. Physiological responses of Indian jujube (Ziziphus mauritiana Lamk.) fruit to storage temperature under modified atmosphere packaging.

    Science.gov (United States)

    Jat, Laxman; Pareek, Sunil; Shukla, Kunj B

    2013-06-01

    The effect of storage temperature on physiological responses in Indian jujube (Ziziphus mauritiana Lamk. cv. Gola) fruit was investigated. Freshly harvested fruits at physiological maturity characterised by colour-turning stage were stored at ambient temperature, 12 and 6 °C for 21, 35 and 35 days respectively. Headspace O2, CO2 and C2H4, moisture content, respiration, ethylene production, firmness, tristimulus colour, chroma, hue angle and chilling injury index were monitored during fruit storage. Rates of respiration and ethylene production increased after 1 week of storage at ambient temperature, while peaks were observed after 2 weeks at 12 and 6 °C. Headspace O2 decreased continuously during storage, while CO2 and C2H4 increased at all storage temperatures. Moisture content and firmness also decreased during storage. Hunter L* values increased during storage, which correlated with the darkening of fruit colour. Fruit stored at ambient temperature did not show any chilling injury symptoms, while chilling injury appeared on day 28 under 12 °C storage and on day 21 under 6 °C storage. Indian jujube fruit showed high rates of respiration and ethylene production that were significantly affected by different storage temperatures. Lower temperatures increased the shelf life of the fruit, but chilling injury was a problem under 6 °C storage. Indian jujube fruit could be stored at 6 °C for up to 35 days if chilling injury could be alleviated. © 2012 Society of Chemical Industry.

  5. Reactive Transport Modeling of Thermal Column Experiments to Investigate the Impacts of Aquifer Thermal Energy Storage on Groundwater Quality

    NARCIS (Netherlands)

    Bonte, M.; Stuijfzand, P.J.; van Breukelen, B.M.

    2014-01-01

    Aquifer thermal energy storage (ATES) systems are increasingly being used to acclimatize buildings and are often constructed in aquifers used for drinking water supply. This raises the question of potential groundwater quality impact. Here, we use laboratory column experiments to develop and

  6. Preparation, characterization, and thermal properties of starch microencapsulated fatty acids as phase change materials thermal energy storage applications

    Science.gov (United States)

    Stable starch-oil composites can be prepared from renewable resources by excess steam jet-cooking aqueous slurries of starch and vegetable oils or other hydrophobic materials. Fatty acids such as stearic acid are promising phase change materials (PCMs) for latent heat thermal energy storage applica...

  7. Thermal energy storage using phase change materials fundamentals and applications

    CERN Document Server

    Fleischer, Amy S

    2015-01-01

    This book presents a comprehensive introduction to the use of solid‐liquid phase change materials to store significant amounts of energy in the latent heat of fusion. The proper selection of materials for different applications is covered in detail, as is the use of high conductivity additives to enhance thermal diffusivity. Dr. Fleischer explores how applications of PCMS have expanded over the past 10 years to include the development of high efficiency building materials to reduce heating and cooling needs, smart material design for clothing, portable electronic systems thermal management, solar thermal power plant design and many others. Additional future research directions and challenges are also discussed.

  8. Latent heat storage in a solar thermal cooling system. Final report; Latentwaermespeicherung in einer solarthermisch angetriebenen Absorptionsklimakaelteanlage. Schlussbericht

    Energy Technology Data Exchange (ETDEWEB)

    Gramlich, K.; Safarik, M.; Schammler, G.

    2001-07-31

    There are not latent heat storage systems in the temperature range above 90 C available at present. For solar thermal cooling the heat has to be provided at this level. The purpose of this study was to quantify the storage capacity and the performance of charging and discharging of a new developed 1 m{sup 3}-latent heat storage system and the constancy of the heat of fusion of the used paraffin. The latent heat storage system was installed and tested as part of a solar thermal cooling system. The constancy of the melting point was separately measured. After melting and solidifying 500 times the melting point of the tested paraffin was still unchanged. Once melted the paraffin in the storage remains more the 36 hours in this state. Therefore the fluctuations in solar radiation and cooling demand over the day can be compensated. Because of the small thermal conductivity of the paraffin the velocity of heat transfer is small, too. The performance is increased by adding metal carrier material to the storage. The latent heat storage system is capable to work within a solar thermal cooling system because of its composition, the used heat storage material and the integration into the whole system. (orig.) [German] Latent-Waermespeicher im Temperaturbereich ueber 90 C sind z.Z. nicht verfuegbar. Fuer die solarthermische Klimakaelteerzeugung muss die Antriebswaerme auf diesem Temperaturniveau bereitgestellt werden. Ziel der Untersuchungen waren Messungen zur Speicherkapazitaet, zur Lade- und Entladeleistung und zur Konstanz der Schmelzenthalpie von Paraffin in einem neu konstruierten 1000 l - Speicher. Der Paraffin-Latentwaermespeicher wurde in einer Solarthermieanlage zur Klimakaelteerzeugung integriert und die Speicherfunktionen im Anlagenbetrieb untersucht. Die Stabilitaet der Schmelztemperatur in Abhaengigkeit von den Phasenwechseln wurde separat gemessen. Die Schmelztemperatur bleibt nach ueber 500 Phasenwechseln konstant. Das Paraffin konnte ueber 36 Stunden im

  9. Automatic Thermal Control System with Temperature Difference or Derivation Feedback

    Directory of Open Access Journals (Sweden)

    Darina Matiskova

    2016-02-01

    Full Text Available Automatic thermal control systems seem to be non-linear systems with thermal inertias and time delay. A controller is also non-linear because its information and power signals are limited. The application of methods that are available to on-linear systems together with computer simulation and mathematical modelling creates a possibility to acquire important information about the researched system. This paper provides a new look at the heated system model and also designs the structure of the thermal system with temperature derivation feedback. The designed system was simulated by using a special software in Turbo Pascal. Time responses of this system are compared to responses of a conventional thermal system. The thermal system with temperature derivation feedback provides better transients, better quality of regulation and better dynamical properties.

  10. Temperature measurements using multicolor pyrometry in thermal radiation heating environments.

    Science.gov (United States)

    Fu, Tairan; Liu, Jiangfan; Duan, Minghao; Zong, Anzhou

    2014-04-01

    Temperature measurements are important for thermal-structural experiments in the thermal radiation heating environments such as used for thermal-structural stress analyses. This paper describes the use of multicolor pyrometry for the measurements of diffuse surfaces in thermal radiation environments that eliminates the effects of background radiation reflections and unknown emissivities based on a least-squares algorithm. The near-infrared multicolor pyrometer had a spectral range of 1100-2400 nm, spectrum resolution of 6 nm, maximum sampling frequency of 2 kHz, working distance of 0.6 m to infinity, temperature range of 700-1700 K. The pyrometer wavelength response, nonlinear intensity response, and spectral response were all calibrated. The temperature of a graphite sample irradiated by quartz lamps was then measured during heating and cooling using the least-squares algorithm based on the calibrated irradiation data. The experiments show that higher temperatures and longer wavelengths are more suitable for the thermal measurements in the quartz lamp radiation heating system. This analysis provides a valuable method for temperature measurements of diffuse surfaces in thermal radiation environments.

  11. Temperature measurements using multicolor pyrometry in thermal radiation heating environments

    Energy Technology Data Exchange (ETDEWEB)

    Fu, Tairan, E-mail: trfu@mail.tsinghua.edu.cn [Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China); Beijing Key Laboratory of CO2 Utilization and Reduction Technology, Beijing 100084 (China); Liu, Jiangfan; Duan, Minghao; Zong, Anzhou [Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Department of Thermal Engineering, Tsinghua University, Beijing 100084 (China)

    2014-04-15

    Temperature measurements are important for thermal-structural experiments in the thermal radiation heating environments such as used for thermal-structural stress analyses. This paper describes the use of multicolor pyrometry for the measurements of diffuse surfaces in thermal radiation environments that eliminates the effects of background radiation reflections and unknown emissivities based on a least-squares algorithm. The near-infrared multicolor pyrometer had a spectral range of 1100–2400 nm, spectrum resolution of 6 nm, maximum sampling frequency of 2 kHz, working distance of 0.6 m to infinity, temperature range of 700–1700 K. The pyrometer wavelength response, nonlinear intensity response, and spectral response were all calibrated. The temperature of a graphite sample irradiated by quartz lamps was then measured during heating and cooling using the least-squares algorithm based on the calibrated irradiation data. The experiments show that higher temperatures and longer wavelengths are more suitable for the thermal measurements in the quartz lamp radiation heating system. This analysis provides a valuable method for temperature measurements of diffuse surfaces in thermal radiation environments.

  12. Temperature measurements using multicolor pyrometry in thermal radiation heating environments

    Science.gov (United States)

    Fu, Tairan; Liu, Jiangfan; Duan, Minghao; Zong, Anzhou

    2014-04-01

    Temperature measurements are important for thermal-structural experiments in the thermal radiation heating environments such as used for thermal-structural stress analyses. This paper describes the use of multicolor pyrometry for the measurements of diffuse surfaces in thermal radiation environments that eliminates the effects of background radiation reflections and unknown emissivities based on a least-squares algorithm. The near-infrared multicolor pyrometer had a spectral range of 1100-2400 nm, spectrum resolution of 6 nm, maximum sampling frequency of 2 kHz, working distance of 0.6 m to infinity, temperature range of 700-1700 K. The pyrometer wavelength response, nonlinear intensity response, and spectral response were all calibrated. The temperature of a graphite sample irradiated by quartz lamps was then measured during heating and cooling using the least-squares algorithm based on the calibrated irradiation data. The experiments show that higher temperatures and longer wavelengths are more suitable for the thermal measurements in the quartz lamp radiation heating system. This analysis provides a valuable method for temperature measurements of diffuse surfaces in thermal radiation environments.

  13. Photoswitchable Molecular Rings for Solar-Thermal Energy Storage.

    Science.gov (United States)

    Durgun, E; Grossman, Jeffrey C

    2013-03-21

    Solar-thermal fuels reversibly store solar energy in the chemical bonds of molecules by photoconversion, and can release this stored energy in the form of heat upon activation. Many conventional photoswichable molecules could be considered as solar thermal fuels, although they suffer from low energy density or short lifetime in the photoinduced high-energy metastable state, rendering their practical use unfeasible. We present a new approach to the design of chemistries for solar thermal fuel applications, wherein well-known photoswitchable molecules are connected by different linker agents to form molecular rings. This approach allows for a significant increase in both the amount of stored energy per molecule and the stability of the fuels. Our results suggest a range of possibilities for tuning the energy density and thermal stability as a function of the type of the photoswitchable molecule, the ring size, or the type of linkers.

  14. Photoswichable Molecular Rings for Solar-Thermal Energy Storage

    Science.gov (United States)

    Durgun, Engin; Kolpak, Alexie M.; Grossman, Jeffrey C.

