WorldWideScience

Sample records for sustain liquid water

  1. Sustainable Water Systems

    Directory of Open Access Journals (Sweden)

    Miklas Scholz

    2013-02-01

    Full Text Available Sustainable water systems often comprise complex combinations of traditional and new system components that mimic natural processes. These green systems aim to protect public health and safety, and restore natural and human landscapes. Green infrastructure elements such as most sustainable drainage systems trap storm water but may contaminate groundwater. There is a need to summarize recent trends in sustainable water systems management in a focused document. The aim of this special issue is therefore to disseminate and share scientific findings on novel sustainable water systems addressing recent problems and opportunities. This special issue focuses on the following key topics: climate change adaptation and vulnerability assessment of water resources systems; holistic water management; carbon credits; potable water savings; sustainable water technologies; nutrient management; holistic storm water reuse; water and wastewater infrastructure planning; ecological status of watercourses defined by the Water Framework Directive. The combined knowledge output advances the understanding of sustainable water, wastewater and storm water systems in the developed and developing world. The research highlights the need for integrated decision-support frameworks addressing the impact of climate change on local and national water resources management strategies involving all relevant stakeholders at all levels.

  2. Sustainability and Water

    Science.gov (United States)

    Sharma, Virender A.

    2009-07-01

    World's population numbered 6.1 billion in 2000 and is currently increasing at a rate of about 77 million per year. By 2025, the estimated total world population will be of the order of 7.9 billion. Water plays a central role in any systematic appraisal of life sustaining requirements. Water also strongly influences economic activity (both production and consumption) and social roles. Fresh water is distributed unevenly, with nearly 500 million people suffering water stress or serious water scarcity. Two-thirds of the world's population may be subjected to moderate to high water stress in 2025. It is estimated that by 2025, the total water use will increase by to 40%. The resources of water supply and recreation may also come under stress due to changes in climate such as water balance for Lake Balaton (Hungary). Conventional urban water systems such as water supply, wastewater, and storm water management are also currently going through stress and require major rethinking. To maintain urban water systems efficiently in the future, a flexibility approach will allow incorporation of new technologies and adaptation to external changes (for example society or climate change). Because water is an essential resource for sustaining health, both the quantity and quality of available water supplies must be improved. The impact of water quality on human health is severe, with millions of deaths each year from water-borne diseases, while water pollution and aquatic ecosystem destruction continue to rise. Additionally, emerging contaminants such as endocrine disruptor chemicals (EDCs), pharmaceuticals, and toxins in the water body are also of a great concern. An innovative ferrate(VI) technology is highly effective in removing these contaminants in water. This technology is green, which addresses problems associated with chlorination and ozonation for treating pollutants present in water and wastewater. Examples are presented to demonstrate the applications of ferrate

  3. A lipid-based liquid crystalline matrix that provides sustained release and enhanced oral bioavailability for a model poorly water soluble drug in rats.

    Science.gov (United States)

    Boyd, Ben J; Khoo, Shui-Mei; Whittaker, Darryl V; Davey, Greg; Porter, Christopher J H

    2007-08-01

    Liquid crystalline phases that are stable in excess water, formed using lipids such as glyceryl monooleate (GMO) and oleyl glycerate (OG), are known to provide a sustained release matrix for poorly water soluble drugs in vitro, yet there has been no report of the use of these materials to impart oral sustained release behaviour in vivo. In the first part of this study, in vitro lipolysis experiments were used to compare the digestibility of GMO with a second structurally related lipid, oleyl glycerate, which was found to be less susceptible to hydrolysis by pancreatic lipase than GMO. Subsequent oral bioavailability studies were conducted in rats, in which a model poorly water soluble drug, cinnarizine (CIN), was administered orally as an aqueous suspension, or as a solution in GMO or OG. In the first bioavailability study, plasma samples were taken over a 30 h period and CIN concentrations determined by HPLC. Plasma CIN concentrations after administration in the GMO formulation were only sustained for a few hours after administration while for the OG formulation, the plasma concentration of cinnarizine was at its highest level 30 h after dosing, and appeared to be increasing. A second study in which CIN was again administered in OG, and plasma samples taken for 120 h, revealed a Tmax for CIN in rats of 36 h and a relative oral bioavailability of 344% when compared to the GMO formulation (117%) and the aqueous suspension formulation (assigned a nominal bioavailability of 100%). The results indicate that lipids that form liquid crystalline structures in excess water, may have application as an oral sustained release delivery system, providing they are not digested rapidly on administration.

  4. Phytantriol and glyceryl monooleate cubic liquid crystalline phases as sustained-release oral drug delivery systems for poorly water-soluble drugs II. In-vivo evaluation.

    Science.gov (United States)

    Nguyen, Tri-Hung; Hanley, Tracey; Porter, Christopher J H; Larson, Ian; Boyd, Ben J

    2010-07-01

    Lipid-based liquid crystals formed from phytantriol (PHY) and glyceryl monooleate (GMO) retain their cubic-phase structure on dilution in physiologically relevant simulated gastrointestinal media, suggesting their potential application as sustained-release drug-delivery systems for poorly water-soluble drugs. In this study the potential of PHY and GMO to serve as sustained-release lipid vehicles for a model poorly-water-soluble drug, cinnarizine, was assessed and compared to that of an aqueous suspension formulation. Small-angle X-ray scattering was used to confirm the nanostructure of the liquid-crystalline matrix in the presence of the selected model drug, cinnarizine. Oral bioavailability studies were conducted in rats, and disposition of lipid and drug in segments of the gastrointestinal tract was determined over time. Differences in the digestibility and stability of formulations under digestion conditions were investigated using an in-vitro lipolysis model. The oral bioavailability of cinnarizine using the PHY formulation was 41%, compared to 19% for the GMO formulation and 6% for an aqueous suspension. The PHY formulation provided a T(max) for cinnarizine of 33 h, with absorption apparent up to 55 h after administration. In contrast, the T(max) for the GMO formulation was only 5 h. The PHY formulation was retained in the stomach for extended periods of time, with 56% of lipid remaining in the stomach after 24 h, in contrast to less than 1% of the GMO formulation after 8 h, suggesting that gastric retention was a key aspect of the prolonged period of absorption, which correlated with the formulations' relative susceptibility to in-vitro lipolysis and degradation. PHY provides a dramatic sustained-release effect for cinnarizine on oral administration, which is linked to gastric retention of the formulation and its ability to resist digestive processing. Poorly digested liquid crystal lipid formulations therefore offer a novel class of sustained

  5. Water: The Strangest Liquid

    Energy Technology Data Exchange (ETDEWEB)

    Nilsson, Anders

    2009-02-24

    Water, H2O, is familiar to everyone - it shapes our bodies and our planet. But despite its abundance, water has remained a mystery, exhibiting many strange properties that are still not understood. Why does the liquid have an unusually large capacity to store heat? And why is it denser than ice? Now, using the intense X-ray beams from particle accelerators, investigations into water are leading to fundamental discoveries about the structure and arrangement of water molecules. This lecture will elucidate the many mysteries of water and discuss current studies that are revolutionizing the way we see and understand one of the most fundamental substances of life.

  6. Towards sustainability in water recycling.

    Science.gov (United States)

    Sala, L; Serra, M

    2004-01-01

    Those like us who believe in and spread the gospel of planned wastewater reclamation and reuse usually emphasize that this is a step towards sustainability in water resource management, but this is something that is very seldom analyzed. This paper discusses, from a critical point of view, issues such as goals in water reuse and influence on water demands, ecological analysis of the cycle of the main pollutants, health aspects and treatment requirements, energy consumption and measurable environmental benefits, in order to provide a set of criteria to assess sustainability in water recycling projects and to decrease the impact of the cultural water cycle on the environment.

  7. Sustaining dry surfaces under water

    DEFF Research Database (Denmark)

    Jones, Paul R.; Hao, Xiuqing; Cruz-Chu, Eduardo R.

    2015-01-01

    not been investigated, and are critically important to maintain surfaces dry under water.In this work, we identify the critical roughness scale, below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys – thus keeping the immersed surface dry. Theoretical...

  8. Water Footprints and Sustainable Water Allocation

    Directory of Open Access Journals (Sweden)

    Arjen Y. Hoekstra

    2015-12-01

    Full Text Available Water Footprint Assessment (WFA is a quickly growing research field. This Special Issue contains a selection of papers advancing the field or showing innovative applications. The first seven papers are geographic WFA studies, from an urban to a continental scale; the next five papers have a global scope; the final five papers focus on water sustainability from the business point of view. The collection of papers shows that the historical picture of a town relying on its hinterland for its supply of water and food is no longer true: the water footprint of urban consumers is global. It has become clear that wise water governance is no longer the exclusive domain of government, even though water is and will remain a public resource with government in a primary role. With most water being used for producing our food and other consumer goods, and with product supply chains becoming increasingly complex and global, there is a growing awareness that consumers, companies and investors also have a key role. The interest in sustainable water use grows quickly, in both civil society and business communities, but the poor state of transparency of companies regarding their direct and indirect water use implies that there is still a long way to go before we can expect that companies effectively contribute to making water footprints more sustainable at a relevant scale.

  9. Ideas towards sustainable water security

    Science.gov (United States)

    Dalin, Carole

    2016-04-01

    With growing global demands and a changing climate, ensuring water security - the access to sufficient, quality water resources for health and livelihoods and an acceptable level of water related risk - is increasingly challenging. While a billion people still lack access to water, over-exploitation of this resource increases in many developed and developing parts of the world. While some solutions to water stress have been known for a long time, financial, cultural and political barriers often prevent their implementations. This talk will highlight three crucial areas that need to be addressed to progress towards sustainable water security. The first point is on scale, the second on the agricultural sector and irrigation, and the third on food trade and policy.

  10. Electrically excited liquid water

    NARCIS (Netherlands)

    Wexler, A.D.

    2016-01-01

    Water is essential to a healthy and secure world. Developing new technologies which can take full advantage of the unique attributes of water is important for meeting the ever increasing global demand while reducing the production footprint. Water exhibits unexpected departures in more than 70

  11. Global warming and water sustainability

    Directory of Open Access Journals (Sweden)

    Cassardo Claudio

    2014-03-01

    Full Text Available Water is a primary element in the human diet and a necessary resource for the agriculture. In addition, industrial practices need a growing amount of water. Since human population is continuously growing at a quasi-exponential rate, water demand, for domestic, agricultural and industrial uses, is increasing too. However, considering that the water resources on the Earth are finite, even disregarding the potential threats due to the climate change, this situation appears as one of the biggest challenges of the current era. Actually, one-third of the world’s population is water-stressed, of which 12% severely: in these nations, a large portion of the population lives below the minimum threshold judged permissible for a decent life. In practice, almost every nation deals with problems related to water sustainability. In some countries, the water supply is ensured only thanks to the extraction of fossil water, which is a limited resource that will not last indefinitely. The impact on water quality has also dramatically increased. The scarcity of water resources is expected to spread to wider areas in the near future, mostly in developing countries, if the actual trends of development and population growth do not change. The rapid urbanizing rate will also create additional stress. Climate change can in turn alter both water supply and demand: increasing temperatures will reflect in increased evaporation and decreased stream flows. Rising seas could contaminate groundwater resources, and increasingly variable precipitation will likely mean more frequent high-intensity droughts and floods and less available rainfall in arid and semiarid regions. The effects of these changes will increase the natural variability of the climate, exacerbating the extreme climatic phenomena (drought and flood events, increasing the difficulty of managing water resources, especially in the most vulnerable regions, and affecting water availability even in regions that are

  12. WATER MANAGEMENT AND SUSTAINABLE DEVELOPMENT

    Directory of Open Access Journals (Sweden)

    Safer Karima

    2014-11-01

    Full Text Available «Of course I wish I was in school. I want to learn, I want to read and write... But how mom need me to fetch water» - Benny Bazan, Bolivia; «…the factories consume a lot of water, while we can hardly find enough basic our needs, not to mention what we need to irrigate crops» - Gopal Jojor, India. Voices are united by the same thing: the denial of access to water. It’s what began the United Nations report of human development for the year 2006. The observed increase of the population and increasing water pressure to use some form of this article despite the enormous availability and large, underground or surface quantities, but the supply and demand equation is no longer as in the past in spite of the new techniques introduced Kthalih seawater. And has worked to highlight the importance of this element as the most important determinants of sustainable development, which aims to rationality and adulthood and dealing with efforts to achieve growth and meet the needs of the population of housing and economic activities and food and education, without prejudice to the negative form of ecological, and sustainable development is the way only to ensure a good quality of life for residents of the present and the future.

  13. Sustaining Waters: From Hydrology to Drinking Water

    Science.gov (United States)

    Toch, S.

    2003-04-01

    Around the world, disastrous effects of floods and droughts are painful evidence of our continuing struggle between human resource demands and the sustainability of our hydrologic systems. Too much or too little rainfall is often deemed the culprit in these water crises, focussing on water "lacks and needs" instead of exploring the mechanisms of the hydrologic functions and processes that sustain us. Applicable to regions around the world, this unified approach is about our human and environmental qualities with user friendly concepts and how-to guides backed up by real life experiences. From the poorest parts of Africa to Urban France to the wealthest state in the USA, examples from surface to groundwater to marine environments demonstrate how the links between vulerable natural areas, and the basins that they support are integral to the availability, adequacy and accessibility of our drinking water. Watershed management can be an effective means for crisis intervention and pollution control. This project is geared as a reference for groups, individuals and agencies concerned with watershed management, a supplement for interdisciplinary high school through university curriculam, for professional development in technical and field assistance, and for community awareness in the trade-offs and consequences of resource decisions that affect hydrologic systems. This community-based project demonstrates how our human resource demands can be managed within ecological constraints. An inter-disciplinary process is developed that specifically assesses risk to human health from resource use practices, and explores the similarities and interations between our human needs and those of the ecosystems in which we all must live together. Disastrous conditions worldwide have triggered reactions in crisis relief rather than crisis prevention. Through a unified management approach to the preservation of water quality, the flows of water that connect all water users can serve as a

  14. Electron affinity of liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Gaiduk, Alex P.; Pham, Tuan Anh; Govoni, Marco; Paesani, Francesco; Galli, Giulia

    2018-01-16

    Understanding redox and photochemical reactions in aqueous environments requires a precise knowledge of the ionization potential and electron affinity of liquid water. The former has been measured, but not the latter. We predict the electron affinity of liquid water and of its surface from first principles, coupling path-integral molecular dynamics with ab initio potentials, and many-body perturbation theory. Our results for the surface (0.8 eV) agree well with recent pump-probe spectroscopy measurements on amorphous ice. Those for the bulk (0.1–0.3 eV) differ from several estimates adopted in the literature, which we critically revisit. We show that the ionization potential of the bulk and surface are almost identical; instead their electron affinities differ substantially, with the conduction band edge of the surface much deeper in energy than that of the bulk. We also discuss the significant impact of nuclear quantum effects on the fundamental gap and band edges of the liquid.

  15. Water Quality and Sustainable Environmental Health

    Science.gov (United States)

    Setegn, S. G.

    2014-12-01

    Lack of adequate safe water, the pollution of the aquatic environment and the mismanagement of resources are major causes of ill-health and mortality, particularly in the developing countries. In order to accommodate more growth, sustainable fresh water resource management will need to be included in future development plans. One of the major environmental issues of concern to policy-makers is the increased vulnerability of ground water quality. The main challenge for the sustainability of water resources is the control of water pollution. To understand the sustainability of the water resources, one needs to understand the impact of future land use and climate changes on the natural resources. Providing safe water and basic sanitation to meet the Millennium Development Goals will require substantial economic resources, sustainable technological solutions and courageous political will. A balanced approach to water resources exploitation for development, on the one hand, and controls for the protection of health, on the other, is required if the benefits of both are to be realized without avoidable detrimental effects manifesting themselves. Meeting the millennium development goals for water and sanitation in the next decade will require substantial economic resources, sustainable technological solutions and courageous political will. In addition to providing "improved" water and "basic" sanitation services, we must ensure that these services provide: safe drinking water, adequate quantities of water for health, hygiene, agriculture and development and sustainable sanitation approaches to protect health and the environment.

  16. Sustainable fishing of inland waters

    Directory of Open Access Journals (Sweden)

    Jeppe Kolding

    2014-04-01

    Full Text Available Sustainability in fisheries has over the past decades evolved from a single species maximization concept to covering ecosystem and biodiversity considerations. This expansion of the notion, together with increased evidence that the targeted removal of selected components of the fish community may have adverse ecological consequences, poses a serious dilemma to the conventional fisheries management approach of protecting juveniles and targeting adults. Recently, the idea of balanced harvest, i.e., harvesting all components in the ecosystem in proportion to their productivity, has been promoted as a unifying solution in accordance with the ecosystem approach to fisheries, but this will require a fundamental change to management. In this paper, we review the objectives, theoretical background, and practicalities of securing high yielding fisheries in inland waters, with empirical examples from tropical freshwater fisheries which satisfy the extended objectives of minimal impact on community and ecosystem structure. We propose a framework of ecological indicators to assess these objectives.  Normal 0 false false false EN-GB ZH-CN HE

  17. Urban water sustainability: framework and application

    OpenAIRE

    Wu Yang; David W Hyndman; Winkler, Julie A.; Andrés Viña; Jillian M. Deines; Frank Lupi; Lifeng Luo; Yunkai Li; Bruno Basso; Chunmiao Zheng; Dongchun Ma; Shuxin Li; Xiao Liu; Hua Zheng; Guoliang Cao

    2016-01-01

    Urban areas such as megacities (those with populations greater than 10 million) are hotspots of global water use and thus face intense water management challenges. Urban areas are influenced by local interactions between human and natural systems and interact with distant systems through flows of water, food, energy, people, information, and capital. However, analyses of water sustainability and the management of water flows in urban areas are often fragmented. There is a strong need to apply...

  18. Assessing Water and Carbon Footprints for Sustainable Water Resource Management

    Science.gov (United States)

    The key points of this presentation are: (1) Water footprint and carbon footprint as two sustainability attributes in adaptations to climate and socioeconomic changes, (2) Necessary to evaluate carbon and water footprints relative to constraints in resource capacity, (3) Critical...

  19. Sustainable development of water resources, water supply and environmental sanitation.

    CSIR Research Space (South Africa)

    Austin, LM

    2006-01-01

    Full Text Available , Colombo, Sri Lanka, 2006 SUSTAINABLE DEVELOPMENT OF WATER RESOURCES, WATER SUPPLY AND ENVIRONMENTAL SANITATION Operational safety of urine diversion toilets in Durban, South Africa L M Austin, South Africa There are approximately 50 000...

  20. Toward A Science of Sustainable Water Management

    Science.gov (United States)

    Brown, C.

    2016-12-01

    Societal need for improved water management and concerns for the long-term sustainability of water resources systems are prominent around the world. The continued susceptibility of society to the harmful effects of hydrologic variability, pervasive concerns related to climate change and the emergent awareness of devastating effects of current practice on aquatic ecosystems all illustrate our limited understanding of how water ought to be managed in a dynamic world. The related challenges of resolving the competition for freshwater among competing uses (so called "nexus" issues) and adapting water resources systems to climate change are prominent examples of the of sustainable water management challenges. In addition, largely untested concepts such as "integrated water resources management" have surfaced as Sustainable Development Goals. In this presentation, we argue that for research to improve water management, and for practice to inspire better research, a new focus is required, one that bridges disciplinary barriers between the water resources research focus on infrastructure planning and management, and the role of human actors, and geophysical sciences community focus on physical processes in the absence of dynamical human response. Examples drawn from climate change adaptation for water resource systems and groundwater management policy provide evidence of initial progress towards a science of sustainable water management that links improved physical understanding of the hydrological cycle with the socioeconomic and ecological understanding of water and societal interactions.

  1. Global warming and water sustainability

    OpenAIRE

    Cassardo Claudio

    2014-01-01

    Water is a primary element in the human diet and a necessary resource for the agriculture. In addition, industrial practices need a growing amount of water. Since human population is continuously growing at a quasi-exponential rate, water demand, for domestic, agricultural and industrial uses, is increasing too. However, considering that the water resources on the Earth are finite, even disregarding the potential threats due to the climate change, this situation appears as one of the biggest ...

  2. Towards sustainable water management in Algeria

    KAUST Repository

    Drouiche, Nadjib

    2012-12-01

    Algeria aspires to protect its water resources and to provide a sustainable answer to water supply and management issues by carrying out a national water plan. This program is in line with all projects the Algerian Government is implementing to improve its water sector performance. The water strategy focuses on desalination for the coastal cities, medium-sized dams to irrigate the inland mountains and high plateau, and ambitious water transfer projects interconnecting Algeria\\'s 65 dams to bring water to water scarce parts of the country. Waste water treatment and water reclamation technologies are also highly sought after. The main objective of the country\\'s water policy consists on providing sufficient potable water for the population supply. This objective is undertaken by increasing the water resources and availability. © 2012 Desalination Publications. All rights reserved.

  3. Dipolar correlations in liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Cui [Department of Chemistry, Princeton University, Princeton, New Jersey 08544 (United States); Galli, Giulia, E-mail: gagalli@uchicago.edu [Institute for Molecular Engineering, The University of Chicago, Chicago, Illinois 60637 (United States)

    2014-08-28

    We present an analysis of the dipolar correlations in water as a function of temperature and density and in the presence of simple ionic solutes, carried out using molecular dynamics simulations and empirical potentials. We show that the dipole-dipole correlation function of the liquid exhibits sizable oscillations over nanodomains of about 1.5 nm radius, with several isosbestic points as a function of temperature; the size of the nanodomains is nearly independent on temperature and density, between 240 and 400 K and 0.9 and 1.3 g/cm{sup 3}, but it is substantially affected by the presence of solvated ions. In the same range of thermodynamic conditions, the decay time (τ) of the system dipole moment varies by a factor of about 30 and 1.5, as a function of temperature and density, respectively. At 300 K, we observed a maximum in τ as a function of density, and a corresponding shallow maximum in the tetrahedral order parameter, in a range where the diffusion coefficient, the pressure and the dielectric constant increase monotonically.

  4. Dipolar correlations in liquid water.

    Science.gov (United States)

    Zhang, Cui; Galli, Giulia

    2014-08-28

    We present an analysis of the dipolar correlations in water as a function of temperature and density and in the presence of simple ionic solutes, carried out using molecular dynamics simulations and empirical potentials. We show that the dipole-dipole correlation function of the liquid exhibits sizable oscillations over nanodomains of about 1.5 nm radius, with several isosbestic points as a function of temperature; the size of the nanodomains is nearly independent on temperature and density, between 240 and 400 K and 0.9 and 1.3 g/cm(3), but it is substantially affected by the presence of solvated ions. In the same range of thermodynamic conditions, the decay time (τ) of the system dipole moment varies by a factor of about 30 and 1.5, as a function of temperature and density, respectively. At 300 K, we observed a maximum in τ as a function of density, and a corresponding shallow maximum in the tetrahedral order parameter, in a range where the diffusion coefficient, the pressure and the dielectric constant increase monotonically.

  5. Shallow Water Tuned Liquid Dampers

    DEFF Research Database (Denmark)

    Krabbenhøft, Jørgen

    The use of sloshing liquid as a passive means of suppressing the rolling motion of ships was proposed already in the late 19th century. Some hundred years later the use of liquid sloshing devices, often termed Tuned Liquid Dampers (TLD), began to find use in the civil engineering community...... that for realistic roughness parameters the bottom friction has very limited effect on the liquid sloshing behavior and can be neglected. Herby the postulate is verified. Based on the mathematical model three dimensionless parameters are derived showing that the response of the damper depends solely on ratio...

  6. Environmental Impact Assessment in Sustainable Water Resources ...

    African Journals Online (AJOL)

    The main purpose of this paper is to review the current level of understanding of environmental impact assessment of water resources development; to assess the major challenges to sustainable environmental systems from water resources development perspectives, and to identify major environmental issues that need to ...

  7. Electrokinetic Power Generation from Liquid Water Microjets

    Energy Technology Data Exchange (ETDEWEB)

    Duffin, Andrew M.; Saykally, Richard J.

    2008-02-15

    Although electrokinetic effects are not new, only recently have they been investigated for possible use in energy conversion devices. We have recently reported the electrokinetic generation of molecular hydrogen from rapidly flowing liquid water microjets [Duffin et al. JPCC 2007, 111, 12031]. Here, we describe the use of liquid water microjets for direct conversion of electrokinetic energy to electrical power. Previous studies of electrokinetic power production have reported low efficiencies ({approx}3%), limited by back conduction of ions at the surface and in the bulk liquid. Liquid microjets eliminate energy dissipation due to back conduction and, measuring only at the jet target, yield conversion efficiencies exceeding 10%.

  8. Urban water sustainability: framework and application

    Directory of Open Access Journals (Sweden)

    Wu Yang

    2016-12-01

    Full Text Available Urban areas such as megacities (those with populations greater than 10 million are hotspots of global water use and thus face intense water management challenges. Urban areas are influenced by local interactions between human and natural systems and interact with distant systems through flows of water, food, energy, people, information, and capital. However, analyses of water sustainability and the management of water flows in urban areas are often fragmented. There is a strong need to apply integrated frameworks to systematically analyze urban water dynamics and factors that influence these dynamics. We apply the framework of telecoupling (socioeconomic and environmental interactions over distances to analyze urban water issues, using Beijing as a demonstration megacity. Beijing exemplifies the global water sustainability challenge for urban settings. Like many other cities, Beijing has experienced drastic reductions in quantity and quality of both surface water and groundwater over the past several decades; it relies on the import of real and virtual water from sending systems to meet its demand for clean water, and releases polluted water to other systems (spillover systems. The integrative framework we present demonstrates the importance of considering socioeconomic and environmental interactions across telecoupled human and natural systems, which include not only Beijing (the water-receiving system but also water-sending systems and spillover systems. This framework helps integrate important components of local and distant human-nature interactions and incorporates a wide range of local couplings and telecouplings that affect water dynamics, which in turn generate significant socioeconomic and environmental consequences, including feedback effects. The application of the framework to Beijing reveals many research gaps and management needs. We also provide a foundation to apply the telecoupling framework to better understand and manage water

  9. Is light water reactor technology sustainable?

    Energy Technology Data Exchange (ETDEWEB)

    Rothwell, G. [Stanford Univ., Dept. of Economics, CA (United States); Van der Zwaan, B. [Vrije Univ., Amsterdam, Inst. for Environmental Studies (Netherlands)

    2001-07-01

    This paper proposes criteria for determining ''intermediate sustainability'' over a 500-year horizon. We apply these criteria to Light Water Reactor (LWR) technology and the LWR industry. We conclude that LWR technology does not violate intermediate sustainability criteria for (1) environmental externalities, (2) worker and public health and safety, or (3) accidental radioactive release. However, it does not meet criteria to (1) efficiently use depleted uranium and (2) avoid uranium enrichment technologies that can lead to nuclear weapons proliferation. Finally, current and future global demand for LWR technology might be below the minimum needed to sustain the current global LWR industry. (author)

  10. Sustainable use of water resources

    DEFF Research Database (Denmark)

    Battilani, A; Jensen, Christian Richardt; Liu, Fulai

    2013-01-01

    , there was no difference between RDI and PRD for the total and marketable yield. In 2008, PRD increased the marketable yield by 14.8% while the total yield was similar to RDI. Water Use Efficiency (WUE) was higher with PRD (+14%) compared to RDI. PRD didn’t improve fruit quality, although in 2007 a better °Brix, colour...... and acidity were observed. PRD reduced irrigation water volume (-9.0% of RDI) while a higher dry matter accumulation in the fruits was recorded both in 2007 and 2008. The income for each cubic meter of irrigation water was 10.6 € in RDI and 14.8 € in PRD, respectively. The gross margin obtained with each kg......A field experiment was carried out in Northern Italy, within the frame of the EU project SAFIR, to test the feasibility of partial root-zone drying (PRD) management on processing tomato and to compare PRD irrigation strategy with regulated deficit irrigation (RDI) management. In 2007...

  11. Evaluating Water Management Practice for Sustainable Mining

    Directory of Open Access Journals (Sweden)

    Xiangfeng Zhang

    2014-02-01

    Full Text Available To move towards sustainable development, the mining industry needs to identify better mine water management practices for reducing raw water use, increasing water use efficiency, and eliminating environmental impacts in a precondition of securing mining production. However, the selection of optimal mine water management practices is technically challenging due to the lack of scientific tools to comprehensively evaluate management options against a set of conflicting criteria. This work has provided a solution to aid the identification of more sustainable mine water management practices. The solution includes a conceptual framework for forming a decision hierarchy; an evaluation method for assessing mine water management practices; and a sensitivity analysis in view of different preferences of stakeholders or managers. The solution is applied to a case study of the evaluation of sustainable water management practices in 16 mines located in the Bowen Basin in Queensland, Australia. The evaluation results illustrate the usefulness of the proposed solution. A sensitivity analysis is performed according to preference weights of stakeholders or managers. Some measures are provided for assessing sensitivity of strategy ranking outcomes if the weight of an indicator changes. Finally, some advice is given to improve the mine water management in some mines.

  12. Global cloud liquid water path simulations

    Energy Technology Data Exchange (ETDEWEB)

    Lemus, L. [Southern Hemisphere Meteorology, Clayton, Victoria (Australia); Rikus, L. [Bureau of Meteorology Research Centre, Melbourne, Victoria (Australia); Martin, C.; Platt, R. [CSIRO, Aspendale, Victoria (Australia)

    1997-01-01

    A new parameterization of cloud liquid water and ice content has been included in the Bureau of Meteorology Global Assimilation and Prediction System. The cloud liquid water content is derived from the mean cloud temperatures in the model using an empirical relationship based on observations. The results from perpetual January and July simulations are presented and show that the total cloud water path steadily decreases toward high latitudes, with two relative maxima at midlatitudes and a peak at low latitudes. To validate the scheme, the simulated fields need to be processed to produce liquid water paths that can be directly compared with the corresponding field derived from Special Sensor Microwave/Imager (SSM/I) data. This requires the identification of cloud ice water content within the parameterization and a prescription to account for the treatment of strongly precipitating subgrid-scale cloud. The resultant cloud liquid water paths agree qualitatively with the SSM/I data but show some systematic errors that are attributed to corresponding errors in the model`s simulation of cloud amounts. Given that a more quantitative validation requires substantial improvement in the model`s diagnostic cloud scheme, the comparison with the SSM/I data indicates that the cloud water path, derived from the cloud liquid water content parameterization introduced in this paper, is consistent with the observations and can be usefully incorporated in the prediction system. 40 refs., 11 figs., 1 tab.

  13. ASSET AND AGENT IN ACHIEVING SUSTAINABLE WATER ...

    African Journals Online (AJOL)

    urban water supply as well as tremendous impact on the urban natural environment. Added to this, is the anthropogenitic .... pose threats to ecosystems health and the well-being of urban environments in general. Urban sustainability proponents ... infrastructure in good working condition. Protecting the infrastructure used to ...

  14. Sustainable treatment of municipal waste water

    DEFF Research Database (Denmark)

    Hansen, Peter Augusto; Larsen, Henrik Fred

    The main goal of the EU FP6 NEPTUNE program is to develop new and improve existing waste water treatment technologies (WWTT) and sludge handling technologies for municipal waste water, in accordance with the concepts behind the EU Water Framework Directive. As part of this work, the project.......e. heavy metals, pharmaceuticals and endocrine disruptors) in the waste water. As a novel approach, the potential ecotoxicity and human toxicity impacts from a high number of micropollutants and the potential impacts from pathogens will be included. In total, more that 20 different waste water and sludge...... treatment technologies are to be assessed. This paper will present the first LCA results from running existing life cycle impact assessment (LCIA) methodology on some of the waste water treatment technologies. Keywords: Sustainability, LCA, micropollutants, waste water treatment technologies....

  15. WATER AND ARCHAEOLOGY FOR SUSTAINABLE TOURISM

    Directory of Open Access Journals (Sweden)

    NICHOLAS KATHIJOTES

    2016-03-01

    Full Text Available Water is undoubtedly the most precious resource of the planet and the accessibility to water resources marked the history of mankind since the dawn of times. Water has been indeed very central to archaeology and anthropology, that studied the ways in which water was provisioned, tanked, distributed, worshipped, exploited for agricultural irrigation or to power machines like water-mills, used for leisure, hygiene and healing, or abused to confer power on particular groups ,and how it played a central role in political and economic strategies. More than any other factor, waterways marked cultural and economic developments in history. This paper outlines examples of water resources management throughout the ages, in Cyprus and the Hellenic Civilization on different aspects of the use and management of water, investigates technical issues and gives suggestions, thus promoting a new approach to archaeological heritage and sustainable tourism.

  16. Liquid Water may Stick on Hydrophobic Surfaces

    Indian Academy of Sciences (India)

    IAS Admin

    The behavior of fluid on a solid surface under static and dynamic conditions are usually clubbed together. • On a wetting surface (hydrophilic), liquid water is believed to adhere to the surface causing multilayer sticking. • On a non-wetting surface (hydrophobic), water is believed to glide across the surface leading to slip ...

  17. Water Sustainability Assessment for Ten Army Installations

    Science.gov (United States)

    2011-03-26

    the severity of this scarcity varies by scenario. It seems that natural condi- tions play a bigger part in water availability for the region than does...question lies with: (1) a picture of how short-term water scarcity might play out across the region, which is outside of the scope of this study, and...ER D C/ CE RL T R- 11 -5 Water Sustainability Assessment for Ten Army Installations Co ns tr uc tio n En gi ne er in g R es

  18. Electromagnetically Sustained Liquid Metal Flow for Feedback Stabilization Studies

    Science.gov (United States)

    Mirhoseini, Seyyed Mohammad; Volpe, Francesco

    2015-11-01

    Liquid metal walls in fusion reactors, whether nearly static or rapidly flowing, will be subject to instabilities that will make them locally bulge, thus entering in contact with the plasma, or deplete, hence exposing the underlying solid substrate. To prevent this, research has begun at Columbia University to create liquid metal flows and demonstrate their stabilization by electromagnetic forces, adjusted in feedback with thickness measurements. Here we present initial results regarding the sustainment of a flow of Galinstan (a gallium, indium, tin alloy) by a special pump consisting of a ferromagnetic rotor, with permanent magnets mounted on it. The magnetic field is partly ``frozen'' in the liquid metal surrounding the rotor. Therefore, as the field rotates, the liquid metal rotates as well, although with a slip factor. This solution was preferred to conventional pumps, which would enter in electrical contact with the metal flow. The pump, 3D-printed at Columbia, allows to adjust the flow-velocity from few mm/s to several cm/s.

  19. Sustainable agricultural water management across climates

    Science.gov (United States)

    DeVincentis, A.

    2016-12-01

    Fresh water scarcity is a global problem with local solutions. Agriculture is one of many human systems threatened by water deficits, and faces unique supply, demand, quality, and management challenges as the global climate changes and population grows. Sustainable agricultural water management is paramount to protecting global economies and ecosystems, but requires different approaches based on environmental conditions, social structures, and resource availability. This research compares water used by conservation agriculture in temperate and tropical agroecosystems through data collected from operations growing strawberries, grapes, tomatoes, and pistachios in California and corn and soybeans in Colombia. The highly manipulated hydrologic regime in California has depleted water resources and incited various adaptive management strategies, varying based on crop type and location throughout the state. Operations have to use less water more efficiently, and sometimes that means fallowing land in select groundwater basins. At the opposite end of the spectrum, the largely untouched landscape in the eastern plains of Colombia are rapidly being converted into commercial agricultural operations, with a unique opportunity to manage and plan for agricultural development with sustainability in mind. Although influenced by entirely different climates and economies, there are some similarities in agricultural water management strategies that could be applicable worldwide. Cover crops are a successful management strategy for both agricultural regimes, and moving forward it appears that farmers who work in coordination with their neighbors to plan for optimal production will be most successful in both locations. This research points to the required coordination of agricultural extension services as a critical component to sustainable water use, successful economies, and protected environments.

  20. Water Contaminant Mitigation in Ionic Liquid Propellant

    Science.gov (United States)

    Conroy, David; Ziemer, John

    2009-01-01

    Appropriate system and operational requirements are needed in order to ensure mission success without unnecessary cost. Purity requirements applied to thruster propellants may flow down to materials and operations as well as the propellant preparation itself. Colloid electrospray thrusters function by applying a large potential to a room temperature liquid propellant (such as an ionic liquid), inducing formation of a Taylor cone. Ions and droplets are ejected from the Taylor cone and accelerated through a strong electric field. Electrospray thrusters are highly efficient, precise, scaleable, and demonstrate low thrust noise. Ionic liquid propellants have excellent properties for use as electrospray propellants, but can be hampered by impurities, owing to their solvent capabilities. Of foremost concern is the water content, which can result from exposure to atmosphere. Even hydrophobic ionic liquids have been shown to absorb water from the air. In order to mitigate the risks of bubble formation in feed systems caused by water content of the ionic liquid propellant, physical properties of the ionic liquid EMI-Im are analyzed. The effects of surface tension, material wetting, physisorption, and geometric details of the flow manifold and electrospray emitters are explored. Results are compared to laboratory test data.

  1. Liquid Water Restricts Habitability in Extreme Deserts.

    Science.gov (United States)

    Cockell, Charles S; Brown, Sarah; Landenmark, Hanna; Samuels, Toby; Siddall, Rebecca; Wadsworth, Jennifer

    2017-04-01

    Liquid water is a requirement for biochemistry, yet under some circumstances it is deleterious to life. Here, we show that liquid water reduces the upper temperature survival limit for two extremophilic photosynthetic microorganisms (Gloeocapsa and Chroococcidiopsis spp.) by greater than 40°C under hydrated conditions compared to desiccated conditions. Under hydrated conditions, thermal stress causes protein inactivation as shown by the fluorescein diacetate assay. The presence of water was also found to enhance the deleterious effects of freeze-thaw in Chroococcidiopsis sp. In the presence of water, short-wavelength UV radiation more effectively kills Gloeocapsa sp. colonies, which we hypothesize is caused by factors including the greater penetration of UV radiation into hydrated colonies compared to desiccated colonies. The data predict that deserts where maximum thermal stress or irradiation occurs in conjunction with the presence of liquid water may be less habitable to some organisms than more extreme arid deserts where organisms can dehydrate prior to being exposed to these extremes, thus minimizing thermal and radiation damage. Life in extreme deserts is poised between the deleterious effects of the presence and the lack of liquid water. Key Words: Deserts-Extremophiles-Stress-High temperatures-UV radiation-Desiccation. Astrobiology 17, 309-318.

  2. Following the Water Cycle to Sustainability

    Science.gov (United States)

    Lutz, T. M.

    2012-12-01

    For scientists, modeling the connections among the parts of complex, dynamic systems is crucial. Doing so lets us understand emergent phenomena such as ecosystem behavior and climate patterns that could not otherwise be predicted. Emergent phenomena can typically only be understood or appreciated when we stand "outside" the system. When scientists take such an outsiders view of earth's systems they can propose many ways that human activities modify the climate system (e.g., increasing or reducing GHG emissions). But what should we do to achieve a sustainable future? Sustainability is an emergent property that arises at the level of the planetary management system, of which the scientific establishment is just a part. We are "insiders" and it is impossible to completely envision the conditions for sustainability or to plan for it. The crises in our atmosphere, biosphere, oceans, and in the natural and energy resource sectors are based in science and do call for urgent changes in science education. But education that focuses solely on science to meet the challenges of sustainability may be as likely to harm humanity's long-term prospects as to improve them. I present activities and teaching strategies that I use in general education classes at West Chester University, a comprehensive institution of roughly 14,000 undergraduates. The overarching concept is to extend "modeling the connections" to the sustainability level and to train students to think outside the system. To make the ideas more accessible, I have the students become sensors at their particular point in the web of connections that constitute the planetary management system. I ask them to evaluate their connection in three domains proposed by John Ehrenfeld (Sustainability by Design, Yale University Press, 2008): sense of place in the natural world; sense of responsibility for our actions, and sense of what it is to be a human being. I have them analyze their sense of connection with reference to a

  3. A review on water pricing problem for sustainable water resource

    Science.gov (United States)

    Hek, Tan Kim; Ramli, Mohammad Fadzli; Iryanto

    2017-05-01

    A report that presented at the World Forum II at The Hague in March 2000, said that it would be water crisis around the world and some countries will be lack of water in 2025, as a result of global studies. Inefficient using of water and considering water as free goods which means it can be used as much as we want without any lost. Thus, it causes wasteful consumption and low public awareness in using water without effort to preserve and conserve the water resources. In addition, the excessive exploitation of ground water for industrial facilities also leads to declining of available freshwater. Therefore, this paper reviews some problems arise all over the world regarding to improper and improving management, policies and methods to determine the optimum model of freshwater price in order to avoid its wasteful thus ensuring its sustainability. In this paper, we also proposed a preliminary model of water pricing represents a case of Medan, North Sumatera, Indonesia.

  4. Water: A Tale of Two Liquids

    Science.gov (United States)

    2016-01-01

    Water is the most abundant liquid on earth and also the substance with the largest number of anomalies in its properties. It is a prerequisite for life and as such a most important subject of current research in chemical physics and physical chemistry. In spite of its simplicity as a liquid, it has an enormously rich phase diagram where different types of ices, amorphous phases, and anomalies disclose a path that points to unique thermodynamics of its supercooled liquid state that still hides many unraveled secrets. In this review we describe the behavior of water in the regime from ambient conditions to the deeply supercooled region. The review describes simulations and experiments on this anomalous liquid. Several scenarios have been proposed to explain the anomalous properties that become strongly enhanced in the supercooled region. Among those, the second critical-point scenario has been investigated extensively, and at present most experimental evidence point to this scenario. Starting from very low temperatures, a coexistence line between a high-density amorphous phase and a low-density amorphous phase would continue in a coexistence line between a high-density and a low-density liquid phase terminating in a liquid–liquid critical point, LLCP. On approaching this LLCP from the one-phase region, a crossover in thermodynamics and dynamics can be found. This is discussed based on a picture of a temperature-dependent balance between a high-density liquid and a low-density liquid favored by, respectively, entropy and enthalpy, leading to a consistent picture of the thermodynamics of bulk water. Ice nucleation is also discussed, since this is what severely impedes experimental investigation of the vicinity of the proposed LLCP. Experimental investigation of stretched water, i.e., water at negative pressure, gives access to a different regime of the complex water diagram. Different ways to inhibit crystallization through confinement and aqueous solutions are

  5. Sustainability evaluation of water supply technologies

    DEFF Research Database (Denmark)

    Godskesen, Berit

    - & stormwater harvesting as the most environmentally friendly technology followed by the cases relying on groundwater abstraction. The least favorable case is desalination of seawater. Rain- & stormwater harvesting and desalination have markedly lower environmental impacts in the use stage compared to the base...... data was extracted from the national implementation of the EU water framework directive. When incorporating the impacts of freshwater withdrawal in addition to the standard LCA the rank order is partly reversed since rain- & stormwater harvesting and desalination are significantly more preferable...... showed that the result depends upon the weighting of the sustainability categories. This study shows that when the highest weight is assigned to environment then the case of rain- & stormwater harvesting is the most sustainable followed by desalination of seawater. When the highest weight was assigned...

