Superheavy elements

CERN Document Server

Hofmann, S

1999-01-01

The outstanding aim of experimental investigations of heavy nuclei is the exploration of spherical 'SuperHeavy Elements' (SHEs). On the basis of the nuclear shell model, the next double magic shell-closure beyond sup 2 sup 0 sup 8 Pb is predicted at proton numbers between Z=114 and 126 and at neutron number N=184. All experimental efforts aiming at identifying SHEs (Z>=114) were negative so far. A highly sensitive search experiment was performed in November-December 1995 at SHIP. The isotope sup 2 sup 9 sup 0 116 produced by 'radiative capture' was searched for in the course of a 33 days irradiation of a sup 2 sup 0 sup 8 Pb target with sup 8 sup 2 Se projectiles, however, only cross-section limits were measured. Positive results were obtained in experiments searching for elements from 110 to 112 using cold fusion and the 1n evaporation channel. The produced isotopes were unambiguously identified by means of alpha-alpha correlations. Not fission, but alpha emission is the dominant decay mode. The measurement ...

Chemistry of superheavy elements

International Nuclear Information System (INIS)

Schaedel, M.

2012-01-01

The chemistry of superheavy elements - or transactinides from their position in the Periodic Table - is summarized. After giving an overview over historical developments, nuclear aspects about synthesis of neutron-rich isotopes of these elements, produced in hot-fusion reactions, and their nuclear decay properties are briefly mentioned. Specific requirements to cope with the one-atom-at-a-time situation in automated chemical separations and recent developments in aqueous-phase and gas-phase chemistry are presented. Exciting, current developments, first applications, and future prospects of chemical separations behind physical recoil separators ('pre-separator') are discussed in detail. The status of our current knowledge about the chemistry of rutherfordium (Rf, element 104), dubnium (Db, element 105), seaborgium (Sg, element 106), bohrium (Bh, element 107), hassium (Hs, element 108), copernicium (Cn, element 112), and element 114 is discussed from an experimental point of view. Recent results are emphasized and compared with empirical extrapolations and with fully-relativistic theoretical calculations, especially also under the aspect of the architecture of the Periodic Table. (orig.)

Superheavy Elements Challenge Experimental and Theoretical Chemistry

CERN Document Server

Zvára, I

2003-01-01

When reflecting on the story of superheavy elements, the an experimenter, acknowledges the role, which the predictions of nuclear and chemical theories have played in ongoing studies. Today, the problems of major interest for experimental chemistry are the studies of elements 112 and 114 including their chemical identification. Advanced quantum chemistry calculations of atoms and molecules would be of much help. First experiments with element 112 evidence that the metal is much more volatile and inert than mercury.

The Superheavy Elements and Anti-Gravity

Science.gov (United States)

Anastasovski, Petar K.

2004-02-01

The essence of any propulsion concept is to overcome gravity. Anti-gravity is a natural means to achieve this. Thus, the technology to pursue anti-gravity, by using superheavy elements, may provide a new propulsion paradigm. The theory of superluminal relativity provides a hypothesis for existence of elements with atomic number up to Z = 145, some of which may possess anti-gravity properties. Analysis results show that curved space-time exists demonstrating both gravitic and anti-gravitic properties not only around nuclei but inside the nuclei as well. Two groups of elements (Z Hawking, in honour of Stephen W. Hawking.

Synthesis and investigation of superheavy elements - perspectives with radioactive beams

International Nuclear Information System (INIS)

Muenzenberg, G.

1997-09-01

The perspectives for the investigation of heavy and superheavy elements with intense beams of radioactive nuclei available from the new generation of secondary beam facilities in combination with modern experimental developments are the subject of this paper. The nuclear properties of the recently discovered shell nuclei centered at Z=108 and N=164 and predictions on the location of the superheavy region with improved theoretical models will be discussed. (orig.)

Frontiers of heavy-ion physics and superheavy elements

International Nuclear Information System (INIS)

Muenzenberg, G.

2003-01-01

This contribution will focus on three topics of GSI nuclear structure research: superheavy elements, direct mass measurements in the storage ring, and studies of fission in reversed kinematics. The GSI project for a new synchrotron facility will be outlined

Search for superheavy elements in monazite from Beach sands of South India

International Nuclear Information System (INIS)

Kapoor, S.S.; Ramamurthy, V.S.; Lal, R.; Kataria, S.K.

1977-01-01

Monazite minerals obtained from beach of South India were examined for the presence of superheavy elements with photon-induced x-ray fluorescence method. The accumulated data of a number of runs each of several days duration do not show any convicing peaks above the background at the expected locations for superheavy elements which are above the present sensitivity of detection of about 10 ppm by weight for element 126. However, some intriguing features pertaining to structures in the x-ray spectra around 27 kev were observed, which are of interest for further investigations. (author)

Study of Superheavy Elements

International Nuclear Information System (INIS)

Hofmann, Sigurd

2007-01-01

The nuclear shell model predicts that the next doubly magic shell-closure beyond 208 Pb is at a proton number Z = 114, 120, or 126 and at a neutron number N = 172 or 184. The outstanding aim of experimental investigations is the exploration of this region of spherical 'SuperHeavy Elements' (SHEs). Experimental methods are described, which allowed for the identification of elements produced on a cross-section level of about 1 pb. The decay data reveal that for the heaviest elements, the dominant decay mode is alpha emission, not fission. Decay properties as well as reaction cross-sections are compared with results of theoretical investigations. Finally, plans are presented for the further development of the experimental set-up and the application of new techniques, as for instance the precise mass measurement of the produced nuclei using ion traps. At increased sensitivity, the detailed exploration of the region of spherical SHEs will start, after first steps on the island were made in recent years. (Author)

Silicon vertex detector for superheavy elements identification

Directory of Open Access Journals (Sweden)

Bednarek A.

2012-07-01

Full Text Available Silicon vertex detector for superheavy elements (SHE identification has been proposed. It will be constructed using very thin silicon detectors about 5 μm thickness. Results of test of 7.3 μm four inch silicon strip detector (SSD with fission fragments and α particles emitted by 252Cf source are presented

On superheavy elements, what did we achieve

International Nuclear Information System (INIS)

Armbruster, P.

1986-03-01

The properties of the heaviest isotopes are discussed using recent results on α-energies, halflives, and branchings between the different decay modes. From the data on α- and spontaneous fission halflives and absolute masses, fission barriers and barrier widths are deduced. Shell corrections of the heaviest nuclei are obtained and compared to recent calculations. The concept of superheavy elements is examined, and it is shown that the heaviest isotopes known must be classified 'superheavy'. The production cross sections are summarized and within the extra-push model the reduced fusion probabilities in the entrance channel are discussed. It is shown that besides nuclear structure effects in the collision partners are of importance. It is concluded that targets around 208 Pb give a double gain, on the one hand from the fact that fusion is relatively cold (1n- and 2n-channels), and on the other hand that the extra-push limitation is setting in later than the model predicts. The possibilities to make still heavier elements are restricted not by their groundstate instability but by the principal limitations of their production. (orig.)

Electronic structure and properties of superheavy elements

International Nuclear Information System (INIS)

Pershina, V.

2015-01-01

Spectacular developments in the relativistic quantum theory and computational algorithms in the last few decades allowed for accurate calculations of properties of the superheavy elements (SHE) and their compounds. Often conducted in a close link to the experimental research, these investigations helped predict and interpret an outcome of sophisticated and expensive experiments with single atoms. Most of the works, particularly those related to the experimental studies, are overviewed in this publication. The role of relativistic effects being of paramount importance for the heaviest elements is elucidated.

Upper Limit of the Periodic Table and Synthesis of Superheavy Elements

Directory of Open Access Journals (Sweden)

Khazan A.

2007-04-01

Full Text Available For the first time, using the heaviest possible element, the diagram for known nuclides and stable isotopes is constructed. The direction of search of superheavy elements is indicated. The Periodic Table with an eighth period is tabulated.

From heavy nuclei to super-heavy nuclei; Des noyaux lourds aux super-lourds

Energy Technology Data Exchange (ETDEWEB)

Theisen, Ch

2003-01-01

The existence of super-heavy nuclei has been predicted nearly fifty years ago. Due to the strong coulomb repulsion, the stabilisation of these nuclei is possible only through shell effects. The reasons for this fragile stability, as well as the theoretical predictions concerning the position of the island of stability are presented in the first part of this lecture. In the second part, experiments and experimental techniques which have been used to synthesize or search for super-heavy elements are described. Spectroscopic studies performed in very heavy elements are presented in the following section. We close this lecture with techniques that are currently being developed in order to reach the superheavy island and to study the structure of very-heavy nuclei. (author)

Chemistry of the superheavy elements.

Science.gov (United States)

Schädel, Matthias

2015-03-13

The quest for superheavy elements (SHEs) is driven by the desire to find and explore one of the extreme limits of existence of matter. These elements exist solely due to their nuclear shell stabilization. All 15 presently 'known' SHEs (11 are officially 'discovered' and named) up to element 118 are short-lived and are man-made atom-at-a-time in heavy ion induced nuclear reactions. They are identical to the transactinide elements located in the seventh period of the periodic table beginning with rutherfordium (element 104), dubnium (element 105) and seaborgium (element 106) in groups 4, 5 and 6, respectively. Their chemical properties are often surprising and unexpected from simple extrapolations. After hassium (element 108), chemistry has now reached copernicium (element 112) and flerovium (element 114). For the later ones, the focus is on questions of their metallic or possibly noble gas-like character originating from interplay of most pronounced relativistic effects and electron-shell effects. SHEs provide unique opportunities to get insights into the influence of strong relativistic effects on the atomic electrons and to probe 'relativistically' influenced chemical properties and the architecture of the periodic table at its farthest reach. In addition, they establish a test bench to challenge the validity and predictive power of modern fully relativistic quantum chemical models. © 2015 The Author(s) Published by the Royal Society. All rights reserved.

Global and local approaches to population analysis: Bonding patterns in superheavy element compounds

Science.gov (United States)

Oleynichenko, Alexander; Zaitsevskii, Andréi; Romanov, Stepan; Skripnikov, Leonid V.; Titov, Anatoly V.

2018-03-01

Relativistic effective atomic configurations of superheavy elements Cn, Nh and Fl and their lighter homologues (Hg, Tl and Pb) in their simple compounds with fluorine and oxygen are determined using the analysis of local properties of molecular Kohn-Sham density matrices in the vicinity of heavy nuclei. The difference in populations of atomic spinors with the same orbital angular momentum and different total angular momenta is demonstrated to be essential for understanding the peculiarities of chemical bonding in superheavy element compounds. The results are fully compatible with those obtained by the relativistic iterative version of conventional projection analysis of global density matrices.

α-decay chains and cluster-decays of superheavy 269-27110 nuclei

International Nuclear Information System (INIS)

Sushil Kumar; Rajesh Kumar; Balasubramaniam, M.; Gupta, Raj K.

2001-01-01

Due to the availability of radioactive nuclear beams (RNB) and the advancement in accelerator technology, it is now possible to synthesize very heavy elements (Z> 100), called superheavy elements. It is a well established fact that these superheavy elements, due to their shorter lifetime, decay via successive alpha emissions and at a later stage undergo spontaneous fission. Several such decay chains are now observed. An attempt is made to fit all such known decay chains and the results of the three observed α-decay chains of Z=110 ( 269-271 10) nuclei are presented. The model used is the preformed cluster model (PCM). Also, an attempt is made for the first time to find the possibility of any branching to heavy-cluster emissions in these chains

Mean-field models and superheavy elements

International Nuclear Information System (INIS)

Reinhard, P.G.; Bender, M.; Maruhn, J.A.; Frankfurt Univ.

2001-03-01

We discuss the performance of two widely used nuclear mean-field models, the relativistic mean-field theory (RMF) and the non-relativistic Skyrme-Hartree-Fock approach (SHF), with particular emphasis on the description of superheavy elements (SHE). We provide a short introduction to the SHF and RMF, the relations between these two approaches and the relations to other nuclear structure models, briefly review the basic properties with respect to normal nuclear observables, and finally present and discuss recent results on the binding properties of SHE computed with a broad selection of SHF and RMF parametrisations. (orig.)

The Superheavy Elements and Anti-Gravity

International Nuclear Information System (INIS)

Anastasovski, Petar K.

2004-01-01

The essence of any propulsion concept is to overcome gravity. Anti-gravity is a natural means to achieve this. Thus, the technology to pursue anti-gravity, by using superheavy elements, may provide a new propulsion paradigm. The theory of superluminal relativity provides a hypothesis for existence of elements with atomic number up to Z = 145, some of which may possess anti-gravity properties. Analysis results show that curved space-time exists demonstrating both gravitic and anti-gravitic properties not only around nuclei but inside the nuclei as well. Two groups of elements (Z < 64 and 63 < Z <145) exist that demonstrate these capabilities. The nuclei of the first group of elements have the masses with only the property of gravity. The nuclei of the elements of the second group have the masses with both properties: gravity and anti-gravity in two different ranges of curved space-time around the nuclei.. The hypothetical element with Z = 145 is the unique among all elements whose nucleus has only anti-gravity property. It is proposed that this element be named Hawking, in honour of Stephen W. Hawking

Search for superheavy elements in the reaction 238U+9.6 MeV/N 63Cu,65Cu

International Nuclear Information System (INIS)

Esterlund, R.A.; Molzahn, D.; Brandt, R.; Patzelt, P.; Vater, P.; Boos, A.H.

1976-01-01

According to calculations of NIX and others, the formation of superheavy elements might occur in heavy-ion reaction systems such as the one under investigation in the present work i.e., 238 U + 63 Cu and 65 Cu at 9.6 MeV/nucleon. Since previous experiments have indicated that upper limits to the production cross-section for superheavy elements are extremely low, two rather long irradiations of 27 hrs and 42 hrs, respectively, have been carried out at the University of Manchester LINAC. The first run has already been reported on in the literature. In the case of the second run, after chemical separation into HgS, CdS, and La(OH) 3 fractions, the samples were assayed simultaneously and continuously over a period of 6 months for alpha- and spontaneous-fission activity, using Si surface-barrier detector. Each sample was at the same time mounted on mica, for the purpose of scanning for fission tracks at a later date. No indications from the data have so far been found that superheavy elements were produced. Possible reasons for the failure to detect superheavy elements in this experiment are: The half-life of any product is either too short (a few hours) or too long (a few years); the chemical properties of the superheavy elements are very different from those predicted; the position of the superheavy island is not where it is commonly assumed to be and may, for example, be at Z>=114 and N>=184, as predicted by ROUBEN et al. (T.G.)

Relativistic quantum chemistry of the superheavy elements. Closed-shell element 114 as a case study

International Nuclear Information System (INIS)

Schwerdtfeger, Peter; Seth, Michael

2002-01-01

The chemistry of superheavy element 114 is reviewed. The ground state of element 114 is closed shell [112]7s 2 7p 1/2 2 and shows a distinct chemical inertness (low reactivity). This inertness makes it rather difficult to study the atom-at-a-time chemistry of 114 in the gas or liquid phase. (author)

Collisions of deformed nuclei and superheavy-element production

International Nuclear Information System (INIS)

Iwamoto, Akira; Moeller, P.; Univ. of Aizu, Fukushima; P. Moller Scientific Computing and Graphics, Inc., Los Alamos, NM; Los Alamos National Lab., NM; Nix, J.R.; Sagawa, Hiroyuki, Sagawa

1995-01-01

A detailed understanding of complete fusion cross sections in heavy-ion collisions requires a consideration of the effects of the deformation of the projectile and target. The aim here is to show that deformation and orientation of the colliding nuclei have a very significant effect on the fusion-barrier height and on the compactness of the touching configuration. To facilitate discussions of fusion configurations of deformed nuclei, the authors develop a classification scheme and introduce a notation convention for these configurations. They discuss particular deformations and orientations that lead to compact touching configurations and to fusion-barrier heights that correspond to fairly low excitation energies of the compound systems. Such configurations should be the most favorable for producing superheavy elements. They analyze a few projectile-target combinations whose deformations allow favorable entrance-channel configurations and whose proton and neutron numbers lead to compound systems in a part of the superheavy region where a half-lives are calculated to be observable, that is, longer than 1 micros

Synthesis and properties of superheavy elements

CERN Document Server

Hofmann, S

2003-01-01

The nuclear shell model predicts that the next doubly magic shell-closure beyond sup 2 sup 0 sup 8 Pb is at a proton number Z = 114, 120, or 126 and at a neutron number N = 172 or 184. The outstanding of experimental investigations is the exploration of this region of spherical 'SuperHeavy Elements' (SHEs). Experimental methods are described which allowed for the identification of elements 107 to 112 in studies of cold fusion reactions based on lead and bismuth targets. Also presented are data which were obtained on the synthesis of elements 112, 114, and 116 in investigation of hot fusion reactions using actinide targets. The decay data reveal that for the heaviest elements, the dominant decay mode is alpha emission, not fission. Decay properties as well as reaction cross- sections are compared with the results of theoretical studies. Finally, plans are presented for the further development of the experimental set-up and the application of new techniques. At a higher sensitivity, the exploration of the regio...

Experimental search for superheavy elements

International Nuclear Information System (INIS)

Wieloch, A.

2008-12-01

This work reports on the experimental search for superheavy elements (SHE). Two types of approaches for SHE production are studied i.e. '' cold '' fusion mechanism and massive transfer mechanism. First mechanism was studied in normal and inverse kinematics, by using Wien filter at the GANIL facility. The production of SHE elements with Z 106 and 108 is reported while negative results on the synthesis of SHE elements with Z 114 and 118 was received. The other approach i.e. reactions induced by heavy ion projectiles (e.g. 172 Yb, 197 Au) on fissile target nuclei (e.g. 238 U, 232 Th) at near Coulomb barrier incident energies was studied by using superconducting solenoid installed Texas A(and)M University. Preliminary results for the reaction 197 Au(7.5 MeV/u) - 232 Th are presented where three cases of the possible candidates for SHE elements were found. A dedicated detection setup for such studies is discussed and the detailed data analysis is presented. Detection of alpha and spontaneous fission radioactive decays is used to unambiguously identify the atomic number of SHE. Special statistical analysis for a very low detected number of α decays is applied to check consistency of the αradioactive chains. (author)

Review of even element super-heavy nuclei and search for element 120

Energy Technology Data Exchange (ETDEWEB)

Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Goethe-Universitaet Frankfurt, Institut fuer Physik, Frankfurt (Germany); Heinz, S.; Mann, R.; Maurer, J.; Barth, W.; Burkhard, H.G.; Dahl, L.; Kindler, B.; Kojouharov, I.; Lang, R.; Lommel, B.; Runke, J.; Scheidenberger, C.; Schoett, H.J.; Tinschert, K. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Muenzenberg, G. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Manipal University, Manipal Centre for Natural Sciences, Manipal, Karnataka (India); Antalic, S.; Saro, S. [Comenius University, Department of Nuclear Physics and Biophysics, Bratislava (Slovakia); Eberhardt, K.; Thoerle-Pospiech, P.; Trautmann, N. [Johannes Gutenberg-Universitaet Mainz, Mainz (Germany); Grzywacz, R. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); University of Tennessee, Knoxville, TN (United States); Hamilton, J.H. [Vanderbuilt University, Department of Physics and Astronomy, Nashville, TN (United States); Henderson, R.A.; Kenneally, J.M.; Moody, K.J.; Shaughnessy, D.A.; Stoyer, M.A. [Lawrence Livermore National Laboratory, Livermore, CA (United States); Miernik, K. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); University of Warsaw, Warsaw (Poland); Miller, D. [University of Tennessee, Knoxville, TN (United States); Morita, K. [RIKEN Nishina Center for Accelerator-Based Science, Wako, Saitama (Japan); Nishio, K. [Japan Atomic Energy Agency, Tokai, Ibaraki (Japan); Popeko, A.G.; Yeremin, A.V. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Roberto, J.B.; Rykaczewski, K.P. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Uusitalo, J. [University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland)

2016-06-15

The reaction {sup 54}Cr + {sup 248}Cm was investigated at the velocity filter SHIP at GSI, Darmstadt, with the intention to study production and decay properties of isotopes of element 120. Three correlated signals were measured, which occurred within a period of 279ms. The heights of the signals correspond with the expectations for a decay sequence starting with an isotope of element 120. However, a complete decay chain cannot be established, since a signal from the implantation of the evaporation residue cannot be identified unambiguously. Measured properties of the event chain are discussed in detail. The result is compared with theoretical predictions. Previously measured decay properties of even element super-heavy nuclei were compiled in order to find arguments for an assignment from the systematics of experimental data. In the course of this review, a few tentatively assigned data could be corrected. New interpretations are given for results which could not be assigned definitely in previous studies. The discussion revealed that the cross-section for production of element 120 could be high enough so that a successful experiment seems possible with presently available techniques. However, a continuation of the experiment at SHIP for a necessary confirmation of the results obtained in a relatively short irradiation of five weeks is not possible at GSI presently. Therefore, we decided to publish the results of the measurement and of the review as they exist now. In the summary and outlook section we also present concepts for the continuation of research in the field of super-heavy nuclei. (orig.)

On the Production of Superheavy Elements

CERN Document Server

Armbruster, P

2003-01-01

Since the discovery of Deformed Superheavy Nuclei (1983–85) a bridge connects the island of SHE to known isotopes of lighter elements. What we know experimentally and theoretically on the nuclear structure of SHE is reported in a first section. The making of the elements, with an analysis of production cross sections, and the macroscopic limitation to Z=112+ is presented in a second section. The break-down of fusion cross sections in the ‘Coulomb Falls’ within a range of about 10 elements is introduced as the universal limiting phenomenon. How the nuclear structure of the collision partners modifies the on-set of this limitation is presented in Section 3. Reactions induced by deformed nuclei are pushed by side collisions to higher excitation energies (4n- and 5n-channels), whereas reactions driven by the cluster-like, closed-shell nuclei, 208126Pb and 13882Ba, are kept at low excitation energies (1n- and 2n-channels). The on-set of production limitation for deformed collision partners is moved to smalle...

Superheavy Elements: Theoretical Expectations and Related Fundamental Issues

International Nuclear Information System (INIS)

Greiner, W.

2008-01-01

I discuss the theory for superheavy elements, based on the Two Center Shell Model. Potential energy surfaces, cold valleys, cold fusion, quasi fusion and other processes will be discussed. The experimental results from GSI, Dubna and Japan are presented. Finally, utilizing the theory of mass-exchange in dynamical encounters by Zagrebaev and myself, I will outline the possibility of long time delays of giant molecular/atomic systems (e.g. U + U, U + Cm, etc) and its relevance for observing the supercritical decay of the QED-vacuum

Coprecipitation experiment with Sm hydroxide using a multitracer produced by nuclear spallation reaction: A tool for chemical studies with superheavy elements

International Nuclear Information System (INIS)

Kasamatsu, Yoshitaka; Yokokita, Takuya; Toyomura, Keigo; Shigekawa, Yudai; Haba, Hiromitsu; Kanaya, Jumpei; Huang, Minghui; Ezaki, Yutaka; Yoshimura, Takashi; Morita, Kosuke; Shinohara, Atsushi

2016-01-01

To establish a new methodology for superheavy element chemistry, the coprecipitation behaviors of 34 elements with samarium hydroxide were investigated using multitracer produced by a spallation of Ta. The chemical reactions were rapidly equilibrated within 10 s for many elements. In addition, these elements exhibited individual coprecipitation behaviors, and the behaviors were qualitatively related to their hydroxide precipitation behaviors. It was demonstrated that the ammine and hydroxide complex formations of superheavy elements could be investigated using the established method. - Highlights: • We established a new methodology for superheavy element (SHE) chemistry. • Coprecipitation behaviors of 34 elements with Sm hydroxide could be simultaneously investigated by using multitracer. • The complex formations were investigated from the coprecipitation behaviors. • The established method will lead to the study on various precipitates of SHEs.

Theoretical Predictions of Cross-Sections of the Super-Heavy Elements

Science.gov (United States)

Bouriquet, B.; Kosenko, G.; Abe, Y.

The evaluation of the residue cross-sections of reactionssynthesising superheavy elements has been achieved by the combination of the two-step model for fusion and the evaporation code (KEWPIE) for survival probability. The theoretical scheme of those calculations is presented, and some encouraging results are given, together with some difficulties. With this approach, the measured excitation functions of the 1n reactions producing elements with Z=108, 110, 111 and 112 are well reproduced. Thus, the model has been used to predict the cross-sections of the reactions leading to the formation of the elements with Z=113 and Z=114.

Theoretical predictions of cross-sections of the super-heavy elements

International Nuclear Information System (INIS)

Bouriquet, B.; Abe, Y.; Kosenko, G.

2004-01-01

The evaluation of the residue cross-sections of reactions synthesising superheavy elements has been achieved by the combination of the two-step model for fusion and the evaporation code (KEWPIE) for survival probability. The theoretical scheme of those calculations is presented, and some encouraging results are given, together with some difficulties. With this approach, the measured excitation functions of the 1n reactions producing elements with Z = 108, 110, 111 and 112 are well reproduced. Thus, the model has been used to predict the cross-sections of the reactions leading to the formation of the elements with Z = 113 and Z = 114. (author)

Are there superheavy atomic nuclei

International Nuclear Information System (INIS)

Herrmann, G.

1982-04-01

The author presents a populary introduction to the formation of nuclei with special regards to superheavy nuclei. After a general description of the methods of physics the atomic hypothesis is considered. Thereafter the structure of the nucleus is discussed, and the different isotopes are considered. Then radioactivity is described as an element transmutation. Thereafter the thermonuclear reactions in the sun are considered. Then the synthesis of elements using heavy ion reactions is described. In this connection the transuranium elements and the superheavy elements are considered. (orig./HSI) [de

Nuclear treasure island [superheavy nuclei

CERN Document Server

CERN. Geneva

1999-01-01

Summary form only given. Soon after the experiments at Dubna, which synthesized element 114 and made the first footprints on the beach of the "island of nuclear stability", two new superheavy elements have been discovered at the Lawrence Berkeley National Laboratory. Element 118 and its immediate decay product, element 116, were manufactured at Berkeley's 88 inch cyclotron by fusing targets of lead-208 with an intense beam of 449 MeV krypton-86 ions. Although both new nuclei almost instantly decay into lighter ones, the decay sequence is consistent with theories that have long predicted the island of stability for nuclei with approximately 114 protons and 184 neutrons. Theorist Robert Smolanczuk, visiting from the Soltan Institute for Nuclear Studies in Poland, had calculated that this reaction should have particularly favourable production rates. Now that this route has been signposted, similar reactions could be possible: new elements and isotopes, tests of nuclear stability and mass models, and a new under...

Mendeleev's principle against Einstein's relativity: news from the chemistry of superheavy elements

Energy Technology Data Exchange (ETDEWEB)

Gaeggeler, Heinz W [Department of Chemistry and Biochemistry, University of Bern, Bern (Switzerland)

2009-12-31

The review briefly considers the problems of synthesis and chemical identification of superheavy elements. The specific features of their properties are determined by the relativistic effects. The synthesis and chemical investigations into bohrium and element 112 are discussed as examples.

Validation of new superheavy elements and IUPAC-IUPAP joint working group

International Nuclear Information System (INIS)

Jarlskog, Cecilia

2016-01-01

The great chemist Glenn Seaborg has written a delightful little book “Man-made Transuranium Elements”, published in 1963, in which he points out that: “The former basic criterion for the discovery of a new element – namely, chemical identification and separation from all previously-known elements – had to be changed in the case of lawrencium (element 103). This also may be true for elements beyond lawrencium.” Indeed this is what has happened. The elements with Z ≥ 103 are produced in nuclear reactions and are detected by counters. The detectors have undergone substantial refinement. For example one uses multiwire proportional chambers [for which George Charpak received the 1992 Nobel Prize in Physics] as well as solid state micro-strip detectors. In spite of this remarkable shift from chemistry to physics, the managerial staff of the International Union of Pure and Applied Chemistry (IUPAC) does not seem to be aware of what has been going on. The validation of superheavy elements should be done by physicists as the chemists lack the relevant competence as I will discuss here below. This article is about a collaboration between International Union of Pure and Applied Chemistry (IUPAC) and its sister organization International Union of Pure and Applied Physics (IUPAP), to deal with discovery of superheavy elements beyond Z = 112. I spent a great deal of time on this issue. In my opinion, the collaboration turned out to be a failure. For the sake of science, which should be our most important concern (and not politics), the rules for the future collaborations, if any, should be accurately defined and respected. The validation of new elements should be done by people who have the relevant competence – the physicists.

What can we learn from the fission time of the super-heavy elements?

OpenAIRE

Boilley, D.; Marchix, A.; Wilgenbus, D.; Lallouet, Y.; Gimbert, F.; Abe, Y.

2007-01-01

International audience; Recent experiments performed at GANIL with a crystal blocking technique have shown direct evidences of long fission times in the Super-Heavy Elements (SHE) region. Aimed to localize the SHE island of stability, can these experiments give access to the fission barrier and then to the shell-correction energy? In this paper, we calculate the fission time of heavy elements by using a new code, KEWPIE2, devoted to the study of the SHE.We also investigate the effect of poten...

Search for long-lived superheavy elements in the reaction system 238U + 9.6-MeV/nucleon 63/sub,/65Cu

International Nuclear Information System (INIS)

Esterlund, R.A.; Molzahn, D.; Brandt, R.; Patzelt, P.; Vater, P.; Boos, A.H.; Chandratillake, M.R.; Grant, I.S.; Hemingway, J.D.; Newton, G.W.A.

1977-01-01

A thick 238 U target has been bombarded with 63 /sub,/ 65 Cu ions at an incident beam energy of 9.6 MeV/nucleon. After radiochemical separations into CdS, HgS, and La-oxalate fractions, a search for evidence of the production of superheavy elements was undertaken using Si surface-barrier detectors and mica foils simultaneously for detection of spontaneous-fission events and high-energy α emission. No evidence for the presence of superheavy elements in the samples was found. Upper limits for production cross sections for superheavy elements in each of the three chemical samples, assuming an arbitrary half-life of 100 days and a target thickness equal to the entire reaction range of the incident ions from initial energy to the reaction barrier, are as follows: (a) CdS (Z = 108--115): 1 x 10 -34 cm 2 ; (b) HgS (Z = 112): 6 x 10 -35 cm 2 ; (c) La-oxalate ( 254 Cf): 8 x 10 -35 cm 2

Dissipative dynamics of the synthesis of superheavy elements

Energy Technology Data Exchange (ETDEWEB)

Wada, Takahiro; Aritomo, Y.; Tokuda, T.; Okazaki, K.; Ohta, M. [Konan Univ., Kobe (Japan). Dept. of Physics; Abe, Y.

1997-07-01

Fusion-fission process in heavy systems are analyzed by Smoluchowski equation taking into account the temperature dependent shell correction energy. The evaporation residue cross sections of superheavy elements have been shown to have an optimum value at a certain temperature, due to the balance between the diffusibility for fusion at high temperature and the restoration of the shell correction energy against fission at low temperature. The isotope dependence of the evaporation residue cross section is found to be very strong. Neutron rich compound system with small neutron separation energy is favorable for larger cross section because of the quick restoration of the shell correction energy. The Z-dependence is discussed for the formation of the compound nuclei with Z=102 to Z=114. (author)

Barium isotopes in Allende meteorite - Evidence against an extinct superheavy element

Science.gov (United States)

Lewis, R. S.; Anders, E.; Shimamura, T.; Lugmair, G. W.

1983-01-01

Carbon and chromite fractions from the Allende meteorite that contain isotopically anomalous xenon-131 to xenon-136 (carbonaceous chondrite fission or CCF xenon) at up to 5 x 10 to the 11th atoms per gram show no detectable isotopic anomalies in barium-130 to barium-138. This rules out the possibility that the CCF xenon was formed by in situ fission of an extinct superheavy element. Apparently the CCF xenon and its carbonaceous carrier are relics from stellar nucleosynthesis.

On the way to unveiling the atomic structure of superheavy elements

International Nuclear Information System (INIS)

Laatiaoui, Mustapha

2016-01-01

Optical spectroscopy of the transfermium elements (atomic number Z > 100) is nowadays one of the most fascinating and simultaneously challenging tasks in atomic physics. On the one hand, key atomic and even nuclear ground-state properties may be obtained by studying the spectral lines of these heaviest elements. On the other hand, these elements have to be produced “online” by heavy-ion induced fusion-evaporation reactions yielding rates on the order of a few atoms per second at most, which renders their optical spectroscopy extremely difficult. Only recently, a first foray of laser spectroscopy into this heaviest element region was reported. Several atomic transitions in the element nobelium (Z = 102) were observed and characterized, using an ultra-sensitive and highly efficient resonance ionization technique. The findings confirm the predictions and additionally provide a benchmark for theoretical modelling. The work represents an important stepping stone towards experimental studies of the atomic structure of superheavy elements.

Status of the low-energy super-heavy element facility at RIKEN

Energy Technology Data Exchange (ETDEWEB)

Schury, P., E-mail: schury@riken.jp [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Wada, M.; Ito, Y. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Arai, F. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Institute of Physics, University of Tsukuba, Tsukuba City, Ibaraki (Japan); Kaji, D. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Kimura, S. [Institute of Physics, University of Tsukuba, Tsukuba City, Ibaraki (Japan); Morimoto, K.; Haba, H. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Jeong, S. [Institute of Particle and Nuclear Studies (IPNS), High Energy Accelerator Research Organization (KEK), Ibaraki 305-0801 (Japan); Koura, H. [Advanced Science Research Center, Japan Atomic Energy Agency, Ibaraki 319-1195 (Japan); Miyatake, H. [Institute of Particle and Nuclear Studies (IPNS), High Energy Accelerator Research Organization (KEK), Ibaraki 305-0801 (Japan); Morita, K.; Reponen, M. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Ozawa, A. [Institute of Physics, University of Tsukuba, Tsukuba City, Ibaraki (Japan); Sonoda, T.; Takamine, A. [RIKEN, Nishina Center for Accelerator Based Science, Wako City, Saitama (Japan); Wollnik, H. [Dept. Chemistry and BioChemistry, New Mexico State University, Las Cruces, NM (United States)

2016-06-01

In order to investigate nuclei produced via fusion–evaporation reactions, especially super-heavy elements (SHE), we have begun construction of a facility for conversion of fusion–evaporation residues (EVR) to low-energy beams. At the base of this facility is a small cryogenic gas cell utilizing a traveling wave RF-carpet, located directly following the gas-filled recoil ion separator GARIS-II, which will thermalize EVRs to convert them into ion beams amenable to ion trapping. We present here the results of initial studies of this small gas cell.

The transuranium elements: From neptunium and plutonium to element 112

International Nuclear Information System (INIS)

Hoffman, D.C.

1996-01-01

Beginning in the 1930's, both chemists and physicists became interested in synthesizing new artificial elements. The first transuranium element, Np, was synthesized in 1940. Over the past six decades, 20 transuranium elements have been produced. A review of the synthesis is given. The procedure of naming the heavy elements is also discussed. It appears feasible to produce elements 113 and 114. With the Berkeley Gas-filled Separator, it should be possible to reach the superheavy elements in the region of the spherical Z=114 shell, but with fewer neutrons than the N=184 spherical shell. 57 refs, 6 figs

The Transplutonium. The superheavy nuclei found in the micas of Madagascar and their interests

International Nuclear Information System (INIS)

Raoelina Andriambololona

1976-01-01

Since June 1976, evidence for the existence of superheavy elements is discussed about. After having recalled artificial elements with atomic numbers Z of wich go from Z=95 (Americium) to Z=107 (built in 1976), superheavy elements having Z greater than 110 are considered. They have been discovered by american searchers in giant halos seen in Madagascar micas. The samples have been recoked in the Fort-Dauphin region (Haut Mandrare). The corresponding numbers Z are 114, 115, 116, 124, 125, 125, 126, 127. It seems that the existence of Z=126 element should be accepted with a greater degree of confidence. But different experiences done by other groups seem to show the evidence of superheavy elements in micas looks weaker. Nevertheless, it is interesting to investigate the evidence or the non-evidence of those elements. We estimate the mass numbers A of those superheavy elements in the liquid drop model if we assume that they are stable versus β. The results thus obtained agree with the shell-model ones within 4 % approximation. We propose if the evidence of superheavies is confirmed to give the name of madagascarium to one of them (Z=126) by similitude with francium, lutetium, polonium, berkelium, americium, europium, ...Their evidence was first conjectured in Madagascar micas in 1976. Superheavy nuclei are to be distinguished from hypernuclei. [fr

Superheavy Element Synthesis and Nuclear Structure

International Nuclear Information System (INIS)

Ackermann, D.

2009-01-01

The search for the next closed proton and neutron shells beyond 2 08P b has yielded a number of exciting results in terms of the synthesis of new elements [1,2,3]. The superheavy elements (SHE), however, are a nuclear structure phenomenon. They owe their existence to the quantum mechanical origin of shell correction energies without which they would not be bound. In recent years the development of efficient experimental set-ups including separators and advanced particle and photon detection arrangements allowed for more and more detailed nuclear structure studies for nuclei at and beyond Z=100. A review of those recent achievements is given in ref. [4]. Among the most interesting features is the observation of K-isomeric states. Experimentally about 14 cases have been identified in the region of Z>96 as shown in Fig. 1. K-isomers or indications of their existence have been found for almost all even-Z elements in the region Z=100 to 110. We could recently establish and/or confirm such states in the even-even isotopes 2 52,254N o [5]. The heaviest nucleus where such a state was found is 2 70D s with Z=110 as we reported in 2001 [6]. Those nuclear structure studies lay out the grounds for a detailed understanding of these heavy and high-Z nuclear systems, and contribute at the same time valuable information to preparation of strategies to successfully continue the hunt for the localisation of the next spherical proton and neutron shells after 2 08P b. The recent activities for both SHE synthesis and nuclear structure investigations at GSI will be reported.(author)

Attempts in search for superheavy elements in nature II

International Nuclear Information System (INIS)

Langrock, E.-J.; Vater, P.; Brandt, R.; Langrock, G.; Schumer, F.; Schreck, P.

1999-01-01

The search for superheavy elements is continued. We chose minerals for long-time exposure in a sandwich arrangement (PAD [polyallyldiglycol carbonate] and mica). In a first step we investigated samples of manganese concretions from the Pacific Ocean, enriched samples from Salton Sea and a volatile by product - fraction of copper - shale (Kupferschiefer) from Mansfeld ('Theisenschlamm'). After an exposure time of 535 days or 326 days, respectively, and proper etching, the SSNTD's were scanned using an optical microscope. Tracks due to the fission fragments could be seen neither at the PAD nor at the mica surface. The most hopeful sample 'Theisenschlamm' gives about 1.2x10 6 tracks of α-particles at PAD. This can be explained by the uranium content. The exposure will be continued and other samples will be investigated, too

From transuranic to superheavy elements a story of dispute and creation

CERN Document Server

Kragh, Helge

2018-01-01

The story of superheavy elements  - those at the very end of the periodic table  - is not well known outside the community of heavy-ion physicists and nuclear chemists. But it is a most interesting story which deserves to be known also to historians, philosophers, and sociologists of science and indeed to the general public. This is what the present work aims at. It tells the story or rather parts of the story, of how physicists and chemists created elements heavier than uranium or searched for them in nature. And it does so with an emphasis on the frequent discovery and naming disputes concerning the synthesis of very heavy elements. Moreover, it calls attention to the criteria which scientists have adopted for what it means to have discovered a new element. In this branch of modern science it may be more appropriate to speak of creation instead of discovery. The work will be of interest to scientists as well as to scholars studying modern science from a meta-perspective.

Synthesis of superheavy elements: Uncertainty analysis to improve the predictive power of reaction models

OpenAIRE

Lu , H.; Boilley , D.; Abe , Y.; Shen , C.

2016-01-01

13 pages, 13 figures, submitted for publication in PRC; International audience; Background: Synthesis of super-heavy elements is performed by heavy-ion fusion-evaporation reactions. However , fusion is known to be hindered with respect to what can be observed with lighter ions. Thus some delicate ambiguities remain on the fusion mechanism that eventually lead to severe discrepancies in the calculated formation probabilities coming from different fusion models. Purpose: In the present work, we...

The cross sections of fusion-evaporation reactions: the most promising route to superheavy elements beyond Z=118

Directory of Open Access Journals (Sweden)

Jadambaa Khuyagbaatar

2017-01-01

Full Text Available The synthesis of superheavy elements beyond oganesson (Og, which has atomic number Z = 118, is currently one of the main topics in nuclear physics. An absence of sufficient amounts of target material with atomic numbers heavier than californium (Z = 98 forces the use of projectiles heavier than 48Ca (Z = 20, which has been successfully used for the discoveries of elements with Z = 114 - 118 in complete fusion reactions. Experimental cross sections of 48Ca with actinide targets behave very differently to “cold” and “hot” fusion-evaporation reactions, where doubly-magic lead and deformed actinides are used as targets, respectively. The known cross sections of these reactions have been analysed compared to calculated fission barriers. It has been suggested that observed discrepancies between the cross sections of 48Ca-induced and other fusionevaporation reactions originate from the shell structure of the compound nucleus, which lies in the island of the stability. Besides scarcely known data on other reactions involving heavier projectiles, the most promising projectile for the synthesis of the elements beyond Og seems to be 50Ti. However, detailed studies of 50Ti, 54Cr, 58Fe and 64Ni-induced reactions are necessary to be performed in order to fully understand the complexities of superheavy element formation.

The cross sections of fusion-evaporation reactions: the most promising route to superheavy elements beyond Z=118

Science.gov (United States)

Jadambaa, Khuyagbaatar

2017-11-01

The synthesis of superheavy elements beyond oganesson (Og), which has atomic number Z = 118, is currently one of the main topics in nuclear physics. An absence of sufficient amounts of target material with atomic numbers heavier than californium (Z = 98) forces the use of projectiles heavier than 48Ca (Z = 20), which has been successfully used for the discoveries of elements with Z = 114 - 118 in complete fusion reactions. Experimental cross sections of 48Ca with actinide targets behave very differently to "cold" and "hot" fusion-evaporation reactions, where doubly-magic lead and deformed actinides are used as targets, respectively. The known cross sections of these reactions have been analysed compared to calculated fission barriers. It has been suggested that observed discrepancies between the cross sections of 48Ca-induced and other fusionevaporation reactions originate from the shell structure of the compound nucleus, which lies in the island of the stability. Besides scarcely known data on other reactions involving heavier projectiles, the most promising projectile for the synthesis of the elements beyond Og seems to be 50Ti. However, detailed studies of 50Ti, 54Cr, 58Fe and 64Ni-induced reactions are necessary to be performed in order to fully understand the complexities of superheavy element formation.

Estimation of atomic masses of heavy and superheavy elements

Energy Technology Data Exchange (ETDEWEB)

Uno, Masahiro [Ministry of Education, Science and Culture, Tokyo (Japan)

1997-07-01

To estimate unknown atomic masses of heavy and superheavy elements, three kinds of formula: FRDM (finite range droplet model by Moeller et al.), TUYY (an empirical formula by Tachibana et al.) and our KUTY are explained. KUTY estimates the crude shell energies of spherical nucleus from sum of single-particle energies. Then, the refined shell energies in due consideration of paring and deformation are obtained by mixing with the functions of the crude shell energies. Experimental values of U and Fm isotopes were compared with estimation mass of KUTY and FRDM. In the field with experimental values of U isotopes, the value of KUTY and FRDM separated the same difference from the experimental value. The behavior of KUTY and FRDM for Fm isotopes were same as that of U, but ETFSI deviated a little from the experimental values. (S.Y.)

Superheavy-element fission tracks in iron meteorites, and reply by Bull, R.K

International Nuclear Information System (INIS)

Runcorn, S.K.

1980-01-01

Comment is made on the lack of superheavy element (SHE) fission tracks observed in silicates from the class IA Odessa iron meteorite by Bull (Nature; 282:393 (1979)). Two explanations are suggested. Firstly, a thermal history for Odessa can be constructed in which the meteorite reaches track retention temperatures only after a time corresponding to many half lives for the SHEs (taken to be approximately 100 Myr) has elapsed and secondly that the IA irons never took up many SHEs. These suggestions are discussed in a reply by Bull. (U.K.)

Relativistic pseudopotential model for superheavy elements: applications to chemistry of eka-Hg and eka-Pb

Energy Technology Data Exchange (ETDEWEB)

Zaitsevskii, Andrei V [Institute of Hydrogen Energetics and Plasma Technologies, Russian Research Centre ' Kurchatov Institute' (Russian Federation); Wuellen, C van [Technische Universitaet Kaiserslautern (Germany); Titov, A V [B P Konstantinov Petersburg Nuclear Physics Institute, Russian Academy of Sciences (Russian Federation)

2009-12-31

Relativistic pseudopotential approach to the electronic structure simulation of superheavy elements (SHE) compounds is presented. Advanced formulations of this approach leaving both valence and outer-core electronic shells for explicit treatment give rise to simple and efficient computational techniques ensuring highly accurate description of most chemical properties of SHE. At present, the errors due to the use of approximate methods for solving the correlation problem for a subsystem of valence electrons are much larger than those stemming from the pseudopotential approximation itself. Recent applications to the studies of the chemistry of elements 112 (eka-Hg) and 114 (eka-Pb) are reviewed; properties of these elements and their lighter homologues, Hg and Pb, are compared.

Theoretical description and predictions of the properties of superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Sobiczewski, A [Department of Theoretical Physics, Andrzej Soltan Institute for Nuclear Studies (Poland)

2009-12-31

Theoretical descriptions of superheavy atomic nuclei are shortly reviewed and illustrated by their results. Such properties of these nuclei as their shapes, masses, fission barriers, decay modes, decay energies, half-lives, are discussed. Special attention is given to the shell structure of the nuclei, due to which they exist. The role of the physical studies of the superheavy nuclei for the chemical research on the superheavy elements and, more generally, the relationship between these two kinds of investigation is underlined. This stresses the importance of close cooperation between physicists and chemists, experimentalists and theoreticians, in these studies.

Electronic structure theory of the superheavy elements

Energy Technology Data Exchange (ETDEWEB)

Eliav, Ephraim, E-mail: ephraim@tau.ac.il [School of Chemistry, Tel Aviv University, 6997801 Tel Aviv (Israel); Fritzsche, Stephan, E-mail: s.fritzsche@gsi.de [Helmholtz-Institut Jena, Fröbelstieg 3, D-07743 Jena (Germany); Theoretisch-Physikalisches Institut, Friedrich-Schiller-Universität Jena, D-07743 Jena (Germany); Kaldor, Uzi, E-mail: kaldor@tau.ac.il [School of Chemistry, Tel Aviv University, 6997801 Tel Aviv (Israel)

2015-12-15

High-accuracy calculations of atomic properties of the superheavy elements (SHE) up to element 122 are reviewed. The properties discussed include ionization potentials, electron affinities and excitation energies, which are associated with the spectroscopic and chemical behavior of these elements, and are therefore of considerable interest. Accurate predictions of these quantities require high-order inclusion of relativity and electron correlation, as well as large, converged basis sets. The Dirac–Coulomb–Breit Hamiltonian, which includes all terms up to second order in the fine-structure constant α, serves as the framework for the treatment; higher-order Lamb shift terms are considered in some selected cases. Electron correlation is treated by either the multiconfiguration self-consistent-field approach or by Fock-space coupled cluster theory. The latter is enhanced by the intermediate Hamiltonian scheme, allowing the use of larger model (P) spaces. The quality of the calculations is assessed by applying the same methods to lighter homologs of the SHEs and comparing with available experimental information. Very good agreement is obtained, within a few hundredths of an eV, and similar accuracy is expected for the SHEs. Many of the properties predicted for the SHEs differ significantly from what may be expected by straightforward extrapolation of lighter homologs, demonstrating that the structure and chemistry of SHEs are strongly affected by relativity. The major scientific challenge of the calculations is to find the electronic structure and basic atomic properties of the SHE and assign its proper place in the periodic table. Significant recent developments include joint experimental–computational studies of the excitation spectrum of Fm and the ionization energy of Lr, with excellent agreement of experiment and theory, auguring well for the future of research in the field.

Synthesis of superheavy elements by cold fusion

Energy Technology Data Exchange (ETDEWEB)

Hofmann, S [Gesellschaft fuer Schwerionenforschung (GSI), Helmholtzzentrum fuer Schwerionenforschung Gmbh (Germany)

2009-12-31

The nuclear shell model predicts that the next doubly magic shell-closure beyond {sup 208}Pb is at the proton number Z=114, 120, or 126 and at the neutron number N=172 or 184. The outstanding aim of experimental investigations is the exploration of this region of spherical 'Super Heavy Elements' (SHEs). Using cold fusion reactions which are based on lead and bismuth targets, the new elements from 107 to 112 were synthesized at GSI in Darmstadt, Germany. Some of these results were confirmed at RIKEN in Wako, Japan, where also a relatively neutron-deficient isotope of element 113 was synthesized. In hot fusion reactions of {sup 48}Ca projectiles with actinide targets, a more neutron-rich isotope of element 112 and the new elements from 113 to 116 and even 118 were produced at FLNR in Dubna, Russia. Recently, part of these hot fusion data, which represent the first identification of nuclei located on the predicted island of SHEs, were confirmed in two independent experiments. The decay data reveal that for the heaviest elements, the dominant decay mode is alpha emission rather than fission. The decay properties as well as reaction cross-sections are compared with results of theoretical studies.

Structure of exotic nuclei and superheavy elements in meson field theory

Energy Technology Data Exchange (ETDEWEB)

Linn, Khin Nyan

2008-07-15

In this work the nuclear structure of exotic nuclei and superheavy nuclei is studied in a relativistic framework. In the relativistic mean-field (RMF) approximation, the nucleons interact with each other through the exchange of various effective mesons (scalar, vector, isovector-vector). Ground state properties of exotic nuclei and superheavy nuclei are studied in the RMF theory with the three different parameter sets (ChiM,NL3,NL-Z2). Axial deformation of nuclei within two drip lines are performed with the parameter set (ChiM). The position of drip lines are investigated with three different parameter sets (ChiM,NL3,NL-Z2) and compared with the experimental drip line nuclei. In addition, the structure of hypernuclei are studied and for a certain isotope, hyperon halo nucleus is predicted. (orig.)

Structure of exotic nuclei and superheavy elements in meson field theory

International Nuclear Information System (INIS)

Linn, Khin Nyan

2008-07-01

In this work the nuclear structure of exotic nuclei and superheavy nuclei is studied in a relativistic framework. In the relativistic mean-field (RMF) approximation, the nucleons interact with each other through the exchange of various effective mesons (scalar, vector, isovector-vector). Ground state properties of exotic nuclei and superheavy nuclei are studied in the RMF theory with the three different parameter sets (ChiM,NL3,NL-Z2). Axial deformation of nuclei within two drip lines are performed with the parameter set (ChiM). The position of drip lines are investigated with three different parameter sets (ChiM,NL3,NL-Z2) and compared with the experimental drip line nuclei. In addition, the structure of hypernuclei are studied and for a certain isotope, hyperon halo nucleus is predicted. (orig.)

Exotic decay modes of odd-Z (105-119) superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Rajeswari, N.S. [Bharathiar University, Department of Physics, Coimbatore (India); Avinashilingam Institute for Home Science and Higher Education for Women - University, Department of Physics, Coimbatore (India); Balasubramaniam, M. [Bharathiar University, Department of Physics, Coimbatore (India)

2014-06-15

Half-lives of proton emission for proton emitters with Z = 51 to 83 are calculated, in the frame-work of unified fission model with the penetrability calculated using the WKB approximation. For all the ground and isomeric state of the proton, the deformation degree of freedom is included. Calculated half-lives are in good agreement with the experimental ones. Experimentally for a few isotopes, proton and alpha branches are reported. Hence we have calculated the half-lives of alpha decay for these elements. For parent nuclei {sup 157}Ta, {sup 166}Ir, {sup 167}Ir, {sup 176}Tl and {sup 177}Tl, the alpha decay mode is preferred over the proton emission. Further, the calculations are extended to find half-lives of superheavy element with odd proton number in the range Z = 105 to 119, for both proton, alpha and for a few cluster decays. Calculations on superheavy elements reveal that cluster radioactivity has half-lives comparable with proton emissions. It is found that proton emission is the primary competing decay mode with respect to alpha decay for superheavy elements. Among considered clusters, {sup 12}C, {sup 20}Ne and {sup 24}Mg are found to have lowest half-lives among other N = Z clusters and for a few clusters the half-lives are found to be comparable with that of proton emission. (orig.)

Systematical calculations on the ground state properties of heavy and superheavy nuclei

International Nuclear Information System (INIS)

Ren, Z.Z.; Center of Theoretical Nuclear Physics, Lanzhou; Mao, Y.C.; Zhi, Q.J.; Xu, C.; Dong, T.K.

2007-01-01

The synthesis of superheavy elements is now a hot topic in nuclear physics. Alpha-decay and spontaneous fission are two main decay modes in heavy and superheavy regions. Theoretical studies on alpha radioactivity and spontaneous fission can provide useful information for experiments. We investigate the alpha-decay and spontaneous fission of heavy and superheavy nuclei with different models. This includes the alpha-decay energies, alpha decay half-lives, and half-lives of spontaneous fission. The theoretical alpha-decay half-lives are in good agreement with experimental ones. The calculated half-lives of spontaneous fission are in reasonable agreement with present data. The properties of unknown nuclei are predicted. (author)

Fission barriers of superheavy nuclei

International Nuclear Information System (INIS)

Burvenich, T.

2001-01-01

Full text: Self consistent microscopic mean-field models are powerful tools for the description of nuclear structure phenomena in the region of known elements, where they have reached a good quality. Especially the Skyrme-Hartree-Fock (SHF) method and the Relativistic Mean-Field (RMF) model will be considered in the discussion of the properties of these models. When it comes to extrapolation to the region of superheavy elements, though there is agreement concerning the global trends, these model exhibit significant differences in their predictions concerning fission barrier heights and structures. (Author)

A novel approach to the island of stability of super-heavy elements search

Directory of Open Access Journals (Sweden)

Wieloch A.

2016-01-01

Full Text Available It is expected that the cross section for super-heavy nuclei production of Z > 118 is dropping into the region of tens of femto barns. This creates a serious limitation for the complete fusion technique that is used so far. Moreover, the available combinations of the neutron to proton ratio of stable projectiles and targets are quite limited and it can be difficult to reach the island of stability of super heavy elements using complete fusion reactions with stable projectiles. In this context, a new experimental investigation of mechanisms other than complete fusion of heavy nuclei and a novel experimental technique are invented for our search of super- and hyper-nuclei. This contribution is focused on that technique.

Hydration energies and specific influence of oxo complexes and high coordination numbers on the predicted chemistry of superheavy elements

International Nuclear Information System (INIS)

Jorgensen, C.K.; Penneman, R.A.

1975-01-01

On the basis of an analysis of the known ionization energies of gaseous ions and aqua ions of the 3d, 4f, and 6d transition groups and the radius effects, the chemistry of the superheavy elements is predicted. The formation of aqua ion and oxo complexes in the elements with Z below 121 is considered. It is probable that the series from 123 to 140 constitute a close analogy to the lanthanides with Th-like chemistry. Above Z = 140 the elements will probably displace a transition group behavior. A brief comment is made on the analytical aspects to be expected. (U.S.)

Isomeric States in the Second and Third Well of the Potential and Long-Lived Superheavy Element

International Nuclear Information System (INIS)

Marinov, A.; Gelberg, S.; Kolb, D.

1999-01-01

Recently, in a study of the 16 O + 197 Au and 28 Si + 181 Ta reactions near and below the Coulomb barrier, long-lived high spin isomeric states have been found by us in the second and third well of the potential-energy surfaces. Such isomeric states have very unusual physical properties. In addition to their very long lifetimes, much longer than of their corresponding ground states, they have very unusual decay properties. They may decay by 5 to 7 orders of magnitude enhanced alpha particles, in transitions from the second or third well of the potential in the parent nuclei to the respective well in the daughters, or by very retarded alpha particles, in transitions from the second well in the parent nucleus to normal states in the daughter, or from the third well in the parent to the second well in the daughter. They also may decay by long-lived proton activities, in transitions from the second well in the parent nucleus to the normal states in the daughter. Experimental evidences for all these new phenomena will be presented in the conference. The existence of long-lived isomeric states in the second and third well of the potential is very important when the production of superheavy elements is considered. Because of the very much reduced extra-push energy needed for their production, they may be produced much easier than the normal states, in reactions between very heavy nuclei. In particular, the discovery of the long-lived superheavy element with Z = 112 can consistently be understood

New approach to description of fusion-fission dynamics in super-heavy element formation

International Nuclear Information System (INIS)

Zagrebaev, V.I.

2002-01-01

A new mechanism of the fusion-fission process for a heavy nuclear system is proposed, which takes place in the (A 1 , A 2 ) space, where A 1 and A 2 are two nuclei, surrounded by a certain number of shared nucleons ΔA. The nuclei A 1 and A 2 gradually lose (or acquire) their individualities with increasing (or decreasing) a number of collectivized nucleons ΔA. The driving potential in the (A 1 , A 2 ) space is derived, which allows the calculation of both the probability of the compound nucleus formation and the mass distribution of fission and quasi-fission fragments in heavy ion fusion reactions. The cross sections of super-heavy element formation in the 'hot' and 'cold' fusion reactions have been calculated up to Z CN =118. (author)

Discovery of element 112

Energy Technology Data Exchange (ETDEWEB)

Hofmann, S. [GSI, Darmstadt (Germany)

1996-12-31

The new elements 110, 111, and 112 were synthesized and unambiguously identified in experiments at SHIP. Due to strong shell effects the dominant decay mode is not fission, but emission of alpha particles. Theoretical investigations predict that maximum shell effects should exist in nuclei near proton number 114 and neutron number 184. Measurements give hope that isotopes of element 114 close to the island of spherical Superheavy Elements could be produced by fusion reactions using {sup 118}Pb as target. systematic studies of the reaction cross-sections indicate that transfer of nucleons is the important process to initiate the fusion.

Stability and production of superheavy nuclei

International Nuclear Information System (INIS)

Moeller, P.; Los Alamos National Lab., NM; Nix, J.R.

