Solubility study of Tc(IV) oxides

International Nuclear Information System (INIS)

Liu, D.J.; Fan, X.H.

2005-01-01

The deep geological disposal of the high level radioactive wastes is expected to be a safer disposal method in most countries. The long-lived fission product 99 Tc is present in large quantities in nuclear wastes and its chemical behavior in aqueous solution is of considerable interest. Under oxidizing conditions technetium exists as the anionic species TcO 4 - whereas under the reducing conditions, expected to exist in a deep geological repository, it is generally predicted that technetium will be present as TcO 2 ·nH 2 O. Hence, the mobility of Tc(IV) in reducing groundwater may be limited by the solubility of TcO 2 ·nH 2 O under these conditions. Due to this fact it is important to investigate the solubility of TcO 2 ·nH 2 O. The solubility determines the release of radionuclides from waste form and is used as a source term in radionuclide migration analysis in performance assessment of radioactive waste repository. Technetium oxide was prepared by reduction of a technetate solution with Sn 2 + . The solubility of Tc(IV) oxide has been determined in simulated groundwater and redistilled water under aerobic and anaerobic conditions. The effects of pH and CO 3 2- concentration of solution on solubility of Tc(IV) oxide were studied. The concentration of total technetium and Tc(IV) species in the solutions were periodically determined by separating the oxidized and reduced technetium species using a solvent extraction procedure and counting the beta activity of the 99 Tc with a liquid scintillation counter. The experimental results show that the rate of oxidation of Tc(IV) in simulated groundwater and redistilled water is about (1.49-1.86) x 10 -9 mol/(L·d) under aerobic conditions, but Tc(IV) in simulated groundwater and redistilled water is not oxidized under anaerobic conditions. Under aerobic or anaerobic conditions the solubility of Tc(IV) oxide in simulated groundwater and redistilled water is equal on the whole after centrifugation or ultrafiltration. The

Upper critical field measurements in high-Tc superconducting oxides

Science.gov (United States)

Ousset, J. C.; Bobo, J. F.; Ulmet, J. P.; Rakoto, H.; Cheggour, N.

We present upper critical field measurements on the superconducting oxides RE Ba2Cu3O7-δ (RE = Y, Gd) performed in a pulsed magnetic field up to 43 T. Values for Hc2 as high as 52 T and 77 T for Y and Gd respectively, are expected at 77 K. However, in order to observe no resistive behaviour up to 43 T the temperature must be decreased down to 50 K. In the case of oxygen deficient systems the magnetoresistance reveals two superconducting phases wich could be related to two different orders of oxygen vacancies. Nous présentons des mesures de champ critique Hc2 sur les supraconducteurs TR Ba 2Cu3O7-δ (TR = Y, Gd) réalisées en champ magnétique pulsé jusqu'à 43 T. Elles permettent de prévoir des valeurs de H c2 de 52 T et 77 T respectivement pour Y et Gd à 77 K. Cependant, pour ne pas observer de comportement résistif jusqu'au champ maximum, il est nécessaire de refroidir l'échantillon jusqu'à 50 K. Dans le cas des systèmes déficients en oxygène (δ important) nous mettons en évidence l'existence de deux phases supraconductrices qui pourraient être dues à deux ordres différents des lacunes d'oxygène.

Critical current of high Tc superconducting Bi223/Ag tapes

NARCIS (Netherlands)

Huang, Y.; ten Haken, Bernard; ten Kate, Herman H.J.

1998-01-01

The magnetic field dependence of the critical current of various high Tc superconducting Bi2223/Ag tapes indicates that the transport current is carried through two paths: one is through weakly-linked grain boundaries (Josephson junctions); another is through well-connected grains. The critical

Analysis of eddy current loss in high-Tc superconducting power cables with respect to various structure of stabilizer

International Nuclear Information System (INIS)

Choi, S. J.; Song, M. K.; Lee, S. J.; Cho, J. W.; Sim, K. D.

2005-01-01

The High-Tc superconducting power cable consists of a multi-layer high-Tc superconducting cable core and a stabilizer which is used to bypass the current at fault time. Eddy current loss is generated in the stabilizer in normal operating condition and affects the whole system. In this paper, the eddy current losses are analyzed with respect to various structure of stabilizer by using opera-3d. Moreover, optimal conditions of the stabilizer are derived to minimize the eddy current losses from the analyzed results. The obtained results could be applied to the design and manufacture of the high-Tc superconducting power cable system.

Theory of high-Tc superconducting cuprates based on experimental evidence

International Nuclear Information System (INIS)

Abrikosov, A. A.

1999-01-01

A model of superconductivity in layered high-temperature superconducting cuprates is proposed, based on the extended saddle point singularities in the electron spectrum, weak screening of the Coulomb interaction and phonon-mediated interaction between electrons plus a small short-range repulsion of Hund's, or spin-fluctuation, origin. This permits to explain the large values of Tc, features of the isotope effect on oxygen and copper, the existence of two types of the order parameter, the peak in the inelastic neutron scattering, the positive curvature of the upper critical field, as function of temperature etc

Unconventional superconductivity in heavy fermionic and high-Tc superconductors

International Nuclear Information System (INIS)

Volovik, G.E.

1989-01-01

Splitting of the superconducting transition and glass spectrum in heavy fermion companies and oxide superconductors are discussed. The multicomponent order parameter leads to splitting of transition due to magnetic field, impurities, orthorhombic distortion, etc... Linear specific heat in oxide superconductors may be explained in terms of the Fermi-surface arising in superconducting state if interband is pairing strong enough

The stability of high-Tc BSCCO/Ag superconducting microcomposites in water, some inorganic solutions and organic solvents

International Nuclear Information System (INIS)

Gao, W.; Chen, J.; Yang, C.O.; McNabb, D.; Sande, J. vander

1992-01-01

Bi(Pb)-Sr-Ca-Cu-O/Ag (BSCCO/Ag) superconducting microcomposites with zero-resistance temperatures from 102 to 108 K and critical current densities of ∝600 A/cm 2 at 77 K were produced by oxidation and annealling of metallic precursor alloys. The stabilities and degradation behavior of BSCCO/Ag specimens in various environments were studied by a combination of mass loss measurement, electrical transport measurement and microstructural observation. The environmental conditions used in the present work were moist air, distilled water, aqueous solutions of NaCl, NaOH and acetic acid, and organic solvents methanol and acetone. Although there is a general tendency toward a decrease in critical current density after a long exposure to most of the testing conditions, the specimens containing a high percent of Ag (≥70 wt.%) showed very little decrease in Tc and J c up to 200 days of exposure in moist air and distilled water, and up to 20 days in NaCl solution, methanol and acetone. It was found that the superconducting ''2223'' phase is stable in water, neutral solutions and the organic solvents, reacts very slowly with basic solutions, and dissolves rapidly in acidic solutions. Some non-superconducting Ca-rich oxides dissolve in water and neutral and basic solutions and therefore damage the connection of the superconducting grains in low-Ag containing specimens. The excellent stability of the BSCCO/Ag superconducting microcomposites containing high Ag provides an important advantage for their potential industrial application. (orig.)

High-Tc superconducting microbolometer for terahertz applications

Science.gov (United States)

Ulysse, C.; Gaugue, A.; Adam, A.; Kreisler, A. J.; Villégier, J.-C.; Thomassin, J.-L.

2002-05-01

Superconducting hot electron bolometer mixers are now a competitive alternative to Schottky diode mixers in the terahertz frequency range because of their ultra wideband (from millimeter waves to visible light), high conversion gain, and low intrinsic noise level. High Tc superconductor materials can be used to make hot electron bolometers and present some advantage in term of operating temperature and cooling. In this paper, we present first a model for the study of superconducting hot electron bolometers responsivity in direct detection mode, in order to establish a firm basis for the design of future THz mixers. Secondly, an original process to realize YBaCuO hot electron bolometer mixers will be described. Submicron YBaCuO superconducting structures are expitaxially sputter deposited on MgO substrates and patterned by using electron beam lithography in combination with optical lithography. Metal masks achieved by electron beam lithography are insuring a good bridge definition and protection during ion etching. Finally, detection experiments are being performed with a laser at 850 nm wavelength, in homodyne mode in order to prove the feasibility and potential performances of these devices.

Superconducting and Structural Transitions in the β-Pyrochlore Oxide KOs2O6 under High Pressure

Science.gov (United States)

Ogusu, Hiroki; Takeshita, Nao; Izawa, Koichi; Yamaura, Jun-ichi; Ohishi, Yasuo; Tsutsui, Satoshi; Okamoto, Yoshihiko; Hiroi, Zenji

2010-11-01

Rattling-induced superconductivity in the β-pyrochlore oxide KOs2O6 is investigated under high pressure up to 5 GPa. Resistivity measurements in a high-quality single crystal reveal a gradual decrease in the superconducting transition temperature Tc from 9.7 K at 1.0 GPa to 6.5 K at 3.5 GPa, followed by a sudden drop to 3.3 K at 3.6 GPa. Powder X-ray diffraction experiments show a structural transition from cubic to monoclinic or triclinic at a similar pressure. The sudden drop in Tc is ascribed to this structural transition, by which an enhancement in Tc due to a strong electron-rattler interaction present in the low-pressure cubic phase is abrogated as the rattling of the K ion is completely suppressed or weakened in the high-pressure phase of reduced symmetry. In addition, we find two anomalies in the temperature dependence of resistivity in the low-pressure phase, which may be due to subtle changes in rattling vibration.

Superconductivity at 43K in SmFeAsO1-xFx

Science.gov (United States)

Chen, X. H.; Wu, T.; Wu, G.; Liu, R. H.; Chen, H.; Fang, D. F.

2008-06-01

Since the discovery of high-transition-temperature (high-Tc) superconductivity in layered copper oxides, extensive effort has been devoted to exploring the origins of this phenomenon. A Tc higher than 40K (about the theoretical maximum predicted from Bardeen-Cooper-Schrieffer theory), however, has been obtained only in the copper oxide superconductors. The highest reported value for non-copper-oxide bulk superconductivity is Tc = 39K in MgB2 (ref. 2). The layered rare-earth metal oxypnictides LnOFeAs (where Ln is La-Nd, Sm and Gd) are now attracting attention following the discovery of superconductivity at 26K in the iron-based LaO1-xFxFeAs (ref. 3). Here we report the discovery of bulk superconductivity in the related compound SmFeAsO1-xFx, which has a ZrCuSiAs-type structure. Resistivity and magnetization measurements reveal a transition temperature as high as 43K. This provides a new material base for studying the origin of high-temperature superconductivity.

High Tc superconducting three-terminal device under quasi-particle injection

International Nuclear Information System (INIS)

Hashimoto, K.; Kabasawa, U.; Tonouchi, M.; Kobayashi, T.

1988-01-01

A new type of the current injection type three terminal device was fabricated using the high Tc YBaCuO thin epitaxial films, wherein the hot quasi-particle injection effect on the superconducting current was closely examined. The zero bias drain current was efficiently suppressed by the injection of the hot quasi-particles through the gate electrode. Though it is speculative, a comparison of the experimental results and analyses based on the familiar BCS theory intimates that the main mechanism of the current modulation is the non-equilibrium superconductivity due to accumulation of the excess quasi-particles

Structural, electronic, superconducting and mechanical properties of ReC and TcC

Energy Technology Data Exchange (ETDEWEB)

Kavitha, M.; Priyanga, G. Sudha; Rajeswarapalanichamy, R., E-mail: rajeswarapalanichamy@gmail.com; Santhosh, M. [Department of Physics, N.M.S.S.V.N College, Madurai, Tamilnadu-625019 (India)

2015-06-24

The structural, electronic, superconducting and mechanical properties of ReC and TcC are investigated using density functional theory calculations. The lattice constants, bulk modulus, and the density of states are obtained. The calculated lattice parameters are in good agreement with the available results. The density of states reveals that ReC and TcC exhibit metallic behavior at ambient condition. A pressure-induced structural phase transition is observed in both materials.

High-Tc superconductivity in the d-p electron system

International Nuclear Information System (INIS)

Ivanov, V.A.; Zaitsev, R.A.

1991-01-01

The relaxation time with spin flip τ s and the parameters ξ, δ, χ of superconducting phase have been calculated on the basis of the kinematical mechanism of superconductivity in strongly correlated oxide models. An inter-relation between the superconducting gap Δ o and the specific heat jump Δ c allowing the experimental verification was obtained and the Ginsburg-Landau equation derived. (author). 8 refs., 2 figs

High Tc superconducting energy storage systems

Energy Technology Data Exchange (ETDEWEB)

Werfel, Frank [Adelwitz Technologiezentrum GmbH (ATZ), Arzberg-Adelwitz (Germany)

2012-07-01

Electric energy is basic to heat and light our homes, to power our businesses and to transport people and goods. Powerful storage techniques like SMES, Flywheel, Super Capacitor, and Redox - Flow batteries are needed to increase the overall efficiency, stability and quality of electrical grids. High-Tc superconductors (HTS) possess superior physical and technical properties and can contribute in reducing the dissipation and losses in electric machines as motors and generators, in electric grids and transportation. The renewable energy sources as solar, wind energy and biomass will require energy storage systems even more as a key technology. We survey the physics and the technology status of superconducting flywheel energy storage (FESS) and magnetic energy storage systems (SMES) for their potential of large-scale commercialization. We report about a 10 kWh / 250 kW flywheel with magnetic stabilization of the rotor. The progress of HTS conductor science and technological engineering are basic for larger SMES developments. The performance of superconducting storage systems is reviewed and compared. We conclude that a broad range of intensive research and development in energy storage is urgently needed to produce technological options that can allow both climate stabilization and economic development.

Rapid solidification for preparation of high Tc superconductors

International Nuclear Information System (INIS)

Yavari, A.R.

1988-01-01

High Tc superconducting oxides are prepared in two different ways using rapid solidification: by oxidation of microcrystalline or amorphous tapes obtained by quenching the liquid alloy and via crystallisation of the amorphous oxide obtained by rapid quenching of the oxide melt. This technique is applied for the first time to the BiCaSrCuO family [fr

Characterization of superconducting thin films by infrared reflection

International Nuclear Information System (INIS)

Gervais, F.

1988-01-01

Infrared reflectivity spectroscopy is shown to be a powerful tool to characterize the new high-Tc oxide superconductors since it gives information about the superconducting gap, phonons, plasmon and possibly low-energy electronic excitations such as excitons, information relevant to understand the mechanism of superconductivity [fr

Uniaxial strain orientation dependence of superconducting transition temperature (Tc) and critical superconducting pressure (Pc) in β-(BDA-TTP)2I3.

Science.gov (United States)

Kikuchi, Koichi; Isono, Takayuki; Kojima, Masayuki; Yoshimoto, Haruo; Kodama, Takeshi; Fujita, Wataru; Yokogawa, Keiichi; Yoshino, Harukazu; Murata, Keizo; Kaihatsu, Takayuki; Akutsu, Hiroki; Yamada, Jun-ichi

2011-12-14

Dependence of the superconducting transition temperature (T(c)) and critial superconducting pressure (P(c)) of the pressure-induced superconductor β-(BDA-TTP)(2)I(3) [BDA-TTP = 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene] on the orientation of uniaxial strain has been investigated. On the basis of the overlap between the upper and lower bands in the energy dispersion curve, the pressure orientation is thought to change the half-filled band to the quarter-filled one. The observed variations in T(c) and P(c) are explained by considering the degree of application of the pressure and the degree of contribution of the effective electronic correlation at uniaxial strains with different orientations parallel to the conducting donor layer. © 2011 American Chemical Society

A study on the development of high Tc superconducting materials and on the effects of neutron irradiation

International Nuclear Information System (INIS)

Won, Dong Yeon; Chang, In Soon; Lee, Jong Min

1990-08-01

An Ag-sheathed (Pb,Bi)SrCaCuO superconducting tape was prepared by the cold rolling and post heat treatment method. The tape shows a c-oriented texture perpendicular to the rolling direction. The aligned grain structure may be resulted from the anisotropic grain growth of the high Tc superconducting phase. The bulk (Pb,Bi)SrCaCuO samples with (a) Tc=10lK and (b) 96K were prepared by the solid state reaction method and were neutron-irradiated up to 1.5 x 10 1 8 n/cm 2 . After irradiation the zero resistance temperature(Tc) of (a) was decreased to 96K but (b) did not show any change in Tc. The critical current density of (a) also decreased from 0.75A/cm 2 but (b) was constant as 1.5 A/cm 2 after irradiation. (Author)

Korea's developmental program for superconductivity

Science.gov (United States)

Hong, Gye-Won; Won, Dong-Yeon; Kuk, Il-Hyun; Park, Jong-Chul

1995-04-01

Superconductivity research in Korea was firstly carried out in the late 70's by a research group in Seoul National University (SNU), who fabricated a small scale superconducting magnetic energy storage system under the financial support from Korea Electric Power Company (KEPCO). But a few researchers were involved in superconductivity research until the oxide high Tc superconductor was discovered by Bednorz and Mueller. After the discovery of YBaCuO superconductor operating above the boiling point of liquid nitrogen (77 K)(exp 2), Korean Ministry of Science and Technology (MOST) sponsored a special fund for the high Tc superconductivity research to universities and national research institutes by recognizing its importance. Scientists engaged in this project organized 'High Temperature Superconductivity Research Association (HITSRA)' for effective conducting of research. Its major functions are to coordinate research activities on high Tc superconductivity and organize the workshop for active exchange of information. During last seven years the major superconductivity research has been carried out through the coordination of HITSRA. The major parts of the Korea's superconductivity research program were related to high temperature superconductor and only a few groups were carrying out research on conventional superconductor technology, and Korea Atomic Energy Research Institute (KAERI) and Korea Electrotechnology Research Institute (KERI) have led this research. In this talk, the current status and future plans of superconductivity research in Korea will be reviewed based on the results presented in interim meeting of HITSRA, April 1-2, 1994. Taejeon, as well as the research activity of KAERI.

Dependence of the quasiparticle recombination rate on the superconducting gap and TC

Science.gov (United States)

Carr, G. L.; Xi, Xiaoxiang; Hwang, J.; Tashiro, H.; Reitze, D. H.; Tanner, D. B.

2010-03-01

The relaxation of excess quasiparticles in a BCS superconductor is known to depend on quantities such as the quasiparticle & phonon density of states, and their coupling (Kaplan et al, Phys. Rev. B 14 4854, 1976). Disorder or an applied field can disrupt superconductivity, as evidenced by a reduced TC. We consider some simple modifications to the quasiparticle density of states consistent with a suppressed energy gap and TC, leading to changes in the intrinsic and effective (measured) rates for excess quasiparticles to recombine into pairs. We review some results for disordered MoGe and discuss the magnetic-field dependence of the recombination process.

Superconductive properties, interaction mechanisms, materials preparation and electronic transport in high-Tc superconductors

International Nuclear Information System (INIS)

Saemann-Ischenko, G.

1993-01-01

The final report is composed of eight chapters dealing with the following aspects: I. Mixed state, critical currents, anisotropy, intrinsic and extrinsic pinning. II. Microwave properties and far-infrared reflectivity of epitactic HTSC films. III. Hall effect at the states of normal conductivity and superconductivity, magnetoresistance, superconducting fluctuation phenomena. IV. Effects of the nuclear and the electronic energy loss. V. Scanning electron microscopy. VI. p- and n-doped high-Tc superconductors: Charge symmetry and magnetism. VII. Preparation methods. VIII. Electrochemical examinations of HTSC films and HTSC monocrystals at low temperatures. (orig./MM) [de

Laser patterning of superconducting oxide films

International Nuclear Information System (INIS)

Gupta, A.; Hussey, B.W.; Koren, G.; Cooper, E.I.; Jagannathan, R.

1988-01-01

The focused output of an argon ion laser (514.5 nm) has been used for wiring superconducting lines of Y/sub 1/Ba/sub 2/CU/sub 3/O/sub 7-δ/ using films prepared from nitrate and trifluoroacetate solution precursors. A stoichiometric solution of the precursors is sprayed or spun on to the substrate to form a film. The film is patterned by irradiating in selected areas to convert the irradiated layers to an intermediate oxide or fluoride state, the nonirradiated areas being unchanged. The nonirradiated areas are then dissolved away, leaving a pattern of the oxide or fluoride material. This patterned layer is converted to the superconducting 1-2-3 oxide in a subsequent annealing step. Maskless patterning of superconducting films has also been demonstrated by laser-assisted etching of the films in aqueous KOH solution. Although superconductivity is destroyed when the films are placed in solution, it can be restored after a brief anneal in oxygen

Studies of Tc oxidation states in humic acid solutions

International Nuclear Information System (INIS)

Wang Bo; Liu Dejun; Yao Jun

2011-01-01

The oxidation state of Tc is an important aspect of the speciation in groundwater which contained organic substances due to it control the precipitation, complexation, sorption and colloid formation behavior of the Tc under HWL geological disposal conditions. In present work, the oxidation states of Tc were investigated using the LaCl 3 coagulation method and solution extraction method in aqueous solutions in which the humic acid concentration range is from 0 to 20 mg/L and the Tc (VII) concentration is about 10 -8 mol/L. The radiocounting of 99 Tc was determined using liquid scintillation spectrometry. The humic acid will influence the radiocounting ratio of 99 Tc apparently, however, the quenching effect can be restrained once keep the volume of the cocktail to about twenty times of the sample volume. The LaCl 3 coagulation method was carried out for the investigation of Tc oxidation states in humic acid aqueous systems at about pH 8. The tetraphenylarsonium chloride (TPA)-chloroform extraction method was used also simultaneously to investigation the concentrations of Tc (IV) and Tc (VII) for the availability of the LaCl 3 precipitation method, and the experimental results demonstrate that tetravalent technetium and pertechnetate concentration are well agreement with the LaCl 3 precipitation method. These two experimental results demonstrated that Tc (VII) is very stable in the Tc (VII)-humic acid system during a 350 days experimental period, and the Tc (IV) concentrations are very lower, that is indicate that there didn't oxidizing reactions between the Fluka humic acid and Tc (VII) in aqueous solutions under anaerobic conditions. That means the presence of humic acids even in anaerobic groundwater is disadvantage for the retardance of radionuclides. (authors)

Abrupt onset of a second energy gap at the superconducting transition of underdoped Bi2212

Energy Technology Data Exchange (ETDEWEB)

Hussain, Zahid; Lee, W.S.; Vishik, I.M.; Tanaka, K.; Lu, D.H.; Sasagawa, T.; Nagaosa, N.; Devereaux, T.P.; Hussain, Z.; Shen, Z.-X.

2007-05-26

he superconducting gap--an energy scale tied to the superconducting phenomena--opens on the Fermi surface at the superconducting transition temperature (Tc) in conventional BCS superconductors. In underdoped high-Tc superconducting copper oxides, a pseudogap (whose relation to the superconducting gap remains a mystery) develops well above Tc (refs 1, 2). Whether the pseudogap is a distinct phenomenon or the incoherent continuation of the superconducting gap above Tc is one of the central questions in high-Tc research3, 4, 5, 6, 7, 8. Although some experimental evidence suggests that the two gaps are distinct9, 10, 11, 12, 13, 14, 15, 16, 17, 18, this issue is still under intense debate. A crucial piece of evidence to firmly establish this two-gap picture is still missing: a direct and unambiguous observation of a single-particle gap tied to the superconducting transition as function of temperature. Here we report the discovery of such an energy gap in underdoped Bi2Sr2CaCu2O8+delta in the momentum space region overlooked in previous measurements. Near the diagonal of Cu?O bond direction (nodal direction), we found a gap that opens at Tc and has a canonical (BCS-like) temperature dependence accompanied by the appearance of the so-called Bogoliubov quasi-particles, a classical signature of superconductivity. This is in sharp contrast to the pseudogap near the Cu?O bond direction (antinodal region) measured in earlier experiments19, 20, 21.

The microscopic twins and their crystal phase in the high Tc Y-Ba-Cu-O and Dy-Ba-Cu-O superconductive ceramics

International Nuclear Information System (INIS)

Zu, Z.J.; Chen, Y.L.

1988-01-01

Most consider that the structure of Y-Ba- Cu-O and Dy-Ba-Cu-O stable superconductive crystals with high Tc is associated with the right-angled phase. The superconductivity is closely connected with the right-angled character of the crystalline texture; the better the right- angled character, the better the superconductivity. From statistical investigations of examples the authors have discovered that most of the Y-Ba-Cu-O and Dy-Ba-Cu-O superconductivity with high Tc ceramic crystals is in the monoclinic phase, which, consists of microscopic, lamellar, single twins. The long-columnar grains consisting of lamellar twin slabs show the optical characteristics of right-angled phase. The microscopic twinning and grain morphologies are summarized in this paper

Fabrication of superconducting wire using organometallic precursors and infiltration

International Nuclear Information System (INIS)

Lee, Y.J.

1991-01-01

Organometallic precursors from naphthenic acid and metal nitrates were used for the synthesis of YBCO oxide superconducting compounds. The characteristics of metal naphthenates as organometallic precursors were investigated by IR spectra, viscosity measurements, and infiltration. 123 superconducting compound obtained from 123 naphthenate showed a Tc of 90 degree K and a rather dense and elongated microstructure. Also, the melting behavior of Ba-cuprates which were used for 123 making was studied. A low-temperature melting process was developed to fabricate silver-sheathed superconducting wire with the powder-in-tube method; flowing argon gas is introduced to the system at 930-945 degree C to reduce the melting temperature of the 123 compound without silver sheath melting. It resulted in a 90 degree K Tc superconducting core with dense and locally aligned microstructure. SEM-EDS and XRD analysis, 4-probe resistance and Jc measurements, and carbon-content determinations were carried out to characterize the microstructure, grain alignment, and superconducting properties of the samples

Studies of the Tc oxidation states in humic acid solutions

International Nuclear Information System (INIS)

Wang Bo; Liu Dejun; Yao Jun

2010-01-01

The oxidation state is an important aspect of the speciation of Tc in groundwater that contained organic substances due to it control the precipitation, complexation, sorption and colloid formation behavior of the Tc under HWL geological disposal conditions. In present work, the oxidation states of Tc were investigated using the LaCl 3 coagulation method and solution extraction method in aqueous solutions in which the humic acid concentration range is from 0 to 20 mg L -1 and the Tc (Ⅶ) concentration range is about 10 -8 mol l -1 . The radiocounting of 99 Tc was determined using liquid scintillation spectrometry. The humic acid will influence the radiocounting ratio of 99 Tc apparently, however, the quenching effect can be restrained once keep the volume of the cocktail to about twenty times of the sample volume. The LaCl 3 coagulation methods were carried out for the investigation of Tc oxidation states in humic acid aqueous systems at about pH 8. The tetraphenylarsonium chloride (IPA)-chloroform extraction method was used also simultaneously to investigation the concentrations of Tc (Ⅳ) and Tc (Ⅶ) for the availability of the LaCl 3 precipitation method, and the experimental results demonstrate that tetravalent technetium and pertechnetate concentrations are well agreement with the LaCl 3 precipitation method. These two experimental results demonstrated that Tc (Ⅶ) is very stable in the Tc (Ⅶ)-humic acid system during a 350 days experimental period, and the Tc (Ⅳ) concentrations are very lower, that is indicate that there didn't oxidizing reactions between the Fluka humic acid and Tc (Ⅶ) in aqueous solutions under anaerobic conditions. That is means the presence of humic acids even in anaerobic groundwater is disadvantage for the retardance of radionuclides. (authors)

Strong correlations and the search for high-Tc superconductivity in chromium pnictides and chalcogenides

Science.gov (United States)

Pizarro, J. M.; Calderón, M. J.; Liu, J.; Muñoz, M. C.; Bascones, E.

2017-02-01

Undoped iron superconductors accommodate n =6 electrons in five d orbitals. Experimental and theoretical evidence shows that the strength of correlations increases with hole doping, as the electronic filling approaches half filling with n =5 electrons. This evidence delineates a scenario in which the parent compound of iron superconductors is the half-filled system, in analogy to cuprate superconductors. In cuprates the superconductivity can be induced upon electron or hole doping. In this work we propose to search for high-Tc superconductivity and strong correlations in chromium pnictides and chalcogenides with n slave-spin and multiorbital random-phase-approximation calculations we analyze the strength of the correlations and the superconducting and magnetic instabilities in these systems with the main focus on LaCrAsO. We find that electron-doped LaCrAsO is a strongly correlated system with competing magnetic interactions, with (π ,π ) antiferromagnetism and nodal d -wave pairing being the most plausible magnetic and superconducting instabilities, respectively.

Sonolytic Oxidation of Tc(IVO2nH2O Nanoparticles to Tc(VIIO4 in Aqueous Solution

Directory of Open Access Journals (Sweden)

M. Zakir

2010-04-01

Full Text Available Sonolysis of a hydrosol of TcO2nH2O was investigated in the Ar- or He- atmosphere. Colloidal TcO2nH2O nanoparticles were irradiated with a 200 kHz and 1.25 W/cm2 ultrasound. It was found that the TcO2nH2O colloids dispersed in an aqueous solution (under Ar or He atmosphere was completely dissolved by ultrasonic irradiation (200 kHz, 200 W. The original brownish black color of the suspension slowly disappeared leaving behind a colorless solution. This change suggests that oxidation of Tc(IV to Tc(VII takes place. The oxidation was almost complete during 30 minutes sonication time under argon atmosphere for initial concentration of 6.0E-5 M. Addition of t-butyl alcohol, an effective radical scavenger which readily reacts with OH radicals, supressed the dissolution of TcO2nH2O colloids. This reaction indicates that TcO2nH2O molecules are oxidized by OH radicals produced in cavitation bubbles.

High-Tc superconducting electric motors

International Nuclear Information System (INIS)

Schiferl, R.; Stein, J.

1992-01-01

In this paper, the advantages and limitations of using superconductors in motors are discussed. A synchronous motor with a high temperature superconducting field winding for pump and fan drive applications is described and some of its unique design features are identified. A 10,000 horsepower superconducting motor design is presented. The critical field and current density requirements for high temperature superconducting wire in motors is discussed. Finally, recent progress in superconducting wire performance is presented

Superconductivity: Is there a problem in transuranics?

International Nuclear Information System (INIS)

Colineau, Eric; Griveau, Jean-Christophe; Eloirdi, Rachel; Hen, Amir; Caciuffo, Roberto

2014-01-01

Superconductivity was first reported in 1942 for uranium metal (¡-U) and in 1958 for U compounds: UCo, U6Mn, U6Fe, and U6Co, with critical temperatures Tc, of 1.7, 2.3, 3.9, and 2.3K, respectively. A new class of U superconductors emerged in the early 1980’s with the discovery of U heavy fermion superconductors : UBe13 (Tc = 0.85K), UPt3 (Tc = 0.53K), URu2Si2 (Tc = 1.5K) , UPd2Al3 (Tc = 1.9K) … Furthermore, in most of these systems, the superconducting phases coexist with antiferromagnetic (AF) correlations which have characteristic temperatures, usually the Néel temperature TN, that are typically one order of magnitude greater than the corresponding superconducting critical temperatures Tc. Superconductivity was even shown to co-exist with ferromagnetism in e.g. UGe2 (Tc ï» 0.8K, TC ï» 30K at p ï» 1.2GPa) and URhGe (Tc = 0.25K, TC = 9.5K). Heavy fermion superconductors still remain a major challenge for condensed matter physics. The existence of heavy fermion superconductivity and its coexistence or proximity with magnetic order suggests that the conventional mechanism of phonon-mediated superconductivity is inappropriate and that alternative mechanisms, like spin fluctuations, should be considered for Cooper pairing

Superconducting properties of the hexagonal-close-packed alloy system TcZr

International Nuclear Information System (INIS)

Chatterjee, P.

1984-01-01

The theoretical formula of McMillan, modified via the multiple-scattering theory of Gomersall and Gyorffy, is very successful in computing the electron-phonon coupling constant (lambda) and the superconducting transition temperature (T/sub c/) of elements and compounds from quantities readily obtainable from band structure work or approaches based on the scattering theory. However, for disordered solids this theory fails because of the breakdown of the translational symmetry used in the multiple scattering theory. In the particular case of substitutional alloys, the problem can still be solved however if, at each lattice point, the t-matrix of an individual scatterer is replaced by a configurational average of the t-matrices of the alloying materials (average t-matrix approximation). This modified theory, which has already been successfully applied to some cubic substitutional alloys, is herein used to predict lambda and T/sub c/ for the h.c.p. TcZr alloy system. The results indicate that this system has good superconducting properties. (author)

99Tc and Re incorporated into metal oxide polyoxometalates: oxidation state stability elucidated by electrochemistry and theory.

Science.gov (United States)

McGregor, Donna; Burton-Pye, Benjamin P; Mbomekalle, Israel M; Aparicio, Pablo A; Romo, Susanna; López, Xavier; Poblet, Josep M; Francesconi, Lynn C

2012-08-20

The radioactive element technetium-99 ((99)Tc, half-life = 2.1 × 10(5) years, β(-) of 253 keV), is a major byproduct of (235)U fission in the nuclear fuel cycle. (99)Tc is also found in radioactive waste tanks and in the environment at National Lab sites and fuel reprocessing centers. Separation and storage of the long-lived (99)Tc in an appropriate and stable waste-form is an important issue that needs to be addressed. Considering metal oxide solid-state materials as potential storage matrixes for Tc, we are examining the redox speciation of Tc on the molecular level using polyoxometalates (POMs) as models. In this study we investigate the electrochemistry of Tc complexes of the monovacant Wells-Dawson isomers, α(1)-P(2)W(17)O(61)(10-) (α1) and α(2)-P(2)W(17)O(61)(10-) (α2) to identify features of metal oxide materials that can stabilize the immobile Tc(IV) oxidation state accessed from the synthesized Tc(V)O species and to interrogate other possible oxidation states available to Tc within these materials. The experimental results are consistent with density functional theory (DFT) calculations. Electrochemistry of K(7-n)H(n)[Tc(V)O(α(1)-P(2)W(17)O(61))] (Tc(V)O-α1), K(7-n)H(n)[Tc(V)O(α(2)-P(2)W(17)O(61))] (Tc(V)O-α2) and their rhenium analogues as a function of pH show that the Tc-containing derivatives are always more readily reduced than their Re analogues. Both Tc and Re are reduced more readily in the lacunary α1 site as compared to the α2 site. The DFT calculations elucidate that the highest oxidation state attainable for Re is VII while, under the same electrochemistry conditions, the highest oxidation state for Tc is VI. The M(V)→ M(IV) reduction processes for Tc(V)O-α1 are not pH dependent or only slightly pH dependent suggesting that protonation does not accompany reduction of this species unlike the M(V)O-α2 (M = (99)Tc, Re) and Re(V)O-α1 where M(V/IV) reduction process must occur hand in hand with protonation of the terminal M═O to

Flux Flow, Pinning, and Resistive Behavior in Superconducting Networks

International Nuclear Information System (INIS)

Stephen Teitel

2005-01-01

Numerical simulators are used to study the behavior of interacting quantized vortices and vortex lines in superconducting networks, films, and three dimensional bulk samples. An emphasis is on the explanation of the phenomenological behavior of the ''high-Tc'' copper-oxide superconductors and related model systems

Degradation of superconducting Nb/NbN films by atmospheric oxidation

Energy Technology Data Exchange (ETDEWEB)

Henry, Michael David; Wolfley, Steven L.; Young, Travis Ryan; Monson, Todd; Pearce, Charles Joseph; Lewis, Rupert M.; Clark, Blythe; Brunke, Lyle Brent; Missert, Nancy A.

2017-03-01

Niobium and niobium nitride thin films are transitioning from fundamental research toward wafer scale manufacturing with technology drivers that include superconducting circuits and electronics, optical single photon detectors, logic, and memory. Successful microfabrication requires precise control over the properties of sputtered superconducting films, including oxidation. Previous work has demonstrated the mechanism in oxidation of Nb and how film structure could have deleterious effects upon the superconducting properties. This study provides an examination of atmospheric oxidation of NbN films. By examination of the room temperature sheet resistance of NbN bulk oxidation was identified and confirmed by secondary ion mass spectrometry. As a result, Meissner magnetic measurements confirmed the bulk oxidation not observed with simple cryogenic resistivity measurements.

Oxide superconducting ribbon and its fabrication process

International Nuclear Information System (INIS)

Belouet, C.

1990-01-01

A film without cavities, of perovskite type superconducting oxide is deposited by melting on a metal or composite flexible substrate with a rectangular cross section. The film thickness is comprised between 1 and 100 micrometers and orientation of C axis of superconducting crystals is perpendicular to the subtrate [fr

Prediction of high-Tc conventional superconductivity in the ternary lithium borohydride system

Science.gov (United States)

Kokail, Christian; von der Linden, Wolfgang; Boeri, Lilia

2017-12-01

We investigate the superconducting ternary lithium borohydride phase diagram at pressures of 0 and 200 GPa using methods for evolutionary crystal structure prediction and linear-response calculations for the electron-phonon coupling. Our calculations show that the ground state phase at ambient pressure, LiBH4, stays in the P n m a space group and remains a wide band-gap insulator at all pressures investigated. Other phases along the 1 :1 :x Li:B:H line are also insulating. However, a full search of the ternary phase diagram at 200 GPa revealed a metallic Li2BH6 phase, which is thermodynamically stable down to 100 GPa. This superhydride phase, crystallizing in a F m 3 ¯m space group, is characterized by sixfold hydrogen-coordinated boron atoms occupying the fcc sites of the unit cell. Due to strong hydrogen-boron bonding this phase displays a critical temperature of ˜100 K between 100 and 200 GPa. Our investigations confirm that ternary compounds used in hydrogen-storage applications should exhibit high-Tc conventional superconductivity in diamond anvil cell experiments, and suggest a viable route to optimize the superconducting behavior of high-pressure hydrides, exploiting metallic covalent bonds.

Internal resonance of an elastic body levitated above high-Tc superconducting bulks

International Nuclear Information System (INIS)

Kokuzawa, T; Toshihiko, S; Yoshizawa, M

2010-01-01

In high-Tc superconducting magnetic levitation systems, levitated bodies can keep stable levitation with no contact and no control and thus their damping is very small. Thanks to these features, their applications to various apparatus are expected. However, on account of their small damping, the nonlinearity of electromagnetic levitation force can give notable effects upon motion of the levitated bodies. Therefore this nonlinearity must be taken into account to accurately analyze the dynamical behavior of the levitated bodies. Structures of such a levitated body can show elastic deformation if the large electromagnetic force acts on it. Therefore, we need to deal with the model as an elastic body. As mentioned above, nonlinear characteristics easily appear in this elastic vibration on account of the small damping. Especially when the ratio of the natural frequencies of the eigenmodes is integer, internal resonance can occur. This nonlinear resonance is derived from nonlinear interactions among the eigenmodes of the elastic levitated body. This kind of internal resonance of an elastic body appearing in high-Tc superconducting levitation systems has not been studied so far. This research especially deals with internal resonance of a beam supported at both its ends by electromagnetic forces acting on permanent magnets. The governing equation with the nonlinear boundary conditions for the dynamics of a levitated beam has been derived. Numerical results show internal resonance of the 1st mode and the 3rd mode. Experimental results are qualitatively in good agreement with numerical ones.

Electrical Insulation of 500-m High-Tc Superconducting Power Cable

International Nuclear Information System (INIS)

Takahashi, T; Ichikawa, M; Suzuki, H; Okamoto, T; Akita, S; Mukoyama, S; Yagi, M; Maruyama, S; Kimura, A

2006-01-01

Electrical insulation is one of the essential technologies for the electric power apparatus. Determination of testing voltages and design method of the electrical insulation layer are inextricably linked each other, and are critical to developing and realizing a cold dielectric (CD) type high-Tc superconducting (HTS) power cable. The authors had proposed the electrical insulation design method with concepts of partial discharge-free designs for ac voltage condition. This paper discusses the testing voltages for a 77 kV 1000 A HTS power cable with a length of 500 m, and describes results of various voltage withstand test. As a result, it is concluded that the proposed electrical insulation design method is appropriate for the HTS power cable

Design and Characteristics Analysis of a Rod Type High-Tc Superconducting Fault Current Limiter through Electromagnetic Analysis

Energy Technology Data Exchange (ETDEWEB)

Hyun, O.B. [Korea Electric Power Research Institute, Taejeon (Korea); Lee, C.J.; Lee, S.J.; Ko, T.K. [Yonsei University, Seoul (Korea)

2001-07-01

The existence of a large air gaps between a High-Tc Superconducting (HTS) tube and an iron core, or between a primary winding and a HTS tube possibly causes magnetic flux leaks, resulting in undesirable voltage drops under normal operation. For this reason optimization of air gaps is essential in designing a high-Tc superconducting fault current limiter (SFCL). In this paper we performed the electromagnetic analysis for the optimization. The inductance L decreases by 20% as the hight of the winding increases from 50 to 200 mm. But, L increases from 5.6 mH to 10.5 mH as the hight of the rod changes from 150 to 400 mm. L is found to be almost constant for the air gap between 5 to 10 mm, but L decreases by 20% as the gap increases from 10 to 20 mm. The computational and experimental results will bo compared. (author). 7 refs., 8 figs., 1 tab.

Oxidative dissolution potential of biogenic and abiogenic TcO2 in subsurface sediments

International Nuclear Information System (INIS)

Fredrickson, J.K.; Zachara, J.M.; Plymale, A.E.; Heald, S.M.; McKinley, J.P.; Kennedy, D.W.; Liu, C.; Nachimuthu, P.

2009-01-01

Technetium-99 (Tc) is an important fission product contaminant associated with sites of nuclear fuels reprocessing and geologic nuclear waste disposal. Tc is highly mobile in its most oxidized state (Tc(VII)O 4 - ) and less mobile in the reduced form (Tc(IV)O 2 · nH 2 O). Here we investigate the potential for oxidation of Tc(IV) that was heterogeneously reduced by reaction with biogenic Fe(II) in two sediments differing in mineralogy and aggregation state; unconsolidated Pliocene-age fluvial sediment from the upper Ringold (RG) Formation at the Hanford Site and a clay-rich saprolite from the Field Research Center (FRC) background site on the Oak Ridge Site. Both sediments contained Fe(III) and Mn(III/IV) as redox active phases, but FRC also contained mass-dominant Fe-phyllosilicates of different types. Shewanella putrefaciens CN32 reduced Mn(III/IV) oxides and generated Fe(II) that was reactive with Tc(VII) in heat-killed, bioreduced sediment. After bioreduction and heat-killing, biogenic Fe(II) in the FRC exceeded that in RG by a factor of two. More rapid reduction rates were observed in the RG that had lower biogenic Fe(II), and less particle aggregation. EXAFS measurements indicated that the primary reduction product was a TcO 2 -like phase in both sediments. The biogenic redox product Tc(IV) oxidized rapidly and completely in RG when contacted with air. Oxidation, in contrast, was slow and incomplete in the FRC, in spite of similar molecular scale speciation of Tc compared to RG. X-ray microprobe, electron microprobe, X-ray absorption spectroscopy, and micro X-ray diffraction were applied to the whole sediment and isolated Tc-containing particles. These analyses revealed that non-oxidizable Tc(IV) in the FRC existed as complexes with octahedral Fe(III) within intra-grain domains of 50-100 (micro)m-sized, Fe-containing micas presumptively identified as celadonite. The markedly slower oxidation rates in FRC as compared to RG were attributed to mass

Oxidative dissolution potential of biogenic and abiogenic TcO 2 in subsurface sediments

Science.gov (United States)

Fredrickson, James K.; Zachara, John M.; Plymale, Andrew E.; Heald, Steve M.; McKinley, James P.; Kennedy, David W.; Liu, Chongxuan; Nachimuthu, Ponnusamy

2009-04-01

Technetium-99 (Tc) is an important fission product contaminant associated with sites of nuclear fuels reprocessing and geologic nuclear waste disposal. Tc is highly mobile in its most oxidized state [Tc(VII)O4-] and less mobile in the reduced form [Tc(IV)O 2· nH 2O]. Here we investigate the potential for oxidation of Tc(IV) that was heterogeneously reduced by reaction with biogenic Fe(II) in two sediments differing in mineralogy and aggregation state; unconsolidated Pliocene-age fluvial sediment from the upper Ringold (RG) Formation at the Hanford Site and a clay-rich saprolite from the Field Research Center (FRC) background site on the Oak Ridge Site. Both sediments contained Fe(III) and Mn(III/IV) as redox active phases, but FRC also contained mass-dominant Fe-phyllosilicates of different types. Shewanella putrefaciens CN32 reduced Mn(III/IV) oxides and generated Fe(II) that was reactive with Tc(VII) in heat-killed, bioreduced sediment. After bioreduction and heat-killing, biogenic Fe(II) in the FRC exceeded that in RG by a factor of two. More rapid reduction rates were observed in the RG that had lower biogenic Fe(II), and less particle aggregation. EXAFS measurements indicated that the primary reduction product was a TcO 2-like phase in both sediments. The biogenic redox product Tc(IV) oxidized rapidly and completely in RG when contacted with air. Oxidation, in contrast, was slow and incomplete in the FRC, in spite of similar molecular scale speciation of Tc compared to RG. X-ray microprobe, electron microprobe, X-ray absorption spectroscopy, and micro X-ray diffraction were applied to the whole sediment and isolated Tc-containing particles. These analyses revealed that non-oxidizable Tc(IV) in the FRC existed as complexes with octahedral Fe(III) within intra-grain domains of 50-100 μm-sized, Fe-containing micas presumptively identified as celadonite. The markedly slower oxidation rates in FRC as compared to RG were attributed to mass

Quantum and superconducting fluctuations effects in disordered Nb 1- xTa x thin films above Tc

Science.gov (United States)

Giannouri, M.; Papastaikoudis, C.

1999-05-01

Disordered Nb 1- xTa x thin films are prepared with e-gun coevaporation. The influence of the β-phase of tantalum in the critical temperature Tc is observed as a function of the substrate temperature. The measurements of transverse magnetoresistance at various isothermals are interpreted in terms of weak-localization and superconducting fluctuations. From the fitting procedure, the phase breaking rate τφ-1 and the Larkin parameter βL are estimated as a function of temperature. Conclusions about the dominant inelastic scattering mechanisms at various temperature regions as well as for the dominant mechanism of superconducting fluctuations near the transition temperature are extracted.

High-Tc superconductivity near the anion height instability in Fe-based superconductors: analysis of LaFeAsO(1-x)H(x).

Science.gov (United States)

Onari, Seiichiro; Yamakawa, Youichi; Kontani, Hiroshi

2014-05-09

The isostructural transition in the tetragonal phase with a sizable change in the anion height, is realized in heavily H-doped LaFeAsO and (La,P) codoped CaFe2As2. In these compounds, the superconductivity with higher Tc (40-50 K) is realized near the isostructural transition. To find the origin of the anion-height instability and the role in realizing the higher-Tc state, we develop the orbital-spin fluctuation theory by including the vertex correction. We analyze LaFeAsO(1-x)H(x) and find that the non-nematic orbital fluctuations, which induce the anion-height instability, are automatically obtained at x∼0.5, in addition to the conventional nematic orbital fluctuations at x∼0. The non-nematic orbital order triggers the isostructural transition, and its fluctuation would be a key ingredient to realize higher-Tc superconductivity of order 50 K.

High Tc superconducting magnetic multivibrators for fluxgate magnetic-field sensors

International Nuclear Information System (INIS)

Mohri, K.; Uchiyama, T.; Ozeki, A.

1989-01-01

Sensitive and quick-response nonlinear inductance characteristics are found for high Tc superconducting (YBa 2 Cu 3 O 7-chi ) disk cores at 77K in which soft magnetic BH hysteresis loops are observed. Various quick response magnetic devices such as modulators, amplifiers and sensors are built using these cores. The magnetizing frequency can be set to more than 20 MHz, which is difficult for conventional ferromagnetic bulk materials such as Permalloy amorphous alloys and ferrite. New quick-response fluxgate type magnetic-field sensors are made using ac and dc voltage sources. The former is used for second-harmonic type sensors, while the latter is for voltage-output multivibrator type sensors. Stable and quick-response sensor characteristics were obtained for two-core type multivibrators

Gauge Model of High-Tc Superconductivity

International Nuclear Information System (INIS)

Ng, Sze Kui

2012-01-01

A simple gauge model of superconductivity is presented. The seagull vertex term of this gauge model gives an attractive potential between electrons for the forming of Cooper pairs of superconductivity. This gauge model gives a unified description of superconductivity and magnetism including antiferromagnetism, pseudogap phenomenon, stripes phenomenon, paramagnetic Meissner effect, Type I and Type II supeconductivity and high-T c superconductivity. The doping mechanism of superconductivity is found. It is shown that the critical temperature T c is related to the ionization energies of elements and can be computed by a formula of T c . For the high-T c superconductors such as La 2-x Sr x CuO 4 , Y Ba 2 Cu 3 O 7 , and MgB 2 , the computational results of T c agree with the experimental results.

Systematics in positron annihilation lifetime analysis of high Tc superconducting transitions

International Nuclear Information System (INIS)

Howell, R.H.; Radousky, H.B.; Wachs, A.L.; Fluss, M.J.; Turchi, P.E.A.; Jean, Y.C.; Sunder, C.S.; Chu, C.W.; Peng, J.L.; Folkerts, T.J.; Shelton, R.N.; Hinks, D.G.

1989-01-01

Values of the positron lifetime have previously been observed to change with temperature below T c in high T c superconducting oxides. The authors report new measurements on Ba .6 K .4 Bio 3 and Nd 1.85 Ce .15 CuO 4

Superconductivity: materials and applications

International Nuclear Information System (INIS)

Duchateau, J.L.; Kircher, F.; Leveque, J.; Tixador, P.

2008-01-01

This digest paper presents the different types of superconducting materials: 1 - the low-TC superconductors: the multi-filament composite as elementary constituent, the world production of NbTi, the superconducting cables of the LHC collider and of the ITER tokamak; 2 - the high-TC superconductors: BiSrCaCuO (PIT 1G) ribbons and wires, deposited coatings; 3 - application to particle physics: the the LHC collider of the CERN, the LHC detectors; 4 - applications to thermonuclear fusion: Tore Supra and ITER tokamaks; 5 - NMR imaging: properties of superconducting magnets; 6 - applications in electrotechnics: cables, motors and alternators, current limiters, transformers, superconducting energy storage systems (SMES). (J.S.)

Determination of copper oxidizing power in superconducting yttrium ceramics

International Nuclear Information System (INIS)

Pontaler, R.P.; Lebed', N.B.

1989-01-01

A new photometric method for determining the formal copper degree of oxidation and oxygen deficiency in superconducting high-temperature oxides containing yttrium, barium and copper is developed. The method is based on oxidation of Co(2) complex with EDTA by Cu(3) ions in acetrate buffer solution with pH 4.2-4.7 and allows one to determine 1-10% of Cu(3). Relative standard deviation when determining Cu(3) makes up 0.03-0.05. Using a qualitative reaction with the application of sodium vanadate hydrochloride solution the absence of peroxide compound in superconducting yttrium ceramics is ascertained

An effective 2-band eg model of sulfur hydride H3S for high-Tc superconductivity

Science.gov (United States)

Nishiguchi, Kazutaka; Teranishi, Shingo; Miyao, Satoaki; Matsushita, Goh; Kusakabe, Koichi

To understand high transition temperature (Tc) superconductivity in sulfur hydride H3S, we propose an effective 2-band model having the eg symmetry as the minimal model for H3S. Two eg orbitals centered on a sulfur S atom are chosen for the smallest representation of relevant bands with the van-Hove singularity around the Fermi levels except for the Γ-centered small hole pockets by the sulfur 3 p orbitals. By using the maximally localized Wannier functions, we derive the minimal effective model preserving the body-centered cubic (bcc) crystal symmetry of the H3S phase having the highest Tc ( 203 K under pressures) among the other polymorphs of H3S.

Superconducting oxide thin films by ion beam sputtering

International Nuclear Information System (INIS)

Kobrin, P.H.; DeNatale, J.F.; Housley, R.M.; Flintoff, J.F.; Harker, A.B.

1987-01-01

Superconducting thin films of ternary copper oxides from the Y-Ba-Cu-O and La-Sr-Cu-O systems have been deposited by ion beam sputtering of ceramic targets. Crystallographic orientation of the polycrystalline films has been shown to vary with substrate identity, deposition temperature and annealing temperature. The onset of the superconductive transition occurs near 90K in the Y-Ba-Cu-O system. Fe impurities of < 0.2% have been found to inhibit the superconducting transition, probably by migrating to the grain boundaries

A phenomenological approach to high Tc oxide superconductors

International Nuclear Information System (INIS)

Chela-Flores, J.; Das, M.P.; Saif, A.G.

1987-06-01

Oxide superconductors are described in terms of macroscopic wave functions Ψ and Φ corresponding, respectively, to electron pairs of the superconducting and insulating states. In terms of the total free energy of the system, including the effect of interaction, we discuss the electrodynamic responses of the oxide superconductors in relation with the experiments to data. (author). 10 refs

Magnetic order close to superconductivity in the iron-based layered LaO1-xFxFeAs systems

Science.gov (United States)

de La Cruz, Clarina; Huang, Q.; Lynn, J. W.; Li, Jiying; , W. Ratcliff, II; Zarestky, J. L.; Mook, H. A.; Chen, G. F.; Luo, J. L.; Wang, N. L.; Dai, Pengcheng

2008-06-01

Following the discovery of long-range antiferromagnetic order in the parent compounds of high-transition-temperature (high-Tc) copper oxides, there have been efforts to understand the role of magnetism in the superconductivity that occurs when mobile `electrons' or `holes' are doped into the antiferromagnetic parent compounds. Superconductivity in the newly discovered rare-earth iron-based oxide systems ROFeAs (R, rare-earth metal) also arises from either electron or hole doping of their non-superconducting parent compounds. The parent material LaOFeAs is metallic but shows anomalies near 150K in both resistivity and d.c. magnetic susceptibility. Although optical conductivity and theoretical calculations suggest that LaOFeAs exhibits a spin-density-wave (SDW) instability that is suppressed by doping with electrons to induce superconductivity, there has been no direct evidence of SDW order. Here we report neutron-scattering experiments that demonstrate that LaOFeAs undergoes an abrupt structural distortion below 155K, changing the symmetry from tetragonal (space group P4/nmm) to monoclinic (space group P112/n) at low temperatures, and then, at ~137K, develops long-range SDW-type antiferromagnetic order with a small moment but simple magnetic structure. Doping the system with fluorine suppresses both the magnetic order and the structural distortion in favour of superconductivity. Therefore, like high-Tc copper oxides, the superconducting regime in these iron-based materials occurs in close proximity to a long-range-ordered antiferromagnetic ground state.