  6. Sustainable Water Use System of Artesian Water in Alluvial Fan

    Science.gov (United States)

    Kishi, K.; Tsujimura, M.; Tase, N.

    2013-12-01

    The traditional water use system, developed with the intelligence of the local residents, usually takes advantage of local natural resources and is considered as a sustainable system, because of its energy saving(only forces of nature). For this reason, such kind of water use system is also recommended in some strategic policies for the purpose of a symbiosis between nature and human society. Therefore, it is important to clarify the relationship between human activities and water use systems. This study aims to clarify the mechanism of traditional water use processes in alluvial fan, and in addition, to investigate the important factors which help forming a sustainable water use system from the aspects of natural conditions and human activities. The study area, an alluvial fan region named Adogawa, is located in Shiga Prefecture, Japan and is in the west of Biwa Lake which is the largest lake in Japan. In this alluvial region where the land use is mainly occupied by settlements and paddy fields, a groundwater flowing well system is called "kabata" according to local tradition. During field survey, we took samples of groundwater, river water and lake water as well as measured the potential head of groundwater. The results showed that the upper boundary of flowing water was approximately 88m amsl, which is basically the same as the results reported by Kishi and Kanno (1966). In study area, a rapid increase of water pumping for domestic water use and melting snow during last 50 years, even if the irrigation area has decreased about 30% since 1970, and this fact may cause a decrease in recharge rate to groundwater. However, the groundwater level didn't decline based on the observed results, which is probably contributed by some water conservancy projects on Biwa Lake which maintained the water level of the lake. All the water samples are characterized by Ca-HCO3 type and similar stable isotopic value of δD and δ18O. Groundwater level in irrigation season is higher

  7. Integrated water resources modelling for assessing sustainable water governance

    Science.gov (United States)

    Skoulikaris, Charalampos; Ganoulis, Jacques; Tsoukalas, Ioannis; Makropoulos, Christos; Gkatzogianni, Eleni; Michas, Spyros

    2015-04-01

    Climatic variations and resulting future uncertainties, increasing anthropogenic pressures, changes in political boundaries, ineffective or dysfunctional governance of natural resources and environmental degradation are some of the most fundamental challenges with which worldwide initiatives fostering the "think globally, act locally" concept are concerned. Different initiatives target the protection of the environment through sustainable development; Integrated Water Resources Management (IWRM) and Transboundary Water Resources Management (TWRM) in the case of internationally shared waters are frameworks that have gained wide political acceptance at international level and form part of water resources management planning and implementation on a global scale. Both concepts contribute in promoting economic efficiency, social equity and environmental sustainability. Inspired by these holistic management approaches, the present work describes an effort that uses integrated water resources modelling for the development of an integrated, coherent and flexible water governance tool. This work in which a sequence of computer based models and tools are linked together, aims at the evaluation of the sustainable operation of projects generating renewable energy from water as well as the sustainability of agricultural demands and environmental security in terms of environmental flow under various climatic and operational conditions. More specifically, catchment hydrological modelling is coupled with dams' simulation models and thereafter with models dedicated to water resources management and planning,while the bridging of models is conducted through geographic information systems and custom programming tools. For the case of Mesta/Nestos river basin different priority rules in the dams' operational schedule (e.g. priority given to power production as opposed to irrigation needs and vice versa), as well as different irrigation demands, e.g. current water demands as opposed to

  8. Sustainable Energy, Water and Environmental Systems

    DEFF Research Database (Denmark)

    Østergaard, Poul Alberg; Duic, Neven

    2014-01-01

    This issue presents research results from the 8th Conference on Sustainable Development of Energy, Water and Environment Systems – SDEWES - held in Dubrovnik, Croatia in 2013. Topics covered here include the energy situation in the Middle East with a focus in Cyprus and Israel, energy planning...... methodology with Ireland as a case and the applicability of energy scenarios modelling tools as a main focus, evaluation of energy demands in Italy and finally evaluation of underground cables vs overhead lines and lacking public acceptance of incurring additional costs for the added benefit of having...

  9. Sustainable Energy, Water and Environmental Systems

    Directory of Open Access Journals (Sweden)

    Poul Alberg Østergaard

    2014-06-01

    Full Text Available This issue presents research results from the 8th Conference on Sustainable Development of Energy, Water and Environment Systems – SDEWES - held in Dubrovnik, Croatia in 2013. Topics covered here include the energy situation in the Middle East with a focus in Cyprus and Israel, energy planning methodology with Ireland as a case and the applicability of energy scenarios modelling tools as a main focus, evaluation of energy demands in Italy and finally evaluation of underground cables vs overhead lines and lacking public acceptance of incurring additional costs for the added benefit of having transmission beyond sight.

  10. Sustainable Water Supplies in Uppsala, Sweden?

    Science.gov (United States)

    Eriksson, Bert

    2014-05-01

    This is a description of a transdisciplinary three-day project with upper secondary school students around ecosystem services and sustainability. Uppsala (200 000 inhabitants) gets its municipal water from wells in the esker that dominates the landscape in and around the town. This esker was formed by glacial melt water around 11 000 BP, at the end of the latest glaciation and was lifted above sea level by post-glacial land rise from 6000 BP. To keep up the water table in the esker, water from river Fyris is pumped up and infiltrated in the esker. The river is also the recipient of wastewater downstream of the town, and the river runs out into Lake Mälaren that in its turn spills out into the Baltic Sea through Stockholm. The esker and river can thus be a central topic to work around, in Biology and Geography in upper secondary school, concerning recent and future water supplies, quaternary geology, limnology and landscape history. The fieldwork is carried out during three days in a period of three subsequent weeks. 1. One day is used to examine the water quality in the river above the town, organisms, pH, levels of nitrogen and phosphorous, conductivity and turbidity. Then the direction of the water is followed, first up to the infiltration dams on the esker, and then along the esker to the wells in the town. The formation of the esker and other traces in the landscape from the latest glaciation is also studied, as well as the historical use of the esker as a road and as a source of gravel and sand. The tap water that comes from the wells is finally tested in school in the same way as in the river. 2. The second day is used to follow the wastewater from households to the sewage plant, where the staff presents the plant. The water quality is tested in the same way as above in the outlet from the plant to the river. 3. The third day consists of a limnological excursion on the lake outside the mouth of the river where plankton and other organisms are studied, as

  11. Developing Sustainable Spacecraft Water Management Systems

    Science.gov (United States)

    Thomas, Evan A.; Klaus, David M.

    2009-01-01

    It is well recognized that water handling systems used in a spacecraft are prone to failure caused by biofouling and mineral scaling, which can clog mechanical systems and degrade the performance of capillary-based technologies. Long duration spaceflight applications, such as extended stays at a Lunar Outpost or during a Mars transit mission, will increasingly benefit from hardware that is generally more robust and operationally sustainable overtime. This paper presents potential design and testing considerations for improving the reliability of water handling technologies for exploration spacecraft. Our application of interest is to devise a spacecraft wastewater management system wherein fouling can be accommodated by design attributes of the management hardware, rather than implementing some means of preventing its occurrence.

  12. Self-Sustaining Thorium Boiling Water Reactors

    Directory of Open Access Journals (Sweden)

    Ehud Greenspan

    2012-10-01

    Full Text Available A thorium-fueled water-cooled reactor core design approach that features a radially uniform composition of fuel rods in stationary fuel assembly and is fuel-self-sustaining is described. This core design concept is similar to the Reduced moderation Boiling Water Reactor (RBWR proposed by Hitachi to fit within an ABWR pressure vessel, with the following exceptions: use of thorium instead of depleted uranium for the fertile fuel; elimination of the internal blanket; and elimination of absorbers from the axial reflectors, while increasing the length of the fissile zone. The preliminary analysis indicates that it is feasible to design such cores to be fuel-self-sustaining and to have a comfortably low peak linear heat generation rate when operating at the nominal ABWR power level of nearly 4000 MWth. However, the void reactivity feedback tends to be too negative, making it difficult to have sufficient shutdown reactivity margin at cold zero power condition. An addition of a small amount of plutonium from LWR used nuclear fuel was found effective in reducing the magnitude of the negative void reactivity effect and enables attaining adequate shutdown reactivity margin; it also flattens the axial power distribution. The resulting design concept offers an efficient incineration of the LWR generated plutonium in addition to effective utilization of thorium. Additional R&D is required in order to arrive at a reliable practical and safe design.

  13. Perspective: The challenge of ecologically sustainable water management

    CSIR Research Space (South Africa)

    Bernhardt, E

    2006-10-01

    Full Text Available Sustainable water resource management is constrained by three pervasive myths; that societal and environmental water demands always compete with one another; that technological solutions can solve all water resource management problems...

  14. Combustion of liquid fuels floating on water

    Directory of Open Access Journals (Sweden)

    Garo Jean-Pierre

    2007-01-01

    Full Text Available The research presented consists of a study of the burning characteristics of a liquid fuel floating on water with emphasis in the phenomena known as boilover. The problem is of technical interest in the petro-chemical industry, particularly from the point of view of pollution and fires resulting from accidental liquid fuel spills in open water. Testing with multicomponent fuels gives information's about events that can occur in a practical situation, while testing with single component fuels permits obtaining fundamental information about the problem. It evidences the major effects caused by the transfer of heat from the fuel to the water underneath. One of these effects is the disruptive burning of the fuel known as boilover, that is caused by the water boiling and splashing, and results in a sharp increase in burning rate and often in the explosive burning of the fuel. It is shown that this event is caused by the onset of water boiling nucleation at the fuel/water interface and that it occurs at an approximate constant temperature that is above the saturation temperature of the water (water is superheated. These measurements conducted in two laboratories, address the major issues of the process by analyzing the effect of the variation of the parameters of the problem (initial fuel-layer thickness, pool diameter, and fuel type, on the burning rate, time to start of boilover, pre-boilover mass ratio, and boilover intensity. Finally, two types of modeling are proposed to describe the heat transfer in fuel and water phases: one simple for practical purposes, the other, more elaborated and transient, taking particularly into consideration the radiation in depth.

  15. Sustainable River Water Quality Management in Malaysia

    Directory of Open Access Journals (Sweden)

    Abdullah Al-Mamun

    2013-04-01

    Full Text Available Ecological status of Malaysia is not as bad as many other developing nations in the world. However, despite the enforcement of the Environmental Quality Act (EQA in 1974, the water quality of Malaysian inland water (especially rivers is following deteriorating trend. The rivers are mainly polluted due to the point and non-point pollution sources. Point sources are monitored and controlled by the Department of Environment (DOE, whereas a significant amount of pollutants is contributed by untreated sullage and storm runoff. Nevertheless, it is not too late to take some bold steps for the effective control of non-point source pollution and untreated sullage discharge, which play significant roles on the status of the rivers. This paper reviews the existing procedures and guidelines related to protection of the river water quality in Malaysia.  There is a good possibility that the sewage and effluent discharge limits in the Environmental Quality Act (EQA may pose hindrance against achieving good quality water in the rivers as required by the National Water Quality Standards (NWQS. For instance, Ammoniacal Nitrogen (NH3-N is identified as one of the main pollutants to render many of the rivers polluted but it was not considered in the EQA as a monitoring parameter until the new regulations published in 2009.  Surprisingly, the new regulation for sewage and industrial effluent limits set allowable NH3-N concentration quite high (5 mg/L, which may result in low Water Quality Index (WQI values for the river water. The water environment is a dynamic system. Periodical review of the monitoring requirements, detecting emerging pollutants in sewage, effluent and runoff, and proper revision of water quality standards are necessary for the management of sustainable water resources in the country. ABSTRAK: Satus ekologi Malaysia tidak seburuk kebanyakan negara membangun lain di dunia. Walaupun Akta Kualiti Alam Sekitar (EQA dikuatkuasakan pada tahun 1974

  16. Thermodynamics of ice nucleation in liquid water.

    Science.gov (United States)

    Wang, Xin; Wang, Shui; Xu, Qinzhi; Mi, Jianguo

    2015-01-29

    We present a density functional theory approach to investigate the thermodynamics of ice nucleation in supercooled water. Within the theoretical framework, the free-energy functional is constructed by the direct correlation function of oxygen-oxygen of the equilibrium water, and the function is derived from the reference interaction site model in consideration of the interactions of hydrogen-hydrogen, hydrogen-oxygen, and oxygen-oxygen. The equilibrium properties, including vapor-liquid and liquid-solid phase equilibria, local structure of hexagonal ice crystal, and interfacial structure and tension of water-ice are calculated in advance to examine the basis for the theory. The predicted phase equilibria and the water-ice surface tension are in good agreement with the experimental data. In particular, the critical nucleus radius and free-energy barrier during ice nucleation are predicted. The critical radius is similar to the simulation value, suggesting that the current theoretical approach is suitable in describing the thermodynamic properties of ice crystallization.

  17. Autodissociation of a water molecule in liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Geissler, Phillip L.; Dellago, Christoph; Chandler, David; Hutter, Jurg; Parrinello, Michele

    2000-04-01

    The dissociation of a water molecule in liquid water is the fundamental event in acid-base chemistry, determining the pH of water.Because the microscopic dynamics of this autodissociation are difficult to probe, both by experiment and by computer simulation, its mechanism has been unknown. Here we report several autodissociation trajectories generated by ab initio molecular dynamics [1]. These trajectories, which were harvested using transition path sampling [2-4], reveal the mechanism for the first time. Rare fluctuations in solvation energies destabilize an oxygen-hydrogen bond. Through the transfer of one or more protons along a hydrogen bond.

  18. (Liquid + liquid) equilibria of (water + ethanol + dimethyl glutarate) at several temperatures[(Liquid+liquid) equilibria; Ethanol; Dimethyl glutarate; UNIFAC method

    Energy Technology Data Exchange (ETDEWEB)

    Ince, Erol. E-mail: erolince@istanbul.edu.tr; Kirbaslar, S. Ismail. E-mail: krbaslar@istanbul.edu.tr

    2003-10-01

    (Liquid + liquid) equilibrium (LLE) data of (water + ethanol + dimethyl glutarate) have been determined experimentally at T=(298.15,308.15 and 318.15) K. The reliability of the experimental tie-line data was ascertained by using the Othmer and Tobias correlation. The LLE data of the ternary mixture were predicted by UNIFAC method. Distribution coefficients and separation factors were evaluated for the immiscibility region.

  19. Factors affecting sustainability of rural water schemes in Swaziland

    Science.gov (United States)

    Peter, Graciana; Nkambule, Sizwe E.

    The Millennium Development Goal (MDG) target to reduce the proportion of people without sustainable access to safe drinking water by the year 2015 has been met as of 2010, but huge disparities exist. Some regions, particularly Sub-Saharan Africa are lagging behind it is also in this region where up to 30% of the rural schemes are not functional at any given time. There is need for more studies on factors affecting sustainability and necessary measures which when implemented will improve the sustainability of rural water schemes. The main objective of this study was to assess the main factors affecting the sustainability of rural water schemes in Swaziland using a Multi-Criteria Analysis Approach. The main factors considered were: financial, social, technical, environmental and institutional. The study was done in Lubombo region. Fifteen functional water schemes in 11 communities were studied. Data was collected using questionnaires, checklist and focused group discussion guide. A total of 174 heads of households were interviewed. Statistical Package for Social Sciences (SPSS) was used to analyse the data and to calculate sustainability scores for water schemes. SPSS was also used to classify sustainability scores according to sustainability categories: sustainable, partially sustainable and non-sustainable. The averages of the ratings for the different sub-factors studied and the results on the sustainability scores for the sustainable, partially sustainable and non-sustainable schemes were then computed and compared to establish the main factors influencing sustainability of the water schemes. The results indicated technical and social factors as most critical while financial and institutional, although important, played a lesser role. Factors which contributed to the sustainability of water schemes were: functionality; design flow; water fetching time; ability to meet additional demand; use by population; equity; participation in decision making on operation and

  20. Polarized View of Supercooled Liquid Water Clouds

    Science.gov (United States)

    Alexandrov, Mikhail D.; Cairns, Brian; Van Diedenhoven, Bastiaan; Ackerman, Andrew S.; Wasilewski, Andrzej P.; McGill, Matthew J.; Yorks, John E.; Hlavka, Dennis L.; Platnick, Steven E.; Arnold, G. Thomas

    2016-01-01

    Supercooled liquid water (SLW) clouds, where liquid droplets exist at temperatures below 0 C present a well known aviation hazard through aircraft icing, in which SLW accretes on the airframe. SLW clouds are common over the Southern Ocean, and climate-induced changes in their occurrence is thought to constitute a strong cloud feedback on global climate. The two recent NASA field campaigns POlarimeter Definition EXperiment (PODEX, based in Palmdale, California, January-February 2013) and Studies of Emissions and Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC4RS, based in Houston, Texas in August- September 2013) provided a unique opportunity to observe SLW clouds from the high-altitude airborne platform of NASA's ER-2 aircraft. We present an analysis of measurements made by the Research Scanning Polarimeter (RSP) during these experiments accompanied by correlative retrievals from other sensors. The RSP measures both polarized and total reflectance in 9 spectral channels with wavelengths ranging from 410 to 2250 nm. It is a scanning sensor taking samples at 0.8deg intervals within 60deg from nadir in both forward and backward directions. This unique angular resolution allows for characterization of liquid water droplet size using the rainbow structure observed in the polarized reflectances in the scattering angle range between 135deg and 165deg. Simple parametric fitting algorithms applied to the polarized reflectance provide retrievals of the droplet effective radius and variance assuming a prescribed size distribution shape (gamma distribution). In addition to this, we use a non-parametric method, Rainbow Fourier Transform (RFT),which allows retrieval of the droplet size distribution without assuming a size distribution shape. We present an overview of the RSP campaign datasets available from the NASA GISS website, as well as two detailed examples of the retrievals. In these case studies we focus on cloud fields with spatial features

  1. Sustainable development of energy, water and environment systems

    DEFF Research Database (Denmark)

    Duić, Neven; Guzović, Zvonimir; Kafarov, Vyatcheslav

    2013-01-01

    The 6th Dubrovnik Conference on Sustainable Development of Energy, Water and Environment Systems (SDEWES Conference), attended by 418 scientists from 55 countries representing six continents. It was held in 2011 and dedicated to the improvement and dissemination of knowledge on methods, policies...... and technologies for increasing the sustainability of development, taking into account its economic, environmental and social pillars, as well as methods for assessing and measuring sustainability of development, regarding energy, transport, water and environment systems and their many combinations....

  2. Virtual water trade and time scales for loss of water sustainability: a comparative regional analysis.

    Science.gov (United States)

    Goswami, Prashant; Nishad, Shiv Narayan

    2015-03-20

    Assessment and policy design for sustainability in primary resources like arable land and water need to adopt long-term perspective; even small but persistent effects like net export of water may influence sustainability through irreversible losses. With growing consumption, this virtual water trade has become an important element in the water sustainability of a nation. We estimate and contrast the virtual (embedded) water trades of two populous nations, India and China, to present certain quantitative measures and time scales. Estimates show that export of embedded water alone can lead to loss of water sustainability. With the current rate of net export of water (embedded) in the end products, India is poised to lose its entire available water in less than 1000 years; much shorter time scales are implied in terms of water for production. The two cases contrast and exemplify sustainable and non-sustainable virtual water trade in long term perspective.

  3. Sustainability assessment of regional water resources under the DPSIR framework

    Science.gov (United States)

    Sun, Shikun; Wang, Yubao; Liu, Jing; Cai, Huanjie; Wu, Pute; Geng, Qingling; Xu, Lijun

    2016-01-01

    Fresh water is a scarce and critical resource in both natural and socioeconomic systems. Increasing populations combined with an increasing demand for water resources have led to water shortages worldwide. Current water management strategies may not be sustainable, and comprehensive action should be taken to minimize the water budget deficit. Sustainable water resources management is essential because it ensures the integration of social, economic, and environmental issues into all stages of water resources management. This paper establishes the indicators to evaluate the sustainability of water utilization based on the Drive-Pressure-Status-Impact-Response (DPSIR) model. Based on the analytic hierarchy process (AHP) method, a comprehensive assessment of changes to the sustainability of the water resource system in the city of Bayannur was conducted using these indicators. The results indicate that there is an increase in the driving force of local water consumption due to changes in society, economic development, and the consumption structure of residents. The pressure on the water system increased, whereas the status of the water resources continued to decrease over the study period due to the increasing drive indicators. The local government adopted a series of response measures to relieve the decreasing water resources and alleviate the negative effects of the increasing driver in demand. The response measures improved the efficiency of water usage to a large extent, but the large-scale expansion in demands brought a rebounding effect, known as ;Jevons paradox; At the same time, the increasing emissions of industrial and agriculture pollutants brought huge pressures to the regional water resources environment, which caused a decrease in the sustainability of regional water resources. Changing medium and short-term factors, such as regional economic pattern, technological levels, and water utilization practices, can contribute to the sustainable utilization of

  4. Optical Fluorescence Detected from X-ray Irradiated Liquid Water.

    Science.gov (United States)

    Hans, Andreas; Ozga, Christian; Seidel, Robert; Schmidt, Philipp; Ueltzhöffer, Timo; Holzapfel, Xaver; Wenzel, Philip; Reiß, Philipp; Pohl, Marvin N; Unger, Isaak; Aziz, Emad F; Ehresmann, Arno; Slavíček, Petr; Winter, Bernd; Knie, André

    2017-03-16

    Despite its importance, the structure and dynamics of liquid water are still poorly understood in many apsects. Here, we report on the observation of optical fluorescence upon soft X-ray irradiation of liquid water. Detection of spectrally resolved fluorescence was achieved by a combination of the liquid microjet technique and fluorescence spectroscopy. We observe a genuine liquid-phase fluorescence manifested by a broad emission band in the 170-340 nm (4-7 eV) photon wavelength range. In addition, another narrower emission near 300 nm can be assigned to the fluorescence of OH (A state) in the gas phase, the emitting species being formed by Auger electrons escaping from liquid water. We argue that the newly observed broad-band emission of liquid water is relevant in search of extraterrestrial life, and we also envision the observed electron-ejection mechanism to find application for exploring solutes at liquid-vapor interfaces.

  5. Assessment of the sustainability of a water resource system expansion

    DEFF Research Database (Denmark)

    Kjeldsen, Thomas Rødding; Rosbjerg, Dan

    2001-01-01

    for the water resources system, comprising all important water users within the catchment. Measures to meet the growing water demand in the catchment are discussed. Six scenarios including both supply and demand oriented solutions are identified, modelled and compared in tenus of the sustainability criteria....... Based on initial experience the method was modified leading to more credible results. A problem with assessing sustainability using risk criteria is a favouring of supply-oriented solutions, in particular when aspects not directly related to demand and availability of water are excluded.......A sustainability assessment method involving risk criteria related to reliability, resilience and vulnerability, has been applied to quantify the relative sustainability of possible expansions of a water resources system in the KwaZulu-Natal province South Africa. A river basin model has been setup...

  6. Pump Management Committees and sustainable community water ...

    African Journals Online (AJOL)

    PMCs), technically known as Water and Sanitation Committees (WATSAN) in the water sector, are institutionalized organs for community water management. A survey of twenty-seven (27) of these institutions in six districts across the Upper ...

  7. Liquid-liquid equilibria of fuel oxygenate + water + hydrocarbon mixtures. 3: Effect of temperature

    Energy Technology Data Exchange (ETDEWEB)

    Wagner, G. [Universitaet Karlsruhe (Germany). Institut fuer Thermische Verfahrenstechnik; Sandler, S.I. [Univ. of Delaware, Newark, DE (United States). Center for Molecular and Engineering Thermodynamics

    1995-09-01

    The authors have measured the ternary liquid-liquid equilibria of water + ethanol mixtures with, separately, 2,2,4-trimethylpentane and toluene at 5 and 40 C, water + tert-amyl alcohol (TAOH) mixtures with, separately, toluene and hexane at 5 and 40 C, and of water + TAOH + pentane mixtures at 5 C. The ethanol-containing systems exhibit type 1 liquid-liquid phase behavior, and the TAOH-containing systems exhibit type 2 behavior. These data, together with the data they have previously reported at 25 C, provide information on how the liquid-liquid equilibria of these systems change as a function of temperature. While the addition of ethanol is found to increase the solubility of hydrocarbons in the aqueous phase, the concentration of the hydrocarbon in the water-rich phase decreases with increasing temperature. With the exception of hydrocarbon in the water-rich phase, the experimental data could be correlated quite well with either the UNIQUAC or NRTL models. For most of the systems considered here the predictions of the phase behavior with the liquid-liquid UNIFAC group-contribution model are only qualitatively correct. However, the liquid-liquid UNIFAC model erroneously predicts type 2 phase behavior to occur for water + ethanol + 2,2,4-trimethylpentane system at 5 C.

  8. Interactions between water and 1-butyl-1-methylpyrrolidinium ionic liquids.

    Science.gov (United States)

    Fadeeva, Tatiana A; Husson, Pascale; DeVine, Jessalyn A; Costa Gomes, Margarida F; Greenbaum, Steven G; Castner, Edward W

    2015-08-14

    We report experimental results on the diffusivity of water in two ionic liquids obtained using the pulsed-gradient spin-echo NMR method. Both ionic liquids have the same cation, 1-butyl-1-methylpyrrolidinium, but different trifluoromethyl-containing anions. One has a strongly hydrophobic anion, bis(trifluoromethylsulfonyl)amide, while the second has a hydrophilic anion, trifluoromethylsulfonate. Transport of water in these ionic liquids is much faster than would be predicted from hydrodynamic laws, indicating that the neutral water molecules experience a very different friction than the anions and cations at the molecular level. Temperature-dependent viscosities, conductivities, and densities are reported as a function of water concentration to further analyze the properties of the ionic liquid-water mixtures. These results on the properties of water in ionic liquids should be of interest to researchers in diverse areas ranging from separations, solubilizing biomass and energy technologies.

  9. Light Water Reactor Sustainability Accomplishments Report

    Energy Technology Data Exchange (ETDEWEB)

    McCarthy, Kathryn A. [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-02-01

    Welcome to the 2014 Light Water Reactor Sustainability (LWRS) Program Accomplishments Report, covering research and development highlights from 2014. The LWRS Program is a U.S. Department of Energy research and development program to inform and support the long-term operation of our nation’s commercial nuclear power plants. The research uses the unique facilities and capabilities at the Department of Energy national laboratories in collaboration with industry, academia, and international partners. Extending the operating lifetimes of current plants is essential to supporting our nation’s base load energy infrastructure, as well as reaching the Administration’s goal of reducing greenhouse gas emissions to 80% below 1990 levels by the year 2050. The purpose of the LWRS Program is to provide technical results for plant owners to make informed decisions on long-term operation and subsequent license renewal, reducing the uncertainty, and therefore the risk, associated with those decisions. In January 2013, 104 nuclear power plants operated in 31 states. However, since then, five plants have been shut down (several due to economic reasons), with additional shutdowns under consideration. The LWRS Program aims to minimize the number of plants that are shut down, with R&D that supports long-term operation both directly (via data that is needed for subsequent license renewal), as well indirectly (with models and technology that provide economic benefits). The LWRS Program continues to work closely with the Electric Power Research Institute (EPRI) to ensure that the body of information needed to support SLR decisions and actions is available in a timely manner. This report covers selected highlights from the three research pathways in the LWRS Program: Materials Aging and Degradation, Risk-Informed Safety Margin Characterization, and Advanced Instrumentation, Information, and Control Systems Technologies, as well as a look-ahead at planned activities for 2015. If you

  10. Water quality objectives as a management tool for sustainability

    OpenAIRE

    Everard, Mark

    1994-01-01

    The aim of this paper is to explore the potential role that quality objectives, particularly when backed by statutory force, may play in the sustainable management of river water quality. Economic valuation techniques are discussed, as well as the theory of "critical natural capital". A brief history of water quality legislation includes the implementation of the National Water Council classification in 1979, and the statutory water quality objectives introduced under the Water Resources Act ...

  11. Measuring global water security towards sustainable development goals

    NARCIS (Netherlands)

    Wada, Y.; Gain, A.K.; Giupponi, C.

    2016-01-01

    Water plays an important role in underpinning equitable, stable and productive societies and ecosystems. Hence, United Nations recognized ensuring water security as one (Goal 6) of the seventeen sustainable development goals(SDGs). Many international river basins are likely to experience ‘low water

  12. Anticipating change : sustainable water policy pathways for an uncertain future

    NARCIS (Netherlands)

    Haasnoot, Marjolijn

    2013-01-01

    Water management should preferably bring solutions that sustain even if conditions change. In anticipating change, a sustainable plan should not only achieve economic, environmental, and social targets, but it should also be robust to uncertainty and able to be adapted over time to (unforeseen)

  13. Sustainable development indicators for urban water systems: a case ...

    African Journals Online (AJOL)

    In the light of the increasing pressures on the world's freshwater resources, changes in the present and future urban water systems are called for in order to achieve sustainable development. The transformation from unsustainable practices demands tools that measure progress and can warn of future trends. Sustainable ...

  14. Refresher Course on Geomatic Applications for Sustainable Water ...

    Indian Academy of Sciences (India)

    Home; Journals; Resonance – Journal of Science Education; Volume 14; Issue 6. Refresher Course on Geomatic Applications for Sustainable Water Resources and Environment. Information and Announcements Volume 14 Issue 6 June 2009 pp 630-630 ...

  15. Sustainable Water Management & Satellite Remote Sensing

    Science.gov (United States)

    Eutrophication assessment frameworks such as the Australian National Water Quality Management Strategy, Oslo Paris (OSPAR) Commission Common Procedure, Water Framework Directive (WFD) of the European Union, Marine Strategy Framework Directive (MSFD) from the European Commission, ...

  16. Sustainability of Ancient Water Supply Facilities in Jerusalem

    Directory of Open Access Journals (Sweden)

    Jamal M. Barghouth

    2009-11-01

    Full Text Available This paper presents an overview on the sustainability of ancient water supply systems in Jerusalem from the Chalcolithic period (4500–3200 B.C. until the present time. Archaeological evidences and landscape settings were applied utilizing all available and accessible literature relevant to ancient water resources management in Jerusalem. Irrigated agriculture was practiced for many centuries in this region, hence sustainable water supply facilities were erected, including well developed aqueducts, water harvesting pools and irrigation channels for water storage and landscaping purposes. To cope with seismic events, soil subsidence and water leakage, ancient water engineers and architects applied innovative construction methods for the erection of water pools, channels and aqueduct systems. Ancient water supply systems in Jerusalem are valuable treasures of past civilizations and crucial urban environmental facilities and their protection is consistent with sustainable development principles. Effective environmental assessment as a decision-making process for sustainable development can be applied to preserve threatened ancient water facilities from major development proposals and urban infrastructure projects in Jerusalem.

  17. Indirect Potable Reuse: A Sustainable Water Supply Alternative

    OpenAIRE

    Rodriguez, Clemencia; Van Buynder, Paul; Lugg, Richard; Blair, Palenque; Devine, Brian; Cook, Angus; Weinstein, Philip

    2009-01-01

    The growing scarcity of potable water supplies is among the most important issues facing many cities, in particular those using single sources of water that are climate dependent. Consequently, urban centers are looking to alternative sources of water supply that can supplement variable rainfall and meet the demands of population growth. A diversified portfolio of water sources is required to ensure public health, as well as social, economical and environmental sustainability. One of the opti...

  18. Sustainable water resources management of Prokletije region

    Directory of Open Access Journals (Sweden)

    Svetlana M Stevovic

    2014-04-01

    Full Text Available The main goal of this paper is the upgrading of classic economic analyses of optimal concept selection of small hydro development. Techno-economic small hydro system needs to be environmentally friendly and socially acceptable solution. Environmental and social parameters are quantified by Delphi method. They are results of Environmental and Social impact assessment study of the project. Environmental and social parameters are incorporated in the techno-economic analyses for the optimal sustainable concept of small hydro development, by Elektra method, as possible multi attributive operational research model. System of small hydro power plants optimization for Prokletije streams catchments area is case study where the developed model is tested and proofed. Economic cost and total investment of fifteen possible small hydro power plants has been upgraded with quantified environmental and social parameters and analyzed in the function of sustainable economic development of Prokletije region.

  19. Environmental sustainability of waste water ozonation

    DEFF Research Database (Denmark)

    Larsen, Henrik Fred; Hansen, Peter Augusto

    The EU FP6 NEPTUNE project is related to the EU Water Framework Directive and the main goal is to develop new and optimize existing waste water treatment technologies (WWTT) and sludge handling methods for municipal waste water. Besides nutrients, a special focus area is micropollutants (e...... and whole effluent toxicity have been developed. About 15 different waste water and sludge treatment technologies (or combinations) have been assessed. This paper will present the LCA results from running the induced versus avoided impact approach on one of the WWTTs, i.e. ozonation....

  20. Environmental sustainability of ozonating municipal waste water

    DEFF Research Database (Denmark)

    Larsen, Henrik Fred; Hansen, Peter Augusto

    The EU FP6 NEPTUNE project is related to the EU Water Framework Directive and the main goal is to develop new and optimize existing waste water treatment technologies (WWTT) and sludge handling methods for municipal waste water. Besides nutrients, a special focus area is micropollutants (e....... In total more that 20 different waste water and sludge treatment technologies are to be assessed. This paper will present the preliminary LCA results from running the induced versus avoided impact approach (mainly based on existing LCIA methodology) on one of the WWTTs, i.e. ozonation....

  1. A pathway to a more sustainable water sector: sustainability-based asset management.

    Science.gov (United States)

    Marlow, D R; Beale, D J; Burn, S

    2010-01-01

    The water sectors of many countries are faced with the need to address simultaneously two overarching challenges; the need to undertake effective asset management coupled with the broader need to evolve business processes so as to embrace sustainability principles. Research has thus been undertaken into the role sustainability principles play in asset management. As part of this research, a series of 25 in-depth interviews were undertaken with water sector professionals from around Australia. Drawing on the results of these interviews, this paper outlines the conceptual relationship between asset management and sustainability along with a synthesis of the relevant opinions voiced in the interviews. The interviews indicated that the participating water authorities have made a strong commitment to sustainability, but there is a need to facilitate change processes to embed sustainability principles into business as usual practices. Interviewees also noted that asset management and sustainability are interlinked from a number of perspectives, especially in the way decision making is undertaken with respect to assets and service provision. The interviews also provided insights into the research needed to develop a holistic sustainability-based asset management framework.

  2. Water retention in mushroom during sustainable processing

    NARCIS (Netherlands)

    Paudel, E.

    2015-01-01

    This thesis deals with the understanding of the water holding capacity of mushroom, in the context of a redesign of their industrial processing. For designing food process the retention of food quality is of the utmost importance. Water holding capacity is an important quality aspect of mushrooms. A

  3. Preliminary experimental study of liquid lithium water interaction

    Energy Technology Data Exchange (ETDEWEB)

    You, X.M.; Tong, L.L.; Cao, X.W., E-mail: caoxuewu@sjtu.edu.cn

    2015-10-15

    Highlights: • Explosive reaction occurs when lithium temperature is over 300 °C. • The violence of liquid lithium water interaction increases with the initial temperature of liquid lithium. • The interaction is suppressed when the initial water temperature is above 70 °C. • Steam explosion is not ignorable in the risk assessment of liquid lithium water interaction. • Explosion strength of liquid lithium water interaction is evaluated by explosive yield. - Abstract: Liquid lithium is the best candidate for a material with low Z and low activation, and is one of the important choices for plasma facing materials in magnetic fusion devices. However, liquid lithium reacts violently with water under the conditions of loss of coolant accidents. The release of large heats and hydrogen could result in the dramatic increase of temperature and pressure. The lithium–water explosion has large effect on the safety of fusion devices, which is an important content for the safety assessment of fusion devices. As a preliminary investigation of liquid lithium water interaction, the test facility has been built and experiments have been conducted under different conditions. The initial temperature of lithium droplet ranged from 200 °C to 600 °C and water temperature was varied between 20 °C and 90 °C. Lithium droplets were released into the test section with excess water. The shape of lithium droplet and steam generated around the lithium were observed by the high speed camera. At the same time, the pressure and temperature in the test section were recorded during the violent interactions. The preliminary experimental results indicate that the initial temperature of lithium and water has an effect on the violence of liquid lithium water interaction.

  4. Materials and membrane technologies for water and energy sustainability

    KAUST Repository

    Le, Ngoc Lieu

    2016-03-10

    Water and energy have always been crucial for the world’s social and economic growth. Their supply and use must be sustainable. This review discusses opportunities for membrane technologies in water and energy sustainbility by analyzing their potential applications and current status; providing emerging technologies and scrutinizing research and development challenges for membrane materials in this field.

  5. Assessing urban water sustainability in South Africa – not just ...

    African Journals Online (AJOL)

    New solutions for improving the sustainability of cities need to be found, including the development of tools to guide decision-makers. Several benchmarking initiatives have been implemented in the SA water sector – mostly in terms of performance measurement of specific water services for regulatory purposes – but none ...

  6. Assessing urban water sustainability in South Africa – not just ...

    African Journals Online (AJOL)

    Assessing urban water sustainability in South Africa. – not just performance measurement. K Carden* and NP Armitage. Department of Civil Engineering, University of Cape Town, Private Bag X3, Rondebosch 7700, South Africa. ABSTRACT. Urban water management – and the impacts that rapid population growth, ...

  7. Sustainability of water resources development in the Komadugu ...

    African Journals Online (AJOL)

    Sustainability of water resources development in the Komadugu Yobe River basin of Nigeria. ... Journal of Applied Science, Engineering and Technology ... Results show that about 2,619 million cubic meters (MCM) of surface water is available annually upstream of Wudil (HS 1), 658 MCM is available between Wudil and ...

  8. pump management committees and sustainable community water ...

    African Journals Online (AJOL)

    policy reforms after series of experiments by the World Bank, CIDA. 7Lecturer in ... most relevant of these are the Water Resources Commission (WRC,. Act 522 of ..... logbook and spare parts purchase book; Considering specific records. 85 ...

  9. Sustained adoption of water, sanitation and hygiene interventions: systematic review.

    Science.gov (United States)

    Martin, Nina A; Hulland, Kristyna R S; Dreibelbis, Robert; Sultana, Farhana; Winch, Peter J

    2018-02-01

    To understand factors that influence sustained adoption of water, sanitation and hygiene (WASH) technologies or behaviours. Systematic review of the current literature. Articles were gathered from databases of peer-reviewed articles and grey literature, and screened for relevance. After exclusion, we created a descriptive map of 148 articles and analysed in-depth 44 articles that had an explicit focus on promoting or evaluating sustained adoption or programme sustainability. Twenty-two of these articles met our definition of measuring sustained adoption. Definitions of sustained adoption varied widely and were often inadequate, making comparison of sustained adoption across studies difficult. The time frame for measurements of sustained adoption is frequently inadequate for examination of longer-term behaviour change. Ideally, an evaluation should specify the project period and describe the context surrounding adoption, make measurements at multiple time points, diversify measurement methods and describe and measure a range of factors affecting sustained adoption. Additional consideration needs to be given to developing behaviour change models that emphasise factors related to sustained adoption, and how they differ from those related to initial adoption. © 2017 John Wiley & Sons Ltd.

  10. Water retention in mushroom during sustainable processing

    OpenAIRE

    Paudel, E.

    2015-01-01

    This thesis deals with the understanding of the water holding capacity of mushroom, in the context of a redesign of their industrial processing. For designing food process the retention of food quality is of the utmost importance. Water holding capacity is an important quality aspect of mushrooms. A convenient process design methodology which accounts also for product quality is Conceptual Process Design (CPD). An approach to follow CPD methodology is first to explore, the material properties...

  11. Water footprints of cities - indicators for sustainable consumption and production

    Science.gov (United States)

    Hoff, H.; Döll, P.; Fader, M.; Gerten, D.; Hauser, S.; Siebert, S.

    2014-01-01

    Water footprints have been proposed as sustainability indicators, relating the consumption of goods like food to the amount of water necessary for their production and the impacts of that water use in the source regions. We further developed the existing water footprint methodology, by globally resolving virtual water flows from production to consumption regions for major food crops at 5 arcmin spatial resolution. We distinguished domestic and international flows, and assessed local impacts of export production. Applying this method to three exemplary cities, Berlin, Delhi and Lagos, we find major differences in amounts, composition, and origin of green and blue virtual water imports, due to differences in diets, trade integration and crop water productivities in the source regions. While almost all of Delhi's and Lagos' virtual water imports are of domestic origin, Berlin on average imports from more than 4000 km distance, in particular soy (livestock feed), coffee and cocoa. While 42% of Delhi's virtual water imports are blue water based, the fractions for Berlin and Lagos are 2 and 0.5%, respectively, roughly equal to the water volumes abstracted in these two cities for domestic water use. Some of the external source regions of Berlin's virtual water imports appear to be critically water scarce and/or food insecure. However, for deriving recommendations on sustainable consumption and trade, further analysis of context-specific costs and benefits associated with export production will be required.

  12. Towards Sustainable Water Management in a Country that Faces Extreme Water Scarcity and Dependency: Jordan

    Science.gov (United States)

    Schyns, J.; Hamaideh, A.; Hoekstra, A. Y.; Mekonnen, M. M.; Schyns, M.

    2015-12-01

    Jordan faces a great variety of water-related challenges: domestic water resources are scarce and polluted; the sharing of transboundary waters has led to tensions and conflicts; and Jordan is extremely dependent of foreign water resources through trade. Therefore, sustainable water management in Jordan is a challenging task, which has not yet been accomplished. The objective of this study was to analyse Jordan's domestic water scarcity and pollution and the country's external water dependency, and subsequently review sustainable solutions that reduce the risk of extreme water scarcity and dependency. We have estimated the green, blue and grey water footprint of five different sectors in Jordan: crop production, grazing, animal water supply, industrial production and domestic water supply. Next, we assessed the blue water scarcity ratio for the sum of surface- and groundwater and for groundwater separately, and calculated the water pollution level. Finally, we reviewed the sustainability of proposed solutions to Jordan's domestic water problems and external water dependency in literature, while involving the results and conclusions from our analysis. We have quantified that: even while taking into account the return flows, blue water scarcity in Jordan is severe; groundwater consumption is nearly double the sustainable yield; water pollution aggravates blue water scarcity; and Jordan's external virtual water dependency is 86%. Our review yields ten essential ingredients that a sustainable water management strategy for Jordan, that reduces the risk of extreme water scarcity and dependency, should involve. With respect to these, Jordan's current water policy requires a strong redirection towards water demand management. Especially, more attention should be paid to reducing water demand by changing the consumption patterns of Jordan consumers. Moreover, exploitation of fossil groundwater should soon be halted and planned desalination projects require careful

  13. High frequency, realtime measurements of stable isotopes in liquid water

    Science.gov (United States)

    Weiler, M.; Herbstritt, B.; Gralher, B.

