WorldWideScience

Sample records for temperature fossil fuel

  1. Fossil Fuels.

    Science.gov (United States)

    Crank, Ron

    This instructional unit is one of 10 developed by students on various energy-related areas that deals specifically with fossil fuels. Some topics covered are historic facts, development of fuels, history of oil production, current and future trends of the oil industry, refining fossil fuels, and environmental problems. Material in each unit may…

  2. New Optimal Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    Energy Technology Data Exchange (ETDEWEB)

    John Coggin; Jonas Ivasauskas; Russell G. May; Michael B. Miller; Rena Wilson

    2006-09-30

    Accomplishments during Phase II of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring. During this program work period, major progress has been experienced in the development of the sensor hardware, and the planning of the system installation and operation. The major focus of the next work period will be the installation of sensors in the Hamilton, Ohio power plant, and demonstration of high-temperature strain gages during mechanical testing of SOFC components.

  3. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Application

    Energy Technology Data Exchange (ETDEWEB)

    John Coggin; Tom Flynn; Jonas Ivasauskas; Daniel Kominsky; Carrie Kozikowski; Russell May; Michael Miller; Tony Peng; Gary Pickrell; Raymond Rumpf; Kelly Stinson-Bagby; Dan Thorsen; Rena Wilson

    2007-12-31

    Accomplishments of a program to develop and demonstrate photonic sensor technology for the instrumentation of advanced powerplants and solid oxide fuel cells are described. The goal of this project is the research and development of advanced, robust photonic sensors based on improved sapphire optical waveguides, and the identification and demonstration of applications of the new sensors in advanced fossil fuel power plants, where the new technology will contribute to improvements in process control and monitoring.

  4. Fossil fuels -- future fuels

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1998-03-01

    Fossil fuels -- coal, oil, and natural gas -- built America`s historic economic strength. Today, coal supplies more than 55% of the electricity, oil more than 97% of the transportation needs, and natural gas 24% of the primary energy used in the US. Even taking into account increased use of renewable fuels and vastly improved powerplant efficiencies, 90% of national energy needs will still be met by fossil fuels in 2020. If advanced technologies that boost efficiency and environmental performance can be successfully developed and deployed, the US can continue to depend upon its rich resources of fossil fuels.

  5. Potential high temperature corrosion problems due to co-firing of biomass and fossil fuels

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Vilhelmsen, T.; Jensen, S.A.

    2008-01-01

    Over the past few years, considerable high temperature corrosion problems have been encountered when firing biomass in power plants due to the high content of potassium chloride in the deposits. Therefore, to combat chloride corrosion problems cofiring of biomass with a fossil fuel has been....... However, the most significant corrosion attack was sulphidation attack at the grain boundaries of 18-8 steel after 3 years exposure. The corrosion mechanisms and corrosion rates are compared with biomass firing and coal firing. Potential corrosion problems due to co-firing biomass and fossil fuels...

  6. Potential high temperature corrosion problems due to co-firing of biomass and fossil fuels

    DEFF Research Database (Denmark)

    Montgomery, Melanie; Vilhelmsen, T.; Jensen, S.A.

    2007-01-01

    Over the past years, considerable high temperature corrosion problems have been encountered when firing biomass in power plants due to the high content of potassium chloride in the deposits. Therefore to combat chloride corrosion problems co-firing of biomass with a fossil fuel has been undertaken...... significant corrosion attack was due to sulphidation attack at the grain boundaries of 18-8 steel after 3 years exposure. The corrosion mechanisms and corrosion rates are compared with biomass firing and coal firing. Potential corrosion problems due to co-firing biomass and fossil fuels are discussed....

  7. New Optical Sensor Suite for Ultrahigh Temperature Fossil Fuel Applications

    Energy Technology Data Exchange (ETDEWEB)

    Russell G. May; Tony Peng; Gary Pickrell

    2005-10-31

    Development of practical, high-temperature optical claddings for improved waveguiding in sapphire fibers continued during the reporting period. A set of designed experiments using the Taguchi method was undertaken to efficiently determine the optimal set of processing variables to yield clad fibers with good optical and mechanical properties. Eighteen samples of sapphire fibers were prepared with spinel claddings, each with a unique set of variables. Statistical analyses of the results were then used to predict the set of factors that would result in a spinel cladding with the optimal geometrical, mechanical, and optical properties. To confirm the predictions of the Taguchi analysis, sapphire fibers were clad with the magnesium aluminate spinel coating using the predicted optimal set of factors. In general, the clad fibers demonstrated high quality, exceeding the best results obtained during the Phase I effort. Tests of the high-temperature stability of the clad fibers were also conducted. The results indicated that the clad fibers were stable at temperatures up to 1300 C for the duration of the three day test. At the higher temperatures, some changes in the geometry of the fibers were observed. The design, fabrication, and testing of a sapphire sensor for measurement of temperature was undertaken. The specific sensor configuration uses a polished sapphire wafer as the temperature-sensitive element. The wafer is attached to a sapphire fiber (clad or unclad), and interrogated as a Fabry-Perot sensor. Methods for assembling the sensor were investigated. A prototype sensor was fabricated and tested at room temperature and elevated temperatures. Results were difficult to interpret, due to the presence of modal noise which was found to result from the use of a spectrometer that was not designed for use with multimode fibers. A spectrometer optimized for use of multimode fiber has been obtained, and further evaluation of the sapphire temperature sensor is continuing.

  8. NEW OPTICAL SENSOR SUITE FOR ULTRAHIGH TEMPERATURE FOSSIL FUEL APPLICATIONS

    Energy Technology Data Exchange (ETDEWEB)

    Russell G. May; Tony Peng; Tom Flynn

    2004-12-01

    Accomplishments during the Phase I of a program to develop and demonstrate technology for the instrumentation of advanced powerplants are described. Engineers from Prime Research, LC and Babcock and Wilcox Research Center collaborated to generate a list of potential applications for robust photonic sensors in existing and future boiler plants. From that list, three applications were identified as primary candidates for initial development and demonstration of high-temperature sensors in an ultrasupercritical power plant. A matrix of potential fiber optic sensor approaches was derived, and a data set of specifications for high-temperature optical fiber was produced. Several fiber optic sensor configurations, including interferometric (extrinsic and intrinsic Fabry-Perot interferometer), gratings (fiber Bragg gratings and long period gratings), and microbend sensors, were evaluated in the laboratory. In addition, progress was made in the development of materials and methods to apply high-temperature optical claddings to sapphire fibers, in order to improve their optical waveguiding properties so that they can be used in the design and fabrication of high-temperature sensors. Through refinements in the processing steps, the quality of the interface between core and cladding of the fibers was improved, which is expected to reduce scattering and attenuation in the fibers. Numerical aperture measurements of both clad and unclad sapphire fibers were obtained and used to estimate the reduction in mode volume afforded by the cladding. High-temperature sensors based on sapphire fibers were also investigated. The fabrication of an intrinsic Fabry-Perot cavity within sapphire fibers was attempted by the bulk diffusion of magnesium oxide into short localized segments of longer sapphire fibers. Fourier analysis of the fringes that resulted when the treated fiber was interrogated by a swept laser spectrometer suggested that an intrinsic cavity had been formed in the fiber. Also

  9. Towards a Future of District Heating Systems with Low-Temperature Operation together with Non-Fossil Fuel Heat Sources

    DEFF Research Database (Denmark)

    Tol, Hakan; Dinçer, Ibrahim; Svendsen, Svend

    2012-01-01

    This study focused on investigation of non-fossil fuel heat sources to be supplied to low-energy district heating systems operating in low temperature such as 55 C and 25 C in terms of, respectively, supply and return. Vast variety of heat sources classed in categories such as fossil fuel...

  10. Fossil fuel furnace reactor

    Science.gov (United States)

    Parkinson, William J.

    1987-01-01

    A fossil fuel furnace reactor is provided for simulating a continuous processing plant with a batch reactor. An internal reaction vessel contains a batch of shale oil, with the vessel having a relatively thin wall thickness for a heat transfer rate effective to simulate a process temperature history in the selected continuous processing plant. A heater jacket is disposed about the reactor vessel and defines a number of independent controllable temperature zones axially spaced along the reaction vessel. Each temperature zone can be energized to simulate a time-temperature history of process material through the continuous plant. A pressure vessel contains both the heater jacket and the reaction vessel at an operating pressure functionally selected to simulate the continuous processing plant. The process yield from the oil shale may be used as feedback information to software simulating operation of the continuous plant to provide operating parameters, i.e., temperature profiles, ambient atmosphere, operating pressure, material feed rates, etc., for simulation in the batch reactor.

  11. Detecting the influence of fossil fuel and bio-fuel black carbon aerosols on near surface temperature changes

    Directory of Open Access Journals (Sweden)

    G. S. Jones

    2011-01-01

    Full Text Available Past research has shown that the dominant influence on recent global climate changes is from anthropogenic greenhouse gas increases with implications for future increases in global temperatures. One mitigation proposal is to reduce black carbon aerosol emissions. How much warming can be offset by controlling black carbon is unclear, especially as its influence on past climate has not been previously unambiguously detected. In this study observations of near-surface warming over the last century are compared with simulations using a climate model, HadGEM1. In the simulations black carbon, from fossil fuel and bio-fuel sources (fBC, produces a positive radiative forcing of about +0.25 Wm−2 over the 20th century, compared with +2.52 Wm−2 for well mixed greenhouse gases. A simulated warming of global mean near-surface temperatures over the twentieth century from fBC of 0.14 ± 0.1 K compares with 1.06 ± 0.07 K from greenhouse gases, −0.58 ± 0.10 K from anthropogenic aerosols, ozone and land use changes and 0.09 ± 0.09 K from natural influences. Using a detection and attribution methodology, the observed warming since 1900 has detectable influences from anthropogenic and natural factors. Fossil fuel and bio-fuel black carbon is found to have a detectable contribution to the warming over the last 50 yr of the 20th century, although the results are sensitive to the period being examined as fBC is not detected for the later fifty year period ending in 2006. The attributed warming of fBC was found to be consistent with the warming from fBC unscaled by the detection analysis. This study suggests that there is a possible significant influence from fBC on global temperatures, but its influence is small compared to that from greenhouse gas emissions.

  12. Inter-annual variability in fossil-fuel CO2 emissions due to temperature anomalies

    Science.gov (United States)

    Bréon, F.-M.; Boucher, O.; Brender, P.

    2017-07-01

    It is well known that short-term (i.e. interannual) variations in fossil-fuel CO2 emissions are closely related to the evolution of the national economies. Nevertheless, a fraction of the CO2 emissions are linked to domestic and business heating and cooling, which can be expected to be related to the meteorology, independently of the economy. Here, we analyse whether the signature of the inter-annual temperature anomalies is discernible in the time series of CO2 emissions at the country scale. Our analysis shows that, for many countries, there is a clear positive correlation between a heating-degree-person index and the component of the CO2 emissions that is not explained by the economy as quantified by the gross domestic product (GDP). Similarly, several countries show a positive correlation between a cooling-degree-person (CDP) index and CO2 emissions. The slope of the linear relationship for heating is on the order of 0.5-1 kg CO2 (degree-day-person)-1 but with significant country-to-country variations. A similar relationship for cooling shows even greater diversity. We further show that the inter-annual climate anomalies have a small but significant impact on the annual growth rate of CO2 emissions, both at the national and global scale. Such a meteorological effect was a significant contribution to the rather small and unexpected global emission growth rate in 2014 while its contribution to the near zero emission growth in 2015 was insignificant.

  13. The legacy of fossil fuels.

    Science.gov (United States)

    Armaroli, Nicola; Balzani, Vincenzo

    2011-03-01

    Currently, over 80% of the energy used by mankind comes from fossil fuels. Harnessing coal, oil and gas, the energy resources contained in the store of our spaceship, Earth, has prompted a dramatic expansion in energy use and a substantial improvement in the quality of life of billions of individuals in some regions of the world. Powering our civilization with fossil fuels has been very convenient, but now we know that it entails severe consequences. We treat fossil fuels as a resource that anyone anywhere can extract and use in any fashion, and Earth's atmosphere, soil and oceans as a dump for their waste products, including more than 30 Gt/y of carbon dioxide. At present, environmental legacy rather than consistence of exploitable reserves, is the most dramatic problem posed by the relentless increase of fossil fuel global demand. Harmful effects on the environment and human health, usually not incorporated into the pricing of fossil fuels, include immediate and short-term impacts related to their discovery, extraction, transportation, distribution, and burning as well as climate change that are spread over time to future generations or over space to the entire planet. In this essay, several aspects of the fossil fuel legacy are discussed, such as alteration of the carbon cycle, carbon dioxide rise and its measurement, greenhouse effect, anthropogenic climate change, air pollution and human health, geoengineering proposals, land and water degradation, economic problems, indirect effects on the society, and the urgent need of regulatory efforts and related actions to promote a gradual transition out of the fossil fuel era. While manufacturing sustainable solar fuels appears to be a longer-time perspective, alternatives energy sources already exist that have the potential to replace fossil fuels as feedstocks for electricity production. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  14. The legacy of fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Armaroli, N.; Balzani, V. [CNR, Bologna (Italy)

    2011-03-01

    Currently, over 80% of the energy used by mankind comes from fossil fuels. Harnessing coal, oil and gas, the energy resources contained in the store of our spaceship, Earth, has prompted a dramatic expansion in energy use and a substantial improvement in the quality of life of billions of individuals in some regions of the world. Powering our civilization with fossil fuels has been very convenient, but now we know that it entails severe consequences. We treat fossil fuels as a resource that anyone anywhere can extract and use in any fashion, and Earth's atmosphere, soil and oceans as a dump for their waste products, including more than 30 Gt/y of carbon dioxide. At present, environmental legacy rather than consistence of exploitable reserves, is the most dramatic problem posed by the relentless increase of fossil fuel global demand. Harmful effects on the environment and human health, usually not incorporated into the pricing of fossil fuels, include immediate and short-term impacts related to their discovery, extraction, transportation, distribution, and burning as well as climate change that are spread over time to future generations or over space to the entire planet. In this essay, several aspects of the fossil fuel legacy are discussed, such as alteration of the carbon cycle, carbon dioxide rise and its measurement, greenhouse effect, anthropogenic climate change, air pollution and human health, geoengineering proposals, land and water degradation, economic problems, indirect effects on the society, and the urgent need of regulatory efforts and related actions to promote a gradual transition out of the fossil fuel era. While manufacturing sustainable solar fuels appears to be a longer-time perspective, alternatives energy sources already exist that have the potential to replace fossil fuels as feedstocks for electricity production.

  15. DETERMINING THE COMPOSITION OF HIGH TEMPERATURE COMBUSTION PRODUCTS OF FOSSIL FUEL BASED ON VARIATIONAL PRINCIPLES AND GEOMETRIC PROGRAMMING

    Directory of Open Access Journals (Sweden)

    Velibor V Vujović

    2011-01-01

    Full Text Available This paper presents the algorithm and results of a computer program for calculation of complex equilibrium composition for the high temperature fossil fuel combustion products. The method of determining the composition of high temperatures combustion products at the temperatures appearing in the open cycle MHD power generation is given. The determination of combustion product composition is based on minimization of the Gibbs free energy. The number of equations to be solved is reduced by using variational principles and a method of geometric programming and is equal to the sum of the numbers of elements and phases. A short description of the computer program for the calculation of the composition and an example of the results are also given.

  16. Development of Metal Oxide Nanostructure-based Optical Sensors for Fossil Fuel Derived Gases Measurement at High Temperature

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Kevin P. [Univ. of Pittsburgh, PA (United States)

    2015-02-13

    operation temperature up to 750°C, first distributed chemical measurements at the record high temperature up to 700°C, first distributed pressure measurement at the record high temperature up to 800°C, and the fiber laser sensors with the record high operation temperature up to 700°C. The research performed by this program dramatically expand the functionality, adaptability, and applicability of distributed fiber optical sensors with potential applications in a number of high-temperature energy systems such as fossil-fuel power generation, high-temperature fuel cell applications, and potential for nuclear energy systems.

  17. Fossil-fuel constraints on global warming

    Energy Technology Data Exchange (ETDEWEB)

    Zecca, Antonio; Chiari, Luca [Physics Department, University of Trento, Via Sommarive 14, I-38050 Povo TN (Italy)

    2010-01-15

    In 2008 and 2009 two papers by Kharecha and Hansen and by Nel and Cooper examined possible fossil energy availability and energy consumption scenarios and consequences for future climate. The papers yield somewhat similar results regarding atmospheric CO{sub 2} levels, but they reach substantially different conclusions regarding future climate change. Here, we compare their methods and results. Our work shows that Nel and Cooper's paper significantly underestimates future warming. Nel and Cooper conclude that even if all the available fossil fuels would be burned at the maximum possible rate during this century, the consequent warming would cap at less than 1 C above the 2000 level. We find that - under Nel and Cooper's assumption of an intensive exploitation of fossil fuels - the global temperature in 2100 will likely reach levels which would lead to severely damaging long-term impacts. (author)

  18. Development of Nano-crystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases

    Energy Technology Data Exchange (ETDEWEB)

    Xiao, Hai [Missouri Univ. of Science and Technology, Rolla, MO (United States); Dong, Junhang [Univ. of Cincinnati, OH (United States); Lin, Jerry [Arizona State Univ., Tempe, AZ (United States); Romero, Van [New Mexico Institute of Mining and Technology, Socorro, NM (United States)

    2012-03-01

    This is a final technical report for the first project year from July 1, 2005 to Jan 31, 2012 for DoE/NETL funded project DE-FC26-05NT42439: Development of Nanocrystalline Doped-Ceramic Enabled Fiber Sensors for High Temperature In-Situ Monitoring of Fossil Fuel Gases. This report summarizes the technical progresses and achievements towards the development of novel nanocrystalline doped ceramic material-enabled optical fiber sensors for in situ and real time monitoring the gas composition of flue or hot gas streams involved in fossil-fuel based power generation and hydrogen production.

  19. Energy properties of solid fossil fuels and solid biofuels

    Energy Technology Data Exchange (ETDEWEB)

    Holubcik, Michal, E-mail: michal.holubcik@fstroj.uniza.sk; Jandacka, Jozef, E-mail: jozef.jandacka@fstroj.uniza.sk [University of Žilina, Faculty of Mechanical Engineering, Department of Power Engineering, Univerzitná 8215/1, 010 26 Žilina (Slovakia); Kolkova, Zuzana, E-mail: zuzana.kolkova@rc.uniza.sk [Research centre, University of Žilina, Univerzitna 8215/1, 010 26 Žilina (Slovakia)

    2016-06-30

    The paper deals about the problematic of energy properties of solid biofuels in comparison with solid fossil fuels. Biofuels are alternative to fossil fuels and their properties are very similar. During the experiments were done in detail experiments to obtain various properties of spruce wood pellets and wheat straw pellets like biofuels in comparison with brown coal and black coal like fossil fuels. There were tested moisture content, volatile content, fixed carbon content, ash content, elementary analysis (C, H, N, S content) and ash fusion temperatures. The results show that biofuels have some advantages and also disadvantages in comparison with solid fossil fuels.

  20. On Prediction of Depreciation Time of Fossil Fuel in Malaysia

    OpenAIRE

    Tey Jin Pin; Nora Muda

    2012-01-01

    Problem statement: The fossil fuels play a crucial role in the world energy markets. Demand for fossil fuels become increasingly high and worrisome, because of fossil fuels will be significantly reduced and ultimately exhausted. This study was conducted to predict the depreciation time of fossil fuels in Malaysia and estimate the time remaining before the fossil fuels will finish. Approach: To predict the depreciation time of fossil fuels, the reserves, consumption and prices of fossil fuel w...

  1. Fossil Fuels, Backstop Technologies, and Imperfect Substitution

    NARCIS (Netherlands)

    van der Meijden, G.C.; Pittel, Karen; van der Ploeg, Frederick; Withagen, Cees

    2014-01-01

    This chapter studies the transition from fossil fuels to backstop technologies in a general equilibrium model in which growth is driven by research and development. The analysis generalizes the existing literature by allowing for imperfect substitution between fossil fuels and the new energy

  2. Fossil fuel support mechanisms in Finland

    Energy Technology Data Exchange (ETDEWEB)

    Lampinen, Ari

    2013-10-15

    Fossil fuel subsidies and other state support for fossil fuels are forbidden by the Kyoto Protocol and other international treaties. However, they are still commonly used. This publication presents and analyses diverse state support mechanisms for fossil fuels in Finland in 2003-2010. Total of 38 support mechanisms are covered in quantitative analysis and some other mechanisms are mentioned qualitatively only. For some mechanisms the study includes a longer historical perspective. This is the case for tax subsidies for crude oil based traffic fuels that have been maintained in Finland since 1965.

  3. Constraints of fossil fuels depletion on global warming projections

    Energy Technology Data Exchange (ETDEWEB)

    Chiari, Luca, E-mail: chiari@science.unitn.it [Department of Physics, University of Trento, Via Sommarive 14, 38123 Povo (Italy); Zecca, Antonio, E-mail: zecca@science.unitn.it [Department of Physics, University of Trento, Via Sommarive 14, 38123 Povo (Italy)

    2011-09-15

    A scientific debate is in progress about the intersection of climate change with the new field of fossil fuels depletion geology. Here, new projections of atmospheric CO{sub 2} concentration and global-mean temperature change are presented, should fossil fuels be exploited at a rate limited by geological availability only. The present work starts from the projections of fossil energy use, as obtained from ten independent sources. From such projections an upper bound, a lower bound and an ensemble mean profile for fossil CO{sub 2} emissions until 2200 are derived. Using the coupled gas-cycle/climate model MAGICC, the corresponding climatic projections out to 2200 are obtained. We find that CO{sub 2} concentration might increase up to about 480 ppm (445-540 ppm), while the global-mean temperature increase w.r.t. 2000 might reach 1.2 deg. C (0.9-1.6 deg. C). However, future improvements of fossil fuels recovery and discoveries of new resources might lead to higher emissions; hence our climatic projections are likely to be underestimated. In the absence of actions of emissions reduction, a level of dangerous anthropogenic interference with the climate system might be already experienced toward the middle of the 21st century, despite the constraints imposed by the exhaustion of fossil fuels. - Highlights: > CO{sub 2} and global temperature are projected under fossil fuels exhaustion scenarios. > Temperature is projected to reach a minimum of 2 deg. C above pre-industrial. > Temperature projections are possibly lower than the IPCC ones. > Fossil fuels exhaustion will not avoid dangerous global warming.

  4. Fossil fuels in the 21st century.

    Science.gov (United States)

    Lincoln, Stephen F

    2005-12-01

    An overview of the importance of fossil fuels in supplying the energy requirements of the 21st century, their future supply, and the impact of their use on global climate is presented. Current and potential alternative energy sources are considered. It is concluded that even with substantial increases in energy derived from other sources, fossil fuels will remain a major energy source for much of the 21st century and the sequestration of CO2 will be an increasingly important requirement.

  5. Dinosaur fossils predict body temperatures.

    OpenAIRE

    Gillooly, James F; Allen, Andrew P.; Charnov, Eric L.

    2006-01-01

    Perhaps the greatest mystery surrounding dinosaurs concerns whether they were endotherms, ectotherms, or some unique intermediate form. Here we present a model that yields estimates of dinosaur body temperature based on ontogenetic growth trajectories obtained from fossil bones. The model predicts that dinosaur body temperatures increased with body mass from approximately 25 degrees C at 12 kg to approximately 41 degrees C at 13,000 kg. The model also successfully predicts observed increases ...

  6. Dinosaur fossils predict body temperatures.

    Directory of Open Access Journals (Sweden)

    James F Gillooly

    2006-07-01

    Full Text Available Perhaps the greatest mystery surrounding dinosaurs concerns whether they were endotherms, ectotherms, or some unique intermediate form. Here we present a model that yields estimates of dinosaur body temperature based on ontogenetic growth trajectories obtained from fossil bones. The model predicts that dinosaur body temperatures increased with body mass from approximately 25 degrees C at 12 kg to approximately 41 degrees C at 13,000 kg. The model also successfully predicts observed increases in body temperature with body mass for extant crocodiles. These results provide direct evidence that dinosaurs were reptiles that exhibited inertial homeothermy.

  7. Dinosaur Fossils Predict Body Temperatures

    Science.gov (United States)

    Allen, Andrew P; Charnov, Eric L

    2006-01-01

    Perhaps the greatest mystery surrounding dinosaurs concerns whether they were endotherms, ectotherms, or some unique intermediate form. Here we present a model that yields estimates of dinosaur body temperature based on ontogenetic growth trajectories obtained from fossil bones. The model predicts that dinosaur body temperatures increased with body mass from approximately 25 °C at 12 kg to approximately 41 °C at 13,000 kg. The model also successfully predicts observed increases in body temperature with body mass for extant crocodiles. These results provide direct evidence that dinosaurs were reptiles that exhibited inertial homeothermy. PMID:16817695

  8. Sanitary effects of fossil fuels; Effets sanitaires des combustibles fossiles

    Energy Technology Data Exchange (ETDEWEB)

    Nifenecker, H. [Centre National de la Recherche Scientifique (IN2P3/CNRS), 38 - Grenoble (France)

    2006-07-01

    In this compilation are studied the sanitary effects of fossil fuels, behavioral and environmental sanitary risks. The risks in connection with the production, the transport and the distribution(casting) are also approached for the oil(petroleum), the gas and the coal. Accidents in the home are evoked. The risks due to the atmospheric pollution are seen through the components of the atmospheric pollution as well as the sanitary effects of this pollution. (N.C.)

  9. Fossil fuels in a trillion tonne world

    Science.gov (United States)

    Scott, Vivian; Haszeldine, R. Stuart; Tett, Simon F. B.; Oschlies, Andreas

    2015-05-01

    The useful energy services and energy density value of fossil carbon fuels could be retained for longer timescales into the future if their combustion is balanced by CO2 recapture and storage. We assess the global balance between fossil carbon supply and the sufficiency (size) and capability (technology, security) of candidate carbon stores. A hierarchy of value for extraction-to-storage pairings is proposed, which is augmented by classification of CO2 containment as temporary (100,000 yr). Using temporary stores is inefficient and defers an intergenerational problem. Permanent storage capacity is adequate to technically match current fossil fuel reserves. However, rates of storage creation cannot balance current and expected rates of fossil fuel extraction and CO2 consequences. Extraction of conventional natural gas is uniquely holistic because it creates the capacity to re-inject an equivalent tonnage of carbon for storage into the same reservoir and can re-use gas-extraction infrastructure for storage. By contrast, balancing the extraction of coal, oil, biomass and unconventional fossil fuels requires the engineering and validation of additional carbon storage. Such storage is, so far, unproven in sufficiency.

  10. The Fascinating Story of Fossil Fuels

    Science.gov (United States)

    Asimov, Isaac

    1973-01-01

    How this energy source was created, its meaning to mankind, our drastically reduced supply, and why we cannot wait for nature to make more are considered. Today fossil fuels supply 96 percent of the energy used but we must find alternate energy options if we are to combat the energy crisis. (BL)

  11. Fossil fuels supplies modeling and research

    Energy Technology Data Exchange (ETDEWEB)

    Leiby, P.N.

    1996-06-01

    The fossil fuel supplies modeling and research effort focuses on models for US Strategic Petroleum Reserve (SPR) planning and management. Topics covered included new SPR oil valuation models, updating models for SPR risk analysis, and fill-draw planning. Another task in this program area is the development of advanced computational tools for three-dimensional seismic analysis.

  12. Diatoms: a fossil fuel of the future.

    Science.gov (United States)

    Levitan, Orly; Dinamarca, Jorge; Hochman, Gal; Falkowski, Paul G

    2014-03-01

    Long-term global climate change, caused by burning petroleum and other fossil fuels, has motivated an urgent need to develop renewable, carbon-neutral, economically viable alternatives to displace petroleum using existing infrastructure. Algal feedstocks are promising candidate replacements as a 'drop-in' fuel. Here, we focus on a specific algal taxon, diatoms, to become the fossil fuel of the future. We summarize past attempts to obtain suitable diatom strains, propose future directions for their genetic manipulation, and offer biotechnological pathways to improve yield. We calculate that the yields obtained by using diatoms as a production platform are theoretically sufficient to satisfy the total oil consumption of the US, using between 3 and 5% of its land area. Copyright © 2014 Elsevier Ltd. All rights reserved.

  13. Emissions Scenarios and Fossil-fuel Peaking

    Science.gov (United States)

    Brecha, R.

    2008-12-01

    Intergovernmental Panel on Climate Change (IPCC) emissions scenarios are based on detailed energy system models in which demographics, technology and economics are used to generate projections of future world energy consumption, and therefore, of greenhouse gas emissions. Built into the assumptions for these scenarios are estimates for ultimately recoverable resources of various fossil fuels. There is a growing chorus of critics who believe that the true extent of recoverable fossil resources is much smaller than the amounts taken as a baseline for the IPCC scenarios. In a climate optimist camp are those who contend that "peak oil" will lead to a switch to renewable energy sources, while others point out that high prices for oil caused by supply limitations could very well lead to a transition to liquid fuels that actually increase total carbon emissions. We examine a third scenario in which high energy prices, which are correlated with increasing infrastructure, exploration and development costs, conspire to limit the potential for making a switch to coal or natural gas for liquid fuels. In addition, the same increasing costs limit the potential for expansion of tar sand and shale oil recovery. In our qualitative model of the energy system, backed by data from short- and medium-term trends, we have a useful way to gain a sense of potential carbon emission bounds. A bound for 21st century emissions is investigated based on two assumptions: first, that extractable fossil-fuel resources follow the trends assumed by "peak oil" adherents, and second, that little is done in the way of climate mitigation policies. If resources, and perhaps more importantly, extraction rates, of fossil fuels are limited compared to assumptions in the emissions scenarios, a situation can arise in which emissions are supply-driven. However, we show that even in this "peak fossil-fuel" limit, carbon emissions are high enough to surpass 550 ppm or 2°C climate protection guardrails. Some

  14. Replacement of fossil fuels by hydrogen

    Science.gov (United States)

    Dahlberg, R.

    The replacement of fossil fuels by solar hydrogen plantations is considered. A model is proposed in which ten plantation families, situated in suitable deserted zones of the world after the year 2000, would generate enough electrical energy to produce solar cells and materials for the construction of ten new plantations within a decade. The technological growth process for identical solar plantation units could be completed about 50 years after construction of the first plantation. All ten plantation families would, by using their electrical energy for the electrolysis of water, generate an amount of hydrogen per year which is four to five times the energy of the world's present annual consumption of oil. This concept envisions the global replacement of fossil fuels by hydrogen within a period consistent with the remaining time span of fossil fuel availability. Storage and transportation of hydrogen would be economical, and the energy produced would not present any environmental problems. Advantages with respect to gains in international cooperation, world peace, and world economy are also discussed.

  15. Traversing the mountaintop: world fossil fuel production to 2050.

    Science.gov (United States)

    Nehring, Richard

    2009-10-27

    During the past century, fossil fuels--petroleum liquids, natural gas and coal--were the dominant source of world energy production. From 1950 to 2005, fossil fuels provided 85-93% of all energy production. All fossil fuels grew substantially during this period, their combined growth exceeding the increase in world population. This growth, however, was irregular, providing for rapidly growing per capita production from 1950 to 1980, stable per capita production from 1980 to 2000 and rising per capita production again after 2000. During the past half century, growth in fossil fuel production was essentially limited by energy demand. During the next half century, fossil fuel production will be limited primarily by the amount and characteristics of remaining fossil fuel resources. Three possible scenarios--low, medium and high--are developed for the production of each of the fossil fuels to 2050. These scenarios differ primarily by the amount of ultimate resources estimated for each fossil fuel. Total fossil fuel production will continue to grow, but only slowly for the next 15-30 years. The subsequent peak plateau will last for 10-15 years. These production peaks are robust; none of the fossil fuels, even with highly optimistic resource estimates, is projected to keep growing beyond 2050. World fossil fuel production per capita will thus begin an irreversible decline between 2020 and 2030.

  16. Microbial biocatalyst developments to upgrade fossil fuels.

    Science.gov (United States)

    Kilbane, John J

    2006-06-01

    Steady increases in the average sulfur content of petroleum and stricter environmental regulations concerning the sulfur content have promoted studies of bioprocessing to upgrade fossil fuels. Bioprocesses can potentially provide a solution to the need for improved and expanded fuel upgrading worldwide, because bioprocesses for fuel upgrading do not require hydrogen and produce far less carbon dioxide than thermochemical processes. Recent advances have demonstrated that biodesulfurization is capable of removing sulfur from hydrotreated diesel to yield a product with an ultra-low sulfur concentration that meets current environmental regulations. However, the technology has not yet progressed beyond laboratory-scale testing, as more efficient biocatalysts are needed. Genetic studies to obtain improved biocatalysts for the selective removal of sulfur and nitrogen from petroleum provide the focus of current research efforts.

  17. Fossil-fuels, bio-fuels and food: Raking priorities

    OpenAIRE

    Dias, Guilherme Leite da Silva; Guilhoto, Joaquim José Martins

    2010-01-01

    This paper deals with the question of the trade-offs between bio-fuels, fossil-fuels, and food. To do so an analysis is conducted taking into consideration the differences in relative prices and in the productive structure among the countries. The results shows that in general food puts a greater stress over the economies than energy does, and mainly in the developing economies. As a consequence of that, the possibilities for the growing use of bio-fuels is limited and restrict to countries w...

  18. Recent developments in biodesulfurization of fossil fuels.

    Science.gov (United States)

    Xu, Ping; Feng, Jinhui; Yu, Bo; Li, Fuli; Ma, Cuiqing

    2009-01-01

    The emission of sulfur oxides can have adverse effects on the environment. Biodesulfurization of fossil fuels is attracting more and more attention because such a bioprocess is environmentally friendly. Some techniques of desulfurization have been used or studied to meet the stricter limitation on sulfur content in China. Recent advances have demonstrated the mechanism and developments for biodesulfurization of gasoline, diesel and crude oils by free cells or immobilized cells. Genetic technology was also used to improve sulfur removal efficiencies. In this review, we summarize recent progress mainly in China on petroleum biodesulfurization.

  19. Burning Fossil Fuels: Impact of Climate Change on Health.

    Science.gov (United States)

    Sommer, Alfred

    2016-01-01

    A recent, sophisticated granular analysis of climate change in the United States related to burning fossil fuels indicates a high likelihood of dramatic increases in temperature, wet-bulb temperature, and precipitation, which will dramatically impact the health and well-being of many Americans, particularly the young, the elderly, and the poor and marginalized. Other areas of the world, where they lack the resources to remediate these weather impacts, will be even more greatly affected. Too little attention is being paid to the impending health impact of accumulating greenhouse gases. © The Author(s) 2015.

  20. Microalgal and terrestrial transport biofuels to displace fossil fuels

    NARCIS (Netherlands)

    Reijnders, L.

    2009-01-01

    Terrestrial transport biofuels differ in their ability to replace fossil fuels. When both the conversion of solar energy into biomass and the life cycle inputs of fossil fuels are considered, ethanol from sugarcane and biodiesel from palm oil do relatively well, if compared with ethanol from corn,

  1. Divesting from Fossil Fuels Makes Sense Morally… and Financially

    Science.gov (United States)

    Cleveland, Cutler J.; Reibstein, Richard

    2015-01-01

    Should university endowments divest from fossil fuels? A public discussion of this question has seen some university presidents issuing statements that they would not divest--that investments should not be used for "political action." Many universities hold large endowments that have significant positions in fossil fuel companies or…

  2. Approaches to bioremediation of fossil fuel contaminated soil: An ...

    African Journals Online (AJOL)

    A reliance on fossil fuels as a source of energy has resulted in the generation of pollutants which have entered the environment. Health of humans, animals, plants and microorganisms has been compromised due to activities linked to fossil fuel extraction, processing and use. Coal conversion to value added products has ...

  3. Traversing the mountaintop: world fossil fuel production to 2050

    OpenAIRE

    Nehring, Richard

    2009-01-01

    During the past century, fossil fuels—petroleum liquids, natural gas and coal—were the dominant source of world energy production. From 1950 to 2005, fossil fuels provided 85–93% of all energy production. All fossil fuels grew substantially during this period, their combined growth exceeding the increase in world population. This growth, however, was irregular, providing for rapidly growing per capita production from 1950 to 1980, stable per capita production from 1980 to 2000 and rising per ...

  4. Evaluation of Biodiesel Fuels to Reduce Fossil Fuel Use in Corps of Engineers Floating Plant Operations

    Science.gov (United States)

    2016-07-01

    ER D C/ CH L TR -1 6- 11 Dredging Operations and Environmental Research Program Evaluation of Biodiesel Fuels to Reduce Fossil Fuel Use... Fuels to Reduce Fossil Fuel Use in Corps of Engineers Floating Plant Operations Michael Tubman and Timothy Welp Coastal and Hydraulics Laboratory...sensitive emissions, increase use of renewable energy, and reduce the use of fossil fuels was conducted with funding from the U.S. Army Corps of

  5. Dataset for analysing the relationships among economic growth, fossil fuel and non-fossil fuel consumption.

    Science.gov (United States)

    Asafu-Adjaye, John; Byrne, Dominic; Alvarez, Maximiliano

    2017-02-01

    The data presented in this article are related to the research article entitled 'Economic Growth, Fossil Fuel and Non-Fossil Consumption: A Pooled Mean Group Analysis using Proxies for Capital' (J. Asafu-Adjaye, D. Byrne, M. Alvarez, 2016) [1]. This article describes data modified from three publicly available data sources: the World Bank׳s World Development Indicators (http://databank.worldbank.org/data/reports.aspx?source=world-development-indicators), the U.S. Energy Information Administration׳s International Energy Statistics (http://www.eia.gov/cfapps/ipdbproject/IEDIndex3.cfm?tid=44&pid=44&aid=2) and the Barro-Lee Educational Attainment Dataset (http://www.barrolee.com). These data can be used to examine the relationships between economic growth and different forms of energy consumption. The dataset is made publicly available to promote further analyses.

  6. Status of fossil fuel reserves; Etat des reserves des combustibles fossiles

    Energy Technology Data Exchange (ETDEWEB)

    Laherrere, J

    2005-07-01

    Reserves represent the sum of past and future productions up to the end of production. In most countries the reserve data of fields are confidential. Therefore, fossil fuel reserves are badly known because the published data are more political than technical and many countries make a confusion between resources and reserves. The cumulated production of fossil fuels represents only between a third and a fifth of the ultimate reserves. The production peak will take place between 2020 and 2050. In the ultimate reserves, which extrapolate the past, the fossil fuels represent three thirds of the overall energy. This document analyses the uncertainties linked with fossil fuel reserves: reliability of published data, modeling of future production, comparison with other energy sources, energy consumption forecasts, reserves/production ratio, exploitation of non-conventional hydrocarbons (tar sands, extra-heavy oils, bituminous shales, coal gas, gas shales, methane in overpressure aquifers, methane hydrates), technology impacts, prices impact, and reserves growth. (J.S.)

  7. Maximum fossil fuel feedstock replacement potential of petrochemicals via biorefineries

    NARCIS (Netherlands)

    Brehmer, B.; Boom, R.M.; Sanders, J.P.M.

    2009-01-01

    The search for feedstock replacement options within the petrochemical industry should logically be based upon non-fossil resources. Retaining the functionality of the biochemicals in biomass for use as chemical products and precursors can lead to a sizeable reduction of fossil fuel consumption. This

  8. The financial impact of divestment from fossil fuels

    NARCIS (Netherlands)

    Plantinga, Auke; Scholtens, Bert

    2016-01-01

    Divesting from fossil companies has been put forward as a means to address climate change. We study the impact of such divesting on investment portfolio performance. To this extent, we systematically investigate the investment performance of portfolios with and without fossil fuel company stocks. We

  9. FOSSIL FUEL ENERGY RESOURCES OF ETHIOPIA Wolela Ahmed ...

    African Journals Online (AJOL)

    a

    , P.O. Box 486, Addis Ababa,. Ethiopia ... KEY WORDS: Coal, Energy, Ethiopia, Fossil fuel, Oil shale, Oil and gas. INTRODUCTION. Energy is ...... metamorphosed to semi-anthracite stage due to high geothermal gradient. The moisture content.

  10. Legislative and Regulatory Timeline for Fossil Fuel Combustion Wastes

    Science.gov (United States)

    This timeline walks through the history of fossil fuel combustion waste regulation since 1976 and includes information such as regulations, proposals, notices, amendments, reports and meetings and site visits conducted.

  11. Fossil Fuel Emission Verification Modeling at LLNL

    Energy Technology Data Exchange (ETDEWEB)

    Cameron-Smith, P; Kosovic, B; Guilderson, T; Monache, L D; Bergmann, D

    2009-08-06

    We have an established project at LLNL to develop the tools needed to constrain fossil fuel carbon dioxide emissions using measurements of the carbon-14 isotope in atmospheric samples. In Figure 1 we show the fossil fuel plumes from Los Angeles and San Francisco for two different weather patterns. Obviously, a measurement made at any given location is going to depend on the weather leading up to the measurement. Thus, in order to determine the GHG emissions from some region using in situ measurements of those GHGs, we use state-of-the-art global and regional atmospheric chemistry-transport codes to simulate the plumes: the LLNL-IMPACT model (Rotman et al., 2004) and the WRFCHEM community code (http://www.wrf-model.org/index.php). Both codes can use observed (aka assimilated) meteorology in order to recreate the actual transport that occurred. The measured concentration of each tracer at a particular spatio-temporal location is a linear combination of the plumes from each region at that location (for non-reactive species). The challenge is to calculate the emission strengths for each region that fit the observed concentrations. In general this is difficult because there are errors in the measurements and modeling of the plumes. We solve this inversion problem using the strategy illustrated in Figure 2. The Bayesian Inference step combines the a priori estimates of the emissions, and their uncertainty, for each region with the results of the observations, and their uncertainty, and an ensemble of model predicted plumes for each region, and their uncertainty. The result is the mathematical best estimate of the emissions and their errors. In the case of non-linearities, or if we are using a statistical sampling technique such as a Markov Chain Monte Carlo technique, then the process is iterated until it converges (ie reaches stationarity). For the Bayesian inference we can use both a direct inversion capability, which is fast but requires assumptions of linearity and

  12. Hydrogen production econometric studies. [hydrogen and fossil fuels

    Science.gov (United States)

    Howell, J. R.; Bannerot, R. B.

    1975-01-01

    The current assessments of fossil fuel resources in the United States were examined, and predictions of the maximum and minimum lifetimes of recoverable resources according to these assessments are presented. In addition, current rates of production in quads/year for the fossil fuels were determined from the literature. Where possible, costs of energy, location of reserves, and remaining time before these reserves are exhausted are given. Limitations that appear to hinder complete development of each energy source are outlined.

  13. Biodesulfurization of refractory organic sulfur compounds in fossil fuels.

    Science.gov (United States)

    Soleimani, Mehran; Bassi, Amarjeet; Margaritis, Argyrios

    2007-01-01

    The stringent new regulations to lower sulfur content in fossil fuels require new economic and efficient methods for desulfurization of recalcitrant organic sulfur. Hydrodesulfurization of such compounds is very costly and requires high operating temperature and pressure. Biodesulfurization is a non-invasive approach that can specifically remove sulfur from refractory hydrocarbons under mild conditions and it can be potentially used in industrial desulfurization. Intensive research has been conducted in microbiology and molecular biology of the competent strains to increase their desulfurization activity; however, even the highest activity obtained is still insufficient to fulfill the industrial requirements. To improve the biodesulfurization efficiency, more work is needed in areas such as increasing specific desulfurization activity, hydrocarbon phase tolerance, sulfur removal at higher temperature, and isolating new strains for desulfurizing a broader range of sulfur compounds. This article comprehensively reviews and discusses key issues, advances and challenges for a competitive biodesulfurization process.

  14. 76 FR 3587 - Standards of Performance for Fossil-Fuel-Fired, Electric Utility, Industrial-Commercial...

    Science.gov (United States)

    2011-01-20

    ... AGENCY 40 CFR Part 60 RIN 2060-AQ46 Standards of Performance for Fossil-Fuel-Fired, Electric Utility... 221112 Fossil fuel-fired electric utility steam generating units. Federal Government 22112 Fossil fuel... government 22112 Fossil fuel-fired electric utility steam generating units owned by municipalities. 921150...

  15. Exploration for fossil and nuclear fuels from orbital altitudes

    Science.gov (United States)

    Short, N. M.

    1977-01-01

    The paper discusses the application of remotely sensed data from orbital satellites to the exploration for fossil and nuclear fuels. Geological applications of Landsat data are described including map editing, lithologic identification, structural geology, and mineral exploration. Specific results in fuel exploration are reviewed and a series of related Landsat images is included.

  16. Alternative fossil-based transportation fuels

    Science.gov (United States)

    2008-01-01

    "Alternative fuels derived from oil sands and from coal liquefaction can cost-effectively diversify fuel supplies, but neither type significantly reduces U.S. carbon-dioxide emissions enough to arrest long-term climate change".

  17. Fossil-Fuel C02 Emissions Database and Exploration System

    Science.gov (United States)

    Krassovski, M.; Boden, T.

    2012-04-01

    Fossil-Fuel C02 Emissions Database and Exploration System Misha Krassovski and Tom Boden Carbon Dioxide Information Analysis Center Oak Ridge National Laboratory The Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL) quantifies the release of carbon from fossil-fuel use and cement production each year at global, regional, and national spatial scales. These estimates are vital to climate change research given the strong evidence suggesting fossil-fuel emissions are responsible for unprecedented levels of carbon dioxide (CO2) in the atmosphere. The CDIAC fossil-fuel emissions time series are based largely on annual energy statistics published for all nations by the United Nations (UN). Publications containing historical energy statistics make it possible to estimate fossil-fuel CO2 emissions back to 1751 before the Industrial Revolution. From these core fossil-fuel CO2 emission time series, CDIAC has developed a number of additional data products to satisfy modeling needs and to address other questions aimed at improving our understanding of the global carbon cycle budget. For example, CDIAC also produces a time series of gridded fossil-fuel CO2 emission estimates and isotopic (e.g., C13) emissions estimates. The gridded data are generated using the methodology described in Andres et al. (2011) and provide monthly and annual estimates for 1751-2008 at 1° latitude by 1° longitude resolution. These gridded emission estimates are being used in the latest IPCC Scientific Assessment (AR4). Isotopic estimates are possible thanks to detailed information for individual nations regarding the carbon content of select fuels (e.g., the carbon signature of natural gas from Russia). CDIAC has recently developed a relational database to house these baseline emissions estimates and associated derived products and a web-based interface to help users worldwide query these data holdings. Users can identify, explore and download desired CDIAC

  18. Microalgal and Terrestrial Transport Biofuels to Displace Fossil Fuels

    Directory of Open Access Journals (Sweden)

    Lucas Reijnders

    2009-02-01

    Full Text Available Terrestrial transport biofuels differ in their ability to replace fossil fuels. When both the conversion of solar energy into biomass and the life cycle inputs of fossil fuels are considered, ethanol from sugarcane and biodiesel from palm oil do relatively well, if compared with ethanol from corn, sugar beet or wheat and biodiesel from rapeseed. When terrestrial biofuels are to replace mineral oil-derived transport fuels, large areas of good agricultural land are needed: about 5x108 ha in the case of biofuels from sugarcane or oil palm, and at least 1.8-3.6x109 ha in the case of ethanol from wheat, corn or sugar beet, as produced in industrialized countries. Biofuels from microalgae which are commercially produced with current technologies do not appear to outperform terrestrial plants such as sugarcane in their ability to displace fossil fuels. Whether they will able to do so on a commercial scale in the future, is uncertain.

  19. Impacts of cofiring biomass with fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Zygarlicke, C.J.; Eylands, K.E.; McCollor, D.P.; Musich, M.A.; Toman, D.L.

    2000-07-01

    In the course of the major worldwide effort to reduce greenhouse gas emissions, cofiring renewable biomass fuels in conventional coal-fired utilities has been identified as one of the lower-cost options to achieve such reductions. The Energy and Environmental Research Center (EERC) has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw and alfalfa stems were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pulverized coal in a bench-scale downfired furnace. Combustion testing was performed to obtain deposits typical of boiler fouling and slagging conditions. Analysis methods using computer-controlled scanning electron microscopy and chemical fractionation were applied to determine the composition and association of inorganic materials in the biomass samples. Modified sample preparation techniques and mineral quantification procedures were developed to accommodate the inorganic material in these samples. Mineralogical analyses of the wheat straw show elongated 10--30-{micro}m amorphous silica particles or phytoliths in the wheat straw structure. Alkali such as potassium, calcium, and sodium is organically bound and dispersed in the wheat straw organic structure. Combustion test results showed that the blends fed quite evenly, with good burnout. Significant slag deposit formation was observed for the 100% wheat straw, compared to bituminous and subbituminous coals burned under similar conditions. Fouling was only slightly worse for the 100% wheat straw fuel compared to the coals. Slagging and fouling deposits are rich in potassium silicate formed during the high-temperature reaction of the organically bound potassium that is in close proximity to silica particles in the wheat straw

  20. Assessing global fossil fuel availability in a scenario framework

    Energy Technology Data Exchange (ETDEWEB)

    Bauer, Nico; Hilaire, Jerome; Brecha, Robert J.; Edmonds, James A.; Jiang, Kejun; Kriegler, Elmar; Rogner, Hans-Holger; Sferra, Fabio

    2016-06-01

    This study assesses global, long-term economic availability of coal, oil and gas within the Shared Socio-economic Pathway (SSP) scenario framework considering alternative assumptions as to highly uncertain future developments of technology, policy and the economy. Diverse sets of trajectories are formulated varying the challenges to mitigation and adaptation of climate change. The potential CO2 emissions from fossil fuels make it a crucial element subject to deep uncertainties. The analysis is based on a well-established data set of cost-quantity combinations that assumes favorable techno-economic developments, but ignores additional constraints on the extraction sector. This study significantly extends that analysis to include alternative assumptions for the fossil fuel sector consistent with the SSP scenario families and applies these filters to the original data set, thus resulting in alternative cumulative fossil fuel availability curves. In a Middle-of-the-Road scenario, low cost fossil fuels embody carbon consistent with a RCP6.0 emission profile, if all the CO2 were emitted freely during the 21st century. In scenarios with high challenges to mitigation, the assumed embodied carbon in low-cost fossil fuels can trigger a RCP8.5 scenario; low mitigation challenges scenarios are still consistent with a RCP4.5 scenario.

  1. Fast optical measurements and imaging of flow mixing: Fast optical measurements and imaging of temperature in combined fossil fuel and biomass/waste systems

    Energy Technology Data Exchange (ETDEWEB)

    Clausen, Soennik; Fateev, A.; Lindorff Nielsen, K.; Evseev, V.

    2012-02-15

    Project is focused on fast time-resolved infrared measurements of gas temperature and fast IR-imagining of flames in various combustion environments. The infrared spectrometer system was developed in the project for fast infrared spectral measurements on industrial scale using IR-fibre- optics. Fast time-and spectral-resolved measurements in 1.5-5.1 mu spectral range give information about flame characteristics like gas and particle temperatures, eddies and turbulent gas mixing. Time-resolved gas composition in that spectral range (H{sub 2}O, CH{sub 4}, CO{sub 2}, CO) which is one of the key parameters in combustion enhancement can be also obtained. The infrared camera was also used together with special endoscope optics for fast thermal imaging of a coal-straw flame in an industrial boiler. Obtained time-resolved infrared images provided useful information for the diagnostics of the flame and fuel distribustion. The applicability of the system for gas leak detection is also demonstrated. The infrared spectrometer system with minor developments was applied for fast time-resolved exhaust gas temperature measurements performed simultaneously at the three optical ports of the exhaust duct of a marine Diesel engine and visualisation of gas flow behaviour in cylinder. (Author)

  2. Fossil Fuels: Factors of Supply Reduction and Use of The Renewable Energy As A Suitable Alternative

    OpenAIRE

    Askari Mohammad Bagher,

    2015-01-01

    In this article we will review the consumption of fossil fuels in the world. According to the exhaustible resources of fossil fuels, and the damaging effects of these fuels on the environment and nature, we introduce renewable energy sources as perfect replacement for fossil fuels.

  3. Fossil fuel combined cycle power system

    Science.gov (United States)

    Labinov, Solomon Davidovich; Armstrong, Timothy Robert; Judkins, Roddie Reagan

    2006-10-10

    A system for converting fuel energy to electricity includes a reformer for converting a higher molecular weight gas into at least one lower molecular weight gas, at least one turbine to produce electricity from expansion of at least one of the lower molecular weight gases, and at least one fuel cell. The system can further include at least one separation device for substantially dividing the lower molecular weight gases into at least two gas streams prior to the electrochemical oxidization step. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  4. Political determinants of fossil fuel pricing

    NARCIS (Netherlands)

    Van Beers, C.P.; Strand, J.

    2013-01-01

    This paper provides an empirical analysis of economic and political determinants of gasoline and diesel prices for about 200 countries over the period 1991–2010. A range of both political and economic variables are found to systematically influence fuel prices, and in ways that differ systematically

  5. The European carbon balance. Part 1: fossil fuel emissions

    NARCIS (Netherlands)

    Ciais, P.; Paris, J.D.; Marland, G.; Peylin, P.; Piao, S.L.; levin, I.; Pregger, T.; Scholz, Y.; Friedrich, R.; Rivier, L.; Houweling, S.; Schulze, E.D.

    2010-01-01

    We analyzed the magnitude, the trends and the uncertainties of fossil-fuel CO2 emissions in the European Union 25 member states (hereafter EU-25), based on emission inventories from energy-use statistics. The stability of emissions during the past decade at EU-25 scale masks decreasing trends in

  6. The preliminary study of urbanization, fossil fuels consumptions and ...

    African Journals Online (AJOL)

    STORAGESEVER

    2010-03-29

    Mar 29, 2010 ... As a result the demand of more energy in form of fossil fuels increased for domestic, industrial and transportation purpose. In this research the maximum available data of Karachi about urbanization, population and vehicles growth, industrialization, energy consumption and CO2 emissions are analyzed.

  7. Divesting Fossil Fuels : The Implications for Investment Portfolios

    NARCIS (Netherlands)

    Trinks, Arjan; Scholtens, Bert; Mulder, Machiel; Dam, Lammertjan

    2017-01-01

    Fossil fuel divestment campaigns urge investors to sell their stakes in companies that supply coal, oil, and gas. However, avoiding investments in such companies can be expected to impose a financial cost on the investor because of reduced opportunities for portfolio diversification. We compare the

  8. Rationale of Early Adopters of Fossil Fuel Divestment

    Science.gov (United States)

    Beer, Christopher Todd

    2016-01-01

    Purpose: This research uses the social science perspectives of institutions, ecological modernization and social movements to analyze the rationale used by the early-adopting universities of fossil fuel divestment in the USA. Design/methodology/approach: Through analysis of qualitative data from interviews with key actors at the universities that…

  9. Fossil Fuel and Food Tax Incidence in Ethiopia | Mekonnen ...

    African Journals Online (AJOL)

    Most studies suggest that environmental taxes are regressive, making them less attractive policy options. The general objective of this paper is to analyze and compare fossil fuel and food tax incidence in Ethiopia in different expenditure groups of households considering urban and rural parts of Ethiopia separately. We use ...

  10. Monthly, global emissions of carbon dioxide from fossil fuel consumption

    DEFF Research Database (Denmark)

    Andres, R.J.; Gregg, Jay Sterling; Losey, L.

    2011-01-01

    This paper examines available data, develops a strategy and presents a monthly, global time series of fossil-fuel carbon dioxide emissions for the years 1950–2006. This monthly time series was constructed from detailed study of monthly data from the 21 countries that account for approximately 80...

  11. The future of oil: unconventional fossil fuels.

    Science.gov (United States)

    Chew, Kenneth J

    2014-01-13

    Unconventional fossil hydrocarbons fall into two categories: resource plays and conversion-sourced hydrocarbons. Resource plays involve the production of accumulations of solid, liquid or gaseous hydro-carbons that have been generated over geological time from organic matter in source rocks. The character of these hydrocarbons may have been modified subsequently, especially in the case of solids and extra-heavy liquids. These unconventional hydrocarbons therefore comprise accumulations of hydrocarbons that are trapped in an unconventional manner and/or whose economic exploitation requires complex and technically advanced production methods. This review focuses primarily on unconventional liquid hydro-carbons. The future potential of unconventional gas, especially shale gas, is also discussed, as it is revolutionizing the energy outlook in North America and elsewhere.

  12. Fossil fuel combined cycle power generation method

    Science.gov (United States)

    Labinov, Solomon D [Knoxville, TN; Armstrong, Timothy R [Clinton, TN; Judkins, Roddie R [Knoxville, TN

    2008-10-21

    A method for converting fuel energy to electricity includes the steps of converting a higher molecular weight gas into at least one mixed gas stream of lower average molecular weight including at least a first lower molecular weight gas and a second gas, the first and second gases being different gases, wherein the first lower molecular weight gas comprises H.sub.2 and the second gas comprises CO. The mixed gas is supplied to at least one turbine to produce electricity. The mixed gas stream is divided after the turbine into a first gas stream mainly comprising H.sub.2 and a second gas stream mainly comprising CO. The first and second gas streams are then electrochemically oxidized in separate fuel cells to produce electricity. A nuclear reactor can be used to supply at least a portion of the heat the required for the chemical conversion process.

  13. Fossil-Fuel C02 Emissions Database and Exploration System

    Science.gov (United States)

    Krassovski, M.; Boden, T.; Andres, R. J.; Blasing, T. J.

    2012-12-01

    The Carbon Dioxide Information Analysis Center (CDIAC) at Oak Ridge National Laboratory (ORNL) quantifies the release of carbon from fossil-fuel use and cement production at global, regional, and national spatial scales. The CDIAC emission time series estimates are based largely on annual energy statistics published at the national level by the United Nations (UN). CDIAC has developed a relational database to house collected data and information and a web-based interface to help users worldwide identify, explore and download desired emission data. The available information is divided in two major group: time series and gridded data. The time series data is offered for global, regional and national scales. Publications containing historical energy statistics make it possible to estimate fossil fuel CO2 emissions back to 1751. Etemad et al. (1991) published a summary compilation that tabulates coal, brown coal, peat, and crude oil production by nation and year. Footnotes in the Etemad et al.(1991) publication extend the energy statistics time series back to 1751. Summary compilations of fossil fuel trade were published by Mitchell (1983, 1992, 1993, 1995). Mitchell's work tabulates solid and liquid fuel imports and exports by nation and year. These pre-1950 production and trade data were digitized and CO2 emission calculations were made following the procedures discussed in Marland and Rotty (1984) and Boden et al. (1995). The gridded data presents annual and monthly estimates. Annual data presents a time series recording 1° latitude by 1° longitude CO2 emissions in units of million metric tons of carbon per year from anthropogenic sources for 1751-2008. The monthly, fossil-fuel CO2 emissions estimates from 1950-2008 provided in this database are derived from time series of global, regional, and national fossil-fuel CO2 emissions (Boden et al. 2011), the references therein, and the methodology described in Andres et al. (2011). The data accessible here take these

  14. CAUSAL RELATIONSHIP BETWEEN FOSSIL FUEL CONSUMPTION AND ECONOMIC GROWTH IN JAPAN: A MULTIVARIATE APPROACH

    Directory of Open Access Journals (Sweden)

    Hazuki Ishida

    2013-01-01

    Full Text Available This paper explores whether Japanese economy can continue to grow without extensive dependence on fossil fuels. The paper conducts time series analysis using a multivariate model of fossil fuels, non-fossil energy, labor, stock and GDP to investigate the relationship between fossil fuel consumption and economic growth in Japan. The results of cointegration tests indicate long-run relationships among the variables. Using a vector error-correction model, the study reveals bidirectional causality between fossil fuels and GDP. The results also show that there is no causal relationship between non-fossil energy and GDP. The results of cointegration analysis, Granger causality tests, and variance decomposition analysis imply that non-fossil energy may not necessarily be able to play the role of fossil fuels. Japan cannot seem to realize both continuous economic growth and the departure from dependence on fossil fuels. Hence, growth-oriented macroeconomic policies should be re-examined.

  15. 76 FR 3517 - Standards of Performance for Fossil-Fuel-Fired, Electric Utility, Industrial-Commercial...

    Science.gov (United States)

    2011-01-20

    ... AGENCY 40 CFR Part 60 RIN 2060-AQ46 Standards of Performance for Fossil-Fuel-Fired, Electric Utility... limited to, the following: Category NAICS \\1\\ Examples of regulated entities Industry 221112 Fossil fuel-fired electric utility steam generating units. Federal Government 22112 Fossil fuel-fired electric...

  16. 75 FR 66008 - Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major...

    Science.gov (United States)

    2010-10-27

    ... Parts 433 and 435 RIN 1904-AB96 Fossil Fuel-Generated Energy Consumption Reduction for New Federal... proposed rulemaking (NOPR) regarding the fossil fuel- generated energy consumption ] requirements for new... regarding the fossil fuel-generated energy consumption requirements for new Federal buildings and major...

  17. 75 FR 63404 - Fossil Fuel-Generated Energy Consumption Reduction for New Federal Buildings and Major...

    Science.gov (United States)

    2010-10-15

    ...; ] DEPARTMENT OF ENERGY 10 CFR Parts 433 and 435 RIN 1904-AB96 Fossil Fuel-Generated Energy Consumption... address the reduction of fossil fuel-generated energy consumption in new Federal buildings and Federal... they believe meeting the full fossil fuel-generated energy consumption reduction level is technically...

  18. The geographical distribution of fossil fuels unused when limiting global warming to 2 °C

    Science.gov (United States)

    McGlade, Christophe; Ekins, Paul

    2015-01-01

    Policy makers have generally agreed that the average global temperature rise caused by greenhouse gas emissions should not exceed 2 °C above the average global temperature of pre-industrial times. It has been estimated that to have at least a 50 per cent chance of keeping warming below 2 °C throughout the twenty-first century, the cumulative carbon emissions between 2011 and 2050 need to be limited to around 1,100 gigatonnes of carbon dioxide (Gt CO2). However, the greenhouse gas emissions contained in present estimates of global fossil fuel reserves are around three times higher than this, and so the unabated use of all current fossil fuel reserves is incompatible with a warming limit of 2 °C. Here we use a single integrated assessment model that contains estimates of the quantities, locations and nature of the world's oil, gas and coal reserves and resources, and which is shown to be consistent with a wide variety of modelling approaches with different assumptions, to explore the implications of this emissions limit for fossil fuel production in different regions. Our results suggest that, globally, a third of oil reserves, half of gas reserves and over 80 per cent of current coal reserves should remain unused from 2010 to 2050 in order to meet the target of 2 °C. We show that development of resources in the Arctic and any increase in unconventional oil production are incommensurate with efforts to limit average global warming to 2 °C. Our results show that policy makers' instincts to exploit rapidly and completely their territorial fossil fuels are, in aggregate, inconsistent with their commitments to this temperature limit. Implementation of this policy commitment would also render unnecessary continued substantial expenditure on fossil fuel exploration, because any new discoveries could not lead to increased aggregate production.

  19. US fossil fuel technologies for Thailand

    Energy Technology Data Exchange (ETDEWEB)

    Buehring, W.A.; Dials, G.E.; Gillette, J.L.; Szpunar, C.B.; Traczyk, P.A.

    1990-10-01

    The US Department of Energy has been encouraging other countries to consider US coal and coal technologies in meeting their future energy needs. Thailand is one of three developing countries determined to be a potentially favorable market for such exports. This report briefly profiles Thailand with respect to population, employment, energy infrastructure and policies, as well as financial, economic, and trade issues. Thailand is shifting from a traditionally agrarian economy to one based more strongly on light manufacturing and will therefore require increased energy resources that are reliable and flexible in responding to anticipated growth. Thailand has extensive lignite deposits that could fuel a variety of coal-based technologies. Atmospheric fluidized-bed combustors could utilize this resource and still permit Thailand to meet emission standards for sulfur dioxide. This option also lends itself to small-scale applications suitable for private-sector power generation. Slagging combustors and coal-water mixtures also appear to have potential. Both new construction and refurbishment of existing plants are planned. 18 refs., 3 figs., 7 tabs.

  20. Fossil fuels in a sustainable energy future

    Energy Technology Data Exchange (ETDEWEB)

    Bechtel, T.F. [Dept. of Energy, Morgantown, WV (United States)

    1995-12-01

    The coal industry in the United States has become a world leader in safety, productivity, and environmental protection in the mining of coal. The {open_quotes}pick-and-shovel{close_quotes} miner with mangled limbs and black lung disease has been replaced by the highly skilled technicians that lead the world in tons per man-hour. The gob piles, polluted streams, and scared land are a thing of the past. The complementary efforts of the DOE and EPRI-funded programs in coal utilization R&D and the Clean Coal Technology Program commercial demonstrations, have positioned the power generation industry to utilize coal in a way that doesn`t pollute the air or water, keeps electrical power costs low, and avoids the mountains of waste material. This paper reviews the potential for advanced coal utilization technologies in new power generation applications as well as the repowering of existing plants to increase their output, raise their efficiency, and reduce pollution. It demonstrates the potential for these advanced coal-fueled plants to play a complementary role in future planning with the natural gas and oil fired units currently favored in the market place. The status of the US program to demonstrate these technologies at commercial scale is reviewed in some detail.

  1. Brown Clouds over South Asia: Biomass or Fossil Fuel Combustion?

    Science.gov (United States)

    Gustafsson, Örjan; Kruså, Martin; Zencak, Zdenek; Sheesley, Rebecca J.; Granat, Lennart; Engström, Erik; Praveen, P. S.; Rao, P. S. P.; Leck, Caroline; Rodhe, Henning

    2009-01-01

    Carbonaceous aerosols cause strong atmospheric heating and large surface cooling that is as important to South Asian climate forcing as greenhouse gases, yet the aerosol sources are poorly understood. Emission inventory models suggest that biofuel burning accounts for 50 to 90 % of emissions, whereas the elemental composition of ambient aerosols points to fossil fuel combustion. We used radiocarbon measurements of winter monsoon aerosols from western India and the Indian Ocean to determine that biomass combustion produced two-thirds of the bulk carbonaceous aerosols, as well as one-half and two-thirds of two black carbon subfractions, respectively. These constraints show that both biomass combustion (such as residential cooking and agricultural burning) and fossil fuel combustion should be targeted to mitigate climate effects and improve air quality.

  2. An oxy-hydrocarbon model of fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Fred D. Lang; Tom Canning [Exergetic Systems, Inc., San Rafael, CA (United States)

    2007-09-15

    This paper asserts a new method of analyzing fossil fuels, useful for sorting coals into well-defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multivariant approach for describing the lower ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high-energy ranks. In addition, for a few special cases, multiple low and high ranks are also well described by the multivariant approach. As useful as these techniques are for analyzing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems' Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time.

  3. Microbial Biotechnology 2020; microbiology of fossil fuel resources.

    Science.gov (United States)

    Head, Ian M; Gray, Neil D

    2016-09-01

    This roadmap examines the future of microbiology research and technology in fossil fuel energy recovery. Globally, the human population will be reliant on fossil fuels for energy and chemical feedstocks for at least the medium term. Microbiology is already important in many areas relevant to both upstream and downstream activities in the oil industry. However, the discipline has struggled for recognition in a world dominated by geophysicists and engineers despite widely known but still poorly understood microbially mediated processes e.g. reservoir biodegradation, reservoir souring and control, microbial enhanced oil recovery. The role of microbiology is even less understood in developing industries such as shale gas recovery by fracking or carbon capture by geological storage. In the future, innovative biotechnologies may offer new routes to reduced emissions pathways especially when applied to the vast unconventional heavy oil resources formed, paradoxically, from microbial activities in the geological past. However, despite this potential, recent low oil prices may make industry funding hard to come by and recruitment of microbiologists by the oil and gas industry may not be a high priority. With regards to public funded research and the imperative for cheap secure energy for economic growth in a growing world population, there are signs of inherent conflicts between policies aimed at a low carbon future using renewable technologies and policies which encourage technologies which maximize recovery from our conventional and unconventional fossil fuel assets. © 2016 The Authors. Microbial Biotechnology published by John Wiley & Sons Ltd and Society for Applied Microbiology.

  4. Water interaction with laboratory-simulated fossil fuel combustion particles.

    Science.gov (United States)

    Popovicheva, O B; Kireeva, E D; Shonija, N K; Khokhlova, T D

    2009-10-01

    To clarify the impact of fossil fuel combustion particles' composition on their capacity to take up water, we apply a laboratory approach in which the method of deposition of compounds, identified in the particulate coverage of diesel and aircraft engine soot particles, is developed. It is found that near-monolayer organic/inorganic coverage of the soot particles may be represented by three groups of fossil fuel combustion-derived particulate matter with respect to their Hansh's coefficients related to hydrophilic properties. Water adsorption measurements show that nonpolar organics (aliphatic and aromatic hydrocarbons) lead to hydrophobization of the soot surface. Acidic properties of organic compounds such as those of oxidized PAHs, ethers, ketones, aromatic, and aliphatic acids are related to higher water uptake, whereas inorganic acids and ionic compounds such as salts of organic acids are shown to be responsible for soot hydrophilization. This finding allows us to quantify the role of the chemical identity of soot surface compounds in water uptake and the water interaction with fossil fuel combustion particles in the humid atmosphere.