Quasiparticle self-consistent GW study of cuprates: electronic structure, model parameters, and the two-band theory for Tc.

Science.gov (United States)

Jang, Seung Woo; Kotani, Takao; Kino, Hiori; Kuroki, Kazuhiko; Han, Myung Joon

2015-07-24

Despite decades of progress, an understanding of unconventional superconductivity still remains elusive. An important open question is about the material dependence of the superconducting properties. Using the quasiparticle self-consistent GW method, we re-examine the electronic structure of copper oxide high-Tc materials. We show that QSGW captures several important features, distinctive from the conventional LDA results. The energy level splitting between d(x(2)-y(2)) and d(3z(2)-r(2)) is significantly enlarged and the van Hove singularity point is lowered. The calculated results compare better than LDA with recent experimental results from resonant inelastic xray scattering and angle resolved photoemission experiments. This agreement with the experiments supports the previously suggested two-band theory for the material dependence of the superconducting transition temperature, Tc.

High temperature superconductivity the road to higher critical temperature

CERN Document Server

Uchida, Shin-ichi

2015-01-01

This book presents an overview of material-specific factors that influence Tc and give rise to diverse Tc values for copper oxides and iron-based high- Tc superconductors on the basis of more than 25 years of experimental data, to most of which the author has made important contributions. The book then explains why both compounds are distinct from others with similar crystal structure and whether or not one can enhance Tc, which in turn gives a hint on the unresolved pairing mechanism. This is an unprecedented new approach to the problem of high-temperature superconductivity and thus will be inspiring to both specialists and non-specialists interested in this field.   Readers will receive in-depth information on the past, present, and future of high-temperature superconductors, along with special, updated information on what the real highest Tc values are and particularly on the possibility of enhancing Tc for each member material, which is important for application. At this time, the highest Tc has not been...

Conductive polymer/high-TC superconductor sandwich structures: An example of a molecular switch for controlling superconductivity

International Nuclear Information System (INIS)

McDevitt, J.T.; Haupt, S.G.; Lo, R.K.

1994-01-01

The preparation of a hybrid conducting polymer/high-temperature superconductor device consisting of a polypyrrole coated YBa 2 Cu 3 O 7-x microbridge is reported. Electrochemical techniques are exploited to alter the oxidation state of the polymer and, in doing so, it is found for the first time that superconductivity can be modulated in a controllable and reproducible fashion by a polymer layer. Whereas the neutral (insulating) polypyrrole only slightly influences the electrical properties of the underlying YBa 2 Cu 3 O 7- film, the oxidized (conductive) polymer depresses T c by up to 50K. In a similar fashion, the oxidation state of the polymer is found to modulate reversibly the magnitude of J c , the superconducting critical current. Thus, a new type of molecular switch for controlling superconductivity is demonstrated. Electrochemical, resistance vs. temperature, atomic force microscopy and scanning electron microscopy measurements are utilized to explore the polymer/superconductor interactions

A manufacturing process for a mixed-oxide type superconducting material

International Nuclear Information System (INIS)

Gendre, P.; Regnier, P.; Schmirgeld-Mignot, L.; Marquet, A.

1995-01-01

In order to produce high temperature superconducting materials such as YBaCuO and Bi 2 Sr 2 Ca Cu 2 O 8 , a process is presented which consists in an electrodeposition on a conductive substrate of successive layers made of the metallic elements composing the superconductor, with only one element in each layer; between each layer deposition, an intermediary oxide-reaction thermal treatment is carried out; a global oxidation thermal treatment is then finally conducted to produce the mixed oxide material. Narrow superconducting transitions and high critical current densities are possible. 3 refs., 4 figs

Analysis of High Tc Superconducting Rectangular Microstrip Patches over Ground Planes with Rectangular Apertures in Substrates Containing Anisotropic Materials

Directory of Open Access Journals (Sweden)

Abderraouf Messai

2013-01-01

Full Text Available A rigorous full-wave analysis of high Tc superconducting rectangular microstrip patch over ground plane with rectangular aperture in the case where the patch is printed on a uniaxially anisotropic substrate material is presented. The dyadic Green’s functions of the considered structure are efficiently determined in the vector Fourier transform domain. The effect of the superconductivity of the patch is taken into account using the concept of the complex resistive boundary condition. The accuracy of the analysis is tested by comparing the computed results with measurements and previously published data for several anisotropic substrate materials. Numerical results showing variation of the resonant frequency and the quality factor of the superconducting antenna with regard to operating temperature are given. Finally, the effects of uniaxial anisotropy in the substrate on the resonant frequencies of different TM modes of the superconducting microstrip antenna with rectangular aperture in the ground plane are presented.

Growth and characterization of high-Tc Y1Ba2Cu3O7-x superconducting thin films by chemical vapor deposition

International Nuclear Information System (INIS)

Feng, A.

1992-01-01

In chapter I, the current status of high-Tc superconductors (especially Y 1 Ba 2 Cu 3 O 7-x ), their microstructures and their unique physical properties are reviewed. An introduction to the potential and importance of those high-Tc superconductors in practical applications, especially for the application of YBCO thin films in microelectronics, is given. A general description of the common YBCO thin film fabrication and characterization techniques is also presented in this first chapter. Chapter II describes a new CVD process, temperature-controlled chemical vapor deposition (TC-CVD) for the growth of YBCO superconducting thin films on substrates of practical importance, such as sapphire (Al 2 O 3 ) and on substrates of lattice matched perovskite-type single crystals, such as LaAlO 3 . In order to verify the viability of this new CVD process the qualities of YBCO superconducting thin films were examined by various characterization methods, such as resistivity vs. temperature (R vs. T), scanning electron microscopy (SEM), X-ray diffraction (XRD), and magnetic susceptibility (x) measurements. Chapter III deals with the effect of substrate temperature on the properties of YBCO thin films made by TC-CVD. The principle objective of this study is to raise the transition temperature and critical current densities of CVD YBCO superconducting thin films. Understanding the relations between YBCO film growth process and varying substrate temperatures proved to be crucial in reaching this goal. The authors present the characterization results of YBCO thin films produced by different temperature schemes, to illustrate the importance of varying substrate temperature during the film growth. In chapter IV, the Rutherford backscattering (RBS) channeling technique is described. They have used RBS channeling to characterize the epitaxial YBCO thin film's crystallinity and lattice alignment. Transmission electron microscopy studies are also included

Biogeochemistry of Fe and Tc Reduction and Oxidation in FRC Sediment

International Nuclear Information System (INIS)

John M, Zachara; James K, Fredrickson; Ravi K, Kukkadapu; Steven C, Smith; David W, Kennedy

2004-01-01

The objectives are: (1) To rigorously characterize the distribution of Fe(II) and Fe(III) in FRC sediment. (2) To identify changes to Fe(II)/Fe(III) distribution and concentration resulting from DIRB activity. (3) To determine the dependence of Tc(VII) reduction rate on biogenic Fe(II) and it's forms. (4) To establish tendency of Tc(IV) and biogenic Fe(II) to oxidize and their effects on Tc immobilization. The mineralogic and chemical properties of the pristine, bioreduced, and chemically extracted FRC sediments were characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), X-ray microscopy (XRM, at the PNC-CAT beamline at APS), Moessbauer spectroscopy, and scanning and transmission electron microscopy with lattice fringe imaging. Chemical extraction included dithionite-citrate-bicarbonate (DCB), acid ammonium oxalate (AAO), and hydroxylamine hydrochloride (HAH). The FRC sediment was incubated under anoxic conditions with the facultative dissimilatory metal-reducing bacterium Shewanella putrefaciens, strain CN32 in defined aqueous solutions/media with bicarbonate and PIPES buffers for time periods exceeding 75 d. Lactate was used as the electron donor. Aqueous and sorbed Fe(II) (ferrozine assay and 0.5 N HCl extraction) and Mn(II) (ICP-MS and 10 mM CuSO 4 extraction), and pH were monitored to define the reduction progress and extent. The bioreduced materials were characterized using the abovementioned techniques. Bioreduced (pasteurized) sediment or chemically extracted/reduced sediment spiked with Fe(II) was washed with a PIPES buffer/electrolyte solution, and spiked with NaTc(VII)O 4 to yield a concentration of 20 (micro)M. The Tc(VII)-spiked samples were agitated and equilibrated at 25 C and sampled over time to assess the Tc(VII) reduction rate. Selected sediment samples containing 20 (micro)M of reduced Tc [Tc(IV)] were subjected to oxidation by: (1) successive headspace replacements of air, and (2) open system equilibration with air. Removed aqueous

Finding new superconductors: the spin-fluctuation gateway to high Tc and possible room temperature superconductivity.

Science.gov (United States)

Pines, David

2013-10-24

We propose an experiment-based strategy for finding new high transition temperature superconductors that is based on the well-established spin fluctuation magnetic gateway to superconductivity in which the attractive quasiparticle interaction needed for superconductivity comes from their coupling to dynamical spin fluctuations originating in the proximity of the material to an antiferromagnetic state. We show how lessons learned by combining the results of almost three decades of intensive experimental and theoretical study of the cuprates with those found in the decade-long study of a strikingly similar family of unconventional heavy electron superconductors, the 115 materials, can prove helpful in carrying out that search. We conclude that, since Tc in these materials scales approximately with the strength of the interaction, J, between the nearest neighbor local moments in their parent antiferromagnetic state, there may not be a magnetic ceiling that would prevent one from discovering a room temperature superconductor.

Oxidative Stability of Tc(I) Tricarbonyl Species Relevant to the Hanford Tank Waste

Energy Technology Data Exchange (ETDEWEB)

Chatterjee, Sayandev [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hall, Gabriel B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Levitskaia, Tatiana G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Walter, Eric D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washton, Nancy M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-12-17

Technetium (Tc), which exists predominately in the liquid supernatant and salt cake fractions of the nuclear tank waste stored at the U.S. DOE Hanford Site, is one of the most difficult contaminants to dispose of and/or remediate. In the strongly alkaline environments prevalent in the tank waste, its dominant chemical form is pertechnetate (TcO₄^-, oxidation state +7). However, based on experimentation to-date, a significant fraction of the soluble Tc cannot be effectively separated from the wastes and may be present as a non-pertechnetate species. The presence of a non pertechnetate species significantly complicates disposition of low-activity waste (LAW), and the development of methods to either convert them to pertechnetate or to separate the non-pertechnetate species directly is needed. The challenge is the uncertainty regarding the nature and stability of the alkaline-soluble, low-valence, non pertechnetate species in the liquid tank waste. One objective of the Tc management project is to address this knowledge gap. This fiscal year (FY) 2015 report summarizes experimental work exploring the oxidative stability of model low-valence Tc(I) tricarbonyl species, derived from the [Tc(CO)₃]⁺ moiety. These compounds are of interest due to their implied presence in several Hanford tank waste supernatants. Work in part was initiated in FY 2014, and a series of samples containing non-pertechnetate Tc generated ex situ or in situ in pseudo-Hanford tank supernatant simulant solutions was prepared and monitored for oxidation to Tc(VII) (Levitskaia et al. 2014). This experimentation continued in FY 2015, and new series of samples containing Tc(I) as [Tc(CO)₃]⁺•Ligand was tested. The monitoring method used for these studies was a combination of ⁹⁹Tc NMR and EPR spectroscopies.

Josephson plasma resonance in superconducting multilayers

DEFF Research Database (Denmark)

Pedersen, Niels Falsig

1999-01-01

We derive an analytical solution for the josephson plasma resonance of superconducting multilayers. This analytical solution is derived mainly for low T-c systems with magnetic coupling between the superconducting layers, but many features of our results are more general, and thus an application...... to the recently derived plasma resonance phenomena for high T-c superconductors of the BSCCO type is discussed....

Electronic structure and superconductivity of FeSe-related superconductors.

Science.gov (United States)

Liu, Xu; Zhao, Lin; He, Shaolong; He, Junfeng; Liu, Defa; Mou, Daixiang; Shen, Bing; Hu, Yong; Huang, Jianwei; Zhou, X J

2015-05-13

FeSe superconductors and their related systems have attracted much attention in the study of iron-based superconductors owing to their simple crystal structure and peculiar electronic and physical properties. The bulk FeSe superconductor has a superconducting transition temperature (Tc) of ~8 K and it can be dramatically enhanced to 37 K at high pressure. On the other hand, its cousin system, FeTe, possesses a unique antiferromagnetic ground state but is non-superconducting. Substitution of Se with Te in the FeSe superconductor results in an enhancement of Tc up to 14.5 K and superconductivity can persist over a large composition range in the Fe(Se,Te) system. Intercalation of the FeSe superconductor leads to the discovery of the AxFe2-ySe2 (A = K, Cs and Tl) system that exhibits a Tc higher than 30 K and a unique electronic structure of the superconducting phase. A recent report of possible high temperature superconductivity in single-layer FeSe/SrTiO3 films with a Tc above 65 K has generated much excitement in the community. This pioneering work opens a door for interface superconductivity to explore for high Tc superconductors. The distinct electronic structure and superconducting gap, layer-dependent behavior and insulator-superconductor transition of the FeSe/SrTiO3 films provide critical information in understanding the superconductivity mechanism of iron-based superconductors. In this paper, we present a brief review of the investigation of the electronic structure and superconductivity of the FeSe superconductor and related systems, with a particular focus on the FeSe films.

On the crystal growth and chemistry of the new electron-type superconducting oxides

Energy Technology Data Exchange (ETDEWEB)

Tarascon, J.M.; Wang, E.; Greene, L.H.; Ramesh, R.; Bagley, B.G.; Hull, G.W.; Miceli, P.F. (Bellcore, Red Bank, NJ (USA)); Wang, Z.Z.; Brawner, D.; Ong, N.P. (Dept. of Physics, Princeton Univ., NJ (USA))

1989-12-01

The effect on transport and superconducting properties produced by changes in x and y in the Nd{sub 2-x}Ce{sub x}CuO{sub y} compound were studied in both polycrystalline ceramics and single crystals. Thermogravimetric analysis shows that the total oxygen content y for the as-prepared samples is always greater than 4 (i.e. presence of interstitial oxygen) whereas for the reduced sample y becomes equal to or smaller than 4 only when x is 0.15 or greater. This is the range of Ce content for which the material superconducts. For a material with Ce x=0.15 the superconducting properties can be varied reversibly by changing the oxygen content. In addition, we propose that the oxygen in these materials can be either ordered or disordered, thereby affecting the transport properties. Platelet-like crystals of Nd{sub 2-x}Ce{sub x}CuO{sub y} with x=0 to 0.18, have been grown via a flux technique. Those having a Ce content between 0.14 and 0.17 are superconducting with the sharpest transitions (Tc=21{plus minus}1K) for x=0.14. Metallic-like behavior above Tc, with a linear temperature dependence above 150K was observed on all the crystals. Below 30K, the in-plane resistivity is independent of T. The Hall coefficient is sensitive to processing conditions but is usually negative above 100K. The upper critical field with field along the c-axis is 6T at 4.2K. (orig.).

In-situ deposition of YBCO high-Tc superconducting thin films by MOCVD and PE-MOCVD

International Nuclear Information System (INIS)

Zhao, J.; Noh, D.W.; Chern, C.; Li, Y.Q.; Norris, P.E.; Kear, B.; Gallois, B.

1991-01-01

Metal-Organic Chemical Vapor Deposition (MOCVD) offers the advantages of a high degree of compositional control, adaptability for large scale production, and the potential for low temperature fabrication. The capability of operating at high oxygen partial pressure is particularly suitable for in situ formation of high temperature superconducting (HTSC) films. Yttrium barium copper oxide (YBCO) thin films having a sharp zero-resistance transition with T(sub c) greater than 90 K and J(sub c) of approximately 10(exp 4) A on YSZ have been prepared, in situ, at a substrate temperature of about 800 C. Moreover, the ability to form oxide films at low temperature is very desirable for device applications of HTSC materials. Such a process would permit the deposition of high quality HTSC films with a smooth surface on a variety of substrates. Highly c-axis oriented, dense, scratch resistant, superconducting YBCO thin films with mirror-like surfaces have been prepared, in situ, at a reduced substrate temperature as low as 570 C by a remote microwave-plasma enhanced metal-organic chemical vapor deposition (PE-MOCVD) process. Nitrous oxide was used as a reactant gas to generate active oxidizing species. This process, for the first time, allows the formation of YBCO thin films with the orthorhombic superconducting phase in the as-deposited state. The as-deposited films grown by PE-MOCVD show attainment of zero resistance at 72 K with a transition width of about 5 K. MOCVD was carried out in a commercial production scale reactor with the capability of uniform deposition over 100 sq cm per growth run. Preliminary results indicate that PE-MOCVD is a very attractive thin film deposition process for superconducting device technology

Enhanced 99 Tc retention in glass waste form using Tc(IV)-incorporated Fe minerals

Energy Technology Data Exchange (ETDEWEB)

Um, Wooyong; Luksic, Steven A.; Wang, Guohui; Saslow, Sarah; Kim, Dong-Sang; Schweiger, Michael J.; Soderquist, Chuck Z.; Bowden, Mark E.; Lukens, Wayne W.; Kruger, Albert A.

2017-11-01

Technetium (99Tc) immobilization by doping into iron oxide mineral phases may alleviate the problems with Tc volatility during vitrification of nuclear waste. Reduced Tc, Tc(IV), substitutes for Fe(III) in the crystal structure by a process of Tc reduction from Tc(VII) to Tc(IV) followed by co-precipitation of Fe oxide minerals. Two Tc-incorporated Fe minerals (Tc-goethite and Tc-magnetite/maghemite) were prepared and tested for Tc retention in glass melt samples at temperatures between 600 – 1,000 oC. After being cooled, the solid glass specimens prepared at different temperatures were analyzed for Tc oxidation state using Tc K-edge XANES. In most samples, Tc was partially oxidized from Tc(IV) to Tc(VII) as the melt temperature increased. However, Tc retention in glass melt samples prepared using Tc-incorporated Fe minerals were moderately higher than in glass prepared using KTcO4 because of limited and delayed Tc volatilization.

High-Tc cuprate superconductivity in a nutshell

International Nuclear Information System (INIS)

Won, Hyekyung; Haas, Stephan; Parker, David; Maki, Kazumi

2005-01-01

Since the discovery of high-T c cuprate superconductivity in 1986 many new experimental techniques and theoretical concepts have been developed. In particular it was shown that the BCS theory of d-wave superconductivity describes semi-quantitatively the high-T c superconductivity. Furthermore, it was demonstrated that Volovik's approach is extremely useful for finding the quasiparticle properties in the vortex state. Here we survey these developments and forecast future directions. (copyright 2005 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (orig.)

Separation of 99Tc from irradiated molybdenum oxide by extraction with trioctilamine

International Nuclear Information System (INIS)

Carvalho, O.G. de.

1979-01-01

A separation method of sup( 99 m)Tc, from irradiated molybdenum oxide, by extraction with trioctilamino in 1,2 dichloroethane, 2% v/v is studied. Two preliminary studies are done: 1) Stablishment of the shaking time necessary to reach the equilibrium between the organic and the aqueous phase; 2) Choice of the concentration of solution of TOA in 1,2 dichloroethane to obtain the best separation conditions of sup( 99 m)Tc. After stablishing these two parameters, the study of extraction in solutions of hydrochloric nitric and sulfuric acids in different concentrations is done, followed by the study of the variation of extraction percentage of sup( 99 m)Tc in relation to the molybdenum oxide mass and the back-extraction of sup( 99 m)Tc to the aqueous phase with solutions of perchloric acid 1,0 and 0,1 N and ammonium hydroxide 1,0 N. (Author) [pt

Superconductivity in bundles of double-wall carbon nanotubes.

Science.gov (United States)

Shi, Wu; Wang, Zhe; Zhang, Qiucen; Zheng, Yuan; Ieong, Chao; He, Mingquan; Lortz, Rolf; Cai, Yuan; Wang, Ning; Zhang, Ting; Zhang, Haijing; Tang, Zikang; Sheng, Ping; Muramatsu, Hiroyuki; Kim, Yoong Ahm; Endo, Morinobu; Araujo, Paulo T; Dresselhaus, Mildred S

2012-01-01

We present electrical and thermal specific heat measurements that show superconductivity in double-wall carbon nanotube (DWCNT) bundles. Clear evidence, comprising a resistance drop as a function of temperature, magnetoresistance and differential resistance signature of the supercurrent, suggest an intrinsic superconducting transition below 6.8 K for one particular sample. Additional electrical data not only confirm the existence of superconductivity, but also indicate the T(c) distribution that can arise from the diversity in the diameter and chirality of the DWCNTs. A broad superconducting anomaly is observed in the specific heat of a bulk DWCNT sample, which yields a T(c) distribution that correlates well with the range of the distribution obtained from the electrical data. As quasi one dimensionality of the DWCNTs dictates the existence of electronic density of state peaks, confirmation of superconductivity in this material system opens the exciting possibility of tuning the T(c) through the application of a gate voltage.

Advances in superconducting materials and electronics technologies

International Nuclear Information System (INIS)

Palmer, D.N.

1990-01-01

Technological barriers blocking the early implementation of ceramic oxide high critical temperature [Tc] and LHe Nb based superconductors are slowly being dismantled. Spearheading these advances are mechanical engineers with diverse specialties and creative interests. As the technology expands, most engineers have recognized the importance of inter-disciplinary cooperation. Cooperation between mechanical engineers and material and system engineers is of particular importance. Recently, several problems previously though to be insurmountable, has been successfully resolved. These accomplishment were aided by interaction with other scientists and practitioners, working in the superconductor research and industrial communities, struggling with similar systems and materials problems. Papers published here and presented at the 1990 ASME Winter Annual Meeting held in Dallas, Texas 25-30 November 1990 can be used as a bellwether to gauge the progress in the development of both ceramic oxide and low temperature Nb superconducting device and system technologies. Topics are focused into two areas: mechanical behavior of high temperature superconductors and thermal and mechanical problems in superconducting electronics

Analysis of thermodynamic properties for high-temperature superconducting oxides

International Nuclear Information System (INIS)

Kushwah, S.S.; Shanker, J.

1993-01-01

Analysis of thermodynamic properties such as specific heat, Debye temperature, Einstein temperature, thermal expansion coefficient, bulk modulus, and Grueneisen parameter is performed for rare-earth-based, Tl-based, and Bi-based superconducting copper oxides. Values of thermodynamic parameters are calculated and reported. The relationship between the Debye temperature and the superconducting transition temperature is used to estimate the values of T c using the interaction parameters from Ginzburg. (orig.)

Superconductivity applications for infrared and microwave devices; Proceedings of the Meeting, Orlando, FL, Apr. 19, 20, 1990

Science.gov (United States)

Bhasin, Kul B.; Heinen, Vernon O.

1990-10-01

Various papers on superconductivity applications for IR and microwave devices are presented. The individual topics addressed include: pulsed laser deposition of Tl-Ca-Ba-Cu-O films, patterning of high-Tc superconducting thin films on Si substrates, IR spectra and the energy gap in thin film YBa2Cu3O(7-delta), high-temperature superconducting thin film microwave circuits, novel filter implementation utilizing HTS materials, high-temperature superconductor antenna investigations, high-Tc superconducting IR detectors, high-Tc superconducting IR detectors from Y-Ba-Cu-O thin films, Y-Ba-Cu0-O thin films as high-speed IR detectors, fabrication of a high-Tc superconducting bolometer, transition-edge microbolometer, photoresponse of YBa2Cu3O(7-delta) granular and epitaxial superconducting thin films, fast IR response of YBCO thin films, kinetic inductance effects in high-Tc microstrip circuits at microwave frequencies.

Superstrate loading effects on the resonant characteristics of high Tc superconducting circular patch printed on anisotropic materials

Science.gov (United States)

Bedra, Sami; Bedra, Randa; Benkouda, Siham; Fortaki, Tarek

2017-12-01

In this paper, the effects of both anisotropies in the substrate and superstrate loading on the resonant frequency and bandwidth of high-Tc superconducting circular microstrip patch in a substrate-superstrate configuration are investigated. A rigorous analysis is performed using a dyadic Galerkin's method in the vector Hankel transform domain. Galerkin's procedure is employed in the spectral domain where the TM and TE modes of the cylindrical cavity with magnetic side walls are used in the expansion of the disk current. The effect of the superconductivity of the patch is taken into account using the concept of the complex resistive boundary condition. London's equations and the two-fluid model of Gorter and Casimir are used in the calculation of the complex surface impedance of the superconducting circular disc. The accuracy of the analysis is tested by comparing the computed results with previously published data for several anisotropic substrate-superstrate materials. Good agreement is found among all sets of results. The numerical results obtained show that important errors can be made in the computation of the resonant frequencies and bandwidths of the superconducting resonators when substrate dielectric anisotropy, and/or superstrate anisotropy are ignored. Other theoretical results obtained show that the superconducting circular microstrip patch on anisotropic substrate-superstrate with properly selected permittivity values along the optical and the non-optical axes combined with optimally chosen structural parameters is more advantageous than the one on isotropic substrate-superstrate by exhibiting wider bandwidth characteristic.

Five-fold way to new high Tc superconductors

Indian Academy of Sciences (India)

shook the foundation of phonon-mediated pairing mechanism. In fact, certain in- ...... of superconducting Tc in doped cuprates below optimal doping. ...... ductor transition, the following are the minimal requirements for superconductivity:.

Experimental Observation of Non-'S-Wave' Superconducting Behavior in Bulk Superconducting Tunneling Junctions of Yba2Cu3O7-δ

Directory of Open Access Journals (Sweden)

Leandro Jose Guerra

1998-06-01

Full Text Available Evidence of non-s-wave superconductivity from normal tunneling experiments in bulk tunneling junctions of YBa2Cu3O7-δ is presented. The I-V and dI/dV characteristics of bulk superconducting tunneling junctions of YBa2Cu3O7-δ have been measured at 77.0K and clear deviation from s-wave superconducting behavior has been observed. The result agrees with d-wave symmetry, and interpreting the data in this way, the magnitude of the superconducting energy gap, 2Δ, is found to be (0.038 ± 0.002 eV. Comparing this energy gap with Tc (2Δ/kB Tc = 5.735, indicates that these high-Tc superconductors are strongly correlated materials, which in contrast with BCS-superconductors are believed to be weakly correlated.

Superconductivity and fast proton transport in nanoconfined water

Science.gov (United States)

Johnson, K. H.

2018-04-01

A real-space molecular-orbital density-wave description of Cooper pairing in conjunction with the dynamic Jahn-Teller mechanism for high-Tc superconductivity predicts that electron-doped water confined to the nanoscale environment of a carbon nanotube or biological macromolecule should superconduct below and exhibit fast proton transport above the transition temperature, Tc ≅ 230 K (-43 °C).

Introduction to superconductivity and high-Tc materials

International Nuclear Information System (INIS)

Cyrot, M.; Pavuna, D.

1991-01-01

What sets this book apart from other introductions to superconductivity and high-T c materials is its pragmatic approach. In this book the authors describe all relevant superconducting phenomena and rely on the macroscopic Ginzburg-Landau theory to derive the most important results. Examples are chosen from selected conventional superconductors like NbTi and compared to those high-T c materials. The text should be of interest to non-specialists in superconductivity either as a textbook for those entering the field (one semester course) or as researchers in advanced technologies and even some managers of interdisciplinary research projects

Influence of multiband sign-changing superconductivity on vortex cores and vortex pinning in stoichiometric high-Tc CaKFe4As4

Science.gov (United States)

Fente, Antón; Meier, William R.; Kong, Tai; Kogan, Vladimir G.; Bud'ko, Sergey L.; Canfield, Paul C.; Guillamón, Isabel; Suderow, Hermann

2018-04-01

We use a scanning tunneling microscope to study the superconducting density of states and vortex lattice of single crystals of CaKFe4As4 . This material has a critical temperature of Tc=35 K, one of the highest among stoichiometric iron based superconductors (FeBSCs), and is comparable to Tc found near optimal doping in other FeBSCs. We observe quasiparticle scattering from defects with a pattern related to interband scattering between zone centered hole sheets. We measure the tunneling conductance in vortex cores and find a peak due to Caroli-de Gennes-Matricon bound states. The peak is located above the Fermi level, showing that CaKFe4As4 is a clean superconductor with vortex core bound states close to the so-called extreme quantum limit. We identify locations where the superconducting order parameter is strongly suppressed due to pair breaking. Vortices are pinned at these locations, and the length scale of the suppression of the order parameter is of order of the vortex core size. As a consequence, the vortex lattice is disordered up to 8 T.

Synthesis of superconducting cobalt oxyhydrates using a novel method: Electrolyzed and oxidized water

International Nuclear Information System (INIS)

Liu, C.-J.; Wu, T.-H.; Hsu, L.-L.; Wang, J.-S.; Chen, S.-Y.

2007-01-01

By deintercalation of Na + followed by inserting bilayers of water molecules into the host lattice, the layered cobalt oxide of γ-Na 0.7 CoO 2 undergoes a topotactic transformation to a layered cobalt oxyhydrate of Na 0.35 (H 2 O) 1.3 CoO 2-δ with the c-axis expanded from c ∼ 10.9 A to c ∼ 19.6 A. In this paper, we demonstrate that the superconducting phase of c ∼ 19.6 A can be directly obtained by simply immersing γ-Na 0.7 CoO 2 powders in electrolyzed/oxidized (EO) water, which is readily available from a commercial electrolyzed water generator. We found that high oxidation-reduction potential of EO water drives the oxidation of the cobalt ions accompanying by the formation of the superconductive c ∼ 19.6 A phase. Our results demonstrate how EO water can be used to oxidize the cobalt ions and hence form superconducting cobalt oxyhydrates in a clean and simple way and may provide an economic and environment-friendly route to oxidize the transition metal of complex metal oxides

Synthesis of superconducting cobalt oxyhydrates using a novel method: Electrolyzed and oxidized water

Science.gov (United States)

Liu, Chia-Jyi; Wu, Tsung-Hsien; Hsu, Lin-Li; Wang, Jung-Sheng; Chen, Shu-Yo

2007-09-01

By deintercalation of Na+ followed by inserting bilayers of water molecules into the host lattice, the layered cobalt oxide of γ-Na0.7CoO2 undergoes a topotactic transformation to a layered cobalt oxyhydrate of Na0.35(H2O)1.3CoO2-δ with the c-axis expanded from c ≈ 10.9 Å to c ≈ 19.6 Å. In this paper, we demonstrate that the superconducting phase of c ≈ 19.6 Å can be directly obtained by simply immersing γ-Na0.7CoO2 powders in electrolyzed/oxidized (EO) water, which is readily available from a commercial electrolyzed water generator. We found that high oxidation-reduction potential of EO water drives the oxidation of the cobalt ions accompanying by the formation of the superconductive c ≈ 19.6 Å phase. Our results demonstrate how EO water can be used to oxidize the cobalt ions and hence form superconducting cobalt oxyhydrates in a clean and simple way and may provide an economic and environment-friendly route to oxidize the transition metal of complex metal oxides.

Synthesis of superconducting cobalt oxyhydrates using a novel method: Electrolyzed and oxidized water

Energy Technology Data Exchange (ETDEWEB)

Liu, C.-J. [Department of Physics, National Changhua University of Education, Changhua 50007, Taiwan (China)], E-mail: liucj@cc.ncue.edu.tw; Wu, T.-H.; Hsu, L.-L.; Wang, J.-S.; Chen, S.-Y. [Department of Physics, National Changhua University of Education, Changhua 50007, Taiwan (China)

2007-09-01

By deintercalation of Na{sup +} followed by inserting bilayers of water molecules into the host lattice, the layered cobalt oxide of {gamma}-Na{sub 0.7}CoO{sub 2} undergoes a topotactic transformation to a layered cobalt oxyhydrate of Na{sub 0.35}(H{sub 2}O){sub 1.3}CoO{sub 2-{delta}} with the c-axis expanded from c {approx} 10.9 A to c {approx} 19.6 A. In this paper, we demonstrate that the superconducting phase of c {approx} 19.6 A can be directly obtained by simply immersing {gamma}-Na{sub 0.7}CoO{sub 2} powders in electrolyzed/oxidized (EO) water, which is readily available from a commercial electrolyzed water generator. We found that high oxidation-reduction potential of EO water drives the oxidation of the cobalt ions accompanying by the formation of the superconductive c {approx} 19.6 A phase. Our results demonstrate how EO water can be used to oxidize the cobalt ions and hence form superconducting cobalt oxyhydrates in a clean and simple way and may provide an economic and environment-friendly route to oxidize the transition metal of complex metal oxides.

Superconductivity

CERN Document Server

Ketterson, John B

2008-01-01

Conceived as the definitive reference in a classic and important field of modern physics, this extensive and comprehensive handbook systematically reviews the basic physics, theory and recent advances in the field of superconductivity. Leading researchers, including Nobel laureates, describe the state-of-the-art in conventional and unconventional superconductors at a particularly opportune time, as new experimental techniques and field-theoretical methods have emerged. In addition to full-coverage of novel materials and underlying mechanisms, the handbook reflects continued intense research into electron-phone based superconductivity. Considerable attention is devoted to high-Tc superconductivity, novel superconductivity, including triplet pairing in the ruthenates, novel superconductors, such as heavy-Fermion metals and organic materials, and also granular superconductors. What’s more, several contributions address superconductors with impurities and nanostructured superconductors. Important new results on...

Superconducting fluctuations and pseudogap in high-Tc cuprates

Directory of Open Access Journals (Sweden)

Alloul H.

2012-03-01

Full Text Available Large pulsed magnetic fields up to 60 Tesla are used to suppress the contribution of superconducting fluctuations (SCF to the ab-plane conductivity above Tc in a series of YBa2Cu3O6+x. These experiments allow us to determine the field Hc’(T and the temperature Tc’ above which the SCFs are fully suppressed. A careful investigation near optimal doping shows that Tc’ is higher than the pseudogap temperature T*, which is an unambiguous evidence that the pseudogap cannot be assigned to preformed pairs. Accurate determinations of the SCF contribution to the conductivity versus temperature and magnetic field have been achieved. They can be accounted for by thermal fluctuations following the Ginzburg-Landau scheme for nearly optimally doped samples. A phase fluctuation contribution might be invoked for the most underdoped samples in a T range which increases when controlled disorder is introduced by electron irradiation. Quantitative analysis of the fluctuating magnetoconductance allows us to determine the critical field Hc2(0 which is found to be be quite similar to Hc’ (0 and to increase with hole doping. Studies of the incidence of disorder on both Tc’ and T* allow us to to propose a three dimensional phase diagram including a disorder axis, which allows to explain most observations done in other cuprate families.

Rugged Low-Resistance Contacts To High-Tc Superconductors

Science.gov (United States)

Caton, Randall; Selim, Raouf; Byvik, Charles E.; Buoncristiani, A. Martin

1992-01-01

Newly developed technique involving use of gold makes possible to fabricate low-resistance contacts with rugged connections to high-Tc superconductors. Gold diffused into specimen of superconducting material by melting gold beads onto surface of specimen, making strong mechanical contacts. Shear strength of gold bead contacts greater than epoxy or silver paste. Practical use in high-current-carrying applications of new high-Tc materials, including superconducting magnets, long-wavelength sensors, electrical ground planes at low temperatures, and efficient transmission of power.

Separation of sup(99m)Tc from 99Mo through a hydrous zirconium oxide column

International Nuclear Information System (INIS)

Mengatti, J.

1980-01-01

The preparation of 99 Mo-,sup(99m)Tc generator based on the adsorption of 99 Mo on hydrous zirconium oxide column, employing the in exchange technique, is described. The adsorption of 99 Mo on hydrous zirconium oxide (HZO) and the separation of sup(99m)Tc, generated by the decay of 99 Mo with saline solution, are analised. The sup(99m)Tc separation yield, pH of the eluted solution, aspect of the elution curve and the adsorption of 99 Mo on hydrous zirconium oxide calcined at 800 0 C are studied. The chemical and radioactive purities of the final product are analysed and the variation of the elution yield for successive elutions is studied. (Author) [pt

Characterization of superconducting coil for fault current limitation

International Nuclear Information System (INIS)

Polasek, Alexander; Dias, Rodrigo; Niedu, Daniel Brito; Ogasawara, Tsuneharu; Oliveira Filho, Orsino Borges de; Serra, Eduardo Torres; Gomes Junior, George; Amorim, Helio Salim

2010-01-01

The increasing power demand has been raising fault currents up to dangerous levels. Superconducting fault current limiters are a promising solution for this problem. In the present work, we studied a superconducting Bi-2212 coil that is used for fault current limitation. Samples were analyzed by XRD, SEM/EDS and measurement of critical temperature (Tc). The Rietveld method was employed for phase quantification. Relatively high Bi-2212 fractions were found. However, Tc varies from a sample to another one. Variations of local Tc are attributed to variations of oxygen content in Bi- 2212 phase. (author)

Superconductivity in single wall carbon nanotubes

Directory of Open Access Journals (Sweden)

H Yavari

2009-08-01

Full Text Available   By using Greens function method we first show that the effective interaction between two electrons mediated by plasmon exchange can become attractive which in turn can lead to superconductivity at a high critical temperature in a singl wall carbon nanotubes (SWCNT. The superconducting transition temperature Tc for the SWCNT (3,3 obtained by this mechanism agrees with the recent experimental result. We also show as the radius of SWCNT increases, plasmon frequency becomes lower and leads to lower Tc.

The NMR probe of high-Tc materials and correlated electron systems

CERN Document Server

Walstedt, Russell E

2018-01-01

This new edition updates readers in three areas of NMR studies, namely, recent developments in high-Tc materials, heavy fermion systems and actinide oxides are presented.  The NMR probe has yielded a vast array of data for solid state materials, corresponding to different compounds, ionic sites, and nuclear species, as well as to a wide variety of experimental conditions. The last two parts of the book are completely new in this edition, while the first part has seen major updates. This edition features the latest developments for high-Tc materials, especially the advances in the area of pseudogap studies are reviewed.  An in depth overview of heavy fermion systems is presented in the second part,  notably Kondo lattices, quantum critical points and unconventional superconductivity are areas of intense research recently and are covered extensively. Finally, valuable information from NMR studies with actinide oxides will be provided. Ongoing analysis and discussion of NMR data have resulted in a wealth o...

What is the role of Pb(II) in high Tc superconductors

International Nuclear Information System (INIS)

Raveau, B.; Hervieu, M.; Michel, C.; Groult, D.; Provost, J.

1990-01-01

An overview of the layered lead cuprates is presented here. The structure of these oxides and their non-stoichiometry are studied in connection with their superconducting properties. The phenomena involving a modulation of the structure, characterized by the presence of satellites on E.D. patterns are described and the particular role of the 6s 2 lone pair of Pb(II) is discussed. Divalent lead is, owing to its size intermediate between that of strontium and barium, a potential cation for superconductive cuprates. Moreover, this interest for Pb(II), is supported by its electronic structure which involves an electronic 6s 2 lone pair well known for its ability to form layered structures. In spite of these characteristics, few superconductive layered suprates were isolated at the beginning of the rush to high Tc superconductors. This is probably due to the possibility of existence of redox reactions involving the couple Pb(II)/Pb(IV), which require very particular experimental conditions. The authors report here on the recent development of the crystal chemistry of those materials and on their corresponding superconducting properties

Magnetically-related properties of bismuth containing high Tc superconductors

Science.gov (United States)

Vezzoli, Gary C.; Chen, M. F.; Craver, F.; Safari, A.; Moon, B. M.; Lalevic, B.; Burke, Terence; Shoga, M.

1990-08-01

The effect of magnetic fields to 15 T on electrical resistance has been measured for the BiSrCaCuO superconductor at precise temperatures during the transition to the superconducting state from pre-onset conditions to essentially zero resistance conditions. The results show that the temperature at which the magnetic field causes a divergence in the resistance versus 1000/ T curve is approximately the same temperature as the value at which, during cooling, the positive Hall coefficient begins its abrupt descent to zero. This temperature gives the best measure of Tc. It is also shown that small oscillations of low frequency start near onset conditions, the amplitude of which at a given temperature is B-field dependent. Additionally, Hall effect studies as a function of temperature at 4 T in three separate experiments (including high Tc BiSrCaCu PbO of > 90% theoretical density) show that sharp delta-function-like peaks in + RH are observed near Tc and are superimposed on a broader maximum. The Hall data are explicable in terms of exciton formation and ionization. The bound holes associated with these excitons are believed to be the mediators producing Cooper-pairing, and scale very well with Tc for all the known high Tc oxides.

Superconductivity: materials and applications; La supraconductivite: materiaux et apllications

Energy Technology Data Exchange (ETDEWEB)

Duchateau, J.L. [CEA Cadarache, 13 - Saint Paul lez Durance (France); Kircher, F. [CEA Saclay, 91 - Gif sur Yvette (France); Leveque, J. [Groupe de Recherche en Electrotechnique et Electronique de Nancy, GREEN - UHP, 54 - Vandoeuvre les Nancy (France); Tixador, P. [INP/Institut Neel, 38 - Grenoble (France)

2008-07-01

This digest paper presents the different types of superconducting materials: 1 - the low-TC superconductors: the multi-filament composite as elementary constituent, the world production of NbTi, the superconducting cables of the LHC collider and of the ITER tokamak; 2 - the high-TC superconductors: BiSrCaCuO (PIT 1G) ribbons and wires, deposited coatings; 3 - application to particle physics: the the LHC collider of the CERN, the LHC detectors; 4 - applications to thermonuclear fusion: Tore Supra and ITER tokamaks; 5 - NMR imaging: properties of superconducting magnets; 6 - applications in electrotechnics: cables, motors and alternators, current limiters, transformers, superconducting energy storage systems (SMES). (J.S.)

Bi-Polaron Condensation in High Tc Superconductors

International Nuclear Information System (INIS)

Ranninger, J.

1995-01-01

On the basis of optical measurements-, photoemission-, EXAFS- and neutron scattering-experiments we conclude that itinerant valence electrons coexist with localized bi-polarons.Entering the metallic phase upon chemical doping, a charge transfer between the two electronic subsystems is triggered off. We show that as the temperature is lowered towards Tc this process leads to a delocalization of bi-polarons due to a precursor effect of superfluidity of those bi-polarons. Upon entering the superconducting phase, these bipolarons ultimately condense into a superfluid state which is expected to largely determine the superconducting properties of high Tc materials. (authors)

High Tc Superconducting Magnet Excited by a Semiconductor Thermoelectric Element

Science.gov (United States)

Kuriyama, T.; Ono, M.; Tabe, S.; Oguchi, A.; Okamura, T.

2006-04-01

A high Tc superconducting (HTS) magnet excited by a thermal electromotive force of a thermoelectric element is studied. This HTS magnet has the advantages of compactness, lightweight and continuous excitation in comparison with conventional HTS magnets, because this HTS magnet does not need a large external power source. In this system, a heat input into the cryogenic environment is necessary to excite the thermoelectric element for constant operation. This heat generation, however, causes a rise in temperature of an HTS coil and reduces the system performance. In this paper, a newly designed magnet system which adopted a two-stage GM cryocooler was investigated. It enabled us to control the temperature of a thermoelectric element and that of an HTS coil independently. The temperature of the HTS coil could be kept at 10-20 K at the second stage of the GM cryocooler, while the thermoelectric element could be excited at higher temperature in the range of 50-70 K at the first stage, where the performance of the thermoelectric element was higher. The experimental results on this HTS magnet are shown and the possibility of the thermoelectric element as a main power source of the HTS magnets is discussed.

Colloquium: High pressure and road to room temperature superconductivity

Science.gov (United States)

Gor'kov, Lev P.; Kresin, Vladimir Z.

2018-01-01

This Colloquium is concerned with the superconducting state of new high-Tc compounds containing hydrogen ions (hydrides). Recently superconductivity with the record-setting transition temperature of Tc=203 K was reported for sulfur hydrides under high pressure. In general, high pressure serves as a path finding tool toward novel structures, including those with very high Tc . The field has a rich and interesting history. Currently, it is broadly recognized that superconductivity in sulfur hydrides owes its origin to the phonon mechanism. However, the picture differs from the conventional one in important ways. The phonon spectrum in sulfur hydride is both broad and has a complex structure. Superconductivity arises mainly due to strong coupling to the high-frequency optical modes, although the acoustic phonons also make a noticeable contribution. A new approach is described, which generalizes the standard treatment of the phonon mechanism and makes it possible to obtain an analytical expression for Tc in this phase. It turns out that, unlike in the conventional case, the value of the isotope coefficient (for the deuterium-hydrogen substitution) varies with the pressure and reflects the impact of the optical modes. The phase diagram, that is the pressure dependence of Tc , is rather peculiar. A crucial feature is that increasing pressure results in a series of structural transitions, including the one which yields the superconducting phase with the record Tc of 203 K. In a narrow region near P ≈150 GPa the critical temperature rises sharply from Tc≈120 to ≈200 K . It seems that the sharp structural transition, which produces the high-Tc phase, is a first-order phase transition caused by interaction between the order parameter and lattice deformations. A remarkable feature of the electronic spectrum in the high-Tc phase is the appearance of small pockets at the Fermi level. Their presence leads to a two-gap spectrum, which can, in principle, be observed with the

Analysis of the superconductivity in perovskite oxides using three ...

Indian Academy of Sciences (India)

2Institute of Theoretical Physics, University of Erlangen-Nürnberg, D-91058 Erlangen, Germany ... taining oxide superconductor with the transition temperature (Tc ≈ 30 K, for x = 0.4 ... high-frequency (energy) optical phonons, as the answer.

Enhanced⁹⁹Tc retention in glass waste form using Tc(IV)-incorporated Fe minerals

OpenAIRE

Um, W; Luksic, SA; Wang, G; Saslow, S; Kim, DS; Schweiger, MJ; Soderquist, CZ; Bowden, ME; Lukens, WW; Kruger, AA

2017-01-01

© 2017 Elsevier B.V. Technetium ( 99 Tc) immobilization by doping into iron oxide mineral phases may alleviate the problems with Tc volatility during vitrification of nuclear waste. Because reduced Tc, Tc(IV), substitutes for Fe(III) in the crystal structure by a process of Tc reduction from Tc(VII) to Tc(IV) followed by co-precipitation of Fe oxide minerals, two Tc-incorporated Fe minerals (Tc-goethite and Tc-magnetite/maghemite) were prepared and tested for Tc retention in glass melt sample...

Conductus makes high-Tc integrated circuit

International Nuclear Information System (INIS)

Anon.

1991-01-01

This paper reports that researchers at Conductus have successfully demonstrated what the company says is the world's first integrated circuit containing active devices made from high-temperature superconductors. The circuit is a SQUID magnetometer made from seven layers of material: three layers of yttrium-barium-copper oxide, two layers of insulating material, a seed layer to create grain boundaries for the Josephson junctions, and a layer of silver for making electrical contact to the device. The chip also contains vias, or pathways that make a superconducting contact between the superconducting layers otherwise separated by insulators. Conductus had previously announced the development of a SQUID magnetometer that featured a SQUID sensor and a flux transformer manufactured on separate chips. What makes this achievement important is that the company was able to put both components on the same chip, thus creating a simple integrated circuit on a single chip. This is still a long way from conventional semiconductor technology, with as many as a million components per chip, or even the sophisticated low-Tc superconducting chips made by the Japanese, but the SQUID magnetometer demonstrates all the elements and techniques necessary to build more complex high-temperature superconductor integrated circuits, making this an important first step

Preparation and properties of high-Tc Bi-oxide superconductors

International Nuclear Information System (INIS)

Maeda, H.

1989-01-01

Bulk superconductors of Pb-doped Bi-oxide system (BSCCO) dominated with the high-Tc phase have the critical transition temperature, Tc of 110 K, and the upper critical fields, H c2 of 140 T at OK and 60 T at 77 K. A highly dense and a highly oriented microstructure is obtained by inserting an intermediate uniaxial pressing process. The critical current density, Jc at 77 K in zero field, Jc (77K,OT) of some 5000 A/cm 2 can be easily obtained by this process, and the field dependence of Jc is also improved. Flexible high-Tc BSCCO ribbons with a Jc (77K,Ot) of 1850 A/cm 2 have been successfully prepared by the combined process of doctor blade casting, cold rolling and sintering. Aq-sheeted multifilamentary wires with 1330 filaments and tapes with 30 filaments have also been successfully fabricated and the 36-filament tape shows a Jc(77K,OT) of 1050 A/cm 2 . (Auth.). 7 refs.; 7 figs

Y-Ba-Cu-O superconducting film on oxidized silicon

International Nuclear Information System (INIS)

Gupta, R.P.; Khokle, W.S.; Dubey, R.C.; Singhal, S.; Nagpal, K.C.; Rao, G.S.T.; Jain, J.D.

1988-01-01

We report thick superconducting films of Y-Ba-Cu-O on oxidized silicon substrates. The critical temperatures for onset and zero resistance are 96 and 77 K, respectively. X-ray diffraction analysis predicts 1, 2, 3 composition and orthorhombic phase of the film

Temperature Dependence of Quasiparticle Spectral Weight and Coherence in High Tc Superconductors

Science.gov (United States)

He, Yang; Zhang, Jessie; Hoffman, Jennifer; Hoffman Lab Team

2014-03-01

Superconductivity arises from the Cooper pairing of quasiparticles on the Fermi surface. Understanding the formation of Cooper pairs is an essential step towards unveiling the mechanism of high Tc superconductivity. We compare scanning tunneling microscope investigations of the temperature dependence of quasiparticle spectral weight and quasiparticle interference in several families of high Tc materials. We calculate the coherent spectral weight related to superconductivity, despite the coexistence of competing orders. The relation between pairing temperature and coherent spectral weight is discussed. We acknowledge support by the New York Community Trust-George Merck Fund.

Dependence of the residual surface resistance of superconducting radio frequency cavities on the cooling dynamics around Tc

Science.gov (United States)

Romanenko, A.; Grassellino, A.; Melnychuk, O.; Sergatskov, D. A.

2014-05-01

We report a strong effect of the cooling dynamics through Tc on the amount of trapped external magnetic flux in superconducting niobium cavities. The effect is similar for fine grain and single crystal niobium and all surface treatments including electropolishing with and without 120 °C baking and nitrogen doping. Direct magnetic field measurements on the cavity walls show that the effect stems from changes in the flux trapping efficiency: slow cooling leads to almost complete flux trapping and higher residual resistance, while fast cooling leads to the much more efficient flux expulsion and lower residual resistance.

CO2-laser ablation of Bi-Sr-Ca-Cu oxide by millisecond pulse lengths

Science.gov (United States)

Meskoob, M.; Honda, T.; Safari, A.; Wachtman, J. B.; Danforth, S.; Wilkens, B. J.

1990-03-01

We have achieved ablation of Bi-Sr-Ca-Cu oxide from single targets of superconducting pellets by CO2-laser pulses of l ms length to grow superconducting thin films. Upon annealing, the 6000-Å thin films have a Tc (onset) of 90 K and zero resistance at 78 K. X-ray diffraction patterns indicate the growth of single-phase thin films. This technique allows growth of uniform single-phase superconducting thin films of lateral area greater than 1 cm2.

Theory of novel normal and superconducting states in doped oxide high-Tc superconductors

International Nuclear Information System (INIS)

Dzhumanov, S.

2001-10-01

A consistent and complete theory of the novel normal and superconducting (SC) states of doped high-T c superconductors (HTSC) is developed by combining the continuum model of carrier self-trapping, the tight-binding model and the novel Fermi-Bose-liquid (FBL) model. The ground-state energy of carriers in lightly doped HTSC is calculated within the continuum model and adiabatic approximation using the variational method. The destruction of the long-range antiferromagnetic (AF) order at low doping x≥ x cl ≅0.015, the formation of the in-gap states or bands and novel (bi)polaronic insulating phases at x c2 ≅0.06-0.08, and the new metal- insulator transition at x≅x c2 in HTSC are studied within the continuum model of impurity (defect) centers and large (bi)polarons by using the appropriate tight-binding approximations. It is found that the three-dimensional (3d) large (bi)polarons are formed at ε ∞ /ε 0 ≤0.1 and become itinerant when the (bi)polaronic insulator-to-(bi)polaronic metal transitions occur at x x c2 . We show that the novel pseudogapped metallic and SC states in HTSC are formed at x c2 ≤x≤x p ≅0.20-0.24. We demonstrate that the large polaronic and small BCS-like pairing pseudogaps opening in the excitation spectrum of underdoped (x c2 BCS =0.125), optimally doped (x BCS o ≅0.20) and overdoped (x>x o ) HTSC above T c are unrelated to superconductivity and they are responsible for the observed anomalous optical, transport, magnetic and other properties of these HTSC. We develop the original two-stage FBL model of novel superconductivity describing the combined novel BCS-like pairing scenario of fermions and true superfluid (SF) condensation scenario of composite bosons (i.e. bipolarons and cooperons) in any Fermi-systems, where the SF condensate gap Δ B and the BCS-like pairing pseudogap Δ F have different origins. The pair and single particle condensations of attracting 3d and two- dimensional (2d) composite bosons are responsible for

Quasiparticles in the superconducting state of high-Tc metals

International Nuclear Information System (INIS)

Amusia, M.Ya.; Shaginyan, V.R.

2003-01-01

The behavior of quasiparticles in the superconducting state of high-T c metals within the framework of the theory of superconducting state based on the fermion condensation quantum phase transition is considered. It is shown that the behavior coincides with the behavior of Bogoliubov quasiparticles, whereas the maximum value of the superconducting gap and other exotic properties are determined by the presence of the fermion condensate. If at low temperatures the normal state is recovered by the application of a magnetic field suppressing the superconductivity, the induced state can be viewed as Landau-Fermi liquid. These observations are in good agreement with recent experimental facts [ru

Structural phase transitions and superconductivity in lanthanum copper oxides

International Nuclear Information System (INIS)

Crawford, M.K.; Harlow, R.L.; McCarron, E.M.

1996-01-01

Despite the enormous effort expended over the past ten years to determine the mechanism underlying high temperature superconductivity in cuprates there is still no consensus on the physical origin of this fascinating phenomenon. This is a consequence of a number of factors, among which are the intrinsic difficulties in understanding the strong electron correlations in the copper oxides, determining the roles played by antiferromagnetic interactions and low dimensionality, analyzing the complex phonon dispersion relationships, and characterizing the phase diagrams which are functions of the physical parameters of temperature and pressure, as well as the chemical parameters of stoichiometry and hole concentration. In addition to all of these intrinsic difficulties, extrinsic materials issues such as sample quality and homogeneity present additional complications. Within the field of high temperature superconductivity there exists a subfield centered around the material originally reported to exhibit high temperature superconductivity by Bednorz and Mueller, Ba doped La 2 CuO 4 . This is structurally the simplest cuprate superconductor. The authors report on studies of phase differences observed between such base superconductors doped with Ba or Sr. What these studies have revealed is a fascinating interplay of structural, magnetic and superconducting properties which is unique in the field of high temperature superconductivity and is summarized in this paper

A new way for preparing superconducting materials: the electrochemical oxidation of La2CuO4

International Nuclear Information System (INIS)

Wattiaux, A.; Park, J.C.; Grenier, J.C.; Pouchard, M.