    2012-02-01

    Solar-thermal fuels reversibly store solar energy in the chemical bonds of molecules by photoconversion, and can release this stored energy in the form of heat upon activation. Many conventional photoswichable molecules could be considered as solar thermal fuels, although they suffer from low energy density and short lifetime in the photo-excited state, rendering their practical use unfeasible. We present a new approach to design systems for solar thermal fuel applications, wherein well-known photoswitchable molecules are connected by different linker agents to form molecular rings. This approach allows for a significant increase in both the amount of stored energy per molecule and the stability of the fuels. Our results suggest a range of possibilities for tuning the energy density and thermal stability as a function of the type of the photoswitchable molecule, the ring size, and/or the type of linkers.

  15. Diurnal cool thermal energy storage: Research programs, technological developments, and commercial status

    Energy Technology Data Exchange (ETDEWEB)

    Wise, M A

    1992-01-01

    This report presents an overview of the major federal and private research and development efforts in diurnal cool thermal energy storage for electric load management in buildings. Included are brief technical descriptions and research histories of the technologies and applications of cool thermal storage. The goals, accomplishments, and funding levels of major thermal storage research programs also are summarized. The report concludes with the results of recent field performance evaluations of cool thermal storage installations and a discussion of the current commercial status of thermal storage equipment, including utility participation programs. This report was sponsored by the Technology and Consumer Products (TCP) Division within the Office of Conservation of the US Department of Energy. This report is part of TCP's ongoing effort to examine and evaluate technology developments and research efforts in the areas of lighting, space heating and cooling, water heating, refrigeration, and other building energy conversion equipment. Information obtained through this effort is used as an input in developing the US research agenda in these areas.

  16. High Temperature Metal Hydrides as Heat Storage Materials for Solar and Related Applications

    Directory of Open Access Journals (Sweden)

    Borislav Bogdanović

    2009-01-01

    Full Text Available For the continuous production of electricity with solar heat power plants the storage of heat at a temperature level around 400 °C is essential. High temperature metal hydrides offer high heat storage capacities around this temperature. Based on Mg-compounds, these hydrides are in principle low-cost materials with excellent cycling stability. Relevant properties of these hydrides and their possible applications as heat storage materials are described.

  17. Thermal Aware Floorplanning Incorporating Temperature Dependent Wire Delay Estimation

    DEFF Research Database (Denmark)

    Winther, AndreasThor; Liu, Wei; Nannarelli, Alberto

    2015-01-01

    Temperature has a negative impact on metal resistance and thus wire delay. In state-of-the-art VLSI circuits, large thermal gradients usually exist due to the uneven distribution of heat sources. The difference in wire temperature can lead to performance mismatch because wires of the same length ...

  18. On the effect of temperature dependent thermal conductivity on ...

    African Journals Online (AJOL)

    We consider the effect of temperature dependent thermal conductivity on temperature rise in biologic tissues during microwave heating. The method of asymptotic expansion is used for finding solution. An appropriate matching procedure was used in our method. Our result reveals the possibility of multiple solutions and it ...

  19. Exergy analysis of integrated photovoltaic thermal solar water heater under constant flow rate and constant collection temperature modes

    NARCIS (Netherlands)

    Tiwari, A.; Dubey, Swapnil; Sandhu, G.S.; Sodha, M.S.; Anwar, S.I.

    2009-01-01

    In this communication, an analytical expression for the water temperature of an integrated photovoltaic thermal solar (IPVTS) water heater under constant flow rate hot water withdrawal has been obtained. Analysis is based on basic energy balance for hybrid flat plate collector and storage tank,

  20. Application of EPR spectroscopy to examine free radicals evolution during storage of the thermally sterilized Ungentum ophthalmicum.

    Science.gov (United States)

    Ramos, Paweł; Pilawa, Barbara

    2016-06-24

    Free radicals formed during thermal sterilization of the Ungentum ophthalmicum were examined by an X-band EPR spectroscopy. The influence of storage time (15 min; 1, 2 and 3 days after heating) on free radical properties and concentrations in this sample was determined. Thermal sterilization was done according to the pharmaceutical norms. The first-derivative EPR spectra with g-values about 2 were measured with magnetic modulation of 100 kHz in the range of microwave power 2.2-70 mW. The changes of amplitudes (A) and linewidths (ΔBpp) with microwave powers were evaluated. Free radicals in concentration ∼10(17) spin/g were formed during heating of the tested Ungentum. Free radical concentration decreased with increase in storage time, and reached values ∼10(17) spin/g after 3 days from sterilization. The tested U. ophthalmicum should not be sterilized at a temperature of 160 °C because of the free radicals formation, or it should be used 3 days after heating, when free radicals were considerably quenched. Free radical properties remain unchanged during storage of the Ungentum. The EPR lines of the U. ophthalmicum were homogeneously broadened and their linewidths (ΔBpp) increased with increase in microwave power. EPR spectroscopy is useful to examine free radicals to optimize sterilization process and storage conditions of ophthalmologic samples.

  1. Thermal behavior of a heat exchanger module for seasonal heat storage

    DEFF Research Database (Denmark)

    Fan, Jianhua; Furbo, Simon; Andersen, Elsa

    2012-01-01

    are theoretically investigated by Computational Fluid Dynamics (CFD) calculations. The heat transfer rates between the PCM storage and the heating fluid/cooling fluid in the plate heat exchangers are determined. The CFD calculated temperatures are compared to measured temperatures. Based on the studies......Experimental and theoretic investigations are carried out to study the heat transfer capacity rate of a heat exchanger module for seasonal heat storage with sodium acetate trihydrate (SAT) supercooling in a stable way. A sandwich heat storage test module has been built with the phase change...... material (PCM) storage box in between two plate heat exchangers. Charge of the PCM storage is investigated experimentally with solid phase SAT as initial condition. Discharge of the PCM storage with the presence of crystallization is studied experimentally. Fluid flow and heat transfer in the PCM module...

  2. Storage temperature: A factor of shelf life of dairy products

    Directory of Open Access Journals (Sweden)

    Memiši Nurgin R.

    2014-01-01

    Full Text Available An experiment was designed to monitor the durability of certain dairy products stored at proper temperatures (8°C and elevated temperatures (14°C within their shelf life. Samples of fermented milk products were tested during 25 days, samples of cheese spread products over 80 days, while soft white cheese samples were analyzed during a storage period of 100 days. In the defined study periods, depending on the type of product, pH and aw value of the product, as well as sensory analysis (odor, taste, color and consistency, along with microbiological safety, were investigated. The investigations were performed in accordance with national legislation. The results indicate that the products stored at 14°C showed significant acidity (lower pH value, changed sensory properties, and had an increased number of aerobic bacteria. [Projekat Ministarstva nauke Republike Srbije, br. III 46009: Improvement and development of hygienic and technological procedures in production of foodstuffs of animal origin with the aim of producing high-quality and safe products competitive on the global market

  3. High Temperature Thermal Properties of Bentonite Foundry Sand

    Directory of Open Access Journals (Sweden)

    Krajewski P.K.

    2015-06-01

    Full Text Available The paper presents results of measuring thermal conductivity and heat capacity of bentonite foundry sand in temperature range ambient - 900­­°C. During the experiments a technical purity Cu plate was cast into the green-sand moulds. Basing on measurements of the mould temperature field during the solidification of the casting, the temperature relationships of the measured properties were evaluated. It was confirmed that water vaporization strongly influences thermal conductivity of the moulding sand in the first period of the mould heating by the poured casting.

  4. Large-Scale Wireless Temperature Monitoring System for Liquefied Petroleum Gas Storage Tanks

    Directory of Open Access Journals (Sweden)

    Guangwen Fan

    2015-09-01

    Full Text Available Temperature distribution is a critical indicator of the health condition for Liquefied Petroleum Gas (LPG storage tanks. In this paper, we present a large-scale wireless temperature monitoring system to evaluate the safety of LPG storage tanks. The system includes wireless sensors networks, high temperature fiber-optic sensors, and monitoring software. Finally, a case study on real-world LPG storage tanks proves the feasibility of the system. The unique features of wireless transmission, automatic data acquisition and management, local and remote access make the developed system a good alternative for temperature monitoring of LPG storage tanks in practical applications.

  5. Lightweight High-Temperature Thermal Insulation

    Science.gov (United States)

    Wagner, W. R.; Fasheh, J. I.

    1985-01-01

    Fine Ni/Cr fibers sintered into corrosion-resistant, fireproof batt. Possible applications include stoves, furnaces, safes, fire clothing, draperies in public buildings, wall firebreaks, airplane walls, and jetengine components. New insulation takes advantage of some of same properties of nickel/chromium alloy useful in heating elements in toasters, namely, corrosion and oxidation resistance even at high temperatures.

  6. High-temperature solar receiver integrated with a short-term storage system

    Science.gov (United States)

    Giovannelli, Ambra; Bashir, Muhammad Anser; Archilei, Erika Maria

    2017-06-01

    Small-Scale Concentrated Solar Power Plants could have a potential market for off-grid applications in rural contexts with limited access to the electrical grid and favorable environmental characteristics. Some Small-Scale plants have already been developed, like the 25-30 kWe Dish-Stirling engine. Other ones are under development as, for example, plants based on Parabolic Trough Collectors coupled with Organic Rankine Cycles. Furthermore, the technological progress achieved in the development of new small high-temperature solar receiver, makes possible the development of interesting systems based on Micro Gas Turbines coupled with Dish collectors. Such systems could have several advantages in terms of costs, reliability and availability if compared with Dish-Stirling plants. In addition, Dish-Micro Gas Turbine systems are expected to have higher performance than Solar Organic Rankine Cycle plants. The present work focuses the attention on some challenging aspects related to the design of small high-temperature solar receivers for Dish-Micro Gas Turbine systems. Natural fluctuations in the solar radiation can reduce system performance and damage seriously the Micro Gas Turbine. To stabilize the system operation, the solar receiver has to assure a proper thermal inertia. Therefore, a solar receiver integrated with a short-term storage system based on high-temperature phase-change materials is proposed in this paper. Steady-state and transient analyses (for thermal storage charge and discharge phases) have been carried out using the commercial CFD code Ansys-Fluent. Results are presented and discussed.

  7. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F. (Minnesota Geological Survey, St. Paul, MN (United States))

    1991-12-01

    The technical feasibility of high-temperature (>100{degrees}C (>212{degrees}F)) aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota's St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  8. University of Minnesota aquifer thermal energy storage (ATES) project report on the second long-term cycle

    Energy Technology Data Exchange (ETDEWEB)

    Hoyer, M.C.; Hallgren, J.P.; Lauer, J.L.; Walton, M.; Eisenreich, S.J.; Howe, J.T.; Splettstoesser, J.F. [Minnesota Geological Survey, St. Paul, MN (United States)

    1991-12-01

    The technical feasibility of high-temperature [>100{degrees}C (>212{degrees}F)] aquifer thermal energy storage (ATES) in a deep, confined aquifer was tested in a series of experimental cycles at the University of Minnesota`s St. Paul field test facility (FTF). This report describes the second long-term cycle (LT2), which was conducted from October 1986 through April 1987. Heat recovery; operational experience; and thermal, chemical, hydrologic, and geologic effects are reported. Approximately 61% of the 9.21 GWh of energy added to the 9.38 {times} 10{sup 4} m{sup 3} of ground water stored during LT2 was recovered. Temperatures of the water stored and recovered averaged 118{degrees}C (244{degrees}F) and 85{degrees}C (185{degrees}F), respectively. Results agreed with previous cycles conducted at the FTF. System operation during LT2 was nearly as planned. Operational experience from previous cycles at the FTF was extremely helpful. Ion-exchange softening of the heated and stored aquifer water prevented scaling in the system heat exchangers and the storage well, and changed the major-ion chemistry of the stored water. Sodium bicarbonate replaced magnesium and calcium bicarbonate as primary ions in the softened water. Water recovered form storage was approximately at equilibrium with respect to dissolved ions. Silica, calcium, and magnesium were significantly higher in recovered water than in injected water. Sodium was significantly lower in water recovered than in water stored.