  5. Evaluation of conventional power systems. [emphasizing fossil fuels and nuclear energy

    Science.gov (United States)

    Smith, K. R.; Weyant, J.; Holdren, J. P.

    1975-01-01

    The technical, economic, and environmental characteristics of (thermal, nonsolar) electric power plants are reviewed. The fuel cycle, from extraction of new fuel to final waste management, is included. Emphasis is placed on the fossil fuel and nuclear technologies.

  6. PERSPECTIVE: Keeping a closer eye on fossil fuel CO2

    Science.gov (United States)

    Nelson, Peter F.

    2009-12-01

    all have a major influence on progress to an international agreement. It is important that the political challenges are not underestimated. Long-term observers of the negotiations necessary for global agreements (Inman 2009) are pessimistic about the chances for success at COP15, and argue that agreements between smaller groups of countries may be more effective. China and other developing countries clearly expect greater emission cuts by developed nations as a condition for a successful deal (Pan 2009). Conversely, the constraints on US climate policies are considerable, notably those imposed by fears that an international agreement that does not include equitable emission control measures for developing countries like China and India, will compromise the agreement and reduce its effectiveness (Skodvin and Andresen 2009). In this context the need for earlier, and more reliable, information on emissions is a high priority. Myhre and coworkers (Myhre et al 2009) provide an efficient method for calculating global carbon dioxide emissions from fossil fuel combustion by combining industry statistics with data from the Carbon Dioxide Information Analysis Center (CDIAC; http://cdiac.ornl.gov/). Recent analyses of carbon dioxide emission data show a worrying acceleration in emissions, beyond even the most extreme IPCC projections, but are based largely on the CDIAC which gives information about emissions released two to three years before real time (Canadell et al 2007, Raupach et al 2007). The approach used by Myhre et al (2009) uses BP annual statistics of fossil fuel consumption and has a much shorter lag, of the order of six months. Of significant concern is that their analysis of the data also reveals that the recent strong increase in fossil fuel CO2 is largely driven by an increase in emissions from coal, most significantly in China. By contrast, emissions from oil and gas continue to follow longer-term historical trends. Earlier and accurate data on CO2 emissions is

  7. Biomass - alternative renewable energy source to the fossil fuels

    Directory of Open Access Journals (Sweden)

    Koruba Dorota

    2017-01-01

    Full Text Available The article presents the fossil fuels combustion effects in terms of the dangers of increasing CO2 concentration in the atmosphere. Based on the bibliography review the negative impact of increased carbon dioxide concentration on the human population is shown in the area of the external environment, particularly in terms of the air pollution and especially the impact on human health. The paper presents biomass as the renewable energy alternative source to fossil fuels which combustion gives a neutral CO2 emissions and therefore should be the main carrier of primary energy in Poland. The paper presents the combustion heat results and humidity of selected dry wood pellets (pellets straw, energy-crop willow pellets, sawdust pellets, dried sewage sludge from two sewage treatment plants of the Holly Cross province pointing their energy potential. In connection with the results analysis of these studies the standard requirements were discussed (EN 14918:2010 “Solid bio-fuels-determination of calorific value” regarding the basic parameters determining the biomass energy value (combustion heat, humidity.

  8. Revisiting global fossil fuel and biofuel emissions of ethane

    Science.gov (United States)

    Tzompa-Sosa, Z. A.; Mahieu, E.; Franco, B.; Keller, C. A.; Turner, A. J.; Helmig, D.; Fried, A.; Richter, D.; Weibring, P.; Walega, J.; Yacovitch, T. I.; Herndon, S. C.; Blake, D. R.; Hase, F.; Hannigan, J. W.; Conway, S.; Strong, K.; Schneider, M.; Fischer, E. V.

    2017-02-01

    Recent measurements over the Northern Hemisphere indicate that the long-term decline in the atmospheric burden of ethane (C2H6) has ended and the abundance increased dramatically between 2010 and 2014. The rise in C2H6 atmospheric abundances has been attributed to oil and natural gas extraction in North America. Existing global C2H6 emission inventories are based on outdated activity maps that do not account for current oil and natural gas exploitation regions. We present an updated global C2H6 emission inventory based on 2010 satellite-derived CH4 fluxes with adjusted C2H6 emissions over the U.S. from the National Emission Inventory (NEI 2011). We contrast our global 2010 C2H6 emission inventory with one developed for 2001. The C2H6 difference between global anthropogenic emissions is subtle (7.9 versus 7.2 Tg yr-1), but the spatial distribution of the emissions is distinct. In the 2010 C2H6 inventory, fossil fuel sources in the Northern Hemisphere represent half of global C2H6 emissions and 95% of global fossil fuel emissions. Over the U.S., unadjusted NEI 2011 C2H6 emissions produce mixing ratios that are 14-50% of those observed by aircraft observations (2008-2014). When the NEI 2011 C2H6 emission totals are scaled by a factor of 1.4, the Goddard Earth Observing System Chem model largely reproduces a regional suite of observations, with the exception of the central U.S., where it continues to underpredict observed mixing ratios in the lower troposphere. We estimate monthly mean contributions of fossil fuel C2H6 emissions to ozone and peroxyacetyl nitrate surface mixing ratios over North America of 1% and 8%, respectively.

  9. Water treatment for fossil fuel power generation - technology status report

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2006-02-07

    This technology status report focuses on the use of water treatment technology in fossil fuel power plants. The use of polymeric ion exchange resins for deionization of water, the currently preferred use of ion exchange for economically treating water containing low dissolved salts, the use of low pressure high-flux membranes, membrane microfiltration, and reverse osmosis are discussed. Details are given of the benefits of the technologies, water use at power plants, the current status of water treatment technologies, and the potential for future developments, along with power plant market trends and potentials, worldwide developments, and UK capabilities in water treatment plant design and manufacturing.

  10. Energy Efficiency Indicators for Public Electricity Production from Fossil Fuels

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2008-07-01

    This paper presents a set of indicators that are used to analyse the energy efficiency of electricity production from fossil fuels on a global level and for a number of key countries and regions. The analysis is based on IEA statistics and includes public electricity plants and public CHP plants. Electricity production by autoproducers is not included and represents less than 6% of global electricity production. However, the share of autoproducers is significant in certain countries, particularly in Europe. Austria, Finland, Luxembourg, the Netherlands and Spain all have a share of electricity production from autoproducers that is more than twice the global average.

  11. Comparing the social costs of biofuels and fossil fuels: A case study of Vietnam

    NARCIS (Netherlands)

    Thanh, le L.; Ierland, van E.C.; Zhu, X.; Wesseler, J.H.H.; Ngo, G.

    2013-01-01

    Biofuel substitution for fossil fuels has been recommended in the literature and promoted in many countries; however, there are concerns about its economic viability. In this paper we focus on the cost-effectiveness of fuels, i.e., we compare the social costs of biofuels and fossil fuels for a

  12. Direct and Indirect Use of Fossil Fuels in Farming: Cost of Fuel-price Rise for Indian Agriculture.

    OpenAIRE

    Anand, Mukesh

    2014-01-01

    A hornet's nest could be an apt simile for fossil fuel prices in India. Over years a policy maze has evolved around it, with sharply diverging influence on disparate constituencies. We estimate the increase in total cost of farming as a multiple of direct input costs of fossil fuels in farming. Over the period between 1990-1 and 2010-1, direct use of fossil fuels on farms has risen and there is also increasing indirect use of fossil fuels for non-energy purposes. Consequently, for Indian agri...

  13. OVERVIEW OF THE ROMANIAN FOSSIL FUEL MARKET BETWEEN 2002 AND 2012

    OpenAIRE

    ALINA ZAHARIA

    2015-01-01

    In a context in which the energy needs seems to increase fast and the limited stocks of fossil fuels can generate negative impacts on human society, biodiversity and environment, the policy makers proposed several economic models for achieving sustainable development, like green economy, which appears to promote the necessity of decreasing fossil fuel consumption and of increasing energy savings. This paper aims to emphasize the evolution of fossil fuel market, and the electricity...

  14. Krakow clean fossil fuels and energy efficiency project

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.A.; Pierce, B.L. [Brookhaven National Lab., Upton, NY (United States)

    1995-11-01

    The Support for Eastern European Democracy (SEED) Act of 1989 directed the U.S. Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. This project is being implemented in the city of Krakow as the `Krakow Clean Fossil Fuels and Energy Efficiency Project.` Funding is provided through the U.S. Agency for International Development (AID). The project is being conducted in a manner that can be generalized to all of Poland and to the rest of Eastern Europe. The historic city of Krakow has a population of 750,000. Almost half of the heating energy used in Krakow is supplied by low-efficiency boilerhouses and home coal stoves. Within the town, there are more than 1,300 local boilerhouses and 100,000 home stoves. These are collectively referred to as the `low emission sources` and they are the primary sources of particulates and hydrocarbon emissions in the city and major contributors of sulfur dioxide and carbon monoxide.

  15. An oxy-hydrocarbon model of fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Tom Canning; Fred D. Lang [Electricity Supply Board, Dublin (Ireland)

    2007-07-01

    This paper asserts a new method of analysing fossil fuels, useful for sorting coals into well defined categories and for the identification of outlying ultimate analysis data. It describes a series of techniques starting with a new multi-variant approach for describing the lower Ranks of coal, progressing to a classical, but modified, single-variant approach for the volatile and high energy Ranks. In addition, for a few special cases, multiple low and high Ranks are also well described by the multivariant approach. As useful as these techniques are for analysing fuel chemistry in the laboratory arena, this work was initiated in support of Exergetic Systems' Input/Loss Method. At commercial coal-fired power plants, Input/Loss allows the determination of fuel chemistry based on combustion effluents. The methods presented allow equations to be developed independent of combustion stoichiometrics, which improve Input/Loss accuracy in determining fuel chemistry on-line and in real time. 17 refs., 9 figs., 7 tabs.

  16. Sensitivity analysis of parameters affecting carbon footprint of fossil fuel power plants based on life cycle assessment scenarios

    Directory of Open Access Journals (Sweden)

    F. Dalir

    2017-12-01

    Full Text Available In this study a pseudo comprehensive carbon footprint model for fossil fuel power plants is presented. Parameters which their effects are considered in this study include: plant type, fuel type, fuel transmission type, internal consumption of the plant, degradation, site ambient condition, transmission and distribution losses. Investigating internal consumption, degradation and site ambient condition effect on carbon footprint assessment of fossil fuel power plant is the specific feature of the proposed model. To evaluate the model, a sensitivity analysis is performed under different scenarios covering all possible choices for investigated parameters. The results show that carbon footprint of fossil fuel electrical energy that is produced, transmitted and distributed, varies from 321 g CO2 eq/kWh to 980 g CO2 equivalent /kWh. Carbon footprint of combined cycle with natural gas as main fuel is the minimum carbon footprint. Other factors can also cause indicative variation. Fuel type causes a variation of 28%. Ambient condition may change the result up to 13%. Transmission makes the carbon footprint larger by 4%. Internal consumption and degradation influence the result by 2 and 2.5%, respectively. Therefore, to minimize the carbon footprint of fossil fuel electricity, it is recommended to construct natural gas ignited combined cycles in low lands where the temperature is low and relative humidity is high. And the internal consumption is as least as possible and the maintenance and overhaul is as regular as possible.

  17. Fossil fuel derivatives with reduced carbon. Phase I final report

    Energy Technology Data Exchange (ETDEWEB)

    Kennel, E.B.; Zondlo, J.W.; Cessna, T.J.

    1999-06-30

    This project involves the simultaneous production of clean fossil fuel derivatives with reduced carbon and sulfur, along with value-added carbon nanofibers. This can be accomplished because the nanofiber production process removes carbon via a catalyzed pyrolysis reaction, which also has the effect of removing 99.9% of the sulfur, which is trapped in the nanofibers. The reaction is mildly endothermic, meaning that net energy production with real reductions in greenhouse emissions are possible. In Phase I research, the feasibility of generating clean fossil fuel derivatives with reduced carbon was demonstrated by the successful design, construction and operation of a facility capable of utilizing coal as well as natural gas as an inlet feedstock. In the case of coal, for example, reductions in CO{sub 2} emissions can be as much as 70% (normalized according to kilowatts produced), with the majority of carbon safely sequestered in the form of carbon nanofibers or coke. Both of these products are value-added commodities, indicating that low-emission coal fuel can be done at a profit rather than a loss as is the case with most clean-up schemes. The main results of this project were as follows: (1) It was shown that the nanofiber production process produces hydrogen as a byproduct. (2) The hydrogen, or hydrogen-rich hydrocarbon mixture can be consumed with net release of enthalpy. (3) The greenhouse gas emissions from both coal and natural gas are significantly reduced. Because coal consumption also creates coke, the carbon emission can be reduced by 75% per kilowatt-hour of power produced.

  18. Hydrogen Separation Membranes for Vision 21 Fossil Fuel Plants

    Energy Technology Data Exchange (ETDEWEB)

    Roark, Shane E.; Mackay, Richard; Sammells, Anthony F.

    2001-11-06

    Eltron Research and team members CoorsTek, McDermott Technology, Sued Chemie, Argonne National Laboratory, and Oak Ridge National Laboratory are developing an environmentally benign, inexpensive, and efficient method for separating hydrogen from gas mixtures produced during industrial processes, such as coal gasification. This objective is being pursued using dense membranes based in part on Eltron-patented ceramic materials with a demonstrated ability for proton and electron conduction. The technical goals are being addressed by modifying single-phase and composite membrane composition and microstructure to maximize proton and electron conductivity without loss of material stability. Ultimately, these materials must enable hydrogen separation at practical rates under ambient and high-pressure conditions, without deactivation in the presence of feedstream components such as carbon dioxide, water, and sulfur. This project was motivated by the Department of Energy (DOE) National Energy Technology Laboratory (NETL) Vision 21 initiative which seeks to economically eliminate environmental concerns associated with the use of fossil fuels. The proposed technology addresses the DOE Vision 21 initiative in two ways. First, this process offers a relatively inexpensive solution for pure hydrogen separation that can be easily incorporated into Vision 21 fossil fuel plants. Second, this process could reduce the cost of hydrogen, which is a clean burning fuel under increasing demand as supporting technologies are developed for hydrogen utilization and storage. Additional motivation for this project arises from the potential of this technology for other applications. By appropriately changing the catalysts coupled with the membrane, essentially the same system can be used to facilitate alkane dehydrogenation and coupling, aromatics processing, and hydrogen sulfide decomposition.

  19. Applying Thermodynamics to Fossil Fuels: Heats of Combustion from Elemental Compositions.

    Science.gov (United States)

    Lloyd, William G.; Davenport, Derek A.

    1980-01-01

    Discussed are the calculations of heats of combustions of some selected fossil fuel compounds such as some foreign shale oils and United States coals. Heating values for coal- and petroleum-derived fuel oils are also presented. (HM)

  20. Possible future environmental issues for fossil fuel technologies. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Attaway, L.D.

    1979-07-01

    The work reported here was carried out for the Department of Energy's Office of Fossil Energy to identify and assess 15 to 20 major environmental issues likely to affect the implementation of fossil energy technologies between 1985 and 2000. The energy technologies specifically addressed are: oil recovery and processing; gas recovery and processing; coal liquefaction; coal gasification (surface); in situ coal gasification; direct coal combustion; advanced power systems; magnetohydrodynamics; surface oil shale retorting; and true and modified in situ oil shale retorting. Environmental analysis of these technologies included, in addition to the main processing steps, the complete fuel cycle from resource extraction to end use. The 16 environmental issues identified as those most likely for future regulatory actions and the main features of, and the possible regulatory actions associated with, each are as follows: disposal of solid waste from coal conversion and combustion technologies; water consumption by coal and oil shale conversion technologies; siting of coal conversion facilities; the carbon dioxide greenhouse effect; emission of polycyclic organic matter (POM); impacts of outer continental shelf (OCS) oil development; emission of trace elements; groundwater contamination; liquefied natural gas (LNG), safety and environmental factors; underground coal mining - health and safety; fugitive emissions from coal gasification and liquefaction - health and safety; boomtown effects; emission of fine particulates from coal, oil and oil shale technologies; emission of radioactivity from the mining and conversion of coal; emission of nitrogn oxides; and land disturbance from surface mining. (LTN)

  1. Krakow Clean Fossil Fuels and Energy Efficiency Program

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.; Pierce, B.; Krishna, C.R.

    1992-09-01

    The Support for Eastern European Democracy (SEED) Act of 1989 directed the US Department of Energy (DOE) to undertake an equipment assessment project aimed at developing the capability within Poland to manufacture or modify industrial-scale combustion equipment to utilize fossil fuels cleanly. The project is being conducted in three phases. In Phase I, testing and analytical activities will establish the current level of emissions from existing equipment and operating practices, and will provide estimates of the costs and emission reductions of various options. Phase II consists of a series of public meetings in both Poland and the United States to present the results of Phase I activities. In Phase III, DOE will issue a solicitation for Polish/US joint ventures to perform commercial feasibility studies for the use of US technology in one or more of the areas under consideration. This report provides interim results from Phase 1.

  2. Aromatic nitrogen compounds in fossil fuels: a potential hazard

    Energy Technology Data Exchange (ETDEWEB)

    Ho, C H; Clark, B R; Guerin, M R; Ma, C Y; Rao, T K

    1979-01-01

    To achieve energy independence in the United States, converting coal to oil or extracting oil from shale will be required. Before commercial scale fossil fuel conversion facilities become a reality, chemical and biological studies of currently available synfuel samples derived from coal or shale are urgently needed in order to determine what the potential health problems, such as from occupational exposure, might be. Aromatic nitrogen compounds such as basic aza-arenes, neutral aza-arenes, and aromatic amines are considered environmentally important and several members of these classes of compounds possess biological activity. For example, dibenz(a,h)acridine, 7 H-dibenzo(c,g)carbazole, and 2-naphthylamine, are well known as carcinogens. The methods used to isolate the basic aromatic nitrogen compounds and neutral aza-arenes from one shale oil and one coal-derived oil are discussed. The mutagenic activities of these fractions, based on the Ames Salmonella typhimurium test, are compared.

  3. On Corporate Accountability: Lead, Asbestos, and Fossil Fuel Lawsuits.

    Science.gov (United States)

    Shearer, Christine

    2015-08-01

    This paper examines the use of lawsuits against three industries that were eventually found to be selling products damaging to human heath and the environment: lead paint, asbestos, and fossil fuels. These industries are similar in that some companies tried to hide or distort information showing their products were harmful. Common law claims were eventually filed to hold the corporations accountable and compensate the injured. This paper considers the important role the lawsuits played in helping establish some accountability for the industries while also noting the limitations of the lawsuits. It will be argued that the lawsuits helped create pressure for government regulation of the industries' products but were less successful at securing compensation for the injured. Thus, the common law claims strengthened and supported administrative regulation and the adoption of industry alternatives more than they provided a means of legal redress. © The Author(s) 2015.

  4. Progress performance report of clean uses of fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    1992-09-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled ``Clean Uses of Fossil Fuels.`` was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  5. Progress performance report of clean uses of fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Todd, Jr., Lee T.; Boggess, Ronald J.; Carson, Ronald J.; Falkenberg, Virginia P.; Flanagan, Patrick; Hettinger, Jr., William P.; Kimel, Kris; Kupchella, Charles E.; Magid, Lee J.; McLaughlin, Barbara; Royster, Wimberly C.; Streepey, Judi L.; Wells, James H.; Stencel, John; Derbyshire, Frank J.; Hanley, Thomas R.; Magid, Lee J.; McEllistrem, Marc T.; Riley, John T.; Steffen, Joseph M.

    1992-01-01

    A one-year USDOE/EPSCOR Traineeship Grant, entitled Clean Uses of Fossil Fuels.'' was awarded to the Kentucky EPSCoR Committee in September 1991 and administered through the the DOE/EPSCoR Subcommittee. Ten Traineeships were awarded to doctoral students who are enrolled or accepted into Graduate Programs at either the University of Kentucky or the University of Louisville. The disciplines of these students include Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for a statewide proposal solicitation and to award the Traineeships are presented. The review panel and Kentucky DOE/EPSCoR Subcommittee involved in awarding the Traineeships are described. A summary of the proposed research to be performed within these awards is presented, along with a description of the qualifications of the faculty and students who proposed projects. Future efforts to increase participation in Traineeship proposals for the succeeding funding period are outlined.

  6. Heat planning for fossil-fuel-free district heating areas with extensive end-use heat savings

    DEFF Research Database (Denmark)

    Harrestrup, Maria; Svendsen, S.

    2014-01-01

    is a theoretical investigation of the district heating system in the Copenhagen area, in which heat conservation is related to the heat supply in buildings from an economic perspective. Supplying the existing building stock from low-temperature energy resources, e.g. geothermal heat, might lead to oversized......The Danish government plans to make the Danish energy system to be completely free of fossil fuels by 2050 and that by 2035 the energy supply for buildings and electricity should be entirely based on renewable energy sources. To become independent from fossil fuels, it is necessary to reduce...... the energy consumption of the existing building stock, increase energy efficiency, and convert the present heat supply from fossil fuels to renewable energy sources. District heating is a sustainable way of providing space heating and domestic hot water to buildings in densely populated areas. This paper...

  7. Fossil Fuels. A Supplement to the "Science 100, 101" Curriculum Guide. Curriculum Support Series.

    Science.gov (United States)

    Soprovich, William, Comp.

    When the fossil fuels unit was first designed for Science 101 (the currently approved provincial guide for grade 10 science in Manitoba), Canadian support materials were very limited. Since students are asked to interpret data concerning energy consumption and sources for certain fossil fuels, the need for appropriate Canadian data became obvious.…

  8. Criteria for solid recovered fuels as a substitute for fossil fuels--a review.

    Science.gov (United States)

    Beckmann, Michael; Pohl, Martin; Bernhardt, Daniel; Gebauer, Kathrin

    2012-04-01

    The waste treatment, particularly the thermal treatment of waste has changed fundamentally in the last 20 years, i.e. from facilities solely dedicated to the thermal treatment of waste to facilities, which in addition to that ensure the safe plant operation and fulfill very ambitious criteria regarding emission reduction, resource recovery and energy efficiency as well. Therefore this contributes to the economic use of raw materials and due to the energy recovered from waste also to the energy provision. The development described had the consequence that waste and solid recovered fuels (SRF) has to be evaluated based on fuel criteria as well. Fossil fuels - coal, crude oil, natural gas etc. have been extensively investigated due to their application in plants for energy conversion and also due to their use in the primary industry. Thereby depending on the respective processes, criteria on fuel technical properties can be derived. The methods for engineering analysis of regular fuels (fossil fuels) can be transferred only partially to SRF. For this reason methods are being developed or adapted to current analytical methods for the characterization of SRF. In this paper the possibilities of the energetic utilization of SRF and the characterization of SRF before and during the energetic utilization will be discussed.

  9. Replacing fossil diesel by biodiesel fuel: expected impact on health.

    Science.gov (United States)

    Hutter, Hans-Peter; Kundi, Michael; Moshammer, Hanns; Shelton, Janie; Krüger, Bernd; Schicker, Irene; Wallner, Peter

    2015-01-01

    Biofuels have become an alternative to fossil fuel, but consequences on human health from changes to emissions compositions are not well understood. By combining information on composition of vehicle exhaust, dispersion models, and relationship between exposure to air contaminants and health, the authors determined expected mortality outcomes in 2 scenarios: a blend of 10% biodiesel and 90% standard diesel (B10) and biodiesel only (B100), for a rural and an urban environment. Vehicle exhaust for both fuel compositions contained lower fine particle mass but higher NO2 levels. Ambient air concentrations in scenario B10 were almost unchanged. In scenario B100, PM2.5 (particulate matter with an aerodynamic diameter <2.5 μm) levels decreased by 4-8% and NO2 levels increased 7-11%. Reduction of PM2.5 is expected to reduce mortality rate by 5 × 10(-6) and 31 × 10(-6) per year, whereas NO2 increase adds 17 × 10(-6) and 30 × 10(-6) to mortality rate for B10 and B100, respectively. Since effects of PM2.5 and NO2 are not independent, a positive net effect is possible.

  10. Identifying the European fossil fuel plumes in the atmosphere over the Northeast Atlantic Region through isotopic observations and numerical modelling

    DEFF Research Database (Denmark)

    Geels, C.; Christensen, J.H.; Hansen, A.W.

    2006-01-01

    Atmospheric transport, C-14. fossil fuel CO_2, numerical modeling, the north East Atlantic Region Udgivelsesdato: 18 August......Atmospheric transport, C-14. fossil fuel CO_2, numerical modeling, the north East Atlantic Region Udgivelsesdato: 18 August...

  11. OVERVIEW OF THE ROMANIAN FOSSIL FUEL MARKET BETWEEN 2002 AND 2012

    Directory of Open Access Journals (Sweden)

    ALINA ZAHARIA

    2015-04-01

    Full Text Available In a context in which the energy needs seems to increase fast and the limited stocks of fossil fuels can generate negative impacts on human society, biodiversity and environment, the policy makers proposed several economic models for achieving sustainable development, like green economy, which appears to promote the necessity of decreasing fossil fuel consumption and of increasing energy savings. This paper aims to emphasize the evolution of fossil fuel market, and the electricity generated from fossil fuels since 2002, and especially after 2010, when in Romania were taken some measures for implementing the principles of green economy. In order to see their effects, this research presents an historical analysis for Romania based on the data obtained from European Commission and Romanian Institute of Statistics. The results indicate decreasing trends of primary energy production and consumption, and decreasing trends of electricity generation from fossil fuels due to the more and more use of renewable and nuclear energy sources. The results highlight the need of taking more actions in the energy sector by promoting even more the renewable energy production and consumption for reducing the fossil fuel use, and by promoting, also, a more efficient use of fossil fuel resources for a sustainable future.

  12. Multiple Threats to Child Health from Fossil Fuel Combustion: Impacts of Air Pollution and Climate Change.

    Science.gov (United States)

    Perera, Frederica P

    2017-02-01

    Approaches to estimating and addressing the risk to children from fossil fuel combustion have been fragmented, tending to focus either on the toxic air emissions or on climate change. Yet developing children, and especially poor children, now bear a disproportionate burden of disease from both environmental pollution and climate change due to fossil fuel combustion. This commentary summarizes the robust scientific evidence regarding the multiple current and projected health impacts of fossil fuel combustion on the young to make the case for a holistic, child-centered energy and climate policy that addresses the full array of physical and psychosocial stressors resulting from fossil fuel pollution. The data summarized here show that by sharply reducing our dependence on fossil fuels we would achieve highly significant health and economic benefits for our children and their future. These benefits would occur immediately and also play out over the life course and potentially across generations. Going beyond the powerful scientific and economic arguments for urgent action to reduce the burning of fossil fuels is the strong moral imperative to protect our most vulnerable populations. Citation: Perera FP. 2017. Multiple threats to child health from fossil fuel combustion: impacts of air pollution and climate change. Environ Health Perspect 125:141-148; http://dx.doi.org/10.1289/EHP299.

  13. The Fossil Fuel Divestment Movement: An Ethical Dilemma for the Geosciences?

    Science.gov (United States)

    Greene, C. H.; Kammen, D. M.

    2014-12-01

    For over 200 years, fossil fuels have been the basis for an industrial revolution that has delivered a level of prosperity to modern society unimaginable during the previous 5000 years of human civilization. However, society's dependence on fossil fuels is coming to an end for two reasons. The first reason is because our fossil fuel reserves are running out, oil in this century, natural gas during the next century, and coal a few centuries later. The second reason is because fossil fuels are having a devastating impact on the habitability of our planet, disrupting our climate system and acidifying our oceans. So the question is not whether we will discontinue using fossil fuels, but rather whether we will stop using them before they do irreparable damage to the Earth's life-support systems. Within our geoscience community, climate scientists have determined that a majority of existing fossil fuel reserves must remain unburned if dangerous climate change and ocean acidification are to be avoided. In contrast, Exxon-Mobil, Shell, and other members of the fossil fuel industry are pursuing a business model that assumes all of their reserves will be burned and will not become stranded assets. Since the geosciences have had a long and mutually beneficial relationship with the fossil fuel industry, this inherent conflict between climate science and industrial interests presents an ethical dilemma for many geoscientists. This conflict is further heightened by the fossil fuel divestment movement, which is underway at over 400 college and university campuses around the world. This presentation will explore some of the ethical and financial issues being raised by the divestment movement from a geoscientist's perspective.

  14. The geographical distribution of fossil fuels unused when limiting global warming to 2 °C.

    Science.gov (United States)

    McGlade, Christophe; Ekins, Paul

    2015-01-08

    Policy makers have generally agreed that the average global temperature rise caused by greenhouse gas emissions should not exceed 2 °C above the average global temperature of pre-industrial times. It has been estimated that to have at least a 50 per cent chance of keeping warming below 2 °C throughout the twenty-first century, the cumulative carbon emissions between 2011 and 2050 need to be limited to around 1,100 gigatonnes of carbon dioxide (Gt CO2). However, the greenhouse gas emissions contained in present estimates of global fossil fuel reserves are around three times higher than this, and so the unabated use of all current fossil fuel reserves is incompatible with a warming limit of 2 °C. Here we use a single integrated assessment model that contains estimates of the quantities, locations and nature of the world's oil, gas and coal reserves and resources, and which is shown to be consistent with a wide variety of modelling approaches with different assumptions, to explore the implications of this emissions limit for fossil fuel production in different regions. Our results suggest that, globally, a third of oil reserves, half of gas reserves and over 80 per cent of current coal reserves should remain unused from 2010 to 2050 in order to meet the target of 2 °C. We show that development of resources in the Arctic and any increase in unconventional oil production are incommensurate with efforts to limit average global warming to 2 °C. Our results show that policy makers' instincts to exploit rapidly and completely their territorial fossil fuels are, in aggregate, inconsistent with their commitments to this temperature limit. Implementation of this policy commitment would also render unnecessary continued substantial expenditure on fossil fuel exploration, because any new discoveries could not lead to increased aggregate production.

  15. Effects of New Fossil Fuel Developments on the Possibilities of Meeting 2C Scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Meindertsma, W.; Blok, K.

    2012-12-15

    Recent years have seen an increasing activity in developing new fossil fuel production capacity. This includes unconventional fossil fuels, such as tar sands and shale gas, fossil fuels from remote locations, and fossil fuels with a very large increase in production in the near future. In this report, the impact of such developments on our ability to mitigate climate change is investigated. Our inventory shows that the new fossil fuel developments currently underway consist of 29,400 billion cubic meters of natural gas, 260,000 million barrels of oil and 49,600 million tonnes of coal. The development of these new fossil fuels would result in emissions of 300 billion tonnes of CO2 -equivalent (CO2e) from 2012 until 2050. Until 2050, a 'carbon budget' of 1550 billion tonnes CO2e is still available if we want to of keep global warming below 2C with a 50% probability. For a 75% probability to stay below 2C this budget is only 1050 billion tonnes CO2e. So, the new fossil fuel developments identified in this report consume 20-33% of the remaining carbon budget until 2050. In a scenario where the new fossil fuels are developed, we need to embark on a rapid emission reductions pathway at the latest in 2019 in order to meet the 50% probability carbon budget. Avoiding the development of new fossil fuels will give us until 2025 to start further rapid emission reductions. These calculations are based on the assumption that the maximum emission reduction rate is 4% per year and that the maximum change in emission trend is 0.5 percentage point per year. The starting year for rapid emission reductions depends on the choice of these parameters. A sensitivity analysis shows that, in all cases, refraining from new fossil fuel development allows for a delay of 5 to 8 years before we should embark on a rapid emission reduction pathway. The high investments required for developing new fossil fuels lead to a lock in effect; once developed, these fossil fuels need to be

  16. Climate agreements: Optimal taxation of fossil fuels and the distribution of costs and benefits across countries

    Energy Technology Data Exchange (ETDEWEB)

    Holtsmark, Bjart

    1997-12-31

    This report analyses the response of governments to a climate agreement that commits them to reduce their CO{sub 2} emissions. It develops a formula for optimal taxation of fossil fuels in open economies subject both to an emission constraint and a public budget constraint. The theory captures how national governments` behaviours are sensitive to the size of the benefits from revenue recycling and how these benefits adjust the distribution of abatement costs. The empirical part of the report illustrates the significance of the participating countries` current and potential fossil fuel taxation schemes and their roles in the fossil fuel markets. 23 refs., 11 figs., 2 tabs.

  17. Fossil fuel-fired power generation. Case studies of recently constructed coal- and gas-fired plants

    Energy Technology Data Exchange (ETDEWEB)

    Henderson, C. [IEA Clean Coal Centre, London (United Kingdom)

    2007-10-23

    To meet future energy demand growth and replace older or inefficient units, a large number of fossil fuel-fired plants will be required to be built worldwide in the next decade. Yet CO{sub 2} emissions from fossil-fired power generation are a major contributor to climate change. As a result, new plants must be designed and operated at highest efficiency both to reduce CO{sub 2} emissions and to facilitate deployment of CO{sub 2} capture and storage in the future. The series of case studies in this report, which respond to a request to the IEA from the G8 Summit in July 2005, were conducted to illustrate what efficiency is achieved now in modern plants in different parts of the world using different grades of fossil fuels. The plants were selected from different geographical areas, because local factors influence attainable efficiency. The case studies include pulverized coal combustion (PCC) with both subcritical and supercritical (very high pressure and temperature) steam turbine cycles, a review of current and future applications of coal-fuelled integrated gasification combined cycle plants (IGCC), and a case study of a natural gas fired combined cycle plant to facilitate comparisons. The results of these analyses show that the technologies for high efficiency (low CO{sub 2} emission) and very low conventional pollutant emissions (particulates, SO{sub 2}, NOx) from fossil fuel-fired power generation are available now through PCC, IGCC or NGCC at commercially acceptable cost. This report contains comprehensive technical and indicative cost information for modern fossil fuel-fired plants that was previously unavailable. It serves as a valuable sourcebook for policy makers and technical decision makers contemplating decisions to build new fossil fuel-fired power generation plants.

  18. Understanding Our Energy Footprint: Undergraduate Chemistry Laboratory Investigation of Environmental Impacts of Solid Fossil Fuel Wastes

    Science.gov (United States)

    Berger, Michael; Goldfarb, Jillian L.

    2017-01-01

    Engaging undergraduates in the environmental consequences of fossil fuel usage primes them to consider their own anthropogenic impact, and the benefits and trade-offs of converting to renewable fuel strategies. This laboratory activity explores the potential contaminants (both inorganic and organic) present in the raw fuel and solid waste…

  19. Fuel Temperature Coefficient of Reactivity

    Energy Technology Data Exchange (ETDEWEB)

    Loewe, W.E.

    2001-07-31

    A method for measuring the fuel temperature coefficient of reactivity in a heterogeneous nuclear reactor is presented. The method, which is used during normal operation, requires that calibrated control rods be oscillated in a special way at a high reactor power level. The value of the fuel temperature coefficient of reactivity is found from the measured flux responses to these oscillations. Application of the method in a Savannah River reactor charged with natural uranium is discussed.

  20. CMS: CO2 Emissions from Fossil Fuels Combustion, ACES Inventory for Northeastern USA

    Data.gov (United States)

    National Aeronautics and Space Administration — This dataset provides estimates of annual and hourly carbon dioxide (CO2) emissions from the combustion of fossil fuels (FF) for 13 states across the Northeastern...

  1. ISLSCP II Carbon Dioxide Emissions from Fossil Fuels, Cement, and Gas Flaring

    Data.gov (United States)

    National Aeronautics and Space Administration — ABSTRACT: This data set contains decadal (1950, 1960, 1970, 1980, 1990 and 1995) estimates of gridded fossil-fuel emissions, expressed in 1,000 metric tons C per...

  2. ISLSCP II Carbon Dioxide Emissions from Fossil Fuels, Cement, and Gas Flaring

    Data.gov (United States)

    National Aeronautics and Space Administration — This data set contains decadal (1950, 1960, 1970, 1980, 1990 and 1995) estimates of gridded fossil-fuel emissions, expressed in 1,000 metric tons C per year per one...

  3. Monitoring fossil fuel sources of methane in Australia

    Science.gov (United States)

    Loh, Zoe; Etheridge, David; Luhar, Ashok; Hibberd, Mark; Thatcher, Marcus; Noonan, Julie; Thornton, David; Spencer, Darren; Gregory, Rebecca; Jenkins, Charles; Zegelin, Steve; Leuning, Ray; Day, Stuart; Barrett, Damian

    2017-04-01

    CSIRO has been active in identifying and quantifying methane emissions from a range of fossil fuel sources in Australia over the past decade. We present here a history of the development of our work in this domain. While we have principally focused on optimising the use of long term, fixed location, high precision monitoring, paired with both forward and inverse modelling techniques suitable either local or regional scales, we have also incorporated mobile ground surveys and flux calculations from plumes in some contexts. We initially developed leak detection methodologies for geological carbon storage at a local scale using a Bayesian probabilistic approach coupled to a backward Lagrangian particle dispersion model (Luhar et al. JGR, 2014), and single point monitoring with sector analysis (Etheridge et al. In prep.) We have since expanded our modelling techniques to regional scales using both forward and inverse approaches to constrain methane emissions from coal mining and coal seam gas (CSG) production. The Surat Basin (Queensland, Australia) is a region of rapidly expanding CSG production, in which we have established a pair of carefully located, well-intercalibrated monitoring stations. These data sets provide an almost continuous record of (i) background air arriving at the Surat Basin, and (ii) the signal resulting from methane emissions within the Basin, i.e. total downwind methane concentration (comprising emissions including natural geological seeps, agricultural and biogenic sources and fugitive emissions from CSG production) minus background or upwind concentration. We will present our latest results on monitoring from the Surat Basin and their application to estimating methane emissions.

  4. Atmospheric measurement of point source fossil fuel CO2 emissions

    Science.gov (United States)

    Turnbull, J. C.; Keller, E. D.; Baisden, W. T.; Brailsford, G.; Bromley, T.; Norris, M.; Zondervan, A.

    2013-11-01

    We use the Kapuni Gas Treatment Plant to examine methodologies for atmospheric monitoring of point source fossil fuel CO2 (CO2ff) emissions. The Kapuni plant, located in rural New Zealand, removes CO2 from locally extracted natural gas and vents that CO2 to the atmosphere, at a rate of ~0.1 Tg carbon per year. The plant is located in a rural dairy farming area, with no other significant CO2ff sources nearby, but large, diurnally varying, biospheric CO2 fluxes from the surrounding highly productive agricultural grassland. We made flask measurements of CO2 and 14CO2 (from which we derive the CO2ff component) and in situ measurements of CO2 downwind of the Kapuni plant, using a Helikite to sample transects across the emission plume from the surface up to 100 m a.g.l. We also determined the surface CO2ff content averaged over several weeks from the 14CO2 content of grass samples collected from the surrounding area. We use the WindTrax plume dispersion model to compare the atmospheric observations with the emissions reported by the Kapuni plant, and to determine how well atmospheric measurements can constrain the emissions. The model has difficulty accurately capturing the fluctuations and short-term variability in the Helikite samples, but does quite well in representing the observed CO2ff in 15 min averaged surface flask samples and in ~1 week integrated CO2ff averages from grass samples. In this pilot study, we found that using grass samples, the modeled and observed CO2ff emissions averaged over one week agreed to within 30%. The results imply that greater verification accuracy may be achieved by including more detailed meteorological observations and refining 14CO2 sampling strategies.

  5. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-07-13

    This Summary Report summarizes the progress of Phases 3, 3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the Material Handling and Conditioning System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem.

  6. INNOVATIVE FOSSIL FUEL FIRED VITRIFICATION TECHNOLOGY FOR SOIL REMEDIATION

    Energy Technology Data Exchange (ETDEWEB)

    J. Hnat; L.M. Bartone; M. Pineda

    2001-10-31

    This Final Report summarizes the progress of Phases 3,3A and 4 of a waste technology Demonstration Project sponsored under a DOE Environmental Management Research and Development Program and administered by the U.S. Department of Energy National Energy Technology Laboratory-Morgantown (DOE-NETL) for an ''Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation''. The Summary Reports for Phases 1 and 2 of the Program were previously submitted to DOE. The total scope of Phase 3 was to have included the design, construction and demonstration of Vortec's integrated waste pretreatment and vitrification process for the treatment of low level waste (LLW), TSCA/LLW and mixed low-level waste (MLLW). Due to funding limitations and delays in the project resulting from a law suit filed by an environmental activist and the extended time for DOE to complete an Environmental Assessment for the project, the scope of the project was reduced to completing the design, construction and testing of the front end of the process which consists of the Material Handling and Waste Conditioning (MH/C) Subsystem of the vitrification plant. Activities completed under Phases 3A and 4 addressed completion of the engineering, design and documentation of the MH/C System such that final procurement of the remaining process assemblies can be completed and construction of a Limited Demonstration Project be initiated in the event DOE elects to proceed with the construction and demonstration testing of the MH/C Subsystem. Because of USEPA policies and regulations that do not require treatment of low level or low-level/PCB contaminated wastes, DOE terminated the project because there is no purported need for this technology.

  7. A Pilot Study to Evaluate California's Fossil Fuel CO2 Emissions Using Atmospheric Observations

    Science.gov (United States)

    Graven, H. D.; Fischer, M. L.; Lueker, T.; Guilderson, T.; Brophy, K. J.; Keeling, R. F.; Arnold, T.; Bambha, R.; Callahan, W.; Campbell, J. E.; Cui, X.; Frankenberg, C.; Hsu, Y.; Iraci, L. T.; Jeong, S.; Kim, J.; LaFranchi, B. W.; Lehman, S.; Manning, A.; Michelsen, H. A.; Miller, J. B.; Newman, S.; Paplawsky, B.; Parazoo, N.; Sloop, C.; Walker, S.; Whelan, M.; Wunch, D.

    2016-12-01

    Atmospheric CO2 concentration is influenced by human activities and by natural exchanges. Studies of CO2 fluxes using atmospheric CO2 measurements typically focus on natural exchanges and assume that CO2 emissions by fossil fuel combustion and cement production are well-known from inventory estimates. However, atmospheric observation-based or "top-down" studies could potentially provide independent methods for evaluating fossil fuel CO2 emissions, in support of policies to reduce greenhouse gas emissions and mitigate climate change. Observation-based estimates of fossil fuel-derived CO2 may also improve estimates of biospheric CO2 exchange, which could help to characterize carbon storage and climate change mitigation by terrestrial ecosystems. We have been developing a top-down framework for estimating fossil fuel CO2 emissions in California that uses atmospheric observations and modeling. California is implementing the "Global Warming Solutions Act of 2006" to reduce total greenhouse gas emissions to 1990 levels by 2020, and it has a diverse array of ecosystems that may serve as CO2 sources or sinks. We performed three month-long field campaigns in different seasons in 2014-15 to collect flask samples from a state-wide network of 10 towers. Using measurements of radiocarbon in CO2, we estimate the fossil fuel-derived CO2 present in the flask samples, relative to marine background air observed at coastal sites. Radiocarbon (14C) is not present in fossil fuel-derived CO2 because of radioactive decay over millions of years, so fossil fuel emissions cause a measurable decrease in the 14C/C ratio in atmospheric CO2. We compare the observations of fossil fuel-derived CO2 to simulations based on atmospheric modeling and published fossil fuel flux estimates, and adjust the fossil fuel flux estimates in a statistical inversion that takes account of several uncertainties. We will present the results of the top-down technique to estimate fossil fuel emissions for our field

  8. Upward revision of global fossil fuel methane emissions based on isotope database.

    Science.gov (United States)

    Schwietzke, Stefan; Sherwood, Owen A; Bruhwiler, Lori M P; Miller, John B; Etiope, Giuseppe; Dlugokencky, Edward J; Michel, Sylvia Englund; Arling, Victoria A; Vaughn, Bruce H; White, James W C; Tans, Pieter P

    2016-10-06

    Methane has the second-largest global radiative forcing impact of anthropogenic greenhouse gases after carbon dioxide, but our understanding of the global atmospheric methane budget is incomplete. The global fossil fuel industry (production and usage of natural gas, oil and coal) is thought to contribute 15 to 22 per cent of methane emissions to the total atmospheric methane budget. However, questions remain regarding methane emission trends as a result of fossil fuel industrial activity and the contribution to total methane emissions of sources from the fossil fuel industry and from natural geological seepage, which are often co-located. Here we re-evaluate the global methane budget and the contribution of the fossil fuel industry to methane emissions based on long-term global methane and methane carbon isotope records. We compile the largest isotopic methane source signature database so far, including fossil fuel, microbial and biomass-burning methane emission sources. We find that total fossil fuel methane emissions (fossil fuel industry plus natural geological seepage) are not increasing over time, but are 60 to 110 per cent greater than current estimates owing to large revisions in isotope source signatures. We show that this is consistent with the observed global latitudinal methane gradient. After accounting for natural geological methane seepage, we find that methane emissions from natural gas, oil and coal production and their usage are 20 to 60 per cent greater than inventories. Our findings imply a greater potential for the fossil fuel industry to mitigate anthropogenic climate forcing, but we also find that methane emissions from natural gas as a fraction of production have declined from approximately 8 per cent to approximately 2 per cent over the past three decades.

  9. Policy Surveillance in the G20 Fossil Fuel Subsidies Agreement: Lessons for Climate Policy

    OpenAIRE

    Aldy, Joseph Edgar

    2015-01-01

    Inadequate policy surveillance has undermined the effectiveness of multilateral climate agreements. To illustrate an alternative approach to transparency, I evaluate policy surveillance under the 2009 G-20 fossil fuel subsidies agreement. The Leaders of the Group of 20 nations tasked their energy and finance ministers to identify and phase-out fossil fuel subsidies. The G-20 leaders agreed to submit their subsidy reform strategies to peer review and to independent expert review conducted by i...

  10. Recent decreases in fossil-fuel emissions of ethane and methane derived from firn air.

    Science.gov (United States)

    Aydin, Murat; Verhulst, Kristal R; Saltzman, Eric S; Battle, Mark O; Montzka, Stephen A; Blake, Donald R; Tang, Qi; Prather, Michael J

    2011-08-10

    Methane and ethane are the most abundant hydrocarbons in the atmosphere and they affect both atmospheric chemistry and climate. Both gases are emitted from fossil fuels and biomass burning, whereas methane (CH(4)) alone has large sources from wetlands, agriculture, landfills and waste water. Here we use measurements in firn (perennial snowpack) air from Greenland and Antarctica to reconstruct the atmospheric variability of ethane (C(2)H(6)) during the twentieth century. Ethane levels rose from early in the century until the 1980s, when the trend reversed, with a period of decline over the next 20 years. We find that this variability was primarily driven by changes in ethane emissions from fossil fuels; these emissions peaked in the 1960s and 1970s at 14-16 teragrams per year (1 Tg = 10(12) g) and dropped to 8-10 Tg  yr(-1) by the turn of the century. The reduction in fossil-fuel sources is probably related to changes in light hydrocarbon emissions associated with petroleum production and use. The ethane-based fossil-fuel emission history is strikingly different from bottom-up estimates of methane emissions from fossil-fuel use, and implies that the fossil-fuel source of methane started to decline in the 1980s and probably caused the late twentieth century slow-down in the growth rate of atmospheric methane.

  11. Material Flow Analysis of Fossil Fuels in China during 2000–2010

    Science.gov (United States)

    Wang, Sheng; Dai, Jing; Su, Meirong

    2012-01-01

    Since the relationship between the supply and demand of fossil fuels is on edge in the long run, the contradiction between the economic growth and limited resources will hinder the sustainable development of the Chinese society. This paper aims to analyze the input of fossil fuels in China during 2000–2010 via the material flow analysis (MFA) that takes hidden flows into account. With coal, oil, and natural gas quantified by MFA, three indexes, consumption and supply ratio (C/S ratio), resource consumption intensity (RCI), and fossil fuels productivity (FFP), are proposed to reflect the interactions between population, GDP, and fossil fuels. The results indicated that in the past 11 years, China's requirement for fossil fuels has been increasing continuously because of the growing mine productivity in domestic areas, which also leads to a single energy consumption structure as well as excessive dependence on the domestic exploitation. It is advisable to control the fossil fuels consumption by energy recycling and new energy facilities' popularization in order to lead a sustainable access to nonrenewable resources and decrease the soaring carbon emissions. PMID:23365525

  12. Material flow analysis of fossil fuels in China during 2000-2010.

    Science.gov (United States)

    Wang, Sheng; Dai, Jing; Su, Meirong

    2012-01-01

    Since the relationship between the supply and demand of fossil fuels is on edge in the long run, the contradiction between the economic growth and limited resources will hinder the sustainable development of the Chinese society. This paper aims to analyze the input of fossil fuels in China during 2000-2010 via the material flow analysis (MFA) that takes hidden flows into account. With coal, oil, and natural gas quantified by MFA, three indexes, consumption and supply ratio (C/S ratio), resource consumption intensity (RCI), and fossil fuels productivity (FFP), are proposed to reflect the interactions between population, GDP, and fossil fuels. The results indicated that in the past 11 years, China's requirement for fossil fuels has been increasing continuously because of the growing mine productivity in domestic areas, which also leads to a single energy consumption structure as well as excessive dependence on the domestic exploitation. It is advisable to control the fossil fuels consumption by energy recycling and new energy facilities' popularization in order to lead a sustainable access to nonrenewable resources and decrease the soaring carbon emissions.

  13. Material Flow Analysis of Fossil Fuels in China during 2000–2010

    Directory of Open Access Journals (Sweden)

    Sheng Wang

    2012-01-01

    Full Text Available Since the relationship between the supply and demand of fossil fuels is on edge in the long run, the contradiction between the economic growth and limited resources will hinder the sustainable development of the Chinese society. This paper aims to analyze the input of fossil fuels in China during 2000–2010 via the material flow analysis (MFA that takes hidden flows into account. With coal, oil, and natural gas quantified by MFA, three indexes, consumption and supply ratio (C/S ratio, resource consumption intensity (RCI, and fossil fuels productivity (FFP, are proposed to reflect the interactions between population, GDP, and fossil fuels. The results indicated that in the past 11 years, China’s requirement for fossil fuels has been increasing continuously because of the growing mine productivity in domestic areas, which also leads to a single energy consumption structure as well as excessive dependence on the domestic exploitation. It is advisable to control the fossil fuels consumption by energy recycling and new energy facilities’ popularization in order to lead a sustainable access to nonrenewable resources and decrease the soaring carbon emissions.

  14. HIGH TEMPERATURE POLYMER FUEL CELLS

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Qingfeng, Li; He, Ronghuan

    2003-01-01

    This paper will report recent results from our group on polymer fuel cells (PEMFC) based on the temperature resistant polymer polybenzimidazole (PBI), which allow working temperatures up to 200°C. The membrane has a water drag number near zero and need no water management at all. The high working...

  15. Energy Analysis of the Danish Food Production System: Food-EROI and Fossil Fuel Dependency

    DEFF Research Database (Denmark)

    Markussen, Mads Ville; Østergård, Hanne

    2013-01-01

    Modern food production depends on limited natural resources for providing energy and fertilisers. We assess the fossil fuel dependency for the Danish food production system by means of Food Energy Returned on fossil Energy Invested (Food-EROI) and by the use of energy intensive nutrients from...... imported livestock feed and commercial fertilisers. The analysis shows that the system requires 221 PJ of fossil energy per year and that for each joule of fossil energy invested in farming, processing and transportation, 0.25 J of food energy is produced; 0.28 when crediting for produced bioenergy....... Furthermore, nutrients in commercial fertiliser and imported feed account for 84%, 90% and 90% of total supply of N, P and K, respectively. We conclude that the system is unsustainable because it is embedded in a highly fossil fuel dependent system based on a non-circular flow of nutrients. As energy and thus...

  16. Replacing Burning of Fossil Fuels with Solar Cell and Wind Energy: How Important and How Soon?

    Science.gov (United States)

    Partain, L., II; Hansen, R. T.; Hansen, S. F.; Bennett, D.; Newlands, A.

    2016-12-01

    The IPCC indicated that atmospheric CO2 rise should stop to control global climate change. CO2 is the longest lived, most problematic anthropogenic greenhouse emission from burning fossil fuel. For 2000 years atmospheric CO2 concentration remained 280 ppm until 1870, when it rose sharply and nonlinearly to 400 ppm, correlated with a 1oC global mean temperature rise. Antarctic ice core data for the past 400,000 years indicate, 80 ppm shifts in atmospheric CO2 concentrations with 10,000-30,000 year interglacial periods at 280 ppm, were between ice-age glacial periods of 75,000-100,000 years at 200 ppm. The last 12,000-year interglacial "Goldilocks" period so far spans 4 civilizations: 6000 years of Western, 4000-5000 years of Inca and Aztec and 7000-8000 years of Chinese civilizations. The UN-led 2015 Paris Agreement set a goal limiting temperature rise to 2oC to prevent devastating climate change. Unfortunately IPCC modeling found a substantial probability of a rise by 4oC or more should all current fossil fuels be burned by 2100. This would result in weather extremes, rising oceans, storm surges and temperatures where low-lying coastal regions, Pacific Islands and large equatorial regions of the world could become uninhabitable. By Swanson's Law, an empirical learning curve observation, solar cell production costs drop 50% for every 10X increase in their cumulative production. After 40 years and over 5 orders-of-magnitude cumulative production increase, solar cells currently provide over 1% of the world's electricity generating capacity at a cost competitive with electricity generated from burning fossil fuels. If their cumulative generating capacity keeps doubling every 2 years (similar to Moore's Law), energy equivalent to all the world's electricity generating capacity could be provided by solar cells by 2028. The variability of solar cell energy can be mitigated by combining it with wind power, storage, super grids, space mirrors, and demand response.

  17. Comparative evaluation of solar, fission, fusion, and fossil energy resources. Part 4: Energy from fossil fuels

    Science.gov (United States)

    Williams, J. R.

    1974-01-01

    The conversion of fossil-fired power plants now burning oil or gas to burn coal is discussed along with the relaxation of air quality standards and the development of coal gasification processes to insure a continued supply of gas from coal. The location of oil fields, refining areas, natural gas fields, and pipelines in the U.S. is shown. The technologies of modern fossil-fired boilers and gas turbines are defined along with the new technologies of fluid-bed boilers and MHD generators.

  18. Energy analysis and break-even distance for transportation for biofuels in comparison to fossil fuels

    Science.gov (United States)

    In the present analysis various forms fuel from biomass and fossil sources, their mass and energy densities, and their break-even transportation distances to transport them effectively were analyzed. This study gives an insight on how many times more energy spent on transporting the fuels to differe...

  19. FUTURE FOSSIL FUEL PRICE IMPACTS ON NDC ACHIEVEMENT; ESTIMATION OF GHG EMISSIONS AND MITIGATION COSTS

    Directory of Open Access Journals (Sweden)

    Yosuke Arino

    2017-12-01

    Full Text Available The Shale Revolution in the US, a supply-side innovation in oil and gas production, has been dramatically changing the world’s fossil fuel energy markets – leading to a decrease in oil, gas and coal prices. Some projections suggest that low fossil fuel prices might continue at least over the next few decades. Uncertainty in fossil fuel prices might affect the levels of emission reductions expected from submitted nationally determined contributions (NDCs and/or influence the difficulty of achieving the NDCs. This paper evaluated the impact of different (high, medium, and low fossil fuel prices, sustained through to 2050, on worldwide GHG emissions reductions and associated costs (mainly marginal abatement costs (MACs. Total global GHG emissions were estimated to be 57.5-61.5 GtCO2eq by 2030, with the range shown reflecting uncertainties about fossil fuel prices and the target levels of several NDCs (i.e., whether their upper or lower targets were adopted. It was found that lower fuel prices not only diminished the environmental effectiveness of global NDCs but also widened regional differences of marginal and total abatement costs, thereby generating more room for carbon leakage. One possible policy direction in terms of abatement efficiency, fairness and environmental effectiveness would be to require countries with low marginal and total abatement costs but having a major influence on global GHG emissions (such as China and India to increase their mitigation efforts, especially in a low-fuelprice world.

  20. Global combustion: the connection between fossil fuel and biomass burning emissions (1997-2010).

    Science.gov (United States)

    Balch, Jennifer K; Nagy, R Chelsea; Archibald, Sally; Bowman, David M J S; Moritz, Max A; Roos, Christopher I; Scott, Andrew C; Williamson, Grant J

    2016-06-05

    Humans use combustion for heating and cooking, managing lands, and, more recently, for fuelling the industrial economy. As a shift to fossil-fuel-based energy occurs, we expect that anthropogenic biomass burning in open landscapes will decline as it becomes less fundamental to energy acquisition and livelihoods. Using global data on both fossil fuel and biomass burning emissions, we tested this relationship over a 14 year period (1997-2010). The global average annual carbon emissions from biomass burning during this time were 2.2 Pg C per year (±0.3 s.d.), approximately one-third of fossil fuel emissions over the same period (7.3 Pg C, ±0.8 s.d.). There was a significant inverse relationship between average annual fossil fuel and biomass burning emissions. Fossil fuel emissions explained 8% of the variation in biomass burning emissions at a global scale, but this varied substantially by land cover. For example, fossil fuel burning explained 31% of the variation in biomass burning in woody savannas, but was a non-significant predictor for evergreen needleleaf forests. In the land covers most dominated by human use, croplands and urban areas, fossil fuel emissions were more than 30- and 500-fold greater than biomass burning emissions. This relationship suggests that combustion practices may be shifting from open landscape burning to contained combustion for industrial purposes, and highlights the need to take into account how humans appropriate combustion in global modelling of contemporary fire. Industrialized combustion is not only an important driver of atmospheric change, but also an important driver of landscape change through companion declines in human-started fires.This article is part of the themed issue 'The interaction of fire and mankind'. © 2016 The Author(s).

  1. Global combustion: the connection between fossil fuel and biomass burning emissions (1997–2010)

    Science.gov (United States)

    Balch, Jennifer K.; Nagy, R. Chelsea; Archibald, Sally; Moritz, Max A.; Williamson, Grant J.

    2016-01-01

    Humans use combustion for heating and cooking, managing lands, and, more recently, for fuelling the industrial economy. As a shift to fossil-fuel-based energy occurs, we expect that anthropogenic biomass burning in open landscapes will decline as it becomes less fundamental to energy acquisition and livelihoods. Using global data on both fossil fuel and biomass burning emissions, we tested this relationship over a 14 year period (1997–2010). The global average annual carbon emissions from biomass burning during this time were 2.2 Pg C per year (±0.3 s.d.), approximately one-third of fossil fuel emissions over the same period (7.3 Pg C, ±0.8 s.d.). There was a significant inverse relationship between average annual fossil fuel and biomass burning emissions. Fossil fuel emissions explained 8% of the variation in biomass burning emissions at a global scale, but this varied substantially by land cover. For example, fossil fuel burning explained 31% of the variation in biomass burning in woody savannas, but was a non-significant predictor for evergreen needleleaf forests. In the land covers most dominated by human use, croplands and urban areas, fossil fuel emissions were more than 30- and 500-fold greater than biomass burning emissions. This relationship suggests that combustion practices may be shifting from open landscape burning to contained combustion for industrial purposes, and highlights the need to take into account how humans appropriate combustion in global modelling of contemporary fire. Industrialized combustion is not only an important driver of atmospheric change, but also an important driver of landscape change through companion declines in human-started fires. This article is part of the themed issue ‘The interaction of fire and mankind’. PMID:27216509

  2. Significant long-term increase of fossil fuel CO2 uptake from reduced marine calcification

    Science.gov (United States)

    Ridgwell, A.; Zondervan, I.; Hargreaves, J. C.; Bijma, J.; Lenton, T. M.

    2006-11-01

    Analysis of available plankton manipulation experiments demonstrates a previously unrecognized wide range of sensitivities of biogenic calcification to simulated anthropogenic acidification of the ocean, with the "lab rat" of planktic calcifiers, Emiliania huxleyi not representative of calcification generally. We assess the implications of the experimental uncertainty in plankton calcification response by creating an ensemble of realizations of an Earth system model that encapsulates a comparable range of uncertainty in calcification response. We predict a substantial future reduction in marine carbonate production, with ocean CO2 sequestration across the model ensemble enhanced by between 62 and 199 PgC by the year 3000, equivalent to a reduction in the atmospheric fossil fuel CO2 burden at that time of up to 13%. Concurrent changes in ocean circulation and surface temperatures contribute about one third to the overall importance of reduced plankton calcification.

  3. Materials for low-temperature fuel cells

    CERN Document Server

    Ladewig, Bradley; Yan, Yushan; Lu, Max

    2014-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in Low-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in low-temperature fuel cells. A related book will cover key materials in high-temperature fuel cells. The two books form part

  4. Uncertainty in projected climate change caused by methodological discrepancy in estimating CO2 emissions from fossil fuel combustion

    Science.gov (United States)

    Quilcaille, Yann; Gasser, Thomas; Ciais, Philippe; Lecocq, Franck; Janssens-Maenhout, Greet; Mohr, Steve; Andres, Robert J.; Bopp, Laurent

    2016-04-01

    to a relative uncertainty of about 11%. We attribute this uncertainty to the different aggregation in subtypes of fossil fuels used in the different methodologies, and more specifically to the aggregation of coal subtypes. This uncertainty in emissions translates into an uncertainty of about 0.5°C in the projected global mean surface temperature. An uncertainty of half a degree shows the importance of improving our understanding and estimates of fossil fuel combustion emissions, since a global warming of 2°C (and even 1.5°C) is now the international target as committed by all Parties during the last COP in Paris.

  5. Low energy buildings – the basis for realizing the strategy for independency of fossil fuels in 2050

    DEFF Research Database (Denmark)

    Svendsen, Svend

    2011-01-01

    The paper introduces how low energy buildings can be developed, designed, optimized, constructed and operated in the future and thereby make a significant contribution to the realization of aim of the energy policy of EU: to become independent of fossil fuels in 2050. The paper describes how low...... energy buildings can become independent of fossil fuels in 2020 based on the following activities. Innovation of building components and systems with improved energy performance. Heating of low energy building with low temperature district heating based on renewable heat. Integrated design...... and optimization of low energy buildings. Continuous commissioning of low energy buildings with respect to energy use, indoor environment and durability. The very big and quick change of the energy performance of buildings is a challenge for the building sector but it can be solved by improving the methods...

  6. Global Inventory of Gas Geochemistry Data from Fossil Fuel, Microbial and Burning Sources, version 2017

    Science.gov (United States)

    Sherwood, Owen A.; Schwietzke, Stefan; Arling, Victoria A.; Etiope, Giuseppe

    2017-08-01

    The concentration of atmospheric methane (CH4) has more than doubled over the industrial era. To help constrain global and regional CH4 budgets, inverse (top-down) models incorporate data on the concentration and stable carbon (δ13C) and hydrogen (δ2H) isotopic ratios of atmospheric CH4. These models depend on accurate δ13C and δ2H end-member source signatures for each of the main emissions categories. Compared with meticulous measurement and calibration of isotopic CH4 in the atmosphere, there has been relatively less effort to characterize globally representative isotopic source signatures, particularly for fossil fuel sources. Most global CH4 budget models have so far relied on outdated source signature values derived from globally nonrepresentative data. To correct this deficiency, we present a comprehensive, globally representative end-member database of the δ13C and δ2H of CH4 from fossil fuel (conventional natural gas, shale gas, and coal), modern microbial (wetlands, rice paddies, ruminants, termites, and landfills and/or waste) and biomass burning sources. Gas molecular compositional data for fossil fuel categories are also included with the database. The database comprises 10 706 samples (8734 fossil fuel, 1972 non-fossil) from 190 published references. Mean (unweighted) δ13C signatures for fossil fuel CH4 are significantly lighter than values commonly used in CH4 budget models, thus highlighting potential underestimation of fossil fuel CH4 emissions in previous CH4 budget models. This living database will be updated every 2-3 years to provide the atmospheric modeling community with the most complete CH4 source signature data possible. Database digital object identifier (DOI): https://doi.org/10.15138/G3201T.

  7. Global Inventory of Gas Geochemistry Data from Fossil Fuel, Microbial and Burning Sources, version 2017

    Directory of Open Access Journals (Sweden)

    O. A. Sherwood

    2017-08-01

    Full Text Available The concentration of atmospheric methane (CH4 has more than doubled over the industrial era. To help constrain global and regional CH4 budgets, inverse (top-down models incorporate data on the concentration and stable carbon (δ13C and hydrogen (δ2H isotopic ratios of atmospheric CH4. These models depend on accurate δ13C and δ2H end-member source signatures for each of the main emissions categories. Compared with meticulous measurement and calibration of isotopic CH4 in the atmosphere, there has been relatively less effort to characterize globally representative isotopic source signatures, particularly for fossil fuel sources. Most global CH4 budget models have so far relied on outdated source signature values derived from globally nonrepresentative data. To correct this deficiency, we present a comprehensive, globally representative end-member database of the δ13C and δ2H of CH4 from fossil fuel (conventional natural gas, shale gas, and coal, modern microbial (wetlands, rice paddies, ruminants, termites, and landfills and/or waste and biomass burning sources. Gas molecular compositional data for fossil fuel categories are also included with the database. The database comprises 10 706 samples (8734 fossil fuel, 1972 non-fossil from 190 published references. Mean (unweighted δ13C signatures for fossil fuel CH4 are significantly lighter than values commonly used in CH4 budget models, thus highlighting potential underestimation of fossil fuel CH4 emissions in previous CH4 budget models. This living database will be updated every 2–3 years to provide the atmospheric modeling community with the most complete CH4 source signature data possible. Database digital object identifier (DOI: https://doi.org/10.15138/G3201T.

  8. Can the envisaged reductions of fossil fuel CO2 emissions be detected by atmospheric observations?

    Science.gov (United States)

    Levin, Ingeborg; Rödenbeck, Christian

    2008-03-01

    The lower troposphere is an excellent receptacle, which integrates anthropogenic greenhouse gases emissions over large areas. Therefore, atmospheric concentration observations over populated regions would provide the ultimate proof if sustained emissions changes have occurred. The most important anthropogenic greenhouse gas, carbon dioxide (CO(2)), also shows large natural concentration variations, which need to be disentangled from anthropogenic signals to assess changes in associated emissions. This is in principle possible for the fossil fuel CO(2) component (FFCO(2)) by high-precision radiocarbon ((14)C) analyses because FFCO(2) is free of radiocarbon. Long-term observations of (14)CO(2) conducted at two sites in south-western Germany do not yet reveal any significant trends in the regional fossil fuel CO(2) component. We rather observe strong inter-annual variations, which are largely imprinted by changes of atmospheric transport as supported by dedicated transport model simulations of fossil fuel CO(2). In this paper, we show that, depending on the remoteness of the site, changes of about 7-26% in fossil fuel emissions in respective catchment areas could be detected with confidence by high-precision atmospheric (14)CO(2) measurements when comparing 5-year averages if these inter-annual variations were taken into account. This perspective constitutes the urgently needed tool for validation of fossil fuel CO(2) emissions changes in the framework of the Kyoto protocol and successive climate initiatives.

  9. Biofuel: an alternative to fossil fuel for alleviating world energy and economic crises.

    Science.gov (United States)

    Bhattarai, Keshav; Stalick, Wayne M; McKay, Scott; Geme, Gija; Bhattarai, Nimisha

    2011-01-01

    The time has come when it is desirable to look for alternative energy resources to confront the global energy crisis. Consideration of the increasing environmental problems and the possible crisis of fossil fuel availability at record high prices dictate that some changes will need to occur sooner rather than later. The recent oil spill in the Gulf of Mexico is just another example of the environmental threats that fossil fuels pose. This paper is an attempt to explore various bio-resources such as corn, barley, oat, rice, wheat, sorghum, sugar, safflower, and coniferous and non-coniferous species for the production of biofuels (ethanol and biodiesel). In order to assess the potential production of biofuel, in this paper, countries are organized into three groups based on: (a) geographic areas; (b) economic development; and(c) lending types, as classified by the World Bank. First, the total fossil fuel energy consumption and supply and possible carbon emission from burning fossil fuel is projected for these three groups of countries. Second, the possibility of production of biofuel from grains and vegetative product is projected. Third, a comparison of fossil fuel and biofuel is done to examine energy sustainability issues.

  10. Towards constraining megacity fossil-fuel emissions estimates with OCO-2 observations and Lagrangian modeling.

    Science.gov (United States)

    Kort, E. A.; Yang, E.; Ware, J.; Ye, X.; Lauvaux, T.; Wu, D.; Lin, J. C.; Oda, T.

