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Sample records for synthesized pendant armed

  1. Pendant-armed Unsymmetrical Aza-macrocycles: Syntheses,Coordination Behavior and Crystal Structure of a Dinuclear Cadmium Complex

    TAO,Jing-Chao(陶京朝); LIAO,Xin-Cheng(廖新成); WANG,Xing-Wang(王兴旺); DU,Chen-Xia(杜晨霞)

    2002-01-01

    Two nsymmetrical tetradentate aza-macrocycles with side arms attached to the N3sp atoms, L1 and L2, as well as their complexes with different metal cations were synthesized and characterized by EA, UV, IR, 1H NMR and MS spectra. Both the two ligands can efficiently transport alkali and transition metal cations across an organic membrane with high selectivity ratio. The structure of a dinuclear Cd(Ⅱ)complex [L1@(CdCl2)2] was elucdated by X-ray crystallography and was solved by the heavy-atom method to afinal R value of 0.029 for 3084reflections with |F| >3σ(I). In the exo-structore of the dinuclear complex each cadmium atom is five-coordinated, bonding to three N atoms and two chlorine atoms.

  2. Biological evaluation of {sup 153}Sm and {sup 166}Ho complexes with tetraazamacrocycles containing methylcarboxylate and/or methylphosphonate pendant arms

    Marques, F.; Gano, L.; Campello, M.P.; Lacerda, S.; Santos, I. [Inst. Tecnologico e Nuclear, Sacavem (Portugal)

    2007-07-01

    {sup 153}Sm and {sup 166}Ho complexes with two series of tetraazamacrocyclic ligands containing methylcarboxylate and/or methylphosphonate pendant arms were synthesized and their charge, lipophilicity, protein binding and in vitro and in vivo behaviour evaluated. The first series has the same backbone, a 14-membered tetraazamacrocycle containing a pyridine unit with different pendant arms, namely methylcarboxylates (ac{sub 3}py14) or methylphosphonates (MeP{sub 2}py14 and P{sub 3}py14). The second series comprises 12- to 14-membered tetraazamacrocycles having methylcarboxylates and/or methylphosphonates as pendant arms (trans-DO2A2P, TRITA, TRITP, TETA and TETP). The {sup 153}Sm/{sup 166}Ho complexes with the 14-membered tetraazamacrocycles containing the pyridine unit are neutral, hydrophilic, have a significant plasmatic protein binding, are unstable in vivo and present a slow rate of radioactivity excretion and high hepatic retention. {sup 153}Sm/{sup 166}Ho complexes with the 12- to 14-membered tetraazamacrocycles are quantitatively prepared, except those with TETP. These complexes are hydrophilic, have an overall negative charge and present a medium to low plasmatic protein binding. The {sup 153}Sm/{sup 166}Ho-trans-DO2A2P, {sup 153}Sm/{sup 166}Ho-TRITA and {sup 166}Ho-TRITP complexes are stable in vitro and in vivo, presenting a rapid clearance from main organs and a high rate of whole body radioactivity excretion. Biological profile of {sup 153}Sm/{sup 166}Ho-TRITA complexes makes them promising candidates for therapy when conjugated to a biomolecule, while {sup 166}Ho-TRITP is potentially useful for bone targeting due to its considerable uptake by bone. (orig.)

  3. Synthesis, structural studies, and oxidation catalysis of the late-first-row-transition-metal complexes of a 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam.

    Jones, Donald G; Wilson, Kevin R; Cannon-Smith, Desiray J; Shircliff, Anthony D; Zhang, Zhan; Chen, Zhuqi; Prior, Timothy J; Yin, Guochuan; Hubin, Timothy J

    2015-03-02

    The first 2-pyridylmethyl pendant-armed ethylene cross-bridged cyclam ligand has been synthesized and successfully complexed to Mn(2+), Fe(2+), Co(2+), Ni(2+), Cu(2+), and Zn(2+) cations. X-ray crystal structures were obtained for all six complexes and demonstrate pentadentate binding of the ligand with the requisite cis-V configuration of the cross-bridged cyclam ring in all cases, leaving a potential labile binding site cis to the pyridine donor for interaction of the complex with oxidants and/or substrates. The electronic properties of the complexes were evaluated using solid-state magnetic moment determination and acetonitrile solution electronic spectroscopy, which both agree with the crystal structure determination of high-spin divalent metal complexes in all cases. Cyclic voltammetry in acetonitrile revealed reversible redox processes in all but the Ni(2+) complex, suggesting that catalytic reactivity involving electron-transfer processes is possible for complexes of this ligand. Kinetic studies of the dissociation of the ligand from the copper(II) complex under strongly acidic conditions and elevated temperatures revealed that the pyridine pendant arm actually destabilizes the complex compared to the parent cross-bridged cyclam complex. Screening for oxidation catalysis using hydrogen peroxide as the terminal oxidant for the most biologically relevant Mn(2+), Fe(2+), and Cu(2+) complexes identified the Mn(2+) complex as a potential mild oxidation catalyst worthy of continued development.

  4. Synthesis, characterization, biological evaluation and docking studies of macrocyclic binuclear manganese(II) complexes containing 3,5-dinitrobenzoyl pendant arms.

    Arthi, P; Shobana, S; Srinivasan, P; Mitu, L; Kalilur Rahiman, A

    2015-05-15

    A series of bis(phenoxo) bridged binuclear manganese(II) complexes of the type [Mn2L(1-3)](ClO4)2 (1-3) containing 3,5-dinitrobenzoyl pendant-arms have been synthesized by cyclocondensation of 2,6-diformyl-4-R-phenols (where R=CH3, C(CH3)3 or Br) with 2,2'-3,5-dinitrobenzoyliminodi(ethylamine) trihydrochloride in the presence of manganese(II) perchlorate. The IR spectra of complexes indicate the presence of uncoordinated perchlorate anions. The UV-Vis spectra of complexes suggest the distorted octahedral geometry around manganese(II) nuclei. The EPR spectra of Mn(II) complexes show a broad signal with g value 2.03-2.04, which is characteristic for octahedral high spin Mn(2+) complex. The observed room temperature magnetic moment values of the Mn(II) complexes (5.60-5.62B.M.) are less than the normal value (5.92B.M.), indicating weak antiferromagnetic coupling interaction between the two metal ions. Electrochemical studies of the complexes show two distinct quasi-reversible one electron transfer processes in the cathodic (E(1)pc=-0.73 to -0.76V, E(2)pc=-1.30 to -1.36V), and anodic (E(1)pa=1.02-1.11V, E(2)pa=1.32-1.79V) potential regions. Antibacterial efficacy of complexes have been screened against four Gram (-ve) and two Gram (+ve) bacterial strains. The DNA interaction studies suggest that these complexes bind with CT-DNA by intercalation, giving the binding affinity in the order 1>2>3. All the complexes display significant cleavage activity against circular plasmid pBR322 DNA. Docking simulation was performed to insert complexes into the crystal structure of EGFR tyrosine kinase and B-DNA at active site to determine the probable binding mode.

  5. Synthesis, characterization, biological evaluation and docking studies of macrocyclic binuclear manganese(II) complexes containing 3,5-dinitrobenzoyl pendant arms

    Arthi, P.; Shobana, S.; Srinivasan, P.; Mitu, L.; Kalilur Rahiman, A.

    2015-05-01

    A series of bis(phenoxo) bridged binuclear manganese(II) complexes of the type [Mn2L1-3](ClO4)2 (1-3) containing 3,5-dinitrobenzoyl pendant-arms have been synthesized by cyclocondensation of 2,6-diformyl-4-R-phenols (where R = sbnd CH3, sbnd C(CH3)3 or sbnd Br) with 2,2‧-3,5-dinitrobenzoyliminodi(ethylamine) trihydrochloride in the presence of manganese(II) perchlorate. The IR spectra of complexes indicate the presence of uncoordinated perchlorate anions. The UV-Vis spectra of complexes suggest the distorted octahedral geometry around manganese(II) nuclei. The EPR spectra of Mn(II) complexes show a broad signal with g value 2.03-2.04, which is characteristic for octahedral high spin Mn2+ complex. The observed room temperature magnetic moment values of the Mn(II) complexes (5.60-5.62 B.M.) are less than the normal value (5.92 B.M.), indicating weak antiferromagnetic coupling interaction between the two metal ions. Electrochemical studies of the complexes show two distinct quasi-reversible one electron transfer processes in the cathodic (E1pc = -0.73 to -0.76 V, E2pc = -1.30 to -1.36 V), and anodic (E1pa = 1.02-1.11 V, E2pa = 1.32-1.79 V) potential regions. Antibacterial efficacy of complexes have been screened against four Gram (-ve) and two Gram (+ve) bacterial strains. The DNA interaction studies suggest that these complexes bind with CT-DNA by intercalation, giving the binding affinity in the order 1 > 2 > 3. All the complexes display significant cleavage activity against circular plasmid pBR322 DNA. Docking simulation was performed to insert complexes into the crystal structure of EGFR tyrosine kinase and B-DNA at active site to determine the probable binding mode.

  6. Uranyl complexes formed with a para-t-butylcalix[4]arene bearing phosphinoyl pendant arms on the lower rim. Solid and solution studies

    Ramirez, F. de M. [Instituto Nacional de Investigaciones Nucleares, La Marquesa, Ocoyoacac (Mexico). Dept. de Quimica; Varbanov, S. [Bulgarian Academy of Sciences, Sofia (Bulgaria). Inst. of Organic Chemistry with Center of Phytochemistry; Buenzli, J.C.G. [Ecole Polytechnique Federale de Lausanne (EPFL) (Switzerland). Inst. of Chemical Sciences and Engineering; Rivas-Silva, J.F.; Ocana-Bribiesca, M.A. [Instituto de Fisica de la BUAP, Puebla (Mexico); Cortes-Jacome, M.A.; Toledo-Antonio, J.A. [Instituto Mexicano del Petroleo/Programa de Ingenieria Molecular (Mexico)

    2012-07-01

    The current interest in functionalized calixarenes with phosphorylated pendant arms resides in their coordination ability towards f elements and capability towards actinide/rare earth separation. Uranyl cation forms 1:1 and 1:2 (M:L) complexes with a tetra-phosphinoylated p-tert-butylcalix[4]arene, B{sub 4}bL{sup 4}: UO{sub 2}(NO{sub 3}){sub 2}(B{sub 4}bL{sup 4}){sub n} . xH{sub 2}O (n = 1, x = 2, 1; n = 2, x = 6, 2). Spectroscopic data point to the inner coordination sphere of 1 containing one monodentate nitrate anion, one water molecule and the four phosphinoylated arms bound to UO{sub 2}{sup 2+} while in 2, uranyl is only coordinated to calixarene ligands. In both cases the U(VI) ion is 8-coordinate. Uranyl complexes display enhanced metal-centred luminescence due to energy transfer from the calixarene ligands; the luminescence decays are bi-exponential with associated lifetimes in the ranges 220 {mu}s < {tau}{sub s} < 250 {mu}s and 630 {mu}s < {tau}{sub L} < 640 {mu}s, pointing to the presence of two species with differently coordinated calixarene, as substantiated by a XPS study of U(4f{sub 5/2,7/2}), O(1s) and P(2p) levels on solid state samples. The extraction study of UO{sub 2}{sup 2+} cation and trivalent rare-earth (Y, La, Eu) ions from acidic nitrate media by B{sub 4}bL{sup 4} in chloroform shows the uranyl cation being much more extracted than rare earths. (orig.)

  7. Synthesis and characterization of Ni(II, Cu(II and Co(III complexes with polyamine-containing macrocycles bearing an aminoethyl pendant arm

    K. S. SIDDIQI

    2004-09-01

    Full Text Available Reaction of [M(ppn2]X2 (where M = Cu(II, Ni(II, Co(II and ppn = 1,3-diaminopropane with formaldehyde and ethylenediamine in methanol results in the ready formation of a 16-membered macrocyclic complex. The complexes were characterized by elemental anlysis, IR, EPR, electronic spectral data, magnetic moments and conductance measurements. The Cu(II, Ni(II and Co(III complexes are coordinated axially with both pendant groups of the hexadentate macrocycle. These pendant donors are attached to the macrocycle by a carbon chain. The electrical conductivities of the Cu(II and Ni(II chelates indicated them to be 1:2 electrolytes whilst those of Co(III is a 1:3 electrolyte in DMSO. The EPR spectrum of the copper complex exhibited G at 3.66, which indicates a considerable exchange interaction in the complex. Spectroscopic evidence suggests that in all of the complexes the metal ion is in an octahedral environment.

  8. Late First-Row Transition-Metal Complexes Containing a 2-Pyridylmethyl Pendant-Armed 15-Membered Macrocyclic Ligand. Field-Induced Slow Magnetic Relaxation in a Seven-Coordinate Cobalt(II) Compound.

    Antal, Peter; Drahoš, Bohuslav; Herchel, Radovan; Trávníček, Zdeněk

    2016-06-20

    The 2-pyridylmethyl N-pendant-armed heptadentate macrocyclic ligand {3,12-bis(2-methylpyridine)-3,12,18-triaza-6,9-dioxabicyclo[12.3.1]octadeca-1,14,16-triene = L} and [M(L)](ClO4)2 complexes, where M = Mn(II) (1), Fe(II) (2), Co(II) (3), Ni(II) (4), and Cu(II) (5), were prepared and thoroughly characterized, including elucidation of X-ray structures of all the compounds studied. The complexes 1-5 crystallize in non-centrosymmetric Sohncke space groups as racemic compounds. The coordination numbers of 7, 6 + 1, and 5 were found in complexes 1-3, 4, and 5, respectively, with a distorted pentagonal bipyramidal (1-4) or square pyramidal (5) geometry. On the basis of the magnetic susceptibility experiments, a large axial zero-field splitting (ZFS) was found for 2, 3, and 4 (D(Fe) = -7.4(2) cm(-1), D(Co) = 34(1) cm(-1), and D(Ni) = -12.8(1) cm(-1), respectively) together with a rhombic ZFS (E/D = 0.136(3)) for 4. Despite the easy plane anisotropy (D > 0, E/D = 0) in 3, the slow relaxation of the magnetization below 8 K was observed and analyzed either with Orbach relaxation mechanism (the relaxation time τ0 = 9.90 × 10(-10) s and spin reversal barrier Ueff = 24.3 K (16.9 cm(-1))) or with Raman relaxation mechanism (C = 2.12 × 10(-5) and n = 2.84). Therefore, compound 3 enlarges the small family of field-induced single-molecule magnets with pentagonal-bipyramidal chromophore. The cyclic voltammetry in acetonitrile revealed reversible redox processes in 1-3 and 5, except for the Ni(II) complex 4, where a quasi-reversible process was dominantly observed. Presence of the two 2-pyridylmethyl pendant arms in L with a stronger σ-donor/π-acceptor ability had a great impact on the properties of all the complexes (1-5), concretely: (i) strong pyridine-metal bonds provided slight axial compression of the coordination sphere, (ii) substantial changes in magnetic anisotropy, and (iii) stabilization of lower oxidation states.

  9. Determination of cobalt ions at nano-level based on newly synthesized pendant armed macrocycle by polymeric membrane and coated graphite electrode.

    Singh, Ashok K; Singh, Prerna; Bhattacharjee, G

    2009-12-15

    Poly(vinylchloride) (PVC) based membranes of macrocycles 2,3,4:9,10,11-dipyridine-1,3,5,8,10,12-hexaazacyclotetradeca-2,9-diene (L(1)) and 2,3,4:9,10,11-dipyridine-1,5,8,12-tetramethylacrylate-1,3,5,8,10,12-hexaazacyclotetradeca-2,9-diene (L(2)) with NaTPB and KTpClPB as anion excluders and dibutylphthalate (DBP), benzyl acetate (BA), dioctylphthalate (DOP), o-nitrophenyloctyl ether (o-NPOE) and tri-n-butylphosphate (TBP) as plasticizing solvent mediators were prepared and investigated as Co(2+) selective electrodes. The best performance was observed with the membranes having the composition L(2):PVC:TBP:NaTPB in the ratio of 6:39:53:2 (w/w; mg). The performance of the membrane based on L(2) was compared with polymeric membrane electrode (PME) and coated graphite electrode (CGE). The PME exhibits detection limit of 4.7x10(-8)M with a Nernstian slope of 29.7 mV decade(-1) of activity between pH 2.5 and 8.5 whereas CGE exhibits the detection limit of 6.8x10(-9)M with a Nernstian slope of 29.5 mV decade(-1) of activity between pH 2.0 and 9.0. The response time for PME and CGE was found to be 11 and 8s, respectively. The CGE has been found to work satisfactorily in partially non-aqueous media up to 35% (v/v) content of methanol, ethanol and 25% (v/v) content of acetonitrile and could be used for a period of 4 months. The CGE was successfully applied for the determination of Co(2+) in real and pharmaceutical samples and as an indicator electrode in potentiometric titration of cobalt ion.

  10. Synthesis of New Spiropyrans With a Polyaromatic or Heteroaromatic Pendant and Their Photochromic Behaviors

    PANG,Mei-Li(庞美丽); NIE,Yun-Tong(聂云艟); WANG,Yong-Mei(王永梅); MENG,Ji-Ben(孟继本); WANG,Ji-Tao(王积涛)

    2002-01-01

    A series of spiropyrans with a polyaromatic or heteroaromatic pendant was synthesized conveniently. Their photochromic behaviors were investigated with the aid of absorption spectral measurements. The results indicated that the compounds with the same parent spiropyran but different armmaaic pendant show significantly different photochromic properties. This may be due to the π-π orbital interaction between the polyaronatic pendant and the open photomerocyanine form of spiropyran.The results obtained are very useful in the molecule design area.

  11. Synthesis of New Spiropyrans With a Polyaromatic or Heteroaromatic Pendant and Their Photochromic Bedhaviors

    庞美丽; 聂云艟; 王永梅; 孟继本; 王积涛

    2002-01-01

    A series of spiropyrans with a polyaromatic or heteroaromatic pendant was synthesized conveniently.Their photochromic behaviors were investigated with the aid of absorption spectral measurements.The results indicated that the compounds with the same parent spiropyran but different aromatic pendant show significantly different photochromic properties.This may be due to the π-π orbital interaction between the polyaromatic pendant and the open photomerocyanine form of spiropyran.The results obtained are very useful in the molecule design area.

  12. Pendant—armed Unsymmetrical Aza—macrocycles:Syntheses,Coordination Behavior and Crystal Structure of a Dinuclear Cadmium Complex

    陶京朝; 廖新成; 等

    2002-01-01

    Two unsymmetridcal tetradentate aza-macrocycles with side arms attached to whte Nsp3 atoms ,L1 and L2 ,as well as their complexes with different metal cations were synthesized and characterized by EA,UV IR ,1H NMR and MS spectra ,Both the two ligands can efficiently transport alkai and transition metal cations across an organic membrane with high selectivity ratio.The structure of a dinuclear Cd(Ⅱ) complex [L1.(CdCl2)2] was elucidated by X-ray crystallography and was solved by the heavy-atom method to a final R value of 0.029 for 3084 reflections with |F|>3σ(I), In the exo-structure of the dinuclear complex each cadmium atom is five-coordinated,bonding to three N atoms and two chlorine atoms.

  13. Sixteen-joint Jade Pendant

    1994-01-01

    This light green jade pendant, measuring 48 cm, was unearthed at the Zenghouyi tomb. It was made from five pieces of jade which were carved into ornamental shapes, including a dragon, a phoenix, a bi(a round flat piece of jade with a hole in the center), and rings. Three slip-hoops are fashioned into an ellipse. A single jade nail connects the pieces to a pendant which can be folded or taken apart. Some designs often were carved either on one side or both sides of these ornaments. On this piece are found 37 styles of dragons, seven kinds of phoenixes and ten snakes, done by drill-carving, carving on the surface or in intagolio. Also on the pendant is a picture titled "The Claws of the Phoenixes Grasp the Snakes."

  14. 5 and 6 - cyclic -perimeter hydrocarbon platinum group metal complexes of 3-(2-pyridyl)pyrazole derived ligands with a pendant nitrile group: Syntheses, spectral and structural studies

    Gloria Sairem; Venkateswara Rao Anna; Peng Wang; Bbulal Das; Mohan Rao Kollipara

    2012-03-01

    Reaction of two equivalents 4-{(3-(pyridine-2-yl) 1H-pyrazole-1-yl}methyl benzonitrile (L1) and 3-{(3-(pyridine-2-yl)1H-pyrazole-1-yl}methyl benzonitrile (L2) with one equivalent of [(6-arene)Ru(- Cl)Cl]2 and [Cp∗M(-Cl)Cl]2 in methanol yielded mononuclear complexes of the formulae [(6-arene)Ru(L1/L2)Cl]BF4{arene =C6H6 (1, 6); C10H14 (2, 7); C6Me6 (3, 8)} and [Cp∗M(L1/L2)Cl]PF6/BF4 {Cp∗= 5-C5Me5, M=Rh (4, 8); Ir (5, 10)}. These complexes are characterized by IR, 1H NMR and identities of the structure are established by single crystal XRD studies of some of the representative complexes. It is confirmed from the spectral studies that the nitrile group is not taking part in complexation; instead it remains as a free pendant group only.

  15. Numerical simulations of pendant droplets

    Pena, Carlos; Kahouadji, Lyes; Matar, Omar; Chergui, Jalel; Juric, Damir; Shin, Seungwon

    2015-11-01

    We simulate the evolution of a three-dimensional pendant droplet through pinch-off using a new parallel two-phase flow solver called BLUE. The parallelization of the code is based on the technique of algebraic domain decomposition where the velocity field is solved by a parallel GMRes method for the viscous terms and the pressure by a parallel multigrid/GMRes method. Communication is handled by MPI message passing procedures. The method for the treatment of the fluid interfaces uses a hybrid Front Tracking/Level Set technique which defines the interface both by a discontinuous density field as well as by a local triangular Lagrangian mesh. This structure allows the interface to undergo large deformations including the rupture and coalescence of fluid interfaces. EPSRC Programme Grant, MEMPHIS, EP/K0039761/1.

  16. Synthesis and structural determination of zinc complexes based on an anilido-aldimine ligand containing an O-donor pendant arm: zinc alkoxide derivative as an efficient initiator for ring-opening polymerization of cyclic esters.

    Wang, Chao-Hsiang; Li, Chen-Yu; Huang, Bor-Hunn; Lin, Chu-Chieh; Ko, Bao-Tsan

    2013-08-14

    Zinc complexes bearing the anilido-aldiminate AA(OMe) ligand (AA(OMe)-H = (E)-2,6-diisopropyl-N-(2-(((2-methoxyethyl)imino)methyl)phenyl)aniline) were synthesized in a stepwise method and were structurally characterized. The reaction of AA(OMe)-H (1) with one equivalent of diethyl zinc (ZnEt2) furnishes a three-coordinated and mononuclear zinc complex [(AA(OMe))ZnEt] (2). Further reaction of 2 with a stoichiometric amount of benzyl alcohol (BnOH) affords a four-coordinated and dinuclear zinc benzylalkoxide complex [(AA(OMe))Zn(μ-OBn)]2 (3). In the presence of two equivalents of AA(OMe)-H with ZnEt2, a homoleptic and four-coordinated zinc complex [(AA(OMe))2Zn] (4) is formed. The geometry around the zinc centres of 3 and 4 are both distorted tetrahedrals, while 2 adopts a different coordination mode with a slightly distorted trigonal planar geometry. The variable-temperature (1)H NMR studies of 3 illustrate that 3 exhibits a dinuclear structure in solution at low temperature as well as in the solid state. While raising the temperature, it drifts towards dissociation to form a mononuclear zinc benzylalkoxide species, which coexists in solution. The ring-opening polymerizations of ε-caprolactone (ε-CL) and β-butyrolactone (β-BL) catalyzed by complexes 3 and 4 are investigated. The ε-CL and β-BL polymerizations initiated by zinc alkoxide 3 were demonstrated to have living characteristics and to proceed in a controlled manner with narrow polydispersity indices (PDIs high monomer-to-initiator ratio (1200/1) initiated by 3 has also been reported.

  17. Thermal and Dielectric Behavior Studies of Poly(Arylene Ether Sulfones with Sulfonated and Phosphonated Pendants

    Shimoga D. Ganesh

    2016-01-01

    Full Text Available The present paper discusses the aspects of the synthesizing valeric acid based poly(ether sulfones with active carboxylic acid pendants (VALPSU from solution polymerization technique via nucleophilic displacement polycondensation reaction among 4,4′-dichlorodiphenyl sulfone (DCDPS and 4,4′-bis(4-hydroxyphenyl valeric acid (BHPA. The conditions necessary to synthesize and purify the polymer were investigated in some detail. The synthesized poly(ether sulfones comprise sulfone and ether linkages in addition to reactive carboxylic acid functionality; these active carboxylic acid functional groups were exploited to hold the phenyl sulphonic acid and phenyl phosphonic acid pendants. The phenyl sulphonic acid pendants in VALPSU were easily constructed by altering active carboxylic acid moieties by sulfanilic acid using N,N′-dicyclohexylcarbodiimide (DCC mediated mild synthetic route, whereas the latter one was built in two steps. Initially, polyphosphoric acid condensation with VALPSU by 4-bromoaniline and next straightforward palladium catalyzed synthetic route, in both of which acidic pendants are clenched by polymer backbone via amide linkage. Without impairing the primary polymeric backbone modified polymers were prepared by varying the stoichiometric ratios of respective combinations. All the polymers were physicochemically characterized and pressed into tablets; electrical contacts were established to study the dielectric properties. Finally, the influence of the acidic pendants on the dielectric properties was examined.

  18. Synthesis and photooxidation of styrene copolymer bearing camphorquinone pendant groups

    Branislav Husár

    2012-03-01

    Full Text Available (±-10-Methacryloyloxycamphorquinone (MCQ was synthesized from (±-10-camphorsulfonic acid either by a known seven-step synthetic route or by a novel, shorter five-step synthetic route. MCQ was copolymerized with styrene (S and the photochemical behavior of the copolymer MCQ/S was compared with that of a formerly studied copolymer of styrene with monomers containing the benzil (BZ moiety (another 1,2-dicarbonyl. Irradiation (λ > 380 nm of aerated films of styrene copolymers with monomers containing the BZ moiety leads to the insertion of two oxygen atoms between the carbonyl groups of BZ and to the formation of benzoyl peroxide (BP as pendant groups on the polymer backbone. An equivalent irradiation of MCQ/S led mainly to the insertion of only one oxygen atom between the carbonyl groups of camphorquinone (CQ and to the formation of camphoric anhydride (11 covalently bound to the polymer backbone. While the decomposition of pendant BP groups formed in irradiated films of styrene copolymers with pendant BZ groups leads to crosslinking, only small molecular-weight changes in irradiated MCQ/S were observed.

  19. Well-defined (co)polypeptides bearing pendant alkyne groups

    Zhao, Wei

    2016-03-18

    A novel metal-free strategy, using hydrogen-bonding catalytic ring opening polymerization of acetylene-functionalized N-carboxy anhydrites of α-amino acids, was developed for the synthesis of well-defined polypeptides bearing pendant alkyne groups. This method provides an efficient way to synthesize novel alkyne-functionalized homopolypeptides (A) and copolypeptides, such as AB diblock (B: non-functionalized), ABA triblock and star-AB diblock, as well as linear and star random copolypeptides, precursors of a plethora complex macromolecular architectures by click chemistry.

  20. Synthesis and ATRP of novel fluorinated aromatic monomer with pendant sulfonate group

    Dimitrov, Ivaylo; Jankova Atanasova, Katja; Hvilsted, Søren

    2013-01-01

    Novel, fluorinated monomer with pendant sulfonate group was synthesized utilizing a two-step derivatization of 2,3,4,5,6-pentafluorostyrene (FS). The first step was a nucleophilic substitution of the fluorine atom in para position by hydroxyl group followed by sulfopropylation. The monomer was po...

  1. Phosphoric acid doped polysulfone membranes with aminopyridine pendant groups and imidazole cross-links

    Hink, Steffen; Elsøe, Katrine; Cleemann, Lars Nilausen;

    2015-01-01

    Udel polysulfone based membranes with 4-aminopyridine pendant groups and cross-linking imidazole units are synthesized in a simple two step reaction. The ratio of 4-aminopyridine and imidazole is varied and the materials are extensively characterized. The average phosphoric acid uptake (in 85 wt...

  2. Syntheses, structural variations and fluorescence studies of two dinuclear zinc(II) complexes of a Schiff base ligand with an extended carboxylate side arm

    Shit, Shyamapada; Sasmal, Ashok; Dhal, Piu; Rizzoli, Corrado; Mitra, Samiran

    2016-03-01

    A potentially tetradentate Schiff base ligand containing carboxylic acid group, HL, (E)-2-((pyridin-2-yl)methyleneamino)-5-chlorobenzoic acid is synthesized and characterized. Reaction of HL with hydrated zinc(II) trichloroacetate and zinc(II) trifluoroacetate under similar reaction condition yields two discrete dinuclear complexes, [Zn(L)(Cl)]2 (1) and [Zn(L)(CF3COO)]2 (2) and characterized by different physicochemical methods. Single crystal X-ray structural characterization reveals different ligating properties of the coordinated anionic ligand (L-) in its zinc(II) complexes. The side arm carboxylate of L- shows μ1,3-carboxylato-bridging mode in 1 and connects zinc(II) atoms in syn-anti fashion while it exhibits a μ1,1-carboxylato-bridging mode in 2. The metal ions display distorted square pyramidal geometries in both the structures and associated with different degrees of distortions. The fluorescence spectra of HL and its zinc(II) complexes recorded in methanol at room temperature which reveal the enhancement of emission intensity for the complexes compared to that of the free ligand. Thermogravimetric analyses (TGA) reveal high thermal stabilities of the complexes.

  3. SYNTHESES AND OPTOELECTRONIC PROPERTIES OF A HEXA-ARMED FLUORENE-BENZENE COPOLYMER BASED ON 2,4,6,8,10,12-HEXABENZYL 2,4,6,8,10,12-HEXAAZAISOWURTZITANECAGED-CORE

    Qian-jin Zhao; Wen-hui Wu; Qiao-li Niu; Jun-biao Peng; Yiu-wing Mai

    2009-01-01

    A novel kind of hexa-armed fluorene-benzene copolymer based on a hexaazaisowurtzitane core was synthesized through Suzuki coupling polycondensation.The introduction of this bulky caged-core could not only enhance the photoluminescence quantum efficiency,but also improve the electroluminescence properties,especially suppress the common green-color emission of polyfluorenes(PFs)material during device operation.These features can be attributed to the successful suppression of PF's chain aggregation which profits from the introduction of the bulky hexaazaisowurtzitane core and the design of multi-armed architecture.

  4. Mechanical vibrations of pendant liquid droplets.

    Temperton, Robert H; Smith, Michael I; Sharp, James S

    2015-07-01

    A simple optical deflection technique was used to monitor the vibrations of microlitre pendant droplets of deuterium oxide, formamide, and 1,1,2,2-tetrabromoethane. Droplets of different volumes of each liquid were suspended from the end of a microlitre pipette and vibrated using a small puff of nitrogen gas. A laser was passed through the droplets and the scattered light was collected using a photodiode. Vibration of the droplets resulted in the motion of the scattered beam and time-dependent intensity variations were recorded using the photodiode. These time-dependent variations were Fourier transformed and the frequencies and widths of the mechanical droplet resonances were extracted. A simple model of vibrations in pendant/sessile drops was used to relate these parameters to the surface tension, density and viscosity of the liquid droplets. The surface tension values obtained from this method were found to be in good agreement with results obtained using the standard pendant drop technique. Damping of capillary waves on pendant drops was shown to be similar to that observed for deep liquid baths and the kinematic viscosities obtained were in agreement with literature values for all three liquids studied.

  5. Synthesis and Reactivity of Tripodal Complexes Containing Pendant Bases

    Blacquiere, Johanna M.; Pegis, Michael L.; Raugei, Simone; Kaminsky, Werner; Forget, Amelie; Cook, Sarah; Taguchi, Taketo; Borovik, Andrew S.; Mayer, James M.

    2014-09-02

    The synthesis of a new tripodal ligand family is reported, with tertiary-amine groups in the second-coordination sphere. The ligands are tris(amido)amine derivatives, with the pendant amines attached via a peptide coupling strategy. They were designed to be used in new catalysts for the oxygen reduction reaction (ORR), in which the pendant acid/base group could improve catalyst performance. Two members of the new ligand family were each metallated with Co(II) and Zn(II) to afford trigonal monopyramidal complexes. Reaction of the cobalt complexes, [Co(L)]-, with dioxygen reversibly generates a small amount of a Co(III)-superoxo species, which was characterized by EPR. Protonation of the zinc complex Zn[N{CH2CH2NC(O)CH2N(CH2Ph)2}3)-– ([Zn(TNBn)]-) with one equivalent of acid occurs with displacement and dissociation of an amide ligand. Addition of excess acid to the any of the complexes [M(L)]- results in complete proteolysis and formation of the ligands H3L. This decomposition limits the use of these complexes as catalysts for the ORR. An alternative ligand with two pyridyl arms was also prepared but could not be metallated. These studies highlight the importance of stability of the primary-coordination sphere of ORR electrocatalysts to both oxidative and acidic conditions. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences.

  6. Mechanical vibrations of pendant liquid droplets

    Temperton, Robert H.; Smith, Michael I.; Sharp, James S.

    2015-01-01

    A simple optical deflection technique was used to monitor the vibrations of microlitre pendant droplets of deuterium oxide, formamide, and 1,1,2,2-tetrabromoethane. Droplets of different volumes of each liquid were suspended from the end of a microlitre pipette and vibrated using a small puff of nitrogen gas. A laser was passed through the droplets and the scattered light was collected using a photodiode. Vibration of the droplets resulted in the motion of the scattered beam and time-dependen...

  7. Pyridinediimine Iron Complexes with Pendant Redox-Inactive Metals Located in the Secondary Coordination Sphere.

    Delgado, Mayra; Ziegler, Joshua M; Seda, Takele; Zakharov, Lev N; Gilbertson, John D

    2016-01-19

    A series of pyridinediimine (PDI) iron complexes that contain a pendant 15-crown-5 located in the secondary coordination sphere were synthesized and characterized. The complex Fe((15c5)PDI)(CO)2 (2) was shown in both the solid state and solution to encapsulate redox-inactive metal ions. Modest shifts in the reduction potential of the metal-ligand scaffold were observed upon encapsulation of either Na(+) or Li(+).

  8. Synthesis of Unsymmetrical Bissalicylaldimine Ligands and bis-Schiff Base Cobalt Complexes with Benzo-10-aza-15-crown-5 Pendant

    LI Jian-Zhang; XU Bin; FENG Fa-Mei; ZHOU Bo; QIN Sheng-Ying

    2007-01-01

    Novel unsymmetrical bissalicylaldimine bis-Schiff bases with a benzo-10-aza-15-crown-5 pendant and their cobalt complexes have been synthesized via condensation of 3 or 5-[(benzo-10-aza-15-crown-5)-10-ylmethyl] salicylaldehyde with the half unit Schiff bases and characterized by 1H NMR, IR, mass spectroscopy, elemental analysis, molar conductances and molar magnetic susceptibility.

  9. Pendant dual sulfonated poly(arylene ether ketone) proton exchange membranes for fuel cell application

    Nguyen, Minh Dat Thinh; Yang, Sungwoo; Kim, Dukjoon

    2016-10-01

    Poly(arylene ether ketone) (PAEK) possessing carboxylic groups at the pendant position is synthesized, and the substitution degree of pendant carboxylic groups is controlled by adjusting the ratio of 4,4-bis(4-hydroxyphenyl)valeric acid and 2,2-bis(4-hydroxyphenyl)propane. Dual sulfonated 3,3-diphenylpropylamine (SDPA) is grafted onto PAEK as a proton-conducting moiety via the amidation reaction with carboxylic groups. The transparent and flexible membranes with different degrees of sulfonation are fabricated so that we can test and compare their structure and properties with a commercial Nafion® 115 membrane for PEMFC applications. All prepared PAEK-SDPA membranes exhibit good oxidative and hydrolytic stability from Fenton's and high temperature water immersion test. SAXS analysis illustrates an excellent phase separation between the hydrophobic backbone and hydrophilic pendant groups, resulting in big ionic clusters. The proton conductivity was measured at different relative humidity, and its behavior was analyzed by hydration number of the membrane. Among a series of membranes, some samples (including B20V80-SDPA) show not only higher proton conductivity, but also higher integrated cell performance than those of Nafion® 115 at 100% relative humidity, and thus we expect these to be good candidate membranes for proton exchange membrane fuel cells (PEMFCs).

  10. ASSOCIATION BEHAVIOR OF PORPHYRIN PENDANTS IN pH-SENSITIVE WATER-SOLUBLE POLYMER

    Ke-wei Ding; Fei Wang; Fei-peng Wu

    2012-01-01

    A novel tripyridylporphyrin monomer,5-[4-[2-(acryloyloxy)ethoxy]phenyl]-10,15,20-tris(4-pyridyl)porphyrin (TrPyP),was synthesized and polymerized with acrylamide (AM) to prepare the hydrophobically associating water-soluble polymer PAM-TrPyP.The aggregation behavior of porphyrin pendants was investigated by UV-Visible and fluorescence spectra.The polymer displays a strong tendency of hydrophobic association even in dilute solutions.With increasing the concentration,the maximum absorption wavelength of Sorer band changes from 416 nm to 407 nm,and the fluorescence corrected for the inner filter effect exhibits moderate concentration quenching.All the results indicate that π-π interaction of porphyrin pendants plays a key role in association of PAM-TrPyP,and H-aggregates of porphyrins are mainly formed in the conccntrated solution.On the other hand,dynamic light scattering (DLS) and transmission electron microscopy (TEM) were used to follow the changes in size and structure of the macromolecular assemblies with the concentration increase.The polymer aggregation conformation changes from loose "vesicle-like" morphology to solid globule accordingly.When pH value of solution decreases to 4.3,pyridine moieties on porphyrin pendants could be protonated and the H-aggregates formed in macromolecular matrix are destroyed by electrostatic repulsion interactions.

  11. Synthesis and Preliminary Properties of Novel Poly(aryl ethers Containing β-Naphthalene Pendant Group

    L. Wang

    2014-01-01

    Full Text Available Two novel poly(aryl ethers containing β-naphthalene pendant group were synthesized and the structures of these polymers were confirmed by 1HNMR spectroscopy. The polymers exhibited good thermal stabilities with high Tg of 256°C and 274°C, respectively. The polymers are soluble in common organic solvents, such as DMAc, DMSO, CH2Cl2, and CHCl3, and can be electrospun into microfiber (1–5 µm with lots of nanopores (<100 nm from CHCl3 solution. These fibers showed high hydrophobicity, and the contact angle of fibers is above 120°.

  12. SYNTHESIS OF POLY ( ETHER-URETHANE) CONTAINING PENDANT AMINO GROUP

    WU Jinhuang; SUN Yanhui; FENG Xinde

    1989-01-01

    This paper is concerned with the synthesis of poly (ether-urethane) with pendant amino groups. The copolyether produced by ring opening copolymerization of tetrahydrofuran and epibromohydrin was treated with sodium azide in dimethylformamide to form azido substituted copolyether. The poly (ether-urethane) made from it was subjected to reduction reaction to convert azido group to amino group. The stress-strain behavior and dynamic-mechanical properties of poly (ether-urethane) containing pendant amino groups were studied.

  13. Communications: Wall free capillarity and pendant drop removal.

    Hong, Siang-Jie; Chang, Feng-Ming; Chan, Seong Heng; Sheng, Yu-Jane; Tsao, Heng-Kwong

    2010-04-28

    When a sessile drop encounters a pendant drop through a hole, it is generally anticipated that they will coalesce and flow downward due to gravity. However, like "wall-free" capillarity, we show that the pendant drop may be sucked up by a sliding drop instantaneously if the radius of the curvature of the former is smaller than that of the later. This phenomenon can be explained by Laplace-Young equation and convective Ostwald ripening. Our results indicate that superhydrophilic perforated surface can be used as an effective way for the removal of small droplets adhering to the inner walls of microchannel systems.

  14. Facile synthesis and characterization of novel biodegradable amphiphilic block copolymers bearing pendant hydroxyl groups

    Hu, Gaicen; Fan, Xiaoshan; Xu, Bingcan; Zhang, Delong; Hu, Zhiguo, E-mail: zghu@htu.cn

    2014-10-01

    Novel amphiphilic block copolymers bearing pendant hydroxyl groups polylactide-b–poly(3,3-bis(Hydroxymethyl–triazolylmethyl) oxetane)-b–polylactide (PLA-b–PHMTYO-b–PLA) were synthesized via a facile and efficient method. First, the block copolymer intermediates polylactide-b–poly(3,3-Diazidomethyloxetane)-b–polylactide (PLA-b–PBAMO-b–PLA) were synthesized through ring-opening polymerization of lactide using PBAMO as a macroinitiator. Following “Click” reaction of PLA-b–PBAMO-b–PLA with propargyl alcohol provided the targeted amphiphilic block copolymers PLA-b–PHMTYO-b–PLA with pendant hydroxyl groups. The composition and structure of prepared copolymers were characterized by {sup 1}H nuclear magnetic resonance ({sup 1}H NMR) spectroscopy, Fourier transform infrared (FT-IR) and gel permeation chromatography (GPC). The self-assembly behavior of the copolymers in water was investigated by transmission electron microscope (TEM), dynamic light scattering (DLS) and static light scattering (SLS). The results showed that the novel copolymers PLA-b–PHMTYO-b–PLA self-assembled into spherical micelles with diameters ranging from 100 nm to 200 nm in aqueous solution. These copolymers also exhibited low critical micellar concentrations (CMC: 6.9 × 10{sup −4} mg/mL and 3.9 × 10{sup −5} mg/mL, respectively). In addition, the in vitro cytotoxicity of these copolymers was determined in the presence of L929 cells. The results showed that the block copolymers PLA-b–PHMTYO-b–PLA exhibited better biocompatibility. Therefore, these well-defined copolymers are expected to find some applications in drug delivery or tissue engineering. - Highlights: • The method to synthesize PLA-b–PHMTYO-b–PLA is relatively facile and efficient. • PLA-b–PHMTYO-b–PLA self-assembles into spherical micelles with low CMC in water. • PLA-b–PHMTYO-b–PLA exhibits better biocompatibility and biodegradability.

  15. Protonation Studies of a Tungsten Dinitrogen Complex Supported by a Diphosphine Ligand Containing a Pendant Amine

    Weiss, Charles J. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Egbert, Jonathan D. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Chen, Shentan [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Helm, Monte L. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Bullock, R. Morris [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Mock, Michael T. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2014-04-28

    Treatment of trans-[W(N2)2(dppe)(PEtNMePEt)] (dppe = Ph2PCH2CH2PPh2; PEtNMePEt = Et2PCH2N(Me)CH2PEt2) with three equivalents of tetrafluoroboric acid (HBF4∙Et2O) at -78 °C generated the seven-coordinate tungsten hydride trans-[W(N2)2(H)(dppe)(PEtNMePEt)][BF4]. Depending on the temperature of the reaction, protonation of a pendant amine is also observed, affording trans-[W(N2)2(H)(dppe)(PEtNMe(H)PEt)][BF4]2, with formation of the hydrazido complex, [W(NNH2)(dppe)(PEtNMe(H)PEt)][BF4]2, as a minor product. Similar product mixtures were obtained using triflic acid (HOTf). Upon acid addition to the carbonyl analogue, cis-[W(CO)2(dppe)(PEtNMePEt)], the seven-coordinate carbonyl-hydride complex, trans-[W(CO)2(H)(dppe)(PEtN(H)MePEt)][OTf]2 was generated. The mixed diphosphine complex without the pendant amine in the ligand backbone, trans-[W(N2)2(dppe)(depp)] (depp = Et2P(CH2)3PEt2), was synthesized and treated with HBF4∙Et2O, selectively generating a hydrazido complex, [W(NNH2)(F)(dppe)(depp)][BF4]. Computational analysis was used to probe proton affinity of three sites of protonation, the metal, pendant amine, and N2 ligand in these complexes. Room temperature reactions with 100 equivalents of HOTf produced NH4+ from reduction of the N2 ligand (electrons come from W). The addition of 100 equivalents HOTf to trans-[W(N2)2(dppe)(PEtNMePEt)] afforded 0.88 ± 0.02 equivalents NH4+, while 0.36 ± 0.02 equivalents of NH4+was formed upon treatment of trans-[W(N2)2(dppe)(depp)], the complex without the pendant amine. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy Office of Science, Office of Basic Energy Sciences. Computational resources were provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for DOE.

  16. SYNTHESIS AND PHOTOCHROMISM OF ACRYLIC ESTER COPOLYMERS BEARING PENDANT VIOLOGEN GROUPS

    SUN Xuehui; YANG Yukun

    1996-01-01

    A series of acrylic ester copolymers with viologen group as pendant were synthesized through the reaction of MMA-EBA (Ethenyl bromoacetate) copolymer with 4-(4'-pyridyl)-N-alkyl (or arylalkyl) pyridiniums. These viologen copolymers can exchange their anion with NH4PF6 in methanol to improve their solubility in organic solvents such as DMF and acetone. Compared with the corresponding low molecular viologens, these viologen copolymers have relatively lower color development rate under UV light and fade faster in air due to less affinity to photo-reductant and deficiency of association between their cation radicals. Their photofatigue resistant ability is also slightly better than that of low molecular viologens.

  17. A water-soluble polycarbonate with dimethylamino pendant groups prepared by enzyme-catalyzed ring-opening polymerization.

    Zhang, Xiaojin; Cai, Mengmeng; Zhong, Zhenlin; Zhuo, Renxi

    2012-04-23

    A water-soluble polycarbonate with dimethylamino pendant groups, poly(2-dimethylaminotrimethylene carbonate) (PDMATC), is synthesized and characterized. First, the six-membered carbonate monomer, 2-dimethylaminotrimethylene carbonate (DMATC), is prepared via the cyclization reaction of 2-(dimethylamino)propane-1,3-diol with triphosgene in the presence of triethylamine. Although the attempted ring-opening polymerization (ROP) of DMATC with Sn(Oct)(2) as a catalyst fails, the ROP of DMATC is successfully carried out with Novozym-435 as a catalyst to give water-soluble aliphatic polycarbonate PDMATC with low cytotoxicity and good degradability.

  18. Experimental Investigation of Pendant and Sessile Drops in Microgravity

    Zhu, Zhi-Qiang; Brutin, David; Liu, Qiu-Sheng; Wang, Yang; Mourembles, Alexandre; Xie, Jing-Chang; Tadrist, Lounes

    2010-09-01

    The experiments regarding the contact angle behavior of pendant and sessile evaporating drops were carried out in microgravity environment. All the experiments were performed in the Drop Tower of Beijing, which could supply about 3.6 s of microgravity (free-fall) time. In the experiments, firstly, drops were injected to create before microgravity. The wettability at different surfaces, contact angles dependance on the surface temperature, contact angle variety in sessile and pendant drops were measured. Different influence of the surface temperature on the contact angle of the drops were found for different substrates. To verify the feasibility of drops creation in microgravity and obtain effective techniques for the forthcoming satellite experiments, we tried to inject liquid to create bigger drop as soon as the drop entering microgravity condition. The contact angle behaviors during injection in microgravity were also obtained.

  19. NETWORK CROWN ETHER POLYMERS WITH CENTRIC FUNCTIONAL GROUPS.Ⅱ.SYNTHESIS OF NETROWK CROWN ETHER POLYMER WITH PENDANT SULFIDE SIDE CHAIN AND ITS PLATINUM COMPLEX

    CHENYuanyin; MENGLingzhi; 等

    1995-01-01

    Network crown ether polymer with pendant sulfide side chain in the network structure units has been synthesized via ring-opening copolymerization of β-ethylthioethyl glycidyl ether and diethylene glycol bisglycidyl ether.A kind of active catalyst suitable for this reaction was suggested.The title polymer was found to be a good ligand for platinous chloride,and the platinous complex could catalyze the hydrosilylation of ole fins with triethoxysilane efficiently.

  20. Pendant bubble method for an accurate characterization of superhydrophobic surfaces.

    Ling, William Yeong Liang; Ng, Tuck Wah; Neild, Adrian

    2011-12-06

    The commonly used sessile drop method for measuring contact angles and surface tension suffers from errors on superhydrophobic surfaces. This occurs from unavoidable experimental error in determining the vertical location of the liquid-solid-vapor interface due to a camera's finite pixel resolution, thereby necessitating the development and application of subpixel algorithms. We demonstrate here the advantage of a pendant bubble in decreasing the resulting error prior to the application of additional algorithms. For sessile drops to attain an equivalent accuracy, the pixel count would have to be increased by 2 orders of magnitude.

  1. Sequential and competitive adsorption of peptides at pendant PEO layers.

    Wu, Xiangming; Ryder, Matthew P; McGuire, Joseph; Snider, Joshua L; Schilke, Karl F

    2015-06-01

    Earlier work provided direction for development of responsive drug delivery systems based on modulation of the structure, amphiphilicity, and surface density of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. In this work, we describe the sequential and competitive adsorption behavior of such peptides at pendant PEO layers. Three cationic peptides were used for this purpose: the arginine-rich, amphiphilic peptide WLBU2, a peptide chemically identical to WLBU2 but of scrambled sequence (S-WLBU2), and the non-amphiphilic peptide poly-L-arginine (PLR). Optical waveguide lightmode spectroscopy (OWLS) was used to quantify the rate and extent of peptide adsorption and elution at surfaces coated with PEO. UV spectroscopy and time-of-flight secondary ion mass spectrometry (TOF-SIMS) were used to quantify the extent of peptide exchange during the course of sequential and competitive adsorption. Circular dichroism (CD) was used to evaluate conformational changes after adsorption of peptide mixtures at PEO-coated silica nanoparticles. Results indicated that amphiphilic peptides are able to displace adsorbed, non-amphiphilic peptides in PEO layers, while non-amphiphilic peptides were not able to displace more amphiphilic peptides. In addition, peptides of greater amphiphilicity dominated the adsorption at the PEO layer from mixtures with less amphiphilic or non-amphiphilic peptides.

  2. Reactivity of Schiff Base Manganese(Ill) Complexes with Different Pendants toward the Hydrolysis of p-Nitrophenyl Picolinate%Reactivity of Schiff Base Manganese(Ill) Complexes with Different Pendants toward the Hydrolysis of p-Nitrophenyl Picolinate

    蒋维东; 何锡阳; 王莹; 徐斌; 李建章; 刘富安

    2011-01-01

    This paper describes the catalytic performance of two manganese(III) complexes with mono-Schiff base ligands as artificial hydrolases towards the hydrolysis of p-nitrophenyl picolinate (PNPP). Observations reveal that the one complex ( MnL22C1 ) containing morpholine pendants exhibits 1.2-1.7 fold kinetic advantage over the other one (MnL12C1) containing benzoaza-15-crown-5 group. Especially, optimum molecule structures using a Gaussian 03 software confirm that MnL2CI indeed possesses a relatively open linked site for the approaching of PNPP, result- ing in higher efficiency due to a convenient association between substrate (PNPP) and MnL2C1. In addition, the steric hindrance of two pendants, i.e., benzoaza-15-crown-5 and morpholine, may be a main influencing factor for tuning catalytic activities of the synthesized Mn(III) catalysts. Both Mn(III) catalysts used here were found to have fine tolerance to the operated temperature and pH. Related kinetic and thermodynamic analyses were also given to demonstrate their structure-activity relationships (SAR) of both catalysts used.

  3. Waveform synthesizer

    Franks, Larry A.; Nelson, Melvin A.

    1981-01-01

    A method of producing optical and electrical pulses of desired shape. An optical pulse of arbitrary but defined shape illuminates one end of an array of optical fiber waveguides of differing lengths to time differentiate the input pulse. The optical outputs at the other end of the array are combined to form a synthesized pulse of desired shape.

  4. On the Odd Gracefulness of Cyclic Snakes With Pendant Edges

    E. M. Badr

    2013-01-01

    Full Text Available Graceful and odd gracefulness of a graph are two entirely different concepts. A graph may posses one orboth of these or neither. We present four new families of odd graceful graphs. In particular we show an oddgraceful labeling of the linear kC4 − snake e mK1 and therefore we introduce the odd graceful labeling of4 1 kC − snake e mK ( for the general case . We prove that the subdivision of linear 3 kC − snake is oddgraceful. We also prove that the subdivision of linear 3 kC − snake with m-pendant edges is odd graceful.Finally, we present an odd graceful labeling of the crown graph n 1 P e mK .

  5. Assemble four-arm DNA junctions into nanoweb

    2001-01-01

    DNA is of structural polymorphism, which is useful in nanoarchitecture; especially, four-arm DNA junc tions can be used to assemble nanowebs. The static four-arm DNA junctions were designed and synthesized. One-arm DNA and two-arm DNA came out simultaneously with the four-arm DNA junction's formation. A new method, termed the two-step method, was proposed and the productivity of four-arm DNA junctions was increased. A nanoweb was assembled successfully, but it showed irregularity itself. It was not the same as we expected. We consider that it is aresult from the flexibility of four-arm DNA junction.

  6. Origin of strong chiroptical activities in films of nonafluorenes with a varying extent of pendant chirality.

    Geng, Yanhou; Trajkovska, Anita; Culligan, Sean W; Ou, Jane J; Chen, H M Philip; Katsis, Dimitris; Chen, Shaw H

    2003-11-19

    Novel nonafluorenes with a varying extent of pendant chirality were synthesized for an investigation of the origins of chiroptical activities in neat films. Thermal annealing of 4-microm-thick sandwiched films and of 90-nm-thick spin-cast films, all on surface-treated substrates, produced monodomain glassy films characterized as a right-handed cholesteric stack with a helical pitch length ranging from 180 to 534 nm and from 252 to 1151 nm, respectively. The observed strong circular dichroism (CD) and g(e) as functions of helical pitch length in single-substrate monodomain glassy cholesteric films were quantitatively interpreted with a circularly polarized fluorescence theory accounting for light absorption, emission, and propagation in a cholesteric stack. Although intertwined molecular helices were likely to be present, cholesteric stacking of rodlike molecules seemed to be the predominant contributor to the strong chiroptical activities. All the cholesteric stacks comprising a polydomain glassy film on an untreated substrate were found to contribute to CD and g(e) largely to the same extent as in a monodomain film. A circularly polarized blue organic light-emitting diode containing a nonafluorene film resulted in a g(e) of 0.35 with a luminance yield of 0.94 cd/A at 20 mA/cm(2), the best performance to date.

  7. POLYAMIDES WITH PENDANT 1,3,4-OXADIAZOLE AND PYRIDINE MOIETIES

    Yagoub Mansoori; Behzad Koohi-Zargar; Hemayat Shekaari; Mohammad Reza Zamanloo; Gholam Hassan Imanzadeh

    2012-01-01

    A novel aromatic diamine,2-(5-(3,5-diaminophenyl)-1,3,4-oxadiazole-2-yl)pyridine (POBD),containing a pyridine ring and a 1,3,4-oxadiazole moiety,was synthcsized.It was used in a polycondensation with various aromatic and aliphatic diacid chlorides to generate a series of new aromatic polyamides with pendant 1,3,4-oxadiazole groups.The prepared polyamides were characterized by IR,elemental analysis and through the synthesis of model compounds.Thermophysical properties of the synthesized polyamides have been studied by DSC,TGA and inherent viscosity measurements.Relatively high inherent viscosity values (0.76-1.62 dL/g,in 0.125% H2SO4 at 25℃) were observed for these compounds.Number average molecular weight (Mn) of the polymers was measured by vapor phase osmometry (VPO).The introduction of bulky side chains in the structure of aromatic polyamides led to increased solubility of these polymers in common polar and aprotic solvents,such as DMF,DMSO,NMP and DMAc,which allowed thin films to be cast from polymer solutions.The highest molecular weight (Mn =51190) was observed for polymer (Ⅸ),which was prepared from pyridine-2,6-dichlorocarbonyl.

  8. Synthesis and Ionic Conductivity of Siloxane Based Polymer Electrolytes with Propyl Butyrate Pendant Groups

    Jalagonia, Natia; Tatrishvili, Tamara; Markarashvili, Eliza; Aneli, Jimsher; Mukbaniani, Omar [Javakhishvili Tbilisi State University, Tbilisi (Georgia); Grazulevicius, Jouzas Vidas [Kaunas University of Technology, Kaunas (Lithuania)

    2016-02-15

    Hydrosilylation reactions of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl butyrate catalyzed by Karstedt's, H2PtCl6 and Pt/C catalyst were studied and 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane was obtained. The reaction order, activation energies and rate constants were determined. Ringopening polymerization of 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane in the presence of CaF2, LiF, KF and anhydrous potassium hydroxide in 60-70 .deg. C temperature range was carried out and methylsiloxane oligomers with regular arrangement of propyl butyrate pendant groups were obtained. The synthesized products were studied by FTIR and NMR spectroscopy. The polysiloxanes were characterized by wide-angle X-ray, gel-permeation chromatography and DSC analyses. Via sol-gel processes of oligomers doped with lithium trifluoromethylsulfonate or lithium bis (trifluoromethylsulfonyl)imide, solid polymer electrolyte membranes were obtained. The dependences of ionic conductivity of obtained polyelectrolytes on temperature and salt concentration were investigated, and it was shown that electric conductivity of the polymer electrolyte membranes at room temperature changed in the range 3.5x10{sup -4} - 6.4xa0{sup -7} S/cm.

  9. Concentration effects on peptide elution from pendant PEO layers.

    Wu, Xiangming; Ryder, Matthew P; McGuire, Joseph; Schilke, Karl F

    2014-06-01

    In earlier work, we have provided direction for development of responsive drug delivery systems based on modulation of structure and amphiphilicity of bioactive peptides entrapped within pendant polyethylene oxide (PEO) brush layers. Amphiphilicity promotes retention of the peptides within the hydrophobic inner region of the PEO brush layer. In this work, we describe the effects of peptide surface density on the conformational changes caused by peptide-peptide interactions, and show that this phenomenon substantially affects the rate and extent of peptide elution from PEO brush layers. Three cationic peptides were used in this study: the arginine-rich amphiphilic peptide WLBU2, the chemically identical but scrambled peptide S-WLBU2, and the non-amphiphilic homopolymer poly-l-arginine (PLR). Circular dichroism (CD) was used to evaluate surface density effects on the structure of these peptides at uncoated (hydrophobic) and PEO-coated silica nanoparticles. UV spectroscopy and a quartz crystal microbalance with dissipation monitoring (QCM-D) were used to quantify changes in the extent of peptide elution caused by those conformational changes. For amphiphilic peptides at sufficiently high surface density, peptide-peptide interactions result in conformational changes which compromise their resistance to elution. In contrast, elution of a non-amphiphilic peptide is substantially independent of its surface density, presumably due to the absence of peptide-peptide interactions. The results presented here provide a strategy to control the rate and extent of release of bioactive peptides from PEO layers, based on modulation of their amphiphilicity and surface density.

  10. Arménie

    François Verdier

    2012-04-01

    Full Text Available L’Arménie est une petite république du Caucase, à la limite sud–est de l’Europe, qui a gagné son autonomie en 1990 après l’ouverture du bloc soviétique. Le nouveau Ministère du Patrimoine a sollicité la coopération de la France pour mettre en place une nouvelle politique culturelle. Tout d’abord, une évaluation sur place de la situation dans les domaines des monuments historiques, de l’archéologie et de l’Inventaire a permis d’envisager les réponses à proposer. Pour la demande d’informatisation des dossiers d’inventaire déjà réalisés sous l’autorité de l’Académie de Saint–Petersbourg, nous avons proposé de former des chercheurs arméniens aux méthodes et techniques de l’Inventaire général. L’accueil d’une stagiaire pendant trois mois au service régional de l’Inventaire de Haute–Normandie a été suivi par la mise en place d’un équipement informatique à Yérévan, puis par l’accueil et la formation de techniciens informaticiens et photographes arméniens. De retour dans leur pays ils ont commencé à remettre en place un service d’inventaire dont le programme comprend la création d’une base de données patrimoniales, le recensement de la ville de Yérévan, la numérisation d’images pour la publication d’un indicateur du patrimoine et la préparation de dossiers de protection au titre du patrimoine mondial.The Armenian heritage comprises both archaeological remains of towns destroyed by never–ending wars and a number of old churches from the eleventh and twelfth centuries. Yerevan, the capital of Armenia, was founded three thousand years ago and is one of Europe’s oldest capitals. From 1925 it has developed according to an ambitious urban planning project. After the major political upheavals of 1991, a special ministry was created to look after the architectural and movable heritage of the country and to promote the Armenian national identity. A mission in Yerevan was

  11. Removal and recovery of toxic metal ions from aqueous waste sites using polymer pendant ligands

    Fish, D. [Lawrence Berkeley National Lab., CA (United States)

    1996-10-01

    The purpose of this project is to investigate the use of polymer pendant ligand technology to remove and recover toxic metal ions from DOE aqueous waste sites. Polymer pendant lgiands are organic ligands, anchored to crosslinked, modified divinylbenzene-polystyrene beads, that can selectively complex metal ions. The metal ion removal step usually occurs through a complexation or ion exchange phenomena, thus recovery of the metal ions and reuse of the beads is readily accomplished.

  12. Quantifying nisin adsorption behavior at pendant PEO layers.

    Dill, Justen K; Auxier, Julie A; Schilke, Karl F; McGuire, Joseph

    2013-04-01

    The antimicrobial peptide nisin shows potent activity against Gram-positive bacteria including the most prevalent implant-associated pathogens. Its mechanism of action minimizes the opportunity for the rise of resistant bacteria and it does not appear to be toxic to humans, suggesting good potential for its use in antibacterial coatings for selected medical devices. A more quantitative understanding of nisin loading and release from polyethylene oxide (PEO) brush layers will inform new strategies for drug storage and delivery, and in this work optical waveguide lightmode spectroscopy was used to record changes in adsorbed mass during cyclic adsorption-elution experiments with nisin, at uncoated and PEO-coated surfaces. PEO layers were prepared by radiolytic grafting of Pluronic® surfactant F108 or F68 to silanized silica surfaces, producing long- or short-chain PEO layers, respectively. Kinetic patterns were interpreted with reference to a model accounting for history-dependent adsorption, in order to evaluate rate constants for nisin adsorption and desorption, as well as the effect of pendant PEO on the lateral clustering behavior of nisin. Nisin adsorption was observed at the uncoated and F108-coated surfaces, but not at the F68-coated surfaces. Nisin showed greater resistance to elution by peptide-free buffer at the uncoated surface, and lateral rearrangement and clustering of adsorbed nisin was apparent only at the uncoated surface. We conclude peptide entrapment at the F108-coated surface is governed by a hydrophobic inner region of the PEO brush layer that is not sufficient for nisin entrapment in the case of the shorter PEO chains of the F68-coated surface.