  9. Experimental investigation for the optimization of heat pipe performance in latent heat thermal storage

    Energy Technology Data Exchange (ETDEWEB)

    Ladekar, Chandrakishor; Choudhary, S. K. [RTM Nagpur University, Wardha (India); Khandare, S. S. [B. D. College of Engineering, Wardha (India)

    2017-06-15

    We investigated the optimum performance of heat pipe in Latent heat thermal energy storage (LHTES), and compared it with copper pipe. Classical plan of experimentation was used to optimize the parameters of heat pipe. Heat pipe fill ratio, evaporator section length to condenser section length ratio i.e., Heat pipe length ratio (HPLR) and heat pipe diameter, was the parameter used for optimization, as result of parametric analysis. Experiment with flow rate of 10 lit./min. was conducted for different fill ratio, HPLR and different diameter. Fill ratio of 80 %, HPLR of 0.9 and heat pipe with diameter of 18 mm showed better trend in charging and discharging. Comparison between the storage tank with optimized heat pipe and copper pipe showed almost 186 % improvement in charging and discharging time compared with the copper pipe embedded thermal storage. Heat transfer between Heat transferring fluid (HTF) and Phase change material (PCM) increased with increase in area of heat transferring media, but storage density of storage tank decreased. Storage tank with heat pipe embedded in place of copper pipe is a better option in terms of charging and discharging time as well heat storage capacity due to less heat lost. This justifies the better efficiency and effectiveness of storage tank with embedded optimized heat pipe.

  10. Temperature dependence of thermal conductivity of biological tissues.

    Science.gov (United States)

    Bhattacharya, A; Mahajan, R L

    2003-08-01

    In this paper, we present our experimental results on the determination of the thermal conductivity of biological tissues using a transient technique based on the principles of the cylindrical hot-wire method. A novel, 1.45 mm diameter, 50 mm long hot-wire probe was deployed. Initial measurements were made on sponge, gelatin and Styrofoam insulation to test the accuracy of the probe. Subsequent experiments conducted on sheep collagen in the range of 25 degrees C thermal conductivity to be a linear function of temperature. Further, these changes in the thermal conductivity were found to be reversible. However, when the tissue was heated beyond 55 degrees C, irreversible changes in thermal conductivity were observed. Similar experiments were also conducted for determining the thermal conductivity of cow liver. In this case, the irreversible effects were found to set in much later at around 90 degrees C. Below this temperature, in the range of 25 degrees C thermal conductivity, as for sheep collagen, varied linearly with temperature. In the second part of our study, in vivo measurements were taken on the different organs of a living pig. Comparison with reported values for dead tissues shows the thermal conductivities of living organs to be higher, indicating thereby the dominant role played by blood perfusion in enhancing the net heat transfer in living tissues. The degree of enhancement is different in different organs and shows a direct dependence on the blood flow rate.

  11. Heat recovery from a thermal energy storage based on the Ca(OH){sub 2}/CaO cycle

    Energy Technology Data Exchange (ETDEWEB)

    Azpiazu, M.N. [E.T.S. Ingenieros, Bilbao (Spain). Dpto. de Ingenieria Quimica y del Medio Ambiente; Morquillas, J.M. [E.T.S. Ingenieros, Bilbao (Spain). Dpto. de Maquinas y Motores Termicos; Vazquez, A. [E.S. da Marina Civil, La Coruna (Spain). Dpto. de Energia y Propulsion Maritima

    2003-04-01

    Thermal energy storage is very important in many applications related to the use of waste heat from industrial processes, renewable energies or from other sources. Thermochemical storage is very interesting for long-term storage as it can be carried out at room temperature with no energy losses. Dehydration/hydration cycle of Ca(OH){sub 2}/CaO has been applied for thermal energy storage in two types of reactors. One of them was a prototype designed by the authors, and in the other type conventional laboratory glassware was used. Parameters such as specific heats, reaction rate and enthalpy, mass losses and heat release were monitored during cycles. Although in the hydration step water is normally added in vapour phase, liquid water, at 0{sup o}C has been used in these experiences. Results indicated that the energy storage system performance showed no significant differences, when we compared several hydration/dehydration cycles. The selected chemical reaction did not exhibit a complete reversibility because complete Ca(OH){sub 2} dehydration, was not achieved. However the system could be used satisfactorily along 20 cycles at least. Heat recovery experiments showed general system behaviour during the hydration step in both types of reactors. The designed prototype was more efficient in this step. Main conclusions suggested carrying out one complete cycle at a higher dehydration temperature to recover total system reversibility. A modification of the prototype design trying to enhance heat transfer from the Ca(OH){sub 2} bed could also be proposed. (author)

  12. Thermal Analysis of a Thermal Energy Storage Unit to Enhance a Workshop Heating System Driven by Industrial Residual Water

    National Research Council Canada - National Science Library

    Wenqiang Sun; Zuquan Zhao; Yanhui Wang

    2017-01-01

    .... However, the majority of applicable waste heat resources are high-grade or stable thermal energy, while the low-grade or unstable waste heat resources, especially low-temperature industrial residual water (IRW...

  13. Effect of storage time and temperature on the rheological and microstructural properties of gluten

    NARCIS (Netherlands)

    Nicolas, Y.; Smit, R.J.M.; van Aalst, H.; Esselink, F.J.; Weegels, P.L.; Agterof, W.G.M.

    2003-01-01

    To investigate the effects of frozen storage on the rheological and microstructural properties of gluten, two model systems were investigated: System A, gluten and water; System B, gluten, water, and NaCl. The storage time was varied from 1 to 16 weeks and the storage temperature was varied from -5

  14. Thermal properties of SFR-HPC exposed to high temperatures

    Science.gov (United States)

    Scheinherrová, Lenka; Pavlík, Zbyšek

    2017-07-01

    In this paper, a non-adiabatic method was used for the assessment of specific heat capacity of steel fibre reinforced high performance concrete in the temperature range 105-1000 °C. The tested SFR-HPC mix was produced from CEM II 42.5 R, ground granulated blast furnace slag, silica sand with maximum particle size of 2 mm, silica fume, brass-coated steel fibres, superplasticizer on polycarboxylate ether basis and batch water. For the studied material, properties after 2 hours thermal treatment at the temperatures of 105 °C, 200 °C, 400 °C, 600 °C, 800 °C, and 1000 °C respectively were tested. Among them, bulk density, matrix density, total open porosity and thermal parameters as thermal conductivity, thermal diffusivity and specific heat capacity were measured. The measured specific heat capacity exhibited high dependence on temperature and pointed to the structural changes that studied material underwent at high temperatures. Accordingly, the obtained residual parameters revealed the thermally induced damage of SFR-HPC and critical temperatures for its functionality.

  15. Advanced Thermal Storage System with Novel Molten Salt: December 8, 2011 - April 30, 2013

    Energy Technology Data Exchange (ETDEWEB)

    Jonemann, M.

    2013-05-01

    Final technical progress report of Halotechnics Subcontract No. NEU-2-11979-01. Halotechnics has demonstrated an advanced thermal energy storage system with a novel molten salt operating at 700 degrees C. The molten salt and storage system will enable the use of advanced power cycles such as supercritical steam and supercritical carbon dioxide in next generation CSP plants. The salt consists of low cost, earth abundant materials.

  16. Adsorption properties of porous materials for solar thermal energy storage and heat pump applications

    OpenAIRE

    Jänchen, Jochen; Stach, Helmut

    2012-01-01

    The water adsorption properties of modified porous sorbents for solar thermal energy storage and heat transformation have been investigated by thermogravimetry (TG) differential thermogravimetry (DTG), microcalorimetry, measurements of water adsorption isotherms, and storage tests. A chabazite type SAPO, a dealuminated faujasite type zeolite, and a mesostructured aluminosilicate, have been synthesized and compared with common zeolites X, Y and silica gel. It has been found that optimized latt...

  17. Experimental characterization of a solar cooker with thermal energy storage based on solar salt

    Science.gov (United States)

    Coccia, G.; Di Nicola, G.; Tomassetti, S.; Gabrielli, G.; Chieruzzi, M.; Pierantozzi, M.

    2017-11-01

    High temperature solar cooking allows to cook food fast and with good efficiency. An unavoidable drawback of this technology is that it requires nearly clear-sky conditions. In addition, evening cooking is difficult to be accomplished, particularly on the winter season during which solar radiation availability is limited to a few hours in the afternoon in most of countries. These restrictions could be overcome using a cooker thermal storage unit (TSU). In this work, a TSU based on solar salt was studied. The unit consists of two metal concentric cylindrical vessels, connected together to form a double-walled vessel. The volume between walls was filled with a certain amount of nitrate based phase change material (solar salt). In order to characterize the TSU, a test bench used to assess solar cooker performance was adopted. Experimental load tests with the TSU were carried out to evaluate the cooker performance. The obtained preliminary results show that the adoption of the solar salt TSU seems to allow both the opportunity of evening cooking and the possibility to better stabilize the cooker temperature when sky conditions are variable.

  18. Analysis of a Concentrated Solar Thermophotovoltaic System with Thermal Energy Storage

    Science.gov (United States)

    Seyf, Hamid Reza; Henry, Asegun

    2017-01-01

    We analyzed a high temperature concentrated solar thermophotovoltaic (TPV) system with thermal energy storage (TES), which is enabled by the potential usage of liquid metal as a high temperature heat transfer fluid. The system concept combines the great advantages of TES with the potential for low cost and high performance derived from photovoltaic cells fabricated on reusable substrates, with a high reflectivity back reflector for photon recycling. The TES makes the electricity produced dispatchable, and thus the system studied should be compared to technologies such as concentrated solar power (CSP) with TES (e.g., using a turbine) or PV with electrochemical batteries, instead of direct and intermittent electricity generation from flat plate PV alone. Thus, the addition of TES places the system in a different class than has previously been considered and based on the model results, appears worthy of increased attention. The system level analysis presented identifies important cell level parameters that have the greatest impact on the overall system performance, and as a result can help to set the priorities for future TPV cell development.

