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Sample records for teknologi nuklir vi

  1. Proceedings of the Sixth Seminar on Computation in Nuclear Science and Technology; Lokakarya Komputasi dalam Sains dan Teknologi Nuklir VI

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1997-07-01

    National Atomic Energy Agency (BATAN) had held the Sixth Seminar on Computation in Nuclear Science and Technology on January 16-17, 1996. The seminar is an event for information exchange among interest society in computation, modeling, and simulation. Similar as previous seminar in the past year, there were also non-BATAN and university-bound presenters and participants whose interest are in the field of science and technology. Examining the papers presented in this seminar, it shows that beside digging the so called classical computation methods, some papers brought relatively new topics like the determination and influence of chaos, neural network method, and expert system. Judging from the variety of the topics, one can conclude that interests in computation and its application are growing stronger in Indonesia.

  2. Moving mesh finite element method for finite time extinction of distributed parameter systems with positive exponential feedback; Lokakarya Komputasi dalam Sains dan Teknologi Nuklir VI

    Energy Technology Data Exchange (ETDEWEB)

    Garnadi, A D [Department of Matematics, Bogor Institute of Agriculture, Bogor (Indonesia)

    1997-07-01

    In the distributed parameter systems with exponential feedback, non-global existence of solution is not always exist. For some positive initial values, there exist finite time T such that the solution goes to infinity, i.e. finite time extinction or blow-up. Here is present a numerical solution using Moving Mesh Finite Element to solve the distributed parameter systems with exponential feedback close to blow-up time. The numerical behavior of the mesh close to the time of extinction is the prime interest in this study.

  3. Teknologi med arkitektonisk kvalitet

    DEFF Research Database (Denmark)

    Sørensen, Peter

    2001-01-01

    Kortfattet artikel om forholdet mellem arkitektonisk fremtræden og den valgte teknologi. Der beskrives to principielt forskellige tilgange til teknologi som redskab for arkitektur: den anonyme teknologi og den synonyme teknologi. Disse to begreber relateres til den aktuelle Projekt-Hus debat om...

  4. Teknologi med arkitektonisk kvalitet

    DEFF Research Database (Denmark)

    Sørensen, Peter

    2001-01-01

    Kortfattet artikel om forholdet mellem arkitektonisk fremtræden og den valgte teknologi. Der beskrives to principielt forskellige tilgange til teknologi som redskab for arkitektur: den anonyme teknologi og den synonyme teknologi. Disse to begrebet relateres til den aktuelle Projekt-Hus debat om...

  5. Tablet-teknologi i fysioterapi

    DEFF Research Database (Denmark)

    Duus, Lene; Støve, Morten Pallisgaard; Harbo, Michael

    2015-01-01

    Projektbaggrund og formål: Med projektet har vi ønsket at udvikle, afdække, implementere og afprøve funktionalitet og design af en app-baseret elektronisk genoptræningsportal. I projektet er der afprøvet en app. rettet mod fysioterapeuten og en app. rettet mod patienten. Formålet var at afdække u...... undervisning i teknologien samt løbende support højt, hvorfor tidsaspektet for deltagerne bliver vigtig. Reference: www.ucviden.dk, Duus, L & Støve Morten P, 2014. Tablet-teknologi i Fysioterapi....

  6. Den humane teknologi

    DEFF Research Database (Denmark)

    Fausing, Bent

    2008-01-01

    Artiklen undersøger hverdagsæstetikkens forestillinger om teknologi i tv-reklamer, nærmere bestemt to mobiltelefoner fra Nokia. Nokias slogan er som bekendt: "Nokia -connecting people". Hvilken funktion tilskrives denne succes-teknologi via billeder, narrativer, lyde, interaktioner og affekter...... personifikation eller antropomorfisering er vigtig for branding af den ny teknologi. Teknologien bliver betragtet som skaber af en teknotranscendens mod en mere kvalificeret humanitet, som er i kontakt med fundamentale humane værdier som intuition, fantasi og sansning. Det drejer sig i alle tilfælde om kvaliteter...

  7. PERKEMBANGAN TEKNOLOGI KOMUNIKASI

    Directory of Open Access Journals (Sweden)

    Yuliyanto Budi Setiawan

    2008-01-01

    Full Text Available Perkembangan teknologi komunikasi di dunia (termasuk Indonesia dapat membuat perubahan pada sikap dan perilaku penggunanya. Hal ini memunculkan dampak positif dan negatif. Untuk contoh dampak positif: jika pengguna ingin mencari informasi, mereka hanya perlu browsing di internet. Hal ini membuat aktivitas mereka menjadi lebih mudah dan sederhana. Untuk contoh dampak negatifnya: anak-anak dapat mengakses situs porno. Hal ini membuat degradasi/turunnya kepribadian mereka. Jadi, kita harus bijaksana saat menggunakan teknologi.

  8. Arkitektur, materialer, teknologi

    DEFF Research Database (Denmark)

    2004-01-01

    En redigeret samling af bidrag til en "tænkt" lærebog om arkitektur, materialer og teknologi, udført af studerende i forbindelse med kursus 0.021. Bygning, produkt og projekt, september 2004. Består af ca. 100 artikler, inddelt efter materialer som tegl, træ, sten, beton, metal, glas, plast...

  9. Tatalaksana Teknologi Informasi Metode Cobit

    OpenAIRE

    Hamzah, Ardi

    2006-01-01

    Metode COBIT perlu diterapkan dalam pengelolaan perusahaan agar penggunaan Teknologi Informasi (TI) sesuai dengan kebutuhan perusahaan dan menghasilkan kinerja yang efisien dan efektif serta mencegah atau meminimalisir adanya risiko terhadap penggunaan TI. Penggunaan dan pengelolaan TI juga mempertimbangkan integrasi dimana perangkat keras, perangkat lunak dan perangkat manusia membangun intergrasi.Kata kunci: metode COBIT, teknologi informasi, perangkat keras, perangkat lunak dan perangkat m...

  10. Danske 4. klasseelever er bedre end gennemsnittet til matematik og natur/teknologi

    DEFF Research Database (Denmark)

    Middelboe, Vibe Abildtrup

    2016-01-01

    En ny undersøgelse af 4. klasseelevers præstationer i fagene matematik og natur/teknologi viser, at danske elever klarer sig godt internationalt set, og at vi i Danmark har mange elever, der er meget dygtige til matematik. Men den negative sociale arv er fortsat stærk, og lærerne oplever mere stø...

  11. Forførende teknologi

    DEFF Research Database (Denmark)

    Agger Nielsen, Jeppe

    casestudie i tre kommuner, hvordan og i hvilken form mobil teknologi omsættes til praksis og eventuelt institutionaliseres i den kommunale hjemmepleje. Forskningsmæssigt bidrager afhandlingen til institutionel teori og information system (IS) forskningsområdet, og afhandlingens er positioneret i relation til....... Afhandlingen argumenterer for, at mobil teknologi i hjemmeplejen med fordel kan forstås i en bredere socio-politisk og inter-organisatorisk sammenhæng, snarere end som en simpel it-løsning designet til at forandre administrative arbejdsgange i hjemmeplejen, idet dynamikken i det organisatoriske felt har haft...

  12. PENINGKATAN KINERJA SISTEM KESELAMATAN PASIF PADA REAKTOR NUKLIR DENGAN PENAMBAHAN KOMPONEN RVACS

    Directory of Open Access Journals (Sweden)

    A. G. Abdullah

    2014-07-01

    Full Text Available Kelengkapan sistem keselamatan pasif dan inheren pada reaktor lanjut merupakan prasyarat utama. Makalah ini mengeksplorasi hasil desain konseptual sistem pembuang sisa panas pada pusat listrik tenaga nuklir berjenis Very High-Temperature Reactor. Tujuan riset ini untuk merancang sistem pembuang sisa panas pusat listrik tenaga nuklir yang terdapat pada dinding reaktor. Studi kinerja Reactor Vessel Auxliary Cooling System (RVACS dilakukan pada dua jenis pendingin yaitu Timbal-Bismut dan Liquid Salt. Panas dari dinding reaktor dihapus melalui sirkulasi alamiah pada keadaan tunak. Analisis melibatkan sistem perpindahan panas secara radiasi, konduksi dan konveksi alami. Perhitungan perpindahan panas dilakukan pada elemen reaktor vessel, dinding luar guard vessel, dan pelat pemisah. Hasil analisis kecelakaan menunjukkan kedua jenis sistem pendingin reaktor dan sistem pasif sisa pembuangan panas cukup menghapus sisa panas hasil peluruhan dengan sirkulasi alami.ABSTRACTCompleteness of passive safety systems and inherent in advanced reactors is a major prerequisite. This paper explores the results of a conceptual design of the heat removal system at the nuclear power plant (NPP type Very High-Temperature Reactor. The purpose of this research was to design the reactor vessel auxiliary cooling system (RVACS of NPP located within the reactor walls. The RVACS performance study was conducted on two types of coolant: Lead-Bismuth and Liquid Salt. Heat was removed from the reactor vessel through the natural circulation in the steady state. Analyses of heat transfer systems involved radiation, conduction and natural convection. Heat transfer calculations were performed on the reactor vessel, guard vessel, and perforated plate. The results from the accident analysis showed that both types, the reactor coolant system and the passive residual heat removal system, adequately remove remaining heat of the decay by a natural circulation.

  13. Proceeding of the Fifth Scientific Presentation on Nuclear Fuel Cycle: Development of Nuclear Fuel Cycle Technology in Third Millennium; Presentasi Ilmiah Daur Bahan Bakar Nuklir V: Pengembangan Teknologi Daur Bahan Bakar Nuklir Dalam Menyongsong Milenium Ketiga

    Energy Technology Data Exchange (ETDEWEB)

    Suripto, A; Sastratenaya, A S; Sutarno, D [National Atomic Energy Agency, Serpong (Indonesia); and others

    2000-03-08

    The proceeding contains papers presented in the Fifth Scientific Presentation on Nuclear Fuel Element Cycle with theme of Development of Nuclear Fuel Cycle Technology in Third Millennium, held on 22 February in Jakarta, Indonesia. These papers were divided by three groups that are technology of exploration, processing, purification and analysis of nuclear materials; technology of nuclear fuel elements and structures; and technology of waste management, safety and management of nuclear fuel cycle. There are 35 papers indexed individually. (id)

  14. TINJAUAN KEAMANAN SISTEM PADA TEKNOLOGI CLOUD COMPUTING

    Directory of Open Access Journals (Sweden)

    Yuli Fauziah

    2014-01-01

    Full Text Available Dalam perspektif teknologi informasi, cloud computing atau komputasi awan dapat diartikan sebagai suatu teknologi yang memanfaatkan internet sebagai resource untuk komputasi yang dapat di-request oleh pengguna dan merupakan sebuah layanan dengan pusat server bersifat virtual atau berada dalam cloud (internet itu sendiri. Banyak perusahaan yang ingin memindahkan aplikasi dan storage-nya ke dalam cloudcomputing. Teknologi ini menjadi trend dikalangan peneliti dan praktisi IT untuk menggali potensi yang dapat ditawarkan kepada masyarakat luas. Tetapi masih banyak isu keamanan yang muncul, karena teknologi yang masih baru. Salah satu isu keamanannya adalah Theft of Information, yaitu pencurian terhadap data yang disimpan di dalam Storage aplikasi yang menggunakan teknologi Cloud Computing. Kerugian yang akan diperoleh oleh pengguna teknologi ini sangat besar, karena informasi yang dicuri menyangkut data rahasia milik perusahaan, maupun data-data penting lainnya.Beberapa tindakan untuk mencegah terjadinya pencurian data ini, yaitu dengan  menghindari jenis ancaman keamanan berupa kehilangan atau kebocoran data dan pembajakan account atau service, serta Identity Management dan access control adalah kebutuhan yang utama bagi SaaS Cloud computing perusahaan. Dan salah satu metode yang digunakan dalam keamanan data aspek autentikasi dan otorisasi pada aplikasi atau service cloud computing adalah teknologi Single-sign-on. Teknologi Single-sign-on (SSO adalah teknologi yang mengizinkan pengguna jaringan agar dapat mengakses sumber daya dalam jaringan hanya dengan menggunakan satu akun pengguna saja. Teknologi ini sangat diminati, khususnya dalam jaringan yang sangat besar dan bersifat heterogen, juga pada jaringan cloud computing. Dengan menggunakan SSO, seorang pengguna hanya cukup melakukan proses autentikasi sekali saja untuk mendapatkan izin akses terhadap semua layanan yang terdapat di dalam jaringan. Kata Kunci : Storage, Aplikasi, Software as a

  15. Penerapan Teknologi Cloud Computing Di Universitas Studi Kasus: Fakultas Teknologi Informasi Ukdw

    OpenAIRE

    Kurniawan, Erick

    2015-01-01

    Teknologi Cloud Computing adalah paradigma baru dalam penyampaian layanan komputasi. Cloud Computing memiliki banyak kelebihan dibandingkan dengan sistem konvensional. Artikel ini membahas tentang arsitektur cloud computing secara umum dan beberapa contoh penerapan layanan cloud computing beserta manfaatnya di lingkungan universitas. Studi kasus yang diambil adalah penerapan layanan cloud computing di Fakultas Teknologi Informasi UKDW.

  16. Identifikasi Materi Mata Kuliah Teknologi Kendaraan Lanjut

    Directory of Open Access Journals (Sweden)

    Joko Sriyanto

    2010-10-01

    Full Text Available Tujuan dari penelitian ini adalah untuk menentukan isi/materi mata kuliah Teknologi Kendaraan Lanjut (TKL di Jurusan Pendidikan Teknik Otomotif Fakultas Teknik Universitas Negeri Yogyakarta. TKL merupakan salah satu mata kuliah yang dikembangkan oleh Jurdiknik Otomotif FT UNY untuk mewadahi perkembangan terkini teknologi otomotif yang akan mulai diberlakukan pada tahun ajaran 2009/2010.Permasalahan di atas dicari jawabannya dengan mengembangkan konsensus dari expert panel yaitu dosen dan praktisi bidang otomotif menggunakan metode Delphi. Metode Delphi adalah suatu metode yang digunakan untuk memperoleh pendapat dan konsensus dari sekelompok ahli (expert secara sistematis melalui serangkaian kuesioner tanpa harus mempertemukan mereka secara langsung/tatap muka. Dua putaran Delphi akan digunakan untuk mengumpulkan data dan mengembangkan konsensus. Hasil penelitian menunjukkan bahwa teknologi terbaru di bidang otomotif yang harus diberikan kepada mahasiswa berdasarkan konsensus dari para ahli di bidang otomotif adalah: (1 Common rail, (2 ASV (Advanced Safety Vehicle, (3 Intellegent Tester seri 2, (4 Hybrid System, dan (5 Smart Entry System.

  17. Teknologi Pengolahan Air Limbah Rumah Sakit

    Directory of Open Access Journals (Sweden)

    Prayitno - -

    2012-05-01

    Full Text Available Abstrak Air limbah rumah sakit mengandung polutan yang bersifat toksid, infeksius, bahkan radioaktif sehingga berpotensi menimbulkan dampak terhadap pencemaran lingkungan dan kesehatan masyarakat. Disamping itu dengan minimnya jumlah rumah sakit di Indonesia yang memiliki IPAL yaitu sebanyak 36%, dan yang memenuhi persyaratan IPAL sebesar 52% maka potensi dampak yang ditimbulkan akan semakin nyata. Pemilihan teknologi pengelolaan air limbah dengan demikian sangat penting. Makalah ini bertujuan untuk menganalisis aspek – aspek yang perlu dipertimbangkan dalam memilih jenis teknologi pengolalaan air limbah rumah sakit secara deskriptif. Dengan menggunakan pendekatan aspek teknis, aspek ekonomis dan aspek keberlanjutan terhadap beberapa teknologi pengolahan air limbah rumah sakit yang berkembangan saat ini, dapat direkomendasi bahwa kombinasi teknologi pengolahan biofilter anaerob – aerob dan ozonasi adalah  teknologi yang efektif dalam pengolahan air limbah rumah sakit.   Kata kunci: limbah rumah sakit, polutan, teknologi pengelolaan limbah Abstract Hospital wastewater contains pollutant which has been recognized toxic, infectious and radioactive that able to degrade environment and community health. In Indonesia, only 36% of hospital has wastewater treatment instrument (IPAL, and among them only 52% meet the national standard.  These situation potentially lead to pollution that threat environments. Promoting hospital water treatments therefore become significant. This reviews aims to analyze general aspect to choose proper technology for hospital water treatments. Using technical and  economical  aspects as well as sustainability perspective, it is recommended that combination of biofilter anaerob – aerob technology and ozonization is the effective strategy to manage and process hospital wastewater in Indonesia. Keywords: hospital wastewater, pollutant, wastewater threatment technology

  18. Proceeding of the Scientific Meeting and Presentation on Basic Research of Nuclear Science and Technology: Book II. Nuclear Chemistry, Process Technology, and Radioactive Waste Processing and Environment; Pertemuan dan Presentasi Ilmiah Penelitian Dasar Ilmu Pengetahuan dan Teknologi Nuklir. Buku II. Kimia Nuklir, Teknologi Proses, dan Pengolahan Limbah Radioaktif dan Lingkungan

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1996-06-01

    The proceeding contains papers presented on Scientific Meeting and Presentation on on Basic Research of Nuclear Science and Technology, held in Yogyakarta, 25-27 April 1995. This proceeding is second part of two books published for the meeting contains papers on nuclear chemistry, process technology, and radioactive waste management and environment. There are 62 papers indexed individually. (ID)

  19. Audit Layanan Teknologi Informasi Berbasis Information Technology Infrastructure Library (ITIL

    Directory of Open Access Journals (Sweden)

    Didin Herlinudinkhaji

    2015-12-01

    Full Text Available IT Service Management adalah salah satu cara untuk mengelola layanan teknologi informasi. Layanan teknologi perlu dikelola dengan baik untuk mendapatkan output dalam bentuk informasi yang dibutuhkan oleh manajemen. Untuk meningkatkan layanan teknologi informasi untuk lebih baik, diperlukan audit meliputi audit layanan teknologi informasi. Audit layanan teknologi informasi dilakukan untuk menentukan kelayakan teknologi informasi denngan terkait, dalam hal ini penulis berfokus pada isu-isu keamanan teknologi informasi. Audit keamanan teknologi informasi dibuat untuk menentukan tingkat keamanan untuk layanan teknologi informasi, sejauh mana informasi tersebut bisa sampai kepada yang berhak menerima, apakah informasi tersebut benar-benar tersedia, apakah informasi tersebut bersifat rahasia. Untuk dapat mengukur tingkat keamanan layanan teknologi informasi, penulis memilih untuk menggunakan metode Information Technology Infrastructure Library Versi 3 (ITIL V3. ITIL adalah set yang terdiri dari Layanan Strategi, Jasa Desain, Jasa Transisi, Layanan Operasi, dan terus-menerus Peningkatan Pelayanan. Dalam hal ini penulis berfokus pada layanan desain pada bagian dari manajemen keamanan informasi, pada bagian ini menjelaskan bagaimana layanan dikatakan baik jika memenuhi 8 poin yang telah distandarisasi secara internasional.

  20. Sæbeopera som Forestillingsgenererende Teknologi

    DEFF Research Database (Denmark)

    Waltorp, Karen

    2013-01-01

    Gennem en række empiriske eksempler fra Mauretanien, Danmark og Sydafrika analyserer artiklen dramaserier på tv som en art social teknologi, der tillader infor- manterne at generere forestillinger om andre liv og andre verdener, der på én gang er langt væk og tæt på. 'Soap operas' produceret i USA...

  1. Teknologi VRML untuk Media Promosi Mobil Berbasis Web

    Directory of Open Access Journals (Sweden)

    Aditya Nur Prasetyo

    2015-01-01

    Full Text Available Peranan teknologi informasi menjadi hal utama yang harus dipenuhi untuk menunjang kegiatan dalam berbagai bidang kehidupan, tidak terkecuali bidang promosi suatu produk atau jasa. Dengan penggunaan internet penyampaian informasi mengenai produk yang dipromosikan menjadi lebih mudah dan dapat diakses setiap saat dan dapat dilakukan dimana saja. Medianya pun juga telah berkembang dengan berbagai macam kemudahan, salah satunya adalah media promosi berbasis multimedia. Teknologi virtual reality merupakan salah satu teknologi yang berbasis multimedia dengan memadukan berbagai elemen multimedia. Dengan penggunaan teknologi virtual reality tersebut diharapkan dapat menunjang media promosi agar lebih interaktif, efektif dan menarik. Aplikasi yang dikembangkan merupakan perpaduan antara teknologi virtual reality dengan website. Teknologi virtual reality akan menyajikan produk mobil yang dipromosikan melalui tampilan tiga dimensi yang interaktif. Teknologi tersebut kemudian ditanamkan dalam website sehingga memungkinkan pengguna dapat mengaksesnya kapan dan dimana saja. Teknologi virtual reality dikembangkan menggunakan VRML (Virtual Reality Modelling Language dan software pemodelan 3D 3ds Max, sedangkan aplikasi berbasis web dikembangkan menggunakan bahasa pemrograman PHP, HTML dan CSS. Aplikasi tersebut juga didukung penggunaan basis data MySQL sehingga mempermudah user dalam mengolah data. Browser yang digunakan perlu dipasangi plug-in Cortona3D Viewer agar dapat menampilkan file tiga dimensi. Hasil dari pembuatan aplikasi ini adalah terancangnya sebuah aplikasi yang menggunakan teknologi VRML untuk media promosi mobil berbasis web. Hasil pengujian menunjukkan bahwa aplikasi ini menjalankan fungsionalitasnya sesuai dengan rancangan.

  2. RANCANGAN TATAKELOLA TEKNOLOGI INFORMASI UNTUK PABRIK PUPUK

    Directory of Open Access Journals (Sweden)

    Kridanto Surendro

    2008-01-01

    Full Text Available Many believe that information technology will be the major driver for economic wealth in the 21st century, but investing in information technology implementation on supporting corporate business process have a huge risk of failure because of the huge investment involved. There is a need of a comprehensive and structured IT governance from design until monitoring phase. This paper was trying to propose an IT governance model for a fertilizer company as a strategic state company in Indonesia’s macro economics. It identified current IT implementation, governance model requirements aligned with corporate resources and vision and mission base on COBIT standard. COBIT Standard is used because it has a good combination of the width and the depth of IT governance processes compared to other standards. Identification of current IT process maturity level showed that 50% of COBIT IT processes have maturity scale at 2, 37,5% at 1, and 12,5% at 3. None of current IT process maturity level had the same level with the expected one, so all of the process had a gap to be closed. The action in closing the maturity gap need a hard work for PT XYZ management. There are actions about defining policies and procedures, documentation of the defined policies and procedures, and a routine reviews of it. Abstract in Bahasa Indonesia: Teknologi Informasi diyakini sebagai pendukung utama tercapainya tujuan perusahaan di abad 21 ini, namun investasi penerapan teknologi informasi dalam menunjang proses bisnis suatu perusahaan mempunyai resiko kegagalan yang cukup besar dikarenakan nilai investasi yang menyertainya cukup besar. Untuk itu diperlukan suatu tatakelola teknologi informasi yang komprehensif dan terstruktur dari mulai perancangan sampai pengawasannya. Makalah ini mencoba memberikan suatu usulan model tatakelola teknologi informasi di sebuah pabrik pupuk yang merupakan salah satu BUMN yang mempunyai nilai strategis dalam menunjang makro ekonomi di Indonesia

  3. PENILAIAN TEKNOLOGI UNTUK MENENTUKAN POSISI INDUSTRI PESAING

    Directory of Open Access Journals (Sweden)

    Wahyu Susihono

    2013-02-01

    Full Text Available PT Sumiati Ekspor Internasinal bergerak pada usaha penjualan handycraft yang dipasok oleh lima industri kecil binaannya. Perusahaan akan melakukan privatisasi dalam waktu dekat, manajer pusat menginginkan ada satu industri kecil mengambil alih pengelolaan. Pihak manajemen perusahaan menghendaki ada penilaian teknologi secara internal dan eksternal kepada lima industri kecil binaanya sebagai dasar pengambilan keputusan. Dalam Penelitian ini dilakukan penilaian kepada semua industri kecil pemasokhandycraft dengan pendekatan model teknometrik, yaitu memperkirakan derajat sophistication komponen teknologi, evaluasi tiap komponen technoware, humanware, inforware dan organware dan menilai state-of-the-art. Kuesioner yang disebarkan dari lima industri kecil diolah menggunakan pairwise comparison Analytic Hierarchy Process”(AHP, dilanjutkan dengan perhitungan TCC (Technology Contribution Coefficient. Penilaian internal perusahaan dilakukan dengan model DEA (data envelopment analysis. Hasil akhir TCC dan DEA secara kuantitatif dibandingkan. Hasil TCC (Technology Contribution Coefficient secara berturut-turut dari industry yang memperoleh nilai terbesar adalah Industri Maharani 52.23%, Industri Bestari 42.87%, Industri Priyo 41.51%, Industri Rizky 32.66%, Industri Teguh 31.93%. Unsur kontribusi teknologi terbesar yang dihasilkan industri Maharani adalah organware, sedangkan empat perusahaan lainnya humanware. Unsur teknologi yang harus dikembangkan dalam jangka pendek untuk semua industri kecil adalah technoware. Hasil penilaian internal perusahaan dengan model DEA menunjukan bahwa industri Maharani mempunyai rangking tertinggi, sedangkan Industri Rizki pada rangking terrendah. Model teknometrik dikombinasi pairwise comparison AHP dan DEA dapat membantu perusahaan besar melakukan penilaian teknologi kepada industri kecil sejenis. Kata Kunci : penilaian teknologi, model teknometrik, pairwise comparison AHP, DEA   Abstract Sumiati Export International

  4. PENGADOPSIAN TEKNOLOGI RFID DI RUMAH SAKIT INDONESIA, MANFAAT DAN HAMBATANNYA

    Directory of Open Access Journals (Sweden)

    Iwan Vanany

    2009-01-01

    Full Text Available This paper explores the benefit and barriers of RFID (Radio Frequency Identification technology adoption in Indonesian hospitals context. The investigation methods of this research used interview and semi-structured questionnaire on RFID consultants, RFID researchers, and big hospital managers in Java Island. The benefits and barriers of RFID technology adoption are identified from literature review. The barriers of RFID technology adoption are divided into two aspects, i.e., as business and technology aspects. The results of this study suggest that the benefits of RFID technology adoption are dominated of intangible benefit. Most of the respondents believed that the main barriers of RFID technology adoption are (1 the complexity of RFID technology (2 the lack of complete and valid information, and (3 there is no sufficient budget available. The detail of the outcomes and the implications of this reasarch are also discussed. Abstract in Bahasa Indonesia: Makalah ini berupaya mengeksplorasi manfaat dan hambatan dari pengadopsian teknologi RFID (Radio Frequency Identification dalam konteks rumah sakit di Indonesia. Metode investigasi dari penelitian ini menggunakan wawancara dan kuesioner semi-struktur untuk konsultan, peneliti teknologi RFID dan manajer rumah sakit berkatagori besar di Pulau Jawa. Manfaat-manfaat dan hambatan-hambatan dari pengadopsian teknologi RFID telah diidentifikasi dari studi literatur. Hambatan dari pengadopsian teknologi RFID dibagi menjadi dua (2 aspek yaitu hambatan dari aspek bisnis dan teknologi. Temuan dari studi ini meyakini bahwa manfaat dari pengadopsian teknologi RFID didominasi oleh manfaat yang bersifat intangible. Sebagian besar responden meyakini bahwa hambatan utama dari pengadopsian teknologi RFID adalah: (1 kompleksnya teknologi RFID, (2 ketiadaan informasi yang lengkap dan valid, (3 tidak tersedianya anggaran yang cukup. Detail dari hasil studi dan implikasinya akan didiskusikan selanjutnya. Kata kunci

  5. SISTEM INVENTORI BARANG DENGAN TEKNOLOGI AJAX

    Directory of Open Access Journals (Sweden)

    Anna Fitriya

    2015-11-01

    Full Text Available ABSTRAK Sistem inventori barang pada pertokoan telah banyak dikembangkan untuk meningkatkan efektivitas dan efisiensi. Pada Toko Karya Indah, kegiatan yang berkaitan dengan inventori barang masih dilakukan secara manual sehingga pihak toko kesulitan untuk mengetahui data barang yang masih tersedia, habis, atau hampir habis. Selain itu, proses yang dilakukan membutuhkan waktu yang relatif lama. Oleh karena itu, diperlukan sistem inventori barang. Sistem dibangun dengan bahasa pemrograman PHP dan database MySQL. Sistem disertai teknologi AJAX (Asynchronous JavaScript And XML, khususnya AJAX autocomplete dan AJAX validasi. Hasil yang diperoleh adalah pengolahan data pada sistem inventori barang dengan menggunakan AJAX dapat dilakukan dengan lebih cepat dari pada tanpa AJAX. Kata kunci: sistem inventori, AJAX.

  6. PENINGKATAN KEMAMPUAN GURU DALAM PEMANFAATAN TEKNOLOGI INFORMASI PADA KEGIATAN PEMBELAJARAN

    Directory of Open Access Journals (Sweden)

    R. Ceha

    2016-01-01

    Full Text Available Dalam upaya peningkatan mutu mengajar dan mutu pembelajaran di era globalisasi, guru sebaiknya menguasai program komputer, agar dapat memanfaatkan teknologi yang telah tersedia dan untuk memudahkan dalam mengajar. Guru hendaknya dapat menggunakan peralatan yang lebih ekonomis, efisien, dan mampu dimiliki oleh sekolah, tidak menolak digunakannya peralatan teknologi modern yang relevan dengan tuntutan masyarakat dan perkembangan zaman, serta mempunyai berbagai keterampilan yang mendukung tugasnya dalam mengajar. Salah satu keterampilan tersebut adalah bagaimana seorang guru dapat menggunakan media pembelajaran (Syaiful Bahri, 2006. Guru dapat membuat kreasi dan variasi media interaktif, pembuatan CD pembelajaran interaktif, powerpoint, dan dengan media komputer. Masalah utama yang dihadapi mitra saat ini adalah kemampuan guru dalam pemanfaatan IT atau ICT untuk kegiatan pembelajaran belum merata. Selain itu juga masih adanya kesenjangan literasi TIK antar wilayah di satu sisi dan perkembangan internet yang juga membawa dampak negatif terhadap nilai dan norma masyarakat sehingga perlu dilakukan upaya secara aktif dari semua stakeholder sekolah dalam peningkatan kualitas pembelajaran dengan memanfaatkan teknologi informasi dan komunikasi. Kegiatan Pengabdian kepada masyarakat yang diusulkan bertujuan untuk meningkatkan pengetahuan guru mengenai pemanfaatan teknologi informasi dan komunikasi pada kegiatan pembelajaran, meningkatkan kemampuan guru untuk membuat bahan ajar pemanfaatan teknologi informasi dan komunikasi sehingga dapat mengoptimalkan potensi yang ada di sekolah mitra dalam pemanfaatan Teknologi Informasi untuk peningkatan kualitas pembelajaran

  7. ADOPSI TEKNOLOGI OLEH USAHA MIKRO, KECIL DAN MENENGAH

    Directory of Open Access Journals (Sweden)

    Margo Purnomo

    2011-09-01

    Full Text Available Penelitian ini menjelaskan tentang pentingnya kecocokan teknologi dalam manajemen usaha mikro, kecil dan menengah (UMKM. Dengan asumsi bahwa sebuah penerapan teknologi dapat memiliki dampak kinerja positif hanya jika cocok dengan tugas yang sedang didukungnya bukan tingkat kecanggihan teknologi. Sayangnya, tidak semua teknologi cocok dengan pekerjaan yang sedang didukungnya. Namun demikian, model yang paling sering dikutip lebih banyak dikarakteristikkan pada fokus pemanfaatan bukan pada kecocokannya. Berangkat dari kondisi ini, justru jika melihat perkembangannya terlihat bahwa telah terjadi metamorfosis model pengaruh teknologi informasi terhadap kinerja. Dengan ini diharapkan UMKM dapat memperoleh masukan dan pemahaman baru dalam penggunaan teknologi.This study explains the importance of suitable technology in Small and Medium Enterprerises (SMEs. An applied technology has a positive impact on performance, only if it is appropiate with the jobs that is supported, not with the level of sophisticated technology. Unfortunately, not all of such technology will be suitable with the jobs, they are supported. Nevertheless, model which is used to be cited is more being characterized in the focus of using, not in the appropiateness. Starting from this condition, if we are reffering to the development, there will be a metamorphosis model of technology influence toward performance. It is expected that UMKM will get some input and new understanding in the using of technology.

  8. Proceeding of the Fourth Scientific Presentation on Nuclear Fuel Cycle: Technology of Nuclear Fuel Cycle facing the Challenge of Energy Need on the 21-st Century; Prosiding presentasi ilmiah daur bahan bakar nuklir IV. Tema: teknologi daur bahan bakar nuklir menghadapi tantangan kebutuhan ketenagaan pada abad-21

    Energy Technology Data Exchange (ETDEWEB)

    Suripto, A [National Atomic Energy Agency, Serpong (Indonesia); Sajuti, D [Research and Development Center for Calibration Instrumentation and Metrology, Indonesian Institute of Sciences, Serpong (Indonesia); Aiman, S [Research and Development Center for Applied Chemistry, Indonesian Institute of Sciences, Serpong (Indonesia); Yuwono, I [National Atomic Energy Agency, Serpong (Indonesia); Fathurrachman, [National Atomic Energy Agency, Serpong (Indonesia); Suwarno, H [National Atomic Energy Agency, Serpong (Indonesia); Suwardi, [National Atomic Energy Agency, Serpong (Indonesia); Amini, S [National Atomic Energy Agency, Serpong (Indonesia); Widjaksana, [National Atomic Energy Agency, Serpong (Indonesia)

    1999-03-01

    The proceeding contains papers presented in the Fourth Scientific Presentation on Nuclear Fuel Element Cycle with theme of Technology of Nuclear Fuel Cycle facing the Challenge of Energy Need on the 21{sup s}t Century, held on 1-2 December in Jakarta, Indonesia. These papers were divided by three groups that are technology of exploration, processing, purification and analysis of nuclear materials; technology of nuclear fuel elements and structures; and technology of waste management, safety and management of nuclear fuel cycle. There are 36 papers indexed individually. (ID)

  9. SISTEM INFORMASI SECARA ONLINE TUGAS AKHIR MAHASISWA JURUSAN TEKNOLOGI INFORMASI FAKULTAS TEKNOLOGI INFORMASI DAN KOMUNIKASI

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    Atmoko Nugroho

    2015-08-01

    Full Text Available Tugas Akhir is the last stage that will surely passed by students to earn college scholarship. And one of the activities in the field of data administration is to manage file of Tugas Akhir, especially for the submission title and Coordinators of Tugas Akhir. Coordinators are often difficult to check the title of Tugas Akhir, if it has been filed or is pending, and the difficulties in monitoring the load guidance from their Supervisor of Tugas Akhir. This also forms the basis for making an Information System of Tugas Akhir (Sistem Informasi Tugas Akhir with the aim of assisting Jurusan Teknologi Informasi and students take this. Sistem Informasi Tugas Akhir called SITA also be made online this method applying Prototype system development. Prototype method according to Pressman has experienced several stages, namely: collection needs (listen to customers, design (built / REVISE mock-up and evaluation of prototypes (customer test-drives a mock-up. The collection needs to be done, among others, the acquisition of data. The data used in this information system is the data of Tugas Akhir of Jurusan Teknologi Informasi. The next stage in the design, researchers uses planning tool in the form of Unified Modeling Language system (UML and developed using the PHP programming language. System of web-based information created a purpose to be accessible without being restricted by time and place, whereas the benefit derived is facilitated student and coordinator duties in management of Tugas Akhir.

  10. Eksplorasi Teknologi Big Data Hadoop Untuk Sistem Aplikasi Berbasis Komunitas

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    Gede Karya

    2017-11-01

    Full Text Available Pada tahun 2014, telah dikembangkan aplikasi pembukuan untuk usaha mikro dan kecil (UMK berbasis mobile cloud. Aplikasi tersebut dikembangkan dengan teknologi mobile berbasis Android, teknologi web dan web service serta menggunakan basis data MySQL sebagai back-end. Dengan populasi usaha mikro sebanyak 55,1 juta unit usaha di Indonesia dan terus berkembang, maka aplikasi pembukuan UMK berpotensi digunakan oleh banyak user. Hal ini menimbulkan kebutuhan akan layanan pengelolaan data yang sangat besar baik volume maupun pertumbuhannya. Oleh karena itu, perlu dipersiapkan sisi back-end dengan teknologi big-data processing untuk menjamin ketersediaan dan kehandalan layanan kepada pengguna UMK. Makalah ini fokus pada eksplorasi teknologi big-data Hadoop yang saat ini banyak diterapkan untuk aplikasi komunitas seperti: Google, Facebook, Twitter, dan Amazon. Pembahasan diawali dengan studi tentang Hadoop dan ekosistemnya, kemudian merumuskan pola adopsi untuk aplikasi berbasis komunitas. Setelah itu pola dan teknologi tersebut diterapkan untuk mengembangkan back-end aplikasi pembukuan UMK berbasis mobile cloud. Hasil studi dan penerapannya menunjukkan bahwa Hadoop dapat diadopsi pada aplikasi pembukuan UMK khususnya HBase. Untuk memudahkan akses dan meminimalkan usaha modifikasi, maka akses HBase dari aplikasi dapat menggunakan Apache Phoenix Java Data Base Connectivity (JDBC dari beberapa opsi yang tersedia.

  11. Menakar Peranan Pustakawan dalam Implementasi Teknologi Informasi di Perpustakaan

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    Agung Nugrohoadhi

    2013-12-01

    Full Text Available Pustakawan dalam era teknologi informasi ini perlu mempersiapkan diri dalam menghadapi era perpustakaan digital. Kemampuan dalam beradaptasi dengan lingkungan ini amat diperlukan karena pemustaka sendiri tentunya  mengharapkan layanan yang berorientasi pada teknologi maju sehingga keakuratan data dan kecepatan informasi dapat diperoleh. Khususnya pada perpustakaan yang melayani lembaga perguruan tinggi akan selalu berkembang baik jumlah koleksi, fasilitas maupun pengembangan profesionalisme para pustakawan. Dalam mendukung aktivitas  kegiatan ini perpustakaan  diharapkan akan selalu sigap dalam menyiapkan kebutuhan pemustaka sehingga koleksi yang disediakan mampu mengimbangi kebutuhan informasi yang diperlukan.

  12. Hjelmkamera som opmærksomhedsunderstøttende teknologi

    DEFF Research Database (Denmark)

    Bøhm, Mikkel; Hagedorn-Rasmussen, Peter; Nickelsen, Niels Christian

    2016-01-01

    Anvendelsen af en relativt simpel teknologi i form af et hjelmkamera kan understøtte og ændre opmærksomhed under og efter håndteringen af en operativ indsats. Hjelmkameraet er fastgjort til den overordnede leder fra brandvæsenet (indsatslederen). Gennem hjelmkameraet er det muligt at opnå indsigt...

  13. The Communicative Ability of Universiti Teknologi MARA Sarawak's Graduates

    Science.gov (United States)

    Hassan, Sharifah Zakiah Wan; Hakim, Simon Faizal; Rahim, Mahdalela; Noyem, John Francis; Ibrahim, Sueb; Ahmad, Johnny; Jusoff, Kamaruzaman

    2009-01-01

    This study explores Universiti Teknologi MARA (UiTM) Sarawak graduating students' oral proficiency, focusing on grammatical accuracy. Oral proficiency in English has always been the benchmark of language proficiency, and in the context of UiTM's language teaching curriculum, efforts to enhance students' oral proficiency are implemented through…

  14. ADOPSI TEKNOLOGI PERTANIAN UNTUK PEMBANGUNAN PEDESAAN: SEBUAH KAJIAN SOSIOLOGIS

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    Apri Kuntariningsih

    2014-10-01

    Full Text Available ABSTRAKTeknologi pertanian diharapkan dapat membantu petani untuk meningkatkan kesejahteraan. Berbagai teknologi pertanian telah diperkenalkan dan disebarluaskan kepada petani, tetapi sebagian besar petani pedesaan masih dianggap tertinggal dari masyarakat lain. Kajian ini bertujuan  mempelajari kegagalan penyebaran teknologi pertanian dalam mengentaskan kemiskinan di daerah pedesaan. Berdasar kajian ini nantinya diharapkan mampu merumuskan strategi dari asepk sosiologis terkait penyebaran teknologi pertanian. Hasil kajian ini menunjukkan bahwa faktor sosial, ekonomi dan kelembagaan perlu mendapat perhatian lebih dari pembuat kebijakan baik di tingkat nasional dan lokal dalam rangka untuk meningkatkan dampak diseminasi teknologi pertanian dalam peningkatan kesejahteraan petani di daerah pedesaan.ABSTRACTAgricultural technology is expected to help farmers to improve welfare. Various agricultural technologies have been introduced and disseminated to farmers, but to some extents, peasants are still considered lag behind other communities. This paper is conducted investigate the failure of agricultural technologies dissemination in alleviating poverty in rural areas. This strudy showssocial, economic and institutional factors that need more attention from policy makers both at national and local levels in orde to improve impact of agricultural technology dissemination in escalating farmers’ welfare in rural areas. 

  15. DAMPAK NEGATIF PERKEMBANGAN TEKNOLOGI INFORMATIKA DAN KOMUNIKASI DAN CARA ANTISIFASINYA

    Directory of Open Access Journals (Sweden)

    I Gede Ratnaya

    2011-03-01

    Full Text Available Sampai saat ini perkembangan ilmu pengetahuan telah menghantarkan masyarakat menuju babak baru yaitu babak yang memanfaatkan peralatan-peralatan yang merupakan hasil dari teknologi. Penggunaan tenaga manusia yang semakin hari semakin kecil volumenya sering kali menyebabkan orang kehilangan pekerjaannya karena tugasnya telah tergantikan oleh peralatan atau mesin. Sebagai sarana penyampaian informasi dan komunikasi, komputer bisa dipakai sebagai sarana berinternetan. Lewat internet orang bisa mencari bermacam-macam informasi dan berkomunikasi. Peran yang dapat diberikan oleh aplikasi teknologi informasi ini adalah mendapatkan informasi untuk kehidupan pribadi seperti informasi tentang kesehatan, hobi, rekreasi, dan rohani. Selain memberikan keuntungan, ternyata peralatan teknologi informasi dan komunikasi juga memberikan dampak negatif bagi penggunanya. Dampak negatif tersebut muncul sebagai akibat dari penggunaan yang salah atau tidak bertanggung jawab dari yang menggunakan. Beberapa dampak negatif tersebut adalah 1. Anak lebih banyak menghabiskan waktu menonton TV ketimbang melakukan hal lainnya (seperti belajar dan olah raga, 2. Anak kehilangan kemampuan berbaur dengan masyarakat dan cenderung nyaman dengan kehidupan online, 3 Adanya pelanggaran hak cipta, 4.  Kejahatan di internet, 5. Penyebaran virus komputer, dan 6. Pornografi, perjudian, penipuan, tayangan kekerasan. Adapun cara mengatasi dampak-dampak negatif tersebut adalah : 1. Gunakan teknologi untuk menjalin hubungan dengan orang yang sudah dikenal, 2. Cari komunitas positif  yang sering melakukan pertemuan didunia nyata, 3. Perlunya penegakkan hukum yang berlaku dengan dibentuknya polisi internet, 4. Menghindari pemakaian telepon seluler yang berfitur canggih oleh anak-anak dibawah umur dan lebih mengawasi penggunaan telepon seluler, 5. Perbanyak membaca buku-buku yang bersifat edukatif dan bersifat keimanan serta aplikasi komputer yang bersifat mendidik, dan 6. Perlunya pengaturan

  16. IMPLEMENTASI TEKNOLOGI WEB SERVICES PADA APLIKASI PENCARIAN TAKSI

    Directory of Open Access Journals (Sweden)

    Debby Erce Sondakh

    2016-09-01

    Full Text Available Taksi merupakan layanan transportasi yang umum ditemui di daerah perkotaan. Untuk menggunakan layanan taksi pengguna dapat menunggu taksi yang lewat atau memesan melalui telepon. Kendala yang terjadi dari metode ini adalah panggilan telepon tidak tersambung karena operator sedang melayani konsumen lain, posisi taksi yang berada jauh dari konsumen, atau konsumen tidak mengetahui posisinya saat ini dengan tepat. Ketika menunggu taksi di jalan, pencarian taksi dapat memakan waktu lama. Makalah ini memaparkan tentang pengembangan aplikasi pencarian taksi berbasis teknologi Android, menggunakan model proses Rational Unified Process dari pendekatan rekayasa perangkat lunak. Implementasi teknologi web service menghasilkan aplikasi pencarian taksi terdekat yang dapat mengintegrasikan aplikasi berbasis web dengan platform berbeda, dengan aplikasi mobile berbasis sistem operasi Android. Pada aplikasi mobile, pengguna dapat mencari taksi terdekat sesuai perusahaan terdaftar yang dilacak menggunakan GPS dan melihat posisi taksi pada peta dari Google Maps Application Programming Interface, melihat informasi taksi, serta memesan taksi atau membatalkan pemesanan.

  17. Pemodelan Kanal Pada Jaringan Area Tubuh Nirkabel Menggunakan Teknologi Bluetooth

    Directory of Open Access Journals (Sweden)

    Rizal Nur Ibrahim

    2017-01-01

    Full Text Available Pada wireless body area network (WBAN, propagasi radio dari node sensor yang berada di permukaan tubuh manusia sangat kompleks dan unik bila dibandingkan dengan lingkungan yang lain karena tubuh manusia memiliki bentuk yang kompleks dan terdiri dari jaringan tubuh manusia yang berbeda-beda. Oleh karena itu, model kanalnya juga berbeda dengan model kanal di lingkungan lain. Telekomunikasi nirkabel pada aplikasi jaringan area tubuh membutuhkan Medium Access Control (MAC yang dapat beradaptasi, dinamis, dan fleksibel untuk mengatasi berbagai persyaratan aplikasi. MAC yang diusulkan menyesuaikan protokol komunikasi dan parameter yang berdasarkan kepada pencapaian konsumsi daya rendah dan laju data yang tinggi untuk itu dipilih salah satu teknologi komunikasi yang memungkinkan untuk hal ini yaitu Bluetooth. Pada tugas akhir ini akan dilakukan pemodelan kanal pada WBAN untuk mendapatkan bentuk kanal yang sesuai dengan kerakteristik tubuh manusia. Dimana pemodelan kanal ini di fokuskan pada teknologi Bluetooth dengan frekuensi 2,4 GHz. Selain itu, dalam pengerjaannya dilakukan simulasi menggunakan software MATLAB.

  18. Mucopolysaccharidosis VI

    Directory of Open Access Journals (Sweden)

    Harmatz Paul

    2010-04-01

    Full Text Available Abstract Mucopolysaccharidosis VI (MPS VI is a lysosomal storage disease with progressive multisystem involvement, associated with a deficiency of arylsulfatase B leading to the accumulation of dermatan sulfate. Birth prevalence is between 1 in 43,261 and 1 in 1,505,160 live births. The disorder shows a wide spectrum of symptoms from slowly to rapidly progressing forms. The characteristic skeletal dysplasia includes short stature, dysostosis multiplex and degenerative joint disease. Rapidly progressing forms may have onset from birth, elevated urinary glycosaminoglycans (generally >100 μg/mg creatinine, severe dysostosis multiplex, short stature, and death before the 2nd or 3rd decades. A more slowly progressing form has been described as having later onset, mildly elevated glycosaminoglycans (generally ARSB gene, located in chromosome 5 (5q13-5q14. Over 130 ARSB mutations have been reported, causing absent or reduced arylsulfatase B (N-acetylgalactosamine 4-sulfatase activity and interrupted dermatan sulfate and chondroitin sulfate degradation. Diagnosis generally requires evidence of clinical phenotype, arylsulfatase B enzyme activity ®, clinical management was limited to supportive care and hematopoietic stem cell transplantation. Galsulfase is now widely available and is a specific therapy providing improved endurance with an acceptable safety profile. Prognosis is variable depending on the age of onset, rate of disease progression, age at initiation of ERT and on the quality of the medical care provided.

  19. Kinerja Perusahaan Terkait dengan Terapan dan Kompetensi Teknologi Informasi

    Directory of Open Access Journals (Sweden)

    Eko Purwanto

    2014-06-01

    Full Text Available AbstractInvestment in information technology (IT implementation in organizations tends to increase manufacturing in Indonesia. Various studies show that implementation of IT that is applied has a major impact on company performance. This study aims to answer, whether at manufacturing organizations in Indonesia, the implementation of IT is applied and competencies have an impact, both directly and indirectly to the performance. The sample of this study is a company registered in the Department of Industry and Trade in East Java, which apply information and communication technologies in local area network. There are 117 companies with 500 employees or more participated in this study. Data were analyzed using SEM, with the application of SPSS and AMOS. The results of this study indicate that the more complete implementation of information technology applied in the company, and the higher the competence of knowledge in information technology, the higher the company's organizational performance is achieved.Keywords: Implementation IT, Competence IT, Organization Performance.AbstrakPenerapan investasi di bidang teknologi informasi (TI dalam organisasi perusahaan cenderung meningkat di Indonesia. Berbagai penelitian menunjukkan bahwa implementasi TI yang diterapkan memiliki dampak besar pada kinerja perusahaan. Penelitian ini bertujuan untuk menjawab, apakah implementasi kompetensi TI di organisasi perusahaan di Indonesia memiliki dampak, baik secara langsung maupun tidak langsung terhadap kinerja. Sampel penelitian ini adalah perusahaan yang terdaftar di Departemen Perindustrian dan Perdagangan di Jawa Timur yang mengaplikasikan informasi dan teknologi komunikasi dalam jaringan area lokal. Ada 117 perusahaan dengan 500 karyawan atau lebih berpartisipasi dalam penelitian ini. Data dianalisis dengan menggunakan SEM, dengan aplikasi SPSS dan AMOS. Hasil penelitian ini menunjukkan bahwa implementasi teknologi informasi yang lebih lengkap di perusahaan

  20. Teknologi Hijau Warisan Nenek Moyang di Tanah Parahyangan

    Directory of Open Access Journals (Sweden)

    Handajani Asriningpuri

    2015-08-01

    Full Text Available Masyarakat tradisional umumnya tidak berkebutuhan majemuk; sederhana; bersahaja; dan menerima keberadaan alam sebagai sahabat, bahkan merupakan bagian kehidupannya. Keadaan ini terjadi di Kampung Naga, Garut, Tanah Parahyangan sebagai suatu kearifan lokal. Dari sudut pandang arsitektur, hal tersebut menginspirasi konsep perancangan. Penelitian ini, membuktikan dari sudut pandang ilmu lingkungan dan arsitektur tentang adanya kaitan kearifan lokal dengan teknologi hijau yang menerapkan “green concept”(ZEB – Zero Energy Building dan 3R – Reuse, Reduce, Recycle. Metoda yang dilakukan adalah metoda diskriptif kualitatif berdasarkan data primer dan sekunder hasil observasi lapangan dan literatur. Kemudian dikaji melalui teori Aarsitektur dan pendekatan Teknologi Hijau, dan dibuktikan melalui Greenship Home Assestment (ketentuan GBCI – Green Building Council Indonesia Hasil kajian dan temuan pemahaman kearifan lokal, akan menginspirasi, membangkitkan semangat hijau, dan menambah wawasan bagiperancang bangunan. Bagi para regulator (pemerintah daerah kearifan lokal harus di pertahankan dan dapat menyadarkan penduduk kampung Naga untuk tetap berkehidupan sesuai ketentuan yang di yakini. Kata Kunci : Green Concept, Kampung Naga, Kearifan lokal, Teknologi Arsitektur

  1. Penerapan Framework COBIT untuk Identifikasi Tingkat Kematangan Tata Kelola Teknologi Informasi: Studi Kasus di Fasilkom Unwidha

    Directory of Open Access Journals (Sweden)

    Agustinus Suradi

    2017-07-01

    Full Text Available Perkembangan IT sebagai media komunikasi data hingga saat ini berkembang sangat pesat. Peranan teknologi informasi dalam suatu lembaga sangat krusial, namun  masalah  yang sering terjadi di lembaga/ instansi adalah penggunaan teknologi informasi yang ternyata tidak sesuai dengan harapan, oleh karena itu diperlukan tata kelola terhadap penggunaan teknologi informasi. Permasalahan yang dihadapi di Fasilkom Unwidha adalah adanya ketidak puasan layanan IT yang diberikan, terdapatnya gangguan layanan yang tidak segera diatasi, adanya koordinasi maintenance infrastruktur IT yang kurang optimal. Sehingga perlu adanya evaluasi terhadap tata kelola teknologi informasi yang diberikan untuk penyelarasan dengan tujuan organisasi agar visi yang diharapkan dapat tercapai. Penelitian ini membahas tentang kondisi tata kelola teknologi informasi di Fasilkom Unwidha, dan sejauh mana telah menerapkan tata kelola teknologi informasi yang baik. Metode analisis yang digunakan dalam penelitian ini adalah dengan menggunakan  framework Control Objectives for Information and Related Technology (COBIT. Hasil dari analisis ini berupa tingkat kematangan tata kelola  teknologi informasi  yang  mencerminkan  kondisi  tata  kelola  teknologi informasi  di  Fakultas Ilmu Komputer Unwidha. Tingkat kematangan dengan mengacu pada maturity level yang disediakan kerangka kerja COBIT, diperoleh nilai  kematangan 2,84 yaitu pada level Defined Process. Sistem memiliki ruang lingkup Business Goals sebanyak 13, IT Goals sebanyak 18, IT Process sebanyak 30 proses dan 4 Domain.

  2. TEKNOLOGI BIOMETRIK DENGAN METODE SIDIK JARI UNTUK SISTEM KEAMANAN DATABASE

    Directory of Open Access Journals (Sweden)

    Adhi Kusmantoro

    2006-07-01

    Full Text Available Keamanan dalam teknologi dunia maya pada saat sangat diperlukan mengingat banyaknya masyarakat yang telah mengakuiteknologi, sehingga kecenderungan banyak ingin mengetahui atau bahkan mencuri sesuatu rahasia super yang sifatnya atau hak cipta yang di bawah aeigis hukum untuk mencari keuntungan individu dengan crack atau lebih dikenal dengan hacker.

  3. Analisis Kontribusi Teknologi Dan Produktivitas Di PT. Surya Jaya Tulungagung

    Directory of Open Access Journals (Sweden)

    Veronika Yulia Kusumawati

    2014-09-01

    Full Text Available Abstrak   Teknologi memiliki peranan penting dalam perkembangan berbagai industri.Pentingnya pengetahuan mengenai produktivitas merupakan sarana untuk meningkatkan efisiensi dan efektivitas perusahaan. Metode penelitian ini menggunakan Technology Contribution Coefficient (TCC untuk mengukur kandungan teknologi, pembobotan kriteria dengan Analytical Hierarchy Process (AHP, pengukuran produktivitas dengan American Productivity Center (APC, dan diagram Ishikawa untuk menganalisis permasalahan di PT. Surya Jaya, Tulungagung. Hasil penelitian menyajikan : 1 Skor TCC sebesar 0.49 dengan komponen yang memberikan kontribusi penting secara berturut-turut adalah Humanware>Orgaware>Inforware>Technoware.2 Indeks produktivitas total mengalami kenaikan dari tahun 2011 sampai 2012 dengan nilai sebesar 102,38 dan 104, 3 Indeks profitabilitas total mengalami kenaikan dari tahun 2011 sampai 2012 sebesar 102,57 dan 104,47, 4 Indeks perubahan harga tidak mengalami kenaikan maupun penurunan dari tahun 2011 sampai 2012 dengan nilai 1,00, 5 Strategi yang harus diperbaiki berdasarkan diagram Ishikawa meliputi semua input yaitu bahan baku, tenaga kerja, energi dan modal.   Kata Kunci :Produktivitas, TCC, AHP, APC

  4. PENGARUH TECHNOLOGY READINESS TERHADAP PENERIMAAN TEKNOLOGI KOMPUTER PADA UMKM DI YOGYAKARTA

    Directory of Open Access Journals (Sweden)

    Mimin Nur Aisyah

    2014-10-01

    Full Text Available Abstrak: Pengaruh Technology Readiness terhadap Penerimaan Teknologi Komputer pada UMKM di Yogyakarta. Penelitian ini bertujuan untuk mengekplorasi pengaruh kesiapan teknologi terhadap persepsi kemanfaatan sistem dan persepsi kemudahan penggunaan sistem serta pengaruh kedua persepsi terhadap teknologi tersebut terhadap minat menggunakan teknologi komputer dalam membantu proses bisnis pada UMKM di Yogyakarta.  Sampel penelitian ini sejumlah 498 UMKM yang terdaftar di Disperindagkop Yogyakarta. Teknik pengambilan sampel menggunakan teknik simple random sampling. Data diperoleh menggunakan kuesioner. Analisis data dan uji hipotesis menggunakan model Partial-Least-Square (PLS. Penelitian ini menemukan bahwa terdapat pengaruh kesiapan teknologi terhadap persepsi kemanfaatan sistem dan persepsi kemudahan penggunaan sistem, serta terdapat pengaruh persepsi kemanfaatan teknologi dan persepsi kemudahan penggunaan teknologi terhadap minat menggunakan teknologi komputer dalam membantu proses bisnis pada UMKM di Yogyakarta.   Kata kunci: kesiapan teknologi, persepsi kemanfaatan, persepsi kemudahan penggunaan, minat menggunakan, UMKM Abstract: The Effect of Technology Readiness toward Acceptance of Computer Technology on SMEs in Yogyakarta. This research aims to explore the effect of technology readiness to the perceived of usefulness of system and perceived ease of use of the system and the influence of both perceptions of these technologies to the behavioral intention of computer technology in business processes in SMEs in Yogyakarta. The research sample number of 498 SMEs were registered in Disperindagkop Yogyakarta. The sampling technique using simple random sampling technique. The data were obtained using a questionnaire. Data analysis and hypothesis testing using a model of the Partial-Least-Square (PLS. The research found that there are significant technology readiness to the perception of the benefit system and perceived ease of use of the system

  5. Cranial mononeuropathy VI

    Science.gov (United States)

    ... Abducens palsy; Lateral rectus palsy; VIth nerve palsy; Cranial nerve VI palsy; Sixth nerve palsy; Neuropathy - sixth nerve ... Cranial mononeuropathy VI is damage to the sixth cranial nerve. This nerve is also called the abducens nerve. ...

  6. Kesiapan Operator Seluler dalam Mengimplementasikan Teknologi Long Term Evolution (LTE

    Directory of Open Access Journals (Sweden)

    Sri Ariyanti

    2012-06-01

    Full Text Available Penelitian ini bertujuan untuk mengetahui seberapa besar kesiapan operator seluler dalam mengimplementasikan teknologi Long Term Evolution (LTE. Model penelitian dengan menggunakan mengadopsi teknik Net Readiness Framwork. Adapun kriteria pengukurannya terdiri dari Leadership, Governance, Competencies dan Technology. Pengumpulan data dilakukan dengan menyebarkan kuesioner kepada operator seluler di Indonesia dan melakukan wawancara kepada regulator. Kajian ini menggunakan teknik analisis data kuantitatif deskriptif. Hasil penelitian menunjukkan bahwa PT. Axis, PT. HCPT dan PT. Telkomsel mempunyai tingkat kesiapan LTE Visionary yang berarti perusahaan sangat antusias dalam perubahan dan lebih dahulu mengambil resiko untuk mengimplementasikan LTE dalam organisasinya yang merupakan bagian yang tak terpisahkan proses bisnis perusahaan. PT. Indosat dan PT. XL mempunyai nilai kesiapan LTE leader  yang berarti perusahaan mampu mengadaptasi perubahan dan menginspirasi organsiasi lain dalam penerapan LTE. PT. Smartfren pada tingkat kesiapan LTE savvy yang berarti operator seluler memahami sebab dan efek dari perubahan dari munculnya LTE terhadap organisasi, namun belum melakukan adaptasi.

  7. Rancang Bangun Sistem Pilkades Menggunakan Teknologi Smart Card Sebagai Kartu Pemilih

    Directory of Open Access Journals (Sweden)

    I Putu Indra Permana

    2016-08-01

    Full Text Available Pemilihan Kepala Desa (Pilkades merupakan proses yang tidak terpisahkan dari Negara Indonesia sebagai negara demokrasi. Pilkades saat ini masih menggunakan sistem pemungutan suara (voting secara konvensional, menggunakan media kertas untuk melakukan proses pemilihan. Pelaksanaan sistem voting konvensional tersebut mempunyai banyak kelemahan seperti menghitung hasil voting relatif lebih lama dan menggunakan perhitungan manual. Perkembangan dan kemajuan teknologi informasi saat ini dapat dimanfaatkan untuk mendukung pelaksanaan voting Pilkades secara lebih baik yang menjadi solusi cerdas akan kemajuan teknologi yang dapat menggantikan sistem voting konvensional, yaitu dengan media sistem elektronik voting (e-voting menggunakan teknologi smart card sebagai kartu pemilih. Sistem dikemas dalam bentuk aplikasi yang dipasang/di-install pada komputer dan reader/writer tools sebagai media untuk membaca/menulis pada smart card. Sistem e-voting Pilkades dengan teknologi smart card telah berhasil dijalankan dan menghasilkan dashboard hasil voting Pilkades dengan menunjukkan jumlah voting dalam bentuk angka, persentase (%, grafik dan diagram.

  8. Dialogmøte om teknologi for trenging av fisk i merd

    OpenAIRE

    Henriksen, Kristian; Sunde, Leif Magne; Digre, Hanne; Svendsen, Erik; Rundtop, Per; Erikson, Ulf Gøran

    2013-01-01

    SINTEF Fiskeri og havbruk arrangerte den 19. mars 2013, i samarbeid med Fiskeri- og havbruksnæringens forskningsfond (FHF), et dialogmøte med fokus på teknologi for trenging av fisk i merd. Under møtet ble status for gjeldene teknologi og operasjoner for trenging av fisk i merd, samt resultater fra forskningsprosjekter tilknyttet trengeprosessen, presentert. Videre ble det samlet innspill om utfordringer tilknyttet trenging av fisk i produksjons- og ventemerd fra oppdrettsbedrifter, leverandø...

  9. Studi dan Uji Coba Teknologi Bluetooth sebagai Alternatif Komunikasi Data Nirkabel

    OpenAIRE

    Yulia, Yulia; Santoso, Leo Willyanto

    2004-01-01

    In Bahasa Indonesia : Bluetooth adalah suatu teknologi baru yang mulai dikenal dan digunakan. Teknologi ini memberikan Perubahan yang signifikan terhadap peralatan elektronik yang kita gunakan. Jika kita melihat sekeliling kita dimana keyboard dihubungkan pada komputer. Demikian juga halnya dengan printer, mouse, monitor dan lain sebagainya. Semua peralatan itu dihubungkan dengan menggunakan kabel. Akibatnya terjadi masalah banyak kabel yang dibutuhkan di kantor, rumah atau tempat-tempat...

  10. PENGARUH KESESUAIAN TUGAS-TEKNOLOGI, KUALITAS INFORMASI, DAN KUALITAS SISTEM TERHADAP KINERJA INDIVIDU PENGGUNA SISTEM ERP

    OpenAIRE

    WIJAYA OEI, SUFENNY

    2016-01-01

    2016 PENGARUH KESESUAIAN TUGAS-TEKNOLOGI, KUALITAS INFORMASI, DAN KUALITAS SISTEM TERHADAP KINERJA INDIVIDU PENGGUNA SISTEM ERP THE EFFECT OF TASK-TECHNOLOGY FIT, INFORMATION QUALITY, AND SYSTEM QUALITY TO ERP SYSTEM???S USER PERFORMANCE Sufenny Wijaya Oei Abdul Hamid Habbe Muhammad Achyar Ibrahim Penelitian ini bertujuan untuk menguji pengaruh kesesuaian tugas-teknologi, kualitas informasi, dan kualitas sistem terhadap kinerja individu pengguna sistem Enterpr...

  11. Biomedisinsk teknologi i idrett: Hvor går grensene?

    Directory of Open Access Journals (Sweden)

    Sigmund Loland

    2010-01-01

    Full Text Available I denne artikkelen drøfter jeg bruk av biomedisinsk teknologi i prestasjonsfremmende hensikt i konkurranseidrett. Mer presist utforsker jeg mulighetene for å skille mellom etisk akseptabel og etisk uakseptabel bruk. Jeg kritiserer WADAs normative grunnlag for å forby visse biomedisinske midler og metoder, og argumenterer for at eventuelle forbud må bygge på tydeligere verdisyn på idrett. Jeg undersøker to idealtypiske syn og deres teknologiske implikasjoner. Det smale synet er liberalt og avviser begrensninger i bruk av biomedisinske midler og metoder blant voksne idrettsutøvere som dårlig begrunnet paternalisme. Det brede synet innebærer en mer restriktiv holdning og aksepterer en viss regulering av trening og prestasjonsutvikling også utenfor konkurransene. I en avsluttende del veier jeg det smale og det brede synet mot hverandre og reflekterer over hvilket syn som vil dominere framtidens idrett.Nøkkelord: etikk, idrett, biomedisinsk teknologi, dopingEnglish summary: The use of biomedical technology in sport: Are there any limits?In the article I examine the use of biomedical technology to enhance performance in competitive sport. More specifically I examine the possibilities for distinguishing between ethically acceptable and ethically unacceptable use of such technology. I criticize the World Antidoping Agency's (WADA normative criterion for banning certain technologies as it is vague and unclear. I argue that any ban by WADA has to build on a clear and operational normative view of sport. Two relevant ideal-typical views are examined together with their technological implications. The narrow view is liberal and rejects restrictions on the use of biomedical technology among professional athletes as unjustifiable paternalism. The wider view implies a more restrictive approach and accepts certain regulations of performance-enhancing means and methods outside of competitions. In the conclusion, I compare the narrow and the wider

  12. Teknologi og etiske problematikker for selvkørende biler

    OpenAIRE

    Clarke, Danijel Charles; Thulstrup, Frederik Zeilberger; Gjermandsen, Niels Henrik Lind; Brodthagen, Morten

    2016-01-01

    Dette project undersøger de etiske problematikker, love omkring selvkørerende biler og hvordan mansikre sig at lovene fastlagt af regeringen, bliver overholdt. Vi har kigget på teknologien bag to selvkø-rerende biler, Tesla Model S og Junior. Til objektgenkendelse benytter Junior et Argumented DiscreteBayes Filter, mens Model S benytter et neuralt netværk. Til ruteplanlægning kunne vi kun finde algoritmerJunior benytter, som er baseret på A* algoritmen.Når selvkørerende biler bliver testet i ...

  13. TEKNOLOGI BERBASIS LAYANAN MANDIRI UNTUK KASUS E-BANKING

    Directory of Open Access Journals (Sweden)

    Edy Purwo Saputro

    2010-12-01

    Full Text Available Revolusi dan evolusi perkembangan teknologi informasi dan sistem informasi memicu transformasi dalam semua bidang dan hal ini kemudian menimbulkan fenomena tentang e-lifestyle yaitu mulai dari e-mail, e-banking, e-shopping, e-book, e-wallets, e-learning, e-news, e-commerce, e-trading, e-election, e-business, e-market, e-service dan e-cards. Di satu sisi, e-lifestyle memberikan banyak kemudahan tapi di sisi lain ini menimbulkan ancaman terutama dikaitkan dengan jaminan keamanan di semua transaksi yang terkait e-lifestyle. Terkait ini, jika aspek keamanan tidak mendapatkan prioritas perhatian dari semua pihak, maka akan terjadi fenomena: ‘don’t trust anyone, don’t trust anything’ dan kepercayaan akan menjadi “blind trust”. Hal ini tentu sangat dimungkinkan karena di cyber economy ada berbagai kasus yang mendasari misalnya ‘phising’ (kegiatan pengiriman e-mail palsu yang di dalamnya terkandung link ke sebuah situs web, yang bisa mengarahkan seseorang untuk menyerahkan identitas pribadi, atau ‘clickjacking’ (yaitu kode jahat yang tersembunyi di balik tombol klik di sebuah situs yang dikunjungi oleh seseorang. Aspek keamanan menjadi sangat penting karena fakta perkembangan e-lifestyle di Indonesia pada umumnya dan adopsi e-banking khususnya masih berada pada tahap pertumbuhan

  14. KOSEP PEMAHAMAN DAN TEKNOLOGI PENGELOLAAN SAMPAH DI RUMAH SUSUN SEWA

    Directory of Open Access Journals (Sweden)

    Henita Rahmayanti

    2016-01-01

    Full Text Available Penelitian ini bertujuan untuk merencanakan pengelolaan sampah di Tempat Penampungan Sampah yang terdapat di rumah susun sewa di Jakarta. Proses pengelolaan yang akan dilakukan dengan cara menanamkan konsep pemahaman pemilahan sampah organik dan anorganik di rumah masing-masing dan sistem pembuangan menggunakan saluran pembuangan secara terpisah. Prinsip pengelolaan sampah yang akan diterapkan yaitu merubah sampah yang tidak berguna menjadi bernilai guna. Semua sampah diolah dengan baik di Tempat Penampungan sampah sehingga tidak ada sampah yang diangkut keluar (Zero Waste. Teknologi pengelolaan sampah organik menggunakan sistem Anaerobic Digester sedangkan untuk pengelolaan sampah anorganik menggunakan sistem 4R (Reduce, Reuse, Recycle, Replace. Hasil dari pengelolaan sampah organik adalah kompos, limbah cair untuk budidaya ikan lele serta biogas. Untuk hasil sampah anorganik akan dijual kepada pengumpul barang bekas, digunakan sebagai bahan yang dapat diolah untuk berbagai kreasi dan dapat mempunyai nilai ekonomis. Proses ini memerlukan peran aktif dari masyarakat untuk mengelola sampah secara terus menerus sehingga dapat dijadikan contoh untuk tempat-tempat lain.

  15. Sistem Reminder Donor Darah dengan Memanfaatkan Teknologi Location Based Service

    Directory of Open Access Journals (Sweden)

    Ismail Abdus Shobar

    2016-11-01

    Full Text Available Donor darah merupakan kegiatan kemanusiaan yang bertujuan untuk membantu anggota masyarakat yang membutuhkan darah. Kegiatan donor darah diselenggarakan dan dikelola oleh Palang Merah Indonesia. Menurut catatan Palang Merah Indonesia, secara keseluruhan kebutuhan kantung darah yang tidak terpenuhi melebihi satu juta kantung darah. Untuk itu dibutuhkan peningkatan produksi kantung darah. Salah satu solusi yang dapat dilakukan adalah perancangan suatu sistem informasi geografis (GIS yang memudahkan pendonor untuk mendonorkan darahnya kembali dengan reminder donor darah dan membantu PMI mendapatkan kantung darah. Makalah ini membahas perancangan sistem reminder donor darah dengan menggunakan teknologi location based service. Kemudian untuk menguji sistem, dibuatkan sebuah prototype dengan hasil pengujian sistem menunjukkan bahwa sistem reminder donor darah dapat memudahkan pendonor dalam mendonorkan darahnya kembali sehingga memberikan motivasi bagi pendonor untuk lebih giat dalam mendonorkan darahnya. Sistem ini berpotensi meningkatkan produktivitas PMI dalam mengumpulkan kantong darah sehingga pemenuhan kebutuhan kantung darah masyarakat dapat meningkat yang pada akhirnya dapat menyelamatkan lebih banyak nyawa manusia khususnya di Indonesia. Kata kunci: donor darah, reminder, GIS, location based service.

  16. Pola Proses Penyebaran dan Penerimaan Informasi Teknologi Kamera DSLR

    Directory of Open Access Journals (Sweden)

    Sidiq Setyawan

    2017-10-01

    Full Text Available Abstrak   Kamera DSLR sebagai sebuah produk inovasi memiliki cara tersendiri untuk dapat diterima dan diadopsi oleh sebuah sistem sosial khususnya fotografer non profesional di Kota Solo. Difusi inovasi menjelaskan secara sistematis bagaimana sebuah produk inovasi DSLR disebarluaskan dan diterima oleh golongan inovasi di dalamnya. Sebagai sebuah bentuk komunikasi khusus, dalam teori difusi inovasi terdapat dua pokok utama kajian komunikasi, yakni bagaimana seorang komunikator maupun komunikan dalam golongan inovasi bertindak untuk menyebarkan pesan dan menerima pesan. Kedua pokok bahasan ini yang menjadi kunci bagaimana sebuah produk inovasi mampu efektif disebarkan dan diterima (diadopsi oleh golongan inovasi di dalamnya. Jenis penelitian ini adalah penelitian deskiptif kualitatif. Peneliti menggunakan metode studi kasus. Studi kasus cocok digunakan bila penelitian berkenaan dengan how dan why. Peneliti menjabarkan hasil dari penelitian yang dilakukan dalam bentuk narasi. Sampel dari populasi yang diambil melalui proses teknik cuplikan dengan maximum variation sampling atau pengambilan sampel variasi maksimum. Selain menggunakan teknik sampel variasi maksimum, peneliti menggunakan teknik cuplikan snowball sampling. Peneliti mengambil sampel fotografer non profesional di Kota Solo. Teknik pengumpulan data melalui in-depth interview (wawancara mendalam dan observasi lingkungan terhadap sampel penelitian. Untuk validasi data, peneliti menggunakan triangulasi sumber Hasil penelitian ini menunjukan bahwa memiliki memiliki karakteristik dan saluran komunikasi komunikasi tersendiri ketika mereka menerima informasi mengenai inovasi dan memutuskan untuk mengadopsi teknologi tersebut. Hal ini misalnya bisa dilihat dari pemilihan media dalam berkomunikasi dan menggunakan berbagai media untuk referensi mengumpulkan informasi terkait dengan inovasi.   Kata kunci: difusi inovasi, innovator, early adopter, early majority, late majority, pola komunikasi.

  17. PENGEMBANGAN PROFESIONALITAS BERKELANJUTAN GURU BERSERTIFIKAT PENDIDIK DI SMK RUMPUN TEKNOLOGI

    Directory of Open Access Journals (Sweden)

    Sujianto Sujianto

    2013-07-01

    Full Text Available Continuous development of certified teachers in vocational high school tech­no­logy clump. The purpose of this study is to describe the continuing professionality deve­lop­ment of teachers certifiedcertified teachers through investments investing in self-development educators, scientific publications, and innovative work wetherboth independently, in groups, or insti­tutionalizedinsti­tutionally. This research uses a descriptive quantitative study design study, with and  a the research subjects are who is certified vocational teachers educators asin Malang Raya. The Research research instruments used in this study are questionnaires and interview guides. The results of this study indi­cate that continuing professionality development of certified teachers certified in vocational educators high school clumps technology clump is still relatively low, most teachers only are categorized in the categories category of sometimes doing self-development investments, scientific publications, and innovative works. Tujuan penelitian ini untuk mendeskripsikan pengembangan profesionalitas berkelanjutan guru bersertifikat pendidik melalui investasi pengembangan diri, publi­kasi ilmiah, dan karya inovatif baik secara mandiri, berkelompok, atau melembaga. Penelitian ini menggunakan rancangan penelitian deskriptif kuantitatif, dengan subjek penelitian guru kejuruan bersertifikat pendidik se-Malang Raya. Instrumen penelitian menggunakan angket dan pedoman wawancara. Hasil penelitian ini menunjukkan bahwa pengembangan profesionalitas berkelanjutan guru berser­tifikat pendidik di SMK rumpun teknologi se-Malang Raya masih tergolong rendah, sebagian besar guru hanya kadang-kadang me­lakukan investasi pengembangan diri, publikasi ilmiah, dan membuat karya inovatif.

