SAFETY EVALUATION OF OXALIC ACID WASTE RETRIEVAL IN SINGLE SHELL TANK (SST) 241-C-106

International Nuclear Information System (INIS)

SHULTZ, M.V.

2003-01-01

This report documents the safety evaluation of the process of retrieving sludge waste from single-shell tank 241-C-106 using oxalic acid. The results of the HAZOP, safety evaluation, and control allocation/decision are part of the report. This safety evaluation considers the use of oxalic acid to recover residual waste in single-shell tank (SST) 241-C-106. This is an activity not addressed in the current tank farm safety basis. This evaluation has five specific purposes: (1) Identifying the key configuration and operating assumptions needed to evaluate oxalic acid dissolution in SST 241-C-106. (2) Documenting the hazardous conditions identified during the oxalic acid dissolution hazard and operability study (HAZOP). (3) Documenting the comparison of the HAZOP results to the hazardous conditions and associated analyzed accident currently included in the safety basis, as documented in HNF-SD-WM-TI-764, Hazard Analysis Database Report. (4) Documenting the evaluation of the oxalic acid dissolution activity with respect to: (A) Accident analyses described in HNF-SD-WM-SAR-067, Tank Farms Final Safety Analysis Report (FSAR), and (B) Controls specified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements (TSR). (5) Documenting the process and results of control decisions as well as the applicability of preventive and/or mitigative controls to each oxalic acid addition hazardous condition. This safety evaluation is not intended to be a request to authorize the activity. Authorization issues are addressed by the unreviewed safety question (USQ) evaluation process. This report constitutes an accident analysis

Safety equipment list for 241-C-106 waste retrieval, Project W-320: Revision 1

International Nuclear Information System (INIS)

Conner, J.C.

1994-01-01

The goals of the C-106 sluicing operation are: (1) to stabilize the tank by reducing the heat load in the tank to less than 42 MJ/hr (40,000 Btu/hour), and (2) to initiate demonstration of single-shell tank (SST) retrieval technology. The purpose of this supporting document (SD) is as follows: (1) to provide safety classifications for items (systems, structures, equipment, components, or parts) for the waste retrieval sluicing system (WRSS), and (2) to document and methodology used to develop safety classifications. Appropriate references are made with regard to use of existing systems, structures, equipments, components, and parts for C-106 single-shell transfer tank located in the C Tank Farm, and 241-AY-102 (AY-102) double shell receiver tanks (DST) located in the Aging Waste Facility (AWF). The Waste Retrieval Sluicing System consists of two transfer lines that would connect the two tanks, one to carry the sluiced waste slurry to AY-102, and the other to return the supernatant liquid to C-106. The supernatant, or alternate fluid, will be used to mobilize waste in C-106 for the sluicing process. The equipment necessary for the WRSS include pumps in each tank, sluicers to direct the supernatant stream in C-106, a slurry distributor in AY-102, HVAC for C-106, instrumentation and control devices, and other existing components as required

Permitting plan for project W-320 tank 241-C-106 waste retrieval sluicing system (WRSS)

International Nuclear Information System (INIS)

Symons, G.A.

1997-01-01

This document describes the permitting plan for Project W-320, Tank 241-C-106 Waste Retrieval Sluicing System (WRSS). A comprehensive review of environmental regulations have indicated that several environmental reviews [e.g. National Environmental Policy Act (NEPA), State Environmental Policy Act (SEPA)], permits, and approvals are required prior to construction or operation of the facility. The environmental reviews, permits and approvals, as well the regulatory authority, potentially applicable to the Tank 241-C-106 WRSS include the following: for NEPA - U.S. Department of Energy-Headquarters: Action Description Memorandum, Environmental Assessment, Categorical Exclusion, and Environmental Impact Statement; and for SEPA - State of Washington Department of Ecology (Ecology) Determination of Nonsignificance, Mitigated Determination of Nonsignificance, Determination of Significance, and SEPA Environmental Checklist

Consequences of a radioactive surface pool resulting from waste transfer operations between tanks 214-C-106 and 241-AY-102

International Nuclear Information System (INIS)

Van Vleet, R.J.

1997-01-01

This document contains supporting calculations for quantifying the dose consequences from a pool formed from an underground leak or a-leak from an above grade structure for the Waste Retrieval Sluicing System (Project W-320), i.e., sluicing the contents of Tank 241-C-106 (high heat, SST) into Tank 241-AY-102 (aging waste, DST)

Consequences of a radioactive surface pool resulting from waste transfer operations between tanks 214-C-106 and 241-AY-102

Energy Technology Data Exchange (ETDEWEB)

Van Vleet, R.J.

1997-08-05

This document contains supporting calculations for quantifying the dose consequences from a pool formed from an underground leak or a-leak from an above grade structure for the Waste Retrieval Sluicing System (Project W-320), i.e., sluicing the contents of Tank 241-C-106 (high heat, SST) into Tank 241-AY-102 (aging waste, DST).

Tank 241-C-106 sampling data requirements developed through the data quality objectives (DQO) process

International Nuclear Information System (INIS)

Wang, O.S.; Bell, K.E.; Anderson, C.M.; Peffers, M.S.; Pulsipher, B.A.; Scott, J.L.

1994-01-01

The rate of heat generation for tank 241-C-106 at the Hanford Site is estimated at more then 100,000 Btu/h. The heat is generated primarily from the radioactive decay of 90 Sr waste that was inadvertently transferred into the tank in the late 1960s. If proper tank cooling is not maintained for this tank, heat-induced structural damage to the tank's concrete shell could result in the release of nuclear waste to the environment. Because of high-heat concerns in January 1991, tank 241-C-106 was designated as a Watch List tank and deemed as a Priority 1 safety issue. Waste Tank Safety Program (WTSP) is responsible for the resolution of this safety issue. Although forced cooling is effective for short term, the long-term resolution for tank cooling is waste retrieval. Single-shell Tank Retrieval Project (Retrieval) is responsible for the safe retrieval and transfer of radioactive waste from tank 241-C-106 to a selected double-shell tank. This data quality objective (DQO) study is an effort to determine engineering and design data needs for WTSP and assist Retrieval in designing contingency action retrieval systems. The 7-step DQO process is a tool developed by the Environmental Protection Agency with a goal of identifying needs and reducing costs. This report discusses the results of two DQO efforts for WTSP and Retrieval. The key data needs to support WTSP are thermal conductivity, permeability, and heat load profile. For the Retrieval support, there are nine and three data needs identified, respectively, for retrieval engineering system design and HVAC system design. The updated schedule to drill two core samples using rotary mode is set for March 1994. The analysis of the sample is expected to be completed by September 1994

Engineering Task Plan for Tank 241-C-106 contingency chiller definitive design

International Nuclear Information System (INIS)

Rensink, G.E.; Kriskovich, J.R.

1995-01-01

This document identifies the scope, cost, schedule and responsible organizations for completing a design of a contingency ventilation inlet air cooling system for Tank 241-C-106. The air cooling system, described in Rensink (1995), consists of a chiller, cooling coils, and supporting equipment that, when installed will be capable of assuring that the waste temperatures in Tank 241-C-106 are maintained within acceptable limits for safe storage. The effort described herein is scheduled for completion by May 31, 1995 to support Performance Based Incentive (PBI) Milestone SI-2x

Preliminary safety evaluation for 241-C-106 waste retrieval, project W-320

International Nuclear Information System (INIS)

Conner, J.C.

1994-01-01

This document presents the Preliminary Safety Evaluation for Project W-320, Tank 241-C-106 Waste Retrieval Sluicing System (WRSS). The US DOE has been mandated to develop plans for response to safety issues associated with the waste storage tanks at the Hanford Site, and to report the progress of implementing those plans to Congress. The objectives of Project W-230 are to design, fabricate, develop, test, and operate a new retrieval system capable of removing a minimum of about 75% of the high-heat waste contained in C-106. It is anticipated that sluicing operations can remove enough waste to reduce the remaining radiogenic heat load to levels low enough to resolve the high-heat safety issue as well as allow closure of the tank safety issue

Baseline estimate of the retained gas volume in Tank 241-C-106

International Nuclear Information System (INIS)

Stewart, C.W.; Chen, G.

1998-06-01

This report presents the results of a study of the retained gas volume in Hanford Tank 241-C-106 (C-106) using the barometric pressure effect method. This estimate is required to establish the baseline conditions for sluicing the waste from C-106 into AY-102, scheduled to begin in the fall of 1998. The barometric pressure effect model is described, and the data reduction and detrending techniques are detailed. Based on the response of the waste level to the larger barometric pressure swings that occurred between October 27, 1997, and March 4, 1998, the best estimate and conservative (99% confidence) retained gas volumes in C-106 are 24 scm (840 scf) and 50 scm (1,770 scf), respectively. This is equivalent to average void fractions of 0.025 and 0.053, respectively

Bench-scale crossflow filtration of Hanford tank C-106, C-107, B-110, and U-110 sludge slurries

International Nuclear Information System (INIS)

Geeting, J.G.H.; Reynolds, B.A.

1997-09-01

Pacific Northwest National Laboratory has a bench-scale crossflow filter installed in a shielded hot cell for testing radioactive feeds. During FY97 experiments were conducted on slurries from radioactive Hanford waste from tanks C-106, C-107, B-110, and U-110. Each tank was tested at three slurry concentrations (8, 1.5, and 0.05 wt% solids). A two-parameter central composite design which tested transmembrane pressure from 5 to 40 psig and axial velocity from 3 to 9 ft/s was used for all feeds. Crossflow filtration was found to remove solids effectively, as judged by filtrate clarity and radiochemical analysis. If the filtrates from these tests were immobilized in a glass matrix, the resulting transuranic and ( 90 Sr) activity would not breach low activity waste glass limits of 100nCi/g (TRU) and 20 μCi/ml ( 90 Sr). Two exceptions were the transuranic activity in filtrates from processing 1.5 and 8 wt% C-106 tank waste. Subsequent analyses indicated that the source of the TRU activity in the filtrate was most likely due to soluble activity, but obviously proved ineffective at removing the soluble plutonium species. Re-testing of the C-106 supported this hypothesis. These data suggest the need to control carbonate and pH when processing tank wastes for immobilization

Monitoring gas retention and slurry transport during the transfer of waste from Tank 241-C-106 to Tank 241-AY-102

International Nuclear Information System (INIS)

Stewart, C.W.; Erian, F.F.; Meyer, P.A.

1997-07-01

The retained gas volume can be estimated by several methods. All of these methods have significant uncertainties, but together they form a preponderance of evidence that describes the gas retention behavior of the tank. The methods are (1) an increase in nonconvective layer thickness; (2) a waste surface level rise (surface level effect [SLE] model); (3) the barometric pressure effect (BPE model); (4) direct void measurement; and (5) the consequences of the transfer process. The nonconvective layer thickness can be determined with sufficient accuracy to describe the overall waste configuration by means of temperature profiles or densitometer indications. However, the presence of a nonconvective layer does not necessarily indicate significant gas retention, and small changes in layer thickness that could quantify gas retention cannot be detected reliably with the methods available. The primary value of this measurement is in establishing the actual open-quotes fluffing factorclose quotes for thermal calculations. Surface level rise is not a useful measure of gas retention in Tank 241-C-106 (C-106) since the waste level fluctuates with regular makeup water additions. In Tank 241-AY-102 (AY-102) with the existing ventilation system it should be possible to determine the gas retention rate within 30-60% uncertainty from the surface level rise, should a significant rise be observed. The planned ventilation system upgrades in AY- 102 will greatly reduce the exhaust flow and the headspace humidity, and the evaporation rate should be significantly lower when transfers begin. This could reduce the uncertainty in gas retention rate estimates to around ± 10%

CSER 94-09: Implications of the heat anomaly in Tank 106-C to criticality safety

Energy Technology Data Exchange (ETDEWEB)

Rogers, C.A.

1994-10-01

Water is periodically added to Tank C-106 to cool its waste. In March 1994 addition of water was temporarily discontinued to determine if the tank could be adequately cooled at a lower water level. Following an addition of water, a temperature fluctuation was observed on one of the thermocouple trees. This Criticality Safety Evaluation Report (CSER) explains why the anomalous temperature measurements could not have been caused by nuclear criticality. Waste in Tank C-106 was discharged from processing facilities under controls designed to ensure that the contents of the tank would remain well subcritical under all credible conditions. The observed temperature profile does not fit the profile expected from a criticality event. In addition, there has been no indication of any significant increase in the rate of water evaporation.

Vapor space characterization of waste tank 241-C-106: Results from samples collected on February 15, 1994

International Nuclear Information System (INIS)

McVeety, B.D.; Clauss, T.W.; Young, J.S.; Ligotke, M.W.; Goheen, S.C.; Lucke, R.B.; Pool, K.H.; McCulloch, M.; Fruchter, J.S.

1995-06-01

This document presents the details of the inorganic and organic analysis that was performed on samples from the headspace of Hanford waste tank 241-C-106. The results described were obtained to support the safety and toxicological evaluations. A summary of the results for the inorganic and organic analytes is included, as well as, a detailed description of the results which appears in the text

Preliminary analysis of tank 241-C-106 dryout due to large postulated leak and vaporization

Energy Technology Data Exchange (ETDEWEB)

Piepho, M.G.

1995-03-01

At the Hanford site in SE Washington, there are 149 single-shell tanks containing radionuclide wastes in the form of liquids, sludges and salt cakes. One of the tanks, tank 241-C-106, is heated to the boiling point due to radionuclide decay (primarily Sr-90). Water is added to the tank, which is ventilated, in order to cool the tank. This analysis assumes that there is a hypothetical large leak at the bottom of Tank 241-C-106 which initiates the dryout of the tank. The time required for a tank to dryout after a leak is of interest for safety reasons. As a tank dries outs, its temperature is expected to greatly increase, which could affect the structural integrity of the concrete tank dome. Hence, it is of interest to know how fast the temperature in a leaky tank increases, so that mitigation procedures can be planned and implemented in a timely manner. The objective of the study was to determine how long it would take for tank 241-C-106 to reach 350 degrees Fahrenheit (about 177 degrees Centigrade) after a postulated large leak develops at the bottom center of the tank.

Engineering study of tank leaks related to hydraulic retrieval of sludge from tank 241-C-106

International Nuclear Information System (INIS)

Lowe, S.S.; Carlos, W.C.; Irwin, J.J.; Khaleel, R.; Kline, N.W.; Ludowise, J.D.; Marusich, R.M.; Rittman, P.D.

1993-01-01

This study evaluates hydraulic retrieval (sluicing) of the waste in single-shell tank 241-C-106 with respect to the likelihood of tank leaks, gross volumes of potential leaks, and their consequences. A description of hydraulic retrieval is developed to establish a baseline for the study. Leak models are developed based on postulated leak mechanisms to estimate the amount of waste that could potentially leak while sluicing. Transport models describe the movement of the waste constituents in the surrounding soil and groundwater after a leak occurs. Environmental impact and risk associated with tank leaks are evaluated. Transport of leaked material to the groundwater is found to be dependent on the rate of recharge of moisture in the soil for moderate-sized leaks. Providing a cover over the tank and surrounding area would eliminate the recharge. The bulk of any leaked material would remain in the vicinity of the tank for remedial action

C-106 tank process ventilation test

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

Project W-320 Acceptance Test Report for tank 241-C-106, 296-C-006 Ventilation System Acceptance Test Procedure (ATP) HNF-SD-W320-012, C-106 Tank Process Ventilation Test, was an in depth test of the 296-C-006 ventilation system and ventilation support systems required to perform the sluicing of tank C-106. Systems involved included electrical, instrumentation, chiller and HVAC. Tests began at component level, moved to loop level, up to system level and finally to an integrated systems level test. One criteria was to perform the test with the least amount of risk from a radioactive contamination potential stand point. To accomplish this a temporary configuration was designed that would simulate operation of the systems, without being connected directly to the waste tank air space. This was done by blanking off ducting to the tank and connecting temporary ducting and an inlet air filter and housing to the recirculation system. This configuration would eventually become the possible cause of exceptions. During the performance of the test, there were points where the equipment did not function per the directions listed in the ATP. These events fell into several different categories. The first and easiest problems were field configurations that did not match the design documentation. This was corrected by modifying the field configuration to meet design documentation and reperforming the applicable sections of the ATP. A second type of problem encountered was associated with equipment which did not operate correctly, at which point an exception was written against the ATP, to be resolved later. A third type of problem was with equipment that actually operated correctly but the directions in the ATP were in error. These were corrected by generating an Engineering Change Notice (ECN) against the ATP. The ATP with corrected directions was then re-performed. A fourth type of problem was where the directions in the ATP were as the equipment should operate, but the design of

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III

Energy Technology Data Exchange (ETDEWEB)

LOCKREM, L.L.

1999-08-13

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999.

C-106 tank sluicer control system

International Nuclear Information System (INIS)

Bellomy, J.R.

1997-01-01

Acceptance Test Report for the Sluicer Control System, Project W-320 This Acceptance Test Procedure (ATP) has been prepared to demonstrate that the C-Farm tank C-106 sluicer functions as required by the design criteria

Uncertainties in the measured quantities of water leaving waste Tank 241-C-106 via the ventilation system

Energy Technology Data Exchange (ETDEWEB)

Minteer, D.J.

1995-01-23

The purpose of this analysis is to estimate the uncertainty in the measured quantity of water which typically leaves Tank 241-C-106 via the ventilation system each month. Such measurements are essential for heat removal estimation and tank liquid level verification purposes. The uncertainty associated with the current, infrequent, manual method of measurement (involves various psychrometric and pressure measurements) is suspected to be unreasonably high. Thus, the possible reduction of this uncertainty using a continuous, automated method of measurement will also be estimated. There are three major conclusions as a result of this analysis: (1) the uncertainties associated with the current (infrequent, manual) method of measuring the water which typically leaves Tank 241-C-106 per month via the ventilation system are indeed quite high (80% to 120%); (2) given the current psychrometric and pressure measurement methods and any tank which loses considerable moisture through active ventilation, such as Tank 241-C-106, significant quantities of liquid can actually leak from the tank before a leak can be positively identified via liquid level measurement; (3) using improved (continuous, automated) methods of taking the psychrometric and pressure measurements, the uncertainty in the measured quantity of water leaving Tank 241-C-106 via the ventilation system can be reduced by approximately an order of magnitude.

Uncertainties in the measured quantities of water leaving waste Tank 241-C-106 via the ventilation system

International Nuclear Information System (INIS)

Minteer, D.J.

1995-01-01

The purpose of this analysis is to estimate the uncertainty in the measured quantity of water which typically leaves Tank 241-C-106 via the ventilation system each month. Such measurements are essential for heat removal estimation and tank liquid level verification purposes. The uncertainty associated with the current, infrequent, manual method of measurement (involves various psychrometric and pressure measurements) is suspected to be unreasonably high. Thus, the possible reduction of this uncertainty using a continuous, automated method of measurement will also be estimated. There are three major conclusions as a result of this analysis: (1) the uncertainties associated with the current (infrequent, manual) method of measuring the water which typically leaves Tank 241-C-106 per month via the ventilation system are indeed quite high (80% to 120%); (2) given the current psychrometric and pressure measurement methods and any tank which loses considerable moisture through active ventilation, such as Tank 241-C-106, significant quantities of liquid can actually leak from the tank before a leak can be positively identified via liquid level measurement; (3) using improved (continuous, automated) methods of taking the psychrometric and pressure measurements, the uncertainty in the measured quantity of water leaving Tank 241-C-106 via the ventilation system can be reduced by approximately an order of magnitude

Acceptance test report for the Tank 241-C-106 in-tank imaging system

International Nuclear Information System (INIS)

Pedersen, L.T.

1998-01-01

This document presents the results of Acceptance Testing of the 241-C-106 in-tank video camera imaging system. The purpose of this imaging system is to monitor the Project W-320 sluicing of Tank 241-C-106. The objective of acceptance testing of the 241-C-106 video camera system was to verify that all equipment and components function in accordance with procurement specification requirements and original equipment manufacturer's (OEM) specifications. This document reports the results of the testing

Project W-340 tank 241-C-106 manipulator system closeout summary

International Nuclear Information System (INIS)

McDaniel, L.B.

1995-02-01

This document summarizes the work that was ongoing when Project W-340 was put on hold. Project W-340: Tank 241-C-106 Manipulator Retrieval System, was a candidate FY98 Major System Acquisition. The project was to develop, procure and deploy a Long Reach Manipulator (LRM) waste retrieval system to provide an alternate method to completing the in-tank demonstration of Single Shell Tank waste retrieval technology. The need for enhanced capabilities derives from (1) the inability of the baseline technology to retrieve certain hard waste forms; (2) uncertainty in the quantity of leakage which will be allowed. Numerous studies over the years have identified an arm architecture as a promising retrieval technology to overcome these concerns. The W340 project was intended to further develop and demonstrate this alternative, as part of selecting the best approach for all tanks. Prior to completing the effort, it was determined that an LRM system was too architecture specific and was envisioned to be too expensive for a one time demonstration of retrieval technology. At the time the work was stopped, an effort was underway to broaden the project scope to allow alternatives to an arm-based system

Tank characterization report for single-shell tank 241-U-106

International Nuclear Information System (INIS)

Brown, T.M.

1997-01-01

One major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-U-106. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241-U-106 waste, and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 of this report summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, and Section 4.0 makes recommendations regarding safety status and additional sampling. The appendixes contain supporting data and information. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ikology et al. 1996), Milestone M-44-10

Tank characterization report for single-shell tank 241-U-106

Energy Technology Data Exchange (ETDEWEB)

Brown, T.M.

1997-04-15

One major function of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-U-106. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241-U-106 waste, and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 of this report summarizes the response to technical issues, Section 3.0 shows the best-basis inventory estimate, and Section 4.0 makes recommendations regarding safety status and additional sampling. The appendixes contain supporting data and information. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ikology et al. 1996), Milestone M-44-10.

Tank vapor sampling and analysis data package for tank 241-C-106 waste retrieval sluicing system process test phase III, sampled March 28, 1999

International Nuclear Information System (INIS)

LOCKREM, L.L.

1999-01-01

This data package presents sampling data and analytical results from the March 28, 1999, vapor sampling of Hanford Site single-shell tank 241-C-106 during active sluicing. Samples were obtained from the 296-C-006 ventilation system stack and ambient air at several locations. Characterization Project Operations (CPO) was responsible for the collection of all SUMMATM canister samples. The Special Analytical Support (SAS) vapor team was responsible for the collection of all triple sorbent trap (TST), sorbent tube train (STT), polyurethane foam (PUF), and particulate filter samples collected at the 296-C-006 stack. The SAS vapor team used the non-electrical vapor sampling (NEVS) system to collect samples of the air, gases, and vapors from the 296-C-006 stack. The SAS vapor team collected and analyzed these samples for Lockheed Martin Hanford Corporation (LMHC) and Tank Waste Remediation System (TWRS) in accordance with the sampling and analytical requirements specified in the Waste Retrieval Sluicing System Vapor Sampling and Analysis Plan (SAP) for Evaluation of Organic Emissions, Process Test Phase III, HNF-4212, Rev. 0-A, (LMHC, 1999). All samples were stored in a secured Radioactive Materials Area (RMA) until the samples were radiologically released and received by SAS for analysis. The Waste Sampling and Characterization Facility (WSCF) performed the radiological analyses. The samples were received on April 5, 1999

Tank 241-BY-106 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-BY-106 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-BY-106 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

High-level waste leakage from the 241-T-106 tank at Hanford

International Nuclear Information System (INIS)

Routson, R.C.; Price, W.H.; Brown, D.J.; Fecht, K.R.

1979-02-01

The history, status, fate, and impact of the 4.34 x 10 5 -liter (115,000-gal) radioactive waste tank leak from the 241-T-106 tank have been studied since 1973. As of May 1978, the maximum detected depth of the 1-microcurie per liter (μCi/l) concentration of 106 Ru penetration was 33 meters (108 ft) below the ground surface or 29 meters (95 ft) above the regional water table. This maximum depth of penetration was detected in two of the dry wells in the 241-T tank farm. In no other well has radioactivity greater than 1.0-μCi/l been found deeper than 29 meters (95 ft). This is approximately 43% of the distance from the bottom of the tank to the water table. The maximum horizontal movement of the 1-μCi/l 106 Ru concentration front from the tank was approximately 23 meters (75 ft) at a depth of 25 meters (82 ft). This distance is approximately equal to the diameter of the tank. The rate of frontal movement of radioactivity was qualitatively estimated. A large portion of the movement occurred in 1973, prior to the publication of an initial tank leak status report. From 1973 to 1974, detectable lateral movement occurred in at least some sediment layers. From 1974 to 1978, movement could not generally be detected. However, migration in wells near the leak perimeter was detected in 1978, and the probable cause defined. Calculations on vadose zone moisture and wetting frontal movement were found to be essentially in qualitative agreement in their assessed lack of movement of any waste above concentration guidelines to the Hanford ground water. Thus, during the hazardous lifetime of the fission products, there will likely be no amount of radioactivity enter the Hanford ground water. Therefore, there appears to be no impact of the leak on the Columbia River

Radiological and toxicological analyses of tank 241-AY-102 and tank 241-C-106 ventilation systems

International Nuclear Information System (INIS)

Himes, D.A.

1998-01-01

The high heat content solids contained in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W320. While sluicing operations are underway, the state of these tanks will be transformed from unagitated to agitated. This means that the partition fraction which describes the aerosol content of the head space will increase from IE-10 to IE-8 (see WHC-SD-WM-CN062, Rev. 2 for discussion of partition fractions). The head spare will become much more loaded with suspended material. Furthermore, the nature of this suspended material can change significantly: sluicing could bring up radioactive solids which normally would lay under many meters of liquid supernate. It is assumed that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split. It is further assumed that the sluicing line, the headspace in Tank 241-C-106, and the filters on Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split. The bases of these assumptions are discussed in Section 3.0. These waste compositions (referred to as mitigated compositions) were used in Attachments 1 through 4 to calculate survey meter exposure rates per liter of inventory in the various system components. Three accident scenarios are evaluated: a high temperature event which melts or burns the HEPA filters and causes releases from other system components; an overpressure event which crushes and blows out the HEPA filters and causes releases from other system components; and an unfiltered release of tank headspace air. The initiating event for the high temperature release is a fire caused by a heater malfunction inside the exhaust dust or a fire outside the duct. The initiating event for the overpressure event could be a steam bump which over pressurizes the tank and leads to a blowout of the HEPA filters in the ventilation system. The catastrophic destruction of the HEPA filters would release a fraction of the accumulated

Radiological and toxicological analyses of tank 241-AY-102 and tank 241-C-106 ventilation systems

Energy Technology Data Exchange (ETDEWEB)

Himes, D.A.

1998-08-11

The high heat content solids contained in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W320. While sluicing operations are underway, the state of these tanks will be transformed from unagitated to agitated. This means that the partition fraction which describes the aerosol content of the head space will increase from IE-10 to IE-8 (see WHC-SD-WM-CN062, Rev. 2 for discussion of partition fractions). The head spare will become much more loaded with suspended material. Furthermore, the nature of this suspended material can change significantly: sluicing could bring up radioactive solids which normally would lay under many meters of liquid supernate. It is assumed that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split. It is further assumed that the sluicing line, the headspace in Tank 241-C-106, and the filters on Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split. The bases of these assumptions are discussed in Section 3.0. These waste compositions (referred to as mitigated compositions) were used in Attachments 1 through 4 to calculate survey meter exposure rates per liter of inventory in the various system components. Three accident scenarios are evaluated: a high temperature event which melts or burns the HEPA filters and causes releases from other system components; an overpressure event which crushes and blows out the HEPA filters and causes releases from other system components; and an unfiltered release of tank headspace air. The initiating event for the high temperature release is a fire caused by a heater malfunction inside the exhaust dust or a fire outside the duct. The initiating event for the overpressure event could be a steam bump which over pressurizes the tank and leads to a blowout of the HEPA filters in the ventilation system. The catastrophic destruction of the HEPA filters would release a fraction of the accumulated

Sample preparation of tank 241-C-106 grab samples and testing For compatibility with tank 241-AY-102 supernate

International Nuclear Information System (INIS)

Crawford, B.A.

1996-01-01

This test plan describes a sample separation method which will be used to obtain physical measurements and separated 241-C-106 solids and supernate fractions. In addition compatibility of tank 241-C-106 sludge with tank 241-AY-102 supernate will be determined

Bench-scale enhanced sludge washing and gravity settling of Hanford Tank C-106 Sludge

International Nuclear Information System (INIS)

Brooks, K.P.; Myers, R.L.; Rappe, K.G.

1997-01-01

This report summarizes the results of a bench-scale sludge pretreatment demonstration of the Hanford baseline flowsheet using liter-quantities of sludge from Hanford Site single-shell tank 241-C-106 (tank C-106). The leached and washed sludge from these tests provided Envelope D material for the contractors supporting Tank Waste Remediation System (TWRS) Privatization. Pretreatment of the sludge included enhanced sludge washing and gravity settling tests and providing scale-up data for both these unit operations. Initial and final solids as well as decanted supernatants from each step of the process were analyzed chemically and radiochemically. The results of this work were compared to those of Lumetta et al. (1996a) who performed a similar experiment with 15 grams of C-106, sludge. A summary of the results are shown in Table S.1. Of the major nonradioactive components, those that were significantly removed with enhanced sludge washing included aluminum (31%), chromium (49%), sodium (57%), and phosphorus (35%). Of the radioactive components, a significant amount of 137 Cs (49%) were removed during the enhanced sludge wash. Only a very small fraction of the remaining radionuclides were removed, including 90 Sr (0.4%) and TRU elements (1.5%). These results are consistent with those of the screening test. All of the supernatants (both individually and as a blend) removed from these washing steps, once vitrified as LLW glasses (at 20 wt% Na 2 O), would be less than NRC Class C in TRU elements and less than NRC Class B in 90 Sr

Tank 241-U-106 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-U-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Tank 241-SX-106 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-SX-106. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedure that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Tank 241C106 structural evaluation in support of Project W320 retrieval

International Nuclear Information System (INIS)

Wallace, D.A.

1994-10-01

Tank 241C106 structural evaluation to support W320. It includes ACI code input and riser evaluations. This work uses the in situ conditions established by Julyk to develop a three-dimensional model of the tank. Non-axisymmetric loads associated with retrieval activities are applied to assess their influence on structural integrity of the tank. This study addresses loads associated with normal opertion and credible accident scenarios. The concrete structure of tank C106 is classified as a Safety Class I non-reactor structure in accordance with the definition given in SDC 4.1. The operating specifications document (OSD) limits applicable to tank C106 include a live load limit for the C Tank Farm of 100 tons. For the technical basis of this limit, the OSD references SD-RE-TI-012, which qualifies the 100 tons as that distributed over a 10-ft radius. However, there is no specification for a uniform live load that would accompany natural hazard phenomena such as snow or ash fall. There is no specific guidance on crane loads applied at the surface outside the tank radius. Further, there is no record of any seismic analysis of tanks in the C Tank Farm. The analysis documented in this report evaluates nonseismic conditions that include a concentrated live load, a uniform live load, and a crane load, in addition to the in situ loads. The model documented in this study also is used to provide the nonseismic stress contribution to the seismic load combination documented by Wallace

Vapor space characterization of waste Tank 241-U-106: Results from samples collected on March 7, 1995. Waste Tank Vapor Program

International Nuclear Information System (INIS)

Klinger, G.S.; Lucke, R.B.; McVeety, B.D.

1995-07-01

This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-U-106 (referred to as Tank U-106). The results described here were obtained to support safety and toxicological evaluations. Quantitative results were obtained for the inorganic compounds ammonia (NH 3 ), nitrogen dioxide (NO 2 ), nitric oxide (NO), and water (H 2 O) Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO x ) was not requested. The NH 3 concentration was 16% greater than that determined from an ISS sample obtained in August 1994; the H 2 O concentration was about 10% less. In addition, quantitative results were obtained for the 39 TO-14 compounds plus an additional 14 analytes. Of these, 5 were observed in two or more canisters above the 5-ppbv reporting cutoff. Eleven organic tentatively identified compounds (TICS) were observed in two or more canisters above the reporting cutoff of (ca.) 10 ppbv and are reported with concentrations that are semiquantitative estimates based on internal-standard response factors. The 10 organic analytes with the highest estimated concentrations account for approximately 90% of the total organic components in Tank U-106. Three permanent gases, nitrous oxide (N 2 O), hydrogen (H 2 ) and carbon dioxide (COD were also detected

Preliminary safety equipment list for Tank 241-C-106 Manipulator Retrieval System, Project W-340

International Nuclear Information System (INIS)

Guthrie, R.L.

1994-01-01

This document identifies the anticipated safety classification of the estimated major subsystems, based on the projected major functions, that will be used as guidance for the development of the conceptual design of the Manipulator Retrieval System for Tank 241-C-106. This document is intended to be updated as the design of the Manipulator Retrieval System evolves through the conceptual and definitive design phases. The Manipulator Retrieval System is to be capable of removing the hardened sludge heel at the bottom of single shell Tank 241-C-106 and to perform an overall clean out of the tank that leaves a maximum of 360 ft 3 (TPA milestone M-45-00). The thickness of the heel prior to initiation of waste retrieval with the Manipulator Retrieval System is estimated to be 1- to 2-ft. The Manipulator Retrieval System is currently in the pre-conceptual phase with no definitive systems or subsystems. The anticipated retrieval functions for the Manipulator Retrieval System is based on Table 6-2 of WHC-SD-W340-ES-001, Rev. 1. Projected equipment to accomplish these functions were based on the following systems and equipment: Rotary Mode Core Sampling Equipment (WHC-SD-WM-SEL-032); Light Duty Utility Arm System Equipment (WHC-SD-WM-SEL-034); Single Shell Tanks Equipment (WHC-SD-WM-SEL-020)

Tank characterization report for single-shell tank 241-T-106

International Nuclear Information System (INIS)

Jo, J.

1996-03-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-T-106. This report supports the requirements of Tri-Party Agreement Milestone M-44-09

Light duty utility arm deployment in Hanford tank T-106

International Nuclear Information System (INIS)

Kiebel, G.R.