  19. Charge and Discharge Analyses of a PCM Storage System Integrated in a High-Temperature Solar Receiver

    Directory of Open Access Journals (Sweden)

    Ambra Giovannelli

    2017-11-01

    Full Text Available Solar Dish Micro Gas Turbine (MGT systems have the potential to become interesting small-scale power plants in off-grid or mini-grid contexts for electricity or poly-generation production. The main challenging component of such systems is the solar receiver which should operate at high temperatures with concentrated solar radiations, which strongly vary with time. This paper deals with the design and the analysis of a novel solar receiver integrated with a short-term storage system based on Phase Change Materials to prevent sudden variations in the maximum temperature of the MGT working fluid. Particularly, the charge and discharge behavior of the storage system was analyzed by means of Computational Fluid Dynamic methods to evaluate the potentiality of the concept and the component capabilities. Achieved results were highly satisfactory: the novel solar receiver has a good thermal inertia and can prevent relevant fluctuations in the working fluid temperature for 20–30 min.

  20. Enhanced mechanical, thermal, and electric properties of graphene aerogels via supercritical ethanol drying and high-temperature thermal reduction

    OpenAIRE

    Yehong Cheng; Shanbao Zhou; Ping Hu; Guangdong Zhao; Yongxia Li; Xinghong Zhang; Wenbo Han

    2017-01-01

    Graphene aerogels with high surface areas, ultra-low densities and thermal conductivities have been prepared to exploit their wide applications from pollution adsorption to energy storage, supercapacitor, and thermal insulation. However, the low mechanical properties, poor thermal stability and electric conductivity restrict these aerogels? applications. In this paper, we prepared mechanically strong graphene aerogels with large BET surface areas, low thermal conductivities, high thermal stab...

  1. Development of a low temperature phase change material package. [for spacecraft thermal control

    Science.gov (United States)

    Brennan, P. J.; Suelau, H. J.; Mcintosh, R.

    1977-01-01

    Test data obtained for a low temperature phase change material (PCM) canisters are presented. The canister was designed to provide up to 30 w-hrs of storage capacity at approximately -90 C with an overall thermal conductance which is greater than 8 w/deg C. N-heptane which is an n-paraffin and has a -90.6 C freezing point was used as the working fluid. The canister was fabricated from aluminum and has an aluminum honeycomb core. Its void volume permits service temperatures up to 70 C. Results obtained from component and system's tests indicate well defined melting and freezing points which are repeatable and within 1 C of each other. Subcooling effects are less than 0.5 C and are essentially negligible. Measured storage capacities are within 94 to 88% the theoretical.

  2. The Heat Transfer of Microencapsulated Phase Change Material Slurry and Its Thermal Energy Storage Performance of Combined Heat and Power Generating Units

    Directory of Open Access Journals (Sweden)

    Yonghong Guo

    2017-10-01

    Full Text Available The application of thermal energy storage (TES is an effective way of improving the power load regulation capability of combined heat and power (CHP generating units. In this paper, a theoretical investigation on the thermal energy storage system of a CHP unit that employs the microencapsulated phase change material slurry (MPCMS as the working fluid is carried out. The results indicate that the microcapsule particle internal melting rate is progressively small; 90% latent heat can be absorbed in 63% total melting time. The melting time of particles in micron is very short, and the diameter is an important factor for microcapsule melting. For the MPCMS flow in a circular tube, the temperature distribution between laminar flows and turbulent flows is different. In a turbulent flow, there is an approximate isothermal section along the tube, which cannot be found in a laminar flow. Additionally, a thermal storage system with MPCMS as heat transfer fluid for a CHP unit is proposed. A case study for a 300 MW CHP unit found that the use of an MPSMS thermal energy storage system increases the power peak shaving capacity by 81.4%. This indicates that the thermal storage system increases the peak shaving capacity of cogeneration units.

  3. Changes in guava (Psidium guajava L. var. Paluma nectar volatile compounds concentration due to thermal processing and storage

    Directory of Open Access Journals (Sweden)

    Maria Ivaneide Coutinho Correa

    2010-12-01

    Full Text Available Guava nectars were formulated for approximately 10, 12, or 14 ºBrix, with 40% guava pulp. Sodium benzoate, 500 mg.kg-1 was used as preservative. The Brix value was adjusted with saturated sucrose syrup. The guava nectar was pasteurized (85 ºC/42 seconds in tubular heat exchanger and then hot filled in 500 mL white glass bottles. The products were stored either at room temperature (25 ± 5 ºC or refrigerated (5 ± 2 ºC under fluorescent light exposure and analyzed on the day after processing (time zero and also 40, 80, and 120 days of storage. Eight compounds were identified and quantified by Gas Chromatography (GC -Mass Spectrometry (MS: hexanal, (E-hex-2-enal, 1-hexenol, (Z-hex-3-enol, (Z-hex-3-enyl acetate, phenyl-3-propyl acetate, cinnamyl acetate, and acetic acid. There was no significant effect of thermal treatment on the volatile compound concentrations, except for a significant decrease (p = 0.0001 in hexanal and (Z-hex-3-enyl acetate (p = 0.0029. As for the storage time, there was a much greater decrease in the esters contents, such as (Z-hex-3-enyl and phenyl-3-propyl acetates. Cinnamyl acetate had the greatest decrease over storage time. Refrigeration was better than room temperature for guava nectar volatile compounds stability over storage time, mainly for esters compounds, which are important for the product aroma and flavor

  4. Comparison of domestic olivine and European magnesite for electrically charged thermal energy storage

    Energy Technology Data Exchange (ETDEWEB)

    Laster, W.R.; Gay, B.M.; Palmour, H.; Schoenhals, R.J.

    1982-01-01

    Electrically charged thermal energy storage (TES) heaters employing high heat capacity ceramic refractories for sensible heat storage have been in use in Europe for several years. With these devices, low cost off-peak electrical energy is stored by heating a storage core composed of ceramic material to approximately 800/sup 0/C. During the peak period, no electrical energy is used as the building heating needs are supplied by extracting the stored energy from the core by forced air circulation. The recent increase in use of off-peak TES units in the U.S. has led to the search for a domestic supply of high heat capacity ceramic refractory material. North Carolina's extensive but underutilized supply of refractory grade olivine has been proposed as a source of storage material for these units. In this paper the suitability of North Carolina olivine for heat storage applications is assessed by comparing its thermal performance with that of European materials. Using the method of ASHRAE Standard 94.2, the thermal performance of two commercially available room-size TES units was determined experimentally with two different storage materials, North Carolina olivine and German magnesite. Comparisons are made and conclusions are drawn.

  5. Boiling/evaporative heat transfer from spheres in packed-bed thermal energy storage units

    Science.gov (United States)

    Arimilli, R. V.; Moy, C. A.

    1990-05-01

    An experimental study was conducted to study boiling/evaporative heat transfer from heated spheres in vertical packed beds with downward liquid vapor flow of Refrigerant-113. Surface superheats of 1 to 50 C; mass flow rates of 1.7, 2.7, and 5.6 kg/min; sphere diameters of 1.59 and 2.54 cm; quality (i.e., mass fraction of vapor) of the inlet flow of 2 to 100 percent; and two surface roughness conditions were considered. To determine heat transfer coefficients, smooth and roughened aluminum spheres of the same diameter as the other spheres in the bed were instrumented with two thermocouples each for measuring the surface temperatures and a tiny electrical resistance heater for input power. The heat transfer measurements were made under steady-state conditions. Heat transfer coefficients were independently determined for each sphere at three values of surface superheat. The quantitative results are represented as a correlation for the boiling heat transfer coefficients in terms of a homogeneous model. The equation correlates very effectively with the dimensionless temperature difference. The correlation may be used in the development of numerical models to simulate the transient thermal performance of a packed-bed thermal energy storage unit while operating as an evaporator. The boiling of the liquid vapor flow around the spheres in the packed bed was visually observed with a fiber optic boroscope and recorded on a video tape. The visualization results showed qualitatively the presence of our four distinct flow regimes. One of these occurs under subcooled regime. The other three occur under saturated inlet conditions and are referred to as the low-quality, medium-quality, and high-quality regimes. The regimes are discussed in detail.

  6. Thermal energy storage technologies for sustainability systems design, assessment and applications

    CERN Document Server

    Kalaiselvam, S

    2014-01-01

    Thermal Energy Storage Technologies for Sustainability is a broad-based overview describing the state-of-the-art in latent, sensible, and thermo-chemical energy storage systems and their applications across industries. Beginning with a discussion of the efficiency and conservation advantages of balancing energy demand with production, the book goes on to describe current state-of-the art technologies. Not stopping with description, the authors also discuss design, modeling, and simulation of representative systems, and end with several case studies of systems in use.Describes how thermal energ

  7. The effects of temperature on the crystalline properties and resistant starch during storage of white bread.

    Science.gov (United States)

    Sullivan, William R; Hughes, Jeff G; Cockman, Russell W; Small, Darryl M

    2017-08-01

    Resistant starch (RS) can form during storage of foods, thereby bestowing a variety of potential health benefits. The purpose of the current study has been to determine the influence of storage temperature and time on the crystallinity and RS content of bread. Loaves of white bread were baked and stored at refrigeration, frozen and room temperatures with analysis over a period of zero to seven days. RS determination and X-ray diffraction (XRD) were used to evaluate the influence of storage temperature and time on total crystallinity and RS content. The rate of starch recrystallisation was affected by storage temperature and time, where refrigeration temperatures accelerated RS formation and total crystallinity more than storage time at both frozen and room temperature. A strong statistical model has been established between RS formation in bread and XRD patterns, having a 96.7% fit indicating the potential of XRD to measure RS concentrations. Copyright © 2017 Elsevier Ltd. All rights reserved.

  8. Experimental investigation on the characteristics of polyethylene glycol/cement composites as thermal energy storage materials

    Energy Technology Data Exchange (ETDEWEB)

    Li, H. [Department of Material Science and Engineering, Nanjing University, Nanjing (China); Fang, G.Y. [School of Physics, Nanjing University, Nanjing (China)

    2010-10-15

    The polyethylene glycol/cement composites as thermal energy storage materials were prepared by blending polyethylene glycol and cement. In composite materials, polyethylene glycol (PEG) is used as the phase change material for thermal energy storage and cement acts as the supporting material. A Fourier transformation infrared spectroscope (FT-IR), X-ray diffractometer (XRD), and scanning electronic microscope (SEM) were used to determine the chemical structure, the crystalloid phase, and microstructure of the polyethylene glycol/cement composites, respectively. The thermal properties and thermal stability were investigated by a differential scanning calorimeter (DSC) and a thermogravimetry analyzer (TGA). The SEM results showed that the polyethylene glycol was well dispersed in the porous network of the cement. (Abstract Copyright [2010], Wiley Periodicals, Inc.)

  9. Advanced storage concepts for solar thermal systems in low energy buildings. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Furbo, S.; Andersen, Elsa; Schultz, Joergen M.