    2016-12-01

    Rapid changes in human behavior are introducing significant perturbations to the Earth's carbon cycle and atmospheric balance of greenhouse gases. Emissions of carbon dioxide (CO2) are continuing to rise, and uncertainties in fossil-fuel emissions are increasing. Meanwhile urbanization continues to concentrate the global population in urban centers, and urban regions are now a dominant driver of global CO2 emissions. Observational constraints on fossil-fuel emissions and models representing fossil-fuel emissions are needed both to inform societal choices and to use atmospheric observations to study feedbacks in the natural carbon cycle. In this presentation we will discuss an approach we are developing that leverages space-based observations of total column carbon dioxide (XCO2, "top-down") and compares with simulated XCO2 values produced with a Lagrangian model coupled with different meteorological winds and multiple fossil-fuel inventories ("bottom-up"). We will highlight observational successes for measurements from the Orbiting Carbon Observatory 2 (OCO-2) and times when robust results are expected. We will further discuss questions that can be robustly answered with this framework and OCO-2 data and when techniques with greater fidelity are required, explaining limitations of the current observational-modeling system. Finally, we will discuss implications of these observational constraints on different bottom-up fossil-fuel emission estimates, and how such impliactions may impact interpretation of global OCO-2 data.

  11. Nuclear Energy R&D Imperative 3: Enable a Transition Away from Fossil Fuel in the Transportation and Industrial Sectors

    Energy Technology Data Exchange (ETDEWEB)

    David Petti; J. Stephen Herring

    2010-03-01

    As described in the Department of Energy Office of Nuclear Energy’s Nuclear Energy R&D Roadmap, nuclear energy can play a significant role in supplying energy for a growing economy while reducing both our dependence on foreign energy supplies and emissions from the burning of fossil fuels. The industrial and transportation sectors are responsible for more than half of the greenhouse gas emissions in the U.S., and imported oil supplies 70% of the energy used in the transportation sector. It is therefore important to examine the various ways nuclear energy can facilitate a transition away from fossil fuels to secure environmentally sustainable production and use of energy in the transportation and manufacturing industry sectors. Imperative 3 of the Nuclear Energy R&D Roadmap, entitled “Enable a Transition Away from Fossil Fuels by Producing Process Heat for use in the Transportation and Industrial Sectors”, addresses this need. This document presents an Implementation Plan for R&D efforts related to this imperative. The expanded use of nuclear energy beyond the electrical grid will contribute significantly to overcoming the three inter-linked energy challenges facing U.S. industry: the rising and volatile prices for premium fossil fuels such as oil and natural gas, dependence on foreign sources for these fuels, and the risks of climate change resulting from carbon emissions. Nuclear energy could be used in the industrial and transportation sectors to: • Generate high temperature process heat and electricity to serve industrial needs including the production of chemical feedstocks for use in manufacturing premium fuels and fertilizer products, • Produce hydrogen for industrial processes and transportation fuels, and • Provide clean water for human consumption by desalination and promote wastewater treatment using low-grade nuclear heat as a useful additional benefit. Opening new avenues for nuclear energy will significantly enhance our nation’s energy

  12. High temperature PEM fuel cells

    Science.gov (United States)

    Zhang, Jianlu; Xie, Zhong; Zhang, Jiujun; Tang, Yanghua; Song, Chaojie; Navessin, Titichai; Shi, Zhiqing; Song, Datong; Wang, Haijiang; Wilkinson, David P.; Liu, Zhong-Sheng; Holdcroft, Steven

    There are several compelling technological and commercial reasons for operating H 2/air PEM fuel cells at temperatures above 100 °C. Rates of electrochemical kinetics are enhanced, water management and cooling is simplified, useful waste heat can be recovered, and lower quality reformed hydrogen may be used as the fuel. This review paper provides a concise review of high temperature PEM fuel cells (HT-PEMFCs) from the perspective of HT-specific materials, designs, and testing/diagnostics. The review describes the motivation for HT-PEMFC development, the technology gaps, and recent advances. HT-membrane development accounts for ∼90% of the published research in the field of HT-PEMFCs. Despite this, the status of membrane development for high temperature/low humidity operation is less than satisfactory. A weakness in the development of HT-PEMFC technology is the deficiency in HT-specific fuel cell architectures, test station designs, and testing protocols, and an understanding of the underlying fundamental principles behind these areas. The development of HT-specific PEMFC designs is of key importance that may help mitigate issues of membrane dehydration and MEA degradation.

  13. Materials for high-temperature fuel cells

    CERN Document Server

    Jiang, San Ping; Lu, Max

    2013-01-01

    There are a large number of books available on fuel cells; however, the majority are on specific types of fuel cells such as solid oxide fuel cells, proton exchange membrane fuel cells, or on specific technical aspects of fuel cells, e.g., the system or stack engineering. Thus, there is a need for a book focused on materials requirements in fuel cells. Key Materials in High-Temperature Fuel Cells is a concise source of the most important and key materials and catalysts in high-temperature fuel cells with emphasis on the most important solid oxide fuel cells. A related book will cover key mater

  14. A synthesis of carbon dioxide emissions from fossil-fuel combustion

    DEFF Research Database (Denmark)

    Andres, R.J.; Boden, T.A.; Bréon, F.-M.

    2012-01-01

    This synthesis discusses the emissions of carbon dioxide from fossil-fuel combustion and cement production. While much is known about these emissions, there is still much that is unknown about the details surrounding these emissions. This synthesis explores our knowledge of these emissions in terms...... of why there is concern about them; how they are calculated; the major global efforts on inventorying them; their global, regional, and national totals at different spatial and temporal scales; how they are distributed on global grids (i.e., maps); how they are transported in models......; and the uncertainties associated with these different aspects of the emissions. The magnitude of emissions from the combustion of fossil fuels has been almost continuously increasing with time since fossil fuels were first used by humans. Despite events in some nations specifically designed to reduce emissions...

  15. Long-term ocean oxygen depletion in response to carbon dioxide emissions from fossil fuels

    DEFF Research Database (Denmark)

    Shaffer, G.; Olsen, S.M.; Pedersen, Jens Olaf Pepke

    2009-01-01

    Ongoing global warming could persist far into the future, because natural processes require decades to hundreds of thousands of years to remove carbon dioxide from fossil-fuel burning from the atmosphere(1-3). Future warming may have large global impacts including ocean oxygen depletion and assoc......Ongoing global warming could persist far into the future, because natural processes require decades to hundreds of thousands of years to remove carbon dioxide from fossil-fuel burning from the atmosphere(1-3). Future warming may have large global impacts including ocean oxygen depletion...... solubility from surface-layer warming accounts for most of the enhanced oxygen depletion in the upper 500 m of the ocean. Possible weakening of ocean overturning and convection lead to further oxygen depletion, also in the deep ocean. We conclude that substantial reductions in fossil-fuel use over the next...

  16. Effect of subsidies to fossil fuel companies on United States crude oil production

    Science.gov (United States)

    Erickson, Peter; Down, Adrian; Lazarus, Michael; Koplow, Doug

    2017-11-01

    Countries in the G20 have committed to phase out `inefficient' fossil fuel subsidies. However, there remains a limited understanding of how subsidy removal would affect fossil fuel investment returns and production, particularly for subsidies to producers. Here, we assess the impact of major federal and state subsidies on US crude oil producers. We find that, at recent oil prices of US50 per barrel, tax preferences and other subsidies push nearly half of new, yet-to-be-developed oil investments into profitability, potentially increasing US oil production by 17 billion barrels over the next few decades. This oil, equivalent to 6 billion tonnes of CO2, could make up as much as 20% of US oil production through 2050 under a carbon budget aimed at limiting warming to 2 °C. Our findings show that removal of tax incentives and other fossil fuel support policies could both fulfil G20 commitments and yield climate benefits.

  17. Estimating methane emissions from biological and fossil-fuel sources in the San Francisco Bay Area

    Science.gov (United States)

    Jeong, Seongeun; Cui, Xinguang; Blake, Donald R.; Miller, Ben; Montzka, Stephen A.; Andrews, Arlyn; Guha, Abhinav; Martien, Philip; Bambha, Ray P.; LaFranchi, Brian; Michelsen, Hope A.; Clements, Craig B.; Glaize, Pierre; Fischer, Marc L.

    2017-01-01

    We present the first sector-specific analysis of methane (CH4) emissions from the San Francisco Bay Area (SFBA) using CH4 and volatile organic compound (VOC) measurements from six sites during September - December 2015. We apply a hierarchical Bayesian inversion to separate the biological from fossil-fuel (natural gas and petroleum) sources using the measurements of CH4 and selected VOCs, a source-specific 1 km CH4 emission model, and an atmospheric transport model. We estimate that SFBA CH4 emissions are 166-289 Gg CH4/yr (at 95% confidence), 1.3-2.3 times higher than a recent inventory with much of the underestimation from landfill. Including the VOCs, 82 ± 27% of total posterior median CH4 emissions are biological and 17 ± 3% fossil fuel, where landfill and natural gas dominate the biological and fossil-fuel CH4 of prior emissions, respectively.

  18. Co-combustion of fossil fuels and waste

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Hao

    2011-05-15

    combustion, co-combustion of coal and SRF (up to 10% thermal share) generally promoted the formation of ultrafine particles with a concentration peak around 0.1 {mu}m, while the total concentration of PM{sub 2.5} decreased. Composition analyses showed that the Ca, S and P were significantly enriched in the ultrafine particles, indicating a high volatility of these elements in pulverized coal combustion. Compared to dedicated coal combustion, the content of the Ca, P and K was larger in the fine particles generated from co-combustion, whereas the S content was slightly smaller. During the full-scale tests, the dust emission appeared to be significantly increased during co-combustion of coal and SRF, which was presumably related to a reduction of the collection efficiency of the electrostatic precipitator (ESP). Dust-firing of straw was performed in an entrained flow reactor, and the feasibility of utilizing spent bleaching earth (SBE) as an additive was investigated through a comparison with kaolinite. It was found that about 70% of the K in the fly ash from straw-dust firing was water soluble, and the KCl contributed more than 40% of the water soluble K. With the addition of 10-20 wt% of SBE, the Cl retention in ash was decreased, the SO{sub 2} emission was increased, and the formation of water soluble alkali species was reduced. Compared to kaolinite, the inhibiting effect of SBE on the formation of alkali chlorides was slightly smaller when the molar ratio of K/(Al+Si) was similar in the fuel mixture. The addition of SBE significantly reduced the Cl content of the deposits collected on a probe. The release and transformation of inorganic elements during the combustion of a residual bran was studied through experiments and equilibrium modeling. The work revealed that the major inorganic elements released during bran combustion were K, P and S. The S was almost fully vaporized during pyrolysis at temperatures below 700 deg. C, whereas about 60-70 % of the K and P in the bran

  19. What Geological, Economic, or Policy Forces Might Limit Fossil Fuel Production?

    Science.gov (United States)

    Heinberg, R.

    2015-12-01

    In order to ensure a 50% chance of keeping global temperatures from exceeding 2°C above pre-industrial levels, it has been estimated that total carbon dioxide emissions between 2011-2050 must be capped at roughly 1,100 gigatons.[1] However, some estimates calculate that global fossil fuel reserves—including unconventional oil and gas—hold at least three times this amount of potential greenhouse gas emissions.[2]What socio-political, technological, or economic forces are most likely to keep these energy resources from being burned? While it is difficult to predict with specificity what combination of technological, geological, or human factors will significantly minimize global fossil fuel production, there are at least four key potential drivers: 1. Under-investment and the economics of unconventional oil and natural gas; 2. International policy, driven by citizen demand and leadership from key nations; 3. Massive deployment of renewable energy sources and other technological solutions; and 4. Large-scale energy curtailment resulting from global economic contraction. We will explore the implications, viability, and consequences of each of these potential factors. [1] [1]United Nations Framework Convention on Climate Change (UNFCC) Report of the Conference of the Parties on its Fifteenth Session, held in Copenhagen from 7 to 19 December 2009. Part Two: Action taken by the Conference of the Parties at its Fifteenth Session. United Nations Climate Change Conf. Report 43 http://unfccc.int/resource/docs/2009/cop15/eng/11a01.pdf (UNFCC, 2009) [2] Raupach, M. R. et al. Sharing a quota on cumulative carbon emissions. Nature Clim. Chang. 4, 873-879 (2014)

  20. The “keep in the ground future” of Arctic fossil fuel resources

    OpenAIRE

    Sandi Lansetti

    2016-01-01

    It is extremely important to understand which role Arctic fossil fuel resources will play in the development and geopolitics of the Arctic region. The article analyses the recent trends in the world energy supply with special focus on renewable energy and future demand for fossil fuels. Focusing on the Arctic LNG projects it comes to the conclusion that there is a growing possibility that the majority of Arctic oil and natural gas will be kept in the ground. Such an outcome would strongly inf...

  1. The “keep in the ground future” of Arctic fossil fuel resources

    Directory of Open Access Journals (Sweden)

    Sandi Lansetti

    2016-12-01

    Full Text Available It is extremely important to understand which role Arctic fossil fuel resources will play in the development and geopolitics of the Arctic region. The article analyses the recent trends in the world energy supply with special focus on renewable energy and future demand for fossil fuels. Focusing on the Arctic LNG projects it comes to the conclusion that there is a growing possibility that the majority of Arctic oil and natural gas will be kept in the ground. Such an outcome would strongly influence the sustainable development and geopolitics of the region.

  2. Interaction of carbon reduction and green energy promotion in a small fossil-fuel importing economy

    Energy Technology Data Exchange (ETDEWEB)

    Pethig, Ruediger; Wittlich, Christian [Sigen Univ. (Germany). Dept. of Economics

    2009-08-15

    We study the incidence of carbon-reduction and green-energy promotion policies in an open fossil-fuel importing general equilibrium economy. The focus is on mixed price-based or quantity-based policies. Instruments directed toward promoting green energy are shown to reduce also carbon emissions and vice versa. Their direct effects are stronger than their side effects, the more so, the greater is the elasticity of substitution in consumption between energy and the consumption good. We calculate the effects of variations in individual policy parameters, especially on energy prices and welfare costs, and determine the impact of exogenous fossil-fuel price shocks on the economy. (orig.)

  3. Energy Analysis of the Danish Food Production System: Food-EROI and Fossil Fuel Dependency

    Directory of Open Access Journals (Sweden)

    Hanne Østergård

    2013-08-01

    Full Text Available Modern food production depends on limited natural resources for providing energy and fertilisers. We assess the fossil fuel dependency for the Danish food production system by means of Food Energy Returned on fossil Energy Invested (Food-EROI and by the use of energy intensive nutrients from imported livestock feed and commercial fertilisers. The analysis shows that the system requires 221 PJ of fossil energy per year and that for each joule of fossil energy invested in farming, processing and transportation, 0.25 J of food energy is produced; 0.28 when crediting for produced bioenergy. Furthermore, nutrients in commercial fertiliser and imported feed account for 84%, 90% and 90% of total supply of N, P and K, respectively. We conclude that the system is unsustainable because it is embedded in a highly fossil fuel dependent system based on a non-circular flow of nutrients. As energy and thus nutrient constraints may develop in the coming decades, the current system may need to adapt by reducing use of fossil energy at the farm and for transportation of food and feed. An operational strategy may be to relocalise the supply of energy, nutrients, feed and food.

  4. High resolution fossil fuel combustion CO2 emission fluxes for the United States

    Energy Technology Data Exchange (ETDEWEB)

    Gurney, Kevin R.; Mendoza, Daniel L.; Zhou, Yuyu; Fischer, Marc L.; Miller, Chris C.; Geethakumar, Sarath; de la Rue du Can, Stephane

    2009-03-19

    Quantification of fossil fuel CO{sub 2} emissions at fine space and time resolution is emerging as a critical need in carbon cycle and climate change research. As atmospheric CO{sub 2} measurements expand with the advent of a dedicated remote sensing platform and denser in situ measurements, the ability to close the carbon budget at spatial scales of {approx}100 km{sup 2} and daily time scales requires fossil fuel CO{sub 2} inventories at commensurate resolution. Additionally, the growing interest in U.S. climate change policy measures are best served by emissions that are tied to the driving processes in space and time. Here we introduce a high resolution data product (the 'Vulcan' inventory: www.purdue.edu/eas/carbon/vulcan/) that has quantified fossil fuel CO{sub 2} emissions for the contiguous U.S. at spatial scales less than 100 km{sup 2} and temporal scales as small as hours. This data product, completed for the year 2002, includes detail on combustion technology and 48 fuel types through all sectors of the U.S. economy. The Vulcan inventory is built from the decades of local/regional air pollution monitoring and complements these data with census, traffic, and digital road data sets. The Vulcan inventory shows excellent agreement with national-level Department of Energy inventories, despite the different approach taken by the DOE to quantify U.S. fossil fuel CO{sub 2} emissions. Comparison to the global 1{sup o} x 1{sup o} fossil fuel CO{sub 2} inventory, used widely by the carbon cycle and climate change community prior to the construction of the Vulcan inventory, highlights the space/time biases inherent in the population-based approach.

  5. Uncertainty in the availability of natural resources: Fossil fuels, critical metals and biomass

    OpenAIRE

    Speirs, Jamie; McGlade, Christophe; Slade, Raphael

    2015-01-01

    Energy policies are strongly influenced by resource availability and recoverability estimates. Yet these estimates are often highly uncertain, frequently incommensurable, and regularly contested. This paper explores how the uncertainties surrounding estimates of the availability of fossil fuels, biomass and critical metals are conceptualised and communicated. The contention is that a better understanding of the uncertainties surrounding resource estimates for both conventional and renewable e...

  6. Environmental and Financial Performance of Fossil Fuel Firms : A Closer Inspection of their Interaction

    NARCIS (Netherlands)

    Gonenc, Halit; Scholtens, Bert

    We investigate the relationship between environmental and financial performance of fossil fuel firms. To this extent, we analyze a large international sample of firms in chemicals, oil, gas, and coal with respect to several environmental indicators in relation to financial performance for the period

  7. Review of NO/sub x/ emission factors for stationary fossil fuel combustion sources. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Milligan, R.J.; Sailor, W.C.; Wasilewski, J.; Kuby, W.C.

    1979-09-01

    A review of recent NOx test data was performed, and summaries of emission factors presented for various types of stationary source combustion and for various fossil fuels. The effects of combustion modifications on NOx emissions are quantified. Background data are given to help the user determine the reliability of each factor in particular applications.

  8. Climate Policy and the Optimal Extraction of High- and Low-Carbon Fossil Fuels

    NARCIS (Netherlands)

    Smulders, J.A.; van der Werf, E.H.

    2005-01-01

    We study how restricting CO2 emissions affcts resource prices and depletion over time.We use a Hotelling-style model with two nonrenewable fossil fuels that differ in their carbon content (e.g. coal and natural gas) and that are imperfect substitutes in final good production.We study both an

  9. Impact of fossil fuel emissions on atmospheric radiocarbon and various applications of radiocarbon over this century.

    Science.gov (United States)

    Graven, Heather D

    2015-08-04

    Radiocarbon analyses are commonly used in a broad range of fields, including earth science, archaeology, forgery detection, isotope forensics, and physiology. Many applications are sensitive to the radiocarbon ((14)C) content of atmospheric CO2, which has varied since 1890 as a result of nuclear weapons testing, fossil fuel emissions, and CO2 cycling between atmospheric, oceanic, and terrestrial carbon reservoirs. Over this century, the ratio (14)C/C in atmospheric CO2 (Δ(14)CO2) will be determined by the amount of fossil fuel combustion, which decreases Δ(14)CO2 because fossil fuels have lost all (14)C from radioactive decay. Simulations of Δ(14)CO2 using the emission scenarios from the Intergovernmental Panel on Climate Change Fifth Assessment Report, the Representative Concentration Pathways, indicate that ambitious emission reductions could sustain Δ(14)CO2 near the preindustrial level of 0‰ through 2100, whereas "business-as-usual" emissions will reduce Δ(14)CO2 to -250‰, equivalent to the depletion expected from over 2,000 y of radioactive decay. Given current emissions trends, fossil fuel emission-driven artificial "aging" of the atmosphere is likely to occur much faster and with a larger magnitude than previously expected. This finding has strong and as yet unrecognized implications for many applications of radiocarbon in various fields, and it implies that radiocarbon dating may no longer provide definitive ages for samples up to 2,000 y old.

  10. Workshop on an Assessment of Gas-Side Fouling in Fossil Fuel Exhaust Environments

    Science.gov (United States)

    Marner, W. J. (Editor); Webb, R. L. (Editor)

    1982-01-01

    The state of the art of gas side fouling in fossil fuel exhaust environments was assessed. Heat recovery applications were emphasized. The deleterious effects of gas side fouling including increased energy consumption, increased material losses, and loss of production were identified.

  11. Fossil Fuel (CO2) Emission Verification Capability07-ERD-064Final Report

    Energy Technology Data Exchange (ETDEWEB)

    Guilderson, T. P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Cameron-Smith, P. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States); Lucas, D. D. [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2011-04-26

    This work focused exclusively on designing a system for California as a test-bed. Fossil fuel CO2 emissions account for ~96% of the total California anthropogenic CO2 emissions (CEC GHG Inventory, 2006).

  12. Nitrogen compounds in pressurised fluidised bed gasification of biomass and fossil fuels

    NARCIS (Netherlands)

    De Jong, W.

    2005-01-01

    Fossil fuels still dominate the energy supply in modern societies. The resources, however, are depleting. Therefore, other energy sources are to be exploited further within this century. Biomass is one of the practically CO2 neutral, renewable contributors to the future energy production. Nowadays

  13. CO2 emission mitigation and fossil fuel markets : Dynamic and international aspects of climate policies

    NARCIS (Netherlands)

    Bauer, Nico; Bosetti, Valentina; Hamdi-Cherif, Meriem; Kitous, Alban; McCollum, David; Méjean, Aurélie; Rao, Shilpa; Turton, Hal; Paroussos, Leonidas; Ashina, Shuichi; Calvin, Katherine; Wada, Kenichi; van Vuuren, Detlef

    2015-01-01

    This paper explores a multi-model scenario ensemble to assess the impacts of idealized and non-idealized climate change stabilization policies on fossil fuel markets. Under idealized conditions climate policies significantly reduce coal use in the short- and long-term. Reductions in oil and gas use

  14. Subsidies in WTO Law and Energy Regulation : Some Implications for Fossil Fuels and Renewable Energy

    NARCIS (Netherlands)

    Marhold, Anna

    2017-01-01

    This contribution discusses WTO subsidies disciplines in the context of the energy sector. After laying out the relevant disciplines, it will discuss the paradox of WTO law with respect to subsidies towards fossil fuels vis-à-vis those towards renewable energy. It is clear that subsidies on clean

  15. Liquid fossil-fuel technology. Quarterly technical progress report, April-June 1982

    Energy Technology Data Exchange (ETDEWEB)

    Linville, B. (ed.)

    1982-10-01

    This report primarily covers in-house oil, gas, and synfuel research and lists the contracted research. The report is broken into the following areas: liquid fossil fuel cycle, extraction, processing, utilization, and project integration and technology transfer. BETC publications are listed. (DLC)

  16. Subsidy regulation in WTO Law : Some implications for fossil fuels and renewable energy

    NARCIS (Netherlands)

    Marhold, Anna

    2016-01-01

    This contribution discusses WTO subsidies disciplines in the context of the energy sector. After laying out the relevant disciplines, it will discuss the paradox of WTO law with respect to subsidies towards fossil fuels vis-à-vis those towards renewable energy. It is clear that subsidies on clean

  17. Subsidies in WTO Law and Energy Regulation : Some Implications for Fossil Fuels and Renewable Energy

    NARCIS (Netherlands)

    Marhold, Anna

    2018-01-01

    This contribution discusses WTO subsidies disciplines in the context of the energy sector. After laying out the relevant disciplines, it will discuss the paradox of WTO law with respect to subsidies towards fossil fuels vis-à-vis those towards renewable energy. It is clear that subsidies on clean

  18. Aluminum-26 in the early solar system - Fossil or fuel

    Science.gov (United States)

    Lee, T.; Papanastassiou, D. A.; Wasserburg, G. J.

    1977-01-01

    The isotopic composition of Mg was measured in different phases of a Ca-Al-rich inclusion in the Allende meteorite. Large excesses of Mg-26 of up to 10% were found. These excesses correlate strictly with the Al-27/Mg-24 ratio for four coexisting phases with distinctive chemical compositions. Models of in situ decay of Al-26 within the solar system and of mixing of interstellar dust grains containing fossil Al-26 with normal solar system material are presented. The observed correlation provides definitive evidence for the presence of Al-26 in the early solar system. This requires either injection of freshly synthesized nucleosynthetic material into the solar system immediately before condensation and planet formation, or local production within the solar system by intense activity of the early sun. Planets promptly produced from material with the inferred Al-26/Al-27 would melt within about 300,000 years.

  19. Economic value of U.S. fossil fuel electricity health impacts.

    Science.gov (United States)

    Machol, Ben; Rizk, Sarah

    2013-02-01

    Fossil fuel energy has several externalities not accounted for in the retail price, including associated adverse human health impacts, future costs from climate change, and other environmental damages. Here, we quantify the economic value of health impacts associated with PM(2.5) and PM(2.5) precursors (NO(x) and SO(2)) on a per kilowatt hour basis. We provide figures based on state electricity profiles, national averages and fossil fuel type. We find that the economic value of improved human health associated with avoiding emissions from fossil fuel electricity in the United States ranges from a low of $0.005-$0.013/kWh in California to a high of $0.41-$1.01/kWh in Maryland. When accounting for the adverse health impacts of imported electricity, the California figure increases to $0.03-$0.07/kWh. Nationally, the average economic value of health impacts associated with fossil fuel usage is $0.14-$0.35/kWh. For coal, oil, and natural gas, respectively, associated economic values of health impacts are $0.19-$0.45/kWh, $0.08-$0.19/kWh, and $0.01-$0.02/kWh. For coal and oil, these costs are larger than the typical retail price of electricity, demonstrating the magnitude of the externality. When the economic value of health impacts resulting from air emissions is considered, our analysis suggests that on average, U.S. consumers of electricity should be willing to pay $0.24-$0.45/kWh for alternatives such as energy efficiency investments or emission-free renewable sources that avoid fossil fuel combustion. The economic value of health impacts is approximately an order of magnitude larger than estimates of the social cost of carbon for fossil fuel electricity. In total, we estimate that the economic value of health impacts from fossil fuel electricity in the United States is $361.7-886.5 billion annually, representing 2.5-6.0% of the national GDP. Published by Elsevier Ltd.

  20. Intelligent control system for the temperature regulation in a gas turbine of a combined cycle fossil fuel power plant; Sistema de control inteligente para regular la temperatura en la turbina de gas de una central termoelectrica de ciclo combinado

    Energy Technology Data Exchange (ETDEWEB)

    Espindola Vasquez, Agustin

    2004-11-15

    In the Turbogas Units (UTG short for Spanish acronym) of a Thermoelectric Power station of Combined Cycle (CTCC short for Spanish acronym), from an operative, as well as a safety standpoint the turbine blade temperature is a critical variable. The best performance of a turbogas unit based in the electrical generation is obtained when the greatest thermal efficiency is reached. From the point of view of safety, it is desirable to keep the blades temperature at the limit established by the manufacturer, guaranteeing with this, the integrity of the UTG internal parts; avoiding that great thermal efforts decrease their useful life. In order to keep the blades temperature at the established limit, the UTG control system have a supervision system of blades temperature, that system modifies the controllers reference of the speed or power PI's which regulate the fuel valve of the UTG combustion chamber. This supervision system is based on logic conditions to generate its exit signal. In the process plants whose operation is complex and its dynamic behavior is nonlinear, the strategies of control of single loop do not provide the wished performance when they are applied in control loops to regulate critical variables; thing doing necessary the design of structures with two hierarchical levels; one with direct control and the other with supervisory control. The fuzzy logic has found a wide acceptance [Chiu, 1998] when is used to handle control functions of high level which are outside of the dominion of the conventional control methods. One of these cases is the application of the fuzzy logic to the supervisory control. In this thesis document is presented the accomplishment of a temperature fuzzy supervision system in a turbogas unit, whose purpose is to keep the turbine blades temperature within the established limits, conserving a satisfactory performance from an operative, as well as a safety standpoint. The temperature supervisor was designed with base on fuzzy

  1. Determination of fossil carbon content in Swedish waste fuel by four different methods.

    Science.gov (United States)

    Jones, Frida C; Blomqvist, Evalena W; Bisaillon, Mattias; Lindberg, Daniel K; Hupa, Mikko

    2013-10-01

    This study aimed to determine the content of fossil carbon in waste combusted in Sweden by using four different methods at seven geographically spread combustion plants. In total, the measurement campaign included 42 solid samples, 21 flue gas samples, 3 sorting analyses and 2 investigations using the balance method. The fossil carbon content in the solid samples and in the flue gas samples was determined using (14)C-analysis. From the analyses it was concluded that about a third of the carbon in mixed Swedish waste (municipal solid waste and industrial waste collected at Swedish industry sites) is fossil. The two other methods (the balance method and calculations from sorting analyses), based on assumptions and calculations, gave similar results in the plants in which they were used. Furthermore, the results indicate that the difference between samples containing as much as 80% industrial waste and samples consisting of solely municipal solid waste was not as large as expected. Besides investigating the fossil content of the waste, the project was also established to investigate the usability of various methods. However, it is difficult to directly compare the different methods used in this project because besides the estimation of emitted fossil carbon the methods provide other information, which is valuable to the plant owner. Therefore, the choice of method can also be controlled by factors other than direct determination of the fossil fuel emissions when considering implementation in the combustion plants.

  2. Reconciling fossil fuel power generation development and climate issues: CCS and CCS-Ready

    Energy Technology Data Exchange (ETDEWEB)

    Paelinck, Philippe; Sonnois, Louis; Leandri, Jean-Francois

    2010-09-15

    This paper intends to analyse how CCS can contribute to reduce CO2 emissions from fossil-fuel power plants and to describe what is its current overall status. Its potential future development is assessed, in both developed and developing countries, and an economical assessment of different investment options highlight the importance of CCS retrofit. The paper analyses then the challenges of the development of fossil fuelled power plants and details case examples to illustrate some technical challenges related to CCS and what are the technical solutions available today to ease and address them: CCS-Ready power plants.

  3. On-line elemental analysis of fossil fuel process streams by inductively coupled plasma spectrometry

    Energy Technology Data Exchange (ETDEWEB)

    Chisholm, W.P.

    1995-06-01

    METC is continuing development of a real-time, multi-element plasma based spectrometer system for application to high temperature and high pressure fossil fuel process streams. Two versions are under consideration for development. One is an Inductively Coupled Plasma system that has been described previously, and the other is a high power microwave system. The ICP torch operates on a mixture of argon and helium with a conventional annular swirl flow plasma gas, no auxiliary gas, and a conventional sample stream injection through the base of the plasma plume. A new, demountable torch design comprising three ceramic sections allows bolts passing the length of the torch to compress a double O-ring seal. This improves the reliability of the torch. The microwave system will use the same data acquisition and reduction components as the ICP system; only the plasma source itself is different. It will operate with a 750-Watt, 2.45 gigahertz microwave generator. The plasma discharge will be contained within a narrow quartz tube one quarter wavelength from a shorted waveguide termination. The plasma source will be observed via fiber optics and a battery of computer controlled monochromators. To extract more information from the raw spectral data, a neural net computer program is being developed. This program will calculate analyte concentrations from data that includes analyte and interferant spectral emission intensity. Matrix effects and spectral overlaps can be treated more effectively by this method than by conventional spectral analysis.

  4. The fossil-fuels and the global warming

    Energy Technology Data Exchange (ETDEWEB)

    Remenyi, Karoly

    2010-09-15

    The earth is heated by solar radiation. One is the most important questions is the effect of the human industry. A simple model used, this gives a good result of the phenomena than difficult expressions of numerical applications. The calculation assigns a small number of parameters to the atmosphere and the Earth's surface. It is most important parameter which is changing. If decrease the atmospheric CO2 concentration on 500 ppm, the surface temperature would rise less 1 oC. The CO2 concentraton is a sensitive criterion, but not so much then we found by other models.

  5. Formulating energy policies related to fossil fuel use: Critical uncertainties in the global carbon cycle

    Energy Technology Data Exchange (ETDEWEB)

    Post, W.M.; Dale, V.H.; DeAngelis, D.L.; Mann, L.K.; Mulholland, P.J.; O' Neill, R.V.; Peng, T.-H.; Farrell, M.P.

    1990-01-01

    The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Four reservoirs can be identified, including the atmosphere, terrestrial biosphere, oceans, and sediments. Atmospheric CO{sub 2} concentration is determined by characteristics of carbon fluxes among major reservoirs of the global carbon cycle. The objective of this paper is to document the knowns, and unknowns and uncertainties associated with key questions that if answered will increase the understanding of the portion of past, present, and future atmospheric CO{sub 2} attributable to fossil fuel burning. Documented atmospheric increases in CO{sub 2} levels are thought to result primarily from fossil fuel use and, perhaps, deforestation. However, the observed atmospheric CO{sub 2} increase is less than expected from current understanding of the global carbon cycle because of poorly understood interactions among the major carbon reservoirs. 87 refs.

  6. Combustion of available fossil fuel resources sufficient to eliminate the Antarctic Ice Sheet.

    Science.gov (United States)

    Winkelmann, Ricarda; Levermann, Anders; Ridgwell, Andy; Caldeira, Ken

    2015-09-01

    The Antarctic Ice Sheet stores water equivalent to 58 m in global sea-level rise. We show in simulations using the Parallel Ice Sheet Model that burning the currently attainable fossil fuel resources is sufficient to eliminate the ice sheet. With cumulative fossil fuel emissions of 10,000 gigatonnes of carbon (GtC), Antarctica is projected to become almost ice-free with an average contribution to sea-level rise exceeding 3 m per century during the first millennium. Consistent with recent observations and simulations, the West Antarctic Ice Sheet becomes unstable with 600 to 800 GtC of additional carbon emissions. Beyond this additional carbon release, the destabilization of ice basins in both West and East Antarctica results in a threshold increase in global sea level. Unabated carbon emissions thus threaten the Antarctic Ice Sheet in its entirety with associated sea-level rise that far exceeds that of all other possible sources.

  7. Opportunities and insights for reducing fossil fuel consumption by households and organizations

    Science.gov (United States)

    Stern, Paul C.; Janda, Kathryn B.; Brown, Marilyn A.; Steg, Linda; Vine, Edward L.; Lutzenhiser, Loren

    2016-05-01

    Realizing the ambitious commitments of the 2015 Paris Climate Conference (COP21) will require new ways of meeting human needs previously met by burning fossil fuels. Technological developments will be critical, but so will accelerated adoption of promising low-emission technologies and practices. National commitments will be more achievable if interventions take into account key psychological, social, cultural and organizational factors that influence energy choices, along with factors of an infrastructural, technical and economic nature. Broader engagement of social and behavioural science is needed to identify promising opportunities for reducing fossil fuel consumption. Here we discuss opportunities for change in households and organizations, primarily at short and intermediate timescales, and identify opportunities that have been underused in much of energy policy. Based on this survey, we suggest design principles for interventions by governments and other organizations, and identify areas of emphasis for future social science and interdisciplinary research.

  8. Formulating Energy Policies Related to Fossil Fuel Use: Critical Uncertainties in the Global Carbon Cycle

    Science.gov (United States)

    Post, W. M.; Dale, V. H.; DeAngelis, D. L.; Mann, L. K.; Mulholland, P. J.; O`Neill, R. V.; Peng, T. -H.; Farrell, M. P.

    1990-02-01

    The global carbon cycle is the dynamic interaction among the earth's carbon sources and sinks. Four reservoirs can be identified, including the atmosphere, terrestrial biosphere, oceans, and sediments. Atmospheric CO{sub 2} concentration is determined by characteristics of carbon fluxes among major reservoirs of the global carbon cycle. The objective of this paper is to document the knowns, and unknowns and uncertainties associated with key questions that if answered will increase the understanding of the portion of past, present, and future atmospheric CO{sub 2} attributable to fossil fuel burning. Documented atmospheric increases in CO{sub 2} levels are thought to result primarily from fossil fuel use and, perhaps, deforestation. However, the observed atmospheric CO{sub 2} increase is less than expected from current understanding of the global carbon cycle because of poorly understood interactions among the major carbon reservoirs.

  9. Innovative Fresh Water Production Process for Fossil Fuel Plants

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight; Venugopal Jogi

    2005-09-01

    This project concerns a diffusion driven desalination (DDD) process where warm water is evaporated into a low humidity air stream, and the vapor is condensed out to produce distilled water. Although the process has a low fresh water to feed water conversion efficiency, it has been demonstrated that this process can potentially produce low cost distilled water when driven by low grade waste heat. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A dynamic analysis of heat and mass transfer demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3 Hg. The optimum operating condition for the DDD process with a high temperature of 50 C and sink temperature of 25 C has an air mass flux of 1.5 kg/m{sup 2}-s, air to feed water mass flow ratio of 1 in the diffusion tower, and a fresh water to air mass flow ratio of 2 in the condenser. Operating at these conditions yields a fresh water production efficiency (m{sub fW}/m{sub L}) of 0.031 and electric energy consumption rate of 0.0023 kW-hr/kg{sub fW}. Throughout the past year, the main focus of the desalination process has been on the direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. The analyses agree quite well with the current data. Recently, it has been recognized that the fresh water production efficiency can be significantly enhanced with air heating. This type of configuration is well suited for power plants utilizing air-cooled condensers. The experimental DDD facility has been modified with an air heating section, and temperature and humidity data have been collected over a range of flow and thermal conditions. It has been experimentally observed that the fresh water production rate is enhanced when air

  10. Organic farming without fossil fuels - life cycle assessment of two Swedish cases

    OpenAIRE

    Sundberg, C; Kimming, M.; Nordberg, Å.; Baky, A; Hansson, P.-A.

    2013-01-01

    Organic agriculture is dependent on fossil fuels, just like conventional agriculture, but this can be reduced by the use of on-farm biomass resources. The energy efficiency and environmental impacts of different alternatives can be assessed by life cycle assessment (LCA), which we have done in this project. Swedish organic milk production can become self-sufficient in energy by using renewable sources available on the farm, with biogas from manure as the main energy source. Thereby greenhouse...

  11. A multiyear, global gridded fossil fuel CO2 emission data product: Evaluation and analysis of results

    Science.gov (United States)

    Asefi-Najafabady, S.; Rayner, P. J.; Gurney, K. R.; McRobert, A.; Song, Y.; Coltin, K.; Huang, J.; Elvidge, C.; Baugh, K.

    2014-09-01

    High-resolution, global quantification of fossil fuel CO2 emissions is emerging as a critical need in carbon cycle science and climate policy. We build upon a previously developed fossil fuel data assimilation system (FFDAS) for estimating global high-resolution fossil fuel CO2 emissions. We have improved the underlying observationally based data sources, expanded the approach through treatment of separate emitting sectors including a new pointwise database of global power plants, and extended the results to cover a 1997 to 2010 time series at a spatial resolution of 0.1°. Long-term trend analysis of the resulting global emissions shows subnational spatial structure in large active economies such as the United States, China, and India. These three countries, in particular, show different long-term trends and exploration of the trends in nighttime lights, and population reveal a decoupling of population and emissions at the subnational level. Analysis of shorter-term variations reveals the impact of the 2008-2009 global financial crisis with widespread negative emission anomalies across the U.S. and Europe. We have used a center of mass (CM) calculation as a compact metric to express the time evolution of spatial patterns in fossil fuel CO2 emissions. The global emission CM has moved toward the east and somewhat south between 1997 and 2010, driven by the increase in emissions in China and South Asia over this time period. Analysis at the level of individual countries reveals per capita CO2 emission migration in both Russia and India. The per capita emission CM holds potential as a way to succinctly analyze subnational shifts in carbon intensity over time. Uncertainties are generally lower than the previous version of FFDAS due mainly to an improved nightlight data set.

  12. The limits of bioenergy for mitigating global life-cycle greenhouse gas emissions from fossil fuels

    Science.gov (United States)

    Staples, Mark D.; Malina, Robert; Barrett, Steven R. H.

    2017-01-01

    The size of the global bioenergy resource has been studied extensively; however, the corresponding life-cycle greenhouse gas benefit of bioenergy remains largely unexplored at the global scale. Here we quantify the optimal use of global bioenergy resources to offset fossil fuels in 2050. We find that bioenergy could reduce life-cycle emissions from fossil fuel-derived electricity and heat, and liquid fuels, by a maximum of 4.9-38.7 Gt CO2e, or 9-68%, and that offsetting electricity and heat with bioenergy is on average 1.6-3.9 times more effective for emissions mitigation than offsetting liquid fuels. At the same time, liquid fuels make up 18-49% of the optimal allocation of bioenergy in our results for 2050, indicating that a mix of bioenergy end-uses maximizes life-cycle emissions reductions. Finally, emissions reductions are maximized by limiting deployment of total available primary bioenergy to 29-91% in our analysis, demonstrating that life-cycle emissions are a constraint on the usefulness of bioenergy for mitigating global climate change.

  13. Evaluation of sustainability by a population living near fossil fuel resources in Northwestern Greece.

    Science.gov (United States)

    Vatalis, Konstantinos I

    2010-12-01

    The emergence of sustainability as a goal in the management of fossil fuel resources is a result of the growing global environmental concern, and highlights some of the issues expected to be significant in coming years. In order to secure social acceptance, the mining industry has to face these challenges by engaging its many different stakeholders and examining their sustainability concerns. For this reason a questionnaire was conducted involving a simple random sampling of inhabitants near an area rich in fossil fuel resources, in order to gather respondents' views on social, economic and environmental benefits. The study discusses new subnational findings on public attitudes to regional sustainability, based on a quantitative research design. The site of the study was the energy-rich Greek region of Kozani, Western Macedonia, one of the country's energy hubs. The paper examines the future perspectives of the area. The conclusions can form a useful framework for energy policy in the wider Balkan area, which contains important fossil fuel resources. Copyright © 2010 Elsevier Ltd. All rights reserved.

  14. Nitrogen Isotope Composition of Thermally Produced NOx from Various Fossil-Fuel Combustion Sources.

    Science.gov (United States)

    Walters, Wendell W; Tharp, Bruce D; Fang, Huan; Kozak, Brian J; Michalski, Greg

    2015-10-06

    The nitrogen stable isotope composition of NOx (δ(15)N-NOx) may be a useful indicator for NOx source partitioning, which would help constrain NOx source contributions in nitrogen deposition studies. However, there is large uncertainty in the δ(15)N-NOx values for anthropogenic sources other than on-road vehicles and coal-fired energy generating units. To this end, this study presents a broad analysis of δ(15)N-NOx from several fossil-fuel combustion sources that includes: airplanes, gasoline-powered vehicles not equipped with a three-way catalytic converter, lawn equipment, utility vehicles, urban buses, semitrucks, residential gas furnaces, and natural-gas-fired power plants. A relatively large range of δ(15)N-NOx values was measured from -28.1‰ to 8.5‰ for individual exhaust/flue samples that generally tended to be negative due to the kinetic isotope effect associated with thermal NOx production. A negative correlation between NOx concentrations and δ(15)N-NOx for fossil-fuel combustion sources equipped with selective catalytic reducers was observed, suggesting that the catalytic reduction of NOx increases δ(15)N-NOx values relative to the NOx produced through fossil-fuel combustion processes. Combining the δ(15)N-NOx measured in this study with previous published values, a δ(15)N-NOx regional and seasonal isoscape was constructed for the contiguous U.S., which demonstrates seasonal and regional importance of various NOx sources.

  15. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Mohamed Darwish; Diego Acevedo; Jessica Knight

    2003-09-01

    This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system, which is powered by the waste heat from low pressure condensing steam in power plants. The desalination is driven by water vapor saturating dry air flowing through a diffusion tower. Liquid water is condensed out of the air/vapor mixture in a direct contact condenser. A thermodynamic analysis demonstrates that the DDD process can yield a fresh water production efficiency of 4.5% based on a feed water inlet temperature of only 50 C. An example is discussed in which the DDD process utilizes waste heat from a 100 MW steam power plant to produce 1.51 million gallons of fresh water per day. The main focus of the initial development of the desalination process has been on the diffusion tower. A detailed mathematical model for the diffusion tower has been described, and its numerical implementation has been used to characterize its performance and provide guidance for design. The analysis has been used to design a laboratory scale diffusion tower, which has been thoroughly instrumented to allow detailed measurements of heat and mass transfer coefficient, as well as fresh water production efficiency. The experimental facility has been described in detail.

  16. INNOVATIVE FRESH WATER PRODUCTION PROCESS FOR FOSSIL FUEL PLANTS

    Energy Technology Data Exchange (ETDEWEB)

    James F. Klausner; Renwei Mei; Yi Li; Jessica Knight

    2004-09-01

    An innovative Diffusion Driven Desalination (DDD) process was recently described where evaporation of mineralized water is driven by diffusion within a packed bed. The energy source to drive the process is derived from low pressure condensing steam within the main condenser of a steam power generating plant. Since waste heat is used to drive the process, the main cost of fresh water production is attributed to the energy cost of pumping air and water through the packed bed. This report describes the annual progress made in the development and analysis of a Diffusion Driven Desalination (DDD) system. A combined thermodynamic and dynamic analysis demonstrates that the DDD process can yield a fresh water production of 1.03 million gallon/day by utilizing waste heat from a 100 MW steam power plant based on a condensing steam pressure of only 3'' Hg. Throughout the past year, the main focus of the desalination process has been on the diffusion tower and direct contact condenser. Detailed heat and mass transfer analyses required to size and analyze these heat and mass transfer devices are described. An experimental DDD facility has been fabricated, and temperature and humidity data have been collected over a range of flow and thermal conditions. The analyses agree quite well with the current data and the information available in the literature. Direct contact condensers with and without packing have been investigated. It has been experimentally observed that the fresh water production rate is significantly enhanced when packing is added to the direct contact condensers.

  17. The first 1-year-long estimate of the Paris region fossil fuel CO2 emissions based on atmospheric inversion

    Science.gov (United States)

    Staufer, Johannes; Broquet, Grégoire; Bréon, François-Marie; Puygrenier, Vincent; Chevallier, Frédéric; Xueref-Rémy, Irène; Dieudonné, Elsa; Lopez, Morgan; Schmidt, Martina; Ramonet, Michel; Perrussel, Olivier; Lac, Christine; Wu, Lin; Ciais, Philippe

    2016-11-01

    The ability of a Bayesian atmospheric inversion to quantify the Paris region's fossil fuel CO2 emissions on a monthly basis, based on a network of three surface stations operated for 1 year as part of the CO2-MEGAPARIS experiment (August 2010-July 2011), is analysed. Differences in hourly CO2 atmospheric mole fractions between the near-ground monitoring sites (CO2 gradients), located at the north-eastern and south-western edges of the urban area, are used to estimate the 6 h mean fossil fuel CO2 emission. The inversion relies on the CHIMERE transport model run at 2 km × 2 km horizontal resolution, on the spatial distribution of fossil fuel CO2 emissions in 2008 from a local inventory established at 1 km × 1 km horizontal resolution by the AIRPARIF air quality agency, and on the spatial distribution of the biogenic CO2 fluxes from the C-TESSEL land surface model. It corrects a prior estimate of the 6 h mean budgets of the fossil fuel CO2 emissions given by the AIRPARIF 2008 inventory. We found that a stringent selection of CO2 gradients is necessary for reliable inversion results, due to large modelling uncertainties. In particular, the most robust data selection analysed in this study uses only mid-afternoon gradients if wind speeds are larger than 3 m s-1 and if the modelled wind at the upwind site is within ±15° of the transect between downwind and upwind sites. This stringent data selection removes 92 % of the hourly observations. Even though this leaves few remaining data to constrain the emissions, the inversion system diagnoses that their assimilation significantly reduces the uncertainty in monthly emissions: by 9 % in November 2010 to 50 % in October 2010. The inverted monthly mean emissions correlate well with independent monthly mean air temperature. Furthermore, the inverted annual mean emission is consistent with the independent revision of the AIRPARIF inventory for the year 2010, which better corresponds to the measurement period than the 2008

  18. The first 1-year-long estimate of the Paris region fossil fuel CO2 emissions based on atmospheric inversion

    Directory of Open Access Journals (Sweden)

    J. Staufer

    2016-11-01

    Full Text Available The ability of a Bayesian atmospheric inversion to quantify the Paris region's fossil fuel CO2 emissions on a monthly basis, based on a network of three surface stations operated for 1 year as part of the CO2-MEGAPARIS experiment (August 2010–July 2011, is analysed. Differences in hourly CO2 atmospheric mole fractions between the near-ground monitoring sites (CO2 gradients, located at the north-eastern and south-western edges of the urban area, are used to estimate the 6 h mean fossil fuel CO2 emission. The inversion relies on the CHIMERE transport model run at 2 km  ×  2 km horizontal resolution, on the spatial distribution of fossil fuel CO2 emissions in 2008 from a local inventory established at 1 km  ×  1 km horizontal resolution by the AIRPARIF air quality agency, and on the spatial distribution of the biogenic CO2 fluxes from the C-TESSEL land surface model. It corrects a prior estimate of the 6 h mean budgets of the fossil fuel CO2 emissions given by the AIRPARIF 2008 inventory. We found that a stringent selection of CO2 gradients is necessary for reliable inversion results, due to large modelling uncertainties. In particular, the most robust data selection analysed in this study uses only mid-afternoon gradients if wind speeds are larger than 3 m s−1 and if the modelled wind at the upwind site is within ±15° of the transect between downwind and upwind sites. This stringent data selection removes 92 % of the hourly observations. Even though this leaves few remaining data to constrain the emissions, the inversion system diagnoses that their assimilation significantly reduces the uncertainty in monthly emissions: by 9 % in November 2010 to 50 % in October 2010. The inverted monthly mean emissions correlate well with independent monthly mean air temperature. Furthermore, the inverted annual mean emission is consistent with the independent revision of the AIRPARIF inventory for the year

  19. Carbon Monitoring System Flux for Fossil Fuel L4 V1 (CMSFluxFossilfuel) at GES DISC

    Data.gov (United States)

    National Aeronautics and Space Administration — This dataset provides the Carbon Flux for Fossil Fuel. The NASA Carbon Monitoring System (CMS) is designed to make significant contributions in characterizing,...

  20. Time scales and ratios of climate forcing due to thermal versus carbon dioxide emissions from fossil fuels

    Science.gov (United States)

    Zhang, Xiaochun; Caldeira, Ken

    2015-06-01

    The Earth warms both when fossil fuel carbon is oxidized to carbon dioxide and when greenhouse effect of carbon dioxide inhibits longwave radiation from escaping to space. Various important time scales and ratios comparing these two climate forcings have not previously been quantified. For example, the global and time-integrated radiative forcing from burning a fossil fuel exceeds the heat released upon combustion within 2 months. Over the long lifetime of CO2 in the atmosphere, the cumulative CO2-radiative forcing exceeds the amount of energy released upon combustion by a factor >100,000. For a new power plant, the radiative forcing from the accumulation of released CO2 exceeds the direct thermal emissions in less than half a year. Furthermore, we show that the energy released from the combustion of fossil fuels is now about 1.71% of the radiative forcing from CO2 that has accumulated in the atmosphere as a consequence of historical fossil fuel combustion.

  1. Challenges faced when using radiocarbon measurements to estimate fossil fuel emissions in the UK.

    Science.gov (United States)

    Wenger, A.; O'Doherty, S.; Rigby, M. L.; Ganesan, A.; Manning, A.; Allen, G.

    2015-12-01

    Estimating the anthropogenic component of carbon dioxide emissions from direct atmospheric measurements is difficult, due to the large natural carbon dioxide fluxes. One way of determining the fossil fuel component of atmospheric carbon dioxide is the use of radiocarbon measurements. Whilst carbon reservoirs with a reasonably fast carbon exchange rate all have a similar radiocarbon content, fossil fuels are completely devoid of radiocarbon due to their age. Previous studies have 14CO2 (UK) this approach is compromised by the high density of 14CO2 emitting nuclear power plants. Of the 16 nuclear reactors in the UK, 14 are advanced gas cooled reactors, which have one of the highest 14CO2 emission rates of all reactor types. These radiocarbon emissions not only lead to a serious underestimation of the recently added fossil fuel CO2, by masking the depletion of 14C in CO2, but can in fact overshadow the depletion by a factor of 2 or more. While a correction for this enhancement can be applied, the emissions from the nuclear power plants are highly variable, and an accurate correction is therefore not straightforward. We present the first attempt to quantify UK fossil fuel CO2 emissions through the use of 14CO2. We employ a sampling strategy that makes use of a Lagrangian particle dispersion model, in combination with nuclear industry emission estimates, to forecast "good" sampling times, in an attempt to minimize the correction due to emissions from the nuclear industry. As part of the Greenhouse gAs Uk and Global Emissions (GAUGE) project, 14CO2measurements are performed at two measurement sites in the UK and Ireland, as well as during science flights around the UK. The measurement locations have been chosen with a focus on high emitting regions such as London and the Midlands. We discuss the unique challenges that face the determination of fossil fuel emissions through radiocarbon measurements in the UK and our sampling strategy to deal with them. In addition we

  2. Contributions of Fossil Fuel Combustion to Winter-time Arctic Aerosols

    Science.gov (United States)

    Barrett, T. E.; Usenko, S.; Robinson, E.; Sheesley, R. J.

    2014-12-01

    Over the last century, the Arctic has been warming at a rate almost twice the global average. Aerosols both directly and indirectly affect the radiative balance of the Arctic through the absorption and scattering of sunlight and by providing a source of cloud and ice condensation nuclei. Global climate models currently have difficulty reproducing the observed warming in the Arctic but could be improved through high temporal resolution measurements of aerosols and their sources. This study focuses on the quantification of fossil fuel and biomass combustion contributions to particulate organic carbon (OC) collected during a winter sampling campaign in the North Slope Alaska. Samples were collected at the Department of Energy Atmospheric Radiation Measurement (ARM) climate research facility in Barrow, AK, USA. Particulate matter (PM10) samples collected from December 2012 to March 2013 were analyzed for organic tracer analysis combined with radiocarbon of elemental and organic carbon (EC and OC). Organic tracers, including polycyclic aromatic hydrocarbons (PAHs), alkanes, hopanes and levoglucosan, were quantified using gas chromatography-mass spectrometry (GCMS). These tracers, commonly used as molecular markers for anthropogenic combustion sources, were then used in a molecular-marker chemical mass balance (CMB) model. Results from the CMB were then combined with radiocarbon (14C) abundance measurements. Radiocarbon analysis differentiates between fossil fuel combustion and biomass burning based on the large difference in end members between fossil and contemporary carbon. Radiocarbon results show an average fossil contribution of 44% to Arctic OC from with spark ignition (gasoline) and compression ignition (diesel) engines being implicated as major sources of fossil OC to Arctic aerosols. The 14C analysis and CMB source apportionment will be combined with back trajectory (BT) to assess the impact of geographic source regions on carbonaceous aerosol burden in the

  3. Climate change adaptation, damages and fossil fuel dependence. An RETD position paper on the costs of inaction

    Energy Technology Data Exchange (ETDEWEB)

    Katofsky, Ryan; Stanberry, Matt; Hagenstad, Marca; Frantzis, Lisa

    2011-07-15

    The Renewable Energy Technology Deployment (RETD) agreement initiated this project to advance the understanding of the ''Costs of Inaction'', i.e. the costs of climate change adaptation, damages and fossil fuel dependence. A quantitative estimate was developed as well as a better understanding of the knowledge gaps and research needs. The project also included some conceptual work on how to better integrate the analyses of mitigation, adaptation, damages and fossil fuel dependence in energy scenario modelling.

  4. Multiregional environmental comparison of fossil fuel power generation-Assessment of the contribution of fugitive emissions from conventional and unconventional fossil resources

    NARCIS (Netherlands)

    Bouman, Evert A.; Ramirez, Andrea; Hertwich, Edgar G.

    2015-01-01

    In this paper we investigate the influence of fugitive methane emissions from coal, natural gas, and shale gas extraction on the greenhouse gas (GHG) impacts of fossil fuel power generation through its life cycle. A multiregional hybridized life cycle assessment (LCA) model is used to evaluate

  5. Solar fuels production as a sustainable alternative for substituting fossil fuels: COSOLπ project

    Science.gov (United States)

    Hernando Romero-Paredes, R.; Alvarado-Gil, Juan José; Arancibia-Bulnes, Camilo Alberto; Ramos-Sánchez, Víctor Hugo; Villafán-Vidales, Heidi Isabel; Espinosa-Paredes, Gilberto; Abanades, Stéphane

    2017-06-01

    This article presents, in summary form, the characteristics of COSOLπ development project and some of the results obtained to date. The benefits of the work of this project will include the generation of a not polluting transportable energy feedstock from a free, abundant and available primary energy source, in an efficient method with no greenhouse gas emission. This will help to ensure energy surety to a future transportation/energy infrastructure, without any fuel import. Further technological development of thermochemical production of clean fuels, together with solar reactors and also with the possibility of determining the optical and thermal properties of the materials involved a milestone in the search for new processes for industrialization. With the above in mind, important national academic institutions: UAM, UNAM, CINVESTAV, UACH, UNISON among others, have been promoting research in solar energy technologies. The Goals and objectives are to conduct research and technological development driving high-temperature thermochemical processes using concentrated solar radiation as thermal energy source for the future sustainable development of industrial processes. It focuses on the production of clean fuels such as H2, syngas, biofuels, without excluding the re-value of materials used in the industry. This project conducts theoretical and experimental studies for the identification, characterization, and optimization of the most promising thermochemical cycles, and for the thorough investigation of the reactive chemical systems. It applies material science and nano-engineering to improve chemicals properties and stability upon cycling. The characterization of materials will serve to measure the chemical composition and purity (MOX fraction-1) of each of the samples. The characterizations also focus on the solid particle morphology (shape, size, state of aggregation, homogeneity, specific surface) images obtained from SEM / TEM and BET measurements. Likewise

  6. Development of Nuclear Renewable Oil Shale Systems for Flexible Electricity and Reduced Fossil Fuel Emissions

    Energy Technology Data Exchange (ETDEWEB)

    Daniel Curtis; Charles Forsberg; Humberto Garcia

    2015-05-01

    We propose the development of Nuclear Renewable Oil Shale Systems (NROSS) in northern Europe, China, and the western United States to provide large supplies of flexible, dispatchable, very-low-carbon electricity and fossil fuel production with reduced CO2 emissions. NROSS are a class of large hybrid energy systems in which base-load nuclear reactors provide the primary energy used to produce shale oil from kerogen deposits and simultaneously provide flexible, dispatchable, very-low-carbon electricity to the grid. Kerogen is solid organic matter trapped in sedimentary shale, and large reserves of this resource, called oil shale, are found in northern Europe, China, and the western United States. NROSS couples electricity generation and transportation fuel production in a single operation, reduces lifecycle carbon emissions from the fuel produced, improves revenue for the nuclear plant, and enables a major shift toward a very-low-carbon electricity grid. NROSS will require a significant development effort in the United States, where kerogen resources have never been developed on a large scale. In Europe, however, nuclear plants have been used for process heat delivery (district heating), and kerogen use is familiar in certain countries. Europe, China, and the United States all have the opportunity to use large scale NROSS development to enable major growth in renewable generation and either substantially reduce or eliminate their dependence on foreign fossil fuel supplies, accelerating their transitions to cleaner, more efficient, and more reliable energy systems.

  7. GASEOUS EMISSIONS FROM FOSSIL FUELS AND BIOMASS COMBUSTION IN SMALL HEATING APPLIANCES

    Directory of Open Access Journals (Sweden)

    Daniele Dell'Antonia

    2012-06-01

    Full Text Available The importance of emission control has increased sharply due to the increased need of energy from combustion. However, biomass utilization in energy production is not free from problems because of physical and chemical characteristics which are substantially different from conventional energy sources. In this situation, the quantity and quality of emissions as well as used renewable sources as wood or corn grain are often unknown. To assess this problem the paper addresses the objectives to quantify the amount of greenhouse gases during the combustion of corn as compared to the emissions in fossil combustion (natural gas, LPG and diesel boiler. The test was carried out in Friuli Venezia Giulia in 2006-2008 to determine the air pollution (CO, NO, NO2, NOx, SO2 and CO2 from fuel combustion in family boilers with a power between 20-30 kWt. The flue gas emission was measured with a professional semi-continuous multi-gas analyzer, (Vario plus industrial, MRU air Neckarsulm-Obereisesheim. Data showed a lower emission of fossil fuel compared to corn in family boilers in reference to pollutants in the flue gas (NOx, SO2 and CO. In a particular way the biomass combustion makes a higher concentration of carbon monoxide (for an incomplete combustion because there is not a good mixing between fuel and air and nitrogen oxides (in relation at a higher content of nitrogen in herbaceous biomass in comparison to another fuel.

  8. Presence of estrogenic activity from emission of fossil fuel combustion as detected by a recombinant yeast bioassay

    Science.gov (United States)

    Wang, Jingxian; Wu, Wenzhong; Henkelmann, Bernhard; You, Li; Kettrup, Antonius; Schramm, Karl-Werner

    Estrogenic activities of emission samples generated by fossil fuel combustion were investigated with human estrogen receptor (ER) recombinant yeast bioassay. The results showed that there were weak but clear estrogenic activities in combustion emissions of fossil fuels including coal, petroleum, and diesel. The estrogenic relative potency (RP) of fossil fuel combustion was the highest in petroleum-fired car, followed by coal-fired stove, diesel-fired agrimotor, coal-fired electric power station. On the other hand, the estrogenic relative inductive efficiency (RIE) was the highest in coal-fired stove and coal-fired electric power station, followed by petroleum-fired car and diesel-fired agrimotor. The estrogenic activities in the sub-fractions from chromatographic separation of emitted materials were also determined. The results indicated that different chemical fractions in these complex systems have different estrogenic potencies. The GC/MS analysis of the emission showed that there were many aromatic carbonyls, big molecular alcohol, PAHs and derivatives, and substituted phenolic compounds and derivatives which have been reported as environmental estrogens. The existence of estrogenic substances in fossil fuel combustion demands further investigation of their potential adverse effects on human and on the ecosystem. The magnitude of pollution due to global usage of fossil fuels makes it imperative to understand the issue of fossil fuel-derived endocrine activities and the associated health risks, particularly the aggregated risks stemmed from exposure to toxicants of multiple sources.

  9. Ambient measurements and source apportionment of fossil fuel and biomass burning black carbon in Ontario

    Science.gov (United States)

    Healy, R. M.; Sofowote, U.; Su, Y.; Debosz, J.; Noble, M.; Jeong, C.-H.; Wang, J. M.; Hilker, N.; Evans, G. J.; Doerksen, G.; Jones, K.; Munoz, A.

    2017-07-01

    Black carbon (BC) is of significant interest from a human exposure perspective but also due to its impacts as a short-lived climate pollutant. In this study, sources of BC influencing air quality in Ontario, Canada were investigated using nine concurrent Aethalometer datasets collected between June 2015 and May 2016. The sampling sites represent a mix of background and near-road locations. An optical model was used to estimate the relative contributions of fossil fuel combustion and biomass burning to ambient concentrations of BC at every site. The highest annual mean BC concentration was observed at a Toronto highway site, where vehicular traffic was found to be the dominant source. Fossil fuel combustion was the dominant contributor to ambient BC at all sites in every season, while the highest seasonal biomass burning mass contribution (35%) was observed in the winter at a background site with minimal traffic contributions. The mass absorption cross-section of BC was also investigated at two sites, where concurrent thermal/optical elemental carbon data were available, and was found to be similar at both locations. These results are expected to be useful for comparing the optical properties of BC at other near-road environments globally. A strong seasonal dependence was observed for fossil fuel BC at every Ontario site, with mean summer mass concentrations higher than their respective mean winter mass concentrations by up to a factor of two. An increased influence from transboundary fossil fuel BC emissions originating in Michigan, Ohio, Pennsylvania and New York was identified for the summer months. The findings reported here indicate that BC should not be considered as an exclusively local pollutant in future air quality policy decisions. The highest seasonal difference was observed at the highway site, however, suggesting that changes in fuel composition may also play an important role in the seasonality of BC mass concentrations in the near-road environment

  10. Emission of greenhouse gases from the use of fossil fuels in Ibague, Tolima (Colombia

    Directory of Open Access Journals (Sweden)

    Hernán Jair Andrade-Castañeda

    2017-01-01

    Full Text Available Climate change is caused by the increase of concen-trations of greenhouse gases (ghg, especially CO2, caused by the proliferation of fossil fuels use. Forest systems can capture carbon in biomass and mitigate the climate change problem. The aim of this research was to estimate the emission of ghg from the sale of fossil fuels in the city of Ibague and propose options of mitigation with productive systems in Tolima. Throughout a review, the total number of service stations in the city urban area was determined. Carrying on interviews to employers that attend public, the sales of fossil fuels (gasoline, diesel and ResumoA mudança climática é causada pelo aumento das concentrações dos gases de efeito estufa (gei, especialmente, pelo CO2 produzido pela prolife-ração do uso de combustíveis fósseis. Os sistemas forestais podem absorver carbono na biomassa e mitigar o problema da mudança climática. O objetivo do estudo foi estimar a emissão de geide acordo com a venda de combustíveis fósseis em Ibagué e plantear opções de mitigação com sistemas de produção no Tolima. Mediante revisão de literatura, determinou-se o número de postos de gasolina no perímetro urbano de Ibagué. Através de enquetes a empregados que atendem ao público, natural gas vehicle-ngv, were determined and based on the total number of stations and emission factors, it was estimated the total emission from each fuel in the city. Some mitigation options, such as coffee, cocoa and teak plantations have been proposed. It was estimated an emission of 368 Gg CO2/year (1 Gg = 10⁹ g from sales of fuels, equivalent to 718 kg CO2/person/year. These ghgemissions should be mitigated with reduction in the use of fossil fuels or throughout establishment of agricultural and forestry production systems which allows fixating CO2

  11. Preliminary carbon isotope measurements of fossil fuel and biogenic emissions from the Brazilian Southeastern region

    Science.gov (United States)

    Oliveira, F. M.; Santos, G.; Macario, K.; Muniz, M.; Queiroz, E.; Park, J.

    2014-12-01

    Researchers have confirmed that the continuing global rising of atmospheric CO2 content is caused by anthropogenic CO2 contributions. Most of those contributions are essentially associated with burning of fossil fuels (coal, petroleum and natural gas). However, deforestation, biomass burning, and land use changes, can also play important roles. Researchers have showed that 14C measurements of annual plants, such as corn leaf (Hsueh et al. 2007), annual grasses (Wang and Pataki 2012), and leaves of deciduous trees (Park et al. 2013) can be used to obtain time-integrated information of the fossil fuel ration in the atmosphere. Those regional-scale fossil fuel maps are essential for monitoring CO2 emissions mitigation efforts and/or growth spikes around the globe. However, no current data from anthropogenic contributions from both biogenic and fossil carbon has been reported from the major urban areas of Brazil. Here we make use of carbon isotopes (13C and 14C) to infer sources of CO2 in the highly populated Brazilian Southeastern region (over 80 million in 2010). This region leads the country in population, urban population, population density, vehicles, industries, and many other utilities and major infrastructures. For a starting point, we focus on collecting Ipê leaves (Tabebuia, a popular deciduous tree) from across Rio de Janeiro city and state as well as Sao Paulo city during May/June of 2014 to obtain the regional distribution of 13C and 14C of those urban domes. So far, Δ14C range from -10 to 32‰, when δ13C values are running from -26 to -35‰. The result of these preliminary investigations will be presented and discussed.Hsueh et al. 2007 Regional patterns of radiocarbon and fossil fuel-derived CO2 in surface air across North America. Geophysical Research Letters. 34: L02816. doi:10.1029/2006GL027032 Wang and Pataki 2012 Drivers of spatial variability in urban plant and soil isotopic composition in the Los Angeles Basin. Plant and Soil 350: 323

  12. Reduced carbon emission estimates from fossil fuel combustion and cement production in China.

    Science.gov (United States)

    Liu, Zhu; Guan, Dabo; Wei, Wei; Davis, Steven J; Ciais, Philippe; Bai, Jin; Peng, Shushi; Zhang, Qiang; Hubacek, Klaus; Marland, Gregg; Andres, Robert J; Crawford-Brown, Douglas; Lin, Jintai; Zhao, Hongyan; Hong, Chaopeng; Boden, Thomas A; Feng, Kuishuang; Peters, Glen P; Xi, Fengming; Liu, Junguo; Li, Yuan; Zhao, Yu; Zeng, Ning; He, Kebin

    2015-08-20

    Nearly three-quarters of the growth in global carbon emissions from the burning of fossil fuels and cement production between 2010 and 2012 occurred in China. Yet estimates of Chinese emissions remain subject to large uncertainty; inventories of China's total fossil fuel carbon emissions in 2008 differ by 0.3 gigatonnes of carbon, or 15 per cent. The primary sources of this uncertainty are conflicting estimates of energy consumption and emission factors, the latter being uncertain because of very few actual measurements representative of the mix of Chinese fuels. Here we re-evaluate China's carbon emissions using updated and harmonized energy consumption and clinker production data and two new and comprehensive sets of measured emission factors for Chinese coal. We find that total energy consumption in China was 10 per cent higher in 2000-2012 than the value reported by China's national statistics, that emission factors for Chinese coal are on average 40 per cent lower than the default values recommended by the Intergovernmental Panel on Climate Change, and that emissions from China's cement production are 45 per cent less than recent estimates. Altogether, our revised estimate of China's CO2 emissions from fossil fuel combustion and cement production is 2.49 gigatonnes of carbon (2 standard deviations = ±7.3 per cent) in 2013, which is 14 per cent lower than the emissions reported by other prominent inventories. Over the full period 2000 to 2013, our revised estimates are 2.9 gigatonnes of carbon less than previous estimates of China's cumulative carbon emissions. Our findings suggest that overestimation of China's emissions in 2000-2013 may be larger than China's estimated total forest sink in 1990-2007 (2.66 gigatonnes of carbon) or China's land carbon sink in 2000-2009 (2.6 gigatonnes of carbon).