  18. Analisis Tata Kelola Teknologi Informasi Menggunakan Kerangka Kerja COBIT 4.1 pada Fakultas Teknik Undip

    Directory of Open Access Journals (Sweden)

    Arini Arumana

    2014-06-01

    Full Text Available Peran teknologi informasi dalam suatu instansi sudah tidak dapat dielakkan lagi, mengingat perkembangannya yang begitu pesat seiring berjalannya waktu. Namun masalah yang sering terjadi di instansi adalah penggunaan teknologi informasi yang kadang tidak sesuai dengan harapan. Oleh karena itu diperlukan tata kelola terhadap penggunaan teknologi informasi yang biasa disebut dengan IT Governance. Fakultas teknik UNDIP adalah salah satu fakultas yang dalam operasionalnya sangat mengandalkan teknologi informasi, baik dalam aktifitas belajar mengajar maupun dalam menjalankan operasional bisnis. Kondisi sekarang di Fakultas Teknik sendiri tidak terdapat suatu indikator yang dapat menyatakan bahwa kinerja TI yang berjalan telah sesuai dengan visi dan misi Fakultas Teknik, oleh karena itu perlu dilakukan analisis tata kelola teknologi informasi, guna mengetahui performa TI sekarang sesuai dengan yang diharapkan oleh managemen atau tidak. Hasil dari analisis ini berupa tingkat kematangan tata kelola TI yang mecerminkan kondisi tata kelola TI di Fakultas Teknik dengan mengacu pada maturity level yang disediakan kerangka kerja COBIT 4.1, yakni dari level 0 (non-existent sampai 5 (optimized. Berdasarkan analisis yang dilakukan, secara garis besar kondisi kematangan tata kelola TI Fakultas Teknik berada pada level 2 yakni repeatable but intuitive. Kondisi ini mengacu pada beberapa kelemahan dalam proses-proses TI yang berjalan, diantaranya penetapan dan dokumentasi tindakan, kebijakan dan prosedur yang minim, serta tidak tersedianya service level yang disetujui bersama.

  19. Katalog Penjualan Rumah Berbasis Android Menggunakan Teknologi Augmented Reality dan Virtual Reality

    Directory of Open Access Journals (Sweden)

    Alders Paliling

    2017-02-01

    Full Text Available Penerapan teknologi augmented reality kian diminati oleh pihak produsen untuk memasarkan produk  yang dihasilkan. Teknologi augmented reality mampu meproyeksikan objek dua dimensi ataupun tiga dimensi kedalam lingkungan nyata. Teknologi virtual reality mampu membawa pengguna masuk kedalam lingkungan virtual sehingga pengguna merasa berada dalam lingkungan virtual. Penelitian ini menggunakan teknologi augmented reality yang mampu memproyeksikan objek tiga dimensi rumah sehingga katalog menjadi lebih nyata,  dan teknologi virtual reality yang membuat pengguna berinteraksi langsung dengan objek tiga dimensi rumah dan merasa berada di dalam rumah. Aplikasi yang dibangun memanfaatkan sensor accelerometer yang tertanam dalam perangkat mobile android yang memungkinkan pengguna melihat seisi ruangan dengan memiringkan perangkat mobile android kekiri dan kekanan. Jumlah kamera virtual yang digunakan berjumlah lima yang diletakkan di ruang tamu, ruang keluarga, ruang kamar utama, ruang kamar anak, dan ruang dapur. Aplikasi ini berjalan pada platform android dan menggunakan personal komputer sebagai server yang menyimpan data informasi rumah. Dengan adanya aplikasi ini pengguna dapat merasakan suasana berbeda dalam melihat sebuah katalog. . Kata kunci—Augmentd Reality, Virtual Reality, Katalog, Android

  20. Hubungan Multitasking Teknologi Informasi Terhadap Produktivitas Kerja (Studi Kasus: Mahasiswa ITS

    Directory of Open Access Journals (Sweden)

    Galang Arga Marendha

    2017-01-01

    Full Text Available Pada era globalisasi saat ini cara hidup individu umumnya para remaja dan dewasa yang selalu bergerak cepat dalam mendapatkan informasi terbaru agar tidak tertinggal dari yang lain memungkinkan melakukan pekerjaan secara bersamaan. Mayoritas dari individu-individu menganggap melakukan banyak pekerjaan sekaligus dapat digunakan sebagai solusi yang tepat. Dengan kemajuan teknologi saat ini dan perilaku seperti itu, banyak sekali contoh pekerjaan yang dilakukan secara bersama-sama seperti halnya mengirim e-mail saat sedang menonton televisi maupun membuat laporan saat rapat. Teknologi informasi tersebut merupakan komponen yang mendukung peningkatan produktivitas kerja. Dalam hasil dari penelitian ini didapatkan perbandingan antara skenario 1 dengan 2 dan skenario 1 dengan 3 berpengaruh terhadap produktivitas kerja karena adanya penambahan tugas me-resume video dan mengerjakan 10 soal matematika, sedangkan perbandingan skenario 2 dengan skenario 3 didapatkan dari hasil wawancara terhadap responden bahwa tidak adanya pengaruh pada produktivitas kerja dikarenakan penambahan tugas me-resume video skenario 2 lebih sulit dari tugas me-resume video skenario 3 serta penambahan 10 soal matematika tidak menjadi masalah dalam pengerjaan skenario 3. Dalam hasil hubungan multitasking teknologi informasi skenario 1 didapatkan hasil 33,1% terhadap produktivitas kerja, kemudian hubungan multitasking teknologi informasi skenario 2 didapatkan hasil 23,6% terhadap produktivitas kerja, dan hubungan multitasking teknologi informasi skenario 3 didapatkan hasil 24,8% terhadap produktivitas kerja. Sehingga dari pengerjaan skenario 2 dan 3 produktivitas kerja responden menurun dikarenakan adanya tambahan kuantitas pengerjaan.

  1. APLIKASI MODEL PENERIMAAN TEKNOLOGI DALAM PENGGUNAAN SOFTWARE AUDIT OLEH AUDITOR

    Directory of Open Access Journals (Sweden)

    Dhini Suryandini

    2012-03-01

    Full Text Available Tujuan penelitian ini adalah untuk menguji faktor yang mempengaruhi penerimaan auditor dari perangkat lunak audit dengan menggunakan Model Penerimaan Teknologi (TAM. Data dikumpulkan dengan menggunakan metode survei melalui surat dan email yang dikirim ke auditor di 4 perusahaan-perusahaan CPA di Indonesia. Data dianalisis dengan menggunakan Partial Least Square (PLS. Metode tersebut merupakan metode alternatif Pemodelan Persamaan Struktur dengan menggunakan program aplikasi Smart PLS. Hasil penelitian ini menunjukkan bahwa ada hubungan positif antara perceived usefulness (PU dan attitude terhadap penggunaan audit software (ATT, antara perceived usefulness (PU dan actual use (AU, experience (EXP dan perceived usefulness (PU, dan computer-self-efficacy (CSE dan perceived ease of use (PEOU. Ada 2 faktor yang memiliki pengaruh signifikan baik secara langsung dan tidak langsung pada penerimaan auditor dari perangkat lunak audit. Perceived usefulnes mempunyai pengaruh positif secara langsung terhadap actual use (AU. The aim of this research is to test the factors, influencing the auditor acceptance of audit software by using Technology Acceptance Model (TAM. The data were collected by using survey method through mail and email delivered to the auditors in big 4 CPA’s firms in Indonesia. The data were analyzed by using Partial Least Square (PLS method. It is the alternative method of Structural Equation Modeling (SEM in which Smart PLS application program is applied. The results of this research indicate that there are positive relationship between perceived usefulness (PU and attitude to the use of the audit software (ATT, between perceived usefulness (PU and actual use (AU, between experience (EXP and perceived usefulness (PU, and between computer-self-efficacy (CSE and perceived ease of use (PEOU.  There are 2 factors that have significant influence on the auditor acceptance of audit software directly and indirectly. Perceived

  2. Vi, de civiliserede

    DEFF Research Database (Denmark)

    Nyemann, Dorthe

    2016-01-01

    Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?......Vi har i årtier troet på, at mennesker under de rette omstændigheder kan lykkes med at leve i fred og fordragelighed med hinanden. Skal vi til at erkende, at også vores samfundsstrukturer kun er en tynd fernis ovenpå et utæmmeligt voldspotentiale og egoisme?...

  3. Online Group Discussion pada Mata Kuliah Teknologi Pembelajaran Fisika

    Directory of Open Access Journals (Sweden)

    Yuberti Yuberti

    2015-10-01

    penawaran akses internet yang menggiurkan demi menarik minat penggunanya. Beberapa fenomena tersebut menunjukkan semakin banyak kalangan yang memanfaatkan internet dan menjadikanya sebagai gaya hidup untuk berintaksi, bersosialisasi, belajar dan mendapatkan informasi. Meluasnya pemanfaatan internet bisa menjadi potensi besar dalam pengembangan pembelajaran dengan sistem online memungkinkan pebelajar untuk mengakses infromasi secara fleksibel tanpa terbatas waktu dan tempat. Diskusi tidak lagi terjadi secara tatap muka, namun dapat terus berlangsung meskipun dalam lingkungan maya. Sebagaimana pelaksanaan metode pembelajaran maya lainnya. Pelaksanaannya diskusi online itu sendiri pada dasarnya mengadopsi dari metode pembelajaran diskusi tatap muka. Kata kunci: online group discussion, teknologi pembelajaran

  4. Hviler Dansk Økonomi på en Cobb-Douglas teknologi?

    DEFF Research Database (Denmark)

    Harck, Søren H.

    Prisdannelsen og faktorefterspørgslen i Det økonomiske Råds sekretariats SMEC-model af dansk økonomi har siden 1998 været teoretisk begrundet i en underliggende Cobb-Douglas teknologi (i kombination med en antagelse om omkostningsminimering). I SMEC-forgængeren SMEC 94 var det derimod markup...

  5. Evaluasi Soft Skills dalam Pembelajaran Mahasiswa Baru di Fakultas Teknologi Pertanian Universitas Udayana

    OpenAIRE

    Arnata, I Wayan; Surjoseputro, Sutarjo

    2014-01-01

    : Penelitian ini dilakukan dengan tujuan untuk mengevaluasi atribut soft skills yang dimiliki oleh mahasiswa baru Fakultas Teknologi Pertanian Universitas Udayana. Penelitian dilakukan dengan menggunakan desain pretest-posttest menggunakan kuesioner yang berisi atribut-atribut soft skills dan penilaian kemampuan pribadi. Dari hasil evaluasi terhadap pengembangan atribut soft skills diperoleh bahwa kemampuan soft skills yang dimiliki oleh mahasiswa baru setelah mengikuti pelatihan semuanya men...

  6. BUDIDAYA UDANG VANAME (Litopenaeus vannamei TEKNOLOGI INTENSIF MENGGUNAKAN BENIH TOKOLAN

    Directory of Open Access Journals (Sweden)

    Markus Mangampa

    2016-11-01

    Full Text Available Salah satu jenis udang yang cukup potensial untuk dikembangkan adalah udang vaname (Litopenaeus vannamei. Budidaya ini berkembang dengan teknologi intensif, namun terbatas pada golongan masyarakat menengah ke atas (padat modal. Riset ini bertujuan untuk mendapatkan data dan informasi pengaruh penggunaan tokolan terhadap produksi, Rasio Konversi Pakan (RKP pada pembesaran udang vaname teknologi intensif. Riset ini dilaksanakan di tambak Punaga, Takalar, Instalasi Balai Riset Perikanan Budidaya Air Payau (BRPBAP, menggunakan empat petak masing masing berukuran 4.000 m2/petak. Hewan uji adalah udang vaname dengan perlakuan: (A pembesaran dengan tebar benur (PL-12, dan (B pembesaran dengan tebar tokolan (PL-27. Setiap perlakuan dengan 2 ulangan, kepadatan benur dan tokolan adalah 50 ekor/m2, dan pemeliharaan berlangsung 80 hari di tambak. Hasil yang diperoleh pada perlakuan B memperlihatkan pertumbuhan mutlak (11,114±0,258 g/ekor, sintasan (92,55±0,23%, produksi (2.087,5±88,2 kg/petak lebih tinggi daripada perlakuan A yaitu: pertumbuhan mutlak (10,085±0,120 g/ekor, sintasan (90,83±8,51%, produksi (1.831,0±149,9 kg/petak, namun ketiga peubah ini berbeda tidak nyata antara kedua perlakuan. RKP lebih rendah pada perlakuan B (1,096±0,034 berbeda nyata dengan perlakuan A (1,257±0,048. Peubah kualitas air memperlihatkan sebaran kisaran yang merata untuk kedua perlakuan, kecuali nitrit (NO2 memperlihatkan kisaran yang tinggi pada perlakuan B (0,18235 mg/L dibandingkan dengan perlakuan A (0,0328 mg/L pada akhir penelitian. Hal ini disebabkan waktu panen yang berbeda sesuai dengan kondisi musim yaitu kualitas air sumber semakin menurun. Kualitas air sumber yang menurun ini diikuti oleh meningkatnya total vibrio di air laut mencapai; 4,33104 cfu/mL dibandingkan dalam air tambak 829.102 cfu/mL. Kesimpulan memperlihatkan bahwa penggunaan tokolan (PL-27 menghasilkan produksi yang tinggi dan rasio konversi pakan yang rendah. One species of shrimps that

  7. PENGARUH MODAL, TENAGA KERJA DAN TEKNOLOGI TERHADAP HASIL PRODUKSI SUSU KABUPATEN BOYOLALI

    Directory of Open Access Journals (Sweden)

    Satya Nugroho

    2014-09-01

    Full Text Available Currently, most of milk in Indonesia should be imported. It is about 78,89 %, and the rest, that is about 22,11% is from local production or local dairy farmers. However, there are some problems faced by the dairy farmers in Kecamatan Musuk. They are capital, workforces, and technology. This study aims at knowing the influence of capital, workforces, and technology to the milk production in Kecamatan Musuk. Ordinary Least Square (OLS was applied for analizing the data. The results show that the regression coefficient values of each independent variable (the variables of capital, workforces, and technology positively influence the production of milk. Based on the T-test (partial, the capital and workforces influence positively and significantly to the production. In addition, technology also has positive effect to the milk production, but it is not significant. Finally, based on F-test, the milk production is influenced by the capital, workforces and technology. It is 87%. Saat ini sebagian besar susu di Indonesia masih harus di impor (sekitar 78,89%, sedangkan 22,11%nya di pasok dari produksi susu domestik yang sebagian besar dihasilkan oleh peternak sapi perah rakyat. Namun ada beberapa permasalaham yang kerap dihadapi oleh peternak sapi perah di Kecamatan Musuk, baik dari segi permodalan, tenaga kerja maupun teknologi yang dipakai.Penelitian ini bertujuan untuk mengetahui seberapa besar pengaruh dari penggunaan faktor produksi modal, tenaga kerja dan teknologi terhadap hasil produksi susu sapi perah di Kecamatan Musuk. Alat analisis yang digunakan adalah analisis regresi berganda atau Ordinary Least Square (OLS.Hasil analisis diperoleh bahwa nilai koefisien regresi masing-masing variabel bebas yaitu variabel Modal, Tenaga Kerja, dan Teknologi berpengaruh secara positif terhadap produksi susu sapi perah. Dari hasil uji-t (parsial modal dan tenaga kerja berpengaruh positif dan signifikan sedangkan teknologi berpengaruh positif namun tidak

  8. Perancangan Dan Realisasi Sistem Transmisi Data GPS Menggunakan Teknologi SMS (Short Messaging Service) Sebagai Aplikasi Sistem Personal Tracking

    OpenAIRE

    DECY NATALIANA

    2013-01-01

    Abstrak Berprinsip pada pengembangan teknologi dan aplikasi dari sistem penjejakan posisi (tracking), maka dibuatlah sistem personal tracking dengan mentransmisikan data GPS (Global Positioning System) dengan menggunakan teknologi SMS (Short Messaging Service) pada jaringan GSM (Global System for Mobile Communications) sebagai media transmisinya.  Dengan sistem GPS akan diperoleh data garis lintang, serta garis bujur dari GPS receiver.  Data tersebut akan diteruskan oleh mikrokontroler untuk ...

  9. II-VI semiconductor compounds

    CERN Document Server

    1993-01-01

    For condensed matter physicists and electronic engineers, this volume deals with aspects of II-VI semiconductor compounds. Areas covered include devices and applications of II-VI compounds; Co-based II-IV semi-magnetic semiconductors; and electronic structure of strained II-VI superlattices.

  10. Penentuan Koordinat Titik pada Teknologi Garis dalam Grafika Komputer dengan Menggunakan Algoritma Line Equation

    Directory of Open Access Journals (Sweden)

    Mufadhol Mufadhol

    2014-07-01

    Full Text Available Grafika  Komputer atau  computer graphics  adalah  bagian  dari ilmu  komputer yang  berkaitan  dengan pembuatan  dan  manipulasi gambar  (visual  secara  digital.  Bentuk sederhana  dari grafika  komputer adalah grafika  komputer 2D yang  kemudian  berkembang  menjadi grafika  komputer 3D.  Pola  penggambaran  yang paling sederhana adalah dengan menggunakan titik pada teknologi garis. Algoritma Line Equation merupakan salah satu metode untuk menentukan lokasi koordinat titik pada teknologi garis dalam grafika komputer dengan cara menentukan nilai gradien garis serta garis yang berpotongan dengan sumbu Y, sehingga bisa mengetahui pixel yang akan menyala pada screen coordinate

  11. Perencanaan Tata Kelola Teknologi Informasi Berdasarkan Framework CobiT (Studi Kasus Pada Direktorat Metrologi)

    OpenAIRE

    Falahah, Falahah

    2006-01-01

    Tatakelola Teknologi Informasi (TI) merupakan salah satu aspek penting dari tatakelola Perusahaan secara keseluruhan. Pengelolaan TI yang baik akan menjamin efisiensi dan pencapaian kualitas layanan yang baik bagi tujuan bisnis Perusahaan. Penerapan tata kelola ini harus direncanakan dengan baik agar dapat diimplementasikan sesuai dengan kondisi dan kemampuan Perusahaan.Salah satu kerangka kerja tatakelola TI adalah CobiT. Dalam dokumentasi resminya CobiT juga disertai dengan serangkaian pedo...

  12. Studi Kesiapan Pemanfaatan Teknologi Informasi dan Komunikasi Serta Implementasi E-Goverment dengan Kerangka Kerja Cobit

    Directory of Open Access Journals (Sweden)

    Ahmad Budi Setiawan

    2011-03-01

    Full Text Available Studi ini bertujuan untuk melihat tentang kesiapan pemanfaatan TeknologiInformasi dan Komunikasi (e-readiness pada Kementerian Komunikasi danInformatika dalam rangka implementasi tata kelola pemerintahan secaraelektronis atau e-government. Dalam studi ini juga dibahas mengenai strategi implementasi e-government menggunakan kerangka kerja COBIT. Hasil dari studi ini menyimpulkan bahwa dengan menggunakan kerangka kerja COBIT sangat membantu dalam menentukan target kinerja proses-proses TI dalam proses implementasi e-government.

  13. Hubungan Multitasking Teknologi Informasi terhadap Produktivitas Kerja (Studi Kasus: Mahasiswa ITS)

    OpenAIRE

    Marendha, Galang Arga; Susanto, Tony Dwi; Arifiana, Isrida Yul

    2016-01-01

    Pada era globalisasi saat ini cara hidup individu umumnya para remaja dan dewasa yang selalu bergerak cepat dalam mendapatkan informasi terbaru agar tidak tertinggal dari yang lain memungkinkan melakukan pekerjaan secara bersamaan. Mayoritas dari individu-individu menganggap melakukan banyak pekerjaan sekaligus dapat digunakan sebagai solusi yang tepat. Dengan kemajuan teknologi saat ini dan perilaku seperti itu, banyak sekali contoh pekerjaan yang dilakukan secara bersama-sama seperti halnya...

  14. Peningkatan Kesejahteraan Perajin Batik Tulis Melalui Penerapan Teknologi Pemungutan Zat Warna Alam

    OpenAIRE

    Prima Astuti Handayani; Catur Rini Widyastuti; Adhi Setiawan

    2013-01-01

    Seiring kemajuan teknologi zat warna alam tergeser oleh keberadaan zat warna sintetis. Penggunaan zat warna alam masih tetap dijaga keberadaannya khususnya pada pembatikan. Kain batik yang menggunakan zat warna alam memiliki nilai jual yang tinggi karena memiliki nilai seni dan warna khas, tidak bersifat karsiogenik, ramah lingkungan serta berkesan etnik dan eksklusif. Zat warna alam coklat untuk pewarnaan batik dapat diperoleh dari kulit soga tingi melalui proses ekstraksi dengan pelarut eta...

  15. Integrasi Arsitektur Dan Manajemen Layanan Ti Untuk Pencapaian Fleksibilitas Teknologi Informasi Pada Organisasi

    OpenAIRE

    Aradea, Aradea

    2011-01-01

    Peran teknologi Informasi (TI) dalam organisasi saat ini telah mengalami pergeseran paradigma, pada awalnyaTI hanya berfokus pada otomatisasi data, pengolahan data atau manipulasi data, saat ini sudah bergeser padafungsi strategi dan layanan. Kesesuaian dan performa layanan TI dapat menjadi faktor penentu dalampencapaian tujuan dan sasaran organisasi, apabila diposisikan dan difungsikan secara tepat dan selarasdengan visi bisnis organisasi. Hal ini tentu dilakukan dengan sudut pandang yang me...

  16. INTEGRASI ARSITEKTUR DAN MANAJEMEN LAYANAN TI UNTUK PENCAPAIAN FLEKSIBILITAS TEKNOLOGI INFORMASI PADA ORGANISASI

    OpenAIRE

    Aradea, Aradea

    2012-01-01

    Peran teknologi Informasi (TI) dalam organisasi saat ini telah mengalami pergeseran paradigma, pada awalnyaTI hanya berfokus pada otomatisasi data, pengolahan data atau manipulasi data, saat ini sudah bergeser padafungsi strategi dan layanan. Kesesuaian dan performa layanan TI dapat menjadi faktor penentu dalampencapaian tujuan dan sasaran organisasi, apabila diposisikan dan difungsikan secara tepat dan selarasdengan visi bisnis organisasi. Hal ini tentu dilakukan dengan sudut pandang yang me...

  17. Development of Delta Wing Aerodynamics Research in Universiti Teknologi Malaysia Low Speed Wind Tunnel

    OpenAIRE

    Shabudin Mat; I. S. Ishak; Tholudin Mat Lazim; Shuhaimi Mansor; Mazuriah Said; Abdul Basid Abdul Rahman; Ahmad Shukeri Mohd. Kamaludim; Romain Brossay

    2014-01-01

    This paper presents wind tunnel experiment on two delta wing configurations which are differentiated by their leading edge profiles: sharp and round-edged wings. The experiments were performed as a part of the delta wing aerodynamics research development in Universiti Teknologi Malaysia, low speed tunnel (UTM-LST). Steady load balance and flow visualization tests were conducted at Reynolds numbers of 0.5, 1, and 1.5 × 106, respectively. The flow measurement at low Reynolds number was also per...

  18. Hubungan Beberapa Faktor Sosial Ekonomi Dengan Sikap Petani Cabai Merah Terhadap Teknologi Pembuatan Pupuk Bokashi.

    OpenAIRE

    Samosir, Lenny Dinamaria

    2011-01-01

    Pengambilan sampel dalam penelitian ini dilakukan secara kelompok atas dasar kelompok petani peserta pelatihan pembuatan pupuk bokashi dan nonpeserta pelatihan pembuatan pupuk bokashi yang diusahan pada lahan cabai sebanyak 22 sampel. Dari hasil penelitian dapat disimpulkan bahwa: 1. Sikap petani cabai terhadap teknologi pembuatan bokashi di Desa Sondi Raya adalah positif yaitu dari 22 orang petani cabai, 13 orang (59,09 %) memiliki sikap positif dan 9 orang (40,91 %) mem...

  19. APLIKASI MOBILE ZAPPELINE SEBAGAI MEDIA TEKNOLOGI MODIFIKASI CUACA (TMC) DAN PENIPISAN POLUTAN UDARA (ASAP)

    OpenAIRE

    Purwadi, Purwadi; Sunarto, Faisal; Muttaqin, Alfan; Seto, Tri Handoko

    2018-01-01

    IntisariTelah dilakukan kajian aplikasi mobile zappeline sebagai media teknologi modifikasi cuaca (tmc) dan media penipisan polutan udara (asap) pada sebuah truk Mitsubishi Colt Diesel berukuran 5,960 x 1,970 meter. Dengan kendaraan tersebut, direkomendasikan dimensi zappeline berbentuk bangun ruang eliptical dengan jari-jari diagonal a dan b masing-masing 3,25 dan 0,65 meter. Selanjutnya, karakteristik aerodinamik dan fisika dihitung dengan memecahkan beberapa persamaan fisika secara numerik...

  20. Udvikling af en internetsøgestrategi til identifikation af ny medicinsk teknologi inden for prostatacancer

    DEFF Research Database (Denmark)

    Thygesen, Marianne; Vondeling, Hindrik; Douw, Karla

    2007-01-01

    internetsider efter efficiens. Her er efficiens forstået som mindst antal minutter brugt pr. fund af information om en ny væsentlig medicinsk teknologi. Resultater: Strategien består af ti sider, som bør benyttes i følgende rækkefølge: YahooHealth, DoctorsGuide, The National Electronic Library for Medicines...

  1. Teknologi Pengendalian Gulma Alang-alang dengan Tanaman Legum untuk Pertanian Tanaman Pangan

    OpenAIRE

    Ishak Juarsah

    2015-01-01

    Di Indonesia, Alang-alang (Imperata cylindrica L. Beauv) merupakan salah satu gulma terpenting dan termasuk sepuluh gulma bermasalah di dunia.  Melalui biji dan rimpang, alang-alang dapat tumbuh dan menyebar luas pada hampir semua kondisi lahan. Teknologi pengendalian alang-alang telah banyak dikenal namun belum dapat menjamin eradikasi populasi alang-alang secara berkelanjutan tanpa diikuti oleh kultur teknis dan pola budidaya tanaman pangan sepanjang tahun. Hasil penelitian menunjukan bahwa...

  2. PENGARUH PEMANFAATAN TEKNOLOGI DAN MODERNISASI SISTEM ADMINISTRASI PERPAJAKAN TERHADAP KEPATUHAN WAJIB PAJAK ORANG PRIBADI

    Directory of Open Access Journals (Sweden)

    Titik Aryati

    2016-12-01

    Keywords: the utilization of technology; modernization of tax administration system; personal taxpayers compliance. Abstrak. Penelitian ini bertujuan untuk menganalisis dampak pemanfaatan teknologi dan modernisasi sistem administrasi perpajakan terhadap kepatuhan wajib pajak pribadi. Variabel independen dalam penelitian ini adalah sistem administrasi perpajakan modern, peraturan pemerintah yang mendukung pemanfaatan teknologi informasi, modernisasi struktur organisasi, modernisasi strategi organisasi, peningkatan sumber daya manusia, good governance, dan whistleblowing system, sedangkan variabel dependennya adalah kepatuhan wajib pajak pribadi. Penelitian ini menggunakan data primer, dengan memberikan kuesioner kepada responden secara online kepada Wajib Pajak orang pribadi dan diisi oleh 180 responden. Metode pengambilan sampel dalam penelitian ini menggunakan metode convenience sampling. Analisis data menggunakan analisis regresi linier berganda. Secara parsial, hasil analisis dan hipotesis menunjukkan bahwa variabel sistem administrasi perpajakan modern, modernisasi strategi organisasi, tata pemerintahan yang baik dan sistem whistleblowing berpengaruh signifikan terhadap kepatuhan wajib pajak pribadi, sedangkan variabel lainnya adalah: peraturan pemerintah, modernisasi struktur organisasi, dan Juga peningkatan sumber daya manusia tidak berdampak terhadap kepatuhan wajib pajak pribadi. Kata Kunci: Pemanfaatan teknolog;  modernisasi sistem administrasi perpajakan; Kepatuhan wajib pajak pribadi.

  3. Perancangan Buku Batik Plumpungan Salatiga Dengan Menggunakan Teknologi Augmented Realty Berbasis Android

    Directory of Open Access Journals (Sweden)

    Ika Cahya Winata

    2017-07-01

    Full Text Available Batik Indonesia telah ditetapkan oleh United Nations Educational, Scientific, and Cultural Organization (UNESCO sebagai warisan kemanusiaan untuk budaya lisan dan non-bendawi pada tanggal 2 Oktober 2009. Pengakuan UNESCO ini meliputi teknik, teknologi serta motif batik Indonesia. Indonesia memiliki motif batik yang beragam, dan hampir disetiap daerah memiliki motif batik yang berbeda-beda. Batik Plumpungan Salatiga merupakan karya seni batik kontemporer yang didesain dari batu Prasasti Kota Salatiga. Batik Salatiga ini masih tergolong baru sehingga hanya dikenal oleh golongan tertentu saja. Untuk memperkenalkan batik Plumpungan Salatiga dibutuhkan media informasi yang dapat menarik masyarakat untuk lebih mengenal batik Plumpungan. Media buku dipilih sebagai sarana untuk memberikan informasi tentang batik Plumpungan Salatiga. Seiring dengan berkembangnya teknologi dan permasalahan yang terjadi, Peneliti menggunakan teknologi Augmented Reality sebagai metode dalam memberikan informasi dan menarik minat masyarakat untuk lebih mengenal dan mengetahui tentang batik Plumpungan yang dapat dijalankan pada smartphone Android. Objek penelitian ini adalah batik Plumpungan Salatiga. Metode Augmented Reality ini sudah diujikan kepada pemilik batik dan 20 responden masyarakat didapatkan hasil metode Augmented Reality dapat memberikan informasi mengenai pengaplikasian motif batik Plumpungan Salatiga pada objek 3D yang ditampilkan.

  4. Identifikasi dan Tingkat Penerapan Inovasi Teknologi Padi Sawah di Kabupaten Parigi Moutong Sulawesi Tengah

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    Syafruddin Syafruddin

    2016-07-01

    Full Text Available Pencapaian tingkat swasembada dan ketahanan pangan khususnya beras tidak terlepas dari beberapa dukungan seperti sumberdaya alam dan penerapan inovasi teknologi. Kabupaten Parigi Moutong merupakan salah satu wilayah penghasil beras yang cukup besar di Sulawesi Tengah yang diharapkan dapat menjadi sumber pertumbuhan baru produksi beras Nasional di Indonesia. Pemerintah Daerah menetapkan wilayah ini, sebagai daerah penyangga beras terbesar di Sulawesi Tengah. Tujuan dari Penelitian ini adalah untuk : 1. Mengidentifikasi berbagai permasalahan dan tingkat penerapan inovasi teknologi pertanian di Kabupaten Parigi Moutong dan 2. Menetapkan arahan dan alternatif teknologi yang potensial untuk pengembangan lahan di Kabupaten Parigi Moutong. Penelitian ini dilaksanakan sebanyak dua tahap yaitu tahap 1 Desk study dan 2. Penelitian Lapangan. Desk study dilakukan dengan cara penelusuran pustaka dan diskusi dengan stake holders lainnya. Untuk Penelitian lapangan dilaksanakan dengan menggunakan metode survey dengan melakukan pengamatan kondisi sosial ekonomi dan budaya serta pengamatan tingkat penerapan inovasi teknologi melalui pendekatan Partisifatif Rural Aprasial atau Pengenalan Desa Secara Partisifatif (PRA. Pelaksanaan penelitian dilakukan selama 2 bulan yaitu dari bulan Juni hingga bulan Juli 2014. Hasil penelitian menunjukkan bahwa terdapat potensi perluasan areal persawahan dan peningkatan luas tanam karena didukung oleh iklim dan irigasi yang cukup baik. Tingkat penerapan teknologi masih cukup rendah terutama penggunaan varietas unggul, benih unggul dan bermutu serta pemupukan. The achievement level of self-sufficiency and food security, particularly in rice production should be supported by natural resources and the application of technology innovation.  Parigi Moutong Regency is one of the largest rice producer areas in Central Sulawesi, which is expected to be a new growth source area of national rice production in Indonesia. Local government

  5. ANALISA SUMBER DAYA MANUSIA TEKNOLOGI INFORMASI MENGGUNAKAN KERANGKA KERJA COBIT 4.1” (STUDI KASUS : UNIT PELAKSANA TEKNIS TELEMATIKA UNIVERSITAS PEMBANGUNAN NASIONAL “VETERAN” JAWA TIMUR

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    Mohammad Idhom

    2016-08-01

    Full Text Available Pengelolaan sumber daya manusia merupakan proses dan struktur hubungan yang mengendalikan dan mengarahkan suatu organisasi perusahaan dalam mencapai tujuan organisasi dengan menambahkan nilai agar teknologi informasi dan prosesnya dapat diseimbangkan dengan resikonya. Diperlukan sebuah evaluasi sumber daya manusia dibidang teknologi informasi untuk mengetahui sejauh mana tingkatan pengelolaan terhadap sumber daya manusia di Unit Pelaksana Teknis Telematika saat ini. Sumber daya manusia di bidang teknologi informasi pada Unit Pelaksana Teknis Telematika membutuhkan pengembangan dan pengelolaan sesuai dengan harapan organisasi. Melihat terbatasnya sumber daya manusia di bidang teknologi informasi pada Unit Pelaksana Teknis Telematika sangat terbatas sehingga kegiatan operasional masih belum efektif dan memenuhi sasaran yang diharapkan. Melihat kondisi organisasi yang mengalami terbatas pada sumber daya manusia di bidang teknologi informasi dilakukan evaluasi secara detail dengan menggunakan COBIT 4.1.Dalam melakukan evaluasi sumber daya manusia dengan menggunakan kerangka kerja COBIT  yang berfokus pada Domain PO7 diharapkan dapat memberikan acuan dan perbaikan yang lebih efektif terhadap organisasi ke depannya.

  6. PENGARUH TEKNOLOGI INFORMASI, SALING KETERGANTUNGAN, KARAKTERISTIK SISTEM AKUNTANSI MANAJEMEN TERHADAP KINERJA MANAJERIAL

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    Arsono Laksmana

    2002-01-01

    Full Text Available The understanding of the antecedent conditions influencing the design of management accounting systems (MAS is very limited. Recently, researchers focus their attention on the understanding how different contingency variables influence MAS. The results of these studies have been, at best, equivocal and numerous calls have been made for further research.This study examines the role of management accounting system characteristics on the relationship to information technology, interdependence and managerial performance. Management accounting system characteristics was defined to the extent on which managers use broad scope MAS information for managerial decision making. Hypotheses were generated for indirect effects of contingency variables. The responses of 110 managers, drawn from manufacturing companies in East Java, were analyzed using a structural equation modelling (SEM. The results indicate that management accounting system characteristics act as a mediator in the relationship between information technology, organizational interdependence and managerial performance. Abstract in Bahasa Indonesia : Penelitian tentang faktor-faktor yang mempengaruhi rancangan sistem akuntansi manajemen (SAM masih sangat terbatas. Akhir-akhir ini perhatian peneliti telah dicurahkan untuk memahami bagaimana variabel kontinjensi yang berbeda mempengaruhi SAM. Banyak penelitian yang telah dilakukan menunjukkan hasil yang tidak konsisten, karenanya diperlukan penelitian-penelitian lanjutan. Penelitian ini mengkaji peran karakterisrik sistem akuntansi manajemen terhadap hubungan antara teknologi informasi, saling ketergantungan dan kinerja manajerial. Karakteristik SAM didefinisikan sebagai tingkat dimana manajer menggunakan informasi SAM scope untuk pengambilan keputusan manajerial. Respon yang diperoleh dari 110 manajer yang bekerja pada perusahaan industri manufaktur di Jawa Timur dianalisa dengan menggunakan structural equation modelling (SEM. Hasil penelitian

  7. TANTANGAN DAKWAH DI ERA TEKNOLOGI DAN INFORMASI: Formulasi Karakteristik, Popularitas, dan Materi di Jalan Dakwah

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    nur Ahmad

    2015-11-01

    Full Text Available Teknologi di era globalisasi telah mengalami kemajuan yang begitu pesat. Berbagai macam media komunikasi bersaing dalam memberikan informasi tanpa batas. Fasilitas internet merupakan yang terlengkap dan efisien, dimana segala bentuk dan macam informasi dapat diakses dengan mudah dan murah termasuk dalam hal ini adalah dakwah di era teknologi didukung dengan semakin menjamurnya warung internet yang memasang tarif murah, kemana dan dengan siapapun. Sekarang kita bisa melakukan dakwah dengan mengunakan fasilitas digital, diantaranya bisa melalui radio, televisi, telepon seluler, media internet, facebook, atau twiter. Berdakwah melalui media internet merupakan salah satu media komunikasi yang fenomenal dan canggih yang lahir di era 60-an. Namun, kemajuan teknologi dan informasi, khususnya media televisi, memungkinkan seorang dai untuk berimprovisasi dengan selingan humor dan hal-hal lain, agar materi ceramahnya tetap menarik untuk disimak. Dampaknya, orientasi dakwah yang diperankan para dai, juga semakin berkembang, bahkan cenderung menjadi bias. Pola berdakwah melalui media sebagai wujud kemajuan teknologi menjadi tantangan bagi diri sendiri bagi seseorang dai. Pengaruh media memungkinkan seorang dai memperoleh popularitas di mata pemirsanya seperti layaknya seorang selebriti (publik figur dan tidak menutup kemungkinan pula setiap kegiatan dakwahnya sering dinilai dengan materi. Kata Kunci: Karakteristik, Popularitas, Materi, Tantangan Dakwah. THE CHALLENGES OF DAWA IN THE ERA OF TECHNOLOGY AND INFORMATION: THE FORMULATION CHARACTERISTICS, POPULARITY, AND MATERIAL IN THE PATH OF DAWA. Technology in the era of globalization has experienced a rapid progress. A wide range of communication media compete in providing information without limits. The internet is the most comprehensive and efficient, where all shapes and kinds of information can be accessed easily and inexpensively included in this is the dawa in the era of technology supported by the

  8. STUDI DAN UJI COBA TEKNOLOGI BLUETOOTH SEBAGAI ALTERNATIF KOMUNIKASI DATA NIRKABEL

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    Yulia Yulia

    2004-01-01

    Full Text Available Bluetooth is a new emerging technology. This technology gives significant changes for electronic devices that we are using. If we look around, a keyboard is connected to a computer. So does a printer, a mouse, a monitor and so on. This condition creates a problem of so many scattered wires installed in the offices, houses and other places. Another problem is how to inspect the damaging or boken wires. In this paper, we will have a discussion on specific applications of bluetooth such as services provided by the bluetooth technology; bluetooth method - how bluetooth devices make connections in a piconet; as well as investigation on bluetooth protocol stack. Bluetooth has succesfully built easy connection among devices from many vendor without using cables, with less power dan money. By using bluetooth, we can build small network or Piconet, consisting of several devices without cables. Abstract in Bahasa Indonesia : Bluetooth adalah suatu teknologi baru yang mulai dikenal dan digunakan. Teknologi ini memberikan perubahan yang signifikan terhadap peralatan elektronik yang kita gunakan. Jika kita melihat sekeliling kita dimana keyboard dihubungkan pada komputer. Demikian juga halnya dengan printer, mouse, monitor dan lain sebagainya. Semua peralatan itu dihubungkan dengan menggunakan kabel. Akibatnya terjadi masalah banyak kabel yang dibutuhkan di kantor, rumah atau tempat-tempat lainnya. Masalah lain yang ditemui adalah bagaimana menelusuri kabel-kabel yang terpasang jika ada suatu kesalahan atau kerusakan. Bluetooth memperbaiki penggunaan teknologi kabel yang cenderung menyulitkan ini dengan cara menghubungkan beberapa peralatan tanpa menggunakan kabel. Pada karya tulis ini, dibahas aplikasi spesifik bluetooth, antara lain servis-servis apa saja yang disediakan oleh teknologi bluetooth; cara kerja bluetooth yaitu bagaimana bluetooth device melakukan koneksi di dalam sebuah piconet serta bluetooth protocol stack. Bluetooth telah berhasil

  9. Pengembangan Teknologi Informasi Mobile Learning Fakultas Teknik Universitas Diponegoro Berbasis Android

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    Resi Jiwa Kasatria

    2014-11-01

    Full Text Available Perkembangan teknologi mobile seluler sudah sedemikian cepat dan dapat dirasakan di seluruh dunia dan dimanfaatkan dalam berbagai bidang kehidupan. Perkembangan ini dapat pula dilakukan dalam dunia pendidikan dan memungkinkan terobosan baru dalam belajar secara mobile menggunakan perangkat teknologi informasi (handphone atau disebut mobile learning (m-learning. M-learning memiliki beberapa kelebihan di antaranya adalah independensi dalam pembelajaran. Namun, di sisi lain, perangkat pembelajaran m-learning memiliki keterbatasan sumber daya dan keragaman platform sehingga diperlukan rancangan yang mampu menjamin kompatibilitas. Aplikasi Mobile Learning ini dikembangkan menggunakan Java EE untuk menangani servernya dan untuk sisi klien menggunakan Bootstrap mobile. Basis data yang digunakan adalah MySQL. Aplikasi ini akan mempunyai 3 role pengguna yaitu admin yang akan menangani penambahan user dan pengelolaan mata kuliah, dosen yang akan memberikan materi, tugas dan kuis dan mahasiswa yang dapat melihat materi, tugas dan kuis yang diberikan dosen. Mobile Learning ini dapat membantu dosen dan mahasiswa dalam melakukan interaksi dalam berbagi materi, dalam pemberian tugas dan mengerjakan kuis. Mahasiswa maupun dosen tidak lagi harus bertatap muka, yang diperlukan hanyalah koneksi internet untuk melakukan proses belajar mengajar. Selain itu Mobile Learning ini juga dapat berjalan dengan baik saat diuji pada 3 buah versi android yang berbeda yaitu versi 2.3, versi 4.0 dan versi 4.2.

  10. Pengembangan Peta Interaktif Tiga Dimensi Perpustakaan Pusat Institut Teknologi Sepuluh Nopember Menggunakan Unreal Engine

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    Mazza Fitroni

    2015-03-01

    Full Text Available Teknologi yang semakin berkembang pesat saat ini membuat penyampaian informasi kepada masyarakat sangat cepat dan banyak perubahan terutama mengenai bangunan. Dahulu penyampaian informasi mengenai bangunan hanya menggunakan dua dimensi (2D, namun sekarang dapat menggunakan tiga dimensi (3D. Tampilan informasi bangunan gambar 3D ini menjadi terlihat lebih jelas, menarik, dan detail. Tak terkecuali pada perguruan tinggi Intstitut Teknologi Sepuluh Nopember (ITS menjadi objek visualisasi 3D sebagai sarana promosi terhadap konsumen atau calon mahasiswa baru. Pada paper ini akan berisi tentang aplikasi virtual peta 3D yang akan menampilkan objek sebuah gedung Perpustakaan Pusat ITS. Aplikasi yang nanti akan digunakan dalam pembuatan virtual 3D adalah dengan Unreal Engine, dan adobe Flash sebagai user interface untuk informasi dan interaksi didalamnya. Aplikasi pendukung utama yaitu 3Ds Max untuk modelling benda 3D. Aplikasi virtual peta 3D nantinya akan menyampaikan tampilan sebuah Gedung Perpustakaan Pusat ITS yang memudahkan pengguna / user untuk mengetahui dan mengunjungi gedung tersebut secara virtual seperti dunia nyata

  11. Pengembangan Sistem Informasi Akuntansi Dan Pengelolaan Keuangan Modul Penganggaran Berbasis Web Menggunakan Teknologi Java Dan Postgresql

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    Hari Rakhmanto Zauhar

    2012-09-01

    Full Text Available Banyaknya fungsi yang dijalankan di satuan kerja pemerintah telah didukung oleh teknologi informasi yaitu berupa aplikasi-aplikasi yang banyak pula. Namun banyaknya aplikasi tersebut menyebabkan munculnya permasalahan baru yaitu sistem database yang masih terpisah. Saat ini akan dikembangkan suatu aplikasi yang bernama Sistem Informasi Akuntansi dan Pengelolaan Keuangan yang akan mengintegrasikan semua aplikasi operasional di satuan kerja. Aplikasi ini berbasis web dan menggunakan teknologi Java dan PostgreSQL Salah satu fungsi yang wajib ikut diintegrasikan aplikasinya adalah fungsi penganggaran dengan aplikasi Rencana Kerja Anggaran-Kementerian Negara/Lembaga Daftar Isian Pelaksanaan Anggaran. Aplikasi ini sangat penting karena merupakan awal dari proses pengelolaan keuangan. Jika aplikasi ini tidak ikut diintegrasikan maka akan berpotensi tidak sinkronnya data Daftar Isian Pelaksanaan Anggaran dari aplikasi Rencana Kerja Anggaran-Kementerian Negara/Lembaga Daftar Isian Pelaksanaan Anggaran dengan aplikasi Surat Perintah Membayar. Terpisahnya database dari aplikasi Rencana Kerja Anggaran-Kementerian Negara/Lembaga Daftar Isian Pelaksanaan Anggaran dengan aplikasi Surat Perintah Membayar juga dapat menimbulkan potensi tindakan kriminal manipulasi data Daftar Isian Pelaksanaan AnggaranDengan diintegrasikannya aplikasi Rencana Kerja Anggaran-Kementerian Negara/Lembaga Daftar Isian Pelaksanaan Anggaran ke dalam aplikasi Sistem Informasi Akuntansi dan Pengelolaan Keuangan maka dapat meningkatkan kinerja satuan kerja sekaligus meningkatkan kualitas laporan keuanganya

  12. IMPLEMENTASI KOMPUTASI AWAN MENGGUNAKAN TEKNOLOGI GOOGLE APP ENGINE (GAE DAN AMAZON WEB SERVICES (AWS

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    Adi Nugroho

    2013-04-01

    Full Text Available Interoperabilitas, dalam arti cara bagaimana suatu sistem yang memiliki platform perangkat keras dan perangkat lunak tertentu dapat berkomunikasi dengan sistem-sistem yang memiliki platform yang berbeda, mungkin merupakan bagian dari ‘masa lalu’. Di masa-masa yang akan datang, interoperabilitas yang selama ini ditangani secara manual oleh organisasi-organisasi/perusahaan-perusahaan akan ditangani langsung oleh vendor-vendor penyedia komputasi awan (cloud computing yang memang memiliki sumberdaya-sumberdaya manusia (analis sistem, pemrogram, pakar jaringan, perangkat keras (komputer-komputer server yang berjumlah sangat banyak dan berkemampuan raksasa, serta perangkat lunak (sistem operasi, server aplikasi, server Web yang memang memenuhi syarat untuk itu. Di masa yang akan datang, untuk mendapatkan layanan-layanan  (service dan tempat penyimpanan tertentu, organisasi-organisasi/ perusahaan-perusahaan tidak perlu berinvestasi terlalu tinggi untuk menyediakannya sendiri; mereka bisa saja menyewanya dari vendor-vendor komputasi awan yang saat ini mulai bermunculan. Google dan Amazon adalah para pendahulu dari teknologi komputasi awan (cloud computing ini. Melalui tulisan ini, kita tidak akan membahas struktur internal keduanya secara rinci, melainkan kita akan mencoba membahas kelebihan serta kekurangan kedua vendor komputasi awan ini dari sudutpandang para manajer di bidang Teknologi Informasi yang akan melakukan investasi yang bermanfaat bagi organisasi/perusahaannya.

  13. IMPLEMENTASI KOMPUTASI AWAN MENGGUNAKAN TEKNOLOGI GOOGLE APP ENGINE (GAE DAN AMAZON WEB SERVICES (AWS

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    Adi Nugroho

    2012-01-01

    Full Text Available Interoperabilitas, dalam arti cara bagaimana suatu sistem yang memiliki platform perangkat keras dan perangkat lunak tertentu dapat berkomunikasi dengan sistem-sistem yang memiliki platform yang berbeda, mungkin merupakan bagian dari masa lalu. Di masa-masa yang akan datang, interoperabilitas yang selama ini ditangani secara manual oleh organisasi-organisasi/perusahaan-perusahaan akan ditangani langsung oleh vendor-vendor penyedia komputasi awan (cloud computing yang memang memiliki sumberdaya-sumberdaya manusia (analis sistem, pemrogram, pakar jaringan, perangkat keras (komputer-komputer server yang berjumlah sangat banyak dan berkemampuan raksasa, serta perangkat lunak (sistem operasi, server aplikasi, server Web yang memang memenuhi syarat untuk itu. Di masa yang akan datang, untuk mendapatkan layanan-layanan (service dan tempat penyimpanan tertentu, organisasi-organisasi/ perusahaan-perusahaan tidak perlu berinvestasi terlalu tinggi untuk menyediakannya sendiri; mereka bisa saja menyewanya dari vendor-vendor komputasi awan yang saat ini mulai bermunculan. Google dan Amazon adalah para pendahulu dari teknologi komputasi awan (cloud computing ini. Melalui tulisan ini, kita tidak akan membahas struktur internal keduanya secara rinci, melainkan kita akan mencoba membahas kelebihan serta kekurangan kedua vendor komputasi awan ini dari sudutpandang para manajer di bidang Teknologi Informasi yang akan melakukan investasi yang bermanfaat bagi organisasi/perusahaannya.

  14. Evaluasi Kesesuaian Struktur Organisasi Pengelola Teknologi Informasi dengan Rencana Jangka Panjang Instansi (Studi Kasus pada Dinas XYZ

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    Arief Anwar Shodiq

    2012-09-01

    Full Text Available Setiap lembaga atau instansi memerlukan teknologi informasi (TI untuk mendukung banyak aktivitas dalam menangani proses bisnisnya. Untuk itu, dibutuhkan pengelolaan teknologi informasi yang ideal dan pembentukan struktur organisasi yang relevan dan dapat menjawab kebutuhan akan kelancaran proses bisnisnya. Tidak terkecuali pada Dinas XYZ sebagai lembaga pemerintahan yang bertugas sebagai pengelola pendidikan dan kebudayaan di tingkat provinsi. Dibutuhkan sebuah struktur organisasi pengelola teknologi informasi yang selaras dengan Rencana Jangka Panjang Instansi untuk mendukung tujuan bisnisnya. Dan ketika perencanaan strategis ini diperbaharui, struktur organisasi juga dituntut untuk diperbaharui mengikuti perubahan kebijakan yang baru. Untuk itu, diperlukan analisis komprehensif mengenai perancangan struktur organisasi yang ideal bagi Dinas XYZ ini, yang meliputi studi pendahuluan yang mengkaji literatur dan kondisi kekinian Dinas XYZ, identifikasi Business Goals, identifikasi IT Goals dan IT Process, penentuan struktur organisasi pengelola TI masa depan beserta tanggung jawab masing-masing bagian, dan analisis gap mengenai kondisi saat ini dan kebutuhan TI masa depan, yang semua itu disesuaikan dengan framework COBIT 4.1 sebagai acuan best practice bagi pengelolaan teknologi informasi.

  15. ANALISIS KEPERCAYAAN-KEPERCAYAAN INDIVIDU DALAM MENGGUNAKAN TEKNOLOGI INFORMASI DALAM MENUNJANG PROSES BELAJAR MENGAJAR DI PERGURUAN TINGGI

    OpenAIRE

    Supardi Supardi; Eka Noor Asamara

    2017-01-01

    Penelitian ini bertujuan untuk mendiskusikan dan menguji secara empiris hubungan faktor sosial dengan cognitive absorption dan hubungannya terhadap faktor kepercayaan-kepercayaan (perceived ease of use dan perceived usefulness) dalam menggunakan teknologi informasi pada proses belajar mengajar diperguruan tinggi. Penelitian ini menggunakan sebanyak 125 dosen jurusan akuntansi di propinsi Yogyakarta sebagai responden. Faktor sosial diukur dengan menggunakan pengaruh rekan sejawat, cognitive ab...

  16. POTENSI ATMOSFER DALAM PEMBENTUKAN AWAN KONVEKTIF PADA PELAKSANAAN TEKNOLOGI MODIFIKASI CUACA DI DAS KOTOPANJANG DAN DAS SINGKARAK 2010

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    Syaifullah, M Djazim

    2011-01-01

    Kajian potensi atmosfer terhadap proses pembentukan dan pertumbuhan awan konvektifpada saat pelaksanaan Teknologi Modifikasi Cuaca (TMC) telah dilakukan dengan datapengamatan sounding dari stasiun Tabing Sumatera Barat. Sebanyak 330 buah datapengamatan harian jam 00Z dan 12Z dari Juni sampai dengan Nopember 2010 telahdianalisis. Dengan aplikasi RAOB analisis dilakukan untuk menentukan parameterdan indeks radiosonde sebagai penduga potensi atmosfer di wilayah tersebut. Hasilanalisis kandungan ...

  17. PENENTUAN KOLABORASI PENELITIAN DAN DISTRIBUSI PENGARANG PADA JURNAL TEKNOLOGI INDONESIA (THE DETERMINATIONS OF RESEARCH COLLABORATION AND AUTHORS DISTRIBUTION IN THE JURNAL TEKNOLOGI INDONESIA

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    Engkos Koswara Natakusumah

    2014-06-01

    Full Text Available This study aims to determine of research collaboration and authors distribution based on the data and informationmentioned in the Jurnal Teknologi Indonesia (JTI during 5 years, from 2007 up to 2011. To reach this aims, theresearch uses methodology of bibliometric analysis to analyse the citation appeared in every last page of the articlepublished in the JTI; including distribution of articles each year, the number of contributors, the authorship, thedistribution of article languages, the single and many authors who wrote write the articles, the number of documentcited by outhors, and average number of references in an article. The bibliometrics data come from 80 articles,ranging from volume 30 up to volume 34. Then the data are tabulated, analysed and described for the purpose tomake conclusion of the research. The results show that there are domination of publication contribution by auhtors’collaboration in the journal, have significant range of research collaboration and have high rank of publication by 4researchers of 7, 6 and 5 articles published. 

  18. PERAMALAN PENENTUAN JUMLAH PERMINTAAN KONSUMEN BERBASIS TEKNOLOGI INFORMASI TERHADAP PRODUK BORDIR PADA KOTA TASIKMALAYA

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    Lies Sunarmintyastuti

    2016-12-01

    Full Text Available Peramalan penentuan jumlah permintaan konsumen berbasis teknologi informasi terhadap produk bordir di Kota Tasikmalaya, mempunyai tujuan khusus untuk menentukan jumlah kebutuhan permintaan konsumen secara periodik, berkala dan pola kebutuhan permintaan konsumen dimasa yang akan datang secara trend, musiman. Penelitian ini berawal dari konsep pemikiran bagaimana supaya produsen bordir di Kota Tasikmalaya mendapatkan pendapatan yang optimal dan efisien dalam biaya produksi bordir mereka. Pendekatan peramalan dalam penelitian ini menggunakan metode Time Series dengan menggunakan Single Exponential Smoothing Modeluntuk mendapatkan nilai peramalan secara periodik, Double Exponential Smoothing Modeluntuk mendapatkan nilai peramalan secara trend dan Triple Exponential SmoothingModeldengan Multiplicative Seasonal Modeluntuk mendapatkan nilai peramalan secara musiman, serta pengujian peramalan menggunakan MAD, MAPE dan MSE untuk mencari error terkecil. Pada tahap berikutnya dibangun sebuah sistem peramalan penentuan permintaan konsumen dengan menggunakan metode pengembangan sistem waterfall dan pembuatansoftware yang dirancang menggunakan bahasa pemrograman Java dengan editor NetBeans dan database MySQL.

  19. Service quality that improves customer satisfaction in a university: a case study in Institut Teknologi Indonesia

    Science.gov (United States)

    Theresia, L.; Bangun, R.

    2017-12-01

    Universities should provide better service quality to get more customers. The purpose of this study was to find service quality which has impact on the increasing of customer satisfaction in a university. This study is a case study in Institut Teknologi Indonesia (ITI). The result of the study will help ITI to improve its service quality to increase customer satisfaction. This study employs path analysis technique. The data were collected through questionnaires developed from the literature. Questionnaires have two parts namely 1) service quality and 2) customer satisfaction. Service quality is measured through 22 questions with five service quality dimensions: 1) Tangibles, 2) Reliability, 3) Responsiveness, 4) Assurance and 5) Empathy. Customer Satisfaction is measured through 4 questions. The data then are processed by SPSS. The results showed that the students preferred to tangible quality improvement than intangible aspect.

  20. Peningkatan Kesejahteraan Perajin Batik Tulis Melalui Penerapan Teknologi Pemungutan Zat Warna Alam

    Directory of Open Access Journals (Sweden)

    Prima Astuti Handayani

    2013-02-01

    Full Text Available Seiring kemajuan teknologi zat warna alam tergeser oleh keberadaan zat warna sintetis. Penggunaan zat warna alam masih tetap dijaga keberadaannya khususnya pada pembatikan. Kain batik yang menggunakan zat warna alam memiliki nilai jual yang tinggi karena memiliki nilai seni dan warna khas, tidak bersifat karsiogenik, ramah lingkungan serta berkesan etnik dan eksklusif. Zat warna alam coklat untuk pewarnaan batik dapat diperoleh dari kulit soga tingi melalui proses ekstraksi dengan pelarut etanol. Tujuan spesifik dari kegiatan pengabdian kepada masyarakat adalah perajin batik Desa Pandan Kabupaten Rembang mampu membuat zat warna batik dari alam, untuk memenuhi kebutuhan dirinya sendiri, sehingga diharapkan dapat meningkatkan pendapatan keluarga. Metode yang dilakukan meliputi metode ceramah mengenai pembuatan zat warna; metode praktek tentang proses pembuatan zat warna dari kulit soga tingi; metode tanya jawab untuk mengetahui sejauh mana peserta mampu menerima atau terlibat dalam kegiatan, dan evaluasi untuk memperoleh gambaran penafsiran dan analisis untuk memperoleh simpulan dari semua kegiatan pengabdian kepada masyarakat yang sudah dilaksanakan.

  1. Development of Delta Wing Aerodynamics Research in Universiti Teknologi Malaysia Low Speed Wind Tunnel

    Directory of Open Access Journals (Sweden)

    Shabudin Mat

    2014-07-01

    Full Text Available This paper presents wind tunnel experiment on two delta wing configurations which are differentiated by their leading edge profiles: sharp and round-edged wings. The experiments were performed as a part of the delta wing aerodynamics research development in Universiti Teknologi Malaysia, low speed tunnel (UTM-LST. Steady load balance and flow visualization tests were conducted at Reynolds numbers of 0.5, 1, and 1.5 × 106, respectively. The flow measurement at low Reynolds number was also performed at as low as speed of 5 m/s. During the experiments, laser with smoke flow visualizations test was performed on both wings. The study has identified interesting features of the interrelationship between the conventional leading edge primary vortex and the occurrence and development of the vortex breakdown above the delta wings. The results conclude the vortex characteristics are largely dependent on the Reynolds number, angle of attack, and leading-edge radii of the wing.

  2. PERAN TEKNOLOGI KOMUNIKASI DALAM INTERAKSI AYAH DAN ANAK STUDI KASUS: INTERAKSI AYAH DAN ANAK MELALUI SMARTPHONE

    Directory of Open Access Journals (Sweden)

    Detania Savitri

    2016-02-01

    Fungsi ayah dalam keluarga adalah sebagai pencari nafkah untuk memenuhi kebutuhan keluarga, sementara ibu berfungsi dalam mendidik anak. Ayah yang bekerja penuh waktu akan berkurang interaksinya dengan anak. Disisi lain, teknologi komunikasi diciptakan untuk mempermudah interaksi antar individu. Penelitian ini ingin mengetahui apakah smartphone dapat meningkatkan intensitas kedekatan interaksi antara ayah dan anak. Selain itu, penelitian ini juga ingin mengetahui apakah ayah dapat memberikan sosialisasi kepada anak melalui smartphone dan mengontrol keseharian anak. Artikel ini menggunakan perspektif fungsionalis. Pendekatan kualitatif digunakan oleh penulis dengan mewawancarai tiga ayah dan tiga anak berusia 20 tahun ke atas yang sama-sama menggunakan smartphone di kota Depok. Temuan yang diperoleh penulis yaitu smartphone dapat merubah interaksi ayah dengan anak, dan ayah dapat memberikan kontrol sosial kepada anak dalam interaksi melalui smartphone. Dalam interaksi ayah dan anak, smartphone juga dapat digunakan ayah untuk mensosialisasikan nilai-nilai kepada anak.

  3. Perancangan Web Interface Institut Teknologi Sepuluh Nopember (ITS Dengan Memperhatikan Aspek Usability

    Directory of Open Access Journals (Sweden)

    Hendry Setyawans Sutedjo

    2012-09-01

    Full Text Available Informasi dalam sebuah website atau web diharapkan dapat sampaikan dan diterima oleh pencari informasi dengan mudah. Di dalam Dunia pendidikan, informasi yang ada di dalam web juga diharapkan mampu diterima oleh para penggunanya dengan tujuan media komunikasi online seperti website dapat membantu para pelajar menerima ilmu yang disampaikan melalui media online. Untuk Mengetahui seberapa mudahnya informasi itu ditangkap ditandai dengan seberapa mudah website itu digunakan (usable. Untuk mengetahui seberapa mudah penggunaan suatu website digunakan analisa usability, banyak metode yang dapat digunakan untuk mengidentifikasi masalah usability terutama dari sisi interface web. Heuristic evaluation merupakan salah satu teknik dalam melakukan hal tersebut yang digunakan dalam penelitian ini guna menilai seberapa mudahnya website Institut Teknologi Sepuluh Nopember dalam menyampaikan informasi yang ada. Dalam penelitian ini digunakan juga Quality Function Deployment (QFD untuk mengidentifikasi keinginan pengguna terhadap tampilan dari web ITS

  4. Studi Migrasi Public Switched Telephone Network (Pstn) Menuju Jaringan Telekomunikasi Berbasis Paket Next Generation Network (Ngn) Dengan Teknologi Softswitch

    OpenAIRE

    Suseno, Andrias Danang; Najib, Warsun; Samiyono, -

    2009-01-01

    Public Switched Telephone Network (PSTN) adalah sistem telekomunikasi berbasis circuit-switched. Pada awalnya PSTN hanya menyediakan layanan voice. PSTN sekarang telah berkembang ke arah pelayanan komunikasi data yang didorong oleh berkembangnya dunia internet dengan Internet Protokol (IP)-nya. Telah muncul teknologi Voice over IP (VoIP) yang mampu melewatkan trafik voice pada jaringan data dengan mengubah voice menjadi paket. VoIP telah mendorong trend/kecenderungan terjadinya konvergensi an...

  5. Pengkajian Rakitan Teknologi Budidaya Kentang dan Strategi Pengembangannya : Studi Kasus di Wilayah Prima Tani Lahan Kering Dataran Tinggi Kabupaten Magetan

    OpenAIRE

    Santoso, Pudji; Yuniarti; Purnomo, Sudarmadi; Subandi

    2009-01-01

    Pengkajian Rakitan Teknologi Budidaya Kentang dan Strategi Pengembangannya : Studi Kasus di Wilayah Prima Tani Lahan Kering Dataran Tinggi Kabupaten Magetan. The assessment on improving the cultivation technology of potato as demonstration plot in farmer's land was done in Prima Tani area of Magetan regency in Genilangit village, during dry season on June – September 2007. Collecting data was done using farm record keeping method on the application of improving cultivation technology of potat...

  6. ANALISIS KEPERCAYAAN-KEPERCAYAAN INDIVIDU DALAM MENGGUNAKAN TEKNOLOGI INFORMASI DALAM MENUNJANG PROSES BELAJAR MENGAJAR DI PERGURUAN TINGGI

    Directory of Open Access Journals (Sweden)

    Supardi Supardi

    2017-04-01

    Full Text Available Penelitian ini bertujuan untuk mendiskusikan dan menguji secara empiris hubungan faktor sosial dengan cognitive absorption dan hubungannya terhadap faktor kepercayaan-kepercayaan (perceived ease of use dan perceived usefulness dalam menggunakan teknologi informasi pada proses belajar mengajar diperguruan tinggi. Penelitian ini menggunakan sebanyak 125 dosen jurusan akuntansi di propinsi Yogyakarta sebagai responden. Faktor sosial diukur dengan menggunakan pengaruh rekan sejawat, cognitive absorption diukur dengan menggunakan lima dimensi yaitu temporal dissociation, focused immertion, heightened enjoyment, control, dan curiosity serta kepercayaan-kepercayaan diukur dengan menggunakan perceived ease of use dan perceived usefulness. Metode pengambilan sampel yang digunakan dalam penelitian ini adalah secara non-probability yaitu purposive sampling dengan tipe judgment. Data dianalisis dengan structural equation modeling (SEM menggunakan SmartPLS2.0. Dari hasil pengujian hipotesis, diperoleh temuan bahwa seluruh hipotesis terdukung. Hal ini ditunjukkan dengan adanya bukti hubungan secara positif signifikan antara faktor sosial dengan cognitive absorption dan cognitive absorption dengan faktor kepercayaan-kepercayaan dalam menggunakan teknologi informasi. Penelitian ini telah membuktikan adanya pengaruh faktor sosial terhadap cognitive absorption dalam kepercayaan-kepercayaan menggunakan teknologi infomarmasi untuk mendukung proses belajar mengajar. Selain itu, penelitian ini telah berhasil mengembangkan model penelitian yang dilakaukan oleh Agarwal dan Karahanna (2000, yaitu dengan memberikan bukti empiris faktor sosial sebagai anteseden bagi cognitive absorption

  7. Inovasi Desain, Teknologi, dan Pemasaran Lewat Website Usaha Kecil Menengah Batik dan Lutik (Lurik Batik di Kecamatan Laweyan Surakarta

    Directory of Open Access Journals (Sweden)

    Anastasia Riani Suprapti

    2016-12-01

      Tujuan penelitian terapan ini adalah untuk meningkatkan produktivitas dan mengembangkan produk batik dan lutik yang ada di wilayah Kecamatan Laweyan Surakarta dengan inovasi desain dan teknologi baru. Program ini bekerja sama dengan mitra UKM Batik Dewi (UKM 1 dan Batik Sinung Rejeki (UKM2 yang terletak di Kecamatan Laweyan. Pengusaha batik Laweyan dengan produknya berupa batik dan tekstil bermotif batik (printing dan cap dalam era globalisasi sekarang ini ternyata memiliki daya tahan yang baik, ditengah persaingan dengan produk sejenis dari daerah lain maupun dari luar negeri. Secara garis besar pola yang digunakan dalam implementasi penelitian ini meliputi: diskusi (FGD, kerja bengkel, operasional pabrik, pelatihan dan pendampingan (kelompok dan individu. Seperti halnya Usaha Kecil Menengah pada umumnya, pengusaha batik di Laweyan juga menghadapi masalah Internal meliputi  permodalan, inovasi desain, pemasaran, dan manajemen keuangan, yang meliputi administrasi keuangan/pembukuan. Beberapa solusi yang ditawarkan untuk mengatasi permasalahan yang dihadapi diantaranya adalah melakukan Inovasi desain dan teknologi, pengaturan layout pabrik, dan pemasaran lewat web. Selain itu mengembangkan desain motif batik yang lebih diminati pasar diberikan juga untuk pengembangan teknik kombinasi batik-lurik ikat dengan cara lukis dan pengelantangan. Penggunaan media teknologi informasi dan komunikasi untuk promosi lewat website. Adapun untuk usaha pengembangan manajemen pemasaran,  diusahakan media promosi dan menjalin kerjasama pemasaran  dengan instansi terkait, misalnya dengan mengikuti pameran-pameran di Solo dan Jakarta.

  8. cis-dioxomolybdenum(VI)-(ONO)

    Indian Academy of Sciences (India)

    Various ONO type Schiff base ligands L(H)2 used for the preparation of ... and derivatives.6–33 Depending on the method of prepa- ration .... HCl. Scheme 6. Synthesis of a Mo(VI) Schiff base complexe by selective inversion at C–1 carbon of a ...

  9. VI Tallinna arhitektuuritriennaal / Leonhard Lapin

    Index Scriptorium Estoniae

    Lapin, Leonhard, 1947-

    2005-01-01

    15.-17. IX Tallinnas Niguliste kirikus toimuval VI Tallinna arhitektuuritriennaalil esinevad inglise arhitektuurikriitik Peter Davey, šveitsi arhitekt Peter Zumthor, soome arhitekt Juha Leviskä, eesti arhitekt Vilen Künnapu, eesti kunstiajaloolane Juhan Maiste jt. Külastatakse KUMU, tutvutab autor Pekka Vapaavuori

  10. Analisis Kelayakan Implementasi Teknologi LTE 1.8 GHz Bagi Operator Seluler di Indonesia [Feasibility Analysis of LTE 1.8 GHz for Mobile Operators in Indonesia

    Directory of Open Access Journals (Sweden)

    Sri Ariyanti

    2015-06-01

    Full Text Available Peningkatan kebutuhan layanan data mendorong operator telekomunikasi berusaha mengimplementasikan jaringan akses broadband yang lebih handal.  Teknologi LTE merupakan salah satu teknologi dengan kecepatan mencapai tiga kali dibanding teknologi HSDPA, sehingga diharapkan dapat memenuhi kebutuhan pelanggan data mobile. Refarming frekuensi 1.8 GHz  untuk penerapan teknologi LTE memberikan efisiensi karena tidak perlu membayar BHP lagi untuk menyewa frekuensi baru. Teknologi 2G GSM selama ini juga semakin ditinggalkan, masyarakat di daerah perkotaan cenderung lebih banyak menggunakan layanan data.  Sebelum diterapkannya teknologi LTE pada frekuensi 1.8 GHz perlu adanya kajian untuk mengetahui kelayakan teknologi LTE pada frekuensi 1.8 GHz. Penelitian ini bertujuan untuk melakukan cost-benefit analysis implementasi LTE pada frekuensi 1.8 GHz.  Metode penelitian menggunakan pendekatan kualitataif yang didukung dengan data kuantitatif.  Hasil penelitian menunjukkan bahwa minimal bandiwdth yang diperlukan agar implementasi LTE layak digunakan adalah 15 MHz.  Meskipun tanpa Global Frequency Returning, penggunaan bandwidth 10 MHz tidak layak digunakan untuk implementasi LTE.      *****The incresing of data demand drives mobile operators to implement more reliable broadband access network. LTE technology has downlink peak rate up to three times than HSDPA,  hence it may fulfill the mobile data user requirement. Frequency 1.8 GHz refarming can be implemented to provide efficiency because They do not need to pay licence fee for leasing new frequency. GSM technology will be abandoned since it is not growing anymore. Besides that, dense urban users tend to use data mobile.  Before implementing LTE technology  on 1.8 GHz frequency, It is necessary to analysis the feasibility such technology. This research used qualitative method supported by quantitative  approach.  The result of this research showed that minimum bandwidth to implement 1.8 GHz LTE

  11. PENERAPAN TEKNOLOGI VOIP UNTUK MENGOPTIMALKAN PENGGUNAAN JARINGAN INTRANET KAMPUS UNIVERSITAS UDAYANA

    Directory of Open Access Journals (Sweden)

    Pande Ketut Sudiarta

    2009-12-01

    Full Text Available Jaringan intranet Universitas Udayana telah menghubungkan ketiga lokasi kampus, yaitu Kampus Bukit, Kampus Sudirman, dan Kampus Nias.  Lokasi kampus yang terpisah-pisah dan kampus Bukit yang memiliki area yang cukup luas memerlukan prasarana teleponi yang memadai.  Selama ini, komunikasi teleponi masih memanfaatkan provider seperti PT Telkom, walaupun komunikasi telepon hanya untuk komunikasi antar fakultas atau antar fakultas dengan rektorat di area kampus bukit.  Demikian juga untuk komunikasi telepon antar lokasi kampus yang berbeda. Walaupun beberapa fakultas dan juga gedung Rektorat memiliki perangkat PABX namun keberadaan kebanyakan hanya melayani komunikasi dalam satu gedung saja.  Pemanfaatan intranet kampus UNUD baru dimanfaatkan untuk akses Internet, akses Sistem Informasi dan untuk videoconference. Dengan beban trafik yang ada, jaringan intranet masih memungkinkan untuk dibebani dengan trafik yang lebih tinggi. Dengan demikian, untuk mengoptimalkan pemanfaatan bandwith,  diupayakan dengan mengembangakan sistem teleponi berbasis VoIP yang memanfaatkan infrastruktur yang ada. Tujuan yang ingin dicapai adalah menyediakan fasilitas telepon internal kampus yang tidak berbayar. Melalui teknologi VoIP ini,  komunikasi dapat dilakukan dengan beberapa cara baik menggunakan telepon analog maupun softphone yang dapat diinstall di masing-masing PC atau laptop. Hal ini nanti tentu akan memberikan efisiensi waktu bagi civitas karena mudah dihubungi dan secara langsung akan berdampak pada efisiensi biaya telekomunikasi di kampus. Infrastruktur yang dikembangkan menggunakan protokol SIP memanfaatkan Free Software Linux Fedora sebagai Operating System, Asterisk dan Ondo sebagai aplikasi server.  Di sisi pemakai, perangkat telepon dapat menggunakan dua model, pertama menggunakan softphone  yang ditujukan untuk personal dengan memanfaatkan nomor induk pegawai (NIP atau nomor induk mahasiswa (NIM sebagai nomor telepon. Model telepon ini aksesnya

  12. Beban Biaya Telekomunikasi yang Dikeluarkan Masyarakat Pengaruh dari Adopsi Teknologi [Telecommunication Costs Incurred Expenses Society Effect of Technology Adoption

    Directory of Open Access Journals (Sweden)

    Sri Ariyanti

    2016-07-01

    Full Text Available Salah satu Rencana Pita Lebar Indonesiatahun 2014 – 2019 yaitu dapat memberikan akses bergerak  di wilayah pedesaan  menjangkau 52% pupulasi dengan data rate mencapai 1 Mbps.  Agar layanan pita lebar dapat terjangkau oleh masyarakat luas, maka harga layanan pita lebar ditargetkan paling tinggi sebesar 5% dari rata-rata pendapatan bulanan pada akhir tahun 2019.  Rencana pita lebar dengan target minimal data rate tersebut tidak akan tercapai tanpa adanya perubahan teknologiTeknologi yang mendukung terpenuhinya data rate tersebut antara lain teknologi 3.5G dan 4G LTE.  Dalam rangka upgrade teknologi, perlu adanya biaya yang cukup besar yang dikeluarkan oleh operator.  Biaya tersebut sangat mempengaruhi besar biaya yang akan dibebankan kepada pelanggan.  Oleh karena itu dalam penelitian ini mengkaji seberapa besar biaya yang ditanggung pelanggan seluler setelah adanya teknologi baru. Penelitian ini bertujuan untuk mengetahui apakah biaya yang dibebankan kepada masyarakat sudah sesuai dengan yang ditetapkan oleh pemerintah dalam Rencana Pita Lebar Indonesia. Teknik peneltiian ini menggunakan pendekatan data kuantitatif yang dianalisis dengan ekonometrika.  Hasil penelitian menunjukkan bahwa berdasarkan data penegeluarna telekomunikasi rumah tangga maupun data ARPU, biaya yang dibebankan kepada pelanggan sudah memenuhih persyaratan yang telah ditetapaka oleh rencana pita lebar Indonesia yaitu kurang dari 5%. *****One of the Indonesia Broadband Plan in 2014 – 2019 is that it can be provided mobile data reaching 52% rural areas with data rate up to 1 Mbps. In order to be affordable, so that maximum price is 5% of the average monthly income at the end of 2019.  That data rate cannot be achieved without upgrading the technology. The technology of 3.5G and 4G are among others technology that can support high data rate.  In order to upgrade technology, it needs a considerable cost from mobile operators, while it can influence the cost

  13. Aplikasi Pengenalan Ikan Hias Predator Air Tawar Menggunakan Teknologi Augmented Reality Berbasis Android

    Directory of Open Access Journals (Sweden)

    Jimmy Moedjahedy

    2017-07-01

    Full Text Available Penggemar dan komunitas hobi ikan hias predator di Manado makin berkembang dan orang yang ingin membelinya pun semakin bertambah. Berdasarkan pengamatan peneliti dibeberapa toko yang menjual ikan hias, pengenalan tentang ikan hias predator masih sangat kurang bahkan ditempat penjualan masih ada yang belum memiliki katalog tentang jenis ikan hias predator. Berdasarkan latar belakang tersebut, peneliti membuat aplikasi pengenalan ikan hias predator dengan menggunakan teknologi augmented reality berbasia android dimana pengguna dapat memanfaatkan smartphone mereka untuk melihat jenis dan info tentang ikan hias yang akan mereka beli dengan jelas dan atraktif. Metode rekayasa perangkat lunak yang digunakan adalah metode spiral karena metode ini menawarkan pendekatan yang lebih baik untuk membuat suatu program dengan cepat dan bertahap. Hasil dari penelitian ini adalah aplikasi android yang dapat menunjukan 9 jenis ikan hias predator dalam bentuk 3D yang dapat dilihat dari 4 sisi dan 6 jenis ikan lainnya dalam bentuk gambar serta informasi tertulis tentang ikan yang akan dipelihara.   Kata kunci : Augemented Reality, 3D, Android

  14. TRANSFEKSI MERUPAKAN METODE TEKNOLOGI TRANSGENIK PENYISIPAN GREEN FLOURESCENT PROTEIN TERHADAP IKAN WILD BETTA

    Directory of Open Access Journals (Sweden)

    Eni Kusrini

    2015-06-01

    Full Text Available Teknik transfer gen banyak dikembangkan untuk mengintroduksi molekul DNA ke dalam embrio. Keberhasilan transfer gen menggunakan metode transfeksi ditentukan oleh berbagai faktor, antara lain pemilihan larutan transfeksi yang sesuai dengan mempertimbangkan kesediaan secara komersial, mudah diaplikasikan, keberhasilan tinggi, dan tidak bersifat toksik terhadap embrio. Studi awal untuk mengetahui keberhasilan transfer gen terhadap embrio ikan wild betta digunakan Green Fluorescent Protein (GFP dan juga dapat digunakan sebagai model terhadap ikan betta. GFP merupakan gen yang mengkodekan protein dan memiliki sifat berpendar hijau. Induk jantan dan betina dipijahkan dengan perbandingan 1:1 pada wadah baskom dengan ketinggian air ± 14 cm serta diberikan substrat. Transfeksi dilakukan pada embrio fase pembelahan 2 sel. Larutan transfeksi dibuat dari campuran DNA plasmid pada media NaCl 0.9% hingga mencapai konsentrasi akhir 100 μL media (campuran transfast + DNA + NaCl. Aktivitas gen ini dapat divisualisasikan dengan menggunakan sinar ultra violet. Keberhasilan dari teknik transfer gen tersebut dibuktikan dengan adanya ekspresi gen atau deteksi DNA gen GFP yang dimasukkan. Ekspresi hasil korporasi DNA ke dalam telur melalui transfeksi pada wild betta dan keberhasilan transfer gen GFP dapat dibuktikan dengan analisis PCR. Tujuan dari penulisan makalah ini adalah menguraikan tentang metode transfeksi yang efektif untuk teknologi transfer gen terhadap ikan wild betta.