1997-01-01

Beyond uranium heavy elements rapidly become increasingly unstable with respect to spontaneous fission as the proton number Z increases, because of the disruptive effect of the long-range Coulomb force. However, in the region just beyond Z = 100 magic proton and neutron numbers and the associated shell structure enhances nuclear stability sufficient to allow observation of additional nuclei. Some thirty years ago it was speculated that an island of spherical, relatively stable superheavy nuclei would exist near the next doubly magic proton-neutron combination beyond 208 Pb, that is, at proton number Z 114 and neutron number N = 184. Theory and experiment now show that there also exists a rock of stability in the vicinity of Z = 110 and N = 162 between the actinide region, which previously was the end of the peninsula of known elements, and the predicted island of spherical superheavy nuclei slightly southwest of the magic numbers Z = 114 and N = 184. The authors review here the stability properties of the heavy region of nuclei. Just as the decay properties of nuclei in the heavy region depend strongly on shell structure, this structure also dramatically affects the fusion entrance channel. The six most recently discovered new elements were all formed in cold-fusion reactions. They discuss here the effect of the doubly magic structure of the target in cold-fusion reactions on the fusion barrier and on dissipation

First prompt in-beam γ-ray spectroscopy of a superheavy element: the 256Rf

International Nuclear Information System (INIS)

Rubert, J; Dorvaux, O; Gall, B J P; Asfari, Z; Piot, J; Greenlees, P T; Grahn, T; Herzan, A; Jakobsson, U; Jones, P; Julin, R; Juutinen, S; Andersson, L L; Cox, D M; Herzberg, R-D; Asai, M; Dechery, F; Hauschild, K; Henning, G; Heßberger, F P

2013-01-01

Using state-of-the-art γ-ray spectroscopic techniques, the first rotational band of a superheavy element, extending up to a spin of 20 h, was discovered in the nucleus 256 Rf. To perform such an experiment at the limits of the present instrumentation, several developments were needed. The most important of these developments was of an intense isotopically enriched 50 Ti beam using the MIVOC method. The experimental set-up and subsequent analysis allowed the 256 Rf ground-state band to be revealed. The rotational properties of the band are discussed and compared with neighboring transfermium nuclei through the study of their moments of inertia. These data suggest that there is no evidence of a significant deformed shell gap at Z = 104.

State of art in experimental studies and theory of superheavy elements

International Nuclear Information System (INIS)

Zvara, I.

2002-01-01

Recent years have seen remarkable progress in synthesizing new, superheavy' elements (SHE). Researchers at Dubna reached the slopes of the expected 'island of stability' (around Z = 114 and N = 184) in a 'sea' of nuclides with very short partial half-lives against spontaneous fission and/or alpha decay. In long bombardments (weeks to months) of isotopes of U, Pu and Cm by very intense (3x10 12 s -1 ) beams of 48 Ca projectiles, they have discovered mostly alpha active isotopes of previously unknown elements 116 and 114, as well as of element 112, all with unusually long half-lives - up to minutes. Only physical methods have been used for isolation and identification of the produced new nuclei. These findings give an impetus to chemical studies. Feasibility of experiments critically depends on half-lives and production cross section. Lifetimes of the order of a second or more are necessary for some gas phase chemistry studies, but at least some 10 seconds for solution chemistry. The production rates of observable atoms might be higher in chemical studies, because chemists can make use of thicker targets, and achieve higher (chemical) yield and detection efficiency than in physical experiments. Work on chemical identification of the 3-min 283 112 is in progress at Dubna and planned in other laboratories. Being a homologue of Hg, element 112 must be even more volatile metal. Thanks to this, hopefully, its single atoms, will be easily separated from interfering activities simultaneously produced in the bombardment. Quantum (theoretical) chemistry studies aim at solving the problem of 'relativistic effects' in chemical properties of SHE; such effects increase with higher Z's. As the available calculational resources fast and steadily grow (unlike the beam time available at accelerators) one can hope that quantum chemists will once be able to advise the experimenters which kind of studies to do to obtain most important and interesting results. This is not yet possible

Superheavy Elements and Beyond: - Supercritical Coulomb Field and Giant Quasiatoms

International Nuclear Information System (INIS)

Greiner, Walter

2007-01-01

The status of theory of Superheavy Nuclei is reviewed. Based with the Two-Center Shell Model Potential Energy Surfaces are calculated. Fusion, fission, quasifission and other processes are discussed. I particular time-delay during the formation of giant quasi atoms/molecules will be crucial for observing the change of the Dirac vacuum in supercritical Coulomb fields by spontaneous positron emission. It will be shown how the various phenomena are interrelated

Half-life predictions for decay modes of superheavy nuclei

International Nuclear Information System (INIS)

Duarte, S.B.; Tavares, O.A.P.; Goncalves, M.; Rodriguez, O.; Guzman, F.; Barbosa, T.N.; Garcia, F.; Dimarco, A.

2004-09-01

We applied the Effective Liquid Drop Model (ELDM) to predict the alpha-decay, cluster emission and cold fission half-life-values of nuclei in the region of Superheavy Elements (SHE). The present calculations have been made in the region of the ZN-plane defined by 155 <=N <=220 and 110<=Z<=135. Shell effects are included via the Q-value of the corresponding decay case. We report the results of a systematic calculation of the half-life for the three nuclear decay modes in a region of the ZN-plane where superheavy elements are expected to be found. Results have shown that, among the decay modes investigated here, the alpha decay is the dominant one. i.e, the decay mode of smallest half-lives. Half-life predictions for alpha decay, cluster emission and cold fission for the isotopic family of the most recent SHE detected of Z=115 and for the isotopic family of the already consolidated SHE of Z=111 are presented. (author)

Positron creation in superheavy quasi-molecules

International Nuclear Information System (INIS)

Mueller, B.

1976-01-01

The review of positron creation in superheavy quasi-molecules includes spontaneous positron emission from superheavy atoms, supercritical quasi-molecules, background effects, and some implications of the new ground state. 66 references

Beyond darmstadtium -Status and perspectives of superheavy element research

International Nuclear Information System (INIS)

Ackermann, D.

2005-01-01

The search for superheavy elements has yielded exciting results for both the ''cold fusion'' approach with reactions employing Pb and Bi targets and the ''hot fusion'' reactions with 48 Ca beams on actinide targets. In recent years the accelerator laboratories in Berkeley, Dubna and Darmstadt have been joined by new players in the game in France with GANIL, Caen, and in Japan with RIKEN, Tokyo. The latter yielding very encouraging results for the reactions on Pb/Bi targets which confirmed the data obtained at GSI. Beyond the successful synthesis, interesting features of the structure of the very heavy nuclei like the hint for a possible K-isomer in 270 Ds or the population of states at a spin of up to 22ℎ in 254 No give a flavor of the exciting physics we can expect in the region at the very extreme upper right of the nuclear chart. To get a hand on it, a considerable increase in sensitivity is demanded from future experimental set-ups. High intensity stable beam accelerators, mass measurement in ion traps and mass spectrometers, as well as the possible employment of unstable neutron-rich projectile species, initially certainly only for systematic studies of reaction mechanism and nuclear structure features for lighter exotic neutron-rich isotopes, are some of the technological challenges which have been taken on. (orig.)

The extension of the Periodic System: superheavy - superneutronic

Energy Technology Data Exchange (ETDEWEB)

Greiner, W [Frankfurt Institute for Advanced Studies, J.W.Goethe University (Germany); Zagrebaev, V [Flerov Laboratory for Nuclear Reactions, Joint Institute for Nuclear Research, Dubna, Moscow Region (Russian Federation)

2009-12-31

Nuclear reactions leading to formation of new superheavy elements and isotopes are discussed. The scope and limitations of different nuclear reactions ('cold' and 'hot' synthesis, fusion of fission fragments, transfer reactions and reactions with radioactive ion beams) are analyzed, trying to find most promising reactions which may be used at available facilities.

Perspectives of production of superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Adamian, G. G.; Antonenko, N. V., E-mail: antonenk@theor.jinr.ru; Bezbakh, A. N.; Sargsyan, V. V. [Joint Institute for Nuclear Research, RU–141980 Dubna (Russian Federation); Scheid, W. [Institut für Theoretische Physik der Justus-Liebig-Universität, D–35392 Giessen (Germany)

2016-07-07

Possible ways of production of superheavies are discussed. Impact of nuclear structure on the production of superheavy nuclei in complete fusion reactions is discussed. The proton shell closure at Z = 120 is discussed.

Fission dynamics of superheavy nuclei formed in uranium induced reactions

International Nuclear Information System (INIS)

Gurjit Kaur; Sandhu, Kirandeep; Sharma, Manoj K.

2017-01-01

The compound nuclear system follows symmetric fission if the competing processes such as quasi-elastic, deep inelastic, quasi-fission etc are absent. The contribution of quasi fission events towards the fusion-fission mechanism depends on the entrance channel asymmetry of reaction partners, deformations and orientations of colliding nuclei beside the dependence on energy and angular momentum. Usually the 209 Bi and 208 Pb targets are opted for the production of superheavy nuclei with Z CN =104-113. The nuclei in same mass/charge range can also be synthesized using actinide targets + light projectiles (i.e. asymmetric reaction partners) via hot fusion interactions. These actinide targets are prolate deformed which prefer the compact configurations at above barrier energies, indicating the occurrence of symmetric fission events. Here an attempt is made to address the dynamics of light superheavy system (Z CN =104-106), formed via hot fusion interactions involving actinide targets

Exploration of (super-)heavy elements using the Skyrme-Hartree-Fock model

International Nuclear Information System (INIS)

Erler, Jochen

2011-01-01

Motivated by the steadily increasing number of known nuclei and nuclear properties, theories of nuclear structure are presently a field of intense research. This work concentrates on the self-consistent description of nuclei in terms of the Skyrme-Hartree-Fock (SHF) approach. The extrapolation of nuclear shell structure to the region of super-heavy elements (SHE) using the SHF model, the dependence on different parameterization and the influence of collective correlation will be studied. The general scope of this work are large scale calculation for a global survey of properties of SHE like binding energies, separation energies and decay characteristics and lifetimes. These calculations were done in a collaboration with the theory group of the GSI in Darmstadt and have the aim to develop a database of lifetimes and reaction rates for α, β-decay and spontaneous fission in a very wide range with proton numbers 86 ≤ Z ≤ 120 and neutron numbers up to N ∼ 260 relevant for the astrophysical r-process. The results of this study for example predictions of a possible islands of very stable nuclei and information of favored decay mode for each nuclei are also applicable in the recent experimental synthesis of exotic SHE. For these calculation a framework to calculate β-decay half-lives within the SHF model has been developed and the existing axial SHF code has been extended to compute β-transition matrix elements and so to provide an estimation of half-lives. (orig.)

Exploration of (super-)heavy elements using the Skyrme-Hartree-Fock model

Energy Technology Data Exchange (ETDEWEB)

Erler, Jochen

2011-01-31

Motivated by the steadily increasing number of known nuclei and nuclear properties, theories of nuclear structure are presently a field of intense research. This work concentrates on the self-consistent description of nuclei in terms of the Skyrme-Hartree-Fock (SHF) approach. The extrapolation of nuclear shell structure to the region of super-heavy elements (SHE) using the SHF model, the dependence on different parameterization and the influence of collective correlation will be studied. The general scope of this work are large scale calculation for a global survey of properties of SHE like binding energies, separation energies and decay characteristics and lifetimes. These calculations were done in a collaboration with the theory group of the GSI in Darmstadt and have the aim to develop a database of lifetimes and reaction rates for {alpha}, {beta}-decay and spontaneous fission in a very wide range with proton numbers 86 {<=} Z {<=} 120 and neutron numbers up to N {approx} 260 relevant for the astrophysical r-process. The results of this study for example predictions of a possible islands of very stable nuclei and information of favored decay mode for each nuclei are also applicable in the recent experimental synthesis of exotic SHE. For these calculation a framework to calculate {beta}-decay half-lives within the SHF model has been developed and the existing axial SHF code has been extended to compute {beta}-transition matrix elements and so to provide an estimation of half-lives. (orig.)

Fusion-fission probabilities, cross sections, and structure notes of superheavy nuclei

International Nuclear Information System (INIS)

Kowal, Michał; Cap, Tomasz; Jachimowicz, Piotr; Skalski, Janusz; Siwek-Wilczyńska, Krystyna; Wilczyński, Janusz

2016-01-01

Fusion – fission probabilities in the synthesis of heaviest elements are discussed in the context of the latest experimental reports. Cross sections for superheavy nuclei are evaluated using the “Fusion by Diffusion” (FBD) model. Predictive power of this approach is shown for experimentally known Lv and Og isotopes and predictions given for Z = 119, 120. Ground state and saddle point properties as masses, shell corrections, pairing energies, and deformations necessary for cross-section estimations are calculated systematically within the multidimensional microscopic-macroscopic method based on the deformed Woods-Saxon single-particle potential. In the frame of the FBD approach predictions for production of elements heavier than Z = 118 are not too optimistic. For this reason, and because of high instability of superheavy nuclei, we comment on some structure effects, connected with the K-isomerism phenomenon which could lead to a significant increase in the stability of these systems.

Problem of ''deformed'' superheavy nuclei

International Nuclear Information System (INIS)

Sobiczewski, A.; Patyk, Z.; Muntian, I.

2000-08-01

Problem of experimental confirmation of deformed shapes of superheavy nuclei situated in the neighbourhood of 270 Hs is discussed. Measurement of the energy E 2+ of the lowest 2+ state in even-even species of these nuclei is considered as a method for this confirmation. The energy is calculated in the cranking approximation for heavy and superheavy nuclei. The branching ratio p 2+ /p 0+ between α decay of a nucleus to this lowest 2+ state and to the ground state 0+ of its daughter is also calculated for these nuclei. The results indicate that a measurement of the energy E 2+ for some superheavy nuclei by electron or α spectroscopy is a promising method for the confirmation of their deformed shapes. (orig.)

New Fragment Separation Technology for Superheavy Element Research

International Nuclear Information System (INIS)

Shaughnessy, D A; Moody, K J; Henderson, R A; Kenneally, J M; Landrum, J H; Lougheed, R W; Patin, J B; Stoyer, M A; Stoyer, N J; Wild, J F; Wilk, P A

2008-01-01

This project consisted of three major research areas: (1) development of a solid Pu ceramic target for the MASHA separator, (2) chemical separation of nuclear decay products, and (3) production of new isotopes and elements through nuclear reactions. There have been 16 publications as a result of this project, and this collection of papers summarizes our accomplishments in each of the three areas of research listed above. The MASHA (Mass Analyzer for Super-Heavy Atoms) separator is being constructed at the U400 Cyclotron at the Flerov Laboratory of Nuclear Reactions in Dubna, Russia. The purpose of the separator is to physically separate the products from nuclear reactions based on their isotopic masses rather than their decay characteristics. The separator was designed to have a separation between isotopic masses of ±0.25 amu, which would enable the mass of element 114 isotopes to be measured with outstanding resolution, thereby confirming their discovery. In order to increase the production rate of element 114 nuclides produced via the 244 Pu+ 48 Ca reaction, a new target technology was required. Instead of a traditional thin actinide target, the MASHA separator required a thick, ceramic-based Pu target that was thick enough to increase element 114 production while still being porous enough to allow reaction products to migrate out of the target and travel through the separator to the detector array located at the back end. In collaboration with UNLV, we began work on development of the Pu target for MASHA. Using waste-form synthesis technology, we began by creating zirconia-based matrices that would form a ceramic with plutonium oxide. We used samarium oxide as a surrogate for Pu and created ceramics that had varying amounts of the starting materials in order to establish trends in material density and porosity. The results from this work are described in more detail in Refs. [1,4,10]. Unfortunately, work on MASHA was delayed in Russia because it was found that

Alguns aspectos históricos da classificação periódica dos elementos químicos Some historical aspects of the periodic classification of the chemical elements

Directory of Open Access Journals (Sweden)

Mario Tolentino

1997-02-01

Full Text Available A history of the periodic table of the elements is presented, from the first tentative classifications, passing through Meyer and Mendeleev, up to recent speculations on super-heavy elements still to be synthesized. Many of the discussions and discoveries related to chemical elements and their proper periodic classification are also presented.

Synthesis and decay process of superheavy nuclei with Z=119-122 via hot-fusion reactions

Energy Technology Data Exchange (ETDEWEB)

Ghahramany, N.; Ansari, A. [Shiraz University, Department of Physics and Biruni Observatory, College of Science, Shiraz (Iran, Islamic Republic of)

2016-09-15

In this research article attempts have been made to calculate the superheavy-nuclei synthesis characteristics including, the potential energy parameters, fusion probability, fusion and evaporation residue (ER) cross sections as well as, decay properties of compound nucleus and the residue nuclei formation probability for elements with Z=119-122 by using the hot-fusion reactions. It is concluded that, although a selection of double magic projectiles such as {sup 48}Ca with high binding energy, simplifies the calculations significantly due to spherical symmetric shape of the projectile, resulting in high evaporation residue cross section, unfortunately, nuclei with Z > 98 do not exist in quantities sufficient for constructing targets for the hot-fusion reactions. Therefore, practically our selection is fusion reactions with titanium projectile because the mass production of target nuclei for experimental purposes is more feasible. Based upon our findings, it is necessary, for new superheavy-nuclei production with Z > 119, to use neutron-rich projectiles and target nuclei. Finally, the maximal evaporation residue cross sections for the synthesis of superheavy elements with Z=119-122 have been calculated and compared with the previously founded ones in the literature. (orig.)

The Peculiarities of the Production and Decay of Superheavy Nuclei

International Nuclear Information System (INIS)

Itkis, M. G.; Bogachev, A. A.; Itkis, I. M.; Jandel, M.; Kliman, J.; Knyazheva, G. N.; Kondratiev, N. A.; Kozulin, E. M.; Krupa, L.; Oganessian, Yu. Ts.; Pokrovsky, I. V.; Prokhorova, E. V.; Rusanov, A. Ya.; Sagaidak, R. N.; Beghini, S.; Montagnoli, G.; Scarlassara, F.; Behera, B. R.; Corradi, L.; Fioretto, E.

2006-01-01

The interest in the study of the fission process of superheavy nuclei mainly deals with the opportunity to obtain information about the cross-section of the compound nucleus (CN) formation at excitation energies E*≅15-30 MeV. It allows one to estimate the survival probability of the superheavy composite system after evaporation of 1-3 neutrons, i.e. in 'cold' or 'warm' fusion reactions. However, in order to solve this problem deeper understanding of the coalescence processes between colliding nuclei, the competition between fusion-fission and quasi-fission processes is needed. The characteristics of both processes, their manifestation in the experimental observables and the relative contribution to the capture cross-section in dependence on the excitation energies, reaction entrance channel etc were investigated for a wide range of target-projectile combinations. Results of the experiments devoted to the study of the fusion-fission and quasi-fission processes in the reactions of the formation of the superheavy nuclei with Z = 102-122 are presented. The heavy ions 26Mg, 48Ca, 50Ti, 58Fe and 64Ni were used as projectiles. The choice of the reactions with 48Ca and actinide-targets was inspired by the experiments on the production of the isotopes 283112, 289114 and 283116 in Dubna using the same reactions. The 50Ti, 58Fe and 64Ni projectiles were chosen since the corresponding projectile-target combinations lead to the synthesis of even heavier elements. The experiments were carried out at the U-400 accelerator of the Flerov Laboratory of Nuclear Reactions (JINR, Russia) and the XTU Tandem accelerator of the National Laboratory of Legnaro (LNL, Italy) using the time-of-flight spectrometer of fission fragments CORSET. The role of the shell effects, the influence of the entrance channel asymmetry and the deformations of colliding nuclei on the mechanism of the fusion-fission and the competitive process of quasi-fission are discussed. The recent results on synthesis of

Gas phase chemical studies of superheavy elements using the Dubna gas-filled recoil separator - Stopping range determination

International Nuclear Information System (INIS)

Wittwer, D.; Abdullin, F.Sh.; Aksenov, N.V.; Albin, Yu.V.; Bozhikov, G.A.; Dmitriev, S.N.; Dressler, R.; Eichler, R.; Gaeggeler, H.W.; Henderson, R.A.; Huebener, S.; Kenneally, J.M.; Lebedev, V.Ya.; Lobanov, Yu.V.; Moody, K.J.; Oganessian, Yu.Ts.; Petrushkin, O.V.; Polyakov, A.N.; Piguet, D.; Rasmussen, P.

2010-01-01

Currently, gas phase chemistry experiments with heaviest elements are usually performed with the gas-jet technique with the disadvantage that all reaction products are collected in a gas-filled thermalisation chamber adjacent to the target. The incorporation of a physical preseparation device between target and collection chamber opens up the perspective to perform new chemical studies. But this approach requires detailed knowledge of the stopping force (STF) of the heaviest elements in various materials. Measurements of the energy loss of mercury (Hg), radon (Rn), and nobelium (No) in Mylar and argon (Ar) were performed at low kinetic energies of around (40-270) keV per nucleon. The experimentally obtained values were compared with STF calculations of the commonly used program for calculating stopping and ranges of ions in matter (SRIM). Using the obtained data points an extrapolation of the STF up to element 114, eka-lead, in the same stopping media was carried out. These estimations were applied to design and to perform a first chemical experiment with a superheavy element behind a physical preseparator using the nuclear fusion reaction 244 Pu( 48 Ca; 3n) 289 114. One decay chain assigned to an atom of 285 112, the α-decay product of 289 114, was observed.

New elements

International Nuclear Information System (INIS)

Flerov, G.

1976-01-01

The history is briefly described of the investigation of superheavy elements at the Joint Institute for Nuclear Research at Dubna. The significance of the investigation is assessed from the point of view of the nuclear structure study and major problems encountered in experimental efforts are indicated. Current experimental methods aiming at the discovery or the production of superheavy nuclei with Z approximately 114 are listed. (I.W.)

A systematic study of superheavy nuclei for Z = 114 and beyond using the relativistic mean field approach

International Nuclear Information System (INIS)

Patra, S.K.; Wu, Cheng-Li; Praharaj, C.R.; Gupta, Raj K.

1999-01-01

We have studied the structural properties of even-even, neutron deficient, Z=114-126, superheavy nuclei in the mass region A ∼ 270-320, using an axially deformed relativistic mean field model. The calculations are performed with three parameter sets (NL1, TM1 and NL-SH), in order to see the dependence of the structural properties on the force used. The calculated ground state shapes are found to be parameter dependent. For some parameter sets, many of the nuclei are degenerate in their ground state configuration. Special attention is given to the investigation of the magic structures (spherical shell closures) in the superheavy region. We find that some known magic numbers are absent and new closed shells are predicted. Large shell gaps appear at Z=80, 92, (114), 120 and 138, N=138, (164), (172), 184, (198), (228) and 258, irrespective of the parameter sets used. The numbers in parenthesis are those which correspond to relatively smaller gaps. The existence of new magic numbers in the valley of superheavy elements is discussed. It is suggested that nuclei around Z=114 and N = 164 ∼ 172 could be considered as candidates for the next search of superheavy nuclei. The existence of superheavy islands around Z=120 and N=172 or N 184 double shell closure is also discussed

Fission times studies of the Z=124 superheavy nucleus by X-ray fluorescence

International Nuclear Information System (INIS)

Airiau, Maud

2016-01-01

Since the 1960's nuclear structure model have predicted the existence of an island of stability of superheavy elements. It should be located around the next magic numbers expected at N=172 or 184 and between Z=114 and 126 depending on the model. Very high fission barrier of a few MeV are predicted to be generated by microscopic effects for those nuclei for which large fission times distributions extended to very high fission times are induced. Fission time measurements of the superheavy element Z=124 have been made by us using the X-ray fluorescence technique, a method based on the filling of inner-shell electronic vacancies created during the collision leading to the formation of the compound nucleus. The aim of this experiment was to detect in coincidence both fission fragments and characteristic X-rays from the Z=124, created by the reaction 238 U+ 70,76 Ge. The main difficulty was to identify those X-rays due to the fact that gamma-rays from fission fragments were emitted in the same energy range, which affected our photon multiplicities for any fragment selection. This new difficulty brings an important limitation to the study of some particular superheavy elements by the X-ray fluorescence method. K X-rays spectra have been simulated using MCDF (Multi-Configuration-Dirac-Fock) and then compared to the experimental ones in order to get a maximal K X-ray multiplicity compatible with our data. The extracted results were about 6-7% for 76 Ge and from 12 to 14% for 70 Ge. Those values remain compatible with the experimental signature of long lifetime component observed for the same system but using a blocking technique in single crystals. (author) [fr

Measurements of Plutonium isotopes and the search for super-heavy elements via AMS

International Nuclear Information System (INIS)

Wallner, A.; Steier, P.; Golser, R.; Knie, K.; Kutschera, W.; Priller, A.; Hrnecek, E.; Jakopic, R.; Korschinek, G.

2006-01-01

Full text: Accelerator Mass Spectrometry (AMS) - being independent on the half-life of a radionuclide - provides a technique to determine isotope ratios with the highest sensitivity and allows the measurement of radionuclides over a wide dynamic range of concentration levels. A combination of AMS, Alpha Spectrometry and Liquid Scintillation Counting was used for the determination of the complete information on isotope ratios of Plutonium isotopes in different environmental reference samples (e.g. from the atolls of Mururoa and Fangataufa) and samples contaminated from nuclear reprocessing. Results for the isotopic ratios of the samples will be shown and the capabilities and detection limits achievable for determination of Pu will be discussed. The long-lived 244 Pu (t 1/2 = 80 Ma) and 247 Cm (t 1/2 = 15.6 Ma) have a very interesting application in astrophysics by detecting possible supernova-produced 244 Pu and 247 Cm in terrestrial archives. The expected extremely small concentrations of 244 Pu makes AMS the favorite method. The actual search for such long-lived extraterrestrial radionuclides and possible implications will be presented. The same method has also been explored for a pinprick-search of long-lived super-heavy elements in the mass region above Z=100. (author)

Superheavy nuclei: a relativistic mean field outlook

International Nuclear Information System (INIS)

Afanasjev, A.V.

2006-01-01

The analysis of quasi-particle spectra in the heaviest A∼250 nuclei with spectroscopic data provides an additional constraint for the choice of effective interaction for the description of superheavy nuclei. It strongly suggests that only the parametrizations which predict Z = 120 and N = 172 as shell closures are reliable for superheavy nuclei within the relativistic mean field theory. The influence of the central depression in the density distribution of spherical superheavy nuclei on the shell structure is studied. A large central depression produces large shell gaps at Z = 120 and N = 172. The shell gaps at Z = 126 and N = 184 are favoured by a flat density distribution in the central part of the nucleus. It is shown that approximate particle number projection (PNP) by means of the Lipkin-Nogami (LN) method removes pairing collapse seen at these gaps in the calculations without PNP

In-beam separation and mass determination of superheavy nuclei

International Nuclear Information System (INIS)

Malyshev, O.N.; Eremin, A.V.; Popeko, A.G.

2003-01-01

Within the past fifteen years, the recoil separator VASSILISSA has been used for the investigations of evaporation residues produced in complete fusion reactions induced by heavy ions. The study of decay properties and formation cross sections of the isotopes of elements 110, 112 and 114 was performed using high intensity 48 Ca beams and 232 Th, 238 U, 242 Pu targets. For further experiments aimed at the synthesis of the superheavy element isotopes (Z≥110) with the use of intense 48 Ca extracted beams, improvements in the ion optical system of the separator and the focal plane detector system have been made. The results from the test reactions and new result for the isotope 283 112 are presented

On the prospects to detect superheavy elements (SHE) in the earth's crust using the high energy synchrotron radiation and the mass spectrometry

International Nuclear Information System (INIS)

Schnier, C.

2001-01-01

There are many indications for the existence of superheavy elements (SHE) in the Earth's crust. The appropriate detection methods are X-ray fluorescence (XRF) using the high energy synchrotron radiation and the mass spectrometry. The characteristic X-rays of each element up to Z >120 (corresponding binding energy of the K-electrons E b >230 keV) can be precisely excited with synchrotron XRF. Up to now, the XRF with high energy photons has never been applied to the quest for SHE. New methods of mass spectrometry eg using resonance ionization (RIMS) are promising to detect unambiguously atomic masses about 300 in solid matrices. It is proposed to restart the quest for SHE in the nature. Finding a SHE in the Earth's crust would be very important, because of what it will tell us about the origin of the elements eg about the nucleosynthesis during a super nova explosion, the structure of the atomic nuclei and the site of SHE in the periodic table of elements. (orig.) [de

Structure of superheavy elements with Meson field theory and beyond

International Nuclear Information System (INIS)

Walter Greiner

2005-01-01

The extension of the periodic system into various new areas is investigated. Experiments for the synthesis of superheavy elements and the predictions of magic numbers with modern meson field theories are reviewed. Furtheron, different channels of nuclear decay are discussed including cluster radioactivity, cold fission and cold multifragmentation. A perspective for future research is given. We also study the possibility of producing a new kind of nuclear system that in addition to ordinary nucleons contains a few antibaryons. The properties of such systems are described within the relativistic mean-field model by employing G-parity transformed interactions for antibaryons. Calculations are first done for infinite systems and then for finite nuclei from 4 He to 208 Pb. It is demonstrated that the presence of a real antibaryon leads to a strong rearrangement of a target nucleus, resulting in a significant increase of its binding energy and local compression. Noticeable effects remain even after the antibaryon coupling constants are reduced by a factor of 3-4 compared to G-parity motivated values. We have performed detailed calculations of the antibaryon annihilation rates in the nuclear environment by applying a kinetic approach. It is shown that owing to significant reduction of the reaction Q values, the in-medium annihilation rates should be strongly suppressed, leading to relatively long-lived antibaryon- nucleus systems. Multinucleon annihilation channels are analyzed too. We have also estimated formation probabilities of bound antibaryon-nucleus systems in antiproton- nucleus reactions and have found that their observation will be feasible at the future GSI antiproton facility. Several observable signatures are proposed. The possibility of producing cold multi-quark-antiquark clusters is discussed. This opens the possibility for cold compression of nuclear matter - in contrast to the creation of hot and dense nuclear matter in nuclear shock waves created in

Neutron and Proton Diffusion in Fusion Reactions for the Synthesis of Superheavy Nuclei

International Nuclear Information System (INIS)

Ming-Hui, Huang; Zai-Guo, Gan; Zhao-Qing, Feng; Xiao-Hong, Zhou; Jun-Qing, Li

2008-01-01

The restriction of the one dimensional (1D) master equation (ME) with the mass number of the projectile-like fragment as a variable is studied, and a two-dimensional (2D) master equation with the neutron and proton numbers as independent variables is set up, and solved numerically. Our study showed that the 2D ME can describe the fusion process well in all projectile-target combinations. Therefore the possible channels to synthesize super-heavy nuclei can be studied correctly in wider possibilities. The available condition for employing 1D ME is pointed out

Status and prospect of super-heavy nuclei research at IMP

International Nuclear Information System (INIS)

Xu Hushan; Sun Zhiyu; Zhan Wenlong; Zhou Xiaohong; Huang Wenxue; Zhang Hongbin; Gan Zaiguo; Li Junqing; Ma Xinwen; Qin Zhi; Xiao Guoqing; Guo Zhongyan; Li Zhihui; Zhang Yuhu; Jin Genming; Huang Tianheng; Hu Zhengguo; Zhang Xueheng; Zheng Chuan; Chinese Academy of Sciences, Beijing

2006-01-01

The history and the international status of the super-heavy nuclei synthesis are briefly described. The related research work carried out at the Institute of Modern Physics (IMP) has been reviewed. The prospect of the super-heavy nuclei research at IMP has been introduced. (authors)

Studies on the synthesis of isotopes of superheavy element Lv (Z = 116)

Energy Technology Data Exchange (ETDEWEB)

Santhosh, K.P.; Safoora, V. [Kannur University, School of Pure and Applied Physics, Payyanur (India)

2017-11-15

The probable projectile-target combinations for the synthesis of superheavy nucleus {sup 296}Lv found in the cold valley of {sup 296}Lv have been identified by studying the interaction barrier of the colliding nuclei, probability of compound nucleus formation, P{sub CN}, and survival probability W{sub sur}. At energies near and above the Coulomb barrier, the capture, fusion and evaporation residue (ER) cross sections for the probable combinations for the hot and cold fusion reactions are systematically investigated. By considering intensities of the projectile beams, availabilities of the targets and half lives of the colliding nuclei, the combination {sup 48}Ca + {sup 248}Cm is found to be the most probable projectile-target pair for the synthesis of {sup 296}Lv. The calculated maximum value of 2n, 3n, 4n and 5n channel cross section for the reaction {sup 48}Ca + {sup 248}Cm are 0.599 pb, 5.957 pb, 4.805 pb, and 0.065 pb, respectively. Moreover, the production cross sections for the synthesis of isotopes {sup 291-295,298}Lv using {sup 48}Ca projectile on {sup 243-247,250}Cm targets are calculated. Among these reactions, the reactions {sup 48}Ca + {sup 247}Cm → {sup 295}Lv and {sup 48}Ca + {sup 250}Cm → {sup 298}Lv have maximum production cross section in 3n (10.697 pb) and 4n (12.006 pb) channel, respectively. Our studies on the SHE Lv using the combinations {sup 48}Ca + {sup 245}Cm → {sup 293}Lv and {sup 48}Ca + {sup 248}Cm → {sup 296}Lv are compared with available experimental data and with other theoretical studies. Our studies are in agreement with experimental data and we hope that these studies will be a guide for the future experiments to synthesize the isotopes of Lv. (orig.)

New semi-empirical formula for α-decay half-lives of the heavy and superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Manjunatha, H.C. [Government College for Women, Department of Physics, Kolar, Karnataka (India); Sridhar, K.N. [Government First Grade College, Department of Physics, Kolar, Karnataka (India)

2017-07-15

We have succesfully formulated the semi-empirical formula for α-decay half-lives of heavy and superheavy nuclei for different isotopes of the wide atomic-number range 94 < Z < 136. We have considered 2627 isotopes of heavy and superheavy nuclei for the fitting. The value produced by the present formula is compared with that of experiments and other eleven models, i.e. ImSahu, Sahu, Royer10, VS2, UNIV2, SemFIS2, WKB. Sahu16, Densov, VSS and Royer formula. This formula is exclusively for heavy and superheavy nuclei. α-decay is one of the dominant decay mode of superheavy nucleus. By identifying the α-decay mode superheavy nuclei can be detected. This formula helps in predicting the α-decay chains of superheavy nuclei. (orig.)

Superheavy elements and decay properties

Indian Academy of Sciences (India)

2015-08-04

Aug 4, 2015 ... The decay properties of the isotopes of = 115, 117, 118 and 119 have been extensively investigated, focussing on the newly synthesized isotopes within the Coulomb and proximity potential model for deformed nuclei (CPPMDN). The half-lives have also been evaluated using the Viola–Seaborg ...

Toroidal Superheavy Nuclei in Skyrme-Hartree-Fock Approach

International Nuclear Information System (INIS)

Staszczak, A.; Wong, Cheuk-Yin

2009-01-01

Within the self-consistent constraint Skyrme-Hartree-Fock+BCS model (SHF+BCS), we found equilibrium toroidal nuclear density distributions in the region of superheavy elements. For nuclei with a sufficient oblate deformation (Q 20 < -200 b), it becomes energetically favorable to change the genus of nuclear surface from 0 to 1, i.e., to switch the shape from a biconcave disc to a torus. The energy of the toroidal (genus=1) SHF+BCS solution relative to the compact (genus=0) ground state energy is strongly dependent both on the atomic number Z and the mass number A. We discuss the region of Z and A where the toroidal SHF+BCS total energy begins to be a global minimum

New isotopes of elements 104, 106 and 108 - highly stable superheavy nuclei

International Nuclear Information System (INIS)

Oganessian, Yuri

1994-01-01

In April 1993, as part of a joint Dubna-Livermore experiment at the Flerov Laboratory of Nuclear Reactions, new heavy isotopes of elements 104 and 106 were synthesized - 262 104, 265 106 and 266 106. Compared with the known even-even isotopes of elements 104 and 106, the new nuclei are characterized by their extraordinary high resistance to spontaneous fission. This is a direct proof of the macro-microscopic theory predictions in its version calculated by A.Sobiczewski et al. regarding a substantial increase in the half-lives of heavy nuclei near deformed shells with atomic number (Z) 108 and neutron number (N) 162.

Fusion-fission dynamics and synthesis of the superheavy elements

International Nuclear Information System (INIS)

Abe, Yasuhisa

2003-01-01

given by a product of the sticking and the formation probabilities. The former is that for the system to overcome the Coulomb barrier to stick each other, while the latter that for the system to overcome the conditional saddle to form the spherical shape. Residue cross sections for the superheavy elements are predicted by combining the survival probability which is calculated with the statistical theory of decay. Some examples will be presented on Z=110, 111, 112 and 113. (author)

Alpha-decay chains of superheavy nuclei 292-296118

Science.gov (United States)

Singh, U. K.; Kumawat, M.; Saxena, G.; Kaushik, M.; Jain, S. K.

2018-05-01

We have employed relativistic mean-field plus BCS (RMF+BCS) approach for the study of even-even superheavy nuclei with Z = 118 which is the last and recent observed element in the periodic chart so far. Our study includes binding energies, Qα values, alpha-decay half-lives and spontaneous decay half-lives along with comparison of available experimental data and the results of FRDM calculations. We find an excellent match with the only known decay chain of 294118 for Z = 118 so far and predict decay chain of 292118 and 296118 in consistency with known experimental decay chains and FRDM results. These results may provide a very helpful insight to conduct experiments for realizing the presence of nuclei with Z = 118.

A pilgrimage through superheavy valley

Indian Academy of Sciences (India)

gap p, average neutron pairing gap n, two-nucleon separation energy S2q and shell .... study has appeared as a powerful tool to study the shapes and collective properties of nuclei ... and identify the magic proton and neutron numbers in the superheavy region. ... pairing gap indicates the close shell structure of the nucleus.

On the thermalization achieved in the reactions involving superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Bansal, Rajni [Department of Physics, MCM DAV College for Women, Sector 36A, Chandigarh-160036, India rajnibansal.pu@gmail.com (India)

2016-05-06

In the present study, we aim to explore the role of Coulomb potential on the thermalization achieved in the reactions involving superheavy nuclei. Particularly, we shall study the degree of the equilibrium attained in a reaction by the 3D density plots, anisotropy ratio as well as by the rapidity distribution of the nucleons. Our study reveals that the degree of the equilibrium attained in the central reactions of the superheavy nuclei remains unaffected by the Coulomb potential.

Transactinide elements

International Nuclear Information System (INIS)

Hemingway, J.D.

1975-01-01

The review is covered in sections, entitled: predicted nuclear properties - including closed shells, decay characteristics; predicted chemical properties - including electronic structure and calculated properties, X-radiation, extrapolated chemical properties, separation chemistry; methods of synthesis; the natural occurrence of superheavy elements. (U.K.)

Gravitational production of superheavy dark matter

International Nuclear Information System (INIS)

Chung, Daniel J. H.; Crotty, Patrick; Kolb, Edward W.; Riotto, Antonio

2001-01-01

The dark matter in the universe can be in the form of a superheavy matter species (wimpzilla). Several mechanisms have been proposed for the production of wimpzilla particles during or immediately following the inflationary epoch. Perhaps the most attractive mechanism is through gravitational particle production, where particles are produced simply as a result of the expansion of the universe. In this paper we present a detailed numerical calculation of wimpzilla gravitational production in hybrid-inflation models and natural-inflation models. Generalizing these findings, we also explore the dependence of the gravitational production mechanism on various models of inflation. We show that superheavy dark matter production seems to be robust, with Omega X h 2 ∼(M X /10 11 GeV) 2 (T RH /10 9 GeV), so long as M X I , where M X is the wimpzilla mass, T RH is the reheat temperature, and H I is the expansion rate of the universe during inflation

The chemistry of transactinide elements. Experimental achievements and perspectives

International Nuclear Information System (INIS)

Schaedel, M.

2002-01-01

The chemistry of transactinides and superheavy elements has reached element 108. Preparations are under way to leap to element 112 and beyond. This development, its current status and future perspectives are reviewed from an experimental point of view. The atom-at-a-time situation of transactinide chemistry is briefly outlines. Experimental techniques and important results enlightening the chemical properties of elements 104 through 108 are presented in an exemplary way with emphasis on the aqueous chemistry of the lighter ones. From the results of these experiments it is justified to place these elements in the Periodic Table of the Elements into groups 4 through 8, respectively. However, strongly due to the influence of relativistic effects, it is no longer possible to deduce detailed chemical properties of these superheavy elements from this position. Perspectives for future research programs are given. (author)

Chemical identification and properties of element 112

Czech Academy of Sciences Publication Activity Database

Yakushev, AB.; Zvára, Ivo; Oganessian, YT.; Belozerov, AV.; Dmitriev, S. N.; Eichler, B.; Hubener, S.; Sokol, EA.; Turler, A.; Yeremin, AV.; Buklanov, GV.; Chelnokov, ML.; Chepigin, VI.; Gorshkov, VA.; Gulyaev, AV.; Lebedev, VY.; Malyshev, ON.; Popeko, AG.; Soverna, S.; Szeglowski, Z.; Timokhin, SN.; Tretyakova, SP.; Vasko, VM.; Itkis, MG.

2003-01-01

Roč. 91, č. 8 (2003), s. 433-439 ISSN 0033-8230 Institutional research plan: CEZ:AV0Z1048901 Keywords : element 112 * superheavy elements * transactinoids Subject RIV: CH - Nuclear ; Quantum Chemistry Impact factor: 0.940, year: 2003

Collective motion in hot superheavy nuclei

NARCIS (Netherlands)

Tveter, TS; Gaardhoje, JJ; Maj, A; Ramsoy, T; Atac, A; Bacelar, J; Bracco, A; Buda, A; Camera, F; Herskind, B; Korten, W; Krolas, W; Menthe, A; Million, B; Nifenecker, H; Pignanelli, M; Pinston, JA; vanderPloeg, H; Schussler, F; Sletten, G

1996-01-01

The superheavy nucleus (272)(108)Hs and its evaporation daughters have been produced using the reaction Th-232(Ar-40,gamma xn) with beam energies 10.5 and 15.0 MeV/A. The Giant Dipole Resonance gamma-radiation from the hot conglomerate system prior to fission has been isolated using a differential

Structural and decay properties of Z = 132, 138 superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Rather, Asloob A.; Ikram, M.; Usmani, A.A. [Aligarh Muslim University, Department of Physics, Aligarh (India); Kumar, Bharat; Patra, S.K. [Institute of Physics, Bhubaneswar (India); Homi Bhabha National Institute, Mumbai, Anushakti Nagar (India)

2016-12-15

In this paper, we analyze the structural properties of Z = 132 and Z = 138 superheavy nuclei within the ambit of axially deformed relativistic mean-field framework with NL3* parametrization and calculate the total binding energies, radii, quadrupole deformation parameter, separation energies, density distributions. We also investigate the phenomenon of shape coexistence by performing the calculations for prolate, oblate and spherical configurations. For clear presentation of nucleon distributions, the two-dimensional contour representation of individual nucleon density and total matter density has been made. Further, a competition between possible decay modes such as α-decay, β-decay and spontaneous fission of the isotopic chain of superheavy nuclei with Z = 132 within the range 312 ≤ A ≤ 392 and 318 ≤ A ≤ 398 for Z = 138 is systematically analyzed within self-consistent relativistic mean-field model. From our analysis, we inferred that the α-decay and spontaneous fission are the principal modes of decay in majority of the isotopes of superheavy nuclei under investigation apart from β-decay as dominant mode of decay in {sup 318-322}138 isotopes. (orig.)

New elements. [Translated from Vestnik Akademii Nauk SSSR, 6 (1974)

Energy Technology Data Exchange (ETDEWEB)

Flerov, G

1976-04-01

The history is briefly described of the investigation of superheavy elements at the Joint Institute for Nuclear Research at Dubna. The significance of the investigation is assessed from the point of view of the nuclear structure study and major problems encountered in experimental efforts are indicated. Current experimental methods aiming at the discovery or the production of superheavy nuclei with Z approximately 114 are listed.

Dynamical limitations to heavy-ion fusion

International Nuclear Information System (INIS)

Back, B.B.

1983-01-01

In spite of the many attempts to synthesize superheavy elements in recent years, these efforts have not yet been successful. Recent improved theoretical models of heavy-ion fusion reactions suggest that the formation of super-heavy elements is hindered by the dynamics of the process. Several recent experiments lend support to these theories. The necessity of an excess radial velocity (extra push) over the Coulomb barrier in order to induce fusion is observed experimentally as predicted by the theory. So is a new reaction mechanism, called quasi-fission which tend to exhaust the part of the reaction cross section, which would otherwise lead to fusion. The present study shows that the angular distribution of fragments from quasi-fission processes are very sensitive to the occurrence of this reaction mechanism. A slight modification of one parameter in the theory demanded by the observation of quasi-fission for lighter projectiles via the angular distributions, has the consequence of posing even more-stringent limitations on heavy-ion-fusion reactions. This reduces even further the possibility for synthesizing and identifying superheavy elements in heavy-ion-fusion reactions

On-line mass separator of superheavy atoms

International Nuclear Information System (INIS)

Oganesyan, Yu.Ts.

2002-01-01

The concept is presented of an on-line Mass Analyzer of SuperHeavy Atoms (MASHA) dedicated to the separation and determination of the mass and decay properties of new elements and isotopes produced in heavy-ion induced reactions. The new nuclides with half-lives T 1/2 ≥ 1 s are transported to an ECR-source working at a frequency of 2.45 GHz and are separated by mass with a mass resolution of M/ΔM ∼ 1500. In the focal plane of the magnetic analyzer a front strip detector surrounded by side detectors will be placed to determine the mass according to the signals from the detected α-particles or fission fragments with efficiency of about 90 %. In comparison to other existing in-flight recoil separators, the present setup will be characterized by higher efficiency and high selectivity relative to background reaction products. The setup MASHA may be used also in the investigation of nuclear reactions of different type induced by stable and radioactive beams

On-Line Mass Separator of Superheavy Atoms

CERN Document Server

Oganessian, Yu T

2002-01-01

The concept is presented of an on-line Mass Analyzer of SuperHeavy Atoms (MASHA) dedicated to the separation and determination of the mass and decay properties of new elements and isotopes produced in heavy-ion induced reactions. The new nuclides with half-lives T_{1/2}\\ge 1 s are transported to an ECR-source working at a frequency of 2.45 GHz and are separated by mass with a mass resolution of M/\\Delta M\\sim 1500. In the focal plane of the magnetic analyzer a front strip detector surrounded by side detectors will be placed to determine the mass according to the signals from the detected alpha-particles or fission fragments with efficiency of about 90 %. In comparison to other existing in-flight recoil separators, the present setup will be characterized by higher efficiency and high selectivity relative to background reaction products. The setup MASHA may be used also in the investigation of nuclear reactions of different type induced by stable and radioactive beams.

Fusion-fission of superheavy nuclei at low excitation energies

International Nuclear Information System (INIS)

Itkis, M.G.; Oganesyan, Yu.Ts.; Kozulin, E.M.

2000-01-01

The process of fusion-fission of superheavy nuclei with Z = 102 -122 formed in the reactions with 22 Ne, 26 Mg, 48 Ca, 58 Fe and 86 Kr ions at energies near and below the Coulomb barrier has been studied. The experiments were carried out at the U-400 accelerator of the Flerov Laboratory of Nuclear Reactions (JINR) using a time-of-flight spectrometer of fission fragments CORSET and a neutron multi-detector DEMON. As a result of the experiments, mass and energy distributions of fission fragments, fission and quasi-fission cross sections, multiplicities of neutrons and gamma-rays and their dependence on the mechanism of formation and decay of compound superheavy systems have been studied

Influence of fragment deformation and orientation on compact configuration of odd-Z superheavy nuclei

International Nuclear Information System (INIS)

Gurjit Kaur; Sandhu, Kirandeep; Sharma, Manoj K.

2016-01-01

The synthesis of heavy and superheavy nuclei is generally carried out by using hot and cold fusion reaction mechanisms. It has been noticed that, the cold fusion reactions occur at relatively low excitation energies (E*_C_N ∼ 10-20 MeV) whereas, the hot fusion reactions occur at excitation energies of E*_C_N ∼ 30- 50 MeV. The fusion mechanism is quite different in both the processes. In the cold fusion process, the interaction of spherical targets (Pb and Bi) with deformed light mass projectiles occurs. On the other hand, the fusion of deformed actinide targets with spherical "4"8Ca projectile characterize the hot interaction processes. Hence the deformations and orientations of targets and projectiles play extremely important role in the superheavy fusion process. The present analysis is carried out to aggrandize the work of which illustrate the role of deformations and orientations on even superheavy nuclei. Here, we extend this analysis for odd superheavy nuclei. It is relevant to note that the temperature and angular momentum effects are not included in the present analysis

Super-heavy dark matter – Towards predictive scenarios from inflation

Energy Technology Data Exchange (ETDEWEB)

Kannike, Kristjan [National Institute of Chemical Physics and Biophysics, Rävala 10, 10143 Tallinn (Estonia); Racioppi, Antonio, E-mail: antonio.racioppi@kbfi.ee [National Institute of Chemical Physics and Biophysics, Rävala 10, 10143 Tallinn (Estonia); Raidal, Martti [National Institute of Chemical Physics and Biophysics, Rävala 10, 10143 Tallinn (Estonia); Institute of Physics, University of Tartu, W. Ostwaldi 1, 50411 Tartu (Estonia)

2017-05-15

A generic prediction of the Coleman–Weinberg inflation is the existence of a heavy particle sector whose interactions with the inflaton, the lightest state in this sector, generate the inflaton potential at loop level. For typical interactions the heavy sector may contain stable states whose relic abundance is generated at the end of inflation by the gravity alone. This general feature, and the absence of any particle physics signal of dark matter so far, motivates us to look for new directions in the dark sector physics, including scenarios in which dark matter is super-heavy. In this article we study the possibility that the dark matter is even heavier than the inflaton, its existence follows from the inflaton dynamics, and its abundance today is naturally determined by the weakness of gravitational interaction. This implies that the super-heavy dark matter scenarios can be tested via the measurements of inflationary parameters and/or the CMB isocurvature perturbations and non-Gaussianities. We explicitly work out details of three Coleman–Weinberg inflation scenarios, study the systematics of super-heavy dark matter production in those cases, and compute which parts of the parameter spaces can be probed by the future CMB measurements.

Decay of heavy and superheavy nuclei

Indian Academy of Sciences (India)

April 2014 physics pp. 705–715. Decay of heavy and superheavy nuclei ... study on the feasibility of observing α decay chains from the isotopes of the ... studies on 284−286115 and 288−292117 will be a guide to future experiments. .... ratio of the α decay from the ground state of the parent nucleus to the level i of the.

Super-heavy dark matter – Towards predictive scenarios from inflation

Directory of Open Access Journals (Sweden)

Kristjan Kannike

2017-05-01

Full Text Available A generic prediction of the Coleman–Weinberg inflation is the existence of a heavy particle sector whose interactions with the inflaton, the lightest state in this sector, generate the inflaton potential at loop level. For typical interactions the heavy sector may contain stable states whose relic abundance is generated at the end of inflation by the gravity alone. This general feature, and the absence of any particle physics signal of dark matter so far, motivates us to look for new directions in the dark sector physics, including scenarios in which dark matter is super-heavy. In this article we study the possibility that the dark matter is even heavier than the inflaton, its existence follows from the inflaton dynamics, and its abundance today is naturally determined by the weakness of gravitational interaction. This implies that the super-heavy dark matter scenarios can be tested via the measurements of inflationary parameters and/or the CMB isocurvature perturbations and non-Gaussianities. We explicitly work out details of three Coleman–Weinberg inflation scenarios, study the systematics of super-heavy dark matter production in those cases, and compute which parts of the parameter spaces can be probed by the future CMB measurements.

Superheavy nuclei – cold synthesis and structure

Indian Academy of Sciences (India)

120 and Ж = 172 or 184, for superheavy nuclei. This result is discussed in ... 1980 [7] on the basis of the QMFT, once again prior to its observation in 1984. Thus, cold ... On the other hand, based on a rather complete deformed relativistic mean field (DRMF) calculation, using the NL1 parameter set, we [16] predicted. = 120.

Superheavy nuclei in the relativistic mean-field theory

International Nuclear Information System (INIS)

Lalazissis, G.A.; Ring, P.; Gambhir, Y.K.

1996-01-01

We have carried out a study of superheavy nuclei in the framework of the relativistic mean-field theory. Relativistic Hartree-Bogoliubov (RHB) calculations have been performed for nuclei with large proton and neutron numbers. A finite-range pairing force of Gogny type has been used in the RHB calculations. The ground-state properties of very heavy nuclei with atomic numbers Z=100-114 and neutron numbers N=154-190 have been obtained. The results show that in addition to N=184 the neutron numbers N=160 and N=166 exhibit an extra stability as compared to their neighbors. For the case of protons the atomic number Z=106 is shown to demonstrate a closed-shell behavior in the region of well deformed nuclei about N=160. The proton number Z=114 also indicates a shell closure. Indications for a doubly magic character at Z=106 and N=160 are observed. Implications of shell closures on a possible synthesis of superheavy nuclei are discussed. (orig.)

Remarks on the fission barriers of super-heavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Hofmann, S. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Goethe-Universitaet Frankfurt, Institut fuer Physik, Frankfurt (Germany); Heinz, S.; Mann, R.; Maurer, J.; Muenzenberg, G.; Barth, W.; Dahl, L.; Kindler, B.; Kojouharov, I.; Lang, R.; Lommel, B.; Runke, J.; Scheidenberger, C.; Tinschert, K. [GSI Helmholtzzentrum fuer Schwerionenforschung, Darmstadt (Germany); Antalic, S. [Comenius University, Department of Nuclear Physics and Biophysics, Bratislava (Slovakia); Eberhardt, K.; Thoerle-Pospiech, P.; Trautmann, N. [Johannes Gutenberg-Universitaet Mainz, Mainz (Germany); Grzywacz, R. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); University of Tennessee, Knoxville, TN (United States); Hamilton, J.H. [Vanderbilt University, Department of Physics and Astronomy, Nashville, TN (United States); Henderson, R.A.; Kenneally, J.M.; Moody, K.J.; Shaughnessy, D.A.; Stoyer, M.A. [Lawrence Livermore National Laboratory, Livermore, CA (United States); Miernik, K. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); University of Warsaw, Warsaw (Poland); Miller, D. [University of Tennessee, Knoxville, TN (United States); Morita, K. [RIKEN Nishina Center for Accelerator-Based Science, Wako, Saitama (Japan); Nishio, K. [Japan Atomic Energy Agency, Tokai, Ibaraki (Japan); Popeko, A.G.; Yeremin, A.V. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Roberto, J.B.; Rykaczewski, K.P. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Uusitalo, J. [University of Jyvaeskylae, Department of Physics, Jyvaeskylae (Finland)

2016-04-15

Shell-correction energies of super-heavy nuclei are approximated by using Q{sub α} values of measured decay chains. Five decay chains were analyzed, which start at the isotopes {sup 285}Fl, {sup 294}118, {sup 291}Lv, {sup 292}Lv and {sup 293}Lv. The data are compared with predictions of macroscopic-microscopic models. Fission barriers are estimated that can be used to eliminate uncertainties in partial fission half-lives and in calculations of evaporation-residue cross-sections. In that calculations, fission probability of the compound nucleus is a major factor contributing to the total cross-section. The data also provide constraints on the cross-sections of capture and quasi-fission in the entrance channel of the fusion reaction. Arguments are presented that fusion reactions for synthesis of isotopes of elements 118 and 120 may have higher cross-sections than assumed so far. (orig.)

First attempt to chemically identify element 112

Czech Academy of Sciences Publication Activity Database

Yakushev, AB.; Buklanov, GV.; Chelnokov, ML.; Chepigin, VI.; Dmitriev, S. N.; Gorshkov, VA.; Hubener, S.; Malyshev, ON.; Oganessian, YT.; Popeko, AG.; Sokol, EA.; Timokhin, SN.; Turler, A.; Vasko, VM.; Yeremin, AV.; Zvára, Ivo

2001-01-01

Roč. 89, 11/12 (2001), s. 743-745 ISSN 0033-8230 Institutional research plan: CEZ:AV0Z1048901 Keywords : superheavy elements * actionoid * transactinoids Subject RIV: CH - Nuclear ; Quantum Chemistry Impact factor: 0.660, year: 2001

Salam-Weinberg symmetry breaking with superheavy Higgs particles

International Nuclear Information System (INIS)

Misra, S.P.

1986-09-01

We discuss here the possibility of the breaking of the Salam-Weinberg symmetry by Higgs particles which are superheavy. The symmetry-breaking is associated with a nonzero vacuum expectation value of fermion condensates. This mechanism, if operative in nature, will imply the absence of Higgs particles at the weak scale. (author)

Observation of superheavy primary cosmic ray nuclei with solid state track detectors and x-ray films

International Nuclear Information System (INIS)

Doke, Tadayoshi; Hayashi, Takayoshi; Ito, Kensai; Yanagimachi, Tomoki; Kobayashi, Shigeru.

1977-01-01

The measurements of energy spectra and the nuclear charge distribution of superheavy nuclei heavier than iron in primary cosmic ray can provide information on the origin, propagation and life time of the cosmic ray. Since incident particles are in the region of relativistic velocity (the low energy cosmic ray below the cutoff energy is forbidden from entering), the charges of cosmic ray nuclei can be determined without knowing the energy of particles. The balloon-borne solid state track detector and plastic and X-ray films were employed for the detection of superheavy cosmic ray, and the five events were detected with the cellulose nitrate film. The flux of superheavy nuclei is predicted from the present analysis. (Yoshimori, M.)

On the problem of synthesis of superheavy nuclei. A short historical review on first theoretical predictions

International Nuclear Information System (INIS)

Kalinkin, B.N.; Gareev, F.A.

1999-01-01

It is shown that it is just Dubna that possesses the priority both in the recent synthesis of a superheavy nucleus with charge Z=114 (Flerov Laboratory of Nuclear Reactions, JINR) and in its theoretical prediction (Bogolyubov Laboratory of Theoretical Physics, JINR) made 33 years ago. Possible sizes of the 'island of stability' of superheavy nuclei are discussed

Dynamics of light, intermediate, heavy and superheavy nuclear ...

Indian Academy of Sciences (India)

2014-05-01

May 1, 2014 ... Various features related to the dynamics of competing decay modes of nuclear systems are explored by addressing the experimental data of a number of reactions in light, intermediate, heavy and superheavy mass regions. The DCM, being a non-statistical description for the decay of a com- pound nucleus ...

Predictions on the modes of decay of even Z superheavy isotopes within the range 104 ≤ Z ≤ 136

Science.gov (United States)

Santhosh, K. P.; Nithya, C.

