Analysis of a self-propelling sheet with heat transfer through non-isothermal fluid in an inclined human cervical canal.

Science.gov (United States)

Walait, Ahsan; Siddiqui, A M; Rana, M A

2018-02-13

The present theoretical analysis deals with biomechanics of the self-propulsion of a swimming sheet with heat transfer through non-isothermal fluid filling an inclined human cervical canal. Partial differential equations arising from the mathematical modeling of the proposed model are solved analytically. Flow variables like pressure gradient, propulsive velocity, fluid velocity, time mean flow rate, fluid temperature, and heat-transfer coefficients are analyzed for the pertinent parameters. Striking features of the pumping characteristics are explored. Propulsive velocity of the swimming sheet becomes faster for lower Froude number, higher Reynolds number, and for a vertical channel. Temperature and peak value of the heat-transfer coefficients below the swimming sheet showed an increase by the increment of Brinkmann number, inclination, pressure difference over wavelength, and Reynolds number whereas these quantities decrease with increasing Froude number. Aforesaid parameters have shown opposite effects on the peak value of the heat-transfer coefficients below and above the swimming sheet. Relevance of the current results to the spermatozoa transport with heat transfer through non-isothermal cervical mucus filling an inclined human cervical canal is also explored.

Heat transfer analysis for unsteady MHD flow past a non-isothermal stretching surface

International Nuclear Information System (INIS)

Mukhopadhyay, Swati

2011-01-01

Highlights: ► Unsteady boundary layer flow and heat transfer over a non-isothermal stretching sheet in a magnetic field are studied. ► Fluid velocity and temperature decrease for increasing unsteadiness parameter. ► Fluid velocity decreases but temperature increases with the increasing values of the Hartman number. ► The sheet temperature in respect of distance and time has analogous effects on the heat transfer. - Abstract: An analysis is made for the unsteady two-dimensional magneto-hydrodynamic flow of an incompressible viscous and electrically conducting fluid over a stretching surface having a variable and general form of surface temperature which removes the restrictions of the particular forms of prescribed surface temperature. Similarity solutions for the transformed governing equations are obtained. The transformed boundary layer equations are solved numerically for some values of the involved parameters, namely the unsteadiness parameter, magnetic parameter, the temperature exponent parameters. The features of the flow and heat transfer characteristics for different values of the governing parameters are analysed and discussed. It is found that the fluid velocity and temperature decrease for increasing unsteadiness parameter. Fluid velocity decreases with the increasing values of the Hartman number resulting an increase in the temperature field in steady as well in unsteady case. It is observed that the variation of the sheet temperature in respect of distance and time has analogous effects both on the free surface temperature and on the heat transfer rate (Nusselt number) at the sheet.

The heat capacity of polyethylene fibers measured by multi-frequency temperature-modulated calorimetry

International Nuclear Information System (INIS)

Pyda, M.; Nowak-Pyda, E.; Wunderlich, B.

2006-01-01

The apparent heat capacity of polyethylene fibers in the melting region was measured by quasi-isothermal, temperature-modulated differential scanning calorimetry (TMDSC) and compared with results from standard differential scanning calorimetry (DSC) and the solid and liquid thermodynamic heat capacity as references from the ATHAS Data Bank. Using a multi-frequency, complex sawtooth modulation in the quasi-isothermal mode disclosed for the first time that the uncorrected apparent heat capacity C p =A Φ /(A T s ω) of the liquid polyethylene fiber increases with increasing frequency (A Φ is the differential heat-flow rate and A T s is the sample temperature). The frequency-dependent heat capacity cannot be represented by the expression: C p =A Φ /(A T s νω)[1+(τνω) 2 ] 0.5 because of a negative τ 2 . The results were later confirmed by independent measurements on single sinusoidal quasi-isothermal TMDSC on the same material. The error is caused by shrinking of the fiber, which deforms the sample pan

Fission track retention in minerals as a function of heating time during isothermal experiments

International Nuclear Information System (INIS)

Burchart, J.; Butkiewicz, T.; Dakowski, M.; Galazka-Friedman, J.

1979-01-01

The linear dependence of track retention on logarithm of heating time (at constant temperature) has been verified by statistical analysis of data on isothermal annealing of apatite. The other functions proposed (rho/rho 0 as a linearly decreasing function of exp t or t) fit the experimental data only within a limited range of heating times, where the shapes of all three are experimentally hard to resolve. The logarithmic relationship implies a memory of tracks for thermal events and creates a basis for methods of age corrections. (author)

Apparent heat capacity measurements and thermodynamic functions of D(−)-fructose by standard and temperature-modulated calorimetry

International Nuclear Information System (INIS)

Magoń, A.; Pyda, M.

2013-01-01

Highlights: ► Experimental, apparent heat capacity of fructose was investigated by advanced thermal analysis. ► Equilibrium melting parameters of fructose were determined. ► Decomposition, superheating of crystalline fructose during melting process were presented. ► TGA, DSC, and TMDSC are useful tools for characterisation of fructose. - Abstract: The qualitative and quantitative thermal analyses of crystalline and amorphous D(−)-fructose were studied utilising methods of standard differential scanning calorimetry (DSC), quasi-isothermal temperature-modulated differential scanning calorimetry (quasi-isothermal TMDSC), and thermogravimetric analysis (TGA). Advanced thermal analysis of fructose was performed based on heat capacity. The apparent total and apparent reversing heat capacities, as well as phase transition parameters were examined on heating and cooling. The melting temperature, T m , of crystalline D(−)-fructose shows a heating rate dependency, which increases with raising the heating rate and leads to superheating. The equilibrium melting temperatures: T m ∘ (onset) = 370 K and T m ∘ (peak) = 372 K, and the equilibrium enthalpy of fusion Δ fus H ° = 30.30 kJ · mol −1 , of crystalline D(−)-fructose were estimated on heating for the results at zero heating rate. Anomalies in the heat capacity in the liquid state of D(−)-fructose, assigned as possible tautomerisation equilibrium, were analysed by DSC and quasi-isothermal TMDSC, both on heating and cooling. Thermal stability of crystals in the region of the melting temperature was examined by TGA and quasi-isothermal TMDSC. Melting, mutarotation, and degradation processes occur simultaneously and there are differences in values of the liquid heat capacity of D(−)-fructose with varied thermal history, measured by quasi-isothermal TMDSC. Annealing of amorphous D(−)-fructose between the glass transition temperature, T g , and the melting temperature, T m , also leads to

Kinetics of coal liquefaction during heating-up and isothermal stages

Energy Technology Data Exchange (ETDEWEB)

Xian Li; Haoquan Hu; Shengwei Zhu; Shuxun Hu; Bo Wu; Meng Meng [Dalian University of Technology, Dalian (China). Institute of Coal Chemical Engineering

2008-04-15

Direct liquefaction of Shenhua bituminous coal was carried out in a 500 ml autoclave with iron catalyst and coal liquefaction cycle-oil as solvent at initial hydrogen of 8.0 MPa, residence time of 0-90 min. To investigate the liquefaction kinetics, a model for heating-up and isothermal stages was developed to estimate the rate constants of both stages. In the model, the coal was divided into three parts, easy reactive part, hard reactive part and unreactive part, and four kinetic constants were used to describe the reaction mechanism. The results showed that the model is valid for both heating-up and isothermal stages of liquefaction perfectly. The rate-controlled process for coal liquefaction is the reaction of preasphaltene plus asphaltene (PAA) to oil plus gas (O + G). The upper-limiting conversion of isothermal stage was estimated by the kinetic calculation. 21 refs., 4 figs., 4 tabs.

Hardness of H13 Tool Steel After Non-isothermal Tempering

Science.gov (United States)

Nelson, E.; Kohli, A.; Poirier, D. R.

2018-04-01

A direct method to calculate the tempering response of a tool steel (H13) that exhibits secondary hardening is presented. Based on the traditional method of presenting tempering response in terms of isothermal tempering, we show that the tempering response for a steel undergoing a non-isothermal tempering schedule can be predicted. Experiments comprised (1) isothermal tempering, (2) non-isothermal tempering pertaining to a relatively slow heating to process-temperature and (3) fast-heating cycles that are relevant to tempering by induction heating. After establishing the tempering response of the steel under simple isothermal conditions, the tempering response can be applied to non-isothermal tempering by using a numerical method to calculate the tempering parameter. Calculated results are verified by the experiments.

Thermodynamics of aqueous methyldiethanolamine (MDEA) and methyldiethanolammonium chloride (MDEAH+Cl-) over a wide range of temperature and pressure: Apparent molar volumes, heat capacities, and isothermal compressibilities

International Nuclear Information System (INIS)

Hawrylak, B.; Palepu, R.; Tremaine, Peter R.

2006-01-01

Apparent molar volumes of aqueous methyldiethanolamine and its salt were determined with platinum vibrating tube densitometers over a range of temperatures from 283K= o , heat capacities C p o , and isothermal compressibilities κ T o . The standard partial molar volumes V o for the neutral amine and its salt show increasingly positive and negative values, respectively, at high temperatures and pressures, as predicted by corresponding states and group additivity arguments. The density model and the revised Helgeson-Kirkham-Flowers (HKF) model have been used to represent the temperature and pressure dependence of the standard partial molar properties to yield a full thermodynamic description of the system

Investigation of ammonia/water hybrid absorption/compression heat pumps for heat supply temperatures above 100 °C

DEFF Research Database (Denmark)

Jensen, Jonas Kjær; Reinholdt, Lars; Markussen, Wiebke Brix

2014-01-01

The hybrid absorption/compression heat pump (HACHP) using ammonia-water as working fluid is a promising technology for development of a high temperature industrial heat pump. This is due to two properties inherent to the use of zeotropic mixtures: non-isothermal phase change and reduced vapour...... using these components. A technically and economically feasible solution is defined as one that satisfies constraints on the coefficient of performance (COP), low and high pressure, compressor discharge temperature and volumetric heat capacity. The ammonia mass fraction of the rich solution...

Isothermal heat measurements of TBP-nitric acid solutions

International Nuclear Information System (INIS)

Smith, J.R.; Cavin, W.S.

1994-01-01

Net heats of reaction were measured in an isothermal calorimeter for both single phase (organic) and two phase (organic and aqueous) TBP/HNO 3 reacting solutions at temperatures above 100 C. The oxidation rate constant was determined to be 5.4E-4 min -1 at 110 C for an open ''vented'' system as compared to 1.33 E-3 min -1 in the closed system. The heat released per unit material oxidized was also reduced. The oxidation in both phases was found to be first order in nitric acid and pseudo-zero order in butylnitrate and water. The hydrolysis (esterification) rate constant determined by Nichols' (1.33E-3 min -1 ) fit the experimental data from this work well. Forced evaporation of the volatile components by the product gases from oxidation resulted in a cooling mechanism which more than balanced the heat from the oxidation reaction in the two-phased systems. Rate expressions were derived and rate constants determined for both the single and two phase systems. An approximating mathematical model was developed to fit the experimental data and to extrapolate beyond the experimental conditions. This model shows that one foot of ''reacting'' 14.3M HNO 3 aqueous phase solution at 121 C will transport sufficient water to the organic phase to replace evaporative losses, maintaining endothermicity, for organic layers up to 12.2 + 6.0 feet deep. If the pressure in a reacting system is allowed to increase due to insufficient venting the temperature of the organic phase would increase in temperature to reach a new equilibrium. The rate of oxidation would increase not only due to the increase in temperature but also from the increased concentration of dissolved HNO 3 reduction products. Another important factor is that the cooling system described in this work becomes less effective as the total pressure increases. These factors probably contributed to the explosion at Tomsk

Isothermal martensite formation at sub-zero temperatures

DEFF Research Database (Denmark)

Stojko, Allan; Hansen, Mikkel Fougt; Slycke, Jan

2012-01-01

, quenched in oil, and thereafter investigated with vibrating sample magnetometry, which allows a quantitative assessment of the fraction of retained austenite as a function of the sub-zero temperature and time. Isothermal martensite formation was observed on interrupting the continuous cooling (5 K...... with a continuation of the martensitic transformation. On prolonged isothermal holding, a volume reduction was observed for AISI 52100, but not for AISI 1070. Copyright © 2011 by ASTM International....

Multi-step cure kinetic model of ultra-thin glass fiber epoxy prepreg exhibiting both autocatalytic and diffusion-controlled regimes under isothermal and dynamic-heating conditions

Science.gov (United States)

Kim, Ye Chan; Min, Hyunsung; Hong, Sungyong; Wang, Mei; Sun, Hanna; Park, In-Kyung; Choi, Hyouk Ryeol; Koo, Ja Choon; Moon, Hyungpil; Kim, Kwang J.; Suhr, Jonghwan; Nam, Jae-Do

2017-08-01

As packaging technologies are demanded that reduce the assembly area of substrate, thin composite laminate substrates require the utmost high performance in such material properties as the coefficient of thermal expansion (CTE), and stiffness. Accordingly, thermosetting resin systems, which consist of multiple fillers, monomers and/or catalysts in thermoset-based glass fiber prepregs, are extremely complicated and closely associated with rheological properties, which depend on the temperature cycles for cure. For the process control of these complex systems, it is usually required to obtain a reliable kinetic model that could be used for the complex thermal cycles, which usually includes both the isothermal and dynamic-heating segments. In this study, an ultra-thin prepreg with highly loaded silica beads and glass fibers in the epoxy/amine resin system was investigated as a model system by isothermal/dynamic heating experiments. The maximum degree of cure was obtained as a function of temperature. The curing kinetics of the model prepreg system exhibited a multi-step reaction and a limited conversion as a function of isothermal curing temperatures, which are often observed in epoxy cure system because of the rate-determining diffusion of polymer chain growth. The modified kinetic equation accurately described the isothermal behavior and the beginning of the dynamic-heating behavior by integrating the obtained maximum degree of cure into the kinetic model development.

Isothermal and non-isothermal cure of a tri-functional epoxy resin (TGAP): A stochastic TMDSC study

International Nuclear Information System (INIS)

Hutchinson, John M.; Shiravand, Fatemeh; Calventus, Yolanda; Fraga, Iria

2012-01-01

Highlights: ► First evaluation of T g of tri-functional epoxy resin TGAP by DSC. ► Clearly shows advantages of TOPEM for isothermal and non-isothermal cure analysis. ► Evidence of highly non-linear enthalpy relaxation in partially cured TGAP system. - Abstract: The isothermal cure of a highly reactive tri-functional epoxy resin, tri-glycidyl para-amino phenol (TGAP), with diamino diphenyl sulphone (DDS), at two different cure temperatures T c has been studied by both conventional differential scanning calorimetry (DSC) and by a stochastic temperature modulated DSC technique, TOPEM. From a series of isothermal cure experiments for increasing cure times, the glass transition temperature T g as a function of isothermal cure time is determined by conventional DSC from a second (non-isothermal) scan, and the vitrification time t v is obtained as the time at which T g = T c . In parallel, TOPEM experiments at the same T c lead directly to the determination of t v from the sigmoidal change in the quasi-static heat capacity. It is not possible to identify the glass transition temperature of the fully cured system, T g∞ , in a third scan by conventional DSC. In contrast, with TOPEM a second (non-isothermal) scan at 2 K/min after the isothermal cure gives rise to three separate transitions: devitrification of the partially cured and vitrified material; almost immediate vitrification as the T g of the system again rises; finally another devitrification, at a temperature approximating closely to T g∞ . Thus with TOPEM it is possible to obtain a calorimetric measure of the glass transition temperature of this fully cured system.

Engineered, Spatially Varying Isothermal Holds: Enabling Combinatorial Studies of Temperature Effects, as Applied to Metastable Titanium Alloy β-21S

International Nuclear Information System (INIS)

Martin, Brian; Colorado School of Mines, Golden, CO; Samimi, Peyman; Colorado School of Mines, Golden, CO; Collins, Peter

2017-01-01

A novel method to systematically vary temperature and thus study the resulting microstructure of a material is presented. This new method has the potential to be used in a combinatorial fashion, allowing the rapid study of thermal holds on microstructures to be conducted. This is demonstrated on a beta titanium alloy, where the thermal history has a strong effect on microstructure. It is informed by simulation and executed using the resistive heating capabilities of a Gleeble 3800 thermomechanical simulator. Spatially varying isothermal holds of 4 h were affected, where the temperature range of the multiple isothermal holds varied by ~175 °C.

Heats of Mixing Using an Isothermal Titration Calorimeter: Associated Thermal Effects

Directory of Open Access Journals (Sweden)

Fabiola Socorro

2009-06-01

Full Text Available The correct determination of the energy generated or absorbed in the sample cell of an Isothermal Titration Calorimeter (ITC requires a thorough analysis of the calorimetric signal. This means the identification and quantification of any thermal effect inherent to the working method. In this work, it is carried out a review on several thermal effects, studied by us in previous work, and which appear when an ITC is used for measuring the heats of mixing of liquids in a continuous mode. These effects are due to: (i the difference between the temperature of the injected liquid and the temperature of the mixture during the mixing process, (ii the increase of the liquid volume located in the mixing cell and (iii the stirring velocity. Besides, methods for the identification and quantification of the mentioned effects are suggested.

Evolution of the Cerro Prieto geothermal system as interpreted from vitrinite reflectance under isothermal conditions

Energy Technology Data Exchange (ETDEWEB)

Barker, C.E. (US Geological Survey, Denver, CO); Pawlewicz, M.J.; Bostick, N.H.; Elders, W.A.

1981-01-01

Temperature estimates from reflectance data in the Cerro Prieto system correlate with modern temperature logs and temperature estimates from fluid inclusion and oxygen isotope geothermometry indicating that the temperature in the central portion of the Cerro Prieto System is now at its historical maximum. Isoreflectance lines formed by contouring vitrinite reflectance data for a given isothermal surface define an imaginary surface that indicates an apparent duration of heating in the system. The 250/sup 0/C isothermal surface has a complex dome-like form suggesting a localized heat source that has caused shallow heating in the central portion of this system. Isoreflectance lines relative to this 250/sup 0/C isothermal surface define a zone of low reflectance roughly corresponding to the crest of the isothermal surface. Comparison of these two surfaces suggest that the shallow heating in the central portion of Cerro Prieto is young relative to the heating (to 250/sup 0/C) on the system margins. Laboratory and theoretical models of hydrothermal convection cells suggest that the form of the observed 250/sup 0/C isothermal surface and the reflectance surface derived relative to it results from the convective rise of thermal fluids under the influence of a regional hydrodynamic gradient that induces a shift of the hydrothermal heating effects to the southwest.

Sorption isotherms modeling approach of rice-based instant soup mix stored under controlled temperature and humidity

Directory of Open Access Journals (Sweden)

Yogender Singh

2015-12-01

Full Text Available Moisture sorption isotherms of rice-based instant soup mix at temperature range 15–45°C and relative humidity from 0.11 to 0.86 were determined using the standard gravimetric static method. The experimental sorption curves were fitted by five equations: Chung-Pfost, GAB, Henderson, Kuhn, and Oswin. The sorption isotherms of soup mix decreased with increasing temperature, exhibited type II behavior according to BET classification. The GAB, Henderson, Kuhn, and Oswin models were found to be the most suitable for describing the sorption curves. The isosteric heat of sorption of water was determined from the equilibrium data at different temperatures. It decreased as moisture content increased and was found to be a polynomial function of moisture content. The study has provided information and data useful in large-scale commercial production of soup and have great importance to combat the problem of protein-energy malnutrition in underdeveloped and developing countries.

Time of isothermal holding in the course of in-air heat treatment of soft magnetic Fe-based amorphous alloys and their magnetic properties

Science.gov (United States)

Skulkina, N. A.; Ivanov, O. A.; Pavlova, I. O.; Minina, O. A.

2011-12-01

On the example of soft magnetic Fe81B13Si4C2 and Fe77Ni1Si9B13 amorphous alloys, the relation between the level of magnetic properties and duration of isothermal holding in the course of heat treatment in air has been studied. The optimum temperature-dependent time τ of isothermal holding has been shown to be related to the volume fraction of domains ( V orth) with orthogonal magnetization in the initial (quenched) ribbon by equation V orth = ττ1/3. A temperature dependence of the proportionality coefficient α, which determines the degree of diffusion-process activity, has been determined. The results obtained allow us to substantially simplify the choice of optimum conditions of atmospheric heat treatment of soft magnetic Fe-based amorphous ribbons.

Improved Isotherm Data for Adsorption of Methane on Activated Carbons

KAUST Repository

Loh, Wai Soong

2010-08-12

This article presents the adsorption isotherms of methane onto two different types of activated carbons, namely, Maxsorb III and ACF (A-20) at temperatures from (5 to 75) °C and pressures up to 2.5 MPa. The volumetric technique has been employed to measure the adsorption isotherms. The experimental results presented herein demonstrate the improved accuracy of the uptake values compared with previous measurement techniques for similar adsorbate-adsorbent combinations. The results are analyzed with various adsorption isotherm models. The heat of adsorption, which is concentration and temperature dependent, has been calculated from the measured isotherm data. Henry\\'s law coefficients for these adsorbent-methane pairs are also evaluated at various temperatures. © 2010 American Chemical Society.

Thermodynamic Properties, Sorption Isotherms and Glass Transition Temperature of Cape Gooseberry (Physalis peruviana L.

Directory of Open Access Journals (Sweden)

Jessica López

2014-01-01

Full Text Available Adsorption and desorption isotherms of fresh and dried Cape gooseberry (Physalis peruviana L. were determined at three temperatures (20, 40 and 60 °C using a gravimetric technique. The data obtained were fitted to several models including Guggenheim-Anderson- De Boer (GAB, Brunauer-Emmett-Teller (BET, Henderson, Caurie, Smith, Oswin, Halsey and Iglesias-Chirife. A non-linear least square regression analysis was used to evaluate the models. The Iglesias-Chirife model fitted best the experimental data. Isosteric heat of sorption was also determined from the equilibrium sorption data using the Clausius-Clapeyron equation and was found to decrease exponentially with increasing moisture content. The enthalpy-entropy compensation theory was applied to the sorption isotherms and indicated an enthalpy-controlled sorption process. Glass transition temperature (Tg of Cape gooseberry was also determined by differential scanning calorimetry and modelled as a function of moisture content with the Gordon-Taylor, the Roos and the Khalloufi models, which proved to be excellent tools for predicting glass transition of Cape gooseberry.

Effect of aspect ratio on natural convective heat transfer adjacent to a vertival isothermal cylinder immersed in pure water

International Nuclear Information System (INIS)

Riu, Kap Jong; Eum, Yong Kyoon; Park, Sung Soon

1990-01-01

A numerical analysis is performed about the effect of aspect ratio on heat transfer adjacent to a vertical-isothermal cylinder of 0 deg C in pure water. The numerical results for the effect of aspect ratio are presented for ambient water temperature from 1.0 deg C to 15.0 deg C. They include velocity profiles, temperature profiles and mean Nusselt number for the entire flow field. The mean Nusselt numbers of vertival-isothermal cylinder are compared with that of vertival-isothermal plate in increasing aspect ratio of cylinder. Furthermore, the mean Nusselt numbers of unsteady region in the range of 0.084< R<0.328 are obtained by curve-fitting. The natural convection caused by phase change was investigated by experiments when the vertical ice cylinder was immersed in the pure water of which the tempetature range is from 2.0 to 10.0 deg C. Each figure shows a time-exposure photograph of flow occuring at the respective ambient water temperature conditions. As the ambient water temperature is increased from 2.0 to 10.0 deg C, the regimes of upward steady state flows, steady state dual flows and downward steady state flows are observed. Also, the variations of shapes of melting ice cylinder are investigated.(Author)

Convective heat transport of high-pressure flows inside active, thick walled-tubes with isothermal outer surfaces: usage of Nusselt correlation equations for an inactive, thin walled-tube

Energy Technology Data Exchange (ETDEWEB)

Campo, Antonio [Idaho State Univ., Nuclear Engineering Dept., Pocatello, ID (United States); Sanchez, Alejo [Universidad de los Andes, Depto. de Ingenieria Mecanica, Merida (Venezuela)

1998-03-01

A semi-analytical analysis was conducted for the prediction of the mean bulk- and interface temperatures of gaseous and liquid fluids moving laminarly at high pressures inside thick-walled metallic tubes. The outer surfaces of the tubes are isothermal. The central goal of this article is to critically examine the thermal response of this kind of in-tube flows utilizing two versions of the 1-D lumped model: one is differential-numerical while the other is differential-algebraic. For the former, the local Nusselt number characterizing an inactive, isothermal tube was taken from correlation equations reported in the heat transfer literature. For the latter, a streamwise-mean Nusselt number associated with an active, isothermal tube was taken from standard correlation equations that appear in text-books on basic heat transfer. For the two different versions of the 1-D lumped model tested, the computed results consistently demonstrate that the differential-algebraic, provides accurate estimates of both the mean bulk- and the interface temperatures when compared with those temperature results computed with formal 2-D differential models. (author)

A sample holder for the study of isothermal heat of hydration of cement

DEFF Research Database (Denmark)

Hansen, Per Freiesleben; Jensen, Ole Mejlhede

1998-01-01

Different techniques for measuring heat of hydration of cement are discussed, and a sample holder designed specially for measuring isothermal heat of hydration is described. A particular characteristic of the sample holder is the vacuum mixing technique which ensures a momentary and homogeneous...

Estimating heat transfer bias of kinetic measurement for polymers by differential scanning calorimetry with isothermal mode; Evaluation de l'erreur due au transfert de chaleur lors des mesures cinetiques dans les polymeres par calorimetrie differentielle a balayage en mode isotherme

Energy Technology Data Exchange (ETDEWEB)

Danes, Florin; Garnier, Bertrand [Laboratoire de Thermocinetique, UMR CNRS 6607, Ecole Polytechnique de l' Universite de Nantes, rue C. Pauc, BP50609, 44306 cedex 3, Nantes (France)

2003-06-01

The non-uniformity of temperatures in the DSC sample, and the subsequent difference between mean sample temperature and measured one (in the support of the crucible) are identified as the main source of bias for the isothermal mode determination of kinetic characteristics by differential scanning calorimetry. Chemical reactions under consideration are these with important heat effects into thermal insulators, as for example the reticulation of polymeric materials.By introducing an analytical model of heat transfer in DSC reactive samples, we have performed an estimation for the upper limit of the maximal size of samples which corresponds to a given relative error of the reaction rate, as measured by isothermal DSC calorimetry. For example, with a 5% error and flat samples, we have found admissible sample thicknesses which decrease with temperature and are between 1.9 and 3.1 mm for the sulphur vulcanization of a natural rubber and between 0.6 and 1.1 mm for the reticulation of a pre-polymerized epoxy resin. (authors)

Modeling Coupled Water and Heat Transport in the Root Zone of Winter Wheat under Non-Isothermal Conditions

Directory of Open Access Journals (Sweden)

Rong Ren

2017-04-01

Full Text Available Temperature is an integral part of soil quality in terms of moisture content; coupling between water and heat can render a soil fertile, and plays a role in water conservation. Although it is widely recognized that both water and heat transport are fundamental factors in the quantification of soil mass and energy balance, their computation is still limited in most models or practical applications in the root zone under non-isothermal conditions. This research was conducted to: (a implement a fully coupled mathematical model that contains the full coupled process of soil water and heat transport with plants focused on the influence of temperature gradient on soil water redistribution and on the influence of change in soil water movement on soil heat flux transport; (b verify the mathematical model with detailed field monitoring data; and (c analyze the accuracy of the model. Results show the high accuracy of the model in predicting the actual changes in soil water content and temperature as a function of time and soil depth. Moreover, the model can accurately reflect changes in soil moisture and heat transfer in different periods. With only a few empirical parameters, the proposed model will serve as guide in the field of surface irrigation.

Survival of encapsulated Lactobacillus plantarum during isothermal heating and bread baking

NARCIS (Netherlands)

Zhang, L.; Chen, Xiao Dong; Boom, R.M.; Schutyser, M.A.I.

2018-01-01

The effect of encapsulation on the survival of Lactobacillus plantarum during isothermal heating and bread baking was investigated. Four encapsulating materials were evaluated, i.e., reconstituted skim milk (RSM), gum arabic (GA), maltodextrin (MD) and inulin. Freeze dried bacteria survived better

Mathematical Modeling of Moisture Sorption Isotherms and Determination of Isosteric Heats of Sorption of Ziziphus Leaves

Directory of Open Access Journals (Sweden)

Amel Saad

2014-01-01

Full Text Available Desorption and adsorption equilibrium moisture isotherms of Ziziphus spina-christi leaves were determined using the gravimetric-static method at 30, 40, and 50°C for water activity (aw ranging from 0.057 to 0.898. At a given aw, the results show that the moisture content decreases with increasing temperature. A hysteresis effect was observed. The experimental data of sorption were fitted by eight models (GAB, BET, Henderson-Thompson, modified-Chung Pfost, Halsey, Oswin, Peleg, and Adam and Shove. After evaluating the models according to several criteria, the Peleg and Oswin models were found to be the most suitable for describing the sorption curves. The net isosteric heats of desorption and adsorption of Ziziphus spina-christi leaves were calculated by applying the Clausius-Clapeyron equation to the sorption isotherms and an expression for predicting these thermodynamic properties was given.

Isothermal calorimeter for measurements of time-dependent heat generation rate in individual supercapacitor electrodes

Science.gov (United States)

Munteshari, Obaidallah; Lau, Jonathan; Krishnan, Atindra; Dunn, Bruce; Pilon, Laurent

2018-01-01

Heat generation in electric double layer capacitors (EDLCs) may lead to temperature rise and reduce their lifetime and performance. This study aims to measure the time-dependent heat generation rate in individual carbon electrode of EDLCs under various charging conditions. First, the design, fabrication, and validation of an isothermal calorimeter are presented. The calorimeter consisted of two thermoelectric heat flux sensors connected to a data acquisition system, two identical and cold plates fed with a circulating coolant, and an electrochemical test section connected to a potentiostat/galvanostat system. The EDLC cells consisted of two identical activated carbon electrodes and a separator immersed in an electrolyte. Measurements were performed on three cells with different electrolytes under galvanostatic cycling for different current density and polarity. The measured time-averaged irreversible heat generation rate was in excellent agreement with predictions for Joule heating. The reversible heat generation rate in the positive electrode was exothermic during charging and endothermic during discharging. By contrast, the negative electrode featured both exothermic and endothermic heat generation during both charging and discharging. The results of this study can be used to validate existing thermal models, to develop thermal management strategies, and to gain insight into physicochemical phenomena taking place during operation.

Experimental study of natural convection heat transfer from an isothermal combined geometry (downward cone- cylinder)

Energy Technology Data Exchange (ETDEWEB)

Mokhtari, A. [Yazd Univ., Yazd (Iran, Islamic Republic of). Dept. of Mechanical Engineering; Goharkhah, M.; Ashjaee, M. [Tehran Univ., Tehran (Iran, Islamic Republic of). Dept. of Mechanical Engineering

2009-07-01

Laminar free convection heat transfer from an isothermal combined geometry which consists of a downward cone attached to a vertical cylinder was studied. In particular, a Mach-Zehnder interferometer was used to determine the change in local and average heat transfer coefficients on the surface of an isothermal combined geometry for different vertex angles. The effect of the vertex angle on heat transfer was also investigated by keeping the height of the cylinder and slant length of the cone constant for all objects. The experimental data showed that the local heat transfer coefficient on the conical part increased in the vicinity of the cylinder and cone intersection. The distance between the point of minimum heat transfer coefficient on the cone and vertex of the cone decreased as the vertex angle increased. The maximum average Nusselt number for a constant Rayleigh number was obtained for the geometry with the smallest vertex angle. For all objects, the average Nusselt number increased with an increase in the Rayleigh number. An experiment was carried out on a vertical isothermal cylinder of circular cross section in order to validate the experimental approach. An analytical solution was found to be in good agreement with experimental results. 31 refs., 9 figs.

The effect of heat generation in inclined slats on the natural convective heat transfer from an isothermal heated vertical plate

International Nuclear Information System (INIS)

Oosthuizen, P.H.; Sun, L.; Naylor, D.

2003-01-01

Natural convective heat transfer from a wide heated vertical isothermal plate with adiabatic surfaces above and below the heated surface has been considered. There are a series of equally spaced vertical thin, flat surfaces (termed 'slats') near the heated surface, these surfaces being, in general, inclined to the heated surface. There is, in general, a uniform heat generation in the slats. The slats are pivoted about their centre-point and thus as their angle is changed, the distance of the tip of the slat from the plate changes. The situation considered is an approximate model of a window with a vertical blind, the particular case where the window is hotter than the room air being considered. The heat generation in the slats in this situation is the result of solar radiation passing through the window and falling on and being absorbed by the slats of the blind. The flow has been assumed to be laminar and steady. Fluid properties have been assumed constant except for the density change with temperature that gives rise to the buoyancy forces. The governing equations have been written in dimensionless form and the resulting dimensionless equations have been solved using a commercial finite-element package. The solution has the following parameters: (1) the Rayleigh number (2) the Prandtl number (3) the dimensionless heat generation rate in the slats per unit frontal area (4) the dimensionless distance of the slat center point (the pivot point) from the surface (5) the dimensionless slat size (6) the dimensionless slat spacing (7) the angle of inclination of the slats. Because of the application that motivated the study, results have only been obtained for a Prandtl number of 0.7. The effect of the other dimensionless variables on the mean dimensionless heat transfer rate from the heated vertical surface has been examined. (author)

A Numerical Study on the Heat Transfer Characteristics of a Solar Thermal Receiver with High-temperature Heat Pipes

International Nuclear Information System (INIS)

Park, Young Hark; Jung, Eui Guk; Boo, Joon Hong

2007-01-01

A numerical analysis was conducted to predict the heat transfer characteristics of a solar receiver which is subject to very high heat fluxes and temperatures for solar thermal applications. The concentration ratio of the solar receiver ranges from 200 to 1000 and the concentrated heat is required to be transported to a certain distance for specific applications. The study deals with a solar receiver incorporating high-temperature sodium heat pipe as well as typical one that employs a molten-salt circulation loop. The isothermal characteristics in the receiver section is of major concern. The diameter of the solar thermal receiver was 120 mm and the length was 400 mm. For the molten-salt circulation type receiver, 48 axial channels of the same dimensions were attached to the outer wall of the receiver with even spacing in the circumferential direction. The molten salt fed through the channels by forced convection using a special pump. For the heat pipe receiver, the channels are changed to high-temperature sodium heat pipes. Commercial softwares were employed to deal with the radiative heat transfer inside the receiver cavity and the convection heat transfer along the channels. The numerical results are compared and analyzed from the view point of high-temperature solar receiver

Instrument-free exothermic heating with phase change temperature control for paper microfluidic devices

Science.gov (United States)

Singleton, Jered; Zentner, Chris; Buser, Josh; Yager, Paul; LaBarre, Paul; Weigl, Bernhard H.

2013-03-01

Many infectious diseases, as well as some cancers, that affect global health are most accurately diagnosed through nucleic acid amplification and detection. There is a great need to simplify nucleic acid-based assay systems for use in global health in low-resource settings as well as in settings that do not have convenient access to laboratory staff and equipment such as doctors' offices and home care settings. In developing countries, unreliable electric power, inadequate supply chains, and lack of maintenance for complex diagnostic instruments are all common infrastructure shortfalls. Many elements of instrument-free, disposable, nucleic acid amplification assays have been demonstrated in recent years. However, the problem of instrument-free,1 low-cost, temperature-controlled chemical heating remains unsolved. In this paper we present the current status and results of work towards developing disposable, low-cost, temperature-controlled heaters designed to support isothermal nucleic acid amplification assays that are integrated with a two-dimensional paper network. Our approach utilizes the heat generated through exothermic chemical reactions and controls the heat through use of engineered phase change materials to enable sustained temperatures required for nucleic acid amplification. By selecting appropriate exothermic and phase change materials, temperatures can be controlled over a wide range, suitable for various isothermal amplification methods, and maintained for over an hour at an accuracy of +/- 1°C.

Improvement of high temperature fatigue lifetime in AZ91 magnesium alloy by heat treatment

International Nuclear Information System (INIS)

Mokhtarishirazabad, Mehdi; Azadi, Mohammad; Hossein Farrahi, Gholam; Winter, Gerhard; Eichlseder, Wilfred

2013-01-01

In the present paper, an improvement in high temperature fatigue properties of the AZ91 magnesium alloy with rare earth elements has been obtained by a typical heat treatment, denoted by T6. For this objective, out-of-phase thermo-mechanical fatigue, room temperature and high temperature low cycle fatigue tests are performed to compare lifetimes. Several rare earth elements are initially added to the AZ91 alloy during a gravity casting process in permanent molds. Also, the type of the heat treatment is examined. Results of specimens with only the solution (the T4 heat treatment) and the solution with the ageing process (the T6 heat treatment) are compared under isothermal fatigue loadings. Microstructural investigations are carried out, before and after fatigue experiments to demonstrate the heat treatment effect. Results showed that both low cycle fatigue and thermo-mechanical fatigue of the alloy at high temperatures increases tremendously after the T6 heat treatment. This behavior attributes to the variation of the ductility, which was a result of microstructural changes during the heat treatment and the varying temperature in fatigue tests

Improvement of high temperature fatigue lifetime in AZ91 magnesium alloy by heat treatment

Energy Technology Data Exchange (ETDEWEB)

Mokhtarishirazabad, Mehdi [School of Metallurgy and Materials Engineering, Iran University of Science and Technology, Tehran (Iran, Islamic Republic of); Azadi, Mohammad, E-mail: m_azadi@ip-co.com [Fatigue and Wear Workgroup, Irankhodro Powertrain Company (IPCO), Tehran (Iran, Islamic Republic of); Hossein Farrahi, Gholam [School of Mechanical Engineering, Sharif University of Technology, Tehran (Iran, Islamic Republic of); Winter, Gerhard; Eichlseder, Wilfred [Chair of Mechanical Engineering, University of Leoben, Leoben (Austria)

2013-12-20

In the present paper, an improvement in high temperature fatigue properties of the AZ91 magnesium alloy with rare earth elements has been obtained by a typical heat treatment, denoted by T6. For this objective, out-of-phase thermo-mechanical fatigue, room temperature and high temperature low cycle fatigue tests are performed to compare lifetimes. Several rare earth elements are initially added to the AZ91 alloy during a gravity casting process in permanent molds. Also, the type of the heat treatment is examined. Results of specimens with only the solution (the T4 heat treatment) and the solution with the ageing process (the T6 heat treatment) are compared under isothermal fatigue loadings. Microstructural investigations are carried out, before and after fatigue experiments to demonstrate the heat treatment effect. Results showed that both low cycle fatigue and thermo-mechanical fatigue of the alloy at high temperatures increases tremendously after the T6 heat treatment. This behavior attributes to the variation of the ductility, which was a result of microstructural changes during the heat treatment and the varying temperature in fatigue tests.

A design method to isothermalize the core of high-temperature gas-cooled reactors

International Nuclear Information System (INIS)

Takano, M.; Sawa, K.

1987-01-01

A practical design method is developed to isothermalize the core of block-type high-temperature gas-cooled reactors (HTGRs). Isothermalization plays an important role in increasing the design margin on fuel temperature. In this method, the fuel enrichment and the size and boron content of the burnable poison rod are determined over the core blockwise so that the axially exponential and radially flat power distribution are kept from the beginning to the end of core life. The method enables conventional HTGRs to raise the outlet gas temperature without increasing the maximum fuel temperature

Characteristics of turbulent velocity and temperature in a wall channel of a heated rod bundle

Energy Technology Data Exchange (ETDEWEB)

Krauss, T.; Meyer, L. [Forschungszentrum Karlsruhe (Germany)

1995-09-01

Turbulent air flow in a wall sub-channel of a heated 37-rod bundle (P/D = 1.12, W/D = 1.06) was investigated. measurements were performed with hot-wire probe with X-wires and a temperature wire. The mean velocity, the mean fluid temperature, the wall shear stress and wall temperature, the turbulent quantities such as the turbulent kinetic energy, the Reynolds-stresses and the turbulent heat fluxes were measured and are discussed with respect to data from isothermal flow in a wall channel and heated flow in a central channel of the same rod bundle. Also, data on the power spectral densities of the velocity and temperature fluctuations are presented. These data show the existence of large scale periodic fluctuations are responsible for the high intersubchannel heat and momentum exchange.

On a non-linear problem posed by the temperature determination in an electrically heated plate

International Nuclear Information System (INIS)

Gerber, R.

1958-01-01

Let us consider a flat plate, electrically heated, with one face thermally insulated and the other face isothermal. It is shown that a two-dimensional perturbation of the insulated face has no influence on the temperature of this face. (author) [fr

Non-isothermal effects on multi-phase flow in porous medium

DEFF Research Database (Denmark)

Singh, Ashok; Wang, W; Park, C. H.

2010-01-01

In this paper a ppT -formulation for non-isothermal multi-phase flow is given including diffusion and latent heat effects. Temperature and pressure dependencies of governing parameters are considered, in particular surface tension variation on phase interfaces along with temperature changes. A we...

Carbide Precipitation in 2.25 Cr-1 Mo Bainitic Steel: Effect of Heating and Isothermal Tempering Conditions

Science.gov (United States)

Dépinoy, Sylvain; Toffolon-Masclet, Caroline; Urvoy, Stéphane; Roubaud, Justine; Marini, Bernard; Roch, François; Kozeschnik, Ernst; Gourgues-Lorenzon, Anne-Françoise

2017-05-01

The effect of the tempering heat treatment, including heating prior to the isothermal step, on carbide precipitation has been determined in a 2.25 Cr-1 Mo bainitic steel for thick-walled applications. The carbides were identified using their amount of metallic elements, morphology, nucleation sites, and diffraction patterns. The evolution of carbide phase fraction, morphology, and composition was investigated using transmission electron microscopy, X-ray diffraction, as well as thermodynamic calculations. Upon heating, retained austenite into the as-quenched material decomposes into ferrite and cementite. M7C3 carbides then nucleate at the interface between the cementite and the matrix, triggering the dissolution of cementite. M2C carbides precipitate separately within the bainitic laths during slow heating. M23C6 carbides precipitate at the interfaces (lath boundaries or prior austenite grain boundaries) and grow by attracting nearby chromium atoms, which results in the dissolution of M7C3 and, depending on the temperature, coarsening, or dissolution of M2C carbides, respectively.

The effect of inclined vertical slats on natural convective heat transfer from an isothermal heated vertical plate

International Nuclear Information System (INIS)

Oosthuizen, P.H.; Sun, L.; Naylor, D.

2002-01-01

Natural convective heat transfer from a wide heated vertical isothermal plate with adiabatic surfaces above and below the heated surface has been considered. There are a series of equally spaced vertical thin, flat adiabatic surfaces (termed 'slats') near the heated surface, these surfaces being, in general, inclined to the heated surface. The slats are pivoted about their center-point and thus as their angle is changed, the distance of the tip of the slat from the plate changes. The situation considered is an approximate model of a window with a vertical blind, the particular case where the window is hotter than the room air, i.e. where air-conditioning is being used, being considered. The flow has been assumed to be laminar and steady. Fluid properties have been assumed constant except for the density change with temperature that gives rise to the buoyancy forces, this being treated by means of the Biuniqueness type approximation. Although the flow is in general three-dimensional, the flow over each slat is assumed to be the same and attention can therefore be restricted to flow over a single slat by using repeating boundary conditions. The governing equations have been written in dimensionless form and the resulting dimensionless equations have been solved using a commercial finite-element package. The solution has the following parameters: (1) the Rayleigh number (2) the Prandtl number (3) the dimensionless distance of the slat center point (the pivot point) from the surface (4) the dimensionless slat size (5) the dimensionless slat spacing (6) the angle of inclination of the slats. Because of the application that motivated the study, results have only been obtained for a Prandtl number of 0.7. The effect of the other dimensionless variables on the mean dimensionless heat transfer rate from the heated surface has been examined. (author)

Analytical solutions for hydromagnetic natural convection flow of a particulate suspension through isoflux-isothermal channels in the presence of a heat source or sink

International Nuclear Information System (INIS)

Chamkha, Ali J.; Al-Rashidi, Seham S.

2010-01-01

This work considers the problem of steady natural convection hydromagnetic flow of a particulate suspension through an infinitely long channel in the presence of heat generation or absorption effects. The channel walls are maintained at isoflux-isothermal condition. That is, the thermal boundary conditions are such that one of the channel walls is maintained at constant heat flux while the other is maintained at a constant temperature. Various closed-form solutions of the governing equations for different special cases are obtained. A parametric study of the physical parameters involved in the problem is done to illustrate the influence of these parameters on the velocity and temperature profiles of both phases.

Water adsorption isotherms and thermodynamic properties of cassava bagasse

International Nuclear Information System (INIS)

Polachini, Tiago Carregari; Betiol, Lilian Fachin Leonardo; Lopes-Filho, José Francisco; Telis-Romero, Javier

2016-01-01

Highlights: • Adsorption isotherms and composition of cassava bagasse were determined. • GAB equation was the best-fitted model to sorption data of type II isotherm. • Isosteric heat of sorption was calculated in a range of equilibrium moisture content. • Differential enthalpy and entropy confirmed the isokinetic compensation theory. • Water adsorption by cassava bagasse is considered an enthalpy driven process. - Abstract: Losses of food industry are generally wet products that must be dried to posterior use and storage. In order to optimize drying processes, the study of isotherms and thermodynamic properties become essential to understand the water sorption mechanisms of cassava bagasse. For this, cassava bagasse was chemically analyzed and had its adsorption isotherms determined in the range of 293.15–353.15 K through the static gravimetric method. The models of GAB, Halsey, Henderson, Oswin and Peleg were fitted, and best adjustments were found for GAB model with R"2 > 0.998 and no pattern distribution of residual plots. Isosteric heat of adsorption and thermodynamic parameters could be determined as a function of moisture content. Compensation theory was confirmed, with linear relationship between enthalpy and entropy and higher values of isokinetic temperature (T_B = 395.62 K) than harmonic temperature. Water adsorption was considered driven by enthalpy, clarifying the mechanisms of water vapor sorption in cassava bagasse.

High pressure adsorption isotherms of nitrogen onto granular activated carbon for a single bed pressure swing adsorption refrigeration system

Science.gov (United States)

Palodkar, Avinash V.; Anupam, Kumar; Roy, Zunipa; Saha, B. B.; Halder, G. N.

2017-10-01

Adsorption characteristics of nitrogen onto granular activated carbon for the wide range of temperature (303-323 K) and pressure (0.2027-2.0265 MPa) have been reported for a single bed pressure swing adsorption refrigeration system. The experimental data were fitted to Langmuir, Dubinin-Astakhov and Dubinin-Radushkevich (D-R) isotherms. The Langmuir and D-R isotherm models were found appropriate in correlating experimental adsorption data with an average relative error of ±2.0541% and ±0.6659% respectively. The isosteric heat of adsorption data were estimated as a function of surface coverage of nitrogen and temperature using D-R isotherm. The heat of adsorption was observed to decrease from 12.65 to 6.98 kJ.mol-1 with an increase in surface concentration at 303 K and it followed the same pattern for other temperatures. It was found that an increase in temperature enhances the magnitude of the heat of adsorption.