1990-01-01

The electrochemical oxidation in alkaline medium is described as a new way for preparing superconducting oxides at room temperature. The application of this method to La 2 CuO 4 gave rise to a metallic material with a superconducting behaviour below 39 K and whose physical and chemical features appear as quite promising [fr

Superconductivity and ceramic superconductors II; Proceedings of the Symposium, Orlando, FL, Nov. 12-15, 1990. Ceramic transactions. Vol. 18

International Nuclear Information System (INIS)

Nair, K.M.; Balachandran, U.; Chiang, Y.-M.; Bhalla, A.S.

1991-01-01

The present symposium on superconductivity and ceramic superconductors discusses fundamentals and general principles, powder processing and properties, fabrication and properties, and device reliability and applications. Attention is given to phase formation in the Tl-Ca-Ba-Cu-O system, comparative defect studies in La2CuO4 and La2NiO4, solid solution and defect behavior in high Tc oxides, oxygen ion transport and disorder in cuprates, and Sr-free Bi-Ln-Ca-Cu-O superconductors. Topics addressed include the preparation of superconductor Y-Ba-Cu-O powder by single-step calcining in air, low-temperature synthesis of YBa2Cu3O(7-x), synthesis of high-phase purity ceramic oxide superconductors by the xerogel method, and the preparation and characterization of the BYa2Cu4O8 superconductor. Also discussed are optical studies of humidity-based corrosion effects on thin film and bulk ceramic YBa2Cu3O(7-delta), thermomechanical processing of YBa2Cu3O(x)/Ag sheathed wires, and the expansion of high-Tc superconducting ceramics

Powder of a copper oxide superconductor precursor, fabrication process and use for the preparation of superconducting oxide

International Nuclear Information System (INIS)

Dehaudt, P.

1990-01-01

The precursor powder comprises at least a copper compound (hydroxide, oxide and hydroxynitrates), at least a rare earth and/or yttrium compound (nitrates, hydroxides and hydroxynitrates) or bismuth oxide and at least an alkaline earth nitrate. It can be prepared by atomization drying of a suspension a copper precipitate or coprecipitate and other elements of the superconducting oxide in solution [fr

Plasma oxidation of the high T/sub c/ superconducting perovskites

International Nuclear Information System (INIS)

Bagley, B.G.; Greene, L.H.; Tarascon, J.; Hull, G.W.

1987-01-01

A near room-temperature plasma oxidation process is shown to restore superconductivity and metalliclike behavior in oxygen deficient La/sub 2-//sub x/ Sr/sub x/ CuO/sub 4-//sub y/ and YBa 2 Cu 3 O/sub 7-//sub x/ compounds. In the YBa 2 Cu 3 O/sub 7-//sub x/ compound the conversion from an oxygen deficient n-type tetragonal to the p-type orthorhombic phase with a concomitant factor of 5 x 10 5 increase in room-temperature conductivity is also accomplished. This process is of technological importance because oxygen can be restored in these materials at temperatures compatible with device processing. Of scientific interest, the process allows us to carefully control the oxidation state and thereby systematically study the 90 and 55 K superconducting transitions in YBa 2 Cu 3 O/sub 7-//sub x/

Spectroscopy of metal "superatom" nanoclusters and high-Tc superconducting pairing

Science.gov (United States)

Halder, Avik; Kresin, Vitaly V.

2015-12-01

A unique property of metal nanoclusters is the "superatom" shell structure of their delocalized electrons. The electronic shell levels are highly degenerate and therefore represent sharp peaks in the density of states. This can enable exceptionally strong electron pairing in certain clusters composed of tens to hundreds of atoms. In a finite system, such as a free nanocluster or a nucleus, pairing is observed most clearly via its effect on the energy spectrum of the constituent fermions. Accordingly, we performed a photoionization spectroscopy study of size-resolved aluminum nanoclusters and observed a rapid rise in the near-threshold density of states of several clusters (A l37 ,44 ,66 ,68 ) with decreasing temperature. The characteristics of this behavior are consistent with compression of the density of states by a pairing transition into a high-temperature superconducting state with Tc≳100 K. This value exceeds that of bulk aluminum by two orders of magnitude. These results highlight the potential of novel pairing effects in size-quantized systems and the possibility to attain even higher critical temperatures by optimizing the particles' size and composition. As a new class of high-temperature superconductors, such metal nanocluster particles are promising building blocks for high-Tc materials, devices, and networks.

Magnetic-Field-Tunable Superconducting Rectifier

Science.gov (United States)

Sadleir, John E.

2009-01-01

Superconducting electronic components have been developed that provide current rectification that is tunable by design and with an externally applied magnetic field to the circuit component. The superconducting material used in the device is relatively free of pinning sites with its critical current determined by a geometric energy barrier to vortex entry. The ability of the vortices to move freely inside the device means this innovation does not suffer from magnetic hysteresis effects changing the state of the superconductor. The invention requires a superconductor geometry with opposite edges along the direction of current flow. In order for the critical current asymmetry effect to occur, the device must have different vortex nucleation conditions at opposite edges. Alternative embodiments producing the necessary conditions include edges being held at different temperatures, at different local magnetic fields, with different current-injection geometries, and structural differences between opposite edges causing changes in the size of the geometric energy barrier. An edge fabricated with indentations of the order of the coherence length will significantly lower the geometric energy barrier to vortex entry, meaning vortex passage across the device at lower currents causing resistive dissipation. The existing prototype is a two-terminal device consisting of a thin-film su - perconducting strip operating at a temperature below its superconducting transition temperature (Tc). Opposite ends of the strip are connected to electrical leads made of a higher Tc superconductor. The thin-film lithographic process provides an easy means to alter edge-structures, current-injection geo - metries, and magnetic-field conditions at the edges. The edge-field conditions can be altered by using local field(s) generated from dedicated higher Tc leads or even using the device s own higher Tc superconducting leads.

Plasma clearance and biodistribution of oxidatively modified 99mTc-ß-VLDL in rabbits

Directory of Open Access Journals (Sweden)

Silva E.L.

1997-01-01

Full Text Available The biodistribution and removal from plasma (measured as fractional clearance rate, FCR, per hour of native and oxidatively modified 99mtechnetium-labeled ß-very low density lipoprotein (99mTc-ß-VLDL were investigated in hypercholesterolemic (HC and control (C three-month old New Zealand rabbits. The intracellular accumulation of ß-VLDL labeled with 99mTc was studied in vitro in THP-1 cells and monocyte-derived macrophages isolated from rabbits. After intravenous injection into C rabbits, copper-oxidized ß-VLDL (99mTc-ox-ß-VLDL was cleared from the circulation faster (0.362 ± 0.070/h than native ß-VLDL (99mTc-nat-ß-VLDL, 0.241 ± 0.070/h. In contrast, the FCR of 99mTc-ox-ß-VLDL in HC rabbits was lower (0.100 ± 0.048/h than that of 99mTc-nat-ß-VLDL (0.163 ± 0.043/h. The hepatic uptake of radiolabeled lipoproteins was lower in HC rabbits (0.114 ± 0.071% injected dose/g tissue for 99mTc-nat-ß-VLDL and 0.116 ± 0.057% injected dose/g tissue for 99mTc-ox-ß-VLDL than in C rabbits (0.301 ± 0.113% injected dose/g tissue for 99mTc-nat-ß-VLDL and 0.305 ± 0.149% injected dose/g tissue for 99mTc-ox-ß-VLDL. The uptake of 99mTc-nat-ß-VLDL and 99mTc-ox-ß-VLDL by atherosclerotic aorta lesions isolated from HC rabbits (99mTc-nat-ß-VLDL: 0.033 ± 0.012% injected dose/g tissue and 99mTc-ox-ß-VLDL: 0.039 ± 0.017% injected dose/g tissue was higher in comparison to that of non-atherosclerotic aortas from C rabbits (99mTc-nat-ß-VLDL: 0.023 ± 0.010% injected dose/g tissue and 99mTc-ox-ß-VLDL: 0.019 ± 0.010% injected dose/g tissue. However, 99mTc-nat-ß-VLDL and 99mTc-ox-ß-VLDL were taken up by atherosclerotic lesions at similar rates. In vitro studies showed that both monocyte-derived macrophages isolated from rabbits and THP-1 macrophages significantly internalized more 99mTc-ox-ß-VLDL than 99mTc-nat-ß-VLDL. These results indicate that in cholesterol-fed rabbits 99mTc-ox-ß-VLDL is slowly cleared from plasma and accumulates in

Dynamics of correlation-frozen antinodal quasiparticles in superconducting cuprates

Science.gov (United States)

Cilento, Federico; Manzoni, Giulia; Sterzi, Andrea; Peli, Simone; Ronchi, Andrea; Crepaldi, Alberto; Boschini, Fabio; Cacho, Cephise; Chapman, Richard; Springate, Emma; Eisaki, Hiroshi; Greven, Martin; Berciu, Mona; Kemper, Alexander F.; Damascelli, Andrea; Capone, Massimo; Giannetti, Claudio; Parmigiani, Fulvio

2018-01-01

Many puzzling properties of high–critical temperature (Tc) superconducting (HTSC) copper oxides have deep roots in the nature of the antinodal quasiparticles, the elementary excitations with wave vector parallel to the Cu–O bonds. These electronic states are most affected by the onset of antiferromagnetic correlations and charge instabilities, and they host the maximum of the anisotropic superconducting gap and pseudogap. We use time-resolved extreme-ultraviolet photoemission with proper photon energy (18 eV) and time resolution (50 fs) to disclose the ultrafast dynamics of the antinodal states in a prototypical HTSC cuprate. After photoinducing a nonthermal charge redistribution within the Cu and O orbitals, we reveal a dramatic momentum-space differentiation of the transient electron dynamics. Whereas the nodal quasiparticle distribution is heated up as in a conventional metal, new quasiparticle states transiently emerge at the antinodes, similarly to what is expected for a photoexcited Mott insulator, where the frozen charges can be released by an impulsive excitation. This transient antinodal metallicity is mapped into the dynamics of the O-2p bands, thus directly demonstrating the intertwining between the low- and high-energy scales that is typical of correlated materials. Our results suggest that the correlation-driven freezing of the electrons moving along the Cu–O bonds, analogous to the Mott localization mechanism, constitutes the starting point for any model of high-Tc superconductivity and other exotic phases of HTSC cuprates. PMID:29507885

Correlation effects in high-Tc superconductors and heavy fermion compounds

International Nuclear Information System (INIS)

Kuzemsky, A.L.

1993-10-01

This paper describes certain aspects of Highly Correlated Systems (HCS) such as high Tc superconductors (HTSC) and some new class of Heavy Fermion (HF) systems which have been studied recently. The problem is discussed on how the charge and spin degrees of freedom participate in the specific character of superconductivity in the copper oxides and competition of the magnetism and Kondo screening in heavy fermions. The electronic structure and possible superconducting mechanisms of HTSC compounds are discussed. The similarity and dissimilarity with HF compounds is pointed out. It is shown that the spins and carriers in the copper oxides are coupled in a very nontrivial way in order to introduce the discussion and the comparison of the Emery model, the t - J-model and the Kondo-Heisenberg model. It concerns attempts to derive from fundamental multi-band Hamiltonian the reduced effective Hamiltonians to extract and separate the relevant low-energy physics. A short review of the arguments which seem to support the spin-polaron pairing mechanism in HTSC are presented. Many other topics like the idea of mixed valence states in oxides, the role of charge transfer (CT) excitations, phase separation, self-consistent nonperturbative technique, etc. are also discussed. (author). 161 refs

Spin dynamics in high-TC superconducting cuprates

International Nuclear Information System (INIS)

Bourges, Ph.

2003-07-01

This work is dedicated to the detailed investigations of the magnetic resonance peak in the superconducting state of cuprates. The existence of such a peak could be the signature of a mechanism linked to magnetism that could explain high critical temperature superconductivity. Inelastic neutron scattering is an adequate tool for the understanding of cuprate properties because it reveals magnetic fluctuations whose behaviour and variety depend strongly on temperature and on the level of doping. The last part of this work is dedicated to the study of spin dynamics in YBa 2 Cu 3 O 6+x system

Possibility of high temperature superconducting phases in PdH

Science.gov (United States)

Tripodi, Paolo; Di Gioacchino, Daniele; Borelli, Rodolfo; Vinko, Jenny Darja

2003-05-01

Possible new superconducting phases with a high critical transition temperature (Tc) have been found in stable palladium-hydrogen (PdHx) samples for stoichiometric ratio x=H/Pd⩾1, in addition to the well-known low critical transition temperature (0⩽Tc⩽9) when x is in the range (0.75⩽x⩽1.00). Possible new measured superconducting phases with critical temperature in the range 51⩽Tc⩽295 K occur. This Tc varies considerably with every milli part of x when x exceeds unit. A superconducting critical current density Jc⩾6.1×104 A cm-2 has been measured at 77 K with HDC=0 T.

Anomalous magnetism of superconducting Mg-doped InN film

Directory of Open Access Journals (Sweden)

P. H. Chang

2016-02-01

Full Text Available We report on the Meissner effect of Mg-doped InN film with superconducting transition onset temperature Tc,onset of 5 K. Mg-doped InN is magnetically ordered and exhibits a simultaneous first-order magnetic and electric transition near 50 K. Its behavior is similar to that of iron-based superconductors. A strong correlation is proposed to exist between structural distortion and superconductivity when Mg is doped into InN. The suppression of magnetic ordering close to Tc by doping is further demonstrated by anisotropic magnetoresistance and M-H measurements. The findings suggest that the superconducting mechanism in the system may not be conventional BCS.

Microscopic Superconductivity and Room Temperature Electronics of High-Tc Cuprates

International Nuclear Information System (INIS)

Liu Fusui; Chen Wanfang

2008-01-01

This paper points out that the Landau criterion for macroscopic superfluidity of He II is only a criterion for microscopic superfluidity of 4 He, extends the Landau criterion to microscopic superconductivity in fermions (electron and hole) system and system with Cooper pairs without long-range phase coherence. This paper gives another three non-superconductive systems that are of microscopic superconductivity. This paper demonstrates that one application of microscopic superconductivity is to establish room temperature electronics of the high-T c cuprates

High-Tc Superconducting Bolometer Noise Measurement Using Low Noise Transformers - Theory and Optimization

Science.gov (United States)

Aslam, Shahid; Jones, Hollis H.

2011-01-01

Care must always be taken when performing noise measurements on high-Tc superconducting materials to ensure that the results are not from the measurement system itself. One situation likely to occur is with low noise transformers. One of the least understood devices, it provides voltage gain for low impedance inputs (< 100 ), e.g., YBaCuO and GdBaCuO thin films, with comparatively lower noise levels than other devices for instance field effect and bipolar junction transistors. An essential point made in this paper is that because of the complex relationships between the transformer ports, input impedance variance alters the transformer s transfer function in particular, the low frequency cutoff shift. The transfer of external and intrinsic transformer noise to the output along with optimization and precautions are treated; all the while, we will cohesively connect the transfer function shift, the load impedance, and the actual noise at the transformer output.

Lighting up superconducting stripes

Science.gov (United States)

Ergeçen, Emre; Gedik, Nuh

2018-02-01

Cuprate superconductors display a plethora of complex phases as a function of temperature and carrier concentration, the understanding of which could provide clues into the mechanism of superconductivity. For example, when about one-eighth of the conduction electrons are removed from the copper oxygen planes in cuprates such as La2‑xBaxCuO4 (LBCO), the doped holes (missing electrons) organize into one-dimensional stripes (1). The bulk superconducting transition temperature (Tc) is greatly reduced, and just above Tc, electrical transport perpendicular to the planes (along the c axis) becomes resistive, but parallel to the copper oxygen planes, resistivity remains zero for a range of temperatures (2). It was proposed a decade ago (3) that this anisotropic behavior is caused by pair density waves (PDWs); superconducting Cooper pairs exist along the stripes within the planes but cannot tunnel to the adjacent layers. On page 575 of this issue, Rajasekaran et al. (4) now report detection of this state in LBCO using nonlinear reflection of high-intensity terahertz (THz) light.

SHMUTZ & PROTON-DIAMANT H + Irradiated/Written-Hyper/Super-conductivity(HC/SC) Precognizance/Early Experiments Connections: Wet-Graphite Room-Tc & Actualized MgB2 High-Tc: Connection to Mechanical Bulk-Moduli/Hardness: Diamond Hydrocarbon-Filaments, Disorder, Nano-Powders:C,Bi,TiB2,TiC

Science.gov (United States)

Wunderman, Irwin; Siegel, Edward Carl-Ludwig; Lewis, Thomas; Young, Frederic; Smith, Adolph; Dresschhoff-Zeller, Gieselle

2013-03-01

SHMUTZ: ``wet-graphite''Scheike-....[Adv.Mtls.(7/16/12)]hyper/super-SCHMUTZ-conductor(S!!!) = ``wet''(?)-``graphite''(?) = ``graphene''(?) = water(?) = hydrogen(?) =ultra-heavy proton-bands(???) = ...(???) claimed room/high-Tc/high-Jc superconductOR ``p''-``wave''/ BAND(!!!) superconductIVITY and actualized/ instantiated MgB2 high-Tc superconductors and their BCS- superconductivity: Tc Siegel[ICMAO(77);JMMM 7,190(78)] connection to SiegelJ.Nonxline-Sol.40,453(80)] disorder/amorphous-superconductivity in nano-powders mechanical bulk/shear(?)-moduli/hardness: proton-irradiated diamond, powders TiB2, TiC,{Siegel[Semis. & Insuls.5:39,47, 62 (79)])-...``VS''/concommitance with Siegel[Phys.Stat.Sol.(a)11,45(72)]-Dempsey [Phil.Mag. 8,86,285(63)]-Overhauser-(Little!!!)-Seitz-Smith-Zeller-Dreschoff-Antonoff-Young-...proton-``irradiated''/ implanted/ thermalized-in-(optimal: BOTH heat-capacity/heat-sink & insulator/maximal dielectric-constant) diamond: ``VS'' ``hambergite-borate-mineral transformable to Overhauser optimal-high-Tc-LiBD2 in Overhauser-(NW-periodic-table)-Land: CO2/CH4-ETERNAL-sequestration by-product: WATER!!!: physics lessons from

A study on the development of high-Tc superconducting wire

International Nuclear Information System (INIS)

Won, Dong Yeon; Chang, In Soon; Lee, Jong Min; Um, Tae Yoon; Hong, Kyae Won; Lee, Ho Jin; Lee, Hee Kwun; Kim, Chan Joong; Park, Soon Dong; Kim, Woo Gon; Kim, Ki Baek; Kwon, Sun Chil

1992-10-01

On this study Y-Ba-Cu-O was prepared by partial melt process and superconducting wire was fabricated by powder-in-tube method. First, mechancial properties, electrical properties, microstructure and oxygen diffusion behavior were observed. Second, through fabricated superconducting wire, conceptual design, composition and plasticity of filament superconducting wire were investigated. (Author)

Microwave effective surface impedance of structures including a high-Tc superconducting film

International Nuclear Information System (INIS)

Hartemann, P.

1992-01-01

The microwave effective surface impedances of different stacks made of high-temperature superconducting films, dielectric materials and bulk normal metals were computed. The calculations were based on the two-fluid model of superconductors and the conventional transmission line theory. These effective impedances are compared to the calculated intrinsic surface impedances of the stacked superconducting films. The considered superconducting material has been the oxide YBa 2 Cu 3 O 7 epitaxially grown on crystalline substrates (MgO, LaAlO 3 , SrTiO 3 ), the film thickness ranging from a few nm to 1μm. Discrepancies between the effective surface resistances or reactances and the corresponding intrinsic values were determined at 10 GHz for non resonant or resonant structures. At resonance the surface resistance discrepancy exhibits a sharp peak which reaches 10 4 or more in relative value according to the geometry and the used materials. Obviously the effective surface reactance shows also huge variations about the resonance and may be negative. Moreover geometries allowing to obtain an effective resistance smaller than the film intrinsic value have been found. The effects of the resonance phenomenon on the electromagnetic wave reflectivity and reflection phase shift are investigated. Therefore the reported theoretical results demonstrate that the effective surface impedance of YBCO films with a thickness smaller than 500 nm can be very different from the intrinsic film impedance according to the structures. (Author). 3 refs., 10 figs., 2 tabs

Superconductivity of high Tc Scientific revolution?

International Nuclear Information System (INIS)

Marquina, J.E.; Ridaura, R.; Gomez, R.; Marquina, V.; Alvarez, J.L.

1997-01-01

A short history of superconductivity, since its discovery by Bednorz and Muller to the development of new materials with high transition temperatures, is presented. Further evolvements are analyzed in terms of T.s. Kuhn conceptions expressed in his book. The Structure of Scientific Revolutions. (Author) 4 refs

Electrical Transport Through Tunnel Barriers and Thin Dielectric Layers and Physical Properties of the High Tc Oxide Superconductors

Science.gov (United States)

1990-03-26

Josephson Tipo Emparedado con Barrera de (Nb-Si)-Amorto," PhD. Thesis, Universidad Nacional Autonoma de Mexico, May 1989. 17. E.S. Hellman, D.G...A15 Nb-Sn," Phys. Rev. B 30, p. 2590 (1984). 4. S.J. Bending, R.H. Hammond, and M.R. Beasley, "Superconductivity in the High-Tc A15 V-6a System," Bull

Superconductivity in nanostructured lead

Science.gov (United States)

Lungu, Anca; Bleiweiss, Michael; Amirzadeh, Jafar; Saygi, Salih; Dimofte, Andreea; Yin, Ming; Iqbal, Zafar; Datta, Timir

2001-01-01

Three-dimensional nanoscale structures of lead were fabricated by electrodeposition of pure lead into artificial porous opal. The size of the metallic regions was comparable to the superconducting coherence length of bulk lead. Tc as high as 7.36 K was observed, also d Tc/d H was 2.7 times smaller than in bulk lead. Many of the characteristics of these differ from bulk lead, a type I superconductor. Irreversibility line and magnetic relaxation rates ( S) were also studied. S( T) displayed two maxima, with a peak value about 10 times smaller than that of typical high- Tc superconductors.

A study on the development of high Tc superconducting materials

International Nuclear Information System (INIS)

Won, D. Y.; Hong, G. Y.; Lee, H. G.; Lee, H. J.; Kim, C. J.; Kwon, S. C.; Kim, K. B.; Kang, Y. H.; Chang, I. S.; Choi, M. J.

1992-01-01

The major work of this project aims to develop the frictionless superconducting bearing with a high speed. The high magnetization YBaCuO bulk superconductor was prepared by Quasi-melt process. The frictionless superconducting magnetic bearing standed a rotating bar with a speed of 75,000 rpm, which were operated by an electric controller. The low temperature chemical vapor deposition technique was developed. YBaCuO superconducting film showing a superconductivity above 77K was successfully prepared at 650 deg C. Effect of oxygen partial pressure, substrate, deposition temperature on the film properties were also investigated. (Author)

Possible universal cause of high-Tc superconductivity in different metals

International Nuclear Information System (INIS)

Amusia, M.Ya.; Shaginyan, V.R.

2002-01-01

Using the theory of the high temperature superconductivity based on the idea of the fermion condensation quantum phase transition (FCQPT) it is shown that neither the d-wave pairing symmetry, nor the pseudogap phenomenon, nor the presence of the Cu-O 2 planes are of decisive importance for the existence of the high-T c superconductivity. The analysis of recent experimental data on this type of superconductivity in different materials is carried out. It is shown that these facts can be understood within the theory of superconductivity based on the FCQPT. The main features of a room-temperature superconductor are discussed [ru

Modal bifurcation in a high-Tc superconducting levitation system

International Nuclear Information System (INIS)

Taguchi, D; Fujiwara, S; Sugiura, T

2011-01-01

This paper deals with modal bifurcation of a multi-degree-of-freedom high-T c superconducting levitation system. As modeling of large-scale high-T c superconducting levitation applications, where plural superconducting bulks are often used, it can be helpful to consider a system constituting of multiple oscillators magnetically coupled with each other. This paper investigates nonlinear dynamics of two permanent magnets levitated above high-T c superconducting bulks and placed between two fixed permanent magnets without contact. First, the nonlinear equations of motion of the levitated magnets were derived. Then the method of averaging was applied to them. It can be found from the obtained solutions that this nonlinear two degree-of-freedom system can have two asymmetric modes, in addition to a symmetric mode and an antisymmetric mode both of which also exist in the linearized system. One of the backbone curves in the frequency response shows a modal bifurcation where the two stable asymmetric modes mentioned above appear with destabilization of the antisymmetric mode, thus leading to modal localization. These analytical predictions have been confirmed in our numerical analysis and experiments of free vibration and forced vibration. These results, never predicted by linear analysis, can be important for application of high-T c superconducting levitation systems.

2005 annual report of MEXT specially promoted research, 'Development of the 4D Space Access Neutron Spectrometer (4SEASONS) and elucidation of the Mechanism of Oxide High-Tc superconductivity'

International Nuclear Information System (INIS)

Arai, Masatoshi; Kajimoto, Ryoichi; Nakajima, Kenji; Shamoto, Shin'ichi; Soyama, Kazuhiko; Nakamura, Mitsutaka; Aizawa, Kazuya; Asaoka, Hidehito; Kodama, Katsuaki; Inamura, Yasuhiro; Imai, Yoshinori; Yokoo, Tetsuya; Ino, Takashi; Yamada, Kazuyoshi; Fujita, Masaki; Ohoyama, Kenji; Hiraka, Haruhiro

2006-11-01

A research project entitled 'Development of the 4D Space Access Neutron Spectrometer (4SEASONS) and Elucidation of the Mechanism of Oxide High-T c Superconductivity' has started in 2005 (repr. by M. Arai). It is supported by MEXT, Grant-in-Aid for Specially Promoted Research and is going to last until fiscal 2009. The goal of the project is to elucidate the mechanism of oxide high-T c superconductivity by neutron scattering technique. For this purpose, we will develop an inelastic neutron scattering instrument 4SEASONS (4d SpacE AccesS neutrON Spectrometer) for the spallation neutron source in Japan Proton Accelerator Research Complex (J-PARC). The instrument will have 100 times higher performance than existing world-class instruments, and will enable detailed observation of anomalous magnetic excitations and phonons in a four-dimensional momentum-energy space. This report summarizes the progress in the research project in fiscal 2005. (author)

Fracton pairing mechanism for unconventional superconductors: Self-assembling organic polymers and copper-oxide compounds

DEFF Research Database (Denmark)

Milovanov, A.V.; Juul Rasmussen, J.

2002-01-01

Self-assembling organic polymers and copper-oxide compounds are two classes of unconventional superconductors, whose challenging behavior does not comply with the traditional picture of Bardeen-Cooper-Schrieffer (BCS) superconductivity in regular crystals. In this paper, we propose a theoretical...... or holes) exchange fracton excitations, quantum oscillations of fractal lattices that mimic the complex microscopic organization of the unconventional superconductors. For the copper oxides, the superconducting transition temperature T-c as predicted by the fracton mechanism is of the order of similar to......150 K. We suggest that the marginal ingredient of the high-temperature superconducting phase is provided by fracton coupled holes that condensate in the conducting copper-oxygen planes owing to the intrinsic field-effect-transistor configuration of the cuprate compounds. For the gate...

Hyperfine interactions in iron substituted high-Tc superconducting oxides

International Nuclear Information System (INIS)

Ellis, D.E.; Saitovitch, E.B.; Lam, D.J.

1991-01-01

The hyperfine interactions in Fe substituted copper oxide ternary and quaternary compounds with perovskite-related structures are studied, using the Local Density theory in an embedded cluster approach. The self-consistent electronic structure is examined for Cu and Fe sites in a number of plausible local geometries representative of La 2 Cu O 4 , YBa 2 Cu 3 O 7-δ and related materials. Moessbauer isomer shifts, electric fields gradients, magnetic moments, and contact hyperfine fields are presented for comparison with experiment and discussed in light of lattice structure data. (author)

On the electronegativity of the high-Tc oxide superconductor

International Nuclear Information System (INIS)

Zhang Liyuan.

1991-08-01

We employ a very useful quantity, the electronegativity, to classify the superconductor. The value of the group average electronegativity to separate superconductor into two categories is 2. Each category has unique chemical bond features. The high-T c oxide superconductor belongs to the second category with group average electronegativity being larger than 2. Their unusual bond nature also gives new insight into some essential factors beneficial to enhance superconductivity. (author). 9 refs, 2 tabs

A high Tc superconducting liquid nitrogen level sensor

International Nuclear Information System (INIS)

Jin, J. X.; Liu, H. K.; Dou, S. X.; Grantham, C.; Beer, J.

1996-01-01

Full text: The dramatic resistance change in the superconducting-normal transition temperature range enables a high T c superconductor to be considered for designing a liquid nitrogen level sensor. A (Bi,Pb) 2 Sr 2 Ca 2 Cu 3 O 10+x Ag clad superconducting wire is selected and tested as a continuous liquid nitrogen level sensor to investigate the possibility for this application. The (Bi,Pb) 2 Sr 2 Ca 2 Cu 3 O 10+x Ag clad superconducting wire has approximately 110 K critical temperature, with more flexible and stable properties compared with bulk shape ceramic high T c superconductors. The voltage drops across the sensor are tested with different immersion lengths in liquid nitrogen. The accuracy of the HTS sensor is analysed with its dR/dT in the superconducting-normal transition range. The voltage signal is sensitive to liquid nitrogen level change, and this signal can be optimized by controlling the transport current. The problems of the Ag clad superconductor are that the Ag sheath thermal conductivity is very high, and the sensor normal resistance is low. These are the main disadvantages for using such a wire as a continuous level sensor. However, a satisfactory accuracy can be achieved by control of the transport current. A different configuration of the wire sensor is also designed to avoid this thermal influence

Electrochemical investigations of high-Tc superconductors - low-temperature electrochemistry

International Nuclear Information System (INIS)

Lorenz, W.J.

1992-01-01

This research report presents a summary of results obtained by electrochemical investigations of high-Tc superconductors at room temperature and below the critical temperature (Tc). The studies were to reveal the behaviour of the ceramic superconducting materials at the interface between superconductor and ionic conductor. (MM) With 4 tabs., 8 figs [de

A novel propulsion method for high-Tc superconducting maglev vehicle

International Nuclear Information System (INIS)

Ma Guangtong; Wang Jiasu; Wang Suyu; Liu Minxian; Jing Hua; Lu Yiyun; Lin Qunxu

2008-01-01

High-Tc superconducting (HTS) maglev is considered as a perfect transportation type because of its unique inherent stability. A direct current (DC) linear motor using the permanent magnet guideway (PMG) as the stator and the on-board coil as the rotor instead of the present inductive or synchronous alternate current (AC) linear motor which has an economic disadvantage due to the necessity to lay primary coil along the guideway is proposed in this paper. In order to modulate the magnetic field under the PMG, an inverse E shape ferromagnetic device (IESFD) core is designed. The possible winding method for the on-board coil is listed, and the analytical result shows that a considerable net ampere force and thus the propulsion force can be generated by this special structure. The influence of the concentrated effect of the IESFD on the maglev performance of HTS bulk is studied by a numerical program, and the results show that the levitation force with the IESFD is 90% of that without. It is also indicated that the load capability and lateral performance of the maglev vehicle combined this propulsion method can be improved thanks to the attractive effect between the IESFD and PMG. The cost of the HTS maglev vehicle will be remarkably reduced and then shorten the distance to practical application with this propulsion method

A novel propulsion method for high- Tc superconducting maglev vehicle

Science.gov (United States)

Ma, Guangtong; Wang, Jiasu; Wang, Suyu; Liu, Minxian; Jing, Hua; Lu, Yiyun; Lin, Qunxu

2008-01-01

High-Tc superconducting (HTS) maglev is considered as a perfect transportation type because of its unique inherent stability. A direct current (DC) linear motor using the permanent magnet guideway (PMG) as the stator and the on-board coil as the rotor instead of the present inductive or synchronous alternate current (AC) linear motor which has an economic disadvantage due to the necessity to lay primary coil along the guideway is proposed in this paper. In order to modulate the magnetic field under the PMG, an inverse E shape ferromagnetic device (IESFD) core is designed. The possible winding method for the on-board coil is listed, and the analytical result shows that a considerable net ampere force and thus the propulsion force can be generated by this special structure. The influence of the concentrated effect of the IESFD on the maglev performance of HTS bulk is studied by a numerical program, and the results show that the levitation force with the IESFD is 90% of that without. It is also indicated that the load capability and lateral performance of the maglev vehicle combined this propulsion method can be improved thanks to the attractive effect between the IESFD and PMG. The cost of the HTS maglev vehicle will be remarkably reduced and then shorten the distance to practical application with this propulsion method.

Superconductivity versus quantum criticality: Effects of thermal fluctuations

Science.gov (United States)

Wang, Huajia; Wang, Yuxuan; Torroba, Gonzalo

2018-02-01

We study the interplay between superconductivity and non-Fermi liquid behavior of a Fermi surface coupled to a massless SU(N ) matrix boson near the quantum critical point. The presence of thermal infrared singularities in both the fermionic self-energy and the gap equation invalidates the Eliashberg approximation, and makes the quantum-critical pairing problem qualitatively different from that at zero temperature. Taking the large N limit, we solve the gap equation beyond the Eliashberg approximation, and obtain the superconducting temperature Tc as a function of N . Our results show an anomalous scaling between the zero-temperature gap and Tc. For N greater than a critical value, we find that Tc vanishes with a Berezinskii-Kosterlitz-Thouless scaling behavior, and the system retains non-Fermi liquid behavior down to zero temperature. This confirms and extends previous renormalization-group analyses done at T =0 , and provides a controlled example of a naked quantum critical point. We discuss the crucial role of thermal fluctuations in relating our results with earlier work where superconductivity always develops due to the special role of the first Matsubara frequency.

Direct observation of competition between superconductivity and charge density wave order in YBa2Cu3O6.67

DEFF Research Database (Denmark)

Chang, J.; Blackburn, E.; Holmes, A. T.

2012-01-01

Superconductivity often emerges in the proximity of, or in competition with, symmetry-breaking ground states such as antiferromagnetism or charge density waves (CDW). A number of materials in the cuprate family, which includes the high transition-temperature (high-Tc) superconductors, show spin...... and charge density wave order. Thus a fundamental question is to what extent do these ordered states exist for compositions close to optimal for superconductivity. Here we use high-energy X-ray diffraction to show that a CDW develops at zero field in the normal state of superconducting YBa2Cu3O6.67 (Tc= 67 K......). This sample has a hole doping of 0.12 per copper and a well-ordered oxygen chain superstructure. Below Tc, the application of a magnetic field suppresses superconductivity and enhances the CDW. Hence, the CDW and superconductivity in this typical high-Tc material are competing orders with similar energy...

Superconductivity mediated by quantum critical antiferromagnetic fluctuations: The rise and fall of hot spots

Science.gov (United States)

Wang, Xiaoyu; Schattner, Yoni; Berg, Erez; Fernandes, Rafael M.

2017-05-01

In several unconventional superconductors, the highest superconducting transition temperature Tc is found in a region of the phase diagram where the antiferromagnetic transition temperature extrapolates to zero, signaling a putative quantum critical point. The elucidation of the interplay between these two phenomena—high-Tc superconductivity and magnetic quantum criticality—remains an important piece of the complex puzzle of unconventional superconductivity. In this paper, we combine sign-problem-free quantum Monte Carlo simulations and field-theoretical analytical calculations to unveil the microscopic mechanism responsible for the superconducting instability of a general low-energy model, called the spin-fermion model. In this approach, low-energy electronic states interact with each other via the exchange of quantum critical magnetic fluctuations. We find that even in the regime of moderately strong interactions, both the superconducting transition temperature and the pairing susceptibility are governed not by the properties of the entire Fermi surface, but instead by the properties of small portions of the Fermi surface called hot spots. Moreover, Tc increases with increasing interaction strength, until it starts to saturate at the crossover from hot-spots-dominated to Fermi-surface-dominated pairing. Our work provides not only invaluable insights into the system parameters that most strongly affect Tc, but also important benchmarks to assess the origin of superconductivity in both microscopic models and actual materials.

Optically activated high Tc superconducting microbolometer

International Nuclear Information System (INIS)

Yefremenko, V; Gordiyenko, E; Shustakova, G; Bader, S D; Karapetrov, G; Novosad, V

2006-01-01

A laser beam, precisely focused on the patterned superconducting structure, was used to nucleate a resistive area that is sensitive to external thermal effects. The electron beam lithography and wet chemical etching were applied as pattern transfer processes in epitaxial Y-Ba-Cu-O films. Two different sensor designs were tested: (i) 3 millimeters long and 40 micrometers wide stripe and (ii) 1.25 millimeters long, and 50 micron wide meander -like structure. It is shown experimentally that scanning the laser beam along the stripe leads to physical displacement of the sensitive area and, therefore may be used as a basis for imaging over a broad spectral range. For example, patterning the superconducting film into a meander structure is equivalent to a two-dimensional detector array. In additional to the simplicity of the detector fabrication sequence (one step mask transfer), a clear advantage of this approach is the simplicity of the read-out process: an image is formed by registering the signal with only two electrical terminals. The proposed approach can be extended for imaging over a wide spectral range

High-Tc superconductor applications

International Nuclear Information System (INIS)

Anon.

1988-01-01

There has been much speculation about new products and business opportunities which high-Tc superconductors might make possible. However, with the exception of one Japanese survey, there have not been any recognized forecasts suggesting a timeframe and relative economic impact for proposed high-Tc products. The purpose of this survey is to provide definitive projections of the timetable for high-Tc product development, based on the combined forecasts of the leading U.S. superconductivity experts. The FTS panel of experts on high-Tc superconductor applications, representing both business and research, forecast the commercialization and economic impact for 28 classes of electronic, magnetic, communications, instrumentation, transportation, industrial, and power generation products. In most cases, forecasts predict the occurrence of developments within a 90% statistical confidence limit of 2-to-3 years. The report provides background information on the 28 application areas, as well as other information useful for strategic planners. The panel also forecast high-Tc research spending, markets, and international competitiveness, and provide insight into how the industry will evolve

Noise and conversion performance of a high-Tc superconducting Josephson junction mixer at 0.6 THz

Science.gov (United States)

Gao, Xiang; Du, Jia; Zhang, Ting; Guo, Yingjie Jay

2017-11-01

This letter presents both theoretical and experimental investigations on the noise and conversion performance of a high-Tc superconducting (HTS) step-edge Josephson-junction mixer at the frequency of 0.6 THz and operating temperatures of 20-40 K. Based on the Y-factor and U-factor methods, a double-sideband noise temperature of around 1000 K and a conversion gain of -3.5 dB were experimentally obtained at 20 K. At the temperature of 40 K, the measured mixer noise and conversion efficiency are around 2100 K and -10 dB, respectively. The experimental data are in good agreement with the numerical analysis results using the three-port model. A detailed performance comparison with other reported HTS terahertz mixers has confirmed the superior performance of our presented mixer device.

Theoretical analyses of superconductivity in iron based ...

African Journals Online (AJOL)

This paper focuses on the theoretical analysis of superconductivity in iron based superconductor Ba1−xKxFe2As2. After reviewing the current findings on this system, we suggest that phononexciton combined mechanism gives a right order of superconducting transition temperature (TC) for Ba1−xKxFe2As2 . By developing ...

Superconducting critical temperature under pressure

Science.gov (United States)

González-Pedreros, G. I.; Baquero, R.

2018-05-01

The present record on the critical temperature of a superconductor is held by sulfur hydride (approx. 200 K) under very high pressure (approx. 56 GPa.). As a consequence, the dependence of the superconducting critical temperature on pressure became a subject of great interest and a high number of papers on of different aspects of this subject have been published in the scientific literature since. In this paper, we calculate the superconducting critical temperature as a function of pressure, Tc(P), by a simple method. Our method is based on the functional derivative of the critical temperature with the Eliashberg function, δTc(P)/δα2F(ω). We obtain the needed coulomb electron-electron repulsion parameter, μ*(P) at each pressure in a consistent way by fitting it to the corresponding Tc using the linearized Migdal-Eliashberg equation. This method requires as input the knowledge of Tc at the starting pressure only. It applies to superconductors for which the Migdal-Eliashberg equations hold. We study Al and β - Sn two weak-coupling low-Tc superconductors and Nb, the strong coupling element with the highest critical temperature. For Al, our results for Tc(P) show an excellent agreement with the calculations of Profeta et al. which are known to agree well with experiment. For β - Sn and Nb, we found a good agreement with the experimental measurements reported in several works. This method has also been applied successfully to PdH elsewhere. Our method is simple, computationally light and gives very accurate results.

Inelastic electron scattering influence on the strong coupling oxide superconductors

International Nuclear Information System (INIS)

Gabovich, A.M.; Voitenko, A.I.

1995-01-01

The superconducting order parameters Δ and energy gap Δ g are calculated taking into account the pair-breaking inelastic quasiparticle scattering by thermal Bose-excitations, e.g., phonons. The treatment is self-consistent because the scattering amplitude depends on Δ. The superconducting transition for any strength of the inelastic scattering is the phase transition of the first kind and the dependences Δ (T) and Δ g (T) tend to rectangular curve that agrees well with the experiment for high-Tc oxides. On the basis of the developed theory the nuclear spin-lattice relaxation rate R s in the superconducting state is calculated. The Hebel-Slichter peak in R s (T) is shown to disappear for strong enough inelastic scattering

Variable temperature superconducting microscope

Science.gov (United States)

Cheng, Bo; Yeh, W. J.

2000-03-01

We have developed and tested a promising type of superconducting quantum interference device (SQUID) microscope, which can be used to detect vortex motion and can operate in magnetic fields over a large temperature range. The system utilizes a single-loop coupling transformer, consisting of a patterned high Tc superconducting thin film. At one end of the transformer, a 20 μm diam detecting loop is placed close to the sample. At the other end, a large loop is coupled to a NbTi coil, which is connected to a low Tc SQUID sensor. Transformers in a variety of sizes have been tested and calibrated. The results show that the system is capable of detecting the motion of a single vortex. We have used the microscope to study the behavior of moving vortices at various positions in a YBa2Cu3O7 thin film bridge.

Superconductivity and spin fluctuations

International Nuclear Information System (INIS)

Scalapino, D.J.

1999-01-01

The organizers of the Memorial Session for Herman Rietschel asked that the author review some of the history of the interplay of superconductivity and spin fluctuations. Initially, Berk and Schrieffer showed how paramagnon spin fluctuations could suppress superconductivity in nearly-ferromagnetic materials. Following this, Rietschel and various co-workers wrote a number of papers in which they investigated the role of spin fluctuations in reducing the Tc of various electron-phonon superconductors. Paramagnon spin fluctuations are also believed to provide the p-wave pairing mechanism responsible for the superfluid phases of 3 He. More recently, antiferromagnetic spin fluctuations have been proposed as the mechanism for d-wave pairing in the heavy-fermion superconductors and in some organic materials as well as possibly the high-Tc cuprates. Here the author will review some of this early history and discuss some of the things he has learned more recently from numerical simulations

Spin-polarons and high-Tc superconductivity

International Nuclear Information System (INIS)

Wood, R.F.

1994-03-01

The spin-polaron concept is introduced in analogy to ionic and electronic polarons and the assumptions underlying the author's approach to spin-polaron mediated high-T c superconductivity are discussed. Elementary considerations about the spin-polaron formation energy are reviewed and the possible origin of the pairing mechanism illustrated schematically. The electronic structure of the CuO 2 planes is treated from the standpoint of antiferromagnetic band calculations that lead directly to the picture of holes predominantly on the oxygen sublattice in a Mott-Hubbard/charge transfer insulator. Assuming the holes to be described in a Bloch representation but with the effective mass renormalized by spin-polaron formation, equations for the superconducting gap, Δ, and transition temperature, T c , are developed and the symmetry of Δ discussed. After further simplifications, T c is calculated as a function of the carrier concentration, x. It is shown that the calculated behavior of T c (x) follows the experimental results closely and leads to a natural explanation of the effects of under- and over-doping. The paper concludes with a few remarks about the evidence for the carriers being fermions (polarons) or bosons (bipolarons)

Feshbach shape resonance for high Tc pairing in superlattices of quantum stripes and quantum wells

Directory of Open Access Journals (Sweden)

A Bianconi

2006-09-01

Full Text Available   The Feshbach shape resonances in the interband pairing in superconducting superlattices of quantum wells or quantum stripes is shown to provide the mechanism for high Tc superconductivity. This mechanism provides the Tc amplification driven by the architecture of material: superlattices of quantum wells (intercalated graphite or diborides and superlattices of quantum stripes (doped high Tc cuprate perovskites where the chemical potential is tuned to a Van Hove-Lifshitz singularity (vHs in the electronic energy spectrum of the superlattice associated with the change of the Fermi surface dimensionality in one of the subbands.

High-Tc superconductivity of Tl-Ba-Ca-Cu-O samples

International Nuclear Information System (INIS)

Porjesz, T.; Kirschner, I.; Kovacs, G.

1988-08-01

A TlBaCaCuO 4.5+x compound has been investigated from the point of view of superconductivity. Depending on the heat treatment, one part of the sample exhibits superconductivity with an onset of 121 K and zero resistivity of 106 K and the other part of them shows a sharp drop in resistivity at 130 K which hints at an existence of superconducting grains. This picture was confirmed by magnetic and ESR measurements giving possibility for estimation of critical magnetic fields. (author). 5 refs, 6 figs

Soil-to-plant transfer of 99mTc: how to determine Tc-species in uptake and transport processes?

International Nuclear Information System (INIS)

Krijger, G. C.; Van Elswijk, D. A.; Wolterbeek, H. Th.

1995-01-01

Selective extraction, filtration and capillary electrophoresis were used to recognize problems dealing with complexation, oxidation and ligand-exchange processes during collection and analysis of Tc-species in xylem exudates, while 99m Tc-citrate was used as a marker complex. Relatively unstable Tc-species were synthesized in xylem exudates. Oxidation of relative unstable Tc-species during the collection of xylem exudates was suggested, requiring new, better procedures to recognize Tc-species representative for the plant interior. (author)

Electrochemistry of high-tc superconductors

International Nuclear Information System (INIS)

Petrij, O.A.; Tsirlina, G.A.

1993-01-01

The review deals with the problems of formation of a new section in modern electrochemistry related to various electrochemical aspects of high-temperature superconductivity. Specific properties of multicomponent oxides as electrode materials are pointed out. The data of experimental works on the study of degradation of superconducting ceramics, electroanalysis of complex oxide systems, electric deposition of metals and polymer films upon them are described. Special attention is paid to electrochemical approaches to electrosynthesis of films, possessing high-temperature superconductivity

Carbon-based superconductors towards high-Tc superconductivity

CERN Document Server

Haruyama, Junji

2014-01-01

Introduction of Condensed Matter Physics; Spin-state Crossover; Li Ion Battery; Huge Thermoelectric Power; Room-temperature Ferromagnetism; Partially Disordered Antiferromagnetic Transition; Superconductivity; Transport Properties Combined with Charge, Spin, and Orbital; Magnetoresistance and Spin Blocade; Intrinsic Inhomogeneity; Move/diffuse and Charge/discharge Effect.

High-temperature superconductivity

International Nuclear Information System (INIS)

Ginzburg, V.L.

1987-07-01

After a short account of the history of experimental studies on superconductivity, the microscopic theory of superconductivity, the calculation of the control temperature and its possible maximum value are presented. An explanation of the mechanism of superconductivity in recently discovered superconducting metal oxide ceramics and the perspectives for the realization of new high-temperature superconducting materials are discussed. 56 refs, 2 figs, 3 tabs

Superconductivity in SnO: a nonmagnetic analog to Fe-based superconductors?

Science.gov (United States)

Forthaus, M K; Sengupta, K; Heyer, O; Christensen, N E; Svane, A; Syassen, K; Khomskii, D I; Lorenz, T; Abd-Elmeguid, M M

2010-10-08

We discovered that under pressure SnO with α-PbO structure, the same structure as in many Fe-based superconductors, e.g., β-FeSe, undergoes a transition to a superconducting state for p≳6 GPa with a maximum Tc of 1.4 K at p=9.3 GPa. The pressure dependence of Tc reveals a domelike shape and superconductivity disappears for p≳16 GPa. It is further shown from band structure calculations that SnO under pressure exhibits a Fermi surface topology similar to that reported for some Fe-based superconductors and that the nesting between the hole and electron pockets correlates with the change of Tc as a function of pressure.

Superconductivity in SnO: A Nonmagnetic Analog to Fe-Based Superconductors?

DEFF Research Database (Denmark)

Forthaus, M. K.; Sengupta, K.; Heyer, O.

2010-01-01

We discovered that under pressure SnO with α-PbO structure, the same structure as in many Fe-based superconductors, e.g., β-FeSe, undergoes a transition to a superconducting state for p≳6  GPa with a maximum Tc of 1.4 K at p=9.3  GPa. The pressure dependence of Tc reveals a domelike shape...... and superconductivity disappears for p≳16  GPa. It is further shown from band structure calculations that SnO under pressure exhibits a Fermi surface topology similar to that reported for some Fe-based superconductors and that the nesting between the hole and electron pockets correlates with the change of Tc...

Quantification of oxygen and carbon in high Tc superconducting films by (α,α) elastic resonance technique

International Nuclear Information System (INIS)

Vizkelethy, G.; Revesz, P.

1993-01-01

The quantification of oxygen and carbon in high-temperature (T c ) superconducting oxide thin films was made by employing elastic resonance in He backscattering analysis. A method combining the oxygen resonance technique and channeling was presented for measuring the nature of the oxygen disorder near the surface and the interface in a YBCO superconducting film grown on an MgO substrate. The oxygen resonance technique was used to quantify the oxygen profiling in the metal/YBCO contacts, showing that Zr and Nb act as sinks to oxygen from YBCO films and are oxidized in the forms Zr/ZrO 2 /YBCO/MgO and Nb 0.2 O/YBCO/MgO after annealing in a vacuum at 350 o C. We combined the carbon and oxygen resonances to determine the carbon contamination and oxygen concentration changes on the YBCO surface after coating and baking the photoresist. Residual carbon on the surface and a thin layer of oxygen depletion near the YBCO surface have been observed. The residual carbon in Bi 2 Sr 2 CaCu 2 O 8 films made by the decomposition of metallo-organic precursors was quantified using carbon resonance. (author)

High-Tc copper oxide superconductors and related novel materials dedicated to prof K. A. Müller on the occasion of his 90th birthday

CERN Document Server

Keller, Hugo; Bianconi, Antonio

2017-01-01

Authored by many of the world's leading experts on high-Tc superconductivity, this volume presents a panorama of ongoing research in the field, as well as insights into related multifunctional materials. The contributions cover many different and complementary aspects of the physics and materials challenges, with an emphasis on superconducting materials that have emerged since the discovery of the cuprate superconductors, for example pnictides, MgB2, H2S and other hydrides. Special attention is also paid to interface superconductivity. In addition to superconductors, the volume also addresses materials related to polar and multifunctional ground states, another class of materials that owes its discovery to Prof. Müller's ground-breaking research on SrTiO3.

Full-switching FSF-type superconducting spin-triplet magnetic random access memory element

Science.gov (United States)

Lenk, D.; Morari, R.; Zdravkov, V. I.; Ullrich, A.; Khaydukov, Yu.; Obermeier, G.; Müller, C.; Sidorenko, A. S.; von Nidda, H.-A. Krug; Horn, S.; Tagirov, L. R.; Tidecks, R.

2017-11-01

In the present work a superconducting Co/CoOx/Cu41Ni59 /Nb/Cu41Ni59 nanoscale thin film heterostructure is investigated, which exhibits a superconducting transition temperature, Tc, depending on the history of magnetic field applied parallel to the film plane. In more detail, around zero applied field, Tc is lower when the field is changed from negative to positive polarity (with respect to the cooling field), compared to the opposite case. We interpret this finding as the result of the generation of the odd-in-frequency triplet component of superconductivity arising at noncollinear orientation of the magnetizations in the Cu41Ni59 layer adjacent to the CoOx layer. This interpretation is supported by superconducting quantum interference device magnetometry, which revealed a correlation between details of the magnetic structure and the observed superconducting spin-valve effects. Readout of information is possible at zero applied field and, thus, no permanent field is required to stabilize both states. Consequently, this system represents a superconducting magnetic random access memory element for superconducting electronics. By applying increased transport currents, the system can be driven to the full switching mode between the completely superconducting and the normal state.

Superconductivity in Mesocrystalline Inverse Opal Structures

Science.gov (United States)

Lungu, Anca; Bleiweiss, Michael; Saygi, Salih; Amirzadeh, Jafar; Datta, Timir

2000-03-01

Mesocrystalline inverse opal structures were fabricated by the electrodeposition of metallic lead in synthetic opals. In these structures, the superconducting regions percolate in all directions through the voids in the artificial opals and their size is comparable to the coherence length for bulk lead. The inverse lead opals were proven superconducting, with a transition temperature close to that of bulk lead (between 7.2 K and 7.36 K) and broad transition regions. The magnetic behavior of the inverse opals was very different from that of bulk lead. Due to the reduced dimensonality of the superconducting regions, not surprisingly, the magnetic properties of our samples were found to be similar to those of type II superconductors. The critical magnetic field (or the field at which T_copals was proven at least two times larger than that for bulk lead and (dT_c/dH) was observed 2.7 times smaller. We found a reversible ZFC-FC magnetic behavior in the temperature range between T* and T_c. We also performed magnetic relaxation measurements and studied the fluctuation diamagnetism above T_c.