  13. Synthesis and properties of poly(1-phenyl-1-octyne)s containing stereogenic and chromophoric pendant groups

    LAM; Jacky; W.Y.; JIM; Cathy; K.W.; KWOK; Hoi; Sing

    2009-01-01

    Poly(1-phenyl-1-octyne)s containing different stereogenic and chromophoric pendants {-[(C6H13)C=C(C6H4-p-CO2-R)]n-R=[(1S)-endo]-(-)-borneyl (P3), (1R,2S,5R)-(-)-menthyl (P4),―C6H4-p-(1R,2S,5R)-(-)-menthyl (P5), 2-napthyl (P6), 4-biphenylyl (P7)} have been designed and synthesized. The polymers are prepared in moderate yields by WCl6-Ph4Sn and possess high molecular weights (Mw up to 64000). The structures and properties of the polymers are characterized and evaluated by NMR, TGA, UV, CD, PL, and EL analyses. All the polymers are thermally stable and their temperatures for 5% weight loss locate in the range of 300 to 416℃ under nitrogen. The energy band gaps of all the polymers are ~3.0 eV. Polymers P4 and P5 show CD absorptions associated with the helicity of the polymer segments. Excitation of the THF solutions of P3―P7 by UV irradiation gives strong blue lights of ~485 nm with quantum yields higher than 20%. The thin films of the polymers also emit in the same spectral region, indicative of little aggregation-caused quenching of light emission. Multilayer EL devices with a configuration of ITO/Polymer:PVK/BCP/Alq3/LiF/Al are constructed, which emit blue lights of ~487 nm. The maximum luminance and external quantum efficiency vary with the pendant groups, with P6 exhibiting the highest external quantum efficiency of 0.16%. The spectra stability of the EL devices is outstanding and the EL peak maximum experiences little change with the applied voltage.

  14. Controlled Synthesis of Fluorinated Copolymers with Pendant Sulfonates

    Dimitrov, Ivaylo; Jankova Atanasova, Katja; Hvilsted, Søren

    2008-01-01

    Novel fluorinated copolymers of different architectures and bearing sulfopropyl groups were synthesized by atom transfer radical polymerization (ATRP) of aromatic fluorinated monomers and two modification reactions performed on the polymer chain - demethylation followed by sulfopropylation. As a ...... characterized by size-exclusion chromatography, FTIR and IH NMR spectroscopy. Their thermal properties were investigated by differential scanning calorimetry and thermal gravimetric analyses....

  15. Supramolecular Complexation Behavior of Novel Cyclotrivera-trylene Derivatives with Benzoate Pendants with C60

    ZHAN Hao-Oiang; JIANG Xi-Kui; LI Zhan-Ting

    2001-01-01

    Four novel cyclotriveratrylene (CTV) derivatives with threebenzoate pendants bearing different aliphatic chains have been prepared in good yields,starting from.CTV.The complexa-tion behavior of these CTV derivatives towards C60 in arene solvents has been measured by UV-visible spectroscopy and high complexation constants are obtained.It is observed the me complexation is promoted by introducing methyl ester groups to the aromatic pendants, while this pro-moting effect is reduced when the methyl groups are replaced by longer alkyl groups.

  16. Reversible photochemical modifications in dicarbene-derived metallacycles with coumarin pendants.

    Han, Ying-Feng; Jin, Guo-Xin; Daniliuc, Constantin G; Hahn, F Ekkehardt

    2015-04-13

    Molecular rectangles were obtained from two bis(NHC) ligands, each featuring two terminal coumarin groups and two Ag(+), Au(+), or Cu(+) ions. Upon UV irradiation (λ=365 nm), the dinuclear complexes undergo photochemical modification through a [2+2] cycloaddition reaction of two adjacent coumarin moieties to give a macrocyclic tetra(NHC) ligand. The photodimerization of the coumarin pendants proceeds stereoselectively to give the syn-head-head isomers in all cases. Subsequent irradiation at λ=254 nm initiates a photocleavage reaction with reconstitution of the initial dinuclear complexes with coumarin pendants.

  17. Sulfonated copolyimide membranes derived from a novel diamine monomer with pendant benzimidazole groups for fuel cells

    Li, Wei; Guo, Xiaoxia; Aili, David;

    2015-01-01

    . A series of sulfonated copolyimides (SPI) are prepared via random copolymerizatio of 1,4,5,8-naphthalenetetracarboxylic dianhydride (NTDA) with a new diamine monomer with pendant benzimidazole groups, 2,2'-bis(4-(1H-benzo[d]imidazol-2-yl)phenoxy)benzidine (BIPOB), and a sulfonated diamine monomer 4,4'-bis...... pendant groups significantly improves the hydrolytic stability as well as the radical oxidative stability of the membranes. In addition, the SPI membranes exhibit high proton conductivities of 0.1 S cm(-1) in the fully hydrated state at 60 degrees C and high elastic modulus and tensile strength...

  18. Removal of Pendant Groups of Vinyl Polymers by Argon Plasma Treatment

    Groenewoud, L.M.H.; Terlingen, J.G.A.; Engbers, G.H.M.; Feijen, J.

    1999-01-01

    Poly(acrylic acid) (PAAc) and poly(vinyl chloride) (PVC) were treated with an argon plasma to create unsaturated bonds at the surface. By use of X-ray photoelectron spectroscopy and Fourier transform infrared measurements, it was shown that the pendant groups of these polymers are removed by the arg

  19. Comparison of the lateral retention forces on sessile and pendant water drops on a solid surface

    de la Madrid, Rafael; Whitehead, Taylor; Irwin, George

    2015-01-01

    We present a simple experiment that demonstrates how a water drop hanging from a Plexiglas surface (pendant drop) experiences a lateral retention force that is comparable to, and in some cases larger than, the lateral retention force on a drop resting on top of the surface (sessile drop). The experiment also affords a simple demonstration of the Coriolis effect in two dimensions.

  20. Synthesis of a Novel Blue- light- emitting Polymer Material Bearing Coumarin Pendants

    2002-01-01

    A novel blue luminescent polymer bearing coumarin pendants was prepared. Its luminescent properties were determined indicating that it had strong blue fluorescent properties and good film formation ability. This novel polymer can be used as a blue organic electroluminescent material (OELM) in organic electroluminescent devices.

  1. Synthesis of a Novel Blue—light—emitting Polymer Material Bearing Coumarin Pendants

    ZhiYunLU; TongSuoYUAN; 等

    2002-01-01

    A novel blue luminescent polymer bearing coumarin pendants was prepared. Its luminescent properties were determined indicating that it had strong blue fluorescent properies and good film formation ability. This novel polymer can be used as a blue organic electroluminescent material (OELM) in organic electroluminescent devices.

  2. Comparison of the lateral retention forces on sessile and pendant water drops on a solid surface

    de la Madrid, Rafael; Whitehead, Taylor; Irwin, George M.

    2015-06-01

    We present a simple experiment that demonstrates how a water drop hanging from a Plexiglas surface (pendant drop) experiences a lateral retention force that is comparable to, and in some cases larger than, the lateral retention force on a drop resting on top of the surface (sessile drop). The experiment also affords a simple demonstration of the Coriolis effect in two dimensions.

  3. Hydrogen-bond stabilized columnar discotic benzenetrisamides with pendant triphenylene groups

    Paraschiv, I.; Lange, de K.; Giesbers, M.; Lagen, van B.; Grozema, F.C.; Abellon, R.D.; Siebbeles, L.D.A.; Sudhölter, E.J.R.; Zuilhof, H.; Marcelis, A.T.M.

    2008-01-01

    series of 1,3,5-benzenetrisamide derivatives with three hexaalkoxytriphenylene pendant groups were prepared, in which the triphenylene groups are connected to the central 1,3,5-benzenetrisamide core through a flexible spacer. The length of this spacer, as well as the size of the ortho-substituent at

  4. Determination of cerium ion by polymeric membrane and coated graphite electrode based on novel pendant armed macrocycle

    Singh, Ashok K., E-mail: akscyfcy@iitr.ernet.in [Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee 247 667 (India); Singh, Prerna [Department of Chemistry, Indian Institute of Technology-Roorkee, Roorkee 247 667 (India)

    2010-08-24

    Plasticized membranes using 2,3,4:12,13,14-dipyridine-1,3,5,8,11,13,15,18-octaazacycloicosa-2,12-diene (L{sub 1}) and 2,3,4:12,13,14-dipyridine-1,5,8,11,15,18-hexamethylacrylate- 1,3,5,8,11,13,15,18-octaazacycloicosa-2,12-diene (L{sub 2}) have been prepared and explored as Ce(III) selective sensors. Effect of various plasticizers viz. dibutylphthalate (DBP), tri-n-butylphthalate (TBP), o-nitrophenyloctylether (o-NPOE), dioctylphthalate (DOP), benzylacetate (BA) and anion excluders, sodium tetraphenylborate (NaTPB) and potassium tetrakis p-(chlorophenyl) borate was studied in detail and improved performance was observed. Optimum performance was observed for the membrane sensor having a composition of L{sub 2}:PVC:o-NPOE:KTpClPB in the ratio of 6:34:58:2 (w/w, mg). The performance of the membrane based on L{sub 2} was compared with polymeric membrane electrode (PME) as well as with coated graphite electrode (CGE). The electrodes exhibit Nernstian slope for Ce(III) ions with limits of detection of 8.3 x 10{sup -8} mol L{sup -1} for PME and 7.7 x 10{sup -9} mol L{sup -1} for CGE. The response time for PME and CGE was found to be 12 s and 10 s respectively. The potentiometric responses are independent of the pH of the test solution in the pH range 3.5-7.5 for PME and 2.5-8.5 for CGE. The CGE could be used for a period of 5 months. The practical utility of the CGE has been demonstrated by its usage as an indicator electrode in potentiometric titration of oxalate and fluoride ions with Ce(III) solution. The proposed electrode was also successfully applied to the determination of fluoride ions in mouthwash solution and oxalate ions in real samples.

  5. Enhancement of 4-electron O2 reduction by a Cu(ii)-pyridylamine complex via protonation of a pendant pyridine in the second coordination sphere in water.

    Kotani, Hiroaki; Yagi, Tomomi; Ishizuka, Tomoya; Kojima, Takahiko

    2015-09-07

    We have synthesised a novel copper(ii) complex with a pyridine pendant as a proton relay port for electrocatalytic 4e(-) reduction of O2 in water. The enhancement of the electrocatalytic O2 reduction via protonation of the pyridine pendant is demonstrated in comparison with a copper(ii) complex without the pyridine pendant.

  6. ABA TRIBLOCK COPOLYMERS WITH PENDANT HYDROXYL GROUPS PREPARED BY CONTROLLED CATIONIC POLYMERIZATION AND THEIR USE AS DELIVERY CARRIER FOR PACLITAXEL

    Ping Ren; Yi-bo Wu; Wen-li Guo; Shu-xin Li; Ying Chen

    2013-01-01

    To improve the hydrophilicity of poly(styrene-b-isobutylene-b-styrene) (SIBS),this study focuses on the synthesis of novel functional ABA triblock copolymer thermoplastic elastomers (TPEs) with polyisobutylene (PIB) as rubbery segments.The precursor poly{(styrene-co-4-[2-(tert-butyldimethylsiloxy) ethyl]styrene)-b-isobutylene-b-(styrene-co-4-[2-(tert-butyldimethylsiloxy)ethyl]styrene)}(P(St-co-TBDMES)-PIB-P(St-co-TBDMES)) triblock copolymer was first synthesized by living sequential cationic copolymerization of isobutylene (IB) with styrene (St) and 4-[2-(tert-butyldimethylsiloxy)ethyl]styrene (TBDMES) using 1,4-di(2-chloro-2-propyl)benzene (DiCumC1)/titanium tetrachloride (TiCl4)/2,6-di-tert-butylpyridine (DtBP) as the initiating system.Then,P(St-co-TBDMES)-PIB-P(St-co-TBDMES) was hydrolyzed in the presence of tetra-butylammonium fluoride to yield poly{[styrene-co-4-(2-hydroxyethyl)styrene]-b-isobutylene-b-[styrene-co-4-(2-hydroxyethyl)styrene]} (P(St-co-HOES)-PIB-P(St-co-HOES)) with pendant hydroxyl groups.P(St-co-HOES)-PIB-P(St-co-HOES) used as the paclitaxel carrier was also investigated in this study.Comparing with SIBS,P(St-co-HOES)-PIB-P(St-co-HOES) has exhibited better compatibility with paclitaxel and higher release rate.

  7. Improved orthopedic arm joint

    Dane, D. H.

    1971-01-01

    Joint permits smooth and easy movement of disabled arm and is smaller, lighter and less expensive than previous models. Device is interchangeable and may be used on either arm at the shoulder or at the elbow.

  8. Arm Lift (Brachioplasty)

    ... sagging. An arm lift might also boost your body image. As you get older, the skin on your upper arms changes — sagging and becoming loose. Significant weight loss also can cause the undersides of your upper arms to droop. While exercise can strengthen and improve muscle tone in the ...

  9. The influence of pendant hydroxyl groups on enzymatic degradation and drug delivery of amphiphilic poly[glycidol-block-(epsilon-caprolactone)] copolymers.

    Mao, Jing; Gan, Zhihua

    2009-11-10

    An amphiphilic diblock copolymer PG-b-PCL with well-controlled structure and pendant hydroxyl groups along hydrophilic block was synthesized by sequential anionic ring-opening polymerization. The micellization and drug release of PG-b-PCL copolymers using pyrene as a fluorescence probe were investigated for determining the influences of copolymer composition and lipase concentration on drug loading capacity and controlled release behavior. The biodegradation of PG-b-PCL copolymers was studied with microspheres as research samples. It has been concluded that the polar hydroxyl groups along each repeat unit of hydrophilic PG block in PG-b-PCL copolymer have great influences on drug encapsulation, drug release, and enzymatic degradation of micelles and microspheres.

  10. Design and Engineering of a Chess-Robotic Arm

    Elouafiq, Ali

    2012-01-01

    In the scope of the "Chess-Bot" project, this study's goal is to choose the right model for the robotic arm that the "the Chess-Bot" will use to move the pawn from a cell to another. In this paper, there is the definition and the structure of a robot arm. Also, the different engineering and kinematics fundamentals of the robot and its components will be detailed. Furthermore, the different structures of robotic arms will be presented and compared based on different criteria. Finally, a model for "the Chess-Bot" arm will be synthesized based on accurate algorithms and equations.

  11. PENDANTS-MEDIAN SPANNING TREE PROBLEM AND ONE RELATED PROBLEM:COMPLEXITY AND ALGORITHM%Pendants-median支撑树及其一个相关问题:复杂性和算法

    付铅生; 李帮义

    2004-01-01

    The complexity status of Pendants-median spanning tree problem is an open problem. Using the complexity of the X3C problem, the paper proves that Pendants-median spanning tree problem is NP-complete. Global-median spanning tree problem is a related problem. Using the complexity of 3SAT, the paper proves that this problem is also NP-complete, and a polynomial -time algorithm to this problem is given, whose time complexity is O(n3).

  12. Measurement of contact angle between stainless steel surface and carbon dioxide by pendant drop method

    PEI NianQiang; GUO KaiHua; LIU Jie; LI TingXun

    2008-01-01

    To measure contact angle between CO2 and solid surface,in this study a visual high-pressure vessel has been developed,with a corresponding well-controlled constant temperature system.Pendant drop method is applied to the investigation of the contact angles of CO2 on a stainless steel surface in its own vapor.The image of the pendant drop is recorded by a camera,and a B-Snake method is used to analyze the contour and the contact angle of the droplet.The experimental results have provided a set of well tested data,which show that CO2 has good infiltration into stainless steel surface and the de-veloped method can be used as a standard testing one for measuring the contact angle between high-pressure liquid and solid surface.

  13. Unusual cyclic terpenoids with terminal pendant prenyl moieties: from occurrence to synthesis.

    Kulcitki, Veaceslav; Harghel, Petru; Ungur, Nicon

    2014-12-01

    The paper reviews the known examples of cyclic terpenoids produced from open chain polyenic precursors by an "unusual" biosynthetic pathway, involving selective electrophilic attack on an internal double bond followed by cyclization. The resulting compounds possess cyclic backbones with pendant terminal prenyl groups. Synthetic approaches applied for the synthesis of such specifically functionalized compounds are also discussed, as well as biological activity of reported representatives.

  14. Redox reactions of [FeFe]-hydrogenase models containing an internal amine and a pendant phosphine.

    Zheng, Dehua; Wang, Mei; Chen, Lin; Wang, Ning; Sun, Licheng

    2014-02-03

    A diiron dithiolate complex with a pendant phosphine coordinated to one of the iron centers, [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe2(CO)5}] (1), was prepared and structurally characterized. The pendant phosphine is dissociated together with a CO ligand in the presence of excess PMe3, to afford [(μ-SCH2)2N(CH2C6H4-o-PPh2){Fe(CO)2(PMe3)}2] (2). Redox reactions of 2 and related complexes were studied in detail by in situ IR spectroscopy. A series of new Fe(II)Fe(I) ([3](+) and [6](+)), Fe(II)Fe(II) ([4](2+)), and Fe(I)Fe(I) (5) complexes relevant to Hox, Hox(CO), and Hred states of the [FeFe]-hydrogenase active site were detected. Among these complexes, the molecular structures of the diferrous complex [4](2+) with the internal amine and the pendant phosphine co-coordinated to the same iron center and the triphosphine diiron complex 5 were determined by X-ray crystallography. To make a comparison, the redox reactions of an analogous complex, [(μ-SCH2)2N(CH2C6H5){Fe(CO)2(PMe3)}2] (7), were also investigated by in situ IR spectroscopy in the absence or presence of extrinsic PPh3, which has no influence on the oxidation reaction of 7. The pendant phosphine in the second coordination sphere makes the redox reaction of 2 different from that of its analogue 7.

  15. Use of the pendant drop method to measure interfacial tension between molten polymers

    Emerson Y. Arashiro

    1999-01-01

    Full Text Available In this paper the pendant drop method to measure interfacial tension between molten polymers is reviewed. A typical pendant drop apparatus is presented. The algorithms used to infer interfacial tension from the geometrical profile of the pendant drop are described in details, in particular a new routine to evaluate correctly the value of the radius at the apex of the drop, necessary to the calculation of interfacial tension is presented. The method was evaluated for the possibility of measuring the interfacial tension between polyethylene and polystyrene. It is shown that the method is unsuitable for the measurement of interfacial tension between high density polyethylene and polystyrene due possibly to a too small difference of density between the two polymers. Values of interfacial tension between low density polyethylene (LDPE and polystyrene (PS as a function of the molecular weight of PS are presented. It was shown that the interfacial tension between LDPE and PS increased as a function of molecular weight of PS up to values of molecular weight of roughly 40,000 g/mol, value for which entanglements occur.

  16. Effects of substitution and terminal groups for liquid-crystallinity enhanced luminescence of disubstituted polyacetylenes carrying chromophoric terphenyl pendants

    2010-01-01

    Liquid-crystalline and light-emitting poly(2-alkyne)s containing terphenyl cores with hexamethyleneoxy spacers,and cyano or n-propoxy tails -[CH3C=C(CH2)6O-terphenyl-R]n-,where R=CN,CH3PA6CN,R=OCH2CH2CH3,CH3PA6OPr,were synthesized.The effects of the substitution and terminal groups on the properties,especially the mesomorphic and optical properties of the polymers,were investigated.The disubstituted acetylene monomers (CH3A6CN,CH3A6OPr) were pre- pared through multistep reaction routes and were polymerized by WCl6-Ph4Sn in good yields (up to 82%).All the monomers and CH3PA6CN exhibited the enantiotropic SmA phase with a monolayer arrangement at elevated temperatures,whereas CH3PA6OPr formed a bilayer SmAd packing arrangement.Upon excitation at 330 nm,strong UV and blue emission peaks at 362 and 411 nm were observed in CH3PA6OPr and CH3PA6CN,respectively.The luminescent properties of CH3PA6CN and CH3PA6OPr have been improved by introducing the methyl substituted group,and the quantum yield of the polymer with cyano tail CH3PA6CN (φ= 74%) was found to be higher than that of CH3PA6OPr (φ= 60%).Compared to polyacety- lene parents,both CH3PA6OPr and CH3PA6CN showed a narrower energy gap.This demonstrated that the electrical con- ductivities of polyacetylenes could be enhanced by attaching appropriate pendants to the conjugated polyene backbones.

  17. Temperature-Triggered Switchable Helix-Helix Inversion of Poly(phenylacetylene Bearing l-Valine Ethyl Ester Pendants and Its Chiral Recognition Ability

    Yanli Zhou

    2016-11-01

    Full Text Available A phenylacetylene containing the l-valine ethyl ester pendant (PAA-Val was synthesized and polymerized by an organorhodium catalyst (Rh(nbdBPh4 to produce the corresponding one-handed helical cis-poly(phenylacetylene (PPAA-Val. PPAA-Val showed a unique temperature-triggered switchable helix-sense in chloroform, while it was not observed in highly polar solvents, such as N,N′-dimethylformamide (DMF. By heating the solution of PPAA-Val in chloroform, the sign of the CD absorption became reversed, but recovered after cooling the solution to room temperature. Even after six cycles of the heating-cooling treatment, the helix sense of the PPAA-Val’s backbone was still switchable without loss of the CD intensity. The PPAA-Val was then coated on silica gel particles to produce novel chiral stationary phases (CSPs for high-performance liquid chromatography (HPLC. These novel PPAA-Val based CSPs showed a high chiral recognition ability for racemic mandelonitrile (α = 2.18 and racemic trans-N,N′-diphenylcyclohexane-1,2-dicarboxamide (α = 2.60. Additionally, the one-handed helical cis-polyene backbone of PPAA-Val was irreversibly destroyed to afford PPAA-Val-H by heating in dimethyl sulfoxide (DMSO accompanied by the complete disappearance of the Cotton effect. Although PPAA-Val-H had the same l-valine ethyl ester pendants as its cis-isomer PPAA-Val, it showed no chiral recognition. It was concluded that the one-handed helical cis-polyene backbone of PPAA-Val plays an important role in the chiral recognition ability.

  18. ARM Mentor Selection Process

    Sisterson, D. L. [Argonne National Lab. (ANL), Argonne, IL (United States)

    2015-10-01

    The Atmospheric Radiation Measurement (ARM) Program was created in 1989 with funding from the U.S. Department of Energy (DOE) to develop several highly instrumented ground stations to study cloud formation processes and their influence on radiative transfer. In 2003, the ARM Program became a national scientific user facility, known as the ARM Climate Research Facility. This scientific infrastructure provides for fixed sites, mobile facilities, an aerial facility, and a data archive available for use by scientists worldwide through the ARM Climate Research Facility—a scientific user facility. The ARM Climate Research Facility currently operates more than 300 instrument systems that provide ground-based observations of the atmospheric column. To keep ARM at the forefront of climate observations, the ARM infrastructure depends heavily on instrument scientists and engineers, also known as lead mentors. Lead mentors must have an excellent understanding of in situ and remote-sensing instrumentation theory and operation and have comprehensive knowledge of critical scale-dependent atmospheric processes. They must also possess the technical and analytical skills to develop new data retrievals that provide innovative approaches for creating research-quality data sets. The ARM Climate Research Facility is seeking the best overall qualified candidate who can fulfill lead mentor requirements in a timely manner.

  19. Coalescence of pendant droplets on an inclined super-hydrophobic substrate

    Sikarwar, Basant Singh; Khanderkar, Sameer; Muralidhar, K.

    2013-07-01

    Dynamics of micro droplets, coalescence underneath an inclined hydrophobic surface is explored, experimentally as well as computationally. Such a situation often arises during dropwise condensation, atmospheric dew formation, condensation in green houses, and metal vapor condensation during enrichment process, etc. Coalescence induced instability in the pendant mode is an effective means of passively enhancing heat transfer coefficient during dropwise condensation. Inclined substrates have natural advantages in terms of rendering effective passive sweeping of drops from the substrate, thereby exposing fresh preferred sites for renucleation. As compared to coalescences of sessile droplets, pendant mode induces flow instabilities at a much faster rate, thereby enhancing the associated heat/ mass transport characteristics. Against this background, the present study reports an experiment involving the coalescence of water drops in pendant mode on an inclined hydrophobic copper substrate of size 20 mm × 20 mm × 2 mm. The substrate has been prepared by developing a monolayer of n-octadecanethiol on it by chemical action. This work focuses on fundamental understanding of the mechanism of drop coalescence underneath an inclined super-hydrophobic substrate to provide aid in controlling and promoting dropwise mode of condensation in order to increase efficiency of condenser or to aid in enrichment of heavy liquid metals in closed vacuum condition. The coalescence process gets initiated by the extra available surface energy which gets released in the process. Immediately afterwards, the process of oscillating free surface formed during the coalescence is limited by viscous and inertia forces. The free surface oscillations can last ˜ 10 to 100 milliseconds, depending on the size of droplets and their thermophysical properties. Depending on the local wettability, size of drops which are coalescing, substrate inclination and pinning/de-pinning behavior, droplet instability

  20. PHASE STRUCTURE AND PROPERTIES OF EPOXY RESIN MODIFIED BY POLYSILOXANE BEARING PENDANT AMINO GROUPS

    Bing Zhang; Xiang-luan Liu; Ying Huang

    2000-01-01

    Polysiloxane-modified epoxy resins were prepared through the reaction of epoxy resin with polydimethylsiloxanes bearing pendant N-(β-aminoethyl)-γ-aminopropyl groups. The morphology and properties of the cured epoxy resins modified by the polysiloxanes were investigated. It was found that the phase structure and properties of the cured epoxy resins depend mainly on the amino group content in the polydimethylsiloxane and the level of the modifier. The change of phase structure in the cured epoxy resin systems was responsible for the dramatic change in their mechanical and surface properties.

  1. Presse et délation au Pays basque pendant la Guerre civile (1936-1937)

    Rojo Hernandez, Severiano

    2016-01-01

    Cet article analyse la délation pendant la guerre d’Espagne, en prenant pour exemple les lettres de dénonciation publiées dans les quotidiens basques antifascistes entre 1936 et 1937. This article analyzes delation during the Spanish Civil War, taking the example of the letters of denunciation published in the antifascist Basque newspapers between 1936 and 1937. Este artículo analiza la delación durante la Guerra Civil tomando como ejemplo las cartas de denuncia publicadas en la prensa ...

  2. Nonspecific Arm Pain

    Ali Moradi

    2013-12-01

    Full Text Available Nonspecific activity-related arm pain is characterized by an absence of objective physical findings and symptoms that do not correspond with objective pathophysiology. Arm pain without strict diagnosis is often related to activity, work-related activity in particular, and is often seen in patients with physically demanding work. Psychological factors such as catastrophic thinking, symptoms of depression, and heightened illness concern determine a substantial percentage of the disability associated with puzzling hand and arm pains. Ergonomic modifications can help to control symptoms, but optimal health may require collaborative management incorporating psychosocial and psychological elements of illness.

  3. Nonspecific Arm Pain

    Ali Moradi

    2013-12-01

    Full Text Available   Nonspecific activity-related arm pain is characterized by an absence of objective physical findings and symptoms that do not correspond with objective pathophysiology. Arm pain without strict diagnosis is often related to activity, work-related activity in particular, and is often seen in patients with physically demanding work. Psychological factors such as catastrophic thinking, symptoms of depression, and heightened illness concern determine a substantial percentage of the disability associated with puzzling hand and arm pains. Ergonomic modifications can help to control symptoms, but optimal health may require collaborative management incorporating psychosocial and psychological elements of illness.

  4. Arms Trafficking and Colombia

    2003-01-01

    Brasil , February 20, 2001. 20 Arms Trafficking and Colombia chased, when and how they were transferred to the guerrillas or paramilitaries, or through...Mercado Blanco De Armas,” 1999, p. 44. 31Franco, Ilimar, “Pf to Block Farc Supply Routes in Amazon,” Jornal do Brasil , August 20, 1999. 26 Arms...Forces Mobilize in Response to Farc,” Sao Paulo Veja, November 10, 1999. 43“Arms Trafficking to Colombia Increases,” El Comercio , August 23, 2000

  5. Des femmes dans la France combattante pendant la Deuxième Guerre mondiale : Le Corps des Volontaires Françaises et le Groupe Rochambeau

    Elodie Jauneau

    2009-01-01

    Full Text Available Cet article aborde la question de l’engagement des femmes dans l’Armée française pendant la Deuxième Guerre Mondiale grâce aux traces écrites qu’elles ont laissés.Dès 1940, plusieurs centaines de femmes rejoignent les rangs des FFL à Londres, mais aussi en Afrique du Nord (Algérie, Maroc, Tunisie. Elles s’engagent dans les trois corps d’Armée et sont présentes dans la plupart des services. Souvent dénigrées par les hommes, sous-estimées aussi, ces femmes accomplissent pourtant des tâches essentielles entre 1940 et 1945. Cet engagement moral, physique et souvent idéologique dans l’Armée de la Libération, devient pour la plupart d’entre elles un tournant définitif dans leur vie. Nombreuses sont celles qui ont éprouvé le besoin de raconter cette période si « particulière » de leur vie. La lecture des témoignages et des souvenirs permet de comprendre quand et comment s’est déroulé leur engagement. Car, contrairement aux idées reçues, elles n’étaient pas toutes dans les transmissions ou dans les services de santé. Elles n’étaient pas non plus « que » des AFAT (Auxiliaires féminines de l’Armée de Terre. Grâce à un panel d’autobiographies et de souvenirs de guerre, les points abordés ici seront donc ceux du contexte et des motivations de l’engagement, des postes occupés par ces femmes, ainsi que du regard que les libérateurs ont porté sur elles pendant mais surtout après la Libération.This article uses women’s writings to examine women’s voluntary enlistment in the French Army during World War II. As early as 1940, several hundred women joined the Free French Army’s ranks in London, but also in North Africa (Algeria, Morocco, Tunisia. They enlisted in the three army corps and were present in most services. These women carried out essential jobs between 1940 and 1945, although men often denigrated and underestimated their contributions. This moral, physical, and often

  6. Synthesis, characterization, and reactivity of Fe complexes containing cyclic diazadiphosphine ligands: the role of the pendant base in heterolytic cleavage of H2.

    Liu, Tianbiao; Chen, Shentan; O'Hagan, Molly J; Rakowski DuBois, Mary; Bullock, R Morris; DuBois, Daniel L

    2012-04-11

    The iron complexes CpFe(P(Ph)(2)N(Bn)(2))Cl (1-Cl), CpFe(P(Ph)(2)N(Ph)(2))Cl (2-Cl), and CpFe(P(Ph)(2)C(5))Cl (3-Cl)(where P(Ph)(2)N(Bn)(2) is 1,5-dibenzyl-1,5-diaza-3,7-diphenyl-3,7-diphosphacyclooctane, P(Ph)(2)N(Ph)(2) is 1,3,5,7-tetraphenyl-1,5-diaza-3,7-diphosphacyclooctane, and P(Ph)(2)C(5) is 1,4-diphenyl-1,4-diphosphacycloheptane) have been synthesized and characterized by NMR spectroscopy, electrochemical studies, and X-ray diffraction. These chloride derivatives are readily converted to the corresponding hydride complexes [CpFe(P(Ph)(2)N(Bn)(2))H (1-H), CpFe(P(Ph)(2)N(Ph)(2))H (2-H), CpFe(P(Ph)(2)C(5))H (3-H)] and H(2) complexes [CpFe(P(Ph)(2)N(Bn)(2))(H(2))]BAr(F)(4), [1-H(2)]BAr(F)(4), (where BAr(F)(4) is B[(3,5-(CF(3))(2)C(6)H(3))(4)](-)), [CpFe(P(Ph)(2)N(Ph)(2))(H(2))]BAr(F)(4), [2-H(2)]BAr(F)(4), and [CpFe(P(Ph)(2)C(5))(H(2))]BAr(F)(4), [3-H(2)]BAr(F)(4), as well as [CpFe(P(Ph)(2)N(Bn)(2))(CO)]BAr(F)(4), [1-CO]Cl. Structural studies are reported for [1-H(2)]BAr(F)(4), 1-H, 2-H, and [1-CO]Cl. The conformations adopted by the chelate rings of the P(Ph)(2)N(Bn)(2) ligand in the different complexes are determined by attractive or repulsive interactions between the sixth ligand of these pseudo-octahedral complexes and the pendant N atom of the ring adjacent to the sixth ligand. An example of an attractive interaction is the observation that the distance between the N atom of the pendant amine and the C atom of the coordinated CO ligand for [1-CO]BAr(F)(4) is 2.848 Å, considerably shorter than the sum of the van der Waals radii of N and C atoms. Studies of H/D exchange by the complexes [1-H(2)](+), [2-H(2)](+), and [3-H(2)](+) carried out using H(2) and D(2) indicate that the relatively rapid H/D exchange observed for [1-H(2)](+) and [2-H(2)](+) compared to [3-H(2)](+) is consistent with intramolecular heterolytic cleavage of H(2) mediated by the pendant amine. Computational studies indicate a low barrier for heterolytic cleavage of H(2). These

  7. An Elastica Arm Scale

    Bosi, F; Corso, F Dal; Bigoni, D

    2015-01-01

    The concept of 'deformable arm scale' (completely different from a traditional rigid arm balance) is theoretically introduced and experimentally validated. The idea is not intuitive, but is the result of nonlinear equilibrium kinematics of rods inducing configurational forces, so that deflection of the arms becomes necessary for the equilibrium, which would be impossible for a rigid system. In particular, the rigid arms of usual scales are replaced by a flexible elastic lamina, free of sliding in a frictionless and inclined sliding sleeve, which can reach a unique equilibrium configuration when two vertical dead loads are applied. Prototypes realized to demonstrate the feasibility of the system show a high accuracy in the measure of load within a certain range of use. It is finally shown that the presented results are strongly related to snaking of confined beams, with implications on locomotion of serpents, plumbing, and smart oil drilling.

  8. Arm CT scan

    ... scanners can perform the exam without stopping.) A computer creates separate images of the arm area, called ... M. is also a founding member of Hi-Ethics and subscribes to the principles of the Health ...

  9. Dynamics of sessile and pendant drop excited by surface acoustic waves: gravity effects and correlation between oscillatory and translational motions

    Bussonière, Adrien; Brunet, Philippe; Matar, Olivier Bou

    2016-01-01

    When sessile droplets are excited by ultrasonic traveling surface acoustic waves (SAWs), they undergo complex dynamics with both oscillations and translational motion. While the nature of the Rayleigh-Lamb quadrupolar drop oscillations has been identified, their origin and their influence on the drop mobility remains unexplained. Indeed the physics behind this peculiar dynamics is complex with nonlinearities involved both at the excitation level (acoustic streaming and radiation pressure) and in the droplet response (nonlinear oscillations and contact line dynamics). In this paper, we investigate the dynamics of sessile and pendant drops excited by SAWs. For pendant drops, so-far unreported dynamics are observed close to the drop detachment threshold with the suppression of the translational motion. Away from this threshold, the comparison between pendant and sessile drop dynamics allows us to identify the role played by gravity or more generally by an initial or dynamically induced stretching of the drop. In...

  10. "Bicontinuous cubic" liquid crystalline materials from discotic molecules: a special effect of paraffinic side chains with ionic liquid pendants.

    Alam, Md Akhtarul; Motoyanagi, Jin; Yamamoto, Yohei; Fukushima, Takanori; Kim, Jungeun; Kato, Kenichi; Takata, Masaki; Saeki, Akinori; Seki, Shu; Tagawa, Seiichi; Aida, Takuzo

    2009-12-16

    Triphenylene (TP) derivatives bearing appropriate paraffinic side chains with imidazolium ion-based ionic liquid (IL) pendants were unveiled to display a phase diagram with liquid crystalline (LC) mesophases of bicontinuous cubic (Cub(bi)) and hexagonal columnar (Col(h)) geometries. While their phase transition behaviors are highly dependent on the length of the side chains and the size of the ionic liquid pendants, TPs with hexadecyl side chains exclusively form a Cub(bi) LC assembly over an extremely wide temperature range of approximately 200 degrees C from room temperature when the anions of the IL pendants are relatively small. Wide-angle X-ray diffraction analysis suggested that the Cub(bi) LC mesophase contains pi-stacked columnar TP arrays with a plane-to-plane separation of approximately 3.5 A. Consistently, upon laser flash photolysis, it showed a transient microwave conductivity comparable to that of a Col(h) LC reference.

  11. Worldwide Report, Arms Control

    2007-11-02

    world war, a nuclear inferno , for over 40 years. A sober assessment of the situation in world politics was conducted at the meet- ing of the...there is success in stopping the arms race, or those forces accelerating the arms race and driving humanity to the edge of a nuclear inferno will gain...dialogue with all forces fighting against a nuclear inferno , affirmed by the Warsaw Pact countries, is being seen more and more as the only practicable

  12. Hello to Arms

    2005-01-01

    This image highlights the hidden spiral arms (blue) that were discovered around the nearby galaxy NGC 4625 by the ultraviolet eyes of NASA's Galaxy Evolution Explorer. The image is composed of ultraviolet and visible-light data, from the Galaxy Evolution Explorer and the California Institute of Technology's Digitized Sky Survey, respectively. Near-ultraviolet light is colored green; far-ultraviolet light is colored blue; and optical light is colored red. As the image demonstrates, the lengthy spiral arms are nearly invisible when viewed in optical light while bright in ultraviolet. This is because they are bustling with hot, newborn stars that radiate primarily ultraviolet light. The youthful arms are also very long, stretching out to a distance four times the size of the galaxy's core. They are part of the largest ultraviolet galactic disk discovered so far. Located 31 million light-years away in the constellation Canes Venatici, NGC 4625 is the closest galaxy ever seen with such a young halo of arms. It is slightly smaller than our Milky Way, both in size and mass. However, the fact that this galaxy's disk is forming stars very actively suggests that it might evolve into a more massive and mature galaxy resembling our own. The armless companion galaxy seen below NGC 4625 is called NGC 4618. Astronomers do not know why it lacks arms but speculate that it may have triggered the development of arms in NGC 4625.

  13. Arm To Arm Interface Using Embedded C

    Mohanraj.C

    2013-02-01

    Full Text Available Embedded systems are the most emerging field in these recent years. In this paper a different number of ARM processors (LPC2148 and LPC2378 are interconnected using C for distributed services. N numbers of processors are connected as the network and each processing devices are interlinked with each other, so that the each data that is processed by the devices and it can be used by the other device to activate their entire process. All the processed data’s are communicated to other device through Xbee interface card. LPC2148 and LPC2378 ARM processors are used in this prototype and winXtalk is used as a software terminal window. In this paper, the ultimate benefits of multiple processor interactions related to the embedded applications and design issues of processor interconnection are discussed. The features of multiple processor interaction in inter process communication and executions of embedded multitasking are also discussed. In modern embedded computing platform, embedded processor used in various applications like home automation, industrial control, medical system, access control, etc. In this paper, using embedded processor interactions, the several data communication is established.

  14. Development of electrochemical sensors for nano scale Tb(III) ion determination based on pendant macrocyclic ligands.

    Singh, Ashok K; Singh, Prerna; Banerjee, Shibdas; Mehtab, Sameena

    2009-02-02

    The two macrocyclic pendant ligands 3,4,5:12,13,14-dipyridine-2,6,11,15-tetramethyl-1,7,10,16-tetramethylacrylate-1,4,7,10,13,16-hexaazacyclooctadeca-3,13-di ene (L(1)) and 3,4,5:12,13,14-dipyridine-2,6,11,15-tetramethyl-1,7,10,16-tetra(2-cyano ethane)-1,4,7,10,13,16-hexaazacyclooctadeca-3,13-diene (L(2)) have been synthesized and explored as neutral ionophores for preparing poly(vinylchloride) (PVC) based membrane sensors selective to Tb(III) ions. Effects of various plasticizers and anion excluders were studied in detail and improved performance was observed. The best performance was obtained for the membrane sensor having a composition of L(1): PVC:1-CN:NaTPB in the ratio of 6: 32: 58: 4 (w/w; mg). The performance of the membrane based on L(1) was compared with polymeric membrane electrode (PME) as well as with coated graphite electrode (CGE). The electrodes exhibit Nernstian slope for Tb(3+) ions with limits of detection of 3.4 x 10(-8)mol L(-1) for PME and 5.7 x 10(-9)mol L(-1) for CGE. The response time for PME and CGE was found to be 10s and 8s, respectively. The potentiometric responses are independent of the pH of the test solution in the pH range 3.0-7.5 for PME and 2.0-8.5 for CGE. The CGE has found to work satisfactorily in partially non-aqueous media upto 30% (v/v) content of methanol, ethanol and 20% (v/v) content of acetonitrile and could be used for a period of 5 months. The CGE was used as indicator electrode in the potentiometric titration of Tb(3+) ions with EDTA and in determination of fluoride ions in various samples. It can also be used in direct determination of Tb(3+) ions in tap water and various binary mixtures with quantitative results.

  15. Jérusalem et la Palestine pendant la première guerre mondiale

    Dominique Trimbur

    2008-05-01

    Full Text Available La journée d’études « Jérusalem et la Palestine pendant la première guerre mondiale » s’inscrit dans le cadre du programme « La France, l’Europe occidentale et la Palestine, 1799-1948 » du Centre de recherche français de Jérusalem. À la suite du colloque portant sur un long XIXe siècle, de 1799 à 1917 (9-11 novembre 1998, et avant la rencontre des 29-30 novembre-1er décembre 1999, portant sur la période mandataire (1917-1948, il paraissait indispensable de s’attarder sur le premier conflit ...

  16. Le travail indépendant des immigrés et sa sociologie

    Riesco Sanz, Alberto

    2012-01-01

    Dans les années 1970-1980, les premières formulations de ce que l’on a appelé la sociologie de l’entreprenariat ethnique (économies ethniques, minorités intermédiaires, économies d’enclave ethnique)1 ont mis en relief les virtualités « émancipatrices » (ou du moins, socialement bénéfiques) de l’entreprenariat et des modes d’emploi basés sur le travail indépendant. Elles ont insisté aussi sur le fait que l’entreprenariat n’était pas distribué de façon homogène au sein de la population. En e...

  17. Nickel Phosphine Catalysts with Pendant Amines for Electrocatalytic Oxidation of Alcohols

    Weiss, Charles J.; Wiedner, Eric S.; Roberts, John A.; Appel, Aaron M.

    2015-01-01

    Nickel phosphine complexes with pendant amines have been found to be electrocatalysts for the oxidation of primary and secondary alcohols, with turnover frequencies as high as 3.3 s-1. These complexes are the first electrocatalysts for alcohol oxidation based on non-precious metals, which will be critical for use in fuel cells. The research by CJW, ESW, and AMA was supported by the US Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences & Biosciences. The research by JASR was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science. Pacific Northwest National Laboratory is operated by Battelle for the US Department of Energy.

  18. MODIFICATION OF EPOXY RESIN WITH POLYSILOXANE BEARING PENDANT QUATERNARY AMMONIUM GROUPS

    Zuo-xin Huang; Ying Huang; Yun-zhao Yu

    2002-01-01

    Polysiloxane bearing pendant quatemary ammonium groups (PSI) was used to modify the surface properties ofepoxy resins. In the cured resin, PSI formed the dispersed phase. Remarkable enrichment and gradient distribution ofpolysiloxane on the surface region of the epoxy resins were demonstrated by XPS analysis. The composition and propertiesof the surface of PSI-modified epoxy resin, which is in contact with the mold, are dependent on the material of the mold.Through the incorporation of PSI, epoxy resins with low surface energy and low friction coefficient were obtained.Polysiloxane with lower ionic group content shows a higher degree of enrichment on the resin surface and leads to a highercontact angle against water, while the polysiloxane having optimum compatibility with the epoxy resin shows a greater effectin reducing the static friction coefficient of the resin against glass.

  19. Proton and Electron Additions to Iron (II) Dinitrogen Complexes Containing Pendant Amines

    Heiden, Zachariah M.; Chen, Shentan; Labios, Liezel AN; Bullock, R. Morris; Walter, Eric D.; Tyson, Elizabeth L.; Mock, Michael T.

    2014-03-10

    We describe a single site cis-(H)FeII-N2 complex, generated by the protonation of an iron-carbon bond of a "reduced" iron complex, that models key aspects of proposed protonated intermediates of the E4 state of nitrogenase. The influence on N2 binding from the addition of protons to the pendant amine sites in the second coordination sphere is described. Furthermore, the addition of electrons to the protonated complexes results in H2 loss. The mechanism of H2 loss is explored to draw a parallel to the origin of H2 loss (homolytic or heterolytic) and the nature of N2 coordination in intermediates of the E4 state of nitrogenase.

  20. Cooperative assembly of Zn cross-linked artificial tripeptides with pendant hydroxyquinoline ligands.

    Zhang, Meng; Gallagher, Joy A; Coppock, Matthew B; Pantzar, Lisa M; Williams, Mary Elizabeth

    2012-11-01

    An artificial peptide with three pendant hydroxyquinoline (hq) ligands on a palindromic backbone was designed and used to form multimetallic assemblies. Reaction of the tripeptide with zinc acetate led to a highly fluorescent tripeptide duplex with three Zn(II) coordinative cross-links. The binding process was monitored using spectrophotometric absorbance and emission titrations; NMR spectroscopy and mass spectrometry confirmed the identity and stoichiometry of the product structure. Titrations monitoring duplex formation of the zinc-tripeptide structure had a sigmoidal shape, equilibrium constant larger than the monomeric analogue, and a Hill coefficient >1, all of which indicate positive cooperativity. Photophysical characterization of the quantum yield, excited state lifetime, and polarization anisotropy are compared with the monometallic zinc-hq analogue. A higher than expected quantum yield for the trimetallic complex suggests a structure in which the central chromophore is shielded from solvent by π-stacking with neighboring Zn(II) complexes.

  1. Method for estimating interfacial tensions and contact angles from sessile and pendant drop shapes

    Huh, C.; Reed, R.L.

    1983-02-01

    Optimal estimation techniques were developed for measurement of interfacial tensions and contact angles for multiphase microemulsion systems of the following types: (1) lower-phase microemulsion in equilibrium with excess oil, (2) upper-phase microemulsion in equilbrium with excess brine, and (3) middle-phase microemulsion in equilibrium with excess brine and excess oil. The surfactant was the monoethanol amine salt of dodecyl o-xylene sulfonate mixed with a cosolvent of t-amyl alcohol in the ratio 63/67 by vol. The oil was a mixture of 90% paraffinic oil (Isopar M) and 10% heavy aromatic naphtha (by volume), and the brine was various concentrations of NaCl in distilled water. The method is applied to sessile drops, bubbles, and pendant configurations. 21 referernces.

  2. The influence of pendant carboxylic acid loading on surfaces of statistical poly(4-hydroxystyrene)-co-styrene)s

    Daugaard, Anders Egede; Hvilsted, Søren

    2008-01-01

    synthesis with propargyl bromide and the copolymers were functionalized with pendant aliphatic or aromatic carboxylic acids by click chemistry. Differential scanning calorimetry of the copolymers demonstrates the large influence on Tg ofthe different functional groups and the backbone composition...... of acid groups on the surface....

  3. Green syntheses, v.1

    Tundo, Pietro

    2014-01-01

    Introduction to the Green Syntheses SeriesPietro Tundo and John AndraosApplication of Material Efficiency Metrics to Assess Reaction Greenness-Illustrative Case Studies from Organic SynthesesJohn AndraosReaction 1: Synthesis of 3-Benzyl-5-Methyleneoxazolidin-2-one from N-Benzylprop-2-yn-1-Amine and CO2Qing-Wen Song and Liang-Nian HeReaction 2: Synthesis of the 5-Membered Cyclic Carbonates from Epoxides and CO2Qing-Wen Song, Liang-Nian HePart I: Green Methods for the Epoxidation of

  4. The Role of Pendant Amines in the Breaking and Forming of Molecular Hydrogen Catalyzed by Nickel Complexes

    Raugei, Simone; Chen, Shentan; Ho, Ming-Hsun; Ginovska-Pangovska, Bojana; Rousseau, Roger J.; Dupuis, Michel; DuBois, Daniel L.; Bullock, R. Morris

    2012-05-15

    We present the results of a comprehensive theoretical investigation of the role of pendant amine ligands in the oxidation of H2 and formation of H2 by [Ni(P2RN2R’)2]2+ electrocatalysts (where P2RN2R’ is the 1,5-R’-3,7-R derivative of 1,5-diaza-3,7-diphosphacyclooctane with R and R’ are aryl or alkyl groups). We focus our analysis on the thermolchemical part of the catalytic cycle, as it is known to be rate determining for both H2 oxidation and production. We find that the presence of pendant amine functional groups greatly facilitates the heterolytic H2 bond cleavage resulting in a protonated amine functional group and a Ni hydride. Only one single well-positioned pendant amine is required to serve this function. The pendant amine can also effectively shuttle protons to the active site making the redistribution of protons and the H2 evolution a very facile processes. An important requirement for the overall catalytic process is the positioning of at least one amine in close proximity to the metal center. Indeed, only protonation of the pendant amines on the metal center side (endo position) leads to catalytically active intermediates, whereas protonation on the opposite side of the metal center (exo position) leads to a variety of isomers, which are detrimental to catalysis. This material is based upon work supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Office of Basic Energy Sciences under FWP56073.

  5. SYNTHESIS AND CHARACTERIZATION OF BLUE LIGHT-EMITTING POLY(ARYL ETHER)S CONTAINING PYRIMIDINE-INCORPORATED OLIGOFLUORENE PENDANTS WITH BIPOLAR FEATURE

    Guo-xin Jiang; Chun-lei Bian; Jun-qiao Ding; Li-xiang Wang

    2013-01-01

    Novel blue light-emitting poly(aryl ether)s comprising of bipolar oligofluorene pendants as chromophores have been designed and synthesized,in which pyrimidine and arylamine moieties are utilized as the electron acceptor and electron donor,respectively.Through varying π bridge length from monofluorene to bifluorene and end-cappers from hydrogen to carbazole and diphenylamine,the emission color of the resulting polymers covers from deep blue to greenish blue,and their HOMO and LUMO levels can be modulated to facilitate charge injection to improve the device performance.Polymer lightemitting diodes (PLEDs) are fabricated with the device structure of ITO/poly(3,4-ethylenedioxythiophene):poly(styrene sulfonic acid) (PEDOT:PSS) (50 nm)/polymer (80 nm)/Ca (10 nm)/A1 (200 nm).Among these polymers,P2Cz5F-Py with bifluorene bridge and carbazole end-capper shows excellent trade-off between the efficiency and emission wavelength,having a peak luminous efficiency as high as 1.26 cd/A and Commission Internationale de L'Eclairage (CIE) coordinates of (0.17,0.17).

  6. JPRS Report, Arms Control

    2007-11-02

    34military activities, whether in the armed forces, their civilian sectors, or in the ’defence’ indus- try". In another paper Professor Carl Sagan ...spurring the development of new weapons. Star Wars is a case in point. As Carl Sagan puts it, the idea is doomed: "SDI is ruinously expensive, it can

  7. Worldwide Report, Arms Control.

    1985-08-12

    thai, in the long run one cannot oven tell to willy frandi’and fgon fahr . ’r’ho Soviets arc thus evoking the suspicion that they are playing dirty...material resources and the knowledge of scientists in combatting diseases , if the resources were spent on it that are taken up by the arms race

  8. JPRS Report, Arms Control.

    2007-11-02

    Joint-Stock Company"] [Text] A constituent conference of the "Ural- Kosmos " closed joint-stock company [aktsionernoye obshchestvo zakrytogo tipa] has...due to be destroyed under arms cuts. Their warheads will be replaced by communications satellites. The founders of the "Ural- Kosmos " company note

  9. Worldwide Report, Arms Control

    2007-11-02

    Soviet Laser Expert (N. G. Bazov Interview; CAMBIO 16, 11-18 Feb 85) 86 Unnamed General Urges French ’Star Wars’ Effort (Hoplites; LE MONDE, 6...1024 85 JPRS-TAC-85-002 1 April 1985 SPACE ARMS SPANISH MAGAZINE CITES SOVIET LASER EXPERT PM211619 [Editorial Report] Madrid CAMBIO 16 in Spanish

  10. Worldwide Report, Arms Control

    1985-12-31

    Bonn RHEINISCHER MERKUR /CHRIST UND WELT, 12 Oct 85) . 14 GDR Commentary on Geneva Talks (Various sources,various dates) 19 Military...USSR GENEVA TALKS FRG DEFENSE UNDERSECRETARY SUPPORTS U.S. VIEW ON ARMS CONTROL Bonn RHEINISCHER MERKUR /CHRIST UND WELT in German 12 Oct 85 p 3

  11. Worldwide Report, Arms Control

    2007-11-02

    like tired runners exposed to the sights of millions of viewers. The fear of oxygen starvation was handled by the U.S. President on several levels...and to present the U.S. attitudes as the only way out of the maze of the arms race. It is an attempt to push through the old principles of U.S

  12. Synthesized night vision goggle

    Zhou, Haixian

    2000-06-01

    A Synthesized Night Vision Goggle that will be described int his paper is a new type of night vision goggle with multiple functions. It consists of three parts: main observing system, picture--superimposed system (or Cathode Ray Tube system) and Charge-Coupled Device system.

  13. Star Formation in Spiral Arms

    Elmegreen, Bruce G

    2011-01-01

    The origin and types of spiral arms are reviewed with an emphasis on the connections between these arms and star formation. Flocculent spiral arms are most likely the result of transient instabilities in the gas that promote dense cloud formation, star formation, and generate turbulence. Long irregular spiral arms are usually initiated by gravitational instabilities in the stars, with the gas contributing to and following these instabilities, and star formation in the gas. Global spiral arms triggered by global perturbations, such as a galaxy interaction, can be wavemodes with wave reflection in the inner regions. They might grow and dominate the disk for several rotations before degenerating into higher-order modes by non-linear effects. Interstellar gas flows through these global arms, and through the more transient stellar spiral arms as well, where it can reach a high density and low shear, thereby promoting self-gravitational instabilities. The result is the formation of giant spiral arm cloud complexes,...

  14. Modernization of African Armed Forces

    Mandrup, Thomas

    2015-01-01

    Concept paper framing the debate at the Dakar Forum Workshop on Modernization of Armed forces in Africa.......Concept paper framing the debate at the Dakar Forum Workshop on Modernization of Armed forces in Africa....

  15. ARM User Survey Report

    Roeder, LR

    2010-06-22

    The objective of this survey was to obtain user feedback to, among other things, determine how to organize the exponentially growing data within the Atmospheric Radiation Measurement (ARM) Climate Research Facility, and identify users’ preferred data analysis system. The survey findings appear to have met this objective, having received approximately 300 responses that give insight into the type of work users perform, usage of the data, percentage of data analysis users might perform on an ARM-hosted computing resource, downloading volume level where users begin having reservations, opinion about usage if given more powerful computing resources (including ability to manipulate data), types of tools that would be most beneficial to them, preferred programming language and data analysis system, level of importance for certain types of capabilities, and finally, level of interest in participating in a code-sharing community.

  16. Thermochemical and Mechanistic Studies of Electrocatalytic Hydrogen Production by Cobalt Complexes Containing Pendant Amines

    Wiedner, Eric S.; Appel, Aaron M.; DuBois, Daniel L.; Bullock, R. Morris

    2013-12-16

    Two cobalt(tetraphosphine) complexes [Co(PnC-PPh22NPh2)(CH3CN)](BF4)2 with a tetradentate phosphine ligand (PnC-PPh22NPh2 = 1,5-diphenyl-3,7-bis((diphenylphosphino)alkyl)-1,5-diaza-3,7-diphosphacyclooctane; alkyl = (CH2)2, n = 2 (L2); (CH2)3, n = 3 (L3)) have been studied for electrocatalytic hydrogen production using 1:1 [(DMF)H]+:DMF. A turnover frequency of 980 s–1 with an overpotential of 1210 mV was measured for [CoII(L2)(CH3CN)]2+, and a turnover frequency of 980 s–1 with an overpotential of 930 mV was measured for [CoII(L3)(CH3CN)]2+. Addition of water increases the turnover frequency of [CoII(L2)(CH3CN)]2+ to 19,000 s–1. The catalytic wave for each of these complexes occurs at the reduction potential of the corresponding HCoIII complex. Comprehensive thermochemical studies of [CoII(L2)(CH3CN)]2+ and [CoII(L3)(CH3CN)]2+ and species derived from them by addition/removal of protons/electrons were carried out using values measured experimentally and calculated using DFT. Notably, HCoI(L2) and HCoI(L2) were found to be remarkably strong hydride donors, with HCoI(L2) being a better hydride donor than BH4-. Mechanistic studies of these catalysts reveal that H2 formation can occur by protonation of a HCoII intermediate, and that the pendant amines of these complexes facilitate proton delivery to the cobalt center. The rate-limiting step for catalysis is a net intramolecular isomerization of the protonated pendant amine from the non-productive exo-isomer to the productive endo isomer. We thank Dr. Shentan Chen for many helpful discussions. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Computational resources were provided at the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for the

  17. Kiikuv maja / Anu Arm

    Arm, Anu

    2006-01-01

    Eesti Kunstiakadeemia esimese kursuse arhitektuuriüliõpilaste II semestri töö. Juhendaja arhitekt Andres Alver, ehitamise Pedaspeale organiseeris suvepraktika juhendaja arhitekt Jaan Tiidemann. Autor Anu Arm, kaasa töötasid ja valmis ehitasid: Ott Alver, Maarja Elm, Mari Hunt, Alvin Järving, Marten Kaevats, Riho Kerge, Reedik Poopuu, Anu Põime, Helen Rebane, Kaisa Saarva, Martin Tago, Reet Volt. Valmis: 19. VIII 2006

  18. JPRS Report, Arms Control

    2007-11-02

    SINMUN in Korean 19 Jan 90 p 2 [ Editorial : "Arms Reduction Amid East-West Reconcil- iation"] [Text] It appears that with the end of cold-war, the...Navigation Radar Deployment PY1701143090 La Paz La Red Panamericana in Spanish 1130 GMT 17 Jan 90 [Text] Aeronautics Minister Luis Gonzales...airspace and that it can guarantee our sovereignty. Aeronautics Military Under Secretary Installed PY1701125290 La Paz La Red Panamericana in

  19. Worldwide Report, Arms Control.

    2007-11-02

    Soviet violations, the Pentagon and the White House ended up in mush . Nevertheless, armed with mush as evidence, the American secretary of...YORK TIMES calling anti-Soviet charges mush is out- numbered by thousands of statements on radio and television, speeches before various...audiences, and articles in newspapers and magazines where that same mush is used as a serious argument. USSR Complying Treaties LD120557 Moscow

  20. Worldwide Report, Arms Control

    2007-11-02

    Service, Springfield, Virginia 22161. In order- ing, it is recommended that the JPRS number, title, date and author, if applicable, of publication be...Road, Arlington, Virginia 22201. JPRS-TAC-86-025 14 March 1986 WORLDWIDE REPORT ARMS CONTROL CONTENTS U.S.-USSR GENEVA TALKS, USSR: Possibility for...34Vreyma" newscast] [Excerpts] A Moscow premiere. Our correspondent reports: The audience is hurrying to a premiere at the Moscow Satire Theater. What

  1. Development of Amylose- and β-Cyclodextrin-Based Chiral Fluorescent Sensors Bearing Terthienyl Pendants

    Tomoyuki Ikai

    2016-11-01

    Full Text Available Phenylcarbamate derivatives of amylose and β-cyclodextrin show excellent chiral recognition when used as chiral stationary phases (CSPs for high-performance liquid chromatography. To open up new possibilities of carbohydrate-based materials, we developed chiral fluorescent sensors based on amylose and β-cyclodextrin (Am-1b and CyD-1b, respectively by attaching fluorescent π-conjugated units on their side chains. Their recognition abilities toward chiral analytes containing a nitrophenyl unit were evaluated by measuring the enantioselective fluorescence quenching behavior. Both sensors showed the same degree of enantioselective fluorescence response for various aromatic nitro compounds. However, in some cases, their enantioselectivities were different depending on the analytes. The difference in the chiral recognition abilities between Am-1b and CyD-1b seems to be based on the structural difference of their inherent backbones, that is, the one-handed helical structure and cyclic structure, respectively. The study on the resolution ability of the Am-1b-based CSP revealed that the terthienyl-based pendant of Am-1b provides not only a fluorescent functionality but also a different chiral recognition site from that of amylose tris(phenylcarbamate.

  2. Dynamics of sessile and pendant drops excited by surface acoustic waves: Gravity effects and correlation between oscillatory and translational motions

    Bussonnière, A.; Baudoin, M.; Brunet, P.; Matar, O. Bou

    2016-05-01

    When sessile droplets are excited by ultrasonic traveling surface acoustic waves (SAWs), they undergo complex dynamics with both oscillations and translational motion. While the nature of the Rayleigh-Lamb quadrupolar drop oscillations has been identified, their origin and their influence on the drop mobility remains unexplained. Indeed, the physics behind this peculiar dynamics is complex with nonlinearities involved both at the excitation level (acoustic streaming and radiation pressure) and in the droplet response (nonlinear oscillations and contact line dynamics). In this paper, we investigate the dynamics of sessile and pendant drops excited by SAWs. For pendant drops, so-far unreported dynamics are observed close to the drop detachment threshold with the suppression of the translational motion. Away from this threshold, the comparison between pendant and sessile drop dynamics allows us to identify the role played by gravity or, more generally, by an initial or dynamically induced stretching of the drop. In turn, we elucidate the origin of the resonance frequency shift, as well as the origin of the strong correlation between oscillatory and translational motion. We show that for sessile drops, the velocity is mainly determined by the amplitude of oscillation and that the saturation observed is due to the nonlinear dependence of the drop response frequency on the dynamically induced stretching.

  3. AES i ARM procesori

    Danijela D. Protić

    2013-12-01

    Full Text Available Potreba za zaštitom informacija dovodi do velikih problema u izradi prenosivih uređaja kojima su limitirani snaga, memorija i energija. Ukoliko se takvim uređajima dodaju koprocesori, koji treba da obavljaju funkcije kriptozaštite, njihove se dimenzije povećavaju, pojavljuje se nefleksibilnost pa cena uređaja raste i do nekoliko puta. Na drugoj strani, algoritmi za zaštitu podataka su često memorijski zahtevni, a zbog velikog broja operacija koje je potrebno izvršavati u procesima šifrovanja i dešifrovanja, koprocesori često uspore rad osnovnog procesora. Za jedan od standarda za kriptozaštitu, AES, NIST je prihvatio Rijndaelov blokovski algoritam sa dužinom ulaznog i izlaznog bloka od 128 b, i dužinama šifarskog ključa od 128 b, 192 b i 256 b. Zbog karakteristika male potrošnje, 32-bitske arhitekture i brzog izvršavanja instrukcija, ARM procesori mogu da realizuju kriptozaštitu podataka, između ostalog i AES-om, a da ne opterete glavne procese u sistemima u kojima se koriste. Tehnologija ARM-a zaštićena je kao intelektualna svojina, pa je veliki broj proizvođača koristi za razvoj sopstvenih proizvoda, što je rezultovalo činjenicom da je u svetu proizvedeno preko 2 milijarde čipova koji su bazirani na ovoj tehnologiji. U radu su prikazane mogućnosti za poboljšanja u izvršenju algoritma AES primenom najnovijih verzija ARM procesora.