1997-07-01

An existing gap in the technology for the remediation of underground waste storage tanks filled by the Light Duty Utility Arm (LDUA) System. On September 27 and 30, 1996, the LDUA System was deployed in underground storage tank T-106 at Hanford. The system performed successfully, satisfying all objectives of the in-tank operational test (hot test); performing close-up video inspection of features of tank dome, risers, and wall; and grasping and repositioning in-tank debris. The successful completion of hot testing at Hanford means that areas of tank structure and waste surface that were previously inaccessible are now within reach of remote tools for inspection, waste analysis, and small-scale retrieval. The LDUA System has become a new addition to the arsenal of technologies being applied to solve tank waste remediation challenges

Light duty utility arm deployment in Hanford tank T-106

Energy Technology Data Exchange (ETDEWEB)

Kiebel, G.R.

1997-07-01

An existing gap in the technology for the remediation of underground waste storage tanks filled by the Light Duty Utility Arm (LDUA) System. On September 27 and 30, 1996, the LDUA System was deployed in underground storage tank T-106 at Hanford. The system performed successfully, satisfying all objectives of the in-tank operational test (hot test); performing close-up video inspection of features of tank dome, risers, and wall; and grasping and repositioning in-tank debris. The successful completion of hot testing at Hanford means that areas of tank structure and waste surface that were previously inaccessible are now within reach of remote tools for inspection, waste analysis, and small-scale retrieval. The LDUA System has become a new addition to the arsenal of technologies being applied to solve tank waste remediation challenges.

Hanford tank residual waste - Contaminant source terms and release models

International Nuclear Information System (INIS)

Deutsch, William J.; Cantrell, Kirk J.; Krupka, Kenneth M.; Lindberg, Michael L.; Jeffery Serne, R.

2011-01-01

Highlights: → Residual waste from five Hanford spent fuel process storage tanks was evaluated. → Gibbsite is a common mineral in tanks with high Al concentrations. → Non-crystalline U-Na-C-O-P ± H phases are common in the U-rich residual. → Iron oxides/hydroxides have been identified in all residual waste samples. → Uranium release is highly dependent on waste and leachant compositions. - Abstract: Residual waste is expected to be left in 177 underground storage tanks after closure at the US Department of Energy's Hanford Site in Washington State, USA. In the long term, the residual wastes may represent a potential source of contamination to the subsurface environment. Residual materials that cannot be completely removed during the tank closure process are being studied to identify and characterize the solid phases and estimate the release of contaminants from these solids to water that might enter the closed tanks in the future. As of the end of 2009, residual waste from five tanks has been evaluated. Residual wastes from adjacent tanks C-202 and C-203 have high U concentrations of 24 and 59 wt.%, respectively, while residual wastes from nearby tanks C-103 and C-106 have low U concentrations of 0.4 and 0.03 wt.%, respectively. Aluminum concentrations are high (8.2-29.1 wt.%) in some tanks (C-103, C-106, and S-112) and relatively low ( 2 -saturated solution, or a CaCO 3 -saturated water. Uranium release concentrations are highly dependent on waste and leachant compositions with dissolved U concentrations one or two orders of magnitude higher in the tests with high U residual wastes, and also higher when leached with the CaCO 3 -saturated solution than with the Ca(OH) 2 -saturated solution. Technetium leachability is not as strongly dependent on the concentration of Tc in the waste, and it appears to be slightly more leachable by the Ca(OH) 2 -saturated solution than by the CaCO 3 -saturated solution. In general, Tc is much less leachable (<10 wt.% of the

AX Tank Farm waste retrieval alternatives cost estimates

International Nuclear Information System (INIS)

Krieg, S.A.

1998-01-01

This report presents the estimated costs associated with retrieval of the wastes from the four tanks in AX Tank Farm. The engineering cost estimates developed for this report are based on previous cost data prepared for Project W-320 and the HTI 241-C-106 Heel Retrieval System. The costs presented in this report address only the retrieval of the wastes from the four AX Farm tanks. This includes costs for equipment procurement, fabrication, installation, and operation to retrieve the wastes. The costs to modify the existing plant equipment and systems to support the retrieval equipment are also included. The estimates do not include operational costs associated with pumping the waste out of the waste receiver tank (241-AY-102) between AX Farm retrieval campaigns or transportation, processing, and disposal of the retrieved waste

Vapor space characterization of waste Tank 241-SX-106: Results from samples collected on 3/24/95

International Nuclear Information System (INIS)

Klinger, G.S.; Clauss, T.W.; Litgotke, M.W.

1995-11-01

This report describes inorganic and organic analyses results from samples obtained from the headspace of the Hanford waste storage Tank 241-SX-106 (referred to as Tank SX-106). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH 3 ), nitrogen dioxide (NO 2 ), nitric oxide (NO), and water (H 2 O). Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO x ) was not requested. In addition, quantitative results were obtained for the 39 TO-14 compounds plus an additional 14 analytes. Of these, 4 were observed above the 5-ppbv reporting cutoff. Three tentatively identified compounds (TICs) were observed above the reporting cutoff of (ca.) 10 ppbv and are reported with concentrations that are semiquantitative estimates based on internal-standard response factors. The 7 organic analytes identified are listed in Table 1 and account for approximately 100% of the total organic components in Tank SX-106. Carbon dioxide (CO 2 ) was the only permanent gas detected. Tank SX-106 is on the Ferrocyanide Watch List

Headspace vapor characterization of Hanford waste tank 241-S-106: Results from samples collected on 06/13/96

International Nuclear Information System (INIS)

Evans, J.C.; Pool, K.H.; Thomas, B.L.; Olsen, K.B.; Fruchter, J.S.; Silvers, K.L.

1997-01-01

This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-S-106 (Tank S-106) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNNL). A summary of the inorganic analytes, permanent gases, and total non-methane organic compounds is listed in a table. The three highest concentration analytes detected in SUMMA trademark canister and triple sorbent trap samples are also listed in the same table. Detailed descriptions of the analytical results appear in the appendices

Contaminant Leach Testing of Hanford Tank 241-C-104 Residual Waste

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Snyder, Michelle M.V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Wang, Guohui [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Buck, Edgar C. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

2015-07-01

Leach testing of Tank C-104 residual waste was completed using batch and column experiments. Tank C-104 residual waste contains exceptionally high concentrations of uranium (i.e., as high as 115 mg/g or 11.5 wt.%). This study was conducted to provide data to develop contaminant release models for Tank C-104 residual waste and Tank C-104 residual waste that has been treated with lime to transform uranium in the waste to a highly insoluble calcium uranate (CaUO4) or similar phase. Three column leaching cases were investigated. In the first case, C-104 residual waste was leached with deionized water. In the second case, crushed grout was added to the column so that deionized water contacted the grout prior to contacting the waste. In the third case, lime was mixed in with the grout. Results of the column experiments demonstrate that addition of lime dramatically reduces the leachability of uranium from Tank C-104 residual waste. Initial indications suggest that CaUO4 or a similar highly insoluble calcium rich uranium phase forms as a result of the lime addition. Additional work is needed to definitively identify the uranium phases that occur in the as received waste and the waste after the lime treatment.

Vapor space characterization of Waste Tank 241-U-106 (in situ): Results from samples collected on 8/25/94

International Nuclear Information System (INIS)

Ligotke, M.W.; Lucke, R.B.; Pool, K.H.

1995-10-01

This report describes inorganic and organic analyses results from in situ samples obtained from the headspace of the Hanford waste storage Tank 241-U-106 (referred to as Tank U-106). The results described here were obtained to support safety and toxicological evaluations. A summary of the results for inorganic and organic analytes is listed in Table 1. Detailed descriptions of the results appear in the text. Quantitative results were obtained for the inorganic compounds ammonia (NH 3 ), nitrogen dioxide (NO 2 ), nitric oxide (NO), and water (H 2 O). Sampling for hydrogen cyanide (HCN) and sulfur oxides (SO x ) was not performed. In addition, the authors looked for the 39 TO-14 compounds plus an additional 14 target analytes. Of these, six were observed above the 5-ppbv reporting cutoff. Ten organic tentatively identified compounds (TICs) were observed above the reporting cutoff of (ca.) 10 ppbv in two or more of the three samples collected and are reported with concentrations that are semiquantitative estimates based on internal standard response factors. The 10 organic analytes with the highest estimated concentrations are listed in Table 1 and account for approximately 89% of the total organic components in Tank U-106. Methyl isocyanate, a compound of possible concern in Tank U-106, was not detected. Tank U-106 is on the Organic Watch List

Project W-320, 241-C-106 sluicing piping calculations, Volume 7

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

The object of this report is to calculate the hydraulic forces imposed at the sluicer nozzle. This is required by Project W-320 waste retrieval for tank 241-C-106. The method of analysis used is Bernoulli's momentum equation for stead flow

Waste compatibility assessments to support project W-320

International Nuclear Information System (INIS)

BLAAK, T.M.

1999-01-01

The intent of this internal memo is to provide a recommendation for the transfer of tank 241-C-106 waste, Attachment 2, to tank 241-AY-102. This internal memo also identifies additional requirements which have been deemed necessary for safely receiving and storing the waste documented in Attachment 2 from tank 241-C-106 in tank 241-AY-102. This waste transfer is planned in support of tank 241-C-106 solids sluicing activities. Approximately 200,000 gallons of waste and flush water are expected to be pumped from tank 241-C-106 into tank 241-AY-102. Several transfers will be necessary to complete the sluicing of tank 241-C-106 solids. To assure ourselves that this waste transfer will not create any compatibility concerns, a waste compatibility assessment adhering to current waste compatibility requirements has been performed

Permitting plan for Project W-340, Tank 241-C-106 manipulator retrieval arm

International Nuclear Information System (INIS)

Tollefson, K.S.

1995-01-01

This document describes the regulatory requirements and describes alternative strategies for obtaining permits and approvals for Project W-340, Tank 241-C-106 Manipulator Retrieval Arm. A comprehensive review of environmental regulations has indicated that several environmental reviews, permits, and approvals are required before design, construction, and operation of the facility. The environmental reviews, permits, and approvals, as well the regulatory authority potentially applicable to the Project W-340 Long Reach Manipulator Arm include the following: National Environmental Policy Act of 1969 -- US Department of Energy, Headquarters; State Environmental Policy Act of 1971 -- State of Washington Department of Ecology; Air Permitting; Dangerous Waste Permitting; Miscellaneous Reviews/Permits/Approvals. This document describes the environmental reviews, permits, and approval requirements for the project. It provides a summary of permit application data requirements, alternative strategies for permit completion and approval, as well as the estimated probability of success for each alternative strategy

Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109

Energy Technology Data Exchange (ETDEWEB)

Mahoney, L.A.; Antoniak, Z.I.; Bates, J.M.

1997-12-01

This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data.

Composition and quantities of retained gas measured in Hanford waste tanks 241-U-103, S-106, BY-101, and BY-109

International Nuclear Information System (INIS)

Mahoney, L.A.; Antoniak, Z.I.; Bates, J.M.

1997-12-01

This report provides the results obtained for the single-shell tanks (SSTs) sampled with the Retained Gas Sampler (RGS) during 1997: Tanks 241-U-103, 241-S-106, 241-BY-101, and 241-BY-109. The RGS is a modified version of the core sampler used at Hanford. It is designed specifically to be used in concert with the gas extraction equipment in the hot cell to capture and extrude a gas-containing waste sample in a hermetically sealed system. The four tanks represent several different types of flammable gas SSTs. Tank U-103 is on the Flammable Gas Watch List (FGWL) and is one of the highest-priority group of SSTs that show evidence of significant gas retention. Tank S-106, though not a FGWL tank, has a uniquely high barometric pressure response and continuing rapid surface level rise, indicating a large and increasing volume of retained gas. Tanks BY-101 and BY-109 are not on the FGWL but were chosen to test the effect of recent salt-well pumping on gas retention. Section 2 of this report provides an overview of the process by which retained gases in the Hanford tanks are sampled and analyzed. A detailed description of the procedure used to reduce and analyze the data is provided in Section 3. Tank-by-tank results are covered in Section 4 (with the data presented in the order in which the tanks were sampled), and an RGS system performance overview is given in Section 5. Section 6 presents conclusions from these analyses and recommendations for further research. The cited references are listed in Section 7. Appendix A describes the procedures used to extract gas and ammonia from the samples, Appendix B contains detailed laboratory data from each of the tanks, and Appendix C gives field sampling data

Characterization of the C1 and C2 waste tanks located in the BVEST system at ORNL

International Nuclear Information System (INIS)

Keller, J.M.; Giaquinto, J.M.

1998-02-01

There was a major effort to sample and analyze the Active Liquid Low-Level Waste (LLLW) tanks at ORNL which include the Melton Valley Storage Tanks (MVST) and the Bethel Valley Evaporator Service Tanks (BVEST). The characterization data summarized in this report was needed to address waste processing options, address concerns dealing with the performance assessment (PA) data for the Waste Isolation Pilot Plant (WIPP), evaluate the waste characteristics with respect to the waste acceptance criteria (WAC) for WIPP and Nevada Test Site (NTS), address criticality concerns, and meet DOT requirements for transporting the waste. This report discusses the analytical characterization data for the supernatant and sludge in the BVEST waste tanks C-1 and C-2. The isotopic data presented in this report supports the position that fissile isotopes of uranium ( 233 U and 235 U) and plutonium ( 239 Pu and 241 Pu) were denatured as required by the administrative controls stated in the ORNL LLLW waste acceptance criteria (WAC). In general, the sludge in tanks C1 and C2 was found to be hazardous based on RCRA characteristics and the transuranic alpha activity was well above the 100 nCi/g limit for TRU waste. Additional characteristics of the C1 and C2 sludge inventory relative to the WIPP WAC limits for fissile gram equivalent, plutonium equivalent activity, and thermal power from decay heat were estimated from the data in this report and found to be far below the upper boundary for any of the remote-handled transuranic waste (RH-TRU) requirements for disposal of the waste in WIPP

Implementation guide for Hanford Tanks Initiative C-106 heel retrieval contract management HNF-2511

International Nuclear Information System (INIS)

McDaniel, L.B.

1998-01-01

This report is an Implementation Guide for Hanford Tanks Initiative C-106 heel retrieval contract management HNF-2511 to provide a set of uniform instructions for managing the two contractors selected. The primary objective is to produce the necessary deliverables and services for the HTI project within schedule and budget

Hanford tank initiative test facility site selection study

International Nuclear Information System (INIS)

Staehr, T.W.

1997-01-01

The Hanford Tanks Initiative (HTI) project is developing equipment for the removal of hard heel waste from the Hanford Site underground single-shell waste storage tanks. The HTI equipment will initially be installed in the 241-C-106 tank where its operation will be demonstrated. This study evaluates existing Hanford Site facilities and other sites for functional testing of the HTI equipment before it is installed into the 241-C-106 tank

Tank 241-C-107 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

The Defense Nuclear Facilities Safety Board (DNFSB) has advised the US Department of Energy (DOE) to concentrate the near-term sampling and analysis activities on identification and resolution of safety issues. The data quality objective (DQO) process was chosen as a tool to be used to identify sampling and analytical needs for the resolution of safety issues. As a result, a revision in the Federal Facility Agreement and Consent Order (Tri-Party Agreement or TPA) milestone M-44-00 has been made, which states that ''A Tank Characterization Plan (TCP) will also be developed for each double-shell tank (DST) and single-shell tank (SST) using the DQO process... Development of TCPs by the DQO process is intended to allow users (e.g., Hanford Facility user groups, regulators) to ensure their needs will be met and that resources are devoted to gaining only necessary information.'' This document satisfies that requirement for the Tank 241-C-107 (C-107) sampling activities. Currently tank C-107 is categorized as a sound, low-heat load tank with partial isolation completed in December 1982. The tank is awaiting stabilization. Tank C-107 is expected to contain three primary layers of waste. The bottom layer should contain a mixture of the following wastes: ion exchange, concentrated phosphate waste from N-Reactor, Hanford Lab Operations, strontium semi-works, Battelle Northwest, 1C, TBP waste, cladding waste, and the hot semi-works. The middle layer should contain strontium recovery supernate. The upper layer should consist of non-complexed waste

Removal of floating organic in Hanford Waste Tank 241-C-103 restart plan

International Nuclear Information System (INIS)

Wilson, T.R.; Hanson, C.

1994-01-01

The decision whether or not to remove the organic layer from Waste Tank 241-C-103 was deferred until May, 1995. The following restart plan was prepared for removal of the organic if the decision is to remove the organic from the waste tank 241-C-103

Removal of floating organic in Hanford Waste Tank 241-C-103 restart plan

Energy Technology Data Exchange (ETDEWEB)

Wilson, T.R.; Hanson, C.

1994-10-03

The decision whether or not to remove the organic layer from Waste Tank 241-C-103 was deferred until May, 1995. The following restart plan was prepared for removal of the organic if the decision is to remove the organic from the waste tank 241-C-103.

Hanford Tanks 241-C-202 and 241-C-203 Residual Waste Contaminant Release Models and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Deutsch, William J.; Krupka, Kenneth M.; Lindberg, Michael J.; Cantrell, Kirk J.; Brown, Christopher F.; Mattigod, Shas V.; Schaef, Herbert T.; Arey, Bruce W.

2007-09-13

As directed by Congress, the U. S. Department of Energy (DOE) established the Office of River Protection in 1998 to manage DOE's largest, most complex environmental cleanup project – retrieval of radioactive waste from Hanford tanks for treatment and eventual disposal. Sixty percent by volume of the nation's high-level radioactive waste is stored at Hanford in aging deteriorating tanks. If not cleaned up, this waste is a threat to the Columbia River and the Pacific Northwest. CH2M Hill Hanford Group, Inc., is the Office of River Protection's prime contractor responsible for the storage, retrieval, and disposal of Hanford's tank waste. As part of this effort, CH2M HILL Hanford Group, Inc. contracted with Pacific Northwest National Laboratory (PNNL) to develop release models for key contaminants that are present in residual sludge remaining after closure of Hanford Tanks 241-C-203 (C-203) and 241-C-204 (C-204). The release models were developed from data generated by laboratory characterization and testing of samples from these two tanks. These release models are being developed to support the tank closure risk assessments performed by CH2M HILL Hanford Group, Inc., for DOE.

Tank characterization data report: Tank 241-C-112

Energy Technology Data Exchange (ETDEWEB)

Simpson, B.C.; Borsheim, G.L.; Jensen, L.

1993-09-01

Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. Analysis of the process history of the tank as well as studies of simulants provided valuable information about the physical and chemical condition of the waste. This information, in combination with the analysis of the tank waste, sup ports the conclusion that an exothermic reaction in tank 241-C-112 is not plausible. Therefore, the contents of tank 241-C-112 present no imminent threat to the workers at the Hanford Site, the public, or the environment from its forrocyanide inventory. Because an exothermic reaction is not credible, the consequences of this accident scenario, as promulgated by the General Accounting Office, are not applicable.

Tank characterization data report: Tank 241-C-112

International Nuclear Information System (INIS)

Simpson, B.C.; Borsheim, G.L.; Jensen, L.

1993-09-01

Tank 241-C-112 is a Hanford Site Ferrocyanide Watch List tank that was most recently sampled in March 1992. Analyses of materials obtained from tank 241-C-112 were conducted to support the resolution of the Ferrocyanide Unreviewed Safety Question (USQ) and to support Hanford Federal Facility Agreement and Consent Order (Tri-Party Agreement) Milestone M-10-00. Analysis of core samples obtained from tank 241-C-112 strongly indicates that the fuel concentration in the tank waste will not support a propagating exothermic reaction. Analysis of the process history of the tank as well as studies of simulants provided valuable information about the physical and chemical condition of the waste. This information, in combination with the analysis of the tank waste, sup ports the conclusion that an exothermic reaction in tank 241-C-112 is not plausible. Therefore, the contents of tank 241-C-112 present no imminent threat to the workers at the Hanford Site, the public, or the environment from its forrocyanide inventory. Because an exothermic reaction is not credible, the consequences of this accident scenario, as promulgated by the General Accounting Office, are not applicable

Neutralized current acid waste consolidation management plan

International Nuclear Information System (INIS)

Powell, W.J.; Brown, R.G.; Galbraith, J.; Jensen, C.; Place, D.E.; Reddick, G.W.; Zuroff, W.; Brothers, A.J.

1996-01-01

The scope of this evaluation is to recommend a management plan for the high-heat tank waste, including neutralized current acid waste (NCAW) in AY and AZ Tank Farms, and tank C-106 waste. The movement of solids, liquids and salt cake in the designated tank farms is included. Decision analysis techniques were used to determine a recommended alternative. The recommended course of action was replacement of a 75-hp mixer pump in tank AY-102 and in-tank concentration of tank AZ-102 supernate. The alternative includes transfer fo tank C-106 sludge to tank AY-102, then transfer to tank AY-102 and tank C-106 sludge to tank AZ-101 using the new 75-hp mixer pump installed in tank AY-102. Tank AZ-101 becomes a storage tank for high-level waste (HLW) sludge, with the capacity to mix and transfer sludge as desired

Remaining Sites Verification Package for the 116-C-3, 105-C Chemical Waste Tanks. Attachment to Waste Site Reclassification Form 2008-002

International Nuclear Information System (INIS)

Dittmer, L.M.

2008-01-01

The 116-C-3 waste site consisted of two underground storage tanks designed to receive mixed waste from the 105-C Reactor Metals Examination Facility chemical dejacketing process. Confirmatory evaluation and subsequent characterization of the site determined that the southern tank contained approximately 34,000 L (9,000 gal) of dejacketing wastes, and that the northern tank was unused. In accordance with this evaluation, the verification sampling and modeling results support a reclassification of this site to Interim Closed Out. The results of verification sampling demonstrate that residual contaminant concentrations do not preclude any future uses and allow for unrestricted use of shallow zone soils. The results also show that residual contaminant concentrations are protective of groundwater and the Columbia River

Final Hazard Categorization for the Remediation of the 116-C-3 Chemical Waste Tanks

Energy Technology Data Exchange (ETDEWEB)

T. M. Blakley; W. D. Schofield

2007-09-10

This final hazard categorization (FHC) document examines the hazards, identifies appropriate controls to manage the hazards, and documents the commitments for the 116-C-3 Chemical Waste Tanks Remediation Project. The remediation activities analyzed in this FHC are based on recommended treatment and disposal alternatives described in the Engineering Evaluation for the Remediation to the 116-C-3 Chemical Waste Tanks (BHI 2005e).

Potential for criticality in Hanford tanks resulting from retrieval of tank waste

International Nuclear Information System (INIS)

Whyatt, G.A.; Sterne, R.J.; Mattigod, S.V.

1996-09-01

This report assesses the potential during retrieval operations for segregation and concentration of fissile material to result in a criticality. The sluicing retrieval of C-106 sludge to AY-102 and the operation of mixer pumps in SY-102 are examined in some detail. These two tanks (C-106, SY-102) were selected because of the near term plans for retrieval of these tanks and their high plutonium inventories relative to other tanks. Although all underground storage tanks are subcritical by a wide margin if assumed to be uniform in composition, the possibility retrieval operations could preferentially segregate the plutonium and locally concentrate it sufficiently to result in criticality was a concern. This report examines the potential for this segregation to occur

Hanford waste tanks-light at the end of the tunnel

International Nuclear Information System (INIS)

POPPITI, J.A.

1999-01-01

The U.S. Department of Energy (DOE) faced several problems in its Hanford Site tank farms in the early nineties. It had 177 waste tanks, ranging in size from 55,000 to 1,100,000 gallons, which contained more than 55 million gallons of liquid and solid high-level radioactive waste (HLW) from a variety of processes. Unfortunately, waste transfer records were incomplete. Chemical reactions going on in the tanks were not totally understood. Every tank had high concentrations of powerful oxidizers in the form of nitrates and nitrites, and some tanks had relatively high concentrations of potential fuels that could react explosively with oxidizers. A few of these tanks periodically released large quantities of hydrogen and nitrous oxide, a mixture that was potentially more explosive than hydrogen and air. Both the nitrate/fuel and hydrogen/nitrous oxide reactions had the potential to rupture a tank exposing workers and the general public to unacceptably large quantities of radioactive material. One tank (241-C-106) was generating so much heat that water had to be added regularly to avoid thermal damage to the tank's concrete exterior shell. The tanks contained more than 250 million Curies of radioactivity. Some of that radioactivity was in the form of fissile plutonium, which represented a potential criticality problem. As awareness of the potential hazards grew, the public and various regulatory agencies brought increasing pressure on DOE to quantify the hazards and mitigate any that were found to be outside accepted risk guidelines. In 1990, then Representative, now Senator Ron Wyden (D-Oregon), introduced an amendment to Public Law 101-510, Section 3137, that required DOE to identify Hanford tanks that might have a serious potential for release of high-level waste

Tank 241-BY-106 tank characterization plan

International Nuclear Information System (INIS)

Schreiber, R.D.

1995-01-01

This document is a plan which serves as the contractual agreement between the Characterization Program, Sampling Operations, PNL 325 Analytical Chemistry Laboratory, and WHC 222-S Laboratory. The scope of this plan is to provide guidance for the sampling and analysis of samples for tank 241-BY-106

Project W-320, 241-C-106 sluicing: Construction specification W-320-C1

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits

Tank characterization report for single-shell tank 241-C-109

Energy Technology Data Exchange (ETDEWEB)

Simpson, B.C.

1997-05-23

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-C-109. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241 C-109 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices.

Tank characterization report for single-shell tank 241-C-109

International Nuclear Information System (INIS)

Simpson, B.C.

1997-01-01

One of the major functions of the Tank Waste Remediation System (TWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-C-109. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241 C-109 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices

Tank 241-B-106 tank characterization plan. Revision 1

International Nuclear Information System (INIS)

Homi, C.S.

1995-01-01

This document is a plan that identifies the information needed to address relevant issues concerning short-term and long-term safe storage and long-term management of Single-Shell Tank (SST) 241-B-106

Tank characterization report for single-shell tank 241-C-104

Energy Technology Data Exchange (ETDEWEB)

Baldwin, J.H.

1997-05-21

A major function of the Tank Waste Remediation System is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendices serve as the TCR for single-shell tank 241-C-104. The objectives of this report are: (1) to use characterization data in response to technical issues associated with tank 241-C-104 waste; and (2) to provide a standard characterization of this waste in terms of a best-basis inventory estimate. The response to technical issues is summarized in Section 2.0, and the best-basis inventory estimate is presented in Section 3.0. Recommendations regarding safety status and additional sampling needs are provided in Section 4.0. Supporting data and information are contained in the appendices. This report supports the requirements of the Hanford Federal Facility Agreement and Consent Order (Ecology et al. 1996) milestone M-44-10.

Leach and EP [extraction procedure] toxicity tests on grouted waste from Tank 106-AN

International Nuclear Information System (INIS)

Serne, R.J.; Martin, W.J.; Lokken, R.O.; LeGore, V.L.; Lindenmeier, C.W.; Martin, P.F.C.

1989-09-01

Pacific Northwest Laboratory is conducting laboratory experiments to produce leach rate data for various waste species that will be contained in grout at Hanford. In the work reported here, grout made from Tank 106-AN liquid waste was used to produce empirical leach rate data for several radionuclides ( 60 Co, 90 Sr, 99Tc, 129I, 137Cs, and 241 Am), stable major components (NO 3 - , NO 2 - , F, Cl, and Na), and trace metals (Cr, Mo, and Ni). Two types of tests were used to produce leach rate data: an intermittent replacement leach test (ANS 16.1 leach test) and a static leach test. Measured effective diffusivities of key species are as follows: 4 to 6 x 10 -8 cm 2 /sec for 99 Tc, 3 to 7 x 10 -8 cm 2 /sec for 129 I, 4 to 6 x 10 -9 cm 2 /sec for nitrate, and 6 to 7 x 10 -9 cm 2 /sec for nitrite. The leach indices of all species studied are above (more favorable than) the waste form criteria. The leach indices for 99 Tc and 129 I are 7.4 ± 1.2 and 7.6 ± 0.4, respectively, and are being further investigated in continuing studies of double-shell slurry feed grouts. An Extraction Procedure (EP) toxicity test was also conducted and the grouted water is considered nontoxic per this test protocol. 19 refs., 9 figs., 8 tabs

High-heat tank safety issue resolution program plan

International Nuclear Information System (INIS)

Wang, O.S.

1993-12-01

The purpose of this program plan is to provide a guide for selecting corrective actions that will mitigate and/or remediate the high-heat waste tank safety issue for single-shell tank (SST) 241-C-106. This program plan also outlines the logic for selecting approaches and tasks to mitigate and resolve the high-heat safety issue. The identified safety issue for high-heat tank 241-C-106 involves the potential release of nuclear waste to the environment as the result of heat-induced structural damage to the tank's concrete, if forced cooling is interrupted for extended periods. Currently, forced ventilation with added water to promote thermal conductivity and evaporation cooling is used to cool the waste. At this time, the only viable solution identified to resolve this safety issue is the removal of heat generating waste in the tank. This solution is being aggressively pursued as the permanent solution to this safety issue and also to support the present waste retrieval plan. Tank 241-C-106 has been selected as the first SST for retrieval. The program plan has three parts. The first part establishes program objectives and defines safety issues, drivers, and resolution criteria and strategy. The second part evaluates the high-heat safety issue and its mitigation and remediation methods and alternatives according to resolution logic. The third part identifies major tasks and alternatives for mitigation and resolution of the safety issue. Selected tasks and best-estimate schedules are also summarized in the program plan

Project W-320, 241-C-106 sluicing: Construction specification W-320-C2

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits

Project W-320, 241-C-106 sluicing: Construction specification W-320-C2

Energy Technology Data Exchange (ETDEWEB)

Bailey, J.W.

1998-07-20

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits.

Project W-320, 241-C-106 sluicing: Construction specification W-320-C6

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits

Project W-320, 241-C-106 sluicing: Construction specification W-320-C5

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits

Project W-320, 241-C-106 sluicing: Construction specification W-320-C7

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits

Project W-320, 241-C-106 sluicing: Construction specification W-320-C5

Energy Technology Data Exchange (ETDEWEB)

Bailey, J.W.

1998-07-20

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits.

Project W-320, 241-C-106 sluicing: Construction specification W-320-C7

Energy Technology Data Exchange (ETDEWEB)

Bailey, J.W.

1998-07-20

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits.

Project W-320, 241-C-106 sluicing: Construction specification W-320-C6

Energy Technology Data Exchange (ETDEWEB)

Bailey, J.W.

1998-07-20

This supporting document has been prepared to make the construction specifications for Project W-320 readily available. Project W-320, Waste Retrieval Sluicing System (WRSS), specification is for procurement, fabrication and installation of equipment at the C Tank Farm, including Operator Station and some equipment just outside the C Tank Farm fence, necessary to support the sluicing operation. Work consists of furnishing labor, equipment, and materials to provide the means to procure materials and equipment, fabricate items, excavate and place concrete, and install equipment, piping, wiring, and structures in accordance with the Contract Documents. Major work elements include: Excavation for process and fire protection piping, electrical conduit trenches, and foundations for small structures; Placement of concrete cover blocks, foundations, and equipment pads; Procurement and installation of double walled piping, electrical conduit, fire and raw water piping, chilled water piping, and electrical cable; Procurement and installation of above-ground ventilation system piping between the (HVAC) Process building and Tank C-106; Core drill existing concrete; Furnish and installation of electrical distribution equipment; Installation of the concrete foundation, and assembly installation of the two Seismic Shutdown Systems with Environmental Enclosures; Fabrication and installation of in-pit pipe jumpers, including related valves, instruments and wiring; and Installation of a vertical submersible pump, horizontal booster pump, and winch assembly into tank access riser pits.

Organic Tanks Safety Program: Advanced organic analysis FY 1996 progress report

International Nuclear Information System (INIS)

1996-09-01

Major focus during the first part of FY96 was to evaluate using organic functional group concentrations to screen for energetics. Fourier transform infrared and Raman spectroscopy would be useful screening tools for determining C-H and COO- organic content in tank wastes analyzed in a hot cell. These techniques would be used for identifying tanks of potential safety concern that may require further analysis. Samples from Tanks 241-C-106 and -C-204 were analyzed; the major organic in C-106 was B2EHPA and in C-204 was TBP. Analyses of simulated wastes were also performed for the Waste Aging Studies Task; organics formed as a result of degradation were identified, and the original starting components were monitored quantitatively. Sample analysis is not routine and required considerable methods adaptation and optimization. Several techniques have been evaluated for directly analyzing chelator and chelator fragments in tank wastes: matrix-assisted laser desorption/ionization time-of-flight mass spectrometry and liquid chromatography with ultraviolet detection using Cu complexation. Although not directly funded by the Tanks Safety Program, the success of these techniques have implications for both the Flammable Gas and Organic Tanks Safety Programs

Contaminant Release from Residual Waste in Single Shell Tanks at the Hanford Site, Washington, USA - 9276

International Nuclear Information System (INIS)

Cantrell, Kirk J.; Krupka, Kenneth M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Determinations of elemental and solid-phase compositions, and contaminant release studies have been applied in an ongoing study of residual tank wastes (i.e., waste remaining after final retrieval operations) from five of 149 underground single-shell storage tanks (241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112) at the U.S. Department of Energy's Hanford Site in Washington State. This work is being conducted to support performance assessments that will be required to evaluate long-term health and safety risks associated with tank site closure. The results of studies completed to date show significant variability in the compositions, solid phase properties, and contaminant release characteristics from these residual tank wastes. This variability is the result of differences in waste chemistry/composition of wastes produced from several different spent fuel reprocessing schemes, subsequent waste reprocessing to remove certain target constituents, tank farm operations that concentrated wastes and mixed wastes between tanks, and differences in retrieval processes used to remove the wastes from the tanks. Release models were developed based upon results of chemical characterization of the bulk residual waste, solid-phase characterization (see companion paper 9277 by Krupka et al.), leaching and extraction experiments, and geochemical modeling. In most cases empirical release models were required to describe contaminant release from these wastes. Release of contaminants from residual waste was frequently found to be controlled by the solubility of phases that could not be identified and/or for which thermodynamic data and/or dissolution rates have not been measured. For example, significant fractions of Tc-99, I-129, and Cr appear to be coprecipitated at trace concentrations in metal oxide phases that could not be identified unambiguously. In the case of U release from tank 241-C-103 residual waste, geochemical calculations indicated that leachate

Hanford Site organic waste tanks: History, waste properties, and scientific issues

International Nuclear Information System (INIS)

Strachan, D.M.; Schulz, W.W.; Reynolds, D.A.