    2012-04-01

    We developed a method to measure in-situ the isotopic composition of liquid water with minimal supervision and, most important, with a temporal resolution of less than a minute. For this purpose a off-the-shelf microporous hydrophobic membrane contactor for under 200€ was combined with an isotope laser spectrometer (Picarro). The contactor, originally designed for degassing liquids, was used with nitrogen as carrier gas in order to transform a small fraction of liquid water to water vapor. The generated water vapor was then analyzed continuously by the isotope laser spectrometer. To prove the membrane's applicability we determined the specific isotope fractionation factor for the phase change through the contactor's membrane for a common temperature range and with different waters of known isotopic compositions. This fractionation factor is then used to derive the liquid water isotope ratio from the measured water vapor isotope ratios and the measured temperature at the phase change. The system was compared for breakthrough curves of isotopically enriched water and the isotope values corresponded very well with those of liquid water samples taken simultaneously and analyzed with a conventional method (CRDS). The introduced method supersedes taking liquid samples and employs only relative cheap and readily available components. This makes it a relatively inexpensive, fast, user-friendly and easily reproducible method. It can be applied in both the field and laboratory wherever a water vapor isotope analyzer can be run and whenever real-time isotope data of liquid water are required at high temporal resolution with the same accuracy as collecting individual water samples.

  14. Sustainable Water Management in Urban, Agricultural, and Natural Systems

    Directory of Open Access Journals (Sweden)

    Tess Russo

    2014-12-01

    Full Text Available Sustainable water management (SWM requires allocating between competing water sector demands, and balancing the financial and social resources required to support necessary water systems. The objective of this review is to assess SWM in three sectors: urban, agricultural, and natural systems. This review explores the following questions: (1 How is SWM defined and evaluated? (2 What are the challenges associated with sustainable development in each sector? (3 What are the areas of greatest potential improvement in urban and agricultural water management systems? And (4 What role does country development status have in SWM practices? The methods for evaluating water management practices range from relatively simple indicator methods to integration of multiple models, depending on the complexity of the problem and resources of the investigators. The two key findings and recommendations for meeting SWM objectives are: (1 all forms of water must be considered usable, and reusable, water resources; and (2 increasing agricultural crop water production represents the largest opportunity for reducing total water consumption, and will be required to meet global food security needs. The level of regional development should not dictate sustainability objectives, however local infrastructure conditions and financial capabilities should inform the details of water system design and evaluation.

  15. Applying Telecoupling Framework for Urban Water Sustainability Research and Management

    Science.gov (United States)

    Yang, W.; Hyndman, D. W.; Winkler, J. A.; Viña, A.; Deines, J.; Lupi, F.; Luo, L.; Li, Y.; Basso, B.; Zheng, C.; Ma, D.; Li, S.; Liu, X.; Zheng, H.; Cao, G.; Meng, Q.; Ouyang, Z.; Liu, J.

    2016-12-01

    Urban areas, especially megacities (those with populations greater than 10 million), are hotspots of global water use and thus face intense water management challenges. Urban areas are influenced by local interactions between human and natural systems and also interact with distant systems through flows of water, food, energy, people, information, and capital. However, analyses of water sustainability and the management of water flows in urban areas are often fragmented. There is a strong need for applying integrated frameworks to systematically analyze urban water dynamics and factors influencing these dynamics. Here, we apply the framework of telecoupling (socioeconomic and environmental interactions over distances) to analyze urban water issues, using Beijing as a demonstration city. Beijing exemplifies the global water sustainability challenge for urban settings. Like many other cities, Beijing has experienced drastic reductions in quantity and quality of both surface water and groundwater over the past several decades; it relies on the import of real and virtual water from sending systems to meet its demand for clean water, and releases polluted water to other systems (spillover systems). The integrated framework presented here demonstrates the importance of considering socioeconomic and environmental interactions across telecoupled human and natural systems, which include not only Beijing (the water receiving system), but also water sending systems and spillover systems. This framework helps integrate important components of local and distant human-nature interactions and incorporates a wide range of local couplings and telecouplings that affect water dynamics, which in turn generate significant socioeconomic and environmental consequences including feedback effects. The application of the framework to Beijing reveals many research gaps and management needs. This study also provides a foundation to apply the telecoupling framework to better understand and

  16. Managed Aquifer Recharge (MAR in Sustainable Urban Water Management

    Directory of Open Access Journals (Sweden)

    Declan Page

    2018-02-01

    Full Text Available To meet increasing urban water requirements in a sustainable way, there is a need to diversify future sources of supply and storage. However, to date, there has been a lag in the uptake of managed aquifer recharge (MAR for diversifying water sources in urban areas. This study draws on examples of the use of MAR as an approach to support sustainable urban water management. Recharged water may be sourced from a variety of sources and in urban centers, MAR provides a means to recycle underutilized urban storm water and treated wastewater to maximize their water resource potential and to minimize any detrimental effects associated with their disposal. The number, diversity and scale of urban MAR projects is growing internationally due to water shortages, fewer available dam sites, high evaporative losses from surface storages, and lower costs compared with alternatives where the conditions are favorable, including water treatment. Water quality improvements during aquifer storage are increasingly being documented at demonstration sites and more recently, full-scale operational urban schemes. This growing body of knowledge allows more confidence in understanding the potential role of aquifers in water treatment for regulators. In urban areas, confined aquifers provide better protection for waters recharged via wells to supplement potable water supplies. However, unconfined aquifers may generally be used for nonpotable purposes to substitute for municipal water supplies and, in some cases, provide adequate protection for recovery as potable water. The barriers to MAR adoption as part of sustainable urban water management include lack of awareness of recent developments and a lack of transparency in costs, but most importantly the often fragmented nature of urban water resources and environmental management.

  17. Isobaric vapor-liquid equilibria of water + ethanol + hexyl acetate

    Energy Technology Data Exchange (ETDEWEB)

    Arce, A.; Soto, A. [Univ. of Santiago de Compostela (Spain). Chemical Engineering Dept.; Orge, B.; Tojo, J. [Univ. of Vigo (Spain). Chemical Engineering Dept.

    1995-09-01

    The authors determined the isobaric vapor-liquid equilibrium data for the ternary system water + ethanol + hexyl acetate at 101.325 kPa using a distillation apparatus recycling both liquid and vapor phases. The results were compared with those predicted using group contribution methods. The UNIFAC method gave the best predictions.

  18. Water footprints of cities - indicators for sustainable consumption and production

    Science.gov (United States)

    Hoff, H.; Döll, P.; Fader, M.; Gerten, D.; Hauser, S.; Siebert, S.

    2013-02-01

    Water footprints have been proposed as sustainability indicators, relating the consumption of goods like food to the amount of water necessary for their production and the impacts of that water use in the source regions. We have further developed the existing water footprint methodology by globally resolving virtual water flows and import and source regions at 5 arc minutes spatial resolution, and by assessing local impacts of export production. Applying this method to three exemplary cities, Berlin, Delhi and Lagos, we find major differences in amounts, composition, and origin of green and blue virtual water imports, due to differences in diets, trade integration and crop water productivities in the source regions. While almost all of Delhi's and Lagos' virtual water imports are of domestic origin, Berlin on average imports from more than 4000 km distance, in particular soy (livestock feed), coffee and cocoa. While 42% of Delhi's virtual water imports are blue water based, the fractions for Berlin and Lagos are 2% and 0.5%, respectively, roughly equal to local drinking water abstractions of these cities. Some of the external source regions of Berlin's virtual water imports appear to be critically water scarce and/or food insecure. However for deriving recommendations on sustainable consumption and trade, further analysis of context-specific costs and benefits associated with export production will be required.

  19. Sustainability Assessment of indicators for integrated water resources management.

    Science.gov (United States)

    Pires, A; Morato, J; Peixoto, H; Botero, V; Zuluaga, L; Figueroa, A

    2017-02-01

    The scientific community strongly recommends the adoption of indicators for the evaluation and monitoring of progress towards sustainable development. Furthermore, international organizations consider that indicators are powerful decision-making tools. Nevertheless, the quality and reliability of the indicators depends on the application of adequate and appropriate criteria to assess them. The general objective of this study was to evaluate how indicators related to water use and management perform against a set of sustainability criteria. Our research identified 170 indicators related to water use and management. These indicators were assessed by an international panel of experts that evaluated whether they fulfil the four sustainability criteria: social, economic, environmental, and institutional. We employed an evaluation matrix that classified all indicators according to the DPSIR (Driving Forces, Pressures, States, Impacts and Responses) framework. A pilot study served to test and approve the research methodology before carrying out the full implementation. The findings of the study show that 24 indicators comply with the majority of the sustainability criteria; 59 indicators are bi-dimensional (meaning that they comply with two sustainability criteria); 86 are one-dimensional indicators (fulfilling just one of the four sustainability criteria) and one indicator do not fulfil any of the sustainability criteria. Copyright © 2016. Published by Elsevier B.V.

  20. Liquid water in the domain of cubic crystalline ice Ic

    Science.gov (United States)

    Jenniskens, P.; Banham, S. F.; Blake, D. F.; McCoustra, M. R.

    1997-01-01

    Vapor-deposited amorphous water ice when warmed above the glass transition temperature (120-140 K), is a viscous liquid which exhibits a viscosity vs temperature relationship different from that of liquid water at room temperature. New studies of thin water ice films now demonstrate that viscous liquid water persists in the temperature range 140-210 K. where it coexists with cubic crystalline ice. The liquid character of amorphous water above the glass transition is demonstrated by (1) changes in the morphology of water ice films on a nonwetting surface observed in transmission electron microscopy (TEM) at around 175 K during slow warming, (2) changes in the binding energy of water molecules measured in temperature programmed desorption (TPD) studies, and (3) changes in the shape of the 3.07 micrometers absorption band observed in grazing angle reflection-absorption infrared spectroscopy (RAIRS) during annealing at high temperature. whereby the decreased roughness of the water surface is thought to cause changes in the selection rules for the excitation of O-H stretch vibrations. Because it is present over such a wide range of temperatures, we propose that this form of liquid water is a common material in nature. where it is expected to exist in the subsurface layers of comets and on the surfaces of some planets and satellites.

  1. Sustainability of water, sanitation and hygiene interventions in Central America.

    Science.gov (United States)

    Sabogal, Raquel I; Medlin, Elizabeth; Aquino, Gonzalo; Gelting, Richard J

    The American Red Cross and U.S. Centers for Disease Control and Prevention collaborated on a sustainability evaluation of post-hurricane water, sanitation and hygiene (WASH) interventions in Central America. In 2006 and 2009, we revisited six study areas in rural El Salvador, Guatemala, Honduras and Nicaragua to assess sustainability of WASH interventions finalized in 2002, after 1998's Hurricane Mitch. We used surveys to collect data, calculate indicators and identify factors that influence sustainability. Regional sustainability indicator results showed there was a statistically significant decline in access to water. The presence of sanitation facilities had not changed since the beginning of the project; however, maintenance and use of latrines declined but continued to meet the goal of 75% use after 7 years. The hygiene indicator, hand washing, initially declined and then increased. Declines in water access were due to operational problems related to storm events and population changes. Sanitation facilities were still present and sometimes used even though they reached or surpassed their original design life. Changes in hygiene practices appeared related to ongoing hygiene promotion from outside organizations. These results provide useful input for making WASH programs more sustainable and informing future, more in-depth research into factors influencing sustainability.

  2. Sustainability of water, sanitation and hygiene interventions in Central America

    Science.gov (United States)

    Medlin, Elizabeth; Aquino, Gonzalo; Gelting, Richard J.

    2015-01-01

    The American Red Cross and U.S. Centers for Disease Control and Prevention collaborated on a sustainability evaluation of post-hurricane water, sanitation and hygiene (WASH) interventions in Central America. In 2006 and 2009, we revisited six study areas in rural El Salvador, Guatemala, Honduras and Nicaragua to assess sustainability of WASH interventions finalized in 2002, after 1998’s Hurricane Mitch. We used surveys to collect data, calculate indicators and identify factors that influence sustainability. Regional sustainability indicator results showed there was a statistically significant decline in access to water. The presence of sanitation facilities had not changed since the beginning of the project; however, maintenance and use of latrines declined but continued to meet the goal of 75% use after 7 years. The hygiene indicator, hand washing, initially declined and then increased. Declines in water access were due to operational problems related to storm events and population changes. Sanitation facilities were still present and sometimes used even though they reached or surpassed their original design life. Changes in hygiene practices appeared related to ongoing hygiene promotion from outside organizations. These results provide useful input for making WASH programs more sustainable and informing future, more in-depth research into factors influencing sustainability. PMID:26413262

  3. Droplet-Sizing Liquid Water Content Sensor Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Icing is one of the most significant hazards to aircraft. A sizing supercooled liquid water content (SSLWC) sonde is being developed to meet a directly related need...

  4. Excited state dynamics of liquid water near the surface

    Directory of Open Access Journals (Sweden)

    Schultz Thomas

    2013-03-01

    Full Text Available Time resolved photoelectron spectroscopy explores the excited state dynamics of liquid water in presence of cations close to the surface. A transient hydrated electroncation complex is observed.

  5. Management strategies for sustainable western water

    Science.gov (United States)

    Scott Tyler; Sudeep Chandra; Gordon Grant

    2017-01-01

    With the effects of the dramatic western US drought still reverberating through the landscape, researchers gathered in advance of the 20th annual Lake Tahoe Summit to discuss western US water issues in the 21st century. This two-day workshop brought together ~40 researchers from universities and agencies (federal and state) to discuss the prospects that...

  6. Sustainability standards and the water question

    NARCIS (Netherlands)

    Vos, J.; Boelens, R.

    2014-01-01

    Increased global trade in agricultural commodities has boosted fresh water consumption. This export of ‘virtual water’, embedded in products sold abroad, has increasingly affected local communities and ecosystems, especially in arid regions. Recent initiatives to certify agricultural production are

  7. Sustainability Standards and the Water Question

    NARCIS (Netherlands)

    Vos, J.M.C.; Boelens, R.A.

    2014-01-01

    Increased global trade in agricultural commodities has boosted fresh water consumption. This export of ‘virtual water’, embedded in products sold abroad, has increasingly affected local communities and ecosystems, especially in arid regions. Recent initiatives to certify agricultural production are

  8. The Sparta Aquifer: A Sustainable Water Resource?

    Science.gov (United States)

    McKee, Paul W.; Hays, Phillip D.

    2002-01-01

    Introduction The Sparta aquifer is an aquifer of regional importance within the Mississippi embayment aquifer system. It consists of varying amounts of unconsolidated sand, inter-stratified with silt and clay lenses within the Sparta Sand of the Claiborne Group. It extends from south Texas, north into Louisiana, Arkansas, and Tennessee, and eastward into Mississippi and Alabama (fig. 1). On both the west and east sides of the Mississippi embayment, the Sparta aquifer is exposed at the surface (outcrops) and is locally unconfined; it becomes confined as it dips toward the axis of the embayment, (generally corresponding with the Mississippi River) and southward toward the Gulf of Mexico where it is deeply buried in the subsurface (Hosman, 1968). Generalized ground-water flow in the Sparta aquifer is from the outcrop areas to the axis (center) of the embayment (fig. 2). In Arkansas, the Sparta aquifer outcrops parallel to the Fall Line at the western extreme of the Mississippi embayment (the Fall Line is a line dividing the mountainous highlands of Arkansas from the lowland area); and the formation dips from its outcrop area to the southeast. The Sparta aquifer supplies water for municipalities, industries such as paper production, and to a lesser degree, irrigation of agricultural crops (fig. 3). This report highlights hydrologic conditions of the aquifer in Arkansas County as an example of how water use is affecting water levels.

  9. pump management committees and sustainable community water ...

    African Journals Online (AJOL)

    District Assemblies inculcate the culture of participatory decision-making, revenue mobilisation and saving as well as records ... (CWSA) to facilitate access of potable water and hygienic latrine facilities to the rural sector. .... among its membership normally comprising caretakers, hygiene and sanitation person, secretary ...

  10. Continuous in situ measurements of stable isotopes in liquid water

    Science.gov (United States)

    Herbstritt, Barbara; Gralher, Benjamin; Weiler, Markus

    2012-03-01

    We developed a method to measure in situ the isotopic composition of liquid water with minimal supervision and, most important, with a temporal resolution of less than a minute. For this purpose a microporous hydrophobic membrane contactor (Membrana) was combined with an isotope laser spectrometer (Picarro). The contactor, originally designed for degassing liquids, was used with N2 as a carrier gas in order to transform a small fraction of liquid water to water vapor. The generated water vapor was then analyzed continuously by the Picarro analyzer. To prove the membrane's applicability, we determined the specific isotope fractionation factor for the phase change through the contactor's membrane across an extended temperature range (8°C-21°C) and with different waters of known isotopic compositions. This fractionation factor is needed to subsequently derive the liquid water isotope ratio from the measured water vapor isotope ratios. The system was tested with a soil column experiment, where the isotope values derived with the new method corresponded well (R2 = 0.998 for δ18O and R2 = 0.997 for δ2H) with those of liquid water samples taken simultaneously and analyzed with a conventional method (cavity ring-down spectroscopy). The new method supersedes taking liquid samples and employs only relatively cheap and readily available components. This makes it a relatively inexpensive, fast, user-friendly, and easily reproducible method. It can be applied in both the field and laboratory wherever a water vapor isotope analyzer can be run and whenever real-time isotope data of liquid water are required at high temporal resolution.

  11. Local Structure Analysis in $Ab$ $Initio$ Liquid Water

    OpenAIRE

    Santra, Biswajit; DiStasio Jr., Robert A.; Martelli, Fausto; Car, Roberto

    2015-01-01

    Within the framework of density functional theory, the inclusion of exact exchange and non-local van der Waals/dispersion (vdW) interactions is crucial for predicting a microscopic structure of ambient liquid water that quantitatively agrees with experiment. In this work, we have used the local structure index (LSI) order parameter to analyze the local structure in such highly accurate $ab$ $initio$ liquid water. At ambient conditions, the LSI probability distribution, P($I$), was unimodal wi...

  12. Scenario analysis for sustainable development of Chongming Island: water resources sustainability.

    Science.gov (United States)

    Ni, Xiong; Wu, Yanqing; Wu, Jun; Lu, Jian; Wilson, P Chris

    2012-11-15

    With the socioeconomic and urban development of Chongming Island (the largest alluvial island in the world), water demand is rapidly growing. To make adjustments to the water utilization structure of each industry, allocate limited water resources, and increase local water use efficiency, this study performed a scenario analysis for the water sustainability of Chongming Island. Four different scenarios were performed to assess the water resource availability by 2020. The growth rate for water demand will be much higher than that of water supply under a serious situation prediction. The water supply growth volume will be 2.22 × 10(8)m(3) from 2010 to 2020 under Scenario I and Scenario II while the corresponding water demand growth volume will be 2.74 × 10(8)m(3) and 2.64 × 10(8)m(3), respectively. There will be a rapid growth in water use benefit under both high and low development modes. The water use benefit will be about 50 CNY/m(3) under Scenarios I and II in 2020. The production structure will need to be adjusted for sustainable utilization of water resources. Sewage drainage but not the forest and grass coverage rate will be a major obstacle to future development and environmental quality. According to a multi-level fuzzy comprehensive evaluation, Scenario II is finally deemed to be the most desirable plan, suggesting that the policy of rapid socioeconomic development and better environmental protection may achieve the most sustainable development of Chongming Island in the future. Copyright © 2012 Elsevier B.V. All rights reserved.

  13. Planning for Sustainable Use of Water

    OpenAIRE

    Hedelin, Beatrice

    2008-01-01

    The basic problem that this work wishes to address concerns the  unsustainable use of water resources in many places of the world. In some places, the problem leads to human suffering and death while also obstructing social and economic development. In other places, where the consequences are less severe, natural environments are seriously damaged. A significant part of the solution to this problem lies in the planning and decision-making domain. The overall aim of this thesis is therefore to...

  14. Improving Potable Water Accessibility And Sustainability Through Efficient Management Of Pipe Water Supply System

    OpenAIRE

    Nakabugo, Stella Mirembe

    2015-01-01

    This paper discusses how to improve potable water accessibility and sustainability through efficient management of pipe water supply system a case study of Uganda, Kampala region. Kampala the capital city of Uganda still faces a challenge to access clean potable water. Water supply coverage is 77.5 % showing at least 22.5 % of the total population has limited access to potable drinking water causing a gap between water supply and water demand. Hypotheses of the paper were that the city's popu...

  15. Self-Sustaining Thorium Boiling Water Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Greenspan, Ehud [Univ. of California, Berkeley, CA (United States); Gorman, Phillip M. [Univ. of California, Berkeley, CA (United States); Bogetic, Sandra [Univ. of California, Berkeley, CA (United States); Seifried, Jeffrey E. [Univ. of California, Berkeley, CA (United States); Zhang, Guanheng [Univ. of California, Berkeley, CA (United States); Varela, Christopher R. [Univ. of California, Berkeley, CA (United States); Fratoni, Massimiliano [Univ. of California, Berkeley, CA (United States); Vijic, Jasmina J. [Univ. of California, Berkeley, CA (United States); Downar, Thomas [Univ. of Michigan, Ann Arbor, MI (United States); Hall, Andrew [Univ. of Michigan, Ann Arbor, MI (United States); Ward, Andrew [Univ. of Michigan, Ann Arbor, MI (United States); Jarrett, Michael [Univ. of Michigan, Ann Arbor, MI (United States); Wysocki, Aaron [Univ. of Michigan, Ann Arbor, MI (United States); Xu, Yunlin [Univ. of Michigan, Ann Arbor, MI (United States); Kazimi, Mujid [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Shirvan, Koroush [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Mieloszyk, Alexander [Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States); Todosow, Michael [Brookhaven National Lab. (BNL), Upton, NY (United States); Brown, Nicolas [Brookhaven National Lab. (BNL), Upton, NY (United States); Cheng, Lap [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-03-15

    The primary objectives of this project are to: Perform a pre-conceptual design of a core for an alternative to the Hitachi proposed fuel-self- sustaining RBWR-AC, to be referred to as a RBWR-Th. The use of thorium fuel is expected to assure negative void coefficient of reactivity (versus positive of the RBWR-AC) and improve reactor safety; Perform a pre-conceptual design of an alternative core to the Hitachi proposed LWR TRU transmuting RBWR-TB2, to be referred to as the RBWR-TR. In addition to improved safety, use of thorium for the fertile fuel is expected to improve the TRU transmutation effectiveness; Compare the RBWR-Th and RBWR-TR performance against that of the Hitachi RBWR core designs and sodium cooled fast reactor counterparts - the ARR and ABR; and, Perform a viability assessment of the thorium-based RBWR design concepts to be identified along with their associated fuel cycle, a technology gap analysis, and a technology development roadmap. A description of the work performed and of the results obtained is provided in this Overview Report and, in more detail, in the Attachments. The major findings of the study are summarized.

  16. Pathways to sustainable intensification through crop water management

    Science.gov (United States)

    MacDonald, Graham K.; D'Odorico, Paolo; Seekell, David A.

    2016-09-01

    How much could farm water management interventions increase global crop production? This is the central question posed in a global modelling study by Jägermeyr et al (2016 Environ. Res. Lett. 11 025002). They define the biophysical realm of possibility for future gains in crop production related to agricultural water practices—enhancing water availability to crops and expanding irrigation by reducing non-productive water consumption. The findings of Jägermeyr et al offer crucial insight on the potential for crop water management to sustainably intensify agriculture, but they also provide a benchmark to consider the broader role of sustainable intensification targets in the global food system. Here, we reflect on how the global crop water management simulations of Jägermeyr et al could interact with: (1) farm size at more local scales, (2) downstream water users at the river basin scale, as well as (3) food trade and (4) demand-side food system strategies at the global scale. Incorporating such cross-scale linkages in future research could highlight the diverse pathways needed to harness the potential of farm-level crop water management for a more productive and sustainable global food system.

  17. The coffee-drop phenomenon and its time fluctuations: Self-sustained oscillations in colloidal liquids

    Science.gov (United States)

    Yakhno, T. A.; Yakhno, V. G.

    2017-03-01

    The instant coffee model has been taken to study self-sustained oscillations in liquid dispersive media using dynamic self-organization processes in drying droplets that stay sessile on a solid wetted substrate. The width of the formed ring and the dynamics of mechanical properties of the drying sediment and the way they fluctuated over 11 h of the experiment have been measured. Analysis has shown a high degree of correlation between these indicators. This dynamics reflects processes that develop in the examined liquid medium. The possible mechanism of self-sustained oscillations, which is related to the aggregation-disaggregation of the colloidal phase and fluctuations of the interphase tension, has been discussed. The practical significance of this work is that fluctuation processes in liquid dispersive media need to be taken into account as a natural source of systematic measurement error.

  18. Systems Reliability Framework for Surface Water Sustainability and Risk Management

    Science.gov (United States)

    Myers, J. R.; Yeghiazarian, L.

    2016-12-01

    With microbial contamination posing a serious threat to the availability of clean water across the world, it is necessary to develop a framework that evaluates the safety and sustainability of water systems in respect to non-point source fecal microbial contamination. The concept of water safety is closely related to the concept of failure in reliability theory. In water quality problems, the event of failure can be defined as the concentration of microbial contamination exceeding a certain standard for usability of water. It is pertinent in watershed management to know the likelihood of such an event of failure occurring at a particular point in space and time. Microbial fate and transport are driven by environmental processes taking place in complex, multi-component, interdependent environmental systems that are dynamic and spatially heterogeneous, which means these processes and therefore their influences upon microbial transport must be considered stochastic and variable through space and time. A physics-based stochastic model of microbial dynamics is presented that propagates uncertainty using a unique sampling method based on artificial neural networks to produce a correlation between watershed characteristics and spatial-temporal probabilistic patterns of microbial contamination. These results are used to address the question of water safety through several sustainability metrics: reliability, vulnerability, resilience and a composite sustainability index. System reliability is described uniquely though the temporal evolution of risk along watershed points or pathways. Probabilistic resilience describes how long the system is above a certain probability of failure, and the vulnerability metric describes how the temporal evolution of risk changes throughout a hierarchy of failure levels. Additionally our approach allows for the identification of contributions in microbial contamination and uncertainty from specific pathways and sources. We expect that this

  19. Moving Towards Sustainable and Resilient Smart Water Grids

    Directory of Open Access Journals (Sweden)

    Michele Mutchek

    2014-03-01

    Full Text Available Urban water systems face sustainability and resiliency challenges including water leaks, over-use, quality issues, and response to drought and natural disasters. Information and communications technology (ICT could help address these challenges through the development of smart water grids that network and automate monitoring and control devices. While progress is being made on technology elements, as a system, the smart water grid has received scant attention. This article aims to raise awareness of the systems-level idea of smart water grids by reviewing the technology elements and their integration into smart water systems, discussing potential sustainability and resiliency benefits, and challenges relating to the adoption of smart water grids. Water losses and inefficient use stand out as promising areas for applications of smart water grids. Potential barriers to the adoption of smart water grids include lack of funding for research and development, economic disincentives as well as institutional and political structures that favor the current system. It is our hope that future work can clarify the benefits of smart water grids and address challenges to their further development.

  20. Solid-liquid critical behavior of water in nanopores.

    Science.gov (United States)

    Mochizuki, Kenji; Koga, Kenichiro

    2015-07-07

    Nanoconfined liquid water can transform into low-dimensional ices whose crystalline structures are dissimilar to any bulk ices and whose melting point may significantly rise with reducing the pore size, as revealed by computer simulation and confirmed by experiment. One of the intriguing, and as yet unresolved, questions concerns the observation that the liquid water may transform into a low-dimensional ice either via a first-order phase change or without any discontinuity in thermodynamic and dynamic properties, which suggests the existence of solid-liquid critical points in this class of nanoconfined systems. Here we explore the phase behavior of a model of water in carbon nanotubes in the temperature-pressure-diameter space by molecular dynamics simulation and provide unambiguous evidence to support solid-liquid critical phenomena of nanoconfined water. Solid-liquid first-order phase boundaries are determined by tracing spontaneous phase separation at various temperatures. All of the boundaries eventually cease to exist at the critical points and there appear loci of response function maxima, or the Widom lines, extending to the supercritical region. The finite-size scaling analysis of the density distribution supports the presence of both first-order and continuous phase changes between solid and liquid. At around the Widom line, there are microscopic domains of two phases, and continuous solid-liquid phase changes occur in such a way that the domains of one phase grow and those of the other evanesce as the thermodynamic state departs from the Widom line.

  1. Water Footprint Assessment in Waste Water Treatment Plant: Indicator of the sustainability of urban water cycle.

    Science.gov (United States)

    Gómez Llanos, Eva; Durán Barroso, Pablo; Matías Sánchez, Agustín; Fernández Rodríguez, Santiago; Guzmán Caballero, Raúl

    2017-04-01

    The seventeen Sustainable Development Goals (SDG) represent a challenge for citizens and countries around the world by working together to reduce social inequality, to fight poverty and climate change. The Goal six water and sanitation aims for ensuring, among others, the protection and restoration of water-related ecosystem (target 6.6) and encouraging the water use efficiency (target 6.3). The commitment to this goal is not only the development of sanitation infrastructure, but also incorporates the necessity of a sustainable and efficient management from ecological and economic perspectives. Following this approach, we propose a framework for assessing the waste water treatment plant (WWTP) management based on the Water Footprint (WF) principles. The WF as indicator is able to highlight the beneficial role of WWTPs within the environment and provide a complementary information to evaluate the impact of a WWTP regarding to the use of freshwater and energy. Therefore, the footprint family provides an opportunity to relate the reduction of pollutant load in a WWTP and the associated consumptions in terms of electricity and chemical products. As a consequence, the new methodology allows a better understanding of the interactions among water and energy resources, economic requirements and environmental risks. Because of this, the current technologies can be improved and innovative solutions for monitoring and management of urban water use can be integrated. The WF was calculated in four different WWTP located in the North East of Extremadura (SW Spain) which have activated sludge process as secondary treatment. This zone is characterized by low population density but an incipient tourism development. The WF estimation and its relationship with the electricity consumption examines the efficiency of each WWTP and identifies the weak points in the management in terms of the sustainability. Consequently, the WF establishes a benchmark for multidisciplinary decision

  2. Sustainable Water Distribution Strategy with Smart Water Grid

    Directory of Open Access Journals (Sweden)

    Seongjoon Byeon

    2015-04-01

    Full Text Available Many problems that are encountered in regards to water balance and resources management are related to challenges of economic development under limited resources and tough competition among various water uses. The development of major infrastructure like airports in remote areas that have limited water resources is becoming a common problem. In order to overcome these difficulties, water management has to articulate and combine several resources in order to respond to various demands while preserving the ecological quality of the environment. The paper discusses the interest in implementing the Smart Water Grid concept on Yeongjongdo Island, which is the location of Korea’s main airport. This new concept is based on the connection of various water resources and their optimized management with new information technology solutions. The proposed system integrates water generated through rainfall, external water resources (i.e., metropolitan water distribution system, gray water and other types of alternative water resources. The paper analyses the feasibility of this approach and explores interest in the Smart Water Grid concept.

  3. Liquid Water in the Extremely Shallow Martian Subsurface

    Science.gov (United States)

    Pavlov, A.; Shivak, J. N.

    2012-01-01

    Availability of liquid water is one of the major constraints for the potential Martian biosphere. Although liquid water is unstable on the surface of Mars due to low atmospheric pressures, it has been suggested that liquid films of water could be present in the Martian soil. Here we explored a possibility of the liquid water formation in the extremely shallow (1-3 cm) subsurface layer under low atmospheric pressures (0.1-10 mbar) and low ("Martian") surface temperatures (approx.-50 C-0 C). We used a new Goddard Martian simulation chamber to demonstrate that even in the clean frozen soil with temperatures as low as -25C the amount of mobile water can reach several percents. We also showed that during brief periods of simulated daylight warming the shallow subsurface ice sublimates, the water vapor diffuses through porous surface layer of soil temporarily producing supersaturated conditions in the soil, which leads to the formation of additional liquid water. Our results suggest that despite cold temperatures and low atmospheric pressures, Martian soil just several cm below the surface can be habitable.

  4. Sustainability of Rainwater Harvesting System in terms of Water Quality

    Directory of Open Access Journals (Sweden)

    Sadia Rahman

    2014-01-01

    Full Text Available Water is considered an everlasting free source that can be acquired naturally. Demand for processed supply water is growing higher due to an increasing population. Sustainable use of water could maintain a balance between its demand and supply. Rainwater harvesting (RWH is the most traditional and sustainable method, which could be easily used for potable and nonpotable purposes both in residential and commercial buildings. This could reduce the pressure on processed supply water which enhances the green living. This paper ensures the sustainability of this system through assessing several water-quality parameters of collected rainwater with respect to allowable limits. A number of parameters were included in the analysis: pH, fecal coliform, total coliform, total dissolved solids, turbidity, NH3–N, lead, BOD5, and so forth. The study reveals that the overall quality of water is quite satisfactory as per Bangladesh standards. RWH system offers sufficient amount of water and energy savings through lower consumption. Moreover, considering the cost for installation and maintenance expenses, the system is effective and economical.

  5. Sustainability of Rainwater Harvesting System in terms of Water Quality

    Science.gov (United States)

    Khan, M. T. R.; Akib, Shatirah; Din, Nazli Bin Che; Biswas, S. K.; Shirazi, S. M.

    2014-01-01

    Water is considered an everlasting free source that can be acquired naturally. Demand for processed supply water is growing higher due to an increasing population. Sustainable use of water could maintain a balance between its demand and supply. Rainwater harvesting (RWH) is the most traditional and sustainable method, which could be easily used for potable and nonpotable purposes both in residential and commercial buildings. This could reduce the pressure on processed supply water which enhances the green living. This paper ensures the sustainability of this system through assessing several water-quality parameters of collected rainwater with respect to allowable limits. A number of parameters were included in the analysis: pH, fecal coliform, total coliform, total dissolved solids, turbidity, NH3–N, lead, BOD5, and so forth. The study reveals that the overall quality of water is quite satisfactory as per Bangladesh standards. RWH system offers sufficient amount of water and energy savings through lower consumption. Moreover, considering the cost for installation and maintenance expenses, the system is effective and economical. PMID:24701186

  6. Sustainability of rainwater harvesting system in terms of water quality.

    Science.gov (United States)

    Rahman, Sadia; Khan, M T R; Akib, Shatirah; Din, Nazli Bin Che; Biswas, S K; Shirazi, S M

    2014-01-01

    Water is considered an everlasting free source that can be acquired naturally. Demand for processed supply water is growing higher due to an increasing population. Sustainable use of water could maintain a balance between its demand and supply. Rainwater harvesting (RWH) is the most traditional and sustainable method, which could be easily used for potable and nonpotable purposes both in residential and commercial buildings. This could reduce the pressure on processed supply water which enhances the green living. This paper ensures the sustainability of this system through assessing several water-quality parameters of collected rainwater with respect to allowable limits. A number of parameters were included in the analysis: pH, fecal coliform, total coliform, total dissolved solids, turbidity, NH3-N, lead, BOD5, and so forth. The study reveals that the overall quality of water is quite satisfactory as per Bangladesh standards. RWH system offers sufficient amount of water and energy savings through lower consumption. Moreover, considering the cost for installation and maintenance expenses, the system is effective and economical.

  7. Roadmap for sustainable water resources in southwestern North America

    Science.gov (United States)

    Gleick, Peter H.

    2010-01-01

    The management of water resources in arid and semiarid areas has long been a challenge, from ancient Mesopotamia to the modern southwestern United States. As our understanding of the hydrological and climatological cycles has improved, and our ability to manipulate the hydrologic cycle has increased, so too have the challenges associated with managing a limited natural resource for a growing population. Modern civilization has made remarkable progress in water management in the past few centuries. Burgeoning cities now survive in desert regions, relying on a mix of simple and complex technologies and management systems to bring adequate water and remove wastewater. These systems have permitted agricultural production and urban concentrations to expand in regions previously thought to have inadequate moisture. However, evidence is also mounting that our current management and use of water is unsustainable. Physical, economic, and ecological limits constrain the development of new supplies and additional water withdrawals, even in regions not previously thought vulnerable to water constraints. New kinds of limits are forcing water managers and policy makers to rethink previous assumptions about population, technology, regional planning, and forms of development. In addition, new threats, especially the challenges posed by climatic changes, are now apparent. Sustainably managing and using water in arid and semiarid regions such as the southwestern United States will require new thinking about water in an interdisciplinary and integrated way. The good news is that a wide range of options suggest a roadmap for sustainable water management and use in the coming decades. PMID:21149725

  8. Membrane-based processes for sustainable power generation using water.

    Science.gov (United States)

    Logan, Bruce E; Elimelech, Menachem

    2012-08-16

    Water has always been crucial to combustion and hydroelectric processes, but it could become the source of power in membrane-based systems that capture energy from natural and waste waters. Two processes are emerging as sustainable methods for capturing energy from sea water: pressure-retarded osmosis and reverse electrodialysis. These processes can also capture energy from waste heat by generating artificial salinity gradients using synthetic solutions, such as thermolytic salts. A further source of energy comes from organic matter in waste waters, which can be harnessed using microbial fuel-cell technology, allowing both wastewater treatment and power production.

  9. Membrane-based processes for sustainable power generation using water

    KAUST Repository

    Logan, Bruce E.

    2012-08-15

    Water has always been crucial to combustion and hydroelectric processes, but it could become the source of power in membrane-based systems that capture energy from natural and waste waters. Two processes are emerging as sustainable methods for capturing energy from sea water: pressure-retarded osmosis and reverse electrodialysis. These processes can also capture energy from waste heat by generating artificial salinity gradients using synthetic solutions, such as thermolytic salts. A further source of energy comes from organic matter in waste waters, which can be harnessed using microbial fuel-cell technology, allowing both wastewater treatment and power production. © 2012 Macmillan Publishers Limited. All rights reserved.

  10. Review: Drinking water for liquid-fed pigs.

    Science.gov (United States)

    Meunier-Salaün, M-C; Chiron, J; Etore, F; Fabre, A; Laval, A; Pol, F; Prunier, A; Ramonet, Y; Nielsen, B L

    2017-05-01

    Liquid feeding has the potential to provide pigs with sufficient water to remain hydrated and prevent prolonged thirst. However, lack of permanent access to fresh water prevents animals from drinking when they are thirsty. Moreover, individual differences between pigs in a pen may result in uneven distribution of the water provided by the liquid feed, leading to some pigs being unable to meet their water requirements. In this review, we look at the need for and provision of water for liquid-fed pigs in terms of their production performance, behaviour, health and welfare. We highlight factors which may lead to water ingestion above or below requirements. Increases in the need for water may be caused by numerous factors such as morbidity, ambient temperature or competition within the social group, emphasising the necessity of permanent access to water as also prescribed in EU legislation. The drinkers can be the target of redirected behaviour in response to feed restriction or in the absence of rooting materials, thereby generating water losses. The method of water provision and drinker design is critical to ensure easy access to water regardless of the pig's physiological state, and to limit the amount of water used, which does not benefit the pig.

  11. Framework for Assessing Water Resource Sustainability in River Basins

    Science.gov (United States)

    Borden, J.; Goodwin, P.; Swanson, D.

    2013-12-01

    As the anthropogenic footprint increases on Earth, the wise use, maintenance, and protection of freshwater resources will be a key element in the sustainability of development. Borne from efforts to promote sustainable development of water resources is Integrated Water Resource Management (IWRM), which promotes efficiency of water resources, equity in water allocation across different social and economic groups, and environmental sustainability. Methodologies supporting IWRM implementation have largely focused on the overall process, but have had limited attention on the evaluation methods for ecologic, economic, and social conditions (the sustainability criterion). Thus, assessment frameworks are needed to support the analysis of water resources and evaluation of sustainable solutions in the IWRM process. To address this need, the River Basin Analysis Framework (RBAF) provides a structure for understanding water related issues and testing the sustainability of proposed solutions in river basins. The RBAF merges three approaches: the UN GEO 4 DPSIR approach, the Millennium Ecosystem Assessment approach, and the principles of sustainable development. Merging these approaches enables users to understand the spatiotemporal interactions between the hydrologic and ecologic systems, evaluate the impacts of disturbances (drivers, pressures) on the ecosystem goods and services (EGS) and constituents of human well-being (HWB), and identify and employ analytical methods and indicators in the assessments. The RBAF is comprised of a conceptual component (RBAF-C) and an analytical component (RBAF-A). For each disturbance type, the RBAF-C shows the potential directional change in the hydrologic cycle (peak flows, seasonality, etc.), EGS (drinking water supply, water purification, recreational opportunities, etc.), and HWB (safety, health, access to a basic materials), thus allowing users insight into potential impacts as well as providing technical guidance on the methods and

  12. Integrated Nutrient and Water Management for Sustainable Food ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Integrated Nutrient and Water Management for Sustainable Food Production in the Sahel (CIFSRF). In the Sahel, agricultural production is strictly limited by drought and low soil fertility. In 2005 and 2010, these two factors led to food scarcity in Niger. However, innovative technologies such as microdose fertilization ...

  13. Climate Change Impact Assessment for Sustainable Water Quality Management

    Directory of Open Access Journals (Sweden)

    Ching-Pin Tung

    2012-01-01

    Full Text Available The goal of sustainable water quality management is to keep total pollutant discharges from exceeding the assimilation capacity of a water body. Climate change may influence streamflows, and further alter assimilation capacity and degrade river sustainability. The purposes of this study are to evaluate the effect of climate change on sustainable water quality management and design an early warning indicator to issue warnings on river sustainability. A systematic assessment procedure is proposed here, including a weather generation model, the streamflow component of GWLF, QUAL2E, and an optimization model. The Touchen creek in Taiwan is selected as the study area. Future climate scenarios derived from projections of four global climate models (GCMs and two pollutant discharge scenarios, as usual and proportional to population, are considered in this study. The results indicate that streamflows may very likely increase in humid seasons and decrease in arid seasons, respectively. The reduction of streamflow in arid seasons may further degrade water quality and assimilation capacity. In order to provide warnings to trigger necessary adaptation strategies, an early warning indicator is designed and its 30-year moving average is calculated. Finally, environmental monitoring systems and methods to prioritize adaptation strategies are discussed for further studies in the future.

  14. Integrated Nutrient and Water Management for Sustainable Food ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Integrated Nutrient and Water Management for Sustainable Food Production in the Sahel (CIFSRF). In the Sahel, agricultural production is strictly limited by drought and low soil fertility. In 2005 and 2010, these two factors led to food scarcity in Niger. However, innovative technologies such as ... Date de début. 1 mars 2011 ...

  15. Sustainable Water Management under Climate Change in Small ...

    International Development Research Centre (IDRC) Digital Library (Canada)

    Sustainable Water Management under Climate Change in Small Island States of the Caribbean. In the Caribbean islands, climate change is affecting freshwater availability and other ecosystem services in complex ways. For example, freshwater supply is diminished by droughts and affected by saline intrusion due to sea ...

  16. Sustainable water for rural security - A transdisciplinary approach [Presentation

    CSIR Research Space (South Africa)

    Maherry, A

    2012-05-01

    Full Text Available Biennial Conference & Exhibition, Cape Town, 2012 Sustainable water for rural security – a transdisciplinary approach *Maherry A1, Genthe B1, Steyn M,1 Clarke S1, Beukman E1, Audouin M1, Van Wyk I2 and Wall K1. 1 CSIR. Natural Resources...