Ice formation in PEM fuel cells operated isothermally at sub-freezing temperatures

Energy Technology Data Exchange (ETDEWEB)

Mukundan, Rangachary [Los Alamos National Laboratory; Luhan, Roger W [Los Alamos National Laboratory; Davey, John R [Los Alamos National Laboratory; Spendelow, Jacob S [Los Alamos National Laboratory; Borup, Rodney L [Los Alamos National Laboratory; Hussey, Daniel S [NIST; Jacobson, David L [NIST; Arif, Muhammad [NIST

2009-01-01

The effect of MEA and GDL structure and composition on the performance of single-PEM fuel cells operated isothermally at subfreezing temperatures is presented. The cell performance and durability are not only dependent on the MEA/GDL materials used but also on their interfaces. When a cell is operated isothermally at sub-freezing temperatures in constant current mode, the water formation due to the current density initially hydrates the membrane/ionomer and then forms ice in the catalyst layer/GDL. An increase in high frequency resistance was also observed in certain MEAs where there is a possibility of ice formation between the catalyst layer and GDL leading to a loss in contact area. The total water/ice holding capacity for any MEA was lower at lower temperatures and higher current densities. The durability of MEAs subjected to multiple isothermal starts was better for LANL prepared MEAs as compared to commercial MEAs, and cloth GDLs when compared to paper GDLs. The ice formation was monitored using high-resolution neutron radiography and was found to be concentrated near the cathode catalyst layer. However, there was significant ice formation in the GDLs especially at the higher temperature ({approx} -10 C) and lower current density (0.02 A/cm{sup 2}) operations. These results are consistent with the longer-term durability observations that show more severe degradation at the lower temperatures.

Method to Predict Tempering of Steels Under Non-isothermal Conditions

Science.gov (United States)

Poirier, D. R.; Kohli, A.

2017-05-01

A common way of representing the tempering responses of steels is with a "tempering parameter" that includes the effect of temperature and time on hardness after hardening. Such functions, usually in graphical form, are available for many steels and have been applied for isothermal tempering. In this article, we demonstrate that the method can be extended to non-isothermal conditions. Controlled heating experiments were done on three grades in order to verify the method.

The use of quasi-isothermal modulated temperature differential scanning calorimetry for the characterization of slow crystallization processes in lipid-based solid self-emulsifying systems.

Science.gov (United States)

Otun, Sarah O; Meehan, Elizabeth; Qi, Sheng; Craig, Duncan Q M

2015-04-01

Slow or incomplete crystallization may be a significant manufacturing issue for solid lipid-based dosage forms, yet little information is available on this phenomenon. In this investigation we suggest a novel means by which slow solidification may be monitored in Gelucire 44/14 using quasi-isothermal modulated temperature DSC (QiMTDSC). Conventional linear heating and cooling DSC methods were employed, along with hot stage microscopy (HSM), for basic thermal profiling of Gelucire 44/14. QiMTDSC experiments were performed on cooling from the melt, using a range of incremental decreases in temperature and isothermal measurement periods. DSC and HSM highlighted the main (primary) crystallization transition; solid fat content analysis and kinetic analysis were used to profile the solidification process. The heat capacity profile from QiMTDSC indicated that after an initial energetic primary crystallisation, the lipid underwent a slower period of crystallization which continued to manifest at much lower temperatures than indicated by standard DSC. We present evidence that Gelucire 44/14 undergoes an initial crystallization followed by a secondary, slower process. QIMTDSC appears to be a promising tool in the investigation of this secondary crystallization process.

Adsorption Isotherms of CH 4 on Activated Carbon from Indonesian Low Grade Coal

KAUST Repository

Martin, Awaludin

2011-03-10

This article presents an experimental approach for the determination of the adsorption isotherms of methane on activated carbon that is essential for methane storage purposes. The experiments incorporated a constant-volume- variable-pressure (CVVP) apparatus, and two types of activated carbon have been investigated, namely, activated carbon derived from the low rank coal of the East of Kalimantan, Indonesia, and a Carbotech activated carbon. The isotherm results which cover temperatures from (300 to 318) K and pressures up to 3.5 MPa are analyzed using the Langmuir, Tóth, and Dubinin-Astakhov (D-A) isotherm models. The heat of adsorption for the single component methane-activated carbon system, which is concentration- and temperature-dependent, is determined from the measured isotherm data. © 2011 American Chemical Society.

On a non-linear problem posed by the temperature determination in an electrically heated plate; Sur un probleme non lineaire pose par la determination de la temperature dans une plaque chauffee electriquement

Energy Technology Data Exchange (ETDEWEB)

Gerber, R [Commissariat a l' Energie Atomique, Saclay (France). Centre d' Etudes Nucleaires

1958-07-01

Let us consider a flat plate, electrically heated, with one face thermally insulated and the other face isothermal. It is shown that a two-dimensional perturbation of the insulated face has no influence on the temperature of this face. (author) [French] Soit une plaque plane, chauffee electriquement, dont une face est isolee thermiquement et l'autre face isotherme. On montre qu'une perturbation bidimensionnelle de la face isolee est sans influence sur la temperature de cette face. (auteur)

Measurement and analysis of adsorption isotherms of CO_2 on activated carbon

International Nuclear Information System (INIS)

Singh, Vinod Kumar; Anil Kumar, E.

2016-01-01

In the present work CO_2 adsorption isotherms of a commercially available activated carbon, Norit Darco type obtained from lignite granular material, were measured. Adsorption isotherms were measured at different temperatures 298 K, 308 K, 318 K and 338 K and over a pressure range of 0–45 bar using Sievert's type experimental setup. Experimental data of CO_2 adsorption isotherms were modelled using Langmuir and Dubinin–Astakhov (D–A) isotherm models. Based on coefficient of correlation and normalized standard deviation it was found that D–A isotherm model was well suited with the experimental data of CO_2 adsorption isotherms. The important thermodynamic properties viz., limiting heat of adsorption at zero coverage, entropy, Gibbs free energy and isosteric heat of adsorption as a function of surface coverage were evaluated using van't Hoff and Clausius–Clapeyron equations. These thermodynamic properties were indicating that CO_2 uptake by activated carbon is a physisorption phenomenon. The adsorption isotherms data and the thermodynamic parameters estimated in the present study are useful for designing of an adsorption based gas storage systems.

Colliding winds: Interaction regions with strong heat conduction

International Nuclear Information System (INIS)

Imamura, J.N.; Chevalier, R.A.

1984-01-01

The interaction of fast stellar wind with a slower wind from previous mass loss gives rise to a region of hot, shocked gas. We obtain self-similar solutions for the interaction region under the assumptions of constant mass loss rate and wind velocity for the two winds, conversion of energy in the shock region, and either isothermal electrons and adiabatic ions or isothermal electrons ad ions in the shocked region. The isothermal assumption is intended to show the effects of strog heat conduction. The solutions have no heat conduction through the shock waves and assume that the electron and ion temperatures are equilibriated in the shock waves. The one-temperature isothermal solutions have nearly constant density through the shocked region, while the two-temperature solutions are intermediate between the one-temperature adiabatic and isothermal solutions. In the two-temperature solutions, the ion temperature goes to zero at the point where the gas comoves with the shocked region and the density peaks at this point. The solution may qualitatively describe the effects of heat conduction on interaction regions in the solar wind. It will be important to determine whether the assumption of no thermal waves outside the shocked region applies to shock waves in the solar wind

Isothermal reaction calorimetry as a tool for kinetic analysis

International Nuclear Information System (INIS)

Zogg, Andreas; Stoessel, Francis; Fischer, Ulrich; Hungerbuehler, Konrad

2004-01-01

Reaction calorimetry has found widespread application for thermal and kinetic analysis of chemical reactions in the context of thermal process safety as well as process development. This paper reviews the most important reaction calorimetric principles (heat-flow, heat-balance, power-compensation, and Peltier principle) and their applications in commercial or scientific devices. The discussion focuses on the different dynamic behavior of the main calorimetric principles during an isothermal reaction measurement. Examples of available reaction calorimeters are further compared considering their detection limit, time constant as well as temperature range. In a second part, different evaluation methods for the isothermally measured calorimetric data are reviewed and discussed. The methods will be compared, focusing especially on the fact that reaction calorimetric data always contains additional informations not directly related to the actual chemical reaction such as heat of mixing, heat of phase-transfer/change processes or simple measurement errors. Depending on the evaluation method applied such disturbances have a significant influence on the calculated reaction enthalpies or rate constants

The kinetic of mass loss of grades A and B of melted TNT by isothermal and non-isothermal gravimetric methods

Directory of Open Access Journals (Sweden)

Hamid Reza Pouretedal

2018-04-01

Full Text Available The kinetic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 °C, respectively, were studied by isothermal and non-isothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 °C. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminum metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30–330 °C at heating rates of 10, 15 and 20 °C⋅min−1. The TG/DTG data were used for determination of activation energy (Ea of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall (OFW and Kissinger-Akahira-Sunose (KAS methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99–120 and 66–70 kJ mol−1, respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade. Keywords: TNT, Isothermal, Non-isothermal, Kinetic, Mass loss

A numerical study on the forced convection heat transfer from an isothermal and isoflux sphere in the steady symmetric flow regime

Energy Technology Data Exchange (ETDEWEB)

Dhole, S.D.; Chhabra, R.P. [Department of Chemical Engineering, Indian Institute of Technology, Kanpur 208 016 (India); Eswaran, V. [Department of Mechanical Engineering, Indian Institute of Technology, Kanpur 208 016 (India)

2006-03-15

The effects of Reynolds and Prandtl numbers on the heat transfer characteristics of an unconfined sphere for different thermal boundary conditions (isothermal and isoflux) on the sphere surface have been investigated numerically by using a finite volume method for the range of conditions as 5=heat transfer correlations are developed for the constant temperature and the constant heat flux boundary conditions on the solid sphere surface in the steady symmetric flow regime. The variation of local Nusselt number on the sphere surface shows the effect of Prandtl number on heat transfer from a sphere in this flow regime. In addition, this work also demonstrates an approach to solve such flow problems using the Cartesian form of the field equations. (author)

Nonequilibrium steady state of biochemical cycle kinetics under non-isothermal conditions

Science.gov (United States)

Jin, Xiao; Ge, Hao

2018-04-01

The nonequilibrium steady state of isothermal biochemical cycle kinetics has been extensively studied, but that under non-isothermal conditions has been much less extensively investigated. When the heat exchange between subsystems is slow, the isothermal assumption of the whole system breaks down, as is true for many types of living organisms. Here, starting with a four-state model of molecular transporter across the cell membrane, we generalize the nonequilibrium steady-state theory of isothermal biochemical cycle kinetics to the circumstances with non-uniform temperatures of subsystems in terms of general master equation models. We obtain a new thermodynamic relationship between the chemical reaction rates and thermodynamic potentials in non-isothermal circumstances, based on the overdamped dynamics along the continuous reaction coordinate. We show that the entropy production can vary up to 3% in real cells, even when the temperature difference across the cell membrane is only approximately 1 K. We then decompose the total thermodynamic driving force into its thermal and chemical components and predict that the net flux of molecules transported by the molecular transporter can potentially go against the temperature gradient in the absence of a chemical driving force. Furthermore, we demonstrate that the simple application of the isothermal transition-state rate formula for each chemical reaction in terms of only the reactant’ temperature is not thermodynamically consistent. Therefore, we mathematically derive several revised reaction rate formulas that are not only consistent with the new thermodynamic relationship but also approximate the exact reaction rate better than Kramers’ rate formula under isothermal conditions.

Effect of Morphological Differences on the Cold Formability of an Isothermally Heat-Treated Advanced High-Strength Steel

Science.gov (United States)

Weißensteiner, Irmgard; Suppan, Clemens; Hebesberger, Thomas; Winkelhofer, Florian; Clemens, Helmut; Maier-Kiener, Verena

2018-04-01

Steel sheets of Fe-0.2C-2Mn-0.2Si-0.03Ti-0.003B (m%) for the automotive industry were isothermally heat-treated, comprising austenitizing and subsequent isothermal annealing at temperatures between 300°C and 500°C. As a consequence, microstructures ranging from granular bainite over lower bainite to auto-tempered and untempered martensite were obtained. In tensile, hole expansion and bending tests, the performances in different forming conditions were compared and the changes of microstructure and texture were studied by complementary electron backscatter diffraction (EBSD) analyses. Samples with granular bainitic microstructures exhibited high total elongations but lower hole expansion ratios; in subsequent EBSD and texture analyses, evidence for inhomogeneous deformation was found. In contrast, the lath-like bainitic/martensitic microstructure showed higher strength and lower elongation to fracture. This results in a reduced bendability, but also in a high tolerance against damage induced by the shearing of edges, and, thus, allows homogeneous deformation to higher strains in the hole expansion test.

Molecular relaxation behavior and isothermal crystallization above glass transition temperature of amorphous hesperetin.

Science.gov (United States)

Shete, Ganesh; Khomane, Kailas S; Bansal, Arvind Kumar

2014-01-01

The purpose of this paper was to investigate the relaxation behavior of amorphous hesperetin (HRN), using dielectric spectroscopy, and assessment of its crystallization kinetics above glass transition temperature (Tg ). Amorphous HRN exhibited both local (β-) and global (α-) relaxations. β-Relaxation was observed below Tg , whereas α-relaxation prominently emerged above Tg . β-Relaxation was found to be of Johari-Goldstein type and was correlated with α-process by coupling model. Secondly, isothermal crystallization experiments were performed at 363 K (Tg + 16.5 K), 373 K (Tg + 26.5 K), and 383 K (Tg + 36.5 K). The kinetics of crystallization, obtained from the normalized dielectric strength, was modeled using the Avrami model. Havriliak-Negami (HN) shape parameters, αHN and αHN .βHN , were analyzed during the course of crystallization to understand the dynamics of amorphous phase during the emergence of crystallites. HN shape parameters indicated that long range (α-like) were motions affected to a greater extent than short range (β-like) motions during isothermal crystallization studies at all temperature conditions. The variable behavior of α-like motions at different isothermal crystallization temperatures was attributed to evolving crystallites with time and increase in electrical conductivity with temperature. © 2013 Wiley Periodicals, Inc. and the American Pharmacists Association.

Critical isothermal temperature and optimum mechanical behaviour of high Si-containing bainitic steels

International Nuclear Information System (INIS)

Misra, A.; Sharma, S.; Sangal, S.; Upadhyaya, A.; Mondal, K.

2012-01-01

The redistribution of carbon during partitioning between retained austenite and bainitic ferrite decides the stability of the retained austenite. The martensitic start temperature (M S ) based on the carbon enriched retained austenite is observed to be the deciding factor for the volume fraction of the constituent phases obtained on isothermal bainitic transformation. The volume fraction of the phases is also calculated on the basis of metastable equi-free energy (T 0 ) curve. A good agreement is found between experimentally and theoretically calculated fractions of the phases. The isothermal holding temperature and time, the fraction of phases based on initial carbon content of the steel and M S temperatures have a close relation with the optimum mechanical properties of bainitic steels.

Critical isothermal temperature and optimum mechanical behaviour of high Si-containing bainitic steels

Energy Technology Data Exchange (ETDEWEB)

Misra, A.; Sharma, S.; Sangal, S.; Upadhyaya, A. [Department of Materials Science and Engineering, Indian Institute of Technology, Kanpur 208016 (India); Mondal, K., E-mail: kallol@iitk.ac.in [Department of Materials Science and Engineering, Indian Institute of Technology, Kanpur 208016 (India)

2012-12-15

The redistribution of carbon during partitioning between retained austenite and bainitic ferrite decides the stability of the retained austenite. The martensitic start temperature (M{sub S}) based on the carbon enriched retained austenite is observed to be the deciding factor for the volume fraction of the constituent phases obtained on isothermal bainitic transformation. The volume fraction of the phases is also calculated on the basis of metastable equi-free energy (T{sub 0}) curve. A good agreement is found between experimentally and theoretically calculated fractions of the phases. The isothermal holding temperature and time, the fraction of phases based on initial carbon content of the steel and M{sub S} temperatures have a close relation with the optimum mechanical properties of bainitic steels.

Temperature stability limits for an isothermal demagnetization refrigerator

Science.gov (United States)

Kittel, P.

1984-01-01

It is pointed out that magnetic refrigeration can provide additional cooling for infrared detectors on space missions, taking into account the Shuttle Infrared Telescope Facility (SIRTF) and the Large Deployable Reflector (LDR). From a temperature of 2 K provided by the primary cryogens, magnetic refrigerators could cool bolometers or pumped photoconductors to 0.1 K or below. Such a reduction in operating temperature would increase the sensitivity for bolometers, while the response at longer wavelengths for pumped photoconductors would be improved. Two types of magnetic refrigeration cycles have been proposed. One type uses a complete demagnetization. The present investigation is concerned with the second type, which uses a feedback-controlled isothermal demagnetization, taking into account the temperature stability limits. Attention is given to control system resolution, thermometer noise, reaction time, and thermal time constants.

Corrosion of Nickel-Based Alloys in Ultra-High Temperature Heat Transfer Fluid

Science.gov (United States)

Wang, Tao; Reddy, Ramana G.

2017-03-01

MgCl2-KCl binary system has been proposed to be used as high temperature reactor coolant. Due to its relatively low melting point, good heat capacity and excellent thermal stability, this system can also be used in high operation temperature concentrating solar power generation system as heat transfer fluid (HTF). The corrosion behaviors of nickel based alloys in MgCl2-KCl molten salt system at 1,000 °C were determined based on long-term isothermal dipping test. After 500 h exposure tests under strictly maintained high purity argon gas atmosphere, the weight loss and corrosion rate analysis were conducted. Among all the tested samples, Ni-201 demonstrated the lowest corrosion rate due to the excellent resistance of Ni to high temperature element dissolution. Detailed surface topography and corrosion mechanisms were also determined by using scanning electron microscopy (SEM) equipped with energy dispersive spectrometer (EDS).

Production of valuable pyrolytic oils from mixed Municipal Solid Waste (MSW in Indonesia using non-isothermal and isothermal experimental

Directory of Open Access Journals (Sweden)

Indra Mamad Gandidi

2017-09-01

Full Text Available Municipal solid waste (MSW, disposed of at open dumping sites, poses health risks, contaminates surface water, and releases greenhouse gasses such as methane. However, pyrolysis offers the opportunity to convert MSW into Bio-Oil (BO for clean energy resource. In this paper, an MSW sample consisting of plastic, paper and cardboard, rubber and textiles, and vegetable waste is pyrolysed on a laboratory scale in a fixed-bed vacuum reactor. In the non-isothermal process, the sample was fed into the reactor and then heated. In the isothermal process, the reactor is first heated and then the sample is added. The non-isothermal process created greater BO in both quality and quantity. The BO had a larger amount of gasoline species than diesel-48 fuel, with at 33.44%the BO produced by isothermal pyrolysis and 36.42% in non-isothermal pyrolysis. However the product of isothermal pyrolysis had a higher acid content that reduced its heating value.

Heat capacity and transition behavior of sucrose by standard, fast scanning and temperature-modulated calorimetry

Energy Technology Data Exchange (ETDEWEB)

Magoń, A. [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland); Wurm, A.; Schick, C. [Department of Physics, University of Rostock, 18057 Rostock (Germany); Pangloli, Ph.; Zivanovic, S. [Department of Food Science and Technology, University of Tennessee, Knoxville, TN 37996 (United States); Skotnicki, M. [Department of Pharmaceutical Technology, Poznan University of Medical Sciences, 60-780 Poznań (Poland); Pyda, M., E-mail: mpyda@utk.edu [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland)

2014-08-10

Highlights: • Experimental, apparent heat capacity of sucrose was investigated by advanced thermal analysis. • Vibrational heat capacity of solid state was linked with a low temperature experimental heat capacity of sucrose. • Equilibrium melting parameters of sucrose were determined. • Decomposition, superheating of crystalline sucrose during melting process were presented. • TGA, DSC, TMDSC, and FSC are useful tools for characterization of sucrose. - Abstract: The heat capacity (C{sub p}) of crystalline and amorphous sucrose was determined using standard and quasi-isothermal temperature modulated differential scanning calorimetry. The results were combined with the published data determined by adiabatic calorimetry, and the C{sub p} values are now reported for the wide 5–600 K range. The experimental C{sub p} of solid sucrose at 5–300 K was used to calculate the vibrational, solid C{sub p} based on the vibrational molecular motions. The calculated solid and liquid C{sub p} together with the transition parameters for equilibrium conditions were used as references for detailed quantitative thermal analysis of crystalline and amorphous sucrose. Melting temperature (T{sub m}) of the crystalline sucrose was identified in a broad 442–465 K range with a heat of fusion of 40–46 J/mol determined at heating rates 0.5–20 K/min, respectively. The equilibrium T{sub m} and heat of fusion of crystalline sucrose were estimated at zero heating rate as T{sup o}{sub m} = 424.4 K and ΔH{sup o}{sub f} = 32 kJ/mol, respectively. The glass transition temperature (T{sub g}) of amorphous sucrose was at 331 K with a change in C{sub p} of 267 J/(mol K) as it was estimated from reversing heat capacity by quasi-isothermal TMDSC on cooling. At heating rates less than 30 K/min, thermal decomposition occurred during melting, while at extreme rate of 1000 K/s, degradation was not observed. Data obtained by fast scanning calorimetry (FSC) at 1000 K/s, showed that T{sub m} was

Loop-Mediated Isothermal Amplification Using a Lab-on-a-Disc Device with Thin-film Phase Change Material.

Science.gov (United States)

Ko, Junguk; Yoo, Jae-Chern

2018-03-05

The design and fabrication of temperature measurement systems that facilitate successful realization of DNA amplification using a lab-on-a-disc (LOD) device are a highly challenging task. The major challenge lies in the fact that such a system must be directly attached to a heating chamber in a way that enables the accurate measurement of temperature of the chamber while allowing the LOD to rotate. This paper presents a temperature control system for implementing isothermal amplification of DNA samples using an LOD device. The proposed system utilizes a thin-film phase change material and non-contact heating system to remotely measure the actual temperature of the chamber and, if required, rapidly heat it to the desired temperature. The results of the experiments performed in this study demonstrate that the proposed system provides an automated platform for molecular amplification and exhibits an operational performance comparable to that of traditional microcentrifuge tube-based isothermal amplification systems.

Force Field Benchmark of the TraPPE_UA for Polar Liquids: Density, Heat of Vaporization, Dielectric Constant, Surface Tension, Volumetric Expansion Coefficient, and Isothermal Compressibility.

Science.gov (United States)

Núñez-Rojas, Edgar; Aguilar-Pineda, Jorge Alberto; Pérez de la Luz, Alexander; de Jesús González, Edith Nadir; Alejandre, José

2018-02-08

The transferable potential for a phase equilibria force field in its united-atom version, TraPPE_UA, is evaluated for 41 polar liquids that include alcohols, thiols, ethers, sulfides, aldehydes, ketones, and esters to determine its ability to reproduce experimental properties that were not included in the parametrization procedure. The intermolecular force field parameters for pure components were fit to reproduce experimental boiling temperature, vapor-liquid coexisting densities, and critical point (temperature, density, and pressure) using Monte Carlo simulations in different ensembles. The properties calculated in this work are liquid density, heat of vaporization, dielectric constant, surface tension, volumetric expansion coefficient, and isothermal compressibility. Molecular dynamics simulations were performed in the gas and liquid phases, and also at the liquid-vapor interface. We found that relative error between calculated and experimental data is 1.2% for density, 6% for heat of vaporization, and 6.2% for surface tension, in good agreement with the experimental data. The dielectric constant is systematically underestimated, and the relative error is 37%. Evaluating the performance of the force field to reproduce the volumetric expansion coefficient and isothermal compressibility requires more experimental data.

Effect of thymol in heating and recovery media on the isothermal and non-isothermal heat resistance of Bacillus spores.

Science.gov (United States)

Esteban, Maria-Dolores; Conesa, Raquel; Huertas, Juan-Pablo; Palop, Alfredo

2015-06-01

Members of the genus Bacillus include important food-borne pathogen and spoilage microorganisms for food industry. Essential oils are natural products extracted from herbs and spices, which can be used as natural preservatives in many foods because of their antibacterial, antifungal, antioxidant and anti-carcinogenic properties. The aim of this research was to explore the effect of the addition of different concentrations of thymol to the heating and recovery media on the thermal resistance of spores of Bacillus cereus, Bacillus licheniformis and Bacillus subtilis at different temperatures. While the heat resistance was hardly reduced when thymol was present in the heating medium, the effect in the recovery medium was greater, reducing the D100 °C values down to one third for B. subtilis and B. cereus when 0.5 mM thymol was added. This effect was dose dependent and was also observed at other heating temperatures. Copyright © 2014 Elsevier Ltd. All rights reserved.

Non-isothermal modelling of the all-vanadium redox flow battery

International Nuclear Information System (INIS)

Al-Fetlawi, H.; Shah, A.A.; Walsh, F.C.

2009-01-01

An non-isothermal model for the all-vanadium redox flow battery (RFB) is presented. The two-dimensional model is based on a comprehensive description of mass, charge, energy and momentum transport and conservation, and is combined with a global kinetic model for reactions involving vanadium species. Heat is generated as a result of activation losses, electrochemical reaction and ohmic resistance. Numerical simulations demonstrate the effects of changes in the operating temperature on performance. It is shown that variations in the electrolyte flow rate and the magnitude of the applied current substantially alter the charge/discharge characteristics, the temperature rise and the distribution of temperature. The influence of heat losses on the charge/discharge behaviour and temperature distribution is investigated. Conditions for localised heating and membrane degradation are discussed.

Non-isothermal decomposition kinetics, heat capacity and thermal safety of 37.2/44/16/2.2/0.2/0.4-GAP/CL-20/Al/N-100/PCA/auxiliaries mixture

International Nuclear Information System (INIS)

Zhang, Jiao-Qiang; Gao, Hong-Xu; Ji, Tie-Zheng; Xu, Kang-Zhen; Hu, Rong-Zu

2011-01-01

Highlights: → Non-isothermal decomposition kinetics, heat capacity and thermal safety on 37.2/44/16/2.2/0.2/0.4-GAP/CL-20/Al/N-100/PCA/auxiliaries mixture. → Apparent activation energy and pre-exponential constant obtained. → Thermal explosion temperature, adiabatic time-to-explosion, 50% drop height of impact sensitivity, and critical temperature of hot-spot initiation calculated. - Abstract: The specific heat capacity (C p ) of 37.2/44/16/2.2/0.2/0.4-GAP/CL-20/Al/N-100/PCA/auxiliaries mixture was determined with the continuous C p mode of microcalorimeter. The equation of C p with temperature was obtained. The standard molar heat capacity of GAP/CL-20/Al/N-100/PCA/auxiliaries mixture was 1.225 J mol -1 K -1 at 298.15 K. With the help of the peak temperature (T p ) from the non-isothermal DTG curves of the mixture at different heating rates (β), the apparent activation energy (E k and E o ) and pre-exponential constant (A K ) of thermal decomposition reaction obtained by Kissinger's method and Ozawa's method. Using density (ρ) and thermal conductivity (λ), the decomposition heat (Q d , taking half-explosion heat), Zhang-Hu-Xie-Li's formula, the values (T e0 and T p0 ) of T e and T p corresponding to β → 0, thermal explosion temperature (T be and T bp ), adiabatic time-to-explosion (t TIad ), 50% drop height (H 50 ) of impact sensitivity, and critical temperature of hot-spot initiation (T cr,hotspot ) of thermal explosion of the mixture were calculated. The following results of evaluating the thermal safety of the mixture were obtained: T be = 441.64 K, T bp = 461.66 K, t Tlad = 78.0 s (n = 2), t Tlad = 74.87s (n = 1), t Tlad = 71.85 s (n = 0), H 50 = 21.33 cm.

Performance of tubes-and plate fins heat exchangers

International Nuclear Information System (INIS)

Rosman, E.C.

1979-11-01

By means of a two-dimensional analysis performance, and using local heat transfer coefficients, the plate fin temperature distribution, the air bulk temperature along the stream path and the fin efficiency can be obtained, for several Reynolds numbers and fin materials. Herein are also presented the average heat transfer coefficients for isothermal plate fins, referring to heat exchangers with central-tube and rear-tube row and to two-row tubes heat exchangers configurations. It is possible to obtain the real tax or the real area of heat transfer, using the average hea transfer coefficients for isothermal plate fins and the fin efficiency. (Author) [pt

Modelling for Temperature Non-Isothermal Continuous Stirred Tank Reactor Using Fuzzy Logic

OpenAIRE

Nasser Mohamed Ramli; Mohamad Syafiq Mohamad

2017-01-01

Many types of controllers were applied on the continuous stirred tank reactor (CSTR) unit to control the temperature. In this research paper, Proportional-Integral-Derivative (PID) controller are compared with Fuzzy Logic controller for temperature control of CSTR. The control system for temperature non-isothermal of a CSTR will produce a stable response curve to its set point temperature. A mathematical model of a CSTR using the most general operating condition was developed through a set of...

Oscillations of non-isothermal N/S boundary with a high frequency and large amplitude

International Nuclear Information System (INIS)

Bezuglyj, A.I.; Shklovskij, V.A.

2016-01-01

Within the framework of the phenomenological approach based on the heat balance equation and the dependence of the critical temperature of the superconductor on the current value theoretically investigated the impact of high-frequency current of high amplitude and arbitrary shape on the non-isothermal balance of the oscillating N/S interface in a long superconductor. We introduce a self-consistent average temperature field of rapidly oscillating non-isothermal N/S boundary (heat kink), which allows to go beyond the well-known concept of mean-square heating and consider the impact of current waveform. With regard to experiments on the effects of microwave high-power radiation on the current-voltage characteristics (CVC) of superconducting films, we give the classification of the families of the CVC for inhomogeneous superconductors which carry a current containing a high frequency component of large amplitude. Several characteristics have hysteresis of thermal nature.

A study of the water vapor sorption isotherms of hardened cement pastes: Possible pore structure changes at low relative humidity and the impact of temperature on isotherms

DEFF Research Database (Denmark)

Wu, Min; Johannesson, Björn; Geiker, Mette Rica

2014-01-01

cement paste samples and a model material MCM-41. The pronounced impact of temperature on desorption isotherms of cement based materials as reported in literature was not found in this investigation. The results suggest that the differences between the sorption isotherms measured at different...

Resistivity behavior in isothermal annealing of Pd-H(D) alloys around 50 K

International Nuclear Information System (INIS)

Yamakawa, Kohji; Maeta, Hiroshi

2004-01-01

The behavior of electrical resistivity during hydrogen (deuterium) ordering is investigated for Pd-H(D) alloys of various hydrogen concentrations around 50 K. The disordered hydrogen (deuterium) atoms are introduced by quenching from 100 K into liquid helium immediately before isothermal annealings. The disordered atoms order by migration of the atoms during the heating-up of the specimens. On the isothermal curves of the resistivity in the high temperature range, the resistivity increases at first and then adopts a constant value dependent on the annealing temperature. On the other hand, the resistivity increases and then decreases during isothermal annealing in the low temperature range, nevertheless the ordering is progressing. The annealing time, at which the resistivity maximum appears, and the resistivity value of the maximum increase with decreasing annealing temperature. Furthermore, the decreasing resistivity after the maximum saturates to a value dependent on each annealing temperature. Therefore, it becomes clear that an equilibrium amount of ordering depends on the temperature and the resistivity increases in the early stage of hydrogen (deuterium) ordering and decreases in the later stage. The resistivity maximum in the isothermal annealing curve is caused by the nucleation and growth of ordered domains of hydrogen (deuterium) atoms

Effect of the isothermal transformation temperature on the fine structure of steel-12Kh1MF

International Nuclear Information System (INIS)

Mints, I.I.; Berezina, T.G.; Lanskaya, K.A.

1976-01-01

For detailed analysis of bainite and pearlite in steel 12Kh1MF, homogeneous structures were obtained by isothermal annealing at 350, 450, 500, and 650 0 for 1 h. Isothermal transformation of austenite leads to the formation of bainite at 350-500 0 and pearlite at 650 0 . The austenitizing temperature was 980 0 for both types of samples, with holding for 20 min. For comparison, the plates were quenched from 980 0 and 1050 0 in ice-cold brine. The investigation was conducted with use of light and electron microscopes and x-ray analysis. The long-term strength was also determined. Isothermal treatment of steel 12Kh1MF at 350-500 0 C leads to the formation of a structure consisting of upper and lower bainite. At 500 0 the structure consists primarily of upper bainite, and at 350 0 of lower bainite. With tempering of the steel with a structure of upper and lower bainite at 730 0 for 3 h the dislocations undergo redistribution of the polygonization type within ferrite needles, with development of a cellular substructure. The acicular structure of the matrix is retained in this case. The density and evenness of the distribution of carbides is higher in upper bainite than in lower bainite. Steel 12Kh1MF with a structure of upper bainite is more susceptible to recrystallization as compared with a structure of lower bainite, which is responsible for the higher heat resistance of the latter

Thermistor based, low velocity isothermal, air flow sensor

International Nuclear Information System (INIS)

Cabrita, Admésio A C M; Mendes, Ricardo; Quintela, Divo A

2016-01-01

The semiconductor thermistor technology is applied as a flow sensor to measure low isothermal air velocities (<2 ms −1 ). The sensor is subjected to heating and cooling cycles controlled by a multifunctional timer. In the heating stage, the alternating current of a main AC power supply source guarantees a uniform thermistor temperature distribution. The conditioning circuit assures an adequate increase of the sensors temperature and avoids the thermal disturbance of the flow. The power supply interruption reduces the consumption from the source and extends the sensors life time. In the cooling stage, the resistance variation of the flow sensor is recorded by the measuring chain. The resistive sensor parameters proposed vary significantly and feature a high sensitivity to the flow velocity. With the aid of a computer, the data transfer, storage and analysis provides a great advantage over the traditional local anemometer readings. The data acquisition chain has a good repeatability and low standard uncertainties. The proposed method measures isothermal air mean velocities from 0.1 ms −1 to 2 ms −1 with a standard uncertainty error less than 4%. (paper)

Investigation of heat flux processes governing the increase of groundwater temperatures beneath cities

Science.gov (United States)

Bayer, P.; Menberg, K.; Zhu, K.; Blum, P.

2012-12-01

In the subsurface of many cities there are widespread and persistent thermal anomalies. These so-called subsurface urban heat islands (UHIs), which also stimulate warming of urban aquifers, are triggered by various processes. Possible heat sources are basements of buildings, leakage of sewage systems, buried district heating networks, re-injection of cooling water and solar irradiation on paved surfaces. In the current study, the reported groundwater temperatures in several Central European cities, such as Berlin, Cologne (Germany) and Zurich (Switzerland) are compared. Available data sets are supplemented by temperature measurements and depth profiles in observation wells. Trend analyses are conducted with time series of groundwater temperatures, and three-dimensional groundwater temperature maps are provided. In all investigated cities, pronounced positive temperature anomalies are present. The distribution of groundwater temperatures appears to be spatially and temporally highly variable. Apparently, the increased heat input into the urban subsurface is controlled by very local and site-specific parameters. In the long-run, the combination of various heat sources results in an extensive temperature increase. In many cases, the maximum temperature elevation is found close to the city center. Regional groundwater temperature differences between the city center and the rural background are up to 5 °C, with local hot spots of even more pronounced anomalies. Particular heat sources, like cooling water injections or case-specific underground constructions, can cause local temperatures > 20 °C in the subsurface. Examination of the long-term variations in isotherm maps shows that temperatures have increased by about 1 °C in the city, as well as in the rural background areas over the last decades. This increase could be reproduced with trend analysis of temperature data gathered from several groundwater wells. Comparison between groundwater and air temperatures in the

Isothermal transitions of a thermosetting system

Science.gov (United States)

Gillham, J. K.; Benci, J. A.; Noshay, A.

1974-01-01

A study of the curing reactions of a cycloaliphatic epoxy resin/anhydride system by torsional braid analysis showed the existence of two critical isothermal temperatures - namely, the maximum glass transition temperature of the thermoset system and the glass transition temperature of the material at its gel point. Two rheologically active kinetic transitions occur during isothermal cure which correspond to gelation and vitrification. Three types of isothermal behavior occur. Methods for determining the time to gel and the time to vitrify, and also the two above-mentioned critical isothermal temperatures, have been developed. The time to gel obeyed the Arrhenius relationship, whereas the time to vitrify passed through a minimum. Application of these results to thermosetting systems in general is discussed in terms of the influence of molecular structure on the values of the critical isothermal temperatures.

WATER ADSORPTION AND DESORPTION ISOTHERMS ON MILK POWDER: II. WHOLE MILK

Directory of Open Access Journals (Sweden)

Edgar M. Soteras

2014-03-01

Full Text Available The aim of this research was the determination of adsorption and desorption isotherms of cow whole milk powder. The experiments have been carried out at 15, 25 and 40 ºC, in ranges of moisture and water activity characteristic of normal conditions in which the processes of drying, packaging and storage are developed. By studying the influence of the temperature on the experimental plots, the isosteric adsorption heat was determined. Experimental data were correlated to the referential model of Guggenheim, Anderson and Boer (GAB. For both, adsorption and desorption, a good model fit was observed. The isotherms showed very similar shapes between them and, by comparing adsorption and desorption isotherms, the phenomenon of hysteresis was confirmed.

Controlled Microwave Heating Accelerates Rolling Circle Amplification.

Directory of Open Access Journals (Sweden)

Takeo Yoshimura

Full Text Available Rolling circle amplification (RCA generates single-stranded DNAs or RNA, and the diverse applications of this isothermal technique range from the sensitive detection of nucleic acids to analysis of single nucleotide polymorphisms. Microwave chemistry is widely applied to increase reaction rate as well as product yield and purity. The objectives of the present research were to apply microwave heating to RCA and indicate factors that contribute to the microwave selective heating effect. The microwave reaction temperature was strictly controlled using a microwave applicator optimized for enzymatic-scale reactions. Here, we showed that microwave-assisted RCA reactions catalyzed by either of the four thermostable DNA polymerases were accelerated over 4-folds compared with conventional RCA. Furthermore, the temperatures of the individual buffer components were specifically influenced by microwave heating. We concluded that microwave heating accelerated isothermal RCA of DNA because of the differential heating mechanisms of microwaves on the temperatures of reaction components, although the overall reaction temperatures were the same.

Controlled Microwave Heating Accelerates Rolling Circle Amplification.

Science.gov (United States)

Yoshimura, Takeo; Suzuki, Takamasa; Mineki, Shigeru; Ohuchi, Shokichi

2015-01-01

Rolling circle amplification (RCA) generates single-stranded DNAs or RNA, and the diverse applications of this isothermal technique range from the sensitive detection of nucleic acids to analysis of single nucleotide polymorphisms. Microwave chemistry is widely applied to increase reaction rate as well as product yield and purity. The objectives of the present research were to apply microwave heating to RCA and indicate factors that contribute to the microwave selective heating effect. The microwave reaction temperature was strictly controlled using a microwave applicator optimized for enzymatic-scale reactions. Here, we showed that microwave-assisted RCA reactions catalyzed by either of the four thermostable DNA polymerases were accelerated over 4-folds compared with conventional RCA. Furthermore, the temperatures of the individual buffer components were specifically influenced by microwave heating. We concluded that microwave heating accelerated isothermal RCA of DNA because of the differential heating mechanisms of microwaves on the temperatures of reaction components, although the overall reaction temperatures were the same.

Impact of Isothermal Aging and Testing Temperature on Large Flip-Chip BGA Interconnect Mechanical Shock Performance

Science.gov (United States)

Lee, Tae-Kyu; Chen, Zhiqiang; Guirguis, Cherif; Akinade, Kola

2017-10-01

The stability of solder interconnects in a mechanical shock environment is crucial for large body size flip-chip ball grid array (FCBGA) electronic packages. Additionally, the junction temperature increases with higher electric power condition, which brings the component into an elevated temperature environment, thus introducing another consideration factor for mechanical stability of interconnection joints. Since most of the shock performance data available were produced at room temperature, the effect of elevated temperature is of interest to ensure the reliability of the device in a mechanical shock environment. To achieve a stable␣interconnect in a dynamic shock environment, the interconnections must tolerate mechanical strain, which is induced by the shock wave input and reaches the particular component interconnect joint. In this study, large body size (52.5 × 52.5 mm2) FCBGA components assembled on 2.4-mm-thick boards were tested with various isothermal pre-conditions and testing conditions. With a heating element embedded in the test board, a test temperature range from room temperature to 100°C was established. The effects of elevated temperature on mechanical shock performance were investigated. Failure and degradation mechanisms are identified and discussed based on the microstructure evolution and grain structure transformations.

High temperature diffusion induced liquid phase joining of a heat resistant alloy

International Nuclear Information System (INIS)

Wikstrom, N.P.; Egbewande, A.T.; Ojo, O.A.

2008-01-01

Transient liquid phase bonding (TLP) of a nickel base superalloy, Waspaloy, was performed to study the influence of holding time and temperature on the joint microstructure. Insufficient holding time for complete isothermal solidification of liquated insert caused formation of eutectic-type microconstituent along the joint centerline region in the alloy. In agreement with prediction by conventional TLP diffusion models, an increase in bonding temperature for a constant gap size, resulted in decrease in the time, t f, required to form a eutectic-free joint by complete isothermal solidification. However, a significant deviation from these models was observed in specimens bonded at and above 1175 deg. C. A reduction in isothermal solidification rate with increased temperature was observed in these specimens, such that a eutectic-free joint could not be achieved by holding for a time period that produced complete isothermal solidification at lower temperatures. Boron-rich particles were observed within the eutectic that formed in the joints prepared at the higher temperatures. An overriding effect of decrease in boron solubility relative to increase in its diffusivity with increase in temperature, is a plausible important factor responsible for the reduction in isothermal solidification rate at the higher bonding temperatures

Isothermal and non-isothermal cure of a tri-functional epoxy resin (TGAP): a stochastic TMDSC study

OpenAIRE

Hutchinson, John M.; Shiravand, Fatemeh; Calventus Solé, Yolanda; Fraga Rivas, Iria

2012-01-01

The isothermal cure of a highly reactive tri-functional epoxy resin, tri-glycidyl para-amino phenol (TGAP), with diamino diphenyl sulphone (DDS), at two different cure temperatures Tc has been studied by both conventional differential scanning calorimetry (DSC) and by a stochastic temperature modulated DSC technique, TOPEM. From a series of isothermal cure experiments for increasing cure times, the glass transition temperature Tg as a function of isothermal cure time is determined by co...

The temperature dependence of the isothermal bulk modulus at 1 bar pressure

International Nuclear Information System (INIS)

Garai, J.; Laugier, A.

2007-01-01

It is well established that the product of the volume coefficient of thermal expansion and the bulk modulus is nearly constant at temperatures higher than the Debye temperature. Using this approximation allows predicting the values of the bulk modulus. The derived analytical solution for the temperature dependence of the isothermal bulk modulus has been applied to ten substances. The good correlations to the experiments indicate that the expression may be useful for substances for which bulk modulus data are lacking

The Use of Quasi-Isothermal Modulated Temperature Differential Scanning Calorimetry for the Characterization of Slow Crystallization Processes in Lipid-Based Solid Self-Emulsifying Systems

OpenAIRE

Otun, Sarah O.; Meehan, Elizabeth; Qi, Sheng; Craig, Duncan Q. M.

2014-01-01

Purpose Slow or incomplete crystallization may be a significant manufacturing issue for solid lipid-based dosage forms, yet little information is available on this phenomenon. In this investigation we suggest a novel means by which slow solidification may be monitored in Gelucire 44/14 using quasi-isothermal modulated temperature DSC (QiMTDSC). Methods Conventional linear heating and cooling DSC methods were employed, along with hot stage microscopy (HSM), for basic thermal profiling of Geluc...

Feasibility of Ericsson type isothermal expansion/compression gas turbine cycle for nuclear energy use

International Nuclear Information System (INIS)

Shimizu, Akihiko

2007-01-01

A gas turbine with potential demand for the next generation nuclear energy use such as HTGR power plants, a gas cooled FBR, a gas cooled nuclear fusion reactor uses helium as working gas and with a closed cycle. Materials constituting a cycle must be set lower than allowable temperature in terms of mechanical strength and radioactivity containment performance and so expansion inlet temperature is remarkably limited. For thermal efficiency improvement, isothermal expansion/isothermal compression Ericsson type gas turbine cycle should be developed using wet surface of an expansion/compressor casing and a duct between stators without depending on an outside heat exchanger performing multistage re-heat/multistage intermediate cooling. Feasibility of an Ericsson cycle in comparison with a Brayton cycle and multi-stage compression/expansion cycle was studied and technologies to be developed were clarified. (author)

Water sorption isotherms of skimmed milk powder within the temperature range of 5–20 °C

Directory of Open Access Journals (Sweden)

Jitka Langová

2012-01-01

Full Text Available Moisture sorption isotherms (MSI’s of skimmed milk powder in the temperature range of 5–20 °C were determined using manometric method. MSI’s, which show the water content versus water activity (Aw at a constant temperature, are used to describe relationships between water content and equilibrium state relative vapour pressure (RVP. The equilibrium moisture content (EMC of skimmed milk powder samples is growing with an increase of Aw at a constant temperature both for water adsorption and desorption. Isotherms were found to be type II of Brunauer-Emmett-Teller classification. It is the type most common for foods. The shape of created isotherms was sigmoid. Structural modifications of crystals were observed during adsorption in the microscope, too. Critical value of EMC of tested samples corresponding to the Aw equal to 0.6 for adsorption was 6.50% MC (w.b. at temperature 5 °C, 9.15% MC (w.b. at temperature 10 °C, and 7.71% MC (w.b. at temperature 20 °C. These values determine optimal conditions for storage from the point of view microorganisms grow, Aw<0.6.

Isothermal and non-isothermal conditions of isotope separation by chemical exchange method

International Nuclear Information System (INIS)

Khoroshilov, A.V.; Andreev, B.M.; Katalnikov, S.G.

1992-01-01

The published data about the effect of temperature on thermodynamic and mass transfer parameters of isotope separation by the chemical exchange method were used to examine the influence of iso- and non-isothermal conditions on the effectiveness of the separation process. It has been shown that simultaneous fulfillment of several optimization criteria is impossible in optimization of the isothermal process. If the limitation that temperature must be constant in the whole range of concentrational changes for an isolated isotope is removed, then it is possible to solve the problem of optimization with simultaneous fulfillment of several optimization criteria. When the separation process is carried out with non-isothermal conditions, that is, in temperature cascade, then the maximum concentration change takes place at every theoretical separation plate, and whole cascade is characterised by maximum throughput, minimum height and volume, and minimum cost for the stream reflux. From the results of our study, it was concluded that in the optimum temperature cascade, the cost of production of unity quantity of isotope can be decreased at least by a factor of two as compared with the optimal isothermal version of the separation process. (author)

Determining the baking isotherm temperature of Söderberg electrodes and associated structural changes

OpenAIRE

Shoko, L.; Beukes, J.P.; Strydom, C.A.

2013-01-01

One of the most commonly employed electrode systems in industrial metal smelting applications is continuous self-baking electrodes, i.e. the Söderberg electrode system. In this system, the temperature at which transition from a liquid/soft paste to a solid carbonaceous electrode takes place is termed the baking isotherm temperature. This temperature is extremely important within the context of electrode management. In this paper, thermo mechanical analysis (TMA) was used to measure the dimens...