  15. Manajemen Sumber Daya Teknologi Informasi Laboratorium Komputer Menggunakan Balanced Scorecard (BSC dan COBIT 5

    Directory of Open Access Journals (Sweden)

    M. Panji Ismail

    2017-05-01

    Full Text Available Laboratorium komputer merupakan salah satu sarana pembelajaran yang berbasis Teknologi Informasi (TI yang terdiri dari tiga sumber daya TI, yaitu software, hardware, dan brainware. Tidak adanya kesesuaian antara kemampuan hardware dengan spesifikasi hardware yang digunakan dapat menghambat pengguna (brainware dalam melakukan praktikum dan pembelajaran di laboratorium. Selain itu, ketidaksesuaian tersebut juga mengakibatkan software berjalan lambat dan computer sering error sehingga praktikum menjadi terganggu dan berjalan tidak lancar. Untuk mengetahui kesesuaian antar sumber daya TI yang ada di laboratorium dibutuhkan proses pengukuran manajemen sumber daya TI yang ada saat ini. Skala likert menjadi salah satu metode untuk mengukur kinerja software, hardware, dan tata kelola laboratorium saat ini. Hasil pengukuran kemudian dievaluasi menggunakan framework Balance Scorecard (BSC dengan melalui beberapa tahapan dan penyelarasan strategi TI. Setelah mengetahui hasil evaluasi dan kendala-kendala apa saka yang ada dalam melakukan pengelolaan maka langkah berikutnya adalah menentukan bagaimana cara memperbaiki dan melakukan peningkatan tata kelola TI. COBIT 5 akan menjadi framework pelengkap untuk memperbaiki sekaligus memprediksi pengembangan manajemen sumber daya TI. Hasil penelitian ini menunjukkan bahwa integrase antara COBIT 5 dengan Balance Scorecard (BSC memberikan kemampuan dalam melakukan pengukuran tata kelola laboratorium serta memberikan kemampuan untuk meningkatkan pelayanan secara kontinyu.

  16. EVALUASI KINERJA TEKNOLOGI INFORMASI DANA PENSIUN SEKOLAH KRISTEN SALATIGA MENGGUNAKAN FRAMEWORK COBIT 5

    Directory of Open Access Journals (Sweden)

    Yosafanto Adi

    2017-04-01

    Full Text Available Sistem Keuangan merupakan infrastruktur teknologi informasi yang ada di Dana Pensiun Sekolah Kristen Salatiga. Sistem Keuangan dapat mengelola berbagai laporan mulai dari pencatatan kas hingga pembuatan laporan keuangan. Pentingnya sistem keuangan dalam operasional, menjadikannya  harus dalam kondisi yang optimal. Perlu adanya kontrol dan evaluasi terhadap kinerja sistem informasi (SI agar sistem yang dibangun organisasi dapat mencapai tujuan bisnis. Untuk itu diperlukannya evaluasi kinerja sistem keuangan, pada penelitian ini standar yang digunakan untuk proses evaluasi kinerja yaitu COBIT 5. Framework COBIT 5 dapat menjadi sebuah alat evaluasi kinerja SI untuk menilai seberapa jauh SI  dapat memenuhi kebutuhan tujuan bisnis. Berdasarkan evaluasi kinerja pada sistem keuangan menggunakan COBIT 5 didapatkan hasil bahwa organisasi sudah mengimplementasikan semua proses, yang berarti Dana Pensiun Sekolah Kristen Salatiga sudah mencapai tingkat kapabilitas pada level 1 (Performed Process maupun level 2 (Managed Process. Untuk memperbaiki tingkat kapabilitas proses-proses TI tersebut, maka COBIT 5 telah memberikan panduan berupa rekomendasi guna penyelerasan antara tujuan bisnis Dana Pensiun Sekolah Kristen dengan tujuan TI dalam rangka meningkatkan efisiensi dan efektifitas Sistem Keuangan untuk mencapai tujuan organisasi.

  17. Visualisasi Iklan Cetak Mobil VW ”New Beetle” Sebagai Pencitraan Hubungan Manusia dan Teknologi

    Directory of Open Access Journals (Sweden)

    Hendro Aryanto

    2009-01-01

    Full Text Available When a new car is launched to the market, sometimes it begins with the appearing of the product advertisement. This happened with VW’s products. In VW Beige ”New Beetle” and VW Black ”New Beetle” print ad versions, they are shown as symbols of beauty and comfort because of their modern technology. VW ”New Beetle” could be the peoples’ choice in many countries with different geographical and cultural backgrounds. In the commodity society, beauty is priceless, for it is supported by the image culture which emphasizes appearance. This point will support belief and loyalty to the brand. Abstract in Bahasa Indonesia: Ketika sebuah mobil baru diluncurkan ke pasar, biasanya diawali dengan pemunculan iklan produk tersebut. Ini yang nampak pada produk VW. Pada iklan cetak versi lipstik VW Beige ”New Beetle” dan VW Black ”New Beetle”, merupakan simbol kecantikan dan kenyamanan karena teknologinya yang modern. VW ”New Beetle” bisa menjadi pilihan orang-orang di negara manapun yang mempunyai geografis yang berbeda-beda tentunya dengan budaya yang berbeda pula. Dalam masyarakat komoditas, kecantikan adalah sangat berharga, karena didukung budaya citra yang mengutamakan penampilan. Hal ini akan mendukung keyakinan dan kesetiaan pada merek tersebut. Kata kunci: iklan cetak, VW Beetle, citra, manusia, teknologi.

  18. PENGARUH MODEL PEMBELAJARAN SAINS TEKNOLOGI MASYARAKAT (STM TERHADAP KEMAMPUAN PEMECAHAN MASALAH DAN SELF-EFFICACY SISWA

    Directory of Open Access Journals (Sweden)

    M. Dwipayana

    2017-10-01

    Full Text Available Penelitian ini bertujuan menganalisis perbedaan kemampuan pemecahan masalah dan self-efficacy siswa antara kelompok siswa yang belajar dengan model pembelajaran Sains Teknologi Masyarakat (STM dibandingkan dengan kelompok siswa yang belajar dengan model pembelajaran langsung (Direct Instruction. Jenis penelitian ini adalah penelitian semu (quasi experiment dengan rancangan pretest-posttest non equivalent control group design Populasi dalam penelitian ini semua siswa kelas VII SMP 2 Singaraja dan sampel sebanyak 75 orang siswa. Data self-efficacy dikumpulkan dengan metode kuisioner dan data kemampuan pemecahan masalah dikumpulkan dengan tes essay. Analisis data yang digunakan dalam penelitian ini adalah Manova. Berdasarkan penelitian yang telah dilakukan didapatkan hasil bahwa terdapat perbedaan kemampuan pemecahan masalah dan self- efficacy siswa antara kelompok siswa yang belajar dengan model pembelajaran STM dibandingkan dengan kelompok siswa yang belajar dengan model pembelajaran langsung (Direct Instruction dengan rata-rata nilai gain score STM lebih unggul dari nilai gain score DI berturut-turut yaitu 0,53>0,48 pada variabel kemampuan pemecahan masalah dan 0,55>0,41 pada variabel self-efficacy. Hasil Uji LSD menunjukan gain score kemampuan pemecahan masalah dan self-efficacy antara kelompok siswa yang belajar dengan model pembelajaran STM lebih baik dibandingkan dengan kelompok siswa yang belajar dengan model pembelajaran langsung (Direct Instruction.

  19. RANCANG BANGUN APLIKASI PENDAFTARAN AKTA PPAT BERBASIS WEB DENGAN TEKNOLOGI QR CODE

    Directory of Open Access Journals (Sweden)

    Timothy Anggriawan

    2014-10-01

    Full Text Available Perkembangan ilmu pengetahuan dan teknologi telah mengalami percepatan yang tinggi. Keadaan tersebut membuat banyak hal dapat dilakukan dengan lebih mudah dan efisien. Seiring dengan hal tersebut kebutuhan akan informasi yang cepat dan akurat juga semakin tinggi. Dengan tujuan untuk menghasilkan penyajian informasi yang cepat, jelas, dan akurat sehingga dapat membantu proses pengambilan keputusan dalam proses verifikasi data. Metode dalam pembuatan aplikasi ini dibagi menjadi tiga bagian yaitu pertama, melakukan pengumpulan data Akta  PPAT. Kedua, perancangan aplikasi pencetakan Akta PPAT, QR Code, dan pengecekan Akta. Ketiga, pembuatan aplikasi pendaftaran Akta QR Code PPAT menggunakan bahasa pemrograman PHP yang dapat dijalankan pada browser. Hasil dari pembuatan aplikasi berupa aplikasi pendaftaran Akta PPAT yang dapat menampilkan proses penginputan data para pihak, pengeditan data pada Akta PPAT, pencetakan Akta QR Code. Aplikasi dapat menampilkan hasil pengecekan Akta melalui scan QR Code pada aplikasi dalam bentuk teks file, dan melakukan validasi data pada hasil scan. Simpulan yang dapat ditarik adalah aplikasi dapat menampilkan hasil cetak Akta dan QR Code.

  20. REMASTERING LIVE USB UNTUK LAMP PADA FAKULTAS SAINS DAN TEKNOLOGI PALEMBANG

    Directory of Open Access Journals (Sweden)

    Klaudius Jevanda B.S.

    2015-11-01

    Full Text Available ABSTRAK Penelitian ini bertujuan untuk membuat distribusi Linux bernama Lubuntu yang memfokuskan diri pada desktop yang ringan serta ditujukan untuk menjadi lingkungan web server yang free dalam bentuk live USB. Dimana, penelitian ini menjelaskan tentang desain dan implementasi dari distribusi Linux Lubuntu itu sendiri yang nantinya bisa terus diperbaiki, disempurnakan dan dimungkinkan untuk dimodifikasi serta dipelajari oleh pihak lain. Lubuntu dikembangkan dengan memodifikasi dari Linux Lubuntu 14.04 dari tahap penambahan program, penghapusan program dan konfigurasi sampai pada tahap pembuatan Live USB untuk LAMP (Linux Apache Mysql PHP menggunakan metode remastering. Hasil dari penelitian ini berupa Live USB yang berisi tool untuk lingkungan web server. Tool utama dalam Live USB diantaranya adalah phpmyadmin, gimp, inkscape, dan bluefish. Keluaran penelitian ini, diharapkan bisa digunakan sebagai sistem operasi dan dikhususkan dalam lingkungan web server yang nyaman untuk dipergunakan dalam proses belajar mengajar pada matakuliah sistem operasi, pemrograman basis web I, dan pemrograman basis web II di Fakultas Sains dan Teknologi Universitas Katolik Musi Charitas palembang. Kata kunci: linux, web server, LAMP, remastering, live usb.

  1. Pendampingan Orang Tua pada Anak Usia Dini dalam Penggunaan Teknologi Digital [Parent Mentoring of Young Children in the Use of Digital Technology

    Directory of Open Access Journals (Sweden)

    Tesa Alia

    2018-01-01

    BAHASA INDONESIA ABSTRAK: Kemajuan teknologi memberikan pengaruh signifikan terhadap kehidupan masyarakat termasuk dalam ruang lingkup keluarga. Tidak bisa dipungkiri bahwa kemajuan teknologi saat ini terutama berbasis layanan internet memberikan dampak positif dan juga dampak negatif bagi tumbuh kembang anak dalam keluarga. Anak-anak yang lahir setelah era tahun 1980-an merupakan generasi yang hidup di tengah majunya teknologi informasi dan beragam aplikasi sosial dimulai secara daring (online. Melalui gadget seperti smartphone, laptop, komputer, tablet, dan lain sebagainya memberikan kemudahan bagi anak untuk mengakses jaringan internet di mana pun dan kapan pun. Orang tua berperan penting dalam perkembangan komunikasi anak usia dini, khususnya anak di bawah usia lima tahun. Salah satu upaya orang tua dalam memberikan pendidikan bagi anak dalam keluarga di era digital seperti sekarang adalah dengan memberikan pendampingan dalam penggunaan teknologi bagi anak. Melalui pendampingan tersebut, orang tua dapat mengawasi anak dan mengarahkan konten-konten positif bagi anak untuk menggunakan kemajuan teknologi secara tepat  sesuai dengan masa tumbuh kembang anak.

  2. Vi mangler endnu et panel

    DEFF Research Database (Denmark)

    Ritter, Thomas

    2016-01-01

    Vi mangler højtuddannede værdiskabere, som transformerer gode idéer og teknologier til indtjening og velstand. Først i mødet med markedet afgøres fremtiden. Troels Lund Poulsen bør nedsætte et kommercialiseringspanel, der byder ind med løsninger, hvordan Danmark bliver et land ikke kun med gode...

  3. Safety aspects of using Ag-In-Cd absorber made by PT. Batan Teknologi (Persero) in the core of multi purposes reactor G.A. Siwabessy

    International Nuclear Information System (INIS)

    Anggoro Septilarso; Zulkarnain; Heryudo Kusumo

    2011-01-01

    Safety Evaluation has been carried out for the using of Ag-In-Cd Absorber made by PT. Batan Teknologi (Persero) in the core of Multi Purposes Reactor G.A. Siwabessy (RSG-GAS). PT. Batan Teknologi (Persero) only licensed by NUKEM GmbH to produce Fuel Element and Control Element U-Al, U 3 O 8 -Al dan U 3 Si 2 -Al, and not including to produce Ag-In-Cd Absorber. But, BAPETEN evaluator think that the danger would be greater if RSG-GAS use the older absorber than use Ag-In-Cd Absorber made by PT. Batan Teknologi. For this purposes, BAPETEN set some requirements and acceptance criteria to be met by the absorber, that is cold test, hot test, shutdown margin value, control rod drop test and visual test. The test show that Ag-In-Cd Absorber meets all the requirements and acceptance criteria required by BAPETEN. (author)

  4. PENGARUH KEPERCAYAAN, KOMITMEN, DAN TEKNOLOGI INFORMASI TERHADAP KINERJA RANTAI PASOKAN (STUDI KASUS IKM PENGOLAH BUAH MARKISA DI KOTA MAKASSAR

    Directory of Open Access Journals (Sweden)

    Musran Munizu

    2017-03-01

    Full Text Available The effective Supply chain management (SCM has increasingly become an important way to enhance competitive strength as well as business performance. Trust, commitment, and well-integrated supply chain by Information Technology (IT support are important elements to improve supply chain performance. The objectives of this study are to examine and analyze the effects of trust variables on supply chain performance, trust on commitment, commitment on supply chain performance, information technology on supply chain performance, and effects of trust variable on supply chain performance through commitment variable to Small and Medium Industries (SMIs of passion fruit processing in Makassar. This study used a quantitative approach, where the questionnaire as main tools for data collection. Data were analyzed by descriptive analysis and partial least square-path modeling (PLS-PM. Data computation used SmartPLS 2.0 Software. The results show that trust has a significant effect on supply chain performance, and it also has a significant effect on commitment. Furthermore, commitment has a significant effect on supply chain performance, and information technology has a significant effect on supply chain performance. Trust can improve the supply chain performance by commitment indirectly, and it gives smaller effect on supply chain performance directly than indirectly mediated by commitment. Then, supply chain performance is more influenced by information technology rather than trust and commitment. The results of this study may have implications for the important role of management in maintaining trust, commitment and utilizing information technology in the supply chain system.Keywords: trust, commitment, Information technology, supply chain performance, SMIs of passion fruit processingAbstrakPengelolaan rantai pasokan yang efektif telah menjadi cara terbaik untuk meningkatkan daya saing dan kinerja perusahaan. Kepercayaan, komitmen, dan dukungan teknologi

  5. DISAIN TEKNOLOGI SURYA SEBAGAI "FORM-GIVER" PADA ARSITEKTUR Implementasi Bangunan Perumahan di Indonesia

    Directory of Open Access Journals (Sweden)

    Jimmy Priatman

    2001-01-01

    faktor penentu disain sistem surya yang mempengaruhi disain arsitektur yang akan membentuk suatu langgam arsitektur baru yang dinamakan "arsitektur surya". Kata kunci: Disain Teknologi Surya, Arsitektur Surya.

  6. Kajian Teknologi High Altitude Platform (HAP [Study of High Altitude Platform (HAP Technology

    Directory of Open Access Journals (Sweden)

    Amry Daulat Gultom

    2016-07-01

    Full Text Available High Altitude Platform (HAP merupakan solusi alternatif untuk mengatasi keterbatasan infrastruktur terestrial maupun satelit. HAP merupakan pesawat ataupun balon udara yang ditempatkan pada ketinggian 20-50 km di atas permukaan bumi. Kelebihan yang utama dari HAP adalah kemudahan dalam penempatan, fleksibilitas, biaya operasionalnya rendah, delay  propagasi rendah, sudut elevasi lebar, cakupan yang luas. Penelitian ini dilakukan untuk mengetahui potensi HAP untuk komunikasi pita lebar dan perkembangannya di Indonesia. Analisis dilakukan secara deskriptif dengan mengolah data literatur yang didapat. Hasil penelitian menunjukkan bahwa di Indonesia terdapat potensi teknologi HAP untuk komunikasi pita lebar dengan lebar pita 2x300 MHz di band 27,9-28,2 GHz dan 31-31,3 GHz. Namun, belum ada peraturan yang mengatur alokasi frekuensi untuk HAP secara khusus di Indonesia.*****High Altitude Platform (HAP has been developed as an alternative solution in order to overcome limitation of terrestrial and satellite communication system. HAP is an aircraft or balloon situated on 20-50 km above the earth. Main advantages of HAP are flexibility in deployment, low propagation delay, wide elevation angle and broad coverage. The research is conducted to gather HAP potential for broadband communication and its development in Indonesia. Analysis is conducted by descriptive analysis from literature study gather. The research result shows that in Indonesia, there is potential of HAP technology for broadband communication with 2x300 MHz bandwidth within 27,9-28,2 GHz and 31-31,3 GHz. Yet, there are no specific regulations managing frequency allocation for HAP in Indonesia.

  7. Teknologi Pengendalian Gulma Alang-alang dengan Tanaman Legum untuk Pertanian Tanaman Pangan

    Directory of Open Access Journals (Sweden)

    Ishak Juarsah

    2015-07-01

    Full Text Available Di Indonesia, Alang-alang (Imperata cylindrica L. Beauv merupakan salah satu gulma terpenting dan termasuk sepuluh gulma bermasalah di dunia.  Melalui biji dan rimpang, alang-alang dapat tumbuh dan menyebar luas pada hampir semua kondisi lahan. Teknologi pengendalian alang-alang telah banyak dikenal namun belum dapat menjamin eradikasi populasi alang-alang secara berkelanjutan tanpa diikuti oleh kultur teknis dan pola budidaya tanaman pangan sepanjang tahun. Hasil penelitian menunjukan bahwa lahan alang-alang dapat dikendalikan/dikelola menjadi lahan produktif setelah direhabilitasi dengan tanaman legume (Mucuna sp. untuk usaha tani tanaman pangan lahan kering berorientasi konservasi tanah. Bahan hijauan tanaman Mucuna dapat meningkatkan kadar C-organik, memperbaiki sifat fisika, kimia tanah dan meningkatkan  produksi tanaman pangan. In Indonesia, Alang-alang (Imperata cylindrica L. Beauv is one of important weeds and included to ten most problematic weeds around the world. Through its seeds and roots, alang-alang can grow and expand in nearly all soil conditions. Many technologies for controlling have been known but can not ensure the eradication of weeds population, however the controlling via food crops cropping systems for the whole years is the best method so far to have sustainability of the agriculture land. Research showed that alang-alang area could be controlled/managed became more productive land after rehabilitation with legume (ie Mucuna sp. especially for dry land conservation oriented. Mucuna green materials might increase C-organic content, both soil chemical and physical improvement, furthermore increased foodcrops production.

  8. PERAN KEPEMIMPINAN KONTAK TANI DALAM PROSES DIFUSI INOVASI TEKNOLOGI PENGELOLAAN TANAMAN DAN SUMBERDAYA TERPADU PADI

    Directory of Open Access Journals (Sweden)

    Pepi Rospina Pertiwi

    2013-03-01

    Full Text Available Farmers group is lead by a farmer leader that was expected to improve a dynamic of group activities. The farmer leader has significant role in ensuring the relationship between farmers in relation to the information sharing of the agricultural innovation. This study was aimed to examine the leadership role of the farmer leaders in the process of technology diffusion namely PTT Paddy, an innovation that was currently being introduced. An explanatory research design was chosen to describe the phenomenon of the leadership role of farmer leaders that was evaluated by other farmers. The research was conducted in the subdistrict Carenang, Serang, Banten. Forty participants in successfull farmer groups were selected to evaluate farmer leadership characteristics. The results showed that the farmer leaders have been helping the group to achieve goals, improving communication, increasing the motivation of the farmers, facilitating the farming infrastructure, and solving problems. The role of the farmer leaders as bridging agent in communication is categorized satisfactory. This role is effectively used in the process of the innovation dissemination of PTT Paddy to the farmers. Kelompok tani dipimpin oleh seorang kontak tani yang diharapkan dapat meningkatkan dinamika kegiatan kelompok. Kontak tani memiliki peran penting dalam memastikan hubungan antara petani dengan berbagi informasi mengenai inovasi pertanian. Penelitian ini bertujuan untuk meneliti peran kontak tani dalam proses difusi teknologi yaitu Pengelolaan Tanaman dan Sumberdaya Terpadu (PTT Padi, sebuah inovasi yang saat ini sedang diperkenalkan. Desain penelitian adalah eksplanatory research dipilih untuk menggambarkan fenomena peran kontak tani yang dievaluasi oleh petani lain. Penelitian dilakukan di Kecamatan Carenang, Serang, Banten. Empat puluh peserta dalam kelompok tani terpilih untuk mengevaluasi karakteristik kontak tani. Hasil penelitian menunjukkan bahwa kontak tani telah membantu

  9. TechTutorer - en ny måde at integrere teknologi i læreruddannelsen?

    DEFF Research Database (Denmark)

    Heiberg, Tobias; Arstorp, Ann-Thérèse

    ’TechTutor-enheden’ skal ses. I rapporten uddybes initiativet, men helt enkelt kan TechTutorerne beskrives som en gruppe af lærerstuderende med særlige kompetencer og interesser inden for det teknologiske felt. Og de samarbejder som TechTutorer om udbud af diverse kursusforløb samt udvikling af...... læreruddannelsen, når det kommer til didaktisering og implementering af teknologi – alt sammen med rapportens forfattere som koordinerende og kvalificerende element. TechTutor-initiativet skal altså overordnet ses som et eksperiment, der centrerer sig omkring nye vinkler på kvalificering og optimering af...

  10. PERAN DUKUNGAN ORGANISASIONAL, KOMPETENSI TEKNOLOGI DAN LINGKUNGAN EKSTERNAL DALAM RANGKA MENDORONG PENGADOPSIAN E-COMMERCE PADA USAHA KECIL MENENGAH

    Directory of Open Access Journals (Sweden)

    Audita Nuvriasari

    2014-07-01

    menjadi kendala dan pendorong bagi UKM dalam mengadopsi e-commerce dan untuk mengetahui pengaruh dari dukungan organisasional, kompetensi teknologi dan lingkungan eksternal terhadap pengadopsian e-commerce. Jumlah sampel penelitian sebanyak 34 UKM yang ada di wilayah Moyudan, DIY yang telah menggunakan teknologi informasi (internet dalam kegiatan bisnisnya. Penelitian ini menggunakan metode deskriptif dan inferensial untuk memecahkan permasalahan penelitian. Berdasarkan hasil analisis deskriptif dapat ditunjukkan bahwa tujuan utama UKM menggunakan internet dalam kegiatan bisnisnya adalah untuk pencarian informs bisnis (97,1%. Sedangkan faktor utama yang menjadi penghambat bagi UKM dalam mengadopsi e-commerce adalah keterbatasan kemampuan dan ketermpilan sumber daya manusia dalam penguasaan teknologi informasi (70,6%. Manfaat utama yang diperoleh UKM dengan pengadopsian e-commerce dalam menjalankan kegiatan bisnisnya adalah dapat dengan mudah mengakses informasi bisnis (85,3%. Hasil lain dari penelitian ini menjelaskan bahwa terdapat pengaruh yang positip dan signifikan antara dukungan organisasional, kompetensi teknologi dan lingkungan eksternal terhadap pengadopsian e-commerce. Kata Kunci: e-commerce, dukungan organisasional, kompetensi teknologi, lingkungan eksternal

  11. EVALUASI PROGRAM PEMBERDAYAAN PETANI MELALUI TEKNOLOGI DAN INFORMASI PERTANIAN USAHA TERNAK DOMBA

    Directory of Open Access Journals (Sweden)

    Desy Anggar Sary

    2017-06-01

    Full Text Available Pemberdayaan SDM pertanian perlu terus dikembangkan agar semakin maju dan efisien serta diarahkan untuk meningkatkan kuantitas dan kualitas produksi. Tujuan penelitian ini adalah mengevaluasi dan menganalisis pelaksanaan program, kendala yang dihadapi dan solusi program, strategi program pemberdayaan petani melalui teknologi dan informasi pertanian pada usaha ternak domba di Kabupaten Temanggung. Hasil penelitian menunjukkan 1 pelaksanaan program tersebut telah sesuai dengan komponen A, B dan E, 2 kendala yang dihadapi  penyuluh berkaitan  dengan SDM  termasuk  rendah dengan  solusi  memberikan  penyuluhan dengan bahasa yang mudah dipahami oleh petani; kendala yang dihadapi petani adalah kesulitan mendapatkan pakan ternak segar pada musim kemarau dengan solusi mencari sumber protein lain, pemasaran hasil ternak domba terbatas dan munculnya pesaing dengan solusi peningkatan kualitas hasil ternak yang kompetitif, 3 strategi pemberdayaan mencakupi kegiatan memberi pelatihan secara nyata dan tepat guna serta intensifikasi  pengelolaan pertanian dan peternakan domba. Kesimpulan dalam penelitian ini bahwa program FEATI/P3TIP komponen A,B dan E telah dilaksanakan di Desa Purwodadi Kecamatan Tembarak Kabupaten Temanggung sehingga mampu memberdayakan petani melalui UP FMA menjadi embrio agribisnis. Diajukan saran agar diberikan pelatihan dasar pertanian dan peternakan untuk meningkatkan pengetahuan petani peserta program pemberdayaan.  The agricultural human resources empowermentneed to develop to be more advanced and efficient and directed to improve the quantity and quality of production. The purpose of this study was to evaluate and analyze the execution of the program, the obstacles encountered and solutions programs, strategies farmer empowerment through technology and information on the business of sheep farming in the district Temanggung.The results showed; 1 implementation of the program in accordance  with the component A, B and E, 2

  12. Penilaian Kandungan Komponen Teknologi Humanware pada IKM (Studi Kasus: IKM Mebel Propinsi DI. Yogyakarta

    Directory of Open Access Journals (Sweden)

    Siti Rohmatul Umah

    2016-04-01

    Full Text Available ABSTRAKKemampuan sumber daya manusia (humanware merupakan faktor penentu dalam keberhasilan suatu organisasi dalam menghadapi tantangan-tantangan perusahaan dalam era globalisasi. Usaha perbaikan dan pengembangan SDM dapat dilakukan secara terarah dan optimal bila diketahui terlebih dahulu kondisi dari komponen humanware pada suatu perusahaan. Penelitian ini bertujuan untuk menilai kandungan komponen humanware pada IKM mebel di propinsi DI Yogyakarta. Perhitungan dilakukan dengan menggunakan metode technometrik. Data diperoleh dengan menyebarkan kuesioner pada sampel 20 IKM mebel DIY dengan dua kategori pemilik dan pekerja. Perhitungan data dilakukan dengan metode teknometrik. Hasil penelitian menunjukkan bahwa batas bawah kecanggihan humanware kategori pemilik ada pada level 1 klasifikasi kemampuan mengoperasikan dan batas atas ada pada level 3 klasifikasi kemampuan memperbaiki. Sedangkan untuk kategori pekerja, batas bawah ada pada level 1 klasifikasi kemampuan mengoperasikan dan batas atas pada level 3 klasifikasi memperbaiki. Hal ini mengimplikasikan bahwa sumber daya manusia pada IKM Mebel baik pemilik dan pekerja memiliki kemampuan yang sama yaitu mempunyai kemampuan dan ketrampilan mengoperasikan dan memperbaiki peralataan produksi. Kata kunci : Kandungan teknologi, humanware, IKM MebelABSTRACTOne of methods performance improving in Small and Medium Industries is by improve technology capability. One of technology components is humanware, where human resource capability in a organization is determinant of organization’s succesfull in facing treats in globalization era. The Improvement and development programs for human resources can be implemented optimally if is known already the conditions of humanware in a organization. The paper is aim to assess humanware content in SME’s in furniture industry with using technometric method. Sample of observation was 20 participants from SME’s Furniture in Yogyakarta province. Respondents

  13. PERANCANGAN ARSITEKTUR E-BISNIS UNTUK LAYANAN PERSEWAAN VIDEO COMPACT DISC BERBASIS TEKNOLOGI SHORT MESSAGE SERVICE

    Directory of Open Access Journals (Sweden)

    Yulia Yulia

    2006-01-01

    Full Text Available Technological growth has made a strong friction to the market. Customer becomes an important factor which must be paid attention to. Information which is easy to get increases customer's bargaining power. Customer always wants to get what they desire easily, cheaper, and of good quality. This structural change obliges a company to develop an e-Business strategy which is innovative, by focusing on the market. This structural change also requires a change in the business process on a large scale. At the same time, company has to develop an e-Business infrastructure that is oriented toward continuous service improvement and innovation. PT. V faces this structural change by developing an e-Business system for a VCD rental service. Using the system, which administers VCD rental with delivery system and SMS facility, customers can, by themselves, loan VCDs, return loaned VCDs, browse newest films, and perform other activities, just by sending SMS, without having to visit the rental place. For this reason, the customers will save time and money, become more efficient and effective. The use of SMS as a facility in e-Business has various advantages such as omitting problems with location and time for doing business, and omitting the errors of manual processing. In the end, e-Business is expected to raise market share and to adapt the company's business process according to customer's needs. Abstract in Bahasa Indonesia : Perkembangan teknologi telah membuat adanya pergeseran kekuatan kepada pelanggan atau pasar. Pelanggan menjadi faktor penting yang harus diperhatikan. Informasi yang semakin mudah diperoleh, membuat daya tawar pelanggan semakin tinggi dan pelanggan selalu ingin mendapat yang diinginkan dengan mudah, murah, berkualitas dan sesuai dengan kebutuhannya. Perubahan struktural ini mengharuskan sebuah perusahaan untuk mengembangkan sebuah strategi e-Bisnis yang inovatif, dengan memusatkan perhatian kepada pasar. Perubahan struktural ini juga

  14. The modal transfer analysis by adding transport costs. Case study: The use of bus and private vehicle student Institut Teknologi Sumatera

    Science.gov (United States)

    Muliarto, H.; Alhamidi; Syahbandi, M.

    2017-06-01

    Since the last two years the Institut Teknologi Sumatera to accept new students in large numbers. Increasing the number of students is directly proportional to the increase of private vehicles that enter the campus it is not in line with the policy of the Institut Teknologi Sumatera as Smart, Friendly, and Forest Campus. Institut Teknologi Sumatera as Smart, Friendly, and Forest Campus fact has made some deal with mass public transport, Damri, to provide bus transportation to the Institut Teknologi Sumatera, but the number of bus users is still inferior to the number of private vehicle users. This study was conducted to see the modal transfer of the entire academic community ITERA, from private cars to public transport such as buses, with the addition of transportation costs in the form of parking rates. This study shows the dominant displacement can occur if the respondent charged parking fees of IDR 4.000. Besides the displacement mode of transportation from using private vehicles be using the bus can occur if Trans Lampung fix three systems including bus departure and arrival schedules, facility service providers that support, and the addition of the Bus Trans Lampung.

  15. Når vi taler om 68

    DEFF Research Database (Denmark)

    Jensen, Henrik; Metz, Georg

    Når vi taler om 68 er en intellektuel samtale mellem to ligeværdige gentlemen og skallesmækkere. En essayistisk dyst om porno, RAF, Pittelkow og livsfilosofi......Når vi taler om 68 er en intellektuel samtale mellem to ligeværdige gentlemen og skallesmækkere. En essayistisk dyst om porno, RAF, Pittelkow og livsfilosofi...

  16. Econophys-Kolkata VI Conference

    CERN Document Server

    Chakrabarti, Bikas; Chakraborti, Anirban; Ghosh, Asim

    2013-01-01

    The primary goal of the book is to present the ideas and research findings of active researchers such as physicists, economists, mathematicians and financial engineers working in the field of “Econophysics,” who have undertaken the task of modeling and analyzing systemic risk, network dynamics and other topics. Of primary interest in these studies is the aspect of systemic risk, which has long been identified as a potential scenario in which financial institutions trigger a dangerous contagion mechanism, spreading from the financial economy to the real economy. This type of risk, long confined to the monetary market, has spread considerably in the recent past, culminating in the subprime crisis of 2008. As such, understanding and controlling systemic risk has become an extremely important societal and economic challenge. The Econophys-Kolkata VI conference proceedings are dedicated to addressing a number of key issues involved. Several leading researchers in these fields report on their recent work and al...

  17. An electrochemical study of U(VI) and Cr(VI) in molten borates

    International Nuclear Information System (INIS)

    Brigaudeau, M.; Gregori de Pinochet, I. de

    1977-01-01

    The electrochemical reduction of U(VI) and Cr(VI), in molten Na 2 B 4 O 7 at 800 deg C was studied by means of linear sweep voltammetry, and chronopotentiometry. The reduction of U(VI) to U(V) proceeded reversibly at a platinum electrode. The diffusion coefficient for the U(VI) species at 800 deg C was 4.10 -7 cm 2 .s -1 . The activation energy of diffusion was (34,8 +- 0,8) kcal. mole -1 . Electrochemical studies of Cr(VI) at 800 0 C reveal a two-step reduction process at a platinum electrode. Only the voltammogram for the first step charge transfer process was studied. Analysis indicated that Cr(VI) is reversibly reduced to Cr(III) at a platinum electrode. The diffusion coefficient for Cr(VI) at 800 0 C is 1,9.10 -7 cm 2 .s -1 [fr

  18. PEMBUATAN PROTOTIPE APLIKASI WEB SERVICES BERBASIS XML MENGGUNAKAN TEKNOLOGI J2EE DENGAN STUDI KASUS RESERVASI HOTEL

    Directory of Open Access Journals (Sweden)

    Isye Arieshanti

    2005-01-01

    Full Text Available Normal 0 false false false IN X-NONE X-NONE MicrosoftInternetExplorer4 /* Style Definitions */ table.MsoNormalTable {mso-style-name:"Table Normal"; mso-tstyle-rowband-size:0; mso-tstyle-colband-size:0; mso-style-noshow:yes; mso-style-priority:99; mso-style-qformat:yes; mso-style-parent:""; mso-padding-alt:0cm 5.4pt 0cm 5.4pt; mso-para-margin:0cm; mso-para-margin-bottom:.0001pt; mso-pagination:widow-orphan; font-size:11.0pt; font-family:"Calibri","sans-serif"; mso-ascii-font-family:Calibri; mso-ascii-theme-font:minor-latin; mso-fareast-font-family:"Times New Roman"; mso-fareast-theme-font:minor-fareast; mso-hansi-font-family:Calibri; mso-hansi-theme-font:minor-latin; mso-bidi-font-family:"Times New Roman"; mso-bidi-theme-font:minor-bidi;} Dalam era globalisasi, para pelaku bisnis secara intensif melakukan usaha-usaha untuk memasuki pasar global. Suatu perusahaan semakin membutuhkan transaksi  bisnis yang bersifat fleksibel, yang bisa dilakukan dengan siapa saja, kapan saja dan dimana saja. Tentunya sistem informasi yang dimiliki perusahaan tersebut harus bisa berkomunikasi dengan sistem yang dimiliki oleh patner bisnis, tanpa harus terlalu banyak perjanjian dan persetujuan. Hal ini berarti diperlukan standard infrastruktur sederhana untuk pertukaran data bisnis.Kebutuhan ini dapat dipenuhi oleh teknologi web service sebagai teknologi yang menyediakan infrastruktur sederhana bagi pelaku bisnis untuk berkomunikasi melalui pertukaran pesan XML. Pada Penelitian ini dikembangkan sebuah prototipe aplikasi web service dengan studi kasus reservasi hotel melalui perantara broker. Studi kasus ini dipilih karena dapat merepresentasikan sistem yang terdistribusi. Dimana broker berperan sebagai penghubung antara customer dan beberapa sistem yang terdistribusi.Pada pembuatan aplikasi ini dipilih teknologi J2EE karena framework J2EE yang telah ada mendukung penerapan web service. Dan selain itu, J2EE bersifat netral terhadap berbagai macam platform (tidak

  19. Emissions of chromium (VI) from arc welding.

    Science.gov (United States)

    Heung, William; Yun, Myoung-Jin; Chang, Daniel P Y; Green, Peter G; Halm, Chris

    2007-02-01

    The presence of Cr in the +6 oxidation state (Cr[VI]) is still observed in ambient air samples in California despite steps taken to reduce emissions from plating operations. One known source of emission of Cr(VI) is welding, especially with high Cr-content materials, such as stainless steels. An experimental effort was undertaken to expand and update Cr(VI) emission factors by conducting tests on four types of arc-welding operations: gas-metal arc welding (GMAW), shielded metal arc welding (SMAW), fluxcore arc welding, and pulsed GMAW. Standard American Welding Society hood results were compared with a total enclosure method that permitted isokinetic sampling for particle size-cut measurement, as well as total collection of the aerosol. The fraction of Cr(VI) emitted per unit mass of Cr electrode consumed was determined. Consistent with AP-42 data, initial results indicate that a significant fraction of the total Cr in the aerosol is in the +6 oxidation state. The fraction of Cr(VI) and total aerosol mass produced by the different arc welding methods varies with the type of welding process used. Self-shielded electrodes that do not use a shield gas, for example, SMAW, produce greater amounts of Cr(VI) per unit mass of electrode consumed. The formation of Cr(VI) from standard electrode wires used for welding mild steel was below the method detection limit after eliminating an artifact in the analytical method used.

  20. Anaerobic bio-removal of uranium (VI) and chromium (VI): Comparison of microbial community structure

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Monica [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Faleiro, Maria Leonor [IBB - Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Chaves, Sandra; Tenreiro, Rogerio [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biodiversidade, Genomica Integrativa e Funcional (BioFIG), Campus de FCUL, Campo Grande 1749-016 Lisboa (Portugal); Santos, Erika [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, Maria Clara, E-mail: mcorada@ualg.pt [Centro de Ciencias do Mar, Universidade do Algarve, Campus de Gambelas, 8005-139 Faro (Portugal)

    2010-04-15

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L{sup -1} U(VI) and 99% of 13 mg L{sup -1} Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  1. Anaerobic bio-removal of uranium (VI) and chromium (VI): Comparison of microbial community structure

    International Nuclear Information System (INIS)

    Martins, Monica; Faleiro, Maria Leonor; Chaves, Sandra; Tenreiro, Rogerio; Santos, Erika; Costa, Maria Clara

    2010-01-01

    Several microbial communities, obtained from uranium contaminated and non-contaminated samples, were investigated for their ability to remove uranium (VI) and the cultures capable for this removal were further assessed on their efficiency for chromium (VI) removal. The highest efficiency for removal of both metals was observed on a consortium from a non-contaminated soil collected in Monchique thermal place, which was capable to remove 91% of 22 mg L -1 U(VI) and 99% of 13 mg L -1 Cr(VI). This study revealed that uranium (VI) removing communities have also ability to remove chromium (VI), but when uranium (VI) was replaced by chromium (VI) several differences in the structure of all bacterial communities were observed. TGGE and phylogenetic analysis of 16S rRNA gene showed that the uranium (VI) removing bacterial consortia are mainly composed by members of Rhodocyclaceae family and Clostridium genus. On the other hand, bacteria from Enterobacteriaceae family were detected in the community with ability for chromium (VI) removal. The existence of members of Enterobacteriaceae and Rhodocyclaceae families never reported as chromium or uranium removing bacteria, respectively, is also a relevant finding, encouraging the exploitation of microorganisms with new abilities that can be useful for bioremediation.

  2. Learning the vi and Vim Editor

    CERN Document Server

    Robbins, Arnold; Hannah, Elbert

    2008-01-01

    There's nothing that hard-core Unix and Linux users are more fanatical about than their text editor. Editors are the subject of adoration and worship, or of scorn and ridicule, depending upon whether the topic of discussion is your editor or someone else's. vi has been the standard editor for close to 30 years. Popular on Unix and Linux, it has a growing following on Windows systems, too. Most experienced system administrators cite vi as their tool of choice. And since 1986, this book has been the guide for vi. However, Unix systems are not what they were 30 years ago, and neither is this

  3. KAJIAN KELAYAKAN INVESTASI PROYEK TEKNOLOGI INFORMASI DENGAN MENGGUNAKAN METODE INFORMATION ECONOMICS

    Directory of Open Access Journals (Sweden)

    Yulia Yulia

    2005-01-01

    Full Text Available Most people argue that Information System (IS/Information System (IT investments are closely related to cost and benefit without understand the benefit that will be received. However, companies keep investing money to create application systems because they have seen some relationship between the costs of IT and the economic performance of company. Costs are much easier to identify and calculate then benefits, especially intangible benefits. The hardest and most tedious part is the effort to quantify intangible benefits into monetary values in order to make the cost-benefit analysis more accurate. Most of business and IS/IT managers prefer not to go into detail when talking about intangible benefits because the depth of analysis is uncertain. The more practical way in using this financial approach is to focus on tangible benefits, such as cost saving, reduced staff, etc. Unfortunately, reducing or even eliminating the intangible benefits contribution to the IS/IT implementation has degraded the economic value of the investment. Based on this issue, some thinkers have introduced a much more practical way for business and IS/IT managers to get snapshots of how IS/IT investment is going to be measured, for example, using the non-financial approach. Some people believe that the two approaches must be combined to have a better and more accurate result. In this paper, information economics methodology, which combines both financial and non-financial approaches, will be used to assess and justify IS/IT investment. Abstract in Bahasa Indonesia : Investasi Sistem Informasi (SI/Teknologi Informasi (TI seringkali hanya dipandang sebagai suatu biaya yang harus dikeluarkan tanpa tahu manfaat apa yang akan diperoleh. Akan tetapi investasi terhadap suatu sistem aplikasi terus dilakukan karena perusahaan melihat bahwa ada hubungan antara biaya TI dengan performa ekonomi dari perusahaan. Biaya lebih mudah diidentifikasikan dan dihitung dibandingkan manfaat

  4. Perancangan Dan Realisasi Sistem Transmisi Data GPS Menggunakan Teknologi SMS (Short Messaging Service Sebagai Aplikasi Sistem Personal Tracking

    Directory of Open Access Journals (Sweden)

    DECY NATALIANA

    2017-06-01

    Full Text Available Abstrak Berprinsip pada pengembangan teknologi dan aplikasi dari sistem penjejakan posisi (tracking, maka dibuatlah sistem personal tracking dengan mentransmisikan data GPS (Global Positioning System dengan menggunakan teknologi SMS (Short Messaging Service pada jaringan GSM (Global System for Mobile Communications sebagai media transmisinya.  Dengan sistem GPS akan diperoleh data garis lintang, serta garis bujur dari GPS receiver.  Data tersebut akan diteruskan oleh mikrokontroler untuk dikirim ke ponsel pengamat melalui komunikasi SMS.  Hasil pengujian menunjukkan bahwa device personal tracking berhasil mengirimkan data berupa IMEI, Tanggal satelit, waktu satelit, koordinat longitude, koordinat latitude, dan jumlah satelit yang berhasil ditangkap oleh device ke ponsel pengamat.  Dari data koordinat tersebut pengamat dapat memantau posisi device personal tracking berada dengan bantuan aplikasi pendukung yaitu Google Maps. Kata kunci: GPS, Personal Tracking, SMS, Google Maps.   Abstract Base on technology and application development of tracking, personal tracking system was made by transmiting GPS (Global Positioning System data using SMS (Short Messaging Service technology with GSM (Global System for Mobile Communications network as transmitter media.  BY GPS system, we can get datas such as latitude and longitude of GPS receiver.  Those datas will be processed by microcontroller to be sent from GSM/GPRS module to user cellular phone through SMS communication.  The test result showed that the device can be sending datas such as IMEI, UTC date, UTC time, longitude coordinate, latitude coordinate, and number sattelite which detected by device to user’s phonecell.  From those coordinate, user can be monitoring the device’s position with the Google Maps application. Keywords: GPS, Personal Tracking, SMS, Google Maps.

  5. Extended analysis of Mo VI

    International Nuclear Information System (INIS)

    Edlen, B.; Rahimullah, K.; Tauheed, A.; Chaghtai, M.S.Z.

    1985-01-01

    The analysis of the RbI-like spectrum Mo VI has been extended to include a total of some 110 classified lines and 44 energy levels belonging to the one-electron configurations 4s 2 4p 6 ( 1 S)nl with n ranging up to 9 and l up to 7. The analysis is based on recordings of vacuum spark spectra made at Lund in the region 230-2350 A, complemented by a list of lines from 2193 to 6336 A observed and identified by Romanov and Striganov in a Penning type arc discharge. The one-electron level system is partly mixed with core-excited configurations, not treated in the present paper. Especially the nf series is strongly perturbed by 4s 2 4p 5 4d 2 , and an anomalous behaviour of the ng series is explained by interaction with the 2 G term of 4s4p 6 4d 2 . The ionization limit, derived from 6h, 7i and 8k by means of the polarization formula, is found to be 555 132+-2 cm -1 . (orig.)

  6. Kiintoainehäviöselvitys

    OpenAIRE

    Ylimys, Jussi

    2014-01-01

    Teoriaosassa käydään läpi yleisesti pyörrepuhdistuslaitoksen toimintaa sekä kiintoainehäviöitä paperi- ja kartonkitehtailla. Tämän opinnäytetyön tarkoituksena oli tutkia Metsä Boardin Kyröskosken tehtaan kiintoainehäviötä. Työssä selvitettiin, minkälaista kiintoainetta jätevesilaitokselle päätyy ja miksi. Selvityksen kohteena oli myös, missä kohteissa kiintoainehäviöt tarkalleen syntyvät ja kuinka paljon häviötä tapahtuu. Kahden edellä mainitun tiedon perusteella selvitettiin, kuinka palj...

  7. 29 CFR 1910.1026 - Chromium (VI).

    Science.gov (United States)

    2010-07-01

    ... allows employees to consume food or beverages at a worksite where chromium (VI) is present, the employer... effect on productivity. 2. Plating Bath Surface Tension Management and Fume Suppression • Lower surface...

  8. 24 CFR 971.11 - HOPE VI developments.

    Science.gov (United States)

    2010-04-01

    ... 24 Housing and Urban Development 4 2010-04-01 2010-04-01 false HOPE VI developments. 971.11... § 971.11 HOPE VI developments. Developments with HOPE VI implementation grants that have approved HOPE... with reasonable revitalization plans. Future HUD actions to approve or deny proposed HOPE VI...

  9. Uranium(VI) speciation by spectroscopy

    International Nuclear Information System (INIS)

    Meinrath, G.

    1997-01-01

    The application of UV-Vis and time-resolved laser-induced fluorescence (TRLF) spectroscopies to direct of uranium(VI) in environmental samples offers various prospects that have, however, serious limitations. While UV-Vis spectroscopy is probably not sensitive enough to detect uranium(VI) species in the majority of environmental samples, TRLFS is principially able to speciate uranium(VI) at very low concentration levels in the nanomol range. Speciation by TRLFS can be based on three parameters: excitation spectrum, emission spectrum and lifetime of the fluorescence emission process. Due to quenching effects, the lifetime may not be expected to be as characteristics as, e.g., the emission spectrum. Quenching of U(VI) fluorescence by reaction with organic substances, inorganic ions and formation of carbonate radicals is one important limiting factor in the application of U(VI) fluorescence spectroscopy. Fundamental photophysical criteria are illustrated using UV-Vis and fluorescence spectra of U(VI) hydrolysis and carbonato species as examples. (author)

  10. Plutonium(VI) accumulation and reduction by lichen biomass: correlation with U(VI)

    International Nuclear Information System (INIS)

    Ohnuki, Toshihiko; Aoyagi, Hisao; Kitatsuji, Yoshihiro; Samadfam, Mohammad; Kimura, Yasuhiko; William Purvis, O.

    2004-01-01

    The uptake of plutonium(VI) and uranium(VI) by lichen biomass was studied in the foliose lichen Parmotrema tinctorum to elucidate the migration behavior of Pu and U in the terrestrial environment. Pu and U uptake by P. tinctorum averaged 0.040±0.010 and 0.055±0.015 g g dry -1 , respectively, after 96 h incubation with 4.0x10 -4 mol l -1 Pu solutions of pH 3, 4 and 5. SEM observations showed that the accumulated Pu is evenly distributed on the upper and lower surfaces of P. tinctorum, in contrast to U(VI), which accumulated in both cortical and medullary layers. UV/VIS absorption spectroscopy demonstrates that a fraction of Pu(VI) in the solution is reduced to Pu(V) by the organic substances released from P. tinctorum, and the accumulated Pu on the surface is reduced to Pu(IV), while U(VI) keeps the oxidation state of VI. Since the solubility of Pu(IV) hydroxides is very low, reduced Pu(VI) does not penetrate to the medullary layers, but is probably precipitated as Pu(IV) hydroxides on the cortical lichen surface. It is concluded that the uptake and reduction of Pu(VI) by lichens is important to determine the mobilization and oxidation states of Pu in the terrestrial environment

  11. Teknologi og forskningslære i videregående skole: Hvem er lærerne og hvordan former de faget?

    Directory of Open Access Journals (Sweden)

    Berit Bungum

    2009-05-01

    Full Text Available Teknologi og forskningslære er et nytt og mangfoldig programfag i videregående skole. Denne artikkelen presenterer en undersøkelse av lærerne i dette faget: hva slags bakgrunn de har, hva de ser som sine styrker og utfordringer i å undervise faget, og hvordan de med utgangspunkt i sin kompetanse realiserer ideene bak læreplanen. Undersøkelsen er utført som en skriftlig spørreundersøkelse med utdypende intervjuer med utvalgte lærere. Resultatene viser at lærerne som har deltatt i undersøkelsen samlet sett er en svært kompetent gruppe, men at de i stor grad framtrer som enten "teknolog" eller "forsker" i hva de ser som sine styrker og utfordringer i faget. Videre beskrives hvordan to lærere, som representerer arketyper av lærere i disse to gruppene, tolker læreplanen ulikt i lys av sin egen kompetanse, og hvordan de på ulike måter realiserer innholdet i Teknologi og forskningslære som fag ved sine skoler.

  12. Analisis Quality of Service (QoS Jaringan Telekomunikasi High-Speed Downlink Packet Access (HSDPA pada Teknologi 3.5G

    Directory of Open Access Journals (Sweden)

    Mey Fenny Wati Simanjuntak

    2016-01-01

    Full Text Available Sejak layanan teknologi 3G pertama kali diperkenalkan, permintaan akan layanan berbasis paket data dari tahun ke tahun mengalami peningkatan yang pesat. Menanggapi hal tersebut, para penyedian jaringan telekomunikasi terus berusaha untuk meningkatkan kemampuan jaringannya. Salah satu solusinya menerapkan teknologi High-Speed Downlink Packet Access yang direkomendasikan oleh 3GPP Release 5. Penelitian ini dikhususkan untuk menganalisis Quality of Service jaringan telekomunikasi High-Speed Downlink Packet Access di Kecamatan Tembalang Kota Semarang. Analisis Quality of Service jaringan telekomunikasi High-Speed Downlink Packet Access pada penelitian ini bertujuan untuk memberikan gambaran kualitas jaringan telekomunikasi High-Speed Downlink Packet Access dari sisi bandwidth, throughput, packet loss dan delay. Metode penelitian yang dibahas dalam penelitian ini yaitu penelitian kualitatif observatif, dimana akan dilakukan pengamatan tentang bagaimana QoS jaringan telekomunikasi High-Speed Downlink Packet Access pada teknologi 3.5G di Kecamatan Tembalang Kota Semarang. Proses pengamatan dalam menganalisis Quality of Service jaringan telekomunikasi High-Speed Downlink Packet Access di Kecamatan Tembalang Kota Semarang berdasarkan 4 parameter diantaranya bandwidth, throughput, packet loss dan delay. Aplikasi yang digunakan yaitu monitoring application Elnus Bandwidth Meter dan Axence NetTools Professional 4.0. Selain itu, Quality of Service jaringan telekomunikasi High- Speed Downlink Packet Access di Kecamatan Tembalang Kota Semarang diamati berdasarkan waktu yaitu harian, mingguan dan bulanan.

  13. ViA: a perceptual visualization assistant

    Science.gov (United States)

    Healey, Chris G.; St. Amant, Robert; Elhaddad, Mahmoud S.

    2000-05-01

    This paper describes an automated visualized assistant called ViA. ViA is designed to help users construct perceptually optical visualizations to represent, explore, and analyze large, complex, multidimensional datasets. We have approached this problem by studying what is known about the control of human visual attention. By harnessing the low-level human visual system, we can support our dual goals of rapid and accurate visualization. Perceptual guidelines that we have built using psychophysical experiments form the basis for ViA. ViA uses modified mixed-initiative planning algorithms from artificial intelligence to search of perceptually optical data attribute to visual feature mappings. Our perceptual guidelines are integrated into evaluation engines that provide evaluation weights for a given data-feature mapping, and hints on how that mapping might be improved. ViA begins by asking users a set of simple questions about their dataset and the analysis tasks they want to perform. Answers to these questions are used in combination with the evaluation engines to identify and intelligently pursue promising data-feature mappings. The result is an automatically-generated set of mappings that are perceptually salient, but that also respect the context of the dataset and users' preferences about how they want to visualize their data.

  14. Aplikasi Penilaian Kinerja Dosen pada Proses Belajar Mengajar Berbasis Web: Studi Kasus di Badan Penjamin Mutu Internal Institut Teknologi Padang

    Directory of Open Access Journals (Sweden)

    Harison Son

    2017-05-01

    Full Text Available The lecturer has the main duty of Tridharma of Higher Education, namely education, research and community service. Currently, the assessment of lecturers using questionnaires by students at the Padang Institute of Technology is still ineffective and the data is less valid. With this application, the internal quality assurance agency of Padang Technology Institute will not be bothered to calculate student questionnaire data as much as 2500 people. The results of this application provide a detailed value to the lecturer, in which a lecturer has a low score and in which part a lecturer excels based on the question items. This value will be calculated by the application of each student who has filled the questionnaire. The application will provide information on the value of the whole lecturer and can be the basis to make improvements to the weakness of the lecturer in detail and accurately. This application is designed using PHP programming language and MySql database. Lecturer performance appraisal results can be obtained directly, to determine the highest to lowest score and can also see the results of the overall lecturer's score accessed on the account of each lecturer on the campus information system. Dosen mempunyai tugas pokok tridharma Perguruan Tinggi, yaitu pendidikan, penelitian dan pengabdian kepada masyarakat. Saat ini, penilaian dosen menggunakan kuesioner oleh mahasiswa di Institut Teknologi Padang masih tidak efektif dan datanya kurang valid. Dengan adanya Aplikasi ini badan penjamin mutu internal Institut Teknologi Padang tidak akan direpotkan untuk mengalkulasi data angket mahasiswa sebanyak 2500 orang. Hasil dari aplikasi ini memberikan nilai secara detail kepada dosen, di bagian mana seorang dosen yang mempunyai nilai rendah dan di bagian mana seorang dosen unggul berdasarkan item pertanyaan. Nilai ini akan di kalkulasi oleh aplikasi setiap mahasiswa yang telah mengisi kuesioner dan akan memberikan informasi nilai secara

  15. Geoinformation postgraduate education at Universiti Teknologi Malaysia - towards a centre of high quality postgraduate education and research

    Science.gov (United States)

    Peters, S.; Kanniah, K. D.; Rahman, A. A.

    2015-10-01

    Studying at Universiti Teknologi Malaysia (UTM) will ensure academic and technological excellence. The Faculty of Geoinformation and Real Estate (FGHT), established in 1972, focus on education and research for undergraduate as well as postgraduate programs in the related disciplines such as geomatic engineering, geoinformatics, remote sensing, property management and land administration & development. FGHT strives to be a leading academic center in geoinformation and real estate in Southeast Asia. Graduates and alumni form major strong professional societies and work force in the related industries. Many of our graduates end up with good jobs not just in Malaysia but also in other countries (Asian, Middle East, Africa and Europe). The strong team and knowledgeable academic members in this faculty provide excellent ingredients for the success of the programs (i.e. with the relevant and up-to-date curriculum and syllabus). FGHT is continuously working to provide and offer first-class geoinformation and real estate education and research in the country and be at a par with other leading institutions in other parts of the globe. The Department of Geoinformation at FGHT runs a Bachelor of Engineering in Geomatic and a Bachelor of Science in Geoinformatics. At the postgraduate levels, namely M.Sc. and PhD programs, the offered disciplines are Geomatic Engineering, Geoinformatics and Remote Sensing. In the following, the state of the art of FGHT's postgraduate education in Geoinformation is presented, including a comparison with other universities in Malaysia, program content and curriculum information, alumni statistics as well as future strategies.

  16. PEMETAAN BOBOT RISIKO DAN TINGKAT KEMAPANAN TEKNOLOGI INFORMASI MENUJU INTEGRASI EMPAT LEMBAGA PENDIDIKAN YPT MENGGUNAKAN COBIT 4.1

    Directory of Open Access Journals (Sweden)

    Sisilia Sari Dewi

    2017-04-01

    Full Text Available Penggabungan dari empat pendidikan tinggi di bawah Yayasan Pendidikan Telkom (YPT merupakan wujud implementasi visi YPT dalam mencapai world class university. Namun tidak dapat dipungkiri bahwa hal tersebut memunculkan tingkat kekhawatiran yang berbeda-beda terhadap suatu risiko pada proses TI yang sudah dijalankan. Begitu pula dengan tingkat kemapanan setiap proses TI yang merealisasikan sasaran pengendalian. Maka dari itu, perlu dibuat pemetaan terhadap profil risiko dan tingkat kemapanan pada masing-masing lembaga. Penelitian berfokus pada domain Plan and Organise,yang bertujuan untuk mendapatkan pemetaan proses TI di Telkom University berdasarkan COBIT 4.1, pemetaan profil risiko dan tingkat kemapanan di empat fakultas dengan kuadran prioritas, serta untuk mendapatkan teknik pengendalian umum untuk merealisasikan sasaran pengendalian dalam rangka integrasi manajemen menjadi Telkom University. Hasil penelitian menunjukkan bahwa keempat lembaga pendidikan tinggi yang bergabung menjadi Telkom University memiliki bobot risiko dan tingkat kemapanan proses TI yang berbeda-beda. Selain itu, proses-proses TI yang sudah dijalankan oleh masing-masing lembaga juga berbeda-beda. Berdasarkan hal tersebut, Telkom University sebaiknya melakukan integrasi terhadap pengelolaan teknologi informasi serta menerapkan langkah-langkah prioritas untuk proses TI yang berada dalam kuadran under-controlled

  17. Peranan Teknologi dalam Mendukung Proses Berpikir Level C3 Siswa pada Materi Operasi Himpunan melalui Penggunaan Swish Max4

    Directory of Open Access Journals (Sweden)

    Arinaldi Arinaldi

    2018-03-01

    Full Text Available Perkembangan teknologi pada abad ke-21 ini sudah sangat pesat, membuat guru menjadi lebih kreatif dalam hal membuat media pembelajaran yang inovatif, menarik, serta tidak ketinggalan zaman. Dengan menggunakan media visual guru dapat memberikan visual tertentu pada siswa dalam proses pembelajaran, yang nantinya diharapkan dapat membantu siswa dalam berpikir C3. Lalu dilatar belakangi oleh kemampuan siswa yang rendah dalam mengerjakan soal applikasi operasi pada himpunan dikehidupan sehari-hari sekaligus memvisualisasikan operasi himpunan, berdasarkan survei peneliti melalui wawancara dengan guru SMP Negeri 11 Tanjungpinang. Sehingga pada penelitian ini peneliti menggunakan media visual berbasis multimedia berbantuan software swish max4, untuk membantu siswa berpikir hingga level C3 atau pada ranah mengaplikasikan khususnya pada materi operasi himpunan dan juga dapat memvisualisasikan operasi himpunan dikehidupan sehari-hari. Telah dilakukan eksperimen di kelas VII.1 dan kelas VII.2 pada SMP Negeri 11 Tanjungpinang, memperoleh hasil posttest kelas eksperimen lebih tinggi 76,24 dibangdingkan dengan kelas kontrol 66,92, terbukti bahwa kelas yang diberikan treatment media swish max4  dapat membantu siswa dalam berpikir hingga level C3 atau mengapplikasikan. Kata kunci : Swish max4, berpikir level C3, Soal applikasi operasi himpunan

  18. 76 FR 60593 - Title VI; Proposed Circular

    Science.gov (United States)

    2011-09-29

    ..., several of them related to ambiguous language in the existing Circular. The proposed Circular reorganizes... regional entity, and inclusive of public and private entities. This term is used exclusively in Chapter IV... revisions to the Title VI Circular. The section that addresses the existing requirement for a Language...

  19. Chromium(VI) bioremediation by probiotics.

    Science.gov (United States)

    Younan, Soraia; Sakita, Gabriel Z; Albuquerque, Talita R; Keller, Rogéria; Bremer-Neto, Hermann

    2016-09-01

    Chromium is a common mineral in the earth's crust and can be released into the environment from anthropogenic sources. Intake of hexavalent chromium (Cr(VI)) through drinking water and food causes toxic effects, leading to serious diseases, and is a commonly reported environmental problem. Microorganisms can mitigate or prevent the toxic effects caused by heavy metals in addition to having effective resistance mechanisms to prevent cell damage and bind to these metals, sequestering them from the cell surface and removing them from the body. Species of Lactobacillus, Streptococcus, Bacillus and Bifidobacterium present in the human mouth and gut and in fermented foods have the ability to bind and detoxify some of these substances. This review address the primary topics related to Cr(VI) poisoning in animals and humans and the use of probiotics as a way to mitigate or prevent the toxic effects caused by Cr(VI). Further advances in the genetic knowledge of such microorganisms may lead to discoveries which will clarify the most active microorganisms that act as bioprotectants in bodies exposed to Cr(VI) and are an affordable option for people and animals intoxicated by the oral route. © 2016 Society of Chemical Industry. © 2016 Society of Chemical Industry.

  20. Vi har selv designet naturens love

    DEFF Research Database (Denmark)

    Bentzen, Martin Mose

    2014-01-01

    ForskerZonenNaturlovene er universelt gyldige i de flestes øjne. De gælder altid, uanset hvad vi tænker. Men dette billede står ikke uimodsagt i videnskabsfilosofien, og der er meget, der tyder på, at det ikke er specielt empirisk korrekt...

  1. Energy balance of ENDF/B-VI

    International Nuclear Information System (INIS)

    MacFarlane, R.E.

    1994-01-01

    ENDF/B-VI through Release 2 has been tested for neutron-photon energy balance using the Heater module of the NJOY nuclear data procesing system. The situation is much improved over ENDF/B-V, but there are still a number of maerials that show problems

  2. Tinjauan Hukum Internasional Terhadap Pengujian Nuklir Korea Utara

    OpenAIRE

    Helmi, Nuzul

    2016-01-01

    Nuclear is a brilliant creation were discovered accidentally by a lot of potential in it. This potentials makes nuclear becomes a tool with unpredictable effects. This fact is used as a reason to developed countries to make nuclear power as a tool to develop the potential of the country and even used in military purposes. The abuse of nuclear power is making countries in the world to form the world organization who can monitored the use of nuclear or IAEA with the objective of nuclear restric...

  3. ENERGI NUKLIR SEBAGAI SOLUSI UNTUK MENGHAMBAT PEMANASAN GLOBAL

    OpenAIRE

    Finahari, Ida Nuryatin

    2018-01-01

    Global warming is the increase in the average temperature of the earth surface, atmosphere and oceans.The global warming in recent years has been international issues. The issues come to the surfacebecause global warming has the very big impact to the world and the lives of animal, plant and human,such as world climate change. The main cause of global warming is the combustion of fossil fuel suchas coal, oil and natural gas, that released carbon dioxide and other gases to atmosphere as greenh...

  4. Enzymatic reduction of U(VI) in groundwaters

    International Nuclear Information System (INIS)

    Addelouas, A.; Gong, W.; Lutze, W.; Nuttall, E.; Fritz, B.; Crovisier, J.L.

    1999-01-01

    The use of enzymatic reduction of U(VI) in remediation of groundwater contaminated with U(VI) is receiving considerable attention. Certain strains of bacteria can combine the oxidation of an organic compound to the reduction of U(VI) to U(IV), which precipitates as uraninite. In the present study, we tested the reduction of U(VI) in groundwaters with various origins and compositions. In all groundwaters u(VI) was reduced by sulfate reducing bacteria that had been activated by ethanol and tri-metaphosphate. The reduction rate of U(VI) depends on sulfate concentration in water and the abundance of bacteria in the system. This work shows that bacteria capable of U(VI) reduction are ubiquitous in nature, and suggests the possibility of a large application of the enzymatic reduction of U(VI) for in situ clean up of groundwaters contaminated with uranium. (authors)

  5. 77 FR 64399 - Order of Succession for HUD Region VI

    Science.gov (United States)

    2012-10-19

    ... Region VI AGENCY: Office of Field Policy and Management, HUD. ACTION: Notice of Order of Succession... its Field Offices (Region VI). This Order of Succession supersedes all previous Orders of Succession for HUD Region VI. DATES: Effective Date: October 9, 2012. FOR FURTHER INFORMATION CONTACT: Lawrence D...

  6. ENDF-201, ENDF/B-VI summary documentation supplement 1, ENDF/HE-VI summary documentation

    International Nuclear Information System (INIS)

    McLane, V.

    1996-12-01

    The National Nuclear Data Center (NNDC) provides coordination for and serves as the secretariat to the Cross Section Evaluation Working Group (CSWEG). CSEWG is responsible for the oversight of the ENDF/B Evaluated Nuclear Data File. All data are checked and reviewed by CSEWG, and the file is maintained at the NNDC. For a description of the ENDF/B-VI file, see the ENDF-102 Data Formats and Procedures for the Evaluated Nuclear Data File ENDF-6. The purpose of this addendum to the ENDF/B-VI Summary Documentation is to provide documentation of Releases 1, 2, 3, and 4 for the ENDF/B-VI and ENDF/HE-VI evaluated nuclear data libraries. These releases contain many new and revised evaluations for the neutron, photo-atomic interaction, radioactive decay data, spontaneous fission product yield, neutron-induced fission product yield, thermal neutron scattering, proton, deuteron, and triton sublibraries. The summaries have been extracted mainly from the ENDF/B-VI File 1 comments (MT = 451), which have been checked, edited, and may also include supplementary information. Some summaries have been provided by the evaluators in electronic format, while others are extracted from reports on the evaluations. All references have been checked and corrected, or updated where appropriate. A list of the laboratories which have contributed evaluations used in ENDF/B-VI is given

  7. ENDF-201, ENDF/B-VI summary documentation supplement 1, ENDF/HE-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    McLane, V.

    1996-12-01

    The National Nuclear Data Center (NNDC) provides coordination for and serves as the secretariat to the Cross Section Evaluation Working Group (CSWEG). CSEWG is responsible for the oversight of the ENDF/B Evaluated Nuclear Data File. All data are checked and reviewed by CSEWG, and the file is maintained at the NNDC. For a description of the ENDF/B-VI file, see the ENDF-102 Data Formats and Procedures for the Evaluated Nuclear Data File ENDF-6. The purpose of this addendum to the ENDF/B-VI Summary Documentation is to provide documentation of Releases 1, 2, 3, and 4 for the ENDF/B-VI and ENDF/HE-VI evaluated nuclear data libraries. These releases contain many new and revised evaluations for the neutron, photo-atomic interaction, radioactive decay data, spontaneous fission product yield, neutron-induced fission product yield, thermal neutron scattering, proton, deuteron, and triton sublibraries. The summaries have been extracted mainly from the ENDF/B-VI File 1 comments (MT = 451), which have been checked, edited, and may also include supplementary information. Some summaries have been provided by the evaluators in electronic format, while others are extracted from reports on the evaluations. All references have been checked and corrected, or updated where appropriate. A list of the laboratories which have contributed evaluations used in ENDF/B-VI is given.

  8. Enzymatic reduction of U(VI) in groundwaters; Reduction enzymatique de U(VI) dans des eaux souterraines

    Energy Technology Data Exchange (ETDEWEB)

    Addelouas, A.; Gong, W. [Center for Radioactive Waste Management, Advanced Materials Laboratory, 1001 University, Albuquerque (United States); Lutze, W.; Nuttall, E. [New Mexico Univ., Albuquerque, NM (United States). Dept. of Chemical and Nuclear Engineering; Fritz, B.; Crovisier, J.L. [Centre National de la Recherche Scientifique (CNRS), 67 - Strasbourg (France). Centre de Sedimentologie et Geochimie de la Surface

    1999-03-01

    The use of enzymatic reduction of U(VI) in remediation of groundwater contaminated with U(VI) is receiving considerable attention. Certain strains of bacteria can combine the oxidation of an organic compound to the reduction of U(VI) to U(IV), which precipitates as uraninite. In the present study, we tested the reduction of U(VI) in groundwaters with various origins and compositions. In all groundwaters u(VI) was reduced by sulfate reducing bacteria that had been activated by ethanol and tri-metaphosphate. The reduction rate of U(VI) depends on sulfate concentration in water and the abundance of bacteria in the system. This work shows that bacteria capable of U(VI) reduction are ubiquitous in nature, and suggests the possibility of a large application of the enzymatic reduction of U(VI) for in situ clean up of groundwaters contaminated with uranium. (authors) 12 refs.

  9. MASYARAKAT MADURA DAN RENCANA PEMBANGUNAN PLTN; PERSPEKTIF TEOLOGI

    Directory of Open Access Journals (Sweden)

    Abd. A'la

    2012-05-01

    Full Text Available Abd A’la   (Staf pengajar pada program Pascasarjana IAIN Sunan Ampel dan Asiten Direktur Bidang Akademik pada lembaga yang sama       Abstrak : Setiap pemanfaatan energi selalu memiliki resiko environmental. Resiko dalam dunia ilmu dapat ditolelir jika hal itu telah terkalkulasikan sehingga merupakan caculable risk. Sementara untuk energi nuklir, sampai saat ini, belum dapat dilakukan terutama terkait dengan teknologi pengamannya sehingga Fitjof Capra menyebutnya sebagai rasionalitas yang tidak bertanggung jawab. Masyarakat Madura merupakan komunitas Sunny dan dalam merespon setiap perkembangan selalu berjangkar pada prinsip-prinsip Sunny yang dicirikan dengan kehati-hatian dan moderasi. Terkait dengan rencana PLTN madura, masalah data tentang kebutuhan hal itu harus segera diperoleh untuk menjawab perlu tidaknya PLTN di Madura. Kekhwatiran bahwa kebutuan itu hanya merupakan rekayasa perusahaan reaktor nuklir patut di pertimbangkan karena memang sangat beralasan Kata Kunci : masyarakat madura, nuklir, PLTN

  10. Demand-side management project for Tenaga Nasional Berhad: Energy efficiency study: Institut Teknologi Mara (ITM) complex. Final report. Export trade information

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    1995-03-01

    This study, conducted by the California Energy Commission, was funded by the U.S. Trade and Development Agency. The report focuses on energy efficiency and conservation measures at the Institut Teknologi Mara (ITM) Complex for Tenaga Nasional Berhad in Malaysia. The study is divided into the following sections: Preface; (1.0) Executive Summary; (2.0) Facility Background and Site Information; (3.0) Site Energy Use; (4.0) Energy Using Systems; (5.0) On-Site Electricity and Energy Generation; (6.0) Technical Project Summary; Figures, Tables, Appendices.

  11. Hvad skal vi med Trump-satire?

    DEFF Research Database (Denmark)

    Møller, Mette

    2017-01-01

    Trump-satire er et stort hit, og særligt en lang række satiriske videohilsner til Trump fra lande verden over får folk til at trække på smilebåndet. Men hvorfor er det så sjovt at gøre grin med Trump, og hvad kan vi bruge den politiske humor til?......Trump-satire er et stort hit, og særligt en lang række satiriske videohilsner til Trump fra lande verden over får folk til at trække på smilebåndet. Men hvorfor er det så sjovt at gøre grin med Trump, og hvad kan vi bruge den politiske humor til?...

  12. The status of ENDF/B-VI

    International Nuclear Information System (INIS)

    Roussin, R.; Dunford, C.; McKnight, R.; Young, P.

    1988-01-01

    A new version of the United States evaluated nuclear data file, ENDF/B-VI, is presently under development. Major emphasis is being placed on correcting some long-standing nuclear data problems that adversely affect applied calculations for both fission and fusion reactors. The paper reviews modifications to the formats and utility codes, outlines the evaluation activities, discusses the data testing programs, and projects a date for the unrestricted release of the new library. 27 refs., 2 tabs

  13. Prospek pengembangan industri perkulitan pada pelita VI

    Directory of Open Access Journals (Sweden)

    D Karyadi

    1995-06-01

    Full Text Available The leather industry is one of the strong competitive industry, as it comes from renewable natural resources. Therefore, the leather industry has good prospect to develop at the Pelita VI to be the industrial products export competitive. To develop leather industry and leather products should be given closed attention and well managed, especially concerning raw material supply, quality and leather waste treatment.

  14. Vi behøver innovation

    DEFF Research Database (Denmark)

    McAloone, Tim C.

    2007-01-01

    -Produktion og Maskiner. Innovation og bæredygtighed er to områder som vi i Skandinavien giver meget stor opmærksomhed for at kunne vedligeholde vores globale konkurrencekraft og stærke velfærdssamfund. Gennem årene har mange brancher bidraget til skabelsen af vidensbaserede innovationer, og det faktum, at de......Analyse: Vi behøver innovation En ny miljøbølge ruller, og danske virksomheder bør ride med Af Tim McAloone, fredag 02. feb 2007 kl. 04:50 Tim McAloone Lektor og ph.d. ved Institut for mekanik, energi og konstruktion ved DTU. Tim McAloone skriver fremover jævnligt kommentarer i Ingeniøren...... skandinaviske lande er relativt små, har ledt til en interessant evne til at etablere og derefter samarbejde inden for tætte netværk, som strækker sig over både faglige og geografiske grænser. Samtidig har vi set miljøhensyn vinde og tabe samfundsmæssig og industriel opmærksomhed på en nærmest periodisk basis...