    2006-04-07

    The aim of Task 32 is to develop new and advanced heat storage systems which are economic and technical suitable as long-term heat storage systems for solar heating plants with a high degree of coverage. The project is international and Denmark's participation has focused on Subtask A, C, and D. In Subtask A Denmark has contributed to a status report about heat storage systems. In Subtask C Denmark has focused on liquid thermal storage tanks based on NaCH{sub 3}COO?3H{sub 2}O with a melting point of 58 deg. C. Theoretical and experimental tests have been conducted in order to establish optimum conditions for storage design. In Subtask D theoretical and experimental tests of optimum designs for advanced water tanks for solar heating plants for combined space heating and domestic hot water have been conducted. (BA)

  10. Damage Assessment of Stress-Thermal Cycled high temperature

    Science.gov (United States)

    Ju, Jae-Hyung; Prochazka, Michael; Ronke, Ben; Morgan, Roger; Shin, Eugence

    2004-01-01

    We report on the characterization of bismaleimide and polyimide carbon fiber composite, microcrack development under stress thermal cycling loading. Such cycles range from cryogenic temperatures associated with cryogenic fuel (LN, LOX) containment to high temperatures of 300 degrees Celsius associated with future hypervelocity aeropropulsion systems. Microcrack development thresholds as a function of temperature range of the thermal cycle; the number of cycles; the applied stress level imposed on the composite are reported. We have conducted stress-thermal cycles on thin bismaleimide-woven carbon fiber foils for three temperature range cycles: 1. Ambient temperature - -196 degrees celsius. 2. Ambient temperature - 150 degrees Celsius; 200 degrees Celsius; 250 degrees Celsius. 3. -196 degrees Celsius - 250 degrees Celsius. The Principle findings are that the full cycles from -196 degrees Celsius to to 250 degrees Celsius cause the most significant microcrack of development. These observations indicate that the high temperature portion of the cycle under load causes fiber-matrix interface failure and subsequent exposure to higher stresses at the cryogenic, low temperature region results in composite matrix microcracking as a result of the additional stresses associate with the fiber-matrix thermal expansion mismatch. Our initial studies for 12 ply PMR-II-50 polyimide/M60JB carbon fabric [0f,90f,90f,0f,0f,90f]ls composites will be presented. The stress-thermal cycle test procedure for these will be described. Moisture absorption characteristics between cycles will be used to monitor interconnected microcrack development. The applied stress level will be 75% of the composite cryogenic (-196 degrees Celsius) ultimate strength.

  11. Thermal properties of solids at room and cryogenic temperatures

    CERN Document Server

    Ventura, Guglielmo

    2014-01-01

    This book is a guide for materials scientists, physicists, chemists and engineers who wish to explore the field of low-temperature material properties. The focus is on heat capacity, thermal expansion and electrical and thermal conductivity. The authors report a wide range of experimental details and data, and have compiled useful tables of low-temperature data. Each chapter of the book starts by addressing the theoretical basis of the phenomena. This is a concise presentation, but it helps the reader to develop a deeper understanding of the experiments. The second part of the chapters is dedicated to describing the main experimental techniques to measure thermal properties at low and very low temperature ranges. The final part of each chapter provides a wealth of relevant experimental data in the form of tables and graphs.

  12. Thin Thermal-Insulation Blankets for Very High Temperatures

    Science.gov (United States)

    Choi, Michael K.

    2003-01-01

    Thermal-insulation blankets of a proposed type would be exceptionally thin and would endure temperatures up to 2,100 C. These blankets were originally intended to protect components of the NASA Solar Probe spacecraft against radiant heating at its planned closest approach to the Sun (a distance of 4 solar radii). These blankets could also be used on Earth to provide thermal protection in special applications (especially in vacuum chambers) for which conventional thermal-insulation blankets would be too thick or would not perform adequately.

  13. Imaging structural transitions in organometallic molecules on Ag(100) for solar thermal energy storage

    OpenAIRE

    Cho, Jongweon; Pechenezhskiy, Ivan V.; Berbil-Bautista, Luis; Meier, Steven K.; Vollhardt, K. Peter C.; Crommie, Michael F.

    2017-01-01

    The use of opto-thermal molecular energy storage at the nanoscale creates new opportunities for powering future microdevices with flexible synthetic tailorability. Practical application of these molecular materials, however, requires a deeper microscopic understanding of how their behavior is altered by the presence of different types of substrates. Here we present single-molecule resolved scanning tunneling microscopy imaging of thermally- and optically-induced structural transitions in (ful...

  14. Low Molecular Weight Norbornadiene Derivatives for Molecular Solar?Thermal Energy Storage

    OpenAIRE

    Quant, Maria; Lennartson, Anders; Dreos, Ambra; Kuisma, Mikael; Erhart, Paul; B?rjesson, Karl; Moth?Poulsen, Kasper

    2016-01-01

    Abstract Molecular solar?thermal energy storage systems are based on molecular switches that reversibly convert solar energy into chemical energy. Herein, we report the synthesis, characterization, and computational evaluation of a series of low molecular weight (193?260?g?mol?1) norbornadiene?quadricyclane systems. The molecules feature cyano acceptor and ethynyl?substituted aromatic donor groups, leading to a good match with solar irradiation, quantitative photo?thermal conversion between t...

  15. Room temperature screening of thermal conductivity by means of thermal transient measurements

    Science.gov (United States)

    García-Cañadas, Jorge; Cheng, Shudan; Márquez-García, Lourdes; Prest, Martin J.; Akbari-Rahimabadi, Ahmad; Min, Gao

    2016-10-01

    A proof of concept of the possibility to estimate thermal conductivity of bulk disc samples at room temperature by means of thermal decays is demonstrated. An experimental set-up was designed and fabricated, which is able to perform thermal transient measurements by using a specially designed multifunctional probe that has the ability to measure temperature at its tip. Initially, the probe is heated by a heater coil located in its interior until the tip temperature reaches a steady state. Then, the probe is contacted with a disc sample which produces a temperature decay until a new state is reached. The difference between the initial and final states temperatures shows a correlation with the thermal conductivity of the sample. Employing a calibration equation, obtained using reference materials, the thermal conductivity can be calculated. Reasonably good random and systematic errors (<13% and ~9% respectively) are obtained. Theoretical simulations performed using COMSOL show a good qualitative agreement with experimental results. This new method involves an inexpensive and simple set-up which can be especially useful for thermal conductivity screening and high-throughput measurements.

  16. Instrument for Measuring Thermal Conductivity of Materials at Low Temperatures

    Science.gov (United States)

    Fesmire, James; Sass, Jared; Johnson, Wesley

    2010-01-01

    With the advance of polymer and other non-metallic material sciences, whole new series of polymeric materials and composites are being created. These materials are being optimized for many different applications including cryogenic and low-temperature industrial processes. Engineers need these data to perform detailed system designs and enable new design possibilities for improved control, reliability, and efficiency in specific applications. One main area of interest is cryogenic structural elements and fluid handling components and other parts, films, and coatings for low-temperature application. An important thermal property of these new materials is the apparent thermal conductivity (k-value).

  17. High-temperature plasmonic thermal emitter for thermophotovotaics

    DEFF Research Database (Denmark)

    Liu, Jingjing; Guler, Urcan; Li, Wei

    2014-01-01

    We use titanium nitride (TiN) to demonstrate an ultra-thin plasmonic thermal emitter operating at high temperatures (830 K). The spectrally selective emitter exhibits a large emittance at around 2.5 μm and below, and suppresses emission at longer wavelengths.......We use titanium nitride (TiN) to demonstrate an ultra-thin plasmonic thermal emitter operating at high temperatures (830 K). The spectrally selective emitter exhibits a large emittance at around 2.5 μm and below, and suppresses emission at longer wavelengths....

  18. Effects of storage temperature and humidity on shelf life and quality ...

    African Journals Online (AJOL)

    Effects of storage temperature and humidity on shelf life and quality of African pear (Dacryodes edulis) fruits. ... Nigerian Food Journal ... However, the quality losses as well as microbiological growths were drastically reduced when the fruits were stored at the lowest storage temperature (50C) and under three relative ...

  19. Numerical analysis of accidental hydrogen releases from high pressure storage at low temperatures

    DEFF Research Database (Denmark)

    Markert, Frank; Melideo, Daniele; Baraldi, Daniele

    2014-01-01

    ) and temperatures (down to 20 K), e.g. cryogenic compressed gas storage covers pressures up to 35 MPa and temperatures between 33 K and 338 K. Accurate calculations of high pressure releases require real gas EOS. This paper compares a number of EOS to predict hydrogen properties typical in different storage types...

  20. Modeling of District Heating Networks for the Purpose of Operational Optimization with Thermal Energy Storage

    Directory of Open Access Journals (Sweden)

    Leśko Michał

    2017-12-01

    Full Text Available The aim of this document is to present the topic of modeling district heating systems in order to enable optimization of their operation, with special focus on thermal energy storage in the pipelines. Two mathematical models for simulation of transient behavior of district heating networks have been described, and their results have been compared in a case study. The operational optimization in a DH system, especially if this system is supplied from a combined heat and power plant, is a difficult and complicated task. Finding a global financial optimum requires considering long periods of time and including thermal energy storage possibilities into consideration. One of the most interesting options for thermal energy storage is utilization of thermal inertia of the network itself. This approach requires no additional investment, while providing significant possibilities for heat load shifting. It is not feasible to use full topological models of the networks, comprising thousands of substations and network sections, for the purpose of operational optimization with thermal energy storage, because such models require long calculation times. In order to optimize planned thermal energy storage actions, it is necessary to model the transient behavior of the network in a very simple way - allowing for fast and reliable calculations. Two approaches to building such models have been presented. Both have been tested by comparing the results of simulation of the behavior of the same network. The characteristic features, advantages and disadvantages of both kinds of models have been identified. The results can prove useful for district heating system operators in the near future.

  1. Modeling of District Heating Networks for the Purpose of Operational Optimization with Thermal Energy Storage

    Science.gov (United States)

    Leśko, Michał; Bujalski, Wojciech

    2017-12-01

    The aim of this document is to present the topic of modeling district heating systems in order to enable optimization of their operation, with special focus on thermal energy storage in the pipelines. Two mathematical models for simulation of transient behavior of district heating networks have been described, and their results have been compared in a case study. The operational optimization in a DH system, especially if this system is supplied from a combined heat and power plant, is a difficult and complicated task. Finding a global financial optimum requires considering long periods of time and including thermal energy storage possibilities into consideration. One of the most interesting options for thermal energy storage is utilization of thermal inertia of the network itself. This approach requires no additional investment, while providing significant possibilities for heat load shifting. It is not feasible to use full topological models of the networks, comprising thousands of substations and network sections, for the purpose of operational optimization with thermal energy storage, because such models require long calculation times. In order to optimize planned thermal energy storage actions, it is necessary to model the transient behavior of the network in a very simple way - allowing for fast and reliable calculations. Two approaches to building such models have been presented. Both have been tested by comparing the results of simulation of the behavior of the same network. The characteristic features, advantages and disadvantages of both kinds of models have been identified. The results can prove useful for district heating system operators in the near future.