  17. Indirect Potable Reuse: A Sustainable Water Supply Alternative

    Science.gov (United States)

    Rodriguez, Clemencia; Van Buynder, Paul; Lugg, Richard; Blair, Palenque; Devine, Brian; Cook, Angus; Weinstein, Philip

    2009-01-01

    The growing scarcity of potable water supplies is among the most important issues facing many cities, in particular those using single sources of water that are climate dependent. Consequently, urban centers are looking to alternative sources of water supply that can supplement variable rainfall and meet the demands of population growth. A diversified portfolio of water sources is required to ensure public health, as well as social, economical and environmental sustainability. One of the options considered is the augmentation of drinking water supplies with advanced treated recycled water. This paper aims to provide a state of the art review of water recycling for drinking purposes with emphasis on membrane treatment processes. An overview of significant indirect potable reuse projects is presented followed by a description of the epidemiological and toxicological studies evaluating any potential human health impacts. Finally, a summary of key operational measures to protect human health and the areas that require further research are discussed. PMID:19440440

  18. Indirect Potable Reuse: A Sustainable Water Supply Alternative

    Directory of Open Access Journals (Sweden)

    Clemencia Rodriguez

    2009-03-01

    Full Text Available The growing scarcity of potable water supplies is among the most important issues facing many cities, in particular those using single sources of water that are climate dependent. Consequently, urban centers are looking to alternative sources of water supply that can supplement variable rainfall and meet the demands of population growth. A diversified portfolio of water sources is required to ensure public health, as well as social, economical and environmental sustainability. One of the options considered is the augmentation of drinking water supplies with advanced treated recycled water. This paper aims to provide a state of the art review of water recycling for drinking purposes with emphasis on membrane treatment processes. An overview of significant indirect potable reuse projects is presented followed by a description of the epidemiological and toxicological studies evaluating any potential human health impacts. Finally, a summary of key operational measures to protect human health and the areas that require further research are discussed.

  19. Measuring global water security towards sustainable development goals

    Science.gov (United States)

    Gain, Animesh K.; Giupponi, Carlo; Wada, Yoshihide

    2016-12-01

    Water plays an important role in underpinning equitable, stable and productive societies and ecosystems. Hence, United Nations recognized ensuring water security as one (Goal 6) of the seventeen sustainable development goals (SDGs). Many international river basins are likely to experience ‘low water security’ over the coming decades. Water security is rooted not only in the physical availability of freshwater resources relative to water demand, but also on social and economic factors (e.g. sound water planning and management approaches, institutional capacity to provide water services, sustainable economic policies). Until recently, advanced tools and methods are available for the assessment of water scarcity. However, quantitative and integrated—physical and socio-economic—approaches for spatial analysis of water security at global level are not available yet. In this study, we present a spatial multi-criteria analysis framework to provide a global assessment of water security. The selected indicators are based on Goal 6 of SDGs. The term ‘security’ is conceptualized as a function of ‘availability’, ‘accessibility to services’, ‘safety and quality’, and ‘management’. The proposed global water security index (GWSI) is calculated by aggregating indicator values on a pixel-by-pixel basis, using the ordered weighted average method, which allows for the exploration of the sensitivity of final maps to different attitudes of hypothetical policy makers. Our assessment suggests that countries of Africa, South Asia and Middle East experience very low water security. Other areas of high water scarcity, such as some parts of United States, Australia and Southern Europe, show better GWSI values, due to good performance of management, safety and quality, and accessibility. The GWSI maps show the areas of the world in which integrated strategies are needed to achieve water related targets of the SDGs particularly in the African and Asian continents.

  20. Measuring Global Water Security Towards Sustainable Development Goals

    Science.gov (United States)

    Gain, Animesh K.; Giupponi, Carlo; Wada, Yoshihide

    2016-01-01

    Water plays an important role in underpinning equitable, stable and productive societies and ecosystems. Hence, United Nations recognized ensuring water security as one (Goal 6) of the seventeen sustainable development goals (SDGs). Many international river basins are likely to experience 'low water security' over the coming decades. Water security is rooted not only in the physical availability of freshwater resources relative to water demand, but also on social and economic factors (e.g. sound water planning and management approaches, institutional capacity to provide water services, sustainable economic policies). Until recently, advanced tools and methods are available for the assessment of water scarcity. However, quantitative and integrated-physical and socio-economic-approaches for spatial analysis of water security at global level are not available yet. In this study, we present a spatial multi-criteria analysis framework to provide a global assessment of water security. The selected indicators are based on Goal 6 of SDGs. The term 'security' is conceptualized as a function of 'availability', 'accessibility to services', 'safety and quality', and 'management'. The proposed global water security index (GWSI) is calculated by aggregating indicator values on a pixel-by-pixel basis, using the ordered weighted average method, which allows for the exploration of the sensitivity of final maps to different attitudes of hypothetical policy makers. Our assessment suggests that countries of Africa, South Asia and Middle East experience very low water security. Other areas of high water scarcity, such as some parts of United States, Australia and Southern Europe, show better GWSI values, due to good performance of management, safety and quality, and accessibility. The GWSI maps show the areas of the world in which integrated strategies are needed to achieve water related targets of the SDGs particularly in the African and Asian continents.

  1. Anharmonic bend-stretch coupling in neat liquid water

    NARCIS (Netherlands)

    Lindner, Joerg; Cringus, Dan; Pshenichnikov, Maxim S.; Voehringer, Peter

    2007-01-01

    Femtosecond mid-IR spectroscopy is used to study the vibrational relaxation dynamics in neat liquid water. By exciting the bending vibration and probing the stretching mode, it is possible to reliably determine the bending and librational lifetimes of water. The anharmonic coupling between the

  2. Communication: Protein dynamical transition vs. liquid-liquid phase transition in protein hydration water

    Science.gov (United States)

    Schirò, Giorgio; Fomina, Margarita; Cupane, Antonio

    2013-09-01

    In this work, we compare experimental data on myoglobin hydrated powders from elastic neutron scattering, broadband dielectric spectroscopy, and differential scanning calorimetry. Our aim is to obtain new insights on the connection between the protein dynamical transition, a fundamental phenomenon observed in proteins whose physical origin is highly debated, and the liquid-liquid phase transition (LLPT) possibly occurring in protein hydration water and related to the existence of a low temperature critical point in supercooled water. Our results provide a consistent thermodynamic/dynamic description which gives experimental support to the LLPT hypothesis and further reveals how fundamental properties of water and proteins are tightly related.

  3. Experimental Evidence for a Liquid-Liquid Crossover in Deeply Cooled Confined Water

    Science.gov (United States)

    Cupane, Antonio; Fomina, Margarita; Piazza, Irina; Peters, Judith; Schirò, Giorgio

    2014-11-01

    In this work we investigate, by means of elastic neutron scattering, the pressure dependence of mean square displacements (MSD) of hydrogen atoms of deeply cooled water confined in the pores of a three-dimensional disordered SiO2 xerogel; experiments have been performed at 250 and 210 K from atmospheric pressure to 1200 bar. The "pressure anomaly" of supercooled water (i.e., a mean square displacement increase with increasing pressure) is observed in our sample at both temperatures; however, contrary to previous simulation results and to the experimental trend observed in bulk water, the pressure effect is smaller at lower (210 K) than at higher (250 K) temperature. Elastic neutron scattering results are complemented by differential scanning calorimetry data that put in evidence, besides the glass transition at about 170 K, a first-order-like endothermic transition occurring at about 230 K that, in view of the neutron scattering results, can be attributed to a liquid-liquid crossover. Our results give experimental evidence for the presence, in deeply cooled confined water, of a crossover occurring at about 230 K (at ambient pressure) from a liquid phase predominant at 210 K to another liquid phase predominant at 250 K; therefore, they are fully consistent with the liquid-liquid transition hypothesis.

  4. Water Sustainability Assessments for Four Net Zero Water Installations

    Science.gov (United States)

    2013-12-01

    Infrastructure Development and Evaluation PVC Polyvinyl Chloride PX Post Exchange QAP Quality Assurance Plan REMIS Real Estate Management Information System...2010. Standard geospatial data layer quality assurance plan ( QAP ): Water line. SDSFIE 2. 6. 1: water_ling. Version 1. 0. 1, September 2010

  5. Bond orientational order in liquids: Towards a unified description of water-like anomalies, liquid-liquid transition, glass transition, and crystallization: Bond orientational order in liquids.

    Science.gov (United States)

    Tanaka, Hajime

    2012-10-01

    There are at least three fundamental states of matter, depending upon temperature and pressure: gas, liquid, and solid (crystal). These states are separated by first-order phase transitions between them. In both gas and liquid phases a complete translational and rotational symmetry exist, whereas in a solid phase both symmetries are broken. In intermediate phases between liquid and solid, which include liquid crystal and plastic crystal phases, only one of the two symmetries is preserved. Among the fundamental states of matter, the liquid state is the most poorly understood. We argue that it is crucial for a better understanding of liquids to recognize that a liquid generally has the tendency to have a local structural order and its presence is intrinsic and universal to any liquid. Such structural ordering is a consequence of many-body correlations, more specifically, bond angle correlations, which we believe are crucial for the description of the liquid state. We show that this physical picture may naturally explain difficult unsolved problems associated with the liquid state, such as anomalies of water-type liquids (water, Si, Ge, ...), liquid-liquid transition, liquid-glass transition, crystallization and quasicrystal formation, in a unified manner. In other words, we need a new order parameter representing a low local free-energy configuration, which is a bond orientational order parameter in many cases, in addition to a density order parameter for the physical description of these phenomena. Here we review our two-order-parameter model of liquid and consider how transient local structural ordering is linked to all of the above-mentioned phenomena. The relationship between these phenomena is also discussed.

  6. Recent history provides sustainable African water quality project insight.

    Science.gov (United States)

    Holm, Rochelle H

    2012-01-01

    Small-scale projects to provide clean drinking water undertaken in the developing world can contribute to significantly improving the livelihood of rural communities. There has been a historical tendency to poorly plan such projects leading to an unsustainable future. Recent history indicates three simple steps to ensuring successful and enduring clean water projects. First, identification of need by the indigenous community provides ownership in the project. Second, a partnership between key individuals in the indigenous community with the donor provides for ambassadors on both sides of the project. Finally, an exit strategy by the donors for the indigenous communities ensures local sustainability for the future. The study site is the village of Geisha in northern Malawi, Africa. Sustainable implementation approaches are discussed in this case study as well as the various lessons learned. Improved project processes ensure sustainable small-scale water quality projects by donor organizations in developing countries. © 2011, The Author(s). Ground Water © 2011, National Ground Water Association.

  7. Practices and perceptions on water resource sustainability in ecovillages

    Science.gov (United States)

    de Moura Leite, Flavia Brunale Vilela; Bertolo, Lídia Sanches; Santos, Rozely Ferreira

    2016-08-01

    In many areas of the world, groups of people have attempted to create urban landscapes that follow the principles of environmental sustainability. To this end, groups have devised alternative models, such as ecovillages, where low-impact handling is used and a way of life different from that of large population centers is adopted. Although these villages exist, their efficiency in the conservation of natural resources has not been effectively evaluated. This study evaluated the practices used by two Brazilian ecovillages to conserve water resources to assess whether this new concept of living is indeed successful in meeting sustainability goals. We selected 25 indicators of water sustainability, and using the compromise programming method, we quantified the distance between those landscapes self-referenced as sustainable and an ideal hypothetical scenario. We also interpreted the communities perceptions using the distance between the current situations and the envisioned scenario. We concluded that both ecovillage are far from technically ideal scenario, but the communities have a strong sense of their limitations in implementing water resources conservation. The communities attributed this fact primarily to deficiencies in the shared management.

  8. Sustainable Development of Energy, Water and Environment Systems

    DEFF Research Database (Denmark)

    Markovska, Natasa; Duić, Neven; Mathiesen, Brian Vad

    2016-01-01

    The Conference on Sustainable Development of Energy, Water and Environment Systems (SDEWES) in 2015 returned to its hometown, Dubrovnik, and once again served as a significant venue for scientists and specialists in different areas of sustainable development from all over the world to initiate...... traditionally cover a range of energy issues - higher renewables penetration and various technologies and fuels assessments at energy supply side, as well as, energy efficiency in various sectors, buildings, district heating, electric vehicles and demand modelling at energy demand side. Also, a review paper...

  9. Surface potential of the water liquid-vapor interface

    Science.gov (United States)

    Wilson, Michael A.; Pohorille, Andrew; Pratt, Lawrence R.

    1988-01-01

    An analysis of an extended molecular dynamics calculation of the surface potential (SP) of the water liquid-vapor interface is presented. The SP predicted by the TIP4P model is -(130 + or - 50) mV. This value is of reasonable magnitude but of opposite sign to the expectations based on laboratory experiments. The electrostatic potential shows a nonmonotonic variation with depth into the liquid.

  10. Increasing Awareness of Sustainable Water Management for Future Civil Engineers

    Science.gov (United States)

    Ilic, Suzana; Karleusa, Barbara; Deluka-Tibljas, Aleksandra

    2010-05-01

    There are more than 1.2 billion people around the world that do not have access to drinking water. While there are plans under the United Nations Millennium Development Goals to halve this number by 2015, there are a number of regions that will be exposed to water scarcity in the coming future. Providing sufficient water for future development is a great challenge for planners and designers of water supply systems. In order to design sustainable water supplies for the future, it is important to learn how people consume water and how water consumption can be reduced. The education of future civil engineers should take into account not only technical aspects of the water supply but also the accompanying social and economical issues, and appreciated the strengths and weaknesses of traditional solutions. The Faculty of Civil Engineering, at the University of Rijeka, has begun incorporating a series of activities that engage undergraduate students and the local community to develop a mutual understanding of the future needs for sustainable management. We present one of the activities, collaboration with the Lancaster Environment Centre at Lancaster University in the UK through the field course Water and environmental management in Mediterranean context. The course, which is designed for the Lancaster University geography students, features a combination of field trips and visits to provide an understanding of the socio-economic and environmental context of water management in two counties (Istra and Primorsko-Goranska). Students from Lancaster visit the Croatian water authority and a regional water company, where they learn about current management practices and problems in managing water supplies and demand through the year. They make their own observations of current management practices in the field and learn about water consumption from the end users. One day field visit to a village in the area that is still not connected to the main water supply system is

  11. Corporatization of the water sector: Implications for transitioning to sustainable urban water management

    DEFF Research Database (Denmark)

    Fratini, Chiara; Elle, Morten; Brown, Norman R.

    2012-01-01

    In the context of climate change, the Danish water sector is experiencing two major pressures. On one hand, a number of agents are pushing towards more sustainable urban water management (SUWM) approaches with the aim of improving surface water quality and mitigating flood risk. On the other hand...

  12. An Integrated Assessment of Investments towards Global Water Sustainability

    Directory of Open Access Journals (Sweden)

    Andrea M. Bassi

    2010-10-01

    Full Text Available To date there has been limited research on integrated water resource management, specifically regarding investments, from a global perspective, largely due to the complexity of the problem and to generally local water management practices. Water demand and supply are very often affected by international factors and with global climate change, population growth and increasing consumption, water management is now more than ever a global issue. This paper gives an overview of current and impending water problems while assessing investment needs for integrated water management as a possible solution to projected water challenges. The analysis compares a business as usual case (BAU to a scenario in which investments improve water efficiency use across sectors to curb demand, increase innovative supply from desalination and enhance conventional water resources management measures. System dynamics modeling is employed to represent the structural factors influencing water demand and supply in the context of an integrated framework including cross-sectoral linkages. The analysis confirms that sustainable water management is feasible, but it requires investments in the range of $145 billion per year between 2011 and 2050 (0.16% of GDP or $17/person/year and timely, effective action.

  13. Liquid marble and water droplet interactions and stability.

    Science.gov (United States)

    Ueno, Kazuyuki; Bournival, Ghislain; Wanless, Erica J; Nakayama, Saori; Giakoumatos, Emma C; Nakamura, Yoshinobu; Fujii, Syuji

    2015-10-21

    The interactions between two individual water droplets were investigated in air using a combination of coalescence rig and high speed video camera. This combination allows the visualization of droplet coalescence dynamics with millisecond resolution which provides information on droplet stability. Bare water droplets coalesced rapidly upon contact, while droplet stability was achieved by coating the droplets with polystyrene particles carrying pH-responsive poly[2-(diethylamino)ethyl methacrylate] hairs (PDEA-PS particles) to form liquid marbles. The asymmetric interaction of a water droplet (pH 3 or 10) armoured with the PDEA-PS particles (liquid marble) with a bare droplet at pH 3 exhibited intermediate stability with coalescence observed following an induction time. The induction time was longer for the pH 10 liquid marble, where the PDEA-PS particles have a hydrophobic surface, than in the case of a pH 3 liquid marble, where the PDEA-PS particles have a hydrophilic surface. Furthermore, film formation of PDEA-PS particles on the liquid marble surface with toluene vapour confirmed capsule formation which prevented coalescence with the neighbouring water droplet instead wetting the capsule upon contact within 3 milliseconds. This study illuminates the stability of individual particle-stabilized droplets and has potential impact on processes and formulations which involve their interaction.

  14. Sustainable water use and management options in a water-stressed river basin in Kenya

    Science.gov (United States)

    Hirpa, Feyera; Dadson, Simon; Dyer, Ellen; Barbour, Emily; Charles, Katrina; Hope, Robert

    2017-04-01

    Sustainable water resource is critical for maintaining healthy ecosystems and supporting socio-economic sectors. Hydro-climatic change and variability, population growth as well as new infrastructure developments create water security risks. Therefore, evidence-based management decisions are necessary to improve water security and meet the future water demands of multiple competing sectors. In this work we perform water resource modelling in order to investigate the impact of increasing water demand (expanding agriculture, booming industry, growing population) on the sustainable water use in Turkwel river basin, located in arid north-western Kenya. We test different management options to determine those that meet the water demands of the concerned sectors whilst minimising environmental impact. We perform scenario analysis using Water Evaluation And Planning (WEAP) model to explore different ranges of climate conditions, population growth rates, irrigation scale, reservoir operations, and economic development. The results can be used as a scientific guideline for the policy makers who decide the alternative management options that ensure the sustainable water use in the basin. The work is part of the REACH - improving water security for the poor program (http://reachwater.org.uk/), aiming to support a pathway to sustainable growth and poverty reduction

  15. Water Phase Diagram Is Significantly Altered by Imidazolium Ionic Liquid

    DEFF Research Database (Denmark)

    Chaban, V. V.; Prezhdo, O. V.

    2014-01-01

    We report unusually large changes in the boiling temperature, saturated vapor pressure, and structure of the liquid-vapor interface for a range of 1-butyl-3-methyl tetrafluoroborate, [C4C1IM][BF4]-water mixtures. Even modest molar fractions of [C4C1IM][BF4] significantly affect the phase behavior...... of water, as represented, for instance, by strong negative deviations from Raoult's law, extending far beyond the standard descriptions. The investigation was carried out using classical molecular dynamics employing a specifically refined force field. The changes in the liquid-vapor interface and saturated...

  16. Structural Origin of Shear Viscosity of Liquid Water.

    Science.gov (United States)

    Yamaguchi, Tsuyoshi

    2018-01-25

    The relation between the microscopic structure and shear viscosity of liquid water was analyzed by calculating the cross-correlation between the shear stress and the two-body density using the molecular dynamics simulation. The slow viscoelastic relaxation that dominates the steady-state shear viscosity was ascribed to the destruction of the hydrogen-bonding network structure along the compression axis of the shear distortion, which resembles the structural change under isotropic hydrostatic compression. It means that the shear viscosity of liquid water reflects the anisotropic destruction-formation dynamics of the hydrogen-bonding network.

  17. Ternary liquid-liquid equilibria measurement for epoxidized soybean oil + acetic acid + water.

    Science.gov (United States)

    Cai, Shuang-Fei; Wang, Li-Sheng; Yan, Guo-Qing; Li, Yi; Feng, Yun-Xia; Linghu, Rong-Gang

    2012-01-01

    Liquid-liquid equilibria (LLE) data were measured for ternary system epoxidized soybean oil (ESO) + acetic acid + water at 313.15, 323.15 and 333.15 K, respectively. The consistency of the measured LLE data was tested, using Othmer-Tobias correlation and root-mean-square deviation (sigma) in mass fraction of water in the lower phase and average value of the absolute difference (AAD) between experimental mass fraction of epoxidized soybean oil in the upper phase and that calculated using Othmer-Tobias correlation.

  18. Sustainable urban water management: understanding and fostering champions of change.

    Science.gov (United States)

    Taylor, A C

    2009-01-01

    This paper highlights and discusses ten characteristic attributes of emergent leaders (also known as 'champions') who worked as influential change agents within publicly managed, Australian water agencies to encourage more sustainable forms of urban water management. These attributes relate to: the 'openness to experience' personality characteristic; career mobility and work history demographics; personal and position power; strategic social networks; the culture of their organisations; and five distinguishing leadership behaviours (e.g. persisting under adversity). Guided by the findings of an international literature review, the author conducted a multiple case study involving six water agencies. This research identified attributes of these leaders that were typically strong and/or distinguishing compared to relevant control groups, as well as influential contextual factors. While it is widely acknowledged that these leaders play a critical role in the delivery of sustainable urban water management, there has been a paucity of context-sensitive research involving them. The research project highlighted in this paper is a response to this situation and has led to the development of a suite of 39 practical, evidence-based strategies to build leadership capacity throughout water agencies. Such capacity is one of the elements needed to drive the transition to more 'water sensitive cities'.

  19. Solid−liquid critical behavior of water in nanopores

    Science.gov (United States)

    Mochizuki, Kenji; Koga, Kenichiro

    2015-01-01

    Nanoconfined liquid water can transform into low-dimensional ices whose crystalline structures are dissimilar to any bulk ices and whose melting point may significantly rise with reducing the pore size, as revealed by computer simulation and confirmed by experiment. One of the intriguing, and as yet unresolved, questions concerns the observation that the liquid water may transform into a low-dimensional ice either via a first-order phase change or without any discontinuity in thermodynamic and dynamic properties, which suggests the existence of solid−liquid critical points in this class of nanoconfined systems. Here we explore the phase behavior of a model of water in carbon nanotubes in the temperature−pressure−diameter space by molecular dynamics simulation and provide unambiguous evidence to support solid−liquid critical phenomena of nanoconfined water. Solid−liquid first-order phase boundaries are determined by tracing spontaneous phase separation at various temperatures. All of the boundaries eventually cease to exist at the critical points and there appear loci of response function maxima, or the Widom lines, extending to the supercritical region. The finite-size scaling analysis of the density distribution supports the presence of both first-order and continuous phase changes between solid and liquid. At around the Widom line, there are microscopic domains of two phases, and continuous solid−liquid phase changes occur in such a way that the domains of one phase grow and those of the other evanesce as the thermodynamic state departs from the Widom line. PMID:26100904

  20. Enabling sustainable urban water management through governance experimentation.

    Science.gov (United States)

    Bos, J J; Brown, R R; Farrelly, M A; de Haan, F J

    2013-01-01

    A shift towards sustainable urban water management is widely advocated but poorly understood. There is a growing body of literature claiming that social learning is of high importance in restructuring conventional systems. In particular, governance experimentation, which explicitly aims for social learning, has been suggested as an approach for enabling the translation of sustainability ideas into practice. This type of experimentation requires a very different dynamic within societal relations and necessitates a changed role for professionals engaged in such a process. This empirically focused paper investigates a contemporary governance experiment, the Cooks River Sustainability Initiative, and determines its outcome in terms of enabling social learning for attaining sustainable water practice in an urban catchment. Drawing on the qualitative insights of the actors directly involved in this novel process, this paper provides evidence of changes in individual and collective understanding generated through diverse forms of social interaction. Furthermore, the research reveals perceived key-factors that foster and/or hamper the execution of this new form of experimentation, including project complexity, resource intensity and leadership. Overall, this paper highlights that, while implementation of governance experimentation in a conventional setting can be highly challenging, it can also be highly rewarding in terms of learning.

  1. A water management decision support system contributing to sustainability

    Science.gov (United States)

    Horváth, Klaudia; van Esch, Bart; Baayen, Jorn; Pothof, Ivo; Talsma, Jan; van Heeringen, Klaas-Jan

    2017-04-01

    Deltares and Eindhoven University of Technology are developing a new decision support system (DSS) for regional water authorities. In order to maintain water levels in the Dutch polder system, water should be drained and pumped out from the polders to the sea. The time and amount of pumping depends on the current sea level, the water level in the polder, the weather forecast and the electricity price forecast and possibly local renewable power production. This is a multivariable optimisation problem, where the goal is to keep the water level in the polder within certain bounds. By optimizing the operation of the pumps the energy usage and costs can be reduced, hence the operation of the regional water authorities can be more sustainable, while also anticipating on increasing share of renewables in the energy mix in a cost-effective way. The decision support system, based on Delft-FEWS as operational data-integration platform, is running an optimization model built in RTC-Tools 2, which is performing real-time optimization in order to calculate the pumping strategy. It is taking into account the present and future circumstances. As being the core of the real time decision support system, RTC-Tools 2 fulfils the key requirements to a DSS: it is fast, robust and always finds the optimal solution. These properties are associated with convex optimization. In such problems the global optimum can always be found. The challenge in the development is to maintain the convex formulation of all the non-linear components in the system, i.e. open channels, hydraulic structures, and pumps. The system is introduced through 4 pilot projects, one of which is a pilot of the Dutch Water Authority Rivierenland. This is a typical Dutch polder system: several polders are drained to the main water system, the Linge. The water from the Linge can be released to the main rivers that are subject to tidal fluctuations. In case of low tide, water can be released via the gates. In case of high

  2. ISSUES ON THE ROLE OF EFFICIENT WATER PRICING FOR SUSTAINABLE WATER MANAGEMENT

    Directory of Open Access Journals (Sweden)

    Simona FRONE

    2012-06-01

    Full Text Available This paper aims to highlight some of the main issues raised by developing and implementing the most appropriate approach to water pricing, and to induce a sustainable water management. Therefore, we define the concept and utility of water demand management as one objective of efficient water pricing. Next we analyse the basic economics and some important theoretical insights of water pricing. We further with state the main four inter-correlated principles of sustainable water pricing (full-cost recovery, economic efficiency,equity and administrative feasability and the trends and challenges of their actual implementing in the water pricing policy of Romania and other EU countries. We end with a review of opinions, personal conclusions and recommendations on the actual opportunity, effectiveness and role of efficient water pricing in fulfilling the goals of sustainabilty.

  3. Liquid-Liquid equilibria of the water-acetic acid-butyl acetate system

    Directory of Open Access Journals (Sweden)

    Ince E.

    2002-01-01

    Full Text Available Experimental liquid-liquid equilibria of the water-acetic acid-butyl acetate system were studied at temperatures of 298.15± 0.20, 303.15± 0.20 and 308.15± 0.20 K. Complete phase diagrams were obtained by determining solubility and tie-line data. The reliability of the experimental tie-line data was ascertained by using the Othmer and Tobias correlation. The UNIFAC group contribution method was used to predict the observed ternary liquid-liquid equilibrium (LLE data. It was found that UNIFAC group interaction parameters used for LLE did not provide a good prediction. Distribution coefficients and separation factors were evaluated for the immiscibility region.

  4. Chloride reduction from brackish water by hollow fiber supported liquid membranes (HFSLM) using ionic liquids as a carrier

    OpenAIRE

    Hofmeister, Markus; Slusarek, Tobias; Madaj, Rafal; Strömbäck, William

    2013-01-01

    The project “Chloride reduction from brackish water by hollow fiber supported liquid membranes (HFSLM) using ionic liquids as a carrier “ is about developing an alternative and cost effective solution for the Abrera drinking water treatment plant to desalinate water from Llobregat river while accomplishing drinking water standards. With a constant increase of the world's population, the demand for drinking water also increases. However, the supply of drinking water is limited, so desalination...

  5. Achieving Sustainable Development Goals from a Water Perspective

    Directory of Open Access Journals (Sweden)

    Anik Bhaduri

    2016-10-01

    Full Text Available Efforts to meet human water needs only at local scales may cause negative environmental externality and stress on the water system at regional and global scales. Hence, assessing SDG targets requires a broad and in-depth knowledge of the global to local dynamics of water availability and use. Further, Interconnection and trade-offs between different SDG targets may lead to sub-optimal or even adverse outcome if the set of actions are not properly pre-designed considering such interlinkages. Thus scientific research and evidence have a role to play in facilitating the implementation of SDGs through assessments and policy engagement from global to local scales. The paper addresses some of these challenges related to implementation and monitoring the targets of the Sustainable Development Goals from a water perspective, based on the key findings of a conference organised in 2015 with the focus on three essential aspects of SDGs- indicators, interlinkages and implementation. The paper discusses that indicators should not be too simple but ultimately deliver sustainability measures. The paper finds that remote sensing and earth observation technologies can play a key role in supporting the monitoring of water targets. It also recognises that implementing SDGs is a societal process of development, and there is need to link how SDGs relate to public benefits and communicate this to the broader public.

  6. Realising sustainable urban water management: can social theory help?

    Science.gov (United States)

    Bos, J J; Brown, R R

    2013-01-01

    It has been acknowledged, in Australia and beyond, that existing urban water systems and management lead to unsustainable outcomes. Therefore, our current socio-technical systems, consisting of institutions, structures and rules, which guide traditional urban water practices, need to change. If a change towards sustainable urban water management (SUWM) practices is to occur, a transformation of our established social-technical configuration that shapes the behaviour and decision making of actors is needed. While some constructive innovations that support this transformation have occurred, most innovations remain of a technical nature. These innovative projects do not manage to achieve the widespread social and institutional change needed for further diffusion and uptake of SUWM practices. Social theory, and its research, is increasingly being recognised as important in responding to the challenges associated with evolving to a more sustainable form of urban water management. This paper integrates three areas of social theories around change in order to provide a conceptual framework that can assist with socio-technical system change. This framework can be utilised by urban water practitioners in the design of interventions to stimulate transitions towards SUWM.

  7. Indigenous Practices of Water Management for Sustainable Services

    Directory of Open Access Journals (Sweden)

    Beshah M. Behailu

    2016-12-01

    Full Text Available This article explores the possibility of incorporating traditional water management experiences into modern water management. After the literature review, two case studies are presented from Borana and Konso communities in southern Ethiopia. The study was conducted through interviews, discussions, and observations. The two cases were selected due to their long existence. Both communities have their own water source types, depending on local hydrogeological conditions. Borana is known for the so-called Ella (wells and Konso for Harta (ponds, which have been managed for more than five centuries. All government and development partners strive to achieve sustainable services in water supply and sanitation. Therefore, they design various management packages to engage the communities and keep the systems sustainable. However, the management components are often designed with little attention to local customs and traditions. The cases in the two communities show that traditional knowledge is largely ignored when replaced by modern one. However, the concepts of cost recovery, ownership experience, equity, enforcement, integrity, and unity, which are highly pronounced in modern systems, can also be found in the traditional water managements of Borana and Konso. Naturally, one shoe never fits all. Borana and Konso experiences are working for their own community. This research implies that when we plan a project or a program for a particular community, the starting point should be the indigenous practices and thoughts on life.

  8. Water, job creation, industrial development and the implementation of sustainable development goals in Africa

    CSIR Research Space (South Africa)

    Simalabwi, Alex

    2017-01-01

    Full Text Available and climate change impacts (industrial) development Water is key for societal development- livelihoods, job creation Water Security for sustainable and climate-resilient industrial development towards Africa’s overall societal development Water, Jobs... to affordable, reliable, sustainable and modern energy for all Make cities and human settlements inclusive, safe, resilient and sustainable End poverty in all its forms everywhere Water Energy Land Ensure sustainable consumption and production...

  9. Molecular reorientation of liquid water studied with femtosecond midinfrared spectroscopy

    NARCIS (Netherlands)

    Bakker, H.J.; Rezus, Y.L.A.; Timmer, R.L.A.

    2008-01-01

    The molecular reorientation of liquid water is key to the hydration and stabilization of molecules and ions in aqueous solution. A powerful technique to study this reorientation is to measure the time-dependent anisotropy of the excitation of the O-H/O-D stretch vibration of HDO dissolved in D2O/H2O

  10. The modelled liquid water balance of the Greenland Ice Sheet

    NARCIS (Netherlands)

    Steger, Christian R.; Reijmer, Carleen H.; van den Broeke, Michiel R.

    2017-01-01

    Recent studies indicate that the surface mass balance will dominate the Greenland Ice Sheet's (GrIS) contribution to 21st century sea level rise. Consequently, it is crucial to understand the liquid water balance (LWB) of the ice sheet and its response to increasing surface melt. We therefore

  11. Ultrafast Librational Relaxation of H2O in Liquid Water

    DEFF Research Database (Denmark)

    Petersen, Jakob; Møller, Klaus Braagaard; Rey, Rossend

    2013-01-01

    The ultrafast librational (hindered rotational) relaxation of a rotationally excited H2O molecule in pure liquid water is investigated by means of classical nonequilibrium molecular dynamics simulations and a power and work analysis. This analysis allows the mechanism of the energy transfer from...

  12. Modeling of liquid/liquid separation by pervaporation: Toluene from water

    NARCIS (Netherlands)

    Meuleman, E.E.B.; Meuleman, Erik E.B.; Bosch, Bert; Mulder, M.H.V.; Strathmann, H.

    1999-01-01

    The resistances-in-series model, the modified solution-diffusion model, the Flory-Rehner theory, and the film theory were used to calculate the diffusion coefficients of two components of a liquid-feed mixture that are separated by pervaporation. The toluene and water fluxes through EPDM membranes

  13. Bulawayo water supplies: Sustainable alternatives for the next decade

    Science.gov (United States)

    Mkandla, Noel; Van der Zaag, Pieter; Sibanda, Peter

    contemplated, namely drawing groundwater from Umguza, part of the Nyamandlovu aquifer. The paper then provides details of the Umguza alternative, which was designed at pre-feasibility level by Mkandla [Mkandla, N., 2003. Bulawayo water supplies: Umguza well field as a sustainable alternative for the next decade. Unpublished M.Sc. WREM dissertation. University of Zimbabwe, Harare]. All alternative additional water supply sources were compared in terms of their Net Present Values. It was found that Umguza well field is the least-cost alternative to meet additional water demand. The Umguza alternative will be able to satisfy water demand for a period of six to ten years. Thereafter, the second least-cost alternative, namely Gwayi Shangani dam, must be on stream.

  14. APPLICATION OF THE UNIFAC MODEL TO LIQUID-LIQUID EQUILIBRIA OF WATER-PROPIONIC ACID-SOLVENT TERNARIES*

    Directory of Open Access Journals (Sweden)

    Süheyla ÇEHRELİ

    2003-01-01

    Full Text Available The liquid-liquid equilibria of Water-Propionic Acid-Benzyl Alcohol, Water-Propionic Acid-Benzyl Acetate and Water-Propionic Acid-Dibenzyl Ether ternary systems were predicted by means of UNIFAC Model. For this purpose, multivariable Newton-Raphson convergence procedure was used. Experimental and model results were compared.

  15. Forest Management Challenges for Sustaining Water Resources in the Anthropocene

    Directory of Open Access Journals (Sweden)

    Ge Sun

    2016-03-01

    Full Text Available The Earth has entered the Anthropocene epoch that is dominated by humans who demand unprecedented quantities of goods and services from forests. The science of forest hydrology and watershed management generated during the past century provides a basic understanding of relationships among forests and water and offers management principles that maximize the benefits of forests for people while sustaining watershed ecosystems. However, the rapid pace of changes in climate, disturbance regimes, invasive species, human population growth, and land use expected in the 21st century is likely to create substantial challenges for watershed management that may require new approaches, models, and best management practices. These challenges are likely to be complex and large scale, involving a combination of direct and indirect biophysical watershed responses, as well as socioeconomic impacts and feedbacks. We discuss the complex relationships between forests and water in a rapidly changing environment, examine the trade-offs and conflicts between water and other resources, and propose new management approaches for sustaining water resources in the Anthropocene.

  16. Using Case Studies to Teach Interdisciplinary Water Resource Sustainability

    Science.gov (United States)

    Orr, C. H.; Tillotson, K.

    2012-12-01

    Teaching about water resources and often emphasizes the biophysical sciences to understand highly complex hydrologic, ecologic and engineering systems, yet most impediments to improving management emerge from social processes. Challenges to more sustainable management often result from trade-offs among stakeholders (e.g., ecosystem services, energy, municipal use, and agriculture) and occur while allocating resources to competing goals of economic development, social equity, and efficient governance. Competing interests operating across multiple scales can increase tensions and prevent collaborative resolution of resource management problems. Here we discuss using specific, place-based cases to teach the interdisciplinary context of water management. Using a case approach allows instructors to first explore the geologic and hydrologic setting of a specific problem to let students understand where water comes from, then how it is used by people and ecosystems, and finally what conflicts arise from mismatches between water quality, quantity, timing, human demand, and ecosystem needs. The case approach helps students focus on specific problem to understand how the landscape influences water availability, without needing to first learn everything about the relevant fields. We look at geology, hydrology and climate in specific watersheds before addressing the human and ecosystem aspects of the broader, integrated system. This gives students the context to understand what limits water availability and how a water budget constrains possible solutions to sustainability problems. It also mimics the approach we have taken in research addressing these problems. In an example case the Spokane Coeur D'Alene basin, spanning the border between SE Washington and NW Idaho, includes a sole source aquifer system with high exchange between surface water and a highly conductive aquifer. The Spokane River does not meet water quality standards and is likely to face climate driven shifts

  17. Measurement of Radiation Damage of Water-based Liquid Scintillator and Liquid Scintillator

    CERN Document Server

    Bignell, Lindsey J; Hans, Sunej; Jaffe, David E; Rosero, Richard; Vigdor, Steven; Viren, Brett; Worcester, Elizabeth; Yeh, Minfang; Zhang, Chao

    2015-01-01

    Liquid scintillating phantoms have been proposed as a means to perform real-time 3D dosimetry for proton therapy treatment plan verification. We have studied what effect radiation damage to the scintillator will have upon this application. We have performed measurements of the degradation of the light yield and optical attenuation length of liquid scintillator and water-based liquid scintillator after irradiation by 201 MeV proton beams that deposited doses of approximately 52 Gy, 300 Gy, and 800 Gy in the scintillator. Liquid scintillator and water-based liquid scintillator (composed of $5\\%$ scintillating phase) exhibit light yield reductions of $1.74 \\pm 0.55 \\%$ and $1.31 \\pm 0.59 \\%$ after $\\approx$ 800 Gy of proton dose, respectively. Whilst some increased optical attenuation was observed in the irradiated samples, the measured reduction to the light yield is also due to damage to the scintillation light production. Based on our results and conservative estimates of the expected dose in a clinical conte...

  18. GEOINFORMATION-CARTOGRAPHIC MODELING OF WATER AVAILABILITY FOR WATER SECURITY AND SUSTAINABLE DEVELOPMENT OF TERRITORIES

    Directory of Open Access Journals (Sweden)

    I. D. Rybkina

    2016-01-01

    Full Text Available The study of problem associated with water availability and its mapping is due to the need to solve urgent water problems of the Russian regions for their sustainable development. At the same time, sustainability is understood as rational use of water resources and their conservation to maintain the ecological balance of territories, and water security of regions is evaluated from the standpoint of water supply to municipalities. The shortage of water resources in Russia is perceived skeptically since our country is rich in water resources and the scarcity of fresh water threatens only a small part of its territory. However, the experts consider [Danilov-Danilyan, Galfan, 2015] that such a myopic point of view can lead in the long term to emergencies. The potential danger and risk of water use are already typical for the areas, which experience water stress. These are the territories with extremely low water availability per capita, less than 1.0-2.0 thousand m3/person/year [Shiklomanov, 2000; Danilov-Danilyan, Losev, 2006]. Geoinformation-cartographic modeling allows to differentiate the area under study according to water resource potential, to identify municipalities with low water availability and to estimate the population living in the area of potential danger and risk of water use.

  19. Numerical studies on the separation performance of liquid- liquid Hydrocyclone for higher water-cut wells

    Science.gov (United States)

    Osei, H.; Al-Kayiem, H. H.; Hashim, F. M.

    2015-12-01

    Liquid-liquid hydrocyclones have nowadays become very useful in the oil industry because of their numerous applications. They can be installed downhole in the case of a well that produces higher water-oil ratios. The design of a liquid-liquid hydrocyclone for such a task is critical and every geometric part of the hydrocyclone has a part to play as far as separation is concerned. This work, through validated numerical technique, investigated the liquid-liquid hydrocyclone performance for the cases of single-inlet and dual-inlets, with different upper cylindrical lengths, specifically, 30mm and 60mm.It was observed that the hydrocyclones with the 30mm upper cylindrical section perform better than the ones with 60 mm upper cylindrical section. It was again noted that, even though higher number of tangential inlets increases the swirl intensity, they have the tendency to break up the oil droplets within the hydrocyclone because of increasing shear and jet flow interaction.

  20. Measurement of liquid-liquid equilibria for condensate + glycol and condensate + glycol + water systems

    DEFF Research Database (Denmark)

    Riaz, Muhammad; Kontogeorgis, Georgios; Stenby, Erling Halfdan

    2011-01-01

    Today's oil and gas production requires the application of various chemicals in large amounts. To evaluate the effects of those chemicals on the environment, it is of crucial importance to know how much of the chemicals are discharged via produced water and how much is dissolved in the crude oil....... The ultimate objective of this work is to develop a predictive thermodynamic model for the mutual solubility of oil, water, and polar chemicals. But for the development and validation of the model, experimental data are required. This work presents new experimental liquid-liquid equilibrium (LLE) data for 1......,2-ethanediol (MEG) + condensate and MEG + water + condensate systems at temperatures from (275 to 323) K at atmospheric pressure. The condensate used in this work is a stabilized natural gas condensate from an offshore field in the North Sea. Compositional analysis of the natural gas condensate was carried out...

  1. Drag crisis moderation by thin air layers sustained on superhydrophobic spheres falling in water

    KAUST Repository

    Jetly, Aditya

    2018-01-22

    We investigate the effect of thin air layers naturally sustained on superhydrophobic surfaces on the terminal velocity and drag force of metallic spheres free falling in water. The surface of 20 mm to 60 mm steel or tungsten-carbide spheres is rendered superhydrophobic by a simple coating process that uses commercially available hydrophobic agent. By comparing the free fall of unmodified spheres and superhydrophobic spheres in a 2.5 meters tall water tank, It is demonstrated that even a very thin air layer (~ 1 – 2 μm) that covers the freshly dipped superhydrophobic sphere, can reduce the drag force on the spheres by up to 80 %, at Reynolds numbers 105 - 3×105 , owing to an early drag crisis transition. This study complements prior investigations on the drag reduction efficiency of model gas layers sustained on heated metal spheres falling in liquid by the Leidenfrost effect. The drag reduction effects are expected to have significant implication for the development of sustainable air-layer-based energy saving technologies.