  4. Worldwide Report, Arms Control

    2007-11-02

    put their feet on the table.... But that Is not the USSR’s problem. It is not for the USSR to teach the rules of etiquette vh~nh are broken in the...34 /12858 CSO: 5200/2634 • 138 - RELATED ISSUES LABOR PARTY DISTRICT CONGRESS: BAN NUCLEAR ARMED SHIPS Oslo AFTENPOSTEN in Norwegian 27 Jan 86 p 3 [Article...that countries which send warships into Norwegian ports should guarantee that these ships are not carry- ing nuclear weapons. The requirement would

  5. Synthesis and Characterization of Novel Aliphatic Polycarbonates Bearing Pendant Allyl Ether Groups

    Gang LIU; Feng HE; Yan Ping WANG; Jun FENG; Ren Xi ZHUO

    2006-01-01

    A new six-membered cyclic carbonate monomer, 5-allyloxytrimethylene carbonate (ATMC), was synthesized starting from glycerol, and the corresponding polycarbonates,poly(5-allyloxytrimethylene carbonate)(PATMC) were further synthesized by ring-opening polymerization in bulk at 150 ℃ using stannous octanoate as an initiator. The structures of the monomer and the polymers were confirmed by IR, 1H-NMR, 13C-NMR, and GPC analysis.

  6. Synthesis and Characterization of Well-Defined Regular Star Polyisoprenes with 3, 4, 6 and 8 Arms

    Ratkanthwar, Kedar R.

    2013-01-01

    Three series of regular well-defined star polyisoprenes (PIs) with 3, 4 and 6 arms (each series: same arm molecular weight) have been synthesized by anionic polymerization high vacuum techniques and chlorosilane chemistry. In addition, three linear PIs with practically the double arm molecular weight of the corresponding series (2-arm star PIs) have been synthesized, as well as one 8-arm star PI. All intermediate (arms) and final (stars) products have been characterized by size exclusion chromatography (SEC), SEC-multi-angle laser light scattering (SEC-MALLS) and nuclear magnetic resonance (NMR) spectroscopy. The Tg of the star PIs was determined by differential scanning calorimetry. These model polymeric materials are essential for polymer physics and polymer physical chemistry in order to establish the structure/property relationships.

  7. Dinuclear manganese(II) complexes of hexaazamacrocycles bearing N-benzoylated pendant separated by aromatic spacers: Antibacterial, DNA interaction, cytotoxic and molecular docking studies.

    Arthi, P; Shobana, S; Srinivasan, P; Prabhu, D; Arulvasu, C; Kalilur Rahiman, A

    2015-12-01

    Three new homodinuclear manganese(II) complexes of the type [Mn2L(1-3)(ClO4)(H2O)](ClO4)3 (1-3) have been synthesized via cyclocondensation of terephthalaldehyde with three different benzoylated pendants in the presence of manganese(II) perchlorate and characterized by spectroscopic methods. Cyclic voltammetric investigation of complexes (1-3) depict two quasi-reversible one electron reduction processes in the cathodic potential region (E(1)pc=-0.73 to-0.83 V, E(2)pc=-1.31 to -1.40 V) and two quasi-reversible one electron oxidation processes in the anodic potential region (E(1)pa=1.03 to 1.10 V, E(2)pa=1.69 to 1.77 V). Electronic absorption spectra of the complexes suggested tetrahedral geometry around the central metal ion. The observed low magnetic moment values (μeff, 5.60-5.68 B.M.) of the complexes indicate the presence of an antiferromagnetic spin-exchange interaction between two metal centers, which was also supported by the broad EPR signal. All the compounds were tested for antibacterial activity against Gram (-ve) and Gram (+ve) bacterial strains. The binding studies of complexes with CT-DNA suggested minor-groove mode of interaction. Molecular docking studies were carried out in order to find the binding affinity of complexes with DNA and protein EGFR Kinase. The complexes are stabilized by additional electrostatic and van der Waals interaction with the DNA, and support minor groove mode of binding. The cleavage activity of complexes on pBR322 plasmid DNA displays efficient activity through a mechanistic pathway involving hydroxyl radicals. The cytotoxicity of complexes 2 and 3 have been tested against human liver adenocarcinoma (HepG2) cell line. Nuclear-chromatin cleavage has also been observed with propidium iodide (PI) staining and alkaline single-cell gel electrophoresis (comet assay) techniques.

  8. Investigation on Al(III) and Zn(II) complexes containing a calix[4]arene bearing two 8-oxyquinoline pendant arms used as emitting materials for OLEDs

    Bagatin, Izilda A. [Instituto de Quimica, Universidade de Sao Paulo, Cx. P.: 26077, CEP 05513-970, Sao Paulo, SP (Brazil)], E-mail: izildabagatin@yahoo.com.br; Legnani, Cristiano [Divisao de Metrologia em Materiais, Instituto Nacional de Metrologia, Normalizacao e Qualidade Industrial, CEP 25250-020, Duque de Caxias, RJ (Brazil); Cremona, Marco [Divisao de Metrologia em Materiais, Instituto Nacional de Metrologia, Normalizacao e Qualidade Industrial, CEP 25250-020, Duque de Caxias, RJ (Brazil); Pontificia Universidade Catolica do Rio de Janeiro, Depto de Fisica, C.P.38071, Rio de Janeiro (Brazil)

    2009-01-01

    A comparison between [Al{center_dot}1]{sup 3+} and [Zn{center_dot}1]{sup 2+} complexes (1 = 5,11,17,23-tetra-tert-butyl-25,27-bis[(quinoline-8-oxy)propyloxy]-26, 28-dihydroxy-calix[4]arene) has been made using electrochemical techniques and the experimental results obtained in the fabrication of organic light emitting devices (OLEDs). The electrochemically determined values of the ionization potential I{sub p} and electron affinity E{sub a} parameters for the [Al{center_dot}1]{sup 3+} (I{sub p} = 5.82eV, E{sub a} = 2.80eV) and [Zn{center_dot}1]{sup 2+} (I{sub p} = 5.67eV, E{sub a} = 2.32eV) evidenced that the [Al{center_dot}1]{sup 3+} complex is a better electron transporting layer with respect to the Zn complex one. The fabricated OLEDs based on these supramolecular complexes show a superior quality with the [Al{center_dot}1]{sup 3+} systems expected from the energy level diagrams.

  9. Structural and Spectral Studies on the Ni(Ⅱ) Complexes of 1,5-Diazacyclooctane (DACO) Bearing Heterocyclic Pendants: Formation of a Two-dimensional Network Via Hydrogen Bonds and π-π Stacking Interactions

    DU,Miao(杜淼); DU,Miao; XU,Qiang(徐强); XU,Qiang; GUO,Ya-Mei (郭亚梅); GUO,Ya-Mei; WENG,Lin-Hong(翁林红); WENG,Lin-Hong; BU,Xian-He (卜显和); BU,Xian-He

    2001-01-01

    A penta-coordinated Ni(II) complex with a 1,5-diazacyclooctane (DACO) ligand functionazed by two imidazole donor pendants, [NiiL1Cl] (ClO4)'HH2O (1) (where L1 = 1,5-bis (imidazol-4-ylmethyl)-1,S-diazacyclooctane) has been synthesized and characterized by X-ray diffraction, infrared spectra, elemental analyses, conductance, thermal analyses and UV-Vis techniques. Complex 1 crystallizes in triclinic crystal system, P-1 space group with a = 0.74782(7), b = 1.15082(10), c = 1.237s1(11) nm, a=82.090(2), β=73.011(2), γ=83.462(2)°, V= 1.00603(16) nn3, Mr = 486.00, Z=2,Dc=1.604 g/cm3, final R=0.0435, and wR=0.1244. The structures of 1 and its related complexes show that in all the three mononuclear complexes, each Ni(Ⅱ) center is penta-coordinated with a near regular square pyranid (RSP) to distorted square-pyramidal (DSP) coordination environment due to the boat/chair configuration of DACO ring in these complexes, and the degree of distortion increases with the augment of the size of the heterocyclic pendants. In addition, the most striking feature of complex 1 resides in the formation of a two-dimensional network structure through hydrogen bonds and stabilized by π-π stacking. The solution behaviors of the Ni(ⅡI) complexes are also discussed in detail.

  10. Doclet To Synthesize UML

    Barry, Matthew R.; Osborne, Richard N.

    2005-01-01

    The RoseDoclet computer program extends the capability of Java doclet software to automatically synthesize Unified Modeling Language (UML) content from Java language source code. [Doclets are Java-language programs that use the doclet application programming interface (API) to specify the content and format of the output of Javadoc. Javadoc is a program, originally designed to generate API documentation from Java source code, now also useful as an extensible engine for processing Java source code.] RoseDoclet takes advantage of Javadoc comments and tags already in the source code to produce a UML model of that code. RoseDoclet applies the doclet API to create a doclet passed to Javadoc. The Javadoc engine applies the doclet to the source code, emitting the output format specified by the doclet. RoseDoclet emits a Rose model file and populates it with fully documented packages, classes, methods, variables, and class diagrams identified in the source code. The way in which UML models are generated can be controlled by use of new Javadoc comment tags that RoseDoclet provides. The advantage of using RoseDoclet is that Javadoc documentation becomes leveraged for two purposes: documenting the as-built API and keeping the design documentation up to date.

  11. Robotic Arm Biobarrier Cable

    2008-01-01

    This image, taken by the Surface Stereo Imager on NASA's Phoenix Mars Lander on the 14th Martian day of the mission (June 7, 2008), shows the cable that held the Robotic Arm's biobarrier in place during flight has snapped. The cable's springs retracted to release the biobarrier right after landing. To the lower right of the image a spring is visible. Extending from that spring is a length of cable that snapped during the biobarrier's release. A second spring separated from the cable when it snapped and has been photographed on the ground under the lander near one of the legs. The Phoenix Mission is led by the University of Arizona, Tucson, on behalf of NASA. Project management of the mission is by NASA's Jet Propulsion Laboratory, Pasadena, Calif. Spacecraft development is by Lockheed Martin Space Systems, Denver.

  12. The Neanderthal lower arm.

    De Groote, Isabelle

    2011-10-01

    Neanderthal forearms have been described as being very powerful. Different individual features in the lower arm bones have been described to distinguish Neanderthals from modern humans. In this study, the overall morphology of the radius and ulna is considered, and morphological differences among Neanderthals, Upper Paleolithic Homo sapiens and recent H. sapiens are described. Comparisons among populations were made using a combination of 3D geometric morphometrics and standard multivariate methods. Comparative material included all available complete radii and ulnae from Neanderthals, early H. sapiens and archaeological and recent human populations, representing a wide geographical and lifestyle range. There are few differences among the populations when features are considered individually. Neanderthals and early H. sapiens fell within the range of modern human variation. When the suite of measurements and shapes were analyzed, differences and similarities became apparent. The Neanderthal radius is more laterally curved, has a more medially placed radial tuberosity, a longer radial neck, a more antero-posteriorly ovoid head and a well-developed proximal interosseous crest. The Neanderthal ulna has a more anterior facing trochlear notch, a lower M. brachialis insertion, larger relative mid-shaft size and a more medio-lateral and antero-posterior sinusoidal shaft. The Neanderthal lower arm morphology reflects a strong cold-adapted short forearm. The forearms of H. sapiens are less powerful in pronation and supination. Many differences between Neanderthals and H. sapiens can be explained as a secondary consequence of the hyper-polar body proportions of the Neanderthals, but also as retentions of the primitive condition of other hominoids.

  13. Synthesis of Ethylene or Propylene/1,3-Butadiene Copolymers Possessing Pendant Vinyl Groups with Virtually No Internal Olefins

    Kenji Michiue

    2015-11-01

    Full Text Available In general, ethylene/1,3-butadiene copolymerizations provides copolymers possessing both pendant vinyls and vinylenes as olefinic moieties. We, at MCI, studied the substituent effects of C2-symmetric zirconocene complexes, rac-[Me2Si(Indenyl’2]ZrCl2 (Indenyl’ = generic substituted indenyl, after activation on the ratio of the pendant vinyls and vinylenes of the resultant copolymers. Complexes examined in this study were rac-dimethylsilylbis (1-indenylzirconium dichloride (1, rac-dimethylsilyl-bis[1-(2-methyl-4,5-benzoindenyl] zirconium dichloride (2, rac-dimethylsilyl-bis[l-(2-methyl -4-phenylindenyl]zirconium dichloride (3, rac-dimethy1si1y1- bis(2-ethyl-4-phenylindenyl zirconium dichloride (4, rac-dimethylsilyl-bis[l-(2-n-propyl -4-(1-naphthylindenyl]zirconium dichloride (5, rac-dimethylsilyl-[1-(2-ethyl-4-(5-(2,2-dimethyl-2,3-dihydro-1H-cyclopenta [a]naphthalenylindenyl][1-(2-n-propyl-4-(5-(2,2-dimethyl-2,3-dihydro-1H-cyclopenta[a] naphthalenylindenyl]zirconium dichloride (6, rac-dimethylsilyl-bis[1-(2-ethyl-4-(9-phenanthrylindenyl]zirconium dichloride (7, and rac-dimethylsilyl-bis[l-(2-n-propyl-4-(9-phenanthrylindenyl]zirconium dichloride (8. We found that the ratio of the pendant vinyls and vinylenes is strongly affected by the bulkiness of the substituent on the complexes examined. The vinyl content increased linearly in the following order, 8 > 7 > 6 > 5 > 4 > 3 > 2 > 1. Notably, complex 8/DMAO formed ethylene/1,3-butadiene copolymers possessing predominant vinyl groups, which can be crucial precursors for functionalized polyolefins. Likewise, complex 8/DMAO afforded propylene/1,3-butadiene copolymers with predominant vinyl groups.

  14. Synthesis and Structure of Vanadium Halide Complexes Containing Diphosphine Ligands with Pendant Amines

    Egbert, Jonathan D.; Labios, Liezel A.; Darmon, Jonathan M.; Piro, Nicholas A.; Scott Kassel, W.; Mock, Michael T.

    2016-02-18

    A series of vanadium(III) diiodide complexes of the formula CpV(PRNR'PR)I2 (Cp = 5-C5H5; PRNR'PR = (R2PCH2)2N(R)), where R = Et, R = Me (1a), R = Ph (1b); R = Ph, R = Me (1c)) is reported. The corresponding vanadium(II) monoiodide complexes of the formula CpV(PRNR'PR)I, where R = Et, R = Me (2a), R = Ph (2b); R = Ph, R = Me (2c)) were prepared in THF by reduction of 1a-c with Zn powder. The paramagnetic complexes 1a-c and 2a-c are characterized by elemental analysis, 1H NMR spectroscopy, and by cyclic voltammetry for complexes 2b and 4b. Complexes 1c and 2a-c were also characterized in the single crystal by X-ray crystallography. We report the preparation of the vanadium(II) complexes CpV(PPh2NPh2)I (3) (PPh2NPh2 = 1,5-diphenyl-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane) and trans-[VCl2(PEtNMePEt)2] (4a) and trans-[VCl2(PEtNPhPEt)2] (4b). These complexes represent initial coordination chemistry of vanadium complexes with PRNR'PR and PPh2NPh2 diphosphine ligands, which contain a pendant amine in the second coordination sphere. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  15. Lasing features of dye-doped pendant drops added with polymer particles: spectral blueshift and intensity enhancement

    普小云; 张曙; 陈超华; 李荣基

    2002-01-01

    When micrometre-sized polymer particles were added into a dye-doped pendant drop that acted as a quasi-two-dimensional circular resonator, we found a blueshift of the peak wavelength of its lasing spectrum. The lasing outputwas also enhanced by the particles. The spectral blueshift was explained by a model of dye lasing in a circular cavity.The model includes losses of the scattering particles, medium absorption, and radiation leakage. An optimum particledensity for maximum lasing output was deduced. The results are consistent with our experimental findings.

  16. A modular synthesis of dithiocarbamate pendant unnatural α-amino acids

    Unnatural α-amino acids containing dithiocarbamate side chains were synthesized by a one-pot reaction of in-situ generated dithiocarbamate anions with sulfamidates. A wide range of these anions participated in the highly regio- and stereo-selective ring opening of sulfamidates to...

  17. ARM Soc Based Enotebook

    Pranita C Bawankar

    2014-05-01

    Full Text Available In recent years, electronic media has grown very fast replacing papers, tape devices, books, etc. The new technologies provide large number of data into single device, fast searching options and more readability than ever. As eBooks are replacing books; we are proposing ENotebook system in which user can write as he did in notebook, save, searches and then reread content. This paper presents design and development of ENotebook using ARM7. The system uses touch screen to get input data and operations like save, delete, open & close of data file. All data sensed by touch screen is digitized by internal ADCs of LPC2148 microcontroller which gives low power platform with fast execution. The output is shown on graphical LCD. Whatever user writes on screen it may need to save for future use. The content of such hand written data will be in graphical/pictorial form hence required large of memory for storage. We can provide external memory using pen drive, memory card, EEPROM etc. in this system we are using SD card interfacing through SPI port.

  18. ARM Lead Mentor Selection Process

    Sisterson, DL

    2013-03-13

    The ARM Climate Research Facility currently operates more than 300 instrument systems that provide ground-based observations of the atmospheric column. To keep ARM at the forefront of climate observations, the ARM infrastructure depends heavily on instrument scientists and engineers, also known as Instrument Mentors. Instrument Mentors must have an excellent understanding of in situ and remote-sensing instrumentation theory and operation and have comprehensive knowledge of critical scale-dependent atmospheric processes. They also possess the technical and analytical skills to develop new data retrievals that provide innovative approaches for creating research-quality data sets.

  19. Taxation, stateness and armed groups

    Hoffmann, Kasper; Vlassenroot, Koen; Marchais, Gauthier

    2016-01-01

    rackets, to the material reciprocation of the recognition of rights. Focusing on the taxation practices of armed groups, the article argues that taxation is at the core of armed groups’ production of public authority and citizenship, and that their modes of taxation are based on long-standing registers...... of authority and practices of rule that originate in the colonial era. In particular, the article shows that by appealing to both local customary and national forms of political community and citizenship, armed groups are able to assume public authority to tax civilians. However, their public authority may...

  20. Data on synthesis and thermo-mechanical properties of stimuli-responsive rubber materials bearing pendant anthracene groups.

    Manhart, Jakob; Ayalur-Karunakaran, Santhosh; Radl, Simone; Oesterreicher, Andreas; Moser, Andreas; Ganser, Christian; Teichert, Christian; Pinter, Gerald; Kern, Wolfgang; Griesser, Thomas; Schlögl, Sandra

    2016-12-01

    The photo-reversible [4πs+4πs] cycloaddition reaction of pendant anthracene moieties represents a convenient strategy to impart wavelength dependent properties into hydrogenated carboxylated nitrile butadiene rubber (HXNBR) networks. The present article provides the (1)H NMR data on the reaction kinetics of the side chain functionalization of HXNBR. 2-(Anthracene-9-yl)oxirane with reactive epoxy groups is covalently attached to the polymer side chain of HXNBR via ring opening reaction between the epoxy and the carboxylic groups. Along with the identification, (1)H NMR data on the quantification of the attached functional groups are shown in dependence on reaction time and concentration of 2-(anthracene-9-yl)oxirane. Changes in the modification yield are reflected in the mechanical properties and DMA data of photo-responsive elastomers are illustrated in dependence on the number of attached anthracene groups. DMA curves over repeated cycles of UV induced crosslinking (λ>300 nm) and UV induced cleavage (λ=254 nm) are further depicted, demonstrating the photo-reversibility of the thermo-mechanical properties. Interpretation and discussion of the data are provided in "Design and application of photo-reversible elastomer networks by using the [4πs+4πs] cycloaddition reaction of pendant anthracene groups" (Manhart et al., 2016) [1].

  1. SYNTHESIS,CHARACTERIZATION AND PHOTOLUMINESCENT PROPERTIES OF NEW PLATINUM-CONTAINING POLY(FLUORENYLENEETHYNYLENE) ANCHORED WITH CARBAZOLE PENDANTS

    Cheuk-lam Ho; Wai-yeung Wong

    2009-01-01

    A new luminescent and thermally stable platinum(Ⅱ) polyyne polymer trans-[-Pt(PBu3)2C≡CArC≡C-]n (P1) containing the 2,7-fluorene chromophoric spacer substituted by pendant carbazolyl group via long alkyl bridges. The regiochemical structures of these compounds were studied by various spectroscopic analyses. We report the photophysical properties of this group 10 polymetallayne and a comparison was made to its binuclear model complex trans-[Pt(Ph)(PEt3)2C≡CArC≡CPt(Ph)(PEt3)2] (M1) as well as to those with non-carbazole-containing fluorene spacer (P2 and M2). Upon photoexcitation, each of P1 and M1 emits an intense purple-blue fluorescence emission in the near-UV to visible region in dilute fluid solutions at room temperature. Harvesting of organic triplet emissions harnessed through the strong heavy-atom effects of platinum metal was examined and at 77 K, each of the metalated compounds displayed dual emission bands, viz. Both the fluorescence and the lower-lying phosphorescence. Spectroscopic results revealed that the formation of excimers was suppressed by introducing carbazole side groups. The spatial extent of the lowest singlet and triplet excitons in PI and M1 was fully elucidated. Such organometallic poly(fluorenyleneethynylene)s anchored with the carbazole pendants was found to have an improved thermal stability and suppressed aggregation.

  2. Pseudotachylite Bearing Cretaceous Fault in the Saddlebag Lake Pendant, Central Sierra Nevada, CA

    Whitesides, A. S.; Cao, W.; Paterson, S. R.

    2010-12-01

    Over the past several years the undergraduate researchers and mentors in the University of Southern California’s Undergraduate Team Research program has mapped the northern continuation of the Gem Lake shear zone from Gem Lake to Virginia Canyon near the north end of the Saddlebag pendant. In the center of this dominantly dextral, ductile shear zone we now recognize a pseudotachylite bearing brittle fault that often juxtaposes Triassic metavolcanics to the east of the fault with a Jurassic metasedimentary package to the west of the fault. Kinematic indicators such as slickenlines, steps, and offset dikes found within the brittle fault zone also suggest dextral oblique motion, similar to the motion of the ductile shear zone. The brittle fault dips steeply and strikes N-NW with the fault zone width varying from narrow (sub m scale) to a 100-200 m wide fracture zone as seen in the Sawmill area. Jurrasic metasediments (> 177Ma) and Cretaceous metavolcanics (110-95Ma) lie to the West of the fault and Triassic metavolcanics (219Ma) lie to the East of the fault in the Virginia Canyon, Saddlebag Lake, and Sawmill areas. The absence of ~45 million years of Jurassic metavolcanics along the contact of the fault in each area, suggests tectonic removal of the sequence. Pseudotachylite, quartz vein rich breccias, gouge, fault scarps, and truncated Cathedral Peak dikes (~88 Ma) originating from the Tuolumne Batholith (TB), are common features associated with the brittle fault. The truncated, 88 Ma Cathedral Peak dikes plus nearby biotite cooling ages of 82 Ma indicate that displacement on the brittle fault continued well after TB emplacement and cooling and likely continued after ~80 Ma. The pseudotachylite suggests earthquakes occurred on the brittle fault during the Cretaceous. Movement also occurred along the fault at fairly shallow depths as indicated by the presence of vugs, or cavities with free euhedral crystal growth, within the quartz vein breccias. In the Sawmill

  3. The Synthesis of a New Type of Calix[4]arene with Chiral Pendant

    2001-01-01

    Two new chiral calixarenes were synthesized by condensing 1,3-bis-chlorocarbomethyl-calix[4]arehes with (1S, 2S)-2-amino-1-(4-nitrophenyl)-1, 3-propanediol, a by-product from antibiotic industry ,and were characterized by 1H-NMR , MS-FAB, and elemental analysis. The 1H-NMR spectra show that those molecules assume a cone conformation in solution.

  4. Synthesis of poly(vinyl ether)s with perfluoroalkyl pendant groups

    Höpken, Jens; Möller, Martin; Lee, Myongsoo; Percec, Virgil

    1992-01-01

    2-Perfluoro(alkyl)ethyl vinyl ethers, F(CF2)nCH2CH2OCHCH2, (n = 6 or 8), were synthesized and polymerized by means of cationic initiators (HI/ZnI2 and CF3SO3H/(CH3)2S). The perfluorohexyl-substituted poly(vinyl ether) is completely amorphous. The polymer with perfluorooctyl segments shows side chain

  5. Bistable Head Positioning Arm Latch

    Wasson, Ken; Endo, Juro; Mita, Masahiro; Abelein, Nathan

    A simple, low cost, yet effective device has been developed for immobilizing the head-arm assembly in a disk drive or similar mechanism during power-off conditions. The latching scheme also provides a consistent means of releasing the head-arm assembly from the immobilized position upon power up of the disk drive. The latch uses no electrical power in either immobilized or released state. This design is immune to extreme torque and linear shock forces applied to the disk drive case. The latch system can use the energy stored in the spinning disks to drive the head-arm assembly toward a safe position while simultaneously arming the latch mechanism to secure the head-arm assembly in the safe position upon arrival. A low energy five msec pulse of current drives the latch from one state to the other. Solenoids as presently used in latch mechanisms are bulky, expensive, have variable force characteristics, and often generate contaminants. The latch described in this paper is expected to replace such solenoids. It may also replace small magnet latches, which have limited latch force and apply unwanted torque to a proximate head positioning arm.

  6. Unequal-Arms Michelson Interferometers

    Tinto, Massimo; Armstrong, J. W.

    2000-01-01

    Michelson interferometers allow phase measurements many orders of magnitude below the phase stability of the laser light injected into their two almost equal-length arms. If, however, the two arms are unequal, the laser fluctuations can not be removed by simply recombining the two beams. This is because the laser jitters experience different time delays in the two arms, and therefore can not cancel at the photo detector. We present here a method for achieving exact laser noise cancellation, even in an unequal-arm interferometer. The method presented in this paper requires a separate readout of the relative phase in each arm, made by interfering the returning beam in each arm with a fraction of the outgoing beam. By linearly combining the two data sets with themselves, after they have been properly time shifted, we show that it is possible to construct a new data set that is free of laser fluctuations. An application of this technique to future planned space-based laser interferometer detector3 of gravitational radiation is discussed.

  7. Algorithms for Unequal-Arm Michelson Interferometers

    Giampieri, Giacomo; Hellings, Ronald W.; Tinto, Massimo; Bender, Peter L.; Faller, James E.

    1994-01-01

    A method of data acquisition and data analysis is described in which the performance of Michelson-type interferometers with unequal arms can be made nearly the same as interferometers with equal arms. The method requires a separate readout of the relative phase in each arm, made by interfering the returning beam in each arm with a fraction of the outgoing beam.

  8. Anionic polymerization and polyhomologation: An ideal combination to synthesize polyethylene-based block copolymers

    Zhang, H.

    2013-08-07

    A novel one-pot methodology combining anionic polymerization and polyhomologation, through a "bridge" molecule (BF3OEt 2), was developed for the synthesis of polyethylene (PE)-based block copolymers. The anionically synthesized macroanion reacts with the "bridge" molecule to afford a 3-arm star (trimacromolecular borane) which serves as an initiator for the polyhomologation. 2013 The Royal Society of Chemistry.

  9. Proprioceptive Interaction between the Two Arms in a Single-Arm Pointing Task.

    Kazuyoshi Kigawa

    Full Text Available Proprioceptive signals coming from both arms are used to determine the perceived position of one arm in a two-arm matching task. Here, we examined whether the perceived position of one arm is affected by proprioceptive signals from the other arm in a one-arm pointing task in which participants specified the perceived position of an unseen reference arm with an indicator paddle. Both arms were hidden from the participant's view throughout the study. In Experiment 1, with both arms placed in front of the body, the participants received 70-80 Hz vibration to the elbow flexors of the reference arm (= right arm to induce the illusion of elbow extension. This extension illusion was compared with that when the left arm elbow flexors were vibrated or not. The degree of the vibration-induced extension illusion of the right arm was reduced in the presence of left arm vibration. In Experiment 2, we found that this kinesthetic interaction between the two arms did not occur when the left arm was vibrated in an abducted position. In Experiment 3, the vibration-induced extension illusion of one arm was fully developed when this arm was placed at an abducted position, indicating that the brain receives increased proprioceptive input from a vibrated arm even if the arm was abducted. Our results suggest that proprioceptive interaction between the two arms occurs in a one-arm pointing task when the two arms are aligned with one another. The position sense of one arm measured using a pointer appears to include the influences of incoming information from the other arm when both arms were placed in front of the body and parallel to one another.

  10. Impact of Pendant 1, 2, 3-Triazole on the Synthesis and Properties of Thiophene-Based Polymers

    Nagarjuna, G.; Yurt, Serkan; Jadhav, Kedar G.; Venkataraman, D.

    2010-10-12

    π-Conjugated moieties are often attached to conjugated polymers to systematically alter their electronic properties. Herein, we report the synthesis and properties of a thiophene polymer bearing a triazole moiety in the third position. Through NMR-based quenching studies, we show that the placement of the triazole moiety alters reaction pathway of the Ni(0)-mediated Grignard metathesis polymerization possibly through chelation. When compared with a triazole on the main chain, the pendant triazole moiety acts as an electron donor and lowers the band gap of the polymer. The triazole moiety also does not hinder the packing of the conjugated backbone. We also show that the fluorescence of this polymer is quenched with PCBM, indicating its potential as a candidate for organic photovoltaic devices.

  11. Exploring the role of pendant amines in transition metal complexes for the reduction of N2 to hydrazine and ammonia

    Bhattacharya, Papri; Prokopchuk, Demyan E.; Mock, Michael T.

    2017-03-01

    This review examines the synthesis and acid reactivity of transition metal dinitrogen complexes bearing diphosphine ligands containing pendant amine groups in the second coordination sphere. This manuscript is a review of the work performed in the Center for Molecular Electrocatalysis. This work was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy (U.S. DOE), Office of Science, Office of Basic Energy Sciences. EPR studies on Fe were performed using EMSL, a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at PNNL. Computational resources were provided by the National Energy Research Scientific Computing Center (NERSC) at Lawrence Berkeley National Laboratory. Pacific Northwest National Laboratory is operated by Battelle for the U.S. DOE.

  12. RAMESES publication standards: realist syntheses

    Wong Geoff

    2013-01-01

    Full Text Available Abstract Background There is growing interest in realist synthesis as an alternative systematic review method. This approach offers the potential to expand the knowledge base in policy-relevant areas - for example, by explaining the success, failure or mixed fortunes of complex interventions. No previous publication standards exist for reporting realist syntheses. This standard was developed as part of the RAMESES (Realist And MEta-narrative Evidence Syntheses: Evolving Standards project. The project's aim is to produce preliminary publication standards for realist systematic reviews. Methods We (a collated and summarized existing literature on the principles of good practice in realist syntheses; (b considered the extent to which these principles had been followed by published syntheses, thereby identifying how rigor may be lost and how existing methods could be improved; (c used a three-round online Delphi method with an interdisciplinary panel of national and international experts in evidence synthesis, realist research, policy and/or publishing to produce and iteratively refine a draft set of methodological steps and publication standards; (d provided real-time support to ongoing realist syntheses and the open-access RAMESES online discussion list so as to capture problems and questions as they arose; and (e synthesized expert input, evidence syntheses and real-time problem analysis into a definitive set of standards. Results We identified 35 published realist syntheses, provided real-time support to 9 on-going syntheses and captured questions raised in the RAMESES discussion list. Through analysis and discussion within the project team, we summarized the published literature and common questions and challenges into briefing materials for the Delphi panel, comprising 37 members. Within three rounds this panel had reached consensus on 19 key publication standards, with an overall response rate of 91%. Conclusion This project used multiple

  13. A mechanistic study of flame retardance of novel copolyester phosphorus containing linked pendant groups by TG/XPS/direct Py-MS

    Nian Hua Huang; Qiang Zhang; Chou Fan; Jian Qi Wang

    2008-01-01

    The flame retardant mechanism of the copolyester phosphorus containing linked pendant groups was investigated by thermogravimetric (TG), X-ray photoelectron spectroscopy (XPS) and direct insertion probe pyrolysis mass spectrometry (DP-MS) technique. TG results show that the incorporation of phosphorus containing unit linked pendant groups can destabilize the copolyester due to the cleavage of P-CH2 bond, and phosphorus containing units cannot promote the char-formation of the copolyester during the thermal degradation of the copolyester. XPS spectra indicate that with the increase of the temperature, the P-CH2 bonds of the copolyester break down gradually, the concentration of phosphorus in the condensed phase products decrease gradually and the chemical state of phosphorus does not change in the temperature of 250-380℃. Direct pyrolysis MS suggests that the P-CH2 bonds cleavage occurs at pendant groups and species containing phosphorus can volatilize into the gas phase. A flame retardant mechanism is proposed for the gas phase mode of action of the halogen-free copolyester phosphorus containing linked pendant groups.

  14. Scanning ARM Cloud Radar Handbook

    Widener, K; Bharadwaj, N; Johnson, K

    2012-06-18

    The scanning ARM cloud radar (SACR) is a polarimetric Doppler radar consisting of three different radar designs based on operating frequency. These are designated as follows: (1) X-band SACR (X-SACR); (2) Ka-band SACR (Ka-SACR); and (3) W-band SACR (W-SACR). There are two SACRs on a single pedestal at each site where SACRs are deployed. The selection of the operating frequencies at each deployed site is predominantly determined by atmospheric attenuation at the site. Because RF attenuation increases with atmospheric water vapor content, ARM's Tropical Western Pacific (TWP) sites use the X-/Ka-band frequency pair. The Southern Great Plains (SGP) and North Slope of Alaska (NSA) sites field the Ka-/W-band frequency pair. One ARM Mobile Facility (AMF1) has a Ka/W-SACR and the other (AMF2) has a X/Ka-SACR.

  15. A Comparative Study of Cellular Uptake and Subcellular Localization of Doxorubicin Loaded in Self-Assemblies of Amphiphilic Copolymers with Pendant Dendron by MDA-MB-231 Human Breast Cancer Cells.

    Viswanathan, Geetha; Hsu, Yu-Hsuan; Voon, Siew Hui; Imae, Toyoko; Siriviriyanun, Ampornphan; Lee, Hong Boon; Kiew, Lik Voon; Chung, Lip Yong; Yusa, Shin-Ichi

    2016-06-01

    Previously synthesized amphiphilic diblock copolymers with pendant dendron moieties have been investigated for their potential use as drug carriers to improve the delivery of an anticancer drug to human breast cancer cells. Diblock copolymer (P71 D3 )-based micelles effectively encapsulate the doxorubicin (DOX) with a high drug-loading capacity (≈95%, 104 DOX molecules per micelle), which is approximately double the amount of drug loaded into the diblock copolymer (P296 D1 ) vesicles. DOX released from the resultant P71 D3 /DOX micelles is approximately 1.3-fold more abundant, at a tumoral acidic pH of 5.5 compared with a pH of 7.4. The P71 D3 /DOX micelles also enhance drug potency in breast cancer MDA-MB-231 cells due to their higher intracellular uptake, by approximately twofold, compared with the vesicular nanocarrier, and free DOX. Micellar nanocarriers are taken up by lysosomes via energy-dependent processes, followed by the release of DOX into the cytoplasm and subsequent translocation into the nucleus, where it exert its cytotoxic effect.

  16. Synthetic strategies for efficient conjugation of organometallic complexes with pendant protein reactive markers

    Jantke, Dominik

    2013-11-01

    Site-directed conjugation of metal centers to proteins is fundamental for biological and bioinorganic applications of transition metals. However, methods for the site-selective introduction of metal centers remain scarce. Herein, we present broadly applicable synthetic strategies for the conjugation of bioactive molecules with a range of organometallic complexes. Following three different synthetic strategies, we were able to synthesize a small library of metal conjugated protein markers featuring different types of protein reactive sites (epoxides, phenylphosphonates, fluorosulfonates and fluorophosphonate groups) as well as different late transition metals (iron, ruthenium, rhodium, palladium and platinum). The products were isolated in moderate to excellent yields and high purity. Furthermore, X-ray diffraction of the metalated protein markers corroborates structural integrity of the metal complex and the protein reactive site. © 2013 Elsevier B.V. All rights reserved.

  17. Pendant triazole ring assisted mesogen containing side chain liquid crystalline polymethacrylates: Synthesis and characterization

    T Palani; C Saravanan; P Kannan

    2011-01-01

    Two series of click chemistry assisted alkoxymethyl-1H-[1,2,3]-triazol-1-yl containing sidechain liquid-crystalline polymethacrylates were synthesized by free radical polymerization technique. Mesogen was linked to backbone through various spacer units. Monomers and polymers were characterized by FT-IR, 1H and 13C-NMR spectral techniques. Thermal stability of polymers was confirmed by thermogravimetric analysis. Mesomorphic property and phase transition temperature of polymers were analysed by differential scanning calorimetry and polarized optical microscopy. Phase transition temperature and mesomorphic property of polymers with respect to insertion of polar alkoxy group on terminal triazole ring and spacer length between backbone and mesogen were investigated. Polymers exhibited grainy like textures under polarized optical microscopy. Spacer length between mesogen and backbone alters phase transition temperature of the polymers.

  18. X-Band PLL Synthesizer

    P. Kutin; Vagner, P.

    2006-01-01

    This paper deals with design and realization of a PLL synthesizer for the microwave X−band. The synthesizer is intended for use as a local oscillator in a K−band downconverter. The design goal was to achieve very low phase noise and spurious free signal with a sufficient power level. For that purpose a low phase noise MMIC VCO was used in phase locked loop. The PLL works at half the output frequency, therefore there is a frequency doubler at the output of the PLL. The output signal ...

  19. Frequency synthesizers concept to product

    Chenakin, Alexander

    2011-01-01

    A frequency synthesizer is an electronic system for generating any of a range of frequencies from a single fixed oscillator. They are found in modern devices like radio receivers, mobile phones, and GPS systems. This comprehensive resource offers RF and microwave engineers a thorough overview of both well-established and recently developed frequency synthesizer design techniques. Professionals find expert guidance on all design aspects, including main architectures, key building blocks, and practical circuit implementation. Engineers learn the development process and gain a solid understanding

  20. Arms control and international security

    Kolkowicz, R. (ed.); Joeck, N.

    1984-01-01

    This book compiles the papers delivered at a symposium held at the University of California, in 1983. It provides the discussions upon the value and importance of arms debate. The paper presents an expression of personal views rather than an analysis of the arguments of the primary presentations.

  1. Nuclear physicist, arms control advocate

    Chang, K

    2002-01-01

    Victor F. Weisskopf, a nuclear physicist who worked on the Manhattan Project to build the first atomic bomb in World War II and later became an ardent advocate of arms control, died Monday at his home in Newton, MA, USA. He was 93 (1 page).

  2. Hand/Wrist/Arm Problems

    ... your doctor right away.Start OverDiagnosisYou may have TENDINITIS, inflammation of a tendon.Self CareUse an over- ... OverDiagnosisYour may have TENNIS ELBOW, a type of TENDINITIS.Self CareRest the arm, apply ice packs to ...

  3. Information Retrieval for Ecological Syntheses

    Bayliss, Helen R.; Beyer, Fiona R.

    2015-01-01

    Research syntheses are increasingly being conducted within the fields of ecology and environmental management. Information retrieval is crucial in any synthesis in identifying data for inclusion whilst potentially reducing biases in the dataset gathered, yet the nature of ecological information provides several challenges when compared with…

  4. Laboratory Syntheses of Insect Pheromones.

    Cormier, Russell A.; Hoban, James N.

    1984-01-01

    Provides background information and procedures for the multi-step synthesis of tiger moth and boll weevil pheromones (sex attractants). These syntheses require several laboratory periods. The tiger moth pheromone synthesis is suitable for introductory organic chemistry while the boll weevil pheromone is recommended for an advanced laboratory…

  5. Template-synthesized opal hydrogels

    LI Jun; JI Lijun; RONG Jianhua; YANG Zhenzhong

    2003-01-01

    Opal hydrogels could be synthesized with polymer inverse opal template. A pH responsive opal N-iso- propylacrylamide/acrylic acid copolymerized hydrogel was prepared as an example. The ordered structure and response to pH were investigated. Through the sol-gel process of tetrabutyl titanate, opal titania was obtained with the opal hydrogel template.

  6. Multiple Identifications in Multi-Armed Bandits

    Bubeck, Sébastien; Viswanathan, Nitin

    2012-01-01

    We study the problem of identifying the top $m$ arms in a multi-armed bandit game. Our proposed solution relies on a new algorithm based on successive rejects of the seemingly bad arms, and successive accepts of the good ones. This algorithmic contribution allows to tackle other multiple identifications settings that were previously out of reach. In particular we show that this idea of successive accepts and rejects applies to the multi-bandit best arm identification problem.

  7. Synthesis and electrochemical studies of cobalt(III) monohydride complexes containing pendant amines.

    Wiedner, Eric S; Roberts, John A S; Dougherty, William G; Kassel, W Scott; DuBois, Daniel L; Bullock, R Morris

    2013-09-03

    Two new tetraphosphine ligands, P(nC-PPh2)2N(Ph)2 (1,5-diphenyl-3,7-bis((diphenylphosphino)alkyl)-1,5-diaza-3,7-diphosphacyclooctane; alkyl = (CH2)2, n = 2 (L2); (CH2)3, n = 3 (L3)), have been synthesized. Coordination of these ligands to cobalt affords the complexes [Co(II)(L2)(CH3CN)](2+) and [Co(II)(L3)(CH3CN)](2+), which are reduced by KC8 to afford [Co(I)(L2)(CH3CN)](+) and [Co(I)(L3)(CH3CN)](+). Protonation of the Co(I) complexes affords [HCo(III)(L2)(CH3CN)](2+) and [HCo(III)(L3)(CH3CN)](2+). The cyclic voltammetry of [HCo(III)(L2)(CH3CN)](2+), analyzed using digital simulation, is consistent with an ErCrEr reduction mechanism involving reversible acetonitrile dissociation from [HCo(II)(L2)(CH3CN)](+) and resulting in formation of HCo(I)(L2). Reduction of HCo(III) also results in cleavage of the H-Co bond from HCo(II) or HCo(I), leading to formation of the Co(I) complex [Co(I)(L2)(CH3CN)](+). Under voltammetric conditions, the reduced cobalt hydride reacts with a protic solvent impurity to generate H2 in a monometallic process involving two electrons per cobalt. In contrast, under bulk electrolysis conditions, H2 formation requires only one reducing equivalent per [HCo(III)(L2)(CH3CN)](2+), indicating a bimetallic route wherein two cobalt hydride complexes react to form 2 equiv of [Co(I)(L2)(CH3CN)](+) and 1 equiv of H2. These results indicate that both HCo(II) and HCo(I) can be formed under electrocatalytic conditions and should be considered as potential catalytic intermediates.

  8. Regenerator cross arm seal assembly

    Jackman, Anthony V.

    1988-01-01

    A seal assembly for disposition between a cross arm on a gas turbine engine block and a regenerator disc, the seal assembly including a platform coextensive with the cross arm, a seal and wear layer sealingly and slidingly engaging the regenerator disc, a porous and compliant support layer between the platform and the seal and wear layer porous enough to permit flow of cooling air therethrough and compliant to accommodate relative thermal growth and distortion, a dike between the seal and wear layer and the platform for preventing cross flow through the support layer between engine exhaust and pressurized air passages, and air diversion passages for directing unregenerated pressurized air through the support layer to cool the seal and wear layer and then back into the flow of regenerated pressurized air.

  9. X-Band PLL Synthesizer

    P. Kutin

    2006-04-01

    Full Text Available This paper deals with design and realization of a PLL synthesizer for the microwave X−band. The synthesizer is intended for use as a local oscillator in a K−band downconverter. The design goal was to achieve very low phase noise and spurious free signal with a sufficient power level. For that purpose a low phase noise MMIC VCO was used in phase locked loop. The PLL works at half the output frequency, therefore there is a frequency doubler at the output of the PLL. The output signal from the frequency doubler is filtered by a band-pass filter and finally amplified by a single stage amplifier.

  10. Phosphorylcholine substituted polyolefins: New syntheses, solution assemblies, and polymer vesicles

    Kratz, Katrina A.

    This thesis describes the synthesis and applications of a new series of amphiphilic homopolymers and copolymers consisting of hydrophobic polyolefin backbone and hydrophilic phosphorylcholine (PC) pendant groups. These polymers are synthesized by ring opening metathesis polymerization (ROMP) of a novel PC- cyclooctene monomer, and copolymerization of various functionalized cyclooctene comonomers. Incorporation of different comonomers into the PC-polyolefin backbone affords copolymers with different functionalities, including crosslinkers, fluorophores, and other reactive groups, that tune the range of applications of these polymers, and their hydrophobic/hydrophilic balance. The amphiphilic nature of PC-polyolefins was exploited in oil-water interfacial assembly, providing robust polymer capsules to encapsulate and deliver nanoparticles to damaged regions of a substrate in a project termed `repair-and-go.' In repair-and-go, a flexible microcapsule filled with a solution of nanoparticles probes an imperfection-riddled substrate as it rolls over the surface. The thin capsule wall allows the nanoparticles to escape the capsules and enter into the cracks, driven in part by favorable interactions between the nanoparticle ligands and the cracked surface (i.e., hydrophobic-hydrophobic interactions). The capsules then continue their transport along the surface, filling more cracks and depositing particles into them. The amphiphilic nature of PC-polyolefins was also exploited in aqueous assembly, forming novel polymer vesicles in water. PC-polyolefin vesicles ranged in size from 50 nm to 30 µm. The mechanical properties of PC-polyolefin vesicles were measured by micropipette aspiration techniques, and found to be more robust than conventional liposomes or polymersomes prepared from block copolymers. PC-polyolefin vesicles have potential use in drug delivery; it was found that the cancer drug doxorubicin could be encapsulated efficiently in PC-polyolefin vesicles. In

  11. Dual arm master controller concept

    Kuban, D.P.; Perkins, G.S.

    1984-01-01

    The Advanced Servomanipulator (ASM) slave was designed with an anthropomorphic stance, gear/torque tube power drives, and modular construction. These features resulted in increased inertia, friction, and backlash relative to tape-driven manipulators. Studies were performed which addressed the human factors design and performance trade-offs associated with the corresponding master controller best suited for the ASM. The results of these studies, as well as the conceptual design of the dual arm master controller, are presented. 6 references, 3 figures.

  12. The DOE ARM Aerial Facility

    Schmid, Beat; Tomlinson, Jason M.; Hubbe, John M.; Comstock, Jennifer M.; Mei, Fan; Chand, Duli; Pekour, Mikhail S.; Kluzek, Celine D.; Andrews, Elisabeth; Biraud, S.; McFarquhar, Greg

    2014-05-01

    The Department of Energy Atmospheric Radiation Measurement (ARM) Program is a climate research user facility operating stationary ground sites that provide long-term measurements of climate relevant properties, mobile ground- and ship-based facilities to conduct shorter field campaigns (6-12 months), and the ARM Aerial Facility (AAF). The airborne observations acquired by the AAF enhance the surface-based ARM measurements by providing high-resolution in-situ measurements for process understanding, retrieval-algorithm development, and model evaluation that are not possible using ground- or satellite-based techniques. Several ARM aerial efforts were consolidated into the AAF in 2006. With the exception of a small aircraft used for routine measurements of aerosols and carbon cycle gases, AAF at the time had no dedicated aircraft and only a small number of instruments at its disposal. In this "virtual hangar" mode, AAF successfully carried out several missions contracting with organizations and investigators who provided their research aircraft and instrumentation. In 2009, AAF started managing operations of the Battelle-owned Gulfstream I (G-1) large twin-turboprop research aircraft. Furthermore, the American Recovery and Reinvestment Act of 2009 provided funding for the procurement of over twenty new instruments to be used aboard the G-1 and other AAF virtual-hangar aircraft. AAF now executes missions in the virtual- and real-hangar mode producing freely available datasets for studying aerosol, cloud, and radiative processes in the atmosphere. AAF is also engaged in the maturation and testing of newly developed airborne sensors to help foster the next generation of airborne instruments.

  13. Solid phase syntheses of oligoureas

    Burgess, K.; Linthicum, D.S.; Russell, D.H.; Shin, H.; Shitangkoon, A.; Totani, R.; Zhang, A.J.; Ibarzo, J. [Texas A& M Univ., College Station, TX (United States)

    1997-02-19

    Isocyanates 7 were formed from monoprotected diamines 3 or 6, which in turn can be easily prepared from commercially available N-BOC- or N-FMOC-protected amino acid derivatives. Isocyanates 7, formed in situ, could be coupled directly to a solid support functionalized with amine groups or to amino acids anchored on resins using CH{sub 2}Cl{sub 2} as solvent and an 11 h coupling time at 25 {degree}C. Such couplings afforded peptidomimetics with an N-phthaloyl group at the N-terminus. The optimal conditions identified for removal of the N-phthaloyl group were to use 60% hydrazine in DMF for 1-3 h. Several sequences of amino acids coupled to ureas (`peptidic ureas`) and of sequential urea units (`oligoureas`) were prepared via solid phase syntheses and isolated by HPLC. Partition coefficients were measured for two of these peptidomimetics, and their water solubilities were found to be similar to the corresponding peptides. A small library of 160 analogues of the YGGFL-amide sequence was prepared via Houghten`s tea bag methodology. This library was tested for binding to the anti-{beta}-endorphin monoclonal antibody. Overall, this paper describes methodology for solid phase syntheses of oligourea derivatives with side chains corresponding to some of the protein amino acids. The chemistry involved is ideal for high-throughput syntheses and screening operations. 51 refs., 3 figs., 2 tabs.

  14. Cobalt Complexes Containing Pendant Amines in the Second Coordination Sphere as Electrocatalysts for H2 Production

    Fang, Ming; Wiedner, Eric S.; Dougherty, William G.; Kassel, W. S.; Liu, Tianbiao L.; DuBois, Daniel L.; Bullock, R. Morris

    2014-10-27

    A series of heteroleptic 17e- cobalt complexes, [CpCoII(PtBu2NPh2)](BF4), [CpC6F5CoII(PtBu2NPh2)](BF4), [CpC5F4NCoII(PtBu2NPh2)](BF4), [where P2tBuN2Ph = 1,5-diphenyl-3,7-di(tert-butyl)-1,5-diaza-3,7-diphosphacyclooctane, CpC6F5 = C5H4(C6F5), and CpC5F4N = C5H4(C5F4N)] were synthesized, and structures of all three were determined by X-ray crystallography. Electrochemical studies showed that the CoIII/II couple of [CpC5F4NCoII(PtBu2NPh2)]+ appears 250 mV positive of the CoIII/II couple of [CpCoII(PtBu2NPh2)] as a result of the strongly electron-withdrawing perfluorpyridyl substituent on the Cp ring. Reduction of these paramagnetic CoII complexes by KC8 led to the diamagnetic 18e- complexes CpICo(PtBu2NPh2), CpC6F5CoI(PtBu2NPh2), CpC5F4NCoI(PtBu2NPh2), which were also characterized by crystallography. Protonation of these neutral CoI complexes led to the cobalt hydrides [CpCoIII(PtBu2NPh2)H](BF4), [CpC6F5CoIII(PtBu2NPh2)H](BF4), and [CpC5F4NCoIII(PtBu2NPh2)H](BF4). The cobalt hydride with the most electron-withdrawing Cp ligand, [CpC5F4NCoIII(PtBu2NPh2)H]+ is an electrocatalyst for production of H2 using 4-MeOC6H4NH3BF4 (pKaMeCN = 11.86) with a turnover frequency of 350 s-1 and an overpotential of 0.75 V. Experimental measurement of thermochemical data provided further insights into the thermodynamics of H2 elimination. This research was supported as part of the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  15. Polymeric adsorbents with peptide pendants as artificial receptors for β-Mactam antibiotics by mimicking the binding sites of β-lactamases

    马建标; 谢志东; 王永健; 王亦农; 范云鸽; 何炳林

    1997-01-01

    A scries of polymeric adsorbents with peptide pendants were designed as the artificial receptors of β-laetarn antibiotics by mimicking the structures of binding site in β-lactamases.Crosslinked poly(N,N-dimethyl acry-lamide) gel as a carrier was prepared by suspension copolyrnerization of N,N-dimethyl acrylamide and N,N-bisacryl-diaminoethane and then functionalized with ethylenediamine after partial hydrolysis.Using solid-phase peptide synthesis with symmetrical anhydride of protected amino acid step by step,various peptide pendants were respectively anchored onto the functionalized carrier.The adsorption properties of these peptide-containing adsorbents for β-lactam antibiotics such as ampicillin and cefotaxime were then studied.The results showed that only those adsorbents in which peptide chains contained more than one lysine residues could obviously adsorb both β-lactams and that static interaction as well as hydrogen bond played an important role during the adsorption

  16. High precision detector robot arm system

    Shu, Deming; Chu, Yong

    2017-01-31

    A method and high precision robot arm system are provided, for example, for X-ray nanodiffraction with an X-ray nanoprobe. The robot arm system includes duo-vertical-stages and a kinematic linkage system. A two-dimensional (2D) vertical plane ultra-precision robot arm supporting an X-ray detector provides positioning and manipulating of the X-ray detector. A vertical support for the 2D vertical plane robot arm includes spaced apart rails respectively engaging a first bearing structure and a second bearing structure carried by the 2D vertical plane robot arm.

  17. Effect of Contact Time and Gas Component on Interfacial Tension of CO2/Crude Oil System by Pendant Drop Method

    Xin Wang

    2015-01-01

    Full Text Available Pendant drop method has been used to measure the equilibrium interfacial tension and dynamic interfacial tension of CO2/crude oil system under the simulated-formation condition, in which the temperature is 355.65 K and pressure ranges from 0 MPa to 30 MPa. The test results indicated that the equilibrium interfacial tension of CO2/crude oil systems decreased with the increase of the systematic pressure. The dynamic interfacial tension of CO2/original oil, CO2/remaining oil, and CO2/produced oil systems is large at the initial contact and decreases gradually after that, and then finally it reaches dynamic balance. In addition, the higher the pressure is, the larger the magnitude of changing of CO2/crude oil interfacial tension with time will reduce. Moreover, by PVT phase experiment, gas-oil ratio, gas composition, and well fluid composition have been got, and different contents of light components in three oil samples under reservoir conditions have also been calculated. The relationship between equilibrium interfacial tensions and pressures of three different components of crude oil and CO2 system was studied, and the higher C1 is, the lower C2–C10 will be, and the equilibrium interfacial tension will get higher. Therefore, the effect of light weight fractions on interfacial tension under formation conditions was studied.

  18. Surface characterization of human serum albumin and sodium perfluorooctanoate mixed solutions by pendant drop tensiometry and circular dichroism.

    Messina, Paula; Prieto, Gerardo; Dodero, Verónica; Cabrerizo-Vílchez, M A; Maldonado-Valderrama, J; Ruso, Juan M; Sarmiento, Félix

    2006-06-15

    The interfacial behavior of mixed human serum albumin (HSA)/sodium perfluorooctanoate (C8FONa) solutions is examined by using two experimental techniques, pendant drop tensiometry and circular dichroism spectroscopy. Through the analysis of the surface tension of the mixed solutions, surface competitive adsorption at the air-water interface between C8FONa and HSA is detected. The dynamic adsorption curves exhibit the distinct regimes in their time-dependent surface tension. The nature of these regimes is further analyzed in terms of the variation of the molecules surface areas. As a consequence, a compact and dense structure was formed where protein molecules were interconnected and overlapped. Thus, a reduction of the area occupied per molecule from 100 to 0.2 nm(2) is interpreted as a gel-like structure at the surface. The presence of the surfactant seems to favor the formation of this interfacial structure. Finally, measurements of circular dichroism suggests a compaction of the protein due to the association with the surfactant given by an increase of alpha-helix structure in the complexes as compared to that of pure protein.

  19. Buoyancy-driven detachment of a wall-bound pendant drop: interface shape at pinchoff and nonequilibrium surface tension.

    Lamorgese, A; Mauri, R

    2015-09-01

    We present numerical results from phase-field simulations of the buoyancy-driven detachment of an isolated, wall-bound pendant emulsion droplet acted upon by surface tension and wall-normal buoyancy forces alone. Our theoretical approach follows a diffuse-interface model for partially miscible binary mixtures which has been extended to include the influence of static contact angles other than 90^{∘}, based on a Hermite interpolation formulation of the Cahn boundary condition as first proposed by Jacqmin [J. Fluid Mech. 402, 57 (2000)JFLSA70022-112010.1017/S0022112099006874]. In a previous work, this model has been successfully employed for simulating triphase contact line problems in stable emulsions with nearly immiscible components, and, in particular, applied to the determination of critical Bond numbers for buoyancy-driven detachment as a function of static contact angle. Herein, the shapes of interfaces at pinchoff are investigated as a function of static contact angle and distance to the critical condition. Furthermore, we show numerical results on the nonequilibrium surface tension that help to explain the discrepancy between our numerically determined static contact angle dependence of the critical Bond number and its sharp-interface counterpart based on a static stability analysis of equilibrium shapes after numerical integration of the Young-Laplace equation. Finally, we show the influence of static contact angle and distance to the critical condition on the temporal evolution of the minimum neck radius in the necking regime of drop detachment.

  20. Universal phase and force diagrams for a microbubble or pendant drop in static fluid on a surface

    Wei, P. S.; Hsiao, C. C.; Chen, K. Y.

    2008-01-01

    Dimensionless three-dimensional universal phase and lift force diagrams of a microbubble (or pendant drop) in static liquid on a solid surface (or orifice) are presented in this work. Microbubble dynamics has been found to play a vital role in mass, momentum, energy, and concentration transfer rates in contemporary micro- and nanosciences and technologies. In this study, dimensionless phase and force diagrams are introduced by utilizing the analytical solutions of the microbubble shape reported in the literature. It shows that phase and force diagrams can be universally specified by two dimensionless independent parameters, Bond number, and contact angle (or base radius). Based on the presence of an inflection point or neck on the microbubble surface, each diagram exhibits three regions. Growth, detachment, and entrapment of a microbubble can be described by path lines in three regions. The corresponding universal total lift forces include hydrostatic buoyancy, difference in gas, and hydrostatic pressures at the base, capillary pressure, as well as surface tension induced by the variation of circumference, which has not been treated in the literature so far. In the absence of viscous stress and Marangoni force, the total lift force equals surface tension induced by the variation of circumference. The latter can be an attaching or lifting force, depending on whether the state in the distinct regions and contact angle is less than or greater than a critical angle. The critical angle, which is slightly less than the inclination angle at the inflection point, is decreased with increasing Bond number.

  1. Pendant-drop method coupled to ultraviolet-visible spectroscopy: A useful tool to investigate interfacial phenomena.

    Andrade, Marco A R; Favarin, Bruno; Derradi, Rafael; Bolean, Mayte; Simão, Ana Maria S; Millán, José Luis; Ciancaglini, Pietro; Ramos, Ana P

    2016-09-05

    UV-vis spectroscopy is a powerful tool to investigate surface phenomena. Surface tension measurements coupled to spectroscopic techniques can help to elucidate how the interface organization influences the electronic properties of molecules. However, appreciable sample volumes are usually necessary to achieve strong signals during conduction of experiments. This study reports on the simultaneous acquisition of surface tension data and UV-vis spectra by axisymmetric drop shape analysis (ADSA) coupled to diffuse reflectance (DRUV) spectrophotometry using a pendant microliter-drop that requires small sample volumes and low analyte concentrations. Three example systems gave evidence of the applicability of this technique: (a) disaggregation of an organic dye driven by surfactant as a function of the surface tension and alterations in the UV-vis spectra, (b) activity of a glycosylphosphatidylinositol anchored enzyme estimated from formation of a colored product, and (c) interaction between this enzyme and biomimetic membrane systems consisting of dipalmitoylphosphaditylcholine and cholestenone. Apart from using smaller sample volume, this coupled technique allowed to investigate interfacial organization in the light of electronic spectra obtained in loco within a shorter acquisition time. This procedure provided precise interfacial information about static and dynamic systems. This has been the first study describing the kinetic activity of an enzyme in the presence of phospholipid monolayers through simultaneous determination of the surface tension and UV-vis spectra.

  2. Axisymmetric Drop Shape Analysis: Computational Methods for the Measurement of Interfacial Properties from the Shape and Dimensions of Pendant and Sessile Drops.

    Río; Neumann

    1997-12-15

    State-of-the-art axisymmetric drop shape analysis (ADSA) techniques for the computation of interfacial tensions and contact angles by fitting the Laplace equation of capillarity to the shape and dimensions of pendant and sessile drops are presented. More accurate, efficient, and reliable versions of the technique for the measurement of contact angles from the volume and diameter of sessile drops [axisymmetric drop shape analysis-diameter (ADSA-D)] and for interfacial tension measurements from a series of arbitrary profile coordinates of sessile and pendant drops [axisymmetric drop shape analysis-profile (ADSA-P)] have been developed. Advanced numerical methods have been used to improve the numerical stability and global convergence, for more accurate results and a wider range of applicability of the methods. A new technique called axisymmetric drop shape analysis-height and diameter (ADSA-HD) has been developed to estimate interfacial tensions from the height and diameter of sessile and pendant drops. Numerical simulations using numerically generated drop profiles were used to evaluate the accuracy and applicability of the methods. Copyright 1997 Academic Press.

  3. The Asteroid Redirect Mission (ARM)

    Abell, Paul; Gates, Michele; Johnson, Lindley; Chodas, Paul; Mazanek, Dan; Reeves, David; Ticker, Ronald

    2016-07-01

    To achieve its long-term goal of sending humans to Mars, the National Aeronautics and Space Administration (NASA) plans to proceed in a series of incrementally more complex human spaceflight missions. Today, human flight experience extends only to Low-Earth Orbit (LEO), and should problems arise during a mission, the crew can return to Earth in a matter of minutes to hours. The next logical step for human spaceflight is to gain flight experience in the vicinity of the Moon. These cis-lunar missions provide a "proving ground" for the testing of systems and operations while still accommodating an emergency return path to the Earth that would last only several days. Cis-lunar mission experience will be essential for more ambitious human missions beyond the Earth-Moon system, which will require weeks, months, or even years of transit time. In addition, NASA has been given a Grand Challenge to find all asteroid threats to human populations and know what to do about them. Obtaining knowledge of asteroid physical properties combined with performing technology demonstrations for planetary defense provide much needed information to address the issue of future asteroid impacts on Earth. Hence the combined objectives of human exploration and planetary defense give a rationale for the Asteroid Re-direct Mission (ARM). Mission Description: NASA's ARM consists of two mission segments: 1) the Asteroid Redirect Robotic Mission (ARRM), the first robotic mission to visit a large (greater than ~100 m diameter) near-Earth asteroid (NEA), collect a multi-ton boulder from its surface along with regolith samples, demonstrate a planetary defense technique, and return the asteroidal material to a stable orbit around the Moon; and 2) the Asteroid Redirect Crewed Mission (ARCM), in which astronauts will take the Orion capsule to rendezvous and dock with the robotic vehicle, conduct multiple extravehicular activities to explore the boulder, and return to Earth with samples. NASA's proposed

  4. Physiologically driven avian vocal synthesizer

    Sitt, Jacobo D.; Arneodo, Ezequiel M.; Goller, Franz; Mindlin, Gabriel B.