  2. Using Encapsulated Phase Change Material in Thermal Energy Storage for Baseload Concentrating Solar Power (EPCM-TES)

    Energy Technology Data Exchange (ETDEWEB)

    Mathur, Anoop [Terrafore Technologies LLC, Minneapolis, MN (United States)

    2013-12-15

    Terrafore successfully demonstrated and optimized the manufacturing of capsules containing phase-changing inorganic salts. The phase change was used to store thermal energy collected from a concentrating solar-power plant as latent heat. This latent heat, in addition to sensible heat increased the energy density (energy stored per unit weight of salt) by over 50%, thus requiring 40% less salt and over 60% less capsule container. Therefore, the cost to store high-temperature thermal energy collected in a concentrating solar power plant will be reduced by almost 40% or more, as compared to conventional two-tank, sensible-only storage systems. The cost for thermal energy storage (TES) system is expected to achieve the Sun Shot goal of $15 per kWh(t). Costs associated with poor heat-transfer in phase change materials (PCM) were also eliminated. Although thermal energy storage that relies on the latent heat of fusion of PCM improves energy density by as much as 50%, upon energy discharge the salt freezes and builds on the heat transfer surfaces. Since these salts have low thermal conductivity, large heat-transfer areas, or larger conventional heat-exchangers are needed, which increases costs. By encapsulating PCM in small capsules we have increased the heat transfer area per unit volume of salt and brought the heat transfer fluid in direct contact with the capsules. These two improvements have increased the heat transfer coefficient and boosted heat transfer. The program was successful in overcoming the phenomenon of melt expansion in the capsules, which requires the creation of open volume in the capsules or shell to allow for expansion of the molten salt on melting and is heated above its melting point to 550°C. Under contract with the Department of Energy, Terrafore Inc. and Southwest Research Institute, developed innovative method(s) to economically create the open volume or void in the capsule. One method consists of using a sacrificial polymer coating as the

  3. A method for accurate temperature measurement using infrared thermal camera.

    Science.gov (United States)

    Tokunaga, Tomoharu; Narushima, Takashi; Yonezawa, Tetsu; Sudo, Takayuki; Okubo, Shuichi; Komatsubara, Shigeyuki; Sasaki, Katsuhiro; Yamamoto, Takahisa

    2012-08-01

    The temperature distribution on a centre-holed thin foil of molybdenum, used as a sample and heated using a sample-heating holder for electron microscopy, was measured using an infrared thermal camera. The temperature on the heated foil area located near the heating stage of the heating holder is almost equal to the temperature on the heating stage. However, during the measurement of the temperature at the edge of the hole of the foil located farthest from the heating stage, a drop in temperature should be taken into consideration; however, so far, no method has been developed to locally measure the temperature distribution on the heated sample. In this study, a method for the accurate measurement of temperature distribution on heated samples for electron microscopy is discussed.

  4. Analysis of Thermal Radiation Effects on Temperatures in Turbine Engine Thermal Barrier Coatings

    Science.gov (United States)

    Siegel, Robert; Spuckler, Charles M.

    1998-01-01

    Thermal barrier coatings are important, and in some instances a necessity, for high temperature applications such as combustor liners, and turbine vanes and rotating blades for current and advanced turbine engines. Some of the insulating materials used for coatings, such as zirconia that currently has widespread use, are partially transparent to thermal radiation. A translucent coating permits energy to be transported internally by radiation, thereby increasing the total energy transfer and acting like an increase in thermal conductivity. This degrades the insulating ability of the coating. Because of the strong dependence of radiant emission on temperature, internal radiative transfer effects are increased as temperatures are raised. Hence evaluating the significance of internal radiation is of importance as temperatures are increased to obtain higher efficiencies in advanced engines.

  5. Effect of Frozen Storage Temperature on the Quality of Premium Ice Cream.

    Science.gov (United States)

    Park, Sung Hee; Jo, Yeon-Ji; Chun, Ji-Yeon; Hong, Geun-Pyo; Davaatseren, Munkhtugs; Choi, Mi-Jung

    2015-01-01

    The market sales of premium ice cream have paralleled the growth in consumer desire for rich flavor and taste. Storage temperature is a major consideration in preserving the quality attributes of premium ice cream products for both the manufacturer and retailers during prolonged storage. We investigated the effect of storage temperature (-18℃, -30℃, -50℃, and -70℃) and storage times, up to 52 wk, on the quality attributes of premium ice cream. Quality attributes tested included ice crystal size, air cell size, melting resistance, and color. Ice crystal size increased from 40.3 μm to 100.1 μm after 52 wk of storage at -18℃. When ice cream samples were stored at -50℃ or -70℃, ice crystal size slightly increased from 40.3 μm to 57-58 μm. Initial air cell size increased from 37.1 μm to 87.7 μm after storage at -18℃ for 52 wk. However, for storage temperatures of -50℃ and -70℃, air cell size increased only slightly from 37.1 μm to 46-47 μm. Low storage temperature (-50℃ and -70℃) resulted in better melt resistance and minimized color changes in comparison to high temperature storage (-18℃ and -30℃). In our study, quality changes in premium ice cream were gradually minimized according to decrease in storage temperature up to-50℃. No significant beneficial effect of -70℃ storage was found in quality attributes. In the scope of our experiment, we recommend a storage temperature of -50℃ to preserve the quality attributes of premium ice cream.

  6. Analyzing Control Challenges for Thermal Energy Storage in Foodstuffs

    DEFF Research Database (Denmark)

    Hovgaard, Tobias Gybel; Larsen, Lars F. S.; Skovrup, Morten Juel

    2012-01-01

    of refrigerated goods in a supermarket to shift the load of the system in time without deteriorating the quality of the foodstuffs. The analyses in this paper go before closing any control loops. In the first part, we introduce and validate a new model with which we can estimate the actual temperatures...... foodstuffs make them behave differently when exposed to changes in air temperature. We present a novel analysis based on Biot and Fourier numbers for the different foodstuffs. This provides a valuable tool for determining how different items can be utilized in load-shifting schemes on different timescales...

  7. Cryogenic thermal storage system for discontinuous industrial vacuum processes

    Science.gov (United States)

    Bruzzi, M.; Chesi, A.; Baldi, A.; Tarani, F.; Mori, R.; Scaringella, M.; Carnevale, E.

    2012-10-01

    Phase Change Materials are proposed for refrigerating systems in discontinuous industrial vacuum processes where temperatures as low as -140 ÷ -100°C are necessary within time-frames representing 10÷20% of total operating time. An application is proposed for cooling systems used in a Physical Vapour Deposition (PVD) apparatus. A prototype has been manufactured which couples a cryopump with a reservoir filled with MethylCycloPentane (MCP-C6H12) and a distribution line where nitrogen in the gaseous state is flowing. Preliminary tests show that temperatures of about -120°C are actually achieved within time windows compatible with PVD applications.

  8. The impact of aquifer heterogeneity on the performance of aquifer thermal energy storage

    NARCIS (Netherlands)

    Sommer, W.T.; Valstar, J.R.; Gaans, van P.; Grotenhuis, J.T.C.; Rijnaarts, H.

    2013-01-01

    Heterogeneity in hydraulic properties of the subsurface is not accounted for in current design calculations of aquifer thermal energy storage (ATES). However, the subsurface is heterogeneous and thus affects the heat distribution around ATES wells. In this paper, the influence of heterogeneity on

  9. Regional assessment of aquifers for thermal-energy storage. Volume 2. Regions 7 through 12

    Energy Technology Data Exchange (ETDEWEB)

    1981-06-01

    This volume contains information on the geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the following regions of the US: Unglaciated Central Region; Glaciated Appalachians, Unglaciated Appalachians; Coastal Plain; Hawaii; and Alaska. (LCL)

  10. A control-oriented model for combined building climate comfort and aquifer thermal energy storage system

    NARCIS (Netherlands)

    Rostampour Samarin, V.; Bloemendal, J.M.; Jaxa-Rozen, M.; Keviczky, T.

    2016-01-01

    This paper presents a control-oriented model for combined building climate comfort and aquifer thermal energy storage (ATES) system. In particular, we first provide a description of building operational systems together with control framework variables. We then focus on the derivation of an

  11. Development of Proposed Standards for Testing Solar Collectors and Thermal Storage Devices. NBS Technical Note 899.

    Science.gov (United States)

    Hill, James E.; And Others

    A study has been made at the National Bureau of Standards of the different techniques that are or could be used for testing solar collectors and thermal storage devices that are used in solar heating and cooling systems. This report reviews the various testing methods and outlines a recommended test procedure, including apparatus and…

  12. Regional assessment of aquifers for thermal energy storage. Volume 1. Regions 1 through 6

    Energy Technology Data Exchange (ETDEWEB)

    1981-06-01

    This volume contains information on the geologic and hydrologic framework, major aquifers, aquifers which are suitable and unsuitable for annual thermal energy storage (ATES) and the ATES potential of the following regions of the US: the Western Mountains; Alluvial Basins; Columbia LAVA Plateau; Colorado Plateau; High Plains; and Glaciated Central Region. (LCL)

  13. Improved thermal stability of gas-phase Mg nanoparticles for hydrogen storage

    NARCIS (Netherlands)

    Krishnan, Gopi; Palasantzas, G.; Kooi, B. J.

    2010-01-01

    This work focuses on improving the thermal stability of Mg nanoparticles (NPs) for use in hydrogen storage. Three ways are investigated that can achieve this goal. (i) Addition of Cu prevents void formation during NP production and reduces the fast evaporation/voiding of Mg during annealing. (ii)

  14. Wind Energy to Thermal and Cold Storage – A Systems Approach

    DEFF Research Database (Denmark)

    Xydis, George

    2013-01-01

    In this paper wind energy to thermal and cold storage scenarios were examined to enable high wind integration through converting renewable electricity excess into thermal or cooling energy, saving part of the energy used in an area and eliminating the need to possibly build a new coal fired plant....... Case studies in Crete Island (not interconnected to the power grid of Greek mainland) with onshore wind power installed were investigated. The aim of this work was to review the options for greater integration of renewables into the grid and the main idea was to analyze the wind to thermal and to cold...

  15. Improving Geothermal Heat Pump Air Conditioning Efficiency with Wintertime Cooling using Seasonal Thermal Energy Storage (STES). Application Manual

    Science.gov (United States)

    2016-11-01

    APPLICATION MANUAL Improving Geothermal Heat Pump Air Conditioning Efficiency with Wintertime Cooling using Seasonal Thermal Energy Storage...application projects to increase energy efficiency and occupant comfort. Seasonal Thermal Energy Storage (STES) technology, energy efficiency, geothermal heat...electrical energy use (kW-hr) for the geothermal heat pump system with and without a dry fluid cooler

  16. Low Molecular Weight Norbornadiene Derivatives for Molecular Solar-Thermal Energy Storage.

    Science.gov (United States)

    Quant, Maria; Lennartson, Anders; Dreos, Ambra; Kuisma, Mikael; Erhart, Paul; Börjesson, Karl; Moth-Poulsen, Kasper

    2016-09-05

    Molecular solar-thermal energy storage systems are based on molecular switches that reversibly convert solar energy into chemical energy. Herein, we report the synthesis, characterization, and computational evaluation of a series of low molecular weight (193-260 g mol(-1) ) norbornadiene-quadricyclane systems. The molecules feature cyano acceptor and ethynyl-substituted aromatic donor groups, leading to a good match with solar irradiation, quantitative photo-thermal conversion between the norbornadiene and quadricyclane, as well as high energy storage densities (396-629 kJ kg(-1) ). The spectroscopic properties and energy storage capability have been further evaluated through density functional theory calculations, which indicate that the ethynyl moiety plays a critical role in obtaining the high oscillator strengths seen for these molecules. © 2016 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.