2018-01-01

The decay modes and half lives of all the even Z isotopes of superheavy elements within the range 104 ≤ Z ≤ 136 have been predicted by comparing the alpha decay half-lives with the spontaneous fission half-lives. The Coulomb and proximity potential model for deformed nuclei (CPPMDN) and the shell-effect-dependent formula of Santhosh et al. are used to calculate the alpha half-lives and spontaneous fission half-lives respectively. For theoretical comparison the alpha decay half-lives are also calculated using Coulomb and proximity potential model (CPPM), the Viola-Seaborg-Sobiczewski semi-empirical (VSS) relation, the universal (UNIV) curve of Poenaru et al., the analytical formula of Royer and the universal decay law (UDL) of Qi et al. Another tool used for the evaluation of spontaneous fission half-lives is the semi-empirical formula of Xu et al. The nuclei with alpha decay half-lives less than spontaneous fission half-lives will survive fission and hence decay through alpha emission. The predicted half lives and decay modes are compared with the available experimental results. The one-proton and two-proton separation energies of all the isotopes are calculated to find nuclei which lie beyond the proton drip line. Among 1119 even Z nuclei within the range 104 ≤ Z ≤ 136, 164 nuclei show sequential alpha emission followed by subsequent spontaneous fission. Since the isotopes decay through alpha decay chain and the half-lives are in measurable range, these isotopes are predicted to be synthesized and detected in laboratory via alpha decay. 2 nuclei will decay by alpha decay followed by proton emission, 54 nuclei show full alpha chains, 642 nuclei will decay through spontaneous fission, 166 nuclei exhibit proton decay and 91 isotopes are found to be stable against alpha decay. All the isotopes are tabulated according to their decay modes. The study is intended to enhance further experimental investigations in superheavy region.

Fission properties of superheavy nuclei for r -process calculations

Science.gov (United States)

Giuliani, Samuel A.; Martínez-Pinedo, Gabriel; Robledo, Luis M.

2018-03-01

We computed a new set of static fission properties suited for r -process calculations. The potential energy surfaces and collective inertias of 3640 nuclei in the superheavy region are obtained from self-consistent mean-field calculations using the Barcelona-Catania-Paris-Madrid energy density functional. The fission path is computed as a function of the quadrupole moment by minimizing the potential energy and exploring octupole and hexadecapole deformations. The spontaneous fission lifetimes are evaluated employing different schemes for the collective inertias and vibrational energy corrections. This allows us to explore the sensitivity of the lifetimes to those quantities together with the collective ground-state energy along the superheavy landscape. We computed neutron-induced stellar reaction rates relevant for r -process nucleosynthesis using the Hauser-Feshbach statistical approach and study the impact of collective inertias. The competition between different reaction channels including neutron-induced rates, spontaneous fission, and α decay is discussed for typical r -process conditions.

Q-value effects in the synthesis of superheavy elements

International Nuclear Information System (INIS)

Graeger, Reimar

2010-01-01

Superheavy elements (Z>or similar 104) only exist due to nuclear shell effects, which stabilize them against spontaneous fission (SF). Theoretical calculations predict these shell stabilization effects to reach a maximum at the closures of the next spherical proton and neutron shells, which are anticipated in the region between Z=114 and Z=126 and at N=184. More recent calculations, that also consider deformed nuclear shapes extended this picture and predicted deformed shell closures at Z=108 and at N=162, creating a region of enhanced stability around 270 Hs, confirmed in recent Hs chemistry experiments by measuring the decay of 270 Hs for the first time. Recently, the formation of deformed doubly-magic 270 Hs in the 4n evaporation channel in the fusion reactions 248 Cm( 26 Mg,4n), 244 Pu( 30 Si,4n), 238 U( 36 S,4n), and 226 Ra( 48 Ca,4n) was studied theoretically using a two-parameter Smoluchowski equation. Simple entrance channel arguments make compound nucleus (CN) formation appear favorable for systems with larger mass asymmetry. However, due to a lower reaction Q value, the reactions 238 U( 36 S,4n) 270 Hs and 226 Ra( 48 Ca,4n) 270 Hs are predicted to have higher cross sections compared to the reactions 248 Cm( 26 Mg,4n) 270 Hs and 244 Pu( 30 Si,4n) 270 Hs. The aim of the research done in the framework of this thesis was to study the influence of the reaction (B-Q)-value on the yield of SHE produced in nuclear fusion reactions. Therefore the most promising reactions 36 S+ 238 U and 48 Ca+ 226 Ra have been investigated and compared with the already measured reaction 26 Mg+ 248 Cm. The reaction 36 S+ 238 U was investigated at two beam energies. One correlated decay chain attributed to 270 Hs was found at E * =51 MeV resulting in a cross section of 0.8 -0.7 +2.6 pb. The reaction 48 Ca+ 226 Ra was investigated at three beam energies. Six correlated decay chains attributed to 270 Hs were detected at E * =40 MeV corresponding to a cross section of 8.3 -3.7 +6.7 pb

Critical angular momentum dependence of the fission barriers and the stability of superheavy nuclei

International Nuclear Information System (INIS)

Magda, M.T.; Sandulescu, A.

1978-10-01

Measured complete fusion and evaporation cross section data are used to determine the critical angular momenta for which the fission barriers are vanishing in the region of nuclei with Z = 102 - 116. It is shown that, in order to fit these data, larger values of the critical angular momenta are obtained for superheavy nuclei (Z = 110 - 112) than for heavy ones (Z = 102 - 107), which indicates a relatively higher stability against fission for superheavy nuclei, in agreement with the theoretically predicted island of stability. (author)

Gold–superheavy-element interaction in diatomics and cluster adducts: A combined four-component Dirac-Kohn-Sham/charge-displacement study

Energy Technology Data Exchange (ETDEWEB)

Rampino, Sergio, E-mail: srampino@thch.unipg.it; Belpassi, Leonardo, E-mail: leonardo.belpassi@cnr.it [Istituto di Scienze e Tecnologie Molecolari, Consiglio Nazionale delle Ricerche c/o Dipartimento di Chimica, Biologia e Biotecnologie, Università degli Studi di Perugia, Via Elce di Sotto 8, 06123 Perugia (Italy); Storchi, Loriano [Dipartimento di Farmacia, Università degli Studi “G. D’Annunzio,” Via dei Vestini 31, 66100 Chieti (Italy)

2015-07-14

The chemistry of superheavy elements (Z ≥ 104) is actively investigated in atom-at-a-time experiments of volatility through adsorption on gold surfaces. In this context, common guidelines for interpretation based on group trends in the periodic table should be used cautiously, because relativistic effects play a central role and may cause predictions to fall short. In this paper, we present an all-electron four-component Dirac-Kohn-Sham comparative study of the interaction of gold with Cn (Z = 112), Fl (Z = 114), and Uuo (Z = 118) versus their lighter homologues of the 6th period, Hg, Pb, and Rn plus the noble gas Xe. Calculations were carried out for Au–E (E = Hg, Cn, Pb, Fl, Xe, Rn, Uuo), Au{sub 7}– and Au{sub 20}–E (E = Hg, Cn, Pb, Fl, Rn) complexes, where Au{sub 7} (planar) and Au{sub 20} (pyramidal) are experimentally determined clusters having structures of increasing complexity. Results are analysed both in terms of the energetics of the complexes and of the electron charge rearrangement accompanying their formation. In line with the available experimental data, Cn and more markedly Fl are found to be less reactive than their lighter homologues. On the contrary, Uuo is found to be more reactive than Rn and Xe. Cn forms the weakest bond with the gold atom, compared to Fl and Uuo. The reactivity of Fl decreases with increasing gold-fragment size more rapidly than that of Cn and, as a consequence, the order of the reactivity of these two elements is inverted upon reaching the Au{sub 20}-cluster adduct. Density difference maps between adducts and fragments reveal similarities in the behaviour of Cn and Xe, and in that of Uuo and the more reactive species Hg and Pb. These findings are given a quantitative ground via charge-displacement analysis.

French contribution to the super-heavy nuclei discovery

International Nuclear Information System (INIS)

Nifenecker, H.; Asghar, M.

1999-01-01

The research on super-heavy nuclei is a science in full operation for which the Berkeley physicist give proof of perseverance. The author wonders about the french absence in this domain. He recalls the strategical decisions concerning the research programs of the period and gives outline of the future with the interest of the ECR (Electronic Cyclotron Resonance) sources. (A.L.B.)

Microstructure Evolution and Surface Cracking Behavior of Superheavy Forgings during Hot Forging

Directory of Open Access Journals (Sweden)

Zhenhua Wang

2018-01-01

Full Text Available In recent years, superheavy forgings that are manufactured from 600 t grade ingots have been applied in the latest generation of nuclear power plants to provide good safety. However, component production is pushing the limits of the current free-forging industry. Large initial grain sizes and a low strain rate are the main factors that contribute to the deformation of superheavy forgings during forging. In this study, 18Mn18Cr0.6N steel with a coarse grain structure was selected as a model material. Hot compression and hot tension tests were conducted at a strain rate of 10−4·s−1. The essential nucleation mechanism of the dynamic recrystallization involved low-angle grain boundary formation and subgrain rotation, which was independent of the original high-angle grain boundary bulging and the presence of twins. Twins were formed during the growth of dynamic recrystallization grains. The grain refinement was not obvious at 1150°C. A lowering of the deformation temperature to 1050°C resulted in a fine grain structure; however, the stress increased significantly. Crack-propagation paths included high-angle grain boundaries, twin boundaries, and the insides of grains, in that order. For superheavy forging, the ingot should have a larger height and a smaller diameter.

Superheavy nuclei and quasi-atoms produced in collisions of transuranium ions

International Nuclear Information System (INIS)

Zagrebaev, V.; Oganessian, Y.; Itkis, M.; Greiner, W.

2005-01-01

For near-barrier collisions of heavy nuclei it is very important to perform a combined (unified) analysis of all strongly coupled channels: deep-inelastic scattering, quasi-fission, fusion and regular fission. This ambitious goal has now become possible within our new approach. The standard (most important) degrees of freedom are used and a unified potential energy surface is derived determining evolution of the nuclear system in all the channels. This potential has also appropriate values of the Coulomb barriers in the entrance channel and proper values of the fission barriers in the exit one. A unified set of dynamic Langevin type equations is proposed for the simultaneous description of DI and fusion-fission processes including nucleon transfer at all reaction stages. For the first time, the whole evolution of the heavy nuclear system can be traced starting from the approaching stage and ending in DI, QF, and/or fusion-fission channels. The calculated mass, charge, energy and angular distributions of the reaction products agree well with available experimental data. Satisfactory agreement of the first calculations with experiments gives us hope not only to obtain rather accurate predictions for the probabilities of superheavy element formation in near-barrier fusion reactions but also to clarify much better than before the mechanisms of quasi-fission and fusion-fission processes. Also the determination of such fundamental characteristics of nuclear dynamics as the nuclear viscosity and the nucleon transfer rate is now possible. Low energy collisions of very heavy nuclei ( 238 U+ 238 U, 232 Th+ 250 Cf and 238 U + 248 Cm) have been studied within the proposed dynamical model. The multidimensional potential energy surfaces of such systems are rather complicated due to the shell effects and dynamic deformations, even if there is no distinct potential pocket. We found that at low near barrier collision energies these very heavy nuclei, after touching their surfaces

Decay properties of {sup 256-339}Ds superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Santhosh, K.P.; Nithya, C. [Kannur University, School of Pure and Applied Physics, Payyanur, Kerala (India)

2017-09-15

The decay properties of 84 isotopes of darmstadtium superheavy nuclei (Z = 110) have been studied using various theoretical models. The proton emission half-lives, the alpha decay half-lives, the spontaneous fission half-lives and the cluster decay half-lives of all the isotopes are evaluated. The one-proton emission half-lives and the alpha decay half-lives are predicted using the Coulomb and proximity potential model for deformed nuclei (CPPMDN). The calculated alpha half-lives are compared with the available experimental results as well as with the predictions of other theoretical models. The predicted half-lives matches well with the experimental results. The one-proton half-lives are also compared with the predictions using other formalisms. The shell-effect-dependent formula of Santhosh et al. has been employed for calculating the spontaneous fission half-lives. A theoretical comparison of spontaneous fission half-lives with four different formalisms is performed. By comparing the one-proton emission half-lives, the alpha decay half-lives and the spontaneous fission half-lives decay modes are predicted for all the isotopes of Ds. It is seen that the isotopes within the range 256 ≤ A ≤ 263 and 279 ≤ A ≤ 339 decay through spontaneous fission and the isotopes 264 ≤ A ≤ 278 exhibit alpha decay. Cluster decay half-lives are calculated using different models including the Coulomb and proximity potential (CPPM), for determining the magicities in the superheavy region. The effect of magicity at N = 184 and N = 202 were confirmed from the plot of log{sub 10}T{sub 1/2} versus neutron number of the daughter nuclei for the emission of different clusters. We hope that the systematic and detailed study of all the possible decay modes of {sup 256-339}Ds using various theoretical models will be helpful in the experimental identification of the isotopes of the element in the future. (orig.)

Development of a novel heavy element chemistry apparatus using the RIKEN gas-field recoil separator as a pre-separator

International Nuclear Information System (INIS)

Haba, H.; Morita, K.; Enomoto, S.; Morimoto, K.; Kaji, D.; Nagame, Yuichiro

2004-01-01

A new system was developed, that supplied the super-heavy element separated physically as the former steps to the chemical analysis devices such as a gas or liquid chromatographs. The gas jet transportation device was newly set up on the edge of existing accelerator research facilities in the Institute of Physical and Chemical Research linac building (GARIS). To conduct the chemical separation experiment of a super-heavy element of 112 in future a radioactive isotope of mercury of light homology elements was manufactured with a gas jet uniting type online multi-tracer manufacturing device. The adsorption chromatograph experiment to the gold was performed using this system. (H. Katsuta)

On the Necessity of Using Element No.155 in the Chemical Physical Calculations: Again on the Upper Limit in the Periodic Table of Elements

Directory of Open Access Journals (Sweden)

Khazan A.

2010-10-01

Full Text Available It is shown how the properties of different elements of the Periodic System of Elements can be obtained using the properties of the theoretically predicted heaviest element No.155 (it draws the upper principal limit of the Table, behind which stable elements cannot exist. It is suggested how the properties of element No.155 can be used in the synthesis of superheavy elements. An analysis of nuclear reactions is also produced on the same basis.

Elements beyond uranium

International Nuclear Information System (INIS)

Seaborg, G.T.; Loveland, W.D.

1990-01-01

This book is the 12th volume in a series on transuranium elements. Varied techniques for production of these elements, the methods used in the identification, and the exquisitely refined microchemical techniques required to deal wth samples sometimes involving only a few atoms are described in detail. The chapter on synthesis of the new elements is liberally laced with reminiscences of the proud progenitors as well as the criteria for the discovery of a new chemical element. The authors lament that the superheavy elements (elements in the region of atomic number 114) still elude detection even though their creation should be possible, and some, at least, should survive long enough to be detected. One chapter in the book is devoted to practical applictions of uranium, and the transuranic elements

The mass (charge) spectrum of superheavy nuclei fission fragments: the new perspectives for the theory of nucleosynthesis

International Nuclear Information System (INIS)

Maslyuk, V.T.

2012-01-01

A new approach to the problem of nucleosynthesis based on assumption of a nuclear matter or superheavy nuclei series fragmentation up to atomic nuclei is proposed. It is shown that studies of the mass (charge) fragments yields (MCFY) after nuclear matter disintegration is possible within proposed statistical theory. The data of MCFY calculation for exotic superheavy nuclei multifragmentation with A=300, 900 and 1200 and arbitrary Z values are demonstrated

Competition between fusion and quasi-fission in heavy ion induced reactions

International Nuclear Information System (INIS)

Back, B.B.

1986-09-01

Quantitative analyses of angular distributions and angle-mass correlations have been applied to the U + Ca reaction to obtain upper limit estimates for the cross sections for complete fusion near or below the interaction barrier. Extrapolating to the systems Ca + Cm and Ca + Es using the well established scaling properties of the extra push model, an estimate of the cross sections relevant to the efforts of synthesizing super-heavy elements in the region Z = 116 and N = 184 via heavy-ion fusion reactions are obtained. A simple evaporation calculation using properties of the super heavy elements shows that the failure to observe super-heavy elements with the Ca + Cm reaction is consistent with estimates of the complete fusion process. 33 refs., 9 figs., 1 tab

Superheavy-element spectroscopy: Correlations along element 115 decay chains

Science.gov (United States)

Rudolph, D.; Forsberg, U.; Sarmiento, L. G.; Golubev, P.; Fahlander, C.

2016-05-01

Following a brief summary of the region of the heaviest atomic nuclei yet created in the laboratory, data on more than hundred α-decay chains associated with the production of element 115 are combined to investigate time and energy correlations along the observed decay chains. Several of these are analysed using a new method for statistical assessments of lifetimes in sets of decay chains.

The synthesis and decay properties of the heaviest elements

International Nuclear Information System (INIS)

Oganesyan, Yu.Ts.

2000-01-01

The synthesis and the study of radioactive properties of new elements is considered with respect to the existence of the 'islands of stability' of hypothetical superheavy elements predicted by the theory more than 35 years ago. Experimental data demonstrating an enhanced stability of nuclei in the vicinity of deformed shells with Z=108 and N=162 is discussed from the point of view of advent into more heavy and much more stable nuclides near the predicted spherical shells Z=114-122 and N=184 following after the doubly magic nucleus 208 Pb. The author presents the results of experiments on the synthesis of isotopes of elements 114 and 116 in the fusion reactions with 48 Ca. In these reactions the decay chains of heavy atoms consisting of sequential α-decays interrupted by spontaneous fission have been observed. The decay energies and probabilities are compared with predictions of different theoretical models describing the structure of heavy nuclei. The obtained results are considered as the first experimental evidence of the existence of domains of stability of superheavy nuclei which substantially extends the boundaries of existence of chemical elements

Proceedings of the workshop on the nuclear sciences of the heaviest elements

Energy Technology Data Exchange (ETDEWEB)

Nagame, Yuichiro; Haba, Hiromitsu; Ikezoe, Hiroshi [eds.

2000-03-01

The workshop on the nuclear sciences of the heaviest elements took place on July 21-22, 1999 at the Japan Atomic Energy Research Institute (JAERI), Tokai. Approximately 40 scientists and 15 graduate students participated in the workshop which was organized by the Advanced Science Research Center, JAERI. The successful syntheses of three new super-heavy elements in 1999, Z=114 at the Joint Institute for Nuclear Research in Dubna, Russia, and Z=118 (with Z=116 following from {alpha}-decay of Z=118) at the Lawrence Berkeley National Laboratory (LBNL) in USA, are tremendous progress in the field of the heavy element research. The 1st International Conference on the Chemistry and Physics of the Transactinide Elements (TAN99) was held in Germany from September 26 to 30, 1999 to discuss in a larger context all scientific aspects of the heaviest elements. Thus, it was timely to hold the present domestic workshop to summarize what has been done in recent years, to see what has come true, and to discuss the perspectives in the near feature. The subjects in the workshop were classified into; (1) synthesis of heavy elements, (2) decay properties of heavy nuclei, (3) chemistry of the heaviest elements, and (4) future plans of the heavy element research in Japan. This volume contains the papers presented in the workshop. The 14 papers are indexed individually. (J.P.N.)

Physics of superheavy dark matter in supergravity

Science.gov (United States)

Addazi, Andrea; Marciano, Antonino; Ketov, Sergei V.; Khlopov, Maxim Yu.

New trends in inflationary model building and dark matter production in supergravity are considered. Starobinsky inflation is embedded into 𝒩 = 1 supergravity, avoiding instability problems, when the inflaton belongs to a vector superfield associated with a U(1) gauge symmetry, instead of a chiral superfield. This gauge symmetry can be spontaneously broken by the super-Higgs mechanism resulting in a massive vector supermultiplet including the (real scalar) inflaton field. Both supersymmetry (SUSY) and the R-symmetry can also be spontaneously broken by the Polonyi mechanism at high scales close to the inflationary scale. In this case, Polonyi particles and gravitinos become superheavy, and can be copiously produced during inflation by the Schwinger mechanism sourced by the universe expansion. The Polonyi mass slightly exceeds twice the gravitino mass, so that Polonyi particles are unstable and decay into gravitinos. Considering the mechanisms of superheavy gravitino production, we find that the right amount of cold dark matter composed of gravitinos can be achieved. In our scenario, the parameter space of the inflaton potential is directly related to the dark matter one, providing a new unifying framework of inflation and dark matter genesis. A multi-superfield extension of the supergravity framework with a single (inflaton) superfield can result in a formation of primordial nonlinear structures like mini- and stellar-mass black holes, primordial nongaussianity, and the running spectral index of density fluctuations. This framework can be embedded into the SUSY GUTs inspired by heterotic string compactifications on Calabi-Yau three-folds, thus unifying particle physics with quantum gravity.

How far are we on the way to the superheavy nuclei?

International Nuclear Information System (INIS)

Muenzenberg, G.

1989-10-01

The discovery of the elements 107, 108, and 109 in a region of dominating shell stabilization is the most important step on the way to the superheavy nuclei in recent years. These experiments leading to the presently upper end of the periodic table were possible with the velocity filter SHIP to separate the heavy nuclei produced in complete fusion reactions of heavy ions. The identification of the unknown nuclei was established by α-α mother-daughter correlation of the nuclei decaying after the implantation into position sensitive surface-barrier detectors. With this method it is possible to identify even single nuclei of unknown isotopes unambiguously. The limits of sensitivity are production cross-sections of a few picobarns and about 2 μs of nuclear lifetime. With this method the elements 107, 108, and 109 were observed for the first time by their α-decay and identified unambiguously. For element 107 the isotopes with masses 261 and 262, for the element 108 the isotopes with masses 264 and 265, and for element 109 the isotope with mass 266 were found. The halflives range from 0.1 ms to 0.1 s. The highly fissile transactinide nuclei were produced in cold fusion of heavy ions using 207,208 Pb and 209 Bi targets, respectively, and 50 Ti, 54 Cr, or 58 Fe beams. The evaluation of the excitation functions for the production of very heavy evaporation residues shows a strong decrease above 25 MeV excitation energy caused by a destruction of the groundstate shell effects at high excitation energies. The strong competition of barrier transmission and survival probability results in rather narrow excitation functions and small production cross sections. The maximum cross section is observed close to the Coulomb barrier and corresponding to projectile energies near 5 MeV/u. (orig.) [de

My journey to the superheavy island with Szymanski, Nilsson, Nix, and Swiatecki from Lysekil to the present

International Nuclear Information System (INIS)

Mueller, Peter

2010-01-01

We discuss the great theoretical insights on nuclear stability that emerged in the late 1960s, especially the realization that observable nuclei might include a superheavy island 20+ protons beyond uranium with 92 protons. However, we now realize that the early models were not sufficiently quantitative to yield definite conclusions. Further groundwork for such models was laid in the 1970s. Around 1980 more quantitative, global and universal models appeared and together with experimental advances the mapping of the superheavy island, or as it turns out now, continent started in earnest. We review these early developments and conclude with some examples of our current insights. In particular, 1) some theoretical models do have predictive capabilities for nuclear properties such as ground-state masses, shapes, and half-lives 10 or more neutrons and protons away from previously known regions and 2) the superheavy island may be a continent connected to the actinides by a narrow land bridge; the continent itself may extend from about proton number Z = 110 to Z = 120 or slightly beyond. (author)

Swimming back from the superheavy island

International Nuclear Information System (INIS)

Draculis, G.

1999-01-01

What's next in the series 108, 109, 110, 111, 112?The answer a couple of years ago looked like being not much. But major ripples are spreading in the Nuclear Physics community as news of the recent discoveries of the Superheavy element Z=118 and its daughters Z=116 and Z=114 was announced by a Berkeley group led by Victor Ninov [1]. Several pieces of news about Z=114 from studies at Dubna promoted by Yuri Oganessian [2,3] were circulating at about the same time.The 'not much' answer was because increasingly heroic efforts seemed to be needed to produce and identify each heavier element in the series. The problem is that such nuclei, if they exist in a stable or quasi-stable form are prone to fission, and so are any nuclei one might conceive as making to provide a path to one's nucleus of choice. The favoured reaction process used to make them is heavy-ion fusion which involves bombarding target nuclei of 208 PB (proton number Z=82), 238 U (Z=92) or even 244 Pu (Z=94) with medium weight (and relatively neutron-rich) beams such as 48 Ca (Z=20) and 86 Kr (Z=36) nuclei, accelerated to energies near or just above the Coulomb barrier, with the hope of the two nuclei overlapping and combining because of the highly attractive (strong) nuclear force. The catch is that putting sufficient energy in to get the nuclei together leaves the compound nucleus with excitation energy and spin, which dramatically increase its probability to fission, and therefore not survive further. As you go lower in beam energy, the probability for the initial fusion drops precipitously since the nuclei have to tunnel through a potential barrier caused by the repulsive Coulomb force between the nuclear charges, in order to make contact. Somewhere between the dramatically falling probability for fusion and steeply increasing probability for fission might be a window of production and survival

The synthesis of superheavy nuclei in the 48Ca + 244Pu reaction

International Nuclear Information System (INIS)

Oganesyan, Yu.Ts.; Utenkov, V.K.; Lobanov, Yu.V.

1999-01-01

In the bombardment of a 244 Pu target with 48 Ca ions, we observed a decay sequence consisting of an implanted heavy atom, three subsequent α-decays, and a spontaneous fission, all correlated in time and position. The measured α-energies and corresponding time intervals were: E α = 9.71 MeV (Δt = 30.4 s), 8.67 MeV (Δt = 15.4 min) and 8.83 MeV (Δt = 1.6 min); for the spontaneous fission (Δt = 16.5 min) the total deposited energy was approximately 190 MeV. The large alpha-particle energies together with the long decay times and spontaneous fission terminating the chain offer evidence of the decay of nuclei with high atomic numbers. This decay chain is a good candidate for originating from the α-decay of the parent nucleus 289 114, produced in the 3n-evaporation channel with a cross section of about 1 pb. The significant increase in the lifetimes of the new Z = 112 and 110 daughters of the Z = 114 nuclide (by a factor of ∼ 10 6 ) with respect to the known heaviest isotopes of elements 112 and 110 can be considered as a direct proof of the existence of the 'island of stability' of superheavy elements

On the synthesis of new elements

International Nuclear Information System (INIS)

Hofmann, S.

2003-01-01

The nuclear shell model predicts that the next doubly magic shell-closure beyond 208 Pb is at a proton number between Z=114 and 126 and at a neutron number N=172 or 184. The outstanding aim of experimental investigations is the exploration of this region of spherical 'Superheavy Elements'. This article describes the experiments that were performed recently at the GSI SHIP. They resulted in an unambiguous identification of elements 110 to 112. They were negative so far in searching for elements 113, 116, and 118. The measured decay data are compared with theoretical predictions. Some aspects concerning the reaction mechanism are also presented. (orig.)

Era of superheavy-particle dominance and big bang nucleosynthesis

Energy Technology Data Exchange (ETDEWEB)

Polnarev, A.G.; Khlopov, M.Y.

1982-01-01

The observed primordial He/sup 4/ abundance imposes astrophysical constraints on the possible departures from radiation dominance in the big bang universe during the neutron hardening era (at epoch t roughly-equal1 sec). Limits are obtained which, along with the data on the spectrum of the cosmic background radiation, practically rule out any stages of superheavy stable-particle dominance in the era 1< or approx. =t<10/sup 10/ sec, thereby setting restrictions on current elementary-particle theories.

Alpha Decay of Even-Even Superheavy Nuclei

International Nuclear Information System (INIS)

Oudih, M.R.; Hamza, Y.; Fellah, M.; Allal, N.H.; Fellah, M.; Allal, N.H.

2011-01-01

Alpha decay properties of even-even superheavy nuclei with 112.Z.120 have been investigated using the Hartree-Fock-Bogoliubov approach. The method is based on the SkP Skyrme interaction and the Lipkin-Nogami prescription for treating the pairing correlations. The alpha decay energies are extracted from the binding energies and then used for the calculation of the decay half-lives using a formula similar to that of Viola-Seaborg. The parameters of the formula were obtained through a least square fit to even-even heavy nuclei taken from the tables of Audi- Wapstra and some more recent references. The results are compared with other theoretical evaluations.

Actinide collisions for QED and superheavy elements with the time-dependent Hartree-Fock theory and the Balian-Vénéroni variational principle

Directory of Open Access Journals (Sweden)

Kedziora David J.

2011-10-01

Full Text Available Collisions of actinide nuclei form, during very short times of few zs (10−21 s, the heaviest ensembles of interacting nucleons available on Earth. Such collisions are used to produce super-strong electric fields by the huge number of interacting protons to test spontaneous positron-electron pair emission (vacuum decay predicted by the quantum electrodynamics (QED theory. Multi-nucleon transfer in actinide collisions could also be used as an alternative way to fusion in order to produce neutron-rich heavy and superheavy elements thanks to inverse quasifission mechanisms. Actinide collisions are studied in a dynamical quantum microscopic approach. The three-dimensional time-dependent Hartree-Fock (TDHF code tdhf3d is used with a full Skyrme energy density functional to investigate the time evolution of expectation values of one-body operators, such as fragment position and particle number. This code is also used to compute the dispersion of the particle numbers (e.g., widths of fragment mass and charge distributions from TDHF transfer probabilities, on the one hand, and using the BalianVeneroni variational principle, on the other hand. A first application to test QED is discussed. Collision times in 238U+238U are computed to determine the optimum energy for the observation of the vacuum decay. It is shown that the initial orientation strongly affects the collision times and reaction mechanism. The highest collision times predicted by TDHF in this reaction are of the order of ~ 4 zs at a center of mass energy of 1200 MeV. According to modern calculations based on the Dirac equation, the collision times at Ecm > 1 GeV are sufficient to allow spontaneous electron-positron pair emission from QED vacuum decay, in case of bare uranium ion collision. A second application of actinide collisions to produce neutron-rich transfermiums is discussed. A new inverse quasifission mechanism associated to a specific orientation of the nuclei is proposed to

Ways to synthesize and study the properties of SHE

International Nuclear Information System (INIS)

Oganessian, Y.

2005-01-01

The reactions for the superheavy nucleus synthesis are considered. Proceeding from the results obtained in reactions of cold fusion with 208 Pb and 209 Bi targets and those of hot fusion with 48 Ca ions, the feasibility of using the reactions with ions (A≥50) is considered. Estimates of the formation of heavy nuclei and superheavy nuclei with large neutron excess in the reactions of quasi-fission and inverse fission reactions are presented. Experiments with 136 Xe and 238 U ion beams may give some idea on the SHE cross sections in the reactions of this type. It is shown that an increase in the intensity of 48 Ca ion beams at the set-ups of the MASHA type open possibilities for γ-spectroscopy of the superheavy nuclides

Stability of superheavy nuclei

Science.gov (United States)

Pomorski, K.; Nerlo-Pomorska, B.; Bartel, J.; Schmitt, C.

2018-03-01

The potential-energy surfaces of an extended set of heavy and superheavy even-even nuclei with 92 ≤Z ≤126 and isospins 40 ≤N -Z ≤74 are evaluated within the recently developed Fourier shape parametrization. Ground-state and decay properties are studied for 324 different even-even isotopes in a four-dimensional deformation space, defined by nonaxiality, quadrupole, octupole, and hexadecapole degrees of freedom. Nuclear deformation energies are evaluated in the framework of the macroscopic-microscopic approach, with the Lublin-Strasbourg drop model and a Yukawa-folded mean-field potential. The evolution of the ground-state equilibrium shape (and possible isomeric, metastable states) is studied as a function of Z and N . α -decay Q values and half-lives, as well as fission-barrier heights, are deduced. In order to understand the transition from asymmetric to symmetric fission along the Fm isotopic chain, the properties of all identified fission paths are investigated. Good agreement is found with experimental data wherever available. New interesting features about the population of different fission modes for nuclei beyond Fm are predicted.

Transfer reaction studies in the region of heavy and superheavy nuclei at SHIP

Energy Technology Data Exchange (ETDEWEB)

Heinz, S; Comas, V; Hofmann, S; Ackermann, D; Heredia, J; Hessberger, F P; Khuyagbaatar, J; Kindler, B; Lommel, B; Mann, R, E-mail: s.heinz@gsi.de [GSI Helmholtzzentrum fuer Schwerionenforschung GmbH, 64291 Darmstadt (Germany)

2011-02-01

We studied multi-nucleon transfer reactions in the region of heavy and superheavy nuclei. The goal was to investigate these reactions as possibility to create new superheavy neutron-rich isotopes, which cannot be produced in fusion reactions. The experiments have been performed at the velocity filter SHIP at GSI. At SHIP we can detect and identify the heavy, target-like, transfer products. Due to the low background at the focal plane detector and the isotope identification via radioactive decays, the setup allows to reach an upper cross-section limit of 10 pb/sr within one day of beamtime. We investigated the systems {sup 58,64}Ni + {sup 207}Pb and {sup 48}Ca + {sup 248}Cm at beam energies below and up to 20% above the Coulomb barrier. At all energies we observed a massive transfer of protons and neutrons, where transfer products with up to eight neutrons more than the target nucleus could be identified.

Approach synthesis of superheavy nuclei from some aspects of cross section calculations

International Nuclear Information System (INIS)

Liu Zuhua

2003-01-01

Several important aspects in the cross section calculations for the synthesis of superheavy nuclei have been inquired. They are the effects of the coupled-channels, the damping of shell correction energy, the collective enhancements in the level density and the spin distributions of evaporation residues. The channel coupling of relative motion with internal degrees of freedom will enhance significantly the capture cross section at sub-barrier energies. However, recent measurements of spin distributions for the survived compound nucleus show that only low partial waves contribute to the evaporation residues, which should at least partially cancel out the enhancement due to the effects of the channel coupling. The fission barriers are determined mainly by the shell correction energy in the case of superheavy nuclei. Therefore, it is especially important to determine as accurate as possible the damping parameter which describes the decrease of the shell effects influence. In addition, the collective enhancement factor in the level density also plays a very important role in the synthesis of heavy spherical nuclei

Superheavy Nuclei in the Quark-Meson-Coupling Model

Directory of Open Access Journals (Sweden)

Stone Jirina

2017-01-01

Full Text Available We present a selection of the first results obtained in a comprehensive calculation of ground state properties of even-even superheavy nuclei in the region of 96 < Z < 136 and 118 < N < 320 from the Quark-Meson-Coupling model (QMC. Ground state binding energies, the neutron and proton number dependence of quadrupole deformations and Qα values are reported for even-even nuclei with 100 < Z < 136 and compared with available experimental data and predictions of macro-microscopic models. Predictions of properties of nuclei, including Qα values, relevant for planning future experiments are presented.

Frontiers of heavy-ion physics and superheavy elements

International Nuclear Information System (INIS)

Muenzenberg, Gottfried

2002-01-01

This contribution will focus on three topics of GSI nuclear structure research: super heavy elements, direct mass measurements in the storage ring, and the measurement of spallation cross section in reversed kinematics. The GSI project for an extended synchrotron facility will be outlined. (author)

The synthesis of the deformed superheavy elements 107 to 111

International Nuclear Information System (INIS)

Armbuster, P.

1995-01-01

By inflight separation, implantation into Si-detector arrays, and correlation analysis of subsequent α-decay chains many isotopes were discovered at GSI since 1980, among others the elements Nielsbohriurn, Hassium and Meitnerium. The sensitivity of the method allows to identify an element by one decay chain, as we demonstrated for the case of 266 Mt. After a break of our work during the time when the new accelerator system SIS-FRS-ESR was installed (1989-1993) at GSI, and many improvements of our system EZR-UNILAC-SHIP accomplished, we restarted element synthesis in 1994. The synthesis of the isotopes 269 110, 271 110, and 272 111 of the new elements Z--110 and Z=l11 was a first success at the end of 1994. This discovery is in the center of this presentation. The reaction mechanism, a one-step, cold and compact rearrangement process at a level of some 10 -36 cm 2 is discussed. Cross sections and excitation functions systematically studied allow to extrapolate to the next element Z=112, which seems not to be out of reach

Synthesis and properties of neutron deficient isotopes of elements around Z=100

International Nuclear Information System (INIS)

Antalic, S.

2005-01-01

In the presented Thesis work the results of spectroscopic studies of 246 Md, 247 Md, 254 Lr and 255 Lr decay chains are given. These isotopes were produced using heavy ion induced fusion reactions of 40 Ar + 209 Bi and 48 Ca + 209 Bi as a part of the long term project aimed to study spectroscopy properties of superheavy elements. The experiments were performed at velocity filter SHIP, placed at the central beam line of the UNILAC accelerator at GSI Darmstadt in Germany. The work also gives a basic overview of research in the region of superheavy elements, description of the used experimental setup and shows the usual analysis methods used in spectroscopic studies in the region of elements around Z ∼ 100. The results were obtained using α, α - γ spectroscopy methods and recoil - α, α - α correlations search. Although these isotopes have been known for a longer time, no detailed spectroscopy investigation were performed so far and only rough information was known. Beside the improved precision of known data, this work gives a new information about the decay properties of these isotopes. This give us the possibility to build a decay schemes for mentioned decay chains. (author)

Synthesis of neutron-rich transuranic nuclei in fissile spallation targets

OpenAIRE

Mishustin, Igor; Malyshkin, Yury; Pshenichnov, Igor; Greiner, Walter

2014-01-01

A possibility of synthesizing neutron-reach super-heavy elements in spallation targets of Accelerator Driven Systems (ADS) is considered. A dedicated software called Nuclide Composition Dynamics (NuCoD) was developed to model the evolution of isotope composition in the targets during a long-time irradiation by intense proton and deuteron beams. Simulation results show that transuranic elements up to Bk-249 can be produced in multiple neutron capture reactions in macroscopic quantities. Howeve...

Seal coat damage evaluation due to superheavy load moves based on a mechanistic-empirical approach.

Science.gov (United States)

2010-03-01

The number of superheavy load (SHL) moves has increased drastically within the past 5 years in : Texas. Along with the increasing SHL moves, the Texas Department of Transportation (TxDOT) has : become increasingly aware of the rising concerns associa...

Neutrino masses and superheavy dark matter in the 3-3-1-1 model

Energy Technology Data Exchange (ETDEWEB)

Huong, D.T.; Dong, P.V. [Vietnam Academy of Science and Technology, Institute of Physics, Hanoi (Viet Nam)

2017-04-15

In this work, we interpret the 3-3-1-1 model when the B - L and 3-3-1 breaking scales behave simultaneously as the inflation scale. This setup not only realizes the previously achieved consequences of inflation and leptogenesis, but also provides new insights in superheavy dark matter and neutrino masses. We argue that the 3-3-1-1 model can incorporate a scalar sextet, which induces both small masses for the neutrinos via a combined type I and II seesaw and large masses for the new neutral fermions. Additionally, all the new particles have large masses in the inflation scale. The lightest particle among the W-particles that have abnormal (i.e., wrong) B - L number in comparison to those of the standard model particles may be superheavy dark matter as it is stabilized by W-parity. The dark matter candidate may be a Majorana fermion, a neutral scalar, or a neutral gauge boson, which was properly created in the early universe due to gravitational effects on the vacuum or thermal production after cosmic inflation. (orig.)

On the fate of superheavy magnetic monopoles in a neutron star

International Nuclear Information System (INIS)

Kuzmin, V.A.; Rubakov, V.A.; AN SSSR, Moscow. Inst. Yadernykh Issledovanij)

1983-02-01

We propose two possible scenarios of the behaviour of superheavy magnetic monopoles in a neutron star, in which the monopole-antimonopole annihilation rate is sufficiently large to prevent the enormous heating of a neutron star due to the monopole induced neutron decays. We find that the galactic monopole flux of order 10 -16 cm -2 s -1 ster -1 can be compatible with the observational limit on the X-ray luminosity of neutron stars. (author)

Predictions on the modes of decay of odd Z superheavy isotopes within the range 105 ≤ Z ≤ 135

Science.gov (United States)

Santhosh, K. P.; Nithya, C.

2018-05-01

The decay modes of 1051 odd Z superheavy nuclei within the range 105 ≤ Z ≤ 135, and their daughter nuclei are studied by comparing the alpha decay half-lives with the spontaneous fission half-lives. The alpha decay half-lives are calculated using the Coulomb and proximity potential model for deformed nuclei (CPPMDN) proposed by Santhosh et al. (2011) and the spontaneous fission half-lives are obtained with the shell-effect dependent formula of Santhosh et al. (Santhosh and Nithya, 2016). For a theoretical comparison, the alpha decay half-lives are also computed with the Coulomb and proximity potential model (CPPM), Viola-Seaborg-Sobiczewski semi-empirical relation (VSS), Universal curve of Poenaru et al. (UNIV), the analytical formula of Royer, and the Universal decay law of Qi et al. (UDL). The predicted decay modes and half-lives were compared with the available experimental results. The proton and neutron separation energies are calculated to identify those nuclei, which decay through proton and neutron emission. From the entire study of odd Z superheavy elements, it is seen that among 1051 nuclei, 233 nuclei exhibit proton emission and 18 nuclei exhibit neutron emission. 56 nuclei are stable against alpha decay with negative Q value for the decay. 92 nuclei show alpha decay followed by spontaneous fission and 9 nuclei show alpha decay followed by proton emission. 39 nuclei decay through full alpha chain and 595 nuclei decay through spontaneous fission. We hope that the study will be very useful for the future experimental investigations in this field.

α decay chains in 271-294115 superheavy nuclei

International Nuclear Information System (INIS)

Santhosh, K. P.; Priyanka, B.; Joseph, Jayesh George; Sahadevan, Sabina

2011-01-01

α decay of 271-294 115 superheavy nuclei is studied using the Coulomb and proximity potential model for deformed nuclei (CPPMDN). The predicted α half-lives of 287 115 and 288 115 nuclei and their decay products are in good agreement with experimental values. Comparison of α and spontaneous fission half-lives predicts four-α chains and three-α chains, respectively, from 287 115 and 288 115 nuclei and are in agreement with experimental observation. Our study predicts two-α chains from 273,274,289 115, three-α chains from 275 115, and four-α chains consistently from 284,285,286 115 nuclei. These observations will be useful for further experimental investigation in this region.

True ternary fission and quasifission of superheavy nuclear systems

Directory of Open Access Journals (Sweden)

Greiner Walter

2011-10-01

Full Text Available We found that a true ternary fission with formation of a heavy third fragment (a new kind of radioactivity is quite possible for superheavy nuclei due to the strong shell effects leading to a three-body clusterization with the two doubly magic tin-like cores. The three-body quasifission process could be even more pronounced for giant nuclear systems formed in collisions of heavy actinide nuclei. In this case a three-body clusterization might be proved experimentally by detection of two coincident lead-like fragments in low-energy U+U collisions.

Chemistry of the actinide elements. Second edition

International Nuclear Information System (INIS)

Katz, J.J.; Seaborg, G.T.; Morss, L.R.

1987-01-01

This is an exhaustive, updated discourse on the chemistry of Actinides, Volume 1 contains a systematic coverage of the elements Ac, Th, Pa, U, Np, and Pu, which constitutes Part 1 of the work. The characterization of each element is discussed in terms of its nuclear properties, occurrence, preparation, atomic and metallic properties, chemistry of specific compounds, and solution chemistry. The first part of Volume 2 follows the same format as Volume 1 but is confined to the elements Am, Cm, Bk, Cf, and Es, plus a more condensed coverage of the Transeinsteinium elements (Fm, Md, No, Lw, and 104-109). Part 2 of this volume is devoted to a discussion of the actinide elements in general, with a specific focus on electronic spectra, thermodynamic and magnetic properties, the metallic state, structural chemistry, solution kinetics, organometallic chemistry for σ- and π-bonded compounds, and some concluding remarks on the superheavy elements

Contributions to the theory of alpha disintegration of heavy and superheavy nuclei

International Nuclear Information System (INIS)

Tarnoveanu, G.I.

1977-01-01

Alpha disintegration of heavy and super-heavy spherical nuclei is studied. When the new calculation technique for alpha intensities dependent on the shell-model has been applied, a technique which allows the use of a more complex structure of the alpha particle, the detailed calculation of the alpha half-times is performed for both radioactive alpha nuclei in the lead area and for the super-heavy nuclei, by using the R matrix theory of alpha disintegration independent of the channel radius. The relative values of overlap integrals calculated by means of the intrinsic function for the Gauss and Moshinsky type alpha particle are presented, as well as a comparison between them and the experiment values for 8.6, 9.00 and 9.6 fm channel radii in the case of Po, Ra, Rn and Th isotopes. Original contributions to the alpha disintegration theory are represented by the generalization of the Taylor series method expressing the transformations to the centre of mass, and the relative distance from two particles to four particles in the same harmonic oscillator potential, and by the development of the R matrix theory for alpha disintegration independent of the channel radius in the case of complex structured alpha particles. (author)

Toward an accurate description of solid-state properties of superheavy elements

Directory of Open Access Journals (Sweden)

Schwerdtfeger Peter

2016-01-01

Full Text Available In the last two decades cold and hot fusion experiments lead to the production of new elements for the Periodic Table up to nuclear charge 118. Recent developments in relativistic quantum theory have made it possible to obtain accurate electronic properties for the trans-actinide elements with the aim to predict their potential chemical and physical behaviour. Here we report on first results of solid-state calculations for Og (element 118 to support future atom-at-a-time gas-phase adsorption experiments on surfaces such as gold or quartz.

Model Experiments on Chemical Properties of Superheavy Elements in Aqueous Solutions

CERN Document Server

Szeglowski, Z

2003-01-01

This paper presents a brief review of model experiments on investigation of chemical properties of transactinide elements, ranging from 104 to 116. The possibilities of isolation of the nuclei of these elements from nuclear reaction products, using the ion-exchange method, are also considered.

Synthesis of the New Element with Z=117

International Nuclear Information System (INIS)

Hamilton, J H; Ramayya, A V; Oganessian, Yu Ts; Abdullin, F Sh; Dmitriev, S N; Itkis, M G; Lobanov, Yu V; Mezentsev, A N; Polyakov, A N; Bailey, P D; Benker, D; Ezold, J; Porter, C E; Riley, F; Roberto, J B; Bennett, M E; Henderson, R A; Moody, K J; Nelson, S L; Ryabinin, M A

2011-01-01

The synthesis of the new chemical element with atomic number Z=117 is presented. The isotopes 293 117 and 294 117were produced in fusion reactions between 48 Ca and 249 Bk. The 249 Bk was produced in the High Flux Isotope Reactor and chemically separated at Oak Ridge. Decay chains involving eleven new nuclei were identified by means of the Dubna Gas Filled Recoil Separator. The measured decay properties show a strong rise of stability for super-heavy nuclei toward N=184.

Toward the drip lines and the superheavy island of stability with the Super Separator Spectrometer S{sup 3}

Energy Technology Data Exchange (ETDEWEB)

Dechery, F.; Boutin, D.; Gall, B.; Le Blanc, F. [Universite de Strasbourg, IPHC, Strasbourg (France); CNRS, UMR7178, Strasbourg (France); Drouart, A.; Authier, M.; Delferriere, O.; Payet, J.; Uriot, D. [CEA-Saclay, Irfu, Gif-sur-Yvette (France); Savajols, H.; Stodel, M.H.; Traykov, E. [GANIL, Caen (France); Nolen, J. [Argonne National Laboratory, Argonne, IL (United States); Amthor, A.M. [Bucknell University, Lewisburg, PA (United States); Hue, A.; Laune, B. [Universite Paris-Sud 11, CNRS/IN2P3, IPNO, Orsay (France); Manikonda, S. [AML Superconductivity and Magnetics, Palm Bay, Florida (United States); Collaboration: S3 Collaboration

2015-06-15

The Super Separator Spectrometer S{sup 3} is a major experimental system developed for SPIRAL2. It has been designed for physics experiments with very low cross sections by taking full advantage of the very high intensity stable beams to be produced by LINAG, the superconducting linear accelerator at GANIL. These intensities will open new opportunities in several physics domains using fusion evaporation reactions, principally: super-heavy and very heavy element properties, spectroscopy at and beyond the dripline, and isomer and ground-state properties. The common feature of these experiments is the requirement to separate very rare events from intense backgrounds. S{sup 3} accomplishes this with a large acceptance, a high background rejection efficiency, and a physical mass separation. This article will present the technical specifications and optical constraints needed to achieve these physical goals. The optical layout of the spectrometer will be presented, focusing on technical elements of the target system, the superconducting multipole magnets used to correct high-order optical aberrations, the electric and magnetic dipoles, and the open multipole triplet used for primary beam rejection. The expected system performance will be presented for three experimental cases using 3 specific optical modes of the spectrometer. (orig.)

Charge-exchange resonances and restoration of Wigner’s supersymmetry in heavy and superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Lutostansky, Yu. S., E-mail: lutostansky@yandex.ru; Tikhonov, V. N. [National Research Center Kurchatov Institute (Russian Federation)

2016-11-15

Various facets of the question of whether Wigner’s supersymmetry [SU(4) symmetry] may be restored in heavy and superheavy nuclei are analyzed on the basis of a comparison of the results of calculations with experimental data. The energy difference between the giant Gamow–Teller resonance and the analog resonance (the difference of E{sub G} and E{sub A}) according to calculations based on the theory of finite Fermi systems is presented for the case of 33 nuclei for which experimental data are available. The calculated difference ΔE{sub G–A} of E{sub G} and E{sub A} tends to zero in heavier nuclei, showing evidence of the restoration of Wigner’s SU(4) symmetry. Also, the isotopic dependence of the Coulomb energy difference between neighboring isobaric nuclei is analyzed within the SU(4) approach for more than 400 nuclei in the mass-number range of A = 5–244. The restoration of Wigner’s SU(4) symmetry in heavy nuclei is confirmed. It is shown that the restoration of SU(4) symmetry is compatible with the possible existence of the stability island in the region of superheavy nuclei.

Production of the superheavy baryon Λ{sub c} {sub anti} {sub c}{sup *}(4209) in kaon-induced reaction

Energy Technology Data Exchange (ETDEWEB)

Wang, Xiao-Yun [Chinese Academy of Sciences, Institute of Modern Physics, Lanzhou (China); University of Chinese Academy of Sciences, Beijing (China); Institute of Modern Physics of CAS and Lanzhou University, Research Center for Hadron and CSR Physics, Lanzhou (China); Chen, Xu-Rong [Chinese Academy of Sciences, Institute of Modern Physics, Lanzhou (China); Institute of Modern Physics of CAS and Lanzhou University, Research Center for Hadron and CSR Physics, Lanzhou (China)

2015-07-15

The production of superheavy Λ{sub c} {sub anti} {sub c}{sup *}(4209) baryon in the K{sup -}p → η{sub c}Λ process via s-channel is investigated with an effective Lagrangian approach and the isobar model. Moreover, the background from the K{sup -}p → η{sub c}Λ reaction through the t-channel with K* exchange and u-channel with nucleon exchange are also considered. The numerical results indicate it is feasible to search for the superheavy Λ{sub c} {sub anti} {sub c}{sup *}(4209) via K{sup -}p scattering. The relevant calculations not only shed light on the further experiment of searching for the Λ{sub c} {sub anti} {sub c}{sup *}(4209) through kaon-induced reaction, but also enable us to have a better understanding of the exotic baryons. (orig.)

Spectroscopy of very heavy nuclei with a view to study super-heavy nuclei

International Nuclear Information System (INIS)

Khalfallah, F.

2007-08-01

Within the recent years, the spectroscopic study of single particle orbitals of very heavy elements (VHE) has become possible with the development of increasingly efficient experimental setups. This allows us, through nuclear deformation, to access with these deformed nuclei to orbitals situated around the Fermi level in the spherical superheavy elements (SHE) and learn more about the nuclear structure of these nuclei. The aim of this work is the spectroscopic studies of heavy and very heavy elements. Because of the experimental difficulties associated with the fusion reactions in the VHE region, a detailed optimization studies is essential. Simulation of energy loss and angular straggling of these nuclei due to the interaction in the target and to neutron's evaporation was carried out and allowed us to optimize the angular acceptance of the separators according to the target thickness. An extensive survey and exploration in the VHE region was also conducted on the basis of cross section's systematics in the literature and simulations carried out using the statistical code Hivap. In this framework, the possible extension of the range of validity of a set of Hivap parameters was investigated. This work has enabled us to prepare a list of experiments of interest for the production of very heavy nuclei. In this thesis, our work was concentrated on the spectroscopy of the nuclei No 256 et Rf 256 for which two experimental proposals were accepted. The octupole deformations predicted in the actinides region is studied in another part of this thesis, a part witch is dedicated to the gamma spectroscopy of Pa 223 . The data from a new experiment carried out using the Jurogam-Ritu-Great setup are analysed and compared to previous results. They confirm the octupole deformed shape in this nucleus. (author)

The predictive accuracy of analytical formulas and semiclassical approaches for α decay half-lives of superheavy nuclei

Science.gov (United States)

Zhao, T. L.; Bao, X. J.; Guo, S. Q.

2018-02-01

Systematic calculations on the α decay half-lives are performed by using three analytical formulas and two semiclassical approaches. For the three analytical formulas, the experimental α decay half-lives and {Q}α values of the 66 reference nuclei have been used to obtain the coefficients. We get only four adjustable parameters to describe α decay half-lives for even-even, odd-A, and odd-odd nuclei. By comparison between the calculated values from ten analytical formulas and experimental data, it is shown that the new universal decay law (NUDL) foumula is the most accurate one to reproduce the experimental α decay half-lives of the superheavy nuclei (SHN). Meanwhile it is found that the experimental α decay half-lives of SHN are well reproduced by the Royer formula although many parameters are contained. The results show that the NUDL formula and the generalized liquid drop model (GLDM2) with consideration of the preformation factor can give fairly equivalent results for the superheavy nuclei.

Synthesis of a New Element with Atomic Number Z=117

International Nuclear Information System (INIS)

Oganessian, Yu. Ts.; Abdullin, F. Sh.; Dmitriev, S. N.; Itkis, M. G.; Lobanov, Yu. V.; Mezentsev, A. N.; Polyakov, A. N.; Sagaidak, R. N.; Shirokovsky, I. V.; Subbotin, V. G.; Sukhov, A. M.; Tsyganov, Yu. S.; Utyonkov, V. K.; Voinov, A. A.; Vostokin, G. K.; Bailey, P. D.; Benker, D. E.; Ezold, J. G.; Porter, C. E.; Riley, F. D.

2010-01-01

The discovery of a new chemical element with atomic number Z=117 is reported. The isotopes 293 117 and 294 117 were produced in fusion reactions between 48 Ca and 249 Bk. Decay chains involving 11 new nuclei were identified by means of the Dubna gas-filled recoil separator. The measured decay properties show a strong rise of stability for heavier isotopes with Z≥111, validating the concept of the long sought island of enhanced stability for superheavy nuclei.

Charge quantization without superheavy masses in a Kaluza--Klein description of electromagnetism

International Nuclear Information System (INIS)

Ross, D.K.

1987-01-01

A scalar matter field coupled to general relativity and electromagnetism in a five-dimensional Kaluza--Klein model is considered. The five-dimensional space is assumed to be a fiber bundle as in the usual description of a gauge theory and not a more general manifold. Properly taking this into account allows one to use a Lagrangian density for the scalar field which includes charge quantization but not the unphysical superheavy masses found by other authors. A natural, satisfactory explanation of why charge is quantized results

Effects of high-order deformation on high-K isomers in superheavy nuclei

International Nuclear Information System (INIS)

Liu, H. L.; Bertulani, C. A.; Xu, F. R.; Walker, P. M.

2011-01-01

Using, for the first time, configuration-constrained potential-energy-surface calculations with the inclusion of β 6 deformation, we find remarkable effects of the high-order deformation on the high-K isomers in 254 No, the focus of recent spectroscopy experiments on superheavy nuclei. For shapes with multipolarity six, the isomers are more tightly bound and, microscopically, have enhanced deformed shell gaps at N=152 and Z=100. The inclusion of β 6 deformation significantly improves the description of the very heavy high-K isomers.

Superheavy magnetic monopoles and the standard cosmology

International Nuclear Information System (INIS)

Turner, M.S.

1984-10-01

The superheavy magnetic monopoles predicted to exist in grand unified theories (GUTs) are very interesting obsects, both from the point of view of particle physics, as well as from astrophysics and cosmology. Astrophysical and cosmological considerations have proved to be invaluable in studying the properties of GUT monopoles. Because of the glut of monopoles predicted in the standard cosmology for the simplest GUTs (so many that the Universe should have reached a temperature of 3 0 K at the tender age of approx. = 10,000 yrs), the simplest GUTs and the standard cosmology are not compatible. This is a very important piece of information about physics at unification energies (E greater than or equal to 10 14 GeV) and about the earliest moments (t less than or equal to 10 -34 s) of the Universe. In this talk the author reviews the cosmological consequences of GUT monopoles within the context of the standard hot big bang model. 46 references

Superheavy thermal dark matter and primordial asymmetries

International Nuclear Information System (INIS)

Bramante, Joseph; Unwin, James

2017-01-01

The early universe could feature multiple reheating events, leading to jumps in the visible sector entropy density that dilute both particle asymmetries and the number density of frozen-out states. In fact, late time entropy jumps are usually required in models of Affleck-Dine baryogenesis, which typically produces an initial particle-antiparticle asymmetry that is much too large. An important consequence of late time dilution, is that a smaller dark matter annihilation cross section is needed to obtain the observed dark matter relic density. For cosmologies with high scale baryogenesis, followed by radiation-dominated dark matter freeze-out, we show that the perturbative unitarity mass bound on thermal relic dark matter is relaxed to 10 10 GeV. We proceed to study superheavy asymmetric dark matter models, made possible by a sizable entropy injection after dark matter freeze-out, and identify how the Affleck-Dine mechanism would generate the baryon and dark asymmetries.

Superheavy thermal dark matter and primordial asymmetries

Energy Technology Data Exchange (ETDEWEB)

Bramante, Joseph [Perimeter Institute for Theoretical Physics,31 Caroline St N, Waterloo, ON N2L 2Y5 (Canada); Unwin, James [Department of Physics, University of Illinois at Chicago,845 W Taylor St, Chicago, IL 60607 (United States)

2017-02-23

The early universe could feature multiple reheating events, leading to jumps in the visible sector entropy density that dilute both particle asymmetries and the number density of frozen-out states. In fact, late time entropy jumps are usually required in models of Affleck-Dine baryogenesis, which typically produces an initial particle-antiparticle asymmetry that is much too large. An important consequence of late time dilution, is that a smaller dark matter annihilation cross section is needed to obtain the observed dark matter relic density. For cosmologies with high scale baryogenesis, followed by radiation-dominated dark matter freeze-out, we show that the perturbative unitarity mass bound on thermal relic dark matter is relaxed to 10{sup 10} GeV. We proceed to study superheavy asymmetric dark matter models, made possible by a sizable entropy injection after dark matter freeze-out, and identify how the Affleck-Dine mechanism would generate the baryon and dark asymmetries.