  13. Steam and partial oxidation reforming options for hydrogen production from fossil fuels for PEM fuel cells

    Directory of Open Access Journals (Sweden)

    Yousri M.A. Welaya

    2012-06-01

    Full Text Available Proton exchange membrane fuel cell (PEM generates electrical power from air and from hydrogen or hydrogen rich gas mixtures. Therefore, there is an increasing interest in converting current hydrocarbon based marine fuels such as natural gas, gasoline, and diesel into hydrogen rich gases acceptable to the PEM fuel cells on board ships. Using chemical flow sheeting software, the total system efficiency has been calculated. Natural gas appears to be the best fuel for hydrogen rich gas production due to its favorable composition of lower molecular weight compounds. This paper presents a study for a 250 kW net electrical power PEM fuel cell system utilizing a partial oxidation in one case study and steam reformers in the second. This study has shown that steam-reforming process is the most competitive fuel processing option in terms of fuel processing efficiency. Partial oxidation process has proved to posses the lowest fuel processing efficiency. Among the options studied, the highest fuel processing efficiency is achieved with natural gas steam reforming system.

  14. Research of fuel temperature control in fuel pipeline of diesel engine using positive temperature coefficient material

    Directory of Open Access Journals (Sweden)

    Xiaolu Li

    2016-01-01

    Full Text Available As fuel temperature increases, both its viscosity and surface tension decrease, and this is helpful to improve fuel atomization and then better combustion and emission performances of engine. Based on the self-regulated temperature property of positive temperature coefficient material, this article used a positive temperature coefficient material as electric heating element to heat diesel fuel in fuel pipeline of diesel engine. A kind of BaTiO3-based positive temperature coefficient material, with the Curie temperature of 230°C and rated voltage of 24 V, was developed, and its micrograph and element compositions were also analyzed. By the fuel pipeline wrapped in six positive temperature coefficient ceramics, its resistivity–temperature and heating characteristics were tested on a fuel pump bench. The experiments showed that in this installation, the surface temperature of six positive temperature coefficient ceramics rose to the equilibrium temperature only for 100 s at rated voltage. In rated power supply for six positive temperature coefficient ceramics, the temperature of injection fuel improved for 21°C–27°C within 100 s, and then could keep constant. Using positive temperature coefficient material to heat diesel in fuel pipeline of diesel engine, the injection mass per cycle had little change, approximately 0.3%/°C. This study provides a beneficial reference for improving atomization of high-viscosity liquids by employing positive temperature coefficient material without any control methods.

  15. Suitability of thin-layer chromatography-flame ionization detection with regard to quantitative characterization of different fossil fuel products. 1. FID performances and response of pure compounds related to fossil fuel products

    Energy Technology Data Exchange (ETDEWEB)

    Cebolla, V.L.; Vela, J.; Membrado, L.; Ferrando, A.C. [CSIC, Zaragoza (Spain). Inst. de Carboquimica, Dept. de Procesos Quimicos

    1998-10-01

    The performance of a modern TLC-FID system (which includes the newest detector configuration) was tested on polycyclic aromatic compound standards and related compounds as a preliminary step to evaluate its suitability for quantitative hydrocarbon group type analysis of different coal and petroleum products. FID linearity was evaluated as a function of sample load and scan speed for high-molecular-weight and semi-volatile standards. TLC-FID response factors for compounds of several homologous series were studied in order to differentiate effects of volatility from those exclusively due to the chemical nature concerning FID response. Criteria are developed for the accurate application of TLC-FID to fossil fuel samples. Measurements of chromarod temperatures were carried out in order to evaluate whether an evaporation of compounds outside the H{sub 2} flame might take place. 10 refs., 3 figs., 4 tabs.

  16. Historic Patterns of CO{sub 2} Emissions from Fossil Fuels: Implications for Stabilization of Emissions

    Science.gov (United States)

    Andres, R. J.; Marland, G.

    1994-06-01

    This paper examines the historical record of greenhouse gas emissions since 1950, reviews the prospects for emissions into the future, and projects what would be the short-term outcome if the stated targets of the FCCC were in fact achieved. The examination focuses on the most important of the greenhouse gases, CO{sub 2}. The extensive record of historic CO{sub 2} emissions is explored to ascertain if it is an adequate basis for useful extrapolation into the near future. Global carbon dioxide emissions from fossil fuel consumption have been documented. Emissions grew at 4.3% per year from 1950 until the time of the 1973 oil crisis. Another disruption in growth followed the oil price increases of 1979. Global total emissions have been increasing steadily since the 1982-1983 minimum and have grown by more than 20% since then. At present, emission Of CO{sub 2} from fossil fuel burning is dominated by a few countries: the U.S., the former Soviet Union, China, the developed countries of Europe and Japan. Only 20 countries emit 84% of emissions from all countries. However, rates of growth in many of the developed countries are now very low. In contrast, energy use has grown rapidly over the last 20 years in some of the large, developing economies. Emissions from fossil fuel consumption are now nearly 4 times those from land use change and are the primary cause of measured increases in the atmospheric concentration of CO{sub 2}. The increasing concentration of atmospheric CO{sub 2} has led to rising concern about the possibility of impending changes in the global climate system. In an effort to limit or mitigate potential negative effects of global climate change, 154 countries signed the United Nations Framework Convention on Climate Change (FCCC) in Rio de Janeiro in June, 1992. The FCCC asks all countries to conduct an inventory of their current greenhouse gas emissions setting non-binding targets.

  17. A Vulnerability-Benefit Analysis of Fossil Fuel CO2 Emissions

    Science.gov (United States)

    Delman, E. M.; Stephenson, S. R.; Davis, S. J.; Diffenbaugh, N. S.

    2015-12-01

    Although we can anticipate continued improvements in our understanding of future climate impacts, the central challenge of climate change is not scientific, but rather political and economic. In particular, international climate negotiations center on how to share the burden of uncertain mitigation and adaptation costs. We expose the relative economic interests of different countries by assessing and comparing their vulnerability to climate impacts and the economic benefits they derive from the fossil fuel-based energy system. Vulnerability refers to the propensity of humans and their assets to suffer when impacted by hazards, and we draw upon the results from a number of prior studies that have quantified vulnerability using multivariate indices. As a proxy for benefit, we average CO2 related to each country's extraction of fossil fuels, production of CO2 emissions, and consumption of goods and services (Davis et al., 2011), which should reflect benefits accrued in proportion to national economic dependence on fossil fuels. We define a nondimensional vulnerability-benefit ratio for each nation and find a large range across countries. In general, we confirm that developed and emerging economies such as the U.S., Western Europe, and China rely heavily on fossil fuels and have substantial resources to respond to the impacts of climate change, while smaller, less-developed economies such as Sierra Leone and Vanuatu benefit little from current CO2 emissions and are much more vulnerable to adverse climate impacts. In addition, we identify some countries with a high vulnerability and benefit, such as Iraq and Nigeria; conversely, some nations exhibit both a low vulnerability and benefit, such as New Zealand. In most cases, the ratios reflect the nature of energy-climate policies in each country, although certain nations - such as the United Kingdom and France - assume a level of responsibility incongruous with their ratio and commit to mitigation policy despite

  18. Flexibility in the Production of Hydrogen and Electricity from Fossil Fuel Power Plants

    OpenAIRE

    Starr, Frederick; STEEN MARC; PETEVES ESTATHIOS

    2005-01-01

    Concerns about global climate change have led to the formulation of a number of fossil fuel power plant concepts, which are intended to capture the carbon dioxide produced, so that it can be stored in geological structures. In the medium and long-term future, these plants will have to operate in a market where a large fraction of the electricity that is produced will come from wind and solar power. Because these renewables are intermittent sources of energy, it is likely that the main use of ...

  19. Challenges of efficient and clean use of fossil fuels for power production

    Energy Technology Data Exchange (ETDEWEB)

    Vortmeyer, Nicolas; Zimmermann, Gerhard

    2010-09-15

    Constantly increasing resource efficiency together with the broad introduction of CCS technologies is fundamental for a continuous use of fossil fuels in power generation against the background of up-coming requirements for CO2 emission reduction. In principle, CCS means up-grading conventional power plant technology with proven CO2 removal processes. However, this leads to additional losses, auxiliary power demand and cost. System integration, development or at least adaption of components and processes are the main requirements in this context. Different technology solutions and recent developments will be addressed as well as challenges when implementing in demonstration projects.

  20. Development and application of new membranes at high temperatures in order to get hydrogen from fossil fuel. Final report. Entwicklung und Einsatz neuer Membranen bei hohen Temperaturen zur Wasserstoffgewinnung aus fossilen Energietraegern. Endbericht

    Energy Technology Data Exchange (ETDEWEB)

    Herzog, F.; Luecke, L.; Oertel, M.; Pavlidis, S.; Schmitz, J.

    1990-06-01

    The use of membranes in dehydration reactions allows hydrogen to be extracted in one process step; at the same time the yield from the reactions is increased by the product extraction. Metallic membranes of titanium/nickel and coated vanadium as well as ceramic membranes have been developed on the basis of separation layers of aluminium oxide and zeolites. Whereas the permeation rates through TiNi are around one magnitude below those of palladium, the figures for vanadium are equal to, and in some cases even exceed those of Pd. When ceramic membranes are used no high-purity hydrogen is produced, but rather the feed gas is enriched with H{sub 1} Separation factors for H{sub 1}/N{sub 2} of between 2 and 3 are achieved with {gamma}-Al{sub 2}O{sub 3} membranes, and between 3 and 6 with zeolite membranes. The use of metal membranes in a steam reforming plant results in increases in the yield of between 10 and 45% depending on the reaction pressure. The service lives of the membrane modules developed when used in a test plant are currently around 2500 hours. The calculations carried out parallel to this are a good reflection of the test results for commercial plants without membranes and laboratory system with integrated membranes. An economic appraisal has shown that the hydrogen production costs in a conventional steam reforming plant are around 5% lower than those of a system using membranes; the relationship does, however, change in favour of the steam reformer with integrated membranes if high temperatures are used as a source of heat. (orig.) With 61 refs., 16 tabs., 55 figs.

  1. Temperature Stratification in a Cryogenic Fuel Tank

    Data.gov (United States)

    National Aeronautics and Space Administration — A reduced dynamical model describing temperature stratification effects driven by natural convection in a liquid hydrogen cryogenic fuel tank has been developed. It...

  2. The influence of weather and environment on pulmonary embolism: pollutants and fossil fuels.

    Science.gov (United States)

    Clauss, Ralf; Mayes, Julian; Hilton, Paul; Lawrenson, Ross

    2005-01-01

    Previous publications have highlighted seasonal variations in the incidence of thrombosis and pulmonary embolism, and that weather patterns can influence these. While medical risk factors for pulmonary thrombo-embolism such as age, obesity, hypercoagulable states, cancer, previous thrombo-embolism, immobility, limb paralysis, surgery, major illness, trauma, hypotension, tachypnoea and right ventricular hypokinesis are not directly implicated regarding environmental factors such as weather, they could be influenced indirectly by these. This would be especially relevant in polluted areas that are associated with a higher pulmonary embolism risk. Routine nuclear medicine lung ventilation/perfusion studies (V/Q scans) of 2071 adult patients referred to the nuclear medicine department of the Royal Surrey County Hospital in Guildford, UK, between January 1998 and October 2002 were reviewed and 316 of these patients were classified as positive for pulmonary embolism with high probability scan on PIOPED criteria. The occurrence of positive scans was compared to environmental factors such as temperature, humidity, vapour pressure, air pressure and rainfall. Multiple linear regression was used to establish the significance of these relations. The incidence of pulmonary embolism was positively related to vapour pressure and rainfall. The most significant relation was to vapour pressure (p=0.010) while rainfall was less significant (p=0.017). There was no significant relation between pulmonary embolism and air pressure, humidity or temperature. It is postulated that rainfall and water vapour may be contributary factors in thrombosis and pulmonary embolism by way of pollutants that are carried as condensation nuclei in micro-droplets of water. In particular, fossil fuel pollutants are implicated as these condensation nuclei. Pollutants may be inhaled by populations exposed to windborne vapour droplets in cities or airports. Polluted vapour droplets may be absorbed by the lung

  3. High Temperature PEM Fuel Cells and Organic Fuels

    DEFF Research Database (Denmark)

    Vassiliev, Anton

    inside the cells and to determine the lifetime. Additionally, comparison was made with methanol as fuel, which is the main competitor to DME in direct oxidation of organic fuels in fuel cells. For the reference, measurements have also been done with conventional hydrogen/air operation. All...... of the electrolyte membrane having a much more pronounced effect on the final performance than the catalyst composition. The increased operating temperature showed improved performances for all 3 investigated fuels, hydrogen, DME and methanol, with the additional energy supplied in terms of heat helping to overcome...... of the latter. Gas chromatography study of the anode exhaust gas at open circuit voltage revealed a small degree of internal fuel reforming with different products when operated on dimethyl ether or methanol. While methanol seemed to reform to syngas, the DME yielded methane rather than CO as one...

  4. Fuel Temperature Fluctuations During Storage

    Science.gov (United States)

    Levitin, R. E.; Zemenkov, Yu D.

    2016-10-01

    When oil and petroleum products are stored, their temperature significantly impacts how their properties change. The paper covers the problem of determining temperature fluctuations of hydrocarbons during storage. It provides results of the authors’ investigations of the stored product temperature variations relative to the ambient temperature. Closeness and correlation coefficients between these values are given. Temperature variations equations for oil and petroleum products stored in tanks are deduced.

  5. High-molecular-mass substances in resinites as possible precursors of specific hydrocarbons in fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Aarssen, B.G.K. van.; de Leeuw, J.W. (Delft University of Technology, Delft (Netherlands). Organic Geochemistry Unit)

    1992-12-01

    A critical review of the literature concerning the composition of high-molecular-mass (HMM) substances in fossil resins, or resinites, indicated that rigorous assignments of chemical structures of resins of gymnosperm origin have not been performed. Detailed knowledge of the structures of such macromolecules is needed to fully understand their diagenetic and catagenetic behaviour. Therefore a representative set of fossil gymnosperm resins (Victoria, Australia) was investigated. HMM substances were separated from the low-molecular-mass (LMM) substances and studied for their structures and thermal breakdown products. The LMM compounds consist mainly of tricyclic carboxylic acids. The presence of C[sub 40]-compounds which were tentatively identified as dimeric communic acids is shown. Specific compounds that are formed upon flash pyrolysis of the HMM substances were tentatively identified by gas chromatography-mass spectrometry. Their proposed structures indicate that the basic structural unit of the macromolecule consists of a diterpenoid carboxylic acid with a labdatriene carbon skeleton. This is in agreement with literature in which the gymnosperm resinous macromolecules are described as polycommunic acids. Prolonged heating of the resinite and the separated HMM substances yields predominantly bi- and tricyclic aromatic hydrocarbons which are often encountered in fossil fuels. 47 refs., 11 figs.

  6. Survey of population health in towns with nuclear and fossil fuel power plants

    Energy Technology Data Exchange (ETDEWEB)

    Ivanov, E.; Shubik, V. M.

    2004-07-01

    Comparative assessment of population health in Sosnovy Bor with nuclear power plant and Kirovsk with fossil fuel power station was made for public and administration information. Both towns are located in Leningrad administrative region at 150 km distance from each other. In nuclear power town radiological situation was assessed as normal and in Kirovsk up to 1995 yr. with coal fuel, maximum permissible levels of suspended particle of sulfur oxide in atmosphere were exceeded in 6-9% of samples. After 1995 yr. the natural gas was used as fuel. Demographic data for 1991-2000 yrs indicate that mortality including infants mortality and stillborns was lower in Sosnovy Bor (NOS) then in Kirovsk (fossil fuel) and on average Leningrad administrative region. Birth rate and population growth was higher in Sosnovy Bor at the same time surprisingly the recorded morbidity was higher in Sosnovy Bor which might be explained by extensive medical supervision and improved diagnostics. However, cancer and tuberculosis morbidity was lower in Sosnovy Bor. In Kirovsk in 1997-2000 yrs. oncological morbidity was higher on average comparing to Leningrad administrative region. Oncological mortality in Sosnovy Bor in 1997-2000 yrs. was lower than in Kirovsk and Leningrad region Standardized annual mortality in Sosnovy Bor, Kirovsk and Leningrad administrative region was 128.3, 209.6 and 211.7 on 100 000 respectively. Health state of pregnant women, deliveries, new-born condition were all in normal range in Sosnovy Bor, contrary to higher increased abortion rate and pregnancy complications in Kirovsk. These findings need further studies. (Author)

  7. Toxicity evaluation of 2-hydroxybiphenyl and other compounds involved in studies of fossil fuels biodesulphurisation.

    Science.gov (United States)

    Alves, L; Paixão, S M

    2011-10-01

    The acute toxicity of some compounds used in fossil fuels biodesulphurisation studies, on the respiration activity, was evaluated by Gordonia alkanivorans and Rhodococcus erythropolis. Moreover, the effect of 2-hydroxybiphenyl on cell growth of both strains was also determined, using batch (chronic bioassays) and continuous cultures. The IC₅₀ values obtained showed the toxicity of all the compounds tested to both strains, specially the high toxicity of 2-HBP. These results were confirmed by the chronic toxicity data. The toxicity data sets highlight for a higher sensitivity to the toxicant by the strain presenting a lower growth rate, due to a lower cells number in contact with the toxicant. Thus, microorganisms exhibiting faster generation times could be more resistant to 2-HBP accumulation during a BDS process. The physiological response of both strains to 2-HBP pulse in a steady-state continuous culture shows their potential to be used in a future fossil fuel BDS process. Copyright © 2011 Elsevier Ltd. All rights reserved.

  8. Radiocarbon-based assessment of fossil fuel-derived contaminant associations in sediments.

    Science.gov (United States)

    White, Helen K; Reddy, Christopher M; Eglinton, Timothy I

    2008-08-01

    Hydrophobic organic contaminants (HOCs) are associated with natural organic matter (OM) in the environment via mechanisms such as sorption or chemical binding. The latter interactions are difficult to quantitatively constrain, as HOCs can reside in different OM pools outside of conventional analytical windows. Here, we exploited natural abundance variations in radiocarbon (14C) to trace various fossil fuel-derived HOCs (14C-free) within chemically defined fractions of contemporary OM (modern 14C content) in 13 samples including marine and freshwater sediments and one dust and one soil sample. Samples were sequentially treated by solvent extraction followed by saponification. Radiocarbon analysis of the bulk sample and resulting residues was then performed. Fossil fuel-derived HOCs released by these treatments were quantified from an isotope mass balance approach as well as by gas chromatography-mass spectrometry. For the majority of samples (n = 13), 98-100% of the total HOC pool was solvent extractable. Nonextracted HOCs are only significant (29% of total HOC pool)in one sample containing p,p-2,2-bis(chlorophenyl)-1,1,1-trichloroethane and its metabolites. The infrequency of significant incorporation of HOCs into nonextracted OM residues suggests that most HOCs are mobile and bioavailable in the environment and, as such, have a greater potential to exert adverse effects.

  9. Forecasting Fossil Fuel Energy Consumption for Power Generation Using QHSA-Based LSSVM Model

    Directory of Open Access Journals (Sweden)

    Wei Sun

    2015-01-01

    Full Text Available Accurate forecasting of fossil fuel energy consumption for power generation is important and fundamental for rational power energy planning in the electricity industry. The least squares support vector machine (LSSVM is a powerful methodology for solving nonlinear forecasting issues with small samples. The key point is how to determine the appropriate parameters which have great effect on the performance of LSSVM model. In this paper, a novel hybrid quantum harmony search algorithm-based LSSVM (QHSA-LSSVM energy forecasting model is proposed. The QHSA which combines the quantum computation theory and harmony search algorithm is applied to searching the optimal values of and C in LSSVM model to enhance the learning and generalization ability. The case study on annual fossil fuel energy consumption for power generation in China shows that the proposed model outperforms other four comparative models, namely regression, grey model (1, 1 (GM (1, 1, back propagation (BP and LSSVM, in terms of prediction accuracy and forecasting risk.

  10. Environmental evidence of fossil fuel pollution in Laguna Chica de San Pedro lake sediments (Central Chile)

    Energy Technology Data Exchange (ETDEWEB)

    Chirinos, L. [Centro de Ciencias Ambientales EULA-Chile, Universidad de Concepcion, PO Box 160-C, Concepcion (Chile)]. E-mail: lchirin@pucp.edu.pe; Rose, N.L. [Environmental Change Research Centre, University College London, 26 Bedford Way, London WG1HOAP (United Kingdom); Urrutia, R. [Centro de Ciencias Ambientales EULA-Chile, Universidad de Concepcion, PO Box 160-C, Concepcion (Chile); Munoz, P. [Departamento de Biologia Marina, Universidad Catolica del Norte, Larrondo 1281, Coquimbo (Chile); Torrejon, F. [Centro de Ciencias Ambientales EULA-Chile, Universidad de Concepcion, PO Box 160-C, Concepcion (Chile); Torres, L. [Departamento de Botanica, Universidad de Concepcion, Concepcion (Chile); Cruces, F. [Departamento de Botanica, Universidad de Concepcion, Concepcion (Chile); Araneda, A. [Centro de Ciencias Ambientales EULA-Chile, Universidad de Concepcion, PO Box 160-C, Concepcion (Chile); Zaror, C. [Facultad de Ingenieria Quimica, Universidad de Concepcion, Concepcion (Chile)

    2006-05-15

    This paper describes lake sediment spheroidal carbonaceous particle (SCP) profiles from Laguna Chica San Pedro, located in the Biobio Region, Chile (36{sup o} 51' S, 73{sup o} 05' W). The earliest presence of SCPs was found at 16 cm depth, corresponding to the 1915-1937 period, at the very onset of industrial activities in the study area. No SCPs were found at lower depths. SCP concentrations in Laguna Chica San Pedro lake sediments were directly related to local industrial activities. Moreover, no SCPs were found in Galletue lake (38{sup o} 41' S, 71{sup o} 17.5' W), a pristine high mountain water body used here as a reference site, suggesting that contribution from long distance atmospheric transport could be neglected, unlike published data from remote Northern Hemisphere lakes. These results are the first SCP sediment profiles from Chile, showing a direct relationship with fossil fuel consumption in the region. Cores were dated using the {sup 21}Pb technique. - The lake sediment record of SCPs shows the record of fossil-fuel derived pollution in Central Chile.

  11. Three Essays on Renewable Energy Policy and its Effects on Fossil Fuel Generation in Electricity Markets

    Science.gov (United States)

    Bowen, Eric

    In this dissertation, I investigate the effectiveness of renewable policies and consider their impact on electricity markets. The common thread of this research is to understand how renewable policy incentivizes renewable generation and how the increasing share of generation from renewables affects generation from fossil fuels. This type of research is crucial for understanding whether policies to promote renewables are meeting their stated goals and what the unintended effects might be. To this end, I use econometric methods to examine how electricity markets are responding to an influx of renewable energy. My dissertation is composed of three interrelated essays. In Chapter 1, I employ recent scholarship in spatial econometrics to assess the spatial dependence of Renewable Portfolio Standards (RPS), a prominent state-based renewable incentive. In Chapter 2, I explore the impact of the rapid rise in renewable generation on short-run generation from fossil fuels. And in Chapter 3, I assess the impact of renewable penetration on coal plant retirement decisions.

  12. Sources of non-fossil-fuel emissions in carbonaceous aerosols during early winter in Chinese cities

    Science.gov (United States)

    Liu, Di; Li, Jun; Cheng, Zhineng; Zhong, Guangcai; Zhu, Sanyuan; Ding, Ping; Shen, Chengde; Tian, Chongguo; Chen, Yingjun; Zhi, Guorui; Zhang, Gan

    2017-09-01

    China experiences frequent and severe haze outbreaks from the beginning of winter. Carbonaceous aerosols are regarded as an essential factor in controlling the formation and evolution of haze episodes. To elucidate the carbon sources of air pollution, source apportionment was conducted using radiocarbon (14C) and unique molecular organic tracers. Daily 24 h PM2. 5 samples were collected continuously from October 2013 to November 2013 in 10 Chinese cities. The 14C results indicated that non-fossil-fuel (NF) emissions were predominant in total carbon (TC; average = 65 ± 7 %). Approximately half of the EC was derived primarily from biomass burning (BB) (average = 46 ± 11 %), while over half of the organic carbon (OC) fraction comprised NF (average = 68 ± 7 %). On average, the largest contributor to TC was NF-derived secondary OC (SOCnf), which accounted for 46 ± 7 % of TC, followed by SOC derived from fossil fuels (FF) (SOCf; 16 ± 3 %), BB-derived primary OC (POCbb; 13 ± 5 %), POC derived from FF (POCf; 12 ± 3 %), EC derived from FF (ECf; 7 ± 2 %) and EC derived from BB (ECbb; 6 ± 2 %). The regional background carbonaceous aerosol composition was characterized by NF sources; POCs played a major role in northern China, while SOCs contributed more in other regions. However, during haze episodes, there were no dramatic changes in the carbon source or composition in the cities under study, but the contribution of POC from both FF and NF increased significantly.

  13. A Transition Strategy from Fossil Fuels to Renewable Energy Sources in the Mexican Electricity System

    Directory of Open Access Journals (Sweden)

    Juan J. Vidal-Amaro

    2018-03-01

    Full Text Available Renewable energy sources exploitation acquires special importance for creating low-carbon energy systems. In Mexico a national regulation limits the fossil fuel-based electricity generation to 65%, 60% and 50% by years 2024, 2030 and 2050 respectively. This study evaluates several scenarios of renewables incorporation into the Mexican electricity system to attend those targets as well as a 75% renewables-based electricity share target towards a 100% renewable system. By its size, the Mexican electricity system, with a generation of 260.4 TWh/year (85% based on fossil fuels, can be regarded as an illustrating reference. The impact of increasing amounts of wind, photovoltaic solar, biomass, biogas, geothermal, hydro and concentrating solar power on the system’s capacity to attend demand on a one-hour timescale resolution is investigated utilizing the EnergyPLAN model and the minimum total mix capacity method. Possible excess of electricity production is also assessed. For every target year, a solution is obtained corresponding to the combination resulting in the minimum total generation capacity for the electricity system. A transition strategy to a system with a high share of renewables-based electricity is designed where every transition step corresponds to the optimal energy mix for each of the target years.

  14. Health effects and related standards for fossil-fuel and geothermal power plants. Volume 6 of health and safety impacts of nuclear, geothermal, and fossil-fuel electric generation in California. [In California

    Energy Technology Data Exchange (ETDEWEB)

    Case, G.D.; Bertolli, T.A.; Bodington, J.C.; Choy, T.A.; Nero, A.V.

    1977-01-01

    This report reviews health effects and related standards for fossil-fuel and geothermal power plants, emphasizing impacts which may occur through emissions into the atmosphere, and treating other impacts briefly. Federal regulations as well as California state and local regulations are reviewed. Emissions are characterized by power plant type, including: coal-fired, oil-fired, gas-fired, combined cycle and advanced fossil-fuel plants; and liquid and vapor geothermal systems. Dispersion and transformation of emissions are treated. The state of knowledge of health effects, based on epidemiological, physiological, and biomedical studies, is reviewed.

  15. The Solodamu Surveys: determining fossil fuel use and sea transport need in a coastal village in Fiji

    Directory of Open Access Journals (Sweden)

    Alison Patricia Newell

    2015-08-01

    Full Text Available Domestic sea transport is critical to all aspects of life in the Pacific, providing access to markets and health and education services, as well as enabling cultural and social connectivity. Current sea transport services are entirely dependent upon use of increasingly expensive fossil fuels. Whilst there has been increasing research on international shipping, very little focus has been given to date to domestic shipping in the Pacific, and in particular at the local, village level. Recent studies have highlighted lack of data, particularly at a village level, as being a major impediment to progressing a shift to more sustainable transport.The importance of transport in achieving sustainable development and green growth is being increasingly highlighted by Pacific Leaders as a key priority, and particularly the need to find alternatives to reduce the region’s crippling dependency on imported fossil fuels. Small Island Developing States (SIDS in other regions also face similar challenges.This paper provides a summary of the findings of a village-based assessment of transport and fossil fuel use in Solodamu Village, Kadavu, Fiji carried out in 2009 and 2011. The objectives of the surveys were to gauge the overall sea, land and air transport use by the village and the fossil fuel footprint of the village by collecting data on a household by household basis. We then go on to outline how this assessment methodology has been expanded for an island group and highlight the potential of using this in other SIDS, so building the data sets available for more accurate analysis of both transport need and fossil fuel use to better address the issues of fossil fuel dependency and sustainable transport for the Pacific.

  16. Dynamic Model of High Temperature PEM Fuel Cell Stack Temperature

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2007-01-01

    The present work involves the development of a model for predicting the dynamic temperature of a high temperature PEM (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system consists of a prototype...... cathode air cooled 30 cell HTPEM fuel cell stack developed at the Institute of Energy Technology at Aalborg University. This fuel cell stack uses PEMEAS Celtec P-1000 membranes, runs on pure hydrogen in a dead end anode configuration with a purge valve. The cooling of the stack is managed by running...... the stack at a high stoichiometric air flow. This is possible because of the PBI fuel cell membranes used, and the very low pressure drop in the stack. The model consists of a discrete thermal model dividing the stack into three parts: inlet, middle and end and predicting the temperatures in these three...

  17. Use of (13)C-labeled compounds to trace their reactivity in fossil fuel systems

    Science.gov (United States)

    McKinney, Daniel E.

    The scope of this investigation was to analyze the fate of sp{13}C isotopically labeled hydrocarbons in complex fuel systems, such as jet fuel and reservoir oils, under pyrolysis conditions using sp{13}C NMR techniques and select ion monitoring-gas chromatography-mass spectrometry. The major questions to be addressed during the thesis research were: (1) to utilize and develop analytical techniques accurate enough to follow the thermal degradation of specific sp{13}C-labeled hydrocarbons in complex fuel mixtures; (2) to assess the accuracy of model compound studies, and determine whether or not these compounds behave in similar fashion when thermally degraded in complex fossil fuel systems; (3) determine what influence, if any, the chemical composition of fossil fuels have on the thermal cracking of some representative saturated and aromatic hydrocarbons. sp{13}C NMR in conjunction with sp{13}C-labeling proved to be a reliable technique for analyzing overall trends and changes which occurred to the sp{13}C-labeled hydrocarbon in question, but a more precise and sensitive analytical technique was needed to follow the reactions of sp{13}C-labeled n-Csb{25} added to two dissimilar crude oils. Select ion monitoring/gas chromatography/mass spectrometry (SIM/GC/MS) in conjunction with sp{13}C-labeling provided a more accurate assessment of the thermal degradation and product distributions of sp{13}C-labeled n-Csb{25}, mixed with reservoir oils in contrast to sp{13}C NMR. Results demonstrated that the n-Csb{25} was more thermally stable in the reservoir oils in comparison to kinetic parameters obtained for the neat thermal stressing of the n-Csb{25} and the n-alkane product distributions varied between the two oil systems, as well. Contrary to the oils ability to stabilize the n-Csb{25} the opposite trend was found when a sp{13}C-labeled alkylarene was added to the oils. The oils enhanced the rate of degradation of the added 9-methylphenanthrene by increasing the rate of

  18. Nitrogen Stable Isotope Composition of Various Fossil-fuel Combustion Nitrogen Oxide Sources

    Science.gov (United States)

    Walters, W.; Michalski, G. M.; Fang, H.

    2015-12-01

    Nitrogen oxides (NOx = NO + NO2) are important trace gases that impact atmospheric chemistry, air quality, and climate. In order to help constrain NOx source contributions, the nitrogen (N) stable isotope composition of NOx (δ15N-NOx) may be a useful indicator for NOx source partitioning. However, despite anthropogenic emissions being the most prevalent source of NOx, there is still large uncertainty in the δ15N-NOx values for anthropogenic sources. To this end, this study provides a detailed analysis of several fossil-fuel combustion NOx sources and their δ15N-NOx values. To accomplish this, exhaust or flue samples from several fossil-fuel combustion sources were sampled and analyzed for their δ15N-NOx that included airplanes, gasoline-powered vehicles not equipped with a catalytic converter, gasoline-powered lawn tools and utility vehicles, diesel-electric buses, diesel semi-trucks, and natural gas-burning home furnace and power plant. A relatively large range of δ15N-NOx values were measured from -28.1 to 0.3‰ for individual exhaust/flue samples with cold started diesel-electric buses contributing on average the lowest δ15N-NOx values at -20.9‰, and warm-started diesel-electric buses contributing on average the highest values of -1.7‰. The NOx sources analyzed in this study primarily originated from the "thermal production" of NOx and generally emitted negative δ15N-NOx values, likely due to the kinetic isotope effect associated with its production. It was found that there is a negative correlation between NOx concentrations and δ15N-NOx for fossil-fuel combustion sources equipped with catalytic NOx reduction technology, suggesting that the catalytic reduction of NOx may have an influence on δ15N-NOx values. Based on the δ15N-NOx values reported in this study and in previous studies, a δ15N-NOx regional and seasonal isoscape was constructed for the contiguous United States. The constructed isoscape demonstrates the seasonal importance of various

  19. Theoretical studies of oxides relevant to the combustion of fossil fuels

    Science.gov (United States)

    Hicks, Jason Michael

    Anthropogenic pollution has greatly increased since the industrial revolution and continues to increase as more of the world becomes dependent upon fossil fuels for important applications like transportation and power production. In a general case, whenever a fossil fuel is consumed, a primary product of a complete combustion reaction is carbon dioxide. In a more specific case, the collection, processing and combustion of coal for power production are one of the primary ways by which trace elements, such as arsenic and selenium, are released into the environment. All of these pollutants are known to have harmful effects, whether on the environment, human health or power production itself. Because of this there has been an increasing interest in studies related to combating these pollutants. Concerning CO2 emissions, recently there has been a significant amount of work related to CO2 capture. A promising method involves the encapsulation of CO2 into isoreticular metal-organic frameworks (IRMOFs). The effectiveness of IMROFs greatly depends on the choice of both metal and organic parts. Molecular simulations have been used in the past to aid in the design and characterization of new MOFs, in particular by generating an adsorption isotherm. However, these traditional simulation methods have several drawbacks. The method used in this thesis, namely expanded Wang-Landau, not only overcomes these drawbacks but provides access to all the thermodynamic properties relevant to the adsorption process through a solution thermodynamics approach. This is greatly beneficial, since an excellent way to characterize the performance of various MOFs is by comparing their desorption free energy, i.e., the energy it takes to regenerate a saturated MOF to prepare it for the next adsorption cycle. Expanded WL was used in the study of CO 2 adsorption into IRMOF-1, 8 and 10 at eight temperatures, spanning both the subcritical and supercritical regimes and the following were obtained

  20. Small Scale SOFC Demonstration Using Bio-Based and Fossil Fuels

    Energy Technology Data Exchange (ETDEWEB)

    Petrik, Michael [Technology Management Inc., Cleveland, OH (United States); Ruhl, Robert [Technology Management Inc., Cleveland, OH (United States)

    2012-05-01

    Technology Management, Inc. (TMI) of Cleveland, Ohio, has completed the project entitled Small Scale SOFC Demonstration using Bio-based and Fossil Fuels. Under this program, two 1-kW systems were engineered as technology demonstrators of an advanced technology that can operate on either traditional hydrocarbon fuels or renewable biofuels. The systems were demonstrated at Patterson's Fruit Farm of Chesterland, OH and were open to the public during the first quarter of 2012. As a result of the demonstration, TMI received quantitative feedback on operation of the systems as well as qualitative assessments from customers. Based on the test results, TMI believes that > 30% net electrical efficiency at 1 kW on both traditional and renewable fuels with a reasonable entry price is obtainable. The demonstration and analysis provide the confidence that a 1 kW entry-level system offers a viable value proposition, but additional modifications are warranted to reduce sound and increase reliability before full commercial acceptance.

  1. Technological research and development of fossil fuels; Ricerca e sviluppo tecnologico per lo sfruttamento ottimale dei combustibili fossili

    Energy Technology Data Exchange (ETDEWEB)

    Minghetti, E.; Palazzi, G. [ENEA, Centro Ricerche Casaccia, Rome (Italy). Dip. Energia

    1995-05-01

    The aim of the present document is to supply general information concerning fossil fuels that represent, today and for the near future, the main energy source of our planet. New fossil fuel technologies are in continual development with two principal goals: to decrease environmental impact and increase transformation process efficiency. Examples of this effort are: (1) gas-steam combined cycles integrated with coal gasification plants, or with pressurized-fluidized-bed combustors; (2) new cycles with humid air or coal direct fired turbine, now under development. In the first part of this document the international and national energy situations and trends are shown. After some brief notes on environment problems and alternative fuels, such as biomasses and municipal wastes, technological aspects, mainly relevant to increasing fossil-fueled power plant performances, are examined in greater depth. Finally the research and technological development activities of ENEA (National Agency for New technologies, Energy and the Environment) Engineering Branch in order to improve fossil fuels energy and environmental use are presented.

  2. Comparison of Different Fuel Temperature Models

    Energy Technology Data Exchange (ETDEWEB)

    Weddig, Beatrice

    2003-02-01

    The purpose of this work is to improve the performance of the core calculation system used in Ringhals for in-core fuel management. It has been observed that, whereas the codes yield results that are in good agreement with measurements when the core operates at full nominal power, this agreement deteriorates noticeably when the reactor is running at reduced power. This deficiency of the code system was observed by comparing the calculated and measured boron concentrations in the moderator of the PWR. From the neutronic point of view, the difference between full power and reduced power in the same core is the different temperature of the fuel and the moderator. Whereas the coolant temperature can be measured and is thus relatively well known, the fuel temperature is only inferred from the moderator temperature as well as neutron physics and heat transfer calculations. The most likely reason for the above mentioned discrepancy is therefore the uncertainty of the fuel temperature at low power, and hence the incorrect calculation of the fuel temperature reactivity feedback through the so called Doppler effect. To obtain the fuel temperature at low power, usually some semi-empirical relations, sometimes called correlations, are used. The above-mentioned inaccuracy of the core calculation procedures can thus be tracked down to the insufficiency of these correlations. Therefore, the suggestion is that the above mentioned deficiency of the core calculation codes can be eliminated or reduced if the fuel temperature correlations are improved. An improved model, called the 30% model, is implemented in SIMULATE-3, the core calculation code used at Ringhals. The accuracy of the 30% model was compared to that of the present model by considering a number of cases, where measured values of the boron concentration at low power were available, and comparing them with calculated values using both the present and the new model. It was found that on the whole, the new fuel temperature

  3. Atmospheric observations of carbon monoxide and fossil fuel CO2 emissions from East Asia

    DEFF Research Database (Denmark)

    Turnbull, Jocelyn C.; Tans, Pieter P.; Lehman, Scott J.

    2011-01-01

    /ppm respectively, consistent with recent bottom-up inventory estimates and other observational studies. Locally influenced TAP samples fall into two distinct data sets, ascribed to air sourced from South Korea and North Korea. The South Korea samples have low R-CO:CO2ff of 13 +/- 3 ppb/ppm, slightly higher than......Flask samples from two sites in East Asia, Tae-Ahn Peninsula, Korea (TAP), and Shangdianzi, China (SDZ), were measured for trace gases including CO2, CO and fossil fuel CO2(CO(2)ff, derived from Delta(CO2)-C-14 observations). The five-year TAP record shows high CO(2)ff when local air comes from...

  4. Chemical and toxicologic characterization of fossil fuel combustion product phenalen-1-one

    Energy Technology Data Exchange (ETDEWEB)

    Leary, J.A.; Lafleur, A.L.; Liber, H.L.; Biemann, K.

    1983-04-01

    In the course of analysis of the combustion products of fossil fuels, phenalen-1-one has been identified as one of the components. It was differentiated from fluoren-9-one and benzo(c)cinnoline, all of which exhibit very similar mass spectra, by gas chromatographic mass spectrometry, and high-performance liquid chromatography with high-speed spectrophotometric detection. Ultraviolet spectra are reported along with retention data for both gas and liquid chromatography. Mutagenic activity was determined in Salmonella typhimurium, using resistance to the purine analogue 8-azaguanine as a genetic marker. Phenalen-1-one was found to be a potent mutagen, while benzo(c)cinnoline was six times less active. Fluoren-9-one was completely inactive as a bacterial mutagen.

  5. Integrated capture of fossil fuel gas pollutants including CO.sub.2 with energy recovery

    Science.gov (United States)

    Ochs, Thomas L [Albany, OR; Summers, Cathy A [Albany, OR; Gerdemann, Steve [Albany, OR; Oryshchyn, Danylo B [Philomath, OR; Turner, Paul [Independence, OR; Patrick, Brian R [Chicago, IL

    2011-10-18

    A method of reducing pollutants exhausted into the atmosphere from the combustion of fossil fuels. The disclosed process removes nitrogen from air for combustion, separates the solid combustion products from the gases and vapors and can capture the entire vapor/gas stream for sequestration leaving near-zero emissions. The invention produces up to three captured material streams. The first stream is contaminant-laden water containing SO.sub.x, residual NO.sub.x particulates and particulate-bound Hg and other trace contaminants. The second stream can be a low-volume flue gas stream containing N.sub.2 and O.sub.2 if CO2 purification is needed. The final product stream is a mixture comprising predominantly CO.sub.2 with smaller amounts of H.sub.2O, Ar, N.sub.2, O.sub.2, SO.sub.X, NO.sub.X, Hg, and other trace gases.

  6. Organic Mass Fragments and Organic Functional Groups in Aged Biomass Burning and Fossil Fuel Combustion Aerosol

    Science.gov (United States)

    Day, D. A.; Hawkins, L. N.; Russell, L. M.

    2009-12-01

    Organic functional group concentrations in submicron aerosol particles collected from 27 June to 17 September at the Scripps Pier in La Jolla, California as part of AeroSCOPE 2008 were quantified using Fourier Transform Infrared (FTIR) spectroscopy. Organic and inorganic non-refractory components in the same air masses were quantified using a Quadrupole Aerosol Mass Spectrometer (Q-AMS). Previous measurements at the Scripps pier indicate that a large fraction of submicron particle mass originates in Los Angeles and the port of Long Beach. Additional particle sources to the region include local urban emissions and periodic biomass burning during large wildfires. Three distinct types of organic aerosol components were identified from organic composition and elemental tracers, including biomass burning, fossil fuel combustion, and polluted marine components. Fossil fuel combustion organic aerosol was dominated by unsaturated alkane and was correlated with sulfur, vanadium, and nickel supporting ship and large trucks in and around the Los Angeles/Long Beach region as the dominant source. Biomass burning organic aerosol comprised a smaller unsaturated alkane fraction and larger fractions of non-acid carbonyl, amine, and carboxylic acid and was correlated with potassium and bromine. Polluted marine organic aerosol was dominated by organic hydroxyl and unsaturated alkane and was not correlated with any elemental tracers. Mass spectra of the organic aerosol support the aerosol sources determined by organic functional groups and elemental tracers and contain fragments commonly attributed to oxygenated organic aerosol (OOA), hydrocarbon-like organic aerosol (HOA), and biomass burning organic aerosol (BBOA). Comparisons of the PMF-derived Q-AMS source spectra with FTIR source spectra and functional group composition provide additional information on the relationship between commonly reported organic aerosol factors and organic functional groups in specific organic aerosol

  7. Quantification of space/time explicit fossil fuel CO2 emissions in urban domes

    Science.gov (United States)

    Gurney, K. R.; Razlivanov, I.; Zhou, Y.; Song, Y.; Turnbull, J. C.; Sweeney, C.; Karion, A.; Davis, K. J.; Miles, N. L.; Richardson, S.; Lauvaux, T.; Shepson, P. B.; Cambaliza, M. L.; Lehman, S. J.; Tans, P. P.

    2011-12-01

    Quantification of fossil fuel CO2 emissions from the bottom-up perspective is a critical element in emerging plans on a carbon monitoring system (CMS). A space/time explicit emissions data product can act as both a verification and planning system. It can verify atmospheric CO2 measurements (in situ and remote) and offer detailed mitigation information to local management authorities in order to optimize the mix of mitigation efforts. Here, we present the Hestia Project, an effort aimed at building a high resolution (eg. building and road link-specific, hourly) fossil fuel CO2 emissions data products for the urban domain. A complete data product has been built for the city of Indianapolis and work is ongoing for the city of Los Angeles. The effort in Indianapolis is now part of a larger effort aimed at a convergent top-down/bottom-up assessment of greenhouse gas emissions, called INFLUX. Our urban-level quantification relies on a mixture of data and modeling structures. We start with the sector-specific Vulcan Project estimate at the mix of geocoded and county-wide levels. The Hestia aim is to distribute the Vulcan result in space and time. Two components take the majority of effort: buildings and onroad emissions. For the buildings, we utilize an energy building model which we constrain through lidar data, county assessor parcel data and GIS layers. For onroad emissions, we use a combination of traffic data and GIS road layers maintaining vehicle class information. Finally, all pointwise data in the Vulcan Project are transferred to our urban landscape and additional time distribution is performed. In collaboration with our INFLUX colleagues, we are transporting these high resolution emissions through an atmospheric transport model for a forward comparison of the Hestia data product with atmospheric measurements, collected on aircraft and cell towers. In preparation for a formal urban-scale inversion, these forward comparisons offer insights into both improving

  8. Fossil Fuel Combustion Fingerprint in High-Resolution Urban Water Vapor Isotope Measurements

    Science.gov (United States)

    Gorski, G.; Good, S. P.; Bowen, G. J.

    2014-12-01

    Increasing energy consumption and rapid urbanization have many important and poorly understood consequences for the hydrologic cycle in urban and suburban areas. Wide use of fossil fuels for transportation and heating releases isotopically distinctive water vapor that contributes to the overall water vapor budget in varying, usually unknown, concentrations. The use of long term, high resolution isotopic measurements can help determine different sources and proportions of water vapor at various time scales. We present two months of high-resolution water vapor isotope measurements coupled with CO2 concentrations and co-located meteorological observations from December 2013 - January 2014 in Salt Lake City, UT. Periods of atmospheric stagnation (cold-air inversions) show a buildup of CO2 from baseline values of 420 ppm to as high as 600 ppm and an associated decrease in water vapor deuterium-excess values from a baseline of approx. 10‰ to values as low as -10‰ (where d = δ2H - 8*δ18O, in per mil units). We suggest that the strong relationship between CO2and d during inversion periods is driven by the build-up of fossil fuel combustion-derived water vapor with very low d values (≤ -150‰). Based on our measurements of its isotopic composition, combustion-derived water vapor could contribute as much as 15% to the total water vapor budget during inversion periods. We present evidence of this effect at both the multi-day scale and the diurnal scale, where periods of increased automobile use and home heating can be identified. This study provides the first isotopic evidence that accumulation of water of combustion can be identified in boundary layer water vapor, suggests that an appreciable fraction of boundary layer vapor can be derived from combustion under certain atmospheric conditions, and indicates that the distinctive d values of combustion-derived vapor may be a useful tracer for this component of the atmospheric water budget in other urban regions.

  9. Low temperature chemical processing of graphite-clad nuclear fuels

    Energy Technology Data Exchange (ETDEWEB)

    Pierce, Robert A.

    2017-10-17

    A reduced-temperature method for treatment of a fuel element is described. The method includes molten salt treatment of a fuel element with a nitrate salt. The nitrate salt can oxidize the outer graphite matrix of a fuel element. The method can also include reduced temperature degradation of the carbide layer of a fuel element and low temperature solubilization of the fuel in a kernel of a fuel element.

  10. Combustion temperature charts for industrial gaseous fuels

    Energy Technology Data Exchange (ETDEWEB)

    Matouskova, V.; Gerak, A.; Hlavacka, V.

    1975-12-01

    Researchers at Czechoslovakia's State Research Institute of Mechanical Engineering offer a method for calculating the theoretical flame temperature that includes the effect of endothermic reactions, especially the dissociation of combustion products. Charts presented for eight types of fuel gases can be used to determine the flame temperature relative to the temperature of the combustion air and to the excess-air ratio. Also considered is the relationship between these parameters and the characteristic temperature relationships for equipment using heat recovered from the flue gases to preheat incoming combustion air.

  11. Cofiring biomass and coal for fossil fuel reduction and other benefits–Status of North American facilities in 2010

    Science.gov (United States)

    David Nicholls; John. Zerbe

    2012-01-01

    Cofiring of biomass and coal at electrical generation facilities is gaining in importance as a means of reducing fossil fuel consumption, and more than 40 facilities in the United States have conducted test burns. Given the large size of many coal plants, cofiring at even low rates has the potential to utilize relatively large volumes of biomass. This could have...

  12. Chemical biorefinery perspectives : the valorisation of functionalised chemicals from biomass resources compared to the conventional fossil fuel production route

    NARCIS (Netherlands)

    Brehmer, B.

    2008-01-01

    In response to the impending problems related to fossil fuels (continued supply, price, and regional and global pollution) alternative feedstocks are gaining interest as possible solutions. Biomass, considered sustainable and renewable, is an option with the potential to replace a wide diversity

  13. Are forestation, bio-char and landfilled biomass adequate offsets for the climate effects of burning fossil fuels?

    NARCIS (Netherlands)

    Reijnders, L.

    2009-01-01

    Forestation and landfilling purpose-grown biomass are not adequate offsets for the CO2 emission from burning fossil fuels. Their permanence is insufficiently guaranteed and landfilling purpose-grown biomass may even be counterproductive. As to permanence, bio-char may do better than forests or

  14. Wine ethanol C-14 as a tracer for fossil fuel CO2 emissions in Europe : Measurements and model comparison

    NARCIS (Netherlands)

    Palstra, Sanne W. L.; Karstens, Ute; Streurman, Harm-Jan; Meijer, Harro A. J.

    2008-01-01

    C-14 (radiocarbon) in atmospheric CO2 is the most direct tracer for the presence of fossil-fuel-derived CO2 (CO2-ff). We demonstrate the C-14 measurement of wine ethanol as a way to determine the relative regional atmospheric CO2-ff concentration compared to a background site ("regional CO2-ff

  15. Strategic backdrop analysis for fossil fuel planning. Task 1. Default Case. Report 468-117-07/01

    Energy Technology Data Exchange (ETDEWEB)

    1980-06-01

    This report presents data describing a default case analysis performed using the strategic backdrop analytical framework developed to facilitate fossil fuel planning within the DOE. Target years are 1985 and 2025. Residential, commercial, and industrial energy demands are forecast as well as the impacts of energy technology implementation and market penetration using a set of energy technology assumptions. (DMC)

  16. Fossil fuel subsidy reform in the WTO : Options for constraining dual pricing in the multilateral trading system

    NARCIS (Netherlands)

    Marhold, Anna

    2017-01-01

    Fossil fuel subsidies harm the environment, add to health hazards caused by air pollution, and delay the energy transition. Scholars and practitioners have therefore been exploring ways to reform and eliminate them. This paper discusses the practice of energy dual pricing in the broader context of

  17. Contextualizing avian mortality. A preliminary appraisal of bird and bat fatalities from wind, fossil-fuel, and nuclear electricity

    Energy Technology Data Exchange (ETDEWEB)

    Sovacool, Benjamin K. [Energy Governance Program, Centre on Asia and Globalisation, Lee Kuan Yew School of Public Policy, National University of Singapore, Singapore 259772 (Singapore)

    2009-06-15

    This article explores the threats that wind farms pose to birds and bats before briefly surveying the recent literature on avian mortality and summarizing some of the problems with it. Based on operating performance in the United States and Europe, this study offers an approximate calculation for the number of birds killed per kWh generated for wind electricity, fossil-fuel, and nuclear power systems. The study estimates that wind farms and nuclear power stations are responsible each for between 0.3 and 0.4 fatalities per gigawatt-hour (GWh) of electricity while fossil-fueled power stations are responsible for about 5.2 fatalities per GWh. While this paper should be respected as a preliminary assessment, the estimate means that wind farms killed approximately seven thousand birds in the United States in 2006 but nuclear plants killed about 327,000 and fossil-fueled power plants 14.5 million. The paper concludes that further study is needed, but also that fossil-fueled power stations appear to pose a much greater threat to avian wildlife than wind and nuclear power technologies. (author)

  18. Contextualizing avian mortality: A preliminary appraisal of bird and bat fatalities from wind, fossil-fuel, and nuclear electricity

    Energy Technology Data Exchange (ETDEWEB)

    Sovacool, Benjamin K. [Energy Governance Program, Centre on Asia and Globalisation, Lee Kuan Yew School of Public Policy, National University of Singapore, Singapore 259772 (Singapore)], E-mail: bsovacool@nus.edu.sg

    2009-06-15

    This article explores the threats that wind farms pose to birds and bats before briefly surveying the recent literature on avian mortality and summarizing some of the problems with it. Based on operating performance in the United States and Europe, this study offers an approximate calculation for the number of birds killed per kWh generated for wind electricity, fossil-fuel, and nuclear power systems. The study estimates that wind farms and nuclear power stations are responsible each for between 0.3 and 0.4 fatalities per gigawatt-hour (GWh) of electricity while fossil-fueled power stations are responsible for about 5.2 fatalities per GWh. While this paper should be respected as a preliminary assessment, the estimate means that wind farms killed approximately seven thousand birds in the United States in 2006 but nuclear plants killed about 327,000 and fossil-fueled power plants 14.5 million. The paper concludes that further study is needed, but also that fossil-fueled power stations appear to pose a much greater threat to avian wildlife than wind and nuclear power technologies.

  19. An overview of alternative fossil fuel price and carbon regulation scenarios

    Energy Technology Data Exchange (ETDEWEB)

    Wiser, Ryan; Bolinger, Mark

    2004-10-01

    The benefits of the Department of Energy's research and development (R&D) efforts have historically been estimated under business-as-usual market and policy conditions. In recognition of the insurance value of R&D, however, the Office of Energy Efficiency and Renewable Energy (EERE) and the Office of Fossil Energy (FE) have been exploring options for evaluating the benefits of their R&D programs under an array of alternative futures. More specifically, an FE-EERE Scenarios Working Group (the Working Group) has proposed to EERE and FE staff the application of an initial set of three scenarios for use in the Working Group's upcoming analyses: (1) a Reference Case Scenario, (2) a High Fuel Price Scenario, which includes heightened natural gas and oil prices, and (3) a Carbon Cap-and-Trade Scenario. The immediate goal is to use these scenarios to conduct a pilot analysis of the benefits of EERE and FE R&D efforts. In this report, the two alternative scenarios being considered by EERE and FE staff--carbon cap-and-trade and high fuel prices--are compared to other scenarios used by energy analysts and utility planners. The report also briefly evaluates the past accuracy of fossil fuel price forecasts. We find that the natural gas prices through 2025 proposed in the FE-EERE Scenarios Working Group's High Fuel Price Scenario appear to be reasonable based on current natural gas prices and other externally generated gas price forecasts and scenarios. If anything, an even more extreme gas price scenario might be considered. The price escalation from 2025 to 2050 within the proposed High Fuel Price Scenario is harder to evaluate, primarily because few existing forecasts or scenarios extend beyond 2025, but, at first blush, it also appears reasonable. Similarly, we find that the oil prices originally proposed by the Working Group in the High Fuel Price Scenario appear to be reasonable, if not conservative, based on: (1) the current forward market for oil, (2

  20. Do forests best mitigate CO2 emissions to the atmosphere by setting them aside for maximization of carbon storage or by management for fossil fuel substitution?

    DEFF Research Database (Denmark)

    Taeroe, Anders; Fayez Mustapha, Walid; Stupak, Inge

    2017-01-01

    fossil fuels and fossil fuel intensive materials. We defined a modelling framework for calculation of the carbon pools and fluxes along the forest energy and wood product supply chains over 200 years for three forest management alternatives (FMA): 1) a traditionally managed European beech forest...... the lowest CCE when using coal as the reference fossil fuel. With natural gas as the reference fossil fuel, the CCE of the business-as-usual and the energy poplar was nearly equal, with the unmanaged forest having the highest CCE after 40 years. CPTs ranged from 0 to 156 years, depending on the applied model...... assumptions. CCE and CPT were especially sensitive to the reference fossil fuel, material alternatives to wood, forest growth rates for the three FMAs, and energy conversion efficiencies. Assumptions about the long-term steady-state levels of carbon stored in the unmanaged forest had a limited effect on CCE...

  1. Impact on food productivity by fossil fuel independence - A case study of a Swedish small-scale integrated organic farm

    Energy Technology Data Exchange (ETDEWEB)

    Johansson, Sheshti [Dept. of Energy and Technology, Swedish Univ. of Agricultural Sciences, Uppsala (Sweden); Belfrage, Kristina [Centre for Sustainable Agriculture, Swedish Univ. of Agricultural Sciences, Uppsala (Sweden); Olsson, Mats [Dept. of Soil and Environment, Swedish Univ. of Agricultural Sciences, Uppsala (Sweden)

    2013-02-15

    The large-scale industrial agriculture that provides the majority of food at present is dependent upon fossil fuels in the form of tractor fuel, mineral fertilizers, pesticides, and irrigation. Yet, the age of cheap and abundant fossil fuels will likely come to an end within the coming decades. In this case study, the productivity of a small-scale farm (8 ha arable land, 5.5 ha meadow, 3.5 ha pasture and 18 ha forest) independent on fossil fuels by using organic methods and draught horse power was investigated. The aim was to quantify its productivity when the animal composition and possible alternatives to tractive power were varied. After an analysis of possible solutions, three scenarios for tractive power were selected: draught horse power, diesel tractor, and combination of draught horse power and rapeseed oil fueled tractor. A model that calculates the amount of food available at the farm in terms of meat, milk egg, and crops, converts it into energy units and calculates how many people can be supplied from the farm was developed. The most reasonable of the scenarios studied was when draught horse power was combined with tractor (and combine harvester) driven on locally produced rapeseed oil. Then the farm will have access to all advantages with the tractor and harvester, e.g., timeliness in harvest and lifting heavy loads, and the renewability and efficiency of draught horse power on smaller fields, and lighter operations. This system was able to support between 66 and 82 persons depending on crop yields, milk yields, meat production, fuel demand for the tractor, and availability of forest grazing. Most likely the production capacity lands on ability to support approximately 68 - 70 persons, and the farm may require fossil fuels to support more than 80 persons. If all farmland globally was to be operated with the same productivity, this would be enough for supplying the global population with food at present.

  2. Photodegradation of polycyclic aromatic hydrocarbons in fossil fuels catalysed by supported TiO{sub 2}

    Energy Technology Data Exchange (ETDEWEB)

    Garcia-Martinez, Maria J.; Da Riva, Ignacio; Canoira, Laureano; Llamas, Juan F.; Alcantara, Ramon [Department of Chemical Engineering and Fuels, School of Mines, Technical University of Madrid, Rios Rosas 21, 28003-Madrid (Spain); Gallego, Jose Luis R. [Department of Exploitation and Prospecting for Mines, Campus of Mieres, University of Oviedo, Gonzalo Gutierrez S/N-33600 Mieres, Asturias (Spain)

    2006-10-05

    This paper describes the photodegradation behavior of polycyclic aromatic hydrocarbons present in different types of fossil fuels (commercial diesel, Arabian light crude, heavy fuel oil from the Prestige oil spill and coal from an abandoned coal dump) suspended in artificial seawater or ultrapure water, under irradiation in a stirred photochemical reactor for 14 days. The reactor was continuously fed with air from a compressor at a constant rate of 6NLh{sup -1}, and thin films of TiO{sub 2} (anatase) supported on pyrex glass raschig rings were used as catalyst. Dark control samples were carried out simultaneously for all the experiments, and both phases, aqueous and organic, were analyzed by gas chromatography-mass spectrometry in the experimental and dark control samples, allowing to calculate a photodegradation ratio. The polycyclic aromatic hydrocarbons reached a high degree of photodegradation in the water-soluble fraction of the samples, but the organic fractions remained almost unaffected in most of the experiments. Some photodegradation products have been also identified in the aqueous and organic fractions of the samples. (author)

  3. Implications of Switching Fossil Fuel Subsidies to Solar: A Case Study for the European Union

    Directory of Open Access Journals (Sweden)

    Jon Sampedro

    2017-12-01

    Full Text Available Fossil fuel subsidies (FFS constitute one of the most obvious barriers to tackling climate change, as they encourage inefficient energy consumption and divert investment away from clean energy sources. According to the International Monetary Fund, FFS amounted globally to $233 billion in 2014, over four times the value of subsidies awarded to promote renewable energy. In this study an integrated assessment model is used to analyse the CO2 implications in the European Union of eliminating FFS and recycling the revenues to promote rooftop PV. It is found that eliminating FFS would give rise to a small reduction in CO2 due to fuel-switching from coal to gas. If the revenues were recycled to promote solar, then the CO2 reduction would increase from 1.8% to 2.2% by 2030. Eliminating FFS is not a panacea from the mitigation point of view, even if the revenues are recycled, but other important objectives, such as those related to renewable energy promotion and the reduction of air pollution, are advanced at zero cost for the government.

  4. The effects of hygroscopicity on ice nucleation of fossil fuel combustion aerosols in mixed-phase clouds

    Directory of Open Access Journals (Sweden)

    Y. Yun

    2013-04-01

    Full Text Available Fossil fuel black carbon and organic matter (ffBC/OM are often emitted together with sulfate, which coats the surface of these particles and changes their hygroscopicity. Observational studies at cirrus temperatures (≈−40 °C show that the hygroscopicity of soot particles can modulate their ice nucleation ability. Here, we implement a scheme for 3 categories of soot (hydrophobic, hydrophilic and hygroscopic on the basis of laboratory data and specify their ability to act as ice nuclei at mixed-phase temperatures by extrapolating the observations using a published deposition/condensation/immersion freezing parameterization. The new scheme results in significant changes to anthropogenic forcing in mixed-phase clouds. The net forcing in our offline model studies varies from 0.111 to 1.059 W m−2 depending on the ice nucleation capability of hygroscopic soot particles. The total anthropogenic cloud forcing and whole-sky forcing with the new scheme are 0.06 W m−2 and −2.45 W m−2, respectively, but could be more positive (by about 1.17 W m−2 if hygroscopic soot particles are allowed to nucleate ice particles. The change in liquid water path dominates the anthropogenic forcing in mixed-phase clouds.

  5. 40 CFR 1065.120 - Fuel properties and fuel temperature and pressure.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 32 2010-07-01 2010-07-01 false Fuel properties and fuel temperature... (CONTINUED) AIR POLLUTION CONTROLS ENGINE-TESTING PROCEDURES Equipment Specifications § 1065.120 Fuel properties and fuel temperature and pressure. (a) Use fuels as specified in the standard-setting part, or as...

  6. Cost-effective policy instruments for greenhouse gas emission reduction and fossil fuel substitution through bioenergy production in Austria

    Energy Technology Data Exchange (ETDEWEB)

    Schmidt, Johannes, E-mail: johannes.schmidt@boku.ac.at [Institute for Sustainable Economic Development, University of Natural Resources and Life Sciences, Peter Jordan Strasse 82, A-1190 Vienna (Austria); Leduc, Sylvain [International Institute for Applied Systems Analysis, Schlossplatz 1, A-2361 Laxenburg (Austria); Dotzauer, Erik [Maelardalen University, P.O. Box 883, SE-72123 Vaesteras (Sweden); Schmid, Erwin [Institute for Sustainable Economic Development, University of Natural Resources and Life Sciences, Peter Jordan Strasse 82, A-1190 Vienna (Austria)

    2011-06-15

    Climate change mitigation and security of energy supply are important targets of Austrian energy policy. Bioenergy production based on resources from agriculture and forestry is an important option for attaining these targets. To increase the share of bioenergy in the energy supply, supporting policy instruments are necessary. The cost-effectiveness of these instruments in attaining policy targets depends on the availability of bioenergy technologies. Advanced technologies such as second-generation biofuels, biomass gasification for power production, and bioenergy with carbon capture and storage (BECCS) will likely change the performance of policy instruments. This article assesses the cost-effectiveness of energy policy instruments, considering new bioenergy technologies for the year 2030, with respect to greenhouse gas emission (GHG) reduction and fossil fuel substitution. Instruments that directly subsidize bioenergy are compared with instruments that aim at reducing GHG emissions. A spatially explicit modeling approach is used to account for biomass supply and energy distribution costs in Austria. Results indicate that a carbon tax performs cost-effectively with respect to both policy targets if BECCS is not available. However, the availability of BECCS creates a trade-off between GHG emission reduction and fossil fuel substitution. Biofuel blending obligations are costly in terms of attaining the policy targets. - Highlights: > Costs of energy policies and effects on reduction of CO{sub 2} emissions and fossil fuel consumption. > Particular focus on new bioenergy production technologies such as second generation biofuels. > Spatially explicit techno-economic optimization model. > CO{sub 2} tax: high costs for reducing fossil fuel consumption if carbon capture and storage is available. > Biofuel policy: no significant reductions in CO{sub 2} emissions or fossil fuel consumption.

  7. Direct Experiments on the Ocean Disposal of Fossil Fuel CO2

    Energy Technology Data Exchange (ETDEWEB)

    Barry, James, P.

    2010-05-26

    Funding from DoE grant # FG0204-ER63721, Direct Experiments on the Ocean Disposal of Fossil Fuel CO2, supposed several postdoctoral fellows and research activities at MBARI related to ocean CO2 disposal and the biological consequences of high ocean CO2 levels on marine organisms. Postdocs supported on the project included Brad Seibel, now an associate professor at the University of Rhode Island, Jeff Drazen, now an associate professor at the University of Hawaii, and Eric Pane, who continues as a research associate at MBARI. Thus, the project contributed significantly to the professional development of young scientists. In addition, we made significant progress in several research areas. We continued several deep-sea CO2 release experiments using support from DoE and MBARI, along with several collaborators. These CO2 release studies had the goal of broadening our understanding of the effects of high ocean CO2 levels on deep sea animals in the vicinity of potential release sites for direct deep-ocean carbon dioxide sequestration. Using MBARI ships and ROVs, we performed these experiments at depths of 3000 to 3600 m, where liquid CO2 is heavier than seawater. CO2 was released into small pools (sections of PVC pipe) on the seabed, where it dissolved and drifted downstream, bathing any caged animals and sediments in a CO2-rich, low-pH plume. We assessed the survival of organisms nearby. Several publications arose from these studies (Barry et al. 2004, 2005; Carman et al. 2004; Thistle et al. 2005, 2006, 2007; Fleeger et al. 2006, 2010; Barry and Drazen 2007; Bernhard et al. 2009; Sedlacek et al. 2009; Ricketts et al. in press; Barry et al, in revision) concerning the sensitivity of animals to low pH waters. Using funds from DoE and MBARI, we designed and fabricated a hyperbaric trap-respirometer to study metabolic rates of deep-sea fishes under high CO2 conditions (Drazen et al, 2005), as well as a gas-control aquarium system to support laboratory studies of the

  8. Fluoride and chloride determination in fossil fuels after sample preparation by pyrohydrolysis; Preparo de amostras de combustiveis fosseis por piroidrolise para a determinacao de fluor e cloro

    Energy Technology Data Exchange (ETDEWEB)

    Antes, Fabiane G.; Duarte, Fabio A.; Flores, Eder L. M.; Paniz, Jose Neri G.; Flores, Erico M. M.; Dressler, Valderi L., E-mail: valdres@quimica.ufsm.b [Universidade Federal de Santa Maria (DQ/UFSM), RS (Brazil). Dept. de Quimica

    2010-07-01

    Pyrohydrolysis is proposed for fossil fuels sample preparation for further fluorine and chlorine determination. Samples were heated during 10 min at temperatures up to 1000 deg C. Water vapor was passed through the reactor and the volatile products were condensed and collected in NH{sub 4}OH solution. Fluoride was determined by potentiometry using an ion selective electrode (ISE) and Cl by ICP OES and DRC-ICP-MS. The results are in good agreement with certified values and the precision is better than 10% (n = 4). Sample preparation by means of pyrohydrolysis is relatively simple, whereas chlorine and fluorine can be determined at low concentrations (author)

  9. High Temperature Polymer Electrolyte Fuel Cells

    DEFF Research Database (Denmark)

    Fleige, Michael

    This thesis presents the development and application of electrochemical half-cell setups to study the catalytic reactions taking place in High Temperature Polymer Electrolyte Fuel Cells (HTPEM-FCs): (i) a pressurized electrochemical cell with integrated magnetically coupled rotating disk electrode...... to 140 ºC and oxygen pressures up to ~100 bar at room temperature. The GDE cell is successfully tested at 130 ºC by means of direct oxidation of methanol and ethanol, respectively. In the second part of the thesis, the emphasis is put on the ORR in H3PO4 with particular focus on the mass transport...... oxidation of ethanol is in principle a promising concept to supply HTPEM-FCs with a sustainable and on large scale available fuel (ethanol from biomass). However, the intermediate temperature tests in the GDE setup show that even on Pt-based catalysts the reaction rates become first significant...