  17. Low Molecular Weight Norbornadiene Derivatives for Molecular Solar‐Thermal Energy Storage

    Science.gov (United States)

    Quant, Maria; Lennartson, Anders; Dreos, Ambra; Kuisma, Mikael; Erhart, Paul; Börjesson, Karl

    2016-01-01

    Abstract Molecular solar‐thermal energy storage systems are based on molecular switches that reversibly convert solar energy into chemical energy. Herein, we report the synthesis, characterization, and computational evaluation of a series of low molecular weight (193–260 g mol−1) norbornadiene–quadricyclane systems. The molecules feature cyano acceptor and ethynyl‐substituted aromatic donor groups, leading to a good match with solar irradiation, quantitative photo‐thermal conversion between the norbornadiene and quadricyclane, as well as high energy storage densities (396–629 kJ kg−1). The spectroscopic properties and energy storage capability have been further evaluated through density functional theory calculations, which indicate that the ethynyl moiety plays a critical role in obtaining the high oscillator strengths seen for these molecules. PMID:27492997

  18. Toward Molecular Solar-Thermal Energy Storage: Systematic Search for New Molecular Systems

    Science.gov (United States)

    Durgun, Engin; Srinivasan, Varadharajan; Kanai, Yosuke; Wintrop, Gordon; Grossman, Jeffrey C.

    2010-03-01

    In the currently intensifying quest to harness solar energy for the powering of our planet, many efforts are centered around photo-induced generic charge separation, such as in photovoltaics, water splitting, and biologically inspired photosynthetic systems. An attractive alternative strategy would be to trap solar energy in the form of chemical bonds, ideally through the photo-conversion of a suitable molecule to a higher energy isomer, which, in turn, releases the stored energy by thermal reversal. Inspired by the discovery and investigations of fulvane-diruthenium, we explore strategies to discover new organometallic complexes that possess superior properties than organic molecules. We systematically search for complexes which are robust to storage cycles, easy to synthesize, tunable and which have high storage capacity and low UV excitation energies. Our analysis reveals that good organometallic candidates for solar-thermal energy storage systems can be identified and their performance can be improved through chemical substitution.

  19. Passive thermal energy storage, part 1: Design concepts and metrics

    DEFF Research Database (Denmark)

    Bastien, Diane; Athienitis, Andreas

    2017-01-01

    used to characterize the performance of TES systems. Different design objectives/parameters are discussed, such as: 1) optimal time lag; 2) optimal decrement factor and transfer admittance; 3) reduction of space heating and cooling energy consumption; 4) minimizing indoor temperature swings; 5...

  20. Active Wireless Temperature Sensors for Aerospace Thermal Protection Systems

    Science.gov (United States)

    Milos, Frank S.; Karunaratne, K.; Arnold, Jim (Technical Monitor)

    2002-01-01

    Health diagnostics is an area where major improvements have been identified for potential implementation into the design of new reusable launch vehicles in order to reduce life-cycle costs, to increase safety margins, and to improve mission reliability. NASA Ames is leading the effort to advance inspection and health management technologies for thermal protection systems. This paper summarizes a joint project between NASA Ames and Korteks to develop active wireless sensors that can be embedded in the thermal protection system to monitor sub-surface temperature histories. These devices are thermocouples integrated with radio-frequency identification circuitry to enable acquisition and non-contact communication of temperature data through aerospace thermal protection materials. Two generations of prototype sensors are discussed. The advanced prototype collects data from three type-k thermocouples attached to a 2.54-cm square integrated circuit.

  1. Temperature mapping, thermal diffusivity and subsoil heat flux at ...

    Indian Academy of Sciences (India)

    Thermal diffusivity () of the soil has been calculated by range and lag methods and also from amplitudes and phase angles of first and second harmonics. The two methods lead to similar results. Diurnal soil heat ux and soil temperatures at different depths are modelled and found to be comparable with observations.

  2. Temperature mapping, thermal diffusivity and subsoil heat flux at ...

    Indian Academy of Sciences (India)

    R. Narasimhan (Krishtel eMaging) 1461 1996 Oct 15 13:05:22

    the day by intense solar radiation than the lay- ers beneath, resulting in temperature gradient between the surface and subsoil on the one hand and surface and air layers near the ground on the other. Within the soil this causes heat flow downward as a thermal wave, the amplitude of which changes with depth. Estimation of ...

  3. THERMAL COUPLE FOR MEASURING TEMPERATURE IN A REACTOR

    Science.gov (United States)

    Kanne, W.

    1959-11-24

    A thermocouple device for measuring the temperature of a flowing fluid in a conduit within which is positioned a metallic rod is presented. A thermocouple junction is secured to the rod centrally, and thermal insulating support disks having a diameter greater than the rod are secured to the end portions of the rod and adapted to fit transversely in the conduit.

  4. Development of a thermal storage system based on the heat of adsorption of water in hygroscopic materials

    NARCIS (Netherlands)

    Wijsman, A.J.T.M.; Oosterhaven, R.; Ouden, C. den

    1979-01-01

    A thermal storage system based on the heat of adsorption of water in hygroscopic materials has been studied as a component of a solar space heating system. The aim of this project is to decrease the storage volume in comparison with a rock-bed storage system by increasing the stored energy density.

  5. Effect of storage temperature on quality of light and full-fat ice cream.

    Science.gov (United States)

    Buyck, J R; Baer, R J; Choi, J

    2011-05-01

    Ice cream quality is dependent on many factors including storage temperature. Currently, the industry standard for ice cream storage is -28.9 °C. Ice cream production costs may be decreased by increasing the temperature of the storage freezer, thus lowering energy costs. The first objective of this research was to evaluate the effect of 4 storage temperatures on the quality of commercial vanilla-flavored light and full-fat ice cream. Storage temperatures used were -45.6, -26.1, and -23.3 °C for the 3 treatments and -28.9 °C as the control or industry standard. Ice crystal sizes were analyzed by a cold-stage microscope and image analysis at 1, 19.5, and 39 wk of storage. Ice crystal size did not differ among the storage temperatures of light and full-fat ice creams at 19.5 or 39 wk. An increase in ice crystal size was observed between 19.5 and 39 wk for all storage temperatures except -45.6 °C. Coldness intensity, iciness, creaminess, and storage/stale off-flavor of the light and full-fat ice creams were evaluated at 39 wk of storage. Sensory evaluation indicated no difference among the different storage temperatures for light and full-fat ice creams. In a second study, light and full-fat ice creams were heat shocked by storing at -28.9 °C for 35 wk and then alternating between -23.3 and -12.2 °C every 24h for 4 wk. Heat-shocked ice creams were analyzed at 2 and 4 wk of storage for ice crystal size and were evaluated by the sensory panel. A difference in ice crystal size was observed for light and full-fat ice creams during heat-shock storage; however, sensory results indicated no differences. In summary, storage of light or full-fat vanilla-flavored ice creams at the temperatures used within this research did not affect quality of the ice creams. Therefore, ice cream manufacturers could conserve energy by increasing the temperature of freezers from -28.9 to -26.1 °C. Because freezers will typically fluctuate from the set temperature, usage of -26.1

  6. Energetic and exergetic analysis of Rankine cycles for solar power plants with parabolic trough and thermal storage

    Directory of Open Access Journals (Sweden)

    Cenuşă Victor-Eduard

    2016-01-01

    Full Text Available The paper analyzes the “secondary” circuit (for thermodynamic conversion of a Concentrated Solar Power (CSP plant with thermodynamic cycle, whose mirrors field supplies a thermal power, averaged over a sunny day, of about 100 MW heat. We study the case of parabolic trough solar collector using silicone oil in the “primary” circuit, which limits the peak temperature below 400 °C. The “primary” circuit uses thermal storage, allowing a delay between the power generation in rapport with the solar energy capture. We choose a water-steam cycle, type Hirn. For increasing its efficiency, it has regenerative feed water preheating and steam reheating. We compared, energetic and exergetic, two types of cycles, using a numerical model with iterative structure, developed by the authors. The results showed that the simplified design achieves practically the same thermodynamic performances with the advanced one.

  7. Preliminary Thermal Modeling of HI-STORM 100 Storage Modules at Diablo Canyon Power Plant ISFSI

    Energy Technology Data Exchange (ETDEWEB)

    Cuta, Judith M.; Adkins, Harold E.

    2014-04-17

    Thermal analysis is being undertaken at Pacific Northwest National Laboratory (PNNL) in support of inspections of selected storage modules at various locations around the United States, as part of the Used Fuel Disposition Campaign of the U.S. Department of Energy, Office of Nuclear Energy (DOE-NE) Fuel Cycle Research and Development. This report documents pre-inspection predictions of temperatures for two modules at the Diablo Canyon Power Plant ISFSI identified as candidates for inspection. These are HI-STORM 100 modules of a site-specific design for storing PWR 17x17 fuel in MPC-32 canisters. The temperature predictions reported in this document were obtained with detailed COBRA-SFS models of these storage systems, with the following boundary conditions and assumptions. • storage module overpack configuration based on FSAR documentation of HI-STORM100S-218, Version B; due to unavailability of site-specific design data for Diablo Canyon ISFSI modules • Individual assembly and total decay heat loadings for each canister, based on at-loading values provided by PG&E, “aged” to time of inspection using ORIGEN modeling o Special Note: there is an inherent conservatism of unquantified magnitude – informally estimated as up to approximately 20% -- in the utility-supplied values for at-loading assembly decay heat values • Axial decay heat distributions based on a bounding generic profile for PWR fuel. • Axial location of beginning of fuel assumed same as WE 17x17 OFA fuel, due to unavailability of specific data for WE17x17 STD and WE 17x17 Vantage 5 fuel designs • Ambient conditions of still air at 50°F (10°C) assumed for base-case evaluations o Wind conditions at the Diablo Canyon site are unquantified, due to unavailability of site meteorological data o additional still-air evaluations performed at 70°F (21°C), 60°F (16°C), and 40°F (4°C), to cover a range of possible conditions at the time of the inspection. (Calculations were also performed at

  8. Cryogenic thermal storage system for discontinuous industrial vacuum processes

    Directory of Open Access Journals (Sweden)

    Scaringella M.

    2012-10-01

    Full Text Available Phase Change Materials are proposed for refrigerating systems in discontinuous industrial vacuum processes where temperatures as low as −140 ÷ −100°C are necessary within time-frames representing 10÷20% of total operating time. An application is proposed for cooling systems used in a Physical Vapour Deposition (PVD apparatus. A prototype has been manufactured which couples a cryopump with a reservoir filled with MethylCycloPentane (MCP-C6H12 and a distribution line where nitrogen in the gaseous state is flowing. Preliminary tests show that temperatures of about −120°C are actually achieved within time windows compatible with PVD applications.