Reprint of “Heat capacity and transition behavior of sucrose by standard, fast scanning and temperature-modulated calorimetry”

Energy Technology Data Exchange (ETDEWEB)

Magoń, A. [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland); Wurm, A.; Schick, C. [Department of Physics, University of Rostock, 18057 Rostock (Germany); Pangloli, Ph.; Zivanovic, S. [Department of Food Science and Technology, University of Tennessee, Knoxville, TN 37996 (United States); Skotnicki, M. [Department of Pharmaceutical Technology, Poznan University of Medical Sciences, 60-780 Poznań (Poland); Pyda, M., E-mail: mpyda@utk.edu [Department of Chemistry, University of Technology, 35-959 Rzeszów (Poland)

2015-03-10

Highlights: • Experimental, apparent heat capacity of sucrose was investigated by advanced thermal analysis. • Vibrational heat capacity of solid state was linked with a low temperature experimental heat capacity of sucrose. • Equilibrium melting parameters of sucrose were determined. • Decomposition, superheating of crystalline sucrose during melting process were presented. • TGA, DSC, TMDSC, and FSC are useful tools for characterization of sucrose. - Abstract: The heat capacity (C{sub p}) of crystalline and amorphous sucrose was determined using standard and quasi-isothermal temperature modulated differential scanning calorimetry. The results were combined with the published data determined by adiabatic calorimetry, and the C{sub p} values are now reported for the wide 5–600 K range. The experimental C{sub p} of solid sucrose at 5–300 K was used to calculate the vibrational, solid C{sub p} based on the vibrational molecular motions. The calculated solid and liquid C{sub p} together with the transition parameters for equilibrium conditions were used as references for detailed quantitative thermal analysis of crystalline and amorphous sucrose. Melting temperature (T{sub m}) of the crystalline sucrose was identified in a broad 442–465 K range with a heat of fusion of 40–46 J/mol determined at heating rates 0.5–20 K/min, respectively. The equilibrium T{sub m} and heat of fusion of crystalline sucrose were estimated at zero heating rate as T{sup o}{sub m} = 424.4 K and ΔH{sup o}{sub f} = 32 kJ/mol, respectively. The glass transition temperature (T{sub g}) of amorphous sucrose was at 331 K with a change in C{sub p} of 267 J/(mol K) as it was estimated from reversing heat capacity by quasi-isothermal TMDSC on cooling. At heating rates less than 30 K/min, thermal decomposition occurred during melting, while at extreme rate of 1000 K/s, degradation was not observed. Data obtained by fast scanning calorimetry (FSC) at 1000 K/s, showed that T{sub m} was

Model-free method for isothermal and non-isothermal decomposition kinetics analysis of PET sample

International Nuclear Information System (INIS)

Saha, B.; Maiti, A.K.; Ghoshal, A.K.

2006-01-01

Pyrolysis, one possible alternative to recover valuable products from waste plastics, has recently been the subject of renewed interest. In the present study, the isoconversion methods, i.e., Vyazovkin model-free approach is applied to study non-isothermal decomposition kinetics of waste PET samples using various temperature integral approximations such as Coats and Redfern, Gorbachev, and Agrawal and Sivasubramanian approximation and direct integration (recursive adaptive Simpson quadrature scheme) to analyze the decomposition kinetics. The results show that activation energy (E α ) is a weak but increasing function of conversion (α) in case of non-isothermal decomposition and strong and decreasing function of conversion in case of isothermal decomposition. This indicates possible existence of nucleation, nuclei growth and gas diffusion mechanism during non-isothermal pyrolysis and nucleation and gas diffusion mechanism during isothermal pyrolysis. Optimum E α dependencies on α obtained for non-isothermal data showed similar nature for all the types of temperature integral approximations

Experimental Adsorption Isotherm of Methane onto Activated Carbon at Sub- and Supercritical Temperatures

KAUST Repository

Rahman, Kazi Afzalur; Loh, Wai Soong; Yanagi, Hideharu; Chakraborty, Anutosh; Saha, Bidyut Baran; Chun, Won Gee; Ng, Kim Choon

2010-01-01

This paper presents the experimentally measured adsorption isotherm data for methane onto the pitch-based activated carbon type Maxsorb III for temperatures ranging from (120 to 220) K and pressures up to 1.4 MPa. These data are useful to study

Effects of Pressure, Temperature, Treatment Time, and Storage on Rheological, Textural, and Structural Properties of Heat-Induced Chickpea Gels

Directory of Open Access Journals (Sweden)

María Dolores Alvarez

2015-04-01

Full Text Available Pressure-induced gelatinization of chickpea flour (CF was studied in combination with subsequent temperature-induced gelatinization. CF slurries (with 1:5 flour-to-water ratio and CF in powder form were treated with high hydrostatic pressure (HHP, temperature (T, and treatment time (t at three levels (200, 400, 600 MPa; 10, 25, 50 °C; 5, 15, 25 min. In order to investigate the effect of storage (S, half of the HHP-treated CF slurries were immediately analyzed for changes in oscillatory rheological properties under isothermal heating at 75 °C for 15 min followed by cooling to 25 °C. The other half of the HHP-treated CF slurries were refrigerated (at 4 °C for one week and subsequently analyzed for changes in oscillatory properties under the same heating conditions as the unrefrigerated samples. HHP-treated CF in powder form was analyzed for changes in textural properties of heat-induced CF gels under isothermal heating at 90 °C for 5 min and subsequent cooling to 25 °C. Structural changes during gelatinization were investigated using microscopy. Pressure had a more significant effect on rheological and textural properties, followed by T and treatment t (in that order. Gel aging in HHP-treated CF slurries during storage was supported by rheological measurements.

Effect of drying method on the adsorption isotherms and isosteric heat of passion fruit pulp powder

Directory of Open Access Journals (Sweden)

Maria Angélica Marques Pedro

2010-12-01

Full Text Available The sorption behavior of dry products is generally affected by the drying method. The sorption isotherms are useful to determine and compare thermodynamic properties of passion fruit pulp powder processed by different drying methods. The objective of this study is to analyze the effects of different drying methods on the sorption properties of passion fruit pulp powder. Passion fruit pulp powder was dehydrated using different dryers: vacuum, spray dryer, vibro-fluidized, and freeze dryer. The moisture equilibrium data of Passion Fruit Pulp (PFP powders with 55% of maltodextrin (MD were determined at 20, 30, 40 and 50 ºC. The behavior of the curves was type III, according to Brunauer's classification, and the GAB model was fitted to the experimental equilibrium data. The equilibrium moisture contents of the samples were little affected by temperature variation. The spray dryer provides a dry product with higher adsorption capacity than that of the other methods. The vibro-fluidized bed drying showed higher adsorption capacity than that of vacuum and freeze drying. The vacuum and freeze drying presented the same adsorption capacity. The isosteric heats of sorption were found to decrease with increasing moisture content. Considering the effect of drying methods, the highest isosteric heat of sorption was observed for powders produced by spray drying, whereas powders obtained by vacuum and freeze drying showed the lowest isosteric heats of sorption.

Evaluation of piping heat transfer, piping flow regimes, and steam generator heat transfer for the Semiscale Mod-1 isothermal tests

International Nuclear Information System (INIS)

French, R.T.

1975-08-01

Selected experimental data pertinent to piping heat transfer, transient fluid flow regimes, and steam generator heat transfer obtained during the Semiscale Mod-1 isothermal blowdown test series (Test Series 1) are analyzed. The tests in this first test series were designed to provide counterparts to the LOFT nonnuclear experiments. The data from the Semiscale Mod-1 intact and broken loop piping are evaluated to determine the surface heat flux and average heat transfer coefficients effective during the blowdown transient and compared with well known heat transfer correlations used in the RELAP4 computer program. Flow regimes in horizontal pipe sections are calculated and compared with data obtained from horizontal and vertical densitometers and with an existing steady state flow map. Effects of steam generator heat transfer are evaluated quantitatively and qualitatively. The Semiscale Mod-1 data and the analysis presented in this report are valuable for evaluating the adequacy and improving the predictive capability of analytical models developed to predict system response to piping heat transfer, piping flow regimes, and steam generator heat transfer during a postulated loss-of-coolant accident (LOCA) in a pressurized water reactor (PWR). 16 references. (auth)

Thermo-kinetic prediction of metastable and stable phase precipitation in Al–Zn–Mg series aluminium alloys during non-isothermal DSC analysis

International Nuclear Information System (INIS)

Lang, Peter; Wojcik, Tomasz; Povoden-Karadeniz, Erwin; Falahati, Ahmad; Kozeschnik, Ernst

2014-01-01

Highlights: • Comparison of laboratory Al–Zn–Mg alloy to industrial Al 7xxx series. • Heat flow evolution during non-isothermal DSC analysis is calculated. • TEM investigations of laboratory Al–Zn–Mg alloy at three pronounced temperatures. • Simulation and modelling of precipitation sequence. • Calculation and prediction of heat flow curves of Al 7xxx series. - Abstract: The technological properties of heat treatable Al–Zn–Mg alloys originate in the morphology and distribution of metastable particles. Starting from the solution-annealed condition, this paper describes the precipitate evolution during non-isothermal temperature changes, namely continuous heating differential scanning calorimetry (DSC) analysis. The distribution and the morphology of the metastable and stable precipitates and the heat flow accompanying the precipitation process is investigated experimentally and calculated by numerical thermo-kinetic simulations. The computer simulation results of the sizes and distributions are confirmed by transmission electron microscopy (TEM). The theoretical background and the results of the investigations are discussed

Thermo-kinetic prediction of metastable and stable phase precipitation in Al–Zn–Mg series aluminium alloys during non-isothermal DSC analysis

Energy Technology Data Exchange (ETDEWEB)

Lang, Peter, E-mail: pl404@cam.ac.uk [Department of Materials Science and Metallurgy, University of Cambridge, Charles Babbage Road 27, Cambridge CB3 0FS (United Kingdom); Wojcik, Tomasz [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Povoden-Karadeniz, Erwin [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Christian Doppler Laboratory “Early Stages of Precipitation”, Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Falahati, Ahmad [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Kozeschnik, Ernst [Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria); Christian Doppler Laboratory “Early Stages of Precipitation”, Institute of Materials Science and Technology, Vienna University of Technology, Favoritenstraße 9-11, Vienna 1040 (Austria)

2014-10-01

Highlights: • Comparison of laboratory Al–Zn–Mg alloy to industrial Al 7xxx series. • Heat flow evolution during non-isothermal DSC analysis is calculated. • TEM investigations of laboratory Al–Zn–Mg alloy at three pronounced temperatures. • Simulation and modelling of precipitation sequence. • Calculation and prediction of heat flow curves of Al 7xxx series. - Abstract: The technological properties of heat treatable Al–Zn–Mg alloys originate in the morphology and distribution of metastable particles. Starting from the solution-annealed condition, this paper describes the precipitate evolution during non-isothermal temperature changes, namely continuous heating differential scanning calorimetry (DSC) analysis. The distribution and the morphology of the metastable and stable precipitates and the heat flow accompanying the precipitation process is investigated experimentally and calculated by numerical thermo-kinetic simulations. The computer simulation results of the sizes and distributions are confirmed by transmission electron microscopy (TEM). The theoretical background and the results of the investigations are discussed.

Adsorption isotherms of pear at several temperatures

OpenAIRE

Mitrevski Vangelče; Lutovska Monika; Mijakovski Vladimir; Pavkov Ivan S.; Babić Mirko M.; Radojčin Milivoje T.

2015-01-01

The moisture adsorption isotherms of pear were determined at 15ºC, 30ºC and 45ºC using the standard static gravimetric method over a range of water activity from 0.112 to 0.920. The experimental data were fitted with isotherm equations recommended in ASAE Standard D245.5. In order to find which equation gives the best results, large number of numerical experiments were performed. After that, several statistical criteria proposed in scientific literature for...

Conjugate heat transfer in a porous cavity filled with nano-fluids and heated by a triangular thick wall

International Nuclear Information System (INIS)

Chamkha, Ali J.; Ismael, Muneer A.

2013-01-01

The conjugate natural convection-conduction heat transfer in a square domain composed of nano-fluids filled porous cavity heated by a triangular solid wall is studied under steady-state conditions. The vertical and horizontal walls of the triangular solid wall are kept isothermal and at the same hot temperature Th. The other boundaries surrounding the porous cavity are kept adiabatic except the right vertical wall where it is kept isothermally at the lower temperature T c . Equations governing the heat transfer in the triangular wall and heat and nano-fluid flow, based on the Darcy model, in the nano-fluid-saturated porous medium together with the derived relation of the interface temperature are solved numerically using the over-successive relaxation finite-difference method. A temperature independent nano-fluids properties model is adopted. Three nano-particle types dispersed in one base fluid (water) are investigated. The investigated parameters are the nano-particles volume fraction φ (0-0.2), Rayleigh number Ra (10-1000), solid wall to base-fluid saturated porous medium thermal conductivity ratio K ro (0.44, 1, 23.8), and the triangular wall thickness D (0.1-1). The results are presented in the conventional form; contours of streamlines and isotherms and the local and average Nusselt numbers. At a very low Rayleigh number Ra = 10, a significant enhancement in heat transfer within the porous cavity with φ is observed. Otherwise, the heat transfer may be enhanced or deteriorated with φ depending on the wall thickness D and the Rayleigh number Ra. At high Rayleigh numbers and low conductivity ratios, critical values of D, regardless of 4, are observed and accounted. (authors)

Stochastic temperature modulation: A new technique in temperature-modulated DSC

International Nuclear Information System (INIS)

Schawe, J.E.K.; Huetter, T.; Heitz, C.; Alig, I.; Lellinger, D.

2006-01-01

A new temperature-modulated differential scanning calorimetry (TMDSC) technique is introduced. The technique is based on stochastic temperature modulation and has been developed as a consequence of a generalized theory of a temperature-modulated DSC. The quasi-static heat capacity and the frequency-dependent complex heat capacity can be determined over a wide frequency range in one single measurement without further calibration. Furthermore, the reversing and non-reversing heat flows are determined directly from the measured data. Examples show the frequency dependence of the glass transition, the isothermal curing of thermosets and a solid-solid transition

Haze heats Pluto's atmosphere yet explains its cold temperature.

Science.gov (United States)

Zhang, Xi; Strobel, Darrell F; Imanaka, Hiroshi

2017-11-15

Pluto's atmosphere is cold and hazy. Recent observations have shown it to be much colder than predicted theoretically, suggesting an unknown cooling mechanism. Atmospheric gas molecules, particularly water vapour, have been proposed as a coolant; however, because Pluto's thermal structure is expected to be in radiative-conductive equilibrium, the required water vapour would need to be supersaturated by many orders of magnitude under thermodynamic equilibrium conditions. Here we report that atmospheric hazes, rather than gases, can explain Pluto's temperature profile. We find that haze particles have substantially larger solar heating and thermal cooling rates than gas molecules, dominating the atmospheric radiative balance from the ground to an altitude of 700 kilometres, above which heat conduction maintains an isothermal atmosphere. We conclude that Pluto's atmosphere is unique among Solar System planetary atmospheres, as its radiative energy equilibrium is controlled primarily by haze particles instead of gas molecules. We predict that Pluto is therefore several orders of magnitude brighter at mid-infrared wavelengths than previously thought-a brightness that could be detected by future telescopes.

(Amino acid + silica) adsorption thermodynamics: Effects of temperature

International Nuclear Information System (INIS)

Sebben, Damien; Pendleton, Phillip

2015-01-01

Highlights: • High resolution, low concentration Gly, Lys and Glu solution adsorption isotherms. • All isotherms fitted with Langmuir–Freundlich isotherm model. • Gly, Lys and Glu show exothermic adsorption processes. • Isosteric heat analyses reveal changes in interaction strength with surface coverage. - Abstract: A thorough understanding of amino acid adsorption by mineral and oxide surfaces has a major impact on a variety of industrial and biomedical applications. Little information currently exists regarding temperature effects on most of these adsorption processes. Deeper thermodynamic analyses of their multiple temperature adsorption isotherms would aid the interpretation of the interfacial interactions. Low solution concentration adsorption isotherms for glycine, lysine and glutamic acid on a silica adsorbent were generated for T = (291, 298 and 310) K. Data analysis via the Clausius–Clapeyron method yielded the isosteric heat of adsorption as a function of fractional monolayer coverage for each adsorptive. Each amino acid showed an exothermic adsorption response. Glycine and lysine experienced a greater negative effect of increased temperature compared with glutamic acid, indicating a greater number of adsorbed molecules than glutamic acid, with the former undergoing intermolecular clustering within the adsorbed phase. Isosteric heat analyses suggest ionic interactions for lysine and hydrogen bonding for glutamic acid, both weakening with increased coverage. In contrast, initial hydrogen bonding led to ionic bonding for glycine with increasing coverage

Non-isothermal compositional gas flow during carbon dioxide storage and enhanced gas recovery

DEFF Research Database (Denmark)

Singh, Ashok; Böettcher, N.; Wang, W.

2011-01-01

In this work we present the conceptual modeling and the numerical scheme for carbon dioxide storage into nearly depleted gas reservoirs for enhanced gas recovery reasons. For this we develop non-isothermal compositional gas flow model. We used a combined monolithic / staggered coupling scheme...... to solve mass balance equation for the gaseous mixture with heat and fractional mass transport equations. Temperature change resulting from fluid expansion and viscous heat dissipation is included in heat transport in addition to advection and conduction. We have used a modified version of the Peng...

A new apparatus for the determination of adsorption isotherms and adsorption enthalpies on microporous and meso-porous media

International Nuclear Information System (INIS)

Mouahid, A.

2010-01-01

A specific thermostated experimental device comprising a differential heat flow calorimeter coupled with a home built manometric system has been built for the simultaneous determination of adsorption isotherms and adsorption enthalpies. The differential heat flow calorimeter is a Tian Calvet Setaram C80 model which measures the heat flux of a gas and can be operated isothermally, the manometric system is a stainless steel homemade apparatus. This coupled apparatus allows measurements for pressure up to 2.5 MPa and temperature up to 423.15 K. On the one hand, the apparatus and the experimental procedures are described. On the second hand the reliability and reproducibility were established by measuring adsorption isotherms on a benchmark (Filtrasorb F400) at 318.15 K. The gravimetric method has been used at higher pressure at various temperatures. These devices allowed us to study the adsorption of supercritical fluid (nitrogen N 2 , methane CH 4 , carbon dioxide CO 2 ) in activated carbons and microporous or meso-porous silica. The adsorption of methane on a rock of type (TGR) was also studied. These experimental results are used for the study of the interactions fluid / solid that must be taken into account in molecular simulations or DFT theory. (author)

Isothermal solidification based packaging of biosensors at low temperatures

International Nuclear Information System (INIS)

Sharma, R.P.; Khanna, P.K.; Kumar, D.

2010-01-01

Thick film Au printed square contact pads are interconnected to Cu substrates at constant pressure and temperature using the isothermal solidification of Bi-In alloy on the joining surfaces. The effect of reaction time on the mechanical strength of the package has been analyzed. Thermal stability of the fabricated specimens have been measured and discussed. The delaminated surfaces examined optically reveal the morphology of the metallization zones on the joining substrates. The scanning electron microscopy of these surfaces is reported in this paper. Tests for thermal shock, pH resistivity and shelf life have been carried out to predict the reliability of the packaging for long term applications.

Behavior study on Na heat pipe in passive heat removal system of new concept molten salt reactor

International Nuclear Information System (INIS)

Wang Chenglong; Tian Wenxi; Su Guanghui; Zhang Dalin; Wu Yingwei; Qiu Suizheng

2013-01-01

The high temperature Na heat pipe is an effective device for transporting heat, which is characterized by remarkable advantages in conductivity, isothermally and passively working. The application of Na heat pipe on passive heat removal system of new concept molten salt reactor (MSR) is significant. The transient performance of high temperature Na heat pipe was simulated by numerical method under the MSR accident. The model of the Na heat pipe was composed of three conjugate heat transfer zones, i.e. the vapor, wick and wall. Based on finite element method, the governing equations were solved by making use of FORTRAN to acquire the profiles of the temperature, velocity and pressure for the heat pipe transient operation. The results show that the high temperature Na heat pipe has a good performance on operating characteristics and high heat transfer efficiency from the frozen state. (authors)

Power Relative to Body Mass Best Predicts Change in Core Temperature During Exercise-Heat Stress.

Science.gov (United States)

Gibson, Oliver R; Willmott, Ashley G B; James, Carl A; Hayes, Mark; Maxwell, Neil S

2017-02-01

Gibson, OR, Willmott, AGB, James, CA, Hayes, M, and Maxwell, NS. Power relative to body mass best predicts change in core temperature during exercise-heat stress. J Strength Cond Res 31(2): 403-414, 2017-Controlling internal temperature is crucial when prescribing exercise-heat stress, particularly during interventions designed to induce thermoregulatory adaptations. This study aimed to determine the relationship between the rate of rectal temperature (Trec) increase, and various methods for prescribing exercise-heat stress, to identify the most efficient method of prescribing isothermic heat acclimation (HA) training. Thirty-five men cycled in hot conditions (40° C, 39% R.H.) for 29 ± 2 minutes. Subjects exercised at 60 ± 9% V[Combining Dot Above]O2peak, with methods for prescribing exercise retrospectively observed for each participant. Pearson product moment correlations were calculated for each prescriptive variable against the rate of change in Trec (° C·h), with stepwise multiple regressions performed on statistically significant variables (p ≤ 0.05). Linear regression identified the predicted intensity required to increase Trec by 1.0-2.0° C between 20- and 45-minute periods and the duration taken to increase Trec by 1.5° C in response to incremental intensities to guide prescription. Significant (p ≤ 0.05) relationships with the rate of change in Trec were observed for prescriptions based on relative power (W·kg; r = 0.764), power (%Powermax; r = 0.679), rating of perceived exertion (RPE) (r = 0.577), V[Combining Dot Above]O2 (%V[Combining Dot Above]O2peak; r = 0.562), heart rate (HR) (%HRmax; r = 0.534), and thermal sensation (r = 0.311). Stepwise multiple regressions observed relative power and RPE as variables to improve the model (r = 0.791), with no improvement after inclusion of any anthropometric variable. Prescription of exercise under heat stress using power (W·kg or %Powermax) has the strongest relationship with the rate of change in

Natural convection heat transfer of fluid with temperature-dependent specific heat

International Nuclear Information System (INIS)

Tanaka, Amane; Kubo, Shinji; Akino, Norio

1998-01-01

The present study investigates natural convection from a heated vertical plate of fluid with temperature-dependent specific heat, which is introduced as a model of microencapsulated phase change material slurries (MCPCM slurries). The temperature dependence of specific heat is represented by Gauss function with three physical parameters (peak temperature, width of phase change temperature and latent heat). Boundary layer equations are solved numerically, and the velocity and temperature fields of the flow are obtained. The relation between the heat transfer coefficients and the physical parameters of specific heat is discussed. The results show that the velocities and temperatures are smaller, and the heat transfer coefficients are larger comparing with those of the fluid with constant specific heat. (author)

Adsorption isotherms of pear at several temperatures

Directory of Open Access Journals (Sweden)

Mitrevski Vangelče

2015-01-01

Full Text Available The moisture adsorption isotherms of pear were determined at 15ºC, 30ºC and 45ºC using the standard static gravimetric method over a range of water activity from 0.112 to 0.920. The experimental data were fitted with isotherm equations recommended in ASAE Standard D245.5. In order to find which equation gives the best results, large number of numerical experiments were performed. After that, several statistical criteria proposed in scientific literature for estimation and selection of the best sorption isotherm equations were used. For each equation and experimental data set, the average performance index was calculated and models were ranked afterwards. After that, some statistical rejection criteria were checked (D’Agostino-Pearson test of normality, single-sample run test and significance and precision of the model parameters. The performed statistical analysis shows that the Guggenheim-Anderson-de Boer (GAB equation has the highest value of average performance index, but higher correlation between pair of parameters leads to lower precision of estimated parameters.[Projekat Ministarstva nauke Republike Srbije, br. TR 31058

Heat-pipe transient model for space applications

International Nuclear Information System (INIS)

Tournier, J.; El-Genk, M.S.; Juhasz, A.J.

1991-01-01

A two-dimensional model is developed for simulating heat pipes transient performance following changes in the input/rejection power or in the evaporator/condenser temperatures. The model employs the complete form of governing equations and momentum and energy jump conditions at the liquid-vapor interface. Although the model is capable of handling both cylindrical and rectangular geometries, the results reported are for a circular heat pipe with liquid lithium as the working fluid. The model incorporates a variety of other working fluids, such as water, ammonia, potassium, sodium, and mercury, and offers combinations of isothermal, isoflux, convective and radiative heating/cooling conditions in the evaporator and condenser regions of the heat pipe. Results presented are for lithium heat pipes with exponential heating of the evaporator and isothermal cooling of the condenser

Experimental study of natural convection adjacent to an isothermal vertical ice cylinder in cold pure water

International Nuclear Information System (INIS)

Riu, Kap Jong; Yea, Yong Taeg; Park, Sang Hee

1991-01-01

A natural convection adjacent to an isothermal vertical ice cylinder is studied experimentally in cold pure water. The experiments are carried out as changing the temperature of the ambient water and then the flow and heat transfer characteristics is visualized and observed. It is shown that flow patterns are steady state upflow, unsteady state flow, steady state dual flow, and steady state downflow. There is also obtained a heat transfer coefficient and mean Nusselt number at various ambient temperature. These results are in good agreement with the theoretical ones. (Author)

Effect of the medium characteristics and the heating and cooling rates on the nonisothermal heat resistance of Bacillus sporothermodurans IC4 spores.

Science.gov (United States)

Esteban, María-Dolores; Huertas, Juan-Pablo; Fernández, Pablo S; Palop, Alfredo

2013-05-01

In recent years, highly thermo-resistant mesophilic spore-forming bacteria belonging to the species Bacillus sporothermodurans have caused non-sterility problems in industrial sterilization processes. The aim of this research was to evaluate the effect of the heating medium characteristics (pH and buffer/food) on the thermal inactivation of B. sporothermodurans spores when exposed to isothermal and non-isothermal heating and cooling treatments and the suitability of non-linear Weibull and Geeraaerd models to predict the survivors of these thermal treatments. Thermal treatments were carried out in pH 3, 5 and 7 McIlvaine buffer and in a courgette soup. Isothermal survival curves showed shoulders that were accurately characterized by means of both models. A clear effect of the pH of the heating medium was observed, decreasing the D120 value from pH 7 to pH 3 buffer down to one third. Differences in heat resistance were similar, regardless of the model used and were kept at all temperatures tested. The heat resistance in courgette soup was similar to that shown in pH 7 buffer. When the heat resistance values obtained under isothermal conditions were used to predict the survival in the non-isothermical experiments, the predictions estimated the experimental data quite accurately, both with Weibull and Geeraerd models. Copyright © 2012 Elsevier Ltd. All rights reserved.

Combined electrochemical, heat generation, and thermal model for large prismatic lithium-ion batteries in real-time applications

Science.gov (United States)

Farag, Mohammed; Sweity, Haitham; Fleckenstein, Matthias; Habibi, Saeid

2017-08-01

Real-time prediction of the battery's core temperature and terminal voltage is very crucial for an accurate battery management system. In this paper, a combined electrochemical, heat generation, and thermal model is developed for large prismatic cells. The proposed model consists of three sub-models, an electrochemical model, heat generation model, and thermal model which are coupled together in an iterative fashion through physicochemical temperature dependent parameters. The proposed parameterization cycles identify the sub-models' parameters separately by exciting the battery under isothermal and non-isothermal operating conditions. The proposed combined model structure shows accurate terminal voltage and core temperature prediction at various operating conditions while maintaining a simple mathematical structure, making it ideal for real-time BMS applications. Finally, the model is validated against both isothermal and non-isothermal drive cycles, covering a broad range of C-rates, and temperature ranges [-25 °C to 45 °C].

Dispersive kinetic model for the non-isothermal reduction of nickel oxide by hydrogen

International Nuclear Information System (INIS)

Adnadevic, Borivoj; Jankovic, Bojan

2008-01-01

The kinetics of the non-isothermal reduction process of powder nickel oxide samples using hydrogen was investigated by temperature-programmed experiments at the different constant heating rates. The new procedure for the determination of density distribution function of activation energies (ddfE a ), evaluated from the experimentally obtained non-isothermal conversion curves, was developed. The analytical relationships between the corresponding thermo-kinetic parameters for the investigated reduction process were established. From the influence of heating rate on the basic characteristics of ddfE a 's, it was concluded that the evaluated ddfE a 's are completely independent of the heating rate (v h ). It was found that the value of activation energy at the peak of the distribution curve (E a,max ), at all considered heating rates, is in good agreement with the value of E a,0 (96.6 kJ mol -1 ) calculated from the isoconversional dependence of activation energy, in the conversion range of 0.20≤α≤0.60. From the appearances of the true compensation effect, it was concluded that the factor that produces the changes of kinetic parameter values is a conversion fraction (α). Using the model prediction, the experimentally obtained conversion curves are completely described by the evaluated distribution curves (g(E a ) vhj ) at all considered heating rates. It was concluded that the assumption about the distribution of potential energies of oxygen vacancies presented in NiO samples leads to the distribution of activation energies, which determine the kinetics of non-isothermal reduction processes

High temperature heat exchange: nuclear process heat applications

International Nuclear Information System (INIS)

Vrable, D.L.

1980-09-01

The unique element of the HTGR system is the high-temperature operation and the need for heat exchanger equipment to transfer nuclear heat from the reactor to the process application. This paper discusses the potential applications of the HTGR in both synthetic fuel production and nuclear steel making and presents the design considerations for the high-temperature heat exchanger equipment

Water adsorption isotherms of carboxymethyl cellulose, guar, locust bean, tragacanth and xanthan gums.

Science.gov (United States)

Torres, María D; Moreira, Ramón; Chenlo, Francisco; Vázquez, María J

2012-06-20

Water adsorption isotherms of carboxymethyl cellulose (CMC), guar gum (GG), locust bean gum (LBG), tragacanth gum (TG) and xanthan gum (XG) were determined at different temperatures (20, 35, 50, and 65°C) using a gravimetric method. Several saturated salt solutions were selected to obtain different water activities in the range from 0.09 to 0.91. Water adsorption isotherms of tested hydrocolloids were classified like type II isotherms. In all cases, equilibrium moisture content decreased with increasing temperature at each water activity value. Three-parameter Guggenheim-Anderson-de Boer (GAB) model was employed to fit the experimental data in the water activity range and statistical analysis indicated that this model gave satisfactory results. CMC and GG were the most and the least hygroscopic gums, respectively. Sorption heats decreased with increasing moisture content. Monolayer moisture content evaluated with GAB model was consistent with equilibrium conditions of maximum stability calculated from thermodynamic analysis of net integral entropy. Values of equilibrium relative humidity at 20°C are proposed to storage adequately the tested gums. Copyright © 2012 Elsevier Ltd. All rights reserved.

Heat Transfer in Metal Foam Heat Exchangers at High Temperature

Science.gov (United States)

Hafeez, Pakeeza

Heat transfer though open-cell metal foam is experimentally studied for heat exchanger and heat shield applications at high temperatures (˜750°C). Nickel foam sheets with pore densities of 10 and 40 pores per linear inch (PPI), have been used to make the heat exchangers and heat shields by using thermal spray coating to deposit an Inconel skin on a foam core. Heat transfer measurements were performed on a test rig capable of generating hot gas up to 1000°C. The heat exchangers were tested by exposing their outer surface to combustion gases at a temperature of 550°C and 750°C while being cooled by air flowing through them at room temperature at velocities up to 5 m/s. The temperature rise of the air, the surface temperature of the heat exchangers and the air temperature inside the heat exchanger were measured. The volumetric heat transfer coefficient and Nusselt number were calculated for different velocities. The heat transfer performance of the 40PPI sample brazed with the foil is found to be the most efficient. Pressure drop measurements were also performed for 10 and 40PPI metal foam. Thermographic measurements were done on 40PPI foam heat exchangers using a high temperature infrared camera. A high power electric heater was used to produce hot air at 300°C that passed over the foam heat exchanger while the cooling air was blown through it. Heat shields were made by depositing porous skins on metal foam and it was observed that a small amount of coolant leaking through the pores notably reduces the heat transfer from the hot gases. An analytical model was developed based assuming local thermal non-equilibrium that accounts for the temperature difference between solid and fluid phase. The experimental results are found to be in good agreement with the predicted values of the model.

Determination of Differential Enthalpy and Isotherm by Adsorption Calorimetry

Directory of Open Access Journals (Sweden)

V. Garcia-Cuello

2008-01-01

Full Text Available An adsorption microcalorimeter for the simultaneous determination of the differential heat of adsorption and the adsorption isotherm for gas-solid systems are designed, built, and tested. For this purpose, a Calvet heat-conducting microcalorimeter is developed and is connected to a gas volumetric unit built in stainless steel to record adsorption isotherms. The microcalorimeter is electrically calibrated to establish its sensitivity and reproducibility, obtaining K=154.34±0.23 WV−1. The adsorption microcalorimeter is used to obtain adsorption isotherms and the corresponding differential heats for the adsorption of CO2 on a reference solid, such as a NaZSM-5 type zeolite. Results for the behavior of this system are compared with those obtained with commercial equipment and with other studies in the literature.

Technical and economic working domains of industrial heat pumps: Part 2 - ammonia-water hybrid absorption-compression heat pumps

DEFF Research Database (Denmark)

Jensen, Jonas Kjær; Ommen, Torben Schmidt; Markussen, Wiebke Brix

2015-01-01

The ammonia-water hybrid absorption-compression heat pump (HACHP) has been proposed as a relevant technology for industrial heat supply, especially for high sink temperatures and high temperature glides in the sink and source. This is due to the reduced vapour pressure and the non-isothermal phase...... change of the zeotropic mixture, ammonia-water. To evaluate to which extent these advantages can be translated into feasible heat pump solutions, the working domain of the HACHP is investigated based on technical and economic constraints. The HACHP working domain is compared to that of the best available...... vapour compression heat pump with natural working fluids. This shows that the HACHP increases the temperature lifts and heat supply temperatures that are feasible to produce with a heat pump. The HACHP is shown to be capable of delivering heat supply temperatures as high as 150 °C and temperature lifts...

Technical and Economic Working Domains of Industrial Heat Pumps: Part 2 - Ammonia-Water Hybrid Absorption-Compression Heat Pumps

DEFF Research Database (Denmark)

Jensen, Jonas Kjær; Ommen, Torben Schmidt; Markussen, Wiebke Brix

2014-01-01

The ammonia-water hybrid absorption-compression heat pump (HACHP) is a relevant technology for industrial heat supply, especially for high sink temperatures and high temperature glides in the sink and source. This is due to the reduced vapour pressure and the non-isothermal phase change...... of the zeotropic mixture, ammonia-water. To evaluate to which extent these advantages can be translated into feasible heat pump solutions, the working domain of the HACHP is investigated based on technical and economic constraints. The HACHP working domain is compared to that of the best possible vapour...... compression heat pump with natural working fluids. This shows that the HACHP increases the temperature lifts and heat supply temperatures that are feasible to produce with a heat pump. The HACHP is shown to be capable of delivering heat supply temperatures as high as 140 XC and temperature lifts up to 60 K...

Dynamics of CO 2 Adsorption on Amine Adsorbents. 1. Impact of Heat Effects

KAUST Repository

Bollini, Praveen

2012-11-21

The packed bed heat and mass transfer dynamics of CO2 adsorption onto a 3-aminopropylsilyl-functionalized SBA-15 silica material are reported. Concentration measurements at the outlet of the packed bed and temperature profiles inside the bed are measured simultaneously. Heat and mass transfer models in conjunction with the linear driving force rate model are used to simulate the concentration and temperature profiles in the bed. The heat and mass transfer processes in the amine adsorbent packed bed are successfully captured by the model, and comparison of isothermal and nonisothermal models reveals that isothermal models provide an accurate description of the dynamic mass transport behavior in the adsorption column under the experimental conditions used in this study. The results help establish that under certain experimental conditions, heat effects in amine adsorbent packed beds have a negligible effect on CO2 breakthrough, and simple isothermal models can be used to accurately assess adsorption kinetics. © 2012 American Chemical Society.

Non-isothermal electrochemical model for lithium-ion cells with composite cathodes

Science.gov (United States)

Basu, Suman; Patil, Rajkumar S.; Ramachandran, Sanoop; Hariharan, Krishnan S.; Kolake, Subramanya Mayya; Song, Taewon; Oh, Dukjin; Yeo, Taejung; Doo, Seokgwang

2015-06-01

Transition metal oxide cathodes for Li-ion batteries offer high energy density and high voltage. Composites of these materials have shown excellent life expectancy and improved thermal performance. In the present work, a comprehensive non-isothermal electrochemical model for a Lithium ion cell with a composite cathode is developed. The present work builds on lithium concentration-dependent diffusivity and thermal gradient of cathode potential, obtained from experiments. The model validation is performed for a wide range of temperature and discharge rates. Excellent agreement is found for high and room temperature with moderate success at low temperatures, which can be attributed to the low fidelity of material properties at low temperature. Although the cell operation is limited by electronic conductivity of NCA at room temperature, at low temperatures a shift in controlling process is seen, and operation is limited by electrolyte transport. At room temperature, the lithium transport in Cathode appears to be the main source of heat generation with entropic heat as the primary contributor at low discharge rates and ohmic heat at high discharge rates respectively. Improvement in electronic conductivity of the cathode is expected to improve the performance of these composite cathodes and pave way for its wider commercialization.

Isothermal sinusoidal analysis of balanced compound Vuilleumier heat pumps

International Nuclear Information System (INIS)

Finkelstein, T.

1992-01-01

This paper reports on Vuilleumier heat pumps with balanced compounding which have been under investigation for about fifteen years but have not yet reached the stage of commercial utilization. Previously published analytical treatment based upon isothermal treatment of the variable-volume spaces resulted in closed form solution of considerable complexity of the coupled differential equations but applied only to free piston machines. In contrast, the procedure presented here is based on previously demonstrated sinusoidal excursions of the reciprocators. It is of the same order of accuracy, but much more simple and usable. It was found that there is only negligible difference between the results of the present and the previous approach. Additionally, the treatment presented here is applicable to kinematic machines, as well as to free piston machines. For the latter design, an equation for the natural frequency is also derived. Ideal proportions and practical expressions for the energy streams are derived. Gas forces are plotted versus displacement and it is shown that they are equivalent to a linear spring, which is of importance for the concept of a free-piston design

A NON-ISOTHERMAL THEORY FOR INTERPRETING SODIUM LINES IN TRANSMISSION SPECTRA OF EXOPLANETS

Energy Technology Data Exchange (ETDEWEB)

Heng, Kevin; Lavie, Baptiste [University of Bern, Physics Institute, Center for Space and Habitability, Sidlerstrasse 5, CH-3012 Bern (Switzerland); Wyttenbach, Aurélien; Ehrenreich, David; Lovis, Christophe [Observatoire de l’Université de Genève, 51 chemin des Maillettes, CH-1290 Sauverny (Switzerland); Sing, David K., E-mail: kevin.heng@csh.unibe.ch [Astrophysics Group, School of Physics, University of Exeter, Stocker Road, Exeter EX4 4QL (United Kingdom)

2015-04-10

We present a theory for interpreting the sodium lines detected in transmission spectra of exoplanetary atmospheres. Previous analyses employed the isothermal approximation and dealt only with the transit radius. By recognizing the absorption depth and the transit radius as being independent observables, we develop a theory for jointly interpreting both quantities, which allows us to infer the temperatures and number densities associated with the sodium lines. We are able to treat a non-isothermal situation with a constant temperature gradient. Our novel diagnostics take the form of simple-to-use algebraic formulae and require measurements of the transit radii (and their corresponding absorption depths) at line center and in the line wing for both sodium lines. We apply our diagnostics to the HARPS data of HD 189733b, confirm the upper atmospheric heating reported by Huitson et al., derive a temperature gradient of 0.4376 ± 0.0154 K km{sup −1}, and find densities ∼1–10{sup 4} cm{sup −3}.

Integration of space heating and hot water supply in low temperature district heating

DEFF Research Database (Denmark)

Elmegaard, Brian; Ommen, Torben Schmidt; Markussen, Michael

2016-01-01

District heating may supply many consumers efficiently, but the heat loss from the pipes to the ground is a challenge. The heat loss may be lowered by decreasing the network temperatures for which reason low temperature networks are proposed for future district heating. The heating demand...... of the consumers involves both domestic hot water and space heating. Space heating may be provided at low temperature in low energy buildings. Domestic hot water, however, needs sufficient temperatures to avoid growth of legionella. If the network temperature is below the demand temperature, supplementary heating...... is required by the consumer. We study conventional district heating at different temperatures and compare the energy and exergetic efficiency and annual heating cost to solutions that utilize electricity for supplementary heating of domestic hot water in low temperature district heating. This includes direct...

High temperature absorption compression heat pump for industrial waste heat

DEFF Research Database (Denmark)

Reinholdt, Lars; Horntvedt, B.; Nordtvedt, S. R.

2016-01-01

Heat pumps are currently receiving extensive interest because they may be able to support the integration of large shares of fluctuating electricity production based on renewable sources, and they have the potential for the utilization of low temperature waste heat from industry. In most industries......, the needed temperature levels often range from 100°C and up, but until now, it has been quite difficult to find heat pump technologies that reach this level, and thereby opening up the large-scale heat recovery in the industry. Absorption compression heat pumps can reach temperatures above 100°C......, and they have proved themselves a very efficient and reliable technology for applications that have large temperature changes on the heat sink and/or heat source. The concept of Carnot and Lorenz efficiency and its use in the analysis of system integration is shown. A 1.25 MW system having a Carnot efficiency...

Thermoluminescent system for low temperatures

International Nuclear Information System (INIS)

Rosa, L.A.R. da; Caldas, L.V.E.; Leite, N.G.

1988-09-01

A system for measurements of the thermoluminescent glow curve, the thermoluminescent emission spectrum and the optical absorption spectrum of solid samples, from liquid nitrogen temperature up to 473 K, is reported. A specially designed temperature programmer provides a linear heating of the sample at a wide range of selectable heating rates, as also long term steady-state temperatures for annealing and isothermal decay studies. The system operates at a pressure of 1.33 x 10 -3 Pa. Presently it is being used for lithium fluoride low temperature thermoluminescent studies. (author) [pt

Heat index and adjusted temperature as surrogates for wet bulb globe temperature to screen for occupational heat stress.

Science.gov (United States)

Bernard, Thomas E; Iheanacho, Ivory

2015-01-01

Ambient temperature and relative humidity are readily ava-ilable and thus tempting metrics for heat stress assessment. Two methods of using air temperature and relative humidity to create an index are Heat Index and Adjusted Temperature. The purposes of this article are: (1) to examine how well Heat Index and Adjusted Temperature estimated the wet bulb globe temperature (WBGT) index, and (2) to suggest how Heat Index and Adjusted Temperature can be used to screen for heat stress level. Psychrometric relationships were used to estimate values of actual WBGT for conditions of air temperature, relative humidity, and radiant heat at an air speed of 0.5 m/s. A relationship between Heat Index [°F] and WBGT [°C] was described by WBGT = -0.0034 HI(2) + 0.96 HI - 34. At lower Heat Index values, the equation estimated WBGTs that were ± 2 °C-WBGT around the actual value, and to about ± 0.5 °C-WBGT for Heat Index values > 100 °F. A relationship between Adjusted Temperature [°F] and WBGT [°C] was described by WBGT = 0.45 Tadj - 16. The actual WBGT was between 1 °C-WBGT below the estimated value and 1.4 °C-WBGT above. That is, there was a slight bias toward overestimating WBGT from Adjusted Temperature. Heat stress screening tables were constructed for metabolic rates of 180, 300, and 450 W. The screening decisions were divided into four categories: (1) exposure limit at rest. The authors do not recommend using Heat Index or Adjusted Temperature instead of WBGT, but they may be used to screen for circumstances when a more detailed analysis using WBGT is appropriate. A particular weakness is accounting for radiant heat; and neither air speed nor clothing was considered.

Development Characteristics of Velocity Transports in An Isothermal Heated Drag-Reducing Surfactant Solution Flow

Science.gov (United States)

Zhang, Hongxia; Wang, Dezhong; Chen, Hanping; Wang, Yanping

2007-06-01

The development characteristics, turbulence transports for stresses and kinetic energy of a cetyltrimethyl ammonium chloride (CTAC) surfactant solution for a two-dimensional channel flow have been experimentally investigated. Time mean velocity and fluctuating velocity are measured using a Phase Doppler Anemometry (PDA) at the Reynolds number 1.78×104 and isothermal heated temperature 31°C. Although mean velocity profiles at three cross sections show that the fluid is almost fully developed, the peak location of fluctuating intensity for the CTAC solution is slightly away from the wall downstream from the fluid and the peak location of fluctuating intensity is observed at far away from the wall than that of water. The location where the velocity gradient has its maximum, the fluctuating intensity does not get the high value. The elastic shear stress contribution to the total shear stress is 15 percents to 36 percents and it gets to the maximum near to the wall. The surfactant elastic shear stress is almost a liner function of the height of the channel, which means that the elastic stress contribution of the different cross locations is approximately the same. The fluctuating surfactant stress work is negative and the fluctuating elastic shear stresses produce rather than dissipate kinetic energy.

WATER ADSORPTION AND DESORPTION ISOTHERMS ON MILK POWDER: II. WHOLE MILK

OpenAIRE

Edgar M. Soteras; Julio Gil; Paola Yacanto; Silvana Muratona; Clidia Abaca; María G. Sustersic

2014-01-01

The aim of this research was the determination of adsorption and desorption isotherms of cow whole milk powder. The experiments have been carried out at 15, 25 and 40 ºC, in ranges of moisture and water activity characteristic of normal conditions in which the processes of drying, packaging and storage are developed. By studying the influence of the temperature on the experimental plots, the isosteric adsorption heat was determined. Experimental data were correlated to the referential model ...

Numerical investigation of heat transfer effects in small wave rotor

International Nuclear Information System (INIS)

Deng, Shi; Okamoto, Koji; Teramoto, Susumu

2015-01-01

Although a wave rotor is expected to enhance the performance of the ultra-micro gas turbine, the device itself may be affected by downsizing. Apart from the immediate effect of viscosity on flow dynamics when downscaled, the effects of heat transfer on flow field increase at such small scales. To gain an insight into the effects of heat transfer on the internal flow dynamics, numerical investigations were carried out with adiabatic, isothermal and conjugate heat transfer boundary treatments at the wall, and the results compared and discussed in the present study. With the light shed by the discussion of adiabatic and conjugate heat transfer boundary treatments, this work presents investigations of the heat flux distributions, as well as the effects of heat transfer on the internal flow dynamics and the consequent charging and discharging processes for various sizes. When heat transfer is taken into account, states of fluid in the cell before compression process varies, shock waves in compression process are found to be weaker, and changes in the charging and discharging processes are observed. Heat transfer differences between conjugate heat transfer boundary treatment and isothermal boundary treatment are addressed through comparisons of local wall temperature and heat flux. As a result, the difference in discharging temperature of high pressure fluid is noticeable in all sizes investigated, and the rapid increase of differences between results of isothermal and conjugate heat transfer boundary treatment in small size reveals that for certain small sizes (length of cell < 23 mm) the thermal boundary treatment should be taken care of.

Direct measurements of adsorption heats of hydrogen on nano-porous carbons

International Nuclear Information System (INIS)

Akihiko Matsumoto; Kazumasa Yamamoto; Tomoyuki Miyata

2005-01-01

Since a exciting report of hydrogen storage in single-walled carbon nano-tubes by Dillon and his colleagues, nano-porous carbon materials, such as carbon nano-tubes, carbon nano-horns and micro-porous activated carbon, have attracted considerable attention as hydrogen storage materials. Adsorption plays a predominating role in the hydrogen storage process on solid surfaces. The adsorption is a spontaneous process, which is caused by interaction between gas molecules and surface, hence, it is always exothermic process and observed as adsorption heats. For this reason, direct measurement of the adsorption heats by adsorption micro-calorimetry would provide quantitative information on the strength of adsorption interaction and the adsorption mechanism. However, the adsorption amounts of hydrogen on carbon materials are far less than those of condensable vapors near room temperature due to low critical temperature of hydrogen (33.2 K), therefore, the adsorption heats can not be determined accurately at conventional measurement conditions near room temperature and the atmospheric pressure. This contribution reports the calorimetric characterization of hydrogen adsorption on nano-porous carbon materials at low temperature and high-pressure conditions. The high-pressure adsorption apparatus consists of a volumetric adsorption line connected to a twin-conduction type microcalorimeter. Activated carbon fibers (ACF, Ad'all Co.) of different micro-pore sizes (Table 1) were used as model adsorbents. Each ACF has slit-shaped micropores of uniform size. The adsorption isotherms and differential heats of adsorption at high-pressure region from 0 to 10 MPa were simultaneously measured at isothermal condition from 203 to 298 K. The adsorption isotherms on ACF were of Henry type regardless of adsorption temperature and pore width; the uptakes increased linearly with equilibrium pressure. The adsorption isotherm at lower sorption temperature tended to show higher sorptivity. The

Effect of austempering temperature and time on mechanical properties of SAE 9260 steel

Science.gov (United States)

Dalwatkar, Ranjit; Prabhu, N.; Singh, R. K. P.