    2010-03-01

    In this work, we build an electronic syrinx, i.e., a programmable electronic device capable of integrating biomechanical model equations for the avian vocal organ in order to synthesize song. This vocal prosthesis is controlled by the bird’s neural instructions to respiratory and the syringeal motor systems, thus opening great potential for studying motor control and its modification by sensory feedback mechanisms. Furthermore, a well-functioning subject-controlled vocal prosthesis can lay the foundation for similar devices in humans and thus provide directly health-related data and procedures.

  5. Method of synthesizing tungsten nanoparticles

    Thoma, Steven G; Anderson, Travis M

    2013-02-12

    A method to synthesize tungsten nanoparticles has been developed that enables synthesis of nanometer-scale, monodisperse particles that can be stabilized only by tetrahydrofuran. The method can be used at room temperature, is scalable, and the product concentrated by standard means. Since no additives or stabilizing surfactants are required, this method is particularly well suited for producing tungsten nanoparticles for dispersion in polymers. If complete dispersion is achieved due to the size of the nanoparticles, then the optical properties of the polymer can be largely maintained.

  6. Synthesized Optimization of Triangular Mesh

    HU Wenqiang; YANG Wenyu

    2006-01-01

    Triangular mesh is often used to describe geometric object as computed model in digital manufacture, thus the mesh model with both uniform triangular shape and excellent geometric shape is expected. But in fact, the optimization of triangular shape often is contrary with that of geometric shape. In this paper, one synthesized optimizing algorithm is presented through subdividing triangles to achieve the trade-off solution between the geometric and triangular shape optimization of mesh model. The result mesh with uniform triangular shape and excellent topology are obtained.

  7. Les Arméniens communistes en France, une histoire oubliée

    Astrig Atamian

    2007-09-01

    Full Text Available Si le nom de Manouchian, immortalisé par l’Affiche rouge, résonne bien au delà de la communauté arménienne, rares sont ceux parmi les Arméniens à connaître son parcours et celui de ses camarades dans la France de l’entre-deux-guerres. Dans un ouvrage récent sur les Arméniens de Vienne (dans l’Isère, Anahide Ter Minassian affirme que « dans le milieu ouvrier viennois […], les communistes arméniens ont été influents avant, pendant, et après la Seconde Guerre mondiale »1. Comment expliquer alors que parmi les travaux sur les Arméniens en France, aucun ne s’appesantit sur eux ? Il semblerait en effet que la communauté arménienne ait souvent été envisagée comme un tout homogène ne portant pas de dissensions politiques ou sociales. Les Arméniens eux-mêmes, soucieux de ne pas raviver les querelles d’hier, et cherchant à offrir un interlocuteur unique aux élus de la République, ont cédé au « mythe de l’unité ». Mais ne serait-on pas tenté de voir, dans cet oubli du rôle des communistes, le sort réservé au groupe des « vaincus », eux qui pendant des décennies s’étaient montrés hostiles à l’idée d’une Arménie indépendante ?Si bien el nombre de Manouchian, inmortalizado por «el Afiche Rojo», resuena bastante mas allá que en la sola comunidad de los armenios, son escasos en cambio los armenios que conocen su trayectoria así como la de sus camaradas en la Francia del periodo situado entre las dos guerras mundiales. En un texto reciente sobre los armenios de Viena (Isère-Francia, Anahide Ter Minassian afirma que «en los medios obreros de Viena […] los comunistas armenios fueron influyentes, antes, durante y después de la Segunda Guerra Mundial». Entonces, ¿cómo explicar que entre los trabajos sobre los armenios de Francia nadie lo mencione? La comunidad armenia parece haber sido considerada como un todo homogéneo en el que no hay lugar para disenciones políticas o

  8. Information retrieval for ecological syntheses.

    Bayliss, Helen R; Beyer, Fiona R

    2015-06-01

    Research syntheses are increasingly being conducted within the fields of ecology and environmental management. Information retrieval is crucial in any synthesis in identifying data for inclusion whilst potentially reducing biases in the dataset gathered, yet the nature of ecological information provides several challenges when compared with medicine that should be considered when planning and undertaking searches. We present ten recommendations for anyone considering undertaking information retrieval for ecological research syntheses that highlight the main differences with medicine and, if adopted, may help reduce biases in the dataset retrieved, increase search efficiency and improve reporting standards. They are as follows: (1) plan for information retrieval at an early stage, (2) identify and use sources of help, (3) clearly define the question to be addressed, (4) ensure that provisions for managing, recording and reporting the search are in place, (5) select an appropriate search type, (6) identify sources to be used, (7) identify limitations of the sources, (8) ensure that the search vocabulary is appropriate, (9) identify limits and filters that can help direct the search, and (10) test the strategy to ensure that it is realistic and manageable. These recommendations may be of value for other disciplines where search infrastructures are not yet sufficiently well developed.

  9. Dual arm master controller development

    Kuban, D.P.; Perkins, G.S.

    1985-01-01

    The advanced servomanipulator (ASM) slave was designed with an anthropomorphic stance, gear/torque tube power drives, and modular construction. These features resulted in increased inertia, friction, and backlash relative to tape-driven manipulators. Studies were performed which addressed the human factors design and performance trade-offs associated with the corresponding master controller best suited for the ASM. The results of these studies, as well as the conceptual design of the dual arm master controller, are presented. This work was performed as part of the Consolidated Fuel Reprocessing Program at the Oak Ridge National Laboratory. 5 refs., 7 figs., 1 tab.

  10. Arms Race in Maghreb Region

    EL AMOURI ALLAL

    2016-01-01

    Maghreb countries competitive altitude towards each other’ s has reached a higher level by entering an arms race.Morocco and Al ̄geria have dominated more than 50 percent of the Africa’ s imported weapons,mainly because of inherited cold war mentality of competi ̄tion and hostility. Maghreb countries competition has drugged the re ̄gion into a chaos that threatens regional stability obviously which af ̄fect the domestic political stability,since military spending weakens the financial capacity of states.

  11. Living cationic polymerization and polyhomologation: an ideal combination to synthesize functionalized polyethylene–polyisobutylene block copolymers

    Zhang, Hefeng

    2015-12-17

    A series of hydroxyl-terminated polyisobutylene-b-polyethylene (PIB-b-PE-OH) copolymers were synthesized by combining living cationic polymerization and polyhomologation. Allyl-terminated PIBs, synthesized by living cationic polymerization, were hydroborated with BH3·THF to produce 3-arm boron-linked stars, PIB3B, which served as macroinitiators for the in situ polyhomologation of dimethylsulfoxonium methylide. The resulting 3-arm star block copolymers, (PIB-b-PE)3B, were oxidized/hydrolysed to afford PIB-b-PE-OH. Characterization of all intermediates and final products by high temperature gel permeation chromatography (HT-GPC) and proton nuclear magnetic resonance spectroscopy (1H NMR) revealed the well-defined character of the copolymers. The thermal properties of the copolymers were studied by differential scanning calorimetry (DSC).

  12. Ristripatsid Eesti 12.–13. sajandi laibakalmistutes: kas ehted või usu tunnused? / The cross-shaped pendants of inhumation burials in 12th-13th century Estonia: adornments or signs of belief?

    Tuuli Kurisoo

    2012-01-01

    Full Text Available Cross-shaped pendants are one of the most discussed symbolically laden artefacts among Estonian archaeological material. The beginning of the distribution of cross-shaped pendants dates back to 11th century when the artefacts, though scarce, appear. The number of such pendants increases noticeably at the very end of the Iron Age. Due to the ambiguous entity of cross and time context, cross-pendants have been interpreted either as symbols of Christian faith, as pieces of adornment not affiliated with Christianity, or as objects with magical qualities. In this paper I study pendants found in the inhumation cemeteries of Estonia. Only those provide us with an archaeological context which shows precisely who could have worn them and how. The analyzed cross-pendants were found at Pada, Kaberla, Kukruse, Haimre and Tammiku cemeteries and from the early burials in Viru-Nigula churchyard. As artefacts, the cross pendants are more or less stylized Greek crosses. In most cases the pendants were either used as a part of jewellery or worn singularly around the neck area. From the total of 48 analyzed cross-pendants one fourth could be interpreted as locally produced items. Of local origin are probably lead pendants from Pada cemetery, heads of decorative pins worn as cross-shaped pendants from Viru-Nigula and Kaberla cemeteries, and obvious scrap and unfinished pendant crosses. In addition, I would like to draw attention that cross-pendants from inhumation burials do not contain many widespread forms, such as ‘Scandinavian’ and some other widespread Russian origin types, which have been found in hoards, from hill-forts and cremation burials. This observation could confirm that cross pendants from 12th–13th century inhumation burials were communally recognized and some of them were locally manufactured. As the next stage of my investigation I studied different occurrence contexts of cross pendants in cemeteries and burials: the location of burials with

  13. Latent herpesvirus infection arms NK cells.

    White, Douglas W; Keppel, Catherine R; Schneider, Stephanie E; Reese, Tiffany A; Coder, James; Payton, Jacqueline E; Ley, Timothy J; Virgin, Herbert W; Fehniger, Todd A

    2010-06-03

    Natural killer (NK) cells were identified by their ability to kill target cells without previous sensitization. However, without an antecedent "arming" event, NK cells can recognize, but are not equipped to kill, target cells. How NK cells become armed in vivo in healthy hosts is unclear. Because latent herpesviruses are highly prevalent and alter multiple aspects of host immunity, we hypothesized that latent herpesvirus infection would arm NK cells. Here we show that NK cells from mice latently infected with Murid herpesvirus 4 (MuHV-4) were armed as evidenced by increased granzyme B protein expression, cytotoxicity, and interferon-gamma production. NK-cell arming occurred rapidly in the latently infected host and did not require acute viral infection. Furthermore, NK cells armed by latent infection protected the host against a lethal lymphoma challenge. Thus, the immune environment created by latent herpesvirus infection provides a mechanism whereby host NK-cell function is enhanced in vivo.

  14. Introduction to Reading and Visualizing ARM Data

    Mather, James [Pacific Northwest National Laboratory

    2014-02-18

    Atmospheric Radiation Measurement (ARM) Program standard data format is NetCDF 3 (Network Common Data Form). The object of this tutorial is to provide a basic introduction to NetCDF with an emphasis on aspects of the ARM application of NetCDF. The goal is to provide basic instructions for reading and visualizing ARM NetCDF data with the expectation that these examples can then be applied to more complex applications.

  15. Asymmetric Syntheses Aided by Biocatalysts

    陈沛然; 顾建新; 魏志亮; 韩世清; 李祖义; 林国强

    2003-01-01

    This article summarizes the achievements of the authors' group in the area of biocatalyst-catalyzed organic reactions in recent 10 years. A strain of Geotrichum sp. obtained by screeninu is capable of stereoselectlvely reducing a number of carbonyl compounds. In many cases, the stermghemistry is complementary with that obtained by baker' s yeast. Therefore, this microorganism provides a useful pathway to the preparation of alcohol eompounds with specific configurations. On the other hand, a nmmber of plant sourees have been screened for oxynitrilases and the hydrocyanation reactions of various arylcarboxalde-hydes have been investigated.A"micro-aqueous reaction system" was invented,by which a serles of novel optically active cyanohydrins were prepared.On this hasis,a high through-put comtimasous reaction system has been designed.This paper also deseribes examples of the syntheses of bio-active compounds by using the optieally active compounds obtained from the above mentioned catalytic reactions as precursors.

  16. Atmospheric Radiation Measurement Climate Research (ARM)

    Federal Laboratory Consortium — With heavily instrumented field sites around the globe, the ARM Climate Research Facility provides the world's most comprehensive outdoor laboratory and data archive...

  17. Cortical Spiking Network Interfaced with Virtual Musculoskeletal Arm and Robotic Arm.

    Dura-Bernal, Salvador; Zhou, Xianlian; Neymotin, Samuel A; Przekwas, Andrzej; Francis, Joseph T; Lytton, William W

    2015-01-01

    Embedding computational models in the physical world is a critical step towards constraining their behavior and building practical applications. Here we aim to drive a realistic musculoskeletal arm model using a biomimetic cortical spiking model, and make a robot arm reproduce the same trajectories in real time. Our cortical model consisted of a 3-layered cortex, composed of several hundred spiking model-neurons, which display physiologically realistic dynamics. We interconnected the cortical model to a two-joint musculoskeletal model of a human arm, with realistic anatomical and biomechanical properties. The virtual arm received muscle excitations from the neuronal model, and fed back proprioceptive information, forming a closed-loop system. The cortical model was trained using spike timing-dependent reinforcement learning to drive the virtual arm in a 2D reaching task. Limb position was used to simultaneously control a robot arm using an improved network interface. Virtual arm muscle activations responded to motoneuron firing rates, with virtual arm muscles lengths encoded via population coding in the proprioceptive population. After training, the virtual arm performed reaching movements which were smoother and more realistic than those obtained using a simplistic arm model. This system provided access to both spiking network properties and to arm biophysical properties, including muscle forces. The use of a musculoskeletal virtual arm and the improved control system allowed the robot arm to perform movements which were smoother than those reported in our previous paper using a simplistic arm. This work provides a novel approach consisting of bidirectionally connecting a cortical model to a realistic virtual arm, and using the system output to drive a robotic arm in real time. Our techniques are applicable to the future development of brain neuroprosthetic control systems, and may enable enhanced brain-machine interfaces with the possibility for finer control of

  18. Cortical spiking network interfaced with virtual musculoskeletal arm and robotic arm

    Salvador eDura-Bernal

    2015-11-01

    Full Text Available Embedding computational models in the physical world is a critical step towards constraining their behavior and building practical applications. Here we aim to drive a realistic musculoskeletal arm model using a biomimetic cortical spiking model, and make a robot arm reproduce the same trajectories in real time. Our cortical model consisted of a 3-layered cortex, composed of several hundred spiking model-neurons, which display physiologically realistic dynamics. We interconnected the cortical model to a two-joint musculoskeletal model of a human arm, with realistic anatomical and biomechanical properties. The virtual arm received muscle excitations from the neuronal model, and fed back proprioceptive information, forming a closed-loop system. The cortical model was trained using spike timing-dependent reinforcement learning to drive the virtual arm in a 2D reaching task. Limb position was used to simultaneously control a robot arm using an improved network interface. Virtual arm muscle activations responded to motoneuron firing rates, with virtual arm muscles lengths encoded via population coding in the proprioceptive population. After training, the virtual arm performed reaching movements which were smoother and more realistic than those obtained using a simplistic arm model. This system provided access to both spiking network properties and to arm biophysical properties, including muscle forces. The use of a musculoskeletal virtual arm and the improved control system allowed the robot arm to perform movements which were smoother than those reported in our previous paper using a simplistic arm.This work provides a novel approach consisting of bidirectionally connecting a cortical model to a realistic virtual arm, and using the system output to drive a robotic arm in real time. Our techniques are applicable to the future development of brain neuro-prosthetic control systems, and may enable enhanced brain-machine interfaces with the possibility

  19. ICRESH-ARMS 2015 Conference

    Ahmadi, Alireza; Verma, Ajit; Varde, Prabhakar

    2016-01-01

    Containing selected papers from the ICRESH-ARMS 2015 conference in Lulea, Sweden, collected by editors with years of experiences in Reliability and maintenance modeling, risk assessment, and asset management, this work maximizes reader insights into the current trends in Reliability, Availability, Maintainability and Safety (RAMS) and Risk Management. Featuring a comprehensive analysis of the significance of the role of RAMS and Risk Management in the decision making process during the various phases of design, operation, maintenance, asset management and productivity in Industrial domains, these proceedings discuss key issues and challenges in the operation, maintenance and risk management of complex engineering systems and will serve as a valuable resource for those in the field.

  20. Arms Control and Strategic Stability

    Hu; Yumin

    2014-01-01

    This essay intends to offer a comment on concepts, trends and attitudes concerning arms control and strategic stability with reference to the current international security situation. It also offers observations from two different perspectives about strategic stability: one proceeds from the concept of universal security and aims to prevent conflicts and instability from disrupting regional and international security environment on which nation states depend so much for their peaceful development; the other starts from maintaining the global leadership by a super power and aiming to contain any challenge that sways or is likely to sway its dominating status. If China and the United States commit themselves to the undertaking of a new type of major powers relationship that stresses win-win cooperation, they will be able to contribute greatly to a stable international security architecture that is good for world peaceful development.

  1. Synthese de champs sonores adaptative

    Gauthier, Philippe-Aubert

    La reproduction de champs acoustiques est une approche physique au probleme technologique de la spatialisation sonore. Cette these concerne l'aspect physique de la reproduction de champs acoustiques. L'objectif principal est l'amelioration de la reproduction de champs acoustiques par "synthese de champs acoustiques" ("Wave Field Synthesis", WFS), une approche connue, basee sur des hypotheses de champ libre, a l'aide du controle actif par l'ajout de capteurs de l'erreur de reproduction et d'une boucle fermee. Un premier chapitre technique (chapitre 4) expose les resultats d'appreciation objective de la WFS par simulations et mesures experimentales. L'effet indesirable de la salle de reproduction sur les qualites objectives de la WFS fut illustre. Une premiere question de recherche fut ensuite abordee (chapitre 5), a savoir s'il est possible de reproduire des champs progressifs en salle dans un paradigme physique de controle actif: cette possibilite fut prouvee. L'approche technique privilegiee, "synthese de champs adaptative" ("Adaptive Wave Field Synthesis" [AWFS]), fut definie, puis simulee (chapitre 6). Cette approche d'AWFS comporte une originalite en controle actif et en reproduction de champs acoustiques: la fonction cout quadratique representant la minimisation des erreurs de reproduction inclut une regularisation de Tikhonov avec solution a priori qui vient de la WFS. L'etude de l'AWFS a l'aide de la decomposition en valeurs singulieres (chapitre 7) a permis de comprendre les mecanismes propres a l'AWFS. C'est la deuxieme principale originalite de la these. L'algorithme FXLMS (LMS et reference filtree) est modifie pour l'AWFS (chapitre 8). Le decouplage du systeme par decomposition en valeurs singulieres est illustre dans le domaine du traitement de signal et l'AWFS basee sur le controle independant des modes de rayonnement est simulee (chapitre 8). Ce qui constitue la troisieme originalite principale de cette these. Ces simulations du traitement de signal

  2. Sensory-Feedback Exoskeletal Arm Controller

    An, Bin; Massie, Thomas H.; Vayner, Vladimir

    2004-01-01

    An electromechanical exoskeletal arm apparatus has been designed for use in controlling a remote robotic manipulator arm. The apparatus, called a force-feedback exoskeleton arm master (F-EAM) is comfortable to wear and easy to don and doff. It provides control signals from the wearer s arm to a robot arm or a computer simulator (e.g., a virtual-reality system); it also provides force and torque feedback from sensors on the robot arm or from the computer simulator to the wearer s arm. The F-EAM enables the wearer to make the robot arm gently touch objects and finely manipulate them without exerting excessive forces. The F-EAM features a lightweight design in which the motors and gear heads that generate force and torque feedback are made smaller than they ordinarily would be: this is achieved by driving the motors to power levels greater than would ordinarily be used in order to obtain higher torques, and by providing active liquid cooling of the motors to prevent overheating at the high drive levels. The F-EAM (see figure) includes an assembly that resembles a backpack and is worn like a backpack, plus an exoskeletal arm mechanism. The FEAM has five degrees of freedom (DOFs) that correspond to those of the human arm: 1. The first DOF is that of the side-to-side rotation of the upper arm about the shoulder (rotation about axis 1). The reflected torque for this DOF is provided by motor 1 via drum 1 and a planar four-bar linkage. 2. The second DOF is that of the up-and-down rotation of the arm about the shoulder. The reflected torque for this DOF is provided by motor 2 via drum 2. 3. The third DOF is that of twisting of the upper arm about its longitudinal axis. This DOF is implemented in a cable remote-center mechanism (CRCM). The reflected torque for this DOF is provided by motor 3, which drives the upper-arm cuff and the mechanism below it. A bladder inflatable by gas or liquid is placed between the cuff and the wearer s upper arm to compensate for misalignment

  3. FUNCTIONAL POLYHYDROXYALKANOATES SYNTHESIZED BY MICROORGANISMS

    Guo-qiang Chen; Qiong Wu; Kai Zhao; Peter H.Yu

    2000-01-01

    Many bacteria have been found to synthesize a family of polyesters termed polyhydroxyalkanoate, abbreviated as PHA. Some interesting physical properties of PHAs such as piezoelectricity, non-linear optical activity, biocompatibility and biodegradability offer promising applications in areas such as degradable packaging, tissue engineering and drug delivery.Over 90 PHAs with various structure variations have been reported and the number is still increasing. The mechanical property of PHAs changes from brittle to flexible to elastic, depending on the side-chainlength of PHA. Many attempts have been made to produce PHAs as biodegradable plastics using various microorganisms obtained from screening natural environments, genetic engineering and mutation. Due to the high production cost, PHAs still can not compete with the nondegradable plastics, such as polyethylene and polypropylene. Various processes have been developed using low cost raw materials for fermentation and an inorganic extraction process for PHA purification. However, a super PHA production strain may play the most critical role for any large-scale PHA production. Our recent study showed that PHA synthesis is a common phenomenon among bacteria inhabiting various locations, especially oil-contaminated soils. This is very important for finding a suitable bacterial strain for PHA production. In fact, PHA production strains capable of rapid growth and rapid PHA synthesis on cheap molasses substrate have been found on molasses contaminated soils. A combination of novel properties and lower cost will allow easier commercialization of PHA for many applications.

  4. Books in Action: The Armed Services Editions.

    Cole, John Y., Ed.

    In an effort to reach a wide audience, the Center for the Book in the Library of Congress presents this book in honor of the 40th anniversary celebration of the Armed Services Editions (ASE), the paperback books distributed during World War II. The titles of the essays and their authors are as follows: "The Armed Services Editions: An…

  5. Gender Integration and the Swedish Armed Forces

    Gustafsson, Daniel Marcus Sunil

    This paper discusses different gender aspects of the Swedish Armed Forces with specific references to sexual harassment and prostitution. By using the concept of Hegemonic Masculinity, sexual harassment of the women in the Swedish Armed Forces is explained in terms of a need of the men within...

  6. Homosexuality in the Dutch Armed Forces 2006

    Anna Adolfsen; Saskia Keuzenkamp; m.m.v. Linda Mans

    2006-01-01

    Original title: Uniform uit de kast. This study looks at the attitudes of defence personnel to homosexuality. How do members of the military view homosexual colleagues? Can gays and lesbians working in the armed forces be open about their sexual preferences? Do they regard the armed forces as a gay

  7. Why we cannot grow a human arm.

    Ricci, John L

    2013-11-01

    There are several significant issues that prevent us from growing a human arm now, or within the next 10-20 years. From a tissue engineering perspective, while we can grow many of the components necessary for construction of a human arm, we can only grow them in relatively small volumes, and when scaled up to large volumes we lack the ability to develop adequate blood/nerve supply. From a genetic engineering perspective, we will probably never be able to turn on the specific genes necessary to "grow an arm" unless it is attached to a fetus and this presents enormous ethical issues related to farming of human organs and structures. Perhaps the most daunting problem facing the transplantation of a tissue engineered or transplanted arm is that of re-innervation of the structure. Since the sensory and motor nerve cells of the arm are located outside of the structure, re-innervation requires those nerves to regenerate over relatively large distances to repopulate the nervous system of the arm. This is something with which we have had little success. We can grow repair parts, but "growing an arm" presents too many insurmountable problems. The best we could possibly do with tissue engineering or genetic engineering would be the equivalent of a fetal arm and the technical problems, costs, and ethical hurdles are enormous. A more likely solution is a functional, permanent, neuroelectronically-controlled prosthesis. These are nearly a reality today.

  8. Design of a biomimetic robotic octopus arm

    Laschi, C; Cianchetti, M [Advanced Robotics Technology and Systems Laboratory, Scuola Superiore Sant' Anna, Pisa (Italy); Mazzolai, B; Dario, P [Italian Institute of Technology, Genova (Italy); Mattoli, V [Centre of Research in Microengineering Laboratory, Scuola Superiore Sant' Anna, Pisa (Italy)], E-mail: cecilia.laschi@sssup.it

    2009-03-01

    This paper reports the rationale and design of a robotic arm, as inspired by an octopus arm. The octopus arm shows peculiar features, such as the ability to bend in all directions, to produce fast elongations, and to vary its stiffness. The octopus achieves these unique motor skills, thanks to its peculiar muscular structure, named muscular hydrostat. Different muscles arranged on orthogonal planes generate an antagonistic action on each other in the muscular hydrostat, which does not change its volume during muscle contractions, and allow bending and elongation of the arm and stiffness variation. By drawing inspiration from natural skills of octopus, and by analysing the geometry and mechanics of the muscular structure of its arm, we propose the design of a robot arm consisting of an artificial muscular hydrostat structure, which is completely soft and compliant, but also able to stiffen. In this paper, we discuss the design criteria of the robotic arm and how this design and the special arrangement of its muscular structure may bring the building of a robotic arm into being, by showing the results obtained by mathematical models and prototypical mock-ups.

  9. Iron Complexes Bearing Diphosphine Ligands with Positioned Pendant Amines as Electrocatalysts for the Oxidation of H2

    Liu, Tianbiao L.; Liao, Qian; O' Hagan, Molly J.; Hulley, Elliott; DuBois, Daniel L.; Bullock, R. Morris

    2015-06-22

    The synthesis and spectroscopic characterization of CpC5F4NFe(PtBu2NBn2)Cl, [3-Cl] (where C5F4N is the tetrafluorpyridyl substituent and PtBu2NBn2 = 1,5-di(tert-butyl)-3,7-di(benzyl)-1,5-diaza-3,7-diphosphacyclooctane) are reported. Complex 3-Cl and previously reported [CpC5F4NFe(PtBu2NtBu2)Cl], 4-Cl, are precursors to intermediates in the catalytic oxidation of H2, including CpC5F4NFe(PtBu2NBn2)H (3-H), CpC5F4NFe(PtBu2NtBu2)H (4-H), [CpC5F4NFe(PtBu2NBn2)]BArF4 ([3](BArF4), [CpC5F4NFe(PtBu2NtBu2)]BArF4 ([4](BArF4), [CpC5F4NFe(PtBu2NBn2)(H2)]BArF4 ([3-H2]BArF4), and [CpC5F4NFe(PtBu2NtBu2H)H]BArF4 ([4-FeH(NH)]BArF4). All of these complexes were characterized by spectroscopic and electrochemical studies; 3-Cl, 3-H and 4-Cl were also characterized by single crystal diffraction studies. 3-H and 4-H are electrocatalysts for H2 (1.0 atm) oxidation in the presence of a excess of the amine base N-methylpyrrolidine, with turnover frequencies at 22 °C of 2.5 s-1 and 0.5 s-1, and overpotentials at Ecat/2 of 235 mV and 95 mV, respectively. Studies of individual chemical and/or electrochemical reactions of the various intermediates provide important insights into the factors governing the overall catalytic activity for H2 oxidation, and provide important insights into the role of the pendant base of the [FeFe] hydrogenase active site. This work was supported by the Center for Molecular Electrocatalysis, an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences. Pacific Northwest National Laboratory is operated by Battelle for the U.S. Department of Energy.

  10. Design And Implementation Of Anthropomorphic Robotic Arm

    Ashish Sharma

    2014-01-01

    Full Text Available The report focuses on the design and demonstration of an anthropomorphic robotic arm with seven degrees of freedom using readily available low-cost components to perform different real time human hand applications. The robotic arm consists of a shoulder, elbow, wrist and a five-finger gripper. It can perform different gripping actions, such as lateral, spherical, cylindrical and tip-holding gripping actions; each finger has three movable links. The actuator used for the robotic arm is a high torque dc servo motor and the five-finger gripper consists of five cables placed like tendons in the human arm. Implementation is done using a human hand glove which senses the motion from sensor technology to produce a proportional analog voltage, digitized via the microcontroller Atmel ATmega32. The microcontroller then through the processed signal controls the mechanical structure that is the robotic arm. Keywords –

  11. Synthesis, Characterization, and Polymerization of New Ferrocene- Fluorene Complexes. A Novel High-Molecular Weight Conjugated Polymer with Pendant Ferrocene Groups

    1992-01-01

    similar to copolymer 4. Cyclic voltametry of complex 5 shows two reversible oxidation events, one at +0.11 V (two-electron event) and another at +0.71 V...unlimited9 a S two oxidation events, one at +0.11 V and the other at +0.71 V (relative to the ferrocene/ferrocenium couple). Cyclic voltammetry of...thermal and cyclic voltammetry behavior. To our knowledge, this is the first conjugated organic polymer backbone to possess pendant ferrocene moieties

  12. Le discours sur «l'étranger» pendant la Terreur, 5 nivôse - 9 thermidor an II

    Sophie WAHNICH

    1995-06-01

    Full Text Available La cartographie des occurrences discursives émises par les différents producteurs d’opinion publique pendant la Révolution française permet de saisir les formes et les déterminations du discours tenu sur l’étranger du 5 nivôse au 9 thermidor an II. On constate alors que ce discours peut obéir soit à des logiques de voisinage guerrier soit à des logiques politiques.

  13. CyARM: Haptic Sensing Device for Spatial Localization on Basis of Exploration by Arms

    Junichi Akita

    2009-01-01

    Full Text Available We introduce a new type of perception aid device based on user's exploration action, which is named as CyARM (acronym of “Cyber Arm”. The user holds this device in her/his arm, the extension of the arm is controlled by tension in wires, which are attached to her/his body according to the distance to the object. This user interface has unique characteristics that give users the illusion of an imaginary arm that extends to existing objects. The implementations of CyARM and our two experiments to investigate the efficiency and effectiveness of CyARM are described. The results show that we could confirm that CyARM can be used to recognize the presence of an object in front of the user and to measure the relative distance to the object.

  14. Photochemical activation of ruthenium(II)-pyridylamine complexes having a pyridine-N-oxide pendant toward oxygenation of organic substrates.

    Kojima, Takahiko; Nakayama, Kazuya; Sakaguchi, Miyuki; Ogura, Takashi; Ohkubo, Kei; Fukuzumi, Shunichi

    2011-11-09

    Ruthenium(II)-acetonitrile complexes having η(3)-tris(2-pyridylmethyl)amine (TPA) with an uncoordinated pyridine ring and diimine such as 2,2'-bipyridine (bpy) and 2,2'-bipyrimidine (bpm), [Ru(II)(η(3)-TPA)(diimine)(CH(3)CN)](2+), reacted with m-chloroperbenzoic acid to afford corresponding Ru(II)-acetonitrile complexes having an uncoordinated pyridine-N-oxide arm, [Ru(II)(η(3)-TPA-O)(diimine)(CH(3)CN)](2+), with retention of the coordination environment. Photoirradiation of the acetonitrile complexes having diimine and the η(3)-TPA with the uncoordinated pyridine-N-oxide arm afforded a mixture of [Ru(II)(TPA)(diimine)](2+), intermediate-spin (S = 1) Ru(IV)-oxo complex with uncoordinated pyridine arm, and intermediate-spin Ru(IV)-oxo complex with uncoordinated pyridine-N-oxide arm. A Ru(II) complex bearing an oxygen-bound pyridine-N-oxide as a ligand and bpm as a diimine ligand was also obtained, and its crystal structure was determined by X-ray crystallography. Femtosecond laser flash photolysis of the isolated O-coordinated Ru(II)-pyridine-N-oxide complex has been investigated to reveal the photodynamics. The Ru(IV)-oxo complex with an uncoordinated pyridine moiety was alternatively prepared by reaction of the corresponding acetonitrile complex with 2,6-dichloropyridine-N-oxide (Cl(2)py-O) to identify the Ru(IV)-oxo species. The formation of Ru(IV)-oxo complexes was concluded to proceed via intermolecular oxygen atom transfer from the uncoordinated pyridine-N-oxide to a Ru(II) center on the basis of the results of the reaction with Cl(2)py-O and the concentration dependence of the consumption of the starting Ru(II) complexes having the uncoordinated pyridine-N-oxide moiety. Oxygenation reactions of organic substrates by [Ru(II)(η(3)-TPA-O)(diimine)(CH(3)CN)](2+) were examined under irradiation (at 420 ± 5 nm) and showed selective allylic oxygenation of cyclohexene to give cyclohexen-1-ol and cyclohexen-1-one and cumene oxygenation to afford cumyl alcohol

  15. 含芳酯侧基聚芳醚酮的合成与性能%SYNTHESIS AND PROPERTIES OF POLY(ARYL ETHER KETONE) S CONTAINING PENDANT ARYL ESTER GROUPS

    宋琤; 余雯雯; 钟鸣; 祝志芳; 易志群; 宋才生

    2011-01-01

    以偏苯三甲酸酐酰氯(TMAc),对苯二甲酰氯(TPC),1,4-二(4-苯氧基苯甲酰基)苯(p-EKKE)为单体,采用亲电溶液共缩聚,通过改变TMAc、TPC的摩尔比,制备了系列含羧基侧基的聚芳醚酮树脂(PEK-A).在对甲苯磺酸催化下与苯酚进行酯化反应合成了系列主链带芳酯侧基的聚芳醚酮树脂(PEK-COO-Ar).用红外光谱(FTIR),广角X射线衍射(WAXD),热失重(TGA),示差量热扫描(DSC)等技术对聚合物的结构和性能进行表征,考察了聚合物的溶解性能.结果表明,随着主链中芳酯侧基比例的增加,聚合物的Tg提高(195~219℃),而Tm降低.当TPC/TMAc摩尔比小于1∶1时,树脂呈非晶态结构.当TPC/TMAc摩尔比为50/50和60/40时,树脂经等温结晶后,具有优良的机械力学性能.%A series of novel poly (aryl ether ketone)s containing pendant aryl ester groups (PEK-COO-Ar)were prepared from poly( aryl ether ketone)s containing pendant carboxyl acid groups (PEK-A) and phenol in the presence of 1,1,2,2-tetrachloroethane and by using p-toluenesulfonic acid as a catalyst. The PEK-A was synthesized from trimellitic anhydride chloride ( TMAc ), terephthaloyl chloride ( TPC ) and 1,4-bis ( 4-phenoxybenzoyl) benzene (p-EKKE) by low temperature solution poly-condensation. By changing the molar ratio of TMAc and TPC a series of PEK-A polymers were prepared. The PEK-COO-Ars were characterized by Fourier transform infrared spectroscopy ( FTIR ) , wide-angle X-ray diffraction ( WAXD ) , thermal gravimetric analysis (TGA) and differential scanning calorimetry (DSC). The results showed that the glass transition temperature (Ts ) of the PEK-COO-Ar was in the range of 195 ~ 219℃ and the decomposition temperature (Td) at 5% weight loss was from 416℃ to 447℃ and the melting temperature (Tm) was between 325℃ and 345℃. The Ts of the PEK-COO-Ar increased by increasing the mole ratio of aryl ester groups in the polymer,while the Td deceased. The polymers were readily

  16. Quantification of branching in model three-arm star polyethylene

    Ramachandran, Ramnath

    2012-01-24

    The versatility of a novel scaling approach in quantifying the structure of model well-defined 3-arm star polyethylene molecules is presented. Many commercial polyethylenes have long side branches, and the nature and quantity of these branches varies widely among the various forms. For instance, low-density polyethylene (LDPE) is typically a highly branched structure with broad distributions in branch content, branch lengths and branch generation (in hyperbranched structures). This makes it difficult to accurately quantify the structure and the inherent structure-property relationships. To overcome this drawback, model well-defined hydrogenated polybutadiene (HPB) structures have been synthesized via anionic polymerization and hydrogenation to serve as model analogues to long-chain branched polyethylene. In this article, model 3-arm star polyethylene molecules are quantified using the scaling approach. Along with the long-chain branch content in polyethylene, the approach also provides unique measurements of long-chain branch length and hyperbranch content. Such detailed description facilitates better understanding of the effect of branching on the physical properties of polyethylene. © 2012 American Chemical Society.

  17. Assistant template and co-template agents in modeling mesoporous silicas and post-synthesizing organofunctionalizations

    Oliveira, Vaeudo V.; Airoldi, Claudio

    2012-12-01

    Mesoporous SBA-16 silicas were synthesized through a direct methodology using the template (F127) combined with co-templates (ethanol and n-butanol), with tetraethylorthosilicate as the silica source. These ordered mesoporous silica were characterized by elemental analyses, infrared spectroscopy, solid-state nuclear magnetic resonance for 13C (CP/MAS) and 29Si (HP/DEC) nuclei, nitrogen sorption/desorption processes, small angle X-ray analyses (SAXS) and transmission electron microscopy (TEM). SAXS and TEM results confirmed the space group Im3m and cubic 3D symmetry, typical for highly ordered SBA-16. The sorption/desorption data for SBA-16 and when functionalized gave type IV isotherms, with hysteresis loop H2. Surface areas of 836; 657 and 618 m2 g-1 and average pore diameters of 7.99; 8.10 and 9.85 nm, for SBA-16A, SBA-16B and SBA-16C were obtained, respectively. When functionalized the silicas presented a reduction in surface area, pore volume and pore diameter due to the pendant chains that interfere with nitrogen sorption in these measurements. The co-template ethanol favors the ordered mesopores with highest wall thicknesses.

  18. The arms race between fishers

    Rijnsdorp, Adriaan D.; Poos, Jan Jaap; Quirijns, Floor J.; HilleRisLambers, Reinier; De Wilde, Jan W.; Den Heijer, Willem M.

    An analysis of the changes in the Dutch demersal fishing fleet since the 1950s revealed that competitive interactions among vessels and gear types within the constraints imposed by biological, economic and fisheries management factors are the dominant processes governing the dynamics of fishing fleets. Double beam trawling, introduced in the early 1960s, proved a successful fishing method to catch deep burying flatfish, in particular sole. In less than 10 years, the otter trawl fleet was replaced by a highly specialised beam trawling fleet, despite an initial doubling of the loss rate of vessels due to stability problems. Engine power, size of the beam trawl, number of tickler chains and fishing speed rapidly increased and fishing activities expanded into previously lightly fished grounds and seasons. Following the ban on flatfish trawling within the 12 nautical mile zone for vessels of more than 300 hp in 1975 and with the restriction of engine power to 2000 hp in 1987, the beam trawl fleet bifurcated. Changes in the fleet capacity were related to the economic results and showed a cyclic pattern with a period of 6-7 years. The arms race between fishers was fuelled by competitive interactions among fishers: while the catchability of the fleet more than doubled in the ten years following the introduction of the beam trawl, a decline in catchability was observed in reference beam trawlers that remained the same. Vessel performance was not only affected by the technological characteristics but also by the number and characteristics of competing vessels.

  19. Youth Armed Groups in Colombia

    Linda Dale

    2014-09-01

    Full Text Available For the many years of Colombia’s civil war, youth have been trying to find their way in complicated and dangerous situations. A central component of this is their relationship with armed groups, something that has evolved considerably over the past ten years. This practice note examines the context within which these connections are formed and the implications this has for self/social identity and meaningful resistance. The ideas in this practice note are based on consultations with young Colombians, particularly those displaced from 2000-2013. These sessions included art activities, focus groups and individual interviews. Art activities involved descriptive and expressive projects so that participants could explore their feelings and memories of situations and experiences. This provided a base for group discussions where youth exchanged information and debated issues. A total of 34 workshops were held over a twelve year period. These consultations revealed how war flows all over young people, touching every aspect of their identity. The boundaries between the personal and political no longer exist in today’s civil wars, if indeed they every truly did. Young people growing up inside Colombia’s war understand this at a deep level. An acknowledgement of this pain – showing the connections between the personal and political dimensions of war – is, they would maintain, the basis for their personal healing as well as an important tool for the building of sustainable peace.

  20. Unexpectedly Facile Rh(I) Catalyzed Polymerization of Ethynylbenzaldehyde Type Monomers: Synthesis of Polyacetylenes Bearing Reactive and Easy Transformable Pendant Carbaldehyde Groups.

    Sedláček, Jan; Havelková, Lucie; Zedník, Jiří; Coufal, Radek; Faukner, Tomáš; Balcar, Hynek; Brus, Jiří

    2017-02-23

    The chain coordination polymerization of (ethynylarene)carbaldehydes with unprotected carbaldehyde groups, namely ethynylbenzaldehydes, 1-ethynylbenzene-3,5-dicarboxaldehyde, and 3-[(4-ethynylphenyl)ethynyl]benzaldehyde, is reported for the first time. Polymerization is catalyzed with various Rh(I) catalysts and yields poly(arylacetylene)s with one or two pendant carbaldehyde groups per monomeric unit. Surprisingly, the carbaldehyde groups of the monomers do not inhibit the polymerization unlike the carbaldehyde group of unsubstituted benzaldehyde that acts as a strong inhibitor of Rh(I) catalyzed polymerization of arylacetylenes. The inhibition ability of carbaldehyde groups in (ethynylarene)carbaldehydes seems to be eliminated owing to a simultaneous presence of unsaturated ethynyl groups in (ethynylarene)carbaldehydes. The reactive carbaldehyde groups make poly[(ethynylarene)carbaldehyde]s promising for functional appreciation via various postpolymerization modifications. The introduction of photoluminescence or chirality to poly(ethynylbenzaldehyde)s via quantitative modification of their carbaldehyde groups in reaction with either photoluminescent or chiral primary amines under formation of the polymers with Schiff-base-type pendant groups is given as an example.

  1. Bioinspired Design and Computational Prediction of Iron Complexes with Pendant Amines for the Production of Methanol from CO2 and H2.

    Chen, Xiangyang; Yang, Xinzheng

    2016-03-17

    Inspired by the active site structure of [FeFe]-hydrogenase, we built a series of iron dicarbonyl diphosphine complexes with pendant amines and predicted their potentials to catalyze the hydrogenation of CO2 to methanol using density functional theory. Among the proposed iron complexes, [(P(tBu)2N(tBu)2H)FeH(CO)2(COOH)](+) (5COOH) is the most active one with a total free energy barrier of 23.7 kcal/mol. Such a low barrier indicates that 5COOH is a very promising low-cost catalyst for high-efficiency conversion of CO2 and H2 to methanol under mild conditions. For comparison, we also examined Bullock's Cp iron diphosphine complex with pendant amines, [(P(tBu)2N(tBu)2H)FeHCp(C5F4N)](+) (5Cp-C5F4N), as a catalyst for hydrogenation of CO2 to methanol and obtained a total free energy barrier of 27.6 kcal/mol, which indicates that 5Cp-C5F4N could also catalyze the conversion of CO2 and H2 to methanol but has a much lower efficiency than our newly designed iron complexes.

  2. ARM Climate Research Facility Annual Report 2005

    J. Voyles

    2005-12-31

    Through the ARM Program, the DOE funded the development of several highly instrumented ground stations for studying cloud formation processes and their influence on radiative transfer, and for measuring other parameters that determine the radiative properties of the atmosphere. This scientific infrastructure, and resultant data archive, is a valuable national and international asset for advancing scientific knowledge of Earth systems. In fiscal year (FY) 2003, the DOE designated ARM sites as a national scientific user facility: the ARM Climate Research (ACRF). The ACRF has enormous potential to contribute to a wide range interdisciplinary science in areas such as meteorology, atmospheric aerosols, hydrology, biogeochemical cycling, and satellite validation, to name only a few.

  3. MiniSAR composite gimbal arm development.

    Klarer, Paul Richard; Winscott, Mark (Orion International, Albuquerque, NM)

    2005-01-01

    An exploratory effort in the application of carbon epoxy composite structural materials to a multi-axis gimbal arm design is described. An existing design in aluminum was used as a baseline for a functionally equivalent redesigned outer gimbal arm using a carbon epoxy composite material. The existing arm was analyzed using finite element techniques to characterize performance in terms of strength, stiffness, and weight. A new design was virtually prototyped. using the same tools to produce a design with similar stiffness and strength, but reduced overall weight, than the original arm. The new design was prototyped using Rapid Prototyping technology, which was subsequently used to produce molds for fabricating the carbon epoxy composite parts. The design tools, process, and results are discussed.

  4. A Novel Route of Furan Compounds Syntheses

    2002-01-01

    A series of compounds that contained furan skeletons were synthesized using 3,4-bis(trimethylsilyl)furan as staring material. 1H NMR, 13C NMR, MS and EA had identified these new molecules. The important factors that influenced reactions were discussed, and the new furan intermediates could be used in various organic syntheses.

  5. "Comments on Slavin": Synthesizing Causal Inferences

    Briggs, Derek C.

    2008-01-01

    When causal inferences are to be synthesized across multiple studies, efforts to establish the magnitude of a causal effect should be balanced by an effort to evaluate the generalizability of the effect. The evaluation of generalizability depends on two factors that are given little attention in current syntheses: construct validity and external…

  6. Composites comprising biologically-synthesized nanomaterials

    Curran, Seamus; Dias, Sampath; Blau, Werner; Wang, Jun; Oremland, Ronald S; Baesman, Shaun

    2013-04-30

    The present disclosure describes composite materials containing a polymer material and a nanoscale material dispersed in the polymer material. The nanoscale materials may be biologically synthesized, such as tellurium nanorods synthesized by Bacillus selenitireducens. Composite materials of the present disclosure may have optical limiting properties and find use in optical limiting devices.

  7. The long arms of anencephaly: A refutation.

    Barr, Mason

    2009-08-01

    A paper published in 1925 reported that human fetuses with anencephaly have arms that are longer than normal. This finding was accepted as true through the early 1990s. An analysis of body dimensions done in 1996 and enlarged and updated here shows that the arms of human fetuses with anencephaly are appropriate for gestational age and normal in proportion to their leg lengths. A subtle difference in measurement technique was found to explain the discordant findings.

  8. The Geometry of the Galaxy's Spiral Arms

    Steiman-Cameron, Thomas Y.; Wolfire, M.; Hollenbach, D.

    2008-05-01

    We present a new model for the spiral structure of the Milky Way based upon an analysis of the essentially all-sky spectral data obtained by the Far Infrared Absolute Spectrophotometer (FIRAS) instrument of the Cosmic Background Explorer (COBE) satellite. The model provides the volume emissivities of the [C II] 128 µm and [N II] 205 µm lines, as a function of position within the Galaxy. These lines are important coolants of the interstellar medium and strong tracers of the spiral structure. Despite decades of work, there is still no full agreement on the number of spiral arms in the Milky Way, much less the details of their geometry. Motivated, in part, by this fact, we conducted a systematic search for 2-arm, 3-arm, and 4-arm models that maximize agreement with the COBE data. We find that only a four-arm model, with arms defined by logarithmic spiral forms and pitch angles ranging from 13.5 to 15.6 degrees, is consistent with the observations. The arms are neither evenly spaced nor identical in form. The resultant volume emissivity models for C+ and N+, when convolved with the FIRAS beam and integrated over the Galaxy, reproduce the COBE [C II] 128 µm and [N II] 205 µm intensity maps extremely well. We also examine all models for the Galaxy's spiral structure that have been proposed over the past half century in the context of the same COBE observations. A significant fraction of these models, including many recent ones, appear to be incompatible with the data. However, several four-arm models from the literature are consistent with the COBE observations.

  9. Regulation of flexible arms under gravity

    De Luca, A. [Univ. di Roma, Rome (Italy). Dipt. di Informatica e Sistemistica; Siciliano, B. [Univ. di Napoli Federico, Napoli (Italy). Dipt. di Informatica e Sistemistica

    1993-08-01

    A simple controller is presented for the regulation problem of robot arms with flexible links under gravity. It consists of a joint PD feedback plus a constant feedforward. Global asymptotic stability of the reference equilibrium state is shown under a structural assumption about link elasticity and a mild condition on the proportional gain. The result holds also in the absence of internal damping of the flexible arm. A numerical case study is presented.

  10. ARM assembly language with hardware experiments

    Elahi, Ata

    2015-01-01

    This book provides a hands-on approach to learning ARM assembly language with the use of a TI microcontroller. The book starts with an introduction to computer architecture and then discusses number systems and digital logic. The text covers ARM Assembly Language, ARM Cortex Architecture and its components, and Hardware Experiments using TILM3S1968. Written for those interested in learning embedded programming using an ARM Microcontroller. ·         Introduces number systems and signal transmission methods   ·         Reviews logic gates, registers, multiplexers, decoders and memory   ·         Provides an overview and examples of ARM instruction set   ·         Uses using Keil development tools for writing and debugging ARM assembly language Programs   ·         Hardware experiments using a Mbed NXP LPC1768 microcontroller; including General Purpose Input/Output (GPIO) configuration, real time clock configuration, binary input to 7-segment display, creating ...

  11. Arm & Interarm Star Formation in Spiral Galaxies

    Foyle, Kelly; Walter, Fabian; Leroy, Adam

    2010-01-01

    We investigate the relationship between spiral arms and star formation in the grand-design spirals NGC 5194 and NGC 628 and in the flocculent spiral NGC 6946. Filtered maps of near-IR (3.6 micron) emission allow us to identify "arm regions" that should correspond to regions of stellar mass density enhancements. The two grand-design spirals show a clear two-armed structure, while NGC 6946 is more complex. We examine these arm and interarm regions, looking at maps that trace recent star formation - far-ultraviolet (GALEX NGS) and 24 micron emission (Spitzer, SINGS) - and cold gas - CO (Heracles) and HI (Things). We find the star formation tracers and CO more concentrated in the spiral arms than the stellar 3.6 micron flux. If we define the spiral arms as the 25% highest pixels in the filtered 3.6 micron images, we find that the majority (60%) of star formation tracers occurs in the interarm regions; this result persists qualitatively even when considering the potential impact of finite data resolution and diffu...

  12. The how and why of arm swing during human walking.

    Meyns, P.; Bruijn, S.M.; Duysens, J.E.J.

    2013-01-01

    Humans walk bipedally, and thus, it is unclear why they swing their arms. In this paper, we will review the mechanisms and functions of arm swinging in human gait. First, we discuss the potential advantages of having swinging arms. Second, we go into the detail on the debate whether arm swing is ari

  13. 侧氨基聚硅氧烷的合成及其在聚氨酯胶粘剂中的应用%Synthesis of Polydimethylsiloxane Oligomers with Pendant Amine Groups and Its Application in Polyurethane Adhesive

    刘飞; 吴晓青; 艾罡; 王志强; 李伟

    2011-01-01

    By co-equilibration polymerization, polydimethylsiloxane oligomers with pendant amine groups (NH2-PDMS)was synthesized from octamethylcyclote trasiloxane ( D4) and N-β-aminoethyl-γ-aminopropylmethyl-dimethy-oxysilane( HC-500) , using hexamethyldisiloxane ( MM) as end capping agent, CH3CH2OK as catalyst and dimethylsulfoxide ( DMSO) as promoter. The influence of process condition to NH2-PDMS ammonia value was studied. The results showed that when the molar ratio of D4 , HC-550 and MM was 45:3:2, the CH3CH2OK and DMSO dosage were 0. 14% and 1. 0% , the reaction temperature was 120 ℃ and the reaction time was 6 h, the ammonia value of synthetical NH2-PDMS was 1. 0 mmol/g. The polyurethane adhesive modified by the NH2-PDMS had good comprehensive properties, lower water absorption rate, higher water resistence and salt tolerance.%以八甲基环四硅氧烷(D4)和N-β-氨乙基-γ-氨丙基甲基二甲氧基硅烷(HC-550)为原料,六甲基二硅氧烷(MM)为封端剂,乙醇钾为催化剂,通过共平衡聚合反应,合成了侧氨基聚硅氧烷 (NH2-PDMS),研究了合成条件对NH2-PDMS胺值的影响.结果表明,当D4、HC-550和MM的摩尔比为45:3:2、乙醇钾和二甲基亚砜的质量分数分别为0.14%和1.0%、反应温度为120℃、反应时间6h时,合成的NH2-PDMS胺值约为1.0 mmol/g.将NH2-PDMS用于改性聚氯酯胶粘剂时,其综合性能较好.

  14. SYNTHESIZED EXPECTED BAYESIAN METHOD OF PARAMETRIC ESTIMATE

    Ming HAN; Yuanyao DING

    2004-01-01

    This paper develops a new method of parametric estimate, which is named as "synthesized expected Bayesian method". When samples of products are tested and no failure events occur, thedefinition of expected Bayesian estimate is introduced and the estimates of failure probability and failure rate are provided. After some failure information is introduced by making an extra-test, a synthesized expected Bayesian method is defined and used to estimate failure probability, failure rateand some other parameters in exponential distribution and Weibull distribution of populations. Finally,calculations are performed according to practical problems, which show that the synthesized expected Bayesian method is feasible and easy to operate.

  15. Thermoresponsive Poly(2-oxazoline) Molecular Brushes by Living Ionic Polymerization: Kinetic Investigations of Pendant Chain Grafting and Cloud Point Modulation by Backbone and Side Chain Length Variation

    Zhang, Ning

    2012-04-17

    Molecular brushes of poly(2-oxazoline)s were prepared by living anionic polymerization of 2-iso-propenyl-2-oxazoline to form the backbone and subsequent living cationic ring-opening polymerization of 2-n- or 2-iso-propyl-2-oxazoline for pendant chain grafting. In situ kinetic studies indicate that the initiation efficiency and polymerization rates are independent from the number of initiator functions per initiator molecule. This was attributed to the high efficiency of oxazolinium salt and the stretched conformation of the backbone, which is caused by the electrostatic repulsion of the oxazolinium moieties along the macroinitiator. The resulting molecular brushes showed thermoresponsive properties, that is, having a defined cloud point (CP). The dependence of the CP as a function of backbone and side chain length as well as concentration was studied. © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. ARM Airborne Carbon Measurements (ARM-ACME) and ARM-ACME 2.5 Final Campaign Reports

    Biraud, S. C. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Tom, M. S. [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Sweeney, C. [NOAA Earth Systems Research Lab., Boulder, CO (United States)

    2016-01-01

    We report on a 5-year multi-institution and multi-agency airborne study of atmospheric composition and carbon cycling at the Atmospheric Radiation Measurement (ARM) Climate Research Facility’s Southern Great Plains (SGP) site, with scientific objectives that are central to the carbon-cycle and radiative-forcing goals of the U.S. Global Change Research Program and the North American Carbon Program (NACP). The goal of these measurements is to improve understanding of 1) the carbon exchange of the Atmospheric Radiation Measurement (ARM) SGP region; 2) how CO2 and associated water and energy fluxes influence radiative-forcing, convective processes, and CO2 concentrations over the ARM SGP region, and 3) how greenhouse gases are transported on continental scales.

  17. Notitie over vangsten en discards van de pulsvisserij van de ARM25 / ARM33 / TH6

    Rasenberg, M.M.M.

    2014-01-01

    In 2011 en 2012 zijn Vof Zeevisserijbedrijf C. Caljouw en Zn. (ARM25), Visserijbedrijf Van Belzen vof (ARM33) en Zeevisserijbedrijf Johanna Cornelia K.J. Bout en Zn. cv. (TH6) overgeschakeld naar de pulsvisserij. De drie chepen hebben deelgenomen aan de pulskormonitoring en in dit onderzoek gegevens

  18. Spiral arms as cosmic ray source distributions

    Werner, M.; Kissmann, R.; Strong, A. W.; Reimer, O.

    2015-04-01

    The Milky Way is a spiral galaxy with (or without) a bar-like central structure. There is evidence that the distribution of suspected cosmic ray sources, such as supernova remnants, are associated with the spiral arm structure of galaxies. It is yet not clearly understood what effect such a cosmic ray source distribution has on the particle transport in our Galaxy. We investigate and measure how the propagation of Galactic cosmic rays is affected by a cosmic ray source distribution associated with spiral arm structures. We use the PICARD code to perform high-resolution 3D simulations of electrons and protons in galactic propagation scenarios that include four-arm and two-arm logarithmic spiral cosmic ray source distributions with and without a central bar structure as well as the spiral arm configuration of the NE2001 model for the distribution of free electrons in the Milky Way. Results of these simulation are compared to an axisymmetric radial source distribution. Also, effects on the cosmic ray flux and spectra due to different positions of the Earth relative to the spiral structure are studied. We find that high energy electrons are strongly confined to their sources and the obtained spectra largely depend on the Earth's position relative to the spiral arms. Similar finding have been obtained for low energy protons and electrons albeit at smaller magnitude. We find that even fractional contributions of a spiral arm component to the total cosmic ray source distribution influences the spectra on the Earth. This is apparent when compared to an axisymmetric radial source distribution as well as with respect to the Earth's position relative to the spiral arm structure. We demonstrate that the presence of a Galactic bar manifests itself as an overall excess of low energy electrons at the Earth. Using a spiral arm geometry as a cosmic ray source distributions offers a genuine new quality of modeling and is used to explain features in cosmic ray spectra at the Earth

  19. Spiral Arms as Cosmic Ray Source Distributions

    Werner, M; Strong, A W; Reimer, O

    2014-01-01

    There is evidence that the distribution of suspected cosmic ray sources are associated with the spiral arm structure of galaxies. It is yet not clearly understood what effect such a cosmic ray source distribution has on the particle transport in our Galaxy. We use the PICARD code to perform high-resolution 3D simulations of electrons and protons in galactic propagation scenarios that include four-arm and two-arm logarithmic spiral cosmic ray source distributions with and without a central bar structure as well as the spiral arm configuration of the NE2001 model for the distribution of free electrons in the Milky Way. Results of these simulation are compared to an axisymmetric radial source distribution. Also, effects on the cosmic ray flux and spectra due to different positions of the Earth relative to the spiral structure are studied. We find that high energy electrons are strongly confined to their sources and the obtained spectra largely depend on the Earth's position relative to the spiral arms. Similar f...

  20. SYNTHESES AND PROPERTIES OF POLYMERIZABLE METALLOPHTHALOCYANINE DERIVATIVES

    LIU Yunqi; YAMADA Akira; SHIGEHARA Kiyotaka; HARA Masahiko

    1988-01-01

    Metallophthalocyanine derivatives with polymerizable vinyl groups were synthesized, characterized and polymerized. Preliminary results on their Langmuir-Blodgett (LB) film formation and the electronic properties of (Indium-Tin Oxide/LB-film/Al) Schottky devices were reported.

  1. The Trajectory Synthesizer Generalized Profile Interface

    Lee, Alan G.; Bouyssounouse, Xavier; Murphy, James R.

    2010-01-01

    The Trajectory Synthesizer is a software program that generates aircraft predictions for Air Traffic Management decision support tools. The Trajectory Synthesizer being used by researchers at NASA Ames Research Center was restricted in the number of trajectory types that could be generated. This limitation was not sufficient to support the rapidly changing Air Traffic Management research requirements. The Generalized Profile Interface was developed to address this issue. It provides a flexible approach to describe the constraints applied to trajectory generation and may provide a method for interoperability between trajectory generators. It also supports the request and generation of new types of trajectory profiles not possible with the previous interface to the Trajectory Synthesizer. Other enhancements allow the Trajectory Synthesizer to meet the current and future needs of Air Traffic Management research.

  2. A universal isocyanide for diverse heterocycle syntheses

    Patil, Pravin; Dömling, Alexander; Khoury, Kareem; Herdtweck, Eberhardt

    2014-01-01

    Novel scaffolds are of uttermost importance for the discovery of functional material. Three different heterocyclic scaffolds easily accessible from isocyanoacetaldehyde dimethylacetal 1 by multicomponent reaction (MCR) are described. They can be efficiently synthesized by a Ugi tetrazole multicompon

  3. Progress in synthesizing functional nano materials

    2006-01-01

    @@ With the consistent investment, the research team directed by Prof. Yadong Li of Chemistry Department of Tsinghua University achieved new progress in synthesizing nano materials with specific functions. The research team led by Prof.

  4. Method to synthesize metal chalcogenide monolayer nanomaterials

    Hernandez-Sanchez, Bernadette A.; Boyle, Timothy J.

    2016-12-13

    Metal chalcogenide monolayer nanomaterials can be synthesized from metal alkoxide precursors by solution precipitation or solvothermal processing. The synthesis routes are more scalable, less complex and easier to implement than other synthesis routes.

  5. Raman assisted lightwave synthesized frequency sweeper

    Pedersen, Anders Tegtmeier; Rottwitt, Karsten

    2010-01-01

    We present a Lightwave Synthesized Frequency Sweeper comprising a Raman amplifier for loss compensation. The generated pulse train contains 123 pulses and has a flat signal level as well as a low noise level.......We present a Lightwave Synthesized Frequency Sweeper comprising a Raman amplifier for loss compensation. The generated pulse train contains 123 pulses and has a flat signal level as well as a low noise level....

  6. Complexation of Bi{sup 3+}, Ac{sup 3+}, Y{sup 3+}, Lu{sup 3+}, La{sup 3+} and Eu{sup 3+} with benzo-diaza-crown ether with carboxylic pendant arms

    Egorova, Bayirta V. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Chemistry Dept.; Oshchepkov, Maxim S.; Fedorova, Olga A. [Mendeleev University of Chemistry and Technology of Russia, Moscow (Russian Federation); Russian Academy of Sciences, Moscow (Russian Federation). A.N. Nesmeyanov Institute of Organoelement Compounds; Fedorov, Yury V. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Chemistry Dept.; Russian Academy of Sciences, Moscow (Russian Federation). A.N. Nesmeyanov Institute of Organoelement Compounds; Budylin, Gleb S.; Shirshin, Evgeny A. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Dept. of Physics; Kalmykov, Stepan N. [Lomonosov Moscow State Univ., Moscow (Russian Federation). Chemistry Dept.; National Research Center ' Kurchatov Institute' , Moscow (Russian Federation)

    2016-11-01

    Polyaminopolycarboxylates are attractive ligands for binding cationic radionuclides for synthesis of radiopharmaceuticals with target delivery to tumor cells. Nowadays beta emitting Y-90 and Lu-177 are used as therapeutic agents, while Ac-225 and Bi-213 are considered as perspective for alpha therapy. In the present study new data on complexation of Y{sup 3+}, Lu{sup 3+}, Ac{sup 3+} and Bi{sup 3+} with 2,2'-(15-formyl-2,3,5,6,8,9,11,12-octahydrobenzo [b][1,4,10,7,13]trioxadiazacyclopentadecine-4,10- diyl)diacetic acid are presented. For ligand and complexes characterization potentiometric titration, solvent extraction, chromatography and solubility techniques were applied. The highest values of stability constants within the range of log K = 5.8 - 7.5 were found for Ac{sup 3+} and REE. Fast complex formation is established which is beneficial for practical applications in radiopharmaceutical synthesis.