1993-01-01

Eight Hanford single-shell waste tanks are included on a safety watch list because they are thought to contain significant concentrations of various organic chemical. Potential dangers associated with the waste in these tanks include exothermic reaction, combustion, and release of hazardous vapors. In all eight tanks the measured waste temperatures are in the range 16 to 46 degree C, far below the 250 to 380 degree C temperatures necessary for onset of rapid exothermic reactions and initiation of deflagration. Investigation of the possibility of vapor release from Tank C-103 has been elevated to a top safety priority. There is a need to obtain an adequate number of truly representative vapor samples and for highly sensitive and capable methods and instruments to analyze these samples. Remaining scientific issues include: an understanding of the behavior and reaction of organic compounds in existing underground tank environments knowledge of the types and amounts of organic compounds in the tanks knowledge of selected physical and chemical properties of organic compounds source, composition, quality, and properties of the presently unidentified volatile organic compound(s) apparently evolving from Tank C-103

Criticality considerations for salt-cake disolution in DOE waste tanks

International Nuclear Information System (INIS)

Trumble, E.F.; Niemer, K.A.

1995-01-01

A large amount of high-level waste is being stored in the form of salt cake at the Savannah River site (SRS) in large (1.3 x 106 gal) underground tanks awaiting startup of the Defense Waste Processing Facility (DWPF). This salt cake will be dissolved with water, and the solution will be fed to DWPF for immobilization in borosilicate glass. Some of the waste that was transferred to the tanks contained enriched uranium and plutonium from chemical reprocessing streams. As water is added to these tanks to dissolve the salt cake, the insoluble portion of this fissile material will be left behind in the tank as the salt solution is pumped out. Because the salt acts as a diluent to the fissile material, the process of repeated water addition, salt dissolution, and salt solution removal will act as a concentrating mechanism for the undissolved fissile material that will remain in the tank. It is estimated that tank 41 H at SRS contains 20 to 120 kg of enriched uranium, varying from 10 to 70% 235 U, distributed nonuniformly throughout the tank. This paper discusses the criticality concerns associated with the dissolution of salt cake in this tank. These concerns are also applicable to other salt cake waste tanks that contain significant quantities of enriched uranium and/or plutonium

Characterization of Hanford tank wastes containing ferrocyanides

International Nuclear Information System (INIS)

Tingey, J.M.; Matheson, J.D.; McKinley, S.G.; Jones, T.E.; Pool, K.H.

1993-02-01

Currently, 17 storage tanks on the Hanford site that are believed to contain > 1,000 gram moles (465 lbs) of ferrocyanide compounds have been identified. Seven other tanks are classified as ferrocyanide containing waste tanks, but contain less than 1,000 gram moles of ferrocyanide compounds. These seven tanks are still included as Hanford Watch List Tanks. These tanks have been declared an unreviewed safety question (USQ) because of potential thermal reactivity hazards associated with the ferrocyanide compounds and nitrate and nitrite. Hanford tanks with waste containing > 1,000 gram moles of ferrocyanide have been sampled. Extensive chemical, radiothermical, and physical characterization have been performed on these waste samples. The reactivity of these wastes were also studied using Differential Scanning Calorimetry (DSC) and Thermogravimetric analysis. Actual tank waste samples were retrieved from tank 241-C-112 using a specially designed and equipped core-sampling truck. Only a small portion of the data obtained from this characterization effort will be reported in this paper. This report will deal primarily with the cyanide and carbon analyses, thermal analyses, and limited physical property measurements

Tank characterization report for single-shell tank 241-C-110. Revision 1

International Nuclear Information System (INIS)

Benar, C.J.

1997-01-01

One of the major functions of the Tank Waste Remediation System (IWRS) is to characterize wastes in support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis, along with other available information about a tank, are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for single-shell tank 241-C-110. The objectives of this report are to use characterization data in response to technical issues associated with 241-C-110 waste and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Supporting data and information are contained in the appendixes. This report also supports the requirements of the Hanford Federal Facility Agreement and Consent Order milestone M-44-05. Characterization information presented in this report originated from sample analyses and known historical sources. While only the results from recent sample events will be used to fulfill the requirements of the data quality objectives (DQOs), other information can be used to support or question conclusions derived from these results. Historical information for tank 241-C-110 are provided included surveillance information, records pertaining to waste transfers and tank operations, and 1124 expected tank contents derived from a process knowledge model. The sampling events are listed, as well as sample data obtained before 1989. The results of the 1992 sampling events are also reported in the data package. The statistical analysis and numerical manipulation of data used in issue resolution are reported in Appendix C. Appendix D contains the evaluation to establish the best basis for the inventory estimate and the statistical analysis performed for this evaluation. A bibliography that resulted from an in-depth literature search of all known information sources applicable to tank 241-C-110 and its respective waste types is contained in Appendix E

Test Summary Report Vitrification Demonstration of an Optimized Hanford C-106/AY-102 Waste-Glass Formulation

International Nuclear Information System (INIS)

Goles, Ronald W.; Buchmiller, William C.; Hymas, Charles R.; MacIsaac, Brett D.

2002-01-01

In order to further the goal of optimizing Hanford?s HLW borosilicate flowsheet, a glass formulation effort was launched to develop an advanced high-capacity waste form exhibiting acceptable leach and crystal formation characteristics. A simulated C-106/AY-102 waste envelop inclusive of LAW pretreatment products was chosen as the subject of these nonradioactive optimization efforts. To evaluate this optimized borosilicate waste formulation under continuous dynamic vitrification conditions, a research-scale Joule-heated ceramic melter was used to demonstrate the advanced waste form?s flowsheet. The main objectives of this melter test was to evaluate (1) the processing characteristics of the newly formulated C-106/AY-102 surrogate melter-feed stream, (2) the effectiveness of sucrose as a glass-oxidation-state modifier, and (3) the impact of this reductant upon processing rates

Calculation note: project W-320 primary ventilation air flow requirements for mitigation of steady state flammable gas concentrations in the headspaces of tanks 241-C-106 and 241-AY-102

International Nuclear Information System (INIS)

Estey, S.D.

1997-01-01

This calculation note analyzes headspace concentrations of hydrogen dependent upon assumed ventilation flow rates provided for tanks 241-C-106 and 241-AY-102. The analyses are based on measured or estimated steady state hydrogen release rates. Tank 241-C-106 is analyzed prior to sluicing; tank 241-AY-102 is analyzed both prior to and after completion of sluicing. Specific analyses, using both best estimated and bounding hydrogen generation rates, include the minimum primary ventilation flow rates required in the tanks to ensure that the steady state hydrogen concentration in the respective tank headspace does not exceed 25% and 100% of the LFL. The headspace hydrogen concentration as a function of time as well as the time required to reach 25% and 100% of LFL upon complete loss of active ventilation, starting from the steady state hydrogen concentration based on a 200 CFM minimum flow rate in tank 241-C-106 and a 100 CFM minimum flow rate in tank241-AY-102. The headspace hydrogen concentration as a function of thee following partial loss of active ventilation (i.e., step changes to l60, l20, 80, and 40 CFM ventilation flow rates) in tank 241-C-106, staffing from a 200 CFM flow rate and the corresponding steady state hydrogen concentration based on the 200 CFM flow rate. The headspace hydrogen concentration as a function of the following partial loss of active ventilation i.e., step changes to 80, 60, 40, and 20 CFM ventilation flow rates) in tank 241-AY-102, starting from a 100 CFM flow rate and the corresponding steady state hydrogen concentration based on the 100 CFM flow rate

Cross flow filtration of aqueous radioactive tank wastes

International Nuclear Information System (INIS)

McCabe, D.J.; Reynolds, B.A.; Todd, T.A.; Wilson, J.H.

1997-01-01

The Tank Focus Area (TFA) of the Department of Energy (DOE) Office of Science and Technology addresses remediation of radioactive waste currently stored in underground tanks. Baseline technologies for treatment of tank waste can be categorized into three types of solid liquid separation: (a) removal of radioactive species that have been absorbed or precipitated, (b) pretreatment, and (c) volume reduction of sludge and wash water. Solids formed from precipitation or absorption of radioactive ions require separation from the liquid phase to permit treatment of the liquid as Low Level Waste. This basic process is used for decontamination of tank waste at the Savannah River Site (SRS). Ion exchange of radioactive ions has been proposed for other tank wastes, requiring removal of insoluble solids to prevent bed fouling and downstream contamination. Additionally, volume reduction of washed sludge solids would reduce the tank space required for interim storage of High Level Wastes. The scope of this multi-site task is to evaluate the solid/liquid separations needed to permit treatment of tank wastes to accomplish these goals. Testing has emphasized cross now filtration with metal filters to pretreat tank wastes, due to tolerance of radiation and caustic

WASTE TANK SUMMARY REPORT FOR MONTH ENDING 01/2004

International Nuclear Information System (INIS)

HANLON, B.M.

2004-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 60 smaller miscellaneous underground storage tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of U.S. Department of Energy Order 435.1 (DOE-HQ, August 28,2001, Radioactive Waste Management, U.S. Department of Energy-Washington, D.C.) requiring the reporting of waste inventories and space utilization for the Hanford Site Tank Farm tanks

Material selection for Multi-Function Waste Tank Facility tanks

International Nuclear Information System (INIS)

Carlos, W.C.

1994-01-01

This report briefly summarizes the history of the materials selection for the US Department of Energy's high-level waste carbon steel storage tanks. It also provide an evaluation of the materials for the construction of new tanks at the Multi-Function Waste Tank Facility. The evaluation included a materials matrix that summarized the critical design, fabrication, construction, and corrosion resistance requirements; assessed each requirement; and cataloged the advantages and disadvantages of each material. This evaluation is based on the mission of the Multi-Function Waste Tank Facility. On the basis of the compositions of the wastes stored in Hanford waste tanks, it is recommended that tanks for the Multi-Function Waste Tank Facility be constructed of normalized ASME SA 516, Grade 70, carbon steel

Tank 241-C-108 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in Program Plan for the Resolution of Tank Vapor Issues (Osborne and Huckaby 1994). Tank 241-C-108 was vapor sampled in accordance with Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution (Osborne et al., 1994)

Tank 241-C-104 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-104 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-C-104 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Hanford Site Tank Waste Remediation System

International Nuclear Information System (INIS)

1993-05-01

The US Department of Energy's (DOE) Hanford Site in southeastern Washington State has the most diverse and largest amount of highly radioactive waste of any site in the US. High-level radioactive waste has been stored in large underground tanks since 1944. A Tank Waste Remediation System Program has been established within the DOE to safely manage and immobilize these wastes in anticipation of permanent disposal in a geologic repository. The Hanford Site Tank Waste Remediation System Waste Management 1993 Symposium Papers and Viewgraphs covered the following topics: Hanford Site Tank Waste Remediation System Overview; Tank Waste Retrieval Issues and Options for their Resolution; Tank Waste Pretreatment - Issues, Alternatives and Strategies for Resolution; Low-Level Waste Disposal - Grout Issue and Alternative Waste Form Technology; A Strategy for Resolving High-Priority Hanford Site Radioactive Waste Storage Tank Safety Issues; Tank Waste Chemistry - A New Understanding of Waste Aging; Recent Results from Characterization of Ferrocyanide Wastes at the Hanford Site; Resolving the Safety Issue for Radioactive Waste Tanks with High Organic Content; Technology to Support Hanford Site Tank Waste Remediation System Objectives

Calcination/dissolution testing for Hanford Site tank wastes

International Nuclear Information System (INIS)

Colby, S.A.; Delegard, C.H.; McLaughlin, D.F.; Danielson, M.J.

1994-07-01

Thermal treatment by calcination offers several benefits for the treatment of Hanford Site tank wastes, including the destruction of organics and ferrocyanides and an hydroxide fusion that permits the bulk of the mostly soluble nonradioactive constituents to be easily separated from the insoluble transuranic residue. Critical design parameters were tested, including: (1) calciner equipment design, (2) hydroxide fusion chemistry, and (3) equipment corrosion. A 2 gal/minute pilot plant processed a simulated Tank 101-SY waste and produced a free flowing 700 C molten calcine with an average calciner retention time of 20 minutes and >95% organic, nitrate, and nitrite destruction. Laboratory experiments using actual radioactive tank waste and the simulated waste pilot experiments indicate that 98 wt% of the calcine produced is soluble in water, leaving an insoluble transuranic fraction. All of the Hanford Site tank wastes can benefit from calcination/dissolution processing, contingent upon blending various tank waste types to ensure a target of 70 wt% sodium hydroxide/nitrate/nitrite fluxing agent. Finally, corrosion testing indicates that a jacketed nickel liner cooled to below 400 C would corrode <2 mil/year (0.05 mm/year) from molten calcine attack

Stabilization of In-Tank Residual Wastes and External-Tank Soil Contamination for the Hanford Tank Closure Program: Applications to the AX Tank Farm

Energy Technology Data Exchange (ETDEWEB)

Anderson, H.L.; Dwyer, B.P.; Ho, C.; Krumhansl, J.L.; McKeen, G.; Molecke, M.A.; Westrich, H.R.; Zhang, P.

1998-11-01

Technical support for the Hanford Tank Closure Program focused on evaluation of concepts for immobilization of residual contaminants in the Hanford AX tanks and underlying soils, and identification of cost-effective approaches to improve long-term performance of AX tank farm cIosure systems. Project objectives are to develop materials or engineered systems that would significantly reduce the radionuclide transport to the groundwater from AX tanks containing residual waste. We pursued several studies that, if implemented, would help achieve these goals. They include: (1) tank fill design to reduce water inilltration and potential interaction with residual waste; (2) development of in-tank getter materials that would specifically sorb or sequester radionuclides; (3) evaluation of grout emplacement under and around the tanks to prevent waste leakage during waste retrieval or to minimize water infiltration beneath the tanks; (4) development of getters that will chemically fix specific radionuclides in soils under tanks; and (5) geochemical and hydrologic modeling of waste-water-soil-grout interactions. These studies differ in scope from the reducing grout tank fill employed at the Savannah River Site in that our strategy improves upon tank fill design by providing redundancy in the barriers to radionuclide migration and by modification the hydrogeochemistry external to the tanks.

Tank characterization report for double-shell tank 241-AP-101. Revision 1

International Nuclear Information System (INIS)

Conner, J.M.

1997-01-01

One major function of the Tank Waste Remediation System (TWRS) is to characterize wastes m support of waste management and disposal activities at the Hanford Site. Analytical data from sampling and analysis and other available information about a tank are compiled and maintained in a tank characterization report (TCR). This report and its appendixes serve as the TCR for double-shell tank 241-AP-101. The objectives of this report are to use characterization data in response to technical issues associated with tank 241-AP-101 waste; and to provide a standard characterization of this waste in terms of a best-basis inventory estimate. Section 2.0 summarizes the response to technical issues, Section 3.0 provides the best-basis inventory estimate, and Section 4.0 makes recommendations about safety status and additional sampling needs. The appendixes contain supporting data and information. This report supported the requirements of the Hanford Federal Facility Agreement and Consent Order, Milestone M-44-05. The characterization information in this report originated from sample analyses and known historical sources. Appendix A provides historical information for tank 241-AP-101 including surveillance, information, records pertaining to waste transfers and tank operations, and expected tank contents derived from a model based upon process knowledge. Appendix B summarizes recent sampling events and historical sampling information. Tank 241-AP-101 was grab sampled in November 1995, when the tank contained 2,790 kL (737 kgal) of waste. An addition1034al 1,438 kL (380 kgal) of waste was received from tank 241-AW-106 in transfers on March 1996 and January 1997. This waste was the product of the 242-A Evaporator Campaign 95-1. Characterization information for the additional 1,438 kL (380 kgal) was obtained using grab sampling data from tank 241-AW-106 and a slurry sample from the evaporator. Appendix C reports on the statistical analysis and numerical manipulation of data used in

Technetium in alkaline, high-salt, radioactive tank waste supernate: Preliminary characterization and removal

International Nuclear Information System (INIS)

Blanchard, D.L. Jr.; Brown, G.N.; Conradson, S.D.

1997-01-01

This report describes the initial work conducted at Pacific Northwest National Laboratory to study technetium (Tc) removal from Hanford tank waste supernates and Tc oxidation state in the supernates. Filtered supernate samples from four tanks were studied: a composite double shell slurry feed (DSSF) consisting of 70% from Tank AW-101, 20% from AP-106, and 10% from AP-102; and three complexant concentrate (CC) wastes (Tanks AN-107, SY-101, ANS SY-103) that are distinguished by having a high concentration of organic complexants. The work included batch contacts of these waste samples with Reillex trademark-HPQ (anion exchanger from Reilly Industries) and ABEC 5000 (a sorbent from Eichrom Industries), materials designed to effectively remove Tc as pertechnetate from tank wastes. A short study of Tc analysis methods was completed. A preliminary identification of the oxidation state of non-pertechnetate species in the supernates was made by analyzing the technetium x-ray absorption spectra of four CC waste samples. Molybdenum (Mo) and rhenium (Re) spiked test solutions and simulants were tested with electrospray ionization-mass spectrometry to evaluate the feasibility of the technique for identifying Tc species in waste samples

Grout Placement and Property Evaluation for Closing Hanford High-Level Waste Tanks - Scale-Up Testing

International Nuclear Information System (INIS)

LANGTON, CHRISTINE

2003-01-01

Hanford has 149 single-shell high level waste (HLW) tanks that were constructed between 1943 and 1964. Many of these tanks have leaked or are suspected of leaking HLW into the soil above the ground water. Consequently, a major effort is ongoing to transfer the liquid portion of the waste to the 28 newer, double-shell tanks. Savannah River National Laboratory (SRNL) was tasked to develop grout formulations for the three-layer closure concept selected by CH2M HILL for closing Tank C-106. These grout formulations were also evaluated for use as fill materials in the next six tanks scheduled to be closed. The overall scope consisted of both bench-scale testing to confirm mix designs and scale-up testing to confirm placement properties. This report provides results of the scale-up testing for the three-phase tank closure strategy. It also contains information on grouts for equipment and riser filling. The three-phase fill strategy is summarized as follows: Phase I fill encapsulates and minimizes dispersion of the residual waste in the tank. This fill is referred to as the Stabilization Layer and consists of the Stabilization Grout. The Phase II fill provides structural stability to the tank system and prevents subsidence. It is referred to as the Structural Layer and consists of the Structural Grout. A final Phase III fill consists of a grout designed to provide protection against intrusion and is referred to as the Capping Layer or Capping Grout

Waste Tank Summary Report for Month Ending 04/30/2002

International Nuclear Information System (INIS)

HANLON, B.M.

2002-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 60 smaller miscellaneous underground storage tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US. Department of Energy Order 435.1 (DOE-HQ, August 28, 2001, Radioactive Waste Management, US. Department of Energy-Washington, D.C.) requiring the reporting of waste inventories and space utilization for the Hanford Site Tank Farm tanks

Tank Waste Remediation System Tank Waste Analysis Plan. FY 1995

International Nuclear Information System (INIS)

Haller, C.S.; Dove, T.H.

1994-01-01

This documents lays the groundwork for preparing the implementing the TWRS tank waste analysis planning and reporting for Fiscal Year 1995. This Tank Waste Characterization Plan meets the requirements specified in the Hanford Federal Facility Agreement and Consent Order, better known as the Tri-Party Agreement

Mass spectrometry analysis of tank wastes at the Hanford Site

International Nuclear Information System (INIS)

Campbell, J.A.; Mong, G.M.; Clauss, S.A.

1995-01-01

Twenty-five of the 177 high-level waste storage tanks at the Hanford Site in southeastern Washington are being watched closely because of the possibility that flammable gas mixtures may be produced from the mixed wastes contained in the storage tanks. One tank in particular, Tank 241-SY-101 (Tank 101-SY), has exhibited episodic releases of flammable gas mixtures since its final filling in the early 1980s. It has been postulated that the organic compounds present in the waste may be precursors to the production of hydrogen. Mass spectrometry has proven to be an invaluable tool for the identification of organic components in wastes from Tank 101-SY and C-103. A suite of physical and chemical analyses has been performed in support of activities directed toward the resolution of an Unresolved Safety Question concerning the potential for a floating organic layer in Hanford Waste Tank 241-C-103 to sustain a pool fire. The aqueous layer underlying the floating organic material was also analyzed for organic components

Ferrocyanide tank waste stability

International Nuclear Information System (INIS)

Fowler, K.D.

1993-01-01

Ferrocyanide wastes were generated at the Hanford Site during the mid to late 1950s as a result of efforts to create more tank space for the storage of high-level nuclear waste. The ferrocyanide process was developed to remove 137 CS from existing waste and newly generated waste that resulted from the recovery of valuable uranium in Hanford Site waste tanks. During the course of research associated with the ferrocyanide process, it was recognized that ferrocyanide materials, when mixed with sodium nitrate and/or sodium nitrite, were capable of violent exothermic reaction. This chemical reactivity became an issue in the 1980s, when safety issues associated with the storage of ferrocyanide wastes in Hanford Site tanks became prominent. These safety issues heightened in the late 1980s and led to the current scrutiny of the safety issues associated with these wastes, as well as current research and waste management programs. Testing to provide information on the nature of possible tank reactions is ongoing. This document supplements the information presented in Summary of Single-Shell Tank Waste Stability, WHC-EP-0347, March 1991 (Borsheim and Kirch 1991), which evaluated several issues. This supplement only considers information particular to ferrocyanide wastes

Hanford waste tank cone penetrometer

International Nuclear Information System (INIS)

Seda, R.Y.

1995-12-01

A new tool is being developed to characterize tank waste at the Hanford Reservation. This tool, known as the cone penetrometer, is capable of obtaining chemical and physical properties in situ. For the past 50 years, this tool has been used extensively in soil applications and now has been modified for usage in Hanford Underground Storage tanks. These modifications include development of new ''waste'' data models as well as hardware design changes to accommodate the hazardous and radioactive environment of the tanks. The modified cone penetrometer is scheduled to be deployed at Hanford by Fall 1996. At Hanford, the cone penetrometer will be used as an instrumented pipe which measures chemical and physical properties as it pushes through tank waste. Physical data, such as tank waste stratification and mechanical properties, is obtained through three sensors measuring tip pressure, sleeve friction and pore pressure. Chemical data, such as chemical speciation, is measured using a Raman spectroscopy sensor. The sensor package contains other instrumentation as well, including a tip and side temperature sensor, tank bottom detection and an inclinometer. Once the cone penetrometer has reached the bottom of the tank, a moisture probe will be inserted into the pipe. This probe is used to measure waste moisture content, water level, waste surface moisture and tank temperature. This paper discusses the development of this new measurement system. Data from the cone penetrometer will aid in the selection of sampling tools, waste tank retrieval process, and addressing various tank safety issues. This paper will explore various waste models as well as the challenges associated with tank environment

Waste Tank Vapor Program: Vapor space characterization of waste tank 241; C-102: Results from samples collected on August 23, 1994

International Nuclear Information System (INIS)

Klinger, G.S.; Clauss, T.W.; Ligotke, M.W.

1995-10-01

This document presents the details of the inorganic and organic analysis that was performed on samples from the headspace of Hanford waste tank 241-C-102. The results described were obtained to support the safety and toxicological evaluations. A summary of the results for the inorganic and organic analytes is included, as well as, a detailed description of the results which appears in the text

In-situ radiation measurements of the C1 and C2 waste storage tank vault

International Nuclear Information System (INIS)

Yong, L.K.; Womble, P.C.; Weems, L.D.

1996-09-01

In August of 1996, the Applied Radiation Measurements Department (ARMD) of the Waste Management and Remedial Action Division (WMRAD) at Oak Ridge National Laboratory (ORNL) was tasked with characterizing the radiation fields in the C 1 and C 2 Liquid Low Level Waste (LLLW) tank vault located at ORNL. These in-situ measurements were made to provide data for evaluating the potential radiological conditions for personnel working in or around the vault during future planned activities. This report describes the locations where measurements were made, the types of radiation detection instruments used, the methods employed, the problems encountered and resolved, and discusses the results obtained

Characterization of Solids in Residual Wastes from Single-Shell Tanks at the Hanford Site, Washington, USA - 9277

International Nuclear Information System (INIS)

Krupka, Kenneth M.; Cantrell, Kirk J.; Schaef, Herbert T.; Arey, Bruce W.; Heald, Steve M.; Deutsch, William J.; Lindberg, Michael J.

2009-01-01

Solid-phase characterization methods have been used in an ongoing study of residual wastes (i.e., waste remaining after final retrieval operations) from the underground single-shell storage tanks 241-C-103, 241-C-106, 241-C-202, 241-C-203, and 241-S-112 at the U.S. Department of Energy's Hanford Site in Washington State. The results of studies completed to date show significant variability in the compositions of those residual wastes and the compositions, morphologies, and crystallinities of the individual phases that make up these wastes. These differences undoubtedly result from the various waste types stored and transferred in and out each tank and the sluicing and retrieval operations used for waste retrieval. Our studies indicate that these residual wastes are chemically-complex assemblages of crystalline and amorphous solids that contain contaminants as discrete phases and/or co-precipitated within oxide phases. Depending on the specific tank, various solids (e.g., gibbsite; boehmite; dawsonite; cancrinite; Fe oxides such as hematite, goethite, and maghemite; rhodochrosite; lindbergite; whewellite; nitratine; and numerous amorphous or poorly crystalline phases) have been identified by X-ray diffraction and scanning electron microscopy/energy dispersive X-ray spectroscopy in residual wastes studied to date. Our studies also show that contact of residual wastes with Ca(OH)2- and CaCO3-saturated aqueous solutions, which were used as surrogates for the compositions of pore-fluid leachants derived from young and aged cements respectively, may alter the compositions of solid phases present in the contacted wastes. Fe oxides/hydroxides have been identified in all residual wastes studied to date. They occur in these wastes as discrete particles, particles intergrown within a matrix of other phases, and surface coatings on other particles or particle aggregates. These Fe oxides/hydroxides typically contain trace concentrations of other transition metals, such Cr, Mn

Radiological and toxicological calculations for AY-102 and C-106HEPA filters and pre-filters

International Nuclear Information System (INIS)

Simpson, T.R.; Van Vleet, R.J.

1997-01-01

The high heat content solids in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W-320. Once sluicing operations are underway, the state of these tanks will be transformed from 'unagitated' to 'agitated'. This means that the partition fraction which described the aerosol content of the head space will increase from 1 X 10 - 20 to 1 X 10 -1 . This head space will become much more loaded with suspended material. The nature of this suspended material may change significantly, sluicing may inadvertently bring up radioactive solids which normally would lay under many meters of liquid supernate. It is an enabling assumption that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split; there is an unmitigated and mitigated composition. It is an enabling assumption that the sluicing line; the headspace in Tank 241-C-106, and the filters in Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split; there is an unmitigated and mitigated composition

Tank waste remediation system baseline tank waste inventory estimates for fiscal year 1995

International Nuclear Information System (INIS)

Shelton, L.W.

1996-01-01

A set of tank-by-tank waste inventories is derived from historical waste models, flowsheet records, and analytical data to support the Tank Waste Remediation System flowsheet and retrieval sequence studies. Enabling assumptions and methodologies used to develop the inventories are discussed. These provisional inventories conform to previously established baseline inventories and are meant to serve as an interim basis until standardized inventory estimates are made available

Tank 241-C-108 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank 241-C-108 headspace gas and vapor samples were collected and analyzed to help determine the potential risks to tank farm workers due to fugitive emissions from the tank. The drivers and objectives of waste tank headspace sampling and analysis are discussed in open-quotes Program Plan for the Resolution of Tank Vapor Issues.close quotes Tank 241-C-108 was vapor sampled in accordance with open-quotes Data Quality Objectives for Generic In-Tank Health and Safety Issue Resolution.close quotes

Tank waste treatment science

International Nuclear Information System (INIS)

LaFemina, J.P.; Blanchard, D.L.; Bunker, B.C.; Colton, N.G.; Felmy, A.R.; Franz, J.A.; Liu, J.; Virden, J.W.

1994-01-01

Remediation efforts at the U.S. Department of Energy's Hanford Site require that many technical and scientific principles be combined for effectively managing and disposing the variety of wastes currently stored in underground tanks. Based on these principles, pretreatment technologies are being studied and developed to separate waste components and enable the most suitable treatment methods to be selected for final disposal of these wastes. The Tank Waste Treatment Science Task at Pacific Northwest Laboratory is addressing pretreatment technology development by investigating several aspects related to understanding and processing the tank contents. The experimental work includes evaluating the chemical and physical properties of the alkaline wastes, modeling sludge dissolution, and evaluating and designing ion exchange materials. This paper gives some examples of results of this work and shows how these results fit into the overall Hanford waste remediation activities. This work is part of series of projects being conducted for the Tank Waste Remediation System

Hanford site waste tank characterization

International Nuclear Information System (INIS)

De Lorenzo, D.S.; Simpson, B.C.

1994-08-01

This paper describes the on-going work in the characterization of the Hanford-Site high-level waste tanks. The waste in these tanks was produced as part of the nuclear weapons materials processing mission that occupied the Hanford Site for the first 40 years of its existence. Detailed and defensible characterization of the tank wastes is required to guide retrieval, pretreatment, and disposal technology development, to address waste stability and reactivity concerns, and to satisfy the compliance criteria for the various regulatory agencies overseeing activities at the Hanford Site. The resulting Tank Characterization Reports fulfill these needs, as well as satisfy the tank waste characterization milestones in the Hanford Federal Facility Agreement and Consent Order

Project W-320, 241-C-106 sluicing: Civil/structural calculations. Volume 6

Energy Technology Data Exchange (ETDEWEB)

Bailey, J.W.

1998-07-24

This supporting document has been prepared to make the FDNW calculations for Project W-320 readily retrievable. The purpose of this calculation is to conservatively estimate the weight of equipment and structures being added over Tank 241-C-106 as a result of Project W-320 and combine these weights with the estimated weights of existing structures and equipment as calculated in Attachment 1. The combined weights will be compared to the allowable live load limit to provide a preliminary assessment of loading conditions above Tank 241-C-106.

Type B Investigation Report for 241-SY-101 Pump Start and 241-C-106 Pit Cleanout

Energy Technology Data Exchange (ETDEWEB)

Ewalt, J.R.

1993-09-01

In accordance with the direction of the Department of Energy (DOE) Manager, Richland Operations Office, a Type ``B`` investigation in accordance with the DOE Order 5484.1, Environmental Protection, Safety and Health Protection Information Reporting Requirements, has been conducted. The scope of the investigation included two events: The ``Inadvertent Mixer Pump Operation at 241-SY-101`` (RL-WHC-TANK FARM-1993-069); ``Inadequate Work Control Results in Personnel Skin Contamination at 241-C-106, Pit B`` (RL-WHC-TANK FARM-1993-071) events. Additionally, at the request of the President of the WHC, a broader investigation into Waste Tank Farm ``safety practices`` and ``Conduct of Operations`` was also conducted. The review was focused on (1) WHC organizations performing operations, maintenance, and radiological safety tasks; and (2) KEH organizations performing major maintenance tasks.

A summary of available information on ferrocyanide tank wastes

International Nuclear Information System (INIS)

Burger, L.L.; Strachan, D.M.; Reynolds, D.A.; Schulz, W.W.

1991-10-01

Ferrocyanide wastes were generated at the Hanford site during the mid to late 1950s to make more tank space available for the storage of high level nuclear waste. The ferrocyanide process was developed as a method of removing 137 Cs from existing waste solutions and from process solutions that resulted from the recovery of valuable uranium in waste tanks. During the coarse of the research associated with the ferrocyanide process, it was discovered that ferrocyanide materials when mixed with NaNO 3 and/or NaNO 2 exploded. This chemical reactivity became an issue in the 1980s when the safety associated with the storage of ferrocyanide wastes in Hanford tanks became prominent. These safety issues heightened in the late 1980s and led to the current scrutiny of the safety associated with these wastes and the current research and waste management programs. Over the past three years, numerous explosive test have been carried out using milligram quantities of cyanide compounds. These tests provide information on the nature of possible tank reactions. On heating a mixture of ferrocyanide and nitrate or nitrite, an explosive reaction normally begins at about 240 degrees C, but may occur well below 200 degrees C in the presence of catalysts or organic compounds that may act as initiators. The energy released is highly dependent on the course of the reaction. Three attempts to model hot spots in local areas of the tanks indicate a very low probability of having a hot spot large enough and hot enough to be of concern. The main purpose of this document is to inform the members of the Tank Waste Science Panel of the background and issues associated with the ferrocyanide wastes. Hopefully, this document fulfills similar needs outside of the framework of the Tank Waste Science Panel. 50 refs., 9 figs., 7 tabs

METHODOLOGY AND CALCULATIONS FOR THE ASSIGNMENT OF WASTE GROUPS FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

Energy Technology Data Exchange (ETDEWEB)

WEBER RA

2009-01-16

The Hanford Site contains 177 large underground radioactive waste storage tanks (28 double-shell tanks and 149 single-shell tanks). These tanks are categorized into one of three waste groups (A, B, and C) based on their waste and tank characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement gas release event. Assignments of waste groups to the 177 double-shell tanks and single-shell tanks, as reported in this document, are based on a Monte Carlo analysis of three criteria. The first criterion is the headspace flammable gas concentration following release of retained gas. This criterion determines whether the tank contains sufficient retained gas such that the well-mixed headspace flammable gas concentration would reach 100% of the lower flammability limit if the entire tank's retained gas were released. If the volume of retained gas is not sufficient to reach 100% of the lower flammability limit, then flammable conditions cannot be reached and the tank is classified as a waste group C tank independent of the method the gas is released. The second criterion is the energy ratio and considers whether there is sufficient supernatant on top of the saturated solids such that gas-bearing solids have the potential energy required to break up the material and release gas. Tanks that are not waste group C tanks and that have an energy ratio < 3.0 do not have sufficient potential energy to break up material and release gas and are assigned to waste group B. These tanks are considered to represent a potential induced flammable gas release hazard, but no spontaneous buoyant displacement flammable gas release hazard. Tanks that are not waste group C tanks and have an energy ratio {ge} 3.0, but that pass the third criterion (buoyancy ratio < 1.0, see below) are also assigned to waste group B. Even though the designation as

METHODOLOGY AND CALCULATIONS FOR THE ASSIGNMENT OF WASTE GROUPS FOR THE LARGE UNDERGROUND WASTE STORAGE TANKS AT THE HANFORD SITE

Energy Technology Data Exchange (ETDEWEB)

FOWLER KD

2007-12-27

This document categorizes each of the large waste storage tanks into one of several categories based on each tank's waste characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement event. Revision 7 is the annual update of the calculations of the flammable gas Waste Groups for DSTs and SSTs. The Hanford Site contains 177 large underground radioactive waste storage tanks (28 double-shell tanks and 149 single-shell tanks). These tanks are categorized into one of three waste groups (A, B, and C) based on their waste and tank characteristics. These waste group assignments reflect a tank's propensity to retain a significant volume of flammable gases and the potential of the waste to release retained gas by a buoyant displacement gas release event. Assignments of waste groups to the 177 double-shell tanks and single-shell tanks, as reported in this document, are based on a Monte Carlo analysis of three criteria. The first criterion is the headspace flammable gas concentration following release of retained gas. This criterion determines whether the tank contains sufficient retained gas such that the well-mixed headspace flammable gas concentration would reach 100% of the lower flammability limit if the entire tank's retained gas were released. If the volume of retained gas is not sufficient to reach 100% of the lower flammability limit, then flammable conditions cannot be reached and the tank is classified as a waste group C tank independent of the method the gas is released. The second criterion is the energy ratio and considers whether there is sufficient supernatant on top of the saturated solids such that gas-bearing solids have the potential energy required to break up the material and release gas. Tanks that are not waste group C tanks and that have an energy ratio < 3.0 do not have sufficient

Waste Retrieval Sluicing System Campaign Number 3 Solids Volume Transferred Calculation

International Nuclear Information System (INIS)

CAROTHERS, K.G.