2018-04-01

This work describes the effect of austempering heat treatment on microstrcuture and mechanical properties of SAE 9260 steel. Steel samples, austenitized at 900 °C for one hour, were isothermally heat treated in the temperature range 300,325 and 350 °C for different times. Microstructural characterization was carried out using optical and scanning electron microscopes. The microstructure of the austempered samples consisted of bainitic ferrite and retained austenite. The volume fraction of retained austenite was determined using X-ray diffraction. Isothermal heat treatment at 350 °C for 20 min, resulted in a retained austenite content of around 38% in the microstructure. Increase in isothermal transformation temperature led to an increase in the fraction of retained austenite. Also, good combination of strength and ductility was obtained in the samples with increased amounts of retained austenite.

Relation between time-temperature transformation and continuous heating transformation diagrams of metallic glassy alloys

International Nuclear Information System (INIS)

Louzguine-Luzgin, Dmitri V.; Inoue, Akihisa

2005-01-01

The time-temperature transformation (TTT) diagrams for the onset of devitrification of the Ge-Ni-La and Cu-Hf-Ti glassy alloys were calculated from the isothermal differential calorimetry data using an Arrhenius equation. The continuous heating transformation (CHT) diagrams for the onset of devitrification of the glassy alloys were subsequently recalculated from TTT diagrams. The recalculation method used for conversion of the TTT into CHT diagrams produces reasonable results and is not sensitive to the type of the devitrification reaction (polymorphous or primary transformation). The diagrams allow to perform a comparison of the stabilities of glassy alloys on a long-term scale. The relationship between these diagrams is discussed

Effect of heat treatment on CO2 adsorption of KOH-activated graphite nanofibers.

Science.gov (United States)

Meng, Long-Yue; Park, Soo-Jin

2010-12-15

In this work, graphite nanofibers (GNFs) were successfully expanded intercalating KOH followed by heat treatment in the temperature range of 700-1000 °C. The aim was to improve the CO(2) adsorption capacity of the GNFs by increasing the porosity of GNFs. The effects of heat treatment on the pore structures of GNFs were investigated by N(2) full isotherms, XRD, SEM, and TEM. The CO(2) adsorption capacity was measured by CO(2) isothermal adsorption at 25 °C and 1 atm. From the results, it was found that the activation temperature had a major influence on CO(2) adsorption capacity and textural properties of GNFs. The specific surface area, total pore volume, and mesopore volume of the GNFs increased after heat treatment. The CO(2) adsorption isotherms showed that G-900 exhibited the best CO(2) adsorption capacity with 59.2 mg/g. Copyright © 2010 Elsevier Inc. All rights reserved.

The development of modulated, quasi-isothermal and ultraslow thermal methods as a means of characterizing the α to γ indomethacin polymorphic transformation.

Science.gov (United States)

Qi, Sheng; Craig, Duncan Q M

2012-05-07

While polymorphism remains a key issue within the pharmaceutical and related industries, the understanding of the transformation process itself remains relatively poorly understood. In this study we use a combination of conventional and modulated temperature differential scanning calorimetry (MTDSC), quasi-isothermal MTDSC (Qi-MTDSC) and ultraslow heating rate MTDSC as a novel means of investigating the temperature-induced α to γ transformation in indomethacin, using hot stage microscopy and variable temperature attenuated total reflectance FTIR spectroscopy as supportive techniques. In particular, we utilize the ability of MTDSC to measure subtle heat capacity changes through the transformation, we examine the use of Lissajous analysis of the modulated heating signal itself (both scanning and quasi-isothermal) and finally we investigate the use of ultraslow heating rates (down to 0.04 °C/min) so as to facilitate examination of the melt-crystallization process at a scanning rate whereby kinetic hindrance becomes negligible. Indomethacin was prepared in the metastable α and stable γ forms using standard approaches. Samples were studied using conventional DSC, Qi-MTDSC (involving holding and modulating the sample at a series of incremental temperature steps) and ultraslow MTDSC. All studies were conducted using a Q-1000 MTDSC using crimped pans, following standard calibration procedures. Conventional DSC at 10 °C/min showed the expected single melting responses for the α and γ forms, while MTDSC at slower rates indicated the presence of a melt-crystallization process. Quasi-isothermal studies allowed the heat capacity to be estimated as a function of time, while the associated Lissajous analysis demonstrated distortion of the elliptical response as a result of the kinetic events involved. Ultraslow heating resulted in superimposition of the melting and crystallization processes, resulting in a discrete thermal event that was enthalpically equivalent to the

Influence on Heat Transfer Coefficient of Heat Exchanger by Velocity and Heat Transfer Temperature Difference

Directory of Open Access Journals (Sweden)

WANG Fang

2017-04-01

Full Text Available Aimed to insufficient heat transfer of heat exchanger, research the influence on the heat transfer coefficient impacted by velocity and heat transfer temperature difference of tube heat exchanger. According to the different heat transfer temperature difference and gas velocity，the experimental data were divided into group. Using the control variable method，the above two factors were analyzed separately. K一△T and k一:fitting curve were clone to obtain empirical function. The entire heat exchanger is as the study object，using numerical simulation methods，porous media，k一￡model，second order upwind mode，and pressure一velocity coupling with SIMPLE algorithm，the entire heat exchanger temperature field and the heat transfer coefficient distribution were given. Finally the trend of the heat transfer coefficient effected by the above two factors was gotten.

Mathematical modelling of non-isothermal venturi scrubbers

Energy Technology Data Exchange (ETDEWEB)

Rahimi, A. [Isfahan Univ., Isfahan (Iran, Islamic Republic of). Dept. of Chemical Engineering; Taheri, M.; Fathikakajahi, J. [Shiraz Univ., Shiraz (Iran, Islamic Republic of). Dept. of Chemical Engineering

2005-06-01

Venturi scrubbers collect gaseous pollutants and particulate matter from industrial exhaust. This air pollution control device is highly efficient, easy to maintain and has a low initial cost. However, the high pressure drop through the device results in a high running cost. The main mechanism for collecting particulates is the inertial impaction of the particles on the droplets, which occurs due to high velocity between the gas stream and droplets. Droplet acceleration and irreversible drag-force which results from this high relative velocity are responsible for the high pressure drop in this type of scrubber. While several attempts have been made to mathematically model particulate removal in Venturi scrubbers, most models do not consider simultaneous heat and mass transfer. This factor is important because most Venturi scrubbers operate under non-isothermal conditions where the inlet gas is humidified in order to cool it before entering the scrubber. For that reason, the authors developed a more realistic model to determine the effects of heat and mass transfer on the particulate removal efficiency of a non-isothermal Venturi type scrubber. The model considers the effect of droplet size distribution and liquid film flow on the walls. It consists of differential equations for energy, momentum and material exchange. Model results were compared with data from experimental studies and industrial facilities. It was concluded that the removal efficiency of the scrubber is influenced by the inlet humidity temperature of the inlet gas. 26 refs., 1 tab., 10 figs.

Isothermal and isochronal annealing methodology to study post-irradiation temperature activated phenomena

International Nuclear Information System (INIS)

Chabrerie, C.; Autran, J.L.; Paillet, P.; Flament, O.; Leray, J.L.; Boudenot, J.C.

1997-01-01

In this work, the evolution of the oxide trapped charge has been modeled, to predict post-irradiation behavior for arbitrary anneal conditions (i.e., arbitrary temperature-time profiles). Using experimental data obtained from a single isochronal anneal, the method consists of calculating the evolution of the energy distribution of the oxide trapped charge, in the framework of a thermally activated charge detrapping model. This methodology is illustrated in this paper by the prediction of experimental isothermal data from isochronal measurements. The implications of these results to hardness assurance test methods are discussed

Non-isothermal spreading of liquid drops on horizontal plates

International Nuclear Information System (INIS)

Ehrhard, P.; Davis, S.H.

1990-05-01

A viscous-liquid drop spreads on a smooth horizontal surface, which is uniformly heated or cooled. Lubrication theory is used to study thin drops subject to capillary, thermocapillary and gravity forces, and a variety of contact-angle-versus-speed conditions. It is found for isothermal drops that gravity is very important at large times and determines the power law for unlimited spreading. Predictions compare well with the experimental data on isothermal spreading for both two-dimensional and axisymmetric configurations. It is found that heating (cooling) retards (augments) the spreading process. When the advancing contact angle is zero, heating will cause the drop to spread only finitely far. For positive advancing contact angles, sufficient cooling will cause unlimited spreading. Thus, the heat transfer serves as a sentitive control on the spreading. (orig.) [de

Partial-Isothermally-Treated Low Alloy Ultrahigh Strength Steel with Martensitic/Bainitic Microstructure

Science.gov (United States)

Luo, Quanshun; Kitchen, Matthew; Patel, Vinay; Filleul, Martin; Owens, Dave

We introduce a new strengthening heat treatment of a Ni-Cr-Mo-V alloyed spring steel by partial isothermal salt-bath and subsequent air-cooling and tempering. Detailed isothermal treatments were made at temperatures below or above the Ms point (230°C). The salt bath time was controlled between 10 and 80 minutes. Through the new treatment, the candidate steel developed ultrahigh tensile strength 2,100 MPa, yield strength 1,800 MPa, elongation 8-10 %, hardness 580-710 HV, and V-notch Charpy toughness 10-12 J. Optical and electron microscopic observations and X-ray diffraction revealed multi-phase microstructures of bainitic/martensitic ferrites, fine carbide precipitates and retained austenite. Carbon partitioning during the bainitic/martensitic transformation was investigated for its remarkable influence on the strengthening mechanism.

Heat transfer in porous medium embedded with vertical plate: Non-equilibrium approach - Part A

Energy Technology Data Exchange (ETDEWEB)

Badruddin, Irfan Anjum [Dept. of Mechanical Engineering, University of Malaya, Kuala Lumpur, 50603 (Malaysia); Quadir, G. A. [School of Mechatronic Engineering, University Malaysia Perlis, Pauh Putra, 02600 Arau, Perlis (Malaysia)

2016-06-08

Heat transfer in a porous medium embedded with vertical flat plate is investigated by using thermal non-equilibrium model. Darcy model is employed to simulate the flow inside porous medium. It is assumed that the heat transfer takes place by natural convection and radiation. The vertical plate is maintained at isothermal temperature. The governing partial differential equations are converted into non-dimensional form and solved numerically using finite element method. Results are presented in terms of isotherms and streamlines for various parameters such as heat transfer coefficient parameter, thermal conductivity ratio, and radiation parameter.

Heat transfer in porous medium embedded with vertical plate: Non-equilibrium approach - Part A

International Nuclear Information System (INIS)

Badruddin, Irfan Anjum; Quadir, G. A.

2016-01-01

Heat transfer in a porous medium embedded with vertical flat plate is investigated by using thermal non-equilibrium model. Darcy model is employed to simulate the flow inside porous medium. It is assumed that the heat transfer takes place by natural convection and radiation. The vertical plate is maintained at isothermal temperature. The governing partial differential equations are converted into non-dimensional form and solved numerically using finite element method. Results are presented in terms of isotherms and streamlines for various parameters such as heat transfer coefficient parameter, thermal conductivity ratio, and radiation parameter

Feedback circuit application for multiple fluid temperature rise or drop; Visestruko dizanje i spustanje temperature fluida povratnom spregom

Energy Technology Data Exchange (ETDEWEB)

Novakovic, M [Tehnoloski fakultet Novi Sad (Yugoslavia); Stefanovic, M [Institute of Nuclear Sciences Vinca, Belgrade (Yugoslavia); Blagojevic, B [MaSinski fakultet, Nis (Yugoslavia); Stoiljkovic, S [Tehnoloski fakultet, Leskovac (Yugoslavia)

1995-07-01

Multiplication of temperature rise or drop is proposed and explained by Feedback method. Application of this method is proposed for different elementary processes of temperature variation (non isothermal processes). The paper points to possibilities of increasing performance of existing apparatuses and new ways for performing heating or cooling. (author)

High temperature alloys and ceramic heat exchanger

International Nuclear Information System (INIS)

Okamoto, Masaharu

1984-04-01

From the standpoint of energy saving, the future operating temperatures of process heat and gas turbine plants will become higher. For this purpose, ceramics is the most promissing candidate material in strength for application to high-temperature heat exchangers. This report deals with a servey of characteristics of several high-temperature metallic materials and ceramics as temperature-resistant materials; including a servey of the state-of-the-art of ceramic heat exchanger technologies developed outside of Japan, and a study of their application to the intermediate heat exchanger of VHTR (a very-high-temperature gas-cooled reactor). (author)

ISOTHERMAL AND THERMOMECHANICAL FATIGUE OF A NICKEL-BASE SUPERALLOY

Directory of Open Access Journals (Sweden)

Carlos Carvalho Engler-Pinto Júnior

2014-06-01

Full Text Available Thermal gradients arising during transient regimes of start-up and shutdown operations produce a complex thermal and mechanical fatigue loading which limits the life of turbine blades and other engine components operating at high temperatures. More accurate and reliable assessment under non-isothermal fatigue becomes therefore mandatory. This paper investigates the nickel base superalloy CM 247LC-DS under isothermal low cycle fatigue (LCF and thermomechanical fatigue (TMF. Test temperatures range from 600°C to 1,000°C. The behavior of the alloy is strongly affected by the temperature variation, especially in the 800°C-1,000°C range. The Ramberg-Osgood equation fits very well the observed isothermal behavior for the whole temperature range. The simplified non-isothermal stress-strain model based on linear plasticity proposed to represent the thermo-mechanical fatigue behavior was able to reproduce the observed behavior for both in-phase and out-of-phase TMF cycling.

Sorption Isotherm Modelling Of Fermented Cassava Flour by Red Yeast Rice

Science.gov (United States)

Cahyanti, M. N.; Alfiah, M. N.; Hartini, S.

2018-04-01

The objective of the study is to determine the characteristic of moisture sorption isotherm from fermented cassava flour by red yeast rice using various modeling. This research used seven salt solutions and storage temperature of 298K, 303K, and 308K. The models used were Brunauer-Emmet-Teller (BET), Guggenheim-Anderson-de Boer (GAB) and Caurie model. The monolayer moisture content was around 4.51 – 5.99% db. Constant related to absorption heat in the multilayer area of [GAB model was around 0.86-0,91. Constant related to absorption heat in the monolayer area of GAB model was around 4.67-5.97. Constant related to absorption heat in the monolayer area of BET model was around 4.83-7.04. Caurie constant was around 1.25-1.59. The equilibrium and monolayer moisture content on fermented cassava flour by red yeast rice was decreasing as increasing temperature. GAB constant value indicated that the process of moisture absorption on the fermented cassava flour by red yeast rice categorized in type II.

Phase composition of Al-Ti-Nb-Mo γ alloys in the heat-treatment temperature range: Calculation and experiment

Science.gov (United States)

Belov, N. A.; Dashkevich, N. I.; Bel'tyukova, S. O.

2015-07-01

The phase composition of TNM-type Al-Ti-Nb-Mo γ alloys at heat-treatment temperatures is quantitatively studied using the Thermo-Calc program package and experimental methods. Isothermal cross sections are calculated and the joint influence of two alloying elements on the phase composition of the alloy is determined at the mean concentration of a third component. Based on the calculations of vertical cross sections, the boundaries of the four-phase eutectoid reaction α → α2 + β + γ are found. The temperature is shown to significantly influence the phase compositions of the γ alloys, among them the mass fractions of various phases (α, β, γ,α2) and the element concentration in them.

Isotherms and isosteric heat of sorption of two varieties of Peruvian quinoa

Directory of Open Access Journals (Sweden)

Augusto Pumacahua-Ramos

2016-01-01

Full Text Available The isosteric heats of sorption of two varieties of quinoa (Chenopodium quinoaWilld. grain were determined by the static gravimetric method at four temperatures (40, 50, 60 and 70 °C andin relative humidity environments provided by six saturated salt solutions. Six mathematical equations were used to model the experimental data: GAB, Oswin, Henderson, Peleg, Smith and Halsey. The isosteric heat of sorption was determined using the parameters of the GAB model. All the equations were shown to be appropriate by the coefficients of determination (R2 and the mean absolute error (MA%E. The influence of temperature was observed because the adsorption of water by the grains was lower at highertemperatures. The equilibrium moisture contents for security of storage, for long periods of time at water activity lower than 0.65, were 12 -13%. The effect of temperature on the parameters of the GAB model was analysed using the exponential Arrhenius equation. The isosteric heats of sorption were determined by applying the Clausius-Clapeyron equation as a function of humidity. The isosteric heat at 5% moisture for grains of the Blanca de Juli variety was 3663 kJ/kg and for the Pasankalla variety it was 3393 kJ/kg. The experimental data for isosteric heat as a function of humidity were satisfactorily modelled using three mathematical equations.

Heat transfer and critical heat flux in a asymmetrically heated tube helicoidal flow

International Nuclear Information System (INIS)

Boscary, J.

1995-10-01

The design of plasma facing components is crucial for plasma performance in next fusion reactors. These elements will be submitted to very high heat flux. They will be actively water-cooled by swirl tubes in the subcooled boiling regime. High heat flux experiments were conducted in order to analyse the heat transfer and to evaluate the critical heat flux. Water-cooled mock-ups were one-side heated by an electron beam gun for different thermal-hydraulic conditions. The critical heat flux was detected by an original method based on the isotherm modification on the heated surface. The wall heat transfer law including forced convection and subcooled boiling regimes was established. Numerical calculations of the material heat transfer conduction allowed the non-homogeneous distribution of the wall temperature and of the wall heat flux to be evaluated. The critical heat flux value was defined as the wall maximum heat flux. A critical heat flux model based on the liquid sublayer dryout under a vapor blanket was established. A good agreement with test results was found. (author). 198 refs., 126 figs., 21 tabs

In situ Raman study of C60 polymerization during isothermal pressurizing at 800 K

International Nuclear Information System (INIS)

Talyzin, A V; Dubrovinsky, L S

2004-01-01

The first in situ Raman study of C 60 isothermal compression at 800 K and up to 32 GPa was performed using rhombohedral and tetragonal phases as starting materials. The rhombohedral phase shows a phase transition to 3D polymer above 10 GPa, similar to that in experiments where isobaric heating was used at pressures of 9-13 GPa. It is shown that the T-P diagram of C 60 polymeric phases (temperature increase followed by pressurizing) is significantly different from the known P-T diagram (pressurizing followed by heating). Tetragonal polymer exhibited significantly stronger stability and can be followed at least up to ∼15 GPa. Heating up to 800 K of tetragonal polymer at pressures of 6-8 GPa confirms that, due to geometrical frustrations, the tetragonal phase remains stable even at pressure and temperature conditions at which rhombohedral polymer is usually formed

Development of isothermal-isobaric replica-permutation method for molecular dynamics and Monte Carlo simulations and its application to reveal temperature and pressure dependence of folded, misfolded, and unfolded states of chignolin

Science.gov (United States)

Yamauchi, Masataka; Okumura, Hisashi

2017-11-01

We developed a two-dimensional replica-permutation molecular dynamics method in the isothermal-isobaric ensemble. The replica-permutation method is a better alternative to the replica-exchange method. It was originally developed in the canonical ensemble. This method employs the Suwa-Todo algorithm, instead of the Metropolis algorithm, to perform permutations of temperatures and pressures among more than two replicas so that the rejection ratio can be minimized. We showed that the isothermal-isobaric replica-permutation method performs better sampling efficiency than the isothermal-isobaric replica-exchange method and infinite swapping method. We applied this method to a β-hairpin mini protein, chignolin. In this simulation, we observed not only the folded state but also the misfolded state. We calculated the temperature and pressure dependence of the fractions on the folded, misfolded, and unfolded states. Differences in partial molar enthalpy, internal energy, entropy, partial molar volume, and heat capacity were also determined and agreed well with experimental data. We observed a new phenomenon that misfolded chignolin becomes more stable under high-pressure conditions. We also revealed this mechanism of the stability as follows: TYR2 and TRP9 side chains cover the hydrogen bonds that form a β-hairpin structure. The hydrogen bonds are protected from the water molecules that approach the protein as the pressure increases.

Studies of non-isothermal flow in saturated and partially saturated porous media

International Nuclear Information System (INIS)

Ho, C.K.; Maki, K.S.; Glass, R.J.

1993-01-01

Physical and numerical experiments have been performed to investigate the behavior of nonisothermal flow in two-dimensional saturated and partially saturated porous media. The physical experiments were performed to identify non-isothermal flow fields and temperature distributions in fully saturated, half-saturated, and residually saturated two-dimensional porous media with bottom heating and top cooling. Two counter-rotating liquid-phase convective cells were observed to develop in the saturated regions of all three cases. Gas-phase convection was also evidenced in the unsaturated regions of the partially saturated experiments. TOUGH2 numerical simulations of the saturated case were found to be strongly dependent on the assumed boundary conditions of the physical system. Models including heat losses through the boundaries of the test cell produced temperature and flow fields that were in better agreement with the observed temperature and flow fields than models that assumed insulated boundary conditions. A sensitivity analysis also showed that a reduction of the bulk permeability of the porous media in the numerical simulations depressed the effects of convection, flattening the temperature profiles across the test cell

Coronal Loops: Evolving Beyond the Isothermal Approximation

Science.gov (United States)

Schmelz, J. T.; Cirtain, J. W.; Allen, J. D.

2002-05-01

Are coronal loops isothermal? A controversy over this question has arisen recently because different investigators using different techniques have obtained very different answers. Analysis of SOHO-EIT and TRACE data using narrowband filter ratios to obtain temperature maps has produced several key publications that suggest that coronal loops may be isothermal. We have constructed a multi-thermal distribution for several pixels along a relatively isolated coronal loop on the southwest limb of the solar disk using spectral line data from SOHO-CDS taken on 1998 Apr 20. These distributions are clearly inconsistent with isothermal plasma along either the line of sight or the length of the loop, and suggested rather that the temperature increases from the footpoints to the loop top. We speculated originally that these differences could be attributed to pixel size -- CDS pixels are larger, and more `contaminating' material would be expected along the line of sight. To test this idea, we used CDS iron line ratios from our data set to mimic the isothermal results from the narrowband filter instruments. These ratios indicated that the temperature gradient along the loop was flat, despite the fact that a more complete analysis of the same data showed this result to be false! The CDS pixel size was not the cause of the discrepancy; rather, the problem lies with the isothermal approximation used in EIT and TRACE analysis. These results should serve as a strong warning to anyone using this simplistic method to obtain temperature. This warning is echoed on the EIT web page: ``Danger! Enter at your own risk!'' In other words, values for temperature may be found, but they may have nothing to do with physical reality. Solar physics research at the University of Memphis is supported by NASA grant NAG5-9783. This research was funded in part by the NASA/TRACE MODA grant for Montana State University.

Optimization criteria for low temperature waste heat utilization

International Nuclear Information System (INIS)

Kranebitter, F.

1977-01-01

A special case in this field is the utilization of very low temperature waste heat. The temperature level under consideration in this paper is in the range between the body temperature of human beings and their environment. The waste heat from power generation and industrial processes is also considered. Thermal energy conversion will be mainly accomplished by heat cycles where discharged waste heat is reverse proportional to the upper cycle temperature. Limiting this upper cycle temperature by technological reasons the optimization of the heat cycle will depend on the nature of the cycle itself and specially on the temperature selected for the heat discharge. The waste heat discharge is typical for the different kinds of heat cycles and the paper presents the four most important of them. Feasible heat transfer methods and their economic evaluations are discussed and the distillation processes will be the basis for further considerations. The waste heat utilization for distillation purposes could be realized by three different cycles, the open cycle, the closed cycle and the multy cycle. Resulting problems as deaeration of large water streams and removal of the dissolved gases and their solutions are also discussed. (M.S.)

Moisture sorption isotherms and glass transition temperature of elecampe (Inula helenium L.) and burdock (Arctium lappa L.) roots at 25°C.

Science.gov (United States)

Cervenka, L; Kubínová, J; Juszczak, L; Witczak, M

2012-02-01

Sorption isotherms of elecampe (Inula helenium L.) and burdock (Arctium lappa L.) root samples were obtained at 25 °C. Elecampe exhibited hysteresis loop in the range of 0.35-0.90 a(w) , whereas burdock roots showed significant differences between adsorption and desorption isotherms from 0.65 to 0.80 a(w) . Blahovec-Yanniotis was considered to give the best fit over the whole range of a(w) tested. Various parameters describing the properties of sorbed water derived from GAB, Henderson and Blahovec-Yanniotis models have been discussed. Differential scanning calorimetric method was used to measure the glass transition temperature (T (g)) of root samples in relation to water activity. The safe moisture content was determined in 12.01 and 14.96 g/100 g d. b. for burdock and elecampe root samples at 25 °C, respectively. Combining the T (g) line with sorption isotherm in one plot, it was found that the glass transition temperature concept overestimated the temperature stability for both root samples.

Novikov Engine with Fluctuating Heat Bath Temperature

Science.gov (United States)

Schwalbe, Karsten; Hoffmann, Karl Heinz

2018-04-01

The Novikov engine is a model for heat engines that takes the irreversible character of heat fluxes into account. Using this model, the maximum power output as well as the corresponding efficiency of the heat engine can be deduced, leading to the well-known Curzon-Ahlborn efficiency. The classical model assumes constant heat bath temperatures, which is not a reasonable assumption in the case of fluctuating heat sources. Therefore, in this article the influence of stochastic fluctuations of the hot heat bath's temperature on the optimal performance measures is investigated. For this purpose, a Novikov engine with fluctuating heat bath temperature is considered. Doing so, a generalization of the Curzon-Ahlborn efficiency is found. The results can help to quantify how the distribution of fluctuating quantities affects the performance measures of power plants.

Evaluation of Degradation of Isothermally Aged Plasma-Sprayed Thermal Barrier Coating

Energy Technology Data Exchange (ETDEWEB)

Koo, Jae Mean; Seok, Chang Sung; Kang, Min Sung; Kim, Dae Jin [Sungkyunkwan University, Seoul (Korea, Republic of); Lee, Dong Hoon [HYUNDAI STEEL CO., Incheon (Korea, Republic of); Kim, Mun Young [KPS Gas Turbine Technology Service Center, Seongnam (Korea, Republic of)

2010-04-15

The thermal barrier coating of a gas turbine blade was degraded by isothermal heating in a furnace and by varying the exposure time and temperature. Then, a micro-Vickers hardness test was conducted on the cross section of the bond coat and Ni-based superalloy substrate. Further, the thickness of TGO(Thermally Grown Oxide) was measured by using an image analyzer, and the changes in the microstructure and element contents in the coating were analyzed by using an optical microscope and by performing SEM-EDX analysis. No significant change was observed in the Vickers hardness of the bond coat when the coated specimen was degraded at a high temperature: delamination was observed between the top coat and the bond coat when the coating was degraded for 50 h at a temperature 1,151 .deg. C.

Medium Deep High Temperature Heat Storage

Science.gov (United States)

Bär, Kristian; Rühaak, Wolfram; Schulte, Daniel; Welsch, Bastian; Chauhan, Swarup; Homuth, Sebastian; Sass, Ingo

2015-04-01

Heating of buildings requires more than 25 % of the total end energy consumption in Germany. Shallow geothermal systems for indirect use as well as shallow geothermal heat storage systems like aquifer thermal energy storage (ATES) or borehole thermal energy storage (BTES) typically provide low exergy heat. The temperature levels and ranges typically require a coupling with heat pumps. By storing hot water from solar panels or thermal power stations with temperatures of up to 110 °C a medium deep high temperature heat storage (MDHTS) can be operated on relatively high temperature levels of more than 45 °C. Storage depths of 500 m to 1,500 m below surface avoid conflicts with groundwater use for drinking water or other purposes. Permeability is typically also decreasing with greater depth; especially in the crystalline basement therefore conduction becomes the dominant heat transport process. Solar-thermal charging of a MDHTS is a very beneficial option for supplying heat in urban and rural systems. Feasibility and design criteria of different system configurations (depth, distance and number of BHE) are discussed. One system is designed to store and supply heat (300 kW) for an office building. The required boreholes are located in granodioritic bedrock. Resulting from this setup several challenges have to be addressed. The drilling and completion has to be planned carefully under consideration of the geological and tectonical situation at the specific site.

Feedback circuit application for multiple fluid temperature rise or drop; Visestruko dizanje i spustanje temperature fluida povratnom spregom

Energy Technology Data Exchange (ETDEWEB)

Novakovic, M [Tehnoloski fakultet Novi Sad (Yugoslavia); Stefanovic, M [Institute of Nuclear Sciences Vinca, Belgrade (Yugoslavia); Blagojevic, B [MaSinski fakultet, Nis (Yugoslavia); Stoiljkovic, S [Tehnoloski fakultet, Leskovac (Yugoslavia)

1996-12-31

Multiplication of temperature rise or drop is proposed and explained by Feedback method. Application of this method is proposed for different elementary processes of temperature variation (non isothermal processes). The paper points to possibilities of increasing performance of existing apparatuses and new ways for performing heating or cooling. (author.) 2 refs. 3 figs. 1 tabs.

Heat transfer and critical heat flux in a spiral flow in an asymmetrical heated tube

International Nuclear Information System (INIS)

Boscary, J.; Association Euratom-CEA, Centre d'Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance

1997-03-01

The design of plasma facing components is crucial for plasma performance in next fusion reactors. These elements will be submitted to very high heat flux. They will be actively water-cooled by swirl tubes in the subcooled boiling regime. High heat flux experiments were conducted in order to analyse the heat transfer and to evaluate the critical heat flux. Water-cooled mock-ups were one-side heated by an electron beam gun for different thermal-hydraulic conditions. The critical heat flux was detected by an original method based on the isotherm modification on the heated surface. The wall heat transfer law including forced convection and subcooled boiling regimes was established. Numerical calculations of the material heat transfer conduction allowed the non-homogeneous distribution of the wall temperature and of the wall heat flux to be evaluated. The critical heat flux value was defined as the wall maximum heat flux. A critical heat flux model based on the liquid sublayer dryout under a vapor blanket was established. A good agreement with test results was found. (author)

Experimental and Numerical Studies on Isothermal and Non-isothermal Deep Drawing of IS 513 CR3 Steel Sheets

Science.gov (United States)

Mayavan, T.; Karthikeyan, L.; Senthilkumar, V. S.

2016-11-01

The present work aims to investigate the effects of the temperature gradient developed within the tool profiles on the formability of IS 513 CR3-grade steel sheets using the cup drawing test. The deformation characteristics of steel sheets were analyzed by comparing the thicknesses in various regions of the formed cup and also the limiting drawing ratios (LDR). Finite element simulations were carried out to predict the behavior of the steel sheets in isothermal and non-isothermal forming using Abaqus/Standard 6.12-1. An analytical model created by Kim was used to validate the experimental and finite element analysis (FEA) results on identical process parameters. Both the FEA and analytical modeling results showed that formability improvement is possible in warm forming; the findings are in good agreement with the experimental results in determining the locations and values of excessive thinning. The results also indicated that formability improvement cannot be achieved by keeping the tooling temperature at the same level. The LDR increased by around 9.5% in isothermal forming and by 19% in non-isothermal forming (with the punch maintained at a lower temperature compared with the die and blank holder). In addition, the fractured surfaces of unsuccessfully formed samples were analyzed using scanning electron microscopy. Metallographic investigations confirmed that the fracture mechanism during the forming of IS 513 CR3-grade steel sheets depends on the brittleness, strain hardening value, forming temperature, and magnitude of stresses developed.

Heating induced structural and chemical behavior of KD2PO4 in the 25 °C–215 °C temperature range

International Nuclear Information System (INIS)

Botez, Cristian E.; Morris, Joshua L.; Encerrado Manriquez, Andres J.; Anchondo, Adan

2013-01-01

We have used powder x-ray diffraction (XRD) to investigate the structural and chemical modifications undergone by KD 2 PO 4 (DKDP) upon heating from room temperature to 215 °C. Full-profile (Le Bail) analysis of our temperature-resolved data shows no evidence of polymorphic structural transitions or deuterium–hydrogen isotope exchange occurring below T s = 185 °C. The lattice parameters of DKDP vary smoothly upon heating to T s and are 0.2% to 0.6% greater than those of its isostructural hydrogenated counterpart KH 2 PO 4 (KDP). In addition, XRD isotherms collected at T s demonstrate the structural and chemical stability of the title compound at this temperature over a 10.5 h time period. Upon further heating, however, the tetragonal DKDP phase becomes unstable, as evidenced by its transition to a monoclinic DKDP modification and eventual chemical decomposition via dehydration. - Highlights: • Structural and chemical behavior of KD 2 PO 4 is investigated upon heating to 215 °C • No polymorphic transitions or deuterium-hydrogen isotope exchange below T s = 185 °C • KD 2 PO 4 is structurally and chemically stable at T s over a 10.5 h time period • KD 2 PO 4 chemically decomposes via dehydration upon heating above T d = 195 °C

Direct measurements of adsorption heats of hydrogen on nano-porous carbons

International Nuclear Information System (INIS)

Akihiko, Matsumoto; Kazumasa, Yamamoto; Tomoyuki, Miyata

2005-01-01

Since a exciting report of hydrogen storage in single-walled carbon nano-tubes by Dillon and his colleagues [1], nano-porous carbon materials, such as carbon nano-tubes, carbon nano-horns and micro-porous activated carbon, have attracted considerable attention as hydrogen storage materials. Adsorption plays a predominating role in the hydrogen storage process on solid surfaces. The adsorption is a spontaneous process, which is caused by interaction between gas molecules and surface, hence, it is always exothermic process and observed as adsorption heats. For this reason, direct measurement of the adsorption heats by adsorption microcalorimetry would provide quantitative information on the strength of adsorption interaction and the adsorption mechanism. However, the adsorption amounts of hydrogen on carbon materials are far less than those of condensable vapors near room temperature due to low critical temperature of hydrogen (33.2 K), therefore, the adsorption heats can not be determined accurately at conventional measurement conditions near room temperature and the atmospheric pressure. This contribution reports the calorimetric characterization of hydrogen adsorption on nano-porous carbon materials at low temperature and high-pressure conditions. The high-pressure adsorption apparatus consists of a volumetric adsorption line connected to a twin-conduction type microcalorimeter. Activated carbon fibers (ACF, Ad'all Co.) of different micropore sizes (Table 1) were used as model adsorbents. Each ACF has slit-shaped micropores of uniform size [2]. The adsorption isotherms and differential heats of adsorption at high-pressure region from 0 to 10 MPa were simultaneously measured at isothermal condition from 203 to 298 K. The adsorption isotherms on ACF were of Henry type regardless of adsorption temperature and pore width; the uptakes increased linearly with equilibrium pressure. The adsorption isotherm at lower sorption temperature tended to show higher sorptivity

Isothermal oxidation behavior of ternary Zr-Nb-Y alloys at high temperature

Energy Technology Data Exchange (ETDEWEB)

Prajitno, Djoko Hadi, E-mail: djokohp@batan.go.id [Research Center for Nuclear Materials and Radiometry, Jl. Tamansari 71, Bandung 40132 (Indonesia); Soepriyanto, Syoni; Basuki, Eddy Agus [Metallurgy Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia); Wiryolukito, Slameto [Materials Engineering, Institute Technology Bandung, Jl. Ganesha 10, Bandung 40132 (Indonesia)

2014-03-24

The effect of yttrium content on isothermal oxidation behavior of Zr-2,5%Nb-0,5%Y, Zr-2,5%Nb-1%Y Zr-2,5%Nb-1,5%Y alloy at high temperature has been studied. High temperature oxidation carried out at tube furnace in air at 600,700 and 800°C for 1 hour. Optical microscope is used for microstructure characterization of the alloy. Oxidized and un oxidized specimen was characterized by x-ray diffraction. In this study, kinetic oxidation of Zr-2,5%Nb with different Y content at high temperature has also been studied. Characterization by optical microscope showed that microstructure of Zr-Nb-Y alloys relatively unchanged and showed equiaxed microstructure. X-ray diffraction of the alloys depicted that the oxide scale formed during oxidation of zirconium alloys is monoclinic ZrO2 while unoxidised alloy showed two phase α and β phase. SEM-EDS examination shows that depletion of Zr composition took place under the oxide layer. Kinetic rate of oxidation of zirconium alloy showed that increasing oxidation temperature will increase oxidation rate but increasing yttrium content in the alloys will decrease oxidation rate.

Thermodynamic analysis of water vapor sorption isotherms and mechanical properties of selected paper-based food packaging materials.

Science.gov (United States)

Rhim, Jong-Whan; Lee, Jun Ho

2009-01-01

Adsorption isotherms of 3 selected paper-based packaging materials, that is, vegetable parchment (VP) paper, Kraft paper, and solid-bleached-sulfate (SBS) paperboard, were determined at 3 different temperatures (25, 40, and 50 degrees C). The GAB isotherm model was found to fit adequately for describing experimental adsorption isotherm data for the paper samples. The monolayer moisture content of the paper samples decreased with increase in temperature, which is in the range of 0.0345 to 0.0246, 0.0301 to 0.0238, and 0.0318 to 0.0243 g water/g solid for the MG paper, the Kraft paper, and the SBS paperboard, respectively. The net isosteric heats of sorption (q(st)) for the paper samples decreased exponentially with increase in moisture content after reaching the maximum values of 18.51, 27.39, and 26.80 kJ/mol for the VP paper, the Kraft paper, and the SBS paperboard, respectively, at low-moisture content. The differential enthalpy and entropy of 3 paper samples showed compensation phenomenon with the isokinetic temperature of 399.7 K indicating that water vapor had been adsorbed onto the paper samples with the same mechanism. Depending on the paper material, tensile strength of paper samples was affected by moisture content.

Estimation of Surface Temperature and Heat Flux by Inverse Heat Transfer Methods Using Internal Temperatures Measured While Radiantly Heating a Carbon/Carbon Specimen up to 1920 F

Science.gov (United States)

Pizzo, Michelle; Daryabeigi, Kamran; Glass, David

2015-01-01

The ability to solve the heat conduction equation is needed when designing materials to be used on vehicles exposed to extremely high temperatures; e.g. vehicles used for atmospheric entry or hypersonic flight. When using test and flight data, computational methods such as finite difference schemes may be used to solve for both the direct heat conduction problem, i.e., solving between internal temperature measurements, and the inverse heat conduction problem, i.e., using the direct solution to march forward in space to the surface of the material to estimate both surface temperature and heat flux. The completed research first discusses the methods used in developing a computational code to solve both the direct and inverse heat transfer problems using one dimensional, centered, implicit finite volume schemes and one dimensional, centered, explicit space marching techniques. The developed code assumed the boundary conditions to be specified time varying temperatures and also considered temperature dependent thermal properties. The completed research then discusses the results of analyzing temperature data measured while radiantly heating a carbon/carbon specimen up to 1920 F. The temperature was measured using thermocouple (TC) plugs (small carbon/carbon material specimens) with four embedded TC plugs inserted into the larger carbon/carbon specimen. The purpose of analyzing the test data was to estimate the surface heat flux and temperature values from the internal temperature measurements using direct and inverse heat transfer methods, thus aiding in the thermal and structural design and analysis of high temperature vehicles.

Integration of Space Heating and Hot Water Supply in Low Temperature District Heating

DEFF Research Database (Denmark)

Elmegaard, Brian; Ommen, Torben Schmidt; Markussen, Michael

2014-01-01

pipes, where the water is at the highest temperature. The heat loss may be lowered by decreasing the temperatures in the network for which reason low temperature networks are proposed as a low loss solution for future district heating. However, the heating demand of the consumers involve both domestic......District heating makes it possible to provide heat for many consumers in an efficient manner. In particular, district heating based on combined heat and power production is highly efficient. One disadvantage of district heating is that there is a significant heat loss from the pipes...... to the surrounding ground. In larger networks involving both transmission and distribution systems, the heat loss is most significant from the distribution network. An estimate is that about 80-90 % of the heat loss occurs in the distribution system. In addition, the heat loss is naturally highest from the forward...

Investigation of a new methodology in high temperature oxidation application to commercial austenitic steels

Energy Technology Data Exchange (ETDEWEB)

Vangeli, P.; Ivarsson, B. [Avesta Sheffield, R and D (Sweden)

2001-07-01

Avesta Sheffield R and D has evaluated a scaling temperature for heat resistant steels from laboratory gravimetric measurements of cyclic exposures. In this paper, this old method is described. A new methodology, based on the results of isothermal and cyclic tests, is proposed and discussed. It includes isothermal and cyclic oxidation kinetics of different commercial austenitic steels. Oxidation of Avesta Sheffield 153MA, 253MA and 353MA and standard commercial heat resistant steels 309S, 310S and A800 have been investigated under isothermal and cyclic conditions, in air, in the temperature range 800-1200 C. For all alloys, oxidation rates obey a parabolic law below a critical temperature. The activation energies have been calculated. Kinetics of the cyclic tests show that a critical mass change corresponding to a critical thickness of the oxide scale is responsible for the spallation start. This thickness depends on the composition of the alloys, and is very much increased by alloying minor elements like Ce. (orig.)

Experimental study of water desorption isotherms and thin-layer convective drying kinetics of bay laurel leaves

Science.gov (United States)

Ghnimi, Thouraya; Hassini, Lamine; Bagane, Mohamed

2016-12-01

The aim of this work is to determine the desorption isotherms and the drying kinetics of bay laurel leaves ( Laurus Nobilis L.). The desorption isotherms were performed at three temperature levels: 50, 60 and 70 °C and at water activity ranging from 0.057 to 0.88 using the statistic gravimetric method. Five sorption models were used to fit desorption experimental isotherm data. It was found that Kuhn model offers the best fitting of experimental moisture isotherms in the mentioned investigated ranges of temperature and water activity. The Net isosteric heat of water desorption was evaluated using The Clausius-Clapeyron equation and was then best correlated to equilibrium moisture content by the empirical Tsami's equation. Thin layer convective drying curves of bay laurel leaves were obtained for temperatures of 45, 50, 60 and 70 °C, relative humidity of 5, 15, 30 and 45 % and air velocities of 1, 1.5 and 2 m/s. A non linear regression procedure of Levenberg-Marquardt was used to fit drying curves with five semi empirical mathematical models available in the literature, The R2 and χ2 were used to evaluate the goodness of fit of models to data. Based on the experimental drying curves the drying characteristic curve (DCC) has been established and fitted with a third degree polynomial function. It was found that the Midilli Kucuk model was the best semi-empirical model describing thin layer drying kinetics of bay laurel leaves. The bay laurel leaves effective moisture diffusivity and activation energy were also identified.

Assessment of Salmonella spp. and Escherichia coli O157:H7 growth on lettuce exposed to isothermal and non-isothermal conditions.

Science.gov (United States)

de Oliveira Elias, Susana; Noronha, Tiago Baptista; Tondo, Eduardo Cesar

2018-06-01

This study aimed to assess the growth of Salmonella and Escherichia coli O157:H7 on lettuce exposed to isothermal and non-isothermal conditions. Pathogens were inoculated on lettuce separately and stored under isothermal condition at 5 °C, 10 °C, 25 °C, 37 °C for both bacteria, at 40 °C for Salmonella and 42 °C for E. coli O157:H7. Growth curves were built by fitting the data to the Baranyi's DMFit, generating R 2 values greater than 0.92 for primary models. Secondary models were fitted with Ratkowsky equations, generating R 2 values higher than 0.91 and RMSE lower than 0.1. Experimental data showed that both bacteria could grow at all temperatures. Also, the growth of both pathogens under non-isothermal conditions was studied simulating temperatures found from harvest to supermarkets in Brazil. Models were analysed by R 2 , RMSE, bias factor (Bf) and accuracy factor (Af). Salmonella and E. coli O157:H7 were able to grow in this temperature profile and the models could predict the behavior of these microorganisms on lettuce under isothermal and non-isothermal conditions. Based on the results, a negligible growth time (ς) was proposed to provide the time which lettuce could be exposed to a specific temperature and do not present an expressive growth of bacteria. The ς was developed based on Baranyi's primary model equation and on growth potential concept. ς is the value of lag phase added of the time necessary to population grow 0.5 log CFU/g. The ς of lettuce exposed to 37 °C was 1.3 h, while at 5 °C was 3.3 days. Copyright © 2017 Elsevier Ltd. All rights reserved.

Mathematical Modeling of the Thermal State of an Isothermal Element with Account of the Radiant Heat Transfer Between Parts of a Spacecraft

Science.gov (United States)

Alifanov, O. M.; Paleshkin, A. V.; Terent‧ev, V. V.; Firsyuk, S. O.

2016-01-01

A methodological approach to determination of the thermal state at a point on the surface of an isothermal element of a small spacecraft has been developed. A mathematical model of heat transfer between surfaces of intricate geometric configuration has been described. In this model, account was taken of the external field of radiant fluxes and of the differentiated mutual influence of the surfaces. An algorithm for calculation of the distribution of the density of the radiation absorbed by surface elements of the object under study has been proposed. The temperature field on the lateral surface of the spacecraft exposed to sunlight and on its shady side has been calculated. By determining the thermal state of magnetic controls of the orientation system as an example, the authors have assessed the contribution of the radiation coming from the solar-cell panels and from the spacecraft surface.

Hyperbolic heat conduction, effective temperature, and third law for nonequilibrium systems with heat flux

Science.gov (United States)

Sobolev, S. L.

2018-02-01

Some analogies between different nonequilibrium heat conduction models, particularly random walk, the discrete variable model, and the Boltzmann transport equation with the single relaxation time approximation, have been discussed. We show that, under an assumption of a finite value of the heat carrier velocity, these models lead to the hyperbolic heat conduction equation and the modified Fourier law with relaxation term. Corresponding effective temperature and entropy have been introduced and analyzed. It has been demonstrated that the effective temperature, defined as a geometric mean of the kinetic temperatures of the heat carriers moving in opposite directions, acts as a criterion for thermalization and is a nonlinear function of the kinetic temperature and heat flux. It is shown that, under highly nonequilibrium conditions when the heat flux tends to its maximum possible value, the effective temperature, heat capacity, and local entropy go to zero even at a nonzero equilibrium temperature. This provides a possible generalization of the third law to nonequilibrium situations. Analogies and differences between the proposed effective temperature and some other definitions of a temperature in nonequilibrium state, particularly for active systems, disordered semiconductors under electric field, and adiabatic gas flow, have been shown and discussed. Illustrative examples of the behavior of the effective temperature and entropy during nonequilibrium heat conduction in a monatomic gas and a strong shockwave have been analyzed.

Low-temperature heating systems and public administration

Energy Technology Data Exchange (ETDEWEB)

Boerner, H

1981-06-01

The even temperature distribution and comfortable climate in rooms heated by low-temperature heating systems is mostly due to one of the preconditions of this type of heating system namely, efficient thermal insulation of the rooms. Thermal insulation is already required as part of the pertinent legal regulations but it is also in the interest of the builder-owner as it will, in the long run, greatly reduce the heating cost.