A study on the development of high Tc superconducting materials

International Nuclear Information System (INIS)

Won, Dong Yeon; Lee, Hee Gyoun; Kim, Chan Joong

1990-01-01

The microstructure, crystal structure and formation kinetics for the superconducting phases were studied in the lead-doped BiSrCaCuO system. The formation kinetics was also investigated in the samples with different Pb/Bi ratio and it was observed that the 30 % Pb addition is most perferable for the formation of the high T c phase. The formation of the high T c phase was delayed by the excessive addition of Pb. The lattice parameter (c) of the unit cell of both low T c and high T c phases increased with increasing Pb content. Superconducting thin film was sucessfully prepared by chemical vapor deposition (CVD). Film deposited on MgO substrate showed a T c , onset of 85 K and did not reach to zero resistivity down to 77 K. Superconducting 124 phase in Y-system, which is more stable than 123 phase at high temperature showed a T c , onser of 84 K. Additionally, 0.1 mole of Pb, Sn and Ca was substituted for yttrium in 124 phase, respectively. For Pb and Sn-subsituted specimens, 124 phase was formed and for Ca substituted specimen, 124 phase was not formed and revealed no superconductivity down to 77 K. For Sn-substituted specimens, 124 phase was formed but showed no superconductivity down to 77 K. (author)

High {Tc} superconductivity: Symmetries and reflections

International Nuclear Information System (INIS)

Zhang, S.C.

1999-01-01

This is a talk given at the Symposium Symmetries and Reflections, dedicated to Prof. C.N. Yang's retirement. In this talk, the author reflects on his personal interaction with Prof. Yang since his graduate career at SUNY Stony Brook, and his profound impact on his understanding of theoretical physics. He also reviews the SO(5) theory of high T c superconductivity and shows how his collaboration with Prof. Yang in 1990 lead to the foundation of this idea

On the application of High-Tc superconductors in power coils and transformers

NARCIS (Netherlands)

Chevtchenko, O.A.

2002-01-01

In this study, the electro-magnetic properties of high-Tc tapes and coils are investigated. The focus is on Bi-2223/Ag tapes with non-twisted superconducting filaments as these are the only high-Tc superconductors at present available in sufficient length for practical applications. The study is

Low-temperature specific heat of the β-pyrochlore oxide superconductors under high pressure

Science.gov (United States)

Isono, T.; Iguchi, D.; Machida, Y.; Izawa, K.; Salce, B.; Flouquet, J.; Ogusu, H.; Yamaura, J.; Hiroi, Z.

2011-01-01

We report the results of the low-temperature specific heat measurements of the single crystalline β-pyrochlore oxide superconductors AOs 2O 6 (A=K, Rb, and Cs) under high pressure up to 13 GPa. We find that superconducting transition temperature ( Tc) monotonically increases for CsOs 2O 6 and RbOs 2O 6, while the one for KOs 2O 6 decreases by applying the pressure. With further increasing the pressure, Tc is suddenly suppressed at the same lattice volume for all compounds, concomitant with the first-order structural phase transition.

On the combination of the Cooper pair and the Ogg pair in the high-Tc oxide superconductor

International Nuclear Information System (INIS)

Zhang Liyuan.

1991-08-01

In this paper it is argued that the superconductivity of the high-T c oxide superconductor (HTOS) can be explained by the combinating mechanism of the Cooper pair and the Ogg pair. The properties of the superconducting state of the HTOS have been calculated under this mechanism, and the theoretical results are overall consistent with the experiment. (author). 37 refs

Influence of disorder on the superconducting critical temperature in indium-opal nanocomposites

Science.gov (United States)

Zakharchuk, I.; Januzaj, A.; Mikhailin, N. Yu.; Traito, K. B.; Chernyaev, A. V.; Romanov, S. G.; Safonchik, M.; Shamshur, D. V.; Lähderanta, E.

2018-06-01

Transport properties of bulk indium-opal and indium-porous glass superconducting nanocomposites possessing moderate and strong disorder are investigated. A strongly nonmonotonous dependence of the global critical temperature Tc versus normal state conductivity of samples is found. The maximum, which is observed at moderate disorder, has Tc higher than that of clean bulk indium. The increasing part can be explained by the Eliashberg equations with disorder and an additional mechanism of interaction between superconducting and dielectric granules. The descending part of the maximum at higher disorder can be explained by the increasing of long-range Coulomb repulsion due to diffusion of charges. Negative slope in magnetic field dependence of resistivity and a peak in the temperature dependence of resistivity, observed in the sample near the proximity to the disorder-induced superconductor-insulator transition (SIT). A large difference between the onset temperature of superconducting fluctuations, Tcon , and global critical temperature Tc is found and considered in the framework of the weak multifractal theory. Slow time-logarithmic relaxation of the resistivity between Tc and Tcon is observed, which assumes existence of the precursor state near the SIT. This unusual state is discussed in the scope of the many-body localization theory.

Second international Israeli conference on High Tc Superconductivity

International Nuclear Information System (INIS)

1993-01-01

The superconductivity fields covered in this conference are: theory, applications, devices, flux properties high frequencies, Josephson junctions, magnetism, material sciences and physical properties of superconductors, spectroscopy and resonances and thin films

Effective valence as the control parameter of the superconducting ...

African Journals Online (AJOL)

One approach to investigating the superconductivity in the ironbased materials is understanding the chemical and structural parameters that can be used to tune their remarkably high Tc. In this paper, we have demonstrated that the effective valence of iron can be used as the control parameter to tune the Tc of this family of ...

Synthesis, structure elucidation and redox properties of 99Tc complexes of lacunary Wells Dawson polyoxometalates: insights into molecular 99Tc - metal oxide interactions

International Nuclear Information System (INIS)

McGregor, Donna; Burton-Pye, Benjamin P.; Howell, Robertha C.; Mbomekalle, Israel M.; Lukens, Wayne W. Jr; Bian, Fang; Mausolf, Edward; Poineau, Frederic; Czerwinski, Kenneth R; Francesconi, Lynn C.

2011-01-01

The isotope 99 Tc (β max : 250 keV, half-life: 2 x 10 5 year) is an abundant product of uranium-235 fission in nuclear reactors and is present throughout the radioactive waste stored in underground tanks at Hanford and Savannah River. Understanding and controlling the extensive redox chemistry of 99 Tc is important to identify tunable strategies to separate 99 Tc from spent fuel and from waste tanks and once separated, to identify and develop an appropriately stable waste-form for 99 Tc. Polyoxometalates (POMs), nanometer sized models for metal oxide solid-state materials, are used in this study to provide a molecular level understanding of the speciation and redox chemistry of incorporated 99 Tc. In this study, 99 Tc complexes of the (α 2 -P 2 W 17 O 61 ) 10- and (α 1 -P 2 W 17 O 61 ) 10- isomers were prepared. Ethylene glycol was used as a 'transfer ligand' to minimize the formation of TcO 2 · xH 2 O. The solution structures, formulations, and purity of Tc V O(α 1 /α 2 -P 2 W 17 O 61 ) 7- were determined by multinuclear NMR. X-ray Absorption Spectroscopy of the complexes are in agreement with the formulation and structures determined from 31 P and 183 W NMR. Preliminary electrochemistry results are consistent with the EXAFS results, showing a facile reduction of the Tc V O(α 1 -P 2 W 17 O 61 ) 7- species compared to the Tc V O(α 2 -P 2 W 17 O 61 ) 7- analog. The α 1 -defect is unique in that a basic oxygen atom is positioned toward the α 1 -site and the Tc V O center appears to form a dative metal-metal bond with a framework W site. These attributes may lead to the assistance of protonation events that facilitate reduction. Electrochemistry comparison shows that the Re V analogs are about 200 mV more difficult to reduce in accordance with periodic trends.

Magnetic and Superconducting Materials at High Pressures

Energy Technology Data Exchange (ETDEWEB)

Struzhkin, Viktor V. [Carnegie Inst. of Washington, Washington, DC (United States)

2015-03-24

The work concentrates on few important tasks in enabling techniques for search of superconducting compressed hydrogen compounds and pure hydrogen, investigation of mechanisms of high-Tc superconductivity, and exploring new superconducting materials. Along that route we performed several challenging tasks, including discovery of new forms of polyhydrides of alkali metal Na at very high pressures. These experiments help us to establish the experimental environment that will provide important information on the high-pressure properties of hydrogen-rich compounds. Our recent progress in RIXS measurements opens a whole field of strongly correlated 3d materials. We have developed a systematic approach to measure major electronic parameters, like Hubbard energy U, and charge transfer energy Δ, as function of pressure. This technique will enable also RIXS studies of magnetic excitations in iridates and other 5d materials at the L edge, which attract a lot of interest recently. We have developed new magnetic sensing technique based on optically detected magnetic resonance from NV centers in diamond. The technique can be applied to study superconductivity in high-TC materials, to search for magnetic transitions in strongly correlated and itinerant magnetic materials under pressure. Summary of Project Activities; development of high-pressure experimentation platform for exploration of new potential superconductors, metal polyhydrides (including newly discovered alkali metal polyhydrides), and already known superconductors at the limit of static high-pressure techniques; investigation of special classes of superconducting compounds (high-Tc superconductors, new superconducting materials), that may provide new fundamental knowledge and may prove important for application as high-temperature/high-critical parameter superconductors; investigation of the pressure dependence of superconductivity and magnetic/phase transformations in 3d transition metal compounds, including

Characterization of the superconducting state in hafnium hydride under high pressure

Science.gov (United States)

Duda, A. M.; Szewczyk, K. A.; Jarosik, M. W.; Szcześniak, K. M.; Sowińska, M. A.; Szcześniak, D.

2018-05-01

The hydrogen-rich compounds at high pressure may exhibit notably high superconducting transition temperatures. In the paper, we have calculated the basic thermodynamic parameters of the superconducting state in two selected phases of HfH2 hydride under high-pressure respectively at 180 GPa for Cmma and 260 GPa for P21 / m . Calculations has been conducted in the framework of the Eliashberg formalism. In particular, we have determined the values of the critical temperature (TC) to be equal to 8 K and 13 K for the Cmma and P21 / m phases, respectively. Moreover, we have estimated other thermodynamic properties such as the order parameter (Δ (T)) , the thermodynamic critical field (HC (T)) , and the specific heat for the normal (CN) and superconducting (CS) state. Finally, we have shown that the characteristic ratios: RΔ = 2 Δ (0) /kBTC and RC = ΔC (TC) /CN (TC) , which are related to the above thermodynamic functions, slightly differ from the predictions of the Bardeen-Cooper-Schrieffer theory due to the strong-coupling and retardation effects.

Isotope effect on superconductivity and Raman phonons of Pyrochlore Cd2Re2O7

Science.gov (United States)

Razavi, F. S.; Hajialamdari, M.; Reedyk, M.; Kremer, R. K.

2018-06-01

Cd2Re2O7 is the only α-Pyrochlore exhibiting superconductivity with a transition temperature (Tc) of ∼ 1 K. In this study, we present the effect of oxygen isotope (18O) as well as combined 18O and cadmium isotope (116Cd) substitution on the superconductivity and Raman scattering spectrum of Cd2Re2O7. The change of Tc and the energy gap Δ(T) are reported using various techniques including point contact spectroscopy. The shift in Raman phonon frequencies upon isotope substitution will be compared with measurement of the isotope effect on the superconducting transition temperature.

Hole superconductivity

International Nuclear Information System (INIS)

Hirsch, J.E.; Marsiglio, F.

1989-01-01

The authors review recent work on a mechanism proposed to explain high T c superconductivity in oxides as well as superconductivity of conventional materials. It is based on pairing of hole carriers through their direct Coulomb interaction, and gives rise to superconductivity because of the momentum dependence of the repulsive interaction in the solid state environment. In the regime of parameters appropriate for high T c oxides this mechanism leads to characteristic signatures that should be experimentally verifiable. In the regime of conventional superconductors most of these signatures become unobservable, but the characteristic dependence of T c on band filling survives. New features discussed her include the demonstration that superconductivity can result from repulsive interactions even if the gap function does not change sign and the inclusion of a self-energy correction to the hole propagator that reduces the range of band filling where T c is not zero

Exafs studies of coprecipitation and adsorption reactions of Tc

Energy Technology Data Exchange (ETDEWEB)

Bunker, D.J.; Jones, M.J.; Livens, F.R.; Collison, D. [Manchester Univ. (United Kingdom). Dept. of Chemistry; Pattrick, R.A.D. [Manchester Univ., Dept. of Earth Sciences (United Kingdom); Charnock, J.M. [CLRC Daresbury Laboratoire, Warrington Cheshire (United Kingdom)

2000-07-01

Adsorption and coprecipitation reactions may be a simple way of removing [TcO{sub 4}]{sup -} from aqueous solution. The effectiveness of a range of potential adsorbents and precipitants has been evaluated and some are capable of near quantitative (>98%) removal of [TcO{sub 4}){sup -} from solution. X-ray absorption near edge structure (XANES) has been used to determine Tc oxidation states and extended X-ray absorption fine structure spectroscopy (EXAFS) has been used to identify the local environment of Tc. The absorption edge position has been determined, using [PPh{sub 4}][TcO{sub 4}], TcS{sub 2} and Tc{sub 2}S{sub 7} as model compounds, and is diagnostic of Tc oxidation state. In a series of experiments investigating FeS coprecipitation, Tc was reduced to oxidation state (IV) and its local environment resembled that in TcO{sub 2} (6 O atoms at approximately 2.0 Angstrom). (authors)

Processing of flexible high-Tc superconducting wires

International Nuclear Information System (INIS)

Lee, B.I.; Modi, V.

1989-01-01

Wires superconducting at temperatures above 77 K are produced by using YBa 2 Cu 3 O 7 materials. Flexibility was obtained by support from prefabricated fibers or a metallic coating on the extruded YBa 2 Cu 3 O 7 wires. The microstructure, the T c and the critical current densities of the wires were determined. Processing variables and steps are described

Improving superconducting properties of YBCO high temperature superconductor by Graphene Oxide doping

Energy Technology Data Exchange (ETDEWEB)

Dadras, S., E-mail: dadras@alzahra.ac.ir; Dehghani, S.; Davoudiniya, M.; Falahati, S.

2017-06-01

In this research, we report the synthesis and characterization of YBa{sub 2}Cu{sub 3}O{sub 7-δ} (YBCO) high temperature superconductor prepared by sol-gel method and doped with Graphene Oxide (GO) in different weight percentages, 0, 0.1, 0.7 and 1 % wt. The x-ray diffraction (XRD) analysis confirms the formation of orthorhombic phase of superconductivity for all the prepared samples. We found that GO doping reduces the crystalline size of the samples. We evaluated the effects of GO doping on the normal state resistivity (ρ), superconducting transition temperature (T{sub c}) and critical current density (J{sub c}). The results show that the GO doping has a positive effect on these properties. Also, the highest J{sub c} is obtained for the 0.7 %wt GO doped YBCO compound that its critical current density is about 15 times more than the J{sub c} of pure one in 0.4 T magnetic field. The scanning electron microscope (SEM) analysis shows that there are better connections between the grains of GO doped samples. - Highlights: • Graphene Oxide doping increased the YBCO critical current density. • Graphene Oxide creates a better connection between the YBCO grains. • The normal resistivity of samples were decreased by GO doping to YBCO compounds. • Graphene Oxide doping has a positive effect on the critical transition temperature.

The filled skutterudite PrOs4Sb12: superconductivity and correlations

International Nuclear Information System (INIS)

Measson, M.A.

2005-12-01

The filled skutterudite PrOs 4 Sb 12 is the first Pr-based heavy fermion superconductor. This thesis addresses several important open questions including the determination of the quasi-particle mass renormalisation, the nature and mechanism of superconductivity, and the intrinsic or extrinsic nature of the double superconducting transition seen in the specific heat. A fit of the specific heat with magnetic interactions between the ions Pr is proposed. We extract from it an electronic term of between 300-750 mJ/K 2 .mol(Pr). Analysis of the specific heat jump provides evidence that heavy carriers are involved in Cooper pairing and that superconductivity is strongly coupled. Extensive characterizations by specific heat, resistivity, susceptibility measurements show that a double transition appears in the best samples. Nevertheless we bring the first serious doubts on the intrinsic nature of the double transition, because we have found samples with a single sharp transition at Tc2 and because the ratio of the two specific heat jumps shows strong dispersion among the samples. Furthermore we have measured the superconducting phase diagrams with an A.C. specific heat technique under magnetic field and under pressure up to 4.2 GPa, and we show that the two transitions, Tc1 and Tc2, exhibit similar behaviours with magnetic field and pressure. We find a strong change in the pressure dependence of Tc's above 2 GPa which might be related to a change in the nature of the superconductivity under pressure (at least partially mediated by fluctuations and only by phonons at respectively low and high pressure) which may be linked to the increase of the crystal field gap of the Pr ions. Analysis of the upper critical field shows the presence of at least two superconducting bands and concludes to a singlet nature of the pairing. A strong distortion of the flux-line lattice, which is constant with temperature and field, is obtained by small angle neutron scattering measurement

Superconductivity in compensated and uncompensated semiconductors

Directory of Open Access Journals (Sweden)

Youichi Yanase and Naoyuki Yorozu

2008-01-01

Full Text Available We investigate the localization and superconductivity in heavily doped semiconductors. The crossover from the superconductivity in the host band to that in the impurity band is described on the basis of the disordered three-dimensional attractive Hubbard model for binary alloys. The microscopic inhomogeneity and the thermal superconducting fluctuation are taken into account using the self-consistent 1-loop order theory. The superconductor-insulator transition accompanies the crossover from the host band to the impurity band. We point out an enhancement of the critical temperature Tc around the crossover. Further localization of electron wave functions leads to the localization of Cooper pairs and induces the pseudogap. We find that both the doping compensation by additional donors and the carrier increase by additional acceptors suppress the superconductivity. A theoretical interpretation is proposed for the superconductivity in the boron-doped diamond, SiC, and Si.

A study on the effect of tantalum-impurity content on the superconducting properties of niobium materials used for making superconducting radio frequency cavities

Science.gov (United States)

Roy, S. B.; Sharath Chandra, L. S.; Chattopadhyay, M. K.; Tiwari, M. K.; Lodha, G. S.; Myneni, G. R.

2012-11-01

Niobium materials in highly pure form are used in the fabrication of superconducting radio frequency cavities. We present here a study of the superconducting properties of such niobium materials that have been used in the fabrication of high accelerating gradient superconducting radio frequency cavities after determining their tantalum-impurity contents using a synchrotron-based x-ray fluorescence spectroscopy technique. Our results show that there is a small change in superconducting parameters such as TC,HC1 and HC2 when the tantalum-impurity content varies from ≈150 to ≈1300 ppm. In contrast, a buffered chemical polishing of the same niobium samples changes all these superconducting parameters more significantly. The implications of these results on the performance of niobium superconducting radio frequency cavities are discussed.

Superconductivity of high Tc Scientific revolution?; Superconductividad de alta Tc una revolucion cientifica?

Energy Technology Data Exchange (ETDEWEB)

Marquina, J E; Ridaura, R; Gomez, R; Marquina, V; Alvarez, J L

1998-12-31

A short history of superconductivity, since its discovery by Bednorz and Muller to the development of new materials with high transition temperatures, is presented. Further evolvements are analyzed in terms of T.s. Kuhn conceptions expressed in his book. The Structure of Scientific Revolutions. (Author) 4 refs.

Effect of increasing disorder on superconductivity of Mo/Nb superlattices

Science.gov (United States)

Pereiro, Juan; Saerbeck, Thomas; Schuller, Ivan K.

2015-08-01

We investigated the superconducting properties of Nb/Mo superlattices (SLs). The structural changes as a function of Nb and Mo layer thickness allow us to investigate the effect of disorder on the superconducting properties in a controlled fashion. Systematic structural studies provide quantitative measures of disorder parameters, such as roughness, interdiffusion, and strain, which allow separating their effect on the individual superconducting layers. The Mo critical temperature does not change as the layer thickness decreases below its coherence length. Thus, the SL critical temperatures in the presence of disorder and proximity effects can be modeled by considering only the effects of the Nb mean free path and coherence length. With increasing layer thickness, the SL critical temperatures approach Nb bulk values. Contrary to expectations the Tc of Mo remains below the Nb Tc. We discuss the results using existing theories based on Coulomb repulsion or changes in the density of states at the Fermi surface as a function of disorder. Questions about current understanding of the effect of disorder on superconductivity arise from the results.

Fabrication and characterizations of high-Tc superconducting ceramic/polymer 0--3 composites

International Nuclear Information System (INIS)

Du, J.; Unsworth, J.

1994-01-01

High-T c superconducting ceramic YBa 2 Cu 3 O 7-x /thermosetting plastic 0--3 composites were fabricated. The structure, physical property, magnetic susceptibility, levitation, and mechanical strength of the composites were accessed. The influence of filler content on these properties was also studied. Although the 0--3 composites lack an electrical superconducting path through materials, the intrinsic diamagnetic properties were preserved. The magnetic superconducting transition temperature was not degraded. The values of magnetic susceptibility and levitation force for the composites were basically proportional to the actual volume fraction of superconducting filler. These new composite materials are most suitable for the applications in levitating vehicles and mechanical bearings

Quality criteria for high Tc superconductors and on the clarification of the superconducting mechanism

International Nuclear Information System (INIS)

Haase, E.L.; Ruzicka, J.

1992-03-01

After the successful basic solution of the Nb 3 Ge and Nb 3 Si problems, optimization strategies and quality criteria were developed for high Tc superconducting (HTCS) samples in analogy. After improvements of the sputtering system, the preparation parameters were tightly controlled, leading to samples with a reproducible linear slope of the specific resistance ρ(T). Further improvements by us and Poppe et al. lead to the preparation of 123 films with non-linear ρ(T) curves above 120K. A generalization to a T 2 behavior of ρ(T) leads to the further generalization that defect free HTCS are essentially two dimensional in nature, with all ensuing consequences. The momentum transport of the moving charge cariers requires, because of momentum conservation, a mechanism to transfer momentum to the lattice (momentum relaxation). The qualitative theory developed for two dimensional (2D) systems shows that the electron-phonon interaction is strongly suppressed and hence that the weaker electron-electron interaction dominates. That theory makes numerous predictions, which so far are confirmed by experiments. In particular, it accounts for the extreme temperature dependence of the mean free path and the Hall effect. It is inferred that the mechanism of HTCS is predominantly due to electron-electron interaction - probably of bipolaron nature, as indicated by experiment. At this point experiment meets just a few theories, that conform with the experimental facts and above theory, all based on the quasi-particle theory of electron-electron interaction. The theory of Newns, Pattnaik and Tsuei should have a T 2 shape of ρ(T) and, because E F lies near a nearly logarithmic van Hove singularity, accounts for the high Tc. Ruvalds and Virosztek's theory predicts the T 2 shape of ρ(T). (orig./GSCH)

Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs.

Science.gov (United States)

Khasanov, Rustem; Guguchia, Zurab; Eremin, Ilya; Luetkens, Hubertus; Amato, Alex; Biswas, Pabitra K; Rüegg, Christian; Susner, Michael A; Sefat, Athena S; Zhigadlo, Nikolai D; Morenzoni, Elvezio

2015-09-08

The recent discovery of pressure (p) induced superconductivity in the binary helimagnet CrAs has raised questions on how superconductivity emerges from the magnetic state and on the mechanism of the superconducting pairing. In the present work the suppression of magnetism and the occurrence of superconductivity in CrAs were studied by means of muon spin rotation. The magnetism remains bulk up to p ≃ 3.5 kbar while its volume fraction gradually decreases with increasing pressure until it vanishes at p ≃ 7 kbar. At 3.5 kbar superconductivity abruptly appears with its maximum Tc ≃ 1.2 K which decreases upon increasing the pressure. In the intermediate pressure region (3.5 magnetic volume fractions are spatially phase separated and compete for phase volume. Our results indicate that the less conductive magnetic phase provides additional carriers (doping) to the superconducting parts of the CrAs sample thus leading to an increase of the transition temperature (Tc) and of the superfluid density (ρs). A scaling of ρs with Tc(3.2) as well as the phase separation between magnetism and superconductivity point to a conventional mechanism of the Cooper-pairing in CrAs.

Impurity band Mott insulators: a new route to high Tc superconductivity

Directory of Open Access Journals (Sweden)

Ganapathy Baskaran

2008-01-01

Full Text Available Last century witnessed the birth of semiconductor electronics and nanotechnology. The physics behind these revolutionary developments is certain quantum mechanical behaviour of 'impurity state electrons' in crystalline 'band insulators', such as Si, Ge, GaAs and GaN, arising from intentionally added (doped impurities. The present article proposes that certain collective quantum behaviour of these impurity state electrons, arising from Coulomb repulsions, could lead to superconductivity in a parent band insulator, in a way not suspected before. Impurity band resonating valence bond theory of superconductivity in boron doped diamond, recently proposed by us, suggests possibility of superconductivity emerging from impurity band Mott insulators. We use certain key ideas and insights from the field of high-temperature superconductivity in cuprates and organics. Our suggestion also offers new possibilities in the field of semiconductor electronics and nanotechnology. The current level of sophistication in solid state technology and combinatorial materials science is very well capable of realizing our proposal and discover new superconductors.

James C. McGroddy Prize Talk: Superconductivity in alkali-metal doped Carbon-60

Science.gov (United States)

Hebard, Arthur

2008-03-01

Carbon sixty (C60), which was first identified in 1985 in laser desorption experiments, is unquestionably an arrestingly beautiful molecule. The high symmetry of the 12 pentagonal and 20 hexagonal faces symmetrically arrayed in a soccer-ball like structure invites special attention and continues to stimulate animated speculation. The availability in 1990 of macroscopic amounts of purified C60 derived from carbon-arc produced soot allowed the growth and characterization of both bulk and thin-film samples. Crystalline C60 is a molecular solid held together by weak van der Waals forces. The fcc structure has a 74% packing fraction thus allowing ample opportunity (26% available volume) for the intercalation of foreign atoms into the interstitial spaces of the three dimensional host. This opportunity catalyzed much of the collaborative work amongst chemists, physicists and materials scientists at Bell Laboratories, and resulted in the discovery of superconductivity in alkali-metal doped C60 with transition temperatures (Tc) in the mid-30-kelvin range. In this talk I will review how the successes of this initial team effort stimulated a worldwide collaboration between experimentalists and theorists to understand the promise and potential of an entirely new class of superconductors containing only two elements, carbon and an intercalated alkali metal. Although the cuprates still hold the record for the highest Tc, there are still open scientific questions about the mechanism that gives rise to such unexpectedly high Tc's in the non-oxide carbon-based superconductors. The doped fullerenes have unusual attributes (e.g., narrow electronic bands, high disorder, anomalous energy scales, and a tantalizing proximity to a metal-insulator Mott transition), which challenge conventional thinking and at the same time provide useful insights into new directions for finding even higher Tc materials. The final chapter of the `soot to superconductivity' story has yet to be written.

Superconducting state in (W, Ta)5SiB2

Science.gov (United States)

Fukuma, M.; Kawashima, K.; Akimitsu, J.

We characterize the superconducting state in a boro-silicide (W, Ta)5SiB2, with Tc of 6.5 K by means of magnetization, electrical resistivity, and specific heat measurements. As x increased, the transition temperature Tc abruptly enhances from 5.8 to 6.5 K. The magnetization versus magnetic field (M-H) curve indicated that (W, Ta)5SiB2 was a conventional type-II superconductor. The estimated lower critical field Hc1(0) and upper critical field Hc2(T) are about 121 Oe and 14.7 kOe, respectively. The penetration depth λ(0) and coherence length ξ(0) are calculated to be approximately 369 and 14.9 nm, respectively, using Ginzburg-Landau (GL) equations. Specific heat data shows the superconductivity in W4.5Ta0.5SiB2 belongs to a week-coupling BCS superconductor. Finally, we discuss the increasing of Tc in of (W, Ta)5SiB2 system.

High-pressure effects on the superconductivity of β-pyrochlore oxides AOs2O6

International Nuclear Information System (INIS)

Muramatsu, Takaki; Takeshita, Nao; Terakura, Chikeko; Takagi, Hidenori; Tokura, Yoshinori; Yonezawa, Shigeki; Muraoka, Yuji; Hiroi, Zenji

2006-01-01

High-pressure effects on the superconducting transitions of β-pyrochlore oxide superconductors AOs 2 O 6 (A=Cs, Rb, K) are studied by measuring resistivity under high pressures up to 16 GPa. The superconducting transition temperature T c first increases with increasing pressure in all the compounds and then exhibits a broad maximum at 7.6 K (6 GPa), 8.2 K (2 GPa) and 10 K (0.6 GPa) for A=Cs, Rb and K, respectively. Finally, the superconductivity is suppressed completely at a critical pressure near 7 and 6 GPa for A=Rb and K and probably above 10 GPa for A=Cs. Characteristic changes in the temperature dependence of resistivity of RbOs 2 O 6 under high pressure. The residual resistivity largely increases with pressure above 4 GPa and, as a result, resistivity indicates small temperature dependence down to 4.2 K at 7 GPa and application of further pressure up to 10 GPa indicates that temperature dependence of resistivity decrease below 100 K. This characteristic behavior in the β-pyrochlore oxides may originate from the nesting of nearly octahedron shape of Fermi surface

Oxidation of methionine - is it limiting the diagnostic properties of 99mTc-labeled Exendin-4, a Glucagon-Like Peptide-1 receptor agonist?

Science.gov (United States)

Janota, Barbara; Karczmarczyk, Urszula; Laszuk, Ewa; Garnuszek, Piotr; Mikołajczak, Renata

2016-01-01

Preliminary clinical evaluation of 99mTc-EDDA/HYNIC-Met14-Exendin-4 showed that the complex offers new diagnostic possibilities for insulinoma and MTC. Exendin-4 contains methionine at position 14 in the amino acid chain, which may be oxidized to methionine sulfoxide and, from the pharmaceutical point of view, the oxidized moiety becomes an undesired impurity in the final radioactive preparation. Therefore, the aim of this study was to investigate the influence of commonly used methods to eliminate the effect of methionine oxidation in peptides, i.e. the replacement of methionine by norleucine (Nle) and the addition of L-methionine, on the in vitro stability and the biodistribution. 99mTc-EDDA/HYNIC-Met14-Exendin-4, 99mTc-EDDA/HYNIC-Nle14-Exendin-4, 99mTc-EDDA/HYNIC-Met14-Ex-endin-4 with the addition of L-methionine and an oxidized form of Exendin-4, i.e. 99mTc-EDDA/HYNIC-Met14(ox)-Exendin-4 were compared in vivo with 68Ga-NODAGA-Nle14-Exendin-4 in normal Wistar rats. The stability and lipophilicity were determined in vitro. Biodistribution studies confirmed the specific uptake of all tested complexes in the GLP-1 positive organs: lungs, pancreas and stomach. The uptake of 99mTc-EDDA/HYNIC-Met14-Exendin-4 with the addition of L-methionine and for 68Ga-NODAGA-Nle14-Exendin-4 at 1h p.i. was around 2-fold higher than that of 99mTc-EDDA/HYNIC-Met14-Exendin-4 and 99mTc-EDDA/HYNIC-Nle14-Exendin-4. Although the substitution of methionine by norleucine in the HYNIC-Exendin-4 did not result in improved bio-distribution, the use of L-methionine, as the excipient that inhibits the oxidation of methionine in the peptide chain resulted in higher lung/blood and stomach/blood uptake ratios. Our results confirmed that methionine at position 14 of amino acid chain of Exendin-4 plays an important role in the interaction with GLP-1 receptor positive tissue.

Interplay of CDW, SDW and superconductivity in high-Tc cuprates

International Nuclear Information System (INIS)

Panda, S.K.; Rout, G.C.

2009-01-01

We present a model calculation of the interplay of the charge density wave (CDW), spin density wave (SDW) and superconductivity in high temperature superconductors. In low doping situation the long range antiferromagnetic order is destroyed to give rise to SDW state accompanied by a CDW state in the system due to doping. For suitable doping the superconductivity appears in the system. The CDW state may describe the pseudogap phenomenon which co-exists with the superconducting phase and extends to normal phase in high-T c systems. These three competiting interactions co-exist together. These three gap parameters are calculated from the model Hamiltonian and solved self-consistently. By varying their coupling constants their interplay are investigated. Finally density of states is calculated for the conduction band which displays the experimental conductance data of Ekino et al. [T. Ekino, Y. Sezaki, H. Fujji, Phys. Rev. B 60 (1999) 6916].

Ab initio molecular-orbital study on electron correlation effects in CuO6 clusters relating to high-Tc superconductivity

International Nuclear Information System (INIS)

Yamamoto, S.; Yamaguchi, K.; Nasu, K.

1990-01-01

Ab initio molecular-orbital calculations for CuO 6 clusters have been performed to elucidate the electronic structures of undoped and doped copper oxides, which are of current interest in relation to high-T c superconductivity. The electron correlation effects for these species are thoroughly investigated by the full-valence configuration-interaction method and the complete-active-space self-consistent-field method. The electron correlation effect is relatively simple for the A g state (σ hole), whereas pair excitations and spin-flip excitations give sizable contributions to the configuration-interaction wave function for the B state (in-plane π hole). Implications of these results are discussed in relation to the mechanisms of the high-T c superconductivity

Development of microstructure and superconductivity of silver-clad Bi(2223) composite tapes in the process of heat treatment

International Nuclear Information System (INIS)

Guo, Y.C.; Liu, H.K.; Dou, S.X.

1994-01-01

A systematic study on the development of phase composition, microstructure and superconducting properties (critical temperature Tc and critical current density J c ) in silver-clad (Bi,Pb) 2 Sr 2 Ca 2 Cu 3 O 10 composite tapes during the process of heat treatment has been conducted using X-ray diffraction, scanning electron microscopy and electrical measurements. The correlation between the tape's high Tc phase purity, microstructure and superconducting properties at different heat treatment stages has been carefully analysed and explained. The results indicate that pure high Tc phase, high degree of grain alignment, high mass density and good connection between grains are all essential for superconducting tapes to carry a large current. With the optimized process parameters, a critical current density J c up to 32665 A cm -2 (corresponding critical current, 42.3 A) at 77 K and self-magnetic field for silver-clad (Bi,Pb) 2 Sr 2 Ca 2 Cu 3 O 10 superconducting composite tapes has been achieved. (orig.)

Mechanochemical effects on high-Tc superconductor powders

International Nuclear Information System (INIS)

Yamada, Taichi; Nagai, Ryoji; Takeuchi, Manabu; Minehara, Eisuke.

1991-03-01

We have investigated the mechanochemical effects on high-Tc superconductor (YBa 2 Cu 3 O 7 -δ) powders. The powder was mechanically ground in air using an agate mortar with a pestle. The grinding time was varied from 2 to 100 min. The mean particle sizes of the powders were measured by a sedimentation method. The degradation of superconductivity was evaluated by the measurements of the crystallinity and volume fraction of the superconducting phase. The crystallinity was estimated from X-ray diffraction patterns. The volume fraction of the superconducting phase was estimated from the diamagnetization. The results of these changes of 2 min. and 100 min. grinding are respectively as follows; 1) mean particle size: 10.8 μm and 7.2 μm, 2) crystallinity: 40.0 % and 24.8 %, 3) volume fraction of superconducting phase: 91.5 % and 30.0 %. Recovery of the crystallinity and superconductivity of the ground specimens by re-sintering and re-annealing was also studied. It was found that the recovery of both of the characteristics was not complete. (author)

Superconductivity in Bi-Sr-Ca-Cu-O bulk and film ceramics

Energy Technology Data Exchange (ETDEWEB)

Sukhanov, A A; Ozmanian, KH R; Sandomirskii, B B

1988-07-01

A superconducting transition with Tc0 = 82-95 K and Tc(R = 0) = 82-72 K was observed in Bi(Sr/1-x/Ca/x/)2Cu3O(y) bulk and film specimens obtained via a solid-phase reaction. Temperature dependences of the resistance, critical current, and magnetic susceptibility were measured.

Methods for forming complex oxidation reaction products including superconducting articles

International Nuclear Information System (INIS)

Rapp, R.A.; Urquhart, A.W.; Nagelberg, A.S.; Newkirk, M.S.

1992-01-01

This patent describes a method for producing a superconducting complex oxidation reaction product of two or more metals in an oxidized state. It comprises positioning at least one parent metal source comprising one of the metals adjacent to a permeable mass comprising at least one metal-containing compound capable of reaction to form the complex oxidation reaction product in step below, the metal component of the at least one metal-containing compound comprising at least a second of the two or more metals, and orienting the parent metal source and the permeable mass relative to each other so that formation of the complex oxidation reaction product will occur in a direction towards and into the permeable mass; and heating the parent metal source in the presence of an oxidant to a temperature region above its melting point to form a body of molten parent metal to permit infiltration and reaction of the molten parent metal into the permeable mass and with the oxidant and the at least one metal-containing compound to form the complex oxidation reaction product, and progressively drawing the molten parent metal source through the complex oxidation reaction product towards the oxidant and towards and into the adjacent permeable mass so that fresh complex oxidation reaction product continues to form within the permeable mass; and recovering the resulting complex oxidation reaction product

Magnetism and superconductivity of some Tl-Cu oxides

Science.gov (United States)

Datta, Timir

1991-01-01

Many copper oxide based Thallium compounds are now known. In comparison to the Bi-compounds, the Tl-system shows a richer diversity; i.e., High Temperature Superconductors (HTSC) can be obtained with either one or two Tl-0 layers (m = 1,2); also, the triple-digit phases are easier to synthesize. The value of d, oxygen stoichiometry, is critical to achieving superconductivity. The Tl system is robust to oxygen loss; Tl may be lost or incorporated by diffusion. A diffusion coefficient equal to 10 ms at 900 C was determined. Both ortho-rhombic and tetragonal structures are found, but HTSC behavior is indifferent to the crystal symmetry. This system has the highest T(sub c) confirmed. T(sub c) generally increases with p, the number of CuO layers, but tends to saturate at p = 3. Zero resistance was observed at temperatures as great as 125 K. Most of these HTSC's are hole type, but the Ce-doped specimens may be electronic. The magnetic aspects were studied; because in addition to defining the perfectly diamagnetic ground state as in conventional superconductors, magnetism of the copper oxides show a surprising variety. This is true of both the normal and the superconducting states. Also, due to the large phonon contribution to the specific heat at the high T(sub c) jump, electronic density of states, D(Ef), and coherence length are uncertain, and thus, are estimated from the magnetic results. Results from the Tl-system CuO, LaBaCuO,120 and the Bi-CuO compounds are discussed. The emphasis is on the role of magnetism in the Tl-CuO HTSC, but technological aspects are also pointed out.

Magnetic levitation and superconductivity

International Nuclear Information System (INIS)

Albrecht, C.

1989-01-01

The paper explains the impressive advances made in the development of superconducting magnets, in cryogenic engineering, and in the development of drive and vehicle concepts in Japan in the period following termination of West German development work for the electrodynamical system (MLU 001, MLU 002). The potentials engineering due to the development of high-Tc superconductors are discussed. (orig./MM) [de

Superconductores de alta Tc, diez años después

Directory of Open Access Journals (Sweden)

A. Mariño Camargo

1996-07-01

Full Text Available This contribution is a short review of the current state of the high temperature superconductivity. After ten years of research in this field. A description of the common characteristics of the new sllperconducting materials is followed by the discussion of so me releva nt problems that limit their applications. Sorne aspects related to the determination of the mechanisms responsibles for the high Tc superconductivity are mentioned.

Synthesis, Structure Elucidation, and Redox Properties of (superscript 99)Tc Complexes of Lacunary Wells-Dawson Polyoxometalates: Insights into Molecular (superscript 99)Tc-Metal Oxide Interactions

International Nuclear Information System (INIS)

McGregor, Donna; Burton-Pye, Benjamin P.; Howell, Robertha C.; Mbomekalle, Israel M.; Lukens, Wayne W. Jr.; Bian, Fang; Mausolf, Edward; Poineau, Frederic; Czerwinski, Kenneth R.; Francesconi, Lynn C.

2011-01-01

The isotope 99 Tc (β max , 293.7; half-life, 2.1 x 10 5 years) is an abundant product of uranium-235 fission in nuclear reactors and is present throughout the radioactive waste stored in underground tanks at the Hanford and Savannah River sites. Understanding and controlling the extensive redox chemistry of 99 Tc is important in identifying tunable strategies to separate 99 Tc from spent fuel and from waste tanks and, once separated, to identify and develop an appropriately stable waste form for 99 Tc. Polyoxometalates (POMs), nanometer-sized models for metal oxide solid-state materials, are used in this study to provide a molecular level understanding of the speciation and redox chemistry of incorporated 99 Tc. In this study, 99 Tc complexes of the (α 2 -P 2 W 17 O 61 ) 10- and (α 1 -P 2 W 17 O 61 ) 10- isomers were prepared. Ethylene glycol was used as a 'transfer ligand' to minimize the formation of TcO 2 · xH 2 O. The solution structures, formulations, and purity of TcVO(α 1 /α 2 -P 2 W 17 O 61 ) 7- were determined by multinuclear NMR. X-ray absorption spectroscopy of the complexes is in agreement with the formulation and structures determined from 31 P and 183 W NMR. Preliminary electrochemistry results are consistent with the EXAFS results, showing a facile reduction of the TcVO(α 1 -P 2 W 17 O 61 ) 7- species compared to the TcVO(α 2 -P 2 W 17 O 61 ) 7- analog. The α 1 defect is unique in that a basic oxygen atom is positioned toward the α 1 site, and the Tc V O center appears to form a dative metal-metal bond with a framework W site. These attributes may lead to the assistance of protonation events that facilitate reduction. Electrochemistry comparison shows that the ReV analogs are about 200 mV more difficult to reduce in accordance with periodic trends.

Silica-gel modified with zirconium oxide as a novel 99Mo adsorbent 99mTc generators

International Nuclear Information System (INIS)

Salehi, H.; Mollarazi, E.; Abbasi, H.

2010-01-01

A new 99 Mo adsorbent has been prepared with modified silica gel with zirconium oxide (SiO 2 /ZrO 2 :Na 2 MoO 4 ) and used in technetium-99m generator. The adsorption behaviors of 99 Mo in the form of molybdate and 99m Tc in the form of pertechnetate on the new adsorbent was investigated showed that the adsorption capacity of molybdate on this generator was considerably higher than the usual generator with alumina column. Coating zirconium oxide on the surface of silica gel resulted in higher 99 Mo adsorption of this compound. 99m Tc is eluted with 0.9% NaCl, and the radionuclidic, radiochemical and chemical purities of the eluate were checked. This generator has a great potential as compared to the traditional alumina generators.

Composite superconducting wires produced by rapid coating in Bi-Sr-Ca-Cu-O metal oxide system

International Nuclear Information System (INIS)

Grozav, A.D.; Konopko, L.A.; Leoporda, N.I.

1989-01-01

Method for producing superconducting composite wires by dip coating of copper wires in metal-oxide BiSrCaCu 2 O x melt is developed. The thickness of the coating is regulated by the change of dip rate, melt viscosity and by the number of passages through the melt. Wire annealing at 700-800 deg C leads to the production of two phases, one of them being superconducting with T c =80K

The war of the cold: an history of the superconductivity

International Nuclear Information System (INIS)

Matricon, J.; Waysand, G.

1994-01-01

The evolution of superconductivity is described from a scientific, and social points of view. The evolution of researches and realizations towards the absolute zero temperature leading to the discovery of superconductivity by Gilles Holst in 1991, is followed by the theoretical modelization of the superconductivity phenomena leading to the Ginzburg and Landau theory in 1950 and to the Bardeen, Cooper and Schrieffer theory in 1957. Then researches on materials that lead to high-tc superconductors are presented with some applications. (A.B.). refs., figs,. tabs

Origin of the pressure-dependent Tc valley in superconducting simple cubic phosphorus

Science.gov (United States)

Wu, Xianxin; Jeschke, Harald O.; Di Sante, Domenico; von Rohr, Fabian O.; Cava, Robert J.; Thomale, Ronny

2018-03-01

Motivated by recent experiments, we investigate the pressure-dependent electronic structure and electron-phonon (e-ph) coupling for simple cubic phosphorus by performing first-principles calculations within the full potential linearized augmented plane-wave method. As a function of increasing pressure, our calculations show a valley feature in Tc, followed by an eventual decrease for higher pressures. We demonstrate that this Tc valley at low pressures is due to two nearby Lifshitz transitions, as we analyze the band-resolved contributions to the e-ph coupling. Below the first Lifshitz transition, the phonon hardening and shrinking of the γ Fermi surface with s -orbital character results in a decreased Tc with increasing pressure. After the second Lifshitz transition, the appearance of δ Fermi surfaces with 3 d -orbital character generate strong e-ph interband couplings in α δ and β δ channels, and hence lead to an increase of Tc. For higher pressures, the phonon hardening finally dominates, and Tc decreases again. Our study reveals that the intriguing Tc valley discovered in experiment can be attributed to Lifshitz transitions, while the plateau of Tc detected at intermediate pressures appears to be beyond the scope of our analysis. This strongly suggests that aside from e-ph coupling, electronic correlations along with plasmonic contributions may be relevant for simple cubic phosphorus. Our findings hint at the notion that increasing pressure can shift the low-energy orbital weight towards d character, and as such even trigger an enhanced importance of orbital-selective electronic correlations despite an increase of the overall bandwidth.

Relations between structural and superconducting properties of bulk and thin film high-Tc materials

International Nuclear Information System (INIS)

Hessel Andersen, N.

1994-06-01

The structural ordering of oxygen deficient and Co-doped YBCO (YBa 2 Cu 3-y Co y O 6+x ) have been studied experimentally, and by computer simulations of the oxygen ordering in the basal plane of the structure. The calculations are based on the two-dimensional ASYNNNI model and its modifications. Good agreement is established between the ASYNNNI calculations and the experimentally observed structural properties of the double cell ortho-II structure and the oxygen disordering process from Co-doping into the basal plane. A model that relates the superconducting transition temperature T c (x) of undoped YBCO and T c (y) of Co-doped YBCO to the formation of specific domains of the two orthorhombic ordered oxygen phases, ortho-I and ortho-II, shows a close agreement with experimental T c (x) and T c (y) data of samples prepared under equilibrium conditions. The structural changes as a result of metal ion substitutions and oxidation/reduction processes have been studied by neutron powder diffraction in Pb 2 Sr 2 Ln 1-x Ca x Cu 3 O 8+y (Ln = Y and Ho), Nd 1.85 Ce 0.15 CuO 4+y , and chemically oxidized La 2-x Sr x CuO 4+y 2 Cu 3-y Al y O 6+x (y 2 Cu 3 O 6+x and Bi 2 Sr 2 CaCu 2 O 8+x thin films deposited on SrTiO 3 (001), MgO (001), LaAlO 3 (001), and NdGaO 3 (001) substrates has been studied by x-ray diffraction, TEM and RBS, and the structural ordering has been analysed in relation to their superconducting properties. (au) (30 ills., 29 refs.)

A simple model to estimate the optimal doping of p - Type oxide superconductors

Directory of Open Access Journals (Sweden)

Adir Moysés Luiz

2008-12-01

Full Text Available Oxygen doping of superconductors is discussed. Doping high-Tc superconductors with oxygen seems to be more efficient than other doping procedures. Using the assumption of double valence fluctuations, we present a simple model to estimate the optimal doping of p-type oxide superconductors. The experimental values of oxygen content for optimal doping of the most important p-type oxide superconductors can be accounted for adequately using this simple model. We expect that our simple model will encourage further experimental and theoretical researches in superconducting materials.

On the interaction of granite with Tc(IV) and Tc(VII) in aqueous solution

International Nuclear Information System (INIS)

Eriksen, T.E.; Cui, Daquing

1991-10-01

The behaviour of technetium in granite-groundwater systems under reducing conditions was investigated. The anion TcO 4 - was reduced to Tc(IV) and simultaneously precipitated as TcO 2 xnH 2 O on the granite surfaces. The electron sources are assumed to be iron oxides and/or iron containing minerals in the granite. The technetium concentration in ground water under repository conditions may be predicted assuming TcO 2 xnH 2 O as the solid phase and TcO(OH) 2 0 and TcO 4 - as the predominant aqueous complexes using a formation constant for TcO(OH) 2 0 of log K = -8.16 and a standard reduction potential E 0 for the reaction TcO 4 - + 3e - + 4H + = TcO 2 xnH 2 O of 0.738 V. The surface related distribution ratio K a for TcO(OH) 2 0 between Stripa granite and ground water is approximately 1 cm based on geometrical surface area. (au)

Structure and superconductivity of double-doped Mg1-x(Al0.5Li0.5)xB2

DEFF Research Database (Denmark)

Xu, G.J.; Grivel, Jean-Claude; Abrahamsen, A.B.

2003-01-01

A series of polycrystalline samples of Mg1-x(Al0.5Li0.5)(x)B-2 (0less than or equal toxless than or equal to0.6) were prepared by a solid state reaction method and their structure, superconducting transition temperature and magneto-transport properties were investigated by means of X-ray diffract......A series of polycrystalline samples of Mg1-x(Al0.5Li0.5)(x)B-2 (0less than or equal toxless than or equal to0.6) were prepared by a solid state reaction method and their structure, superconducting transition temperature and magneto-transport properties were investigated by means of X......-ray diffraction (XRD), ac-susceptibility and resistance in varied magnetic fields. The double doping leads to decreases in both the lattice parameters a and c. The superconducting transition temperature (T-c) decreases with double doping, but the T-c is systematically higher than that of the single Al......-doped samples. It is suggested that the hole band filling has little effect on T-c at high doping level, while the disorder induced by doping plays an important role in suppressing T-c. A systematic comparison with Al-doped MgB2 of the structure, superconducting transition and irreversibility field is made. (C...

Resonance of Superconducting Microstrip Antenna with Aperture in the Ground Plane

Directory of Open Access Journals (Sweden)

S. Benkouda

2013-08-01

Full Text Available This paper presents a rigorous full-wave analysis of a high Tc superconducting rectangular microstrip antenna with a rectangular aperture in the ground plane. To include the effect of the superconductivity of the microstrip patch in the full-wave analysis, a complex surface impedance is considered. The proposed approach is validated by comparing the computed results with previously published data. Results showing the effect of the aperture on the resonance of the superconducting microstrip antenna are given.

Electronic properties of high Tc superconductors

International Nuclear Information System (INIS)

Rojo, A.G.

1989-01-01

Using analytical and numerical methods, the electronic properties of the copper-oxygen plane in the normal phase of high Tc superconductors are described. Using the slave-boson technique in the saddle point, a theory of the metal insulator transition which generalizes the notions of a Mott insulator to the case of more than a single band for those planes is presented. A phase-diagram is obtained in the parameter space and effective masses, optical gaps and metallization are calculated as a function of the number of carriers. Based on the experimental evidence, the theory permits classification of superconducting compounds as charge transfer insulators in the stoichiometric case. The insulator state is characterized by a non-zero optical gap and a divergent effective mass which corresponds to the breakage of a Fermi-liquid scheme. The results obtained are applicable to metal-transition-oxides whose behaviour has been traditionally controversial and it is concluded that it is necessary to broaden the meaning of a Mott insulator to the case of more than a single band to better understand them. Based on the ideas of group renormalization in a real space, a lattice approximation is presented, which allows: a) To complement the treatment of slave-bosons in phase diagrams and optical gaps; b) Identification of an attraction mechanism between carriers originating from purely repulsive interactions. Numerical calculations in small clusters show the existence of a pairing mechanism showing a superconducting instability from a charge transfer insulator. (Author) [es

A universal order underlying the pseudogap regime of the underdoped high Tc cuprates

Science.gov (United States)

Harrison, Neil

2014-03-01

A major achievement in condensed matter physics in the last quarter century has been a step towards the understanding of the unconventional d-wave superconducting state in the copper-oxide materials. Surprisingly, the normal state out of which the superconducting state emerges remains a mystery at low charge carrier densities, i.e., in the underdoped regime. This regime is of particular interest because it is characterised by an unusual momentum dependent energy pseudogap in the excitation spectrum that has defied explanation and is key to a full understanding of the unconventional d-wave superconducting state. I will present new quantum oscillation experimental results within the pseudogap regime of the high Tc superconductors YBa2Cu3O6+x and YBa2Cu4O8 which now extend up to the optimally-doped regime. These data reveal the evolution of the Fermi surface approaching the putative quantum critical point under the superconducting dome. A comprehensive angle-resolved study of the Fermi surface enables us to unambiguously identify a specific form of order that accounts for the observed quantum oscillations as well as other spectroscopic, transport and thermodynamic probes within the pseudogap regime. The author would like to thank B. Ramshaw, S. Sebastian, F. Balakirev, C. Mielke, M. Altarawneh, P. Goddard, S. Sabok, B. Babrowski, D. Bonn, W. Hardy, R. Liang and G. Lonzarich. This work was supported by the DOE BES ``Science of 100 tesla'' project and by the NSF and Florida State.

Bi-based superconducting fibers with high critical parameters

International Nuclear Information System (INIS)

Huo Yujing; He Yusheng; Liu Menglin; Mao Sining; Cai Liying; Wang Ying; Zhang Jincang; He Aisheng; Wang Jinsong

1991-01-01

Superconducting fibers of Bi(Pb)-Sr-Ca-Cu-O high Tc superconducting materials have been prepared by means of the laser-heated pedestal growth (LHPG) method. The highest zero resistance temperature T c0 reaches is 114K, and the highest critical current density J c (77K, O T) is greater than 5000 A/cm 2 . As-grown superconducting fibers were successfully fabricated without post growth heat treatment. Amorphous materials were used for the first time to make high quality fibers. The influence of growth conditions, thermal treatment and the composition of the fibers were discussed. (author). 5 refs., 7 figs., 3 tabs

Laser-excited photoemission spectroscopy study of superconducting boron-doped diamond

Directory of Open Access Journals (Sweden)

K. Ishizaka, R. Eguchi, S. Tsuda, T. Kiss, T. Shimojima, T. Yokoya, S. Shin, T. Togashi, S. Watanabe, C.-T. Chen, C.Q. Zhang, Y. Takano, M. Nagao, I. Sakaguchi, T. Takenouchi and H. Kawarada

2006-01-01

Full Text Available We have investigated the low-energy electronic state of boron-doped diamond thin film by the laser-excited photoemission spectroscopy. A clear Fermi-edge is observed for samples doped above the semiconductor–metal boundary, together with the characteristic structures at 150×n meV possibly due to the strong electron–lattice coupling effect. In addition, for the superconducting sample, we observed a shift of the leading edge below Tc indicative of a superconducting gap opening. We discuss the electron–lattice coupling and the superconductivity in doped diamond.