  10. Fossil fuels: technical, economical and political challenges for 2030-2050; Combustibles fossiles: enjeux techniques, economiques et politiques a l'horizon 2030-2050

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2004-07-01

    This panorama takes stock on the international energy actuality in 2003 and discusses the instability of the geo-political context of the energy and the part of the fossil fuels for the future years 2030-2050. The following topics were presented: activities and market for the exploration-production, refining and petrochemistry, the world gas trade situation, the petroleum supply and demand, the Iraq, the diesel in the USA, the investments and the depletion, long-dated evolutions of motors and fuels, implementing of the european directive concerning the market of tradable permits of CO{sub 2}, the carbon sequestration, hydrogen the energy of the future and the biofuels in Europe. (A.L.B.)

  11. Estimating Human Health Impacts and Costs Due to Iranian Fossil Fuel Power Plant Emissions through the Impact Pathway Approach

    Directory of Open Access Journals (Sweden)

    Mojtaba Jorli

    2017-12-01

    Full Text Available Air pollutants from fossil fuel fired power plants harm the environment and human health. More than 91% of Iran’s electricity production is from thermal power plants that use natural gas, diesel, and fuel oil. We apply the impact pathway approach to estimate the health impacts arising from Iranian fossil-based electricity generation emission, and in a next step, we calculate monetary costs of the estimated damages, for a one-year period starting from 20 March 2016 through 2017. We use the new version of SIMPACTS (International Atomic Energy Agency, Vienna, Austria to investigate the health effects from 61 major Iran fossil-based power plants separately. The selected plants represent 95.6% of total Iran fossil-based power generation. Using the individual and different power plant estimates, we avoid extrapolation and our results can be considered more reliable, taking into account spatial differences. The total damage cost is 723.42 million USD (2000. The damage cost per generated electricity varies from 0.06 to 22.41 USD/MWh and average plant damage cost is 2.85 USD/MWh. Accounting for these external costs indicates the actual costs of fossil energy. The results are useful for policy makers to compare the health costs from these plants and to decide on cleaner energy sources and to take measures to increase benefits for society.

  12. Spatiotemporal patterns of the fossil-fuel CO2 signal in central Europe: results from a high-resolution atmospheric transport model

    Science.gov (United States)

    Liu, Yu; Gruber, Nicolas; Brunner, Dominik

    2017-11-01

    The emission of CO2 from the burning of fossil fuel is a prime determinant of variations in atmospheric CO2. Here, we simulate this fossil-fuel signal together with the natural and background components with a regional high-resolution atmospheric transport model for central and southern Europe considering separately the emissions from different sectors and countries on the basis of emission inventories and hourly emission time functions. The simulated variations in atmospheric CO2 agree very well with observation-based estimates, although the observed variance is slightly underestimated, particularly for the fossil-fuel component. Despite relatively rapid atmospheric mixing, the simulated fossil-fuel signal reveals distinct annual mean structures deep into the troposphere, reflecting the spatially dense aggregation of most emissions. The fossil-fuel signal accounts for more than half of the total (fossil fuel + biospheric + background) temporal variations in atmospheric CO2 in most areas of northern and western central Europe, with the largest variations occurring on diurnal timescales owing to the combination of diurnal variations in emissions and atmospheric mixing and transport out of the surface layer. The covariance of the fossil-fuel emissions and atmospheric transport on diurnal timescales leads to a diurnal fossil-fuel rectifier effect of up to 9 ppm compared to a case with time-constant emissions. The spatial pattern of CO2 from the different sectors largely reflects the distribution and relative magnitude of the corresponding emissions, with power plant emissions leaving the most distinguished mark. An exception is southern and western Europe, where the emissions from the transportation sector dominate the fossil-fuel signal. Most of the fossil-fuel CO2 remains within the country responsible for the emission, although in smaller countries up to 80 % of the fossil-fuel signal can come from abroad. A fossil-fuel emission reduction of 30 % is clearly

  13. Intermediate Temperature Solid Oxide Fuel Cell Development

    Energy Technology Data Exchange (ETDEWEB)

    S. Elangovan; Scott Barnett; Sossina Haile

    2008-06-30

    Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600

  14. Atmospheric Fossil Fuel CO2 Tracing By 14C In Some Chinese Cities

    Science.gov (United States)

    Zhou, W.; Niu, Z.; Zhu, Y., Sr.

    2016-12-01

    CO2 plays an important role in global climate as a primary greenhouse gas in the atmosphere. Moreover, it has been shown that more than 70% of global fossil fuel CO2 (CO2ff) emissions are concentrated in urban areas (Duren and Miller, 2012). Our study focuses on atmospheric CO2ff concentrations in 15 Chinese cities using accelerator mass spectrometer (AMS) to measure 14C. Our objectives are: (1) to document atmospheric CO2ff concentrations in a variety of urban environments, (2) to differentiate the spatial-temporal variations in CO2ff among these cities, and (3) to ascertain the factors that control the observed variations. For about two years (winter 2014 to winter 2016), the CO2ff concentrations we observed from all sites varied from 5.1±4.5 ppm to 65.8±39.0 ppm. We observed that inland cities display much higher CO2ff concentrations and overall temporal variations than coastal cities in winter, and that northern cities have higher CO2ff concentrations than those of southern cities in winter. For inland cities relatively high CO2ff values are observed in winter and low values in summer; while seasonal variations are not distinct in the coastal cities. No significant (p > 0.05) differences in CO2ff values are found between weekdays and weekends as was shown previously in Xi'an (Zhou et al., 2014). Diurnal CO2ff variations are plainly evident, with high values between midnight and 4:00 am, and during morning and afternoon rush hours (Niu et al., 2016). The high CO2ff concentrations in northern inland cities in winter results mainly from the substantial consumption of fossil fuels for heating. The high CO2ff concentrations seen in diurnal measurements result mainly from variations in atmospheric dispersion, and from vehicle emissions related to traffic flows. The inter-annual variations in CO2ff in cities could provide a useful reference for local governments to develop policy around the effect of energy conservation and emission reduction strategies.

  15. Quantification of space/time explicit fossil fuel CO2 emissions in urban domains

    Science.gov (United States)

    Gurney, K. R.; Razlivanov, I. N.; Song, Y.

    2013-05-01

    Quantification of fossil fuel CO2 emissions from the bottom-up perspective is a critical element in development of a carbon monitoring system. A space/time explicit emissions data product can verify atmospheric CO2 measurements and offer practical information to authorities in order to optimize mitigation efforts. Here, we present the Hestia Project, an effort aimed at building a high resolution (eg. building and road link-specific, hourly) fossil fuel CO2 emissions data product for the urban domain. A complete data product has been built for the city of Indianapolis and work is ongoing in Los Angeles. The work in Indianapolis is now part of a larger effort, INFLUX, aimed at a convergent top-down/bottom-up assessment of greenhouse gas emissions. The work in Los Angeles with JPL colleagues is aimed at building an operational carbon monitoring system with focus on global megacities. Our urban-level quantification relies on a mixture of data and modeling structures. We start with the sector-specific Vulcan Project estimate using Hestia to distribute emissions in space and time. Two components take the majority of effort: buildings and onroad emissions. For the buildings, we utilize an energy building model constrained with multiple local data streams. For onroad emissions, we use a combination of traffic data and GIS road layers maintaining vehicle class information. In collaboration with our INFLUX colleagues, we are transporting these high resolution emissions through an atmospheric transport model for a forward comparison of the Hestia data product with atmospheric measurements, collected on aircraft and cell towers. In collaboration with our JPL colleagues, we are testing the feasibility of quantifying a megacity domain and how it might integrate with remote sensing and in situ measurement systems. The Hestia effort also holds promise for a useable policy tool at the city scale. With detailed information on energy consumption and emissions with process

  16. Bioethanol from poplar clone Imola: an environmentally viable alternative to fossil fuel?

    Science.gov (United States)

    Guo, Miao; Li, Changsheng; Facciotto, Gianni; Bergante, Sara; Bhatia, Rakesh; Comolli, Roberto; Ferré, Chiara; Murphy, Richard

    2015-01-01

    Environmental issues, e.g. climate change, fossil resource depletion have triggered ambitious national/regional policies to develop biofuel and bioenergy roles within the overall energy portfolio to achieve decarbonising the global economy and increase energy security. With the 10 % binding target for the transport sector, the Renewable Energy Directive confirms the EU's commitment to renewable transport fuels especially advanced biofuels. Imola is an elite poplar clone crossed from Populus deltoides Bartr. and Populus nigra L. by Research Units for Intensive Wood Production, Agriculture Research Council in Italy. This study examines its suitability for plantation cultivation under short or very short rotation coppice regimes as a potential lignocellulosic feedstock for the production of ethanol as a transport biofuel. A life cycle assessment (LCA) approach was used to model the cradle-to-gate environmental profile of Imola-derived biofuel benchmarked against conventional fossil gasoline. Specific attention was given to analysing the agroecosystem fluxes of carbon and nitrogen occurring in the cultivation of the Imola biomass in the biofuel life cycle using a process-oriented biogeochemistry model (DeNitrification-DeComposition) specifically modified for application to 2G perennial bioenergy crops and carbon and nitrogen cycling. Our results demonstrate that carbon and nitrogen cycling in perennial crop-soil ecosystems such as this example can be expected to have significant effects on the overall environmental profiles of 2G biofuels. In particular, soil carbon accumulation in perennial biomass plantations is likely to be a significant component in the overall greenhouse gas balance of future biofuel and other biorefinery products and warrants ongoing research and data collection for LCA models. We conclude that bioethanol produced from Imola represents a promising alternative transport fuel offering some savings ranging from 35 to 100 % over petrol in global

  17. Current fossil fuel power plant performance monitoring. Volume 1. Practices. Final report

    Energy Technology Data Exchange (ETDEWEB)

    Dixon, R.R.; Kraje, N.B.; Roberts, R.C.

    1984-01-01

    A description of current fossil power industry performance monitoring and control practices is presented. Both standard ASME acceptance testing procedures and individualized plant performance testing procedures are reviewed. The instrumentation required for performance testing, along with its limitations, is cited. A review of digital computer uses is presented, including some examples of typical performance related logs used by a few utilities. Control functions that affect plant performance, such as steam temperature control, are discussed, and the potential impact of several of the above issues on economic dispatching is mentioned. It is concluded that there is no typical utility or common practice regarding performance improvement. Each utility has its own strategy, practice, and methods or lack thereof. Furthermore, knowledge of what other utilities are doing, successfully and unsuccessfully, is lacking. The recommendations stress better information dissemination, more quantitative evaluation of advanced concepts, and initiation of a few high priority research projects.

  18. Delta13C values of grasses as a novel indicator of pollution by fossil-fuel-derived greenhouse gas CO2 in urban areas.

    Science.gov (United States)

    Lichtfouse, Eric; Lichtfouse, Michel; Jaffrézic, Anne

    2003-01-01

    A novel fossil fuel pollution indicator based on the 13C/12C isotopic composition of plants has been designed. This bioindicator is a promising tool for future mapping of the sequestration of fossil fuel CO2 into urban vegetation. Theoretically, plants growing in fossil-fuel-CO2-contaminated areas, such as major cities, industrial centers, and highway borders, should assimilate a mixture of global atmospheric CO2 of delta13C value of -8.02 per thousand and of fossil fuel CO2 of average delta13C value of -27.28 per thousand. This isotopic difference should, thus, be recorded in plant carbon. Indeed, this study reveals that grasses growing near a major highway in Paris, France, have strikingly depleted delta13C values, averaging at -35.08 per thousand, versus rural grasses that show an average delta13C value of -30.59 per thousand. A simple mixing model was used to calculate the contributions of fossil-fuel-derived CO2 to the plant tissue. Calculation based on contaminated and noncontaminated isotopic end members shows that urban grasses assimilate up to 29.1% of fossil-fuel-CO2-derived carbon in their tissues. The 13C isotopic composition of grasses thus represents a promising new tool for the study of the impact of fossil fuel CO2 in major cities.

  19. Assessing the potential long-term increase of oceanic fossil fuel CO2 uptake due to CO2-calcification feedback

    Science.gov (United States)

    Ridgwell, A.; Zondervan, I.; Hargreaves, J. C.; Bijma, J.; Lenton, T. M.

    2007-07-01

    Plankton manipulation experiments exhibit a wide range of sensitivities of biogenic calcification to simulated anthropogenic acidification of the ocean, with the "lab rat" of planktic calcifiers, Emiliania huxleyi apparently not representative of calcification generally. We assess the implications of this observational uncertainty by creating an ensemble of realizations of an Earth system model that encapsulates a comparable range of uncertainty in calcification response to ocean acidification. We predict that a substantial reduction in marine carbonate production is possible in the future, with enhanced ocean CO2 sequestration across the model ensemble driving a 4-13% reduction in the year 3000 atmospheric fossil fuel CO2 burden. Concurrent changes in ocean circulation and surface temperatures in the model contribute about one third to the increase in CO2 uptake. We find that uncertainty in the predicted strength of CO2-calcification feedback seems to be dominated by the assumption as to which species of calcifier contribute most to carbonate production in the open ocean.

  20. Assessing the potential long-term increase of oceanic fossil fuel CO2 uptake due to CO2-calcification feedback

    Directory of Open Access Journals (Sweden)

    T. M. Lenton

    2007-07-01

    Full Text Available Plankton manipulation experiments exhibit a wide range of sensitivities of biogenic calcification to simulated anthropogenic acidification of the ocean, with the "lab rat" of planktic calcifiers, Emiliania huxleyi apparently not representative of calcification generally. We assess the implications of this observational uncertainty by creating an ensemble of realizations of an Earth system model that encapsulates a comparable range of uncertainty in calcification response to ocean acidification. We predict that a substantial reduction in marine carbonate production is possible in the future, with enhanced ocean CO2 sequestration across the model ensemble driving a 4–13% reduction in the year 3000 atmospheric fossil fuel CO2 burden. Concurrent changes in ocean circulation and surface temperatures in the model contribute about one third to the increase in CO2 uptake. We find that uncertainty in the predicted strength of CO2-calcification feedback seems to be dominated by the assumption as to which species of calcifier contribute most to carbonate production in the open ocean.

  1. Climate Change Effects of Forest Management and Substitution of Carbon-Intensive Materials and Fossil Fuels

    Science.gov (United States)

    Sathre, R.; Gustavsson, L.; Haus, S.; Lundblad, M.; Lundström, A.; Ortiz, C.; Truong, N.; Wikberg, P. E.

    2016-12-01

    Forests can play several roles in climate change mitigation strategies, for example as a reservoir for storing carbon and as a source of renewable materials and energy. To better understand the linkages and possible trade-offs between different forest management strategies, we conduct an integrated analysis where both sequestration of carbon in growing forests and the effects of substituting carbon intensive products within society are considered. We estimate the climate effects of directing forest management in Sweden towards increased carbon storage in forests, with more land set-aside for protection, or towards increased forest production for the substitution of carbon-intensive materials and fossil fuels, relative to a reference case of current forest management. We develop various scenarios of forest management and biomass use to estimate the carbon balances of the forest systems, including ecological and technological components, and their impacts on the climate in terms of cumulative radiative forcing over a 100-year period. For the reference case of current forest management, increasing the harvest of forest residues is found to give increased climate benefits. A scenario with increased set-aside area and the current level of forest residue harvest begins with climate benefits compared to the reference scenario, but the benefits cannot be sustained for 100 years because the rate of carbon storage in set-aside forests diminishes over time as the forests mature, but the demand for products and fuels remains. The most climatically beneficial scenario, expressed as reduced cumulative radiative forcing, in both the short and long terms is a strategy aimed at high forest production, high residue recovery rate, and high efficiency utilization of harvested biomass. Active forest management with high harvest level and efficient forest product utilization will provide more climate benefit, compared to reducing harvest and storing more carbon in the forest. Figure

  2. Innovative fossil fuel fired vitrification technology for soil remediation. Phase 1

    Energy Technology Data Exchange (ETDEWEB)

    1994-01-01

    Vortec has successfully completed Phase 1 of the ``Innovative Fossil Fuel Fired Vitrification Technology for Soil Remediation`` program. The Combustion and Melting System (CMS) has processed 7000 pounds of material representative of contaminated soil that is found at DOE sites. The soil was spiked with Resource Conservation and Recovery Act (RCRA) metals surrogates, an organic contaminant, and a surrogate radionuclide. The samples taken during the tests confirmed that virtually all of the radionuclide was retained in the glass and that it did not leach to the environment-as confirmed by both ANS 16.1 and Toxicity Characteristic Leaching Procedure (TCLP) testing. The organic contaminant, anthracene, was destroyed during the test with a Destruction and Removal Efficiency (DRE) of at least 99.99%. RCRA metal surrogates, that were in the vitrified product, were retained and did not leach to the environment as confirmed by the TCLP testing. Semi-volatile RCRA metal surrogates were captured by the Air Pollution Control (APC) system, and data on the amount of metal oxide particulate and the chemical composition of the particulate were established for use in the Phase 2 APC subsystem design.

  3. The Zero Emission Fossil Fuel Power Plant - from vision to reality.

    Energy Technology Data Exchange (ETDEWEB)

    Stroemberg, L.; Sauthoff, M.

    2007-07-01

    Sufficient supply of energy without fossil fuels is not possible the next fifty years. Thus, we must find a solution to use coal, without endangering the environment. Carbon Capture and Storage, CCS, might be the answer. At a cost of about 20 Euro/ton CO{sub 2}, there exist technologies, which can be ready for commercial application in 2020. After that, even more cost effective technologies will be developed. To reduce emissions by more than half until 2050, cannot be reached without CCS. However, CCS is very powerful, but not the only tool. All ways to reduce emissions, including renewables and nuclear must be used. To put emphasis behind the words, Vattenfall has started an R and D program to develop technology for CCS in a ten year program. As part of that, Vattenfall is building a Pilot Plant including all process steps from coal input to liquid CO{sub 2}. It will be ready in 2008. In parallel, preparations for a demonstration plant are ongoing. It will be a coal fired full size plant with storage on shore. That will be ready for operation in 2015. (auth)

  4. Integral power evaluation in fossil fuel power plants; Evaluacion energetica integral en unidades de centrales termoelectricas

    Energy Technology Data Exchange (ETDEWEB)

    Figueroa I, Luis R; Sanchez H, Laura E; Rodriguez M, Jose H [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico); Nebradt G, Jesus [Unidad de Investigacion y Desarrollo de la Subdireccion de Generacion de la Comision Federal de Electricidad, (Mexico)

    2006-07-01

    In this occasion, a methodology is presented that carries out an integral energy evaluation of fossil fuel power plants units (FFPPU) with the purpose of determining the root of the significant decrements of power produced soon after the annual maintenance service. This proposal, besides identifying the origin of the energy efficiency problems, offers information about the contributions of each one of the involved equipment in the total decrement of the unit. With this methodology, the maintenance focuses in the equipment that contributes to the greater energy loss. This document presents such methodology along with its application in a real case, results and necessary remedial actions, demonstrating that its application offers bases for the investment in corrective measures. [Spanish] En esta ocasion se presenta una metodologia que efectua una evaluacion energetica integral de las unidades de centrales termoelectricas (UCT) con el fin de determinar la raiz de los decrementos de potencia significativos producidos luego del servicio anual de mantenimiento. Dicha propuesta, ademas de identificar el origen de los problemas de eficiencia energetica, brinda informacion acerca de las aportaciones de cada uno de los equipos involucrados al decremento total de la unidad. Con esta metodologia, el mantenimiento se enfoca a los equipos que contribuyen a la mayor perdida de potencia. Este documento exhibe tal metodologia junto con su aplicacion en un caso real, resultados y las acciones correctivas necesarias, demostrando que su aplicacion ofrece bases para una inversion futura en medidas correctivas.

  5. Response of the global climate to changes in atmospheric chemical composition due to fossil fuel burning

    Science.gov (United States)

    Hameed, S.; Cess, R. D.; Hogan, J. S.

    1980-01-01

    Recent modeling of atmospheric chemical processes (Logan et al, 1978; Hameed et al, 1979) suggests that tropospheric ozone and methane might significantly increase in the future as the result of increasing anthropogenic emissions of CO, NO(x), and CH4 due to fossil fuel burning. Since O3 and CH4 are both greenhouse gases, increases in their concentrations could augment global warming due to larger future amounts of atmospheric CO2. To test the possible climatic impact of changes in tropospheric chemical composition, a zonal energy-balance climate model has been combined with a vertically averaged tropospheric chemical model. The latter model includes all relevant chemical reactions which affect species derived from H2O, O2, CH4, and NO(x). The climate model correspondingly incorporates changes in the infrared heating of the surface-troposphere system resulting from chemically induced changes in tropospheric ozone and methane. This coupled climate-chemical model indicates that global climate is sensitive to changes in emissions of CO, NO(x) and CH4, and that future increases in these emissions could augment global warming due to increasing atmospheric CO2.

  6. Improving the Carbon Dioxide Emission Estimates from the Combustion of Fossil Fuels in California

    Energy Technology Data Exchange (ETDEWEB)

    de la Rue du Can, Stephane; Wenzel, Tom; Price, Lynn

    2008-08-13

    Central to any study of climate change is the development of an emission inventory that identifies and quantifies the State's primary anthropogenic sources and sinks of greenhouse gas (GHG) emissions. CO2 emissions from fossil fuel combustion accounted for 80 percent of California GHG emissions (CARB, 2007a). Even though these CO2 emissions are well characterized in the existing state inventory, there still exist significant sources of uncertainties regarding their accuracy. This report evaluates the CO2 emissions accounting based on the California Energy Balance database (CALEB) developed by Lawrence Berkeley National Laboratory (LBNL), in terms of what improvements are needed and where uncertainties lie. The estimated uncertainty for total CO2 emissions ranges between -21 and +37 million metric tons (Mt), or -6percent and +11percent of total CO2 emissions. The report also identifies where improvements are needed for the upcoming updates of CALEB. However, it is worth noting that the California Air Resources Board (CARB) GHG inventory did not use CALEB data for all combustion estimates. Therefore the range in uncertainty estimated in this report does not apply to the CARB's GHG inventory. As much as possible, additional data sources used by CARB in the development of its GHG inventory are summarized in this report for consideration in future updates to CALEB.

  7. Various Perspectives of Mitigating Fossil Fuel Use and Air Pollutant Emissions in China's Megacity

    Science.gov (United States)

    Wang, H.

    2014-12-01

    It is critical to reduce energy use and air pollutions in metropolitan areas because these areas usually serve as economic engines and have large, dense populations. Fossil fuel use and air-polluting emissions were analyzed in Beijing between 1997 and 2010 from both a bottom-up and a top-down perspective. From a bottom-up perspective, the key energy-intensive industrial sectors directly caused changes in Beijing's air pollution by means of a series of energy and economic policies. From a top-down perspective, variation in industrial production caused increases in most emissions between 2000 and 2010, however, there were decreases in PM10 and PM2.5 emissions during 2005-2010. Population growth was found to be the largest driver of energy consumption and emissions between1997 and 2010. Energy use and air pollutant emissions were also found to outsource from Beijing to other regions in China. Policies for reducing urban energy consumption and emissions should consider not only the key industrial sectors but also socioeconomic drivers.

  8. TOWARDS A RESILIENT ENERGY SYSTEM IN EASTERN ROMANIA – FROM FOSSIL FUELS TO RENEWABLE SOURCES

    Directory of Open Access Journals (Sweden)

    BĂNICĂ Alexandru

    2015-12-01

    Full Text Available The study takes into account the two Romanian Eastern regions (North East and South East trying to emphasize the post-communist dynamics of the energy sector in order to draw a general perspective for the future evolution towards both energy security and a clean environment. Before 1989, the energy sector, that had to sustain not only the population needs, but also an oversized manufacturing industry, was based on big power plants usually using coal and oil and highly polluting the environment. The hydropower had a rather small share in the total energy production. This inherited system was very much resistant after the end of the centralized political system, therefore after the general industrial decline the energy sector remained the main source of air pollution in many towns and cities from Romania. Meanwhile, in the last 6-7 years, due to a favourable national political context, we assisted, especially in the analysed area, to an important emergence of renewable energy investments (mainly wind and solar energy, but also biomass or hydro-energy. Our purpose is to evaluate, from a geographical point of view, the extent and the implications of a desirable progressive shift from fossil fuels to renewable energy that could radically change the territorial relations and sustain development on the long term.

  9. Mapping Global Flows of Chemicals: From Fossil Fuel Feedstocks to Chemical Products.

    Science.gov (United States)

    Levi, Peter G; Cullen, Jonathan M

    2018-02-20

    Chemical products are ubiquitous in modern society. The chemical sector is the largest industrial energy consumer and the third largest industrial emitter of carbon dioxide. The current portfolio of mitigation options for the chemical sector emphasizes upstream "supply side" solutions, whereas downstream mitigation options, such as material efficiency, are given comparatively short shrift. Key reasons for this are the scarcity of data on the sector's material flows, and the highly intertwined nature of its complex supply chains. We provide the most up to date, comprehensive and transparent data set available publicly, on virgin production routes in the chemical sector: from fossil fuel feedstocks to chemical products. We map global mass flows for the year 2013 through a complex network of transformation processes, and by taking account of secondary reactants and by-products, we maintain a full mass balance throughout. The resulting data set partially addresses the dearth of publicly available information on the chemical sector's supply chain, and can be used to prioritise downstream mitigation options.

  10. Efficiency-improving fossil fuel technologies for electricity generation: Data selection and trends

    Energy Technology Data Exchange (ETDEWEB)

    Lanzi, Elisa [Fondazione Eni Enrico Mattei (Italy); Verdolini, Elena, E-mail: elena.verdolini@feem.it [Fondazione Eni Enrico Mattei (Italy); Universita Cattolica, del Sacro Cuore di Milano (Italy); Hascic, Ivan [OECD Environment Directorate (France)

    2011-11-15

    This paper studies patenting dynamics in efficiency improving electricity generation technologies as an important indicator of innovation activity. We build a novel database of worldwide patent applications in efficiency-improving fossil fuel technologies for electricity generation and then analyse patenting trends over time and across countries. We find that patenting has mostly been stable over time, with a recent decreasing trend. OECD countries represent the top innovators and the top markets for technology. Some non-OECD countries, and particularly China, are also very active in terms of patenting activity in this sector. The majority of patents are first filed in OECD countries and only then in BRIC and other non-OECD countries. BRIC and other non-OECD countries apply for patents that are mostly marketed domestically, but BRIC countries represent important markets for patent duplication of OECD inventions. These results are indicative of significant technology transfer in the field of efficiency-improving technologies for electricity production. - Highlights: > We study innovation in efficiency-improving electricity generation technologies. > Relevant patents are identified and used as an indicator of innovation. > We show that there is significant technology transfer in this field. > Most patents are first filed in OECD countries and then in non-OECD countries. > Patents in non-OECD countries are mostly marketed domestically.

  11. The future of airborne sulfur-containing particles in the absence of fossil fuel sulfur dioxide emissions.

    Science.gov (United States)

    Perraud, Véronique; Horne, Jeremy R; Martinez, Andrew S; Kalinowski, Jaroslaw; Meinardi, Simone; Dawson, Matthew L; Wingen, Lisa M; Dabdub, Donald; Blake, Donald R; Gerber, R Benny; Finlayson-Pitts, Barbara J

    2015-11-03

    Sulfuric acid (H2SO4), formed from oxidation of sulfur dioxide (SO2) emitted during fossil fuel combustion, is a major precursor of new airborne particles, which have well-documented detrimental effects on health, air quality, and climate. Another precursor is methanesulfonic acid (MSA), produced simultaneously with SO2 during the atmospheric oxidation of organosulfur compounds (OSCs), such as dimethyl sulfide. In the present work, a multidisciplinary approach is used to examine how contributions of H2SO4 and MSA to particle formation will change in a large coastal urban area as anthropogenic fossil fuel emissions of SO2 decline. The 3-dimensional University of California Irvine-California Institute of Technology airshed model is used to compare atmospheric concentrations of gas phase MSA, H2SO4, and SO2 under current emissions of fossil fuel-associated SO2 and a best-case futuristic scenario with zero fossil fuel sulfur emissions. Model additions include results from (i) quantum chemical calculations that clarify the previously uncertain gas phase mechanism of formation of MSA and (ii) a combination of published and experimental estimates of OSC emissions, such as those from marine, agricultural, and urban processes, which include pet waste and human breath. Results show that in the zero anthropogenic SO2 emissions case, particle formation potential from H2SO4 will drop by about two orders of magnitude compared with the current situation. However, particles will continue to be generated from the oxidation of natural and anthropogenic sources of OSCs, with contributions from MSA and H2SO4 of a similar order of magnitude. This could be particularly important in agricultural areas where there are significant sources of OSCs.

  12. Optimal Design of a Fossil Fuel-Based Hydrogen Infrastructure with Carbon Capture and Sequestration: Case Study in Ohio

    OpenAIRE

    Johnson, Nils; Yang, Christopher; Ni, Jason; Johnson, Joshua; Lin, Zhenhong; Ogden, Joan M

    2005-01-01

    Presented at the National Hydrogen Association Annual Hydrogen Conference (NHA 2005), Washington, DC, March 29 - April 1, 2005 The use of hydrogen as a light-duty transportation fuel requires the development of a widespread regional hydrogen infrastructure, including production facilities, a distribution network, and refueling stations. In the case of fossil-based hydrogen production with carbon capture and sequestration, additional infrastructure is needed for CO2 disposal. If const...

  13. A multiresolution spatial parameterization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions

    Directory of Open Access Journals (Sweden)

    J. Ray

    2014-09-01

    Full Text Available The characterization of fossil-fuel CO2 (ffCO2 emissions is paramount to carbon cycle studies, but the use of atmospheric inverse modeling approaches for this purpose has been limited by the highly heterogeneous and non-Gaussian spatiotemporal variability of emissions. Here we explore the feasibility of capturing this variability using a low-dimensional parameterization that can be implemented within the context of atmospheric CO2 inverse problems aimed at constraining regional-scale emissions. We construct a multiresolution (i.e., wavelet-based spatial parameterization for ffCO2 emissions using the Vulcan inventory, and examine whether such a~parameterization can capture a realistic representation of the expected spatial variability of actual emissions. We then explore whether sub-selecting wavelets using two easily available proxies of human activity (images of lights at night and maps of built-up areas yields a low-dimensional alternative. We finally implement this low-dimensional parameterization within an idealized inversion, where a sparse reconstruction algorithm, an extension of stagewise orthogonal matching pursuit (StOMP, is used to identify the wavelet coefficients. We find that (i the spatial variability of fossil-fuel emission can indeed be represented using a low-dimensional wavelet-based parameterization, (ii that images of lights at night can be used as a proxy for sub-selecting wavelets for such analysis, and (iii that implementing this parameterization within the described inversion framework makes it possible to quantify fossil-fuel emissions at regional scales if fossil-fuel-only CO2 observations are available.

  14. Effective utilization of fossil fuels for low carbon world -- IGCC and high performance gas turbine

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Hiromi; Hashimoto, Takao; Sakamoto, Koichi; Komori, Toyoaki; Kishine, Takashi; Shiozaki, Shigehiro

    2010-09-15

    The reduction of greenhouse-gas emissions is required to minimize the effect of hydrocarbon based power generation on global warming. In pursue of this objective, Mitsubishi Heavy Industries is dedicating considerable efforts on two different ways to reduce the environmental impact. The first one involves gas turbine performance improvement by raising firing temperature for Natural-gas and LNG applications. In this regard, the latest J class gas turbine was designed to operate at 1600 deg C and expected combined cycle efficiency in excess of 60%. The other approach involves the use of Integrated Gasification Combined Cycle (IGCC) plants to burn solid fuel like coal.

  15. A very high-resolution (1 km?1 km) global fossil fuel CO2 emission inventory derived using a point source database and satellite observations of nighttime lights

    National Research Council Canada - National Science Library

    T. Oda; S. Maksyutov

    2011-01-01

    .... We developed a global 1 km×1 km annual fossil fuel CO 2 emission inventory for the years 1980-2007 by combining a worldwide point source database and satellite observations of the global nightlight distribution...

  16. A numerical analysis of worldwide CO{sub 2} emissions based on fossil fuels and effects on atmospheric warming in Turkey

    Energy Technology Data Exchange (ETDEWEB)

    Tokgoz, Nuray

    2007-07-01

    The climate system of the earth, globally and locally, obviously has been changed from pre-industrial period to present. Some of the changes are due to human activities where the vital role has been played by the emission. Fossil fuels (coal, natural gas, oil), the raw materials for energy, play an effective and determining role in the development and sustenance of industrial development, as well as in the energy planning in all major countries. When global and regional geographies are evaluated from the geo-strategic and geo-political points of view, it is clearly seen that among all fossil fuels, coal is distributed more 'equally' in ratio than oil and natural gas reserves. Coal is gradually gaining importance for countries that do not have energy resources, have limited ones, or have resources on the verge of exhaustion. With the latest environmentally-friendly technological innovations in the field of burning-storing CO2 emissions in thermal power plants and given today's emphasis on the principle of 'sustainable development,' it is an undeniable fact that coal will continue to be a significant primary energy resource in the future, both in Turkey and around the world. In this study, in order to numerically calculate the impact of CO2 from fossil fuel consumption on global warming and the process of climate change, a global scale numerical evaluation has been constructed. The evaluation utilizes the 'total primary energy supply (TPES) - CO2 emission' from 136 countries in 2004 together with such basic indicators as 'TPES/capita' and 'ton CO2/capita'. The potential CO2 emission for the year 2030 has also been estimated. Moreover, to maintain the integrity of the subject under study, the distribution of thermal power plants utilizing fossil fuels among the differing geographical regions of Turkey, the relationship between forests (F) in these regions, and the average annual increase in temperature ({delta

  17. Clean uses of fossil fuels. Progress performance report, September 29, 1991--January 25, 1994

    Energy Technology Data Exchange (ETDEWEB)

    Stencel, J.M.

    1994-01-25

    Science and engineering doctoral students performing energy related research were supported by a USDOE/ESPCoR Traineeship grant awarded to the Kentucky EPSCoR Committee. The grant, administered by the KY DOE/EPSCoR Subcommittee, focused on research having the general description of {open_quotes}Clean Uses of Fossil Fuels{close_quotes}. The value of the grant was $500,000 for three years duration, beginning September 30, 1991 and ending September 29, 1994. Ten PhD students were selected for support during the first year of the Traineeship. Upon reviewing coursework and research progress of the students at the end of the first year, the KY DOE/EPSCoR Subcommittee awarded a second year of support at the same $25,000/year funding level. A total of 12 students will have been supported during the duration of the grant as a consequence of one student completing his degree during the support period and of one student deciding that she wanted to complete only a Masters rather than a PhD degree. The students supported were at either the University of Kentucky or the University of Louisville - the two PhD, science and engineering granting universities within the Commonwealth of Kentucky. The disciplines of these students included Biology, Chemical Engineering, Chemistry, Geological Sciences, and Physics. The methods used for the initial statewide solicitation for student support, the annual review of the students progress for support renewal, and a summary of progress and impact of the awards after two years are presented. It is shown that the Traineeships presented opportunities to: perform high quality research; initiate interactions between different scientific disciplines and departments; develop collaborations at national DOE laboratories, universities outside of Kentucky and industries; and establish research ideas for submittal to funding agencies.

  18. Spatially- explicit Fossil Fuel Carbon Dioxide Inventories for Transportation in the U.S.

    Science.gov (United States)

    Hutchins, M.; Gurney, K. R.

    2016-12-01

    The transportation sector is the second largest source of Fossil Fuel CO2 (FFCO2) emissions, and is unique in that federal, state, and municipal levels of government are all able to enact transportation policy. However, since data related to transportation activities are reported by multiple different government agencies, the data are not always consistent. As a result, the methods and data used to inventory and account for transportation related FFCO2 emissions have important implications for both science and policy. Aggregate estimates of transportation related FFCO2 emissions can be spatially distributed using traffic data, such as the Highway Performance Monitoring System (HPMS) Average Annual Daily Traffic (AADT). There are currently two datasets that estimate the spatial distribution of transportation related FFCO2 in the United States- Vulcan 3.0 and the Database of Road Transportation Emissions (DARTE). Both datasets are at 1 km resolution, for the year 2011, and utilize HPMS AADT traffic data. However, Vulcan 3.0 and DARTE spatially distribute emissions using different methods and inputs, resulting in a number of differences. Vulcan 3.0 and DARTE estimate national transportation related FFCO2 emissions within 2.5% of each other, with more significant differences at the county and state level. The differences are most notable in urban versus rural regions, and for specific road classes. The origin of these differences are explored in depth to understand the implication of using specific data sources, such as the National Emissions Inventory and other aggregate transportation statistics from the Federal Highway Administration (FHWA). In addition to comparing Vulcan 3.0 and DARTE to each other, the results from both data sets are compared to independent traffic volume measurements acquired from the FHWA Continuous Count Station (CCS) network. The CCS records hourly traffic counts at fixed locations in space throughout the U.S. We calculate transportation

  19. Resource Usage Strategies and Trade-Offs between Cropland Demand, Fossil Fuel Consumption, and Greenhouse Gas Emissions—Building Insulation as an Example

    OpenAIRE

    Anja Hansen; Jörn Budde; Annette Prochnow

    2016-01-01

    Bioresources are used in different production systems as materials as well as energy carriers. The same is true for fossil fuel resources. This study explored whether preferential resource usages exist, using a building insulation system as an example, with regard to the following sustainability criteria: climate impact, land, and fossil fuel demand. We considered the complete life cycle in a life cycle assessment-based approach. The criteria were compared for two strategies: one used natural...

  20. Solubility of multi-component biodiesel fuel systems.

    Science.gov (United States)

    Makareviciene, Violeta; Sendzikiene, Egle; Janulis, Prutenis

    2005-03-01

    Solubility of biodiesel fuel components in fossil diesel fuel-methanol-rapeseed oil methyl ester, fossil diesel fuel-ethanol-rapeseed oil methyl ester and fossil diesel fuel-ethanol-rapeseed oil ethyl ester systems was investigated. The solubility of components in the fossil diesel fuel-ethanol-rapeseed oil methyl ester system at 20 degrees C was substantially higher than in the fossil diesel fuel-methanol-rapeseed oil methyl ester system. The solubility of components in the fossil diesel fuel-ethanol-rapeseed oil ethyl ester system was slightly lower than in the fossil diesel fuel-ethanol-rapeseed oil methyl ester mixture. The moisture content of ethanol had a great influence on mixture solubility. With decrease of temperature, the solubility of components in the fossil diesel fuel-ethanol-rapeseed oil methyl ester system decreased.

  1. The energy demand and the impact by fossil fuels use in the Mexico City Metropolitan Area, from 1988 to 2000

    Energy Technology Data Exchange (ETDEWEB)

    Nava, M. [Instituto Mexicano del Petroleo, Eje Central Norte 152. Del. Gustavo A. Madero, CP 07730 Mexico, D.F. (Mexico)]. E-mail: manava@imp.mx; Gasca, J. [Instituto Mexicano del Petroleo, Eje Central Norte 152. Del. Gustavo A. Madero, CP 07730 Mexico, D.F. (Mexico); Gonzalez, U. [Instituto Mexicano del Petroleo, Eje Central Norte 152. Del. Gustavo A. Madero, CP 07730 Mexico, D.F. (Mexico)

    2006-12-15

    Temporary variation for the demand of refining products which are used in the Mexico City Metropolitan Area (MCMA) is presented. Its consequent energy contribution is evaluated from 1988 to 2000. The annual estimation was integrated from a detailed inventory of fuels volume, so as the calculus of its respective energy equivalence. The fuel quality specifications, which have been required by regional Air Quality authority for controlling emissions to the atmosphere, are also presented for the same period. The evolution demand of fuels, in term of volume, quality and its energy contribution for this area, is compared with the national demand. On this regard, fuel pool differs in each bound and the demand along the same period has been increasing on both regions but at different rates, with 21% at MCMA and 31% countrywide. In 2000, the MCMA demanded 14% of the internal refining products volume sales, which represented 17% of the energy contribution to the country for those fuels. Likewise, the energy use coefficient (GJ per capita) was applied to compare this region with country trends. During 1996 and up to 2000, the MCMA presented slightly minor energy use per capita, than the rest of the country, and this period was distinguished also for using cleaner fuels and for obtaining improvements in air quality. On the other hand, MCMA and country greenhouse gases emissions will increase because of their fossil fuel dependence, so several mitigation measures must be implemented in the next decades.

  2. Co-firing experiences of biomass with fossil fuel in the world's largest biofuel power boiler

    Energy Technology Data Exchange (ETDEWEB)

    Nickull, S.; Petaenen, P. [Oy Alholmens Kraft AB (Finland)

    2007-07-01

    The major objective of Alhomens Kraft power plant that started up in early 2002 in Pietarsaari, Finland was to demonstrate a novel technology for multifuel and low emission cogeneration at a new commercial size, and co-firing of biomass with fossil fuel. Plant design was based on maximum exploitation of wood based fuels and peat with bituminous coal. Other objectives included electricity production at a competitive price for sale in the open market, utilization of the process steam and heat in the paper mill and for the city of Pietarsaari, and maximum use of combustible by-products from the paper industry. The utility side required higher steam data and the industrial side required better load flexibility. The boiler design requirements combine both features. The biofuel handling systemposed challenges due to the large plant and the diversity of fuels. The ratio of fuels to be used is varying according to availability, quality and price. The boiler capacity is 550 MWth. The high-pressure and re-heater steam values are 194/179 kg/s at 545/545{sup o}C and 165/40 bar. The large fuel flow and fuel variation make even mixing of the fuel components essential in order to secure optimal combustion, which ensures the lowest emissions for the circulating fluidized bed process. The paper compares operating experiences to objectives of the planning and design phase related to fuel logistics up to boiler plant operation. It describes the experience of using different fuel components in different operational situations. Experiences of auxiliary systems needed for reliable operation in co-combustion as well as experience of the boiler controllability with this heterogeneous fuel combination are described. 7 figs.

  3. Characteristics of particulate emissions from a diesel generator fueled with varying blends of biodiesel and fossil diesel.

    Science.gov (United States)

    Tsai, Jen-Hsiung; Chen, Shui-Jen; Huang, Kuo-Lin; Lee, Wen-Jhy; Kuo, Wen-Chien; Lin, Wen-Yinn

    2011-01-01

    This study investigated the particulate matter (PM), particle-bound carbons, and polycyclic aromatic hydrocarbons (PAHs) emitted from a diesel-engine generator fuelled with blends of pure fossil diesel oil (D100) and varying percentages of waste-edible-oil biodiesel (W10, 10 vol %; W20, 20 vol %; W30, 30 vol %; and W50, 50 vol %) under generator loads of 0, 1.5, and 3 kW. On average, the PM emission factors of all blends was 30.5 % (range, 13.7-52.3 %) lower than that of D100 under the tested loads. Substituting pure fossil diesel oil with varying percentages of waste-edible-oil biodiesel reduced emissions of particle-bound total carbon (TC) and elemental carbon (EC). The W20 blend had the lowest particle-bound organic carbon (OC) emissions. Notably, W10, W20, and W30 also had lower Total-PAH emissions and lower total equivalent toxicity (Total-BaP(eq)) compared to D100. Additionally, the brake-specific fuel consumption of the generator correlated positively with the ratio of waste-edible-oil biodiesel to pure fossil diesel. However, generator energy efficiency correlated negatively with the ratio of waste-edible-oil biodiesel to pure fossil diesel.

  4. Surrogate gas proxy prediction model for Delta 14C-based measurements of fossil fuel-CO2

    Science.gov (United States)

    Coakley, K. J.; Miller, J. B.; Montzka, S. A.; Sweeney, C.; Miller, B.

    2016-12-01

    The measured {}14}C {:12} {C isotopic ratio ofatmospheric CO2 (and its associated derived Δ 14Cvalue) is an ideal tracer for determination of the fossil fuelderived CO2 enhancement contributing to any atmosphericCO2 measurement (Cff). Given enough such measurements,independent top-down estimation of US fossil fuel- CO2emissions should be possible. However, the number of Δ 14Cmeasurements is presently constrained by cost, available samplevolume, and availability of mass spectrometer measurement facilities.Δ 14C is therefore measured in just a small fraction ofsamples obtained by flask air sampling networks around the world.Here, we develop a Projection Pursuit Regression model topredict Cff as a function of multiple surrogate gases acquiredwithin the NOAA/ESRL Global Greenhouse Gas Reference Network (GGGRN).The surrogates consist of measured enhancements of various anthropogenictrace gases, including CO, SF6, and halo- andhydro-carbons acquired in vertical airborne sampling profiles nearCape May, NJ and Portsmouth, NH from 2005 through 2010. Modelperformance is quantified based on predicted values correspondingto test data excluded from the model building process. Chi-squarehypothesis test analysis indicates that these predictions andcorresponding observations are consistent given our uncertaintybudget which accounts for random effects and one particular systematiceffect. To account for the possibility of additional systematiceffects, we incorporate another component of uncertainty into ourbudget. Provided that these estimates are of comparable qualityto Δ 14C -based estimates, we expect an improved determinationof fossil fuel-CO2 emissions.

  5. Partial replacement of fossil fuel in a cement plant: risk assessment for the population living in the neighborhood.

    Science.gov (United States)

    Rovira, Joaquim; Mari, Montse; Nadal, Martí; Schuhmacher, Marta; Domingo, José L

    2010-10-15

    In cement plants, the substitution of traditional fossil fuels not only allows a reduction of CO(2), but it also means to check-out residual materials, such as sewage sludge or municipal solid wastes (MSW), which should otherwise be disposed somehow/somewhere. In recent months, a cement plant placed in Alcanar (Catalonia, Spain) has been conducting tests to replace fossil fuel by refuse-derived fuel (RDF) from MSW. In July 2009, an operational test was progressively initiated by reaching a maximum of partial substitution of 20% of the required energy. In order to study the influence of the new process, environmental monitoring surveys were performed before and after the RDF implementation. Metals and polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) were analyzed in soil, herbage, and air samples collected around the facility. In soils, significant decreases of PCDD/F levels, as well as in some metal concentrations were found, while no significant increases in the concentrations of these pollutants were observed. In turn, PM(10) levels remained constant, with a value of 16μgm(-3). In both surveys, the carcinogenic and non-carcinogenic risks derived from exposure to metals and PCDD/Fs for the population living in the vicinity of the facility were within the ranges considered as acceptable according to national and international standards. This means that RDF may be a successful choice in front of classical fossil fuels, being in accordance with the new EU environmental policies, which entail the reduction of CO(2) emissions and the energetic valorization of MSW. However, further long-term environmental studies are necessary to corroborate the harmlessness of RDF, in terms of human health risks. Copyright © 2010 Elsevier B.V. All rights reserved.

  6. Temperature Stratification in a Cryogenic Fuel Tank

    Science.gov (United States)

    Daigle, Matthew John; Smelyanskiy, Vadim; Boschee, Jacob; Foygel, Michael Gregory

    2013-01-01

    A reduced dynamical model describing temperature stratification effects driven by natural convection in a liquid hydrogen cryogenic fuel tank has been developed. It accounts for cryogenic propellant loading, storage, and unloading in the conditions of normal, increased, and micro- gravity. The model involves multiple horizontal control volumes in both liquid and ullage spaces. Temperature and velocity boundary layers at the tank walls are taken into account by using correlation relations. Heat exchange involving the tank wall is considered by means of the lumped-parameter method. By employing basic conservation laws, the model takes into consideration the major multi-phase mass and energy exchange processes involved, such as condensation-evaporation of the hydrogen, as well as flows of hydrogen liquid and vapor in the presence of pressurizing helium gas. The model involves a liquid hydrogen feed line and a tank ullage vent valve for pressure control. The temperature stratification effects are investigated, including in the presence of vent valve oscillations. A simulation of temperature stratification effects in a generic cryogenic tank has been implemented in Matlab and results are presented for various tank conditions.

  7. Temperature feedback of TRIGA MARK-II fuel

    Energy Technology Data Exchange (ETDEWEB)

    Usang, M. D., E-mail: mark-dennis@nuclearmalaysia.gov.my; Minhat, M. S.; Rabir, M. H.; Rawi, M. Z. M. [Malaysia Nuclear Agency, Bangi, 43000 Kajang, Selangor (Malaysia)

    2016-01-22

    We study the amount of temperature feedback on reactivity for the three types of TRIGA fuel i.. ST8, ST12 and LEU fuel, are used in the TRIGA MARK II reactor in Malaysia Nuclear Agency. We employ WIMSD-5B for the calculation of kin f for a single TRIGA fuel surrounded by water. Typical calculations of TRIGA fuel reactivity are usually limited to ST8 fuel, but in this paper our investigation extends to ST12 and LEU fuel. We look at the kin f of our model at various fuel temperatures and calculate the amount reactivity removed. In one instance, the water temperature is kept at room temperature of 300K to simulate sudden reactivity increase from startup. In another instance, we simulate the sudden temperature increase during normal operation where the water temperature is approximately 320K while observing the kin f at various fuel temperatures. For accidents, two cases are simulated. The first case is for water temperature at 370K and the other is without any water. We observe that the higher Uranium content fuel such as the ST12 and LEU have much smaller contribution to the reactivity in comparison to the often studied ST8 fuel. In fact the negative reactivity coefficient for LEU fuel at high temperature in water is only slightly larger to the negative reactivity coefficient for ST8 fuel in void. The performance of ST8 fuel in terms of negative reactivity coefficient is cut almost by half when it is in void. These results are essential in the safety evaluation of the reactor and should be carefully considered when choices of fuel for core reconfiguration are made.

  8. Temperature feedback of TRIGA MARK-II fuel

    Science.gov (United States)

    Usang, M. D.; Minhat, M. S.; Rabir, M. H.; M. Rawi M., Z.

    2016-01-01

    We study the amount of temperature feedback on reactivity for the three types of TRIGA fuel i.. ST8, ST12 and LEU fuel, are used in the TRIGA MARK II reactor in Malaysia Nuclear Agency. We employ WIMSD-5B for the calculation of kin f for a single TRIGA fuel surrounded by water. Typical calculations of TRIGA fuel reactivity are usually limited to ST8 fuel, but in this paper our investigation extends to ST12 and LEU fuel. We look at the kin f of our model at various fuel temperatures and calculate the amount reactivity removed. In one instance, the water temperature is kept at room temperature of 300K to simulate sudden reactivity increase from startup. In another instance, we simulate the sudden temperature increase during normal operation where the water temperature is approximately 320K while observing the kin f at various fuel temperatures. For accidents, two cases are simulated. The first case is for water temperature at 370K and the other is without any water. We observe that the higher Uranium content fuel such as the ST12 and LEU have much smaller contribution to the reactivity in comparison to the often studied ST8 fuel. In fact the negative reactivity coefficient for LEU fuel at high temperature in water is only slightly larger to the negative reactivity coefficient for ST8 fuel in void. The performance of ST8 fuel in terms of negative reactivity coefficient is cut almost by half when it is in void. These results are essential in the safety evaluation of the reactor and should be carefully considered when choices of fuel for core reconfiguration are made.

  9. The Fossil Fueled Metropolis: Los Angeles and the Emergence of Oil-Based Energy in North America, 1865--1930

    Science.gov (United States)

    Cooke, Jason Arthur

    Beginning with coal in the nineteenth century, the mass production and intensive consumption of fossil fuel energy fundamentally changed patterns of urban and industrial development in North America. Focusing on the metropolitan development of Los Angeles, this dissertation examines how the emergence of oil-based capitalism in the first three decades of the twentieth century was sustained and made increasingly resilient through the production of urban and industrial space. In a region where coal was scarce, the development of oil-based energy was predicated on long-term investments into conversion technologies, storage systems and distribution networks that facilitated the efficient and economical flow of liquefied fossil fuel. In this dissertation, I argue that the historical and geographical significance of the Southern California petroleum industry is derived from how its distinctive market expansion in the first three decades of the twentieth century helped establish the dominance of oil-based energy as the primary fuel for transportation in capitalist society. In North America, the origins of oil-based capitalism can be traced to the turn of the twentieth century when California was the largest oil-producing economy in the United States and Los Angeles was the fastest growing metropolitan region. This dissertation traces how Los Angeles became the first city in North America where oil became a formative element of urban and industrial development: not only as fuel for transportation, but also in the infrastructures, landscapes and networks that sustain a critical dependence on oil-based energy. With a distinctive metropolitan geography, decentralized and automobile-dependent, Los Angeles became the first oil-based city in North America and thus provides an ideal case study for examining the regional dynamics of energy transition, establishment and dependence. Interwoven with the production of urban and industrial space, oil remains the primary fuel that

  10. Pollution from Fossil-Fuel Combustion is the Leading Environmental Threat to Global Pediatric Health and Equity: Solutions Exist.

    Science.gov (United States)

    Perera, Frederica

    2017-12-23

    Fossil-fuel combustion by-products are the world's most significant threat to children's health and future and are major contributors to global inequality and environmental injustice. The emissions include a myriad of toxic air pollutants and carbon dioxide (CO₂), which is the most important human-produced climate-altering greenhouse gas. Synergies between air pollution and climate change can magnify the harm to children. Impacts include impairment of cognitive and behavioral development, respiratory illness, and other chronic diseases-all of which may be "seeded" in utero and affect health and functioning immediately and over the life course. By impairing children's health, ability to learn, and potential to contribute to society, pollution and climate change cause children to become less resilient and the communities they live in to become less equitable. The developing fetus and young child are disproportionately affected by these exposures because of their immature defense mechanisms and rapid development, especially those in low- and middle-income countries where poverty and lack of resources compound the effects. No country is spared, however: even high-income countries, especially low-income communities and communities of color within them, are experiencing impacts of fossil fuel-related pollution, climate change and resultant widening inequality and environmental injustice. Global pediatric health is at a tipping point, with catastrophic consequences in the absence of bold action. Fortunately, technologies and interventions are at hand to reduce and prevent pollution and climate change, with large economic benefits documented or predicted. All cultures and communities share a concern for the health and well-being of present and future children: this shared value provides a politically powerful lever for action. The purpose of this commentary is to briefly review the data on the health impacts of fossil-fuel pollution, highlighting the neurodevelopmental

  11. Inverse modeling of fossil fuel CO2 emissions at urban scale using OCO-2 retrievals of total column CO2

    Science.gov (United States)

    Ye, X.; Lauvaux, T.; Kort, E. A.; Lin, J. C.; Oda, T.; Yang, E.; Wu, D.

    2016-12-01

    Rapid economic development has given rise to a steady increase of global carbon emissions, which have accumulated in the atmosphere for the past 200 years. Urbanization has concentrated about 70% of the global fossil-fuel CO2 emissions in large metropolitan areas distributed around the world, which represents the most significant anthropogenic contribution to climate change. However, highly uncertain quantifications of urban CO2 emissions are commonplace for numerous cities because of poorly-documented inventories of energy consumption. Therefore, accurate estimates of carbon emissions from global observing systems are a necessity if mitigation strategies are meant to be implemented at global scales. Space-based observations of total column averaged CO2 concentration (XCO2) provide a very promising and powerful tool to quantify urban CO2 fluxes. For the first time, measurements from the Orbiting Carbon Observatory 2 (OCO-2) mission are assimilated in a high resolution inverse modeling system to quantify fossil-fuel CO2 emissions of multiple cities around the globe. The Open-source Data Inventory for Anthropogenic CO2 (ODIAC) emission inventory is employed as a first guess, while the atmospheric transport is simulated using the WRF-Chem model at 1-km resolution. Emission detection and quantification is performed with an Ensemble Kalman Filter method. We demonstrate here the potential of the inverse approach for assimilating thousands of OCO-2 retrievals along tracks near metropolitan areas. We present the detection potential of the system with real-case applications near power plants and present inverse emissions using actual OCO-2 measurements on various urban landscapes. Finally, we will discuss the potential of OCO-2-like satellite instruments for monitoring temporal variations of fossil-fuel CO2 emissions over multiple years, which can provide valuable insights for future satellite observation strategies.

  12. Age and transit time distributions of carbon in a nonlinear global model perturbed by nonautonomous fossil-fuel emissions signals

    Science.gov (United States)

    Metzler, Holger; Müller, Markus; Sierra, Carlos A.

    2017-04-01

    Carbon fluxes in the ocean-atmosphere-biosphere system are governed by nonlinear processes, which are usually modeled by a system of ordinary differential equations. It is very difficult to analyze such nonlinear models and to predict their future behavior, particularly their internal age structure: How old is the carbon in different pools (ages) and how old is the carbon that leaves the system (transit times)? How is this age structure modified by the addition of fossil fuel emissions? To answer these questions, we developed a new mathematical approach that allows us to compute and visualize the age structure of models of well mixed pools even if they are nonlinear and nonautonomous. We do not only consider mean ages and mean transit times, but entire distributions. Consequently, we can consider important statistics such as the median, quantiles, or the variance. We applied this mathematical approach to a nonlinear global carbon model consisting of three pools (atmosphere, surface ocean, and terrestrial biosphere) and driven by four emission scenarios (RCP3-PD, RCP4.5, RCP6, RCP8.5). Results showed that the addition of fossil fuels modifies the age structure of C in the atmosphere by drastically increasing its proportion of young carbon. We found little differences among predicted mean ages for the four emission scenarios, but changes in the overall distributions were large with effects on median, quantiles and variance. In the short-term, fossil-fuel emissions have an important effect on the amount of carbon that is exchanged among Earth's main C reservoirs. In the long-term, most added C will eventually end up in the deep ocean, but the time required to return to pre-industrial C age distributions is largely dependent on emission scenarios.

  13. Evaluation of long range transport of fossil fuel originated organic aerosol at a background site in Northeast Asia

    Science.gov (United States)

    Hwang, Eun Jin; Lee, Ji Yi; Park, Jin Soo; Lee, Seok Jo; Kim, Hyun Jae; Jeon, Ha Eun; Sung, Min Young

    2013-04-01

    Northeast Asia is heavy air pollution region due to usage of large amounts of fossil fuel. In addition, meteorological conditions represented as prevailing westerlies in Northeast Asia region causes long range transport of anthropogenic pollutants emitted from China to Korea and Japan and even the United States across the Pacific Ocean (Bey et al., 2001). The Baengnyeong Island of Korea is located at the northwestern part of the Korean peninsula and close by North Korea and China, thus this site is regarded as an ideal place for background air measurements in Northeast Asia. Also, it has low local anthropogenic emissions and is frequently influenced by various air masses from China and North Korea in the Island. In this study, we performed intensive sampling during summer and winter in the Baengnyeong Island and analyzed various organic compounds including fossil fuel originated organic markers such as hopanes and PAHs using thermal desorption two dimensional gas chromatography with time of flight mass spectrometry (TD-GC×GC-TOFMS). We also analyzed ~20 urban aerosol samples collected at Seoul, a representative urban site in Northeast Asia region to compare organic compounds distributions of aerosol samples at the Baengnyeong Island. By applying air mass back trajectory analysis and comparing organic compounds distributions in aerosol samples of the Baengnyeong Island and Seoul, the impact of long-range transport of fossil fuel originated organic pollutants at a background site in Northeast Asia were evaluated. (References) Bey, I., Jacob, D.J., Logan, J.A., Yantosca, R.M., 2001. Asian chemical outflow to the Pacific in spring: origins, pathways, and budgets. Journal of Geophysical Research-Atmosphere 106, 23097-23113.

  14. Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

    2014-03-14

    Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known ‘signal-to-noise’ problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

  15. Continental-scale enrichment of atmospheric 14CO2 from the nuclear power industry: potential impact on the estimation of fossil fuel-derived CO2

    Directory of Open Access Journals (Sweden)

    N. Gruber

    2011-12-01

    Full Text Available The 14C-free fossil carbon added to atmospheric CO2 by combustion dilutes the atmospheric 14C/C ratio (Δ14C, potentially providing a means to verify fossil CO2 emissions calculated using economic inventories. However, sources of 14C from nuclear power generation and spent fuel reprocessing can counteract this dilution and may bias 14C/C-based estimates of fossil fuel-derived CO2 if these nuclear influences are not correctly accounted for. Previous studies have examined nuclear influences on local scales, but the potential for continental-scale influences on Δ14C has not yet been explored. We estimate annual 14C emissions from each nuclear site in the world and conduct an Eulerian transport modeling study to investigate the continental-scale, steady-state gradients of Δ14C caused by nuclear activities and fossil fuel combustion. Over large regions of Europe, North America and East Asia, nuclear enrichment may offset at least 20% of the fossil fuel dilution in Δ14C, corresponding to potential biases of more than −0.25 ppm in the CO2 attributed to fossil fuel emissions, larger than the bias from plant and soil respiration in some areas. Model grid cells including high 14C-release reactors or fuel reprocessing sites showed much larger nuclear enrichment, despite the coarse model resolution of 1.8°×1.8°. The recent growth of nuclear 14C emissions increased the potential nuclear bias over 1985–2005, suggesting that changing nuclear activities may complicate the use of Δ14C observations to identify trends in fossil fuel emissions. The magnitude of the potential nuclear bias is largely independent of the choice of reference station in the context of continental-scale Eulerian transport and inversion studies, but could potentially be reduced by an appropriate choice of reference station in the context of local-scale assessments.

  16. Proceedings of the US Department of Energy environmental control symposium. Volume 1. Plenary session and fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    None

    1979-09-01

    Volume one of the proceedings (Plenary Session and Fossil Fuels) contains papers on environmental pollution control which resulted mainly from US DOE's research programs in coal (preparation, desulfurization, gasification, liquefaction, combustion, fluidized-bed combustion, and pollution control methods with respect to SO/sub 2/, NO/sub x/, and CO/sub 2/ (global effects and feasibility studies); a few papers deal with oil shale operations and the enhanced recovery of petroleum. Papers have been entered individually into EDB and ERA, with 3 also into EAPA; six papers had been entered previously from other sources. (LTN)

  17. Toward verifying fossil fuel CO2 emissions with the CMAQ model: motivation, model description and initial simulation.

    Science.gov (United States)

    Liu, Zhen; Bambha, Ray P; Pinto, Joseph P; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A

    2014-04-01

    Motivated by the question of whether and how a state-of-the-art regional chemical transport model (CTM) can facilitate characterization of CO2 spatiotemporal variability and verify CO2 fossil-fuel emissions, we for the first time applied the Community Multiscale Air Quality (CMAQ) model to simulate CO2. This paper presents methods, input data, and initial results for CO2 simulation using CMAQ over the contiguous United States in October 2007. Modeling experiments have been performed to understand the roles of fossil-fuel emissions, biosphere-atmosphere exchange, and meteorology in regulating the spatial distribution of CO2 near the surface over the contiguous United States. Three sets of net ecosystem exchange (NEE) fluxes were used as input to assess the impact of uncertainty of NEE on CO2 concentrations simulated by CMAQ. Observational data from six tall tower sites across the country were used to evaluate model performance. In particular, at the Boulder Atmospheric Observatory (BAO), a tall tower site that receives urban emissions from Denver CO, the CMAQ model using hourly varying, high-resolution CO2 fossil-fuel emissions from the Vulcan inventory and Carbon Tracker optimized NEE reproduced the observed diurnal profile of CO2 reasonably well but with a low bias in the early morning. The spatial distribution of CO2 was found to correlate with NO(x), SO2, and CO, because of their similar fossil-fuel emission sources and common transport processes. These initial results from CMAQ demonstrate the potential of using a regional CTM to help interpret CO2 observations and understand CO2 variability in space and time. The ability to simulate a full suite of air pollutants in CMAQ will also facilitate investigations of their use as tracers for CO2 source attribution. This work serves as a proof of concept and the foundation for more comprehensive examinations of CO2 spatiotemporal variability and various uncertainties in the future. Atmospheric CO2 has long been modeled

  18. Use of Chia Plant to Monitor Urban Fossil Fuel CO2 Emission: An Example From Irvine, CA in 2010

    Science.gov (United States)

    Xu, X.; Stills, A.; Trumbore, S.; Randerson, J. T.; Yi, J.

    2011-12-01

    Δ14CO2 is a unique tracer for quantifying anthropogenic CO2 emissions. However, monitoring 14CO2 change and distribution in an urban environment is challenging because of its large spatial and temporal variations. We have tested the potential use of a chia plant (Salvia hispanica) as an alternative way to collect a time-integrated CO2 sample for radiocarbon analysis. The results show that Δ14C of the new growth of chia sprouts and chia leaves are consistent with the Δ14C of air samples collected during the growing period, indicating the new growth has no inherited C from seeds and thus records atmospheric 14CO2. Time-integrated air samples and chia leaf samples significantly reduced the noises of Δ14CO2 in an urban environment. We report here an example of monitoring 14CO2 change in Irvine, CA from Mar 2010 to Mar 2011 utilizing such a method. The results showed a clear seasonal cycle with high (close to remote air background level) Δ14C in summer and low Δ14C in winter months in this urban area. Excess (above remote air background) fossil fuel CO2 was calculated to be closed to 0 ppm in June to about 16 ppm from November 2010 to February 2011. Monthly mean Δ14CO2 was anti-correlated with monthly mean CO mixing ratio, indicating Δ14CO2 is mainly controlled by fossil fuel CO2 mixing with clean on-shore marine air. In summary, this study has shown encouraging result that chia plant can be potentially used as a convenient and inexpensive sampling method for time-integrated atmospheric 14CO2. Combined with other annual plants this provides the opportunity to map out time-integrated fossil fuel-derived CO2 in major cities at low cost. This in turn can be used to: 1) establish a baseline for fossil fuel emissions reductions in cities in the future; 2) provide invaluable information for validating emission models.

  19. Competition between the various fossil-fuel energy resources on the European and World markets in the year 2000

    Energy Technology Data Exchange (ETDEWEB)

    Brunner, G.

    1980-05-01

    This paper looks at probable developments between now and the year 2000 in the role played by each of the major primary energy sources : Oil (still occupies a dominant position but is partially on the decline); natural gas (uncertainty over cost prices); coal (substantial developments in international trade due in the main to the increase in European requirements); and nuclear energy (competition with coal over electricity generation). Also looks at other fossil fuels - where production is limited on the grounds of cost and environmental problems. (In French)

  20. Unconventional fossil-based fuels : economic and environmental trade-offs

    Science.gov (United States)

    2008-01-01

    Both high import payments for petroleum motor fuels and concerns regarding emissions of carbon dioxide (CO2) are motivating interest in possible fuel substitutes. In this report, RAND researchers assess the potential future production levels, product...

  1. Microscale In Vitro Assays for the Investigation of Neutral Red Retention and Ethoxyresorufin-O-Deethylase of Biofuels and Fossil Fuels

    DEFF Research Database (Denmark)

    Heger, Sebastian; Bluhm, Kerstin; Brendt, Julia

    2016-01-01

    Only few information on the potential toxic effectiveness of biofuels are available. Due to increasing worldwide demand for energy and fuels during the past decades, biofuels are considered as a promising alternative for fossil fuels in the transport sector. Hence, more information on their hazard......, ecotoxicological methods are applied to gain information on potential adverse environmental effects of biofuels at an early phase of their development. In the present study, three potential biofuels, ethyl levulinate, 2-methyltetrahydrofuran and 2-methylfuran were tested. Furthermore, we investigated a fossil...... gasoline fuel, a fossil diesel fuel and an established biodiesel. Two in vitro bioassays, one for assessing cytotoxicity and one for aryl hydrocarbon receptor agonism, so called dioxin-like activity, as measured by Ethoxyresorufin-O-Deethylase, were applied using the permanent fish liver cell line RTL-W1...

  2. Measurement and correlation of jet fuel viscosities at low temperatures

    Science.gov (United States)

    Schruben, D. L.