  7. Traumatisme, réinsertion psychosociale et résilience chez des femmes victimes de viol pendant les conflits armés en Côte d’Ivoire

    Opadou Koudou

    2016-04-01

    From the perspective of data analysis, we used the phenomenological analysis. This showed the psychological, physical and socio-economic women who have suffered sexual violence were deeply affected negatively. However, the study highlights cases of resilience among these traumatized women. It appears that despite the adversity these women succeeded by a process of resilience to overcome their disability or trauma to reintegrate into the socio-economic fabric.

  8. Characterizing spiral arm and interarm star formation

    Kreckel, K; Schinnerer, E; Groves, B; Adamo, A; Hughes, A; Meidt, S

    2016-01-01

    Interarm star formation contributes significantly to a galaxy's star formation budget, and provides an opportunity to study stellar birthplaces unperturbed by spiral arm dynamics. Using optical integral field spectroscopy of the nearby galaxy NGC 628 with VLT/MUSE, we identify 391 HII regions at 35pc resolution over 12 kpc^2. Using tracers sensitive to the underlying gravitational potential, we associate HII regions with either arm (271) or interarm (120) environments. We find that most HII region physical properties (luminosity, size, metallicity, ionization parameter) are independent of environment. We calculate the fraction of Halpha luminosity due to the diffuse ionized gas (DIG) background contaminating each HII region, and find the DIG surface brightness to be higher within HII regions compared to the surroundings, and slightly higher within arm HII regions. Use of the temperature sensitive [SII]/Halpha line ratio map instead of the Halpha surface brightness to identify HII region boundaries does not ch...

  9. ARM Cloud Retrieval Ensemble Data Set (ACRED)

    Zhao, C; Xie, S; Klein, SA; McCoy, R; Comstock, JM; Delanoë, J; Deng, M; Dunn, M; Hogan, RJ; Jensen, MP; Mace, GG; McFarlane, SA; O’Connor, EJ; Protat, A; Shupe, MD; Turner, D; Wang, Z

    2011-09-12

    This document describes a new Atmospheric Radiation Measurement (ARM) data set, the ARM Cloud Retrieval Ensemble Data Set (ACRED), which is created by assembling nine existing ground-based cloud retrievals of ARM measurements from different cloud retrieval algorithms. The current version of ACRED includes an hourly average of nine ground-based retrievals with vertical resolution of 45 m for 512 layers. The techniques used for the nine cloud retrievals are briefly described in this document. This document also outlines the ACRED data availability, variables, and the nine retrieval products. Technical details about the generation of ACRED, such as the methods used for time average and vertical re-grid, are also provided.

  10. Featured Image: The Birth of Spiral Arms

    Kohler, Susanna

    2017-01-01

    In this figure, the top panels show three spiral galaxies in the Virgo cluster, imaged with the Sloan Digital Sky Survey. The bottom panels provide a comparison with three morphologically similar galaxies generated insimulations. The simulations run by Marcin Semczuk, Ewa okas, and Andrs del Pino (Nicolaus Copernicus Astronomical Center, Poland) were designed to examine how the spiral arms of galaxies like the Milky Way may have formed. In particular, the group exploredthe possibility that so-called grand-design spiral arms are caused by tidal effects as a Milky-Way-like galaxy orbits a cluster of galaxies. The authors show that the gravitational potential of the cluster can trigger the formation of two spiral arms each time the galaxy passes through the pericenter of its orbit around the cluster. Check out the original paper below for more information!CitationMarcin Semczuk et al 2017 ApJ 834 7. doi:10.3847/1538-4357/834/1/7

  11. Systems Approach to Arms Control Verification

    Allen, K; Neimeyer, I; Listner, C; Stein, G; Chen, C; Dreicer, M

    2015-05-15

    Using the decades of experience of developing concepts and technologies for verifying bilateral and multilateral arms control agreements, a broad conceptual systems approach is being developed that takes into account varying levels of information and risk. The IAEA has already demonstrated the applicability of a systems approach by implementing safeguards at the State level, with acquisition path analysis as the key element. In order to test whether such an approach could also be implemented for arms control verification, an exercise was conducted in November 2014 at the JRC ITU Ispra. Based on the scenario of a hypothetical treaty between two model nuclear weapons states aimed at capping their nuclear arsenals at existing levels, the goal of this exercise was to explore how to use acquisition path analysis in an arms control context. Our contribution will present the scenario, objectives and results of this exercise, and attempt to define future workshops aimed at further developing verification measures that will deter or detect treaty violations.

  12. Phoenix Deploying its Robotic Arm Elbow

    2008-01-01

    This animated gif is compiled of images from Phoenix's Stereo Surface Imager (SSI) taken on Sol 3. It shows the stair-step motion used to unstow the arm from a protective covering called the biobarrier. The last two moves allow the arm to stand straight up. The Phoenix Mission is led by the University of Arizona, Tucson, on behalf of NASA. Project management of the mission is by NASA's Jet Propulsion Laboratory, Pasadena, Calif. Spacecraft development is by Lockheed Martin Space Systems, Denver.

  13. The ARM unpiloted aerospace vehicle (UAV) program

    Sowle, D. [Mission Research Corporation, Santa Barbara, CA (United States)

    1995-09-01

    Unmanned aerospace vehicles (UAVs) are an important complement to the DOE`s Atmospheric Radiation Measurement (ARM) Program. ARM is primarily a ground-based program designed to extensively quantify the radiometric and meteorological properties of an atmospheric column. There is a need for airborne measurements of radiative profiles, especially flux at the tropopause, cloud properties, and upper troposphere water vapor. There is also a need for multi-day measurements at the tropopause; for example, in the tropics, at 20 km for over 24 hours. UAVs offer the greatest potential for long endurance at high altitudes and may be less expensive than piloted flights. 2 figs.

  14. Two-Armed, Mobile, Sensate Research Robot

    Engelberger, J. F.; Roberts, W. Nelson; Ryan, David J.; Silverthorne, Andrew

    2004-01-01

    The Anthropomorphic Robotic Testbed (ART) is an experimental prototype of a partly anthropomorphic, humanoid-size, mobile robot. The basic ART design concept provides for a combination of two-armed coordination, tactility, stereoscopic vision, mobility with navigation and avoidance of obstacles, and natural-language communication, so that the ART could emulate humans in many activities. The ART could be developed into a variety of highly capable robotic assistants for general or specific applications. There is especially great potential for the development of ART-based robots as substitutes for live-in health-care aides for home-bound persons who are aged, infirm, or physically handicapped; these robots could greatly reduce the cost of home health care and extend the term of independent living. The ART is a fully autonomous and untethered system. It includes a mobile base on which is mounted an extensible torso topped by a head, shoulders, and two arms. All subsystems of the ART are powered by a rechargeable, removable battery pack. The mobile base is a differentially- driven, nonholonomic vehicle capable of a speed >1 m/s and can handle a payload >100 kg. The base can be controlled manually, in forward/backward and/or simultaneous rotational motion, by use of a joystick. Alternatively, the motion of the base can be controlled autonomously by an onboard navigational computer. By retraction or extension of the torso, the head height of the ART can be adjusted from 5 ft (1.5 m) to 6 1/2 ft (2 m), so that the arms can reach either the floor or high shelves, or some ceilings. The arms are symmetrical. Each arm (including the wrist) has a total of six rotary axes like those of the human shoulder, elbow, and wrist joints. The arms are actuated by electric motors in combination with brakes and gas-spring assists on the shoulder and elbow joints. The arms are operated under closed-loop digital control. A receptacle for an end effector is mounted on the tip of the wrist and

  15. Diversity in the Danish Armed Forces

    Schaub Jr, Gary John; Pradhan-Blach, Flemming; Larsen, Esben Salling;

    The Danish Armed Forces face the functional imperative of becoming a smaller, professional expeditionary force and the societal imperative of including women and ethnic minorities. It currently lags behind its NATO partners in gender and ethnic diversity. Lessons to be learned from NATO members...... with more diverse militaries, such as the United States, Great Britain, and Canada, include recognition of diversity as a societal imperative to sustain the legitimacy of the armed forces, the necessity of systematically collecting and reporting personnel data to guide policy, the necessity of patience...

  16. The quest for the bionic arm.

    Hutchinson, Douglas T

    2014-06-01

    The current state of research of upper extremity prosthetic devices is focused on creating a complete prosthesis with full motor and sensory function that will provide amputees with a near-normal human arm. Although advances are being made rapidly, many hurdles remain to be overcome before a functional, so-called bionic arm is a reality. Acquiring signals via nerve or muscle inputs will require either a reliable wireless device or direct wiring through an osseous-integrated implant. The best way to tap into the "knowledge" present in the peripheral nerve is yet to be determined.

  17. Amine-functionalized, multi-arm star polymers: A novel platform for removing glyphosate from aqueous media.

    Samuel, Lianna; Wang, Ran; Dubois, Geraud; Allen, Robert; Wojtecki, Rudy; La, Young-Hye

    2017-02-01

    We describe a novel method for efficiently removing glyphosate from aqueous media via adsorption onto highly functionalized star-shaped polymeric particles. These particles have a polystyrene core with more than 35 attached methacrylate polymer arms, each containing a plurality of pendant amines (poly(dimethylamino ethyl methacrylate): PDMAEMA) that are partially protonated in water. Kinetic studies demonstrate that these star-polymers successfully remove up to 93% of glyphosate present in aqueous solution (feed concentration: 5 ppm), within 10 min contact time, outperforming activated carbon, which removed 33% after 20 min. On these star-polymers, glyphosate adsorption closely follows the Langmuir model indicating monolayer coverage at most. Ionic interaction between the protonated amines and glyphosate's dissociated carboxylic and phosphoric acid groups lead to effective glyphosate capture even at feed concentrations below 1 ppm. Surface charge of these star polymers and dissociation of glyphosate are both influenced by pH, thus glyphosate removal efficiency increases from 63% to 93% when pH increases from 4.2 to 7.7. NMR studies conducted with butylamine as a proxy for these polymeric particles confirm that the amine group binds with both glyphosate's carboxylic and phosphoric acid groups when its concentrations are in a 2:1 or higher molar ratio with glyphosate.

  18. Synthesis and luminescence properties of lanthanide complexes with a new tripodal ligands featuring salicylamide arms.

    Song, Xue-Qin; Dong, Wen-Kui; Zhang, Yu-Jie; Liu, Wei-Sheng

    2010-01-01

    A series of luminescent lanthanide complexes with a new tripodal ligand featuring salicylamide arms, 2,2',2''-nitrilotris(2-furfurylaminoformylphenoxy)triethylamine (L), were synthesized and characterized by elemental analysis, IR and molar conductivity measurements. Photophysical properties of the complexes were studied by means of UV-vis absorption and steady-state luminescence spectroscopy. Excited-state luminescence lifetimes and quantum yield of the complexes were determined. Luminescence studies demonstrated that the tripodal ligand featuring salicylamide arms exhibits a good antennae effect with respect to the Tb(III) and Dy(III) ion due to efficient intersystem crossing and ligand to metal energy transfer. From a more general perspective, this work offers interesting perspectives for the development of efficient luminescent stains and enlarges the arsenal for developing novel luminescent lanthanide complexes of salicylamide derivatives.

  19. Offset between stellar spiral arms and gas arms of the Milky Way

    Hou, L G

    2015-01-01

    Spiral arms shown by different components may not be spatially coincident, which can constrain formation mechanisms of spiral structure in a galaxy. We reassess the spiral arm tangency directions in the Milky Way through identifying the bump features in the longitude plots of survey data for infrared stars, radio recombination lines (RRLs), star formation sites, CO, high density regions in clouds, and HI. The bump peaks are taken as indications for arm tangencies, which are close to the real density peaks near the spiral arm tangency point but often have $\\sim$ 1$^\\circ$ offset to the interior of spiral arms. The arm tangencies identified from the longitudes plots for RRLs, HII regions, methanol masers, CO, high density gas regions, and HI gas appear nearly the same Galactic longitude, and therefore there is no obvious offset for spiral arms traced by different gas components. However, we find obvious displacements of 1.3$^\\circ-$ 5.8$^\\circ$ between gaseous bump peaks from the directions of the maximum densi...

  20. VCO PLL Frequency Synthesizers for Spacecraft Transponders

    Smith, Scott; Mysoor, Narayan; Lux, James; Cook, Brian

    2007-01-01

    Two documents discuss a breadboard version of advanced transponders that, when fully developed, would be installed on future spacecraft to fly in deep space. These transponders will be required to be capable of operation on any deepspace- communications uplink frequency channel between 7,145 and 7,235 MHz, and any downlink frequency channel between 8,400 and 8,500 MHz. The document focuses on the design and operation of frequency synthesizers for the receiver and transmitter. Heretofore, frequency synthesizers in deep-space transponders have been based on dielectric resonator oscillators (DROs), which do not have the wide tuning bandwidth necessary to tune over all channels in the uplink or downlink frequency bands. To satisfy the requirement for tuning bandwidth, the present frequency synthesizers are based on voltage-controlled-oscillator (VCO) phase-locked loops (PLLs) implemented by use of monolithic microwave integrated circuits (MMICs) implemented using inGaP heterojunction bipolar transistor (HBT) technology. MMIC VCO PLL frequency synthesizers similar to the present ones have been used in commercial and military applications but, until now, have exhibited too much phase noise for use in deep-space transponders. The present frequency synthesizers contain advanced MMIC VCOs, which use HBT technology and have lower levels of flicker (1/f) phase noise. When these MMIC VCOs are used with high-speed MMIC frequency dividers, it becomes possible to obtain the required combination of frequency agility and low phase noise.

  1. Variation in the human Achilles tendon moment arm during walking.

    Rasske, Kristen; Thelen, Darryl G; Franz, Jason R

    2017-02-01

    The Achilles tendon (AT) moment arm is an important determinant of ankle moment and power generation during locomotion. Load and depth-dependent variations in the AT moment arm are generally not considered, but may be relevant given the complex triceps surae architecture. We coupled motion analysis and ultrasound imaging to characterize AT moment arms during walking in 10 subjects. Muscle loading during push-off amplified the AT moment arm by 10% relative to heel strike. AT moment arms also varied by 14% over the tendon thickness. In walking, AT moment arms are not strictly dependent on kinematics, but exhibit important load and spatial dependencies.

  2. ATLAS software stack on ARM64

    Smith, Joshua Wyatt; The ATLAS collaboration

    2016-01-01

    The ATLAS experiment explores new hardware and software platforms that, in the future, may be more suited to its data intensive workloads. One such alternative hardware platform is the ARM architecture, which is designed to be extremely power efficient and is found in most smartphones and tablets. CERN openlab recently installed a small cluster of ARM 64-bit evaluation prototype servers. Each server is based on a single-socket ARM 64-bit system on a chip, with 32 Cortex-A57 cores. In total, each server has 128 GB RAM connected with four fast memory channels. This paper reports on the port of the ATLAS software stack onto these new prototype ARM64 servers. This included building the "external" packages that the ATLAS software relies on. Patches were needed to introduce this new architecture into the build as well as patches that correct for platform specific code that caused failures on non-x86 architectures. These patches were applied such that porting to further platforms will need no or only very little adj...

  3. Arms Control, Disarmament, and Peace Newsletters.

    Atkins, Stephen

    1986-01-01

    Considers the research value of four types of newsletters on arms control, disarmament, and peace: direct-action, informational, scholarly, and single-issue. An annotated list of 58 newsletters includes those considered most significant of their type and recommended for library collections. (EM)

  4. Light duty utility arm startup plan

    Barnes, G.A.

    1998-09-01

    This plan details the methods and procedures necessary to ensure a safe transition in the operation of the Light Duty Utility Arm (LDUA) System. The steps identified here outline the work scope and identify responsibilities to complete startup, and turnover of the LDUA to Characterization Project Operations (CPO).

  5. [A wireless ECG monitor based on ARM].

    Fan, Ai-Hua; Bian, Chun-Hua; Ning, Xin-Bao; He, Ai-Jun; Zhuang, Jian-Jun; Wu, Xu-Hui

    2008-11-01

    This paper presents a novel monitor which uses ARM controller AT91SAM7S64 as its main processor, LCM (Liquid Crystal Display Module) for displaying ECG waves, SD (Secure Digital memory) card for data storage and RF module PTR8000 for radio data transmission. This portable monitor boasts alarm function for abnormality and can provide dynamic ECG monitoring for patients.

  6. Watchdog for ARM Radar Network Operations

    2016-07-28

    WARNO is a software system designed to monitor the radars in the ARM Radar Network. It allows real time monitoring and tracking of instrument state and condition. It provides a web portal on the front end to interact with users, a REST API webpoint for interactions with third party systems, and an internal distributed architecture to allow it to be deployed at multiple sites.

  7. Synthesizing Modular Invariants for Synchronous Code

    Pierre-Loic Garoche

    2014-12-01

    Full Text Available In this paper, we explore different techniques to synthesize modular invariants for synchronous code encoded as Horn clauses. Modular invariants are a set of formulas that characterizes the validity of predicates. They are very useful for different aspects of analysis, synthesis, testing and program transformation. We describe two techniques to generate modular invariants for code written in the synchronous dataflow language Lustre. The first technique directly encodes the synchronous code in a modular fashion. While in the second technique, we synthesize modular invariants starting from a monolithic invariant. Both techniques, take advantage of analysis techniques based on property-directed reachability. We also describe a technique to minimize the synthesized invariants.

  8. SYNTHESIS OF POLYACRYLAMIDE WITH PENDANT POLY(BUTYL ACRYLATE) CHAINS USING THE MACROMER TECHNIQUE AND STUDIES ON THEIR PROPERTIES

    Hong-quan Xie; Gui-ying Liao; Yu Gao

    2004-01-01

    An amphiphilic graft polymer, (PAM-g-PBA), polyacrylamide (PAM) having poly(n-butyl acrylate) (PBA) side chains, was obtained by radical copolymerization of acrylamide with PBA macromer in solution. The macromer was synthesized by free radical polymerization of butyl acrylate in the presence of different amounts of thioglycolic acid as the chain transfer agent, followed by termination with glycidyl methacrylate. The reactivity ratio and effects of copolymerization conditions on the conversion of macromer or grafting efficiency were studied. The crude products were purified by extraction with toluene and water successively. Thc purified graft copolymer was characterized by IR, DSC and TEM. PAM-g-PBA can bring about microphase separation and exhibits good emulsifying properties and water absorbency. PAM-g-PBA exhibits a very good compatibilizing effect on the acrylic rubber/poly(vinyl chloride) blends. 2%-3% of the graft copolymer is enough for enhancing the tensile strength of the blends. The tensile strength of the blends is more than twice that without the compatibilizer. DSC and SEM demonstrated the enhancement of compatibility in the presence of the graft copolymer.

  9. An automated Teflon microfluidic peptide synthesizer.

    Zheng, Hui; Wang, Weizhi; Li, Xiaojun; Wang, Zihua; Hood, Leroy; Lausted, Christopher; Hu, Zhiyuan

    2013-09-07

    We present a microfluidic synthesizer made entirely of Teflon material for solid phase peptide synthesis (SPPS). Solvent-resistant perfluoroalkoxy (PFA) was used to construct chip-sized devices featuring multiple tri-layer pneumatic microvalves. Using these devices, model peptides were automatically synthesized and cleaved in situ in a continuous-flow manner. The total coupling and cleavage time was significantly reduced compared to conventional bulk reactors. The synthesis of a decapeptide, for instance, took less than 6 h using our device while it usually takes more than three days using conventional reactors.

  10. Synthesis of enantiopure sugar-decorated six-armed triptycene derivatives

    Paola Bonaccorsi

    2013-11-01

    Full Text Available A new class of molecules with a triptycene rigid core surrounded by six monosaccharide residues was synthesized. Hexakis(bromomethyl substituted triptycene was converted into a six-armed triptycene azide (2,3,6,7,14,15-hexakis(azidomethyl-9,10-dihydro-9,10-[1’,2’]benzenoanthracene. The key step of the synthesis was the cycloaddition of the azide to 2-propyn-1-yl β-D-gluco- or galactopyranosides. All products were isolated in good yields and were fully characterized.

  11. Synthesis of enantiopure sugar-decorated six-armed triptycene derivatives

    Gioia, Maria Luisa Di; Leggio, Antonella; Minuti, Lucio; Papalia, Teresa; Siciliano, Carlo; Temperini, Andrea; Barattucci, Anna

    2013-01-01

    Summary A new class of molecules with a triptycene rigid core surrounded by six monosaccharide residues was synthesized. Hexakis(bromomethyl) substituted triptycene was converted into a six-armed triptycene azide (2,3,6,7,14,15-hexakis(azidomethyl)-9,10-dihydro-9,10-[1’,2’]benzenoanthracene). The key step of the synthesis was the cycloaddition of the azide to 2-propyn-1-yl β-D-gluco- or galactopyranosides. All products were isolated in good yields and were fully characterized. PMID:24367407

  12. Does computer use affect the incidence of distal arm pain?

    Mikkelsen, Sigurd; Lassen, Christina Funch; Vilstrup, Imogen;

    2012-01-01

    To study how objectively recorded mouse and keyboard activity affects distal arm pain among computer workers.......To study how objectively recorded mouse and keyboard activity affects distal arm pain among computer workers....

  13. Emissie-arme mesttoediening op klei en veen

    Verburg, S.; Corporaal, J.

    1993-01-01

    In dit artikel wordt ingegaan op een aantal technische aspecten van emissie-arme mesttoediening. In het Praktijkonderzoek van februari 1993 is al aandacht besteed aan het effect van emissie-arme mesttoediening op het broedsucces van weidevogels.

  14. Embedded ARM Control Robotic Arm using BoaWeb server – a Survey

    V.Sirisha

    2015-10-01

    Full Text Available In today’s market, the competing microprocessors are ARM (Advanced Risc Microprocessor, Intel, AMD. ARM is preferred since it has been powering portable devices for decades and has simple architecture to keep the energy waste to be minimum. The electronics advancements and embedded technology advancements have become a challenging field in today’s techno world. In paper, the diligent features of embedded systems are introduced. It deals about how a robot is controlled using embedded operating system and ARM. Based on the combination of ARM, DSP and ARM Linux, the robot is controlled. The paper introduces development of embedded robot control system using Wi-Fi and also IOT. The embedded control system design includes four aspects. i.e., system structure, functions, hardware design and software design. By using these aspects (hardware and software adjustments, many robotic applications can be developed. Due to the fast execution speed and reasonable Ethernet speed in ARM processor, this system can be used in industrial oriented applications where there is very much necessity of safety and security.

  15. Effect of pendant isophthalic acid moieties on the adsorption properties of light hydrocarbons in HKUST-1-like tbo -MOFs: Application to methane purification and storage

    Belmabkhout, Youssef

    2014-01-01

    Equilibrium adsorption of methane (CH4), C2+ gases (ethane (C2H6), ethylene (C2H4), propane (C3H8), and propylene (C3H6)), and carbon dioxide (CO2) was measured on a series of tbo-MOFs (topological analogues of the prototypical MOF, HKUST-1, correspondingly dubbed tbo-MOF-1), which were developed via the supermolecular building layer (SBL) pillaring strategy. Specifically, tbo-MOF-2 and its isoreticular, functionalized analogue, tbo-MOF-2-{CH2O[Ph(CO2H)2]}2 (or tbo-MOF-3), which is characterized by pendant isophthalic acid moieties freely pointing into the cavities, were evaluated on the basis of potential use in methane storage and C2+/CH4 separation. The parent, tbo-MOF-2, showed high gravimetric and volumetric CH4 uptake, close to the U.S. Department of Energy (DOE) target for methane storage at 35 bar and room temperature. Though the presence of the pendant isophthalic acid moiety in the analogous compound, tbo-MOF-3, led to a decrease in total CH4 uptake, due mainly to the reduced size of the cavities, interestingly, it increased the affinity of the SBL-based tbo-MOF platform for propane, propene, ethane, and ethylene at low pressures compared with CH4, due additionally to the enhanced interactions of the highly polarizable light hydrocarbons with the isophthalic acid moiety. Using Ideal Adsorption Solution Theory (IAST), the predicted mixture adsorption equilibria for the C3H8/CH4, C3H6/CH4, C2H6/CH4, C2H4/CH4, and C3H8/CO2 systems showed high adsorption selectivity for C2+ over methane for tbo-MOF-3 compared with tbo-MOF-2. The high working storage capacity of tbo-MOF-2 and the high affinity of tbo-MOF-3 for C2+ over CH4 and CO2 make tbo-MOF an ideal platform for studies in gas storage and separation.

  16. Selective chelation of Cd(II) and Pb(II) versus Ca(II) and Zn(II) by using octadentate ligands containing pyridinecarboxylate and pyridyl pendants.

    Ferreirós-Martínez, Raquel; Esteban-Gómez, David; Platas-Iglesias, Carlos; de Blas, Andrés; Rodríguez-Blas, Teresa

    2009-12-07

    Herein we report the coordination properties toward Cd(II), Pb(II), Ca(II), and Zn(II) of a new octadentate ligand (py-H(2)bcpe) based on a ethane-1,2-diamine unit containing two picolinate and two pyridyl pendants, which is structurally derived from the previous reported ligand bcpe. Potentiometric studies have been carried out to determine the protonation constants of the ligand and the stability constants of the complexes with these cations. The introduction of the pyridyl pendants in bcpe provokes a very important increase of the logK(ML) values obtained for the Pb(II) and Cd(II) complexes, while this effect is less important in the case of the Zn(II) analogue. As a result, py-bcpe shows a certain selectivity for Cd(II) and Pb(II) over Zn(II) while keeping good Pb(II)/Ca(II) and Cd(II)/Ca(II) selectivities, and the new receptor py-bcpe can be considered as a new structural framework for the design of novel Cd(II) and Pb(II) extracting agents. Likewise, the stabilities of the Cd(II) and Pb(II) complexes are higher than those of the corresponding EDTA analogues. The X-ray crystal structure of [Zn(py-bcpe)] shows hexadentate binding of the ligand to the metal ion, the coordination polyhedron being best described as a severely distorted octahedron. However, the X-ray crystal structure of the Pb(II) analogue shows octadentate binding of the ligand to the metal ion. A detailed investigation of the structure in aqueous solution of the complexes by using nuclear magnetic resonance (NMR) techniques and density functional theory (DFT) calculations (B3LYP) shows that while in the Zn(II) complex the metal ion is six-coordinated, in the Pb(II) and Ca(II) analogues the metal ions are eight-coordinated. For the Cd(II) complex, our results suggest that in solution the complex exists as a mixture of seven- and eight-coordinated species. DFT calculations performed both in the gas phase and in aqueous solution have been also used to investigate the role of the Pb(II) lone pair in

  17. Fully Oxidized and Mixed-Valent Polyoxomolybdates Structured by Bisphosphonates with Pendant Pyridine Groups: Synthesis, Structure and Photochromic Properties

    Olivier Oms

    2015-06-01

    Full Text Available Hybrid organic-inorganic polyoxometalates (POMs were synthesized in water by the reaction of a MoVI precursor with bisphosphonate ligands functionalized by pyridine groups. The fully oxidized POM [(MoVI3O82(O(O3PC(O(C3H6NH2CH2C5H4NHPO32]4− has been isolated as water insoluble pure Na salt (NaMo6(Ale-4Py2 or mixed Na/K salt (NaKMo6(Ale-4Py2 and their structure solved using single-crystal X-ray diffraction. The mixed-valent complex [(MoV2O4(MoVI2O62{O3PC(O(C3H6N(CH2C5H4N2(MoVIO3PO3}2]8− was obtained as an ammonium salt (NH4Mo6(AlePy2Mo2, in the presence of a reducing agent (hydrazine. 31P NMR spectroscopic studies in aqueous media have allowed determining the pH stability domain of NH4Mo6(AlePy2Mo2. NaMo6(Ale-4Py2 and NaKMo6(Ale-4Py2 exhibit remarkable solid-state photochromic properties in ambient conditions. Under UV excitation, they develop a very fast color-change from white to deep purple and proved to be the fastest photochromic organoammonium/POM systems. The coloration kinetics has been fully quantified for both salts and is discussed in light of the hydrogen-bonding networks.

  18. Syntheses of haptens containing dioxaphosphorinan methoxyacetic acid linker arms for the production of antibodies to organophosphate pesticides

    tenHoeve, W; Wynberg, H; Jones, WT; Harvey, D; Ryan, GB; Reynolds, PHS

    1997-01-01

    Four generic heterobifunctional reagents, namely 2-(2-chloro-5-methyl-1,3,2-dioxaphosphorinan-5-yl)methoxyacetic acid methyl ester, p-sulfide, 2-(2-chloro-5-methyl-1,3,2-dioxaphosphorinan-5-yl)methoxyacetic acid methyl ester, p-oxide, 2-(2-mercapto-5-methyl-1,3,2-dioxaphosphorinan-5-yl)methoxyacetic

  19. Evaluating Text-to-Speech Synthesizers

    Cardoso, Walcir; Smith, George; Fuentes, Cesar Garcia

    2015-01-01

    Text-To-Speech (TTS) synthesizers have piqued the interest of researchers for their potential to enhance the L2 acquisition of writing (Kirstein, 2006), vocabulary and reading (Proctor, Dalton, & Grisham, 2007) and pronunciation (Cardoso, Collins, & White, 2012; Soler-Urzua, 2011). Despite their proven effectiveness, there is a need for…

  20. Digital Frequency Synthesizer For Radar Astronomy

    Sadr, Ramin; Satorius, Edgar; Robinett, J. Loris, Jr.; Olson, Erlend

    1992-01-01

    Report discusses conceptual digital frequency synthesizer part of programmable local oscillator in radar-astronomy system. Phase must remain continuous during adjustments of frequency, phase noise must be low, and spectral purity must be high. Discusses theory of operation in some mathematical detail and presents new analysis of spectral purity of output.

  1. Urea Decomposition Method to Synthesize Hydrotalcites

    Piao Ping YANG; Jian Feng YU; Tong Hao WU; Guo Zong LIU; Tae Sun CHANG; Dong Koo LEE; Deug Hee CHO

    2004-01-01

    The urea decomposition property at high temperature has been used to control the pH value in the synthesis of layer compounds. The hydrotalcites of Mg-Al and Ni-Al with high crystallinity were synthesized by using this property.

  2. SYNTHESES AND PROPERTIES OF SOME ORGANOSILANE POLYMERS

    ZHANG Xinghua; Robert West

    1984-01-01

    Some organosilane polymers with high molecular weights have been synthesized by cocondensation of organosilicon dihalide monomers with sodium metal in toluene. These polymers are both soluble in common solvents and meltable at lower temperatures, and can be molded, cast into films or drawn into fibers. Exposure of the solid polymers to ultraviolet light leads to degradation or crosslinking.

  3. Simulation of Octopus Arm Based on Coupled CPGs

    Juan Tian; Qiang Lu

    2015-01-01

    The octopus arm has attracted many researchers’ interests and became a research hot spot because of its amazing features. Several dynamic models inspired by an octopus arm are presented to realize the structure with a large number of degrees of freedom. The octopus arm is made of a soft material introducing high-dimensionality, nonlinearity, and elasticity, which makes the octopus arm difficult to control. In this paper, three coupled central pattern generators (CPGs) are built and a 2-dimens...

  4. Self-assembled targeted nanoparticles based on transferrin-modified eight-arm-polyethylene glycol–dihydroartemisinin conjugate

    Liu, Kefeng; Dai, Lin; Li, Chunxiao; Liu, Jing; Wang, Luying; Lei, Jiandu

    2016-07-01

    Poor delivery of insoluble anticancer drugs has so far precluded their clinical application. In this study, an efficient tumor targeted-nanoparticle delivery system, transferrin-eight-arm-polyethylene glycol–dihydroartemisinin nanoparticles (TF-8arm-PEG-DHA NPs) for the vehiculation of dihydroartemisinin (DHA) was first prepared and evaluated for its targeting efficiency and cytotoxicity in vitro and in vivo to Lewis lung carcinoma (LLC) cells, which overexpress transferrin receptors (TFRs). The synthesized TF-8arm-PEG–DHA NPs had high solubility (~102 fold of free DHA), relatively high drug loading (~10 wt% DHA), long circulating half-life and moderate particle size (~147 nm). The in vitro cytotoxicity and in vivo tumor growth inhibition studies in LLC-tumor bearing mice confirmed the enhanced efficacy of TF-modified 8arm-PEG-DHA NPs compared to free DHA and non-modified 8arm-PEG-DHA NPs. All these results together supported that the formulation developed in this work exhibited great potential as an effective tumor targeting delivery system for insoluble anticancer drugs.

  5. Anchoring the "floating arm": Use of proprioceptive and mirror visual feedback from one arm to control involuntary displacement of the other arm.

    Brun, C; Guerraz, M

    2015-12-01

    Arm movement control takes advantage of multiple inputs, including those originating from the contralateral arm. In the mirror paradigm, it has been suggested that control of the unseen arm, hidden by the mirror, is facilitated by the reflection of the other, moving arm. Although proprioceptive feedback originating from the moving arm, (the image of which is reflected in the mirror), is always coupled with visual feedback in the mirror paradigm, the former has received little attention. We recently showed that the involuntary arm movement following a sustained, isometric contraction, known as the "floating arm" or "Kohnstamm phenomenon", was adjusted to the passive-motorized displacement of the other arm. However, provision of mirror feedback, that is, the reflection in the mirror of the passively moved arm, did not add to this coupling effect. Therefore, the interlimb coupling in the mirror paradigm may to a large extent have a proprioceptive origin rather than a visual origin. The objective of the present study was to decouple mirror feedback and proprioceptive feedback from the reflected, moving arm and evaluate their respective contributions to interlimb coupling in the mirror paradigm. First (in Experiment 1, under eyes-closed conditions), we found that masking the proprioceptive afferents of the passively moved arm (by co-vibrating the antagonistic biceps and triceps muscles) suppressed the interlimb coupling between involuntary displacement of one arm and passive displacement of the other. Next (in Experiment 2), we masked proprioceptive afferents of the passively moved arm and specifically evaluated mirror feedback. We found that interlimb coupling through mirror feedback (though significant) was weaker than interlimb coupling through proprioceptive feedback. Overall, the present results show that in the mirror paradigm, proprioceptive feedback is stronger and more consistent than visual-mirror feedback in terms of the impact on interlimb coupling.

  6. Dynamics of Non-Steady Spiral Arms in Disk Galaxies

    Baba, Junichi; Wada, Keiichi

    2012-01-01

    In order to understand the physical mechanisms underlying non-steady stellar spiral arms in disk galaxies, we analyzed the growing and damping phases of their spiral arms using three-dimensional $N$-body simulations. We confirmed that the spiral arms are formed due to a swing amplification mechanism that reinforces density enhancement as a seeded wake. In the damping phase, the Coriolis force exerted on a portion of the arm surpasses the gravitational force that acts to shrink the portion. Consequently, the stars in the portion escape from the arm, and subsequently they form a new arm at a different location. The time-dependent nature of the spiral arms are originated in the continual repetition of this non-linear phenomenon. Since a spiral arm does not rigidly rotate, but follows the galactic differential rotation, the stars in the arm rotate at almost the same rate as the arm. In other words, every single position in the arm can be regarded as the co-rotation point. Due to interaction with their host arms, ...

  7. Predictive validity of the Hand Arm Risk assessment Method (HARM)

    Douwes, M.; Boocock, M.; Coenen, P.; Heuvel, S. van den; Bosch, T.

    2014-01-01

    The Hand Arm Risk assessment Method (HARM) is a simplified risk assessment method for determining musculoskeletal symptoms to the arm, neck and/or shoulder posed by hand-arm tasks of the upper body. The purpose of this study was to evaluate the predictive validity of HARM using data collected from a

  8. 32 CFR 707.3 - Yard arm signaling lights.

    2010-07-01

    ... 32 National Defense 5 2010-07-01 2010-07-01 false Yard arm signaling lights. 707.3 Section 707.3... RESPECT TO ADDITIONAL STATION AND SIGNAL LIGHTS § 707.3 Yard arm signaling lights. Naval vessels may display, as a means of visual signaling, white all round lights at the ends of the yard arms. These...

  9. Two new helical compounds based on Keggin clusters and N-donor multidentate ligand: Syntheses, structures and properties

    Zhou, Shi; Liu, Bo; Li, Xiao-Min; Shi, Tian; Chen, Ya-Guang

    2014-11-01

    Two isostructural polyoxometalate-based inorganic-organic hybrids with 1D helical chain, [CuH3L2(GeMo12O40)]·2H2O (1) and [CuH3L2(SiMo12O40)]·2H2O (2), where L=2,4,5-tri(4-pyridyl)-imidazole have been synthesized under hydrothermal conditions. It is the first time to use the L ligand to synthesis the Keggin-type polyoxometalate-based inorganic-organic hybrids. The two compounds possess the left- and right-handed helical chains and the POMs as pendants attach in the helical chains through Cu-O bonds. The two compounds have been characterized by elemental analyses, infrared (IR) spectroscopy, powder X-ray diffraction (PXRD), X-ray photoelectron spectra (XPS), thermogravimetric analysis (TGA) and photoluminescent spectroscopy. Moreover, nitrogen adsorption-desorption measurement, electrochemical and photocatalysis properties for degradation of methylene blue (MB) upon a UV irradiation of compound 1 have been examined.

  10. Camera Augmented Mobile C-arm

    Wang, Lejing; Weidert, Simon; Traub, Joerg; Heining, Sandro Michael; Riquarts, Christian; Euler, Ekkehard; Navab, Nassir

    The Camera Augmented Mobile C-arm (CamC) system that extends a regular mobile C-arm by a video camera provides an X-ray and video image overlay. Thanks to the mirror construction and one time calibration of the device, the acquired X-ray images are co-registered with the video images without any calibration or registration during the intervention. It is very important to quantify and qualify the system before its introduction into the OR. In this communication, we extended the previously performed overlay accuracy analysis of the CamC system by another clinically important parameter, the applied radiation dose for the patient. Since the mirror of the CamC system will absorb and scatter radiation, we introduce a method for estimating the correct applied dose by using an independent dose measurement device. The results show that the mirror absorbs and scatters 39% of X-ray radiation.

  11. Embedded Ethernet Controller using ARM LPC2138

    S.P.Magadum

    2013-05-01

    Full Text Available — With the development of network technology and communication technology needs that industrial control can be completed via network has become a trend. Here the proposed system consists of an ARM processor LPC2148 with an external Ethernet interface controller WIZ810MJ and the whole system can function as a web server. In the system the data can be transmitted transparently between host and serial device. The host can communicate with any serial device connected Ethernet without knowing each other’s physical location. Since ARM processor has fast execution capability and Ethernet standard can provide internet access with reasonable speed, this system is suitable for enhancing security in industrial conditions by remotely monitoring various industrial appliances where high safety and care is a necessity. There is no doubt that this system will be useful for a wide variety of industrial applications.

  12. ATLAS software stack on ARM64

    Smith, Joshua Wyatt; The ATLAS collaboration

    2017-01-01

    This paper reports on the port of the ATLAS software stack onto new prototype ARM64 servers. This included building the “external” packages that the ATLAS software relies on. Patches were needed to introduce this new architecture into the build as well as patches that correct for platform specific code that caused failures on non-x86 architectures. These patches were applied such that porting to further platforms will need no or only very little adjustments. A few additional modifications were needed to account for the different operating system, Ubuntu instead of Scientific Linux 6 / CentOS7. Selected results from the validation of the physics outputs on these ARM 64-bit servers will be shown. CPU, memory and IO intensive benchmarks using ATLAS specific environment and infrastructure have been performed, with a particular emphasis on the performance vs. energy consumption.

  13. MAGIC: Marine ARM GPCI Investigation of Clouds

    Lewis, ER; Wiscombe, WJ; Albrecht, BA; Bland, GL; Flagg, CN; Klein, SA; Kollias, P; Mace, G; Reynolds, RM; Schwartz, SE; Siebesma, AP; Teixeira, J; Wood, R; Zhang, M

    2012-10-03

    The second Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF2) will be deployed aboard the Horizon Lines cargo container ship merchant vessel (M/V) Spirit for MAGIC, the Marine ARM GPCI1 Investigation of Clouds. The Spirit will traverse the route between Los Angeles, California, and Honolulu, Hawaii, from October 2012 through September 2013 (except for a few months in the middle of this time period when the ship will be in dry dock). During this field campaign, AMF2 will observe and characterize the properties of clouds and precipitation, aerosols, and atmospheric radiation; standard meteorological and oceanographic variables; and atmospheric structure. There will also be two intensive observational periods (IOPs), one in January 2013 and one in July 2013, during which more detailed measurements of the atmospheric structure will be made.

  14. ARM Operations Quarterly Report - April - June 2012

    Voyles, JW

    2012-07-18

    Individual raw datastreams from instrumentation at the Atmospheric Radiation Measurement (ARM) Climate Research Facility fixed and mobile sites are collected and sent to the Data Management Facility (DMF) at Pacific Northwest National Laboratory (PNNL) for processing in near real-time. Raw and processed data are then sent approximately daily to the ARM Data Archive, where they are made available to the research community. For each instrument, we calculate the ratio of the actual number of processed data records received daily at the Archive to the expected number of data records. The results are tabulated by (1) individual datastream, site, and month for the current year and (2) site and fiscal year (FY) dating back to 1998.

  15. The Norma arm region Chandra survey catalog: X-ray populations in the spiral arms

    Fornasini, Francesca M. [Astronomy Department, University of California, 601 Campbell Hall, Berkeley, CA 94720 (United States); Tomsick, John A.; Bodaghee, Arash; Krivonos, Roman A. [Space Sciences Laboratory, 7 Gauss Way, University of California, Berkeley, CA 94720 (United States); An, Hongjun [Department of Physics, McGill University, Rutherford Physics Building, 3600 University Street, Montreal, QC H3A 2T8 (Canada); Rahoui, Farid [European Southern Observatory, Karl Schwarzschild-Strasse 2, D-85748 Garching bei München (Germany); Gotthelf, Eric V. [Columbia Astrophysics Laboratory, Columbia University, 550 West 120th Street, New York, NY 10027 (United States); Bauer, Franz E. [Instituto de Astrofísica, Facultad de Física, Pontificia Universidad Católica de Chile, 306, Santiago 22 (Chile); Stern, Daniel, E-mail: f.fornasini@berkeley.edu [Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, MS 169-506, Pasadena, CA 91109 (United States)

    2014-12-01

    We present a catalog of 1415 X-ray sources identified in the Norma Arm Region Chandra Survey (NARCS), which covers a 2° × 0.°8 region in the direction of the Norma spiral arm to a depth of ≈20 ks. Of these sources, 1130 are point-like sources detected with ≥3σ confidence in at least one of three energy bands (0.5-10, 0.5-2, and 2-10 keV), five have extended emission, and the remainder are detected at low significance. Since most sources have too few counts to permit individual classification, they are divided into five spectral groups defined by their quantile properties. We analyze stacked spectra of X-ray sources within each group, in conjunction with their fluxes, variability, and infrared counterparts, to identify the dominant populations in our survey. We find that ∼50% of our sources are foreground sources located within 1-2 kpc, which is consistent with expectations from previous surveys. Approximately 20% of sources are likely located in the proximity of the Scutum-Crux and near Norma arm, while 30% are more distant, in the proximity of the far Norma arm or beyond. We argue that a mixture of magnetic and nonmagnetic cataclysmic variables dominates the Scutum-Crux and near Norma arms, while intermediate polars and high-mass stars (isolated or in binaries) dominate the far Norma arm. We also present the cumulative number count distribution for sources in our survey that are detected in the hard energy band. A population of very hard sources in the vicinity of the far Norma arm and active galactic nuclei dominate the hard X-ray emission down to f{sub X} ≈ 10{sup –14} erg cm{sup –2} s{sup –1}, but the distribution curve flattens at fainter fluxes. We find good agreement between the observed distribution and predictions based on other surveys.

  16. Arms Control in the Korean Peninsula.

    1986-05-01

    defense expenditures of both sides are assessed as follows:4 The South Korean population outnumbers North Korea two to one. This presents difficulties for...99. Kim, Chum-Kon, The Korean War, Seoul, Kwang-Myong Publishing Company Ltd., 1980. The Text of Mutual Defense Treaty between Korea and the USA...AIR WAR COLLEGE RESEARCH REPORT ABSTRACT TITLE: Arms Control in the Korean Peninsula AUTHOR: Kim, Hyon, Colonel, Republic of Korea Air Force - 1

  17. Hezbollah: Armed Resistance to Political Participation

    2014-06-01

    to understand the policy of such an organization, considerable analysis is necessary. Social movement and armed resistance theory bring together...manifestation, were inherently unjust and imperialist. The Open Letter and the public statements of Hezbollah’s leadership until 1992 demonstrate a...providing an Islamic alternative to what they saw was fundamentally unjust . The Taif Agreement of 1989 was the first successful attempt to end the 16

  18. Arms Transfers to the Irish Republican Army.

    1987-06-01

    dealer who supplied illicitly manufactured submachine guns to agents posing as IRA gun- runners . 14 The IRA has also attempted, through arms ieaiers. to...Corps, trained in communications and crew-served weapons.34 Perhaps coincidentally, one of the IRA gun- runners captured by the Irish Navy in 1984 was a...the Maze , a maximum security prison near Belfast, it was revealed 116 V V. Aug. 27 (1982). None of the devices contained explosive material. [Facts on

  19. Exploring Instruction Cache Analysis - On Arm

    Svedenborg, Stian Valentin

    2014-01-01

    This thesis explores the challenges of implementing an instruction cache side-channel attack on an ARM platform. The information leakage through the instruction cache is formally discussed using information theoretic metrics. A successful Prime+Probe instruction cache side-channel attack against RSA is presented, recovering 967/1024 secret key bits by observing a single decryption using a synchronous spy process. Furthermore, an unsuccessful attempt is made at decoupling the spy from the vict...

  20. A Global Obstacle-avoidance Map for Anthropomorphic Arms

    Cheng Fang

    2014-07-01

    Full Text Available More and more humanoid robots are used in human society, and they face a wide variety of complicated manipulation tasks, which are mainly to be achieved by their anthropomorphic arms. Obstacle avoidance for the anthropomorphic arm must be a fundamental consideration to guarantee the successful implementation of these tasks. Different from traditional methods searching for feasible or optimal collision-free solutions for the anthropomorphic arm, a global obstacle- avoidance map for the whole arm is proposed to indicate the complete set of feasible solutions. In this map, the motion of the arm can be appropriately planned to intuitively control the configuration of the arm in motion. First, the cubic spline function is adopted to interpolate some well-chosen path points to generate a smooth collision-free path for the wrist of the anthropomorphic arm. Second, based on the path function of the wrist, the time and the self-rotation angle of the arm about the “shoulder-wrist” axis are used to parameterize all possible configurations of the arm so that a global two- dimensional map considering the obstacle avoidance can be established. Subsequently, a collision-free self-rotation angle profile of the arm can be well planned. Finally, the joint trajectories of a specific anthropomorphic arm, which correspond to the planned path of the wrist and self-rotation angle profile of the arm, can be solved on the basis of the general kinematic analysis of the anthropomorphic arm, and the specific structure. Several simulations are conducted to verify that the proposed collision-free motion planning method for anthropomorphic arms has some advantages and can be regarded as a convenient and intuitive tool to control the configuration of the anthropomorphic arm in motion, without collision with obstacles in its surroundings.

  1. Design of Poly(L-lactide)-Poly(ethylene glycol) Copolymer with Light-Induced Shape-Memory Effect Triggered by Pendant Anthracene Groups.

    Xie, Hui; He, Man-jie; Deng, Xiao-Ying; Du, Lan; Fan, Cheng-Jie; Yang, Ke-Ke; Wang, Yu-Zhong

    2016-04-13

    A novel light-induced shape-memory material based on poly(l-lactide)-poly(ethylene glycol) copolymer is developed successfully by dangling the photoresponsive anthracene group on the PEG soft segment selectively. For synthesis strategy, the preprepared photoresponsive monomer N,N-bis(2-hydroxyethyl)-9-anthracene-methanamine (BHEAA) is first embedded into PEG chains; then, we couple this anthracene-functionalized PEG precursor with PLA precursor to result in PLA-PEG-A copolymer. The composition of target product can be well-defined by simply adjusting the feed ratio. The chemical structures of intermediate and final products are confirmed by (1)H NMR. Differential scanning calorimetry analysis of material reveals that the PEG soft segment became noncrystallizable when 4% or more BHEAA is introduced, and this feature is beneficial to the mobility of anthracene groups in polymer matrix. The static tensile tests show that the samples exhibit rubberlike mechanical properties except for the PLA-dominant one. The reversibility of [4 + 4] cycloaddition reaction between pendant anthracene groups in PLA-PEG-A film is demonstrated by UV-vis. Eventually, the light-induced shape-memory effect (LSME) is successfully realized in PLA-PEG-A. The results of cyclic photomechanical tests also reveal that the content of PLA hard segment as well as photosensitive anthracene moieties plays a crucial role in LSME.

  2. After Arizona: Military Musicians in the Second World War Après Arizona: les musiciens dans la marine américaine pendant la Seconde Guerre mondiale

    Rosemary Peters

    2012-03-01

    Full Text Available Cet article traite du rôle des musiciens dans la marine américaine pendant la Seconde Guerre mondiale. L’histoire de l’USS Arizona — et de son orchestre, noyé avec le cuirassé lors de l’attaque surprise des forces japonaises — étant bien connue, je m’appuie sur cet exemple comme point de départ afin de contextualiser la situation des musiciens militaires après les événements de Pearl Harbor, en décembre 1941. Dans le sillage de ce grand moment de l’Histoire, j’évoque ici des histoires à une autre échelle, celle de la « micro-histoire »— celle d’un militaire seul au milieu d’autres militaires. À travers les lettres échangées entre des recrues ayant suivi ensemble la même formation, je trace ici leurs expériences de guerre en tant qu’artistes, ainsi que les divers conflits pratiques et idéologiques qui se manifestent dans la tension entre l’art musical et l’art martial.

  3. Nommer le conflit. Le cas de l’Alsace pendant son annexion de fait au Troisième Reich, 1940-1945

    Anne-Ségolène Verneret

    2011-12-01

    Full Text Available L’étude des comportements et opinions de la population en Alsace entre 1940 et 1945 fait appel à la nécessité de nommer une conflictualité parfois floue, ambivalente et qui évolue au cours de la période. Il convient de s’interroger sur l’adaptation des outils de définition des comportements développés en France et en Allemagne pour la situation alsacienne pendant l’annexion de fait de son territoire.   Alsace 1940-1945, oppositions au nazisme, comportements collectifsDie Erforschung des Verhaltens und der Meinung der Bevölkerung im Elsass zwischen 1940-1945 bringt die Notwendigkeit mit sich, eine zuweilen undurchsichtige, zweideutige Konfliktträchtigkeit zu benennen, die sich im Zeitraum der Annektierung zudem entwickelte. Die methodischen Werkzeuge zur Definition kollektiven Verhaltens, die in Frankreich und Deutschland für diesen elsässischen Fall entwickelt wurden, müssen hierbei angepasst werden.

  4. Computational Design of Iron Diphosphine Complexes with Pendant Amines for Hydrogenation of CO2 to Methanol: A Mimic of [NiFe] Hydrogenase.

    Chen, Xiangyang; Jing, Yuanyuan; Yang, Xinzheng

    2016-06-20

    Inspired by the active-site structure of the [NiFe] hydrogenase, we have computationally designed the iron complex [P(tBu) 2 N(tBu) 2 )Fe(CN)2 CO] by using an experimentally ready-made diphosphine ligand with pendant amines for the hydrogenation of CO2 to methanol. Density functional theory calculations indicate that the rate-determining step in the whole catalytic reaction is the direct hydride transfer from the Fe center to the carbon atom in the formic acid with a total free energy barrier of 28.4 kcal mol(-1) in aqueous solution. Such a barrier indicates that the designed iron complex is a promising low-cost catalyst for the formation of methanol from CO2 and H2 under mild conditions. The key role of the diphosphine ligand with pendent amine groups in the reaction is the assistance of the cleavage of H2 by forming a Fe-H(δ-) ⋅⋅⋅H(δ+) -N dihydrogen bond in a fashion of frustrated Lewis pairs.

  5. Subway station smoke control based on the air curtain and smoke-proof pendant wall%基于空气幕和挡烟垂壁的地铁站烟气控制

    应志刚

    2012-01-01

    FDS was used to analyze the smoke control measures combined with the subway station model through the research of smoke prevention performances of air curtain and smoke -proof pendant wall. The analysis was done under the considera-tion of smoke-proof pendant wall's height and wind speed of air curtain on the effects of smoke spread control. It showed that the higher smoke-proof pendant wall could effectively control the smoke spread to the station hall and appropriate increase of the air curtain wind speed could control the smoke at the station effectively. The effective combination and reasonable set of the smoke-proof pendant wall's height and air curtain wind speed could inhibit the smoke spread to the station hall.%通过研究空气幕和挡烟垂壁阻挡烟气蔓延的性能,结合地铁站模型,利用FDS对控烟措施进行研究分析.考虑挡烟垂壁的高度以及空气幕的风速大小对烟气蔓延控制效果的影响.结果表明,挡烟垂壁高度越大越能有效控制烟气蔓延至站厅层;空气幕的风速适当增大能有效地把烟气控制在站台层.二者的有效结合、合理设置能抑制烟气蔓延至站厅层.

  6. Multi-Armed Bandits in Metric Spaces

    Kleinberg, Robert; Upfal, Eli

    2008-01-01

    In a multi-armed bandit problem, an online algorithm chooses from a set of strategies in a sequence of trials so as to maximize the total payoff of the chosen strategies. While the performance of bandit algorithms with a small finite strategy set is quite well understood, bandit problems with large strategy sets are still a topic of very active investigation, motivated by practical applications such as online auctions and web advertisement. The goal of such research is to identify broad and natural classes of strategy sets and payoff functions which enable the design of efficient solutions. In this work we study a very general setting for the multi-armed bandit problem in which the strategies form a metric space, and the payoff function satisfies a Lipschitz condition with respect to the metric. We refer to this problem as the "Lipschitz MAB problem". We present a complete solution for the multi-armed problem in this setting. That is, for every metric space (L,X) we define an isometry invariant which bounds f...

  7. The Perseus arm in the anticenter direction

    Monguió, M.; Grosbøl, P.; Figueras, F.

    2015-05-01

    The stellar overdensity due to the Perseus arm has been detected in the anticenter direction through individual field stars. For that purpose, a Str&{uml;o}mgren photometric survey covering 16° ^2 was developed with the Wide Field Camera at the Isaac Newton Telescope. This photometry allowed us to compute individual physical parameters for these stars using a new method based on atmospheric models and evolutionary tracks. The analysis of the surface density as a function of distance for intermediate young stars in this survey allowed us to detect an overdensity at 1.6±0.2 kpc from the Sun, that can be associated with the Perseus arm, with a surface density amplitude of ˜14%. The significance of the detection is above 4σ for all the cases. The fit for the radial scale length of the Galactic disk provided values in the range [2.9,3.5] kpc for the population of the B4-A1 stars. We also analyzed the interstellar visual absorption distribution, and its variation as a function of distance is coherent with a dust layer before the Perseus arm location.

  8. Syntheses and studies of organosilicon compounds

    Xie, Ren [Iowa State Univ., Ames, IA (United States)

    1999-02-12

    The syntheses of polycarbosilanes and polysilanes as silicon carbide ceramic precursors have been active research areas in the Barton Research Group. In this thesis, the work is focused on the preparation of polycarbosilanes and polysilanes as stoichiometric silicon carbide precursor polymers. The syntheses of the precursor polymers are discussed and the conversions of these precursors to silicon carbide via pyrolysis are reported. The XRD pattern and elemental analyses of the resulting silicon carbide ceramics are presented. Silicon monoxide is an important intermediate in the production of silicon metal. The existence of silicon monoxide in gap phase has been widely accepted. In the second part of this thesis, the generation of gaseous silicon monoxide in four different reactors and the reactions of gaseous silicon monoxide towards organic compounds are discussed.

  9. SYNTHESES AND CHARACTERIZATIONS OF HYPERBRANCHED POLYPHENYLENES

    Han Peng; Hong-chen Dong; Yu-ping Dong; De-min Jia; Ben-zhong Tang

    2004-01-01

    New hyperbranched polyphenylenes with high molecular weights are synthesized by the copolycyclotrimerizations of 1,4-diethynylbenzene (I) with phenylacetylene (A), 1-octyne (B), and 1-dodecyne (C) catalyzed by TaCl5-Ph4Sn. The polymers are completely soluble in common solvents such as toluene, THF, chloroform, and dichloromethane. The polymers are characterized by spectroscopic methods and all of the polymers give satisfactory analysis data corresponding to their expected molecular structures.

  10. Predictions of synthesizing element 119 and 120

    2011-01-01

    The evaporation residue cross sections of synthesizing superheavy nuclei Z=119, 120 are calculated by different sets of master equations with different dynamical variables. Two methods basically predicted similar results that the Ca induced hot fusion can 48 produce element 119 easier than produce 120, and the evaporation residue cross sections for 119 are detectable by current advanced techniques, while the evaporation residue cross sections are below 0.1 pb for producing element 120.

  11. NIST digitally synthesized power calibration source

    Oldham, N. M.; Laug, O. B.; Waltrip, B. C.; Palm, R. H.

    1990-08-01

    A digitally-synthesized source of phantom power for calibration electrical power and energy meters is described. Independent sources of voltage, current, and phase angle are programmable between 0-240 volts, 0-5 amps, and 0-360 degrees, respectively. The uncertainty of the active and reactive power is estimated to be within +/- 100 ppm of the full scale apparent power (volt-amps).

  12. Template Syntheses, Crystal Structures and Supramolecular Assembly of Hexaaza Macrocyclic Copper(II) Complexes

    Kim, Taehyung; Kim, Ju Chang [Pukyong National Univ., Busan (Korea, Republic of); Lough, Alan J. [Univ. of Toronto, Toronto (Canada)

    2013-06-15

    Two new hexaaza macrocyclic copper(II) complexes were prepared by a template method and structurally characterized. In the solid state, they were self-assembled by intermolecular interactions to form the corresponding supramolecules 1 and 2, respectively. In the structure of 1, the copper(II) macrocycles are bridged by a tp ligand to form a macrocyclic copper(II) dimer. The dimer extends its structure by intermolecular forces such as hydrogen bonds and C-H···π interactions, resulting in the formation of a double stranded 1D supramolecule. In 2, the basic structure is a monomeric copper(II) macrocycle with deprotonated imidazole pendants. An undulated 1D hydrogen bonded array is achieved through hydrogen bonds between imidazole pendants and secondary amines, where the imidazole pendants act as a hydrogen bond acceptor. The 1D hydrogen bonded supramolecular chain is supported by C-H···π interactions between the methyl groups of acetonitrile ligands and imidazole pendants of the copper(II) macrocycles. In both complexes, the introduction of imidazoles to the macrocycle as a pendant plays an important role for the formation of supramolecules, where they act as intermolecular hydrogen bond donors and/or acceptors, C-H···π and π-π interactions.

  13. Titanat aluminium synthesized in a solar furnace

    Suleimanov, S.; Gulamova, D. [Uzbek Academy of Sciences, Tashkent (Uzbekistan). Materials Science Inst.; Boehmer, M.; Fend, T.; Rietbrock, P. [DLR, Koeln (Germany). MD-ET

    1997-12-31

    Solar furnace technology is an ecologically clean and economically attractive way, most suitable for research and development of new advanced materials. Such features of the solar furnace as sterile conditions of heating, high speed temperature delivering, materials processing in the whole range of the solar spectrum, quenching of the melt with rates of {proportional_to}10{sup 6} K/s, possibility of melting in the cold crucible etc. allow to synthesize complex oxide compositions, such as Al{sub 2}TiO{sub 5}. The study of Al{sub 2}TiO{sub 5} synthesized in the solar furnace has shown that the material is pure {beta}-Al{sub 2}TiO{sub 5} and possesses orthorhombic crystal structure. Microstructure of the material obtained from the melt has a prolonged prismatic shape. When the material is obtained by quenching the microstructure displays fine-grain structure with crystallites of 3-5 micron in size. Raman spectroscopy investigations have been performed on {beta}-Al{sub 2}TiO{sub 5} synthesized on the solar furnace. It has been observed a distinct band at 900 1/cm which is not presented in other six coordinated titanates. Most probably this band is connected with valent vibrations of the Al-O coupling in distorted octahedrons [AlO{sub 6}]. (orig.)

  14. Magnesioferrite synthesized from magnesian-magnetites

    Marcelo Hidemassa Anami

    2014-02-01

    Full Text Available Magnesioferrite is an important mineral due to its use in different scientific fields and by the fact that the soil through the action of weathering, can be a source of nutrients essential for plant development by the fact that in the soil. Its use in pure form or associated with other minerals is only possible through the synthesis in laboratory conditions. This study aimed to synthesize magnesioferrite and hematite from magnesian-magnetite by a co-precipitation procedure. The methodology used is an adaptation of the method of synthesis of pure magnetite, partially replacing the soluble salts of iron with soluble magnesium salts in the proportion of 30.0 mol% of Fe for Mg. The characterization of the synthetic minerals used x-rays diffraction, total chemical analysis and mass specific magnetic susceptibility. The results showed that besides the magnesian-magnetite an unprecedented muskoxita was synthesized, which upon annealing was converted to magnesioferrite and hematite and in the proportion of 93.1% and 6.9% respectively. The isomorphous substitution of Fe for Mg enhanced the thermal stability of the ferrimagnetic mineral synthesized.

  15. Syntheses and studies of acetylenic polymers

    Yiwei, Ding [Iowa State Univ., Ames, IA (United States)

    1994-03-03

    Based on new diiodo aryl compounds a series of novel soluble polymers, poly(2,5-dialkoxy-1,4-phenyleneethynylene)s (PPE polymers) were synthesized using palladium-catalysis. The molecular weights (MW) range from 8,000 to 40,000. Properties such as absorption, fluorescence, and conductivity were studied. A PPE polymer with butoxy side chain exhibits a weak electrical conductivity (σ = 10-3 S/cm) after doping with AsF5. Absorption spectra in THF solution at room temperature (RT) show a maximum at 440 nm. However, absorption spectra of PPE polymers in the film state at (RT) show a maximum at 480 nm. PPE polymer-based light emitting diode (LED) devices have been prepared; greenish light from these LED devices can be observed. Poly(ethynylene-p-arylene-ethynylene-silylene)s were synthesized through the same palladium-catalyzed polymerization; MWs are between 6,000 and 82,000. Absorption and fluorescence were studied. Some of these polymers exhibit thermotropic liquid crystalline properties. In addition, nonlinear optical properties were briefly examined. Poly(silylene-ethynylene) homopolymers as well as alternating copolymers were synthesized through a novel palladium-catalyzed polymerization; MWs range from 56 x 103 to 5.3 x 103. Thermal stability of these was also investigated; char yields range from 56 to 83%. One of these polymers exhibits thermotropic liquid crystalline properties.