  15. PENGEMBANGAN PROTOTIPE EGG BOILER SEBAGAI MEDIA PEMBELAJARAN PRAKARYA DAN KEWIRAUSAHAAN UNTUK MATERI TEKNOLOGI TEPAT GUNA KELAS XI MIA SMA NEGERI 4 SINGARAJA TAHUN AJARAN 2016/2017

    Directory of Open Access Journals (Sweden)

    Indra Kusuma Harta

    2017-07-01

    Full Text Available Penelitian ini bertujuan untuk mengembangkan Prototipe Egg Boiler (Pengkukus Telur Otomatis sebagai media pembelajaran untuk mata pelajaran Prakarya dan Kewirausahaan pada materi Teknologi Tepat Guna di Kelas XI MIA SMA Negeri 4 Singaraja. Penelitian ini dilakukan dengan menggunakan metode Penelitian dan Pengembangan dalam bidang pendidikan. Hasil uji validasi ahli media memperoleh skor sebesar 0,75 dalam kategori tinggi. Uji validasi isi dengan nilai sebesar 0,81 dalam kategori sangat tinggi.  Sedangkan hasil uji coba perorangan dengan nilai sebesar 0.93, uji coba kelompok kecil dengan nilai sebesar 0.71, dan uji coba lapangan dengan nilai sebesar 0.82. Pada uji coba lapangan juga dilakukan dengan menganalisis nilai dari kegiatan praktikum, nilai yang diperoleh 87.4 dikategorikan dengan hasil belajar tinggi. Dari hasil nilai pre-test dan post-test tersebut secara keseluruhan mengalami peningkatan. Sehingga Pototipe Egg Boiler yang telah dikembangkan sangat membantu siswa dalam memahami materi dan praktikum mata pelajaran Prakarya dan Kewirausahaan untuk materi Teknologi Tepat Guna di Kelas XI MIA SMA Negeri 4 Singaraja.

  16. Hvordan kan teknologi skape nye undervisnings- og læringsmåter i fremmedspråksundervisningen fram mot 2030?

    Directory of Open Access Journals (Sweden)

    Eli-Marie Danbolt Drange

    2014-09-01

    Full Text Available I denne artikkelen drøfter jeg hvordan teknologi kan skape nye undervisnings- og læringsmåter i fremmedspråksundervisningen fram mot 2030. Jeg starter med å skissere et mulig framtidsscenario i form av et blogginnlegg skrevet av en 15 åring i året 2030. Videre i artikkelen tar jeg utgangspunkt i dette framtidsscenarioet og sammenligner det med dagens situasjon, i tillegg til at jeg drøfter hva som må til for at scenarioet kan oppfylles. Læreren spiller en nøkkelrolle i utviklingen av nye undervisnings- og læringsmåter, og det er først når læreren integrerer teknologien i sin undervisning at nye praksiser oppstår. Jeg viser noen konkrete eksempler på bruk av teknologi på nye måter, samt refleksjon rundt utviklingen framover.

  17. STUDI KASUS PEMANFAATAN E-LEARNING SEBAGAI SALAH SATU SARANA YANG MENDUKUNG PEMBELAJARAN DI FAKULTAS TEKNOLOGI INFORMASI DAN KOMUNIKASI UNIVERSITAS SEMARANG

    Directory of Open Access Journals (Sweden)

    Maya Rini Handayani

    2011-01-01

    Full Text Available Seiring dengan perkembangan Teknologi Informasi (TI yang semakin pesat, kebutuhan akan suatu konsep dan mekanisme belajar mengajar (pendidikan berbasis TI menjadi tidak terelakkan lagi. Konsep yang kemudian terkenal dengan sebutan e-Learning ini membawa pengaruh terjadinya proses transformasi pendidikan konvensional ke dalam bentuk digital, baik secara isi (contents dan sistemnya. Sistem e-Learning mutlak diperlukan untuk mengantisipasi perkembangan jaman dengan dukungan Teknologi Informasi dimana semua menuju ke era digital, baik mekanisme maupun konten. Pengembangan sistem e-Learning harus didahului dengan melakukan analisa terhadap kebutuhan dari pengguna (user needs. Sesuai dengan paradigma rekayasa sistem dan perangkat lunak, kebutuhan dari pengguna ini memiliki kedudukan tertinggi, dan merupakan dasar kreasi dan kerja pengembang. Agar penelitian ini dapat memberikan hasil yang baik, maka penulisan laporannya menggunakan berbagai macam data, keterangan data, serta informasi penting yang diperoleh dari berbagai sumber, didasarkan pada (1 data primer, yaitu data yang diperoleh secara langsung dari obyek penelitian ( dosen dan mahasiswa , (2 data sekunder, yaitu data yang diperoleh dari buku-buku, literatur sebagai pelengkap dalam penyusunan laporan penelitian ini. Metode Studi Pustaka, yaitu metode pengumpulan data melalui pemahaman literatur maupun buku dan juga browsing internet sebagai acuan untuk menentukan landasan teori. Metode angket / kuesioner, yaitu pengumpulan data dengan membagikan kuesioner kepada para dosen dan mahasiswa di lingkungan FTIK USM

  18. Tingkat Kematangan Infrastruktur Teknologi Informasi pada Domain Acquire and Implement Menggunakan COBIT 4.1 (Studi Kasus: UPT Perpustakaan Universitas Pembangunan Nasional “VETERAN” Jawa Timur

    Directory of Open Access Journals (Sweden)

    Ronggo Alit

    2017-07-01

    Full Text Available Berdasarkan hasil wawancara UPT Perpustakaan kekurangan perangkat komputer dan masih menggunakan server milik UPT Telematika serta kecepatan akses wifi akan lambat jika banyak yang menggunakan sehingga perlu dilakukan penelitian ini yang bertujuan untuk mengetahui tingkat kematangan dan menghasilkan rekomendasi guna meningkatkan pengelolaan infrastruktur teknologi informasi. Penelitian dilakukan menggunakan COBIT Framework 4.1 tahap penelitian diawali dengan analisa data wawancara kemudian diidentifikasi IT goals, IT process, serta Control Objectives. Perhitungan maturity level untuk mengetahui gap antara kondisi sekarang dengan kondisi yang diharapkan dan rekomendasi digunakan untuk mengatasi gap tersebut. Dari hasil penelitian yang dilakukan diperoleh 4 IT Goals, 10 IT Processes dan 17 detailed control objectives. Karena pemilihan subdomain disesuaikan dengan masalah dan kebutuhan maka subdomain yang digunakan adalah PO3, PO7, AI3 dan AI5. Ditemukan gap sebesar 1.5 dan maturity level sebesar 2.5 sehingga berada pada level 3 artinya perpustakaan telah memiliki mekanisme dan prosedur yang jelas mengenai tata cara dan manajemen teknologi informasi.

  19. UJI COBA TEKNOLOGI BIOFILM KONSORSIUM BAKTERI PADA REAKTOR SEMIANAEROB-AEROB UNTUK PENGOLAHAN AIR LIMBAH DI INDUSTRI PENCELUPAN TEKSTIL SKALA RUMAH TANGGA

    Directory of Open Access Journals (Sweden)

    Dewa Ketut Sastrawidana

    2013-04-01

    Full Text Available Penelitian ini bertujuan untuk menganalisis efektifitas teknologi biofilm konsorsium bakteri pada  reaktor semianaerob-aerob ntuk mengolah air limbah pencelupan tekstil. Bakteri pada reaktor semianaerob terdiri dari  Aeromonas sp. Pseudomonas sp, dan Flavobacterium sp. sedangkan pada reaktor aerob terdiri dari Vibrio sp. Plesiomonas sp. dan Enterobacter sp. Perombakan proses pertumbuhan terlekat diawali dengan menumbuhkan konsorsium bakteri pada masing-masing reaktor selama 10  hari menggunakan pada batu vulkanik merah sebagai media pelekatan bakteri. Setelah terbentuk biofilm,selanjutnya digunakan untuk merombak limbah denagn waktu tinggal limbah 2 hari. Hasil penelitian menunjukkan teknologi biofilm cukup efektif diaplikasikan pada skala lapang menghasilkan efisiensi perombakan TSS, BOD dan COD secara berturut-turut sebesar 84,7%; 80,56% dan 90,40%. Uji toksisitas air limbah tekstil menggunakan ikan nila dengan waktu paparan 3 hari menunjukkan bahwa air limbah tekstil sebelum diolah berkatagori toksik ringan dengan nilai EC50 adalah 88,80% sedangkan setelah diolah dalam reaktor biofilm konsorsium bakteri sistem anaerob-aerob selama 2 hari menjadi katagori tidak toksik dengan nilai EC50 sebesar 101,64%. Dengan demikian, pengolahan limbah tektil dengan sistem kombinasi anaerob-aerob menghasilkan kualitas limbah dengan kriteria sudah memenuhi baku mutu untuk dibuang ke lingkungan.

  20. SISTEM PENDUKUNG KEPUTUSAN TEKNOLOGI PENANGANAN DAN KELAYAKAN INVESTASI PASCAPANEN KAKAO (Theobroma cacao L. (STUDI KASUS DI KABUPATEN PIDIE JAYA, PROPINSI ACEH

    Directory of Open Access Journals (Sweden)

    Raida Agustina

    2013-06-01

    Full Text Available Cocoa beans produced by smallholders have low quality because of gaps in information on post-harvest tecnology. Information is needed to provide decision-support making for choosing one alternative implementation of the handling technology cocoa most appropriate and in accordance with the conditions of its territory which can improve the quality of dried cocoa beans. The purpose of this study was developed an  decision-support system software as a tool for decision making cocoa post-harvest handling, obtain the best alternative based on technical analysis and economic analysis, evaluate the feasibility of investment, and know the value of the sensitivity of each alternative. This study was carried out from July to December 2010 in Bandar Baru sub district, Pidie Jaya district of Aceh province. Survey and interview were used to collecting data. Collected data used to create a database for a decision-support system model of cocoa post-harvest handling technology, which was processed using  the Java programming language. Based on the analysis post harvest technology of cocoa to farmers and investors indicated a mechanical alternative is the best alternative because it produces the greatest benefits. Mechanical alternative  gives farmers a profit of Rp.1,419,279,165 per year and gives investors a profit of Rp. 1,023,246,397 per year and feasibility analysis shows NPV Rp 923,577,155 and the value of R/C ratio of 3 is also available in mechanical alternative. The results of sensitivity analysis on each alternative show that the most influential variables on the profitability of farmers and investors is wage labor, the price of fresh cacao fruit, and the price of dry beans. Keywords: Decision-support system, information, cocoa, post harvest technology   ABSTRAK Biji kakao yang dihasilkan perkebunan rakyat memiliki mutu yang rendah karena adanya kesenjangan dalam informasi mengenai teknologi penanganan pascapanen. Informasi dibutuhkan untuk memberi

  1. INTERVENSI KOGNITIF DAN PENDEKATAN RANTAI NILAI DALAM PENINGKATAN PEMANFAATAN TEKNOLOGI INFORMASI DAN KOMUNIKASI DI USAHA KECIL DAN MENENGAH DI BANDUNG

    Directory of Open Access Journals (Sweden)

    Ari Widyanti

    2016-06-01

    Full Text Available Pemanfaatan teknologi informasi dan komunikasi (TIK di usaha kecil dan menengah (UKM di Indonesia masih pada tingkat yang belum sesuai harapan. Mempertimbangkan bahwa UKM di Indonesia banyak menyerap tenaga kerja dan menyumbang pendapatan nasional yang cukup besar, serta melihat bahwa pemanfaatan TIK di banyak industri besar telah membawa peningkatan performansi yang cukup signifikan,  peningkatan pemanfaatan TIK di UKM merupakan hal yang penting untuk dilakukan. Penelitian ini dilakukan dengan tujuan untuk memetakan tingkat pemanfaatan TIK di UKM dan mengaplikasikan intervensi kognitif dan pendekatan rantai nilai dalam meningkatkan pemanfaatan TIK di UKM. Pemetaan pemanfaatan TIK dilakukan melalui survey dengan menggunakan kuesioner terstruktur dan wawancara yang melibatkan 61 UKM di berbagai bidang di Bandung. Hasil pemetaan pemanfaatan TIK di UKM menunjukkan bahwa pemanfaatan TIK di UKM sebatas pada tujuan pemasaran produk dan sebatas pada penggunaan website. Kendala utama pemanfaatan TIK di UKM adalah faktor SDM terutama berkaitan dengan keterbatasan pengetahuan dan informasi. Berdasarkan hasil pemetaan, selanjutnya, intervensi dilakukan melalui edukasi/kampanye dengan materi mengenai rantai nilai pada 30 UKM yang bergerak di bidang fashion. Hasil intervensi menunjukkan bahwa level pengetahuan dan intensi/kemauan untuk menerapkan TIK di UKM selain untuk kepentingan pemasaran (misalnya untuk perancangan produk dan hubungan dengan pemasok semakin meningkat. Implikasi dari hasil penelitian ini dibahas lebih lanjut.       Abstract The use of information and communication technology (ICT in small and medium enterprise (SME in Indonesia is at low level. Considering that SME in Indonesia employ a lot of people and contribute to Gross Domestic Product (GDP as well as improve performance of industries,  coupled with low level of ICT use in Indonesian SME, ICT’ used in SME must be increased. Therefore, this study aims to map the use of ICT in

  2. Voltammetry of Os(VI)-modified polysaccharides

    Czech Academy of Sciences Publication Activity Database

    Trefulka, Mojmír; Paleček, Emil

    2010-01-01

    Roč. 22, č. 16 (2010), s. 1837-1845 ISSN 1040-0397 R&D Projects: GA AV ČR(CZ) GPP301/10/P548; GA MŠk(CZ) LC06035 Grant - others:GA AV ČR(CZ) KAN400310651 Program:KA Institutional research plan: CEZ:AV0Z50040507; CEZ:AV0Z50040702 Keywords : chemical modification of polysaccharides * electroactive labels * osmium(VI) complexes Subject RIV: BO - Biophysics Impact factor: 2.721, year: 2010

  3. Environmental survey of Region VI, Haltenbanken, 2009; Miljoeundersoekelse i Region VI, Haltenbanken, 2009

    Energy Technology Data Exchange (ETDEWEB)

    Holm, May-Helen; Cochrane, Sabine; Mannvik, Hans-Petter; Wasbotten, Ingar Halvorsen

    2010-07-01

    There has been an environmental investigation in Region VI Halten Bank. This report presents the results of the chemical and biological assays performed on samples from a total of 316 stations in 16 fields and 15 regional stations. A status of environmental conditions in the region is given at the end of the report. (AG)

  4. Environmental Survey in Region VI, Haltenbanken, 2009. Summary report; Miljoeundersoekelse i Region VI, Haltenbanken, 2009. Sammendragsrapport

    Energy Technology Data Exchange (ETDEWEB)

    Mannvik, Hans-Petter; Wasbotten, Ingar Halvorsen

    2010-07-01

    An environmental survey of Region VI, Haltenbanken, has been carried out. This report presents the results from the analyses carried out on samples from a total of 316 stations at 16 fields and 15 regional stations. A status of the environmental conditions in the region is given at the end of the report. (Author)

  5. Fremtidens lavenergibyggeri - kan vi gøre som vi plejer?

    DEFF Research Database (Denmark)

    Larsen, Tine Steen

    2011-01-01

    Stramninger af kravene til energiforbruget i vores boliger medfører stor fokus på energiberegningen, men erfaringer fra lavenergiboliger opført i dag viser, at vi, for at sikre succes for fremtidens boliger, også skal inddrage dokumentation af indeklimaet og forbedre samarbejdet mellem arkitekter...

  6. Synthesis, characterization and oxidative behaviour of dioxoruthenium(VI) complexes

    International Nuclear Information System (INIS)

    Agarwal, D.D.; Rastogi, Rachana

    1995-01-01

    Dioxoruthenium(VI) complexes are found to give low yield of epoxide but good yield of cyclohexanone. The complexes are electro active giving metal centered Ru VI /Ru V couple. Cis-stilbene gives trans epoxide and benzaldehyde. Norbornene gives exo epoxy norbornene. The selectivity for allylic oxidation is high. In the present note the synthesis of dioxoruthenium(VI) complexes and their oxidation behaviour is reported. The dioxoruthenium(VI) complexes have been stoichiometrically found to be good oxidants. (author). 21 refs., 1 tab

  7. Enzymatic U(VI) reduction by Desulfosporosinus species

    International Nuclear Information System (INIS)

    Suzuki, Y.; Kelly, S.D.; Kemner, K.M.; Banfield, J.F.

    2004-01-01

    Here we tested U(VI) reduction by a Desulfosporosinus species (sp.) isolate and type strain (DSM 765) in cell suspensions (pH 7) containing 1 mM U(VI) and lactate, under an atmosphere containing N 2 -CO 2 -H 2 (90: 5: 5). Although neither Desulfosporosinus species (spp.) reduced U(VI) in cell suspensions with 0.25% Na-bicarbonate or 0.85% NaCl, U(VI) was reduced in these solutions by a control strain, desulfovibrio desulfuricans (ATCC 642). However, both Desulfosporosinus strains reduced U(VI) in cell suspensions depleted in bicarbonate and NaCl. No U(VI) reduction was observed without lactate and H 2 electron donors or with heat-killed cells, indicating enzymatic U(VI) reduction. Uranium(VI) reduction by both strains was inhibited when 1 mM CuCl 2 was added to the cell suspensions. Because the Desulfosporosinus DSM 765 does not contain cytochrome c 3 used by Desulfovibrio spp. to reduce U(VI), Desulfosporosinus species reduce uranium via a different enzymatic pathway. (orig.)

  8. Diagnostic and treatment strategies in mucopolysaccharidosis VI

    Directory of Open Access Journals (Sweden)

    Vairo F

    2015-10-01

    Full Text Available Filippo Vairo,1–3 Andressa Federhen,1,3,4 Guilherme Baldo,1,2,5–7 Mariluce Riegel,1,6 Maira Burin,1 Sandra Leistner-Segal,1,8 Roberto Giugliani1,5,6,81Medical Genetics Service, Hospital de Clínicas de Porto Alegre, Porto Alegre, Brazil; 2Department of Genetics, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil; 3Clinical Research Group on Medical Genetics, Hospital de Clínicas de Porto Alegre, Porto Alegre, Brazil; 4Post-Graduate Program in Child and Adolescent Health, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil; 5Gene Therapy Center, Hospital de Clínicas de Porto Alegre, Porto Alegre, Brazil; 6Post-Graduate Program in Genetics and Molecular Biology, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil; 7Department of Physiology, Universidade Federal do Rio Grande do Sul, Porto Alegre, Brazil; 8Post-Graduate Program in Medical Sciences, Universidade Federal do Rio Grande do Sul, Porto Alegre, BrazilAbstract: Mucopolysaccharidosis VI (MPS VI is a very rare autosomal recessive disorder caused by mutations in the ARSB gene, which lead to deficient activity of the lysosomal enzyme ASB. This enzyme is important for the breakdown of the glycosaminoglycans (GAGs dermatan sulfate and chondroitin sulfate, which accumulate in body tissues and organs of MPS VI patients. The storage of GAGs (especially dermatan sulfate causes bone dysplasia, joint restriction, organomegaly, heart disease, and corneal clouding, among several other problems, and reduced life span. Despite the fact that most cases are severe, there is a spectrum of severity and some cases are so attenuated that diagnosis is made late in life. Although the analysis of urinary GAGs and/or the measurement of enzyme activity in dried blood spots are useful screening methods, the diagnosis is based in the demonstration of the enzyme deficiency in leucocytes or fibroblasts, and/or in the identification of pathogenic mutations in the ARSB gene

  9. Effect of uranium (VI) on the growth of yeast and influence of metabolism of yeast on adsorption of U (VI)

    International Nuclear Information System (INIS)

    Sakamoto, Fuminori; Ohnuki, Toshihiko; Kozai, Naofumi; Wakai, Eiichi; Francis, A.J.

    2005-01-01

    We have carried out the growth experiments of 3 strains of yeast in a medium containing uranium (VI) to elucidate the effect of U (VI) on the growth of microorganisms. Hansenula fabianii J640 grew in the liquid medium containing 0.1 mM U (VI) at lower rate than the control, but Saccharomyces cerevisiae did not grow under this condition. The H. fabianii J640 pre-cultured for 21 h in the liquid medium without U (VI) grew even after the exposure to 1 mM U (VI), but did not grow without pre-cultivation. For the pre-cultured H. fabianii J640, radioactivity of U in the medium was the same as the initial one for 110 h, and then gradually decreased. TEM-EDS analysis of H. fabianii J640 exposed to 1 mM U (VI) for 165 h showed accumulation of U (VI) on the cells. When H. fabianii J640 was not pre-cultured, radioactivity of U in the medium was lower than the initial one. These results indicated that U (VI) inhibits the growth of yeast, and that the adsorption of U (VI) by the cells depends on the metabolism of yeast. (author)

  10. VI School on Cosmic Rays and Astrophysics

    International Nuclear Information System (INIS)

    2017-01-01

    VI School on Cosmic Rays and Astrophysics 17-25 November 2015, Chiapas, Mexico The VI School on Cosmic Rays and Astrophysics was held at the MCTP, at the Autonomous University of Chiapas (UNACH), Tuxtla Gutiérrez, Chiapas, Mexico thanks to the Science for Development ICTP-UNACH-UNESCO Regional Seminar, 17-25 November 2015 (http://mctp.mx/e-VI-School-on-Cosmic-Rays-and-Astrophysics.html). The School series started in La Paz, Bolivia in 2004 and it has been, since then, hosted by several Latin American countires: 1.- La Paz, Bolivia (August, 2004), 2.- Puebla, Mexico (September, 2006), 3.- Arequipa, Peru (September, 2008), 4.- Santo André, Brazil (September, 2010), 5.- La Paz, Bolivia (August, 2012). It aims to promote Cosmic Ray (CR) Physics and Astrophysics in the Latin American community and to provide a general overview of theoretical and experimental issues on these topics. It is directed to undergraduates, postgraduates and active researchers in the field. The lectures introduce fundamental Cosmic Ray Physics and Astrophysics with a review of standards of the field. It is expected the school continues happening during the next years following a tradition. In this edition, the list of seminars included topics such as experimental techniques of CR detection, development of CR showers and hadronic interactions, composition and energy spectrum of primary CR, Gamma-Ray Bursts (GRBs), neutrino Astrophysics, spacecraft detectors, simulations, solar modulation, and the current state of development and results of several astroparticle physics experiments such as The Pierre Auger Observatory in Argentina, HAWC in Mexico, KASCADE and KASCADE Grande, HESS, IceCube, JEM-EUSO, Fermi-LAT, and others. This time the school has been complemented with the ICTP-UNACH-UNESCO Seminar of theory on Particle and Astroparticle Physics. The organization was done by MCTP, the Mesoamerican Centre for Theoretical Physics. The school had 46 participants, 30 students from Honduras, Brazil

  11. Predicting chromium (VI) adsorption rate in the treatment of liquid ...

    African Journals Online (AJOL)

    Administrator

    The adsorption rate of chromium (VI) on commercial activated carbon during the ... time and initial chromium (VI) ion concentration. .... model, the separation factor r, according to Calvo et al (2001) cited .... Lead (II) and nickel (II) adsorption kinetics .... heavy metal by Talaromyces helicus: a trained fungus for copper and.

  12. Procedure for plutonium determination using Pu(VI) spectra

    International Nuclear Information System (INIS)

    Walker, L.F.; Temer, D.J.; Jackson, D.D.

    1996-01-01

    This document describes a simple spectrophotometric method for determining total plutonium in nitric acid solutions based on the spectrum of Pu(VI). Plutonium samples in nitric acid are oxidized to Pu(VI) with Ce(IV) and the net absorbance at the 830 nm peak is measured

  13. Predicting chromium (VI) adsorption rate in the treatment of liquid ...

    African Journals Online (AJOL)

    The adsorption rate of chromium (VI) on commercial activated carbon during the treatment of the flocculation effluent of liquid-phase oil-based drill-cuttings has been investigated in terms of contact time and initial chromium (VI) ion concentration. Homogenizing 1 g of the activated carbon with 100 ml of the flocculation ...

  14. A CMOS rail-to-rail linear VI-converter

    NARCIS (Netherlands)

    Vervoort, P.P.; Vervoort, P.P.; Wassenaar, R.F.

    1995-01-01

    A linear CMOS VI-converter operating in strong inversion with a common-mode input range from the negative to the positive supply rail is presented. The circuit consists of three linear VI-converters based on the difference of squares principle. Two of these perform the actual V to I conversion,

  15. Cloning and expression of a Vi mimotope of Salmonella enterica ...

    African Journals Online (AJOL)

    STORAGESEVER

    2009-09-15

    Sep 15, 2009 ... A recombinant His-Vi protein of Salmonella enterica serovar Typhi was successfully constructed and cloned into ... mainly through consumption of food or water contami- nated with .... and healthy individuals (double arrows) followed by the detection using recombinant His-Vi protein as the primary antibody ...

  16. Research progress in the electrochemical synthesis of ferrate(VI)

    International Nuclear Information System (INIS)

    Macova, Zuzana; Bouzek, Karel; Hives, Jan; Sharma, Virender K.; Terryn, Raymond J.; Baum, J. Clayton

    2009-01-01

    There is renewed interest in the +6 oxidation state of iron, ferrate (VI) (Fe VI O 4 2- ), because of its potential as a benign oxidant for organic synthesis, as a chemical in developing cleaner ('greener') technology for remediation processes, and as an alternative for environment-friendly battery cathodes. This interest has led many researchers to focus their attention on the synthesis of ferrate(VI). Of the three synthesis methods, electrochemical, wet chemical and thermal, electrochemical synthesis has received the most attention due to its ease and the high purity of the product. Moreover, electrochemical processes use an electron as a so-called clean chemical, thus avoiding the use of any harmful chemicals to oxidize iron to the +6 oxidation state. This paper reviews the development of electrochemical methods to synthesize ferrate(VI). The approaches chosen by different laboratories to overcome some of the difficulties associated with the electrochemical synthesis of ferrate(VI) are summarized. Special attention is paid to parameters such as temperature, anolyte, and anode material composition. Spectroscopic work to understand the mechanism of ferrate(VI) synthesis is included. Recent advances in two new approaches, the use of an inert electrode and molten hydroxide salts, in the synthesis of ferrate(VI) are also reviewed. Progress made in the commercialization of ferrate(VI) continuous production is briefly discussed as well

  17. KENO-VI Primer: A Primer for Criticality Calculations with SCALE/KENO-VI Using GeeWiz

    International Nuclear Information System (INIS)

    Bowman, Stephen M.

    2008-01-01

    The SCALE (Standardized Computer Analyses for Licensing Evaluation) computer software system developed at Oak Ridge National Laboratory is widely used and accepted around the world for criticality safety analyses. The well-known KENO-VI three-dimensional Monte Carlo criticality computer code is one of the primary criticality safety analysis tools in SCALE. The KENO-VI primer is designed to help a new user understand and use the SCALE/KENO-VI Monte Carlo code for nuclear criticality safety analyses. It assumes that the user has a college education in a technical field. There is no assumption of familiarity with Monte Carlo codes in general or with SCALE/KENO-VI in particular. The primer is designed to teach by example, with each example illustrating two or three features of SCALE/KENO-VI that are useful in criticality analyses. The primer is based on SCALE 6, which includes the Graphically Enhanced Editing Wizard (GeeWiz) Windows user interface. Each example uses GeeWiz to provide the framework for preparing input data and viewing output results. Starting with a Quickstart section, the primer gives an overview of the basic requirements for SCALE/KENO-VI input and allows the user to quickly run a simple criticality problem with SCALE/KENO-VI. The sections that follow Quickstart include a list of basic objectives at the beginning that identifies the goal of the section and the individual SCALE/KENO-VI features that are covered in detail in the sample problems in that section. Upon completion of the primer, a new user should be comfortable using GeeWiz to set up criticality problems in SCALE/KENO-VI. The primer provides a starting point for the criticality safety analyst who uses SCALE/KENO-VI. Complete descriptions are provided in the SCALE/KENO-VI manual. Although the primer is self-contained, it is intended as a companion volume to the SCALE/KENO-VI documentation. (The SCALE manual is provided on the SCALE installation DVD.) The primer provides specific examples of

  18. Bleaching Dengan Teknologi Laser

    OpenAIRE

    Eliwaty

    2008-01-01

    Penulisan tentang bleaching dengan laser dimaksudkan untuk menambah wawasan serta pengetahuan dari pembaca di bidang kedokteran gigi. Macam-macam laser yang dipergunakan dalam bleaching yaitu argon, CO2 serta dioda laser. Contoh merek produk laser yaitu Blulaze, Dentcure untuk argonlaser, Novapulse untuk C02 serta Opus 5 untuk dioda laser. Laser bleaching hasilnya dapat dicapai dalam satu kunjungan saja, cepat, efisien namun biayanya relatif mahal, dapat menimbulkan burn, sensitivitas se...

  19. Introduktion. Om rotavirus. Teknologi

    DEFF Research Database (Denmark)

    Wejse, Christian

    2012-01-01

    vil skyldes rotavirus. Typisk vil børnene få feber, opkastninger og/eller diarré. Sygdommen går sædvanligvis over af sig selv i løbet af 3 til 7 dage. Nogle børn får dog væske- og saltmangel i en sådan grad, at de må indlægges på hospital til behandling med drop og væske direkte ind i årerne. 85 – 90...... % af danske børn følger det danske børnevaccinationsprogram og bliver vaccineret mod en række infektioner. Der findes i Danmark to velafprøvede og godkendte vacciner mod rotavirus. Begge vacciner gives gennem munden og ikke gennem indsprøjtning i huden, som de øvrige vacciner i det danske...... børnevaccinationsprogram. Verdenssundhedsorganisation (WHO=World Health Organisation) samt nationale og europæiske faglige selskaber har anbefalet at vaccinere mod rotavirus. I en række europæiske lande er vaccination mod rotavirus indført i det nationale børnevaccinationsprogram. Andre europæiske lande har fravalgt...

  20. Analisis Redaman Pada Jaringan FTTH (Fiber To The Home Dengan Teknologi GPON (Gigabit Passive Optical Network Di PT MNC Kabel Mediacom

    Directory of Open Access Journals (Sweden)

    Minal Abral

    2017-06-01

    Full Text Available iber optic merupakan teknologi yang menyediakan kapasitas bandwith besar dengan kecepatan tinggi, tidak dipengaruhi interferensi gelombang elektromagnetik, Sejalan dengan berkembang secara pesatnya penggunaan serat optik sebagai medium penghantar, ada kemungkinan terjadinya hilang informasi akibat kerugian dari pemanjangan kabel fiber optic ataupun penyambungan kabel fiber optic, kerugian tersebut yaitu redaman. Dalam penerapan metode link power budget, perhitungan redaman dilakukan dengan data yang diperoleh berdasarkan standarisasi dan pengukuran menggunakan perangkat optical power meter. Hasil analisa perhitungan, sistem mampu dalam keadaan normal menggunakan layanan gigabit passive optical network dapat diterima oleh perangkat akhir jaringan fiber to the home pada pelanggan perusahaan PT MNC Kabel Mediacom yang berada di Kelurahan Jati RW 02 Pulo Gadung Jakarta Timur.

  1. Testing of ENDF/B-VI data for shielding applications

    International Nuclear Information System (INIS)

    Ingersoll, D.T.

    1995-01-01

    Version VI of the U.S. Evaluated Nuclear Data File (END/B-VI) was released for open distribution in 1990 after an extensive multiyear, multilaboratory evaluation effort coordinated by the Cross Section Evaluation Working Group (CSEWG). More than 75 of the 320 evaluations contained in the library are new for Version VI, including many relatively important nuclides and many with substantial changes to the cross-section data. Also, several important changes were made to the basic data formats for Version VI to permit better representation of the data and to allow additional types of data. Although these format changes yielded improved evaluations, they hindered processing of the data for use in applications codes and delayed the timely integral testing of the data. It has been only during the past year that significant integral testing of END/B-VI data has been achieved. The results and conclusions from some of these efforts are summarized in the following paragraphs

  2. Factors affecting the adsorption of chromium (VI) on activated carbon

    Energy Technology Data Exchange (ETDEWEB)

    Yavuz, R.; Orbak, I.; Karatepe, N. [Istanbul Technical University, Istanbul (Turkey)

    2006-09-15

    The aim of this investigation was to determine the adsorption behavior of chromium (VI) on two different activated carbon samples produced from Tuncbilek lignite. The effects of the initial chromium (VI) concentration (250-1000 mg/L), temperature (297-323 K) and pH (2.0-9.5) on adsorption were investigated systematically. The effectiveness of the parameters on chromium adsorption was found to be in the order of pH, the initial Cr(VI) concentration and the temperature. Increasing the pH from 2.0 to 9.5 caused a decrease in adsorption. However, the adsorption was increased by increasing the initial Cr(VI) concentration and temperature. The multilinear mathematical model was also developed to predict the Cr(VI) adsorption on activated carbon samples within the experimental conditions.

  3. Spectrophotometry of Comet West 1976 VI

    International Nuclear Information System (INIS)

    Rozenbush, V.K.

    1986-01-01

    Spectra obtained for the coma, nuclear fragments A and D, and tail of Comet West 1976 VI on April 1, 2 and 7, 1976 are noted to encompass coma spectra which differed from those of the nuclear fragments, which exhibited a strong continuum with superimposed emissions that included a stronger CO(+)-band system than that of the coma. A detailed comparison between fragment spectra has revealed great differences in both quasi-simultaneously obtained and five-day-separated cases. The relative intensities of different CO(+) bands are compared to the theoretical ones, and the abundances of CO(+) ions corresponding to different vibrational transitions are determined relative to that of CN. 24 references

  4. Cranial nerves III, IV and VI

    International Nuclear Information System (INIS)

    Laine, I.J.; Smoker, W.R.; Kuta, A.J.; Felton, W.L.

    1991-01-01

    Because of advances in CT and MR imaging, accurate identification and evaluation of cranial nerve lesions is now possible. Cranial nerves III, IV, and VI, providing motor and sensory control of the eye, can be evaluated as a unit. In this paper, the authors present an overview of the anatomy and pathology of these cranial nerves. We first illustrate their normal anatomic pathways from the brain stem to the orbit. This is followed by clinical examples of patients with a variety of isolated and complex palsies of these three cranial nerves. This is accomplished by inclusion of ocular photographs, correlative imaging studies, and the use of diagrams. Knowledge of the gross and imaging anatomy and the ophthalmologic manifestations of pathology affecting these three cranial nerves permits a tailored approach to their evaluation

  5. New energy level identifications in Kr VI

    International Nuclear Information System (INIS)

    Tauheed, A.; Pinnington, E.H.; Ansbacher, W.; Kernahan, J.A.

    1990-01-01

    Beam-foil delayed spectra from 89.0 to 101.0 nm are used to identify the intercombination lines connecting the 4s4p 2 4 P and 4s 2 4p 2 P levels in Kr VI. The existing analysis is extended to include the 4s 2 5s 2 S 1/2 , 4f 2 F 5/2 , 2 F 7/2 , 4p 3 2 D 3/2 , 2 D 5/2 , 2 P 3/2 , 4 S 3/2 and 4s4p 2 4 P 1/2 , 4 P 3/2 , 4 P 5/2 levels. Lifetime measurements for the 4s4p 2 4 P 1/2 , 4 P 5/2 , 4p 3 2 D 3/2 and 2 D 5/2 levels are also discussed in support of these assignments. (orig.)

  6. Spectrum and energy levels of Y VI

    International Nuclear Information System (INIS)

    Persson, W.; Reader, J.

    1986-01-01

    The spectrum of the five-times-ionized yttrium atom (Y VI), excited in a sliding-spark discharge, was studied in the 160--2500 A-circle range. About 900 Y VI lines were classified as transitions between 101 odd and 69 even energy levels.The energy-level system established includes almost all levels of the 4s 2 4p 4 , 4s4p 5 , 4s 2 4p 3 4d, 5d, 5s, 6s, and 5p configurations and a number of levels of the 7s, 4f, and 4s4p 4 4d configurations. The observed level system has been theoretically interpreted by means of Hartree--Fock calculations and least-squares parametric fits. Strong configuration mixings are found between the 4s4p 5 and 4s 2 4p 3 4d configurations, between the 4s 2 4p 3 5p and 4s4p 4 4d configurations, and between the 4s 2 4p 3 4f and 4s4p 4 4d configurations. From the optimized energy-level values, a system of Ritz-type wavelength standards with accuracies varying from 0.0003 to 0.003 A-circle in the range 179--500 A-circle has been determined. The ionization energy as determined from 4s 2 4p 3 ns levels (n = 5-7) is 737 110 +- 200 cm/sup -1/ (91.390 +- 0.025 eV)

  7. Investigation of uranium (VI) adsorption by polypyrrole

    Energy Technology Data Exchange (ETDEWEB)

    Abdi, S. [Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan 35195-363 (Iran, Islamic Republic of); Nasiri, M., E-mail: mnasiri@semnan.ac.ir [Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan 35195-363 (Iran, Islamic Republic of); Mesbahi, A. [Faculty of Chemical, Petroleum and Gas Engineering, Semnan University, Semnan 35195-363 (Iran, Islamic Republic of); Khani, M.H. [Nuclear Fuel Cycle Research School, Nuclear Science and Technology Research Institute, Tehran, 14395-836 (Iran, Islamic Republic of)

    2017-06-15

    Highlights: • The adsorbent (polypyrrole) was synthesized by a chemical method using PEG, DBSNa and CTAB as the surfactant. • The solution pH was one of the most important parameters affecting the adsorption of uranium. • The CTAB provided higher removal percentage compared with the other surfactants. • The maximum adsorption capacity obtained from Langmuir isotherm was 87.72 mg/g. • The pseudo second-order model fitted well with the adsorption kinetic of polypyrrole to uranium. - Abstract: The purpose of this study was to investigate the adsorption of uranium (VI) ions on the polypyrrole adsorbent. Polypyrrole was synthesized by a chemical method using polyethylene glycol, sodium dodecylbenzenesulfonate, and cetyltrimethylammonium bromide as the surfactant and iron (III) chloride as an oxidant in the aqueous solution. The effect of various surfactants on the synthesized polymers and their performance as the uranium adsorbent were investigated. Adsorbent properties were characterized by scanning electron microscopy (SEM) and Fourier transform infrared spectroscopy (FTIR) techniques. The effect of different parameters such as pH, contact time, initial metal ion concentrations, adsorbent dose, and the temperature was investigated in the batch system for uranium adsorption process. It has been illustrated that the adsorption equilibrium time is 7 min. The results showed that the Freundlich model had the best agreement and the maximum adsorption capacity of polypyrrole for uranium (VI) was determined 87.72 mg/g from Langmuir isotherm. In addition, the mentioned adsorption process was fast and the kinetic data were fitted to the Pseudo first and second order models. The adsorption kinetic data followed the pseudo-second-order kinetic model. Moreover, the thermodynamic parameters ΔG{sup 0}, ΔH{sup 0} and ΔS{sup 0} showed that the uranium adsorption process by polypyrrole was endothermic and spontaneous.

  8. Kinetic investigations of quinoline oxidation by ferrate(VI).

    Science.gov (United States)

    Luo, Zhiyong; Li, Xueming; Zhai, Jun

    2016-01-01

    Quinoline is considered as one of the most toxic and carcinogenic compounds and is commonly found in industrial wastewaters, which require treatment before being discharged. Removal of quinoline by the use of an environmentally friendly oxidant, potassium ferrate(VI) (K2FeO4), was assessed by studying the kinetics of the oxidation of quinoline by ferrate(VI) (Fe(VI)) as a function of pH (8.53-10.53) and temperature (21-36°C) in this work. The reaction of quinoline with Fe(VI) was found to be first order in Fe(VI), half order in quinoline, and 1.5 order overall. The observed rate constant at 28°C decreased non-linearly from 0.5334 to 0.2365 M(-0.5) min(-1) with an increase in pH from 8.53 to 10.03. Considering the equilibria of Fe(VI) and quinoline, the reaction between quinoline and Fe(VI) contained two parallel reactions under the given pH conditions. The individual rate constants of these two reactions were determined. The results indicate that the protonated species of Fe(VI) reacts more quickly with quinoline than the deprotonated form of Fe(VI). The reaction activation energy Ea was obtained to be 51.44 kJ·mol(-1), and it was slightly lower than that of conventional chemical reaction. It reveals that the oxidation of quinoline by Fe(VI) is feasible in the routine water treatment.

  9. Technology-derived storage solutions for stabilizing insulin in extreme weather conditions I: the ViViCap-1 device.

    Science.gov (United States)

    Pfützner, Andreas; Pesach, Gidi; Nagar, Ron

    2017-06-01

    Injectable life-saving drugs should not be exposed to temperatures 30°C/86°F. Frequently, weather conditions exceed these temperature thresholds in many countries. Insulin is to be kept at 4-8°C/~ 39-47°F until use and once opened, is supposed to be stable for up to 31 days at room temperature (exception: 42 days for insulin levemir). Extremely hot or cold external temperature can lead to insulin degradation in a very short time with loss of its glucose-lowering efficacy. Combined chemical and engineering solutions for heat protection are employed in ViViCap-1 for disposable insulin pens. The device works based on vacuum insulation and heat consumption by phase-change material. Laboratory studies with exposure of ViViCap-1 to hot outside conditions were performed to evaluate the device performance. ViViCap-1 keeps insulin at an internal temperature phase-change process and 'recharges' the device for further use. ViViCap-1 performed within its specifications. The small and convenient device maintains the efficacy and safety of using insulin even when carried under hot weather conditions.

  10. U(VI) sorption on kaolinite. Effects of pH, U(VI) concentration and oxyanions

    International Nuclear Information System (INIS)

    Liang Gao; Ziqian Yang; Keliang Shi; Xuefeng Wang; Zhijun Guo; Wangsuo Wu

    2010-01-01

    U(VI) sorption on kaolinite was studied as functions of contact time, pH, U(VI) concentration, solid-to-liquid ratio (m/V) by using a batch experimental method. The effects of sulfate and phosphate on U(VI) sorption were also investigated. It was found that the sorption kinetics of U(VI) can be described by a pseudo-second-order model. Potentiometric titrations at variable ionic strengths indicated that the titration curves of kaolinite were not sensitive to ionic strength, and that the pH of the zero net proton charge (pH PZNPC ) was at 6.9. The sorption of U(VI) on kaolinite increased with pH up to 6.5 and reached a plateau at pH >6.5. The presence of phosphate strongly increased U(VI) sorption especially at pH <5.5, which may be due to formation of ternary surface complexes involving phosphate. In contrast, the presence of sulfate did not cause any apparent effect on U(VI) sorption. A double layer model was used to interpret both results of potentiometric titrations and U(VI) sorption on kaolinite. (author)

  11. The reduction of Np(VI) and Pu(VI) by organic chelating agents

    International Nuclear Information System (INIS)

    Reed, D.T.; Aase, S.B.; Banaszak, J.E.

    1998-01-01

    The reduction of NpO 2+ and PuO 2 2+ by oxalate. citrate, and ethylenediaminetetraacetic acid (EDTA) was investigated in low ionic strength media and brines. This was done to help establish the stability of the An(VI) oxidation state in the presence of organic complexants. The stability of the An(VI) oxidation state depended on the pH and relative strength of the various oxidation state-specific complexes. At low ionic strength and pH 6, NpO 2 O 2+ was rapidly reduced to form NpO 2 + organic complexes. At longer times, Np(IV) organic complexes were observed in the presence of citrate. PuO 2 2+ was predominantly reduced to Pu 4+ , resulting in the formation of organic complexes or polymeric/hydrolytic precipitates. The relative rates of reduction to the An(V) complex were EDTA > citrate > oxalate. Subsequent reduction to An(IV) complexes, however, occurred in the following order: citrate > EDTA > oxalate because of the stability of the An(V)-EDTA complex. The presence of organic complexants led to the rapid reduction of NpO 2 2+ and PuO 2 P 2+ in G-seep brine at pHs 5 and 7. At pHs 8 and 10 in ERDA-6 brine, carbonate and hydrolytic complexes predominated and slowed down or prevented the reduction of An(VI) by the organics present

  12. Behaviour of chromium(VI) in stormwater soil infiltration systems

    DEFF Research Database (Denmark)

    Cederkvist, Karin; Ingvertsen, Simon T.; Jensen, Marina B.

    2013-01-01

    mm in 2 h) and extreme (100 mm in 3 h) rain events. The objectives were to understand the behaviour of the anionic and toxic Cr(VI) in soil at neutral pH and to asses treatment efficiency towards Cr(VI). During normal rain events Cr(VI) was largely retained (more than 50, even though pH was neutral......The ability of stormwater infiltration systems to retain Cr(VI) was tested by applying a synthetic stormwater runoff solution with a neutral pH and high Cr(VI) concentrations to four intact soil columns excavated from two roadside infiltration swales in Germany. Inlet flow rates mimicked normal (10......, while under extreme rain events approximately 20% of Cr(VI) was retained. In both cases effluent concentrations of Cr(VI) would exceed the threshold value of 3.4 mu g/L if the infiltrated water were introduced to freshwater environments. More knowledge on the composition of the stormwater runoff...

  13. Electrochemical alkaline Fe(VI) water purification and remediation.

    Science.gov (United States)

    Licht, Stuart; Yu, Xingwen

    2005-10-15

    Fe(VI) is an unusual and strongly oxidizing form of iron, which provides a potentially less hazardous water-purifying agent than chlorine. A novel on-line electrochemical Fe(VI) water purification methodology is introduced. Fe(VI) addition had been a barrier to its effective use in water remediation, because solid Fe(VI) salts require complex (costly) syntheses steps and solutions of Fe(VI) decompose. Online electrochemical Fe(VI) water purification avoids these limitations, in which Fe(VI) is directly prepared in solution from an iron anode as the FeO42- ion, and is added to the contaminant stream. Added FeO42- decomposes, by oxidizing a wide range of water contaminants including sulfides (demonstrated in this study) and other sulfur-containing compounds, cyanides (demonstrated in this study), arsenic (demonstrated in this study), ammonia and other nitrogen-containing compounds (previously demonstrated), a wide range of organics (phenol demonstrated in this study), algae, and viruses (each previously demonstrated).

  14. Social Set Visualizer (SoSeVi) II

    DEFF Research Database (Denmark)

    Flesch, Benjamin; Vatrapu, Ravi

    2016-01-01

    This paper reports the second iteration of the Social Set Visualizer (SoSeVi), a set theoretical visual analytics dashboard of big social data. In order to further demonstrate its usefulness in large-scale visual analytics tasks of individual and collective behavior of actors in social networks......, the current iteration of the Social Set Visualizer (SoSeVi) in version II builds on recent advancements in visualizing set intersections. The development of the SoSeVi dashboard involved cutting-edge open source visual analytics libraries (D3.js) and creation of new visualizations such as of actor mobility...

  15. Wavelengths and energy levels of I V and I VI

    International Nuclear Information System (INIS)

    Kaufman, V.; Sugar, J.; Joshi, Y.N.

    1988-01-01

    The spectra of iodine were photographed in the 139--1500-Aat;O region on various spectrographs. Earlier analyses of I V and I VI were revised and extended. For I V 26 lines were classified, and for I VI 35 lines were classified. Ionization energies have been estimated to be 415 510 atm≅ 300 cm -1 (51.52 atm≅ 0.04 eV) and 599 800 atm≅ 3 000 cm -1 (74.37 atm≅ 0.37 eV) for I V and I VI, respectively

  16. Cinética e equilíbrio de adsorção dos oxiânions Cr (VI, Mo (VI e Se (VI pelo sal de amônio quaternário de quitosana Kinetics and equilibrium of adsorption of oxyanions Cr (VI, Mo (VI and Se (VI by quaternary ammonium chitosan salt

    Directory of Open Access Journals (Sweden)

    Viviane A. Spinelli

    2005-07-01

    Full Text Available O sal quaternário de quitosana foi sintetizado com cloreto de glicidil trimetil amônio. A modificação química foi caracterizada por espectrometria no IV, RMN de 13C e ¹H, e mmol/g de grupos quaternários presentes na matriz polimérica por condutimetria. A remoção de Cr (VI, Mo (VI e Se (VI, em meio aquoso, foi investigada em processo de batelada. A adsorção mostrou ser dependente do pH para o Cr (VI e Se (VI, com um pH ótimo de adsorção, entre 4,0 a 6,0. Para o Mo (VI a adsorção manteve-se quase constante no intervalo de pH entre 4,0 e 11,5. O modelo de isoterma de Langmuir descreveu melhor os dados de equilíbrio na faixa de concentração investigada. No presente estudo, um grama do sal quaternário de quitosana reticulado com glutaraldeído adsorveu 68,3 mg de Cr, 63,4 mg de Mo e 90,0 mg de Se. A velocidade de adsorção, no processo, segue a equação cinética de pseudo segunda-ordem, sendo que o equilíbrio para os três íons foi alcançado próximo aos 200 minutos. A análise dispersiva de raios-X para o Cr (VI mostrou que o principal mecanismo de adsorção é a troca iônica entre os íons Cl- da superfície do polímero pelos oxiânions. O trocador aniônico apresentou a seguinte ordem de seletividade: Cr (VI > Mo (VI > Se (VI.Quaternary chitosan salt was synthesized in the presence of glycidyl trimetyl ammonium chloride. The polymer was characterized by spectroscopic techniques: infrared, 13C and ¹H NMR, while the amount of quaternary ammonium groups was obtained by condutimetry. The removal of Cr (VI, Mo (VI and Se (VI from aqueous solutions was carried out in batch adsorption processes. The process seemed to be pH dependent for Cr (VI and Se (VI with an optimum pH ranging from 4.0 to 6.0; while for Mo (VI the adsorption remained almost constant within the range between 4.0 and 11.5. The Langmuir isotherm model provided the best fit of the equilibrium data over the whole concentration investigated. In the experiment

  17. Wind tunnel test of musi VI bridge

    Science.gov (United States)

    Permata, Robby; Andika, Matza Gusto; Syariefatunnisa, Risdhiawan, Eri; Hermawan, Budi; Noordiana, Indra

    2017-11-01

    Musi VI Bridge is planned to cross the Musi River in Palembang City, South Sumatera Province, Indonesia. The main span is a steel arch type with 200 m length and side span length is 75 m. Finite element analysis results showed that the bridge has frequency ratio for torsional and heaving mode (torsional frequency/heaving frequency)=1.14. This close to unity value rises concern about aerodynamic behaviour and stability of the bridge deck under wind loading. Sectional static and free vibration wind tunnel test were performed to clarify this phenomena in B2TA3 facility in Serpong, Indonesia. The test followed the draft of Guide of Wind Tunnel Test for Bridges developed by Indonesian Ministry of Public Works. Results from wind tunnel testing show that the bridge is safe from flutter instability and no coupled motion vibration observed. Therefore, low value of frequency ratio has no effect to aerodynamic behaviour of the bridge deck. Vortex-induced vibration in heaving mode occurred in relatively low wind velocity with permissible maximum amplitude value.

  18. Separation of Rhenium (VII) from Tungsten (VI)

    International Nuclear Information System (INIS)

    Vucina, J.; Lukic, D.; Stoiljkovic, M.; Milosevic, M.; Orlic, M.

    2004-01-01

    Examined were the conditions for an effective separation of tungsten (VI) and rhenium (VII) on alumina if the solution of 0.20 mol dm -3 NaCl, ph=2.6 is used as the aqueous phase. Under the given experimental conditions alumina was found to be much better adsorbent for tungsten than for rhenium. The breakthrough and saturation capacities of alumina at pH=2 are 24 and 78 mg W/g Al 2 O 3 , respectively. With the increase of pH these values decrease. So, at pH=6 they are only 4 and 13 mg W/g Al 2 O 3 respectively. The elution volume for rhenium for the given column dimensions and quantity of the adsorbent is about 16 ml. These results were confirmed by the experiments of the radiological separations. Tungsten-187 remains firmly bound to the alumina. The radionuclide purity of the eluted 186'188 Re at pH=2 is very high. (authors)

  19. VIM: Initial ENDF/B-VI experience

    International Nuclear Information System (INIS)

    Blomquist, R.N.

    1997-01-01

    The VIM Monte Carlo particle transport code uses detailed continuous-energy cross sections produced from ENDF/B data by a set of specialized codes developed or adapted for use at Argonne National Laboratory. ENDF/B-IV data were used until about 1979, and Version V data since then. These VIM libraries were extensively benchmarked against the MC 2 -2 code and against ZPR and ZPPR criticals for fast spectrum calculations, as well as other fast and thermal experiments and calculations. Recently, the cross section processing codes have been upgraded to accommodate ENDF/B-VI files, and a small library has been tested. Several fundamental tasks comprise the construction of a faithful representation of ENDF data for VIM calculations: (1) The resolved resonance parameters are converted to Doppler-broadened continuous-energy cross sections with energy grids suitable for linear-linear interpolation. (2) The unresolved resonance parameter distributions are sampled to produce many (40-400) resonance ladders in each energy band. These are converted to Doppler-broadened continuous energy resonance cross sections that are then binned by cross section, accumulating ladders until statistical convergence, the result being probability tables of total cross sections and conditional mean scattering and fission cross sections. VIM samples these tables at run time, and File 3 back ground cross sections are added. (3) Anisotropic angular distribution data are converted to angular probability tables. All other ENDF data are unmodified, except for format

  20. Mechanism of uranium (VI) removal by two anaerobic bacterial communities

    Energy Technology Data Exchange (ETDEWEB)

    Martins, Monica [Centro de Ciencias do Mar, Universidade do Algarve, FCT-DQF (edificio 8), Campus de Gambelas, 8005-139 Faro (Portugal); Faleiro, Maria Leonor [IBB - Centro de Biomedicina Molecular e Estrutural, Universidade do Algarve, FCT, Campus de Gambelas, 8005-139 Faro (Portugal); Costa, Ana M. Rosa da [Centro de Investigacao em Quimica do Algarve, Universidade do Algarve, FCT, DQF, Campus de Gambelas, 8005-139 Faro (Portugal); Chaves, Sandra; Tenreiro, Rogerio [Universidade de Lisboa, Faculdade de Ciencias, Centro de Biodiversidade, Genomica Integrativa e Funcional (BioFIG), Campus de FCUL, Campo Grande, 1749-016 Lisboa (Portugal); Matos, Antonio Pedro [Servico de Anatomia Patologica, Hospital Curry Cabral, Lisboa (Portugal); Costa, Maria Clara, E-mail: mcorada@ualg.pt [Centro de Ciencias do Mar, Universidade do Algarve, FCT-DQF (edificio 8), Campus de Gambelas, 8005-139 Faro (Portugal)

    2010-12-15

    The mechanism of uranium (VI) removal by two anaerobic bacterial consortia, recovered from an uncontaminated site (consortium A) and other from an uranium mine (consortium U), was investigated. The highest efficiency of U (VI) removal by both consortia (97%) occurred at room temperature and at pH 7.2. Furthermore, it was found that U (VI) removal by consortium A occurred by enzymatic reduction and bioaccumulation, while the enzymatic process was the only mechanism involved in metal removal by consortium U. FTIR analysis suggested that after U (VI) reduction, U (IV) could be bound to carboxyl, phosphate and amide groups of bacterial cells. Phylogenetic analysis of 16S rRNA showed that community A was mainly composed by bacteria closely related to Sporotalea genus and Rhodocyclaceae family, while community U was mainly composed by bacteria related to Clostridium genus and Rhodocyclaceae family.

  1. Extraction behavior of uranium(VI) with polyurethane foam

    International Nuclear Information System (INIS)

    Tingchia Huang; Donghwang Chen; Muchang Shieh; Chingtsven Huang

    1992-01-01

    The extraction of uranium(VI) from aqueous solution with polyether-based polyurethane (PU) foam was studied. The effects of the kinds and concentrations of nitrate salts, uranium(VI) concentration, temperature, nitric acid concentration, pH, the content of poly(ethylene oxide) in the polyurethane foam, and the ratio of PU foam weight and solution volume on the extraction of uranium(VI) were investigated. The interferences of fluoride and carbonate ions on the extraction of uranium(VI) were also examined, and methods to overcome both interferences were suggested. It was found that no uranium was extracted in the absence of a nitrate salting-out agent, and the extraction behaviors of uranium(IV) with polyurethane foam could be explained in terms of an etherlike solvent extraction mechanism. In addition, the percentage extraction of a multiple stage was also estimated theoretically

  2. BEHA VI OUR OF TOPI IN A SHADELESS ENVIRONMENT ...

    African Journals Online (AJOL)

    BEHA VI OUR OF TOPI IN A SHADELESS ENVIRONMENT ... one population for signs of behavioural adaptiveness in the species' environmental relation- .... The major change is obviously in the proportion of topi which had their heads up, as.

  3. ALTERATION OF U(VI)-PHASES UNDER OXIDIZING CONDITIONS

    Energy Technology Data Exchange (ETDEWEB)

    A.P. Deditius; S. Utsunomiya; R.C. Ewing

    2006-02-21

    Uranium-(VI) phases are the primary alteration products of the UO{sub 2} in spent nuclear fuel and the UO{sub 2+x}, in natural uranium deposits. The U(VI)-phases generally form sheet structures of edge-sharing UO{sub 2}{sup 2+} polyhedra. The complexity of these structures offers numerous possibilities for coupled-substitutions of trace metals and radionuclides. The incorporation of radionuclides into U(VI)-structures provides a potential barrier to their release and transport in a geologic repository that experiences oxidizing conditions. In this study, we have used natural samples of UO{sub 2+x}, to study the U(VI)-phases that form during alteration and to determine the fate of the associated trace elements.

  4. ALTERATION OF U(VI)-PHASES UNDER OXIDIZING CONDITIONS

    International Nuclear Information System (INIS)

    A.P. Deditius; S. Utsunomiya; R.C. Ewing

    2006-01-01

    Uranium-(VI) phases are the primary alteration products of the UO 2 in spent nuclear fuel and the UO 2+x , in natural uranium deposits. The U(VI)-phases generally form sheet structures of edge-sharing UO 2 2+ polyhedra. The complexity of these structures offers numerous possibilities for coupled-substitutions of trace metals and radionuclides. The incorporation of radionuclides into U(VI)-structures provides a potential barrier to their release and transport in a geologic repository that experiences oxidizing conditions. In this study, we have used natural samples of UO 2+x , to study the U(VI)-phases that form during alteration and to determine the fate of the associated trace elements

  5. Mechanism of uranium (VI) removal by two anaerobic bacterial communities

    International Nuclear Information System (INIS)

    Martins, Monica; Faleiro, Maria Leonor; Costa, Ana M. Rosa da; Chaves, Sandra; Tenreiro, Rogerio; Matos, Antonio Pedro; Costa, Maria Clara

    2010-01-01

    The mechanism of uranium (VI) removal by two anaerobic bacterial consortia, recovered from an uncontaminated site (consortium A) and other from an uranium mine (consortium U), was investigated. The highest efficiency of U (VI) removal by both consortia (97%) occurred at room temperature and at pH 7.2. Furthermore, it was found that U (VI) removal by consortium A occurred by enzymatic reduction and bioaccumulation, while the enzymatic process was the only mechanism involved in metal removal by consortium U. FTIR analysis suggested that after U (VI) reduction, U (IV) could be bound to carboxyl, phosphate and amide groups of bacterial cells. Phylogenetic analysis of 16S rRNA showed that community A was mainly composed by bacteria closely related to Sporotalea genus and Rhodocyclaceae family, while community U was mainly composed by bacteria related to Clostridium genus and Rhodocyclaceae family.

  6. Polarography of uranium(VI)-salicylic acid system

    International Nuclear Information System (INIS)

    Salah, El-Maraghy B.

    1980-01-01

    Uranium(VI)-salicylic acid system has been studied polarographically in perchloric acid medium. Varying concentrations of HClO 4 and salicylic acid have been used. The nature of the polarographic waves is irreversible. (author)

  7. Polarography of uranium(VI)-salicylic acid system

    Energy Technology Data Exchange (ETDEWEB)

    Salah, E M.B. [Ain Shams Univ., Cairo (Egypt). Faculty of Education

    1980-08-01

    Uranium(VI)-salicylic acid system has been studied polarographically in perchloric acid medium. Varying concentrations of HClO/sub 4/ and salicylic acid have been used. The nature of the polarographic waves is irreversible.

  8. Potentiometric studies on quaternary complexes of dioxouranium(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Kumari, Vinod; Chaturvedi, G K [Agra Coll., (India). Chemical Laboratories

    1979-10-01

    The formation of quaternary complexes of dioxouranium(VI) with three different organic acids (OX, MALN and SA, SSA, TAR or TMA) has been inferred from the potentiometric studies. The formation constants for the resulting triligand complexes have been evaluated.

  9. strong>Hvad skal vi med en hjerne?strong>

    DEFF Research Database (Denmark)

    Hermansen, Judy

    2009-01-01

    neurologen Antonio Damasio, at sikre vores overlevelse og velbefindende (i nævnte rækkefølge). Vi ved, at der findes såkaldte belønningsstrukturer i hjernen på både dyr og mennesker, som aktiverer følelser af velbehag, når vi gør "det rigtige", dvs. noget der er godt for os. Men hvordan de mere konkret...

  10. Extraction of uranium (VI) sulphate complexes by Adogen amines

    Energy Technology Data Exchange (ETDEWEB)

    Elyamani, I S; Abd Elmessieh, E N [Nuclear chemistry department, hot laboratories center, atomic energy authority, Cairo, (Egypt)

    1995-10-01

    The distribution of U(VI) between aqueous H{sub 2} So{sub 4} solutions and organic phases of adogen-368 has been described. The dependence of extraction on acidity, diluent type, metal and extractant concentrations was investigated. The possible extraction mechanism is discussed in the light of results obtained. The separation of U(VI) from rare earths is suggested. 5 figs., 1 tab.

  11. Electronic structure, fluorescence and photochemistry of the uranyl ion, and comparison with octahedral uranium (VI), ruthenyl (VI), rhenium (V) and osmium (VI) complexes

    Energy Technology Data Exchange (ETDEWEB)

    Joergensen, C K [Geneva Univ. (Switzerland)

    1977-01-01

    The highly anisotropic uranyl complexes (with very short U-O distances and very long distances to the ligating atoms in the equatorial plane) are compared with trans-dioxo complexes of 4d/sup 2/Ru(VI) and 5d/sup 2/Re(V) and Os(VI). A major difference is the low-lying empty 5f orbitals, and the first excited state is highly oxidizing, and sufficiently long-lived to abstract hydrogen atoms from most organic molecules. It is argued that even the low concentrations of uranyl carbonate present in sea water is excited by solar radiation roughly every 10 minutes. Octahedral U(VI)O/sub 6/ in perovskites and UF/sub 6/ are also discussed, as well as trans-lawrencium chemistry.

  12. Analisis Kinerja Sistem Informasi dan Teknologi Informasi untuk Menunjang Kinerja Karyawan Menggunakan Framework IT Balanced Scorecard (Studi Kasus pada Wi-Fi Universitas Kristen Satya Wacana

    Directory of Open Access Journals (Sweden)

    Bertho Molly

    2017-12-01

    Wi-Fi UKSW merupakan fasilitas jaringan internet yang dibangun untuk memfasilitasi dan mendukung kebutuhan civitas UKSW dalam proses belajar mengajar. Tujuan penelitian ini adalah melakukan pengukuran bagaimana tingkat pemanfaatan Sistem Informasi dan Teknologi Informasi berdasarkan kinerja karyawan Wi-Fi UKSW. Penelitian ini menggunakan metode IT Balanced Scorecard sebagai sarana pengukuran yang jelas, memantau dan mengoptimalkan realisasi dari nilai atau manfaat bisnis dan manfaat Teknologi Informasi dimana IT Balanced Scorecard mempunyai 4 perspektif (Perspektif Kontribusi Perusahaan, Perspektif Orientasi Pengguna, Perspektif Penyempurnaan Operasional, dan Perspektif Orientasi Masa Depan. Penelitian ini dimulai dari tahapan perencanaan, tahapan studi kelayakan awal dan studi literature, tahapan wawancara dan observasi, tahapan analisis data, serta tahapan membuat dan menyusun laporan serta rekomendasi menggunakan IT Balanced Scorecard. Adapun beberapa hal yang ditemukan dalam penelitian ini dan harus ditangani yaitu, dibutuhkannya penambahan Sumber Daya Manusia (SDM untuk membantu kinerja Wi-Fi UKSW baik dalam hal penanganan complain maupun penyelesaian proyek mengingat Wi-Fi UKSW selalu dibutuhkan dan digunakan oleh semua civitas UKSW serta perlu adanya evaluasi dan upgrade terhadap sistem aplikasi monitoring Wi-Fi. Karena sebagai sarana penyedia layanan jaringan internet yang mana semua yang dilakukan karyawan Wi-Fi UKSW berhubungan erat dengan Sistem Informasi dan Teknologi Informasi dan hasilnya, yang kehadirannya memberikan nilai manfaat yang baik khususnya bagi kemajuan kinerja karyawan Wi-Fi UKSW. Kata kunci: Kinerja SI dan TI, IT Balanced Scorecard, Wi-Fi UKSW Abstract Wi-Fi SWCU is an internet network facility built to facilitate and support the needs of SWCU civities in teaching and learning. The purpose of this research is take measurements of what is the level the use of Information Systems and Information Technology based on of employee performance

  13. Vi-da: vitiligo diagnostic assistance mobile application

    Science.gov (United States)

    Nugraha, G. A.; Nurhudatiana, A.; Bahana, R.

    2018-03-01

    Vitiligo is a skin disorder in which white patches of depigmentation appear on different parts of the body. Usually, patients come to hospitals or clinics to have their vitiligo conditions assessed. This can be very tiring to the patients, as vitiligo treatments usually take a relatively long period of time, which can range from months to years. To address this challenge, we present in this paper a prototype of an Android-based mobile application called Vi-DA, which stands for Vitiligo Diagnostic Assistance. Vi-DA consists of three subsystems, which are user sign-up subsystem, camera and image analysis subsystem, and progress report subsystem. The mobile application was developed in Java programming language and uses MySQL as the database system. Vi-DA adopts a vitiligo segmentation algorithm to segment input image into normal skin area, vitiligo skin area, and non-skin area. Results showed that Vi-DA gave comparable results to the previous system implemented in Matlab. User acceptance testing results also showed that all respondents agreed on the usefulness of the system and agreed to use Vi-DA again in the future. Vi-DA benefits both dermatologists and patients as not only a computer-aided diagnosis (CAD) tool but also as a smart application that can be used for self-assessment at home.

  14. Recovery of uranium (VI) from low level aqueous radioactive waste

    International Nuclear Information System (INIS)

    Kulshrestha, Mukul

    1996-01-01

    Investigation was undertaken to evaluate the uranium (VI) removal and recovery potential of a naturally occurring, nonviable macrofungus, Ganoderma Lucidum from the simulated low level aqueous nuclear waste. These low level waste waters discharged from nuclear mine tailings and nuclear power reactors have a typical U(VI) concentration of 10-100 mg/L. It is possible to recover this uranium economically with the advent of biosorption as a viable technology. Extensive laboratory studies have revealed Ganoderma Lucidum to be a potential biosorbent with a specific uptake of 2.75 mg/g at an equilibrium U(VI) concentration of 10 mg/L at pH 4.5. To recover the sorbed U(VI), the studies indicated 0.2N Na 2 CO 3 to be an effective elutant. The kinetics of U(VI) desorption from loaded Ganoderma Lucidum with 0.2N Na 2 CO 3 as elutant, was found to be rapid with more than 75% recovery occurring in the first five minutes, the specific metal release rate being 0.102 mg/g/min. The equilibrium data fitted to a linearised Freundlich plot and exhibited a near 100% recovery of sorbed U(VI), clearly revealing a cost-effective method of recovery of precious uranium from low level wastewater. (author). 7 refs., 3 figs., 1 tab

  15. Editorial das organizadoras do VI ENANCIB

    Directory of Open Access Journals (Sweden)

    Ligia Maria Arruda Café

    2006-07-01

    Full Text Available EDITORIAL A história das idéias, em um determinado campo do conhecimento, se faz por meio de seus cientistas e de suas instituições. Ela torna visível a produção intelectual deste campo, construída por seus atores individuais e coletivos. Neste sentido, o ENANCIB é um elemento-chave neste processo de construção, o momento por excelência da disseminação do conhecimento nesta área. Ele permite a continuidade da história, o desenvolvimento da Ciência da Informação que se faz no Brasil e a coesão de sua comunidade. Por meio de debates, da troca de idéias e de experiências, promovem a construção da identidade deste campo científico, sua visibilidade, a delimitação de suas fronteiras e sua interrelação com outras áreas do conhecimento. O ENANCIB permite, além disso, a construção de novas parcerias científicas e a consolidação dos grupos de trabalho existentes. Este evento vem se estabelecendo, desde 1994, como fundamental para a consolidação e estruturação da área da Ciência da Informação brasileira, influenciando o desenvolvimento dos cursos de pós-graduação do país. Um campo se constrói somente se compreender as especificidades dos processos que atravessam o seu caminho. Em sua evolução, a Ciência da Informação, nos últimos 50 anos, tem se caracterizado pela diversidade de suas abordagens buscando definir a sua essência, por diferentes estudos e teorias. Nestes estudos, inúmeros aportes conceituais vêm sendo apresentados por diferentes pensadores por meio da visão particular de cada um deles. Na realidade, cada um adota uma forma distinta de observar, representar e explicitar a realidade com base na sua visão de mundo. Alguns autores enfatizam os aspectos comunicacionais da Ciência da Informação; outros destacam sua função social; outros, ainda, ressaltam sua forte ligação com as tecnologias. Este número da revista Encontros Bibli traz quatorze artigos apresentados no VI ENANCIB

  16. Vi har intet lært - hvornår lærer vi det?

    DEFF Research Database (Denmark)

    Sodemann, Morten

    2016-01-01

    WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en kerneakti......WHO anså fra i går ikke længere ebola for at være en trussel mod global folkesundhed, så fra i dag er kameraerne slukket i Vestafrika og vi er tilbage hvor vi startede. SDG målene skal have et dansk udtryk, men hvad er de danske kompetencer på globalt plan når sundhed ikke længere er en...

  17. Magnetic chitosan for removal of uranium (VI)

    International Nuclear Information System (INIS)

    Stopa, Luiz Claudio Barbosa

    2007-01-01

    The chitosan, an aminopolysaccharide formed for repeated units of D-glucosamine, is a deacetylation product of chitin. It presents favorable ionic properties acting as chelant, being considered a removing ionic of contaminants from water effluents. It has ample bioactivity, that is, is biocompatible, biodegradable, bioadhesive and biosorbent. The chitosan interacts for crosslinked by means of its active groups with other substances, can still coat superparamagnetic materials as magnetite nanoparticles producing one conjugated polymer-magnetite. Superparamagnetic materials are susceptible for the magnetic field, thus these particles can be attracted and grouped by a magnetic field and as they do not hold back the magnetization, they can be disagrouped and reused in processes for removal of contaminants from industrial effluents and waste water. The present work consisted of preparing coated magnetic magnetite particles with chitosan (PMQ). The PMQ powder has showed a magnetic response of intense attraction in the presence of a magnetic field without however becoming magnetic, a typical behavior of superparamagnetic material. It was characterized by Fourier transform infrared spectrometry and measurements of magnetization. Its performance of Uranium (VI) adsorption as uranyl species, U0 2 2+ , was evaluated with regard to the influence of adsorbent dose, speed of agitation, pH, the contact time and had studied the isotherms of adsorption as well as the behavior of desorption using ions of carbonate and oxalate. The optimal pH to the best removal occurred in pH 5 and that the increase of the dose increases the removal, becoming constant above of 20 g.L -1 . In the kinetic study the equilibrium was achieved after 20 minutes. The results of equilibrium isotherm agreed well with the Langmuir model, being the maximum adsorption capacity equal 41.7 mg.g -1 . In the desorption studies were verified 94% of U0 2 2+ recovered with carbonate ion and 49.9% with oxalate ion

  18. Diverse anaerobic Cr(VI) tolerant bacteria from Cr(VI)-contaminated 100H site at Hanford

    Science.gov (United States)

    Chakraborty, R.; Phan, R.; Lam, S.; Leung, C.; Brodie, E. L.; Hazen, T. C.

    2007-12-01

    Hexavalent Chromium [Cr(VI)] is a widespread contaminant found in soil, sediment, and ground water. Cr(VI) is more soluble, toxic, carcinogenic, and mutagenic compared to its reduced form Cr(III). In order to stimulate microbially mediated reduction of Cr(VI), a poly-lactate compound HRC was injected into the chromium contaminated aquifers at site 100H at Hanford. Based on the results of the bacterial community composition using high-density DNA microarray analysis of 16S rRNA gene products, we recently investigated the diversity of the dominant anaerobic culturable microbial population present at this site and their role in Cr(VI) reduction. Positive enrichments set up at 30°C using specific defined anaerobic media resulted in the isolation of an iron reducing isolate strain HAF, a sulfate reducing isolate strain HBLS and a nitrate reducing isolate, strain HLN among several others. Preliminary 16S rDNA sequence analysis identifies strain HAF as Geobacter metallireducens, strain HLN as Pseudomonas stutzeri and strain HBLS as a member of Desulfovibrio species. Strain HAF isolated with acetate as the electron donor utilized propionate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Growth was optimal at 37°C, pH of 6.5 and 0% salinity. Strain HLN isolated with lactate as electron donor utilized acetate, glycerol and pyruvate as alternative carbon sources, and reduced metals like Mn(IV) and Cr(VI). Optimal growth was observed at 37°C, at a pH of 7.5 and 0.3% salinity. Anaerobic active washed cell suspension of strain HLN reduced almost 95 micromolar Cr(VI) within 4 hours relative to controls. Further, with 100 micromolar Cr(VI) as the sole electron acceptor, cells of strain HLN grew to cell numbers of 4.05X 107/ml over a period of 24hrs after an initial lag, demonstrating direct enzymatic Cr(VI) reduction by this species. 10mM lactate served as the sole electron donor. These results demonstrate that Cr(VI

  19. Synthesis, structure and properties of oxo- and dioxochloride complexes of molybdenum(VI) and tungsten(VI) with 8-oxyquinoline

    International Nuclear Information System (INIS)

    Abramenko, V.L.; Sergienko, V.S.; Egorova, O.A.

    2005-01-01

    Complexes of oxo- and dioxochlorides of molybdenum(VI) and tungsten(VI) with 8-oxyquinoline of molecular and intracomplex type are synthesized and studied by the method of IR spectroscopy. The complexes have octahedral structure. It is proposed that 8-oxyquinoline in molecular complexes is coordinated by central atom through nitrogen atom of heterocycle, but in intracomplex compounds - through heterocyclic nitrogen atom and oxygen atom of deprotonated OH-group. Thermal stability of the complexes is studied [ru

  20. Inhibition of bacterial U(VI) reduction by calcium

    International Nuclear Information System (INIS)

    Brooks, Scott C.; Fredrickson, Jim K.; Carroll, S. L.; Kennedy, David W.; Zachara, John M.; Plymale, Andrew E.; Kelly, S. D.; Kemner, K. M.; Fendorf, S.

    2003-01-01

    The rapid kinetics of bacterial U(VI) reduction and low solubility of uraninite (UO2,cr) make this process an attractive option for removing uranium from groundwater. Nevertheless, conditions that may promote or inhibit U(VI) reduction are not well-defined. Recent descriptions of Ca-UO2-CO3 complexes indicate that these species may dominate the aqueous speciation of U(VI) in many environments. We monitored the bacterial reduction of U(VI) in bicarbonate-buffered solution in the presence and absence of Ca. XAFS measurements confirmed the presence of a Ca-U(VI)-CO3 complex in the initial solutions containing calcium. Calcium, at millimolar concentrations (0.45-5 mM), caused a significant decrease in the rate and extent of bacterial U(VI) reduction. Both facultative (Shewanella putrefaciens strain CN32) and obligate (Desulfovibrio desulfuricans, Geobacter sulfurreducens) anaerobic bacteria were affected by the presence of calcium. Reduction of U(VI) ceased when the calculated system Eh re ached -0.046+/- 0.001 V, based on the Ca2UO2(CO3)(3) -- > UO2,cr couple. The results are consistent with the hypothesis that U is a less energetically favorable electron acceptor when the Ca-UO2-CO3 complexes are present. The results do not support Ca inhibition caused by direct interactions with the cells or with the electron donor as the reduction of fumarate or Tc(VII)O-4(-) under identical conditions was unaffected by the presence of Ca

  1. Establishment proper of the balanced scorecard indicators to support decision making in a university: a case study in Institut Teknologi Indonesia

    Science.gov (United States)

    Theresia, L.; Lahuddin, A. H.; Bangun, R.

    2017-12-01

    Balanced Scorecard (BSC) is a powerful tool in decision making process. Nevertheless, it is not rare that the BSC does not give satisfactory results because the indicators chosen do not reflect the needs of the organization. Therefore, indicator establishment is very crucial in the utilization of BSC. This research aims to determine the indicators BSC for a university and the research is a case study in Institut Teknologi Indonesia (ITI). In this study, BSC structure and indicators, comparison made by 4 previous researchers was used as the initial guide to determine the structure and indicators of ITI. And then, questionnaires were distributed to selected respondents and a focus group discussion (FGD) was conducted in order to produce indicators of BSC based on the mental model of the ITI. It is found 15 indicators based on the mental model of ITI. Furthermore, the relationships between the indicators are seen as dynamic relationships, and by using system dynamics, some feedback loops that are considered critical to organizational success can be identified and isolated.