    1985-01-01

    Apparatus and procedures were developed to measure jet fuel viscosity for eight current and future jet fuels at temperatures from ambient to near -60 C by shear viscometry. Viscosity data showed good reproducibility even at temperatures a few degrees below the measured freezing point. The viscosity-temperature relationship could be correlated by two linear segments when plotted as a standard log-log type representation (ASTM D 341). At high temperatures, the viscosity-temperature slope is low. At low temperatures, where wax precipitation is significant, the slope is higher. The breakpoint between temperature regions is the filter flow temperature, a fuel characteristic approximated by the freezing point. A generalization of the representation for the eight experimental fuels provided a predictive correlation for low-temperature viscosity, considered sufficiently accurate for many design or performance calculations.

  3. Melting temperature of uranium - plutonium mixed oxide fuel

    Energy Technology Data Exchange (ETDEWEB)

    Ishii, Tetsuya; Hirosawa, Takashi [Power Reactor and Nuclear Fuel Development Corp., Oarai, Ibaraki (Japan). Oarai Engineering Center

    1997-08-01

    Fuel melting temperature is one of the major thermodynamical properties that is used for determining the design criteria on fuel temperature during irradiation in FBR. In general, it is necessary to evaluate the correlation of fuel melting temperature to confirm that the fuel temperature must be kept below the fuel melting temperature during irradiation at any conditions. The correlations of the melting temperature of uranium-plutonium mixed oxide (MOX) fuel, typical FBR fuel, used to be estimated and formulized based on the measured values reported in 1960`s and has been applied to the design. At present, some experiments have been accumulated with improved experimental techniques. And it reveals that the recent measured melting temperatures does not agree well to the data reported in 1960`s and that some of the 1960`s data should be modified by taking into account of the recent measurements. In this study, the experience of melting temperature up to now are summarized and evaluated in order to make the fuel pin design more reliable. The effect of plutonium content, oxygen to metal ratio and burnup on MOX fuel melting was examined based on the recent data under the UO{sub 2} - PuO{sub 2} - PuO{sub 1.61} ideal solution model, and then formulized. (J.P.N.)

  4. Resource Usage Strategies and Trade-Offs between Cropland Demand, Fossil Fuel Consumption, and Greenhouse Gas Emissions—Building Insulation as an Example

    Directory of Open Access Journals (Sweden)

    Anja Hansen

    2016-06-01

    Full Text Available Bioresources are used in different production systems as materials as well as energy carriers. The same is true for fossil fuel resources. This study explored whether preferential resource usages exist, using a building insulation system as an example, with regard to the following sustainability criteria: climate impact, land, and fossil fuel demand. We considered the complete life cycle in a life cycle assessment-based approach. The criteria were compared for two strategies: one used natural fibers as material and generated production energies from fossil fuels; the other generated production energies from bioenergy carriers and transformed fossil resources into the insulation material. Both strategies finally yielded the same insulation effect. Hence, the energy demand for heating the building was ignored. None of the strategies operated best in all three criteria: While cropland demand was lower in the bioenergy than in the biomaterial system, its fossil fuel demand was higher. Net contribution to climate change was in the same range for both strategies if we considered no indirect changes in land use. Provided that effective recycling concepts for fossil-derived insulations are in place, using bioresources for energy generation was identified as a promising way to mitigate climate change along with efficient resource use.

  5. High Temperature PEM Fuel Cell Systems, Control and Diagnostics

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen; Justesen, Kristian Kjær

    2015-01-01

    Various system topologies are available when it comes to designing high temperature PEM fuel cell systems. Very simple system designs are possible using pure hydrogen, and more complex system designs present themselves when alternative fuels are desired, using reformer systems. The use of reformed...... fuels utilizes one of the main advantages of the high temperature PEM fuel cell: robustness to fuel quality and impurities. In order for such systems to provide efficient, robust, and reliable energy, proper control strategies are needed. The complexity and nonlinearity of many of the components...

  6. Hybrid Organic - Inorganic Polymer Electrolyte Membranes for Low to Medium Temperature Fuel Cells

    NARCIS (Netherlands)

    Cordova Chavez, M.E.

    2017-01-01

    Crude oil, coal and gas are currently the main resources of energy in the world. The World Energy Outlook claimed in 2007 that the major source of energy (about 84%) would still be generated from fossil fuels in 2030. By these projections, the world's fossil fuel reserves will be consumed within a

  7. Innovative High Temperature Fuel Cell systems

    OpenAIRE

    Au, Siu Fai

    2003-01-01

    The world's energy consumption is growing extremely rapidly. Fuel cell systems are of interest by researchers and industry as the more efficient alternative to conventional thermal systems for power generation. The principle of fuel cell conversion does not involve thermal combustion and hence in theory fuel cell systems can be far more efficient than thermal power systems. This advantage is only partly utilized in present fuel cell pilot plants and additional optimization is needed. The comp...

  8. Design, quality, and quality assurance of solid recovered fuels for the substitution of fossil feedstock in the cement industry.

    Science.gov (United States)

    Sarc, R; Lorber, K E; Pomberger, R; Rogetzer, M; Sipple, E M

    2014-07-01

    This paper describes the requirements for the production, quality, and quality assurance of solid recovered fuels (SRF) that are increasingly used in the cement industry. Different aspects have to be considered before using SRF as an alternative fuel. Here, a study on the quality of SRF used in the cement industry is presented. This overview is completed by an investigation of type and properties of input materials used at waste splitting and SRF production plants in Austria. As a simplified classification, SRF can be divided into two classes: a fine, high-calorific SRF for the main burner, or coarser SRF material with low calorific value for secondary firing systems, such as precombustion chambers or similar systems. In the present study, SRFs coming from various sources that fall under these two different waste fuel classes are discussed. Both SRFs are actually fired in the grey clinker kiln of the Holcim (Slovensko) plant in Rohožnik (Slovakia). The fine premium-quality material is used in the main burner and the coarse regular-quality material is fed to a FLS Hotdisc combustion device. In general, the alternative fuels are used instead of their substituted fossil fuels. For this, chemical compositions and other properties of SRF were compared to hard coal as one of the most common conventional fuels in Europe. This approach allows to compare the heavy metal input from traditional and alternative fuels and to comment on the legal requirements on SRF that, at the moment, are under development in Europe. © The Author(s) 2014.

  9. Method development for mass spectrometry based molecular characterization of fossil fuels and biological samples

    Science.gov (United States)

    Mahat, Rajendra K.

    In an analytical (chemical) method development process, the sample preparation step usually determines the throughput and overall success of the analysis. Both targeted and non-targeted methods were developed for the mass spectrometry (MS) based analyses of fossil fuels (coal) and lipidomic analyses of a unique micro-organism, Gemmata obscuriglobus. In the non-targeted coal analysis using GC-MS, a microwave-assisted pressurized sample extraction method was compared with the traditional extraction method, such as Soxhlet. On the other hand, methods were developed to establish a comprehensive lipidomic profile and to confirm the presence of endotoxins (a.k.a. lipopolysaccharides, LPS) in Gemmata.. The performance of pressurized heating techniques employing hot-air oven and microwave irradiation were compared with that of Soxhlet method in terms of percentage extraction efficiency and extracted analyte profiles (via GC-MS). Sub-bituminous (Powder River Range, Wyoming, USA) and bituminous (Fruitland formation, Colorado, USA) coal samples were tested. Overall 30-40% higher extraction efficiencies (by weight) were obtained with a 4 hour hot-air oven and a 20 min microwave-heating extraction in a pressurized container when compared to a 72 hour Soxhlet extraction. The pressurized methods are 25 times more economic in terms of solvent/sample amount used and are 216 times faster in term of time invested for the extraction process. Additionally, same sets of compounds were identified by GC-MS for all the extraction methods used: n-alkanes and diterpanes in the sub-bituminous sample, and n-alkanes and alkyl aromatic compounds in the bituminous coal sample. G. obscuriglobus, a nucleated bacterium, is a micro-organism of high significances from evolutionary, cell and environmental biology standpoints. Although lipidomics is an essential tool in microbiological systematics and chemotaxonomy, complete lipid profile of this bacterium is still lacking. In addition, the presence of

  10. Design Optimization of Liquid Fueled High Velocity Oxy- Fuel Thermal Spraying Technique for Durable Coating for Fossil Power Systems

    Energy Technology Data Exchange (ETDEWEB)

    Choudhuri, Ahsan [Univ. of Texas, El Paso, TX (United States); Love, Norman [Univ. of Texas, El Paso, TX (United States)

    2016-11-04

    High-velocity oxy–fuel (HVOF) thermal spraying was developed in 1930 and has been commercially available for twenty-five years. HVOF thermal spraying has several benefits over the more conventional plasma spray technique including a faster deposition rate which leads to quicker turn-around, with more durable coatings and higher bond strength, hardness and wear resistance due to a homogeneous distribution of the sprayed particles. HVOF thermal spraying is frequently used in engineering to deposit cermets, metallic alloys, composites and polymers, to enhance product life and performance. HVOF thermal spraying system is a highly promising technique for applying durable coatings on structural materials for corrosive and high temperature environments in advanced ultra-supercritical coal- fired (AUSC) boilers, steam turbines and gas turbines. HVOF thermal spraying is the preferred method for producing coatings with low porosity and high adhesion. HVOF thermal spray process has been shown to be one of the most efficient techniques to deposit high performance coatings at moderate cost. Variables affecting the deposit formation and coating properties include hardware characteristics such as nozzle geometry and spraying distance and process parameters such as equivalence ratio, gas flow density, and powder feedstock. In the spray process, the powder particles experience very high speeds combined with fast heating to the powder material melting point or above. This high temperature causes evaporation of the powder, dissolution, and phase transformations. Due to the complex nature of the HVOF technique, the control and optimization of the process is difficult. In general, good coating quality with suitable properties and required performance for specific applications is the goal in producing thermal spray coatings. In order to reach this goal, a deeper understanding of the spray process as a whole is needed. Although many researchers studied commercial HVOF thermal spray

  11. Characterization of solid airborne particles deposited in snow in the vicinity of urban fossil fuel thermal power plant (Western Siberia).

    Science.gov (United States)

    Talovskaya, A V; Yazikov, E G; Filimonenko, E A; Lata, J-C; Kim, J; Shakhova, T S

    2017-07-20

    Recognition and detailed characterization of solid particles emitted from thermal power plants into the environment is highly important due to their potential detrimental effects on human health. Snow cover is used for the identification of anthropogenic emissions in the environment. However, little is known about types, physical and chemical properties of solid airborne particles (SAP) deposited in snow around thermal power plants. The purpose of this study is to quantify and characterize in detail the traceable SAP deposited in snow near fossil fuel thermal power plant in order to identify its emissions into the environment. Applying the scanning electron microscopy-energy dispersive spectroscopy, and X-ray diffraction, mineral and anthropogenic phase groups in SAP deposited in snow near the plant and in fly ash were observed. We identified quartz, albite and mullite as most abundant mineral phases and carbonaceous matter, slag and spherical particles as dominate anthropogenic phases. This is the first study reporting that zircon and anthropogenic sulphide-bearing, metal oxide-bearing, intermetallic compound-bearing and rare-earth element-bearing particles were detected in snow deposits near thermal power plant. The identified mineral and anthropogenic phases can be used as tracers for fossil fuel combustion emissions, especially with regard to their possible effect on human health.

  12. Tetrazole substituted polymers for high temperature polymer electrolyte fuel cells

    DEFF Research Database (Denmark)

    Henkensmeier, Dirk; My Hanh Duong, Ngoc; Brela, Mateusz

    2015-01-01

    interesting for use in a high temperature fuel cell (HT PEMFC). Based on these findings, two polymers incorporating the proposed TZ groups were synthesised, formed into membranes, doped with PA and tested for fuel cell relevant properties. At room temperature, TZ-PEEN and commercial meta-PBI showed...

  13. INVESTIGATION OF FOSSIL FUEL AND LIQUID BIOFUEL BLEND PROPERTIES USING ARTIFICIAL NEURAL NETWORK

    OpenAIRE

    Najafi, G.; B Ghobadian; P. Nematizade

    2012-01-01

    Gasoline fuel is the baseline fuel in this research, to which bioethanol, biodiesel and diesel are additives. The fuel blends were prepared based on different volumes and following which, ASTM (American Society for Testing and Materials) test methods analysed some of the important properties of the blends, such as: density, dynamic viscosity, kinematic viscosity and water and sediment. Experimental data were analysed by means of Matlab software. The results obtained from artificial neural net...

  14. Forest biomass and tree planting for fossil fuel offsets in the Colorado Front Range

    Science.gov (United States)

    Mike A. Battaglia; Kellen Nelson; Dan Kashian; Michael G. Ryan

    2010-01-01

    This study estimates the amount of carbon available for removal in fuel reduction and reforestation treatments in montane forests of the Colorado Front Range based on site productivity, pre-treatment basal area, and planting density. Thinning dense stands will yield the greatest offsets for biomass fuel. However, this will also yield the greatest carbon losses, if the...

  15. Carbon as Investment Risk—The Influence of Fossil Fuel Divestment on Decision Making at Germany’s Main Power Providers

    Directory of Open Access Journals (Sweden)

    Dagmar Kiyar

    2015-09-01

    Full Text Available German electricity giants have recently taken high-level decisions to remove selected fossil fuel operations from their company portfolio. This new corporate strategy could be seen as a direct response to the growing global influence of the fossil fuel divestment campaign. In this paper we ask whether the divestment movement currently exerts significant influence on decision-making at the top four German energy giants—E.On, RWE, Vattenfall and EnBW. We find that this is not yet the case. After describing the trajectory of the global fossil fuel divestment campaign, we outline four alternative influences on corporate strategy that, currently, are having a greater impact than the divestment movement on Germany’s power sector. In time, however, clear political decisions and strong civil support may increase the significance of climate change concerns in the strategic management of the German electricity giants.

  16. Innovative High Temperature Fuel Cell systems

    NARCIS (Netherlands)

    De Wit, J.H.W.; Kouffeld, R.W.J.; Hemmes, K.; Au, Siu Fai

    The world's energy consumption is growing extremely rapidly. Fuel cell systems are of interest by researchers and industry as the more efficient alternative to conventional thermal systems for power generation. The principle of fuel cell conversion does not involve thermal combustion and hence in

  17. Innovative High Temperature Fuel Cell systems

    NARCIS (Netherlands)

    Au, Siu Fai

    2003-01-01

    The world's energy consumption is growing extremely rapidly. Fuel cell systems are of interest by researchers and industry as the more efficient alternative to conventional thermal systems for power generation. The principle of fuel cell conversion does not involve thermal combustion and hence in

  18. Overall intelligent hybrid control system for a fossil-fuel power unit

    Energy Technology Data Exchange (ETDEWEB)

    Garduno-Ramirez, Raul

    2000-08-01

    This research present a methodology to design a generalized overall unit control system for a fossil fuel power unit (FFPU), and develops a minimum prototype to demonstrate its feasibility. Toward the above goal, the associated research project was undertaken as a technology innovation process with its two ends identified as follows. First, it is recognized that the coordinated control strategies constitute the uppermost control level in current FFPUs, and so, are responsible for driving the boiler-turbine-generator set as a single entity. Second, a FFPU is envisioned as a complex process, subject to multiple changing operating conditions, that should perform as an intelligent system, for which an advanced integral control concept is needed. Therefore, as an outcome of the innovation process, a generalized unit control concept that extends the capabilities of current coordinated control schemes is proposed. This concept is presented as the Intelligent Coordinated Control System (ICCS) paradigm, which establishes an open reference framework for the development of overall unit control schemes. The ICCS's system goals are identified using power plant process engineering concepts, and intelligent control systems engineering concepts are used to identify main tasks and to achieve system functional decomposition. A software engineering agency concept is used to identify and group agents according to their knowledge and purpose interactions. The resultant ICCS structure is an open set of functionally grouped agent clusters in a two-level hierarchical system. The upper level, mainly characterized for knowledge-driven processes, performs the supervisory functions needed to provide self governing operation characteristics, while the lower level, mainly characterized for data-driven processes, performs the fast reactive behavior functions necessary for hybrid real-time control and protection. Developed through several stages, the ICCS-MP finally implements a two

  19. Health and safety impacts of nuclear, geothermal, and fossil-fuel electric generation in California. Volume 9. Methodologies for review of the health and safety aspects of proposed nuclear, geothermal, and fossil-fuel sites and facilities

    Energy Technology Data Exchange (ETDEWEB)

    Nero, A.V.; Quinby-Hunt, M.S.

    1977-01-01

    This report sets forth methodologies for review of the health and safety aspects of proposed nuclear, geothermal, and fossil-fuel sites and facilities for electric power generation. The review is divided into a Notice of Intention process and an Application for Certification process, in accordance with the structure to be used by the California Energy Resources Conservation and Development Commission, the first emphasizing site-specific considerations, the second examining the detailed facility design as well. The Notice of Intention review is divided into three possible stages: an examination of emissions and site characteristics, a basic impact analysis, and an assessment of public impacts. The Application for Certification review is divided into five possible stages: a review of the Notice of Intention treatment, review of the emission control equipment, review of the safety design, review of the general facility design, and an overall assessment of site and facility acceptability.

  20. Influence of fossil-fuel power plant emissions on the surface fine particulate matter in the Seoul Capital Area, South Korea.

    Science.gov (United States)

    Kim, Byeong-Uk; Kim, Okgil; Kim, Hyun Cheol; Kim, Soontae

    2016-09-01

    The South Korean government plans to reduce region-wide annual PM2.5 (particulate matter with an aerodynamic diameter ≤2.5 μm) concentrations in the Seoul Capital Area (SCA) from 2010 levels of 27 µg/m(3) to 20 µg/m(3) by 2024. At the same time, it is inevitable that emissions from fossil-fuel power plants will continue to increase if electricity generation expands and the generation portfolio remains the same in the future. To estimate incremental PM2.5 contributions due to projected electricity generation growth in South Korea, we utilized an ensemble forecasting member of the Integrated Multidimensional Air Quality System for Korea based on the Community Multi-scale Air Quality model. We performed sensitivity runs with across-the-board emission reductions for all fossil-fuel power plants in South Korea to estimate the contribution of PM2.5 from domestic fossil-fuel power plants. We estimated that fossil-fuel power plants are responsible for 2.4% of the annual PM2.5 national ambient air quality standard in the SCA as of 2010. Based on the electricity generation and the annual contribution of fossil-fuel power plants in 2010, we estimated that annual PM2.5 concentrations may increase by 0.2 µg/m(3) per 100 TWhr due to additional electricity generation. With currently available information on future electricity demands, we estimated that the total future contribution of fossil-fuel power plants would be 0.87 µg/m(3), which is 12.4% of the target reduction amount of the annual PM2.5 concentration by 2024. We also approximated that the number of premature deaths caused by existing fossil-fuel power plants would be 736 in 2024. Since the proximity of power plants to the SCA and the types of fuel used significantly impact this estimation, further studies are warranted on the impact of physical parameters of plants, such as location and stack height, on PM2.5 concentrations in the SCA due to each precursor. Improving air quality by reducing fine particle

  1. N2O release from agro-biofuel production negates global warming reduction by replacing fossil fuels

    Directory of Open Access Journals (Sweden)

    A. R. Mosier

    2008-01-01

    Full Text Available The relationship, on a global basis, between the amount of N fixed by chemical, biological or atmospheric processes entering the terrestrial biosphere, and the total emission of nitrous oxide (N2O, has been re-examined, using known global atmospheric removal rates and concentration growth of N2O as a proxy for overall emissions. For both the pre-industrial period and in recent times, after taking into account the large-scale changes in synthetic N fertiliser production, we find an overall conversion factor of 3–5% from newly fixed N to N2O-N. We assume the same factor to be valid for biofuel production systems. It is covered only in part by the default conversion factor for "direct" emissions from agricultural crop lands (1% estimated by IPCC (2006, and the default factors for the "indirect" emissions (following volatilization/deposition and leaching/runoff of N: 0.35–0.45% cited therein. However, as we show in the paper, when additional emissions included in the IPCC methodology, e.g. those from livestock production, are included, the total may not be inconsistent with that given by our "top-down" method. When the extra N2O emission from biofuel production is calculated in "CO2-equivalent" global warming terms, and compared with the quasi-cooling effect of "saving" emissions of fossil fuel derived CO2, the outcome is that the production of commonly used biofuels, such as biodiesel from rapeseed and bioethanol from corn (maize, depending on N fertilizer uptake efficiency by the plants, can contribute as much or more to global warming by N2O emissions than cooling by fossil fuel savings. Crops with less N demand, such as grasses and woody coppice species, have more favourable climate impacts. This analysis only considers the conversion of biomass to biofuel. It does not take into account the use of fossil fuel on the farms and for fertilizer and pesticide production, but it also neglects the production of useful co-products. Both factors

  2. Chemistry of fossil fuels and biofuels (cambridge series in chemical engineering)

    CERN Document Server

    Schobert, Harold

    2013-01-01

    Focusing on today's major fuel resources - ethanol, biodiesel, wood, natural gas, petroleum products and coal - this book discusses the formation, composition and properties of the fuels, and the ways in which they are processed for commercial use. The book examines the origin of fuels through natural processes such as photosynthesis and the geological transformation of ancient plant material; the relationships between their composition, molecular structures, and physical properties; and the various processes by which they are converted or refined into the fuel products appearing on today's market. Fundamental chemical aspects such as catalysis and the behaviour of reactive intermediates are presented, and global warming and anthropogenic carbon dioxide emissions are also discussed. The book is suitable for graduate students in energy engineering, chemical engineering, mechanical engineering and chemistry, as well as professional scientists and engineers.

  3. Exploration for fossil and nuclear fuels from orbital altitudes. [results of ERTS program for oil exploration

    Science.gov (United States)

    Short, N. M.

    1974-01-01

    Results from the ERTS program pertinent to exploration for oil, gas, and uranium are discussed. A review of achievements in relevant geological studies from ERTS, and a survey of accomplishments oriented towards exploration for energy sources are presented along with an evaluation of the prospects and limitations of the space platform approach to fuel exploration, and an examination of continuing programs designed to prove out the use of ERTS and other space system in exploring for fuel resources.

  4. Real Costs Assessment of Solar-Hydrogen and Some Fossil Fuels by means of a Combustion Analysis

    Directory of Open Access Journals (Sweden)

    Giovanni Nicoletti

    2016-01-01

    Full Text Available In order to compare solar-hydrogen and the most used fossil fuels, the evaluation of the “external” costs related to their use is required. These costs involve the environmental damage produced by the combustion reactions, the health problems caused by air pollution, the damage to land from fuel mining, and the environmental degradation linked to the global warming, the acid rains, and the water pollution. For each fuel, the global cost is determined as sum of the market price and of the correspondent external costs. In order to obtain a quantitative comparison, the quality of the different combustion reactions and the efficiency of the technologies employed in the specific application sector have to be considered adequately. At this purpose, an entropic index that considers the degree of irreversibility produced during the combustion process and the degradation of surroundings is introduced. Additionally, an environmental index that measures the pollutants released during the combustions is proposed. The combination of these indexes and the efficiency of the several technologies employed in four energy sectors have allowed the evaluation of the total costs, highlighting an economic scenario from which the real advantages concerning the exploitation of different energy carrier are determined.

  5. Thermodynamic analysis of biofuels as fuels for high temperature fuel cells

    Directory of Open Access Journals (Sweden)

    Milewski Jarosław

    2013-02-01

    Full Text Available Based on mathematical modeling and numerical simulations, applicativity of various biofuels on high temperature fuel cell performance are presented. Governing equations of high temperature fuel cell modeling are given. Adequate simulators of both solid oxide fuel cell (SOFC and molten carbonate fuel cell (MCFC have been done and described. Performance of these fuel cells with different biofuels is shown. Some characteristics are given and described. Advantages and disadvantages of various biofuels from the system performance point of view are pointed out. An analysis of various biofuels as potential fuels for SOFC and MCFC is presented. The results are compared with both methane and hydrogen as the reference fuels. The biofuels are characterized by both lower efficiency and lower fuel utilization factors compared with methane. The presented results are based on a 0D mathematical model in the design point calculation. The governing equations of the model are also presented. Technical and financial analysis of high temperature fuel cells (SOFC and MCFC are shown. High temperature fuel cells can be fed by biofuels like: biogas, bioethanol, and biomethanol. Operational costs and possible incomes of those installation types were estimated and analyzed. A comparison against classic power generation units is shown. A basic indicator net present value (NPV for projects was estimated and commented.

  6. Crude Glycerol as Cost-Effective Fuel for Combined Heat and Power to Replace Fossil Fuels, Final Technical Report

    Energy Technology Data Exchange (ETDEWEB)

    Roberts, William L

    2012-10-31

    The primary objectives of this work can be summed into two major categories. Firstly, the fundamentals of the combustion of glycerol (in both a refined and unrefined form) were to be investigated, with emphasis of the development of a system capable of reliably and repeatedly combusting glycerol as well as an analysis of the emissions produced during glycerol combustion. Focus was placed on quantifying common emissions in comparison to more traditional fuels and this work showed that the burner developed was able to completely combust glycerol within a relatively wide range of operating conditions. Additionally, focus was placed on examining specific emissions in more detail, namely interesting NOx emissions observed in initial trials, acrolein and other volatile organic emissions, and particulate and ash emissions. This work showed that the combustion of crude glycerol could result in significantly reduced NOx emissions as a function of the high fuel bound oxygen content within the glycerol fuel. It also showed that when burned properly, the combustion of crude glycerol did not result in excessive emissions of acrolein or any other VOC compared to the combustion from more traditional fuels. Lastly however, this work has shown that in any practical application in which glycerol is being burned, it will be necessary to explore ash mitigation techniques due to the very high particulate matter concentrations produced during glycerol combustion. These emissions are comparable to unfiltered coal combustion and are directly tied to the biodiesel production method. The second focus of this work was directed to developing a commercialization strategy for the use of glycerol as a fuel replacement. This strategy has identified a 30 month plan for the scaling up of the laboratory scale burner into a pre-pilot scale system. Additionally, financing options were explored and an assessment was made of the economics of replacing a traditional fuel (namely natural gas) with crude

  7. Effect of fossil fuels on the parameters of CO2 capture.

    Science.gov (United States)

    Nagy, Tibor; Mizsey, Peter

    2013-08-06

    The carbon dioxide capture is a more and more important issue in the design and operation of boilers and/or power stations because of increasing environmental considerations. Such processes, absorber desorber should be able to cope with flue gases from the use of different fossil primary energy sources, in order to guarantee a flexible, stable, and secure energy supply operation. The changing flue gases have significant influence on the optimal operation of the capture process, that is, where the required heating of the desorber is the minimal. Therefore special considerations are devoted to the proper design and control of such boiler and/or power stations equipped with CO2 capture process.

  8. Sensitivity of global-scale climate change attribution results to inclusion of fossil fuel black carbon aerosol - article no. L14701

    Energy Technology Data Exchange (ETDEWEB)

    Jones, G.S.; Jones, A.; Roberts, D.L.; Stott, P.A.; Williams, K.D. [Hadley Center for Climate Predictions & Research, Exeter (United Kingdom)

    2005-07-16

    It is likely that greenhouse gas emissions caused most of the global mean warming observed during the 20th century, and that sulphate aerosols counteracted this warming to some extent, by reflecting solar radiation to space and thereby cooling the planet. However, the importance of another aerosol, namely black carbon, could be underestimated. Here we include fossil fuel black carbon aerosol in a detection and attribution analysis with greenhouse gas and sulphate aerosols. We find that most of the warming of the 20th Century is attributable to changes in greenhouse gases offset by net aerosol cooling. However the pattern of temperature change due to black carbon is currently indistinguishable from the sulphate aerosol pattern of temperature change. The attribution of temperature change due to greenhouse gases is not sensitive to the inclusion of black carbon. We can be confident about the overall attribution of total aerosols, but less so about the contributions of black carbon emissions to 20th century climate change. This work presents no evidence that black carbon aerosol forcing outweighed the cooling due to sulphate aerosol.

  9. High Temperature PEM Fuel Cells - Degradation and Durability

    DEFF Research Database (Denmark)

    Araya, Samuel Simon

    be stored in liquid alcohols such as methanol, which can be sources of hydrogen for fuel cell applications. In addition, fuel cells unlike other technologies can use a variety of other fuels that can provide a source of hydrogen, such as biogas, methane, butane, etc. More fuel flexibility combined...... for storage and distribution of hydrogen, it is more practical to use liquid alcohols as energy carriers for fuel cells. Among these, methanol is very attractive, as it can be obtained from a variety of renewable sources and has a relatively low reforming temperature for the production of hydrogen rich....... On the other hand, CO and methanol-water vapor mixture degrade the fuel cell proportionally to the amounts in which they are tested. In this dissertation some of the mechanisms with which the impurities affect the fuel cell are discussed and interdependence among the effects is also studied. This showed...

  10. Energy Systems in the Era of Energy Vectors A Key to Define, Analyze and Design Energy Systems Beyond Fossil Fuels

    CERN Document Server

    Orecchini, Fabio

    2012-01-01

    What lies beyond the era of fossil fuels? While most answers focus on different primary energy resources, Energy Systems in the Era of Energy Vectors provides a completely new approach. Instead of providing a traditional consumption analysis of classical primary energy resources such as oil, coal, nuclear power and gas, Energy Systems in the Era of Energy Vectors describes and assesses energy technologies, markets and future strategies, focusing on their capacity to produce, exchange, and use energy vectors. Special attention is given to the renewable energy resources available in different areas of the world and made exploitable by the integration of energy vectors in the global energy system. Clear definitions of energy vectors and energy systems are used as the basis for a complete explanation and assessment of up-to-date, available technologies for energy resources, transport and storage systems, conversion and use. The energy vectors scheme allows the potential realisation of a worldwide sustainable ener...

  11. Determination of wood burning and fossil fuel contribution of black carbon at Delhi, India using aerosol light absorption technique.

    Science.gov (United States)

    Tiwari, S; Pipal, A S; Srivastava, A K; Bisht, D S; Pandithurai, G

    2015-02-01

    A comprehensive measurement program of effective black carbon (eBC), fine particle (PM2.5), and carbon monoxide (CO) was undertaken during 1 December 2011 to 31 March 2012 (winter period) in Delhi, India. The mean mass concentrations of eBC, PM2.5, and CO were recorded as 12.1 ± 8.7 μg/m(3), 182.75 ± 114.5 μg/m(3), and 3.41 ± 1.6 ppm, respectively, during the study period. Also, the absorption Angstrom exponent (AAE) was estimated from eBC and varied from 0.38 to 1.29 with a mean value of 1.09 ± 0.11. The frequency of occurrence of AAE was ~17 % less than unity whereas ~83 % greater than unity was observed during the winter period in Delhi. The mass concentrations of eBC were found to be higher by ~34 % of the average value of eBC (12.1 μg/m(3)) during the study period. Sources of eBC were estimated, and they were ~94 % from fossil fuel (eBCff) combustion whereas only 6 % was from wood burning (eBCwb). The ratio between eBCff and eBCwb was 15, which indicates a higher impact from fossil fuels compared to biomass burning. When comparing eBCff during day and night, a factor of three higher concentrations was observed in nighttime than daytime, and it is due to combustion of fossil fuel (diesel vehicle emission) and shallow boundary layer conditions. The contribution of eBCwb in eBC was higher between 1800 and 2100 hours due to burning of wood/biomass. A significant correlation between eBC and PM2.5 (r = 0.78) and eBC and CO (r = 0.46) indicates the similarity in location sources. The mass concentration of eBC was highest (23.4 μg/m(3)) during the month of December when the mean visibility (VIS) was lowest (1.31 km). Regression analysis among wind speed (WS), VIS, soot particles, and CO was studied, and significant negative relationships were seen between VIS and eBC (-0.65), eBCff (-0.66), eBCwb (-0.34), and CO (-0.65); however, between WS and eBC (-0.68), eBCff (-0.67), eBCwb (-0.28), and CO (-0.53). The regression analysis indicated

  12. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report

    Energy Technology Data Exchange (ETDEWEB)

    Bergman, H.L.; Anderson, A.D.

    1977-12-01

    This is the first annual report issued under a project to evaluate the effects of aqueous effluents from in-situ fossil fuel processing technologies on aquatic biota. Briefly, the goals of the project are to: evaluate the toxicity of process water effluents on aquatic biota; recommend maximum exposure concentrations for process water constituents; and assist DOE in using project data and recommendations to design control technologies and to assess environmental impacts. The project objectives for Year 1 were pursued through the following five tasks: a literature review on process water constituents; toxicity studies on the effect of process waters and six process water constituents on aquatic biota; degradation rate studies on four to six process water constituents; bioaccumulation studies on four to six process water constituents; and recommendations on maximum exposure concentrations for process water constituents based on data from the project and from the literature. Progress toward completion of these goals is presented.

  13. A 21st-century shift from fossil-fuel to biogenic methane emissions indicated by 13CH4

    Science.gov (United States)

    Schaefer, Hinrich; Fletcher, Sara E. Mikaloff; Veidt, Cordelia; Lassey, Keith R.; Brailsford, Gordon W.; Bromley, Tony M.; Dlugokencky, Edward J.; Michel, Sylvia E.; Miller, John B.; Levin, Ingeborg; Lowe, Dave C.; Martin, Ross J.; Vaughn, Bruce H.; White, James W. C.

    2016-04-01

    Between 1999 and 2006, a plateau interrupted the otherwise continuous increase of atmospheric methane concentration [CH4] since preindustrial times. Causes could be sink variability or a temporary reduction in industrial or climate-sensitive sources. We reconstructed the global history of [CH4] and its stable carbon isotopes from ice cores, archived air, and a global network of monitoring stations. A box-model analysis suggests that diminishing thermogenic emissions, probably from the fossil-fuel industry, and/or variations in the hydroxyl CH4 sink caused the [CH4] plateau. Thermogenic emissions did not resume to cause the renewed [CH4] rise after 2006, which contradicts emission inventories. Post-2006 source increases are predominantly biogenic, outside the Arctic, and arguably more consistent with agriculture than wetlands. If so, mitigating CH4 emissions must be balanced with the need for food production.

  14. Quantification of fossil fuel CO2 emissions at the urban scale: Results from the Indianapolis Flux Project (INFLUX)

    Science.gov (United States)

    Turnbull, J. C.; Cambaliza, M. L.; Sweeney, C.; Karion, A.; Newberger, T.; Tans, P. P.; Lehman, S.; Davis, K. J.; Miles, N. L.; Richardson, S.; Lauvaux, T.; Shepson, P.; Gurney, K. R.; Song, Y.; Razlivanov, I. N.

    2012-12-01

    Emissions of fossil fuel CO2 (CO2ff) from anthropogenic sources are the primary driver of observed increases in the atmospheric CO2 burden, and hence global warming. Quantification of the magnitude of fossil fuel CO2 emissions is vital to improving our understanding of the global and regional carbon cycle, and independent evaluation of reported emissions is essential to the success of any emission reduction efforts. The urban scale is of particular interest, because ~75% CO2ff is emitted from urban regions, and cities are leading the way in attempts to reduce emissions. Measurements of 14CO2 can be used to determine CO2ff, yet existing 14C measurement techniques require laborious laboratory analysis and measurements are often insufficient for inferring an urban emission flux. This presentation will focus on how 14CO2 measurements can be combined with those of more easily measured ancillary tracers to obtain high resolution CO2ff mixing ratio estimates and then infer the emission flux. A pilot study over Sacramento, California showed strong correlations between CO2ff and carbon monoxide (CO) and demonstrated an ability to quantify the urban flux, albeit with large uncertainties. The Indianapolis Flux Project (INFLUX) aims to develop and assess methods to quantify urban greenhouse gas emissions. Indianapolis was chosen as an ideal test case because it has relatively straightforward meteorology; a contained, isolated, urban region; and substantial and well-known fossil fuel CO2 emissions. INFLUX incorporates atmospheric measurements of a suite of gases and isotopes including 14C from light aircraft and from a network of existing tall towers surrounding the Indianapolis urban area. The recently added CO2ff content is calculated from measurements of 14C in CO2, and then convolved with atmospheric transport models and ancillary data to estimate the urban CO2ff emission flux. Significant innovations in sample collection include: collection of hourly averaged samples to

  15. Sources of non-fossil-fuel emissions in carbonaceous aerosols during early winter in Chinese cities

    Directory of Open Access Journals (Sweden)

    D. Liu

    2017-09-01

    Full Text Available China experiences frequent and severe haze outbreaks from the beginning of winter. Carbonaceous aerosols are regarded as an essential factor in controlling the formation and evolution of haze episodes. To elucidate the carbon sources of air pollution, source apportionment was conducted using radiocarbon (14C and unique molecular organic tracers. Daily 24 h PM2. 5 samples were collected continuously from October 2013 to November 2013 in 10 Chinese cities. The 14C results indicated that non-fossil-fuel (NF emissions were predominant in total carbon (TC; average  =  65 ± 7 %. Approximately half of the EC was derived primarily from biomass burning (BB (average  =  46 ± 11 %, while over half of the organic carbon (OC fraction comprised NF (average  =  68 ± 7 %. On average, the largest contributor to TC was NF-derived secondary OC (SOCnf, which accounted for 46 ± 7 % of TC, followed by SOC derived from fossil fuels (FF (SOCf; 16 ± 3 %, BB-derived primary OC (POCbb; 13 ± 5 %, POC derived from FF (POCf; 12 ± 3 %, EC derived from FF (ECf; 7 ± 2 % and EC derived from BB (ECbb; 6 ± 2 %. The regional background carbonaceous aerosol composition was characterized by NF sources; POCs played a major role in northern China, while SOCs contributed more in other regions. However, during haze episodes, there were no dramatic changes in the carbon source or composition in the cities under study, but the contribution of POC from both FF and NF increased significantly.

  16. Characterization of carbonaceous aerosols outflow from India and Arabia: Biomass/biofuel burning and fossil fuel combustion

    Science.gov (United States)

    Guazzotti, S. A.; Suess, D. T.; Coffee, K. R.; Quinn, P. K.; Bates, T. S.; Wisthaler, A.; Hansel, A.; Ball, W. P.; Dickerson, R. R.; Neusüß, C.; Crutzen, P. J.; Prather, K. A.

    2003-08-01

    A major objective of the Indian Ocean Experiment (INDOEX) involves the characterization of the extent and chemical composition of pollution outflow from the Indian Subcontinent during the winter monsoon. During this season, low-level flow from the continent transports pollutants over the Indian Ocean toward the Intertropical Convergence Zone (ITCZ). Traditional standardized aerosol particle chemical analysis, together with real-time single particle and fast-response gas-phase measurements provided characterization of the sampled aerosol chemical properties. The gas- and particle-phase chemical compositions of encountered air parcels changed according to their geographic origin, which was traced by back trajectory analysis. The temporal evolutions of acetonitrile, a long-lived specific tracer for biomass/biofuel burning, number concentration of submicrometer carbon-containing particles with potassium (indicative of combustion sources), and mass concentration of submicrometer non-sea-salt (nss) potassium are compared. High correlation coefficients (0.84 biofuel burning are subject to long-range transport, thereby contributing to anthropogenic pollution even in areas downwind of South Asia. Specifically, high concentrations of submicrometer nss potassium, carbon-containing particles with potassium, and acetonitrile are observed in air masses advected from the Indian subcontinent, indicating a strong impact of biomass/biofuel burning in India during the sampling periods (74 (±9)% biomass/biofuel contribution to submicrometer carbonaceous aerosol). In contrast, lower values for these same species were measured in air masses from the Arabian Peninsula, where dominance of fossil fuel combustion is suggested by results from single-particle analysis and supported by results from gas-phase measurements (63 (±9))% fossil fuel contribution to submicrometer carbonaceous aerosol). Results presented here demonstrate the importance of simultaneous, detailed gas- and particle

  17. A multiresolution spatial parametrization for the estimation of fossil-fuel carbon dioxide emissions via atmospheric inversions.

    Energy Technology Data Exchange (ETDEWEB)

    Ray, Jaideep; Lee, Jina; Lefantzi, Sophia; Yadav, Vineet [Carnegie Institution for Science, Stanford, CA; Michalak, Anna M. [Carnegie Institution for Science, Stanford, CA; van Bloemen Waanders, Bart Gustaaf [Sandia National Laboratories, Albuquerque, NM; McKenna, Sean Andrew [IBM Research, Mulhuddart, Dublin 15, Ireland

    2013-04-01

    The estimation of fossil-fuel CO2 emissions (ffCO2) from limited ground-based and satellite measurements of CO2 concentrations will form a key component of the monitoring of treaties aimed at the abatement of greenhouse gas emissions. To that end, we construct a multiresolution spatial parametrization for fossil-fuel CO2 emissions (ffCO2), to be used in atmospheric inversions. Such a parametrization does not currently exist. The parametrization uses wavelets to accurately capture the multiscale, nonstationary nature of ffCO2 emissions and employs proxies of human habitation, e.g., images of lights at night and maps of built-up areas to reduce the dimensionality of the multiresolution parametrization. The parametrization is used in a synthetic data inversion to test its suitability for use in atmospheric inverse problem. This linear inverse problem is predicated on observations of ffCO2 concentrations collected at measurement towers. We adapt a convex optimization technique, commonly used in the reconstruction of compressively sensed images, to perform sparse reconstruction of the time-variant ffCO2 emission field. We also borrow concepts from compressive sensing to impose boundary conditions i.e., to limit ffCO2 emissions within an irregularly shaped region (the United States, in our case). We find that the optimization algorithm performs a data-driven sparsification of the spatial parametrization and retains only of those wavelets whose weights could be estimated from the observations. Further, our method for the imposition of boundary conditions leads to a 10computational saving over conventional means of doing so. We conclude with a discussion of the accuracy of the estimated emissions and the suitability of the spatial parametrization for use in inverse problems with a significant degree of regularization.

  18. Isotopic measurements of atmospheric methane in Los Angeles, California, USA: Influence of “fugitive” fossil fuel emissions

    Science.gov (United States)

    Townsend-Small, Amy; Tyler, Stanley C.; Pataki, Diane E.; Xu, Xiaomei; Christensen, Lance E.

    2012-04-01

    Recent studies have suggested that CH4 emissions in Los Angeles and other large cities may be underestimated. We utilized stable isotopes (13C and D) and radiocarbon (14C) to investigate sources of CH4 in Los Angeles, California. First, we made measurements of δ13C and δD of various CH4 sources in urban areas. Fossil fuel CH4 sources (oil refineries, power plants, traffic, and oil drilling fields) had δ13C values between -45 and -30‰ and dD values between -275 and -100‰, whereas biological CH4 (cows, biofuels, landfills, sewage treatment plants, and cattle feedlots) had δ13C values between -65 and -45‰ and δD values between -350 and -275‰. We made high-altitude observations of CH4 concentration using continuous tunable laser spectroscopy measurements combined with isotope analyses (13C, 14C, and D) of discrete samples to constrain urban CH4 sources. Our data indicate that the dominant source of CH4 in Los Angeles has a δ13C value of approximately -41.5‰ and a δD value between -229 and -208‰. Δ14C of CH4 in urban air samples ranged from +262 to +344‰ (127.1 to 134.9 pMC), depleted with respect to average global background CH4. We conclude that the major source of CH4 in Los Angeles is leakage of fossil fuels, such as from geologic formations, natural gas pipelines, oil refining, and/or power plants. More research is needed to constrain fluxes of CH4 from natural gas distribution and refining, as this flux may increase with greater reliance on natural gas and biogas for energy needs.

  19. Lowering the temperature of solid oxide fuel cells.

    Science.gov (United States)

    Wachsman, Eric D; Lee, Kang Taek

    2011-11-18

    Fuel cells are uniquely capable of overcoming combustion efficiency limitations (e.g., the Carnot cycle). However, the linking of fuel cells (an energy conversion device) and hydrogen (an energy carrier) has emphasized investment in proton-exchange membrane fuel cells as part of a larger hydrogen economy and thus relegated fuel cells to a future technology. In contrast, solid oxide fuel cells are capable of operating on conventional fuels (as well as hydrogen) today. The main issue for solid oxide fuel cells is high operating temperature (about 800°C) and the resulting materials and cost limitations and operating complexities (e.g., thermal cycling). Recent solid oxide fuel cells results have demonstrated extremely high power densities of about 2 watts per square centimeter at 650°C along with flexible fueling, thus enabling higher efficiency within the current fuel infrastructure. Newly developed, high-conductivity electrolytes and nanostructured electrode designs provide a path for further performance improvement at much lower temperatures, down to ~350°C, thus providing opportunity to transform the way we convert and store energy.

  20. Final Report - Low Temperature Combustion Chemistry And Fuel Component Interactions

    Energy Technology Data Exchange (ETDEWEB)

    Wooldridge, Margaret [Univ. of Michigan, Ann Arbor, MI (United States)

    2017-02-24

    Recent research into combustion chemistry has shown that reactions at “low temperatures” (700 – 1100 K) have a dramatic influence on ignition and combustion of fuels in virtually every practical combustion system. A powerful class of laboratory-scale experimental facilities that can focus on fuel chemistry in this temperature range is the rapid compression facility (RCF), which has proven to be a versatile tool to examine the details of fuel chemistry in this important regime. An RCF was used in this project to advance our understanding of low temperature chemistry of important fuel compounds. We show how factors including fuel molecular structure, the presence of unsaturated C=C bonds, and the presence of alkyl ester groups influence fuel auto-ignition and produce variable amounts of negative temperature coefficient behavior of fuel ignition. We report new discoveries of synergistic ignition interactions between alkane and alcohol fuels, with both experimental and kinetic modeling studies of these complex interactions. The results of this project quantify the effects of molecular structure on combustion chemistry including carbon bond saturation, through low temperature experimental studies of esters, alkanes, alkenes, and alcohols.

  1. Estimating particulate matter health impact related to the combustion of different fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Kuenen, Jeroen; Kranenburg, Richard; Hendriks, Carlijn; Schaap, Martijn [TNO, Utrecht (Netherlands); Gschwind, Benoit; Lefevre, Mireille; Blanc, Isabelle [MINES ParisTech, Sophia Antipolis (France); Drebszok, Kamila; Wyrwa, Artur [AGH Univ. of Science and Technology, Krakow (Poland); Stetter, Daniel [DLR Deutsches Zentrum fuer Luft- und Raumfahrt e.V., Stuttgart (Germany)

    2013-07-01

    Exposure to particulate matter (PM) in ambient air leads to adverse health effects. To design cost effective mitigation strategies, a thorough understanding of the sources of particulate matter is crucial. We have successfully generated a web map service that allows to access information on fuel dependent health effects due to particulate matter. For this purpose, the LOTOS-EUROS air pollution model was equipped with a source apportionment module that tracks the origin of the modelled particulate matter distributions thoughout a simulation. Combined with a dedicated emission inventory PM2.5 maps specified by fuel type were generated for 2007-2009. These maps were combined with a health impact calculation to estimate Lost of Life Expectancy for each fuel categories. An user friendly web client was generated to access the results and use the web mapping service in an easy manner. (orig.)

  2. INVESTIGATION OF FOSSIL FUEL AND LIQUID BIOFUEL BLEND PROPERTIES USING ARTIFICIAL NEURAL NETWORK

    Directory of Open Access Journals (Sweden)

    G. Najafi

    2012-06-01

    Full Text Available Gasoline fuel is the baseline fuel in this research, to which bioethanol, biodiesel and diesel are additives. The fuel blends were prepared based on different volumes and following which, ASTM (American Society for Testing and Materials test methods analysed some of the important properties of the blends, such as: density, dynamic viscosity, kinematic viscosity and water and sediment. Experimental data were analysed by means of Matlab software. The results obtained from artificial neural network analysis of the data showed that the network with feed forward back propagation of the Levenberg-Marquardt train LM function with 10 neurons in the hidden layer was the best for predicting the parameters, including: Water and sediment (W, dynamic viscosity (DV, kinematic viscosity (KV and density (De. The experimental data had a good correlation with ANN-predicted values according to 0.96448 for regression.

  3. Microscale In Vitro Assays for the Investigation of Neutral Red Retention and Ethoxyresorufin-O-Deethylase of Biofuels and Fossil Fuels.

    Directory of Open Access Journals (Sweden)

    Sebastian Heger

    Full Text Available Only few information on the potential toxic effectiveness of biofuels are available. Due to increasing worldwide demand for energy and fuels during the past decades, biofuels are considered as a promising alternative for fossil fuels in the transport sector. Hence, more information on their hazard potentials are required to understand the toxicological impact of biofuels on the environment. In the German Cluster of Excellence "Tailor-made Fuels from Biomass" design processes for economical, sustainable and environmentally friendly biofuels are investigated. In an unique and interdisciplinary approach, ecotoxicological methods are applied to gain information on potential adverse environmental effects of biofuels at an early phase of their development. In the present study, three potential biofuels, ethyl levulinate, 2-methyltetrahydrofuran and 2-methylfuran were tested. Furthermore, we investigated a fossil gasoline fuel, a fossil diesel fuel and an established biodiesel. Two in vitro bioassays, one for assessing cytotoxicity and one for aryl hydrocarbon receptor agonism, so called dioxin-like activity, as measured by Ethoxyresorufin-O-Deethylase, were applied using the permanent fish liver cell line RTL-W1 (Oncorhynchus mykiss. The special properties of these fuel samples required modifications of the test design. Points that had to be addressed were high substance volatility, material compatibility and low solubility. For testing of gasoline, diesel and biodiesel, water accommodated fractions and a passive dosing approach were tested to address the high hydrophobicity and low solubility of these complex mixtures. Further work has to focus on an improvement of the chemical analyses of the fuel samples to allow a better comparison of any effects of fossil fuels and biofuels.

  4. Microscale In Vitro Assays for the Investigation of Neutral Red Retention and Ethoxyresorufin-O-Deethylase of Biofuels and Fossil Fuels.

    Science.gov (United States)

    Heger, Sebastian; Bluhm, Kerstin; Brendt, Julia; Mayer, Philipp; Anders, Nico; Schäffer, Andreas; Seiler, Thomas-Benjamin; Hollert, Henner

    Only few information on the potential toxic effectiveness of biofuels are available. Due to increasing worldwide demand for energy and fuels during the past decades, biofuels are considered as a promising alternative for fossil fuels in the transport sector. Hence, more information on their hazard potentials are required to understand the toxicological impact of biofuels on the environment. In the German Cluster of Excellence "Tailor-made Fuels from Biomass" design processes for economical, sustainable and environmentally friendly biofuels are investigated. In an unique and interdisciplinary approach, ecotoxicological methods are applied to gain information on potential adverse environmental effects of biofuels at an early phase of their development. In the present study, three potential biofuels, ethyl levulinate, 2-methyltetrahydrofuran and 2-methylfuran were tested. Furthermore, we investigated a fossil gasoline fuel, a fossil diesel fuel and an established biodiesel. Two in vitro bioassays, one for assessing cytotoxicity and one for aryl hydrocarbon receptor agonism, so called dioxin-like activity, as measured by Ethoxyresorufin-O-Deethylase, were applied using the permanent fish liver cell line RTL-W1 (Oncorhynchus mykiss). The special properties of these fuel samples required modifications of the test design. Points that had to be addressed were high substance volatility, material compatibility and low solubility. For testing of gasoline, diesel and biodiesel, water accommodated fractions and a passive dosing approach were tested to address the high hydrophobicity and low solubility of these complex mixtures. Further work has to focus on an improvement of the chemical analyses of the fuel samples to allow a better comparison of any effects of fossil fuels and biofuels.

  5. Biofuel Impacts on World Food Supply: Use of Fossil Fuel, Land and Water Resources

    Directory of Open Access Journals (Sweden)

    Robert McCormack

    2008-09-01

    Full Text Available The rapidly growing world population and rising consumption of biofuels are increasing demand for both food and biofuels. This exaggerates both food and fuel shortages. Using food crops such as corn grain to produce ethanol raises major nutritional and ethical concerns. Nearly 60% of humans in the world are currently malnourished, so the need for grains and other basic foods is critical. Growing crops for fuel squanders land, water and energy resources vital for the production of food for human consumption. Using corn for ethanol increases the price of U.S. beef, chicken, pork, eggs, breads, cereals, and milk more than 10% to 30%.

  6. System for controlling the operating temperature of a fuel cell

    Science.gov (United States)

    Fabis, Thomas R.; Makiel, Joseph M.; Veyo, Stephen E.

    2006-06-06

    A method and system are provided for improved control of the operating temperature of a fuel cell (32) utilizing an improved temperature control system (30) that varies the flow rate of inlet air entering the fuel cell (32) in response to changes in the operating temperature of the fuel cell (32). Consistent with the invention an improved temperature control system (30) is provided that includes a controller (37) that receives an indication of the temperature of the inlet air from a temperature sensor (39) and varies the heat output by at least one heat source (34, 36) to maintain the temperature of the inlet air at a set-point T.sub.inset. The controller (37) also receives an indication of the operating temperature of the fuel cell (32) and varies the flow output by an adjustable air mover (33), within a predetermined range around a set-point F.sub.set, in order to maintain the operating temperature of the fuel cell (32) at a set-point T.sub.opset.

  7. Global Partitioning of NOx Sources Using Satellite Observations: Relative Roles of Fossil Fuel Combustion, Biomass Burning and Soil Emissions

    Science.gov (United States)

    Jaegle, Lyatt; Steinberger, Linda; Martin, Randall V.; Chance, Kelly

    2005-01-01

    This document contains the following abstract for the paper "Global partitioning of NOx sources using satellite observations: Relative roles of fossil fuel combustion, biomass burning and soil emissions." Satellite observations have been used to provide important new information about emissions of nitrogen oxides. Nitrogen oxides (NOx) are significant in atmospheric chemistry, having a role in ozone air pollution, acid deposition and climate change. We know that human activities have led to a three- to six-fold increase in NOx emissions since pre-industrial times, and that there are three main surface sources of NOx: fuel combustion, large-scale fires, and microbial soil processes. How each of these sources contributes to the total NOx emissions is subject to some doubt, however. The problem is that current NOx emission inventories rely on bottom-up approaches, compiling large quantities of statistical information from diverse sources such as fuel and land use, agricultural data, and estimates of burned areas. This results in inherently large uncertainties. To overcome this, Lyatt Jaegle and colleagues from the University of Washington, USA, used new satellite observations from the Global Ozone Monitoring Experiment (GOME) instrument. As the spatial and seasonal distribution of each of the sources of NOx can be clearly mapped from space, the team could provide independent topdown constraints on the individual strengths of NOx sources, and thus help resolve discrepancies in existing inventories. Jaegle's analysis of the satellite observations, presented at the recent Faraday Discussion on "Atmospheric Chemistry", shows that fuel combustion dominates emissions at northern mid-latitudes, while fires are a significant source in the Tropics. Additionally, she discovered a larger than expected role for soil emissions, especially over agricultural regions with heavy fertilizer use. Additional information is included in the original extended abstract.

  8. Novel High Temperature Membrane for PEM Fuel Cells Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The innovation proposed in this STTR program is a high temperature membrane to increase the efficiency and power density of PEM fuel cells. The NASA application is...

  9. GREENHOUSE GASES FROM BIOMASS AND FOSSIL FUEL STOVES IN DEVELOPING COUNTRIES: A MANILA PILOT STUDY

    Science.gov (United States)

    Samples were taken of the combustion gases released by household cookstoves in Manila, Philippines. In a total of 24 samples, 14 cookstoves were tested. These were fueled by liquefied petroleum gas (LPG), kerosene (three kinds of stoves), charcoal, and wood. Ambient samples were ...

  10. COPROCESSING OF FOSSIL FUELS AND BIOMASS FOR CO2 EMISSION REDUCTION IN THE TRANSPORTATION SECTOR

    Science.gov (United States)

    The paper discusses an evaluation of the Hydrocarb process for conversion of carbonaceous raw material to clean carbon and methanol products. As fuel, methanol and carbon can be used economically, either independently or in slurry form, in efficient heat engines (turbines and int...

  11. Analytical correlations for intermediate temperature PEM fuel cells

    Science.gov (United States)

    Cheddie, Denver; Munroe, Norman

    This paper presents analytical correlations, which predict the polarization performance and thermal effects in an intermediate temperature proton exchange membrane fuel cell (PEMFC). Such correlations are useful for engineers and designers of fuel cells to expedite calculations without depending on complex computational models. Analytical results compare well with published experimental polarization data. They also indicate the temperature variations and dominant modes of heat transfer in a unit cell.

  12. Will economic growth and fossil fuel scarcity help or hinder climate stabilization? Overview of the RoSE multi-model study

    NARCIS (Netherlands)

    Kriegler, Elmar; Mouratiadou, Ioanna; Luderer, Gunnar; Bauer, Nico; Brecha, Robert J.; Calvin, Katherine; De Cian, Enrica; Edmonds, Jae; Jiang, Kejun; Tavoni, Massimo; Edenhofer, Ottmar

    We investigate the extent to which future energy transformation pathways meeting ambitious climate change mitigation targets depend on assumptions about economic growth and fossil fuel availability. The analysis synthesizes results from the RoSE multi-model study aiming to identify robust and

  13. Prices of agricultural commodities, biofuels and fossil fuels in long-run relationships: a comparative study for the USA and Europe

    DEFF Research Database (Denmark)

    Groth, Tanja; Bentzen, Jan

    2013-01-01

    Time-series data for the USA and Europe representing prices of agricultural commodities, biofuels and fossil fuels are used for a comparative analysis of long-run price relationships. There is some evidence for cointegration between ethanol and gasoline, especially for the USA, and in the case of...

  14. Carbon storage versus fossil fuel substitution: a climate change mitigation option for two different land use categories based on short and long rotation forestry in India

    NARCIS (Netherlands)

    Kaul, M.; Mohren, G.M.J.; Dadhwal, V.K.

    2010-01-01

    Short rotation bioenergy crops for energy production are considered an effective means to mitigate the greenhouse effect, mainly due to their ability to substitute fossil fuels. Alternatively, carbon can be sequestered and stored in the living biomass. This paper compares the two land use categories

  15. Fossil Fuels, Let’s Leave Them under Earth. Four Reasons to Vote “Yes” at the Italian Referendum on Drilling

    OpenAIRE

    ASPO Italy Association for the Study of PeakOil And Gas

    2016-01-01

    The referendum that will be held on 17 April 2016 is calling Italians to express their willingness on an aspect of licensing the sea drilling activities: The end of the licenses to the offshore exploitation of fossil fuel resources within the 12 miles from the coast.

  16. Fossil Fuels, Let’s Leave Them under Earth. Four Reasons to Vote “Yes” at the Italian Referendum on Drilling

    Directory of Open Access Journals (Sweden)

    ASPO Italy Association for the Study of PeakOil And Gas

    2016-04-01

    Full Text Available The referendum that will be held on 17 April 2016 is calling Italians to express their willingness on an aspect of licensing the sea drilling activities: The end of the licenses to the offshore exploitation of fossil fuel resources within the 12 miles from the coast.

  17. To break away from fossil fuels : a contribution to solve climatic change and energy security for Quebec; S'affranchir des carburants fossiles : une contribution a la lutte aux changements climatiques et a la securite energetique du Quebec

    Energy Technology Data Exchange (ETDEWEB)

    Bonin, P.; Seguin, H.; Waridel, L.

    2006-06-15

    In response to growing energy demands, Quebec has proposed the construction of 3 deep water terminals to accommodate methane tankers which transport liquefied natural gas (LNG). This paper focused on the proposed Gros Cacouna Port project in the St. Lawrence Seaway which is currently under study and subject to approval. Equiterre, questioned the energy security aspect of the proposal and argued that increasing Quebec's reliance on increasingly expensive energy would decrease energy security. In addition, importation of LNG would bring a clear exit of capital outside the province. Equiterre also argued that reliance on fossil fuels should be decreased in order to mitigate greenhouse gas emissions which contribute to climate change. The organization questioned whether the economic and social need for the proposed project justifies a greater dependency on fossil fuels and the associated impact on the environment and fragile ecosystems of the St. Lawrence. It was suggested that alternative solutions such as renewable energy sources and energy efficiency should be explored in order to promote sustainable development, increase energy security and reduce greenhouse gases. Equiterre argued that Quebec can and must decrease, and even eliminate, its dependence on fossil fuels, including natural gas, for Quebec's economic, social and environmental well-being. For these reasons, Equiterre recommended that the proposed project be rejected, particularly since the project proponents failed to show the real impact that the project would have on Quebec markets. 72 refs., 10 tabs., 21 figs.

  18. Advanced anodes for high-temperature fuel cells

    DEFF Research Database (Denmark)

    Atkinson, A.; Barnett, S.; Gorte, R.J.

    2004-01-01

    of these energy technologies; it is an all-ceramic device that operates at temperatures in the range 500-1,000degreesC. The SOFC offers certain advantages over lower temperature fuel cells, notably its ability to use carbon monoxide as a fuel rather than being poisoned by it, and the availability of high...... or anode. In terms of mitigating global warming, the ability of the SOFC to use commonly available fuels at high efficiency, promises an effective and early reduction in carbon dioxide emissions, and hence is one of the lead new technologies for improving the environment. Here, we discuss recent...

  19. Biofuels that cause land-use change may have much larger non-GHG air quality emissions than fossil fuels.

    Science.gov (United States)

    Tsao, C-C; Campbell, J E; Mena-Carrasco, M; Spak, S N; Carmichael, G R; Chen, Y

    2012-10-02

    Although biofuels present an opportunity for renewable energy production, significant land-use change resulting from biofuels may contribute to negative environmental, economic, and social impacts. Here we examined non-GHG air pollution impacts from both indirect and direct land-use change caused by the anticipated expansion of Brazilian biofuels production. We synthesized information on fuel loading, combustion completeness, and emission factors, and developed a spatially explicit approach with uncertainty and sensitivity analyses to estimate air pollution emissions. The land-use change emissions, ranging from 6.7 to 26.4 Tg PM(2.5), were dominated by deforestation burning practices associated with indirect land-use change. We also found Brazilian sugar cane ethanol and soybean biodiesel including direct and indirect land-use change effects have much larger life-cycle emissions than conventional fossil fuels for six regulated air pollutants. The emissions magnitude and uncertainty decrease with longer life-cycle integration periods. Results are conditional to the single LUC scenario employed here. After LUC uncertainty, the largest source of uncertainty in LUC emissions stems from the combustion completeness during deforestation. While current biofuels cropland burning policies in Brazil seek to reduce life-cycle emissions, these policies do not address the large emissions caused by indirect land-use change.

  20. Design and Control of High Temperature PEM Fuel Cell System

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl

    . Converting a liquid renewable fuel such as methanol in a chemical reactor, a reformer system, can provide the high temperature PEM fuel cells with a hydrogen rich gas that e-ciently produces electricity and heat at similar e-ciencies as with pure hydrogen. The systems retain their small and simple...... configuration, because the high quality waste heat of the fuel cells can be used to support the steam reforming process and the heat and evaporation of the liquid methanol/water mixture. If e-cient heat integration is manageable, similar performance to hydrogen based systems can be expected. In many......E-cient fuel cell systems have started to appear in many dierent commercial applications and large scale production facilities are already operating to supply fuel cells to support an ever growing market. Fuel cells are typically considered to replace leadacid batteries in applications where...

  1. Hydrologic impacts of past shifts of Earth's thermal equator offer insight into those to be produced by fossil fuel CO2.

    Science.gov (United States)

    Broecker, Wallace S; Putnam, Aaron E

    2013-10-15

    Major changes in global rainfall patterns accompanied a northward shift of Earth's thermal equator at the onset of an abrupt climate change 14.6 kya. This northward pull of Earth's wind and rain belts stemmed from disintegration of North Atlantic winter sea ice cover, which steepened the interhemispheric meridional temperature gradient. A southward migration of Earth's thermal equator may have accompanied the more recent Medieval Warm to Little Ice Age climate transition in the Northern Hemisphere. As fossil fuel CO2 warms the planet, the continents of the Northern Hemisphere are expected to warm faster than the Southern Hemisphere oceans. Therefore, we predict that a northward shift of Earth's thermal equator, initiated by an increased interhemispheric temperature contrast, may well produce hydrologic changes similar to those that occurred during past Northern Hemisphere warm periods. If so, the American West, the Middle East, and southern Amazonia will become drier, and monsoonal Asia, Venezuela, and equatorial Africa will become wetter. Additional paleoclimate data should be acquired and model simulations should be conducted to evaluate the reliability of this analog.

  2. Do forests best mitigate CO2emissions to the atmosphere by setting them aside for maximization of carbon storage or by management for fossil fuel substitution?

    Science.gov (United States)

    Taeroe, Anders; Mustapha, Walid Fayez; Stupak, Inge; Raulund-Rasmussen, Karsten

    2017-07-15

    Forests' potential to mitigate carbon emissions to the atmosphere is heavily debated and a key question is if forests left unmanaged to store carbon in biomass and soil provide larger carbon emission reductions than forests kept under forest management for production of wood that can substitute fossil fuels and fossil fuel intensive materials. We defined a modelling framework for calculation of the carbon pools and fluxes along the forest energy and wood product supply chains over 200 years for three forest management alternatives (FMA): 1) a traditionally managed European beech forest, as a business-as-usual case, 2) an energy poplar plantation, and 3) a set-aside forest left unmanaged for long-term storage of carbon. We calculated the cumulative net carbon emissions (CCE) and carbon parity times (CPT) of the managed forests relative to the unmanaged forest. Energy poplar generally had the lowest CCE when using coal as the reference fossil fuel. With natural gas as the reference fossil fuel, the CCE of the business-as-usual and the energy poplar was nearly equal, with the unmanaged forest having the highest CCE after 40 years. CPTs ranged from 0 to 156 years, depending on the applied model assumptions. CCE and CPT were especially sensitive to the reference fossil fuel, material alternatives to wood, forest growth rates for the three FMAs, and energy conversion efficiencies. Assumptions about the long-term steady-state levels of carbon stored in the unmanaged forest had a limited effect on CCE after 200 years. Analyses also showed that CPT was not a robust measure for ranking of carbon mitigation benefits. Copyright © 2017 Elsevier Ltd. All rights reserved.

  3. Enhanced High Temperature Corrosion Resistance in Advanced Fossil Energy Systems by Nano-Passive Layer Formation

    Energy Technology Data Exchange (ETDEWEB)

    Arnold R. Marder

    2007-06-14

    Due to their excellent corrosion resistance, iron aluminum alloys are currently being considered for use as weld claddings in fossil fuel fired power plants. The susceptibility to hydrogen cracking of these alloys at higher aluminum concentrations has highlighted the need for research into the effect of chromium additions on the corrosion resistance of lower aluminum alloys. In the present work, three iron aluminum alloys were exposed to simulated coal combustion environments at 500 C and 700 C for both short (100 hours) and long (5,000 hours) isothermal durations. Scanning electron microscopy was used to analyze the corrosion products. All alloys exhibited excellent corrosion resistance in the short term tests. For longer exposures, increasing the aluminum concentration was beneficial to the corrosion resistance. The addition of chromium to the binary iron aluminum alloy prevented the formation iron sulfide and resulted in lower corrosion kinetics. A classification of the corrosion products that developed on these alloys is presented. Scanning transmission electron microscopy (STEM) of the as-corroded coupons revealed that chromium was able to form chromium sulfides only on the higher aluminum alloy, thereby preventing the formation of deleterious iron sulfides. When the aluminum concentration was too low to permit selective oxidation of only aluminum (upon initial exposure to the corrosion environment), the formation of chromium oxide alongside the aluminum oxide led to depletion of chromium beneath the oxide layer. Upon penetration of sulfur through the oxide into this depletion layer, iron sulfides (rather than chromium sulfides) were found to form on the low aluminum alloy. Thus, it was found in this work that the role of chromium on alloy corrosion resistance was strongly effected by the aluminum concentration of the alloy. STEM analysis also revealed the encapsulation of external iron sulfide products with a thin layer of aluminum oxide, which may provide a

  4. Model-based Fuel Flow Control for Fossil-fired Power Plants

    DEFF Research Database (Denmark)

    Niemczyk, Piotr

    2010-01-01

    such sources may vary unpredictably meaning that the desired level of generation cannot always be achieved upon request. On-demand production from controllable units, such as thermal power plants, must change quickly in order to ensure balance between consumer demands and electricity generation. Coal-fired...... power plants represent the largest reserve of such controllable power sources in several countries. However, their production take-up rates are limited, mainly due to poor fuel flow control. The thesis presents analysis of difficulties and potential improvements in the control of the coal grinding...