Post synthetic modification of MIL-101(Cr) for S-shaped isotherms and fast kinetics with water adsorption

International Nuclear Information System (INIS)

Teo, How Wei Benjamin; Chakraborty, Anutosh; Kayal, Sibnath

2017-01-01

Highlights: • Modification of parent MIL-101(Cr) metal organic framework (MOF) employing alkali metal ions (Li + , Na + , K + ). • Surface characteristics of the parent and alkali doped MIL-101(Cr) adsorbents. • Water uptakes are measured for the temperatures ranging from 25 °C to 60 °C under static and dynamic conditions. • Isotherms and kinetics data are fitted with Langmuir analogy models. • The 5% Li-doped MIL-101(Cr) is suitable for adsorption cooling. - Abstract: This article presents the surface characteristics of alkali (Li + , Na + , K + ) doped MIL-101(Cr) metal organic frameworks (MOFs), and the structural properties are evaluated by scanning electron micrography (SEM), X-ray diffraction (XRD), thermo-gravimetric analyser (TGA) and N 2 adsorption analysis. The amount of water uptakes are measured by a gravimetric analyser for the temperatures ranging from 298 K to 333 K and pressures up to the saturated conditions. The experimentally measured isotherms and kinetics data are fitted with the equations developed from the concept of Langmuir analogy. The isosteric heat of adsorption is calculated employing Van’t Hoff equation in the pressure-temperature-uptake co-ordinate systems. The hydrophobic length at low pressure regions is shortened by the addition of alkali dopants. It is observed that the alkali (Na, K and Li) ions on MIL-101(Cr) MOF increase the water uptakes at lower relative pressure region with fast kinetics. We have shown here that the alkali doped MIL-101(Cr) MOFs can be used as potential adsorbents for various low temperature heat transmission applications such as adsorption assisted heat pump, cooling and desalination.

Self-heating, gamma heating and heat loss effects on resistance temperature detector (RTD) accuracy

International Nuclear Information System (INIS)

Qian, T.; Hinds, H.W.; Tonner, P.

1997-01-01

Resistance temperature detectors (RTDs) are extensively used in CANDU nuclear power stations for measuring various process and equipment temperatures. Accuracy of measurement is an important performance parameter of RTDs and has great impact on the thermal power efficiency and safety of the plant. There are a number of factors that contribute to some extent to RTD measurement error. Self-heating, gamma heating and the heat-loss throughout conduction of the thermowell are three of these factors. The degree to which these three affect accuracy of RTDs used for the measurement of reactor inlet header temperature (RIHT) has been analyzed and is presented in this paper. (author)

Isothermal Stability and Selected Mechanical Properties of Zr48Cu36Al8Ag8 Bulk Metallic Glass

Directory of Open Access Journals (Sweden)

Błyskun P.

2017-09-01

Full Text Available The aim of this work was to investigate the influence of isothermal annealing on the amorphous structure stability of the Zr48Cu36Al8Ag8 alloy. A series of continuous heating examinations was performed on the differential scanning calorimeter in order to determine the temperature limits for isothermal annealing series where the time to crystallization was measured. The obtained results were calculated and a time-temperature-transformation diagram was created and discussed. Static compression test as well as microhardness measurements of the as-quenched samples gave a mechanical properties results supplement. The measured properties (σc = 1800 MPa and 614 HV0.05 are comparable to the literature results for this alloy. Fractographic observations with the scanning electron microscope were also performed in order to prove some plasticity observed during the strength tests.

Survey of high-temperature nuclear heat application

International Nuclear Information System (INIS)

Kirch, N.; Schaefer, M.

1984-01-01

Nuclear heat application at high temperatures can be divided into two areas - use of high-temperature steam up to 550 deg. C and use of high-temperature helium up to about 950 deg. C. Techniques of high-temperature steam and heat production and application are being developed in several IAEA Member States. In all these countries the use of steam for other than electricity production is still in a project definition phase. Plans are being discussed about using steam in chemical industries, oil refineries and for new synfuel producing plants. The use of nuclear generated steam for oil recovery from sands and shale is also being considered. High-temperature nuclear process heat production gives new possibilities for the application of nuclear energy - hard coals, lignites, heavy oils, fuels with problems concerning transport, handling and pollution can be converted into gaseous or liquid energy carriers with no loss of their energy contents. The main methods for this conversion are hydrogasification with hydrogen generated by nuclear heated steam reformers and steam gasification. These techniques will allow countries with large coal resources to replace an important part of their natural gas and oil consumption. Even countries with no fossil fuels can benefit from high-temperature nuclear heat - hydrogen production by thermochemical water splitting, nuclear steel making, ammonia production and the chemical heat-pipe system are examples in this direction. (author)

Diagnostic Devices for Isothermal Nucleic Acid Amplification

Directory of Open Access Journals (Sweden)

Chia-Chen Chang

2012-06-01

Full Text Available Since the development of the polymerase chain reaction (PCR technique, genomic information has been retrievable from lesser amounts of DNA than previously possible. PCR-based amplifications require high-precision instruments to perform temperature cycling reactions; further, they are cumbersome for routine clinical use. However, the use of isothermal approaches can eliminate many complications associated with thermocycling. The application of diagnostic devices for isothermal DNA amplification has recently been studied extensively. In this paper, we describe the basic concepts of several isothermal amplification approaches and review recent progress in diagnostic device development.

Diagnostic devices for isothermal nucleic acid amplification.

Science.gov (United States)

Chang, Chia-Chen; Chen, Chien-Cheng; Wei, Shih-Chung; Lu, Hui-Hsin; Liang, Yang-Hung; Lin, Chii-Wann

2012-01-01

Since the development of the polymerase chain reaction (PCR) technique, genomic information has been retrievable from lesser amounts of DNA than previously possible. PCR-based amplifications require high-precision instruments to perform temperature cycling reactions; further, they are cumbersome for routine clinical use. However, the use of isothermal approaches can eliminate many complications associated with thermocycling. The application of diagnostic devices for isothermal DNA amplification has recently been studied extensively. In this paper, we describe the basic concepts of several isothermal amplification approaches and review recent progress in diagnostic device development.

Stirling Engine With Radial Flow Heat Exchangers

Science.gov (United States)

Vitale, N.; Yarr, George

1993-01-01

Conflict between thermodynamical and structural requirements resolved. In Stirling engine of new cylindrical configuration, regenerator and acceptor and rejector heat exchangers channel flow of working gas in radial direction. Isotherms in regenerator ideally concentric cylinders, and gradient of temperature across regenerator radial rather than axial. Acceptor and rejector heat exchangers located radially inward and outward of regenerator, respectively. Enables substantial increase in power of engine without corresponding increase in diameter of pressure vessel.

District Heating Expansion Potential with Low-Temperature and End-Use Heat Savings

DEFF Research Database (Denmark)

Nielsen, Steffen; Grundahl, Lars

2018-01-01

District heating has the potential to play a key role in the transition towards a renewable energy system. However, the development towards reduced heat demands threatens the feasibility of district heating. Despite this challenge, opportunity exists in the form of fourth generation district...... heating, which operates at lower temperatures and enables better renewable integration. This article investigates this challenge by examining the district heating potential within three scenarios: The first is a reference scenario with current heat demand and temperatures, the second includes heat demand...... costs. The models are applied using an example case of The Northern Region of Denmark. The article concludes that the district heating potential is highest in the reference scenario. When heat savings are introduced, district heating expansions, in most cases, will not be feasible. Introducing low...

Utilization of low-temperature heat sources for heat and power production

DEFF Research Database (Denmark)

Haglind, Fredrik; Elmegaard, Brian

2014-01-01

Low-temperature heat sources are available in many applications, ranging from waste heat from marine diesel engines, industries and refrigeration plants to biomass, geothermal and solar heat sources. There is a great potential for enhancing the utilization of these heat sources by novel...

Empirical equation to let reproducing the temperature field of air around a horizontal isothermal cylinder in natural convection case

International Nuclear Information System (INIS)

Diez Gonzalez, R.; Dolz, M.; Belsa, R.; Herraez, J.V.

1988-01-01

The analysis of 7.000 measured pairs of values, distance-temperature, of air around a horizontal isothermal cylinder has made possible to obtain an empirical simple equation to let reproducing the temperature field of air in the natural convection case. The experimental and calculated results for a cylinder of 1 cm diameter and 10.5 cm length are compared with the same given for other authors. (Author)

P, ρ, T and heat capacity measurements of (α-pinene + β-pinene) mixtures over the temperature range 283.15 K to 358.15 K and pressures up to 40 MPa: Experiments and modelling

International Nuclear Information System (INIS)

Langa, Elisa; Palavra, Antonio M.F.; Lourenço, Maria J.V.; Nieto de Castro, Carlos A.; Mainar, Ana M.

2013-01-01

Highlights: ► Density as a function of P, T and composition was measured for pinene mixtures. ► Isothermal compressibility and coefficients of cubic expansion were also calculated. ► Isobaric heat capacity was also determined as function of temperature and composition. ► Usual behaviour of these properties was found. ► SAFT and PC-SAFT were used as predictive models, showing PC-SAFT the best predictions. - Abstract: The density and isobaric heat capacity of the binary system {α-pinene (4,7,7-trimethylbicyclo[3.1.1]hept-3-ene (1), CAS Number 7785-26-4) + β-pinene (6,6-dimethyl-2-methylene-bicyclo[3.1.1]heptane (2), CAS Number 127-91-3)} has been measured for eleven different compositions. The density was determined at five pressures from (20 MPa to 40 MPa) and temperatures from (283.15 K to 358.15 K) and the isobaric heat capacity at atmospheric pressure and temperatures from (313.15 K to 418.15 K). Density was measured with an experimental uncertainty estimated to be ± 0.5 kg·m −3 . The isothermal compressibility and isobaric thermal expansion were derived from the experimental density data. The isobaric heat capacity was determined with a DSC calorimeter being the experimental uncertainty lower than 1.5%. Isobaric heat capacity behaviour was as expected for both pure compounds and for mixtures. Two different equations of state, conventional SAFT and PC-SAFT, were applied to calculate the densities of the mixture, being the best predictions achieved with PC-SAFT equation.

Power generation from low-temperature heat source

Energy Technology Data Exchange (ETDEWEB)

Lakew, Amlaku Abie

2012-07-01

The potential of low-temperature heat sources for power production has been discussed for decades. The diversity and availability of low-temperature heat sources makes it interesting for power production. The thermodynamic power cycle is one of the promising technologies to produce electricity from low-temperature heat sources. There are different working fluids to be used in a thermodynamic power cycle. Working fluid selection is essential for the performance of the power cycle. Over the last years, different working fluid screening criteria have been used. In broad speaking the screening criteria can be grouped as thermodynamic performance, component size requirement, economic performance, safety and environmental impact. Screening of working fluids at different heat source temperatures (80-200 Celsius degrees) using thermodynamic performance (power output and exergy efficiency) and component size (heat exchanger and turbine) is investigated. It is found that the 'best' working fluid depends on the criteria used and heat source temperature level. Transcritical power cycles using carbon dioxide as a working fluid is studied to produce power at 100 Celsius degrees. Carbon dioxide is an environmentally friendly refrigerant. The global warming potential of carbon dioxide is 1. Furthermore, because of its low critical temperature (31 Celsius degrees), carbon dioxide can operate in a transcritical power cycle for lower heat source temperatures. A transcritical configuration avoids the problem of pinching which otherwise would happened in subcritical power cycle. In the process, better temperature matching is achieved and more heat is extracted. Thermodynamic analysis of transcritical cycle is performed; it is found that there is an optimal operating pressure for highest net power output. The pump work is a sizable fraction of the work produced by the turbine. The effect of efficiency deterioration of the pump and the turbine is compared. When the

TOURGHREACT: A Simulation Program for Non-isothermal Multiphase Reactive Geochemical Transport in Variably Saturated Geologic Media

OpenAIRE

Xu, Tianfu; Sonnenthal, Eric; Spycher, Nicolas; Pruess, Karsten

2004-01-01

TOUGHREACT is a numerical simulation program for chemically reactive non-isothermal flows of multiphase fluids in porous and fractured media. The program was written in Fortran 77 and developed by introducing reactive geochemistry into the multiphase fluid and heat flow simulator TOUGH2. A variety of subsurface thermo-physical-chemical processes are considered under a wide range of conditions of pressure, temperature, water saturation, ionic strength, and pH and Eh. Interactions between ...

MEASUREMENT OF SPECIFIC HEAT CAPACITY OF SALTSTONE

International Nuclear Information System (INIS)

Harbour, J.; Williams, V.

2008-01-01

One of the goals of the Saltstone variability study is to identify (and quantify the impact of) the operational and compositional variables that control or influence the important processing and performance properties of Saltstone grout mixtures. The heat capacity of the Saltstone waste form is one of the important properties of Saltstone mixes that was last measured at SRNL in 1997. It is therefore important to develop a core competency for rapid and accurate analysis of the specific heat capacity of the Saltstone mixes in order to quantify the impact of compositional and operational variations on this property as part of the variability study. The heat capacity, coupled with the heat of hydration data obtained from isothermal calorimetry for a given Saltstone mix, can be used to predict the maximum temperature increase in the cells within the vaults of the Saltstone Disposal Facility (SDF). The temperature increase controls the processing rate and the pour schedule. The maximum temperature is also important to the performance properties of the Saltstone. For example, in mass pours of concrete or grout of which Saltstone is an example, the maximum temperature increase and the maximum temperature difference (between the surface and the hottest location) are controlled to ensure durability of the product and prevent or limit the cracking caused by the thermal gradients produced during curing. This report details the development and implementation of a method for the measurement of the heat capacities of Saltstone mixes as well as the heat capacities of the cementitious materials of the premix and the simulated salt solutions used to batch the mixes. The developed method utilizes the TAM Air isothermal calorimeter and takes advantage of the sophisticated heat flow measurement capabilities of the instrument. Standards and reference materials were identified and used to validate the procedure and ensure accuracy of testing. Heat capacities of Saltstone mixes were �

MEASUREMENT OF SPECIFIC HEAT CAPACITY OF SALTSTONE

Energy Technology Data Exchange (ETDEWEB)

Harbour, J; Vickie Williams, V

2008-09-29

One of the goals of the Saltstone variability study is to identify (and quantify the impact of) the operational and compositional variables that control or influence the important processing and performance properties of Saltstone grout mixtures. The heat capacity of the Saltstone waste form is one of the important properties of Saltstone mixes that was last measured at SRNL in 1997. It is therefore important to develop a core competency for rapid and accurate analysis of the specific heat capacity of the Saltstone mixes in order to quantify the impact of compositional and operational variations on this property as part of the variability study. The heat capacity, coupled with the heat of hydration data obtained from isothermal calorimetry for a given Saltstone mix, can be used to predict the maximum temperature increase in the cells within the vaults of the Saltstone Disposal Facility (SDF). The temperature increase controls the processing rate and the pour schedule. The maximum temperature is also important to the performance properties of the Saltstone. For example, in mass pours of concrete or grout of which Saltstone is an example, the maximum temperature increase and the maximum temperature difference (between the surface and the hottest location) are controlled to ensure durability of the product and prevent or limit the cracking caused by the thermal gradients produced during curing. This report details the development and implementation of a method for the measurement of the heat capacities of Saltstone mixes as well as the heat capacities of the cementitious materials of the premix and the simulated salt solutions used to batch the mixes. The developed method utilizes the TAM Air isothermal calorimeter and takes advantage of the sophisticated heat flow measurement capabilities of the instrument. Standards and reference materials were identified and used to validate the procedure and ensure accuracy of testing. Heat capacities of Saltstone mixes were

Estimating temperature reactivity coefficients by experimental procedures combined with isothermal temperature coefficient measurements and dynamic identification

International Nuclear Information System (INIS)

Tsuji, Masashi; Aoki, Yukinori; Shimazu, Yoichiro; Yamasaki, Masatoshi; Hanayama, Yasushi

2006-01-01

A method to evaluate the moderator coefficient (MTC) and the Doppler coefficient through experimental procedures performed during reactor physics tests of PWR power plants is proposed. This method combines isothermal temperature coefficient (ITC) measurement experiments and reactor power transient experiments at low power conditions for dynamic identification. In the dynamic identification, either one of temperature coefficients can be determined in such a way that frequency response characteristics of the reactivity change observed by a digital reactivity meter is reproduced from measured data of neutron count rate and the average coolant temperature. The other unknown coefficient can also be determined by subtracting the coefficient obtained from the dynamic identification from ITC. As the proposed method can directly estimate the Doppler coefficient, the applicability of the conventional core design codes to predict the Doppler coefficient can be verified for new types of fuels such as mixed oxide fuels. The digital simulation study was carried out to show the feasibility of the proposed method. The numerical analysis showed that the MTC and the Doppler coefficient can be estimated accurately and even if there are uncertainties in the parameters of the reactor kinetics model, the accuracies of the estimated values are not seriously impaired. (author)

The Dependence of the Dose Response Supralinearity of Peak 5 in TLD-100 on Recombination Temperature

International Nuclear Information System (INIS)

Horowitz, Y.S.; Satinger, D.; Oster, L.

1999-01-01

Isothermal readout of LiF:Mg,Ti (TLD-700) has recently been used to study the dependence of the supralinearity of peak 5 on recombination temperature. The results were interpreted to be in conflict with earlier results which investigated the effect of readout heating rate on the supralinearity of peak 5 in TLD-100. In this work the two experiments are inspected in greater detail. It is illustrated that the isothermal decay data is not in conflict with the heating rate data. However, the heating rate results do apparently indicate a strong transition in the temperature dependence of the relative strengths of the recombination and competitive cross sections at approximately 235 deg. C, which requires further study and analysis. (author)

Temperature control for high pressure processes up to 1400 MPa

International Nuclear Information System (INIS)

Reineke, K; Mathys, A; Knorr, D; Heinz, V

2008-01-01

Pressure- assisted sterilisation is an emerging technology. Hydrostatic high pressure can reduce the thermal load of the product and this allows quality retention in food products. To guarantee the safety of the sterilisation process it is necessary to investigate inactivation kinetics especially of bacterial spores. A significant roll during the inactivation of microorganisms under high pressure has the thermodynamic effect of the adiabatic heating. To analyse the individual effect of pressure and temperature on microorganism inactivation an exact temperature control of the sample to reach ideal adiabatic conditions and isothermal dwell times is necessary. Hence a heating/cooling block for a high pressure unit (Stansted Mini-Food-lab; high pressure capillary with 300 μL sample volume) was constructed. Without temperature control the sample would be cooled down during pressure built up, because of the non-adiabatic heating of the steel made vessel. The heating/cooling block allows an ideal adiabatic heat up and cooling of the pressure vessel during compression and decompression. The high pressure unit has a pressure build-up rate up to 250 MPa s -1 and a maximum pressure of 1400 MPa. Sebacate acid was chosen as pressure transmitting medium because it had no phase shift over the investigate pressure and temperature range. To eliminate the temperature difference between sample and vessel during compression and decompression phase, the mathematical model of the adiabatic heating/cooling of water and sebacate acid was implemented into a computational routine, written in Test Point. The calculated temperature is the setpoint of the PID controller for the heating/cooling block. This software allows an online measurement of the pressure and temperature in the vessel and the temperature at the outer wall of the vessel. The accurate temperature control, including the model of the adiabatic heating opens up the possibility to realise an ideal adiabatic heating and cooling

Rapid self-heating and internal temperature sensing of lithium-ion batteries at low temperatures

International Nuclear Information System (INIS)

Zhang, Guangsheng; Ge, Shanhai; Xu, Terrence; Yang, Xiao-Guang; Tian, Hua; Wang, Chao-Yang

2016-01-01

Highlights: • Self-heating lithium-ion battery (SHLB) structure provided a practical solution to the poor performance at subzero temperatures. • We report an improved SHLB that heats from −20 °C to 0 °C in 12.5 seconds, or 56% more rapidly, while consuming 24% less energy than previously reported. • The nickel foil heating element embedded inside a SHLB cell plays a dominant role in rapid self-heating. • The embedded nickel foil can simultaneously perform as an internal temperature sensor (ITS). • 2-sheet design self-heats faster than 1-sheet design due to more uniform internal temperature distribution. - Abstract: The recently discovered self-heating lithium-ion battery structure provided a practical solution to the poor performance at subzero temperatures that has hampered battery technology for decades. Here we report an improved self-heating lithium-ion battery (SHLB) that heats from −20 °C to 0 °C in 12.5 seconds, or 56% more rapidly, while consuming 24% less energy than that reported previously. We reveal that a nickel foil heating element embedded inside a SHLB cell plays a dominant role in self-heating and we experimentally demonstrate that a 2-sheet design can achieve dramatically accelerated self-heating due to more uniform internal temperature distribution. We also report, for the first time, that this embedded nickel foil can simultaneously perform as an internal temperature sensor (ITS) due to the perfectly linear relationship between the foil’s electrical resistance and temperature.

Challenges in Smart Low-Temperature District Heating Development

DEFF Research Database (Denmark)

Li, Hongwei; Wang, Stephen Jia

2014-01-01

Previous research and development shows that low temperature district heating (LTDH) system is economic feasible for low energy buildings and buildings at sparse areas. Coupling with reduced network temperature and well-designed district heating (DH) networks, LTDH can reduce network heat loss by...

Isotherms and isosteric heat of sorption of two varieties of Peruvian quinoa

OpenAIRE

Augusto Pumacahua-Ramos; José Antonio Gomez Vieira; Javier Telis-Romero; Harvey Alexander Villa-Vélez; Jose Francisco Lopes Filho

2016-01-01

The isosteric heats of sorption of two varieties of quinoa (Chenopodium quinoaWilld.) grain were determined by the static gravimetric method at four temperatures (40, 50, 60 and 70 °C) andin relative humidity environments provided by six saturated salt solutions. Six mathematical equations were used to model the experimental data: GAB, Oswin, Henderson, Peleg, Smith and Halsey. The isosteric heat of sorption was determined using the parameters ...

Soft computing modelling of moisture sorption isotherms of milk-foxtail millet powder and determination of thermodynamic properties.

Science.gov (United States)

Simha, H V Vikram; Pushpadass, Heartwin A; Franklin, Magdaline Eljeeva Emerald; Kumar, P Arun; Manimala, K

2016-06-01

Moisture sorption isotherms of spray-dried milk-foxtail millet powder were determined at 10, 25 and 40 °C. Sorption data was fitted using classical and soft-computing approaches. The isotherms were of type II, and equilibrium moisture content (EMC) was temperature dependent. The BET monolayer moisture content decreased from 3.30 to 2.67 % as temperature increased from 10 to 40 °C. Amongst the classical models, Ferro-Fontan gave the best fit of EMC-aw data. However, the Sugeno-type adaptive neuro-fuzzy inference system (ANFIS) with generalized bell-shaped membership function performed better than artificial neural network and classical models with RMSE as low as 0.0099. The isosteric heat of sorption decreased from 150.32 kJ mol(-1) at 1 % moisture content to 44.11 kJ mol(-1) at 15 % moisture. The enthalpy-entropy compensation theory was validated, and the isokinetic and harmonic mean temperatures were determined as 333.1 and 297.5 K, respectively.

Empirical equation to let reproducing the temperature field of air around a horizontal isothermal cylinder in natural convection case

Energy Technology Data Exchange (ETDEWEB)

Diez Gonzalez, R.; Dolz, M.; Belsa, R.; Herraez, J.V.

1988-01-01

The analysis of more or 7.000 measured pairs of values, diatance-temperature, of air around a horizontal isothermal cylinder has made it possible to obtain a empirical simple equation to let reproducing the temperature field of air in the natural convection case. The experimental and calculated results for a cylinder of 1 cm diameter and 10.5 cm length are compared with the same fiven for others authors

Thermodynamic and transport properties of (1-Butanol + 1,4-Butanediol) at temperatures from (298.15 to 318.15) K

International Nuclear Information System (INIS)

Zorebski, Edward; Geppert-Rybczynska, Monika

2010-01-01

Densities and kinematic viscosities have been measured for (1-butanol + 1,4-butanediol) over the temperature range from (298.15 to 318.15) K. The speeds of sound within the temperature range from (293.15 to 318.15) K have been measured as well. Using these results and literature values of isobaric heat capacities, the molar volumes, isentropic and isothermal compressibility coefficients, molar isentropic and isothermal compressibilities, isochoric heat capacities as well as internal pressures were calculated. Also the corresponding excess and deviation values (excess molar volumes, excess isentropic and isothermal compressibility coefficients, excess molar isentropic and isothermal compressibilities, different defined deviation speed of sound and dynamic viscosity deviations) were calculated. The excess values are negative over the whole concentration and temperature range. The excess and deviation values are expressed by Redlich-Kister polynomials and discussed in terms of the variations of the structure of the system caused by the participation of the two different alcohol molecules in the dynamic intermolecular association process through hydrogen bonding at various temperatures. The predictive abilities of Grunberg-Nissan and McAllister equations for viscosities of mixtures have also been examined.

Isothermal calorimeter for reactor radiation dosimetry

Energy Technology Data Exchange (ETDEWEB)

Radak, B; Markovic, V [Institute of Nuclear Sciences Boris Kidric, Odeljenje za radijacionu hemiju, Vinca, Beograd (Serbia and Montenegro)

1961-12-15

An isothermal calorimeter with thermistors for measuring absorbed dose rates from 10{sup 4}-5-6.10{sup 5} rad/h in reactor experimental holes has been designed. A kinetics method for determining the equilibrium temperature difference has been developed, and its application in isothermal calorimetry proved. The expected accuracy in measurements within {+-} 2-5% has been proved by measurements carried out in the reactor. Some data obtained by measurements in the reactor RA are presented (author)

On the question of heat engine cycles optimization

Directory of Open Access Journals (Sweden)

Костянтин Ігорович Ткаченко

2015-10-01

Full Text Available It is known that the efficiency of heat engines nowadays isn’t more than 50-60% for prototypes and maximum possible efficiency of a heat engine is considered Carnot cycle efficiency Thus, at least 40% of the disposable amount of heat is lost in the surrounding medium, unless the waste gases heat is utilized somehow. General idea of heat engines cycles is the transfer of energy from the heater (both external and internal to a working fluid, obtaining mechanical work from expanding of the working fluid, and returning the working fluid to the initial state by compression and excess heat discharge into a cooler. In this paper the combination of a heat engine operating according to the standard Edwards cycle and consisting of isochor, adiabat and isotherm, and the heat pump, using the reverse Carnot cycle is investigated. The heat pump partially picks out the heat of the working fluid at its isothermal compression, and returns it to the equivalent working fluid or regenerator cap, at the beginning of isochoric heating. The efficiency coefficient of the heat pump, and thus the work to putting it into action is calculated by proper equations at the constant temperature of the low-potential heat source (working fluid and variable temperature of the heated equivalent of the working fluid or the regenerator cap. Taking as an example selected quantitative parameters of the Edwards cycle it has been proved that the use of the heat pump increases the effective efficiency of combined cycle as compared to the basic one. In addition, it has been shown that the dependence of the efficiency on the degree of heat return is not monotonic and has a maximum

Lattice Boltzmann analysis of effect of heating location and Rayleigh number on natural convection in partially heated open ended cavity

Energy Technology Data Exchange (ETDEWEB)

Gangawane, Krunal Madhukar; Bharti, Ram Prakash; Kumar, Surendra [Indian Institute of Technology Roorkee, Uttarakhand (India)

2015-08-15

Natural convection characteristics of a partially heated open ended square cavity have been investigated numerically by using an in-house computational flow solver based on the passive scalar thermal lattice Boltzmann method (PS-TLBM) with D2Q9 (two-dimensional and nine-velocity link) lattice model. The partial part of left wall of the cavity is heated isothermally at either of the three different (bottom, middle and top) locations for the fixed heating length as half of characteristic length (H/2) while the right wall is open to the ambient conditions. The other parts of the cavity are thermally isolated. In particular, the influences of partial heating locations and Rayleigh number (103≤ Ra≤106) in the laminar zone on the local and global natural convection characteristics (such as streamline, vorticity and isotherm contours; centerline variations of velocity and temperature; and local and average Nusselt numbers) have been presented and discussed for the fixed value of the Prandtl number (Pr=0.71). The streamline patterns show qualitatively similar nature for all the three heating cases and Rayleigh numbers, except the change in the recirculation zone which is found to be largest for middle heating case. Isotherm patterns are shifted towards a partially heated wall on increasing Rayleigh number and/or shifting of heating location from bottom to top. Both the local and average Nusselt numbers, as anticipated, shown proportional increase with Rayleigh number. The cavity with middle heating location shown higher heat transfer rate than that for the top and bottom heating cases. Finally, the functional dependence of the average Nusselt number on flow governing parameters is also presented as a closure relationship for the best possible utilization in engineering practices and design.

Application of Abaqus to analysis of the temperature field in elements heated by moving heat sources

Directory of Open Access Journals (Sweden)

W. Piekarska

2010-10-01

Full Text Available Numerical analysis of thermal phenomena occurring during laser beam heating is presented in this paper. Numerical models of surface andvolumetric heat sources were presented and the influence of different laser beam heat source power distribution on temperature field wasanalyzed. Temperature field was obtained by a numerical solution the transient heat transfer equation with activity of inner heat sources using finite element method. Temperature distribution analysis in welded joint was performed in the ABAQUS/Standard solver. The DFLUXsubroutine was used for implementation of the movable welding heat source model. Temperature-depended thermophysical properties for steelwere assumed in computer simulations. Temperature distribution in laser beam surface heated and butt welded plates was numericallyestimated.

Mapping of low temperature heat sources in Denmark

DEFF Research Database (Denmark)

Bühler, Fabian; Holm, Fridolin Müller; Huang, Baijia

2015-01-01

heat. The total accessible waste heat potential is found to be approximately 266 PJ per year with 58 % of it below 100 °C. In the natural heat category, temperatures below 20 °C originate from ambient air, sea water and shallow geothermal energy, and temperatures up to 100 °C are found for solar...... and deep geothermal energy. The theoretical solar thermal potential alone would be above 500 PJ per year. For the development of advanced thermodynamic cycles for the integration of heat sources in the Danish energy system, several areas of interest are determined. In the maritime transport sector a high......Low temperature heat sources are available in many applications, ranging from waste heat from industrial processes and buildings to geothermal and solar heat sources. Technical advancements, such as heat pumps with novel cycle design and multi-component working fluids, make the utilisation of many...

Martensitic transformation behaviour in sensitized SUS304 austenitic stainless steel during isothermal holding at low temperature

International Nuclear Information System (INIS)

Lee, Jae-hwa; Fukuda, Takashi; Kakeshita, Tomoyuki

2009-01-01

We investigated martensitic transformation behaviour in sensitized SUS304 austenitic stainless steel to determine the stability of the austenitic phase at low temperatures. We found that a specimen that was sensitized at 973 K for 100 h exhibits an isothermal martensitic transformation when the specimen is held in the temperature range between 60 and 260 K. We constructed a time-temperature-transformation (TTT) diagram corresponding to the formation of 0.5 vol. % α'-martensite. A magnetization measurement was used to evaluate the volume fraction of a'-martensite. The TTT diagram shows a double-C curve with two noses located at about 100 and 200 K. In-situ optical microscope observations reveal that the double C-curve is due to two different transformation sequences. That is, the upper part of the C-curve is due to a direct γ → α' martensitic transformation and the lower part of the C-curve is due to a successive γ → ψ → α' martensitic transformation. The direct γ → α' transformation occurs in the vicinity of grain boundaries while the successive γ → ψ' → α' transformation occurs near the centre of grains. A scanning electron microscope observation reveals that carbide particles of M 23 C 6 are formed in the grain boundaries. The concentration difference between the centre of the grains and regions near grain boundaries is the reason for the difference in the isothermal transformation sequence for the sensitized SUS304 stainless steel.

Effect of radiant heat transfer on the performance of high temperature heat exchanger

International Nuclear Information System (INIS)

Mori, Yasuo; Hijikata, Kunio; Yamada, Yukio

1975-01-01

The development of high temperature gas-cooled reactors is motivated by the consideration of the application of nuclear heat for industrial uses or direct steelmaking and chemical processes. For these purposes, reliable and efficient heat exchangers should be developed. This report analyzes the effect of radiant heat transfer on the performance of high temperature heat exchangers. The heat transfer model is as follows: the channel composed with two parallel adiabatic walls is divided with one parallel plate between the walls. Non-radiative fluid flows in the two separated channels in opposite direction. Heat transfer equations for this system were obtained, and these equations were solved by some approximate method and numerical analysis. The effect of radiation on heat transfer became larger as the radiant heat transfer between two walls was larger. In the heat exchangers of counter flow type, the thermal efficiency is controlled with three parameters, namely radiation-convection parameter, Stanton number and temperature difference. The thermal efficiency was larger with the increase of these parameters. (Iwase, T.)

Structure of slow shocks in a magnetized plasma with heat conduction

International Nuclear Information System (INIS)

Tsai, C.L.; Tsai, R.H.; Wu, B.H.; Lee, L.C.

2002-01-01

The structure of slow shocks in the presence of a heat conduction parallel to the local magnetic field is simulated from the set of magnetohydrodynamic equations. In this study, a pair of slow shocks is formed through the evolution of a current sheet initiated by the presence of a normal magnetic field. It is found that the slow shock consists of two parts: The isothermal main shock and foreshock. Significant jumps in plasma density, velocity and magnetic field occur across the main shock, but the temperature is found to be continuous across the main shock. The foreshock is featured by a smooth temperature variation and is formed due to the heat flow from downstream to upstream region. The plasma density downstream of the main shock decreases with time, while the downstream temperature increases with time, keeping the downstream pressure constant. It is shown that the jumps in plasma density, pressure, velocity, and magnetic field across the main shock are determined by the set of modified isothermal Rankine-Hugoniot conditions. It is also found that a jump in the temperature gradient is present across the main shock in order to satisfy the energy conservation. The present results can be applied to the heating in the solar corona and solar wind

Low Temperature District Heating for Future Energy Systems

DEFF Research Database (Denmark)

Schmidt, Dietrich; Kallert, Anna; Blesl, Markus

2017-01-01

of the building stock. Low temperature district heating (LTDH) can contribute significantly to a more efficient use of energy resources as well as better integration of renewable energy (e.g. geothermal or solar heat), and surplus heat (e.g. industrial waste heat) into the heating sector. LTDH offers prospects......The building sector is responsible for more than one third of the final energy consumption of societies and produces the largest amount of greenhouse gas emissions of all sectors. This is due to the utilisation of combustion processes of mainly fossil fuels to satisfy the heating demand...... for both the demand side (community building structure) and the supply side (network properties or energy sources). Especially in connection with buildings that demand only low temperatures for space heating. The utilisation of lower temperatures reduces losses in pipelines and can increase the overall...

Van ‘t Hoff global analyses of variable temperature isothermal titration calorimetry data

International Nuclear Information System (INIS)

Freiburger, Lee A.; Auclair, Karine; Mittermaier, Anthony K.

2012-01-01

Highlights: ▶ We developed a global fitting strategy for ITC data collected at multiple temperatures. ▶ This method does not require prior knowledge of the binding mechanism. ▶ Monte Carlo simulations show that the approach improves the accuracy of extracted thermodynamic parameters. ▶ The method is used to study coupled folding/binding in aminoglycoside 6′-N-acetyltransferase-Ii. - Abstract: Isothermal titration calorimetry (ITC) can provide detailed information on the thermodynamics of biomolecular interactions in the form of equilibrium constants, K A , and enthalpy changes, ΔH A . A powerful application of this technique involves analyzing the temperature dependences of ITC-derived K A and ΔH A values to gain insight into thermodynamic linkage between binding and additional equilibria, such as protein folding. We recently developed a general method for global analysis of variable temperature ITC data that significantly improves the accuracy of extracted thermodynamic parameters and requires no prior knowledge of the coupled equilibria. Here we report detailed validation of this method using Monte Carlo simulations and an application to study coupled folding and binding in an aminoglycoside acetyltransferase enzyme.

Effects of low-temperature pretreatment on carbonization of cellulose for the production of biocarbons

Science.gov (United States)

Kwon, Gu-Joong; Kim, Dae-Young; Kang, Kyu-Young

2012-05-01

Pretreatment of cellulose at temperatures below 300 °C prior to carbonization at 1200 °C was studied for the production of high-yield biocarbons. Filter paper as the cellulosic raw material was pyrolyzed by using heating schemes, including 16-h isothermal step at 215-270 °C under nitrogen atmosphere, followed by fast heating up to 600 °C and finally to 1200 °C. Cellulose degradation was completed in the 16-h holding isothermal step at a temperature above 250 °C, as confirmed by IR spectroscopy and X-ray diffraction. The yield of char was increased from 11% to 21% by pretreatment of cellulose after post-treatment at 600 °C or 1200 °C. The BET surface area as the microporosity value was also significantly enhanced from 461 m2/g to 837 m2/g by straight heating of 10 °C/min. These results are thought to be caused by slow heating and stabilizing effects due to pretreatment of cellulose at the critical temperature for degradation.

Isothermality of the gas in the Coma cluster

International Nuclear Information System (INIS)

Hughes, J.P.; Yamashita, K.; Okumura, Y.; Tsunemi, H.; Matsuoka, M.

1988-01-01

The high-quality X-ray spectrum of the Coma cluster observed by the Japanese satelite Tenma in conjunction with imaging data from the Einstein Observatory was used to explore the temperature distribution of the cluster gas. It is found that pure polytropic models are inadequate to describe this temperature distribution. Instead, a hybrid model is proposed consisting of a central isothermal region surrounded by a polytropic distribution. It is shown that as much as 75 percent of the global emission may come from the isothermal component. 30 references

Cyclic high temperature heat storage using borehole heat exchangers

Science.gov (United States)

Boockmeyer, Anke; Delfs, Jens-Olaf; Bauer, Sebastian

2016-04-01

The transition of the German energy supply towards mainly renewable energy sources like wind or solar power, termed "Energiewende", makes energy storage a requirement in order to compensate their fluctuating production and to ensure a reliable energy and power supply. One option is to store heat in the subsurface using borehole heat exchangers (BHEs). Efficiency of thermal storage is increasing with increasing temperatures, as heat at high temperatures is more easily injected and extracted than at temperatures at ambient levels. This work aims at quantifying achievable storage capacities, storage cycle times, injection and extraction rates as well as thermal and hydraulic effects induced in the subsurface for a BHE storage site in the shallow subsurface. To achieve these aims, simulation of these highly dynamic storage sites is performed. A detailed, high-resolution numerical simulation model was developed, that accounts for all BHE components in geometrical detail and incorporates the governing processes. This model was verified using high quality experimental data and is shown to achieve accurate simulation results with excellent fit to the available experimental data, but also leads to large computational times due to the large numerical meshes required for discretizing the highly transient effects. An approximate numerical model for each type of BHE (single U, double U and coaxial) that reduces the number of elements and the simulation time significantly was therefore developed for use in larger scale simulations. The approximate numerical model still includes all BHE components and represents the temporal and spatial temperature distribution with a deviation of less than 2% from the fully discretized model. Simulation times are reduced by a factor of ~10 for single U-tube BHEs, ~20 for double U-tube BHEs and ~150 for coaxial BHEs. This model is then used to investigate achievable storage capacity, injection and extraction rates as well as induced effects for

First heats of cerium solution in liquid aluminium, gallium, indium, tin, lead and bismuth

International Nuclear Information System (INIS)

Yamshchikov, L.F.; Lebedev, V.A.; Nichkov, I.F.; Raspopin, S.P.; Shein, V.G.

1983-01-01

Cerium solution heats in liquid alluminium, gallium, indium, tin, lead and bismuth are determined in high temperature mixing calorimeter with an isothermal shell. The statistical analysis carried out proves that values of cerium solution heat in fusible metals obtained by the methods of electric motive forces and calorimety give a satisfactory agreement

Constitutive relationships for 22MnB5 boron steel deformed isothermally at high temperatures

International Nuclear Information System (INIS)

Naderi, M.; Durrenberger, L.; Molinari, A.; Bleck, W.

2008-01-01

The strain, strain rate and temperature dependency of a boron steel, which was isothermally deformed under uniaxial compression tests, has been investigated at temperatures between 600 and 900 o C, and at strain rates of 0.1, 1.0 and 10.0 s -1 . Two constitutive models were used to correlate the plastic behavior: the Voce constitutive relation in combination with the kinetic model proposed by Kocks and the phenomenological model proposed by Molinari-Ravichandran. The Kocks model has been introduced in the Voce formulation to describe the temperature and the strain rate dependency of the saturation stress and of the yield stress. The Molinari-Ravichandran model is based on a single internal variable that can be viewed as being related to a characteristic length scale of the microstructure that develops during deformation. It has been shown that the plastic behavior of the boron steel can be well described using these two models

Integrated Temperature Sensors based on Heat Diffusion

NARCIS (Netherlands)

Van Vroonhoven, C.P.L.

2015-01-01

This thesis describes the theory, design and implementation of a new class of integrated temperature sensors, based on heat diffusion. In such sensors, temperature is sensed by measuring the time it takes for heat to diffuse through silicon. An on-chip thermal delay can be determined by geometry and

Measurement of low-temperature specific heat

International Nuclear Information System (INIS)

Stewart, G.R.

1983-01-01

The measurement of low-temperature specific heat (LTSH) (0.1 K< T<60 K) has seen a number of breakthroughs both in design concepts and instrumentation in the last 15 years: particularly in small sample calorimetry. This review attempts to provide an overview of both large and small sample calorimetry techniques at temperatures below 60 K, with sufficient references to enable more detailed study. A comprehensive review is made of the most reliable measurements of the LTSH of 84 of the elements to illustrate briefly some of the problems of measurements and analysis, as well as to provide additional references. More detail is devoted to three special areas of low-temperature calorimetry that have seen rapid development recently: (1) measurement of the specific heat of highly radioactive samples, (2) measurement of the specific heat of materials in high magnetic fields (18 T), and (3) measurement of the specific heat of very small (100 μg) samples. The review ends with a brief discussion of the frontier research currently underway on microcalorimetry for nanogram sample weights

High temperature industrial heat pumps

Energy Technology Data Exchange (ETDEWEB)

Berghmans, J. (Louvain Univ., Heverlee (Belgium). Inst. Mechanica)

1990-01-01

The present report intends to describe the state of the art of high temperature industrial heat pumps. A description is given of present systems on the market. In addition the research and development efforts on this subject are described. Compression (open as well as closed cycle) systems, as well as absorption heat pumps (including transformers), are considered. This state of the art description is based upon literature studies performed by a team of researchers from the Katholieke Universiteit Leuven, Belgium. The research team also analysed the economics of heat pumps of different types under the present economic conditions. The heat pumps are compared with conventional heating systems. This analysis was performed in order to evaluate the present condition of the heat pump in the European industry.

Demonstration of Isothermal Compressed Air Energy Storage to Support Renewable Energy Production

Energy Technology Data Exchange (ETDEWEB)

Bollinger, Benjamin [Sustainx, Incorporated, Seabrook, NH (United States)

2015-01-02

This project develops and demonstrates a megawatt (MW)-scale Energy Storage System that employs compressed air as the storage medium. An isothermal compressed air energy storage (ICAES^TM) system rated for 1 MW or more will be demonstrated in a full-scale prototype unit. Breakthrough cost-effectiveness will be achieved through the use of proprietary methods for isothermal gas cycling and staged gas expansion implemented using industrially mature, readily-available components.The ICAES approach uses an electrically driven mechanical system to raise air to high pressure for storage in low-cost pressure vessels, pipeline, or lined-rock cavern (LRC). This air is later expanded through the same mechanical system to drive the electric motor as a generator. The approach incorporates two key efficiency-enhancing innovations: (1) isothermal (constant temperature) gas cycling, which is achieved by mixing liquid with air (via spray or foam) to exchange heat with air undergoing compression or expansion; and (2) a novel, staged gas-expansion scheme that allows the drivetrain to operate at constant power while still allowing the stored gas to work over its entire pressure range. The ICAES system will be scalable, non-toxic, and cost-effective, making it suitable for firming renewables and for other grid applications.

Determination of the liquidus temperature of tin using the heat pulse-based melting and comparison with traditional methods

Science.gov (United States)

Joung, Wukchul; Park, Jihye; Pearce, Jonathan V.

2018-06-01

In this work, the liquidus temperature of tin was determined by melting the sample using the pressure-controlled loop heat pipe. Square wave-type pressure steps generated periodic 0.7 °C temperature steps in the isothermal region in the vicinity of the tin sample, and the tin was melted with controllable heat pulses from the generated temperature changes. The melting temperatures at specific melted fractions were measured, and they were extrapolated to the melted fraction of unity to determine the liquidus temperature of tin. To investigate the influence of the impurity distribution on the melting behavior, a molten tin sample was solidified by an outward slow freezing or by quenching to segregate the impurities inside the sample with concentrations increasing outwards or to spread the impurities uniformly, respectively. The measured melting temperatures followed the local solidus temperature variations well in the case of the segregated sample and stayed near the solidus temperature in the quenched sample due to the microscopic melting behavior. The extrapolated melting temperatures of the segregated and quenched samples were 0.95 mK and 0.49 mK higher than the outside-nucleated freezing temperature of tin (with uncertainties of 0.15 mK and 0.16 mK, at approximately 95% level of confidence), respectively. The extrapolated melting temperature of the segregated sample was supposed to be a closer approximation to the liquidus temperature of tin, whereas the quenched sample yielded the possibility of a misleading extrapolation to the solidus temperature. Therefore, the determination of the liquidus temperature could result in different extrapolated melting temperatures depending on the way the impurities were distributed within the sample, which has implications for the contemporary methodology for realizing temperature fixed points of the International Temperature Scale of 1990 (ITS-90).

Case study of low-temperature heating in an existing single-family house-A test of methods for simulation of heating system temperatures

DEFF Research Database (Denmark)

Østergaard, Dorte Skaarup; Svendsen, Svend

2016-01-01

and the calculated indoor temperatures and radiator return temperatures were compared to temperatures measured in the case house. The results showed that the detail of the simulation model has a large influence on the results obtained. The estimated return temperatures from the radiators varied by up to 16 degrees C...... depending on the assumptions made in the simulation model. The results indicated that a detailed building simulation model can provide a good estimate of the actual heating system operation, provided that actual radiators and realistic indoor temperatures are taken into account in the model. (C) 2016......Low-temperature heating provides an efficient way of heating our buildings. To obtain a high efficiency it is important that the heating systems in the buildings are operated with both low supply and return temperatures. This study set out to investigate how typical assumptions in the modelling...

Human local and total heat losses in different temperature.

Science.gov (United States)

Wang, Lijuan; Yin, Hui; Di, Yuhui; Liu, Yanfeng; Liu, Jiaping

2016-04-01

This study investigates the effects of operative temperature on the local and total heat losses, and the relationship between the heat loss and thermal sensation. 10 local parts of head, neck, chest, abdomen, upper arm, forearm, hand, thigh, leg and foot are selected. In all these parts, convection, radiation, evaporation, respiration, conduction and diffusion heat losses are analyzed when operative temperature is 23, 28, 33 and 37 °C. The local heat losses show that the radiation and convection heat losses are mainly affected by the area of local body, and the heat loss of the thigh is the most in the ten parts. The evaporation heat loss is mainly affected by the distribution of sweat gland, and the heat loss of the chest is the most. The total heat loss of the local body shows that in low temperature, the thigh, leg and chest have much heat loss, while in high temperature, the chest, abdomen, thigh and head have great heat loss, which are useful for clothing design. The heat losses of the whole body show that as the operative temperature increases, the radiation and convection heat losses decrease, the heat losses of conduction, respiration, and diffusion are almost constant, and the evaporation heat loss increases. By comparison, the heat loss ratios of the radiation, convection and sweat evaporation, are in agreement with the previous researches. At last, the formula about the heat loss ratio of convection and radiation is derived. It's useful for thermal comfort evaluation and HVAC (heating, ventilation and air conditioning) design. Copyright © 2016 Elsevier Inc. All rights reserved.