  2. Penyuluhan Dan Pelatihan Teknologi Pemanfaatan Tanaman Obat Berbasis Kearifan Dan Sumber Daya Alam Lokal Untuk Perbaikan Tingkat Kesehatan Masyarakat Desa Karangsari Wedomartani Sleman

    Directory of Open Access Journals (Sweden)

    Sri Handayani

    2017-02-01

    Full Text Available Program Pengabdian kepada Masyarakat ini bertujuan untuk memberikan penyuluhan dan pelatihan teknologi pemanfaatan tanaman obat berbasis kearifan dan sumber daya alam lokal untuk perbaikan tingkat kesehatan masyarakat desa karangsari wedomartani Sleman. Pada akhirnya kegiatan ini akan memberikan wawasan, pengetahuan, kemampuan, dan keterampilan kepada warga terutama para remaja dan  ibu –ibu dalam memanfaatkan bahan alam di lingkungan sekitar sebagai minuman kesehatan. Kegiatan ini dilaksanakan pada tanggal 7 Agustus 2016 dengan peserta kegiatan adalah remaja dan ibu-ibu PKK desa Wedomartani Sleman. Kegiatan ini diawali dengan analisis permasalahan di lapangan, diikuti oleh persiapan rancangan  pelaksanaan program, pelatihan dan sosialisasi program yang dilengkapi alat dan bahan serta sarana dan prasarana penunjang kegiatan. Kegiatan diakhiri dengan sosialisasi serta pengarahan pembuatan minuman kesehatan berbasis sumber daya alam local. Hasil kegiatan ini menunjukkan bahwa 100% para peserta pelatihan merasakan bahwa kegiatan ini bermanfaat dan memiliki kemauan yang kuat untuk belajar hal baru. Dengan pelatihan yang berkelanjutan,diharapkan peserta memiliki pengetahuan dan keterampilan yang dapat digunakan untuk meningkatkan kualitas hidup bahkan menunjang kebutuhan ekonomi.   Kata kunci: Tanaman obat, sumber daya alam local

  3. Evaluasi Manajemen Keamanan Informasi Menggunakan Indeks Keamanan Informasi (KAMI Berdasarkan ISO/IEC 27001:2013 pada Direktorat Pengembangan Teknologi dan Sistem Informasi (DPTSI ITS Surabaya

    Directory of Open Access Journals (Sweden)

    Firzah Abdullah Basyarahil

    2017-03-01

    Full Text Available DPTSI merupakan sebuah direktorat untuk menangani permasalahan teknologi informasi dan sistem informasi yang dimiliki oleh ITS. Menurut UU. No. 12 Tahun 12 Ttg. Perguruan Tinggi, misi mencari, menemukan, dan menyebarluaskan kebenaran ilmiah tersebut dapat diwujudkan apabila perguruan tinggi di kelola berdasarkan suatu Tata kelola perguruan tinggi yang baik (Good University Governance. Pengelolaan Informasi merupakan salah satu aspek dalam Good University Governance, termasuk kualitas dan keamanan pengelolaan informasi. Salah satu upaya yang dapat dilakukan untuk meningkatkan kualitas dari keamanan informasi, kementrian Kominfo membuat alat bantu untuk mengukur tingkat kematangan dan kelengkapan dalam keamanan informasi yang disebut dengan Indeks Keamanan Informasi (KAMI. Penggunaan Indeks KAMI ini juga diikuti dengan penerapan ISO 27001 sebagai standar keamanan internasional yang dapat membantu sebuah organisasi memastikan bahwa keamanan informasi yang diterapkan sudah efektif. Hasil dari penggunaan Indeks KAMI versi 3.1 di DPTSI ITS ini adalah tingkat ketergantungan penggunaan sistem elektronik sebesar 26 dari total skor 50 dan masuk kedalam kategori Tinggi dimana sistem elektronik adalah bagian yang tidak terpisahkan dari proses kerja yang berjalan. Hasil penilaian kelima area yang telah dilakukan adalah sebesar 249 dari 645 dan berada pada kategori tidak layak. Dari hasil tersebut maka dibuat rekomendasi berdasarkan kontrol ISO 27002:2013 untuk pertanyaan-pertanyaan yang mendapat nilai kurang. Kemudian rekomendasi dari penelitian ini dapat dijadikan sebagai bahan pertimbangan dan evaluasi bagi pihak DPTSI ITS Surabaya dalam melakukan perbaikan yang berkaitan dengan mitigasi atau pencegahan kerentanan keamanan informasi, serta memastikan regulasi dapat dicapai dengan baik dan kebijakan keamanan institusi di masa yang akan datang.

  4. Role of U(VI) adsorption in U(VI) Reduction by Geobacter species

    International Nuclear Information System (INIS)

    Lovely, Derrick

    2008-01-01

    Previous work had suggested that Acholeplasma palmae has a higher capacity for uranium sorption than other bacteria studied. Sorption studies were performed with cells in suspension in various solutions containing uranium, and results were used to generate uranium-biosorption isotherms. Results from this study showed that the U(VI) sorption capacity of G. uraniireducens was relatively similar in simple solutions, such as sodium chloride or bicarbonate. However, this ability to sorb uranium significantly decreased in groundwater. This suggested that certain chemicals present in the groundwater were inhibiting the ability of cell components of Geobacter to adsorb uranium. It was hypothesized that uranium removal would also be diminished in the bicarbonate solution. However, this did not seem to be the case, as uranium was as easily removed in the bicarbonate solution as in the sodium chloride solution.

  5. Experiments indicating a second hydrogen ordered phase of ice VI.

    Science.gov (United States)

    Gasser, Tobias M; Thoeny, Alexander V; Plaga, Lucie J; Köster, Karsten W; Etter, Martin; Böhmer, Roland; Loerting, Thomas

    2018-05-14

    In the last twelve years five new ice phases were experimentally prepared. Two of them are empty clathrate hydrates and three of them represent hydrogen ordered counterparts of previously known disordered ice phases. Here, we report on hydrogen ordering in ice VI samples produced by cooling at pressures up to 2.00 GPa. Based on results from calorimetry, dielectric relaxation spectroscopy, Raman spectroscopy, and powder X-ray diffraction the existence of a second hydrogen ordered polymorph related to ice VI is suggested. Powder X-ray data show the oxygen network to be the one of ice VI. For the 1.80 GPa sample the activation energy from dielectric spectroscopy is 45 kJ mol -1 , which is much larger than for the known hydrogen ordered proxy of ice VI, ice XV. Raman spectroscopy indicates the 1.80 GPa sample to be more ordered than ice XV. It is further distinct from ice XV in that it experiences hydrogen disordering above ≈103 K which is 26 K below the ice XV to ice VI disordering transition. Consequently, below 103 K it is thermodynamically more stable than ice XV, adding a stability region to the phase diagram of water. For the time being we suggest to call this new phase ice β-XV and to relabel it ice XVIII once its crystal structure is known.

  6. Integrated Cr(VI) removal using constructed wetlands and composting.

    Science.gov (United States)

    Sultana, Mar-Yam; Chowdhury, Abu Khayer Md Muktadirul Bari; Michailides, Michail K; Akratos, Christos S; Tekerlekopoulou, Athanasia G; Vayenas, Dimitrios V

    2015-01-08

    The present work was conducted to study integrated chromium removal from aqueous solutions in horizontal subsurface (HSF) constructed wetlands. Two pilot-scale HSF constructed wetlands (CWs) units were built and operated. One unit was planted with common reeds (Phragmites australis) and one was kept unplanted. Influent concentrations of Cr(VI) ranged from 0.5 to 10mg/L. The effect of temperature and hydraulic residence time (8-0.5 days) on Cr(VI) removal were studied. Temperature was proved to affect Cr(VI) removal in both units. In the planted unit maximum Cr(VI) removal efficiencies of 100% were recorded at HRT's of 1 day with Cr(VI) concentrations of 5, 2.5 and 1mg/L, while a significantly lower removal rate was recorded in the unplanted unit. Harvested reed biomass from the CWs was co-composted with olive mill wastes. The final product had excellent physicochemical characteristics (C/N: 14.1-14.7, germination index (GI): 145-157%, Cr: 8-10mg/kg dry mass), fulfills EU requirements and can be used as a fertilizer in organic farming. Copyright © 2014 Elsevier B.V. All rights reserved.

  7. [Adsorptive Stabilization of Soil Cr (VI) Using HDTMA Modified Montmorillonite].

    Science.gov (United States)

    2016-03-15

    A series of organo-montomorillonites were prepared using Na-montomorillonite and hexadecyl trimethyl ammonium bromide (HDTMA). The organo-montomorillonites were then investigated for the remediation of Cr(VI) contaminated soils. FT-IR, XRD, SEM and N2 -BET, CEC, Zeta potential measurement were conducted to understand the structural changes of montmorillonites as different amounts of HDTMAs were added as modifier. The characterization results indicated that the clay interlayer spacing distance increased from 1. 25 nm to 2. 13 nm, the clay surface roughness decreased, the clay surface area reduced from 38.91 m² · g⁻¹ to 0.42 m² · g⁻¹, the clay exchangeable cation amount reduced from 62 cmol · kg⁻¹ to 9.9 cmol · kg⁻¹ and the clay surface charge changed from -29.1 mV to 5.59 mV as the dosage of HDTMA in montmorillonite was increased. The TCLP (toxicity characteristic leaching procedure) was used to evaluate the leachate toxicity of Cr(VI). The effects of the initial soil Cr(VI) concentration, montmorillonites dosage, reaction time and HDTMA modification amount were investigated, respectively. The results revealed that modification of montmorillonites would manifest an attenuated physical adsorptive effect and an enhanced electrostatic adsorptive effect on Cr(VI), suggesting electrostatic effect was the major force that resulted in improved Cr(VI) adsorption onto HDTMA modified montmorillonites.

  8. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    International Nuclear Information System (INIS)

    Uygun, Murat; Feyzioğlu, Esra; Özçalışkan, Emir; Caka, Müşerref; Ergen, Aygen; Akgöl, Sinan; Denizli, Adil

    2013-01-01

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO 3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m 2 /g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities

  9. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    Science.gov (United States)

    Uygun, Murat; Feyzioğlu, Esra; Özçalışkan, Emir; Caka, Müşerref; Ergen, Aygen; Akgöl, Sinan; Denizli, Adil

    2013-08-01

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO3 solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m2/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.

  10. New generation ion-imprinted nanocarrier for removal of Cr(VI) from wastewater

    Energy Technology Data Exchange (ETDEWEB)

    Uygun, Murat, E-mail: muygun@adu.edu.tr [Adnan Menderes University, Kocarl Latin-Small-Letter-Dotless-I Vocational and Training School (Turkey); Feyzioglu, Esra; Oezcal Latin-Small-Letter-Dotless-I skan, Emir; Caka, Mueserref; Ergen, Aygen; Akgoel, Sinan [Ege University, Department of Biochemistry, Faculty of Science (Turkey); Denizli, Adil [Hacettepe University, Department of Chemistry, Faculty of Science (Turkey)

    2013-08-15

    The purpose of this study was to prepare a novel ion-imprinted nanoparticle to remove Cr(VI) ions from waste water. For this, Cr(VI) ions were complexed with 2-methacryloylamido histidine (MAH) and then Cr(VI)-imprinted poly(HEMAH) nanoparticles were synthesized by surfactant-free emulsion polymerization technique. The templates, Cr(VI) ions, were removed from the nanoparticles using 0.1 M of HNO{sub 3} solution. The specific surface area of the Cr(VI)-imprinted poly(HEMAH) nanoparticles was found to be 1,397.85 m{sup 2}/g, and the particle size was calculated as 155.3 nm. These Cr(VI)-imprinted nanoparticles were used for the adsorption/desorption of Cr(VI) ions from its aqueous solutions. The effects of initial Cr(VI) concentration and medium pH on the Cr(VI) adsorption capacity were also studied. The maximum adsorbed amount of Cr(VI) on the imprinted nanoparticles was found to be 3,830.58 mg/g nanoparticle in pH 4.0. In order to investigate the selectivity of the imprinted nanoparticle, adsorption studies were repeated using Cr(III) ions. The selectivity results demonstrated that Cr(VI)-imprinted poly(HEMAH) nanoparticles showed high affinity for the Cr(VI) ions than Cr(III). The Cr(VI)-imprinted nanoparticles were used several times without decreasing their Cr(VI) adsorption capacities.

  11. Nitrate Enhanced Microbial Cr(VI) Reduction-Final Report

    Energy Technology Data Exchange (ETDEWEB)

    John F. Stolz

    2011-06-15

    A major challenge for the bioremediation of radionuclides (i.e., uranium, technetium) and metals (i.e., Cr(VI), Hg) is the co-occurrence of nitrate as it can inhibit metal transformation. Denitrification (nitrate reduction to dinitrogen gas) is considered the most important ecological process. For many metal and metalloid reducing bacteria, however, ammonia is the end product through respiratory nitrate reduction (RNRA). The focus of this work was to determine how RNRA impacts Cr(VI) transformation. The goal was to elucidate the specific mechanism(s) that limits Cr(VI) reduction in the presence of nitrate and to use this information to develop strategies that enhance Cr(VI) reduction (and thus detoxification). Our central hypothesis is that nitrate impacts the biotransformation of metals and metalloids in three ways 1) as a competitive alternative electron acceptor (inhibiting transformation), 2) as a co-metabolite (i.e., concomitant reduction, stimulating transformation), and 3) as an inducer of specific proteins and pathways involved in oxidation/reduction reactions (stimulating transformation). We have identified three model organisms, Geobacter metallireducens (mechanism 1), Sulfurospirillum barnesii, (mechasism 2), and Desulfovibrio desulfuricans (mechanisms 3). Our specific aims were to 1) investigate the role of Cr(VI) concentration on the kinetics of both growth and reduction of nitrate, nitrite, and Cr(VI) in these three organisms; 2) develop a profile of bacterial enzymes involved in nitrate transformation (e.g., oxidoreductases) using a proteomic approach; 3) investigate the function of periplasmic nitrite reductase (Nrf) as a chromate reductase; and 4) develop a strategy to maximize microbial chromium reduction in the presence of nitrate. We found that growth on nitrate by G. metallireducens was inhibited by Cr(VI). Over 240 proteins were identified by LC/MS-MS. Redox active proteins, outer membrane heavy metal efflux proteins, and chemotaxis sensory

  12. Polarographic behaviour of uranium (VI) in tributyl phosphate organic solutions

    International Nuclear Information System (INIS)

    Degueldre, C.A.; Meklati, M.

    1984-01-01

    U(VI) determination by D.C. and differential pulse polarography was studied in the organic solutions derived from tributyl phosphate - diluent extracts (after separation from nitric acid media) along with a selected aprotic solvent (i.e.: propylene carbonate and N,N-dimethylacetamide). Miscibility of the TBP-diluent (e.g. cyclohexane, n-hexane, kerosene, n-dodecane) phase with nitric acid as supporting electrolyte, either by addition or already present in the extract was larger in DMA than in PC. In the DMA organic mixture, U(VI) exhibited a DPP peak due to a one electron step, with Esub(p)=-0.4 V (position connected with H 2 O and HNO 3 concentrations). This peak which was proportionnel to the U(VI) concentration from 5x10 -6 to 10 -3 M can be used to determinate directly hexavalent uranium in the industrial organic extraction phases TBP-diluent. (orig.)

  13. Benchmark analysis of MCNP trademark ENDF/B-VI iron

    International Nuclear Information System (INIS)

    Court, J.D.; Hendricks, J.S.

    1994-12-01

    The MCNP ENDF/B-VI iron cross-section data was subjected to four benchmark studies as part of the Hiroshima/Nagasaki dose re-evaluation for the National Academy of Science and the Defense Nuclear Agency. The four benchmark studies were: (1) the iron sphere benchmarks from the Lawrence Livermore Pulsed Spheres; (2) the Oak Ridge National Laboratory Fusion Reactor Shielding Benchmark; (3) a 76-cm diameter iron sphere benchmark done at the University of Illinois; (4) the Oak Ridge National Laboratory Benchmark for Neutron Transport through Iron. MCNP4A was used to model each benchmark and computational results from the ENDF/B-VI iron evaluations were compared to ENDF/B-IV, ENDF/B-V, the MCNP Recommended Data Set (which includes Los Alamos National Laboratory Group T-2 evaluations), and experimental data. The results show that the ENDF/B-VI iron evaluations are as good as, or better than, previous data sets

  14. Extraction kinetics of uranium (VI) with polyurethane foam

    International Nuclear Information System (INIS)

    Huang, Ting-Chia; Chen, Dong-Hwang; Huang, Shius-Dong; Huang, Ching-Tsven; Shieh, Mu-Chang.

    1993-01-01

    The extraction kinetics of uranium(VI) from aqueous nitrate solution with polyether-based polyurethane foam was investigated in a batch reactor with automatic squeezing. The extraction curves of uranium(VI) concentration in solution vs. extraction time exhibited a rather rapid exponential decay within the first few minutes, followed by a slower exponential decay during the remaining period. This phenomenon can be attributed to the presence of two-phase structure, hard segment domains and soft segment matrix in the polyurethane foam. A two-stage rate model expressed by a superposition of two exponential curves was proposed, according to which the experimental data were fitted by an optimization method. The extraction rate of uranium (VI) was also found to increase with increasing temperature, nitrate concentration, and hydration of the cation of nitrate salt. (author)

  15. Isolation of a star-shaped uranium(V/VI) cluster from the anaerobic photochemical reduction of uranyl(VI)

    International Nuclear Information System (INIS)

    Chatelain, Lucile; White, Sarah; Scopelliti, Rosario; Mazzanti, Marinella

    2016-01-01

    Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI) has potential application in catalysis and spent nuclear fuel reprocessing, but the intermediate species involved in this reduction have not yet been elucidated. Here we show that the photolysis of partially hydrated uranyl(VI) in anaerobic conditions leads to the reduction of uranyl(VI), and to the incorporation of the resulting U V species into the stable mixed-valent star-shaped U VI /U V oxo cluster [U(UO 2 ) 5 (μ 3 -O) 5 (PhCOO) 5 (Py) 7 ]. This cluster is only the second example of a U VI /U V cluster and the first one associating uranyl groups to a non-uranyl(V) center. The U V center in 1 is stable, while the reaction of uranyl(V) iodide with potassium benzoate leads to immediate disproportionation and formation of the U 12 IV U 4 V O 24 cluster {[K(Py) 2 ] 2 [K(Py)] 2 [U 16 O 24 (PhCOO) 24 (Py) 2 ]}.

  16. Isolation of a star-shaped uranium(V/VI) cluster from the anaerobic photochemical reduction of uranyl(VI)

    Energy Technology Data Exchange (ETDEWEB)

    Chatelain, Lucile; White, Sarah; Scopelliti, Rosario; Mazzanti, Marinella [Ecole Polytechnique Federale de Lausanne (EPFL) (Switzerland). Inst. de Sciences et Ingenierie Chimiques

    2016-11-07

    Actinide oxo clusters are an important class of compounds due to their impact on actinide migration in the environment. The photolytic reduction of uranyl(VI) has potential application in catalysis and spent nuclear fuel reprocessing, but the intermediate species involved in this reduction have not yet been elucidated. Here we show that the photolysis of partially hydrated uranyl(VI) in anaerobic conditions leads to the reduction of uranyl(VI), and to the incorporation of the resulting U{sup V} species into the stable mixed-valent star-shaped U{sup VI}/U{sup V} oxo cluster [U(UO{sub 2}){sub 5}(μ{sub 3}-O){sub 5}(PhCOO){sub 5}(Py){sub 7}]. This cluster is only the second example of a U{sup VI}/U{sup V} cluster and the first one associating uranyl groups to a non-uranyl(V) center. The U{sup V} center in 1 is stable, while the reaction of uranyl(V) iodide with potassium benzoate leads to immediate disproportionation and formation of the U{sub 12}{sup IV}U{sub 4}{sup V}O{sub 24} cluster {[K(Py)_2]_2[K(Py)]_2[U_1_6O_2_4(PhCOO)_2_4(Py)_2]}.

  17. Studies on extraction of uranium (VI) with petroleum sulfoxides

    International Nuclear Information System (INIS)

    Yang Yanzhao; Sun Sixiu; Bao Borong

    1999-01-01

    The extraction of uranium(VI) with petroleum sulfoxides(PSO) in different diluents is studied. The extraction ability of U(VI) decreases in the following order: benzene, toluene, cyclohexane, heptane, kerosene, carbon tetrachloride and chloroform. The influence of the concentrations of nitric acid, PSO, salting out agent, complexing anion and temperature on the extraction equilibrium is also investigated, and the enthalpy of the extraction reaction is obtained. The relationship between the extraction equilibrium constants K ex and the physical parameters of diluents is derived. The extraction mechanism and equilibrium are examined by measurement of IR spectrophotometry

  18. Neutron cross section standards evaluations for ENDF/B-VI

    International Nuclear Information System (INIS)

    Carlson, A.D.; Poenitz, W.P.; Hale, G.M.; Peelle, R.W.

    1985-01-01

    The neutron cross section standards are now being evaluated as the initial phase in the development of the new ENDF/B-VI file. These standards evaluations are following a somewhat different process compared with that used for earlier versions of ENDF. The primary effort is concentrated on a simultaneous evaluation using a generalized least squares program, R-matrix evaluations, and a procedure for combining the results of these evaluations. The ENDF/B-VI standards evaluation procedure is outlined, and preliminary simultaneous evaluation and R-matrix results are presented. 16 refs., 7 figs

  19. Thermophysical Properties of Selected II-VI Semiconducting Melts

    Science.gov (United States)

    Li, C.; Su, Ching-Hua; Lehoczky, S. L.; Scripa, R. N.; Ban, H.; Lin, B.

    2004-01-01

    Thermophysical properties are essential for the accurate predication of the crystal growth process by computational modeling. Currently, the temperature dependent thermophysical property data for the II-VI semiconductor melts are scarce. This paper reports the results of the temperature dependence of melt density, viscosity and electrical conductivity of selected II-VI compounds, including HgTe, HgCdTe and HgZnTe. The melt density was measured using a pycnometric method, and the viscosity and electrical conductivity were measured by a transient torque method. The results were compared with and showed good agreement with the existing data in the literature.

  20. Quantifying Cr(VI) Production and Export from Serpentine Soil of the California Coast Range.

    Science.gov (United States)

    McClain, Cynthia N; Fendorf, Scott; Webb, Samuel M; Maher, Kate

    2017-01-03

    Hexavalent chromium (Cr(VI)) is generated in serpentine soils and exported to surface and groundwaters at levels above health-based drinking water standards. Although Cr(VI) concentrations are elevated in serpentine soil pore water, few studies have reported field evidence documenting Cr(VI) production rates and fluxes that govern Cr(VI) transport from soil to water sources. We report Cr speciation (i) in four serpentine soil depth profiles derived from the California Coast Range serpentinite belt and (ii) in local surface waters. Within soils, we detected Cr(VI) in the same horizons where Cr(III)-minerals are colocated with biogenic Mn(III/IV)-oxides, suggesting Cr(VI) generation through oxidation by Mn-oxides. Water-extractable Cr(VI) concentrations increase with depth constituting a 7.8 to 12 kg/km 2 reservoir of Cr(VI) in soil. Here, Cr(VI) is produced at a rate of 0.3 to 4.8 kg Cr(VI)/km 2 /yr and subsequently flushed from soil during water infiltration, exporting 0.01 to 3.9 kg Cr(VI)/km 2 /yr at concentrations ranging from 25 to 172 μg/L. Although soil-derived Cr(VI) is leached from soil at concentrations exceeding 10 μg/L, due to reduction and dilution during transport to streams, Cr(VI) levels measured in local surface waters largely remain below California's drinking water limit.

  1. Contribution of extracellular polymeric substances from Shewanella sp. HRCR-1 biofilms to U(VI) immobilization.

    Science.gov (United States)

    Cao, Bin; Ahmed, Bulbul; Kennedy, David W; Wang, Zheming; Shi, Liang; Marshall, Matthew J; Fredrickson, Jim K; Isern, Nancy G; Majors, Paul D; Beyenal, Haluk

    2011-07-01

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) to U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells with minimal EPS, we show that (i) bEPS from Shewanella sp. HRCR-1 biofilms contribute significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; (ii) bEPS can be considered a functional extension of the cells for U(VI) immobilization and they likely play more important roles at lower initial U(VI) concentrations; and (iii) the U(VI) reduction efficiency is dependent upon the initial U(VI) concentration and decreases at lower concentrations. To quantify the relative contributions of sorption and reduction to U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(VI). We found that, when reduced, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated the reactivity of laEPS, while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, possibly facilitated U(VI) reduction.

  2. Group IB Organometallic Chemistry XXXIV: Thermal behavior and chemical reactivity of tetranuclear Me2N-substituted diarylpropenylcopper-copper anion (Vi2Cu4X2) and mixed diarylpropenyl/organocopper (Vi2Cu4R2) compounds

    NARCIS (Netherlands)

    Koten, G. van; Hoedt, R.W.M. ten; Noltes, J.G.

    1980-01-01

    Thermal decomposition of configurationally pure 1, 2-diarylpropenylcopper compounds Z-Vi{2}CU{4}Br{2} and Z-Vi{2}Cu{4}R{2} [Vi @? (2-Me{2}NC{6}H{4})C@?C(Me)-(C{6}H{4}Me-4), R @? 2-Me{2}NC{6}H{4} or 4-MeC{6}H{4}C@?C] predominantly results in the formation of ViH. In contrast, only dimers (ViVi) were

  3. Thermodynamic parameters and sorption of U(VI) on ACSD

    International Nuclear Information System (INIS)

    Donat, R.; Cilgi, G.K.; Cetisli, H.; Aytas, S.

    2009-01-01

    This paper discusses the sorption properties for U(VI) by alginate coated CaSO 4 x 2H 2 O sepiolite and calcined diatomite earth (Kieselguhr) (ACSD). The removal of U(VI) from aqueous solution by sorption onto ACSF in a single component system with various contact times, pH, temperatures, and initial concentrations of U(VI) was investigated. The sorption patterns of uranium on the composite adsorbent followed the Langmuir, Freundlich and Dubinin-Radushkhevic (D-R) isotherms. The Freundlich, Langmuir, and D-R models have been applied and the data correlated well with Freundlich model and that the sorption was physical in nature (sorption energy, E a = 17.05 kJ/mol). The thermodynamic parameters such as variation of enthalpy ΔH, variation of entropy ΔS and variation of Gibbs free energy ΔG were calculated from the slope and intercept of lnK 0 vs. 1/T plots. Thermodynamic parameters (ΔH ads = 31.83 kJ/mol, ΔS ads = 167 J/mol x K, ΔGdeg ads (293.15 K) = -17.94 kJ/mol) showed the endothermic heat of sorption and the feasibility of the process. The thermodynamics of U(VI) ion/ACSD system indicates the spontaneous and endothermic nature of the process. It was noted that an increase in temperature resulted in a higher uranium loading per unit weight of the adsorbent. (author)

  4. ENDF-201: ENDF/B-VI summary documentation

    International Nuclear Information System (INIS)

    Rose, P.F.

    1991-10-01

    Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe 56 . The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on ''tapes.'' Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the ''tape'' number. These evaluations have been released without restrictions on their distribution or use

  5. National Environmental/Energy Workforce Assessment for Region VI.

    Science.gov (United States)

    National Field Research Center Inc., Iowa City, IA.

    This report represents a detailed summation of existing workforce levels, training programs, career potential, and staffing level projections through 1981 for EPA Region VI. This region serves the Gulf fringe states of Texas, Arkansas, New Mexico, Oklahoma, and Louisiana. The specific pollution programs considered include air, noise, pesticides,…

  6. Revolutsioonilisest ja igavikulisest VI Tallinna arhitektuuritriennaalil / Ave Randviir

    Index Scriptorium Estoniae

    Randviir, Ave, 1981-

    2005-01-01

    Tallinna arhitektuuritriennaali idee sünnist. 1990.a. toimus esimene triennaal nimega Põhja- ja Baltimaade Arhitektuuritriennaal. Niguliste kirikus toimunud VI Tallinna arhitektuuritriennaalist. Korraldajaks Irina Raud. Tunnuslauseks "Feeling Architecture". Triennaali avanud ja lõpetanud Peter Davey ja teiste esinejate ettekannetest. Eestlastest esinesid Juhan Maiste ja Vilen Künnapu

  7. Osteogenesis Imperfecta Type VI in Individuals from Northern Canada.

    Science.gov (United States)

    Ward, Leanne; Bardai, Ghalib; Moffatt, Pierre; Al-Jallad, Hadil; Trejo, Pamela; Glorieux, Francis H; Rauch, Frank

    2016-06-01

    Osteogenesis imperfecta (OI) type VI is a recessively inherited form of OI that is caused by mutations in SERPINF1, the gene coding for pigment-epithelium derived factor (PEDF). Here, we report on two apparently unrelated children with OI type VI who had the same unusual homozygous variant in intron 6 of SERPINF1 (c.787-10C>G). This variant created a novel splice site that led to the in-frame addition of three amino acids to PEDF (p.Lys262_Ile263insLeuSerGln). Western blotting showed that skin fibroblasts with this mutation produced PEDF but failed to secrete it. Both children were treated with intravenous bisphosphonates, but the treatment of Individual 1 was switched to subcutaneous injections of denosumab (dose 1 mg per kg body weight, repeated every 3 months). An iliac bone sample obtained after 5 denosumab injections (and 3 months after the last injection) showed no change in the increased osteoid parameters that are typical of OI type VI, but the number of osteoclasts in trabecular bone was markedly increased. This suggests that the effect of denosumab on osteoclast suppression is of shorter duration in children with OI type VI than what has previously been reported on adults with osteoporosis.

  8. Paisaje del viñedo: patrimonio y recurso

    Directory of Open Access Journals (Sweden)

    Luis Vicente Elías

    2008-01-01

    Full Text Available La propuesta de que el paisaje del viñedo sea el complemento a la visita a la bodega, siendo esta el eje del turismo del vino, es el objetivo de este trabajo. Repasando los conceptos variables de patrimonio, llegamos al paisaje del viñedo como recurso, formando parte del patrimonio natural. Pero este no se puede desvincular de los otros aspectos patrimoniales, por lo que la cultura tradicional es el soporte de la tipología de paisaje que queremos proponer y que va contrastar con los nuevos paisajes del viñedo que surgen de las recientes técnicas en los cultivos y de la actual vitivicultura, emparejada con una moderna “cultura del vino”. El análisis de las diversas normativas, que salvaguardan el paisaje y la comprobación del escaso valor legal del paisaje del viñedo, es otro puntal de este trabajo que trata de unir paisaje con cultura tradicional como recursos del Turismo del Vino, integrados en las Rutas del Vino.

  9. Selective removal of chromium (VI) from sulphates and other metal ...

    African Journals Online (AJOL)

    Leaching of the chromate template from the polymer particles was achieved with successive stirring of the ion-imprinted polymer (IIP) particles in 4 M HNO3 solutions to obtain leached materials, which were then ... Despite the method's very low detection limits for direct injection (below 1 μg∙ℓ-1), no Cr (VI) was obtained.

  10. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    International Nuclear Information System (INIS)

    Liu, Haitao

    2007-01-01

    In the last two decades, the field of nanoscience and nanotechnology has witnessed tremendous advancement in the synthesis and application of group II-VI colloidal nanocrystals. The synthesis based on high temperature decomposition of organometallic precursors has become one of the most successful methods of making group II-VI colloidal nanocrystals. This method is first demonstrated by Bawendi and coworkers in 1993 to prepare cadmium chalcogenide colloidal quantum dots and later extended by others to prepare other group II-VI quantum dots as well as anisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod. This dissertation focuses on the chemistry of this type of nanocrystal synthesis. The synthesis of group II-VI nanocrystals was studied by characterizing the molecular structures of the precursors and products and following their time evolution in the synthesis. Based on these results, a mechanism was proposed to account for the 2 reaction between the precursors that presumably produces monomer for the growth of nanocrystals. Theoretical study based on density functional theory calculations revealed the detailed free energy landscape of the precursor decomposition and monomer formation pathway. Based on the proposed reaction mechanism, a new synthetic method was designed that uses water as a novel reagent to control the diameter and the aspect ratio of CdSe and CdS nanorods

  11. As duas naturezas de Lévi-Strauss

    Directory of Open Access Journals (Sweden)

    Philippe Descola

    2011-11-01

    Full Text Available Aborda-se aqui a complexidade do status do par conceitual natureza e cultura no pensamento de Lévi-Strauss. Ao mesmo tempo ferramenta de análise, cena filosófica dos primórdios e antinomia a superar, revisita-se os diferentes usos e significados na obra de Lévi-Strauss do conceito de natureza e sua relação com o de cultura. Mostra-se como é possível reconhecer na obra de Lévi-Strauss dois conceitos de natureza: por um lado, uma natureza que se opõe à cultura num programa científico formulado em termos classicamente dualistas e, por outro, uma teoria do conhecimento decididamente monista que considera o espírito como parte e produto desse mesmo mundo. Argumenta-se que se o dualismo entre cultura e natureza fundou o pensamento estruturalista de Lévi-Strauss, é na própria obra deste que encontramos os argumentos e meios de superá-lo. A vocação do estruturalismo na antropologia de hoje, no entanto, é de ir mais longe neste caminho do que foi o próprio fundador.

  12. Chemistry of the Colloidal Group II-VI Nanocrystal Synthesis

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Haitao [Univ. of California, Berkeley, CA (United States)

    2007-05-17

    In the last two decades, the field of nanoscience andnanotechnology has witnessed tremendous advancement in the synthesis andapplication of group II-VI colloidal nanocrystals. The synthesis based onhigh temperature decomposition of organometallic precursors has becomeone of the most successful methods of making group II-VI colloidalnanocrystals. This methodis first demonstrated by Bawendi and coworkersin 1993 to prepare cadmium chalcogenide colloidal quantum dots and laterextended by others to prepare other group II-VI quantum dots as well asanisotropic shaped colloidal nanocrystals, such as nanorod and tetrapod.This dissertation focuses on the chemistry of this type of nanocrystalsynthesis. The synthesis of group II-VI nanocrystals was studied bycharacterizing the molecular structures of the precursors and productsand following their time evolution in the synthesis. Based on theseresults, a mechanism was proposed to account for the 2 reaction betweenthe precursors that presumably produces monomer for the growth ofnanocrystals. Theoretical study based on density functional theorycalculations revealed the detailed free energy landscape of the precursordecomposition and monomerformation pathway. Based on the proposedreaction mechanism, a new synthetic method was designed that uses wateras a novel reagent to control the diameter and the aspect ratio of CdSeand CdS nanorods.

  13. Habitat et environnement urbain au Viêt-nam

    International Development Research Centre (IDRC) Digital Library (Canada)

    Avant 1985, la construction et la gestion du logement au Viêt-nam étaient en ...... du contrôle administratif et n'ont pas été en mesure d'inciter le développement ...... et les syndicats, il est toutefois encore trop tôt pour juger de leur performance.

  14. Peroxo complexes of molybdenum(VI), tungsten(VI), uranium(VI), zirconium(IV) and thorium(IV) ions containing tridentate Schiff bases derived from salicylaldehyde and amino acids

    International Nuclear Information System (INIS)

    Tarafder, M.T.H.; Khan, A.R.

    1997-01-01

    The synthesis of peroxo complexes of molybdenum(VI), tungsten(VI), uranium(VI), zirconium(IV), thorium(IV) and their possible oxygen transfer reactions is presented. An attempt has also been made to study the size of the metal ions and the electronic effect derived from the tridentate Schiff bases on the v 1 (O-O) mode of the complexes in their IR spectra

  15. Selectivity enhancement of phosphate based functional polymeric gels towards Uranium(VI) using ion imprinting

    International Nuclear Information System (INIS)

    Chappa, Sankararao; Agarwal, Chhavi; Pandey, A.K.

    2015-01-01

    The imprinting of gel containing polymer chains of ethylene glycol methacrylate phosphate (EGMP) for U(VI) ions were carried out. The U(VI) imprinting has been carried out in pure EGMP and in EGMP: poly(ethylene glycol) methacrylate (PEGMA) = 1:9 composition. Complexation of the monomer with template (U(VI)) followed by polymerization have been used to imprint the U(VI) onto the polymer chains. The comparison of uptake studies of U(VI) and Pu(IV) at 3 M HNO 3 shows increased selectivity of U(VI) relative to Pu(IV) for both the gel compositions. The less uptake of U(VI) for imprinted EGMP:PEGMA gel relative to pure imprinted EGMP gel at tracer level can be possibly due to the requirement of two EGMP units in the vicinity for U(VI) complexation. (author)

  16. Influence of U(VI) on the metabolism of plant cells studied by microcalorimetry and TRLFS

    Energy Technology Data Exchange (ETDEWEB)

    Sachs, Susanne; Geipel, Gerhard [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Biogeochemistry; Fahmy, Karim; Oertel, Jana [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Biophysics; Bok, Frank [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Surface Processes

    2017-06-01

    Uranium(VI) shows a concentration-dependent influence on the metabolic activity of plant cells. With increasing U(VI) concentration, the predominant U(VI) species in medium R{sub red} changes from UO{sub 2}HPO{sub 4}(s) to (UO{sub 2}){sub 3}(OH){sub 5}{sup +}, which may affect the bioavailability of U(VI).

  17. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Directory of Open Access Journals (Sweden)

    Peter J Hart

    Full Text Available Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  18. Differential Killing of Salmonella enterica Serovar Typhi by Antibodies Targeting Vi and Lipopolysaccharide O:9 Antigen.

    Science.gov (United States)

    Hart, Peter J; O'Shaughnessy, Colette M; Siggins, Matthew K; Bobat, Saeeda; Kingsley, Robert A; Goulding, David A; Crump, John A; Reyburn, Hugh; Micoli, Francesca; Dougan, Gordon; Cunningham, Adam F; MacLennan, Calman A

    2016-01-01

    Salmonella enterica serovar Typhi expresses a capsule of Vi polysaccharide, while most Salmonella serovars, including S. Enteritidis and S. Typhimurium, do not. Both S. Typhi and S. Enteritidis express the lipopolysaccharide O:9 antigen, yet there is little evidence of cross-protection from anti-O:9 antibodies. Vaccines based on Vi polysaccharide have efficacy against typhoid fever, indicating that antibodies against Vi confer protection. Here we investigate the role of Vi capsule and antibodies against Vi and O:9 in antibody-dependent complement- and phagocyte-mediated killing of Salmonella. Using isogenic Vi-expressing and non-Vi-expressing derivatives of S. Typhi and S. Typhimurium, we show that S. Typhi is inherently more sensitive to serum and blood than S. Typhimurium. Vi expression confers increased resistance to both complement- and phagocyte-mediated modalities of antibody-dependent killing in human blood. The Vi capsule is associated with reduced C3 and C5b-9 deposition, and decreased overall antibody binding to S. Typhi. However, purified human anti-Vi antibodies in the presence of complement are able to kill Vi-expressing Salmonella, while killing by anti-O:9 antibodies is inversely related to Vi expression. Human serum depleted of antibodies to antigens other than Vi retains the ability to kill Vi-expressing bacteria. Our findings support a protective role for Vi capsule in preventing complement and phagocyte killing of Salmonella that can be overcome by specific anti-Vi antibodies, but only to a limited extent by anti-O:9 antibodies.

  19. Spectroscopic Studies on Complex Formation of U(VI)-thiosalicylate

    Energy Technology Data Exchange (ETDEWEB)

    Cha, Wan Sik; Cho, Hye Ryun; Park, Kyoung Kyun; Jung, Euo Chang [Korea Atomic Energy Research Institute, Daejeon (Korea, Republic of)

    2011-05-15

    The dynamic interaction between radionuclides and organic ligands is largely dependent on the composition of functional groups in a ligand chemical structure. Therefore, the structural mimics of natural ligands possessing specific functional groups, such as hydroxy, phenol, carboxyl, thiol and amine groups, have been studied to understand their influence on the migration of radionuclides including actinide species under geological groundwater conditions. In previous studies, we demonstrated that the fraction of hydrolyzed U(VI) species occurring in weak acidic solutions (pH {approx}4.5) is significantly influenced by the presence of salicylate (Sal) ligand due to the simultaneous participation of both phenol and carboxyl groups in the formation of U(VI)-complexes. Thiosalicylic acid (TSalH{sub 2}) is a good model compound for studying the effects of both carboxyl and thiol (-SH) groups. The fraction of di-anionic ligand form (TSal{sup 2-}) is higher at near neutral pH due to the lower pKa ({approx} 8) of the thiol group than the case of salicylic acid (pKa, {approx}13 for salicylic -OH), despite the structural similarity. In addition, the redox capability of the thiol group is expected to influence the reducible radiouclides and the chemical structures of natural ligands by creating cross-linkage (-S-S-) upon oxidation. The goal of the present study is to investigate aqueous U(VI)-TSal complexation equilibrium via laser-based spectroscopic techniques including time resolved laser-induced fluorescence spectroscopy (TRLFS). In this preliminary work, we report the results of spectroscopic studies using conventional UVVis absorbance and fluorescence (FL) measurement methods. The photo-stability of U(VI)-TSal complex or ligand itself upon exposure to a series of laser pulses is estimated by monitoring the change in their absorption bands. Additionally, TSal FL-quenching effect by U(VI) ions is discussed in comparison with that of Sal FL-quenching

  20. Diverse functions of myosin VI elucidated by an isoform-specific α-helix domain.

    Science.gov (United States)

    Wollscheid, Hans-Peter; Biancospino, Matteo; He, Fahu; Magistrati, Elisa; Molteni, Erika; Lupia, Michela; Soffientini, Paolo; Rottner, Klemens; Cavallaro, Ugo; Pozzoli, Uberto; Mapelli, Marina; Walters, Kylie J; Polo, Simona

    2016-04-01

    Myosin VI functions in endocytosis and cell motility. Alternative splicing of myosin VI mRNA generates two distinct isoform types, myosin VI(short) and myosin VI(long), which differ in the C-terminal region. Their physiological and pathological roles remain unknown. Here we identified an isoform-specific regulatory helix, named the α2-linker, that defines specific conformations and hence determines the target selectivity of human myosin VI. The presence of the α2-linker structurally defines a new clathrin-binding domain that is unique to myosin VI(long) and masks the known RRL interaction motif. This finding is relevant to ovarian cancer, in which alternative myosin VI splicing is aberrantly regulated, and exon skipping dictates cell addiction to myosin VI(short) in tumor-cell migration. The RRL interactor optineurin contributes to this process by selectively binding myosin VI(short). Thus, the α2-linker acts like a molecular switch that assigns myosin VI to distinct endocytic (myosin VI(long)) or migratory (myosin VI(short)) functional roles.

  1. Contribution of Extracellular Polymeric Substances from Shewanella sp. HRCR-1 Biofilms to U(VI) Immobilization

    Energy Technology Data Exchange (ETDEWEB)

    Cao, Bin; Ahmed, B.; Kennedy, David W.; Wang, Zheming; Shi, Liang; Marshall, Matthew J.; Fredrickson, Jim K.; Isern, Nancy G.; Majors, Paul D.; Beyenal, Haluk

    2011-06-05

    The goal of this study was to quantify the contribution of extracellular polymeric substances (EPS) in U(VI) immobilization by Shewanella sp. HRCR-1. Through comparison of U(VI) immobilization using cells with bound EPS (bEPS) and cells without EPS, we showed that i) bEPS from Shewanella sp. HRCR-1 biofilms contributed significantly to U(VI) immobilization, especially at low initial U(VI) concentrations, through both sorption and reduction; ii) bEPS could be considered as a functional extension of the cells for U(VI) immobilization and they likely play more important roles at initial U(VI) concentrations; and iii) U(VI) reduction efficiency was found to be dependent upon initial U(VI) concentration and the efficiency decreased at lower concentrations. To quantify relative contribution of sorption and reduction in U(VI) immobilization by EPS fractions, we isolated loosely associated EPS (laEPS) and bEPS from Shewanella sp. HRCR-1 biofilms grown in a hollow fiber membrane biofilm reactor and tested their reactivity with U(V). We found that, when in reduced form, the isolated cell-free EPS fractions could reduce U(VI). Polysaccharides in the EPS likely contributed to U(VI) sorption and dominated reactivity of laEPS while redox active components (e.g., outer membrane c-type cytochromes), especially in bEPS, might facilitate U(VI) reduction.

  2. Extraction of uranium (VI) from sea water using hydrous metalic oxide binded with hydrophilic polymers

    International Nuclear Information System (INIS)

    Shigetomi, Yasumasa; Kojima, Takehiro; Kamba, Hideaki

    1978-01-01

    In the past five years, many researches have been made to extract U(VI) from sea water. This is a report of the extraction of U(VI) from sea water using hydrous titanium oxide binded with hydrophilic polymers, the apparatus for the adsorption and the separation of U(VI) by means of ion exchange. (author)

  3. 77 FR 16251 - Announcement of Funding Awards, HOPE VI Revitalization Grant Program, Fiscal Year 2010

    Science.gov (United States)

    2012-03-20

    ... Awards, HOPE VI Revitalization Grant Program, Fiscal Year 2010 AGENCY: Office of the Assistant Secretary... the Fiscal Year 2010 (FY2010) Notice of Funding Availability (NOFA) for the HOPE VI Revitalization... recipients under the HOPE VI Revitalization grant program. FOR FURTHER INFORMATION CONTACT: For questions...

  4. 76 FR 18570 - Notice of Proposed Information Collection for Public Comment; HOPE VI Public Housing Programs...

    Science.gov (United States)

    2011-04-04

    ... Information Collection for Public Comment; HOPE VI Public Housing Programs: Funding and Program Data... responses. This Notice also lists the following information: Title of Proposal: HOPE VI program. OMB Control... (Pub. L. 105- 276, 112 Stat. 2461, approved October 21, 1998) and revised by the HOPE VI Program...

  5. 24 CFR 972.115 - Relationship between required conversions and HOPE VI developments.

    Science.gov (United States)

    2010-04-01

    ... conversions and HOPE VI developments. 972.115 Section 972.115 Housing and Urban Development Regulations... Relationship between required conversions and HOPE VI developments. HUD actions to approve or deny proposed HOPE VI revitalization plans must be consistent with the requirements of this subpart. Developments...

  6. 78 FR 72056 - Proposed Amendment of Class D and Class E Airspace; Christiansted, St. Croix, VI

    Science.gov (United States)

    2013-12-02

    ... Class D and Class E Airspace; Christiansted, St. Croix, VI AGENCY: Federal Aviation Administration (FAA... Class E Airspace at Christiansted, St. Croix, VI, to adjust the geographic coordinates of Henry E..., Christiansted, St. Croix, VI, to bring it in concert with the FAAs aeronautical database. The coordinates would...

  7. Mechanisms of chromium (VI)-induced apoptosis in anterior pituitary cells.

    Science.gov (United States)

    Quinteros, Fernanda A; Machiavelli, Leticia I; Miler, Eliana A; Cabilla, Jimena P; Duvilanski, Beatriz H

    2008-07-30

    Hexavalent chromium (Cr (VI)) is a highly toxic metal. Exposure to Cr (VI) compounds may affect reproductive functions. Due to the importance of anterior pituitary hormones on reproductive physiology we have studied the effects of Cr (VI) on anterior pituitary. We previously demonstrated that, after in vivo Cr (VI) administration, Cr accumulates in the pituitary gland and affects prolactin secretion. In vitro, Cr (VI) causes apoptosis in anterior pituitary cells due to oxidative stress generation. To better understand the mechanisms involved in Cr (VI)-induced apoptosis we studied: (a) whether Cr (VI) affects the intracellular antioxidant response and (b) which of the apoptotic factors participates in Cr (VI) effect. Our results show that Cr (VI) treatment induces a decrease in catalase and glutathione peroxidase (GPx) activity but does not modify glutathione reductase (GR) activity. Cr (VI) exposure causes an increase of GSH levels. p53 and Bax mRNA are also upregulated by the metal. Pifithrin alpha, a p53 transcriptional inhibitor, increases Cr (VI) cytotoxicity, suggesting a role of p53 as a survival molecule. The antioxidant N-acetyl-cysteine (NAC) could prevent Bax mRNA increase and caspase 3 activation, confirming that Cr (VI)-induced apoptosis involves oxidative stress generation.

  8. Immunization with the conjugate vaccine Vi-CRM₁₉₇ against Salmonella typhi induces Vi-specific mucosal and systemic immune responses in mice.

    Science.gov (United States)

    Fiorino, Fabio; Ciabattini, Annalisa; Rondini, Simona; Pozzi, Gianni; Martin, Laura B; Medaglini, Donata

    2012-09-21

    Typhoid fever is a public health problem, especially among young children in developing countries. To address this need, a glycoconjugate vaccine Vi-CRM₁₉₇, composed of the polysaccharide antigen Vi covalently conjugated to the non-toxic mutant of diphtheria toxin CRM₁₉₇, is under development. Here, we assessed the antibody and cellular responses, both local and systemic, following subcutaneous injection of Vi-CRM₁₉₇. The glycoconjugate elicited Vi-specific serum IgG titers significantly higher than unconjugated Vi, with prevalence of IgG1 that persisted for at least 60 days after immunization. Vi-specific IgG, but not IgA, were present in intestinal washes. Lymphocytes proliferation after restimulation with Vi-CRM₁₉₇ was observed in spleen and mesenteric lymph nodes. These data confirm the immunogenicity of Vi-CRM₁₉₇ and demonstrate that the vaccine-specific antibody and cellular immune responses are present also in the intestinal tract, thus strengthening the suitability of Vi-CRM₁₉₇ as a promising candidate vaccine against Salmonella Typhi. Copyright © 2012 Elsevier Ltd. All rights reserved.

  9. Cr(III) reactivity and foot dermatitis in Cr(VI) positive patients

    DEFF Research Database (Denmark)

    Hansen, Malene Barré; Menné, Torkil; Johansen, Jeanne Duus

    2006-01-01

    Chromium allergy has become synonymous with Cr(VI) allergy. However, real exposure to chromium from leather products may include both Cr(III) and Cr(VI). In this study, we investigate the reactivity to both Cr(VI) and Cr(III) in consecutive patients to analyse the relation between foot eczema/leather...... to Cr(III). The increased risk was not due to a higher degree of sensitivity to Cr(VI). Leather was reported most frequently as the suspected cause of chromium dermatitis (54%). However, Cr(VI) allergics having foot eczema and positive or doubtful Cr(III) reactions often had positive reactions to other...

  10. Cr(VI) removal from aqueous solution by dried activated sludge biomass

    International Nuclear Information System (INIS)

    Wu Jun; Zhang Hua; He Pinjing; Yao Qian; Shao Liming

    2010-01-01

    Batch experiments were conducted to remove Cr(VI) from aqueous solution using activated sludge biomass. The effects of acid pretreatment of the biomass, initial pH, biomass and Cr(VI) concentrations on Cr(VI) removal efficiency were investigated. Proton consumption during the removal process and the reducing capacity of sludge biomass were studied. The results show that acid pretreatment could significantly improve Cr(VI) removal efficiency and increase Cr(VI) reducing capacity by 20.4%. Cr(VI) removal was remarkably pH-dependent; lower pH (pH = 1, 2) facilitated Cr(VI) reduction while higher pH (pH = 3, 4) favored sorption of the converted Cr(III). Lower Cr(VI) concentration as well as higher biomass concentration could accelerate Cr(VI) removal. Cr(VI) reduction was not the only reason for proton consumption in the removal process. Pseudo-second-order adsorption kinetic model could successfully simulate Cr(VI) removal except under higher pH conditions (pH = 3, 4).

  11. On reforming chapter VI of the Euratom Treaty

    International Nuclear Information System (INIS)

    Sandtner, W.

    1984-01-01

    The supply of uranium to the countries of the EC has been provided for in Chapter VI of the European Treaty. An Euratom Supply Agency was created, which enjoys a monopoly. However, this arrangement was hardly ever utilized in practice. For this reason, several attempts were made in the course of time to reform Chapter VI, most recently in 1979 on the initiative of France. The EC Commission now presented a ''new nuclear power strategy'' in early 1982, which was followed by a detailed report about the proposed changes in late 1982. Its main points as outlined and discussed in this article are these: defining the range of application; the unity of the market; international relations; solidarity measures; the future role of the Supply Agency. (orig.) [de

  12. ECG-ViEW II, a freely accessible electrocardiogram database

    Science.gov (United States)

    Park, Man Young; Lee, Sukhoon; Jeon, Min Seok; Yoon, Dukyong; Park, Rae Woong

    2017-01-01

    The Electrocardiogram Vigilance with Electronic data Warehouse II (ECG-ViEW II) is a large, single-center database comprising numeric parameter data of the surface electrocardiograms of all patients who underwent testing from 1 June 1994 to 31 July 2013. The electrocardiographic data include the test date, clinical department, RR interval, PR interval, QRS duration, QT interval, QTc interval, P axis, QRS axis, and T axis. These data are connected with patient age, sex, ethnicity, comorbidities, age-adjusted Charlson comorbidity index, prescribed drugs, and electrolyte levels. This longitudinal observational database contains 979,273 electrocardiograms from 461,178 patients over a 19-year study period. This database can provide an opportunity to study electrocardiographic changes caused by medications, disease, or other demographic variables. ECG-ViEW II is freely available at http://www.ecgview.org. PMID:28437484

  13. A spectroscopic study of uranium(VI) interaction with magnetite

    International Nuclear Information System (INIS)

    El Aamrani, S.; Gimenez, J.; Rovira, M.; Seco, F.; Grive, M.; Bruno, J.; Duro, L.; Pablo, J. de

    2007-01-01

    The uranium sorbed onto commercial magnetite has been characterized by using two different spectroscopic techniques such as X-ray photoelectron spectroscopy (XPS), and extended X-ray absorption fine structure (EXAFS). Magnetite samples have been put in contact with uranium(VI) solutions in conditions in which a high uranium uptake is expected. After several days, the magnetite surface has been analysed by XPS and EXAFS. The XPS results obtained are not conclusive regarding the uranium oxidation state in the magnetite surface. On the other hand, the results obtained with the EXAFS technique show that the uranium-magnetite sample spectrum has characteristics from both the UO 2 and schoepite spectra, e.g. a relatively high coordination number of equatorial oxygens and two axial oxygens, respectively. These results would indicate that the uranium sorbed onto magnetite would be a mixture of uranium(IV) and uranium(VI)

  14. Complex formation between glutamic acid and molybdenum (VI)

    International Nuclear Information System (INIS)

    Gharib, Farrokh; Khorrami, S.A.; Sharifi, Sasan

    1997-01-01

    Equilibria of the reaction of molybdenum (VI) with L-glutamic acid have been studied in aqueous solution in the pH range 2.5 to 9.5, using spectrophotometric and optical rotation methods at constant ionic strength (0.15 mol dm -3 sodium perchlorate) and temperature 25 ± 0.1 degC. Our studies have shown that glutamic acid forms a mononuclear complex with Mo(VI) of the type MoO 3 L 2- at pH 5.5. The stability constant of this complexation and the dissociation constants of L-glutamic acid have been determined. (author). 17 refs., 2 figs., 4 tabs

  15. Charge separation sensitized by advanced II-VI semiconductor nanostructures

    Energy Technology Data Exchange (ETDEWEB)

    Kelley, David F. [Univ.of California, Merced, CA (United States)

    2017-04-11

    This proposal focuses on how the composition and morphology of pure and alloyed II-VI semiconductor heterostructures control their spectroscopic and dynamical properties. The proposed research will use a combination of synthesis development, electron microscopy, time-resolved electronic spectroscopy and modeling calculations to study these nanostructures. The proposed research will examine the extent to which morphology, compression due to lattice mismatch and alloy effects can be used to tune the electron and hole energies and the spectroscopic properties of II-VI heterojunctions. It will also use synthesis, optical spectroscopy and HRTEM to examine the role of lattice mismatch and hence lattice strain in producing interfacial defects, and the extent to which defect formation can be prevented by controlling the composition profile through the particles and across the interfaces. Finally, we will study the magnitude of the surface roughness in core/shell nanostructures and the role of shell thickness variability on the inhomogeneity of interfacial charge transfer rates.

  16. Hvad skal vi med Etisk Råd?

    DEFF Research Database (Denmark)

    Ploug, Thomas; Gjerris, Mickey

    2012-01-01

    Det Etiske Råd har for os at se en væsentlig rolle at spille i et åbent og demokratisk samfund som det danske. Vi skal være med til at skabe grobund for de værdidiskussioner, som skal forme fremtidens samfund. Etik er at være i dialog – ikke at kaste med mudder.......Det Etiske Råd har for os at se en væsentlig rolle at spille i et åbent og demokratisk samfund som det danske. Vi skal være med til at skabe grobund for de værdidiskussioner, som skal forme fremtidens samfund. Etik er at være i dialog – ikke at kaste med mudder....

  17. Uranium (Vi) sorption onto zirconium diphosphate chemically modified

    International Nuclear Information System (INIS)

    Garcia G, N.; Ordonez R, E.

    2010-10-01

    This work deals with the uranium (Vi) speciation after sorption onto zirconium diphosphate (ZrP 2 O 7 ) surface, hydrated and in a surface modified with organic acids. Oxalic and citric acids were chosen to modify the ZrP 2 O 7 surface because they have poly carboxylic groups and they mimic the organic matter in nature. Thus the interest of this work is to evaluate the uranium (Vi) sorption edge at different s ph values in natural and modified surfaces. The luminescence technique (fluorescence and phosphorescence, respectively) was used for the quantification and speciation of uranyl sorbed at the zirconium diphosphate interface. The fluorescence experiment, showed that adsorption of uranyl on surface of zirconium diphosphate tends to 100%. The speciation shows that there are different complexes in surface which were formed between zirconium diphosphate and uranyl, since it is produced a displacement of wavelength in fluorescence spectra of each system. (Author)

  18. Latest NASA Instrument Cost Model (NICM): Version VI

    Science.gov (United States)

    Mrozinski, Joe; Habib-Agahi, Hamid; Fox, George; Ball, Gary

    2014-01-01

    The NASA Instrument Cost Model, NICM, is a suite of tools which allow for probabilistic cost estimation of NASA's space-flight instruments at both the system and subsystem level. NICM also includes the ability to perform cost by analogy as well as joint confidence level (JCL) analysis. The latest version of NICM, Version VI, was released in Spring 2014. This paper will focus on the new features released with NICM VI, which include: 1) The NICM-E cost estimating relationship, which is applicable for instruments flying on Explorer-like class missions; 2) The new cluster analysis ability which, alongside the results of the parametric cost estimation for the user's instrument, also provides a visualization of the user's instrument's similarity to previously flown instruments; and 3) includes new cost estimating relationships for in-situ instruments.

  19. Biosorption of chromium (VI) from aqueous solutions and ANN modelling.

    Science.gov (United States)

    Nag, Soma; Mondal, Abhijit; Bar, Nirjhar; Das, Sudip Kumar

    2017-08-01

    The use of sustainable, green and biodegradable natural wastes for Cr(VI) detoxification from the contaminated wastewater is considered as a challenging issue. The present research is aimed to assess the effectiveness of seven different natural biomaterials, such as jackfruit leaf, mango leaf, onion peel, garlic peel, bamboo leaf, acid treated rubber leaf and coconut shell powder, for Cr(VI) eradication from aqueous solution by biosorption process. Characterizations were conducted using SEM, BET and FTIR spectroscopy. The effects of operating parameters, viz., pH, initial Cr(VI) ion concentration, adsorbent dosages, contact time and temperature on metal removal efficiency, were studied. The biosorption mechanism was described by the pseudo-second-order model and Langmuir isotherm model. The biosorption process was exothermic, spontaneous and chemical (except garlic peel) in nature. The sequence of adsorption capacity was mango leaf > jackfruit leaf > acid treated rubber leaf > onion peel > bamboo leaf > garlic peel > coconut shell with maximum Langmuir adsorption capacity of 35.7 mg g -1 for mango leaf. The treated effluent can be reused. Desorption study suggested effective reuse of the adsorbents up to three cycles, and safe disposal method of the used adsorbents suggested biodegradability and sustainability of the process by reapplication of the spent adsorbent and ultimately leading towards zero wastages. The performances of the adsorbents were verified with wastewater from electroplating industry. The scale-up study reported for industrial applications. ANN modelling using multilayer perception with gradient descent (GD) and Levenberg-Marquart (LM) algorithm had been successfully used for prediction of Cr(VI) removal efficiency. The study explores the undiscovered potential of the natural waste materials for sustainable existence of small and medium sector industries, especially in the third world countries by protecting the environment by eco-innovation.

  20. The new geographic information system in ETVA VI.PE.

    Science.gov (United States)

    Xagoraris, Zafiris; Soulis, George

    2016-08-01

    ETVA VI.PE. S.A. is a member of the Piraeus Bank Group of Companies and its activities include designing, developing, exploiting and managing Industrial Areas throughout Greece. Inside ETVA VI.PE.'s thirty-one Industrial Parks there are currently 2,500 manufacturing companies established, with 40,000 employees and € 2.5 billion of invested funds. In each one of the industrial areas ETVA VI.PE guarantees the companies industrial lots of land (sites) with propitious building codes and complete infrastructure networks of water supply, sewerage, paved roads, power supply, communications, cleansing services, etc. The development of Geographical Information System for ETVA VI.PE.'s Industrial Parks started at the beginning of 1992 and consists of three subsystems: Cadastre, that manages the information for the land acquisition of Industrial Areas; Street Layout - Sites, that manages the sites sold to manufacturing companies; Networks, that manages the infrastructure networks (roads, water supply, sewerage etc). The mapping of each Industrial Park is made incorporating state-of-the-art photogrammetric, cartographic and surveying methods and techniques. Passing through the phases of initial design (hybrid GIS) and system upgrade (integrated Gis solution with spatial database), the system is currently operating on a new upgrade (integrated gIS solution with spatial database) that includes redesigning and merging the system's database schemas, along with the creation of central security policies, and the development of a new web GIS application for advanced data entry, highly customisable and standard reports, and dynamic interactive maps. The new GIS bring the company to advanced levels of productivity and introduce the new era for decision making and business management.

  1. Uranyl(VI) luminescence spectroscopy at elevated temperatures

    Energy Technology Data Exchange (ETDEWEB)

    Steudtner, Robin; Franzen, Carola; Brendler, Vinzenz [Helmholtz-Zentrum Dresden-Rossendorf e.V., Dresden (Germany). Div. Surface Processes; Haubitz, Toni [Brandenburg Univ. of Technology, Cottbus-Senftenberg (Germany)

    2016-07-01

    We studied the influence of temperature and ionic strength on the luminescence characteristics (band position, decay time and intensity) of the free uranyl ion (UO{sub 2}{sup 2+}) in acidic aqueous solution. Under the chosen conditions an increasing temperature reduced both intensity and luminescence decay time of the UO{sub 2}{sup 2+} luminescence, but the individual U(VI) emission bands did not change.

  2. ENDF-201: ENDF/B-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    Rose, P.F. (comp.)

    1991-10-01

    Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on tapes.'' Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the tape'' number. These evaluations have been released without restrictions on their distribution or use.

  3. ENDF-201: ENDF/B-VI summary documentation

    Energy Technology Data Exchange (ETDEWEB)

    Rose, P.F. [comp.

    1991-10-01

    Responsibility for oversight of the ENDF/B Evaluated Nuclear Data file lies with the Cross Section Evaluation Working Group (CSEWG), which is comprised of representatives from various governmental and industrial laboratories in the United States. Individual evaluations are provided by scientists at several US laboratories, including significant contributions by scientists from all over the world. In addition, ENDF/B-VI includes for the first time complete evaluations for three materials that were provided from laboratories outside the US. All data are checked and reviewed by CSEWG, and the data file is maintained and issued by the National Nuclear Data Center at Brookhaven National Laboratory. The previous version of the library, ENDF/B-V, was issued in 1979, and two revisions to the data file were provided in subsequent years, the latest occurring in 1981. A total of 75 new or extensively modified neutron sublibrary evaluations are included in ENDF/B-VI, and are summarized in this document. One incident proton sublibrary is described for Fe{sup 56}. The remaining evaluations in ENDF/B-VI have been carried over from earlier versions of ENDF, and have been updated to reflect the new formats. The release of ENDF/B-VI was carried out between January and June of 1990, with groups of materials being released on ``tapes.`` Table 1 is an index to the evaluation summaries, and includes the material identification or MAT number, the responsible laboratory, and the ``tape`` number. These evaluations have been released without restrictions on their distribution or use.

  4. EXTRACTION DU Cr(VI PAR MEMBRANE POLYMERE A INCLUSION

    Directory of Open Access Journals (Sweden)

    O KEBICHE SENHADJI

    2008-06-01

    Le pH de la solution aqueuse constituant la phase source est un paramètre clé dans l’opération de transport du Cr(VI à travers les MPIs étudiées. Un pH de 1,2 est recommandé pour la réalisation de l’extraction dans les conditions optimales déterminées.

  5. Hvad forstår vi ved pragmatiske sprogvanskeligheder?

    DEFF Research Database (Denmark)

    Hansen, Helle Hallenberg; Christensen, Rikke Vang

    2017-01-01

    I artiklen formidles nogle af de opmærksomhedsområder, vi anser for vigtige i det logopædiske arbejde med børn med pragmatiske sprogvanskeligheder, blandt andet det store spænd i karakteristika og mulige problemer med anvendeligheden af en ny diagnostisk kategori, ”Developmental language disorder...... with impairment of mainly pragmatic language”, i ICD-1.1...

  6. Non-enzymatic U(VI) interactions with biogenic mackinawite

    Science.gov (United States)

    Veeramani, H.; Qafoku, N. P.; Kukkadapu, R. K.; Murayama, M.; Hochella, M. F.

    2011-12-01

    Reductive immobilization of hexavalent uranium [U(VI)] by stimulation of dissimilatory metal and/or sulfate reducing bacteria (DMRB or DSRB) has been extensively researched as a remediation strategy for subsurface U(VI) contamination. These bacteria derive energy by reducing oxidized metals as terminal electron acceptors, often utilizing organic substrates as electron donors. Thus, when evaluating the potential for in-situ uranium remediation in heterogeneous subsurface media, it is important to understand how the presence of alternative electron acceptors such as Fe(III) and sulfate affect U(VI) remediation and the long term behavior and reactivity of reduced uranium. Iron, an abundant subsurface element, represents a substantial sink for electrons from DMRB, and the reduction of Fe(III) leads to the formation of dissolved Fe(II) or to reactive biogenic Fe(II)- and mixed Fe(II)/Fe(III)- mineral phases. Consequently, abiotic U(VI) reduction by reactive forms of biogenic Fe(II) minerals could be a potentially important process for uranium immobilization. In our study, the DMRB Shewanella putrefaciens CN32 was used to synthesize a biogenic Fe(II)-bearing sulfide mineral: mackinawite, that has been characterized by XRD, SEM, HRTEM and Mössbauer spectroscopy. Batch experiments involving treated biogenic mackinawite and uranium (50:1 molar ratio) were carried out at room temperature under strict anoxic conditions. Following complete removal of uranium from solution, the biogenic mackinawite was analyzed by a suite of analytical techniques including XAS, HRTEM and Mössbauer spectroscopy to determine the speciation of uranium and investigate concomitant Fe(II)-phase transformation. Determining the speciation of uranium is critical to success of a remediation strategy. The present work elucidates non-enzymatic/abiotic molecular scale redox interactions between biogenic mackinawite and uranium.

  7. Deep desulfurization of diesel oil oxidized by Fe (VI) systems

    Energy Technology Data Exchange (ETDEWEB)

    Shuzhi Liu; Baohui Wang; Baochen Cui; Lanlan Sun [Daqing Petroleum Institute, Daqing (China). College of Chemistry and Chemical Engineering

    2008-03-15

    Fe (VI) compound, such as K{sub 2}FeO{sub 4}, is a powerful oxidizing agent. Its oxidative potential is higher than KMnO{sub 4}, O{sub 3} and Cl{sub 2}. Oxidation activity of Fe (VI) compounds can be adjusted by modifying their structure and pH value of media. The reduction of Fe (VI), differing from Cr and Mn, results in a relatively non-toxic by-product Fe (III) compounds, which suggests that Fe (VI) compound is an environmentally friendly oxidant. Oxidation of model sulfur compound and diesel oil by K{sub 2}FeO{sub 4} in water-phase, in organic acid and in the presence of phase-transfer catalysts is investigated, respectively. The results show that the activity of oxidation of benzothiophene (BT) and dibenzothiophene (DBT) is low in water-phase, even adding phase-transfer catalyst to the system, because K{sub 2}FeO{sub 4} reacts rapidly with water to form brown Fe(OH){sub 3} to lose ability of oxidation of organic sulfur compounds. The activity of oxidation of the BT and DBT increases markedly in acetic acid. Moreover, the addition of the solid catalyst to the acetic acid medium promotes very remarkably oxidation of organic sulfur compounds. Conversions of the DBT and BT are 98.4% and 70.1%, respectively, under the condition of room temperature, atmospheric pressure, acetic acid/oil (v/v) = 1.0, K{sub 2}FeO{sub 4}/S (mol/mol) = 1.0 and catalyst/K{sub 2}FeO{sub 4} (mol/mol) = 1.0. Under the same condition, diesel oil is oxidized, followed by furfural extraction, the results display sulfur removal rate is 96.7% and sulfur content in diesel oil reduces from 457 ppm to 15.1 ppm. 11 refs., 9 figs., 5 tabs.

  8. Precipitation of Np(VI) by urotropine from heated solutions

    International Nuclear Information System (INIS)

    Logvis, A.I.; Krot, N.N.

    1993-01-01

    The precipitate formed by heating HNO 3 solutions of Np(VI) and urotropine under various conditions is studied by x-ray phase analysis, gravimetry, and spectrophotometry. The precipitate is determined to be NpO 3 ·xH 2 O·yNH 3 , where x ≤ 2 and y ≤ 0.28. It is demonstrated that at least 12% of the starting Np remains in solution as Np(V)

  9. Voltammetry of Os(VI)-modified polysaccharides at carbon electrodes

    Czech Academy of Sciences Publication Activity Database

    Trefulka, Mojmír; Paleček, Emil

    2009-01-01

    Roč. 21, č. 15 (2009), s. 1763-1766 ISSN 1040-0397 R&D Projects: GA ČR(CZ) GA301/07/0490; GA MŠk(CZ) LC06035 Institutional research plan: CEZ:AV0Z50040507; CEZ:AV0Z50040702 Keywords : chemical modification of polysaccharides * Os(VI)L-polysaccharide adducts * pyrolytic graphite electrodes Subject RIV: BO - Biophysics Impact factor: 2.630, year: 2009

  10. Discrepancy by Design in Virg., Aen. VI 562-600

    Directory of Open Access Journals (Sweden)

    Clifford Weber

    2012-06-01

    Full Text Available As the context of Virg., Aen. VI 565 requires, the ancient interpretation of this line is correct, while the current consensus is mistaken. The Sibyl has never seen Tartarus. Subsequently, when she repeatedly asserts that she has witnessed the punishment of criminals confined in Tartarus, this blatant contradiction imitates the famously contradictory location of Odysseus outside Hades initially but later firmly within it.

  11. Structural and elastic properties of AIBIIIC 2 VI semiconductors

    Science.gov (United States)

    Kumar, V.; Singh, Bhanu P.

    2018-01-01

    The plane wave pseudo-potential method within density functional theory has been used to calculate the structural and elastic properties of AIBIIIC 2 VI semiconductors. The electronic band structure, density of states, lattice constants (a and c), internal parameter (u), tetragonal distortion (η), energy gap (Eg), and bond lengths of the A-C (dAC) and B-C (dBC) bonds in AIBIIIC 2 VI semiconductors have been calculated. The values of elastic constants (Cij), bulk modulus (B), shear modulus (G), Young's modulus (Y), Poisson's ratio (υ), Zener anisotropy factor (A), Debye temperature (ϴD) and G/B ratio have also been calculated. The values of all 15 parameters of CuTlS2 and CuTlSe2 compounds, and 8 parameters of 20 compounds of AIBIIIC 2 VI family, except AgInS2 and AgInSe2, have been calculated for the first time. Reasonably good agreement has been obtained between the calculated, reported and available experimental values.

  12. Sorption of Chromium (VI Using Excess Municipal Sludge

    Directory of Open Access Journals (Sweden)

    Farzaneh Mohammadi

    2014-04-01

    Full Text Available Removing or decreasing hexavalent Chromium from wastewater to the permitted levels is important due to its non-biodegradation, bioaccumulation, cancer-causing and toxic effects. In this study, biosorption of Cr(VI from aqueous solutions by Excess Active Municipal Sludge was investigated as a function of initial Chromium (VI concentration (in the range of 5-90 mg/l, initial pH (in the range of 2-8, agitation speed (in the range of 50-200 rpm, adsorbent dosage (in the range of 2-10 g/l and agitation time (in the range of 5-480 min in a batch system. The optimum conditions were found by full factorial design approach. The results showed that the equilibrium time for adsorbent is 120 minutes. Also, sorption data have a good fitness by Freundlich isotherm model and adsorption kinetic is adopted with pseudo-second order model. In batch studies, at optimum condition (90 mg/l initial concentration, pH 2, agitation speed 200 rpm and adsorbent dosage 4 g/l, the adsorption performance was about 96%; the maximum adsorption capacity was calculated about 41.69 mg of Cr/g of adsorbent. Overall, it can be concluded that Excess Active Municipal Sludge, has a good performance as a biological, biodegradable, abundant and low-cost adsorbent for the removal of Cr (VI from aqueous solutions.

  13. Implementation of MP_Lite for the VI Architecture

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Weiyi [Iowa State Univ., Ames, IA (United States)

    2001-01-01

    MP_Lite is a light weight message-passing library designed to deliver the maximum performance to applications in a portable and user friendly manner. The Virtual Interface (VI) architecture is a user-level communication protocol that bypasses the operating system to provide much better performance than traditional network architectures. By combining the high efficiency of MP_Lite and high performance of the VI architecture, they are able to implement a high performance message-passing library that has much lower latency and better throughput. The design and implementation of MP_Lite for M-VIA, which is a modular implementation of the VI architecture on Linux, is discussed in this thesis. By using the eager protocol for sending short messages, MP_Lite M-VIA has much lower latency on both Fast Ethernet and Gigabit Ethernet. The handshake protocol and RDMA mechanism provides double the throughput that MPICH can deliver for long messages. MP_Lite M-VIA also has the ability to channel-bonding multiple network interface cards to increase the potential bandwidth between nodes. Using multiple Fast Ethernet cards can double or even triple the maximum throughput without increasing the cost of a PC cluster greatly.

  14. vi-Strauss, Caduveo Body Painting and the Readymade

    DEFF Research Database (Denmark)

    Wiseman, Boris Nicholas Daniel

    2008-01-01

    The aim of this article is to explore some convergences between aesthetics and the anthropology of art, two disciplines often thought of as incompatible or mutually exclusive. Its impetus is the conviction that we have much to gain by a more systematic and concerted attempt at constituting an eth...... that is implicit in Lévi-Strauss's works but not articulated as such, is a boundary marking processes, one that is central to the way in which we create an order of the world around us.......-aesthetics, i.e. a decentred aesthetics enriched by the dynamic of cross-cultural comparison. I will take as my starting point Lévi-Strauss's classic studies of Caduveo body painting and try to show how, beyond the clichés often repeated about structuralism, they provide valuable insights for an understanding...... will argue here that Lévi-Strauss's own theorisation of the relations between nature, culture and art enables us to see them, in at least one of their dimensions, as prime examples of the fulfilling of the mytho-poetic function. What I will place, here, at the core of mytho-poetic function, following a view...

  15. Monolayer II-VI semiconductors: A first-principles prediction

    Science.gov (United States)

    Zheng, Hui; Chen, Nian-Ke; Zhang, S. B.; Li, Xian-Bin

    A systematic study of 32 honeycomb monolayer II-VI semiconductors is carried out by first-principles methods. It appears that BeO, MgO, CaO, ZnO, CdO, CaS, SrS, SrSe, BaTe, and HgTe honeycomb monolayers have a good dynamic stability which is revealed by phonon calculations. In addition, from the molecular dynamic (MD) simulation of other unstable candidates, we also find two extra monolayers dynamically stable, which are tetragonal BaS and orthorhombic HgS. The honeycomb monolayers exist in form of either a planar perfect honeycomb or a low-buckled 2D layer, all of which possess a band gap and most of them are in the ultraviolet region. Interestingly, the dynamically stable SrSe has a gap near visible light, and displays exotic electronic properties with a flat top of the valence band, and hence has a strong spin polarization upon hole doping. The honeycomb HgTe has been reported to achieve a topological nontrivial phase under appropriate in-plane tensile strain and spin-orbital coupling (SOC). Some II-VI partners with less than 5% lattice mismatch may be used to design novel 2D heterojunction devices. If synthesized, potential applications of these 2D II-VI families could include optoelectronics, spintronics, and strong correlated electronics. Distinguished Student (DS) Program of APS FIP travel funds.