  5. Bioethanol from poplar: a commercially viable alternative to fossil fuel in the European Union.

    Science.gov (United States)

    Littlewood, Jade; Guo, Miao; Boerjan, Wout; Murphy, Richard J

    2014-01-01

    The European Union has made it a strategic objective to develop its biofuels market in order to minimize greenhouse gas (GHG) emissions, to help mitigate climate change and to address energy insecurity within the transport sector. Despite targets set at national and supranational levels, lignocellulosic bioethanol production has yet to be widely commercialized in the European Union. Here, we use techno-economic modeling to compare the price of bioethanol produced from short rotation coppice (SRC) poplar feedstocks under two leading processing technologies in five European countries. Our evaluation shows that the type of processing technology and varying national costs between countries results in a wide range of bioethanol production prices (€0.275 to 0.727/l). The lowest production prices for bioethanol were found in countries that had cheap feedstock costs and high prices for renewable electricity. Taxes and other costs had a significant influence on fuel prices at the petrol station, and therefore the presence and amount of government support for bioethanol was a major factor determining the competitiveness of bioethanol with conventional fuel. In a forward-looking scenario, genetically engineering poplar with a reduced lignin content showed potential to enhance the competitiveness of bioethanol with conventional fuel by reducing overall costs by approximately 41% in four out of the five countries modeled. However, the possible wider phenotypic traits of advanced poplars needs to be fully investigated to ensure that these do not unintentionally negate the cost savings indicated. Through these evaluations, we highlight the key bottlenecks within the bioethanol supply chain from the standpoint of various stakeholders. For producers, technologies that are best suited to the specific feedstock composition and national policies should be optimized. For policymakers, support schemes that benefit emerging bioethanol producers and allow renewable fuel to be

  6. Fuel particles for high temperature reactors; Combustibles a particules pour reacteurs a haute temperature

    Energy Technology Data Exchange (ETDEWEB)

    Pheip, M. [CEA Cadarache (DEN/CAD/DEC/SESC/LIPA), 13 - Saint Paul lez Durance (France). Dept. d' Etudes des Combustibles; Masson, M. [CEA Valrho, Dept. Radiochimie et Procedes, 30 (France); Perrais, Ch. [CEA Cadarache (DEN/DEC/SPUA), 13 - Saint Paul lez Durance (France). Dept. d' Etudes des Combustibles; Pelletier, M. [CEA Cadarache (DEN/DEC/SESC), 13 - Saint Paul lez Durance (France). Dept. d' Etudes des Combustibles

    2007-07-15

    The concept of fuel particles with a millimeter size was born at the end of the 1950's and is the reference concept of high or very high temperature gas-cooled reactors (HTR/VHTR). The specificity of this fuel concerns its fine divided structure, its all-ceramic composition and its micro-confining properties with respect to fission products. These 3 properties when combined together allow the access to high temperatures and to a high level of safety. This article presents: 1 - the general properties of particle fuels; 2 - the fabrication and control of fuel elements: nuclei elaboration processes, vapor deposition coating of nuclei, shaping of fuel elements, quality control of fabrication; 3 - the fuel particles behaviour under irradiation: mechanical and thermal behaviour, behaviour and diffusion of fission products, ruining mode; 4 - the reprocessing of particle fuels: stakes and options, direct storage, separation of constituents, processing of carbonous wastes; 5 - conclusion. (J.S.)

  7. A possible temperature measurement model for fuel cell

    Science.gov (United States)

    Yu, Qiaoling; Zhang, Pu; Mao, Wenping; Liu, Wenzhong

    2017-11-01

    In this paper, an improved temperature measuring model for fuel cell temperature measurement is proposed based on the existed nanothermometer model, which is regarded as traditional temperature measuring model. With more realistic cases taken into consideration, the results of the improved model are more practical and accurate compared with the traditional one. Limited by the existed experimental conditions, this paper emphases on simulating the different conditions of the temperature distribution inside SOFC. As a result, the experiments are carried out with similar temperature distribution but under relatively lower temperatures, which can come to similar conclusions as by simulation.

  8. High Temperature Fuel Cladding Chemical Interactions Between TRIGA Fuels and 304 Stainless Steel

    Energy Technology Data Exchange (ETDEWEB)

    Perez, Emmanuel [Idaho National Lab. (INL), Idaho Falls, ID (United States); Keiser, Jr., Dennis D. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Forsmann, Bryan [Boise State Univ., ID (United States); Janney, Dawn E. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Henley, Jody [Idaho National Lab. (INL), Idaho Falls, ID (United States); Woolstenhulme, Eric C. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-02-01

    High-temperature fuel-cladding chemical interactions (FCCI) between TRIGA (Training, Research, Isotopes, General Atomics) fuel elements and the 304 stainless steel (304SS) are of interest to develop an understanding of the fuel behavior during transient reactor scenarios. TRIGA fuels are composed of uranium (U) particles dispersed in a zirconium-hydride (Zr-H) matrix. In reactor, the fuel is encased in 304-stainless-steel (304SS) or Incoloy 800 clad tubes. At high temperatures, the fuel can readily interact with the cladding, resulting in FCCI. A number of FCCI can take place in this system. Interactions can be expected between the cladding and the Zr-H matrix, and/or between the cladding and the U-particles. Other interactions may be expected between the Zr-H matrix and the U-particles. Furthermore, the fuel contains erbium-oxide (Er-O) additions. Interactions can also be expected between the Er-O, the cladding, the Zr-H and the U-particles. The overall result is that very complex interactions may take place as a result of fuel and cladding exposures to high temperatures. This report discusses the characterization of the baseline fuel microstructure in the as-received state (prior to exposure to high temperature), characterization of the fuel after annealing at 950C for 24 hours and the results from diffusion couple experiments carries out at 1000C for 5 and 24 hours. Characterization was carried out via scanning electron microscopy (SEM) and transmission electron microscopy (TEM) with sample preparation via focused ion beam in situ-liftout-technique.

  9. Particulate emission factors for mobile fossil fuel and biomass combustion sources.

    Science.gov (United States)

    Watson, John G; Chow, Judith C; Chen, L-W Antony; Lowenthal, Douglas H; Fujita, Eric M; Kuhns, Hampden D; Sodeman, David A; Campbell, David E; Moosmüller, Hans; Zhu, Dongzi; Motallebi, Nehzat

    2011-05-15

    PM emission factors (EFs) for gasoline- and diesel-fueled vehicles and biomass combustion were measured in several recent studies. In the Gas/Diesel Split Study (GD-Split), PM(2.5) EFs for heavy-duty diesel vehicles (HDDV) ranged from 0.2 to ~2 g/mile and increased with vehicle age. EFs for HDDV estimated with the U.S. EPA MOBILE 6.2 and California Air Resources Board (ARB) EMFAC2007 models correlated well with measured values. PM(2.5) EFs measured for gasoline vehicles were ~two orders of magnitude lower than those for HDDV and did not correlate with model estimates. In the Kansas City Study, PM(2.5) EFs for gasoline-powered vehicles (e.g., passenger cars and light trucks) were generally vehicles ranged from 0.18±0.03 and 1.20±0.12 g/kg fuel, corresponding to 0.3 and 2 g/mile, respectively. These values are comparable to those of on-road HDDV. EFs for biomass burning measured during the Fire Laboratory at Missoula Experiment (FLAME) were compared with EFs from the ARB Emission Estimation System (EES) model. The highest PM(2.5) EFs (76.8±37.5 g/kg) were measured for wet (>50% moisture content) Ponderosa Pine needles. EFs were generally 40%. Average EFs for dry chamise, rice straw, and dry grass were within a factor of three of values adopted by ARB in California's San Joaquin Valley (SJV). Discrepancies between measured and modeled emission factors suggest that there may be important uncertainties in current PM(2.5) emission inventories. Copyright © 2011 Elsevier B.V. All rights reserved.

  10. TASK 3.4--IMPACTS OF COFIRING BIOMASS WITH FOSSIL FUELS

    Energy Technology Data Exchange (ETDEWEB)

    Christopher J. Zygarlicke; Donald P. McCollor; Kurt E. Eylands; Melanie D. Hetland; Mark A. Musich; Charlene R. Crocker; Jonas Dahl; Stacie Laducer

    2001-08-01

    With a major worldwide effort now ongoing to reduce greenhouse gas emissions, cofiring of renewable biomass fuels at conventional coal-fired utilities is seen as one of the lower-cost options to achieve such reductions. The Energy & Environmental Research Center has undertaken a fundamental study to address the viability of cofiring biomass with coal in a pulverized coal (pc)-fired boiler for power production. Wheat straw, alfalfa stems, and hybrid poplar were selected as candidate biomass materials for blending at a 20 wt% level with an Illinois bituminous coal and an Absaloka subbituminous coal. The biomass materials were found to be easily processed by shredding and pulverizing to a size suitable for cofiring with pc in a bench-scale downfired furnace. A literature investigation was undertaken on mineral uptake and storage by plants considered for biomass cofiring in order to understand the modes of occurrence of inorganic elements in plant matter. Sixteen essential elements, C, H, O, N, P, K, Ca, Mg, S, Zn, Cu, Fe, Mn, B, Mo, and Cl, are found throughout plants. The predominant inorganic elements are K and Ca, which are essential to the function of all plant cells and will, therefore, be evenly distributed throughout the nonreproductive, aerial portions of herbaceous biomass. Some inorganic constituents, e.g., N, P, Ca, and Cl, are organically associated and incorporated into the structure of the plant. Cell vacuoles are the repository for excess ions in the plant. Minerals deposited in these ubiquitous organelles are expected to be most easily leached from dry material. Other elements may not have specific functions within the plant, but are nevertheless absorbed and fill a need, such as silica. Other elements, such as Na, are nonessential, but are deposited throughout the plant. Their concentration will depend entirely on extrinsic factors regulating their availability in the soil solution, i.e., moisture and soil content. Similarly, Cl content is determined

  11. The Model of Temperature Dynamics of Pulsed Fuel Assembly

    CERN Document Server

    Bondarchenko, E A; Popov, A K

    2002-01-01

    Heat exchange process differential equations are considered for a subcritical fuel assembly with an injector. The equations are obtained by means of the use of the Hermit polynomial. The model is created for modelling of temperature transitional processes. The parameters and dynamics are estimated for hypothetical fuel assembly consisting of real mountings: the powerful proton accelerator and the reactor IBR-2 core at its subcritica l state.

  12. 400 W High Temperature PEM Fuel Cell Stack Test

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2006-01-01

    This work demonstrates the operation of a 30 cell high temperature PEM (HTPEM) fuel cell stack. This prototype stack has been developed at the Institute of Energy Technology, Aalborg University, as a proof-of-concept for a low pressure cathode air cooled HTPEM stack. The membranes used are Celtec P...... of the species as in a LTPEM fuel cell system. The use of the HTPEM fuel cell makes it possible to use reformed gas at high CO concentrations, still with a stable efficient performance....

  13. Observationally based surface fluxes of CH4 and N2O, and fossil fuel-derived CO2 for a 300x100 km region (the Netherlands)

    Science.gov (United States)

    Laan, S. V.; Karstens, U.; Neubert, R.; Laan-Luijkx, I. V.; Meijer, H. A.

    2010-12-01

    Fossil fuel-derived CO2 (FFCO2), CH4 and N2O are the most important anthropogenic greenhouse gases that are held responsible for most of the observed increase in global surface temperature. Currently, their mixing ratios are monitored very accurately and with high precision at many stations around the world. However, quantitative knowledge about their sources and sinks on relative small temporal and spatial scales is still not satisfactory. This makes it also difficult to independently validate the emission reductions as reported by countries who are committed to internationally agreed reduction targets. The reported emissions are based on statistical methods and inventories of known sources and sinks. This method, however, relies heavily on the availability and correctness of the data and can be biased if relevant information is missing (or wrong). We use a customized version of the 222Radon-flux approach to determine regional fluxes of FFCO2, CH4 and N2O from their mixing ratios and 222Rn concentrations observed at station Lutjewad in the Netherlands. The radioactive noble gas 222Rn is used as a tracer for atmospheric mixing and dilution. After surface emanation 222Rn experiences the same atmospheric mixing and dilution as any other constituent released from, or close to, the surface. A coefficient is determined from the ratio of the 222Rn concentrations to the 222Rn soil flux (assumed to be well-known) and applied to calculate surface fluxes from the mixing ratios of (e.g.) FFCO2, CH4 and N2O, sampled at the same height. The mixing ratios of FFCO2 are determined from CO mixing ratios, calibrated with 14CO2 measurements. Since CO2 from fossil fuels does not contain any 14C, and the sources of CO are closely linked to that of FFCO2, a high temporal resolution proxy record can be made from which surface fluxes can be calculated. A back trajectory model is used to select emissions representative for the Netherlands and to distinguish between local sources and those

  14. Assessing Uncertainties in Gridded Emissions: A Case Study for Fossil Fuel Carbon Dioxide (FFCO2) Emission Data

    Science.gov (United States)

    Oda, T.; Ott, L.; Lauvaux, T.; Feng, S.; Bun, R.; Roman, M.; Baker, D. F.; Pawson, S.

    2017-01-01

    Fossil fuel carbon dioxide (CO2) emissions (FFCO2) are the largest input to the global carbon cycle on a decadal time scale. Because total emissions are assumed to be reasonably well constrained by fuel statistics, FFCO2 often serves as a reference in order to deduce carbon uptake by poorly understood terrestrial and ocean sinks. Conventional atmospheric CO2 flux inversions solve for spatially explicit regional sources and sinks and estimate land and ocean fluxes by subtracting FFCO2. Thus, errors in FFCO2 can propagate into the final inferred flux estimates. Gridded emissions are often based on disaggregation of emissions estimated at national or regional level. Although national and regional total FFCO2 are well known, gridded emission fields are subject to additional uncertainties due to the emission disaggregation. Assessing such uncertainties is often challenging because of the lack of physical measurements for evaluation. We first review difficulties in assessing uncertainties associated with gridded FFCO2 emission data and present several approaches for evaluation of such uncertainties at multiple scales. Given known limitations, inter-emission data differences are often used as a proxy for the uncertainty. The popular approach allows us to characterize differences in emissions, but does not allow us to fully quantify emission disaggregation biases. Our work aims to vicariously evaluate FFCO2 emission data using atmospheric models and measurements. We show a global simulation experiment where uncertainty estimates are propagated as an atmospheric tracer (uncertainty tracer) alongside CO2 in NASA's GEOS model and discuss implications of FFCO2 uncertainties in the context of flux inversions. We also demonstrate the use of high resolution urban CO2 simulations as a tool for objectively evaluating FFCO2 data over intense emission regions. Though this study focuses on FFCO2 emission data, the outcome of this study could also help improve the knowledge of similar

  15. Control of fossil-fuel particulate black carbon and organic matter, possibly the most effective method of slowing global warming

    Science.gov (United States)

    Jacobson, Mark Z.

    2002-10-01

    Under the 1997 Kyoto Protocol, no control of black carbon (BC) was considered. Here, it is found, through simulations in which 12 identifiable effects of aerosol particles on climate are treated, that any emission reduction of fossil-fuel (f.f.) particulate BC plus associated organic matter (OM) may slow global warming more than may any emission reduction of CO2 or CH4 for a specific period. When all f.f. BC + OM and anthropogenic CO2 and CH4 emissions are eliminated together, the period is 25-100 years. It is also estimated that historical net global warming can be attributed roughly to greenhouse gas plus f.f. BC + OM warming minus substantial cooling by other particles. Eliminating all f.f. BC + OM could eliminate 20-45% of net warming (8-18% of total warming before cooling is subtracted out) within 3-5 years if no other change occurred. Reducing CO2 emissions by a third would have the same effect, but after 50-200 years. Finally, diesel cars emitting continuously under the most recent U.S. and E.U. particulate standards (0.08 g/mi; 0.05 g/km) may warm climate per distance driven over the next 100+ years more than equivalent gasoline cars. Thus, fuel and carbon tax laws that favor diesel appear to promote global warming. Toughening vehicle particulate emission standards by a factor of 8 (0.01 g/mi; 0.006 g/km) does not change this conclusion, although it shortens the period over which diesel cars warm to 13-54 years. Although control of BC + OM can slow warming, control of greenhouse gases is necessary to stop warming. Reducing BC + OM will not only slow global warming but also improve human health.

  16. Technical benchmarking of fossil energy sources to regenerative substitute fuels for medium speed for-stroke diesel engines; Technisches Benchmark fossiler Energietraeger zu regenerativen Substitutbrennstoffen fuer mittelschnelllaufende 4-Takt Dieselgeneratoren

    Energy Technology Data Exchange (ETDEWEB)

    Schillings, Hubert

    2010-07-01

    Diesel engines were actually designed for fossil fuels. For this reason an operation with substitute fuels poses a special challenge. For example native oils/fats are elements comprising a range of more than 5000 chemically different substances. Each of these has individual characteristics which have to be considered during operation. Hence, an adapted operation is necessary. Typical damages include: 1. Cavitation pitting in the fuel injection system. 2. Precipitation of combustion residues in inlet and outlet. 3. Engine damages caused by lube oil dilution. 4. Engine damages caused by agglutination of lube oil. 5. Plugging of fuel conduit and filter systems caused by polymerization reactions. Practice has shown that the operational mode of engines are not generally reproducible. It is a fact that engines of the same type and manufacturer show a different operating performance. This is due to catalytic effects which can be traced back to the consistence of the material grade. Traditionally the material grades of these engines are designed for basic fuels. In contrast to that most of the substitute fuels (oils/fats) have distinctive acidic characteristics. The question in how far the catalytically active surfaces boost or avoid polymerization is part of current researches. (orig.)

  17. Fe-Al Weld Overlay and High Velocity Oxy-Fuel Thermal Spray Coatings for Corrosion Protection of Waterwalls in Fossil Fired Plants with Low NOx Burners

    Energy Technology Data Exchange (ETDEWEB)

    Regina, J.R.

    2002-02-08

    Iron-aluminum-chromium coatings were investigated to determine the best candidates for coatings of boiler tubes in Low NOx fossil fueled power plants. Ten iron-aluminum-chromium weld claddings with aluminum concentrations up to 10wt% were tested in a variety of environments to evaluate their high temperature corrosion resistance. The weld overlay claddings also contained titanium additions to investigate any beneficial effects from these ternary and quaternary alloying additions. Several High-Velocity Oxy-Fuel (HVOF) thermal spray coatings with higher aluminum concentrations were investigated as well. Gaseous corrosion testing revealed that at least 10wt%Al is required for protection in the range of environments examined. Chromium additions were beneficial in all of the environments, but additions of titanium were beneficial only in sulfur rich atmospheres. Similar results were observed when weld claddings were in contact with corrosive slag while simultaneously, exposed to the corrosive environments. An aluminum concentration of 10wt% was required to prevent large amounts of corrosion to take place. Again chromium additions were beneficial with the greatest corrosion protection occurring for welds containing both 10wt%Al and 5wt%Cr. The exposed thermal spray coatings showed either significant cracking within the coating, considerable thickness loss, or corrosion products at the coating substrate interface. Therefore, the thermal spray coatings provided the substrate very little protection. Overall, it was concluded that of the coatings studied weld overlay coatings provide superior protection in these Low NOx environments; specifically, the ternary weld composition of 10wt%Al and 5wt%Cr provided the best corrosion protection in all of the environments tested.

  18. Substitutability of Electricity and Renewable Materials for Fossil Fuels in a Post-Carbon Economy

    Directory of Open Access Journals (Sweden)

    Antonio García-Olivares

    2015-11-01

    Full Text Available A feasible way to avoid the risk of energy decline and combat climate change is to build a 100% renewable global energy mix. However, a globally electrified economy cannot grow much above 12 electric terawatts without putting pressure on the limits of finite mineral reserves. Here we analyze whether 12 TW of electricity and 1 TW of biomass (final power will be able to fuel a future post-carbon economy that can provide similar services to those of a contemporary economy. Contrarily to some pessimistic expectations, this analysis shows that the principle economic processes can be replaced with sustainable alternatives based on electricity, charcoal, biogas and hydrogen. Furthermore, those services that cannot be replaced are not as crucial so as to cause a return to a pre-industrial society. Even so, land transport and aviation are at the limit of what is sustainable, outdoor work should be reorganized, metal primary production should be based on hydrogen reduction when possible, mineral production should be increasingly based on recycling, the petrochemical industry should shrink to a size of 40%–43% of the 2012 petrochemical sector, i.e., a size similar to that the sector had in 1985–1986, and agriculture may require organic farming methods to be sustainable.

  19. Fossil fuel savings, carbon emission reduction and economic attractiveness of medium-scale integrated biomass gasification combined cycle cogeneration plants

    Directory of Open Access Journals (Sweden)

    Kalina Jacek

    2012-01-01

    Full Text Available The paper theoretically investigates the system made up of fluidized bed gasifier, SGT-100 gas turbine and bottoming steam cycle. Different configurations of the combined cycle plant are examined. A comparison is made between systems with producer gas (PG and natural gas (NG fired turbine. Supplementary firing of the PG in a heat recovery steam generator is also taken into account. The performance of the gas turbine is investigated using in-house built Engineering Equation Solver model. Steam cycle is modeled using GateCycleTM simulation software. The results are compared in terms of electric energy generation efficiency, CO2 emission and fossil fuel energy savings. Finally there is performed an economic analysis of a sample project. The results show relatively good performance in the both alternative configurations at different rates of supplementary firing. Furthermore, positive values of economic indices were obtained. [Acknowledgements. This work was carried out within the frame of research project no. N N513 004036, titled: Analysis and optimization of distributed energy conversion plants integrated with gasification of biomass. The project is financed by the Polish Ministry of Science.

  20. Conclusions drawn from actions implemented within the first stage of the Cracow program of energy conservation and clean fossil fuels

    Energy Technology Data Exchange (ETDEWEB)

    Bieda, J.; Bardel, J.; Pierce, B.

    1995-12-31

    Since 1992 Brookhaven National Laboratory (BNL) and Pacific Northwest Laboratory (PNL), acting on behalf of the U.S. Department of Energy, executed the first stage of the Cracow Program of Energy Conservation and Clean Fossil Fuels, called also American-Polish Program of Actions for Elimination of Low Emission Sources in Cracow. The main contractor for BNL and PNL was the Cracow Development Office (BRK). The interest in improving the condition of Cracow air results from the fact that the standard for permissible air pollution was exceeded several times in Cracow and especially within the central part of the town. Therefore, air pollution appeared one of the most important problems that faced the municipal authorities. It followed from monitoring investigations that the high level of air pollutant concentration is caused by in-home coal-fired tile stoves operated in winter seasons and by coal- and coke-fired boiler houses simulated mainly in the central part of the town. The results obtained in first stage are presented. This paper is an attempt to formulate conclusions drawn from these works and recommendations with regard to the future policy of the town authorities; selected results are presented to clarify or illustrate the conclusions.

  1. China: Emissions pattern of the world leader in CO2 emissions from fossil fuel consumption and cement production

    Energy Technology Data Exchange (ETDEWEB)

    Gregg, J [University of Maryland; Andres, Robert Joseph [ORNL; Marland, Gregg [ORNL

    2008-01-01

    Release of carbon dioxide (CO2) from fossil fuel combustion and cement manufacture is the primary anthropogenic driver of climate change. Our best estimate is that China became the largest national source of CO2 emissions during 2006. Previously, the United States (US) had occupied that position. However, the annual emission rate in the US has remained relatively stable between 2001-2006 while the emission rate in China has more than doubled, apparently eclipsing that of the US in late 2006. Here we present the seasonal and spatial pattern of CO2 emissions in China, as well as the sectoral breakdown of emissions. Though our best point estimate places China in the lead position in terms of CO2 emissions, we qualify this statement in a discussion of the uncertainty in the underlying data (3-5% for the US; 15-20% for China). Finally, we comment briefly on the implications of China's new position with respect to international agreements to mitigate climate change.

  2. Is There a Future for Nuclear Power? Wind and Emission Reduction Targets in Fossil-Fuel Alberta.

    Science.gov (United States)

    van Kooten, G Cornelis; Duan, Jun; Lynch, Rachel

    2016-01-01

    This paper explores the viability of relying on wind power to replace upwards of 60% of electricity generation in Alberta that would be lost if coal-fired generation is phased out. Using hourly wind data from 17 locations across Alberta, we are able to simulate the potential wind power output available to the Alberta grid when modern, 3.5 MW-capacity wind turbines are spread across the province. Using wind regimes for the years 2006 through 2015, we find that available wind power is less than 60% of installed capacity 98% of the time, and below 30% of capacity 74% of the time. There is only a small amount of correlation between wind speeds at different locations, but yet it remains necessary to rely on fossil fuel generation. Then, based on the results from a grid allocation model, we find that CO2 emissions can be reduced by about 30%, but only through a combination of investment in wind energy and reliance on purchases of hydropower from British Columbia. Only if nuclear energy is permitted into the generation mix would Alberta be able to meet its CO2-emissions reduction target in the electricity sector. With nuclear power, emissions can be reduced by upwards of 85%.

  3. High temperature polymer fuel cells and their Interplay with fuel processing systems

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Qingfeng, Li; He, R.

    2003-01-01

    This paper reports recent results from our group on polymer electrolyte membrane fuel cells (PEMFC) based on the temperature resistant polymer polybenzimidazole (PBI), which allow working temperatures up to 200°C. The membrane has a water drag number near zero and need no water management at all....... The high working temperature allows for utilization of the excess heat for fuel processing. Moreover, it provides an excellent CO tolerance of several percent, and the system needs no purification of hydrogen from a reformer. Continuous service for over 6 months at 150°C has been demonstrated....

  4. Structural Path Analysis of Fossil Fuel Based CO2 Emissions: A Case Study for China.

    Science.gov (United States)

    Yang, Zhiyong; Dong, Wenjie; Xiu, Jinfeng; Dai, Rufeng; Chou, Jieming

    2015-01-01

    Environmentally extended input-output analysis (EEIOA) has long been used to quantify global and regional environmental impacts and to clarify emission transfers. Structural path analysis (SPA), a technique based on EEIOA, is especially useful for measuring significant flows in this environmental-economic system. This paper constructs an imports-adjusted single-region input-output (SRIO) model considering only domestic final use elements, and it uses the SPA technique to highlight crucial routes along the production chain in both final use and sectoral perspectives. The results indicate that future mitigation policies on household consumption should change direct energy use structures in rural areas, cut unreasonable demand for power and chemical products, and focus on urban areas due to their consistently higher magnitudes than rural areas in the structural routes. Impacts originating from government spending should be tackled by managing onsite energy use in 3 major service sectors and promoting cleaner fuels and energy-saving techniques in the transport sector. Policies on investment should concentrate on sectoral interrelationships along the production chain by setting up standards to regulate upstream industries, especially for the services, construction and equipment manufacturing sectors, which have high demand pulling effects. Apart from the similar methods above, mitigating policies in exports should also consider improving embodied technology and quality in manufactured products to achieve sustainable development. Additionally, detailed sectoral results in the coal extraction industry highlight the onsite energy use management in large domestic companies, emphasize energy structure rearrangement, and indicate resources and energy safety issues. Conclusions based on the construction and public administration sectors reveal that future mitigation in secondary and tertiary industries should be combined with upstream emission intensive industries in a

  5. Krakow clean fossil fuels and energy efficiency program. Phase 1 report

    Energy Technology Data Exchange (ETDEWEB)

    Butcher, T.; Pierce, B. [eds.

    1995-06-01

    Krakow is one of the largest and oldest cities in Poland. It is situated in the south of the country on the banks of the Vistula River. From the 11th until the 17th centuries, it was the capital of Poland. Today, Krakow is a city of 750,000 residents, one of the largest centers of higher education, an important industrial center, and is of particular importance because of the number and kinds of historic buildings and sites. For this reason, Krakow was included by the UNESCO in the list of the world`s cultural heritages. For about three decades, significant air pollution has been one of Krakow`s most serious problems. Because the city is situated in the Vistula River valley, it is poorly ventilated and experiences a high concentration of air pollutants. The quality of air in Krakow is affected mainly by industry (Sendzimir Steelworks, energy industry, chemical plants), influx from the Silesian industrial region (power plants, metallurgy), transboundary pollution (Ostrava - Czech Republic), and local sources of low pollution, i.e. more than 1,000 boiler houses using solid fuels and more than 100,000 coal-fired home stoves. These local sources, with low stacks and almost no pollution-control equipment, are responsible for about 35-40% of the air pollution. This report presents phase I results of a program to reduce pollution in krakow. Phase I was to gather information on emissions and costs, and to verify assumptions on existing heating methods and alternatives.

  6. Structural Path Analysis of Fossil Fuel Based CO2 Emissions: A Case Study for China.

    Directory of Open Access Journals (Sweden)

    Zhiyong Yang

    Full Text Available Environmentally extended input-output analysis (EEIOA has long been used to quantify global and regional environmental impacts and to clarify emission transfers. Structural path analysis (SPA, a technique based on EEIOA, is especially useful for measuring significant flows in this environmental-economic system. This paper constructs an imports-adjusted single-region input-output (SRIO model considering only domestic final use elements, and it uses the SPA technique to highlight crucial routes along the production chain in both final use and sectoral perspectives. The results indicate that future mitigation policies on household consumption should change direct energy use structures in rural areas, cut unreasonable demand for power and chemical products, and focus on urban areas due to their consistently higher magnitudes than rural areas in the structural routes. Impacts originating from government spending should be tackled by managing onsite energy use in 3 major service sectors and promoting cleaner fuels and energy-saving techniques in the transport sector. Policies on investment should concentrate on sectoral interrelationships along the production chain by setting up standards to regulate upstream industries, especially for the services, construction and equipment manufacturing sectors, which have high demand pulling effects. Apart from the similar methods above, mitigating policies in exports should also consider improving embodied technology and quality in manufactured products to achieve sustainable development. Additionally, detailed sectoral results in the coal extraction industry highlight the onsite energy use management in large domestic companies, emphasize energy structure rearrangement, and indicate resources and energy safety issues. Conclusions based on the construction and public administration sectors reveal that future mitigation in secondary and tertiary industries should be combined with upstream emission intensive

  7. Year-round Source Contributions of Fossil Fuel and Biomass Combustion to Elemental Carbon on the North Slope Alaska Utilizing Radiocarbon Analysis

    Science.gov (United States)

    Barrett, T. E.; Gustafsson, O.; Winiger, P.; Moffett, C.; Back, J.; Sheesley, R. J.

    2015-12-01

    It is well documented that the Arctic has undergone rapid warming at an alarming rate over the past century. Black carbon (BC) affects the radiative balance of the Arctic directly and indirectly through the absorption of incoming solar radiation and by providing a source of cloud and ice condensation nuclei. Among atmospheric aerosols, BC is the most efficient absorber of light in the visible spectrum. The solar absorbing efficiency of BC is amplified when it is internally mixed with sulfates. Furthermore, BC plumes that are fossil fuel dominated have been shown to be approximately 100% more efficient warming agents than biomass burning dominated plumes. The renewal of offshore oil and gas exploration in the Arctic, specifically in the Chukchi Sea, will introduce new BC sources to the region. This study focuses on the quantification of fossil fuel and biomass combustion sources to atmospheric elemental carbon (EC) during a year-long sampling campaign in the North Slope Alaska. Samples were collected at the Department of Energy Atmospheric Radiation Measurement (ARM) climate research facility in Barrow, AK, USA. Particulate matter (PM10) samples collected from July 2012 to June 2013 were analyzed for EC and sulfate concentrations combined with radiocarbon (14C) analysis of the EC fraction. Radiocarbon analysis distinguishes fossil fuel and biomass burning contributions based on large differences in end members between fossil and contemporary carbon. To perform isotope analysis on EC, it must be separated from the organic carbon fraction of the sample. Separation was achieved by trapping evolved CO2 produced during EC combustion in a cryo-trap utilizing liquid nitrogen. Radiocarbon results show an average fossil contribution of 85% to atmospheric EC, with individual samples ranging from 47% to 95%. Source apportionment results will be combined with back trajectory (BT) analysis to assess geographic source region impacts on the EC burden in the western Arctic.

  8. Estimation of the fossil fuel component in atmospheric CO2 based on radiocarbon measurements at the Beromünster tall tower, Switzerland

    Science.gov (United States)

    Berhanu, Tesfaye A.; Szidat, Sönke; Brunner, Dominik; Satar, Ece; Schanda, Rüdiger; Nyfeler, Peter; Battaglia, Michael; Steinbacher, Martin; Hammer, Samuel; Leuenberger, Markus

    2017-09-01

    Fossil fuel CO2 (CO2ff) is the major contributor of anthropogenic CO2 in the atmosphere, and accurate quantification is essential to better understand the carbon cycle. Since October 2012, we have been continuously measuring the mixing ratios of CO, CO2, CH4, and H2O at five different heights at the Beromünster tall tower, Switzerland. Air samples for radiocarbon (Δ14CO2) analysis have also been collected from the highest sampling inlet (212.5 m) of the tower on a biweekly basis. A correction was applied for 14CO2 emissions from nearby nuclear power plants (NPPs), which have been simulated with the Lagrangian transport model FLEXPART-COSMO. The 14CO2 emissions from NPPs offset the depletion in 14C by fossil fuel emissions, resulting in an underestimation of the fossil fuel component in atmospheric CO2 by about 16 %. An average observed ratio (RCO) of 13.4 ± 1.3 mmol mol-1 was calculated from the enhancements in CO mixing ratios relative to the clean-air reference site Jungfraujoch (ΔCO) and the radiocarbon-based fossil fuel CO2 mole fractions. The wintertime RCO estimate of 12.5 ± 3.3 is about 30 % higher than the wintertime ratio between in situ measured CO and CO2 enhancements at Beromünster over the Jungfraujoch background (8.7 mmol mol-1) corrected for non-fossil contributions due to strong biospheric contribution despite the strong correlation between ΔCO and ΔCO2 in winter. By combining the ratio derived using the radiocarbon measurements and the in situ measured CO mixing ratios, a high-resolution time series of CO2ff was calculated exhibiting a clear seasonality driven by seasonal variability in emissions and vertical mixing. By subtracting the fossil fuel component and the large-scale background, we have determined the regional biospheric CO2 component that is characterized by seasonal variations ranging between -15 and +30 ppm. A pronounced diurnal variation was observed during summer modulated by biospheric exchange and vertical mixing, while no

  9. Estimates of global, regional, and national annual CO{sub 2} emissions from fossil-fuel burning, hydraulic cement production, and gas flaring: 1950--1992

    Energy Technology Data Exchange (ETDEWEB)

    Boden, T.A.; Marland, G. [Oak Ridge National Lab., TN (United States); Andres, R.J. [University of Alaska, Fairbanks, AK (United States). Inst. of Northern Engineering

    1995-12-01

    This document describes the compilation, content, and format of the most comprehensive C0{sub 2}-emissions database currently available. The database includes global, regional, and national annual estimates of C0{sub 2} emissions resulting from fossil-fuel burning, cement manufacturing, and gas flaring in oil fields for 1950--92 as well as the energy production, consumption, and trade data used for these estimates. The methods of Marland and Rotty (1983) are used to calculate these emission estimates. For the first time, the methods and data used to calculate CO, emissions from gas flaring are presented. This C0{sub 2}-emissions database is useful for carbon-cycle research, provides estimates of the rate at which fossil-fuel combustion has released C0{sub 2} to the atmosphere, and offers baseline estimates for those countries compiling 1990 C0{sub 2}-emissions inventories.

  10. Carbon Capture and Water Emissions Treatment System (CCWESTRS) at Fossil-Fueled Electric Generating Plants

    Energy Technology Data Exchange (ETDEWEB)

    P. Alan Mays; Bert R. Bock; Gregory A. Brodie; L. Suzanne Fisher; J. Devereux Joslin; Donald L. Kachelman; Jimmy J. Maddox; N. S. Nicholas; Larry E. Shelton; Nick Taylor; Mark H. Wolfe; Dennis H. Yankee; John Goodrich-Mahoney

    2005-08-30

    The Tennessee Valley Authority (TVA), the Electric Power Research Institute (EPRI), and the Department of Energy-National Energy Technologies Laboratory (DOE-NETL) are evaluating and demonstrating integration of terrestrial carbon sequestration techniques at a coal-fired electric power plant through the use of Flue Gas Desulfurization (FGD) system gypsum as a soil amendment and mulch, and coal fly ash pond process water for periodic irrigation. From January to March 2002, the Project Team initiated the construction of a 40 ha Carbon Capture and Water Emissions Treatment System (CCWESTRS) near TVA's Paradise Fossil Plant on marginally reclaimed surface coal mine lands in Kentucky. The CCWESTRS is growing commercial grade trees and cover crops and is expected to sequester 1.5-2.0 MT/ha carbon per year over a 20-year period. The concept could be used to meet a portion of the timber industry's needs while simultaneously sequestering carbon in lands which would otherwise remain non-productive. The CCWESTRS includes a constructed wetland to enhance the ability to sequester carbon and to remove any nutrients and metals present in the coal fly ash process water runoff. The CCWESTRS project is a cooperative effort between TVA, EPRI, and DOE-NETL, with a total budget of $1,574,000. The proposed demonstration project began in October 2000 and has continued through December 2005. Additional funding is being sought in order to extend the project. The primary goal of the project is to determine if integrating power plant processes with carbon sequestration techniques will enhance carbon sequestration cost-effectively. This goal is consistent with DOE objectives to provide economically competitive and environmentally safe options to offset projected growth in U.S. baseline emissions of greenhouse gases after 2010, achieve the long-term goal of $10/ton of avoided net costs for carbon sequestration, and provide half of the required reductions in global greenhouse gases by

  11. Low temperature direct propane polymer electrolyte membranes fuel cell (DPFC)

    Energy Technology Data Exchange (ETDEWEB)

    Savadogo, O.; Varela, F. J. R. [Ecole Polytechnique, Laboratoire d' electrochimie et de materiaux energetiques, Montreal, PQ (Canada)

    2001-04-01

    A low-temperature direct propane polymer electrolyte membrane fuel cell (DPFC) is demonstrated. The propane is fed into the fuel cell directly, eliminating the need for reforming. The key elements of the DPFC system are an appropriate catalyst for the anodes, an appropriate membrane and a propane humidifier. Overall, the system consists of a propane container, an oxygen container, a propane humidifier, and oxygen humidifier, a proton exchange membrane fuel cell (PEMFC), and a fuel cell station monitored by a computer. The membranes are Nafion 117, doped with heteropolyacids (HPAs) or polybenzimidazole (PBI). The fuel cell was built of graphite blocks in which flow fields were engraved, one for humidified propane, the other for oxygen. The anode was based on platinum, platinum-ruthenium, or platinum-chromium oxide electrocatalysts; the cathode was based on a platinum electrocatalyst. Results showed that polymer electrolyte membranes can be directly fed by propane gas to make direct propane fuel cell (DPFC). This has many advantages compared to methanol, such as lower cost, greater operating temperature range, easy handling, simpler infrastructure requirements, and higher energy than those of methanol. However, like methanol, DPFC also has the disadvantage that its reaction product is carbon dioxide. 22 refs., 2 tabs., 5 figs.

  12. Battery-free Wireless Sensor Network For Advanced Fossil-Fuel Based Power Generation

    Energy Technology Data Exchange (ETDEWEB)

    Yi Jia

    2011-02-28

    This report summarizes technical progress achieved during the project supported by the Department of Energy under Award Number DE-FG26-07NT4306. The aim of the project was to conduct basic research into battery-free wireless sensing mechanism in order to develop novel wireless sensors and sensor network for physical and chemical parameter monitoring in a harsh environment. Passive wireless sensing platform and five wireless sensors including temperature sensor, pressure sensor, humidity sensor, crack sensor and networked sensors developed and demonstrated in our laboratory setup have achieved the objective for the monitoring of various physical and chemical parameters in a harsh environment through remote power and wireless sensor communication, which is critical to intelligent control of advanced power generation system. This report is organized by the sensors developed as detailed in each progress report.

  13. Simultaneously saccharification and fermentation approach as a tool for enhanced fossil fuels biodesulfurization.

    Science.gov (United States)

    Paixão, Susana M; Arez, Bruno F; Roseiro, José C; Alves, Luís

    2016-11-01

    Biodesulfurization can be a complementary technology to the hydrodesulfurization, the commonly physical-chemical process used for sulfur removal from crude oil. The desulfurizing bacterium Gordonia alkanivorans strain 1B as a fructophilic microorganism requires fructose as C-source. In this context, the main goal of this work was the optimization of a simultaneous saccharification and fermentation (SSF) approach using the Zygosaccharomyces bailii strain Talf1 crude enzymes with invertase activity and sucrose as a cheaper fructose-rich commercial C-source (50% fructose) towards dibenzothiophene (DBT) desulfurization by strain 1B. The determination of optimal conditions, for both sucrose hydrolysis and DBT desulfurization was carried out through two sequential experimental uniform designs according to the Doehlert distribution for two factors: pH (5.5-7.5) and temperature (28-38 °C), with the enzyme load of 1.16 U/g/L; and enzyme load (0-4 U/g/L) and temperature (28-38 °C), with pH at 7.5. Based on 2-hydroxybiphenyl production, the analysis of the response surfaces obtained pointed out for pH 7.5, 32 °C and 1.8 U/g/L as optimal conditions. Further optimized SSF of sucrose during the DBT desulfurization process permitted to attain a 4-fold enhanced biodesulfurization. This study opens a new focus of research through the exploitation of sustainable low cost sucrose-rich feedstocks towards a more economical viable bioprocess scale-up. Copyright © 2016 Elsevier Ltd. All rights reserved.

  14. Direct dimethyl ether high temperature polymer electrolyte membrane fuel cells

    DEFF Research Database (Denmark)

    Vassiliev, Anton; Jensen, Jens Oluf; Li, Qingfeng

    A high temperature polybenzimidazole (PBI) polymer fuel cell was fed with dimethyl ether (DME) and water vapour mixture on the anode at ambient pressure with air as oxidant. A peak power density of 79 mW/cm2 was achieved at 200°C. A conventional polymer based direct DME fuel cell is liquid fed an......V higher than that of methanol, indicating less fuel crossover.......A high temperature polybenzimidazole (PBI) polymer fuel cell was fed with dimethyl ether (DME) and water vapour mixture on the anode at ambient pressure with air as oxidant. A peak power density of 79 mW/cm2 was achieved at 200°C. A conventional polymer based direct DME fuel cell is liquid fed...... and suffers from low DME solubility in water. When the DME - water mixture is fed as vapour miscibility is no longer a problem. The increased temperature is more beneficial for the kinetics of the direct oxidation of DME than of methanol. The Open Circuit Voltage (OCV) with DME operation was 50 to 100 m...

  15. Dynamic Model of the High Temperature Proton Exchange Membrane Fuel Cell Stack Temperature

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Kær, Søren Knudsen

    2009-01-01

    The present work involves the development of a model for predicting the dynamic temperature of a high temperature proton exchange membrane (HTPEM) fuel cell stack. The model is developed to test different thermal control strategies before implementing them in the actual system. The test system...... is managed by running the stack at a high stoichiometric air flow. This is possible because of the polybenzimidazole (PBI) fuel cell membranes used and the very low pressure drop in the stack. The model consists of a discrete thermal model dividing the stack into three parts: inlet, middle, and end....... The temperature is predicted in these three parts, where they also are measured. The heat balance of the system involves a fuel cell model to describe the heat added by the fuel cells when a current is drawn. Furthermore the model also predicts the temperatures when heating the stack with external heating...

  16. Intelligent system of aid for the starting of fossil fuel units; Sistema inteligente de ayuda para el arranque de unidades termoelectricas

    Energy Technology Data Exchange (ETDEWEB)

    Suarez Cerda, Dionisio A; Ibargueengoytia Gonzalez, Pablo H; Villavicencio Ramirez, Alejandro [Instituto de Investigaciones Electricas, Temixco, Morelos (Mexico)

    1999-07-01

    In this article the aid system for the starting of fossil fuel units is described (SIAAT) based on techniques of artificial intelligence, that the Management of Supervision of Processes of the Instituto de Investigaciones Electricas (IIE) develops. It analyzes the problem of the starting of fossil fuel units, which sets out to solve through computer techniques based on artificial intelligence. The system architecture is proposed and the challenges that are due to face are mentioned so that the system works in line with the process and along with it. In addition to the technical aspects covered in the project, the more relevant results that make an impact in the expectations of application of the system are mentioned, as well as the expected benefits of its use in fossil fuel power stations. [Spanish] En este articulo se describe el Sistema de ayuda para el Arranque de Unidades Termoelectricas (SIAAT) basado en tecnicas de inteligencia artificial, que desarrolla la Gerencia de Supervision de Procesos del Instituto de Investigaciones Electricas (IIE). Se analiza el problema del arranque de unidades termoelectricas, el cual se propone resolver a traves de tecnicas computacionales basadas en inteligencia artificial. Se presenta la arquitectura del sistema y se mencionan los retos que se deben enfrentar para que el sistema funcione en linea junto con el proceso. Ademas de los aspectos tecnicos abordados en el proyecto, se mencionan los resultados mas relevantes que impactan en las expectativas de aplicacion del sistema, asi como los beneficios esperados de su uso en centrales termoelectricas.

  17. {Delta}{sup 14}C level of annual plants and fossil fuel derived CO{sub 2} distribution across different regions of China

    Energy Technology Data Exchange (ETDEWEB)

    Xi, X.T.; Ding, X.F.; Fu, D.P. [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China); Zhou, L.P. [Laboratory for Earth Surface Processes, Department of Geography, Peking University, Beijing 100871 (China); Liu, K.X., E-mail: kxliu@pku.edu.cn [State Key Laboratory of Nuclear Physics and Technology and Institute of Heavy Ion Physics, School of Physics, Peking University, Beijing 100871 (China)

    2013-01-15

    The {sup 14}C level in annual plants is a sensitive tracer for monitoring fossil fuel derived CO{sub 2} in the atmosphere. Corn leave samples were selected from different regions of China, including high mountains in the Tibetan Plateau, grassland in Inner Mongolia, and inland and coastal cities during the summer of 2010. The {sup 14}C/{sup 12}C ratio of the samples was measured with the NEC compact AMS system at the Institute of Heavy Ion Physics, Peking University. The fossil fuel derived CO{sub 2} was estimated by comparing the measured {Delta}{sup 14}C values of corn leave samples to background atmospheric {Delta}{sup 14}C level. The influences of topography, meteorological conditions and carbon cycling processes on the fossil fuel derived CO{sub 2} concentration are considered when interpreting the data. Our results show a clear association of the low {Delta}{sup 14}C values with regions where human activities are intensive.

  18. Molecular Characterization of Thiols in Fossil Fuels by Michael Addition Reaction Derivatization and Electrospray Ionization Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.

    Science.gov (United States)

    Wang, Meng; Zhao, Suoqi; Liu, Xuxia; Shi, Quan

    2016-10-04

    Thiols widely occur in sediments and fossil fuels. However, the molecular composition of these compounds is unclear due to the lack of appropriate analytical methods. In this work, a characterization method for thiols in fossil fuels was developed on the basis of Michael addition reaction derivatization followed by electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS). Model thiol compound studies showed that thiols were selectively reacted with phenylvinylsulfone and transformed to sulfones with greater than 98% conversions. This method was applied to a coker naphtha, light and heavy gas oils, and crude oils from various geological sources. The results showed that long alkyl chain thiols are readily present in petroleum, which have up to 30 carbon atoms. Large DBE dispersity of thiols indicates that naphthenic and aromatic thiols are also present in the petroleum. This method is capable of detecting thiol compounds in the part per million range by weight. This method allows characterization of thiols in a complex hydrocarbon matrix, which is complementary to the comprehensive analysis of sulfur compounds in fossil fuels.

  19. Determination of oil/water and octanol/water distribution coefficients from aqueous solutions from four fossil fuels. [MS thesis; in oil-water and octanol-water

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, B.L.

    1984-07-01

    Liquid fossil fuels, both petroleum and synthetically derived oils, are exceedingly complex mixtures of thousands of components. The effect of many of these energy-related components on the environment is largely unknown. Octanol/water distribution coefficients relate both to toxicity and to the bioaccumulation potential of chemical components. Use of these partition data in conjunction with component concentrations in the oils in environmental models provides important information on the fate of fossil fuel components when released to the environment. Octanol/water distribution data are not available for many energy-related organic compounds, and those data that are available have been determined for individual components in simple, one-component octanol/water equilibrium mixtures. In this study, methods for determining many octanol/water distribution coefficients from aqueous extracts of oil products were developed. Sample aqueous mixtures were made by equilibrating liquid fossil fuels with distilled water. This approach has the advantage of detecting interactions between components of interest and other sample components. Compound types studied included phenols, nitrogen bases, hydrocarbons, sulfur heterocyclic compounds, and carboxylic acids. Octanol/water distribution coefficients that were determined in this study ranged from 9.12 for aniline to 67,600 for 1,2-dimethylnaphthalene. Within a compound type, distribution coefficients increased logarithmically with increasing alkyl substitution and molecular weight. Additionally, oil/water distribution data were determined for oil components. These data are useful in predicting maximum environmental concentrations in water columns. 96 references, 26 figures, and 40 tables.

  20. Potential for worldwide displacement of fossil-fuel electricity by nuclear energy in three decades based on extrapolation of regional deployment data.

    Directory of Open Access Journals (Sweden)

    Staffan A Qvist

    Full Text Available There is an ongoing debate about the deployment rates and composition of alternative energy plans that could feasibly displace fossil fuels globally by mid-century, as required to avoid the more extreme impacts of climate change. Here we demonstrate the potential for a large-scale expansion of global nuclear power to replace fossil-fuel electricity production, based on empirical data from the Swedish and French light water reactor programs of the 1960s to 1990s. Analysis of these historical deployments show that if the world built nuclear power at no more than the per capita rate of these exemplar nations during their national expansion, then coal- and gas-fired electricity could be replaced worldwide in less than a decade. Under more conservative projections that take into account probable constraints and uncertainties such as differing relative economic output across regions, current and past unit construction time and costs, future electricity demand growth forecasts and the retiring of existing aging nuclear plants, our modelling estimates that the global share of fossil-fuel-derived electricity could be replaced within 25-34 years. This would allow the world to meet the most stringent greenhouse-gas mitigation targets.

  1. Potential for worldwide displacement of fossil-fuel electricity by nuclear energy in three decades based on extrapolation of regional deployment data.

    Science.gov (United States)

    Qvist, Staffan A; Brook, Barry W

    2015-01-01

    There is an ongoing debate about the deployment rates and composition of alternative energy plans that could feasibly displace fossil fuels globally by mid-century, as required to avoid the more extreme impacts of climate change. Here we demonstrate the potential for a large-scale expansion of global nuclear power to replace fossil-fuel electricity production, based on empirical data from the Swedish and French light water reactor programs of the 1960s to 1990s. Analysis of these historical deployments show that if the world built nuclear power at no more than the per capita rate of these exemplar nations during their national expansion, then coal- and gas-fired electricity could be replaced worldwide in less than a decade. Under more conservative projections that take into account probable constraints and uncertainties such as differing relative economic output across regions, current and past unit construction time and costs, future electricity demand growth forecasts and the retiring of existing aging nuclear plants, our modelling estimates that the global share of fossil-fuel-derived electricity could be replaced within 25-34 years. This would allow the world to meet the most stringent greenhouse-gas mitigation targets.

  2. Advanced energy analysis of high temperature fuel cell systems

    NARCIS (Netherlands)

    Kouffeld, R.W.J.; Veringa, H.J.; De Groot, A.

    In this thesis the performance of high temperature fuel cell systems is studied using a new method of exergy analysis. The thesis consists of three parts: ⢠In the first part a new analysis method is developed, which not only considers the total exergy losses in a unit operation, but which

  3. Low-Temperature Additive Performance in Jet A Fuels

    Science.gov (United States)

    2013-04-01

    5. The C-130 aircraft has the same APU as the older Boeing 737 . Unfortunately, this APU is known for problems with low temperature starting. Some of...impede fuel flow through the test filter. Manual remote shut off valves Clear collection container Filter elements Figure 23. Image of test

  4. Advanced energy analysis of high temperature fuel cell systems

    NARCIS (Netherlands)

    De Groot, A.

    2004-01-01

    In this thesis the performance of high temperature fuel cell systems is studied using a new method of exergy analysis. The thesis consists of three parts: ⢠In the first part a new analysis method is developed, which not only considers the total exergy losses in a unit operation, but which

  5. New polymer electrolytes for low temperature fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Sundholm, F.; Elomaa, M.; Ennari, J.; Hietala, S.; Paronen, M. [Univ. of Helsinki (Finland). Lab. of Polymer Chemistry

    1998-12-31

    Proton conducting polymer membranes for demanding applications, such as low temperature fuel cells, have been synthesised and characterised. Pre-irradiation methods are used to introduce sulfonic acid groups, directly or using polystyrene grafting, in stable, preformed polymer films. The membranes produced in this work show promise for the development of cost-effective, highly conducting membranes. (orig.)

  6. EPR and FTIR Characterization of Paramagnetic Transition Metal Ions in Fossil Fuels: Tar Sands

    Science.gov (United States)

    Shepherd, Robert Anthony

    The techniques of EPR and FTIR spectroscopy have been applied to the bitumen and mineral fractions of a tar sand sample originating from Circle Cliffs, Utah to detect and identify paramagnetic transition metal ions present, indicate whether or not they are organically bound, and determine the identities of the complexes in which they occur. An EPR spectrum of the bitumen reveals the presence of V('4+) at a site of axial symmetry. Fitting the spectrum to the second order perturbation solution of the spin Hamiltonian indicates that the spectrum originates from vanadyl etioporphyrin. An EPR spectrum characteristic of Mn('2+) in a carbonate lattice was observed for the mineral component. A quantitative analysis of the mineral components, conducted using FTIR spectroscopy, shows the tar sand mineral fraction consists of the two clays, kaolinite and illite, quartz, gypsum, and one carbonate, dolomite. A computer simulation of the EPR spectrum positively identifies the Mn('2+) host as polycrystalline dolomite, shows the ions are at two crystallographically distinct sites in the dolomite lattice, and gives the relative population at each site. A second feature observed in the EPR spectrum of the mineral fraction is a broad line at g = 4.2 which is attributed to Fe('3+) in kaolinite. A third and final feature observed in the EPR spectrum of the tar sand mineral fraction is a broad line at g = 2. The temperature-dependent behavior of this line suggests that it is due to Fe('3+) in amorphous iron oxides and wustite, two compounds that commonly coat kaolinite surfaces.

  7. Strategies for Lowering Solid Oxide Fuel Cells Operating Temperature

    Directory of Open Access Journals (Sweden)

    Albert Tarancón

    2009-11-01

    Full Text Available Lowering the operating temperature of solid oxide fuel cells (SOFCs to the intermediate range (500–700 ºC has become one of the main SOFC research goals. High operating temperatures put numerous requirements on materials selection and on secondary units, limiting the commercial development of SOFCs. The present review first focuses on the main effects of reducing the operating temperature in terms of materials stability, thermo-mechanical mismatch, thermal management and efficiency. After a brief survey of the state-of-the-art materials for SOFCs, attention is focused on emerging oxide-ionic conductors with high conductivity in the intermediate range of temperatures with an introductory section on materials technology for reducing the electrolyte thickness. Finally, recent advances in cathode materials based on layered mixed ionic-electronic conductors are highlighted because the decreasing temperature converts the cathode into the major source of electrical losses for the whole SOFC system. It is concluded that the introduction of alternative materials that would enable solid oxide fuel cells to operate in the intermediate range of temperatures would have a major impact on the commercialization of fuel cell technology.

  8. An Innovative Configuration for CO2 Capture by High Temperature Fuel Cells

    Directory of Open Access Journals (Sweden)

    Federico Rossi

    2014-09-01

    Full Text Available Many technological solutions have been proposed for CO2 capture in the last few years. Most of them are characterized by high costs in terms of energy consumption and, consequently, higher fossil fuel use and higher economic costs. High temperature fuel cells are technological solutions currently developed for energy production with low environmental impact. In CIRIAF—University of Perugia labs, cylindrical geometry, small-sized molten carbonate fuel cell (MCFC prototypes were built and tested with good energy production and lifetime performances. In the present work, an innovative application for MCFCs is proposed, and an innovative configuration for CO2 capture/separation is investigated. The plant scheme is based on a reformer and a cylindrical MCFC. MCFCs are the most suitable solutions, because CO2 is used in their operating cycle. An analysis in terms of energy consumption/kgCO2 captured is made by coupling the proposed configuration with a gas turbine plant. The proposed configuration is characterized by a theoretical energy consumption of about 500 kJ/kgCO2, which is quite lower than actual sequestration technologies. An experimental campaign will be scheduled to verify the theoretical findings.

  9. Light-absorbing properties of ambient black carbon and brown carbon from fossil fuel and biomass burning sources

    Science.gov (United States)

    Healy, R. M.; Wang, J. M.; Jeong, C.-H.; Lee, A. K. Y.; Willis, M. D.; Jaroudi, E.; Zimmerman, N.; Hilker, N.; Murphy, M.; Eckhardt, S.; Stohl, A.; Abbatt, J. P. D.; Wenger, J. C.; Evans, G. J.

    2015-07-01

    The optical properties of ambient black carbon-containing particles and the composition of their associated coatings were investigated at a downtown site in Toronto, Canada, for 2 weeks in June 2013. The objective was to assess the relationship between black carbon (BC) coating composition/thickness and absorption. The site was influenced by emissions from local vehicular traffic, wildfires in Quebec, and transboundary fossil fuel combustion emissions in the United States. Mass concentrations of BC and associated nonrefractory coatings were measured using a soot particle-aerosol mass spectrometer (SP-AMS), while aerosol absorption and scattering were measured using a photoacoustic soot spectrometer (PASS). Absorption enhancement was investigated both by comparing ambient and thermally denuded PASS absorption data and by relating absorption data to BC mass concentrations measured using the SP-AMS. Minimal absorption enhancement attributable to lensing at 781 nm was observed for BC using both approaches. However, brown carbon was detected when the site was influenced by wildfire emissions originating in Quebec. BC coating to core mass ratios were highest during this period (~7), and while direct absorption by brown carbon resulted in an absorption enhancement at 405 nm (>2.0), no enhancement attributable to lensing at 781 nm was observed. The efficiency of BC coating removal in the denuder decreased substantially when wildfire-related organics were present and may represent an obstacle for future similar studies. These findings indicate that BC absorption enhancement due to lensing is minimal for downtown Toronto, and potentially other urban locations, even when impacted by long-range transport events.

  10. Methods of economic analysis applied to fusion research: discount rate determination and the fossil fuel price effect

    Energy Technology Data Exchange (ETDEWEB)

    1978-09-25

    In current and previous efforts, ECON has provided a preliminary economic assessment of a fusion research program. Part of this effort was the demonstration of a methodology for the estimation of reactor system costs and risk and for the treatment of program alternatives as a series of steps (tests) to buy information, thereby controlling program risk and providing a sound economic rationale for properly constructed research programs. The first phase of work also identified two areas which greatly affect the overall economic evaluation of fusion research and which warranted further study in the second phase. This led to the two tasks of the second phase reported herein: (1) discount rate determination and (2) evaluation of the effect of the expectation of the introduction of fusion power on current fossil fuel prices. In the first task, various conceptual measures of the social rate of discount were reviewed and critiqued. In the second task, a benefit area that had been called out by ECON was further examined. Long-range R and D yields short-term benefits in the form of lower nonrenewable energy resource prices because the R and D provides an expectation of future competition for the remaining reserves at the time of technology availability. ECON developed a model of optimal OPEC petroleum pricing as a function of the expectation of future competing technologies. It was shown that the existence of this expectation lowers the optimal OPEC export price and that accelerated technology R and D programs should provide further price decreases. These price reductions translate into benefits to the U.S. of at least a billion dollars.

  11. On the Ability of Ascends to Constrain Fossil Fuel, Ocean and High Latitude Emissions: Flux Estimation Experiments

    Science.gov (United States)

    Crowell, S.; Kawa, S. R.; Hammerling, D.; Moore, B., III; Rayner, P. J.

    2014-12-01

    In Hammerling et al., 2014 (H14) the authors demonstrated a geostatistical method for mapping satellite estimates of column integrated CO2 mixing ratio, denoted XCO2, that incorporates the spatial variability in satellite-measured XCO2 as well as measurement precision. The goal of the study was to determine whether the Active Sensing of CO2 over Nights, Days and Seasons (ASCENDS) mission would be able to detect changes in XCO2 given changes in the underlying fluxes for different levels of instrument precision. Three scenarios were proposed: a flux-neutral shift in fossil fuel emissions from Europe to China (shown in the figure); a permafrost melting event; interannual variability in the Southern Oceans. The conclusions of H14 were modest but favorable for detectability in each case by ASCENDS given enough observations and sufficient precision. These signal detection experiments suggest that ASCENDS observations, together with a chemical transport model and data assimilation methodology, would be sufficient to provide quality estimates of the underlying surface fluxes, so long as the ASCENDS observations are precise enough. In this work, we present results that bridge the gap between the previous signal detection work by [Hammerling et al., 2014] and the ability of transport models to recover flux perturbations from ASCENDS observations utilizing the TM5-4DVAR data assimilation system. In particular, we will explore the space of model and observational uncertainties that will yield useful scientific information in each of the flux perturbation scenarios. This work will give a sense of the ability of ASCENDS to answer key questions about some of the foremost questions in carbon cycle science today. References: Hammerling, D., Kawa, S., Schaefer, K., and Michalak, A. (2014). Detectability of CO2 flux signals by a space-based lidar mission. Submitted.

  12. Polybenzimidazoles based on high temperature polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Linares Leon, Jose Joaquin; Camargo, Ana Paula M.; Ashino, Natalia M.; Morgado, Daniella L.; Frollini, Elisabeth; Paganin, Valdecir A.; Gonzalez, Ernesto Rafael [Universidade de Sao Paulo (IQSC/USP), Sao Carlos, SP (Brazil); Bajo, Justo Lobato [University of Castilla-La Mancha, Ciudad Real (Spain). Dept. of Chemical Engineering

    2010-07-01

    This work presents an interesting approach in order to enhance the performance of Polymer Electrolyte Membrane Fuel Cells (PEMFC) by means of an increase in the operational temperature. For this, two polymeric materials, Poly(2,5-bibenzimidazole) (ABPBI) and Poly[2,2'-(m-phenyl en)-5,5' bib enzimidazol] (PBI), impregnated with phosphoric acid have been utilized. These have shown excellent properties, such as thermal stability above 500 deg C, reasonably high conductivity when impregnated with H{sub 3}PO{sub 4} and a low permeability to alcohols compared to Nafion. Preliminary fuel cells measurements on hydrogen based Polymer Electrolyte Membrane Fuel Cell (PEMFC) displayed an interestingly reasonable good fuel cell performance, a quite reduced loss when the hydrogen stream was polluted with carbon monoxide, and finally, when the system was tested with an ethanol/water (E/W) fuel, it displayed quite promising results that allows placing this system as an attractive option in order to increase the cell performance and deal with the typical limitations of low temperature Nafion-based PEMFC. (author)

  13. Influence of human-climate system feedbacks on predicted 21st century land use/land cover trajectories, fossil fuel emissions, and climate change

    Science.gov (United States)

    Thornton, P. E.; Edmonds, J. A.; Collins, W.; Janetos, A. C.; Hurtt, G. C.; Shi, X.; Mao, J.; Thomson, A. M.; Calvin, K. V.; Bond-Lamberty, B. P.; Chini, L. P.

    2012-12-01

    The interaction between human system and climate system models in the current climate change assessment framework is based on one-way coupling, in which estimates of human actions such as land use and land cover change (LULCC), and fossil fuel combustion, are generated by integrated assessment models (IAMs) and passed as forcing functions to Earth system models (ESMs). By neglecting the return flow of information from the physical climate and biogeochemical systems, inconsistencies are inevitably introduced in this one-way coupling approach. We are developing an integrated Earth System Model (iESM) to characterize, address, and minimize these inconsistencies, by merging the capabilities of IAMs and ESMs in a single coupling framework. Here, we have applied the iESM to estimate the impact of two-way interactions between LULCC and climate on the evolution of the coupled human-climate system over the 21st century. Our simulations followed the Reference Concentration Pathway (RCP) 4.5 scenario, a member of the recent Climate Model Intercomparison Project v5 (CMIP5) family of climate system scenarios. We compared a traditional RCP4.5 simulation from the Community Earth System Model v1 (CESM1) coupled climate-biogeochemistry model with an iESM simulation in which the estimation of LULCC dynamics was performed synchronously with the physical climate simulation. As a first step in a series of planned coupling exercises, we evaluated the influence of a very simple feedback mechanism, in which information generated within the physical-biogeochemical model components was passed back to the human dimensions component by way of a set of scalars capturing the effects of changing climate on terrestrial ecosystem productivity. This mechanism provides a signal within the human system component model modifying crop yields, bioenergy potential, and pasture and forest productivity in response to climate change, including changes in temperature, precipitation, CO2 concentrations, and

  14. High temperature PEM fuel cell. Final report. Public part

    Energy Technology Data Exchange (ETDEWEB)

    Jensen, Jens Oluf (DTU (DK)); Yde Andersen, S.; Rycke, T. de (IRD Fuel Cells A/S (DK)); Nilsson, M. (Danish Power Systems ApS (DK)); Christensen, Torkild, (DONG Energy (DK))

    2006-07-01

    The main outcome of the project is the development of stacking technology for high temperature PEMFC stacks based on phosphoric acid doped polybenzimidazole membranes (PBI-membranes) and a study of the potential of a possible accommodation of HT-PEMFC in the national energy system. Stacks of different lengths (up to 40 cells) have been built using two different approaches in terms of plate materials and sealing. The stacks still need maturing and further testing to prove satisfactory reliability, and a steady reduction of production cost is also desired (as in general for fuel cells). However, during the project the process has come a long way. The survey of HT-PEM fuel cells and their regulatory power in the utility system concludes that fuel cells will most likely not be the dominating technique for regulation, but as no other technique has that potential alone, fuel cells are well suited to play a role in the system provided that the establishment of a communication system is not too complicated. In order to maintain an efficient power system with high reliability in a distributed generation scenario, it is important that communication between TSO (Transmission System Operator) and fuel cells is included in the fuel cell system design at an early stage. (au)

  15. Influence of the Ambient Temperature, to the Hydrogen Fuel Cell Functioning

    Directory of Open Access Journals (Sweden)

    POPOVICI Ovidiu

    2012-10-01

    Full Text Available The reversible fuel cell can be used to produce hydrogen. The hydrogen is further the chemical energy source to produce electrical energy using the fuel cell. The ambient temperature will influence theparameters of the hydrogen fuel cell.

  16. Where do fossil fuel carbon dioxide emissions from California go? An analysis based on radiocarbon observations and an atmospheric transport model

    Energy Technology Data Exchange (ETDEWEB)

    Riley, W.J.; Hsueh, D.Y.; Randerson, J.T.; Fischer, M.L.; Hatch, J.G.; Pataki, D.E.; Wang, W.; Goulden, M.L.

    2008-05-01

    Characterizing flow patterns and mixing of fossil fuel-derived CO{sub 2} is important for effectively using atmospheric measurements to constrain emissions inventories. Here we used measurements and a model of atmospheric radiocarbon ({sup 14}C) to investigate the distribution and fluxes of atmospheric fossil fuel CO{sub 2} across the state of California. We sampled {sup 14}C in annual C{sub 3} grasses at 128 sites and used these measurements to test a regional model that simulated anthropogenic and ecosystem CO{sub 2} fluxes, transport in the atmosphere, and the resulting {sup 14}C of annual grasses ({Delta}{sub g}). Average measured {Delta}{sub g} in Los Angeles, San Francisco, the Central Valley, and the North Coast were 27.7 {+-} 20.0, 44.0 {+-} 10.9, 48.7 {+-} 1.9, and 59.9 {+-} 2.5{per_thousand}, respectively, during the 2004-2005 growing season. Model predictions reproduced regional patterns reasonably well, with estimates of 27.6 {+-} 2.4, 39.4 {+-} 3.9, 46.8 {+-} 3.0, and 59.3 {+-} 0.2{per_thousand} for these same regions and corresponding to fossil fuel CO{sub 2} mixing ratios (Cf) of 13.7, 6.1, 4.8, and 0.3 ppm. {Delta}{sub g} spatial heterogeneity in Los Angeles and San Francisco was higher in the measurements than in the predictions, probably from insufficient spatial resolution in the fossil fuel inventories (e.g., freeways are not explicitly included) and transport (e.g., within valleys). We used the model to predict monthly and annual transport patterns of fossil fuel-derived CO{sub 2} within and out of California. Fossil fuel CO{sub 2} emitted in Los Angeles and San Francisco was predicted to move into the Central Valley, raising Cf above that expected from local emissions alone. Annually, about 21, 39, 35, and 5% of fossil fuel emissions leave the California airspace to the north, east, south, and west, respectively, with large seasonal variations in the proportions. Positive correlations between westward fluxes and Santa Ana wind conditions were

  17. Hydrogen: A real alternative to fossil fuels and bio fuels in the Spanish vehicle industry; El Hidrogeno: Una alternativa real a los combustible fosiles y a los biocombustible para automoacion en Espana

    Energy Technology Data Exchange (ETDEWEB)

    Hernandez-Sobrino, F.; Rodriguez-Monroy, C.; Hernandez-Perez, J. L.