Structural chemistry of superconducting pnictides and pnictide oxides with layered structures

Energy Technology Data Exchange (ETDEWEB)

Johrendt, Dirk [Ludwig-Maximilians-Univ. Muenchen (Germany). Dept. Chemie und Biochemie; Hosono, Hideo [Tokyo Institute of Technology, Yokohama (Japan). Frontier Research Center; Hoffmann, Rolf-Dieter; Poettgen, Rainer [Muenster Univ. (Germany). Inst. fuer Anorganische und Analytische Chemie

2011-07-01

The basic structural chemistry of superconducting pnictides and pnictide oxides is reviewed. Crystal chemical details of selected compounds and group subgroup schemes are discussed with respect to phase transitions upon charge-density formation, the ordering of vacancies, or the ordered displacements of oxygen atoms. Furthermore, the influences of doping and solid solutions on the valence electron concentration are discussed in order to highlight the structural and electronic flexibility of these materials. (orig.)

Pulsed laser deposition of high Tc superconducting thin films

International Nuclear Information System (INIS)

Singh, R.K.; Narayan, J.

1990-01-01

This paper reports on the pulsed laser evaporation (PLE) technique for deposition of thin films characterized by a number of unique properties. Based on the experimental characteristics, a theoretical model is developed which considers the formation and anisotropic three dimensional expansion of the laser generated plasma. This model explains most of the experimental features observed in PLE. We have also employed the PLE technique for in-situ fabrication of YBa 2 Cu 3 O 7 superconducting thin films on different substrates in the temperature range of 500--650 degrees C. At temperatures below 600 degrees C, a biased interposing ring between the substrate and the target was found to significantly improve the superconducting properties. The minimum ion channeling yields were between 3--3.5% for films deposited on (100) SrTiO 3 and (100) LaAlO 3 substrates

Chemical approaches to understanding the environmental behavior of Pu, Np, and Tc

International Nuclear Information System (INIS)

Bondietti, E.A.

1978-01-01

Some topics discussed are as follows: speciation behavior of Pu, Np, and Tc; thermodynamic and radiochemical behavior; sorption studies with soils; Pu oxidation states in fresh water; Np oxidation states in soils; effect of oxidation state of Tc on environmental transport predictions; and thermodynamic calculations of Tc speciation

Response of high Tc superconducting Josephson junction to nuclear radiation

International Nuclear Information System (INIS)

Ding Honglin; Zhang Wanchang; Zhang Xiufeng

1992-10-01

The development of nuclear radiation detectors and research on high T c superconducting nuclear radiation detectors are introduced. The emphases are the principle of using thin-film and thick-film Josephson junctions (bridge junction) based on high T c YBCO superconductors to detect nuclear radiation, the fabrication of thin film and thick-film Josephson junction, and response of junction to low energy gamma-rays of 59.5 keV emitted from 241 Am and beta-rays of 546 keV. The results show that a detector for measuring nuclear radiation spectrum made of high T c superconducting thin-film or thick-film, especially, thick-film Josephson junction, certainly can be developed

Comparative evaluation of different nanostructured metal oxides for preparation of clinically useful 99Mo/99mTc generators

International Nuclear Information System (INIS)

Ram, Ramu; Chakravarty, Rubel; Dash, Ashutosh

2015-01-01

The potential of nanostructured metal oxides such as nanotitania, nanozirconia, nanoalumina and mesoporous alumina, as new generation sorbent materials for preparation of 99 Mo/ 99m Tc generator has recently been demonstrated. A comparative assessment of such materials is essential for determination of their suitability for preparation of clinically useful generators using (n,γ) 99 Mo. Characteristics which were compared included the sorption capacity, shelf-life of the generator, radioactive concentration and purity of 99m Tc for radiopharmaceutical applications. Mesoporous alumina was identified as the most suitable sorbent for ensuring sustainable production of clinical grade 99 Mo/ 99m Tc generators using low specific activity 99 Mo. (author)

Effects of graphene oxide doping on the structural and superconducting properties of YBa2Cu3O7-δ

Science.gov (United States)

Dadras, S.; Falahati, S.; Dehghani, S.

2018-05-01

In this research we reported the effects of graphene oxide (GO) doping on the structural and superconducting properties of YBa2Cu3O7-δ (YBCO) high temperature superconductors. We synthesized YBCO powder by sol-gel method. After calcination, the powder mixed with different weight percent (0, 0.1, 0.3, 0.7, 1 wt.%) of GO. Refinement of X-ray diffraction (XRD) was carried out by material analysis using diffraction (MAUD) program to obtain the structural parameters such as lattice parameters, site occupancy of different atoms and orthorhombicity value for the all samples. Results show that GO doping does not change the structure of YBCO compound, Cu (1), Cu (2) and oxygen sites occupancy. It seems that GO remains between the grains and can play the role of weak links. We found that GO addition to YBCO compound increases transition temperature (TC). The oxygen contents of the all GO-doped samples are increased with respect to the pure one. The strain (ɛ) of the samples obtained from Williamson-Hall method, varies with increasing of GO doping. The scanning electron microscopy (SEM) images of the samples show better YBCO grain connections by GO doping.

Superconductivity pairing mechanism from cobalt impurity doping in FeSe: Spin (s±) or orbital (s++) fluctuation

Science.gov (United States)

Urata, T.; Tanabe, Y.; Huynh, K. K.; Yamakawa, Y.; Kontani, H.; Tanigaki, K.

2016-01-01

In high-superconducting transition temperature (Tc) iron-based superconductors, interband sign reversal (s±) and sign preserving (s++) s -wave superconducting states have been primarily discussed as the plausible superconducting mechanism. We study Co impurity scattering effects on the superconductivity in order to achieve an important clue on the pairing mechanism using single-crystal Fe1 -xCoxSe and depict a phase diagram of a FeSe system. Both superconductivity and structural transition/orbital order are suppressed by the Co replacement on the Fe sites and disappear above x = 0.036. These correlated suppressions represent a common background physics behind these physical phenomena in the multiband Fermi surfaces of FeSe. By comparing experimental data and theories so far proposed, the suppression of Tc against the residual resistivity is shown to be much weaker than that predicted in the case of general sign reversal and full gap s± models. The origin of the superconducting paring in FeSe is discussed in terms of its multiband electronic structure.

Superconductivity in Weyl semimetal candidate MoTe{sub 2}

Energy Technology Data Exchange (ETDEWEB)

Qi, Yanpeng; Naumov, Pavel; Rajamathi, Catherine; Barkalov, Oleg; Wu, Shu-Chun; Shekhar, Chandra; Sun, Yan; Suess, Vicky; Schmidt, Marcus; Schwarz, Ulrich; Schnelle, Walter; Felser, Claudia; Medvedev, Sergey [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Ali, Mazhar; Cava, Robert [Department of Chemistry, Princeton University, Princeton (United States); Hanfland, Michael [European Synchrotron Radiation Facility, Grenoble (France); Pippel, Eckhard; Werner, Peter; Hillebrand, Reinald; Parkin, Stuart [Max Planck Institute of Microstructure Physics, Halle (Germany); Foerster, Tobias; Kampert, Erik [Dresden High Magnetic Field Laboratory, Dresden (Germany); Yan, Binghai [Max Planck Institute for Chemical Physics of Solids, Dresden (Germany); Max Planck Institute for the Physics of Complex Systems, Dresden (Germany)

2016-07-01

In this work, we investigate the sister compound of WTe{sub 2}, MoTe{sub 2}, which is also predicted to be a Weyl semimetal and a quantum spin Hall insulator in bulk and monolayer form, respectively. We find that MoTe{sub 2} exhibits superconductivity with a resistive transition temperature T{sub c} of 0.1 K. The application of a small pressure is shown to dramatically enhance the T{sub c}, with a maximum value of 8.2 K being obtained at 11.7 GPa (a more than 80-fold increase in Tc). This yields a dome-shaped superconducting phase diagram. Further explorations into the nature of the superconductivity in this system may provide insights into the interplay between superconductivity and topological physics.

Tuning of superconductivity by Ni substitution into noncentrosymmetric ThC o1 -xN ixC2

Science.gov (United States)

Grant, T. W.; Cigarroa, O. V.; Rosa, P. F. S.; Machado, A. J. S.; Fisk, Z.

2017-07-01

The recently discovered noncentrosymmetric superconductor ThCoC2 was observed to show unusual superconducting behavior with a critical temperature of Tc=2.65 K . Here we investigate the effect of nickel substitution on the superconducting state in ThC o1 -xN ixC2 . Magnetization, resistivity, and heat capacity measurements demonstrate Ni substitution has a dramatic effect with critical temperature increased up to Tc=12.1 K for x =0.4 Ni concentration, which is a rather high transition temperature for a noncentrosymmetric superconductor. In addition, the unusual superconducting characteristics observed in pure ThCoC2 appear to be suppressed or tuned with Ni substitution towards a more conventional fully gapped superconductor.

High-temperature superconducting oxide synthesis and the chemical doping of the Cu-O planes

International Nuclear Information System (INIS)

Tarascon, J.M.; Barboux, P.; Bagley, B.G.; Greene, L.H.; McKinnon, W.R.; Hull, G.W.

1987-01-01

Different synthesis techniques for the preparation of dense superconducting ceramics are discussed, and a sol-gel process is shown to be very promising. The effect of oxygen content, and the effect of substitution of Ni and Zn for copper, on the structural, transport and superconducting properties of the La-Sr-Cu-O and Y-Ba-Cu-O systems are presented. The authors find that substitution on the copper sites destroys T/sub c/ in the La-Sr-Cu-O system and decreases it in the Y-Ba-Cu-O system, and this effect is insensitive as to whether the 3d metal is magnetic (Ni) or diamagnetic (Zn). A detailed study of the YBa/sub 2/Cu/sub 3/O/sub 7-y/ system as a function of oxygen content (y) shows that superconductivity can be destroyed in these materials by the removal of oxygen and restored by reinjecting oxygen; either thermally at 500 0 C or at temperatures (80 0 C) compatible with device processing by means of a novel plasma oxidation process. Of scientific interest, the plasma process induces bulk superconductivity in the undoped La/sub 2/CuO/sub 4/

Structure, stoichiometry and spectroscopy of oxide superconductors

Science.gov (United States)

Rao, C. N. R.

In the new oxide superconductors, structure and oxygen stoichiometry play the most crucial role. Thus, all the high-temperature oxide superconductors are orthorhombic perovskites with low-dimensional features. Oxygen stoichiometry in YBa2Cu3O7-δ has an important bearing on the structure as well as superconductivity. This is equally true in the La3-xBa3+xCu 6O14+δ system of which only the 123 oxide (x = 1) with the orthorhombic structure shows high Tc. Orthorhombicity though not essential, is generally found ; it is necessary for the formation of twins. The nature of oxygen and copper in the cuprates has been examined by electron spectroscopy. Copper in these cuprates is only in 1 + and 2 + states. It seems likely that oxygen holes are responsible for superconductivity of the cuprates as well as Ba(Bi, Pb)O3. High Tc superconductivity is also found in oxides of the Bi-(Ca, Sr)-Cu-O and related oxides possessing Cu-O sheets. Dans les nouveaux oxydes supraconducteurs, la structure et la stoechiométrie de l'oxygène jouent un rôle absolument crucial. Ainsi, tous les oxydes supraconducteurs à haute température critique sont des pérovskites orthorhombiques possédant des propriétés de basse dimensionnalité. La stoechiométrie de l'oxygène dans YBa2Cu3O7- δ a une influence importante tant sur la structure que sur la supraconductibilité. Ceci est également valable pour les composés du type La3 -xBa3 + xCu 6O14 + δ parmi lesquels seul l'oxyde 123 (x = 1) à structure orthorhombique présente un grand T. Bien que ce ne soit pas essentiel, cette orthorhombicité est fréquente ; elle est nécessaire à la formation de macles. La nature de l'oxygène et du cuivre a été observée par spectroscopie électronique... Dans ces cuprates, le cuivre est dans les seuls états de valence + 1 et + 2. Vraisemblablement, les trous logés sur l'oxygène sont responsables de la supraconductibilité des cuprates comme de Ba(Bi, Pb)O3. La supraconductibilité existe aussi

Determination of the electromagnetic field in a high-Tc linear superconducting resonator

International Nuclear Information System (INIS)

Trotel, A.; Sautrot, S.; Pyee, M.

1994-01-01

In this paper, the electromagnetic field configuration in a linear SHTC resonator is described. Two areas are considered: 1) the superconducting strip, 2) the dielectric around the strip. The calculation is based on the current density given by Bowers for an infinite superconducting line. The current density in the resonator is defined by these relations and the resonance conditions. (orig.)

Redox behavior of Tc(VII)/Tc(IV) under various reducing conditions in 0.1 M NaCl solutions

International Nuclear Information System (INIS)

Kobayashi, T.; Gaona, X.; Altmaier, M.; Scheinost, A.C.; Fellhauer, D.; European Commission Joint Research Centre, Karlsruhe

2013-01-01

Redox behaviour of Tc(VII)/Tc(IV) was investigated in 0.1 M NaCl solutions containing different reducing agents in the pH range 2 to 13 at 22 C under inert Ar atmosphere. In several samples, the 1 x 10 -5 mol/dm 3 (M) initially added TcO 4 - was reduced to form a Tc(IV) oxide solid phase with low solubility. The observed Tc redox transformation processes are systematized according to E h -pH conditions in solution, indicating that a borderline for the reduction of Tc(VII) to Tc(IV), TcO 4 - + 3e - + 4H + TcO 2 . xH 2 O(coll, hyd) + (2-x)H 2 O exists, independent of the reducing chemical system. This experimentally derived borderline is about 100 mV lower than the equilibrium line calculated from the reported standard redox potential of TcO 2 . 1.6H 2 O(s). This behaviour can be related to the existence of more soluble solid phase modifications, i.e. nanoparticulate Tc(IV) oxide species TcO 2 . xH 2 O(coll, hyd). The reaction kinetics likewise correlate to the redox potential measured in solution. Slow reduction of Tc(VII) to Tc(IV) was observed when the redox potential in the system was slightly below the above mentioned reduction borderline. Fast reduction was observed in the systems far below the borderline, but also in those systems containing Fe(II) solids, suggesting a specific surface mediated effect in the reduction process. EXAFS analysis on two magnetite samples indicate reduced Tc(IV) species which do not remain adsorbed at the reactive mineral surface and are incorporated in the magnetite structure. (orig.)

Midwest Superconductivity Consortium: 1994 Progress report

Energy Technology Data Exchange (ETDEWEB)

1995-01-01

The mission of the Midwest Superconductivity Consortium, MISCON, is to advance the science and understanding of high {Tc} superconductivity. During the past year, 27 projects produced over 123 talks and 139 publications. Group activities and interactions involved 2 MISCON group meetings (held in August and January); with the second MISCON Workshop held in August; 13 external speakers; 79 collaborations (with universities, industry, Federal laboratories, and foreign research centers); and 48 exchanges of samples and/or measurements. Research achievements this past year focused on understanding the effects of processing phenomena on structure-property interrelationships and the fundamental nature of transport properties in high-temperature superconductors.

Superconductivity in ThPd2Ge2

Science.gov (United States)

Domieracki, Krzysztof; Wiśniewski, Piotr; Wochowski, Konrad; Romanova, Tetiana; Hackemer, Alicja; Gorzelniak, Roman; Pikul, Adam; Kaczorowski, Dariusz

2018-05-01

Our on-going search for unconventional superconductors among the ThTE2Ge2 phases (TE is a d-electron transition metal) revealed that ThPd2Ge2, which crystallizes with a body-centered tetragonal ThCr2Si2-type structure, exhibits superconductivity at low temperatures. In this paper, we report on the electrical transport and thermodynamic properties of a polycrystalline sample of this new superconductor, extended down to 50 mK. The experimental data indicates weakly-coupled type-II superconductivity with Tc = 0.63(2) K and μ0Hc2(0) = 32(2) mT.

Anomalous electron doping independent two-dimensional superconductivity

Science.gov (United States)

Zhou, Wei; Xing, Xiangzhuo; Zhao, Haijun; Feng, Jiajia; Pan, Yongqiang; Zhou, Nan; Zhang, Yufeng; Qian, Bin; Shi, Zhixiang

2017-07-01

Transition metal (Co and Ni) co-doping effects are investigated on an underdoped Ca0.94La0.06Fe2As2 compound. It is discovered that electron doping from substituting Fe with transition metal (TM = Co, Ni) can trigger high-{T}{{c}} superconductivity around 35 K, which emerges abruptly before the total suppression of the innate spin-density-wave/anti-ferromagnetism (SDW/AFM) state. Remarkably, the critical temperature for the high-{T}{{c}} superconductivity remains constant against a wide range of TM doping levels. And the net electron doping density dependence of the superconducting {T}{{c}} based on the rigid band model can be nicely scaled into a single curve for Co and Ni substitutions, in stark contrast to the case of Ba(Fe1-x TM x )2As2. This carrier density independent superconductivity and the unusual scaling behavior are presumably resulted from the interface superconductivity based on the similarity with the interface superconductivity in a La2-x Sr x CuO4-La2CuO4 bilayer. Evidence of the two-dimensional character of the superfluid by angle-resolved magneto-resistance measurements can further strengthen the interface nature of the high-{T}{{c}} superconductivity.

Thermoelectric Power and Normal State of the High - Tc Copper Oxides

International Nuclear Information System (INIS)

Goodenough, J.B.; Zhou, J.S.; Besuker, G.I.

1995-01-01

The temperature dependence of the thermoelectric power and resistance for the system La 2-x Sr x CuO 4 , 0≤ x ≤0.30, are presented and interpreted. The following model emerges: (1) In the underdoped region 0 2 sheets by Sr substitution form non-adiabatic large polarons containing 6 ± 1 Cu atoms; a cooperative pseudo Jahn-Teller vibronic coupling increases the size of the polaron, but a contraction of the equilibrium Cu-O distance inside the polaron limits the size. Polaron motion occurs via a tunneling of one Cu - O bond at a time. A dynamic segregation into a hole-poor parent phase and a hole-rich superconductive phase occurs below 150K. (2) The range 0.10 2 sheet. In the polaron liquid, pairs of polarons form zig-zag polaron chains; these chains form an ordered array of alternating polaron and parent-phase stripes. Complete ordering of the stripes occurs below Tc. (4) In the overdoped region x>0.27, polaron overcrowding suppresses polaron formation; however, the vibronic coupling stabilized by the dynamic pseudo Jahn -Teller deformations persists to give unusual properties to the overdoped metallic phase. (author)

Preparation of YBaCuO superconducting tape by RF magnetron sputtering

Energy Technology Data Exchange (ETDEWEB)

Fukutomi, Masao; Akutsu, Nakao; Tanaka, Yoshiaki; Asano, Toshihisa; Maeda, Hiroshi (National Research Inst. for Metals, Tsukuba (Japan); Mitsui Mining and Smelting Co., Ltd., Tokyo (Japan))

1989-04-01

The effect of buffer layers, conditions of film preparation, and the relation between superconducting characteristics and bombardment of high energy ions on films were discussed in an attempt to fabricate YBaCuO films on metallic substrates by sputtering. Hastelloy-X tapes and Chromel (Ni-10Cr) fine wires were used as metallic substrates, and MgO films as buffer layers, which were provided by sputtering a MgO sintered target and annealing. As a result, superconducting films were favorably obtained on the Hastelloy tapes with the MgO buffer layers, however, counter diffusion at the interface of the film and layer was unavoidable in annealing. C axis-highly oriented film with high zero resistance Tc was obtained in such an arrangement of the target and substrate as to lower the effect of 0{sup {minus}} ion resputtering, resulting in the most favorable Tc=80.4K. YBaCuO superconducting films could be also deposited on a bundle of Chromel fine wires preliminarily. 11 refs., 7 figs.

Dimensionality Driven Enhancement of Ferromagnetic Superconductivity in URhGe

Science.gov (United States)

Braithwaite, Daniel; Aoki, Dai; Brison, Jean-Pascal; Flouquet, Jacques; Knebel, Georg; Nakamura, Ai; Pourret, Alexandre

2018-01-01

In most unconventional superconductors, like the high-Tc cuprates, iron pnictides, or heavy-fermion systems, superconductivity emerges in the proximity of an electronic instability. Identifying unambiguously the pairing mechanism remains nevertheless an enormous challenge. Among these systems, the orthorhombic uranium ferromagnetic superconductors have a unique position, notably because magnetic fields couple directly to ferromagnetic order, leading to the fascinating discovery of the reemergence of superconductivity in URhGe at a high field. Here we show that uniaxial stress is a remarkable tool allowing the fine-tuning of the pairing strength. With a relatively small stress, the superconducting phase diagram is spectacularly modified, with a merging of the low- and high-field superconducting states and a significant enhancement of the superconductivity. The superconducting critical temperature increases both at zero field and under a field, reaching 1 K, more than twice higher than at ambient pressure. This enhancement of superconductivity is shown to be directly related to a change of the magnetic dimensionality detected from an increase of the transverse magnetic susceptibility: In addition to the Ising-type longitudinal ferromagnetic fluctuations, transverse magnetic fluctuations also play an important role in the superconducting pairing.

Application of high-pressure techniques: stabilization and oxidation-state control of novel superconductive and related multi-layered copper oxides

International Nuclear Information System (INIS)

Yamauchi, H.; Karppinen, M.

2000-01-01

Copper oxide superconductors possess multi-layered structures with a layer sequence of -CuO 2 -(Q-CuO 2 ) n-1 -AO-(MO 1±δ ) m -AO- or -CuO 2 -B-(O 2 -B) s-1 -CuO 2 -AO-(MO 1±δ ) m -AO- along the elongated c axis. Based on this layer sequence, the known copper oxide structures are categorized as members of the homologous series, M m A r Q n-1 Cu n O m+r+2 +n ±δ (M-mr(n-1)n ; category A) or M m A 2k B s Cu 1+k O m +4k +2s±δ (M-m(2k)s (1+k ); category B). Stabilization of such structures especially in the case of high values of the n /s parameter, i.e. the higher members of the homologous series, has been demonstrated to be apparently promoted under high pressures and/or strongly oxidizing conditions. Consequently, techniques for applying both high oxygen gas pressures (10-2000 atm) and ultra-high solid-medium pressures (2-8 GPa) have been advantageously utilized in synthesizing various superconductive copper oxide phases. Especially the ultra-high solid-medium pressure synthesis carried out in the so-called cubic-anvil/belt-type apparatus has proven to be extremely successful in synthesizing novel superconductive phases. In order to achieve high partial pressures of oxygen in the solid-medium environment, 'external' oxygen-generating oxides such as KClO 4 , KClO 3 and Ag 2 O 2 are commonly added to the precursor mixtures. It is emphasized that in some cases it is possible to utilize 'internal' oxidizing agents alone, i.e. highly oxidized precursors such as BaCuO 2+δ and Ba 2 Cu 3 O 5+δ containing metal constituents common with the desired copper oxide phase only. In the present paper, the potential and applications of high-pressure techniques in synthesizing multi-layered copper oxides and related structures are reviewed and discussed with emphasis on the important 'historical' discoveries of novel phases and the present status of controlled production of high-quality samples of such phases. (author)

The effect of ammonia intercalation on the superconducting ...

African Journals Online (AJOL)

A theoretical investigation of the electronic properties of the relatively high-Tc alkali-metal doped superconducting fullerides when they are further exposed to ammonia molecules as dopants is presented. Our numerical method relies on a group theoretical technique for the formation of molecular orbitals (MO's) for the solid ...

Moessbauer studies of 57Fe substitution of Cu ions in superconducting oxides

International Nuclear Information System (INIS)

Saitovitch, E.B.

1988-01-01

Since the discovery of high-T c superconductivity in YBa 2 Cu 3 O 7 oxides several studies of metal ions substitutions were reported. The observed depression on T c without a systematic correlation with the charge and magnetic moment of Cu substituents claims for more detailed information about its local properties as can be revealed by 57 Fe Moessbauer spectroscopy. The results for different iron concentrations combined with modifications of the superconducting transition are discussed concerning the presence of magnetic moments on the Fe ions and the preferential occupation of Cu(1) sites, recently confirmed by neutron and electron diffraction experiments. The oxygen coordination for the different iron species are proposed on the basis of their dependence on Fe concentration, their behavior at high temperatures as well as the electron diffraction and electron microscopy measurements reported for Fe: YBa 2 Cu 3 O 7 samples. (author) [pt

Conventional proximity effect in bilayers of superconducting underdoped $La_{1.88}Sr_{0.12}CuO_4$ islands coated with non superconducting overdoped $La_{1.65}Sr_{0.35}CuO_4$

OpenAIRE

Koren, G.; Millo, O.

2009-01-01

Following a recent study by our group in which a large $T_c$ enhancement was reported in bilayers of the non-superconducting $La_{1.65}Sr_{0.35}CuO_4$ and superconducting $La_{1.88}Sr_{0.12}CuO_4$ films [Phys. Rev. Lett. \\textbf{101}, 057005 (2008)], we checked if a similar effect occurs when superconducting $La_{1.88}Sr_{0.12}CuO_4$ islands are coated with a continuous layer of the non superconducting $La_{1.65}Sr_{0.35}CuO_4$. We found that no such phenomenon is observed. The bare supercond...

Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

KAUST Repository

Wu, B. L.

2013-10-10

Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb of same thickness; the suppression effect is even stronger than that of a ferromagnet in NiFe/Nb bilayers. The addition of an insulating MgO layer at the IrMn-Nb interface nearly restores Tc to that of the single layer Nb, but Hc1 still remains suppressed. These results suggest that, in addition to proximity effect and magnetic impurity scattering, magnetostatic interaction also plays a role in suppressing superconductivity of Nb in IrMn/Nb bilayers. In addition to reduced Tc and Hc1, the IrMn layer also induces broadening in the transition temperature of Nb, which can be accounted for by a finite distribution of stray field from IrMn.

Running Performance of a Pinning-Type Superconducting Magnetic Levitation Guide

International Nuclear Information System (INIS)

Okano, M; Iwamoto, T; Furuse, M; Fuchino, S; Ishii, I

2006-01-01

A pinning-type superconducting magnetic levitation guide with bulk high-Tc superconductors was studied for use as a goods transportation system, an energy storage system, etc. A superconducting magnetic levitation running test apparatus with a circular track of ca. 38 m length, 12 m diameter, which comprises the magnetic rail constituted by Nd-B-Fe rare-earth permanent magnets and steel plates, was manufactured to examine loss and high-speed performance of the magnetic levitation guide. Running tests were conducted in air. These tests clarify that a vehicle supported by a superconducting magnetic levitation guide runs stably at speeds greater than 42 km/h above the circular track

Running Performance of a Pinning-Type Superconducting Magnetic Levitation Guide

Science.gov (United States)

Okano, M.; Iwamoto, T.; Furuse, M.; Fuchino, S.; Ishii, I.

2006-06-01

A pinning-type superconducting magnetic levitation guide with bulk high-Tc superconductors was studied for use as a goods transportation system, an energy storage system, etc. A superconducting magnetic levitation running test apparatus with a circular track of ca. 38 m length, 12 m diameter, which comprises the magnetic rail constituted by Nd-B-Fe rare-earth permanent magnets and steel plates, was manufactured to examine loss and high-speed performance of the magnetic levitation guide. Running tests were conducted in air. These tests clarify that a vehicle supported by a superconducting magnetic levitation guide runs stably at speeds greater than 42 km/h above the circular track.

The Mercereau effect as a guide to the theory of high-Tc superconductivity in rare earth oxide ceramics

International Nuclear Information System (INIS)

Chela-Flores, J.; Martin, P.; Rodriguez-Nunez, J.

1988-08-01

We emphasize the importance of performing definite experiments on quantum interferometers, basing our work on a phenomenological theory of high-T c superconductivity co-existing with antiferromagnetism. The theory satisfies all the general requirements of previous models, including minimal gauge invariant coupling terms. Yet, since no doping-dependent displacements are implied in the Mercereau diffraction pattern, this phenomenological approach underlines the urgency of performing new experiments in order to guide the theory. (author). 21 refs, 1 fig

Imaging the electron-boson coupling in superconducting FeSe films using a scanning tunneling microscope.

Science.gov (United States)

Song, Can-Li; Wang, Yi-Lin; Jiang, Ye-Ping; Li, Zhi; Wang, Lili; He, Ke; Chen, Xi; Hoffman, Jennifer E; Ma, Xu-Cun; Xue, Qi-Kun

2014-02-07

Scanning tunneling spectroscopy has been used to reveal signatures of a bosonic mode in the local quasiparticle density of states of superconducting FeSe films. The mode appears below Tc as a "dip-hump" feature at energy Ω∼4.7kBTc beyond the superconducting gap Δ. Spectra on strained regions of the FeSe films reveal simultaneous decreases in Δ and Ω. This contrasts with all previous reports on other high-Tc superconductors, where Δ locally anticorrelates with Ω. A local strong coupling model is found to reconcile the discrepancy well, and to provide a unified picture of the electron-boson coupling in unconventional superconductors.

Characterization of transparent superconductivity Fe-doped CuCrO{sub 2} delafossite oxide

Energy Technology Data Exchange (ETDEWEB)

Taddee, Chutirat [Materials Science and Nanotechnology Program, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand); Kamwanna, Teerasak, E-mail: teekam@kku.ac.th [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand); Nanotec-KKU Center of Excellence on Advanced Nanomaterials for Energy Production and Storage, Khon Kaen 40002 (Thailand); Integrated Nanotechnology Research Center (INRC), Khon Kaen University, Khon Kaen 40002 (Thailand); Amornkitbamrung, Vittaya [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand); Nanotec-KKU Center of Excellence on Advanced Nanomaterials for Energy Production and Storage, Khon Kaen 40002 (Thailand); Integrated Nanotechnology Research Center (INRC), Khon Kaen University, Khon Kaen 40002 (Thailand)

2016-09-01

Graphical abstract: - Highlights: • Effect of Fe substitution on the physical properties in CuCrO{sub 2} is studied. • The substitution of Cr{sup 3+} by Fe{sup 3+} produces a mixed effect on the magnetic properties. • CuCr{sub 1−x}Fe{sub x}O{sub 2} delafossite oxides show transparent superconductivity. - Abstract: Delafossite CuCr{sub 1−x}Fe{sub x}O{sub 2} (0.0 ≤ x ≤ 0.15) semiconductors were synthesized using a self-combustion urea nitrate process. The effects of Fe concentration on its microstructural, optical, magnetic, and electrical properties were investigated. X-ray diffraction (XRD) analysis results revealed the delafossite structure in all the samples. The lattice spacing of CuCr{sub 1−x}Fe{sub x}O{sub 2} slightly increased with increasing substitution of Fe at the Cr sites. The optical properties measured at room temperature using UV–visible spectroscopy showed a weak absorbability in the visible light and near IR regions. The corresponding direct optical band gap was about 3.61 eV, exhibiting transparency in the visible region. The magnetic hysteresis loop measurements showed that the Fe-doped CuCrO{sub 2} samples exhibited ferromagnetic behavior at room temperature. This indicated that the substitution of Fe{sup 3+} for Cr{sup 3+} produced a mixed effect on the magnetic properties of CuCrO{sub 2} delafossite oxide. The temperature dependent resistivity measurements clearly revealed the presence of superconductivity in the CuCr{sub 1−x}Fe{sub x}O{sub 2} with a superconducting transition up to 118 K.

Synthesis and study of the magnetic properties of thallium-based over-doped superconducting compounds

International Nuclear Information System (INIS)

Opagiste, C.

1994-07-01

The synthesis, structure and magnetic properties of the normal and superconducting states of over-doped Tl 2 Ba 2 Cu O 6±x and Tl 2 Ba 2 Ca Cu 2 O 8±x superconducting compounds, are presented. Synthesis under high pressure using Tl 2 Ba 2 O 5 as a precursor avoids thallium losses and Ba Cu O 2 formation. The entire over-doped region has been investigated (Tc ranging from 0 to 92 K) and the different stability zones for the two crystallographic structures have been explored. The orthorhombic structure is shown to be stoichiometric in cations, while the tetragonal one could present thallium deficiency. Clear correlations have been established between Tc and the lattice parameters for the two phases. It has been observed that the Meissner fraction increased with Tc and that the reversibility domain was more extended for samples having a Tc near the maximal value, which must be linked to the decrease of the anisotropy with over-doping. In the reversible regime, the mixed state is affected by thermal fluctuations around Tc. Evolution of the penetration depth with Tc is examined; it shows that the optimum doped compound (maximal Tc) behaves as a BCS type superconductor. The over-doping results in a penetration depth behaviour which strongly deviates from the standard model (BCS, two fluids). The zero temperature, obtained by extrapolation, seems to be independent of the over-doping. 54 figs., 3 tabs., 168 refs

Theoretical study of stability and superconductivity of ScHn (n =4 -8 ) at high pressure

Science.gov (United States)

Qian, Shifeng; Sheng, Xiaowei; Yan, Xiaozhen; Chen, Yangmei; Song, Bo

2017-09-01

The synthesis of hydrogen sulfides, with the potential of high-temperature superconductivity, was recently proposed at high Tc = 203 K. It motivated us to employ an ab initio approach for the predictions of crystal structures to find the stable scandium hydrides. In addition to the earlier predicted three stoichiometries of ScH, ScH2, and ScH3, we identify three other metallic stoichiometries of ScH4, ScH6, and ScH8, which show superconductivity at significantly higher temperatures. The phases of ScH4 and ScH6, whose stability does not require extremely high pressures (ZPE), are primarily ionic compounds containing exotic quasimolecular H2 arrangements. The present electron-phonon calculations revealed the superconductive potential of ScH4 and ScH6 with estimated Tc of 98 K and 129 K at 200 GPa and 130 GPa, respectively. The superconductivity of ScHn stems from the large electron-phonon coupling associated with the wagging, bending, and intermediate-frequency modes attributed mainly to the hydrogen atoms.

Conductive polymer switch for controlling superconductivity

International Nuclear Information System (INIS)

McDevitt, J.T.; Haupt, S.G.; Riley, D.R.; Zhao, J.; Grassi, J.; Lo, K.; Jones, C.

1994-01-01

The preparation of a hybrid conducting polymer/high-temperature superconductor device consisting of a polypyrrole coated YBa 2 Cu 3 O 7-σ microbridge is reported. Electrochemical techniques are exploited to alter the oxidation state of the polymer and, in doing so, it is found for the first time that superconductivity can be modulated in a controllable and reproducible fashion by a polymer layout. Whereas the neutral (insulating) polypyrrole only slightly influences the electrical properties of the underlying YBa 2 Cu 3 O 7-σ film, the oxidized (conductive) polymer depresses T c by up to 50K. In a similar fashion, the oxidation state of the polymer is found to reversibly modulate the magnitude of J c , the superconducting critical current. Thus, a new type of molecule switch for controlling superconductivity is demonstrated

Muon spin rotation studies of magnetic order and strong magnetic correlations in magnetic and superconducting systems based on the high Tc copper oxide structures

International Nuclear Information System (INIS)

Rudnick, J.J.; Filipkowski, M.E.; Tan, Z.; Chamberland, B.; Niedermayer, C.; Weidinger, A.; Golnik, A.; Simon, R.; Rauer, M.; Recknagel, E.; Gluckler, H.; Baines, C.

1990-01-01

In this paper the authors review results of a series of muon spin rotation (μSR) studies extending down to milli Kelvin temperatures in order to explore the existence of magnetic correlations below T C in the La 2-x Sr x CuO 4 system. Evidence is presented for the existence of local magnetic fields thought to originate from Cu electronic moments in both superconducting La 2-x Sr x CuO 4 and in superconducting oxygen deficient YBa 2 Cu 3 O 6.6 . μSR results are also presented for oxygen deficient and superconducting GdBa 2 Cu 3 O 6+x samples. Some discussion of the relevance of these results to recent proposals for pairing mechanisms is presented

Spectroscopic Properties of Tc(I) Tricarbonyl Species Relevant to the Hanford Tank Waste

Energy Technology Data Exchange (ETDEWEB)

Levitskaia, Tatiana G. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Andersen, Amity [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Chatterjee, Sayandev [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Hall, Gabriel B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Walter, Eric D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Washton, Nancy M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-12-04

Technetium-99 (Tc) exists predominately in soluble forms in the liquid supernatant and salt cake fractions of the nuclear tank waste stored at the U.S. DOE Hanford Site. In the strongly alkaline environments prevalent in the tank waste, its dominant chemical form is pertechnetate (TcO4-, oxidation state +7). However, attempts to remove Tc from the Hanford tank waste using ion-exchange processes specific to TcO₄^- only met with limited success, particularly processing tank waste samples containing elevated concentrations of organic complexants. This suggests that a significant fraction of the soluble Tc can be present as non-pertechnetate low-valent Tc (oxidation state < +7) (non-pertechnetate). The chemical identities of these non-pertechnetate species are poorly understood. Previous analysis of the SY-101 and SY-103 tank waste samples provided strong evidence that non-pertechnetate can be comprised of [Tc(CO)₃]⁺ complexes containing Tc in oxidation state +1 (Lukens et al. 2004). During the last two years, our team has expanded this work and demonstrated that high-ionic-strength solutions typifying tank waste supernatants promote oxidative stability of the [Tc(CO)₃]⁺ species (Rapko et al. 2013; Levitskaia et al. 2014). It also was observed that high-ionic-strength alkaline matrices stabilize Tc(VI) and potentially Tc(IV) oxidation states, particularly in presence organic chelators, suggesting that the relevant Tc compounds can serve as important redox intermediates facilitating the reduction of Tc(VII) to Tc(I). Designing strategies for effective Tc processing, including separation and immobilization, necessitates understanding the molecular structure of these non-pertechnetate species and their identification in the actual tank waste samples. To-date, only limited information exists regarding the nature and characterization of the Tc(I), Tc(IV), and Tc(VI) species. One objective of this project is to

Interface-enhanced high-temperature superconductivity in single-unit-cell FeT e1 -xS ex films on SrTi O3

Science.gov (United States)

Li, Fangsen; Ding, Hao; Tang, Chenjia; Peng, Junping; Zhang, Qinghua; Zhang, Wenhao; Zhou, Guanyu; Zhang, Ding; Song, Can-Li; He, Ke; Ji, Shuaihua; Chen, Xi; Gu, Lin; Wang, Lili; Ma, Xu-Cun; Xue, Qi-Kun

2015-06-01

Recently discovered high-temperature superconductivity in single-unit-cell (UC) FeSe films on SrTi O3 (STO) substrate has stimulated tremendous research interest, both experimental and theoretical. Whether this scenario could be extended to other superconductors is vital in both identifying the enhanced superconductivity mechanism and further raising the critical transition temperature (Tc). Here we successfully prepared single-UC FeT e1 -xS ex(0.1 ≤x ≤0.6 ) films on STO substrates by molecular beam epitaxy and observed U -shaped superconducting gaps (Δ ) up to ˜16.5 meV , nearly ten times the gap value (Δ ˜1.7 meV ) of the optimally doped bulk FeT e0 .6S e0 .4 single crystal (Tc˜14.5 K ). No superconducting gap has been observed on the second UC and thicker FeT e1 -xS ex films at 5.7 K, indicating the important role of the interface. This interface-enhanced high-temperature superconductivity is further confirmed by ex situ transport measurements, which revealed an onset superconducting transition temperature above 40 K, nearly two times higher than that of the optimally doped bulk FeT e0 .6S e0 .4 single crystal. This work demonstrates that interface engineering is a feasible way to discover alternative superconductors with higher Tc.

Superconducting materials

International Nuclear Information System (INIS)

Kormann, R.; Loiseau, R.; Marcilhac, B.

1989-01-01

The invention concerns superconducting ceramics containing essentially barium, calcium and copper fluorinated oxides with close offset and onset temperatures around 97 K and 100 K and containing neither Y nor rare earth [fr

Superconductivity in power engineering

International Nuclear Information System (INIS)

1989-01-01

This proceedings volume presents 24 conference papers and 15 posters dealing with the following aspects: 1) Principles and elementary aspects of high-temperature superconductivity (3 plenary lectures); 2) Preparation, properties and materials requirements of metallic or oxide superconductors (critical current behaviour, soldered joints, structural studies); 3) Magnet technology (large magnets for thermonuclear fusion devices; magnets for particle accelerators and medical devices); 4) Magnetic levitation and superconductivity; 5) Cryogenics; 6) Energy storage systems using superconducting coils (SMES); 7) Superconducting power transmission cables, switches, transformers, and generator systems for power plant; 8) Supporting activities, industrial aspects, patents. There are thirty-eight records in the ENERGY database relating to individual conference papers. (MM) [de

Chemical casting of high-Tc superconducting BiSCCO

International Nuclear Information System (INIS)

Toth, L.E.; Das, B.N.; Rayne, R.J.; Bender, B.A.; Lechter, W.L.; Hoff, H.A.; Osofsky, M.S.; Soulen, R.J. Jr.

1989-01-01

BiSCCO has been successfully cast into a number of useful shapes. This casting process differs significantly from traditional casting in that the process includes a change in the oxygen content of the melt. A heat treatment is required to restore the original chemistry, properly form the BiSCCO crystal structure and develop the superconducting properties. This paper emphasizes the microstructures of as-cast and heat treated BiSCCO. Casting causes considerable grain alignment of the BiSCCO platelets. The platelets align preferentially along the thermal gradients which exist during the solidification process

Role of oxygen and structural defects in properties of high-Tc superconductors

International Nuclear Information System (INIS)

Raveau, B.; Michel, C.; Hervieu, M.; Deslandes, F.; Maignan, A.

1989-01-01

Almost two years have passed since the discovery of superconductivity in mixed-valence copper oxides. A number of papers have now been published in this field. In spite of these numerous results, the mechanisms which govern superconductivity in those oxides are so far not understood. The authors discuss how the study of the crystal chemistry of these oxides suggests that two points are of capital importance for the appearance of superconductivity in those compounds: the low dimensionality of the structure and the mixed-valence of copper

High Tc superconductor-gallate crystal structures

International Nuclear Information System (INIS)

Gallagher, W.J.; Giess, E.A.; Gupta, A.; Laibowitz, R.B.; O'Sullivan, E.J.; Sandstrom, R.L.

1990-01-01

This patent describes a superconductive combination. It comprises a crystalline gallate layer, including a rare earth element or another element selected from the group consisting of Y, La, Bi, and Sc, or combinations of a rare earth element and at least one of the another elements. A superconductive layer thereon, the superconductive layer having a transition temperature in excess of 77 degrees K. and being an oxide material having Cu-O planes whose Cu and O atoms align with Ga and O atoms in the gallate layer

The study on a new superconductor (oxide Ba-Y-Cu) with high critical temperature Tc by positron annihilation

International Nuclear Information System (INIS)

Zhang Caigu; Yu Zhuxing; Wang Zhu; Huang Zhe; Zhou Jun

1987-01-01

The study on a new superconductor oxide Ba-Y-Cu with high critical temperature Tc is described. The experimental results show that positron lifetime reducing reflects variable curve of resistance with temperature. A peak of positron lifetime is appeared at critical temperature

Effect of disorder on the superconducting properties of materials

International Nuclear Information System (INIS)

Brouers, F.; Derenne, M.

1982-01-01

The effect of the variation of the density states at the Fermi level on the critical superconductivity temperature TC of transition metal compounds is studied. This paper suggests using the technique of calculating the 5-fold degenerate d-band density of states from a continued fraction extension of a tight-binding Green function to study the relative importance of one dimensionality chain coupling, three dimensional interactions and the effect of disorder on the electronic and superconducting properties of complex phase and in particular A15 phases. The first results obtained for A15 phases density of states indicate that an extension of the suggested method can be of great interest to analyze the effect of disorder on superconductivity properties of complex phases

Ab initio Eliashberg Theory: Making Genuine Predictions of Superconducting Features

Science.gov (United States)

Sanna, Antonio; Flores-Livas, José A.; Davydov, Arkadiy; Profeta, Gianni; Dewhurst, Kay; Sharma, Sangeeta; Gross, E. K. U.

2018-04-01

We present an application of Eliashberg theory of superconductivity to study a set of novel superconducting systems with a wide range of structural and chemical properties. The set includes three intercalated group-IV honeycomb layered structures, SH3 at 200 GPa (the superconductor with the highest measured critical temperature), the similar system SeH3 at 150 GPa, and a lithium doped mono-layer of black phosphorus. The theoretical approach we adopt is a recently developed, fully ab initio Eliashberg approach that takes into account the Coulomb interaction in a full energy-resolved fashion avoiding any free parameters like μ*. This method provides reasonable estimations of superconducting properties, including TC and the excitation spectra of superconductors.

Solubility study of Tc(IV) in a granitic water

International Nuclear Information System (INIS)

Liu, D.J.; Yao, J.; Wang, B.; Bruggeman, C.; Maes, N.

2007-01-01

The deep geological disposal of the high level radioactive wastes is expected to be a safe disposal method in most countries. The long-lived fission product 99 Tc is present in large quantities in nuclear wastes and its chemical behavior in aqueous solution is of considerable interest. Under oxidizing conditions technetium exists as the anionic species TcO 4 - whereas under the reducing conditions, expected to exist in a deep geological repository, it is generally predicted that technetium will be present as TcO 2 .nH 2 O. Hence, the mobility of Tc(IV) in reducing groundwater may be limited by the solubility of TcO 2 .nH 2 O under these conditions. Due to this fact it is important to investigate the solubility of TcO 2 .nH 2 O. The solubility determines the release of radionuclides from waste form and is used as a source term in radionuclide migration analysis in performance assessment of radioactive waste repository. Technetium(IV) was prepared by reduction of a technetate solution with Sn 2+ . The solubility of Tc(IV) has been determined in simulated groundwater and redistilled water under aerobic and anaerobic conditions. The effects of pH and CO 3 2- concentration of solution on solubility of Tc(IV) were studied. The concentration of total technetium and Tc(IV) species in the solutions were periodically determined by separating the oxidized and reduced technetium species using a solvent extraction procedure and counting the beta activity of the 99 Tc with a liquid scintillation counter. The experimental results show that the rate of oxidation of Tc(IV) in simulated groundwater and redistilled water is about (1.49 ∝ 1.86) x 10 -9 mol L -1 d -1 under aerobic conditions, while no Tc(IV) oxidation was detected in simulated groundwater and redistilled water under anaerobic conditions. Under aerobic or anaerobic conditions the solubility of Tc(IV) in simulated groundwater and redistilled water is equal on the whole after centrifugation or ultrafiltration. The

Foreword: Focus on Superconductivity in Semiconductors

Directory of Open Access Journals (Sweden)

Yoshihiko Takano

2008-01-01

Full Text Available Since the discovery of superconductivity in diamond, much attention has been given to the issue of superconductivity in semiconductors. Because diamond has a large band gap of 5.5 eV, it is called a wide-gap semiconductor. Upon heavy boron doping over 3×1020 cm−3, diamond becomes metallic and demonstrates superconductivity at temperatures below 11.4 K. This discovery implies that a semiconductor can become a superconductor upon carrier doping. Recently, superconductivity was also discovered in boron-doped silicon and SiC semiconductors. The number of superconducting semiconductors has increased. In 2008 an Fe-based superconductor was discovered in a research project on carrier doping in a LaCuSeO wide-gap semiconductor. This discovery enhanced research activities in the field of superconductivity, where many scientists place particular importance on superconductivity in semiconductors.This focus issue features a variety of topics on superconductivity in semiconductors selected from the 2nd International Workshop on Superconductivity in Diamond and Related Materials (IWSDRM2008, which was held at the National Institute for Materials Science (NIMS, Tsukuba, Japan in July 2008. The 1st workshop was held in 2005 and was published as a special issue in Science and Technology of Advanced Materials (STAM in 2006 (Takano 2006 Sci. Technol. Adv. Mater. 7 S1.The selection of papers describe many important experimental and theoretical studies on superconductivity in semiconductors. Topics on boron-doped diamond include isotope effects (Ekimov et al and the detailed structure of boron sites, and the relation between superconductivity and disorder induced by boron doping. Regarding other semiconductors, the superconducting properties of silicon and SiC (Kriener et al, Muranaka et al and Yanase et al are discussed, and In2O3 (Makise et al is presented as a new superconducting semiconductor. Iron-based superconductors are presented as a new series of high-TC

Solubility study of Tc(Ⅳ) in a granitic water

International Nuclear Information System (INIS)

Liu Dejun; Yao Jun; Wang Bo

2008-01-01

The deep geological disposal of the high level radioactive wastes is expected to be a safe disposal method in most countries. The long-lived fission product 99 Tc is present in large quantities in nuclear wastes and its chemical behavior in aqueous solution is of considerable interest. Under oxidizing conditions technetium exists as the anionic species TcO 4 - whereas under the reducing conditions, expected to exist in a deep geological repository, it is generally predicted that technetium will be present as TcO 2 -nH 2 O. Hence, the mobility of Tc(Ⅳ) in reducing groundwater may be limited by the solubility of TcO 2 ·nH 2 O under these conditions. Due to this fact it is important to investigate the solubility of TcO 2 ·nH 2 O. The solubility determines the release of radionuclides from waste form and is used as a source term in radionuclide migration analysis in performance assessment of radioactive waste repository. Technetium (Ⅳ) was prepared by reduction of a technetate solution with Sn 2+ . The solubility of Tc(Ⅳ) has been determined in simulated groundwater and redistilled water under aerobic and anaerobic conditions. The effects of pH and CO 3 2- concentration of solution on solubility of Tc(Ⅳ) were studied. The concentration of total technetium and Tc(Ⅳ) species in the solutions were periodically determined by separating the oxidized and reduced technetium species using a solvent extraction procedure and counting the beta activity of the 99 Tc with a liquid scintillation counter. The experimental results show that the rate of oxidation of Tc(Ⅳ) in simulated groundwater and redistilled water is about (1.49-1.86)x10 -9 mol·L -1 d -1 under aerobic conditions, while no Tc(Ⅳ) oxidation was detected in simulated groundwater and redistilled water under anaerobic conditions. Under aerobic or anaerobic conditions the solubility of Tc(Ⅳ) in simulated groundwater and redistilled water is equal on the whole after centrifugation or ultrafiltration. The

Trapped magnetic field of a superconducting bulk magnet in high- Tc RE-Ba-Cu-O

International Nuclear Information System (INIS)

Fujimoto, Hiroyuki; Yoo, Sang Im; Higuchi, Takamitsu; Nakamura, Yuichi; Kamijo, Hiroki; Nagashima, Ken; Murakami, Masato

1999-01-01

Superconducting magnets made of high-T c superconductors are promising for industrial applications. It is well known that REBa 2 Cu 3 O 7-x and LRE (light rare-earth) Ba 2 Cu 3 O 7-x superconductors prepared by melt processes have a high critical current density, J c , at 77 K and high magnetic fields. Therefore, the materials are very prospective for high magnetic field application as a superconducting permanent/bulk magnet with liquid-nitrogen refrigeration. LREBaCuO bulks, compared with REBaCuO bulks, exhibit a larger J c in high magnetic fields and a much improved irreversibility field, H irr , at 77 K. In this study, we discuss the possibility and trapped field properties of a superconducting bulk magnet, as well as the melt processing for bulk superconductors and their characteristic superconducting properties. One of the applications is a superconducting magnet for the future magnetically levitated (Maglev) train

Crystal layered structure and superconducting high-Tc behaviour of the mercurocuprates

International Nuclear Information System (INIS)

Kuzemsky, A.L.; Kuzemskaya, I.G.; Cheglokov, A.A.

1998-10-01

The high-T c superconducting behaviour of the mercurocuprate family HgBa 2 Ca n-1 Cu n O 2n+2+δ was analyzed from the point of view of their layered crystal structure. A dependence of superconducting critical temperature for different members of mercurocuprate family was studied in terms of phenomenological model of layered superconductors. The redistribution of charge was taken into account. This leads to an observable nonmonotonic ''bell''-shaped dependence of T c (n) with a maximum at n=3 and provides a quantitative explanation of the experiments. It was shown that the correlations between the copper valence, lattice parameters, extra oxygen contents and number of layers are essential factors for the physical behaviour and HTSC characterization of the mercurocuprates. (author)

Lead-doped electron-beam-deposited Bi-Sr-Ca-Cu-O superconducting thin films

Energy Technology Data Exchange (ETDEWEB)

Agnihotry, S.A.; Saini, K.K.; Kant, C.; Sharma, C.P.; Ekbote, S.N.; Asthana, P.; Nagpal, K.C.; Chandra, S. (National Physical Lab., New Delhi (India))

1991-03-20

Superconducting thin films of the lead-doped Bi-Sr-Ca-Cu-O system have been prepared on (100) single-crystal SrTiO{sub 3} substrates by an electron beam deposition technique using a single sintered pellet as the evaporation source. As-deposited films are amorphous and non-superconducting; post-deposition annealing at an optimized temperature in air has been found to result in crystalline and superconducting films. The superconducting characteristics of the films have been observed to be sensitive not only to the duration and temperature of post-deposition annealing but also to the lead content and the sintering parameters for the pellet to be used as the evaporation source. A pellet with nominal composition Bi{sub 3}Pb{sub 1}Sr{sub 3}Ca{sub 3}Cu{sub 4}O{sub y} that had been sintered for 200 h zero resistivity Tc{sup 0}=112 K. However, films deposited using such a pellet as the evaporation source had Tc{sup 0} {approx equal} 73-78 K, as had the films deposited from a pellet without any lead. We investigated systematically films deposited from pellets with more lead and sintered for different durations. It is evident from these investigations that pellets with nominal composition Bi{sub 3}Pb{sub 2}Sr{sub 3}Ca{sub 3}Cu{sub 4}O{sub y}, i.e. with an excess of lead, and sintered for about 75 h when used as the evaporation source yield films with Tc{sup 0} {approx equal} 100 K when annealed between 835 and 840deg C for an optimized long duration. The films are characterized by X-ray diffraction and energy-dispersive spectroscopy techniques and have been found to be highly c axis oriented. The effect of lead in promoting a high Tc{sup 0}=110 K phase seems to be similar to that in bulk ceramics. (orig.).

Applied superconductivity handbook on devices and applications

CERN Document Server

2015-01-01

This wide-ranging presentation of applied superconductivity, from fundamentals and materials right up to the latest applications, is an essential reference for physicists and engineers in academic research as well as in the field. Readers looking for a systematic overview on superconducting materials will expand their knowledge and understanding of both low and high Tc superconductors, including organic and magnetic materials. Technology, preparation and characterization are covered for several geometries, but the main benefit of this work lies in its broad coverage of significant applications in power engineering or passive devices, such as filter and antenna or magnetic shields. The reader will also find information on superconducting magnets for diverse applications in mechanical engineering, particle physics, fusion research, medicine and biomagnetism, as well as materials processing. SQUIDS and their usage in medicine or geophysics are thoroughly covered as are applications in quantum metrology, and, las...