  16. Uranium(VI) transport modeling: geochemical data and submodels

    International Nuclear Information System (INIS)

    Tripathi, V.S.

    1984-01-01

    Understanding the geochemical mobility of U(VI) and modeling its transport is important in several contexts including ore genesis, uranium exploration, nuclear and mill-tailings waste management, and solution mining of uranium ores. Adsorption is a major control on partitioning of solutes at the mineral/solution interface. The effect of carbonate, fluoride, and phosphate complexing on adsorption of uranium was investigated. A critical compilation of stability constants of inorganic complexes and solid compounds of U(VI) necessary for proper design of experiment and for modeling transport of uranium was prepared. The general features of U(VI) adsorption in ligand-free systems are similar to those characteristic of other hydrolyzable metal ions. The adsorption processes studied were found to be reversible. The adsorption model developed in ligand-free systems, when solution complexing is taken into account, proved remarkably successful in describing adsorption of uranium in the presence of carbonate and fluoride. The presence of phosphate caused a much smaller decrease in the extent of adsorption than expected; however, a critical reassessment of the stability of UO 2 2+ .HPO 4 2- complexes, showed that phosphato complexes, if any, are extremely weak under experimental conditions. Removal of uranium may have occurred due to precipitation of sodium uranyl phosphates in addition to adsorption

  17. Group ib organometallic chemistry. XXXIV. Thermal behaviour and chemical reactivity of tetranuclear Me2N-substituted diarypropenylcopper-copper anion (Vi2Cu4X2) and mixed diarylpropenyl/organocopper (Vi2Cu4R2) compounds

    NARCIS (Netherlands)

    Hoedt, R.W.M. ten; Koten, G. van; Noltes, J.G.

    1980-01-01

    Thermal decomposition of configurationally pure 1,2-diarylpropenylcopper compounds Z-Vi2CU4Br2 and Z-Vi2Cu4R2 [Vi = (2-Me2NC6H4)C=C(Me)-(C6H4Me-4), R = 2-Me2NC6H4 or 4-MeC6H4CC] predominantly results in the formation of ViH. In contrast, only dimers (ViVi) were formed on thermolysis of (Z-ViCu2OTf)η

  18. Analytical applications of N-phenyl-n-butyro hydroxamic and N-p-tolyl-n-butyro hydroxamic acids towards chromium (VI), copper (II), iron (III) and uranium (VI)

    International Nuclear Information System (INIS)

    Elkhadir, A. Y. F.

    2001-05-01

    Two aliphatic hydroxamic acids were prepared; N-phenyl-n-butyro hydroxamic acid and N-p-tolyl-n-butyro hydroxamic acid, by the reaction of β-phenylhydroxylamine and p-tolyl hydroxylamine with n-butyryl chloride. The acids were identified by: their melting points, characteristic reactions with acidic solutions of vanadium (V) and iron (III), infrared spectroscopy, nitrogen content and molecular weight determination. The extractability of these acids towards Cr (VI), Cu (II), Fe (III) and U (VI) were investigated at different pH values and molar acid concentrations. N-phenyl-n- butyro hydroxamic acid has a maximum extraction (98.80%) for Cr (VI) at 4 M H 2 SO 4 , (83.25%) for Cu (II) at pH 6, (99.17%) for Fe (III) at pH 5 and (99.76%) at 4 M HNO 3 for U (VI) respectively. N-p-tolyl-n-butyro hydroxamic acid has a maximum extraction (98.40%) for Cr (VI)at 4 M H 2 SO 4 , (81.30%) for Cu (II) at pH 6, (92.80%) for Fe (III) at pH 5 and (99.64%) for U (VI) at 4 M HNO 3 , respectively. The ratios of the metal to ligands were determined by job method (continuous variation method) and were found to be 1:2 for Cr (VI) and U (VI). (Author)

  19. Analytical applications of N-phenyl-n-butyro hydroxamic and N-p-tolyl-n-butyro hydroxamic acids towards chromium (VI), copper (II), iron (III) and uranium (VI)

    Energy Technology Data Exchange (ETDEWEB)

    Elkhadir, A Y. F. [Department of Chemistry, Faculty of Science, University of Khartoum, Khartoum (Sudan)

    2001-05-01

    Two aliphatic hydroxamic acids were prepared; N-phenyl-n-butyro hydroxamic acid and N-p-tolyl-n-butyro hydroxamic acid, by the reaction of {beta}-phenylhydroxylamine and p-tolyl hydroxylamine with n-butyryl chloride. The acids were identified by: their melting points, characteristic reactions with acidic solutions of vanadium (V) and iron (III), infrared spectroscopy, nitrogen content and molecular weight determination. The extractability of these acids towards Cr (VI), Cu (II), Fe (III) and U (VI) were investigated at different pH values and molar acid concentrations. N-phenyl-n- butyro hydroxamic acid has a maximum extraction (98.80%) for Cr (VI) at 4 M H{sub 2}SO{sub 4}, (83.25%) for Cu (II) at pH 6, (99.17%) for Fe (III) at pH 5 and (99.76%) at 4 M HNO{sub 3} for U (VI) respectively. N-p-tolyl-n-butyro hydroxamic acid has a maximum extraction (98.40%) for Cr (VI)at 4 M H{sub 2} SO{sub 4}, (81.30%) for Cu (II) at pH 6, (92.80%) for Fe (III) at pH 5 and (99.64%) for U (VI) at 4 M HNO{sub 3}, respectively. The ratios of the metal to ligands were determined by job method (continuous variation method) and were found to be 1:2 for Cr (VI) and U (VI). (Author)

  20. Cr (VI) remediation by indigenous bacteria in soils contaminated by chromium-containing slag

    International Nuclear Information System (INIS)

    Chai Liyuan; Huang Shunhong; Yang Zhihui; Peng Bing; Huang Yan; Chen Yuehui

    2009-01-01

    Hexavalent chromium (Cr) is a toxic element causing serious environmental threat. Recently, more and more attention is paid to the bio-remediation of Cr (VI) in the contaminated soils. Cr (VI) remediation by indigenous bacteria in soils contaminated by chromium-containing slag at a steel-alloy factory in Hunan Province, China, was investigated in the present study. The results showed that when sufficient nutrients were amended into the contaminated soils, total Cr (VI) concentration declined from the initial value of 462.8 to 10 mg kg -1 at 10 days and the removal rate was 97.8%. Water soluble Cr (VI) decreased from the initial concentration of 383.8 to 1.7 mg kg -1 . Exchangeable Cr (VI) and carbonates-bound Cr (VI) were removed by 92.6% and 82.4%, respectively. Meanwhile, four Cr (VI) resistant bacterial strains were isolated from the soil under the chromium-containing slag. Only one strain showed a high ability for Cr (VI) reduction in liquid culture. This strain was identified as Pannonibacter phragmitetus sp. by gene sequencing of 16S rRNA. X-ray photoelectron spectroscope (XPS) analysis indicated that Cr (VI) was reduced into trivalent chromium. The results suggest that indigenous bacterial strains have potential application for Cr (VI) remediation in the soils contaminated by chromium-containing slag.

  1. Characterization of U(VI)-carbonato ternary complexes on hematite: EXAFS and electrophoretic mobility measurements

    Science.gov (United States)

    Bargar, John R.; Reitmeyer, Rebecca; Lenhart, John J.; Davis, James A.

    2000-01-01

    We have measured U(VI) adsorption on hematite using EXAFS spectroscopy and electrophoresis under conditions relevant to surface waters and aquifers (0.01 to 10 μM dissolved uranium concentrations, in equilibrium with air, pH 4.5 to 8.5). Both techniques suggest the existence of anionic U(VI)-carbonato ternary complexes. Fits to EXAFS spectra indicate that U(VI) is simultaneously coordinated to surface FeO6 octahedra and carbonate (or bicarbonate) ligands in bidentate fashions, leading to the conclusion that the ternary complexes have an inner-sphere metal bridging (hematite-U(VI)-carbonato) structure. Greater than or equal to 50% of adsorbed U(VI) was comprised of monomeric hematite-U(VI)-carbonato ternary complexes, even at pH 4.5. Multimeric U(VI) species were observed at pH ≥ 6.5 and aqueous U(VI) concentrations approximately an order of magnitude more dilute than the solubility of crystalline β-UO2(OH)2. Based on structural constraints, these complexes were interpreted as dimeric hematite-U(VI)-carbonato ternary complexes. These results suggest that Fe-oxide-U(VI)-carbonato complexes are likely to be important transport-limiting species in oxic aquifers throughout a wide range of pH values.

  2. CoQ10 Deficiency May Indicate Mitochondrial Dysfunction in Cr(VI Toxicity

    Directory of Open Access Journals (Sweden)

    Xiali Zhong

    2017-04-01

    Full Text Available To investigate the toxic mechanism of hexavalent chromium Cr(VI and search for an antidote for Cr(VI-induced cytotoxicity, a study of mitochondrial dysfunction induced by Cr(VI and cell survival by recovering mitochondrial function was performed. In the present study, we found that the gene expression of electron transfer flavoprotein dehydrogenase (ETFDH was strongly downregulated by Cr(VI exposure. The levels of coenzyme 10 (CoQ10 and mitochondrial biogenesis presented by mitochondrial mass and mitochondrial DNA copy number were also significantly reduced after Cr(VI exposure. The subsequent, Cr(VI-induced mitochondrial damage and apoptosis were characterized by reactive oxygen species (ROS accumulation, caspase-3 and caspase-9 activation, decreased superoxide dismutase (SOD and ATP production, increased methane dicarboxylic aldehyde (MDA content, mitochondrial membrane depolarization and mitochondrial permeability transition pore (MPTP opening, increased Ca2+ levels, Cyt c release, decreased Bcl-2 expression, and significantly elevated Bax expression. The Cr(VI-induced deleterious changes were attenuated by pretreatment with CoQ10 in L-02 hepatocytes. These data suggest that Cr(VI induces CoQ10 deficiency in L-02 hepatocytes, indicating that this deficiency may be a biomarker of mitochondrial dysfunction in Cr(VI poisoning and that exogenous administration of CoQ10 may restore mitochondrial function and protect the liver from Cr(VI exposure.

  3. Impact of water quality parameters on the sorption of U(VI) onto hematite

    International Nuclear Information System (INIS)

    Zhao Donglin; Wang Xianbiao; Yang Shitong; Guo Zhiqiang; Sheng Guodong

    2012-01-01

    In this study, the sorption of U(VI) from aqueous solution on hematite was studied as a function of various water quality parameters such as contact time, pH, ionic strength, soil humic acid (HA) or fulvic acid (FA), solid content and temperature by using a batch technique. The results demonstrated that the sorption of U(VI) was strongly dependent on ionic strength at pH 6.0 and the sorption was mainly dominated by inner-sphere surface complexation. The presence of HA/FA increases U(VI) sorption at low pH, whereas decreases U(VI) sorption at high pH. The thermodynamic parameters (ΔH 0 , ΔS 0 , and ΔG 0 ) were calculated from the temperature dependent sorption isotherms, and the results suggested that U(VI) sorption was a spontaneous and endothermic process. The results might be important for the application of hematite in U(VI) pollution management. Highlights: ► The sorption of U(VI) was strongly dependent on ionic strength at pH 6.0. ► A positive effect of HA/FA on U(VI) sorption was found at low pH, whereas a negative effect was observed at high pH. ► U(VI) sorption was a spontaneous and endothermic process. ► The results are quite important for the application of hematite in U(VI) pollution management.

  4. CHROMIUM(VI REDUCTION BY A MIXED CULTURE OF SULFATE REDUCING BACTERIA DEVELOPED IN COLUMN REACTOR

    Directory of Open Access Journals (Sweden)

    Cynthia Henny

    2008-03-01

    Full Text Available A lactate enriched mixed sulfate reducing bacteria (SRB culture was examined for the reduction of Cr(VI in a continuous flow system. The influent was mineral salts media added with lactate and sulfate with amounts of 8 and 6 mM respectively as electron donor and electron acceptor. The SRB culture was allowed to stabilize in the column before adding the Cr(VI to the influent. Chromium and sulfate reduction and lactate oxidation were examined by measuring the concentrations of Cr(Vl, sulfate and lactate in the influent and the effluent over time. The experiment was discontinued when Cr(VI concentration in the effiuent was breakthrough. In the absence of Cr(VI, sulfate was not completely reduced in the column, although lactate was completely oxidized and acetate as an intermediate product was not often detected. Almost all of Cr(VI loaded was reduced in the column seeded with the SRB culture at influent Cr(VI concentrations of 192,385 and769 mM. There was no significant Cr(VI loss in the control column, indicating that Cr(VI removal was due to the reduction of Cr(VI to Cr (lll by the SRB culture. The instantaneous Cr(VI removal decreased to a minimum of 32%, 24 days after the influent Cr(VI concentration was increased to 1540 mM, ancl sulfate removal efficiency decreased to a minimum of 17%. The SRB population in the column decreased 100 days after C(VI was added to the column. The total mass of Cr(VI reduced was approximately 878 mmol out of 881 mmol of Cr(Vl loaded in 116 days. The results clearly show that our developed SRB culture could reduced Cr(Vl considerably.

  5. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Chang [College of Environmental Science and Engineering, Anhui Normal University, South Jiuhua Road, 189, 241002 Wuhu (China); Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Fiol, Núria [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Villaescusa, Isabel, E-mail: Isabel.Villaescusa@udg.edu [Chemical Engineering Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain); Poch, Jordi [Applied Mathematics Department, Escola Politècnica Superior, Universitat de Girona, Ma Aurèlia Capmany, 61, 17071 Girona (Spain)

    2016-01-15

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data.

  6. New approach in modeling Cr(VI) sorption onto biomass from metal binary mixtures solutions

    International Nuclear Information System (INIS)

    Liu, Chang; Fiol, Núria; Villaescusa, Isabel; Poch, Jordi

    2016-01-01

    In the last decades Cr(VI) sorption equilibrium and kinetic studies have been carried out using several types of biomasses. However there are few researchers that consider all the simultaneous processes that take place during Cr(VI) sorption (i.e., sorption/reduction of Cr(VI) and simultaneous formation and binding of reduced Cr(III)) when formulating a model that describes the overall sorption process. On the other hand Cr(VI) scarcely exists alone in wastewaters, it is usually found in mixtures with divalent metals. Therefore, the simultaneous removal of Cr(VI) and divalent metals in binary mixtures and the interactive mechanism governing Cr(VI) elimination have gained more and more attention. In the present work, kinetics of Cr(VI) sorption onto exhausted coffee from Cr(VI)–Cu(II) binary mixtures has been studied in a stirred batch reactor. A model including Cr(VI) sorption and reduction, Cr(III) sorption and the effect of the presence of Cu(II) in these processes has been developed and validated. This study constitutes an important advance in modeling Cr(VI) sorption kinetics especially when chromium sorption is in part based on the sorbent capacity of reducing hexavalent chromium and a metal cation is present in the binary mixture. - Highlights: • A kinetic model including Cr(VI) reduction, Cr(VI) and Cr(III) sorption/desorption • Synergistic effect of Cu(II) on Cr(VI) elimination included in the model • Model validation by checking it against independent sets of data

  7. Reduction of ferrate(VI) and oxidation of cyanate in a Fe(VI)-TiO2-UV-NCO- system.

    Science.gov (United States)

    Winkelmann, Kurt; Sharma, Virender K; Lin, Yekaterina; Shreve, Katherine A; Winkelmann, Catherine; Hoisington, Laura J; Yngard, Ria A

    2008-08-01

    The aqueous photocatalytic degradation of cyanate (NCO(-)), which is a long-lived neurotoxin formed during the remediation of cyanide in industrial waste streams, was studied in the ferrate(VI)-UV-TiO2-NCO(-) system. Kinetics measurements of the photocatalytic reduction of ferrate(VI) were carried out as a function of [NCO(-)], [ferrate(VI)], [O(2)], light intensity (I(o)), and amount of TiO2 in suspensions at pH 9.0. The photocatalytic reduction rate of ferrate(VI) in the studied system can be expressed as -d[Fe(VI)]/dt=kI(o)(0.5) [NCO(-)] [TiO2]. The rate of photocatalytic oxidation of cyanate with ferrate(VI) was greater than the rate in the analogous system without ferrate(VI). The possibility of involvement of reactive ferrate(V) species for this enhancement was determined by studying the reactivity of ferrate(V) with NCO(-) in a homogeneous solution using a premix pulse radiolysis technique. The rate constant for the reaction of ferrate(V) and NCO(-) in alkaline medium was estimated to be (9.60+/-0.07) x 10(2) M(-1) s(-1), which is much slower than the ferrate(VI) self-decomposition reaction (k approximately 10(7) M(-1) s(-1)). An analysis of the kinetic data in the Fe(VI)-UV-TiO2-NCO(-) system suggests that ferrate(V) is not directly participating in the oxidation of cyanate. Possible reactions in the system are presented to explain results of ferrate(VI) reduction and oxidation of cyanate.

  8. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: A potential source of geogenic Cr(VI) to groundwater

    International Nuclear Information System (INIS)

    Mills, Christopher T.; Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J.

    2011-01-01

    Highlights: → Southern Sacramento Valley soil and sediment has abundant naturally-occurring Cr(III). → Cr(III) resides mainly in chromite but some is associated with clays and Fe oxides. → Cr(VI) is mostly absent in surface soil but ubiquitous in deeper soil and sediment. → Cr(VI) increased linearly with time during lab soil incubations with no additions. → Cation exchange processes resulted in greater Cr(VI) generation rates. - Abstract: Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization's maximum contaminant level for drinking water (50 μg L -1 ) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 μg L -1 . To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to ∼1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged from 0 to 42

  9. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: A potential source of geogenic Cr(VI) to groundwater

    Energy Technology Data Exchange (ETDEWEB)

    Mills, Christopher T., E-mail: cmills@usgs.gov [United States Geological Survey, Crustal Geophysics and Geochemistry Science Center, Denver Federal Center, MS 964D, Denver, CO 80225 (United States); Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J. [United States Geological Survey, Crustal Geophysics and Geochemistry Science Center, Denver Federal Center, MS 964D, Denver, CO 80225 (United States)

    2011-08-15

    Highlights: > Southern Sacramento Valley soil and sediment has abundant naturally-occurring Cr(III). > Cr(III) resides mainly in chromite but some is associated with clays and Fe oxides. > Cr(VI) is mostly absent in surface soil but ubiquitous in deeper soil and sediment. > Cr(VI) increased linearly with time during lab soil incubations with no additions. > Cation exchange processes resulted in greater Cr(VI) generation rates. - Abstract: Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization's maximum contaminant level for drinking water (50 {mu}g L{sup -1}) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 {mu}g L{sup -1}. To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to {approx}1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged

  10. Importance of c-Type cytochromes for U(VI reduction by Geobacter sulfurreducens

    Directory of Open Access Journals (Sweden)

    Leang Ching

    2007-03-01

    Full Text Available Abstract Background In order to study the mechanism of U(VI reduction, the effect of deleting c-type cytochrome genes on the capacity of Geobacter sulfurreducens to reduce U(VI with acetate serving as the electron donor was investigated. Results The ability of several c-type cytochrome deficient mutants to reduce U(VI was lower than that of the wild type strain. Elimination of two confirmed outer membrane cytochromes and two putative outer membrane cytochromes significantly decreased (ca. 50–60% the ability of G. sulfurreducens to reduce U(VI. Involvement in U(VI reduction did not appear to be a general property of outer membrane cytochromes, as elimination of two other confirmed outer membrane cytochromes, OmcB and OmcC, had very little impact on U(VI reduction. Among the periplasmic cytochromes, only MacA, proposed to transfer electrons from the inner membrane to the periplasm, appeared to play a significant role in U(VI reduction. A subpopulation of both wild type and U(VI reduction-impaired cells, 24–30%, accumulated amorphous uranium in the periplasm. Comparison of uranium-accumulating cells demonstrated a similar amount of periplasmic uranium accumulation in U(VI reduction-impaired and wild type G. sulfurreducens. Assessment of the ability of the various suspensions to reduce Fe(III revealed no correlation between the impact of cytochrome deletion on U(VI reduction and reduction of Fe(III hydroxide and chelated Fe(III. Conclusion This study indicates that c-type cytochromes are involved in U(VI reduction by Geobacter sulfurreducens. The data provide new evidence for extracellular uranium reduction by G. sulfurreducens but do not rule out the possibility of periplasmic uranium reduction. Occurrence of U(VI reduction at the cell surface is supported by the significant impact of elimination of outer membrane cytochromes on U(VI reduction and the lack of correlation between periplasmic uranium accumulation and the capacity for uranium

  11. Am(VI) Extraction Final Report: FY16

    Energy Technology Data Exchange (ETDEWEB)

    Mincher, Bruce Jay [Idaho National Lab. (INL), Idaho Falls, ID (United States); Grimes, Travis Shane [Idaho National Lab. (INL), Idaho Falls, ID (United States); Tillotson, Richard Dean [Idaho National Lab. (INL), Idaho Falls, ID (United States); Law, Jack Douglas [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2016-08-01

    This report summarizes activities related to hexavalent Am extraction for FY16, in completion of FCR&D Milestone M3FT-16IN030103027. Activities concentrated on three areas of research: 1) centrifugal contactor hot testing, 2) Am(VI) stability studies, and 3) alternative oxidant studies. A brief summary of each task follows. Hot Testing: A new engineering-scale oxidation and solvent extraction test bed was built at Idaho National Laboratory to allow for solvent extraction testing of minor actinide separation concepts. The test bed consists of an oxidation vessel, filtration apparatus, four, 3D printed, 2-cm diameter centrifugal contactors, feed/product vessels, and sample ports. This system replaced the previous 3 stage, 5-cm contactor test bed that was used for the initial testing in FY14. In the FY16 hot test, a feed simulant was spiked with 243Am and 139Ce and treated with 60 g/L sodium bismuthate for two hours to oxidize the Am(III) to Am(VI). This solution was then pumped through a filter and into the four-stage centrifugal contactor setup. The organic phase solvent formulation was 1 M diethylhexylbutyramide (DEHBA)/dodecane. The test showed that Am(VI) was produced by bismuthate oxidation and the residual oxidant was successfully filtered without back pressure buildup. Sixty-four percent of Am was extracted in the contactors using DEHBA. Both Am and Ce were quantitatively stripped by 0.1 M H2O2. Successful demonstration of the utility of small, printable contactors suggests that hot testing of separations concepts can now be conducted more often, since it is cheaper, generates less waste, and entails much less radcon risk than previous testing. Am(VI) stability: A rigorous examination of reagents was conducted to determine if contaminants could interfere with Am oxidation and extraction. An series of DAm measurements showed that bismuthate particle size, water source, acid quality, and DAAP batch or pre-treatment had little effect on extraction efficiency

  12. Summary of the planning, management, and evaluation process for the Geothermal Program Review VI conference

    Energy Technology Data Exchange (ETDEWEB)

    1988-10-01

    The purpose of this document is to present an overview of the planning, facilitation, and evaluation process used to conduct the Geothermal Program Review VI (PR VI) conference. This document was also prepared to highlight lessons learned from PR VI and, by utilizing the evaluation summaries and recommendations, be used as a planning tool for PR VII. The conference, entitled Beyond Goals and Objectives,'' was sponsored by the US Department of Energy's (DOE) Geothermal Technology Division (GTD), PR VI was held in San Francisco, California on April 19--21, 1988 and was attended by 127 participants. PR VI was held in conjunction with the National Geothermal Association's (NGA) Industry Round Table. This document presents a brief summary of the activities, responsibilities, and resources for implementing the PR VI meeting and provides recommendations, checklists, and a proposed schedule for assisting in planning PR VII.

  13. An experimental study on the sorption of U(VI) onto granite

    International Nuclear Information System (INIS)

    Baik, Min Hoon; Hahn, Pil Soo

    2002-01-01

    The sorption of U(VI) on a domestic granite is studied as a function of experimental conditions such as contact time, solution-solid ratio, ionic strength, and pH using a batch procedure. The distribution coefficients, K d 's, of U(VI) are about 1-100mL/g depending on the experimental conditions. The sorption of U(VI) onto granite particles is greatly dependent upon the contact time, solution-solid ratio, and pH, but very little is dependent on the ionic strength. It is noticed that an U(VI)-carbonato ternary surface complex can be formed in the neutral range of pH. In the alkaline range of pH above 7, U(VI) sorption onto granite particles is greatly decreased due to the formation of anionic U(VI)-carbonato aqueous complexes

  14. Reduction of Cr(VI) in aqueous solution with DC diaphragm glow discharge

    International Nuclear Information System (INIS)

    Wang, Xiaoyan; Jin, Xinglong; Zhou, Minghua; Chen, Zhenhai; Deng, Kai

    2013-01-01

    This paper investigated the reduction of Cr(VI) in aqueous solution with direct current diaphragm glow discharge (DGD). The glow discharge sustained around the hole on a quartz tube which divided the electrolyte cell into two parts. The reduction efficiencies of Cr(VI) under different applied voltages, initial conductivities, hole diameters, hole numbers, initial pH values and initial concentrations were systematically studied. The results showed that the reduction efficiency of Cr(VI) increased with the increase of applied voltage, initial conductivity, hole diameter and hole number. The different initial pH values showed less effects on the reduction of Cr(VI). The reduction efficiency decreased with the increasing initial concentration. In addition, the simultaneous reduction of Cr(VI) and decolorization of acid orange (AO) with DGD were also fulfilled. Furthermore, the energy efficiency for Cr(VI) reduction with DGD was calculated and compared with those in photocatalysis and other glow discharge reactor

  15. Modification of zirconium diphosphate with salicylic acid and its effect on the uranium (Vi) sorption

    International Nuclear Information System (INIS)

    Almazan T, M. G.; Garcia G, N.; Simoni, E.

    2014-10-01

    The surface of zirconium diphosphate (ZrP 2 O 7 ) was modified with salicylic acid and its effect was evaluated on the uranium (Vi) sorption. The modified surface of the material was analyzed with different analytical techniques among which are included the atomic force microscopy, scanning electron microscopy and X-ray photoelectron spectroscopy. This analysis allowed showing that the salicylic acid is being held on the surface of the zirconium diphosphate. The reactivity of modified zirconium diphosphate compared with uranium (Vi) was investigated using the classical method of batch sorption. The analysis of sorption isotherms shows that the salicylic acid has an important effect in the uranium (Vi) sorption. According to the study conducted, the interaction among the uranium (Vi) and the surface of zirconium diphosphate modified with the salicylic acid most likely leads to the complexes formation of binary (U(Vi)/ZrP 2 O 7 ) and ternary (U(Vi)/salicylate/ZrP 2 O 7 ) surface. (Author)

  16. Social Set Visualizer (SoSeVi) II

    DEFF Research Database (Denmark)

    Flesch, Benjamin; Vatrapu, Ravi; Mukkamala, Raghava Rao

    2016-01-01

    SeVi). The development of the dashboard involved cutting-edge open source visual analytics libraries (D3.js) and creation of new visualizations such as visualizations of actor mobility across time and space, conversational comets, and more. Evaluation of the dashboard consisted of technical testing, usability testing......Current state-of-the-art in big social data analytics is largely limited to graph theoretical approaches such as social network analysis (SNA) informed by the social philosophical approach of relational sociology. This paper proposes and illustrates an alternate holistic approach to big social data...

  17. Radiographically visualized skeletal changes associated with mucopolysaccharidosis VI in cats

    International Nuclear Information System (INIS)

    Konde, L.J.; Thrall, M.A.; Gasper, P.; Dial, S.M.; McBiles, K.; Colgan, S.; Haskins, M.

    1987-01-01

    The radiographic skeletal form and structure of all cats with mucopolysaccharidosis VI is described. Common manifestations included epiphyseal dysplasia, generalized osteoporosis, abnormal nasal turbinate development, his subluxation, impaired development of skeletal growth, pectus excavatum, hyoid hypoplasia, aplasia, hypoplasia and fragmentation or abnormal ossification of the dens, and aplasia or hypoplasia of frontal and sphenoid sinuses. The skeletal measurements of two affected cats were compared with those of normal, sex-matched littermates, and the measurements of two affected female cats were compared with those of a normal male littermate

  18. Le tumulus Apatesaro VI (Compte-rendu de fouilles 1990.

    Directory of Open Access Journals (Sweden)

    Jacques Blot

    1992-01-01

    Full Text Available El túmulo pedregoso de Apatesaro VI, excavado en 1990, mide 7 metros de diámetro y 0.20 metros de altura. Este amontonamiento de piedras presenta cierta organización : distribución de bloques   del túmulo en 3 zonas según sus dimensiones ; cista central con depósito de carbones de leña, pero sin ajuar. La fecha : 1267-1005 av. J.C., perteneciente por tanto al Bronce final, hace de este monumento uno de los más antiguos de esta necrópolis.

  19. Ion-exchanger ultraviolet spectrophotometry for uranium(VI)

    International Nuclear Information System (INIS)

    Waki, H.; Korkisch, J.

    1983-01-01

    A sensitive method based on solid-phase spectrophotometry has been developed for the microdetermination of uranium(VI) in water samples. Uranium is sorbed on the anion-exchanger QAE-Sephadex from thiocyanate solution and the absorbance of the exchanger is measured at 300 nm. This method is about 30 times more sensitive than solution spectrophotometry. Absorption spectra of various metals in the anion-exchanger phase are presented and their interferences discussed. A procedure for the cation-exchange separation of uranium from accompanying elements before spectral measurement of uranium is proposed. (author)

  20. Mixed-ligand complexes of dioxouranium(VI)

    International Nuclear Information System (INIS)

    Ahuja, Renu; Dwivedi, K.

    1995-01-01

    A number of mixed ligand complexes of UO 2 2+ ion have been studied with aminopolycarboxylic acids, such as ethylenediaminetetraacetic acid with coordination number (CN) = 6, nitrilotriacetic acid with CN = 4 and iminodiacetic acid with CN = 3. Ethyleneglycol-bis-2-aminoethylether tetraacetic acid (EGTA) is an octadentate aminopolycarboxylic acid and forms stable binary complexes with many metal ions at low pH. In this paper the results obtained for the study of 1:1:1 UO 2 VI -EGTA-aspartic acid/glutamic acid systems are studied. (author). 7 refs., 1 fig., 1 tab

  1. The ENDF/B-VI photon interaction library

    International Nuclear Information System (INIS)

    Cullen, D.E.; Perkins, S.T.; Plechaty, E.F.

    1992-02-01

    The ENDF/B-VI photon interaction library includes data to describe the interaction of photons with the elements Z = 1 to 100 over the energy range 10 eV to 100 MeV. This library has been designed to meet the traditional needs of users to model the interaction and transport of primary photons. However, this library contains additional information which used in a combination with our other data libraries can be used to perform much more detailed calculations, e.g., emission of secondary fluorescence photons. This paper describes both traditional and more detailed uses of this library

  2. Evaluated nuclear data file ENDF/B-VI

    International Nuclear Information System (INIS)

    Dunford, C.L.

    1991-01-01

    For the past 25 years, the United States Department of Energy has sponsored a cooperative program among its laboratories, contractors and university research programs to produce an evaluated nuclear data library which would be application independent and universally accepted. The product of this cooperative activity is the ENDF/B evaluated nuclear data file. After approximately eight years of development, a new version of the data file, ENDF/B-VI has been released. The essential features of this evaluated data library are described in this paper. 7 refs

  3. Irradiation capsules VISA-2a-f, chapter VI

    International Nuclear Information System (INIS)

    Pavicevic, M.

    1962-01-01

    Irradiation capsules VISA-2a, b,c,d, and e were constructed in Saclay according to the drawings from Vinca and according to the demand of the experimentators. This chapter VI includes documentation for each type of capsule, review about each experiment within the VISA-2 project, the objective and purpose of the experiment as well as experimental device. Irradiation capsule VISA-2f was placed in the RA reactor core in September 1962. It was completely manufactured in Vinca including sample holders and leak tight shells. It will remain in the reactor core for about month in order to obtain the integral fast neutron flux [sr

  4. Removal of chromium (vi) by using eucalyptus bark (biosorption)

    International Nuclear Information System (INIS)

    Khatoon, S.; Anwar, J.; Fatima, H.B.

    2009-01-01

    Adsorption of Chromium (VI) on the Eucalyptus bark has been studied with variation in parameters. Different parameters like particle size of adsorbent, concentration of adsorbate, amount of adsorbent, stirring speed, time, temperature and pH were studied. The adsorption has been carried out in batch process. The adsorption capacity increases with decreasing the particle size of adsorbent. The optimum conditions for the maximum adsorption are attained with 2.0 g of adsorbent, 40 ppm metal ion concentration, at room temperature (10 degree C), with 90 min contact time, with 300 rpm agitation speed and at pH 2. (author)

  5. Phase 2 testing of ENDF/B-VI shielding data

    International Nuclear Information System (INIS)

    Ingersoll, D.T.; Wright, R.Q.; Slater, C.O.

    1992-01-01

    Version 6 of the US Evaluated Nuclear Data File (ENDF/B-VI) was released in early 1990 and is currently undergoing phase 2 testing. In Phase 2 testing, the evaluated data are approximately processed and used in an integral manner to predict the solution of previously specified benchmark experiments. Results are presented for the initial testing of several light elements and structural materials which are important for shielding applications. These initial tests indicate that the relatively subtle changes made to the iron data and the major modernization of the boron-11 data in Version 6 both represent significant and positive advancements in the quality of the evaluated data files

  6. PENGGUNAAN TEKNOLOGI INTERNET DALAM BISNIS

    OpenAIRE

    Oviliani Yuliana

    2000-01-01

    The uses of internet in business are for information exchange, product catalog, promotion media, electronic mail, bulletin boards, electronic questioner, and mailing list. Internet can also be used for dialog, discussion, and consultation with customer online, therefore consumer can be proactively and interactively involved in designing, developing, marketing, and selling products. There are 2 methods for marketing products via internet, which are push and pull marketing. The advantages of in...

  7. Penggunaan Teknologi Internet Dalam Bisnis

    OpenAIRE

    Yuliana, Oviliani

    2000-01-01

    The uses of internet in business are for information exchange, product catalog, promotion media, electronic mail, bulletin boards, electronic questioner, and mailing list. Internet can also be used for dialog, discussion, and consultation with customer online, therefore consumer can be proactively and interactively involved in designing, developing, marketing, and selling products. There are 2 methods for marketing products via internet, which are push and pull marketing. The advantages of in...

  8. Ulasan Teknologi dan Layanan Femtocell

    Directory of Open Access Journals (Sweden)

    Franciscus o Xaverius Ari Wibow

    2013-09-01

    Abstract The development of technology and mobile communication services today has encouraged the growth of mobile data traffic which is very high. In addition, the results of research from Informa states that more than 60% of mobile data traffic generated when the user is in the room. This causes the need for a technology that can solve the problem of weak communication signal in the room due to obstacles and walls other objects in the room. In general, femtocell technology exists to provide solutions to the limitations of mobile networks. Femtocell is an access point with a low transmit power on the basis of mobile communications technology (GSM, CDMA, HSDPA or even LTE that uses a network of fixed broadband (e.g. ADSL and FTTH as a backhaul that can provide wireless voice and data services to the users of mobile communication networks within the home or office environment. Basic services that can be provided by the femtocell are a voice service and high-quality data. In addition, femtocell is also one of technology that supports the convergence of fixed and mobile. But in addition to these basic services, it is also necessary value-added services as well as other applications in order to meet the increasingly diverse needs of customers. Therefor, femtocells have the capabilities that can be used in services design and applications design, which is the location information capability, presence detection, context, local networks, service discovery and secure remote access. The capabilities can be mixed to develop services such as Virtual Home Phone, Messaging Alert, Location based Message Delivery, Digital Signage and business support applications.

  9. Teknologi penyamakan kulit kras buaya

    Directory of Open Access Journals (Sweden)

    Bambang Oetojo

    1992-08-01

    Full Text Available The objective of this research is to know the influence of basic chromium tanning agent used to the colour and softness of the crust leather. In the carrying out it was used 12 pieces green salted cured crocodile skin of 11 up to 14 inch width. All of the crocodile skins were than pre-tanned with basic chromium tanning agent varying from 0.5%.; 1.0% and 1.5%. Each treatment needed two pieces of crocodile skin and was done twice. They were than tanned with 30% Irgatan LV. The Crust leather out put from the research was visual investigated for the Colour and the softness. Statistical analysis paints out that there is extremely signify difference (P < 0.01 the influence of the use of basic chromium tanning agent to the coulor and the softnees of the crusts leather. Practical meaning of this research is that to tan crocodile skin to be crust leather it is used 1.0 % basic chromium tanning agent 30% Irgatan LV.

  10. PENGGUNAAN TEKNOLOGI INFORMASI DALAM PENDIDIKAN

    Directory of Open Access Journals (Sweden)

    Fenny Purwani

    2015-12-01

    Full Text Available The development of information communication technology (ICT or Information and Communication Technology (ICT is increasingly more active over the last two decades and has created a change in many ways, including in education. Information technology is a combination of computer technology, databases, networks and improved communications, and Information Management Personnel. The aplication of ICT in teaching and learning can be use to make learning media (CAI, e-Learning, Virtual Library, the Virtual School and the Virtual University

  11. Pemanfaatan Teknologi Internet Dalam Pendidikan

    OpenAIRE

    Aziz, Nurazzmi

    2013-01-01

    Internet technology keeps on developing and touching various aspects of human daily life. Starting from the very simple utilization of internet, such as the use of email for communication purposes, browsing varied information, up to the relatively advanced one, such as designing and developing homepage or the use of internet for shopping purposes (e-shopping). Some initiatives, either individually or in collaboration, to utilize internet for learning has been conducted by some Secondary Schoo...

  12. Terrorgruppers brug af moderne teknologi

    DEFF Research Database (Denmark)

    Jensen, Mikkel Storm

    2008-01-01

    or affiliated groups tend to follow certain doctrines in spite of operational risks. −General doctrines and limitations within the skills of the respective groups shape the employment of technologies. The groups face a choice between utilizing current skills or risking communication to gain access to more...... advanced technologies. Communications present an opportunity to detect Islamic terrorist activities. −Terrorists apparently develop new technologies and adjust doctrines in order to de-feat developments in countermeasures. −Indications suggest that within the examined timeframe, an organisation with scien......-tific resources developed a new hydrogen-peroxide based explosive and distributed knowledge of this technology to Western Islamic terrorist groups visiting Pakistan....

  13. PENGGUNAAN TEKNOLOGI INTERNET DALAM BISNIS

    Directory of Open Access Journals (Sweden)

    Oviliani Yuliana

    2000-01-01

    Full Text Available The uses of internet in business are for information exchange, product catalog, promotion media, electronic mail, bulletin boards, electronic questioner, and mailing list. Internet can also be used for dialog, discussion, and consultation with customer online, therefore consumer can be proactively and interactively involved in designing, developing, marketing, and selling products. There are 2 methods for marketing products via internet, which are push and pull marketing. The advantages of internet in business strategy are global and interactive communication, information supply; consumer based service; increased cooperation; possibility to open new marketplace, product or services; and integrated the activity on-line. There are 2 applications in electronic commerce, which are business-to-business and business-to-consumer commerce. Electronic commerce payment transaction is arranged by Electronic Funds Transfer system, whereas the data security is governed by Secure Socket Layer, which then be developed to Secure Electronic Transaction. Abstract in Bahasa Indonesia : Internet dalam bisnis digunakan untuk pertukaran informasi, katalog produk, media promosi, surat elektronik, bulletin boards, kuesioner elektronik, dan mailing list. Internet juga bisa digunakan untuk berdialog, berdiskusi, dan konsultasi dengan konsumen secara on-line, sehingga konsumen dapat dilibatkan secara proaktif dan interaktif dalam perancangan, pengembangan, pemasaran, dan penjualan produk. Pemasaran lewat internet ada 2 metode, yaitu push dan pull marketing. Keunggulan strategi bisnis yang dapat diperoleh dari internet adalah komunikasi global dan interaktif; menyediakan informasi dan pelayanan sesuai dengan kebutuhan konsumen; meningkatkan kerja sama; memungkinkan untuk membuka pasar, produk, atau pelayanan baru; serta mengintegrasikan aktivitas secara on-line. Aplikasi Electronic Commerce ada 2, yaitu: Business-to-Consumer dan Business-to-Business Commerce. Pembayaran transaksi electronic commerce diatur dalam Sistem Electronic Funds Transfer, sedangkan keamanan datanya diatur oleh Secure Socket Layer yang dikembangkan menjadi Secure Electronic Transaction. Kata kunci: internet, electronic commerce, business

  14. Klonasi Manusia, Teknologi, dan Dehumanisasi

    Directory of Open Access Journals (Sweden)

    Septiana Dwiputri Maharani

    2007-04-01

    Full Text Available Being one of the institution of culture, science can be understood as human activities to understand themselves and their enviroment. While it enables human to adapt to the world, it also causes human to be greddy for the world. Unable to recognize the limit of human power, science, and techonology is frequently in opposition to religion. Human cloning is a case in point, as this is taken the rights of God away from creating the creature. Human cloning, it will be argued, would be a case ofhuman lost in scientific orientation to be human.

  15. POTENSI PENGEMBANGAN TEKNOLOGI ROOF GARDEN DI KAWASAN MAMPANG PRAPATAN DAN SEKITARNYA, JAKARTA SELATAN (Development Potential of Roof Garden Technology in Mampang Prapatan Area and Surroundings, South Jakarta

    Directory of Open Access Journals (Sweden)

    Sitti Sarifa Kartika Kinasih

    2013-11-01

    Full Text Available ABSTRAK Penelitian ini dilatarbelakangi oleh kondisi kotaJakartayang memiliki beragam masalah lingkungan. Tujuan penelitian ini adalah untuk mendapatkan fakta rinci manfaat ekologis, ekonomis, estetika, dan sosial yang dapat diraih oleh kawasan Jalan Mampang Prapatan dengan penerapan roof garden secara meluas; mengkaji persepsi stakeholder mengenai roof garden di kawasan Mampang Prapatan dan sekitarnya; serta memperoleh fakta peluang dan tantangan dalam penerapannya di Mampang Prapatan dan sekitarnya. Metode penelitian yang digunakan yakni analisis proyeksi manfaat dari citra Quick Bird kawasan Mampang Prapatan tahun 2010, analisis deskriptif induktif kondisi saat ini dan persepsi stakeholder terhadap penerapan roof garden, dan studi pustaka. Hasil penelitian menunjukkan bahwa analisis proyeksi manfaat dari blok terdelineasi daerah penelitian dengan luasan lahan 416.380 m2 dapat diperoleh manfaat secara ekologis (menghemat 25% energi yang biasa terpakai, dapat mereduksi 8.956 kg hingga 89.563 kg kotoran udara, dapat menjadi habitat untuk 597.088 tumbuhan, dan dapat meresapkan air hujan sebanyak 5.105.102 liter per tahun; secara ekonomis akan dapat menghasilkan 1.378 kg nasi mochi; secara estetis mengurangi kebisingan sekitar 10 dB hingga 40 dB serta dapat menyediakan 203 area estetis kota; secara sosial dapat memberikan tambahan 203 area komunitas pada blok kawasan terdelineasi Jalan Mampang Prapatan. Zona paling berpotensi memberikan manfaat adalah zona B yaitu zona perdagangan dan jasa (mengubah RTH existing 10,84% menjadi 28,15% dan terdapat 8 struktur di zona B yang telah menggunakan teknologi roof garden. Persepsi stakeholder dianalisis dari 5 konsep  telah terbukti sangat positif dan mendukung. Peluang penerapan roof garden di Mampang Prapatan dan sekitarnya jauh lebih besar daripada tantangan yang ada, bahkan solusi untuk tantangan tersebut diberikan oleh informan.   ABSTRACT This research is stimulated by the condition of Jakarta city

  16. Method for making graded I-III-VI.sub.2 semiconductors and solar cell obtained thereby

    Science.gov (United States)

    Devaney, Walter E.

    1987-08-04

    Improved cell photovoltaic conversion efficiencies are obtained by the simultaneous elemental reactive evaporation process of Mickelsen and Chen for making semiconductors by closer control of the evaporation rates and substrate temperature during formation of the near contact, bulk, and near junction regions of a graded I-III-VI.sub.2, thin film, semiconductor, such as CuInSe.sub.2 /(Zn,Cd)S or another I-III-VI.sub.2 /II-VI heterojunction.

  17. Antimicrobial Peptide Trichokonin VI-Induced Alterations in the Morphological and Nanomechanical Properties of Bacillus subtilis

    OpenAIRE

    Su, Hai-Nan; Chen, Zhi-Hua; Song, Xiao-Yan; Chen, Xiu-Lan; Shi, Mei; Zhou, Bai-Cheng; Zhao, Xian; Zhang, Yu-Zhong

    2012-01-01

    Antimicrobial peptides are promising alternative antimicrobial agents compared to conventional antibiotics. Understanding the mode of action is important for their further application. We examined the interaction between trichokonin VI, a peptaibol isolated from Trichoderma pseudokoningii, and Bacillus subtilis, a representative Gram-positive bacterium. Trichokonin VI was effective against B. subtilis with a minimal inhibitory concentration of 25 µM. Trichokonin VI exhibited a concentration- ...

  18. Towards a consistent geochemical model for prediction of uranium(VI) removal from groundwater by ferrihydrite

    International Nuclear Information System (INIS)

    Gustafsson, Jon Petter; Daessman, Ellinor; Baeckstroem, Mattias

    2009-01-01

    Uranium(VI), which is often elevated in granitoidic groundwaters, is known to adsorb strongly to Fe (hydr)oxides under certain conditions. This process can be used in water treatment to remove U(VI). To develop a consistent geochemical model for U(VI) adsorption to ferrihydrite, batch experiments were performed and previous data sets reviewed to optimize a set of surface complexation constants using the 3-plane CD-MUSIC model. To consider the effect of dissolved organic matter (DOM) on U(VI) speciation, new parameters for the Stockholm Humic Model (SHM) were optimized using previously published data. The model, which was constrained from available X-ray absorption fine structure (EXAFS) spectroscopy evidence, fitted the data well when the surface sites were divided into low- and high-affinity binding sites. Application of the model concept to other published data sets revealed differences in the reactivity of different ferrihydrites towards U(VI). Use of the optimized SHM parameters for U(VI)-DOM complexation showed that this process is important for U(VI) speciation at low pH. However in neutral to alkaline waters with substantial carbonate present, Ca-U-CO 3 complexes predominate. The calibrated geochemical model was used to simulate U(VI) adsorption to ferrihydrite for a hypothetical groundwater in the presence of several competitive ions. The results showed that U(VI) adsorption was strong between pH 5 and 8. Also near the calcite saturation limit, where U(VI) adsorption was weakest according to the model, the adsorption percentage was predicted to be >80%. Hence U(VI) adsorption to ferrihydrite-containing sorbents may be used as a method to bring down U(VI) concentrations to acceptable levels in groundwater

  19. Uranium(VI) adsorption properties of a chelating resin containing polyamine-substituted methylphosphonic acid moiety

    International Nuclear Information System (INIS)

    Matsuda, Masaaki; Akiyoshi, Yoshirou

    1991-01-01

    Uranium(VI) adsorption and desorption properties of a chelating resin containing polyamine-substituted methylphosphonic acid moiety of 2.29 mmol/g-resin (APA) were examined. Uranium(VI) adsorption properties of several ion exchange resins and extractant agents which were known as excellent adsorbents for uranium(VI), were examined together for a comparison with those of APA. Uranium(VI) adsorption capacity of APA at the concentration of 100 mg·dm -3 -uranium(VI) in 100 g·dm -3 -H 2 SO 4 aq. soln., 190 g·dm -3 -H 3 PO 4 aq. soln. and uranium enriched sea water, was 0.2, 0.05 and 0.05 mmol·g -1 respectively. The adsorption capacity of APA for uranium(VI) in these solutions was larger than that of another adsorbents, except the adsorption of uranium(VI) in enriched sea water on ion exchange resin containing phosphoric acid moiety (adsorption capacity ; 0.2 mmol·g -1 ). Uranium(VI) adsorption rate on APA was high and the relation between treatment time (t : min) and uranium(VI) concentration (y : mg·dm -3 ) in 100 g·dm -3 H 2 SO 4 aq. soln. after treatment, was shown as following equation, y=20 0.048t+1.90 (0≤t≤30). The adsorbed uranium(VI) on APA was able to be eluted with a mixed aq. soln. of hydrogen peroxide and sodium hydroxide and also was able to be eluted with an aq. alkaline soln. dissolved reduction agents such as sodium sulfite and hydrazine. From these results, it was thought that uranium(VI) adsorbed on APA was eluted due to the reduction to uranium(VI) by these eluents. (author)

  20. Biosorption of Cr(VI) by coconut coir: Spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material

    International Nuclear Information System (INIS)

    Shen, Ying-Shuian; Wang, Shan-Li; Huang, Shiuh-Tsuen; Tzou, Yu-Min; Huang, Jang-Hung

    2010-01-01

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment.

  1. Biosorption of Cr(VI) by coconut coir: Spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material

    Energy Technology Data Exchange (ETDEWEB)

    Shen, Ying-Shuian [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Wang, Shan-Li, E-mail: slwang@nchu.edu.tw [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Huang, Shiuh-Tsuen [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China); Department of Science Application and Dissemination, National Taichung University, Taichung, Taiwan (China); Tzou, Yu-Min; Huang, Jang-Hung [Department of Soil and Environmental Sciences, National Chung Hsing University, 250 Kuo Kuang Road, Taichung 40227, Taiwan (China)

    2010-07-15

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment.

  2. Biosorption of Cr(VI) by coconut coir: spectroscopic investigation on the reaction mechanism of Cr(VI) with lignocellulosic material.

    Science.gov (United States)

    Shen, Ying-Shuian; Wang, Shan-Li; Huang, Shiuh-Tsuen; Tzou, Yu-Min; Huang, Jang-Hung

    2010-07-15

    In this study, the removal mechanism of Cr(VI) from water by coconut coir (CC) was investigated using X-ray photoelectron spectroscopy (XPS), Cr K-edge X-ray absorption near edge structure (XANES) and FTIR spectroscopy. The results showed that, upon reaction with CC at pH 3, Cr(VI) was reduced to Cr(III), which was either bound to CC or released back into solution. As revealed by the FTIR spectra of CC before and after reacting with Cr(VI), the phenolic methoxyl and hydroxyl groups of lignin in CC are the dominant drivers of Cr(VI) reduction, giving rise to carbonyl and carboxyl groups on CC. These functional groups can subsequently provide binding sites for Cr(III) resulting from Cr(VI) reduction. In conjunction with forming complexes with carbonyl and carboxyl groups, the formation of Cr(III) hydroxide precipitate could also readily occur as revealed by the linear combination fitting of the Cr K-edge XANES spectrum using a set of reference compounds. The phenolic groups in lignin are responsible for initiating Cr(VI) reduction, so lignocellulosic materials containing a higher amount of phenolic groups are expected to be more effective scavengers for removal of Cr(VI) from the environment. 2010 Elsevier B.V. All rights reserved.

  3. Transient groundwater chemistry near a river: Effects on U(VI) transport in laboratory column experiments

    Science.gov (United States)

    Yin, Jun; Haggerty, Roy; Stoliker, Deborah L.; Kent, Douglas B.; Istok, Jonathan D.; Greskowiak, Janek; Zachara, John M.

    2011-01-01

    In the 300 Area of a U(VI)-contaminated aquifer at Hanford, Washington, USA, inorganic carbon and major cations, which have large impacts on U(VI) transport, change on an hourly and seasonal basis near the Columbia River. Batch and column experiments were conducted to investigate the factors controlling U(VI) adsorption/desorption by changing chemical conditions over time. Low alkalinity and low Ca concentrations (Columbia River water) enhanced adsorption and reduced aqueous concentrations. Conversely, high alkalinity and high Ca concentrations (Hanford groundwater) reduced adsorption and increased aqueous concentrations of U(VI). An equilibrium surface complexation model calibrated using laboratory batch experiments accounted for the decrease in U(VI) adsorption observed with increasing (bi)carbonate concentrations and other aqueous chemical conditions. In the column experiment, alternating pulses of river and groundwater caused swings in aqueous U(VI) concentration. A multispecies multirate surface complexation reactive transport model simulated most of the major U(VI) changes in two column experiments. The modeling results also indicated that U(VI) transport in the studied sediment could be simulated by using a single kinetic rate without loss of accuracy in the simulations. Moreover, the capability of the model to predict U(VI) transport in Hanford groundwater under transient chemical conditions depends significantly on the knowledge of real-time change of local groundwater chemistry.

  4. Kinetics and Products of Chromium(VI) Reduction by Iron(II/III)-Bearing Clay Minerals.

    Science.gov (United States)

    Joe-Wong, Claresta; Brown, Gordon E; Maher, Kate

    2017-09-05

    Hexavalent chromium is a water-soluble pollutant, the mobility of which can be controlled by reduction of Cr(VI) to less soluble, environmentally benign Cr(III). Iron(II/III)-bearing clay minerals are widespread potential reductants of Cr(VI), but the kinetics and pathways of Cr(VI) reduction by such clay minerals are poorly understood. We reacted aqueous Cr(VI) with two abiotically reduced clay minerals: an Fe-poor montmorillonite and an Fe-rich nontronite. The effects of ionic strength, pH, total Fe content, and the fraction of reduced structural Fe(II) [Fe(II)/Fe(total)] were examined. The last variable had the largest effect on Cr(VI) reduction kinetics: for both clay minerals, the rate constant of Cr(VI) reduction varies by more than 3 orders of magnitude with Fe(II)/Fe(total) and is described by a linear free energy relationship. Under all conditions examined, Cr and Fe K-edge X-ray absorption near-edge structure spectra show that the main Cr-bearing product is a Cr(III)-hydroxide and that Fe remains in the clay structure after reacting with Cr(VI). This study helps to quantify our understanding of the kinetics of Cr(VI) reduction by Fe(II/III)-bearing clay minerals and may improve predictions of Cr(VI) behavior in subsurface environments.

  5. Role of paramagnetic chromium in chromium(VI)-induced damage in cultured mammalian cells.

    OpenAIRE

    Sugiyama, M

    1994-01-01

    Chromium(VI) compounds are known to be potent toxic and carcinogenic agents. Because chromium(VI) is easily taken up by cells and is subsequently reduced to chromium(III), the formation of paramagnetic chromium such as chromium(V) and chromium(III) is believed to play a role in the adverse biological effects of chromium(VI) compounds. The present report, uses electron spin resonance (ESR) spectroscopy; the importance of the role of paramagnetic chromium in chromium(VI)-induced damage in intac...

  6. Influence of Calcium on Microbial Reduction of Solid Phase Uranium (VI)

    International Nuclear Information System (INIS)

    Liu, Chongxuan; Jeon, Byong-Hun; Zachara, John M.; Wang, Zheming

    2007-01-01

    The effect of calcium on microbial reduction of a solid phase U(VI), sodium boltwoodite (NaUO2SiO3OH · 1.5H2O), was evaluated in a culture of a dissimilatory metal-reducing bacterium (DMRB), Shewanella oneidensis strain MR-1. Batch experiments were performed in a non-growth bicarbonate medium with lactate as electron donor at pH 7 buffered with PIPES. Calcium increased both the rate and extent of Na-boltwoodite dissolution by increasing its solubility through the formation of a ternary aqueous calcium-uranyl-carbonate species. The ternary species, however, decreased the rates of microbial reduction of aqueous U(VI). Laser-induced fluorescence spectroscopy (LIFS) and transmission electron microscopy (TEM) revealed that microbial reduction of solid phase U(VI) is a sequentially coupled process of Na-boltwoodite dissolution, U(VI) aqueous speciation, and microbial reduction of dissolved U(VI) to U(IV) that accumulated on bacterial surfaces/periplasm. The overall rates of microbial reduction of solid phase U(VI) can be described by the coupled rates of dissolution and microbial reduction that were both influenced by calcium. The results demonstrated that dissolved U(VI) concentration during microbial reduction was a complex function of solid phase U(VI) dissolution kinetics, aqueous U(VI) speciation, and microbial activity

  7. Kinetics of Uranium(VI) Desorption from Contaminated Sediments: Effect of Geochemical Conditions and Model Evaluation

    International Nuclear Information System (INIS)

    Liu, Chongxuan; Shi, Zhenqing; Zachara, John M.

    2009-01-01

    Stirred-flow cell experiments were performed to investigate the kinetics of uranyl (U(VI)) desorption from a contaminated sediment collected from the Hanford 300 Area at the US Department of Energy (DOE) Hanford Site, Washington. Three influent solutions of variable pH, Ca and carbonate concentrations that affected U(VI) aqueous and surface speciation were used under dynamic flow conditions to evaluate the effect of geochemical conditions on the rate of U(VI) desorption. The measured rate of U(VI) desorption varied with solution chemical composition that evolved as a result of thermodynamic and kinetic interactions between the influent solutions and sediment. The solution chemical composition that led to a lower equilibrium U(VI) sorption to the solid phase yielded a faster desorption rate. The experimental results were used to evaluate a multi-rate, surface complexation model (SCM) that has been proposed to describe U(VI) desorption kinetics in the Hanford sediment that contained complex sorbed U(VI) species in mass transfer limited domains. The model was modified and supplemented by including multi-rate, ion exchange reactions to describe the geochemical interactions between the solutions and sediment. With the same set of model parameters, the modified model reasonably well described the evolution of major ions and the rates of U(VI) desorption under variable geochemical and flow conditions, implying that the multi-rate SCM is an effective way to describe U(VI) desorption kinetics in subsurface sediments

  8. A combined wet chemistry and EXAFS study of U(VI) uptake by cementitious materials

    International Nuclear Information System (INIS)

    Wieland, E.; Harfouche, M.; Tits, J.; Kunz, D.; Daehn, R.; Fujita, T.; Tsukamoto, M.

    2006-01-01

    The sorption behaviour and speciation of U(VI) in cementitious systems was investigated by a combination of wet chemistry experiments and synchrotron-based X-ray absorption spectroscopy (XAS) measurements. Radiotracer studies using 233 U were carried out on hardened cement paste (HCP) and calcium silicate hydrates (C-S-H), which are the major constituents of HCP, to determine the uptake kinetics and sorption isotherms. C-S-H phases were synthesized using different methods for solid phase preparation, which enabled us to study the U(VI) uptake by different types of C-S-H phases and a wide range of Ca/Si compositions, and to distinguish U(VI) sorption on the surface of C-S-H from U(VI) incorporation into the structure. XAS measurements were performed using U(VI) loaded HCP and C-S-H materials (sorption and co-precipitation samples) to gain structural information on the U(VI) speciation in these systems, i.e., the type and number of neighbouring atoms, and bond distances. Examples of studies that have utilized XAS to characterize U(VI) speciation in cementitious systems are still rare, and to the best of our knowledge, detailed XAS investigations of the U(VI)/C-S-H system are lacking. The results obtained from the combined use of wet chemical and spectroscopic techniques allow mechanistic models of the immobilization process to be proposed for cementitious waste forms containing low and high U(VI) inventories. In the latter case U(VI) immobilization is controlled by a solubility-limiting process with the U(VI) mineral predominantly formed under the conditions prevailing in cementitious systems. At low U(VI) concentrations, however, U(VI) appears to be predominantly bound onto C-S-H phases. The coordination environment of U(VI) taken up by C-S-H was found to resemble that of U(VI) in uranophane. A mechanistic understanding of the U(VI) binding by cementitious materials will allow more detailed and scientifically well founded predictions of the retention of

  9. Oxidation of trimethoprim by ferrate(VI): kinetics, products, and antibacterial activity.

    Science.gov (United States)

    Anquandah, George A K; Sharma, Virender K; Knight, D Andrew; Batchu, Sudha Rani; Gardinali, Piero R

    2011-12-15

    Kinetics, stoichiometry, and products of the oxidation of trimethoprim (TMP), one of the most commonly detected antibacterial agents in surface waters and municipal wastewaters, by ferrate(VI) (Fe(VI)) were determined. The pH dependent second-order rate constants of the reactions of Fe(VI) with TMP were examined using acid-base properties of Fe(VI) and TMP. The kinetics of reactions of diaminopyrimidine (DAP) and trimethoxytoluene (TMT) with Fe(VI) were also determined to understand the reactivity of Fe(VI) with TMP. Oxidation products of the reactions of Fe(VI) with TMP and DAP were identified by liquid chromatography-tandem mass spectrometry (LC-MS/MS). Reaction pathways of oxidation of TMP by Fe(VI) are proposed to demonstrate the cleavage of the TMP molecule to ultimately result in 3,4,5,-trimethoxybenzaldehyde and 2,4-dinitropyrimidine as among the final identified products. The oxidized products mixture exhibited no antibacterial activity against E. coli after complete consumption of TMP. Removal of TMP in the secondary effluent by Fe(VI) was achieved.

  10. Polyaniline (PANI) modified bentonite by plasma technique for U(VI) removal from aqueous solution

    Energy Technology Data Exchange (ETDEWEB)

    Liu, Xinghao [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China); Intelligent Manufacturing Technology Research Institute, Hefei University of Technology, Hefei 230088 (China); Cheng, Cheng [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Xiao, Chengjian, E-mail: xiaocj@caep.cn [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China); Shao, Dadong, E-mail: shaodadong@126.com [Institute of Plasma Physics, Chinese Academy of Sciences, Hefei 230031 (China); Xu, Zimu, E-mail: xzm@mail.ustc.edu.cn [Intelligent Manufacturing Technology Research Institute, Hefei University of Technology, Hefei 230088 (China); Wang, Jiaquan; Hu, Shuheng [Intelligent Manufacturing Technology Research Institute, Hefei University of Technology, Hefei 230088 (China); Li, Xiaolong; Wang, Weijuan [Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, Mianyang 621900 (China)

    2017-07-31

    Highlights: • PANI/bentonie can be synthesized by simple plasma technique. • PANI/bentonie has an excellent adsorption capacity for trace uranium in solution. • U(VI) adsorption on PANI/bentonite is a spontaneous and endothermic process. - Abstract: Polyaniline (PANI) modified bentonite (PANI/bentonie) was synthesized by plasma induced polymerization of aniline on bentonite surface, and applied to uptake of uranium(VI) ions from aqueous solution. The as-synthesized PANI/bentonie was characterized by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Batch adsorption technique was utilized to investigate the adsorption of U(VI) on bentonite and PANI/bentonite. The adsorption of U(VI) (10 mg/L) on PANI/bentonite surface is fairly depend on solution pH, ionic strength, and temperature in solution. The modified PANI on PANI/bentonite surface significantly enhances its adsorption capability for U(VI). The presence of humic acid (HA) can sound enhance U(VI) adsorption on PANI/bentonite at pH < 6.5 because of the strong complexation, and inhibits U(VI) adsorption at pH > 6.5. According to the thermodynamic parameters, the adsorption of U(VI) on PANI/bentonite surface is a spontaneous and endothermic process. The results highlight the application of PANI/bentonite composites as candidate material for the uptake of trace U(VI) from aqueous solution.

  11. A coupled mass transfer and surface complexation model for uranium (VI) removal from wastewaters

    International Nuclear Information System (INIS)

    Lenhart, J.; Figueroa, L.A.; Honeyman, B.D.

    1994-01-01

    A remediation technique has been developed for removing uranium (VI) from complex contaminated groundwater using flake chitin as a biosorbent in batch and continuous flow configurations. With this system, U(VI) removal efficiency can be predicted using a model that integrates surface complexation models, mass transport limitations and sorption kinetics. This integration allows the reactor model to predict removal efficiencies for complex groundwaters with variable U(VI) concentrations and other constituents. The system has been validated using laboratory-derived kinetic data in batch and CSTR systems to verify the model predictions of U(VI) uptake from simulated contaminated groundwater

  12. Comparison of U(VI) adsorption onto nanoscale zero-valent iron and red soil in the presence of U(VI)–CO_3/Ca–U(VI)–CO_3 complexes

    International Nuclear Information System (INIS)

    Zhang, Zhibin; Liu, Jun; Cao, Xiaohong; Luo, Xuanping; Hua, Rong; Liu, Yan; Yu, Xiaofeng; He, Likai

    2015-01-01

    Highlights: • NZVI can be used for adsorbing U(VI)–CO_3 complexes. • Use of NZVI is feasible for remediation of uranium-contaminated soils. • The mechanism of U(VI)–CO_3 complexes adsorbing onto NZVI has been explained. - Abstract: The influence of U(VI)–CO_3 and Ca–U(VI)–CO_3 complexes on U(VI) adsorption onto red soil and nanoscale zero-valent iron (NZVI) was investigated using batch adsorption and fixed-bed column experiments to simulate the feasibility of NZVI as the reactive medium in permeable- reactive barriers (PRB) for in situ remediation of uranium-contaminated red soils. The adsorption capacity (q_e) and distribution constant (K_d) of NZVI and red soil decreased with increasing pH, dissolved carbonate and calcium concentrations, but the q_e and K_d values of NZVI were 5–10 times higher than those of red soil. The breakthrough pore volume (PV) values increased with the decrease of pH, dissolved carbonate and calcium concentration; however, the breakthrough PV values of the PRB column filled with 5% NZVI were 2.0–3.5 times higher than the 100% red soil column. The U(VI)–CO_3 complexes adsorbed onto the surface of red soil/NZVI (≡SOH) to form SO–UO_2CO_3"− or SO–UO_2 (CO_3)_2"3"−. XPS and XRD analysis further confirmed the reduction of U(VI) to U(IV) and the formation of FeOOH on NZVI surfaces. The findings of this study are significant to the remediation of uranium-contaminated red soils and the consideration of practical U(VI) species in the natural environment.

  13. Comparison of U(VI) adsorption onto nanoscale zero-valent iron and red soil in the presence of U(VI)–CO{sub 3}/Ca–U(VI)–CO{sub 3} complexes

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Zhibin [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Liu, Jun [State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Cao, Xiaohong, E-mail: xhcao@ecit.cn [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Luo, Xuanping [Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Hua, Rong; Liu, Yan [Key Laboratory of Radioactive Geology and Exploration Technology Fundamental Science for National Defense, East China Institute of Technology, Nanchang 330013 (China); State Key Laboratory Breeding Base of Nuclear Resources and Environment (East China Institute of Technology), Ministry of Education, Nanchang 330013 (China); Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); Yu, Xiaofeng; He, Likai [Chemistry, Biological and Materials Sciences Department, East China Institute of Technology, Nanchang 330013 (China); and others

    2015-12-30

    Highlights: • NZVI can be used for adsorbing U(VI)–CO{sub 3} complexes. • Use of NZVI is feasible for remediation of uranium-contaminated soils. • The mechanism of U(VI)–CO{sub 3} complexes adsorbing onto NZVI has been explained. - Abstract: The influence of U(VI)–CO{sub 3} and Ca–U(VI)–CO{sub 3} complexes on U(VI) adsorption onto red soil and nanoscale zero-valent iron (NZVI) was investigated using batch adsorption and fixed-bed column experiments to simulate the feasibility of NZVI as the reactive medium in permeable- reactive barriers (PRB) for in situ remediation of uranium-contaminated red soils. The adsorption capacity (q{sub e}) and distribution constant (K{sub d}) of NZVI and red soil decreased with increasing pH, dissolved carbonate and calcium concentrations, but the q{sub e} and K{sub d} values of NZVI were 5–10 times higher than those of red soil. The breakthrough pore volume (PV) values increased with the decrease of pH, dissolved carbonate and calcium concentration; however, the breakthrough PV values of the PRB column filled with 5% NZVI were 2.0–3.5 times higher than the 100% red soil column. The U(VI)–CO{sub 3} complexes adsorbed onto the surface of red soil/NZVI (≡SOH) to form SO–UO{sub 2}CO{sub 3}{sup −} or SO–UO{sub 2} (CO{sub 3}){sub 2}{sup 3−}. XPS and XRD analysis further confirmed the reduction of U(VI) to U(IV) and the formation of FeOOH on NZVI surfaces. The findings of this study are significant to the remediation of uranium-contaminated red soils and the consideration of practical U(VI) species in the natural environment.

  14. On halide derivatives of rare-earth metal(III) oxidomolybdates(VI) and -tungstates(VI)

    International Nuclear Information System (INIS)

    Schleid, Thomas; Hartenbach, Ingo

    2016-01-01

    Halide derivatives of rare-earth metal(III) oxidomolybdates(VI) have been investigated comprehensively over the last decade comprising the halogens fluorine, chlorine, and bromine. Iodide-containing compounds are so far unknown. The simple composition REXMoO 4 (RE=rare-earth element, X=halogen) is realized for X=F almost throughout the complete lanthanide series as well as for yttrium. While ytterbium and lutetium do not form any fluoride derivative, for lanthanum, only a fluoride-deprived compound with the formula La 3 FMo 4 O 16 is realized. Moreover, molybdenum-rich compounds with the formula REXMo 2 O 7 are also known for yttrium and the smaller lanthanoids. For X=Cl the composition REClMoO 4 is known for yttrium and the whole lanthanide series, although, four different structure types were identified. Almost the same holds for X=Br, however, only two different structure types are realized in this class of compounds. In the case of halide derivatives of rare-earth metal(III) oxidotungstates(VI) the composition REXWO 4 is found for chlorides and bromides only, so far. Due to the similar size of Mo 6+ and W 6+ cations, the structures found for the tungstates are basically the same as for the molybdates. With the larger lanthanides, the representatives for both chloride and bromide derivates exhibit similar structural motifs as seen in the molybdates, however, the crystal structure cannot be determined reliably. In case of the smaller lanthanoids, the chloride derivatives are isostructural with the respective molybdates, although the existence ranges differ slightly. The same is true for rare-earth metal(III) bromide oxidotungstates(VI).

  15. Different roles of ROS and Nrf2 in Cr(VI)-induced inflammatory responses in normal and Cr(VI)-transformed cells

    Energy Technology Data Exchange (ETDEWEB)

    Roy, Ram Vinod; Pratheeshkumar, Poyil; Son, Yong-Ok; Wang, Lei [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Department of Toxicology and Cancer Biology, College of Medicine, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Hitron, John Andrew [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Divya, Sasidharan Padmaja; Zhang, Zhuo [Department of Toxicology and Cancer Biology, College of Medicine, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States); Shi, Xianglin, E-mail: xshi5@email.uky.edu [Center for Research on Environmental Disease, University of Kentucky, 1095 VA Drive, Lexington, KY 40536 (United States)

    2016-09-15

    Hexavalent chromium (Cr(VI)) is classified as a human carcinogen. Cr(VI) has been associated with adenocarcinomas and squamous cell carcinoma of the lung. The present study shows that acute Cr(VI) treatment in human bronchial epithelial cells (BEAS-2B) increased inflammatory responses (TNF-α, COX-2, and NF-кB/p65) and expression of Nrf2. Cr(VI)-induced generation of reactive oxygen species (ROS) are responsible for increased inflammation. Despite the fact that Nrf2 is a master regulator of response to oxidative stress, silencing of Nrf2 in the acute Cr(VI) treatment had no effect on Cr(VI)-induced inflammation. In contrast, in Cr(VI)-transformed (CrT) cells, Nrf2 is constitutively activated. Knock-down of this protein resulted in decreased inflammation, while silencing of SOD2 and CAT had no effect in the expression of these inflammatory proteins. Results obtained from the knock-down of Nrf2 in CrT cells are very different from the results obtained in the acute Cr(VI) treatment. In BEAS-2B cells, knock-down of Nrf2 had no effect in the inflammation levels, while in CrT cells a decrease in the expression of inflammation markers was observed. These results indicate that before transformation, ROS plays a critical role while Nrf2 not in Cr(VI)-induced inflammation, whereas after transformation (CrT cells), Nrf2 is constitutively activated and this protein maintains inflammation while ROS not. Constitutively high levels of Nrf2 in CrT binds to the promoter regions of COX-2 and TNF-α, leading to increased inflammation. Collectively, our results demonstrate that before cell transformation ROS are important in Cr(VI)-induced inflammation and after transformation a constitutively high level of Nrf2 is important. - Highlights: • Cr(VI)-induced ROS increased inflammation, while Nrf2 had no effect. • In the CrT cells knock-down of Nrf2 resulted in decreased inflammation. • Mechanistic differences in regulating Cr(VI)-induced inflammation.

  16. A simple Cr(VI)–S(IV)–O{sub 2} system for rapid and simultaneous reduction of Cr(VI) and oxidative degradation of organic pollutants

    Energy Technology Data Exchange (ETDEWEB)

    Yuan, Yanan; Yang, Shaojie [Department of Environmental Science, Hubei Key Lab of Biomass Resource Chemistry and Environmental Biotechnology, School of Resources and Environmental Science, Wuhan University, 430079 (China); Zhou, Danna, E-mail: zdncug@163.com [Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 430074 (China); Wu, Feng [Department of Environmental Science, Hubei Key Lab of Biomass Resource Chemistry and Environmental Biotechnology, School of Resources and Environmental Science, Wuhan University, 430079 (China)

    2016-04-15

    Highlights: • Rapid and simultaneous reduction of Cr(VI) and degradation of organic pollutants occur. • Oxysulfur radicals generated in Cr(VI)–S(IV)–O{sub 2} system oxidize the organic pollutants. • Acidic pH facilitates the reactions from both directions of reduction and oxidation. • Degradation potential of aromatic amines depends on the substituted groups. • Cr(VI)–S(IV)–O{sub 2} system is promising for “waste control by waste”. - Abstract: Hexavalent chromium (Cr(VI)), a heavy-metal contaminant, can be easily reduced to less toxic trivalent chromium (Cr(III)) by sulfite ions (S(IV)). However, S(IV) has not drawn as much attention as the ferrous ion has. We report herein a novel Cr(VI)–S(IV)–O{sub 2} system containing sulfite ions that rapidly and simultaneously reduces Cr(VI) and oxidize organic pollutants in the presence of oxygen in aqueous solutions. This Cr(VI)–S(IV)-O{sub 2} system contains the initiator Cr(VI), the reductant S(IV), and the oxidant O{sub 2}, which produce oxysulfur radicals (mainly SO{sub 4}·{sup −} and SO{sub 5}·{sup −}) and hydroxyl radicals (OH·). The Cr(VI)/S(IV) molar ratio, pH, and oxygen content play important roles in the entire reaction system. Acidic conditions (pH 3.0) facilitated degradation of organic compounds and reduction of Cr(VI) as well. In addition, experiments of rapid degradation of several kinds of organic pollutants such as azo dye (acid orange 7, AO7), aniline, phenol, bisphenol A etc were also conducted. Preliminary results show that the removal rates of the analogs of phenols or aromatic amines in this Cr(VI)–S(IV)–O{sub 2} system have a relationship with the electronic parameters (Hammett constant, σ) of the substituted groups. Thus, the Cr(VI)–S(IV)–O{sub 2} system, provides an excellent strategy of “waste control by waste” for removing multiple industrial contaminants.