  16. Syntheses and studies of acetylenic polymers

    Yiwei, Ding

    1994-03-03

    Based on new diiodo aryl compounds a series of novel soluble polymers, poly(2,5-dialkoxy-1,4-phenyleneethynylene)s (PPE polymers) were synthesized using palladium-catalysis. The molecular weights (MW) range from 8,000 to 40,000. Properties such as absorption, fluorescence, and conductivity were studied. A PPE polymer with butoxy side chain exhibits a weak electrical conductivity ({sigma} = 10{sup {minus}3} S/cm) after doping with AsF{sub 5}. Absorption spectra in THF solution at room temperature (RT) show a maximum at 440 nm. However, absorption spectra of PPE polymers in the film state at (RT) show a maximum at 480 nm. PPE polymer-based light emitting diode (LED) devices have been prepared; greenish light from these LED devices can be observed. Poly(ethynylene-p-arylene-ethynylene-silylene)s were synthesized through the same palladium-catalyzed polymerization; MWs are between 6,000 and 82,000. Absorption and fluorescence were studied. Some of these polymers exhibit thermotropic liquid crystalline properties. In addition, nonlinear optical properties were briefly examined. Poly(silylene-ethynylene) homopolymers as well as alternating copolymers were synthesized through a novel palladium-catalyzed polymerization; MWs range from 56 {times} 10{sup 3} to 5.3 {times} 10{sup 3}. Thermal stability of these was also investigated; char yields range from 56 to 83%. One of these polymers exhibits thermotropic liquid crystalline properties.

  17. Method of synthesizing cubic system boron nitride

    Yuzu, S.; Sumiya, H.; Degawa, J.

    1987-10-13

    A method is described for synthetically growing cubic system boron nitride crystals by using boron nitride sources, solvents for dissolving the boron nitride sources, and seed crystals under conditions of ultra-high pressure and high temperature for maintaining the cubic system boron nitride stable. The method comprises the following steps: preparing a synthesizing vessel having at least two chambers, arrayed in order in the synthesizing vessel so as to be heated according to a temperature gradient; placing the solvents having different eutectic temperatures in each chamber with respect to the boron nitride sources according to the temperature gradient; placing the boron nitride source in contact with a portion of each of the solvents heated at a relatively higher temperature and placing at least a seed crystal in a portion of each of the solvents heated at a relatively lower temperature; and growing at least one cubic system boron nitride crystal in each of the solvents in the chambers by heating the synthesizing vessel for establishing the temperature gradient while maintaining conditions of ultra-high pressure and high temperature.

  18. Design of a novel 3-DOF hybrid mechanical arm

    LI YanBiao; JIN ZhenLin; JI ShiMing

    2009-01-01

    Parameter optimization for a novel 3-DOF hybrid mechanical arm was presented by using a statistics method called the statistics parameters optimization method based on index atlases.Several kinematics and mechanics performance evaluation indices were proposed and discussed,according to the kinematics and mechanics analyses of the mechanical arm.Considering the assembly technique,a prototype of the 3-DOF hybrid mechanical arm was developed,which provided a basis for applications of the 3-DOF hybrid mechanical arm.The novel 3-DOF hybrid mechanical arm can be applied to the modern industrial fields requiring high stiffness,lower inertia and good technological efficiency.A novel 6-DOF hybrid humanoid mechanical arm was built,in which the present mechanical arm was connected with a spherical 3-DOF parallel manipulator.

  19. Visual Display of 5p-arm and 3p-arm miRNA Expression with a Mobile Application

    Chao-Yu Pan

    2017-01-01

    Full Text Available MicroRNAs (miRNAs play important roles in human cancers. In previous studies, we have demonstrated that both 5p-arm and 3p-arm of mature miRNAs could be expressed from the same precursor and we further interrogated the 5p-arm and 3p-arm miRNA expression with a comprehensive arm feature annotation list. To assist biologists to visualize the differential 5p-arm and 3p-arm miRNA expression patterns, we utilized a user-friendly mobile App to display. The Cancer Genome Atlas (TCGA miRNA-Seq expression information. We have collected over 4,500 miRNA-Seq datasets from 15 TCGA cancer types and further processed them with the 5p-arm and 3p-arm annotation analysis pipeline. In order to be displayed with the RNA-Seq Viewer App, annotated 5p-arm and 3p-arm miRNA expression information and miRNA gene loci information were converted into SQLite tables. In this distinct application, for any given miRNA gene, 5p-arm miRNA is illustrated on the top of chromosome ideogram and 3p-arm miRNA is illustrated on the bottom of chromosome ideogram. Users can then easily interrogate the differentially 5p-arm/3p-arm expressed miRNAs with their mobile devices. This study demonstrates the feasibility and utility of RNA-Seq Viewer App in addition to mRNA-Seq data visualization.

  20. Two new helical compounds based on Keggin clusters and N-donor multidentate ligand: Syntheses, structures and properties

    Zhou, Shi [Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024 (China); College of Chemistry, Jilin Normal University, Siping 136000 (China); Liu, Bo [College of Chemistry, Jilin Normal University, Siping 136000 (China); Li, Xiao-Min; Shi, Tian [Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024 (China); Chen, Ya-Guang, E-mail: chenyg146@nenu.edu.cn [Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun 130024 (China)

    2014-11-15

    Two isostructural polyoxometalate-based inorganic–organic hybrids with 1D helical chain, [CuH{sub 3}L{sub 2}(GeMo{sub 12}O{sub 40})]·2H{sub 2}O (1) and [CuH{sub 3}L{sub 2}(SiMo{sub 12}O{sub 40})]·2H{sub 2}O (2), where L=2,4,5-tri(4-pyridyl)-imidazole have been synthesized under hydrothermal conditions. It is the first time to use the L ligand to synthesis the Keggin-type polyoxometalate-based inorganic–organic hybrids. The two compounds possess the left- and right-handed helical chains and the POMs as pendants attach in the helical chains through Cu–O bonds. The two compounds have been characterized by elemental analyses, infrared (IR) spectroscopy, powder X-ray diffraction (PXRD), X-ray photoelectron spectra (XPS), thermogravimetric analysis (TGA) and photoluminescent spectroscopy. Moreover, nitrogen adsorption−desorption measurement, electrochemical and photocatalysis properties for degradation of methylene blue (MB) upon a UV irradiation of compound 1 have been examined. - Graphical abstract: Two new compounds, [CuH{sub 3}L{sub 2}(GeMo{sub 12}O{sub 40})]·2H{sub 2}O (1) and [CuH{sub 3}L{sub 2}(SiMo{sub 12}O{sub 40})]·2H{sub 2}O (2) have been synthesized under hydrothermal conditions. The two compounds possess the left- and right-handed helical chains. - Highlights: • The tridentate L ligand is first used to synthesis Keggin-type polyoxometalates. • The two compounds possess the left- and right-handed Cu–L helical chains. • Relationship between surface properties and photocatalytic activity was studied. • Two compounds exhibit photoluminescence of ligand-to-metal charge transfer.

  1. Optimizing Armed Forces Capabilities for Hybrid Warfare – New Challenge for Slovak Armed Forces

    Peter PINDJÁK

    2015-09-01

    Full Text Available The paper deals with the optimization of military capabilities of the Slovak Armed Forces for conducting operations in a hybrid conflict, which represents one of the possible scenarios of irregular warfare. Whereas in the regular warfare adversaries intend to eliminate the centers of gravity of each other, most often command and control structures, in irregular conflicts, the center of gravity shifts towards the will and cognitive perception of the target population. Hybrid warfare comprises a thoroughly planned combination of conventional military approaches and kinetic operations with subversive, irregular activities, including information and cyber operations. These efforts are often accompanied by intensified activities of intelligence services, special operation forces, and even mercenary and other paramilitary groups. The development of irregular warfare capabilities within the Slovak Armed Forces will require a progressive transformation process that may turn the armed forces into a modern and adaptable element of power, capable of deployment in national and international crisis management operations.

  2. Effects of hand clasping and arm folding on academic performance

    Zhenxiang Zang; Zaizhu Han; Yufeng Zang

    2008-01-01

    BACKGROUND: Similar to handedness, hand clasping and arm folding are also lateral preferences.Previous studies showed a variation frequency for hand clasping and arm folding among different populations.OBJECTIVE: To investigate the relationship between patterns of lateral preferences (hand clasping or arm folding) and academic performance of middle school students.DESIGN, TIME AND SETTINGS: Cross-sectional investigation. The data were collected in the Beijing Zhongguancun High School in Beijing in May 2007. Data analysis was performed in the State Key Laboratory of Cognitive Neuroscience and Learning, Beijing Normal University during June to July 2007.PARTICIPANTS: A total of 102 senior-grade students from Beijing Zhongguancun High School, including 58 males and 44 females, were selected for this study.METHODS: Different forms of hand clasping and arm folding were recorded. More specifically, hand clasping was either right-thumb-top or left-thumb-top, and arm folding was either right-arm-top or left-arm-top. Students with congruent preference used right-thumb-top-right-arm-top or left-thumb-top-left-arm-top, and incongruent preference was displayed by right-thumb-top-left-arm-top or left-thumb-top-right-arm-top. Academic performances were collected from mid-term exams in six subjects (Chinese, Mathematics, English, Physics, Chemistry, and Biology), with a total points = 100 for each. A three-way (hand clasping, arm folding, and sex) ANOVA was performed to determine the effect on academic performances.MAIN OUTCOME MEASURES: The relationship between hand clasping, arm folding, sex, and academic performance of students.RESULTS: (1) There was no significant difference in distribution frequency between right-thumb-top and left-thumb-top (P > 0.05), or between right-arm-top and left-arm-top (P > 0.05). The distribution frequency difference between boys and girls was not significant for any subtype (P > 0.05). (2) hand clasping had no significant main effect on any of the

  3. Toward the Rational Design of Galactosylated Glycoclusters That Target Pseudomonas aeruginosa Lectin A (LecA): Influence of Linker Arms That Lead to Low-Nanomolar Multivalent Ligands.

    Wang, Shuai; Dupin, Lucie; Noël, Mathieu; Carroux, Cindy J; Renaud, Louis; Géhin, Thomas; Meyer, Albert; Souteyrand, Eliane; Vasseur, Jean-Jacques; Vergoten, Gérard; Chevolot, Yann; Morvan, François; Vidal, Sébastien

    2016-08-01

    Anti-infectious strategies against pathogen infections can be achieved through antiadhesive strategies by using multivalent ligands of bacterial virulence factors. LecA and LecB are lectins of Pseudomonas aeruginosa implicated in biofilm formation. A series of 27 LecA-targeting glycoclusters have been synthesized. Nine aromatic galactose aglycons were investigated with three different linker arms that connect the central mannopyranoside core. A low-nanomolar (Kd =19 nm, microarray) ligand with a tyrosine-based linker arm could be identified in a structure-activity relationship study. Molecular modeling of the glycoclusters bound to the lectin tetramer was also used to rationalize the binding properties observed.

  4. CHARACTERISTICS OF SPIRAL ARMS IN LATE-TYPE GALAXIES

    Honig, Z. N.; Reid, M. J., E-mail: mreid@cfa.harvard.edu [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)

    2015-02-10

    We have measured the positions of large numbers of H II regions in four nearly face-on, late-type, spiral galaxies: NGC 628 (M74), NGC 1232, NGC 3184, and NGC 5194 (M51). Fitting log-periodic spiral models to segments of each arm yields local estimates of spiral pitch angle and arm width. While pitch angles vary considerably along individual arms, among arms within a galaxy, and among galaxies, we find no systematic trend with galactocentric distance. We estimate the widths of the arm segments from the scatter in the distances of the H II regions from the spiral model. All major arms in these galaxies show spiral arm width increasing with distance from the galactic center, similar to the trend seen in the Milky Way. However, in the outermost parts of the galaxies, where massive star formation declines, some arms reverse this trend and narrow. We find that spiral arms often appear to be composed of segments of ∼5 kpc length, which join to form kinks and abrupt changes in pitch angle and arm width; these characteristics are consistent with properties seen in the large N-body simulations of D'Onghia et al. and others.

  5. Thermal Conductivity Measurement of Synthesized Mantle Minerals

    Asimow, P. D.; Luo, S.; Mosenfelder, J. L.; Liu, W.; Staneff, G. D.; Ahrens, T. J.; Chen, G.

    2002-12-01

    Direct thermal conductivity (k) measurement of mantle minerals is crucial to constrain the thermal profile of the Earth as well as geodynamic studies of the mantle (e.g., to determine the Rayleigh number). We have embarked on systematic multi-anvil syntheses of dense polycrystalline specimens of mantle phases of adequate size and zero porosity for precise thermal conductivity measurements by the 3ω method (\\textit{Cahill and Pohl, Phys. Rev. B, 1987}) under elevated temperatures (T). Coesite and stishovite (see \\textit{Luo et al., GRL, 2002}) as well as majorite and wadsleyite have been synthesized; ringwoodite and perovskite are scheduled. Preliminary thermal conductivity measurements at ambient pressure on coesite (120 - 300 K, 9.53 Wm-1K-1 at 300 K) are consistent with prior room temperature data (\\textit{Yukutake & Shimada, PEPI, 1978}), while our stishovite data at 300 K appear to be low (1.96 Wm-1K-1). Efforts are being made to extend the measurement to higher temperatures (e.g., above Debye temperature Θ D), thus allowing determination of k(T) relationship (say, k~ T-n); success will depend on the decomposition kinetics of these metastable phases. The pressure dependence of k of these synthesized samples can also be measured (\\textit{e.g., Osako et al., HPMPS-6, 2002; Xu et al., EOS, 2001}). Recent thermal conductivity measurement on LiF and Al2O_3 from shock wave loading (\\textit{Holland & Ahrens, 1998}) is consistent with the modeling on MgO and Al2O_3 (\\textit{Manga & Jeanloz, JGR, 1997}) with classical theories. Thus, k values at modest pressures and T (say, above Θ D) would allow extrapolation of k to appropriate mantle conditions.

  6. Effects of age, sex and arm on the accuracy of arm position sense – Left-arm superiority in healthy right-handers

    Lena eSchmidt

    2013-12-01

    Full Text Available Position sense is an important proprioceptive ability. Disorders of arm position sense (APS often occur after unilateral stroke, and are associated with a negative functional outcome. In the present study we assessed horizontal APS by measuring angular deviations from a visually defined target separately for each arm in a large group of healthy subjects. We analyzed the accuracy and instability of horizontal APS as a function of age, sex and arm. Subjects were required to specify verbally the position of their unseen arm on a 0-90° circuit by comparing the current position with the target position indicated by a LED lamp, while the arm was passively moved by the examiner. Eighty-seven healthy subjects participated in the study, ranging from 20 to 77 years, subdivided into three age groups. The results revealed that APS was not a function of age or sex, but was significantly better in the non-dominant (left arm in absolute but not in constant errors across all age groups of right-handed healthy subjects. This indicates a right-hemisphere superiority for left arm position sense in right-handers and neatly fits to the more frequent and more severe left-sided body-related deficits in patients with unilateral stroke (i.e. impaired arm position sense in left spatial neglect, somatoparaphrenia or in individuals with abnormalities of the right cerebral hemisphere. These clinical issues will be discussed.

  7. Les infirmières-visiteuses pendant l’entre-deux-guerres en Haute-Normandie : entre professionnalisme officiel et bénévolat officieux

    Stéphane Henry

    2009-12-01

    Full Text Available Marginale avant 1914, révélée pendant la Première Guerre mondiale, adulée ou décriée pendant l’entre-deux-guerres, l’évolution de la profession d’infirmière-visiteuse est étrangement commune à l’évolution de la place des femmes dans le travail salarié. En effet, même si une législation est venue encadrer ce nouveau corps de femmes au début des années vingt, force est de constater, au travers des exemples des départements de Seine-Inférieure et de l’Eure, que celui-ci a gardé de nombreux attributs propres au bénévolat. D’ailleurs, bien que les dirigeants de l’action antituberculeuse, Albert Calmette en tête, aient régulièrement encensé la profession, ils ont néanmoins cherché à l’encadrer strictement, redoutant des envies trop fortes d’autonomie. À cette professionnalisation toute relative se sont ajoutées des conditions de travail particulièrement rudes pour ces jeunes femmes novices, finalement peu préparées à côtoyer une misère insoupçonnée. Ainsi, si la fonction d’infirmière-visiteuse correspond à un virage non négligeable dans l’acceptation du travail qualifié des femmes par la société, son efficacité dans le cadre des luttes contre les fléaux sociaux (tuberculose et mortalité infantile reste tout de même mesurée dans les faits.The evolutions of the status of the visiting nurse echo the evolution in women's position within the workforce: marginal prior to 1914, revealed during the First World War, idolized or disparaged in the inter-war years. Despite legislation governing this new corps of women nurses in the early twenties, examples from the departments of the Seine-Inférieure and  the Eure make clear that it retained many attributes of volunteer work. Moreover, although the leaders of the war against tuberculosis, such as Albert Calmette, regularly praised the profession, they nonetheless sought to regulate it strictly, fearing a move toward excessive autonomy. The

  8. 拦阻索冲击的多体动力学仿真研究%Multi-body dynamic simulation of impact on cross deck pendant

    沈文厚; 赵治华; 任革学; 王宁羽

    2015-01-01

    舰载机着舰时,尾钩冲击拦阻索导致索内应力动态向甲板两端传播。为研究拦阻索应力波传播规律及峰值决定因素,本文在多体动力学框架下,发展了基于绝对节点坐标法的具有接触碰撞功能的大位移索单元,在此基础上建立了包含缓冲装置的拦阻系统多体动力学模型,仿真揭示了拦阻索受冲击后应力波在传播过程中,分别在甲板两侧的导向轮和尾钩处,因横波的反射与叠加均造成了应力尖峰,而滑轮缓冲装置与钢索末端缓冲装置均能有效的降低索内应力峰值。拦阻系统中的钢索用轻质材料代替,亦能降低索内应力峰值。此外,建立的全尺寸舰载机拦阻系统多体动力学模型为系统的设计与优化提供了一种计算手段。%When an aircraft is landing on an aircraft-carrier,the impact stress generated at the moment of its tail-hook arresting cross deck pendant propagates to both ends of the wire rope.To simulate and understand the governing law of this stress wave,a cable element with contact and large displacement functions was developed based on absolute nodal coordinate formulation under the framework of multi-body dynamics.And then a multi-body dynamic model of the whole arresting system was built.The results of simulation showed that stress peaks are caused by reflection and superposition of transverse waves at deck sheaves and carrier-based aircraft tail-hook,after the tail-hook arrests the cross deck pendant;damping sheave installation can reduce stress peak effectively,and replacing the steel rope with lightweight material also weakens the stress peak.The multi-body model of full-size arresting system built here provided an effective simulation way to assist the design and optimization of the whole arresting system.

  9. ARM assembly language fundamentals and techniques

    Hohl, William

    2009-01-01

    Written by the director of ARM's worldwide academic program, this volume gives computer science professionals and students an edge, regardless of their preferred coding language. For those with some basic background in digital logic and high-level programming, the book examines code relevant to hardware and peripherals found on today's microcontrollers and looks at situations all programmers will eventually encounter. The book's carefully chosen examples teach easily transferrable skills that will help readers optimize routines and significantly streamline coding, especially in the embedded sp

  10. HS06 Benchmark for an ARM Server

    Kluth, Stefan

    2014-06-01

    We benchmarked an ARM cortex-A9 based server system with a four-core CPU running at 1.1 GHz. The system used Ubuntu 12.04 as operating system and the HEPSPEC 2006 (HS06) benchmarking suite was compiled natively with gcc-4.4 on the system. The benchmark was run for various settings of the relevant gcc compiler options. We did not find significant influence from the compiler options on the benchmark result. The final HS06 benchmark result is 10.4.

  11. HS06 Benchmark for an ARM Server

    Kluth, Stefan

    2013-01-01

    We benchmarked an ARM cortex-A9 based server system with a four-core CPU running at 1.1 GHz. The system used Ubuntu 12.04 as operating system and the HEPSPEC 2006 (HS06) benchmarking suite was compiled natively with gcc-4.4 on the system. The benchmark was run for various settings of the relevant gcc compiler options. We did not find significant influence from the compiler options on the benchmark result. The final HS06 benchmark result is 10.4.

  12. 'Great power' intervention in African armed conflicts

    Olsen, Gorm Rye

    2015-01-01

    to contribute to understanding the changing geopolitical environment and the current conditions for conflict management in Africa. The focus is not on trade and aid. The paper launches the hypothesis that the explanations why the US, China and the EU have intervened are basically identical. In spite......This paper asks why the United States (US), China and the European Union (EU) have intervened in a number of armed conflicts in Africa in the twenty-first century. Scrutiny and comparison of the motivations and interests of the three non-African actors in intervening in African crises are assumed...

  13. Photochromism of 36-Armed Liquid Crystalline Dendrimer

    2005-01-01

    The photochromism of a 36-armed liquid crystalline dendrimer D6 was briefly described in this paper. The molar absorption coefficient, photoisomerization and photo back-isomerization of D6 in solution were investigated by UV/Vis absorption spectra. The results indicate that the photochromism and photo back-isomerization of D6 in chloroform (CHCl3) and tetrahydrofuran (THF) solutions are in accordance with the first order kinetics. The photochromism rate constants of D6 are 10-1 s-1, it is 107 times larger than that of side-chain liquid crystalline polymers containing the same azobenzene moieties.

  14. Telerobotics with whole arm collision avoidance

    Wilhelmsen, K.; Strenn, S.

    1993-09-01

    The complexity of teleorbotic operations in a cluttered environment is exacerbated by the need to present collision information to the operator in an understandable fashion. In addition to preventing movements which will cause collisions, a system providing some form of virtual force reflection (VFR) is desirable. With this goal in mind, Lawrence Livermore National Laboratory (LLNL) has installed a kinematically master/slave system and developed a whole arm collision avoidance system which interacts directly with the telerobotic controller. LLNL has also provided a structure to allow for automated upgrades of workcell models and provide collision avoidance even in a dynamically changing workcell.

  15. TRIGGERED STAR FORMATION IN SPIRAL ARMS

    E. E. Martínez-García

    2009-01-01

    Full Text Available We present the status of our research, relative to the triggering of star formation by large-scale galactic shocks associated with spiral density waves. Around a third of the galaxies in our sample do not seem suitable for this kind of study, because they present an e ect, probably due to opacity, that is not well understood. The remaining objects seem to favor the idea of density wave triggering of star formation in the arms. The comparison with stellar population synthesis models, and the orbital resonance positions for these galaxies (derived by means of spiral pattern angular speeds corroborate this hypothesis.

  16. High-Energy Optical Parametric Waveform Synthesizer

    Muecke, Oliver D.; Cirmi, G.; Fang, S.; Rossi, G. M.; Chia, Shih-Hsuan; Kärtner, F. X.; Manzoni, C.; Farinello, P.; Cerullo, and G.

    2014-01-01

    We discuss the ongoing development of a phase-stable, multi-mJ 3-channel parametric waveform synthesizer generating a 2-octave-wide spectrum (0.52-2.4μm). After two amplification stages, the combined >125-μJ output supports 1.9-fs waveforms. First preliminary FROG-characterization results of the second-stage outputs demonstrate the feasibility to recompress all three channels simultaneously close to the Fourier limit. Energy scaling to ~2 mJ is achieved after three amplification stages. The f...

  17. Kootenay Lake Fertilization Experiment, Year 15 (North Arm) and Year 3 (South Arm) (2006) Report

    Schindler, E.U.; Sebastian, D.; Andrusak, G.F. [Fish and Wildlife Science and Allocation, Ministry of Environment, Province of British Columbia

    2009-07-01

    This report summarizes results from the fifteenth year (2006) of nutrient additions to the North Arm of Kootenay Lake and three years of nutrient additions to the South Arm. Experimental fertilization of the lake has been conducted using an adaptive management approach in an effort to restore lake productivity lost as a result of nutrient uptake in upstream reservoirs. The primary objective of the experiment is to restore kokanee (Oncorhynchus nerka) populations, which are the main food source for Gerrard rainbow trout (Oncorhynchus mykiss) and bull trout (Salvelinus confluentus). The quantity of agricultural grade liquid fertilizer (10-34-0, ammonium polyphosphate and 28-0-0, urea ammonium nitrate) added to the North Arm in 2006 was 44.7 tonnes of P and 248.4 tonnes of N. The total fertilizer load added to the South Arm was 257 tonnes of nitrogen; no P was added. Kootenay Lake has an area of 395 km{sup 2}, a maximum depth of 150 m, a mean depth of 94 m, and a water renewal time of approximately two years. Kootenay Lake is a monomictic lake, generally mixing from late fall to early spring and stratifying during the summer. Surface water temperatures generally exceed 20 C for only a few weeks in July. Results of oxygen profiles were similar to previous years with the lake being well oxygenated from the surface to the bottom depths at all stations. Similar to past years, Secchi disc measurements at all stations in 2006 indicate a typical seasonal pattern of decreasing depths associated with the spring phytoplankton bloom, followed by increasing depths as the bloom gradually decreases by the late summer and fall. Total phosphorus (TP) ranged from 2-7 {micro}g/L and tended to decrease as summer advanced. Over the sampling season dissolved inorganic nitrogen (DIN) concentrations decreased, with the decline corresponding to nitrate (the dominant component of DIN) being utilized by phytoplankton during summer stratification. Owing to the importance of epilimnetic nitrate

  18. Two pathways for electrocatalytic oxidation of hydrogen by a nickel bis(diphosphine) complex with pendant amines in the second coordination sphere.

    Yang, Jenny Y; Smith, Stuart E; Liu, Tianbiao; Dougherty, William G; Hoffert, Wesley A; Kassel, W Scott; Rakowski DuBois, M; DuBois, Daniel L; Bullock, R Morris

    2013-07-01

    A nickel bis(diphosphine) complex containing pendant amines in the second coordination sphere, [Ni(P(Cy)2N(t-Bu)2)2](BF4)2 (P(Cy)2N(t-Bu)2 = 1,5-di(tert-butyl)-3,7-dicyclohexyl-1,5-diaza-3,7-diphosphacyclooctane), is an electrocatalyst for hydrogen oxidation. The addition of hydrogen to the Ni(II) complex gives three isomers of the doubly protonated Ni(0) complex [Ni(P(Cy)2N(t-Bu)2H)2](BF4)2. Using the pKa values and Ni(II/I) and Ni(I/0) redox potentials in a thermochemical cycle, the free energy of hydrogen addition to [Ni(P(Cy)2N(t-Bu)2)2](2+) was determined to be -7.9 kcal mol(-1). The catalytic rate observed in dry acetonitrile for the oxidation of H2 depends on base size, with larger bases (NEt3, t-BuNH2) resulting in much slower catalysis than n-BuNH2. The addition of water accelerates the rate of catalysis by facilitating deprotonation of the hydrogen addition product before oxidation, especially for the larger bases NEt3 and t-BuNH2. This catalytic pathway, where deprotonation occurs prior to oxidation, leads to an overpotential that is 0.38 V lower compared to the pathway where oxidation precedes proton movement. Under the optimal conditions of 1.0 atm H2 using n-BuNH2 as a base and with added water, a turnover frequency of 58 s(-1) is observed at 23 °C.

  19. A novel branched side-chain-type sulfonated polyimide membrane with flexible sulfoalkyl pendants and trifluoromethyl groups for vanadium redox flow batteries

    Li, Jinchao; Liu, Suqin; He, Zhen; Zhou, Zhi

    2017-04-01

    A novel branched side-chain-type sulfonated polyimide (6F-s-bSPI) membrane with accessible branching agents of melamine, hydrophobic trifluoromethyl groups (sbnd CF3), and flexible sulfoalkyl pendants is prepared by a high-temperature polycondensation and post-sulfonation method for use in vanadium redox flow batteries (VRFBs). The chemical structure of the 6F-s-bSPI membrane is confirmed by ATR-FTIR and 1H NMR spectra. The physico-chemical properties of the as-prepared 6F-s-bSPI membrane are systematically investigated and found to be strongly related to the specially designed structure. The 6F-s-bSPI membrane offers a reduced cost and possesses a significantly lowered vanadium ion permeability (1.18 × 10-7 cm2 min-1) compared to the linear SPI (2.25 × 10-7 cm2 min-1) and commercial Nafion 115 (1.36 × 10-6 cm2 min-1) membranes, prolonging the self-discharge duration of the VRFBs. In addition, the VRFB assembled with a 6F-s-bSPI membrane shows higher coulombic (98.3%-99.7%) and energy efficiencies (88.4%-66.12%) than that with a SPI or Nafion 115 membrane under current densities ranging from 20 to 100 mA cm-2. Moreover, the VRFB with a 6F-s-bSPI membrane delivers a stable cycling performance over 100 cycles with no decline in coulombic and energy efficiencies. These results show that the branched side-chain-type structure is a promising design to prepare excellent proton conductive membranes.

  20. 侧链含有全氟磺酸的聚芳醚砜质子交换膜材料的制备及性能%Synthesis and Properties of Poly (aryl ether sulfones) Functionalized with Pendant Perfluoroalkyl Sulfonic Acid for Proton Exchange Membrane

    王永鹏; 岳喜贵; 庞金辉; 李雪峰; 李娜; 张海博; 姜振华

    2012-01-01

    A novel poly(arylene ether sulfone) with a perfluoroalkyl sulfonic acid pendant ( PES-PSA) was synthesized by Ullman coupling of poly {oxy-4,4'-[2-(4'-bromophenyl ene)biphenylene]oxy-4,4'-diphenyl-sulfone 1 (PES-Br) and potassium 1,1,2,2-tetrafluoro-2-(l ,1,2,2-tetiafluoro-2-iodo-ethoxy)ethane9ulfonate ( PSA-K). The introduction of the perfluoroalkyl sulfonic acids was successfully carried out with high conversion (c. a. 50% ) to yield the desired polymer. Even with a low ion exchange capacity(IEC) of 0.907 meq. / g, PES-PSA exhibited a high proton conductivity of 0.039 S/cm at 80 ℃ under 100% relative humidity. The low IEC makes the membrane own good dimensional stability and thermal stability. Other membrane properties , such as thermal properties and water uptake were also investigated in detail.%利用含溴苯侧基的聚芳醚砜( PES-Br)和1,1,2,2-四氟-2-(1,1,2,2-四氟-2-碘乙氧基)乙烷磺酸钾(PSA-K)进行Ullman偶联反应,制备了新型含全氟磺酸侧链的聚芳醚砜(PES-PSA),全氟磺酸的引入量为50%.在离子交换容量(IEC)为0.907 meq./g,80℃,相对湿度为100%时,PES-PSA质子传导率达到0.039S/cm,表现出较高的质子传导能力.其较低的IEC值使膜材料表现出良好的热稳定性和尺寸稳定性.

  1. Mid-upper-arm-circumference and mid-upper-arm circumference z-score

    Rasmussen, J; Andersen, A; Fisker, A B;

    2012-01-01

    Mid-upper-arm circumference (MUAC) is a simple method of assessing nutritional status in children above 6 months of age. In 2007 World Health Organization (WHO) introduced a MUAC z-score for children above 3 months of age. We evaluated whether MUAC or MUAC z-score had the best ability to identify...

  2. Human microglial cells synthesize albumin in brain.

    Sung-Min Ahn

    Full Text Available Albumin, an abundant plasma protein with multifunctional properties, is mainly synthesized in the liver. Albumin has been implicated in Alzheimer's disease (AD since it can bind to and transport amyloid beta (Abeta, the causative agent of AD; albumin is also a potent inhibitor of Abeta polymerization. Despite evidence of non-hepatic transcription of albumin in many tissues including kidney and pancreas, non-hepatic synthesis of albumin at the protein level has been rarely confirmed. In a pilot phase study of Human Brain Proteome Project, we found evidence that microglial cells in brain may synthesize albumin. Here we report, for the first time, the de novo synthesis of albumin in human microglial cells in brain. Furthermore, we demonstrate that the synthesis and secretion of albumin from microglial cells is enhanced upon microglial activation by Abeta(1-42- or lipopolysaccharide (LPS-treatment. These data indicate that microglial cells may play a beneficial role in AD by secreting albumin that not only inhibits Abeta polymerization but also increases its clearance.

  3. Biogenic synthesized nanoparticles and their applications

    Singh, Abhijeet; Sharma, Madan Mohan

    2016-05-01

    In the present scenario, there are growing concerns over the potential impacts of bioengineered nanoparticles in the health sector. However, our understanding of how bioengineered nanoparticles may affect organisms within natural ecosystems, lags far behind our rapidly increasing ability to engineer novel nanoparticles. To date, research on the biological impacts of bioengineered nanoparticles has primarily consisted of controlled lab studies of model organisms with single species in culture media. Here, we described a cost effective and environment friendly technique for green synthesis of silver nanoparticles. Silver nanoparticles were successfully synthesized from 1 mM AgNO3 via a green synthesis process using leaf extract as reducing as well as capping agent. Nanoparticles were characterized with the help of UV-vis absorption spectroscopy, X-ray diffraction and TEM analysis which revealed the size of nanoparticles of 30-40 nm size. Further the nanoparticles synthesized by green route are found highly toxic against pathogenic bacteria and plant pathogenic fungi viz. Escherichia coli, Pseudomonas syringae and Sclerotiniasclerotiorum. The most important outcome of this work will be the development of value-added products and protection of human health from pathogens viz., bacteria, virus, fungi etc.

  4. Recent Advances in Chemoenzymatic Peptide Syntheses

    Kenjiro Yazawa

    2014-09-01

    Full Text Available Chemoenzymatic peptide synthesis is the hydrolase-catalyzed stereoselective formation of peptide bonds. It is a clean and mild procedure, unlike conventional chemical synthesis, which involves complicated and laborious protection-deprotection procedures and harsh reaction conditions. The chemoenzymatic approach has been utilized for several decades because determining the optimal conditions for conventional synthesis is often time-consuming. The synthesis of poly- and oligopeptides comprising various amino acids longer than a dipeptide continues to pose a challenge owing to the lack of knowledge about enzymatic mechanisms and owing to difficulty in optimizing the pH, temperature, and other reaction conditions. These drawbacks limit the applications of the chemoenzymatic approach. Recently, a variety of enzymes and substrates produced using recombinant techniques, substrate mimetics, and optimal reaction conditions (e.g., frozen aqueous media and ionic liquids have broadened the scope of chemoenzymatic peptide syntheses. In this review, we highlight the recent advances in the chemoenzymatic syntheses of various peptides and their use in developing new materials and biomedical applications.

  5. ANA - A framework for building ATHENA on ARM

    Smith, Joshua Wyatt; Hamilton, Andrew

    2015-10-01

    The ATLAS software framework (ATHENA) is large and dynamic, comprised of around 6.5 million lines of code. It is compiled using the ATLAS monitoring system, NICOS which uses tools and scripts located and tuned for the CERN services, LXPLUS and AFS. Furthermore, the constraints placed on the hardware that the software is based, limits compilations to traditional x86 architecture. With the sudden interest in ARM processors for large scale high energy physics computing, a new system needs to be implemented to build ATHENA versions for ARM, on ARM. This letter serves to introduce a building framework called Atlas Nightly on ARM (ANA). This new framework implements patches to suit the ARM architecture with the goal of a final ATHENA version for ARM.

  6. ARM 7 BASED MP3 PLAYER

    Ashiq V Mehta

    2014-02-01

    Full Text Available MP3 is a patented encoding format for digital audio which uses a form of lossy data compression. It is a common audio format for consumer audio streaming or storage, as well as a de facto standard of digital audio compression for the transfer and playback of music on most digital audio players. Since the MPEG-1 Layer III encoding technology is nowadays widely used it might be interesting to gain knowledge of how this powerful compression/decompression scheme actually functions. The MPEG-1 Layer III is capable of reducing the bit rate with a factor of 12 without almost any audible degradation. Arm7 lpc2148 is arm7tdmi-s core board microcontroller that uses 16/32-bit 64 pin (lqfp microcontroller no.lpc2148 from Philips (nxp.The hardware system of lpc2148 includes the necessary devices within only one mcu has such as usb, adc, dac, timer/counter, pwm, capture, i2c, spi, uart, and etc.

  7. Characterizing Truthful Multi-Armed Bandit Mechanisms

    Babaioff, Moshe; Slivkins, Aleksandrs

    2008-01-01

    We consider a multi-round auction setting motivated by pay-per-click auctions for Internet advertising. In each round the auctioneer selects an advertiser and shows her ad, which is then either clicked or not. An advertiser derives value from clicks; the value of a click is her private information. Initially, neither the auctioneer nor the advertisers have any information about the likelihood of clicks on the advertisements. The auctioneer's goal is to design a (dominant strategies) truthful mechanism that (approximately) maximizes the social welfare. If the advertisers bid their true private values, our problem is equivalent to the "multi-armed bandit problem", and thus can be viewed as a strategic version of the latter. In particular, for both problems the quality of an algorithm can be characterized by "regret", the difference in social welfare between the algorithm and the benchmark which always selects the same "best" advertisement. We investigate how the design of multi-armed bandit algorithms is affect...

  8. ARM Climate Research Facility Annual Report 2004

    Voyles, J.

    2004-12-31

    Like a rock that slowly wears away beneath the pressure of a waterfall, planet earth?s climate is almost imperceptibly changing. Glaciers are getting smaller, droughts are lasting longer, and extreme weather events like fires, floods, and tornadoes are occurring with greater frequency. Why? Part of the answer is clouds and the amount of solar radiation they reflect or absorb. These two factors clouds and radiative transfer represent the greatest source of error and uncertainty in the current generation of general circulation models used for climate research and simulation. The U.S. Global Change Research Act of 1990 established an interagency program within the Executive Office of the President to coordinate U.S. agency-sponsored scientific research designed to monitor, understand, and predict changes in the global environment. To address the need for new research on clouds and radiation, the U.S. Department of Energy (DOE) established the Atmospheric Radiation Measurement (ARM) Program. As part of the DOE?s overall Climate Change Science Program, a primary objective of the ARM Program is improved scientific understanding of the fundamental physics related to interactions between clouds and radiative feedback processes in the atmosphere.

  9. Computing Arm Movements with a Monkey Brainet.

    Ramakrishnan, Arjun; Ifft, Peter J; Pais-Vieira, Miguel; Byun, Yoon Woo; Zhuang, Katie Z; Lebedev, Mikhail A; Nicolelis, Miguel A L

    2015-07-09

    Traditionally, brain-machine interfaces (BMIs) extract motor commands from a single brain to control the movements of artificial devices. Here, we introduce a Brainet that utilizes very-large-scale brain activity (VLSBA) from two (B2) or three (B3) nonhuman primates to engage in a common motor behaviour. A B2 generated 2D movements of an avatar arm where each monkey contributed equally to X and Y coordinates; or one monkey fully controlled the X-coordinate and the other controlled the Y-coordinate. A B3 produced arm movements in 3D space, while each monkey generated movements in 2D subspaces (X-Y, Y-Z, or X-Z). With long-term training we observed increased coordination of behavior, increased correlations in neuronal activity between different brains, and modifications to neuronal representation of the motor plan. Overall, performance of the Brainet improved owing to collective monkey behaviour. These results suggest that primate brains can be integrated into a Brainet, which self-adapts to achieve a common motor goal.

  10. Why START. [Strategic Arms Reduction Talks treaty

    Mendelsohn, J.

    1991-04-01

    Barring some major unexpected downturn in US-Soviet relations, it seems likely that the long-awaited Strategic Arms Reduction Talks (START) treaty will be signed sometime in 1991. Under negotiation for the past nine years, public acceptance and Senate approval of a START treaty will be facilitated by the generally less confrontational East-West relationship which has evolved over that time, by the growing constraints on the US defense budget, and by the obvious merits of the treaty itself. Not only will the nearly complete START treaty be an extremely useful and powerful arms control agreement, it is also decidedly advantageous to US security interests. First and foremost, a START treaty will cap and reduce the steady buildup of nuclear weapons that has characterized the last 30 years of the US-Soviet strategic relationship. As a result of the basic outline originally agreed to at the Reykjavik summit, START will take a 25 to 35 percent bite out of existing nuclear arsenals, impose approximately a 50 percent cut in overall Soviet ballistic missile warheads and throw-weight (lifting power or payload capacity), and produce an exact 50 percent cut in Soviet SS-18 missiles.

  11. The Phoenix Mars Lander Robotic Arm

    Bonitz, Robert; Shiraishi, Lori; Robinson, Matthew; Carsten, Joseph; Volpe, Richard; Trebi-Ollennu, Ashitey; Arvidson, Raymond E.; Chu, P. C.; Wilson, J. J.; Davis, K. R.

    2009-01-01

    The Phoenix Mars Lander Robotic Arm (RA) has operated for over 150 sols since the Lander touched down on the north polar region of Mars on May 25, 2008. During its mission it has dug numerous trenches in the Martian regolith, acquired samples of Martian dry and icy soil, and delivered them to the Thermal Evolved Gas Analyzer (TEGA) and the Microscopy, Electrochemistry, and Conductivity Analyzer (MECA). The RA inserted the Thermal and Electrical Conductivity Probe (TECP) into the Martian regolith and positioned it at various heights above the surface for relative humidity measurements. The RA was used to point the Robotic Arm Camera to take images of the surface, trenches, samples within the scoop, and other objects of scientific interest within its workspace. Data from the RA sensors during trenching, scraping, and trench cave-in experiments have been used to infer mechanical properties of the Martian soil. This paper describes the design and operations of the RA as a critical component of the Phoenix Mars Lander necessary to achieve the scientific goals of the mission.

  12. Ad-hoc Network Based on ARM-Linux%基于ARM-Linux的Ad-hoc组网

    王晓华; 贾继洋

    2014-01-01

    Aiming to solve the problem of the contemporary communication system in the absence of any network, a new scheme of the Ad-hoc network based on ARM-Linux system is designed. Firstly, this paper introduces the transportation of the Linux2.6.36 and the driver of RT3070 on ARM11 platform. Then based on socket programming in TCP/IP, program designing of communication and tests are conducted on the ARM-Linux platform. Results have proved that the Ad-hoc network can use the least resources and costs to achieve reliable high rate communication. It is significant for practical application.%针对传统通信系统不能满足在无任何网络情况下的通信需求现状,设计并实现了一种由 ARM-Linux 系统及其外围部件组成的无线自组网(Ad-hoc)的通信方案.在 ARM11平台上完成了 Linux2.6.36操作系统和RT3070无线通信模块的驱动程序移植.利用基于TCP/IP协议的socket编程,编写测试程序,进行节点间无线通信传输实验.实验结果表明:本文搭建的Ad-hoc网络,可以用最少的资源和成本,实现节点间可靠的无线高速率通信,具有现实应用意义.

  13. ARM Operations and Engineering Procedure Mobile Facility Site Startup

    Voyles, Jimmy W

    2015-05-01

    This procedure exists to define the key milestones, necessary steps, and process rules required to commission and operate an Atmospheric Radiation Measurement (ARM) Mobile Facility (AMF), with a specific focus toward on-time product delivery to the ARM Data Archive. The overall objective is to have the physical infrastructure, networking and communications, and instrument calibration, grooming, and alignment (CG&A) completed with data products available from the ARM Data Archive by the Operational Start Date milestone.

  14. The Determinants of Arms Spending in South America

    2013-01-01

    In recent years, South America has witnessed a large increase in arms purchases. Nonetheless, there are important intraregional differences in terms of the allocation of resources for weapons acquisitions. How can we account for these disparities? Mainstream literature suggests that levels of arms importation depend on either the size of the defense budget or the perception of threat. In contrast, this article contends that the level of spending on arms is mainly determined by: (a) the expans...

  15. Hardware And Software For Development Of Robot Arms

    Usikov, Daniel

    1995-01-01

    System of modular, reusable hardware and software assembled for use in developing remotely controlled robotic arms. Includes (1) central computer and peripheral equipment at control and monitoring station and (2) remote mechanical platform that supports robotic arm. Central computer controls motor drives of robotic arm, but optically, platform holds on-board computer for autonomous operation. Consists mostly of commercial hardware and software. Simulated results of commands viewed in three dimensions.

  16. A Survey of Interstellar Gas Inside the 3 KPC Arm

    Massa, Derck L.

    We are requesting 5 US1 shifts to obtain high dispersion spectra Of B stars in the direction of the 3 kpc arm. The interstellar absorption along these lines of sight will be compared to models for the absorbing gas in order to determine whether additional absorption is present inside the 3 kpc arm. This information will help to distinguish between the two competing theories for the formation of the arm.

  17. System For Research On Multiple-Arm Robots

    Backes, Paul G.; Hayati, Samad; Tso, Kam S.; Hayward, Vincent

    1991-01-01

    Kali system of computer programs and equipment provides environment for research on distributed programming and distributed control of coordinated-multiple-arm robots. Suitable for telerobotics research involving sensing and execution of low level tasks. Software and configuration of hardware designed flexible so system modified easily to test various concepts in control and programming of robots, including multiple-arm control, redundant-arm control, shared control, traded control, force control, force/position hybrid control, design and integration of sensors, teleoperation, task-space description and control, methods of adaptive control, control of flexible arms, and human factors.

  18. A modest proposal for dropping poor arms in clinical trials.

    Proschan, Michael A; Dodd, Lori E

    2014-08-30

    This paper presents a simple procedure for clinical trials comparing several arms with control. Demand for streamlining the evaluation of new treatments has led to phase III clinical trials with more arms than would have been used in the past. In such a setting, it is reasonable that some arms may not perform as well as an active control. We introduce a simple procedure that takes advantage of negative results in some comparisons to lessen the required strength of evidence for other comparisons. We evaluate properties analytically and use them to support claims made about multi-arm multi-stage designs.

  19. Experimental validation of flexible robot arm modeling and control

    Ulsoy, A. Galip

    1989-01-01

    Flexibility is important for high speed, high precision operation of lightweight manipulators. Accurate dynamic modeling of flexible robot arms is needed. Previous work has mostly been based on linear elasticity with prescribed rigid body motions (i.e., no effect of flexible motion on rigid body motion). Little or no experimental validation of dynamic models for flexible arms is available. Experimental results are also limited for flexible arm control. Researchers include the effects of prismatic as well as revolute joints. They investigate the effect of full coupling between the rigid and flexible motions, and of axial shortening, and consider the control of flexible arms using only additional sensors.

  20. Selection, training and retention of an armed private security department.

    Hollar, David B

    2009-01-01

    To arm or not to arm security officers? One hospital which has opted for arming its officers is Cook Children's Healthcare System, Fort Worth, TX, an integrated pediatric healthcare facility with over 4000 employees. Because of its location in a major metropolitan area and based on several factors including demographics, exterior risk assessments and crime statistics, the hospital's Administration and its Risk Manager supported the decision to operate as an armed security force, according to the author. In this article he shares its current program and presents some thoughts and ideas that may benefit others who are considering this important step.

  1. Simulation of Octopus Arm Based on Coupled CPGs

    Juan Tian

    2015-01-01

    Full Text Available The octopus arm has attracted many researchers’ interests and became a research hot spot because of its amazing features. Several dynamic models inspired by an octopus arm are presented to realize the structure with a large number of degrees of freedom. The octopus arm is made of a soft material introducing high-dimensionality, nonlinearity, and elasticity, which makes the octopus arm difficult to control. In this paper, three coupled central pattern generators (CPGs are built and a 2-dimensional dynamic model of the octopus arm is presented to explore possible strategies of the octopus movement control. And the CPGs’ signals treated as activation are added on the ventral, dorsal, and transversal sides, respectively. The effects of the octopus arm are discussed when the parameters of the CPGs are changed. Simulations show that the octopus arm movements are mainly determined by the shapes of three CPGs’ phase diagrams. Therefore, some locomotion modes are supposed to be embedded in the neuromuscular system of the octopus arm. And the octopus arm movements can be achieved by modulating the parameters of the CPGs. The results are beneficial for researchers to understand the octopus movement further.

  2. Determining loads on the arms of a milling longwall shearer

    Krauze, K. (Akademia Gorniczo-Hutnicza, Cracow (Poland). Instytut Maszyn Gorniczych, Przerobczych i Automatyki)

    1992-07-01

    Derives formulae for calculating forces in the hydraulic cylinder of a shearer arm and reactions in cylinder joints at the points of mounting to the shearer body. Force variation trends are shown for front and rear arms of ripping heads of the KGS and KWB shearer loaders equipped with cutters or discs. A computer program developed on the basis of the calculation methods presented allows the loads on the arms to be determined for various kinematic configurations and design parameters of a shearer. It was found that cutting tools of the disc type cause increased load variations on shearer arms.

  3. Novel 4-Arm Poly(Ethylene Glycol-Block-Poly(Anhydride-Esters Amphiphilic Copolymer Micelles Loading Curcumin: Preparation, Characterization, and In Vitro Evaluation

    Li Lv

    2013-01-01

    Full Text Available A novel 4-arm poly(ethylene glycol-block-poly(anhydride-esters amphiphilic copolymer (4-arm PEG-b-PAE was synthesized by esterization of 4-arm poly(ethylene glycol and poly(anhydride-esters which was obtained by melt polycondensation of α-, ω-acetic anhydride terminated poly(L-lactic acid. The obtained 4-arm PEG-b-PAE was characterized by 1H-NMR and gel permeation chromatography. The critical micelle concentration of 4-arm PEG-b-PAE was 2.38 μg/mL. The curcumin-loaded 4-arm PEG-b-PAE micelles were prepared by a solid dispersion method and the drug loading content and encapsulation efficiency of the micelles were 7.0% and 85.2%, respectively. The curcumin-loaded micelles were spherical with a hydrodynamic diameter of 151.9 nm. Curcumin was encapsulated within 4-arm PEG-b-PAE micelles amorphously and released from the micelles, faster in pH 5.0 than pH 7.4, presenting one biphasic drug release pattern with rapid release at the initial stage and slow release later. The hemolysis rate of the curcumin-loaded 4-arm PEG-b-PAE micelles was 3.18%, which was below 5%. The IC50 value of the curcumin-loaded micelles against Hela cells was 10.21 μg/mL, lower than the one of free curcumin (25.90 μg/mL. The cellular uptake of the curcumin-loaded micelles in Hela cell increased in a time-dependent manner. The curcumin-loaded micelles could induce G2/M phase cell cycle arrest and apoptosis of Hela cells.

  4. Simplification of Methods for PET Radiopharmaceutical Syntheses

    Kilbourn, Michael, R.

    2011-12-27

    In an attempt to develop simplified methods for radiochemical synthesis of radiopharmaceuticals useful in Positron Emission Tomography (PET), current commercially available automated synthesis apparati were evaluated for use with solid phase synthesis, thin-film techniques, microwave-accelerated chemistry, and click chemistry approaches. Using combinations of these techniques, it was shown that these automated synthesis systems can be simply and effectively used to support the synthesis of a wide variety of carbon-11 and fluorine-18 labeled compounds, representing all of the major types of compounds synthesized and using all of the common radiochemical precursors available. These techniques are available for use to deliver clinically useful amounts of PET radiopharmaceuticals with chemical and radiochemical purities and high specific activities, suitable for human administration.

  5. The Complexity of Synthesizing Uniform Strategies

    Bastien Maubert

    2013-03-01

    Full Text Available We investigate uniformity properties of strategies. These properties involve sets of plays in order to express useful constraints on strategies that are not μ-calculus definable. Typically, we can state that a strategy is observation-based. We propose a formal language to specify uniformity properties, interpreted over two-player turn-based arenas equipped with a binary relation between plays. This way, we capture e.g. games with winning conditions expressible in epistemic temporal logic, whose underlying equivalence relation between plays reflects the observational capabilities of agents (for example, synchronous perfect recall. Our framework naturally generalizes many other situations from the literature. We establish that the problem of synthesizing strategies under uniformity constraints based on regular binary relations between plays is non-elementary complete.

  6. Energy storage materials synthesized from ionic liquids.

    Gebresilassie Eshetu, Gebrekidan; Armand, Michel; Scrosati, Bruno; Passerini, Stefano

    2014-12-01

    The advent of ionic liquids (ILs) as eco-friendly and promising reaction media has opened new frontiers in the field of electrochemical energy storage. Beyond their use as electrolyte components in batteries and supercapacitors, ILs have unique properties that make them suitable as functional advanced materials, media for materials production, and components for preparing highly engineered functional products. Aiming at offering an in-depth review on the newly emerging IL-based green synthesis processes of energy storage materials, this Review provides an overview of the role of ILs in the synthesis of materials for batteries, supercapacitors, and green electrode processing. It is expected that this Review will assess the status quo of the research field and thereby stimulate new thoughts and ideas on the emerging challenges and opportunities of IL-based syntheses of energy materials.

  7. Structure of the enzymatically synthesized fructan inulin

    Heyer, A.G.; Schroeer, B. [Max-Planck-Institut fuer Molekulare Pflanzenphysiologie, Karl-Liebknecht-Str. 25, 14476 Golm (Germany); Radosta, S. [Fraunhofer-Institut fuer Angewandte Polymerforschung, Postfach 126, 14504 Teltow (Germany); Wolff, D.; Czapla, S.; Springer, J. [Technische Universitaet Berlin, FG Makromolekulare Chemie, Str. des 17. Juni 135, 10623 Berlin (Germany)

    1998-12-15

    Construction, purification and characterization of a fusion protein of maltose-binding protein of Escherichia coli and the fructosyltransferase of Streptococcus mutans is described. With the purified protein, in vitro synthesis of inulin was performed. The obtained polysaccharide was characterized by high-performance size-exclusion chromatography (HPSEC) and static light scattering (SLS) in dilute aqueous and dimethyl sulfoxide solution. For all samples very high molecular weights between 60x10{sup 6} and 90x10{sup 6} g/mol and a remarkable small polydispersity index of 1.1 have been determined. Small root-mean-square radii of gyration point to a compact conformation in dilute solution. No difference between native and enzymatically synthesized inulin was observed by X-ray powder diffraction and thermoanalysis of solid samples. (Copyright (c) 1998 Elsevier Science B.V., Amsterdam. All rights reserved.)

  8. Methods for synthesizing metal oxide nanowires

    Sunkara, Mahendra Kumar; Kumar, Vivekanand; Kim, Jeong H.; Clark, Ezra Lee

    2016-08-09

    A method of synthesizing a metal oxide nanowire includes the steps of: combining an amount of a transition metal or a transition metal oxide with an amount of an alkali metal compound to produce a mixture; activating a plasma discharge reactor to create a plasma discharge; exposing the mixture to the plasma discharge for a first predetermined time period such that transition metal oxide nanowires are formed; contacting the transition metal oxide nanowires with an acid solution such that an alkali metal ion is exchanged for a hydrogen ion on each of the transition metal oxide nanowires; and exposing the transition metal oxide nanowires to the plasma discharge for a second predetermined time period to thermally anneal the transition metal oxide nanowires. Transition metal oxide nanowires produced using the synthesis methods described herein are also provided.

  9. Method and apparatus for synthesizing hydrocarbons

    Colmenares, C.A.; Somorjai, G.A.; Maj, J.J.

    1985-04-16

    A method and apparatus for synthesizing a mixture of aliphatic alcohols having five carbons or less is disclosed. An equal molar ratio of CO and H/sub 2/ gases is caused to pass through a ThO/sub 2/ catalyst having a surface area of about 80 to 125 m/sup 2//g. The catalyst further optionally includes Na ions present as substitutional cations in an amount of about 5 to 10 atom %. At a temperature of about 570 to 630/sup 0/K, and at pressures of about 20 to 50 atm, methanol and isobutanol are the predominant products and are produced in amounts of about 90 wt % of the total hydrocarbon mixture. 6 figs.

  10. Using quantum mechanics to synthesize electronic devices

    Schmidt, Petra; Levi, Anthony

    2005-03-01

    Adaptive quantum design [1] has been used to explore the possibility of creating new classes of electronic semiconductor devices. We show how non-equilibrium electron transmission through a synthesized conduction band potential profile can be used to obtain a desired current - voltage characteristic. We illustrate our methodology by designing a two-terminal linear resistive element in which current is limited by quantum mechanical transmission through a potential profile and power is dissipated non-locally in the electrodes. As electronic devices scale to dimensions in which the physics of operation is dominated by quantum mechanical effects, classical designs fail to deliver the desired functionality. Our device synthesis approach is a way to realize device functionality that may not otherwise be achieved. [1] Y.Chen, R.Yu, W.Li, O.Nohadani, S.Haas, A.F.J. Levi, Journal of Applied Physics, Vol.94, No.9, p6065, 2003

  11. Syntheses and Structure Determinations of Calcium Thiolates.

    Chadwick, Scott; Englich, Ulrich; Noll, Bruce; Ruhlandt-Senge, Karin

    1998-09-07

    The exploration of synthetic methodologies toward heavy alkaline-earth chalcogenolates resulted in the preparation and structural characterization of a family of calcium thiolates, including [Ca(SC(6)F(5))(2)(py)(4)], 1 (py = pyridine), the separated ion-triple [Ca(18-crown-6)(NH(3))(3))][SMes](2).2THF, 2 (Mes = 2,4,6-tBu(3)C(6)H(2)), and the contact triple [Ca(18-crown-6)(SMes)(2)].THF, 3. Compound 1 was prepared by treating [Ca(N(SiMe(3))(2))(2)](2) with 4 equiv of HSC(6)F(5) under addition of pyridine. The thiolates 2 and 3 were synthesized by treatment of calcium metal dissolved in dry, liquid NH(3) under addition of 2 equiv of HSMes and crown ether or, alternatively, by the reduction of MesSSMes with calcium metal in dry, liquid ammonia. We also report two reaction products isolated during attempted calcium thiolate syntheses: [CaBr(4)(THF)(2)(&mgr;(2)-Li)(2)(THF)(4)], 4, isolated as the product of a salt elimination reaction between CaBr(2) and 2 equiv of [Li(THF)(n)()S-2,4,6-(i)()Pr(3)C(6)H(2)](m)(). [(NH(4))(py)(SC(6)F(5))], 5, was obtained as the sole product in the reaction of metallic calcium with HSC(6)F(5) in liquid ammonia under addition of pyridine. All compounds were characterized by single-crystal X-ray crystallography in addition to IR and NMR spectroscopy.

  12. National Gas Survey. Synthesized gaseous hydrocarbon fuels

    None

    1978-06-01

    The supply-Technical Advisory Task Force-Synthesized Gaseous Hydrocarbon Fuels considered coal, hydrocarbon liquids, oil shales, tar sands, and bioconvertible materials as potential feedstocks for gaseous fuels. Current status of process technology for each feedstock was reviewed, economic evaluations including sensitivity analysis were made, and constraints for establishment of a synthesized gaseous hydrocarbon fuels industry considered. Process technology is presently available to manufacture gaseous hydrocarbon fuels from each of the feedstocks. In 1975 there were eleven liquid feedstock SNG plants in the United States having a capacity of 1.1 billion SCFD. There can be no contribution of SNG before 1982 from plants using feedstocks other than liquids because there are no plants in operation or under construction as of 1977. Costs for SNG are higher than current regulated prices for U.S. natural gas. Because of large reserves, coal is a prime feedstock candidate although there are major constraints in the area of coal leases, mining and water permits, and others. Commercial technology is available and several new gasification processes are under development. Oil shale is also a feedstock in large supply and commercial process technology is available. There are siting and permit constraints, and water availability may limit the ultimate size of an oil shale processing industry. Under projected conditions, bioconvertible materials are not expected to support the production of large quantities of pipeline quality gas during the next decade. Production of low or medium Btu gas from municipal solid wastes can be expected to be developed in urban areas in conjunction with savings in disposal costs. In the economic evaluations presented, the most significant factor for liquid feedstock plants is the anticipated cost of feedstock and fuel. The economic viability of plants using other feedstocks is primarily dependent upon capital requirements.

  13. The ARM West Antarctic Radiation Experiment (AWARE)

    Lubin, Dan; Bromwich, David; Vogelmann, Andrew; Verlinde, Johannes; Russell, Lynn

    2016-04-01

    West Antarctica is one of the most rapidly warming regions on Earth, and its changing climate in both atmosphere and ocean is linked to loss of Antarctic ice mass and global sea level rise. The specific mechanisms for West Antarctic Ice Sheet (WAIS) warming are not fully understood, but are hypothesized to involve linkage between moisture from Southern Ocean storm tracks and the surface energy balance over the WAIS, and related teleconnections with subtropical and tropical meteorology. This present lack of understanding has motivated a climate science and cloud physics campaign jointly supported by the US National Science Foundation (NSF) and Department of Energy (DOE), called the Atmospheric Radiation Measurement Program (ARM) West Antarctic Radiation Experiment (AWARE). The DOE's second ARM Mobile Facility (AMF2) was deployed to McMurdo Station on Ross Island in November 2015 and will operate through December 2016. The AMF2 includes (1) cloud research radars, both scanning and zenith, operating in the Ka- and X-bands, (2) high spectral resolution and polarized micropulse lidars, and (3) a suite of shortwave and longwave broadband and spectral radiometers. A second suite of instruments is deployed at the WAIS Divide Ice Camp on the West Antarctic plateau during December 2015 and January 2016. The WAIS instrument suite provides (1) measurement of all surface energy balance components, (2) a polarized micropulse lidar and shortwave spectroradiometer, (3) microwave total water column measurement, and (4) four times daily rawinsonde launches which are the first from West Antarctica since 1967. There is a direct linkage between the WAIS instrument suite and the AMF2 at McMurdo, in that air masses originating in Southern Ocean storm tracks that are driven up over the WAIS often subsequently descend over the Ross Ice Shelf and arrive at Ross Island. Preliminary data are already illustrating the prevalence of mixed-phase clouds and their role in the surface energy balance

  14. Enantioselective catalytic syntheses of alpha-branched chiral amines

    Brase, S.; Baumann, T.; Dahmen, S.

    2007-01-01

    Chiral amines play a pivotal role in fine chemical and natural product syntheses and the design of novel materials.......Chiral amines play a pivotal role in fine chemical and natural product syntheses and the design of novel materials....

  15. Synthesis and characterization of three-arm star-shaped polyethylene glycols with 1,1,1-trihydroxmethylpropane as cores

    Kangcheng WANG; Wei HUANG; Yongfeng ZHOU; Deyue YAN

    2008-01-01

    A small molecule core (TMP,SK3) with three terminal carboxyl groups was synthesized successfully by the reaction of 1,1,1,trihydroxymethylpropane with the excessive sebacic acid diacetic anhydride (SK). Then, the core molecule was used as a coupling agent to condensate with polyethylene glycols (PEG) of different molecular weights or polyethylene glycol monomethyl ether (PEGm) in the presence of stannous octoate as catalyst and diphenyl ether as an azeotropic agent to remove water. Thus, the three,arm star,shaped PEGs was obtained successfully and characterized by IH,NMR,DSC, GPC and XRD etc. DSC measurements indicate that the crystallizing and the melting temperatures of the three,arm star,shaped PEGs were different from those of the corresponding linear PEG because the existence of TMP,SK3 altered its crystallizing velocity and perfect degree of crystallization.