Magnetic and superconducting phase diagram of Nb/Gd/Nb trilayers

Science.gov (United States)

Khaydukov, Yu. N.; Vasenko, A. S.; Kravtsov, E. A.; Progliado, V. V.; Zhaketov, V. D.; Csik, A.; Nikitenko, Yu. V.; Petrenko, A. V.; Keller, T.; Golubov, A. A.; Kupriyanov, M. Yu.; Ustinov, V. V.; Aksenov, V. L.; Keimer, B.

2018-04-01

We report on a study of the structural, magnetic, and superconducting properties of Nb (25 nm ) /Gd (df) /Nb (25 nm ) hybrid structures of a superconductor/ ferromagnet (S/F) type. The structural characterization of the samples, including careful determination of the layer thickness, was performed using neutron and x-ray scattering with the aid of depth-sensitive mass spectrometry. The magnetization of the samples was determined by superconducting quantum interference device magnetometry and polarized neutron reflectometry, and the presence of magnetic ordering for all samples down to the thinnest Gd(0.8 nm) layer was shown. The analysis of the neutron spin asymmetry allowed us to prove the absence of magnetically dead layers in junctions with Gd interlayer thickness larger than one monolayer. The measured dependence of the superconducting transition temperature Tc(df) has a damped oscillatory behavior with well-defined positions of the minimum at df=3 nm and the following maximum at df=4 nm, in qualitative agreement with prior work [J. S. Jiang et al., Phys. Rev. B 54, 6119 (1996), 10.1103/PhysRevB.54.6119]. We use a theoretical approach based on the Usadel equations to analyze the experimental Tc(df) dependence. The analysis shows that the observed minimum at df=3 nm can be described by the so-called zero to π phase transitions of highly transparent S/F interfaces with a superconducting correlation length ξf≈4 nm in Gd. This penetration length is several times higher than for strong ferromagnets like Fe, Co, and Ni, thus simplifying the preparation of S/F structures with df˜ξf which are of topical interest in superconducting spintronics.

Midwest Superconductivity Consortium: 1995 Progress report

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-01-01

The mission of the Midwest Superconductivity Consortium, MISCON, is to advance the science and understanding of high Tc superconductivity. During the past year, 26 projects produced over 133 talks and 127 publications. Three Master`s Degrees and 9 Doctor`s of Philosophy Degrees were granted to students working on MISCON projects. Group activities and interactions involved 2 MISCON group meetings (held in January and July); the third MISCON Summer School held in July; 12 external speakers; 81 collaborations (with universities, industry, Federal laboratories, and foreign research centers); and 54 exchanges of samples and/or measurements. Research achievements this past year focused on understanding the effects of processing phenomena on structure-property interrelationships and the fundamental nature of transport properties in high-temp superconductors.

Midwest Superconductivity Consortium: 1995 Progress report

International Nuclear Information System (INIS)

1996-01-01

The mission of the Midwest Superconductivity Consortium, MISCON, is to advance the science and understanding of high Tc superconductivity. During the past year, 26 projects produced over 133 talks and 127 publications. Three Master's Degrees and 9 Doctor's of Philosophy Degrees were granted to students working on MISCON projects. Group activities and interactions involved 2 MISCON group meetings (held in January and July); the third MISCON Summer School held in July; 12 external speakers; 81 collaborations (with universities, industry, Federal laboratories, and foreign research centers); and 54 exchanges of samples and/or measurements. Research achievements this past year focused on understanding the effects of processing phenomena on structure-property interrelationships and the fundamental nature of transport properties in high-temp superconductors

The Geochemical Behaviour of Tc, Np, and Pu in Spent Nuclear Fuel in an Oxidizing Environment

Energy Technology Data Exchange (ETDEWEB)

Buck, Edgar C.; Hanson, Brady D.; McNamara, Bruce K.; R. Giere and P. Stille

2004-10-01

Studies at the Nopal and Shinkolowbwe uranium deposits show that the primary uraninite (UO2) altered to a suite of secondary uranyl minerals similar to those observed in corrosion tests with uranium oxide . Although the Nopal I deposit tells us something about the possible fate of uranium, it tells us little about the likely fate of the important long-lived radionuclides; iodine (129I), cesium (135Cs), technetium (99Tc), neptunium (237Np), and plutonium (239Pu). Most performance assessment (PA) models, assume conservatively, that as the UO2 matrix corrodes, the key radionuclides (129I, 99Tc, 237Np, and 239Pu) will be released congruently. In so doing, these PA models force increased reliance on human engineered barriers.

The Geochemical Behavior of Tc, Np, and Pu in Spent Nuclear Fuel in an Oxidizing Environment

International Nuclear Information System (INIS)

Buck, Edgar C.; Hanson, Brady D.; McNamara, Bruce K.; R. Giere; P. Stille

2004-01-01

Studies at the Nopal and Shinkolowbwe uranium deposits show that the primary uraninite (UO2) altered to a suite of secondary uranyl minerals similar to those observed in corrosion tests with uranium oxide . Although the Nopal I deposit tells us something about the possible fate of uranium, it tells us little about the likely fate of the important long-lived radionuclides; iodine (129I), cesium (135Cs), technetium (99Tc), neptunium (237Np), and plutonium (239Pu). Most performance assessment (PA) models, assume conservatively, that as the UO2 matrix corrodes, the key radionuclides (129I, 99Tc, 237Np, and 239Pu) will be released congruently. In so doing, these PA models force increased reliance on human engineered barriers

Superconducting Technology Assessment

National Research Council Canada - National Science Library

2005-01-01

This Superconducting Technology Assessment (STA) has been conducted by the National Security Agency to address the fundamental question of a potential replacement for silicon complementary metal oxide semiconductor (CMOS...

Hyperfine interactions associated with iron substitute superconducting oxides

International Nuclear Information System (INIS)

Ellis, D.E.; Dunlap, B.D.; Saitovitch, E.B.; Azevedo, I.S.; Scorzelli, R.B.; Kimball, C.W.

1988-01-01

Theoretical and experimental Moessbauer spectroscopy studies have been made concerning charge and spin densities and magnetic hyperfine fields (H hf in iron-substituted superconducting oxides. Calculations were carried out in the self-consistent-field embedded cluster model using local density theory (SCF-Xα) with a variational atomic orbital basis. Spectral densities and changes in charge and spin density were monitored around neighboring Cu sites, as well as Fe impurity site, in La 2 Cu 1-x Fe x O 4 and YBa 2 Cu 3-x Fe x O 7-y compounds. Moessbauer isomer shifts (IS), quadrupole splittings (QS) and H hf are obtained by fitting multiline models to the observed spectra and are compared with SCF-Xα results for specific lattice sites. The influence of oxygen vacancies and partial oxygen disorder is modelled and compared with the experimental data on variable oxygen content and disorder. (author)

Manufacturing of superconductive silver/ceramic composites

DEFF Research Database (Denmark)

Seifi, Behrouz; Bech, Jakob Ilsted; Eriksen, Morten

2000-01-01

Manufacturing of superconducting metal/ceramic composites is a rather new discipline within materials forming processes. High Temperature SuperConductors, HTSC, are manufactured applying the Oxide-Powder-In-Tube process, OPIT. A ceramic powder containing lead, calcium, bismuth, strontium, and cop......Manufacturing of superconducting metal/ceramic composites is a rather new discipline within materials forming processes. High Temperature SuperConductors, HTSC, are manufactured applying the Oxide-Powder-In-Tube process, OPIT. A ceramic powder containing lead, calcium, bismuth, strontium...

Formation of high-Tc YBa2Cu3O(7-delta) films on Y2BaCuO5 substrate

Science.gov (United States)

Wang, W. N.; Lu, H. B.; Lin, W. J.; Yao, P. C.; Hsu, H. E.

1988-07-01

High-Tc superconducting YBa2Cu3O(7-delta) films have been successfully prepared on green Y2BaCuO5 (2115) ceramic substrate. The films have been formed by RF sputtering and screen printing with post annealing at 925 C. Regarding superconducting features, the sharp resistivity drop with Tc onset around 95 K (midpoint 84 K) and 99 K (midpoint 89 K) has been observed for RF sputtered and printed films respectively. Both films show the excellent adhesion towards the 2115 substrate. Powder X-ray diffraction profiles indicate a majority of 1237 phase with preferred orientation for RF sputtered thin film.

High-Tc Superconducting Thick-Film Spiral Magnet: Development and Characterization of a Single Spiral Module

National Research Council Canada - National Science Library

McGinnis, W

1997-01-01

The objective of this project was to make characterized and numerically model prototype modules of a new type of superconducting electromagnet based on stacked spirals of superconducting thick films...

Superconductivity in Pd-Intercalated Ternary Rare-Earth Polychalcogenide NdSeTe_2

International Nuclear Information System (INIS)

Wang Pei-Pei; Xue Mian-Qi; Long Yu-Jia; Zhao Ling-Xiao; Cai Yao; Yang Huai-Xin; Li Jian-Qi; Ren Zhi-An; Chen Gen-Fu

2015-01-01

We synthesize a set of Pd-doped polycrystalline samples Pd_xNdSeTe_2 and measure their physical properties. Compared with pure NdSeTe_2, the charge density wave (CDW) order is continuously suppressed with the Pd-intercalation. Bulk superconductivity first appears at x = 0.06 with T_c nearly 2.5K, coexisting with a CDW transition at 176K. Further Pd-doping enhances T_c, until it reaches the maximum value 2.84K at x=0.1, meanwhile the CDW transition vanishes. The upper critical field for the optimal doping sample Pd_0_._1NdSeTe_2 is determined from the R-H measurement, which is estimated to be 0.6 T. These results provide another kind of ideal compound for studying the interplay between CDW and superconductivity systematically. (paper)

First-Principles Study of Superconductivity in Ultra- thin Pb Films

Science.gov (United States)

Noffsinger, Jesse; Cohen, Marvin L.

2010-03-01

Recently, superconductivity in ultrathin layered Pb has been confirmed in samples with as few as two atomic layers [S. Qin, J. Kim, Q. Niu, and C.-K. Shih, Science 2009]. Interestingly, the prototypical strong-coupling superconductor exhibits different Tc's for differing surface reconstructions in samples with only two monolayers. Additionally, Tc is seen to oscillate as the number of atomic layers is increased. Using first principles techniques based on Wannier functions, we analyze the electronic structure, lattice dynamics and electron-phonon coupling for varying thicknesses and surface reconstructions of layered Pb. We discuss results as they relate to superconductivity in the bulk, for which accurate calculations of superconducting properties can be compared to experiment [W. L. McMillan and J.M. Rowell, PRL 1965]. This work was supported by National Science Foundation Grant No. DMR07-05941, the U.S. Department of Energy under Contract No. DE-AC02-05CH11231. Computational resources have been provided by the Lawrencium computational cluster resource provided by the IT Division at the Lawrence Berkeley National Laboratory (Supported by the Director, Office of Science, Office of Basic Energy Sciences, of the U.S. Department of Energy under Contract No. DE-AC02-05CH11231)

The new superconductors. Les nouveaux supraconducteurs

Energy Technology Data Exchange (ETDEWEB)

Gervais, F

1991-01-01

The first half of the book is a scanning of superconductivity from 1911 to our days, with Bardeen-Cooper-Schrieffer theory in 1957, with the concept of phonons and the importance of the Brillouin zone, with the discovery of high-tc superconductors oxides by Bednortz and Mueller in 1986. The second part is dealing with physical investigation means for trying to explain this high-tc superconductivity.

Dependences on RE of superconducting properties of transition metal co-doped (Ca, RE)FeAs_2 with RE = La–Gd

International Nuclear Information System (INIS)

Yakita, H.; Ogino, H.; Sala, A.; Okada, T.; Yamamoto, A.; Kishio, K.; Iyo, A.; Eisaki, H.; Shimoyama, J.

2015-01-01

Highlights: • We synthesized Co or Ni co-doped (Ca, RE)FeAs_2 with RE = La–Gd. • Co or Ni co-doping improved superconducting properties of all (Ca, RE)FeAs_2 samples. • T_c of (Ca, RE)FeAs_2 decreased with decreasing ionic radii of RE"3"+. • Eu doped samples showed exceptionally low T_c and long interlayer distance. • Long interlayer distance of Eu doped samples suggested co-existence of Eu"2"+ and Eu"3"+. - Abstract: Dependence of superconducting properties of (Ca, RE)(Fe, TM)As_2 [(Ca, RE)112, TM: Co, Ni)] on RE elements (RE = La–Gd) was systematically investigated. Improvement of superconducting properties by Co or Ni co-doping was observed for all (Ca, RE)112, which is similar to Co-co-doped (Ca, La)112 or (Ca, Pr)112. T_c of Co-co-doped samples decreased from 38 K for RE = La to 29 K for RE = Gd with decreasing ionic radii of RE"3"+. However, Co-co-doped (Ca, Eu)112 showed exceptionally low T_c = 21 K probably due to the co-existence of Eu"3"+ and Eu"2"+ suggested by longer interlayer distance d_F_e_–_F_e of (Ca, Eu)112 than other (Ca, RE)112.

Approaches to the high Tc superconductivity in β-(BEDT-TTF)2X structure

International Nuclear Information System (INIS)

Tokumoto, M.; Anzai, H.; Murata, K.; Bando, H.; Kajimura, K.; Morita, S.; Ishiguro, T.; Saito, G.

1987-01-01

Experimental strategies to realize a high T c superconductivity comparable with the high-T c state of β-(BEDT-TTF) 2 I 3 by means of modification of the β-(BEDT-TTF) 2 X structure are discussed. Some experimental results related to such trials are presented, including the effect of anion alloying and the effect of solvent used for crystal growth on the superconductivity in β-(BEDT-TTF) 2 I 3 . (orig.)

Synthesis and characterization of technetium(III) complexes with nitrogen heterocycles by O atom transfer from oxotechnetium(V) cores. Crystal structures of mer-[Cl3(pic)3Tc] and mer-[Cl3(pic)(PMe2Ph)2Tc] (pic = 4-picoline). Electrochemical parameters fore the reduction of TcII, TcIII, and TcIV

International Nuclear Information System (INIS)

Lu, Jun; Yamano, Akahito; Clarke, M.J.

1990-01-01

The combination of pyridine ligands, (OCl 4 Tc) - , and O atom acceptors of different cone angles, such as PMe 2 Ph or PPh 3 , results in Tc III complexes that vary in the coordination of the phosphine ligand. The compounds mer[Cl 3 (4-picoline) 3 Tc] and mer-(Cl 3 (4-picoline)(PMe 2 Ph) 2 Tc) have been obtained in good yield and have been characterized spectroscopically and by single-crystal x-ray diffraction. The crystal structure data are reported. Linear correlations of technetium reduction potentials in DMF with electrochemical ligand additivity parameters (E L 's) have been obtained for the Tc II,I , Tc III,II , and Tc IV,III couples. The slope and intercept (S M , I M ) pairs for each technetium oxidation-reduction couple, respectively, are (1.39, -2.07), (1.29, -0.91), and (1.00, 0.65). 32 refs., 3 figs., 6 tabs

Uniaxial compression on the superconductivity of {beta}-BDA-TTP salts

Energy Technology Data Exchange (ETDEWEB)

Ito, Hiroshi; Ishihara, Tetsuo; Tanaka, Hisaaki; Kuroda, Shin-ichi [Department of Applied Physics, Nagoya University, Chikusa, Nagoya, 464-8603 (Japan); Yamada, Jun-ichi [Department of Material Science, University of Hyogo, 3-2-1 Kouto, Kamigori-cho, Hyogo 678-1297 (Japan)], E-mail: ito@nuap.nagoya-u.ac.jp

2008-10-15

The {beta}-type BDA-TTP superconductors attract attention due to the high transition temperature Tc at ambient pressure for organic superconductors. In order to get insight into the superconductivity in terms of the dimerized anisotropic triangular lattice model, Tc of {beta}-(BDA-TTP){sub 2}X [X = SbF{sub 6}, X = AsF{sub 6}] is studied under uniaxial compression by resistivity measurements. Under compression parallel to the donor stack, Tc increases gradually up to 3 (X = SbF{sub 6}), 5 (X = AsF{sub 6}) kbar, and decreases under further piston pressure. Under compression perpendicular to the donor stack, Tc decreases gradually up to 2.5 (X = SbF{sub 6}), 4 (X = AsF{sub 6}) kbar and then decreases rapidly under further pressure. Only for X = AsF{sub 6}, a Tc minimum at 3 kbar is found for both direction. These trends in Tc are understood as an interplay between the enhancement of antiferromagnetic spin fluctuation and frustration on the triangular lattice. By the interplane compression, Tc increased by 0.5 K up to 2 kbar for both salts, demonstrating the importance of the interlayer interaction.

Uniaxial compression on the superconductivity of β-BDA-TTP salts

International Nuclear Information System (INIS)

Ito, Hiroshi; Ishihara, Tetsuo; Tanaka, Hisaaki; Kuroda, Shin-ichi; Yamada, Jun-ichi

2008-01-01

The β-type BDA-TTP superconductors attract attention due to the high transition temperature Tc at ambient pressure for organic superconductors. In order to get insight into the superconductivity in terms of the dimerized anisotropic triangular lattice model, Tc of β-(BDA-TTP) 2 X [X = SbF 6 , X = AsF 6 ] is studied under uniaxial compression by resistivity measurements. Under compression parallel to the donor stack, Tc increases gradually up to 3 (X = SbF 6 ), 5 (X = AsF 6 ) kbar, and decreases under further piston pressure. Under compression perpendicular to the donor stack, Tc decreases gradually up to 2.5 (X = SbF 6 ), 4 (X = AsF 6 ) kbar and then decreases rapidly under further pressure. Only for X = AsF 6 , a Tc minimum at 3 kbar is found for both direction. These trends in Tc are understood as an interplay between the enhancement of antiferromagnetic spin fluctuation and frustration on the triangular lattice. By the interplane compression, Tc increased by 0.5 K up to 2 kbar for both salts, demonstrating the importance of the interlayer interaction.

Uniaxial compression on the superconductivity of β-BDA-TTP salts

Science.gov (United States)

Ito, Hiroshi; Ishihara, Tetsuo; Tanaka, Hisaaki; Kuroda, Shin-ichi; Yamada, Jun-ichi

2008-10-01

The β-type BDA-TTP superconductors attract attention due to the high transition temperature Tc at ambient pressure for organic superconductors. In order to get insight into the superconductivity in terms of the dimerized anisotropic triangular lattice model, Tc of β-(BDA-TTP)2X [X = SbF6, X = AsF6] is studied under uniaxial compression by resistivity measurements. Under compression parallel to the donor stack, Tc increases gradually up to 3 (X = SbF6), 5 (X = AsF6) kbar, and decreases under further piston pressure. Under compression perpendicular to the donor stack, Tc decreases gradually up to 2.5 (X = SbF6), 4 (X = AsF6) kbar and then decreases rapidly under further pressure. Only for X = AsF6, a Tc minimum at 3 kbar is found for both direction. These trends in Tc are understood as an interplay between the enhancement of antiferromagnetic spin fluctuation and frustration on the triangular lattice. By the interplane compression, Tc increased by 0.5 K up to 2 kbar for both salts, demonstrating the importance of the interlayer interaction.

Temperature-dependent transformation of the magnetic excitation spectrum on approaching superconductivity in Fe(1+y-x)(Ni/Cu)(x)Te(0.5)Se(0.5).

Science.gov (United States)

Xu, Zhijun; Wen, Jinsheng; Zhao, Yang; Matsuda, Masaaki; Ku, Wei; Liu, Xuerong; Gu, Genda; Lee, D-H; Birgeneau, R J; Tranquada, J M; Xu, Guangyong

2012-11-30

Spin excitations are one of the top candidates for mediating electron pairing in unconventional superconductors. Their coupling to superconductivity is evident in a large number of systems, by the observation of an abrupt redistribution of magnetic spectral weight at the superconducting transition temperature, T(c), for energies comparable to the superconducting gap. Here we report inelastic neutron scattering measurements on Fe-based superconductors, Fe(1+y-x)(Ni/Cu)(x)Te(0.5)Se(0.5) that emphasize an additional signature. The overall shape of the low energy magnetic dispersion changes from two incommensurate vertical columns at T≫T(c) to a distinctly different U-shaped dispersion at low temperature. Importantly, this spectral reconstruction is apparent for temperatures up to ~3T(c). If the magnetic excitations are involved in the pairing mechanism, their surprising modification on the approach to T(c) demonstrates that strong interactions are involved.

One- and two-dimensional sublattices as preconditions for high-Tc superconductivity

International Nuclear Information System (INIS)

Krueger, E.

1989-01-01

In an earlier paper it was proposed describing superconductivity in the framework of a nonadiabatic Heisenberg model in order to interprete the outstanding symmetry proper ties of the (spin-dependent) Wannier functions in the conduction bands of superconductors. This new group-theoretical model suggests that Cooper pair formation can only be mediated by boson excitations carrying crystal-spin-angular momentum. While in the three-dimensionally isotropic lattices of the standard superconductors phonons are able to transport crystal-spin-angular momentum, this is not true for phonons propagating through the one- or two-dimensional Cu-O sublattices of the high-T c compounds. Therefore, if such an anisotropic material is superconducting, it is necessarily higher-energetic excitations (of well-defined symmetry) which mediate pair formation. This fact is proposed being responsible for the high transition temperatures of these compounds. (author)

Tunneling observation at very low temperature of impurity bands within the gap of the Kondo superconducting system CuFe/Pb(T(K)>T(c))

International Nuclear Information System (INIS)

Dumoulin, Louis; Le Fur, Daniel

1976-01-01

Very low temperature superconducting tunneling experiments on CuFe(12.10 -6 ) backed by superconducting lead show a band of localized states next to the gap edge. There is no quantitative agreement with the perturbative approach of Mueller-Hartmann Zittartz in this system where the Kondo temperature is larger than the superconductive T(c) [fr

Superconducting properties of Zn and Al double-doped Mg1-x(Zn0.5Al0.5)xB2

DEFF Research Database (Denmark)

Xu, G.J.; Grivel, Jean-Claude; Abrahamsen, A.B.

2004-01-01

(XRD), ac susceptibility, magnetization and resistivity. The double doping leads to decreases in both the lattice parameters a and c, and the T-c decreases with increasing dopant content. A systematical comparison with Al doped- and Li, Al double doped MgB2 of structure, superconducting transition......A series of polycrystalline samples of Mg1-x(Zn0.5Al0.5)(x)B-2 (0less than or equal toxless than or equal to0.8) were prepared by solid state reaction method and their structure, superconducting transition temperature (T-c) and transport properties were investigated by means of X-ray diffraction...

Environmental conditions for the formation of insoluble Tc in water ponds located above paddy fields

International Nuclear Information System (INIS)

Ishii, Nobuyoshi; Koiso, Hiroyuki; Takeda, Hiroshi; Uchida, Shigeo

2008-01-01

Optimum conditions for the formation of insoluble Tc (Tc in >0.2 μm size fraction) were studied using a microcosm including water ponds above a paddy field to understand Tc behavior in such fields. In the microcosm, soluble TcO 4 - was converted to insoluble forms, but no changes in the form of Tc were observed in filtered microcosm samples which were microorganisms-free. The formation of insoluble Tc was inhibited by the addition of the antibiotic chloramphenicol. In addition, the reduction of soluble Tc(VII)O 4 - to low-valence oxide was not observed in the filtered microcosm samples, although reducing conditions were present. These results indicated that bacteria were involved in the formation of insoluble Tc. Since oxidizing conditions influence bacterial metabolism, the formation of insoluble Tc by bacteria was studied under aerobic and anaerobic conditions. The results showed that anaerobic conditions were favorable for the formation of insoluble Tc. In addition, the addition of formate as an electron donor to a microcosm sample facilitated the formation of insoluble Tc. The results suggested that insoluble Tc in the water ponds above paddy fields was caused by bacteria, which were shown to couple the oxidation of formate to the reduction of Tc(VII) during anaerobic respiration

Elliptical vortex and oblique vortex lattice in the FeSe superconductor based on the nematicity and mixed superconducting orders

Science.gov (United States)

Lu, Da-Chuan; Lv, Yang-Yang; Li, Jun; Zhu, Bei-Yi; Wang, Qiang-Hua; Wang, Hua-Bing; Wu, Pei-Heng

2018-03-01

The electronic nematic phase is characterized as an ordered state of matter with rotational symmetry breaking, and has been well studied in the quantum Hall system and the high-Tc superconductors, regardless of cuprate or pnictide family. The nematic state in high-Tc systems often relates to the structural transition or electronic instability in the normal phase. Nevertheless, the electronic states below the superconducting transition temperature is still an open question. With high-resolution scanning tunneling microscope measurements, direct observation of vortex core in FeSe thin films revealed the nematic superconducting state by Song et al. Here, motivated by the experiment, we construct the extended Ginzburg-Landau free energy to describe the elliptical vortex, where a mixed s-wave and d-wave superconducting order is coupled to the nematic order. The nematic order induces the mixture of two superconducting orders and enhances the anisotropic interaction between the two superconducting orders, resulting in a symmetry breaking from C4 to C2. Consequently, the vortex cores are stretched into an elliptical shape. In the equilibrium state, the elliptical vortices assemble a lozenge-like vortex lattice, being well consistent with experimental results.

Superconducting wires and methods of making thereof

Energy Technology Data Exchange (ETDEWEB)

Xu, Xingchen; Sumption, Michael D.; Peng, Xuan

2018-03-13

Disclosed herein are superconducting wires. The superconducting wires can comprise a metallic matrix and at least one continuous subelement embedded in the matrix. Each subelement can comprise a non-superconducting core, a superconducting layer coaxially disposed around the non-superconducting core, and a barrier layer coaxially disposed around the superconducting layer. The superconducting layer can comprise a plurality of Nb.sub.3Sn grains stabilized by metal oxide particulates disposed therein. The Nb.sub.3Sn grains can have an average grain size of from 5 nm to 90 nm (for example, from 15 nm to 30 nm). The superconducting wire can have a high-field critical current density (J.sub.c) of at least 5,000 A/mm.sup.2 at a temperature of 4.2 K in a magnetic field of 12 T. Also described are superconducting wire precursors that can be heat treated to prepare superconducting wires, as well as methods of making superconducting wires.

A superconducting battery material: Lithium gold boride (LiAu3B)

Science.gov (United States)

Aydin, Sezgin; Şimşek, Mehmet

2018-04-01

The superconducting and potential cathode material properties of ternary boride of LiAu3B have been investigated by density functional first principles. The Li-concentration effects on the actual electronic and structural properties, namely the properties of LixAu9B3 (x = 0, 1, 2) sub-systems are studied. It is remarkably shown that the existence of Li-atoms has no considerable effect on the structural properties of Au-B skeleton in LiAu3B. Then, it can be offered as a potential cathode material for Li-ion batteries with the very small volume deviation of 0.42%, and the suitable average open circuit voltage of ∼1.30 V. Furthermore, the vibrational and superconducting properties such as electron-phonon coupling constant (λ) and critical temperature (Tc) of LiAu3B are studied. The calculated results suggest that LiAu3B should be a superconductor with Tc ∼5.8 K, also.

New bisaminoethanethiol (BAT) ligands which form two interconvertible Tc-99m complexes

International Nuclear Information System (INIS)

Oya, Shunichi; Kung, Mei-Ping; Frederick, Dana; Kung, Hank F.

1995-01-01

Most commonly used radiopharmaceuticals in diagnostic nuclear medicine are labeled with Tc-99m. This is due to its superior physical characteristics (T (1(2)) = 6 h and gamma energy 140 KeV) and convenient availability from the 99 Mo/ 99mm Tc generator. In an attempt to fine tune the properties of Tc-99m complexes, the synthesis and radiolabeling of two novel N 2 S 2 ligands, N,-2-mercaptobenzyl-N'-(1-oxo-2-mercapto-2-methyl)propyl ethylenediamine,8, and N,-2-methylthiobenzyl-N'-(1-oxo-2-mercapto-2-methyl)propyl ethylenediamine, 11, with an ionizable SH or unionizable SMe group, respectively, for the formation of complexes with Tc v O center cores, have been examined. Both ligands initially formed one apparently stable, lipophilic and neutral complex (HPLC, Rt = 7 min, reverse-phase column, acetonitrile: buffer, pH 7.0; (55(45)); V/V; partition coefficient between 1-octanol and buffer of 410 and 335, respectively) with [ 99m Tc]pertechnetate in the presence of stannous chloride. After treatment with a reducing agent, NaCNBH 3 , the initial [ 99m Tc]8 and 11 complexes were reduced; the reduced complexes were less lipophilic (shorter retention time, Rt = 5 min, on the same reversed phase HPLC). However, only the oxidized form showed sufficient stability. The reduced forms of both [ 99m Tc]8 and 11 were readily and completely converted back to the oxidized forms by a stream of air. Biodistribution studies in rats demonstrated that the [ 99m Tc]8 (oxidized form) penetrated the blood-brain barrier (0.67% dose/organ at 2 min postinjection), but washed out from the brain quickly (0.29% dose/organ at 30 min postinjection). On the contrary, [ 99m Tc]11 (oxidized form) did not show any brain uptake (0.03% dose/organ at 2 min postinjection), despite its higher lipophilicity. The disparity between these two Tc-99m complexes may be related to the relative instability of [ 99m Tc]11 (oxidized form) by the introduction of the unionizable methylated thiol group as one of the donor

Superconductivity applications for infrared and microwave devices II; Proceedings of the Meeting, Orlando, FL, Apr. 4, 5, 1991

Science.gov (United States)

Heinen, Vernon O.; Bhasin, Kul B.

Topics discussed include thin-film technology, microwave transmission lines and resonators, microwave devices and circuits, infrared detectors and bolometers, and superconducting junctions. Papers are presented on possible enhancement in bolometric response using free-standing film of YBa2Cu3O(x), aging and surface instability in high-Tc superconductors, epitaxial Tl2Ba2CaCu2O8 thin films on LaAlO3 and their microwave device properties, the performance of stripline resonators using sputtered YBCO films, and a coplanar waveguide microwave filter of YBa2Cu3O7. Attention is also given to the performance characteristics of Y-Ba-Cu-O microwave superconducting detectors, high-Tc bolometer developments for planetary missions, infrared detectors from YBaCuO thin films, high-temperature superconductor junction technology, and submillimeter receiver components using superconducting tunnel junctions. (For individual items see A93-27244 to A93-27248)

Giant Overlap between the Magnetic and Superconducting Phases of CeAu_{2}Si_{2} under Pressure

Directory of Open Access Journals (Sweden)

Z. Ren

2014-09-01

Full Text Available High pressure provides a powerful means for exploring unconventional superconductivity which appears mostly on the border of magnetism. Here, we report the discovery of pressure-induced heavy-fermion superconductivity up to 2.5 K in the antiferromanget CeAu_{2}Si_{2} (T_{N}≈10  K. Remarkably, the magnetic and superconducting phases are found to overlap across an unprecedentedly wide pressure interval from 11.8 to 22.3 GPa. Moreover, both the bulk T_{c} and T_{M} are strongly enhanced when increasing the pressure from 16.7 to 20.2 GPa. T_{c} reaches a maximum at a pressure slightly below p_{c}≈22.5  GPa, at which magnetic order disappears. Furthermore, the scaling behavior of the resistivity provides evidence for a continuous delocalization of the Ce 4f electrons associated with a critical end point lying just above p_{c}. We show that the maximum T_{c} of CeAu_{2}Si_{2} actually occurs at almost the same unit-cell volume as that of CeCu_{2}Si_{2} and CeCu_{2}Ge_{2}, and when the Kondo and crystal-field splitting energies become comparable. Dynamical mean-filed theory calculations suggest that the peculiar behavior in pressurized CeAu_{2}Si_{2} might be related to its Ce-4f orbital occupancy. Our results not only provide a unique example of the interplay between superconductivity and magnetism, but also underline the role of orbital physics in understanding Ce-based heavy-fermion systems.

Pretreatment of Tc-Containing Waste and Its Effect on Tc-99 Leaching From Grouts

International Nuclear Information System (INIS)

Aloy, Albert; Kovarskaya, Elena N.; Harbour, John R.; Langton, Christine A.; Holtzscheiter, E. William

2007-01-01

A salt solution (doped with Tc-99), that simulates the salt waste stream to be processed at the Saltstone Production Facility, was immobilized in grout waste forms with and without (1) ground granulated blast furnace slag and (2) pretreatment with iron salts. The degree of immobilization of Tc-99 was measured through monolithic and crushed grout leaching tests. Although Fe (+2) was shown to be effective in reducing Tc-99 to the +4 state, the strong reducing nature of the blast furnace slag present in the grout formulation dominated the reduction of Tc-99 in the cured grouts. An effective diffusion coefficient of 4.75 x 10 -12 (Leach Index of 11.4) was measured using the ANSI/ANS-16.1 protocol. The leaching results show that, even in the presence of a concentrated salt solution, blast furnace slag can effectively reduce pertechnetate to the immobile +4 oxidation state. The measured diffusivity was introduced into a flow and transport model (PORFLOW) to calculate the release of Tc-99 from a Saltstone Vault as a function of hydraulic conductivity of the matrix. (authors)

Unconventional superconductivity in CaFe0.85Co0.15AsF evidenced by torque measurements

Science.gov (United States)

Xiao, Hong; Li, X. J.; Mu, G.; Hu, T.

Out-of-plane angular dependent torque measurements were performed on CaFe0.85Co0.15AsF single crystals. Abnormal superconducting fluctuation, featured by enhanced diamagnetism with magnetic field, is detected up to about 1.5 times superconducting transition temperature Tc. Compared to cuprate superconductors, the fluctuation effect in iron-based superconductor is less pronounced. Anisotropy parameter γ is obtained from the mixed state torque data and it is found that γ shows both magnetic field and temperature depenence, pointing to multiband superconductivity. The temperature dependence of penetration depth λ (T) suggests unconventional superconductivity in CaFe0.85Co0.15AsF.

Microstructures and superconducting properties of Y-Ba-Cu and Bi-Sr-Ca-Cu oxide wires and coils prepared by the explosive compaction technique

International Nuclear Information System (INIS)

Hagino, S.; Suzuki, M.; Takeshita, T.; Takashima, K.; Tonda, H.

1989-01-01

It has been shown that explosive compaction technique can be used to densify metal, and ceramics powders and their mixtures. The authors discuss how they applied this technique to produce silver sheathed superconducting oxide wires and coils (Y-B-Cu-O and Bi-Sr-Ca-Cu-O). The wires and coils to be compacted were placed into metal tube and the tube was filled with SiC powder as a pressure propagating medium and the tube was compacted by a cylindrically axisymmetric method. The wires and coils compacted were then heat-treated in order to improve grain boundary connections of superconducting oxide crystalline grains. The oxide cores heat-treated were seen to be very dense, and a part of a Y-Ba-Cu oxide coil which was heat-treated optimally was found to have a critical current density higher than 13,000A/cm 2 at 77K

An investigation of texturing by magnetic and mechanical techniques in high critical temperature superconducting ceramics

International Nuclear Information System (INIS)

Deschanels, X.

1992-11-01

The principal goal of this work is to quantify the influence of texture of ceramic superconductors ReBaCuO (Re=Dy, Y) on their critical current density (Jc). The magnetic alignment of particles at ambient temperature is the first technique who has allowed us to produce superconducting (Meissner effect) and textured ceramics. However, these materials are very brittle because of their porosity and this makes it impossible to measure their Jc. Press-forging (or creep sintering) is the second technique who has allowed us to prepare highly textured ceramics materials which are also dense. We have studied the influence of various conditions of thermomechanical treatment (sintering time and temperature, applied load, rate of deformation, density of the material at the beginning) on the texture quality. We have shown that at 900 deg, the eutectic liquid formed by BaCuO 2 , CuO and YBa 2 Cu 3 0 7-Y various mechanisms that help explain the formation of observed texture. After the oxidation stage which requires heat treatment under controlled atmospheres, we obtain superconducting ceramics (Tc=85 K). Moreover, this study also shows that the texture can improve the Jc by 400%, to 750 A/cm 2 at 77 K in the best specimens. This low value is explained by the presence of non-superconducting secondary phases and amorphous phases at the grain boundaries. (Author). 120 refs., figs., tabs

Y1Ba2Cu3O(7-delta) thin film dc SQUIDs (superconducting quantum interference device)

Science.gov (United States)

Racah, Daniel

1991-03-01

Direct current superconducting quantum interferometers (SQUIDs) based on HTSC thin films have been measured and characterized. The thin films used were of different quality: (1) Granular films on Sapphire substrates, prepared either by e-gun evaporation, by laser ablation or by MOCVD (metal oxide chemical vapor deposition), (2) Epitaxial films on MgO substrates. Modulations of the voltage on the SQUIDs as a function of the applied flux have been observed in a wide range of temperatures. The nature of the modulation was found to be strongly dependent on the morphology of the film and on its critical current. The SQUIDs based on granular films were relatively noisy, hysteretic and with a complicated V-phi shape. Those devices based on low quality (lowIc) granular films could be measured only at low temperatures (much lower than 77 K). While those of higher quality (granular films with high Ic) could be measured near to the superconductive transition. The SQUID based on high quality epitaxial film was measured near Tc and showed an anomalous, time dependent behavior.

State of the art and trends of high-Tc superconductivity

International Nuclear Information System (INIS)

Barone, A.

1990-01-01

In this paper a brief account is given on some aspects of the development of high-T c Superconductivity since the last edition of the SATT Conference. This year significant results have been obtained in the challenging endeavor of increasing high critical current densities and in the context of high-T c junctions. The attention is confined to achievements and perspectives in these two topics

Processing of Mixed Oxide Superconductors

Science.gov (United States)

1990-07-01

rapid changes world wide a major research centre on high Tc superconductors was awarded to Cambridge which involved moving the work and people to a...reports and paper is in the appendices. Separation Ceramic superconductors tend to be mixtures of phases, especially when first discovered. It would...properties of the superconducting state will in principle allow superconducting material to be levitated from the non superconductor and several designs

Status of RF superconductivity at Argonne

International Nuclear Information System (INIS)

Shepard, K.W.

1990-01-01

Development of a superconducting slow-wave structures began at Argonne National Laboratory (ANL) in 1971, and led to the first superconducting heavy-ion linac (ATLAS - the Argonne Tandem-Linac Accelerator System). The Physics Division at ANL has continued to develop superconducting RF technology for accelerating heavy-ions, with the result that the linac has been in an almost continuous process of upgrade and expansion. In 1987, the Engineering Physics Division at ANL began developing of superconducting RF components for the acceleration of high-brightness proton and deuterium beams. The two divisions collaborate in work on several applications of RF superconductivity, and also in work to develop the technology generally. The present report briefly describes major features of the superconducting heavy-ion linac (very-low-velocity superconducting linac, positive ion injector), proton accelerating structures (superconducting resonant cavities for acceleration of high-current proton and deuteron beams, RF properties of oxide superconductors), and future work. Both divisions expect to continue a variety of studies, frequently in collaboration, to advance the basic technology of RF superconductivity. (N.K.)

Antiferromagnetic ordering in superconducting YBa₂Cu₃O_6.5

DEFF Research Database (Denmark)

Sidis, Y.; Ulrich, C.; Bourges, P.

2001-01-01

Commensurate antiferromagnetic ordering has been observed in the superconducting high-T-c. cuprate YBa2Cu3O6.5 (T-c = 55 K) by polarized and unpolarized elastic neutron scattering. The magnetic peak intensity exhibits a marked enhancement at T-c. Zero-field muon-spin-resonance experiments...

Novel structures and superconductivities of calcium–lithium alloys at high pressures: A first-principles study

International Nuclear Information System (INIS)

Xu, Ying; Chen, Changbo; Wang, Sihan; Sun, Xiuping

2016-01-01

Exposing a material to high pressures can fundamentally influence its crystal and electronic structure, leading to the formation of new materials with unique physical and chemical properties. Here, we have conducted a systematic search for Ca–Li alloys by using a global minima search based on particle-swarm optimization algorithm in combination with density functional theory calculations. We predict that Calcium and Lithium with a high Ca composition CaLi, Ca_2Li and Ca_3Li exist, and a strikingly decomposition-combination-decomposition oscillating behavior with pressure is revealed. All predicted Ca–Li compounds are metallic and good electron–phonon superconductors with transition temperatures (T_c) of around 8–19 K. The superconductivity mainly originates from the low-energy Ca vibrations and the pressure dependence of T_c is dominated by the phonon softening/hardening. - Highlights: • Three high Ca compositions of CaLi, Ca_2Li, and Ca_3Li alloys have been predicted. • High superconducting temperatures were predicted for Ca–Li alloys at high pressures. • The origin of the superconductivity is revealed. • The superconducting temperature increases with increasing pressures for Fd-3m CaLi. • The Fd-3m phase of CaLi is a potential high-temperature superconductor.

Pressure effect on the superconducting and the normal state of β -B i2Pd

Science.gov (United States)

Pristáš, G.; Orendáč, Mat.; Gabáni, S.; Kačmarčík, J.; Gažo, E.; Pribulová, Z.; Correa-Orellana, A.; Herrera, E.; Suderow, H.; Samuely, P.

2018-04-01

The pressure effect up to 24.0 kbar on superconducting and normal-state properties of β -B i2Pd single crystal (Tc≈4.98 K at ambient pressure) has been investigated by measurements of the electrical resistivity. In addition, we have performed the heat capacity measurements in the temperature range 0.7-300 K at ambient pressure. The recent calculations of electronic density of states, electron-phonon interaction spectral function, and phonon density of states of β -B i2Pd [Zheng and Margine, Phys. Rev. B 95, 014512 (2017), 10.1103/PhysRevB.95.014512], are used to fit the resistivity and the heat capacity data. In the superconducting state we have focused on the influence of pressure on the superconducting transition temperature Tc and upper critical field Hc 2 and a negative effect with d Tc/d p =-0.025 K /kbar and d Hc 2/d p =-8 mT /kbar is found. A simplified Bloch-Grüneisen model was used to analyze the pressure effect on the temperature dependence of the normal-state resistivity. The obtained results point to a decrease of the electron-phonon coupling parameter λ and to a shift of phonon frequencies to higher values with pressure. Moreover, the temperature dependence of the normal-state resistivity follows a T2 dependence above Tc up to about 25 K. Together with the enhanced value of Sommerfeld coefficient γ =13.23 mJ mo l-1K-2 these results point to a certain role of the electron-electron interaction in the superconducting pairing mechanism in β -B i2Pd .

On characteristic voltage of the high Tc superconductor. [Y-Ba-Cu-O

Energy Technology Data Exchange (ETDEWEB)

Vasiliev, B V; Uchaikin, S V [Joint Inst. for Nuclear Research, Low Temperature Physics Dept., Dubna (USSR)

1991-12-01

The critical currents and normal resistances of the small bridges from yttrium-based high-Tc superconducting ceramics have been measured. The characteristic voltage of these bridges was found to be approximately 20{mu}V. This effect can be explained if between the ceramic grains there are contacts of an order of one crystalline cell in size. (orig.).

Levitation properties of a ring-shaped flywheel supported by high Tc superconducting levitation

International Nuclear Information System (INIS)

Teshima, Hidekazu; Tawara, Taichi; Shimada, Ryuichi.

1997-01-01

In this paper we propose a new combination of high T c superconducting levitation and ring-shaped flywheel energy storage systems. Superconducting levitation is appropriate for rotating a ring-shaped flywheel which has neither shaft nor hub, because it is a non-contact and automatically stable levitation without any control systems. The levitation properties such as static and dynamic lateral stiffnesses, lateral damping, and lateral vibration during rotation have been investigated using a small-scaled experimental machine consisting of 16 bulk superconductors 46 mm in diameter and a ring-shaped flywheel about 300 mm in diameter. The spring constant increased as the levitation gap height decreased, and the dynamic spring constant was slightly higher than the static constant. The damping coefficient increased as the gap height decreased and the vibration amplitude increased. The experimental critical speed was in good agreement with the calculated one using a one-degree of freedom model. Finally, the possibility of large-scaled practical systems is discussed from the viewpoint of superconducting levitation. (author)

Observation of high Tc one dimensional superconductivity in 4 angstrom carbon nanotube arrays

KAUST Repository

Zhang, Bing; Liu, Yang; Chen, Qihong; Lai, Zhiping; Sheng, Ping

2017-01-01

The only known approach to fabricate large, uniform arrays of 4-Å single wall carbon nanotubes (SWNTs) is by using zeolite crystals as the template, in which the nanotubes are formed by chemical vapor deposition inside the linear channels of the AlPO-5 (AFI for short) zeolite. However, up to now the pore filling factor has been very low, as evidenced by the weight percentage of carbon in thermal gravimetric analysis (TGA) measurements. In this work, we show that by using a new, micro-platelet AFI crystals as the template, combined with the use of a new CVD process, we can increase the TGA result to 22.5wt%, which translates to a pore filling factor of 91%. We have observed one dimensional (1D) superconductivity in such samples. The temperature dependence of resistance shows a smooth decreasing trend below 60 K, and the differential resistance displays a gap that disappears above the 1D superconducting initiation temperature. The observed behaviour is shown to agree very well with the theoretical predictions of 1D superconductivity.

Observation of high Tc one dimensional superconductivity in 4 angstrom carbon nanotube arrays

KAUST Repository

Zhang, Bing

2017-02-14

The only known approach to fabricate large, uniform arrays of 4-Å single wall carbon nanotubes (SWNTs) is by using zeolite crystals as the template, in which the nanotubes are formed by chemical vapor deposition inside the linear channels of the AlPO-5 (AFI for short) zeolite. However, up to now the pore filling factor has been very low, as evidenced by the weight percentage of carbon in thermal gravimetric analysis (TGA) measurements. In this work, we show that by using a new, micro-platelet AFI crystals as the template, combined with the use of a new CVD process, we can increase the TGA result to 22.5wt%, which translates to a pore filling factor of 91%. We have observed one dimensional (1D) superconductivity in such samples. The temperature dependence of resistance shows a smooth decreasing trend below 60 K, and the differential resistance displays a gap that disappears above the 1D superconducting initiation temperature. The observed behaviour is shown to agree very well with the theoretical predictions of 1D superconductivity.

Round robin tests of Tc and Ic on YBa/sub 2/Cu/sub 3/O/sub x/

International Nuclear Information System (INIS)

Kimura, Y.; Higuchi, N.; Meguro, S.; Takahashi, K.; Uyeda, K.; Ishihara, T.; Inukai, E.; Umeda, M.

1989-01-01

In the author's research and development of oxide superconducting material, methods for measuring the critical properties such as critical temperature and critical current were investigated and studied by way of round robin tests. The investigation was carried out through the steps of (1) decision on the specifications of common samples and measuring methods, (2) preparation and characterization of common samples, (3) distribution of samples to ten member research organs of Super-GM, (4) experimental measurement in the respective research organs, and (5) analysis of measurement results. The measurement of critical temperature and critical current were made mainly using the 4-probe method, and partially the magnetization method. The results were found to disperse, depending on the measurement methods and definitions of Tc and lc. Data analysis with these factors clarified is important

Suppression of superconductivity in Nb by IrMn in IrMn/Nb bilayers

KAUST Repository

Wu, B. L.; Yang, Y. M.; Guo, Z. B.; Wu, Y. H.; Qiu, J. J.

2013-01-01

Effect of antiferromagnet on superconductivity has been investigated in IrMn/Nb bilayers. Significant suppression of both transition temperature (Tc) and lower critical field (Hc1) of Nb is found in IrMn/Nb bilayers as compared to a single layer Nb

Dense high temperature ceramic oxide superconductors

Science.gov (United States)

Landingham, Richard L.

1993-01-01

Dense superconducting ceramic oxide articles of manufacture and methods for producing these articles are described. Generally these articles are produced by first processing these superconducting oxides by ceramic processing techniques to optimize materials properties, followed by reestablishing the superconducting state in a desired portion of the ceramic oxide composite.

High-temperature superconducting phase of HBr under pressure predicted by first-principles calculations

Science.gov (United States)

Gu, Qinyan; Lu, Pengchao; Xia, Kang; Sun, Jian; Xing, Dingyu

2017-08-01

The high pressure phases of HBr are explored with an ab initio crystal structure search. By taking into account the contribution of zero-point energy (ZPE), we find that the P 4 /n m m phase of HBr is thermodynamically stable in the pressure range from 150 to 200 GPa. The superconducting critical temperature (Tc) of P 4 /n m m HBr is evaluated to be around 73 K at 170 GPa, which is the highest record so far among binary halogen hydrides. Its Tc can be further raised to around 95K under 170 GPa if half of the bromine atoms in the P 4 /n m m HBr are substituted by the lighter chlorine atoms. Our study shows that, in addition to lower mass, higher coordination number, shorter bonds, and more highly symmetric environment for the hydrogen atoms are important factors to enhance the superconductivity in hydrides.

Multigap superconductivity and Shubnikov-de Haas oscillations in single crystals of the layered boride OsB2

Science.gov (United States)

Singh, Yogesh; Martin, C.; Bud'Ko, S. L.; Ellern, A.; Prozorov, R.; Johnston, D. C.

2010-10-01

Single crystals of superconducting OsB2 [Tc=2.10(5)K] have been grown using a Cu-B eutectic flux. We confirm that OsB2 crystallizes in the reported orthorhombic structure (space group Pmmn ) at room temperature. Both the normal and superconducting state properties of the crystals are studied using various techniques. Heat capacity versus temperature C(T) measurements yield the normal state electronic specific heat coefficient γ=1.95(1)mJ/molK2 and the Debye temperature ΘD=539(2)K . The measured frequencies of Shubnikov-de Haas oscillations are in good agreement with those predicted by band structure calculations. Magnetic susceptibility χ(T,H) , electrical resistivity ρ(T) , and C(T,H) measurements ( H is the magnetic field) demonstrate that OsB2 is a bulk low- κ [κ(Tc)=2(1)] type-II superconductor that is intermediate between the clean and dirty limits [(ξ(T=0)/ℓ=0.97)] with a small upper critical magnetic field Hc2(T=0)=186(4)Oe . The penetration depth is λ(T=0)=0.300μm . An anomalous (not single-gap BCS) T dependence of λ was fitted by a two-gap model with Δ1(T=0)/kBTc=1.9 and Δ2(T=0)/kBTc=1.25 , respectively. The discontinuity in the heat capacity at Tc , ΔC/γTc=1.32 , is smaller than the weak-coupling BCS value of 1.43, consistent with the two-gap nature of the superconductivity in OsB2 . An anomalous increase in ΔC at Tc of unknown origin is found in finite H ; e.g., ΔC/γTc≈2.5 for H≈25Oe .

Superconducting Electronic Film Structures

Science.gov (United States)

1991-02-14

Segmuller, A., Cooper, E.I., Chisholm, M.F., Gupta, A. Shinde, S., and Laibowitz, R.B. Lanthanum gallate substrates for epitaxial high-T superconducting thin...M. F. Chisholm, A. Gupta, S. Shinde, and R. B. Laibowitz, " Lanthanum Gallate Substrates for Epitaxial High-T c Superconducting Thin Films," Appl...G. Forrester and J. Talvacchio, " Lanthanum Copper Oxide Buffer Layers for Growth of High-T c Superconductor Films," Disclosure No. RDS 90-065, filed

Earlier and recent aspects of superconductivity

International Nuclear Information System (INIS)

Bednorz, J.G.; Muller, K.A.

1990-01-01

Contemporary knowledge of superconductivity is set against its historical background in this book. First, the highlights of superconductivity research in the twentieth century are reviewed. Further contributions then describe the basic phenomena resulting from the macroscopic quantum state of superconductivity (such as zero resistivity, the Meissner-Ochsenfeld effect, and flux quantization) and review possible mechanisms, including the classical BCS theory and the more recent alternative theories. The main categories of superconductors - elements, intermetallic phases, chalcogenides, oxides and organic compounds - are described. Common features and differences in their structure and electronic properties are pointed out. This overview of superconductivity is completed by a discussion of properties related to the coherence length

Oxygen hole mechanism of superconductivity in cuprates and other metal oxides

International Nuclear Information System (INIS)

Rao, C.N.R.

1989-01-01

Several theoretical models have been proposed to explain high-temperature superconductivity in cuprates. An issue that is central to any model is the nature of copper and oxygen species in the cuprates since superconductivity clearly owes its origin to the Cu-O sheets universally present in all the cuprate families. Thus, the five families of cuprate superconductors, La 2 - x M x CuO 4 (M = Ca, Sr or Ba) of the K 2 NiF 4 structure, LnBa 2 Cu 3 O 7 - δ (Ln = Y or rare earth), Bi 2 (Ca, Sr) n + 1 Cu n O 2n + 4 , Tl 2 (Ca, Ba) n + 1 Cu n O 2n + 4 and Tl (Ca, Ba) n + 1 Cu n O 2n + 3 , all contain two-dimensional Cu-O sheets. The Cu-O chains additionally present in the 123 compounds do not seem to play any crucial role. It has been generally believed that magnetic, superconducting and related properties of cuprates have some thing to do with the mixed valency of copper. For example, the resonating valence bond (RVB) model requires the presence of holes on Cu sites (Cu 3 + species). There are also a few models, however, based on the presence of holes on oxygen sites (O - species); dimerization of oxygen holes has also been suggested to occur by a few workers. It is the purpose of this article to briefly present the available experimental evidence for the presence of oxygen holes and to discuss their role in high-temperature conductivity. It will be shown that these holes play a role in other oxide materials as well as including the Cu-free Ba 1 - x K x BiO 3 superconductor

Superconductivity of Ba8Si46-xGax clathrates

Science.gov (United States)

Li, Yang; Zhang, Ruihong; Chen, Ning; Ma, Xingqiao; Cao, Guohui; Luo, Z. P.; Hu, C. R.; Ross, Joseph H., Jr.

2007-03-01

We have presented a combined experimental and theoretical study of the effect of Gallium substitution on the superconductivity of the type I clathrate Ba8Si46-xGax. In Ga-doped clathrates, the Ga state is found to be strongly hybridized with the cage conduction-band state. Ga substitution results in a shift toward to a lower energy, a decrease of density of states at Fermi level, a lowering of the carrier concentration and a breakage of integrity of the sp3 hybridized networks. These play key roles in the suppression of superconductivity. For Ba8Si40Ga6, the onset of the superconducting transition occurs at Tc=3.3 K. The investigation of the magnetic superconducting state shows that Ba8Si40Ga6 is a type II superconductor. The critical magnetic fields were measured to be Hc1=35 Oe and Hc2=8.5 kOe. Our estimate of the lectron-phonon coupling reveals that Ba8Si40Ga6 is a moderate phonon-mediated BCS superconductor.