Indoor temperatures for calculating room heat loss and heating capacity of radiant heating systems combined with mechanical ventilation systems

DEFF Research Database (Denmark)

Wu, Xiaozhou; Olesen, Bjarne W.; Fang, Lei

2016-01-01

change rates on the indoor temperatures were performed using the proposed model. When heated surface temperatures and air change rates were from 21.0 to 29.0 degrees C and from 0.5 to 4.0 h-1, the indoor temperatures for calculating the transmission heat loss and ventilation heat loss were between 20...

Heat pipes for temperature control

International Nuclear Information System (INIS)

Groll, M.

1978-01-01

Heat pipes have known for years as effective constructional elements for temperature control. With the aid of special techniques (gas, liquid, steam, and voltage control), special operating characteristics can be obtained, e.g. variable heat conduction or diode behaviour. Their main field of application is in spacecraft technology and in nuclear technology in the isothermalisation of irradiation capsules. The different control techniques are presented and critically evaluated on the basis of characteristic properties like heat transfer capacity, volume and mass requirements, complexity of structure and production, reliability, and temperature control characteristics. Advantages and shortcomings of the different concepts are derived and compared. The state of the art of these control techniques is established on the basis of four development levels. Finally, the necessity and direction of further R + D activities are discussed, and suggestions are made for further work. (orig./HP) [de

Influence of radiation heat transfer during a severe accident

Energy Technology Data Exchange (ETDEWEB)

Cazares R, R. I.; Epinosa P, G.; Varela H, J. R.; Vazquez R, A. [Universidad Autonoma Metropolitana, Unidad Iztapalapa, San Rafael Atlixco No. 186, Col. Vicentina, 09340 Ciudad de Mexico (Mexico); Polo L, M. A., E-mail: ricardo-cazares@hotmail.com [Comision Nacional de Seguridad Nuclear y Salvaguardias, Dr. Barragan No. 779, Col. Narvarte, 03020 Ciudad de Mexico (Mexico)

2016-09-15

The aim of this work is to determine the influence of the radiation heat transfer on an average fuel channel during a severe accident of a BWR nuclear power plant. The analysis considers the radiation heat transfer in a participating medium, where the gases inside the system participate in the radiation heat transfer. We consider the steam-water mixture as an isothermal gray gas, and the boundaries of the system as a gray diffuse isothermal surface for the clad and refractory surfaces for the rest, and consider the average fuel channel as an enclosure system. During a severe accident, generation and diffusion of hydrogen begin at high temperature range (1,273 to 2,100 K), and the fuel rod cladding oxidation, but the hydrogen generated do not participate in the radiation heat transfer because it does not have any radiation properties. The heat transfer process in the fuel assembly is considered with a reduced order model, and from this, the convection and the radiation heat transfer is introduced in the system. In this paper, a system with and without the radiation heat transfer term was calculated and analyzed in order to obtain the influence of the radiation heat transfer on the average fuel channel. We show the behavior of radiation heat transfer effects on the temporal evolution of the hydrogen concentration and temperature profiles in a fuel assembly, where a stream of steam is flowing. Finally, this study is a practical complement for more accurate modeling of a severe accident analysis. (Author)

Influence of radiation heat transfer during a severe accident

International Nuclear Information System (INIS)

Cazares R, R. I.; Epinosa P, G.; Varela H, J. R.; Vazquez R, A.; Polo L, M. A.

2016-09-01

The aim of this work is to determine the influence of the radiation heat transfer on an average fuel channel during a severe accident of a BWR nuclear power plant. The analysis considers the radiation heat transfer in a participating medium, where the gases inside the system participate in the radiation heat transfer. We consider the steam-water mixture as an isothermal gray gas, and the boundaries of the system as a gray diffuse isothermal surface for the clad and refractory surfaces for the rest, and consider the average fuel channel as an enclosure system. During a severe accident, generation and diffusion of hydrogen begin at high temperature range (1,273 to 2,100 K), and the fuel rod cladding oxidation, but the hydrogen generated do not participate in the radiation heat transfer because it does not have any radiation properties. The heat transfer process in the fuel assembly is considered with a reduced order model, and from this, the convection and the radiation heat transfer is introduced in the system. In this paper, a system with and without the radiation heat transfer term was calculated and analyzed in order to obtain the influence of the radiation heat transfer on the average fuel channel. We show the behavior of radiation heat transfer effects on the temporal evolution of the hydrogen concentration and temperature profiles in a fuel assembly, where a stream of steam is flowing. Finally, this study is a practical complement for more accurate modeling of a severe accident analysis. (Author)

Isotherms and isosteric heat of sorption of two varieties of Peruvian quinoa

OpenAIRE

Pumacahua-Ramos, Augusto; Gomez Vieira, José Antonio; Telis- Romero, Javier; Villa-Vélez, Harvey Alexander; Lopes Filho, Jose Francisco

2016-01-01

The isosteric heats of sorption of two varieties of quinoa (Chenopodium quinoa Willd.) grain were determined by the static gravimetric method at four temperatures (40, 50, 60 and 70 °C) and in relative humidity environments provided by six saturated salt solutions. Six mathematical equations were used to model the experimental data:  GAB, Oswin, Henderson, Peleg, Smith and Halsey. The isosteric heat of sorption was determined using the parameters of the GAB model. All the equations were shown...

Hovering in the heat: effects of environmental temperature on heat regulation in foraging hummingbirds.

Science.gov (United States)

Powers, Donald R; Langland, Kathleen M; Wethington, Susan M; Powers, Sean D; Graham, Catherine H; Tobalske, Bret W

2017-12-01

At high temperature (greater than 40°C) endotherms experience reduced passive heat dissipation (radiation, conduction and convection) and increased reliance on evaporative heat loss. High temperatures challenge flying birds due to heat produced by wing muscles. Hummingbirds depend on flight for foraging, yet inhabit hot regions. We used infrared thermography to explore how lower passive heat dissipation during flight impacts body-heat management in broad-billed ( Cynanthus latirostris , 3.0 g), black-chinned ( Archilochus alexandri , 3.0 g), Rivoli's ( Eugenes fulgens , 7.5 g) and blue-throated ( Lampornis clemenciae , 8.0 g) hummingbirds in southeastern Arizona and calliope hummingbirds ( Selasphorus calliope , 2.6 g) in Montana. Thermal gradients driving passive heat dissipation through eye, shoulder and feet dissipation areas are eliminated between 36 and 40°C. Thermal gradients persisted at higher temperatures in smaller species, possibly allowing them to inhabit warmer sites. All species experienced extended daytime periods lacking thermal gradients. Broad-billed hummingbirds lacking thermal gradients regulated the mean total-body surface temperature at approximately 38°C, suggesting behavioural thermoregulation. Blue-throated hummingbirds were inactive when lacking passive heat dissipation and hence might have the lowest temperature tolerance of the four species. Use of thermal refugia permitted hummingbirds to tolerate higher temperatures, but climate change could eliminate refugia, forcing distributional shifts in hummingbird populations.

Energy and exergy analysis of low temperature district heating network

DEFF Research Database (Denmark)

Li, Hongwei; Svendsen, Svend

2012-01-01

is designed to supply heating for 30 low energy detached residential houses. The network operational supply/return temperature is set as 55 °C/25 °C, which is in line with a pilot project carried out in Denmark. Two types of in-house substations are analyzed to supply the consumer domestic hot water demand...... energy/exergy losses and increase the quality match between the consumer heating demand and the district heating supply.......Low temperature district heating with reduced network supply and return temperature provides better match of the low quality building heating demand and the low quality heating supply from waste heat or renewable energy. In this paper, a hypothetical low temperature district heating network...

Temperature Oscillations in Loop Heat Pipes - A Revisit

Science.gov (United States)

Ku, Jentung

2018-01-01

Three types of temperature oscillation have been observed in the loop heat pipes. The first type is an ultra-high frequency temperature oscillation with a period on the order of seconds or less. This type of temperature oscillation is of little significance in spacecraft thermal control because the amplitude is in the noise level. The second type is a high frequency, low amplitude temperature oscillation with a period on the order of seconds to minutes and an amplitude on the order of one Kelvin. It is caused by the back-and-forth movement of the vapor front near the inlet or outlet of the condenser. The third type is a low frequency, high amplitude oscillation with a period on the order of hours and an amplitude on the order of tens of Kelvin. It is caused by the modulation of the net heat load into the evaporator by the attached large thermal mass which absorbs and releases energy alternately. Several papers on LHP temperature oscillation have been published. This paper presents a further study on the underlying physical processes during the LHP temperature oscillation, with an emphasis on the third type of temperature oscillation. Specifically, equations governing the thermal and hydraulic behaviors of LHP operation will be used to describe interactions among LHP components, heat source, and heat sink. The following sequence of events and their interrelationship will also be explored: 1) maxima and minima of reservoir and thermal mass temperatures; 2) the range of the vapor front movement inside the condenser; 3) rates of change of the reservoir and thermal mass temperatures; 4) the rate of heat absorption and heat release by the thermal mass and the rate of vapor front movement; and 5) inflection points of the reservoir and thermal mass temperatures.

HEAT PUMP USING SUBSOIL WATERS AS LOW TEMPERATURE HEAT SOURCE

Directory of Open Access Journals (Sweden)

Denysova Alla

2015-08-01

Full Text Available One of the basic directions of perfection of heat supply systems is the tendency of transition to the low-temperature heating systems based on application of heat pump installations. We consider heat supply system with heat pump installations using subsoil waters. Numerical simulation of thermal processes in the elements of a single-stage and double-stage heat pump systems has been worked out. Values of depths of wells and their quantity, necessary for effective operation of the offered installations, and values of capacity of electric water pumps for subsoil waters unit are calculated. Capacity of compressor electric drive and coefficient of performance of heat pump for the conditions of the city of Odessa are presented.

Decentralized substations for low-temperature district heating with no Legionella risk, and low return temperatures

International Nuclear Information System (INIS)

Yang, Xiaochen; Li, Hongwei; Svendsen, Svend

2016-01-01

To improve energy efficiency and give more access to renewable energy sources, low-temperature district heating (LTDH) is a promising concept to be realized in the future. However, concern about Legionella proliferation restricts applying low-temperature district heating in conventional systems with domestic hot water (DHW) circulation. In this study, a system with decentralized substations was analysed as a solution to this problem. Furthermore, a modification for the decentralized substation system were proposed in order to reduce the average return temperature. Models of conventional system with medium-temperature district heating, decentralized substation system with LTDH, and innovative decentralized substation system with LTDH were built based on the information of a case building. The annual distribution heat loss and the operating costs of the three scenarios were calculated and compared. From the results, realizing LTDH by the decentralized substation unit, 30% of the annual distribution heat loss inside the building can be saved compared to a conventional system with medium-temperature district heating. Replacing the bypass pipe with an in-line supply pipe and a heat pump, the innovative decentralized substation system can reduce distribution heat loss by 39% compared to the conventional system and by 12% compared to the normal decentralized substation system with bypass. - Highlights: • The system of decentralized substations can realize low-temperature district heating without running the risk of Legionella. • Decentralized substations help reduce the distribution heat loss inside the building compared to conventional system. • A new concept that can reduce the return temperature for district heating is proposed and analysed.

CDC WONDER: Daily Air Temperatures and Heat Index

Data.gov (United States)

U.S. Department of Health & Human Services — The Daily Air Temperature and Heat Index data available on CDC WONDER are county-level daily average air temperatures and heat index measures spanning the years...

Energy and exergy analysis of low temperature district heating network

International Nuclear Information System (INIS)

Li, Hongwei; Svendsen, Svend

2012-01-01

Low temperature district heating with reduced network supply and return temperature provides better match of the low quality building heating demand and the low quality heating supply from waste heat or renewable energy. In this paper, a hypothetical low temperature district heating network is designed to supply heating for 30 low energy detached residential houses. The network operational supply/return temperature is set as 55 °C/25 °C, which is in line with a pilot project carried out in Denmark. Two types of in-house substations are analyzed to supply the consumer domestic hot water demand. The space heating demand is supplied through floor heating in the bathroom and low temperature radiators in the rest of rooms. The network thermal and hydraulic conditions are simulated under steady state. A district heating network design and simulation code is developed to incorporate the network optimization procedure and the network simultaneous factor. Through the simulation, the overall system energy and exergy efficiencies are calculated and the exergy losses for the major district heating system components are identified. Based on the results, suggestions are given to further reduce the system energy/exergy losses and increase the quality match between the consumer heating demand and the district heating supply. -- Highlights: ► Exergy and energy analysis for low and medium temperature district heating systems. ► Different district heating network dimensioning methods are analyzed. ► Major exergy losses are identified in the district heating network and the in-house substations. ► Advantages to apply low temperature district heating are highlighted through exergy analysis. ► The influence of thermal by-pass on system exergy/energy performance is analyzed.

Fundamental research on the gravity assisted heat pipe thermal storage unit (GAHP-TSU) with porous phase change materials (PCMs) for medium temperature applications

International Nuclear Information System (INIS)

Hu, Bo-wen; Wang, Qian; Liu, Zhen-Hua

2015-01-01

Highlights: • A novel gravity-assisted heat pipe thermal storage unit (GAHP-TSU) is presented and tested. • Composite granular solid–liquid PCM is piled up as the porous medium layer in GAHP-TSU. • GAHP-TSU avoids the major obstacle of low thermal conductivity of the PCM. • GAHP-TSU enables the thermal storage unit with outstanding heat transfer performance. - Abstract: In this study, a novel gravity-assisted heat pipe type thermal storage unit (GAHP-TSU) has been presented for the potential application in solar air conditioning and refrigeration systems, in which composite granular solid–liquid PCMs compounded by RT100 and high-density polyethylene with phase change temperature of 100 °C are piled up as a porous PCMs medium layer. Water is used as heat transfer fluid in the GAHP-TSU. The heat transfer mechanism of heat storage/release in the GAHP-TSU is similar to that of the gravity-assisted heat pipe, which is superior to traditional direct-contact or indirect-contact thermal storage units. The properties of start-up, heat transfer characteristics on the stages of heat absorption and release of the GAHP-TSU are studied in detailed, including necessary calculations based on heat transfer theory. The results show that the whole system is almost isothermal at the temperature over 70 °C and the heat transfer properties are excellent both for heat absorption and release stages. The GAHP-TSU device with low thermal conductivity of the PCMs is promising in potential industry applications

The influence of heat sink temperature on the seasonal efficiency of shallow geothermal heat pumps

Science.gov (United States)

Pełka, Grzegorz; Luboń, Wojciech; Sowiżdżał, Anna; Malik, Daniel

2017-11-01

Geothermal heat pumps, also known as ground source heat pumps (GSHP), are the most efficient heating and cooling technology utilized nowadays. In the AGH-UST Educational and Research Laboratory of Renewable Energy Sources and Energy Saving in Miękinia, shallow geothermal heat is utilized for heating. In the article, the seasonal efficiency of two geothermal heat pump systems are described during the 2014/2015 heating season, defined as the period between 1st October 2014 and 30th April 2015. The first system has 10.9 kW heating capacity (according to European Standard EN 14511 B0W35) and extracts heat from three vertical geothermal loops at a depth of 80m each. During the heating season, tests warmed up the buffer to 40°C. The second system has a 17.03 kW heating capacity and extracts heat from three vertical geothermal loops at a depth of 100 m each, and the temperature of the buffer was 50°C. During the entire heating season, the water temperatures of the buffers was constant. Seasonal performance factors were calculated, defined as the quotient of heat delivered by a heat pump to the system and the sum of electricity consumed by the compressor, source pump, sink pump and controller of heat pumps. The measurements and calculations give the following results: - The first system was supplied with 13 857 kWh/a of heat and consumed 3 388 kWh/a electricity. The SPF was 4.09 and the average temperature of outlet water from heat pump was 40.8°C, and the average temperature of brine flows into the evaporator was 3.7 °C; - The second system was supplied with 12 545 kWh/a of heat and consumed 3 874 kWh/a electricity. The SPF was 3.24 and the average temperature of outlet water from heat pump was 51.6°C, and the average temperature of brine flows into the evaporator was 5.3°C. To summarize, the data shown above presents the real SPF of the two systems. It will be significant in helping to predict the SPF of objects which will be equipped with ground source heat pumps.

Achieving low return temperature for domestic hot water preparation by ultra-low-temperature district heating

DEFF Research Database (Denmark)

Yang, Xiaochen; Svendsen, Svend

2017-01-01

District heating (DH) is a cost-effective method of heat supply, especially to area with high heat density. Ultra-low-temperature district heating (ULTDH) is defined with supply temperature at 35-45 degrees C. It aims at making utmost use of the available low-temperature energy sources. In order...... to achieve high efficiency of the ULTDH system, the return temperature should be as low as possible. For the energy-efficient buildings in the future, it is feasible to use ULTDH to cover the space heating demand. However, considering the comfort and hygiene requirements of domestic hot water (DHW...... lower return temperature and higher efficiency for DHW supply, an innovative substation was devised, which replaced the bypass with an instantaneous heat exchanger and a micro electric storage tank. The energy performance of the proposed substation and the resulting benefits for the DH system...

Modified heat treatment for lower temperature improvement of the mechanical properties of two ultrahigh strength low alloy steels

Science.gov (United States)

Tomita, Yoshiyuki; Okabayashi, Kunio

1985-01-01

In the previous papers, a new heat treatment for improving the lower temperature mechanical propertise of the ultrahigh strength low alloy steels was suggested by the authors which produces a mixed structure of 25 vol pct lower bainite and 75 vol pct martensite through isothermal transformation at 593 K for a short time followed by water quenching (after austenitization at 1133 K). In this paper, two commercial Japanese ultrahigh strength steels, 0.40 pct C-Ni-Cr-Mo (AISI 4340 type) and 0.40 pct C-Cr-Mo (AISI 4140 type), have been studied to determine the effect of the modified heat treatment, coupled above new heat treatment with γ ⇆ α' repctitive heat treatment, on the mechanical properties from ambient temperature (287 K) to 123 K. The results obtained for various test temperatures have been compared with those for the new heat treatment reported previously and the conventional 1133 K direct water quenching treatment. The incorporation of intermediate four cyclic γ ⇆ α' repctitive heat treatment steps (after the initial austenitization at 1133 K and oil quenching) into the new heat treatment reported previously, as compared with the conventional 1133 K direct water quenching treatment, significantly improved 0.2 pct proof stress as well as notch toughness of the 0.40 pct C-Ni-Cr-Mo ultrahigh strength steel at similar fracture ductility levels from 287 to 123 K. Also, this heat treatment, as compared with the conventional 1133 K direct water quenching treatment, significantly improved both 0.2 pct proof stress and notch toughness of the 0.40 pct C-Cr-Mo ultrahigh strength steel with increased fracture ductility at 203 K and above. The microstructure consists of mixed areas of ultrafine grained martensite, within which is the refined blocky, highly dislocated structure, and the second phase lower bainite (about 15 vol pct), which appears in acicular form and partitions prior austenite grains. This newly developed heat treatment makes it possible to modify

Influence of the boundary conditions on a temperature field in the turbulent flow near the heated wall

International Nuclear Information System (INIS)

Bergant, R.; Tiselj, I.

2002-01-01

Direct Numerical Simulation (DNS) of the fully developed velocity and temperature fields in the two-dimensional turbulent channel flow was performed for friction Reynolds number Reτ = 150 and Prandtl number Pr 0.71. Two thermal boundary conditions (BCs), isothermal and isoflux, were carried out. The main difference between two ideal types of boundary conditions is in temperature fluctuations, which retain a nonzero value on the wall for isoflux BC, and zero for isothermal BC. Very interesting effect is seen in streamwise temperature auto-correlation functions. While the auto-correlation function for isothermal BC decreases close to zero in the observed computational domain, the decrease of the auto-correlation function for the isoflux BC is slower and remains well above zero. Therefore, another DNS at two times longer computational domain was performed, but results did not show any differences larger than the statistical uncertainty.(author)

Time and spatial heat transfer performance around an isothermally heated sphere placed in a uniform, downwardly directed flow (in relation to the enhancement of latent heat storage rate in a spherical capsule)

International Nuclear Information System (INIS)

Koizumi, H.

2004-01-01

The aim of this study is to reveal the temporal and spatial heat transfer performance of an isothermally heated sphere placed in a uniform, downwardly directed flow using a micro-foil heat flow sensor (HFS). A HFS, whose response time is about 0.02 s, was pasted on the surface of a heated copper sphere. Experiments were carried out using air with a Grashof number of 3.3 x 10 5 and with several Reynolds numbers (Re) up to 1800. Three flow patterns appeared: a chaotic flow at Re<240; a two-dimensional steady separated flow at 240 ≤ Re<500, and a three-dimensional unsteady separated flow at Re ≥ 500. In addition, the instantaneous and time-averaged heat transfer performance around the sphere in each of the three regions was clarified. Next, enhancement of the latent heat storage rate of a solid phase change material (PCM) in a spherical capsule was performed. The flow around the spherical capsule, in which the solid PCM was filled and placed in a heated, upwardly directed flow, is the approximate adverse flow phenomenon around the heated sphere which was placed in a downwardly directed flow. In other words, the buoyant flow and the forced flow are in the opposite directions in these two cases. Tests of latent heat storage were run for two Reynolds numbers which represented different flow characteristics in the heat transfer experiments, Re=150 and 1800. Furthermore, copper plates were inserted into the solid PCM, of which thermal conductivity was considerably low, to enhance the latent heat storage rate for the two Reynolds number flows

MODELING OF TEMPERATURE FIELDS IN A SOLID HEAT ACCUMULLATORS

Directory of Open Access Journals (Sweden)

S. S. Belimenko

2016-10-01

Full Text Available Purpose. Currently, one of the priorities of energy conservation is a cost savings for heating in commercial and residential buildings by the stored thermal energy during the night and its return in the daytime. Economic effect is achieved due to the difference in tariffs for the cost of electricity in the daytime and at night. One of the most common types of devices that allow accumulating and giving the resulting heat are solid heat accumulators. The main purpose of the work: 1 software development for the calculation of the temperature field of a flat solid heat accumulator, working due to the heat energy accumulation in the volume of thermal storage material without phase transition; 2 determination the temperature distribution in its volumes at convective heat transfer. Methodology. To achieve the study objectives a heat transfer theory and Laplace integral transform were used. On its base the problems of determining the temperature fields in the channels of heat accumulators, having different cross-sectional shapes were solved. Findings. Authors have developed the method of calculation and obtained solutions for the determination of temperature fields in channels of the solid heat accumulator in conditions of convective heat transfer. Temperature fields over length and thickness of channels were investigated. Experimental studies on physical models and industrial equipment were conducted. Originality. For the first time the technique of calculating the temperature field in the channels of different cross-section for the solid heat accumulator in the charging and discharging modes was proposed. The calculation results are confirmed by experimental research. Practical value. The proposed technique is used in the design of solid heat accumulators of different power as well as full-scale production of them was organized.

Simulation of competitive Cu precipitation in steel during non-isothermal aging

International Nuclear Information System (INIS)

Yang, J.B.; Yamashita, T.; Sano, N.; Enomoto, M.

2008-01-01

A numerical model has been developed to simulate Cu precipitation in dilute bcc Fe-Cu alloys during non-isothermal aging taking into account competitive nucleation at grain boundaries, dislocations and in the matrix, and structural transformation of Cu particles that occurs during growth. The temporal evolution of number density, mean particle size and size distribution during continuous cooling is simulated and is compared with experimental observations under transmission electron microscope and three-dimensional atom probe field ion microscope. With decreasing temperature the growth and coarsening rates diminishes rapidly whereas nucleation continues to occur down to lower temperatures due to the decrease in the activation energy of nucleation and thus, distributions of fine particles can be obtained relatively easily after cooling. Precipitation and dissolution during continuous heating are simulated and are compared with experimental observations in the literature

Ground Source Heat Supply in Moscow Oblast: Temperature Potential and Sustainable Depth of Heat Wells

Science.gov (United States)

Vasil'ev, G. P.; Gornov, V. F.; Dmitriev, A. N.; Kolesova, M. V.; Yurchenko, V. A.

2018-01-01

The paper is devoted to a problem of increasing the efficiency of low-potential geothermal heat in heat pump systems of residential buildings the Moscow oblast of Russia, including Moscow. Estimates of a natural geothermal potential in the Moscow oblast (based on climatological data for the period from 1982 to 2011) are presented and a "Typical climatic year of natural soil temperature variations for the geoclimatic conditions of the Moscow oblast, including the city of Moscow" is proposed. Numerical simulation of the influence of geothermal energy potential and the depth of heat wells on the efficiency of ground source heat pump systems for the heat supply of residential buildings is carried out. Analysis of the numerical simulation showed that the operation of a heat pump system in a house heating mode under the geoclimatic conditions of the Moscow oblast leads to a temperature drop of the heat-exchange medium circulating through heat wells to 5-6°C by the end of the first 10 years of operation, and the process stabilizes by the 15th year of operation, and further changes in the heat-exchange medium temperature do not any longer significantly affect the temperature of the heat-exchange medium in the heat well. In this case, the exact dependence of the heat-exchange medium temperature drop on the depth is not revealed. Data on the economically expedient heat well depth for the conditions of the Moscow oblast ensuring a net present value for the whole residential building life cycle are presented. It is found that the heat well depth of 60 m can be considered as an endpoint for the Moscow oblast, and a further heat well deepening is economically impractical.

Determination of Ground Heat Exchangers Temperature Field in Geothermal Heat Pumps

Science.gov (United States)

Zhurmilova, I.; Shtym, A.

2017-11-01

For the heating and cooling supply of buildings and constructions geothermal heat pumps using low-potential ground energy are applied by means of ground exchangers. The process of heat transfer in a system of ground exchangers is a phenomenon of complex heat transfer. The paper presents a mathematical modeling of heat exchange processes, the temperature fields are built which are necessary for the determination of the ground array that ensures an adequate supply of low potential energy excluding the freezing of soil around the pipes in the ground heat exchangers and guaranteeing a reliable operation of geothermal heat pumps.

Comparative technical-economic analysis of the low temperature heating systems

International Nuclear Information System (INIS)

Sharevski, Vasko; Sharevski, Milan

1994-01-01

A method for comparative technical-economic analysis between low temperature heating systems and heating systems with fossil fuel boiler plant, heat pump heating system and electrical heating systems is presented. The single and combined heating systems are analyzed. The technical-economic priority application of the heating system is determined according to the prices of the low temperature heat energy, fossil fuel heat energy, electrical energy, as well as to the coefficient of the annual use of the installed heating capacity, investment expenses, structure of the combined heating system and coefficient of performances of the heat pump. The combined heating system, composed with a low temperature heating subsystem, which is used to cover the base heat demands, and a oil boiler plant heating subsystem, for the top heat demands, have technical-economic justification and wide range of priority application, in comparison with single heating systems. (author)

A helium based pulsating heat pipe for superconducting magnets

Science.gov (United States)

Fonseca, Luis Diego; Miller, Franklin; Pfotenhauer, John

2014-01-01

This study was inspired to investigate an alternative cooling system using a helium-based pulsating heat pipes (PHP), for low temperature superconducting magnets. In addition, the same approach can be used for exploring other low temperature applications. The advantages of PHP for transferring heat and smoothing temperature profiles in various room temperature applications have been explored for the past 20 years. An experimental apparatus has been designed, fabricated and operated and is primarily composed of an evaporator and a condenser; in which both are thermally connected by a closed loop capillary tubing. The main goal is to measure the heat transfer properties of this device using helium as the working fluid. The evaporator end of the PHP is comprised of a copper winding in which heat loads up to 10 watts are generated, while the condenser is isothermal and can reach 4.2 K via a two stage Sumitomo RDK408A2 GM cryocooler. Various experimental design features are highlighted. Additionally, performance results in the form of heat transfer and temperature characteristics are provided as a function of average condenser temperature, PHP fill ratio, and evaporator heat load. Results are summarized in the form of a dimensionless correlation and compared to room temperature systems. Implications for superconducting magnet stability are highlighted.

Threshold heating temperature for magnetic hyperthermia: Controlling the heat exchange with the blocking temperature of magnetic nanoparticles

Science.gov (United States)

Pimentel, B.; Caraballo-Vivas, R. J.; Checca, N. R.; Zverev, V. I.; Salakhova, R. T.; Makarova, L. A.; Pyatakov, A. P.; Perov, N. S.; Tishin, A. M.; Shtil, A. A.; Rossi, A. L.; Reis, M. S.

2018-04-01

La0.75Sr0.25MnO3 nanoparticles with average diameter close to 20.9 nm were synthesized using a sol-gel method. Measurements showed that the heating process stops at the blocking temperaturesignificantly below the Curie temperature. Measurements of Specific Absorption Rate (SAR) as a function of AC magnetic field revealed a superquadratic power law, indicating that, in addition to usual Néel and Brown relaxation, the hysteresis also plays an important role in the mechanism of heating. The ability to control the threshold heating temperature, a low remanent magnetization and a low field needed to achieve the magnetic saturation are the advantages of this material for therapeutic magnetic hyperthermia.

Modelling of Temperature Profiles and Transport Scaling in Auxiliary Heated Tokamaks

DEFF Research Database (Denmark)

Callen, J.D.; Christiansen, J.P.; Cordey, J.G.

1987-01-01

time , the heating effectiveness η, and the energy offset W(0). Considering both the temperature profile responses and the global transport scaling, the constant heat pinch or excess temperature gradient model is found to best characterize the present JET data. Finally, new methods are proposed......The temperature profiles produced by various heating profiles are calculated from local heat transport models. The models take the heat flux to be the sum of heat diffusion and a non-diffusive heat flow, consistent with local measurements of heat transport. Two models are developed analytically...... in detail: (i) a heat pinch or excess temperature gradient model with constant coefficients; and (ii) a non-linear heat diffusion coefficient (χ) model. Both models predict weak (lesssim20%) temperature profile responses to physically relevant changes in the heat deposition profile – primarily because...

Parametric Study of an Air Charged Franchot Engine with Novel Hot and Cold Isothermalizers

Directory of Open Access Journals (Sweden)

Jafar M. Daoud

2017-12-01

Full Text Available The Stirling engine is an external combustion engine that uses heat exchangers to enhance the addition and removal of energy. This makes the engine power-dense but expensive, less efficient and complicated. In this contribution, the Stirling engine based on the Franchot engine has novel cylindrical fins working as isothermalizers to improve heat transfer without the complications of heat exchangers. Enhancing the power density by isothermalizing work spaces is compared to the bare cylinder optimized by varying the phase angle. The theoretical analysis shows that both the adiabatic and isothermal fins increase the power and efficiency, achieving the Curzon and Ahlborn efficiency at the maximum power point. In comparison to the phase angle method, the finned engine resulted in much lower gas mass flow rate, which leads to a reduction in the regenerator pumping and enthalpy losses. Thus, the Stirling engine has the potential to be simple, cheap, efficient and power-dense, and thus can be used effectively for different applications.

Isothermal Titration Calorimetry in the Student Laboratory

Science.gov (United States)

Wadso, Lars; Li, Yujing; Li, Xi

2011-01-01

Isothermal titration calorimetry (ITC) is the measurement of the heat produced by the stepwise addition of one substance to another. It is a common experimental technique, for example, in pharmaceutical science, to measure equilibrium constants and reaction enthalpies. We describe a stirring device and an injection pump that can be used with a…

Non-isothermal Moisture Transport Through Insulation Materials

DEFF Research Database (Denmark)

Peuhkuri, Ruut Hannele; Rode, Carsten; Hansen, Kurt Kielsgaard

2008-01-01

An experimental investigation was conducted in order to draw some conclusions on the magnitude of moisture transport due to temperature gradient on a range of porous light-weight building materials. A special constructed non-isothermal set-up allowed the creation of a temperature gradient of 10K...... and given humidity gradient over the sample. The resulting moisture ux as well as the hygrothermal states around and within the material were monitored. The hypothesis of relative humidity being a driving force for non-isothermal moisture transport already in the hygroscopic range could not be confirmed....... On the contrary, indications exist that the temperature gradient itself is driving the moisture from the warm side towards the cold side. An attempt to identify and quantify the single contributions of the different transport forms involved is also presented. The diferent results gave, however, diverging...

Design manual. [High temperature heat pump for heat recovery system

Energy Technology Data Exchange (ETDEWEB)

Burch, T.E.; Chancellor, P.D.; Dyer, D.F.; Maples, G.

1980-01-01

The design and performance of a waste heat recovery system which utilizes a high temperature heat pump and which is intended for use in those industries incorporating indirect drying processes are described. It is estimated that use of this heat recovery system in the paper, pulp, and textile industries in the US could save 3.9 x 10/sup 14/ Btu/yr. Information is included on over all and component design for the heat pump system, comparison of prime movers for powering the compressor, control equipment, and system economics. (LCL)

Non-isothermal kinetics of phase transformations in magnetron sputtered alumina films with metastable structure

International Nuclear Information System (INIS)

Zuzjaková, Š.; Zeman, P.; Kos, Š.

2013-01-01

Highlights: • Non-isothermal kinetics of phase transformations in alumina films was investigated. • The structure of alumina films affects kinetics of the transformation processes. • Kinetic triplets of all transformation processes were determined. • The KAS, FWO, FR and IKP methods for determination of E a and A were used. • The Málek method for determination of the kinetic model was used. - Abstract: The paper reports on non-isothermal kinetics of transformation processes in magnetron sputtered alumina thin films with an amorphous and γ-phase structure leading ultimately to the formation of the thermodynamically stable α-Al 2 O 3 phase. Phase transformation sequences in the alumina films were investigated using differential scanning calorimetry (DSC) at four different heating rates (10, 20, 30, 40 °C/min). Three isoconversional methods (Kissinger–Akahira–Sunose (KAS), Flynn–Wall–Ozawa (FWO) and Friedman (FR) method) as well as the invariant kinetic parameters (IKP) method were used to determine the activation energies for transformation processes. Moreover, the pre-exponential factors were determined using the IKP method. The kinetic models of the transformation processes were determined using the Málek method. It was found that the as-deposited structure of alumina films affects kinetics of the transformation processes. The film with the amorphous as-deposited structure heated at 40 °C/min transforms to the crystalline γ phase at a temperature of ∼930 °C (E a,IKP = 463 ± 10 kJ/mol) and subsequently to the crystalline α phase at a temperature of ∼1200 °C (E a,IKP = 589 ± 10 kJ/mol). The film with the crystalline γ-phase structure heated at 40 °C/min is thermally stable up to ∼1100 °C and transforms to the crystalline α phase (E a,IKP = 511 ± 16 kJ/mol) at a temperature of ∼1195 °C. The empirical two-parameter Šesták–Berggren kinetic model was found to be the most adequate one to describe all transformation processes

Force Field Benchmark of Organic Liquids: Density, Enthalpy of Vaporization, Heat Capacities, Surface Tension, Isothermal Compressibility, Volumetric Expansion Coefficient, and Dielectric Constant.

Science.gov (United States)

Caleman, Carl; van Maaren, Paul J; Hong, Minyan; Hub, Jochen S; Costa, Luciano T; van der Spoel, David

2012-01-10

The chemical composition of small organic molecules is often very similar to amino acid side chains or the bases in nucleic acids, and hence there is no a priori reason why a molecular mechanics force field could not describe both organic liquids and biomolecules with a single parameter set. Here, we devise a benchmark for force fields in order to test the ability of existing force fields to reproduce some key properties of organic liquids, namely, the density, enthalpy of vaporization, the surface tension, the heat capacity at constant volume and pressure, the isothermal compressibility, the volumetric expansion coefficient, and the static dielectric constant. Well over 1200 experimental measurements were used for comparison to the simulations of 146 organic liquids. Novel polynomial interpolations of the dielectric constant (32 molecules), heat capacity at constant pressure (three molecules), and the isothermal compressibility (53 molecules) as a function of the temperature have been made, based on experimental data, in order to be able to compare simulation results to them. To compute the heat capacities, we applied the two phase thermodynamics method (Lin et al. J. Chem. Phys.2003, 119, 11792), which allows one to compute thermodynamic properties on the basis of the density of states as derived from the velocity autocorrelation function. The method is implemented in a new utility within the GROMACS molecular simulation package, named g_dos, and a detailed exposé of the underlying equations is presented. The purpose of this work is to establish the state of the art of two popular force fields, OPLS/AA (all-atom optimized potential for liquid simulation) and GAFF (generalized Amber force field), to find common bottlenecks, i.e., particularly difficult molecules, and to serve as a reference point for future force field development. To make for a fair playing field, all molecules were evaluated with the same parameter settings, such as thermostats and barostats

A state-of-the-art review on hybrid heat pipe latent heat storage systems

International Nuclear Information System (INIS)

Naghavi, M.S.; Ong, K.S.; Mehrali, M.; Badruddin, I.A.; Metselaar, H.S.C.

2015-01-01

The main advantage of latent heat thermal energy storage systems is the capability to store a large quantity of thermal energy in an isothermal process by changing phase from solid to liquid, while the most important weakness of these systems is low thermal conductivity that leads to unsuitable charging/discharging rates. Heat pipes are used in many applications – as one of the most efficient heat exchanger devices – to amplify the charging/discharging processes rate and are used to transfer heat from a source to the storage or from the storage to a sink. This review presents and critically discusses previous investigations and analysis on the incorporation of heat pipe devices into latent heat thermal energy storage with heat pipe devices. This paper categorizes different applications and configurations such as low/high temperature solar, heat exchanger and cooling systems, analytical approaches and effective parameters on the performance of hybrid HP–LHTES systems.

Effective thermal conductivity of a heat generating rod bundle dissipating heat by natural convection and radiation

International Nuclear Information System (INIS)

Senve, Vinay; Narasimham, G.S.V.L.

2011-01-01

Highlights: → Transport processes in isothermal hexagonal sheath with 19 heat generating rods is studied. → Correlation is given to predict the maximum temperature considering all transport processes. → Effective thermal conductivity of rod bundle can be obtained using max temperature. → Data on the critical Rayleigh numbers for p/d ratios of 1.1-2.0 is presented. → Radiative heat transfer contributes to heat dissipation of 38-65% of total heat. - Abstract: A numerical study of conjugate natural convection and surface radiation in a horizontal hexagonal sheath housing 19 solid heat generating rods with cladding and argon as the fill gas, is performed. The natural convection in the sheath is driven by the volumetric heat generation in the solid rods. The problem is solved using the FLUENT CFD code. A correlation is obtained to predict the maximum temperature in the rod bundle for different pitch-to-diameter ratios and heat generating rates. The effective thermal conductivity is related to the heat generation rate, maximum temperature and the sheath temperature. Results are presented for the dimensionless maximum temperature, Rayleigh number and the contribution of radiation with changing emissivity, total wattage and the pitch-to-diameter ratio. In the simulation of a larger system that contains a rod bundle, the effective thermal conductivity facilitates simplified modelling of the rod bundle by treating it as a solid of effective thermal conductivity. The parametric studies revealed that the contribution of radiation can be 38-65% of the total heat generation, for the parameter ranges chosen. Data for critical Rayleigh number above which natural convection comes into effect is also presented.

Heat transfer of natural convection in a rectangular cavity with vertical walls of different temperatures

International Nuclear Information System (INIS)

Seki, Nobuhiro; Fukusako, Shoichiro; Inaba, Hideo

1978-01-01

In the present study the behavior of heat transfer in a rectangular cavity with one isothermal vertical wall heated and the other cooled is investigated. Heat transfer coefficients on the vertical walls are measured for fluids with Prandtl number Pr of 3 to 40,000 in case of aspect-ratio H/W from 5 to 47.5 and their correlated results are presented for laminar, transition and turbulent regions, respectively. It is shown that the present arrangement (Nu sub(H) - Ra sub(H)) using the height of cavity as a representative length may significantly be useful in the various heat transfer modes accompanied with flow patterns of them. (auth.)

β → α isothermal transformation in pure and weakly alloyed uranium

International Nuclear Information System (INIS)

Aubert, H.; Lelong, C.

1966-01-01

The TTT diagrams describing the β → α isothermal transformation have been made by isothermal dilatometry for pure uranium and 21 alloys based on chromium, silicon, molybdenum, iron, aluminium, zirconium. The thermal cycle preceding the isothermal step influences the decomposition kinetics at temperature corresponding to the eutectoid and martensitic mechanisms, but not in the range where the bainitic transformation occurs. The stability of the β phase decreases with the chromium, molybdenum and silicon concentration: it is affected differently for each of the three transformation mechanisms. The ternary additions, even at very low concentration have a considerable effect on the stability. When the concentration decreases the martensitic mechanism is active at progressively higher temperature, diminishing to the point of disappearance the temperature range where the transformation is considered as being of the bainitic mode. (author) [fr

Effect of radiation heat transfer on the performance of high temperature heat exchanger, (2)

International Nuclear Information System (INIS)

Yamada, Yukio; Mori, Yasuo; Hijikata, Kunio.

1977-01-01

In high temperature helium gas-cooled reactors, the nuclear energy can be utilized effectively, and the safety is excellent as compared with conventional reactors. They are advantageous also in view of environmental problems. In this report, the high temperature heat exchanger used for heating steam with the helium from a high temperature gas reactor is modeled, and the case that radiating gas flow between parallel plates is considered. Analysis was made on the case of one channel and constant heat flux and on the model for a counter-flow type heat exchanger with two channels, and the effect of radiation on the heat transfer in laminar flow and turbulent flow regions was clarified theoretically. The basic equations, the method of approximate solution and the results of calculation are explained. When one dimensional radiation was considered, the representative temperature Tr regarding fluid radiation was introduced, and its relation to mean mixing temperature Tm was determined. It was clarified that the large error in the result did not arise even if Tr was taken equally to Tm, especially in case of turbulent flow. The error was practically negligible when the rate of forced convection heat transfer in case of radiating medium flow was taken same as that in the case without radiation. (Kako, I.)

Comprehensive study of flow and heat transfer at the surface of circular cooling fin

Science.gov (United States)

Mityakov, V. Yu; Grekov, M. A.; Gusakov, A. A.; Sapozhnikov, S. Z.; Seroshtanov, V. V.; Bashkatov, A. V.; Dymkin, A. N.; Pavlov, A. V.; Milto, O. A.; Kalmykov, K. S.

2017-11-01

For the first time is proposed to combine heat flux measurements with thermal imaging and PIV (particle image velocimetry) for a comprehensive study of flow and heat transfer at the surface of the circular cooling fin. The investigated hollow fin is heated from within with saturated water steam; meanwhile the isothermal external surface simulates one of the perfect fin. Flow and heat transfer at the surface of the solid fin of the same size and shape, made of titanium alloy is investigated in the same regimes. Gradient Heat Flux Sensors (GHFS) were installed at different places of the fin surface. Velocity field around a cylinder, temperature field at the surface of the fin and heat flux for each rated time were obtained. Comprehensive method including heat flux measurement, PIV and thermal imaging allow to study flow and heat transfer at the surface of the fin in real time regime. The possibility to study flow and heat transfer for non-isothermal fins is shown; it is allow to improve traditional calculation of the cooling fins.

Can high temperature steam electrolysis function with geothermal heat?

International Nuclear Information System (INIS)

Sigurvinsson, J.; Mansilla, C.; Werkoff, F.; Lovera, P.

2007-01-01

It is possible to improve the performance of electrolysis processes by operating at a high temperature. This leads to a reduction in electricity consumption but requires a part of the energy necessary for the dissociation of water to be in the form of thermal energy. Iceland produces low cost electricity and very low cost geothermal heat. However, the temperature of geothermal heat is considerably lower than the temperature required at the electrolyser's inlet, making heat exchangers necessary to recuperate part of the heat contained in the gases at the electrolyser's outlet. A techno-economic optimisation model devoted to a high-temperature electrolysis (HTE) process which includes electrolysers as well as a high temperature heat exchanger network was created. Concerning the heat exchangers, the unit costs used in the model are based on industrial data. For the electrolyser cells, the unit cost scaling law and the physical sub-model we used were formulated using analogies with solid oxide fuel cells. The method was implemented in a software tool, which performs the optimisation using genetic algorithms. The first application of the method is done by taking into account the prices of electricity and geothermal heat in the Icelandic context. It appears that even with a geothermal temperature as low as 230 degrees C, the HTE could compete with alkaline electrolysis. (authors)

High-temperature process heat reactor with solid coolant and radiant heat exchange

International Nuclear Information System (INIS)

Alekseev, A.M.; Bulkin, Yu.M.; Vasil'ev, S.I.

1984-01-01

The high temperature graphite reactor with the solid coolant in which heat transfer is realized by radiant heat exchange is described. Neutron-physical and thermal-technological features of the reactor are considered. The reactor vessel is made of sheet carbon steel in the form of a sealed rectangular annular box. The moderator is a set of graphite blocks mounted as rows of arched laying Between the moderator rows the solid coolant annular layings made of graphite blocks with high temperature nuclear fuel in the form of coated microparticles are placed. The coolant layings are mounted onto ring movable platforms, the continuous rotation of which is realizod by special electric drives. Each part of the graphite coolant laying consecutively passes through the reactor core neutron cut-off zones and technological zone. In the core the graphite is heated up to the temperature of 1350 deg C sufficient for effective radiant heat transfer. In the neutron cut-off zone the chain reaction and further graphite heating are stopped. In the technological zone the graphite transfers the accumulated heat to the walls of technological channels in which the working medium moves. The described reactor is supposed to be used in nuclear-chemical complex for ammonia production by the method of methane steam catalytic conversion

Measured Performance of a Low Temperature Air Source Heat Pump

Energy Technology Data Exchange (ETDEWEB)

R.K. Johnson

2013-09-01

A 4-ton Low Temperature Heat Pump (LTHP) manufactured by Hallowell International was installed in a residence near New Haven, Connecticut and monitored over two winters of operation. After attending to some significant service issues, the heat pump operated as designed. This report should be considered a review of the dual compressor “boosted heat pump” technology. The Low Temperature Heat Pump system operates with four increasing levels of capacity (heat output) as the outdoor temperature drops.

Temperature Assessment of Heating Stage for a Thermoforming Equipment

International Nuclear Information System (INIS)

Mohd Ghazali, F.A.; Ab Rahim, M.F.; Jaafar, A.A.; Ahmad, M.N.

2016-01-01

Thermoforming is a well-known manufacturing process in the productions of various plastic household and industrial solutions. The heating of a plastic sheet allows the plastic to soften and within its forming window temperature the sheet can replicate a required shape when pressed against a mould. Hence, the heating process is an important thermoforming stage that determine uniformity of the material distribution. This article proposed an experimental approach to investigate the thermal characteristics of the heating section of a low cost thermoforming equipment designed for teaching and research purposes. The temperatures of air and a model of a stretched heated plastic sheet were measured and analysed. The experimental data indicates that the spatial temperatures distribution was not localised and the temperature history of the infrared heating agrees well with those given by fast response thermocouples. The findings suggest that the spatial uniformity of temperature can be reasonably evaluated by using the proposed method. (paper)

Temperature distribution in spouted bed and heat transfer

International Nuclear Information System (INIS)

Takeda, Hiroshi; Yamamoto, Yutaka

1976-01-01

Temperature distribution in spouted bed was measured by using brass and graphite spouted beds so as to investigate heat transfer characteristic of spouted bed applied to an apparatus of PyC coating. These spouted beds are batch type and are spouted by air or nitrogen gas of room temperature, and the outer wall of beds are heated by nichrome or graphite heater. Particles used for experiments are alumina spherical particles and the diameter is 0.80 -- 1.12 mm. Temperature condition is in the range of 400 -- 1,400 0 C. In the neighborhood of 400 0 C, the spouting condition is stable, while the spouting condition becomes unstable in the case of above 1,000 0 C. This is caused by abrupt temperature increase of spouting gas. It was found that heat transfer coefficient h sub(w) of our low temperature experiments was closer to the calculated from Malek et al.'s equation, h sub(p) of our experiments was several times greater than the calculated from Uemaki et al.'s equation. On the other hand, h sub(p) of high temperature experiments was compared with an experimental relation for convective heat transfer of fluidized bed, it was found that Nu sub(p) of our experiments was nearly equal to or greater than the calculated from the relation, this would be caused by radiant heat transfer. (auth.)