  17. Preparation and properties of N-Phenylbutyrohydroxamic acid and N-p-Chlorophenylbutyrohydroxamic acid and their uses as extracting agents for Chromium (VI), Molybdenum (VI), Titanium (IV) and Uranium (VI)

    Energy Technology Data Exchange (ETDEWEB)

    Abu Elnour, Sawsan Hassan [Department of Chemistry, Faculty of Science, University of Khartoum, Khartoum (Sudan)

    1993-05-01

    Two lignads, N-phenylbutyrohydroxamic acid (1), N-p-chlorophenylbutyryl chloride with {beta} phenyl-hydroylamine and N-p-chlorophenylhydroxylamine, respectively. The acids prepared were identified and characterised through their reactions with Vanadiun (V) and iron (III), their melting points, infra-red spectra and nitrogen content. The extractive properties of these acids towards the metals Cr (VI), Mo (VI), Ti (IV) and U (VI) were examined at different PH values. The percentage of maximum extraction with the two acids was found to be as follows : for Cr (VI) at PH 1, (100%) for both acids, Mo (VI) at PH 2 (33.34%) with acid (I) and (16.67%) with acid (II) and U (VI) at PH 6 (72%) with acid (I) and (76%) with acid (II). The metal: Ligand complexes ratios were determined by using the continuous variation method, the ratio of the two ligands with four metals was found to be 1:2. Finally the suitability of the two acids for spectrophotometric determination of four metals was examined.(Author) 90 refs. , 24 tabs. , 24 figs

  18. Preparation and properties of N-Phenylbutyrohydroxamic acid and N-p-Chlorophenylbutyrohydroxamic acid and their uses as extracting agents for Chromium (VI), Molybdenum (VI), Titanium (IV) and Uranium (VI)

    International Nuclear Information System (INIS)

    Abu Elnour, Sawsan Hassan

    1993-05-01

    Two lignads, N-phenylbutyrohydroxamic acid (1), N-p-chlorophenylbutyryl chloride with β phenyl-hydroylamine and N-p-chlorophenylhydroxylamine, respectively. The acids prepared were identified and characterised through their reactions with Vanadiun (V) and iron (III), their melting points, infra-red spectra and nitrogen content. The extractive properties of these acids towards the metals Cr (VI), Mo (VI), Ti (IV) and U (VI) were examined at different PH values. The percentage of maximum extraction with the two acids was found to be as follows : for Cr (VI) at PH 1, (100%) for both acids, Mo (VI) at PH 2 (33.34%) with acid (I) and (16.67%) with acid (II) and U (VI) at PH 6 (72%) with acid (I) and (76%) with acid (II). The metal: Ligand complexes ratios were determined by using the continuous variation method, the ratio of the two ligands with four metals was found to be 1:2. Finally the suitability of the two acids for spectrophotometric determination of four metals was examined.(Author)

  19. Validating Imaginary Worlds? The AdViSHE Assessment Tool

    Directory of Open Access Journals (Sweden)

    Paul C Langley

    2017-01-01

    Full Text Available The publication in April 2016 of the Assessment of the Validation Status of Health-Economic Decision Models (AdViSHE checklist for decision models raises a number of issues that the health technology assessment literature has yet to address. The principal issue being the role of decision models in generating claims that are evaluable and replicable. Unfortunately, this is not addressed in this new checklist which is intended to address the perceived need for a tradeoff between confidence in a decision model and the need to allocate resources by developers and payers to validating the model. Irrespective of the degree of confidence a developer or payers may have in the sufficiency of the model in representing ‘reality’ unless the model has generated evaluable claims and evidence for those claims in target treating populations, the model fails the standards of normal science. Apart from the absence of a commitment in the AdViSHE checklist to the modeling of claims that are evaluable and replicable, the validation check list makes no allowance for a product pricing strategy that may commits a manufacturer to regular and substantial annual or semi-annual product price increases. Indeed, product pricing assumptions are conspicuous by their absence. The commentary argues that failure to accommodate anticipated pricing behavior renders lifetime cost-per-QALY models and the application of willingness-to-pay thresholds meaningless.   Type: Commentary

  20. ENDF/B-VI data for MCNP trademark

    International Nuclear Information System (INIS)

    Hendricks, J.S.; Frankle, S.C.; Court, J.D.

    1994-12-01

    Nuclear and atomic data are the foundation upon which the radiation transport codes are built. For neutron transport the international standard is the Evaluated Nuclear Data File from Brookhaven National Laboratory. The latest version, ENDF/B-VI release 2, has recently become available for use in the Monte Carlo N-Particle (MCNP) radiation transport code. These neutron cross-section data are designated by ZAID identifiers ending in .60c and are referred to as the ENDF60 library. The ENDF60 data library was processed from the ENDF/B-VI evaluations using the NJOY code. Fifty-two percent of the data evaluations are translations from ENDF/B-V. The remaining 48% are new evaluations which have sometimes changed significantly. The RSIC release package contains the ENDF60 neutron library, a new photon library MCPLIB02, the electron library EL1, and an updated XSDIR file. The authors report here the work done by the LANL Radiation Transport Group (X-6) in testing and validating the ENDF60 data library and in developing the necessary new sampling and detector schemes. When the ENDF60 library should be used in preference to the previous libraries, is also considered. The development of the new photon library MCPLIB02 is also discussed

  1. Treatment of hexavalent chromium Cr (VI) in tanning effluent

    International Nuclear Information System (INIS)

    Ahmed, I.; Ali, S.

    1999-01-01

    Most common chemical used in chrome tanning is basic chromium sulphate (BCS). Manufacturing of BCS involves many steps producing liquid waste. Waste generated at every stage contains Cr (VI), which must be reduced to Cr (III) before being disposed to the environment. Different methods were studied for the reduction of toxic Cr (III). Pickle liquor (waste of electroplating industry) can also be used for the reduction of hexavalent chromium Cr (vi) along with other reducing materials / chemicals. In an electroplating process metal is treated with HCl or H/sub 2/SO/sub 4/ to remove scales and rust, the pickled items are then washed with water, washing contains FeCl/sub 2/ or fees/sub 4/ respectively called pickle liquor. During waste treatment pH adjustment to 6.0 - 9.0 and settling the sludge, is discharged to the lagoon. The sludge obtained is dried and disposed off in landfills. Other reducing agents like sodium bisulphite and sulfur dioxide were also studied, but pickle liquor was found to be more effective and economical. (author)

  2. Absorption spectra and speciation of plutonium(VI) with phosphate

    Energy Technology Data Exchange (ETDEWEB)

    Weger, H.T.; Reed, D.

    1996-02-01

    Plutonium(VI)-phosphate species in aqueous solution, at pH < 2.4, formed two species: PuO{sub 2}H{sub 2}PO{sub 4}{sup +} (characterized by an 835 nm absorption band) and the solid phase PuO{sub 2}(H{sub 2}PO{sub 4}){sub 2}. The stability constant {beta} for the PuO{sub 2}H{sub 2}PO{sub 4}{sup +} species was determined to be log {beta} = 2.1 {+-} 0.1 (ionic strength = 0.6--0.9 M) and log {beta}{sup T} = 2.6 {+-} 0.15 (zero ionic strength). Four Pu(VI)-phosphate species (absorption bands at 842, 846, 857, and 866 nm) formed at pH = 2.4 to 12.2 and are characterized by polynuclear behavior, the formation of precipitates, and colloidal properties. The 842 and 846 nm species are believed to be [PuO{sub 2}(HPO{sub 4}){sub m}]{sub n} and [PuO{sub 2}(NaPO{sub 4}){sub m}]{sub n}. The 857 and 866 nm species area as yet unidentified. The speciation of plutonium with phosphate is of interest to radionuclide migration studies because phosphate is present in many groundwaters and may be used as an actinide getter in nuclear waste disposal. An actinide getter is a complexing agent that forms insoluble phases with actinides, thereby reducing their migration.

  3. Kinetics of chromium (VI) reduction by ferrous iron

    International Nuclear Information System (INIS)

    Batchelor, B.; Schlautman, M.; Hwang, I.; Wang, R.

    1998-09-01

    Chromium is a primary inorganic contaminant of concern at the Pantex Plant. Chromium concentrations have been found to be two orders of magnitude higher than the drinking water standards, particularly in certain wells in the perched aquifer below Zone 12. In situ reduction of a mobile form of chromium, Cr(VI) to an immobile form, Cr(III), was examined as a viable option to active soil restoration. Successfully immobilizing chromium in the vadose zone as Cr(III) will reduce the amount of chromium that reaches the groundwater table. The results from the solution experiments indicated that chromium was rapidly and stoichiometrically reduced by Fe(II) in solution. Also, the slurry experiments showed that the aquifer solids removed Fe(II) from solution, but a portion of the iron removed remained available for reaction with Cr(VI), but at a slower rate. A model to predict different amounts of iron pseudo-components was developed, which allowed prediction of iron amounts required to reduce chromium under in situ conditions

  4. The feasibility of BRT corridor VI shelters in Semarang City

    Science.gov (United States)

    Purnomo, Andi; Setiawan, Moch Fathoni

    2018-03-01

    Like other big cities in Indonesia, Semarang City as the capital of Central Java Province also has various city problems, one of them is the transportation problem. Transportation problems arise due to increased mobility of society that is not in balanced with the public transportation facilities and infrastructure availability. In order to create a better transportation system, the local government of Semarang City held Trans Semarang bus rapid transit (BRT) which began operating in 2010. This study aims to analyze the feasibility of BRT Trans Semarang corridor VI shelters. This research uses descriptive critique technique. The results are expected to be considered in determining the right policy in creating a better transportation system. Based on observations made, the majority of BRT Trans Semarang corridor VI uses non-permanent shelters and is less feasible to be a BRT shelter. Thus, the local government is expected to improve the feasibility of BRT Trans Semarang shelter so that the sense of security and comfort can be obtained by users of BRT. In addition, the local government is also expected to maintain the quality of services provided. These services include ticket service, the condition of buses, speed and waiting time, as well as the placement and condition of shelters.

  5. Geothermal Program Review VI: proceedings. Beyond goals and objectives

    Energy Technology Data Exchange (ETDEWEB)

    1988-01-01

    Program Review VI was comprised of six sessions, including an opening session, four technical sessions that addressed each of the major DOE research areas, and a session on special issues. The technical sessions were on Hydrothermal, Hot Dry Rock, Geopressured and Magma resources. Presenters in the technical sessions discussed their R and D activities within the context of specific GTD Programmatic Objectives for that technology, their progress toward achieving those objectives, and the value of those achievements to industry. The ''Special Issues'' presentations addressed several topics such as the interactions between government and industry on geothermal energy R and D; the origin and basis for the programmatic objectives analytical computer model; and international marketing opportunities for US geothermal equipment and services. The unique aspect of Program Review VI was that it was held in conjunction with the National Geothermal Association's Industry Round Table on Federal R and D. The Round Table provided a forum for open and lively discussions between industry and government researchers and gave industry an opportunity to convey their needs and perspectives on DOE's research programs. These discussions also provided valuable information to DOE regarding industry's priorities and directions.

  6. Energy levels and radiative rates for transitions in Ti VI

    International Nuclear Information System (INIS)

    Aggarwal, K M; Keenan, F P; Msezane, A Z

    2013-01-01

    We report on calculations of energy levels, radiative rates, oscillator strengths and line strengths for transitions among the lowest 253 levels of the (1s 2 2s 2 2p 6 ) 3s 2 3p 5 , 3s3p 6 , 3s 2 3p 4 3d, 3s3p 5 3d, 3s 2 3p 3 3d 2 , 3s 2 3p 4 4s, 3s 2 3p 4 4p and 3s 2 3p 4 4d configurations of Ti VI. The general-purpose relativistic atomic structure package and flexible atomic code are adopted for the calculations. Radiative rates, oscillator strengths and line strengths are reported for all electric dipole (E1), magnetic dipole (M1), electric quadrupole (E2) and magnetic quadrupole (M2) transitions among the 253 levels, although calculations have been performed for a much larger number of levels. Comparisons are made with existing available results and the accuracy of the data is assessed. Additionally, lifetimes for all 253 levels are listed, although comparisons with other theoretical results are limited to only 88 levels. Our energy levels are estimated to be accurate to better than 1% (within 0.03 Ryd), whereas results for other parameters are probably accurate to better than 20%. A reassessment of the energy level data on the National Institute of Standards and Technology website for Ti VI is suggested. (paper)

  7. Clinical evaluation of complete solo surgery with the "ViKY®" robotic laparoscope manipulator.

    Science.gov (United States)

    Takahashi, Masahiro; Takahashi, Masanori; Nishinari, Naoto; Matsuya, Hideki; Tosha, Tsutomu; Minagawa, Yukihiro; Shimooki, Osamu; Abe, Tadashi

    2017-02-01

    Advancement in both surgical technique and medical equipment has enabled solo surgery. ViKY ® Endoscope Positioning System (ViKY ® ) is a robotic system that remotely controls an endoscope and provides direct vision control to the surgeon. Here, we report our experience with ViKY ® -assisted solo surgery. We retrospectively examined 25 cases of solo surgery TAPP with ViKY ® . ViKY ® was setup by the surgeon alone, and the setup duration was determined as the time at which the side rail was positioned and that when the endoscope was installed. For assessing the control unit, the number of false movements was counted. We compared the operative results between ViKY ® -assisted solo surgery TAPP and the conventional method with an assistant. The average time to set up ViKY ® was 7.9 min. The average number of commands for ViKY ® during surgery was 98.3, and the average number of errors and no response of control unit was 7.9. The mean duration of surgery was 136 min for the ViKY ® group, including the setup time, and 117 min for the conventional method. No case required an assistant during the operation. There was also no difference between the two groups with regard to postoperative complications and the rate of recurrence. ViKY ® proved reliable in recognizing orders with very few failures, and the operations were performed safely and were comparable to the conventional operations with assistants. Solo surgery with ViKY ® was beneficial in this clinical evaluation.

  8. Retention of U(VI) onto silica in presence of model organic molecules

    International Nuclear Information System (INIS)

    Pham, T.T.H.; Mercier-Bion, F.; Drot, R.; Lagarde, G.; Simoni, E.; Lambert, J.

    2008-01-01

    It is well-known that the organic matter influences the retention of ions onto mineral surfaces. However, the major part of concerned studies implies humic substances and complex solids. Another approach for identifying the sorption mechanisms is possible by studying simpler solids than those present in natural medium. So, silica is chosen as mineral surface because of its abundance in soils and of the presence of Si-O groups in clayey minerals. Uranium (VI) is selected as cation. Simple organic molecules like acetic (one carboxylic group) and oxalic (two carboxylic functions) acids are considered as models of the natural organic matter for understanding their role in the retention of U(VI) onto powders and slides of silica. Binary (organics/silica, U(VI)/silica) and ternary systems (organics/silica/U(VI)) are studied by complementary approaches. Sorption edges as function of pH are obtained by liquid scintillation methods and capillary electrophoresis. Different spectroscopic techniques are used to deduce the interactions between the organic matter and U(VI) sorbed onto the silica whose: Time-Resolved Laser induced Fluorescence Spectroscopy (TRLFS), X-ray Photoelectron Spectroscopy (XPS), Nuclear Microprobe Analysis (NMA). The results of the effect of these model organic molecules onto the U(VI) retention showed a good agreement between the different techniques. Concerning the acetic acid, there are not differences in the sorption percentages of uranyl (see the figure). All these results indicate that the uranyl-acetate complexes stay in the aqueous solution rather than sorbing onto the silica. On the contrary, oxalic acid influences the sorption of U(VI) onto the silica surface. The sorption percentage of U(VI) in the ternary system (oxalic acid/silica/U(VI)) is lower than the binary system (U(VI)/silica) (see the figure). So, the presence of oxalic acid decreases the sorption of U(VI) onto the silica surface. (authors)

  9. Probing uranyl(VI) speciation in the presence of amidoxime ligands using electrospray ionization mass spectrometry.

    Science.gov (United States)

    Mustapha, Adetayo M; Pasilis, Sofie P

    2013-10-15

    Extraction processes using poly(acrylamidoxime) resins are being developed to extract uranium from seawater. The main complexing agents in these resins are thought to be 2,6-dihydroxyiminopiperidine (DHIP) and N(1),N(5)-dihydroxypentanediimidamide (DHPD), which form strong complexes with uranyl(VI) at the pH of seawater. It is important to understand uranyl(VI) speciation in the presence of these and similar amidoxime ligands to understand factors affecting uranyl(VI) adsorption to the poly(acrylamidoxime) resins. Experiments were carried out in positive ion mode on a quadrupole ion trap mass spectrometer equipped with an electrospray ionization source. The ligands investigated were DHIP, DHPD, and N(1),N(2)-dihydroxyethanediimidamide (DHED). DHED and DHPD differ only in the number of carbons separating the oxime groups. The effects on the mass spectra of changes in uranyl(VI):ligand ratio, pH, and ligand type were examined. DHIP binds uranyl(VI) more effectively than DHPD or DHED in the pH range investigated, forming ions derived from solution-phase species with uranyl(VI):DHIP stoichiometries of 1:1, 1:2, and 2:3. The 2:3 uranyl(VI):DHIP complex appears to be a previously undescribed solution species. Ions related to uranyl(VI):DHPD complexes were detected in very low abundance. DHED is a more effective complexing agent for uranyl(VI) than DHPD, forming ions having uranyl(VI):DHED stoichiometries of 1:1, 1:2, 1:3, and 2:3. This study presents a first look at the solution chemistry of uranyl(VI)-amidoxime complexes using electrospray ionization mass spectrometry. The appearance of previously undescribed solution species suggests that the uranyl-amidoxime system is a rich and relatively complex one, requiring a more in-depth investigation. Copyright © 2013 John Wiley & Sons, Ltd.

  10. Chromium(VI) generation in vadose zone soils and alluvial sediments of the southwestern Sacramento Valley, California: a potential source of geogenic Cr(VI) to groundwater

    Science.gov (United States)

    Mills, Christopher T.; Morrison, Jean M.; Goldhaber, Martin B.; Ellefsen, Karl J.

    2011-01-01

    Concentrations of geogenic Cr(VI) in groundwater that exceed the World Health Organization’s maximum contaminant level for drinking water (50 μg L−1) occur in several locations globally. The major mechanism for mobilization of this Cr(VI) at these sites is the weathering of Cr(III) from ultramafic rocks and its subsequent oxidation on Mn oxides. This process may be occurring in the southern Sacramento Valley of California where Cr(VI) concentrations in groundwater can approach or exceed 50 μg L−1. To characterize Cr geochemistry in the area, samples from several soil auger cores (approximately 4 m deep) and drill cores (approximately 25 m deep) were analyzed for total concentrations of 44 major, minor and trace elements, Cr associated with labile Mn and Fe oxides, and Cr(VI). Total concentrations of Cr in these samples ranged from 140 to 2220 mg per kg soil. Between 9 and 70 mg per kg soil was released by selective extractions that target Fe oxides, but essentially no Cr was associated with the abundant reactive Mn oxides (up to ~1000 mg hydroxylamine-reducible Mn per kg soil was present). Both borehole magnetic susceptibility surveys performed at some of the drill core sites and relative differences between Cr released in a 4-acid digestion versus total Cr (lithium metaborate fusion digestion) suggest that the majority of total Cr in the samples is present in refractory chromite minerals transported from ultramafic exposures in the Coast Range Mountains. Chromium(VI) in the samples studied ranged from 0 to 42 μg kg−1, representing a minute fraction of total Cr. Chromium(VI) content was typically below detection in surface soils (top 10 cm) where soil organic matter was high, and increased with increasing depth in the soil auger cores as organic matter decreased. Maximum concentrations of Cr(VI) were up to 3 times greater in the deeper drill core samples than the shallow auger cores. Although Cr(VI) in these vadose zone soils and sediments was only a

  11. Study of new U(VI) and Pu(VI) coprecipitation methods for the preparation of (U,Pu)O2

    International Nuclear Information System (INIS)

    Sanoit, J. de.

    1990-01-01

    Two U(VI) and Pu(VI) coprecipitation methods have been studied, for the definition of new processes to prepare (U,Pu)O 2 mixed oxides suitable for making MoX fuels or fast breeder reactor fuels. The first system is based on the coprecipitation of a new U(VI), Pu(VI) compound; ammonium uranoplutonate, where as a second system is related to the precipitation of uranyl plutonyl monocarbonate. Experimental conditions to optimize the precipitation and the filtration steps of these two systems have been determined. After calcination under reducing conditions, the mixed oxides obtained are characterized according to different techniques: granulometry, thermogravimetry, solubility in boiling HNO 3 solutions. The properties of such oxides are excellent. The possible processes for preparing (U, Pu)O 2 using these new routes are compared with those actually exploited [fr

  12. Titanium dioxide-based DGT for measuring dissolved As(V), V(V), Sb(V), Mo(VI) and W(VI) in water

    DEFF Research Database (Denmark)

    Panther, Jared G.; Stewart, Ryan R.; Teasdale, Peter R.

    2013-01-01

    A titanium dioxide-based DGT method (Metsorb-DGT) was evaluated for the measurement of As(V), V(V), Sb(V), Mo(VI), W(VI) and dissolved reactive phosphorus (DRP) in synthetic waters. Mass vs. time DGT deployments at pH 6.06 (0.01 mol L-1 NaNO3) demonstrated linear uptake of all analytes (R2...... for deployment times >4 h (CDGT=0.27-0.72). For ferrihydrite-DGT, CDGT/CSol values in the range 0.92-1.16 were obtained for As(V), V(V) and DRP, however, Mo(VI), Sb(V) and W(VI) could not be measured to within 15% of the solution concentration (C DGT/CSol 0.02-0.83)....

  13. Microbial Precipitation of Cr(III)-Hydroxide and Se(0) Nanoparticles During Anoxic Bioreduction of Cr(VI)- and Se(VI)-Contaminated Water.

    Science.gov (United States)

    Kim, Yumi; Oh, Jong-Min; Roh, Yul

    2017-04-01

    This study examined the microbial precipitations of Cr(III)-hydroxide and Se(0) nanoparticles during anoxic bioreductions of Cr(VI) and Se(VI) using metal-reducing bacteria enriched from groundwater. Metal-reducing bacteria enriched from groundwater at the Korea Atomic Energy Research Institute (KAERI) Underground Research Tunnel (KURT), Daejeon, S. Korea were used. Metal reduction and precipitation experiments with the metal-reducing bacteria were conducted using Cr(VI)- and Se(VI)-contaminated water and glucose as a carbon source under an anaerobic environment at room temperature. XRD, SEM-EDX, and TEM-EDX analyses were used to characterize the mineralogy, crystal structure, chemistry, shape, and size distribution of the precipitates. The metal-reducing bacteria reduced Cr(VI) of potassium chromate (K₂CrO₄) to Cr(III) of chromium hydroxide [Cr(OH)3], and Se(VI) of sodium selenate (Na₂SeO₄) to selenium Se(0), with changes of color and turbidity. XRD, SEM-EDX, and TEM-EDX analyses revealed that the chromium hydroxide [Cr(OH)₃] was formed extracellularly with nanoparticles of 20–30 nm in size, and elemental selenium Se(0) nanoparticles had a sphere shape of 50–250 nm in size. These results show that metal-reducing bacteria in groundwater can aid or accelerate precipitation of heavy metals such as Cr(VI) and Se(VI) via bioreduction processes under anoxic environments. These results may also be useful for the recovery of Cr and Se nanoparticles in natural environments.

  14. A Salmonella Typhimurium-Typhi genomic chimera: a model to study Vi polysaccharide capsule function in vivo.

    Directory of Open Access Journals (Sweden)

    Angela M Jansen

    2011-07-01

    Full Text Available The Vi capsular polysaccharide is a virulence-associated factor expressed by Salmonella enterica serotype Typhi but absent from virtually all other Salmonella serotypes. In order to study this determinant in vivo, we characterised a Vi-positive S. Typhimurium (C5.507 Vi(+, harbouring the Salmonella pathogenicity island (SPI-7, which encodes the Vi locus. S. Typhimurium C5.507 Vi(+ colonised and persisted in mice at similar levels compared to the parent strain, S. Typhimurium C5. However, the innate immune response to infection with C5.507 Vi(+ and SGB1, an isogenic derivative not expressing Vi, differed markedly. Infection with C5.507 Vi(+ resulted in a significant reduction in cellular trafficking of innate immune cells, including PMN and NK cells, compared to SGB1 Vi(- infected animals. C5.507 Vi(+ infection stimulated reduced numbers of TNF-α, MIP-2 and perforin producing cells compared to SGB1 Vi(-. The modulating effect associated with Vi was not observed in MyD88(-/- and was reduced in TLR4(-/- mice. The presence of the Vi capsule also correlated with induction of the anti-inflammatory cytokine IL-10 in vivo, a factor that impacted on chemotaxis and the activation of immune cells in vitro.

  15. Proceeding of the Scientific Presentation on Nuclear Fuel Cycle; Prosiding Presentasi Ilmiah Daur Bahan Bakar Nuklir

    Energy Technology Data Exchange (ETDEWEB)

    Suripto, A; Yuwono, I; Nasution, H; Hersubeno, B J; Amini, S; Sigit,; Cahyono, A [Nuclear Fuel Elements Development Centre, National Atomic Energy Agency, Serpong, Indonesia (Indonesia)

    1996-11-01

    The proceeding contains papers presented on Scientific Presentation on Nuclear Fuel Cycle held in Jakarta, 18-19 March 1996. These are 46 papers resulted from scientific works on various disciplines which have supported to nuclear fuel cycle activities both in and outside National Atomic Energy Agency of Indonesia.(ID)

  16. 6. Dampak Program Pengembangan Nuklir Korea Utara Terhadap Hubungan Bilateralnya Dengan Tiongkok Tahun 2013 – 2015

    OpenAIRE

    Isnaeni, Nur Afiyah; Utomo, Tri Cahyo; Hanura, Marten

    2017-01-01

    China and North Korea have had good bilateral relations, as the result of their geographical proximity and their similar ideology (communist). China's status as a member of the UN Security Council and its stable economy, causes North Korea to depend on diplomatic and economic support from China. North Korea needs diplomatic support from China because its nuclear proliferation since North Korea decided to withdraw from the non-proliferation treaty. As North Korea's closest ally, China provided...

  17. The Operation Consequence of Nuclear Energy to Environment; Konsekuensi Pengoperasian Tenaga Nuklir terhadap Lingkungan

    Energy Technology Data Exchange (ETDEWEB)

    Suhariyono, Gatot; Sutarman, [Center for Research and Development of Radiation Safety and Nuclear Biomedicine, (Indonesia)

    2003-08-15

    Objective of the paper is to give information the operation consequence of nuclear energy to environment, so that expected as organizer of PLTN can anticipate or depress as minimum as possible radiology impact to the radiation workers and society in general, and also socialization that operation of nuclear energy do not give the negative impact, if conducted its control to environment seriously. Parts of which it is important to know from this paper are : one. Estimate of equivalent dose of collective effective in a normal condition is the operation cycle for nuclear energy at worker and local or regional resident 10, 100 or 10.000 next years. 2. Equivalent dose of global collective effective is for various the radiation sources. 3. Estimate of dose per cap ut annual of nuclear electric power until year 2500. 4. Aspect of non-radiology is to cooler system, usage of farm, dismissal of chemistry, advantage of hot water waste, its effect to fish, benthos, plankton, vegetation, animal and preparation of nuclear emergency.

  18. Perekayasaan Heat Exchanger Sebagai Pemanas Umpan Uf 6 Dalam Pabrik Elemen Bakar Nuklir

    OpenAIRE

    Zacharias, Petrus; Pancoko, Marliyadi

    2011-01-01

    DESIGN OF HEAT EXCHANGER FOR HEATING UF6 FEED IN NUCLEAR FUEL ELEMENT PLANT. The process of conversion of UF6 to UO through Integrated Dry Route (IDR) i s done in a rotary kiln reactor. There are two stages of initi al treatment / conditioni ng before inserting the UF 6 in to the reactor : changing UF6 2 solid into the gas phase at a temperature of 60°C in an evaporator, and then, raising the temperature of UF C to 2900 C i n a Heat Exchanger (HE). Therefore it i s necessary to desi gn...

  19. combined effect of polyaniline emeraldine salt for removal of Cr(VI)

    Indian Academy of Sciences (India)

    Cr(VI) ion is one of the major industrial wastes as dichromate and chromate ions are ... more [9–12]. For the toxic nature of Cr(VI) in aqueous medium, it becomes a ... techniques such as adsorption [13–15], chemical reduction. [16], reverse ...

  20. Enhanced Cr(VI) removal by polyethylenimine- and phosphorus-codoped hierarchical porous carbons.

    Science.gov (United States)

    Chen, Shixia; Wang, Jun; Wu, Zeliang; Deng, Qiang; Tu, Wenfeng; Dai, Guiping; Zeng, Zheling; Deng, Shuguang

    2018-08-01

    The amino- and phosphorus-codoped (N,P-codoped) porous carbons derived from oil-tea shells were facilely fabricated through a combination of phosphoric acid (H 3 PO 4 ) activation and amino (polyethylenimine, PEI) modification method. The as-synthesized carbon adsorbents were systematically characterized and evaluated for Cr(VI) removal in aqueous solutions. The relationship between adsorbent properties and adsorption behaviors was illustrated. Moreover, the influences of contact time, initial Cr(VI) concentration, pH, coexisting anions and temperature were also investigated. The adsorption behavior of Cr(VI) could be perfectly described by the pseudo-second-order kinetic model and Sips adsorption model. The maximum adsorption capacity of Cr(VI) on the carbon adsorbents synthesized in this work was 355.0 mg/g, and this excellent Cr(VI) capacity could be sustained with other coexisting anions. In addition to high surface area and suitable pore size distribution, the high Cr(VI) removal capacity is induced by rich heteroatoms incorporation and the Cr(VI) removal mechanism was clearly illustrated. Furthermore, the continuous column breakthrough experiment on obtained N,P-codoped carbon was conducted and well fitted by the Thomas model. This work revealed that PEI modification and P-containing groups could significantly enhance Cr(VI) adsorption capacity and make these N,P-codoped biomass-derived carbons potent adsorbents in practical water treatment applications. Copyright © 2018 Elsevier Inc. All rights reserved.

  1. Photoreduction of chromium(VI) in the presence of algae, Chlorella vulgaris

    International Nuclear Information System (INIS)

    Deng Lin; Wang Hongli; Deng Nansheng

    2006-01-01

    In this thesis, the photochemical reduction of hexavalent chromium Cr(VI) in the presence of algae, Chlorella vulgaris, was investigated under the irradiation of metal halide lamps (λ=365nm, 250W). The affecting factors of photochemical reduction were studied in detail, such as exposure time, initial Cr(VI) concentration, initial algae concentration and pH. The rate of Cr(VI) photochemical reduction increased with algae concentration increasing, exposure time increasing, initial Cr(VI) concentration decreasing and the decrease of pH. When pH increased to 6, the rate of Cr(VI) photochemical reduction nearly vanished. When initial Cr(VI) concentration ranged from 0.4 to 1.0mgL -1 and initial algae concentration ranged from ABS algae (the absorbency of algae)=0.025 to ABS algae =0.180, According to the results of kinetic analyses, the kinetic equation of Cr(VI) photochemical reduction in aqueous solution with algae under 250W metal halide lamps was V 0 =kC 0 0.1718 A algae 0.5235 (C 0 was initial concentration of Cr(VI); A algae was initial concentration of algae) under the condition of pH 4

  2. Delineation and Diagnostic Criteria of Oral-Facial-Digital Syndrome Type VI

    NARCIS (Netherlands)

    Poretti, Andrea; Vitiello, Giuseppina; Hennekam, Raoul C. M.; Arrigoni, Filippo; Bertini, Enrico; Borgatti, Renato; Brancati, Francesco; D'Arrigo, Stefano; Faravelli, Francesca; Giordano, Lucio; Huisman, Thierry A. G. M.; Iannicelli, Miriam; Kluger, Gerhard; Kyllerman, Marten; Landgren, Magnus; Lees, Melissa M.; Pinelli, Lorenzo; Romaniello, Romina; Scheer, Ianina; Schwarz, Christoph E.; Spiegel, Ronen; Tibussek, Daniel; Valente, Enza Maria; Boltshauser, Eugen

    2012-01-01

    Oral-Facial-Digital Syndrome type VI (OFD VI) represents a rare phenotypic subtype of Joubert syndrome and related disorders (JSRD). In the original report polydactyly, oral findings, intellectual disability, and absence of the cerebellar vermis at post-mortem characterized the syndrome.

  3. Osmium(VI) complexes as a new class of potential anti-cancer agents.

    Science.gov (United States)

    Ni, Wen-Xiu; Man, Wai-Lun; Cheung, Myra Ting-Wai; Sun, Raymond Wai-Yin; Shu, Yuan-Lan; Lam, Yun-Wah; Che, Chi-Ming; Lau, Tai-Chu

    2011-02-21

    A nitridoosmium(VI) complex [Os(VI)(N)(sap)(OH(2))Cl] (H(2)sap = N-salicylidene-2-aminophenol) displays prominent in vitro and in vivo anti-cancer properties, induces S- and G2/M-phase arrest and forms a stable adduct with dianionic 5'-guanosine monophosphate.

  4. Polyaniline (PANI) modified bentonite by plasma technique for U(VI) removal from aqueous solution

    International Nuclear Information System (INIS)

    Liu, Xinghao; Cheng, Cheng; Xiao, Chengjian; Shao, Dadong; Xu, Zimu; Wang, Jiaquan; Hu, Shuheng; Li, Xiaolong; Wang, Weijuan

    2017-01-01

    Highlights: • PANI/bentonie can be synthesized by simple plasma technique. • PANI/bentonie has an excellent adsorption capacity for trace uranium in solution. • U(VI) adsorption on PANI/bentonite is a spontaneous and endothermic process. - Abstract: Polyaniline (PANI) modified bentonite (PANI/bentonie) was synthesized by plasma induced polymerization of aniline on bentonite surface, and applied to uptake of uranium(VI) ions from aqueous solution. The as-synthesized PANI/bentonie was characterized by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Batch adsorption technique was utilized to investigate the adsorption of U(VI) on bentonite and PANI/bentonite. The adsorption of U(VI) (10 mg/L) on PANI/bentonite surface is fairly depend on solution pH, ionic strength, and temperature in solution. The modified PANI on PANI/bentonite surface significantly enhances its adsorption capability for U(VI). The presence of humic acid (HA) can sound enhance U(VI) adsorption on PANI/bentonite at pH 6.5. According to the thermodynamic parameters, the adsorption of U(VI) on PANI/bentonite surface is a spontaneous and endothermic process. The results highlight the application of PANI/bentonite composites as candidate material for the uptake of trace U(VI) from aqueous solution.

  5. Oxidation of ciprofloxacin and enrofloxacin by ferrate(VI): Products identification, and toxicity evaluation

    International Nuclear Information System (INIS)

    Yang, Bin; Kookana, Rai S.; Williams, Mike; Ying, Guang-Guo; Du, Jun; Doan, Hai; Kumar, Anupama

    2016-01-01

    Ferrate(VI) (Fe(VI)) has been known to react with emerging organic contaminants containing electron-rich organic moieties, such as phenols, anilines, olefins, reduced sulfur and deprotonated amines. Oxidation of fluoroquinolone antibiotics, ciprofloxacin (CIP) and enrofloxacin (ENR), by Fe(VI) were investigated for their reaction products and toxicity changes as well as biodegradability of these products. Ten products were identified for both CIP and ENR reactions with Fe(VI) using a high-resolution accurate-mass Orbitrap mass analyzer. Structural changes to the CIP and ENR molecule included dealkylation, formation of alcohols and amides in piperazine ring and oxygen transfer to the double bond in quinolone structure. An enamine formation mechanism was tentatively proposed to facilitate the interpretation of CIP and ENR oxidation pathways. Toxicity evaluation using Microbial Assay for toxicity Risk Assessment (MARA) bioassay indicated that Fe(VI) oxidation products of CIP and ENR contributed negligible antibacterial potency and Fe(VI) oxidation treatment can remove the residual toxicity of CIP and ENR impacted source waters. The Fe(VI) oxidation treatment resulted in formation of relatively more biodegradable products (based on in silico assessment) than their corresponding parent compounds. The results showed that Fe(VI) has a good potential to degrade fluoroquinolone antibiotics and their antimicrobial potency in natural waters.

  6. Oxidation of ciprofloxacin and enrofloxacin by ferrate(VI): Products identification, and toxicity evaluation

    Energy Technology Data Exchange (ETDEWEB)

    Yang, Bin, E-mail: Bin.Yang@csiro.au [CSIRO Land and Water, Waite Campus, PMB 2, Glen Osmond, South Australia 5064 (Australia); Kookana, Rai S.; Williams, Mike [CSIRO Land and Water, Waite Campus, PMB 2, Glen Osmond, South Australia 5064 (Australia); Ying, Guang-Guo [State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 (China); Du, Jun; Doan, Hai; Kumar, Anupama [CSIRO Land and Water, Waite Campus, PMB 2, Glen Osmond, South Australia 5064 (Australia)

    2016-12-15

    Ferrate(VI) (Fe(VI)) has been known to react with emerging organic contaminants containing electron-rich organic moieties, such as phenols, anilines, olefins, reduced sulfur and deprotonated amines. Oxidation of fluoroquinolone antibiotics, ciprofloxacin (CIP) and enrofloxacin (ENR), by Fe(VI) were investigated for their reaction products and toxicity changes as well as biodegradability of these products. Ten products were identified for both CIP and ENR reactions with Fe(VI) using a high-resolution accurate-mass Orbitrap mass analyzer. Structural changes to the CIP and ENR molecule included dealkylation, formation of alcohols and amides in piperazine ring and oxygen transfer to the double bond in quinolone structure. An enamine formation mechanism was tentatively proposed to facilitate the interpretation of CIP and ENR oxidation pathways. Toxicity evaluation using Microbial Assay for toxicity Risk Assessment (MARA) bioassay indicated that Fe(VI) oxidation products of CIP and ENR contributed negligible antibacterial potency and Fe(VI) oxidation treatment can remove the residual toxicity of CIP and ENR impacted source waters. The Fe(VI) oxidation treatment resulted in formation of relatively more biodegradable products (based on in silico assessment) than their corresponding parent compounds. The results showed that Fe(VI) has a good potential to degrade fluoroquinolone antibiotics and their antimicrobial potency in natural waters.

  7. Adsorption of Cu(II) and Cr(VI) ions by chitosan: kinetics and ...

    African Journals Online (AJOL)

    The ability of chitosan as an adsorbent for Cu (II) and Cr (VI) ions in aqueous solution was studied. The experiments were done as batch processes. Equilibrium studies were done on both cross-linked and non-cross-linked chitosan for both metals. Cr (VI) adsorption behaviour could be described using the Langmuir ...

  8. Modelling biological Cr(VI) reduction in aquifer microcosm column systems.

    Science.gov (United States)

    Molokwane, Pulane E; Chirwa, Evans M N

    2013-01-01

    Several chrome processing facilities in South Africa release hexavalent chromium (Cr(VI)) into groundwater resources. Pump-and-treat remediation processes have been implemented at some of the sites but have not been successful in reducing contamination levels. The current study is aimed at developing an environmentally friendly, cost-effective and self-sustained biological method to curb the spread of chromium at the contaminated sites. An indigenous Cr(VI)-reducing mixed culture of bacteria was demonstrated to reduce high levels of Cr(VI) in laboratory samples. The effect of Cr(VI) on the removal rate was evaluated at concentrations up to 400 mg/L. Following the detailed evaluation of fundamental processes for biological Cr(VI) reduction, a predictive model for Cr(VI) breakthrough through aquifer microcosm reactors was developed. The reaction rate in batch followed non-competitive rate kinetics with a Cr(VI) inhibition threshold concentration of approximately 99 mg/L. This study evaluates the application of the kinetic parameters determined in the batch reactors to the continuous flow process. The model developed from advection-reaction rate kinetics in a porous media fitted best the effluent Cr(VI) concentration. The model was also used to elucidate the logistic nature of biomass growth in the reactor systems.

  9. Chromium VI and stomach cancer: a meta-analysis of the current epidemiological evidence.

    Science.gov (United States)

    Welling, Roberta; Beaumont, James J; Petersen, Scott J; Alexeeff, George V; Steinmaus, Craig

    2015-02-01

    Chromium VI (hexavalent chromium, Cr(VI)) is an established cause of lung cancer, but its association with gastrointestinal cancer is less clear. The goal of this study was to examine whether the current human epidemiological research on occupationally inhaled Cr(VI) supports the hypothesis that Cr(VI) is associated with human stomach cancer. Following a thorough literature search and review of individual studies, we used meta-analysis to summarise the current epidemiological literature on inhaled Cr(VI) and stomach cancer, explore major sources of heterogeneity, and assess other elements of causal inference. We identified 56 cohort and case-control studies and 74 individual relative risk (RR) estimates on stomach cancer and Cr(VI) exposure or work in an occupation associated with high Cr(VI) exposure including chromium production, chrome plating, leather work and work with Portland cement. The summary RR for all studies combined was 1.27 (95% CI 1.18 to 1.38). In analyses limited to only those studies identifying increased risks of lung cancer, the summary RR for stomach cancer was higher (RR=1.41, 95% CI 1.18 to 1.69). Overall, these results suggest that Cr(VI) is a stomach carcinogen in humans, which is consistent with the tumour results reported in rodent studies. Published by the BMJ Publishing Group Limited. For permission to use (where not already granted under a licence) please go to http://group.bmj.com/group/rights-licensing/permissions.

  10. Cr(III) and Cr(VI) in leather and elicitation of eczema

    DEFF Research Database (Denmark)

    Hansen, Malene Barré; Menne, Torkil; Johansen, Jeanne Duus

    2006-01-01

    The aim of the present study was to investigate the relation between the content of Cr(VI) and soluble Cr(III) in leather and the ability of the leather to elicit eczema in chromium allergic patients. An array of chromium-tanned leather samples was analysed for the content of total Cr(VI) and sol...

  11. Electrochemical processes for the environmental remediation of toxic Cr(VI): A review

    International Nuclear Information System (INIS)

    Jin, Wei; Du, Hao; Zheng, Shili; Zhang, Yi

    2016-01-01

    Highlights: • Recent advances in electrochemical technologies for practical Cr(VI) treatment applications was reviewed. • The mechanism and performance of electrocoagulation, electrochemical reduction, electrodialysis, electro-electrodialysis and electrodeionization were discussed and compared. • The remained challenges and future perspectives were commented. - Abstract: Hexavalent chromium Cr(VI) is extremely toxic and classified as one of the 17 chemicals posing the greatest threat to humans. Large amounts of Cr(VI) compounds are directly or indirectly discharged into the environment, therefore considerable efforts have been made to control the Cr(VI) concentration below the recommended level. It has been demonstrated that electrochemical technique is one of the most efficient and environmental benign approach for the Cr(VI) removal. This review aims at recent advances in electrochemical technology for practical Cr(VI) treatment applications. By using the “clean reagent” of electron, Cr(VI) can be completely eliminated or separated via different electrochemical techniques such as electrocoagulation, electrochemical reduction, electrodialysis, electro-electrodialysis and electrodeionization. Besides, the mechanism and performance of different strategies are commented and compared. The treatment process is largely dependent on variables such as pH, electrode materials, cell configuration and techniques integration. Furthermore, the remained limitation and challenges for the electrochemical Cr(VI) remediation are also discussed.

  12. Photoreduction of chromium(VI) in the presence of algae, Chlorella vulgaris

    Energy Technology Data Exchange (ETDEWEB)

    Deng Lin [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China); Wang Hongli [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China); Deng Nansheng [School of Resources and Environmental Science, Wuhan University, Wuhan 430072 (China)]. E-mail: nsdengwhu@163.com

    2006-11-16

    In this thesis, the photochemical reduction of hexavalent chromium Cr(VI) in the presence of algae, Chlorella vulgaris, was investigated under the irradiation of metal halide lamps ({lambda}=365nm, 250W). The affecting factors of photochemical reduction were studied in detail, such as exposure time, initial Cr(VI) concentration, initial algae concentration and pH. The rate of Cr(VI) photochemical reduction increased with algae concentration increasing, exposure time increasing, initial Cr(VI) concentration decreasing and the decrease of pH. When pH increased to 6, the rate of Cr(VI) photochemical reduction nearly vanished. When initial Cr(VI) concentration ranged from 0.4 to 1.0mgL{sup -1} and initial algae concentration ranged from ABS{sub algae} (the absorbency of algae)=0.025 to ABS{sub algae}=0.180, According to the results of kinetic analyses, the kinetic equation of Cr(VI) photochemical reduction in aqueous solution with algae under 250W metal halide lamps was V{sub 0}=kC{sub 0}{sup 0.1718}A{sub algae}{sup 0.5235} (C{sub 0} was initial concentration of Cr(VI); A{sub algae} was initial concentration of algae) under the condition of pH 4.

  13. Kinetics of Cr(III) and Cr(VI) removal from water by two floating macrophytes.

    Science.gov (United States)

    Maine, M A; Hadad, H R; Sánchez, G; Caffaratti, S; Pedro, M C

    2016-01-01

    The aim of this work was to compare Cr(III) and Cr(VI) removal kinetics from water by Pistia stratiotes and Salvinia herzogii. The accumulation in plant tissues and the effects of both Cr forms on plant growth were also evaluated. Plants were exposed to 2 and 6 mg L(-1) of Cr(III) or Cr(VI) during 30 days. At the end of the experiment, Cr(VI) removal percentages were significantly lower than those obtained for Cr(III) for both macrophytes. Cr(III) removal kinetics involved a fast and a slow component. The fast component was primarily responsible for Cr(III) removal while Cr(VI) removal kinetics involved only a slow process. Cr accumulated principally in the roots. In the Cr(VI) treatments a higher translocation from roots to aerial parts than in Cr(III) treatments was observed. Both macrophytes demonstrated a high ability to remove Cr(III) but not Cr(VI). Cr(III) inhibited the growth at the highest studied concentration of both macrophytes while Cr(VI) caused senescence. These results have important implications in the use of constructed wetlands for secondary industrial wastewater treatment. Common primary treatments of effluents containing Cr(VI) consists in its reduction to Cr(III). Cr(III) concentrations in these effluents are normally below the highest studied concentrations in this work.

  14. Simultaneous Cr(VI) bio-reduction and methane production by anaerobic granular sludge.

    Science.gov (United States)

    Hu, Qian; Sun, Jiaji; Sun, Dezhi; Tian, Lan; Ji, Yanan; Qiu, Bin

    2018-08-01

    Wastewater containing toxic hexavalent chromium (Cr(VI)) were treated with well-organized anaerobic granular sludge in this study. Results showed that the anaerobic granular sludge rapidly removed Cr(VI), and 2000 µg·L -1 Cr(VI) was completely eliminated within 6 min, which was much faster than the reported duration of removal by reported artificial materials. Sucrose added as a carbon source acted as an initial electron donor to reduce Cr(VI) to Cr(III). This process was considered as the main mechanism of Cr(VI) removal. Methane production by anaerobic granular sludge was improved by the addition of Cr(VI) at a concentration lower than 500 µg·L -1 . Anaerobic granular sludge had a well-organized structure, which presented good resistance against toxic Cr(VI). Trichoccus accelerated the degradation of organic substances to generate acetates with a low Cr(VI) concentration, thereby enhancing methane production by acetotrophic methanogens. Copyright © 2018 Elsevier Ltd. All rights reserved.

  15. Microbial Fuel Cell Inoculated with Ochrobactrum Tritici KCC210 for Chromium (VI) Measurement in Electroplating Wastewater

    Science.gov (United States)

    Kuo, Jongtar; Kuo, Juiling; Cheng, Chiuyu; Chung, Yingchien

    2018-01-01

    Many methods/techniques have been developed for Cr(VI) measurement, but they are often conducted offsite or/and cannot provide real-time for Cr(VI) monitoring. A microbial fuel cell (MFC) is a self-sustaining device and has great potential as a biosensor for in situ Cr(VI) measurement, especially for wastewater generated from different electroplating units. In this study, Ochrobactrum tritici KCC210, a facultatively anaerobic, Cr(VI)-reducing, and exoelectrogenic bacterium, was isolated and inoculated into the MFC to evaluate its feasibility as a Cr(VI) biosensor. The results indicated that O. tritici KCC210 exhibited high adaptability to pH, and temperature under anaerobic conditions. The maximum power density of the MFC biosensor was 17.5±0.9 mW/m2 at 2,000 Ω. A good linear relationship was observed between the Cr(VI) concentration (10-80 mg/L) and voltage output. The stable performance of the MFC biosensor indicated its potential as a reliable biosensor system. Moreover, the developed MFC biosensor is a simple device that can accurately measure Cr(VI) concentrations in the actual electroplating wastewater generated from different electroplating units within 15 min with low deviations (-1.8% to 7.8%) in comparison with the values determined using standard method. Thus, the MFC biosensor can measure Cr(VI) concentrations in situ in the effluents and has potential as an early warning detection device.

  16. Removal of chromium (VI) from electroplating wastewater using an anion exchanger derived from rice straw.

    Science.gov (United States)

    Cao, Wei; Dang, Zhi; Yia, Xiao-Yun; Yang, Chen; Lu, Gui-Ning; Liu, Yun-Feng; Huang, Se-Yan; Zheng, Liu-Chun

    2013-01-01

    An anion exchanger from rice straw was used to remove Cr (VI) from synthetic wastewater and electroplating effluent. The exchanger was characterized using Fourier transform infrared (FTIR) spectrum and scanning electron microscopy (SEM), and it was found that the quaternary amino group and hydroxyl group are the main functional groups on the fibrous surface of the exchanger. The effect of contact time, initial concentration and pH on the removal of Cr (VI), and adsorption isotherms at different temperature, was investigated. The results showed that the removal of Cr (VI) was very rapid and was significantly affected by the initial pH of the solution. Although acidic conditions (pH = 2-6) facilitated Cr (VI) adsorption, the exchanger was effective in neutral solution and even under weak base conditions. The equilibrium data fitted well with Langmuir adsorption model, and the maximum Cr (VI) adsorption capacities at pH 6.4 were 0.35, 0.36 and 0.38 mmol/g for 15, 25 and 35 degrees C, respectively. The exchanger was finally tested with real electroplating wastewater, and at sorbent dosage of 10 g/L, the removal efficiencies for Cr (VI) and total Cr were 99.4% and 97.8%, respectively. In addition, the positive relationship between adsorbed Cr (VI) and desorbed Cl- suggested that Cr (VI) was mainly removed by ion exchange with chlorine.

  17. 28 CFR 42.405 - Public dissemination of title VI information.

    Science.gov (United States)

    2010-07-01

    ... Federally Assisted Programs § 42.405 Public dissemination of title VI information. (a) Federal agencies... 28 Judicial Administration 1 2010-07-01 2010-07-01 false Public dissemination of title VI information. 42.405 Section 42.405 Judicial Administration DEPARTMENT OF JUSTICE NONDISCRIMINATION; EQUAL...

  18. 75 FR 22168 - Region VI-Houston District; Advisory Council Meeting; Public Meeting

    Science.gov (United States)

    2010-04-27

    ... SMALL BUSINESS ADMINISTRATION Region VI--Houston District; Advisory Council Meeting; Public Meeting The Small Business Administration-Region VI--Houston Advisory Council, located in the geographical Area of Houston, Texas will hold a federal public meeting on--Thursday, May 20, 2010, starting at 10:30...

  19. 76 FR 36564 - Notice of Submission of Proposed Information Collection to OMB; HOPE VI Application

    Science.gov (United States)

    2011-06-22

    ... Proposed Information Collection to OMB; HOPE VI Application AGENCY: Office of the Chief Information Officer... to allow HUD to obligate grant funds in accordance with the HOPE VI program authorizing statute, and... electronic submission of responses. This notice also lists the following information: Title of Proposal: HOPE...

  20. Microbial conversion of Cr (VI) in to Cr (III) in industrial effluent ...

    African Journals Online (AJOL)

    These bacterial strains also take up and reduce Cr (VI) present in industrial effluents, and their reduction potential was not significantly affected in the presence of different metallic salts. Key Words: Cr (VI) reduction, bacteria, industrial effluent, heavy metals. African Journal of Biotechnology Vol.3(11) 2004: 610-617 ...

  1. Chromium (VI) biosorption properties of multiple resistant bacteria isolated from industrial sewerage.

    Science.gov (United States)

    Oyetibo, Ganiyu Oladunjoye; Ilori, Matthew Olusoji; Obayori, Oluwafemi Sunday; Amund, Olukayode Oladipo

    2013-08-01

    Chromium (VI) [Cr (VI)] biosorption by four resistant autochthonous bacterial strains was investigated to determine their potential for use in sustainable marine water-pollution control. Maximum exchange between Cr (VI) ions and protons on the cells surfaces were at 30-35 °C, pH 2.0 and 350-450 mg/L. The bacterial strains effectively removed 79.0-90.5 % Cr (VI) ions from solution. Furthermore, 85.3-93.0 % of Cr (VI) ions were regenerated from the biomasses, and 83.4-91.7 % of the metal was adsorbed when the biomasses was reused. Langmuir isotherm performed better than Freundlich isotherm, depicting that Cr (VI) affinity was in the sequence Rhodococcus sp. AL03Ni > Burkholderia cepacia AL96Co > Corynebacterium kutscheri FL108Hg > Pseudomonas aeruginosa CA207Ni. Biosorption isotherms confirmed that Rhodococcus sp. AL03Ni was a better biosorbent with a maximum uptake of 107.46 mg of Cr (VI) per g (dry weight) of biomass. The results highlight the high potential of the organisms for bacteria-based detoxification of Cr (VI) via biosorption.

  2. Modelling Cr(VI) removal by a combined carbon-activated sludge system

    International Nuclear Information System (INIS)

    Orozco, A. Micaela Ferro; Contreras, Edgardo M.; Zaritzky, Noemi E.

    2008-01-01

    The combined carbon-activated sludge process has been proposed as an alternative to protect the biomass against toxic substances in wastewaters; however, the information about the effect of powdered-activated carbon (PAC) addition in activated sludge reactors for the treatment of wastewaters containing Cr(VI) is limited. The objectives of the present study were: (a) to evaluate the removal of hexavalent chromium by (i) activated sludge microorganisms in aerobic batch reactors, (ii) powdered-activated carbon, and (iii) the combined action of powdered-activated carbon and biomass; (b) to propose mathematical models that interpret the experimental results. Different Cr(VI) removal systems were tested: (S1) biomass (activated sludge), (S2) PAC, and (S3) the combined activated carbon-biomass system. A Monod-based mathematical model was used to describe the kinetics of Cr(VI) removal in the system S1. A first-order kinetics with respect to Cr(VI) and PAC respectively, was proposed to model the removal of Cr(VI) in the system S2. Cr(VI) removal in the combined carbon-biomass system (S3) was faster than both Cr(VI) removal using PAC or activated sludge individually. Results showed that the removal of Cr(VI) using the activated carbon-biomass system (S3) was adequately described by combining the kinetic equations proposed for the systems S1 and S2

  3. Synthesis of surface Cr (VI)-imprinted magnetic nanoparticles for selective dispersive solid-phase extraction and determination of Cr (VI) in water samples.

    Science.gov (United States)

    Qi, Xue; Gao, Shuang; Ding, Guosheng; Tang, An-Na

    2017-01-01

    A facile, rapid and selective magnetic dispersed solid-phase extraction (dSPE) method for the extraction and enrichment of Cr (VI) prior to flame atomic absorption spectrometry (AAS) was introduced. For highly selective and efficient extraction, magnetic Cr (VI)-imprinted nanoparticles (Fe 3 O 4 @ Cr (VI) IIPs) were prepared by hyphenating surface ion-imprinted with sol-gel techniques. In the preparation process, chromate (Cr(VI)) was used as the template ion; vinylimidazole and 3-aminopropyltriethoxysilane were selected as organic functional monomer and co-monomer respectively. Another reagent, methacryloxypropyltrimethoxysilane was adopted as coupling agent to form the stable covalent bonding between organic and inorganic phases. The effects of various parameters on the extraction efficiency, such as pH of sample solution, the amount of adsorbent, extraction time, the type and concentration of eluent were systematically investigated. Furthermore, the thermodynamic and kinetic properties of the adsorption process were studied to explore the internal adsorption mechanism. Under optimized conditions, the preconcentration factor, limit of detection and linear range of the established dSPE-AAS method for Cr (VI) were found to be 98, 0.29μgL -1 and 4-140μgL -1 , respectively. The developed method was also successfully applied to the analysis of Cr (VI) in different water samples with satisfactory results, proving its reliability and feasibility in real sample analysis. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Synthesis of Graphene Oxide by Oxidation of Graphite with Ferrate(VI) Compounds: Myth or Reality?

    Science.gov (United States)

    Sofer, Zdeněk; Luxa, Jan; Jankovský, Ondřej; Sedmidubský, David; Bystroň, Tomáš; Pumera, Martin

    2016-09-19

    It is well established that graphene oxide can be prepared by the oxidation of graphite using permanganate or chlorate in an acidic environment. Recently, however, the synthesis of graphene oxide using potassium ferrate(VI) ions has been reported. Herein, we critically replicate and evaluate this new ferrate(VI) oxidation method. In addition, we test the use of potassium ferrate(VI) for the synthesis of graphene oxide under various experimental routes. The synthesized materials are analyzed by a number of analytical methods in order to confirm or disprove the possibility of synthesizing graphene oxide by the ferrate(VI) oxidation route. Our results confirm the unsuitability of using ferrate(VI) for the oxidation of graphite on graphene oxide because of its high instability in an acidic environment and low oxidation power in neutral and alkaline environments. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The adsorption ability of Cr(VI) on sawdust–polyaniline nanocomposite

    International Nuclear Information System (INIS)

    Binh Phan, Thi; Que Do, Ngoc; Thanh Thuy Mai, Thi

    2010-01-01

    The results of this study of sawdust–polyaniline nanocomposite synthesized by a chemical method for Cr(VI) treatment in the environment are presented. Cr(VI) adsorption on a composite was determined by colorimetry. The results showed that sawdust–polyaniline composite synthesized with an aniline:sawdust ratio equal to 0.5 had an adsorption degree of 21.4 mg g −1 and adsorbed nearly 99% of the Cr(VI) after 2 h. The composite could be used for the adsorption of Cr(VI) from waste water. The Cr(VI) adsorption ability of the composite slightly depends on the pH value of the medium. The adsorption is fast during the first half hour and then the rate decreases

  6. Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

    Science.gov (United States)

    Philips , Elizabeth J.P.; Landa, Edward R.; Lovely, Derek R.

    1995-01-01

    A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranuum-contaminated soils. Bicarbonate (100 mM) extracted 20–94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism,Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils.

  7. Remediation of uranium contaminated soils with bicarbonate extraction and microbial U(VI) reduction

    International Nuclear Information System (INIS)

    Phillips, E.J.P.; Landa, E.R.; Lovley, D.R.

    1995-01-01

    A process for concentrating uranium from contaminated soils in which the uranium is first extracted with bicarbonate and then the extracted uranium is precipitated with U(VI)-reducing microorganisms was evaluated for a variety of uranium-contaminated soils. Bicarbonate (100 mM) extracted 20-94% of the uranium that was extracted with nitric acid. The U(VI)-reducing microorganism, Desulfovibrio desulfuricans reduced the U(VI) to U(IV) in the bicarbonate extracts. In some instances unidentified dissolved extracted components, presumably organics, gave the extract a yellow color and inhibited U(VI) reduction and/or the precipitation of U(IV). Removal of the dissolved yellow material with the addition of hydrogen peroxide alleviated this inhibition. These results demonstrate that bicarbonate extraction of uranium from soil followed by microbial U(VI) reduction might be an effective mechanism for concentrating uranium from some contaminated soils. (author)

  8. Raman spectrometric determination of Pu(VI) and Pu(V) in nitric acid solutions

    International Nuclear Information System (INIS)

    Gantner, E.; Freudenberger, M.; Steinert, D.; Ache, H.J.

    1987-03-01

    The determination of Pu(VI) in nitric acid solutions by spontaneous Laser Raman Spectrometry (LRS) was investigated and a calibration curve was established using U(VI) as internal standard. In addition, the concentrations of Pu(VI) and Pu(V) as a function of time were measured by this method in Pu(VI) solutions of different acidity containing H 2 O 2 as the reducing agent. In solutions which are intensely coloured by the presence of Ru(NO) complexes Pu(VI) can also be determined by LRS using a Kr + laser as excitation source. In future experiments, the study of the Pu(IV)-interaction with Ru using LRS and spectrophotometry as analytical techniques is therefore intended. (orig.) [de

  9. Reduction of trace quantities of chromium(VI by strong acids

    Directory of Open Access Journals (Sweden)

    Pezzin Sérgio H

    2004-01-01

    Full Text Available The chemical behavior of Cr(VI at low concentrations (10-4 to 10-7 mol L-1 in several strong acids was studied using high specific activity 51Cr(VI as a tracer. The speciation of the products from these systems was carried out by ion exchange chromatography with stepwise elution. The results show that trace quantities of Cr(VI, monitored by means of radiochromium (51Cr, are reduced in the presence of mineral acids such as perchloric, hydrochloric, hydrofluoric, sulfuric, nitric and trifluoromethanesulfonic acids, even in the absence of conventional reducing agents, producing different measureable Cr(III species, depending on the acid anion. Detailed studies of the reduction of low concentrations of Cr(VI with nitric acid have shown that the relative rate of reduction increases as the concentration of the acid increases or as the concentration of the Cr(VI decreases.

  10. Extraction and Separation of Uranium (VI) and Thorium (IV) Using Tri-n-dodecylamine Impregnated Resins

    International Nuclear Information System (INIS)

    Metwally, E.; Saleh, A.Sh.; El-Naggar, H.A.

    2005-01-01

    Extraction of U(VI) and Th(IV) from chloride and nitrate solutions with tri-n- dodecylamine impregnated on Amberlite XAD4, was investigated. The distribution of U(VI) and Th(IV) was studied at different concentrations of acid, salting-out agent, extractant, aqueous metal ion and other parameters. Absorption spectral studies have been investigated for uranium species in both aqueous HCl solution and the resin phase. From these studies, it is suggested that the tetrachloro complex of U(VI) is formed in the extraction of uranium (VI) from hydrochloric acid solutions by TDA impregnated resin. Stripping of the extracted U(VI) and Th(IV) was assayed with HCl and HNO 3 . Finally, the separation of uranium from thorium and fission products in HCl media was achieved

  11. Study on the DNA-protein crosslinks induced by chromium (VI) in SPC-A1

    Science.gov (United States)

    Liu, Yanqun; Ding, Jianjun; Lu, Xiongbing; You, Hao

    2018-01-01

    Objective: This study was designed to investigate the effect of chromium (VI) on DNA-protein crosslinks (DPC) of SPC-A1 cells. Methods: We exposed SPC-A1 cells were cultured in 1640 medium and treated with the SPC-A1 cells in vitro to different concentrations of Hexavalent chromium Cr(VI) for 2h, the KC1-SDS precipitation assay were used to measure the DNA-protein cross-linking effect. Results: All the different concentrations of Cr(VI) could cause the increase of DPC coefficient in SPC-A1 cells. But this effect was not significant (P>0.05) at low concentrations; while in high concentration Cr(VI) induced SPC-A1 cells could produce DNA-protein cross-linking effect significantly (P<0.05). Conclusions: chromium (VI) could induce DNA-protein crosslink.

  12. Solvent impregnated resin for isolation of U(VI) from industrial wastes

    International Nuclear Information System (INIS)

    Karve, M.; Rajgor, R.V.

    2008-01-01

    A solid-phase extraction method based upon impregnation of Cyanex 302 (bis(2,4,4- trimethylpentyl)mono-thio-phosphinic acid) on Amberlite XAD-2 resin is proposed for isolation of U(VI) from uranmicrolite ore tailing samples and industrial effluent samples. U(VI) was sorbed from nitric acid media on the solvent-impregnated resin (SIR) and was recovered completely with 1.0 M HCl. Based upon sorption behavior of U(VI) with Cyanex 302, it was quantitatively sorbed on the SIR in a dynamic method, while the other metal ions were not sorbed by the modified resin. The preparation of impregnated resin is simple, based upon physical interaction of the extractant and solid support, has good sorption capacity for U(VI), and is also reliable for detection of traces of U(VI). (authors)

  13. Analysis of the sixth spectrum of copper (Cu VI)

    International Nuclear Information System (INIS)

    Raassen, A.J.J.; Kleef, A.M. van

    1981-01-01

    The emission spectrum of copper has been observed in the regions 210-310 Angstroem and 950-1330 Angstroem. In the low-wavelength region 862 lines belonging to transitions between the 3d 5 4p and 3d 6 configurations in Cu VI have been classified while in the upper region 59 lines could be assigned to transitions from 3d 5 4p to 3d 5 4s. Of the 34 levels of the 3d 6 ground configuration 33 have been determined, while 208 of the 214 levels in the 3d 5 4p configuration and 13 of the 74 3d 5 4s levels have been established. For the 3d 6 and 3d 5 4p configurations parametric fits have been performed. The parameter values obtained for these configurations are compared to Hartree-Fock predictions. (orig.)

  14. Bianchi VI0 and III models: self-similar approach

    International Nuclear Information System (INIS)

    Belinchon, Jose Antonio

    2009-01-01

    We study several cosmological models with Bianchi VI 0 and III symmetries under the self-similar approach. We find new solutions for the 'classical' perfect fluid model as well as for the vacuum model although they are really restrictive for the equation of state. We also study a perfect fluid model with time-varying constants, G and Λ. As in other studied models we find that the behaviour of G and Λ are related. If G behaves as a growing time function then Λ is a positive decreasing time function but if G is decreasing then Λ 0 is negative. We end by studying a massive cosmic string model, putting special emphasis in calculating the numerical values of the equations of state. We show that there is no SS solution for a string model with time-varying constants.

  15. VI International Workshop on Nature Inspired Cooperative Strategies for Optimization

    CERN Document Server

    Otero, Fernando; Masegosa, Antonio

    2014-01-01

    Biological and other natural processes have always been a source of inspiration for computer science and information technology. Many emerging problem solving techniques integrate advanced evolution and cooperation strategies, encompassing a range of spatio-temporal scales for visionary conceptualization of evolutionary computation. This book is a collection of research works presented in the VI International Workshop on Nature Inspired Cooperative Strategies for Optimization (NICSO) held in Canterbury, UK. Previous editions of NICSO were held in Granada, Spain (2006 & 2010), Acireale, Italy (2007), Tenerife, Spain (2008), and Cluj-Napoca, Romania (2011). NICSO 2013 and this book provides a place where state-of-the-art research, latest ideas and emerging areas of nature inspired cooperative strategies for problem solving are vigorously discussed and exchanged among the scientific community. The breadth and variety of articles in this book report on nature inspired methods and applications such as Swarm In...

  16. Elucidating bonding preferences in tetrakis(imido)uranate(VI) dianions

    Science.gov (United States)

    Anderson, Nickolas H.; Xie, Jing; Ray, Debmalya; Zeller, Matthias; Gagliardi, Laura; Bart, Suzanne C.

    2017-09-01

    Actinyl species, [AnO2]2+, are well-known derivatives of the f-block because of their natural occurrence and essential roles in the nuclear fuel cycle. Along with their nitrogen analogues, [An(NR)2]2+, actinyls are characterized by their two strong trans-An-element multiple bonds, a consequence of the inverse trans influence. We report that these robust bonds can be weakened significantly by increasing the number of multiple bonds to uranium, as demonstrated by a family of uranium(VI) dianions bearing four U-N multiple bonds, [M]2[U(NR)4] (M = Li, Na, K, Rb, Cs). Their geometry is dictated by cation coordination and sterics rather than by electronic factors. Multiple bond weakening by the addition of strong π donors has the potential for applications in the processing of high-valent actinyls, commonly found in environmental pollutants and spent nuclear fuels.

  17. Extraction separation studies of uranium(VI) by amine oxides

    International Nuclear Information System (INIS)

    Ejaz, M.

    1975-01-01

    The extraction of uranium(VI) by two amine oxides, 4-(5-nonyl)pyridine oxide and trioctylamine oxide has been studied. The extraction behavior of these two N-oxides is compared. The dependence of extraction on the type of amine oxide and acid, nature of organic diluent, and amine oxide concentration has been investigated. The influence of the concentration of the metal and salting-out agents is described. The possible mechanism of extraction is discussed in the light of the results of extraction isotherms, loading radiodata, and log-log plots of amine oxide concentration vs distribution ratio. The separation factors for a number of metal ions are reported, and the separation of uranium from some fission elements has also been achieved

  18. II-VI Narrow-Bandgap Semiconductors for Optoelectronics

    Science.gov (United States)

    Baker, Ian

    The field of narrow-gap II-VI materials is dominated by the compound semiconductor mercury cadmium telluride, (Hg1-x Cd x Te or MCT), which supports a large industry in infrared detectors, cameras and infrared systems. It is probably true to say that HgCdTe is the third most studied semiconductor after silicon and gallium arsenide. Hg1-x Cd x Te is the material most widely used in high-performance infrared detectors at present. By changing the composition x the spectral response of the detector can be made to cover the range from 1 μm to beyond 17 μm. The advantages of this system arise from a number of features, notably: close lattice matching, high optical absorption coefficient, low carrier generation rate, high electron mobility and readily available doping techniques. These advantages mean that very sensitive infrared detectors can be produced at relatively high operating temperatures. Hg1-x Cd x Te multilayers can be readily grown in vapor-phase epitaxial processes. This provides the device engineer with complex doping and composition profiles that can be used to further enhance the electro-optic performance, leading to low-cost, large-area detectors in the future. The main purpose of this chapter is to describe the applications, device physics and technology of II-VI narrow-bandgap devices, focusing on HgCdTe but also including Hg1-x Mn x Te and Hg1-x Zn x Te. It concludes with a review of the research and development programs into third-generation infrared detector technology (so-called GEN III detectors) being performed in centers around the world.

  19. U(VI) sorption on granite: prediction and experiments

    International Nuclear Information System (INIS)

    Nebelung, C.; Brendler, V.

    2010-01-01

    One widely accepted approach - component additivity (CA) - to describe the sorption of contaminants onto complex materials such as rocks or soils is based on the assumption that the surface of a complex mineral assemblage is composed of a mixture of mineral constituents whose surface properties are known from independent studies. An internally consistent SCM (surface complexation model) database can be developed that describes the adsorption reactions of solutes to each phase. Here, the capability of such a methodology was tested, using the code MINTEQA2 including thermodynamic data of the NEA-TDB, and literature data for SCM, namely the DDL model. The sorption characteristics of U(VI) on granite (from Eibenstock, Saxony, Germany, with the main components quartz, albite, orthoclase, and muscovite) was predicted and then compared to batch experiments. Granite plays an important role in the remediation of former uranium ore mining and milling sites, but is also one of the host rocks considered for final disposal of nuclear materials. Safety assessment requires a detailed understanding of this system and its retention potential with regard to hazardous components. Namely the sorption of uranium in this complex rock is not fully understood yet. The experiments thus also provided a better understanding of the far-field behaviour in granitic geological nuclear repositories. The robustness of the prediction was tested by variation of the granite composition and the variation of the specific surface area (SSA) - first all components were predicted with a uniform granite SSA, second with a distinct SSA for each granite component (determined on pure minerals for the same grain size fractions). Changes in compositions yielded only marginal differences in the prediction. Different approaches to SSA showed somewhat larger deviations. In conclusion, the CA methodology is a valid and robust approach to U(VI) sorption onto complex substrates such as granite, provided sufficient

  20. Influence of Calcite and Dissolved Calcium on Uranium(VI) Sorption to a Hanford Subsurface Sediment

    International Nuclear Information System (INIS)

    Dong, Wenming; Ball, William P.; Liu, Chongxuan; Wang, Zheming; Stone, Alan T.; Bai, Jing; Zachara, John M.

    2005-01-01

    The influence of calcite and dissolved calcium on U(VI) adsorption was investigated using a calcite-containing sandy silt/clay sediment from the U. S. Department of Energy Hanford site. U(VI) adsorption to sediment, treated sediment, and sediment size fractions was studied in solutions that both had and had not been preequilibrated with calcite, at initial [U(VI)] ) 10-7-10-5 mol/L and final pH ) 6.0- 10.0. Kinetic and reversibility studies (pH 8.4) showed rapid sorption (30 min), with reasonable reversibility in the 3-day reaction time. Sorption from solutions equilibrated with calcite showed maximum U(VI) adsorption at pH 8.4 (0.1. In contrast, calcium-free systems showed the greatest adsorption at pH 6.0-7.2. At pH > 8.4, U(VI) adsorption was identical from calcium-free and calcium-containing solutions. For calcite-presaturated systems, both speciation calculations and laser-induced fluorescence spectroscopic analyses indicated that aqueous U(VI) was increasingly dominated by Ca2UO2(CO3)3 0(aq) at pH<8.4 and that formation of Ca2UO2(CO3)3 0(aq) is what suppresses U(VI) adsorption. Above pH 8.4, aqueous U(VI) speciation was dominated by UO2(CO3)3 4- in all solutions. Finally, results also showed that U(VI) adsorption was additive in regard to size fraction but not in regard to mineral mass: Carbonate minerals may have blocked U(VI) access to surfaces of higher sorption affinity

  1. Effect of Salicylic and Picolinic Acids on the Adsorption of U(VI) onto Oxides

    International Nuclear Information System (INIS)

    Park, Kyoung Kyun; Jung, Euo Chang; Cho, Hye Ryun; Song, Kyu Seok

    2009-01-01

    The effect of organic acids on the adsorption of U(VI) onto oxide surfaces (TiO 2 (anatase), SiO 2 (amorphous) and Al 2 O-3(amorphous)) has been investigated. Two different organic acids, salicylic and picolinic acids, were used. Changes of adsorption ratio of U(VI), which depend on the existence of organic acids in a sample, were measured as a function of pH. Quantities of adsorbed organic acids, which depend on the existence of U(VI) in a sample, were also measured as a function of pH. It is confirmed that the soluble complex formation of U(VI) with organic acids can deteriorate the adsorption of U(VI) onto TiO 2 surface. It is noteworthy that salicylic acid does not affect the adsorption of U(VI) onto SiO 2 surface, however, picolinic acid enhances the adsorption of U(VI) onto SiO 2 surface. The latter effect can be understood by considering the formation of a ternary surface complex on SiO 2 surface, which was confirmed by the co-adsorption of picolinic acid with U(VI) and the change in a fluorescence spectra of U(VI) on surface, In the case of Al 2 O-3, organic acids themselves were largely adsorbed onto a surface without deteriorating the adsorption of U(VI). This would support the possibility of a ternary surface complex formation on the Al 2 O-3 surface, and an additional spectroscopic study is required.

  2. Cr(VI) occurrence and geochemistry in water from public-supply wells in California

    Science.gov (United States)

    Izbicki, John; Wright, Michael; Seymour, Whitney A.; McCleskey, R. Blaine; Fram, Miranda S.; Belitz, Kenneth; Esser, Bradley K.

    2015-01-01

    Hexavalent chromium, Cr(VI), in 918 wells sampled throughout California between 2004 and 2012 by the Groundwater Ambient Monitoring and Assessment-Priority Basin Project (GAMA-PBP) ranged from less than the study reporting limit of 1 microgram per liter (μg/L) to 32 μg/L. Statewide, Cr(VI) was reported in 31 percent of wells and equaled or exceeded the recently established (2014) California Maximum Contaminant Level (MCL) for Cr(VI) of 10 μg/L in 4 percent of wells. Cr(VI) data collected for regulatory purposes overestimated Cr(VI) occurrence compared to spatially-distributed GAMA-PBP data. Ninety percent of chromium was present as Cr(VI), which was detected more frequently and at higher concentrations in alkaline (pH ≥ 8), oxic water; and more frequently in agricultural and urban land uses compared to native land uses. Chemical, isotopic (tritium and carbon-14), and noble-gas data show high Cr(VI) in water from wells in alluvial aquifers in the southern California deserts result from long groundwater-residence times and geochemical reactions such as silicate weathering that increase pH, while oxic conditions persist. High Cr(VI) in water from wells in alluvial aquifers along the west-side of the Central Valley results from high-chromium in source rock eroded to form those aquifers, and areal recharge processes (including irrigation return) that can mobilize chromium from the unsaturated zone. Cr(VI) co-occurred with oxyanions having similar chemistry, including vanadium, selenium, and uranium. Cr(VI) was positively correlated with nitrate, consistent with increased concentrations in areas of agricultural land use and mobilization of chromium from the unsaturated zone by irrigation return.