Extended abstracts of the 12th JAERI workshop on high-Tc superconductors

Energy Technology Data Exchange (ETDEWEB)

Hojou, Kiichi; Okayasu, Satoru; Sasase, Masato [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment; Ishida, Takekazu [Osaka Prefectual Univ., Sakai (JP)] (eds.)

2001-03-01

This workshop was held on December 7-8, 2000 at JAERI (Tokai). The research group at JAERI shares a responsibility for material modification of high-Tc superconductors by irradiation in 'the multi-core project II of the high temperature superconducting material research' organized by STA (Science and Technology Agency) of Japan. This report contains the extended abstracts of workshop presentations covering basic theories, various experimental results and material improvement studies of the superconductivity by high energy ion irradiation. The twelve presentations of the workshop were devoted to a mini symposium where the direct observations of vortices were discussed in view of the various sophisticated techniques. (author)

Extended abstracts of the 12th JAERI workshop on high-Tc superconductors

International Nuclear Information System (INIS)

Hojou, Kiichi; Okayasu, Satoru; Sasase, Masato

2001-03-01

This workshop was held on December 7-8, 2000 at JAERI (Tokai). The research group at JAERI shares a responsibility for material modification of high-Tc superconductors by irradiation in 'the multi-core project II of the high temperature superconducting material research' organized by STA (Science and Technology Agency) of Japan. This report contains the extended abstracts of workshop presentations covering basic theories, various experimental results and material improvement studies of the superconductivity by high energy ion irradiation. The twelve presentations of the workshop were devoted to a mini symposium where the direct observations of vortices were discussed in view of the various sophisticated techniques. (author)

Superatom representation of high-TC superconductivity

International Nuclear Information System (INIS)

Panas, Itai

2012-01-01

A “super-atom” conceptual interface between chemistry and physics is proposed in order to assist in the search for higher T C superconductors. The plaquettes generating the checkerboard superstructure in the cuprates, the C 60 molecules in K 3 C 60 , and the Mo 6 S 8 2- clusters in Chevrel phase materials offer such candidate super-atoms. Thus, in the present study high-T C superconductivity HTSC is articulated as the entanglement of two disjoint electronic manifolds in the vicinity of a common Fermi energy. The resulting HTSC ground state couples near-degenerate protected local super-atom states to virtual magnons in an antiferromagnetic AFM embedding. The composite Cooper pairs emerge as the interaction particles for virtual magnons mediated “self-coherent entanglement” of super-atom states. A Hückel type resonating valence bond RVB formalism is employed in order to illustrate the real-space Cooper pairs as well as their delocalization and Bose Einstein condensation BEC on a ring of super-atoms. The chemical potential μ BEC for Cooper pairs joining the condensate is formulated in terms of the super-exchange interaction, and consequently the T C in terms of the Neél temperature. A rationale for the robustness of the HTSC ground state is proposed: achieving local maximum “electron correlation entropy” at the expense of non-local phase rigidity.

Flux free growth of large FeSe1/2Te1/2 superconducting single crystals by an easy high temperature melt and slow cooling method

Directory of Open Access Journals (Sweden)

P. K. Maheshwari

2015-09-01

Full Text Available We report successful growth of flux free large single crystals of superconducting FeSe1/2Te1/2 with typical dimensions of up to few cm. The AC and DC magnetic measurements revealed the superconducting transition temperature (Tc value of around 11.5K and the isothermal MH showed typical type-II superconducting behavior. The lower critical field (Hc1 being estimated by measuring the low field isothermal magnetization in superconducting regime is found to be above 200Oe at 0K. The temperature dependent electrical resistivity ρ(T  showed the Tc (onset to be 14K and the Tc(ρ = 0 at 11.5K. The electrical resistivity under various magnetic fields i.e., ρ(TH for H//ab and H//c demonstrated the difference in the width of Tc with applied field of 14Tesla to be nearly 2K, confirming the anisotropic nature of superconductivity. The upper critical and irreversibility fields at absolute zero temperature i.e., Hc2(0 and Hirr(0 being determined by the conventional one-band Werthamer–Helfand–Hohenberg (WHH equation for the criteria of normal state resistivity (ρn falling to 90% (onset, and 10% (offset is 76.9Tesla, and 37.45Tesla respectively, for H//c and 135.4Tesla, and 71.41Tesla respectively, for H//ab. The coherence length at the zero temperature is estimated to be above 20Å ´ by using the Ginsburg-Landau theory. The activation energy for the FeSe1/2Te1/2 in both directions H//c and H//ab is determined by using Thermally Activation Flux Flow (TAFF model.

Growth of epitaxial Ba2YCu3O(7-delta) thin films and control of their superconducting properties

International Nuclear Information System (INIS)

Siegal, M.P.; Phillips, J.M.

1992-01-01

The relationship is experimentally defined between the superconducting behavior of Ba2YCu3O(7-delta) (BYCO) films and their structural characteristics. The BYCO films are grown on LaAlO3 100-plane by coevaporating BaF2, Y, and Cu followed by ex situ annealing, and the crystalline quality is tested by Rutherford backscattering ion channeling. SEM is employed to study film morphology, and several techniques are used to measure the transition temperature (Tc), critical current density (Jc), and the penetration length. It is found that point defects and dislocations decrease as the high-temperature stage (Ta) increases; crevices, pinholes, and microcracks are also noted which are related to specific values of Tc, Ta, and penetration length. The results of the present experiments indicate that the material properties of superconducting materials should be examined closely to distinguish between pure superconducting behavior and characteristics related to material structure. 21 refs

Solid-state ionics: Studies of lithium-conducting sulfide glasses and a superconducting oxide compound

International Nuclear Information System (INIS)

Ahn, Byung Tae.

1989-01-01

The first part of this work studies lithium-conducting sulfide glasses for battery applications, while the second part studies the thermodynamic properties of a superconducting oxide compound by using an oxide electrolyte. Lithium conducting glasses based on the SiS 2 -Li 2 S system are possible solid electrolytes for high-energy-density lithium batteries. The foremost requirement for solid electrolytes is that they should have high ionic conductivities. Unfortunately, most crystalline lithium conductors have low ionic conductivities at room temperature. However, glass ionic conductors show higher ionic conductivities than do crystalline forms of the same material. In addition to higher ionic conductivities, glasses appear to have several advantages over crystalline materials. These advantages include isotropic conductivity, absence of grain boundary effects, ease of glass forming, and the potential for a wide range of stability to oxidizing and reducing conditions. Using pyrolitic graphite-coated quartz ampoules, new ternary compounds and glasses in the SiS 2 -Li 2 S system were prepared. Several techniques were used to characterize the materials: powder x-ray diffraction, differential thermal analysis, differential scanning calorimetry, and AC impedance spectroscopy. The measured lithium conductivity of the sulfide glasses was one of the highest among the known solid lithium conductors. Measuring the equilibrium open circuit voltages assisted in determining the electrochemical stabilities of the ternary compounds and glasses with respect to pure Li. A solid-state ionic technique called oxygen coulometric titration was used to measure the thermodynamic stability, the oxygen stoichiometry, and the effects of the oxygen stoichiometry, and the effects of the oxygen stoichiometry and the cooling rate on superconductivity of the YBa 2 Cu 3 O 7-x compound were investigated

Status of RF superconductivity at Argonne

Energy Technology Data Exchange (ETDEWEB)

Shepard, K.W.

1989-01-01

Development of a superconducting (SC) slow-wave structures began at Argonne National Laboratory (ANL) in 1971, and led to the first SC heavy-ion linac (ATLAS - the Argonne Tandem-Linac Accelerating System), which began regularly scheduled operation in 1978. To date, more than 40,000 hours of bean-on target operating time has been accumulated with ATLAS. The Physics Division at ANL has continued to develop SC RF technology for accelerating heavy-ions, with the result that the SC linac has, up to the present, has been in an almost continuous process of upgrade and expansion. It should be noted that this has been accomplished while at the same time maintaining a vigorous operating schedule in support of the nuclear and atomic physics research programs of the division. In 1987, the Engineering Physics Division at ANL began development of SC RF components for the acceleration of high-brightness proton and deuterium beams. This work has included the evaluation of RF properties of high-{Tc} oxide superconductors, both for the above and for other applications. The two divisions collaborated while they worked on several applications of RF SC, and also worked to develop the technology generally. 11 refs., 6 figs.

Anomalous enhancement of the lower critical field deep in the superconducting state of LaRu4As12

Science.gov (United States)

Juraszek, J.; Bochenek, Ł.; Wawryk, R.; Henkie, Z.; Konczykowski, M.; Cichorek, T.

2018-05-01

LaRu4As12 with the critical temperature Tc = 10.4 K displays several features which point at a non-singlet superconducting order parameter, although the bcc crystal structure of the filled skutterudites does not favour the emergence of multiple energy gaps. LaRu4As12 displays an unexpected enhancement of the lower critical field deep in superconducting state which can be attributed to the existence of two superconducting gaps. At T = 0.4 K, the local magnetization measurements were performed utilizing miniaturized Hall sensors.

New bisaminoethanethiol (BAT) ligands which form two interconvertible Tc-99m complexes

Energy Technology Data Exchange (ETDEWEB)

Oya, Shunichi; Kung, Mei-Ping; Frederick, Dana; Kung, Hank F

1995-08-01

Most commonly used radiopharmaceuticals in diagnostic nuclear medicine are labeled with Tc-99m. This is due to its superior physical characteristics (T{sub (1(2))} = 6 h and gamma energy 140 KeV) and convenient availability from the {sup 99}Mo/{sup 99mm}Tc generator. In an attempt to fine tune the properties of Tc-99m complexes, the synthesis and radiolabeling of two novel N{sub 2}S{sub 2} ligands, N,-2-mercaptobenzyl-N'-(1-oxo-2-mercapto-2-methyl)propyl ethylenediamine,8, and N,-2-methylthiobenzyl-N'-(1-oxo-2-mercapto-2-methyl)propyl ethylenediamine, 11, with an ionizable SH or unionizable SMe group, respectively, for the formation of complexes with Tc{sup v}O center cores, have been examined. Both ligands initially formed one apparently stable, lipophilic and neutral complex (HPLC, Rt = 7 min, reverse-phase column, acetonitrile: buffer, pH 7.0; (55(45)); V/V; partition coefficient between 1-octanol and buffer of 410 and 335, respectively) with [{sup 99m}Tc]pertechnetate in the presence of stannous chloride. After treatment with a reducing agent, NaCNBH{sub 3}, the initial [{sup 99m}Tc]8 and 11 complexes were reduced; the reduced complexes were less lipophilic (shorter retention time, Rt = 5 min, on the same reversed phase HPLC). However, only the oxidized form showed sufficient stability. The reduced forms of both [{sup 99m}Tc]8 and 11 were readily and completely converted back to the oxidized forms by a stream of air. Biodistribution studies in rats demonstrated that the [{sup 99m}Tc]8 (oxidized form) penetrated the blood-brain barrier (0.67% dose/organ at 2 min postinjection), but washed out from the brain quickly (0.29% dose/organ at 30 min postinjection). On the contrary, [{sup 99m}Tc]11 (oxidized form) did not show any brain uptake (0.03% dose/organ at 2 min postinjection), despite its higher lipophilicity. The disparity between these two Tc-99m complexes may be related to the relative instability of [{sup 99m}Tc]11 (oxidized form) by the introduction of the

Superconductivity mediated by anharmonic phonons: application to β-pyrochlore oxides

Science.gov (United States)

Hattori, Kazumasa; Tsunetsugu, Hirokazu

2010-03-01

We investigate three dimensional anharmonic phonons under tetrahedral symmetry and superconductivity mediated by these phonons. Three dimensional anharmonic phonon spectra are calculated directly by solving Schr"odinger equation and the superconducting transition temperature is determined by using the theory of strong coupling superconductivity assuming an isotropic gap function. With increasing the third order anharmonicity b of the tetrahedral potential, we find a crossover in the energy spectrum to a quantum tunneling regime. We obtain strongly enhanced transition temperatures around the crossover point. The first order transition observed in KOs2O6 is discussed in terms of the first excited state energy δ, and the coupling constant λ in the strong coupling theory of superconductivity. Our results suggest that the decrease of λ and increase of δ below the first order transition temperature. We point out that the change in the oscillation amplitude and characterizes this isomorphic transition. The chemical trends of the superconducting transition temperature, λ, and δ in the β-pyrochlore compounds are also discussed.

Anomalous superconductivity in the tJ model; moment approach

DEFF Research Database (Denmark)

Sørensen, Mads Peter; Rodriguez-Nunez, J.J.

1997-01-01

By extending the moment approach of Nolting (Z, Phys, 225 (1972) 25) in the superconducting phase, we have constructed the one-particle spectral functions (diagonal and off-diagonal) for the tJ model in any dimensions. We propose that both the diagonal and the off-diagonal spectral functions...... Hartree shift which in the end result enlarges the bandwidth of the free carriers allowing us to take relative high values of J/t and allowing superconductivity to live in the T-c-rho phase diagram, in agreement with numerical calculations in a cluster, We have calculated the static spin susceptibility......, chi(T), and the specific heat, C-v(T), within the moment approach. We find that all the relevant physical quantities show the signature of superconductivity at T-c in the form of kinks (anomalous behavior) or jumps, for low density, in agreement with recent published literature, showing a generic...

Study on magnetic separation system using high Tc superconducting bulk magnets for water purification technique

International Nuclear Information System (INIS)

Oka, T; Kanayama, H; Tanaka, K; Fukui, S; Ogawa, J; Sato, T; Ooizumi, M; Yamaguchi, M; Yokoyama, K; Noto, K

2009-01-01

The application of superconducting bulk magnets to the magnetic separation techniques has been investigated for the Mn-bearing waste water drained from the university laboratories. The research has been conducted in comparison with the electromagnets, and the cryo-cooled superconducting solenoid magnet. The separation ratios of ferrite precipitates including Mn element in the waste slurry were estimated by means of the high gradient magnetic separation method with ferromagnetic iron filters in the water channel and open gradient magnetic separation without them. As the magnetic force acting on the particles is given by the product of a magnetization of particles and a gradient of magnetic field, and a superconducting bulk magnet shows a sharp gradient of the magnetic field on the surface, the performances of the bulk magnet system were almost equivalent to those of the superconducting solenoid magnet with wide bore with respect to the magnetic separation ratios. The separation ratios for Mn have reached over 80 % for HGMS and 10 % for OGMS under the flow rates less than 3 liter/min.

Low-temperature rapid synthesis and superconductivity of Fe-based oxypnictide superconductors.

Science.gov (United States)

Fang, Ai-Hua; Huang, Fu-Qiang; Xie, Xiao-Ming; Jiang, Mian-Heng

2010-03-17

Fe-based oxypnictide superconductors were successfully synthesized at lower reaction temperatures and with shorter reaction times made possible by starting with less stable compounds, which provide a larger driving force for reactions. Using ball-milled powders of intermediate compounds, phase-pure superconductors with T(c) above 50 K were synthesized at 1173 K in 20 min. This method is particularly advantageous for retaining F, a volatile dopant that enhances superconductivity. Bulk superconductivity and high upper critical fields up to 392 T in Sm(0.85)Nd(0.15)FeAsO(0.85)F(0.15) were demonstrated.

Preparation of textured high Tc superconducting films by CVD using halides on technical substrates with appropriate buffer layers. Final report

International Nuclear Information System (INIS)

Selbmann, D.; Balarin, M.; Klosowski, J.

1993-01-01

On the basis of a thermodynamical calculation of the system Y-Ba-Cu-O-Hal-C-H, Hal = I, Br, Cl the deposition conditions of the 123-phase and the other phases in this system was investigated. For the practical applications a reaction temperature higher 850 C and an oxidizer excesse higher 5 . 10 3 is necessary in order to deposit halid- and carbon free layers. A new Aerosol-CVD-process has been developed, which allows the reproducible preparation of superconducting YBa 2 Cu 3 O 7 thin films. The process uses a solution source of Y-, Ba-, Cu-bromide dissolved in suitable organic solvents. With the process the films consisting of the 123-phase, however the content of other phases is too high. With this composition it is not possible to deposit textured layers. This behaviour is due to flow technical problems. In order to avoid the formation of oxides in the evaporator it is necessary to mix the oxidizer directly near the substrate. Therefore the development of a new reactor and a process optimization is necessary. (orig.) [de

Pulse measurement of the hot spot current in a NbTiN superconducting filament

Science.gov (United States)

Harrabi, K.; Mekki, A.; Kunwar, S.; Maneval, J. P.

2018-02-01

We have studied the voltage response of superconducting NbTiN filaments to a step-pulse of over-critical current I > Ic. The current induces the destruction of the Cooper pairs and initiates different mechanisms of dissipation depending on the bath temperature T. For the sample investigated, and for T above a certain T*, not far from Tc, the resistance manifests itself in the form of a phase-slip center, which turns into a normal hot spot (HS) as the step-pulse is given larger amplitudes. However, at all temperatures below T*, the destruction of superconductivity still occurs at Ic(T), but leads directly to an ever-growing HS. By lowering the current amplitude during the pulse, one can produce a steady HS and thus define a threshold HS current Ih(T). That is achieved by combining two levels of current, the first and larger one to initiate an HS, the second one to search for constant voltage response. The double diagram of the functions Ic(T) and Ih(T) was plotted in the T-range Tc/2 < T < Tc, and their crossing found at T* = (8.07 ± 0.07) K.

International Discussion Meeting on High-Tc Superconductors

CERN Document Server

1988-01-01

In the past two years conferences on superconductivity have been characterized by the attendance of hundreds of scientists. Consequently, the organizers were forced to schedule numerous parallel sessions and poster presentations with an almost unsurveyable amount of information. It was, therefore, felt that a more informal get-together, providing ample time for a thourough discussion of some topics of current interest in high-temperature superconductivity, was timely and benefitial for leading scientists as well as for newcomers in the field. The present volume contains the majority of papers presented at the International Discussion Meeting on High-Tc Superconductors held at the Mauterndorf Castle in the Austrian Alps from February 7 to 11, 1988. Each subject was introduced in review form by a few invited speakers and then discussed together with the contributed poster presentations. These discussion sessions chaired by selected scientists turned out to be the highlights of the meeting, not only because all ...

Superconductivity in SrNi2P2 single crystals

Energy Technology Data Exchange (ETDEWEB)

Ronning, Filip [Los Alamos National Laboratory; Bauer, Eric D [Los Alamos National Laboratory; Park, Tuscon [Los Alamos National Laboratory; Thompson, Joe D [Los Alamos National Laboratory

2009-01-01

Heat capacity, magnetic susceptibility, and resistivity of SrNi{sub 2}P{sub 2} single crystals are presented, illustrating the structural transition at 325 K, and bulk superconductivity at 1.4 K. The magnitude of {Tc}, fits to the heat capacity data, the small upper critical field H{sub c2} = 390 Oe, and {kappa} = 2.1 suggests a conventional fully gapped superconductor. With applied pressure we find that superconductivity persists into the so-called 'collapsed tetragonal' phase, although the transition temperature is monotonically suppressed with increasing pressure. This argues that reduced dimensionality can be a mechanism for increasing the transition temperatures of layered NiP, as well as layered FeAs and NiAs, superconductors.

The interaction between ApoA2 -265T>C polymorphism and dietary fatty acids intake on oxidative stress in patients with type 2 diabetes mellitus.

Science.gov (United States)

Zamani, Elham; Sadrzadeh-Yeganeh, Haleh; Sotoudeh, Gity; Keramat, Laleh; Eshraghian, Mohammadreza; Rafiee, Masoumeh; Koohdani, Fariba

2017-08-01

Apolipoprotein A2 (APOA2) -265T>C polymorphism has been studied in relation to oxidative stress and various dietary fatty acids. Since the interaction between APOA2 polymorphism and dietary fatty acids on oxidative stress has not yet discussed, we aimed to investigate the interaction on oxidative stress in type 2 diabetes mellitus (T2DM) patients. The subjects were 180 T2DM patients with known APOA2 genotype, either TT, TC or CC. Superoxide dismutase (SOD) activity was determined by colorimetric method. Total antioxidant capacity (TAC) and serum level of 8-isoprostane F2α were measured by spectrophotometry and ELISA, respectively. Dietary intake was collected through a food frequency questionnaire. Based on the median intake, fatty acids intake was dichotomized into high or low groups. The interaction between APOA2 polymorphism and dietary fatty acids intake was analyzed by ANCOVA multivariate interaction model. Higher than median intake of omega-6 polyunsaturated fatty acids (n-6 PUFA) was associated with increased serum level of 8-isoprostane F2α in subjects with TT/TC genotype (p = 0.004), and higher than median intake of omega-3 polyunsaturated fatty acids (n-3 PUFA) was associated with increased serum SOD activity in CC genotype (p fatty acids intake on oxidative stress. More investigations on different populations are required to confirm the interaction.

Crystalline phases and electronic structures in superconducting Bi endash Sr endash Ca endash Cu oxides

International Nuclear Information System (INIS)

Giardina, M.D.; Feduzi, R.; Inzaghi, D.; Manara, A.; Giori, C.; Sora, I.N.; Dallacasa, V.

1997-01-01

Two classes of samples, designated A and B, of layered Bi endash Sr endash Ca endash Cu oxides having the same nominal composition 4:3:3:4, but different thermal histories, were investigated by using field modulated microwave absorption (ESR), powder x-ray diffraction (XRD), x-ray photoelectron spectroscopy (XPS), and x-ray absorption near the edge structure (XANES). Previous electrical resistivity measurements showed that the B samples only presented two superconducting phases with midpoints of the transition temperatures at ∼80K and ∼105K. The microwave absorption technique indicated instead the presence of islands which became superconducting at the above-mentioned temperatures also in the A samples. The crystalline and electronic structures of the two types of samples are illustrated and discussed. A plausible theoretical interpretation of the experimental results, based on a quantum percolation model with Coulomb interaction, is also given. copyright 1997 Materials Research Society

Feshbach shape resonance for high Tc superconductivity in superlattices of nanotubes

International Nuclear Information System (INIS)

Bianconi, Antonio

2006-01-01

The case of a Feshbach shape resonance in the pairing mechanism for high T c superconductivity in a crystalline lattice of doped metallic nanotubes is described. The superlattice of doped metallic nanotubes provides a superconductor with a strongly asymmetric gap. The disparity and different spatial locations of the wave functions of electrons in different subbands at the Fermi level should suppress the single electron impurity interband scattering giving multiband superconductivity in the clean limit. The Feshbach resonances will arise from the component single-particle wave functions out of which the electron pair wave function is constructed: pairs of wave functions which are time inverse of each other. The Feshbach shape resonance increases the critical temperature by tuning the chemical potential at the Lifshitz electronic topological transition (ETT) where the Fermi surface of one of the bands changes from the one dimensional (1D) to the two dimensional (2D) topology (1D/2D ETT). (copyright 2006 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim) (Abstract Copyright [2006], Wiley Periodicals, Inc.)

High-temperature superconductivity from fine-tuning of Fermi-surface singularities in iron oxypnictides

Science.gov (United States)

Charnukha, A.; Evtushinsky, D. V.; Matt, C. E.; Xu, N.; Shi, M.; Büchner, B.; Zhigadlo, N. D.; Batlogg, B.; Borisenko, S. V.

2015-12-01

In the family of the iron-based superconductors, the REFeAsO-type compounds (with RE being a rare-earth metal) exhibit the highest bulk superconducting transition temperatures (Tc) up to 55 K and thus hold the key to the elusive pairing mechanism. Recently, it has been demonstrated that the intrinsic electronic structure of SmFe0.92Co0.08AsO (Tc = 18 K) is highly nontrivial and consists of multiple band-edge singularities in close proximity to the Fermi level. However, it remains unclear whether these singularities are generic to the REFeAsO-type materials and if so, whether their exact topology is responsible for the aforementioned record Tc. In this work, we use angle-resolved photoemission spectroscopy (ARPES) to investigate the inherent electronic structure of the NdFeAsO0.6F0.4 compound with a twice higher Tc = 38 K. We find a similarly singular Fermi surface and further demonstrate that the dramatic enhancement of superconductivity in this compound correlates closely with the fine-tuning of one of the band-edge singularities to within a fraction of the superconducting energy gap Δ below the Fermi level. Our results provide compelling evidence that the band-structure singularities near the Fermi level in the iron-based superconductors must be explicitly accounted for in any attempt to understand the mechanism of superconducting pairing in these materials.

Chemistry of /sup 99m/Tc labeling kits

International Nuclear Information System (INIS)

Srivastava, S.C.; Meinken, G.; Richards, P.

1976-01-01

Problems have been reported with the use of kit-produced /sup 99m/Tc radiopharmaceuticals. This study was undertaken to understand the chemistry involved in various stannous kit systems. The relation between Tc, tin, and the ligands used to complex the reduced Tc was investigated. It is concluded that for reliable performance, stannous kits should be prepared so that most of the tin is kept in the usable (reducing) form; a solution would be to use minimum tin and a large excess of complexing agent. Oxidation of the Tc complex to free pertechnetate is not a major problem in most kit systems. 5 figures

Enhancement of superconductivity near the pressure-induced semiconductor-metal transition in the BiS₂-based superconductors LnO₀.₅F₀.₅BiS₂ (Ln = La, Ce, Pr, Nd).

Science.gov (United States)

Wolowiec, C T; White, B D; Jeon, I; Yazici, D; Huang, K; Maple, M B

2013-10-23

Measurements of electrical resistivity were performed between 3 and 300 K at various pressures up to 2.8 GPa on the BiS2-based superconductors LnO0.5F0.5BiS2 (Ln=Pr, Nd). At lower pressures, PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2 exhibit superconductivity with critical temperatures Tc of 3.5 and 3.9 K, respectively. As pressure is increased, both compounds undergo a transition at a pressure Pt from a low Tc superconducting phase to a high Tc superconducting phase in which Tc reaches maximum values of 7.6 and 6.4 K for PrO0.5F0.5BiS2 and NdO0.5F0.5BiS2, respectively. The pressure-induced transition is characterized by a rapid increase in Tc within a small range in pressure of ∼0.3 GPa for both compounds. In the normal state of PrO0.5F0.5BiS2, the transition pressure Pt correlates with the pressure where the suppression of semiconducting behaviour saturates. In the normal state of NdO0.5F0.5BiS2, Pt is coincident with a semiconductor-metal transition. This behaviour is similar to the results recently reported for the LnO0.5F0.5BiS2 (Ln=La, Ce) compounds. We observe that Pt and the size of the jump in Tc between the two superconducting phases both scale with the lanthanide element in LnO0.5F0.5BiS2 (Ln=La, Ce, Pr, Nd).

Influence of substitution, nonstoichiometry and annealing-conditions on superconductivity and normal conductivity of Fe1+δ (Te1‑x Xx ) (X=Se, S)

Science.gov (United States)

Lima, M. S. L.; ElMassalami, M.; Deguchi, K.; Takeya, H.; Takano, Y.

2018-03-01

Thermal evolution of resistivity, ρ(T, x), of as-prepared samples of Fe1+δ Te1‑x S x (δ ≈ 0, x ≤ 0.2 = solubility limit) demonstrate a granular log-in-T character within Ts < T <300K, a Kondo-like resistive contribution within Tc < T < Ts and granular superconductivity at low temperature (Ts = structural transition point of Fe1+δ Te, Tc =superconducting transition point). We attribute the log-in-T character as well as the nonbulk superconducting features of as-prepared samples to their granular superconductor nature. Annealing in oxygen removes Kondo-like contribution, annihilates pair-breaking centres and establishes bulk superconductivity but, in contrast, the high-temperature granular log-in-T character is hardly influenced. This analysis was successfully extended to the isomorphous Fe1+δ Te1‑x Se x as well as to other types of post-synthesis sample-treatment (e.g. annealing in different gas ambient or soaking in particular liquids).

Introducing Barium in Transition Metal Oxide Frameworks: Impact upon Superconductivity, Magnetism, Multiferroism and Oxygen Diffusion and Storage.

Science.gov (United States)

Raveau, Bernard

2017-06-01

The role of barium in the structural chemistry of some transition metal oxides of the series "Cu, Mn, Fe,Co" is reviewed, based on its size effect and its particular chemical bonding. Its impact upon various properties, superconductivity, magnetism, multiferroism, oxygen storage is emphasized. © 2017 The Chemical Society of Japan & Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electron-phonon superconductivity in YIn3

Science.gov (United States)

Billington, D.; Llewellyn-Jones, T. M.; Maroso, G.; Dugdale, S. B.

2013-08-01

First-principles calculations of the electron-phonon coupling were performed on the cubic intermetallic compound YIn3. The electron-phonon coupling constant was found to be λep = 0.42. Using the Allen-Dynes formula with a Coulomb pseudopotential of μ* = 0.10, a Tc of approximately 0.77 K is obtained which is reasonably consistent with the experimentally observed temperature (between 0.8 and 1.1 K). The results indicate that conventional electron-phonon coupling is capable of producing the superconductivity in this compound.

The war of the cold: an history of the superconductivity; La guerre du froid: une histoire de la supraconductivite

Energy Technology Data Exchange (ETDEWEB)

Matricon, J; Waysand, G [Paris-7 Univ., 75 (France)

1994-12-31

The evolution of superconductivity is described from a scientific, and social points of view. The evolution of researches and realizations towards the absolute zero temperature leading to the discovery of superconductivity by Gilles Holst in 1991, is followed by the theoretical modelization of the superconductivity phenomena leading to the Ginzburg and Landau theory in 1950 and to the Bardeen, Cooper and Schrieffer theory in 1957. Then researches on materials that lead to high-tc superconductors are presented with some applications. (A.B.). refs., figs,. tabs.

High-Tc superconducting antenna-coupled microbolometer on silicon

Science.gov (United States)

Rice, Joseph P.; Grossman, Erich N.; Borcherdt, L. J.; Rudman, D. A.

1994-05-01

A process is described for fabricating antenna-coupled resistive-edge microbolometers based on the high-Tc superconductor YBa2Cu3O7 (YBCO) on silicon. The YBCO and a buffer layer of yttria-stabilized zirconia (YSZ) were grown epitaxially on silicon to minimize excess electrical noise. A silicon-micromachined YBCO/YSZ air-bridge was incorporated to minimize the thermal conductance and the heat capacity. The thermal conductance of the air-bridge was measured to be 3 X 10-6 W/K at a temperature of 100 K. At an operating temperature of 89 K, the detector is estimated to have a response time of 2 microsecond(s) , a responsivity of the 1000 V/W range, and a noise-equivalent power in the 10-12 W/Hz1/2 range at 1000 Hz.

Long-term research in Japan: amorphous metals, metal oxide varistors, high-power semiconductors and superconducting generators

Energy Technology Data Exchange (ETDEWEB)

Hane, G.J.; Yorozu, M.; Sogabe, T.; Suzuki, S.

1985-04-01

The review revealed that significant activity is under way in the research of amorphous metals, but that little fundamental work is being pursued on metal oxide varistors and high-power semiconductors. Also, the investigation of long-term research program plans for superconducting generators reveals that activity is at a low level, pending the recommendations of a study currently being conducted through Japan's Central Electric Power Council.

Liquid phase sintered superconducting cermet

International Nuclear Information System (INIS)

Ray, S.P.

1990-01-01

This patent describes a method of making a superconducting cermet having superconducting properties with improved bulk density, low porosity and in situ stabilization. It comprises: forming a structure of a superconducting ceramic material having the formula RM 2 Cu 3 O (6.5 + x) wherein R is one or more rare earth elements capable of reacting to form a superconducting ceramic, M is one or more alkaline earth metal elements selected from barium and strontium capable of reacting to form a superconducting ceramic, x is greater than 0 and less than 0.5; and a precious metal compound in solid form selected from the class consisting of oxides, sulfides and halides of silver; and liquid phase sintering the mixture at a temperature wherein the precious metal of the precious metal compound is molten and below the melting point of the ceramic material. The liquid phase sintering is carried out for a time less than 36 hours but sufficient to improve the bulk density of the cermet

Local switching of two-dimensional superconductivity using the ferroelectric field effect

Science.gov (United States)

Takahashi, K. S.; Gabay, M.; Jaccard, D.; Shibuya, K.; Ohnishi, T.; Lippmaa, M.; Triscone, J.-M.

2006-05-01

Correlated oxides display a variety of extraordinary physical properties including high-temperature superconductivity and colossal magnetoresistance. In these materials, strong electronic correlations often lead to competing ground states that are sensitive to many parameters-in particular the doping level-so that complex phase diagrams are observed. A flexible way to explore the role of doping is to tune the electron or hole concentration with electric fields, as is done in standard semiconductor field effect transistors. Here we demonstrate a model oxide system based on high-quality heterostructures in which the ferroelectric field effect approach can be studied. We use a single-crystal film of the perovskite superconductor Nb-doped SrTiO3 as the superconducting channel and ferroelectric Pb(Zr,Ti)O3 as the gate oxide. Atomic force microscopy is used to locally reverse the ferroelectric polarization, thus inducing large resistivity and carrier modulations, resulting in a clear shift in the superconducting critical temperature. Field-induced switching from the normal state to the (zero resistance) superconducting state was achieved at a well-defined temperature. This unique system could lead to a field of research in which devices are realized by locally defining in the same material superconducting and normal regions with `perfect' interfaces, the interface being purely electronic. Using this approach, one could potentially design one-dimensional superconducting wires, superconducting rings and junctions, superconducting quantum interference devices (SQUIDs) or arrays of pinning centres.

Formation of a Tc(III)-adenosine diphosphate complex

International Nuclear Information System (INIS)

Torres, J.; Kremer, C.; Kremer, E.

1995-01-01

A 99 Tc-ADP complex was prepared when KTcO 4 was reduced in aqueous medium by SnCl 2 , Na 2 S 2 O 4 , NaBH 4 or Zn in the presence of ADP in excess. The resulting solution was studied by chromatography and spectrophotometry. Electrochemical reduction and substitution on [Tc III (tu) 6 ] 3+ were investigated as alternative synthetic routes. The anionic Tc-ADP complex was isolated as a solid. Cerimetric titrations confirmed the oxidation state +3 for the central atom. IR and 1 H-NMR data showed that the purine base is bonded to the Tc central atom but not the ribose moiety. No oxo groups seemed to be directly bonded to the Tc atom. The complex is rather stable in neutral solutions. However, it decomposes to pertechnetate and TcO 2 at extreme pH values. (author). 16 refs., 2 figs., 3 tabs

Rotational loss of a ring-shaped flywheel supported by high Tc superconducting levitation

International Nuclear Information System (INIS)

Teshima, Hidekazu; Tawara, Taichi; Shimada, Ryuichi.

1997-01-01

This paper describes the experimental results for the rotational loss of a ring-shaped flywheel supported by high T c superconducting levitation. Superconducting levitation is appropriate for rotating a ring-shaped flywheel which has neither shaft nor hub because it is a non-contact and automatically stable levitation without any control systems. The rotational loss has been investigated using a small-scaled experimental machine consisting of 16 bulk superconductors 46 mm in diameter and a ring-shaped flywheel about 300 mm in diameter. The rotational loss decreased as the levitation gap height increased. In low-speed rotational regions, the rotational loss was in proportion to the rotation speed and depended more on the levitation gap. In high-speed rotational regions, the rotational loss was in proportion to the third power of the rotation speed and depended less on the levitation gap. The cubic rotational loss in He was reduced to one-fifth of that in air. The magnetic field pinned in bulk superconductors induces a loss in the materials composing the ring-shaped flywheel. The rotational loss of a ring-shaped flywheel supported by superconducting levitation can be reduced by improving the uniformity of the magnetic fields along the ring, enlargement of the bulk superconductor(s), and densely arranging the bulk superconductors. (author)

Assessment of potential advantages of high Tc-superconductors for technical application of superconductivity

International Nuclear Information System (INIS)

Schauer, F.; Juengst, K.P.; Komarek, P.; Maurer, W.

1987-09-01

A first assessment of the technical and economical consequences of liquid nitrogen cooling of new superconductors is given. For the investigation the applications of superconductivity are classified in two categories: First, systems where superconductors are practically indispensable for achieving the system's objectives; second, superconductor applications in competition with highly developed conventional technologies. Further development of those superconducting systems in the first category for which the cost of cryogenic equipment is a smaller fraction of the total system cost (e.g. fusion reactor or MHD generator) will hardly be affected. However, for systems like particle accelerators, research magnets, and NMR spectroscopy and imaging systems, the cryogenic equipment expenditures are significant and LN 2 cooling leads here to a reduction of investment and operating costs, to simplified handling and maintenance, to better reliability and availability, and will thereby improve the acceptance and further spread of these systems. In the second category each application of superconductivity has to be compared with its conventional counterpart, separately. Here, electonic components, power switches, resistive current limiters, and especially the power transmission cables are those applications which look most promising. For magnet applications the main advantageous arguments are less the cost saving aspect but more the higher reliability, simplicity, N 2 -availability, and ease of handling. (orig.) [de

Ceramic superconductors II

International Nuclear Information System (INIS)

Yan, M.F.

1988-01-01

This volume compiles papers on ceramic superconductors. Topics include: structural patterns in High-Tc superconductors, phase equilibria of barium oxide superconductors, localized electrons in tetragonal YBa/sub 2/Cu/sub 3/O/sub 7-δ/, lattice and defect structure and properties of rare earth/alkaline earth-copper-oxide superconductors, alternate candidates for High-Tc superconductors, perovskite-structure superconductors; superconductive thin film fabrication, and superconductor/polymer composites

Investigation of Pb doping on electrical, structural and superconducting properties of YBa2-xPbxCu3O7-δ superconductors

Science.gov (United States)

Ezzatpour, S.; Sharifzadegan, L.; Sarvari, F.; Sedghi, H.

2018-06-01

In this study the high temperature superconductor YBa2-xPbxCu3O7-δ with doping x = ,0.05,0.1,0.15 were prepared by the standard solid-state reaction method. The effect of Pb substitution on Ba site of YBCO superconducting system, structural, electrical and superconducting properties of Y-based superconductor has been investigated. The measurements of dc resisitivity were performed on all samples with four-probe method using low frequency/lowAC current (4 mA) . The superconducting temperature, Tc, were determined from the resistivity versus temperature (R-T) curves. Results show that Pb doping reduced the cirtical temperature(Tc) and superconductivity properties of our samples. The maximum and the minimum Tc were observed for the samples with x = 0.15 and x = 0.1 respectively. The structure and phase purity of samples were examined by the X-ray powder diffraction technique (XRD) performed by means of D8 Advance Bruker diffractometer with Cu kα radiation. The grain morphology of surface of the samples was analyzed by sacanning electron microscopy (SEM). XRD patterns of polycrystalline materials of composition YBa2-xPbxCu3O7-δ revealed that all prepared samples are orthorhombic. All of the peaks of YBCO and YBa2-xPbxCu3O7-δ have been used for the estimation of volume fractions of the phases and ignored the void peaks.

A Tc-99m-labeled long chain fatty acid derivative for myocardial imaging.

Science.gov (United States)

Magata, Yasuhiro; Kawaguchi, Takayoshi; Ukon, Misa; Yamamura, Norio; Uehara, Tomoya; Ogawa, Kazuma; Arano, Yasushi; Temma, Takashi; Mukai, Takahiro; Tadamura, Eiji; Saji, Hideo

2004-01-01

C-11- and I-123-labeled long chain fatty acid derivatives have been reported as useful radiopharmaceuticals for the estimation of myocardial fatty acid metabolism. We have reported that Tc-99m-labeled N-[[[(2-mercaptoethyl)amino]carbonyl]methyl]-N-(2-mercaptoethyl)-6-aminohexanoic acid ([(99m)Tc]MAMA-HA), a medium chain fatty acid derivative, is metabolized by beta-oxidation in the liver and that the MAMA ligand is useful for attaching to the omega-position of fatty acid derivatives as a chelating group for Tc-99m. On the basis of these findings, we focused on developing a Tc-99m-labeled long chain fatty acid derivative that reflected fatty acid metabolism in the myocardium. In this study, we synthesized a dodecanoic acid derivative, MAMA-DA, and a hexadecanoic acid derivative, MAMA-HDA, and performed radiolabeling and biodistribution studies. [(99m)Tc]MAMA-DA and [(99m)Tc]MAMA-HDA were prepared using a ligand-exchange reaction. Biodistribution studies were carried out in normal mice and rats. Then, a high initial uptake of Tc-99m was observed, followed by a rapid clearance from the heart. The maximum heart/blood ratio was 3.6 at 2 min postinjection of [(99m)Tc]MAMA-HDA. These kinetics were similar to those with postinjection of p-[(125)I]iodophenylpentadecanoic acid. Metabolite analysis showed [(99m)Tc]MAMA-HDA was metabolized by beta-oxidation in the body. In conclusion, [(99m)Tc]MAMA-HDA is a promising compound as a long chain fatty acid analogue for estimating beta-oxidation of fatty acid in the heart.

Superconductivity in engineered two-dimensional electron gases

Science.gov (United States)

Chubukov, Andrey V.; Kivelson, Steven A.

2017-11-01

We consider Kohn-Luttinger mechanism for superconductivity in a two-dimensional electron gas confined to a narrow well between two grounded metallic planes with two occupied subbands with Fermi momenta kF L>kF S . On the basis of a perturbative analysis, we conclude that non-s -wave superconductivity emerges even when the bands are parabolic. We analyze the conditions that maximize Tc as a function of the distance to the metallic planes, the ratio kF L/kF S , and rs, which measures the strength of Coulomb correlations. The largest attraction is in p -wave and d -wave channels, of which p wave is typically the strongest. For rs=O (1 ) we estimate that the dimensionless coupling λ ≈10-1 , but it likely continues increasing for larger rs (where we lose theoretical control).

Influence of ion beam mixing on the growth of high temperature oxide superconducting thin film

International Nuclear Information System (INIS)

Bordes, N.; Rollett, A.D.; Cohen, M.R.; Nastasi, M.

1989-01-01

The superconducting properties of high temperature superconductor thin films are dependent on the quality of the substrate used to grow these films. In order to maximize the lattice matching between the superconducting film and the substrate, we have used a YBa 2 Cu 3 O 7 thin film deposited on left-angle 100 right-angle SrTiO 3 as a template. The first film was prepared by coevaporation of Y, BaF 2 and Cu on left-angle 100 right-angle SrTiO 3 , followed by an anneal in ''wet'' oxygen at 850 degree C. This film showed a sharp transition at about 90 K. A thicker layer of about 5000 A was then deposited on top of this first 2000 angstrom film, using the same procedure. After the post anneal at 850 degree C, the transition took place at 80 K and no epitaxy of the second film was observed. Ion beam mixing at 400 degree C, using 400 keV O ions was done at the interface of the two films (the second one being not annealed). After the post anneal, the film displayed an improved Tc at 90K. Moreover, epitaxy was shown to take place from the interface SrTiO 3 -123 film towards the surface and was dependent of the dose. These results will be discussed from the data obtained from Rutherford backscattering spectroscopy (RBS) combined with channeling experiments, x-ray diffraction (XRD) and scanning electron microscopy (SEM) observations. 8 refs., 2 figs., 2 tabs

The filled skutterudite PrOs{sub 4}Sb{sub 12}: superconductivity and correlations; La skutterudite PrOs{sub 4}Sb{sub 12}: supraconductivite et correlations

Energy Technology Data Exchange (ETDEWEB)

Measson, M.A

2005-12-15

The filled skutterudite PrOs{sub 4}Sb{sub 12} is the first Pr-based heavy fermion superconductor. This thesis addresses several important open questions including the determination of the quasi-particle mass renormalisation, the nature and mechanism of superconductivity, and the intrinsic or extrinsic nature of the double superconducting transition seen in the specific heat. A fit of the specific heat with magnetic interactions between the ions Pr is proposed. We extract from it an electronic term of between 300-750 mJ/K{sup 2}.mol(Pr). Analysis of the specific heat jump provides evidence that heavy carriers are involved in Cooper pairing and that superconductivity is strongly coupled. Extensive characterizations by specific heat, resistivity, susceptibility measurements show that a double transition appears in the best samples. Nevertheless we bring the first serious doubts on the intrinsic nature of the double transition, because we have found samples with a single sharp transition at Tc2 and because the ratio of the two specific heat jumps shows strong dispersion among the samples. Furthermore we have measured the superconducting phase diagrams with an A.C. specific heat technique under magnetic field and under pressure up to 4.2 GPa, and we show that the two transitions, Tc1 and Tc2, exhibit similar behaviours with magnetic field and pressure. We find a strong change in the pressure dependence of Tc's above 2 GPa which might be related to a change in the nature of the superconductivity under pressure (at least partially mediated by fluctuations and only by phonons at respectively low and high pressure) which may be linked to the increase of the crystal field gap of the Pr ions. Analysis of the upper critical field shows the presence of at least two superconducting bands and concludes to a singlet nature of the pairing. A strong distortion of the flux-line lattice, which is constant with temperature and field, is obtained by small angle neutron scattering

Spin-fluctuation mechanism of high-Tc superconductivity and order-parameter symmetry

International Nuclear Information System (INIS)

Izyumov, Yurii A

1999-01-01

The notion that electrons in high-T c cuprates pair via antiferromagnetic spin fluctuations is discussed and the symmetry of the superconducting order parameter is analyzed. Three approaches to the problem, one phenomenological (with an experimental dynamic magnetic susceptibility) and two microscopic (involving, respectively, the Hubbard model and the tJ-model) are considered and it is shown that in each case strong-coupling theory leads to a d-wave order parameter with zeros at the Fermi surface. The review then proceeds to consider experimental techniques in which the d-symmetry of the order parameter may manifest itself. These include low-temperature thermodynamic measurements, measurements of the penetration depth and the upper critical field, Josephson junction experiments to obtain the phase of the superconducting order parameter, and various spectroscopic methods. The experimental data suggest that the order parameter in cuprates is d x 2 -y 2 -wave. Ginzburg-Landau theory for a superconductor with a d-wave order parameter is outlined and both an isolated vortex and a vortex lattice are investigated. Finally, some theoretical aspects of the effects of nonmagnetic impurities on a d-wave superconductor are considered. (reviews of topical problems)

The Electrical Aspects of the choice of Former in a High T-c Superconducting Power Cable

DEFF Research Database (Denmark)

Däumling, Manfred; Kühle (fratrådt), Anders Van Der Aa; Olsen, Søren Krüger

1999-01-01

Centrally located in a superconducting power cable the former supplies a rigid means onto which to wind the superconducting tapes and enables a continuous supply of cooling power via a flow of liquid cryogen through it. Therefore, the choice of former has a broad impact on the construction and de...

Magnetic profiles in ferromagnetic/superconducting superlattices.

Energy Technology Data Exchange (ETDEWEB)

te Velthuis, S. G. E.; Hoffmann, A.; Santamaria, J.; Materials Science Division; Univ. Complutense de Madrid

2007-02-28

The interplay between ferromagnetism and superconductivity has been of longstanding fundamental research interest to scientists, as the competition between these generally mutually exclusive types of long-range order gives rise to a rich variety of physical phenomena. A method of studying these exciting effects is by investigating artificially layered systems, i.e. alternating deposition of superconducting and ferromagnetic thin films on a substrate, which enables a straight-forward combination of the two types of long-range order and allows the study of how they compete at the interface over nanometer length scales. While originally studies focused on low temperature superconductors interchanged with metallic ferromagnets, in recent years the scope has broadened to include superlattices of high T{sub c} superconductors and colossal magnetoresistance oxides. Creating films where both the superconducting as well as the ferromagnetic layers are complex oxide materials with similar crystal structures (Figure 1), allows the creation of epitaxial superlattices, with potentially atomically flat and ordered interfaces.

10th International Symposium on Superconductivity

CERN Document Server

Hirabayashi, Izumi

1998-01-01

The International Symposium on Superconductivity, which has been held annu­ ally since 1988, is a forum for presenting the most up-to-date information about a broad range of research and development in superconductivity, from funda­ mental aspects to applications. More than 10 years have passed since the discovery of oxide superconductors and since various developments of applications began. It may be said that the prospects for application of oxide superconductors recently have opened up. Great progress has been made toward practical use, for example, of the flywheel, which uses bulk materials, and the high-performance cryo-cooled magnet made of bismuth wire. These were the results of persistent efforts to develop materials from the viewpoint of materials science and engineering. Also important is the progress in comprehensive understanding of high­ temperature superconductivity. Unique electronic properties of cuprates such as the non-Fermi liquid normal state, spin-charge separation, spin gap, and d-wav...

Doping dependence of low-energy quasiparticle excitations in superconducting Bi2212.

Science.gov (United States)

Ino, Akihiro; Anzai, Hiroaki; Arita, Masashi; Namatame, Hirofumi; Taniguchi, Masaki; Ishikado, Motoyuki; Fujita, Kazuhiro; Ishida, Shigeyuki; Uchida, Shinichi

2013-12-05

: The doping-dependent evolution of the d-wave superconducting state is studied from the perspective of the angle-resolved photoemission spectra of a high-Tc cuprate, Bi2Sr2CaCu2 O8+δ (Bi2212). The anisotropic evolution of the energy gap for Bogoliubov quasiparticles is parametrized by critical temperature and superfluid density. The renormalization of nodal quasiparticles is evaluated in terms of mass enhancement spectra. These quantities shed light on the strong coupling nature of electron pairing and the impact of forward elastic or inelastic scatterings. We suggest that the quasiparticle excitations in the superconducting cuprates are profoundly affected by doping-dependent screening.

The design of high-Tc superconductors - Room-temperature superconductivity?

International Nuclear Information System (INIS)

Tallon, J.L.; Storey, J.G.; Mallett, B.

2012-01-01

This year is the centennial of the discovery of superconductivity and the 25th anniversary of the discovery of high-T c superconductors (HTS). Though we still do not fully understand how HTS work, the basic rules of design can be determined from studying their systematics. We know what to do to increase T c and, more importantly, what to do to increase critical current density J c . This in turn lays down a challenge for the chemist. Can the ideal design be synthesized? More importantly, what are the limits? Can one make a room-temperature superconductor? In fact fluctuations place strict constraints on this objective and provide important guidelines for the design of the ideal superconductor.

Fe-vacancy and superconductivity in FeSe-based superconductors

Science.gov (United States)

Wang, C. H.; Chen, T. K.; Chang, C. C.; Lee, Y. C.; Wang, M. J.; Huang, K. C.; Wu, P. M.; Wu, M. K.

2018-06-01

This review summarizes recent advancements in FeSe and related systems. The FeSe and related superconductors are currently receiving considerable attention for the high Tcs observed and for many similar features to the high Tc cuprate superconductors. These similarities suggest that understanding the FeSe based compounds could potentially help our understanding of the cuprates. We shall first review the common features observed in the FeSe-based system. It was found that with a careful control of material synthesizing processes, numerous rich phases have been observed in the FeSe-based system. Detailed studies show that the Fe-vacancy ordered phases found in the FeSe based compounds, which are non-superconducting Mott insulators, are the parent compounds of the superconductors. Superconductivity emerges from the parent phases by disordering the Fe vacancy order, often by a simple annealing treatment. Recent high temperature X-ray diffraction experiments show that the degree of structural distortion associated with the disorder of Fe-vacancy is closely related to volume fraction of the superconductivity observed. These results suggest the strong lattice to spin coupling are important for the occurrence of superconductivity in FeSe based superconductors.

Anomalous pressure dependence of the superconducting transition temperature in the β-Pyrochlore KOs2O6

Science.gov (United States)

Miyoshi, Kiyotaka; Takaichi, Yuta; Takeuchi, Jun

2009-03-01

DC magnetic measurements have been performed for β-pyrochlore superconductor KOs2O6 (Tc = 9.6 K) under pressure for the precise determination of the pressure dependence of Tc, using a miniature diamond anvil cell combined with a commercial SQUID magnetometer. It is found that the critical temperature Tc shows a maximum of ~10 K at P=0.5 GPa. The maximum of Tc is higher than that for CsOs2O6 and RbOs2O6, in both of which Tc is known to increase and saturate at Tcm = 8.8 K by the application of pressure, suggesting the enhanced superconductivity due to the rattling of K ions in an oversized cage of Os-O network. For the further application of pressure, Tc decreases linearly but the decreasing rate appears to be suddenly changed at P~2 GPa and Tc~8 K. The sharp bend of the Tc — P line probably corresponds to the transition concerning to the rattling motion which occurs at Tp=7.5 K at ambient pressure, suggesting the positive pressure dependence of Tp.

Uniaxial-Strain-Orientation Dependence of the Competition between Mott and Charge Ordered Phases and their Corresponding Superconductivity of β-(BDA-TTP)2I3

Science.gov (United States)

Nuruzzaman, Md.; Yokogawa, Keiichi; Yoshino, Harukazu; Yoshimoto, Haruo; Kikuchi, Koichi; Kaihatsu, Takayuki; Yamada, Jun-ichi; Murata, Keizo

2012-12-01

We studied the electronic transport properties of the charge transfer salt β-(BDA-TTP)2I3 [BDA-TTP: 2,5-bis(1,3-dithian-2-ylidene)-1,3,4,6-tetrathiapentalene] by applying uniaxial strains along the three crystallographic axes, and obtained three corresponding temperature-pressure phase diagrams. Three phase diagrams were quite dependent on the direction of compression. Following the preceding paper by Kikuchi et al., we speculate that the insulating states are of 1/2-filled Mott insulators for the a- and b-axes compressions, and of 1/4-filled charge ordered states for the c-axis compression as well as hydrostatic pressure. The superconducting phase under uniaxial strain was realized with Tc = 5 K at 1.9 GPa along the a-axis and with Tc = 5.6 K at 1.75 GPa along the b-axis. Superconductivity was also reproduced with a Tc of 9.5 K at 1.0 GPa for the c-axis compressions in the range of 0.85 to 1.53 GPa as previously reported. We studied tentative measurement on upper critical fields, Bc2's of these superconductivities and found that the extrapolated values, Bc2(0)'s, exceeded Pauli-limit by about 2--3 times. However, at least in terms of Bc2, the difference in superconductivity associated with two different insulating states was not clear.

Depth profiling of superconducting thin films using rare gas ion sputtering with laser postionization

Science.gov (United States)

Pallix, J. B.; Becker, C. H.; Missert, N.; Char, K.; Hammond, R. H.