1999-01-01

Waste Retrieval Sluicing System (WRSS) operations at tank 241-C-106 began on Wednesday, November 18, 1998. The purpose of this system is to retrieve and transfer the high-heat sludge from the tank for storage in double-shell tank 241-AY-102, thereby resolving the high-heat safety issue for the tank, and to demonstrate modernized past-practice retrieval technology for single-shell tank waste. Performance Agreement (PA) TWR 1.2.2, C-106 Sluicing, was established by the Department of Energy, Office of River Protection (ORP) for achieving completion of sluicing retrieval of waste from tank 241-C-106 by September 30, 1999. This level of sludge removal is defined in the PA as either removal of approximately 72 inches of sludge or removal of 172,000 gallons of sludge (approximately 62 inches) and less than 6,000 gallons (approximately 2 inches) of sludge removal per 12 hour sluice batch for three consecutive batches. Preliminary calculations of the volume of tank 241-C-106 sludge removed as of September 29, 1999 were provided to ORP documenting completion of PA TWR 1.2.2 (Allen 1999a). The purpose of this calculation is to document the final sludge volume removed from tank 241-C-106 up through September 30, 1999. Additionally, the results of an extra batch completed October 6, 1999 is included to show the total volume of sludge removed through the end of WRSS operations. The calculation of the sludge volume transferred from the tank is guided by engineering procedure HNF-SD-WM-PROC-021, Section 15.0,Rev. 3, sub-section 4.4, ''Calculation of Sludge Transferred.''

Waste Retrieval Sluicing System Campaign Number 3 Solids Volume Transferred Calculation

International Nuclear Information System (INIS)

CAROTHERS, K.G.

1999-01-01

Waste Retrieval Sluicing System (WRSS) operations at tank 241-C-106 began on Wednesday, November 18,1998. The purpose of this system is to retrieve and transfer the high-heat sludge from the tank for storage in double-shell tank 241-AY-102, thereby resolving the high-heat safety issue for the tank, and to demonstrate modernized past-practice retrieval technology for single-shell tank waste. Performance Agreement (PA) TWR 1.2.2, C-106 Sluicing, was established by the Department of Energy, Office of River Protection (ORP) for achieving completion of sluicing retrieval of waste from tank 241-C-106 by September 30,1999. This level of sludge removal is defined in the PA as either removal of approximately 72 inches of sludge or removal of 172,000 gallons of sludge (approximately 62 inches) and less than 6,000 gallons (approximately 2 inches) of sludge removal per 12 hour sluice batch for three consecutive batches. Preliminary calculations of the volume of tank 241-C-106 sludge removed as of September 29, 1999 were provided to ORP documenting completion of PA TWR 1.2.2 (Allen 1999a). The purpose of this calculation is to document the final sludge volume removed from tank 241-C-106 up through September 30, 1999. Additionally, the results of an extra batch completed October 6, 1999 is included to show the total volume of sludge removed through the end of WRSS operations. The calculation of the sludge volume transferred from the tank is guided by engineering procedure HNF-SD-WM-PROC-021, Section 15.0,Rev. 3, sub-section 4.4, ''Calculation of Sludge Transferred.''

PHYSICAL CHARACTERIZATION OF VITREOUS STATE LABORATORY AY102/C106 AND AZ102 HIGH LEVEL WASTE MELTER FEED SIMULANTS (U)

Energy Technology Data Exchange (ETDEWEB)

Hansen, E

2005-03-31

The objective of this task is to characterize and report specified physical properties and pH of simulant high level waste (HLW) melter feeds (MF) processed through the scaled melters at Vitreous State Laboratories (VSL). The HLW MF simulants characterized are VSL AZ102 straight hydroxide melter feed, VSL AZ102 straight hydroxide rheology adjusted melter feed, VSL AY102/C106 straight hydroxide melter feed, VSL AY102/C106 straight hydroxide rheology adjusted melter feed, and Savannah River National Laboratory (SRNL) AY102/C106 precipitated hydroxide processed sludge blended with glass former chemicals at VSL to make melter feed. The physical properties and pH were characterized using the methods stated in the Waste Treatment Plant (WTP) characterization procedure (Ref. 7).

Tank 241-C-107 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-107. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Tank 241-C-102 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-102. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196 and RCRA Borehole 299-W11-39

International Nuclear Information System (INIS)

Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2004-01-01

contaminated boreholes around T-106 do not clearly identify the leading edge of the plume. However, the profiles do collectively suggest that bulk of tank-related fluids (center of mass) still resides in Ringold Formation Taylor Flats member fine-grained sediments. Most of the chemical data, especially the nitrate and technetium-99 distributions with depth, support a flow conceptual model that suggests vertical percolation through the Hanford formation H2 unit near T-106 and then a strong horizontal spreading within the CCUu unit followed by more slow vertical percolation, perhaps via diffusion, into the deeper strata. Slow flushing by enhanced recharge and rapid snow melt events (Feb. 1979) appear to lead to more horizontal movement of the tank fluids downgradient towards C4105. The inventories as a function of depth of potential contaminants of concern, nitrate, technetium, uranium, and chromium, are provided. In-situ Kd values were calculated from water and acid extract measurements. For conservative modeling purposes we recommend using Kd values of 0 mL/g for nitrate, Co-60, and technetium-99, a value of 0.1 mL/g for uranium near borehole C4104 and 10 mL/g for U near borehole C4105, and 1 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. A technetium-99 groundwater plume exists northeast and east of T WMA. The highest technetium-99 concentration in fiscal year 2003 was 9,200 pCi/L in well 299-W11-39. The most probable source for the technetium-99 is the T waste management area. Groundwater from wells in the west (upgradient) and north of WMA T appear to be highly influenced by wastes disposed to the cribs and trenches on the west side of the WMA. Groundwater from wells at the northeast corner and the east side of the WMA appears to be evolving towards tank waste that has leaked from T-101 or T-106

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196 and RCRA Borehole 299-W11-39

Energy Technology Data Exchange (ETDEWEB)

Serne, R JEFFREY.; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; LeGore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2004-09-01

contaminated boreholes around T-106 do not clearly identify the leading edge of the plume. However, the profiles do collectively suggest that bulk of tank-related fluids (center of mass) still resides in Ringold Formation Taylor Flats member fine-grained sediments. Most of the chemical data, especially the nitrate and technetium-99 distributions with depth, support a flow conceptual model that suggests vertical percolation through the Hanford formation H2 unit near T-106 and then a strong horizontal spreading within the CCUu unit followed by more slow vertical percolation, perhaps via diffusion, into the deeper strata. Slow flushing by enhanced recharge and rapid snow melt events (Feb. 1979) appear to lead to more horizontal movement of the tank fluids downgradient towards C4105. The inventories as a function of depth of potential contaminants of concern, nitrate, technetium, uranium, and chromium, are provided. In-situ Kd values were calculated from water and acid extract measurements. For conservative modeling purposes we recommend using Kd values of 0 mL/g for nitrate, Co-60, and technetium-99, a value of 0.1 mL/g for uranium near borehole C4104 and 10 mL/g for U near borehole C4105, and 1 mL/g for chromium to represent the entire vadose zone profile from the bottoms of the tanks to the water table. A technetium-99 groundwater plume exists northeast and east of T WMA. The highest technetium-99 concentration in fiscal year 2003 was 9,200 pCi/L in well 299-W11-39. The most probable source for the technetium-99 is the T waste management area. Groundwater from wells in the west (upgradient) and north of WMA T appear to be highly influenced by wastes disposed to the cribs and trenches on the west side of the WMA. Groundwater from wells at the northeast corner and the east side of the WMA appears to be evolving towards tank waste that has leaked from T-101 or T-106.

Acceptance test procedure, 241-SY-101/241-C-106 shot loading system

International Nuclear Information System (INIS)

Ostrom, M.J.

1994-01-01

This Acceptance Test Procedure is for the 241-SY-101/241-C-106 Shot Loading System. The procedure will test the components of the Shot Loading System and its capability of adequately loading shot into the annular space of the Container. The loaded shot will provide shielding as required for transporting and storage of a contaminated pump after removal from the tank. This test serves as verification that the SLS is acceptable for use in the pump removal operations for Tanks 241-SY-101, 241-C-106 and 241-AY-102. The pump removal operation for these three tanks will be performed by two different organizations with different equipment, but the Shot Loading System will be compatible between the two operations

Radiological and toxicological calculations for AY-102 and C-106HEPA filters and pre-filters

Energy Technology Data Exchange (ETDEWEB)

Simpson, T.R.; Van Vleet, R.J.

1997-07-01

The high heat content solids in Tank 241-C-106 are to be removed and transferred to Tank 241-AY-102 by sluicing operations, to be authorized under project W-320. Once sluicing operations are underway, the state of these tanks will be transformed from `unagitated` to `agitated`. This means that the partition fraction which described the aerosol content of the head space will increase from 1 X 10{sup - 20} to 1 X 10{sup -1}. This head space will become much more loaded with suspended material. The nature of this suspended material may change significantly, sluicing may inadvertently bring up radioactive solids which normally would lay under many meters of liquid supernate. It is an enabling assumption that the headspace and filter aerosols in Tank 241-AY-102 are a 90/10 liquid/solid split; there is an unmitigated and mitigated composition. It is an enabling assumption that the sluicing line; the headspace in Tank 241-C-106, and the filters in Tank 241-C-106 contain aerosols which are a 67/33 liquid/solid split; there is an unmitigated and mitigated composition.

Environmental Assessment: Waste Tank Safety Program, Hanford Site, Richland, Washington

International Nuclear Information System (INIS)

1994-02-01

The US Department of Energy (DOE) needs to take action in the near-term, to accelerate resolution of waste tank safety issues at the Hanford Site near the City of Richland, Washington, and reduce the risks associated with operations and management of the waste tanks. The DOE has conducted nuclear waste management operations at the Hanford Site for nearly 50 years. Operations have included storage of high-level nuclear waste in 177 underground storage tanks (UST), both in single-shell tank (SST) and double-shell tank configurations. Many of the tanks, and the equipment needed to operate them, are deteriorated. Sixty-seven SSTs are presumed to have leaked a total approximately 3,800,000 liters (1 million gallons) of radioactive waste to the soil. Safety issues associated with the waste have been identified, and include (1) flammable gas generation and episodic release; (2) ferrocyanide-containing wastes; (3) a floating organic solvent layer in Tank 241-C-103; (4) nuclear criticality; (5) toxic vapors; (6) infrastructure upgrades; and (7) interim stabilization of SSTs. Initial actions have been taken in all of these areas; however, much work remains before a full understanding of the tank waste behavior is achieved. The DOE needs to accelerate the resolution of tank safety concerns to reduce the risk of an unanticipated radioactive or chemical release to the environment, while continuing to manage the wastes safely

Tank waste remediation system: An update

International Nuclear Information System (INIS)

Alumkal, W.T.; Babad, H.; Dunford, G.L.; Honeyman, J.O.; Wodrich, D.D.

1995-02-01

The US Department of Energy's Hanford Site, located in southeastern Washington State, contains the largest amount and the most diverse collection of highly radioactive waste in the US. High-level radioactive waste has been stored at the Hanford Site in large, underground tanks since 1944. Approximately 217,000 M 3 (57 Mgal) of caustic liquids, slurries, saltcakes, and sludges have accumulated in 177 tanks. In addition, significant amounts of 90 Sr and 137 Cs were removed from the tank waste, converted to salts, doubly encapsulated in metal containers, and stored in water basins. The Tank Waste Remediation System Program was established by the US Department of Energy in 1991 to safely manage and immobilize these wastes in anticipation of permanent disposal of the high-level waste fraction in a geologic repository. Since 1991, significant progress has been made in resolving waste tank safety issues, upgrading Tank Farm facilities and operations, and developing a new strategy for retrieving, treating, and immobilizing the waste for disposal

Proposed plan for the Tank 105-C Hazardous Waste Management Facility. Revision 1

International Nuclear Information System (INIS)

Miles, W.C. Jr.

1994-01-01

This Proposed Plan was developed to describe the remedial action selected at the Tank 105-C Hazardous Waste Management Facility (HWMF) source-specific unit within the C-Area Fundamental Study Area (FSA) at the Savannah River Site (SRS) and to fulfill Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) requirements. This 8,400 gallon capacity tank was certified and accepted closed according to a closure plan approved by the state of South Carolina under the Resource Conservation and Recovery Act (RCRA) authority in January 1991. As a result of the closure, previously performed under RCRA, the unit poses no current or potential threat to human health or the environment. Accordingly, no further remedial action is necessary under CERCLA

Tank 241-C-101 vapor sampling and analysis tank characterization report

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

Tank C-101 headspace gas and vapor samples were collected and analyzed to help determine the potential risks of fugitive emissions to tank farm workers. Gas and vapor samples from the Tank C-101 headspace were collected on July 7, 1994 using the in situ sampling (ISS) method, and again on September 1, 1994 using the more robust vapor sampling system (VSS). Gas and vapor concentrations in Tank C-101 are influenced by its connections to other tanks and its ventilation pathways. At issue is whether the organic vapors in Tank C-101 are from the waste in that tank, or from Tanks C-102 or C-103. Tank C-103 is on the Organic Watch List; the other two are not. Air from the Tank C-101 headspace was withdrawn via a 7.9-m long heated sampling probe mounted in riser 8, and transferred via heated tubing to the VSS sampling manifold. The tank headspace temperature was determined to be 34.0 C, and all heated zones of the VSS were maintained at approximately 50 C. Sampling media were prepared and analyzed by WHC, Oak Ridge National Laboratories, Pacific Northwest Laboratories, and Oregon Graduate Institute of Science and Technology through a contract with Sandia National Laboratories. The 39 tank air samples and 2 ambient air control samples collected are listed in Table X-1 by analytical laboratory. Table X-1 also lists the 14 trip blanks and 2 field blanks provided by the laboratories

Waste retrieval sluicing system campaign number 1 solids volume transferred calculation

International Nuclear Information System (INIS)

BAILEY, J.W.

1999-01-01

This calculation has been prepared to document the volume of sludge removed from tank 241-C-106 during Waste Retrieval Sluicing System (WRSS) Sluicing Campaign No.1. This calculation will be updated, if necessary, to incorporate new data. This calculation supports the declaration of completion of WRSS Campaign No.1 and, as such, is also the documentation for completion of Performance Agreement TWR 1.2.1 , C-106 Sluicing Performance Expectations. It documents the performance of all the appropriate tank 241-C-106 mass transfer verifications, evaluations, and appropriate adjustments discussed in HNF-SD-WM-PROC-021, Chapter 23, ''Process Engineering Calculations for Tank 241-C-106 Sluicing and Retrieval''

Waste retrieval sluicing system campaign number 1 solids volume transferred calculation

International Nuclear Information System (INIS)

BAILEY, J.W.

1999-01-01

This calculation has been prepared to document the volume of sludge removed from tank 241-C-106 during Waste Retrieval Sluicing System (WRSS) Sluicing Campaign No.1. This calculation will be updated, if necessary, to incorporate new data. This calculation supports the declaration of completion of WRSS Campaign No.1 and, as such, is also the documentation for completion of Performance Agreement TWR 1.2.1 C-106 Sluicing Performance Expectations. It documents the performance of all the appropriate tank 241-C-106 mass transfer verifications, evaluations, and appropriate adjustments discussed in HNF-SD-WM-PROC-021, Chapter 23, ''Process Engineering Calculations for Tank 241-C-106 Sluicing and Retrieval''

Waste Tank Safety Screening Module: An aspect of Hanford Site tank waste characterization

International Nuclear Information System (INIS)

Hill, J.G.; Wood, T.W.; Babad, H.; Redus, K.S.

1994-01-01

Forty-five (45) of the 149 Hanford single-shell tanks have been designated as Watch-List tanks for one or more high-priority safety issues, which include significant concentrations of organic materials, ferrocyanide salts, potential generation of flammable gases, high heat generation, criticality, and noxious vapor generation. While limited waste characterization data have been acquired on these wastes under the original Tri-Party Agreement, to date all of the tank-by-tank assessments involved in these safety issue designations have been based on historical data rather than waste on data. In response to guidance from the Defense Nuclear Facilities Safety Board (DNFSB finding 93-05) and related direction from the US Department of Energy (DOE), Westinghouse Hanford Company, assisted by Pacific Northwest Laboratory, designed a measurements-based screening program to screen all single-shell tanks for all of these issues. This program, designated the Tank Safety Screening Module (TSSM), consists of a regime of core, supernatant, and auger samples and associated analytical measurements intended to make first-order discriminations of the safety status on a tank-by-tank basis. The TSSM combines limited tank sampling and analysis with monitoring and tank history to provide an enhanced measurement-based categorization of the tanks relative to the safety issues. This program will be implemented beginning in fiscal year (FY) 1994 and supplemented by more detailed characterization studies designed to support safety issue resolution

Waste Tank Organic Safety Program: Analytical methods development. Progress report, FY 1994

International Nuclear Information System (INIS)

Campbell, J.A.; Clauss, S.A.; Grant, K.E.

1994-09-01

The objectives of this task are to develop and document extraction and analysis methods for organics in waste tanks, and to extend these methods to the analysis of actual core samples to support the Waste Tank organic Safety Program. This report documents progress at Pacific Northwest Laboratory (a) during FY 1994 on methods development, the analysis of waste from Tank 241-C-103 (Tank C-103) and T-111, and the transfer of documented, developed analytical methods to personnel in the Analytical Chemistry Laboratory (ACL) and 222-S laboratory. This report is intended as an annual report, not a completed work

Test plan for tank 241-C-104 retrieval testing

International Nuclear Information System (INIS)

HERTING, D.L.

1999-01-01

Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document

Test Plan for Tank 241-C-104 Retrieval Testing

International Nuclear Information System (INIS)

HERTING, D.L.

1999-01-01

Tank 241-C-104 has been identified as one of the first tanks to be retrieved for high-level waste pretreatment and immobilization. Retrieval of the tank waste will require dilution. Laboratory tests are needed to determine the amount of dilution required for safe retrieval and transfer of feed. The proposed laboratory tests are described in this document

Results Of Physicochemical Characterization And Caustic Dissolution Tests On Tank 241-C-108 Heel Solids

International Nuclear Information System (INIS)

Callaway, W.S.; Huber, H.J.

2010-01-01

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

RESULTS OF PHYSICOCHEMICAL CHARACTERIZATION AND CAUSTIC DISSOLUTION TESTS ON TANK 241-C-108 HEEL SOLIDS

Energy Technology Data Exchange (ETDEWEB)

CALLAWAY WS; HUBER HJ

2010-07-01

Based on an ENRAF waste surface measurement taken February 1, 2009, double-shell tank (DST) 241-AN-106 (AN-106) contained approximately 278.98 inches (793 kgal) of waste. A zip cord measurement from the tank on February 1, 2009, indicated a settled solids layer of 91.7 inches in height (280 kgal). The supernatant layer in February 2009, by difference, was approximately 187 inches deep (514 kgal). Laboratory results from AN-106 February 1, 2009 (see Table 2) grab samples indicated the supernatant was below the chemistry limit that applied at the time as identified in HNF-SD-WM-TSR-006, Tank Farms Technical Safety Requirements, Administrative Control (AC) 5.16, 'Corrosion Mitigation Controls.' (The limits have since been removed from the Technical Safety Requirements (TSR) and are captured in OSD-T-151-00007, Operating Specifications for the Double-Shell Storage Tanks.) Problem evaluation request WRPS-PER-2009-0218 was submitted February 9, 2009, to document the finding that the supernatant chemistry for grab samples taken from the middle and upper regions of the supernatant was noncompliant with the chemistry control limits. The lab results for the samples taken from the bottom region of the supernatant met AC 5.16 limits.

Vapor space characterization of waste tank 241-C-101: Results from samples collected on 9/1/94

International Nuclear Information System (INIS)

Lucke, R.B.; Clauss, T.W.; Ligotke, M.W.

1995-11-01

This report describes results of the analyses of tank-headspace samples taken from the Hanford waste Tank 241-C-101 (referred to as Tank C-101) and the ambient air collected - 30 ft upwind near the tank and through the VSS near the tank. Pacific Northwest Laboratory (PNL) contracted with Westinghouse Hanford Company (WHC) to provide sampling devices and to analyze inorganic and organic analytes collected from the tank headspace and ambient air near the tank. The sample job was designated S4056, and samples were collected by WHC on September 1, 1994, using the vapor sampling system (VSS). The samples were inspected upon delivery to the 326/23B laboratory and logged into PNL record book 55408 before implementation of PNL Technical Procedure PNL-TVP-07. Custody of the sorbent traps was transferred to PNL personnel performing the inorganic analysis and stored at refrigerated (≤ 10 degrees C) temperature until the time of analysis. The canisters were stored in the 326/23B laboratory at ambient (25 degrees C) temperature until the time of the analysis. Access to the 326/23B laboratory is limited to PNL personnel working on the waste-tank safety program. Analyses described in this report were performed at PNL in the 300 area of the Hanford Reservation. Analytical methods that were used are described in the text. In summary, sorbent traps for inorganic analyses containing sample materials were either weighed (for water analysis) or desorbed with the appropriate aqueous solutions (for NH 3 , NO 2 , and NO analyses). The aqueous extracts were analyzed either by selective electrode or by ion chromatography (IC). Organic analyses were performed using cryogenic preconcentration followed by gas chromatography/mass spectrometry (GC/MS)

Waste acceptance and waste loading for vitrified Oak Ridge tank waste

International Nuclear Information System (INIS)

Harbour, J.R.; Andrews, M.K.

1997-01-01

The Office of Science and Technology of the DOE has funded a joint project between the Oak Ridge National Laboratory (ORNL) and the Savannah River Technology Center (SRTC) to evaluate vitrification and grouting for the immobilization of sludge from ORNL tank farms. The radioactive waste is from the Gunite and Associated Tanks (GAAT), the Melton Valley Storage Tanks (MVST), the Bethel Valley Evaporator Service Tanks (BVEST), and the Old Hydrofractgure Tanks (OHF). Glass formulation development for sludge from these tanks is discussed in an accompanying article for this conference (Andrews and Workman). The sludges contain transuranic radionuclides at levels which will make the glass waste form (at reasonable waste loadings) TRU. Therefore, one of the objectives for this project was to ensure that the vitrified waste form could be disposed of at the Waste Isolation Pilot Plant (WIPP). In order to accomplish this, the waste form must meet the WIPP Waste Acceptance Criteria (WAC). An alternate pathway is to send the glass waste forms for disposal at the Nevada Test Site (NTS). A sludge waste loading in the feed of 6 wt percent will lead to a waste form which is non-TRU and could potentially be disposed of at NTS. The waste forms would then have to meet the requirements of the NTS WAC. This paper presents SRTC''s efforts at demonstrating that the glass waste form produced as a result of vitrification of ORNL sludge will meet all the criteria of the WIPP WAC or NTS WAC

Single-Shell Tank (SST) Retrieval Project Plan for Tank 241-C-104 Retrieval

International Nuclear Information System (INIS)

DEFIGH PRICE, C.

2000-01-01

In support of the SST Interim Closure Project, Project W-523 ''Tank 241-C-104 Waste Retrieval System'' will provide systems for retrieval and transfer of radioactive waste from tank 241-C-104 (C-104) to the DST staging tank 241-AY-101 (AY-101). At the conclusion of Project W-523, a retrieval system will have been designed and tested to meet the requirements for Acceptance of Beneficial Use and been turned over to operations. Completion of construction and operations of the C-104 retrieval system will meet the recently proposed near-term Tri-Party Agreement milestone, M-45-03F (Proposed Tri-Party Agreement change request M-45-00-01A, August, 30 2000) for demonstrating limits of retrieval technologies on sludge and hard heels in SSTs, reduce near-term storage risks associated with aging SSTs, and provide feed for the tank waste treatment plant. This Project Plan documents the methodology for managing Project W-523; formalizes responsibilities; identifies key interfaces required to complete the retrieval action; establishes the technical, cost, and schedule baselines; and identifies project organizational requirements pertaining to the engineering process such as environmental, safety, quality assurance, change control, design verification, testing, and operational turnover

Low temperature hydrothermal destruction of organics in Hanford tank wastes

International Nuclear Information System (INIS)

Orth, R.J.; Elmore, M.R.; Zacher, A.H.; Neuenschwander, G.G.; Schmidt, A.J.; Jones, E.O.; Hart, T.R.; Poshusta, J.C.

1994-08-01

The objective of this work is to evaluate and develop a low temperature hydrothermal process (HTP) for the destruction of organics that are present wastes temporarily stored in underground tanks at the Hanford Site. Organic compounds contribute to tank waste safety issues, such as hydrogen generation. Some organic compounds act as complexants, promoting the solubility of radioactive constituents such as 90 Sr and 241 Am, which is undesirable for waste pretreatment processing. HTP is thermal-chemical autogenous processing method that is typically operated between 250 degrees C and 375 degrees C and approximately 200 atm. Testing with simulated tank waste, containing a variety of organics has been performed. The distribution of strontium, cesium and bulk metals between the supernatant and solid phases as a function of the total organic content of the waste simulant will be presented. Test results using simulant will be compared with similar tests conducted using actual radioactive waste

Flammable gas tank waste level reconciliation tank 241-SX-105

International Nuclear Information System (INIS)

Brevick, C.H.; Gaddie, L.A.

1997-01-01

Fluor Daniel Northwest was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 241-SX-105 (SX-105, typical). The trapped gas evaluation document states that Tank SX-105 exceeds the 25% of the lower flammable limit criterion, based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the Welty Report is the basis for this letter report. The Welty Report is also a part of the trapped gas evaluation document criteria. The Welty Report contains various tank information, including: physical information, status, levels, and dry wells. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unaccounted for surface level rise. From 1973 through 1980, the Welty Report tracked Tank SX-105 transfers and reported a net cumulative change of 20.75 in. This surface level increase is from an unknown source or is unaccounted for. Duke Engineering and Services Hanford and Lockheed Martin Hanford Corporation are interested in determining the validity of unexplained surface level changes reported in the Welty Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unaccounted for surface level changes as shown in the Welty Report from 1973 through 1980. Tank SX-105 initially received waste from REDOX starting the second quarter of 1955. After June 1975, the tank primarily received processed waste (slurry) from the 242-S Evaporator/Crystallizer and transferred supernate waste to Tanks S-102 and SX-102. The Welty Report shows a cumulative change of 20.75 in. from June 1973 through December 1980

Effect of viscosity on seismic response of waste storage tanks

International Nuclear Information System (INIS)

Tang, Yu; Uras, R.A.; Chang, Yao-Wen.

1992-06-01

The dynamic response of liquid-storage tanks subjected to harmonic excitations and earthquake ground motions has been studied. A rigid tank of negligible mass, rigidly supported at the base having a diameter of 50 ft. and fluid height of 20.4 ft. was used in the computer analysis. The liquid is assumed to have a density of 1.5 g/ml. Viscosity values, μ = 60, 200, 100, and 10,000 cP, were used in the numerical analyses to study the effects of viscosity on sloshing wave height, impulsive and convective pressure on the tank wall, base shear and base moments. Harmonic excitations as well as earthquake ground motions were used as input motions. The harmonic excitations used in the analyses covers a wide range of frequencies, including both the resonant and non-resonant frequencies. Two earthquake motions were used. One matches the Newmark-Hall median response spectrum and is anchored at 0.24 g for a rock site with a damping of 2% and a time duration of 10 s. The other is the 1978 Tabas earthquake which had a peak ZPA of 0.81 g and a time duration of 29 s. A small tank, about 1/15 the size of the typical waste storage tank, was used in the harmonic excitation study to investigate the effect of viscosity on the response of liquid-storage tanks and how the viscosity effect is affected by the size of the storage tank. The results of this study show that for the typical waste storage tank subjected to earthquake motions, the effect of viscosity on sloshing wave height and impulsive and convective pressures is very small and can be neglected. For viscosity effect to become noticeable in the response of the typical waste storage tank, the waste viscosity must be greater than 10,000 cP. This value is far greater than the estimated viscosity value of the high level wastes, which may range from 60 to 200 cP for some tanks

Hanford Site Tank 241-C-108 Residual Waste Contaminant Release Models and Supporting Data

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Arey, Bruce W.; Schaef, Herbert T.

2010-06-18

This report presents the results of laboratory characterization, testing, and analysis for a composite sample (designated 20578) of residual waste collected from single-shell tank C-108 during the waste retrieval process after modified sluicing. These studies were completed to characterize concentration and form of contaminant of interest in the residual waste; assess the leachability of contaminants from the solids; and develop release models for contaminants of interest. Because modified sluicing did not achieve 99% removal of the waste, it is expected that additional retrieval processing will take place. As a result, the sample analyzed here is not expected to represent final retrieval sample.

Strategy plan for management of Hanford tank wastes

International Nuclear Information System (INIS)

Humphreys, L.L.; Morgan, S.R.

1993-01-01

The Secretary of Energy in 1992 directed Hanford to plan for the retrieval and processing of all stored high level waste at Hanford for disposal at an offsite repository. This substantial change in the tank disposal program's assignment has resulted in a reevaluation of the entire Tank Waste Remediation System (TWRS) strategy. This strategic plan covers that portion of the TWRS strategy related to management of stored tank waste until it is retrieved, processed, and disposed by the disposal program and covers the responsibilities assigned to the ''manage tank waste'' function. The ''manage tank waste'' function is one of the level 2 functions as set forth in the Tank Waste Remediation System Mission Analysis Report (Baynes et al. 1993) and depicted in Figure 1. The following level 3 functions have been developed below the level 2, ''manage tank waste'' function: (1) Store waste; (2) Transfer waste; (3) Characterize, surveil and monitor waste; (4) Restore and upgrade systems; (5) Manage tank waste management system

Tank 241-C-111 vapor sampling and analysis tank characterization report. Revision 1

International Nuclear Information System (INIS)

Huckaby, J.L.

1995-01-01

This report presents the details of the Hanford waste tank characterization study for tank 241-C-111. The drivers and objectives of the headspace vapor sampling and analysis were in accordance with procedures that were presented in other reports. The vapor and headspace gas samples were collected and analyzed to determine the potential risks to tank farm workers due to fugitive emissions from the tank

C-tank transfers: Transuranic sludge removal from the C-1, C-2, and W-23 waste storage tanks at Oak Ridge National Laboratory, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

Dahl, T.L.; Lay, A.C.; Taylor, S.A.; Moore, J.W.

1999-01-01

Two fluidic pulse jet mixing systems were used to successfully mobilize remote-handled transuranic sludge for retrieval from three 50,000-gal horizontal waste storage tanks at Oak Ridge National Laboratory (ORNL). The results of this operation indicate that the pulse jet system should be considered for mixing and bulk retrieval of sludges in other vertical and horizontal waste tanks at ORNL and at other U.S. Department of Energy sites

Tank 24-C-103 headspace flammability

International Nuclear Information System (INIS)

Huckaby, J.L.

1994-05-01

Information regarding flammable vapors, gases, and aerosols is presented and interpreted to help resolve the tank 241-C-103 headspace flammability issue. Analyses of recent vapor and liquid samples, as well as visual inspections of the tank headspace, are discussed in the context of tank dynamics. Concern that the headspace of tank 241-C-103 may contain a flammable mixture of organic vapors and an aerosol of combustible organic liquid droplets arises from the presence of a layer of organic liquid in the tank. This organic liquid is believed to have originated in the plutonium-uranium extraction (PUREX) process, having been stored initially in tank 241-C-102 and apparently transferred to tank 241-C-103 in 1975 (Carothers 1988). Analyses of samples of the organic liquid collected in 1991 and 1993 indicate that the primary constituents are tributyl phosphate (TBP) and several semivolatile hydrocarbons (Prentice 1991, Pool and Bean 1994). This is consistent with the premise that the organic waste came from the PUREX process, because the PUREX process used a solution of TBP in a diluent composed of the n-C 11 H 24 to n-C 15 H 32 normal paraffinic hydrocarbons (NPH)

Screening for organic solvents in Hanford waste tanks using organic vapor concentrations

International Nuclear Information System (INIS)

Huckaby, J.L.; Sklarew, D.S.

1997-09-01

The potential ignition of organic liquids stored in the Hanford Site high-level radioactive waste tanks has been identified as a safety issue because expanding gases could potentially affect tank dome integrity. Organic liquid waste has been found in some of the waste tanks, but most are thought to contain only trace amounts. Due to the inhomogeneity of the waste, direct sampling of the tank waste to locate organic liquids may not conclusively demonstrate that a given tank is free of risk. However, organic vapors present above the organic liquid waste can be detected with a high degree of confidence and can be used to identify problem tanks. This report presents the results of a screening test that has been applied to 82 passively ventilated high-level radioactive waste tanks at the Hanford Site to identify those that might contain a significant amount of organic liquid waste. It includes seven tanks not addressed in the previous version of this report, Screening for Organic Solvents in Hanford Waste Tanks Using Total Non-Methane Organic Compound Vapor Concentrations. The screening test is based on a simple model of the tank headspace that estimates the effective surface area of semivolatile organic liquid waste in a tank. Analyses indicate that damage to the tank dome is credible only if the organic liquid burn rate is above a threshold value, and this can occur only if the surface area of organic liquid in a tank is above a corresponding threshold value of about one square meter. Thirteen tanks were identified as potentially containing at least that amount of semivolatile organic liquid based on conservative estimates. Most of the tanks identified as containing potentially significant quantities of organic liquid waste are in the 241-BY and 241-C tank farms, which agrees qualitatively with the fact that these tank farms received the majority of the PUREX process organic wash waste and waste organic liquids

Enhanced Waste Tank Level Model

Energy Technology Data Exchange (ETDEWEB)

Duignan, M.R.