Superheavy dark matter through Higgs portal operators

Science.gov (United States)

Kolb, Edward W.; Long, Andrew J.

2017-11-01

The WIMPzilla hypothesis is that the dark matter is a super-weakly-interacting and superheavy particle. Conventionally, the WIMPzilla abundance is set by gravitational particle production during or at the end of inflation. In this study we allow the WIMPzilla to interact directly with Standard Model fields through the Higgs portal, and we calculate the thermal production (freeze-in) of WIMPzilla dark matter from the annihilation of Higgs boson pairs in the plasma. The two particle-physics model parameters are the WIMPzilla mass and the Higgs-WIMPzilla coupling. The two cosmological parameters are the reheating temperature and the expansion rate of the universe at the end of inflation. We delineate the regions of parameter space where either gravitational or thermal production is dominant, and within those regions we identify the parameters that predict the observed dark matter relic abundance. Allowing for thermal production opens up the parameter space, even for Planck-suppressed Higgs-WIMPzilla interactions.

48Ca+249Bk fusion reaction leading to element Z = 117: long-lived α-decaying 270Db and discovery of 266Lr.

Science.gov (United States)

Khuyagbaatar, J; Yakushev, A; Düllmann, Ch E; Ackermann, D; Andersson, L-L; Asai, M; Block, M; Boll, R A; Brand, H; Cox, D M; Dasgupta, M; Derkx, X; Di Nitto, A; Eberhardt, K; Even, J; Evers, M; Fahlander, C; Forsberg, U; Gates, J M; Gharibyan, N; Golubev, P; Gregorich, K E; Hamilton, J H; Hartmann, W; Herzberg, R-D; Heßberger, F P; Hinde, D J; Hoffmann, J; Hollinger, R; Hübner, A; Jäger, E; Kindler, B; Kratz, J V; Krier, J; Kurz, N; Laatiaoui, M; Lahiri, S; Lang, R; Lommel, B; Maiti, M; Miernik, K; Minami, S; Mistry, A; Mokry, C; Nitsche, H; Omtvedt, J P; Pang, G K; Papadakis, P; Renisch, D; Roberto, J; Rudolph, D; Runke, J; Rykaczewski, K P; Sarmiento, L G; Schädel, M; Schausten, B; Semchenkov, A; Shaughnessy, D A; Steinegger, P; Steiner, J; Tereshatov, E E; Thörle-Pospiech, P; Tinschert, K; Torres De Heidenreich, T; Trautmann, N; Türler, A; Uusitalo, J; Ward, D E; Wegrzecki, M; Wiehl, N; Van Cleve, S M; Yakusheva, V

2014-05-02

The superheavy element with atomic number Z=117 was produced as an evaporation residue in the (48)Ca+(249)Bk fusion reaction at the gas-filled recoil separator TASCA at GSI Darmstadt, Germany. The radioactive decay of evaporation residues and their α-decay products was studied using a detection setup that allowed measuring decays of single atomic nuclei with half-lives between sub-μs and a few days. Two decay chains comprising seven α decays and a spontaneous fission each were identified and are assigned to the isotope (294)117 and its decay products. A hitherto unknown α-decay branch in (270)Db (Z = 105) was observed, which populated the new isotope (266)Lr (Z = 103). The identification of the long-lived (T(1/2) = 1.0(-0.4)(+1.9) h) α-emitter (270)Db marks an important step towards the observation of even more long-lived nuclei of superheavy elements located on an "island of stability."

Superheavy contributions to FCNC in the flipped SU(5) x U(1)

Energy Technology Data Exchange (ETDEWEB)

Gabbiani, F.; Masiero, A.

1988-08-04

In the supersymmetric GUT's the presence of the superheavy fields yields new contributions to flavour-changing neutral-current effects at low energy. We analyse this phenomenon in the context of the flipped SU(5) x U(1) superstring (-inspired) model. We show that possibly sizeable flavour leptonic changes (..mu.. -> e..gamma.., ..mu.. -> eeanti e, ..mu..-e conversion in nuclei) are generated. K-anti K, B-anti B mixings and b -> s..gamma.. constrain new couplings at the superlarge scale, which are unrelated to the standard Yukawa coefficients.

Superheavy particles in cosmology and evolution of inhomogeneities in the early universe

International Nuclear Information System (INIS)

Khlopov, M. Yu.; Polnarev, A.G.

1983-01-01

The stages of dominance of superheavy metastable particles, predicted by GUTs, are shown to result in the formation of primordial black holes (PBH) in the course of evolution of small initial inhomogeneities. The minimal probability of PBH formation is estimated. The relationship between the spectrum of these PBH, the spectrum of initial metric fluctuations and the parameters of the GUTs is established. Observational astrophysical restrictions on the PBH spectrum then provide a number of restrictions on the parameters of the GUTs depending on the amplitude of initial metric perturbations. (author)

Spallation RI beam facility and heavy element nuclear chemistry

Energy Technology Data Exchange (ETDEWEB)

Nagame, Yuichiro [Japan Atomic Energy Research Inst., Tokai, Ibaraki (Japan). Tokai Research Establishment

1997-11-01

An outline of the spallation RI (Radioactive Ion) beam facility is presented. Neutron-rich nuclides are produced in the reaction of high intensity (10-1000 {mu}A) protons with energy of 1.5 GeV and an uranium carbide target. Produced nuclides are ionized in an isotope separator on-line (ISOL) and accelerated by the JAERI tandem and the booster linac. Current progress and a future project on the development of the RI beam facility are given. Studies of transactinide elements, including the synthesis of superheavy elements, nuclear structure far from stability, and RI-probed material science are planned with RI beams. An outlook of the transactinide nuclear chemistry studies using neutron-rich RI beams is described. (author)

Recent developments for high-precision mass measurements of the heaviest elements at SHIPTRAP

International Nuclear Information System (INIS)

Minaya Ramirez, E.; Ackermann, D.; Blaum, K.; Block, M.; Droese, C.; Düllmann, Ch. E.; Eibach, M.; Eliseev, S.; Haettner, E.; Herfurth, F.; Heßberger, F.P.

2013-01-01

Highlights: • Direct high-precision mass measurements of No and Lr isotopes performed. • High-precision mass measurements with a count rate of 1 ion/hour demonstrated. • The results provide anchor points for a large region connected by alpha-decay chains. • The binding energies determine the strength of the deformed shell closure N = 152. • Technical developments and new techniques will pave the way towards heavier elements. -- Abstract: Atomic nuclei far from stability continue to challenge our understanding. For example, theoretical models have predicted an “island of stability” in the region of the superheavy elements due to the closure of spherical proton and neutron shells. Depending on the model, these are expected at Z = 114, 120 or even 126 and N = 172 or 184. Valuable information on the road to the island of stability is derived from high-precision mass measurements, which give direct access to binding energies of short-lived trans-uranium nuclei. Recently, direct mass measurements at SHIPTRAP have been extended to nobelium and lawrencium isotopes around the deformed shell gap N = 152. In order to further extend mass measurements to the region of superheavy elements, new technical developments are required to increase the performance of our setup. The sensitivity will increase through the implementation of a new detection method, where observation of one single ion is sufficient. Together with the use of a more efficient gas stopping cell, this will us allow to significantly enhance the overall efficiency of SHIPTRAP

Nuclear spectroscopy with Geant4. The superheavy challenge

Science.gov (United States)

Sarmiento, Luis G.

2016-12-01

The simulation toolkit Geant4 was originally developed at CERN for high-energy physics. Over the years it has been established as a swiss army knife not only in particle physics but it has seen an accelerated expansion towards nuclear physics and more recently to medical imaging and γ- and ion- therapy to mention but a handful of new applications. The validity of Geant4 is vast and large across many particles, ions, materials, and physical processes with typically various different models to choose from. Unfortunately, atomic nuclei with atomic number Z > 100 are not properly supported. This is likely due to the rather novelty of the field, its comparably small user base, and scarce evaluated experimental data. To circumvent this situation different workarounds have been used over the years. In this work the simulation toolkit Geant4 will be introduced with its different components and the effort to bring the software to the heavy and superheavy region will be described.

Search for super-heavy GUT magnetic monopoles in cosmic rays

International Nuclear Information System (INIS)

Shepko, M.J.

1986-05-01

A search for superheavy grand unified (GUT) magnetic monopoles has been performed utilizing a large (260m 2 sr) array of scintillation counters, sited underground at a depth of 1200 m.w.e. This apparatus measures both the time of flight and specific ionization of particles passing through it and has a trigger which is sensitive to prompt as well as very slowly developing pulses from the detector. No monopole events have been observed during 280 days of live time operation of this detector. An upper limit on the flux of monopoles of 4.6 x 10 -14 cm -2 sr -1 s -1 is obtained in the velocity range 8.5 x 10 -4 c to 0.012c at a 90% confidence level. 50 refs., 47 figs., 16 tabs

Heavy-Ion Fusion Mechanism and Predictions of Super-Heavy Elements Production

International Nuclear Information System (INIS)

Abe, Yasuhisa; Shen Caiwan; Boilley, David; Giraud, Bertrand G.; Kosenko, Grigory

2009-01-01

Fusion process is shown to firstly form largely deformed mono-nucleus and then to undergo diffusion in two-dimensions with the radial and mass-asymmetry degrees of freedom. Examples of prediction of residue cross sections are given for the elements with Z = 117 and 118.

Towards Superheavies: Spectroscopy of 94 < Z < 98, 150 < N < 154 Nuclei

Directory of Open Access Journals (Sweden)

Chowdhury P.

2016-01-01

nuclear structure studies are important testing grounds for theoretical models that aim to describe superheavy nuclei. To study the highest neutron orbitals (150 ≤ N ≤ 154, we have populated high angular momentum states in a series of Pu (Z = 94, Cm (Z = 96 and Cf (Z = 98 nuclei, via inelastic and transfer reactions, with heavy beams on long-lived radioactive actinide targets. Multiple collective excitation modes and structures were identified, and their configurations deduced. Quasiparticle alignments are mapped, with odd-A band structures helping identify specific orbital contributions via blocking arguments. Higher-order multipole shapes are observed to play a significant role in disentangling competing neutron and proton alignments. The N > 152 data provide new perspectives on physics beyond the N = 152 sub-shell gap.

The Synthesis and Decay Properties of the Heaviest Elements

CERN Document Server

Oganessian, Yu T

2000-01-01

The synthesis and the study of radioactive properties of new elements is considered with respect to the existence of the "islands of stability" of hypothetical superheavy elements predicted by the theory more than 35 years ago. Experimental data demonstrating an enhanced stability of nuclei in the vicinity of deformed shells with Z=108 and N=162 is discussed from the point of view of advent into more heavy and much more stable nuclides near the predicted spherical shells Z=114-122 and N=184 following after the doubly magic nucleus ^{208}Pb. The author presents the results of experiments on the synthesis of isotopes of elements 114 and 116 in the fusion reactions with ^{48}Ca. In these reactions the decay chains of heavy atoms consisting of sequential alpha-decays interrupted by spontaneous fission have been observed. The decay energies and probabilities are compared with predictions of different theoretical models describing the structure of heavy nuclei. The obtained results are considered as the first exper...

CHARGE SPECTRUM OF HEAVY AND SUPERHEAVY COMPONENTS OF GALACTIC COSMIC RAYS: RESULTS OF THE OLIMPIYA EXPERIMENT

Energy Technology Data Exchange (ETDEWEB)

Alexeev, Victor; Kalinina, Galina; Pavlova, Tatyana, E-mail: aval37@mail.ru, E-mail: gakalin@mail.ru, E-mail: pavlova4tat@mail.ru [Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, 19 Kosygin Str., Moscow 119991 (Russian Federation); and others

2016-10-01

The aim of the OLIMPIYA experiment is to search for and identify traces of heavy and superheavy nuclei of galactic cosmic rays (GCR) in olivine crystals from stony–iron meteorites serving as nuclear track detectors. The method is based on layer-by-layer grinding and etching of particle tracks in these crystals. Unlike the techniques of other authors, this annealing-free method uses two parameters: the etching rate along the track ( V {sub etch}) and the total track length ( L ), to identify charge Z of a projectile. A series of irradiations with different swift heavy ions at the accelerator facilities of GSI (Darmstadt) and IMP (Lanzhou) were performed in order to determine and calibrate the dependence of projectile charge on V {sub etch} and L . To date, one of the most essential results of the experiment is the obtained charge spectrum of GCR nuclei within the range of Z > 40, based on about 11.6 thousand processed tracks. As the result of data processing, 384 nuclei with charges Z ≥ 75 have been identified, including 10 nuclei identified as actinides (90 < Z < 103). Three tracks were identified to be produced by nuclei with charges 113 < Z < 129. Such nuclei may be part of the Island of Stability of transfermium elements.

Integrated PC-based system for detecting and parameter monitoring at the Dubna Gas Filled Recoil Separator

International Nuclear Information System (INIS)

Tsyganov, Yu.S.; Polyakov, A.N.; Sukhov, A.M.

2012-01-01

New detection system of the Dubna Gas Filled Recoil Separator (DGFRS) was put into operation in May 2012. It includes 32-strip position sensitive PIPS detector manufactured by CANBERRA NV, 24-strip back side PIPS detector, 8-strip V ETO P IPS detector, time-of-flight low pressure (∼1.7 Torr) pentane-filled gaseous detector, CAMAC fast ADC's with 5 μs dead time per three signals (energy, top position, bottom position), modified CC012 crate controller and PC-based C ++ Builder code for spectrometry data acquisition. New parameter monitoring system (project) is reported too together with the brief review of the present system. It is planned to put into operation with this system during 2013-2014. Examples of applications in the long-term experiments aimed at the synthesis of superheavy elements in 48 Ca induced complete fusion nuclear reactions are also presented. Namely with the DGFRS facility 45 new isotopes of superheavy nuclei were synthesized since 2001

On the spectroscopy of the 1ssigma-orbital in superheavy collision systems

International Nuclear Information System (INIS)

Stiebing, K.E.; Schmidt-Boecking, H.; Schadt, W.; Bethge, K.; Mokler, P.H.; Bosch, F.; Liesen, D.; Vincent, P.

1982-01-01

The probability for the emission of quasimolecular K-radiation (K-MO-radiation) in superheavy collision systems was measured in the system 208 Pb + 208 Pb as function of the scattering angle and the photon energy for incident energies of 4.3 and 4.8 MeV/u. In the present article these measurements and their evaluation are extensively described. The results are discussed with special regards to the contributions from the 1ssigma-molecular orbital, because there exists a great interest on an utmost precise knowledge of the binding energy of these most strongly bound electrons. For this a survey about the dynamical model of the emission of quasimolecular X-radiation in the configuration formalism is given. (orig./HSI) [de

Synthesis of neutron-rich transuranic nuclei in fissile spallation targets

Energy Technology Data Exchange (ETDEWEB)

Mishustin, Igor, E-mail: mishustin@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); “Kurchatov Institute”, National Research Center, 123182 Moscow (Russian Federation); Malyshkin, Yury, E-mail: malyshkin@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); Institute for Nuclear Research, Russian Academy of Sciences, 117312 Moscow (Russian Federation); Pshenichnov, Igor, E-mail: pshenich@fias.uni-frankfurt.de [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany); Institute for Nuclear Research, Russian Academy of Sciences, 117312 Moscow (Russian Federation); Greiner, Walter [Frankfurt Institute for Advanced Studies, J.-W. Goethe University, 60438 Frankfurt am Main (Germany)

2015-04-15

A possibility of synthesizing neutron-rich superheavy elements in spallation targets of Accelerator Driven Systems (ADS) is considered. A dedicated software called Nuclide Composition Dynamics (NuCoD) was developed to model the evolution of isotope composition in the targets during a long-time irradiation by intense proton and deuteron beams. Simulation results show that transuranic elements up to {sup 249}Bk can be produced in multiple neutron capture reactions in macroscopic quantities. However, the neutron flux achievable in a spallation target is still insufficient to overcome the so-called fermium gap. Further optimization of the target design, in particular, by including moderating material and covering it by a reflector could turn ADS into an alternative source of transuranic elements in addition to nuclear fission reactors.

Fission in the landscape of heaviest elements: Some recent examples

International Nuclear Information System (INIS)

Khuyagbaatar, J.; Yakushev, A.; Düllmann, Ch.E.; Ackermann, D.; Andersson, L.-L.; Block, M.; Brand, H.; Even, J.; Forsberg, University; Hartmann, W.; Herzberg, R.-D.; Heßberger, F.P.; Hoffmann, J.; Hübner, A.; Jäger, E.; Jeppsson, J.; Kindler, B.; Kratz, J.V.; Krier, J.; Kurz, N.; Lommel, B.; Maiti, M.; Minami, S.; Rudolph, D.; Runke, J.; Sarmiento, L.G.; Schädel, M.; Schausten, B.; Steiner, J.; Heidenreich, T. Torres De; Uusitalo, J.; Wiehl, N.; Yakusheva, V.

2016-01-01

The fission process still remains a main factor that determines the stability of the atomic nucleus of heaviest elements. Fission half-lives vary over a wide range, 10"−"1"9−10"2"4 s. Present experimental techniques for the synthesis of the superheavy elements that usually measure α-decay chains are sensitive only in a limited range of half-lives, often 10"−"5−10"3 s. In the past years, measurement techniques for very short-lived and very long-lived nuclei were significantly improved at the gas-filled recoil separator TASCA at GSI Darmstadt. Recently, several experimental studies of fission-related phenomena have successfully been performed. In this paper, results on "2"5"4"−"2"5"6Rf and "2"6"6Lr are presented and corresponding factors for retarding the fission process are discussed.

How elements up to 118 were reached and how to go beyond

Science.gov (United States)

Düllmann, Christoph E.

2017-11-01

The new superheavy elements with Z=113, 115, 117, and 118 were recently accepted into the periodic table and have been named. Elements with Z≥112 are predominantly produced in 48Ca-induced fusion reactions on actinide targets. This pathway is exhausted at Z=118 due to the lack of target materials with sufficiently high proton number to reach elements with Z≥119. Search experiments for yet heavier elements were performed at GSI Darmstadt and FLNR Dubna. The reactions 50Ti + 249Bk, which leads to Z=119, as well as 64Ni + 238U, 58Fe + 244Pu, 54Cr + 248Cm, and 50Ti + 249Cf, leading to Z=120, have been studied. Despite a total duration of these experiments of more than one year, neither succeeded in the identification of a new element. To obtain improved guidance for better-informed search experiments, nuclear reaction studies appear necessary and have recently started. Also technical advances will be an important pillar to this end. At GSI, work towards a new continuous-wave linear accelerator is ongoing and is briefly described.

Superheavy elements and decay properties

Indian Academy of Sciences (India)

chains from 294118 and, it can be seen that our predictions on the α decay ... The Coulomb and proximity potential model for deformed nuclei (CPPMDN) .... Here the half-life is in seconds, Q-value is in MeV and Z is the atomic number of the.

Thermodynamic analysis of volatile organometallic fission products

International Nuclear Information System (INIS)

Auxier II, J.D.; Hall, H.L.; Cressy, Derek

2016-01-01

The ability to perform rapid separations in a post nuclear weapon detonation scenario is an important aspect of national security. In the past, separations of fission products have been performed using solvent extraction, precipitation, etc. The focus of this work is to explore the feasibility of using thermochromatography, a technique largely employed in superheavy element chemistry, to expedite the separation of fission products from fuel components. A series of fission product complexes were synthesized and the thermodynamic parameters were measured using TGA/DSC methods. Once measured, these parameters were used to predict their retention times using thermochromatography. (author)

Description of new element Z=113 and its α-decay chain

International Nuclear Information System (INIS)

Tai Fei; Chen Dinghan; Xu Chang; Ren Zhongzhou; National Laboratory of Heavy Ion Accelerator, Lanzhou

2005-01-01

RIKEN has produced a new element Z=113 by cold-fusion reaction. Here we systematically study the new nuclide 278 113 and its α-Decay chain using deformed relativistic mean-field theory with three sets of force parameters, TMA, NL-Z2 and NL3. The results are compared with those of the Skyrme-Hartree-Fock model, Moeller et al and also with the new experimental data. The experimental decay energies are well reproduced with RMF. This not only shows the validity of self-consistent field theoretical model in researching the ground state properties of superheavy nuclei, but also shows that prolate deformation is important for the ground state of these nuclei. (authors)

How elements up to 118 were reached and how to go beyond

Directory of Open Access Journals (Sweden)

Düllmann Christoph E.

2017-01-01

Full Text Available The new superheavy elements with Z=113, 115, 117, and 118 were recently accepted into the periodic table and have been named. Elements with Z≥112 are predominantly produced in 48Ca-induced fusion reactions on actinide targets. This pathway is exhausted at Z=118 due to the lack of target materials with sufficiently high proton number to reach elements with Z≥119. Search experiments for yet heavier elements were performed at GSI Darmstadt and FLNR Dubna. The reactions 50Ti + 249Bk, which leads to Z=119, as well as 64Ni + 238U, 58Fe + 244Pu, 54Cr + 248Cm, and 50Ti + 249Cf, leading to Z=120, have been studied. Despite a total duration of these experiments of more than one year, neither succeeded in the identification of a new element. To obtain improved guidance for better-informed search experiments, nuclear reaction studies appear necessary and have recently started. Also technical advances will be an important pillar to this end. At GSI, work towards a new continuous-wave linear accelerator is ongoing and is briefly described.

The discovery of elements 107 to 112

Directory of Open Access Journals (Sweden)

Hofmann Sigurd

2016-01-01

Full Text Available In the 1960s, theoretical concepts prepared the path to nuclear matter with proton and neutron numbers far beyond the nuclei known at that time. The new laboratory GSI was founded for research on reactions with heavy ions, in particular those for production of the predicted super-heavy nuclei. In this contribution it is presented how the interaction between experiment and theory resulted in a continuous improvement of the experimental set-ups on the one hand, and of the knowledge of the processes during the nuclear reaction and of the properties of the produced nuclei on the other hand. In the course of this work six new elements from 107 to 112 were produced and identified. An overview of the present status of experimental results and a comparison with theoretical interpretations is given.

Search for surviving actinides and superheavy nuclei in damped collisions of 238U with 238U and 248Cm

International Nuclear Information System (INIS)

Kratz, J.V.

1980-03-01

In the present talk aspects of the reaction mechanism related to the survival probability of the heaviest fragments in 238 U + 238 U collisions are discussed first. This is followed by a description of the experiments that have been performed to search for surviving superheavy fragments in the 238 U + 238 U reaction and by a presentation of the results obtained so far. In a third section our recent first attempts with the 238 U + 248 Cm reaction are described and preliminary results are discussed. (orig.)

Perspectives of Super-Heavy Nuclei research with the upcoming separator-spectrometer setup S3 at GANIL/SPIRAL2 - The VAMOS Gas-Filled separator and AGATA

Science.gov (United States)

Theisen, Christophe

2017-11-01

Several facilities or apparatus for the synthesis and spectroscopy of the Super-Heavy Nuclei (SHN) are presently under construction in the world, which reflect the large interest for this region of extreme mass and charge, but also for the need of even more advanced research infrastructures. Among this new generation, the GANIL/SPIRAL2 facility in Caen, France, will soon deliver very high intense ion beams of several tens of particle μA. The Super Separator Spectrometer S3 has been designed to exploit these new beams for the study of SHN after separation. It will provide the needed beam rejection, mass selection and full arsenal of state-of-the art detection setups. Still at GANIL, the AGATA new generation gamma-ray tracking array is being operated. The VAMOS high acceptance spectrometer is being upgraded as a gas-filled separator. Its coupling with AGATA will lower the spectroscopic limits for the prompt gamma-ray studies of heavy and super-heavy nuclei. In this proceeding, these new devices will be presented along with a selected physics case.

Search for isobar-analog states of superheavy hydrogen isotopes5-7He

Science.gov (United States)

Chernyshev, B. A.; Gurov, Yu B.; Korotkova, L. Yu; Kuznetsov, D. S.; Lapushkin, S. V.; Tel'kushev, M. V.; Schurenkova, T. D.

2016-02-01

Search for isobar-analog states (IAS) of superheavy hydrogen isotopes 5-7H was performed among the high-excited states of helium isotopes 5-7He. The excited spectra were measured in stopped pion absorption by light nuclei. The experiment was performed at low energy pion channel of LANL with two-arm multilayer semiconductor spectrometer. Excited states of 5-7He were observed in three-body reaction channels on 10,11B nuclei. Several excited levels were observed for the first time. 6He excited state with Ex = 27.0(8) MeV observed in 10B(π-,pt)X channel is an IAS candidate for 6H with Er ∼ 5.5 MeV. 7He excited state with Ex = 24.8(4) MeV observed in 10B(π-,pd)X, nB(π-,pt)X and nB(π-,dd)X channels is an IAS candidate for 7H with Er ∼ 3 MeV.

Workshop of Advanced Science Research Center, JAERI. Nuclear physics and nuclear chemistry of superheavy elements

International Nuclear Information System (INIS)

Nishio, Katsuhisa; Nishinaka, Ichiro; Ikezoe, Hiroshi; Nagame, Yuichiro

2004-03-01

A liquid drop model predicts that the fission barrier of a nucleus whose atomic number (Z) is larger than 106 disappears, so that such heavier nuclei as Z > 106 cannot exist. The shell effect, however, drastically changes structure of the fission barrier and stabilizes nucleus against fission, predicting the presence of super heavy element (SHE, Z=114-126) with measurable half-life. In the SHE region, a wave function of outermost electron of an atom, which controls chemical properties of an elements, is disturbed or changed by relativistic effects compared to the one from the non-relativistic model. This suggests that the SHEs have different chemical properties from those of lighter elements belonging to the same family. The chemistry of SHEs requires event by event analysis to reveal their chemical properties, thus is called 'atom-at-a-time chemistry'. Japan Atomic Energy Research Institute (JAERI) has been investigating fusion mechanism between heavy nuclei to find out favorable reactions to produce SHE by using JAERI-tandem and booster accelerator. In the JAERI-tandem facility, isotopes of Rf and Db are produced by using actinide targets such as 248 Cm in order to investigate their chemical properties. The present workshop was held in Advanced Science Research Center of JAERI at February 27-28 (2003) in order to discuss current status and future plans for the heavy element research. The workshop also included topics of the radioactive nuclear beam project forwarded by the JAERI-KEK cooperation and the nuclear transmutation facility of J-PARC. Also included is the nuclear fission process as a decay characteristic of heavy elements. There were sixty participants in the workshop including graduate and undergraduate eleven students. We had guests from Germany and Hungary. Through the workshop, we had a common knowledge that researches on SHE in Japan should fill an important role in the world. (author)

Recent results of experiments at SHIP

International Nuclear Information System (INIS)

Hofmann, S.

1997-10-01

The new elements 110, 111 and 112 were synthesized and unambiguously identified in experiments at SHIP. The decay data were compared with the predictions of theoretical models. Good agreement was obtained for the nuclei up to element Z=112. Theory predicts deformed nuclei with minimum (negative) shell-correction energy at Z=108 and N=162. Candidates for an experimental investigation of spherical superheavy nuclei (SHE) are selected on the basis of the predictions of the nuclear models and extrapolation of experimental results. The production cross-sections up to element Z=112 were measured, partly accurate excitation functions were obtained. The data allow to fix a narrow energy window for production of SHE by ln-emission channels. Possibilities to broaden the energy window by radiative capture reactions, use of neutron deficient projectile isotopes and use of actinide targets are discussed. (orig.)

Synthesis of superheavy elements and dinuclear-system concept of compound-nucleus formation

Energy Technology Data Exchange (ETDEWEB)

Antonenko, N.V.; Adamian, G.G.; Cherepanov, E.A. [Joint Institute for Nuclear Research, Dubna (Russian Federation)] [and others

1996-12-31

Dinuclear system concept is applied to the analysis of reactions used for the synthesis of elements with Z = 110, 112, 114, and 116. The inner fusion barriers obtained for these reactions are in good agreement with the experimental estimations resulted from the excitation energies of compound nuclei. A model is suggested for the calculation of the competition between complete fusion and quasifission in reactions with heavy nuclei. The fusion rate through the inner fusion barrier in mass asymmetry is found by using the multidimensional Kramers-type stationary solution of the Fokker-Planck equation. The influence of dissipative effects on the dynamics of nuclear fusion is considered.

Operational Design that Synthesizes Art and Science

Science.gov (United States)

2011-05-04

FINAL 3. DATES COVERED (From - To) Feb - May 2011 4. TITLE AND SUBTITLE OPERATIONAL DESIGN THAT SYNTHESIZES ART AND SCIENCE 5a...TITLE AND SUBTITLE Operational Design That Synthesizes Art And Science 5a. CONTRACT NUMBER 5b. GRANT NUMBER 5c. PROGRAM ELEMENT NUMBER 6. AUTHOR...proponents of EBO view warfare as only a science and not a combination of art and science . 9 Another main point of contention centered on the term

Ionization history of the universe as a test for superheavy dark matter particles

International Nuclear Information System (INIS)

Doroshkevich, A.G.; Naselsky, P.D.

2002-01-01

In this paper we discuss the possible distortions of the ionization history of the universe caused by an injection of nonthermal energy due to decays of hypothetical superheavy dark matter (SHDM) particles. These particles are usually considered as a possible source of ultrahigh energy cosmic rays in the framework of the top-down model. Estimates of the fraction of energy of decays converted to the UV range show that, for suitable parameters of the SHDM particles, significant distortions of the power spectra of the cosmic microwave background anisotropy appear. A comparison with the observed power spectrum allows us to restrict some properties of the SHDM particles. These decays can also increase by about 5-10 times the degree of ionization of hydrogen at redshifts z∼10-50, which essentially accelerates the formation of molecules of H 2 and the first stars during the 'dark ages'

Quest for superheavy nuclei

Energy Technology Data Exchange (ETDEWEB)

Heenen, P.H. [Universite Libre de Bruxelles, Service de Physique Nucleaire Theorique (Belgium); Nazarewicz, W. [Tennessee Univ., Knoxville, TN (United States). Dept. of Physics; Warsaw Univ. (Poland). Inst. Fizyki Teoretycznej

2002-02-01

This article draws the long history of the discovery of new heavy nuclei since its beginning in 1940 when neptunium was found, and presents the current status of research in this field. The last 3 years have brought a number of experimental surprises which have truly rejuvenated the field. In January 1999, scientists from Dubna (Russia) reported the synthesis of 1 atom of element 114 ({sup 298}Uuq) in a hot fusion reaction between a {sup 48}Ca beam and a {sup 244}Pu target. This discovery was followed by 3 other reports from Dubna. First using the {sup 242}Pu({sup 48}Ca,3n) reaction, they produced {sup 287}Uuq. In 1999 the synthesis of another isotope of Z=114, the even-even {sup 288}Uuq was reported. The element Z=116 ({sup 292}Uuh) was discovered as a product of the {sup 248}Cm({sup 48}Ca,4n) reaction. The GSI (Germany) group found a new even isotope of the element 110: {sup 270}Uun and also {sup 272}Uuu (element 111) and {sup 277}Uub (element 112). 2 new isotopes of the element 107: {sup 266}Bh and {sup 267}Bh have been found at Berkeley (Usa). The synthesis of the new element Z=118 ({sup 293}Uuo) announced in 1999 by the Berkeley group was retracted 2 years later. The lifetimes reported for the elements {sup 284}Uub and {sup 280}Uun are by many orders of magnitude longer than those of the isotopes with Z{<=}112 previously discovered at GSI. (A.C.)

On the Source of the Systematic Errors in the Quatum Mechanical Calculation of the Superheavy Elements

Directory of Open Access Journals (Sweden)

Khazan A.

2010-10-01

Full Text Available It is shown that only the hyperbolic law of the Periodic Table of Elements allows the exact calculation for the atomic masses. The reference data of Periods 8 and 9 manifest a systematic error in the computer software applied to such a calculation (this systematic error increases with the number of the elements in the Table.

On the Source of the Systematic Errors in the Quantum Mechanical Calculation of the Superheavy Elements

Directory of Open Access Journals (Sweden)

Khazan A.

2010-10-01

Full Text Available It is shown that only the hyperbolic law of the Periodic Table of Elements allows the exact calculation for the atomic masses. The reference data of Periods 8 and 9 manifest a systematic error in the computer software applied to such a calculation (this systematic error increases with the number of the elements in the Table.

Aqueous chemistry of transactinides

International Nuclear Information System (INIS)

Schaedel, M.

2001-01-01

The aqueous chemistry of the first three transactinide elements is briefly reviewed with special emphasis given to recent experimental results. Short introductory remarks are discussing the atom-at-a-time situation of transactinide chemistry as a result of low production cross-sections and short half-lives. In general, on-line experimental techniques and, more specifically, the automated rapid chemistry apparatus, ARCA, are presented. Present and future developments of experimental techniques and resulting perspectives are outlined at the end. The central part is mainly focussing on hydrolysis and complex formation aspects of the superheavy group 4, 5, and 6 transition metals with F - and Cl - anions. Experimental results are compared with the behaviour of lighter homologous elements and with relativistic calculations. It will be shown that the chemical behaviour of the first superheavy elements is already strongly influenced by relativistic effects. While it is justified to place rutherfordium, dubnium and seaborgium in the Periodic Table of the Elements into group 4, 5 and 6, respectively, it is no more possible to deduce from this position in detail the chemical properties of these transactinide or superheavy elements. (orig.)

Binary fragmentation based studies for the near super-heavy compound nucleus {sup 256}Rf

Energy Technology Data Exchange (ETDEWEB)

Thakur, Meenu; Behera, B.R.; Mahajan, Ruchi; Kaur, Gurpreet; Sharma, Priya; Kapoor, Kushal; Rani, Kavita [Panjab University, Department of Physics, Chandigarh (India); Saneesh, N.; Dubey, R.; Yadav, A.; Sugathan, P.; Jhingan, A.; Chatterjee, A.; Chatterjee, M.B. [Inter University Accelerator Centre, New Delhi (India); Kumar, Neeraj; Mandal, S. [University of Delhi, Department of Physics and Astrophysics, Delhi (India); Kumar, S. [Andhra University, Department of Nuclear Physics, Visakhapatnam (India); Saxena, A.; Kailas, S. [Bhabha Atomic Research Centre, Nuclear Physics Division, Mumbai (India); Pal, Santanu [CS, Kolkata (India); Nasirov, Avazbek [JINR, Bogoliubov Laboratory of Theoretical Physics, Dubna (Russian Federation); National University, Department of Physics, Tashkent (Uzbekistan); Kayumov, Bakhodir [National University, Department of Physics, Tashkent (Uzbekistan)

2017-06-15

Binary fragmentation of the near super-heavy compound nucleus {sup 256}Rf has been studied through the reaction {sup 48}Ti + {sup 208}Pb at a bombarding energy well above the Coulomb barrier. For a better understanding of its reaction dynamics, the mass distribution, mass-energy distribution and mass-angle distribution of the fission fragments produced from {sup 256}Rf have been investigated thoroughly. The masses and kinetic energies of the fission fragments were reconstructed event-by-event from their measured velocities and emission angles. From the mass-energy analysis, a sizeable contribution from the asymmetric fission was observed on the edges of symmetric mass distribution. Evidence of asymmetric fission was also clued from the observed correlation between the masses and emission angles of the fission fragments. Contribution of the quasi-fission products has also been estimated by performing the theoretical dinuclear system calculations. (orig.)

Growth mechanism and elemental distribution of beta-Ga2O3 crystalline nanowires synthesized by cobalt-assisted chemical vapor deposition.

Science.gov (United States)

Wang, Hui; Lan, Yucheng; Zhang, Jiaming; Crimp, Martin A; Ren, Zhifeng

2012-04-01

Long beta-Ga2O3 crystalline nanowires are synthesized on patterned silicon substrates using chemical vapor deposition technique. Advanced electron microscopy indicates that the as-grown beta-Ga2O3 nanowires are consisted of poly-crystalline (Co, Ga)O tips and straight crystalline beta-Ga2O3 stems. The catalytic cobalt not only locates at the nanowire tips but diffuses into beta-Ga2O3 nanowire stems several ten nanometers. A solid diffusion growth mechanism is proposed based on the spatial elemental distribution along the beta-Ga2O3 nanowires at nanoscale.

Nuclear structure studies towards superheavy elements and perspectives with AGATA

International Nuclear Information System (INIS)

Korichi, A.

2005-01-01

A variety of theoretical approaches have been used to calculate the shell closure of spherical Super Heavy Elements (SHE) but the predictions of the location of the 'island of stability' vary from Z=114 to 120 and 126, with neutron numbers around N=172 or N=184 depending on the model employed. A deformed minimum around Z=108 and N=162 is predicted and an increase of the half-life of Hassium (Z=108) is experimentally observed when approaching the neutron number N=162. Super heavy nuclei are produced with very low cross-section (a few picobarns) and this makes their spectroscopic study impossible with today's beam intensities and detectors. However, important information can be obtained from the structure of mid-shell deformed nuclei (Z∼104) where selected single particle orbitals, which lie close to the spherical shell gap in SHE, are close to the Fermi level. The information will come from decay and in-beam spectroscopy. A promising area of progress, using the state-of-the art instruments, is represented by the observation of rotational gamma-ray transitions in No and Fm isotopes showing the deformed character of these nuclei. One of the objectives and focus of the nuclear structure community is related to the investigation of Single particle excitations beyond the N=152 neutron gap and collective properties of heavier systems towards Z∼104. The IN2P3-JINR collaboration has launched a project of electron and gamma-ray spectroscopy studies of heavy nuclei at the FLNR. This project benefits from the radioactive actinide targets uniquely available at Dubna and from the very intense stable beams provided by the U400 cyclotron. This offers a unique opportunity for the study of nuclei above Z=100 along an isotopic chain approaching N=162. In this contribution, the emphasis will be on the GABRIELA project and its issues. I will finally point out the perspectives with the new generation of gamma detectors such as AGATA

Towards the island of superheavy stability - Prompt spectroscopy of 246Fm and 256Rf nuclei

International Nuclear Information System (INIS)

Piot, J.

2010-10-01

The region of trans-fermium nuclei (Z = 100 to 104) is the last region of the nuclides chart to be accessible to spectroscopic measurements. It therefore provides the ultimate anchor points for nuclear models. This region also lies on the path of the alpha-decay chains of the super-heavy elements. This region represents the limit of today's spectroscopic capabilities. It therefore requires technological developments in order to overcome these limits. My thesis focuses on various aspects of the spectroscopy of trans-fermium nuclei. I took part in the development of the TNT2D digital acquisition cards for germanium detectors. I validated their use on the gamma-ray spectrometer JUROGAM during an in-beam experiment and demonstrated the gain compared to an analogue acquisition system. These tests were part of the developments needed to secure a study of the prompt spectroscopy of 256 Rf. The preparation of this experiment also lead me to work on the development of a 50 Ti beam. For that purpose, I studied and tested the use of titanium organo-metallic compounds compatible with the MIVOC technique. In parallel, I studied the use of metallic and oxide titanium pellets with an inductive oven newly developed at the University of Jyvaeskylae. In addition to these developments, I had the opportunity to study the in-beam prompt spectroscopy of 246 Fm at the University of Jyvaeskylae. The measurements yielded a rotational band built on the ground state of 246 Fm. This band has been observed up to the level 16 + and shows a behaviour quite similar to the neighbouring even-even isotopes, except for the top of the band for which a wider statistics is necessary in order to conclude. (author)

Study of the influence of the shell correction energy on the nuclear reactions leading to the region of the superheavy nuclei

International Nuclear Information System (INIS)

Marchix, A.

2007-11-01

The aim of this work is to study the influence of shell correction energy on the deexcitation of superheavy nuclei. For that purpose, a new statistical code, called Kewpie2, which is based on an original algorithm allowing to have access to very weak probabilities, was developed. The results obtained with Kewpie2 have been compared to the experimental data on residue cross sections obtained by cold fusion (Z=108 to Z=113) and by hot fusion (Z=112, Z=114 and Z=116), as well as data on fission times (Z=114, Z=120 and Z=126). Constraints on the microscopic structure of the studied nuclei have been obtained by means of the shell correction energy. By adjusting the intrinsic parameters of the models of fusion in order to reproduce the data on the fusion cross sections, this study shows the necessity of decreasing very strongly the shell correction energy predicted by the calculations of Moller and Nix, during the study of the residues cross sections as well for the nuclei produced by cold fusion as by hot fusion. On the other hand, during the confrontation of the results of Kewpie2 to the data on mean fission times, it is rather advisable to increase it. A shift of the proton shell closure predicted for Z=114 by the calculations of Moller and Nix towards larger Z would allow to explain these opposite conclusions. In this thesis, we also have shown the significant influence of the inclusion of isomeric states on fission times for the superheavy nuclei. (author)

Annual reports in inorganic and general syntheses 1972

CERN Document Server

Niedenzu, Kurt

1973-01-01

Annual Reports in Inorganic and General Syntheses-1972 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book discusses alkali and alkaline earth elements, alloys, silver, gold, zinc, cadmium, mercury, boron, aluminum, gallium, indium, thallium, yttrium, scandium, lanthanides, actinides, titanium, zirconium, hafnium, Group V and VI transition elements, manganese, technetium, rhenium, iron, cobalt, nickel, ruthenium, osmium, rhodium, and iridium. The text also describes the chemistry of palladium, platinum, silicon, germanium, tin,

Peaceful berkelium

Science.gov (United States)

Trabesinger, Andreas

2017-09-01

The first new element produced after the Second World War has led a rather peaceful life since entering the period table -- until it became the target of those producing superheavy elements, as Andreas Trabesinger describes.

The attenuation of the periodic table

International Nuclear Information System (INIS)

Cook, N.D.

1990-01-01

Unique among models of nuclear structure, the face-centered-cubic (FCC) lattice model predicts the attenuation of the periodic table at Z < 110 and the impossibility of superheavy nuclei. The total binding energies of superheavy nuclei in the FCC model (109 < Z < 127) were calculated on the basis of parameters obtained from a least-squares best-fit for 914 nuclei (Z < 99). No indication of increased stability is found for any of the transuranic elements

Annual reports in inorganic and general syntheses 1973

CERN Document Server

Niedenzu, Kurt

1974-01-01

Annual Reports in Inorganic and General Syntheses-1973 presents an organized annual summary of synthetic developments in inorganic chemistry and its related areas. The book covers the synthetic aspects and structural or mechanistic features of elements, including the main group hydrides, alkali and alkaline earth elements, boron, aluminium, gallium, indium, thallium, silicon, germanium, tin, and lead, nitrogen, phosphorus, arsenic, antimony, bismuth, chalcogens, halogens and pseudohalogens, and noble gases. The text also discusses the synthetic aspects and structural or mechanistic features of

Synthesis of superheavy elements and application of nuclear physics methods in related fields

International Nuclear Information System (INIS)

Flerov, G.

1985-01-01

Heavy ion accelerators are used not only for the synthesis of new elements but also for the production of nuclear filters from polymers. The principle is described of the manufacture of such filters, and their chemical processing. By changes in irradiation conditions and in conditions of chemical leaching, nuclear filters may be obtained of various density, shape and size of pores and with a different angular distribution of tracks in the polymer material. The most frequently used polymer is polyethylene terephthalate film. The uses are described of nuclear filters, such as water treatment in the production of semiconductor instruments, in cryogenic instruments, in the purification concentration and sterilization filtration of viruses and vaccines, etc. Other uses of heavy ion beams are suggested, such as the method of nuclear tracks, the manufacture of membranes with a single opening, the manufacture of laser diaphragms, lithography, etc. (E.S.)

Syntheses and spectroscopic properties of mercury(II) and nickel(II ...

African Journals Online (AJOL)

Syntheses and spectroscopic properties of mercury(II) and nickel(II) ... The complexes were characterized by IR, diffuse reflectance, 1H NMR spectra and elemental ... coordinating through thiolato sulphur and hydrazinic nitrogen atoms.

Mass and angular distributions of the reaction products in heavy ion collisions

Science.gov (United States)

Nasirov, A. K.; Giardina, G.; Mandaglio, G.; Kayumov, B. M.; Tashkhodjaev, R. B.

2018-05-01

The optimal reactions and beam energies leading to synthesize superheavy elements is searched by studying mass and angular distributions of fission-like products in heavy-ion collisions since the evaporation residue cross section consists an ignorable small part of the fusion cross section. The intensity of the yield of fission-like products allows us to estimate the probability of the complete fusion of the interacting nuclei. The overlap of the mass and angular distributions of the fusion-fission and quasifission products causes difficulty at estimation of the correct value of the probability of the compound nucleus formation. A study of the mass and angular distributions of the reaction products is suitable key to understand the interaction mechanism of heavy ion collisions.

Syntheses and studies of organosilicon compounds

Energy Technology Data Exchange (ETDEWEB)

Xie, Ren [Iowa State Univ., Ames, IA (United States)

1999-02-12

The syntheses of polycarbosilanes and polysilanes as silicon carbide ceramic precursors have been active research areas in the Barton Research Group. In this thesis, the work is focused on the preparation of polycarbosilanes and polysilanes as stoichiometric silicon carbide precursor polymers. The syntheses of the precursor polymers are discussed and the conversions of these precursors to silicon carbide via pyrolysis are reported. The XRD pattern and elemental analyses of the resulting silicon carbide ceramics are presented. Silicon monoxide is an important intermediate in the production of silicon metal. The existence of silicon monoxide in gap phase has been widely accepted. In the second part of this thesis, the generation of gaseous silicon monoxide in four different reactors and the reactions of gaseous silicon monoxide towards organic compounds are discussed.

Synthesis of selective extractor for minor actinide elements

Energy Technology Data Exchange (ETDEWEB)

Kim, Jong Seung [Konyang University, Nonsan (Korea); Cho, Moon Hwan [Kangwon National University, Chunchon (Korea)

1998-04-01

To selectively co-separate the lanthanide and actinide elements (MA) such as Am or Cm ion from radioactive waste, synthesis of diamide derivatives has been accomplished. In addition, picoline amide derivatives were also synthesized for selectively separate the minor actinide elements from lanthanide elements. The content of research has don are as follows: (1) synthesis of diamide as co-extractant (2) introduction of n-tetradecyl to increase the lipophilicity (3) Picolyl chloride, intermediate of the final product, was synthesized by improved method rather than reported method. (4) The length of alkyl side chain was adjusted to increase the lipophilicity of free ligand and its derivatives able to selectively separate the actinide metal from lanthanide metal ions was successfully synthesized and determined their purity by analytical instruments. (author). 12 refs., 28 figs.

Shell stabilization of super- and hyperheavy nuclei without magic gaps

International Nuclear Information System (INIS)

Bender, M.; Nazarewicz, W.; Oak Ridge National Lab., TN; Warsaw Univ.; Reinhard, P.G.; Oak Ridge National Lab., TN

2001-05-01

Quantum stabilization of superheavy elements is quantified in terms of the shell-correction energy. We compute the shell correction using self-consistent nuclear models: the non-relativistic Skyrme-Hartree-Fock approach and the relativistic mean-field model, for a number of parametrizations. All the forces applied predict a broad valley of shell stabilization around Z = 120 and N = 172-184. We also predict two broad regions of shell stabilization in hyperheavy elements with N ∼ 258 and N ∼ 308. Due to the large single-particle level density, shell corrections in the superheavy elements differ markedly from those in lighter nuclei. With increasing proton and neutron numbers, the regions of nuclei stabilized by shell effects become poorly localized in particle number, and the familiar pattern of shells separated by magic gaps is basically gone. (orig.)

Spectroscopy of very heavy nuclei with a view to study super-heavy nuclei; Spectroscopie de noyaux tres lourds en vue de l'etude des noyaux super-lourds

Energy Technology Data Exchange (ETDEWEB)

Khalfallah, F

2007-08-15

Within the recent years, the spectroscopic study of single particle orbitals of very heavy elements (VHE) has become possible with the development of increasingly efficient experimental setups. This allows us, through nuclear deformation, to access with these deformed nuclei to orbitals situated around the Fermi level in the spherical superheavy elements (SHE) and learn more about the nuclear structure of these nuclei. The aim of this work is the spectroscopic studies of heavy and very heavy elements. Because of the experimental difficulties associated with the fusion reactions in the VHE region, a detailed optimization studies is essential. Simulation of energy loss and angular straggling of these nuclei due to the interaction in the target and to neutron's evaporation was carried out and allowed us to optimize the angular acceptance of the separators according to the target thickness. An extensive survey and exploration in the VHE region was also conducted on the basis of cross section's systematics in the literature and simulations carried out using the statistical code Hivap. In this framework, the possible extension of the range of validity of a set of Hivap parameters was investigated. This work has enabled us to prepare a list of experiments of interest for the production of very heavy nuclei. In this thesis, our work was concentrated on the spectroscopy of the nuclei No{sup 256} et Rf{sup 256} for which two experimental proposals were accepted. The octupole deformations predicted in the actinides region is studied in another part of this thesis, a part witch is dedicated to the gamma spectroscopy of Pa{sup 223}. The data from a new experiment carried out using the Jurogam-Ritu-Great setup are analysed and compared to previous results. They confirm the octupole deformed shape in this nucleus. (author)

Proceedings of transuranium elements

International Nuclear Information System (INIS)

Anon.

1992-01-01

The identification of the first synthetic elements was established by chemical evidence. Conclusive proof of the synthesis of the first artificial element, technetium, was published in 1937 by Perrier and Segre. An essential aspect of their achievement was the prediction of the chemical properties of element 43, which had been missing from the periodic table and which was expected to have properties similar to those of manganese and rhenium. The discovery of other artificial elements, astatine and francium, was facilitated in 1939-1940 by the prediction of their chemical properties. A little more than 50 years ago, in the spring of 1940, Edwin McMillan and Philip Abelson synthesized element 93, neptunium, and confirmed its uniqueness by chemical means. On August 30, 1940, Glenn Seaborg, Arthur Wahl, and the late Joseph Kennedy began their neutron irradiations of uranium nitrate hexahydrate. A few months later they synthesized element 94, later named plutonium, by observing the alpha particles emitted from uranium oxide targets that had been bombarded with deuterons. Shortly thereafter they proved that is was the second transuranium element by establishing its unique oxidation-reduction behavior. The symposium honored the scientists and engineers whose vision and dedication led to the discovery of the transuranium elements and to the understanding of the influence of 5f electrons on their electronic structure and bonding. This volume represents a record of papers presented at the symposium

Measurement of the first ionization potential of lawrencium, element 103.

Science.gov (United States)

Sato, T K; Asai, M; Borschevsky, A; Stora, T; Sato, N; Kaneya, Y; Tsukada, K; Düllmann, Ch E; Eberhardt, K; Eliav, E; Ichikawa, S; Kaldor, U; Kratz, J V; Miyashita, S; Nagame, Y; Ooe, K; Osa, A; Renisch, D; Runke, J; Schädel, M; Thörle-Pospiech, P; Toyoshima, A; Trautmann, N

2015-04-09

The chemical properties of an element are primarily governed by the configuration of electrons in the valence shell. Relativistic effects influence the electronic structure of heavy elements in the sixth row of the periodic table, and these effects increase dramatically in the seventh row--including the actinides--even affecting ground-state configurations. Atomic s and p1/2 orbitals are stabilized by relativistic effects, whereas p3/2, d and f orbitals are destabilized, so that ground-state configurations of heavy elements may differ from those of lighter elements in the same group. The first ionization potential (IP1) is a measure of the energy required to remove one valence electron from a neutral atom, and is an atomic property that reflects the outermost electronic configuration. Precise and accurate experimental determination of IP1 gives information on the binding energy of valence electrons, and also, therefore, on the degree of relativistic stabilization. However, such measurements are hampered by the difficulty in obtaining the heaviest elements on scales of more than one atom at a time. Here we report that the experimentally obtained IP1 of the heaviest actinide, lawrencium (Lr, atomic number 103), is 4.96(+0.08)(-0.07) electronvolts. The IP1 of Lr was measured with (256)Lr (half-life 27 seconds) using an efficient surface ion-source and a radioisotope detection system coupled to a mass separator. The measured IP1 is in excellent agreement with the value of 4.963(15) electronvolts predicted here by state-of-the-art relativistic calculations. The present work provides a reliable benchmark for theoretical calculations and also opens the way for IP1 measurements of superheavy elements (that is, transactinides) on an atom-at-a-time scale.

ANALISYS OF FRACTIONAL-N FREQUENCY SYNTHESIZERS

Directory of Open Access Journals (Sweden)

Boris I. Shakhtarin

2018-01-01

Full Text Available Modern information and control systems cannot be imagined without synchronization subsystems. These are the basic elements that provide tracking of the frequency and phase of reference and information signals, the evaluation of information parameters, and the synthesis of reference and clock signals. Frequency synthesizers (FS are widely used due to the high speed of frequency setting, a wide range of frequency grids and minimal phase noise in the operating frequency range. Since with the mass appearance of specialized microprocessors and with the improvement of automatic design systems, the feasibility and repeatability of products has become simpler, digital FS are increasingly being used. The most widely used are FS with a frequency divider on digital elements, which serves to convert the signal of a reference oscillator and a controlled generator. For FS using a divisor with an integer division factor in the feedback loop, there are a number of limitations, such as the lower frequency of the FS and the frequency step of the FS. To solve this problem, divisors with fractional-variable division factors in the feedback loop are used, which allow to obtain the required range and the grid frequency step of the FS. The methods of improving the quality of spectral and dynamic characteristics of digital synthesizers in a given band of frequency detuning are analyzed. The principles of the FS operation with a divisor with a fractionalvariable fission coefficient are described, and structural schemes are given. The results of imitation simulation in the Simulink system of the software package MATLAB of frequency synthesizers with a divisor with a fractional-variable fission factor implemented in various ways are presented, and a comparative analysis of the spectral characteristics of the obtained models is carried out. 

Nuclear structure effects in quasifission – understanding the formation of the heaviest elements

Directory of Open Access Journals (Sweden)

Hinde D. J.

2016-01-01

Full Text Available Quasifission is an important process suppressing the fusion of two heavy nuclei in reactions used to create superheavy elements. Quasifission results in rapid separation of the dinuclear system initially formed at contact. Achieving reliable a priori prediction of quasifission probabilities is a very diffcult problem. Through measurements with projectiles from C to Ni, the Australian National University’s Heavy Ion Accelerator Facility and CUBE spectrometer have been used to map out mass-angle distributions (MAD - the fission mass-ratio as a function of centre-of-mass angle. These provide information on quasifission dynamics in the least modeldependent way. Average quasifission time-scales have been extracted, and compared with TDHF calculations of the collisions, with good agreement being found. With the baseline information from the survey of experimental MAD, strong influences of the nuclear structure of the projectile and target nuclei can be clearly determined.

Superheavy research at RIKEN

International Nuclear Information System (INIS)

Morita, Kosuke

2010-01-01

At RIKEN, Japan, we performed experiments to study the productions and decays of the heaviest elements produced by 208 Pb- and 209 Bi- based 'cold fusion' reactions. A gas-filled recoil separator GARIS was used for the study. In the study of 209 Bi( 70 Zn, n) reaction, we observed two decay chains originating from an isotope of the 113th element, 178 113, which were assigned firstly by generic correlation of the alpha decay chains connected into the previously known decay of 266 Bh and 262 Db via previously unknown alpha decays of 278 113, 274 Rg, and 270 Mt. In addition, decay properties of an isotope 266 Bh and its daughter nucleus 262 Db produced by the 248 Cm( 23 Na, 5n) reaction were studied. 266 Bh was clearly identified from the correlation of the known nuclide, 262 Db, providing further confirmation of the discovery of 278 113.

The synthetic elements

Energy Technology Data Exchange (ETDEWEB)

Hoffman, D.C.

1990-05-01

Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered.

The synthetic elements

International Nuclear Information System (INIS)

Hoffman, D.C.

1990-05-01

Prior to 1940, the heaviest element known was uranium, discovered in 1789. Since that time the elements 93 through 109 have been synthesized and identified and the elements 43, 61, 85, and 87 which were missing form the periodic tables of the 1930's have been discovered. The techniques and problems involved in these discoveries and the placement of the transuranium elements in the periodic table will be discussed. The production and positive identification of elements heavier than Md (Z=101), which have very short half-lives and can only be produced an atom-at-a-time, are very difficult and there have been controversies concerning their discovery. Some of the new methods which have been developed and used in these studies will be described. The prospects for production of still heavier elements will be considered

Hirschegg '03: Nuclear structure and dynamics at the limits. Proceedings

International Nuclear Information System (INIS)

Feldmeier, H.; Knoll, J.; Noerenberg, W.; Wambach, J.

2003-01-01

The following topics were dealt with: Nuclear structure ans symmetries, nuclei near the drip line, halo nuclei and nuclear resonances, superheavy elements and fission, fragmentation and multifragmentation, nuclear astrophysics. (HSI)

Eleven new heaviest isotopes of elements Z=105 to Z=117 identified among the products of 249Bk+48Ca reactions

International Nuclear Information System (INIS)

Oganessian, Yu. Ts.; Abdullin, F. Sh.; Dmitriev, S. N.; Itkis, M. G.; Lobanov, Yu. V.; Mezentsev, A. N.; Polyakov, A. N.; Sagaidak, R. N.; Shirokovsky, I. V.; Subbotin, V. G.; Sukhov, A. M.; Tsyganov, Yu. S.; Utyonkov, V. K.; Voinov, A. A.; Vostokin, G. K.; Bailey, P. D.; Benker, D. E.; Ezold, J. G.; Porter, C. E.; Riley, F. D.

2011-01-01

The heaviest isotopes of elements Z=117 to Z=105, 294 117, 293 117, 290 115, 289 115, 286 113, 285 113, 282 Rg, 281 Rg, 278 Mt, 274 Bh, and 270 Db, were identified by means of the Dubna gas-filled recoil separator among the products of the 249 Bk + 48 Ca reaction. The details of the observed six decay chains, indicating the production and decay of isotopes 293 117 and 294 117, are presented and discussed. The decay energies and resulting half-lives of these new nuclei show a strong rise of stability with increasing neutron number, validating the concept of the island of enhanced stability for superheavy nuclei [Oganessian et al., Phys. Rev. Lett. 104, 142502 (2010)].