Computational solutions for non-isothermal, nonlinear magneto-convection in porous media with hall/ionslip currents and ohmic dissipation

Directory of Open Access Journals (Sweden)

O. Anwar Bég

2016-03-01

Full Text Available A theoretical and numerical study is presented to analyze the nonlinear, non-isothermal, magnetohydrodynamic (MHD free convection boundary layer flow and heat transfer in a non-Darcian, isotropic, homogenous porous medium, in the presence of Hall currents, Ionslip currents, viscous heating and Joule heating. A power-law variation is used for the temperature at the wall. The governing nonlinear coupled partial differential equations for momentum conservation in the x and z directions and heat conservation, in the flow regime are transformed from an (x, y, z coordinate system to a (ξ,η coordinate system in terms of dimensionless x-direction velocity (∂F/∂η and z-direction velocity (G and dimensionless temperature function (H under appropriate boundary conditions. Both Darcian and Forchheimer porous impedances are incorporated in both momentum equations. Computations are also provided for the variation of the x and z direction shear stress components and also local Nusselt number. Excellent correlation is achieved with a Nakamura tridiagonal finite difference scheme (NTM. The model finds applications in magnetic materials processing, MHD power generators and purification of crude oils.

Pressure drop and heat transfer characteristics of a high-temperature printed circuit heat exchanger

International Nuclear Information System (INIS)

Chen, Minghui; Sun, Xiaodong; Christensen, Richard N.; Skavdahl, Isaac; Utgikar, Vivek; Sabharwall, Piyush

2016-01-01

Highlights: • Pressure drop and heat transfer characteristics of a high-temperature printed circuit heat exchanger have been obtained. • Comparisons of experimental data and available correlations have been performed. • New Fanning friction factor and heat transfer correlations for the test PCHE are developed. - Abstract: Printed circuit heat exchanger (PCHE) is one of the leading intermediate heat exchanger (IHX) candidates to be employed in the very-high-temperature gas-cooled reactors (VHTRs) due to its capability for high-temperature, high-pressure applications. In the current study, a reduced-scale zigzag-channel PCHE was fabricated using Alloy 617 plates for the heat exchanger core and Alloy 800H pipes for the headers. The pressure drop and heat transfer characteristics of the PCHE were investigated experimentally in a high-temperature helium test facility (HTHF) at The Ohio State University. The PCHE helium inlet temperatures and pressures were varied up to 464 °C/2.7 MPa for the cold side and 802 °C/2.7 MPa for the hot side, respectively, while the maximum helium mass flow rates on both sides of the PCHE reached 39 kg/h. The corresponding maximum channel Reynolds number was approximately 3558, covering the laminar flow and laminar-to-turbulent flow transition regimes. New pressure drop and heat transfer correlations for the current zigzag channels with rounded bends were developed based on the experimental data. Comparisons between the experimental data and the results obtained from the available PCHE and straight circular pipe correlations were conducted. Compared to the heat transfer performance in straight circular pipes, the zigzag channels provided little advantage in the laminar flow regime but significant advantage near the transition flow regime.

Thermodynamic properties of molybdenum borides at temperatures above 300 K

International Nuclear Information System (INIS)

Bolgar, A.S.; Blinder, A.V.; Serbova, M.I.

1990-01-01

Enthalpy of Mo 2 B, MoB, Mo 2 B 5 borides within the range of temperatures above 300 K has been experimentally studied. Parameters of temperature dependences of enthalpy, heat capacity, entropy and the reduced Gibbs energy of the studied substances are calculated within a wide range. It is stated that high-temperature heat capacity of the studied borides can be presented as a sum of the electron component, a harmonic part of the lattice component and a contribution caused by anharmonic oscillations of lattice atoms. Values of coefficients of isothermal compressibility of Mo 2 , MoB, Mo 2 B 5 within the high temperature range are estimated

Transectional heat transfer in thermoregulating bigeye tuna (Thunnus obesus) - a 2D heat flux model.

Science.gov (United States)

Boye, Jess; Musyl, Michael; Brill, Richard; Malte, Hans

2009-11-01

We developed a 2D heat flux model to elucidate routes and rates of heat transfer within bigeye tuna Thunnus obesus Lowe 1839 in both steady-state and time-dependent settings. In modeling the former situation, we adjusted the efficiencies of heat conservation in the red and the white muscle so as to make the output of the model agree as closely as possible with observed cross-sectional isotherms. In modeling the latter situation, we applied the heat exchanger efficiencies from the steady-state model to predict the distribution of temperature and heat fluxes in bigeye tuna during their extensive daily vertical excursions. The simulations yielded a close match to the data recorded in free-swimming fish and strongly point to the importance of the heat-producing and heat-conserving properties of the white muscle. The best correspondence between model output and observed data was obtained when the countercurrent heat exchangers in the blood flow pathways to the red and white muscle retained 99% and 96% (respectively) of the heat produced in these tissues. Our model confirms that the ability of bigeye tuna to maintain elevated muscle temperatures during their extensive daily vertical movements depends on their ability to rapidly modulate heating and cooling rates. This study shows that the differential cooling and heating rates could be fully accounted for by a mechanism where blood flow to the swimming muscles is either exclusively through the heat exchangers or completely shunted around them, depending on the ambient temperature relative to the body temperature. Our results therefore strongly suggest that such a mechanism is involved in the extensive physiological thermoregulatory abilities of endothermic bigeye tuna.

Optimal usage of low temperature heat sources to supply district heating by heat pumps

DEFF Research Database (Denmark)

Pieper, Henrik; Ommen, Torben Schmidt; Markussen, Wiebke Brix

2017-01-01

This paper presents a theoretical study on the optimal usage of different low temperature heat sources to supply district heating by heat pumps. The study is based on data for the Copenhagen region. The heat sources were prioritized based on the coefficient of performance calculated for each hour...... and the covered demand of each heat source as well as required peak unit capacity. The results showed that heat pumps using different heat sources yield better performance than a heat pump based on a single one. The performance was influenced by the composition of the different heat sources. It was found that 78......% groundwater, 22% seawater and 0% air resulted in highest COP of 3.33 for the given heat demand. Furthermore, the implementation of rule based short term storage made peak units redundant. The variation in base load capacity showed that heat pumps utilizing the analyzed heat sources could perform very...

Comfortable, high-efficiency heat pump with desiccant-coated, water-sorbing heat exchangers.

Science.gov (United States)

Tu, Y D; Wang, R Z; Ge, T S; Zheng, X

2017-01-12

Comfortable, efficient, and affordable heating, ventilation, and air conditioning systems in buildings are highly desirable due to the demands of energy efficiency and environmental friendliness. Traditional vapor-compression air conditioners exhibit a lower coefficient of performance (COP) (typically 2.8-3.8) owing to the cooling-based dehumidification methods that handle both sensible and latent loads together. Temperature- and humidity-independent control or desiccant systems have been proposed to overcome these challenges; however, the COP of current desiccant systems is quite small and additional heat sources are usually needed. Here, we report on a desiccant-enhanced, direct expansion heat pump based on a water-sorbing heat exchanger with a desiccant coating that exhibits an ultrahigh COP value of more than 7 without sacrificing any comfort or compactness. The pump's efficiency is doubled compared to that of pumps currently used in conventional room air conditioners, which is a revolutionary HVAC breakthrough. Our proposed water-sorbing heat exchanger can independently handle sensible and latent loads at the same time. The desiccants adsorb moisture almost isothermally and can be regenerated by condensation heat. This new approach opens up the possibility of achieving ultrahigh efficiency for a broad range of temperature- and humidity-control applications.

Performance of ultra low temperature district heating systems with utility plant and booster heat pumps

DEFF Research Database (Denmark)

Ommen, Torben Schmidt; Thorsen, Jan Eric; Markussen, Wiebke Brix

2017-01-01

The optimal integration of booster heat pumps in ultra low temperature district heating (ULTDH) was investigated and compared to the performance of low temperature district heating. Two possible heat production technologies for the DH networks were analysed, namely extraction combined heat...... temperature and the heat consumption profile. For reference conditions, the optimal return of ULTDH varies between 21 °C and 27 °C. When using a central HP to supply the DH system, the resulting coefficient of system performance (COSP) was in the range of 3.9 (-) to 4.7 (-) for equipment with realistic...... component efficiencies and effectiveness, when including the relevant parameters such as DH system pressure and heat losses. By using ULTDH with booster HPs, performance improvements of 12% for the reference calculations case were found, if the system was supplied by central HPs. Opposite results were found...

Experimental Study of the Performance of Air Source Heat Pump Systems Assisted by Low-Temperature Solar-Heated Water

Directory of Open Access Journals (Sweden)

Jinshun Wu

2013-01-01

Full Text Available Due to the low temperatures, the heating efficiency of air source heat pump systems during the winter is very low. To address this problem, a low-temperature solar hot water system was added to a basic air source heat pump system. Several parameters were tested and analyzed. The heat collection efficiency of the solar collector was analyzed under low-temperature conditions. The factors that affect the performance of the heat pumps, such as the fluid temperature, pressure, and energy savings, were analyzed for cases where the solar energy auxiliary heat pump and the air source heat pump are used independently. The optimal heating temperature and the changes in the fluid temperature were determined. The influence of the compression ratio and the coefficient of performance (COP were investigated theoretically. The results revealed the parameters that are important to the performance of the system. Several measures for improving the COP of the heat pump units are provided for other applications and future research.

Lunar ash flow with heat transfer.

Science.gov (United States)

Pai, S. I.; Hsieh, T.; O'Keefe, J. A.

1972-01-01

The most important heat-transfer process in the ash flow under consideration is heat convection. Besides the four important nondimensional parameters of isothermal ash flow (Pai et al., 1972), we have three additional important nondimensional parameters: the ratio of the specific heat of the gas, the ratio of the specific heat of the solid particles to that of gas, and the Prandtl number. We reexamine the one dimensional steady ash flow discussed by Pai et al. (1972) by including the effects of heat transfer. Numerical results for the pressure, temperature, density of the gas, velocities of gas and solid particles, and volume fraction of solid particles as function of altitude for various values of the Jeffreys number, initial velocity ratio, and two different gas species (steam and hydrogen) are presented.

Low-temperature nuclear heat applications: Nuclear power plants for district heating

International Nuclear Information System (INIS)

1987-08-01

The IAEA reflected the needs of its Member States for the exchange of information in the field of nuclear heat application already in the late 1970s. In the early 1980s, some Member States showed their interest in the use of heat from electricity producing nuclear power plants and in the development of nuclear heating plants. Accordingly, a technical committee meeting with a workshop was organized in 1983 to review the status of nuclear heat application which confirmed both the progress made in this field and the renewed interest of Member States in an active exchange of information about this subject. In 1985 an Advisory Group summarized the Potential of Low-Temperature Nuclear Heat Application; the relevant Technical Document reviewing the situation in the IAEA's Member States was issued in 1986 (IAEA-TECDOC-397). Programme plans were made for 1986-88 and the IAEA was asked to promote the exchange of information, with specific emphasis on the design criteria, operating experience, safety requirements and specifications for heat-only reactors, co-generation plants and power plants adapted for heat application. Because of a growing interest of the IAEA's Member States about nuclear heat employment in the district heating domaine, an Advisory Group meeting was organized by the IAEA on ''Low-Temperature Nuclear Heat Application: Nuclear Power Plants for District Heating'' in Prague, Czechoslovakia in June 1986. The information gained up to 1986 and discussed during this meeting is embodied in the present Technical Document. 22 figs, 11 tabs

The partial molar heat capacity, expansion, isentropic, and isothermal compressions of thymidine in aqueous solution at T = 298.15 K

International Nuclear Information System (INIS)

Hedwig, Gavin R.; Jameson, Geoffrey B.; Hoiland, Harald

2011-01-01

Highlights: → Solution densities and sound speeds were measured for aqueous solutions of thymidine. → Partial molar volumetric properties at infinite dilution and T = 298.15 K were derived. → The partial molar isentropic and isothermal compressions are of opposite signs. → The partial molar heat capacity for thymidine at infinite dilution was determined. - Abstract: Solution densities have been determined for aqueous solutions of thymidine at T = (288.15, 298.15, 303.15, and 313.15) K. The partial molar volumes at infinite dilution, V 2 0 , obtained from the density data were used to derive the partial molar isobaric expansion at infinite dilution for thymidine at T = 298.15 K, E 2 0 {E 2 0 =(∂V 2 0 /∂T) p }. The partial molar heat capacity at infinite dilution for thymidine, C p,2 0 , at T = 298.15 K has also been determined. Sound speeds have been measured for aqueous solutions of thymidine at T = 298.15 K. The partial molar isentropic compression at infinite dilution, K S,2 0 , and the partial molar isothermal compression at infinite dilution, K T,2 0 {K T,2 0 =-(∂V 2 0 /∂P) T }, have been derived from the sound speed data. The V 2 0 , E 2 0 , C p,2 0 , and K S,2 0 results for thymidine are critically compared with those available from the literature.

Temperature-gated thermal rectifier for active heat flow control.

Science.gov (United States)

Zhu, Jia; Hippalgaonkar, Kedar; Shen, Sheng; Wang, Kevin; Abate, Yohannes; Lee, Sangwook; Wu, Junqiao; Yin, Xiaobo; Majumdar, Arun; Zhang, Xiang

2014-08-13

Active heat flow control is essential for broad applications of heating, cooling, and energy conversion. Like electronic devices developed for the control of electric power, it is very desirable to develop advanced all-thermal solid-state devices that actively control heat flow without consuming other forms of energy. Here we demonstrate temperature-gated thermal rectification using vanadium dioxide beams in which the environmental temperature actively modulates asymmetric heat flow. In this three terminal device, there are two switchable states, which can be regulated by global heating. In the "Rectifier" state, we observe up to 28% thermal rectification. In the "Resistor" state, the thermal rectification is significantly suppressed (Rectifier state. This temperature-gated rectifier can have substantial implications ranging from autonomous thermal management of heating and cooling systems to efficient thermal energy conversion and storage.

Isothermal α″ formation in β metastable titanium alloys

International Nuclear Information System (INIS)

Aeby-Gautier, E.; Settefrati, A.; Bruneseaux, F.; Appolaire, B.; Denand, B.; Dehmas, M.; Geandier, G.; Boulet, P.

2013-01-01

Highlights: ► Isothermal kinetics of orthorhombic α″ formation is characterized by HEXRD. ► Cell parameters of parent and product phases are obtained. ► Partitioning of solutes during the transformation and the ageing is discussed. -- Abstract: Thanks to time resolved high energy X-ray diffraction, isothermal decomposition of β metastable phase was studied, directly after solution treatment in the β temperature range, for temperatures ranging from 300 to 450 °C for two beta metastable alloys (Ti 17 and Ti 5553). The formation of an orthorhombic α″ phase is clearly identified at the beginning of the transformation whatever the alloy studied. If transformation occurs at the higher temperature an evolution of α″ is observed toward the hexagonal α phase. The phase amounts and the mean cell parameters of each phase were quantified by the Rietveld refinement method. The obtained cell parameters evolutions and the orthorhombicity of α″ are discussed. Moreover, the orthorhombicity of α″ compared to that obtained for stress induced martensite may indicate a slight partitioning of solutes in isothermal α″

Isothermal α″ formation in β metastable titanium alloys

Energy Technology Data Exchange (ETDEWEB)

Aeby-Gautier, E., E-mail: Elisabeth.Gautier@mines.inpl-nancy.fr [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Settefrati, A. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Airbus Operations, Materials and Processes, Toulouse (France); Bruneseaux, F. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France); Appolaire, B. [Laboratoire d’Etudes des Microstructures ONERA – CNRS Chatillon (France); Denand, B.; Dehmas, M.; Geandier, G.; Boulet, P. [Institut Jean Lamour, UMR CNRS Nancy Université, UPVM 7198, Nancy (France)

2013-11-15

Highlights: ► Isothermal kinetics of orthorhombic α″ formation is characterized by HEXRD. ► Cell parameters of parent and product phases are obtained. ► Partitioning of solutes during the transformation and the ageing is discussed. -- Abstract: Thanks to time resolved high energy X-ray diffraction, isothermal decomposition of β metastable phase was studied, directly after solution treatment in the β temperature range, for temperatures ranging from 300 to 450 °C for two beta metastable alloys (Ti 17 and Ti 5553). The formation of an orthorhombic α″ phase is clearly identified at the beginning of the transformation whatever the alloy studied. If transformation occurs at the higher temperature an evolution of α″ is observed toward the hexagonal α phase. The phase amounts and the mean cell parameters of each phase were quantified by the Rietveld refinement method. The obtained cell parameters evolutions and the orthorhombicity of α″ are discussed. Moreover, the orthorhombicity of α″ compared to that obtained for stress induced martensite may indicate a slight partitioning of solutes in isothermal α″.

Innovative system for delivery of low temperature district heating

OpenAIRE

Ianakiev, A; Cui, JM; Garbett, S; Filer, A

2017-01-01

An innovative low temperature district heating (LTDH) local network is developed in Nottingham, supported by the REMOURBAN project, part of the H2020 Smart City and Community Lighthouse scheme. It was proposed that a branch emanating from the return pipe of the existing district heating system in Nottingham would be created to use low temperature heating for the first time on such scale in the UK. The development is aimed to extract unused heat from existing district heating system and to mak...

A thermoacoustic engine capable of utilizing multi-temperature heat sources

International Nuclear Information System (INIS)

Qiu Limin; Wang Bo; Sun Daming; Liu Yu; Steiner, Ted

2009-01-01

Low-grade energy is widespread. However, it cannot be utilized with high thermal efficiency directly. Following the principle of thermal energy cascade utilization, a thermoacoustic engine (TE) with a new regenerator that can be driven by multiple heat sources at different temperature levels is proposed. Taking a regenerator that utilizes heat sources at two temperatures as an example, theoretical research has been conducted on a traveling-wave TE with the new regenerator to predict its performance. Experimental verification is also done to demonstrate the benefits of the new regenerator. Results indicate that a TE with the new regenerator utilizing additional heat at a lower temperature experiences an increase in pressure ratio, acoustic power, efficiency, and exergy efficiency with proper heat input at an appropriate temperature at the mid-heater. A regenerator that uses multi-temperature heat sources can provide a means of recovering lower grade heat.

A new method to determine the water activity and the net isosteric heats of sorption for low moisture foods at elevated temperatures.

Science.gov (United States)

Tadapaneni, Ravi Kiran; Yang, Ren; Carter, Brady; Tang, Juming

2017-12-01

In recent years, research studies have shown that the thermal resistance of foodborne pathogens in the low moisture foods is greatly influenced by the water activity (a w ) at temperatures relevant to thermal treatments for pathogen control. Yet, there has been a lack of an effective method for accurate measurement of a w at those temperatures. Thus, the main aim of this study was to evaluate a new method for measuring a w of food samples at elevated temperatures. An improved thermal cell with a relative humidity and temperature sensor was used to measure the a w of the three different food samples, namely, organic wheat flour, almond flour, and non-fat milk powder, over the temperature range between 20 and 80°C. For a constant moisture content, the a w data was used to estimate the net isosteric heat of sorption (q st ). The q st values were then used in the Clausius Clapeyron equation (CCE) equation to estimate the moisture sorption isotherm for all test food samples at different temperatures. For all the tested samples of any fixed moisture content, a w value generally increased with the temperature. The energy for sorption decreased with increasing moisture content. With the experimentally determined q st value, CCE describes well about the changes in a w of the food samples between 20 and 80°C. This study presents a method to obtain a w of a food sample for a specific moisture content at different temperatures which could be extended to obtain q st values for different moisture contents and hence, the moisture sorption isotherm of a food sample at different temperatures. Copyright © 2017 Elsevier Ltd. All rights reserved.

Active ion temperature measurement with heating neutral beam

International Nuclear Information System (INIS)

Miura, Yukitoshi; Matsuda, Toshiaki; Yamamoto, Shin

1987-03-01

When the heating neutral-beam (hydrogen beam) is injected into a deuterium plasma, the density of neutral particles is increased locally. By using this increased neutral particles, the local ion temperature is measured by the active charge-exchange method. The analyzer is the E//B type mass-separated neutral particle energy analyzer and the measured position is about one third outside of the plasma radius. The deuterium energy spectrum is Maxwellian, and the temperature is increased from 350 eV to 900 eV during heating. Since the local hydrogen to deuterium density concentration and the density of the heating neutral-beam as well as the ion temperature can be obtained good S/N ratio, the usefulness of this method during neutral-beam heating is confirmed by this experiment. (author)

Lauric and palmitic acids eutectic mixture as latent heat storage material for low temperature heating applications

International Nuclear Information System (INIS)

Tuncbilek, Kadir; Sari, Ahmet; Tarhan, Sefa; Erguenes, Gazanfer; Kaygusuz, Kamil

2005-01-01

Palmitic acid (PA, 59.8 deg. C) and lauric acid (LA, 42.6 deg. C) are phase change materials (PCM) having quite high melting temperatures which can limit their use in low temperature solar applications such as solar space heating and greenhouse heating. However, their melting temperatures can be tailored to appropriate value by preparing a eutectic mixture of the lauric and the palmitic acids. In the present study, the thermal analysis based on differential scanning calorimetry (DSC) technique shows that the mixture of 69.0 wt% LA and 31 wt% PA forms a eutectic mixture having melting temperature of 35.2 deg. C and the latent heat of fusion of 166.3 J g -1 . This study also considers the experimental determination of the thermal characteristics of the eutectic mixture during the heat charging and discharging processes. Radial and axial temperature distribution, heat transfer coefficient between the heat transfer fluid (HTF) pipe and the PCM, heat recovery rate and heat charging and discharging fractions were experimentally established employing a vertical concentric pipe-in-pipe energy storage system. The changes of these characteristics were evaluated with respect to the effect of inlet HTF temperature and mass flow rate. The DSC thermal analysis and the experimental results indicate that the LA-PA eutectic mixture can be a potential material for low temperature thermal energy storage applications in terms of its thermo-physical and thermal characteristics

Non-isothermal crystallization kinetics of As{sub 30}Te{sub 60}Ga{sub 10} glass

Energy Technology Data Exchange (ETDEWEB)

Mohamed, Mansour; Abd-Elnaiem, Alaa M.; Abdel-Rahim, M.A.; Hafiz, M.M. [Assiut University, Physics Department, Faculty of Science, Assiut (Egypt); Hassan, R.M. [Assiut University, Physics Department, Faculty of Science, Assiut (Egypt); Aden University, Physics Department, Faculty of Education-Zingiber, Aden (Yemen)

2017-08-15

The crystallization study under non-isothermal conditions of As{sub 30}Te{sub 60}Ga{sub 10} glass was investigated. The studied composition was synthesized by melt-quenching technique and characterized by different techniques such as X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and differential scanning calorimetry (DSC). The XRD analysis revealed that the as-prepared and annealed bulk glass of As{sub 30}Te{sub 60}Ga{sub 10} exhibit the amorphous, and polycrystalline nature, respectively. The DSC results showed that the heating rate affects the characteristic temperatures, for instance, the glass transition, onset, and peak crystallization temperatures. Furthermore, some thermal analysis methods such as the Kissinger and Matusita et al., approximations were employed to determine the crystallization parameters: for example Avrami exponent and the activation energies for glass transition and crystallization process. In addition, we have compared the experimental DSC data with the calculated ones based on the Johnson-Mehl-Avrami (JMA) and Sestak-Berggren SB(M,N) models. The results indicated that the SB(M,N) model is more suitable for describing the non-isothermal crystallization kinetics of the investigated composition. (orig.)

Effects of rotation on MHD flow past an accelerated isothermal vertical plate with heat and mass diffusion

Directory of Open Access Journals (Sweden)

Muthucumaraswamy R.

2010-01-01

Full Text Available An exact analysis of rotation effects on unsteady flow of an incompressible and electrically conducting fluid past a uniformly accelerated infinite isothermal vertical plate, under the action of transversely applied magnetic field has been presented. The plate temperature is raised to Tw and the concentration level near the plate is also raised to C′w . The dimensionless governing equations are solved using Laplace-transform technique. The velocity profiles, temperature and concentration are studied for different physical parameters like thermal Grashof number, mass Grashof number, Schmidt number, Prandtl number and time. It is observed that the velocity increases with increasing values of thermal Grashof number or mass Grashof number. It is also observed that the velocity increases with decreasing magnetic field parameter.

Low Temperature District Heating for Future Energy Systems

DEFF Research Database (Denmark)

Ford, Rufus; Pietruschka, Dirk; Sipilä, Kari

participants being VTT Technical Research Centre of Finland (VTT), Technical University of Denmark (DTU), Norwegian University of Science and Technology (NTNU), Stuttgart Technology University of Applied Sciences (HFT) and SSE Enterprise in United Kingdom. The demonstration cases described in the report......This report titled “Case studies and demonstrations” is the subtask D report of the IEA DHC|CHP Annex TS1 project “Low Temperature District Heating for Future Energy Systems” carried out between 2013 and 2016. The project was led by Fraunhofer Institute for Building Physics (IBP) with the other...... include examples on low temperature district heating systems, solar heating in a district heating system, heat pump based heat supply and energy storages for both peak load management and for seasonal heat storage. Some demonstrations have been implemented while others are at planning phase...

Low temperature oxidation and spontaneous combustion characteristics of upgraded low rank coal

Energy Technology Data Exchange (ETDEWEB)

Choi, H.K.; Kim, S.D.; Yoo, J.H.; Chun, D.H.; Rhim, Y.J.; Lee, S.H. [Korea Institute of Energy Research, Daejeon (Korea, Republic of)

2013-07-01

The low temperature oxidation and spontaneous combustion characteristics of dried coal produced from low rank coal using the upgraded brown coal (UBC) process were investigated. To this end, proximate properties, crossing-point temperature (CPT), and isothermal oxidation characteristics of the coal were analyzed. The isothermal oxidation characteristics were estimated by considering the formation rates of CO and CO{sub 2} at low temperatures. The upgraded low rank coal had higher heating values than the raw coal. It also had less susceptibility to low temperature oxidation and spontaneous combustion. This seemed to result from the coating of the asphalt on the surface of the coal, which suppressed the active functional groups from reacting with oxygen in the air. The increasing upgrading pressure negatively affected the low temperature oxidation and spontaneous combustion.

Comparison of LCA results of low temperature heat plant using electric heat pump, absorption heat pump and gas-fired boiler

International Nuclear Information System (INIS)

Nitkiewicz, Anna; Sekret, Robert

2014-01-01

Highlights: • Usage of geothermal heat pump can bring environmental benefits. • The lowest environmental impact for whole life cycle is obtained for absorption heat pump. • The value of heat pump COP has a significant influence on environmental impact. • In case of coal based power generation the damage to human health is significant. - Abstract: This study compares the life cycle impacts of three heating plant systems which differ in their source of energy and the type of system. The following heating systems are considered: electric water-water heat pump, absorption water-water heat pump and natural gas fired boiler. The heat source for heat pump systems is low temperature geothermal source with temperature below 20 °C and spontaneous outflow 24 m 3 /h. It is assumed that the heat pumps and boiler are working in monovalent system. The analysis was carried out for heat networks temperature characteristic at 50/40 °C which is changing with outdoor temperature during heating season. The environmental life cycle impact is evaluated within life cycle assessment methodological framework. The method used for life cycle assessment is eco-indicator ‘99. The functional unit is defined as heating plant system with given amount of heat to be delivered to meet local heat demand in assumed average season. The data describing heating plant system is derived from literature and energy analysis of these systems. The data describing the preceding life cycle phases: extraction of raw materials and fuels, production of heating devices and their transportation is taken from Ecoinvent 2.0 life cycle inventory database. The results were analyzed on three levels of indicators: single score indicator, damage category indicators and impact category indicator. The indicators were calculated for characterization, normalization and weighting phases as well. SimaPro 7.3.2 is the software used to model the systems’ life cycle. The study shows that heating plants using a low

Isothermal phase transition and the transition temperature limitation in the lead-free (1-x)Bi0.5Na0.5TiO3-xBaTiO3 system

International Nuclear Information System (INIS)

Zhang, Dawei; Yao, Yonggang; Fang, Minxia; Luo, Zhengdong; Zhang, Lixue; Li, Linglong; Cui, Jian; Zhou, Zhijian; Bian, Jihong; Ren, Xiaobing; Yang, Yaodong

2016-01-01

Most ferroelectric transitions occur ultrafast and are time independent. However, here in (1-x) (Bi 0.5 Na 0.5 )TiO 3 -xBaTiO 3 , we have found a ferroelectric phase transition induced solely by increasing waiting time at certain temperatures (isothermal phase transition). Through cooling, a unique metastable state between a relaxor ferroelectric and a ferroelectric is unveiled, which in essence is initially a short-range ordered glassy state and then can evolve into a long-range ordered ferroelectric state through the isothermal process. It is also found that these isothermal ferroelectric transitions only occur within a specific temperature region with different waiting time needed. These features of isothermal phase transition can be understood by Landau theory analysis with the consideration of random defects as a competition between the thermodynamically favored long-range ordered state and the kinetically frustrated short-range ordered glassy state from random defects. This study offers a precise experimental as well as a phenomenological interpretation on the isothermal ferroelectric transition, which may help to further clarify the intricate structure-property relationship in this important lead-free piezoelectric material and other related systems.

Calculation of the fuel temperature field under heat release and heat conductance transient conditions

International Nuclear Information System (INIS)

Kazakov, E.K.; Chernukhina, G.M.

1974-01-01

Results of calculation of the temperature distribution in an annular fuel element at transient thermal conductivity and heat release values are given. The calculation has been carried out by the mesh technique with the third-order boundary conditions for the inner surface assumed and with heat fluxes and temperatures at the zone boundaries to be equal. Three variants of solving the problem of a stationary temperature field are considered for failed fuel elements with clad flaking or cracks. The results obtained show the nonuniformity of the fuel element temperature field to depend strongly on the perturbation parameter at transient thermal conductivity and heat release values. In case of can flaking at a short length, the core temperature rises quickly after flaking. While evaluating superheating, one should take into account the symmetry of can flaking [ru

Developing Buoyancy Driven Flow of a Nanofluid in a Vertical Channel Subject to Heat Flux

Directory of Open Access Journals (Sweden)

Nirmal C. Sacheti

2014-01-01

Full Text Available The developing natural convective flow of a nanofluid in an infinite vertical channel with impermeable bounding walls has been investigated. It is assumed that the nanofluid is dominated by two specific slip mechanisms and that the channel walls are subject to constant heat flux and isothermal temperature, respectively. The governing nonlinear partial differential equations coupling different transport processes have been solved numerically. The variations of velocity, temperature, and nanoparticles concentration have been discussed in relation to a number of physical parameters. It is seen that the approach to the steady-state profiles of velocity and temperature in the present work is different from the ones reported in a previous study corresponding to isothermal wall conditions.

Maximum Power Output of Quantum Heat Engine with Energy Bath

Directory of Open Access Journals (Sweden)

Shengnan Liu

2016-05-01

Full Text Available The difference between quantum isoenergetic process and quantum isothermal process comes from the violation of the law of equipartition of energy in the quantum regime. To reveal an important physical meaning of this fact, here we study a special type of quantum heat engine consisting of three processes: isoenergetic, isothermal and adiabatic processes. Therefore, this engine works between the energy and heat baths. Combining two engines of this kind, it is possible to realize the quantum Carnot engine. Furthermore, considering finite velocity of change of the potential shape, here an infinite square well with moving walls, the power output of the engine is discussed. It is found that the efficiency and power output are both closely dependent on the initial and final states of the quantum isothermal process. The performance of the engine cycle is shown to be optimized by control of the occupation probability of the ground state, which is determined by the temperature and the potential width. The relation between the efficiency and power output is also discussed.

Crystallization of Polymers Investigated by Temperature-Modulated DSC

Directory of Open Access Journals (Sweden)

Maria Cristina Righetti

2017-04-01

Full Text Available The aim of this review is to summarize studies conducted by temperature-modulated differential scanning calorimetry (TMDSC on polymer crystallization. This technique can provide several advantages for the analysis of polymers with respect to conventional differential scanning calorimetry. Crystallizations conducted by TMDSC in different experimental conditions are analysed and discussed, in order to illustrate the type of information that can be deduced. Isothermal and non-isothermal crystallizations upon heating and cooling are examined separately, together with the relevant mathematical treatments that allow the evolution of the crystalline, mobile amorphous and rigid amorphous fractions to be determined. The phenomena of ‘reversing’ and ‘reversible‘ melting are explicated through the analysis of the thermal response of various semi-crystalline polymers to temperature modulation.

Temperature distribution of the energy consumed as heat in Canada

International Nuclear Information System (INIS)

Puttagunta, V.R.

1974-10-01

The amount of energy consumed as heat (excluding thermal generation of electricity) in Canada is estimated from statistical data available on the total consumption of energy for the years 1958 to 2000. Based on some actual plant data and other statistical information this energy consumption is sub-divided into four temperature categories: high (>260 degrees C), intermediate (140-260 degrees C), low (100-140 degrees C), and space heating (<100 degrees C). The results of this analysis show that approximately half of all the energy consumed in Canada has an end use as heat. Less than 10 percent of the energy consumed as heat is in the high temperature category, 12 to 14 percent is in the intermediate temperature range, 21 to 27 percent is in the low temperature range, and 50 to 58 percent is used for space heating. Over 90 percent of the energy consumed as heat in Canada is within the temperature capability of the CANDU-PHW reactor. (author)

Heat treatment for improvement in lower temperature mechanical properties of 0.40 pct C-Cr-Mo ultrahigh strength steel

Science.gov (United States)

Tomita, Yoshiyuki; Okabayashi, Kunio

1983-11-01

In the previous paper, it was reported that isothermal heat treatment of a commercial Japanese 0.40 pct C-Ni-Cr-Mo ultrahigh strength steel (AISI 4340 type) at 593 K for a short time followed by water quenching, in which a mixed structure of 25 vol pct lower bainite and 75 vol pct martensite is produced, results in the improvement of low temperature mechanical properties (287 to 123 K). The purpose of this paper is to study whether above new heat treatment will still be effective in commercial practice for improving low temperature mechanical properties of the ultrahigh strength steel when applied to a commercial Japanese 0.40 pct C-Cr-Mo ultrahigh strength steel which is economical because it lacks the expensive nickel component (AISI 4140 type). At and above 203 K this new heat treatment, as compared with the conventional 1133 K direct water quenching treatment, significantly improved the strength, tensile ductility, and notch toughness of the 0.40 pct C-Cr-Mo ultrahigh strength steel. At and above 203 K the new heat treatment also produced superior fracture ductility and notch toughness results at similar strength levels as compared to those obtained by using γ α' repetitive heat treatment for the same steel. However, the new heat treatment remarkably decreased fracture ductility and notch toughness of the 0.40 pct C-Cr-Mo ultrahigh strength steel below 203 K, and thus no significant improvement in the mechanical properties was noticeable as compared with the properties produced by the conventional 1133 K direct water quenching treatment and the γ α' repetitive heat treatment. This contrasts with the fact that the new heat treatment, as compared with the conventional 1133 K direct water quenching treatment and the γ α' repetitive heat treatment, dramatically improved the notch toughness of the 0.40 pct C-Ni-Cr-Mo ultrahigh strength steel, providing a better combination of strength and ductility throughout the 287 to 123 K temperature range. The difference

Heat exchangers and recuperators for high temperature waste gases

Science.gov (United States)

Meunier, H.

General considerations on high temperature waste heat recovery are presented. Internal heat recovery through combustion air preheating and external heat recovery are addressed. Heat transfer and pressure drop in heat exchanger design are discussed.

Method of determination of temperature and heat resistance of the points on the integrated circuit crystal surface

Directory of Open Access Journals (Sweden)

Popov V. M.

2011-12-01

Full Text Available Method for visualization of integrated circuit (IC surface temperature by means of the liquid crystal film deposited from solution on its surface is proposed. The boundaries of local regions represent isotherms with corresponding phase transitions. On the base of isotherms positions and consumed by IC power thermal resistances between crystal and environment are determined.

Subsurface urban heat islands in German cities.

Science.gov (United States)

Menberg, Kathrin; Bayer, Peter; Zosseder, Kai; Rumohr, Sven; Blum, Philipp

2013-01-01

Little is known about the intensity and extension of subsurface urban heat islands (UHI), and the individual role of the driving factors has not been revealed either. In this study, we compare groundwater temperatures in shallow aquifers beneath six German cities of different size (Berlin, Munich, Cologne, Frankfurt, Karlsruhe and Darmstadt). It is revealed that hotspots of up to +20K often exist, which stem from very local heat sources, such as insufficiently insulated power plants, landfills or open geothermal systems. When visualizing the regional conditions in isotherm maps, mostly a concentric picture is found with the highest temperatures in the city centers. This reflects the long-term accumulation of thermal energy over several centuries and the interplay of various factors, particularly in heat loss from basements, elevated ground surface temperatures (GST) and subsurface infrastructure. As a primary indicator to quantify and compare large-scale UHI intensity the 10-90%-quantile range UHII(10-90) of the temperature distribution is introduced. The latter reveals, in comparison to annual atmospheric UHI intensities, an even more pronounced heating of the shallow subsurface. Copyright © 2012 Elsevier B.V. All rights reserved.

Desalination by very low temperature nuclear heat

International Nuclear Information System (INIS)

Saari, Risto

1977-01-01

A new sea water desalination method has been developed: Nord-Aqua Vacuum Evaporation, which utilizes waste heat at a very low temperature. The requisite vacuum is obtained by the aid of a barometric column and siphon, and the dissolved air is removed from the vacuum by means of water flows. According to test results from a pilot plant, the process is operable if the waste heat exists at a temperature 7degC higher than ambient. The pumping energy which is then required is 9 kcal/kg, or 1.5% of the heat of vaporization of water. Calculations reveal that the method is economically considerably superior to conventional distilling methods. (author)

Numerical study of inflow conditions on a turbulent isothermal or heated plane jet; Etude numerique des conditions d'emission sur un ecoulement de type jet plan turbulent isotherme ou chauffe

Energy Technology Data Exchange (ETDEWEB)

Mhiri, H.; Habli, S.; El Golli, S. [Ecole Nationale d' Ingenieurs de Monastir (Tunisia); Le Palec, G.; Bournot, Ph. [Institut de Mecanique de Marseille (France)

1999-11-01

We intend to solve equations governing turbulent plane-vertical isotherm and non isotherm jets by taking into account inflow conditions at the exit of the nozzle. The analysis is focused on the influence of these conditions on this type of flow. Two cases are considered (uniform and parabolic velocity and temperature profiles). A finite difference scheme is developed to solve the governing equations. This numeric model allows us to show that the region of fully developed regime begins much nearer the nozzle for the turbulent case than for the laminar flow case. Indeed, the turbulence increases the mixing between the incoming gas from the nozzle and the ambient fluid, and consequently the size of the potential core zone decreases. The results are compared to other works introducing mathematical variables based on the energy conservation for the case of the mixed convection and the momentum conservation for the forced convection, which allows the validation of our results. (authors)

Phase change heat transfer device for process heat applications

International Nuclear Information System (INIS)

Sabharwall, Piyush; Patterson, Mike; Utgikar, Vivek; Gunnerson, Fred

2010-01-01

The next generation nuclear plant (NGNP) will most likely produce electricity and process heat, with both being considered for hydrogen production. To capture nuclear process heat, and transport it to a distant industrial facility requires a high temperature system of heat exchangers, pumps and/or compressors. The heat transfer system is particularly challenging not only due to the elevated temperatures (up to ∼1300 K) and industrial scale power transport (≥50 MW), but also due to a potentially large separation distance between the nuclear and industrial plants (100+ m) dictated by safety and licensing mandates. The work reported here is the preliminary analysis of two-phase thermosyphon heat transfer performance with alkali metals. A thermosyphon is a thermal device for transporting heat from one point to another with quite extraordinary properties. In contrast to single-phased forced convective heat transfer via 'pumping a fluid', a thermosyphon (also called a wickless heat pipe) transfers heat through the vaporization/condensing process. The condensate is further returned to the hot source by gravity, i.e., without any requirement of pumps or compressors. With this mode of heat transfer, the thermosyphon has the capability to transport heat at high rates over appreciable distances, virtually isothermally and without any requirement for external pumping devices. Two-phase heat transfer by a thermosyphon has the advantage of high enthalpy transport that includes the sensible heat of the liquid, the latent heat of vaporization, and vapor superheat. In contrast, single-phase forced convection transports only the sensible heat of the fluid. Additionally, vapor-phase velocities within a thermosyphon are much greater than single-phase liquid velocities within a forced convective loop. Thermosyphon performance can be limited by the sonic limit (choking) of vapor flow and/or by condensate entrainment. Proper thermosyphon requires analysis of both.

Thermodynamic Temperatures of High-Temperature Fixed Points: Uncertainties Due to Temperature Drop and Emissivity

Science.gov (United States)

Castro, P.; Machin, G.; Bloembergen, P.; Lowe, D.; Whittam, A.

2014-07-01

This study forms part of the European Metrology Research Programme project implementing the New Kelvin to assign thermodynamic temperatures to a selected set of high-temperature fixed points (HTFPs), Cu, Co-C, Pt-C, and Re-C. A realistic thermal model of these HTFPs, developed in finite volume software ANSYS FLUENT, was constructed to quantify the uncertainty associated with the temperature drop across the back wall of the cell. In addition, the widely applied software package, STEEP3 was used to investigate the influence of cell emissivity. The temperature drop, , relates to the temperature difference due to the net loss of heat from the aperture of the cavity between the back wall of the cavity, viewed by the thermometer, defining the radiance temperature, and the solid-liquid interface of the alloy, defining the transition temperature of the HTFP. The actual value of can be used either as a correction (with associated uncertainty) to thermodynamic temperature evaluations of HTFPs, or as an uncertainty contribution to the overall estimated uncertainty. In addition, the effect of a range of furnace temperature profiles on the temperature drop was calculated and found to be negligible for Cu, Co-C, and Pt-C and small only for Re-C. The effective isothermal emissivity is calculated over the wavelength range from 450 nm to 850 nm for different assumed values of surface emissivity. Even when furnace temperature profiles are taken into account, the estimated emissivities change only slightly from the effective isothermal emissivity of the bare cell. These emissivity calculations are used to estimate the uncertainty in the temperature assignment due to the uncertainty in the emissivity of the blackbody.

A new predictive dynamic model describing the effect of the ambient temperature and the convective heat transfer coefficient on bacterial growth.

Science.gov (United States)

Ben Yaghlene, H; Leguerinel, I; Hamdi, M; Mafart, P

2009-07-31

In this study, predictive microbiology and food engineering were combined in order to develop a new analytical model predicting the bacterial growth under dynamic temperature conditions. The proposed model associates a simplified primary bacterial growth model without lag, the secondary Ratkowsky "square root" model and a simplified two-parameter heat transfer model regarding an infinite slab. The model takes into consideration the product thickness, its thermal properties, the ambient air temperature, the convective heat transfer coefficient and the growth parameters of the micro organism of concern. For the validation of the overall model, five different combinations of ambient air temperature (ranging from 8 degrees C to 12 degrees C), product thickness (ranging from 1 cm to 6 cm) and convective heat transfer coefficient (ranging from 8 W/(m(2) K) to 60 W/(m(2) K)) were tested during a cooling procedure. Moreover, three different ambient air temperature scenarios assuming alternated cooling and heating stages, drawn from real refrigerated food processes, were tested. General agreement between predicted and observed bacterial growth was obtained and less than 5% of the experimental data fell outside the 95% confidence bands estimated by the bootstrap percentile method, at all the tested conditions. Accordingly, the overall model was successfully validated for isothermal and dynamic refrigeration cycles allowing for temperature dynamic changes at the centre and at the surface of the product. The major impact of the convective heat transfer coefficient and the product thickness on bacterial growth during the product cooling was demonstrated. For instance, the time needed for the same level of bacterial growth to be reached at the product's half thickness was estimated to be 5 and 16.5 h at low and high convection level, respectively. Moreover, simulation results demonstrated that the predicted bacterial growth at the air ambient temperature cannot be assumed to be

Water-Column Stratification Observed along an AUV-Tracked Isotherm

Science.gov (United States)

Zhang, Y.; Messié, M.; Ryan, J. P.; Kieft, B.; Stanway, M. J.; Hobson, B.; O'Reilly, T. C.; Raanan, B. Y.; Smith, J. M.; Chavez, F.

2016-02-01

Studies of marine physical, chemical and microbiological processes benefit from observing in a Lagrangian frame of reference, i.e. drifting with ambient water. Because these processes can be organized relative to specific density or temperature ranges, maintaining observing platforms within targeted environmental ranges is an important observing strategy. We have developed a novel method to enable a Tethys-class long-range autonomous underwater vehicle (AUV) (which has a propeller and a buoyancy engine) to track a target isotherm in buoyancy-controlled drift mode. In this mode, the vehicle shuts off its propeller and autonomously detects the isotherm and stays with it by actively controlling the vehicle's buoyancy. In the June 2015 CANON (Controlled, Agile, and Novel Observing Network) Experiment in Monterey Bay, California, AUV Makai tracked a target isotherm for 13 hours to study the coastal upwelling system. The tracked isotherm started from 33 m depth, shoaled to 10 m, and then deepened to 29 m. The thickness of the tracked isotherm layer (within 0.3°C error from the target temperature) increased over this duration, reflecting weakened stratification around the isotherm. During Makai's isotherm tracking, another long-range AUV, Daphne, acoustically tracked Makai on a circular yo-yo trajectory, measuring water-column profiles in Makai's vicinity. A wave glider also acoustically tracked Makai, providing sea surface measurements on the track. The presented method is a new approach for studying water-column stratification, but requires careful analysis of the temporal and spatial variations mingled in the vehicles' measurements. We will present a synthesis of the water column's stratification in relation to the upwelling conditions, based on the in situ measurements by the mobile platforms, as well as remote sensing and mooring data.

Heat capacity and magnetocaloric effect in polycrystalline Gd 1-xSm xMn 2Si 2

Science.gov (United States)

Kumar, Pramod; Singh, Niraj K.; Suresh, K. G.; Nigam, A. K.; Malik, S. K.

2007-12-01

We report the magnetocaloric effect in terms of isothermal magnetic entropy change as well as adiabatic temperature change, calculated using the heat capacity data. Using the zero-field heat capacity data, the magnetic contribution to the heat capacity has been estimated. The variations in the magnetocaloric behavior have been explained on the basis of the magnetic structure of these compounds. The refrigerant capacities have also been calculated for these compounds.

Effect of heat-treatment on elevated temperature fatigue-crack growth behavior of two heats of Alloy 718

International Nuclear Information System (INIS)

Mills, W.J.; James, L.A.