1999-06-24

'With the increased sensitivity of waste-level measurements in the H-Area Tanks and with periods of isolation, when no mass transfer occurred for certain tanks, waste-level changes have been recorded with are unexplained.'

Tank Vapor Characterization Project: Headspace vapor characterization of Hanford Waste Tank 241-C-204: Results from samples collected on 07/02/96

International Nuclear Information System (INIS)

Thomas, B.L.; Evans, J.C.; Pool, K.H.

1997-01-01

This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-C-204 (Tank C-204) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNNL. Analyte concentrations were based on analytical results and, where appropriate, sample volumes provided by WHC. A summary of the inorganic analytes, permanent gases, and total non-methane organic compounds is listed in Table S.1. The three highest concentration analytes detected in SUMMA trademark canister and triple sorbent trap samples are also listed in Table S.1. Detailed descriptions of the analytical results appear in the appendices

Organic analysis of the headspace in Hanford waste tanks

International Nuclear Information System (INIS)

Lucke, R.B.; McVeety, B.D.; Clauss, T.W.; Fruchter, J.S.; Goheen, S.C.

1994-01-01

Before radioactive mixed waste in Hanford waste tanks can be isolated and permanently stored, several safety issues need to be addressed. The headspace vapors in Hanford Tank 103-C raise two issues: (1) the potential flammability of the vapor and aerosol, and (2) the potential worker health and safety hazards associated with the toxicity of the constituents. As a result, the authors have implemented organic analysis methods to characterize the headspace vapors in Hanford waste tanks. To address the flammability issue, they have used OSHA versatile sampling (OVS) tubes as the sampling method followed by solvent extraction and GC/MS analysis. For analyzing volatile organics and organic air toxins, they have implemented SUMMA trademark canisters as the collection device followed by cryogenic trapping and GC/MS analysis. Strategies for modifying existing NIOSH and EPA methods to make them applicable to vapors in Hanford waste tanks are discussed. Identification and quantification results of volatile and semivolatile organics are presented

Contaminant Release from Residual Waste in Closed Single-Shell Tanks and Other Waste Forms Associated with the Tanks

International Nuclear Information System (INIS)

Deutsch, William J.

2008-01-01

This chapter describes the release of contaminants from the various waste forms that are anticipated to be associated with closure of the single-shell tanks. These waste forms include residual sludge or saltcake that will remain in the tanks after waste retrieval. Other waste forms include engineered glass and cementitious materials as well as contaminated soil impacted by previous tank leaks. This chapter also describes laboratory testing to quantify contaminant release and how the release data are used in performance/risk assessments for the tank waste management units and the onsite waste disposal facilities. The chapter ends with a discussion of the surprises and lessons learned to date from the testing of waste materials and the development of contaminant release models

Hanford Tank 241-S-112 Residual Waste Composition and Leach Test Data

Energy Technology Data Exchange (ETDEWEB)

Cantrell, Kirk J.; Krupka, Kenneth M.; Geiszler, Keith N.; Lindberg, Michael J.; Arey, Bruce W.; Schaef, Herbert T.

2008-08-29

This report presents the results of laboratory characterization and testing of two samples (designated 20406 and 20407) of residual waste collected from tank S-112 after final waste retrieval. These studies were completed to characterize the residual waste and assess the leachability of contami¬nants from the solids. This is the first report from this PNNL project to describe the composition and leach test data for residual waste from a salt cake tank. All previous PNNL reports (Cantrell et al. 2008; Deutsch et al. 2006, 2007a, 2007b, 2007c) describing contaminant release models, and characterization and testing results for residual waste in single-shell tanks were based on samples from sludge tanks.

Ferrocyanide Safety Program: Thermal analysis of Tank 241-BY-106

International Nuclear Information System (INIS)

McLaren, J.M.

1993-05-01

An analysis was conducted of tank 241-BY-106 to determine the conditions required for an uneven distribution of heat generation (e.g., a hotspot) that would produce temperatures of concern (considered to be 220 degree C [418 degree F]). Two types of hotspots were investigated. One was 1 meter square, 7.62 cm (3 in.) thick, that was placed on the bottom of the tank two-thirds of the radial distance from the center to the edge of the tank. The other was a 1 meter cube placed in the same location. It was found that the concentrations of heat-producing material required to reach a maximum temperature of 220 degree C (418 degree F) were greater than 160 times that of the material surrounding the hotspot. A transient case was also studied, where a hotspot was formed over 5 years. The 1 meter cube hotspot was used. It was determined that the maximum temperature reached was less than the steady-state analysis under the same conditions. The maximum temperature was reached in 5.5 years. The change in the surface temperature was slow enough that the hotspot could not be detected in less than 3 years. The steady-state analysis showed that a large pattern of thermocouple trees would be required to detect a hotspot by this means. The steady-state analysis showed that a hotspot with temperatures that approached 220 degree C (418 degree F) could probably be detected by surface temperature measurements

Tank 241-AP-106, Grab samples, 6AP-98-1, 6AP-98-2 and 6AP-98-3 Analytical results for the final report

Energy Technology Data Exchange (ETDEWEB)

FULLER, R.K.

1999-02-23

This document is the final report for tank 241-AP-106 grab samples. Three grab samples 6AP-98-1, 6AP-98-2 and 6AP-98-3 were taken from riser 1 of tank 241-AP-106 on May 28, 1998 and received by the 222-S Laboratory on May 28, 1998. Analyses were performed in accordance with the ''Compatability Grab Sampling and Analysis Plan'' (TSAP) (Sasaki, 1998) and the ''Data Quality Objectives for Tank Farms Waste Compatability Program (DQO). The analytical results are presented in the data summary report. No notification limits were exceeded. The request for sample analysis received for AP-106 indicated that the samples were polychlorinated biphenyl (PCB) suspects. The results of this analysis indicated that no PCBs were present at the Toxic Substance Control Act (TSCA) regulated limit of 50 ppm. The results and raw data for the PCB analysis are included in this document.

Tank 241-AP-106, Grab samples, 6AP-98-1, 6AP-98-2 and 6AP-98-3 Analytical results for the final report

International Nuclear Information System (INIS)

FULLER, R.K.

1999-01-01

This document is the final report for tank 241-AP-106 grab samples. Three grab samples 6AP-98-1, 6AP-98-2 and 6AP-98-3 were taken from riser 1 of tank 241-AP-106 on May 28, 1998 and received by the 222-S Laboratory on May 28, 1998. Analyses were performed in accordance with the ''Compatability Grab Sampling and Analysis Plan'' (TSAP) (Sasaki, 1998) and the ''Data Quality Objectives for Tank Farms Waste Compatability Program (DQO). The analytical results are presented in the data summary report. No notification limits were exceeded. The request for sample analysis received for AP-106 indicated that the samples were polychlorinated biphenyl (PCB) suspects. The results of this analysis indicated that no PCBs were present at the Toxic Substance Control Act (TSCA) regulated limit of 50 ppm. The results and raw data for the PCB analysis are included in this document

Waste Tank Organic Safety Project: Analysis of liquid samples from Hanford waste tank 241-C-103

International Nuclear Information System (INIS)

Pool, K.H.; Bean, R.M.

1994-03-01

A suite of physical and chemical analyses has been performed in support of activities directed toward the resolution of an Unreviewed Safety Question concerning the potential for a floating organic layer in Hanford waste tank 241-C-103 to sustain a pool fire. The analysis program was the result of a Data Quality Objectives exercise conducted jointly with staff from Westinghouse Hanford Company and Pacific Northwest Laboratory (PNL). The organic layer has been analyzed for flash point, organic composition including volatile organics, inorganic anions and cations, radionuclides, and other physical and chemical parameters needed for a safety assessment leading to the resolution of the Unreviewed Safety Question. The aqueous layer underlying the floating organic material was also analyzed for inorganic, organic, and radionuclide composition, as well as other physical and chemical properties. This work was conducted to PNL Quality Assurance impact level III standards (Good Laboratory Practices)

Tank waste remediation system dangerous waste training plan

International Nuclear Information System (INIS)

POHTO, R.E.

1999-01-01

This document outlines the dangerous waste training program developed and implemented for all Treatment, Storage, and Disposal (TSD) Units operated by Lockheed Martin Hanford Corporation (LMHC) Tank Waste Remediation System (TWRS) in the Hanford 200 East, 200 West and 600 Areas and the <90 Day Accumulation Area at 209E. Operating TSD Units operated by TWRS are: the Double-Shell Tank (DST) System (including 204-AR Waste Transfer Building), the 600 Area Purgewater Storage and the Effluent Treatment Facility. TSD Units undergoing closure are: the Single-Shell Tank (SST) System, 207-A South Retention Basin, and the 216-B-63 Trench

High-heat tank safety issue resolution program plan. Revision 2

International Nuclear Information System (INIS)

Wang, O.S.

1994-12-01

The purpose of this program plan is to provide a guide for selecting corrective actions that will mitigate and/or remediate the high-heat waste tank safety issue for single-shell tank 241-C-106. The heat source of approximately 110,000 Btu/hr is the radioactive decay of the stored waste material (primarily 90 Sr) inadvertently transferred into the tank in the later 1960s. Currently, forced ventilation, with added water to promote thermal conductivity and evaporation cooling, is used for heat removal. The method is very effective and economical. At this time, the only viable solution identified to permanently resolve this safety issue is the removal of heat-generating waste in the tank. This solution is being aggressively pursued as the only remediation method to this safety issue, and tank 241-C-106 has been selected as the first single-shell tank for retrieval. The current cooling method and other alternatives are addressed in this program as means to mitigate this safety issue before retrieval. This program plan has three parts. The first part establishes program objectives and defines safety issue, drivers, and resolution criteria and strategy. The second part evaluates the high-heat safety issue and its mitigation and remediation methods and other alternatives according to resolution logic. The third part identifies major tasks and alternatives for mitigation and resolution of the safety issue. A table of best-estimate schedules for the key tasks is also included in this program plan

Evaluation of tank waste transfers at 241-AW tank farm

International Nuclear Information System (INIS)

Willis, W.L.

1998-01-01

A number of waste transfers are needed to process and feed waste to the private contractors in support of Phase 1 Privatization. Other waste transfers are needed to support the 242-A Evaporator, saltwell pumping, and other ongoing Tank Waste Remediation System (TWRS) operations. The purpose of this evaluation is to determine if existing or planned equipment and systems are capable of supporting the Privatization Mission of the Tank Farms and continuing operations through the end of Phase 1B Privatization Mission. Projects W-211 and W-314 have been established and will support the privatization effort. Equipment and system upgrades provided by these projects (W-211 and W-314) will also support other ongoing operations in the tank farms. It is recognized that these projects do not support the entire transfer schedule represented in the Tank Waste Remediation system Operation and Utilization Plan. Additionally, transfers surrounding the 241-AW farm must be considered. This evaluation is provided as information, which will help to define transfer paths required to complete the Waste Feed Delivery (WFD) mission. This document is not focused on changing a particular project, but it is realized that new project work in the 241-AW Tank Farm is required

Steel corrosion in radioactive waste storage tanks

International Nuclear Information System (INIS)

Carranza, Ricardo M.; Giordano, Celia M.; Saenz, E.; Weier, Dennis R.

2004-01-01

A collaborative study is being conducted by CNEA and USDOE (Department of Energy of the United States of America) to investigate the effects of tank waste chemistry on radioactive waste storage tank corrosion. Radioactive waste is stored in underground storage tanks that contain a combination of salts, consisting primarily of sodium nitrate, sodium nitrite and sodium hydroxide. The USDOE, Office of River Protection at the Hanford Site, has identified a need to conduct a laboratory study to better understand the effects of radioactive waste chemistry on the corrosion of waste storage tanks at the Hanford Site. The USDOE science need (RL-WT079-S Double-Shell Tanks Corrosion Chemistry) called for a multi year effort to identify waste chemistries and temperatures within the double-shell tank (DST) operating limits for corrosion control and operating temperature range that may not provide the expected corrosion protection and to evaluate future operations for the conditions outside the existing corrosion database. Assessment of corrosion damage using simulated (non-radioactive) waste is being made of the double-shell tank wall carbon steel alloy. Evaluation of the influence of exposure time, and electrolyte composition and/or concentration is being also conducted. (author) [es

Contingency plan for deployment of the void fraction instrument in Tank 241-AY-102

International Nuclear Information System (INIS)

CONNER, J.M.

1999-01-01

High-heat producing sludge from tank 241-C-106 will be sluiced and transferred to tank 241-AY-102 beginning in October 1998. Safety analyses have postulated that after retrieval, the waste in 241-AY-102 may generate and retain unsafe levels of flammable gases (Noorani 1998, Pasamebmetoglu etal. 1997). Unsafe levels of retained gas are not expected, but cannot be ruled out because of the large uncertainty in the gas generation and retention rates. The Tank Waste Remediation System Basis for Interim Operation (Noorani 1998) identifies the need for a contingency plan to add void fraction monitoring to tank 241-AY-102 within 2 weeks of the identification of flammable gas buildup that would warrant monitoring. The Tank 241-C-106 Waste Retrieval Sluicing System Process Control Plan (Carothers et al. 1998) committed to providing a contingency plan for deployment of the void fraction instrument (VFI) in tank 241-AY-102. The VFI determines the local void fraction of the waste by compressing a waste sample captured in a gas-tight test chamber. The sample chamber is mounted on the end of a 76-cm (2.5-ft) arm that can be rotated from vertical to horizontal when the instrument is deployed. Once in the waste, the arm can be positioned horizontally and rotated to sample in different areas below the riser. The VFI is deployed using a crane. The VFI has been deployed previously in 241-AW, 241-AN, and 241-SY tank farms, most recently in tank 241-SY-101 in June and July 1998. An additional test in tank 241-SY-101 is planned in September 1998. Operating instructions for the VFI are included in the Void Fraction Instrument Operation and Maintenance Manual (Pearce 1994)

Tank characterization report for single-shell tank 241-C-204

International Nuclear Information System (INIS)

Conner, J.M.

1996-01-01

This document summarizes the information on the historical uses, present status, and the sampling and analysis results of waste stored in Tank 241-C-204. This report supports the requirements of Tri Party Agreement Milestone M 44 09

Hanford Tank Waste - Near Source Treatment of Low Activity Waste

International Nuclear Information System (INIS)

Ramsey, William Gene

2013-01-01

Abstract only. Treatment and disposition of Hanford Site waste as currently planned consists of 100+ waste retrievals, waste delivery through up to 8+ miles of dedicated, in-ground piping, centralized mixing and blending operations- all leading to pre-treatment combination and separation processes followed by vitrification at the Hanford Tank Waste Treatment and Immobilization Plant (WTP). The sequential nature of Tank Farm and WTP operations requires nominally 15-20 years of continuous operations before all waste can be retrieved from many Single Shell Tanks (SSTs). Also, the infrastructure necessary to mobilize and deliver the waste requires significant investment beyond that required for the WTP. Treating waste as closely as possible to individual tanks or groups- as allowed by the waste characteristics- is being investigated to determine the potential to 1) defer, reduce, and/or eliminate infrastructure requirements, and 2) significantly mitigate project risk by reducing the potential and impact of single point failures. The inventory of Hanford waste slated for processing and disposition as LAW is currently managed as high-level waste (HLW), i.e., the separation of fission products and other radionuclides has not commenced. A significant inventory of this waste (over 20M gallons) is in the form of precipitated saltcake maintained in single shell tanks, many of which are identified as potential leaking tanks. Retrieval and transport (as a liquid) must be staged within the waste feed delivery capability established by site infrastructure and WTP. Near Source treatment, if employed, would provide for the separation and stabilization processing necessary for waste located in remote farms (wherein most of the leaking tanks reside) significantly earlier than currently projected. Near Source treatment is intended to address the currently accepted site risk and also provides means to mitigate future issues likely to be faced over the coming decades. This paper

Vitrification technology for Hanford Site tank waste

International Nuclear Information System (INIS)

Weber, E.T.; Calmus, R.B.; Wilson, C.N.

1995-04-01

The US Department of Energy's (DOE) Hanford Site has an inventory of 217,000 m 3 of nuclear waste stored in 177 underground tanks. The DOE, the US Environmental Protection Agency, and the Washington State Department of Ecology have agreed that most of the Hanford Site tank waste will be immobilized by vitrification before final disposal. This will be accomplished by separating the tank waste into high- and low-level fractions. Capabilities for high-capacity vitrification are being assessed and developed for each waste fraction. This paper provides an overview of the program for selecting preferred high-level waste melter and feed processing technologies for use in Hanford Site tank waste processing

Speciation of organic carbon in Hanford waste storage tanks: Part 1

International Nuclear Information System (INIS)

Carlson, C.D.

1997-02-01

This report is the first in a series to report on speciation of organic carbon in Hanford waste storage tanks. The comparison of the existing total organic carbon with oxalate and limited analyses of other organic species (acetate, formate, and normal paraffin hydrocarbons [NPH]) are reported. All of the data have been previously reported by the Grout and Characterization programs; the information includes all of the publicly available data through October 1996. Oxalate data were reported for 33 tanks, TOC data were reported for 82 tanks, and both oxalate and TOC data were available for 27 tanks. Of these 27 tanks, seven were found to have greater than 80% of the TOC identified as oxalate: 241-BY-104, 241-BY-105, 241-BY-106, 241-BY-110, 241-S-109, and 241-SX-108. Eighty percent accountability has been tentatively established as a minimum goal of the Organic Safety Program for speciation of TOC. Accountability of TOC through speciation will allow more accurate estimate of the potential energy content of the wastes as currently stored. Of the remaining 19 tanks, seven had between 40 and 80% of the TOC identified as oxalate, and eleven had less than 35% of the TOC identified. Of these, only five tanks had segment results that were greater than 1% TOC, and none was above 2%. Since the cur-rent safety criterion outlined in the Safety Analysis is 4.5% TOC, it may be determined that the further analyses of these tank wastes are not necessary. If additional analyses are deemed necessary, minimal work may be required, possibly limited to ion chromatography (IC), ion pair chromatography and capillary zone electrophoresis (CZE). Additional speciation work is planned for this fiscal year in both the Organic Tanks Safety and Characterization programs. The Characterization program reports acetate and formate data in addition to the oxalate data for all the tank cores it processes

Disposal of Hanford site tank wastes

International Nuclear Information System (INIS)

Kupfer, M.J.

1993-09-01

Between 1943 and 1986, 149 single-shell tanks (SSTs) and 28 double-shell tanks (DSTs) were built and used to store radioactive wastes generated during reprocessing of irradiated uranium metal fuel elements at the U.S. Department of Energy (DOE) Hanford Site in Southeastern Washington state. The 149 SSTs, located in 12 separate areas (tank farms) in the 200 East and 200 West areas, currently contain about 1.4 x 10 5 m 3 of solid and liquid wastes. Wastes in the SSTs contain about 5.7 x 10 18 Bq (170 MCi) of various radionuclides including 90 Sr, 99 Tc, 137 Cs, and transuranium (TRU) elements. The 28 DSTs also located in the 200 East and West areas contain about 9 x 10 4 m 3 of liquid (mainly) and solid wastes; approximately 4 x 10 18 Bq (90 MCi) of radionuclides are stored in the DSTs. Important characteristics and features of the various types of SST and DST wastes are described in this paper. However, the principal focus of this paper is on the evolving strategy for final disposal of both the SST and DST wastes. Also provided is a chronology which lists key events and dates in the development of strategies for disposal of Hanford Site tank wastes. One of these strategies involves pretreatment of retrieved tank wastes to separate them into a small volume of high-level radioactive waste requiring, after vitrification, disposal in a deep geologic repository and a large volume of low-level radioactive waste which can be safely disposed of in near-surface facilities at the Hanford Site. The last section of this paper lists and describes some of the pretreatment procedures and processes being considered for removal of important radionuclides from retrieved tank wastes

Radioactive tank waste remediation focus area

International Nuclear Information System (INIS)

1996-08-01

EM's Office of Science and Technology has established the Tank Focus Area (TFA) to manage and carry out an integrated national program of technology development for tank waste remediation. The TFA is responsible for the development, testing, evaluation, and deployment of remediation technologies within a system architecture to characterize, retrieve, treat, concentrate, and dispose of radioactive waste stored in the underground stabilize and close the tanks. The goal is to provide safe and cost-effective solutions that are acceptable to both the public and regulators. Within the DOE complex, 335 underground storage tanks have been used to process and store radioactive and chemical mixed waste generated from weapon materials production and manufacturing. Collectively, thes tanks hold over 90 million gallons of high-level and low-level radioactive liquid waste in sludge, saltcake, and as supernate and vapor. Very little has been treated and/or disposed or in final form

Radioactive tank waste remediation focus area

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-08-01

EM`s Office of Science and Technology has established the Tank Focus Area (TFA) to manage and carry out an integrated national program of technology development for tank waste remediation. The TFA is responsible for the development, testing, evaluation, and deployment of remediation technologies within a system architecture to characterize, retrieve, treat, concentrate, and dispose of radioactive waste stored in the underground stabilize and close the tanks. The goal is to provide safe and cost-effective solutions that are acceptable to both the public and regulators. Within the DOE complex, 335 underground storage tanks have been used to process and store radioactive and chemical mixed waste generated from weapon materials production and manufacturing. Collectively, thes tanks hold over 90 million gallons of high-level and low-level radioactive liquid waste in sludge, saltcake, and as supernate and vapor. Very little has been treated and/or disposed or in final form.

Process chemistry for the pretreatment of Hanford tank wastes

International Nuclear Information System (INIS)

Lumetta, G.J.; Swanson, J.L.; Barker, S.A.

1992-08-01

Current guidelines for disposing radioactive wastes stored in underground tanks at the US Department of Energy's Hanford Site call for the vitrification of high-level waste in borosilicate glass and disposal of the glass canisters in a deep geologic repository. Low-level waste is to be cast in grout and disposed of on site in shallow burial vaults. Because of the high cost of vitrification and geologic disposal, methods are currently being developed to minimize the volume of high-level waste requiring disposal. Two approaches are being considered for pretreating radioactive tank sludges: (1) leaching of selected components from the sludge and (2) acid dissolution of the sludge followed by separation of key radionuclides. The leaching approach offers the advantage of simplicity, but the acid dissolution/radionuclide extraction approach has the potential to produce the least number of glass canisters. Four critical components (Cr, P, S, and Al) were leached from an actual Hanford tank waste-Plutonium Finishing Plant sludge. The Al, P, and S were removed from the sludge by digestion of the sludge with 0.1 M NaOH at 100 degrees C. The Cr was leached by treating the sludge with alkaline KMnO 4 at 100 degrees C. Removing these four components from the sludge will dramatically lower the number of glass canisters required to dispose of this waste. The transuranic extraction (TRUEX) solvent extraction process has been demonstrated at a bench scale using an actual Hanford tank waste. The process, which involves extraction of the transuranic elements with octyl(phenyl)-N,N-diisobutylcarbamoylmethylphosphine oxide (CMPO), separated 99.9% of the transuranic elements from the bulk components of the waste. Several problems associated with the TRUEX processing of this waste have been addressed and solved

Waste gas combustion in a Hanford radioactive waste tank

International Nuclear Information System (INIS)

Travis, J.R.; Fujita, R.K.; Spore, J.W.

1994-01-01

It has been observed that a high-level radioactive waste tank generates quantities of hydrogen, ammonia, nitrous oxide, and nitrogen that are potentially well within flammability limits. These gases are produced from chemical and nuclear decay reactions in a slurry of radioactive waste materials. Significant amounts of combustible and reactant gases accumulate in the waste over a 110- to 120-d period. The slurry becomes Taylor unstable owing to the buoyancy of the gases trapped in a matrix of sodium nitrate and nitrite salts. As the contents of the tank roll over, the generated waste gases rupture through the waste material surface, allowing the gases to be transported and mixed with air in the cover-gas space in the dome of the tank. An ignition source is postulated in the dome space where the waste gases combust in the presence of air resulting in pressure and temperature loadings on the double-walled waste tank. This analysis is conducted with hydrogen mixing studies HMS, a three-dimensional, time-dependent fluid dynamics code coupled with finite-rate chemical kinetics. The waste tank has a ventilation system designed to maintain a slight negative gage pressure during normal operation. We modeled the ventilation system with the transient reactor analysis code (TRAC), and we coupled these two best-estimate accident analysis computer codes to model the ventilation system response to pressures and temperatures generated by the hydrogen and ammonia combustion

Stabilization of in-tank residual wastes and external tank soil contamination for the Hanford tank closure program: application to the AX tank farm

Energy Technology Data Exchange (ETDEWEB)

SONNICHSEN, J.C.

1998-10-12

Mixed high-level waste is currently stored in underground tanks at the US Department of Energy's (DOE's) Hanford Site. The plan is to retrieve the waste, process the water, and dispose of the waste in a manner that will provide less long-term health risk. The AX Tank Farm has been identified for purposes of demonstration. Not all the waste can be retrieved from the tanks and some waste has leaked from these tanks into the underlying soil. Retrieval of this waste could result in additional leakage. During FY1998, the Sandia National Laboratory was under contract to evaluate concepts for immobilizing the residual waste remaining in tanks and mitigating the migration of contaminants that exist in the soil column. Specifically, the scope of this evaluation included: development of a layered tank fill design for reducing water infiltration; development of in-tank getter technology; mitigation of soil contamination through grouting; sequestering of specific radionuclides in soil; and geochemical and hydrologic modeling of waste-water-soil interactions. A copy of the final report prepared by Sandia National Laboratory is attached.

Tank waste chemistry: A new understanding of waste aging

International Nuclear Information System (INIS)

Babad, H.; Camaioni, D.M.; Lilga, M.A.; Samuels, W.D.; Strachan, D.M.

1993-02-01

There is concern about the risk of uncontrolled exothermic reactions(s) in Hanford Site waste tanks containing NO 3 minus /NO 2 minus based salts and/or metal hydroxide sludges in combination with organics or ferrocyanides. However, gradual oxidation of the waste in the tanks to less reactive species appears to have reduced the risk. In addition, wastes sampled to date contain sufficiently large quantities of water so that propagation reactions are highly unlikely. This report details an investigation into the risk of an uncontrolled exothermic reaction in Hanford Site high-activity water tanks

WRPS Meeting The Challenge Of Tank Waste

International Nuclear Information System (INIS)

Britton, J.C.

2012-01-01

Washington River Protection Solutions (WRPS) is the Hanford tank operations contractor, charged with managing one of the most challenging environmental cleanup projects in the nation. The U.S. Department of Energy hired WRPS to manage 56 million gallons of high-level radioactive waste stored in 177 underground tanks. The waste is the legacy of 45 years of plutonium production for the U. S. nuclear arsenal. WRPS mission is three-fold: safely manage the waste until it can be processed and immobilized; develop the tools and techniques to retrieve the waste from the tanks, and build the infrastructure needed to deliver the waste to the Waste Treatment Plant (WTP) when it begins operating. WTP will 'vitrify' the waste by mixing it with silica and other materials and heating it in an electric melter. Vitrification turns the waste into a sturdy glass that will isolate the radioactivity from the environment. It will take more than 20 years to process all the tank waste. The tank waste is a complex highly radioactive mixture of liquid, sludge and solids. The radioactivity, chemical composition of the waste and the limited access to the underground storage tanks makes retrieval a challenge. Waste is being retrieved from aging single-shell tanks and transferred to newer, safer double-shell tanks. WRPS is using a new technology known as enhanced-reach sluicing to remove waste. A high-pressure stream of liquid is sprayed at 100 gallons per minute through a telescoping arm onto a hard waste layer several inches thick covering the waste. The waste is broken up, moved to a central pump suction and removed from the tank. The innovative Mobile Arm Retrieval System (MARS) is also being used to retrieve waste. MARS is a remotely operated, telescoping arm installed on a mast in the center of the tank. It uses multiple technologies to scrape, scour and rake the waste toward a pump for removal. The American Reinvestment and Recovery Act (ARRA) provided nearly $326 million over two

Tank waste concentration mechanism study

International Nuclear Information System (INIS)

Pan, L.C.; Johnson, L.J.

1994-09-01

This study determines whether the existing 242-A Evaporator should continue to be used to concentrate the Hanford Site radioactive liquid tank wastes or be replaced by an alternative waste concentration process. Using the same philosophy, the study also determines what the waste concentration mechanism should be for the future TWRS program. Excess water from liquid DST waste should be removed to reduce the volume of waste feed for pretreatment, immobilization, and to free up storage capacity in existing tanks to support interim stabilization of SSTS, terminal cleanout of excess facilities, and other site remediation activities

Project W-320, 241-C-106 sluicing supporting documentation bibliography

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the listing of documentation used to develop, or in support of Project W-320, readily retrievable. All documents are sorted by document number and list the document type. Tank 241-C-106 has been included on the High Heat Load Watch List

Mechanisms of gas retention and release: Experimental results for Hanford single-shell waste tanks 241-A-101, 241-S-106, and 241-U-103

International Nuclear Information System (INIS)

Rassat, S.D.; Caley, S.M.; Bredt, P.R.; Gauglitz, P.A.; Rinehart, D.E.; Forbes, S.V.

1998-09-01

The 177 underground waste storage tanks at the Hanford Site contain millions of gallons of radioactive waste resulting from the purification of nuclear materials and related processes. Through various mechanisms, flammable gas mixtures of hydrogen, ammonia, methane, and nitrous oxide are generated and retained in significant quantities within the waste in many (∼25) of these tanks. The potential for large releases of retained gas from these wastes creates a flammability hazard. It is a critical component of the effort to understand the flammability hazard and a primary goal of this laboratory investigation to establish an understanding of the mechanisms of gas retention and release in these wastes. The results of bubble retention experimental studies using waste samples from several waste tanks and a variety of waste types support resolution of the Flammable Gas Safety Issue. Gas bubble retention information gained in the pursuit of safe storage will, in turn, benefit future waste operations including salt-well pumping, waste transfers, and sluicing/retrieval

Potential for erosion corrosion of SRS high level waste tanks

International Nuclear Information System (INIS)

Zapp, P.E.

1994-01-01

SRS high-level radioactive waste tanks will not experience erosion corrosion to any significant degree during slurry pump operations. Erosion corrosion in carbon steel structures at reported pump discharge velocities is dominated by electrochemical (corrosion) processes. Interruption of those processes, as by the addition of corrosion inhibitors, sharply reduces the rate of metal loss from erosion corrosion. The well-inhibited SRS waste tanks have a near-zero general corrosion rate, and therefore will be essentially immune to erosion corrosion. The experimental data on carbon steel erosion corrosion most relevant to SRS operations was obtained at the Hanford Site on simulated Purex waste. A metal loss rate of 2.4 mils per year was measured at a temperature of 102 C and a slurry velocity comparable to calculated SRS slurry velocities on ground specimens of the same carbon steel used in SRS waste tanks. Based on these data and the much lower expected temperatures, the metal loss rate of SRS tanks under waste removal and processing conditions should be insignificant, i.e. less than 1 mil per year

Analysis of SRP waste streams for waste tank certification

International Nuclear Information System (INIS)

Coleman, C.J.

1989-01-01

The Savannah River Plant (SRP) will apply for certification from the State of South Carolina to operate the SRP High-Level Waste Tanks. The permit application will be submitted as a RCRA Part B, Volume 16, entitled ''RCRA Part B Application For the F and H-Area Radioactive Waste Farm.'' RCRA regulations require that influent and effluent streams of hazardous waste sites be characterized to obtain an operating permit. The Waste Management Technology Department requested ADD to determine 21 components (including pH and weight percent solids) in the current influent streams to SRP High-Level Waste Tanks. The analyses will be used to supplement existing data on the composition of High-Level Waste. Effluent streams, which will feed Saltstone and the DWPF, will be analyzed when they are produced. This report contains the data obtained from analyzing key influent streams to SRP High-Level Waste Tanks. The precision of the data and the analytical methods that were used are also discussed

Ferrocyanide tank safety program: Cesium uptake capacity of simulated ferrocyanide tank waste. Final report

International Nuclear Information System (INIS)

Burgeson, I.E.; Bryan, S.A.

1995-07-01

The objective of this project is to determine the capacity for 137 Cs uptake by mixed metal ferrocyanides present in Hanford Site waste tanks, and to assess the potential for aggregation of these 137 Cs-exchanged materials to form ''hot-spots'' in the tanks. This research, performed at Pacific Northwest Laboratory (PNL) for Westinghouse Hanford Company, stems from concerns regarding possible localized radiolytic heating within the tanks. After ferrocyanide was added to 18 high-level waste tanks in the 1950s, some of the ferrocyanide tanks received considerable quantities of saltcake waste that was rich in 137 Cs. If radioactive cesium was exchanged and concentrated by the nickel ferrocyanide present in the tanks, the associated heating could cause tank temperatures to rise above the safety limits specified for the ferrocyanide-containing tanks, especially if the supernate in the tanks is pumped out and the waste becomes drier

Dual-Remote Raman Technology for In-Situ Identification of Tank Waste - 13549

International Nuclear Information System (INIS)

Bryan, Sam; Levitskaia, Tatiana; Lines, Amanda; Smith, Frannie; Josephson, Gary; Bello, Job

2013-01-01

A new Raman spectroscopic system for in-situ identification of the composition of solid nuclear tank waste is being developed by collaborative effort between Pacific Northwest National Laboratory (PNNL) and EIC Laboratories, Inc. The recent advancements in Raman technology allow probing the chemical composition of the tank waste without sample collection. In the newly tested configuration, the Raman probe is installed on the top of the tank riser and sends the incident laser beam to the bottom of the tank, 10 - 70 feet away. The returning light containing chemical information is collected by the Raman probe and is transmitted via fiber optic cable to the spectrometer located outside the tank farm area. This dual remote technology significantly expands currently limited options for the safe rapid in-situ identification of the solid tank waste needed for the retrieval decisions. The developed Raman system was extensively tested for acceptability prior to tank farm deployment. This testing included calibration of the system with respect of the distance between the Raman probe and the sample, incident laser beam angle, and presence of the optical interferences. The Raman system was successfully deployed on Tank C-111 at the US DOE Hanford site. As the result of this deployment, the composition of the hardpan at the bottom of C-111 tank was identified. Further development of the dual-remote Raman technology will provide a significant safety enhancement eliminating the potential of personnel radiation exposure associated with the grab sample collection and expands options of the rapid and cost-effective in-situ chemical analysis of the tank waste. (authors)

Double shell tank waste analysis plan

International Nuclear Information System (INIS)

Mulkey, C.H.; Jones, J.M.