  2. Entropy of liquid water from ab initio molecular dynamics.

    Science.gov (United States)

    Zhang, Cui; Spanu, Leonardo; Galli, Giulia

    2011-12-08

    We have computed the entropy of liquid water using a two-phase thermodynamic model and trajectories generated by ab initio molecular dynamics simulations. We present the results obtained with semilocal, hybrid, and van der Waals density functionals. We show that in all cases, at the experimental equilibrium density and at temperatures in the vicinity of 300 K, the computed entropies are underestimated, with respect to experiment, and the liquid exhibits a degree of tetrahedral order higher than in experiments. The underestimate is more severe for the PBE and PBE0 functionals than for several van der Waals functionals. © 2011 American Chemical Society

  3. Liquid - liquid equilibria of the water + butyric acid + decanol ternary system

    Directory of Open Access Journals (Sweden)

    S.I. Kirbaslar

    2006-09-01

    Full Text Available Liquid-liquid equilibrium (LLE data for the water + butyric acid + decanol ternary system were determined experimentally at temperatures of 298.15, 308.15 and 318.15 K. Complete phase diagrams were obtained by determining the solubility curve and the tie lines. The reliability of the experimental tie line data was confirmed with the Othmer-Tobias correlation. The UNIFAC method was used to predict the phase equilibrium of the system using the interaction parameters for groups CH3, CH2, COOH, OH and H2O determined experimentally. Distribution coefficients and separation factors were evaluated for the immiscibility region.

  4. Towards sustainable urban water governance in Denmark: collective building of capabilities in local authorities

    OpenAIRE

    Nielsen, Susanne Balslev; Jensen, Marina Bergen

    2016-01-01

    To address the climate adaptation of cities, today’s water managers need more than technical skills to drive sustainable urban water projects, which also stimulate demand for post-graduate education so that professionalisation of integrated sustainable water management in the public sector can be achieved. The ‘urban water platform’ was tested and is hereby presented as a course concept for building collective capabilities for integrated sustainable water design among local authorities in Den...

  5. Economic sustainability, water security and multi-level governance of local water schemes in Nepal

    Directory of Open Access Journals (Sweden)

    Emma Hakala

    2017-07-01

    Full Text Available This article explores the role of multi-level governance and power structures in local water security through a case study of the Nawalparasi district in Nepal. It focuses on economic sustainability as a measure to address water security, placing this thematic in the context of a complicated power structure consisting of local, district and national administration as well as external development cooperation actors. The study aims to find out whether efforts to improve the economic sustainability of water schemes have contributed to water security at the local level. In addition, it will consider the interactions between water security, power structures and local equality and justice. The research builds upon survey data from the Nepalese districts of Nawalparasi and Palpa, and a case study based on interviews and observation in Nawalparasi. The survey was performed in water schemes built within a Finnish development cooperation programme spanning from 1990 to 2004, allowing a consideration of the long-term sustainability of water management projects. This adds a crucial external influence into the intra-state power structures shaping water management in Nepal. The article thus provides an alternative perspective to cross-regional water security through a discussion combining transnational involvement with national and local points of view.

  6. Effect of ionic liquids on (vapor + liquid) equilibrium behavior of (water + 2-methyl-2-propanol)

    Energy Technology Data Exchange (ETDEWEB)

    Zhang Lianzhong; Qiao Bingbang; Ge Yun; Deng Dongshun [College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310014 (China); Ji Jianbing [College of Chemical Engineering and Material Science, Zhejiang University of Technology, Hangzhou 310014 (China)], E-mail: jjb@zjut.edu.cn

    2009-01-15

    Isobaric T, x, y data were reported for ternary systems of {l_brace}water + 2-methyl-2-propanol (tert-butyl alcohol, TBA) + ionic liquid (IL){r_brace} at p = 100 kPa. When the mole fraction of TBA on IL-free basis was fixed at 0.95, measurements were performed at IL mass fractions from 0.6 down to 0.05, in a way of repeated synthesis. The vapor-phase compositions were obtained by analytical methods and the liquid-phase compositions were calculated with the aid of mass balances. Activity coefficients of water and TBA were obtained without the need of a thermodynamic model of the liquid-phase. Six ILs, composed of an anion chosen from [OAc]{sup -} or [Cl]{sup -}, and a cation from [emim]{sup +}, or [bmim]{sup +}, or [hmim]{sup +}, were studied. Relative volatility and activity coefficients were presented in relation with the IL mole fraction, showing the effect of the ILs on a molar basis. The effect of the ILs on relative volatility of TBA to water was depicted by the effect of anions and cations on, respectively, the activity coefficients of water and TBA. The results indicated that, among the six ILs studied, [emim][Cl] has the most significant effect on enhancement of the relative volatility, which reaches a value of 7.2 at an IL mass fraction of 0.58. Another IL, [emim][OAc], has also significant effect, with an appreciable value of 5.2 for the relative volatility when the IL mass fraction is 0.6. Considering the relatively low viscosity and melting point of [emim][OAc], it might be a favorable candidate as solvent for the separation of water and TBA by extractive distillation. Simultaneous correlation by the NRTL model was presented for both systems of (water + ethanol + IL) and (water + TBA + IL), using consistent binary parameters for water and IL.

  7. Polyelectrolyte microcapsules for sustained delivery of water-soluble drugs

    Energy Technology Data Exchange (ETDEWEB)

    Anandhakumar, S.; Debapriya, M. [Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012 (India); Nagaraja, V. [Department of Microbiology and Cell Biology, Indian Institute of Science, Bangalore, 560012 (India); Raichur, Ashok M., E-mail: amr@materials.iisc.ernet.in [Department of Materials Engineering, Indian Institute of Science, Bangalore, 560012 (India)

    2011-03-12

    Polyelectrolyte capsules composed of weak polyelectrolytes are introduced as a simple and efficient system for spontaneous encapsulation of low molecular weight water-soluble drugs. Polyelectrolyte capsules were prepared by layer-by-layer (LbL) assembling of weak polyelectrolytes, poly(allylamine hydrochloride) (PAH) and poly(methacrylic acid) (PMA) on polystyrene sulfonate (PSS) doped CaCO{sub 3} particles followed by core removal with ethylene-diaminetetraacetic acid (EDTA). The loading process was observed by confocal laser scanning microscopy (CLSM) using tetramethylrhodamineisothiocyanate labeled dextran (TRITC-dextran) as a fluorescent probe. The intensity of fluorescent probe inside the capsule decreased with increase in cross-linking time. Ciprofloxacin hydrochloride (a model water-soluble drug) was spontaneously deposited into PAH/PMA capsules and their morphological changes were investigated by scanning electron microscopy (SEM) and atomic force microscopy (AFM). The quantitative study of drug loading was also elucidated which showed that drug loading increased with initial drug concentration, but decreased with increase in pH. The loaded drug was released in a sustained manner for 6 h, which could be further extended by cross-linking the capsule wall. The released drug showed significant antibacterial activity against E. coli. These findings indicate that such capsules can be potential carriers for water-soluble drugs in sustained/controlled drug delivery applications.

  8. Fast-switching chiral nematic liquid-crystal mode with polymer-sustained twisted vertical alignment

    Science.gov (United States)

    Chang, Kai-Han; Joshi, Vinay; Chien, Liang-Chy

    2017-04-01

    We demonstrate a fast-switching liquid-crystal mode with polymer-sustained twisted vertical alignment. By optimizing the polymerization condition, a polymer microstructure with controlled orientation is produced. The polymer microstructure not only synergistically suppresses the optical bounce during field-induced homeotropic-twist transition but also shortens the response time significantly. Theoretical analyses validate that the ground state free energy density is modified by the aligning field of the polymer microstructure, which affects the driving voltage of the device. The outcomes of this paper will enable the development of fast-switching and achromatic electro-optical and photonic devices.

  9. A quantitative account of quantum effects in liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Fanourgakis, Georgios S.; Schenter, Gregory K.; Xantheas, Sotiris S.

    2006-10-14

    We report quantum statistical mechanical simulations of liquid water with the TTM2.1-F flexible, polarizable interaction potential for water. The potential is the first representation of the molecular interaction that reproduces the converged Born-Oppenheimer potential energy surface obtained from systematically improvable electronic structure analysis of binding energies of water clusters. Proper quantum statistical simulation of properties allows for a quantitative account of the magnitude of quantum effects in liquid water. We report path integral quantum dynamical simulations of total length of 600 ps with a 0.05 fs time step for a periodic system of 256 molecules. The representation of the quantum effects was achieved using up to 32 replicas per atom. These allow for a quantitative description of the broadening of the radial distribution functions and the corresponding energy shifts in the heat of vaporization. Our best estimate for the enthalpy of the liquid from the results of the quantum simulations is in the range 10.4 ? 10.6 kcal/mol, in agreement with the experimental value of 10.51 kcal/mol. 1Battelle operates PNNL for the USDOE

  10. Water resource management for sustainable agriculture in Punjab, India.

    Science.gov (United States)

    Aggarwal, Rajan; Kaushal, Mohinder; Kaur, Samanpreet; Farmaha, Bhupinder

    2009-01-01

    The state of Punjab comprising 1.5% area of the country has been contributing 40-50% rice and 60-65% wheat to the central pool since last three decades. During last 35 years The area under foodgrains has increased from 39,200 sq km ha to 63,400 sq km and the production of rice and wheat has increased from 0.18 to 0.32 kg/m2 and 0.22 to 0.43 kg/m2 respectively. This change in cropping pattern has increased irrigation water requirement tremendously and the irrigated area has increased from 71 to 95% in the state. Also the number of tube wells has increased from 0.192 to 1.165 million in the last 35 years. The excessive indiscriminate exploitation of ground water has created a declining water table situation in the state. The problem is most critical in central Punjab. The average rate of decline over the last few years has been 55 cm per year. The worst affected districts are Moga, Sangrur, Nawanshahar, Ludhiana and Jalandhar. This has resulted in extra power consumption, affects the socio-economic conditions of the small farmers, destroy the ecological balance and adversely affect the sustainable agricultural production and economy of the state. Therefore, in this paper attempt has been made to analyse the problem of declining water table, possible factors responsible for this and suggest suitable strategies for arresting declining water table for sustainable agriculture in Punjab. The strategies include shift of cropping pattern, delay in paddy transplantation, precision irrigation and rainwater harvesting for artificial groundwater recharge.

  11. Measuring the Sustainability of Water Plans in Inter-Regional Spanish River Basins

    Directory of Open Access Journals (Sweden)

    María M. Borrego-Marín

    2016-08-01

    Full Text Available This paper analyses and compares the sustainability of the water plans in the Spanish River basins according to the objectives of the Water Framework Directive. Even though the concept of sustainability has been traditionally associated with the triple bottom line framework, composed of economic, environmental, and social dimensions, in this paper sustainability has been enlarged by including governance aspects. Two multicriteria decision analysis approaches are proposed to aggregate the sustainability dimensions. Results show that the environmental dimension plays the most important role in the whole sustainability (40% of water basins, followed by both economic and social criteria (25%. By contrast, the dimension of governance is the least important for sustainability (11%. A classification of the Spanish basins according to their sustainability indicates that the water agency with the highest sustainability is Western Cantabrian, followed by Eastern Cantabrian and Tagus. By contrast, Minho-Sil, Jucar, and Douro are the least sustainable.

  12. Virtual Water and Water Footprints: Overreaching Into the Discourse on Sustainability, Efficiency, and Equity

    Directory of Open Access Journals (Sweden)

    Dennis Wichelns

    2015-10-01

    Full Text Available The notions of virtual water and water footprints were introduced originally to bring attention to the large amounts of water required to produce crops and livestock. Recently, several authors have begun applying those notions in efforts to describe efficiency, equity, and the sustainability of resources and production activities. In this paper, I describe why the notions of virtual water and water footprints are not appropriate for analysing issues pertaining to those topics. Both notions lack a supporting conceptual framework and they contain too little information to enhance understanding of important policy issues. Neither notion accounts for the opportunity cost or scarcity value of water in any setting, or the impacts of water availability and use on livelihoods. In addition, countries trade in goods and services – not in crop and livestock water requirements. Thus, the notions of virtual water and water footprints cannot provide helpful insight regarding the sustainability of water use, economic efficiency, or social equity. Gaining such insight requires the application of legitimate conceptual frameworks, representing a broad range of perspectives from the physical and social sciences, with due consideration of dynamics, uncertainty, and the impacts of policy choices on livelihoods and natural resources.

  13. Looking for the rainbow on exoplanets covered by liquid and icy water clouds

    OpenAIRE

    Karalidi, T.; Stam, D.M.; Hovenier, J.W.

    2012-01-01

    Aims. Looking for the primary rainbow in starlight that is reflected by exoplanets appears to be a promising method to search for liquid water clouds in exoplanetary atmospheres. Ice water clouds, that consist of water crystals instead of water droplets, could potentially mask the rainbow feature in the planetary signal by covering liquid water clouds. Here, we investigate the strength of the rainbow feature for exoplanets that have liquid and icy water clouds in their atmosphere, and calcula...

  14. Water, climate change, and sustainability in the southwest

    Science.gov (United States)

    2010-01-01

    The current Southwest drought is exceptional for its high temperatures and arguably the most severe in history. Coincidentally, there has been an increase in forest and woodland mortality due to fires and pathogenic outbreaks. Although the high temperatures and aridity are consistent with projected impacts of greenhouse warming, it is unclear whether the drought can be attributed to increased greenhouse gasses or is a product of natural climatic variability. Climate models indicate that the 21st century will be increasingly arid and droughts more severe and prolonged. Forest and woodland mortality due to fires and pathogens will increase. Demography and food security dictate that water demand in the Southwest will remain appreciable. If projected population growth is twinned with suburb-centered development, domestic demands will intensify. Meeting domestic demands through transference from agriculture presents concerns for rural sustainability and food security. Environmental concerns will limit additional transference from rivers. It is unlikely that traditional supply-side solutions such as more dams will securely meet demands at current per-capita levels. Significant savings in domestic usage can be realized through decreased applications of potable water to landscaping, but this is a small fraction of total regional water use, which is dominated by agriculture. Technical innovations, policy measures, and market-based solutions that increase supply and decrease water demand are all needed. Meeting 21st-century sustainability challenges in the Southwest will also require planning, cooperation, and integration that surpass 20th-century efforts in terms of geographic scope, jurisdictional breadth, multisectoral engagement, and the length of planning timelines. PMID:21149704

  15. Binary, ternary and quaternary liquid-liquid equilibria in 1-butanol, oleic acid, water and n-heptane mixtures

    NARCIS (Netherlands)

    Winkelman, J. G. M.; Kraai, G. N.; Heeres, H. J.

    2009-01-01

    This work reports on liquid-liquid equilibria in the system 1-butanol, oleic acid, water and n-heptane used for biphasic, lipase catalysed esterifications. The literature was studied on the mutual solubility in binary systems of water and each of the organic components. Experimental results were

  16. Development of sustainable coal to liquid processes: Minimising process CO2 emissions

    Directory of Open Access Journals (Sweden)

    S. Kauchali

    2017-12-01

    Full Text Available Traditional coal-to-liquid (CTL plants are synonymous with the production of carbon dioxide. Coal may be gasified in the presence of steam and oxygen to produce gas comprising carbon dioxide (CO2, carbon monoxide (CO, methane (CH4, hydrogen (H2 and steam (H2O. The gases can be reacted to a myriad of chemicals and fuels via the Fischer-Tropsch (FT reaction. However, excess carbon dioxide is generated via the Water-Gas-Shift reaction during preparation of CO:H2 ratios for FT. Here, a process development is represented on a CHO phase diagram, where unique regions are identified for autothermal operations for coal conversion. Considerations are given to develop idealised processes for the production of liquid chemicals from coal which emit minimal process CO2, require minimal energy input and do not require steam. This is achieved by co-feeding coal with methane and identifying endothermic-exothermic process pairs for methane-coal dry reforming. Furthermore, it is shown that a preferred method to produce liquid fuels from coal is by first creating dimethyl ether (DME as an intermediate, followed by the dehydration of DME to liquid fuels (gasoline range. For this route, via DME, the CO2 emission was found to be four times less than idealised CTL processes. Keywords: Gasification, Reforming, Coal to liquid, Carbon dioxide, Autothermal, Fischer tropsch

  17. Water Quality, Mitigation Measures of Arsenic Contamination and Sustainable Rural Water Supply Options in Bangladesh

    Directory of Open Access Journals (Sweden)

    HOSSAIN M. ANAWAR

    2012-06-01

    Full Text Available Arsenic contamination of groundwater has created a serious public health issue in Bangladesh and West Bengal (India, because groundwater is widely used for drinking, household and agriculture purposes. Given the magnitude of the problem of groundwater contamination facing Bangladesh, effective, acceptable and sustainable solutions are urgently required. Different NGOs (Non-government organizations and research organizations are using their extensive rural networks to raise awareness and conduct pilot projects. The implication of the results from the previous studies is robust, but coastly arsenic reduction technologies such as activated alumina technology, and As and Fe removal filters may find little social acceptance, unless heavily subsidized. This review paper analysed the quality of surface water and ground water, all mitigation measures and the most acceptable options to provide sustainable access to safe- water supply in the rural ares of Bangladesh. Although there are abundant and different sources of surface water, they can not be used for drinking and hosehold purposes due to lack of sanitation, high faecal coliform concentration, turibidity and deterioration of quality of surface water sources. There are a few safe surface water options; and also there are several methods available for removal of arsenic and iron from groundwater in large conventional treatments plants. This review paper presented a short description of the currently available and most sustainable technologies for arsenic and iron removal, and alternative water supply options in the rural areas.

  18. Thermally driven electrokinetic energy conversion with liquid water microjets

    Science.gov (United States)

    Lam, Royce K.; Gamlieli, Zach; Harris, Stephen J.; Saykally, Richard J.

    2015-11-01

    A goal of current energy research is to design systems and devices that can efficiently exploit waste heat and utilize solar or geothermal heat energy for electrical power generation. We demonstrate a novel technique exploiting water's large coefficient of thermal expansion, wherein modest thermal gradients produce the requisite high pressure for driving fast-flowing liquid water microjets, which can effect the direct conversion of the kinetic energy into electricity and gaseous hydrogen. Waste heat in thermoelectric generating plants and combustion engines, as well as solar and geothermal energy could be used to drive these systems.

  19. Sustainable energy development and water supply security in Kamojang Geothermal Field: The Energy-Water Nexus

    Science.gov (United States)

    Sofyan, Y.; Nishijima, J.; Fujimitsu, Y.

    2014-12-01

    The Kamojang Geothermal Field (KGF) is a typical vapor dominated hydrothermal system in West Java, Indonesia. This geothermal field is the oldest exploited geothermal field in Indonesia. From 1983 to 2005, more than 160 million tons of steam have been exploited from the KGF and more than 30 million tons of water were injected into the reservoir system. The injected water come from condensed water, local river and ground water. Sustainable production in the geothermal energy development is the ability of the production system applied to sustain the stable production level over long times and to manage the mass balance between production, injection and natural recharge in the geothermal reservoir during exploitation. Mass balance in the reservoir system can be monitored by using time lapse gravity monitoring. Mass variation of hydrodynamic in the reservoir of KGF from 1999 to 2005 is about -3.34 Mt/year while is about -3.78 Mt/year from 1999 to 2008. Another period between 2009 and 2010, mass variation decreased about -8.24 Mt. According to the history of production and injection, natural recharge to the KGF's reservoir is estimated at about 2.77 Mt/year from 1999 to 2005 and 2.75 Mt/year from 1999 to 2008. Between 2009 and 2010, KGF has a bigger mass deficiency rate throughout 200 MWe maintain production. Large amount of fresh water is needed for sustainable geothermal energy production, while the domestic water supply need is also increased. Natural recharge, about 50% of injected water, cooling system, drilling and other production activities in KGF spend large amounts of fresh water. Water consumption for local people around KGF is about 1.46 MT/year. The water volume around KGF of total runoff is the range between dry season 0.07 MT/month and rainy season 4.4 MT/month. The water demands for sustainable geothermal production of KGF and for local people's consumption will increase in the future. Integrated planning between the energy and water sectors in KGF

  20. Diversification of the resources of the Parisian water network : contribution to sustainable management of water resources

    OpenAIRE

    Trinh, Bich-Thuy

    2017-01-01

    At the scale of a city, a sustainable water management raises questions about the links between uses and resources: what water quality is needed for what purpose? The Parisian context is a favourable ground for conducting such type of reflection thanks to the existence of a non-potable water network (RENP) dating from the late nineteenth century. The network is currently supplied by summarily filtrated water from the Seine river (20%) and the canal de l’Ourcql (80%). It is mainly used for mun...

  1. Sustainable Poly(Ionic Liquids) for CO2 Capture Based on Deep Eutectic Monomers

    KAUST Repository

    Isik, Mehmet

    2016-10-05

    The design of high performance solid sorbent materials for CO2 capture is a technology which has been employed to mitigate global warming. However, the covalent incorporation of functionalities into polymeric supports usually involves multistep energy-intensive chemical processes. This fact makes the net CO2 balance of the materials negative even though they possess good properties as CO2 sorbents. Here we show a new family of polymers which are based on amines, amidoximes, and natural carboxylic acids and can be obtained using sustainable low energy processes. Thus, deep eutectic monomers based on natural carboxylic acids, amidoximes, and amines have been prepared by just mixing with cholinium type methacrylic ammonium monomer. The formation of deep eutectic monomers was confirmed by differential scanning calorimetry measurements. In all cases, the monomers displayed glass transition temperatures well below room temperature. Computational studies revealed that the formation of eutectic complexes lengthens the distance between the cation and the anion causing charge delocalization. The liquid nature of the resulting deep eutectic monomers (DEMs) made it possible to conduct a fast photopolymerization process to obtain the corresponding poly(ionic liquids). Materials were characterized by means of nuclear magnetic resonance, differential scanning calorimetry, thermogravimetric analysis, and X-ray diffraction to evaluate the properties of the polymers. The polymers were then used as solid sorbents for CO2 capture. It has been shown that the polymers prepared with citric acid displayed better performance both experimentally and computationally. The current endeavor showed that sustainable poly(ionic liquids) based on deep eutectic monomers can be easily prepared to produce low-energy-cost alternatives to the materials currently being researched for CO2 capture. © 2016 American Chemical Society.

  2. Deficit irrigation and sustainable water-resource strategies in agriculture for China's food security

    National Research Council Canada - National Science Library

    Du, Taisheng; Kang, Shaozhong; Zhang, Jianhua; Davies, William J

    2015-01-01

    .... For future global food security, water use in agriculture must become sustainable. Agricultural water-use efficiency and water productivity can be improved at different points from the stomatal to the regional scale...

  3. The Cross-fertilization between the Sustainable Development Goals and International Water Law

    NARCIS (Netherlands)

    Spijkers, O.

    2016-01-01

    Are the main principles of international water law, as reflected in the Watercourses Convention, sufficiently equipped to motivate States to sustainably manage their freshwater resources? This article suggests that a more pronounced sustainable approach to these principles is desirable. The

  4. Performance of Water-Based Liquid Scintillator: An Independent Analysis

    Directory of Open Access Journals (Sweden)

    D. Beznosko

    2014-01-01

    Full Text Available The water-based liquid scintillator (WbLS is a new material currently under development. It is based on the idea of dissolving the organic scintillator in water using special surfactants. This material strives to achieve the novel detection techniques by combining the Cerenkov rings and scintillation light, as well as the total cost reduction compared to pure liquid scintillator (LS. The independent light yield measurement analysis for the light yield measurements using three different proton beam energies (210 MeV, 475 MeV, and 2000 MeV for water, two different WbLS formulations (0.4% and 0.99%, and pure LS conducted at Brookhaven National Laboratory, USA, is presented. The results show that a goal of ~100 optical photons/MeV, indicated by the simulation to be an optimal light yield for observing both the Cerenkov ring and the scintillation light from the proton decay in a large water detector, has been achieved.

  5. Improvements in crop water productivity increase water sustainability and food security—a global analysis

    Science.gov (United States)

    Brauman, Kate A.; Siebert, Stefan; Foley, Jonathan A.

    2013-06-01

    Irrigation consumes more water than any other human activity, and thus the challenges of water sustainability and food security are closely linked. To evaluate how water resources are used for food production, we examined global patterns of water productivity—food produced (kcal) per unit of water (l) consumed. We document considerable variability in crop water productivity globally, not only across different climatic zones but also within climatic zones. The least water productive systems are disproportionate freshwater consumers. On precipitation-limited croplands, we found that ∼40% of water consumption goes to production of just 20% of food calories. Because in many cases crop water productivity is well below optimal levels, in many cases farmers have substantial opportunities to improve water productivity. To demonstrate the potential impact of management interventions, we calculated that raising crop water productivity in precipitation-limited regions to the 20th percentile of productivity would increase annual production on rainfed cropland by enough to provide food for an estimated 110 million people, and water consumption on irrigated cropland would be reduced enough to meet the annual domestic water demands of nearly 1.4 billion people.

  6. Light Water Reactor Sustainability Program Integrated Program Plan

    Energy Technology Data Exchange (ETDEWEB)

    Kathryn McCarthy; Jeremy Busby; Bruce Hallbert; Shannon Bragg-Sitton; Curtis Smith; Cathy Barnard

    2013-04-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

  7. Light Water Reactor Sustainability Program Integrated Program Plan

    Energy Technology Data Exchange (ETDEWEB)

    McCarthy, Kathryn A. [Idaho National Lab. (INL), Idaho Falls, ID (United States); Busby, Jeremy [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Hallbert, Bruce [Idaho National Lab. (INL), Idaho Falls, ID (United States); Bragg-Sitton, Shannon [Idaho National Lab. (INL), Idaho Falls, ID (United States); Smith, Curtis [Idaho National Lab. (INL), Idaho Falls, ID (United States); Barnard, Cathy [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2014-04-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline—even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy’s Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration’s energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans.

  8. Light Water Reactor Sustainability Program Integrated Program Plan

    Energy Technology Data Exchange (ETDEWEB)

    George Griffith; Robert Youngblood; Jeremy Busby; Bruce Hallbert; Cathy Barnard; Kathryn McCarthy

    2012-01-01

    Nuclear power has safely, reliably, and economically contributed almost 20% of electrical generation in the United States over the past two decades. It remains the single largest contributor (more than 70%) of non-greenhouse-gas-emitting electric power generation in the United States. Domestic demand for electrical energy is expected to experience a 31% growth from 2009 to 2035. At the same time, most of the currently operating nuclear power plants will begin reaching the end of their initial 20-year extension to their original 40-year operating license for a total of 60 years of operation. Figure E-1 shows projected nuclear energy contribution to the domestic generating capacity. If current operating nuclear power plants do not operate beyond 60 years, the total fraction of generated electrical energy from nuclear power will begin to decline - even with the expected addition of new nuclear generating capacity. The oldest commercial plants in the United States reached their 40th anniversary in 2009. The U.S. Department of Energy Office of Nuclear Energy's Research and Development Roadmap (Nuclear Energy Roadmap) organizes its activities around four objectives that ensure nuclear energy remains a compelling and viable energy option for the United States. The four objectives are as follows: (1) develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors; (2) develop improvements in the affordability of new reactors to enable nuclear energy to help meet the Administration's energy security and climate change goals; (3) develop sustainable nuclear fuel cycles; and (4) understand and minimize the risks of nuclear proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program's plans.

  9. Solar water heating for aquaculture : optimizing design for sustainability

    Energy Technology Data Exchange (ETDEWEB)

    McDonald, M.; Thwaites, J. [Taylor Munro Energy Systems Inc., Delta, BC (Canada)

    2003-08-01

    This paper presents the results of a solar water heating project at Redfish Ranch, the first Tilapia tropical fish farm in British Columbia. The fish are raised in land-based tanks, eliminating the risk of contamination of local ecosystems. As a tropical species, they requires warm water. Natural gas or propane boilers are typically used to maintain tank temperatures at 26 to 28 degrees C. Redfish Ranch uses solar energy to add heat to the fish tanks, thereby reducing fossil-fuel combustion and greenhouse gas emissions. This unique building-integrated solar system is improving the environmental status of of this progressive industrial operation by offsetting fossil-fuel consumption. The system was relatively low cost, although substantial changes had to be made to the roof of the main building. The building-integrated design of the solar water heating system has reduced operating costs, generated local employment, and shows promise of future activity. As such, it satisfies the main criteria for sustainability. 7 refs.

  10. Water Information as a Tool to Enhance Sustainable Water Management—The Australian Experience

    Directory of Open Access Journals (Sweden)

    James Horne

    2015-05-01

    Full Text Available Many countries and regions have struggled to put in place adequate water information systems to assist with sustainable water management. This article describes and assesses the key components of Australia’s water information and data systems, with particular reference to rural and regional Australia, focusing on progress with strengthening these systems at a national level since 2007. Through the early part of the period, much of Australia was experiencing a crisis in water availability. The article concludes with ongoing challenges for Australia and lessons from the Australian experience for other countries embarking on upgrading their water information and data systems. Upgrading a nation’s water information systems is a long-term task, but an important one in a world of climate change and increased climate variability. Substantial progress is likely to take five to 10 years to materialize. From the outset, upgrading information systems needs to be focused on data series that will facilitate answering key policy questions, assist water users in making significant decisions more effectively, and allow businesses and government to better address risks from water-related events. As always, political support matters. To sustain investments in information, its coverage must facilitate illuminating key questions and issues. Custodians of information systems must ensure that the value proposition is clear to all.

  11. A New Framework for Assessing the Sustainability Reporting Disclosure of Water Utilities

    Directory of Open Access Journals (Sweden)

    Silvia Cantele

    2018-02-01

    Full Text Available Sustainability reporting is becoming more and more widespread among companies aiming at disclosing their contribution to sustainable development and gaining legitimacy from stakeholders. This is more significant for firms operating in a public services’ context and mainly when supplying a fundamental public resource, like water utilities. While the literature on sustainability reporting in the water sector is scant, there is an increasing need to study the usefulness and quality of its sustainability disclosures to adequately inform the stakeholders about the activities of water utilities to protect this fundamental resource and general sustainable development. This article presents a novel assessment framework based on a scoring technique and an empirical analysis on the sustainability reports of Italian water utilities carried out through it. The results highlight a low level of disclosure on the sustainability indicators suggested by the main sustainability reporting guidelines (Global Reporting Initiative, (GRI, and Sustainability Accounting Standard Board, (SASB; most companies tend to disclose only qualitative information and fail to inform about some material aspects of water management, such as water recycled, network resilience, water sources, and effluent quality. These findings indicate that sustainability reporting is mainly considered as a communication tool, rather than a performance measurement and an accountability tool, but also suggest the need for a new and international industry-specific sustainability reporting standard.

  12. Water for Survival, Water for Pleasure – A Biopolitical Perspective on the Social Sustainability of the Basic Water Agenda

    Directory of Open Access Journals (Sweden)

    Sofie Hellberg

    2017-02-01

    Full Text Available This article explores the social sustainability of the basic water agenda. It does so through a biopolitical analysis of water narratives from eThekwini municipality, South Africa, where a policy of Free Basic Water (FBW has been implemented. The article addresses the question of what water 'is' and 'does' and shows that water and water governance are productive of lifestyles, people’s self-understanding and how they view their place in the social hierarchy. The analysis brings to light that a differentiated management system, that provides different levels of water services to different populations and individuals, becomes part of (reproducing social hierarchies and deepens divisions between communities. Based on these findings, the article argues that while the basic water agenda has brought successful results globally and remains important in terms of guaranteeing health and survival for the most vulnerable, it should not be confused with efforts of social sustainability. Social sustainability would not only involve a situation where basic needs are met but would also have to address effects of water systems on the relationships between individuals and populations in society.

  13. Light Water Reactor Sustainability Program: Integrated Program Plan

    Energy Technology Data Exchange (ETDEWEB)

    None, None

    2017-05-01

    proliferation and terrorism. The Light Water Reactor Sustainability (LWRS) Program is the primary programmatic activity that addresses Objective 1. This document summarizes the LWRS Program’s plans. For the LWRS Program, sustainability is defined as the ability to maintain safe and economic operation of the existing fleet of nuclear power plants for a longer-than-initially-licensed lifetime. It has two facets with respect to long-term operations: (1) manage the aging of plant systems, structures, and components so that nuclear power plant lifetimes can be extended and the plants can continue to operate safely, efficiently, and economically; and (2) provide science-based solutions to the industry to implement technology to exceed the performance of the current labor-intensive business model.

  14. A "First Principles" Potential Energy Surface for Liquid Water from VRT Spectroscopy of Water Clusters

    Energy Technology Data Exchange (ETDEWEB)

    Goldman, N; Leforestier, C; Saykally, R J

    2004-05-25

    We present results of gas phase cluster and liquid water simulations from the recently determined VRT(ASP-W)III water dimer potential energy surface. VRT(ASP-W)III is shown to not only be a model of high ''spectroscopic'' accuracy for the water dimer, but also makes accurate predictions of vibrational ground-state properties for clusters up through the hexamer. Results of ambient liquid water simulations from VRT(ASP-W)III are compared to those from ab initio Molecular Dynamics, other potentials of ''spectroscopic'' accuracy, and to experiment. The results herein represent the first time that a ''spectroscopic'' potential surface is able to correctly model condensed phase properties of water.

  15. Sustainable Water and Agricultural Land Use in the Guanting Watershed under Limited Water Resources

    Science.gov (United States)

    Wechsung, F.; Möhring, J.; Otto, I. M.; Wang, X.; Guanting Project Team

    2012-04-01

    The Yongding River System is an important water source for the northeastern Chinese provinces Shanxi, Hebei, Beijing, and Tianjin. The Guanting Reservoir within this river system is one of the major water sources for Beijing, which is about 70 km away. Original planning assumed a discharge of 44 m3/s for the reservoir, but the current mean discharge rate is only about 5 m3/s; there is often hardly any discharge at all. Water scarcity is a major threat for the socio-economic development of the area. The situation is additionally aggravated by climate change impacts. Typical upstream-downstream conflicts with respect to water quantity and quality requests are mixed up with conflicts between different sectors, mainly mining, industry, and agriculture. These conflicts can be observed on different administrative levels, for example between the provinces, down to households. The German-Chinese research project "Sustainable water and agricultural land use in the Guanting Watershed under limited water resources" investigates problems and solutions related to water scarcity in the Guanting Catchment. The aim of the project is to create a vulnerability study in order to assess options for (and finally achieve) sustainable water and land use management in the Guanting region. This includes a comprehensive characterization of the current state by gap analysis and identification of pressures and impacts. The presentation gives an overview of recent project results regarding regionalization of global change scenarios and specification for water supply, evaluation of surface water quantity balances (supply-demand), evaluation of the surface water quality balances (emissions-impact thresholds), and exploration of integrative measurement planning. The first results show that climate in the area is becoming warmer and drier which leads to even more dramatically shrinking water resources. Water supply is expected to be reduced between one and two thirds. Water demand might be

  16. Closing of water circuits – a global benchmark on sustainable water management

    Directory of Open Access Journals (Sweden)

    Fröhlich Siegmund

    2017-01-01

    Full Text Available Access to clean water resources has always been a crucial factor in the history of mankind. Now, in the 21st century, water, as an increasingly scarce resource, will take a strategic role for the future development of global populations. As the former UN Secretary General Dr. Dr. Boutrous Boutrous Ghali predicts: “The wars of the 21st century will be fought not over oil, they will be fought over water.” [1]. In nine global examples will be demonstrated the different ways of dealing with water resources. That are: Mexico City, Egypt, Libya, DOW Terneuzen, Los Angeles, Israel, China and Singapore and also global trends, such as, scarcity & rural exodus and salinization of soil. Thereby, he explains the different kinds of water management to be observed. The most relevant prognosis of the WHO is, that to the end of 21st century Africa's population will grow over proportionally from 1 billion now up to nearly 4 billion [9]. That is why all efforts need to be concentrated on helping Africa create a sustainable economic development. The first and by far most important strategic step is to assure access to clean water resources in the rural and mostly arid regions of the continent. The lecturer shows several technological proposals on how to overcame problems like: water scarcity, rural exodus, salinization of soil and others. Such technologies could be successfully implemented in sustainable development programs in African countries.

  17. Closing of water circuits - a global benchmark on sustainable water management

    Science.gov (United States)

    Fröhlich, Siegmund

    2017-11-01

    Access to clean water resources has always been a crucial factor in the history of mankind. Now, in the 21st century, water, as an increasingly scarce resource, will take a strategic role for the future development of global populations. As the former UN Secretary General Dr. Dr. Boutrous Boutrous Ghali predicts: "The wars of the 21st century will be fought not over oil, they will be fought over water." [1]. In nine global examples will be demonstrated the different ways of dealing with water resources. That are: Mexico City, Egypt, Libya, DOW Terneuzen, Los Angeles, Israel, China and Singapore and also global trends, such as, scarcity & rural exodus and salinization of soil. Thereby, he explains the different kinds of water management to be observed. The most relevant prognosis of the WHO is, that to the end of 21st century Africa's population will grow over proportionally from 1 billion now up to nearly 4 billion [9]. That is why all efforts need to be concentrated on helping Africa create a sustainable economic development. The first and by far most important strategic step is to assure access to clean water resources in the rural and mostly arid regions of the continent. The lecturer shows several technological proposals on how to overcame problems like: water scarcity, rural exodus, salinization of soil and others. Such technologies could be successfully implemented in sustainable development programs in African countries.

  18. Interfacial thermodynamics of water and six other liquid solvents.

    Science.gov (United States)

    Pascal, Tod A; Goddard, William A

    2014-06-05

    We examine the thermodynamics of the liquid-vapor interface by direct calculation of the surface entropy, enthalpy, and free energy from extensive molecular dynamics simulations using the two-phase thermodynamics (2PT) method. Results for water, acetonitrile, cyclohexane, dimethyl sulfoxide, hexanol, N-methyl acetamide, and toluene are presented. We validate our approach by predicting the interfacial surface tensions (IFT--excess surface free energy per unit area) in excellent agreement with the mechanical calculations using Kirkwood-Buff theory. Additionally, we evaluate the temperature dependence of the IFT of water as described by the TIP4P/2005, SPC/Ew, TIP3P, and mW classical water models. We find that the TIP4P/2005 and SPC/Ew water models do a reasonable job of describing the interfacial thermodynamics; however, the TIP3P and mW are quite poor. We find that the underprediction of the experimental IFT at 298 K by these water models results from understructured surface molecules whose binding energies are too weak. Finally, we performed depth profiles of the interfacial thermodynamics which revealed long tails that extend far into what would be considered bulk from standard Gibbs theory. In fact, we find a nonmonotonic interfacial free energy profile for water, a unique feature that could have important consequences for the absorption of ions and other small molecules.

  19. The boson peak of deeply cooled confined water reveals the existence of a low-temperature liquid-liquid crossover

    Science.gov (United States)

    Cupane, Antonio; Fomina, Margarita; Schirò, Giorgio

    2014-11-01

    The Boson peak of deeply cooled water confined in the pores of a silica xerogel is studied by inelastic neutron scattering at different hydration levels to separate the contributions from matrix, water on the pore surfaces and "internal" water. Our results reveal that at high hydration level, where the contribution from internal water is dominant, the temperature dependence of the Boson peak intensity shows an inflection point at about 225 K. The complementary use of differential scanning calorimetry to describe the thermodynamics of the system allows identifying the inflection point as the signature of a water liquid-liquid crossover.

  20. An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale

    Energy Technology Data Exchange (ETDEWEB)

    Matthew Bruff; Ned Godshall; Karen Evans

    2011-04-30

    This Final Scientific/ Technical Report submitted with respect to Project DE-FE0000833 titled 'An Integrated Water Treatment Technology Solution for Sustainable Water Resource Management in the Marcellus Shale' in support of final reporting requirements. This final report contains a compilation of previous reports with the most current data in order to produce one final complete document. The goal of this research was to provide an integrated approach aimed at addressing the increasing water resource challenges between natural gas production and other water stakeholders in shale gas basins. The objective was to demonstrate that the AltelaRain{reg_sign} technology could be successfully deployed in the Marcellus Shale Basin to treat frac flow-back water. That objective has been successfully met.

  1. Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials

    Science.gov (United States)

    Takada, Akihiko; Kadokawa, Jun-ichi

    2015-01-01

    A review of the fabrication of polysaccharide ion gels with ionic liquids is presented. From various polysaccharides, the corresponding ion gels were fabricated through the dissolution with ionic liquids. As ionic liquids, in the most cases, 1-butyl-3-methylimidazolium chloride has been used, whereas 1-allyl-3methylimidazolium acetate was specifically used for chitin. The resulting ion gels have been characterized by suitable analytical measurements. Characterization of a pregel state by viscoelastic measurement provided the molecular weight information. Furthermore, the polysaccharide ion gels have been converted into value-added sustainable materials by appropriate procedures, such as exchange with other disperse media and regeneration. PMID:25793912

  2. Fabrication and Characterization of Polysaccharide Ion Gels with Ionic Liquids and Their Further Conversion into Value-Added Sustainable Materials

    Directory of Open Access Journals (Sweden)

    Akihiko Takada

    2015-03-01

    Full Text Available A review of the fabrication of polysaccharide ion gels with ionic liquids is presented. From various polysaccharides, the corresponding ion gels were fabricated through the dissolution with ionic liquids. As ionic liquids, in the most cases, 1-butyl-3-methylimidazolium chloride has been used, whereas 1-allyl-3methylimidazolium acetate was specifically used for chitin. The resulting ion gels have been characterized by suitable analytical measurements. Characterization of a pregel state by viscoelastic measurement provided the molecular weight information. Furthermore, the polysaccharide ion gels have been converted into value-added sustainable materials by appropriate procedures, such as exchange with other disperse media and regeneration.