Probing the stability of superheavy dark matter particles with high-energy neutrinos

International Nuclear Information System (INIS)

Esmaili, Arman; Peres, O.L.G.

2012-01-01

Full text: There is currently mounting evidence for the existence of dark matter in our Universe from various astrophysical and cosmological observations, but the two of the most fundamental properties of the dark matter particle, the mass and the lifetime, are only weakly constrained by the astronomical and cosmological evidence of dark matter. We derive lower limits on the lifetime of dark matter particles with masses in the range 10 TeV - 10 18 GeV from the non-observation of ultrahigh energy neutrinos in the AMANDA, IceCube, Auger and ANITA experiments. All these experiments probe different energy windows and perfectly complement each other. For dark matter particles which produce neutrinos in a two body or a three body decay, we find that the dark matter lifetime must be longer than ∼ 10 26 s for masses between 10 TeV and the Grand Unification scale. We will consider various scenarios where the decay of the dark matter particle produces high energy neutrinos. Neutrinos travel in the Universe without suffering an appreciable attenuation, even for EeV neutrinos, in contrast to photons which rapidly lose their energy via pair production. This remarkable property makes neutrinos a very suitable messenger to constrain the lifetime of superheavy dark matter particles. Finally, we also calculate, for concrete particle physics scenarios, the limits on the strength of the interactions that induce the dark matter decay. (author)

Measurements of distribution coefficient for U and Th on sand stone in synthesized sea water and distilled water

International Nuclear Information System (INIS)

Nakazawa, Toshiyuki; Okada, Kenichi; Saito, Yoshihiko; Shibata, Masahiro; Sasamoto, Hiroshi

2005-01-01

Japan Nuclear Cycle Development Institute (JNC) has developed the sorption database for bentonite and rocks in order to assess the retardation property of important radioactive elements in natural and engineered barriers in the H12 report. However, there are not enough distribution coefficient data for radioactive elements in saline type groundwater in the database. Thus the batch sorption tests were performed for uranium (U) and thorium (Th) in saline type groundwater. For these elements, there are little registration numbers in the JNC's sorption database, and also these elements are important to evaluate the safety of disposal system. The experiments for each radioactive element were performed on the following conditions; U: Kd measurements using the solutions (synthesized sea water and distilled water) reacted with sand stone as a function of carbonate concentration, under reducing conditions. Th: Kd measurements using the solutions (synthesized sea water and distilled water) reacted with sand stone. The results of the experiments are summarized below; In the case of U, Kd was approximately 6.5E-01 - 9.2E-01 m 3 /kg in synthesized sea water. On the other hand, Kd was 2.2E-02 - 2.4E-02 m 3 /kg in the high carbonate solution. And also, Kd was 6.5E-02 - 7.2E-02 m 3 /kg in synthesized sea water adjusted pH 10 and 3.4E-02 - 4.1E-02 m 3 /kg in distilled water adjusted pH 10, respectively. In the case of Th, Kd was measured in synthesized sea water adjusted to pH 10 and in distilled water adjusted to pH 10. At the sorption measurements of Th, precipitation might be occurred by very low solubility of Th. (author)

MicroSISAK for the chemistry of the heaviest elements

International Nuclear Information System (INIS)

Hild, Daniel

2012-01-01

This thesis describes experiments with an apparatus called MicroSISAK which is able to perform liquid-liquid-extraction on a microliter-scale. Two immiscible liquids are mixed in a microstructured mixer unit and separated again via a Teflon membrane. In the first experiments, different extraction systems were explored for elements of the groups 4 and 7 of the periodic table. Their results were compared with those from batch experiments. The initial achieved extraction yields were insufficient for the envisaged experiments, for which reason different modifications were arranged to obtain improvements. With the aid of a heating element, which was connected to the MicroSISAK apparatus, one was able to rise the temperature for the extraction inside. This led to the expected increasing of the extraction yield. Furthermore the MikroSISAK apparatus was modified by the Institut fuer Mikrotechnik Mainz, which had developed and constructed this apparatus. The contact time of the two phases between the mixer and the separation unit was extended. This also led to an increased yield. Now the performance appeared to be sufficient to connect the apparatus to the TRIGAreactor Mainz to perform online-experiments. Fission products (technetium) produced in a nuclear reaction were guided to the MicroSISAK apparatus to separate them and to detect their decay in a γ-ray detector. Apart from the successful separations, the experiments also proved the functionality of a new degasser system and that an adequate detection system can be coupled to MicroSISAK. With this, the prerequisites for the vision of an application of MicroSISAK are realised: The investigation of the chemical properties of short-lived superheavy elements (SHE) at a heavy-ion accelerator. It is obvious to plan such an experiment for the heavy homolog of technetium, element 107, bohrium.

Diffractive optical element for creating visual 3D images.

Science.gov (United States)

Goncharsky, Alexander; Goncharsky, Anton; Durlevich, Svyatoslav

2016-05-02

A method is proposed to compute and synthesize the microrelief of a diffractive optical element to produce a new visual security feature - the vertical 3D/3D switch effect. The security feature consists in the alternation of two 3D color images when the diffractive element is tilted up/down. Optical security elements that produce the new security feature are synthesized using electron-beam technology. Sample optical security elements are manufactured that produce 3D to 3D visual switch effect when illuminated by white light. Photos and video records of the vertical 3D/3D switch effect of real optical elements are presented. The optical elements developed can be replicated using standard equipment employed for manufacturing security holograms. The new optical security feature is easy to control visually, safely protected against counterfeit, and designed to protect banknotes, documents, ID cards, etc.

Strong nonlinear photonic responses from microbiologically synthesized tellurium nanocomposites

Science.gov (United States)

Liao, K.-S.; Wang, Jingyuan; Dias, S.; Dewald, J.; Alley, N.J.; Baesman, S.M.; Oremland, R.S.; Blau, W.J.; Curran, S.A.

2010-01-01

A new class of nanomaterials, namely microbiologically-formed nanorods composed of elemental tellurium [Te(0)] that forms unusual nanocomposites when combined with poly(m-phenylenevinylene-co-2,5-dioctoxy-phenylenevinylene) (PmPV) is described. These bio-nanocomposites exhibit excellent broadband optical limiting at 532 and 1064 nm. Nonlinear scattering, originating from the laser induced solvent bubbles and microplasmas, is responsible for this nonlinear behavior. The use of bacterially-formed Te(0) when combined with an organic chemical host (e.g., PmPV) is a new green method of nanoparticle syntheses. This opens the possibilities of using unique, biologically synthesized materials to advance future nanoelectronic and nanophotonic applications. ?? 2009 Elsevier B.V. All rights reserved.

A novel nanostructure of cadmium oxide synthesized by mechanochemical method

Energy Technology Data Exchange (ETDEWEB)

Tadjarodi, A., E-mail: tajarodi@iust.ac.ir [Research Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran (Iran, Islamic Republic of); Imani, M. [Research Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology, 16846-13114 Tehran (Iran, Islamic Republic of)

2011-11-15

Highlights: {yields} A novel nanostructure of CdO was synthesized by mechanochemical reaction followed by calcination. {yields} Mechanochemical method is a simple and low-cost to synthesize nanomaterials. {yields} The obtained precursor was characterized by FT-IR, NMR techniques and elemental analysis. {yields} SEM images showed cauliflower-like shape of sample with components average diameter of 68 nm. {yields} The rods and tubes bundles with single crystalline nature were revealed by ED pattern and TEM images. -- Abstract: Cauliflower-like cadmium oxide (CdO) nanostructure was synthesized by mechanochemical reaction followed calcination procedure. Cadmium acetate dihydrate and acetamide were used as reagents and the resulting precursor was calcinated at 450 {sup o}C for 2 h in air. The structures of the precursor and resultant product of the heating treatment were characterized using Fourier transform infrared (FT-IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and elemental analysis, X-ray powder diffraction (XRD), energy-dispersive X-ray spectroscopy analysis (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electron diffraction pattern (ED). SEM and TEM images revealed the cauliflower-like morphology of the sample. This structure includes the bundles of rods and tubes in nanoscale, which combine with each other and form the resulting morphology with the average diameter, 68 nm of the components. ED pattern indicated the single crystal nature of the formed bundles.

A novel nanostructure of cadmium oxide synthesized by mechanochemical method

International Nuclear Information System (INIS)

Tadjarodi, A.; Imani, M.

2011-01-01

Highlights: → A novel nanostructure of CdO was synthesized by mechanochemical reaction followed by calcination. → Mechanochemical method is a simple and low-cost to synthesize nanomaterials. → The obtained precursor was characterized by FT-IR, NMR techniques and elemental analysis. → SEM images showed cauliflower-like shape of sample with components average diameter of 68 nm. → The rods and tubes bundles with single crystalline nature were revealed by ED pattern and TEM images. -- Abstract: Cauliflower-like cadmium oxide (CdO) nanostructure was synthesized by mechanochemical reaction followed calcination procedure. Cadmium acetate dihydrate and acetamide were used as reagents and the resulting precursor was calcinated at 450 o C for 2 h in air. The structures of the precursor and resultant product of the heating treatment were characterized using Fourier transform infrared (FT-IR) spectroscopy, nuclear magnetic resonance (NMR) spectroscopy and elemental analysis, X-ray powder diffraction (XRD), energy-dispersive X-ray spectroscopy analysis (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and electron diffraction pattern (ED). SEM and TEM images revealed the cauliflower-like morphology of the sample. This structure includes the bundles of rods and tubes in nanoscale, which combine with each other and form the resulting morphology with the average diameter, 68 nm of the components. ED pattern indicated the single crystal nature of the formed bundles.

First dedicated in-beam X-ray measurement in heavy-ion fusion reactions

Energy Technology Data Exchange (ETDEWEB)

Berner, C. [Technische Universitaet Muenchen, Lehrstuhl E12 (Germany); RIKEN, Research Group for Superheavy Elements (Japan); Henning, W. [Argonne National Laboratory, Physics Division (United States); RIKEN, Research Group for Superheavy Elements (Japan); Muecher, D.; Gernhaeuser, R.; Hellgartner, S.; Maier, L. [Technische Universitaet Muenchen, Lehrstuhl E12 (Germany); Morita, K.; Morimoto, K.; Kaji, D.; Wakabayashi, Y.; Baba, H. [RIKEN, Research Group for Superheavy Elements (Japan); Lutter, R. [Ludwig-Maximilians-Universitaet, Muenchen (Germany)

2016-07-01

We report on an experiment aiming at in-beam X-ray spectroscopy of heavy and superheavy elements (SHE). The goal is to establish K-X-ray spectroscopy as a sensitive tool to identify SHE produced in fusion reactions. SHE, formed after cold or hot fusion, are usually identified via the alpha-decay products, which have to be connected to well-known elements. However, various theories predict spontaneous fission as the dominant decay mode for the daughter nuclides. Additionally, half-lives of these elements are expected to increase to values impeding the identification of SHE solely by their decay. The in-beam identification of the characteristic X-rays would precisely allow to identify the charge number of the produced SHE. Experiments were performed at the RIKEN Nishina Centre for Accelerator based Science by using the gas-filled magnet separator GARIS for superheavy element detection. A high-purity, low-energy planar germanium LEGe-detector was adapted to the GARIS system at the target place for the first time in order to measure the element-characteristic, prompt X-ray emission.

Alpha decay properties of heavy and superheavy elements

Indian Academy of Sciences (India)

region which is smoothly connected by a Yukawa plus exponential potential for the region after separation. Then the potential as a function of r (which is the centre of mass distance .... A 789, 142 (2007). [12] I Muntian, S Hofmann, Z Patyk and A Sobiczewski, Acta Phys. Pol. B 32, 691 (2001). [13] D Ackermann, Nucl. Phys.

Barrier for cold-fusion production of superheavy elements

International Nuclear Information System (INIS)

Ichikawa, Takatoshi; Iwamoto, Akira; Moeller, Peter; Sierk, Arnold J.

2005-01-01

We estimate the fusion-barrier height B fu (two-body) for approaching ions in cold-fusion reactions in a model where the projectile deformation and quadrupole zero-point vibrational energy are taken into account. This barrier height is defined as the barrier energy at the target and projectile separation distance where an original oblate deformation of projectile and/or target caused by a repulsive Coulomb force turns into a large prolate deformation caused by the attractive nuclear force as the target and projectile come closer. The instability develops before touching because the attractive short-range nuclear force overcomes the repulsive Coulomb force and the shape-stabilizing effect of shell structure. The shell structure of the doubly magic 208 Pb target is sufficiently strong that its shape remains very close to spherical in all cases studied here. The fusion potential for approaching ions in the two-body channel is calculated in the macroscopic-microscopic model with the quadrupole vibrational zero-point energy obtained in the WKB approximation. We compare our results with data from 10 experimental cold-fusion reactions and with the Bass barriers. Differences and similarities between the Yukawa-plus-exponential model and the Bass model are discussed. We also calculate five-dimensional potential-energy surfaces for the single compound system and show that well-established fission and fusion valleys are both present. For heavy systems, B fu (two-body) becomes lower than the fission barrier just beyond the ground state of the compound system. In the vicinity of this transition, the optimum collision energy for formation of evaporation residues can be expected to depend in a delicate fashion on the interplay among B fu (two-body) , the fusion valley, the fission barrier of the compound system, and the one- and two-neutron separation energies S 1n and S 2n . We discuss these issues in detail and calculate fission-barrier heights. Except for reactions in which the projectile is doubly magic or near doubly magic, the calculated quantities are consistent with the observed optimal energies for evaporation-residue formation

On the criterion for the optimum choice of a compound nucleus reaction for producing superheavy elements

International Nuclear Information System (INIS)

Aroumougame, R.; Gupta, R.K.

1979-01-01

The possible reaction partners of a cool compound nucleus reaction for the synthesis of the elements Z = 104, 106 and 108 are studied in terms of the potential energy surfaces, interaction barriers and the nuclear shapes calculated within the frame work of the Fragmentation theory based on two centre shell model. An estimate of the total reaction cross-section suggests that for larger fusion probabilities, the mass and charge asymmetries are the only essential criterion for the optimum choice of a cooler compound nuclear reaction. Larger the mass and charge asymmetries, larger is the fusion cross-section. (auth.)

Antibacterial activity of silver nanoparticles synthesized from serine

Energy Technology Data Exchange (ETDEWEB)

Jayaprakash, N. [Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai 600 034 (India); SRM Valliammai Engineering College, Department of Chemistry, Chennai 603 203 (India); Judith Vijaya, J., E-mail: jjvijayaloyola@yahoo.co.in [Catalysis and Nanomaterials Research Laboratory, Department of Chemistry, Loyola College, Chennai 600 034 (India); John Kennedy, L. [Materials Division, School of Advanced Sciences, VIT University, Chennai Campus, Chennai 600 048 (India); Priadharsini, K.; Palani, P. [Department of Center for Advanced Study in Botany, University of Madras, Guindy Campus, Chennai 600 025 (India)

2015-04-01

Silver nanoparticles (Ag NPs) were synthesized by a simple microwave irradiation method using polyvinyl pyrrolidone (PVP) as a capping agent and serine as a reducing agent. UV–Visible spectra were used to confirm the formation of Ag NPs by observing the surface plasmon resonance (SPR) band at 443 nm. The emission spectrum of Ag NPs showed an emission band at 484 nm. In the presence of microwave radiation, serine acts as a reducing agent, which was confirmed by Fourier transformed infrared (FT-IR) spectrum. High-resolution transmission electron microscopy (HR-TEM) and high-resolution scanning electron microscopy (HR-SEM) were used to investigate the morphology of the synthesized sample. These images showed the sphere-like morphology. The elemental composition of the sample was determined by the energy dispersive X-ray analysis (EDX). Selected area electron diffraction (SAED) was used to find the crystalline nature of the Ag NPs. The electrochemical behavior of the synthesized Ag NPs was analyzed by the cyclic voltammetry (CV). Antibacterial experiments showed that the prepared Ag NPs showed relatively similar antibacterial activities, when compared with AgNO{sub 3} against Gram-positive and Gram-negative bacteria. - Highlights: • Microwave irradiation method is used to synthesize silver nanoparticles. • Highly stable silver nanoparticles are produced from serine. • A detailed study of antibacterial activities is discussed. • Formation mechanism of silver microspheres has been proposed.

25 years of innovation in industrial-scale research. Pt. 2

Energy Technology Data Exchange (ETDEWEB)

Kreuz, B

1982-07-01

DESY research centre, the PETRA electron-positron storage ring, recent technological developments, particle physics, quarks, Y-particles, leptons, gluons, heavy ion research at GSI the UNILAC accelerator, fusion, experiments, superheavy elements, ion bombardment and fusion.

Radiochemistry division. Chapter 2

International Nuclear Information System (INIS)

Anon.

In radiochemistry, the experiments made in 1976 were in the following fields: in nuclear chemistry, the study of heavy-ion reaction mechanisms of fusion and fission, quasi-elastic transfer reactions; in radiochemistry the study of the physico-chemical properties of the actinides and transuranium elements and the search for natural superheavy elements [fr

Environmental research on actinide elements

International Nuclear Information System (INIS)

Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G.

1987-08-01

The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers

Effects of a superheavy, weak-isoscalar quark on flavor-changing neutral current processes, especially charge-parity violation in Z0decay

International Nuclear Information System (INIS)

Rivard, M.J.

1987-01-01

A superheavy, weak-isoscalar, Q = -1/3 quark is added to the Standard Model, inducing tree-level flavor-changing neutral currents (TLFCNCs) involving only the Q = -1/3 quarks. Although constrained by current low-energy experimental data to be extremely weak, it is nonetheless found that the tree-level s ↔ d mixing strength could still be large enough to increase the absolute value of r/sub sd/ = [Gamma(Z 0 → anti sd) - (s ↔ d)] Gamma/sub T/(Z 0 → quarks) by a factor of 360 over its Standard Model-predicted upper limit. The K/sub L/ 0 -K/sub s/ 0 mass difference Δm and K/sub L/ 0 -K/sub s/ 0 mixing parameter anti epsilon are used as input to determine the behavior of the tree-level s ↔ d multiplicative mixing parameter

Environmental research on actinide elements

Energy Technology Data Exchange (ETDEWEB)

Pinder, J.E. III; Alberts, J.J.; McLeod, K.W.; Schreckhise, R.G. (eds.)

1987-08-01

The papers synthesize the results of research sponsored by DOE's Office of Health and Environmental Research on the behavior of transuranic and actinide elements in the environment. Separate abstracts have been prepared for the 21 individual papers. (ACR)

The influence of the surprising decay properties of element 108 on search experiments for new elements

International Nuclear Information System (INIS)

Hofmann, S.; Armbruster, P.; Muenzenberg, G.; Reisdorf, W.; Schmidt, K.H.; Burkhard, H.G.; Hessberger, F.P.; Schoett, H.J.; Agarwal, Y.K.; Berthes, G.; Gollerthan, U.; Folger, H.; Hingmann, J.G.; Keller, J.G.; Leino, M.E.; Lemmertz, P.; Montoya, M.; Poppensieker, K.; Quint, B.; Zychor, I.

1986-01-01

Results of experiments to synthesize the heaviest elements are reported. Surprising is the high stability against fission not only of the odd and odd-odd nuclei but also of even isotopes of even elements. Alpha decay data gave an increasing stability of nuclei by shell effects up to 266 109, the heaviest known element. Theoretically, the high stability is explained by an island of nuclei with big quadrupole and hexadecapole deformations around Z=109 and N=162. Future experiments will be planned to prove the island character of these heavy nuclei. (orig.)

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

Science.gov (United States)

Rodin, A. M.; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V.

2010-02-01

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The α-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

International Nuclear Information System (INIS)

Rodin, A. M.; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V.

2010-01-01

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The α-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Application of the mass-spectrometer MASHA for mass-spectrometry and laser-spectroscopy

Energy Technology Data Exchange (ETDEWEB)

Rodin, A. M., E-mail: rodin@nrmail.jinr.ru; Belozerov, A. V.; Dmitriev, S. N.; Oganessian, Yu. Ts.; Sagaidak, R. N.; Salamatin, V. S.; Stepantsov, S. V.; Vanin, D. V. [JINR, Flerov Laboratory of Nuclear Reactions (Russian Federation)

2010-02-15

We report the present status of the mass-spectrometer MASHA (Mass-Analyzer of Supper Heavy Atoms) designed for determination of the masses of superheavy elements. The mass-spectrometer is connected to the U-400M cyclotron of the Flerov Laboratory for Nuclear Reactions (FLNR) JINR, Dubna. The first experiments on mass-measurements for 112 and 114 elements will be performed in the upcoming 2010. For this purpose a hot catcher, based on a graphite stopper, is constructed. The {alpha}-decay of the superheavy nuclides or spontaneous fission products will be detected with a silicon 192 strips detector. The experimental program of future investigations using the technique of a gas catcher is discussed. It should be regarded as an alternative of the classical ISOL technique. The possibilities are considered for using this mass-spectrometer for laser spectroscopy of nuclei far off-stability.

Stability analysis of artificial synthetic overweight elements

International Nuclear Information System (INIS)

Zhou Jian

1990-01-01

Stability of artificial synthetic overweight elements has been analysed theoretically using a diagram of nuclear stability. It is indicated that overweight nucleus can be synthesized only when a certain amount of neutrons participate simultaneously in the synthesis. The maximum number of protons in overweight elements is 1002. The proton number of 'extreme overweight' elements of which the neutron star is possibly composed is in the range from 326 to 1002. It is expected that the mass number of the stable overweight elements with proton number 114 is in the range from 299 to 315

A review on SHE research at GANIL

International Nuclear Information System (INIS)

Stodel, Ch.; Anne, R.; Bouriquet, B.; Cee, R.; France, G. de; Oliveira Santos, F. de; Tourreil, R. de; Grevy, S.; Peghaire, A.; Saint-Laurent, M.-G.; Villari, A. C. C.; Wieleczko, J.-P.; Amar, N.; Peter, J.; Auger, G.; Casandjian, J.-M.; Clement, E.; Dayras, R.; Drouart, A.; Theisen, Ch.

2007-01-01

This report summarizes the experiments relative to Super-Heavy Element studies done at GANIL - CEA - CNRS since 1999. It also gives an overview of future experiments and opportunities offered by SPIRAL 2 and LINAG beams in a medium term.

Optimization of film synthesized rare earth transition metal permanent magnet systems

International Nuclear Information System (INIS)

Cadieu, F.J.

1990-01-01

This report reviews work on the optimization of film synthesized rare earth transition metal permanent magnet systems. Topics include: high coercivity in Sm-Fe-Ti-V, Sm-Fe-V, and two element systems; ThMn 12 type pseudobinary SmFe 12 - X T X ; and sputter process control for the synthesis of precisely textured RE-TM magnetic films. (JL)

Neutron-rich isotopes of the lightest elements

International Nuclear Information System (INIS)

Oganesyan, Yu.Ts.; Penionzhkevich, Yu.Eh.; Kalpakchieva, R.

1989-01-01

A review is presented of the experimental investigations on the stability of very neutron-rich light nuclei carried out at the JINR Laboratory of Nuclear Reactions. Results on mass excess measurements are reported for 4 H, 5 H, 6 H, 7 H and for the superheavy helium isotope 9 He. Some results from the joint JINR-Ganil experiment on the search for and study of new neutron-rich light nuclei are also given. Analyzed are new possibilities for the investigation of multineutron decay of light nuclei. 14 refs.; 10 figs

Study of the properties of the superheavy nuclei Z=117 produced in the 249Bk + 48Ca reaction

International Nuclear Information System (INIS)

Oganessian, Y.T.; Abdullin, F.S.; Dmitriev, S.N.; Itkis, M.G.; Polyakov, A.N.; Sagaidak, R.N.; Shirokovsky, I.V.; Shumeiko, M.V.; Subbotin, V.G.; Sukhov, A.M.; Tsyganov, Y.S.; Utyonkov, V.K.; Voinov, A.A.; Vostokin, G.K.; Alexander, C.; Binder, J.; Boll, R.A.; Ezold, J.; Felker, K.; Miernik, K.; Roberto, J.B.; Rykaczewski, K.P.; Gostic, J.M.; Henderson, R.A.; Moody, K.J.; Shaughnessy, D.H.; Stoyer, M.A.; Stoyer, N.J.; Grzywacz, R.K.; Miller, D.; Hamilton, J.H.; Ramayya, A.V.; Ryabinin, M.A.

2014-01-01

The reaction of 249 Bk with 48 Ca have been reinvestigated to provide new evidence for the discovery of element 117 on a larger number of events. The experiments were performed at five projectile energies and with a total beam dose of 48 Ca of about 4.6*10 19 . Two isotopes 293,294 117 were synthesized in the 249 Bk+ 48 Ca reaction, providing excitation functions and α-decay spectra of the produced isotopes that establishes these nuclei to be the products of the 4n- and 3n-evaporation channels, respectively. Decay properties of 293,294 117 and of all the daughter products agree with the data of the experiment in which these nuclei were synthesized for the first time in 2010. The new 289 115 events, populated by a decay of 293 117, demonstrate the same decay properties as those observed for 289 115 produced in the 243 Am( 48 Ca,2n) reaction thus providing cross-bombardment evidence. In addition, a single decay of 294 118 was observed from the reaction with 249 Cf - a result of the in-growth of 249 Cf in the 249 Bk target. (authors)

Chemistry aided nuclear physics studies

NARCIS (Netherlands)

Even, Julia

2016-01-01

Studies of the superheavy elements bring several challenges through low production yields, short half-lives, and high background rates. This paper describes the possibilities of chemical separations as techniques to overcome the background problematic and to investigate the nuclear properties of the

Characterization of selenium doped silica glasses synthesized by sol-gel method

International Nuclear Information System (INIS)

Kobayashi, R.A.; Toffoli, S.M.

2012-01-01

Selenium is a rare element in nature. It is used in the food, pharmaceutical, and glass industries. In commercial glasses, selenium is the element responsible for most of the pink or light red color, but its effect is primarily dependent on the oxidation state of the element in the glassy matrix. Besides, selenium is highly volatile, and as high as 80 wt% may be lost in the furnace during the industrial glass elaboration. The sol– gel method yields synthesized materials of high purity and homogeneity, and uses low processing temperatures. Samples of silica glass were obtained by sol-gel method, incorporating precursors of selenium, with the main objective of reducing selenium losses during its heating. The results of optical absorption, XRD and thermal analysis (TGA, DSC) of the glasses are presented and discussed. (author)

Towards a Sign Language Synthesizer: a Bridge to Communication Gap of the Hearing/Speech Impaired Community

Science.gov (United States)

Maarif, H. A.; Akmeliawati, R.; Gunawan, T. S.; Shafie, A. A.

2013-12-01

Sign language synthesizer is a method to visualize the sign language movement from the spoken language. The sign language (SL) is one of means used by HSI people to communicate to normal people. But, unfortunately the number of people, including the HSI people, who are familiar with sign language is very limited. These cause difficulties in the communication between the normal people and the HSI people. The sign language is not only hand movement but also the face expression. Those two elements have complimentary aspect each other. The hand movement will show the meaning of each signing and the face expression will show the emotion of a person. Generally, Sign language synthesizer will recognize the spoken language by using speech recognition, the grammatical process will involve context free grammar, and 3D synthesizer will take part by involving recorded avatar. This paper will analyze and compare the existing techniques of developing a sign language synthesizer, which leads to IIUM Sign Language Synthesizer.

Atomic physics

International Nuclear Information System (INIS)

Armbruster, P.; Beyer, H.; Bosch, F.; Dohmann, H.D.; Kozhuharov, C.; Liesen, D.; Mann, R.; Mokler, P.H.

1984-01-01

The heavy ion accelerator UNILAC is well suited to experiments in the field of atomic physics because, with the aid of high-energy heavy ions atoms can be produced in exotic states - that is, heavy atoms with only a few electrons. Also, in close collisions of heavy ions (atomic number Z 1 ) and heavy target atoms (Z 2 ) short-lived quasi-atomic 'superheavy' systems will be formed - huge 'atoms', where the inner electrons are bound in the field of the combined charge Z 1 + Z 2 , which exceeds by far the charge of the known elements (Z <= 109). Those exotic or transient superheavy atoms delivered from the heavy ion accelerator make it possible to study for the first time in a terrestrial laboratory exotic, but fundamental, processes, which occur only inside stars. Some of the basic research carried out with the UNILAC is discussed. This includes investigation of highly charged heavy atoms with the beam-foil method, the spectroscopy of highly charged slow-recoil ions, atomic collision studies with highly ionised, decelerated ions and investigations of super-heavy quasi-atoms. (U.K.)

Nanocrystals-based Macroporous Materials Synthesized by Freeze-drying Combustion

International Nuclear Information System (INIS)

Yan, Ruiqiang; Chen, Yu; Lin, Ye; Chen, Fanglin

2016-01-01

We present a novel freeze-drying combustion method for synthesis of macroporous powders with nano-network, using Sm 0.2 Ce 0.8 O 1.9 (SDC) as an example. The metal nitrate salt solution mixed with glycine is frozen to form homogeneous nitrate/glycine mixture and then freeze-dried through sublimation of ice crystals. Upon combustion of the freeze-dried mixture, SDC powders with macroporous microstructure consisting of 10–20 nm nanocrystals, high surface area and excellent sinterability are achieved. High resolution transmission electron microscopy (HRTEM) analysis indicates that nanodomains due to aggregation/segregation of dopants in the SDC powders obtained from freeze-drying combustion are much smaller than those in the SDC powders synthesized by the conventional nitrate solution combustion approach, demonstrating better elemental homogeneity and improved conductivity. Using low cost precursors and simple processing conditions, freeze-drying combustion can be a versatile method to synthesize nanocrystalline powders with excellent composition homogeneity for broad applications.

20 months UNILAC - first experiments and results

International Nuclear Information System (INIS)

Schwalm, D.

1978-01-01

The first few results obtained with the UNILAC heavy ion accelerator are described in an elementary survey. The results pretain to the fields of solid state research, quasi-atoms, nuclear coulomb excitation, heavy ion fusion and superheavy elements, and deep inelastic heavy ion reactions. (WL) [de

Fission fragment mass and angular distributions

Indian Academy of Sciences (India)

2015-07-22

Jul 22, 2015 ... Synthesis of heavy and superheavy elements is severely hindered by fission and fission-like processes. The probability of these fission-like, non-equilibrium processes strongly depends on the entrance channel parameters. This article attempts to summarize the recent experimental findings and classify the ...

Syntheses and structures of three f-element selenite/hydroselenite compounds

International Nuclear Information System (INIS)

Burns, Wendy L.; Ibers, James A.

2009-01-01

The selenite/hydroselenite compounds Ce(SeO 3 )(HSeO 3 ), Tb(SeO 3 )(HSeO 3 ).2H 2 O, and Cs[U(SeO 3 )(HSeO 3 )].3H 2 O were synthesized by hydrothermal means at 453 K from the reaction of CeO 2 or Tb 4 O 7 or UO 2 with SeO 2 and CsCl (as a mineralizer). Ce(SeO 3 )(HSeO 3 ) crystallizes in the non-centrosymmetric orthorhombic space group Pca2 1 . The structure comprises a two-dimensional network of interconnected CeO 10 bicapped distorted square antiprisms and SeO 3 trigonal pyramids. Tb(SeO 3 )(HSeO 3 ).2H 2 O crystallizes in the non-centrosymmetric orthorhombic space group P2 1 2 1 2 1 . The structure features a two-dimensional layer of interconnected TbO 8 distorted square antiprisms and SeO 3 trigonal pyramids. Cs[U(SeO 3 )(HSeO 3 )].3H 2 O crystallizes in the centrosymmetric monoclinic space group P2 1 /n. The structure consists of two-dimensional layers of interconnected UO 7 pentagonal bipyramids and SeO 3 trigonal pyramids. The layers in all three structures are held together by hydrogen-bonding networks. - Graphical abstract: Structure of Ce[U(SeO 3 )(HSeO 3 )].3H 2 O (Cs, purple; U, black; Se, blue; O, red; O w , green; H, gray).

Organotrichlorogermane synthesis by the reaction of elemental germanium, tetrachlorogermane and organic chloride via dichlorogermylene intermediate.

Science.gov (United States)

Okamoto, Masaki; Asano, Takuya; Suzuki, Eiichi

2004-08-07

Organotrichlorogermanes were synthesized by the reaction of elemental germanium, tetrachlorogermane and organic chlorides, methyl, propyl, isopropyl and allyl chlorides. Dichlorogermylene formed by the reaction of elemental germanium with tetrachlorogermane was the reaction intermediate, which was inserted into the carbon-chlorine bond of the organic chloride to give organotrichlorogermane. When isopropyl or allyl chloride was used as an organic chloride, organotrichlorogermane was formed also in the absence of tetrachlorogermane. These chlorides were converted to hydrogen chloride, which subsequently reacted with elemental germanium to give the dichlorogermylene intermediate. The reaction of elemental germanium, tetrachlorogermane and organic chlorides provides a simple and easy method for synthesizing organotrichlorogermanes, and all the raw materials are easily available.

GSI scientific report 2004

Energy Technology Data Exchange (ETDEWEB)

Grosse, K [ed.

2005-07-01

the following topics are dealt with: The FAIR project, nuclear structure studies, nuclear and quark matter experiments, search for superheavy elements, atomic, plasma, and solid-state physics with heavy ions, radiation research and biophysics with heavy ions, accelerator operations and developments, radiation detection, cancer therapy with ion beams. (HSI)

Nuclear Structure of the Heaviest Elements – Investigated at SHIP-GSI

Directory of Open Access Journals (Sweden)

Heßberger Fritz Peter

2014-03-01

Full Text Available The quest for the heaviest nuclei that can exist is a basic topic in natural science as their stability is characterized by a delicate interplay of short range nuclear forces acting between the nucleons (protons and neutrons and long-range Coulomb forces acting solely between charged particles, i.e. the protons. As the stability of a nucleus is strongly correlated to its structure, understanding the nuclear structure of heaviest nuclei is presently a main challenge of experimental and theoretical investigations concerning the field of Superheavy Elements. At the velocity filter SHIP at GSI Darmstadt an extensive program on nuclear structure investigations has been started about a decade ago. The project covered both as well systematic investigations of single particle levels in odd-mass isotopes populated by α-decay as investigation of two- or fourquasi-particle states forming K isomers and was supplemented by direct mass measurements at SHIPTRAP and investigation of spontaneous fission properties. Recent experimental studies allowed to extend the systematics of low lying levels in N = 151 and N = 153 up to 255Rf and 259Sg, investigation of possible relations between nuclear structure and fission properties of odd-mass nuclei and investigation of shell strengths at N = 152 and towards N = 162.

The evolution of the elements

International Nuclear Information System (INIS)

Williams, P.M.

1978-01-01

It is believed that only the lightest elements, hydrogen and helium, were created during the 'Big Bang' origin of the Universe and that all heavier elements were synthesized by nuclear reactions in stars, the interstellar medium and possibly in 'little bangs' in the nuclei of galaxies. The composition of the interstellar medium has evolved through enrichment by processed material shed by evolving stars and the composition of the Solar System reflects that of the interstellar medium at the time of its formation. Differentiation processes during the evolution of the Solar System and individual planets account for the different compositions of the Sun and the planets. The measurement of the abundance distribution of the elements has become a very powerful tool in the elucidation of the evolution of the Solar System, stars and the Galaxy. This review attempts to trace the formation of the elements in stars and their subsequent evolution. (author)

HISTORY OF THE ORIGIN OF THE CHEMICAL ELEMENTS AND THEIR DISCOVERERS

International Nuclear Information System (INIS)

Holden, N.E.

2001-01-01

What do we mean by a chemical element? A chemical element is matter, all of whose atoms are alike in having the same positive charge on the nucleus and the same number of extra-nuclear electrons. As we shall see in the following elemental review, the origin of the chemical elements show a wide diversity with some of these elements having an origin in antiquity, other elements having been discovered within the past few hundred years and still others have been synthesized within the past fifty years via nuclear reactions on heavy elements since these other elements are unstable and radioactive and do not exist in nature

HISTORY OF THE ORIGIN OF THE CHEMICAL ELEMENTS AND THEIR DISCOVERIES.

Energy Technology Data Exchange (ETDEWEB)

HOLDEN,N.E.

2001-06-29

What do we mean by a chemical element? A chemical element is matter, all of whose atoms are alike in having the same positive charge on the nucleus and the same number of extra-nuclear electrons. As we shall see in the following elemental review, the origin of the chemical elements show a wide diversity with some of these elements having an origin in antiquity, other elements having been discovered within the past few hundred years and still others have been synthesized within the past fifty years via nuclear reactions on heavy elements since these other elements are unstable and radioactive and do not exist in nature.

Copper-indium-gallium-diselenide nanoparticles synthesized by a solvothermal method for solar cell application

Directory of Open Access Journals (Sweden)

Chiou Chuan-Sheng

2017-01-01

Full Text Available Chalcopyrite copper-indium-gallium-diselenide (CIGS nanoparticles are useful for photovoltaic applications. In this study, the synthesis of CIGS powder was examined, and the powder was successfully synthesized using a relatively simple and convenient elemental solvothermal route. From the reactions of elemental Cu, In, Se and Ga(NO33 powders in an autoclave with ethylenediamine as a solvent, spherical CIGS nanoparticles, with diameters ranging from 20-40 nm, were obtained using a temperature of 200°C for 36h. The structure, morphology, chemical composition and optical properties of the as-synthesized CIGS were characterized using X-ray diffraction, transmission electron microscopy, selected area electron diffraction, scanning electron microscopy, inductively coupled plasma-mass spectrometry. In this sample, the mole ratio of Cu:In:Ga:Se was equal to 0.89:0.71:0.29:2.01, and the optical band gap was found to be 1.18 eV. The solar cell obtained a power conversion efficiency of 5.62% under standard air mass 1.5 global illumination.

Exotic nuclei: another aspect of nuclear structure

International Nuclear Information System (INIS)

Dobaczewski, J.; Blumenfeld, Y.; Flocard, H.; Garcia Borge, M.J.; Nowacki, F.; Rombouts, S.; Theisen, Ch.; Marques, F.M.; Lacroix, D.; Dessagne, P.; Gaeggeler, H.

2002-01-01

This document gathers the lectures made at the Joliot Curie international summer school in 2002 whose theme that year was exotic nuclei. There were 11 contributions whose titles are: 1) interactions, symmetry breaking and effective fields from quarks to nuclei; 2) status and perspectives for the study of exotic nuclei: experimental aspects; 3) the pairing interaction and the N = Z nuclei; 4) borders of stability region and exotic decays; 5) shell structure of nuclei: from stability to decay; 6) variational approach of system with a few nucleons; 7) from heavy to super-heavy nuclei; 8) halos, molecules and multi-neutrons; 9) macroscopic approaches for fusion reactions; 10) beta decay: a tool for spectroscopy; 11) the gas phase chemistry of super-heavy elements

Exotic nuclei: another aspect of nuclear structure; Les noyaux exotiques: un autre regard sur la structure nucleaire

Energy Technology Data Exchange (ETDEWEB)

Dobaczewski, J [Warsaw Univ., Institute of Theoretical Physics (Poland); Blumenfeld, Y; Flocard, H; Garcia Borge, M J; Nowacki, F; Rombouts, S; Theisen, Ch; Marques, F M; Lacroix, D; Dessagne, P; Gaeggeler, H

2002-07-01

This document gathers the lectures made at the Joliot Curie international summer school in 2002 whose theme that year was exotic nuclei. There were 11 contributions whose titles are: 1) interactions, symmetry breaking and effective fields from quarks to nuclei; 2) status and perspectives for the study of exotic nuclei: experimental aspects; 3) the pairing interaction and the N = Z nuclei; 4) borders of stability region and exotic decays; 5) shell structure of nuclei: from stability to decay; 6) variational approach of system with a few nucleons; 7) from heavy to super-heavy nuclei; 8) halos, molecules and multi-neutrons; 9) macroscopic approaches for fusion reactions; 10) beta decay: a tool for spectroscopy; 11) the gas phase chemistry of super-heavy elements.

Structural analysis of nanocrystalline ZnTe alloys synthesized by melt quenching technique

Science.gov (United States)

Singh, Harinder; Singh, Tejbir; Thakur, Anup; Sharma, Jeewan

2018-05-01

Nanocrystalline ZnxTe100-x (x=0, 5, 20, 30, 40, 50) alloys have been synthesized using melt quenching technique. Energy-dispersive X-Ray spectroscopy (EDS) has been used to verify the elemental composition of samples. Various absorption modes are recorded from Fourier transform infrared spectroscopy (FTIR) confirming the formation of ZnTe. The structural study has been performed using X-Ray Diffraction (XRD) method. All synthesized samples have been found to be nanocrystalline in nature with average crystallite size in the range from 49.3 nm to 77.1 nm. Results have shown that Zn0Te100 exhibits hexagonal phase that transforms into a cubic ZnTe phase as the amount of zinc is increased. Pure ZnTe phase has been obtained for x = 50. The texture coefficient (Tc) has been calculated to find the prominent orientations of different planes.

G.N. Florov Laboratory of Nuclear Reactions, history and the present day

International Nuclear Information System (INIS)

Szmider, J.

1996-01-01

The scientific activity and review of results attained at Florov Nuclear Reactions Laboratory of the Joined Institute of Nuclear Research, Dubna, have been presented in historical order. Especially the heavy ion cyclotron use for synthesis of new super-heavy elements as well as investigations of their physical and chemical properties have been shown. 1 fig

High-accuracy coupled cluster calculations of atomic properties

Energy Technology Data Exchange (ETDEWEB)

Borschevsky, A. [School of Chemistry, Tel Aviv University, 69978 Tel Aviv, Israel and Centre for Theoretical Chemistry and Physics, The New Zealand Institute for Advanced Study, Massey University Auckland, Private Bag 102904, 0745 Auckland (New Zealand); Yakobi, H.; Eliav, E.; Kaldor, U. [School of Chemistry, Tel Aviv University, 69978 Tel Aviv (Israel)

2015-01-22

The four-component Fock-space coupled cluster and intermediate Hamiltonian methods are implemented to evaluate atomic properties. The latter include the spectra of nobelium and lawrencium (elements 102 and 103) in the range 20000-30000 cm{sup −1}, the polarizabilities of elements 112-114 and 118, required for estimating their adsorption enthalpies on surfaces used to separate them in accelerators, and the nuclear quadrupole moments of some heavy atoms. The calculations on superheavy elements are supported by the very good agreement with experiment obtained for the lighter homologues.

High-accuracy coupled cluster calculations of atomic properties

International Nuclear Information System (INIS)

Borschevsky, A.; Yakobi, H.; Eliav, E.; Kaldor, U.

2015-01-01

The four-component Fock-space coupled cluster and intermediate Hamiltonian methods are implemented to evaluate atomic properties. The latter include the spectra of nobelium and lawrencium (elements 102 and 103) in the range 20000-30000 cm −1 , the polarizabilities of elements 112-114 and 118, required for estimating their adsorption enthalpies on surfaces used to separate them in accelerators, and the nuclear quadrupole moments of some heavy atoms. The calculations on superheavy elements are supported by the very good agreement with experiment obtained for the lighter homologues

Stability of superheavy elements around Z=120 probed by the study of their fission time obtained by the crystal blocking method; Stabilite d'elements superlourds au voisinage de Z=120 testee par l'etude de leurs temps de fission deduits par la methode du blocage cristallin

Energy Technology Data Exchange (ETDEWEB)

Laget, M

2007-10-15

While the existence of an island of stability beyond Z=110 is theoretically acquired, the location of this island ranges from Z=114 to Z=126 depending on models. In this work, the stability of super-heavy nuclei is probed through the study of their fission time. The chosen experimental method, the crystal blocking method, is sensitive to the presence of possible long time components in the fission time distribution which indicates a fission mechanism occurring after the formation of a compound nucleus. The blocking dips were therefore constituted for the various products of the reaction U{sup 238} + Ni (6.6 MeV/A) {yields} 120, the experimental set-up allowing us to clearly identify and select the reaction mechanisms. The comparison of the blocking dip constituted for quasi-elastic scattering events with the one obtained for the fission fragments of a Z=120, combined with the study of kinematical properties of these fission fragments, give evidences of the existence of very long fission times (> 10{sup -18} s) only compatible with a fusion-fission mechanism implying a non vanishing fission barrier height for Z=120. The second part outlines microscopic calculations of fission barrier heights, carried out in the framework of the finite temperature of the Hartree-Fock-Bogoliubov (HFB) theory. Because of the progressive vanishing of the pairing correlation with T, which happens differently at the ground state and at the top of the barrier, B{sub f} first grows until T {approx_equal} 0.8 MeV before dropping with T owing to shell-effects damping with temperature. (author)

Molybdenum carbide-carbon nanocomposites synthesized from a reactive template for electrochemical hydrogen evolution

KAUST Repository

Alhajri, Nawal Saad

2014-01-01

Molybdenum carbide nanocrystals (Mo2C) with sizes ranging from 3 to 20 nm were synthesized within a carbon matrix starting from a mesoporous graphitic carbon nitride (mpg-C3N4) template with confined pores. A molybdenum carbide phase (Mo2C) with a hexagonal structure was formed using a novel synthetic method involving the reaction of a molybdenum precursor with the carbon residue originating from C3N4 under nitrogen at various temperatures. The synthesized nanocomposites were characterized using powder X-ray diffraction (XRD), temperature-programmed reaction with mass spectroscopy (MS), CHN elemental analyses, thermogravimetric analyses (TGA), nitrogen sorption, X-ray photoelectron spectroscopy (XPS), and transmission electron microscopy (TEM). The results indicated that the synthesized samples have different surface structures and compositions, which are accordingly expected to exhibit different electrocatalytic activities toward the hydrogen evolution reaction (HER). Electrochemical measurements demonstrated that the sample synthesized at 1323 K exhibited the highest and most stable HER current in acidic media, with an onset potential of -100 mV vs. RHE, among the samples prepared in this study. This result is attributed to the sufficiently small particle size (∼8 nm on average) and accordingly high surface area (308 m2 g-1), with less oxidized surface entrapped within the graphitized carbon matrix. © 2014 the Partner Organisations.

Theoretical Description of the Fission Process

International Nuclear Information System (INIS)

Nazarewicz, Witold

2009-01-01

Advanced theoretical methods and high-performance computers may finally unlock the secrets of nuclear fission, a fundamental nuclear decay that is of great relevance to society. In this work, we studied the phenomenon of spontaneous fission using the symmetry-unrestricted nuclear density functional theory (DFT). Our results show that many observed properties of fissioning nuclei can be explained in terms of pathways in multidimensional collective space corresponding to different geometries of fission products. From the calculated collective potential and collective mass, we estimated spontaneous fission half-lives, and good agreement with experimental data was found. We also predicted a new phenomenon of trimodal spontaneous fission for some transfermium isotopes. Our calculations demonstrate that fission barriers of excited superheavy nuclei vary rapidly with particle number, pointing to the importance of shell effects even at large excitation energies. The results are consistent with recent experiments where superheavy elements were created by bombarding an actinide target with 48-calcium; yet even at high excitation energies, sizable fission barriers remained. Not only does this reveal clues about the conditions for creating new elements, it also provides a wider context for understanding other types of fission. Understanding of the fission process is crucial for many areas of science and technology. Fission governs existence of many transuranium elements, including the predicted long-lived superheavy species. In nuclear astrophysics, fission influences the formation of heavy elements on the final stages of the r-process in a very high neutron density environment. Fission applications are numerous. Improved understanding of the fission process will enable scientists to enhance the safety and reliability of the nation's nuclear stockpile and nuclear reactors. The deployment of a fleet of safe and efficient advanced reactors, which will also minimize radiotoxic

Institut fuer Kernchemie, Univ. Mainz. Annual report 1983

International Nuclear Information System (INIS)

Weber, M.

1984-01-01

This annual report contains extended abstracts about the work performed at the named institute together with a list of publications and speeches. The work concern fast chemical separations, the detection of short-lived nuclides, mass separations, nuclear spectroscopy, nuclear fission, heavy ion research, superheavy elements, radionuclide ecology, and the operation of the TRIGA Mainz reactor. (HSI) [de

Amino acid linked bromobenzoyl thiourea derivatives: syntheses, characterization and antimicrobial activities

International Nuclear Information System (INIS)

Raheel, A.; Din, I.U.; Badshah, A.; Rauf, M.K.; Andleeb, S.

2016-01-01

Five new bromobenzoyl thiourea derivatives (1-5) linked with different amino acids were synthesized via the reaction of bromobenzoyl chloride with potassium thiocyanide and the corresponding amines. The synthetic compounds were characterized by single crystal XRD, IR and NMR (/sup 1/H- and /sup 13/C-) spectroscopy in addition to elemental analysis and melting point determinations. These compounds were also preliminary analyzed for antifungal and antibacterial activity against different strains of fungi and bacteria, respectively. The data suggest that the compounds exhibited promising antimicrobial activity and may prove potential lead compounds as antimicrobial agent. (author)

Elements of quantum chromodynamics

International Nuclear Information System (INIS)

Bjorken, J.D.

1979-01-01

The subject of quantum chromodynamics is discussed at length. The introduction motivates the exposition and points out the analogies between QCD and QED. Then, after some assumptions about the nature of QCD, a description is given of what the solution of the theory should look like for three stages of complexity: pure QCD with no fermions or other sources, introduction of superheavy quarks, introduction of the light quarks (u, d, s) with vacuum polarization and pair creation. Next, canonical quantization of QCD by use of a Hamiltonian formulation (in A 0 = 0 gauge) is considered; gauge ambiguities, theta vacua, instantons, etc., are encountered. Then the properties of the three stages noted above are discussed in much greater detail. These follow descriptions of the confinement problem and various approaches to it, as well as of more radical alternatives to QCD, such as the string model or the Pati-Salam program. Included in the summary is an assessment of the current situation. 101 references, 23 figures, 2 tables

Comparative catalytic reduction of 4-nitrophenol by polyacrylamide-gold nanocomposite synthesized by hydrothermal autoclaving and conventional heating routes

Science.gov (United States)

Salaheldin, Hosam I.

2017-12-01

Gold nanoparticles (AuNPs) in polymeric polyacrylamide (PAAm) matrix were synthesized using conventional heating and autoclaving thermal techniques. The synthesized Au/PAAm nanocomposite was characterized using UV-vis spectroscopy and high-resolution transmission electron microscopy. The size of the synthesized particles was approximately 6.37 nm and 8.19 nm with the conventional heating and autoclaving thermal techniques, respectively. Electron diffraction x-ray spectroscopy and the Fourier transformation infrared spectroscopy were used for the composition and elemental studies, which confirmed that the Au metallic atoms were synthesized and embedded within a PAAm matrix via a coordination bond between the carbonyl (-CONH2) group and the metallic NPs. X-ray diffraction confirmed the crystalline nature of the fabricated AuNPs with face centered cubic of nanocrystals. The catalytic activity of the as-prepared Au/PAAm nanocomposite for the reduction of 4-nitrophenol to 4-aminophenol was studied in the presence of sodium borohydrate. The synthesized AuNPs had an effective catalytic activity; the smaller NPs synthesized NPs with the conventional heating technique had a higher reaction kinetic rate in comparation with those synthesized with the autoclaving technique. Therefore, the Au/PAAm nanocomposite can be widely used as an eco-friendly, non-toxic, a fast and cost-effective product to remove versatile organic pollutants such as aromatic nitro compounds.

Integrated digital superconducting logic circuits for the quantum synthesizer. Report

International Nuclear Information System (INIS)

Buchholz, F.I.; Kohlmann, J.; Khabipov, M.; Brandt, C.M.; Hagedorn, D.; Balashov, D.; Maibaum, F.; Tolkacheva, E.; Niemeyer, J.

2006-11-01

This report presents the results, which were reached in the framework of the BMBF cooperative plan ''Quantum Synthesizer'' in the partial plan ''Integrated Digital Superconducting Logic Circuits''. As essential goal of the plan a novel instrument on the base of quantum-coherent superconducting circuits should be developed. which allows to generate praxis-relevant wave forms with quantum accuracy, the quantum synthesizer. The main topics of development of the reported partial plan lied at the one hand in the development of integrated, digital, superconducting circuit in rapid-single-flux (RSFQ) quantum logics for the pattern generator of the quantum synthesizer, at the other hand in the further development of the fabrication technology for the aiming of high circuit complexity. In order to fulfil these requirements at the PTB a new design system was implemented, based on the software of Cadence. Together with the required RSFQ extensions for the design of digital superconducting circuits was a platform generated, on which the reachable circuit complexity is exclusively limited by the technology parameters of the available fabrication technology: Physical simulations are with PSCAN up to a complexity of more than 1000 circuit elements possible; furthermore VHDL allows the verification of arbitrarily large circuit architectures. In accordance for this the production line at the PTB was brought to a level, which allows in Nb/Al-Al x O y /Nb SIS technology implementation the fabrication of highly integrable RSFQ circuit architectures. The developed and fabricated basic circuits of the pattern generator have proved correct functionality and reliability in the measuring operation. Thereby for the circular RSFQ shift registers a key role as local memories in the construction of the pattern generator is devolved upon. The registers were realized with the aimed bit lengths up to 128 bit and with reachable signal-processing speeds of above 10 GHz. At the interface RSFQ

The Energetic Trans-Iron Cosmic-ray Experiment (ENTICE)

Science.gov (United States)

Binns, W. R.; Adams. J. H.; Barghouty, A. F.; Christian, E. R.; Cummings, A. C.; Hams, T.; Israel, M. H.; Labrador, A. W.; Leske, R. A.; Link, J. T.;

PULSE SYNTHESIZING GENERATOR

Science.gov (United States)

Kerns, Q.A.

1963-08-01

>An electronlc circuit for synthesizing electrical current pulses having very fast rise times includes several sinewave generators tuned to progressively higher harmonic frequencies with signal amplitudes and phases selectable according to the Fourier series of the waveform that is to be synthesized. Phase control is provided by periodically triggering the generators at precisely controlled times. The outputs of the generators are combined in a coaxial transmission line. Any frequency-dependent delays that occur in the transmission line can be readily compensated for so that the desired signal wave shape is obtained at the output of the line. (AEC)

The RIKEN gas-filled recoil separator and a possible new approach to superheavy elements by the (HI, αxn) reaction

International Nuclear Information System (INIS)

Nomura, T.

1990-10-01

The (HI, αxn) reaction, in which precompound α particle emission takes place, is shown to occur significantly even near the Coulomb barrier. Because the α emission can efficiently cool down a highly excited nucleus both in energy and angular momentum, it is considered to be very effective for production of heavy elements like SHE. However, the angular distributions of residual nuclei produced in this reaction are side-peaked, requiring a recoil-type separator with large angular acceptance when it is applied for collection of the relevant nuclei. A brief description is given about a gas-filled separator recently constructed at RIKEN, which meets the above requirement. (author)

Synthesizing R&D Data: Experiences from the Integrated Manufacturing Technology Roadmap (IMTR) Project

Energy Technology Data Exchange (ETDEWEB)

merrell, m.a.

1999-05-05

IMTR is a tremendous undertaking to assess the current state and future needs of Manufacturing Technology R&D. A follow-on project to the roadmaps is the development and populating of a Gap Analysis database containing current R&D abstracts related to the roadmaps' technical elements. Efficiently identifying the R&D projects within scope presents many travails of synthesizing data from across a wide spectrum. Challenges to this project were directly proportional to the lack of single-source data collections.

Different aspects of nuclear physics from low energies up to intermediate energies

International Nuclear Information System (INIS)

Lallouet, Y.

2011-12-01

This study focuses on different aspects of nuclear physics from low energies to intermediate ones. For the low energies, the nuclear matter is essentially constituted from interacting nucleons. Part I is on the fusion-fission of super-heavy elements, while Part II is on the Skyrme interactions associated sum rules. In the case of the intermediate energies, where the nuclear matter is considered as being an hadronic phase mainly constituted from pions, Part III is focused on nuclear matter relativistic hydrodynamics with spontaneous chiral symmetry breaking. In Part I, the formation and the deexcitation of super-heavy nuclei are being studied. The memory effect must be taken into consideration within the super-heavy nuclei formation dynamics. Therefore we analyzed the formation of compound nuclei including the memory effects. As for the intermediate memory effects some oscillations appear, which is very different from the Markovian dynamics. For super-heavy nuclei deexcitation, the existence of isomeric state within the potential barrier cannot explain the results of experiments performed at GANIL with the crystal blocking technique, and this despite of the fact that it modifies the deexcitation dynamics and increases the fission time. However, this latter study could be useful for the study of the actinides fission. In Part II, the phenomenological Skyrme effective interactions-associated M 1 and M 3 sum rules are being calculated based on their intrinsic definitions. We identify then M 1 up to the tensorial level and M 3 with central potential. In Part III, as for the hadronic matter hydrodynamics being applied to heavy ions collisions, and as a first approach only, we can neglect spontaneous chiral symmetry but certainly not the dissipative impact. (author)

Effect of Rare Earth Element on Microstructure and Properties of in situ Synthesized TiB2/Al Composites

Directory of Open Access Journals (Sweden)

QU Min

2018-03-01

Full Text Available The effect of rare earth element Ce, Sc and Er on TiB2 particles and matrix alloy micros-tructure of TiB2/Al composites was studied with in situ synthesis method. It shows that the addition of rare earth element improves the microstructure and properties of TiB2/Al composites notably. The particles of TiB2 are relatively homogenously distributed as adding 0.3% (mass fraction rare earth element Sc and Er, moreover, it is Er that refines the microstructure of matrix alloy most significantly, then is Sc. Similarly, it is demonstrated that the addition of Sc and Er results in better tensile strength, which is enhanced by 32% and 31%, respectively; the addition of Er also leads to the best ductility by 85% with optimal tensile property. Meanwhile, fracture morphology analysis reveals that the fracture of the composites is microporous gathered ductile fracture when adding Sc and Er. Finally, it is verified that the mechanism of rare earth element on composites lies in two aspects:one is that the addition of rare earth element improves the wettability of the composites and suppresses the agglomeration of TiB2 particles; the other is that the addition of rare earth element refines the microstructure of matrix alloy and then improves the tensile strength of the composites.

Composites comprising biologically-synthesized nanomaterials

Science.gov (United States)

Curran, Seamus; Dias, Sampath; Blau, Werner; Wang, Jun; Oremland, Ronald S; Baesman, Shaun

2013-04-30

The present disclosure describes composite materials containing a polymer material and a nanoscale material dispersed in the polymer material. The nanoscale materials may be biologically synthesized, such as tellurium nanorods synthesized by Bacillus selenitireducens. Composite materials of the present disclosure may have optical limiting properties and find use in optical limiting devices.