1994-01-01

Waste analysis plan for the double shell tanks. SD-WM-EV-053 is Superseding SD-WM-EV-057.This document provides the plan for obtaining information needed for the safe waste handling and storage of waste in the Double Shell Tank Systems. In Particular it addresses analysis necessary to manage waste according to Washington Administrative Code 173-303 and Title 40, parts 264 and 265 of the Code of Federal Regulations

In situ Spectroscopic Analysis and Quantification of [Tc(CO)3]+ in Hanford Tank Waste.

Science.gov (United States)

Branch, Shirmir D; French, Amanda D; Lines, Amanda M; Soderquist, Chuck Z; Rapko, Brian M; Heineman, William R; Bryan, Samuel A

2018-06-12

The quantitative conversion of non-pertechnetate [Tc(CO)3]+ species in nuclear waste storage tank 241-AN-102 at the Hanford Site is demonstrated. A waste sample containing the [Tc(CO)3]+ species is added to a developer solution that rapidly converts the non-emissive species into a luminescent complex, which is detected spectroscopically. This method was first demonstrated using a [Tc(CO)3]+ sample non-waste containing matrix to determine a detection limit (LOD), resulting in a [Tc(CO)3]+ LOD of 2.20 × 10-7 M, very near the LOD of the independently synthesized standard (2.10 × 10-7 M). The method was then used to detect [Tc(CO)3]+ in a simulated waste using the standard addition method, resulting in a [Tc(CO)3]+ concentration of 1.89 × 10-5 M (within 27.7% of the concentration determined by β- liquid scintillation counting). Three samples from 241-AN-102 were tested by the standard addition method: (1) a 5 M Na adjusted fraction, (2) a fraction depleted of 137Cs, (3) and an acid-stripped eluate. The concentrations of [Tc(CO)3]+ in these fractions were determined to be 9.90 × 10-6 M (1), 0 M (2), and 2.46 × 10-6 M (3), respectively. The concentration of [Tc(CO)3]+ in the as-received AN-102 tank waste supernatant was determined to be 1.84 × 10-5 M.

Supporting document for the north east quadrant historical tank content estimate report for C-Tank Farm

International Nuclear Information System (INIS)

Brevick, C.H.; Gaddis, L.A.; Walsh, A.C.

1994-06-01

This Supporting Document provides historical in-depth characterization information gathered on C-Tank Farm, such as historical waste transfer and level data, tank physical information, temperature data, sampling data, and drywell and liquid observation well data for Historical Tank Content Estimate Report of the NE Quadrant and the Hanford 200 East Areas

Evidence for dawsonite in Hanford high-level nuclear waste tanks.

Science.gov (United States)

Reynolds, Jacob G; Cooke, Gary A; Herting, Daniel L; Warrant, R Wade

2012-03-30

Gibbsite [Al(OH)(3)] and boehmite (AlOOH) have long been assumed to be the most prevalent aluminum-bearing minerals in Hanford high-level nuclear waste sludge. The present study shows that dawsonite [NaAl(OH)(2)CO(3)] is also a common aluminum-bearing phase in tanks containing high total inorganic carbon (TIC) concentrations and (relatively) low dissolved free hydroxide concentrations. Tank samples were probed for dawsonite by X-ray Diffraction (XRD), Scanning Electron Microscopy with Energy Dispersive Spectrometry (SEM-EDS) and Polarized Light Optical Microscopy. Dawsonite was conclusively identified in four of six tanks studied. In a fifth tank (AN-102), the dawsonite identification was less conclusive because it was only observed as a Na-Al bearing phase with SEM-EDS. Four of the five tank samples with dawsonite also had solid phase Na(2)CO(3) · H(2)O. The one tank without observable dawsonite (Tank C-103) had the lowest TIC content of any of the six tanks. The amount of TIC in Tank C-103 was insufficient to convert most of the aluminum to dawsonite (Al:TIC mol ratio of 20:1). The rest of the tank samples had much lower Al:TIC ratios (between 2:1 and 0.5:1) than Tank C-103. One tank (AZ-102) initially had dawsonite, but dawsonite was not observed in samples taken 15 months after NaOH was added to the tank surface. When NaOH was added to a laboratory sample of waste from Tank AZ-102, the ratio of aluminum to TIC in solution was consistent with the dissolution of dawsonite. The presence of dawsonite in these tanks is of significance because of the large amount of OH(-) consumed by dawsonite dissolution, an effect confirmed with AZ-102 samples. Copyright © 2012 Elsevier B.V. All rights reserved.

Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

International Nuclear Information System (INIS)

Hubbard, Mike; Herbert, James E.; Scheele, Patrick W.

2015-01-01

The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m 3 to 4921 m 3 (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removal and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and product lubricated canned

Waste behavior analysis for tank 241-SY-103

International Nuclear Information System (INIS)

Wilkins, N.E.

1994-01-01

Tank 241-SY-103 is on the Flammable Gas Watch List. The waste in this tank behaves similarly to that in tank 241-Sy-101. Both show slurry growth and periodic surface level drops. However, the surface level drops are much smaller than those in tank 101-SY. A standard hydrogen monitoring system (SHMS) was recently installed in tank 103-SY, and waste auger samples were recently taken. This document covers the characterization results to date for the auger samples, and the behavior of the tank waste during both steady state periods and gas release events

Double-shell tank system dangerous waste permit application

International Nuclear Information System (INIS)

1991-06-01

This Double-Shell Tank System Dangerous Waste Permit Application should be read in conjunction with the 242-A Evaporator Dangerous Waste Permit Application and the Liquid Effluent Retention Facility Dangerous Waste Permit Application, also submitted on June 28, 1991. Information contained in the Double-Shell Tank System permit application is referenced in the other two permit applications. The Double-Shell Tank System stores and treats mixed waste received from a variety of sources on the Hanford Site. The 242-A Evaporator treats liquid mixed waste received from the double-shell tanks. The 242-A Evaporator returns a mixed-waste slurry to the double-shell tanks and generates the dilute mixed-waste stream stored in the Liquid Effluent Retention Facility. This report contains information on the following topics: Facility Description and General Provisions; Waste Characteristics; Process Information; Groundwater Monitoring; Procedures to Prevent Hazards; Contingency Plan; Personnel Training; Exposure Information Report; Waste Minimization Plan; Closure and Postclosure Requirements; Reporting and Recordkeeping; other Relevant Laws; and Certification. 150 refs., 141 figs., 118 tabs

Characterization results for 106-AN grout produced in a pilot-scale test

International Nuclear Information System (INIS)

Lokken, R.O.; Bagaasen, L.M.; Martin, P.F.C.; Palmer, S.E.; Anderson, C.M.

1993-06-01

The Grout Treatment Facility (GTF) at Hanford. Washington, will process the low-level fraction of selected double-shell tank (DST) wastes into a cementitious waste form. This facility, which is operated by Westinghouse Hanford Company (WHC), mixes liquid waste with cementitious materials to produce a waste form that immobilizes hazardous constituents through chemical reactions and/or microencapsulation. Over one million gallons of phosphate/sulfate waste were solidified in the first production campaign with this facility. The next tank waste scheduled for treatment is 106-AN (the waste from Tank 241-AN-106). After laboratory studies were conducted to select the grout formulation, tests using the 1/4-scale pilot facilities at the Pacific Northwest Laboratory (PNL) were conducted as part of the formulation verification process. The major objectives of these pilot-scale tests were to determine if the proposed grout formulation could be processed in the pilotscale equipment. to collect thermal information to help determine the best way to manage the grout hydration heat, and to characterize the solidified grout

Annual radioactive waste tank inspection program -- 1993

International Nuclear Information System (INIS)

McNatt, F.G. Sr.

1994-05-01

Aqueous radioactive wastes from Savannah River Site (SRS) separations processes are contained in large underground carbon steel tanks. Inspections made during 1993 to evaluate these vessels, and evaluations based on data accrued by inspections made since the tanks were constructed, are the subject of this report. The 1993 inspection program revealed that the condition of the Savannah River Site waste tanks had not changed significantly from that reported in the previous annual report. No new leaksites were observed. No evidence of corrosion or materials degradation was observed in the waste tanks. However, degradation was observed on covers of the concrete encasements for the out-of-service transfer lines to Tanks 1 through 8

Project W-320, 241-C-106 sluicing, master calculation list

International Nuclear Information System (INIS)

Bailey, J.W.

1998-01-01

This supporting document has been prepared to make the Master Calculation List readily retrievable. The list gives the status of the calculation (as-built, not used, applied, etc.), the calculation title, its originator, comments, and report number under which it was issued. Tank 241-C-106 has been included on the High Heat Load Watch List

Tank waste source term inventory validation. Volume II. Letter report

Energy Technology Data Exchange (ETDEWEB)

NONE

1995-04-01

This document comprises Volume II of the Letter Report entitled Tank Waste Source Term Inventory Validation. This volume contains Appendix C, Radionuclide Tables, and Appendix D, Chemical Analyte Tables. The sample data for selection of 11 radionuclides and 24 chemical analytes were extracted from six separate sample data sets, were arranged in a tabular format and were plotted on scatter plots for all of the 149 single-shell tanks, the 24 double-shell tanks and the four aging waste tanks. The solid and liquid sample data was placed in separate tables and plots. The sample data and plots were compiled from the following data sets: characterization raw sample data, recent core samples, D. Braun data base, Wastren (Van Vleet) data base, TRAC and HTCE inventories.

Tank waste source term inventory validation. Volume II. Letter report

International Nuclear Information System (INIS)

1995-04-01

This document comprises Volume II of the Letter Report entitled Tank Waste Source Term Inventory Validation. This volume contains Appendix C, Radionuclide Tables, and Appendix D, Chemical Analyte Tables. The sample data for selection of 11 radionuclides and 24 chemical analytes were extracted from six separate sample data sets, were arranged in a tabular format and were plotted on scatter plots for all of the 149 single-shell tanks, the 24 double-shell tanks and the four aging waste tanks. The solid and liquid sample data was placed in separate tables and plots. The sample data and plots were compiled from the following data sets: characterization raw sample data, recent core samples, D. Braun data base, Wastren (Van Vleet) data base, TRAC and HTCE inventories

Recommendations for erosion-corrosion allowance for Multi-Function Waste Tank Facility tanks

International Nuclear Information System (INIS)

Carlos, W.C.; Brehm, W.F.; Larrick, A.P.; Divine, J.R.

1994-10-01

The Multi-Function Waste Tank Facility carbon steel tanks will contain mixer pumps that circulate the waste. On the basis of flow characteristics of the system and data from the literature, an erosion allowance of 0.075 mm/y (3 mil/year) was recommended for the tank bottoms, in addition to the 0.025 mm/y (1 mil/year) general corrosion allowance

Organic Tanks Safety Program: Waste aging studies

International Nuclear Information System (INIS)

Camaioni, D.M.; Samuels, W.D.; Lenihan, B.D.; Clauss, S.A.; Wahl, K.L.; Campbell, J.A.

1994-11-01

The underground storage tanks at the Hanford Complex contain wastes generated from many years of plutonium production and recovery processes, and mixed wastes from radiological degradation processes. The chemical changes of the organic materials used in the extraction processes have a direct on several specific safety issues, including potential energy releases from these tanks. This report details the first year's findings of a study charged with determining how thermal and radiological processes may change the composition of organic compounds disposed to the tank. Their approach relies on literature precedent, experiments with simulated waste, and studies of model reactions. During the past year, efforts have focused on the global reaction kinetics of a simulated waste exposed to γ radiation, the reactions of organic radicals with nitrite ion, and the decomposition reactions of nitro compounds. In experiments with an organic tank non-radioactive simulant, the authors found that gas production is predominantly radiolytically induced. Concurrent with gas generation they observe the disappearance of EDTA, TBP, DBP and hexone. In the absence of radiolysis, the TBP readily saponifies in the basic medium, but decomposition of the other compounds required radiolysis. Key organic intermediates in the model are C-N bonded compounds such as oximes. As discussed in the report, oximes and nitro compounds decompose in strong base to yield aldehydes, ketones and carboxylic acids (from nitriles). Certain aldehydes can react in the absence of radiolysis to form H 2 . Thus, if the pathways are correct, then organic compounds reacting via these pathways are oxidizing to lower energy content. 75 refs

The Hanford Site Tank Waste Remediation System: An update

International Nuclear Information System (INIS)

Alumkal, W.T.; Babad, H.; Harmon, H.D.; Wodrich, D.D.

1994-01-01

The U.S. Department of Energy's Hanford Site, located in southeastern Washington State, has the most diverse and largest amount of highly radioactive waste in the United States. High-level radioactive waste has been stored in large underground tanks since 1944. Approximately 230,000 m 3 (61 Mgal) of caustic liquids, slurries, saltcakes, and sludges have 137 Cs accumulated in 177 tanks. In addition, significant amounts of 90 Sr and were removed from the tank waste, converted to salts, doubly encapsulated in metal containers., and stored in water basins. A Tank Waste Remediation System Program was established by the U.S. Department of Energy in 1991 to safely manage and immobilize these wastes in anticipation of permanent disposal of the high-level waste fraction in a geologic repository. Since 1991, progress has been made resolving waste tank safety issues, upgrading Tank Farm facilities and operations, and developing a new strategy for retrieving, treating, and immobilizing the waste for disposal

Tank 241-C-103 organic vapor and liquid characterization and supporting activities, Hanford Site, Richland, Washington

International Nuclear Information System (INIS)

1993-01-01

The action proposed is to sample the vapor space and liquid waste and perform other supporting activities in Tank 241-C-103 located in the 241-C Tank Farm on the Hanford Site. Operations at Tank 241-C-103 are curtailed because of an unreviewed safety question (USQ) concerning flammability issues of the organic waste in the tank. This USQ must be resolved before normal operation and surveillance of the tank can resume. In addition to the USQ, Tank 241-C-103 is thought to be involved in several cases of exposure of individuals to noxious vapors. This safety issue requires the use of supplied air for workers in the vicinity of the tank. Because of the USQ, the US Department of Energy proposes to characterize the waste in the vapor space and the organic and aqueous layers, to determine the volume of the organic layer. This action is needed to: (1) assess potential risks to workers, the public, and the environment from continued routine tank operations and (2) provide information on the waste material in the tank to facilitate a comprehensive safety analysis of this USQ. The information would be used to determine if a flammable condition within the tank is credible. This information would be used to prevent or mitigate an accident during continued waste storage and future waste characterization. Alternatives to the proposed activities have been considered in this analysis

Headspace vapor characterization of Hanford waste Tank 241-C-201: Results from samples collected on 06/19/96

International Nuclear Information System (INIS)

Thomas, B.L.; Evans, J.C.; Pool, K.H.; Olsen, K.B.; Fruchter, J.S.; Silvers, K.L.

1997-01-01

This report describes the analytical results of vapor samples taken from the headspace of the waste storage tank 241-C-201 (Tank C-201) at the Hanford Site in Washington State. The results described in this report were obtained to characterize the vapors present in the tank headspace and to support safety evaluations and tank farm operations. The results include air concentrations of selected inorganic and organic analytes and grouped compounds from samples obtained by Westinghouse Hanford Company (WHC) and provided for analysis to Pacific Northwest National Laboratory (PNNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNNL. Analyte concentrations were based on analytical results and, where appropriate, on sample volumes provided by WHC. A summary, of the inorganic analytes, permanent gases, and total non-methane organic compounds is listed in a table. Detailed descriptions of the analytical results appear in the appendices

Decision and systems analysis for underground storage tank waste retrieval systems and tank waste remediation system

International Nuclear Information System (INIS)

Bitz, D.A.; Berry, D.L.; Jardine, L.J.

1994-03-01

Hanford's underground tanks (USTs) pose one of the most challenging hazardous and radioactive waste problems for the Department of Energy (DOE). Numerous schemes have been proposed for removing the waste from the USTs, but the technology options for doing this are largely unproven. To help assess the options, an Independent Review Group (IRG) was established to conduct a broad review of retrieval systems and the tank waste remediation system. The IRG consisted of the authors of this report

Technology Successes in Hanford Tank Waste Storage and Retrieval

International Nuclear Information System (INIS)

Cruz, E. J.

2002-01-01

The U. S. Department of Energy (DOE), Office of River Protection (ORP) is leading the River Protection Project (RPP), which is responsible for dispositioning approximately 204,000 cubic meters (54 million gallons) of high-level radioactive waste that has accumulated in 177 large underground tanks at the Hanford Site since 1944. The RPP is comprised of five major elements: storage of the waste, retrieval of the waste from the tanks, treatment of the waste, disposal of treated waste, and closure of the tank facilities. Approximately 3785 cubic meters (1 million gallons) of waste have leaked from the older ''single-shell tanks.'' Sixty-seven of the 147 single shell tanks are known or assumed ''leakers.'' These leaks have resulted in contaminant plumes that extend from the tank to the groundwater in a number of tank farms. Retrieval and closure of the leaking tanks complicates the ORP technical challenge because cleanup decisions must consider the impacts of past leaks along with a strategy for retrieving the waste in the tanks. Completing the RPP mission as currently planned and with currently available technologies will take several decades and tens of billions of dollars. RPP continue to pursue the benefits from deploying technologies that reduce risk to human health and the environment, as well as, the cost of cleanup. This paper discusses some of the recent technology partnering activities with the DOE Office of Science and Technology activities in tank waste retrieval and storage

The effect of dilution on the gas-retention behavior of Tank 241-SY-101 waste

International Nuclear Information System (INIS)

Bredt, P.R.; Tingey, S.M.; Shade, E.H.

1995-09-01

The effect of dilution on gas retention in waste from Tank 241-SY-101 was investigated. A composite sample was prepared from material collected during the Window ''C'' and Window ''E'' sampling events. The composite contained material from both the convective and nonconvective layer in the proportions existing in the tank. Operation of the mixer pump in Tank 241-SY-101 has homogenized the tank material, and dilution of the current waste would require additional mixing; therefore, no attempt was made to use unhomogenized tank waste to prepare the composite. The composite was diluted with 2 M NaOH at ratios of 0.5:1, 0.75: 1, 1:1, and 3:1 per volume (2 M NaOH:tank waste)

Tank waste processing analysis: Database development, tank-by-tank processing requirements, and examples of pretreatment sequences and schedules as applied to Hanford Double-Shell Tank Supernatant Waste - FY 1993

International Nuclear Information System (INIS)

Colton, N.G.; Orth, R.J.; Aitken, E.A.

1994-09-01

This report gives the results of work conducted in FY 1993 by the Tank Waste Processing Analysis Task for the Underground Storage Tank Integrated Demonstration. The main purpose of this task, led by Pacific Northwest Laboratory, is to demonstrate a methodology to identify processing sequences, i.e., the order in which a tank should be processed. In turn, these sequences may be used to assist in the development of time-phased deployment schedules. Time-phased deployment is implementation of pretreatment technologies over a period of time as technologies are required and/or developed. The work discussed here illustrates how tank-by-tank databases and processing requirements have been used to generate processing sequences and time-phased deployment schedules. The processing sequences take into account requirements such as the amount and types of data available for the tanks, tank waste form and composition, required decontamination factors, and types of compact processing units (CPUS) required and technology availability. These sequences were developed from processing requirements for the tanks, which were determined from spreadsheet analyses. The spreadsheet analysis program was generated by this task in FY 1993. Efforts conducted for this task have focused on the processing requirements for Hanford double-shell tank (DST) supernatant wastes (pumpable liquid) because this waste type is easier to retrieve than the other types (saltcake and sludge), and more tank space would become available for future processing needs. The processing requirements were based on Class A criteria set by the U.S. Nuclear Regulatory Commission and Clean Option goals provided by Pacific Northwest Laboratory

Commercial Submersible Mixing Pump For SRS Tank Waste Removal - 15223

Energy Technology Data Exchange (ETDEWEB)

Hubbard, Mike [Savannah River Remediation, LLC., Aiken, SC (United States); Herbert, James E. [Savannah River Remediation, LLC., Aiken, SC (United States); Scheele, Patrick W. [Savannah River Remediation, LLC., Aiken, SC (United States)

2015-01-12

The Savannah River Site Tank Farms have 45 active underground waste tanks used to store and process nuclear waste materials. There are 4 different tank types, ranging in capacity from 2839 m³ to 4921 m³ (750,000 to 1,300,000 gallons). Eighteen of the tanks are older style and do not meet all current federal standards for secondary containment. The older style tanks are the initial focus of waste removal efforts for tank closure and are referred to as closure tanks. Of the original 51 underground waste tanks, six of the original 24 older style tanks have completed waste removal and are filled with grout. The insoluble waste fraction that resides within most waste tanks at SRS requires vigorous agitation to suspend the solids within the waste liquid in order to transfer this material for eventual processing into glass filled canisters at the Defense Waste Processing Facility (DWPF). SRS suspends the solid waste by use of recirculating mixing pumps. Older style tanks generally have limited riser openings which will not support larger mixing pumps, since the riser access is typically 58.4 cm (23 inches) in diameter. Agitation for these tanks has been provided by four long shafted standard slurry pumps (SLP) powered by an above tank 112KW (150 HP) electric motor. The pump shaft is lubricated and cooled in a pressurized water column that is sealed from the surrounding waste in the tank. Closure of four waste tanks has been accomplished utilizing long shafted pump technology combined with heel removal using multiple technologies. Newer style waste tanks at SRS have larger riser openings, allowing the processing of waste solids to be accomplished with four large diameter SLPs equipped with 224KW (300 HP) motors. These tanks are used to process the waste from closure tanks for DWPF. In addition to the SLPs, a 224KW (300 HP) submersible mixer pump (SMP) has also been developed and deployed within older style tanks. The SMPs are product cooled and

Waste Tank Corrosion Program at Savannah River Site

International Nuclear Information System (INIS)

Chandler, J.R.; Hsu, T.C.; Hobbs, D.T.; Iyer, N.C.; Marra, J.E.; Zapp, P.E.

1993-01-01

The Savannah River Site (SRS) has approximately 30 million gallons of high level radioactive waste stored in 51 underground tanks. SRS has maintained an active corrosion research and corrosion control and monitoring program throughout the operating history of SRS nuclear waste storage tanks. This program is largely responsible for the successful waste storage experience at SRS. The program has consisted of extensive monitoring of the tanks and surrounding environment for evidence of leaks, extensive research to understand the potential corrosion processes, and development and implementation of corrosion chemistry control. Current issues associated with waste tank corrosion are primarily focused on waste processing operations and are being addressed by a number of active programs and initiatives

Stabilization of in-tank residual wastes and external-tank soil contamination for the tank focus area, Hanford tank initiative: Applications to the AX Tank Farm

International Nuclear Information System (INIS)

Balsley, S.D.; Krumhansl, J.L.; Borns, D.J.; McKeen, R.G.

1998-07-01

A combined engineering and geochemistry approach is recommended for the stabilization of waste in decommissioned tanks and contaminated soils at the AX Tank Farm, Hanford, WA. A two-part strategy of desiccation and gettering is proposed for treatment of the in-tank residual wastes. Dry portland cement and/or fly ash are suggested as an effective and low-cost desiccant for wicking excess moisture from the upper waste layer. Getters work by either ion exchange or phase precipitation to reduce radionuclide concentrations in solution. The authors recommend the use of specific natural and man-made compounds, appropriately proportioned to the unique inventory of each tank. A filler design consisting of multilayered cementitous grout with interlayered sealant horizons should serve to maintain tank integrity and minimize fluid transport to the residual waste form. External tank soil contamination is best mitigated by placement of grouted skirts under and around each tank, together with installation of a cone-shaped permeable reactive barrier beneath the entire tank farm. Actinide release rates are calculated from four tank closure scenarios ranging from no action to a comprehensive stabilization treatment plan (desiccant/getters/grouting/RCRA cap). Although preliminary, these calculations indicate significant reductions in the potential for actinide transport as compared to the no-treatment option

Rethinking the Hanford Tank Waste Program

International Nuclear Information System (INIS)

Parker, F. L.; Clark, D. E.; Morcos, N.

2002-01-01

The program to treat and dispose of the highly radioactive wastes stored in underground tanks at the U.S. Department of Energy's Hanford site has been studied. A strategy/management approach to achieve an acceptable (technically sound) end state for these wastes has been developed in this study. This approach is based on assessment of the actual risks and costs to the public, workers, and the environment associated with the wastes and storage tanks. Close attention should be given to the technical merits of available waste treatment and stabilization methodologies, and application of realistic risk reduction goals and methodologies to establish appropriate tank farm cleanup milestones. Increased research and development to reduce the mass of non-radioactive materials in the tanks requiring sophisticated treatment is highly desirable. The actual cleanup activities and milestones, while maintaining acceptable safety standards, could be more focused on a risk-to-benefit cost effectiveness, as agreed to by the involved stakeholders and in accordance with existing regulatory requirements. If existing safety standards can be maintained at significant cost savings under alternative plans but with a change in the Tri-Party Agreement (a regulatory requirement), those plans should be carried out. The proposed strategy would also take advantage of the lessons learned from the activities and efforts in the first phase of the two-phased cleanup of the Hanford waste tank farms

Low-level tank waste simulant data base

International Nuclear Information System (INIS)

Lokken, R.O.

1996-04-01

The majority of defense wastes generated from reprocessing spent N- Reactor fuel at Hanford are stored in underground Double-shell Tanks (DST) and in older Single-Shell Tanks (SST) in the form of liquids, slurries, sludges, and salt cakes. The tank waste remediation System (TWRS) Program has the responsibility of safely managing and immobilizing these tank wastes for disposal. This report discusses three principle topics: the need for and basis for selecting target or reference LLW simulants, tanks waste analyses and simulants that have been defined, developed, and used for the GDP and activities in support of preparing and characterizing simulants for the current LLW vitrification project. The procedures and the data that were generated to characterized the LLW vitrification simulants were reported and are presented in this report. The final section of this report addresses the applicability of the data to the current program and presents recommendations for additional data needs including characterization and simulant compositional variability studies

Review of Tank Lay-Up Status at US Department of Energy Radioactive Waste Tank Sites

International Nuclear Information System (INIS)

Elmore, Monte R.; Henderson, Colin

2002-01-01

During fiscal year (FY) 2001 as part of a Tanks Focus Area strategic initiative, tank lay-up options were developed and evaluated for the two high-level waste (HLW) storage tanks at the West Valley Demonstration Project. As follow-on task, a list of key waste tank contacts throughout the US Department of Energy complex was developed. Visits were then made to the primary DOE sites with radioactive waste storage tanks to discuss the concept and applicability of tank lay-up. This report documents the results of individual discussions with tank closure staff at the four DOE Sites concerning tank closure status and plans as well as lay-up options and activities

CRITICAL ASSUMPTIONS IN THE F-TANK FARM CLOSURE OPERATIONAL DOCUMENTATION REGARDING WASTE TANK INTERNAL CONFIGURATIONS

Energy Technology Data Exchange (ETDEWEB)

Hommel, S.; Fountain, D.

2012-03-28

The intent of this document is to provide clarification of critical assumptions regarding the internal configurations of liquid waste tanks at operational closure, with respect to F-Tank Farm (FTF) closure documentation. For the purposes of this document, FTF closure documentation includes: (1) Performance Assessment for the F-Tank Farm at the Savannah River Site (hereafter referred to as the FTF PA) (SRS-REG-2007-00002), (2) Basis for Section 3116 Determination for Closure of F-Tank Farm at the Savannah River Site (DOE/SRS-WD-2012-001), (3) Tier 1 Closure Plan for the F-Area Waste Tank Systems at the Savannah River Site (SRR-CWDA-2010-00147), (4) F-Tank Farm Tanks 18 and 19 DOE Manual 435.1-1 Tier 2 Closure Plan Savannah River Site (SRR-CWDA-2011-00015), (5) Industrial Wastewater Closure Module for the Liquid Waste Tanks 18 and 19 (SRRCWDA-2010-00003), and (6) Tank 18/Tank 19 Special Analysis for the Performance Assessment for the F-Tank Farm at the Savannah River Site (hereafter referred to as the Tank 18/Tank 19 Special Analysis) (SRR-CWDA-2010-00124). Note that the first three FTF closure documents listed apply to the entire FTF, whereas the last three FTF closure documents listed are specific to Tanks 18 and 19. These two waste tanks are expected to be the first two tanks to be grouted and operationally closed under the current suite of FTF closure documents and many of the assumptions and approaches that apply to these two tanks are also applicable to the other FTF waste tanks and operational closure processes.

Hanford Site Waste Storage Tank Information Notebook

International Nuclear Information System (INIS)

Husa, E.I.; Raymond, R.E.; Welty, R.K.; Griffith, S.M.; Hanlon, B.M.; Rios, R.R.; Vermeulen, N.J.

1993-07-01

This report provides summary data on the radioactive waste stored in underground tanks in the 200 East and West Areas at the Hanford Site. The summary data covers each of the existing 161 Series 100 underground waste storage tanks (500,000 gallons and larger). It also contains information on the design and construction of these tanks. The information in this report is derived from existing reports that document the status of the tanks and their materials. This report also contains interior, surface photographs of each of the 54 Watch List tanks, which are those tanks identified as Priority I Hanford Site Tank Farm Safety Issues in accordance with Public Law 101-510, Section 3137*

Preliminary assessment of blending Hanford tank wastes

International Nuclear Information System (INIS)

Geeting, J.G.H.; Kurath, D.E.

1993-03-01

A parametric study of blending Hanford tank wastes identified possible benefits from blending wastes prior to immobilization as a high level or low level waste form. Track Radioactive Components data were used as the basis for the single-shell tank (SST) waste composition, while analytical data were used for the double-shell tank (DST) composition. Limiting components were determined using the existing feed criteria for the Hanford Waste Vitrification Plant (HWVP) and the Grout Treatment Facility (GTF). Results have shown that blending can significantly increase waste loading and that the baseline quantities of immobilized waste projected for the sludge-wash pretreatment case may have been drastically underestimated, because critical components were not considered. Alternatively, the results suggest further review of the grout feed specifications and the solubility of minor components in HWVP borosilicate glass. Future immobilized waste estimates might be decreased substantially upon a thorough review of the appropriate feed specifications

Preliminary assessment of blending Hanford tank wastes

Energy Technology Data Exchange (ETDEWEB)

Geeting, J.G.H.; Kurath, D.E.

1993-03-01

A parametric study of blending Hanford tank wastes identified possible benefits from blending wastes prior to immobilization as a high level or low level waste form. Track Radioactive Components data were used as the basis for the single-shell tank (SST) waste composition, while analytical data were used for the double-shell tank (DST) composition. Limiting components were determined using the existing feed criteria for the Hanford Waste Vitrification Plant (HWVP) and the Grout Treatment Facility (GTF). Results have shown that blending can significantly increase waste loading and that the baseline quantities of immobilized waste projected for the sludge-wash pretreatment case may have been drastically underestimated, because critical components were not considered. Alternatively, the results suggest further review of the grout feed specifications and the solubility of minor components in HWVP borosilicate glass. Future immobilized waste estimates might be decreased substantially upon a thorough review of the appropriate feed specifications.

Characterization of Vadose Zone Sediments Below the T Tank Farm: Boreholes C4104, C4105, 299-W10-196, and RCRA Borehole 299-W11-39

Energy Technology Data Exchange (ETDEWEB)

Serne, R. Jeffrey; Bjornstad, Bruce N.; Horton, Duane G.; Lanigan, David C.; Schaef, Herbert T.; Lindenmeier, Clark W.; Lindberg, Michael J.; Clayton, Ray E.; Legore, Virginia L.; Geiszler, Keith N.; Baum, Steven R.; Valenta, Michelle M.; Kutnyakov, Igor V.; Vickerman, Tanya S.; Orr, Robert D.; Brown, Christopher F.

2008-09-11

This report was revised in September 2008 to remove acid-extractable sodium data from Tables 4.8, 4.28, and 4.52. The sodium data was removed due to potential contamination introduced during the acid extraction process. The rest of the text remains unchanged from the original report issued in September 2004. The overall goal of the Tank Farm Vadose Zone Project, led by CH2M HILL Hanford Group, Inc., is to define risks from past and future single-shell tank farm activities at Hanford. To meet this goal, CH2M HILL Hanford Group, Inc. tasked scientists from Pacific Northwest National Laboratory to perform detailed analyses on vadose zone sediments from within Waste Management Area (WMA) T-TX-TY. This report is the second of two reports written to present the results of these analyses. Specifically, this report contains all the geologic, geochemical, and selected physical characterization data collected on vadose zone sediment recovered from boreholes C4104 and C4105 in the T Tank Farm, and from borehole 299-W-11-39 installed northeast of the T Tank Farm. Finally, the measurements on sediments from borehole C4104 are compared with a nearby borehole drilled in 1993, 299- W10-196, through the tank T-106 leak plume.

Acoustic imaging of underground storage tank wastes

International Nuclear Information System (INIS)

Mech, S.J.

1995-09-01

Acoustics is a potential tool to determine the properties of high level wastes stored in Underground Storage Tanks. Some acoustic properties were successfully measured by a limited demonstration conducted in 114-TX. This accomplishment provides the basis for expanded efforts to qualify techniques which depend on the acoustic properties of tank wastes. This work is being sponsored by the Department of Energy under the Office of Science and Technology. In FY-1994, limited Tank Waste Remediation Systems EM-30 support was available at Hanford and Los Alamos National Laboratory. The Massachusetts Institute of Technology (MIT) and Earth Resources Laboratory (ERL) were engaged for analysis support, and Elohi Geophysics, Inc. for seismic testing services. Westinghouse-Hanford Company provided the testing and training, supplied the special engineering and safety analysis equipment and procedures, and provided the trained operators for the actual tank operations. On 11/9/94, limited in-tank tests were successfully conducted in tank 114-TX. This stabilized Single Shell Tank was reported as containing 16.8 feet of waste, the lower 6.28 feet of which contained interstitial liquid. Testing was conducted over the lower 12 feet, between two Liquid Observation Wells thirty feet apart. The ''quick-look'' data was reviewed on-site by MIT and Elohi

History of waste tank 11, 1955 through 1974

International Nuclear Information System (INIS)

Davis, T.L.; Tharin, D.W.; Lohr, D.R.