    2010-07-01

    For several years, UE has been trying to increase the use of bio fuels to replace petrol or diesel in the transports with the aim of fulfilling a commitment about climate change, supplying environmentally friendly conditions, promoting renewable energy sources. To achieve this, the 2003/30/EC Directive states that in all the European countries, before 31st December 2010, at least 5.75% of all petrol and diesel fuels used for transport are bio fuels. In previous papers, the authors evaluated this possibility. Analyzing hydrogen as replacement of fossil fuels and bio fuels nowadays in spain and a technical,economic and environmental point of view is the aim of this paper. (Author)

  18. Distributions of fossil fuel originated CO{sub 2} in five metropolitan areas of Korea (Seoul, Busan, Daegu, Daejeon, and Gwangju) according to the {Delta}{sup 14}C in ginkgo leaves

    Energy Technology Data Exchange (ETDEWEB)

    Park, J.H.; Hong, W. [Korea Institute of Geoscience and Mineral Resources, 124 Gwahang-no Yuseong, Daejeon 305-350 (Korea, Republic of); Park, G., E-mail: junghun@kigam.re.kr [Korea Institute of Geoscience and Mineral Resources, 124 Gwahang-no Yuseong, Daejeon 305-350 (Korea, Republic of); Sung, K.S.; Lee, K.H.; Kim, Y.E.; Kim, J.K.; Choi, H.W.; Kim, G.D.; Woo, H.J. [Korea Institute of Geoscience and Mineral Resources, 124 Gwahang-no Yuseong, Daejeon 305-350 (Korea, Republic of)

    2013-01-15

    We collected a batch of ginkgo (Ginkgo biloba Linnaeus) leaf samples at five metropolitan areas of Korea (Seoul, Busan, Daegu, Daejeon, and Gwangju) in 2009 to obtain the regional distribution of fossil fuel originated CO{sub 2} (fossil fuel CO{sub 2}) in the atmosphere. Regions assumed to be free of fossil fuel CO{sub 2} were also selected, namely Mt. Chiak, Mt. Kyeryong, Mt. Jiri, Anmyeon Island, and Jeju Island and ginkgo leaf samples were collected in those areas during the same period. The {Delta}{sup 14}C values of the samples were measured using Accelerator Mass Spectrometry (AMS) and the fossil fuel CO{sub 2} ratios in the atmosphere were obtained in the five metropolitan areas. The average ratio of fossil fuel CO{sub 2} in Seoul was higher than that in the other four cities. The leaves from the Sajik Tunnel in Seoul recorded the highest FFCTC (fossil fuel CO{sub 2} over total CO{sub 2} in atmosphere), 13.9 {+-} 0.5%, as the air flow of the surrounding neighborhood of the Sajik Tunnel was blocked.

  19. The effect of axial fuel rod power profile on fuel temperature and cladding strain

    Directory of Open Access Journals (Sweden)

    Kim Kyu-Tae

    2010-01-01

    Full Text Available The most limiting design criteria for nuclear reactor normal operating conditions (ANS Condition I are known to be rod internal pressure and cladding oxidation, while those for nuclear reactor transient operating conditions (ANS Conditon II to be fuel centerline temperature and transient cladding total tensile strain. However, the design margins against fuel temperature and transient cladding tensile strain become smaller since power uprating is being or will be utilized for the most of nuclear power reactors to enhance the economics of nuclear power. In order to secure sufficient design margins against fuel temperature and cladding total tensile strain even for power uprating, the current axial rod power profiles used in the reactor transient analysis were optimized to reduce over-conservatism, considering that 118% overpower of a steady-state peak rod average power was not exceeded during the reactor transients. The comparison of the current axial rod power profiles and the optimized ones indicates that the latter reduces the fuel centerline temperature and cladding total tensile strain by 26°C and 0.02%, respectively.

  20. High performance internal reforming unit for high temperature fuel cells

    Science.gov (United States)

    Ma, Zhiwen [Sandy Hook, CT; Venkataraman, Ramakrishnan [New Milford, CT; Novacco, Lawrence J [Brookfield, CT

    2008-10-07

    A fuel reformer having an enclosure with first and second opposing surfaces, a sidewall connecting the first and second opposing surfaces and an inlet port and an outlet port in the sidewall. A plate assembly supporting a catalyst and baffles are also disposed in the enclosure. A main baffle extends into the enclosure from a point of the sidewall between the inlet and outlet ports. The main baffle cooperates with the enclosure and the plate assembly to establish a path for the flow of fuel gas through the reformer from the inlet port to the outlet port. At least a first directing baffle extends in the enclosure from one of the sidewall and the main baffle and cooperates with the plate assembly and the enclosure to alter the gas flow path. Desired graded catalyst loading pattern has been defined for optimized thermal management for the internal reforming high temperature fuel cells so as to achieve high cell performance.

  1. Gasoline Ultra Efficient Fuel Vehicle with Advanced Low Temperature Combustion

    Energy Technology Data Exchange (ETDEWEB)

    Confer, Keith [Delphi Automotive Systems, LLC, Troy, MI (United States)

    2014-12-18

    The objective of this program was to develop, implement and demonstrate fuel consumption reduction technologies which are focused on reduction of friction and parasitic losses and on the improvement of thermal efficiency from in-cylinder combustion. The program was executed in two phases. The conclusion of each phase was marked by an on-vehicle technology demonstration. Phase I concentrated on short term goals to achieve technologies to reduce friction and parasitic losses. The duration of Phase I was approximately two years and the target fuel economy improvement over the baseline was 20% for the Phase I demonstration. Phase II was focused on the development and demonstration of a breakthrough low temperature combustion process called Gasoline Direct- Injection Compression Ignition (GDCI). The duration of Phase II was approximately four years and the targeted fuel economy improvement was 35% over the baseline for the Phase II demonstration vehicle. The targeted tailpipe emissions for this demonstration were Tier 2 Bin 2 emissions standards.

  2. Durable Catalysts for High Temperature Proton Exchange Membrane Fuel Cells

    DEFF Research Database (Denmark)

    the selectivity for platinum loading. Fuel cell durability tests in term of performance degradation were performed with acid doped polybenzimidazole membrane fuel cells at temperatures of up to 160°C. The tests were focused on catalyst degradation by means of a potential cycling protocol. The electrochemical......Durability of proton exchange membrane fuel cells (PEMFCs) is recognized as one of the most important issues to be addressed before the commercialization. The failure mechanisms are not well understood, however, degradation of carbon supported noble metal catalysts is identified as a major failure...... mode of PEMFCs. Under idle, load-cycling or start-up/shutdown modes of operation, which are prerequisite for automobile applications, the cathode will experience significantly higher potentials and therefore suffer from serious carbon corrosion, especially at the presence of platinum. The carbon...

  3. The reliability of the repair weld joints of aged high temperature components in fossil power boilers

    Energy Technology Data Exchange (ETDEWEB)

    Okamura, Hiroyuki [Science Univ. of Tokyo (Japan); Ohtani, Ryuichi [Kyoto Univ. (Japan); Fujii, Kazuya [Japan Power Engineering and Inspection Corp., Tokyo (Japan); Yokoyama, Tomomitsu; Nishimura, Nobuhiko [Mitsubishi Heavy Industries Ltd., Tokyo (Japan); Suzuki, Komei [Japan Steel Works Ltd., Tokyo (Japan)

    1998-11-01

    It is of fundamental engineering importance to be able to give reliable assessments of the effective service life of the critical components used within fossil power plants, particularly for those operating for prolonged periods. It is common practice for such assessments to have been estimated using destructive tests, typically the stress rupture test, this having been recognized as one of the most reliable evaluation methods available. Its only drawback is that it often does not permit the component to be in use following the sampling of the test specimen without repairing. The current piece of work focuses on the reliability of the repair welds of components for specimens taken from fossil power plants, having been in service for prolonged periods. Several such repairs to welds have been made to an old power boiler, in particular to a superheater header which is fabricated from 2.25Cr-1Mo steel. Under close examination the repairs to the girth weldment showed susceptibilities of weld cracking, similar to that observed in as-manufactured material. Within the repaired region of the welded joint the microstructure, tensile properties and toughness seemed to be unaffected. The hardness attained its minimum value within the heat affected zone, HAZ of the repair weld, overlapping that of original girth weld HAZ. Furthermore, the stress rupture strength achieved its minimum value at the same position taking on the same value as the strength associated with the aged girth welded joint. (orig.)

  4. In-flight and simulated aircraft fuel temperature measurements

    Science.gov (United States)

    Svehla, Roger A.

    1990-01-01

    Fuel tank measurements from ten flights of an L1011 commercial aircraft are reported for the first time. The flights were conducted from 1981 to 1983. A thermocouple rake was installed in an inboard wing tank and another in an outboard tank. During the test periods of either 2 or 5 hr, at altitudes of 10,700 m (35,000 ft) or higher, either the inboard or the outboard tank remained full. Fuel temperature profiles generally developed in the expected manner. The bulk fuel was mixed by natural convection to a nearly uniform temperature, especially in the outboard tank, and a gradient existed at the bottom conduction zone. The data indicated that when full, the upper surface of the inboard tank was wetted and the outboard tank was unwetted. Companion NASA Lewis Research Center tests were conducted in a 0.20 cubic meter (52 gal) tank simulator of the outboard tank, chilled on the top and bottom, and insulated on the sides. Even though the simulator tank had no internal components corresponding to the wing tank, temperatures agreed with the flight measurements for wetted upper surface conditions, but not for unwetted conditions. It was concluded that if boundary conditions are carefully controlled, simulators are a useful way of evaluating actual flight temperatures.

  5. Online prediction of the piston maximum temperature in dual-fuel engine

    National Research Council Canada - National Science Library

    Fu, Youyao; Xiao, Bing

    2017-01-01

    .... The piston maximum temperature of dual-fuel engine easily exceeds the security border. Toward this, this article presents a relational model to real-timely predict the piston maximum temperature of dual-fuel engine...

  6. High Temperature PEM Fuel Cell Stacks with Advent TPS Meas

    Directory of Open Access Journals (Sweden)

    Neophytides Stylianos

    2017-01-01

    Full Text Available High power/high energy applications are expected to greatly benefit from high temperature Polymer Electrolyte Membrane Fuel Cells (PEMFCs. In this work, a combinatorial approach is presented, in which separately developed and evaluated MEAs, design and engineering are employed to result in reliable and effective stacks operating above 180°C and having the characteristics well matched to applications including auxiliary power, micro combined heat and power, and telecommunication satellites.

  7. The Hestia Project: High Spatial Resolution Fossil Fuel Carbon Dioxide Emissions Quantification at Hourly Scale in Indianapolis, USA

    Science.gov (United States)

    Zhou, Y.; Gurney, K. R.

    2009-12-01

    In order to advance the scientific understanding of carbon exchange with the land surface and contribute to sound, quantitatively-based U.S. climate change policy interests, quantification of greenhouse gases emissions drivers at fine spatial and temporal scales is essential. Quantification of fossil fuel CO2 emissions, the primary greenhouse gases, has become a key component to cost-effective CO2 emissions mitigation options and a carbon trading system. Called the ‘Hestia Project’, this pilot study generated CO2 emissions down to high spatial resolution and hourly scale for the greater Indianapolis region in the USA through the use of air quality and traffic monitoring data, remote sensing, GIS, and building energy modeling. The CO2 emissions were constructed from three data source categories: area, point, and mobile. For the area source emissions, we developed an energy consumption model using DOE/EIA survey data on building characteristics and energy consumption. With the Vulcan Project’s county-level CO2 emissions and simulated building energy consumption, we quantified the CO2 emissions for each individual building by allocating Vulcan emissions to roughly 50,000 structures in Indianapolis. The temporal pattern of CO2 emissions in each individual building was developed based on temporal patterns of energy consumption. The point sources emissions were derived from the EPA National Emissions Inventory data and effluent monitoring of electricity producing facilities. The mobile source CO2 emissions were estimated at the month/county scale using the Mobile6 combustion model and the National Mobile Inventory Model database. The month/county scale mobile source CO2 emissions were downscaled to the “native” spatial resolution of road segments every hour using a GIS road atlas and traffic monitoring data. The result is shown in Figure 1. The resulting urban-scale inventory can serve as a baseline of current CO2 emissions and should be of immediate use to

  8. Jerusalem artichoke as low-cost fructose-rich feedstock for fossil fuels desulphurization by a fructophilic bacterium.

    Science.gov (United States)

    Silva, T P; Paixão, S M; Roseiro, J C; Alves, L

    2015-03-01

    Through biodesulphurization (BDS) is possible to remove the sulphur present in fossil fuels to carry out the very strict legislation. However, this biological process is limited by the cost of the culture medium, and thus, it is important to explore cheaper alternative carbon sources, such as Jerusalem artichoke (JA). These carbon sources usually contain sulphates which interfere with the BDS process. The goal of this work was to remove the sulphates from Jerusalem artichoke juice (JAJ) through BaCl2 precipitation viewing the optimization of dibenzothiophene (DBT) desulphurization by Gordonia alkanivorans strain 1B. Using a statistical design (Doehlert distribution), the effect of BaCl2 concentration (0.125-0.625%) and pH (5-9) was studied on sulphate concentration in hydrolysed JAJ. A validated surface response derived from data indicated that zero sulphates can be achieved with 0.5-0.55% (w/v) BaCl2 at pH 7; however, parallel BDS assays showed that the highest desulphurization was obtained with the juice treated with 0.5% (w/v) BaCl2 at pH 8.73. Further assays demonstrated that enhanced DBT desulphurization was achieved using hydrolysed JAJ treated in these optimal conditions. A total conversion of 400 μmol l(-1) DBT into 2-hydroxybiphenyl (2-HBP) in <90 h was observed, attaining a 2-HBP maximum production rate of 28.2 μmol l(-1) h(-1) and a specific production rate of 5.06 μmol(-1) g(-1) (DCW) h(-1) . These results highlight the efficacy of the treatment applied to JAJ in making this agromaterial a promising low-cost renewable feedstock for improved BDS by the fructophilic strain 1B. This study is a fundamental step viewing BDS application at the industrial level as it accounts a cost-effective production of the biocatalysts, one of the main drawbacks for BDS scale-up. © 2014 The Society for Applied Microbiology.

  9. High temperature PEM fuel cells - Degradation and durability

    Energy Technology Data Exchange (ETDEWEB)

    Araya, S.S.

    2012-12-15

    This work analyses the degradation issues of a High Temperature Proton Exchange Membrane Fuel Cell (HT-PEMFC). It is based on the assumption that given the current challenges for storage and distribution of hydrogen, it is more practical to use liquid alcohols as energy carriers for fuel cells. Among these, methanol is very attractive, as it can be obtained from a variety of renewable sources and has a relatively low reforming temperature for the production of hydrogen rich gaseous mixture. The effects on HT-PEMFC of the different constituents of this gaseous mixture, known as a reformate gas, are investigated in the current work. For this, an experimental set up, in which all these constituents can be fed to the anode side of a fuel cell for testing, is put in place. It includes mass flow controllers for the gaseous species, and a vapor delivery system for the vapor mixture of the unconverted reforming reactants. Electrochemical Impedance Spectroscopy (EIS) is used to characterize the effects of these impurities. The effects of CO were tested up to 2% by volume along with other impurities. All the reformate impurities, including ethanol-water vapor mixture, cause loss in the performance of the fuel cell. In general, CO{sub 2} dilutes the reactants, if tested alone at high operating temperatures (180 C), but tends to exacerbate the effects of CO if they are tested together. On the other hand, CO and methanol-water vapor mixture degrade the fuel cell proportionally to the amounts in which they are tested. In this dissertation some of the mechanisms with which the impurities affect the fuel cell are discussed and interdependence among the effects is also studied. This showed that the combined effect of reformate impurities is more than the arithmetic sum of the individual effects of reformate constituents. The results of the thesis help to understand better the issues of degradation and durability in fuel cells, which can help to make them more durable and

  10. An assessment of fossil fuel energy use and CO{sub 2} emissions from farm field operations using a regional level crop and land use database for Canada

    Energy Technology Data Exchange (ETDEWEB)

    Dyer, J.A. [Private Consultant, Cambridge, ON (Canada); Kulshreshtha, S.N. [University of Saskatchewan, Saskatoon, SA (Canada); McConkey, B.G. [Research Branch, AAFC, Swift Current, SA (Canada); Desjardins, R.L. [Research Branch, AAFC, C.E.F. Ottawa, ON (Canada)

    2010-05-15

    The Canadian Economic and Emissions Model for Agriculture (CEEMA) is considered a potentially useful tool for investigating the impacts of biofuel feedstock production on rural land use. Fossil CO{sub 2} emissions from fieldwork in the CEEMA model were upgraded with the Fossil Fuel Farm Fieldwork Energy and Emissions (F4E2) simulation model. There was very close agreement between the two models at the national level, but differences between the two models at the regional scale and among the three major land uses illustrated the need to revise CEEMA. Emission coefficients from the F4E2 model will give the upgraded CEEMA a more realistic response to the energy requirements by specific field operations and to differences between the major forms of land cover (annuals and perennials). The highest fossil fuel CO{sub 2} emission intensity for fieldwork in 2001 was in Quebec at 0.19 t{l_brace}CO{sub 2}{r_brace}/ha, followed by Ontario at 0.17 t{l_brace}CO{sub 2}{r_brace}/ha, while the emission intensities were the lowest in Western Canada, at 0.12 t{l_brace}CO{sub 2}{r_brace}/ha. Fossil CO{sub 2} emissions from just annual crops in Canada was 0.16 t/ha and the emissions from just harvesting perennial forages was 0.07 t{l_brace}CO{sub 2}{r_brace}/ha. Fieldwork to maintain summerfallow emitted only 0.02 t{l_brace}CO{sub 2}{r_brace}/ha. (author)

  11. Effect of temperature on a miniaturized microbial fuel cell (MFC)

    Science.gov (United States)

    Ren, Hao; Jiang, Chenming; Chae, Junseok

    2017-12-01

    A microbial fuel cell (MFC) is a bioinspired energy converter which directly converts biomass into electricity through the catalytic activity of a specific species of bacteria. The effect of temperature on a miniaturized microbial fuel cell with Geobacter sulfurreducens dominated mixed inoculum is investigated in this paper for the first time. The miniaturized MFC warrants investigation due to its small thermal mass, and a customized setup is built for the temperature effect characterization. The experiment demonstrates that the optimal temperature for the miniaturized MFC is 322-326 K (49-53 °C). When the temperature is increased from 294 to 322 K, a remarkable current density improvement of 282% is observed, from 2.2 to 6.2 Am-2. Furthermore, we perform in depth analysis on the effect of temperature on the miniaturized MFC, and found that the activation energy for the current limiting mechanism of the MFC is approximately between 0.132 and 0.146 eV, and the result suggest that the electron transfer between cytochrome c is the limiting process for the miniaturized MFC.

  12. 78 FR 9016 - Approval and Promulgation of Air Quality Implementation Plans; Massachusetts; Revisions to Fossil...

    Science.gov (United States)

    2013-02-07

    ...; Revisions to Fossil Fuel Utilization and Source Registration Regulations and Boiler Industrial Standards... revisions add new monitoring, inspection, maintenance and testing requirements for certain fossil fuel... approval of the state's revised fossil fuel utilization facility regulation, source registration regulation...

  13. Intelligent support system online for the operation of fossil fuel units; Sistema inteligente de ayuda en linea para la operacion de unidades termoelectricas

    Energy Technology Data Exchange (ETDEWEB)

    Quintero R, Agustin; Suarez C, Dionisio A; Sanchez L, Jose Alfredo [Instituto de Investigaciones Electricas, Cuernavaca, Morelos (Mexico)

    2006-07-01

    The purpose of this publication is to present a support system online for the operation (SAO) of fossil fuel units, having as objective to support the operator of fossil fuel units when handling guidelines and essential information to carry out the starting and shutdown in a safe and efficient way, reducing the consumption of the useful life of the steam generator and the turbine, as well as the operational cost. Here are presented the intelligent systems for the support of the operation and are described the main characteristics in the dominion of application for the support system, its architecture and functionality, as well as the results obtained in the system assessment performed with the aid of total reach simulator of a fossil fuel unit and a pilot unit. [Spanish] Es motivo de esta publicacion, la presentacion de un sistema de ayuda en linea para la operacion (SAO) de unidades termoelectricas que tiene como objetivo asistir al operador de una unidad termoelectrica con guias de manejo e informacion esencial para llevar a cabo el arranque o paro en forma segura y eficiente, reducir el consumo de vida util del generador de vapor y la turbina, asi como el costo de operacion. Aqui se presentan los sistemas inteligentes de ayuda a la operacion y se describen las caracteristicas principales del dominio de aplicacion para el sistema de ayuda, su arquitectura y funcionalidad, asi como los resultados obtenidos de la evaluacion del sistema realizada con la ayuda de un simulador de alcance total de una unidad termoelectrica y una unidad piloto.

  14. Effects of aqueous effluents from in situ fossil fuel processing technologies on aquatic systems. Annual progress report, January 1-December 31, 1979

    Energy Technology Data Exchange (ETDEWEB)

    Bergman, H.L.

    1980-01-04

    This is the third annual progress report for a continuing EPA-DOE jointly funded project to evaluate the effects of aqueous effluents from in situ fossil-fuel processing technologies on aquatic biota. The project is organized into four project tasks: (1) literature review; (2) process water screening; (3) methods development; and (4) recommendations. Our Bibliography of aquatic ecosystem effects, analytical methods and treatment technologies for organic compounds in advanced fossil-fuel processing effluents was submitted to the EPA for publication. The bibliography contains 1314 citations indexed by chemicals, keywords, taxa and authors. We estimate that the second bibliography volume will contain approximately 1500 citations and be completed in February. We compiled results from several laboratories of inorganic characterizations of 19 process waters: 55 simulated in situ oil-shale retort waters; and Hanna-3, Hanna-4B 01W and Lawrence Livermore Hoe Creek underground coal gasification condenser waters. These process waters were then compared to a published summary of the analyses from 18 simulated in situ oil-shale retort waters. We completed this year 96-h flow-through toxicity bioassays with fathead minnows and rainbow trout and 48-h flow-through bioassays with Daphnia pulicaria exposed to 5 oil-shale process waters, 1 tar-sand process water, 2 underground coal gasification condenser waters, 1 post-gasification backflood condenser water, as well as 2 bioassays with fossil-fuel process water constituents. The LC/sub 50/ toxicity values for these respective species when exposed to these waters are given in detail. (LTN)

  15. Impact assessment of biomass-based district heating systems in densely populated communities. Part II: Would the replacement of fossil fuels improve ambient air quality and human health?

    Science.gov (United States)

    Petrov, Olga; Bi, Xiaotao; Lau, Anthony

    2017-07-01

    To determine if replacing fossil fuel combustion with biomass gasification would impact air quality, we evaluated the impact of a small-scale biomass gasification plant (BRDF) at a university campus over 5 scenarios. The overall incremental contribution of fine particles (PM2.5) is found to be at least one order of magnitude lower than the provincial air quality objectives. The maximum PM2.5 emission from the natural gas fueled power house (PH) could adversely add to the already high background concentration levels. Nitrogen dioxide (NO2) emissions from the BRDF with no engineered pollution controls for NOx in place exceeded the provincial objective in all seasons except during summer. The impact score, IS, was the highest for NO2 (677 Disability Adjusted Life Years, DALY) when biomass entirely replaced fossil fuels, and the highest for PM2.5 (64 DALY) and CO (3 DALY) if all energy was produced by natural gas at PH. Complete replacement of fossil fuels by one biomass plant can result in almost 28% higher health impacts (708 DALY) compared to 513 DALY when both the current BRDF and the PH are operational mostly due to uncontrolled NO2 emissions. Observations from this study inform academic community, city planners, policy makers and technology developers on the impacts of community district heating systems and possible mitigation strategies: a) community energy demand could be met either by splitting emissions into more than one source at different locations and different fuel types or by a single source with the least-impact-based location selection criteria with biomass as a fuel; b) advanced high-efficiency pollution control devices are essential to lower emissions for emission sources located in a densely populated community; c) a spatial and temporal impact assessment should be performed in developing bioenergy-based district heating systems, in which the capital and operational costs should be balanced with not only the benefit to greenhouse gas emission

  16. Results concerning a clean co-combustion technology of waste biomass with fossil fuel, in a pilot fluidised bed combustion facility

    Energy Technology Data Exchange (ETDEWEB)

    Ionel, Ioana; Trif-Tordai, Gavril; Ungureanu, Corneliu; Popescu, Francisc; Lontis, Nicolae [Politehnica Univ. Timisoara (Romania). Faculty for Mechanical Engineering

    2008-07-01

    The research focuses on a facility, the experimental results, interpretation and future plans concerning a new developed technology of using waste renewable energy by applying the cocombustion of waste biomass with coal, in a fluidised bed system. The experimental facility is working entirely in accordance to the allowed limits for the exhaust flue gas concentration, with special concern for typical pollutants. The experiments conclude that the technology is cleaner, has as main advantage the possibility to reduce both the SO{sub 2} and CO{sub 2} exhaust in comparison to standard fossil fuel combustion, under comparable circumstances. The combustion is occurring in a stable fluidised bed. (orig.)

  17. Oxidation of dibenzothiophene as a model substrate for the removal of organic sulphur from fossil fuels by iron(III ions generated from pyrite by Acidithiobacillus ferrooxidans

    Directory of Open Access Journals (Sweden)

    VLADIMIR P. BESKOSKI

    2007-06-01

    Full Text Available Within this paper a new idea for the removal of organically bonded sulphur from fossil fuels is discussed. Dibenzothiophene (DBT was used as a model compound of organicmolecules containing sulphur. This form of (biodesulphurization was performed by an indirect mechanism in which iron(III ions generated from pyrite by Acidithiobacillus ferrooxidans performed the abiotic oxidation. The obtained reaction products, dibenzothiopene sulfoxide and dibenzothiophene sulfone, are more soluble in water than the basic substrate and the obtained results confirmed the basic hypothesis and give the posibility of continuing the experiments related to application of this (biodesulphurization process.

  18. Transient response of high temperature PEM fuel cell

    Science.gov (United States)

    Peng, J.; Shin, J. Y.; Song, T. W.

    A transient three-dimensional, single-phase and non-isothermal numerical model of polymer electrolyte membrane (PEM) fuel cell with high operating temperature has been developed and implemented in computational fluid dynamic (CFD) code. The model accounts for transient convective and diffusive transport, and allows prediction of species concentration. Electrochemical charge double-layer effect is considered. Heat generation according to electrochemical reaction and ohmic loss are involved. Water transportation across membrane is ignored due to low water electro-osmosis drag force of polymer polybenzimidazole (PBI) membrane. The prediction shows transient in current density which overshoots (undershoots) the stabilized state value when cell voltage is abruptly decreased (increased). The result shows that the peak of overshoot (undershoot) is related with cathode air stoichiometric mass flow rate instead of anode hydrogen stoichiometric mass flow rate. Current is moved smoothly and there are no overshoot or undershoot with the influence of charge double-layer effect. The maximum temperature is located in cathode catalyst layer and both fuel cell average temperature and temperature deviation are increased with increasing of current load.

  19. Validation of the BISON 3D Fuel Performance Code: Temperature Comparisons for Concentrically and Eccentrically Located Fuel Pellets

    Energy Technology Data Exchange (ETDEWEB)

    J. D. Hales; D. M. Perez; R. L. Williamson; S. R. Novascone; B. W. Spencer

    2013-03-01

    BISON is a modern finite-element based nuclear fuel performance code that has been under development at the Idaho National Laboratory (USA) since 2009. The code is applicable to both steady and transient fuel behaviour and is used to analyse either 2D axisymmetric or 3D geometries. BISON has been applied to a variety of fuel forms including LWR fuel rods, TRISO-coated fuel particles, and metallic fuel in both rod and plate geometries. Code validation is currently in progress, principally by comparison to instrumented LWR fuel rods. Halden IFA experiments constitute a large percentage of the current BISON validation base. The validation emphasis here is centreline temperatures at the beginning of fuel life, with comparisons made to seven rods from the IFA-431 and 432 assemblies. The principal focus is IFA-431 Rod 4, which included concentric and eccentrically located fuel pellets. This experiment provides an opportunity to explore 3D thermomechanical behaviour and assess the 3D simulation capabilities of BISON. Analysis results agree with experimental results showing lower fuel centreline temperatures for eccentric fuel with the peak temperature shifted from the centreline. The comparison confirms with modern 3D analysis tools that the measured temperature difference between concentric and eccentric pellets is not an artefact and provides a quantitative explanation for the difference.

  20. Anodes for Solid Oxide Fuel Cells Operating at Low Temperatures

    DEFF Research Database (Denmark)

    Abdul Jabbar, Mohammed Hussain

    . On the other hand, low-temperature operation poses serious challenges to the electrode performance. Effective catalysts, redox stable electrodes with improved microstructures are the prime requisite for the development of efficient SOFC anodes. The performance of Nb-doped SrT iO3 (STN) ceramic anodes......An important issue that has limited the potential of Solid Oxide Fuel Cells (SOFCs) for portable applications is its high operating temperatures (800-1000 ºC). Lowering the operating temperature of SOFCs to 400-600 ºC enable a wider material selection, reduced degradation and increased lifetime...... at 400ºC. The potential of using WO3 ceramic as an alternative anode materials has been explored. The relatively high electrode polarization resistance obtained, 11 Ohm cm2 at 600 ºC, proved the inadequate catalytic activity of this system for hydrogen oxidation. At the end of this thesis...

  1. Development of a 400 W High Temperature PEM Fuel Cell Power Pack

    DEFF Research Database (Denmark)

    Andreasen, Søren Juhl; Bang, Mads; Korsgaard, Anders

    2006-01-01

    reformer design because CO removal is not needed. A fuel like methanol would be a preferable choice for reforming when using HTPEM fuel cells because of its high energy density and low reforming temperatures. The thermal integration and use of HTPEM fuel cells with methanol reformers show promising results......When using pressurized hydrogen to fuel a fuel cell, much space is needed for fuel storage. This is undesirable especially with mobile or portable fuel cell systems, where refuelling also often is inconvenient. Using a reformed liquid carbonhydrate can reduce this fuel volume considerably. Nafion...... based low temperature PEM (LTPEM) fuel cells are very intolerant to reformate gas because of the presence of CO. PBI based high temperature PEM (HTPEM) fuel cells can operate stable at much higher CO concentrations. This makes the HTPEM very suitable for applications using a reformer, and could simplify...

  2. Allerod--younger dryas lake temperatures from midge fossils in atlantic Canada.

    Science.gov (United States)

    Walker, I R; Mott, R J; Smol, J P

    1991-08-30

    Remains of freshwater midges are abundant in lake sediments, and their species distributions are closely related to the surface-water temperature of lakes; their distributions thus provide a powerful tool for paleoclimatology. The distribution of species in a core from Splan Pond in Atlantic Canada indicates that there were abrupt transitions in late-glacial temperatures between warm and cold states. The transitions are correlative with the well-known warm Allerød and cold Younger Dryas events in Europe. These data thus confirm the inference from palynological data that these events affected regions on both sides of the Atlantic.

  3. Assessment of the impacts on health due to the emissions of Cuban power plants that use fossil fuel oils with high content of sulfur. Estimation of external costs

    Energy Technology Data Exchange (ETDEWEB)

    Carbonell, L. Turtos; Ruiz, E. Meneses; Gacita, M. Sanchez; Oliva, J. Rivero; Rivero, N. Diaz [Cubaenergia, Playa, Ciudad de la Habana (Cuba)

    2007-03-15

    Fossil fuel electricity generation has been demonstrated to be a main source of atmospheric pollution. The necessity of finding out a balance between the costs of achieving a lower level of environmental and health injury and the benefits of providing electricity at a reasonable cost have lead to the process of estimating the external costs derived from these impacts and not included in the electricity prices as a quantitative measure of it that, even when there are large uncertainties involved, can be used by decision makers in the process of achieving a global sustainable development. The external costs of the electricity generation in three Cuban power plants that use fossil fuel oils with high sulfur content have been assessed. With that purpose a specific implementation of the Impact Pathways Methodology for atmospheric emissions was developed. Dispersion of atmospheric pollutants is modeled at local and regional scales in a detailed way. Health impacts include mortality and those morbidity effects that showed relation with the increment of selected pollutant concentration in national studies. The external cost assessed for the three plants was 40, 588, 309 USD yr{sup -1} (min/max: 10, 194, 833/169, 013, 252), representing 1.06 USD Cent kWh{sup -1}. Costs derived from sulfur species (SO{sub 2} and sulfate aerosol) stand for 93% of the total costs. (Author)

  4. The relationship between air pollution, fossil fuel energy consumption, and water resources in the panel of selected Asia-Pacific countries.

    Science.gov (United States)

    Rafindadi, Abdulkadir Abdulrashid; Yusof, Zarinah; Zaman, Khalid; Kyophilavong, Phouphet; Akhmat, Ghulam

    2014-10-01

    The objective of the study is to examine the relationship between air pollution, fossil fuel energy consumption, water resources, and natural resource rents in the panel of selected Asia-Pacific countries, over a period of 1975-2012. The study includes number of variables in the model for robust analysis. The results of cross-sectional analysis show that there is a significant relationship between air pollution, energy consumption, and water productivity in the individual countries of Asia-Pacific. However, the results of each country vary according to the time invariant shocks. For this purpose, the study employed the panel least square technique which includes the panel least square regression, panel fixed effect regression, and panel two-stage least square regression. In general, all the panel tests indicate that there is a significant and positive relationship between air pollution, energy consumption, and water resources in the region. The fossil fuel energy consumption has a major dominating impact on the changes in the air pollution in the region.

  5. Relating N2O emissions from energy crops to the avoided fossil fuel-derived CO2 – a study on bioethanol and biogas produced from organically managed maize, rye, vetch and grass-clover

    DEFF Research Database (Denmark)

    Carter, Mette Sustmann; Hauggard-Nielsen, Henrik; Thomsen, Sune Tjalfe

    2010-01-01

    One way of reducing the emissions of fossil fuel‐derived CO2 is to replace fossil fuels with biofuels. However, cultivation of soils results in emission of other greenhouse gasses, especially nitrous oxide (N2O). In this study we relate measured field emissions of N2O to the reduction in fossil...... fuel‐derived CO2, which is obtained when energy crops are used for biofuel production. The analysis includes five organically managed crops (viz. maize, rye, rye‐vetch, vetch and grass‐clover) and three scenarios for conversion of biomass to biofuel. The scenarios are 1) bioethanol production, 2......) biogas production and 3) co‐production of bioethanol and biogas, where the energy crops are first used for bioethanol fermentation and subsequently the residues from this process are utilized for biogas production. The net reduction in greenhouse gas missions is calculated as the avoided fossil fuel...

  6. Effect of increased fuel temperature on emissions of oxides of nitrogen from a gas turbine combustor burning ASTM jet-A fuel

    Science.gov (United States)

    Marchionna, N. R.

    1974-01-01

    An annular gas turbine combustor was tested with heated ASTM Jet-A fuel to determine the effect of increased fuel temperature on the formation of oxides of nitrogen. Fuel temperature ranged from ambient to 700 K. The NOx emission index increased at a rate of 6 percent per 100 K increase in fuel temperature.

  7. Bio-Fuel Production Assisted with High Temperature Steam Electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Grant Hawkes; James O' Brien; Michael McKellar

    2012-06-01

    Two hybrid energy processes that enable production of synthetic liquid fuels that are compatible with the existing conventional liquid transportation fuels infrastructure are presented. Using biomass as a renewable carbon source, and supplemental hydrogen from high-temperature steam electrolysis (HTSE), these two hybrid energy processes have the potential to provide a significant alternative petroleum source that could reduce dependence on imported oil. The first process discusses a hydropyrolysis unit with hydrogen addition from HTSE. Non-food biomass is pyrolyzed and converted to pyrolysis oil. The pyrolysis oil is upgraded with hydrogen addition from HTSE. This addition of hydrogen deoxygenates the pyrolysis oil and increases the pH to a tolerable level for transportation. The final product is synthetic crude that could then be transported to a refinery and input into the already used transportation fuel infrastructure. The second process discusses a process named Bio-Syntrolysis. The Bio-Syntrolysis process combines hydrogen from HTSE with CO from an oxygen-blown biomass gasifier that yields syngas to be used as a feedstock for synthesis of liquid synthetic crude. Conversion of syngas to liquid synthetic crude, using a biomass-based carbon source, expands the application of renewable energy beyond the grid to include transportation fuels. It can also contribute to grid stability associated with non-dispatchable power generation. The use of supplemental hydrogen from HTSE enables greater than 90% utilization of the biomass carbon content which is about 2.5 times higher than carbon utilization associated with traditional cellulosic ethanol production. If the electrical power source needed for HTSE is based on nuclear or renewable energy, the process is carbon neutral. INL has demonstrated improved biomass processing prior to gasification. Recyclable biomass in the form of crop residue or energy crops would serve as the feedstock for this process. A process model

  8. "Fossil" Forecasting.

    Science.gov (United States)

    Brody, Michael J.; deOnis, Ann

    2001-01-01

    Presents a density study in which students calculate the density of limestone substrate to determine if the specimen contains any fossils. Explains how to make fossils and addresses national standards. (YDS)

  9. Introduction to selected references on fossil fuels of the central and southern Appalachian basin: Chapter H.1 in Coal and petroleum resources in the Appalachian basin: distribution, geologic framework, and geochemical character

    Science.gov (United States)

    Ruppert, Leslie F.; Lentz, Erika E.; Tewalt, Susan J.; Román Colón, Yomayra A.; Ruppert, Leslie F.; Ryder, Robert T.

    2014-01-01

    The Appalachian basin contains abundant coal and petroleum resources that have been studied and extracted for at least 150 years. In this volume, U.S. Geological Survey (USGS) scientists describe the geologic framework and geochemical character of the fossil-fuel resources of the central and southern Appalachian basin. Separate subchapters (some previously published) contain geologic cross sections; seismic profiles; burial history models; assessments of Carboniferous coalbed methane and Devonian shale gas; distribution information for oil, gas, and coal fields; data on the geochemistry of natural gas and oil; and the fossil-fuel production history of the basin. Although each chapter and subchapter includes references cited, many historical or other important references on Appalachian basin and global fossil-fuel science were omitted because they were not directly applicable to the chapters.

  10. Method of Hydrogenous Fuel Usage to Increase the Efficiency in Tandem Diverse Temperature Oxidation System

    Directory of Open Access Journals (Sweden)

    Zubkova Marina

    2016-01-01

    Full Text Available This paper presents the results of estimation energy efficiency, the collation data of thermodynamic calculations and data on material balance for an assessment of electric and thermal components in considered ways to use convention products, performance enhancement in the tandem system containing the high-temperature fuel cell and the low-temperature fuel cell with full heat regeneration for hydrogenous fuel (CH4. The overall effective efficiency (ηΣef. making full use of the recovered heat considered tandem system depends on the efficiency of its constituent fuel cells. The overall effective efficiency of the tandem installation including the fuel converter, separating system, high-temperature oxidation system, and hydrogen disposal system in case of fuel use in the low-temperature fuel cell, is higher than for each of the fuel cell elements separately.

  11. Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems

    Energy Technology Data Exchange (ETDEWEB)

    Pickrell, Gary [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States); Scott, Brian [Virginia Polytechnic Institute & State University, Blacksburg, VA (United States)

    2014-06-30

    This report covers the technical progress on the program “Novel Modified Optical Fibers for High Temperature In-Situ Miniaturized Gas Sensors in Advanced Fossil Energy Systems”, funded by the National Energy Technology Laboratory of the U.S. Department of Energy, and performed by the Materials Science & Engineering and Electrical & Computer Engineering Departments at Virginia Tech, and summarizes technical progress from July 1st, 2005 –June 30th, 2014. The objective of this program was to develop novel fiber materials for high temperature gas sensors based on evanescent wave absorption in optical fibers. This project focused on two primary areas: the study of a sapphire photonic crystal fiber (SPCF) for operation at high temperature and long wavelengths, and a porous glass based fiber optic sensor for gas detection. The sapphire component of the project focused on the development of a sapphire photonic crystal fiber, modeling of the new structures, fabrication of the optimal structure, development of a long wavelength interrogation system, testing of the optical properties, and gas and temperature testing of the final sensor. The fabrication of the 6 rod SPCF gap bundle (diameter of 70μm) with a hollow core was successfully constructed with lead-in and lead-out 50μm diameter fiber along with transmission and gas detection testing. Testing of the sapphire photonic crystal fiber sensor capabilities with the developed long wavelength optical system showed the ability to detect CO2 at or below 1000ppm at temperatures up to 1000°C. Work on the porous glass sensor focused on the development of a porous clad solid core optical fiber, a hollow core waveguide, gas detection capabilities at room and high temperature, simultaneous gas species detection, suitable joining technologies for the lead-in and lead-out fibers and the porous sensor, sensor system sensitivity improvement, signal processing improvement, relationship between pore structure and fiber

  12. Reducing the fuel temperature for pressure-tube supercritical-water-cooled reactors and the effect of fuel burnup

    Energy Technology Data Exchange (ETDEWEB)

    Nichita, E., E-mail: eleodor.nichita@uoit.ca; Kovaltchouk, V., E-mail: vitali.kovaltchouk@uoit.ca

    2015-12-15

    Highlights: • Typical PT-SCWR fuel uses single-region pins consisting of a homogeneous mixture of ThO{sub 2} and PuO{sub 2}. • Using two regions (central for the ThO{sub 2} and peripheral for the PuO{sub 2}) reduces the fuel temperature. • Single-region-pin melting-to-average power ratio is 2.5 at 0.0 MW d/kg and 2.3 at 40 MW d/kg. • Two-region-pin melting-to-average power ratio is 36 at 0.0 MW d/kg and 10.5 at 40 MW d/kg. • Two-region-pin performance drops with burnup due to fissile-element buildup in the ThO{sub 2} region. - Abstract: The Pressure-Tube Supercritical-Water-Cooled Reactor (PT-SCWR) is one of the concepts under investigation by the Generation IV International Forum for its promise to deliver higher thermal efficiency than nuclear reactors currently in operation. The high coolant temperature (>625 K) and high linear power density employed by the PT-SCWR cause the fuel temperature to be fairly high, leading to a reduced margin to fuel melting, thus increasing the risk of actual melting during accident scenarios. It is therefore desirable to come up with a fuel design that lowers the fuel temperature while preserving the high linear power ratio and high coolant temperature. One possible solution is to separate the fertile (ThO{sub 2}) and fissile (PuO{sub 2}) fuel materials into different radial regions in each fuel pin. Previously-reported work found that by locating the fertile material at the centre and the fissile material at the periphery of the fuel pin, the fuel centreline temperature can be reduced by ∼650 K for fresh fuel compared to the case of a homogeneous (Th–Pu)O{sub 2} mixture for the same coolant temperature and linear power density. This work provides a justification for the observed reduction in fuel centreline temperature and suggests a systematic approach to lower the fuel temperature. It also extends the analysis to the dependence of the radial temperature profile on fuel burnup. The radial temperature profile is

  13. Fossil Explorers

    Science.gov (United States)

    Moran, Sean; McLaughlin, Cheryl; MacFadden, Bruce; Jacobbe, Elizabeth; Poole, Michael

    2015-01-01

    Many young learners are fascinated with fossils, particularly charismatic forms such as dinosaurs and giant sharks. Fossils provide tangible, objective evidence of life that lived millions of years ago. They also provide a timescale of evolution not typically appreciated by young learners. Fossils and the science of paleontology can, therefore,…

  14. Marquee Fossils

    Science.gov (United States)

    Clary, Renee; Wandersee, James

    2008-01-01

    Professors of an online graduate-level paleontology class developed the concept of marquee fossils--fossils that have one or more unique characteristics that capture the attention and direct observation of students. In the classroom, Marquee fossils integrate the geology, biology, and environmental science involved in the study of fossilized…

  15. Index Fossils

    Indian Academy of Sciences (India)

    Fossils are actually vestiges of plants or animals preserved in strata of earth that give evidences of their presence in the geologic past [1]. In a strict sense, fossils include not only the remains of organisms or their parts but also any thing connected with an organism proving its existence (trace fossil). Thus, a chemical which ...

  16. Irradiation performance of AGR-1 high temperature reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Demkowicz, Paul A., E-mail: paul.demkowicz@inl.gov [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Hunn, John D. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Ploger, Scott A. [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Morris, Robert N.; Baldwin, Charles A. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Harp, Jason M.; Winston, Philip L. [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Gerczak, Tyler J. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States); Rooyen, Isabella J. van [Idaho National Laboratory, PO Box 1625, Idaho Falls, ID 83415-6188 (United States); Montgomery, Fred C.; Silva, Chinthaka M. [Oak Ridge National Laboratory, PO Box 2008, Oak Ridge, TN 37831-6093 (United States)

    2016-09-15

    Highlights: • Post-irradiation examination was performed on AGR-1 coated particle fuel. • Cesium release from the particles was very low in the absence of failed SiC layers. • Silver release was often substantial, and varied considerably with temperature. • Buffer and IPyC layers were found to play a key role in TRISO coating behavior. • Fission products palladium and silver were found in the SiC layer of particles. - Abstract: The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.6% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel including the extent of fission product release and the evolution of kernel and coating microstructures was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of {sup 110m}Ag from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocarbon and compact matrix. The capsule-average fractional release from the compacts was 1 × 10{sup −4} to 5 × 10{sup −4} for {sup 154}Eu and 8 × 10{sup −7} to 3 × 10{sup −5} for {sup 90}Sr. The average {sup 134}Cs fractional release from compacts was <3 × 10{sup −6} when all particles maintained intact SiC. An estimated four particles out of 2.98 × 10{sup 5} in the experiment experienced partial cesium release due to SiC failure during the irradiation, driving {sup 134}Cs fractional release in two capsules to approximately 10{sup −5}. Identification and characterization of these particles has provided unprecedented insight into

  17. Direct dimethyl ether fueling of a high temperature polymer fuel cell

    DEFF Research Database (Denmark)

    Jensen, Jens Oluf; Vassiliev, Anton; Olsen, M.I.

    2012-01-01

    Direct dimethyl ether (DME) fuel cells suffer from poor DME–water miscibility and so far peak powers of only 20–40 mW cm−2 have been reported. Based on available literature on solubility of dimethyl ether (DME) in water at ambient pressure it was estimated that the maximum concentration of DME...... at 80 °C will be 300–600 times lower than the ratio 1 to 3 which is the stoichiometric ratio for full conversion to CO2. To overcome this dilution problem a high temperature polymer fuel cell was operated on DME–water vapor at ambient pressure and with air as oxidant. A peak power density of 67 mW cm−2...... was measured at 200 °C. A series of performance curves at temperatures ranging from 150 to 250 °C showed a pronounced temperature effect on the performance. Comparison was made between performances as direct DME and direct methanol cells and the difference was not as large as normally seen with conventional...

  18. Tactical techno-economic analysis of electricity generation from forest, fossil, and wood waste fuels in a heating plant

    Directory of Open Access Journals (Sweden)

    Palander Teijo

    2012-01-01

    Full Text Available The Finnish energy industry is subject to policy decisions regarding renewable energy production and energy efficiency regulation. Conventional electricity generation has environmental side-effects that may cause global warming. Renewable fuels are superior because they offer near-zero net emissions. In this study, we investigated a heating mill's ability to generate electricity from forest fuels in southern Finland on a 1-year strategic decision-making horizon. The electricity-generation, -purchase, and -sales decisions are made using three different energy efficiency and forest technology rates. Then the decision environment was complicated by the sequence-dependent procurement chains for forest fuels (below-ground on a tactical decision-making horizon. With this aim, fuel data of three forest fuel procurement teams were collected for 3 months. The strategic fuel procurement decisions were adjusted to the changed decision environment based on a tactical techno-economic analysis using forest technology rates. The optimal energy product and fuel mixtures were solved by minimizing procurement costs, maximizing production revenues, and minimizing energy losses.

  19. Irradiation performance of AGR-1 high temperature reactor fuel

    Energy Technology Data Exchange (ETDEWEB)

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuel–including the extent of fission product release and the evolution of kernel and coating microstructures–was evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 1×10 4 to 5×10 4 for 154Eu and 8×10 7 to 3×10 5 for 90Sr. The average 134Cs release from compacts was <3×10 6 when all particles maintained intact SiC. An estimated four particles out of 2.98×105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization

  20. Aircraft and Bases Powered by Compact Nuclear Reactors: Solutions to Projecting Power in Highly Contested Environments and Fossil Fuel Dependence

    Science.gov (United States)

    2015-05-01

    deuterium, and lithium are plentiful on the earth and in the solar system. As far as fuel for existing and future fission reactors, uranium and...number of operating centrifuges and its stockpile of low- enriched uranium. In return, the United States promised fewer economic sanctions. President...vessels, and bases. Like fission, fusion reactors have options for fuel. These options include hydrogen, deuterium, lithium , and helium-3. The first

  1. What a future for fossil fuels? Will scientific and technological progresses warrant growth of use in carbon-based fuels?; Quel avenir pour les combustibles fossiles? Les avancees scientifiques et technologiques permettront-elles la poursuite d'un developpement soutenable avec les energies carbonees?

    Energy Technology Data Exchange (ETDEWEB)

    Tissot, B. [Commission Nationale d' Evaluation, 75 - Paris (France)

    2001-12-01

    The world demand for primary energy keeps increasing and has little chance to decrease over the next decades, when considering the desirable and necessary development of the less wealthy countries. The two weightiest questions are to provide electricity to megalopolis, and fuels for transportation. In the present situation, fossil fuels (crude oil, natural gas and coal) provide 90 % of primary energy. Furthermore, hydrocarbons (crude oil and gas) are considered as closing energies to balance the level of demand. However, the link between fossil fuel consumption for one and a half century and climate change is now considered as highly probable. Crude oil and natural gas reserves are substantial, but limited. One half of the proven reserves of crude oil, and one third of gas reserves will be already used in year 2020. Gas reserves will be sufficient to reach 2050, but proven reserves of crude oil will not last until that year. Coal only, which is the largest source of CO{sub 2} and pollutants, provides enough reserves for several centuries. A considerable effort of scientific and technological research is the only way to reach the end of the century using oil and gas, plus a drastic effort for saving energy. This effort in research is discussed in the paper, but it does not provide until now an answer to the climate problem. (author)

  2. Platinum redispersion on metal oxides in low temperature fuel cells

    DEFF Research Database (Denmark)

    Tripkovic, Vladimir; Cerri, Isotta; Nagami, Tetsuo

    2013-01-01

    We have analyzed the aptitude of several metal oxide supports (TiO2, SnO2, NbO2, ZrO2, SiO2, Ta2O5 and Nb2O5) to redisperse platinum under electrochemical conditions pertinent to the Proton Exchange Membrane Fuel Cell (PEMFC) cathode. The redispersion on oxide supports in air has been studied...... in detail; however, due to different operating conditions it is not straightforward to link the chemical and the electrochemical environment. The largest differences reflect in (1) the oxidation state of the surface (the oxygen species coverage), (2) temperature and (3) the possibility of platinum...... dissolution at high potentials and the interference of redispersion with normal working potential of the PEMFC cathode. We have calculated the PtOx (x = 0, 1, 2) adsorption energies on different metal oxides' surface terminations as well as inside the metal oxides' bulk, and we have concluded that NbO2 might...

  3. Research of power fuel low-temperature vortex combustion in industrial boiler based on numerical modelling

    Directory of Open Access Journals (Sweden)

    Orlova K.Y.

    2017-01-01

    Full Text Available The goal of the presented research is to perform numerical modelling of fuel low-temperature vortex combustion in once-through industrial steam boiler. Full size and scaled-down furnace model created with FIRE 3D software and was used for the research. All geometrical features were observed. The baseline information for the low-temperature vortex furnace process are velocity and temperature of low, upper and burner blast, air-fuel ratio, fuel consumption, coal dust size range. The obtained results are: temperature and velocity three dimensional fields, furnace gases and solid fuel ash particles concentration.

  4. Sustainability Impact Assessment on the Production and Use of Different Wood and Fossil Fuels Employed for Energy Production in North Karelia, Finland

    Directory of Open Access Journals (Sweden)

    Matias Pekkanen

    2012-11-01

    Full Text Available The utilization rate of woody biomass in eastern Finland is high and expected to increase further in the near future as set out in several regional, national and European policies and strategies. The aim of this study was to assess the sustainability impacts of changes in fuel consumption patterns. We investigated fossil and woody biomass-based energy production chains in the region of North Karelia, focusing on some economic, environmental and social indicators. Indicators were selected based on stakeholder preferences and evaluated using the Tool for Sustainability Impact Assessment (ToSIA. The analysis was based on representative values from National Forest Inventory data, scientific publications, national and regional statistics, databases, published policy targets and expert opinion. From the results it became evident that shifting from fossil to wood-based energy production implies some trade-offs. Replacing oil with woody biomass in energy production would increase the local value added remaining in the region, create employment opportunities and would reduce total GHG emissions. However, firewood, wood chips from small-diameter trees from early thinning and wood pellets have high production costs. Moreover, large greenhouse gas emission resulted from wood pellet production. The case study generated valuable reference data for future sustainability assessments and demonstrated the usefulness of ToSIA as a tool presenting existing knowledge on sustainability impacts of alternative energy supply chains to inform decision making.

  5. Impacts of proposed RCRA regulations and other related federal environmental regulations on Fossil Fuel-Fired Facilities: Final report, Volume 1

    Energy Technology Data Exchange (ETDEWEB)

    1987-03-01

    In order to fulfill its responsibilities, DOE contracted with Engineering-Science to perform a multi-phase engineering and economics study to evaluate the impact of the proposed RCRA regulations and other related federal environmental regulations on coal-fired utilities. This Interim Phase I report presents the findings of the impacts of proposed RCRA and related federal regulations on the utility sector fossil fuel-fired facilities. Subsequent phases involve parallel engineering studies on the industrial sector as well as economic evaluations. The framework of this study was based on the development and analysis (engineering and economic) of four regulatory scenarios for the disposal of fly ash, bottom ash and FGD sludge from the utility industry.

  6. Methods for nitrogen oxides (NO{sub x}) control in fossil fuel power stations; Metodos para control de oxidos de nitrogeno (NO{sub x}) en centrales termoelectricas

    Energy Technology Data Exchange (ETDEWEB)

    Romo Millares, Cesar A.; Huerta Espino, Mario [Instituto de Investigaciones Electricas, Cuernavaca (Mexico)

    1994-03-01

    In this article the different existing methods for nitrogen oxides (NO{sub x}) control in fossil fuel power stations, mainly those related to operational parameters and to burners design, that show a decisive influence on the formation or destruction of the NO{sub x}, are delineated. Also, a review of the new technologies of low NO{sub x} generation burners and of their basic operational principles, is presented. [Espanol] En este articulo se describen los diversos metodos existentes para el control de oxidos de nitrogeno (NO{sub x}) en centrales termoelectricas, principalmente aquellos que tienen que ver con los parametros operativos y de diseno en quemadores, y que muestran una influencia decisiva en la formacion o destruccion de los NO{sub x}. Se presenta ademas una revision de las nuevas tecnologias de quemadores de baja produccion de NO{sub x} y sus principios basicos de operacion.

  7. Reactor Design for CO2 Photo-Hydrogenation toward Solar Fuels under Ambient Temperature and Pressure

    Directory of Open Access Journals (Sweden)

    Chun-Ying Chen

    2017-02-01

    Full Text Available Photo-hydrogenation of carbon dioxide (CO2 is a green and promising technology and has received much attention recently. This technique could convert solar energy under ambient temperature and pressure into desirable and sustainable solar fuels, such as methanol (CH3OH, methane (CH4, and formic acid (HCOOH. It is worthwhile to mention that this direction can not only potentially depress atmospheric CO2, but also weaken dependence on fossil fuel. Herein, 1 wt % Pt/CuAlGaO4 photocatalyst was successfully synthesized and fully characterized by ultraviolet-visible light (UV-vis spectroscopy, X-ray diffraction (XRD, Field emission scanning electron microscopy using energy dispersive spectroscopy analysis (FE-SEM/EDS, transmission electron microscopy (TEM, X-ray photoelectron spectroscopy (XPS, and Brunauer-Emmett-Teller (BET, respectively. Three kinds of experimental photo-hydrogenation of CO2 in the gas phase, liquid phase, and gas-liquid phase, correspondingly, were conducted under different H2 partial pressures. The remarkable result has been observed in the gas-liquid phase. Additionally, increasing the partial pressure of H2 would enhance the yield of product. However, when an extra amount of H2 is supplied, it might compete with CO2 for occupying the active sites, resulting in a negative effect on CO2 photo-hydrogenation. For liquid and gas-liquid phases, CH3OH is the major product. Maximum total hydrocarbons 8.302 µmol·g−1 is achieved in the gas-liquid phase.

  8. The combined effect of reduced fossil fuel consumption and increasing biomass combustion on Athens' air quality, as inferred from long term CO measurements.

    Science.gov (United States)

    Gratsea, Myrto; Liakakou, Eleni; Mihalopoulos, Nikos; Adamopoulos, Anastasios; Tsilibari, Eirini; Gerasopoulos, Evangelos

    2017-08-15

    To evaluate the role of biomass burning emissions, and in particular of residential wood heating, as a result of the economic recession in Greece, carbon monoxide (CO) atmospheric concentrations from five (5) stations of the National Air Pollution Monitoring Network in Athens, spanning the period 2000-2015, in conjunction with black carbon (BC) concentrations from the NOA (National Observatory of Athens) station at Thissio were analysed. The contribution of the different sources to the diurnal cycle of these two pollutants is clear, resulting to a morning peak, mainly due to traffic, and a late evening peak attributed both to fossil fuel (traffic plus central heating) and biomass combustion. Calculated morning and evening integrals of CO peaks, for the investigated period, show consistent seasonal modulations, characterised by low summer and high winter values. The summer and winter morning CO peak integrals demonstrate an almost constant decreasing trend of CO concentrations over time (by almost 50% since 2000), attributed to the renewal of passenger car fleet and to reduced anthropogenic activities during the last years. On the other hand, an increase of 23%-78% (depending on the monitoring site) in the winter evening integrals since 2012, provides evidence of the significant contribution of biomass combustion, which has prevailed over fossil fuel for domestic heating. CO emitted by wood burning was found to contribute almost 50% to the total CO emissions during night time (16:00-5:00), suggesting that emissions from biomass combustion have gained an increasing role in atmospheric pollution levels in Athens. Copyright © 2017 Elsevier B.V. All rights reserved.

  9. Δ14CO2from dark respiration in plants and its impact on the estimation of atmospheric fossil fuel CO2.

    Science.gov (United States)

    Xiong, Xiaohu; Zhou, Weijian; Cheng, Peng; Wu, Shugang; Niu, Zhenchuan; Du, Hua; Lu, Xuefeng; Fu, Yunchong; Burr, George S

    2017-04-01

    Radiocarbon ( 14 C) has been widely used for quantification of fossil fuel CO 2 (CO 2ff ) in the atmosphere and for ecosystem source partitioning studies. The strength of the technique lies in the intrinsic differences between the 14 C signature of fossil fuels and other sources. In past studies, the 14 C content of CO 2 derived from plants has been equated with the 14 C content of the atmosphere. Carbon isotopic fractionation mechanisms vary among plants however, and experimental study on fractionation associated with dark respiration is lacking. Here we present accelerator mass spectrometry (AMS) radiocarbon results of CO 2 respired from 21 plants using a lab-incubation method and associated bulk organic matter. From the respired CO 2 we determine Δ 14 C res values, and from the bulk organic matter we determine Δ 14 C bom values. A significant difference between Δ 14 C res and Δ 14 C bom (P < 0.01) was observed for all investigated plants, ranging from -42.3‰ to 10.1‰. The results show that Δ 14 C res values are in agreement with mean atmospheric Δ 14 CO 2 for several days leading up to the sampling date, but are significantly different from corresponding bulk organic Δ 14 C values. We find that although dark respiration is unlikely to significantly influence the estimation of CO 2ff , an additional bias associated with the respiration rate during a plant's growth period should be considered when using Δ 14 C in plants to quantify atmospheric CO 2ff . Copyright © 2017 Elsevier Ltd. All rights reserved.

  10. The spatial distribution of fossil fuel CO2 traced by Δ(14)C in the leaves of gingko (Ginkgo biloba L.) in Beijing City, China.

    Science.gov (United States)

    Niu, Zhenchuan; Zhou, Weijian; Zhang, Xiaoshan; Wang, Sen; Zhang, Dongxia; Lu, Xuefeng; Cheng, Peng; Wu, Shugang; Xiong, Xiaohu; Du, Hua; Fu, Yunchong

    2016-01-01

    Atmospheric fossil fuel CO2 (CO2ff ) information is an important reference for local government to formulate energy-saving and emission reduction in China. The CO2ff spatial distribution in Beijing City was traced by Δ(14)C in the leaves of gingko (Ginkgo biloba L.) from late March to September in 2009. The Δ(14)C values were in the range of -35.2 ± 2.8∼15.5 ± 3.2 ‰ (average 3.4 ± 11.8 ‰), with high values found at suburban sites (average 12.8 ± 3.1 ‰) and low values at road sites (average -8.4 ± 18.1 ‰). The CO2ff concentrations varied from 11.6 ± 3.7 to 32.5 ± 9.0 ppm, with an average of 16.4 ± 4.9 ppm. The CO2ff distribution in Beijing City showed spatial heterogeneity. CO2ff hotspots were found at road sites resulted from the emission from vehicles, while low CO2ff concentrations were found at suburban sites because of the less usage of fossil fuels. Additionally, CO2ff concentrations in the northwest area were generally higher than those in the southeast area due to the disadvantageous topography.

  11. New technologies for the reduction of the use of fossil fuels in automobiles; Nuevas tecnologias para la reduccion del uso de combustibles fosiles en automoviles

    Energy Technology Data Exchange (ETDEWEB)

    Maya Violante, A.; Dorantes Rodriguez, R. [Universidad Autonoma Metropolitana, Unidad Azcapotzalco, Departamento de Energia, Mexico D. F. (Mexico)

    1995-12-31

    The new technologies developed for the reduction of the use of fossil fuels in automobiles can be classified by the way these try to reduce the use of energy. In the search for the technologies for the conservation of it the environmental problem is added, that although it is not the subject of this presentation results decisive for the evaluation of the performance of type of technology. The development of technologies in this field has followed three basic tendencies. First: The efficient improvement of internal combustion motors, which consist in the control and constant monitoring the functioning of these motors in order to determine the strictly necessary consumption for the motor operation in accordance with its load conditions. Second, the development of a system that utilizes alternate fuels, as is the case of hybrid vehicles, that utilize gas turbines that can burn these fuels. Third the development of electric driven and energy regeneration systems avoiding the use of fossil fuels. A fourth tendency could be considered, which consists in determining the best way of controlling and using the transportation time, with all the implicit benefits. The purpose of this paper is to answer all these questions beginning with a detailed revision of the main technological innovations developed by the leading car manufacturers at world level, such as BMW, Mercedes Benz, Ford, etc. concerned in bringing to the market the best vehicles that burn less or none fossil fuels and at the same time comply with the every day more strict standards on the environmental pollution subject. Through these innovations the advantages and disadvantages of each one of them are set forth, with special emphasis in the technologies that, to our concern, will be the most convenient to promote in the years to come. [Espanol] Las nuevas tecnologias desarrolladas para la reduccion del uso de combustibles fosiles en automoviles se pueden caracterizar por la manera en que estas tratan de reducir

  12. Investigation of black and brown carbon multiple-wavelength-dependent light absorption from biomass and fossil fuel combustion source emissions

    Science.gov (United States)

    Michael R. Olson; Mercedes Victoria Garcia; Michael A. Robinson; Paul Van Rooy; Mark A. Dietenberger; Michael Bergin; James Jay Schauer

    2015-01-01

    Quantification of the black carbon (BC) and brown carbon (BrC) components of source emissions is critical to understanding the impact combustion aerosols have on atmospheric light absorption. Multiple-wavelength absorption was measured from fuels including wood, agricultural biomass, coals, plant matter, and petroleum distillates in controlled combustion settings....

  13. Combustion starter and maintenance burner for pulverized solid fossil fuels, and combustion chamber equipped with burners of the kind

    Energy Technology Data Exchange (ETDEWEB)

    Vidal, J.; Malaubier, F.; Mevel, J-C.

    1990-05-15

    A power station boiler is described, which is fired by pulverized coal. The boiler has an axial conduit for feeding the pulverized fuel in a primary combustion supporting gas. The burner incorporates a flame detector and an igniter in the refractory tap-hole or in the axial conduit. The advantage of the burner is improved efficiency and reduced operating cost.

  14. Assessing the current Brazilian sugar cane industry and directing developments for maximum fossil fuel mitigation for the international petrochemical market

    NARCIS (Netherlands)

    Brehmer, B.; Sanders, J.P.M.

    2009-01-01

    The EU proposes that 5.75% of the transportation fuels market consist of biofuels by 2010 and the USA proposes that all gasoline be blended with 10% bioethanol by 2012. While these targets have not yet been reached, an aura of critique is emerging, arguing that biofuel mandates are not sustainable.

  15. Perspectives on gasification systems to produce energy carriers and other chemicals with low CO2 emissions : techno‐economic system analysis on current and advanced flexible thermo‐chemical conversion of fossil fuels and biomass

    NARCIS (Netherlands)

    Meerman, J.C.

    2012-01-01

    To prevent dangerous climate change, the emissions of anthropogenic greenhouse gasses (GHG) need to be reduced. Two key mitigation options to reduce GHG involve a transition from the current fossil-fuel based infrastructure towards one based on renewable and the implementation of CO2 capture,

  16. Analytical approximations for temperature dependent thermophysical properties of supercritical diesel fuel surrogates used in combustion modeling

    Science.gov (United States)

    Kumar, Abhinav; Saini, Vishnu; Dondapati, Raja Sekhar; Usurumarti, Preeti Rao

    2017-07-01

    Supercritical fluid technology is introduced to combat the critical challenges related with emissions, incomplete and clean diesel fuel combustion. The chemical kinetics of diesel fuel is a strong function of temperature. As surrogate fuels have a potential to represent a real diesel fuel, thermophysical properties of such fuels have been studied in this present work as a function of temperature. Further, two diesel surrogate fuels which have been identified as the components of actual diesel fuel for jet engines are studied and thermophysical properties of these two surrogates are evaluated as a function of temperature at critical pressure. In addition, the accuracy and reliability of the developed correlations is estimated using two statistical parameters such as Absolute Average of Relative Error (AARE) and Sum of Average Residues (SAR). Results show an excellent agreement between the standard data and the correlated property values.

  17. Electrochemical Impedance Spectroscopy (EIS) Characterization of Reformate-operated High Temperature PEM Fuel Cell Stack

    DEFF Research Database (Denmark)

    Sahlin, Simon Lennart; Simon Araya, Samuel; Andreasen, Søren Juhl

    2017-01-01

    This paper presents an experimental characterization of a high temperature protonexchange membrane fuel cell (HT-PEMFC) short stack carried out by means of impedance spectroscopy. Selected operating parameters; temperature, stoichiometry and reactant compositions were varied to investigate...

  18. Ediacara Fossils

    Science.gov (United States)

    Science Teacher, 2005

    2005-01-01

    Now, a research team from Virginia Tech and Nanjing Institute of Geology and Paleontology has discovered uniquely well-preserved fossil forms from 550-million-year-old rocks of the Ediacaran Period. The research appears in the Proceedings of the National Academy of Sciences. The discovery of these unusually preserved fossils reveals unprecedented…

  19. Index Fossils

    Indian Academy of Sciences (India)

    Permanent link: http://www.ias.ac.in/article/fulltext/reso/011/10/0069-0077. Keywords. Index fossil; guide fossil; correlation; age determination; Dicroidium; Glossopteris. Author Affiliations. Dipanjan Ghosh1. Biological Science Department Kirnahar Shib Chandra High School Kirnahar, Birbhum 731302, West Bengal, India.

  20. Experimental Study of the Stability of Aircraft Fuels at Elevated Temperatures

    Science.gov (United States)

    Vranos, A.; Marteney, P. J.

    1980-01-01

    An experimental study of fuel stability was conducted in an apparatus which simulated an aircraft gas turbine fuel system. Two fuels were tested: Jet A and Number 2 Home Heating oil. Jet A is an aircraft gas turbine fuel currently in wide use. No. 2HH was selected to represent the properties of future turbine fuels, particularly experimental Reference Broad Specification, which, under NASA sponsorship, was considered as a possible next-generation fuel. Tests were conducted with varying fuel flow rates, delivery pressures and fuel pretreatments (including preheating and deoxygenation). Simulator wall temperatures were varied between 422K and 672K at fuel flows of 0.022 to 0.22 Kg/sec. Coking rate was determined at four equally-spaced locations along the length of the simulator. Fuel samples were collected for infrared analysis. The dependence of coking rate in Jet A may be correlated with surface temperature via an activation energy of 9 to 10 kcal/mole, although the results indicate that both bulk fluid and surface temperature affect the rate of decomposition. As a consequence, flow rate, which controls bulk temperature, must also be considered. Taken together, these results suggest that the decomposition reactions are initiated on the surface and continue in the bulk fluid. The coking rate data for No. 2 HH oil are very highly temperature dependent above approximately 533K. This suggests that bulk phase reactions can become controlling in the formation of coke.