  16. Arm-in-Arm Response Regulator Dimers Promote Intermolecular Signal Transduction

    Baker, Anna W.; Satyshur, Kenneth A.; Moreno Morales, Neydis

    2016-01-01

    ABSTRACT Bacteriophytochrome photoreceptors (BphPs) and their cognate response regulators make up two-component signal transduction systems which direct bacteria to mount phenotypic responses to changes in environmental light quality. Most of these systems utilize single-domain response regulators to transduce signals through unknown pathways and mechanisms. Here we describe the photocycle and autophosphorylation kinetics of RtBphP1, a red light-regulated histidine kinase from the desert bacterium Ramlibacter tataouinensis. RtBphP1 undergoes red to far-red photoconversion with rapid thermal reversion to the dark state. RtBphP1 is autophosphorylated in the dark; this activity is inhibited under red light. The RtBphP1 cognate response regulator, the R. tataouinensis bacteriophytochrome response regulator (RtBRR), and a homolog, AtBRR from Agrobacterium tumefaciens, crystallize unexpectedly as arm-in-arm dimers, reliant on a conserved hydrophobic motif, hFWAhL (where h is a hydrophobic M, V, L, or I residue). RtBRR and AtBRR dimerize distinctly from four structurally characterized phytochrome response regulators found in photosynthetic organisms and from all other receiver domain homodimers in the Protein Data Bank. A unique cacodylate-zinc-histidine tag metal organic framework yielded single-wavelength anomalous diffraction phases and may be of general interest. Examination of the effect of the BRR stoichiometry on signal transduction showed that phosphorylated RtBRR is accumulated more efficiently than the engineered monomeric RtBRR (RtBRRmon) in phosphotransfer reactions. Thus, we conclude that arm-in-arm dimers are a relevant signaling intermediate in this class of two-component regulatory systems. IMPORTANCE BphP histidine kinases and their cognate response regulators comprise widespread red light-sensing two-component systems. Much work on BphPs has focused on structural understanding of light sensing and on enhancing the natural infrared fluorescence of these

  17. Octopus-inspired multi-arm robotic swimming.

    Sfakiotakis, M; Kazakidi, A; Tsakiris, D P

    2015-05-13

    The outstanding locomotor and manipulation characteristics of the octopus have recently inspired the development, by our group, of multi-functional robotic swimmers, featuring both manipulation and locomotion capabilities, which could be of significant engineering interest in underwater applications. During its little-studied arm-swimming behavior, as opposed to the better known jetting via the siphon, the animal appears to generate considerable propulsive thrust and rapid acceleration, predominantly employing movements of its arms. In this work, we capture the fundamental characteristics of the corresponding complex pattern of arm motion by a sculling profile, involving a fast power stroke and a slow recovery stroke. We investigate the propulsive capabilities of a multi-arm robotic system under various swimming gaits, namely patterns of arm coordination, which achieve the generation of forward, as well as backward, propulsion and turning. A lumped-element model of the robotic swimmer, which considers arm compliance and the interaction with the aquatic environment, was used to study the characteristics of these gaits, the effect of various kinematic parameters on propulsion, and the generation of complex trajectories. This investigation focuses on relatively high-stiffness arms. Experiments employing a compliant-body robotic prototype swimmer with eight compliant arms, all made of polyurethane, inside a water tank, successfully demonstrated this novel mode of underwater propulsion. Speeds of up to 0.26 body lengths per second (approximately 100 mm s(-1)), and propulsive forces of up to 3.5 N were achieved, with a non-dimensional cost of transport of 1.42 with all eight arms and of 0.9 with only two active arms. The experiments confirmed the computational results and verified the multi-arm maneuverability and simultaneous object grasping capability of such systems.

  18. Well ARMed and FiRM

    Rasmussen, Kourosh Marjani; Zenios, Stavros A.

    2007-01-01

    or the homeowner's situation warrants it. And while, traditionally, a single mortgage loan would serve borrower needs, today it appears that a portfolio of loans may satisfy much better the mortgage needs of the individual and his or her appetite for risk. In this paper we develop a model for the diversification...... of mortgage loans of a homeowner and apply it to data from the Danish market. Even in the presence of mortgage origination costs it is shown that most risk averse homeowners will do well to consider a diversified portfolio of both fixed (FRM) and adjustable (ARM) rate mortgages. This is particularly so if one...... takes, unavoidably, a long term perspective in financing the purchase of a home through a mortgage loan....

  19. Plants versus pathogens: an evolutionary arms race.

    Anderson, Jonathan P; Gleason, Cynthia A; Foley, Rhonda C; Thrall, Peter H; Burdon, Jeremy B; Singh, Karam B

    2010-05-20

    The analysis of plant-pathogen interactions is a rapidly moving research field and one that is very important for productive agricultural systems. The focus of this review is on the evolution of plant defence responses and the coevolution of their pathogens, primarily from a molecular-genetic perspective. It explores the evolution of the major types of plant defence responses including pathogen associated molecular patterns and effector triggered immunity as well as the forces driving pathogen evolution, such as the mechanisms by which pathogen lineages and species evolve. Advances in our understanding of plant defence signalling, stomatal regulation, R gene-effector interactions and host specific toxins are used to highlight recent insights into the coevolutionary arms race between pathogens and plants. Finally, the review considers the intriguing question of how plants have evolved the ability to distinguish friends such as rhizobia and mycorrhiza from their many foes.

  20. Cloud and Star Formation in Spiral Arms

    Dobbs, Clare

    2014-01-01

    We present the results from simulations of GMC formation in spiral galaxies. First we discuss cloud formation by cloud-cloud collisions, and gravitational instabilities, arguing that the former is prevalent at lower galactic surface densities and the latter at higher. Cloud masses are also limited by stellar feedback, which can be effective before clouds reach their maximum mass. We show other properties of clouds in simulations with different levels of feedback. With a moderate level of feedback, properties such as cloud rotations and virial parameters agree with observations. Without feedback, an unrealistic population of overly bound clouds develops. Spiral arms are not found to trigger star formation, they merely gather gas into more massive GMCs. We discuss in more detail interactions of clouds in the ISM, and argue that these are more complex than early ideas of cloud-cloud collisions. Finally we show ongoing work to determine whether the Milky Way is a flocculent or grand design spiral.

  1. Hot Galactic Arms Point To Vicious Cycle

    2001-12-01

    NASA's Chandra X-ray Observatory has revealed the aftermath of a titanic explosion that wracked the elliptical galaxy known as NGC 4636. This eruption could be the latest episode in a cycle of violence that is triggered by gas falling into a central massive black hole. Chandra's images of NGC 4636 show spectacular symmetric arms, or arcs, of hot gas extending 25,000 light years into a huge cloud of multimillion-degree-Celsius gas that envelopes the galaxy. At a temperature of 10 million degrees, the arms are 30 percent hotter than the surrounding gas cloud. "The temperature jump, together with the symmetry and scale of the arms, suggests that we are observing the effects of a tremendous outburst that occurred in the center of the galaxy," said Christine Jones of the Harvard-Smithsonian Center for Astrophysics in Cambridge, Mass., lead author of a paper on these observations scheduled for publication in Astrophysical Journal Letters. "The energy of this explosion would be the equivalent of several hundred thousand supernovas." The arms appear to be the leading edges of a galaxy-sized shock wave that is racing outward at 700 kilometers per second, or 1.6 million miles per hour. At this speed, it would take 3 million years for the structures to attain their present size. Cavities detected in the hot gas cloud to the east and west of the center of the galaxy support the shockwave explanation. The authors suggest that the explosion is part of a majestic cosmic feedback process that keeps the galaxy in a state of turmoil. Over a period of a few million years, a hot gas cloud that envelops the stars in the galaxy cools and falls inward toward a central, massive black hole. The feeding of the black hole by the infalling material leads to an explosion that heats the hot gaseous envelope, starting the cycle anew. NGC 4636 NGC 4636 Background Subtracted This feedback cycle may explain one puzzling feature of the galaxy - the lack of a strong radio source of the type that is

  2. Tolerance at arm's length: the Dutch experience.

    Schuijer, J

    1990-01-01

    With respect to pedophilia and the age of consent, the Netherlands warrants special attention. Although pedophilia is not as widely accepted in the Netherlands as sometimes is supposed, developments in the judicial practice showed a growing reservedness. These developments are a spin-off of related developments in Dutch society. The tolerance in the Dutch society has roots that go far back in history and is also a consequence of the way this society is structured. The social changes of the sixties and seventies resulted in a "tolerance at arm's length" for pedophiles, which proved to be deceptive when the Dutch government proposed to lower the age of consent in 1985. It resulted in a vehement public outcry. The prevailing sex laws have been the prime target of protagonists of pedophile emancipation. Around 1960, organized as a group, they started to undertake several activities. In the course of their existence, they came to redefine the issue of pedophilia as one of youth emancipation.

  3. Study on the collision detection method between the 2-arm drill rig arms and the roadway

    Fuxiang ZHANG

    2015-12-01

    Full Text Available In order to achieve the automation drilling of the improved CMJ2-27 drill, kinematic analysis of the drill rig is conducted aiming the collision between the arms and the roadway during the operation process. By suing the Denavit-Hartenberg (D-H method, the transformation matrix of coordinate system is obtained, then the coordinates of each joint and the ends are derived. The collision detection approach between the arm and the roadway is given. Theoretical calculation and the motion simulation experiment are conducted by using the detection method for a 88-hole drilling program for a mine. The research results show that the method is feasible and has the characteristics of simple procedures and high efficiency.

  4. The International Arms Control and Disarmament Situation in 2015

    He Yidan; Yu Xiaoling

    2016-01-01

    In 2015,the situation of the international arms control and disarmament was in the overall stability,the United States and Russia continued to promote the performance process of the Strategic Arms Reduction Treaty(New START),the final agreement on the Iran nuclear issue was signed.But the ninth Review

  5. Rehabilitation robotics : stimulating restoration of arm function after stroke

    Prange, Grada Berendina

    2009-01-01

    Stroke is a major cause of permanent disability, due to neurological damage in the brain. As a consequence, arm and hand function may be compromised: 60% of stroke patients experiences serious limitations in daily life due to reduced arm and hand function. To minimize such limitations, patients rece

  6. Satellite data sets for the atmospheric radiation measurement (ARM) program

    Shi, L.; Bernstein, R.L. [SeaSpace Corp., San Diego, CA (United States)

    1996-04-01

    This abstract describes the type of data obtained from satellite measurements in the Atmospheric Radiation Measurement (ARM) program. The data sets have been widely used by the ARM team to derive cloud-top altitude, cloud cover, snow and ice cover, surface temperature, water vapor, and wind, vertical profiles of temperature, and continuoous observations of weather needed to track and predict severe weather.

  7. Arm and hand skills: Training preferences after stroke

    Timmermans, A.A.A.; Seelen, H.A.M.; Willmann, R.D.; Bakx, W.; Ruyter, B.E.R. de; Lanfermann, G.; Kingma, H.

    2009-01-01

    Purpose. An increasing demand for training after stroke has brought about the need to develop rehabilitation technology. This article reports an inquiry into skill preferences of persons after stroke regarding arm-hand training and examines the relationship between the use of the affected arm and th

  8. Why and how the EU should act on armed drones

    Martins, Bruno Oliveira; Backhaus, Benedikt

    2015-01-01

    This article systematizes the reasons that demand EU action on the issue of armed drones. It argues that a clear positioning of Brussels is required due to consistency with former practices in similar events and fundamental vectors of EU foreign and security policy, as well as legal and strategic...... position itself in the international debate on the regulation of armed drones....

  9. Modelling and control of two coordinated robot arms

    Tarn, T. J.; Yun, X.; Bejczy, A. K.

    1988-01-01

    Two coordinated robot arms are modeled by considering the two arms as working on the same object simultaneously and as a closed kinematic chain. In both formulations, a novel dynamic control method is used which is based on feedback linearization and simultaneous output decoupling.

  10. On galaxy spiral arms' nature as revealed by rotation frequencies

    Roca-Fabrega, Santi; Valenzuela, Octavio; Figueras, Francesca; Romero-Gomez, Merce; Velazquez, Hector; Antoja Castelltort, Teresa; Pichardo, Barbara

    2013-01-01

    High-resolution N-body simulations using different codes and initial condition techniques reveal two different behaviours for the rotation frequency of transient spiral arms like structures. Whereas unbarred discs present spiral arms nearly corotating with disc particles, strong barred models (bulge

  11. armA and aminoglycoside resistance in Escherichia coli.

    González-Zorn, Bruno; Teshager, Tirushet; Casas, María; Porrero, María C; Moreno, Miguel A; Courvalin, Patrice; Domínguez, Lucas

    2005-06-01

    We report armA in an Escherichia coli pig isolate from Spain. The resistance gene was borne by self-transferable IncN plasmid pMUR050. Molecular analysis of the plasmid and of the armA locus confirmed the spread of this resistance determinant.

  12. armA and Aminoglycoside Resistance in Escherichia coli

    González-Zorn, Bruno; Teshager, Tirushet; Casas, María; Porrero, María C.; Moreno, Miguel A.; Courvalin, Patrice; Domínguez, Lucas

    2005-01-01

    We report armA in an Escherichia coli pig isolate from Spain. The resistance gene was borne by self-transferable IncN plasmid pMUR050. Molecular analysis of the plasmid and of the armA locus confirmed the spread of this resistance determinant.

  13. Reading and Readability Research in the Armed Services. Final Report.

    Sticht, Thomas G., Ed.; Zapf, Diana Welty, Ed.

    The Conference on Reading and Readability Research in the Armed Services brought together reading, technical writing, and readability experts from civilian research and development (R & D) centers with R & D specialists from the armed services for discussion of reading and text-design problems in the military. This report of the proceedings…

  14. Stellar dynamics around transient co-rotating spiral arms

    Cropper M.

    2012-02-01

    Full Text Available Spiral density wave theory attempts to describe the spiral pattern in spiral galaxies in terms of a long-lived wave structure with a constant pattern speed in order to avoid the winding dilemma. The pattern is consequently a rigidly rotating, long-lived feature. We run an N-body/SPH simulation of a Milky Way-sized barred disk, and find that the spiral arms are transient features whose pattern speeds decrease with radius, in such a way that the pattern speed is almost equal to the rotation curve of the galaxy. We trace particle motion around the spiral arms. We show that particles from behind and in front of the spiral arm are drawn towards and join the arm. Particles move along the arm in the radial direction and we find a clear trend that they migrate toward the outer (inner radii on the trailing (leading side of the arm. Our simulations demonstrate that tat all radii where there is a co-rotating spiral arm the particles continue to be accelerated (decelerated by the spiral arm for long periods, which leads to strong migration.

  15. 78 FR 26328 - 36(b)(1) Arms Sales Notification

    2013-05-06

    ...)(1) of the Arms Export Control Act, as amended (U) (i) Prospective Purchaser: North Atlantic Treaty Organization (ii) Total Estimated Value: * As defined in Section 47(6) of the Arms Export Control Act. Major... NATO and furthering weapon system standardization and interoperability with U.S. forces. NATO...

  16. 77 FR 52698 - 36(b)(1) Arms Sales Notification

    2012-08-30

    ... of the Secretary 36(b)(1) Arms Sales Notification AGENCY: Defense Security Cooperation Agency... of a section 36(b)(1) arms sales notification. This is published to fulfill the requirements of...: 18 AGM-65K2 MAVERICK All-Up- Round Missiles, 36 TGM-65K2 Captive Air Training Missiles, 3...

  17. Systematic medical data collection of intentional injuries during armed conflicts

    Helweg-Larsen, Karin; Abdel-Jabbar Al-Qadi, Ashraf Hasan; Al-Jabriri, Jalal;

    2004-01-01

    A study was undertaken on implementing medical data collection as a tool to assess the relative number and character of intentional injuries before and during an armed conflict.......A study was undertaken on implementing medical data collection as a tool to assess the relative number and character of intentional injuries before and during an armed conflict....

  18. Professional armed forces new trend in Europe : transformation of the Czech armed forces

    2002-01-01

    Approved for public release; distribution is unlimited In 2001 the Czech Republic decided to abandon conscription in favor of professional armed forces. Western European countries are following the same trend, since the new security environment requires quickly deployable, highly skilled and well-equipped forces. The current round of reforms started with Belgium and Netherlands, and have seen followed by France, Spain, Italy and Portugal. These countries are beneficiary from experience in ...

  19. Localization of ANP-synthesizing cells in rat stomach

    Chun-Hui Li; Li-Hui Pan; Chun-Yu Li; Chang-Lin Zhu; Wen-Xie Xu

    2006-01-01

    AIM: To study the morphological positive expression of antrial natriuretic peptide (ANP)-synthesizing cells and ultrastructural localization and the relationship between ANP-synthesizing cells and microvessel density in the stomach of rats and to analyze the distribution of the three histologically distinct regions of ANP-synthesizing cells.METHODS: Using immunohistochemical techniques, we studied positive expression of ANP-synthesizing cells in rat stomach. A postembedding immunogold microscopy technique was used for ultrastructural localization of ANP-synthesizing cells. Microvessel density in the rat stomach was estimated using tannic acid-ferric chloride (TAFC) method staining. Distribution of ANP-synthesizing cells were studied in different regions of rat stomach histochemically.RESULTS: Positive expression of ANP-synthesizing cells were localized in the gastric mucosa of rats. Localization of ANP-synthesizing cells identified them to be enterochrochromaffin cells (EC) by using a postembedding immunogold electron microscopy technique. EC cells were in the basal third of the cardiac mucosa region.ANP-synthesizing cells existed in different regions of rat stomach and its density was largest in the gastric cardiac region, and the distribution order of ANP-synthesizing cells in density was cardiac region, pyloric region and fundic region in mucosa layer. We have also found a close relationship between ANP-synthesizing cells and microvessel density in gastric mucosa of rats using TAFC staining.CONCLUSION: ANP-synthesizing cells are expressed in the gastric mucosa. EC synthesize ANP. There is a close relationship between ANP-synthesizing cells and microvessel density in gastric mucosa of rats.The distribution density of ANP-synthesizing cells is largest in the gastric cardiac region.

  20. Kootenay Lake Fertilization Experiment, Year 15 (North Arm) and Year 3 (South Arm) (2006) Report

    Schindler, E.U.; Sebastian, D.; Andrusak, G.F. [Fish and Wildlife Science and Allocation, Ministry of Environment, Province of British Columbia

    2009-07-01

    This report summarizes results from the fifteenth year (2006) of nutrient additions to the North Arm of Kootenay Lake and three years of nutrient additions to the South Arm. Experimental fertilization of the lake has been conducted using an adaptive management approach in an effort to restore lake productivity lost as a result of nutrient uptake in upstream reservoirs. The primary objective of the experiment is to restore kokanee (Oncorhynchus nerka) populations, which are the main food source for Gerrard rainbow trout (Oncorhynchus mykiss) and bull trout (Salvelinus confluentus). The quantity of agricultural grade liquid fertilizer (10-34-0, ammonium polyphosphate and 28-0-0, urea ammonium nitrate) added to the North Arm in 2006 was 44.7 tonnes of P and 248.4 tonnes of N. The total fertilizer load added to the South Arm was 257 tonnes of nitrogen; no P was added. Kootenay Lake has an area of 395 km{sup 2}, a maximum depth of 150 m, a mean depth of 94 m, and a water renewal time of approximately two years. Kootenay Lake is a monomictic lake, generally mixing from late fall to early spring and stratifying during the summer. Surface water temperatures generally exceed 20 C for only a few weeks in July. Results of oxygen profiles were similar to previous years with the lake being well oxygenated from the surface to the bottom depths at all stations. Similar to past years, Secchi disc measurements at all stations in 2006 indicate a typical seasonal pattern of decreasing depths associated with the spring phytoplankton bloom, followed by increasing depths as the bloom gradually decreases by the late summer and fall. Total phosphorus (TP) ranged from 2-7 {micro}g/L and tended to decrease as summer advanced. Over the sampling season dissolved inorganic nitrogen (DIN) concentrations decreased, with the decline corresponding to nitrate (the dominant component of DIN) being utilized by phytoplankton during summer stratification. Owing to the importance of epilimnetic nitrate

  1. Multidirectional manual arm strength and its relationship with resultant shoulder moment and arm posture.

    La Delfa, Nicholas J; Potvin, Jim R

    2016-12-01

    Previous work has quantified manual force capabilities for ergonomics design, but the number of studies and range of conditions tested are limited in scope. Therefore, the aims of this study were to collect seated manual arm strength (MAS) data from 24 females in several unique exertion directions (n = 26) and hand locations relative to the shoulder (n = 8), and to investigate the associations between MAS and shoulder/elbow moments. MAS was generally highest when the direction of force application was oriented parallel to the vector from the shoulder to knuckle, and weakest when oriented orthogonal to that vector. Moderate correlations were found between MAS and: (1) resultant shoulder moment (r = 0.34), (2) resultant moment arms (r = -0.545) and (3) elbow flexion/extension moment (r = 0.481). Our strength data will be used in the development of a comprehensive MAS predictive method, so that strength capabilities can be predicted to help design acceptable tasks in the workplace. Practitioner Summary: This study sought to enhance our understanding of one-handed manual arm strength capabilities for ergonomics task evaluations. Our findings provide researchers and practitioners with manual strength data for off-axis force directions, as well as hand locations not previously measured. These data will contribute to future methods for predicting strength capabilities.

  2. A Unified Approach for Reporting ARM Measurement Uncertainties Technical Report

    Campos, E [Argonne National Laboratory; Sisterson, DL [Argonne National Laboratory

    2015-10-01

    The Atmospheric Radiation Measurement (ARM) Climate Research Facility is observationally based, and quantifying the uncertainty of its measurements is critically important. With over 300 widely differing instruments providing over 2,500 datastreams, concise expression of measurement uncertainty is quite challenging. The ARM Facility currently provides data and supporting metadata (information about the data or data quality) to its users through a number of sources. Because the continued success of the ARM Facility depends on the known quality of its measurements, the Facility relies on instrument mentors and the ARM Data Quality Office (DQO) to ensure, assess, and report measurement quality. Therefore, an easily-accessible, well-articulated estimate of ARM measurement uncertainty is needed.

  3. Effect of Shim Arm Depletion in the NBSR

    Hanson A. H.; Brown N.; Diamond, D.J.

    2013-02-22

    The cadmium shim arms in the NBSR undergo burnup during reactor operation and hence, require periodic replacement. Presently, the shim arms are replaced after every 25 cycles to guarantee they can maintain sufficient shutdown margin. Two prior reports document the expected change in the 113Cd distribution because of the shim arm depletion. One set of calculations was for the present high-enriched uranium fuel and the other for the low-enriched uranium fuel when it was in the COMP7 configuration (7 inch fuel length vs. the present 11 inch length). The depleted 113Cd distributions calculated for these cores were applied to the current design for an equilibrium low-enriched uranium core. This report details the predicted effects, if any, of shim arm depletion on the shim arm worth, the shutdown margin, power distributions and kinetics parameters.

  4. The European Union and armed drones: framing the debate

    Martins, Bruno Oliveira

    2015-01-01

    Armed drones are an issue extremely relevant for the EU. The recent emergence of targeted killings as a common counter-terrorism technique, the existence of several EU member states using armed and surveillance drones in military scenarios, the presence of member states troops in areas where armed...... drones have been active, the US use of European-originated intelligence to execute targeted killings, and the broader status of international law, are developments that illustrate the importance of the topic. Yet, the EU still does not have an official position on armed drones. In 2014 the European...... Parliament recognized that this is problematic, adopting a Resolution that expressed “grave concern over the use of armed drones outside the international legal framework” and that urged the EU to “develop an appropriate policy response at both European and global level”. This Forum answers to the European...

  5. A software radio platform based on ARM and FPGA

    Yang Xin.

    2016-01-01

    Full Text Available The rapid rise in computational performance offered by computer systems has greatly increased the number of practical software radio applications. A scheme presented in this paper is a software radio platform based on ARM and FPGA. FPGA works as the coprocessor together with the ARM, which serves as the core processor. ARM is used for digital signal processing and real-time data transmission, and FPGA is used for synchronous timing control and serial-parallel conversion. A SPI driver for real-time data transmission between ARM and FPGA under ARM-Linux system is provided. By adopting modular design, the software radio platform is capable of implementing wireless communication functions and satisfies the requirements of real-time signal processing platform for high security and broad applicability.

  6. Guest Editorial: Research update: VA study to optimize DEKA Arm

    Linda Resnik, PT, PhD

    2010-05-01

    Full Text Available In 2005, the Defense Advanced Research Projects Agency (DARPA announced its Revolutionizing Prosthetics program and funded the development of the DEKA prosthetic arm. The DEKA Arm System incorporates major technological advances such as flexible socket design, innovative control features, software, and hardware that together enable enhanced functionality that promises to surpass any currently available prosthetic device. In 2008, the Department of Veterans Affairs (VA entered into an agreement with DARPA to conduct clinical evaluations of the prototype DEKA Arm System, a prosthetic device system still under development and not yet available commercially. Studies of the DEKA Arm System have been underway at VA sites since late 2008, with the first subject fitted with a DEKA Arm in early 2009.

  7. Cambrian stalked echinoderms show unexpected plasticity of arm construction.

    Zamora, S; Smith, A B

    2012-01-22

    Feeding arms carrying coelomic extensions of the theca are thought to be unique to crinoids among stemmed echinoderms. However, a new two-armed echinoderm from the earliest Middle Cambrian of Spain displays a highly unexpected morphology. X-ray microtomographic analysis of its arms shows they are polyplated in their proximal part with a dorsal series of uniserial elements enclosing a large coelomic lumen. Distally, the arm transforms into the more standard biserial structure of a blastozoan brachiole. Phylogenetic analysis demonstrates that this taxon lies basal to rhombiferans as sister-group to pleurocystitid and glyptocystitid blastozoans, drawing those clades deep into the Cambrian. We demonstrate that Cambrian echinoderms show surprising variability in the way their appendages are constructed, and that the appendages of at least some blastozoans arose as direct outgrowths of the body in much the same way as the arms of crinoids.

  8. The role of tactile support in arm levitation.

    Peter, Burkhard; Piesbergen, Christoph; Lucic, Kristina; Staudacher, Melina; Hagl, Maria

    2013-10-01

    How many persons need tactile support à la Milton H. Erickson to achieve arm levitation during hypnosis? How do these differ from those who do not need it? Hypnotic arm levitation was suggested three times consecutively to 30 medium suggestible students. Sixteen succeeded without any tactile support; 7 needed it one or two times; 5 needed it every time; and 2 achieved no arm levitation at all. Participants without any tactile support went more quickly into deeper hypnosis, experienced more involuntariness, less effort, and had higher electrodermal activity. This greater physiological activity seems necessary for hypnotic arm levitation as a form of "attentive hypnosis" in contrast to "relaxation hypnosis." A change in verbal suggestion from "imagine a helium balloon" to "leave levitation to your unconscious mind" revealed no differences. Several issues resulting from this exploratory arm levitation study are discussed. The idea of different proprioceptive-kinesthetic abilities is introduced and the profound need of co-creating an individual suggestion is emphasized.

  9. The start of the Sagittarius spiral arm (Sagittarius origin) and the start of the Norma spiral arm (Norma origin) - model-computed and observed arm tangents at galactic longitudes -20 degrees < l < +23 degrees

    Vallee, Jacques P

    2016-01-01

    Here we fitted a 4-arm spiral structure to the more accurate data on global arm pitch angle and arm longitude tangents, to get the start of each spiral arm near the Galactic nucleus. We find that the tangent to the 'start of the Sagittarius' spiral arm (arm middle) is at l= -17 degrees +/- 0.5 degree, while the tangent to the 'start of the Norma' spiral arm (arm middle) is at l= +20 degrees +/- 0.5 degree. Earlier, we published a compilation of observations and analysis of the tangent to each spiral arm tracer, from longitudes +23 degrees to +340 degrees; here we cover the arm tracers in the remaining longitudes +340 degrees (=- 20 degrees) to +23 degrees. Our model arm tangents are confirmed through the recent observed masers data (at the arm's inner edge). Observed arm tracers in the inner Galaxy show an offset from the mid-arm; this was also found elsewhere in the Milky Way disk (Vallee 2014c). In addition, we collated the observed tangents to the so-called '3-kpc-arm' features; here they are found statist...

  10. Enantioselective Syntheses of (-)- and (+)-Homocitric Acid Lactones.

    Rodríguez R, Gastón H.; Biellmann, Jean-François

    1996-03-08

    Highly enantioselective syntheses of enantiomers of homocitric acid lactones (R)-5a and (S)-5b are described. Thermal Diels-Alder cycloadditions of 2a and 2b to 1,3-butadiene produced adducts 3a and 3b, respectively. Oxidative ozonolysis of latter adducts gave products 4a and 4b which after acid treatment afforded a mixture with 5a and 5b as major component. Acid lactones 5a and 5b were converted into their dimethyl esters 6a and 6b which were purified by chromatography. After saponification, the products obtained were crystallized to yield (-)- and (+)-homocitric acid lactones ((R)-5a and (S)-5b). Diastereomeric excess (de) of Diels-Alder adducts 3a and 3b was determined by means of Mosher esters of glycols 8a, 8b, and racemic 8. Diels-Alder cycloaddition products of lactones 2a and 2b to 1,3-butadiene showed a diastereoselectivity of 96%.

  11. Computational Models to Synthesize Human Walking

    Lei Ren; David Howard; Laurence Kenney

    2006-01-01

    The synthesis of human walking is of great interest in biomechanics and biomimetic engineering due to its predictive capabilities and potential applications in clinical biomechanics, rehabilitation engineering and biomimetic robotics. In this paper,the various methods that have been used to synthesize humanwalking are reviewed from an engineering viewpoint. This involves a wide spectrum of approaches, from simple passive walking theories to large-scale computational models integrating the nervous, muscular and skeletal systems. These methods are roughly categorized under four headings: models inspired by the concept of a CPG (Central Pattern Generator), methods based on the principles of control engineering, predictive gait simulation using optimisation, and models inspired by passive walking theory. The shortcomings and advantages of these methods are examined, and future directions are discussed in the context of providing insights into the neural control objectives driving gait and improving the stability of the predicted gaits. Future advancements are likely to be motivated by improved understanding of neural control strategies and the subtle complexities of the musculoskeletal system during human locomotion. It is only a matter of time before predictive gait models become a practical and valuable tool in clinical diagnosis, rehabilitation engineering and robotics.

  12. Why can't vertebrates synthesize trehalose?

    Argüelles, Juan-Carlos

    2014-10-01

    The non-reducing disaccharide trehalose is a singular molecule, which has been strictly conserved throughout evolution in prokaryotes (bacteria and archaea), lower eukaryotes, plants, and invertebrates, but is absent in vertebrates and-more specifically-in mammals. There are notable differences regarding the pivotal roles played by trehalose among distantly related organisms as well as in the specific metabolic pathways of trehalose biosynthesis and/or hydrolysis, and the regulatory mechanisms that control trehalose expression genes and enzymatic activities. The success of trehalose compared with that of other structurally related molecules is attributed to its exclusive set of physical properties, which account for its physiological roles and have also promoted important biotechnological applications. However, an intriguing question still remains: why are vertebrates in general, and mammals in particular, unable (or have lost the capacity) to synthesize trehalose? The search for annotated genomes of vertebrates reveals the absence of any functional trehalose synthase gene. Indeed, this is also true for the human genome, which contains, however, two genes encoding for isoforms of the hydrolytic activity (trehalase). Although we still lack a convincing answer, this striking difference might reflect the divergent evolutionary lineages followed by invertebrates and vertebrates. Alternatively, some clinical data point to trehalose as a toxic molecule when stored inside the human body.

  13. Measuring and Synthesizing Systems in Probabilistic Environments

    Chatterjee, Krishnendu; Jobstmann, Barbara; Singh, Rohit

    2010-01-01

    Often one has a preference order among the different systems that satisfy a given specification. Under a probabilistic assumption about the possible inputs, such a preference order is naturally expressed by a weighted automaton, which assigns to each word a value, such that a system is preferred if it generates a higher expected value. We solve the following optimal-synthesis problem: given an omega-regular specification, a Markov chain that describes the distribution of inputs, and a weighted automaton that measures how well a system satisfies the given specification under the given input assumption, synthesize a system that optimizes the measured value. For safety specifications and measures that are defined by mean-payoff automata, the optimal-synthesis problem amounts to finding a strategy in a Markov decision process (MDP) that is optimal for a long-run average reward objective, which can be done in polynomial time. For general omega-regular specifications, the solution rests on a new, polynomial-time al...

  14. Syntheses of surfactants from oleochemical epoxides

    Warwel Siegfried

    2001-01-01

    Full Text Available Sugar-based surfactants were obtained in good yields (up to 100% under mild conditions (70°C, methanol or mixtures of methanol and water by ring-opening of terminal epoxides with aminopolyols, derived from glucose. Reaction of N-methyl glucamine with epoxides from even-numbered C4-C18 alpha-olefins or from terminal unsaturated fatty acid methyl esters leads to linear products, while corresponding reactions with N-dodecyl glucamine or glucamine yield surfactants with different Y-structures. Products obtained by conversion of omega-epoxy fatty acid methyl esters were saponificated with NaOH or hydrolyzed enzymatically to sodium salts or free acids respectively, which are amphoteric surfactants. Studies of the surfactants at different pH-values demonstrate different surface active properties in aqueous solutions. Critical micelle concentrations (c.m.c. in a range between 2 and 500mg/l and surface tensions of 25-40mN/m were measured for several of the synthesized sugar-based surfactants. The ring-opening products are rather poor foamers, whereas some of the corresponding hydrobromides show good foaming properties.

  15. Multistep sintering to synthesize fast lithium garnets

    Xu, Biyi; Duan, Huanan; Xia, Wenhao; Guo, Yiping; Kang, Hongmei; Li, Hua; Liu, Hezhou

    2016-01-01

    A multistep sintering schedule is developed to synthesize Li7La3Zr2O12 (LLZO) doped with 0.2 mol% Al3+. The effect of sintering steps on phase, relative density and ionic conductivity of Al-doped LLZO has been evaluated using powder X-Ray diffraction (XRD), scanning electron microscopy (SEM), 27Al magic spinning nuclear magnetic resonance (NMR) spectroscopy and electrochemical impedance spectroscopy (EIS). The results show that by holding the sample at 900 °C for 6 h, the mixture of tetragonal and cubic garnet phases are obtained; by continuously holding at 1100 °C for 6 h, the tetragonal phase completely transforms into cubic phase; by holding at 1200 °C, the relative density increases without decomposition of the cubic phase. The Al-LLZO pellets after multistep sintering exhibit cubic phase, relative density of 94.25% and ionic conductivity of 4.5 × 10-4 S cm-1 at room temperature. Based on the observation, a sintering model is proposed and discussed.

  16. Bis(alkyl) rare-earth complexes coordinated by bulky tridentate amidinate ligands bearing pendant Ph2P[double bond, length as m-dash]O and Ph2P[double bond, length as m-dash]NR groups. Synthesis, structures and catalytic activity in stereospecific isoprene polymerization.

    Rad'kova, Natalia Yu; Tolpygin, Aleksei O; Rad'kov, Vasily Yu; Khamaletdinova, Nadia M; Cherkasov, Anton V; Fukin, Georgi K; Trifonov, Alexander A

    2016-11-22

    A series of new tridentate amidines 2-[Ph2P[double bond, length as m-dash]X]C6H4NHC(tBu)[double bond, length as m-dash]N(2,6-R2C6H3) (X = O, R = iPr (1); X = S, R = Me (2); X = NPh, R = Me (3); X = N(2,6-Me2C6H3), R = Me (4)) bearing various types of donor Ph2P[double bond, length as m-dash]X groups in a pendant chain was synthesized. Bis(alkyl) complexes {2-[Ph2P[double bond, length as m-dash]X]C6H4NC(tBu)N(2,6-R2C6H3)}Ln(CH2SiMe3)2 (Ln = Y, X = O, R = iPr (5); Ln = Er, X = O, R = iPr (6); Ln = Lu, X = O, R = iPr (7); Ln = Y, X = NPh, R = Me (8); Ln = Lu, X = NPh, R = Me (9); Ln = Lu, X = N(2,6-Me2C6H3), R = Me (10)) were prepared using alkane elimination reactions of 1, 3 and 4 with Ln(CH2SiMe3)3(THF)2 (Ln = Y, Er, Lu) in toluene and were isolated in 45 (5), 62 (6), 56 (7), 65 (8), 60 (9), and 60 (10) % yields respectively. The X-ray diffraction studies showed that complexes 6-8 are solvent free and feature intramolecular coordination of the P[double bond, length as m-dash]X (X = O, NPh) group to the lanthanide ions. The ternary systems 5-10/borate/AlR3 (borate = [PhNHMe2][B(C6F5)4], [Ph3C][B(C6F5)4], AlR3 = AliBu3, AliBu2H; molar ratio = 1/1/10 or 1/1/1, toluene) proved to be active in isoprene polymerization and enable complete conversion of 1000-10 000 equivalents of the monomer into a polymer at 25 °C within 0.5-24 h affording polyisoprenes with polydispersities Mw/Mn = 1.22-3.18. A comparative study of the catalytic performance of the bis(alkyl) complexes coordinated by tridentate amidinate ligands containing different pendant donor groups demonstrated that replacement of the Ph2P[double bond, length as m-dash]O group by Ph2P[double bond, length as m-dash]NPh leads to a switch of stereoselectivity in isoprene polymerization from cis-1,4 (up to 98.5%) to trans-1,4 (up to 84.8%). And conversely introduction of methyl substituents in the 2,6 positions of the phenyl group of the Ph2P[double bond, length as m-dash]NPh fragment allows us to restore the 1,4-cis

  17. Effect of swim speed on leg-to-arm coordination in unilateral arm amputee front crawl swimmers.

    Osborough, Conor; Daly, Daniel; Payton, Carl

    2015-01-01

    The aim of this study was to examine the effect of swimming speed on leg-to-arm coordination in competitive unilateral arm amputee front crawl swimmers. Thirteen well-trained swimmers were videotaped underwater during three 25-m front crawl trials (400 m, 100 m and 50 m pace). The number, duration and timing of leg kicks in relation to arm stroke phases were identified by video analysis. Within the group, a six-beat kick was predominantly used (n = 10) although some swimmers used a four-beat (n = 2) or eight-beat kick (n = 1). Swimming speed had no significant effect on the relative duration of arm stroke and leg kick phases. At all speeds, arm stroke phases were significantly different (P amputee swimmers functionally adapt their motor organisation to swim front crawl.

  18. Torsional Arming of Thiomannosyl Donors & Conformational Control of Hexahydropyridazines via pH

    Olsen, Jacob Ingemar

    demonstrated their ability to change conformation under different conditions. These conformational changes are connected to various intramolecular interactions and can to some extent, be controlled by pH (Chapter 3). Fusing these conformationally labile compounds to the rim of a cyclodextrin would create...... and can to some extent, be controlled by pH (Chapter 3). Fusing these conformationally labile compounds to the rim of a cyclodextrin would create compounds that could release molecules at a specified change in pH conditions. To investigate this, four hexahydropyridazines were synthesized and investigated......The overall objective of the research presented in this PhD thesis was to investigate torsional arming of thiogalacto- and thiomannosyl donors (part 1) and to investigate the possible synthesis and attachment of a pH regulated conformational switch to an α-cyclodextrin (part 2). Part 1: It is well...

  19. Two Multi-armed Neutral Receptors for α, ω-Dicarboxylate Anions

    WU, Jin-Long; HE, Yong-Bing; WEI, Lan-Hua; LIU, Shun-Ying; XU, Kuo-Xi; MENG, Ling-Zhi

    2006-01-01

    Two new multi-armed neutral receptors 1 and 2 containing thiourea and amide groups were synthesized by simple steps in good yields. Receptors 1 and 2 have a better selectivity and higher association constants for malonate anion than other anions examined by the present work. In particular, distinct color changes were observed upon addition of dicarboxylate anions to the solution of 1 in DMSO. The UV-Vis and fluorescence spectra data indicate that a 1: 2 stoichiometry complex was formed between compound 1 or 2 and dicarboxylate anions of shorter carbon chain, and a 1: 1 stoichiometry complex was formed between compound 1 or 2 and dicarboxylate anions of longer carbon chain through hydrogen bonding interactions.

  20. Syntheses of aliphatic polycarbonates from 2'-deoxyribonucleosides.

    Suzuki, Masato; Sekido, Toyokazu; Matsuoka, Shin-ichi; Takagi, Koji

    2011-05-01

    Poly(2'-deoxyadenosine) and poly(thymidine) constructed of carbonate linkages were synthesized by polycondensation between silyl ether and carbonylimidazolide at the 3'- and 5'-positions of the 2'-deoxyribonucleoside monomers. The N-benzoyl-2'-deoxyadenosine monomer afforded the corresponding polycarbonate together with the cyclic oligomers. However, the deprotection of the N-benzoyl group resulted in the scission of the polymer main chain. Thus, the N-unprotected 2'-deoxyadenosine monomers were examined for polycondensation. However, there was involved the undesired reaction between the adenine amino group and the carbonylimidazolide to form the carbamate linkage. In order to exclude this unfavorable reaction, dynamic protection was employed. Strong hydrogen bonding was used in place of the usual covalent bonding for reducing the nucleophilicity of the adenine amino group. Herein, 3',5'-O-diacylthymidines that form the complementary hydrogen bonding with the adenine amino group were added to the polymerization system of the N-unprotected 2'-deoxyadenosine monomer. Consequently, although the oligomers (M(n) = 1000-1500) were produced, the contents of the carbamate group were greatly reduced. The dynamic protection reagents were easily and quantitatively recovered as the MeOH soluble parts from the polymerization mixtures. In the polycondensation of the thymidine monomer, there tended to be involved another unfavorable reaction of carbonate exchange, which consequently formed the irregular carbonate linkages at not only the 3'-5' but also the 3'-3' and 5'-5' positions. Employing the well-designed monomer suppressed the carbonate exchange reaction to produce poly(thymidine) with the almost regular 3'-5'carbonate linkages.

  1. SYNTHESIS AND CHARACTERIZATION OF FOUR-ARMED BLOCK POLY(STYRENE-b-p-NITRO PHENYL METHACRYLATE) PREPARED BY THE ATRP METHOD

    Cai-yuan Pan; Lei Tao; Ye Liu

    2002-01-01

    A novel tetrafunctional initiator, C[CH2O(CH2)3OOCCH(Br)CH3]4 (1), was synthesized through the reaction oftetraol with α-bromopropionyl chloride, and then was used as initiator of atom transfer radical polymerization (ATRP) in thepreparation of 4-armed polystyrene (PSt) with narrow polydispersity. The structure, molecular weight and molecular weightdistribution (MWD) of each arm were studied by 1H-NMR and GPC data of hydrolyzed products of the 4-armed PSt. TheATRP of St using 1/CuBr/bpy as initiator system is of "living" character based on the following evidence: narrow MWD,constant concentration of chain radical during the polymerization, control of molecular weight by the molar ratio of monomerconsumed to 1. The 4-armed poly(St-b-p-nitrophenyl methacrylate) [poly(St-b-NPMA)] was prepared by the ATRP ofNPMA using 4-armed PSt with terminal bromine as the initiator, and characterized by FT-IR, 1H-NMR spectra and GPCcurves. The micelles with PSt as core, and PNPMA as shell were formed by dropping DMSO into a solution of 4-armedpoly(St-b-NPMA) in DMF, as proved by laser light scatter (LLS) method.

  2. Star-Shaped Conjugated Molecules with Oxa- or Thiadiazole Bithiophene Side Arms.

    Kotwica, Kamil; Kostyuchenko, Anastasia S; Data, Przemyslaw; Marszalek, Tomasz; Skorka, Lukasz; Jaroch, Tomasz; Kacka, Sylwia; Zagorska, Malgorzata; Nowakowski, Robert; Monkman, Andrew P; Fisyuk, Alexander S; Pisula, Wojciech; Pron, Adam

    2016-08-08

    Star-shaped conjugated molecules, consisting of a benzene central unit symmetrically trisubstituted with either oxa- or thiadiazole bithiophene groups, were synthesized as promising molecules and building blocks for application in (opto)electronics and electrochromic devices. Their optical (Eg (opt)) as well as electrochemical (Eg (electro)) band gaps depended on the type of the side arm and the number of solubilizing alkyl substituents. Oxadiazole derivatives showed Eg (opt) slightly below 3 eV and by 0.2 eV larger than those determined for thiadiazole-based compounds. The presence of alkyl substituents in the arms additionally lowered the band gap. The obtained compounds were efficient electroluminophores in guest/host-type light-emitting diodes. They also showed a strong tendency to self-organize in monolayers deposited on graphite, as evidenced by scanning tunneling microscopy. The structural studies by X-ray scattering revealed the formation of supramolecular columnar stacks in which the molecules were organized. Differences in macroscopic alignment in the specimen indicated variations in the self-assembly mechanism between the molecules. The compounds as trifunctional monomers were electrochemically polymerized to yield the corresponding polymer network. As shown by UV/Vis-NIR spectroelectrochemical studies, these networks exhibited reversible electrochromic behavior both in the oxidation and in the reduction modes.

  3. Mesomorphic properties of multi-arm liquid crystals containing glucose and sorbitol as cores

    Tian, Mei; Zhang, Bao-Yan; Cong, Yue-Hua; Zhang, Na; Yao, Dan-Shu

    2009-04-01

    Six thermotropic cholesteric multi-arm liquid crystals (MALCs) were synthesized with glucose and sorbitol as chiral cores. b0, b1 and b2 were introduced into hydroxy groups of the chiral cores as the mesogenic units in the arm scaffold. The roles played by the chiral cores and the terminal chain length of the mesogenic units to the mesomorphic behavior of the MALCs were studied. b0, b1 and b2 displayed nematic phase. c0, c1, c2, d0, d1 and d2 exhibited cholesteric phases and wide mesogenic regions. The results indicated that the chiral cores played an important effect on inducing the cholesteric phase and an obvious effect on the melting temperature, clear point and mesophase region of the MALCs. The corresponding melting temperature and the clear point of d0, d1 and d2, were lower than those of the c0, c1 and c2. The mesophase regions of the formers were narrower than those of the latters. The terminal chain length of the mesogenic units played an important effect on mesogenic region, too. The mesogenic region increased as the terminal chain length increasing for the MALCs containing the same chiral core.

  4. synthesis of novel four armed PE-PCL grafted superparamagnetic and biocompatible nanoparticles.

    Panja, Sudipta; Saha, Biswajit; Ghosh, S K; Chattopadhyay, Santanu

    2013-10-08

    Novel biocompatible polymer immobilized superparamagnetic nanoparticles (MNP) are prepared by grafting four armed pentaerythritol poly(ε-polycaprolactone) (PE-PCL) onto silane modified MNP. The MNPs are synthesized by hydrothermal process and its modification using (3-aminopropyl)trimethoxysilane (TMAS) coating is done by the sol-gel technique. The pentaerythritol (PE) initiated ring-opening polymerization (ROP) is carried out to prepare four armed PE-PCL. The reaction is shown to follow first order kinetics. The structure of PE-PCL is confirmed by NMR spectrum and MALDI-TOF analysis. The in situ grafting of PE-PCL onto modified MNP has been carried out by using 4,4'-methylenediphenyl diisocyanate (MDI) as an intermediate linker. The grafting density as determined by TGA analysis has been found to be significantly higher than previously reported linear PCL grafted MNPs in the literature. This leads to uniform dispersion of grafted MNPs which still is a challenging task in contemporary research. The effective dispersion of MNP into PE-PCL matrix is analyzed by HRTEM. The saturation magnetization of the PE-PCL grafted MNPs is significantly high and this can be tailored further by varying the grafting density. The biocompatibility of polymer grafted nanoparticles is confirmed by MTT assay using HeLa cell line. The superparamagnetic and biocompatible novel PE-PCL grafted MNP so prepared would have manifold potential applications including in therapy and targeted drug delivery.

  5. ARM System Developer's Guide Designing and Optimizing System Software

    Sloss, Andrew

    2004-01-01

    Over the last ten years, the ARM architecture has become one of the most pervasive architectures in the world, with more than 2 billion ARM-based processors embedded in products ranging from cell phones to automotive braking systems. A world-wide community of ARM developers in semiconductor and product design companies includes software developers, system designers and hardware engineers. To date no book has directly addressed their need to develop the system and software for an ARM-based system. This text fills that gap. This book provides a comprehensive description of the operation of the ARM core from a developer's perspective with a clear emphasis on software. It demonstrates not only how to write efficient ARM software in C and assembly but also how to optimize code. Example code throughout the book can be integrated into commercial products or used as templates to enable quick creation of productive software. The book covers both the ARM and Thumb instruction sets, covers Intel''s XScale Processors, ou...

  6. Tidal origin of spiral arms in galaxies orbiting a cluster

    Semczuk, Marcin; del Pino, Andres

    2016-01-01

    One of the scenarios for the formation of grand-design spiral arms in disky galaxies involves their interactions with a satellite or another galaxy. Here we consider another possibility, where the perturbation is instead due to the potential of a galaxy cluster. Using $N$-body simulations we investigate the formation and evolution of spiral arms in a Milky Way-like galaxy orbiting a Virgo-like cluster. The galaxy is placed on a few orbits of different size but similar eccentricity and its evolution is followed for 10 Gyr. The tidally induced, two-armed, approximately logarithmic spiral structure forms on each of them during the pericenter passages. The spiral arms dissipate and wind up with time, to be triggered again at the next pericenter passage. We confirm this transient and recurrent nature of the arms by analyzing the time evolution of the pitch angle and the arm strength. We find that the strongest arms are formed on the tightest orbit, however they wind up rather quickly and are disturbed by another p...

  7. Arm coordination in octopus crawling involves unique motor control strategies.

    Levy, Guy; Flash, Tamar; Hochner, Binyamin

    2015-05-04

    To cope with the exceptional computational complexity that is involved in the control of its hyper-redundant arms [1], the octopus has adopted unique motor control strategies in which the central brain activates rather autonomous motor programs in the elaborated peripheral nervous system of the arms [2, 3]. How octopuses coordinate their eight long and flexible arms in locomotion is still unknown. Here, we present the first detailed kinematic analysis of octopus arm coordination in crawling. The results are surprising in several respects: (1) despite its bilaterally symmetrical body, the octopus can crawl in any direction relative to its body orientation; (2) body and crawling orientation are monotonically and independently controlled; and (3) contrasting known animal locomotion, octopus crawling lacks any apparent rhythmical patterns in limb coordination, suggesting a unique non-rhythmical output of the octopus central controller. We show that this uncommon maneuverability is derived from the radial symmetry of the arms around the body and the simple pushing-by-elongation mechanism by which the arms create the crawling thrust. These two together enable a mechanism whereby the central controller chooses in a moment-to-moment fashion which arms to recruit for pushing the body in an instantaneous direction. Our findings suggest that the soft molluscan body has affected in an embodied way [4, 5] the emergence of the adaptive motor behavior of the octopus.

  8. Climatic gradients of arms race coevolution.

    Toju, Hirokazu; Abe, Harue; Ueno, Saneyoshi; Miyazawa, Yoshiyuki; Taniguchi, Fumiya; Sota, Teiji; Yahara, Tetsukazu

    2011-05-01

    In nature, spatiotemporally dynamic coevolutionary processes play major roles in the foundation and maintenance of biodiversity. Here, we examined the arms race coevolution involving a seed-eating weevil with a long snout and its camellia plant host with a thick fruit coat (pericarp) throughout the marked climatic gradient observed across the Japanese islands. Results demonstrated that female weevils, which bored holes through camellia pericarps to lay eggs into seeds, had evolved much longer snouts than males, especially in areas in which Japanese camellia pericarps were very thick. The thickness of the plant pericarp was heritable, and the camellia plant evolved a significantly thicker pericarp on islands with the weevil than on islands without it. Across populations with weevils, resource allocation to plant defense increased with increasing annual mean temperature or annual precipitation, thereby geographically differentiating the evolutionary and ecological interactions between the two species. Given that the coevolutionary relationship exhibited appreciable variation across a relatively small range of annual mean temperatures, ongoing global climatic change can dramatically alter the coevolutionary process, thereby changing the ecological interaction between these species.

  9. FIDO Rover Retracted Arm and Camera

    1999-01-01

    The Field Integrated Design and Operations (FIDO) rover extends the large mast that carries its panoramic camera. The FIDO is being used in ongoing NASA field tests to simulate driving conditions on Mars. FIDO is controlled from the mission control room at JPL's Planetary Robotics Laboratory in Pasadena. FIDO uses a robot arm to manipulate science instruments and it has a new mini-corer or drill to extract and cache rock samples. Several camera systems onboard allow the rover to collect science and navigation images by remote-control. The rover is about the size of a coffee table and weighs as much as a St. Bernard, about 70 kilograms (150 pounds). It is approximately 85 centimeters (about 33 inches) wide, 105 centimeters (41 inches) long, and 55 centimeters (22 inches) high. The rover moves up to 300 meters an hour (less than a mile per hour) over smooth terrain, using its onboard stereo vision systems to detect and avoid obstacles as it travels 'on-the-fly.' During these tests, FIDO is powered by both solar panels that cover the top of the rover and by replaceable, rechargeable batteries.

  10. Bionic robot arm with compliant actuators

    Moehl, Bernhard

    2000-10-01

    Traditional robotics uses non-compliant materials for all components involved in the production of movement. Elasticity is avoided as far as possible, because it leads to hazardous oscillations and makes control of precise movements very difficult. Due to this deliberate stiffness, robots are typically heavy and clumsy structures in comparison to their living counterparts (i.e. man and animals). Yet, moving systems in nature cope not only with the difficulties introduced by compliant materials, they also take advantage of the elasticity in muscles and tendons to produce smooth and even rapid movements. It is understood, that elasticity in a multi-jointed moving system requires sophisticated control mechanisms- as provided by a nervous system or a suitably programmed computer. In this contribution I shall describe a two-jointed robot with purpose-built elasticity in its actuators. This is accomplished by spiral springs places in series with a conventional electric motor and a tendon to the arm. It is shown that, with sufficiently soft elasticity, oscillations can be avoided by active oscillation damping. (Such active oscillation damping presumably also governs movement control in man and animals.) Furthermore, once the major problem has been overcome, elasticity is found to offer a wide spectrum of valuable advantages, as far as the most serious problems in traditional robotics are concerned. They are summarized by terms such as less dangerous, position tolerant, lightweight construction, controlled forces, and ballistic movements. These will be explained in detail and presented for discussion.

  11. Arm Structure in Anemic Spiral Galaxies

    Elmegreen, D M; Frogel, J A; Eskridge, P B; Pogge, R W; Gallagher, A; Iams, J; Elmegreen, Debra Meloy; Elmegreen, Bruce G.; Frogel, Jay A.; Eskridge, Paul B.; Pogge, Richard W.; Gallagher, Andrew; Iams, Joel

    2002-01-01

    Anemic galaxies have less prominent star formation than normal galaxies of the same Hubble type. Previous studies showed they are deficient in total atomic hydrogen but not in molecular hydrogen. Here we compare the combined surface densities of HI and H2 at mid-disk radii with the Kennicutt threshold for star formation. The anemic galaxies are below threshold, which explains their lack of prominent star formation, but they are not much different than other early type galaxies, which also tend to be below threshold. The spiral wave amplitudes of anemic and normal galaxies were also compared, using images in B and J passbands from the OSU Bright Spiral Galaxy Survey. Anemic galaxies have normal spiral wave properties too, with the same amplitudes and radial dependencies as other galaxies of the same arm class. Because of the lack of gas, spiral waves in early type galaxies and anemics do not have a continuous supply of stars with low velocity dispersions to maintain a marginally stable disk. As a result, they ...

  12. Tidal Origin of Spiral Arms in Galaxies Orbiting a Cluster

    Semczuk, Marcin; Łokas, Ewa L.; del Pino, Andrés

    2017-01-01

    One of the scenarios for the formation of grand-design spiral arms in disky galaxies involves their interactions with a satellite or another galaxy. Here we consider another possibility, where the perturbation is instead due to the potential of a galaxy cluster. Using N-body simulations we investigate the formation and evolution of spiral arms in a Milky-Way-like galaxy orbiting a Virgo-like cluster. The galaxy is placed on a few orbits of different size but similar eccentricity and its evolution are followed for 10 Gyr. The tidally induced, two-armed, approximately logarithmic spiral structure forms on each of them during the pericenter passages. The spiral arms dissipate and wind up with time, to be triggered again at the next pericenter passage. We confirm this transient and recurrent nature of the arms by analyzing the time evolution of the pitch angle and the arm strength. We find that the strongest arms are formed on the tightest orbit; however, they wind up rather quickly and are disturbed by another pericenter passage. The arms on the most extended orbit, which we analyze in more detail, wind up slowly and survive for the longest time. Measurements of the pattern speed of the arms indicate that they are kinematic density waves. We attempt a comparison with observations by selecting grand-design spiral galaxies in the Virgo cluster. Among those, we find nine examples bearing no sign of recent interactions or the presence of companions. For three of them we present close structural analogues among our simulated spiral galaxies.

  13. Coke Formation During Hydrocarbons Pyrolysis. Part One: Steam Cracking Formation de coke pendant la pyrolise des hydrocarbures. Première partie : vapocraquage

    Weill J.

    2006-11-01

    Full Text Available Thermal cracking is always accompanied by coke formation, which becomes deposited on the wall and limits heat transfers in the reactor while increasing pressure drops and possibly even plugging up the reactor. This review article covers undesirable coking operations in steam craking reactors. These coking reactions may take place in the gas phase and/or on the surface of the reactor, with coke being produced during pyrolysis by a complex mechanism that breaks down into a catalytic sequence and a noncatalytic sequence. After a brief description of different experimental set-ups used to measure the coke deposition, on the basis of research described in the literature, the different factors and their importance for coke formation are listed. In particular, we describe the effects of surface properties of stainless-steel and quartz reactors as well as the influence of the cracked feedstock, of temperature, of dilution, of residence time and of the conversion on coke deposition. Some findings about the morphology of coke are described and linked to formation mechanisms. To illustrate this review, some particularly interesting research is referred to concerning models developed to assess coke formation during propane steam cracking. Le craquage thermique est toujours accompagné de la formation de coke qui, en se déposant à la paroi, limite les transferts de chaleur au réacteur, augmente les pertes de charges et même peut boucher celui-ci. Cet article fait le point sur les réactions indésirables de cokage dans les réacteurs de vapocraquage. Ces réactions de cokage peuvent avoir lieu en phase gazeuse et/ou sur la surface du réacteur, le coke étant produit pendant la pyrolyse par un mécanisme complexe qui se décompose en une séquence catalytique et une séquence non catalytique. Après une brève présentation des différents montages expérimentaux utilisés pour mesurer le dépôt de coke, il est mentionné, à partir de travaux de la

  14. Robots arm motion representation in Petri NETS using sequent calculus

    Syed Uzair Ahmad

    2015-12-01

    Full Text Available There are many sort of motion in robots structure. Such as the robot locomotion robot jumps robots picking and so on but all are presented through Petri NETS. The one motion which is also the important one and most worthy motion of the robots is the robots arm motion. Which till yet not represented through Petri NETS. In this paper we are going to represent the motion of the robot arm in different angles and different aspect, such as up, down, circular, back and front moment of the robot arm, through Petri net we can present the complex form of motions into simplex paths.

  15. Suicide mortality at time of armed conflict in Ukraine.

    Yur'yev, Andriy; Yur'yeva, Lyudmyla

    2015-12-01

    The purpose of this review is to explore the dynamics of suicide mortality rates in Ukraine during an ongoing armed conflict between 2014 and 2015. Suicide mortality data were obtained by reviewing annual analytical releases from the State Service for Emergent Situations of Ukraine and annual release of Russian Federal Service of State Statistics. Suicide mortality in mainland Ukraine and in the Crimea region demonstrated a mild decrease, whereas suicide mortality in the regions directly involved in the armed conflict demonstrated a prominent decrease. The results of this review support Durkheim theory. The limitation of this review includes general concern about quality of data at time of armed conflict in the country.

  16. Light Duty Utility Arm computer software configuration management plan

    Philipp, B.L.

    1998-09-14

    This plan describes the configuration management for the Light Duty Utility Arm robotic manipulation arm control software. It identifies the requirement, associated documents, and the software control methodology. The Light Duty Utility Ann (LDUA) System is a multi-axis robotic manipulator arm and deployment vehicle, used to perform surveillance and characterization operations in support of remediation of defense nuclear wastes currently stored in the Hanford Underground Storage Tanks (USTs) through the available 30.5 cm (12 in.) risers. This plan describes the configuration management of the LDUA software.

  17. Dynamic Simulation Analysis of Forest-fruit Vibratory Harvester Arm

    Jian Zhou

    2014-01-01

    Full Text Available For obtaining excellent properties of vibration type picking machine of oil tea fruit, two and three dimensional virtual prototype of forest-fruit vibratory harvester was established by CAD and Pro/E software, then the dynamic prototype was converted and the dynamics simulation was worked out by the Adams system simulation software for the arm. The mechanical characteristics of arm were measured during positioning and vibrating the end of arm and they provide a theoretical references to optimize the physical prototype.

  18. Haptic stabilization of posture: changes in arm proprioception and cutaneous feedback for different arm orientations

    Rabin, E.; Bortolami, S. B.; DiZio, P.; Lackner, J. R.

    1999-01-01

    Postural sway during quiet stance is attenuated by actively maintained contact of the index finger with a stationary surface, even if the level of applied force (proprioceptive information about the hand and arm can serve as an active sensor of body position relative to the point of contact. A geometric analysis of the relationship between hand and torso displacement during body sway led to the prediction that arm and hand proprioceptive and finger somatosensory information about body sway would be maximized with finger contact in the plane of body sway. Therefore, the most postural stabilization should be possible with such contact. To test this analysis, subjects touched a laterally versus anteriorly placed surface while in each of two stances: the heel-to-toe tandem Romberg stance that reduces medial-lateral stability and the heel-to-heel, toes-outward, knees-bent, "duck stance" that reduces fore-aft stability. Postural sway was always least with finger contact in the unstable plane: for the tandem stance, lateral fingertip contact was significantly more effective than frontal contact, and, for the duck stance, frontal contact was more effective than lateral fingertip contact. Force changes at the fingertip led changes in center of pressure of the feet by approximately 250 ms for both fingertip contact locations for both test stances. These results support the geometric analysis, which showed that 1) arm joint angles change by the largest amount when fingertip contact is maintained in the plane of greatest sway, and 2) the somatosensory cues at the fingertip provide both direction and amplitude information about sway when the finger is contacting a surface in the unstable plane.

  19. Syntheses and electronic structures of decamethylmetallocenes

    Robbins, J.L.