1978-10-01

Tank 11 was placed in service as a receiver of low heat waste (LW) in July 1955. In November 1961, the supernate was decanted from the sludge to prepare tank 11 for receipt of frame waste. In July 1962, the supernate was again decanted and tank 11 was used to receive fresh high heat waste (HW) from the enriched uranium process in Building 221-H. Again, the supernate was decanted in June 1965 and July 1967 to allow the tank to be reused for waste receipt. In order to use tank 11 for solid salt storage, a sludge removal operation was conducted in October 1969. The operation was unsuccessful. Tank 11 consequently received hot concentrated supernate from tank 10 blended with dilute waste and was later returned to service as a receiver of HW. A small, apparently inactive leak site was found in April 1974. Inspections have been made of the annulus and the interior of the tank both visually and with an optical periscope. Samples of the sludge, supernate, and tank vapor have been analyzed. Top-to-bottom profiles of radiation and temperature in the tank have been taken and measurements were made of deflections in the bottom knuckle plate due to changing liquid level. One horizontal and seventeen vertical cooling coils have failed, all within one month following the sludge removal operation. Several equipment modifications and various equipment repairs were made. 14 figures, 3 tables

Flammable gas tank waste level reconcilliation tank 241-SX-102

International Nuclear Information System (INIS)

Brevick, C.H.; Gaddie, L.A.

1997-01-01

Fluoro Dynel Northwest (FDNW) was authorized to address flammable gas issues by reconciling the unexplained surface level increases in Tank 24 1-S-1 1 1 (S-I 1 1, typical). The trapped gas evaluation document (ref 1) states that Tank SX-102 exceeds the 25% of the lower flammable limit (FL) criterion (ref 2), based on a surface level rise evaluation. The Waste Storage Tank Status and Leak Detection Criteria document, commonly referred to as the ''Wallet Report'' is the basis for this letter report (ref 3). The Wallet Report is also a part of the trapped gas evaluation document criteria. The Wallet Report contains various tank information, including: physical information, status, levels, and dry wells, see Appendix A. The unexplained waste level rises were attributed to the production and retention of gas in the column of waste corresponding to the unacquainted for surface level rise. From 1973 through 1980, the Wallet Report tracked Tank S- 102 transfers and reported a net cumulative change of 19.95 in. This surface level increase is from an unknown source or is unacquainted for. Duke Engineering and Services Hanford (DASH) and Leached Martin Hanford Corporation (LMHC) are interested in determining the validity of the unexplained surface level changes reported in the 0611e Wallet Report based upon other corroborative sources of data. The purpose of this letter report is to assemble detailed surface level and waste addition data from daily tank records, logbooks, and other corroborative data that indicate surface levels, and to reconcile the cumulative unacquainted for surface level changes as shown in the Wallet Report from 1973 through 1980

History of waste tank 16, 1959 through 1974

International Nuclear Information System (INIS)

Davis, T.L.; Tharin, D.W.; Jones, D.W.; Lohr, D.R.

1977-07-01

Tank 16 was placed in service as a receiver of fresh high heat waste (HW) on May 9, 1959, and was filled to capacity in May 1960. Approximately half the tank contents were transferred to tanks 14 and 15 during September and October 1960 because of leakage into the annulus. Use of tank 16 was resumed in October 1967 when authorization (TA 2-603) was obtained to receive LW, and the tank was filled to capacity by June 1968. Subsequently, supernate was removed from the tank, and a blend of fresh LW and evaporator bottoms was added. In March 1972, the supernate was transferred to tank 13 because leakage had resumed. The sludge was left in the tank bottom and the use of tank 16 for any additional waste storage was discontinued. In September 1960 liquid waste overflowed the annulus pan. Leakage essentially stopped after the tank liquid level was lowered below the middle horizontal weld. After exhaustive study, tank cracking and resultant leakage was concluded to have been caused by stress corrosion due to the action of NaOH or NaNO 3 on areas of high local stress in the steel plate such as welds. Samples of sludge, supernate, tank vapors, and leaked material in the annulus were analyzed, and tank temperature and radiation profiles were taken. Two disk samples were cut from the primary tank wall for metallurgical examination. Test coupons of various metals were exposed to tank 16 waste to aid new tank design and to study stress corrosion and hydrogen embrittlement. In addition, samples of SRP bedrock were placed in tank 16 to study reactions between bedrock and HW. 18 figures, 2 tables

History of waste tank 22, 1965--1974

International Nuclear Information System (INIS)

McNatt, F.G.

1979-04-01

Tank 22 (a 1,300,000-gallon Type IV tank) was placed in service June 6, 1965, receiving HW from tank 21. The HW was transferred back into tank 21 in September 1965 and fed to the Building 242-H evaporator. This recycled concentrate and concentrate from other waste was then received in tank 22 until the tank was filled. The HW concentrate and salt remained in the tank until November 1971 when removal was begun. The concentrated supernate was transferred from the tank followed by dissolution and removal of salt from the tank walls and bottom. The salt removal was completed in May 1974 and since that time tank 22 has served as a receiver of LW from Building 221-H. Inspections of the tank interior were made using a 40-ft optical periscope and the steel thickness of the tank bottom was measured ultrasonically. Samples of the tank vapors and liquid collected in the sidewall and bottom sumps were analyzed. Temperature and specific gravity measurements were made of waste stored in the tank. Several equipment modifications and repairs were made

Progress in evaluating the hazard of ferrocyanide waste storage tanks

International Nuclear Information System (INIS)

Babad, Harry; Cash, Robert J.; Postma, Arlin

1992-01-01

There are 177 high-level waste tanks on the Hanford site. Twenty-four single-shell tanks are identified as potential safety issues. These tanks contain quantities of ferrocyanide, nitrate, and nitrite salts that potentially could explode under certain conditions. Efforts were initiated in September 1990 to determine the reactive properties of the ferrocyanide waste and to define the criteria necessary to ensure tank safety until mitigation or remediation actions, if required, could be implemented. This paper describes the results of recent chemical and physical studies on synthetic ferrocyanide waste mixtures. Data obtained from monitoring, tank behavior modeling, and research studies on waste have provided sufficient understanding of the tank behavior. The Waste Tank Safety Program is exploring whether the waste in many of the ferrocyanide tanks actually represents an unreviewed safety question. The General Accounting Office (GAO) in October 1990 suggested that ferrocyanide tank accident scenarios exceed the bounds of the Hanford Environmental Impact Statement. Using the same assumptions Westinghouse Hanford Company (WHC) staff confirmed the consistency of the GAO report calculations. The hypothetical accident scenario in the GAO report, and in the EIS, are based on several assumptions that may, or may not reflect actual tank conditions. The Ferrocyanide Stabilization Program at Westinghouse Hanford (summarized in this paper) will provide updated and new data using scientific research with synthetic wastes and characterization of actual tank samples. This new information will replace the assumptions on tank waste chemical and physical properties allowing an improved recalculation of current safety and future risk associated with these tanks. (author)

Progress in evaluating the hazards of ferrocyanide waste storage tanks

International Nuclear Information System (INIS)

Babad, H.; Cash, R.; Postma, A.

1992-03-01

There are 177 high-level waste tanks on the Hanford site. Twenty-four single-shell tanks are identified as potential safety issues. These tanks contain quantities of ferrocyanide, nitrate, and nitrite salts that potentially could explode under certain conditions. Efforts were initiated in September 1990 to determine the reactive properties of the ferrocyanide waste and to define the criteria necessary to ensure tank safety until mitigation or remediation actions, if required, could be implemented. This paper describes the results of recent chemical and physical studies on synthetic ferrocyanide waste mixtures. Data obtained from monitoring, tank behavior modeling, and research studies on waste have provided sufficient understanding of the tank behavior. The Waste Tank Safety Program is exploring to determine whether the waste in many of the ferrocyanide tanks actually represents an unreviewed safety question. The General Accounting Office (GAO) in October 1990 (1) suggested that ferrocyanide-tanks accident scenarios exceed the bounds of the Hanford Environmental Impact Statement (2). Using the same assumptions Westinghouse Hanford Company (WHC) staff confirmed the consistency of the GAO report calculations. The hypothetical accident scenario in the GAO report, and in the EIS, are based on several assumptions that may, or may not reflect actual tank conditions. The Ferrocyanide Stabilization Program at Westinghouse Hanford (summarized in this paper) will provide updated and new data using scientific research with synthetic and actual waste tank characterization. This new information will replace the assumptions on tank waste chemical and physical properties allowing an improved recalculation of current safety and future risk associated with these tanks

1996 structural integrity assessments for the Category C Liquid Low-Level Waste Tank Systems at Oak Ridge National Laboratory, Oak Ridge, Tennessee

International Nuclear Information System (INIS)

1996-09-01

This document provides a report of the efforts made to satisfy the Federal Facility Agreement for the structural integrity certification of ten Category C Liquid Low Level Waste (LLLW) tank systems on the Oak Ridge Reservation in Oak Ridge, Tennessee. Within this document, each Category C tank system is described including the associated pipeline segments evaluated as a part of those tank systems. A separate structural integrity assessment was conducted for each of the LLLW Tank Systems, four of which are located in Melton Valley, and six of which are located in Bethel Valley. The results of the structural integrity assessments are reported herein. The assessments are based on (1) a review of available tank design drawings, (2) a qualitative assessment of corrosion on the tank and pipelines, and primarily (3) leak testing program results

1996 structural integrity assessments for the Category C Liquid Low-Level Waste Tank Systems at Oak Ridge National Laboratory, Oak Ridge, Tennessee

Energy Technology Data Exchange (ETDEWEB)

NONE

1996-09-01

This document provides a report of the efforts made to satisfy the Federal Facility Agreement for the structural integrity certification of ten Category C Liquid Low Level Waste (LLLW) tank systems on the Oak Ridge Reservation in Oak Ridge, Tennessee. Within this document, each Category C tank system is described including the associated pipeline segments evaluated as a part of those tank systems. A separate structural integrity assessment was conducted for each of the LLLW Tank Systems, four of which are located in Melton Valley, and six of which are located in Bethel Valley. The results of the structural integrity assessments are reported herein. The assessments are based on (1) a review of available tank design drawings, (2) a qualitative assessment of corrosion on the tank and pipelines, and primarily (3) leak testing program results.

Waste Tank Summary Report for Month Ending February 28 2001

International Nuclear Information System (INIS)

HANLON, B.M.

2001-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 63 smaller miscellaneous underground storage tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of U.S. Department of Energy-Richland Operations Office Order 435.I (DOE-RL, July 1999, Radioactive Waste Management, U.S. Department of Energy-Richland Operations Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm tanks

Underground storage tank soft waste dislodging and conveyance

International Nuclear Information System (INIS)

Wellner, A.F.S.

1993-01-01

The primary objective of this task is to demonstrate potential technical solutions and to acquire engineering data and information on the retrieval technologies applicable for use in retrieving waste from underground storage tanks. This task focuses on soft waste dislodging and conveyance technologies that would be used in conjunction with a manipulator-based retrieval system. This retrieval task focuses on Hanford single-shell tanks, but the results may also have applications to other waste retrieval problems. This work is part of the U.S. Department of Energy's (DOE's) Office of Technology Development, sponsored by the DOE's Richland Operations Office under the Underground Storage Tanks Integrated Demonstration (USTID) program. This task is one element of the whole waste dislodging and conveyance system in the USTID. The tank wastes contain both hazardous and radioactive constituents. This task focuses on the processes for dislodging and retrieving soft wastes, mainly sludge. Sludge consists primarily of heavy-metal, iron, and aluminum precipitates. Sludges vary greatly in their physical properties and may contain pockets of liquid. Sludges have been described as varying in consistency from thick slurry to sticky clay and as sandy with hard chunks of material. The waste is believed to have adhesive and cohesive properties. The quantitative physical properties of the wastes have yet to be measured. The waste simulants used in the testing program emulate the physical properties of the tank waste

Headspace gas and vapor characterization summary for the 43 vapor program suspect tanks

International Nuclear Information System (INIS)

Huckaby, J.L.; Bratzel, D.R.

1995-01-01

During the time period between February 1994 and September 1995, Westinghouse Hanford Company (WHC) sampled the waste tank headspace of 43 single-shell tanks for a variety of gaseous and/or volatile and semi-volatile compounds. This report summarizes the results of analyses of those sampling activities with respect to both the Priority 1 Safety Issues and relative to the detection in the headspace of significant concentrations of target analytes relating to worker breathing space consideration as recommended by the Pacific Northwest Laboratory (PNL) Toxicology Review Panel. The information contained in the data tables was abstracted from the vapor sampling and analysis tank characterization reports. Selected results are tabulated and summarized. Sampling equipment and methods, as well as sample analyses, are briefly described. Vapor sampling of passively ventilated single-shell tanks (tanks C-105, C-106, and SX-106 were sampled and are actively ventilated) has served to highlight or confirm tank headspace conditions associated with both priority 1 safety issues and supports source term analysis associated with protecting worker health and safety from noxious vapors

Tank waste remediation system tank waste retrieval risk management plan

International Nuclear Information System (INIS)

Klimper, S.C.

1997-01-01

This Risk Management Plan defines the approach to be taken to manage programmatic risks in the TWRS Tank Waste Retrieval program. It provides specific instructions applicable to TWR, and is used to supplement the guidance given by the TWRS Risk Management procedure

Tank 241-U-106, cores 147 and 148, analytical results for the final report

Energy Technology Data Exchange (ETDEWEB)

Steen, F.H.

1996-09-27

This document is the final report deliverable for tank 241-U-106 push mode core segments collected between May 8, 1996 and May 10, 1996 and received by the 222-S Laboratory between May 14, 1996 and May 16, 1996. The segments were subsampled and analyzed in accordance with the Tank 241-U-106 Push Mode Core Sampling and analysis Plan (TSAP), the Historical Model Evaluation Data Requirements (Historical DQO), Data Quality Objective to Support Resolution of the Organic Complexant Safety Issue (Organic DQO) and the Safety Screening Data Quality Objective (DQO). The analytical results are included in Table 1.

Tank vapor characterization project - headspace vapor characterization of Hanford Waste Tank 241-C-107: Second comparison study results from samples collected on 3/26/96

International Nuclear Information System (INIS)

Evans, J.C.; Pool, K.H.; Thomas, B.L.

1997-01-01

This report describes the analytical results of vapor samples taken from the headspace of waste storage tank 241-C-107 (Tank C-107) at the Hanford Site in Washington State. The results described in this report is the second in a series comparing vapor sampling of the tank headspace using the Vapor Sampling System (VSS) and In Situ Vapor Sampling (ISVS) system without high efficiency particulate air (HEPA) prefiltration. The results include air concentrations of water (H 2 O) and ammonia (NH 3 ), permanent gases, total non-methane organic compounds (TO-12), and individual organic analytes collected in SUMMA trademark canisters and on triple sorbent traps (TSTs). Samples were collected by Westinghouse Hanford Company (WHC) and analyzed by Pacific Northwest National Laboratory (PNNL). Analyses were performed by the Vapor Analytical Laboratory (VAL) at PNNL. Analyte concentrations were based on analytical results and, where appropriate, sample volume measurements provided by WHC

Effects of hydrated lime on radionuclides stabilization of Hanford tank residual waste.

Science.gov (United States)

Wang, Guohui; Um, Wooyong; Cantrell, Kirk J; Snyder, Michelle M V; Bowden, Mark E; Triplett, Mark B; Buck, Edgar C

2017-10-01

Chemical stabilization of tank residual waste is part of a Hanford Site tank closure strategy to reduce overall risk levels to human health and the environment. In this study, a set of column leaching experiments using tank C-104 residual waste were conducted to evaluate the leachability of uranium (U) and technetium (Tc) where grout and hydrated lime were applied as chemical stabilizing agents. The experiments were designed to simulate future scenarios where meteoric water infiltrates through the vadose zones into the interior of the tank filled with layers of grout or hydrated lime, and then contacts the residual waste. Effluent concentrations of U and Tc were monitored and compared among three different packing columns (waste only, waste + grout, and waste + grout + hydrated lime). Geochemical modeling of the effluent compositions was conducted to determine saturation indices of uranium solid phases that could control the solubility of uranium. The results indicate that addition of hydrated lime strongly stabilized the uranium through transforming uranium to a highly insoluble calcium uranate (CaUO 4 ) or similar phase, whereas no significant stabilization effect of grout or hydrated lime was observed on Tc leachability. The result implies that hydrated lime could be a great candidate for stabilizing Hanford tank residual wastes where uranium is one of the main concerns. Published by Elsevier Ltd.

Estimating retained gas volumes in the Hanford tanks using waste level measurements

International Nuclear Information System (INIS)

Whitney, P.D.; Chen, G.; Gauglitz, P.A.; Meyer, P.A.; Miller, N.E.

1997-09-01

The Hanford site is home to 177 large, underground nuclear waste storage tanks. Safety and environmental concerns surround these tanks and their contents. One such concern is the propensity for the waste in these tanks to generate and trap flammable gases. This report focuses on understanding and improving the quality of retained gas volume estimates derived from tank waste level measurements. While direct measurements of gas volume are available for a small number of the Hanford tanks, the increasingly wide availability of tank waste level measurements provides an opportunity for less expensive (than direct gas volume measurement) assessment of gas hazard for the Hanford tanks. Retained gas in the tank waste is inferred from level measurements -- either long-term increase in the tank waste level, or fluctuations in tank waste level with atmospheric pressure changes. This report concentrates on the latter phenomena. As atmospheric pressure increases, the pressure on the gas in the tank waste increases, resulting in a level decrease (as long as the tank waste is open-quotes softclose quotes enough). Tanks with waste levels exhibiting fluctuations inversely correlated with atmospheric pressure fluctuations were catalogued in an earlier study. Additionally, models incorporating ideal-gas law behavior and waste material properties have been proposed. These models explicitly relate the retained gas volume in the tank with the magnitude of the waste level fluctuations, dL/dP. This report describes how these models compare with the tank waste level measurements

Evaluation of fourier transform profilometry performance: quantitative waste volume determination under simulated Hanford waste tank conditions

International Nuclear Information System (INIS)

Jang, Ping-Rey; Leone, Teresa; Long, Zhiling; Mott, Melissa A.; Perry Norton, O.; Okhuysen, Walter P.; Monts, David L.

2007-01-01

The Hanford Site is currently in the process of an extensive effort to empty and close its radioactive single-shell and double-shell waste storage tanks. Before this can be accomplished, it is necessary to know how much residual material is left in a given waste tank and the chemical makeup of the residue. The objective of Mississippi State University's Institute for Clean Energy Technology's (ICET) efforts is to develop, fabricate, and deploy inspection tools for the Hanford waste tanks that will (1) be remotely operable; (2) provide quantitative information on the amount of wastes remaining; and (3) provide information on the spatial distribution of chemical and radioactive species of interest. A collaborative arrangement has been established with the Hanford Site to develop probe-based inspection systems for deployment in the waste tanks. ICET is currently developing an in-tank inspection system based on Fourier Transform Profilometry, FTP. FTP is a non-contact, 3-D shape measurement technique. By projecting a fringe pattern onto a target surface and observing its deformation due to surface irregularities from a different view angle, FTP is capable of determining the height (depth) distribution (and hence volume distribution) of the target surface, thus reproducing the profile of the target accurately under a wide variety of conditions. Hence FTP has the potential to be utilized for quantitative determination of residual wastes within Hanford waste tanks. We have completed a preliminary performance evaluation of FTP in order to document the accuracy, precision, and operator dependence (minimal) of FTP under conditions similar to those that can be expected to pertain within Hanford waste tanks. Based on a Hanford C-200 series tank with camera access through a riser with significant offset relative to the centerline, we devised a testing methodology that encompassed a range of obstacles likely to be encountered 'in tank'. These test objects were inspected by use

1990 waste tank inspection program

International Nuclear Information System (INIS)

McNatt, F.G.

1990-01-01

Aqueous radioactive wastes from Savannah River Site separations processes are contained in large underground carbon steel tanks. Tank conditions are evaluated by inspection using periscopes, still photography, and video systems for visual imagery. Inspections made in 1990 are the subject of this report

PROGRESS & CHALLENGES IN CLEANUP OF HANFORDS TANK WASTES

Energy Technology Data Exchange (ETDEWEB)

HEWITT, W.M.; SCHEPENS, R.

2006-01-23

The River Protection Project (RPP), which is managed by the Department of Energy (DOE) Office of River Protection (ORP), is highly complex from technical, regulatory, legal, political, and logistical perspectives and is the largest ongoing environmental cleanup project in the world. Over the past three years, ORP has made significant advances in its planning and execution of the cleanup of the Hartford tank wastes. The 149 single-shell tanks (SSTs), 28 double-shell tanks (DSTs), and 60 miscellaneous underground storage tanks (MUSTs) at Hanford contain approximately 200,000 m{sup 3} (53 million gallons) of mixed radioactive wastes, some of which dates back to the first days of the Manhattan Project. The plan for treating and disposing of the waste stored in large underground tanks is to: (1) retrieve the waste, (2) treat the waste to separate it into high-level (sludge) and low-activity (supernatant) fractions, (3) remove key radionuclides (e.g., Cs-137, Sr-90, actinides) from the low-activity fraction to the maximum extent technically and economically practical, (4) immobilize both the high-level and low-activity waste fractions by vitrification, (5) interim store the high-level waste fraction for ultimate disposal off-site at the federal HLW repository, (6) dispose the low-activity fraction on-site in the Integrated Disposal Facility (IDF), and (7) close the waste management areas consisting of tanks, ancillary equipment, soils, and facilities. Design and construction of the Waste Treatment and Immobilization Plant (WTP), the cornerstone of the RPP, has progressed substantially despite challenges arising from new seismic information for the WTP site. We have looked closely at the waste and aligned our treatment and disposal approaches with the waste characteristics. For example, approximately 11,000 m{sup 3} (2-3 million gallons) of metal sludges in twenty tanks were not created during spent nuclear fuel reprocessing and have low fission product concentrations. We

Maintenance study for W-340 Waste Retrieval System

International Nuclear Information System (INIS)

Christensen, C.; Conner, C.C.; Sekot, J.P.

1994-05-01

This study was performed to identify attributes and maintainability requirements for the Tank Waste Retrieval System (TWRS). The system will be developed for Westinghouse Hanford Company in Richland, Washington, as an integrated system to perform waste removal in Tank C-106 and, thus, demonstrate technologies for tank remediation that will satisfy requirements of the Tri-Party Agreement. The study examines attributes of the TWRS, scope of maintenance operations required for the TWRS, maintenance requirements, and potential methods of performing maintenance functions. Recommendations are provided for consideration in the development of both the conceptual design and performance specification, which will be used in procuring the W-340 Waste Retrieval System

Summary of tank waste physical properties at the Hanford Site

International Nuclear Information System (INIS)

Nguyen, Q.H.

1994-04-01

This report summarizes the physical parameters measured from Hanford Site tank wastes. Physical parameters were measured to determine the physical nature of the tank wastes to develop simulants and design in-tank equipment. The physical parameters were measured mostly from core samples obtained directly below tank risers. Tank waste physical parameters were collected through a database search, interviewing and selecting references from documents. This report shows the data measured from tank waste but does not describe how the analyses wee done. This report will be updated as additional data are measured or more documents are reviewed

Tank Farm Contractor Waste Remediation System and Utilization Plan

International Nuclear Information System (INIS)

KIRKBRIDE, R.A.

1999-01-01

The Tank Waste Remediation System Operation and Utilization Plan updates the operating scenario and plans for the delivery of feed to BNFL Inc., retrieval of waste from single-shell tanks, and the overall process flowsheets for Phases I and II of the privatization of the Tank Waste Remediation System. The plans and flowsheets are updated with the most recent tank-by-tank inventory and sludge washing data. Sensitivity cases were run to evaluate the impact or benefits of proposed changes to the BNFL Inc. contract and to evaluate a risk-based SST retrieval strategy

Tank Space Options Report

International Nuclear Information System (INIS)

BOYLES, V.C.

2001-01-01

A risk-based priority for the retrieval of Hanford Site waste from the 149 single-shell tanks (SSTs) has been adopted as a result of changes to the Hanford Federal Facility Agreement and Consent Order (HFFACO) (Ecology et al. 1997) negotiated in 2000. Retrieval of the first three tanks in the retrieval sequence fills available capacity in the double-shell tanks (DSTs) by 2007. As a result, the HFFACO change established a milestone (M-45-12-TO1) requiring the determination of options that could increase waste storage capacity for single-shell tank waste retrieval. The information will be considered in future negotiations. This document fulfills the milestone requirement. This study presents options that were reviewed for the purpose of increasing waste storage capacity. Eight options are identified that have the potential for increasing capacity from 5 to 10 million gallons, thus allowing uninterrupted single-shell tank retrieval until the planned Waste Treatment Plant begins processing substantial volumes of waste from the double-shell tanks in 2009. The cost of implementing these options is estimated to range from less than $1 per gallon to more than $14 per gallon. Construction of new double-shell tanks is estimated to cost about $63 per gallon. Providing 5 to 10 million gallons of available double-shell tank space could enable early retrieval of 5 to 9 high-risk single-shell tanks beyond those identified for retrieval by 2007. These tanks are A-101, AX-101, AX-103, BY-102, C-107, S-105, S-106, S-108, and S-109 (Garfield et al. 2000). This represents a potential to retrieve approximately 14 million total curies, including 3,200 curies of long-lived mobile radionuclides. The results of the study reflect qualitative analyses conducted to identify promising options. The estimated costs are rough-order-of magnitude and, therefore, subject to change. Implementing some of the options would represent a departure from the current baseline and may adversely impact the

Chemistry of application of calcination/dissolution to the Hanford tank waste inventory

International Nuclear Information System (INIS)

Delegard, C.H.; Elcan, T.D.; Hey, B.E.

1994-05-01

Approximately 330,000 metric tons of sodium-rich radioactive waste originating from separation of plutonium from irradiated uranium fuel are stored in underground tanks at the Hanford Site in Washington State. Fractionation of the waste into low-level waste (LLW) and high-level waste (HLW) streams is envisioned via partial water dissolution and limited radionuclide extraction operations. Under optimum conditions, LLW would contain most of the chemical bulk while HLW would contain virtually all of the transuranic and fission product activity. Calcination at around 850 C, followed by water dissolution, has been proposed as an alternative initial treatment of Hanford Site waste to improve waste dissolution and the envisioned LLW/HLW split. Results of literature and laboratory studies are reported on the application of calcination/dissolution (C/D) to the fractionation of the Hanford Site tank waste inventory. Both simulated and genuine Hanford Site waste materials were used in the lab tests. To evaluation confirmed that C/D processing reduced the amount of several components from the waste. The C/D dissolutions of aluminum and chromium allow redistribution of these waste components from the HLW to the LLW fraction. Comparisons of simple water-washing with C/D processing of genuine Hanford Site waste are also reported based on material (radionuclide and chemical) distributions to solution and solid residue phases. The lab results show that C/D processing yielded superior dissolution of aluminum and chromium sludges compared to simple water dissolution. 57 refs., 26 figs., 18 tabs

Chemistry of application of calcination/dissolution to the Hanford tank waste inventory

Energy Technology Data Exchange (ETDEWEB)

Delegard, C.H.; Elcan, T.D.; Hey, B.E.

1994-05-01

Approximately 330,000 metric tons of sodium-rich radioactive waste originating from separation of plutonium from irradiated uranium fuel are stored in underground tanks at the Hanford Site in Washington State. Fractionation of the waste into low-level waste (LLW) and high-level waste (HLW) streams is envisioned via partial water dissolution and limited radionuclide extraction operations. Under optimum conditions, LLW would contain most of the chemical bulk while HLW would contain virtually all of the transuranic and fission product activity. Calcination at around 850 C, followed by water dissolution, has been proposed as an alternative initial treatment of Hanford Site waste to improve waste dissolution and the envisioned LLW/HLW split. Results of literature and laboratory studies are reported on the application of calcination/dissolution (C/D) to the fractionation of the Hanford Site tank waste inventory. Both simulated and genuine Hanford Site waste materials were used in the lab tests. To evaluation confirmed that C/D processing reduced the amount of several components from the waste. The C/D dissolutions of aluminum and chromium allow redistribution of these waste components from the HLW to the LLW fraction. Comparisons of simple water-washing with C/D processing of genuine Hanford Site waste are also reported based on material (radionuclide and chemical) distributions to solution and solid residue phases. The lab results show that C/D processing yielded superior dissolution of aluminum and chromium sludges compared to simple water dissolution. 57 refs., 26 figs., 18 tabs.

Ferrocyanide safety program: Heat load and thermal characteristics determination for selected tanks

International Nuclear Information System (INIS)

McLaren, J.M.; Cash, R.J.

1993-11-01

An analysis was conducted to determine the heat loads, conductivities, and heat distributions of waste tanks 241-BY-105, -106, -108, -110, -111, and 241-C-109 at the Hanford Site. The heat distribution of tank 241-BY-111 was determined to be homogeneously distributed throughout the sludge contained in the tank. All of the other tanks, with the exception of 241-C-109, showed evidence of a heat-producing layer at the bottom of the tanks. No evidence of a heat-producing layer in a position above the bottom was found. The thermal conductivities were determined to be within the ranges found by previous laboratory and computer analysis. The heat loads of the tanks were found to be below 2.81 kW (9,600 Btu/hr)

Application of value of information of tank waste characterization: A new paradigm for defining tank waste characterization requirements

International Nuclear Information System (INIS)

Fassbender, L.L.; Brewster, M.E.; Brothers, A.J.

1996-11-01

This report presents the rationale for adopting a recommended characterization strategy that uses a risk-based decision-making framework for managing the Tank Waste Characterization program at Hanford. The risk-management/value-of-information (VOI) strategy that is illustrated explicitly links each information-gathering activity to its cost and provides a mechanism to ensure that characterization funds are spent where they can produce the largest reduction in risk. The approach was developed by tailoring well-known decision analysis techniques to specific tank waste characterization applications. This report illustrates how VOI calculations are performed and demonstrates that the VOI approach can definitely be used for real Tank Waste Remediation System (TWRS) characterization problems

Application of value of information of tank waste characterization: A new paradigm for defining tank waste characterization requirements

Energy Technology Data Exchange (ETDEWEB)

Fassbender, L.L.; Brewster, M.E.; Brothers, A.J. [and others

1996-11-01

This report presents the rationale for adopting a recommended characterization strategy that uses a risk-based decision-making framework for managing the Tank Waste Characterization program at Hanford. The risk-management/value-of-information (VOI) strategy that is illustrated explicitly links each information-gathering activity to its cost and provides a mechanism to ensure that characterization funds are spent where they can produce the largest reduction in risk. The approach was developed by tailoring well-known decision analysis techniques to specific tank waste characterization applications. This report illustrates how VOI calculations are performed and demonstrates that the VOI approach can definitely be used for real Tank Waste Remediation System (TWRS) characterization problems.

Waste tank characterization sampling limits

International Nuclear Information System (INIS)

Tusler, L.A.

1994-01-01

This document is a result of the Plant Implementation Team Investigation into delayed reporting of the exotherm in Tank 241-T-111 waste samples. The corrective actions identified are to have immediate notification of appropriate Tank Farm Operations Shift Management if analyses with potential safety impact exceed established levels. A procedure, WHC-IP-0842 Section 12.18, ''TWRS Approved Sampling and Data Analysis by Designated Laboratories'' (WHC 1994), has been established to require all tank waste sampling (including core, auger and supernate) and tank vapor samples be performed using this document. This document establishes levels for specified analysis that require notification of the appropriate shift manager. The following categories provide numerical values for analysis that may indicate that a tank is either outside the operating specification or should be evaluated for inclusion on a Watch List. The information given is intended to translate an operating limit such as heat load, expressed in Btu/hour, to an analysis related limit, in this case cesium-137 and strontium-90 concentrations. By using the values provided as safety flags, the analytical laboratory personnel can notify a shift manager that a tank is in potential violation of an operating limit or that a tank should be considered for inclusion on a Watch List. The shift manager can then take appropriate interim measures until a final determination is made by engineering personnel

Tank Bump Accident Potential and Consequences During Waste Retrieval

International Nuclear Information System (INIS)

BRATZEL, D.R.

2000-01-01

This report provides an evaluation of Hanford tank bump accident potential and consequences during waste retrieval operations. The purpose of this report is to consider the best available new information to support recommendations for safety controls. A new tank bump accident analysis for safe storage (Epstein et al. 2000) is extended for this purpose. A tank bump is a postulated event in which gases, consisting mostly of water vapor, are suddenly emitted from the waste and cause tank headspace pressurization. Tank bump scenarios, physical models, and frequency and consequence methods are fully described in Epstein et al. (2000). The analysis scope is waste retrieval from double-shell tanks (DSTs) including operation of equipment such as mixer pumps and air lift circulators. The analysis considers physical mechanisms for tank bump to formulate criteria for bump potential during retrieval, application of the criteria to the DSTs, evaluation of bump frequency, and consequence analysis of a bump. The result of the consequence analysis is the mass of waste released from tanks; radiological dose is calculated using standard methods (Cowley et al. 2000)

Optimization of quantitative waste volume determination technique for hanford waste tank closure

International Nuclear Information System (INIS)

Monts, David L.; Jang, Ping-Rey; Long, Zhiling; Okhuysen, Walter P.; Norton, Olin P.; Gresham, Lawrence L.; Su, Yi; Lindner, Jeffrey S.