  3. Liquid water and ices: understanding the structure and physical properties

    Energy Technology Data Exchange (ETDEWEB)

    Malenkov, George [AN Frumkin Institute of Physical Chemistry and Electrochemistry, Leninskii Prospect, 31 119991, Moscow (Russian Federation)], E-mail: egor38@mail.ru

    2009-07-15

    A review of the structure and some properties of condensed phases of water is given. Since the discovery of the polymorphism of crystalline ice (beginning of the twentieth century), 15 ice modifications have been found and their structures have been determined. If we do not take into consideration proton ordering or disordering, nine distinct crystalline ice modifications in which water molecules retain their individuality are known. In the tenth, ice X, there are no H{sub 2}O molecules. It contains ions (or atoms) of oxygen and hydrogen. The structure of all these modifications is described and information about their fields of stability and about the transition between them is given. It is emphasized that there are ice modifications which are metastable at any temperature and pressure (ices Ic, IV and XII), and many modifications can exist as metastable phases beyond their fields of stability. The ability of water to exist in metastable states is one of its remarkable properties. Several amorphous ice modifications (all of them are metastable) are known. Brief information about their properties and transitions between them is given. At the end of the 1960s the conception of the water structure as a three-dimensional hydrogen-bonded network was conclusively formed. Discovery of the polymorphism of amorphous ices awakened interest in the heterogeneity of the water network. Structural and dynamical heterogeneity of liquid water is discussed in detail. Computer simulation showed that the diffusion coefficient of water molecules in dense regions of the network is lower than in the loose regions, while an increase of density of the entire network gives rise to an increase of diffusion coefficient. This finding contradicts the conceptions associated with the primitive two-state models and can be explained from pressure dependences of melting temperature and of homogeneous nucleation temperature. A brief discussion of the picture of molecular motions in liquid water

  4. Simultaneous Design of Ionic Liquids and Azeotropic Separation for Systems Containing Water

    DEFF Research Database (Denmark)

    Roughton, Brock; Camarda, Kyle V.; Gani, Rafiqul

    interaction parameters were fitted for the newly defined ionic liquid groups. The ionic liquid UNIFAC model was used to predict vapor-liquid equilibria for several aqueous azeotropic systems. The ionic liquids were evaluated for use as an entrainer for water in binary azeotropic mixtures where the mole....... Since a large number of azeotropes encountered include water as one of the compounds, the use of ionic liquids in solvent-based separation of water in azeotropic systems has been investigated. Along with the design of the ionic liquid being used to entrain water, the extractive distillation process has...... to check for consistency. The ionic liquid UNIFAC model was developed for a selected set of ionic liquid cations and anions. Group volume and area parameters were calculated using a three step procedure. First, the rules of Bondi were used for any applicable molecular groups within the cation or anion...

  5. Carbon Sequestration through Sustainably Sourced Algal Fertilizer: Deep Ocean Water.

    Science.gov (United States)

    Sherman, M. T.

    2014-12-01

    Drawing down carbon from the atmosphere happens in the oceans when marine plants are growing due to the use of carbon dioxide for biological processes and by raising the pH of the water. Macro- and microscopic marine photosynthesizers are limited in their growth by the availability of light and nutrients (nitrogen, phosphorous, iron, etc.) Deep ocean water (DOW), oceanic water from bellow about 1000m, is a natural medium for marine algae, which contains all (except in rare circumstances) necessary components for algal growth and represents over 90% of the volume of the ocean. The introduction of DOW to a tropical or summer sea can increase chlorophyll from near zero to 60 mg per M3 or more. The form of the utilization infrastructure for DOW can roughly be divided into two effective types; the unconstrained release and the open pond system. Unconstrained release has the advantage of having relatively low infrastructure investment and is available to any area of the ocean. The open pond system has high infrastructure costs but enables intensive use of DOW for harvesting macro- and microalgae and sustainable mariculture. It also enables greater concomitant production of DOW's other potential products such as electricity or potable water. However, unlike an unconstrained release the open pond system can capture much of the biomaterial from the water and limits the impact to the surrounding ecosystem. The Tidal Irrigation and Electrical System (TIESystem), is an open pond that is to be constructed on a continental shelf. It harnesses the tidal flux to pump DOW into the pond on the rising tide and then uses the falling tide to pump biologically rich material out of the pond. This biomaterial represents fixed CO2 and can be used for biofuel or fertilizers. The TIESystem benefits from an economy of scale that increases at a rate that is roughly equal to the relationship of the circumference of a circle (the barrier that creates the open pond) to the area of the pond

  6. Thin Liquid Water Clouds: Their Importance and Our Challenge

    Energy Technology Data Exchange (ETDEWEB)

    Turner, David D.; Vogelmann, A. M.; Austin, Richard T.; Barnard, James C.; Cady-Pereira, Karen; Chiu, C.; Clough, Shepard A.; Flynn, Connor J.; Khaiyer, Mandana M.; Liljegren, James C.; Johnson, Karen L.; Lin, B.; Long, Charles N.; Marshak, A.; Matrosov, S. Y.; McFarlane, Sally A.; Miller, Mark A.; Min, Qilong; Minnis, Patrick; O' Hirok, William; Wang, Zhien; Wiscombe, Warren J.

    2007-02-19

    Many of the clouds important to the Earth’s energy balance, from the tropics to the Arctic, are optically thin and contain liquid water. Longwave and shortwave radiative fluxes are very sensitive to small perturbations of the cloud liquid water path (LWP) when the LWP is small (i.e., <100 gm-2) and, thus, the radiative properties of these clouds must be well understood to capture them correctly in climate models. Here we review the importance of these thin clouds to the Earth’s energy balance, and explain the difficulties in observing them. In particular, because these clouds are optically thin, potentially mixed-phase, and often broken (i.e., have large 3-D variability), it is challenging to retrieve their microphysical properties accurately. We describe a retrieval algorithm intercomparison that was conducted to evaluate the issues involved. Seventeen different algorithms participated and their retrieved LWP, optical depth, and effective radii are evaluated using data from several case studies. Surprisingly, evaluation of the simplest case, a single-layer overcast cloud, revealed that huge discrepancies exist among the various techniques, even among different algorithms that are in the same general classification. This suggests that, despite considerable advances that have occurred in the field, much more work must be done, and we discuss fruitful avenues for future research.

  7. Thermodynamic mechanism of density anomaly of liquid water

    Directory of Open Access Journals (Sweden)

    Makoto eYasutomi

    2015-03-01

    Full Text Available Although density anomaly of liquid water has long been studied by many different authors up to now, it is not still cleared what thermodynamic mechanism induces the anomaly. The thermodynamic properties of substances are determined by interparticle interactions. We analyze what characteristics of pair potential cause the density anomaly on the basis of statistical mechanics and thermodynamics using a thermodynamically self-consistent Ornstein-Zernike approximation (SCOZA. We consider a fluid of spherical particles with a pair potential given by a hard-core repulsion plus a soft-repulsion and an attraction. We show that the density anomaly occurs when the value of the soft-repulsive potential at hard-core contact is in some proper range, and the range depends on the attraction. Further, we show that the behavior of the excess internal energy plays an essential role in the density anomaly and the behavior is mainly determined by the values of the soft-repulsive potential, especially near the hard core contact. Our results show that most of ideas put forward up to now are not the direct causes of the density anomaly of liquid water.

  8. Distribution of binding energies of a water molecule in the water liquid-vapor interface

    Energy Technology Data Exchange (ETDEWEB)

    Chempath, Shaji [Los Alamos National Laboratory; Pratt, Lawrence R [TULANE UNIV

    2008-01-01

    Distributions of binding energies of a water molecule in the water liquid-vapor interface are obtained on the basis of molecular simulation with the SPC/E model of water. These binding energies together with the observed interfacial density profile are used to test a minimally conditioned Gaussian quasi-chemical statistical thermodynamic theory. Binding energy distributions for water molecules in that interfacial region clearly exhibit a composite structure. A minimally conditioned Gaussian quasi-chemical model that is accurate for the free energy of bulk liquid water breaks down for water molecules in the liquid-vapor interfacial region. This breakdown is associated with the fact that this minimally conditioned Gaussian model would be inaccurate for the statistical thermodynamics of a dilute gas. Aggressive conditioning greatly improves the performance of that Gaussian quasi-chemical model. The analogy between the Gaussian quasi-chemical model and dielectric models of hydration free energies suggests that naive dielectric models without the conditioning features of quasi-chemical theory will be unreliable for these interfacial problems. Multi-Gaussian models that address the composite nature of the binding energy distributions observed in the interfacial region might provide a mechanism for correcting dielectric models for practical applications.

  9. Detachment of Liquid-Water Droplets from Gas-Diffusion Layers

    OpenAIRE

    Das, Prodip K.

    2011-01-01

    A critical issue for optimal water management in proton-exchange-membrane fuel cells at lower temperatures is the removal of liquid water from the cell. This pathway is intimately linked with the phenomena of liquid-water droplet removal from surface of the gas-diffusion layer and into the flow channel. Thus, a good understanding of liquid-water transport and droplet growth and detachment from the gas-diffusion layer is critical. In this study, liquid-water droplet growth and detachment on th...

  10. The Energy-Water Nexus: Managing the Links between Energy and Water for a Sustainable Future

    Directory of Open Access Journals (Sweden)

    Karen Hussey

    2012-03-01

    Full Text Available Water and energy are each recognized as indispensable inputs to modern economies. And, in recent years, driven by the three imperatives of security of supply, sustainability, and economic efficiency, the energy and water sectors have undergone rapid reform. However, it is when water and energy rely on each other that the most complex challenges are posed for policymakers. Despite the links and the urgency in both sectors for security of supply, in existing policy frameworks, energy and water policies are developed largely in isolation from one another - a degree of policy fragmentation that is seeing erroneous developments in both sectors. Examples of the trade-offs between energy and water security include: the proliferation of desalination plants and interbasin transfers to deal with water scarcity; extensive groundwater pumping for water supplies; first-generation biofuels; the proliferation of hydropower plants; decentralized water supply solutions such as rainwater tanks; and even some forms of modern irrigation techniques. Drawing on case studies from Australia, Europe, and the United States, this Special Issue attempts to develop a comprehensive understanding of the links between energy and water, to identify where better-integrated policy and management strategies and solutions are needed or available, and to understand where barriers exist to achieve that integration. In this paper we draw out some of the themes emerging from the Special Issue, and, particularly, where insights might be valuable for policymakers, practitioners, and scientists across the many relevant domains.

  11. Ecosystem services, efficiency, sustainability and equity: South Africa's Working for Water Programme

    CSIR Research Space (South Africa)

    Van Wilgen, BW

    1998-09-01

    Full Text Available In this paper, South Africa’s working for water programme is described. The programme maximizes an ecosystem services (the delivery of water), enhances sustainability by eliminating invading alien plants, and promotes social equity through jobs...

  12. A Method to Develop Sustainable Water Management Strategies for an Uncertain Future

    NARCIS (Netherlands)

    Haasnoot, M.; Middelkoop, H.; Beek, E. van; Deursen, W.P.A. van

    2011-01-01

    Development of sustainable water management strategies involves identifi cation of vulnerability and adaptation possibilities, followed by an effect analysis of these adaptation strategies under different possible futures. Recent scenario studies on water management were mainly ‘what-if’

  13. Water Requirements and Sustainable Sources in the Barnett Shale, March 29, 2011

    Science.gov (United States)

    This paper will focus on the water requirements and sustainable sources in the Barnett Shale. Devon Energy Corporation is committed to the principles of water conservation and reuse where feasible in its operations.

  14. Data from Sustainability Base Characterizing Hot Water Pump Differential Pressure Spikes for ACCEPT

    Data.gov (United States)

    National Aeronautics and Space Administration — During the heating season in Sustainability Base, a critical alarm associated with a hot water pump circulating heating water for the radiative system which...

  15. Development of Pre-Service Science Teachers' Awareness of Sustainable Water Use

    Science.gov (United States)

    Cankaya, Cemile; Filik Iscen, Cansu

    2015-01-01

    Water is a vital resource for sustainable development. The aim of this research was to develop and evaluate pre-service science teachers' awareness of sustainable water usage. This research was based on a mixed method. The qualitative part of the research was based on a single group pretest-posttest experimental design, and the qualitative data…

  16. Adaptive exchange of capitals in urban water resources management : an approach to sustainability?

    Science.gov (United States)

    With water availability increasingly restricted by deficiencies in quality and quantity, water resources management is a central issue in planning for sustainability in the Anthropocene. We first offer a definition of sustainability based on the ease with which capitals (e.g., na...

  17. Materials Inventory Database for the Light Water Reactor Sustainability Program

    Energy Technology Data Exchange (ETDEWEB)

    Kazi Ahmed; Shannon M. Bragg-Sitton

    2013-08-01

    Scientific research involves the purchasing, processing, characterization, and fabrication of many sample materials. The history of such materials can become complicated over their lifetime – materials might be cut into pieces or moved to various storage locations, for example. A database with built-in functions to track these kinds of processes facilitates well-organized research. The Material Inventory Database Accounting System (MIDAS) is an easy-to-use tracking and reference system for such items. The Light Water Reactor Sustainability Program (LWRS), which seeks to advance the long-term reliability and productivity of existing nuclear reactors in the United States through multiple research pathways, proposed MIDAS as an efficient way to organize and track all items used in its research. The database software ensures traceability of all items used in research using built-in functions which can emulate actions on tracked items – fabrication, processing, splitting, and more – by performing operations on the data. MIDAS can recover and display the complete history of any item as a simple report. To ensure the database functions suitably for the organization of research, it was developed alongside a specific experiment to test accident tolerant nuclear fuel cladding under the LWRS Advanced Light Water Reactor Nuclear Fuels Pathway. MIDAS kept track of materials used in this experiment from receipt at the laboratory through all processes, test conduct and, ultimately, post-test analysis. By the end of this process, the database proved to be right tool for this program. The database software will help LWRS more efficiently conduct research experiments, from simple characterization tests to in-reactor experiments. Furthermore, MIDAS is a universal tool that any other research team could use to organize their material inventory.

  18. Liquid water content variation with altitude in clouds over Europe

    Science.gov (United States)

    Andreea, Boscornea; Sabina, Stefan

    2013-04-01

    Cloud water content is one of the most fundamental measurements in cloud physics. Knowledge of the vertical variability of cloud microphysical characteristics is important for a variety of reasons. The profile of liquid water content (LWC) partially governs the radiative transfer for cloudy atmospheres, LWC profiles improves our understanding of processes acting to form and maintain cloud systems and may lead to improvements in the representation of clouds in numerical models. Presently, in situ airborne measurements provide the most accurate information about cloud microphysical characteristics. This information can be used for verification of both numerical models and cloud remote sensing techniques. The aim of this paper was to analyze the liquid water content (LWC) measurements in clouds, in time of the aircraft flights. The aircraft and its platform ATMOSLAB - Airborne Laboratory for Environmental Atmospheric Research is property of the National Institute for Aerospace Research "Elie Carafoli" (INCAS), Bucharest, Romania. The airborne laboratory equipped for special research missions is based on a Hawker Beechcraft - King Air C90 GTx aircraft and is equipped with a sensors system CAPS - Cloud, Aerosol and Precipitation Spectrometer (30 bins, 0.51-50 m). The processed and analyzed measurements are acquired during 4 flights from Romania (Bucharest, 44°25'57″N 26°06'14″E) to Germany (Berlin 52°30'2″N 13°23'56″E) above the same region of Europe. The flight path was starting from Bucharest to the western part of Romania above Hungary, Austria at a cruse altitude between 6000-8500 m, and after 5 hours reaching Berlin. In total we acquired data during approximately 20 flight hours and we presented the vertical and horizontal LWC variations for different cloud types. The LWC values are similar for each type of cloud to values from literature. The vertical LWC profiles in the atmosphere measured during takeoff and landing of the aircraft have shown their

  19. A full value-chain Water Footprint Assessment to help informed decision in corporate sustainability strategies

    Science.gov (United States)

    Zhang, Guoping; Chico Zamanilo, Daniel; Bai, Xue; Ren, Xiajing; Chen, Rong; Qin, Jun

    2017-04-01

    This study evaluated the water footprint (WF) of five production facilities along Muyuan Foodstuff Co. Ltd's (Muyuan) value chain, and assessed the sustainability and impact of their water footprints at the river catchment level. Muyuan, a large-scale, integrated pig breeder and producer in China, is keen to fulfil its corporate social responsibilities and committed to ensuring food quality and security, promoting environmental protection, and participating in catchment water resources management. Formulating corporate water related sustainability strategies, however, has been challenging. This study carried out a comprehensive Water Footprint Assessment (WFA) for Muyuan's full value chain to assist in formulating such strategies and setting up action plans with water footprint reduction targets. The study showed that that the water footprint of the supply chain, resulting from crops and crop products used in Muyuan's feed production facility is a major contributor to Muyuan's facilities' water footprint. From the perspective of the direct WF at the facilities, addressing the impact on water quality from effluents (i.e. the grey water footprint) at hog farms is a critical component of any water sustainability strategy. From the blue WF perspective, there are opportunities to reduce blue water consumption at hog farms through improved technology and implementation of best practices. The water footprint sustainability assessment in this study indicated that Muyuan operates in a catchment which is already under water stress and is a hotspot in terms of both blue water scarcity and water pollution level. The study helped identify potential water-related risks and opportunities for improving Muyuan's water use efficiency as well as ways Muyuan could contribute to sustainable water resources management in the catchment within which it operates. This is an innovative application of WFA in the livestock sector and supports the development of Muyuan's corporate water

  20. A framework for planning sustainable seawater desalination water supply.

    Science.gov (United States)

    Shahabi, Maedeh P; McHugh, Adam; Anda, Martin; Ho, Goen

    2017-01-01

    A quantitative framework for sustainable desalination planning in metropolitan areas, which integrates the tools of mixed integer linear programming and life cycle assessment, is presented. The life cycle optimisation framework allows for optimal desalination planning by considering choices over intake type, staging and location of the infrastructure under different land-use, environmental and economic policies. Optimality is defined by the decision maker's selected objective function, being either an environmental impact or a levelised cost indicator. The framework was tested for future desalination planning scenarios in the northern metropolitan area of Perth, Western Australia. Results indicate that multi-staged construction and decentralised planning solutions may produce lower life cycle environmental impacts (58%) and at a lower levelised cost (24%) than a centralised desalination solution currently being considered by Western Australian water planners. Sensitivity analysis results suggest that the better environmental and economic performance of decentralised planning over centralised planning is highly sensitive to the proportion of land that can be made available for the siting of decentralised plants near the demand zone. Insight into land use policies is a critical factor to the initiation and success of decentralised solution in developed metropolitan areas. Copyright © 2016 Elsevier B.V. All rights reserved.

  1. Direct simulation of liquid water dynamics in the gas channel of a polymer electrolyte fuel cell

    NARCIS (Netherlands)

    Qin, C.; Rensink, D.; Hassanizadeh, S.M.; Fell, S.

    2012-01-01

    For better water management in gas channels (GCs) of polymer electrolyte fuel cells (PEFCs), a profound understanding of the liquid water dynamics is needed. In this study, we propose a novel geometrical setup to conduct a series of direct simulations of the liquid water dynamics in a GC. The

  2. Towards sustainable urban water governance in Denmark: collective building of capabilities in local authorities

    DEFF Research Database (Denmark)

    Nielsen, Susanne Balslev; Jensen, Marina Bergen

    2016-01-01

    To address the climate adaptation of cities, today’s water managers need more than technical skills to drive sustainable urban water projects, which also stimulate demand for post-graduate education so that professionalisation of integrated sustainable water management in the public sector can...... be achieved. The ‘urban water platform’ was tested and is hereby presented as a course concept for building collective capabilities for integrated sustainable water design among local authorities in Denmark. The course is an innovation because: 1) it invites urban planners, road and park managers and sewage...... managers to take part in a dialogue about sustainable urban water projects, while collectively exploring new design solutions; 2) it facilitates an appreciative communication between several disciplines; 3) it promotes careful planning in the early stages of an urban water construction project....

  3. The Relationship Between Dynamics and Structure in the Far Infrared Absorption Spectrum of Liquid Water

    Energy Technology Data Exchange (ETDEWEB)

    Woods, K.

    2005-01-14

    Using an intense source of far-infrared radiation, the absorption spectrum of liquid water is measured at a temperature ranging from 269 to 323 K. In the infrared spectrum we observe modes that are related to the local structure of liquid water. Here we present a FIR measured spectrum that is sensitive to the low frequency (< 100cm{sup -1}) microscopic details that exist in liquid water.

  4. Determination of insecticides in water using in situ halide exchange reaction-assisted ionic liquid dispersive liquid-liquid microextraction followed by high-performance liquid chromatography.

    Science.gov (United States)

    Li, Songqing; Gao, Haixiang; Zhang, Jiaheng; Li, Yubo; Peng, Bing; Zhou, Zhiqiang

    2011-11-01

    A dispersive liquid-liquid microextraction (DLLME) method using in situ halide exchange reaction to form ionic liquid (IL) extraction phase was developed to determine four insecticides (i.e. methoxyfenozide, tetrachlorvinphos, thiamethoxam, and diafenthiuron) in water samples. The preconcentration procedure, followed by high-performance liquid chromatography and variable wavelength detectors (VWD), enabled the formation of the immiscible IL extraction phase; the insecticides were transferred into the IL phase simultaneously, which enhanced the efficiency and sufficiency, greatly shortening the operation time. The experimental parameters affecting the extraction efficiency including volume of extraction IL, extraction and centrifugation times, volume of the sample solution and exchanging reagent, and addition of organic solvent and salt were investigated and optimized. Under optimized conditions, the extractions yielded recoveries of the target analytes from 82 to 102%. The calibration curves were linear, and the correlation coefficient ranged from 0.9990 to 0.9999 under the concentration levels of 5-200 μg/L. The relative standard deviation (n=6) was 2.9-4.6%. The limits of detection (LODs) for the four insecticides were between 0.98 and 2.54 μg/L. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  5. The modelled liquid water balance of the Greenland Ice Sheet

    Directory of Open Access Journals (Sweden)

    C. R. Steger

    2017-11-01

    Full Text Available Recent studies indicate that the surface mass balance will dominate the Greenland Ice Sheet's (GrIS contribution to 21st century sea level rise. Consequently, it is crucial to understand the liquid water balance (LWB of the ice sheet and its response to increasing surface melt. We therefore analyse a firn simulation conducted with the SNOWPACK model for the GrIS and over the period 1960–2014 with a special focus on the LWB and refreezing. Evaluations of the simulated refreezing climate with GRACE and firn temperature observations indicate a good model–observation agreement. Results of the LWB analysis reveal a spatially uniform increase in surface melt (0.16 m w.e. a−1 during 1990–2014. As a response, refreezing and run-off also indicate positive changes during this period (0.05 and 0.11 m w.e. a−1, respectively, where refreezing increases at only half the rate of run-off, implying that the majority of the additional liquid input runs off the ice sheet. This pattern of refreeze and run-off is spatially variable. For instance, in the south-eastern part of the GrIS, most of the additional liquid input is buffered in the firn layer due to relatively high snowfall rates. Modelled increase in refreezing leads to a decrease in firn air content and to a substantial increase in near-surface firn temperature. On the western side of the ice sheet, modelled firn temperature increases are highest in the lower accumulation zone and are primarily caused by the exceptional melt season of 2012. On the eastern side, simulated firn temperature increases are more gradual and are associated with the migration of firn aquifers to higher elevations.

  6. The modelled liquid water balance of the Greenland Ice Sheet

    Science.gov (United States)

    Steger, Christian R.; Reijmer, Carleen H.; van den Broeke, Michiel R.

    2017-11-01

    Recent studies indicate that the surface mass balance will dominate the Greenland Ice Sheet's (GrIS) contribution to 21st century sea level rise. Consequently, it is crucial to understand the liquid water balance (LWB) of the ice sheet and its response to increasing surface melt. We therefore analyse a firn simulation conducted with the SNOWPACK model for the GrIS and over the period 1960-2014 with a special focus on the LWB and refreezing. Evaluations of the simulated refreezing climate with GRACE and firn temperature observations indicate a good model-observation agreement. Results of the LWB analysis reveal a spatially uniform increase in surface melt (0.16 m w.e. a-1) during 1990-2014. As a response, refreezing and run-off also indicate positive changes during this period (0.05 and 0.11 m w.e. a-1, respectively), where refreezing increases at only half the rate of run-off, implying that the majority of the additional liquid input runs off the ice sheet. This pattern of refreeze and run-off is spatially variable. For instance, in the south-eastern part of the GrIS, most of the additional liquid input is buffered in the firn layer due to relatively high snowfall rates. Modelled increase in refreezing leads to a decrease in firn air content and to a substantial increase in near-surface firn temperature. On the western side of the ice sheet, modelled firn temperature increases are highest in the lower accumulation zone and are primarily caused by the exceptional melt season of 2012. On the eastern side, simulated firn temperature increases are more gradual and are associated with the migration of firn aquifers to higher elevations.

  7. Nanotechnology for a safe and sustainable water supply: enabling integrated water treatment and reuse.

    Science.gov (United States)

    Qu, Xiaolei; Brame, Jonathon; Li, Qilin; Alvarez, Pedro J J

    2013-03-19

    promising route both to retrofit aging infrastructure and to develop high performance, low maintenance decentralized treatment systems including point-of-use devices. Broad implementation of nanotechnology in water treatment will require overcoming the relatively high costs of nanomaterials by enabling their reuse and mitigating risks to public and environmental health by minimizing potential exposure to nanoparticles and promoting their safer design. The development of nanotechnology must go hand in hand with environmental health and safety research to alleviate unintended consequences and contribute toward sustainable water management.

  8. Thermodynamic constraint on the cloud liquid water feedback in climate models

    Science.gov (United States)

    Betts, Alan K.; HARSHVARDHAN

    1987-01-01

    The cloud liquid water feedback in climate models consists of the increase (decrease) in optical depth of clouds resulting from higher (lower) liquid water contents that might accompany tropospheric warming (cooling). The change in cloud liquid water with temperature is shown to depend on the rate of change of the slope of the moist adiabat with respect to temperature, and it is a strong function of temperature. The value of this rate of change in the tropics is about half that in mid and high latitudes and is much less than the value obtained by assuming that liquid water scales with the saturation mixing ratio.

  9. Explaining ionic liquid water solubility in terms of cation and anion hydrophobicity

    National Research Council Canada - National Science Library

    Ranke, Johannes; Othman, Alaa; Fan, Ping; Müller, Anja

    2009-01-01

    .... In this contribution, the activity coefficients of ionic liquids in water are split into cation and anion contributions by regression against cation hydrophobicity parameters that are experimentally...

  10. Energy loss measurement of protons in liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Siiskonen, T; Peraejaervi, K; Turunen, J [STUK - Radiation and Nuclear Safety Authority, PO Box 14, FI-00881 Helsinki (Finland); Kettunen, H; Javanainen, A; Rossi, M; Trzaska, W H; Virtanen, A, E-mail: teemu.siiskonen@stuk.fi [Department of Physics, University of Jyvaeskylae, PO Box 35, FI-40014, Jyvaeskylae (Finland)

    2011-04-21

    The proton stopping power of liquid water was, for the first time, measured in the energy range 4.7-15.2 MeV. The proton energies were determined by the time-of-flight transmission technique with the microchannel plate detectors, which were especially developed for timing applications. The results are compared to the literature values (from ICRU Report 49 (1993) and Janni's tabulation (1982 At. Data Nucl. Data Tables 27 147-339)) which are based on Bethe's formula and an agreement is found within the experimental uncertainty of 4.6%. Thus, earlier reported discrepancy between the experimental and literature stopping power values at lower energies was not observed at the energies considered in this experiment.

  11. Electrokinetic Hydrogen Generation from Liquid WaterMicrojets

    Energy Technology Data Exchange (ETDEWEB)

    Duffin, Andrew M.; Saykally, Richard J.

    2007-05-31

    We describe a method for generating molecular hydrogen directly from the charge separation effected via rapid flow of liquid water through a metal orifice, wherein the input energy is the hydrostatic pressure times the volume flow rate. Both electrokinetic currents and hydrogen production rates are shown to follow simple equations derived from the overlap of the fluid velocity gradient and the anisotropic charge distribution resulting from selective adsorption of hydroxide ions to the nozzle surface. Pressure-driven fluid flow shears away the charge balancing hydronium ions from the diffuse double layer and carries them out of the aperture. Downstream neutralization of the excess protons at a grounded target electrode produces gaseous hydrogen molecules. The hydrogen production efficiency is currently very low (ca. 10-6) for a single cylindrical jet, but can be improved with design changes.

  12. Cloud Liquid Water, Mean Droplet Radius and Number Density Measurements Using a Raman Lidar

    Science.gov (United States)

    Whiteman, David N.; Melfi, S. Harvey

    1999-01-01

    A new technique for measuring cloud liquid water, mean droplet radius and droplet number density is outlined. The technique is based on simultaneously measuring Raman and Mie scattering from cloud liquid droplets using a Raman lidar. Laboratory experiments on liquid micro-spheres have shown that the intensity of Raman scattering is proportional to the amount of liquid present in the spheres. This fact is used as a constraint on calculated Mie intensity assuming a gamma function particle size distribution. The resulting retrieval technique is shown to give stable solutions with no false minima. It is tested using Raman lidar data where the liquid water signal was seen as an enhancement to the water vapor signal. The general relationship of retrieved average radius and number density is consistent with traditional cloud physics models. Sensitivity to the assumed maximum cloud liquid water amount and the water vapor mixing ratio calibration are tested. Improvements to the technique are suggested.

  13. Managing Water Sustainability: Virtual Water Flows and Economic Water Productivity Assessment of the Wine Trade between Italy and the Balkans

    Directory of Open Access Journals (Sweden)

    Pier Paolo Miglietta

    2018-02-01

    Full Text Available The management of natural resources in economic activities has become a fundamental issue when considering the perspective of sustainable development. It is necessary to rethink every process in order to reach efficiency from different points of view, not only environmentally but also economically. Water scarcity is growing because of economic and population growth, climate change, and the increasing water demand. Currently, agri-food represents the most water consumptive sector, and the increasing importance of international trade in this industry puts freshwater issues in a global context that should be analyzed and regulated by sustainable policies. This analysis is focused on virtual water flows and economic water productivity related to the wine trade, and aims to evaluate water loss/savings achieved through bilateral trade relations. The choice fell on Italy, the first wine producer in the world, and the Balkan countries. The latter are new markets for wine production/consumption, in which Italian wines are strongly positioned for different reasons. The results show that, from a national point of view and considering wine trade, Italy exports water in virtual form to the Balkan countries, more than it imports, so that in effect it partially uses its own water resources for the wine supply of the Balkans. The latter, on the other hand, being a net importer of wine, partially depends on Italian water resources and exerts less pressure on their own water basins in the supporting wine supply. We also observed that the wine trade between Italy and the Balkans implies global water savings.

  14. A NUTRIENT-IN-WATER RESOURCE FOR SUSTAINABLE CROP ...

    African Journals Online (AJOL)

    sys01

    2011-09-03

    Sep 3, 2011 ... SUSTAINABLE CROP PRODUCTION ON 'ACID SANDS' OF SOUTHERN. NIGERIA. Amalu U. C. and Okon P. B. ... sustainable production of arable and vegetable crops. Application of a solution of urea and lime, ... conducted at Teaching and Research Farm,. Faculty of Agriculture, University of Calabar,.

  15. Prospect of Pongamia pinnata (Karanja in Bangladesh: A Sustainable Source of Liquid Fuel

    Directory of Open Access Journals (Sweden)

    P. K. Halder

    2014-01-01

    Full Text Available Energy is the basic requirement for the existence of human being in today’s digital world. Indigenous energy of Bangladesh (especially natural gas and diesel is basically used in power generation and depleting hastily to meet the increasing power demand. Therefore, special emphasis has been given to produce alternative liquid fuel worldwide to overcome the crisis of diesel. Pongamia pinnata (karanja may be an emerging option for providing biooil for biodiesel production. Although karanja biooil has been used as a source of traditional medicines in Bangladesh, it can also be used for rural illumination. This paper outlines the medical and energy aspects of Pongamia pinnata. It has been assessed that Bangladesh can utilize about 128.95 PJ through Pongamia cultivation in unused lands. The paper reviews the potentiality of Pongamia pinnata as a source of biodiesel and its benefits in Bangladesh. The paper also revives that, about 0.52 million tons of biodiesel can be produced only utilizing the unused lands per year in sustainable basis as it reduces CO2, CO, HC, and NOx emission compared to pure diesel.

  16. Distillery effluent as a liquid fertilizer: a win-win option for sustainable agriculture.

    Science.gov (United States)

    Kumari, K; Ranjan, N; Kumar, S; Sinha, R C

    2016-01-01

    A promising approach to recycle the residual distillery waste as a potential liquid fertilizer has been discussed in this paper. Field studies were conducted on Brassica compestris to assess the potential of the diluted post- methanated distillery effluent. The results indicated that there was not much variation in pH, conductivity and nitrate of soil, whereas total dissolved solids, conductivity, nitrate and chemical oxygen demand of the well water increased slightly but well within the permissible limit. However, there was a significant increase in the plant biomass, diameter of the shoot and root, area of leaf, as well as number and length of pods and root hairs. The hydrophilic colloids of the seed increased significantly (p < .01) and the yield of mustard seeds was increased by 30% as compared to the conventional fertilizer. The carbohydrate, chlorophyll and ascorbic acid content of the leaf, stem and root were also analysed and its morpho- physiological significance is also presented in this paper.

  17. Water and Energy Sustainability: A Balance of Government Action and Industry Innovation

    Energy Technology Data Exchange (ETDEWEB)

    Ben Grunewald

    2009-12-31

    By completing the tasks and subtasks of the project, the Ground Water Protection Council (GWPC) through its state regulatory agency members and oil and gas industry partners, will bring attention to water quality and quantity issues and make progress toward water and energy sustainability though enhanced water protection and conservation thus enhancing the viability of the domestic fossil fuel industry. The project contains 4 major independent Tasks. Task 1 - Work Plan: Water-Energy Sustainability: A Symposium on Resource Viability. Task 2 - Work Plan: A Regional Assessment of Water and Energy Sustainability. Task 3 - Work Plan: Risk Based Data Management System-Water Water and Energy Module. Task 4 - Work Plan: Identification and Assessment of States Regulatory Programs Regarding Geothermal Heating and Cooling Systems. Each task has a specific scope (details given).

  18. THE COMMUNITY WATER MANAGEMENT IN MEXICO AND ECUADOR: OTHER APPROACHES TO SUSTAINABILITY

    Directory of Open Access Journals (Sweden)

    Adriana Sandoval-Moreno

    2013-04-01

    Full Text Available The present work aims to analyze on community water management in two cases in Latin America, Mexico and Ecuador, face the great sustainability challenges of water resources in the world. The central questions that guide the study are: How does community water management contributes to solve the water crisis locally? and How community responses are sustainable responses to the problem of water supply? The paper presents the main aspects of the problem of water in Latin America, discusses the relevance of addressing the problem of water by the dominant management models and alternative. Finally, it offers the analysis of the community management of water for human consumption in the Cienega de Chapala, Michoacan, Mexico and Imbabura, Ecuador, highlighting their contributions in terms of sustainability.

  19. In situ separation of root hydraulic redistribution of soil water from liquid and vapor transport

    Science.gov (United States)

    Jeffrey M. Warren; J. Renée Brooks; Maria I. Dragila; Frederick C. Meinzer

    2011-01-01

    Nocturnal increases in water potential and water content in the upper soil profile are often attributed to root water efflux, a process termed hydraulic redistribution (HR). However, unsaturated liquid or vapor flux of water between soil layers independent of roots also contributes to the daily recovery in water content, confounding efforts to determine the actual...

  20. Thermophysical properties of pure and water-saturated tetradecyltrihexylphosphonium-based ionic liquids

    Energy Technology Data Exchange (ETDEWEB)

    Neves, Catarina M.S.S.; Carvalho, Pedro J.; Freire, Mara G. [Departamento de Quimica, CICECO, Universidade de Aveiro, 3810-193 Aveiro (Portugal); Coutinho, Joao A.P., E-mail: jcoutinho@ua.p [Departamento de Quimica, CICECO, Universidade de Aveiro, 3810-193 Aveiro (Portugal)

    2011-06-15

    Research highlights: {yields} Density and viscosity data of seven pure phosphonium ionic liquids are reported. {yields} Water content of saturated phosphonium ionic liquids is presented. {yields} Density and viscosity data of water-saturated ionic liquids are reported. {yields} Density data is only marginally affected by the presence of water. {yields} The presence of water has a large impact in viscosities. - Abstract: In this work, the solubility of water in several tetradecyltrihexylphosphonium-based ionic liquids at 298.15 K, and densities and viscosities of both pure and water-saturated ionic liquids in a broad temperature range were measured. The selected ionic liquids comprise the common tetradecyltrihexylphosphonium cation combined with the following anions: bromide, chloride, bis(trifluoromethylsulfonyl)imide, decanoate, methanesulfonate, dicyanamide and bis(2,4,4-trimethylpentyl)phosphinate. The isobaric thermal expansion coefficients for pure and water-saturated ionic liquids were determined based on the density dependence with temperature. Taking into account that the excess molar volumes of the current hydrophobic water-saturated ionic liquids are negligible, the solubility of water was additionally estimated from the gathered density data and compared with the experimental solubilities obtained. Moreover, the experimental densities were compared with those predicted by the Gardas and Coutinho model while viscosity data were correlated using the Vogel-Tammann-Fulcher method.

  1. Investigation of the Extinguishing Features for Liquid Fuels and Organic Flammable Liquids Atomized by a Water Flow

    Directory of Open Access Journals (Sweden)

    Voytkov Ivan V.

    2016-01-01

    Full Text Available The processes of heat and mass transfer were investigated experimentally while moving and evaporating the atomized water flow in high-temperature combustion products of typical liquid fuels and organic flammable liquids: gasoline, kerosene, acetone, crude oil, industrial alcohol. We determined typical periods of liquid extinguishing by an atomized water flow of various dispersability. Data of the discharge of extinguishing medium corresponding to various parameters of atomization and duration of using the atomization devices was presented. It is shown that Um≈3.5 m/s is a minimal outflow velocity of droplets during moving while passing the distance of 1m in the high-temperature gas medium to stop the combustion of organic liquids.

  2. Perception of drinking water safety and factors influencing acceptance and sustainability of a water quality intervention in rural southern India.

    Science.gov (United States)

    Francis, Mark Rohit; Nagarajan, Guru; Sarkar, Rajiv; Mohan, Venkata Raghava; Kang, Gagandeep; Balraj, Vinohar

    2015-07-30

    Acceptance and long-term sustainability of water quality interventions are pivotal to realizing continued health benefits. However, there is limited research attempting to understand the factors that influence compliance to or adoption of such interventions. Eight focus group discussions with parents of young children--including compliant and not compliant households participating in an intervention study, and three key-informant interviews with village headmen were conducted between April and May 2014 to understand perceptions on the effects of unsafe water on health, household drinking water treatment practices, and the factors influencing acceptance and sustainability of an ongoing water quality intervention in a rural population of southern India. The ability to recognize health benefits from the intervention, ease of access to water distribution centers and the willingness to pay for intervention maintenance were factors facilitating acceptance and sustainability of the water quality intervention. On the other hand, faulty perceptions on water treatment, lack of knowledge about health hazards associated with drinking unsafe water, false sense of protection from locally available water, resistance to change in taste or odor of water and a lack of support from male members of the household were important factors impeding acceptance and long term use of the intervention. This study highlights the need to effectively involve communities at important stages of implementation for long term success of water quality interventions. Timely research on the factors influencing uptake of water quality interventions prior to implementation will ensure greater acceptance and sustainability of such interventions in low income settings.

  3. Advancing Water Footprint Assessment Research: Challenges in Monitoring Progress towards Sustainable Development Goal 6

    Directory of Open Access Journals (Sweden)

    Arjen Y. Hoekstra

    2017-06-01

    Full Text Available This special issue is a collection of recent papers in the field of Water Footprint Assessment (WFA, an emerging area of research focused on the analysis of freshwater use, scarcity, and pollution in relation to consumption, production, and trade. As increasing freshwater scarcity forms a major risk to the global economy, sustainable management of water resources is a prerequisite to development. We introduce the papers in this special issue by relating them to Sustainable Development Goal (SDG number 6 of the United Nations, the goal on water. We will particularly articulate how each paper drives the understanding needed to achieve target 6.3 on water quality and pollution and target 6.4 on water-use efficiency and water scarcity. Regarding SDG 6, we conclude that it lacks any target on using green water more efficiently, and while addressing efficiency and sustainability of water use, it lacks a target on equitable sharing of water. The latter issue is receiving limited attention in research as well. By primarily focusing on water-use efficiency in farming and industries at the local level, to a lesser extent to using water sustainably at the level of total water systems (like drainage basins, aquifers, and largely ignoring issues around equitable water use, understanding of our water problems and proposed solutions will likely remain unbalanced.

  4. Learning Science Through Guided Discovery: Liquid Water and Molecular Networks

    Science.gov (United States)

    Essmann, U.; Glotzer, S.; Gyure, M.; Ostrovsky, B.; Poole, P. H.; Sastry, S.; Schwarzer, S.; Selinger, R.; Shann, M. H.; Shore, L. S.; Stanley, H. E.; Taylor, E. F.; Trunfio, P.

    In every drop of water, down at the scale of atoms and molecules, there is a world that can fascinate anyone—ranging from a non-verbal young science student to an ardent science-phobe. The objective of Learning Science through Guided Discovery: Liquid Water and Molecular Networks is to use advanced technology to provide a window into this submicroscopic world, and thereby allow students to discover by themselves a new world. We have developed a coordinated two-fold approach in which a cycle of hands-on activities, games, and experimentation is followed by a cycle of advanced computer simulations employing the full power of computer animation to "ZOOM" into the depths of his or her newly-discovered world, an interactive experience surpassing that of an OMNIMAX theater. Pairing of laboratory experiments with corresponding simulations challenges students to understand multiple representations of concepts. Answers to student questions, resolution of student misconceptions, and eventual personalized student discoveries are all guided by a clear set of "cues" which we build into the computer display. We thereby provide students with the opportunity to work in a fashion analogous to that in which practicing scientists work—e.g., by using advanced technology to "build up" to general principles from specific experiences. Moreover, the ability to visualize "real-time" dynamic motions allows for student-controlled animated graphic simulations on the molecular scale and interactive guided lessons superior to those afforded by even the most artful of existing texts.

  5. Influence of gravity on the collective molecular dynamics of liquid water: the case of the floating water bridge

    CERN Document Server

    Del Giudice, Emilio

    2010-01-01

    Quantum electrodynamics (QED) produces a picture of liquid water as a mixture of a low density coherent phase and an high density non-coherent phase. Consequently, the Archimedes principle prescribes that, within a gravitational field, liquid water should be made up, at surface, mainly of the coherent fraction, which becomes a cage where the gas-like non-coherent fraction is trapped, acquiring a non-vanishing pressure (vapor tension). Therefore, it is possible to probe the QED picture by observing the behavior of liquid water under reduced gravity conditions. The floating water bridge could be a useful test model.

  6. Orientational dynamics of room temperature ionic liquid/water mixtures: water-induced structure.

    Science.gov (United States)

    Sturlaugson, Adam L; Fruchey, Kendall S; Fayer, Michael D

    2012-02-16

    Optical heterodyne detected optical Kerr effect (OHD-OKE) measurements on a series of 1-alkyl-3-methylimidazolium tetrafluoroborate room-temperature ionic liquids (RTILs) as a function of chain length and water concentration are presented. The pure RTIL reorientational dynamics are identical in form to those of other molecular liquids studied previously by OHD-OKE (two power laws followed by a single exponential decay at long times), but are much slower at room temperature. In contrast, the addition of water to the longer alkyl chain RTILs causes the emergence of a long time biexponential orientational anisotropy decay. Such distinctly biexponential decays have not been seen previously in OHD-OKE experiments on any type of liquid and are analyzed here using a wobbling-in-a-cone model. The slow component for the longer chain RTILs does not obey the Debye-Stokes-Einstein (DSE) equation across the range of solutions, and thus we attribute it to slow cation reorientational diffusion caused by a stiffening of cation alkyl tail-tail associations. The fast component of the decay is assigned to the motions (wobbling) of the tethered imidazolium head groups. The wobbling-in-a-cone analysis provides estimates of the range of angles sampled by the imidazolium head group prior to the long time scale complete orientational randomization. The heterogeneous dynamics and non-DSE behavior observed here should have a significant effect on reaction rates in RTIL/water cosolvent mixtures.