1978-05-01

The room temperature and elevated temperature fatigue-crack growth behavior of two heats of Alloy 718 was characterized within a linear-elastic fracture mechanics framework. Two different heat-treatments were used: the ''conventional'' (ASTM A637) treatment, and a ''modified'' heat-treatment designed to improve the toughness of Alloy 718 base metal and weldments. Heat-to-heat variations in the fatigue-crack propagation behavior were observed in the conventionally-treated material. On the other hand, no heat-to-heat variations were observed in the modified condition. Furthermore, both heats of Alloy 718 exhibited superior fatigue-crack growth resistance when given the modified heat-treatment. Electron fractographic examination of Alloy 718 fatigue fracture surfaces revealed that the operative crack growth mechanisms were dependent on heat-treatment, temperature, and ΔK level

DuPont IsoTherming clean fuel technology

Energy Technology Data Exchange (ETDEWEB)

Levinski, E. [E.I. DuPont Co., Wilmington, DE (United States)

2009-07-01

This poster described a hydroprocessing technology that DuPont has acquired from Process Dynamics, Inc. The IsoTherming clean fuel technology significantly reduces sulphur in motor fuels. The technology provides petroleum refiners the solution for meeting ultra low sulphur diesel requirements, at much lower costs than conventional technologies. IsoTherming hydroprocessing operates in a kinetically limited mode, with no mass transfer limitation. Hydrogen is delivered to the reactor in the liquid phase as soluble hydrogen, allowing for much higher space velocities than conventional hydrotreating reactors. Treated diesel is recycled back to the inlet of the reactor, generating less heat and more hydrogen into the reactor. The process results in a more isothermal reactor operation that allows for better yields, fewer light ends and greater catalyst life. The technology reduces coking, because the process provides enough hydrogen in the solution when cracking reactions take place. As a result, the process yields longer catalyst life. Other advantages for refiners include lower total investment; reduced equipment delivery lead times; reduced maintenance and operating costs; and configuration flexibility. tabs., figs.

On Microstructure and Microhardness of Isothermally Aged UNS S32760 and the Effect on Toughness and Corrosion Behavior

Science.gov (United States)

Elsabbagh, Fady M.; Hamouda, Rawia M.; Taha, Mohamed A.

2014-01-01

This paper investigates the microstructure and secondary phase precipitations obtained in UNS S32760 super duplex stainless steel and their effect on impact toughness and corrosion resistance. The heat treatment included first solution annealing at 1150 °C followed by water quenching, then isothermal heating at different temperatures from 350 to 950 °C for different times, ranging from less than 1 min to 600 min, followed by water quenching again. Microscopic investigation, microhardness tests, and x-ray diffraction (XRD) analysis were used to identify the microstructure and secondary phase precipitations formed by heat treatment. The study indicates a fair correlation between the microscopic observations and microhardness results, while XRD analysis defined the phase's chemistry and confirmed the microscopic and hardness results. In addition to the austenite (γ) and ferrite (α) phases of the duplex structure, secondary phases of (σ, χ, and chromium nitrides) are observed at a high temperature range, while (ά) and (aged ά) are observed at a lower temperature range. It is concluded that the microhardness test can be used to identify the phases appearing in the microstructure, which results in fair prediction for the TTT diagram and σ-phase range. The variation of toughness and corrosion resistance by heat treatment differs depending on the secondary phase formation.

Exergetic evaluation of heat pump booster configurations in a low temperature district heating network

DEFF Research Database (Denmark)

Ommen, Torben Schmidt; Elmegaard, Brian

2012-01-01

In order to minimise losses in a district heating network, one approach is to lower the temperature difference between working media and soil. Considering only direct heat exchange, the minimum forward temperature level is determined by the demand side, as energy services are required at a certai...

Heat transfer and critical heat flux in a asymmetrically heated tube helicoidal flow; Transfert thermique et flux critique dans un ecoulement helicoidal en tube chauffe asymetriquement

Energy Technology Data Exchange (ETDEWEB)

Boscary, J

1995-10-01

The design of plasma facing components is crucial for plasma performance in next fusion reactors. These elements will be submitted to very high heat flux. They will be actively water-cooled by swirl tubes in the subcooled boiling regime. High heat flux experiments were conducted in order to analyse the heat transfer and to evaluate the critical heat flux. Water-cooled mock-ups were one-side heated by an electron beam gun for different thermal-hydraulic conditions. The critical heat flux was detected by an original method based on the isotherm modification on the heated surface. The wall heat transfer law including forced convection and subcooled boiling regimes was established. Numerical calculations of the material heat transfer conduction allowed the non-homogeneous distribution of the wall temperature and of the wall heat flux to be evaluated. The critical heat flux value was defined as the wall maximum heat flux. A critical heat flux model based on the liquid sublayer dryout under a vapor blanket was established. A good agreement with test results was found. (author). 198 refs., 126 figs., 21 tabs.

Inverse heat transfer problem in digital temperature control in plate fin and tube heat exchangers

Science.gov (United States)

Taler, Dawid; Sury, Adam

2011-12-01

The aim of the paper is a steady-state inverse heat transfer problem for plate-fin and tube heat exchangers. The objective of the process control is to adjust the number of fan revolutions per minute so that the water temperature at the heat exchanger outlet is equal to a preset value. Two control techniques were developed. The first is based on the presented mathematical model of the heat exchanger while the second is a digital proportional-integral-derivative (PID) control. The first procedure is very stable. The digital PID controller becomes unstable if the water volumetric flow rate changes significantly. The developed techniques were implemented in digital control system of the water exit temperature in a plate fin and tube heat exchanger. The measured exit temperature of the water was very close to the set value of the temperature if the first method was used. The experiments showed that the PID controller works also well but becomes frequently unstable.

Heat transfer from a high temperature condensable mixture

International Nuclear Information System (INIS)

Chan, S.H.; Cho, D.H.; Condiff, D.W.

1978-01-01

A new development in heat transfer is reported. It is concerned with heat transfer from a gaseous mixture that contains a condensable vapor and is at very high temperature. In the past, heat transfer associated with either a condensable mixture at low temperature or a noncondensable mixture at high temperature has been investigated. The former reduces to the classical problem of fog formation in, say, atmosphere where the rate of condensation is diffusion controlled (molecular or conductive diffusions). In the presence of noncondensable gases, heat transfer to a cooler boundary by this mechanism is known to be drastically reduced. In the latter case, where the high temperature mixture is noncondensable, radiative transfer may become dominant and a vast amount of existing literature exists on this class of problem. A fundamentally different type of problem of relevance to recent advances in open cycle MHD power plants and breeder reactor safety is considered. In the advanced coal-fired power plant using MHD as a topping cycle, a condensable mixture is encountered at temperatures of 2000 to 3000 0 . Condensation of the vaporized slag and seed materials at such a high temperature can take place in the MHD generator channel as well as in the radiant boiler. Similarly, in breeder reactor accident analyses involving hypothetical core disruptive accidents, a UO 2 vapor mixture at 400 0 K or higher is often considered. Since the saturation temperature of UO 2 at one atmosphere is close to 4000 0 K, condensation is also likely at a very high temperature. Accordingly, an objective of the present work is to provide an understanding of heat transfer and condensation mechanics insystems containing a high temperature condensable mixture. The results of the study show that, when a high temperature mixture is in contact with a cooler surface, a thermal boundary layer develops rapidly because of intensive radiative cooling from the mixture

Waste Heat Recovery from a High Temperature Diesel Engine

Science.gov (United States)

Adler, Jonas E.

Government-mandated improvements in fuel economy and emissions from internal combustion engines (ICEs) are driving innovation in engine efficiency. Though incremental efficiency gains have been achieved, most combustion engines are still only 30-40% efficient at best, with most of the remaining fuel energy being rejected to the environment as waste heat through engine coolant and exhaust gases. Attempts have been made to harness this waste heat and use it to drive a Rankine cycle and produce additional work to improve efficiency. Research on waste heat recovery (WHR) demonstrates that it is possible to improve overall efficiency by converting wasted heat into usable work, but relative gains in overall efficiency are typically minimal ( 5-8%) and often do not justify the cost and space requirements of a WHR system. The primary limitation of the current state-of-the-art in WHR is the low temperature of the engine coolant ( 90 °C), which minimizes the WHR from a heat source that represents between 20% and 30% of the fuel energy. The current research proposes increasing the engine coolant temperature to improve the utilization of coolant waste heat as one possible path to achieving greater WHR system effectiveness. An experiment was performed to evaluate the effects of running a diesel engine at elevated coolant temperatures and to estimate the efficiency benefits. An energy balance was performed on a modified 3-cylinder diesel engine at six different coolant temperatures (90 °C, 100 °C, 125 °C, 150 °C, 175 °C, and 200 °C) to determine the change in quantity and quality of waste heat as the coolant temperature increased. The waste heat was measured using the flow rates and temperature differences of the coolant, engine oil, and exhaust flow streams into and out of the engine. Custom cooling and engine oil systems were fabricated to provide adequate adjustment to achieve target coolant and oil temperatures and large enough temperature differences across the

Analysis of the Potential of Low-Temperature Heat Pump Energy Sources

Directory of Open Access Journals (Sweden)

Pavel Neuberger

2017-11-01

Full Text Available The paper deals with an analysis of temperatures of ground masses in the proximities of linear and slinky-type HGHE (horizontal ground heat exchanger. It evaluates and compares the potentials of HGHEs and ambient air. The reason and aim of the verification was to gain knowledge of the temperature course of the monitored low-temperature heat pump energy sources during heating periods and periods of stagnation and to analyse the knowledge in terms of the potential to use those sources for heat pumps. The study was conducted in the years 2012–2015 during three heating periods and three periods of HGHEs stagnation. The results revealed that linear HGHE had the highest temperature potential of the observed low-temperature heat pump energy sources. The average daily temperatures of the ground mass surrounding the linear HGHE were the highest ranging from 7.08 °C to 9.20 °C during the heating periods, and having the lowest temperature variation range of 12.62–15.14 K, the relative frequency of the average daily temperatures of the ground mass being the highest at 22.64% in the temperature range containing the mode of all monitored temperatures in a recorded interval of [4.10, 6.00] °C. Ambient air had lower temperature potential than the monitored HGHEs.

Temperature distributions of a conductively heated filament

International Nuclear Information System (INIS)

Tamura, Koji; Ohba, Hironori; Shibata, Takemasa

1999-07-01

Temperature distributions of a heated filament were measured. A W-Re(5%) filament (0.25 mm in diameter, 24.7 mm in length) was conductively heated by currents between 5A and 7A with a DC power supply, and the surface of the filament was imaged with a charge coupled device (CCD) camera through a monochromatic filter. The spectral radiation intensity at the filament center region was almost uniform. Since the temperature distribution was also uniform and the energy loss by thermal conduction was negligible, temperature in this region was determined from the energy balance between applied power and radiation loss. Temperature distribution of the filament was determined based on the Planck's law of radiation from the spectral radiation intensity ratio of the filament surface using obtained temperature as a reference. It was found that temperature distribution of a filament was easily measured by this method. (author)

High temperature superconducting current lead test facility with heat pipe intercepts

International Nuclear Information System (INIS)

Blumenfeld, P.E.; Prenger, C.; Roth, E.W.; Stewart, J.A.

1998-01-01

A high temperature superconducting (HTS) current lead test facility using heat pipe thermal intercepts is under development at the Superconducting Technology Center at Los Alamos National Laboratory. The facility can be configured for tests at currents up to 1,000 A. Mechanical cryocoolers provide refrigeration to the leads. Electrical isolation is maintained by intercepting thermal energy from the leads through cryogenic heat pipes. HST lead warm end temperature is variable from 65 K to over 90 K by controlling heat pipe evaporator temperature. Cold end temperature is variable up to 30 K. Performance predictions in terms of heat pipe evaporator temperature as a function of lead current are presented for the initial facility configuration, which supports testing up to 200 A. Measurements are to include temperature and voltage gradient in the conventional and HTS lead sections, temperature and heat transfer rate in the heat pipes. as well as optimum and off-optimum performance of the conventional lead sections

On the effect of optical and isothermal treatments on luminescence signals from feldspars

International Nuclear Information System (INIS)

Pagonis, Vasilis; Polymeris, George; Kitis, George

2015-01-01

During luminescence dosimetry and luminescence dating applications it is often necessary to precondition the geological samples by applying a thermal or optical treatment before measuring the luminescence signal. In luminescence applications using apatites or feldspars, measurement of continuous-wave infrared or optically stimulated signals (CW-IRSL and CW-OSL) are customarily preceded by either an isothermal heating of the samples at a fixed temperature for a short time interval, or alternatively by optically bleaching the samples using light from LEDs with the appropriate wavelength. This paper presents new analytical equations which can be used to describe these commonly employed double experimental procedures. The equations are based on a recently published model which assumes that tunneling processes are taking place in random distributions of donor–acceptor pairs. The concentration of charge carriers during the CW-IRSL or CW-OSL experiment is expressed in terms of the parameters of the preceding thermal or optical bleaching procedure, and depends also on the distribution of distances between electron and hole pairs. The analytical equations in this paper are compared with experimental data from a feldspar sample which undergoes an isothermal procedure followed by measurement of the CW-IRSL signal. Additional comparisons with experiment are provided using a feldspar sample which undergoes an infrared bleaching process, followed by measurement of the CW-OSL signal. These results and conditions under which the equations can be used are discussed within the framework of the model. - Highlights: • CW-IRSL and CW-OSL measurements are preceded by heating or optical bleaching. • New analytical equations are derived to describe these double experimental procedures. • Equations are compared with data from a feldspar sample following isothermal procedure. • Equations are compared with data from a feldspar sample following optical bleaching.

Analysis of the spatial and temporal accuracy of heating in the prostate gland using transurethral ultrasound therapy and active MR temperature feedback

International Nuclear Information System (INIS)

Chopra, Rajiv; Tang, Kee; Burtnyk, Mathieu; Boyes, Aaron; Bronskill, Michael; Sugar, Linda; Appu, Sree; Klotz, Laurence

2009-01-01

A new MRI-guided therapy is being developed as a minimally invasive treatment for localized prostate cancer utilizing high-intensity ultrasound energy to generate a precise region of thermal coagulation within the prostate gland. The purpose of this study was to evaluate in vivo the capability to produce a spatial heating pattern in the prostate that accurately matched the shape of a target region using transurethral ultrasound heating and active MR temperature feedback. Experiments were performed in a canine model (n = 9) in a 1.5 T MR imager using a prototype device comprising a single planar transducer operated under rotational control. The spatial temperature distribution, measured every 5 s with MR thermometry, was used to adjust the acoustic power and rotation rate in order to achieve a temperature of 55 0 C along the outer boundary of the target region. The results demonstrated the capability to produce accurate spatial heating patterns within the prostate gland. An average temperature of 56.2 ± 0.6 0 C was measured along the outer boundary of the target region across all experiments in this study. The average spatial error between the target boundary and the 55 0 C isotherm was 0.8 ± 0.7 mm (-0.2 to 3.2 mm), and the overall treatment time was ≤20 min for all experiments. Excellent spatial agreement was observed between the temperature information acquired with MRI and the pattern of thermal damage measured on H and E-stained tissue sections. This study demonstrates the benefit of adaptive energy delivery using active MR temperature feedback, and an excellent capability to treat precise regions within the prostate gland with this technology.

Non-Isothermal Gas-Based Direct Reduction Behavior of High Chromium Vanadium-Titanium Magnetite Pellets and the Melting Separation of Metallized Pellets

Directory of Open Access Journals (Sweden)

Jue Tang

2017-04-01

Full Text Available The non-isothermal reduction behavior of high chromium vanadium-titanium magnetite (HCVTM pellets by gas mixtures was investigated using different heating rates (4, 8, and 12 K/min and varied gas compositions (H2/CO = 2/5, H2/CO = 1/1, and H2/CO = 5/2 volume ratios; the pellets were then used for melting separation. It was observed that the temperature corresponding to the maximum reduction ratio increased with the increasing heating rate. The HCVTM pellets reached the same final reduction ratio under a given reducing gas composition, although the heating rates were different. Under the same heating rate, the gas mixture with more H2 was conducive for obtaining a higher reduction ratio. The phase transformations during the non-isothermal reduction were ordered as follows: Fe2O3 → Fe3O4 → FeO → Fe; Fe9TiO15 + Fe2Ti3O9 → Fe2.75Ti0.25O4 → FeTiO3 → TiO2; V1.7Cr0.3O3 → V2O3 → Fe2VO4; Fe1.2Cr0.8O3 → Cr2O3 → FeCr2O4. The non-isothermal reduction kinetic model was established based on the unreacted core model with multiple reaction interfaces. The correlation coefficients were greater than 0.99, revealing that this kinetic model could properly describe the non-isothermal reduction of the HCVTM pellets by gas mixtures. Iron containing V and Cr along with the Ti-rich slag was obtained through the melting separation of the metallized HCVTM pellets. The mass fractions and recovery rates of Fe, V, and Cr in the iron were 93.87% and 99.45%, 0.91% and 98.83%, and 0.72% and 95.02%, respectively. The mass fraction and recovery rate of TiO2 in the slag were 38.12% and 95.08%, respectively.

Heating and Domestic Hot Water Systems in Buildings Supplied by Low-Temperature District Heating

DEFF Research Database (Denmark)

Brand, Marek

solutions simply redirect the bypassed water back to the DH network without additional cooling, but bypassed water can instead be redirected to floor heating in the bathroom to be further cooled and thus reduce heat loss from the DH network while improving comfort for occupants and still ensure fast DHW...... increased risk of Legionella if the DH substation and DHW system are designed for the low-temperature supply conditions. To ensure the fast provision of DHW during non-heating periods, the supply service pipe should be kept warm, preferably with the bypass solution redirecting the bypass flow to bathroom...... temperature. To accord with the literature, the modelling of internal heat gains reflected the improved efficiency of equipment by reduction of value from 5W/m2 to 4.2W/m2, also modelled as intermittent heat gains based on a realistic week schedule. Furthermore, the indoor set-point temperature was increased...

Cyclic and isothermal oxidation behavior of 2.25Cr-1Mo steel

International Nuclear Information System (INIS)

Proy, M.; Utrilla, M. v.; Otero, E.

2014-01-01

Cyclic and isothermal oxidation of chromium-molybdenum steel 2.25Cr-1Mo were analyzed at 550 degree centigrade and 650 degree centigrade during 360 hours in air atmospheres. The cycles were performed with two stages; one of heating in furnace during 90 minutes and then the sample were cooled to 50 degree centigrade by air flow. Thermogravimetric analyses were performed to obtain high temperature corrosion kinetics. Several characterization techniques have been used to identify the corrosion mechanism, as X-Ray Diffraction (XRD), Optical Microscopy (OM) and Scanning Electron Microscopy (SEM). Thermal cycling tests can changes the corrosion mechanism, due cracks propagation in oxide scale, that witch can favors the access of oxidant agent to the substrate. (Author)

Exergy and Energy Analysis of Low Temperature District Heating Network

DEFF Research Database (Denmark)

Li, Hongwei; Svendsen, Svend

is in line with a pilot project that is carrying out in Denmark with network supply/return temperature at 55oC/25 oC. The consumer domestic hot water (DHW) demand is supplied with a special designed district heating (DH) storage tank. The space heating (SH) demand is supplied with a low temperature radiator......Low temperature district heating (LTDH) with reduced network supply and return temperature provides better match of the low quality building thermal demand and the low quality waste heat supply. In this paper, an exemplary LTDH network was designed for 30 low energy demand residential houses, which....... The network thermal and hydraulic conditions were simulated under steady state with an in-house district heating network design and simulation code. Through simulation, the overall system energetic and exergetic efficiencies were calculated and the exergy losses for the major district heating system...

Research on suitable heating conditions during local PWHT. Pt. 1. Influence of heating conditions on temperature distribution

International Nuclear Information System (INIS)

Tanaka, Jinkichi; Horii, Yukihiko; Sato, Masanobu; Murakawa, Hidekazu; Wang Jianhua

1999-01-01

To improve weld joint properties a heat treatment so called post weld heat treatment (PWHT) is often implemented for steel weldment. Generally, the PWHT is conducted in a furnace at a factory. But in site welds such as the girth joint of pipe, a local PWHT is applied using electric heater and so on. In the local PWHT steep temperature gradient occurs depending on the heating condition and it leads to rise of the thermal stress in addition to the welding residual stress. However, heating condition is not always defined the same in some standards. Therefore, suitable heat conditions for the local PWHT were studied supposing the power plant and so on experimentally and theoretically. Temperature distribution and thermal strains under different heating conditions were measured during the local PWHT using carbon steel pipes of 340 mm in diameter and 53 mm in wall thickness. The temperature gradient, thermal strain were also analyzed using Finite Element Method (FEM) as axis-symmetric model. Further, the influences of pipe size and heat transfer coefficient on the temperature distribution were analyzed and suitable heating source widths for various pipe sizes were proposed from the viewpoint of temperature distribution. (orig.)

Loop Heat Pipe Temperature Oscillation Induced by Gravity Assist and Reservoir Heating

Science.gov (United States)

Ku, Jentung; Garrison, Matt; Patel, Deepak; Robinson, Frank; Ottenstein, Laura

2015-01-01

The Laser Thermal Control System (LCTS) for the Advanced Topographic Laser Altimeter System (ATLAS) to be installed on NASA's Ice, Cloud, and Land Elevation Satellite (ICESat-2) consists of a constant conductance heat pipe and a loop heat pipe (LHP) with an associated radiator. During the recent thermal vacuum testing of the LTCS where the LHP condenser/radiator was placed in a vertical position above the evaporator and reservoir, it was found that the LHP reservoir control heater power requirement was much higher than the analytical model had predicted. Even with the control heater turned on continuously at its full power, the reservoir could not be maintained at its desired set point temperature. An investigation of the LHP behaviors found that the root cause of the problem was fluid flow and reservoir temperature oscillations, which led to persistent alternate forward and reversed flow along the liquid line and an imbalance between the vapor mass flow rate in the vapor line and liquid mass flow rate in the liquid line. The flow and temperature oscillations were caused by an interaction between gravity and reservoir heating, and were exacerbated by the large thermal mass of the instrument simulator which modulated the net heat load to the evaporator, and the vertical radiator/condenser which induced a variable gravitational pressure head. Furthermore, causes and effects of the contributing factors to flow and temperature oscillations intermingled.

Increase of COP for heat transformer in water purification systems. Part I - Increasing heat source temperature

International Nuclear Information System (INIS)

Siqueiros, J.; Romero, R.J.

2007-01-01

The integration of a water purification system in a heat transformer allows a fraction of heat obtained by the heat transformer to be recycled, increasing the heat source temperature. Consequently, the evaporator and generator temperatures are also increased. For any operating conditions, keeping the condenser and absorber temperatures and also the heat load to the evaporator and generator, a higher value of COP is obtained when only the evaporator and generator temperatures are increased. Simulation with proven software compares the performance of the modeling of an absorption heat transformer for water purification (AHTWP) operating with water/lithium bromide, as the working fluid-absorbent pair. Plots of enthalpy-based coefficients of performance (COP ET ) and the increase in the coefficient of performance (COP) are shown against absorber temperature for several thermodynamic operating conditions. The results showed that proposed (AHTWP) system is capable of increasing the original value of COP ET more than 120%, by recycling part of the energy from a water purification system. The proposed system allows to increase COP values from any experimental data for water purification or any other distillation system integrated to a heat transformer, regardless of the actual COP value and any working fluid-absorbent pair

Surface temperature and surface heat flux determination of the inverse heat conduction problem for a slab

International Nuclear Information System (INIS)

Kuroyanagi, Toshiyuki

1983-07-01

Based on an idea that surface conditions should be a reflection of interior temperature and interior heat flux variation as inverse as interior conditions has been determined completely by the surface temperature and/on surface heat flux as boundary conditions, a method is presented for determining the surface temperature and the surface heat flux of a solid when the temperature and heat flux at an interior point are a prescribed function of time. The method is developed by the integration of Duhumels' integral which has unknown temperature or unknown heat flux in its integrand. Specific forms of surface condition determination are developed for a sample inverse problem: slab. Ducussing the effect of a degree of avairable informations at an interior point due to damped system and the effect of variation of surface conditions on those formulations, it is shown that those formulations are capable of representing the unknown surface conditions except for small time interval followed by discontinuous change of surface conditions. The small un-resolved time interval is demonstrated by a numerical example. An evaluation method of heat flux at an interior point, which is requested by those formulations, is discussed. (author)

Mixed convection heat transfer simulation in a rectangular channel with a variable speed rotational cylinder

Science.gov (United States)

Khan, Md Imran; Billah, Md. Mamun; Rahman, Mohammed Mizanur; Hasan, Mohammad Nasim

2017-12-01

Numerical simulation of steady two-dimensional heat transfer in a rectangular channel with a centered variable speed cylinder has been performed in this paper. In this setup, an isoflux heater is placed at the bottom wall of the channel while the upper wall is kept isothermal with a low temperature. The cylinder's peripheral speed to maximum inlet fluid velocity ratio (ξ) is varied from 0.5 to 1.5 for both clockwise and anticlockwise rotational cases. Air has been considered as working fluid while other system parameters such as Grashof and Reynolds numbers are varied. The effects of rotational speed, Grashof and Reynolds numbers on the streamline pattern, isothermal lines, local and average Nusselt number are analyzed and presented. It is observed the cylinder's rotational direction and speed has a significant effect on the flow pattern, temperature distribution as well as heat transfer characteristics.

Flow and Heat Transfer in Cooling Microchannels with Phase-Change

Energy Technology Data Exchange (ETDEWEB)

Peles, Y P; Yarin, L P; Hetsroni, G [Technion, Israel Institute of Technology, Haifa (Israel) Faculty of Engineering

1998-05-19

The subject of the present work is the parametrical investigation of hydrodynamic and thermal characteristics of laminar flow with phase-change in a heating microchannels. The study is based on the quasi-one-dimensional model of non-isothermal capillary flow. This model takes into account the evolution of flow, heating and evaporation of the liquid, as well as the influence of capillary, inertia, friction and gravity forces. The effect of various parameters (sizes of microchannel, initial temperature of cooling liquid, wall heat flux etc.) on hydrodynamic and thermal structures of the flow, the length of heating, evaporation and superheat regions is studied. Thc specific features of the phenomena is discussed.

Flow and Heat Transfer in Cooling Microchannels with Phase-Change

International Nuclear Information System (INIS)

Peles, Y.P.; Yarin, L.P.; Hetsroni, G.

1998-01-01

The subject of the present work is the parametrical investigation of hydrodynamic and thermal characteristics of laminar flow with phase-change in a heating microchannels. The study is based on the quasi-one-dimensional model of non-isothermal capillary flow. This model takes into account the evolution of flow, heating and evaporation of the liquid, as well as the influence of capillary, inertia, friction and gravity forces. The effect of various parameters (sizes of microchannel, initial temperature of cooling liquid, wall heat flux etc.) on hydrodynamic and thermal structures of the flow, the length of heating, evaporation and superheat regions is studied. Thc specific features of the phenomena is discussed

Characterization of bainitic/martensitic structures formed in isothermal treatments below the M

NARCIS (Netherlands)

Navarro Lopez, A.; Hidalgo Garcia, J.; Sietsma, J.; Santofimia Navarro, M.J.

2017-01-01

Advanced Multiphase High Strength Steels are generally obtained by applying isothermal treatments around the martensite start temperature (M_s). Previous investigations have shown that bainitic ferrite can form from austenite in isothermal treatments below M_s, where its

Isothermal annealing of silicon implanted with 50 keV 10B ions

International Nuclear Information System (INIS)

Weidner, B.; Zaschke, G.

1974-01-01

Isothermal annealing characteristics of silicon implanted with boron were measured and compared with calculated results. Implantation was performed with 50 keV 10 B ions in the dose range of 7.5 x 10 12 cm -2 to 2.0 x 10 15 cm -2 . Annealing temperatures ranged from 700 to 900 0 C. Maximum annealing time was 10 4 minutes. Annealing time strongly increases with increasing dose and decreasing temperature. Assuming that there is only one activation energy the isothermal annealing curves of constant dose and different temperatures were combined to a reduced annealing curve and the reduced isothermal annealing curve calculated. Starting from first order kinetics, considering the doping profile of boron in silicon and assuming a depth-dependent decay constant the experimentally determined annealing curves could be easily described over the total dose and time range

Entropy Generation Analysis of Natural Convection in Square Enclosures with Two Isoflux Heat Sources

Directory of Open Access Journals (Sweden)

S. Z. Nejad

2017-04-01

Full Text Available This study investigates entropy generation resulting from natural convective heat transfer in square enclosures with local heating of the bottom and symmetrical cooling of the sidewalls. This analysis tends to optimize heat transfer of two pieces of semiconductor in a square electronic package. In this simulation, heaters are modeled as isoflux heat sources and sidewalls of the enclosure are isothermal heat sinks. The top wall and the non-heated portions of the bottom wall are adiabatic. Flow and temperature fields are obtained by numerical simulation of conservation equations of mass, momentum and energy in laminar, steady and two dimensional flows. With constant heat energy into the cavity, effect of Rayleigh number, heater length, heater strength ratios and heater position is evaluated on flow and temperature fields and local entropy generation. The results show that a minimum entropy generation rate is obtained under the same condition in which a minimum peak heater temperature is obtained.

Heat transfer and critical heat flux in a spiral flow in an asymmetrical heated tube; Transfert thermique et flux critique dans un ecoulement helicoidal en tube chauffe asymetriquement

Energy Technology Data Exchange (ETDEWEB)

Boscary, J [CEA Centre d` Etudes de Cadarache, 13 - Saint-Paul-lez-Durance (France). Direction des Sciences de la Matiere; [Association Euratom-CEA, Centre d` Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France). Dept. de Recherches sur la Fusion Controlee

1997-03-01

The design of plasma facing components is crucial for plasma performance in next fusion reactors. These elements will be submitted to very high heat flux. They will be actively water-cooled by swirl tubes in the subcooled boiling regime. High heat flux experiments were conducted in order to analyse the heat transfer and to evaluate the critical heat flux. Water-cooled mock-ups were one-side heated by an electron beam gun for different thermal-hydraulic conditions. The critical heat flux was detected by an original method based on the isotherm modification on the heated surface. The wall heat transfer law including forced convection and subcooled boiling regimes was established. Numerical calculations of the material heat transfer conduction allowed the non-homogeneous distribution of the wall temperature and of the wall heat flux to be evaluated. The critical heat flux value was defined as the wall maximum heat flux. A critical heat flux model based on the liquid sublayer dryout under a vapor blanket was established. A good agreement with test results was found. (author) 197 refs.

Advanced industrial ceramic heat pipe recuperators

Energy Technology Data Exchange (ETDEWEB)

Strumpf, H.J.; Stillwagon, T.L.; Kotchick, D.M.; Coombs, M.G.

1988-01-01

This paper summarizes the results of an investigation involving the use of ceramic heat pipe recuperators for high-temperature heat recovery from industrial furnaces. The function of the recuperator is to preheat combustion air with furnace exhaust gas. The heat pipe recuperator comprises a bundle of individual ceramic heat pipes acting in concert, with a partition separating the air and exhaust gas flow streams. Because each heat pipe is essentially an independent heat exchanger, the failure of a single tube does not compromise recuperator integrity, has only a minimal effect on overall heat exchanger performance and enables easier replacement of individual heat pipes. In addition, the heat pipe acts as an essentially isothermal heat transfer device, leading to a high thermodynamic efficiency. Cost estimates developed for heat pipe recuperator systems indicate favorable payback periods. Laboratory studies have demonstrated the feasibility of fabricating the required ceramic tubes, coating the inside of the tubes with CVD tungsten, and sealing the heat pipe with an electron-beam-welded or vacuum-brazed end cap.

Measurement of a surface heat flux and temperature

Science.gov (United States)

Davis, R. M.; Antoine, G. J.; Diller, T. E.; Wicks, A. L.

1994-04-01

The Heat Flux Microsensor is a new sensor which was recently patented by Virginia Tech and is just starting to be marketed by Vatell Corp. The sensor is made using the thin-film microfabrication techniques directly on the material that is to be measured. It consists of several thin-film layers forming a differential thermopile across a thermal resistance layer. The measured heat flux q is proportional to the temperature difference across the resistance layer q= k(sub g)/delta(sub g) x (t(sub 1) - T(sub 2)), where k(sub g) is the thermal conductivity and delta (sub g) is the thickness of the thermal resistance layer. Because the gages are sputter coated directly onto the surface, their total thickness is less than 2 micrometers, which is two orders of magnitude thinner than previous gages. The resulting temperature difference across the thermal resistance layer (delta is less than 1 micrometer) is very small even at high heat fluxes. To generate a measurable signal many thermocouple pairs are put in series to form a differential thermopile. The combination of series thermocouple junctions and thin-film design creates a gage with very attractive characteristics. It is not only physically non-intrusive to the flow, but also causes minimal disruption of the surface temperature. Because it is so thin, the response time is less than 20 microsec. Consequently, the frequency response is flat from 0 to over 50 kHz. Moreover, the signal of the Heat Flux Microsensor is directly proportional to the heat flux. Therefore, it can easily be used in both steady and transient flows, and it measures both the steady and unsteady components of the surface heat flux. A version of the Heat Flux Microsensor has been developed to meet the harsh demands of combustion environments. These gages use platinum and platinum-10 percent rhodium as the thermoelectric materials. The thermal resistance layer is silicon monoxide and a protective coating of Al2O3 is deposited on top of the sensor. The

Industrial waste heat utilization for low temperature district heating

International Nuclear Information System (INIS)

Fang, Hao; Xia, Jianjun; Zhu, Kan; Su, Yingbo; Jiang, Yi

2013-01-01

Large quantities of low grade waste heat are discharged into the environment, mostly via water evaporation, during industrial processes. Putting this industrial waste heat to productive use can reduce fossil fuel usage as well as CO 2 emissions and water dissipation. The purpose of this paper is to propose a holistic approach to the integrated and efficient utilization of low-grade industrial waste heat. Recovering industrial waste heat for use in district heating (DH) can increase the efficiency of the industrial sector and the DH system, in a cost-efficient way defined by the index of investment vs. carbon reduction (ICR). Furthermore, low temperature DH network greatly benefits the recovery rate of industrial waste heat. Based on data analysis and in-situ investigations, this paper discusses the potential for the implementation of such an approach in northern China, where conventional heat sources for DH are insufficient. The universal design approach to industrial-waste-heat based DH is proposed. Through a demonstration project, this approach is introduced in detail. This study finds three advantages to this approach: (1) improvement of the thermal energy efficiency of industrial factories; (2) more cost-efficient than the traditional heating mode; and (3) CO 2 and pollutant emission reduction as well as water conservation. -- Highlights: •We review situation of industrial waste heat recovery with a global perspective. •We present a way to analyze the potential to utilize industrial waste heat for DH. •Northern China has huge potential for using low-grade industrial waste heat for DH. •A demonstration project is introduced using the universal approach we propose. •It proves huge benefits for factories, heat-supply companies and the society

Decentralized substations for low-temperature district heating with no Legionella risk, and low return temperatures

DEFF Research Database (Denmark)

Yang, Xiaochen; Li, Hongwei; Svendsen, Svend

2016-01-01

. From the results, realizing LTDH by the decentralized substation unit, 30% of the annual distribution heat loss inside the building can be saved compared to a conventional system with medium-temperature district heating. Replacing the bypass pipe with an in-line supply pipe and a heat pump...... with domestic hot water (DHW) circulation. In this study, a system with decentralized substations was analysed as a solution to this problem. Furthermore, a modification for the decentralized substation system were proposed in order to reduce the average return temperature. Models of conventional system...... with medium-temperature district heating, decentralized substation system with LTDH, and innovative decentralized substation system with LTDH were built based on the information of a case building. The annual distribution heat loss and the operating costs of the three scenarios were calculated and compared...

Development of multilayer perceptron networks for isothermal time temperature transformation prediction of U-Mo-X alloys

Energy Technology Data Exchange (ETDEWEB)

Johns, Jesse M., E-mail: jesse.johns@pnnl.gov; Burkes, Douglas, E-mail: douglas.burkes@pnnl.gov

2017-07-15

In this work, a multilayered perceptron (MLP) network is used to develop predictive isothermal time-temperature-transformation (TTT) models covering a range of U-Mo binary and ternary alloys. The selected ternary alloys for model development are U-Mo-Ru, U-Mo-Nb, U-Mo-Zr, U-Mo-Cr, and U-Mo-Re. These model's ability to predict 'novel' U-Mo alloys is shown quite well despite the discrepancies between literature sources for similar alloys which likely arise from different thermal-mechanical processing conditions. These models are developed with the primary purpose of informing experimental decisions. Additional experimental insight is necessary in order to reduce the number of experiments required to isolate ideal alloys. These models allow test planners to evaluate areas of experimental interest; once initial tests are conducted, the model can be updated and further improve follow-on testing decisions. The model also improves analysis capabilities by reducing the number of data points necessary from any particular test. For example, if one or two isotherms are measured during a test, the model can construct the rest of the TTT curve over a wide range of temperature and time. This modeling capability reduces the cost of experiments while also improving the value of the results from the tests. The reduced costs could result in improved material characterization and therefore improved fundamental understanding of TTT dynamics. As additional understanding of phenomena driving TTTs is acquired, this type of MLP model can be used to populate unknowns (such as material impurity and other thermal mechanical properties) from past literature sources.

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds

Energy Technology Data Exchange (ETDEWEB)

Ramos-Ramirez, Esthela, E-mail: ramosre@quijote.ugto.mx [Centro de Investigaciones en Quimica Inorganica de la Universidad de Guanajuato, Noria Alta s/n, Col. Noria Alta, C.P. 36050, Guanajuato, Gto. (Mexico); Gutierrez Ortega, Norma L.; Conteras Soto, Cesar A. [Centro de Investigaciones en Quimica Inorganica de la Universidad de Guanajuato, Noria Alta s/n, Col. Noria Alta, C.P. 36050, Guanajuato, Gto. (Mexico); Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, km 36.5, La Marquesa, Coyoacan Mexico, C.P. 52750 (Mexico); Olguin Gutierrez, Maria T. [Instituto Nacional de Investigaciones Nucleares, Carretera Mexico-Toluca s/n, km 36.5, La Marquesa, Coyoacan Mexico, C.P. 52750 (Mexico)

2009-12-30

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio = 2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N{sub 2} adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds

International Nuclear Information System (INIS)

Ramos-Ramirez, Esthela; Gutierrez Ortega, Norma L.; Conteras Soto, Cesar A.; Olguin Gutierrez, Maria T.

2009-01-01

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio = 2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N 2 adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Adsorption isotherm studies of chromium (VI) from aqueous solutions using sol-gel hydrotalcite-like compounds.

Science.gov (United States)

Ramos-Ramírez, Esthela; Ortega, Norma L Gutiérrez; Soto, Cesar A Contreras; Gutiérrez, Maria T Olguín

2009-12-30

In under-developed countries, industries such as paint and pigment manufacturing, leather tanning, chrome plating and textile processing, usually discharge effluents containing Cr(VI) and Cr(III) into municipal sanitary sewers. It has been reported that Cr(VI) acts as a powerful epithelial irritant and as a human carcinogen. In the present work, hydrotalcite-like compounds with a Mg/Al ratio=2 were synthesized by the sol-gel method. The hydrotalcite-like compounds and their corresponding thermally treated products were characterized by powder X-ray diffraction, infrared spectroscopy and N(2) adsorption. The hydrotalcite-like compounds and the heated solids were used as adsorbents for Cr(VI) in aqueous solutions. Adsorption isotherm studies of Cr(VI) from aqueous solution are described. The adsorbent capacity was determined using the Langmuir, Freundlich and Dubinin-Radushkevich adsorption isotherm models. The Cr(VI) adsorption isotherm data fit best to the Langmuir isotherm model. The maximum Cr(VI) uptake by hydrotalcite and the heated solids was determined using the Langmuir equation and was found to range between 26 and 29 mg Cr(VI)/g adsorbent.

Calculation of Vertical Temperature Gradients in Heated Rooms

DEFF Research Database (Denmark)

Overby, H.; Steen-Thøde, Mogens

This paper deals with a simple model which predicts the vertical temperature gradient in a heated room. The gradient is calculated from a dimensionless temperature profile which is determined by two room air temperatures only, the mean temperature in the occupied zone and the mean temperature...

The ADAM and EVE project: Heat transfer at ambient temperature

International Nuclear Information System (INIS)

Boltendahl, U.; Harth, R.

1980-01-01

In the nuclear research plant at Juelich a new heating system is at present being developed as part of the Nuclear Long-distance Heating Project. Helium is heated up in a high-temperature reactor. The heat chemically converts a gas mixture in a reformer plant (EVE). The gases 'charged' with energy can be transported through tubes over any distance required at ambient temperatures. In a methanisation plant (ADAM) the gases react with one another, releasing the energy in the form of heat which can be used for heating air or water. (orig.) [de

Urban heat islands in the subsurface of German cities

Science.gov (United States)

Menberg, K.; Blum, P.; Zhu, K.; Bayer, P.

2012-04-01

In the subsurface of many cities there are widespread and persistent thermal anomalies (subsurface urban heat islands) that result in a warming of urban aquifers. The reasons for this heating are manifold. Possible heat sources are basements of buildings, leakage of sewage systems, buried district heating networks, re-injection of cooling water and solar irradiation on paved surfaces. In the current study, the reported groundwater temperatures in several German cities, such as Berlin, Munich, Cologne and Karlsruhe, are compared. Available data sets are supplemented by temperature measurements and depth profiles in observation wells. Trend analyses are conducted with time series of groundwater temperatures, and three-dimensional groundwater temperature maps are provided. In all investigated cities, pronounced positive temperature anomalies are present. The distribution of groundwater temperatures appears to be spatially and temporally highly variable. Apparently, the increased heat input into the urban subsurface is controlled by very local and site-specific parameters. In the long-run, the superposition of various heat sources results in an extensive temperature increase. In many cases, the maximum temperature elevation is found close to the city centre. Regional groundwater temperature differences between the city centre and the rural background are up to 5 °C, with local hot spots of even more pronounced anomalies. Particular heat sources, like cooling water injections or case-specific underground constructions, can cause local temperatures > 20°C in the subsurface. Examination of the long-term variations in isotherm maps shows that temperatures have increased by about 1°C in the city, as well as in the rural background areas over the last decades. This increase could be reproduced with trend analysis of temperature data gathered from several groundwater wells. Comparison between groundwater and air temperatures in Karlsruhe, for example, also indicates a

Basic thermo-fluid dynamic problems in high temperature heat exchangers

International Nuclear Information System (INIS)

McEligot, D.M.

1986-01-01

The authors consider high temperature heat exchangers to be ones where the heat transfer coefficients cannot be predicted confidently by classical analyses for pure forced convection with constant fluid properties. Alternatively, one could consider heat exchangers operating above some arbitrary temperature, say 1000F or 600C perhaps, to be at high temperature conditions. In that case, most common working fluids will be superheated vapors or gases. While some liquid metal heat exchangers are designed to operate in this range, the heat transfer coefficients of liquid metals are usually sufficiently high that the dominant thermal resistance would be due to the second fluid. This paper concentrates on convective heat transfer with gases. Typical applications include modular gas cooled nuclear reactors, proposed nuclear propulsion systems and space power plants, and superheaters in Rankine steam cycles

A two-phase flow and non-isothermal agglomerate model for a proton exchange membrane (PEM) fuel cell

International Nuclear Information System (INIS)

Xing, Lei; Liu, Xiaoteng; Alaje, Taiwo; Kumar, Ravi; Mamlouk, Mohamed; Scott, Keith

2014-01-01

A two dimensional, across the channel, steady-state model for a proton exchange membrane fuel cell (PEMFC) is presented in which the non-isothermal model for temperature distribution, the two-phase flow model for liquid water transport and the agglomerate model for oxygen reduction reaction are fully coupled. This model is used to investigate thermal transport within the membrane electrode assembly (MEA) associated with the combinational water phase-transfer and transport mechanisms. Effective temperature distribution strategies are established aim to enhance the cell performance. Agglomerate assumption is adopted in which the ionomer and liquid water in turn cover the agglomerate to form the ionomer and liquid water films. Ionomer swelling is associated with the non-uniform distribution of the water content. The modelling results show that heat accumulates within the cathode catalyst layer under the channel. Higher operating temperature improves the cell performance by increasing the kinetics, reducing the liquid water saturation on the cathode and increasing the water carrying capacity of the anode gas. Applying higher temperature on the anode and enlarging the width ratio of the channel/rib could improve the cell performance. Higher cathode temperature decreases the oxygen mole fraction, resulting in an insufficient oxygen supply and a limitation of the cell performance. - Highlights: • The two-phase flow and non-isothermal model couple with the agglomerate model. • Oxygen diffusivity and solubility in Nafion ® relate to water content and temperature. • Higher anode operating temperature improves the fuel cell performance. • Insufficient oxygen supply limits cell performance at higher current densities

Isothermal and dynamic oxidation behaviour of Mo-W doped carbon-based coating

Science.gov (United States)

Mandal, Paranjayee; Ehiasarian, Arutiun P.; Hovsepian, Papken Eh.

2015-10-01

The oxidation behaviour of Mo-W doped carbon-based coating (Mo-W-C) is investigated in elevated temperature (400-1000 °C). Strong metallurgical bond between Mo-W-C coating and substrate prevents any sort of delamination during heat-treatment. Isothermal oxidation tests show initial growth of metal oxides at 500 °C, however graphitic nature of the as-deposited coating is preserved. The oxidation progresses with further rise in temperature and the substrate is eventually exposed at 700 °C. The performance of Mo-W-C coating is compared with a state-of-the-art DLC(Cr/Cr-WC/W:C-H/a:C-H) coating, which shows preliminary oxidation at 400 °C and local delamination of the coating at 500 °C leading to substrate exposure. The graphitisation starts at 400 °C and the diamond-like structure is completely converted into the graphite-like structure at 500 °C. Dynamic oxidation behaviour of both the coatings is investigated using Thermo-gravimetric analysis carried out with a slow heating rate of 1 °C/min from ambient temperature to 1000 °C. Mo-W-C coating resists oxidation up to ˜800 °C whereas delamination of DLC(Cr/Cr-WC/W:C-H/a:C-H) coating is observed beyond ˜380 °C. In summary, Mo-W-C coating provides improved oxidation resistance at elevated temperature compared to DLC(Cr/Cr-WC/W:C-H/a:C-H) coating.

Heat Transfer and Cooling Techniques at Low Temperature

CERN Document Server

Baudouy, B

2014-07-17

The first part of this chapter gives an introduction to heat transfer and cooling techniques at low temperature. We review the fundamental laws of heat transfer (conduction, convection and radiation) and give useful data specific to cryogenic conditions (thermal contact resistance, total emissivity of materials and heat transfer correlation in forced or boiling flow for example) used in the design of cooling systems. In the second part, we review the main cooling techniques at low temperature, with or without cryogen, from the simplest ones (bath cooling) to the ones involving the use of cryocoolers without forgetting the cooling flow techniques.

Heat Transfer and Cooling Techniques at Low Temperature

Energy Technology Data Exchange (ETDEWEB)

Baudouy, B [Saclay (France)

2014-07-01

The first part of this chapter gives an introduction to heat transfer and cooling techniques at low temperature. We review the fundamental laws of heat transfer (conduction, convection and radiation) and give useful data specific to cryogenic conditions (thermal contact resistance, total emissivity of materials and heat transfer correlation in forced or boiling flow for example) used in the design of cooling systems. In the second part, we review the main cooling techniques at low temperature, with or without cryogen, from the simplest ones (bath cooling) to the ones involving the use of cryocoolers without forgetting the cooling flow techniques.