2011-01-01

The Hanford Site is currently in the process of an extensive effort to empty and close its radioactive single-shell and double-shell waste storage tanks. Before this can be accomplished, it is necessary to know how much residual material is left in a given waste tank and the uncertainty with which that volume is known. The Institute for Clean Energy Technology (ICET) at Mississippi State University is currently developing a quantitative in-tank imaging system based on Fourier Transform Profilometry, FTP. FTP is a non-contact, 3-D shape measurement technique. By projecting a fringe pattern onto a target surface and observing its deformation due to surface irregularities from a different view angle, FTP is capable of determining the height (depth) distribution (and hence volume distribution) of the target surface, thus reproducing the profile of the target accurately under a wide variety of conditions. Hence FTP has the potential to be utilized for quantitative determination of residual wastes within Hanford waste tanks. In this paper, efforts to characterize the accuracy and precision of quantitative volume determination using FTP and the use of these results to optimize the FTP system for deployment within Hanford waste tanks are described. (author)

Mathematical model of the Savannah River Site waste tank farm

International Nuclear Information System (INIS)

Smith, F.G. III.

1991-01-01

A mathematical model has been developed to simulate operation of the waste tank farm and the associated evaporator systems at the Savannah River Site. The model solves material balance equations to predict the volumes of liquid waste, salt, and sludge for all of the tanks within each of the evaporator systems. Additional logic is included to model the behavior of waste tanks not directly associated with the evaporators. Input parameters include the Material Management Plan forecast of canyon operations, specification of other waste sources for the evaporator systems, evaporator operating characteristics, and salt and sludge removal schedules. The model determines how the evaporators will operate, when waste transfers can be made, and waste accumulation rates. Output from the model includes waste tank contents, summaries of systems operations, and reports of space gain and the remaining capacity to store waste materials within the tank farm. Model simulations can be made to predict waste tank capacities on a daily basis for up to 20 years. The model is coded as a set of three computer programs designed to run on either IBM compatible or Apple Macintosh II personal computers

Extraction of technetium from simulated Hanford tank wastes

International Nuclear Information System (INIS)

Chaiko, D.J.; Vojta, Y.; Takeuchi, M.

1993-01-01

Aqueous biphasic separation systems are being developed for the treatment of liquid radioactive wastes. These extraction systems are based on the use of polyethylene glycols (PEGs) for the selective extraction and recovery of long-lived radionuclides, such as 129 I, 75 Se, and 99 Tc, from caustic solutions containing high concentrations of nitrate, nitrite, and carbonate. Because of the high ionic strengths of supernatant liquids in Hanford underground storage tanks, aqueous biphasic systems can be generated by simply adding aqueous PEG solutions directly to the waste solution. In the process, anionic species like I - and TcO 4 - are selectively transferred to the less dense PEG phase. The partition coefficient for a wide range of inorganic cations and anions, such as sodium, potassium, aluminum, nitrate, nitrate, and carbonate, are all less than one. The authors present experimental data on extraction of technetium from several simulated Hanford tank wastes at 25 degree and 50 degree C

Data quality objectives lessons learned for tank waste characterization

International Nuclear Information System (INIS)

Eberlein, S.J.

1996-01-01

The tank waste characterization process is an integral part of the overall effort to control the hazards associated with radioactive wastes stored in underground tanks at the Hanford Reservation. The programs involved in the characterization of the wastes are employing Data Quality Objective (DQO) process in all information and data collection activities. The DQO process is used by the programs to address an issue or problem rather than a specific sampling event. Practical limits do not always allow for precise characterization of a tank or the implementation of the DQO process. Because of the flexibility of the DQO process, it can be used as a tool for sampling and analysis of the underground waste storage tanks. The iterative nature of the DQO process allows it to be used as additional information is claimed or lessons are learned concerning an issue or problem requiring sampling and analysis of tank waste. In addition, the application of DQO process forces alternative actions to be considered when precise characterization of a tank or the full implementation of the DQO process is not practical

History of waste tank 1, 1954 through 1974

International Nuclear Information System (INIS)

McNatt, F.G.; Stevens, W.E.

1978-10-01

Tank 1 was placed in service as a receiver of high heat waste (HW) in October 1954. The supernate was removed from the tank in October 1961 and the tank began receiving low heat waste (LW) in January 1962. The LW supernate was decanted in October 1962 and prior to beginning a second HW filling in April 1963. The supernate from this HW filling was decanted twice in 1969. Sludge removal operations were conducted in May and August 1969 in order to use tank 1 for salt storage. The first evaporator concentrate receipt was in September 1969 and tank 1 has only been used as a salt storage tank since. Leakage from the tank into the annulus was discovered in February 1969. Deposits less than 1/4 inch deep of leaked waste were found on the pan floor. However, no leak sites have been found. Inspections of the tank interior and annulus were made by direct observation and by using a 40-ft optical periscope. Samples of sludge, supernate, tank vapors, and leaked material into the annulus were analyzed and tank temperature profiles were taken. Deflection measurements were made of the primary tank bottom knuckle plate while filling the tank with salt. Two vertical cooling coils have failed. Several equipment modifications and various equipment repairs were made. 18 figures, 2 tables

Underground storage tank integrated demonstration: Evaluation of pretreatment options for Hanford tank wastes

International Nuclear Information System (INIS)

Lumetta, G.J.; Wagner, M.J.; Colton, N.G.; Jones, E.O.

1993-06-01

Separation science plays a central role inn the pretreatment and disposal of nuclear wastes. The potential benefits of applying chemical separations in the pretreatment of the radioactive wastes stored at the various US Department of Energy sites cover both economic and environmental incentives. This is especially true at the Hanford Site, where the huge volume (>60 Mgal) of radioactive wastes stored in underground tanks could be partitioned into a very small volume of high-level waste (HLW) and a relatively large volume of low-level waste (LLW). The cost associated with vitrifying and disposing of just the HLW fraction in a geologic repository would be much less than those associated with vitrifying and disposing of all the wastes directly. Futhermore, the quality of the LLW form (e.g., grout) would be improved due to the lower inventory of radionuclides present in the LLW stream. In this report, we present the results of an evaluation of the pretreatment options for sludge taken from two different single-shell tanks at the Hanford Site-Tanks 241-B-110 and 241-U-110 (referred to as B-110 and U-110, respectively). The pretreatment options examined for these wastes included (1) leaching of transuranic (TRU) elements from the sludge, and (2) dissolution of the sludge followed by extraction of TRUs and 90 Sr. In addition, the TRU leaching approach was examined for a third tank waste type, neutralized cladding removal waste

Development of simulated tank wastes for the US Department of Energy's Underground Storage Tank Integrated Demonstration

International Nuclear Information System (INIS)

Elmore, M.R.; Colton, N.G.; Jones, E.O.

1992-08-01

The purpose of the Underground Storage Tank Integrated Demonstration (USTID) is to identify and evaluate technologies that may be used to characterize, retrieve, treat, and dispose of hazardous and radioactive wastes contained in tanks on US Department of Energy sites. Simulated wastes are an essential component of the evaluation process because they provide controlled samples for technology assessment, and minimize costs and risks involved when working with radioactive wastes. Pacific Northwest Laboratory has developed a recipe to simulate Hanford single-shell tank, (SST) waste. The recipe is derived from existing process recipes, and elemental concentrations are based on characterization data from 18 SSTs. In this procedure, salt cake and metal oxide/hydroxide sludge are prepared individually, and mixed together at varying ratios depending on the specific tank, waste to be simulated or the test being conducted. Elemental and physical properties of the stimulant are comparable with analyzed tank samples, and chemical speciation in the simulant is being improved as speciation data for actual wastes become available. The nonradioactive chemical waste simulant described here is useful for testing technologies on a small scale

The Gunite and Associated Tanks Remediation Project Tank Waste Retrieval Performance and Lessons Learned, vol. 1 [of 2

Energy Technology Data Exchange (ETDEWEB)

Lewis, BE

2003-10-07

The Gunite and Associated Tanks (GAAT) Remediation Project was the first of its kind performed in the United States. Robotics and remotely operated equipment were used to successfully transfer almost 94,000 gal of remote-handled transuranic sludge containing over 81,000 Ci of radioactive contamination from nine large underground storage tanks at the Oak Ridge National Laboratory (ORNL). The sludge was transferred with over 439,000 gal of radioactive waste supernatant and {approx}420,500 gal of fresh water that was used in sluicing operations. The GAATs are located in a high-traffic area of ORNL near a main thoroughfare. A phased and integrated approach to waste retrieval operations was used for the GAAT Remediation Project. The project promoted safety by obtaining experience from low-risk operations in the North Tank Farm before moving to higher-risk operations in the South Tank Farm. This approach allowed project personnel to become familiar with the tanks and waste, as well as the equipment, processes, procedures, and operations required to perform successful waste retrieval. By using an integrated approach to tank waste retrieval and tank waste management, the project was completed years ahead of the original baseline schedule, which resulted in avoiding millions of dollars in associated costs. This report is organized in two volumes. Volume 1 provides information on the various phases of the GAAT Remediation Project. It also describes the different types of equipment and how they were used. The emphasis of Volume 1 is on the description of the tank waste retrieval performance and the lessons learned during the GAAT Remediation Project. Volume 2 provides the appendixes for the report, which include the following information: (A) Background Information for the Gunite and Associated Tanks Operable Unit; (B) Annotated Bibliography; (C) Comprehensive Listing of the Sample Analysis Data from the GAAT Remediation Project; (D) GAAT Equipment Matrix; and (E) Vendor List

Decision Document for Heat Removal from High-Level Waste Tanks

International Nuclear Information System (INIS)

WILLIS, W.L.

2000-01-01

This document establishes the combination of design and operational configurations that will be used to provide heat removal from high-level waste tanks during Phase 1 waste feed delivery to prevent the waste temperature from exceeding tank safety requirement limits. The chosen method--to use the primary and annulus ventilation systems to remove heat from the high-level waste tanks--is documented herein

Modeling water retention of sludge simulants and actual saltcake tank wastes

International Nuclear Information System (INIS)

Simmons, C.S.

1996-07-01

The Ferrocyanide Tanks Safety Program managed by Westinghouse hanford Company has been concerned with the potential combustion hazard of dry tank wastes containing ferrocyanide chemical in combination with nitrate salts. Pervious studies have shown that tank waste containing greater than 20 percent of weight as water could not be accidentally ignited. Moreover, a sustained combustion could not be propagated in such a wet waste even if it contained enough ferrocyanide to burn. Because moisture content is a key critical factor determining the safety of ferrocyanide-containing tank wastes, physical modeling was performed by Pacific Northwest National laboratory to evaluate the moisture-retaining behavior of typical tank wastes. The physical modeling reported here has quantified the mechanisms by which two main types of tank waste, sludge and saltcake, retain moisture in a tank profile under static conditions. Static conditions usually prevail after a tank profile has been stabilized by pumping out any excess interstitial liquid, which is not naturally retained by the waste as a result of physical forces such as capillarity

Tank farm surveillance and waste status report for July 1991

International Nuclear Information System (INIS)

Hanlon, B.M.

1991-09-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. The intent of the report is to provide data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and to provide supplemental information regarding tank surveillance anomalies and ongoing investigations. 1 fig., 8 tabs

Salt removal from tanks containing high-level radioactive waste

International Nuclear Information System (INIS)

Kiser, D.L.

1981-01-01

At the Savannah River Plant (SRP), there are 23 waste storage tanks containing high-level radioactive wastes that are to be retired. These tanks contain about 23 million liters of salt and about 10 million liters of sludge, that are to be relocated to new Type III, fully stress-relieved tanks with complete secondary containment. About 19 million liters of salt cake are to be dissolved. Steam jet circulators were originally proposed for the salt dissolution program. However, use of steam jet circulators raised the temperature of the tank contents and caused operating problems. These included increased corrosion risk and required long cooldown periods prior to transfer. Alternative dissolution concepts were investigated. Examination of mechanisms affecting salt dissolution showed that the ability of fresh water to contact the cake surface was the most significant factor influencing dissolution rate. Density driven and mechanical agitation techniques were developed on a bench scale and then were demonstrated in an actual waste tank. Actual waste tank demonstrations were in good agreement with bench-scale experiments at 1/85 scale. The density driven method utilizes simple equipment, but leaves a cake heel in the tank and is hindered by the presence of sludge or Zeolite in the salt cake. Mechanical agitation overcomes the problems found with both steam jet circulators and the density driven technique and is the best method for future waste tank salt removal

Tank farm surveillance and waste status summary report for October 1992

International Nuclear Information System (INIS)

Hanlon, B.M.

1993-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for January 1993

International Nuclear Information System (INIS)

Hanlon, B.M.

1993-03-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for November 1992

International Nuclear Information System (INIS)

Hanlon, B.M.

1993-02-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank Farm surveillance and waste status summary report for September 1993

International Nuclear Information System (INIS)

Hanlon, B.M.

1994-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for October 1992

Energy Technology Data Exchange (ETDEWEB)

Hanlon, B.M.

1993-01-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks.

Tank farm surveillance and waste status summary report for May 1994

Energy Technology Data Exchange (ETDEWEB)

Hanlon, B.M.

1994-08-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks.

Tank farm surveillance and waste status summary report for June 1993

International Nuclear Information System (INIS)

Hanlon, B.M.

1993-10-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for May 1994

International Nuclear Information System (INIS)

Hanlon, B.M.

1994-08-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter 1, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for December 1992

International Nuclear Information System (INIS)

Hanlon, B.M.

1993-02-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks

Tank farm surveillance and waste status summary report for December 1993

Energy Technology Data Exchange (ETDEWEB)

Hanlon, B.M.

1994-05-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special 9 surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of U.S. Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, U.S. Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks.

Tank farm surveillance and waste status summary report for December 1992

Energy Technology Data Exchange (ETDEWEB)

Hanlon, B.M.

1993-02-01

This report is the official inventory for radioactive waste stored in underground tanks in the 200 Areas at the Hanford Site. Data that depict the status of stored radioactive waste and tank vessel integrity are contained within the report. This report provides data on each of the existing 177 large underground waste storage tanks and 49 smaller catch tanks and special surveillance facilities, and supplemental information regarding tank surveillance anomalies and ongoing investigations. This report is intended to meet the requirement of US Department of Energy-Richland Operations Office Order 5820.2A, Chapter I, Section 3.e. (3) (DOE-RL, 1990, Radioactive Waste Management, US Department of Energy-Richland Operation Office, Richland, Washington) requiring the reporting of waste inventories and space utilization for Hanford Tank Farm Tanks.

Tank Waste Remediation System optimized processing strategy

International Nuclear Information System (INIS)

Slaathaug, E.J.; Boldt, A.L.; Boomer, K.D.; Galbraith, J.D.; Leach, C.E.; Waldo, T.L.

1996-03-01

This report provides an alternative strategy evolved from the current Hanford Site Tank Waste Remediation System (TWRS) programmatic baseline for accomplishing the treatment and disposal of the Hanford Site tank wastes. This optimized processing strategy performs the major elements of the TWRS Program, but modifies the deployment of selected treatment technologies to reduce the program cost. The present program for development of waste retrieval, pretreatment, and vitrification technologies continues, but the optimized processing strategy reuses a single facility to accomplish the separations/low-activity waste (LAW) vitrification and the high-level waste (HLW) vitrification processes sequentially, thereby eliminating the need for a separate HLW vitrification facility

Methods for Heel Retrieval for Tanks C-101, C-102, and C-111 at the Hanford Site - 13064

International Nuclear Information System (INIS)

Sams, T.L.; Kirch, N.W.; Reynolds, J.H.

2013-01-01

The purpose of this paper is to evaluate the prospects of using bulk waste characteristics to determine the most appropriate heel retrieval technology. If the properties of hard to remove heels can be determined before bulk retrieval, then a heel retrieval technology can be selected before bulk retrieval is complete. This would save substantially on sampling costs and would allow the deployment of the heel retrieval technology immediately after bulk retrieval. The latter would also accelerate the heel removal schedule. A number of C-farm retrievals have been fully or partially completed at the time of this writing. Thus, there is already substantial information on the success of different technologies and the composition of the heels. There is also substantial information on the waste types in each tank based on historical records. Therefore, this study will correlate the performance of technologies used so far and compare them to the known waste types in the tanks. This will be used to estimate the performance of future C Farm heel retrievals. An initial decision tree is developed and employed on tanks C-101, C-102, and C 111. An assumption of this study is that no additional characterization information would be available, before or after retrieval. Note that collecting additional information would substantially increase the probability of success. Deploying some in-situ testing technologies, such as a water lance or an in-situ Raman probe, might substantially increase the probability of successfully selecting the process conditions without having to take samples from the tanks for laboratory analysis. (authors)

Methods for Heel Retrieval for Tanks C-101, C-102, and C-111 at the Hanford Site - 13064

Energy Technology Data Exchange (ETDEWEB)

Sams, T.L.; Kirch, N.W.; Reynolds, J.H. [Washington River protection Solutions, Richland, WA 99352 (United States)

2013-07-01

The purpose of this paper is to evaluate the prospects of using bulk waste characteristics to determine the most appropriate heel retrieval technology. If the properties of hard to remove heels can be determined before bulk retrieval, then a heel retrieval technology can be selected before bulk retrieval is complete. This would save substantially on sampling costs and would allow the deployment of the heel retrieval technology immediately after bulk retrieval. The latter would also accelerate the heel removal schedule. A number of C-farm retrievals have been fully or partially completed at the time of this writing. Thus, there is already substantial information on the success of different technologies and the composition of the heels. There is also substantial information on the waste types in each tank based on historical records. Therefore, this study will correlate the performance of technologies used so far and compare them to the known waste types in the tanks. This will be used to estimate the performance of future C Farm heel retrievals. An initial decision tree is developed and employed on tanks C-101, C-102, and C 111. An assumption of this study is that no additional characterization information would be available, before or after retrieval. Note that collecting additional information would substantially increase the probability of success. Deploying some in-situ testing technologies, such as a water lance or an in-situ Raman probe, might substantially increase the probability of successfully selecting the process conditions without having to take samples from the tanks for laboratory analysis. (authors)

Methods for heel retrieval for tanks C-101, C-102, and C-111 at the Hanford Site-13064

International Nuclear Information System (INIS)

Sams, Terry L.; Kirch, N. W.; Reynolds, Jacob G.

2013-01-01

The purpose of this paper is to evaluate the prospects of using bulk waste characteristics to determine the most appropriate heel retrieval technology. If the properties of hard to remove heels can be determined before bulk retrieval, then a heel retrieval technology can be selected before bulk retrieval is complete. This would save substantially on sampling costs and would allow the deployment of the heel retrieval technology immediately after bulk retrieval. The latter would also accelerate the heel removal schedule. A number of C-farm retrievals have been fully or partially completed at the time of this writing. Thus, there is already substantial information on the success of different technologies and the composition of the heels. There is also substantial information on the waste types in each tank based on historical records. Therefore, this study will correlate the performance of technologies used so far and compare them to the known waste types in the tanks. This will be used to estimate the performance of future C Farm heel retrievals. An initial decision tree is developed and employed on tanks C-101, C-102, and C 111. An assumption of this study is that no additional characterization information would be available, before or after retrieval. Note that collecting additional information would substantially increase the probability of success. Deploying some in-situ testing technologies, such as a water lance or an in-situ Raman probe, might substantially increase the probability of successfully selecting the process conditions without having to take samples from the tanks for laboratory analysis

TWRS privatization support project waste characterization database development

International Nuclear Information System (INIS)

1995-11-01

Pacific Northwest National Laboratory requested support from ICF Kaiser Hanford Company in assembling radionuclide and chemical analyte sample data and inventory estimates for fourteen Hanford underground storage tanks: 241-AN-102, -104, -105, -106, and -107, 241-AP-102, -104, and -105, 241-AW-101, -103, and -105, 241 AZ-101 and -102; and 241-C-109. Sample data were assembled for sixteen radionuclides and thirty-five chemical analytes. The characterization data were provided to Pacific Northwest National Laboratory in support of the Tank Waste Remediation Services Privatization Support Project. The purpose of this report is to present the results and document the methodology used in preparing the waste characterization information data set to support the Tank Waste Remediation Services Privatization Support Project. This report describes the methodology used in assembling the waste characterization information and how that information was validated by a panel of independent technical reviewers. Also, contained in this report are the various data sets created: the master data set, a subset, and an unreviewed data set. The master data set contains waste composition information for Tanks 241-AN-102 and -107, 241-AP-102 and -105, 241-AW-101; and 241-AZ-101 and -102. The subset contains only the validated analytical sample data from the master data set. The unreviewed data set contains all collected but unreviewed sample data for Tanks 241-AN-104, -105, and -106; 241-AP-104; 241-AW-103 and-105; and 241-C-109. The methodology used to review the waste characterization information was found to be an accurate, useful way to separate the invalid or questionable data from the more reliable data. In the future, this methodology should be considered when validating waste characterization information

History of waste tank 14, 1957 through 1974

International Nuclear Information System (INIS)

Davis, T.L.; Tharin, D.W.; Jones, D.W.; Lohr, D.R.

1977-08-01

Tank 14 was placed in service as a receiver of fresh high heat waste (HW) in September 1957. Annulus leakage was discovered in April 1959 and continued until annulus ventilation was increased in January 1965. Practically all of the approximately 40 leak sites that have been identified on the tank wall are located at or below the bottom horizontal weld. Tank supernate was removed from the tank in preparation for a sludge removal operation which was performed in December 1968. The tank was then filled to its present level with blended supernate from tanks 10 and 13. In December 1972, supernate was inadvertently siphoned into the annulus through a dewatering jet, filling the annulus pan to a level of 33 in. The waste was promptly returned to the tank. Inspections of the tank interior and annulus were performed by direct observation, with a 40-ft optical periscope, and with photography and closed circuit television. Radioactive waste was first found in the annulus during visual inspection in May 1959. Samples of sludge, supernate, tank vapors, and leaked material in the annulus were analyzed, and numerous tank temperature profiles were taken. Soil and tank wall temperatures were measured in a study of tank nil ductility transition temperature. Six cooling coils failed, five of which occurred within 7 months after sludge removal. Several modifications to equipment and various equipment repairs were made. 14 figures, 3 tables

Using Photogrammetry to Estimate Tank Waste Volumes from Video

Energy Technology Data Exchange (ETDEWEB)

Field, Jim G. [Washington River Protection Solutions, LLC, Richland, WA (United States)

2013-03-27

Washington River Protection Solutions (WRPS) contracted with HiLine Engineering & Fabrication, Inc. to assess the accuracy of photogrammetry tools as compared to video Camera/CAD Modeling System (CCMS) estimates. This test report documents the results of using photogrammetry to estimate the volume of waste in tank 241-C-I04 from post-retrieval videos and results using photogrammetry to estimate the volume of waste piles in the CCMS test video.

Using Photogrammetry to Estimate Tank Waste Volumes from Video

International Nuclear Information System (INIS)

Field, Jim G.

2013-01-01

Washington River Protection Solutions (WRPS) contracted with HiLine Engineering and Fabrication, Inc. to assess the accuracy of photogrammetry tools as compared to video Camera/CAD Modeling System (CCMS) estimates. This test report documents the results of using photogrammetry to estimate the volume of waste in tank 241-C-I04 from post-retrieval videos and results using photogrammetry to estimate the volume of waste piles in the CCMS test video

Specialized video systems for use in waste tanks

International Nuclear Information System (INIS)

Anderson, E.K.; Robinson, C.W.; Heckendorn, F.M.

1992-01-01

The Robotics Development Group at the Savannah River Site is developing a remote video system for use in underground radioactive waste storage tanks at the Savannah River Site, as a portion of its site support role. Viewing of the tank interiors and their associated annular spaces is an extremely valuable tool in assessing their condition and controlling their operation. Several specialized video systems have been built that provide remote viewing and lighting, including remotely controlled tank entry and exit. Positioning all control components away from the facility prevents the potential for personnel exposure to radiation and contamination. The SRS waste tanks are nominal 4.5 million liter (1.3 million gallon) underground tanks used to store liquid high level radioactive waste generated by the site, awaiting final disposal. The typical waste tank (Figure 1) is of flattened shape (i.e. wider than high). The tanks sit in a dry secondary containment pan. The annular space between the tank wall and the secondary containment wall is continuously monitored for liquid intrusion and periodically inspected and documented. The latter was historically accomplished with remote still photography. The video systems includes camera, zoom lens, camera positioner, and vertical deployment. The assembly enters through a 125 mm (5 in) diameter opening. A special attribute of the systems is they never get larger than the entry hole during camera aiming etc. and can always be retrieved. The latest systems are easily deployable to a remote setup point and can extend down vertically 15 meters (50ft). The systems are expected to be a valuable asset to tank operations

History of waste tank 9 , 1955--1974

International Nuclear Information System (INIS)

Tharin, D.W.; Lohr, D.R.

1979-01-01

Tank 9 was placed in service as a receiver for Purex HLW on July 19, 1955. Filling was essentially completed in December 1955, and this original complement of waste remained in the tank until December 1965, when most of the liquid was decanted to allow refilling. In July 1966, the remaining liquid and approximately 15 inches of sludge were removed using 3000 to 3500 psi water introduced through nozzles to mobilize the sludge. The tank was then used as a receiver and cooler for aged HLW solution concentrated by the tank farm evaporator; the resulting crystallized salt, covered with saturated solution, is now stored in this tank. Inspections have been made of the tank interior and annulus by direct observation and with a 40-ft optical periscope. Analytical samples have been taken of the sludge, supernate, vapor, and leaked material in the annulus. Top-to-bottom profiles of radiation and temperature have been obtained in the annulus and tank, respectively, and measurements have been made of roof deflection caused by salt adhering to roof-supported cooling coils. Leaked waste was discovered in the annulus pan in October 1957. During 1958-59, the annulus pan was flushed nine times with water in 2000-gallon batches, jetting the waste and flush water into the primary tank. However, waste leakage into the annulus continued. The maximum liquid depth reached in the annulus was about 12 inches. This was jetted out in 1961., but some leakage continued theeeafter as indicated by roddings. The roddings showed no standing liquid by August 1964, but some liquid may have been present undera salt crust. In March 1972, salt depth in the annulus was measured to be 8 to 10 in., and the bottom 3 in. was quite wet. The salt remains although most of the liquid has been removed

PROGRESS and CHALLENGES IN CLEANUP OF HANFORDS TANK WASTES

International Nuclear Information System (INIS)

HEWITT, W.M.; SCHEPENS, R.

2006-01-01

The River Protection Project (RPP), which is managed by the Department of Energy (DOE) Office of River Protection (ORP), is highly complex from technical, regulatory, legal, political, and logistical perspectives and is the largest ongoing environmental cleanup project in the world. Over the past three years, ORP has made significant advances in its planning and execution of the cleanup of the Hartford tank wastes. The 149 single-shell tanks (SSTs), 28 double-shell tanks (DSTs), and 60 miscellaneous underground storage tanks (MUSTs) at Hanford contain approximately 200,000 m 3 (53 million gallons) of mixed radioactive wastes, some of which dates back to the first days of the Manhattan Project. The plan for treating and disposing of the waste stored in large underground tanks is to: (1) retrieve the waste, (2) treat the waste to separate it into high-level (sludge) and low-activity (supernatant) fractions, (3) remove key radionuclides (e.g., Cs-137, Sr-90, actinides) from the low-activity fraction to the maximum extent technically and economically practical, (4) immobilize both the high-level and low-activity waste fractions by vitrification, (5) interim store the high-level waste fraction for ultimate disposal off-site at the federal HLW repository, (6) dispose the low-activity fraction on-site in the Integrated Disposal Facility (IDF), and (7) close the waste management areas consisting of tanks, ancillary equipment, soils, and facilities. Design and construction of the Waste Treatment and Immobilization Plant (WTP), the cornerstone of the RPP, has progressed substantially despite challenges arising from new seismic information for the WTP site. We have looked closely at the waste and aligned our treatment and disposal approaches with the waste characteristics. For example, approximately 11,000 m 3 (2-3 million gallons) of metal sludges in twenty tanks were not created during spent nuclear fuel reprocessing and have low fission product concentrations. We plan to

Tank Waste Remediation System, Hanford Site, Richland, Washington. Final Environmental Impact Statement. Volume II

International Nuclear Information System (INIS)

1996-08-01

This document, Volume 2, provides the inventory of waste addressed in this Final Environmental Impact Statement (EIS) for the Tank Waste Remediation System, Hanford Site, Richland, Washington. The inventories consist of waste from the following four groups: (1) Tank waste; (2) Cesium (Cs) and Strontium (Sr) capsules; (3) Inactive miscellaneous underground storage tanks (MUSTs); and (4) Anticipated future tank waste additions. The major component by volume of the overall waste is the tank waste inventory (including future tank waste additions). This component accounts for more than 99 percent of the total waste volume and approximately 70 percent of the radiological activity of the four waste groups identified previously. Tank waste data are available on a tank-by-tank basis, but the accuracy of these data is suspect because they primarily are based on historical records of transfers between tanks rather than statistically based sampling and analyses programs. However, while the inventory of any specific tank may be suspect, the overall inventory for all of the tanks combined is considered more accurate. The tank waste inventory data are provided as the estimated overall chemical masses and radioactivity levels for the single-shell tanks (SSTs) and double-shell tanks (DSTs). The tank waste inventory data are broken down into tank groupings or source areas that were developed for analyzing groundwater impacts

Feed Basis for Processing Relatively Low Radioactivity Waste Tanks

International Nuclear Information System (INIS)

Pike, J.A.

2002-01-01

This paper presents the characterization of potential feed for processing relatively low radioactive waste tanks. The feed characterization is based on waste characterization data extracted from the waste characterization system. This data is compared to salt cake sample results from Tanks 37, 38 and 41

Data quality objectives lessons learned for tank waste characterization

International Nuclear Information System (INIS)

Eberlein, S.J.; Banning, D.L.

1996-01-01

The tank waste characterization process is an integral part of the overall effort to control the hazards associated with radioactive wastes stored in underground tanks at the Hanford Reservation. The programs involved in the characterization of the waste are employing the Data Quality Objective (DQO) process in all information and data collection activities. The DQO process is used by the programs to address an issue or problem rather than a specific sampling event. Practical limits (e.g., limited number and location of sampling points) do not always allow for precise characterization of a tank or the full implementation of the DQO process. Because of the flexibility of the DQO process, it can be used as a planning tool for sampling and analysis of the underground waste storage tanks. The iterative nature of the DQO process allows it to be used as additional information is obtained or open-quotes lessons are learnedclose quotes concerning an issue or problem requiring sampling and analysis of tank waste. In addition, the application of the DQO process forces alternative actions to be considered when precise characterization of a tank or the fall implementation of the DQO process is not practical

The Retrieval Knowledge Center Evaluation Of Low Tank Level Mixing Technologies For DOE High Level Waste Tank Retrieval 10516

International Nuclear Information System (INIS)

Fellinger, A.

2009-01-01

The Department of Energy (DOE) Complex has over two-hundred underground storage tanks containing over 80-million gallons of legacy waste from the production of nuclear weapons. The majority of the waste is located at four major sites across the nation and is planned for treatment over a period of almost forty years. The DOE Office of Technology Innovation and Development within the Office of Environmental Management (DOE-EM) sponsors technology research and development programs to support processing advancements and technology maturation designed to improve the costs and schedule for disposal of the waste and closure of the tanks. Within the waste processing focus area are numerous technical initiatives which included the development of a suite of waste removal technologies to address the need for proven equipment and techniques to remove high level radioactive wastes from the waste tanks that are now over fifty years old. In an effort to enhance the efficiency of waste retrieval operations, the DOE-EM Office of Technology Innovation and Development funded an effort to improve communications and information sharing between the DOE's major waste tank locations as it relates to retrieval. The task, dubbed the Retrieval Knowledge Center (RKC) was co-lead by the Savannah River National Laboratory (SRNL) and the Pacific Northwest National Laboratory (PNNL) with core team members representing the Oak Ridge and Idaho sites, as well as, site contractors responsible for waste tank operations. One of the greatest challenges to the processing and closure of many of the tanks is complete removal of all tank contents. Sizeable challenges exist for retrieving waste from High Level Waste (HLW) tanks; with complications that are not normally found with tank retrieval in commercial applications. Technologies currently in use for waste retrieval are generally adequate for bulk removal; however, removal of tank heels, the materials settled in the bottom of the tank, using the same

Hydrothermal processing of Hanford tank waste. Organic destruction technology development task annual report -- FY 1993

International Nuclear Information System (INIS)

Orth, R.J.; Schmidt, A.J.; Zacher, A.H.

1993-09-01

Low-temperature hydrothermal processing (HTP) is a thermal-chemical autogenous processing method that can be used to destroy organics and ferrocyanide in Hanford tank waste at temperatures from 250 C to 400 C. With HTP, organics react with oxidants, such as nitrite and nitrate, already present in the waste. Ferrocyanides and free cyanide will hydrolyze at similar temperatures and may also react with nitrates or other oxidants in the waste. No air or oxygen or additional chemicals need to be added to the autogenous HTP system. However, enhanced kinetics may be realized by air addition, and, if desired, chemical reductants can be added to the system to facilitate complete nitrate/nitrate destruction. Tank waste can be processed in a plug-flow, tubular reactor, or a continuous-stirred tank reactor system designed to accommodate the temperature, pressure, gas generation, and heat release associated with decomposition of the reactive species. The work described in this annual report was conducted in FY 1993 for the Organic Destruction Technology Development Task of Hanford's Tank Waste Remediation System (TWRS). This task is part of an overall program to develop organic destruction technologies originally funded by TWRS to meet tank safety and waste form disposal criteria and condition the feed for further pretreatment. During FY 1993 the project completed seven experimental test plans, a 30-hr pilot-scale continuous run, over 200 hr of continuous bench-scale HTP testing, and 20 batch HTP tests; two contracts were established with commercial vendors, and a commercial laboratory reactor was procured and installed in a glovebox for HTP testing with actual Hanford tank waste

Technology development activities supporting tank waste remediation

International Nuclear Information System (INIS)

Bonner, W.F.; Beeman, G.H.

1994-06-01

This document summarizes work being conducted under the U.S. Department of Energy's Office of Technology Development (EM-50) in support of the Tank Waste Remediation System (TWRS) Program. The specific work activities are organized by the following categories: safety, characterization, retrieval, barriers, pretreatment, low-level waste, and high-level waste. In most cases, the activities presented here were identified as supporting tank remediation by EM-50 integrated program or integrated demonstration lead staff and the selections were further refined by contractor staff. Data sheets were prepared from DOE-HQ guidance to the field issued in September 1993. Activities were included if a significant portion of the work described provides technology potentially needed by TWRS; consequently, not all parts of each description necessarily support tank remediation

Tank waste pretreatment issues, alternatives and strategies for resolution