  7. Strengthening Sustainable Water Resources Adaptive Capacity To Climate Change, A Case Study in Taiwan

    Science.gov (United States)

    Tung, C.; Chen, S.; Liu, T.; Yu, P.

    2008-12-01

    Climate change refers to the long-term variation, which may exacerbate short-term climate variability and more extreme events, and then may impact on human society and natural environment. Socioeconomic development is dependent on adequate water resources, but climate change may impact on such supply system, including available streamflow, groundwater, irrigation requirement and also impact on the sustainability for regional water alimentation. The purposes of this study are to assess the climate change impacts on regional water supply systems and to propose response strategies strengthening adaptive capacity to achieve sustainable water uses. To simulate the processes of surface water, a physical model, Hydrologiska Byråns Vattenbalansavdelning (HBV) model, is used. A system dynamics approach using a specialized software tool, Vensim, is used to simulate a water supply system of the Danshuei river watershed in Taiwan to analyze the climate impacts on sustainable water resource utilization. In order to understand the improvement of adaptive capacity for all response strategies, adjusting parameters on a system dynamics model and a definition of a sustainable index is necessary to recognize the benefits of every response strategy. To make the adaptive strategies practical, the selection of adaptive strategies according to the governmental plan such as re-allocation of regional water resources and increase of water supply capacity will be discussed in the end. Hopefully, the adaptive capacity will be enhanced to mitigate climate change impacts on water supply system to achieve sustainable water uses.

  8. Towards a sustainable human right to water : Supporting vulnerable people and protecting water resources with Suriname as a case study

    NARCIS (Netherlands)

    Misiedjan, D.J.E.

    2017-01-01

    This study answers a key question: how can the concept of sustainable development contribute to the sustainable realization of the human right to water for vulnerable people, by taking the following approaches. This was answered in the following ways. Firstly, by widening the scope of vulnerability

  9. Ultrapreconcentration and determination of organophosphorus pesticides in water by solid-phase extraction combined with dispersive liquid-liquid microextraction and high-performance liquid chromatography.

    Science.gov (United States)

    Chen, Junhua; Zhou, Guangming; Deng, Yongli; Cheng, Hongmei; Shen, Jie; Gao, Yi; Peng, Guilong

    2016-01-01

    Solid-phase extraction coupled with dispersive liquid-liquid microextraction was developed as an ultra-preconcentration method for the determination of four organophosphorus pesticides (isocarbophos, parathion-methyl, triazophos and fenitrothion) in water samples. The analytes considered in this study were rapidly extracted and concentrated from large volumes of aqueous solutions (100 mL) by solid-phase extraction coupled with dispersive liquid-liquid microextraction and then analyzed using high performance liquid chromatography. Experimental variables including type and volume of elution solvent, volume and flow rate of sample solution, salt concentration, type and volume of extraction solvent and sample solution pH were investigated for the solid-phase extraction coupled with dispersive liquid-liquid microextraction with these analytes, and the best results were obtained using methanol as eluent and ethylene chloride as extraction solvent. Under the optimal conditions, an exhaustive extraction for four analytes (recoveries >86.9%) and high enrichment factors were attained. The limits of detection were between 0.021 and 0.15 μg/L. The relative standard deviations for 0.5 μg/L of the pesticides in water were in the range of 1.9-6.8% (n = 5). The proposed strategy offered the advantages of simple operation, high enrichment factor and sensitivity and was successfully applied to the determination of four organophosphorus pesticides in water samples. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  10. Effectiveness of Liquid-Liquid Extraction, Solid Phase Extraction, and Headspace Technique for Determination of Some Volatile Water-Soluble Compounds of Rose Aromatic Water

    Science.gov (United States)

    2017-01-01

    Steam distillation is used to isolate scent of rose flowers. Rose aromatic water is commonly used in European cuisine and aromatherapy besides its use in cosmetic industry for its lovely scent. In this study, three different sampling techniques, liquid-liquid extraction (LLE), headspace technique (HS), and solid phase extraction (SPE), were compared for the analysis of volatile water-soluble compounds in commercial rose aromatic water. Some volatile water-soluble compounds of rose aromatic water were also analyzed by gas chromatography mass spectrometry (GCMS). In any case, it was concluded that one of the solid phase extraction methods led to higher recoveries for 2-phenylethyl alcohol (PEA) in the rose aromatic water than the liquid-liquid extraction and headspace technique. Liquid-liquid extraction method provided higher recovery ratios for citronellol, nerol, and geraniol than others. Ideal linear correlation coefficient values were observed by GCMS for quantitative analysis of volatile compounds (r2 ≥ 0.999). Optimized methods showed acceptable repeatability (RSDs 95%). For compounds such as α-pinene, linalool, β-caryophyllene, α-humulene, methyl eugenol, and eugenol, the best recovery values were obtained with LLE and SPE. PMID:28791049

  11. Ionic Liquid Dispersive Liquid-Liquid Microextraction Method for the Determination of Irinotecan, an Anticancer Drug, in Water and Urine Samples Using UV-Vis Spectrophotometry.

    Science.gov (United States)

    Uysal, Deniz; Karadaş, Cennet; Kara, Derya

    2017-05-01

    A new, simple, efficient, and environmentally friendly ionic liquid dispersive liquid-liquid microextraction method was developed for the determination of irinotecan, an anticancer drug, in water and urine samples using UV-Vis spectrophotometry. The ionic liquid 1-hexyl-3-methylimidazolium hexafluorophosphate was used as the extraction solvent, and ethanol was used as the disperser solvent. The main parameters affecting the extraction efficiency, including sample pH, volume of the ionic liquid, choice of the dispersive solvent and its volume, concentration of NaCl, and extraction and centrifugation times, were investigated and optimized. The effect of interfering species on the recovery of irinotecan was also examined. Under optimal conditions, the LOD (3σ) was 48.7 μg/L without any preconcentration. Because the urine sample was diluted 10-fold, the LOD for urine would be 487 μg/L. However, this could be improved 16-fold if preconcentration using a 40 mL aliquot of the sample is used. The proposed method was successfully applied to the determination of irinotecan in tap water, river water, and urine samples spiked with 10.20 mg/L for the water samples and 8.32 mg/L for the urine sample. The average recovery values of irinotecan determined were 99.1% for tap water, 109.4% for river water, and 96.1% for urine.

  12. Sustainable water demand management in the face of rapid urbanization and ground water depletion for social–ecological resilience building

    Directory of Open Access Journals (Sweden)

    Md. Arfanuzzaman

    2017-04-01

    Full Text Available Necessity of Sustainable water demand management (SWDM is immensely higher in the rapidly urbanized mega cities of the world where groundwater depletion and water deficit are taking place perilously. This paper focuses on the present condition of water demand, supply, system loss, pricing strategy, groundwater level, and per capita water consumption of Dhaka city, Bangladesh. The study founds population growth has a large influence on water demand to rise and demand of water is not responsive to the existing pricing rule adopted by DWASA. It emerges that, water demand is increasing at 4% rate an average in the Dhaka city since 1990 and groundwater table goes more than 70 m down in central capital due to extensive withdrawal of water. The study suggests an integrated SWDM approach, which incorporates optimum pricing, ground and surface water regulation, water conservation, sustainable water consumption and less water foot print to ease groundwater depletion. In order to attain sustainability in water demand management (WDM the study recommends certain criteria under economic, social and environmental segment to administer the increasing water demand of growing population and conserve the fresh water resources of the world’s mega cities for social–ecological resilience building.

  13. Water and Carbon Footprints for Sustainability Analysis of Urban Infrastructure

    Science.gov (United States)

    Water and transportation infrastructures define spatial distribution of urban population and economic activities. In this context, energy and water consumed per capita are tangible measures of how efficient water and transportation systems are constructed and operated. At a hig...

  14. Isobaric vapor-liquid equilibria for methanol + ethanol + water and the three constituent binary systems

    Energy Technology Data Exchange (ETDEWEB)

    Kurihara, Kiyofumi; Nakamichi, Mikiyoshi; Kojima, Kazuo (Nihon Univ., Tokyo (Japan). Dept. of Industrial Chemistry)

    1993-07-01

    Vapor-liquid equilibrium data for methanol + ethanol + water and its three constituent binary systems methanol + ethanol, ethanol + water, and methanol + water were measured at 101.3 kPa using a liquid-vapor ebullition-type equilibrium still. The experimental binary data were correlated by the NRTL equation. The ternary system methanol + ethanol + water was predicted by means of the binary NRTL parameters with good accuracy.

  15. Experiments on FTU with an actively water cooled liquid lithium limiter

    Energy Technology Data Exchange (ETDEWEB)

    Mazzitelli, G., E-mail: giuseppe.mazzitelli@enea.it [Associazione EURATOM-ENEA sulla Fusione, C.R. Frascati, C.P. 65-00044 Frascati, Rome (Italy); Apicella, M.L.; Apruzzese, G.; Crescenzi, F.; Iannone, F.; Maddaluno, G. [Associazione EURATOM-ENEA sulla Fusione, C.R. Frascati, C.P. 65-00044 Frascati, Rome (Italy); Pericoli-Ridolfini, V. [Associazione EURATOM-ENEA sulla Fusione, CREATE, Università di Napoli Federico II, 80125 Napoli (Italy); Roccella, S.; Reale, M.; Viola, B. [Associazione EURATOM-ENEA sulla Fusione, C.R. Frascati, C.P. 65-00044 Frascati, Rome (Italy); Lyublinski, I.; Vertkov, A. [JSC “RED STAR”, Moscow (Russian Federation)

    2015-08-15

    In order to prevent the overheating of the liquid Li surface and the consequent Li evaporation for T > 500 °C, an advanced version of the liquid lithium limiter has been realized and installed on FTU. This new system, named Cooled Lithium Limiter (CLL), has been optimized to demonstrate the lithium limiter capability to sustain thermal loads as high as 10 MW/m{sup 2} with up to 5 s of plasma pulse duration. The CLL operates with an actively cooled system with water circulation at the temperature of about 200 °C, for heating lithium up to the melting point and for the heat removal during the plasma discharges. To characterize CLL during discharges, a fast infrared camera and the spectroscopic signals from Li and D atom emission have been used. The experiments analyzed so far and simulated by ANSYS code, point out that heat loads as high as 2 MW/m{sup 2} for 1.5 s have been withstood without problems.

  16. Structure dynamics of the proton in liquid water probed with terahertz time-domain spectroscopy

    NARCIS (Netherlands)

    Tielrooij, K.J.; Timmer, R.L.A.; Bakker, H.J.; Bonn, M.

    2009-01-01

    We study the hydration of protons in liquid water using terahertz time-domain spectroscopy and polarization-resolved femtosecond midinfrared pump-probe spectroscopy. We observe that the addition of protons leads to a very strong decrease of the dielectric response of liquid water that corresponds to

  17. Vapor-Liquid Equilibria of Imidazolium Ionic Liquids with Cyano Containing Anions with Water and Ethanol.

    Science.gov (United States)

    Khan, Imran; Batista, Marta L S; Carvalho, Pedro J; Santos, Luís M N B F; Gomes, José R B; Coutinho, João A P

    2015-08-13

    Isobaric vapor-liquid equilibria of 1-butyl-3-methylimidazolium thiocyanate ([C4C1im][SCN]), 1-butyl-3-methylimidazolium dicyanamide ([C4C1im][N(CN)2]), 1-butyl-3-methylimidazolium tricyanomethanide ([C4C1im][C(CN)3]), and 1-ethyl-3-methylimidazolium tetracyanoborate ([C2C1im][B(CN)4]), with water and ethanol were measured over the whole concentration range at 0.1, 0.07, and 0.05 MPa. Activity coefficients were estimated from the boiling temperatures of the binary systems, and the data were used to evaluate the ability of COSMO-RS for describing these molecular systems. Aiming at further understanding the molecular interactions on these systems, molecular dynamics (MD) simulations were performed. On the basis of the interpretation of the radial and spatial distribution functions along with coordination numbers obtained through MD simulations, the effect of the increase of CN-groups in the IL anion in its capability to establish hydrogen bonds with water and ethanol was evaluated. The results obtained suggest that, for both water and ethanol systems, the anion [N(CN)2](-) presents the higher ability to establish favorable interactions due to its charge, and that the ability of the anions to interact with the solvent, decreases with further increasing of the number of cyano groups in the anion. The ordering of the partial charges in the nitrogen atoms from the CN-groups in the anions agrees with the ordering obtained for VLE and activity coefficient data.

  18. Sustainability of water-supply at military installations, Kabul Basin, Afghanistan

    Science.gov (United States)

    Mack, Thomas J.; Chornack, Michael P.; Verstraeten, Ingrid M.; Linkov, Igor

    2014-01-01

    The Kabul Basin, including the city of Kabul, Afghanistan, is host to several military installations of Afghanistan, the United States, and other nations that depend on groundwater resources for water supply. These installations are within or close to the city of Kabul. Groundwater also is the potable supply for the approximately four million residents of Kabul. The sustainability of water resources in the Kabul Basin is a concern to military operations, and Afghan water-resource managers, owing to increased water demands from a growing population and potential mining activities. This study illustrates the use of chemical and isotopic analysis, groundwater flow modeling, and hydrogeologic investigations to assess the sustainability of groundwater resources in the Kabul Basin.Water supplies for military installations in the southern Kabul Basin were found to be subject to sustainability concerns, such as the potential drying of shallow-water supply wells as a result of declining water levels. Model simulations indicate that new withdrawals from deep aquifers may have less of an impact on surrounding community water supply wells than increased withdrawals from near- surface aquifers. Higher rates of recharge in the northern Kabul Basin indicate that military installations in that part of the basin may have fewer issues with long-term water sustainability. Simulations of groundwater withdrawals may be used to evaluate different withdrawal scenarios in an effort to manage water resources in a sustainable manner in the Kabul Basin.

  19. Factors influencing sustainability of communally-managed water facilities in rural areas of Zimbabwe

    Science.gov (United States)

    Kativhu, T.; Mazvimavi, D.; Tevera, D.; Nhapi, I.

    2017-08-01

    Sustainability of point water facilities is a major development challenge in many rural settings of developing countries not sparing those in the Sub-Saharan Africa region. This study was done in Zimbabwe to investigate the factors influencing sustainability of rural water supply systems. A total of 399 water points were studied in Nyanga, Chivi and Gwanda districts. Data was collected using a questionnaire, observation checklist and key informant interview guide. Multi-Criteria analysis was used to assess the sustainability of water points and inferential statistical analysis such as Chi square tests and Analysis of Variance (ANOVA) were used to determine if there were significant differences on selected variables across districts and types of lifting devices used in the study area. The thematic approach was used to analyze qualitative data. Results show that most water points were not functional and only 17% across the districts were found to be sustainable. A fusion of social, technical, financial, environmental and institutional factors was found to be influencing sustainability. On technical factors the ANOVA results show that the type of lifting device fitted at a water point significantly influences sustainability (F = 37.4, p planning stage of water projects was also found to be critical for sustainability although field results showed passive participation by communities at this critical project stage. Financial factors of adequacy of financial contributions and establishment of operation and maintenance funds were also found to be of great importance in sustaining water supply systems. It is recommended that all factors should be considered when assessing sustainability since they are interrelated.

  20. Light Water Reactor Sustainability Program. Digital Architecture Requirements

    Energy Technology Data Exchange (ETDEWEB)

    Thomas, Kenneth [Idaho National Lab. (INL), Idaho Falls, ID (United States); Oxstrand, Johanna [Idaho National Lab. (INL), Idaho Falls, ID (United States)

    2015-03-01

    The Digital Architecture effort is a part of the Department of Energy (DOE) sponsored Light-Water Reactor Sustainability (LWRS) Program conducted at Idaho National Laboratory (INL). The LWRS program is performed in close collaboration with industry research and development (R&D) programs that provides the technical foundations for licensing and managing the long-term, safe, and economical operation of current nuclear power plants (NPPs). One of the primary missions of the LWRS program is to help the U.S. nuclear industry adopt new technologies and engineering solutions that facilitate the continued safe operation of the plants and extension of the current operating licenses. Therefore, a major objective of the LWRS program is the development of a seamless digital environment for plant operations and support by integrating information from plant systems with plant processes for nuclear workers through an array of interconnected technologies. In order to get the most benefits of the advanced technology suggested by the different research activities in the LWRS program, the nuclear utilities need a digital architecture in place to support the technology. A digital architecture can be defined as a collection of information technology (IT) capabilities needed to support and integrate a wide-spectrum of real-time digital capabilities for nuclear power plant performance improvements. It is not hard to imagine that many processes within the plant can be largely improved from both a system and human performance perspective by utilizing a plant wide (or near plant wide) wireless network. For example, a plant wide wireless network allows for real time plant status information to easily be accessed in the control room, field workers’ computer-based procedures can be updated based on the real time plant status, and status on ongoing procedures can be incorporated into smart schedules in the outage command center to allow for more accurate planning of critical tasks. The goal

  1. Sustained Recycle in Light Water and Sodium-Cooled Reactors

    Energy Technology Data Exchange (ETDEWEB)

    Steven J. Piet; Samuel E. Bays; Michael A. Pope; Gilles J. Youinou

    2010-11-01

    From a physics standpoint, it is feasible to sustain recycle of used fuel in either thermal or fast reactors. This paper examines multi-recycle potential performance by considering three recycling approaches and calculating several fuel cycle parameters, including heat, gamma, and neutron emission of fresh fuel; radiotoxicity of waste; and uranium utilization. The first recycle approach is homogeneous mixed oxide (MOX) fuel assemblies in a light water reactor (LWR). The transuranic portion of the MOX was varied among Pu, NpPu, NpPuAm, or all-TRU. (All-TRU means all isotopes through Cf-252.) The Pu case was allowed to go to 10% Pu in fresh fuel, but when the minor actinides were included, the transuranic enrichment was kept below 8% to satisfy the expected void reactivity constraint. The uranium portion of the MOX was enriched uranium. That enrichment was increased (to as much as 6.5%) to keep the fuel critical for a typical LWR irradiation. The second approach uses heterogeneous inert matrix fuel (IMF) assemblies in an LWR - a mix of IMF and traditional UOX pins. The uranium-free IMF fuel pins were Pu, NpPu, NpPuAm, or all-TRU. The UOX pins were limited to 4.95% U-235 enrichment. The number of IMF pins was set so that the amount of TRU in discharged fuel from recycle N (from both IMF and UOX pins) was made into the new IMF pins for recycle N+1. Up to 60 of the 264 pins in a fuel assembly were IMF. The assembly-average TRU content was 1-6%. The third approach uses fast reactor oxide fuel in a sodium-cooled fast reactor with transuranic conversion ratio of 0.50 and 1.00. The transuranic conversion ratio is the production of transuranics divided by destruction of transuranics. The FR at CR=0.50 is similar to the CR for the MOX case. The fast reactor cases had a transuranic content of 33-38%, higher than IMF or MOX.

  2. Hydrothermal Conversion in Near-Critical Water – A Sustainable Way of Producing Renewable Fuels

    DEFF Research Database (Denmark)

    Hoffmann, Jessica; Pedersen, Thomas Helmer; Rosendahl, Lasse

    2014-01-01

    Liquid fuels from biomass will form an essential part of meeting the grand challenges within energy. The need for renewable and sustainable energy sources is triggered by a number of factors; like increase in global energy demand, depletion of conventional resources, climate issues and the desire...

  3. Adaptive capacity indicators to assess sustainability of urban water systems - Current application.

    Science.gov (United States)

    Spiller, Marc

    2016-11-01

    Sustainability is commonly assessed along environmental, societal, economic and technological dimensions. A crucial aspect of sustainability is that inter-generational equality must be ensured. This requires that sustainability is attained in the here and now as well as into the future. Therefore, what is perceived as 'sustainable' changes as a function of societal opinion and technological and scientific progress. A concept that describes the ability of systems to change is adaptive capacity. Literature suggests that the ability of systems to adapt is an integral part of sustainable development. This paper demonstrates that indicators measuring adaptive capacity are underrepresented in current urban water sustainability studies. Furthermore, it is discussed under which sustainability dimensions adaptive capacity indicators are lacking and why. Of the >90 indicators analysed, only nine are adaptive capacity indicators, of which six are socio-cultural, two technological, one economical and none environmental. This infrequent use of adaptive capacity indicators in sustainability assessments led to the conclusion that the challenge of dynamic and uncertain urban water systems is, with the exception of the socio-cultural dimension, not yet sufficiently reflected in the application of urban water sustainability indicators. This raises concerns about the progress towards urban water systems that can transform as a response variation and change. Therefore, research should focus on developing methods and indicators that can define, evaluate and quantify adaptive capacity under the economic, environmental and technical dimension of sustainability. Furthermore, it should be evaluated whether sustainability frameworks that focus on the control processes of urban water systems are more suitable for measuring adaptive capacity, than the assessments along environmental, economic, socio-cultural and technological dimensions. Copyright © 2016 Elsevier B.V. All rights reserved.

  4. Hydrophobic zeolites for biofuel upgrading reactions at the liquid-liquid interface in water/oil emulsions.

    Science.gov (United States)

    Zapata, Paula A; Faria, Jimmy; Ruiz, M Pilar; Jentoft, Rolf E; Resasco, Daniel E

    2012-05-23

    HY zeolites hydrophobized by functionalization with organosilanes are much more stable in hot liquid water than the corresponding untreated zeolites. Silylation of the zeolite increases hydrophobicity without significantly reducing the density of acid sites. This hydrophobization with organosilanes makes the zeolites able to stabilize water/oil emulsions and catalyze reactions of importance in biofuel upgrading, i.e., alcohol dehydration and alkylation of m-cresol and 2-propanol in the liquid phase, at high temperatures. While at 200 °C the crystalline structure of an untreated HY zeolite collapses in a few hours in contact with a liquid medium, the functionalized hydrophobic zeolites keep their structure practically unaltered. Detailed XRD, SEM, HRTEM, and BET analyses indicate that even after reaction under severe conditions, the hydrophobic zeolites retain their crystallinity, surface area, microporosity, and acid density. It is proposed that by preferentially anchoring hydrophobic functionalities on the external surface, the direct contact of bulk liquid water and the zeolite is hindered, thus preventing the collapse of the framework during the reaction in liquid hot water.

  5. Water for Agriculture: the Convergence of Sustainability and Safety.

    Science.gov (United States)

    Markland, Sarah M; Ingram, David; Kniel, Kalmia E; Sharma, Manan

    2017-05-01

    Agricultural water is a precious and limited resource. Increasingly more water types and sources are being explored for use in irrigation within the United States and across the globe. As outlined in this chapter, the Produce Safety Rule (PSR) in the Food Safety and Modernization Act (FSMA) provide irrigation water standards for application of water to fruits and vegetables consumed raw. These rules for production and use of water will continue to develop and be required as the world experiences aspects of a changing climate including flooding as well as drought conditions. Research continues to assess the use of agricultural water types. The increased use of reclaimed water in the United States as well as for selected irrigation water needs for specific crops may provide increased water availability. The use of surface water can be used in irrigation as well, but several studies have shown the presence of some enteric bacterial pathogens (enterohemorrhagic E. coli , Salmonella spp. and Listeria monocytogenes ) in these waters that may contaminate fruits and vegetables. There have been outbreaks of foodborne illness in the U.S., South America, Europe, and Australia related to the use of contaminated water in fruit and vegetable irrigation or washing. Unreliable water supplies, more stringent microbial water standards, mitigation technologies and expanded uses of reclaimed waters have all increased interest in agricultural water.

  6. Implications of Frugal Innovations on Sustainable Development: Evaluating Water and Energy Innovations

    Directory of Open Access Journals (Sweden)

    Jarkko Levänen

    2015-12-01

    Full Text Available Frugal innovations are often associated with sustainable development. These connections, however, are based on anecdotal assumptions rather than empirical evidence. This article evaluates the sustainability of four frugal innovations from water and energy sectors. For the purposes of the evaluation, a set of indicators was developed. Indicators are drawn from sustainable development goals by the United Nations and they encompass central dimensions of sustainability: ecological, social and economic. In this article, frugal innovations are compared to solutions that are currently used in similar low-income contexts. Studied frugal innovations were found more sustainable in terms of energy production and water purification capacity than the existing solutions. In terms of social sustainability, larger differences between innovations were found. For example, business models of frugal energy solutions focus on capacity building and the inclusion of marginalized low-income people, whereas business models of water purification solutions focus on more traditional corporate social responsibility activities, such as marketing awareness campaigns and cooperation with non-governmental organizations. Three major sustainability challenges for frugal innovators were identified: (1 the proper integration of material efficiency into product or service systems; (2 the patient promotion of inclusive employment; and (3 the promotion of inclusive and sustainable local industrialization. The article concludes that despite indisputable similarities between frugality and sustainability, it is problematic to equate the two conceptually.

  7. Water reuse for domestic consumption. A key element for environmental and economic sustainability

    OpenAIRE

    Coimbra, José; Almeida, Manuela Guedes de

    2013-01-01

    In a context of increasing social awareness about resources conservation, residential water management is essential in ensuring environmental and economic sustainability. An adequate management is attained with integrated solutions, which simultaneously reduce potable water consumption at least in 25% and enable the storage of recovered water. The recovery and storage of underground water can be ensured with the installation of a groundwater drainage network and an underground water deposi...

  8. City Blueprints: Baseline Assessments of Sustainable Water Management in 11 Cities of the Future

    NARCIS (Netherlands)

    van Leeuwen, C.J.|info:eu-repo/dai/nl/071976817

    2013-01-01

    The necessity of Urban Water Cycle Services (UWCS) adapting to future stresses calls for changes that take sustainability into account. Megatrends (e.g. population growth, water scarcity, pollution and climate change) pose urgent water challenges in cities. In a previous paper, a set of indicators,

  9. The institutional regulation of the sustainability of water resources within mining contexts: accountability and plurality

    NARCIS (Netherlands)

    Sosa, M.; Zwarteveen, M.

    2014-01-01

    This article reviews recent literature on water and mining and uses illustrations from a large gold mine, Yanacocha, operating in Peru, to assess the effectiveness of institutional mechanisms for safeguarding the sustainability of water resources (and water-based ecosystems) in mining regions. The

  10. A Sustainability Index of potential co-location of offshore wind farms and open water aquaculture

    DEFF Research Database (Denmark)

    Bennassai, G.; Mariani, Patrizio; Stenberg, Claus

    2014-01-01

    of the productivity). The further development of the technique, already used in open water aquaculture localization, consists in converting raw data into sustainability scores, which have been combined using additive models, in order to define the overall sustainability. The study area used to implement...

  11. Method selection for sustainability assessments: The case of recovery of resources from waste water.

    Science.gov (United States)

    Zijp, M C; Waaijers-van der Loop, S L; Heijungs, R; Broeren, M L M; Peeters, R; Van Nieuwenhuijzen, A; Shen, L; Heugens, E H W; Posthuma, L

    2017-07-15

    Sustainability assessments provide scientific support in decision procedures towards sustainable solutions. However, in order to contribute in identifying and choosing sustainable solutions, the sustainability assessment has to fit the decision context. Two complicating factors exist. First, different stakeholders tend to have different views on what a sustainability assessment should encompass. Second, a plethora of sustainability assessment methods exist, due to the multi-dimensional characteristic of the concept. Different methods provide other representations of sustainability. Based on a literature review, we present a protocol to facilitate method selection together with stakeholders. The protocol guides the exploration of i) the decision context, ii) the different views of stakeholders and iii) the selection of pertinent assessment methods. In addition, we present an online tool for method selection. This tool identifies assessment methods that meet the specifications obtained with the protocol, and currently contains characteristics of 30 sustainability assessment methods. The utility of the protocol and the tool are tested in a case study on the recovery of resources from domestic waste water. In several iterations, a combination of methods was selected, followed by execution of the selected sustainability assessment methods. The assessment results can be used in the first phase of the decision procedure that leads to a strategic choice for sustainable resource recovery from waste water in the Netherlands. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. CORPORATE GOVERNANCE, SOCIAL RESPONSIBILITY AND SUSTAINABILITY A SURVEY OF WATER USE IN INDUSTRY

    National Research Council Canada - National Science Library

    DOINA PRODAN PALADE; LEON DUMITRU DANIEL

    2015-01-01

    ...’ corporate governance and social responsibility. The work aims to highlight some of the main issues regarding the sustainable use of water, as a finite and vulnerable resource, essential element for life and environment...

  13. The sustainability of urban water supply in low income countries: a livelihoods model

    NARCIS (Netherlands)

    Hadipuro, W.; Wiering, M.A.; Naerssen, A.L. van

    2013-01-01

    Urban water supply can be managed by public institutions, private companies, communities, or by combinations thereof. Controversy continues over which system can most effectively improve livelihoods. Responding to this discussion, an extended model of sustainable livelihoods analysis is proposed

  14. Safe and Sustainable Water Resources Strategic Research Action Plan 2016-2019

    Science.gov (United States)

    EPA's Safe and Sustainable Water Resources (SSWR) research program is using an integrated systems approach to develop scientific and technological solutions to protect human health, and to protect and restore watersheds and aquatic ecosystems.

  15. Safe and Sustainable Water Resources Strategic Research Action Plan 2012-2016

    Science.gov (United States)

    This document represents a strategic guide to EPA’s research actions, alone and in part-nership with the broader federal, industry and scientific research community, to provide the science and engineering necessary for safe and sustainable water resources.

  16. Dissociative ionization of liquid water induced by vibrational overtone excitation

    Energy Technology Data Exchange (ETDEWEB)

    Natzle, W.C.

    1983-03-01

    Photochemistry of vibrationally activated ground electronic state liquid water to produce H/sup +/ and OH/sup -/ ions has been initiated by pulsed, single-photon excitation of overtone and combination transitions. Transient conductivity measurements were used to determine quantum yields as a function of photon energy, isotopic composition, and temperature. The equilibrium relaxation rate following perturbation by the vibrationally activated reaction was also measured as a function of temperature reaction and isotopic composition. In H/sub 2/O, the quantum yield at 283 +- 1 K varies from 2 x 10/sup -9/ to 4 x 10/sup -5/ for wave numbers between 7605 and 18140 cm/sup -1/. In D/sub 2/O, the dependence of quantum yield on wavelength has the same qualitative shape as for H/sub 2/O, but is shifted to lower quantum yields. The position of a minimum in the quantum yield versus hydrogen mole fraction curve is consistent with a lower quantum yield for excitation of HOD in D/sub 2/O than for excitation of D/sub 2/O. The ionic recombination distance of 5.8 +- 0.5 A is constant within experimental error with temperature in H/sub 2/O and with isotopic composition at 25 +- 1/sup 0/C.

  17. Environmental sustainability control by water resources carrying capacity concept: application significance in Indonesia

    Science.gov (United States)

    Djuwansyah, M. R.

    2018-02-01

    This paper reviews the use of Water Resources carrying capacity concept to control environmental sustainability with the particular note for the case in Indonesia. Carrying capacity is a capability measure of an environment or an area to support human and the other lives as well as their activities in a sustainable manner. Recurrently water-related hazards and environmental problems indicate that the environments are exploited over its carrying capacity. Environmental carrying capacity (ECC) assessment includes Land and Water Carrying Capacity analysis of an area, suggested to always refer to the dimension of the related watershed as an incorporated hydrologic unit on the basis of resources availability estimation. Many countries use this measure to forecast the future sustainability of regional development based on water availability. Direct water Resource Carrying Capacity (WRCC) assessment involves population number determination together with their activities could be supported by available water, whereas indirect WRCC assessment comprises the analysis of supply-demand balance status of water. Water resource limits primarily environmental carrying capacity rather than the land resource since land capability constraints are easier. WRCC is a crucial factor known to control land and water resource utilization, particularly in a growing densely populated area. Even though capability of water resources is relatively perpetual, the utilization pattern of these resources may change by socio-economic and cultural technology level of the users, because of which WRCC should be evaluated periodically to maintain usage sustainability of water resource and environment.

  18. Husbandry and Sustainability of Water Buffaloes in Turkey

    Directory of Open Access Journals (Sweden)

    Orhan Ermetin

    2017-12-01

    Full Text Available Water buffaloes in Turkey originate from Mediterranean Water Buffaloes, a subgroup of river water buffaloes and are known as Anatolian Water Buffalo. During the 1970’s the number of water buffaloes in Turkey was one million, but in 2010 this figure dropped to about 85.000. Thanks to the incentives introduced for water buffalo husbandry in recent years, the water buffalo population has risen to 143.073 heads. Water buffalo husbandry in Turkey is performed in some provinces of the Black Sea, Marmara and Central Anatolian Regions. The provinces with the highest amount of water buffalo existence are listed as Samsun, Diyarbakır, Istanbul, Tokat, Bitlis, Muş, Afyon, Kayseri, Sivas and Amasya. Breeding style in Turkey is in the form small family business, with an average of 1-5 animals per enterprise. Family enterprises are keeping water buffaloes for their own consumption. Mostly breeding in modern enterprises formed for indoor barn breeding, the size of the herds is around 50 to 100 heads. Being done only at swamps or waterfronts in the past, water buffalo husbandry increasingly takes place in modern facilities nowadays. The colour of Anatolian Water Buffaloes is generally black and their horns curved backwards, are called arch horns in Turkey. The lactation milk yield and lactation length in Anatolian Water Buffaloes are between 800 and 1100 kg and about 180-280 days respectively. It is demonstrated that they varied according to effects of environmental factors, care and feeding. Adult water buffalo’s live weight is about 411-518 kg. The first insemination age of water buffalo is 32 to 43 months and during a lifespan the number of lactation periods is 5 to 10. For adult water buffalo at withers the height of females is being expressed as around 135 cm. Calves are generally breastfed for 3-4 months. Generally, water buffaloes are milked twice a day in the village farms by hand.

  19. Looking for the rainbow on exoplanets covered by liquid and icy water clouds

    NARCIS (Netherlands)

    Karalidi, T.; Stam, D.M.; Hovenier, J.W.

    2012-01-01

    Aims. Looking for the primary rainbow in starlight that is reflected by exoplanets appears to be a promising method to search for liquid water clouds in exoplanetary atmospheres. Ice water clouds, that consist of water crystals instead of water droplets, could potentially mask the rainbow feature in

  20. Ionic Liquid Dispersive LiquidLiquid Microextraction Method for the Determination of Irinotecan, an Anticancer Drug, in Water and Urine Samples Using UV-Vis Spectrophotometry.

    Science.gov (United States)

    Uysal, Deniz; Karadaş, Cennet; Kara, Derya

    2016-12-16

    A new, simple, efficient, and environmentally friendly ionic liquid dispersive liquid–liquid microextractionmethod was developed for the determination of irinotecan, an anticancer drug, in water and urine samples using UV-Vis spectrophotometry. The ionic liquid 1-hexyl-3-methylimidazolium hexafluorophosphate was used as the extraction solvent, and ethanol was used as the disperser solvent. The main parameters affecting the extraction efficiency, including sample pH, volume of the ionic liquid, choice of the dispersive solvent and its volume, concentration of NaCl, and extraction and centrifugation times, were investigated and optimized. The effect of interfering species on the recovery of irinotecan was also examined. Under optimal conditions, the LOD (3σ) was 48.7 μg/L without any preconcentration. Because the urine sample was diluted 10-fold, the LOD for urine would be 487 μg/L. However, this could be improved 16-fold if preconcentration using a 40 mL aliquot of the sample is used. The proposed method was successfully applied to the determination of irinotecan in tap water, river water, and urine samples spiked with 10.20 mg/L for the water samples and 8.32 mg/L for the urine sample. The average recovery values of irinotecan determined were 99.1% for tap water, 109.4% for river water, and 96.1% for urine.

  1. Sustainable water management in Alberta's oil sands

    Energy Technology Data Exchange (ETDEWEB)

    Byers, Bill; Usher, Robyn; Roach, Andrea [CH2M HILL, Englewood, CO (United States); Lambert, Gord; Kotecha, Prit [Suncor Energy Inc., Calgary (Canada)

    2012-07-01

    The Canadian Association of Petroleum Producers forecast published in 2011 predicts that oil production from oil sands will increase by 50% in the next 3 years and double by 2020. This rate of growth will result in significant pressure on water resources; water use per barrel of oil sands production is comparable to other energy resources - about 2.5 barrels of fresh water per barrel of oil produced are used by mining operations and 0.5 barrels by in-situ operations. Suncor Energy Inc. (Suncor) was the first company to develop the oil sands in northern Alberta and holds one of the largest oil sands positions in Canada. In 2010, Suncor announced plans to increase production to more than 1 million barrels of oil equivalent per day by 2020, which it plans to achieve through oil sands production growth of approximately 10% per year. Because water supply and potential impacts to water quality are critical to its future growth, in 2010-2011 Suncor conducted a risk assessment to identify water-related business risks related to its northern Alberta operations. The assessment identified more than 20 high level business risks in strategic water risk areas including water supply, water reuse, storm water management, groundwater, waste management and river water return. The risk assessment results prompted development of a strategic roadmap to guide water stewardship across Suncor's regional operations. The roadmap describes goals, objectives, and specific activities for each of six key water risk areas, and informs prioritization and selection of prospective water management activities. Suncor is not only exploring water within its own boundaries, but is also collaborating with other oil sands producers to explore ways of integrating its water systems through industry consortia; Suncor is a member of the Oil Sands Leadership Initiative and of the recently formed Canadian Oil Sands Innovation Alliance, among others. (author)

  2. Reuse water and urban horticulture: alliance towards more sustainable cities

    OpenAIRE

    Bizari,Douglas R.; Cardoso,Jean C

    2016-01-01

    ABSTRACT The need to rethink current models of using water resources in the various sectors of human activity is escalating, as thousands of people in different regions of the world are suffering from clean water shortage for their basic daily needs. In this context, the use of recycled water from treated domestic sewage in agricultural activities is gaining ground. Reuse water can combine environmental protection and high agricultural productivity, especially for simultaneously carrying plan...

  3. Water content distribution in a polymer electrolyte membrane for advanced fuel cell system with liquid water supply.

    Science.gov (United States)

    Tsushima, Shohji; Teranishi, Kazuhiro; Nishida, Kousuke; Hirai, Shuichiro

    2005-02-01

    To better understand the operation of a new fuel cell design, we used magnetic resonance imaging (MRI) to measure the water content distribution in a polymer electrolyte membrane under fuel cell operation with and without a supply of liquid water. The supply of liquid water to the membrane improved the cell performance by increasing the water content in the membrane and thus reducing the electrical resistance of the membrane. The study also showed that MRI is a promising method to investigate the distribution of water in the membrane of a fuel cell under operating conditions.

  4. Sustainability of Drinking Water Supply Projects in Rural of North ...

    African Journals Online (AJOL)

    Background: Safe water supply coverage in the rural areas of Ethiopia is very marginal. The coverage still remains very low because of limited progress in water supply activities in these areas. Factors affecting the continued use of the outcome of water supply projects in the background of limited resources are not well ...

  5. Application of a sustainability index for integrated urban water ...

    African Journals Online (AJOL)

    Integrated urban water management (IUWM) is that component of IWRM that addresses the impact of urban centres on the nat- ural water cycle. It explores, through appropriate management and concerted action, avenues for improved service delivery. It considers the efficient management of water resources including.

  6. Water and sanitation committees for sustainable service delivery in ...

    African Journals Online (AJOL)

    The achievement of the targets in terms of water and sanitation coverage in Ghana depends to a large extent on the establishment of institutions like Water and Sanitation Committees (WATSAN) for effective operation and maintenance of the water and sanitation facilities. This paper is based on the assessment of WATSAN ...

  7. Water and sanitation committees for sustainable Bruimoh and Jagri

    African Journals Online (AJOL)

    ABSTRACT ~. The achievement of the targets in terms of water and sanitation coverage in Ghana depends to a large extent on the establishment of'institntions like Water and Sanitation Committees (WA TSAN). ' for eflective operation'and maintenance of they water and sanitation facilities. This paper is based.

  8. Determination of water in room temperature ionic liquids by cathodic stripping voltammetry at a gold electrode.

    Science.gov (United States)

    Zhao, Chuan; Bond, Alan M; Lu, Xunyu

    2012-03-20

    An electrochemical method based on cathodic stripping voltammetry at a gold electrode has been developed for the determination of water in ionic liquids. The technique has been applied to two aprotic ionic liquids, (1-butyl-3-ethylimidazolium tetrafluoroborate and 1-butyl-3-methylimidazolium hexafluorophosphate), and two protic ionic liquids, (bis(2-hydroxyethyl)ammonium acetate and triethylammonium acetate). When water is present in an ionic liquid, electrooxidation of a gold electrode forms gold oxides. Thus, application of an anodic potential scan or holding the potential of the electrode at a very positive value leads to accumulation of an oxide film. On applying a cathodic potential scan, a sensitive stripping peak is produced as a result of the reduction of gold oxide back to gold. The magnitude of the peak current generated from the stripping process is a function of the water concentration in an ionic liquid. The method requires no addition of reagents and can be used for the sensitive and in situ determination of water present in small volumes of ionic liquids. Importantly, the method allows the determination of water in the carboxylic acid-based ionic liquids, such as acetate-based protic ionic liquids, where the widely used Karl Fischer titration method suffering from an esterification side reaction which generates water as a side product.

  9. A Framework for Sustainable Urban Water Management through Demand and Supply Forecasting: The Case of Istanbul

    Directory of Open Access Journals (Sweden)

    Murat Yalçıntaş

    2015-08-01

    Full Text Available The metropolitan city of Istanbul is becoming overcrowded and the demand for clean water is steeply rising in the city. The use of analytical approaches has become more and more critical for forecasting the water supply and demand balance in the long run. In this research, Istanbul’s water supply and demand data is collected for the period during 2006 and 2014. Then, using an autoregressive integrated moving average (ARIMA model, the time series water supply and demand forecasting model is constructed for the period between 2015 and 2018. Three important sustainability metrics such as water loss to supply ratio, water loss to demand ratio, and water loss to residential demand ratio are also presented. The findings show that residential water demand is responsible for nearly 80% of total water use and the consumption categories including commercial, industrial, agriculture, outdoor, and others have a lower share in total water demand. The results also show that there is a considerable water loss in the water distribution system which requires significant investments on the water supply networks. Furthermore, the forecasting results indicated that pipeline projects will be critical in the near future due to expected increases in the total water demand of Istanbul. The authors suggest that sustainable management of water can be achieved by reducing the residential water use through the use of water efficient technologies in households and reduction in water supply loss through investments on distribution infrastructure.

  10. Water-saving liquid-gas conditioning system

    Science.gov (United States)

    Martin, Christopher; Zhuang, Ye

    2014-01-14

    A method for treating a process gas with a liquid comprises contacting a process gas with a hygroscopic working fluid in order to remove a constituent from the process gas. A system for treating a process gas with a liquid comprises a hygroscopic working fluid comprising a component adapted to absorb or react with a constituent of a process gas, and a liquid-gas contactor for contacting the working fluid and the process gas, wherein the constituent is removed from the process gas within the liquid-gas contactor.