Antimicrobial and cytotoxicity effect of silver nanoparticle synthesized by Croton bonplandianum Baill. leaves

Directory of Open Access Journals (Sweden)

K. Khanra

2016-01-01

Full Text Available Objective(s: For the development of reliable, ecofriendly, less expensive process for the synthesis of silver nanoparticles and to evaluate the bactericidal, and cytotoxicity properties of silver nanoparticles synthesized from root extract of Croton bonplandianum, Baill. Materials and Methods: The synthesis of silver nanoparticles by plant part of Croton bonplandianum was carried out.  The formation of nanoparticles was confirmed by Transmission Electron Microscopy (TEM, Scanning Electron Microscopy (SEM, XRD and UV-Vis spectrophotometric analysis.  The biochemical properties were assayed by antibacterial study, cytotoxicity assay using cancer cell line.  Results: The formation of silver nanoparticles was confirmed by UV-VIS spectroscopic analysis which showed absorbance peak at 425 nm.  X-ray diffraction photograph indicated the face centered cubic structure of the synthesized AgNPs.  TEM has displayed the different dimensional images of biogenic silver nanoparticles with particle size distribution ranging from 15-40 nm with an average size of 32 nm. Silver particles are spherical in shape, clustered.  The EDX analysis was used to identify the elemental composition of synthesized AgNPs. Antibacterial activity of the synthesized AgNPs against three Gram positive and Gram negative bacteria strains like Staphylococcus aureus, Escherichia coli and Pseudomonas aeruginosa carried out showed significant zones of inhibition. The cytotoxicity study by AgNPS also showed cytotoxicity on ovarian cancer cell line PA-1 and lung epithelial cancer cell line A549.  Conclusion: The present study confirms that the AgNPs have great promise as antibacterial, and anticancer agent.

Rotating target wheel system for super-heavy element production at ATLAS

CERN Document Server

Greene, J P; Falout, J; Janssens, R V F

2004-01-01

A new scattering chamber housing a large diameter rotating target wheel has been designed and constructed in front of the Fragment Mass Analyzer (FMA) for the production of very heavy nuclei (Z greater than 100) using beams from the Argonne Tandem Linear Accelerator System (ATLAS). In addition to the target and drive system, the chamber is extensively instrumented in order to monitor target performance and deterioration. Capabilities also exist to install rotating entrance and exit windows for gas cooling of the target within the scattering chamber. The design and initial tests are described.

From SRAFAP to SISAK - rapid chemical separations in nuclear research

International Nuclear Information System (INIS)

Herrmann, G.

1988-10-01

The author gives an overview of rapid radiochemical separations, starting from the early experiments done by Rutherford up to the very sophisticated recoil fragment separations by fast on-line methods as an attempt to produce superheavy elements. Main emphasis is given to developments during the last decades and the extensive work performed by collaborators of the Nuclear Chemistry Institute at the University of Mainz. (RB)

Luminescent and photocatalytic properties of cadmium sulfide nanoparticles synthesized via microwave irradiation

International Nuclear Information System (INIS)

Yang Huaming; Huang Chenghuan; Li Xianwei; Shi Rongrong; Zhang Ke

2005-01-01

Uniform cadmium sulfide (CdS) nanoparticles of about 6 nm in crystal size have been successfully synthesized via microwave irradiation. The as-prepared sample has a uniform morphology and high purity. The red photoluminescence spectrum of the CdS nanoparticles displays a strong peak at 602 nm by using a 300 nm excitation wavelength. The photocatalytic oxidation of methyl orange (MeO) in CdS suspensions under ultraviolet illumination was investigated. The results indicate that a low pH value (pH 2.0) and low reaction temperatures (20-30 deg. C) will facilitate the decolorization of the MeO solution. The photodegradation degree decreases with increasing the pH value and temperature of solution. The efficiency of the recycled CdS semiconductor becomes lower due to the deposit of elemental Cd on the CdS surface, which weakens the photocatalytic activity. The luminescent and photocatalytic mechanisms of the as-prepared CdS nanoparticles were primarily discussed. Microwave irradiation is proved to be a convenient, efficient and environmental-friendly one-step route to synthesize nanoparticles

Recent developments in the synthesis of super heavy elements

International Nuclear Information System (INIS)

Ackermann, D.

2001-01-01

Throughout the passed two decades isotopes of the elements with atomic numbers 107-112 have been synthesized and unambiguously identified at the velocity filter SHIP at GSI. In a recent experiment at SHIP the results for element 112 have been confirmed and a third decay chain of the isotope 277 112 has been observed. Cold fusion reactions using Pb- and Bi- targets and evaporation residue(ER)-α-α correlations together with an efficient separation and detection system are the major ingredients for the success of these experiments. The sensitivity limit of the set-up at GSI has reached the 1pb level. For a systematic investigation in this region of the chart of nuclei and to synthesize heavier nuclei this limit has to be pushed to even lower values. An extensive development program is pursued at SHIP in order to reach at least an order of magnitude lower cross sections. Systematic investigations, the construction of decay chain networks and mass measurements are some of the possible approaches to study the decay chains attributed to isotopes of the elements 114, 116 and 118 at Dubna and Berkeley, which are, in contrast to those observed at GSI, not connected to decays of known isotopes. For the Berkeley results, in particular, several trials of confirmation have been undertaken at various laboratories including GSI

Sub-barrier quasifission in heavy element formation reactions with deformed actinide target nuclei

Science.gov (United States)

Hinde, D. J.; Jeung, D. Y.; Prasad, E.; Wakhle, A.; Dasgupta, M.; Evers, M.; Luong, D. H.; du Rietz, R.; Simenel, C.; Simpson, E. C.; Williams, E.

2018-02-01

Background: The formation of superheavy elements (SHEs) by fusion of two massive nuclei is severely inhibited by the competing quasifission process. Low excitation energies favor SHE survival against fusion-fission competition. In "cold" fusion with spherical target nuclei near 208Pb, SHE yields are largest at beam energies significantly below the average capture barrier. In "hot" fusion with statically deformed actinide nuclei, this is not the case. Here the elongated deformation-aligned configurations in sub-barrier capture reactions inhibits fusion (formation of a compact compound nucleus), instead favoring rapid reseparation through quasifission. Purpose: To determine the probabilities of fast and slow quasifission in reactions with prolate statically deformed actinide nuclei, through measurement and quantitative analysis of the dependence of quasifission characteristics at beam energies spanning the average capture barrier energy. Methods: The Australian National University Heavy Ion Accelerator Facility and CUBE fission spectrometer have been used to measure fission and quasifission mass and angle distributions for reactions with projectiles from C to S, bombarding Th and U target nuclei. Results: Mass-asymmetric quasifission occurring on a fast time scale, associated with collisions with the tips of the prolate actinide nuclei, shows a rapid increase in probability with increasing projectile charge, the transition being centered around projectile atomic number ZP=14 . For mass-symmetric fission events, deviations of angular anisotropies from expectations for fusion fission, indicating a component of slower quasifission, suggest a similar transition, but centered around ZP˜8 . Conclusions: Collisions with the tips of statically deformed prolate actinide nuclei show evidence for two distinct quasifission processes of different time scales. Their probabilities both increase rapidly with the projectile charge. The probability of fusion can be severely

Attempt to produce silicide fuel elements in Indonesia

International Nuclear Information System (INIS)

Soentono, S.; Suripto, A.

1991-01-01

After the successful experiment to produce U 3 Si 2 powder and U 3 Si 2 -Al fuel plates using depleted U and Si of semiconductor quality, silicide fuel was synthesized using x -Al available at the Fuel Element Production Installation (FEPI) at Serpong, Indonesia. Two full-size U 3 Si 2 -Al fuel elements, having similar specifications to the ones of U 3 O 8 -Al for the RSG-GAS (formerly known as MPR-30), have been produced at the FEPI. All quality controls required have been imposed to the feeds, intermediate, as well as final products throughout the production processes of the two fuel elements. The current results show that these fuel elements are qualified from fabrication point of view, therefore it is expected that they will be permitted to be tested in the RSG-GAS, sometime by the end of 1989, for normal (∝50%) and above normal burn-up. (orig.)

First superheavy element experiments at the GSI recoil separator TASCA: The production and decay of element 114 in the 244Pu(48Ca,3-4n) reaction

International Nuclear Information System (INIS)

Gates, J. M.; Duellmann, Ch. E.; Schaedel, M.; Ackermann, D.; Block, M.; Bruechle, W.; Essel, H. G.; Hartmann, W.; Hessberger, F. P.; Huebner, A.; Jaeger, E.; Khuyagbaatar, J.; Kindler, B.; Krier, J.; Kurz, N.; Lommel, B.; Schaffner, H.; Schausten, B.; Schimpf, E.; Steiner, J.

2011-01-01

Experiments with the new recoil separator, Transactinide Separator and Chemistry Apparatus (TASCA), at the GSI were performed by using beams of 48 Ca to irradiate targets of 206-208 Pb, which led to the production of 252-254 No isotopes. These studies allowed for evaluation of the performance of TASCA when coupled to a new detector and electronics system. By following these studies, the isotopes of element 114 ( 288-291 114) were produced in irradiations of 244 Pu targets with 48 Ca beams at compound nucleus excitation energies around 41.7 and 37.5 MeV, demonstrating TASCA's ability to perform experiments with picobarn-level cross sections. A total of 15 decay chains were observed and were assigned to the decay of 288-291 114. A new α-decay branch in 281 Ds was observed, leading to the new nucleus 277 Hs.

New elements - approaching Z=114

International Nuclear Information System (INIS)

Hofmann, S.

1998-03-01

The search for new elements is part of the broader field of investigations of nuclei at the limits of stability. In two series of experiments at SHIP, six new elements (Z=107-112) were synthesized via fusion reactions using 1n-deexcitation channels and lead or bismuth targets. The isotopes were unambiguously identified by means of α-α correlations. Not fission, but alpha decay is the dominant decay mode. The collected decay data establish a means of comparison with theoretical data. This aids in the selection of appropriate models that describe the properties of known nuclei. Predictions based on these models are useful in the preparation of the next generation of experiments. Cross-sections decrease by two orders of magnitude from bohrium (Z=107) to element 112, for which a cross-section of 1 pb was measured. The development of intense beam currents and sensitive detection methods is essential for the production and identification of still heavier elements and new isotopes of already known elements, as well as the measurement of small α-, β- and fission-branching ratios. An equally sensitive set-up is needed for the measurement of excitation functions at low cross-sections. Based on our results, it is likely that the production of isotopes of element 114 close to the island of spherical super heavy elements (SHE) could be achieved by fusion reactions using 208 Pb targets. Systematic studies of the reaction cross-sections indicate that the transfer of nucleons is an important process for the initiation of fusion. The data allow for the fixing of a narrow energy window for the production of SHE using 1n-emission channels. (orig.)

Common elements of adolescent prevention programs: minimizing burden while maximizing reach.

Science.gov (United States)

Boustani, Maya M; Frazier, Stacy L; Becker, Kimberly D; Bechor, Michele; Dinizulu, Sonya M; Hedemann, Erin R; Ogle, Robert R; Pasalich, Dave S

2015-03-01

A growing number of evidence-based youth prevention programs are available, but challenges related to dissemination and implementation limit their reach and impact. The current review identifies common elements across evidence-based prevention programs focused on the promotion of health-related outcomes in adolescents. We reviewed and coded descriptions of the programs for common practice and instructional elements. Problem-solving emerged as the most common practice element, followed by communication skills, and insight building. Psychoeducation, modeling, and role play emerged as the most common instructional elements. In light of significant comorbidity in poor outcomes for youth, and corresponding overlap in their underlying skills deficits, we propose that synthesizing the prevention literature using a common elements approach has the potential to yield novel information and inform prevention programming to minimize burden and maximize reach and impact for youth.

Electron and Nucleon Localization Functions of Oganesson: Approaching the Thomas-Fermi Limit

Science.gov (United States)

Jerabek, Paul; Schuetrumpf, Bastian; Schwerdtfeger, Peter; Nazarewicz, Witold

2018-02-01

Fermion localization functions are used to discuss electronic and nucleonic shell structure effects in the superheavy element oganesson, the heaviest element discovered to date. Spin-orbit splitting in the 7 p electronic shell becomes so large (˜10 eV ) that Og is expected to show uniform-gas-like behavior in the valence region with a rather large dipole polarizability compared to the lighter rare gas elements. The nucleon localization in Og is also predicted to undergo a transition to the Thomas-Fermi gas behavior in the valence region. This effect, particularly strong for neutrons, is due to the high density of single-particle orbitals.

Extracellular Polymeric Substances Govern the Surface Charge of Biogenic Elemental Selenium Nanoparticles

KAUST Repository

Jain, Rohan

2015-02-03

© 2014 American Chemical Society. The origin of the organic layer covering colloidal biogenic elemental selenium nanoparticles (BioSeNPs) is not known, particularly in the case when they are synthesized by complex microbial communities. This study investigated the presence of extracellular polymeric substances (EPS) on BioSeNPs. The role of EPS in capping the extracellularly available BioSeNPs was also examined. Fourier transform infrared (FT-IR) spectroscopy and colorimetric measurements confirmed the presence of functional groups characteristic of proteins and carbohydrates on the BioSeNPs, suggesting the presence of EPS. Chemical synthesis of elemental selenium nanoparticles in the presence of EPS, extracted from selenite fed anaerobic granular sludge, yielded stable colloidal spherical selenium nanoparticles. Furthermore, extracted EPS, BioSeNPs, and chemically synthesized EPS-capped selenium nanoparticles had similar surface properties, as shown by ζ-potential versus pH profiles and isoelectric point measurements. This study shows that the EPS of anaerobic granular sludge form the organic layer present on the BioSeNPs synthesized by these granules. The EPS also govern the surface charge of these BioSeNPs, thereby contributing to their colloidal properties, hence affecting their fate in the environment and the efficiency of bioremediation technologies.

Photodeposited diffractive optical elements of computer generated masks

International Nuclear Information System (INIS)

Mirchin, N.; Peled, A.; Baal-Zedaka, I.; Margolin, R.; Zagon, M.; Lapsker, I.; Verdyan, A.; Azoulay, J.

2005-01-01

Diffractive optical elements (DOE) were synthesized on plastic substrates using the photodeposition (PD) technique by depositing amorphous selenium (a-Se) films with argon lasers and UV spectra light. The thin films were deposited typically onto polymethylmethacrylate (PMMA) substrates at room temperature. Scanned beam and contact mask modes were employed using computer-designed DOE lenses. Optical and electron micrographs characterize the surface details. The films were typically 200 nm thick

Study of the influence of the shell correction energy on the nuclear reactions leading to the region of the superheavy nuclei; Etude de l'influence de l'energie de correction de couches sur les reactions nucleaires menant a la region des noyaux superlourds

Energy Technology Data Exchange (ETDEWEB)

Marchix, A

2007-11-15

The aim of this work is to study the influence of shell correction energy on the deexcitation of superheavy nuclei. For that purpose, a new statistical code, called Kewpie2, which is based on an original algorithm allowing to have access to very weak probabilities, was developed. The results obtained with Kewpie2 have been compared to the experimental data on residue cross sections obtained by cold fusion (Z=108 to Z=113) and by hot fusion (Z=112, Z=114 and Z=116), as well as data on fission times (Z=114, Z=120 and Z=126). Constraints on the microscopic structure of the studied nuclei have been obtained by means of the shell correction energy. By adjusting the intrinsic parameters of the models of fusion in order to reproduce the data on the fusion cross sections, this study shows the necessity of decreasing very strongly the shell correction energy predicted by the calculations of Moller and Nix, during the study of the residues cross sections as well for the nuclei produced by cold fusion as by hot fusion. On the other hand, during the confrontation of the results of Kewpie2 to the data on mean fission times, it is rather advisable to increase it. A shift of the proton shell closure predicted for Z=114 by the calculations of Moller and Nix towards larger Z would allow to explain these opposite conclusions. In this thesis, we also have shown the significant influence of the inclusion of isomeric states on fission times for the superheavy nuclei. (author)

Synthesizing A Phase Changing Bistable Electroactive Polymer And Silver Nanoparticles Coated Fabric As A Resistive Heating Element

Science.gov (United States)

Ren, Zhi

Transducer technologies that convert energy from one form to another (e.g. electrical energy to mechanical energy or thermal energy and vise versa) are considered as the basic building blocks of robots and wearable electronics, two of the rapidly emerging technologies that impact our daily life. With an emphasis on developing the essential smart materials, this dissertation focuses on two specific transducer technologies, bistable large-strain electro-mechanical actuation and resistive Joule heating, in pursuit of refreshable Braille electronic displays and wearable thermal management element, respectively. Dielectric elastomers (DEs) have been intensively studied for their promising ability to mimic human muscles in providing efficient electro-mechanical actuation. They exhibit a unique combination of properties, including large strain, fast response, high energy density, mechanical compliancy, lightweight, and low cost. However, the softness of the DE materials, which is a prerequisite for electrically induced large actuation strain, has been hindering their application in adaptive structures. In these applications such as braille displays, a certain amount of mechanical support is necessary in addition to large strains for the device or system to function. Bistable electroactive polymers (BSEP) that leverage the electrically induced large-strain actuation of DE actuators and the bi-stable rigid-to-rigid deformation of shape memory polymers are innovated to provide large electrical actuation strain in their rubbery state and fix the deformation by cooling down to room temperature to incorporate mechanical rigidity. BSEP materials that can suppress electromechanical instability and exhibit stable mechanical properties in the rubbery state are desired. A bimodal BSEP material with a glass transition temperature right above room temperature has been synthesized employing simple UV curing process. The BSEP has a large storage modulus over 1GPa at room temperature

Rare particles

International Nuclear Information System (INIS)

Kutschera, W.

1984-01-01

The use of Accelerator Mass Spectrometry (AMS) to search for hypothetical particles and known particles of rare processes is discussed. The hypothetical particles considered include fractionally charged particles, anomalously heavy isotopes, and superheavy elements. The known particles produced in rare processes discussed include doubly-charged negative ions, counting neutrino-produced atoms in detectors for solar neutrino detection, and the spontaneous emission of 14 C from 223 Ra. 35 references

Thermoelectric properties of high pressure synthesized lithium and calcium double-filled CoSb3

Directory of Open Access Journals (Sweden)

Xiaohui Li

2017-01-01

Full Text Available Lithium and calcium are inefficient filling elements of CoSb3 at ambient pressure, but show nice filling behavior under high pressure. In this work, we synthesized Li/Ca double-filled CoSb3 with high pressure synthesis method. The products show the skutterudite structure of Im3¯ symmetry. Thermoelectric properties were effectively enhanced through Li and Ca co-filling. For the optimal Li0.08Ca0.18Co4Sb12 sample, the power factor maintains a relatively high value over the whole measurement temperature range and peaks at 4700μWm−1K−2, meanwhile the lattice thermal conductivity is greatly suppressed, leading to a maximal ZT of 1.18 at 700 K. Current work demonstrates high pressure synthesis as an effective method to produce multiple elemental filled CoSb3 skutterudites.

Variational approach to probabilistic finite elements

Science.gov (United States)

Belytschko, T.; Liu, W. K.; Mani, A.; Besterfield, G.

1991-08-01

Probabilistic finite element methods (PFEM), synthesizing the power of finite element methods with second-moment techniques, are formulated for various classes of problems in structural and solid mechanics. Time-invariant random materials, geometric properties and loads are incorporated in terms of their fundamental statistics viz. second-moments. Analogous to the discretization of the displacement field in finite element methods, the random fields are also discretized. Preserving the conceptual simplicity, the response moments are calculated with minimal computations. By incorporating certain computational techniques, these methods are shown to be capable of handling large systems with many sources of uncertainties. By construction, these methods are applicable when the scale of randomness is not very large and when the probabilistic density functions have decaying tails. The accuracy and efficiency of these methods, along with their limitations, are demonstrated by various applications. Results obtained are compared with those of Monte Carlo simulation and it is shown that good accuracy can be obtained for both linear and nonlinear problems. The methods are amenable to implementation in deterministic FEM based computer codes.

Electrochemical synthesis of transition element complexes with carboxyl- and carbonyl-containing ligands

International Nuclear Information System (INIS)

Frolov, V.Yu.; Bolotin, S.N.; Panyushkin, V.T.

2005-01-01

Complexes of d- and f-elements (E = Cu, Ni, Zn, Nd, Tb, Pr, Gd, Er) with carboxyl- and carbonyl-containing ligands were synthesized by the electrochemical method. The products were characterized by elemental analysis, thermal gravimetric analysis and IR spectra. The influence exerted by a number of factors on the process course was studied. The dependence of the electro synthesis parameters on the composition of the forming compounds was established. A new method for anodic synthesis of these compounds was developed [ru

CAMAC programmable-control frequency synthesizer

International Nuclear Information System (INIS)

Yumaguzin, T.Kh.; Vyazovkin, D.E.; Nazirov, Eh.P.; Tuktarov, R.F.

1989-01-01

Synthesizer allows to set frequency with 0.015% accuracy and to scan it with variable step. Frequency controlled divider with further summing-up of divided frequency with fundamental one is used in synthesizer, and it has allowed to use digit of the input code and to obtain 3-4 MHz frequency range. Variation of operation flowsheet in the other frequency range is possible. K-155 and K-531 series microcircuits were used during development

Ion beam analysis of zeolites type Li-ABW synthesized by hydrothermal method

Energy Technology Data Exchange (ETDEWEB)

Andrade, E.; De Lucio, O. G.; Solis, C.; Zavala, E. P.; Cruz, J. [UNAM, Instituto de Fisica, Circuito Exterior, Ciudad Universitaria, 04510 Mexico D. F. (Mexico); Alfaro, S.; Rodriguez, C.; Valenzuela, M. A. [IPN, Escuela Superior de Ingenieria Quimica e Industrias Extractivas, Laboratorio de Catalisis y Materiales, Zacantenco, 07738 Mexico D. F. (Mexico); Rocha, M. F. [IPN, Escuela Superior de Ingenieria Mecanica y Electrica, Av. Instituto Politecnico Nacional s/n, Col. Lindavista, 07738 Mexico D. F. (Mexico); Murillo, G.; Policroniades, R. [ININ, Carretera Mexico-Toluca s/n, Ocoyoacac 52750, Estado de Mexico (Mexico)

2010-02-15

This work reports a method to synthesize and characterize Li-ABW zeolites by a hydrothermal method. These materials are good candidates for CO{sub 2} capture because of the high reactivity between the Li{sup +} with CO{sub 2} to form Li{sub 2}CO{sub 3}. We performed and elemental profile concentration using ion beam analysis. The elastic backscattered proton energy spectra from the Al, Si, O and Li nuclei, in combination with the {alpha} particles from the {sup 7}Li ({rho}, {alpha}){sup 4}He nuclear reaction energy spectra, were employed for this task. X-ray diffraction was also applied to determine the crystalline structure. (Author)

Amorphous phase formation in intermetallic Mg2Ni alloy synthesized by ethanol wet milling

International Nuclear Information System (INIS)

Wang, H.-W.; Chyou, S.-D.; Wang, S.-H.; Yang, M.-W.; Hsu, C.-Y.; Tien, H.-C.; Huang, N.-N.

2009-01-01

The hydriding/dehydriding properties of an intermetallic Mg 2 Ni alloy synthesized by wet ball milling in ethanol have been investigated. The appearance of the particle surface after different milling methods is one obvious difference. The alloyed powders prepared by either dry milling or wet milling under ethanol were characterized for phase content by X-ray diffractometer (XRD). The results show that two broad diffuse peaks, which are an ionic-organic-Mg amorphous material, appear in addition to the nickel element peaks. This unexpected amorphous phase has the special hydrogen absorbing/desorbing features.

Big bang photosynthesis and pregalactic nucleosynthesis of light elements

Science.gov (United States)

Audouze, J.; Lindley, D.; Silk, J.

1985-01-01

Two nonstandard scenarios for pregalactic synthesis of the light elements (H-2, He-3, He-4, and Li-7) are developed. Big bang photosynthesis occurs if energetic photons, produced by the decay of massive neutrinos or gravitinos, partially photodisintegrate He-4 (formed in the standard hot big bang) to produce H-2 and He-3. In this case, primordial nucleosynthesis no longer constrains the baryon density of the universe, or the number of neutrino species. Alternatively, one may dispense partially or completely with the hot big bang and produce the light elements by bombardment of primordial gas, provided that He-4 is synthesized by a later generation of massive stars.

Big bang photosynthesis and pregalactic nucleosynthesis of light elements

International Nuclear Information System (INIS)

Audouze, J.; Lindley, D.; Silk, J.; and Laboratoire Rene Bernas, Orsay, France)

1985-01-01

Two nonstandard scenarios for pregalactic synthesis of the light elements ( 2 H, 3 He, 4 He, and 7 Li) are developed. Big bang photosynthesis occurs if energetic photons, produced by the decay of massive neutrinos or gravitinos, partially photodisintegrate 4 He (formed in the standard hot big bang) to produce 2 H and 3 He. In this case, primordial nucleosynthesis no longer constrains the baryon density of the universe, or the number of neutrino species. Alternatively, one may dispense partially or completely with the hot big bang and produce the light elements by bombardment of primordial gas, provided that 4 He is synthesized by a later generation of massive stars

Porous oxides synthesized by the combustion method

International Nuclear Information System (INIS)

Lugo L, V.

2005-01-01

The result of this work, seeks to be a contribution for the treatment of radioactive wastes, with base to the sorption properties that present those porous oxides, synthesized by a method that allows to increase the sorption capacity. The main objective of the present investigation has been the modification of the structural characteristics of the oxides of Fe, Mg and Zn to increase its capacity of sorption of 60 Co in particular. It was studied the effect of the synthesis method by combustion in the inorganic oxides; the obtained solids were characterized using the following techniques: X-ray diffraction (XRD), scanning electron microscopy (SEM), semiquantitative elementary analysis by Dispersive energy spectroscopy (EDS) and determination of surface area by the Brunauner-Emmett-Teller method (BET). Also was carried out batch type experiments for the sorption of Co 2+ , with the purpose of studying the sorption capacity of each one of the prepared oxides. In accordance with that previously exposed, the working plan that was carried out in this investigation is summarized in the following stages: 1. Preparation of inorganic oxides by two different methods, studying the effect of the temperature in the synthesis process. 2. Characterization of the inorganic oxides by XRD, by means of which those were chosen the solids with better properties. 3. Characterization of the inorganic oxides by SEM and EDS where it was studied the morphology of the synthesized materials and the semiquantitative elemental composition. 4. Realization of a sorption experiment type Batch with non radioactive Co 2+ to simulate the sorption of 60 Co and determination of the sorption capacity by means of neutron activation of the non radioactive cobalt. 5. Determination of the surface area by the (BET) technique of the inorganic oxides with better sorption properties. (Author)

Synthesis of new thermoelectrics using modulated elemental reactants

Energy Technology Data Exchange (ETDEWEB)

Hornbostel, M D; Sellinschegg, H; Johnson, D C

1997-07-01

A series of new, metastable ternary crystalline compounds with the skutterudite crystal structure have been synthesized using modulated elemental reactants. The initial reactants are made up of multiple repeats of a {approximately}25 {angstrom} thick unit containing elemental layers of the desired ternary metal, iron and antimony. Low temperature annealing (150 C) results in interdiffusion of the elemental layers to form amorphous reaction intermediates. Annealing these intermediates at temperatures between 200 C and 250 C results in exothermic crystallization of the desired skutterudite crystal structure. Most of the new compounds prepared are only kinetically stable, decomposing exothermically to form thermodynamically more stable mixtures of binary compounds and elements. Low angle x-ray diffraction studies show that the resulting films are exceedingly smooth. These films have an ideal geometry for measuring properties of importance for thermoelectric devices--the Seebeck coefficient and the electrical conductivity. Thermal conductivity can be measured using a modification of the 3{omega} technique of Cahill. Samples can be produced rapidly, allowing for systematic screening and subsequent optimization as a function of composition and doping levels.

Synthesizing Modular Invariants for Synchronous Code

Directory of Open Access Journals (Sweden)

Pierre-Loic Garoche

2014-12-01

Full Text Available In this paper, we explore different techniques to synthesize modular invariants for synchronous code encoded as Horn clauses. Modular invariants are a set of formulas that characterizes the validity of predicates. They are very useful for different aspects of analysis, synthesis, testing and program transformation. We describe two techniques to generate modular invariants for code written in the synchronous dataflow language Lustre. The first technique directly encodes the synchronous code in a modular fashion. While in the second technique, we synthesize modular invariants starting from a monolithic invariant. Both techniques, take advantage of analysis techniques based on property-directed reachability. We also describe a technique to minimize the synthesized invariants.

Nucleus Z=126 with magic neutron number N=184 may be related to the measured Maruhn-Greiner maximum at A/2=155 from compound nuclei at low energy nuclear reactions

Science.gov (United States)

Prelas, M. A.; Hora, H.; Miley, G. H.

2014-07-01

Evaluation of nuclear binding energies from theory close to available measurements of a very high number of superheavy elements (SHE) based on α-decay energies Qα, arrived at a closing shell with a significant neutron number 184. Within the option of several discussed magic numbers for protons of around 120, Bagge's numbers 126 and 184 fit well and are supported by the element generation measurements by low energy nuclear reactions (LENR) discovered in deuterium loaded host metals. These measurements were showing a Maruhn-Greiner maximum from fission of compound nuclei in an excited state with double magic numbers for mutual confirmation.

Nuclides and isotopes. Twelfth edition

International Nuclear Information System (INIS)

Anon.

1977-01-01

This explanatory booklet was designed to be used with the Chart of the Nuclides. It contains a brief history of the atomic theory of matter: ancient speculations, periodic properties of elements (Mendeleev table), radioactivity, early models of atomic structure, the Bohr atom, quantum numbers, nature of isotopes, artificial radioactivity, and neutron fission. Information on the pre-Fermi (natural) nuclear reactor at Oklo and the search for superheavy elements is given. The booklet also discusses information presented on the Chart and its coding: stable nuclides, metastable states, data display and color, isotopic abundances, neutron cross sections, spins and parities, fission yields, half-life variability, radioisotope power and production data, radioactive decay chains, and elements without names. The Periodic Table of the Elements is appended. 3 figures, 3 tables

International symposium on exotic nuclear structures. Book of abstracst

International Nuclear Information System (INIS)

2000-01-01

The following topics were discussed at the meeting: Physics of weakly bound nuclei, neutron skin and halo; Evolution of shell structures for neutron-rich nuclei; Collective excitations in nuclei with exotic nuclear shapes; Cluster structures; Super- and hyperdeformed nuclei, exotic structures in the actinides; Superheavy elements; Towards understanding the structure of nucleons; New experimental techniques, facilities for radioactive beams. All abstracts (75 items) were submitted as full text to the INIS database. (R.P.)

Synthèse des noyaux super-lourds : Rôle de l'analyse d'incertitude dans la modélisation

OpenAIRE

Lu, Hongliang

2015-01-01

The existence of super-heavy elements (SHE) has been predicted by the nuclear shell model. However, thenuclear reaction theory for heavy systems, which is essential for the synthesis of SHE, has not been wellestablished yet. Although we have reached a general agreement on the reaction mechanism, large discrepanciesbetween quantitative predictions still persist because of the presence of the fusion hindrance phenomenon. Thefirst aim of this Ph.D. work is to investigate different models associa...

1973-1975 progress report

International Nuclear Information System (INIS)

This report is a survey of the work done at the CSNSM during the years 1973-1975. Two important parts are studied: firstly in nuclear spectrometry section: radioelements study and neutron activation analysis and datation used for archeology, atomic effects bound to nuclear transitions and heavy-ion reactions; secondly in mass spectrometry section; on-line mass spectrometry, super-heavy elements search in nature, nuclear astrophysics and technical developments in isotopes separators and ion implantation [fr

Determination of 60 Co by means of Neutron Activation Analysis in the sorption of Co in synthesized porous oxides by the combustion method

International Nuclear Information System (INIS)

Lugo, V.; Bulbulian, S.; Urena, F.

2005-01-01

Recently inorganic materials are investigating as sorbent of radioactive pollutants present in water. The inorganic oxides belong to this group of materials. A quick method exists for the obtaining of inorganic oxides, denominated combustion method that could be used to produce porous oxides successfully with good properties for the sorption of radioactive ions. In this investigation, iron oxides, magnesium and zinc were synthesized obtained by the combustion method, comparing them with those synthesized by the calcination method, using two different synthesis temperatures. The obtained solids were characterized by scanning electron microscopy (Sem), by X-ray diffraction (XRD) and by semiquantitative elemental analysis (EDS). After the characterization, the crystalline oxides synthesized by both methods, to temperature of 800 C, were evaluated as sorbents in the removal of Co 2+ ions, through experiments in batch, and using neutron activation analysis, determining the sorption percentage, with this it was concluded that the magnesium oxide produced by combustion it is more effective in the removal of Co 2+ ions than that synthesized by calcination. It was determined the surface area of the magnesium oxides, obtaining a surface area greater for the synthesized oxide by combustion method. (Author)

Nucleosynthesis of heavy elements by the photonuclear reaction

International Nuclear Information System (INIS)

Hayakawa, Takehito

2002-01-01

Nucleosynthesis of heavy elements is important for understanding of the site mechanism in the stellar and cosmochronology. The nuclei heavier than iron have been synthesized mainly by the s-process and the β-decay after the r-process. The light isotope p-nuclei produced by the photonuclear reaction in Type II supernovae explosions. In order to understand the role of each process, the ratios of the processes are calculated. I propose the experimental plan using the photon sources. (author)

Synthesizing dimensional and categorical approaches to personality disorders: refining the research agenda for DSM-V Axis II.

Science.gov (United States)

Krueger, Robert F; Skodol, Andrew E; Livesley, W John; Shrout, Patrick E; Huang, Yueqin

2007-01-01

Personality disorder researchers have long considered the utility of dimensional approaches to diagnosis, signaling the need to consider a dimensional approach for personality disorders in the Diagnostic and Statistical Manual of Mental Disorders, Fifth Edition (DSM-V). Nevertheless, a dimensional approach to personality disorders in DSM-V is more likely to succeed if it represents an orderly and logical progression from the categorical system in DSM-IV. With these considerations and opportunities in mind, the authors sought to delineate ways of synthesizing categorical and dimensional approaches to personality disorders that could inform the construction of DSM-V. This discussion resulted in (1) the idea of having a set of core descriptive elements of personality for DSM-V, (2) an approach to rating those elements for specific patients, (3) a way of combining those elements into personality disorder prototypes, and (4) a revised conception of personality disorder as a construct separate from personality traits. Copyright (c) 2007 John Wiley & Sons, Ltd.

Assessment voice synthesizers for reading in digital books

Directory of Open Access Journals (Sweden)

Sérvulo Fernandes da Silva Neto

2013-07-01

Full Text Available The digital accessibility shows ways to information access in digital media that assist people with different types of disabilities to a better interaction with the computer independent of its limitations. Of these tools are composed by voice synthesizers, that supposedly simplifying their access to any recorded knowledge through digital technologies. However such tools have emerged originally in countries foreign language. Which brings us to the following research problem: the voice synthesizers are appropriate for reading digital books in the Portuguese language? The objective of this study was to analyze and classify different software tools voice synthesizers in combination with software digital book readers to support accessibility to e-books in Portuguese. Through literature review were identified applications software voice synthesizers, composing the sample analyzed in this work. We used a simplified version of the method of Multiple Criteria Decision Support - MMDA, to assess these. In the research 12 were considered readers of e-books and 11 software voice synthesizer, tested with six formats of e-books (E-pub, PDF, HTML, DOC, TXT, and Mobi. In accordance with the results, the software Virtual Vision achieved the highest score. Relative to formats, it was found that the PDF has measured a better score when summed the results of the three synthesizers. In the studied universe contacted that many synthesizers simply cannot be used because they did not support the Portuguese language.

Perception of Paralinguistic Traits in Synthesized Voices

DEFF Research Database (Denmark)

Baird, Alice Emily; Hasse Jørgensen, Stina; Parada-Cabaleiro, Emilia

2017-01-01

Along with the rise of artificial intelligence and the internet-of-things, synthesized voices are now common in daily–life, providing us with guidance, assistance, and even companionship. From formant to concatenative synthesis, the synthesized voice continues to be defined by the same traits we...

R -process Element Cosmic Rays from Neutron Star Mergers

Energy Technology Data Exchange (ETDEWEB)

Komiya, Yutaka; Shigeyama, Toshikazu [Research Center for the Early Universe, Graduate School of Science, University of Tokyo, Hongo 7-3-1, Bunkyo-ku, 113-0033, Tokyo (Japan)

2017-09-10

Neutron star mergers (NSMs) are one of the most plausible sources of r -process elements in the universe. Therefore, NSMs can also be a major source of ultra-heavy elements in cosmic rays. In this paper, we first estimate the contribution of r -process elements synthesized in NSMs to the ultra-heavy element cosmic rays (UHCRs) by calculating transport equations that take into account energy loss processes and spallations. We show that the flux of UHCRs accelerated by the NSMs themselves fluctuates by many orders of magnitude on a timescale of several million years and can overwhelm UHCRs accelerated by supernova remnants (SNRs) after an NSM takes place within a few kiloparsec from the solar system. Experiments with very long exposure times using meteorites as UHCR detectors can detect this fluctuation. As a consequence, we show that if NSMs are the primary source of UHCRs, future experiments using meteorites may be able to reveal the event history of NSMs in the solar vicinity. We also describe a possible difference in the abundance pattern and energy spectrum of UHCRs between NSM and SNR accelerations.

Raman assisted lightwave synthesized frequency sweeper

DEFF Research Database (Denmark)

Pedersen, Anders Tegtmeier; Rottwitt, Karsten

2010-01-01

We present a Lightwave Synthesized Frequency Sweeper comprising a Raman amplifier for loss compensation. The generated pulse train contains 123 pulses and has a flat signal level as well as a low noise level.......We present a Lightwave Synthesized Frequency Sweeper comprising a Raman amplifier for loss compensation. The generated pulse train contains 123 pulses and has a flat signal level as well as a low noise level....

Synthesizing new types of ultrathin 2D metal oxide nanosheets via half-successive ion layer adsorption and reaction

Science.gov (United States)

Gao, Linjie; Li, Yaguang; Xiao, Mu; Wang, Shufang; Fu, Guangsheng; Wang, Lianzhou

2017-06-01

Two-dimensional (2D) metal oxide nanosheets have demonstrated their great potential in a broad range of applications. The existing synthesis strategies are mainly preparing 2D nanosheets from layered and specific transition metal oxides. How to prepare the other types of metal oxides as ultrathin 2D nanosheets remains unsolved, especially for metal oxides containing alkali, alkaline earth metal, and multiple metal elements. Herein, we developed a half-successive ion layer adsorption and reaction (SILAR) method, which could synthesize those types of metal oxides as ultrathin 2D nanosheets. The synthesized 2D metal oxides nanosheets are within 1 nm level thickness and 500 m2 · g-1 level surface area. This method allows us to develop many new types of ultrathin 2D metal oxides nanosheets that have never been prepared before.

Effect of zinc oxide nanoparticles synthesized by a precipitation

Indian Academy of Sciences (India)

ZnO nanoparticles were synthesized by a precipitation method in aqueous media from zinc nitrate hexahydrate and sodium hydroxide. The synthesized ZnO nanoparticles exhibited a crystalline structure with hexagonal structure of the wurtzite. The morphology of the synthesized ZnO nanoparticles presented a spherical ...

Accelerator mass spectrometry - From DNA to astrophysics

International Nuclear Information System (INIS)

Kutschera, W.

2013-01-01

A brief review of accelerator mass spectrometry (AMS) is presented. The present work touches on a few technical aspects and recent developments of AMS, and describes two specific applications of AMS, the dating of human DNA with the 14 C bomb peak and the search for superheavy elements in nature. Since two extended general reviews on technical developments in AMS [1] and applications of AMS [2] will appear in 2013, frequent reference to these reviews is made. (authors)

Studying Nuclear Structure at the extremes with S3

Science.gov (United States)

Piot, Julien

2018-05-01

The in-depth study of the regions of Superheavy elements and the proton drip line around 100Sn are two major challenges of today's Nuclear Physics. Performing detailed spectroscopic studies on these nuclei requires a significant improvement of our detection capabilities. The Super-Separator-Spectrometer S3 is part of the SPIRAL2 facility at GANIL. Its aim is to use the high stable beam currents provided by the new LINAC to reach rare isotopes by fusion-evaporation.

Consequences of fine structure of β-strength function in the nuclear physics and astrophysics

International Nuclear Information System (INIS)

Klapdor, H.V.; Wene, C.O.

1980-01-01

The consequences of structural effects in the β-strength function Ssub(β) in different fields of nuclear physics and astrophysics are considered. The given structure is shown to affect essentially the lifetimes relative to β-decay, emission of delayed particles, delayed fission and, consequently, all the calculations of synthesis of heavy and superheavy elements in astrophysical and thermonuclear processes. A table of experimental procedures applied for studying the β-strength function in different reactions is given

Structural and optical properties of arsenic sulfide films synthesized by a novel PECVD-based approach

Science.gov (United States)

Mochalov, Leonid; Kudryashov, Mikhail; Logunov, Aleksandr; Zelentsov, Sergey; Nezhdanov, Aleksey; Mashin, Alexandr; Gogova, Daniela; Chidichimo, Giuseppe; De Filpo, Giovanni

2017-11-01

A new plasma-enhanced chemical vapor deposition-based (PECVD) approach for synthesizing of As-S films, with As content in the range 60-40 at.%, is demonstrated. The process has been carried out in a low-temperature Ar-plasma, employing for the first time volatile As and S as precursors. Utilization of inorganic elemental precursors, in contrast to the typically used in CVD metal-organic compounds or volatile hydrides/halides of Va- and VIa-group-elements, gives the possibility to reach the highest quality and purity of the As-S ≿halcogenide films. Quantum-chemical calculations have been performed to gain insight into the PECVD As-S chalcogenide films structure and the mechanism of its formation in the plasma discharge. An additional vibrational band near 650 cm-1 corresponding to cycled 2-dimensional units is observed by Raman spectroscopy. The process developed is cost-efficient one due to the very precise control and the long-term stability of the plasma parameters and it possesses a high potential for large-area applications such as fabrication of miniature integrated optical elements and 2D/3D printing of optical devices.

The light element formation: a signature of high energy nuclear astrophysics

International Nuclear Information System (INIS)

Audouze, J.; Meneguzzi, M.; Reeves, H.

1976-01-01

Light elements D, 6 Li, 9 Be, 10 B and 11 B (and possibly also 7 Li) are not produced by the general nucleosynthetic processes occurring in stars. They appear to be synthesized by high energy processes occuring either during the interaction of galactic cosmic rays with the interstellar medium or in supernovae envelopes. These formation processes are discussed. It is emphasized that the most coherent scenario regarding the formation of the light elements is obtained by taking also into account the nuclear processes which may have occurred during hot phases of the early Universe (Big Bang). Implications on chemical evolution of galaxies and on cosmology are briefly recalled. (Auth.)

A new method to synthesize sulfur-doped graphene as effective metal-free electrocatalyst for oxygen reduction reaction

Energy Technology Data Exchange (ETDEWEB)

Zhai, Chunyang; Sun, Mingjuan [School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211 (China); Zhu, Mingshan, E-mail: mingshanzhu@yahoo.com [School of Materials Science and Chemical Engineering, Ningbo University, Ningbo 315211 (China); Song, Shaoqing [School of Chemistry, Biology and Materials Science, East China Institute of Technology, Nanchang 330013 (China); Jiang, Shujuan, E-mail: sjjiang@ecit.edu.cn [School of Chemistry, Biology and Materials Science, East China Institute of Technology, Nanchang 330013 (China)

2017-06-15

Highlights: • S doped graphene was facile synthesized by one-pot solvothermal method. • DMSO acted as S source as well as reaction solvent. • S-RGO worked as an efficient metal-free electrocatalyst for ORR. • S-RGO acted as a promising candidate instead of Pt-based catalyst. - Abstract: The exploration of a metal-free catalyst with highly efficient yet low-cost for the oxygen-reduction reaction (ORR) is under wide spread investigation. In this paper, by using dimethyl sulfoxide (DMSO) as S source as well as solvent, we report a new, low-cost, and facile solvothermal route to synthesize S-doped reduced graphene oxide (S-RGO). The existence of S element in the framework of RGO was solidly confirmed by energy-dispersive X-ray (EDX) and X-ray photoelectron spectroscopy (XPS). The as-synthesized S-RGO can be worked as an efficient metal-free electrocatalyst for ORR. Moreover, compared to commercial Pt/C electrocatalyst, the S-RGO displays superior resistance to crossover effect and stability by evaluating the addition of methanol and CO poisoning experiment. This result not only shows S-RGO as a promising candidate instead of Pt-based catalyst for ORR, but also provides a new approach for the preparation of metal-free electrocatalyst in future.

Temperature dependence of morphology, structural and optical properties of ZnS nanostructures synthesized by wet chemical route

International Nuclear Information System (INIS)

Navaneethan, M.; Archana, J.; Nisha, K.D.; Hayakawa, Y.; Ponnusamy, S.; Muthamizhchelvan, C.

2010-01-01

Research highlights: → ZnS nanoparticles and nanorods have been synthesized by wet chemical route. → Higher annealing temperature influenced the change in morphology due to aggregation of the nanoparticles. → The temperature dependent optical properties were investigated. → Absorption edge of nanoparticles (295 nm) and nanorods (326 nm) were shifted towards shorter wavelength compared to bulk ZnS (337 nm) due to the quantum confinement effect. → ZnS nanoparticles exhibit high photoluminescence intensity than that of ZnS nanorods annealed at 180 o C. - Abstract: ZnS nanostructures have been synthesized by simple wet chemical route and annealed at two different temperatures of 50 o C and 180 o C. From the measurements of transmission electron microscopy and contact-mode atomic force microscopy, it is found that annealed temperature changes the morphology from nanoparticles to nanorods. The optical properties of the synthesized ZnS nanomaterial have been characterized by UV-visible absorption spectroscopy and photoluminescence spectroscopy. The structural and elemental analyses were carried out by powder X-ray diffraction pattern and energy dispersive X-ray absorption spectroscopy, respectively. Absorption edge of the nanoparticles (295 nm) and nanorods (326 nm) was shifted towards shorter wavelength compared to bulk ZnS (337 nm) due to the quantum confinement effect.

In-situ synthesized Ni–Zr intermetallic/ceramic reinforced composite coatings on zirconium substrate by high power diode laser

Energy Technology Data Exchange (ETDEWEB)

Liu, Kun; Li, Yajiang, E-mail: yajli@sdu.edu.cn; Wang, Juan; Ma, Qunshuang

2015-03-05

Highlights: • In-situ synthesized Ni–Zr intermetallics/ceramic reinforced composite coatings. • Si enrichment and Ni replacing site of Si both resulted in forming Zr{sub 5}(Si{sub x}Ni{sub 1−x}){sub 4.} • Microstructure and forming of ZrB{sub 2} depended on affinity of elements and Si/B ratio. - Abstract: Ni–Zr intermetallic/ceramic reinforced composite coatings were in-situ synthesized by laser cladding series of Ni–Cr–B–Si powders on zirconium substrate. Microstructure, phase constituents and microhardness of coatings were investigated by means of optical microscope (OM), scanning electron microscope (SEM), energy dispersive spectrometer (EDS), X-ray diffraction (XRD) and microsclemeter. Results indicated that coatings with metallurgical bonding to substrate consisted of cellular NiZr matrix and massive reinforcements including NiZr{sub 2}, Zr{sub 5}(Si{sub x}Ni{sub 1−x}){sub 4} and ZrB{sub 2}. Morphologies of reinforcements were mainly dominated by temperature gradient and cooling rate from surface to bottom of the coating produced by same powder. In different coatings, microstructure and forming of ZrB{sub 2} mainly depended on affinity of elements and Si/B ratio in different powders. In addition, the mean microhardness of coatings up to 1200–1300 HV{sub 0.2} is nearly 7 times higher than that of R60702 zirconium substrate.

Enantioselective catalytic syntheses of alpha-branched chiral amines

DEFF Research Database (Denmark)

Brase, S.; Baumann, T.; Dahmen, S.

2007-01-01

Chiral amines play a pivotal role in fine chemical and natural product syntheses and the design of novel materials.......Chiral amines play a pivotal role in fine chemical and natural product syntheses and the design of novel materials....

Aeon: Synthesizing Scheduling Algorithms from High-Level Models

Science.gov (United States)

Monette, Jean-Noël; Deville, Yves; van Hentenryck, Pascal

This paper describes the aeon system whose aim is to synthesize scheduling algorithms from high-level models. A eon, which is entirely written in comet, receives as input a high-level model for a scheduling application which is then analyzed to generate a dedicated scheduling algorithm exploiting the structure of the model. A eon provides a variety of synthesizers for generating complete or heuristic algorithms. Moreover, synthesizers are compositional, making it possible to generate complex hybrid algorithms naturally. Preliminary experimental results indicate that this approach may be competitive with state-of-the-art search algorithms.

The development of [18F]FDG synthesizer

International Nuclear Information System (INIS)

Hu, M. G.; Kim, S. W.; Lee, J. Y.; Yang, S. D.; Jun, G. S.

2003-01-01

The automatic system for [ 18 F]FDG production using for the diagnosis of cancer has been developed. This automation system was consisted of a synthesizer module, a PLC based controller and a PMU for graphic user interface. By this system, the radiochemical purity was over 98%, the production yield was over 30% after synthesize and elapsed time was 35 minute

CHEMISRTY OF NOVEL SPIRO OXAZOLO-THIADIAZOLES DERIVATIVES – SYNTHESIS, CHARACTERIZATION AND BIOLOGICAL EVALUATION CHEMISRTY NEUARTIGER SPIRO oxazolo-Thiadiazole DERIVATE - Synthese, Charakterisierung und biologische Bewertung

OpenAIRE

Vijay V. Dabholkar, Abhishek Karekar, Prem Naik & N. B. Shinde

2012-01-01

A series of novel 2-N-acetyl hydrazino,4-acetyl,7-phenyl,9-(substitutedbenzylidine),1-thia, 3,4,8,triaza,6-oxa Spiro[4.4] nona-2,7-diene (4) were synthesized and screened for their antibacterial activity. The structures of the products were confirmed by IR, 1H,13C NMR and elemental analysis.

Spectroscopic identification of rare earth elements in phosphate glass

Science.gov (United States)

Devangad, Praveen; Tamboli, Maktum; Muhammed Shameem, K. M.; Nayak, Rajesh; Patil, Ajeetkumar; Unnikrishnan, V. K.; Santhosh, C.; Kumar, G. A.

2018-01-01

In this work, rare earth-doped phosphate glasses were synthesized and characterized using three different spectroscopic techniques. The absorption spectra of the prepared praseodymium (Pr) and samarium (Sm) doped glasses, recorded by a UV-VIS-NIR spectrophotometer, show the characteristic absorption bands of these elements. To confirm this inference, laser-induced fluorescence spectra of Pr and Sm were obtained at a laser excitation of 442 nm. Their emission bands are reported here. The elemental analysis of these samples was carried out using a laser-induced breakdown spectroscopy (LIBS) system. Characteristic emission lines of Pr and Sm have been identified and reported by the recorded LIBS spectra of glass samples. Results prove that using these three complimentary spectroscopic techniques (absorption, fluorescence and LIBS), we can meaningfully characterize rare earth-doped glass samples.

Syntheses and absorption-structure relationships of some new ...

Indian Academy of Sciences (India)

New biheterocyclic compound was synthesized as starting material to prepare new photosensitizers mono-, tri-, substituted tri-, azadimethine and mixed cyanine dyes. Absorption-structure relationship of the synthesized cyanine dyes were determined by studying their electronic spectral behaviour in ethanol. The structure of ...

The role of the dinuclear system in the processes of nuclear fusion, quasi-fission, fission and cluster formation

International Nuclear Information System (INIS)

Volkov, V.V.

1999-01-01

The nuclear fusion, quasi-fission, fission and cluster formation in an excited nucleus are considered as the processes of the formation and evolution of the dinuclear system. This approach allows one to reveal new aspects of nuclear fusion, to show that quasi-fission plays an important role in nuclear reactions used to synthesise superheavy elements. A qualitative picture is given of the fission process of an excited nucleus and an important role of cluster formation in this process is shown

Distribution of trace elements between clays and zeolites and aqueous solutions similar to sea water

International Nuclear Information System (INIS)

Berger, G.

1992-01-01

The mechanisms of solid-solution partitioning during mineral crystallization in sea water have been investigated for Rb, Cs, Co, Sr, U, Th and lanthanides as trace elements, and Fe, Mg-chlorite/smectites and Na-zeolites as solid phases. These minerals have been synthesized by alteration at 40 o C in saline solutions of silicate glasses of appropriate compositions. The variation of the distribution coefficients (D) with the concentration of the elements as well as competition mechanisms between elements of analogous crystallochemical properties have been studied. The ''trapping'' of trace elements is shown to be governed by two mechanisms, according to D values or to water-rock ratios. At low values of D the incorporation of elements is controlled only by D, whereas at high values it is controlled by the number of available crystallochemical sites. (Author)

Attraction of posture and motion-trajectory elements of conspecific biological motion in medaka fish.

Science.gov (United States)

Shibai, Atsushi; Arimoto, Tsunehiro; Yoshinaga, Tsukasa; Tsuchizawa, Yuta; Khureltulga, Dashdavaa; Brown, Zuben P; Kakizuka, Taishi; Hosoda, Kazufumi

2018-06-05

Visual recognition of conspecifics is necessary for a wide range of social behaviours in many animals. Medaka (Japanese rice fish), a commonly used model organism, are known to be attracted by the biological motion of conspecifics. However, biological motion is a composite of both body-shape motion and entire-field motion trajectory (i.e., posture or motion-trajectory elements, respectively), and it has not been revealed which element mediates the attractiveness. Here, we show that either posture or motion-trajectory elements alone can attract medaka. We decomposed biological motion of the medaka into the two elements and synthesized visual stimuli that contain both, either, or none of the two elements. We found that medaka were attracted by visual stimuli that contain at least one of the two elements. In the context of other known static visual information regarding the medaka, the potential multiplicity of information regarding conspecific recognition has further accumulated. Our strategy of decomposing biological motion into these partial elements is applicable to other animals, and further studies using this technique will enhance the basic understanding of visual recognition of conspecifics.

Solid phase syntheses of oligoureas

Energy Technology Data Exchange (ETDEWEB)

Burgess, K.; Linthicum, D.S.; Russell, D.H.; Shin, H.; Shitangkoon, A.; Totani, R.; Zhang, A.J.; Ibarzo, J. [Texas A& M Univ., College Station, TX (United States)

1997-02-19

Isocyanates 7 were formed from monoprotected diamines 3 or 6, which in turn can be easily prepared from commercially available N-BOC- or N-FMOC-protected amino acid derivatives. Isocyanates 7, formed in situ, could be coupled directly to a solid support functionalized with amine groups or to amino acids anchored on resins using CH{sub 2}Cl{sub 2} as solvent and an 11 h coupling time at 25 {degree}C. Such couplings afforded peptidomimetics with an N-phthaloyl group at the N-terminus. The optimal conditions identified for removal of the N-phthaloyl group were to use 60% hydrazine in DMF for 1-3 h. Several sequences of amino acids coupled to ureas (`peptidic ureas`) and of sequential urea units (`oligoureas`) were prepared via solid phase syntheses and isolated by HPLC. Partition coefficients were measured for two of these peptidomimetics, and their water solubilities were found to be similar to the corresponding peptides. A small library of 160 analogues of the YGGFL-amide sequence was prepared via Houghten`s tea bag methodology. This library was tested for binding to the anti-{beta}-endorphin monoclonal antibody. Overall, this paper describes methodology for solid phase syntheses of oligourea derivatives with side chains corresponding to some of the protein amino acids. The chemistry involved is ideal for high-throughput syntheses and screening operations. 51 refs., 3 figs., 2 tabs.

Substitution of conventional high-temperature syntheses of inorganic compounds by near-room-temperature syntheses in ionic liquids

KAUST Repository

Groh, Matthias Friedrich

2013-01-01

The high-temperature syntheses of the low-valent halogenides P2I4, Te2Br, α-Te4I4, Te4(Al2Cl7)2, Te4(Bi6Cl20), Te8(Bi4Cl14),Bi8(AlCl4)2, Bi6Cl7,and Bi6Br7, as well as of WSCl4 andWOCl4 have been replaced by resource-efficient low-temperature syntheses in room temperature ionic liquids (RTILs). The simple one-pot syntheses generally do not require elaborate equipment such as twozone furnaces or evacuated silica ampoules. Compared to the published conventional approaches, reduction of reaction time (up to 80%) and temperature (up to 500 K) and, simultaneously, an increase in yield were achieved. In the majority of cases, the solid products were phase-pure. X-Ray diffraction on single crystals (redetermination of 11 crystal structures) has demonstrated that the quality of the crystals from RTILs is comparable to that of products obtained by chemical transport reactions. © 2013 Verlag der Zeitschrift für Naturforschung, Tübingen.

Fission delay and GDR γ-ray from very heavy system

International Nuclear Information System (INIS)

Shen, W.Q.; Wang, J.S.; Ye, W.; Cai, Y.H.; Ma, Y.G.; Feng, J.; Fang, D.Q.; Cai, X.Z.

1999-01-01

The study of the fission delay in reaction of 84 Kr+ 27 Al at 10.6 Mev/u and the systematics of fission delay are described. Authors also discussed the possibility to study the GDR γ rays emitted from the super-heavy compound system on the basis of the strong increasing of the GDR γ rays duo to the fission delay. The calculation results of the GDR γ rays from the super-heavy compound system via microscopic semi-classical Vlasov equation and the experimental data analysis for searching the super-heavy compound system via GDR γ were given

Production of building elements based on alkali-activated red clay brick waste

Directory of Open Access Journals (Sweden)

Rafael Andres Robayo-Salazar

2016-09-01

Full Text Available This paper analyzes the feasibility of reusing a red clay brick waste (RCBW in order to produce building elements such as blocks, pavers and tiles, by using the technique of alkaline activation. The production of these building elements was based on the design of a hybrid mortar with 48.61 MPa of compressive strength, at 28 curing days at room temperature (25 °C. The hybrid mortar was synthesized by adding 10% by weight of Portland cement (OPC to the RCBW, Red Clay Brick Waste. As alkaline activators were used commercial industrial grade sodium hydroxide (NaOH and sodium silicate (Na2SiO3. Building elements were physically and mechanically characterized, according to Colombian Technical Standards (NTC. This technology process is presented as an alternative for the reuse of RCBW and its contribution to the environmental sustainability.