1988-02-01

Surface analysis by laser ionization (SALI) has been used to examine a high-Tc superconducting thin film of nominal composition YBa2Cu3O7 deposited on SrTiO3 (100) by reactive magnetron sputtering. The main focus of this work was to probe the compositional uniformity and the impurity content throughout the 1800 Å thick film having critical current densities of 1 to 2×106 A/cm2. SALI depth profiles show this film to be more uniform than thicker films (˜1 μm, prepared by electron beam codeposition) which were studied previously, yet the data show that some additional (non-superconducting) phases derived from Y, Ba, Cu, and O are still present. These additional phases are studied by monitoring the atomic and diatomic-oxide photoion profiles and also the depth profiles of various clusters (e.g. Y2O2+, Y2O3+, Y3O4+, Ba2O+, Ba2O2+, BaCu+, BaCuO+, YBaO2+, YSrO2+, etc.). A variety of impurities are observed to occur throughout the film including rather large concentrations of Sr. Hydroxides, F, Cl, and COx are evident particularly in the sample's near surface region (the top ˜100 Å).

Microwave superconductivity for particle accelerators - How the high TC superconductors measure up

International Nuclear Information System (INIS)

Padamsee, H.; Green, K.; Gruschus, J.

1988-01-01

Application of superconducting niobium cavities to accelerators for high energy physics, nuclear physics and free electron laser is growing rapidly. Cornell has a long standing effort in the development of superconducting RF accelerator technology. Nb cavities developed here from the basis for constructing the world's highest energy electron accelerator for nuclear physics. These cavities have set a standard against which the behavior of the new superconductors must be compared. From available results on dc critical fields, and the energy gap, it appears that the new materials could make a significant impact on the capabilities of future accelerators. Crucial to this assessment, however, are direct microwave loss measurements, together with measurements of the energy gap and RF frequency dependence as well as the behavior at high RF fields. Latest results on these properties for bulk sintered ceramics, thin films and single crystals at RF frequencies of 1.5 and 6 Ghz are presented

Control of superconductivity by means of electric-field-induced strain in superconductor/piezoelectric hybrids

Science.gov (United States)

Stamopoulos, D.; Zeibekis, M.; Zhang, S. J.

2018-01-01

The controlled modification of superconductivity by any means, specifically in hybrid systems, has attracted much interest in the recent decades. Here, we present experimental data and phenomenological modeling on the control of TC of superconducting (SC) Nb thin films, with thickness 3 nm ≤ dN b≤50 nm, under the application of in-plane strain, S(Eex) induced by an external out-of-plane electric field, Eex to piezoelectric (PE) single crystals, namely, ( 1 -x )Pb(Mg1/3Nb2/3)O3-xPbTiO3 (PMN-xPT), with x = 0.27 and 0.31. We report experimental modification of TC of Nb by Eex, accurately described by a phenomenological model that incorporates the constitutive relation S(Eex) of PMN-xPT. The systematic experimental-phenomenological modeling approach introduced here is generic and paves the way for an understanding of the underlying physical mechanisms in any SC/PE hybrid.

Localized chemistry of 99Tc in simulated low activity waste glass

Science.gov (United States)

Weaver, Jamie L.

A priority of the United States Department of Energy (DOE) is to dispose of the nuclear waste accumulated in the underground tanks at the Hanford Nuclear Reservation in Richland, WA. Incorporation and stabilization of technetium (99Tc) from these tanks into vitrified waste forms is a concern to the waste glass community and DOE due to 99Tc's long half-life ( 2.13˙105 y), and its high mobility in the subsurface environment under oxidizing conditions. Working in collaboration with researchers at Pacific Northwest National Laboratory (PNNL) and other national laboratories, plans were formulated to obtain first-of-a-kind chemical structure determination of poorly understood and environmentally relevant technetium compounds that relate to the chemistry of the Tc in nuclear waste glasses. Knowledge of the structure and spectral signature of these compounds aid in refining the understanding of 99Tc incorporation into and release from oxide based waste glass. In this research a first-of-its kind mechanism for the behavior of 99Tc during vitrification is presented, and the structural role of Tc(VII) and (IV) in borosilicate waste glasses is readdressed.

Splitting of the resistive transition of copper oxide superconductors: Intrinsic double superconducting transitions versus extrinsic effects

International Nuclear Information System (INIS)

Pomar, A.; Curras, S.R.; Veira, J.A.; Vidal, F.

1996-01-01

To prove the possible existence of an intrinsic double superconducting transition in the high-temperature copper oxide superconductors (HTSC), an effect recently attributed by various groups to different intrinsic properties of these materials (including unconventional wave pairing), we present in this paper high resolution data of the electrical resistivity, ρ(T), around the superconducting transition of different single crystal and polycrystal YBa 2 Cu 3 O 7-δ samples. The analysis of the temperature derivative of these ρ(T) data strongly suggests that (i) with a temperature resolution well to within 20 mK, the intrinsic resistive transition of the HTSC does not present any double transition anomaly and (ii) the double peak structure observed in dρ(T)/dT by some authors is probably an extrinsic effect (associated with stoichiometric inhomogeneities in some cases, and with experimental artifacts in other cases). copyright 1996 The American Physical Society

Magneto-transport properties of Co3O4 nanoparticles added (Cu0.5Tl0.5)Ba2Ca2Cu3O10-δ superconducting phase

Science.gov (United States)

Mumtaz, M.; Baig, Mirza Hassan; Waqee-ur-Rehman, M.; Nasir Khan, M.

2018-05-01

Solid-state reaction method was used to synthesize Cu0.5Tl0.5Ba2Ca2Cu3O10-δ (CuTl-1223) superconducting phase and sol-gel method was used to prepare cobalt oxide (Co3O4) magnetic nanoparticles. These Co3O4 nanoparticles were added in CuTl-1223 superconducting matrix to get (Co3O4)x/CuTl-1223; x = 0-2.00 wt.% nanoparticles-superconductor composites. The effects of Co3O4 nanoparticles on crystal structure, phase formation, phase purity and infield superconducting transport properties of CuTl-1223 phase were investigated at different operating temperatures and external applied magnetic fields. The crystal structure and phase formation of Co3O4 nanoparticles and CuTl-1223 superconductor were determined by X-ray diffraction (XRD) technique. XRD peaks of Co3O4 nanoparticles were well indexed according to FCC crystal structure and the average particle size of 70 nm was calculated by using Debye-Scherer's formula. The unaltered crystal structure of host CuTl-1223 superconducting phase (i.e. Tetragonal) with the addition of Co3O4 nanoparticles indicated the dispersion of nanoparticles at inter-granular sites. Temperature dependent magneto-transport superconducting properties of (Co3O4)x/CuTl-1223 composites were investigated by zero field cooled (ZFC) and field cooled (FC) magnetic moment versus temperature (M-T) measurements. The onset transition temperatures {TcOnset (K)} was decreased along with the suppression of diamagnetic amplitude of CuTl-1223 superconducting phase with the addition of magnetic Co3O4 nanoparticles. Temperature dependent magnetic hysteresis (M-H loops) measurements of (Co3O4)x/CuTl-1223 composites were carried out at different operating temperatures from 5 K to 150 K. Critical current density (Jc) was calculated from M-H loops measurements by using Bean's model. Like the suppression of TcOnset (K) values, Jc was also decreased with the inclusion of Co3O4 nanoparticles. It was also observed that variation of Jc with H followed the power law Jc = �

High-{Tc} superconducting antenna-coupled microbolometer on silicon

Energy Technology Data Exchange (ETDEWEB)

Rice, J.P.; Grossman, E.N.; Borcherdt, L.J.; Rudman, D.A. [National Inst. of Standards and Technology, Boulder, CO (United States). Cryoelectronic Metrology Group

1994-12-31

A process is described for fabricating antenna-coupled resistive-edge microbolometers based on the high-{Tc} superconductor YBa{sub 2}Cu{sub 3}O{sub 7} (YBCO) on silicon. The YBCO and a buffer layer of yttria-stabilized zirconia (YSZ) were grown epitaxially on silicon to minimize excess electrical noise. A silicon-micromachined YBCO/YSZ air-bridge was incorporated to minimize the thermal conductance and the heat capacity. The thermal conductance of the air-bridge was measured to be 3 {times} 10{sup {minus}6} W/K at a temperature of 100 K. At an operating temperature of 89 K, the detector is estimated to have a response time of 2 {micro}s, a responsivity in the 1,000 V/W range, and a noise-equivalent power (NEP) in the 10{sup {minus}12} W/Hz{sup 1/2} range at 1,000 Hz.

The Effect of Twins on Critical Currents of High Tc Superconductors

Science.gov (United States)

1989-01-01

particles to stick together due to electrostatic forces. To overcome this we have formed a slurry of the material in liquid nitrogen and flash...can use and the liquid convection tends to counteract the separation process. We have-now designed a magnetic track which particles will slide down with...Currents of High Tc Superconductors" - A.M. Campbell and M.F. Ashby The initial work on levitation forces and separation of superconducting powders has

Superconducting property measuring system by magnetization method

International Nuclear Information System (INIS)

Ikisawa, K.; Mori, T.; Takasu, N.

1988-01-01

Superconducting property measuring system (CMS-370B) for high temperature oxide superconductor has been developed. This system adopts magnetization measurement. The superconducting properties are able to be measured automatically and continuously changing the temperature and external magnetic field. The critical current density as a function of temperature and magnetic field of high temperature superconductor YBa 2 Cu 3 O 7-y (YBCO) has been measured. This paper reports how it was confirmed that this system having the high performance and the accuracy gave the significant contribution to the superconducting material development

Impeding 99Tc(IV) mobility in novel waste forms

Science.gov (United States)

Lee, Mal-Soon; Um, Wooyong; Wang, Guohui; Kruger, Albert A.; Lukens, Wayne W.; Rousseau, Roger; Glezakou, Vassiliki-Alexandra

2016-01-01

Technetium (99Tc) is an abundant, long-lived radioactive fission product whose mobility in the subsurface is largely governed by its oxidation state. Tc immobilization is crucial for radioactive waste management and environmental remediation. Tc(IV) incorporation in spinels has been proposed as a novel method to increase Tc retention in glass waste forms during vitrification. However, experiments under high-temperature and oxic conditions show reoxidation of Tc(IV) to volatile pertechnetate, Tc(VII). Here we examine this problem with ab initio molecular dynamics simulations and propose that, at elevated temperatures, doping with first row transition metal can significantly enhance Tc retention in magnetite in the order Co>Zn>Ni. Experiments with doped spinels at 700 °C provide quantitative confirmation of the theoretical predictions in the same order. This work highlights the power of modern, state-of-the-art simulations to provide essential insights and generate theory-inspired design criteria of complex materials at elevated temperatures. PMID:27357121

High critical temperature superconducting composite and fabrication process

International Nuclear Information System (INIS)

Dubots, P.; Legat, D.

1989-01-01

The core comprises a high temperature superconducting sintered oxide coated with alumina or barium oxide covered with a first sheath in aluminum, a second sheath in niobium and a third sheath in copper [fr

Purification of condenser water in thermal power station by superconducting magnetic separation

International Nuclear Information System (INIS)

Ha, D.W.; Kwon, J.M.; Baik, S.K.; Lee, Y.J.; Han, K.S.; Ko, R.K.; Sohn, M.H.; Seong, K.C.

2011-01-01

Magnetic separation using cryo-cooled Nb-Ti superconducting magnet was applied for the purification of condenser water. Iron oxides in condenser water were effectively removed by superconducting magnetic separation. The effect of magnetic field strength and filter size was determined. Thermal power station is made up of a steam turbine and a steam condenser which need a lot of water. The water of steam condenser should be replaced, since scales consisting of iron oxide mainly are accumulated on the surface of condenser pipes as it goes. Superconducting high gradient magnetic separation (HGMS) system has merits to remove paramagnetic substance like iron oxides because it can generate higher magnetic field strength than electromagnet or permanent magnet. In this paper, cryo-cooled Nb-Ti superconducting magnet that can generate up to 6 T was used for HGMS systems. Magnetic filters were designed by the analysis of magnetic field distribution at superconducting magnets. The result of X-ray analysis showed contaminants were mostly α-Fe 2 O 3 (hematite) and γ-Fe 2 O 3 (maghemite). The higher magnetic field was applied up to 6 T, the more iron oxides were removed. As the wire diameter of magnetic filter decreased, the turbidity removal of the sample was enhanced.

Behavior of high Tc-superconductors and irradiated defects under reactor irradiation

International Nuclear Information System (INIS)

Atobe, Kozo; Honda, Makoto; Fukuoka, Noboru; Yoshida, Hiroyuki.

1991-01-01

It has been well known that the lattice defects of various types are introduced in ceramics without exception, and exert large effect to the function of these materials. Among oxides, the electronic materials positively using oxygen defect control have been already put in practical use. Also in the oxide high temperature superconductors which are Perovskite type composite oxides, the superconductive characteristics are affected largely by the concentration of the oxygen composing them. This is regarded as an important factor for causing superconductivity, related with the oxygen cavities arising at this time and the carriers bearing superconductivity. In this study, the irradiation effect with relatively low dose, the measurement under irradiation, the effect of irradiation temperature, and the effect of radiation quality were evaluated by the irradiation of YBCO, EBCO and LBCO. The experimental method, and the irradiation effect at low temperature and normal temperature, the effect of Co-60 gamma ray irradiation instead of reactor irradiation are reported. (K.I.)

Spatial distribution of superconducting and charge-density-wave order parameters in cuprates and its influence on the quasiparticle tunnel current (Review Article)

Science.gov (United States)

Gabovich, Alexander M.; Voitenko, Alexander I.

2016-10-01

The state of the art concerning tunnel measurements of energy gaps in cuprate oxides has been analyzed. A detailed review of the relevant literature is made, and original results calculated for the quasiparticle tunnel current J(V) between a metallic tip and a disordered d-wave superconductor partially gapped by charge density waves (CDWs) are reported, because it is this model of high-temperature superconductors that becomes popular owing to recent experiments in which CDWs were observed directly. The current was calculated suggesting the scatter of both the superconducting and CDW order parameters due to the samples' intrinsic inhomogeneity. It was shown that peculiarities in the current-voltage characteristics inherent to the case of homogeneous superconducting material are severely smeared, and the CDW-related features transform into experimentally observed peak-dip-hump structures. Theoretical results were used to fit data measured for YBa2Cu3O7-δ and Bi2Sr2CaCu2O8+δ. The fitting demonstrated a good qualitative agreement between the experiment and model calculations. The analysis of the energy gaps in high-Tc superconductors is important both per se and as a tool to uncover the nature of superconductivity in cuprates not elucidated so far despite of much theoretical effort and experimental progress.

Models of high-Tc superconductivity and applications to electric generators and motors

DEFF Research Database (Denmark)

Sørensen, Mads Peter

We present the Ginzburg Landau model for mesoscopic high-Tc superconductors of complex geometry. It is shown that giant vortices can form at boundary defects. The relation between total magnetic flux penetration through the superconductor and the externally applied field is established. This is i...

High-pressure studies of superconductivity in BiO0. 75F0. 25BiS2

Indian Academy of Sciences (India)

). We have investigated the effect of pressure on magnetization measurements. Our studies suggest improved superconducting properties in polycrystalline samples of BiO 0.75 F 0.25 BiS 2 . The Tc in our sample is 5.3 K, at ambient pressure, ...

Kramers non-magnetic superconductivity in LnNiAsO superconductors.

Science.gov (United States)

Li, Yuke; Luo, Yongkang; Li, Lin; Chen, Bin; Xu, Xiaofeng; Dai, Jianhui; Yang, Xiaojun; Zhang, Li; Cao, Guanghan; Xu, Zhu-an

2014-10-22

We investigated a series of nickel-based oxyarsenides LnNiAsO (Ln=La, Ce, Pr, Nd, Sm) compounds. CeNiAsO undergoes two successive anti-ferromagnetic transitions at TN1=9.3 K and TN2=7.3 K; SmNiAsO becomes an anti-ferromagnet below TN≃3.5 K; NdNiAsO keeps paramagnetic down to 2 K but orders anti-ferromagnetically below TN≃1.3 K. Superconductivity was observed only in Kramers non-magnetic LaNiAsO and PrNiAsO with Tc=2.7 K and 0.93 K, respectively. The superconductivity of PrNiAsO is further studied by upper critical field and specific heat measurements, which reveal that PrNiAsO is a weakly coupled Kramers non-magnetic superconductor. Our work confirms that the nickel-based oxyarsenide superconductors are substantially different in mechanism to iron-based ones, and are likely to be described by the conventional superconductivity theory.

Quantum Statistical Approach to Superconductivity

Science.gov (United States)

Nam, Eunsoo

The Frohlich Hamiltonian representing an interaction between electron and phonon is derived. By exchanging a virtual phonon, a system of two electrons can lower the system's total energy if the difference of their kinetic energies is less than the energy of the phonon exchanged. This is shown by using quantum mechanical perturbation theory, which is fully developed. A general theory of superconductivity is developed, starting with a BCS Hamiltonian in which the interaction strengths (V_{11}, V_{22 }, V_{12}) among and between "electron" (1) and "hole" (2) Cooper pairs are differentiated. The supercondensate is shown to be composed of equal numbers of "electron" and "hole" ground (zero-momentum) Cooper pairs with charges mp 2e.. Based on the Hamiltonian, the normal-to-super phase transition is investigated, approaching the critical temperature T_{c} from the high temperature side. Non zero momentum Cooper pairs, that is, pairs of electrons (holes) with antiparallel spins and nearly opposite momenta above T_{c } in the bulk limit, are shown to move like independent bosons with the energy momentum relation varepsilon = (1/2)upsilon_ {F}p, where upsilon_ {F} represents the Fermi velocity. We have investigated the Bose-Einstein condensation of pairons. The system of free Cooper pairs in a 3D superconductors undergoes a phase transition of the second order with the critical temperature T_{c} given byk_{B}T_{c } = (1/2)(pi^2hbar^3v_sp {F}{3}n/1.20257)^{1over3 }where n is the number density of Cooper pairs. We calculate various properties associated with superconductivity at finite temperature. We derive general expressions for the energy gaps for both quasi electrons and pairons. Based on the independent pairon model, we explain the flux quantization, London's equation and the Josephson effects, stressing the importance of the macroscopic wave -function which represents the supercondensate in motion. We derived the basic equations governing the behavior of the

Spin-polaron theory of high-Tc superconductivity: I, spin polarons and high-Tc pairing

International Nuclear Information System (INIS)

Wood, R.F.

1993-06-01

The concept of a spin polaron is introduced and contrasted with the more familiar ionic polaron picture. A brief review of aspects of ionic bipolaronic superconductivity is given with particular emphasis on the real-space pairing and true Bose condensation characteristics. The formation energy of spin polarons is then calculated in analogy with ionic polarons. The spin-flip energy of a Cu spin in an antiferromagnetically aligned CuO 2 plane is discussed. It is shown that the introduction of holes into the CuO 2 planes will always lead to the destruction of long-range AF ordering due to the formation of spin polarons. The pairing of two spin polarons can be expected because of the reestablishment of local (short-range) AF ordering; the magnitude of the pairing energy is estimated using a simplified model. The paper closes with a brief discussion of the formal theory of spin polarons

Superconductivity and magnetic order in the noncentrosymmetric half-Heusler compound ErPdBi

NARCIS (Netherlands)

Pan, Y.; Nikitin, A.M.; Bay, T.V.; Huang, Y.K.; Paulsen, C.; Yan, B.H.; de Visser, A.

2013-01-01

We report superconductivity at Tc = 1.22 K and magnetic order at TN = 1.06\\ K in the semimetallic noncentrosymmetric half-Heusler compound ErPdBi. The upper critical field, Bc2, has an unusual quasi-linear temperature variation and reaches a value of 1.6 T for T - 0 . Magnetic order is found below

6. Trilateral German-Russian-Ukrainian seminar on high-temperature superconductivity

International Nuclear Information System (INIS)

Aksenov, V.L.; Kornilov, E.I.

1993-01-01

The proceedings of the 6. Trilateral German-Russian-Ukrainian seminar on high-temperature superconductivity are reported. Nuclear methods (neutron diffraction, neutron polarization, Raman scattering, ESR) applied to study rare earth cuprates are described. The reports dealing with fundamental experimental studies and theoretical investigations are presented. The source materials for preparation of high-tc superconductors and the ways of their preparation, as well as their physico-chemical properties are considered

Development of Pb-rich (Bi, Pb) sub 3 Sr sub 2 Ca sub 2 Cu sub 1 O sub x phase during reformation of lead doped 2223 superconducting phase from melt quenched glass. [BiPbSrCaCuO

Energy Technology Data Exchange (ETDEWEB)

Oezkan, N; Glowacki, B A [IRC in Superconductivity, Univ. of Cambridge (United Kingdom)

1992-05-01

The reformation process of the lead doped superconducting 2223 phase from the melt quenched glass was investigated. It was shown that during the crystallisation of the glass a new lead rich phase, Bi{sub 0.5}Pb{sub 3}Sr{sub 2}Ca{sub 2}Cu{sub 1}O{sub x}, was formed and severe copper segregation was observed. The volume fraction of the high Tc 2223 phase increased with annealing time for an annealing temperature of 840degC. A glass sample annealed at 840degC for 150 h showed two superconducting transitions Tc = 107 K and Tc = 70 K. (orig.).

Method and system for controlling chemical reactions between superconductors and metals in superconducting cables

Science.gov (United States)

Shen, Tengming

2016-11-15

A method, system, and apparatus for fabricating a high-strength Superconducting cable comprises pre-oxidizing at least one high-strength alloy wire, coating at least one Superconducting wire with a protective layer, and winding the high-strength alloy wire and the Superconducting wire to form a high-strength Superconducting cable.

Method and system for controlling chemical reactions between superconductors and metals in superconducting cables

Energy Technology Data Exchange (ETDEWEB)

Shen, Tengming

2018-01-02

A method, system, and apparatus for fabricating a high-strength Superconducting cable comprises pre-oxidizing at least one high-strength alloy wire, coating at least one Superconducting wire with a protective layer, and winding the high-strength alloy wire and the Superconducting wire to form a high-strength Superconducting cable.

Spin-rotation symmetry breaking and triplet superconducting state in doped topological insulator CuxBi2Se3

Science.gov (United States)

Zheng, Guo-Qing

Spontaneous symmetry breaking is an important concept for understanding physics ranging from the elementary particles to states of matter. For example, the superconducting state breaks global gauge symmetry, and unconventional superconductors can break additional symmetries. In particular, spin rotational symmetry is expected to be broken in spin-triplet superconductors. However, experimental evidence for such symmetry breaking has not been obtained so far in any candidate compounds. We report 77Se nuclear magnetic resonance measurements which showed that spin rotation symmetry is spontaneously broken in the hexagonal plane of the electron-doped topological insulator Cu0.3Bi2Se3 below the superconducting transition temperature Tc =3.4 K. Our results not only establish spin-triplet (odd parity) superconductivity in this compound, but also serve to lay a foundation for the research of topological superconductivity (Ref.). We will also report the doping mechanism and superconductivity in Sn1-xInxTe.

An investigation in texturing high Tc superconducting ceramics by creep sintering

International Nuclear Information System (INIS)

Regnier, P.; Deschanels, X.; Maurice, F.; Schmirgeld, L.; Aguillon, C.; Senoussi, S.; Mac Carthy, M.; Tatlock, G.J.

1991-01-01

We study in detail the possibility of high-T c superconducting ceramics texturing by high pressing them during sintering. We show texture variations as a function of the applied load, of the deformation, of the temperature, and of the sintering stage length, of the rate of variation of temperature, of the material nature in contact with ceramic and of the original powder quality. We present results obtained by optical microscopy, electronic microscopy, X-rays, and local chemical analysis

Relaxation of polarized nuclei in superconducting rhodium

DEFF Research Database (Denmark)

Knuuttila, T.A.; Tuoriniemi, J.T.; Lefmann, K.

2000-01-01

Nuclear spin lattice relaxation rates were measured in normal and superconducting (sc) rhodium with nuclear polarizations up to p = 0.55. This was sufficient to influence the sc state of Rh, whose T, and B-c, are exceptionally low. Because B-c ... is unchanged, the nuclear spin entropy was fully sustained across the sc transition. The relaxation in the sc state was slower at all temperatures without the coherence enhancement close to T-c. Nonzero nuclear polarization strongly reduced the difference between the relaxation rates in the sc and normal...

A new way for preparing superconducting materials: the electrochemical oxidation of La sub 2 CuO sub 4. Une nouvelle voie d'acces aux oxydes supraconducteurs: l'oxydation electrochimique de La sub 2 CuO sub 4

Energy Technology Data Exchange (ETDEWEB)

Wattiaux, A; Park, J C; Grenier, J C; Pouchard, M [Bordeaux-1 Univ., 33 - Talence (FR)

1990-04-01

The electrochemical oxidation in alkaline medium is described as a new way for preparing superconducting oxides at room temperature. The application of this method to La{sub 2}CuO{sub 4} gave rise to a metallic material with a superconducting behaviour below 39 K and whose physical and chemical features appear as quite promising.

PREFACE: ISEC 2005: The 10th International Superconductive Electronics Conference

Science.gov (United States)

Rogalla, Horst

2006-05-01

The 10th International Superconductive Electronics Conference took place in Noordwijkerhout in the Netherlands, 5-9 September 2005, not far from the birthplace of superconductivity in Leiden nearly 100 years ago. There have been many reasons to celebrate the 10th ISEC: not only was it the 20th anniversary, but also the achievements since the first conference in Tokyo in 1987 are tremendous. We have seen whole new groups of superconductive materials come into play, such as oxide superconductors with maximum Tc in excess of 100 K, carbon nanotubes, as well as the realization of new digital concepts from saturation logic to the ultra-fast RSFQ-logic. We have learned that superconductors not only show s-wave symmetries in the spatial arrangement of the order parameter, but also that d-wave dependence in oxide superconductors is now well accepted and can even be successfully applied to digital circuits. We are now used to operating SQUIDs in liquid nitrogen; fT sensitivity of SQUID magnetometers is not surprising anymore and can even be reached with oxide-superconductor based SQUIDs. Even frequency discriminating wide-band single photon detection with superconductive devices, and Josephson voltage standards with tens of thousands of junctions, nowadays belong to the daily life of advanced laboratories. ISEC has played a very important role in this development. The first conferences were held in 1987 and 1989 in Tokyo, and subsequently took place in Glasgow (UK), Boulder (USA), Nagoya (Japan), Berlin (Germany), Berkeley (USA), Osaka (Japan), Sydney (Australia), and in 2005 for the first time in the Netherlands. These conferences have provided platforms for the presentation of the research and development results of this community and for the vivid discussion of achievements and strategies for the further development of superconductive electronics. The 10th conference has played a very important role in this context. The results in laboratories show great potential and

Design study of SMES system using high temperature superconductors

International Nuclear Information System (INIS)

Yoshihara, T.; Masuda, M.; Shintomi, T.; Hasegawa, J.

1988-01-01

Various studies of high Tc superconductors are being energetically pursued all over the world, since IBM Zurich Research Laboratory reported on the superconducting oxide. A new design using a high Tc superconductor is under study for 5000 MWh, on the assumption that it is available like conventional superconductors. Problems related to the Tc SMES system, mainly thermal insulation, refrigeration system, stability of superconductors, etc., are considered. Some design examples of high Tc SMES system are proposed

Superconductivity in the background of disordered flux state of spins

International Nuclear Information System (INIS)

Feng Shiping; Guo Rui; Han Fei

1992-01-01

The phase diagram of the copper oxide materials with the antiferromagnetic and the superconducting properties as a function of doping δ is obtained in the framework of the t-J model by using the Schwinger boson-slave fermion theory. The results show that the spiral order of spins competes and coexists with superconductivity for small doping δ. For large doping δ, superconductivity appears, which may be caused by the occurrence of a disordered flux state of spins. The phase diagram suggests a strong relationship between antiferromagnetism and superconductivity. (orig.)

Superconducting Gap Symmetry of LaFeP(O,F Observed by Impurity Doping Effect

Directory of Open Access Journals (Sweden)

Shigeki Miyasaka

2016-08-01

Full Text Available We have investigated Mn, Co and Ni substitution effects on polycrystalline samples of LaFePO0.95F0.05 by resistivity and magnetoresistance measurements. In LaFe1-xMxPO0.95F0.05 (M = Mn, Co and Ni, the superconducting transition temperature (Tc monotonously decreases with increasing the impurity doping level of x. There is a clear difference of Tc suppression rates among Mn, Co and Ni doping cases, and the decreasing rate of Tc by Mn doping as a magnetic impurity is larger than those by the nonmagnetic doping impurities (Co/Ni. This result indicates that in LaFePO0.95F0.05, Tc is rapidly suppressed by the pair-breaking effect of magnetic impurities, and the pairing symmetry is a full-gapped s-wave. In the nonmagnetic impurity-doped systems, the residual resistivity in the normal state has nearly the same value when Tc becomes zero. The residual resistivity value is almost consistent with the universal value of sheet resistance for two-dimensional superconductors, suggesting that Tc is suppressed by electron localization in Co/Ni-doped LaFePO0.95F0.05.

Superconducting magnetic energy storage and superconducting self-supplied electromagnetic launcher

Science.gov (United States)

Ciceron, Jérémie; Badel, Arnaud; Tixador, Pascal

2017-10-01

Superconductors can be used to build energy storage systems called Superconducting Magnetic Energy Storage (SMES), which are promising as inductive pulse power source and suitable for powering electromagnetic launchers. The second generation of high critical temperature superconductors is called coated conductors or REBCO (Rare Earth Barium Copper Oxide) tapes. Their current carrying capability in high magnetic field and their thermal stability are expanding the SMES application field. The BOSSE (Bobine Supraconductrice pour le Stockage d'Energie) project aims to develop and to master the use of these superconducting tapes through two prototypes. The first one is a SMES with high energy density. Thanks to the performances of REBCO tapes, the volume energy and specific energy of existing SMES systems can be surpassed. A study has been undertaken to make the best use of the REBCO tapes and to determine the most adapted topology in order to reach our objective, which is to beat the world record of mass energy density for a superconducting coil. This objective is conflicting with the classical strategies of superconducting coil protection. A different protection approach is proposed. The second prototype of the BOSSE project is a small-scale demonstrator of a Superconducting Self-Supplied Electromagnetic Launcher (S3EL), in which a SMES is integrated around the launcher which benefits from the generated magnetic field to increase the thrust applied to the projectile. The S3EL principle and its design are presented. Contribution to the topical issue "Electrical Engineering Symposium (SGE 2016)", edited by Adel Razek

Experimental study of {sup 99m}Tc-aluminum oxide use for sentinel lymph nodes detection

Energy Technology Data Exchange (ETDEWEB)

Chernov, V. I., E-mail: Chernov@oncology.tomsk.ru; Sinilkin, I. G.; Zelchan, R. V.; Medvedeva, A. A. [Tomsk Cancer Research Institute, Kooperativny Street 5, Tomsk, 634050 (Russian Federation); Tomsk Polytechnic University, Lenin Avenue 30, Tomsk, 634050 (Russian Federation); Lyapunov, A. Yu., E-mail: Lyapunov1720.90@mail.ru [Tomsk Cancer Research Institute, Kooperativny Street 5, Tomsk, 634050 (Russian Federation); Bragina, O. D.; Varlamova, N. V.; Skuridin, V. S. [Tomsk Polytechnic University, Lenin Avenue 30, Tomsk, 634050 (Russian Federation)

2016-08-02

The purpose of the study was a comparative research in the possibility of using the radiopharmaceuticals {sup 99m}Tc-Al{sub 2}O{sub 3} and {sup 99m}Tc-Nanocis for visualizing sentinel lymph nodes. The measurement of the sizes of {sup 99m}Tc-Al{sub 2}O{sub 3} and {sup 99m}Tc-Nanocis colloidal particles was performed in seven series of radiopharmaceuticals. The pharmacokinetics of {sup 99m}Tc-Al{sub 2}O{sub 3} and {sup 99m}Tc-Nanocis was researched on 50 white male rats. The possibility of the use of {sup 99m}Tc-Al{sub 2}O{sub 3} and {sup 99m}Tc-Nanocis for lymphoscintigraphy was studied in the experiments on 12 white male rats. The average dynamic diameter of the sol particle was 52–77 nm for {sup 99m}Tc-Al{sub 2}O{sub 3} and 16.7–24.5 nm for {sup 99m}Tc-Nanocis. Radiopharmaceuticals accumulated in the inguinal lymph node in 1 hour after administration; the average uptake of {sup 99}mTc-Al{sub 2}O{sub 3} was 8.6% in it, and the accumulation of {sup 99m}Tc-Nanocis was significantly lower—1.8% (p < 0.05). In all study points the average uptake of {sup 99m}Tc-Al{sub 2}O{sub 3} in the lymph node was significantly higher than {sup 99m}Tc-Nanocis accumulation. The results of dynamic scintigraphic studies in rats showed that {sup 99m}Tc-Al{sub 2}O{sub 3} and {sup 99m}Tc-Nanocis actively accumulated into the lymphatic system. By using {sup 99m}Tc-Al{sub 2}O{sub 3} inguinal lymph node was determined in 5 minutes after injection and clearly visualized in all the animals in the 15th minute, when the accumulation became more than 1% of the administered dose. Further observation indicated that the {sup 99m}Tc-Al{sub 2}O{sub 3} accumulation reached a plateau in a lymph node (average 10.5%) during 2-hour study and then its accumulation remained practically at the same level, slightly increasing to 12% in 24 hours. In case of {sup 99m}Tc-Nanocis inguinal lymph node was visualized in all animals for 15 min when it was accumulated on the average 1.03% of the administered dose

Olson sees how they conduct (High Tc superconductors)

International Nuclear Information System (INIS)

Olson, C.

1989-01-01

Thanks to Cliff Olson's synchrotron radiation measurements of the surface of several of the new high-temperature superconducting materials, these ceramic-like crystals can now be classified as metals. This means their electronic band structure meets the criteria for a metal or conductor, rather than those of an insulator, or of a semiconductor. Working with graduate assistant Liu, Olson has now measured the energy gap in crystals of a bismuth-strontium-calcium-copper oxide with a 100K or 300K transition temperature. They determined that the superconductivity gap is isotropic, or independent of direction within the layer. This is significant, because the high temperature materials are all anisotropic, layered in flat sheets, a fact that had led to speculations about a very different kind of superconducting coupling in these materials. The superconducting mechanism now turns out to be the same as that in classical superconductors

High Tc screen-printed YBa2Cu3O(7-x) films - Effect of the substrate material

Science.gov (United States)

Bansal, Narottam P.; Simons, Rainee N.; Farrell, D. E.

1988-08-01

Thick films of YBa2Cu3O(7-x) have been deposited on highly polished alumina, magnesia spinel, nickel aluminum titanate (Ni-Al-Ti), and barium tetratitanate (Ba-Ti) substrates by the screen printing technique. Properties of the films were found to be highly sensitive to the choice of the substrate material. The film on Ba-Ti turned green after firing, due to a reaction with the substrate and were insulating. A film on Ni-Al-Ti had a Tc (onset) of about 95 K and lost 90 percent of its resistance by about 75 K. However, even at 4 K it was not fully superconducting, possibly due to a reaction between the film and the substrate and interdiffusion of the reaction products. The film on alumina had Tc (onset) of about 96 K, Tc (zero) of about 66 K, and Delta Tc of about 10 K. The best film was obtained on spinel and had Tc (onset) of about 94 K, zero resistance at 81 K, and a transition width of about 7 K.

Nanostructured metal oxides: promise opportunity and challenge to develop clinically useful 99Mo/99mTc generators using (n, gamma)99Mo

International Nuclear Information System (INIS)

Dash, Ashutosh

2014-01-01

The role of 99m Tc diagnostic nuclear medicine needs hardly to be reiterated. Today, it is the most widely used radionuclide for single photon emission computed tomography (SPECT) imaging procedures. The current strategy of availing 99m Tc is ensured from column chromatographic 99 Mo/ 99m Tc generators using a bed of acidic alumina. While the column chromatographic 99 Mo/ 99m Tc generator constitute a successful exemplar of availing 99m Tc, the limited capacity of alumina (2-20 mg Mo per g of alumina) for taking up molybdate ions necessitates the use of 99 Mo of the highest specific activity available, as can be found in fission produced 99 Mo (F 99 Mo). In order to reduce dependence of F 99 Mo, the scope of using low specific activity (n,γ) 99 Mo along with high capacity adsorbent is an interesting prospect. In this context, the scope of using nanomaterials as a viable adsorbent seemed attractive by virtue of their huge surface to volume ratios, altered physical properties, tailored surface chemistry, favorable adsorption characteristics, and enhanced surface reactivity resulting from the nanoscale dimensions. This emerging class of adsorbent represents an innovative paradigm and is expected to play an important role in the development of 99 Mo/ 99m Tc generators adaptable to the existing and foreseeable demands. This talk outlines a critical assessment on the role of nanostructured metal oxides, recent developments, the contemporary status, and key challenges and apertures to the near future. (author)

Superconductivity in doped semiconductors

Energy Technology Data Exchange (ETDEWEB)

Bustarret, E., E-mail: Etienne.bustarret@neel.cnrs.fr

2015-07-15

A historical survey of the main normal and superconducting state properties of several semiconductors doped into superconductivity is proposed. This class of materials includes selenides, tellurides, oxides and column-IV semiconductors. Most of the experimental data point to a weak coupling pairing mechanism, probably phonon-mediated in the case of diamond, but probably not in the case of strontium titanate, these being the most intensively studied materials over the last decade. Despite promising theoretical predictions based on a conventional mechanism, the occurrence of critical temperatures significantly higher than 10 K has not been yet verified. However, the class provides an enticing playground for testing theories and devices alike.

Ab-initio calculations of superconducting properties of YBa2Cu3O7

International Nuclear Information System (INIS)

Zhao, G.L.; Bagayoko, D.

1999-01-01

The authors present ab-initio calculations for the electronic structure and superconducting properties of YBa 2 Cu 3 O 7 (YBCO). The electronic structure was calculated using a self-consistent ab-initio LCAO method. They solved the anisotropic Eliashberg gap equation numerically. The strong coupling of the high energy optical phonons around 60--73 meV, with the electrons at the Fermi surface, leads to a high Tc in YBCO. The calculated Tc is about 89 K for μ* = 0.1. The good agreement of the calculated results with experimental measurements and the ab-initio nature of the calculations support the scenario of an anisotropic s-wave superconductor for YBCO

Comparison of phase boundaries between kagomé and honeycomb superconducting wire networks

Science.gov (United States)

Xiao, Yi; Huse, David A.; Chaikin, Paul M.; Higgins, Mark J.; Bhattacharya, Shobo; Spencer, David

2002-06-01

We measure resistively the mean-field superconducting-normal phase boundaries of both kagomé and honeycomb wire networks immersed in a transverse magnetic field. In addition to their agreement with theory about the overall shapes of phase diagrams, they show striking one-to-one correspondence between the cusps in the honeycomb phase boundary and those in the kagomé curve. This correspondence is due to their geometric arrangements and agrees with Lin and Nori's recent calculation. We also find that for the frustrated honeycomb network at f=1/2, the current patterns in the superconducting phase differ between the low-temperature London regime and the higher-temperature Ginzburg-Landau regime near Tc.

MgB2 superconducting wires basics and applications

CERN Document Server

2016-01-01

The compendium gives a complete overview of the properties of MgB2 (Magnesium Diboride), a superconducting compound with a transition temperature of Tc = 39K, from the fundamental properties to the fabrication of multifilamentary wires and to the presentation of various applications. Written by eminent researchers in the field, this indispensable volume not only discusses superconducting properties of MgB2 compounds, but also describes known preparation methods of thin films and of bulk samples obtained under high pressure methods. A unique selling point of the book is the detailed coverage of various applications based on MgB2, starting with MRI magnets and high current cables, cooled by Helium (He) vapor. High current cables cooled by liquid hydrogen are also highlighted as an interesting alternative due to the shrinking He reserves on earth. Other pertinent subjects comprise permanent magnets, ultrafine wires for space applications and wind generator projects.

Maskless X-Ray Writing of Electrical Devices on a Superconducting Oxide with Nanometer Resolution and Online Process Monitoring.

Science.gov (United States)

Mino, Lorenzo; Bonino, Valentina; Agostino, Angelo; Prestipino, Carmelo; Borfecchia, Elisa; Lamberti, Carlo; Operti, Lorenza; Fretto, Matteo; De Leo, Natascia; Truccato, Marco

2017-08-22

X-ray nanofabrication has so far been usually limited to mask methods involving photoresist impression and subsequent etching. Herein we show that an innovative maskless X-ray nanopatterning approach allows writing electrical devices with nanometer feature size. In particular we fabricated a Josephson device on a Bi 2 Sr 2 CaCu 2 O 8+δ (Bi-2212) superconducting oxide micro-crystal by drawing two single lines of only 50 nm in width using a 17.4 keV synchrotron nano-beam. A precise control of the fabrication process was achieved by monitoring in situ the variations of the device electrical resistance during X-ray irradiation, thus finely tuning the irradiation time to drive the material into a non-superconducting state only in the irradiated regions, without significantly perturbing the crystal structure. Time-dependent finite element model simulations show that a possible microscopic origin of this effect can be related to the instantaneous temperature increase induced by the intense synchrotron picosecond X-ray pulses. These results prove that a conceptually new patterning method for oxide electrical devices, based on the local change of electrical properties, is actually possible with potential advantages in terms of heat dissipation, chemical contamination, miniaturization and high aspect ratio of the devices.

High temperature interface superconductivity

International Nuclear Information System (INIS)

Gozar, A.; Bozovic, I.

2016-01-01

Highlight: • This review article covers the topic of high temperature interface superconductivity. • New materials and techniques used for achieving interface superconductivity are discussed. • We emphasize the role played by the differences in structure and electronic properties at the interface with respect to the bulk of the constituents. - Abstract: High-T_c superconductivity at interfaces has a history of more than a couple of decades. In this review we focus our attention on copper-oxide based heterostructures and multi-layers. We first discuss the technique, atomic layer-by-layer molecular beam epitaxy (ALL-MBE) engineering, that enabled High-T_c Interface Superconductivity (HT-IS), and the challenges associated with the realization of high quality interfaces. Then we turn our attention to the experiments which shed light on the structure and properties of interfacial layers, allowing comparison to those of single-phase films and bulk crystals. Both ‘passive’ hetero-structures as well as surface-induced effects by external gating are discussed. We conclude by comparing HT-IS in cuprates and in other classes of materials, especially Fe-based superconductors, and by examining the grand challenges currently laying ahead for the field.

Effect of superconducting transition on microcreep of high-TC ceramics

International Nuclear Information System (INIS)

Soldatov, V.P.; Natsik, V.D.; Chajkovskaya, N.M.

1991-01-01

Influence of N-S and S-N transition on microplastic deformation kinetics of YBa 2 Cu 3 O 7-δ ceramic samples by there deformation in liquid nitrogen under microscreep conditions is studied. Superconductivity disruption in the sample was achieved by critical value currents. It is shown, that N-S transition increases creep rate,whereas S-N transition slows it down. Microplastic deformation rate by sample state change may very by two-eight times. Influence of heat expansion on creep kinetics as probable associated effect is analyzed. Assumption is expressed, that stimulated transition effect on microplastic deformation of ceramic samples is related to change of their electron state in the area of Josephson contacts between grains

Current redistribution effects on superconducting d.c, and microwave measurements

International Nuclear Information System (INIS)

Barra, M; Cassinese, A; Vaglio, R

2006-01-01

In the last two decades, non conventional behavior of the d.c. transport properties of superconductors, with the appearance of anomalous peaks at the transition, have been investigated and interpreted in different ways. In several cases it was recognized that the behavior can be due to current redistribution effects related to the non-homogeneous nature of the measured superconducting sample. In this paper we will briefly review and discuss these effects and, referring to simple concentrated constant equivalent circuits, we will show that sample non-homogeneity can produce the observed features. Then, in the same framework, by performing specific simulations on planar resonators, we will show that anomalous peaks in temperature dependence of the resonant frequency and of the extracted surface reactance can occur at the transition temperature of minority, lower Tc, superconducting phases

The Rashba spin-orbit coupling for superconductivity in oxide interfaces

Energy Technology Data Exchange (ETDEWEB)

Beyl, Stefan; Orth, Peter P.; Schmalian, Joerg [Institut fuer Theorie der Kondensierten Materie, Karlsruher Institut fuer Technologie, Karlsruhe (Germany)

2014-07-01

We investigate the role of the Rashba spin-orbit coupling on the superconducting order parameter and the phase stiffness at the interface of LaAlO{sub 3} and SrTiO{sub 3}. In particular, we analyze the gate controlled crossover between BCS superconductivity and Bose-Einstein condensation of Cooper pairs, amplified by the Rashba coupling and the possibility of a phase fluctuation induced quantum critical point.

Effect of a pseudogap on Tc and on the superconducting order parameter

International Nuclear Information System (INIS)

Rodriguez Nunez, J.J.; Reimer Romero, J.J.; Valera, M.; Schmidt, A.A.

2007-09-01

We further develop the pseudogap model proposed by J.L. Tallon and J.W. Loram, Physica C 349, 53-68 (2001). For the pseudogap order parameter we choose a particular form which reproduces the main features of the high temperature superconductor (HTSC) phase diagram which depends on carrier number, n. For fitting the key features of the cuprate oxides we have sensible parameters at our disposal, namely, α, which fixes the density where the pseudogap order parameter is maximum, α' which allows us to display the T c vs n curve and E go which gives us the value of the pseudogap. We have reproduced in a qualitative fashion the main details of the experimental data given in the work of Suryadijaya, T. Sasaqawa, and H. Takagi, Physica C 426-431, 402-406 (2005). Our main results are the following: To have decreased the value of T c with respect to the 'free' case, namely, E go = 0, namely, when the pseudogap order parameter is not present. To have obtained the maximum of T c by choosing α' ≠ 0. To have chosen the minimum value of T c inside the pseudogap region, namely, in the region where the pseudogap parameter is a maximum. To have bounded the region of the superconducting dome by choosing the value of E g. In short, we have proposed a phenomenological form for the pseudogap energy, which depends on carrier number and which reproduces in a qualitative way the results of Suryadijaya, T. Sasaqawa and H. Takagi, Physica C 426-431, 402-406 (2005). Consequently, we conclude that the pseudogap is necessary for HTSC. (author)

Influence of various parameters on the elaboration of superconducting oxides. Influence de divers parametres sur la synthese d'oxydes supraconducteurs

Energy Technology Data Exchange (ETDEWEB)

Remy, F; Monnereau, O; Vacquier, G; Sorbier, J P; Fournel, A [Aix-Marseille-1 Univ., 13 - Marseille (FR); Mokrani, R [Aix-Marseille-3 Univ., 13 - Marseille (FR)

1989-01-01

Several oxides able to give rise to a high T{sub c} superconductivity have been studied. Samples were prepared in both series: La(Ba{sub 2-x}La{sub x}) Cu{sub 3}O{sub 7+y} and YBa{sub 2} (Cu{sub 3-x}Ag{sub x})O{sub 7-y}. The evolution of the resistance versus the composition has been studied on sintered samples. The results assess the importance of the experimental conditions of the synthesis. In the system La(Ba{sub 2-x}La{sub x})Cu{sub 3}O{sub 7+y} our results complete the work of Segre et al. and precise composition at which the superconductivity transition disappear for the profit of the semiconductive behaviour. The samples YBa{sub 2}(Cu{sub 3-x}Ag{sub x})O{sub 7-y} has for x = 0 electrical properties very dependent of the thermal treatment. Some characteristic data are shown. The partial substitution of Cu by Ag for x {ge} 1 enables to keep the superconducting behaviour.

Superconducting magnesium diboride coatings for radio frequency cavities fabricated by hybrid physical-chemical vapor deposition

Science.gov (United States)

Wolak, M. A.; Tan, T.; Krick, A.; Johnson, E.; Hambe, M.; Chen, Ke; Xi, X. X.

2014-01-01

We have investigated the coating of an inner surface of superconducting radio frequency cavities with a magnesium diboride thin film by hybrid physical-chemical vapor deposition (HPCVD). To simulate a 6 GHz rf cavity, a straight stainless steel tube of 1.5-inch inner diameter and a dummy stainless steel cavity were employed, on which small sapphire and metal substrates were mounted at different locations. The MgB2 films on these substrates showed uniformly good superconducting properties including Tc of 37-40 K, residual resistivity ratio of up to 14, and root-mean-square roughness Rq of 20-30 nm. This work demonstrates the feasibility of coating the interior of cylindrical and curved objects with MgB2 by the HPCVD technique, an important step towards superconducting rf cavities with MgB2 coating.

Spatial distribution of superconducting and charge-density-wave order parameters in cuprates and its influence on the quasiparticle tunnel current (Review Article)

International Nuclear Information System (INIS)

Cabovich, Alexander M.; Voitenko, Alexander I.

2016-01-01

The state of the art concerning tunnel measurements of energy gaps in cuprate oxides has been analyzed. A detailed review of the relevant literature is made, and original results calculated for the quasiparticle tunnel current J(V) between a metallic tip and a disordered d-wave superconductor partially gapped by charge density waves (CDWs) are reported, because it is this model of high-temperature superconductors that becomes popular owing to recent experiments in which CDWs were observed directly. The current was calculated suggesting the scatter of both the superconducting and CDW order parameters due to the samples intrinsic inhomogeneity. It was shown that peculiarities in the current-voltage characteristics inherent to the case of homogeneous super-conducting material are severely smeared, and the CDW-related features transform into experimentally observed peak-dip-hump structures. Theoretical results were used to fit data measured for YBa_2Cu_3O_7_-_d_e_l_t_a and Bi_2Sr_2CaCu_2O_8_+_d_e_l_t_a. The fitting demonstrated a good qualitative agreement between the experiment and model calculations. The analysis of the energy gaps in high-Tc superconductors is important both per se and as a tool to uncover the nature of superconductivity in cuprates not elucidated so far despite of much theoretical effort and experimental progress.

Similarity in the superconducting properties of chalcogenides, cuprate oxides and fullerides

International Nuclear Information System (INIS)

Tsendin, K.D.; Popov, B.P.; Denisov, D.V.

2004-01-01

The idea of Anderson pairs has been put forward for explanation of many extraordinary properties of chalcogenides glassy semiconductors. Recent decades made obvious that these pairs localized on the centers with negative effective correlation energy (negative-U centers) really exist in chalcogenides. If the concentration of negative-U centers is enough to create the pair band states, this can lead to superconductivity because Anderson pairs are Bose particles. In the present paper we show that several puzzling superconductivity properties of chalcogenides, high-temperature cuprate superconductors and fullerides are similar for these three groups of materials and can be naturally explained in the frame of negative-U centers model of superconductivity

Non-equilibrium spectroscopy of high-Tc superconductors

International Nuclear Information System (INIS)

Krasnov, V M

2009-01-01

In superconductors, recombination of two non-equilibrium quasiparticles into a Cooper pair results in emission of excitation that mediates superconductivity. This is the basis of the proposed new type of 'non-equilibrium' spectroscopy of high T c superconductors, which may open a possibility for direct and unambiguous determination of the coupling mechanism of high T c superconductivity. In case of low T c superconductors, the feasibility of such the non-equilibrium spectroscopy was demonstrated in classical phonon generation-detection experiments almost four decades ago. Recently it was demonstrated that a similar technique can be used for high T c superconductors, using natural intrinsic Josephson junctions both for injection of non-equilibrium quasiparticles and for detection of the non-equilibrium radiation. Here I analyze theoretically non-equilibrium phenomena in intrinsic Josephson junctions. It is shown that extreme non-equilibrium state can be achieved at bias equal to integer number of the gap voltage, which can lead to laser-like emission from the stack. I argue that identification of the boson type, constituting this non-equilibrium radiation would unambiguously reveal the coupling mechanism of high Tc superconductors.

Anisotropic vortex pinning in the β-pyrochlore oxide superconductor KOs 2O 6

Science.gov (United States)

Ishii, Y.; Yamaura, J.; Okamoto, Y.; Maeda, A.; Hiroi, Z.

2011-11-01

Vortex pinning in the β-pyrochlore oxide superconductor KOs2O6 with Tc = 9.6 K is investigated by measuring magnetic torque. A large anisotropy of magnetic torque is observed in the superconducting state below Tp = 7.6 K, where a first-order structural transition takes place, in spite of the inherent isotropic nature of the structural and electronic properties. Magnetic torque is enhanced at external magnetic fields parallel to the [1 1 1] and [0 0 1] directions. Moreover, a pronounced peak effect is also observed in the magnetic field dependence of the torque in these two directions. We consider that the observed anisotropy is related to a microstructure associated with the structural transition.

Effect of plasma on the superconductive property of YBCO system

International Nuclear Information System (INIS)

Chaudhary, K.A.; Anwar, M.I.; Zakaullah, M.; Alamgir, K.; Murtaza, G.; Haq, A.U.

1999-01-01

Oxygen deficient Y/sub 1/Ba/sub 2/Cu 3/O/sub 7-x/ samples are exposed to the rarefied are discharge. The air plasma has gas and electron temperatures as 170 deg. C and 2.1 eV, respectively. As a result of plasma treatment the semiconducting tetragonal phase transformed into superconducting orthorhombic phase with Tc= 84K the phase relating properties have been investigated by monochromated X-ray diffraction and low temperature resistivity measurements. (author)

Electronic properties of high Tc superconductors. Propiedades electronicas de los superconductores de alta temperatura critica

Energy Technology Data Exchange (ETDEWEB)

Rojo, A G

1989-01-01

Using analytical and numerical methods, the electronic properties of the copper-oxygen plane in the normal phase of high Tc superconductors are described. Using the slave-boson technique in the saddle point, a theory of the metal insulator transition which generalizes the notions of a Mott insulator to the case of more than a single band for those planes is presented. A phase-diagram is obtained in the parameter space and effective masses, optical gaps and metallization are calculated as a function of the number of carriers. Based on the experimental evidence, the theory permits classification of superconducting compounds as charge transfer insulators in the stoichiometric case. The insulator state is characterized by a non-zero optical gap and a divergent effective mass which corresponds to the breakage of a Fermi-liquid scheme. The results obtained are applicable to metal-transition-oxides whose behaviour has been traditionally controversial and it is concluded that it is necessary to broaden the meaning of a Mott insulator to the case of more than a single band to better understand them. Based on the ideas of group renormalization in a real space, a lattice approximation is presented, which allows: a) To complement the treatment of slave-bosons in phase diagrams and optical gaps; b) Identification of an attraction mechanism between carriers originating from purely repulsive interactions. Numerical calculations in small clusters show the existence of a pairing mechanism showing a superconducting instability from a charge transfer insulator. (Author).

Superconducting Properties of Lead-Bismuth Films Controlled by Ferromagnetic Nanowire Arrays