  9. Review of thermal energy storage technologies based on PCM application in buildings

    DEFF Research Database (Denmark)

    Pomianowski, Michal Zbigniew; Heiselberg, Per; Zhang, Yinping

    2013-01-01

    Thermal energy storage systems (TES), using phase change material (PCM) in buildings, are widely investigated technologies and a fast developing research area. Therefore, there is a need for regular and consistent reviews of the published studies. This review is focused on PCM technologies...... is paid to discussion and identification of proper methods to correctly determine the thermal properties of PCM materials and their composites and as well procedures to determine their energy storage and saving potential. The purpose of the paper is to highlight promising technologies for PCM application...... developed to serve the building industry. Various PCM technologies tailored for building applications are studied with respect to technological potential to improve indoor environment, increase thermal inertia and decrease energy use for building operation. What is more, in this review special attention...

  10. Modelling the Size of Seasonal Thermal Storage in the Solar District Heating System

    Directory of Open Access Journals (Sweden)

    Giedrė Streckienė

    2012-12-01

    Full Text Available The integration of a thermal storage system into the solar heating system enables to increase the use of solar thermal energy in buildings and allows avoiding the mismatch between consumers’ demand and heat production in time. The paper presents modelling a seasonal thermal storage tank various sizes of which have been analyzed in the district solar heating system that could cover a part of heat demand for the district of individual houses in Vilnius. A biomass boiler house, as an additional heat source, should allow covering the remaining heat demand. energyPRO software is used for system modelling. The paper evaluates heat demand, climate conditions and technical characteristics.Article in Lithuanian

  11. Long term lily scale bulblet storage : effects of temperature and storage in polyethylene bags

    NARCIS (Netherlands)

    Bonnier, Frans J.M.; Jansen, Ritsert C.; Tuyl, Jaap M. van

    Collections of lily genotypes are usually maintained by yearly planting, harvesting and storage of the bulbs. To facilitate this maintenance, a storage method has been developed for a collection of lily genotypes, including Asiatic hybrids, Oriental hybrids, Lilium longiflorum and L. henryi. Scale

  12. Computational Analysis of Nanoparticles-Molten Salt Thermal Energy Storage for Concentrated Solar Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Kumar, Vinod [Univ. of Texas, El Paso, TX (United States)

    2017-05-05

    High fidelity computational models of thermocline-based thermal energy storage (TES) were developed. The research goal was to advance the understanding of a single tank nanofludized molten salt based thermocline TES system under various concentration and sizes of the particles suspension. Our objectives were to utilize sensible-heat that operates with least irreversibility by using nanoscale physics. This was achieved by performing computational analysis of several storage designs, analyzing storage efficiency and estimating cost effectiveness for the TES systems under a concentrating solar power (CSP) scheme using molten salt as the storage medium. Since TES is one of the most costly but important components of a CSP plant, an efficient TES system has potential to make the electricity generated from solar technologies cost competitive with conventional sources of electricity.

  13. Thermal energy storage - A review of concepts and systems for heating and cooling applications in buildings

    DEFF Research Database (Denmark)

    Pavlov, Georgi Krasimiroy; Olesen, Bjarne W.

    2012-01-01

    period required, economic viability, and operating conditions. One of the main issues impeding the utilization of the full potential of natural and renewable energy sources, e.g., solar and geothermal, for space heating and space cooling applications is the development of economically competitive......The use of thermal energy storage (TES) in buildings in combination with space heating and/or space cooling has recently received much attention. A variety of TES techniques have developed over the past decades. TES systems can provide short-term storage for peak-load shaving as well as long......-term (seasonal) storage for the introduction of natural and renewable energy sources. TES systems for heating or cooling are utilized in applications where there is a time mismatch between the demand and the most economically favorable supply of energy. The selection of a TES system mainly depends on the storage...

  14. THERMAL EVALUATION OF DRUM TYPE RADIOACTIVE MATERIAL PACKAGING ARRAYS IN STORAGE

    Energy Technology Data Exchange (ETDEWEB)

    Gupta, N

    2009-04-27

    Drum type packages are routinely used to transport radioactive material (RAM) in the U.S. Department of Energy (DOE) complex. These packages are designed to meet the federal regulations described in 10 CFR 71.[1] In recent years, there has been a greater need to use these packagings to store the excess fissile material, especially plutonium for long term storage. While the design requirements for safe transportation of these packagings are well defined, the requirements for safe long term storage are not well established. Since the RAM contents in the packagings produce decay heat, it is important that they are stored carefully to prevent overheating of the containment vessel (CV) seals to prevent any leakage and the impact limiter to maintain the package structural integrity. This paper analyzes different storage arrays for a typical 9977 packaging for thermal considerations and makes recommendations for their safe storage under normal operating conditions.

  15. Effect of sweetener combination and storage temperature on physicochemical properties of sucrose free white chocolate.

    Science.gov (United States)

    Rodriguez Furlán, Laura T; Baracco, Yanina; Lecot, Javier; Zaritzky, Noemi; Campderrós, Mercedes E

    2017-08-15

    The influence of a combination of sweeteners (Stevia (St) and sucralose (Su)) and storage temperature on thermal properties, microstructure, water content, texture and Bloom of sucrose free white chocolate was investigated. A strong relationship between the microstructure and the highest percentage of Bloom was observed. The samples with 100%Su and 50%S+50%Su presented microstructures with channels through which solids and fat could more easily spread to the surface, increasing the fat and sugar Bloom formation. However, 50%St+50%Su and 75%St+25%Su samples showed a minimum Bloom formation, probably due to its dense microstructure with no void spaces. The differential scanning calorimetry studies demonstrated that the samples containing 100%St and 75%St+25%Su showed the smallest decrease of melting enthalpy with increasing temperature. Besides, non-isothermal crystallization kinetics was studied by applying Avrami model. The sample 75%St+25%Su presented the highest values of activation energy showing the greatest stability in the temperature range studied (7°C-30°C). Copyright © 2017 Elsevier Ltd. All rights reserved.

  16. Preliminary Thermal Modeling of HI-Storm 100S-218 Version B Storage Modules at Hope Creek Cuclear Power Station ISFSI

    Energy Technology Data Exchange (ETDEWEB)

    Cuta, Judith M.; Adkins, Harold E.

    2013-08-30

    As part of the Used Fuel Disposition Campaign of the U. S. Department of Energy, Office of Nuclear Energy (DOE-NE) Fuel Cycle Research and Development, a consortium of national laboratories and industry is performing visual inspections and temperature measurements of selected storage modules at various locations around the United States. This report documents thermal analyses in in support of the inspections at the Hope Creek Nuclear Generating Station ISFSI. This site utilizes the HI-STORM100 vertical storage system developed by Holtec International. This is a vertical storage module design, and the thermal models are being developed using COBRA-SFS (Michener, et al., 1987), a code developed by PNNL for thermal-hydraulic analyses of multi assembly spent fuel storage and transportation systems. This report describes the COBRA-SFS model in detail, and presents pre-inspection predictions of component temperatures and temperature distributions. The final report will include evaluation of inspection results, and if required, additional post-test calculations, with appropriate discussion of results.

  17. Measurement of temperature-dependent viscosity and thermal conductivity of alumina and titania thermal oil nanofluids

    Science.gov (United States)

    Cieśliński, Janusz T.; Ronewicz, Katarzyna; Smoleń, Sławomir

    2015-12-01

    In this study the results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e., thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1%, and 5% by weight within temperature range from 20 °C to 60 °C. Measurement devices were carefully calibrated by comparison obtained results for pure base liquid (thermal oil) with manufacturer's data. The results obtained for tested nanofluids were compared with predictions made by use of existing models for liquid/solid particles mixtures.

  18. Measurement of temperature-dependent viscosity and thermal conductivity of alumina and titania thermal oil nanofluids

    Directory of Open Access Journals (Sweden)

    Cieśliński Janusz T.

    2015-12-01

    Full Text Available In this study the results of simultaneous measurements of dynamic viscosity, thermal conductivity, electrical conductivity and pH of two nanofluids, i.e., thermal oil/Al2O3 and thermal oil/TiO2 are presented. Thermal oil is selected as a base liquid because of possible application in ORC systems as an intermediate heating agent. Nanoparticles were tested at the concentration of 0.1%, 1%, and 5% by weight within temperature range from 20 °C to 60 °C. Measurement devices were carefully calibrated by comparison obtained results for pure base liquid (thermal oil with manufacturer’s data. The results obtained for tested nanofluids were compared with predictions made by use of existing models for liquid/solid particles mixtures.

  19. Thermodynamic Calculations of Ternary Polyalcohol and Amine Phase Diagrams for Thermal Energy Storage Materials

    Science.gov (United States)

    Shi, Renhai

    Organic polyalcohol and amine globular molecular crystal materials as phase change materials (PCMs) such as Pentaglycerine (PG-(CH3)C(CH 2OH)3), Tris(hydroxymethyl)aminomethane (TRIS-(NH2)C(CH 2OH)3), 2-amino-2methyl-1,3-propanediol (AMPL-(NH2)(CH3)C(CH2OH)2), and neopentylglycol (NPG-(CH3)2C(CH2OH) 2) can be considered to be potential candidates for thermal energy storage (TES) applications such as waste heat recovery, solar energy utilization, energy saving in buildings, and electronic device management during heating or cooling process in which the latent heat and sensible heat can be reversibly stored or released through solid state phase transitions over a range of temperatures. In order to understand the polymorphism of phase transition of these organic materials and provide more choice of materials design for TES, binary systems have been studied to lower the temperature of solid-state phase transition for the specific application. To our best knowledge, the study of ternary systems in these organic materials is limited. Based on this motivation, four ternary systems of PG-TRIS-AMPL, PG-TRIS-NPG, PG-AMPL-NPG, and TRIS-AMPL-NPG are proposed in this dissertation. Firstly, thermodynamic assessment with CALPHAD method is used to construct the Gibbs energy functions into thermodynamic database for these four materials based on available experimental results from X-Ray Diffraction (XRD) and Differential Scanning Calorimetry (DSC). The phase stability and thermodynamic characteristics of these four materials calculated from present thermodynamic database with CALPHAD method can match well the present experimental results from XRD and DSC. Secondly, related six binary phase diagrams of PG-TRIS, PG-AMPL, PG-NPG, TRIS-AMPL, TRIS-NPG, and AMPL-NPG are optimized with CALPHAD method in Thermo-Calc software based on available experimental results, in which the substitutional model is used and excess Gibbs energy is expressed with Redlich-Kister formalism. The

  20. Wide Temperature Range Hybrid Energy Storage Device Project

    Data.gov (United States)

    National Aeronautics and Space Administration — This proposal concerns the fabrication of a hybrid battery capacitor (HBC) using Eltron's knowledge gained in battery and capacitor research. Energy storage systems...