    1981-04-01

    The synthesis of decamethylmanganocene ((eta-C/sub 5/(CH/sub 3/)/sub 5/)/sub 2/Mn or (Me/sub 5/Cp)/sub 2/Mn)) is described. Magnetic susceptibility and electron paramagnetic resonance (EPR) studies show that (Me/sub 5/Cp)/sub 2/Mn is a low-spin, 17-electron compound with an orbitally degenerate, /sup 2/E/sub 2g/ (e/sub 2g//sup 3/ a/sub 1g//sup 2/) ground state. An x-ray crystallographic study of (Me/sub 5/Cp)/sub 2/Mn shows that it is a monomeric, D/sub 5d/ decamethylmetallocene with metal to ring carbon distances that are about 0.3 A shorter than those determined for high-spin manganocenes. The syntheses of new (Me/sub 5/Cp)/sub 2/M (M = Mg,V,Cr,Co, and Ni) and ((Me/sub 5/Cp)/sub 2/M)PF/sub 6/ (M = Cr,Co, and Ni) compounds are described. In addition, a preparative route to a novel, dicationic decamethylmetallocene, ((Me/sub 5/Cp)/sub 2/Ni)(PF/sub 6/)/sub 2/ is reported. Infrared, nuclear magnetic resonance, magnetic susceptibility, and/or x-ray crystallographic studies indicate that all the above compounds are D/sub 5d/ or D/sub 5h/ decamethylmetallocenes with low-spin electronic configurations. Cyclic voltammetry studies verify the reversibility and the one-electron nature of the (Me/sub 5/Cp)/sub 2/M ..-->.. ((Me/sub 5/Cp)/sub 2/M)/sup +/ (M = Cr,Mn,Fe,Co,Ni), ((Me/sub 5/Cp)/sub 2/Mn)/sup -/ ..-->.. (Me/sub 5/Cp)/sub 2/Mn and ((Me/sub 5/Cp)/sub 2/Ni)/sup +/ ..-->.. (Me/sub 5/Cp)/sub 2/Ni)/sup 2 +/ redox reactions. These studies reveal that the neutral decamethylmetallocenes are much more easily oxidized than their metallocene counterparts. This result attests to the electron-donating properties of the ten substituent methyl groups. Proton and carbon-13 NMR data are reported for the diamagnetic Mg(II), Mn(I), Fe(II), Co(III), and Ni(IV) decamethylmetallocenes and for ((Me/sub 5/Cp)/sub 2/V(CO)/sub 2/)/sup +/. The uv-visible absorption spectra of the 15-, 18- and 20- electron decamethylmetallocenes are also reported.

  20. Bis(indolyl)methane alkaloids: Isolation, bioactivity, and syntheses

    Praveen, P.; Parameswaran, P.S.; Majik, M.S.

    Author version: Synthesis - Stuttgart, vol.47; 2015; 1827-1837 Bisindolyl Methane Alkaloids: Isolation, Bioactivity and Syntheses P. J. Praveen,a,b P. S. Parameswaran*b, M. S. Majik*c aCSIR-National Institute of Oceanography, Bioorganic Chemistry... to their wide applications in medicinal chemistry, drug discovery and agrochemicals, the syntheses and isolation of BIMs have attracted attention of several chemists over last few years. Due to their symmetric structure, they are easy to synthesize...

  1. MM-wave synthesizer has 8-to-15-GHz bandwidth

    Fortunato, M. P.; Ishikawa, K. Y.

    1982-05-01

    Millimeter-wave sweeper IMPATT diodes are combined with microprocessor control and opamp circuitry to give a fast and accurate W-band synthesizer. The breakthrough in millimeter-wave frequency synthesizer development derives from the ability to lock virtually any millimeter-wave IMPATT. The considerable improvement in SSB phase noise of a phase-locked sweeper IMPATT versus a free-running Gunn, fixed-tuned IMPATT, and free-running sweeper IMPATT is illustrated. The spectra of a free-running and a phase-locked sweeper IMPATT are compared. A block diagram of the complete millimeter-wave synthesizer is included, together with typical W-band synthesizer specifications.

  2. Introduction and Analysis of I-ARM-Droid%I-ARM-Droid框架研究与分析

    李红

    2014-01-01

    对I-ARM-Droid框架进行分析和研究,将其与其它的主流方案进行了对比;展示了在应用I-ARM-Droid框架重写一个安卓应用程序时的部分代码和Dalvik bytecode;帮助安卓系统安全的研究者进一步了解I-ARM-Droid框架,并了解使用在重写安卓应用程序过程中的一些有用工具.

  3. Arms control and the rule of law

    Tanzman, E.A.

    1995-03-01

    Many who speak of the end of the Cold War emphasize the warming of international relations when they speak of the momentous consequences of this event. According to this image, the half century since Trinity has been a period of sparse international communication during which the Eastern and Western blocs hibernated in their isolated dens of security alliances. Yet it is equally valid to consider the implications of the end of the war footing that has underlain the policies of all of the major military powers during the last fifty years. While meaningful international dialogue was in a state of relative lethargy during much of this period, the military establishments of the Great Powers were actively engaged in using as much force as possible in their efforts to control world affairs, short of triggering a nuclear holocaust. International discourse, at least in English, was rife with such military images as appeasement, containment, crisis stability, and tripwires. From the military posture of the U.S. and Russia a tense peace ironically emerged, but the terms by which decisions were made about controlling weapons of mass destruction (i.e., nuclear, chemical, and biological weapons) were the terms of war. The thesis of this paper is that the end of the Cold War marks a shift away from reliance on military might toward an international commitment to control weapons of mass destruction through the rule of law developed by John Rawls. The progression of agreements during this century to limit weapons of mass destruction testifies to this new development. A review of arms control agreements that the U.S. is a part of show clear growth of the rule of law as the world has left the Cold War.

  4. New developments in prosthetic arm systems

    Vujaklija I

    2016-07-01

    functionality. This article is aimed at reviewing the latest state of the upper limb prosthetic market, offering insights on the accompanying technologies and techniques. We also examine the capabilities and features of some of academia’s flagship solutions and methods. Keywords: prosthetic, amputations, rehabilitation, hand, arm

  5. Light duty utility arm walkdown report

    Smalley, J.L.

    1998-09-25

    This document is a report of the Light Duty Utility Arm (LDUA) drawing walkdown. The purpose of this walkdown was to validate the essential configuration of the LDUA in preparation of deploying the equipment in a Hanford waste tank. The LDUA system has, over the course of its development, caused the generation of a considerable number of design drawings. The number of drawings is estimated to be well over 1,000. A large number consist of vendor type drawings, furnished by both Pacific Northwest National Laboratory (PNNL) and SPAR Aerospace Limited (SPAR). A smaller number, approximately 200, are H-6 type drawing sheets in the Project Hanford Management Contract (PHMC) document control system. A preliminary inspection of the drawings showed that the physical configuration of the LDUA did not match the documented configuration. As a result of these findings, a scoping walkdown of 20 critical drawing sheets was performed to determine if a problem existed in configuration management of the LDUA system. The results of this activity showed that 18 of the 20 drawing sheets were found to contain errors or omissions of varying concern. Given this, Characterization Engineering determined that a walkdown of the drawings necessary and sufficient to enable safe operation and maintenance of the LDUA should be performed. A review team was assembled to perform a review of all of the drawings and determine the set which would need to be verified through an engineering walkdown. The team determined that approximately 150 H-6 type drawing sheets would need to be verified, 12 SPAR/PNNL drawing sheets would need to be verified and converted to H-6 drawings, and three to six new drawings would be created (see Appendix A). This report documents the results of that walkdown.

  6. [Protection of medical personnel in contemporary armed conflicts].

    Goniewicz, Krzysztof; Goniewicz, Mariusz; Pawłowski, Witold

    2016-01-01

    International humanitarian law provides special protection devices and medical personnel during armed conflicts. In today's wars it became more frequent lack of respect for the protective emblems of the red cross and red crescent and the lack of respect for medical activities. The paper presents selected issues of humanitarian law with a particular emphasis on the rules concerning the protection of medical services and victims of armed conflicts. All countries that have ratified the Geneva Conventions and Additional Protocols, are required to comply in time of war the principles contained in them and their dissemination in peacetime. Education societies in the field of international humanitarian law can help to eliminate attacks on medical facilities and personnel and significantly improve the fate of the victims of armed conflict and mitigate the cruelty of war. Knowledge of humanitarian law does not prevent further wars, but it can cause all parties to any armed conflict will abide by its rules during such activities.

  7. Engaging armed non-state actors in mechanisms for protection

    Pauline Lacroix

    2011-03-01

    Full Text Available Experience of engagement with armed non-state actors on the landmine ban may point the way to innovative approaches to preventing forced displacement and other abuses of human rights....

  8. High Performance Arm for an Exploration Space Suit Project

    National Aeronautics and Space Administration — Final Frontier Design (FFD) proposes to develop and deliver an advanced pressure garment arm with low torque and high Range of Motion (ROM), and increased...

  9. Modelling and Control of 5 dof Robotic Arm

    Nurettin Gökhan Adar

    2013-01-01

    Full Text Available In this paper, dynamic modeling of a 5 DOF Robotic Arm was carried out. The Robotic Arm totally had 5 DOF spatial articulated arm which consist of 3 parts. The modeling of dynamic equations of motion were based on Lagrange-Euler equations. The equations were taked into matrix-vector form. The parts of Robotic Arm had been in free fall to see the accuracy of the equations of motion and each joint graphs were obtained. A control algorithm was designed to achieve the position of the joint corresponding to the desired scenario. PID control algorithm is used in this study. As a result of the simulation of the orbits of the cubic joint position had been followed up successfully.

  10. Explore the Performance of the ARM Processor Using JPEG

    A.D. Jadhav

    2010-01-01

    Full Text Available Recently, the evolution of embedded systems has shown a strong trend towards application- specific, single- chip solutions. The ARM processor core is a leading RISC processor architecture in the embedded domain. The ARM family of processors supports a unique feature of code size reduction. In this paper it is illustrated using an embedded platform trying to design an image encoder, more specifically a JPEG encoder using ARM7TDMI processor. Here gray scale image is used and it is coded by using keil software and same procedure is repeated by using MATLAB software for compare the results with standard one. Successfully putting a new application of JPEG on ARM7 processor.

  11. Modelling and Simulation of Mobile Hydraulic Crane with Telescopic Arm

    Nielsen, Brian; Pedersen, Henrik Clemmensen; Andersen, Torben Ole

    2005-01-01

    paper a model of a loader crane with a flexible telescopic arm is presented, which may be used for evaluating control strategies. The telescopic arm is operated by four actuators connected hydraulically by a parallel circuit. The operating sequences of the individual actuators is therefore...... not controllable, but depends on the flow from the common control valve, flow resistances between the actuators and friction. The presented model incorporates structural flexibility of the telescopic arm and is capable of describing the dynamic behaviour of both the hydraulic and the mechanical system, including...... the relative movement of the individual mechanical bodies in the telescopic arm. The model is verified through comparisons between simulated and measured results for various operating conditions....

  12. Doppler ultrasound exam of an arm or leg

    ... page: //medlineplus.gov/ency/article/003775.htm Doppler ultrasound exam of an arm or leg To use ... this page, please enable JavaScript. This test uses ultrasound to look at the blood flow in the ...

  13. Why do arms extract less oxygen than legs during exercise?

    Calbet, J A L; Holmberg, H-C; Rosdahl, H;

    2005-01-01

    To determine whether conditions for O2 utilization and O2 off-loading from the hemoglobin are different in exercising arms and legs, six cross-country skiers participated in this study. Femoral and subclavian vein blood flow and gases were determined during skiing on a treadmill at approximately 76......% maximal O2 uptake (V(O2)max) and at V(O2)max with different techniques: diagonal stride (combined arm and leg exercise), double poling (predominantly arm exercise), and leg skiing (predominantly leg exercise). The percentage of O2 extraction was always higher for the legs than for the arms. At maximal...... exercise (diagonal stride), the corresponding mean values were 93 and 85% (n = 3; P

  14. Higher detection sensitivity of anxiolytic effects of diazepam by ledge-free open arm with opaque walled closed arm elevated plus maze in male rats.

    Horii, Yasuyuki; Kawaguchi, Maiko

    2015-11-01

    The elevated plus maze (EPM) is an established method for testing animal anxiety. However, EPM apparatuses and their features can differ among laboratories, most notably in the presence/absence of ledges on the open arm and/or the transparency/opaqueness of walls on the closed arm. The combined effects of these variable arm features on EPM behavior are not yet fully understood. In the present study, we prepared four types of EPM apparatus - open arms with (0.5 cm) or without (0 cm) ledges×closed arms with transparent or opaque walls - and compared the maze-exploration behavior of male Sprague-Dawley rats. We found that the presence of open arm ledges significantly increased the incidence of open arm exploration. Furthermore, time spent in the distal segment of the open arm was shortest in the apparatus that had open arms with no ledges and opaque closed arms (No-Ledges/Opaque), and was longest in the apparatus that had open arms with ledges and transparent closed arms (Ledges/Transparent). Additionally, the No-Ledges/Opaque apparatus could detect the effect of 0.5mg/kg diazepam, an anxiolytic drug, whereas the Ledges/Transparent apparatus could not. These results indicate that arm structure (features of both open and closed arms) significantly influences maze-exploratory behavior in rats, and that No-Ledges/Opaque apparatuses have higher detection sensitivity for anxiolytic effects of diazepam than that of Ledges/Transparent apparatuses.

  15. The Norma Arm Region Chandra Survey: X-ray Populations in the Spiral Arms

    Fornasini, Francesca M; Bodaghee, Arash; Krivonos, Roman A; An, Hongjun; Rahoui, Farid; Gotthelf, Eric V; Bauer, Franz E; Stern, Daniel

    2014-01-01

    We present a catalog of 1415 X-ray sources identified in the Norma arm region Chandra survey (NARCS), which covers a 2 deg x 0.8 deg region in the direction of the Norma spiral arm to a depth of $\\approx$20 ks. Of these sources, 1130 are point-like sources detected with $\\geq3\\sigma$ confidence in at least one of three energy bands (0.5-10, 0.5-2, and 2-10 keV), five have extended emission, and the remainder are detected at low significance. Since most sources have too few counts to permit individual classification, they are divided into five spectral groups defined by their quantile properties. We analyze stacked spectra of X-ray sources within each group, in conjunction with their fluxes, variability, and infrared counterparts, to identify the dominant populations in our survey. We find that $\\sim$50% of our sources are foreground sources located within 1-2 kpc, which is consistent with expectations from previous surveys. Approximately 20% of sources are likely located in the proximity of the Scutum-Crux an...

  16. User and clinician perspectives on DEKA arm: results of VA study to optimize DEKA arm.

    Resnik, Linda; Klinger, Shana Lieberman; Etter, Katherine

    2014-01-01

    This article summarizes feedback from Department of Veterans Affairs (VA) subjects and clinicians gathered during the VA optimization study of the DEKA Arm. VA subjects and clinicians tested two DEKA Arm prototypes (second-generation [gen 2] and third-generation [gen 3]). Features of the prototypes in three configurations are described. DEKA used feedback from the VA optimization study and from their own subjects to refine the gen 2 prototype. Thirty-three unique subjects participated in the VA evaluation; 26 participated in the gen 2 evaluation (1 subject participated twice), 13 participated in the gen 3 evaluation, and 5 participated in both gen 2 and gen 3 evaluations. Subject data were gathered through structured and open-ended surveys, interviews, and audio- and videotaped sessions. Study prosthetists and therapists provided ongoing feedback and completed surveys at the end of each subject's protocol. Eleven categories of feedback were identified: weight, cosmesis, hand grips, wrist design, elbow design, end-point control, foot controls, batteries and chargers, visual notifications, tactor, and socket features. Final feedback on the gen 3 was generally positive, particularly regarding improvements in wrist design, visual notifications, foot controls, end-point control, and cosmesis. Additional refinements to make the device lighter in weight, eliminate external wires and cables, and eliminate the external battery may further enhance its perceived usability and acceptability.

  17. Application of C-arm computed tomography in cardiology; Kardiale Anwendung der C-Arm-Computertomographie

    Rieber, J. [Klinikum der Ludwig-Maximilians-Universitaet Muenchen, Campus Innenstadt, Abteilung fuer Kardiologie, Medizinische Poliklinik, Muenchen (Germany); Rohkohl, C. [Friedrich-Alexander-Universitaet Erlangen-Nuernberg, Lehrstuhl fuer Mustererkennung, Department Informatik, Erlangen (Germany); Siemens AG, Healthcare Sector, Forchheim, Forchheim (Germany); Lauritsch, G. [Siemens AG, Healthcare Sector, Forchheim, Forchheim (Germany); Rittger, H. [Krankenhaus Coburg, Abteilung fuer Kardiologie, Coburg (Germany); Meissner, O. [Siemens AG, Healthcare Sector, Forchheim, Forchheim (Germany); Klinikum der Ludwig-Maximilians-Universitaet Muenchen, Institut fuer Klinische Radiologie, Muenchen (Germany)

    2009-09-15

    C-arm computed tomography is currently being introduced into cardiac imaging and offers the potential for three-dimensional imaging of the cardiac anatomy within the interventional environment. This detailed view is necessary to support complex interventional strategies, such as transcutaneous valve replacement, interventional therapy of atrial fibrillation, implantation of biventricular pacemakers and assessment of myocardial perfusion. Currently, the major limitation of this technology is its insufficient temporal resolution which limits the visualization of fast moving parts of the heart. (orig.) [German] Durch die Entwicklung der C-Arm-Computertomographie- (CACT-)Angiographie ist es erstmals moeglich, waehrend einer Herzkatheteruntersuchung eine detaillierte dreidimensionale Darstellung der kardialen Anatomie zu erhalten. Derartige zusaetzliche Informationen koennten die Durchfuehrung der immer komplexer werdenden Strategien der interventionellen Kardiologie wirkungsvoll unterstuetzen. Hierzu zaehlen u. a. der transkutane Klappenersatz, die interventionelle Behandlung von Vorhofflimmern, die Implantation biventrikulaerer Schrittmacher sowie die Beurteilung der Myokardperfusion. Die derzeit groesste Limitation dieser Methode ist die relativ geringe zeitliche Aufloesung, die aufgrund der Bewegung des Herzens die Anwendung dieser Technologie einschraenkt. (orig.)

  18. Motor asymmetry attenuation in older adults during imagined arm movements

    CHRISTOS ePAIZIS

    2014-03-01

    Full Text Available Laterality is an important feature of motor behavior. Several studies have shown that lateralization in right-handed young adults (i.e., right versus left arm superiority emerges also during imagined actions, that is when an action is internally simulated without any motor output. Such information, however, is lacking for elderly people and it could be valuable to further comprehend the evolution of mental states of action in normal aging. Here, we evaluated the influence of age on motor laterality during mental actions. Twenty-four young (mean age: 24.7  4.4 years and twenty-four elderly (mean age: 72.4  3.6 years participants mentally simulated and actually executed pointing movements with either their dominant-right or nondominant-left arm in the horizontal plane. We recorded and analyzed the time of actual and mental movements and looked for differences between groups and arms. In addition, electromyographic activity from arm muscle was recorded to quantify any enhancement in muscle activation during mental actions. Our findings indicated that both groups mentally simulated arm movements without activating the muscles of the right or the left arm above the baseline level. This finding suggests that young and, notably, elderly adults are able to generate covert actions without any motor output. We found that manual asymmetries (i.e., faster movements with the right arm were preserved in young adults for both actual and mental movements. In elderly adults, manual asymmetries were observed for actual but not for mental movements (i.e., equal movement times for both arms. These findings clearly indicate an age-related reduction of motor laterality during mental actions.

  19. Armed Conflict in Syria: Overview and U.S. Response

    2014-09-17

    Armed Conflict in Syria : Overview and U.S. Response Christopher M. Blanchard, Coordinator Specialist in Middle Eastern Affairs Carla E. Humud... Syria : Overview and U.S. Response 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR(S) 5d. PROJECT NUMBER 5e. TASK NUMBER...98) Prescribed by ANSI Std Z39-18 Armed Conflict in Syria : Overview and U.S. Response Congressional Research Service Summary The summer 2014

  20. A review of assistive devices for arm balancing.

    Dunning, A G; Herder, J L

    2013-06-01

    Due to neuromuscular disorders (e.g., Duchenne Muscular Dystrophy) people often loose muscle strength and become wheelchair bound. It is important to use muscles as much as possible. To allow this, and to increase independency of patients, an arm orthosis can be used to perform activities of daily life. The orthosis compensates for the gravity force of the arm, allowing people to perform movements with smaller muscle forces. For patients, the aesthetics of the orthosis is one of the critical issues. This paper presents the state-of-the-art in passive and wearable active arm orthoses, and investigates how to proceed towards a suitable structure for a wearable passive arm orthosis, that is able to balance the arm within its natural range of motion and is inconspicuous; in the ideal case it fits underneath the clothes. Existing devices were investigated with respect to the body interface, the volume, and the workspace. According to these evaluation metrics it is investigated to what extent the devices are wearable and inconspicuous. Furthermore, the balancing principle of the devices, the architecture, force transmission through the devices, and alignment with the body joints are investigated. It appears that there is only one wearable passive orthosis presented in literature. This orthosis can perform throughout the natural workspace of the arm, but is still too bulky to be inconspicuous. The other passive orthoses were conspicuous and mounted to the wheelchair. Except one, the wearable active orthoses were all conspicuous and heavy due to a large backpack to enclose the actuators. They also could not achieve the entire natural workspace of the human arm. A future design of an inconspicuous, wearable, passive arm orthoses should stay close to the body, be comfortable to wear, and supports pronation and supination.

  1. Hydraulic Arm Modeling via Matlab SimHydraulics

    Věchet, Stanislav; Krejsa, Jiří

    2009-01-01

    System modeling is a vital tool for cost reduction and design process speed up in most engineering fields. The paper is focused on modeling of hydraulic arm as a part of intelligent prosthesis project, in the form of 2DOF open kinematic chain. The arm model combines mechanical, hydraulic and electric subsystems and uses Matlab as modeling tool. SimMechanics Matlab extension is used for mechanical part modeling, SimHydraulics toolbox is used for modeling of hydraulic circuit used for actuating...

  2. Practical application with plc in manipulation of a robotic arm

    Cristian Barz

    2014-12-01

    Full Text Available This paper presents the use of a robotic arm PLC Siemens in order not using CNC commands. This is done by programming the PLC ladder diagram language that makes movement on the three axes of the arm by means of stepper motors. Required command console PLC is built with the help of a touch screen HMI Weintek. In the user interface are introduced distances and displacement speeds on the three axes.

  3. Implementing the ECOWAS Small Arms Moratorium : a new regionalism approach?

    Bakke, Joakim Michael

    2005-01-01

    In realisation of the huge consequences of the proliferation of small arms and light weapons, the Economic Community of West African States acted upon an initiative by President Konare of Mali in 1993. On 31 October 1998 a Moratorium on the Importation, Exportation and Manufacture of Small Arms and Light Weapons was signed and declared by 16 West African countries for a renewable period of three years. Now they had to begin the huge task of implementing this arrangement. The leading theor...

  4. Outer Arm in the Second Galactic Quadrant: Structure

    Du, Xinyu; Yang, Ji; Sun, Yan; Li, Facheng; Zhang, Shaobo; Zhou, Xin

    2016-01-01

    The lack of arm tracers, especially the remote tracers, is one of the most difficult problems that prevent us studying the Milky Way structure. Fortunately, with its high sensitivity CO survey, the Milky Way Imaging Scroll Painting (MWISP) project offers such an opportunity. As the project has completed about one third of its plan, the area of l=[100,150] deg, b=[-3,5] deg has been nearly covered. And the Outer arm of the Milky Way first clearly revealed its shape in the second galactic quadrant with the form of molecular gas --- this is the first time that the Outer arm is reported in such the large scale mapping of molecular gas. Using the 115 GHz 12CO(1-0) data of MWISP in the LSR velocity ~= [-100,-60] km s^-1 and in the area mentioned above, we have detected 481 molecular clouds in total, among them 332 (about 69\\%) are newly detected, and 457 probably belong to the Outer arm. The total mass of the detected Outer arm clouds is ~ 3.1*10^6 M_sun. Assuming the spiral arm is logarithmic spiral, the pitch ang...

  5. Robotic Mirror Therapy System for Functional Recovery of Hemiplegic Arms.

    Beom, Jaewon; Koh, Sukgyu; Nam, Hyung Seok; Kim, Wonshik; Kim, Yoonjae; Seo, Han Gil; Oh, Byung-Mo; Chung, Sun Gun; Kim, Sungwan

    2016-08-15

    Mirror therapy has been performed as effective occupational therapy in a clinical setting for functional recovery of a hemiplegic arm after stroke. It is conducted by eliciting an illusion through use of a mirror as if the hemiplegic arm is moving in real-time while moving the healthy arm. It can facilitate brain neuroplasticity through activation of the sensorimotor cortex. However, conventional mirror therapy has a critical limitation in that the hemiplegic arm is not actually moving. Thus, we developed a real-time 2-axis mirror robot system as a simple add-on module for conventional mirror therapy using a closed feedback mechanism, which enables real-time movement of the hemiplegic arm. We used 3 Attitude and Heading Reference System sensors, 2 brushless DC motors for elbow and wrist joints, and exoskeletal frames. In a feasibility study on 6 healthy subjects, robotic mirror therapy was safe and feasible. We further selected tasks useful for activities of daily living training through feedback from rehabilitation doctors. A chronic stroke patient showed improvement in the Fugl-Meyer assessment scale and elbow flexor spasticity after a 2-week application of the mirror robot system. Robotic mirror therapy may enhance proprioceptive input to the sensory cortex, which is considered to be important in neuroplasticity and functional recovery of hemiplegic arms. The mirror robot system presented herein can be easily developed and utilized effectively to advance occupational therapy.

  6. Effect of reverse shoulder design philosophy on muscle moment arms.

    Hamilton, Matthew A; Diep, Phong; Roche, Chris; Flurin, Pierre Henri; Wright, Thomas W; Zuckerman, Joseph D; Routman, Howard

    2015-04-01

    This study analyzes the muscle moment arms of three different reverse shoulder design philosophies using a previously published method. Digital bone models of the shoulder were imported into a 3D modeling software and markers placed for the origin and insertion of relevant muscles. The anatomic model was used as a baseline for moment arm calculations. Subsequently, three different reverse shoulder designs were virtually implanted and moment arms were analyzed in abduction and external rotation. The results indicate that the lateral offset between the joint center and the axis of the humerus specific to one reverse shoulder design increased the external rotation moment arms of the posterior deltoid relative to the other reverse shoulder designs. The other muscles analyzed demonstrated differences in the moment arms, but none of the differences reached statistical significance. This study demonstrated how the combination of variables making up different reverse shoulder designs can affect the moment arms of the muscles in different and statistically significant ways. The role of humeral offset in reverse shoulder design has not been previously reported and could have an impact on external rotation and stability achieved post-operatively.

  7. Limited angle C-arm tomosynthesis reconstruction algorithms

    Malalla, Nuhad A. Y.; Xu, Shiyu; Chen, Ying

    2015-03-01

    In this paper, C-arm tomosynthesis with digital detector was investigated as a novel three dimensional (3D) imaging technique. Digital tomosythses is an imaging technique to provide 3D information of the object by reconstructing slices passing through the object, based on a series of angular projection views with respect to the object. C-arm tomosynthesis provides two dimensional (2D) X-ray projection images with rotation (-/+20 angular range) of both X-ray source and detector. In this paper, four representative reconstruction algorithms including point by point back projection (BP), filtered back projection (FBP), simultaneous algebraic reconstruction technique (SART) and maximum likelihood expectation maximization (MLEM) were investigated. Dataset of 25 projection views of 3D spherical object that located at center of C-arm imaging space was simulated from 25 angular locations over a total view angle of 40 degrees. With reconstructed images, 3D mesh plot and 2D line profile of normalized pixel intensities on focus reconstruction plane crossing the center of the object were studied with each reconstruction algorithm. Results demonstrated the capability to generate 3D information from limited angle C-arm tomosynthesis. Since C-arm tomosynthesis is relatively compact, portable and can avoid moving patients, it has been investigated for different clinical applications ranging from tumor surgery to interventional radiology. It is very important to evaluate C-arm tomosynthesis for valuable applications.

  8. Ray tracing reconstruction investigation for C-arm tomosynthesis

    Malalla, Nuhad A. Y.; Chen, Ying

    2016-04-01

    C-arm tomosynthesis is a three dimensional imaging technique. Both x-ray source and the detector are mounted on a C-arm wheeled structure to provide wide variety of movement around the object. In this paper, C-arm tomosynthesis was introduced to provide three dimensional information over a limited view angle (less than 180o) to reduce radiation exposure and examination time. Reconstruction algorithms based on ray tracing method such as ray tracing back projection (BP), simultaneous algebraic reconstruction technique (SART) and maximum likelihood expectation maximization (MLEM) were developed for C-arm tomosynthesis. C-arm tomosynthesis projection images of simulated spherical object were simulated with a virtual geometric configuration with a total view angle of 40 degrees. This study demonstrated the sharpness of in-plane reconstructed structure and effectiveness of removing out-of-plane blur for each reconstruction algorithms. Results showed the ability of ray tracing based reconstruction algorithms to provide three dimensional information with limited angle C-arm tomosynthesis.

  9. INVESTIGATION OF STRESSES IN ARM TYPE ROTATING FLYWHEEL

    S. M. Dhengle

    2012-02-01

    Full Text Available There are many causes of flywheel failure. Among them, maximum tensile and bending stresses induced in the rim and tensile stresses induced in the arm under the action of centrifugal forces are the main causes of flywheel failure. Hence in this work evaluation of stresses in the rim and arm are studied using finite element method and results are validated by analytical calculations .The models of flywheel having four, six and eight no. arms are developed for FE analysis. The FE analysis is carried out for different cases of loading applied on the flywheel and the maximum Von mises stresses and deflection in the rim are determined. From this analysis it is found that Maximum stresses induced are in the rim and arm junction. Due to tangential forces, maximum bending stresses occurs near the hub end of the arm. It is also observed that for low angular velocity the effect gravity on stresses and deflection of rim and arm is predominant.

  10. Kinematic Analysis of Exoskeleton Suit for Human Arm

    Surachai Panich

    2010-01-01

    Full Text Available Problem statement: There are many robotic arms developed for providing care to physically disabled people. It is difficult to find robot designs in literature that articulate such a procedure. Therefore, it is our hope that the design work shown in this study may serve as a good example of a systematic method for rehabilitation robot design. Approach: The arm exoskeleton suit was developed to increase human's strength, endurance, or speed enabling them to perform tasks that they previously could not perform. It should not impede the user's natural motion and should be comfortable and safe to wear and easy to use. Although movement is difficult for them, they usually want to go somewhere by themselves. Results: The kinematic exoskeleton suit for human arms is simulated by MATLAB software. The exoskeleton suit of human arm consists of one link length, three link twists, two link offsets and three joint angles. Conclusion: This study introduced the kinematic of exoskeleton suit for human arm. The exoskeleton suit can be used to be instrument for anyone who needs to improve human's performance. It will increase the strength of human that can lift heavy load or help handicapped patients, who cannot use their arm.

  11. Star formation in galaxies: the role of spiral arms

    Dobbs, Clare

    2013-01-01

    Studying star formation in spiral arms tells us not only about the evolution of star formation, and molecular clouds, but can also tell us about the nature of spiral structure in galaxies. I will address both these topics using the results of recent simulations and observations. Galactic scale simulations are beginning to examine in detail the evolution of GMCs as they form in spiral arms, and then disperse by stellar feedback or shear. The overall timescale for this process appears comparable to the crossing time of the GMCs, a few Myrs for $10^5$ M$_{\\odot}$ clouds, 20 Myr or so for more massive GMCs. Both simulations and observations show that the massive clouds are found in the spiral arms, likely as a result of cloud-cloud collisions. Simulations including stars should also tell us about the stellar age distribution in GMCs, and across spiral arms. More generally, recent work on spiral galaxies suggests that the dynamics of gas flows in spiral arms are different in longlived and transient spiral arms, re...

  12. Digital Signature Based Fax Machine Using ARM9 and Linux

    Ch. Komali

    2013-01-01

    Full Text Available In this method we are having the S3C2240A (ARM9 Board which is ported with Linux in it. And this ARM9 board with Linux will be connected to the Touch Screen device. This ARM9 board intern will be connected to the LAN network (Ethernet. To design this fax machine we are using two Arm controller boards. One Arm board will keep at fax Transmission side and another board will keep at fax receiving side. By using the Ethernet we will send and receive the fax, for that we are using TCP/IP server and TCP/IP client. In this fax machine we have too many options on touch screen of arm like retrieve, sign, send, save etc. By selecting the retrieve option we can see the received text data on touch screen. If we want to transmit text data, we can select send option, then the fax will sent to the destination. On the receiving side, the received fax will be displayed on LCD touch screen. If necessary, we can sign directly on the touch panel by selecting the sign option. If we want to retransmit that signed document, we should active server. In this way bidirectional transmission and reception is possible

  13. SYNTHESIS, CHARACTERIZATION AND NANOPARTICLE FORMATION OF STAR-SHAPED POLY(L-LACTIDE) WITH SIX ARMS

    Lu Wang; Chen Cai; Chang-Ming Dong

    2008-01-01

    Well-defined star-shaped poly(L-lactide) with six arms (sPLLA) was synthesized via the ring-openingpolymerization of I.,-lactide using dipentaerythritol as initiator and stannous octoate as catalyst in bulk at 125~C. The effectsof molar ratios of both monomer to initiator and monomer to catalyst on the molecular weights of as-synthesized sPLLApolymers were in detail investigated. The molecular weights of sPLLA polymers linearly increased with the molar ratio ofmonomer to initiator, and the molecular weight distribution was narrow (Mw/Mn=1.04-1.12). However, the molar ratio ofmonomer to catalyst had no apparent influence on the polymer molecular weight. Moreover, the maximal melting point, thecrystallization temperature, and the degree of crystallinity of sPLLA polymers increased with the increasing molecularweight, meanwhile they exhibited a spherulitic morphology. Furthermore, spherical nanoparticles (less than 100 nm) couldbe generated by direct injection of sPLLA solutions into distilled water, and the average size of nanoparticles could beadjusted through both the macromolecular architecture and the polymer molecular weight, respectively.

  14. Présences mémorielles et carences fictionnelles : L’espace du deuil dans le cinéma indépendant new-yorkais post-11/09

    Vincent SOULADIÉ

    2011-09-01

    Full Text Available Alors que les majors hollywoodiennes ont observé une distance prudente à l’égard de l’évocation et de la représentation des attentats du onze septembre, plusieurs cinéastes indépendants new-yorkais ont pour leur part choisi de tourner rapidement des films dont les récits se situent explicitement dans le contexte immédiat de l’après-catastrophe et dans le décor meurtri de New York. Les films indépendants se caractérisent principalement par leur absence de contraintes artistiques imposées, par la modestie de leurs moyens, par leur liberté de ton, et par l’appartenance marquée des cinéastes à leur milieu culturel d’origine. En tenant compte de ces facteurs, intimité du tournage et intimité du récit, il importe de questionner l’orientation adoptée par le cinéma indépendant new yorkais pour traiter le sujet dramatique du onze septembre. Un corpus filmique se dégage et nous semble cristalliser des enjeux esthétiques et discursifs communs autour du onze septembre comme contexte diégétique et vecteur narratif. Lien communautaire, équilibre familial, harmonie conjugale ou quête identitaire se mesurent dans ces films à l’échelle englobante du trauma collectif.Whereas the Hollywood majors observed a careful distance in the evocation and the representation of 9/11, several filmmakers belonging to New York's independent cinema chose to rapidly direct movies set in its immediate aftermath and in the bruised landscape of New York. These movies are characterized by their low production budget, by their independent tone and their absence of exterior artistic constraint, and by the clear signs that the filmmakers 'belong' to the city. Taking into account the intimacy of both shooting and story, we will examine the orientation adopted in order to deal with the tragedy of 9/11 by New York's independent cinema. A number of movies indeed raise common aesthetic and discursive issues with regard to 9/11 as narrative context

  15. Optical studies of directly synthesized trans-polyacetylene films

    Nishioka, T. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan); Suruga, K. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan); Natsume, N. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan); Ishikawa, K. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan); Takezoe, H. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan); Fukuda, A. [Department of Organic and Polymeric Materials, Tokyo Institute of Technology, 2-12-1 O-okayama, Meguro-ku, Tokyo 152 (Japan)

    1995-03-01

    We studied optical spectra of directly synthesized trans-polyacetylene films. Reflection and resonance Raman spectra show that effective conjugation length distribution has longer average length and narrower width than that of ordinary thermoisomerized films. Moreover, ESR spectra show that directly synthesized films have fewer defects than ordinary thermoisomerized films. (orig.)

  16. Syntheses of (±-Romucosine and (±-Cathafiline

    Surachai Nimgirawath

    2006-11-01

    Full Text Available The structures previously assigned to (--romucosine and (+-cathafiline, N-(methoxycarbonyl aporphine alkaloids from Rollina mucosa (Annonaceae and Cassytha filiformis (Lauraceae respectively, have been confirmed by total syntheses of the racemic substances. The key step of the syntheses involved formation of ring C of the aporphines by a radical-initiated cyclisation.

  17. Diaminoalkane as Spacer Arm between Polystyrene and - Cylodextrin in Affinity Chromatography for -Amylase Separation

    Sri Widarti* ,

    2014-02-01

    Full Text Available Stationary phase design in affinity chromatography has to fulfill at least two requirements: non-specific interaction between solid support and or spacer arm and protein target or others is minimal and specific interaction between ligand and protein target is maximal. In this study, stationary phases that consist of polystyrene (PS as solid support, diaminoalkane as spacer arm and with and without βCD as a ligand are performed in α-amylase separation. Therefore, the research was carried out in two steps; stationary phase preparation and adsorption parameter determination towards α-amylase. Stationary phases that consist of PS, 1,6-diaminohexane and βCD (PS–DAH–βCD and without βCD (PS–DAH were synthesized. Stationary phase structure was confirmed by FTIR, 13C NMR solid, 13C dan 1H NMR liquid spectroscopy. Other stationary phases, PS–DAP–βCD and PS–DAP that consist of 1,2-diaminopropane (DAP as spacer arm was synthesized in the previous research. Dynamic α-amylase adsorption isotherm on PS–DAP and PS–DAH shows that both of them did not fix any adsorption isotherm model. The average binding capacity are 0.071 and 0.31 mg/0.1 g resin, respectively. In another hand, PS–DAP–βCD and PS–DAH–βCD fix isotherm adsorption Langmuir model and the adsorption parameters; the maximum binding capacity (qm are 5.5 and 2.1 mg/0.1 g resin, adsorption equilibrium constant (KA are 0.01965 and 0.01925 μL—1 and desorption rate constant (k2 are 0.201 and 0.774 mg s—1 , respectively. Due to adsorption parameters, PS–DAP–βCD offer the best adsorption capacity and selectivity as stationary phase in affinity chromatography for α-amylase separation.

  18. Estimation of stature from arm span, arm length and tibial length among Bengalee children aged 3-11 years

    B. Dorjee

    2016-05-01

    Full Text Available Background: Estimation of human stature has significant bearings on assessment of growth, nutritional status and personal identification. Often the prediction of stature from bone remains or body parts of children is complicated by the ongoing growth. Despite these disadvantages, a situation may arise where estimation of a child’s stature becomes important. In such a situation equations derived for adults cannot be applicable. Materials and Methods: The present cross-sectional study was conducted among 240 children (boys: 116; girls: 124 aged between 3 to 11 years and belonging to the Bengali Hindu Caste Population from Naxalbari, District Darjeeling, West Bengal, India. Standard procedures were followed to record stature, arm span, arm length and tibial length. Intra- and inter- observer technical errors of the measurement (TEM were calculated. One way analysis of variance (ANOVA, correlation, linear regression and stepwise regression were used to analyze the data. Result: The boys had higher mean age, mean stature, mean arm span, mean arm length and tibial length than girls. However, using ANOVA, the sex difference were not significant (p>0.05. Stature was observed to be positively and significantly correlated with all the anthropometric variables among both sexes. When stepwise regression was used, it was observed that the correlation coefficient (R and the coefficient of determination (R2 increased with inclusion of arm length and tibial length with arm span as the predictor. The addition of age as a variable further increased the predictive accuracy of the model. Predictive accuracies of the equations were higher among girls than boys. Conclusion: The present study has observed strong associations of stature with age, arm span, arm length and tibia length. The strength of prediction in general increased with the increasing number of parameters and from using linear to stepwise multiple regressions. Addition of age as a variable influenced

  19. Determination of arm fat area and arm muscle area norms in children 6-12 years of age in Bursa.

    Günay, U; Sapan, N; Salih, C; Doğruyol, H

    1990-01-01

    Since arm fat area and arm muscle area measurements are said to assess the calorie and protein reserves in the body more accurately than triceps skinfold thickness measurements, we decided to use this system on 1497 girls and 1651 boys who were pupils in elementary schools in Bursa. From the data obtained, percentile norms for the children aged between 6-12 were calculated and percentile curves were drawn. The data that we collected can be used in future nutritional surveys.

  20. 基于ARM920 T嵌入式低频数字扫描仪设计%Design of ARM920T-based embedded low-frequency digital scanner

    刘顺财

    2014-01-01

    系统采用ARM920T作为核心处理器,以低频信号作为信号源,采用DDS技术,从而实现相频、幅度、频率特性的分析仪器,能够简单地实现信号源的时域和具体参数的波形。系统主要由ARM920T控制处理器、DDS扫频模块、ADC采样模块、DAC输出模块、检波滤波器模块、扫频信号源幅度模块组成。其中处理器采样ARM920T,扫频信号源采样DDS芯片AD9851,检波模块以AD637JQ芯片构成,相位检测模块由AD8302芯片构成,DAC芯片TLV5618控制扫频信号的幅度。实验结果表明,仪器可以检测20 Hz~1 MHz左右的频率信号源,可以显示在LCD屏幕上,直观地读出频率、幅度和相位。%Direct digital synthesizer (DDS )technology was employed to implement phase frequen-cy,amplitude,frequency characteristics analysis instruments,in which advanced RISC machines (ARM)920T was adopted as core processor and low frequency signal as the signal source.The sys-tem can simply realize the time domain of signal sources and specific parameters waveforms (simple signal source in the time domain waveform and specific parameters ),which mainly consists of ARM920T processor,DDS frequency sweeping module,analog to digital converter (ADC)sampling module,digital to analog converter (DAC)output module,waveforms detection filter module and frequency sweeping signal source amplitude module.The processor sampling was controlled by ARM920T,while the frequency sweeping signal source sampling was implemented by DDS chip AD9851.The waveform detection module was controlled by AD637JQ chip.The phase detection module and the frequency sweeping signal amplitude were controlled by AD8302 chip and the DAC chip TLV5618,respectively.The instrument can detect frequency signal source ranged between 20 Hz to 1 MHz and can directly display frequency,amplitude and phase on the liquid crystal display (LCD)screen.

  1. Respiration and cardio-respiratory interactions during sleep in space: influence of gravity / Respiration et interaction cardio-respiratoire pendant le sommeil en apesanteur: influence de la gravité

    Pereira de Sá, Rui Carlos

    2008-01-01

    Le principal objectif de ce travail est l’étude de l’influence de la pesanteur sur la mécanique respiratoire et le contrôle de la respiration, ainsi que sur les interactions cardio-respiratoires pendant les différents stades du sommeil. Le chapitre introductif présente le contexte général et les objectifs de la thèse. Des sections abordant le sommeil, la respiration, et l’interaction cardio-respiratoire y sont présentées, résumant l’état actuel des connaissances sur les effets de la pes...

  2. Société Musicale Indépendante – SMI, sua fundação, sua bandeira e o testemunho da imprensa especializada em torno de sua primeira temporada artística

    Danieli Verônica Longo Benedetti

    2015-06-01

    Full Text Available O presente artigo, segmento de pesquisa de Pós-Doutorado sediada no Departamento de Música da ECA/USP e amparada pela FAPESP, pretende traçar o histórico da Société Musicale Indépendante – SMI, sociedade musical francesa criada em 1909 por um grupo de compositores entre os quais Maurice Ravel, Charles Koechlin e Florent Schmitt, cujo principal objetivo foi promover a música contemporânea sem distinção de escola e nacionalidade. Fundamentado em material coletado no acervo privado de Charles Koechlin e da Bibliothèque nationale de France-BnF o texto pretende ainda uma reflexão sobre a primeira temporada artística da SMI por meio do testemunho da crítica especializada publicado por importantes órgãos de imprensa da época.

  3. Assessment voice synthesizers for reading in digital books

    Sérvulo Fernandes da Silva Neto

    2013-07-01

    Full Text Available The digital accessibility shows ways to information access in digital media that assist people with different types of disabilities to a better interaction with the computer independent of its limitations. Of these tools are composed by voice synthesizers, that supposedly simplifying their access to any recorded knowledge through digital technologies. However such tools have emerged originally in countries foreign language. Which brings us to the following research problem: the voice synthesizers are appropriate for reading digital books in the Portuguese language? The objective of this study was to analyze and classify different software tools voice synthesizers in combination with software digital book readers to support accessibility to e-books in Portuguese. Through literature review were identified applications software voice synthesizers, composing the sample analyzed in this work. We used a simplified version of the method of Multiple Criteria Decision Support - MMDA, to assess these. In the research 12 were considered readers of e-books and 11 software voice synthesizer, tested with six formats of e-books (E-pub, PDF, HTML, DOC, TXT, and Mobi. In accordance with the results, the software Virtual Vision achieved the highest score. Relative to formats, it was found that the PDF has measured a better score when summed the results of the three synthesizers. In the studied universe contacted that many synthesizers simply cannot be used because they did not support the Portuguese language.

  4. Optimization on robot arm machining by using genetic algorithms

    Liu, Tung-Kuan; Chen, Chiu-Hung; Tsai, Shang-En

    2007-12-01

    In this study, an optimization problem on the robot arm machining is formulated and solved by using genetic algorithms (GAs). The proposed approach adopts direct kinematics model and utilizes GA's global search ability to find the optimum solution. The direct kinematics equations of the robot arm are formulated and can be used to compute the end-effector coordinates. Based on these, the objective of optimum machining along a set of points can be evolutionarily evaluated with the distance between machining points and end-effector positions. Besides, a 3D CAD application, CATIA, is used to build up the 3D models of the robot arm, work-pieces and their components. A simulated experiment in CATIA is used to verify the computation results first and a practical control on the robot arm through the RS232 port is also performed. From the results, this approach is proved to be robust and can be suitable for most machining needs when robot arms are adopted as the machining tools.

  5. The importance of domestic law to international arms control

    Lehman, R.F. II

    1993-11-01

    Studies of arms control and disarmament tend to focus on political, military, and diplomatic processes. Recently, in the context of the conversion of defense activities to civilian use, the economic aspects of arms control have also received renewed interest. The legal dimension, however, is in need of fresh examination. Both international and domestic law are sailing increasingly in uncharted waters. Recent arms control agreements and related developments in international peacekeeping have expanded the scope of international law and altered how one perceives certain fundamentals, including the principle of national sovereignty. Still, the nation state is largely unchallenged as the primary actor in international affairs. National governments retain near absolute sovereign rights and responsibilities even in an age of trans-national economic integration and codified international norms for human rights, freedom of the press, and the peaceful resolution of disputes. Indeed, the role of domestic law in arms control and disarmament may be more significant now than ever before. A brief review of relationships between arms control and domestic law should illustrate ways in which ones thinking has been underestimating the importance of domestic law. Hopefully, this survey will set the stage properly for the excellent, more detailed case studies by Elinor Hammarskjold and Alan Crawford. Toward that end, this paper will highlight a number of more general, and sometimes provocative, themes. These themes should be kept in mind when those two complementary presentations are considered.

  6. One-Armed Spiral Instability in a Model Protostar

    Johnson, M. S.; Pickett, B. K.; Durisen, R. H.

    1995-05-01

    Analytic and numerical work by several research groups over the last five years have shown that one-armed spiral instabilities (e.g. SLING) may play a crucial role in the evolution of protostars and protostellar disks. One-armed spirals have been shown to be effective at transporting angular momentum and mass and producing modest fragmentation. We have recently conducted a numerical survey of global nonaxisymmetric instabilities in self-gravitating, rapidly rotating protostar models (Pickett et al. 1995, ApJ., submitted). One interesting result is that the protostar models which correspond to equilibrium objects formed from the dynamical collapse of centrally condensed molecular clouds are quite unstable to one-armed spiral disturbances. These one-armed instabilities occur under conditions not anticipated by the work of others. Although significant mass and angular momentum transport occurs, the protostar does not fragment. This poster presents a detailed investigation of the dramatic one-armed mode detected in Pickett et al. (1995). We use a variety of initial conditions and a second-order 3D hydrodynamics code to probe the nature of the instability in three dimensions. The relevance of this work to the formation of binaries and planetary systems will be discussed. This work is supported by NASA grant NAGW-3399.

  7. Target allocation and prioritized motion planning for MIRADAS probe arms

    Sabater, Josep; Riera-Ledesma, Jorge; Torres, Santiago; Garzón, Francisco; Torra, Jordi; Gómez, José M.

    2016-07-01

    The Mid-resolution InfRAreD Astronomical Spectrograph (MIRADAS) is a near-infrared multi-object echelle spectrograph for the 10.4-meter Gran Telescopio Canarias. The instrument has 12 pickoff mirror optics on cryogenic probe arms, enabling it to concurrently observe up to 12 user-defined objects located in its field-of-view. In this paper, a method to compute collision-free trajectories for the arms of MIRADAS is presented. We propose a sequential approach that has two stages: target to arm assignment and motion planning. For the former, we present a model based on linear programming that allocates targets according to their associated priorities. The model is constrained by two matrices specifying the targets' reachability and the incompatibilities among each pair of feasible target-arm pairs. This model has been implemented and experiments show that it is able to determine assignments in less than a second. Regarding the second step, we present a prioritized approach which uses sampled-based roadmaps containing a variety of paths. The motions along a given path are coordinated with the help of a depth-first search algorithm. Paths are sequentially explored according to how promising they are and those not leading to a solution are skipped. This motion planning approach has been implemented considering real probe arm geometries and joint velocities. Experimental results show that the method achieves good performance in scenarios presenting two different types of conflicts.

  8. Grand Design Spiral Arms in A Young Forming Circumstellar Disk

    Tomida, Kengo; Hosokawa, Takashi; Sakurai, Yuya; Lin, Chia Hui

    2016-01-01

    We study formation and long-term evolution of a circumstellar disk in a collapsing molecular cloud core using a resistive magnetohydrodynamic simulation. While the formed circumstellar disk is initially small, it grows as accretion continues and its radius becomes as large as 200 AUs toward the end of the Class-I phase. A pair of grand-design spiral arms form due to gravitational instability in the disk, and they transfer angular momentum in the highly resistive disk. Although the spiral arms disappear in a few rotations as expected in a classical theory, new spiral arms form recurrently as the disk soon becomes unstable again by gas accretion. Such recurrent spiral arms persist throughout the Class-0 and I phase. We then perform synthetic observations and compare our model with a recent high-resolution observation of a young stellar object Elias 2-27, whose circumstellar disk has grand design spiral arms. We find an excellent agreement between our theoretical model and the observation. Our model suggests tha...

  9. Manipulability measure of dual-arm space robot and its application to design an optimal configuration

    Zhang, Bo; Liang, Bin; Wang, Xueqian; Li, Gang; Chen, Zhang; Zhu, Xiaojun

    2016-11-01

    Coupling effect exists among different arms and the base in a multi-arm space robot. The manipulability measure of one arm can be affected by the base and the other arms, which has important effects on the configuration optimization, the singularity avoidance and the compliant control. The manipulability measure for a multi-arm space robot is more complex than that of a single-arm space robot. At present, the manipulability measure of a multi-arm space robot has not been studied. In the paper, a new concept of manipulability measure is applied to analyze the manipulability measure for a dual-arm space robot, especially for the manipulability measure of the mission arm subjecting to the influence from coupling effect of auxiliary arm and the base. Based on the manipulability measure of mission arm, a performance index is introduced and used to design and choose an optimization configuration for a dual-arm space robot. Finally, a plane dual-arm space robot is simulated, which is illustrated the influence of joint angles and the base attitude on mission arm's manipulability measure. Simulation results show that the proposed manipulability measure is useful for a multi-arm space robot and optimal configuration can be extended and applied to the coordinated soft rendezvous and docking and the target capture in the field of on-orbit servicing.

  10. Well-defined 4-arm stars with hydroxy-terminated polyethylene, polyethylene-b-polycaprolactone and polyethylene-b-(polymethyl methacrylate) 2 arms

    Zhang, Zhen

    2016-07-20

    Bis-boron-thexyl-silaboracycle was prepared by hydroboration of 1,4-bis(methyldivinylsilyl)butane with thexylborane and used to initiate the polyhomologation of dimethylsulfoxonium methylide to afford well-defined hydroxy-terminated 4-arm polyethylene (PE) stars. The synthesized PE stars were transformed to (PE-b-PCL)4 starblock copolymers via the ring-opening polymerization of ϵ-caprolactone (CL) initiated by the hydroxyl end groups of (PE-OH)4 in the presence of P2-tBu phosphazene base. Esterification of the hydroxyl groups of the OH-terminated PE star with 2,2-dichloroacetyl chloride led to (PE-Cl2)4 which was used as initiator (eight initiating atom transfer radical polymerization, ATRP, sites) for the synthesis of (PE-b-PMMA2)4 dendrimer-like stars by the ATRP of methyl methacrylate (MMA). All intermediates and final products were characterized by high temperature gel permeation chromatography and proton nuclear magnetic resonance spectroscopy. © 2016 The Royal Society of Chemistry.

  11. Supporting the President's Arms Control and Nonproliferation Agenda: Transparency and Verification for Nuclear Arms Reductions

    Doyle, James E [Los Alamos National Laboratory; Meek, Elizabeth [Los Alamos National Laboratory

    2009-01-01

    The President's arms control and nonproliferation agenda is still evolving and the details of initiatives supporting it remain undefined. This means that DOE, NNSA, NA-20, NA-24 and the national laboratories can help define the agenda, and the policies and the initiatives to support it. This will require effective internal and interagency coordination. The arms control and nonproliferation agenda is broad and includes the path-breaking goal of creating conditions for the elimination of nuclear weapons. Responsibility for various elements of the agenda will be widely scattered across the interagency. Therefore an interagency mapping exercise should be performed to identify the key points of engagement within NNSA and other agencies for creating effective policy coordination mechanisms. These can include informal networks, working groups, coordinating committees, interagency task forces, etc. It will be important for NA-20 and NA-24 to get a seat at the table and a functional role in many of these coordinating bodies. The arms control and nonproliferation agenda comprises both mature and developing policy initiatives. The more mature elements such as CTBT ratification and a follow-on strategic nuclear arms treaty with Russia have defined milestones. However, recent press reports indicate that even the START follow-on strategic arms pact that is planned to be complete by the end of 2009 may take significantly longer and be more expansive in scope. The Russians called for proposals to count non-deployed as well as deployed warheads. Other elements of the agenda such as FMCT, future bilateral nuclear arms reductions following a START follow-on treaty, nuclear posture changes, preparations for an international nuclear security summit, strengthened international safeguards and multilateral verification are in much earlier stages of development. For this reason any survey of arms control capabilities within the USG should be structured to address potential needs

  12. Syntheses of (+)-cytisine, (-)-kuraramine, (-)-isokuraramine, and (-)-jussiaeiine A.

    Honda, Toshio; Takahashi, Rie; Namiki, Hidenori

    2005-01-21

    Total syntheses of (+)-cytisine, (-)-kuraramine, (-)-isokuraramine, and (-)-jussiaeiine A were achieved via a samarium diiodide-promoted reductive deamination reaction, followed by simultaneous recyclization of a proline derivative to give the corresponding delta-lactam derivative, as a key step.

  13. GaN Nanowires Synthesized by Electroless Etching Method

    Najar, Adel

    2012-01-01

    Ultra-long Gallium Nitride Nanowires is synthesized via metal-electroless etching method. The morphologies and optical properties of GaN NWs show a single crystal GaN with hexagonal Wurtzite structure and high luminescence properties.

  14. Template Syntheses and Crystal Structures of Hexaaza Macrocyclic Complexes with C-Methyl Substituents

    2005-01-01

    Two new macrocyclic complexes with C-methyl substituents on the framework,namely, [CuL](ClO4)2 (L = 5,12-dimethyl- 1,8-dihydroxyethyl- 1,3,6,8,10,13-hexaazacyclotetradecane) 1 and [NiL](ClO4)2 2, have been synthesized and structurally characterized through X-ray diffraction analysis. Also, crystal structure of [CuL1](ClO4)2 (L1 = 1,8-dimethyl- 1,3,6,8,10,13- hexaazacyclotetradecane) 3 has been determined. Crystal data for 1: C14H32C12CuN6O10, Mr = 578.90,monoclinic, P21In, a = 8.3529(11), b = 10.8105(17), c = 13.3709(17) A, β = 105.189(10)°, V =1165.2(3) A3, Z = 2, Dc = 1.650 g/cm3, F(000) = 602, λ(MoKα) = 0.71073 A,μ = 1.229 mm-1, R =0.0474 and wR = 0.0895 for 2771 observed reflections (I > 2σ(I)). Crystal data for 2:C14H32C12N6NiO10, Mr = 574.07, monoclinic, P21/c, a = 8.3636(12), b = 12.997(2), c = 10.764(2) A,β = 99.31 (2)°, V = 1154.7(3) A3, Z = 2, Dc = 1.651 g/cm3, F(000) = 600, λ(MoKα) = 0.71073 A,μ =1.134 mm-1, R = 0.0380 and wR = 0.0796 for 2670 observed reflections (I > 2σ(Ⅰ)). Crystal data for 3. C10H26Cl2CuN6O8, Mr = 492.81, monoclinic, P21/n, a = 8.4860(17), b = 8.6320(17), c = 12.662(3)A, β = 103.40(3)°, V = 902.2(3) A3, Z = 2, Dc = 1.814 g/cm3, F(000) = 510, λ(MoKα) = 0.71073 A,μ = 1.562 mm - 1, R = 0.0505 and wR = 0. 1 061 for 1967 observed reflections (I > 2σ(Ⅰ)). Complexes 1 and 2 are isostructural with the metal ions situated at the inversion center. Hydrogen bonds between O atoms of pendant and perchlorate anion give rise to a two-dimensional supramolecular layer. The Cu(Ⅱ) ions of compounds 1 and 3 adopt distorted axially-elongated octahedral coordinate geometry, and the nickel(Ⅱ) ion in complex 2 is four-coordinated with a square-planar configuration.

  15. Arm Motion Recognition and Exercise Coaching System for Remote Interaction

    Hong Zeng

    2016-01-01

    Full Text Available Arm motion recognition and its related applications have become a promising human computer interaction modal due to the rapid integration of numerical sensors in modern mobile-phones. We implement a mobile-phone-based arm motion recognition and exercise coaching system that can help people carrying mobile-phones to do body exercising anywhere at any time, especially for the persons that have very limited spare time and are constantly traveling across cities. We first design improved k-means algorithm to cluster the collecting 3-axis acceleration and gyroscope data of person actions into basic motions. A learning method based on Hidden Markov Model is then designed to classify and recognize continuous arm motions of both learners and coaches, which also measures the action similarities between the persons. We implement the system on MIUI 2S mobile-phone and evaluate the system performance and its accuracy of recognition.

  16. Gesture Recognition Based on the Probability Distribution of Arm Trajectories

    Wan, Khairunizam; Sawada, Hideyuki

    The use of human motions for the interaction between humans and computers is becoming an attractive alternative to verbal media, especially through the visual interpretation of the human body motion. In particular, hand gestures are used as non-verbal media for the humans to communicate with machines that pertain to the use of the human gestures to interact with them. This paper introduces a 3D motion measurement of the human upper body for the purpose of the gesture recognition, which is based on the probability distribution of arm trajectories. In this study, by examining the characteristics of the arm trajectories given by a signer, motion features are selected and classified by using a fuzzy technique. Experimental results show that the use of the features extracted from arm trajectories effectively works on the recognition of dynamic gestures of a human, and gives a good performance to classify various gesture patterns.

  17. Measuring spiral arm torques results for M100

    Gnedin, O Y; Frei, Z; Gnedin, Oleg Y; Goodman, Jeremy; Frei, Zsolt

    1995-01-01

    Spiral arms, if they are massive, exert gravitational torques that transport angular momentum radially within galactic disks. These torques depend not on the pattern speed or permanence of the arms but only on the nonaxisymmetric mass distribution. Hence the torques can be measured from photometry. We demonstrate this using gri CCD data for M100 (NGC 4321). Since we find consistency among the three bands, we believe that dust and young stars in the arms do not seriously bias our results. If the present epoch is representative, the timescale for redistribution of angular momentum in M100 is 5-10 Gyr, the main uncertainty being the mass-to-light ratio of the disk.

  18. The formation of spiral arms and rings in barred galaxies

    Romero-Gomez, M; Masdemont, J J; García-Gomez, C

    2007-01-01

    We propose a new theory to explain the formation of spiral arms and of all types of outer rings in barred galaxies. We have extended and applied the technique used in celestial mechanics to compute transfer orbits. Thus, our theory is based on the chaotic orbital motion driven by the invariant manifolds associated to the periodic orbits around the hyperbolic equilibrium points. In particular, spiral arms and outer rings are related to the presence of heteroclinic or homoclinic orbits. Thus, R1 rings are associated to the presence of heteroclinic orbits, while R1R2 rings are associated to the presence of homoclinic orbits. Spiral arms and R2 rings, however, appear when there exist neither heteroclinic nor homoclinic orbits. We examine the parameter space of three realistic, yet simple, barred galaxy models and discuss the formation of the different morphologies according to the properties of the galaxy model. The different morphologies arise from differences in the dynamical parameters of the galaxy.

  19. Searching for the Perseus arm in the anticenter direction

    Figueras F.

    2012-02-01

    Full Text Available Here we propose a two step approach to provide new insights on the outer spiral arm pattern of the Milky Way: 1 a Strömgren photometric survey to map the stellar space density of moderate young type stars tracing the Perseus arm, and 2 a spectroscopic survey to determine the velocity perturbation due to the density wave through accurate Radial Velocity (RV, hereafter. First reduced preliminary data suggest an overdensity around 1.5–2 kpc, probably associated with the Perseus arm. Results from this project will present a significant step towards mapping the spiral structure between the second and the third galactic quadrant, where the determination of kinematic distances is not possible.

  20. A Parallax-based Distance Estimator for Spiral Arm Sources

    Reid, M J; Menten, K M; Brunthaler, A

    2016-01-01

    The spiral arms of the Milky Way are being accurately located for the first time via trigonometric parallaxes of massive star forming regions with the BeSSeL Survey, using the Very Long Baseline Array and the European VLBI Network, and with the Japanese VERA project. Here we describe a computer program that leverages these results to significantly improve the accuracy and reliability of distance estimates to other sources that are known to follow spiral structure. Using a Bayesian approach, sources are assigned to arms based on their (l,b,v) coordinates with respect to arm signatures seen in CO and HI surveys. A source's kinematic distance, displacement from the plane, and proximity to individual parallax sources are also considered in generating a full distance probability density function. Using this program to estimate distances to large numbers of star forming regions, we generate a realistic visualization of the Milky Way's spiral structure as seen from the northern hemisphere.