Carbon nanotubes doped with trivalent elements by using back - scattering Raman spectroscopy

Directory of Open Access Journals (Sweden)

S. A. Babanejad

2008-12-01

Full Text Available  In this paper by using DC arc discharge method and acetylene gas, as the carbon source, and nitrogen, as the carrier gas, canrbon nanotubes, CNTs, doped with trivalent element boron, B, have been produced. The deposited CNTs on the cathod electrod, which have structural doped properties to boron element, have been collected and after purification have been investigated by back-scattering Raman spectroscopy. The results reveal that the high frequency G mode component in CNTs doped with electron acceptor element, B, shift to higher wavenumbers. The low frequency G mode component which can appear at approximately 1540–1570 cm-1 wavenumber region, called BWF mode, is a sign of metallic CNT. In the synthesized doped CNTs due to the presence of boron dopant, D mode has sharp peaks and has relatively high intensity in the Raman spectra .

Fully automated parallel oligonucleotide synthesizer

Czech Academy of Sciences Publication Activity Database

Lebl, M.; Burger, Ch.; Ellman, B.; Heiner, D.; Ibrahim, G.; Jones, A.; Nibbe, M.; Thompson, J.; Mudra, Petr; Pokorný, Vít; Poncar, Pavel; Ženíšek, Karel

2001-01-01

Roč. 66, č. 8 (2001), s. 1299-1314 ISSN 0010-0765 Institutional research plan: CEZ:AV0Z4055905 Keywords : automated oligonucleotide synthesizer Subject RIV: CC - Organic Chemistry Impact factor: 0.778, year: 2001

Widely tunable THz synthesizer

Science.gov (United States)

Hindle, F.; Mouret, G.; Eliet, S.; Guinet, M.; Cuisset, A.; Bocquet, R.; Yasui, T.; Rovera, D.

2011-09-01

The generation of cw-THz radiation by photomixing is particularly suited to the high resolution spectroscopy of gases; nevertheless, until recently, it has suffered from a lack of frequency metrology. Frequency combs are a powerful tool that can transfer microwave frequency standards to optical frequencies and a single comb has permitted accurate (10-8) THz frequency synthesis with a limited tuning range. A THz synthesizer composed of three extended cavity laser diodes phase locked to a frequency comb has been constructed and its utility for high resolution gas phase spectroscopy demonstrated. The third laser diode allows a larger tuning range of up to 300 MHz to be achieved without the need for large frequency excursions, while the frequency comb provides a versatile link to be established from any traceable microwave frequency standard. The use of a single frequency comb as a reference for all of the cw-lasers eliminates the dependency of synthesized frequency on the carrier envelope offset frequency. This greatly simplifies the frequency comb stabilization requirements and leads to a reduced instrument complexity.

Optical and Electrical Properties of Copper Oxide Thin Films Synthesized by Spray Pyrolysis Technique

Directory of Open Access Journals (Sweden)

S. S. Roy

2015-08-01

Full Text Available Copper oxide (CuO thin films have been synthesized on to glass substrates at different temperatures in the range 250-450 °C by spray pyrolysis technique from aqueous solution using cupric acetate Cu(CH3COO2·H2O as a precursor. The structure of the deposited CuO thin films characterized by X-ray diffraction, the surface morphology was observed by a scanning electron microscope, the presence of elements was detected by energy dispersive X-ray analysis, the optical transmission spectra was recorded by ultraviolet-visible spectroscopy and electrical resistivity was studied by Van-der Pauw method. All the CuO thin films, irrespective of growth temperature, showed a monoclinic structure with the main CuO (111 orientation, and the crystallite size was about 8.4784 Å for the thin film synthesized at 350 °C. The optical transmission of the as-deposited film is found to decrease with the increase of substrate temperature, the optical band gap of the thin films varies from 1.90 to 1.60 eV and the room temperature electrical resistivity varies from 30 to18 Ohm·cm for the films grown at different substrate temperatures.

A frequency tracking synthesizer for beam diagnostic systems

International Nuclear Information System (INIS)

Peterson, D.; Marriner, J.

1991-01-01

In low and medium energy synchrotrons the beam revolution frequency changes by a large factor during the acceleration process. High production rates require that these machines cycle rapidly. In attempting to diagnose instabilities which develop during the acceleration process it is useful to be able to select some frequency segment between revolution harmonics for viewing. Most types of test equipment operating in the frequency domain, such as spectrum analyzers and network analyzers, are not suited to making direct measurements on such rapidly sweeping signals. Ideally, one would want to set the frequency frame of reference to the spot in the accelerating revolution harmonic domain where the measurements are to be made. A scheme using a direct digital synthesizer (DDS) was developed to provide this moving reference frame. This paper describes a synthesizer scheme combining digital and analog synthesizer techniques to allow tracking of signals during acceleration. Virtually any ratio of synthesizer to beam revolution frequency may be generated by this scheme. Details of hardware and measurement results are presented

Sonochemically synthesized Ag nanoparticles as a SERS active substrate and effect of surfactant

Energy Technology Data Exchange (ETDEWEB)

Dar, Nitzan, E-mail: n58987012@mail.ncku.edu.tw [Department of Material Science and Engineering, National Cheng Kung University, Tainan 70101 Taiwan (China); Chen, Kuang-Yu [Department of Material Science and Engineering, National Cheng Kung University, Tainan 70101 Taiwan (China); Nien, Yung-Tang, E-mail: ytnien@nfu.edu.tw [Department of Materials Science and Engineering, National Formosa University, Huwei, Yunlin 63201, Taiwan (China); Perkas, Nina [Institute of nanotechnology and advanced materials, Department of Chemistry, Bar-Ilan University, Ramat-Gan 5290002 (Israel); Gedanken, Aharon, E-mail: Aharon.Gedanken@biu.ac.il [Institute of nanotechnology and advanced materials, Department of Chemistry, Bar-Ilan University, Ramat-Gan 5290002 (Israel); Chen, In-Gann, E-mail: ingann@mail.ncku.edu.tw [Department of Material Science and Engineering, National Cheng Kung University, Tainan 70101 Taiwan (China)

2015-03-15

Highlights: • Solid state Ag SERS active substrates were sonochemically synthesized. • High intensity SERS spectra of both crystal violet and rhodamine 6G were observed. • We discovered that PVP aided synthesized substrates showed higher SERS intensity. - Abstract: Surface enhanced Raman scattering (SERS) enables the detection of substances at low concentrations using silver or gold nanostructure. The SERS technique has many applications, such as environmental detection and biosensing. Sonochemistry is an excellent and cheap deposition technique for coating substrates in a form of nanostructure at ambient temperature. It can also be utilized to prepare large SERS substrates. Here, we used the advantages of sonochemistry to deposit solid SERS substrates immobilized on GaN nanostructure. Morphology was studied by scanning electron microscopy. The elemental composition and the spatial distribution were examined by energy dispersive X-ray spectroscopy. The crystal structure and atomic presence was confirmed by X-ray diffraction. SERS substrates were examined with the analytes crystal violet (10{sup −5} M) and rhodamine 6G (10{sup −6} M), they showed prominent characteristic peaks. We discovered that the SERS intensity of poly-vinyl-pyrrolidinone aided sonochemical deposition of Ag nanoparticles was increased. The reason for the effect is morphological changes of the Ag nanoparticles. Smaller nanoparticles were fabricated, which increase their SERS intensity.

Perspectives for nuclear structure research at GSI: from halo nuclei to superheavy elements

Energy Technology Data Exchange (ETDEWEB)

Muenzenberg, G.

1997-11-01

After a brief overview on recent advances in the investigation of nuclei at the driplines and the upper end of the nuclear table key issues of nuclear structure research as adressed by new theoretical developments will be discussed in context with new developments in heavy-ion accelerators and experimental techniques. (orig.)

Perspectives for nuclear structure research at GSI--from halo nuclei to superheavy elements

International Nuclear Information System (INIS)

Munzenberg, G.

1997-01-01

After a brief overview on recent advances in the investigation of nuclei at the drip lines and the upper end of the nuclear table key issues of nuclear structure research as addressed by new theoretical developments will be discussed in context with new developments in heavy-ion accelerators and experimental techniques

Quantum electrodynamic corrections for the valence shell in heavy many-electron atoms

International Nuclear Information System (INIS)

Thierfelder, C.; Schwerdtfeger, P.

2010-01-01

We present quantum electrodynamic (QED) calculations within the picture of bound-state QED for the frequency-dependent Breit interaction between electrons, the vacuum polarization, and the electron self-energy correction starting from the Dirac-Coulomb Hamiltonian for the ionization potentials of the group 1, 2, 11, 12, 13, and 18 elements of the periodic table, and down to the superheavy elements up to nuclear charge Z=120. The results for the s-block elements are in very good agreement with earlier studies by Labzowsky et al. [Phys. Rev. A 59, 2707 (1999)]. We discuss the influence of the variational versus perturbative treatment of the Breit interaction for valence-space ionization potentials. We argue that the lowest-order QED contributions become as important as the Breit interaction for ionization potentials out of the valence s shell.

Three new Ag(I) coordination architectures based on mixed ligands: Syntheses, structures and photoluminescent properties

Energy Technology Data Exchange (ETDEWEB)

Li, Yamin, E-mail: liyamin@henu.edu.cn [Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Xiao, Changyu; Li, Shu; Chen, Qi; Li, Beibei; Liao, Qian; Niu, Jingyang [Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004 (China)

2013-04-15

Three new silver (I) coordination complexes, [Ag{sub 2}(1,2-bdc)(phdat)]{sub n} (1), [Ag{sub 2}(NO{sub 2}-bdc)(phdat)]{sub n} (2), [Ag{sub 4}(nta){sub 3}(phdat)NO{sub 3}]{sub n} (3) (1,2-bdc=phthalic acid dianion, NO{sub 2}-bdc=5-nitro-1,3-benzenedicarboxylic acid dianion, nta=nicotinic acid anion, phdat=2,4-diamine-6-phenyl-1,3,5-triazine) have been hydrothermally synthesized by the reactions of silver nitrate and phdat with the homologous ligands 1,2-H{sub 2}bdc, NO{sub 2}-H{sub 2}bdc, and Hnta, respectively, and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses thermogravimetric analyses (TGA). The compound 1 exhibits a chiral 3D network with cbs/CrB self-dual topological net, which contains two kinds of single helical chains. For compound 2, the 3D network is comprised of two kinds of similar 2D sheets with the topological symbol of sql-type packed in AABBAA mode by Ag–N/O weakly contacts. And compound 3 has 2D double layer architecture, consisting of the 2D plane with hcb-type topological symbol connected by Ag–O weakly coordinations. The photoluminescent properties associated with the crystal structures of three compounds have also been measured. - Graphical abstract: Three new silver(I) coordination complexes 1–3 have been synthesized and characterized by single-crystal X-ray diffractions, IR spectra, elemental analyses, thermogravimetric analyses (TGA) and photoluminescent spectra. Highlights: ► The compound 1 exhibits a novel chiral 3D network with two kinds of single helical chains. ► 3D or 2D new Ag coordination complexes. ► The photoluminescent properties have been measured.

Microscopic evolution of dielectric nanoparticles at different calcination temperatures synthesized via sol-gel auto-combustion

International Nuclear Information System (INIS)

Adil, Muhammad; Zaid, Hasnah Mohd; Chuan, Lee Kean; Latiff, Noor Rasyada Ahmad; Alta’ee, Ali F.

2015-01-01

Dielectric nano powder synthesis is carried by a simple and fast sol-gel auto-combustion method. The transformation of crystalline phases of as-synthesized nano powders is investigated through the detailed transmission electron microscopy (TEM), revealed the crystallographic alterations and morphological information even at lattice scale. From specific area electron diffraction (SAED) pattern, has specified the d-spacing and corresponding planes supported by the observed lattice fringes. The morphological characterization of nanoparticles is performed through field-emission scanning electron microscopy (FESEM), exhibiting the increment in particle size due to agglomeration with the increase in annealing temperature. Furthermore, EDX pattern has been used to verify the formation of nanoparticles by revealing the presence of required elements

Microscopic evolution of dielectric nanoparticles at different calcination temperatures synthesized via sol-gel auto-combustion

Energy Technology Data Exchange (ETDEWEB)

Adil, Muhammad, E-mail: muhammadadil86@hotmail.com; Zaid, Hasnah Mohd, E-mail: hasnamz@petronas.com.my; Chuan, Lee Kean, E-mail: lee.kc@petronas.com.my; Latiff, Noor Rasyada Ahmad, E-mail: syasya.latiff@gmail.com [Fundamental and Applied Sciences Department, Universiti Teknologi PETRONAS Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia); Alta’ee, Ali F., E-mail: ali-mangi@petronas.com.my [Geoscience and Petroleum Engineering Department, Universiti Teknologi PETRONAS Bandar Seri Iskandar, 31750 Tronoh, Perak (Malaysia)

2015-07-22

Dielectric nano powder synthesis is carried by a simple and fast sol-gel auto-combustion method. The transformation of crystalline phases of as-synthesized nano powders is investigated through the detailed transmission electron microscopy (TEM), revealed the crystallographic alterations and morphological information even at lattice scale. From specific area electron diffraction (SAED) pattern, has specified the d-spacing and corresponding planes supported by the observed lattice fringes. The morphological characterization of nanoparticles is performed through field-emission scanning electron microscopy (FESEM), exhibiting the increment in particle size due to agglomeration with the increase in annealing temperature. Furthermore, EDX pattern has been used to verify the formation of nanoparticles by revealing the presence of required elements.

Sol-gel synthesized ZnO for optoelectronics applications: a characterization review

Science.gov (United States)

Harun, Kausar; Hussain, Fayaz; Purwanto, Agus; Sahraoui, Bouchta; Zawadzka, Anna; Azmin Mohamad, Ahmad

2017-12-01

The rapid growth in green technology has resulted in a marked increase in the incorporation of ZnO in energy and optoelectronic devices. Research involving ZnO is being given renewed attention in the quest to fully exploit its promising properties. The purity and state of defects in the ZnO system are optimized through several modifications to the synthesis conditions and the starting materials. These works have been verified through a series of characterizations. This review covers the essential characterization outcomes of pure ZnO nanoparticles. Emphasis is placed on recent techniques, examples and some issues concerning sol-gel synthesized ZnO nanoparticles. Thermal, phase, structural and morphological observations are combined to ascertain the level of purity of ZnO. The subsequent elemental and optical characterizations are also discussed. This review would be the collective information and suggestions at one place for investigators to focus on the best development of ZnO-based optical and energy devices.

Characterization, antioxidant and antimicrobial activities of green synthesized silver nanoparticles from Psidium guajava L. leaf aqueous extracts.

Science.gov (United States)

Wang, Lu; Wu, Yanan; Xie, Jia; Wu, Sheng; Wu, Zhenqiang

2018-05-01

The green synthesis of nanoparticles has become increasingly promising due to their potential applications in nanomedicine and materials science. In this study, silver nanoparticles (P-AgNPs) were synthesized from aqueous extracts of P. guajava L. leaf. The synthesized silver nanoparticles were confirmed by UV-vis spectrophotometry at 438 nm. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), and zetasizer analyses showed that the average sizes of the P-AgNPs were 20-35 nm, 25 nm, and 25-35 nm, respectively. Element mapping analyses of the P-AgNPs were confirmed by X-ray diffraction (XRD) and energy dispersive X-ray spectroscopy (EDX) analyses. Moreover, FTIR spectra of the synthesized P-AgNPs showed the presence of phyto constituents as capping agents. Zeta potential measurements (-20.17 mV) showed that the synthesized P-AgNPs had reasonably good stability. The in vitro antioxidant properties of the P-AgNPs were evaluated using two different methods. A highly efficient radical scavenging activity of P-AgNPs possessing IC 50 values of 52.53 ± 0.31 μg/mL (DPPH) and 55.10 ± 0.29 μg/mL (ABTS + ) were confirmed. At a concentration of 100 μg/mL, antimicrobial activity assays of the P-AgNPs showed significant inhibition against selected bacteria, S. cerevisiae, A. niger and R. oryzae, especially against Alcaligenes faecalis and Escherichia coli. The present study revealed that the low-cost and environmentally friendly synthesis of P-AgNPs can be widely used in biomedicine, water treatment or purification, and nanobiotechnology. Copyright © 2018 Elsevier B.V. All rights reserved.

Method of synthesizing pyrite nanocrystals

Science.gov (United States)

Wadia, Cyrus; Wu, Yue

2013-04-23

A method of synthesizing pyrite nanocrystals is disclosed which in one embodiment includes forming a solution of iron (III) diethyl dithiophosphate and tetra-alkyl-ammonium halide in water. The solution is heated under pressure. Pyrite nanocrystal particles are then recovered from the solution.

Aspects of Landau condensation in atomic physics

International Nuclear Information System (INIS)

Gay, J.C.

1980-01-01

Some aspects of Landau condensation in atomic physics are reviewed both as regards current work on Rydberg states under laboratory conditions and from the viewpoint of the prospects of spontaneous decay of neutral vacuum with superheavy elements. The characteristics of the hydrogen-atom spectrum in a strong magnetic field are presented and discussed using essentially semiclassical arguments. Some schematic attempt at a global interpretation of the Rydberg spectrum near the ionization limit is also given. Then the action of an electric field on the quasi-Landau spectrum is discussed. The conditions for spontaneous production of positrons from neutral vacuum decay with superheavy elements are reconsidered for the case when the system experiences ultrastrong magnetic fields, as in pulsars and white dwarfs. It is shown that spontaneous decay of neutral vacuum may occur at lower Z values than 169. The possible importance of such effects during heavy-ion collisions is briefly discussed. We deal with some qualitative trends of the problem of an atom in a magnetic field with particular emphasis on diamagnetic effects. In the last few years, we have had the capability of making accurate experimental investigations of Rydberg atoms, and perhaps in the future we will develop fundamentally new means of studying heavy-ion collisions. Accordingly it seems of interest to make qualitative remarks regarding the present state of the problem and the possible importance of Landau condensation in various domains of atomic physics now under active development. (author)

Coordination chemistry of actinide elements: preparation of new uranium complexes with schiff bases and their characterization (Preprint No. CT-31)

International Nuclear Information System (INIS)

Hingorani, S.; Reddy, P.S.N.; Agarwala, B.V.

1988-02-01

The Schiff bases, o-vanillin semicarbazone (oVSC) and 2-pyridine carboxaldehyde isonicotinoyl hydrazone (PCINH) have been prepared and their novel complexes with dioxouranium(VI) have been synthesized and characterized by IR spectra, elemental analysis and other physico-chemical techniques. (author)

Synthesizing diverse evidence: the use of primary qualitative data analysis methods and logic models in public health reviews.

Science.gov (United States)

Baxter, S; Killoran, A; Kelly, M P; Goyder, E

2010-02-01

The nature of public health evidence presents challenges for conventional systematic review processes, with increasing recognition of the need to include a broader range of work including observational studies and qualitative research, yet with methods to combine diverse sources remaining underdeveloped. The objective of this paper is to report the application of a new approach for review of evidence in the public health sphere. The method enables a diverse range of evidence types to be synthesized in order to examine potential relationships between a public health environment and outcomes. The study drew on previous work by the National Institute for Health and Clinical Excellence on conceptual frameworks. It applied and further extended this work to the synthesis of evidence relating to one particular public health area: the enhancement of employee mental well-being in the workplace. The approach utilized thematic analysis techniques from primary research, together with conceptual modelling, to explore potential relationships between factors and outcomes. The method enabled a logic framework to be built from a diverse document set that illustrates how elements and associations between elements may impact on the well-being of employees. Whilst recognizing potential criticisms of the approach, it is suggested that logic models can be a useful way of examining the complexity of relationships between factors and outcomes in public health, and of highlighting potential areas for interventions and further research. The use of techniques from primary qualitative research may also be helpful in synthesizing diverse document types. Copyright 2010 The Royal Society for Public Health. Published by Elsevier Ltd. All rights reserved.

A low-spurious fast-hopping MB-OFDM UWB synthesizer

Energy Technology Data Exchange (ETDEWEB)

Chen Danfeng; Li Wei; Li Ning; Ren Junyan, E-mail: w-li@fudan.edu.c [State Key Laboratory of ASIC and System, Fudan University, Shanghai 201203 (China)

2010-06-15

A frequency synthesizer for the ultra-wide band (UWB) group no. 1 is proposed. The synthesizer uses a phase-locked loop (PLL) and single-sideband (SSB) mixers to generate the three center frequencies of the first band group by mixing 4224 MHz with {+-}264 MHz and 792 MHz, respectively. A novel multi-QSSB mixer is designed to combine the function of frequency selection and frequency conversion for low power and high linearity. The synthesizer is fabricated in Jazz 0.18-{mu}m RF CMOS technology. The measured reference spur is as low as -69 dBc and the maximum spur is the LO leakage of -32 dBc. A low phase noise of -110 dBc/Hz - 1 MHz offset and an integrated phase noise of 1.86{sup 0} are achieved. The hopping time between different bands is less than 1.8 ns. The synthesizer consumes 30 mA from a 1.8 V supply. (semiconductor integrated circuits)

A low-spurious fast-hopping MB-OFDM UWB synthesizer

International Nuclear Information System (INIS)

Chen Danfeng; Li Wei; Li Ning; Ren Junyan

2010-01-01

A frequency synthesizer for the ultra-wide band (UWB) group no. 1 is proposed. The synthesizer uses a phase-locked loop (PLL) and single-sideband (SSB) mixers to generate the three center frequencies of the first band group by mixing 4224 MHz with ±264 MHz and 792 MHz, respectively. A novel multi-QSSB mixer is designed to combine the function of frequency selection and frequency conversion for low power and high linearity. The synthesizer is fabricated in Jazz 0.18-μm RF CMOS technology. The measured reference spur is as low as -69 dBc and the maximum spur is the LO leakage of -32 dBc. A low phase noise of -110 dBc/Hz - 1 MHz offset and an integrated phase noise of 1.86 0 are achieved. The hopping time between different bands is less than 1.8 ns. The synthesizer consumes 30 mA from a 1.8 V supply. (semiconductor integrated circuits)

Thin films of molecular materials synthesized from fisher's carbene ferrocenyl: Film formation and electrical properties

International Nuclear Information System (INIS)

Sanchez-Vergara, M.E.; Ortiz, A.; Alvarez-Toledano, C.; Moreno, A.; Alvarez, J.R.

2008-01-01

The synthesis of materials from Fisher's carbene ferrocenyl of the elements chromium, molybdenum and tungsten was carried out. The Fisher's compounds that were synthesized included the following combinations of two different metallic atoms: iron with chromium, iron with molybdenum and iron with tungsten. The molecular solids' preparation was done in electro-synthesis cells with platinum electrodes. Thin films were prepared by vacuum thermal evaporation on quartz substrates and crystalline silicon wafers. Pellets and thin films from these compounds were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive spectroscopy, atomic force microscopy and ellipsometry. The powder and thin films synthesized from these materials show the same intra-molecular bonds shown by infrared spectroscopy results, suggesting that thermal evaporation does not alter these bonds in spite of the thin films being amorphous, in contrast with other bimetallic complexes where material decomposition occurs. The differences in the conductivity values of the prepared films are very small, so they may be attributed to the different metallic ions employed in each case. The tungsten complex exhibits a higher conductivity than the molybdenum and chromium complexes at room temperature. Electrical conductivity values found for thin films are higher than for pellets made of the same molecular materials

Information Retrieval for Ecological Syntheses

Science.gov (United States)

Bayliss, Helen R.; Beyer, Fiona R.

2015-01-01

Research syntheses are increasingly being conducted within the fields of ecology and environmental management. Information retrieval is crucial in any synthesis in identifying data for inclusion whilst potentially reducing biases in the dataset gathered, yet the nature of ecological information provides several challenges when compared with…

Inhibition of growth of S. epidermidis by hydrothermally synthesized ZnO nanoplates

Science.gov (United States)

Abinaya, C.; Mayandi, J.; Osborne, J.; Frost, M.; Ekstrum, C.; Pearce, J. M.

2017-07-01

The antibacterial effect of zinc oxide (ZnO#1) as prepared and annealed (ZnO#2) at 400 °C, Cu doped ZnO (CuZnO), and Ag doped ZnO (AgZnO) nanoplates on Staphylococcus epidermidis was investigated for the inhibition and inactivation of cell growth. The results shows that pure ZnO and doped ZnO samples exhibited antibacterial activity against Staphylococcus epidermidis (S. epidermidis) as compared to tryptic soy broth (TSB). Also it is observed that S. epidermidis was extremely sensitive to treatment with ZnO nanoplates and it is clear that the effect is not purely depend on Cu/Ag. Phase identification of a crystalline material and unit cell dimensions were studied by x-ray powder diffraction (XRD). The scanning electron microscopy (SEM) provides information on sample’s surface topography and the EDX confirms the presence of Zn, O, Cu and Ag. X-ray photo-electron spectroscopy (XPS) was used to analyze the elemental composition and electronic state of the elements that exist within the samples. These studies confirms the formation of nanoplates and the presence of Zn, O, Ag, Cu with the oxidation states  +2, -2, 0 and  +2 respectively. These results indicates promising antibacterial applications of these ZnO-based nanoparticles synthesized with low-cost hydrothermal methods.

Probing in-medium spin–orbit interaction with intermediate-energy heavy-ion collisions

International Nuclear Information System (INIS)

Xu, Jun; Li, Bao-An

2013-01-01

Incorporating for the first time both the spin and isospin degrees of freedom explicitly in transport model simulations of intermediate-energy heavy-ion collisions, we observe that a local spin polarization appears during collision process. Most interestingly, it is found that the nucleon spin up–down differential transverse flow is a sensitive probe of the spin–orbit interaction, providing a novel approach to probe both the density and isospin dependence of the in-medium spin–orbit coupling that is important for understanding the structure of rare isotopes and synthesis of superheavy elements

Complexes cobalt(II, zinc(II and copper(II with some newly synthesized benzimidazole derivatives and their antibacterial activity

Directory of Open Access Journals (Sweden)

S. O. PODUNAVAC-KUZMANOVIC

1999-05-01

Full Text Available The preparation and properties of some complexes of cobalt(II, zinc(II and copper(II with several newly synthesized benzimidazole derivatives (L are reported. The complexes, of the general formula [MCl2L2] (M=Co(II, Zn(II and [CuCl2L(H2O], have a tetrahedral structure. The complexes were characterized by elemental analysis, molar conductivity, magnetic susceptibility measurements, IR and absorption electronic spectra. The antibacterial activitiy of the benzimidazoles and their complexes was evaluated against Erwinia carotovora subsp. carotovora and Erwinia amylovora. The complexes were found to be more toxic than the ligands.

Fast, High-Precision Optical Polarization Synthesizer for Ultracold-Atom Experiments

Science.gov (United States)

Robens, Carsten; Brakhane, Stefan; Alt, Wolfgang; Meschede, Dieter; Zopes, Jonathan; Alberti, Andrea

2018-03-01

We present a technique for the precision synthesis of arbitrary polarization states of light with a high modulation bandwidth. Our approach consists of superimposing two laser light fields with the same wavelength, but with opposite circular polarizations, where the phase and the amplitude of each light field are individually controlled. We find that the polarization-synthesized beam reaches a degree of polarization of 99.99%, which is mainly limited by static spatial variations of the polarization state over the beam profile. We also find that the depolarization caused by temporal fluctuations of the polarization state is about 2 orders of magnitude smaller. In a recent work, Robens et al. [Low-Entropy States of Neutral Atoms in Polarization-Synthesized Optical Lattices, Phys. Rev. Lett. 118, 065302 (2017), 10.1103/PhysRevLett.118.065302] demonstrated an application of the polarization synthesizer to create two independently controllable optical lattices which trap atoms depending on their internal spin state. We use ultracold atoms in polarization-synthesized optical lattices to give an independent, in situ demonstration of the performance of the polarization synthesizer.

nanoparticles synthesized by citrate precursor m

African Journals Online (AJOL)

user

(M=Co, Cu) nanoparticles synthesized by citrate precursor method ... The structural characterization was carried out using an X-ray Diffractometer (Rikagu Miniflex, Japan) ..... His current area of interest includes magnetic nanomaterials.

Syntheses and Characterization of Some Tetradentate Schiff-Base Complexes and Their Heteroleptic Analogues

Directory of Open Access Journals (Sweden)

A. A. Osowole

2008-01-01

Full Text Available VO(IV, Ni(II and Cu(II complexes of the asymmetric Schiff base [(HOC6H3(OCH3C(C6H5:N(CH2CH2N:C(CH3CH:C(C6H5OH], and their heteroleptic analogues with triphenyl phosphine and 2,2’-bipyridine have been synthesized and characterized by elemental analyses, conductance, magnetic, infrared and electronic spectral measurements. The ligand is tetradentate coordinating via the imine N and enolic O atoms. The Ni(II and Cu(II complexes adopt a four coordinate square planar geometry, the VO(IV complex is five coordinate square-pyramidal and the heteroleptic complexes are 6-coordinate, octahedral. The assignment of geometry is collaborated by magnetic moments and electronic spectra measurements. The compounds are non-electrolyte in nitromethane and are magnetically dilute.

Proteins synthesized in tobacco mosaic virus infected protoplasts

International Nuclear Information System (INIS)

Huber, R.

1979-01-01

The author deals with research on the multiplication of tobacco mosaic virus (TMV) in leaf cell protoplasts. An attempt is made to answer three questions: (1) Which proteins are synthesized in TMV infected protoplasts as a result of TMV multiplication. (2) Which of the synthesized proteins are made under the direction of the TMV genome and, if any, which of the proteins are host specific. (3) In which functions are these proteins involved. (Auth.)

Syntheses, structures and third-order non-linear optical properties of homometal clusters containing molybdenum

International Nuclear Information System (INIS)

Li Yong; Lu Jing; Cui Xiaobing; Xu Jiqing; Li Kechang; Sun Huaying; Li Guanghua; Pan Lingyun; Yang Qingxin

2005-01-01

Both the homometal cluster [P(ph 4 )] 2 [Mo 2 O 2 (μ-S) 2 (S 2 ) 2 ] (1) and [Mo 2 O 2 (μ-S) 2 (Et 2 dtc) 2 ] (2) (Et 2 dtc=diethyl-dithiocarbamate) were successfully synthesized by low-temperature solid-state reactions. X-ray single-crystal diffraction studies suggest that compound (1) is a dinuclear anion cluster, and compound (2) is a dinuclear neutral cluster. The two compounds were characterized by elemental analyses, IR spectra and UV-Vis spectra. The third-order non-linear optical (NLO) properties of the clusters were also investigated and all exhibited nice non-linear absorption and self-defocusing performance with moduli of the hyperpolarizabilities 5.145x10 -30 esu for (1) and 5.428x10 -30 esu for (2)

SYNTH: A spectrum synthesizer

International Nuclear Information System (INIS)

Hensley, W.K.; McKinnon, A.D.; Miley, H.S.; Panisko, M.E.; Savard, R.M.

1993-10-01

A computer code has been written at the Pacific Northwest Laboratory (PNL) to synthesize the results of typical gamma ray spectroscopy experiments. The code, dubbed SYNTH, allows a user to specify physical characteristics of a gamma ray source, the quantity of the nuclides producing the radiation, the source-to-detector distance and the presence of absorbers, the type and size of the detector, and the electronic set up used to gather the data. In the process of specifying the parameters needed to synthesize a spectrum, several interesting intermediate results are produced, including a photopeak transmission function versus energy, a detector efficiency curve, and a weighted list of gamma and x rays produced from a set of nuclides. All of these intermediate results are available for graphical inspection and for printing. SYNTH runs on personal computers. It is menu driven and can be customized to user specifications. SYNTH contains robust support for coaxial germanium detectors and some support for sodium iodide detectors. SYNTH is not a finished product. A number of additional developments are planned. However, the existing code has been compared carefully to spectra obtained from National Institute for Standards and Technology (NIST) certified standards with very favorable results. Examples of the use of SYNTH and several spectral results are presented

Vasorelaxant Effect of a Newly Synthesized Dihydropyridine Ethyl Ester (DHPEE on Rat Thoracic Aorta: Dual Mechanism of Action

Directory of Open Access Journals (Sweden)

Hossein Babaei

2011-06-01

Full Text Available Introduction: DHPEE is a newly synthesized compound by merging the key structural elements in an angiotensin receptor blocker (Telmisartan with key structural elements in 1,4- dihydropyridine calcium channel blocker (Nifedipine. In this study, we examined dual calcium channel blocking and AT1 antagonist activity for DHPEE. Methods: The functional inhibitory characteristics of DHPEE were studied in vitro in rat thoracic aorta preparations precontracted by phenylephrine (1µM or KCl (80µM or Ang II in normal or calcium-free solutions. Results: Concentration–dependent significant relaxation was observed in aortic rings precontracted with phenylephrine, KCl or Ang II. The tension increment produced by increasing external calcium was also reduced by DHPEE. DHPEE caused a marked decrease in the maximal contractile response of the vasoactive agents and shifted their concentration-response curves to the right. Conclusion: DHPEE possesses dual characteristics and cause vasorelaxation by blocking the L-type calcium channels and blocking Ang II receptors (AT1 in rat aortic smooth muscle.

General Syntheses of Nanotubes Induced by Block Copolymer Self-Assembly

DEFF Research Database (Denmark)

Zhao, Jianming; Huang, Wei; Si, Pengchao

2018-01-01

Amphiphilic block copolymer templating strategies are extensively used for syntheses of mesoporous materials. However, monodisperse tubular nanostructures are limited. Here, a general method is developed to synthesize monodisperse nanotubes with narrow diameter distribution induced by self...

Comparison on Bactericidal and Cytotoxic Effect of Silver Nanoparticles Synthesized by Different Methods

Science.gov (United States)

Mala, R.; Celsia, A. S. Ruby; Malathi Devi, S.; Geerthika, S.

2017-08-01

Biologically synthesized silver nanoparticle are biocompatible for medical applications. The present work is aimed to synthesize silver nanoparticle using the fruit pulp of Tamarindusindica and to evaluate its antibacterial and anticancer activity against lung cancercell lines. Antibacterial activity was assessed by well diffusion method. Cytotoxicity was evaluated using MTT assay. GC-MS of fruit pulp extract showed the presence of levoglucosenone, n-hexadecanoic acid, 9,12-octadecadienoic acid etc. Antioxidant activity of the fruit pulp was determined by DPPH assay, hydrogen peroxide scavenging assay and lipid peroxidation. The size of biologically synthesized silver nanoparticle varied from 50 nm to 76 nm. It was 59 nm to 98 nm for chemically synthesized silver nanoparticle. Biologically synthesized silver nanoparticle showed 26 mm inhibition zone against E. coli and chemically synthesized silver nanoparticle showed 20 mm. Antioxidant activity of fruit extract by DPPH showed 84 % reduction. The IC 50 of biologically synthesized silver nanoparticle against lung cancer cell lines was 48 µg/ml. It was 95 µg/ml for chemically synthesized silver nanoparticle. The increased activity of biologically synthesized silver nanoparticle was due to its smaller size, stability and the bioactive compounds capping the silver nanoparticle extracted from the fruit extract.

Evaluation of Biological Activities of Chemically Synthesized Silver Nanoparticles

International Nuclear Information System (INIS)

Mostafa, A. A.; Solkamy, E.N.; Sayed, Sh. R. M.; Khan, M.; Shaik, M.R.; Al-Warthan, A.; Adil, S.F.

2015-01-01

Silver nanoparticles were synthesized by the earlier reported methods. The synthesized nanoparticles were characterized using ultraviolet-visible spectrophotometry (UV/Vis), transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDX), and X-ray powder diffraction (XRD). The synthesized materials were also evaluated for their antibacterial activity against Gram positive and Gram negative bacterial strains. TEM micrograph showed the spherical morphology of AgNPs with size range of 40-60 nm. The synthesized nanoparticles showed a strong antimicrobial activity and their effect depends upon bacterial strain as AgNPs exhibited greater inhibition zone for Pseudomonas aeruginosa (19.1 mm) followed by Staphylococcus aureus (14.8?mm) and S. pyogenes (13.6 mm) while the least activity was observed for Salmonella typhi (12.5 mm) at concentration of 5 μg/disc. The minimum inhibitory concentration (MIC) of AgNPs against S. aureus was 2.5 μg/disc and less than 2.5 μg/disc for P. aeruginosa. These results suggested that AgNPs can be used as an effective antiseptic agent for infectious control in medical field.

Characterization, antibacterial, and neurotoxic effect of Green synthesized nanosilver using Ziziphus spina Christi aqueous leaf extract collected from Riyadh, Saudi Arabia

Science.gov (United States)

El-Ansary, Afaf; Warsy, Arjumand; Daghestani, Maha; Merghani, Nada M.; Al-Dbass, Abeer; Bukhari, Wadha; Al-Ojayan, Badryah; Ibrahim, Eiman M.; Al-Qahtani, Asma M.; Shafi Bhat, Ramesa

2018-02-01

The current study aims to synthesize silver nanoparticles using Ziziphus spina Christi (ZSC) or (Sidr) aqueous leaf extract collected from Riyadh, Saudi Arabia. The green synthesis of silver nanoparticles using sidr leaves extract was successful. Production of silver nanoparticles was confirmed through UV-vis Spectrophotometer, particles size and zeta potential analysis, Infra-red spectroscopy, Scanning, and Transmission Electron Microscope (SEM and TEM). The UV-visible spectra showed that the absorption peak existed at 400 nm. SEM analysis showed that the synthesized AgNPs were spherical but in slightly aggregated form. TEM demonstrated different size range of 4-33 nm with an average size of 13. The element analysis profile showed silver signal together with oxygen, calcium, and potassium peaks which might be related to the plant structure. Biological effects of the synthesized AgNPs exhibit satisfactory inhibitory effect against ten tested microorganisms. It inhibited the growth of 5 gram-positive and five gram-negative bacteria. Moreover, AgNPs demonstrated a synergistic effect on the neurotoxicity induced in rat pups with orally administered methyl mercury (MeHg). The present study showed that AgNPs prepared from ZSC might be a promising antimicrobial agent for successful treatment of bacterial infection in intensive care units (ICU) especially in case of antibiotic resistance.

Characterization of Cr-rich Cr-Sb multilayer films: Syntheses of a new metastable phase using modulated elemental reactants

International Nuclear Information System (INIS)

Regus, Matthias; Mankovsky, Sergiy; Polesya, Svitlana; Kuhn, Gerhard; Ditto, Jeffrey; Schürmann, Ulrich; Jacquot, Alexandre; Bartholomé, Kilian; Näther, Christian; Winkler, Markus; König, Jan D.; Böttner, Harald; Kienle, Lorenz; Johnson, David C.; Ebert, Hubert; Bensch, Wolfgang

2015-01-01

The new metastable compound Cr 1+x Sb with x up to 0.6 has been prepared via a thin film approach using modulated elemental reactants and investigated by in-situ X-ray reflectivity, X-ray diffraction, differential scanning calorimetry, energy dispersive X-ray analysis as well as transmission electron microscopy and atomic force microscopy. The new Cr-rich antimonide crystallizes in a structure related to the Ni 2 In-type structure, where the crystallographic position (1/3, 2/3, 3/4) is partially occupied by excess Cr. The elemental layers of the pristine material interdiffused significantly before Cr 1+x Sb crystallized. A change in the activation energy was observed for the diffusion process when crystal growth starts. First-principles electronic structure calculations provide insight into the structural stability, magnetic properties and resistivity of Cr 1+x Sb. - Graphical abstract: 1 amorphous multilayered film 2 interdiffused amorphous film 3 metastable crystalline phase 4 thermodynamic stable phase (and by-product). - Highlights: • Interdiffusion of amorphous Cr and Sb occurs before crystallization. • Crystallization of a new metastable phase Cr 1.6 Sb in Ni 2 In-type structure. • The new Cr-rich phase shows half-metallic behavior

Syntheses, molecular and crystalline architectures, and ...

Indian Academy of Sciences (India)

Syntheses, molecular and crystalline architectures, and luminescence behaviour of terephthalate bridged heptacoordinated dinuclear lead(II) complexes containing a pentadentate N-donor Schiff base. SUBHASIS ROYa, SOMNATH CHOUBEYa, SUMITAVA KHANa, KISHALAY BHARa,. PARTHA MITRAb and BARINDRA ...

HISTORY OF THE ORIGIN OF THE CHEMICAL ELEMENTS AND THEIR DISCOVERIES

International Nuclear Information System (INIS)

HOLDEN, N.E.

2001-01-01

The origin of the chemical elements show a wide diversity with some of these elements having their origin in antiquity. Still other elements have been synthesized within the past fifty years via nuclear reactions on heavy elements, because these other elements are unstable and radioactive and do not exist in nature. The names of the elements come from many sources including mythological concepts or characters; places, areas or countries; properties of the element or its compounds, such as color, smell or its inability to combine; and the names of scientists. There are also some miscellaneous names as well as some obscure names for particular elements. The claim of discovery of an element has varied over the centuries. Many claims, e.g., the discovery of certain rare earth elements of the lanthanide series, involved the discovery of a mineral ore from which an element was later extracted. The honor of discovery has often been accorded not to the person who first isolated the element but to the person who discovered the original mineral itself, even when the ore was impure and contained many elements. The reason for this is that in the case of these rare earth elements, the ''earth'' now refers to oxides of a metal not to the metal itself. This fact was not realized at the time of their discovery, until the English chemist Humphry Davy showed that earths were compounds of oxygen and metals in 1808. In the early discoveries, the atomic weight of an element and spectral analysis of the element were not available. Later both of these elemental properties would be required before discovery of the element would be accepted. In general, the requirements for discovery claims have tightened through the years and claims that were previously accepted would no longer meet the minimum constraints now imposed. There are cases where the honor of discovery is not given to the first person to actually discover the element but to the first person to claim the discovery in print. If a

HISTORY OF THE ORIGIN OF THE CHEMICAL ELEMENTS AND THEIR DISCOVERIES.

Energy Technology Data Exchange (ETDEWEB)

HOLDEN,N.E.

2001-06-29

The origin of the chemical elements show a wide diversity with some of these elements having their origin in antiquity. Still other elements have been synthesized within the past fifty years via nuclear reactions on heavy elements, because these other elements are unstable and radioactive and do not exist in nature. The names of the elements come from many sources including mythological concepts or characters; places, areas or countries; properties of the element or its compounds, such as color, smell or its inability to combine; and the names of scientists. There are also some miscellaneous names as well as some obscure names for particular elements. The claim of discovery of an element has varied over the centuries. Many claims, e.g., the discovery of certain rare earth elements of the lanthanide series, involved the discovery of a mineral ore from which an element was later extracted. The honor of discovery has often been accorded not to the person who first isolated the element but to the person who discovered the original mineral itself, even when the ore was impure and contained many elements. The reason for this is that in the case of these rare earth elements, the ''earth'' now refers to oxides of a metal not to the metal itself. This fact was not realized at the time of their discovery, until the English chemist Humphry Davy showed that earths were compounds of oxygen and metals in 1808. In the early discoveries, the atomic weight of an element and spectral analysis of the element were not available. Later both of these elemental properties would be required before discovery of the element would be accepted. In general, the requirements for discovery claims have tightened through the years and claims that were previously accepted would no longer meet the minimum constraints now imposed. There are cases where the honor of discovery is not given to the first person to actually discover the element but to the first person to claim the

Biomedical applications of green synthesized Nobel metal nanoparticles.

Science.gov (United States)

Khan, Zia Ul Haq; Khan, Amjad; Chen, Yongmei; Shah, Noor S; Muhammad, Nawshad; Khan, Arif Ullah; Tahir, Kamran; Khan, Faheem Ullah; Murtaza, Behzad; Hassan, Sadaf Ul; Qaisrani, Saeed Ahmad; Wan, Pingyu

2017-08-01

Synthesis of Nobel metal nanoparticles, play a key role in the field of medicine. Plants contain a substantial number of organic constituents, like phenolic compounds and various types of glycosides that help in synthesis of metal nanoparticles. Synthesis of metal nanoparticles by green method is one of the best and environment friendly methods. The major significance of the green synthesis is lack of toxic by-products produced during metal nanoparticle synthesis. The nanoparticles, synthesized by green method show various significant biological activities. Most of the research articles report the synthesized nanoparticles to be active against gram positive and gram negative bacteria. Some of these bacteria include Escherichia coli, Bacillus subtilis, Klebsiella pneumonia and Pseudomonas fluorescens. The synthesized nanoparticles also show significant antifungal activity against Trichophyton simii, Trichophyton mentagrophytes and Trichophyton rubrum as well as different types of cancer cells such as breast cancer cell line. They also exhibit significant antioxidant activity. The activities of these Nobel metal nano-particles mainly depend on the size and shape. The particles of small size with large surface area show good activity in the field of medicine. The synthesized nanoparticles are also active against leishmanial diseases. This research article explores in detail the green synthesis of the nanoparticles and their uses thereof. Copyright © 2017 Elsevier B.V. All rights reserved.

Dynamic correction of the laser beam coordinate in fabrication of large-sized diffractive elements for testing aspherical mirrors

Science.gov (United States)

Shimansky, R. V.; Poleshchuk, A. G.; Korolkov, V. P.; Cherkashin, V. V.

2017-05-01

This paper presents a method of improving the accuracy of a circular laser system in fabrication of large-diameter diffractive optical elements by means of a polar coordinate system and the results of their use. An algorithm for correcting positioning errors of a circular laser writing system developed at the Institute of Automation and Electrometry, SB RAS, is proposed and tested. Highprecision synthesized holograms fabricated by this method and the results of using these elements for testing the 6.5 m diameter aspheric mirror of the James Webb space telescope (JWST) are described..

Souper: A Synthesizing Superoptimizer

OpenAIRE

Sasnauskas, Raimondas; Chen, Yang; Collingbourne, Peter; Ketema, Jeroen; Lup, Gratian; Taneja, Jubi; Regehr, John

2017-01-01

If we can automatically derive compiler optimizations, we might be able to sidestep some of the substantial engineering challenges involved in creating and maintaining a high-quality compiler. We developed Souper, a synthesizing superoptimizer, to see how far these ideas might be pushed in the context of LLVM. Along the way, we discovered that Souper's intermediate representation was sufficiently similar to the one in Microsoft Visual C++ that we applied Souper to that compiler as well. Shipp...

A low-power CMOS frequency synthesizer for GPS receivers

International Nuclear Information System (INIS)

Yu Yunfeng; Xiao Shimao; Zhuang Haixiao; Ma Chengyan; Ye Tianchun; Yue Jianlian

2010-01-01

A low-power frequency synthesizer for GPS/Galileo L1/E1 band receivers implemented in a 0.18 μm CMOS process is introduced. By adding clock-controlled transistors at latch outputs to reduce the time constant at sensing time, the working frequency of the high-speed source-coupled logic prescaler supplying quadrature local oscillator signals has been increased, compared with traditional prescalers. Measurement results show that this synthesizer achieves an in-band phase noise of -87 dBc/Hz at 15 kHz offset, with spurs less than -65 dBc. The whole synthesizer consumes 6 mA in the case of a 1.8 V supply, and its core area is 0.6 mm 2 . (semiconductor integrated circuits)

Synthese en chemotherapeutisch onderzoek van sulfanilamidopyrimidinen

NARCIS (Netherlands)

Grevenstuk, Anton Bernard

1942-01-01

In order to investigate the influence of substitution in the pyrimidine nucleous on the activity of the three isomeric sulfanilamidopyrimidines (2, 5 and 6), a number of substituted sulfanilamidopyrimidines were synthesized and tested on chemotherapeutic activity. ... Zie: Summary

SYNTH: A spectrum synthesizer

International Nuclear Information System (INIS)

Hensley, W.K.; McKinnon, A.D.; Miley, H.S.; Panisko, M.E.; Savard, R.M.

1994-07-01

A computer code has been written at the Pacific Northwest Laboratory (PNL) to synthesize the results of typical gamma-ray spectroscopy experiments. The code, dubbed SYNTH, allows a use r to specify physical characteristics of a gamma-ray source, the quantity of the nuclides producing the radiation, the source-to-detector distance and the type and thickness of absorbers, the size and composition of the detector (Ge or NaI), and the electronic set up used to gather the data. In the process of specifying the parameters needed to synthesize a spectrum, several interesting intermediate results are produced, including a photopeak transmission function vs energy, a detector efficiency curve, and a weighted list of gamma and x rays produced from a set of nuclides. All of these intermediate results are available for graphical inspection and for printing. SYNTH runs on personal computers. It is menu driven and can be customized to user specifications. SYNTH contains robust support for coaxial germanium detectors and some support for sodium iodide detectors. SYNTH is not a finished product. A number of additional developments are planned. However, the existing code has been compared carefully to spectra obtained from National Institute for Standards and Technology (NIST) certified standards with very favorable results. Examples of the use of SYNTH and several spectral results will be presented

Synthetic Smectite Colloids: Characterization of Nanoparticles after Co-Precipitation in the Presence of Lanthanides and Tetravalent Elements (Zr, Th

Directory of Open Access Journals (Sweden)

Muriel Bouby

2015-09-01

Full Text Available The magnesian smectite hectorite is a corrosion product frequently detected in nuclear waste glass alteration experiments. The structural incorporation of a single trivalent lanthanide was previously demonstrated. Hectorite was presently synthesized, for the first time, in the presence of several lanthanides (La, Eu, Yb following a multi-step synthesis protocol. The smallest-sized particles (nanoparticles, NPs were isolated by centrifugation and analyzed by asymmetrical flow field-flow fractionation (AsFlFFF coupled to ICP-MS, in order to obtain information on the elemental composition and distribution as a function of the size. Nanoparticles can be separated from the bulk smectite phase. The particles are able to accommodate even the larger-sized lanthanides such as La, however, with lower efficiency. We, therefore, assume that the incorporation proceeds by substitution for octahedral Mg accompanied by a concomitant lattice strain that increases with the size of the lanthanides. The presence of a mixture does not seem to affect the incorporation extent of any specific element. Furthermore, syntheses were performed where in addition the tetravalent zirconium or thorium elements were admixed, as this oxidation state may prevail for many actinide ions in a nuclear waste repository. The results show that they can be incorporated as well.

A fractional-N frequency synthesizer for wireless sensor network nodes

International Nuclear Information System (INIS)

Ma Xiao; Du Zhankun; Liu Chang; Liu Ke; Yan Yuepeng; Ye Tianchun

2014-01-01

This paper presents a fractional-N frequency synthesizer for wireless sensor network (WSN) nodes. The proposed frequency synthesizer adopts a phase locked loop (PLL) based structure, which employs an LC voltage-controlled oscillator (VCO) with small VCO gain (K VCO ) and frequency step (f step ) variations, a charge pump (CP) with current changing in proportion with the division ratio and a 20-bit ΔΣ modulator, etc. To realize constant K VCO and f step , a novel capacitor sub-bands grouping method is proposed. The VCO sub-groups' sizes are arranged according to the maximal allowed K VCO variation of the system. Besides, a current mode logic divide-by-2 circuit with inside-loop buffers ensures the synthesizer generates I/Q quadrature signals robustly. This synthesizer is implemented in a 0.13 μm CMOS process. Measurement results show that the frequency synthesizer has a frequency span from 2.07 to 3.11 GHz and the typical phase noise is −86.34 dBc/Hz at 100 kHz offset and −114.17 dBc/Hz at 1 MHz offset with a loop bandwidth of about 200 kHz, which meet the WSN nodes' requirements. (semiconductor integrated circuits)

Exploring Ultra-Heavy Cosmic Rays with the Trans-Iron Galactic Element Recorder (TIGER)

Science.gov (United States)

Link, Jason; Supertiger Collaboration

2017-01-01

Elements heavier than iron are primarily synthesized by neutron capture. These elements can be accelerated as cosmic-rays and measuring their abundances at Earth can yield information about galactic cosmic-rays' sources, the acceleration processes and the composition of the universe beyond the boundaries of our solar system. The Trans-Iron Galactic Element Recorder (TIGER) and its larger successor SuperTIGER was designed to measure the abundance of these ultra-heavy cosmic rays between Z=10 and Z=60. These detectors utilize scintillators with a wavelength shifter bar and PMT readout system as well as aerogel and acrylic Cherenkov detectors to identify the charge and energy of a particle and utilize a scintillating fiber hodoscope to provide trajectory information. In this talk I will review the results from this highly successful program, give the status for the next SuperTIGER flight planned for a December 2017 launch from Antarctica, and discuss the future direction of the program.

SYNTHESIZER CONTROLLED BEAM TRANSFER FROM THE AGS TO RHIC

International Nuclear Information System (INIS)

DELONG, J.; BRENNAN, J.M.; FISCHER, W.; HAYES, T.; SMITH, K.; VALENTINO, S.

2001-01-01

To ensure minimal losses and to preserve longitudinal emittance, beam is transferred from the AGS to the RHIC bunch to bucket. This requires precision frequency and phase control for synchronization and kicker timing. The required precision is realized with a set of Direct Digital Synthesizers. Each synthesizer can be frequency and phase modulated to align the AGS bunch to the target bucket in the RHIC phase

Supersymmetric grand unified theories and cosmology

International Nuclear Information System (INIS)

Lazarides, G.; Shafi, Q.

1983-01-01

By examining the behavior of supersymmetric grand unified theories (GUT's) in the very early universe we find two classes of realistic models. In one of them supersymmetry is broken at or near superheavy GUT scale. The cosmological implications of such models are expected to be similar to those of nonsupersymmetric GUT's. In the second class of models, the superheavy GUT scale is related to the supersymmetry-breaking scale in the manner of Witten. Two types of cosmological scenarios appear possible in this case, either with or without an intermediate (new) inflationary phase. They can be experimentally distinguished, since the former predicts an absence and the latter an observable number density of superheavy monopoles. A mechanism for generating baryon asymmetry in such models is pointed out

Introducing the "Human Element" in Chemistry by Synthesizing Blue Pigments and Creating Cyanotypes in a First-Year Chemistry Course

Science.gov (United States)

Morizot, Olivier; Audureau, Eric; Briend, Jean-Yves; Hagel, Gaetan; Boulc'h, Florence

2015-01-01

In this article, we present two concrete applications of the concept of the human element to chemistry education; starting with a course and experimental project on blue pigment synthesis and concluding with cross-disciplinary lessons and experiments on blue photography. In addition to the description of the content of these courses, we explore…

Analysis of the thermoluminescent signal in the hydroxyapatite synthesized by the sol-gel method

International Nuclear Information System (INIS)

Mendoza A, D.; Gonzalez, P.R.; Lobato, M.; Rubio, E.; Rodriguez L, V.; Custodio, E.

2004-01-01

The physical properties of the ceramics are related with the chemical bonds and the crystalline structure, because the elements that constitute it can be united by ionic bonds or partially ionic giving a covalent character, this last causes that the outer layer is full of electrons. This property makes that the ceramic ones become interesting materials for thermoluminescent applications, as it demonstrates through the recent works presented on the hydroxyapatite that is a ceramic biomaterials that has shown an interesting thermoluminescent signal when being exposed to gamma radiation. In this sense, this work presents the thermoluminescent signal analysis induced by the UV and gamma radiation in a particular type of hydroxyapatite synthesized by sol gel method in which the temperature synthesis is varied. The final thermoluminescent sensitivity of materials is correlated with the crystalline degree, which is analysed through X-ray diffraction. (Author)

The Semi-automatic Synthesis of 18F-fluoroethyl-choline by Domestic FDG Synthesizer

Directory of Open Access Journals (Sweden)

ZHOU Ming

2016-02-01

Full Text Available As an important complementary imaging agent for 18F-FDG, 18F-fluoroethyl-choline (18F-FECH has been demonstrated to be promising in brain and prostate cancer imaging. By using domestic PET-FDG-TI-I CPCU synthesizer, 18F-FECH was synthesized by different reagents and consumable supplies. The C18 column was added before the product collection bottle to remove K2.2.2. The 18F-FECH was synthesized by PET-FDG-IT-I synthesizer efficiently about 30 minutes by radiochemical yield of 42.0% (no decay corrected, n=5, and the radiochemical purity was still more than 99.0% after 6 hours. The results showed the domestic PET-FDG-IT-I synthesizer could semi-automatically synthesize injectable 18F-FECH in high efficiency and radiochemical purity

Microstructure and mechanical properties of thermoelectric nanostructured n-type silicon-germanium alloys synthesized employing spark plasma sintering

Energy Technology Data Exchange (ETDEWEB)

Bathula, Sivaiah [CSIR-Network of Institutes for Solar Energy, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Marg, New Delhi 110012 (India); Department of Applied Physics, Delhi Technological University, Delhi (India); Gahtori, Bhasker; Tripathy, S. K.; Tyagi, Kriti; Srivastava, A. K.; Dhar, Ajay, E-mail: adhar@nplindia.org [CSIR-Network of Institutes for Solar Energy, CSIR-National Physical Laboratory, Dr. K. S. Krishnan Marg, New Delhi 110012 (India); Jayasimhadri, M. [Department of Applied Physics, Delhi Technological University, Delhi (India)

2014-08-11

Owing to their high thermoelectric (TE) figure-of-merit, nanostructured Si{sub 80}Ge{sub 20} alloys are evolving as a potential replacement for their bulk counterparts in designing efficient radio-isotope TE generators. However, as the mechanical properties of these alloys are equally important in order to avoid in-service catastrophic failure of their TE modules, we report the strength, hardness, fracture toughness, and thermal shock resistance of nanostructured n-type Si{sub 80}Ge{sub 20} alloys synthesized employing spark plasma sintering of mechanically alloyed nanopowders of its constituent elements. These mechanical properties show a significant enhancement, which has been correlated with the microstructural features at nano-scale, delineated by transmission electron microscopy.

Zinc Oxide Nano crystals Synthesized by Quenching Technique

International Nuclear Information System (INIS)

Norhayati Abu Bakar; Akrajas Ali Umar; Muhamad Mat Salleh; Muhammad Yahya

2011-01-01

This paper reports an attempt to synthesize non toxic zinc oxide (ZnO) nano crystals using a simple quenching technique. The hot zinc oxide powder was quenched in hexane solution to obtain ZnO nano crystals. As the result, diameter size of the synthesized ZnO is 200 nm. It was also exhibited a good crystalline with wurtzite phase. The nano crystals properties of ZnO were revealed from good absorbance and green luminescence under UV exposure. This may be related with oxygen vacancy ionization during the annealing process. (author)

Biological activities of synthesized silver nanoparticles

Indian Academy of Sciences (India)

The C. halicacabum leaf extract synthesized AgNPs efficiency were tested against different bacterial pathogens MTCC-426 Proteus vulgaris, MTCC-2453 Pseudomonas aeruginosa, MTCC-96 Staphylococcus aureus, MTCC-441 Bacillus subtilis andMTCC-735 Salmonella paratyphi, and fungal pathogens Alternaria solani ...