  3. Measurement and Analysis of Output Radiation Dose on X-Ray Device over 10 Years at Hospitals in Medan City

    Directory of Open Access Journals (Sweden)

    Herty Afrina Sianturi

    2018-01-01

    Adhikari, Suraj Raj. 2012. Effect And Application      Of Ionization Radiation (X-Ray In Living  Organism. Kaski: Volume 3.The Himalaya  Physics. Badan Pengawas Tenaga Nuklir, Peraturan Kepala BAPETEN No. 8 Tahun 2011  tentang Keselamatan Radiasi dalam Penggunaan Pesawat Sinar-X Radiologi Diagnostik dan Intervensional, 2011. BAPETEN, 1999, Surat Keputusan Kepala Bapeten nomor 01/Ka-Bapeten/V-99 tentang Kesehatan terhadap radiasi pengion, Jakarta BATAN, 2005, Disain Penahan Ruang Sinar – X, Pusdiklat, BATAN, Jakarta Bushong, Steward C. 2013. Radologic Science for Technologists. 10th edition.United State of  America : CV. Mosby Company. Kramer, H. M., dan Selbach, H. J. 2008. Extension of the Range of Definition of the Practical Peak Voltage up to 300 kV. The British Journal of  Radiologhy (81:693-698. Rassad, S. dkk, Radiologi Diagnostik, Fakultas Kedokteran Universitas Indonesia Rumah Sakit Dr Cipto Mangunkusumo, Jakarta (2000. Suryanto, Sigit Bachtiar. 2011. Analisis Pembentukan Gambar Dan Batas Toleransi Uji Kesesuaian Pada Pesawat Sinar-X Diagnostik. Prosiding Seminar Penelitian Dan Pengelolaan Perangkat Nuklir. Trikasjono, T. dkk. 2009. Analisis Keselamatan Pesawat Sinar-X di Instalasi Radiologi Rumah Sakit Umum daerah Sleman Yogyakarta. Prosiding Seminar Nasional Sains dan Teknologi Nuklir PTNBR – BATAN. Vassileva, J. 2004. A Phantom for Dose Image Quality Optimization in Chest Radiography. The British Journal of Radiologhy 75:837-842. Wadianto, Azis Muslim. 2017. Uji Akurasi Tegangan Tinggi Alat Rontgen Radiography Mobile. INOVASI, Volume XIX Nomor 1,Januari 2017

  4. Euro VI particulate limits. Methods of development for GDI engines; Euro VI Partikelgrenzwerte. Entwicklungsmethoden fuer GDI Motoren

    Energy Technology Data Exchange (ETDEWEB)

    Fuchs, Heribert; Hopfner, Wolfgang; Kapus, Paul; Kortschak, Martin; Winklhofer, Ernst [AVL List GmbH, Graz (Austria)

    2011-07-01

    Development of direct injection spark ignition (DISI) engines is focussing on techniques to provide mixture quality and charge motion suitable for clean and fuel efficient combustion. A significant number of such DISI engines employ turbo charging. They most often operate under homogeneous and stoichiometric conditions. Charge stratification and fuel rich combustion modes are, however, selected for specific drive conditions and must be included into emissions development strategies. Particle mass and number emissions allowed by forthcoming Euro VI legistation for the NEDC test impose engine out limits which require mixture formation quality otherwise achieved in natural gas engines and in modern port injection engines. Such high quality mixture formation targets with direct injection of liquid fuel need development techniques including all relevant steps from engine concept selection until final vehicle calibration. This paper describes testing techniques supporting such development efforts from first hardware tests on single cylinder optical engines up to in-cylinder evaluation of mixture quality in vehicle calibration work. (orig.)

  5. Reduction of Fe(III), Cr(VI), U(VI), and Tc(VII) by Deinococcus radiodurans R1

    International Nuclear Information System (INIS)

    Fredrickson, J.K.; Kostandarithes, H.M.; Li, S.W.; Plymake, A.E.; Daly, M.J.

    2000-01-01

    Deinococcus radiodurans is an exceptionally radiation-resistant microorganism capable of surviving acute exposures to ionizing radiation doses of 15,000 Gy and previously described as having a strictly aerobic respiratory metabolism. Under strict anaerobic conditions, D. radiodurans R1 reduced Fe(III)-nitrilotriacetic acid coupled to the oxidation of lactate to CO 2 and acetate but was unable to link this process to growth. D. radiodurans reduced the humic acid analog anthraquinone-2,6-disulfonate (AQDS) to its dihydroquinone form, AH 2 DS, which subsequently transferred electrons to the Fe(III) oxides hydrous ferric oxide and goethite via a previously described electron shuttle mechanism. D. radiodurans reduced the solid-phase Fe(III) oxides in the presence of either 0.1 mM AQDS or leonardite humic acids (2 mg ml -1 ) but not in their absence. D. radiodurans also reduced U(VI) and Tc(VII) in the presence of AQDS. In contrast, Cr(VI) was directly reduced in anaerobic cultures with lactate although the rate of reduction was higher in the presence of AQDS. The results are the first evidence that D. radiodurans can reduce Fe(III) coupled to the oxidation of lactate or other organic compounds. Also, D. radiodurans, in combination with humic acids or synthetic electron shuttle agents, can reduce U and Tc and thus has potential applications for remediation of metal- and radionuclide-contaminated sites where ionizing radiation or other DNA-damaging agents may restrict the activity of more sensitive organisms

  6. Simultaneous determination of chromium(III) and chromium(VI) in aqueous solutions by ion chromatography and chemiluminescence detection

    DEFF Research Database (Denmark)

    Gammelgaard, Bente; Jøns, O; Nielsen, B

    1992-01-01

    A method for the simultaneous determination of chromium(iii) and chromium(vi) in a flow system based on chemiluminescence was developed. A Dionex cation-exchange guard column was used to separate chromium(iii) from chromium(vi), and chromium(vi) was reduced by potassium sulfite, whereupon both...

  7. 75 FR 71137 - Announcement of Funding Awards for the HOPE VI Revitalization Grant Program for Fiscal Year 2009

    Science.gov (United States)

    2010-11-22

    ... Awards for the HOPE VI Revitalization Grant Program for Fiscal Year 2009 AGENCY: Office of the Assistant... the Fiscal Year 2009 (FY 2009) Notice of Funding Availability (NOFA) for the HOPE VI Revitalization.... FOR FURTHER INFORMATION CONTACT: For questions concerning the HOPE VI Revitalization grant awards...

  8. 78 FR 8552 - Announcement of Funding Awards, HOPE VI Main Street Grant Program, Fiscal Year (FY) 2011 and 2012

    Science.gov (United States)

    2013-02-06

    ... Awards, HOPE VI Main Street Grant Program, Fiscal Year (FY) 2011 and 2012 AGENCY: Office of the Assistant... the FY 2011 and FY 2012 (FY 2011-12) Notice of Funding Availability (NOFA) for the HOPE VI Main Street... said NOFA. FOR FURTHER INFORMATION CONTACT: For questions concerning the HOPE VI Main Street Program...

  9. Kinetics of U(VI) reduction by a dissimilatory Fe(III)-reducing bacterium under non-growth conditions

    International Nuclear Information System (INIS)

    Truex, M.J.; Peyton, B.M.; Valentine, N.B.; Gorby, Y.A.

    1997-01-01

    Dissimilatory metal-reducing microorganisms may be useful in processes designed for selective removal of uranium from aqueous streams. These bacteria can use U(VI) as an electron acceptor and thereby reduce soluble U(VI) to insoluble U(IV). While significant research has been devoted to demonstrating and describing the mechanism of dissimilatory metal reduction, the reaction kinetics necessary to apply this for remediation processes have not been adequately defined. In this study, pure culture Shewanella alga strain BrY reduced U(VI) under non-growth conditions in the presence of excess lactate as the electron donor. Initial U(VI) concentrations ranged from 13 to 1,680microM. A maximum specific U(VI) reduction rate of 2.37 micromole-U(VI)/(mg-biomass h) and Monod half-saturation coefficient of 132 microM-U(VI) were calculated from measured U(VI) reduction rates. U(VI) reduction activity was sustained at 60% of this rate for at least 80 h. The initial presence of oxygen at a concentration equal to atmospheric saturation at 22 C delays but does not prevent U(VI) reduction. The rate of U(VI) reduction by BrY is comparable or better than rates reported for other metal reducing species. BrY reduces U(VI) at a rate that is 30% of its Fe(III) reduction rate

  10. Determination of chromium (VI) in primary and secondary fertilizer and their respective precursors.

    Science.gov (United States)

    Krüger, Oliver; Fiedler, Francesca; Adam, Christian; Vogel, Christian; Senz, Rainer

    2017-09-01

    Hexavalent chromium species (Cr(VI)) are often carcinogenic, of high acute toxicity, highly mobile, and thus pose a severe risk to health and environment. Fertilizers usually contain significant amounts of chromium. Therefore, a reliable analysis of chromium and the fraction of Cr(VI) are crucial for safe use of fertilizers. This problem is expected to increase in the future, since more and more recycled fertilizers emerge due to increasing fertilizer demand and respective supply risks. However, existing analytical methods have been developed for conventional fertilizers and have to be tested whether they are suitable for the new materials. Thus, we performed a wet-chemical extraction for Cr(VI) on several matrices as well as respective quality control experiments including spiking with Cr(III) and Cr(VI) compounds. We found the Cr(VI) amounts to be below 2 mg/kg except for a thermally post-treated sewage sludge ash (SSA) that showed 12.3 mg/kg. The presence of organic matter e.g. in sludge or precipitated struvite caused a reduction of spiked Cr(VI) and thus no satisfying recovery for quality control. Cr(VI) reduction was also observed for SSA, presumably due to the presence of Fe(II) compounds. Even though the tested procedure can be hampered in some recycled fertilizer matrices, it might be adapted to be applicable also for these complex samples. Copyright © 2017 Elsevier Ltd. All rights reserved.

  11. Vi-CRM 197 as a new conjugate vaccine against Salmonella Typhi.

    Science.gov (United States)

    Micoli, F; Rondini, S; Pisoni, I; Proietti, D; Berti, F; Costantino, P; Rappuoli, R; Szu, S; Saul, A; Martin, L B

    2011-01-17

    An efficacious, low cost vaccine against typhoid fever, especially for young children, would make a major impact on disease burden in developing countries. The virulence capsular polysaccharide of Salmonella Typhi (Vi) coupled to recombinant mutant Pseudomonas aeruginosa exoprotein A (Vi-rEPA) has been shown to be highly efficacious. We investigated the use of carrier proteins included in infant vaccines, standardized the conjugation process and developed key assays required for routine lot release at production scale. Vi from a BSL1 organism, Citrobacter freundii, strain WR7011, was used as an alternative to Vi from S. Typhi. We showed that Vi conjugated to CRM(197), a non-toxic mutant of diphtheria toxin, widely used in commercial vaccines, was produced at high yield. Vi-CRM(197) proved immunogenic in animal studies, even without adjuvant. Thus, Vi-CRM(197) appears to be a suitable candidate for the development of a commercially viable, effective typhoid vaccine for developing countries. Copyright © 2010 Elsevier Ltd. All rights reserved.

  12. Ferrate(VI) as a greener oxidant: Electrochemical generation and treatment of phenol.

    Science.gov (United States)

    Sun, Xuhui; Zhang, Qi; Liang, He; Ying, Li; Xiangxu, Meng; Sharma, Virender K

    2016-12-05

    Ferrate(VI) (Fe(VI)O4(2-), Fe(VI)) is a greener oxidant in the treatment of drinking water and wastewater. The electrochemical synthesis of Fe(VI) may be considered environmentally friendly because it involves one-step process to convert Fe(0) to Fe(VI) without using harmful chemicals. Electrolysis was performed by using a sponge iron as an anode in NaOH solution at different ionic strengths. The cyclic voltammetric (CV) curves showed that the sponge iron had higher electrical activity than the grey cast iron. The optimum current density was 0.054mAcm(-2) in 10M NaOH solution, which is much lower than the electrolyte concentrations used in other electrode materials. A comparison of current efficiency and energy consumption was conducted and is briefly discussed. The generated ferrate solution was applied to degrade phenol in water at two levels (2mgL(-1) and 5mgL(-1)). The maximum removal efficiency was ∼70% and the optimum pH for phenol treatment was 9.0. Experiments on phenol removal using conventional coagulants (ferric chloride (FeCl3) and polyaluminium chloride (PAC)) were performed independently to demonstrate that removal of phenol by Fe(VI) occurred mainly by oxidative transformation. A combination of Fe(VI) and coagulant may be advantageous in enhancing removal efficiency, adjusting pH, and facilitating flocculation. Copyright © 2015 Elsevier B.V. All rights reserved.

  13. Polyaniline (PANI) modified bentonite by plasma technique for U(VI) removal from aqueous solution

    Science.gov (United States)

    Liu, Xinghao; Cheng, Cheng; Xiao, Chengjian; Shao, Dadong; Xu, Zimu; Wang, Jiaquan; Hu, Shuheng; Li, Xiaolong; Wang, Weijuan

    2017-07-01

    Polyaniline (PANI) modified bentonite (PANI/bentonie) was synthesized by plasma induced polymerization of aniline on bentonite surface, and applied to uptake of uranium(VI) ions from aqueous solution. The as-synthesized PANI/bentonie was characterized by scanning electron microscopy (SEM), powder X-ray diffraction (XRD), thermal gravimetric analysis (TGA), and X-ray photoelectron spectroscopy (XPS). Batch adsorption technique was utilized to investigate the adsorption of U(VI) on bentonite and PANI/bentonite. The adsorption of U(VI) (10 mg/L) on PANI/bentonite surface is fairly depend on solution pH, ionic strength, and temperature in solution. The modified PANI on PANI/bentonite surface significantly enhances its adsorption capability for U(VI). The presence of humic acid (HA) can sound enhance U(VI) adsorption on PANI/bentonite at pH 6.5. According to the thermodynamic parameters, the adsorption of U(VI) on PANI/bentonite surface is a spontaneous and endothermic process. The results highlight the application of PANI/bentonite composites as candidate material for the uptake of trace U(VI) from aqueous solution.

  14. Collagen VI disorders: Insights on form and function in the extracellular matrix and beyond.

    Science.gov (United States)

    Lamandé, Shireen R; Bateman, John F

    2017-12-22

    Mutations in the three canonical collagen VI genes, COL6A1, COL6A2 and COL6A3, cause a spectrum of muscle disease from Bethlem myopathy at the mild end to the severe Ullrich congenital muscular dystrophy. Mutations can be either dominant or recessive and the resulting clinical severity is influenced by the way mutations impact the complex collagen VI assembly process. Most mutations are found towards the N-terminus of the triple helical collagenous domain and compromise extracellular microfibril assembly. Outside the triple helix collagen VI is highly polymorphic and discriminating mutations from rare benign changes remains a major diagnostic challenge. Collagen VI deficiency alters extracellular matrix structure and biomechanical properties and leads to increased apoptosis and oxidative stress, decreased autophagy, and impaired muscle regeneration. Therapies that target these downstream consequences have been tested in a collagen VI null mouse and also in small human trials where they show modest clinical efficacy. An important role for collagen VI in obesity, cancer and diabetes is emerging. A major barrier to developing effective therapies is the paucity of information about how collagen VI deficiency in the extracellular matrix signals the final downstream consequences - the receptors involved and the intracellular messengers await further characterization. Copyright © 2017 International Society of Matrix Biology. Published by Elsevier B.V. All rights reserved.

  15. Kinetic study of time-dependent fixation of U{sup VI} on biochar

    Energy Technology Data Exchange (ETDEWEB)

    Ashry, A. [Division of Agricultural and Environmental Sciences, School of Biosciences, University of Nottingham, Sutton Bonington, Leicestershire LE12 5RD (United Kingdom); Radiation Protection Department, Nuclear Research Centre, Egyptian Atomic Energy Authority, Cairo (Egypt); Bailey, E.H., E-mail: liz.bailey@nottingham.ac.uk [Division of Agricultural and Environmental Sciences, School of Biosciences, University of Nottingham, Sutton Bonington, Leicestershire LE12 5RD (United Kingdom); Chenery, S.R.N. [British Geological Survey, Nicker Hill, Keyworth, Nottingham NG12 5GG (United Kingdom); Young, S.D. [Division of Agricultural and Environmental Sciences, School of Biosciences, University of Nottingham, Sutton Bonington, Leicestershire LE12 5RD (United Kingdom)

    2016-12-15

    Biochar, a by-product from the production of biofuel and syngas by gasification, was tested as a material for adsorption and fixation of U{sup VI} from aqueous solutions. A batch experiment was conducted to study the factors that influence the adsorption and time-dependent fixation on biochar at 20 °C, including pH, initial concentration of U{sup VI} and contact time. Uranium (U{sup VI}) adsorption was highly dependent on pH but adsorption on biochar was high over a wide range of pH values, from 4.5 to 9.0, and adsorption strength was time-dependent over several days. The experimental data for pH > 7 were most effectively modelled using a Freundlich adsorption isotherm coupled to a reversible first order kinetic equation to describe the time-dependent fixation of U{sup VI} within the biochar structure. Desorption experiments showed that U{sup VI} was only sparingly desorbable from the biochar with time and isotopic dilution with {sup 233}U{sup VI} confirmed the low, or time-dependent, lability of adsorbed {sup 238}U{sup VI}. Below pH 7 the adsorption isotherm trend suggested precipitation, rather than true adsorption, may occur. However, across all pH values (4.5-9) measured saturation indices suggested precipitation was possible: autunite below pH 6.5 and either swartzite, liebigite or bayleyite above pH 6.5.

  16. The O VI Mystery: Mismatch between X-Ray and UV Column Densities

    Science.gov (United States)

    Mathur, S.; Nicastro, F.; Gupta, A.; Krongold, Y.; McLaughlin, B. M.; Brickhouse, N.; Pradhan, A.

    2017-12-01

    The UV spectra of Galactic and extragalactic sightlines often show O VI absorption lines at a range of redshifts, and from a variety of sources from the Galactic circumgalactic medium to active galactic nuclei (AGN) outflows. Inner shell O VI absorption is also observed in X-ray spectra (at λ =22.03 Å), but the column density inferred from the X-ray line was consistently larger than that from the UV line. Here we present a solution to this discrepancy for the z = 0 systems. The O II Kβ line {}4{S}0\\to {(}3D)3{p}4P at 562.40 eV (≡22.04 Å) is blended with the O VI Kα line in X-ray spectra. We estimate the strength of this O II line in two different ways, and show that in most cases the O II line accounts for the entire blended line. The small amount of O VI equivalent width present in some cases has column density entirely consistent with the UV value. This solution to the O VI discrepancy, however, does not apply to high column-density systems like AGN outflows. We discuss other possible causes to explain their UV/X-ray mismatch. The O VI and O II lines will be resolved by gratings on board the proposed mission Arcus and the concept mission Lynx, and would allow the detection of weak O VI lines not just at z = 0, but also at higher redshift.

  17. THE SURPRISINGLY CONSTANT STRENGTH OF O VI ABSORBERS OVER COSMIC TIME

    International Nuclear Information System (INIS)

    Fox, Andrew J.

    2011-01-01

    O VI absorption is observed in a wide range of astrophysical environments, including the local interstellar medium, the disk and halo of the Milky Way, high-velocity clouds, the Magellanic Clouds, starburst galaxies, the intergalactic medium (IGM), damped Lyα systems, and gamma-ray-burst host galaxies. Here, a new compilation of 775 O VI absorbers drawn from the literature is presented, all observed at high resolution (instrumental FWHM ≤ 20 km s -1 ) and covering the redshift range z = 0-3. In galactic environments [log N(H I) ∼> 20], the mean O VI column density is shown to be insensitive to metallicity, taking a value log N(O VI) ∼ 14.5 for galaxies covering the range -1.6 ∼ 4 K) clouds and hot (∼10 6 K) plasma, although many such layers would have to be intersected by a typical galaxy-halo sight line to build up the characteristic galactic N(O VI). The alternative, widely used model of single-phase photoionization for intergalactic O VI is ruled out by kinematic evidence in the majority of IGM O VI components at low and high redshift.

  18. Biased Brownian motion mechanism for processivity and directionality of single-headed myosin-VI.

    Science.gov (United States)

    Iwaki, Mitsuhiro; Iwane, Atsuko Hikikoshi; Ikebe, Mitsuo; Yanagida, Toshio

    2008-01-01

    Conventional form to function as a vesicle transporter is not a 'single molecule' but a coordinated 'two molecules'. The coordinated two molecules make it complicated to reveal its mechanism. To overcome the difficulty, we adopted a single-headed myosin-VI as a model protein. Myosin-VI is an intracellular vesicle and organelle transporter that moves along actin filaments in a direction opposite to most other known myosin classes. The myosin-VI was expected to form a dimer to move processively along actin filaments with a hand-over-hand mechanism like other myosin organelle transporters. However, wild-type myosin-VI was demonstrated to be monomer and single-headed, casting doubt on its processivity. Using single molecule techniques, we show that green fluorescent protein (GFP)-fused single-headed myosin-VI does not move processively. However, when coupled to a 200 nm polystyrene bead (comparable to an intracellular vesicle in size) at a ratio of one head per bead, single-headed myosin-VI moves processively with large (40 nm) steps. Furthermore, we found that a single-headed myosin-VI-bead complex moved more processively in a high-viscous solution (40-fold higher than water) similar to cellular environment. Because diffusion of the bead is 60-fold slower than myosin-VI heads alone in water, we propose a model in which the bead acts as a diffusional anchor for the myosin-VI, enhancing the head's rebinding following detachment and supporting processive movement of the bead-monomer complex. This investigation will help us understand how molecular motors utilize Brownian motion in cells.

  19. A new optical sensor for spectrophotometric determination of uranium (VI) and thorium (IV) in acidic medium

    Energy Technology Data Exchange (ETDEWEB)

    Elhefnawy, O.A. [Nuclear and Radiological Regulatory Authority (NRRA), Cairo (Egypt). Nuclear Safeguards and Physical Protection Dept.

    2017-07-01

    A spectrophotometric method was developed for U(VI) and Th(IV) determination in acidic medium by using proposed optical sensor. This sensor is base on the complexation reaction of the ionophore midodrine hydrochloride (L) with U(VI)/Th(IV) in plasticized (o-NPOE) high molecular weight (PVC). Several parameters such as effect of acidic medium, response time and sensor compositions were studied. The determination of the complexes stoichiometry was also studied using Job's method. The complexes stoichiometry were measured at the absorbance spectra 302 nm and the results were found to be 1:1 for both complexes U(VI)-L and Th(IV)-L. The complexation reaction was extremely rapid at room temperature; it takes 5, 10 min to complete the complexation reaction in U(VI) and Th(IV), respectively. Under the optimum conditions the calibration curves of U(VI)/Th(IV) determination, have good linearity at different acidic medium nitric, sulfuric, and phosphoric acids with low detection and quantification limits. The accuracy and precision studies proved that the proposed optical sensor is valid and qualified for U(VI)/Th(IV) spectrophotometric determination in different acidic medium. The selectivity of the proposed optical sensor was studied. The proposed optical sensor was applied successfully for U(VI)/Th(IV) determination in research and development (R and D) nuclear waste samples with satisfactory results. A comparative study of the proposed optical sensor with other previous spectrophotometric sensors for U(VI)/Th(IV) determination, proved the high efficiency of the proposed optical sensor, that it presents wide linear range and low detection limit. The proposed optical sensor could be applied for a quantitative determination of U(VI)/Th(IV) in acidic waste samples.

  20. A new optical sensor for spectrophotometric determination of uranium (VI) and thorium (IV) in acidic medium

    International Nuclear Information System (INIS)

    Elhefnawy, O.A.

    2017-01-01

    A spectrophotometric method was developed for U(VI) and Th(IV) determination in acidic medium by using proposed optical sensor. This sensor is base on the complexation reaction of the ionophore midodrine hydrochloride (L) with U(VI)/Th(IV) in plasticized (o-NPOE) high molecular weight (PVC). Several parameters such as effect of acidic medium, response time and sensor compositions were studied. The determination of the complexes stoichiometry was also studied using Job's method. The complexes stoichiometry were measured at the absorbance spectra 302 nm and the results were found to be 1:1 for both complexes U(VI)-L and Th(IV)-L. The complexation reaction was extremely rapid at room temperature; it takes 5, 10 min to complete the complexation reaction in U(VI) and Th(IV), respectively. Under the optimum conditions the calibration curves of U(VI)/Th(IV) determination, have good linearity at different acidic medium nitric, sulfuric, and phosphoric acids with low detection and quantification limits. The accuracy and precision studies proved that the proposed optical sensor is valid and qualified for U(VI)/Th(IV) spectrophotometric determination in different acidic medium. The selectivity of the proposed optical sensor was studied. The proposed optical sensor was applied successfully for U(VI)/Th(IV) determination in research and development (R and D) nuclear waste samples with satisfactory results. A comparative study of the proposed optical sensor with other previous spectrophotometric sensors for U(VI)/Th(IV) determination, proved the high efficiency of the proposed optical sensor, that it presents wide linear range and low detection limit. The proposed optical sensor could be applied for a quantitative determination of U(VI)/Th(IV) in acidic waste samples.

  1. Molasses as an efficient low-cost carbon source for biological Cr(VI) removal

    Energy Technology Data Exchange (ETDEWEB)

    Michailides, Michail K. [Department of Environmental and Natural Resources Management, University of Patras, 2 G. Seferi Str., GR-30100 Agrinio (Greece); Tekerlekopoulou, Athanasia G., E-mail: atekerle@upatras.gr [Department of Environmental and Natural Resources Management, University of Patras, 2 G. Seferi Str., GR-30100 Agrinio (Greece); Akratos, Christos S.; Coles, Sandra [Department of Environmental and Natural Resources Management, University of Patras, 2 G. Seferi Str., GR-30100 Agrinio (Greece); Pavlou, Stavros [Institute of Chemical Engineering Sciences (FORTH/ICE-HT), Stadiou Str., Platani, P.O. Box 1414, GR-26504 Patras (Greece); Department of Chemical Engineering, University of Patras, GR-26504 Patras (Greece); Vayenas, Dimitrios V. [Department of Environmental and Natural Resources Management, University of Patras, 2 G. Seferi Str., GR-30100 Agrinio (Greece); Institute of Chemical Engineering Sciences (FORTH/ICE-HT), Stadiou Str., Platani, P.O. Box 1414, GR-26504 Patras (Greece)

    2015-01-08

    Highlights: • Suspended and attached growth reactors were examined for Cr(VI) bio-reduction. • Molasses was proved an efficient and very low cost carbon source. • Molasses was more efficient than sugar in enhancing Cr(VI) reduction. • SBR with recirculation was the most proper operating mode. - Abstract: In the present study, indigenous microorganisms from industrial sludge were used to reduce the activity of Cr(VI). Molasses, a by-product of sugar processing, was selected as the carbon source (instead of sugar used in a previous work) as it is a low-cost energy source for bioprocesses. Initially, experiments were carried out in suspended growth batch reactors for Cr(VI) concentrations of 1.5–110 mg/L. The time required for complete Cr(VI) reduction increased with initial Cr(VI) concentration. Initial molasses concentration was also found to influence the Cr(VI) reduction rate. The optimal concentration for all initial Cr(VI) concentrations tested was 0.8 gC/L. Experiments were also carried out in packed-bed reactors. Three different operating modes were used to investigate the optimal performance and efficiency of the filter, i.e. batch, continuous and SBR with recirculation. The latter mode with a recirculation rate of 0.5 L/min lead to significantly high Cr(VI) reduction rates (up to 135 g/m{sup 2} d). The results of this work were compared with those of a similar work using sugar as the carbon source and indicate that molasses could prove a feasible technological solution to a serious environmental problem.

  2. Ex-situ bioremediation of U(VI from contaminated mine water using Acidithiobacillus ferrooxidans strains

    Directory of Open Access Journals (Sweden)

    Maria eRomero-Gonzalez

    2016-05-01

    Full Text Available The ex-situ bioremoval of U(VI from contaminated water using Acidithiobacillus ferrooxidans strain 8455 and 13538 was studied under a range of pH and uranium concentrations. The effect of pH on the growth of bacteria was evaluated across the range 1.5 – 4.5 pH units. The respiration rate of At. ferrooxidans at different U(VI concentrations was quantified as a measure of the rate of metabolic activity over time using an oxygen electrode. The biosorption process was quantified using a uranyl nitrate solution, U-spiked growth media and U-contaminated mine water. The results showed that both strains of At. ferrooxidans are able to remove U(VI from solution at pH 2.5 – 4.5, exhibiting a buffering capacity at pH 3.5. The respiration rate of the micro-organism was affected at U(VI concentration of 30 mg L-1. The kinetics of the sorption fitted a pseudo-first order equation, and depended on the concentration of U(VI. The KD obtained from the biosorption experiments indicated that strain 8455 is more efficient for the removal of U(VI. A bioreactor designed to treat a solution of 100 mg U(VI L-1 removed at least 50% of the U(VI in water. The study demonstrated that At. ferrooxidans can be used for the ex-situ bioremediation of U(VI contaminated mine water.

  3. Treatment of selected pharmaceuticals by ferrate(VI): performance, kinetic studies and identification of oxidation products.

    Science.gov (United States)

    Zhou, Zhengwei; Jiang, Jia-Qian

    2015-03-15

    The performance of ferrate(VI) in treating sulfamethoxazole (SMX), diclofenac (DCF), carbamazepine (CBZ) and bezafibrate (BZF) in test solutions containing the four compounds was investigated. A series of jar-test experiments was performed on a bench-scale at pH 6-9 and at a ferrate(VI) dose of 1-5 mg Fe/L. The results suggested that ferrate(VI) can effectively remove SMX, DCF and CBZ from the test solutions, with greater than 80% removal under optimum conditions. However, the removal efficiency of BZF was very low, less than 25% under the studied conditions. Increasing the dose of ferrate(VI) improved the treatment performance, while the influence of solution pH on ferrate(VI) performance varied among the different target compounds. Ferrate(VI) demonstrated the highest reactivity with SMX at pH 8 and pH 9 (20 °C), with apparent second-order rate constants of 360±17 M(-1) s(-1) and 1.26±0.02 M(-1) s(-1), respectively. However, BZF showed the lowest removal by ferrate(VI) with the smallest rate constants (less than 0.5 M(-1) s(-1)) at pH 8 and pH 9. Furthermore, a number of oxidation products (OPs) of SMX, DCF and CBZ during ferrate(VI) oxidation were detected by liquid chromatography and mass spectrometry (LC-MS), and their degradation pathways were tentatively proposed. No OPs of BZF were detected during ferrate(VI) oxidation. Copyright © 2014 Elsevier B.V. All rights reserved.

  4. Thermodynamic analysis of Cr(VI) extraction using TOPO impregnated membranes

    Energy Technology Data Exchange (ETDEWEB)

    Praveen, Prashant; Loh, Kai-Chee, E-mail: chelohkc@nus.edu.sg

    2016-08-15

    Highlights: • Cr(VI) extraction by extractant impregnated membranes (EIM) was investigated. • EIM exhibited high extraction efficiency, mass transfer rate and stability. • Mass transfer mechanism was proposed based on kinetics and equilibrium data. • Uptake of Cr(VI) by EIMs was endothermic and spontaneous. • Cr(VI) extraction by EIMs was dominated by physical interactions. - Abstract: Solid/liquid extraction of Cr(VI) was accomplished using trioctylphosphine oxide impregnated polypropylene hollow fiber membranes. Extraction of 100–500 mg/L Cr(VI) by the extractant impregnated membranes (EIM) was characterized by high uptake rate and capacity, and equilibrium was attained within 45 min of contact. Extraction equilibrium was pH-dependent (at an optimal pH 2), whereas stripping using 0.2 M sodium hydroxide yielded the highest recovery of 98% within 60 min. The distribution coefficient was independent of initial Cr(VI) concentration, and the linear distribution equilibrium isotherm could be modeled using Freundlich isotherm. The mass transfer kinetics of Cr(VI) was examined using pseudo-second-order and intraparticle diffusion models and a mass transfer mechanism was deduced. The distribution coefficient increased with temperature, which indicated endothermic nature of the reaction. Enthalpy and entropy change during Cr(VI) extraction were positive and varied in the range of 37–49 kJ/mol and 114–155 J/mol, respectively. The free energy change was negative, confirming the feasibility and spontaneity of the mass transfer process. Results obtained suggest that EIMs are efficient and sustainable for extraction of Cr(VI) from wastewater.

  5. Application of NKF-6 zeolite for the removal of U(VI) from aqueous solution

    International Nuclear Information System (INIS)

    Pengfei Zong; Hai Wang; Hui Pan; Yaolin Zhao; Chaohui He

    2013-01-01

    To better understand the application of NKF-6 zeolite as an adsorbent for the removal of U(VI) from radionuclides and heavy metal ions polluted water, herein, NKF-6 zeolite was employed to remove U(VI) at different experimental conditions. The influence of solid/liquid ratio, contact time, pH, ionic strength, humic substances and temperature on sorption of U(VI) to NKF-6 zeolite was investigated using batch technique under ambient conditions. The experimental results demonstrated that the sorption of U(VI) on NKF-6 zeolite was strongly dependent on pH. The sorption property of U(VI) was influenced by ionic strength at pH 7.0. The presence of fulvic acid or humic acid promoted the sorption of U(VI) on NKF-6 zeolite at low pH values while restrained the sorption at high pH values. The thermodynamic parameters (i.e., ΔS 0 , ΔH 0 , and ΔG 0 ) calculated from the temperature-dependent sorption isotherms demonstrated that the sorption process of U(VI) on NKF-6 zeolite was endothermic and spontaneous. At low pH values, the sorption of U(VI) was dominated by outer-sphere surface complexation and ion exchange with Na + /H + on NKF-6 zeolite surfaces, while inner-sphere surface complexation was the main sorption mechanism at high pH values. From the experimental results, one can conclude that NKF-6 zeolite can be used as a potential adsorbent for the preconcentration and solidification of U(VI) from large volumes of aqueous solutions. (author)

  6. Effect of flavin compounds on uranium(VI) reduction- kinetic study using electrochemical methods with UV-vis spectroscopy

    International Nuclear Information System (INIS)

    Yamasaki, Shinya; Tanaka, Kazuya; Kozai, Naofumi; Ohnuki, Toshihiko

    2017-01-01

    The reduction of uranium hexavalent (U(VI)) to tetravalent (U(IV)) is an important reaction because of the change in its mobility in the natural environment. Although the flavin mononucleotide (FMN) has acted as an electron shuttle for the U(VI) reduction in vivo system, which is called an electron mediator, only the rate constant for the electron transfer from FMN to U(VI) has been determined. This study examined the rate constant for the U(VI) reduction process by three flavin analogues (riboflavin, flavin mononucleotide, flavin adenine dinucleotide) to elucidate their substituent group effect on the U(VI) reduction rate by electrochemical methods. The formation of the U(IV) was monitored by UV-vis spectrometry at 660 nm during the constant potential electrolysis of the U(VI) solution in the presence of the mediator. The cyclic voltammograms indicated that the three flavin analogues behaved as electron mediator to reduce U(VI). The logarithmic rate constant for the U(VI) reduction was related to the standard redox potential of the mediators. This linear relationship indicated that the redox-active group of the mediator and the substituent group of the mediator dominate capability of the U(VI) reduction and its rate, respectively. The apparent reduction potential of U(VI) increased about 0.2 V in the presence of the mediators, which strongly suggests that the biological electron mediator makes the U(VI) reduction possible even under more oxidative conditions. - Highlights: • The rate constant for the U(VI) reduction by flavin analogues was determined. • The flavins showed a mediator effect on the U(VI) reduction. • The logarithmic rate constants for the U(VI) reduction was proportional to redox potential of the mediator. • The presence of the mediator increased about 0.2 V apparent redox potential of U(VI) to U(IV).

  7. Thermoelectric properties of IV–VI-based heterostructures and superlattices

    Energy Technology Data Exchange (ETDEWEB)

    Borges, P.D., E-mail: pabloborges@ufv.br [Instituto de Ciências Exatas e Tec., Universidade Federal de Viçosa, Rio Paranaíba, MG (Brazil); Department of Physics, Texas State University, San Marcos, TX 78666 (United States); Petersen, J.E.; Scolfaro, L. [Department of Physics, Texas State University, San Marcos, TX 78666 (United States); Leite Alves, H.W. [Departamento de Ciências Naturais, Universidade Federal de São João Del Rei, Caixa Postal 110, São João Del Rei 36300-000, MG (Brazil); Myers, T.H. [Department of Physics, Texas State University, San Marcos, TX 78666 (United States)

    2015-07-15

    Doping in a manner that introduces anisotropy in order to reduce thermal conductivity is a significant focus in thermoelectric research today. By solving the semiclassical Boltzmann transport equations in the constant scattering time (τ) approximation, in conjunction with ab initio electronic structure calculations, within Density Functional Theory, we compare the Seebeck coefficient (S) and figure of merit (ZT) of bulk PbTe to PbTe/SnTe/PbTe heterostructures and PbTe doping superlattices (SLs) with periodically doped planes. Bismuth and Thallium were used as the n- and p-type impurities, respectively. The effects of carrier concentration are considered via chemical potential variation in a rigid band approximation. The impurity bands near the Fermi level in the electronic structure of PbTe SLs are of Tl s- and Bi p-character, and this feature is independent of the doping concentration or the distance between impurity planes. We observe the impurity bands to have a metallic nature in the directions perpendicular to the doping planes, yet no improvement on the values of ZT is found when compared to bulk PbTe. For the PbTe/SnTe/PbTe heterostructures, the calculated S presents good agreement with recent experimental data, and an anisotropic behavior is observed for low carrier concentrations (n<10{sup 18} cm{sup −3}). A large value of ZT{sub ||} (parallel to the growth direction) of 3.0 is predicted for n=4.7×10{sup 18} cm{sup −3} and T=700 K, whereas ZT{sub p} (perpendicular to the growth direction) is found to peak at 1.5 for n=1.7×10{sup 17} cm{sup −3}. Both electrical conductivity enhancement and thermal conductivity reduction are analyzed. - Graphical abstract: Figure of merit for PbTe/SnTe/PbTe heterostructure along the [0 0 1] direction, P.D. Borges, J.E. Petersen, L. Scolfaro, H.W. Leite Alves, T.H. Myers, Improved thermoelectric properties of IV–VI-based heterostructures and superlattices. - Highlights: • Thermoelectric properties of IV–VI

  8. Determination of Cr(VI) in wood specimen: A XANES study at the Cr K edge

    International Nuclear Information System (INIS)

    Strub, E.; Plarre, R.; Radtke, M.; Reinholz, U.; Riesemeier, H.; Schoknecht, U.; Urban, K.; Juengel, P.

    2008-01-01

    The content of chromium in different oxidation states in chromium-treated wood was studied with XANES (X-ray absorption near-edge structure) measurements at the Cr K absorption edge. It could be shown that wood samples treated with Cr(VI) (pine and beech) did still contain a measurable content of Cr(VI) after four weeks conditioning. If such wood samples were heat exposed for 2 h with 135 deg. C prior conditioning, Cr(VI) was no longer detected by XANES, indicating a complete reduction to chromium (III)

  9. Ferric chloride modified zeolite in wastewater on Cr (VI) adsorption characteristics

    Science.gov (United States)

    Wu, Xiaoqing; Zhang, Kang; Chen, Wen; Zhang, Hua

    2018-03-01

    Zeolite was modified by ferric chloride(Fe-Z) removal Cr (VI) ion from wastewater. The results showed that the effect of Cr(VI) adsorption on modified zeolite depended significantly on pH. It is favorable for the adsorption of Cr(VI) in acid condition. The Langmuir isotherm model has high fitting accuracy with experimental data, demonstrated that is monolayer adsorption and chemical adsorption.The pseudo-second-order equation provided the best correlation to the data. The model can describe the adsorption reaction process well.

  10. AR4VI: AR as an Accessibility Tool for People with Visual Impairments

    OpenAIRE

    Coughlan, James M.; Miele, Joshua

    2017-01-01

    Although AR technology has been largely dominated by visual media, a number of AR tools using both visual and auditory feedback have been developed specifically to assist people with low vision or blindness – an application domain that we term Augmented Reality for Visual Impairment (AR4VI). We describe two AR4VI tools developed at Smith-Kettlewell, as well as a number of pre-existing examples. We emphasize that AR4VI is a powerful tool with the potential to remove or significantly reduce a r...

  11. REMOVAL OF Cr(VI FROM AQUEOUS SOLUTION BY ACTIVATED COAL FROM LIGNITE COAL

    Directory of Open Access Journals (Sweden)

    Mehmet MAHRAMANLIOĞLU

    2001-03-01

    Full Text Available Activated coal produced from Ağaçlı Lignite coal was used to remove Cr(VI from aqueous solutions. The adsorption of Cr(VI was studied as a function of initial concentration, time, pH, adsorbent concentration and temperature. The adsorption data were found to fit to Langmuir and Freundlich isotherms. Lagergren equation was used to calculate the adsorption rate. The amount of Cr(VI adsorbed was increased with decreasing pH and decreased with increasing temperature.

  12. Effective Microporosity for Enhanced Adsorption Capacity of Cr (VI) from Dilute Aqueous Solution: Isotherm and Kinetics

    OpenAIRE

    Lloyd Mukosha; Maurice S. Onyango; Aoyi Ochieng; John Siame

    2017-01-01

    The adsorbent pore structure significant to enhanced adsorption capacity of Cr (VI) from dilute aqueous solution is evaluated. As reference, low-cost micro-mesoporous activated carbon (AC) of high basicity, mesoporosity centred about 2.4 nm, and effective microporosity centred about 0.9 nm was tested for removal of Cr (VI) from dilute aqueous solution in batch mode. At pH 2 the low-cost AC exhibited highly improved Langmuir Cr (VI) capacity of 115 mg/g which was competitive to high performanc...

  13. Chromium(VI) release from leather and metals can be detected with a diphenylcarbazide spot test

    DEFF Research Database (Denmark)

    Bregnbak, David; Johansen, Jeanne D.; Jellesen, Morten Stendahl

    2015-01-01

    Along with chromium, nickel and cobalt are the clinically most important metal allergens. However, unlike for nickel and cobalt, there is no validated colorimetric spot test that detects chromium. Such a test could help both clinicians and their patients with chromium dermatitis to identify culprit...... exposures. To evaluate the use of diphenylcarbazide (DPC) as a spot test reagent for the identification of chromium(VI) release. A colorimetric chromium(VI) spot test based on DPC was prepared and used on different items from small market surveys. The DPC spot test was able to identify chromium(VI) release...

  14. Accumulation of type VI collagen in the primary osteon of the rat femur during postnatal development.

    Science.gov (United States)

    Kohara, Yukihiro; Soeta, Satoshi; Izu, Yayoi; Amasaki, Hajime

    2015-05-01

    In rodents, the long bone diaphysis is expanded by forming primary osteons at the periosteal surface of the cortical bone. This ossification process is thought to be regulated by the microenvironment in the periosteum. Type VI collagen (Col VI), a component of the extracellular matrix (ECM) in the periosteum, is involved in osteoblast differentiation at early stages. In several cell types, Col VI interacts with NG2 on the cytoplasmic membrane to promote cell proliferation, spreading and motility. However, the detailed functions of Col VI and NG2 in the ossification process in the periosteum are still under investigation. In this study, to clarify the relationship between localization of Col VI and formation of the primary osteon, we examined the distribution of Col VI and osteoblast lineages expressing NG2 in the periosteum of rat femoral diaphysis during postnatal growing periods by immunohistochemistry. Primary osteons enclosing the osteonal cavity were clearly identified in the cortical bone from 2 weeks old. The size of the osteonal cavities decreased from the outer to the inner region of the cortical bone. In addition, the osteonal cavities of newly formed primary osteons at the outermost region started to decrease in size after rats reached the age of 4 weeks. Immunohistochemistry revealed concentrated localization of Col VI in the ECM in the osteonal cavity. Col VI-immunoreactive areas were reduced and they disappeared as the osteonal cavities became smaller from the outer to the inner region. In the osteonal cavities of the outer cortical regions, Runx2-immunoreactive spindle-shaped cells and mature osteoblasts were detected in Col VI-immunoreactive areas. The numbers of Runx2-immunoreactive cells were significantly higher in the osteonal cavities than in the osteogenic layers from 2 to 4 weeks. Most of these Runx2-immunoreactive cells showed NG2-immunoreactivity. Furthermore, PCNA-immunoreactivity was detected in the Runx2-immunoreactive spindle

  15. Analysis of KROTOS KS-2 and KS-4 steam explosion experiments with TEXAS-VI

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Ronghua, E-mail: rhchen@mail.xjtu.edu.cn [State Key Laboratory of Multiphase Flow in Power Engineering, School of Nuclear Science and Technology, Xi’an Jiaotong University, Xi’an 710049 (China); Wang, Jun [Nuclear Engineering and Engineering Physics, College of Engineering, University of Wisconsin Madison, WI 53706 (United States); Su, G.H.; Qiu, Suizheng [State Key Laboratory of Multiphase Flow in Power Engineering, School of Nuclear Science and Technology, Xi’an Jiaotong University, Xi’an 710049 (China); Corradini, M.L., E-mail: Corradini@engr.wisc.edu [Nuclear Engineering and Engineering Physics, College of Engineering, University of Wisconsin Madison, WI 53706 (United States)

    2016-12-01

    Highlights: • The KS-2 and KS-4 steam explosion experiments were analyzed by TEXAS-VI. • The coarse mixing status up to the explosion triggering time was well predicted by TEXAS-VI. • The predicted dynamic explosion pressure was in good agreement with the experimental results. - Abstract: TEXAS-VI is a transient, three-field, one-dimensional mechanistic model for the steam explosion phenomena. A fuel solidification model and associated fragmentation criteria of the solidifying particle for both the mixing phase and explosion phase were developed and incorporated into TEXAS-VI to account for solidification. In the present study, TEXAS-VI was used to analyze the KS-2 and KS-4 steam explosion experiments, which were performed in the KROTOS facility as part of the OECD-SERENA-2 program. In the simulation, the KROTOS experimental facility was modeled as Eulerian control volumes based on the facility geometry. The molten corium jet was divided up into a series of LaGrangian master particles equal to the initial jet diameter. Both the mixing phase and the explosion phase of the experiments were simulated by TEXAS-VI. Comparison to test data indicates that the fuel jet kinematics and the vapor volume during the mixing phase were well predicted by TEXAS-VI. The TEXAS-VI prediction of the dynamic explosion pressure at different axial locations in the test was also in good agreement with the experimental results. The maximum pressure of KS-2 and KS-4 predicted by TEXAS-VI were 16.7 MPa and 41.9 MPa, respectively. The KS-4 maximum steam explosion pressure predicted by TEXAS-VI was higher than that of KS-2, which was consistent with experiment observation. The observed differences of the dynamic explosion pressure between the KS-2 and KS-4 experiments were also successfully simulated by TEXAS-VI. This suggests that TEXAS-VI is able to analyze the effect of prototypic melt compositions on the steam explosion phenomena. Additional benchmarking and evaluations are ongoing.

  16. Intervening O vi Quasar Absorption Systems at Low Redshift: A Significant Baryon Reservoir.

    Science.gov (United States)

    Tripp; Savage; Jenkins

    2000-05-01

    Far-UV echelle spectroscopy of the radio-quiet QSO H1821+643 (zem=0.297), obtained with the Space Telescope Imaging Spectrograph (STIS) at approximately 7 km s-1 resolution, reveals four definite O vi absorption-line systems and one probable O vi absorber at 0.15quasar in redshift; these are likely intervening systems unrelated to the background QSO. In the case of the strong O vi system at zabs=0.22497, multiple components are detected in Si iii and O vi as well as H i Lyman series lines, and the differing component velocity centroids and b-values firmly establish that this is a multiphase absorption system. A weak O vi absorber is detected at zabs=0.22637, i.e., offset by approximately 340 km s-1 from the zabs=0.22497 system. Lyalpha absorption is detected at zabs=0.22613, but no Lyalpha absorption is significantly detected at 0.22637. Other weak O vi absorbers at zabs=0.24531 and 0.26659 and the probable O vi system at 0.21326 have widely diverse O vi/H i column density ratios with N(O vi)/N(H i) ranging from vi absorbers with rest equivalent width greater than 30 mÅ in the H1821+643 spectrum is remarkably high, dN&solm0;dz approximately 48, which implies with a high (90%) confidence that it is greater than 17 in the low-redshift intergalactic medium. We conservatively estimate that the cosmological mass density of the O vi systems is Omegab(Ovi&parr0; greater, similar0.0008 h-175. With an assumed metallicity of 1/10 solar and a conservative assumption that the fraction of oxygen in the O vi ionization stage is 0.2, we obtain Omegab(Ovi&parr0; greater, similar0.004 h-175. This is comparable to the combined cosmological mass density of stars and cool gas in galaxies and X-ray-emitting gas in galaxy clusters at low redshift.

  17. Separation of molybdenum(VI) by extraction with n-octylaniline from hydrochloric acid medium

    International Nuclear Information System (INIS)

    Sawant, S.S.; Anuse, M.A.; Chavan, M.B.

    1997-01-01

    N-Octylaniline in benzene was used for the extractive separation of molybdenum(VI) from hydrochloric acid medium. Molybdenum(VI) was extracted quantitatively from 10 ml aqueous solution 1.5M in hydrochloric acid and 10M in lithium chloride into 10 ml of 10% n-octylaniline in benzene. It was stripped from the organic phase with 5% aqueous ammonia solution and estimated spectrophotometrically with thiocyanate at 465 nm. The interference of various ions has been studied in detail and conditions have been established for the determination of molybdenum(VI) in synthetic mixtures and alloy samples. (author)

  18. Liquid-liquid extraction of uranium (VI) using Cyanex 272 in kerosene from sodium salicylate medium

    International Nuclear Information System (INIS)

    Kamble, Pravin N.; Mohite, Baburao S.; Suryavanshi, Vishal J.; Salunkhe, Suresh T.

    2015-01-01

    Liquid-liquid extraction of uranium (VI) from sodium salicylate media using Cyanex 272 in kerosene has been carried out. Uranium (VI) was quantitatively extracted from 1x10 -4 M sodium salicylate with 5x10 -4 M Cyanex 272 in kerosene. It was stripped quantitatively from the organic phase with 4M HCl and determined spectrophotometrically with arsenazo(III) at 600 nm. The effects of concentrations of sodium salicylate, metal ions and strippants have been studied. Separation of uranium (VI) from other elements was achieved from binary as well as from multicomponent mixtures. The method is simple, rapid and selective with good reproducibility (approximately ±2%). (author)

  19. Multi-crystalline II-VI based multijunction solar cells and modules

    Science.gov (United States)

    Hardin, Brian E.; Connor, Stephen T.; Groves, James R.; Peters, Craig H.

    2015-06-30

    Multi-crystalline group II-VI solar cells and methods for fabrication of same are disclosed herein. A multi-crystalline group II-VI solar cell includes a first photovoltaic sub-cell comprising silicon, a tunnel junction, and a multi-crystalline second photovoltaic sub-cell. A plurality of the multi-crystalline group II-VI solar cells can be interconnected to form low cost, high throughput flat panel, low light concentration, and/or medium light concentration photovoltaic modules or devices.

  20. Sorption of chromium (VI) by Mg/Fe hydrotalcite type compunds

    Energy Technology Data Exchange (ETDEWEB)

    García-Sosa, I., E-mail: irma.garcia@inin.gob.mx; Cabral-Prieto, A., E-mail: agustin.cabral@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Nava, N., E-mail: tnava@imp.mx; Navarrete, J. [Instituto Mexicano del Petróleo (Mexico); Olguín, M. T., E-mail: teresa.olguin@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Química (Mexico); Escobar, Luis, E-mail: luis.escobar@inin.gob.mx [Instituto Nacional de Investigaciones Nucleares, Departamento de Física (Mexico); López-Castañares, R., E-mail: rlc@anuies.mx; Olea-Cardoso, O., E-mail: olc@anuies.mx [Universidad Autónoma del Edo. de México, Facultad de Química (Mexico)

    2015-06-15

    The synthesis by co-precipitation and characterization by X-ray diffraction, Raman and Mössbauer spectroscopies of Mg-Fe-hydrotalcite compounds, and their sorption capacities for Cr(VI) in aqueous media were carried out. The average sorption capacity of Cr(VI) for the non-thermal treated samples was of 6.2 mg/g. The ferrihydrite was omnipresent in all prepared hydrotalcite samples. A brief discussion is made on the role of both the hydrotalcite and ferrihydrite for removing such amount of Cr(VI)

  1. vi and Vim Editors Pocket Reference Support for every text editing task

    CERN Document Server

    Robbins, Arnold

    2011-01-01

    Many Unix, Linux, and Mac OS X geeks enjoy using the powerful, platform-agnostic text editors vi and Vim, but there are far too many commands for anyone to remember. Author Arnold Robbins has chosen the most valuable commands for vi, Vim, and vi's main clones-vile, elvis, and nvi-and packed them into this easy-to-browse pocket reference. You'll find commands for all kinds of editing tasks, such as programming, modifying system files, and writing and marking up articles. This second edition includes: Command-line optionsvi commands and set optionsInput mode shortcutsSubstitution and regular e

  2. Blockchain kan forbedre sundhedsvæsnet

    DEFF Research Database (Denmark)

    Damsgaard, Jan

    2017-01-01

    Med blockchain-teknologi får vi en mulighed for at gentænke vores udskældte sundheds-IT-systemer.......Med blockchain-teknologi får vi en mulighed for at gentænke vores udskældte sundheds-IT-systemer....

  3. Sorption mechanism of U(VI) on to natural soil system: a study using intra-particle diffusion model

    International Nuclear Information System (INIS)

    Rout, S.; Kumar, A.; Ravi, P.M.; Tripathi, R.M.

    2015-01-01

    The rate of U(VI) adsorption onto natural soils from different parent materials has been studied experimentally using the batch adsorption method at five different initial U(VI) concentrations. The utility of Weber and Morris Interparticle diffusion model for describing the mechanism and kinetics of sorption is discussed. The study reveals that the mechanism of U(VI) sorption involves three steps such as: external surface adsorption, gradual adsorption stage which is the rate determining step and the last portion refers to the final equilibrium stage. The steps involved in sorption of U(VI) on to soil is same irrespective of soil types and initial U(VI) concentration. (author)

  4. Remediation of Cr(VI) contaminated soil using long-duration sodium thiosulfate supported by micro–nano networks

    International Nuclear Information System (INIS)

    He, Lulu; Wang, Min; Zhang, Guilong; Qiu, Guannan; Cai, Dongqing; Wu, Zhengyan; Zhang, Xin

    2015-01-01

    Highlights: • This work aims to develop a long-duration remediation agent (LRA). • LRA was obtained using Na 2 S 2 O 3 supported by attapulgite (ATP) micro–nano networks. • ATP micro–nano networks was induced by high-energy electron beam irradiation. • LRA can effectively control the migration of Cr(VI) and reducing Cr(VI) to Cr(III). • LRA displayed high performance on the remediation of heavy metal contaminated soil. - Abstract: In this work, a long-duration remediation agent (LRA) on hexavalent chromium (Cr(VI)) was developed using sodium thiosulfate (ST) supported by attapulgite (ATP) micro–nano networks induced through high-energy electron beam (HEEB) irradiation. The ATP networks could effectively reduce the leaching amount of Cr(VI) in soil. More importantly, the ATP networks could significantly control the leaching behavior of ST, and then prolong the duration and increase the reduction efficiency of ST on Cr(VI). As a result, LRA displayed high performance on controlling the migration of Cr(VI) and reducing Cr(VI) to Cr(III). Additionally, pot experiment indicated that LRA could effectively decrease the absorbed amount of Cr(VI) in corn, and reduce the inhibition effect of Cr(VI) on the growth of corn. Therefore, this work could provide a facile approach to remediate the Cr(VI)-contaminated soil and lower the harmful effect of Cr(VI) on crop

  5. Remediation of Cr(VI) contaminated soil using long-duration sodium thiosulfate supported by micro–nano networks

    Energy Technology Data Exchange (ETDEWEB)

    He, Lulu [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China); Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Wang, Min; Zhang, Guilong [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Qiu, Guannan [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Cai, Dongqing, E-mail: dqcai@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Wu, Zhengyan, E-mail: zywu@ipp.ac.cn [Key Laboratory of Ion Beam Bioengineering, Hefei Institutes of Physical Science, Chinese Academy of Sciences and Anhui Province, Hefei, Anhui 230031 (China); Bioenergy Forest Research Center of State Forestry Administration, Hefei 230031 (China); Zhang, Xin, E-mail: xinzhang@ahau.edu.cn [School of Life Sciences, Anhui Agricultural University, Hefei 230036 (China)

    2015-08-30

    Highlights: • This work aims to develop a long-duration remediation agent (LRA). • LRA was obtained using Na{sub 2}S{sub 2}O{sub 3} supported by attapulgite (ATP) micro–nano networks. • ATP micro–nano networks was induced by high-energy electron beam irradiation. • LRA can effectively control the migration of Cr(VI) and reducing Cr(VI) to Cr(III). • LRA displayed high performance on the remediation of heavy metal contaminated soil. - Abstract: In this work, a long-duration remediation agent (LRA) on hexavalent chromium (Cr(VI)) was developed using sodium thiosulfate (ST) supported by attapulgite (ATP) micro–nano networks induced through high-energy electron beam (HEEB) irradiation. The ATP networks could effectively reduce the leaching amount of Cr(VI) in soil. More importantly, the ATP networks could significantly control the leaching behavior of ST, and then prolong the duration and increase the reduction efficiency of ST on Cr(VI). As a result, LRA displayed high performance on controlling the migration of Cr(VI) and reducing Cr(VI) to Cr(III). Additionally, pot experiment indicated that LRA could effectively decrease the absorbed amount of Cr(VI) in corn, and reduce the inhibition effect of Cr(VI) on the growth of corn. Therefore, this work could provide a facile approach to remediate the Cr(VI)-contaminated soil and lower the harmful effect of Cr(VI) on crop.

  6. Type VI Secretion System Toxins Horizontally Shared between Marine Bacteria.

    Directory of Open Access Journals (Sweden)

    Dor Salomon

    2015-08-01

    Full Text Available The type VI secretion system (T6SS is a widespread protein secretion apparatus used by Gram-negative bacteria to deliver toxic effector proteins into adjacent bacterial or host cells. Here, we uncovered a role in interbacterial competition for the two T6SSs encoded by the marine pathogen Vibrio alginolyticus. Using comparative proteomics and genetics, we identified their effector repertoires. In addition to the previously described effector V12G01_02265, we identified three new effectors secreted by T6SS1, indicating that the T6SS1 secretes at least four antibacterial effectors, of which three are members of the MIX-effector class. We also showed that the T6SS2 secretes at least three antibacterial effectors. Our findings revealed that many MIX-effectors belonging to clan V are "orphan" effectors that neighbor mobile elements and are shared between marine bacteria via horizontal gene transfer. We demonstrated that a MIX V-effector from V. alginolyticus is a functional T6SS effector when ectopically expressed in another Vibrio species. We propose that mobile MIX V-effectors serve as an environmental reservoir of T6SS effectors that are shared and used to diversify antibacterial toxin repertoires in marine bacteria, resulting in enhanced competitive fitness.

  7. Correlation effects on transition probabilities in Mo vi

    International Nuclear Information System (INIS)

    Froese Fischer, Charlotte

    2011-01-01

    The effect of correlation on transition probabilities for transitions in Mo vi from 4p 6 4d 2 D and 4p 6 5s 2 S to 4p 6 4f, 4p 6 5p, 4p 6 5f, 4p 5 4d 2 with J = 1/2-7/2 is investigated. Non-relativistic correlation studies show the near degeneracy of 4p 5 4d 2 ( 3 F) 2 F o and 4p 5 4d 2 ( 1 G) 2 F o configuration state functions and their strong interaction with 4p 6 5f 2 F o . The multiconfiguration Dirac-Hartree-Fock method is used to include relativistic effects and correlation simultaneously. Wavefunction composition is compared with other theory and with the least-squares fitted values recently published by Reader (2010 J. Phys. B: At. Mol. Opt. Phys. 43 074024). Transition probability data are provided along with data required for accessing accuracy. Results are compared with other published values.

  8. Branching ratios of radiative transitions in O VI

    International Nuclear Information System (INIS)

    Sur, Chiranjib; Chaudhuri, Rajat K

    2007-01-01

    We study the branching ratios of the allowed and forbidden radiative transitions among the first few (9) fine structure levels of O VI using relativistic coupled-cluster theory. We find irregular patterns for a number of transitions within n-complexes with n ≤ 4. We have used the existing values of the allowed electric dipole (E1) transition as a benchmark of our theory. Good agreement with the existing values establish accuracies of not only the theoretical method but the basis function as well. In general, the electric quadrupole (E2) transition probabilities are greater in magnitude than magnetic dipole (M1) transition probabilities, whereas for medium atomic transition frequencies they are of the same order of magnitude. On the other hand, if the transitions involved are in between two fine-structure components of the same term, then the M1 transition probability is more probable than that of E2. The results presented here in tabular and graphical form are compared with the available theoretical and observed data. Graphical analysis helps to understand the trends of electric and magnetic transitions for the decay channels presented here. Our calculated values of the lifetimes of the excited states are in very good agreement with the available results

  9. Sorption of U(VI) species on hydroxyapatite

    International Nuclear Information System (INIS)

    Thakur, P.; Moore, R.C.; Choppin, G.R.

    2005-01-01

    The sorption of uranyl (UO 2 2+ ) cations to hydroxyapatite was studied as a function of the amount of sorbent, ionic strength, U(VI) concentration, pH and temperature. The rate of uranyl sorption on hydroxyapatite decreased with increased uranyl concentrations. The amount sorbed decreased with increased ionic strength and increased with pH to a maximum at 7-8. The sorption data for UO 2 2+ were fitted well by the Freundlich and Dubinin-Radushkevich (D-R) isotherms. The anions Cl - , NO 3 - , SO 4 2- and CH 3 COO - decreased the sorption of uranium on hydroxyapatite while S 2 O 3 2- slightly increased it. The sorbed uranium was desorbed by 0.10 M and 1.00 M solutions of HCl and HNO 3 . The thermodynamic parameters for the sorption of UO 2 2+ were measured at temperatures of 298, 313, 323 and 333 K. The temperature dependence confirmed an endothermic heat of sorption. The activation energy for the sorption process was calculated to be +2.75±0.02 kJ/mol. (orig.)

  10. Recovery of U(Vi) with unexpanded perlite

    International Nuclear Information System (INIS)

    Cuevas J, A.K.; Davila R, J. I.; Lopez del R, H.; Mireles G, F.

    2015-09-01

    Perlite is a glass volcanic rock that is hydrated by the addition of water during its formation. Is a natural material widely used in the chemical and construction industries, but recently beginning to be studied their adsorptive properties. In this paper the adsorption capacity of unexpanded perlite to remove U(Vi) in aqueous solution depending on the grain size of the material was investigated, as well as the contact time between the liquid and solid phases, ph of solution and initial concentration of uranium. The adsorption was dependent on the surface area of the material, recovering higher uranium percentage to smaller particle size. Meanwhile kinetics showed that the uranium adsorption is rapid, reaching equilibrium in 1 h. Adsorption to slightly acidic conditions was favored but dropped dramatically to ph highly acidic and basic; at a concentration of 1 x 10 -3 M UO 2 +2 the maximum uranium recovery was 46% at ph 6. In dilute solutions (1 x 10 -5 to 1 x 10 -3 M) the adsorption percentage reached values between 34 and 42%, but was reduced to 1% at a concentration of 1 x 10 -2 M. (Author)

  11. Density functional study of uranyl (VI) amidoxime complexes

    International Nuclear Information System (INIS)

    Chi Fang-Ting; Xiong Jie; Hu Sheng; Xia Xiu-Long; Wang Xiao-Lin; Li Peng; Gao Tao

    2012-01-01

    Uranyl (VI) amidoxime complexes are investigated using relativistic density functional theory. The equilibrium structures, bond orders, and Mulliken populations of the complexes have been systematically investigated under a generalized gradient approximation (GGA). Comparison of (acet) uranyl amidoxime complexes ([UO 2 (AO) n ] 2−n , 1 ≤ n ≤ 4) with available experimental data shows an excellent agreement. In addition, the U−O(1), U−O(3), C(1)−N(2), and C(3)−N(4) bond lengths of [UO 2 (CH 3 AO) 4 ] 2− are longer than experimental data by about 0.088, 0.05, 0.1, and 0.056 Å. The angles of N(3)−O(3)−U, O(2)−N(1)−C(1), N(3)−C(3)−N(4), N(4)−C(3)−C(4), and C(4)−C(3)−N(3) are different from each other, which is due to existing interaction between oxygen in uranyl and hydrogen in amino group. This interaction is found to be intra-molecular hydrogen bond. Studies on the bond orders, Mulliken charges, and Mulliken populations demonstrate that uranyl oxo group functions as hydrogen-bond acceptors and H atoms in ligands act as hydrogen-bond donors forming hydrogen bonds within the complex

  12. Speedup and fracturing of George VI Ice Shelf, Antarctic Peninsula

    Directory of Open Access Journals (Sweden)

    T. O. Holt

    2013-05-01

    Full Text Available George VI Ice Shelf (GVIIS is located on the Antarctic Peninsula, a region where several ice shelves have undergone rapid breakup in response to atmospheric and oceanic warming. We use a combination of optical (Landsat, radar (ERS 1/2 SAR and laser altimetry (GLAS datasets to examine the response of GVIIS to environmental change and to offer an assessment on its future stability. The spatial and structural changes of GVIIS (ca. 1973 to ca. 2010 are mapped and surface velocities are calculated at different time periods (InSAR and optical feature tracking from 1989 to 2009 to document changes in the ice shelf's flow regime. Surface elevation changes are recorded between 2003 and 2008 using repeat track ICESat acquisitions. We note an increase in fracture extent and distribution at the south ice front, ice-shelf acceleration towards both the north and south ice fronts and spatially varied negative surface elevation change throughout, with greater variations observed towards the central and southern regions of the ice shelf. We propose that whilst GVIIS is in no imminent danger of collapse, it is vulnerable to ongoing atmospheric and oceanic warming and is more susceptible to breakup along its southern margin in ice preconditioned for further retreat.

  13. Atomic Structure of Type VI Contractile Sheath from Pseudomonas aeruginosa.

    Science.gov (United States)

    Salih, Osman; He, Shaoda; Planamente, Sara; Stach, Lasse; MacDonald, James T; Manoli, Eleni; Scheres, Sjors H W; Filloux, Alain; Freemont, Paul S

    2018-02-06

    Pseudomonas aeruginosa has three type VI secretion systems (T6SSs), H1-, H2-, and H3-T6SS, each belonging to a distinct group. The two T6SS components, TssB/VipA and TssC/VipB, assemble to form tubules that conserve structural/functional homology with tail sheaths of contractile bacteriophages and pyocins. Here, we used cryoelectron microscopy to solve the structure of the H1-T6SS P. aeruginosa TssB1C1 sheath at 3.3 Å resolution. Our structure allowed us to resolve some features of the T6SS sheath that were not resolved in the Vibrio cholerae VipAB and Francisella tularensis IglAB structures. Comparison with sheath structures from other contractile machines, including T4 phage and R-type pyocins, provides a better understanding of how these systems have conserved similar functions/mechanisms despite evolution. We used the P. aeruginosa R2 pyocin as a structural template to build an atomic model of the TssB1C1 sheath in its extended conformation, allowing us to propose a coiled-spring-like mechanism for T6SS sheath contraction. Copyright © 2017 The Authors. Published by Elsevier Ltd.. All rights reserved.

  14. Spectrum and energy levels of kryptonlike ion Nb VI

    International Nuclear Information System (INIS)

    Reader, J.; Ekberg, J.O.

    1993-01-01

    The spectrum of five-times ionized niobium, Nb, VI, was observed from 238 to 2700 angstrom with sliding spark discharges on 10.7-m normal- and grazing-incidence spectrographs. Experimental energies were determined for all levels of the 4s 2 4p 6 , 4s 2 4p 6 , 4s 2 4p 5 4d, 4f, 5s, 5p, 5g, 6s, and 4s4p 6 4d configurations as well as some levels of 4p 5 6g. A total of 291 lines were classified as transitions between 88 observed levels. A previous analysis of this spectrum was found to be totally erroneous. Large hyperfine splittings were found for several levels of the 4p 5 5s and 5p configurations. The observed configurations were theoretically interpreted by means of Hartree-Fock calculations and least squares fits of the energy parameters to the observed levels. A revised value of the ionization energy was obtained from the 4p 5 5g and 6g configurations

  15. Radiation effects on II-VI compound-based detectors

    CERN Document Server

    Cavallini, A; Dusi, W; Auricchio, N; Chirco, P; Zanarini, M; Siffert, P; Fougeres, P

    2002-01-01

    The performance of room temperature CdTe and CdZnTe detectors exposed to a radiation source can be strongly altered by the interaction of the ionizing particles and the material. Up to now, few experimental data are available on the response of II-VI compound detectors to different types of radiation sources. We have carried out a thorough investigation on the effects of gamma-rays, neutrons and electron irradiation both on CdTe : Cl and Cd sub 0 sub . sub 9 Zn sub 0 sub . sub 1 Te detectors. We have studied the detector response after radiation exposure by means of dark current measurements and of quantitative spectroscopic analyses at low and medium energies. The deep traps present in the material have been characterized by means of PICTS (photo-induced current transient spectroscopy) analyses, which allow to determine the trap apparent activation energy and capture cross-section. The evolution of the trap parameters with increasing irradiation doses has been monitored for all the different types of radiati...

  16. Reactivity of nitrido complexes of ruthenium(VI), osmium(VI), and manganese(V) bearing Schiff base and simple anionic ligands.

    Science.gov (United States)

    Man, Wai-Lun; Lam, William W Y; Lau, Tai-Chu

    2014-02-18

    Nitrido complexes (M≡N) may be key intermediates in chemical and biological nitrogen fixation and serve as useful reagents for nitrogenation of organic compounds. Osmium(VI) nitrido complexes bearing 2,2':6',2″-terpyridine (terpy), 2,2'-bipyridine (bpy), or hydrotris(1-pyrazolyl)borate anion (Tp) ligands are highly electrophilic: they can react with a variety of nucleophiles to generate novel osmium(IV)/(V) complexes. This Account describes our recent results studying the reactivity of nitridocomplexes of ruthenium(VI), osmium(VI), and manganese(V) that bear Schiff bases and other simple anionic ligands. We demonstrate that these nitrido complexes exhibit rich chemical reactivity. They react with various nucleophiles, activate C-H bonds, undergo N···N coupling, catalyze the oxidation of organic compounds, and show anticancer activities. Ruthenium(VI) nitrido complexes bearing Schiff base ligands, such as [Ru(VI)(N)(salchda)(CH3OH)](+) (salchda = N,N'-bis(salicylidene)o-cyclohexyldiamine dianion), are highly electrophilic. This complex reacts readily at ambient conditions with a variety of nucleophiles at rates that are much faster than similar reactions using Os(VI)≡N. This complex also carries out unique reactions, including the direct aziridination of alkenes, C-H bond activation of alkanes and C-N bond cleavage of anilines. The addition of ligands such as pyridine can enhance the reactivity of [Ru(VI)(N)(salchda)(CH3OH)](+). Therefore researchers can tune the reactivity of Ru≡N by adding a ligand L trans to nitride: L-Ru≡N. Moreover, the addition of various nucleophiles (Nu) to Ru(VI)≡N initially generate the ruthenium(IV) imido species Ru(IV)-N(Nu), a new class of hydrogen-atom transfer (HAT) reagents. Nucleophiles also readily add to coordinated Schiff base ligands in Os(VI)≡N and Ru(VI)≡N complexes. These additions are often stereospecific, suggesting that the nitrido ligand has a directing effect on the incoming nucleophile. M≡N is also

  17. Estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyVi® en ratones

    Directory of Open Access Journals (Sweden)

    Juan Carlos Ramírez

    2006-08-01

    Full Text Available Salmonella enterica serovar Typhi es un microorganismo que provoca más de 16 millones de casos de fiebre tifoidea con aproximadamente 600 000 muertes al año en todo el mundo. Dentro de las vacunas antitifoídicas la de polisacárido capsular Vi ha encontrado, gracias a sus incuestionables ventajas, una gran aceptación entre productores y consumidores. El presente trabajo aborda el estudio de inmunogenicidad de la vacuna antitifoídica cubana de polisacárido Vi vax-TyViâ en ratones. El estudio estuvo conformado por un grupo control no inoculado y un segundo grupo que recibió 0,05 mL de la vacuna por vía intramuscular. Se tomaron muestras de sangre a los -3, 7, 14, 21, 28, 42, 56 y 84 días. La actividad de anticuerpos IgG antipolisacárido Vi de los sueros individuales fue determinada por ELISA. Los datos fueron analizados por grupo y por sexo y se calculó el porcentaje de seroconversión, considerándose respondedor aquel animal que al menos aumentara en cuatro veces su título inicial. La respuesta de anticuerpos inducida por la vacuna mostró un aumento notable de los títulos de IgG antipolisacárido Vi en el grupo vacunado (100% de seroconversión, mientras que el grupo control no incrementó sus niveles mínimos iniciales (0% de respondedores. Aunque más dispersa, la respuesta de anticuerpos antiVi fue significativamente mayor en las hembras que en los machos.

  18. Preparation of N-1 -naphthyl benzo- and N-phenyl benzo hydroxamic acids and study of their extractability towards Fe (III), Cr (VI) and U (VI)

    International Nuclear Information System (INIS)

    Mohamed, Eltoum Elnour

    1997-12-01

    Two aryl hydroxamic acids were prepared; The N-phenyl benzo hydroxamic acid and the N-1- naphthyl benzohydroxamic acid the first one was prepared by the partial reduction of nitrobenzene to the β-phenyl hydroxylamine and coupling the latter with benzyl chloride. The reduction was carried out using ammonium chloride and zinc dust; this pair failed after so many attempts to give the N-1- naphthyl hydroxylamine. So the latter was prepared by using a somewhat milder reducing agent; hydrogen sulphide and ammonia gas in absolute alcohol. The two acids were obtained using the modified procedure of Tandon coupling the hydroxylamine with benzoyl chloride. The two acids were characterized by their melting points, elemental analysis, their I.R functional group frequencies and by their characteristic colour tests with vanadium (VI) and Iron (III). The acids were used for the extraction and spectrophotometric determination for iron (III), Chromium (VI), and Uranium (VI) from different molar solution, PH and from synthetic sea water. The maximum recovery of iron (III) occurred at PH 4 and PH 5 giving 92.25 and 91.25% when using N-1-naphthyl benzo hydroxamic acid and a maximum recovery of 100% at PH 5 with other acid. The maximum recovery of Chromium (VI) occurred at 3MH 2 SO 4 of 97.50% when using N-1-naphthyl benzohydroxamic acid and a maximum of 94.25% at the same molar concentration with N-phenyl benzo hydroxamic acid. The maximum recovery for Uranium (VI) was occurred at PH 7 giving 100% when using N-1-naphthyl benzo hydroxamic acid and a maximum recovery of 85% at PH 7 and PH* with the other acid. The two reagents give sharp colour with both iron (III) and chromium (VI), so trials were carried out to compare the curves obtained with that of the original reagent i.e. Thiocynate and diphenylcarbazide, which give a smaller slope.(Author)

  19. Uranium(VI) sorption on iron oxides in Hanford Site sediment: Application of a surface complexation model

    International Nuclear Information System (INIS)

    Um, Wooyong; Serne, R. Jeffrey; Brown, Christopher F.; Rod, Kenton A.

    2008-01-01

    Sorption of U(VI) on Hanford fine sand (HFS) with varying Fe-oxide (especially ferrihydrite) contents showed that U(VI) sorption increased with the incremental addition of synthetic ferrihydrite into HFS, consistent with ferrihydrite being one of the most reactive U(VI) sorbents present in natural sediments. Surface complexation model (SCM) calculations for U(VI) sorption, using only U(VI) surface-reaction constants obtained from U(VI) sorption data on freshly synthesized ferrihydrite at different pHs, were similar to the measured U(VI) sorption results on pure synthetic ferrihydrite and on HFS with high contents of ferrihydrite (5 wt%) added. However, the SCM prediction using only U(VI) sorption reactions and constants for synthetic ferrihydrite overestimated U(VI) sorption on the natural HFS or HFS with addition of low amounts of added ferrihydrite (1 wt% added). Over-predicted U(VI) sorption was attributed to reduced reactivity of natural ferrihydrite present in Hanford Site sediments, compared to freshly prepared synthetic ferrihydrite. Even though the SCM general composite (GC) approach is considered to be a semi-quantitative estimation technique for contaminant sorption, which requires systematic experimental data on the sorbent-sorbate system being studied to obtain credible SCM parameters, the general composite SCM model was still found to be a useful technique for describing U(VI) sorption on natural sediments. Based on U(VI) batch sorption results, two simple U(VI) monodentate surface species, SO U O 2 HCO 3 and SO U O 2 OH on ferrihydrite and phyllosillicate in HFS, respectively, can be successfully used to describe U(VI) sorption onto Hanford Site sediment contacting varying geochemical solutions

  20. Immediate remediation of heavy metal (Cr(VI)) contaminated soil by high energy electron beam irradiation

    International Nuclear Information System (INIS)

    Zhang, Jing; Zhang, Guilong; Cai, Dongqing; Wu, Zhengyan

    2015-01-01

    Highlights: • An immediate remediation method for Cr(VI) contaminated soil (CCS) was developed. • High energy electron beam (HEEB) irradiation could reduce Cr(VI) in CCS to Cr(III). • This effect was attributed to electrons, hydrated electrons, and reductive radicals. • This remediation method was effective, environmentally friendly, and low-cost. - Abstract: This work developed an immediate and high-performance remediation method for Cr(VI) contaminated soil (CCS) using high energy electron beam (HEEB) irradiation. The result indicated that, compared with γ-ray irradiation, HEEB irradiation displayed a significant reduction efficiency on Cr(VI) in CCS to Cr(III) with substantially lower toxicity, which was mainly attributed to the reduction effects of electrons, hydrated electrons, and reductive radicals generated in the irradiation process of HEEB. This work could provide a one-step and effective method for the remediation of heavy metal contaminated soil (HMCS)