Electrochemical Study on Newly Synthesized Chlorocurcumin as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid

Directory of Open Access Journals (Sweden)

Ahmed A. Al-Amiery

2013-11-01

Full Text Available A new curcumin derivative, i.e., (1E,4Z,6E-5-chloro-1,7-bis(4-hydroxy-3-methoxyphenylhepta-1,4,6-trien-3-one (chlorocurcumin, was prepared starting with the natural compound curcumin. The newly synthesized compound was characterized by elemental analysis and spectral studies (IR, 1H-NMR and 13C-NMR. The corrosion inhibition of mild steel in 1 M HCl by chlorocurcumin has been studied using potentiodynamic polarization (PDP measurements and electrochemical impedance spectroscopy (EIS. The inhibition efficiency increases with the concentration of the inhibitor but decreases with increases in temperature. The potentiodynamic polarization reveals that chlorocurcumin is a mixed-type inhibitor. The kinetic parameters for mild steel corrosion were determined and discussed.

Electrochemical Study on Newly Synthesized Chlorocurcumin as an Inhibitor for Mild Steel Corrosion in Hydrochloric Acid

Science.gov (United States)

Al-Amiery, Ahmed A.; Kadhum, Abdul Amir H.; Mohamad, Abu Bakar; Musa, Ahmed Y.; Li, Cheong Jiun

2013-01-01

A new curcumin derivative, i.e., (1E,4Z,6E)-5-chloro-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,4,6-trien-3-one (chlorocurcumin), was prepared starting with the natural compound curcumin. The newly synthesized compound was characterized by elemental analysis and spectral studies (IR, 1H-NMR and 13C-NMR). The corrosion inhibition of mild steel in 1 M HCl by chlorocurcumin has been studied using potentiodynamic polarization (PDP) measurements and electrochemical impedance spectroscopy (EIS). The inhibition efficiency increases with the concentration of the inhibitor but decreases with increases in temperature. The potentiodynamic polarization reveals that chlorocurcumin is a mixed-type inhibitor. The kinetic parameters for mild steel corrosion were determined and discussed. PMID:28788402

3 and 4 oxidation state element solubilities in borosilicate glasses. Implement to actinides in nuclear glasses

International Nuclear Information System (INIS)

Cachia, J.N.

2005-12-01

In order to ensure optimal radionuclides containment, the knowledge of the actinide loading limits in nuclear waste glasses and also the comprehension of the solubilization mechanisms of these elements are essential. A first part of this manuscript deals with the study of the differences in solubility of the tri and tetravalent elements (actinides and surrogates) particularly in function of the melting temperature. The results obtained indicate that trivalent elements (La, Gd, Nd, Am, Cm) exhibit a higher solubility than tetravalent elements (Hf, Th, Pu). Consequently, it was planned to reduce plutonium at the oxidation state (III), the later being essentially tetravalent in borosilicate glasses. An innovating reduction process of multi-valent elements (cerium, plutonium) using silicon nitride has been developed in a second part of this work. Reduced plutonium-bearing glasses synthesized by Si 3 N 4 addition made it possible to double the plutonium solubility from 2 to 4 wt% at 1200 deg C. A structural approach to investigate the differences between tri and tetravalent elements was finally undertaken. These investigations were carried out by X-rays Absorption Spectroscopy (EXAFS) and NMR. Trivalent rare earth and actinide elements seem to behave as network modifiers while tetravalent elements rather present true intermediaries' behaviour. (author)

Enzymatic synthesizing of phytosterol oleic esters.

Science.gov (United States)

Pan, Xinxin; Chen, Biqiang; Wang, Juan; Zhang, Xinzhi; Zhul, Biyun; Tan, Tianwei

2012-09-01

A method of synthesizing the phytosterol esters from oleic acid and sterols was studied, using immobilized lipase Candida sp. 99-125 as catalyst. Molar ratio (oleic acid/phytosterols), temperature, reaction period, organic solvents, catalyst, and silica-gel drier were optimized, and the result showed that 93.4% of the sterols had been esterified under the optimal synthetic condition: the molar ratio of oleic acid/phytosterol is 1:1 in 10 mL iso-octane, immobilized lipase (w, 140% of the sterols), incubated in an orbital shaker (200 rpm) at a temperature of 45 °C for 24 h. The immobilized lipase could be reused for at least 13 times with limited loss of esterification activity. The conversion still maintained up to 86.6%. Hence, this developed process for synthesizing phytosterol esters could be considered as simple and low-energy consumption compared to existing chemical processes.

Fusion reaction using low energy neutron-excess nucleus beam

International Nuclear Information System (INIS)

Fukuda, Tomokazu

1994-01-01

The present state and the plan of the experiment of measuring the fusion reaction near barriers by using neutron-excess nucleus beam, which has been advanced at RIKEN are reported. One of the purposes of this experiment is the feasibility investigation of the fusion reaction by using neutron-excess nuclei, which is indispensable for synthesizing superheavy elements. It is intended to systematically explore some enhancing mechanism in the neutron-excess nuclei which are unfavorable in beam intensity. This research can become the good means to prove the dynamic behavior of the neutrons on the surfaces of nuclei in reaction. The fusion reaction of 27 Al + Au was measured by using the stable nucleus beam of 27 Al, and the results are shown. In order to know the low energy fusion reaction of 11 Li and 11 Be which are typical halo nuclei, the identification by characteristic α ray of composite nuclei is carried out in 7,9,11 Li + 209 Bi and 9,10,11 Be + 208 Pb. A new detector having high performance, New MUSIC, is being developed. As the experiment by using this detector, the efficient measurement of the fusion reaction by using heavy neutron-excess nuclei up to Ni is considered. An example of 8 Li + α → 11 B + n reaction for celestial body physics is mentioned. (K.I.)

Radiochemical study of the reactions of heavy ions with gold

International Nuclear Information System (INIS)

Binder, I.

1977-07-01

Thick gold foils have been bombarded with heavy-ion projectiles at energies above the Coulomb barrier. The radioactive products were identified and their yields measured using gamma-ray spectrometry and an extensive series of computer programs developed for the data analysis. The total mass-yield distribution was extracted from the data using charge-dispersion curves inferred from the experimental results. One observes a change in the mass-yield distributions corresponding to primarily fusion-fission tractions occurring with the lighter projectiles Ne-20 and Ar-40 and deep-inelastic transfer reactions predominating with heavier Kr-84, Kr-86, and Xe-136 projectiles. For the deep-inelastic transfer reaction, more mass transfer is seen to occur for a higher incident projectile energy, and the Gaussian distribution of products shows exponential tailing. The preferred direction for mass transfer is from gold to the projectile nucleus. Sequential fission is a likely fate for nucludes beyond the lead shell closure. The ''gold finger'' is explained as a combination of mass transfer, nucleon evaporation and sequential fission. The yields of gold nuclides indicate a superposition of two reaction mechanisms, quasi-elastic and deep-inelastic. The angular momentum involved with each mechanism determines which of two isomeric states is the end product of the nuclear reaction. Suggestions are offered regarding the possibility of synthesizing super-heavy elements by use of heavy-ion nuclear reactions

Synthesis and radioactive properties of the heaviest nuclei

International Nuclear Information System (INIS)

Oganesyan, Yu.Ts.

1996-01-01

Experimental investigations on the synthesis and study of properties of faraway transactinide elements confirm the predictions of macro-microscopic theory on the existence of closed shells in the region of heavy deformed nuclei. It has been demonstrated experimentally that nuclear structure plays a decisive role in the stability of superheavy nuclides. Based on the experimental confirmation of the main provisions of the theory and after the introduction of a necessary correction into the calculation the properties of heavier nuclides in the region of spherical shells Z=114 and N=180-184 have been predicted. Here a substantial increase in the stability of nuclei is also expected. All the nuclei synthesized by now, were obtained in fusion reactions with a formation of a compound nucleus, the transition of which to the ground state takes place with the emission of neutrons and gamma-rays. Both the reactions of cold and hot fusion of nuclei can be used for the synthesis of new nuclei. Nevertheless, new experimental data on the fusion mechanism are required, since a number of theoretical descriptions of the fusion dynamics of complex nuclear systems need a substantial revising. One can assume that the reactions of the type 244 Pu, 248 Cm + 48 Ca are still within the current potential of the accelerators and experimental technique. This potential, nevertheless, is still to be implemented. 37 refs., 6 figs

Radiochemical study of the reactions of heavy ions with gold

Energy Technology Data Exchange (ETDEWEB)

Binder, I.

1977-07-01

Thick gold foils have been bombarded with heavy-ion projectiles at energies above the Coulomb barrier. The radioactive products were identified and their yields measured using gamma-ray spectrometry and an extensive series of computer programs developed for the data analysis. The total mass-yield distribution was extracted from the data using charge-dispersion curves inferred from the experimental results. One observes a change in the mass-yield distributions corresponding to primarily fusion-fission tractions occurring with the lighter projectiles Ne-20 and Ar-40 and deep-inelastic transfer reactions predominating with heavier Kr-84, Kr-86, and Xe-136 projectiles. For the deep-inelastic transfer reaction, more mass transfer is seen to occur for a higher incident projectile energy, and the Gaussian distribution of products shows exponential tailing. The preferred direction for mass transfer is from gold to the projectile nucleus. Sequential fission is a likely fate for nucludes beyond the lead shell closure. The ''gold finger'' is explained as a combination of mass transfer, nucleon evaporation and sequential fission. The yields of gold nuclides indicate a superposition of two reaction mechanisms, quasi-elastic and deep-inelastic. The angular momentum involved with each mechanism determines which of two isomeric states is the end product of the nuclear reaction. Suggestions are offered regarding the possibility of synthesizing super-heavy elements by use of heavy-ion nuclear reactions.

Essential oils-oriented fenvalerate analogues: syntheses, characterization and biological evaluation

International Nuclear Information System (INIS)

Su, H.; Li, H.

2016-01-01

A series of essential oils oriented ester derivatives have been designed, synthesized and characterized based on the skeleton of fenvalerate. The preliminary bioassay results indicated that some of the newly synthesized compounds showed better insecticidal activities against Pyrausta nubilalis and Heliothis armigera than that of the control trans-prallethrin chloride. (author)

GHz band frequency hopping PLL-based frequency synthesizers

Institute of Scientific and Technical Information of China (English)

XU Yong; WANG Zhi-gong; GUAN Yu; XU Zhi-jun; QIAO Lu-feng

2005-01-01

In this paper we describe a full-integrated circuit containing all building blocks of a completed PLL-based synthesizer except for low pass filter(LPF).The frequency synthesizer is designed for a frequency hopping (FH) transceiver operating up to 1.5 GHz as a local oscillator. The architecture of Voltage Controlled Oscillator (VCO) is optimized to get better performance, and a phase noise of -111.85-dBc/Hz @ 1 MHz and a tuning range of 250 MHz are gained at a centre frequency of 1.35 GHz.A novel Dual-Modulus Prescaler(DMP) is designed to achieve a very low jitter and a lower power.The settling time of PLL is 80 μs while the reference frequency is 400 KHz.This monolithic frequency synthesizer is to integrate all main building blocks of PLL except for the low pass filter,with a maximum VCO output frequency of 1.5 GHz,and is fabricated with a 0.18 μm mixed signal CMOS process. Low power dissipation, low phase noise, large tuning range and fast settling time are gained in this design.

Synthesizer: Expediting synthesis studies from context-free data with information retrieval techniques.

Directory of Open Access Journals (Sweden)

Lisa M Gandy

Full Text Available Scientists have unprecedented access to a wide variety of high-quality datasets. These datasets, which are often independently curated, commonly use unstructured spreadsheets to store their data. Standardized annotations are essential to perform synthesis studies across investigators, but are often not used in practice. Therefore, accurately combining records in spreadsheets from differing studies requires tedious and error-prone human curation. These efforts result in a significant time and cost barrier to synthesis research. We propose an information retrieval inspired algorithm, Synthesize, that merges unstructured data automatically based on both column labels and values. Application of the Synthesize algorithm to cancer and ecological datasets had high accuracy (on the order of 85-100%. We further implement Synthesize in an open source web application, Synthesizer (https://github.com/lisagandy/synthesizer. The software accepts input as spreadsheets in comma separated value (CSV format, visualizes the merged data, and outputs the results as a new spreadsheet. Synthesizer includes an easy to use graphical user interface, which enables the user to finish combining data and obtain perfect accuracy. Future work will allow detection of units to automatically merge continuous data and application of the algorithm to other data formats, including databases.

Thin films of molecular materials synthesized from fisher's carbene ferrocenyl: Film formation and electrical properties

Energy Technology Data Exchange (ETDEWEB)

Sanchez-Vergara, M.E. [Coordinacion de Ingenieria Mecatronica. Escuela de Ingenieria, Universidad Anahuac del Norte. Avenida Lomas de la Anahuac s/n, Col. Lomas Anahuac, 52786, Huixquilucan (Mexico)], E-mail: elena.sanchez@anahuac.mx; Ortiz, A. [Instituto de Investigaciones en Materiales. Universidad Nacional Autonoma de Mexico. A. P. 70-360, 04510, Mexico, DF (Mexico); Alvarez-Toledano, C.; Moreno, A. [Instituto de Quimica, Universidad Nacional Autonoma de Mexico. Circuito Exterior, Ciudad Universitaria, 04510, Mexico, DF (Mexico); Alvarez, J.R. [Instituto Tecnologico y de Estudios Superiores de Monterrey, Campus Ciudad de Mexico. Calle del Puente 222, Col. Ejidos de Huipulco, 14380, Mexico, DF (Mexico)

2008-07-31

The synthesis of materials from Fisher's carbene ferrocenyl of the elements chromium, molybdenum and tungsten was carried out. The Fisher's compounds that were synthesized included the following combinations of two different metallic atoms: iron with chromium, iron with molybdenum and iron with tungsten. The molecular solids' preparation was done in electro-synthesis cells with platinum electrodes. Thin films were prepared by vacuum thermal evaporation on quartz substrates and crystalline silicon wafers. Pellets and thin films from these compounds were characterized by Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive spectroscopy, atomic force microscopy and ellipsometry. The powder and thin films synthesized from these materials show the same intra-molecular bonds shown by infrared spectroscopy results, suggesting that thermal evaporation does not alter these bonds in spite of the thin films being amorphous, in contrast with other bimetallic complexes where material decomposition occurs. The differences in the conductivity values of the prepared films are very small, so they may be attributed to the different metallic ions employed in each case. The tungsten complex exhibits a higher conductivity than the molybdenum and chromium complexes at room temperature. Electrical conductivity values found for thin films are higher than for pellets made of the same molecular materials.

Heavy-Ion Reactions: a current awareness bulletin

International Nuclear Information System (INIS)

Kinser, W.H.

1985-01-01

This current awareness bulletin announces on a semimonthly basis the current worldwide information entered into the Energy Data Base on theoretical and experimental studies (including instrumentation) of heavy-ion (A > 4) nuclear reactions for nuclear structure studies; for producing new isotopes and superheavy elements for nuclear, atomic, and chemical properties studies; for understanding quantum chromodynamics as an exact theory of the strong nuclear force; and for studying the equations of state and phases of nuclear matter (pion condensate and quark matter) of special interest in astrophysics, and cosmology. An abstract is included with each citation. Regular publication began in January 1985

Cold valleys in fusion and fission

International Nuclear Information System (INIS)

Misicu, S.

2003-01-01

The cold fission configuration after the preformation of the fragments resembles a short-lived dinuclear or quasi-molecular system. The most conceivable scission configuration is given by two fission fragments in touching with the symmetry axes aligned (pole-pole orientation). This conclusion was based on the simple argument that this configuration offers the optimal tunneling time, i.e. the difference between the Coulomb barrier and the decay energy Q is minimal. Other orientations are apparently precluded in cold spontaneous fission and should be regarded as quasi-fission doorways in the synthesis of superheavy elements by cold fusion. (orig.)

Radiochemistry

International Nuclear Information System (INIS)

Urch, D.S.

1991-01-01

This section of Annual Reports will review recent developments in those branches of chemistry where nuclear transformations are of importance, but will exclude a consideration of the general chemical properties of elements that happen to be radioactive or of radiation chemistry. Much of the review will, be devoted to progress in the preparation of molecules of increasing complexity, labelled with short-lived positron emitting isotopes. A book, New Trends in Radiopharmaceutical Synthesis, Quality Assurance and Regulatory Control has appeared. Trends in the teaching of radiochemistry were considered at a recent meeting of the American Chemical Society. Concern was voiced about the current status of radio- and nuclear-chemistry education. There will be an increasing need for trained radiochemists and it is necessary to ensure that the topic is introduced into the school science curriculum. Failure in the hunt for the elusive 'super-heavy' elements is discussed in 'Elements beyond Uranium'. (author)

Magnetic properties and EXAFS study of nanocrystalline Fe2Mn0.5Cu0.5Al synthesized using mechanical alloying technique

International Nuclear Information System (INIS)

Nanto, Dwi; Yang, Dong-Seok; Yu, Seong-Cho

2014-01-01

Nanocrystalline Fe 2 Mn 0.5 Cu 0.5 Al has been synthesized by the mechanical alloying technique and studied as a function of milling time. Alloy nature of Fe 2 Mn 0.5 Cu 0.5 Al was observed in a sample milled for 96 h. The magnetic saturation is 4.0 μ B /f.u., which coincidently follows Slater–Pauling rule at 5 K. Nanocrystalline Fe 2 Mn 0.5 Cu 0.5 Al has enhanced saturate magnetization compared to any other fabrication of Fe 2 MnAl reported. Cu element plays an important role in site competes with other elements and may result in the enhancement of saturate magnetization. In accordance to the magnetic results and EXAFS pattern, it was revealed that the dynamics of magnetic properties were confirmed as structural changes of nanocrystalline Fe 2 Mn 0.5 Cu 0.5 Al

Unstable structure of ribosomal particles synthesized in. gamma. -irradiated Escherichia coli

Energy Technology Data Exchange (ETDEWEB)

Fujita, H; Morita, K [National Inst. of Radiological Sciences, Chiba (Japan)

1975-06-01

Stability of Escherichia coli ribosomes newly synthesized after ..gamma..-irradiation was compared with that of normal ribosomes. The ribosomal particles around 70-S synthesized in irradiated cells were more sensitive to digestion by pancreatic ribonuclease A. A larger number of the salt-unstable '50-S' precursor particles existed in the extract from irradiated cells than in the extract from unirradiated cells. These facts suggest that ribosomal particles, synthesized during an earlier stage in irradiated cells, maintain an incomplete structure even though they are not distinguishable from normal ribosomes by means of sucrose density-gradient centrifugation.

Method to synthesize metal chalcogenide monolayer nanomaterials

Science.gov (United States)

Hernandez-Sanchez, Bernadette A.; Boyle, Timothy J.

2016-12-13

Metal chalcogenide monolayer nanomaterials can be synthesized from metal alkoxide precursors by solution precipitation or solvothermal processing. The synthesis routes are more scalable, less complex and easier to implement than other synthesis routes.

3 and 4 oxidation state element solubilities in borosilicate glasses. Implement to actinides in nuclear glasses; Solubilite des elements aux degres d'oxydation (3) et (4) dans les verres de borosilicate. Application aux actinides dans les verres nucleaires

Energy Technology Data Exchange (ETDEWEB)

Cachia, J.N

2005-12-15

In order to ensure optimal radionuclides containment, the knowledge of the actinide loading limits in nuclear waste glasses and also the comprehension of the solubilization mechanisms of these elements are essential. A first part of this manuscript deals with the study of the differences in solubility of the tri and tetravalent elements (actinides and surrogates) particularly in function of the melting temperature. The results obtained indicate that trivalent elements (La, Gd, Nd, Am, Cm) exhibit a higher solubility than tetravalent elements (Hf, Th, Pu). Consequently, it was planned to reduce plutonium at the oxidation state (III), the later being essentially tetravalent in borosilicate glasses. An innovating reduction process of multi-valent elements (cerium, plutonium) using silicon nitride has been developed in a second part of this work. Reduced plutonium-bearing glasses synthesized by Si{sub 3}N{sub 4} addition made it possible to double the plutonium solubility from 2 to 4 wt% at 1200 deg C. A structural approach to investigate the differences between tri and tetravalent elements was finally undertaken. These investigations were carried out by X-rays Absorption Spectroscopy (EXAFS) and NMR. Trivalent rare earth and actinide elements seem to behave as network modifiers while tetravalent elements rather present true intermediaries' behaviour. (author)

Sol–gel synthesized mesoporous anatase titanium dioxide ...

Indian Academy of Sciences (India)

for dye sensitized solar cell (DSSC) applications. R GOVINDARAJ1,∗, M ... DSSC than rutile phase. In this work, we have synthesized hierarchically structured ... Hydrolysis and polycondensation reaction mechanism of sol–gel process. 2.

Synthesis, characterization, and wear and friction properties of variably structured SiC/Si elements made from wood by molten Si impregnation

DEFF Research Database (Denmark)

Dhiman, Rajnish; Rana, Kuldeep; Bengu, Erman

2012-01-01

We have synthesized pre-shaped SiC/Si ceramic material elements from charcoal (obtained from wood) by impregnation with molten silicon, which takes place in a two-stage process. In the first process, a porous structure of connected micro-crystals of β-SiC is formed, while, in the second process...

Characterization and electrocatalytic activity of Pt–M (M=Cu, Ag, and Pd) bimetallic nanoparticles synthesized by pulsed plasma discharge in water

Energy Technology Data Exchange (ETDEWEB)

Kim, Sung-Min; Cho, Ah-Rong; Lee, Sang-Yul, E-mail: sylee@kau.ac.kr [Korea Aerospace University, Department of Materials Engineering, Center for Surface Technology and Applications (Korea, Republic of)

2015-07-15

The synthetic approach for electrocatalysts is one of the most important methods of determining electrocatalytic performance. In this work, we synthesized Pt and Pt–M (M=Cu, Ag, and Pd) bimetallic nanoparticles using a pulsed plasma discharge in water. A morphological investigation revealed that the as-synthesized Pt and Pt–M bimetallic nanoparticles constituted a nanochain network structure interconnected with primary nanoparticles of 4–6 nm in size, and the nanochains grew from the primary nanoparticles via the oriented attachment. The Z-contrast, EDX line scanning, and XRD analysis confirmed that the Pt was alloyed with M without elemental segregation or phase segregation. Furthermore, it was found that the composition difference was dependent on the electrode temperature determined by the power density and thermal parameters. The electrochemical results revealed that the electrocatalytic activity, stability, and durability of the Pt–Ag bimetallic nanoparticles were superior with respect to the methanol oxidation reaction, which could be attributed to the downshift of the d-band center via electronic modification.

Knowledge Syntheses in Medical Education: Demystifying Scoping Reviews.

Science.gov (United States)

Thomas, Aliki; Lubarsky, Stuart; Durning, Steven J; Young, Meredith E

2017-02-01

An unprecedented rise in health professions education (HPE) research has led to increasing attention and interest in knowledge syntheses. There are many different types of knowledge syntheses in common use, including systematic reviews, meta-ethnography, rapid reviews, narrative reviews, and realist reviews. In this Perspective, the authors examine the nature, purpose, value, and appropriate use of one particular method: scoping reviews. Scoping reviews are iterative and flexible and can serve multiple main purposes: to examine the extent, range, and nature of research activity in a given field; to determine the value and appropriateness of undertaking a full systematic review; to summarize and disseminate research findings; and to identify research gaps in the existing literature. Despite the advantages of this methodology, there are concerns that it is a less rigorous and defensible means to synthesize HPE literature. Drawing from published research and from their collective experience with this methodology, the authors present a brief description of scoping reviews, explore the advantages and disadvantages of scoping reviews in the context of HPE, and offer lessons learned and suggestions for colleagues who are considering conducting scoping reviews. Examples of published scoping reviews are provided to illustrate the steps involved in the methodology.

Effect of similar elements on improving glass-forming ability of La-Ce-based alloys

International Nuclear Information System (INIS)

Zhang Tao; Li Ran; Pang Shujie

2009-01-01

To date the effect of unlike component elements on glass-forming ability (GFA) of alloys have been studied extensively, and it is generally recognized that the main consisting elements of the alloys with high GFA usually have large difference in atomic size and atomic interaction (large negative heat of mixing) among them. In our recent work, a series of rare earth metal-based alloy compositions with superior GFA were found through the approach of coexistence of similar constituent elements. The quinary (La 0.5 Ce 0.5 ) 65 Al 10 (Co 0.6 Cu 0.4 ) 25 bulk metallic glass (BMG) in a rod form with a diameter up to 32 mm was synthesized by tilt-pour casting, for which the glass-forming ability is significantly higher than that for ternary Ln-Al-TM alloys (Ln = La or Ce; TM = Co or Cu) with critical diameters for glass-formation of several millimeters. We suggest that the strong frustration of crystallization by utilizing the coexistence of La-Ce and Co-Cu to complicate competing crystalline phases is helpful to construct BMG component with superior GFA. The results of our present work indicate that similar elements (elements with similar atomic size and chemical properties) have significant effect on GFA of alloys.

Study on magnetite nanoparticles synthesized by chemical method

International Nuclear Information System (INIS)

Pei Wenli; Kumada, H.; Natusme, T.; Saito, H.; Ishio, S.

2007-01-01

Magnetite nanoparticles with controlled size were synthesized by chemical method. Higher deposition temperature and a rapid-raising temperature procedure are favorable to particle size distribution and fabrication of monodisperse nanoparticles. The larger nanoparticles can be synthesized by the two-step method. The large nanoparticle (up to 25 nm) without agglomeration was successfully produced. The saturation magnetization of 11 nm magnetite particles was 45 emu/g at room temperature, which is smaller than that of bulk magnetite due to surface effect. Hysteresis of the magnetite nanoparticle was very small, indicating superparamagnetic behavior. The magnetic domains of the 11 nm magnetite nanoparticles were successfully observed by MFM

Taenia solium tapeworms synthesize corticosteroids and sex steroids in vitro.

Science.gov (United States)

Valdez, R A; Jiménez, P; Fernández Presas, A M; Aguilar, L; Willms, K; Romano, M C

2014-09-01

Cysticercosis is a disease caused by the larval stage of Taenia solium cestodes that belongs to the family Taeniidae that affects a number of hosts including humans. Taeniids tapeworms are hermaphroditic organisms that have reproductive units called proglottids that gradually mature to develop testis and ovaries. Cysticerci, the larval stage of these parasites synthesize steroids. To our knowledge there is no information about the capacity of T. solium tapeworms to metabolize progesterone or other precursors to steroid hormones. Therefore, the aim of this paper was to investigate if T. solium tapeworms were able to transform steroid precursors to corticosteroids and sex steroids. T. solium tapeworms were recovered from the intestine of golden hamsters that had been orally infected with cysticerci. The worms were cultured in the presence of tritiated progesterone or androstenedione. At the end of the experiments the culture media were analyzed by thin layer chromatography. The experiments described here showed that small amounts of testosterone were synthesized from (3)H-progesterone by complete or segmented tapeworms whereas the incubation of segmented tapeworms with (3)H-androstenedione, instead of (3)H-progesterone, improved their capacity to synthesize testosterone. In addition, the incubation of the parasites with (3)H-progesterone yielded corticosteroids, mainly deoxicorticosterone (DOC) and 11-deoxicortisol. In summary, the results described here, demonstrate that T. solium tapeworms synthesize corticosteroid and sex steroid like metabolites. The capacity of T. solium tapeworms to synthesize steroid hormones may contribute to the physiological functions of the parasite and also to their interaction with the host. Copyright © 2014 Elsevier Inc. All rights reserved.

Experiments on the Synthesis of Element 115 in the Reaction ^{243}Am (^{48}Ca, xn)^{291-x}115

CERN Document Server

Oganessian, Yu T; Lobanov, Yu V; Abdullin, F S; Polyakov, A N; Shirokovsky, I V; Tsyganov, Yu S; Gulbekyan, G G; Bogomolov, S L; Mezentsev, A N; Iliev, S; Subbotin, V G; Sukhov, A M; Voinov, A A; Buklanov, G V; Subotic, K M; Zagrebaev, V I; Itkis, M G; Patin, J B; Moody, K J; Wild, J F; Stoyer, M A; Stoyer, N J; Shaughnessy, D A; Kenneally, J M; Lougheed, R W

2003-01-01

The results of experiments designed to synthesize element 115 isotopes in the ^{243}Am(^{48}Ca,xn)^{291-x}115 reaction are presented. With a beam dose of 4.3\\cdot 10^{18} 248-Mev ^{48}Ca projectiles, we observed three similar decay chains consisting of five consecutive alpha-decays, all detected in time intervals of about 20 s and terminated at a later time by a spontaneous fission with a high energy release (TKE \\sim 220 MeV). At a higher bombarding energy of 253 MeV, with an equal ^{48}Ca beam dose, we registered a different decay chain of four consecutive alpha-decays detected in a time interval of about 0.5 s, also terminated by spontaneous fission. The alpha-decay energies and half-lives for nine new alpha-decaying nuclei were determined. The decay properties of these synthesized nuclei are consistent with consecutive alpha-decays originating from the parent isotopes of the new element 115, ^{288}115 and ^{287}115, produced in the 3n- and 4n-evaporation channels with cross sections of about 3 and 1 pb, r...

Mesoporous Akaganeite of Adjustable Pore Size Synthesized using Mixed Templates

Science.gov (United States)

Zhang, Y.; Ge, D. L.; Ren, H. P.; Fan, Y. J.; Wu, L. M.; Sun, Z. X.

2017-12-01

Mesoporous akaganeite with large and adjustable pore size was synthesized through a co-template method, which was achieved by the combined interaction between PEG2000 and alkyl amines with different lengths of the straight carbon chain. The characterized results indicate that the synthesized samples show comparatively narrow BJH pore size distributions and centered at 14.3 nm when PEG and HEPA was used, and it could be enlarged to 16.8 and 19.4 nm respectively through changing the alkyl amines to DDA and HDA. Meanwhile, all the synthesized akaganeite possess relativity high specific surface area ranging from 183 to 281 m2/g and high total pore volume of 0.98 to 1.5 cm3/g. A possible mechanism leading to the pore size changing was also proposed.

An Open-Source Automated Peptide Synthesizer Based on Arduino and Python.

Science.gov (United States)

Gali, Hariprasad

2017-10-01

The development of the first open-source automated peptide synthesizer, PepSy, using Arduino UNO and readily available components is reported. PepSy was primarily designed to synthesize small peptides in a relatively small scale (<100 µmol). Scripts to operate PepSy in a fully automatic or manual mode were written in Python. Fully automatic script includes functions to carry out resin swelling, resin washing, single coupling, double coupling, Fmoc deprotection, ivDde deprotection, on-resin oxidation, end capping, and amino acid/reagent line cleaning. Several small peptides and peptide conjugates were successfully synthesized on PepSy with reasonably good yields and purity depending on the complexity of the peptide.

M10.6.6: Designed and manufactured Frequency Synthesizer Board (AMC)

CERN Document Server

Czuba, K

2011-01-01

The LLRF system require generation of highly stable clock and trigger signals for high precision data processing and synchronous system operation. This deliverable provides an updated AMC module designed to fulfill the LLRF system timing synchronization needs. The module contains three independent clock synthesizers that are able to generate LVDS clock signals in the range of 10 MHz to 100 MHz. The clock synthesizers can be synchronized either by an internal quartz oscillator or an external phase reference signal provided to the board from the FLASH Master Oscillator. Besides clock synthesizers the AMC card contains also an optical receiver suited to convert and decode FLASH timing signals.

Supersymmetric GUTs and cosmology

International Nuclear Information System (INIS)

Lazarides, G.; Shafi, Q.

1982-06-01

By examining the behaviour of supersymmetric GUTs in the very early universe we find two classes of realistic models. In one of them supersymmetry is broken at or near the superheavy GUT scale. The cosmological implications of such models are expected to be similar to those of nonsupersymmetric GUTs. In the second class of models, the superheavy GUT scale is related to the supersymmetry breaking scale a la Witten. Two types of cosmological scenarios appear possible in this case, either with or without an intermediate (new) inflationary phase. They can be experimentally distinguished, since the former predicts an absence and the latter an observable number density of superheavy monopoles. A mechanism for generating baryon asymmetry in such models is pointed out. Further constraint on model building appears if global R invariance is employed to resolve the strong CP problem. (author)

Increasing reconstruction quality of diffractive optical elements displayed with LC SLM

Science.gov (United States)

Cheremkhin, Pavel A.; Evtikhiev, Nikolay N.; Krasnov, Vitaly V.; Rodin, Vladislav G.; Starikov, Sergey N.

2015-03-01

Phase liquid crystal (LC) spatial light modulators (SLM) are actively used in various applications. However, majority of scientific applications require stable phase modulation which might be hard to achieve with commercially available SLM due to its consumer origin. The use of digital voltage addressing scheme leads to phase temporal fluctuations, which results in lower diffraction efficiency and reconstruction quality of displayed diffractive optical elements (DOE). Due to high periodicity of fluctuations it should be possible to use knowledge of these fluctuations during DOE synthesis to minimize negative effect. We synthesized DOE using accurately measured phase fluctuations of phase LC SLM "HoloEye PLUTO VIS" to minimize its negative impact on displayed DOE reconstruction. Synthesis was conducted with versatile direct search with random trajectory (DSRT) method in the following way. Before DOE synthesis begun, two-dimensional dependency of SLM phase shift on addressed signal level and time from frame start was obtained. Then synthesis begins. First, initial phase distribution is created. Second, random trajectory of consecutive processing of all DOE elements is generated. Then iterative process begins. Each DOE element sequentially has its value changed to one that provides better value of objective criterion, e.g. lower deviation of reconstructed image from original one. If current element value provides best objective criterion value then it left unchanged. After all elements are processed, iteration repeats until stagnation is reached. It is demonstrated that application of SLM phase fluctuations knowledge in DOE synthesis with DSRT method leads to noticeable increase of DOE reconstruction quality.

4-GHz counters bring synthesizers up to speed

Science.gov (United States)

Lee, F.; Miller, R.

1984-06-01

The availability of digital IC counters built on GaAs makes direct frequency division in microwave synthesizers possible. Four GHz is the highest clock rate achievable in production designs. These devices have the ability to drive TTL/CMOS logic, and the counter can be connected directly to single-chip frequency synthesizers controllers. A complete microwave sythesizer is formed by two chips and a voltage-controlled oscillator (VCO). The advantages of GaAs are discussed along with flip-flop basics, aspects of device fabrication, and the characteristics of GaAs MESAFETs. Attention is given to a GaAs prescaler usable for direct conversion, four kinds of flip-flops in a divide-by-two mode, and seven-stage binary ripple counters.

Hydrothermal syntheses, crystal structures, and photophysical properties of two coordination polymers with mixed ligands

Science.gov (United States)

Yan, Li; Liu, Chun-Ling

2017-10-01

Two novel metal-organic coordination polymers [Cd(ipdt)(m-BDC)·3H2O]n (1) and [Pb(mip)2(NTC) ·2H2O]n (2) [ipdt = 2,6-Dimethoxy-4-(1H-1,3,7,8-tetraaza-cyclopenta[l]phenanthren-2-yl)-phenol, mip = 2-(3-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline, m-BDC = isophthalic acid, NTC = nicotinic acid] have been synthesized by hydrothermal reactions and characterized by elemental analysis, thermogravimetric (TG) analysis, infrared spectrum (IR) and single-crystal X-ray diffraction. Single-crystal X-ray diffraction reveals that 1 exhibits two-dimensional (2D) layer architecture, and 2 shows 1D chain architecture. TG analysis shows clear courses of weight loss, which corresponds to the decomposition of different ligands. The luminescent properties for the ligand ipdt, mip and complexes 1-2 are also discussed in detail, which should be acted as potential luminescent material.

Microstructural characterization of gold nanoparticles synthesized by solution plasma processing

International Nuclear Information System (INIS)

Cho, Sung-Pyo; Bratescu, Maria Antoaneta; Takai, Osamu; Saito, Nagahiro

2011-01-01

Microstructural characteristics of gold nanoparticles (Au NPs) fabricated by solution plasma processing (SPP) in reverse micelle solutions have been studied by high-resolution transmission electron microscopy (HRTEM). The synthesized Au NPs, with an average size of 6.3 ± 1.4 nm, have different crystal characteristics; fcc single-crystalline particles, multiply twinned particles (MTPs), and incomplete MTPs (single-nanotwinned fcc configuration). The crystal structure characteristics of the Au NPs synthesized by the SPP method were analyzed and compared with similar-size Au NPs obtained by the conventional chemical reduction synthesis (CRS) method. The TEM analysis results show that the Au NPs synthesized by the CRS method have shapes and crystal structures similar to those nanoparticles obtained by the SPP method. However, from the detailed HRTEM analysis, the relative number of the Au MTPs and incomplete MTPs to the total number of the Au NPs synthesized by the SPP method was observed to be around 94%, whereas the relative number of these kinds of crystal structures fabricated by the CRS method was about 63%. It is most likely that the enhanced formation of the Au MTPs is due to the fact that the SPP method generates highly reaction-activated species under low environmental temperature conditions.

Physical--chemical studies of transuranium elements. Progress report, April 1, 1977--March 31, 1978

International Nuclear Information System (INIS)

Peterson, J.R.

1978-01-01

Major advances in our continuing program to determine, interpret, and correlate the basic chemical and physical properties of the transuranium elements are summarized for the period April 1, 1977, through March 31, 1978. CfCl 2 , EsCl 2 , EsBr 2 , and EsI 2 were synthesized and characterized spectrophotometrically, as were several mixed-valence lanthanide-actinide halides (e.g., GdCf 4 Cl 11 ) and CmF 4 , CfF 4 , and EsF 3 . All samples not containing einsteinium were also examined by X rays. Studies of the chemical consequences of the radioactive decay series 253 Es alpha decaying to 249 Bk beta decaying to 249 Cf have continued and expanded. Elemental Cm-248 has been prepared on the one-half milligram scale and used to synthesize CmP and CmSb. Single crystals of AmTe 2 and AmSe 2 have been grown from a Te melt and by iodine transport, respectively. Our SQUID magnetometer was tested successfully in a preliminary configuration, and the expected sensitivity of the device was confirmed. A new design for the flux sensing coils was incorporated prior to an apparatus calibration experiment with lead. A porous vitreous carbon material was found to make a useful optically transparent electrode for simultaneous electrochemical and absorption spectroscopic investigations. Cyclic voltammograms of UO 2 2+ were obtained prior to a spectroelectrochemical study of the radiation of UO 2 2+ . The major obstacle in our solution microcalorimetry program was overcome by the realization of a leak-free sample container. Calorimeter performance now warrants experiments with transuranium element samples. The electrochemical reductions of Cf(III) and Es(III) have been studied by polarography and/or cyclic voltammetry. The results suggest that both are reduced to the divalent state before being reduced to the amalgam

Biosynthesis of silver nanoparticles synthesized by Aspergillus

Indian Academy of Sciences (India)

In the present study, biosynthesis of silver nanoparticles and its antioxidant, antimicrobial and cytotoxic activities were investigated. Silver nanoparticles were extracellularly synthesized using Aspergillus flavus and the formation of nanoparticles was observed after 72 h of incubation. The results recorded from colour ...

Design of a synthesizer for magnetic resonance equipment using FPGA

International Nuclear Information System (INIS)

Sonora A

2006-01-01

This paper exposes the design of a direct digital synthesizer in FPGA. This desing can generate a sine wave output up to 4MHZ with 3,33 mHz of precision. The frequency is set by 32bit word of phase increment in 350ns. The desing was made for Magnetic Resonance scanners and uses a 97% of logic resources of device. Functions for the synthesizer control are implemented in the same chip

Entwicklung eines kontinuierlichen Verfahrens zur enzymkatalysierten Synthese eines strukturierten Triglycerides

OpenAIRE

Stadler, Hans-Gerhard

2005-01-01

Ausgangspunkt für die in der vorliegenden Arbeit durchgeführten Entwicklung eines kontinuierlichen Verfahrens zur Synthese des strukturierten Triglycerides 1,3-Oleyl-2-palmitoylglycerin war die von Schmid [Schmid 1999] entwickelte lipase-katalysierte Zwei-Schritt-Synthese für strukturierte Triglyceride vom Typ ABA [European Patent Application; EP 0 882 797 A2]. In der ersten Reaktionsstufe dieser zweistufigen Umesterung wird in einer Folgereaktion das Substrat Tripalmitin mit Hilfe ein...

Origin of the heavy elements in binary neutron-star mergers from a gravitational-wave event.

Science.gov (United States)

Kasen, Daniel; Metzger, Brian; Barnes, Jennifer; Quataert, Eliot; Ramirez-Ruiz, Enrico

2017-11-02

The cosmic origin of elements heavier than iron has long been uncertain. Theoretical modelling shows that the matter that is expelled in the violent merger of two neutron stars can assemble into heavy elements such as gold and platinum in a process known as rapid neutron capture (r-process) nucleosynthesis. The radioactive decay of isotopes of the heavy elements is predicted to power a distinctive thermal glow (a 'kilonova'). The discovery of an electromagnetic counterpart to the gravitational-wave source GW170817 represents the first opportunity to detect and scrutinize a sample of freshly synthesized r-process elements. Here we report models that predict the electromagnetic emission of kilonovae in detail and enable the mass, velocity and composition of ejecta to be derived from observations. We compare the models to the optical and infrared radiation associated with the GW170817 event to argue that the observed source is a kilonova. We infer the presence of two distinct components of ejecta, one composed primarily of light (atomic mass number less than 140) and one of heavy (atomic mass number greater than 140) r-process elements. The ejected mass and a merger rate inferred from GW170817 imply that such mergers are a dominant mode of r-process production in the Universe.

Nucleus Z=126 with magic neutron number N=184 may be related to the measured Maruhn–Greiner maximum at A/2=155 from compound nuclei at low energy nuclear reactions

Energy Technology Data Exchange (ETDEWEB)

Prelas, M.A. [University of Missouri, Columbia, MO (United States); Hora, H. [University of New South Wales, Sydney (Australia); Miley, G.H. [University of Illinois, Urbana-Champaign (United States)

2014-07-04

Evaluation of nuclear binding energies from theory close to available measurements of a very high number of superheavy elements (SHE) based on α-decay energies Q{sub α}, arrived at a closing shell with a significant neutron number 184. Within the option of several discussed magic numbers for protons of around 120, Bagge's numbers 126 and 184 fit well and are supported by the element generation measurements by low energy nuclear reactions (LENR) discovered in deuterium loaded host metals. These measurements were showing a Maruhn–Greiner maximum from fission of compound nuclei in an excited state with double magic numbers for mutual confirmation. - Highlights: • Use of Bagge procedure confirmed that Z=126 and N=184 are proper magic numbers. • Elements are generated by low energy nuclear reactions in deuterium loaded metal. • Postulated from measured distribution that a compound nucleus {sup 310}X{sub 126} was formed. • Formation of 164 deuterons in Bose–Einstein state clusters with 2 pm spacing.

Nucleus Z=126 with magic neutron number N=184 may be related to the measured Maruhn–Greiner maximum at A/2=155 from compound nuclei at low energy nuclear reactions

International Nuclear Information System (INIS)

Prelas, M.A.; Hora, H.; Miley, G.H.

2014-01-01

Evaluation of nuclear binding energies from theory close to available measurements of a very high number of superheavy elements (SHE) based on α-decay energies Q α , arrived at a closing shell with a significant neutron number 184. Within the option of several discussed magic numbers for protons of around 120, Bagge's numbers 126 and 184 fit well and are supported by the element generation measurements by low energy nuclear reactions (LENR) discovered in deuterium loaded host metals. These measurements were showing a Maruhn–Greiner maximum from fission of compound nuclei in an excited state with double magic numbers for mutual confirmation. - Highlights: • Use of Bagge procedure confirmed that Z=126 and N=184 are proper magic numbers. • Elements are generated by low energy nuclear reactions in deuterium loaded metal. • Postulated from measured distribution that a compound nucleus 310 X 126 was formed. • Formation of 164 deuterons in Bose–Einstein state clusters with 2 pm spacing

Synthese monitoring mestmarkt 2006-2012

OpenAIRE

Koeijer, de, T.J.; Luesink, H.H.; Daatselaar, C.H.G.

2014-01-01

De aanvoer en afzet van dierlijke mest via de mestmarkt in Nederland zijn op verzoek van het ministerie van Economische Zaken (EZ) voor de periode 2006-2012 in beeld gebracht. Dit is gedaan op basis van analyses van de Vervoersbewijzen Dierlijke Mest (VDM’s) van RVO.nl (Rijksdienst voor Ondernemend Nederland) en op basis van modelberekeningen met MAMBO. Dit WOt-technical report geeft een synthese van de resultaten. Op basis van vergelijkbare meststromen is het aanbod op basis van de VDM’s 73 ...

SYNTHESES AND CHARACTERIZATIONS OF THE CYANIDE ...

African Journals Online (AJOL)

2015-10-28

(Received October 28, 2015; revised June 25, 2016) ... suggest that the Ni(II) ion is four coordinate with four cyanide-carbon atoms in ... However, there have been many studies on octahedral [M(CN)6]n- but little ... were synthesized and investigated by vibrational spectral (FT-IR and ..... Karaağaç, D.; Kürkçüoğlu, G.S. Bull.

Synthesizing genetic sequential logic circuit with clock pulse generator.

Science.gov (United States)

Chuang, Chia-Hua; Lin, Chun-Liang

2014-05-28

Rhythmic clock widely occurs in biological systems which controls several aspects of cell physiology. For the different cell types, it is supplied with various rhythmic frequencies. How to synthesize a specific clock signal is a preliminary but a necessary step to further development of a biological computer in the future. This paper presents a genetic sequential logic circuit with a clock pulse generator based on a synthesized genetic oscillator, which generates a consecutive clock signal whose frequency is an inverse integer multiple to that of the genetic oscillator. An analogous electronic waveform-shaping circuit is constructed by a series of genetic buffers to shape logic high/low levels of an oscillation input in a basic sinusoidal cycle and generate a pulse-width-modulated (PWM) output with various duty cycles. By controlling the threshold level of the genetic buffer, a genetic clock pulse signal with its frequency consistent to the genetic oscillator is synthesized. A synchronous genetic counter circuit based on the topology of the digital sequential logic circuit is triggered by the clock pulse to synthesize the clock signal with an inverse multiple frequency to the genetic oscillator. The function acts like a frequency divider in electronic circuits which plays a key role in the sequential logic circuit with specific operational frequency. A cascaded genetic logic circuit generating clock pulse signals is proposed. Based on analogous implement of digital sequential logic circuits, genetic sequential logic circuits can be constructed by the proposed approach to generate various clock signals from an oscillation signal.

Electrochemical sensor for dopamine based on a novel graphene-molecular imprinted polymers composite recognition element

DEFF Research Database (Denmark)

Mao, Yan; Bao, Yu; Gan, Shiyu

2011-01-01

A novel composite of graphene sheets/Congo red-molecular imprinted polymers (GSCR-MIPs) was synthesized through free radical polymerization (FRP) and applied as a molecular recognition element to construct dopamine (DA) electrochemical sensor. The template molecules (DA) were firstly absorbed...... at the GSCR surface due to their excellent affinity, and subsequently, selective copolymerization of methacrylic acid (MAA) and ethylene glycol dimethacrylate (EGDMA) was further achieved at the GSCR surface. Potential scanning was presented to extract DA molecules from the imprinted polymers film...

Cytotoxicity of Nanoliposomal Cisplatin Coated with Synthesized ...

African Journals Online (AJOL)

Purpose: To evaluate the cytotoxicity of pegylated nanoliposomal cisplatin on human ovarian cancer cell line A2780CP. Methods: Synthesized methoxypolyethylene glycol (mPEG) propionaldehyde was characterized by 1Hnuclear magnetic resonance (1H-NMR) and Fourier transform infrared spectroscopy (FTIR) and used ...

Doping effect on SILAR synthesized crystalline nanostructured Cu-doped ZnO thin films grown on indium tin oxide (ITO) coated glass substrates and its characterization

Science.gov (United States)

Dhaygude, H. D.; Shinde, S. K.; Velhal, Ninad B.; Takale, M. V.; Fulari, V. J.

2016-08-01

In the present study, a novel chemical route is used to synthesize the undoped and Cu-doped ZnO thin films in aqueous solution by successive ionic layer adsorption and reaction (SILAR) method. The synthesized thin films are characterized by x-ray diffractometer (XRD), field emission scanning electron microscopy (FE-SEM), energy dispersive x-ray analysis (EDAX), contact angle goniometer and UV-Vis spectroscopic techniques. XRD study shows that the prepared films are polycrystalline in nature with hexagonal crystal structure. The change in morphology for different doping is observed in the studies of FE-SEM. EDAX spectrum shows that the thin films consist of zinc, copper and oxygen elements. Contact angle goniometer is used to measure the contact angle between a liquid and a solid interface and after detection, the nature of the films is initiated from hydrophobic to hydrophilic. The optical band gap energy for direct allowed transition ranging between 1.60-2.91 eV is observed.

Biogenic synthesized nanoparticles and their applications

Energy Technology Data Exchange (ETDEWEB)

Singh, Abhijeet, E-mail: abhijeet.singh@jaipur.manipal.edu; Sharma, Madan Mohan [Manipal University Jaipur (India)

2016-05-06

In the present scenario, there are growing concerns over the potential impacts of bioengineered nanoparticles in the health sector. However, our understanding of how bioengineered nanoparticles may affect organisms within natural ecosystems, lags far behind our rapidly increasing ability to engineer novel nanoparticles. To date, research on the biological impacts of bioengineered nanoparticles has primarily consisted of controlled lab studies of model organisms with single species in culture media. Here, we described a cost effective and environment friendly technique for green synthesis of silver nanoparticles. Silver nanoparticles were successfully synthesized from 1 mM AgNO{sub 3} via a green synthesis process using leaf extract as reducing as well as capping agent. Nanoparticles were characterized with the help of UV–vis absorption spectroscopy, X-ray diffraction and TEM analysis which revealed the size of nanoparticles of 30-40 nm size. Further the nanoparticles synthesized by green route are found highly toxic against pathogenic bacteria and plant pathogenic fungi viz. Escherichia coli, Pseudomonas syringae and Sclerotiniasclerotiorum. The most important outcome of this work will be the development of value-added products and protection of human health from pathogens viz., bacteria, virus, fungi etc.

Biogenic synthesized nanoparticles and their applications

International Nuclear Information System (INIS)

Singh, Abhijeet; Sharma, Madan Mohan

2016-01-01

In the present scenario, there are growing concerns over the potential impacts of bioengineered nanoparticles in the health sector. However, our understanding of how bioengineered nanoparticles may affect organisms within natural ecosystems, lags far behind our rapidly increasing ability to engineer novel nanoparticles. To date, research on the biological impacts of bioengineered nanoparticles has primarily consisted of controlled lab studies of model organisms with single species in culture media. Here, we described a cost effective and environment friendly technique for green synthesis of silver nanoparticles. Silver nanoparticles were successfully synthesized from 1 mM AgNO_3 via a green synthesis process using leaf extract as reducing as well as capping agent. Nanoparticles were characterized with the help of UV–vis absorption spectroscopy, X-ray diffraction and TEM analysis which revealed the size of nanoparticles of 30-40 nm size. Further the nanoparticles synthesized by green route are found highly toxic against pathogenic bacteria and plant pathogenic fungi viz. Escherichia coli, Pseudomonas syringae and Sclerotiniasclerotiorum. The most important outcome of this work will be the development of value-added products and protection of human health from pathogens viz., bacteria, virus, fungi etc.

Method of synthesizing tungsten nanoparticles

Science.gov (United States)

Thoma, Steven G; Anderson, Travis M

2013-02-12

A method to synthesize tungsten nanoparticles has been developed that enables synthesis of nanometer-scale, monodisperse particles that can be stabilized only by tetrahydrofuran. The method can be used at room temperature, is scalable, and the product concentrated by standard means. Since no additives or stabilizing surfactants are required, this method is particularly well suited for producing tungsten nanoparticles for dispersion in polymers. If complete dispersion is achieved due to the size of the nanoparticles, then the optical properties of the polymer can be largely maintained.

Neutron rich clusters and the dynamics of fission and fusion

International Nuclear Information System (INIS)

Armbruster, P.

1988-07-01

In this lecture I want to discuss experimental evidence for the appearance of cluster aspects in the dynamics of large rearrangement processes, as fusion and fission. Clusters in the sense as used in my lecture are the strongly bound doubly magic nuclei as 20 Ca 28 48 , 28 Ni 50 78 , 132 50 Sn 82 , and 208 82 Pb 126 and the superheavy nucleus 298 114 184 . Two of these nuclei, 78 Ni and 298 114 have not yet been identified. I discuss first the experimental findings from heavy element production. Then I cover the stability of cluster aspects to intrinsic excitation energy in fusion and fission. (orig./HSI)

Production of heavy evaporation residues in the reactions induced by an extracted 48Ca beam on a 208Pb target

International Nuclear Information System (INIS)

Eremin, A.V.; Chepigin, V.I.; Itkis, M.G.

1998-01-01

The production cross sections of the isotopes 253-255 No were measured for the heavy ion complete fusion reaction 48 Ca + 208 Pb using the electrostatic recoil separator VASSILISSA. The obtained excitation functions for the reaction products formed after the evaporation of 1-3 neutrons from the compound nucleus are discussed and compared with the data obtained earlier and with the results of the statistical model calculations. The background conditions at the extraction of the correlated events of the reaction product decay are also considered from the point of view of future experiments on the superheavy element synthesis in the complete fusion reactions induced by 48 Ca projectiles

Decay properties of heavier nuclei and mass formula

International Nuclear Information System (INIS)

Uno, Masahiro

2000-01-01

The stabilities of heavy nuclei, including super-heavy elements, are governed by alpha decay and fission. Some exotic types of decay, such as heavy cluster decay, which does not occur so frequently as to govern stability, have been also reported. The half-time estimations of various types of decay are reviewed. And the possibility of decay, mainly in case of heavy cluster decay, is discussed with Q-value obtained from mass formulae as well. Some topics concerning other types of exotic decay are presented. Recent trends in the research on mass formula are reviewed from the historical point of view, to get perspectives of future development. (Yamamoto, A.)

Decay properties of heavier nuclei and mass formula

Energy Technology Data Exchange (ETDEWEB)

Uno, Masahiro [Ministry of Education, Science and Culture, Tokyo (Japan)

2000-03-01

The stabilities of heavy nuclei, including super-heavy elements, are governed by alpha decay and fission. Some exotic types of decay, such as heavy cluster decay, which does not occur so frequently as to govern stability, have been also reported. The half-time estimations of various types of decay are reviewed. And the possibility of decay, mainly in case of heavy cluster decay, is discussed with Q-value obtained from mass formulae as well. Some topics concerning other types of exotic decay are presented. Recent trends in the research on mass formula are reviewed from the historical point of view, to get perspectives of future development. (Yamamoto, A.)

Final technical report

Energy Technology Data Exchange (ETDEWEB)

Loveland, Walter David [Oregon State Univ., Corvallis, OR (United States)

2016-08-27

This report describes the research carried out under this grant for the period from 1997 to 2014. This work has been previously described in annual progress reports and renewal applications. As a result of this project, ~100 papers were published in open refereed journals and 107 invited talks were given by the PI. The research subjects covered by this project included the synthesis and characterization of super-heavy nuclei, the critical study of the reaction mechanisms used in these synthesis reactions, the mechanism(s) of intermediate energy and relativistic nuclear collisions, the study of reactions induced by radioactive nuclear beams, and general properties of the heaviest elements.

Spurious in PLL-DDS frequency synthesizers

Czech Academy of Sciences Publication Activity Database

Kroupa, Věnceslav František; Štursa, Jarmil

2002-01-01

Roč. 2, č. 1 (2002), s. 48-51 ISSN 1335-8243. [Digital Signal Processing and Multimedia Communications DSP-MCOM 2001 /5./. Košice, 27.11.2001-29.11.2001] R&D Projects: GA ČR GA102/00/0958 Institutional research plan: CEZ:AV0Z2067918 Keywords : frequency synthesizers * phase locked loops * direct digital synthesis Subject RIV: JA - Electronics ; Optoelectronics, Electrical Engineering

Bias Voltage-Dependent Impedance Spectroscopy Analysis of Hydrothermally Synthesized ZnS Nanoparticles

Science.gov (United States)

Dey, Arka; Dhar, Joydeep; Sil, Sayantan; Jana, Rajkumar; Ray, Partha Pratim

2018-04-01

In this report, bias voltage-dependent dielectric and electron transport properties of ZnS nanoparticles were discussed. ZnS nanoparticles were synthesized by introducing a modified hydrothermal process. The powder XRD pattern indicates the phase purity, and field emission scanning electron microscope image demonstrates the morphology of the synthesized sample. The optical band gap energy (E g = 4.2 eV) from UV measurement explores semiconductor behavior of the synthesized material. The electrical properties were performed at room temperature using complex impedance spectroscopy (CIS) technique as a function of frequency (40 Hz-10 MHz) under different forward dc bias voltages (0-1 V). The CIS analysis demonstrates the contribution of bulk resistance in conduction mechanism and its dependency on forward dc bias voltages. The imaginary part of the impedance versus frequency curve exhibits the existence of relaxation peak which shifts with increasing dc forward bias voltages. The dc bias voltage-dependent ac and dc conductivity of the synthesized ZnS was studied on thin film structure. A possible hopping mechanism for electrical transport processes in the system was investigated. Finally, it is worth to mention that this analysis of bias voltage-dependent dielectric and transport properties of as-synthesized ZnS showed excellent properties for emerging energy applications.

Exploitation of rare earth catalysts in polymer syntheses

Institute of Scientific and Technical Information of China (English)

Shen Zhiquan

2006-01-01

The studies over forty years on rare earth catalysts in polymer syntheses of diene,alkyne,alkylene oxide,thiirane, carbon dioxide copolymerization, lactide,caprolactone,cyclic carbonate and so forth in China have been reviewed.