  11. Rethinking Sustainability, Scaling Up, and Enabling Environment: A Framework for Their Implementation in Drinking Water Supply

    Directory of Open Access Journals (Sweden)

    Urooj Q. Amjad

    2015-04-01

    Full Text Available The terms sustainability, scaling up, and enabling environment are inconsistently used in implementing water supply projects. To clarify these terms we develop a framework based on Normalization Process Theory, and apply the framework to a hypothetical water supply project in schools. The resulting framework provides guidance on how these terms could be implemented and analyzed in water supply projects. We conclude that effective use of the terms sustainability, scaling up, and enabling environment would focus on purpose, process, and perspective. This is the first known attempt to analyze the implementation of the three terms together in the context of water supply services.

  12. Pressurized liquid extraction of ginger (Zingiber officinale Roscoe) with bioethanol: an efficient and sustainable approach.

    Science.gov (United States)

    Hu, Jiajin; Guo, Zheng; Glasius, Marianne; Kristensen, Kasper; Xiao, Langtao; Xu, Xuebing

    2011-08-26

    To develop an efficient green extraction approach for recovery of bioactive compounds from natural plants, we examined the potential of pressurized liquid extraction (PLE) of ginger (Zingiber officinale Roscoe) with bioethanol/water as solvents. The advantages of PLE over other extraction approaches, in addition to reduced time/solvent cost, the extract of PLE showed a distinct constituent profile from that of Soxhlet extraction, with significantly improved recovery of diarylheptanoids, etc. Among the pure solvents tested for PLE, bioethanol yield the highest efficiency for recovering most constituents of gingerol-related compounds; while for a broad concentration spectrum of ethanol aqueous solutions, 70% ethanol gave the best performance in terms of yield of total extract, complete constituent profile and recovery of most gingerol-related components. PLE with 70% bioethanol operated at 1500 psi and 100 °C for 20 min (static extraction time: 5 min) is recommended as optimized extraction conditions, achieving 106.8%, 109.3% and 108.0% yield of [6]-, [8]- and [10]-gingerol relative to the yield of corresponding constituent obtained by 8h Soxhlet extraction (absolute ethanol as extraction solvent). Copyright © 2011 Elsevier B.V. All rights reserved.

  13. Explaining Ionic Liquid Water Solubility in Terms of Cation and Anion Hydrophobicity

    OpenAIRE

    Johannes Ranke; Alaa Othman; Ping Fan; Anja Müller

    2009-01-01

    The water solubility of salts is ordinarily dictated by lattice energy and ion solvation. However, in the case of low melting salts also known as ionic liquids, lattice energy is immaterial and differences in hydrophobicity largely account for differences in their water solubility. In this contribution, the activity coefficients of ionic liquids in water are split into cation and anion contributions by regression against cation hydrophobicity parameters that are experimentally determined by r...

  14. Modeling the liquid-liquid equilibria of water plus fluorocarbons with the cubic-plus-association equation of state

    DEFF Research Database (Denmark)

    Oliveira, Mariana B.; Freire, Mara G.; Marrucho, Isabel M.

    2007-01-01

    dioxide, making them interesting for several biomedical applications. In most of these applications, water or aqueous systems are present for which the knowledge of the mutual solubilities between the fluorocarbons and the aqueous phases is important. In this work, the application of the cubic......-plus-association equation of state (CPA EoS) has been extended to binary mixtures of water with several linear, cyclic, aromatic, and substituted fluorocarbons. The CPA EoS was successfully used to model the liquid-liquid equilibria of aqueous mixtures that contain FCs, while also being able to describe the cross......-association phenomena between substituted and aromatic FCs and water. It is shown that, for aliphatic perfluorocarbons, CPA can be used without any mixture binary parameter to predict the water solubility....

  15. Use of Dispersive Liquid-Liquid Microextraction and UV-Vis Spectrophotometry for the Determination of Cadmium in Water Samples

    Directory of Open Access Journals (Sweden)

    J. Pérez-Outeiral

    2014-01-01

    Full Text Available A simple and inexpensive method for cadmium determination in water using dispersive liquid-liquid microextraction and ultraviolet-visible spectrophotometry was developed. In order to obtain the best experimental conditions, experimental design was applied. Calibration was made in the range of 10–100 μg/L, obtaining good linearity (R2 = 0.9947. The obtained limit of detection based on calibration curve was 8.5 μg/L. Intra- and interday repeatability were checked at two levels, obtaining relative standard deviation values from 9.0 to 13.3%. The enrichment factor had a value of 73. Metal interferences were also checked and tolerable limits were evaluated. Finally, the method was applied to cadmium determination in real spiked water samples. Therefore, the method showed potential applicability for cadmium determination in highly contaminated liquid samples.

  16. Selecting Sustainability Indicators for Small to Medium Sized Urban Water Systems Using Fuzzy-ELECTRE.

    Science.gov (United States)

    Chhipi-Shrestha, Gyan; Hewage, Kasun; Sadiq, Rehan

    2017-03-01

      Urban water systems (UWSs) are challenged by the sustainability perspective. Certain limitations of the sustainability of centralized UWSs and decentralized household level wastewater treatments can be overcome by managing UWSs at an intermediate scale, referred to as small to medium sized UWSs (SMUWSs). SMUWSs are different from large UWSs, mainly in terms of smaller infrastructure, data limitation, smaller service area, and institutional limitations. Moreover, sustainability assessment systems to evaluate the sustainability of an entire UWS are very limited and confined only to large UWSs. This research addressed the gap and has developed a set of 38 applied sustainability performance indicators (SPIs) by using fuzzy-Elimination and Choice Translating Reality (ELECTRE) I outranking method to assess the sustainability of SMUWSs. The developed set of SPIs can be applied to existing and new SMUWSs and also provides a flexibility to include additional SPIs in the future based on the same selection criteria.

  17. Another glimpse over the salting-out assisted liquid-liquid extraction in acetonitrile/water mixtures.

    Science.gov (United States)

    Valente, Inês Maria; Gonçalves, Luís Moreira; Rodrigues, José António

    2013-09-20

    The use of the salting-out effect in analytical chemistry is very diverse and can be applied to increase the volatility of the analytes in headspace extractions, to cause the precipitation of proteins in biological samples or to improve the recoveries in liquid-liquid extractions. In the latter, the salting-out process can be used to create a phase separation between water-miscible organic solvents and water. Salting-out assisted liquid-liquid extraction (SALLE) is an advantageous sample preparation technique aiming HPLC-UV analysis when developing analytical methodologies. In fact, some new extraction methodologies like QuEChERS include the SALLE concept. This manuscript discusses another point of view over SALLE with particular emphasis over acetonitrile-water mixtures for HPLC-UV analysis; the influence of the salting-out agents, their concentration and the water-acetonitrile volume ratios were the studied parameters. α-dicarbonyl compounds and beer were used as test analytes and test samples, respectively. The influence of the studied parameters was characterized by the obtained phase separation volume ratio and the fraction of α-dicarbonyls extracted to the acetonitrile phase. Results allowed the distribution of salts within three groups according to the phase separation and their extractability: (1) chlorides and acetates, (2) carbonates and sulfates and (3) magnesium sulfate; of all tested salts, sodium chloride had the highest influence on the α-dicarbonyls fraction extracted. Copyright © 2013 Elsevier B.V. All rights reserved.

  18. Thermodynamic modeling of ternary and quaternary (liquid + liquid) systems containing water, FeCl3, HCl and diisopropyl ether

    NARCIS (Netherlands)

    Milosevic, M.; Hendriks, I.; Smits, R.E.R.; Schuur, Boelo; de Haan, A.B.

    2013-01-01

    Liquid–liquid extraction using ethers as solvents is a potentially energy saving alternative for the concentration of aqueous ferric chloride solutions. Adequate thermodynamic models that describe the behavior of the resulting quaternary systems (FeCl3, ether, acid and water) are not available in

  19. Spoiling and sustainability: technology, water insecurity, and visibility in Arctic Alaska.

    Science.gov (United States)

    Eichelberger, Laura

    2014-01-01

    One third of households in Alaska Native villages lack running water and sewer services. Historically, this public health need drove policies to improve access to treated water and sanitation. However, despite public health being a stated priority of water infrastructure development, current policies require demonstrated economic sustainability in ways that render suffering from water insecurity invisible. In this article, I situate the introduction of water treatment technologies within the history of domination coproduced with vulnerability. These processes are reflected in local narratives describing the relationships between technology, tradition, and suffering. By drawing attention to the role of the state in creating vulnerability, village leaders are trying to historicize and insert their health concerns into the sustainability conversation using narratives that both fit within and challenge the ideology of sustainability. These narratives are thus central to Iñupiat struggles for visibility.

  20. An analysis of the allocation of Yakima River water in terms of sustainability and economic efficiency.

    Science.gov (United States)

    Hillman, Brett; Douglas, Ellen M; Terkla, David

    2012-07-30

    Decades of agricultural growth has led to the over appropriation of Yakima water and the ecological integrity of the Basin has been compromised. We evaluate the impact of current water allocation on the natural flow regime of the Yakima River using the Indicators of Hydrologic Alteration/Range of Variability Analysis and by quantifying indicators of ecosurplus and ecodeficit. We analyze the sustainability of the current water allocation scheme based on a range of sustainability criteria, from weak to strong to environmentally sustainable. Economic efficiency is assessed by describing the current allocation framework and suggesting ways to make it more efficient. Our IHA/RVA analysis suggests that the allocation of water in the Yakima River has resulted in a highly altered flow regime. Ecodeficit is far in excess of ecosurplus. We conclude that this allocation scheme is weakly sustainable, if sustainable at all, in its current framework. The allocation of water is also not economically efficient and we suggest that a reallocation of water rights may be necessary in order to achieve this objective. The creation of water markets to stimulate voluntary water rights transactions is the best way to approach economic efficiency. The first step would be to extend beneficial use requirements to include instream flows, which would essentially allow individuals to convert offstream rights into instream rights. The Washington trust water rights program was implemented as a means of creating a water market, which has contributed to the protection of instream flows, however more needs to be done to create an ideal water rights market so that rights migrate to higher valued uses, many of which are met instream. However, water markets will likely not solve the Yakima's water allocation problems alone; some degree of regulation may still be necessary. Copyright © 2012 Elsevier Ltd. All rights reserved.

  1. Revisiting a many-body model for water based on a single polarizable site: from gas phase clusters to liquid and air/liquid water systems.

    Science.gov (United States)

    Réal, Florent; Vallet, Valérie; Flament, Jean-Pierre; Masella, Michel

    2013-09-21

    We present a revised version of the water many-body model TCPE [M. Masella and J.-P. Flament, J. Chem. Phys. 107, 9105 (1997)], which is based on a static three charge sites and a single polarizable site to model the molecular electrostatic properties of water, and on an anisotropic short range many-body energy term specially designed to accurately model hydrogen bonding in water. The parameters of the revised model, denoted TCPE/2013, are here developed to reproduce the ab initio energetic and geometrical properties of small water clusters (up to hexamers) and the repulsive water interactions occurring in cation first hydration shells. The model parameters have also been refined to reproduce two liquid water properties at ambient conditions, the density and the vaporization enthalpy. Thanks to its computational efficiency, the new model range of applicability was validated by performing simulations of liquid water over a wide range of temperatures and pressures, as well as by investigating water liquid/vapor interfaces over a large range of temperatures. It is shown to reproduce several important water properties at an accurate enough level of precision, such as the existence liquid water density maxima up to a pressure of 1000 atm, the water boiling temperature, the properties of the water critical point (temperature, pressure, and density), and the existence of a "singularity" temperature at about 225 K in the supercooled regime. This model appears thus to be particularly well-suited for characterizing ion hydration properties under different temperature and pressure conditions, as well as in different phases and interfaces.

  2. Nitrolimegation: A Nutrient-In-Water Resource for Sustainable Crop ...

    African Journals Online (AJOL)

    Two types of nitrogenous fertilizer sources [Urea and liquid pig manure (LPM)] and two types of lime [limestone-CaCO3 and slake lime-Ca(OH)2] were employed variously at the following levels: Urea [CO (NH2)2] 0, 40, 50, 80, 100, 120, and 150 kg/ha; lime 0, 0.1, 0.3, 0.5, 1.0, 5.0, and 10.0 metric tonnes per hectare (t/ha) ...

  3. Journal of Sustainable Development of Energy, Water and Environment Systems - Volume II

    Directory of Open Access Journals (Sweden)

    Neven Duić

    2014-12-01

    Full Text Available The Journal of Sustainable Development of Energy, Water and Environment Systems – JSDEWES is an international journal dedicated to the improvement and dissemination of knowledge on methods, policies and technologies for increasing the sustainability of development by de-coupling growth from natural resources and replacing them with knowledge based economy, taking into account its economic, environmental and social pillars, as well as methods for assessing and measuring sustainability of development, regarding energy, transport, water, environment and food production systems and their many combinations. In total 32 manuscripts were published in Volume II, all of them reviewed by at least two reviewers. The Journal of Sustainable Development of Energy, Water and Environment Systems would like to thank reviewers for their contribution to the quality of the published manuscripts.

  4. Chloride reduction from brackish water by supported liquid membranes using ionic liquids as carriers

    OpenAIRE

    Benito, Sergi; Fortuny Sanromá, Agustín; Coll Ausió, Mª Teresa; Sastre Requena, Ana María

    2012-01-01

    The desalinization of the continental waters is one of the actual challenges on supplying water requirements. Water with high contents in salts is inadequate for drinking water and irrigation uses. In the industry this water involves additional conditioning steps. Salinity in water can determine the aquatic ecosystem and the life of the pants. High concentration of chloride in continental water is a great problem for the exploitation of these natural resources. In general, Cl- in water can be...

  5. Sustainable Water Systems for the City of Tomorrow—A Conceptual Framework

    Directory of Open Access Journals (Sweden)

    Xin (Cissy Ma

    2015-09-01

    Full Text Available Urban water systems are an example of complex, dynamic human–environment coupled systems which exhibit emergent behaviors that transcend individual scientific disciplines. While previous siloed approaches to water services (i.e., water resources, drinking water, wastewater, and stormwater have led to great improvements in public health protection, sustainable solutions for a growing global population facing increased resource constraints demand a paradigm shift based on holistic management to maximize the use and recovery of water, energy, nutrients, and materials. The objective of this review paper is to highlight the issues in traditional water systems including water demand and use, centralized configuration, sewer collection systems, characteristics of mixed wastewater, and to explore alternative solutions such as decentralized water systems, fit for purpose and water reuse, natural/green infrastructure, vacuum sewer collection systems, and nutrient/energy recovery. This review also emphasizes a system thinking approach for evaluating alternatives that should include sustainability indicators and metrics such as emergy to assess global system efficiency. An example paradigm shift design for urban water system is presented, not as the recommended solution for all environments, but to emphasize the framework of system-level analysis and the need to visualize water services as an organic whole. When water systems are designed to maximize the resources and optimum efficiency, they are more prevailing and sustainable than siloed management because a system is more than the sum of its parts.

  6. Deficit irrigation and sustainable water-resource strategies in agriculture for China's food security.

    Science.gov (United States)

    Du, Taisheng; Kang, Shaozhong; Zhang, Jianhua; Davies, William J

    2015-04-01

    More than 70% of fresh water is used in agriculture in many parts of the world, but competition for domestic and industrial water use is intense. For future global food security, water use in agriculture must become sustainable. Agricultural water-use efficiency and water productivity can be improved at different points from the stomatal to the regional scale. A promising approach is the use of deficit irrigation, which can both save water and induce plant physiological regulations such as stomatal opening and reproductive and vegetative growth. At the scales of the irrigation district, the catchment, and the region, there can be many other components to a sustainable water-resources strategy. There is much interest in whether crop water use can be regulated as a function of understanding of physiological responses. If this is the case, then agricultural water resources can be reallocated to the benefit of the broader community. We summarize the extent of use and impact of deficit irrigation within China. A sustainable strategy for allocation of agricultural water resources for food security is proposed. Our intention is to build an integrative system to control crop water use during different cropping stages and actively regulate the plant's growth, productivity, and development based on physiological responses. This is done with a view to improving the allocation of limited agricultural water resources. © The Author 2015. Published by Oxford University Press on behalf of the Society for Experimental Biology. All rights reserved. For permissions, please email: journals.permissions@oup.com.

  7. Deficit irrigation and sustainable water-resource strategies in agriculture for China’s food security

    Science.gov (United States)

    Du, Taisheng; Kang, Shaozhong; Zhang, Jianhua; Davies, William J.

    2015-01-01

    More than 70% of fresh water is used in agriculture in many parts of the world, but competition for domestic and industrial water use is intense. For future global food security, water use in agriculture must become sustainable. Agricultural water-use efficiency and water productivity can be improved at different points from the stomatal to the regional scale. A promising approach is the use of deficit irrigation, which can both save water and induce plant physiological regulations such as stomatal opening and reproductive and vegetative growth. At the scales of the irrigation district, the catchment, and the region, there can be many other components to a sustainable water-resources strategy. There is much interest in whether crop water use can be regulated as a function of understanding of physiological responses. If this is the case, then agricultural water resources can be reallocated to the benefit of the broader community. We summarize the extent of use and impact of deficit irrigation within China. A sustainable strategy for allocation of agricultural water resources for food security is proposed. Our intention is to build an integrative system to control crop water use during different cropping stages and actively regulate the plant’s growth, productivity, and development based on physiological responses. This is done with a view to improving the allocation of limited agricultural water resources. PMID:25873664

  8. Explaining Ionic Liquid Water Solubility in Terms of Cation and Anion Hydrophobicity

    Science.gov (United States)

    Ranke, Johannes; Othman, Alaa; Fan, Ping; Müller, Anja

    2009-01-01

    The water solubility of salts is ordinarily dictated by lattice energy and ion solvation. However, in the case of low melting salts also known as ionic liquids, lattice energy is immaterial and differences in hydrophobicity largely account for differences in their water solubility. In this contribution, the activity coefficients of ionic liquids in water are split into cation and anion contributions by regression against cation hydrophobicity parameters that are experimentally determined by reversed phase liquid chromatography. In this way, anion hydrophobicity parameters are derived, as well as an equation to estimate water solubilities for cation-anion combinations for which the water solubility has not been measured. Thus, a new pathway to the quantification of aqueous ion solvation is shown, making use of the relative weakness of interactions between ionic liquid ions as compared to their hydrophobicities. PMID:19399248

  9. Explaining ionic liquid water solubility in terms of cation and anion hydrophobicity.

    Science.gov (United States)

    Ranke, Johannes; Othman, Alaa; Fan, Ping; Müller, Anja

    2009-03-01

    The water solubility of salts is ordinarily dictated by lattice energy and ion solvation. However, in the case of low melting salts also known as ionic liquids, lattice energy is immaterial and differences in hydrophobicity largely account for differences in their water solubility. In this contribution, the activity coefficients of ionic liquids in water are split into cation and anion contributions by regression against cation hydrophobicity parameters that are experimentally determined by reversed phase liquid chromatography. In this way, anion hydrophobicity parameters are derived, as well as an equation to estimate water solubilities for cation-anion combinations for which the water solubility has not been measured. Thus, a new pathway to the quantification of aqueous ion solvation is shown, making use of the relative weakness of interactions between ionic liquid ions as compared to their hydrophobicities.

  10. Explaining Ionic Liquid Water Solubility in Terms of Cation and Anion Hydrophobicity

    Directory of Open Access Journals (Sweden)

    Johannes Ranke

    2009-03-01

    Full Text Available The water solubility of salts is ordinarily dictated by lattice energy and ion solvation. However, in the case of low melting salts also known as ionic liquids, lattice energy is immaterial and differences in hydrophobicity largely account for differences in their water solubility. In this contribution, the activity coefficients of ionic liquids in water are split into cation and anion contributions by regression against cation hydrophobicity parameters that are experimentally determined by reversed phase liquid chromatography. In this way, anion hydrophobicity parameters are derived, as well as an equation to estimate water solubilities for cation-anion combinations for which the water solubility has not been measured. Thus, a new pathway to the quantification of aqueous ion solvation is shown, making use of the relative weakness of interactions between ionic liquid ions as compared to their hydrophobicities.

  11. New method for vitrifying water and other liquids by rapid cooling of their aerosols

    Science.gov (United States)

    Mayer, Erwin

    1985-07-01

    A method for the vitrification of pure liquid water and dilute aqueous solutions is described which is the only one without a liquid cryomedium for heat transfer: rapid cooling of aqueous aerosol droplets on a solid cryoplate. This method is not limited to water and aqueous solutions, but can be used for the vitrification of any liquid aerosol, the only impurity being some codeposited vapor. The method can be applied in diverse fields such as cryobiology, cryomicroscopy, and low-temperature spectroscopy of water and dilute aqueous solutions to avoid the formation of crystalline ice.

  12. Application of a sustainability index for integrated urban water ...

    African Journals Online (AJOL)

    ice for water supply were based on the WHO Guidelines for. Access to Water Supply (Howard and Bartram, .... a minimum of 25 ℓ/cap∙d within a cartage distance of 200m, and a VIP latrine per household); 70% have ... ice that is responsive to issues such as low pressure, leaks and blockages. In response to ever-increasing ...

  13. Water resource co-management and sustainable regional development

    NARCIS (Netherlands)

    Boer, C.L.; Bressers, Johannes T.A.

    2013-01-01

    Purpose – Given the importance of multi-stakeholder processes in managing water resources, this paper aims to shed light on various project management strategies being used in The Netherlands to increase the effectiveness and efficiency of implementing multifunctional water projects.

  14. Integrated Water Management Approaches for Sustainable Food Production

    NARCIS (Netherlands)

    Fraiture, de C.M.S.; Fayrap, A.; Unver, O.; Ragab, R.

    2014-01-01

    With a growing and increasingly wealthy and urban population, it is likely that the role of agricultural water management in ensuring food security will become more important. Pressure on water resources is high. Adverse environmental impacts as a result of sometimes poor management of irrigation

  15. Sustainable Urban Water and Wastewater Services: The TRUST Approach

    Science.gov (United States)

    The TRUST (Transitions to the Urban Water Services of Tomorrow) Project is a research program funded by the European Union Seventh Framework Programme. The overall objective of TRUST is to help water and wastewater authorities and utilities across Europe to formulate and impleme...

  16. The structure of graphene oxide membranes in liquid water, ethanol and water-ethanol mixtures.

    Science.gov (United States)

    Talyzin, Alexandr V; Hausmaninger, Tomas; You, Shujie; Szabó, Tamás

    2014-01-07

    The structure of graphene oxide (GO) membranes was studied in situ in liquid solvents using synchrotron radiation X-ray diffraction in a broad temperature interval. GO membranes are hydrated by water similarly to precursor graphite oxide powders but intercalation of alcohols is strongly hindered, which explains why the GO membranes are permeated by water and not by ethanol. Insertion of ethanol into the membrane structure is limited to only one monolayer in the whole studied temperature range, in contrast to precursor graphite oxide powders, which are intercalated with up to two ethanol monolayers (Brodie) and four ethanol monolayers (Hummers). As a result, GO membranes demonstrate the absence of "negative thermal expansion" and phase transitions connected to insertion/de-insertion of alcohols upon temperature variations reported earlier for graphite oxide powders. Therefore, GO membranes are a distinct type of material with unique solvation properties compared to parent graphite oxides even if they are composed of the same graphene oxide flakes.

  17. Socio-hydrology: Use-inspired water sustainability science for the Anthropocene

    Science.gov (United States)

    Sivapalan, M.; Konar, M.; Srinivasan, V.; Chhatre, A.; Wutich, A.; Scott, C. A.; Wescoat, J. L.; Rodríguez-Iturbe, I.

    2014-04-01

    Water is at the core of the most difficult sustainability challenges facing humans in the modern era, involving feedbacks across multiple scales, sectors, and agents. We suggest that a transformative new discipline is necessary to address many and varied water-related challenges in the Anthropocene. Specifically, we propose socio-hydrology as a use-inspired scientific discipline to focus on understanding, interpretation, and scenario development of the flows and stocks in the human-modified water cycle across time and space scales. A key aspect of socio-hydrology is explicit inclusion of two-way feedbacks between human and water systems, which differentiates socio-hydrology from other inter-disciplinary disciplines dealing with water. We illustrate the potential of socio-hydrology through three examples of water sustainability problems, defined as paradoxes, which can only be fully resolved within a new socio-hydrologic framework that encompasses such two-way coupling between human and water systems.

  18. Innovative Sustainable Water Management Practices in Solar Residential Design

    Directory of Open Access Journals (Sweden)

    C. Jason Mabry

    2012-11-01

    Full Text Available This paper communicates the results of an architectural research project which sought innovative design strategies for achieving energy and resource efficiencies in water management systems traditionally used in single-family housing. It describes the engineering of an efficient, multifaceted, and fully integrated water management system for a domesticenvironment of 800 sq. ft., entirely powered by solar energy. The four innovations whose details are conveyed include the use of alternate materials for piping distribution and collection, the use of water in solar energy generation, the design of a building skin which capitalizes on water’s capacity to store heat as well as the design of a ecological groundscape which re-usesand filters waste water and rain water.Keywords: energy, plumbing, home design

  19. On the collective network of ionic liquid/water mixtures. IV. Kinetic and rotational depolarization.

    Science.gov (United States)

    Schröder, Christian; Sega, Marcello; Schmollngruber, Michael; Gailberger, Elias; Braun, Daniel; Steinhauser, Othmar

    2014-05-28

    Dielectric spectroscopy is a measure of the collective Coulomb interaction in liquid systems. Adding ionic liquids to an aqueous solution results in a decrease of the static value of the generalized dielectric constant which cannot be attributed to kinetic depolarization models characterized by the static conductivity and rotational relaxation constant. However, a dipolar Poisson-Boltzmann model computing the water depolarization in the proximity of ions is not only successful for simple electrolytes but also in case of molecular ionic liquids. Moreover, our simple geometric hydration model is also capable to explain the dielectric depolarization. Both models compute the dielectric constant of water and obtain the overall dielectric constant by averaging the values of its components, water and the ionic liquid, weighted by their volume occupancies. In this sense, aqueous ionic liquid mixtures seem to behave like polar mixtures.

  20. Liquid-Liquid Equilibrium data for mono ethylene glycol extraction from water with the new ionic liquid tetraoctyl ammonium 2-methyl-1-naphtoate as solvent

    NARCIS (Netherlands)

    Garcia Chavez, L.Y.; Schuur, Boelo; de Haan, A.B.

    2012-01-01

    Thermal recovery of mono ethylene glycol (MEG) from aqueous streams is one of the most energy demanding operations in industry, because of the large amount of water that needs to be evaporated. The use of alternative technologies such as liquid–liquid extraction could save energy. A new tailor made

  1. Supercooled and glassy water: Metastable liquid(s), amorphous solid(s), and a no-man's land

    Science.gov (United States)

    Handle, Philip H.; Loerting, Thomas; Sciortino, Francesco

    2017-12-01

    We review the recent research on supercooled and glassy water, focusing on the possible origins of its complex behavior. We stress the central role played by the strong directionality of the water–water interaction and by the competition between local energy, local entropy, and local density. In this context we discuss the phenomenon of polyamorphism (i.e., the existence of more than one disordered solid state), emphasizing both the role of the preparation protocols and the transformation between the different disordered ices. Finally, we present the ongoing debate on the possibility of linking polyamorphism with a liquid–liquid transition that could take place in the no-man's land, the temperature–pressure window in which homogeneous nucleation prevents the investigation of water in its metastable liquid form.

  2. Transforming landscapes, transforming lives : the business of sustainable water buffer management

    NARCIS (Netherlands)

    Steenbergen, van F.; Tuinhof, A.; Knoop, L.; Kauffman, J.H.

    2011-01-01

    This book is about sustainable land management, the development of water buffers and the business case underneath it. It is part of the discussion on the green economy: investment in natural resource management makes business sense. This also applies for investment in land, water and vegetative

  3. Amsterdam as a Sustainable European Metropolis : Integration of Water, Energy and Material Flows

    NARCIS (Netherlands)

    Van Der Hoek, J.P.; Struker, A.; Danschutter, J.E.M.

    2013-01-01

    Amsterdam has the ambition to develop as a competitive and sustainable European metropolis. The flows of energy, water and resources within the urban environment have a large potential to contribute to this ambition. The overall mass balances of phosphate, food, water, energy and material imports in

  4. A global survey of urban water tariffs: are they sustainable, efficient and fair?

    NARCIS (Netherlands)

    Zetland, D.J.; Gasson, C.

    2013-01-01

    This paper examines the relations between tariffs and sustainability, efficiency and equity, using a unique data-set for 308 cities in 102 countries. Higher water tariffs are correlated with lower per capita consumption, smaller local populations, lower water availability, higher demand and a lower

  5. Argentina - Water Resources Management : Policy Elements for Sustainable Development in the 21st Century, Main Report

    OpenAIRE

    World Bank

    2000-01-01

    The study reviews the challenges water resources management faces, and the opportunities for policy formulation towards sustainable development in Argentina, where regardless of prudent public finances management, water resources management remain disproportionately backward compared to regional, and international best practices. Hence, within a frame of reference on the country's populati...

  6. Scalar alignment and sustainable water governance: The case of irrigated agriculture in Turkey

    NARCIS (Netherlands)

    Özerol, Gül; Bressers, Johannes T.A.

    2015-01-01

    Irrigated agriculture plays a significant role in global food security and poverty reduction. At the same time its negative impacts on water and land resources threaten environmental sustainability. With the objective of improving the understanding on the complexity of governing water resources for

  7. PREDICTING SUSTAINABLE GROUND WATER TO CONSTRUCTED RIPARIAN WETLANDS: SHAKER TRACE, OHIO, USA

    Science.gov (United States)

    Water isotopy is introduced as a best management practice for the prediction of sustained ground water inflows to prospective constructed wetlands. A primer and application of the stable isotopes, 18O and 2H, are discussed for riparian wetland restoration ar...

  8. Ethnographic Approaches to Understanding Social Sustainability in Small-scale Water Systems

    Science.gov (United States)

    Wutich, A.

    2011-12-01

    Social sustainability is an important, but often neglected, aspect of determining the success of small-scale water systems. This paper reviews ethnographic approaches for understanding how indigenous knowledge enhances social sustainability of small-scale water systems, particularly in small-scale water systems threatened by water scarcity. After reviewing the literature on common-pool and traditional resource management strategies, the paper will focus on the case of a community-managed small-scale water system in Cochabamba, Bolivia. This study uses ethnographic evidence to demonstrate how indigenous institutions can be used to manage a small-scale urban water system sustainably. Several factors were crucial to the institution's success. First, indigenous residents had previous experience with common management of rural irrigation systems which they were able to adapt for use in an urban environment. Second, institutional rules were designed to prioritize the conservation of the water source. Third, indigenous Andean social values of uniformity, regularity, and transparency ensured that community members perceived the system as legitimate and complied with community rules. Fourth, self-governance enabled community members to quickly adapt to changing environmental conditions, such as seasonal scarcity and groundwater overdraft. The paper concludes with a discussion of the promise and limitations of ethnographic approaches and indigenous knowledge for understanding social sustainability in small-scale water systems.

  9. Towards Sustainable Urban Water and Sanitation Services: Barriers and Bridges

    Directory of Open Access Journals (Sweden)

    Peder Hjorth

    2009-11-01

    Full Text Available The Mar del Plata International Water Conference provided the first global assessment of the water sector. It was found that in most developing countries the state of water supply and sanitation services were deplorable. Consequently, a call for concerted action to improve coverage and efficiency of the water supply and sanitation sector was launched. This call resulted in the International Water Supply and Sanitation Decade (1981–1990. The Decade provided important lessons concerning effective methodologies to improve the state of the WSS sector. The paper discusses why the poor state of the water supply and sanitation conditions still tend to be the greatest development failure during the 20th century. The recipe for success was there, and the money was there. So, why were governments and big donors like the World Bank refusing to apply the lessons from the Decade? The basic conditions for success are spelled out, and some successful cases are used to illustrate these. The conclusion is that change is possible but that civil society organizations have to be empowered to make governments "feel the heat" and spend more money on water and sanitation, and to spend it more wisely.

  10. Sustainable land and water management of River Oases along the Tarim River

    Directory of Open Access Journals (Sweden)

    M. Disse

    2016-05-01

    Full Text Available The Tarim Basin in Xinjiang province in northwest China is characterized by a hyper arid climate. Climate change and a strong increase in agricultural land use are major challenges for sustainable water management. The largest competition for water resources exists between irrigated fields and natural riparian vegetation, which is dependent on seasonal flooding of the Tarim River. In addition to numerous water management measures implemented by the Chinese government, the Sino-German project SuMaRiO (Sustainable Management of River Oases along the Tarim River provided a decision support system based on ecosystem services for the Chinese stakeholders. This tool will help to implement sustainable land and water management measures in the next 5-year plan.

  11. Primitive Liquid Water of the Solar System in an Aqueous Altered Carbonaceous Chondrite

    Science.gov (United States)

    Tsuchiyama, A.; Miyake, A.; Kitayama, A.; Matsuno, J.; Takeuchi, A.; Uesugi, K.; Suzuki, Y.; Nakano, T.; Zolensky, M. E.

    2016-01-01

    Non-destructive 3D observations of the aqueous altered CM chondrite Sutter's Mill using scanning imaging x-ray microscopy (SIXM) showed that some of calcite and enstatite grains contain two-phase inclusion, which is most probably composed of liquid water and bubbles. This water should be primitive water responsible for aqueous alteration in an asteroid in the early solar system.

  12. Urban stormwater – greywater management system for sustainable urban water management at sub-watershed level

    Directory of Open Access Journals (Sweden)

    Arora Amarpreet Singh

    2017-01-01

    Full Text Available Urban water management involves urban water supply (import, treatment and distribution of water, urban wastewater management (collection, treatment and disposal of urban sewage and urban storm water management. Declining groundwater tables, polluted and declining sources of water, water scarcity in urban areas, unsatisfactory urban water supply and sanitation situation, pollution of receiving water bodies (including the ground water, and urban floods have become the concerns and issues of sustainable urban water management. This paper proposes a model for urban stormwater and sewage management which addresses these concerns and issues of sustainable urban water management. This model proposes segregation of the sewage into black water and greywater, and urban sub-watershed level stormwater-greywater management systems. During dry weather this system will be handling only the greywater and making the latter available as reclaimed water for reuse in place of the fresh water supply. During wet weather, the system will be taking care of (collection and treatment both the storm water and the greywater, and the excess of the treated water will be disposed off through groundwater recharging. Application of this model in the Patiala city, Punjab, INDIA for selected urban sub-watersheds has been tried. Information and background data required for the conceptualization and design of the sub-watershed level urban stormwater-greywater management system was collected and the system has been designed for one of the sub-watersheds in the Patiala city. In this paper, the model for sustainable urban water management and the design of the Sub-watershed level Urban Stormwater-Greywater Management System are described.

  13. Urban stormwater - greywater management system for sustainable urban water management at sub-watershed level

    Science.gov (United States)

    Singh Arora, Amarpreet

    2017-11-01

    Urban water management involves urban water supply (import, treatment and distribution of water), urban wastewater management (collection, treatment and disposal of urban sewage) and urban storm water management. Declining groundwater tables, polluted and declining sources of water, water scarcity in urban areas, unsatisfactory urban water supply and sanitation situation, pollution of receiving water bodies (including the ground water), and urban floods have become the concerns and issues of sustainable urban water management. This paper proposes a model for urban stormwater and sewage management which addresses these concerns and issues of sustainable urban water management. This model proposes segregation of the sewage into black water and greywater, and urban sub-watershed level stormwater-greywater management systems. During dry weather this system will be handling only the greywater and making the latter available as reclaimed water for reuse in place of the fresh water supply. During wet weather, the system will be taking care of (collection and treatment) both the storm water and the greywater, and the excess of the treated water will be disposed off through groundwater recharging. Application of this model in the Patiala city, Punjab, INDIA for selected urban sub-watersheds has been tried. Information and background data required for the conceptualization and design of the sub-watershed level urban stormwater-greywater management system was collected and the system has been designed for one of the sub-watersheds in the Patiala city. In this paper, the model for sustainable urban water management and the design of the Sub-watershed level Urban Stormwater-Greywater Management System are described.

  14. Regulation of water resources for sustaining global future socioeconomic development

    Science.gov (United States)

    Chen, J.; SHI, H.; Sivakumar, B.

    2016-12-01

    With population projections indicating continued growth during this century, socio-economic problems (e.g., water, food, and energy shortages) will be most likely to occur, especially if proper planning, development, and management strategies are not adopted. In the present study, firstly, we explore the vital role of dams in promoting economic growth through analyzing the relationship between dams and Gross Domestic Product (GDP) at both global and national scales. Secondly, we analyze the current situation of global water scarcity based on the data representing water resources availability, dam development, and the level of economic development. Third, with comprehensive consideration of population growth as the major driving force, water resources availability as the basic supporting factor, and topography as the important constraint, this study addresses the question of dam development in the future and predicts the locations of future dams around the world.

  15. Engaging Southwestern Tribes in Sustainable Water Resources Topics and Management

    Directory of Open Access Journals (Sweden)

    Karletta Chief

    2016-08-01

    Full Text Available Indigenous peoples in North America have a long history of understanding their societies as having an intimate relationship with their physical environments. Their cultures, traditions, and identities are based on the ecosystems and sacred places that shape their world. Their respect for their ancestors and ‘Mother Earth’ speaks of unique value and knowledge systems different than the value and knowledge systems of the dominant United States settler society. The value and knowledge systems of each indigenous and non-indigenous community are different but collide when water resources are endangered. One of the challenges that face indigenous people regarding the management of water relates to their opposition to the commodification of water for availability to select individuals. External researchers seeking to work with indigenous peoples on water research or management must learn how to design research or water management projects that respect indigenous cultural contexts, histories of interactions with settler governments and researchers, and the current socio-economic and political situations in which indigenous peoples are embedded. They should pay particular attention to the process of collaborating on water resource topics and management with and among indigenous communities while integrating Western and indigenous sciences in ways that are beneficial to both knowledge systems. The objectives of this paper are to (1 to provide an overview of the context of current indigenous water management issues, especially for the U.S. federally recognized tribes in the Southwestern United States; (2 to synthesize approaches to engage indigenous persons, communities, and governments on water resources topics and management; and (3 to compare the successes of engaging Southwestern tribes in five examples to highlight some significant activities for collaborating with tribes on water resources research and management. In discussing the engagement

  16. Study of sustainable production in two-phase liquid dominated with steam cap underlying brine reservoir by numerical simulation

    Science.gov (United States)

    Pratama, Heru Berian; Miryani Saptadji, Nenny

    2017-12-01

    The main issue in the management of the two-phase liquid-dominated geothermal field is rapid decline pressure in the reservoir so that the supply of steam to the power plant cannot be fulfilled. To understanding that, modelling and numerical simulation used reservoir simulators. The model is developed on liquid-dominated geothermal fields are assessed in various scenarios of production strategies (focusing only steam cap, brine reservoir and a combination) and injection strategies (deep and shallow injection, centered and dispersed injection), with the calculation using separated steam cycle method. The simulation results of the model for sustainable production are production 25% from steam cap + 75% from brine reservoir, dispersed and deep reinjection with make-up wells from steam cap results 9 make-up well number. The implementation of production-injection strategy needs to be planned right from the beginning of exploitation so that the strategy can adapt to changes in reservoir characteristics.

  17. The reactivity of Cymbidium hybridum protocorms, sustained on luffa ligno-skeleton in vitrocultures in liquid media

    Directory of Open Access Journals (Sweden)

    Ildiko SZABO

    2007-05-01

    Full Text Available Is known the fact that the Cymbidium hybridum orchid protocorms, submersed in liquid culture medium (in hypoxia conditions himself multiply with higher speed in comparison to aerated condition, on surface of agarized (solid culture media. Also, is known the fact that the Luffa ligno-skeleton (obtained from ripe pulp of Luffa cilindrica fruits lends successfully at its usage as wick in supply with nutrients of various plant species inoculs, cultivated “in vitro” on liquid media. In this work, we are presenting the role of Luffa ligno-skeleton in maintaining the Cymbidium hybridum protocorms, cultivated “in vitro”, on culture medium liquid surface (type of Murashige-Skoog, 1962.Behind these experiments, was proved that the ligno-skeleton of Luffa type of bridges for Cymbidium hybridum protocorms, sustained in aerated condition, is more efficient in bearing with those marked on solid culture medium, as in number, as in accumulation of fresh and dry weight, regardless of growth regulators included in media; on liquid culture media containing 1 mg/l AIB or 2 mg/l K as growth regulators, where bearing with the homologue culture variant (solidified media with agar-agar, with same mineral and organic composition, the differences was until 29.3% superior, and bearing with the witness medium (solid – agarized – medium, but without growth regulators until 30.2% biggest, concerning the number of protocorms.

  18. Recycling acetic acid from polarizing film of waste liquid crystal display panels by sub/supercritical water treatments.

    Science.gov (United States)

    Wang, Ruixue; Chen, Ya; Xu, Zhenming

    2015-05-19

    Waste liquid crystal display (LCD) panels mainly contain inorganic materials (glass substrate) and organic materials (polarizing film and liquid crystal). The organic materials should be removed first since containing polarizing film and liquid crystal is to the disadvantage of the indium recycling process. In the present study, an efficient and environmentally friendly process to obtain acetic acid from waste LCD panels by sub/supercritical water treatments is investigated. Furthermore, a well-founded reaction mechanism is proposed. Several highlights of this study are summarized as follows: (i) 99.77% of organic matters are removed, which means the present technology is quite efficient to recycle the organic matters; (ii) a yield of 78.23% acetic acid, a quite important fossil energy based chemical product is obtained, which can reduce the consumption of fossil energy for producing acetic acid; (iii) supercritical water acts as an ideal solvent, a requisite reactant as well as an efficient acid-base catalyst, and this is quite significant in accordance with the "Principles of Green Chemistry". In a word, the organic matters of waste LCD panels are recycled without environmental pollution. Meanwhile, this study provides new opportunities for alternating fossil-based chemical products for sustainable development, converting "waste" into "fossil-based chemicals".

  19. Design of a process for supercritical water desalination with zero liquid discharge

    NARCIS (Netherlands)

    Odu, Samuel Obarinu; van der Ham, Aloysius G.J.; Metz, S.; Kersten, Sascha R.A.

    2015-01-01

    Conventional desalination methods have a major drawback; the production of a liquid waste stream which must be disposed. The treatment of this waste stream has always presented technical, economic, and environmental challenges. The supercritical water desalination (SCWD) process meets these

  20. Evidence of the Existence of the Low-Density Liquid Phase in Supercooled, Confined Water

    National Research Council Canada - National Science Library

    Francesco Mallamace; Matteo Broccio; Carmelo Corsaro; Antonio Faraone; Domenico Majolino; Valentina Venuti; Li Liu; Chung-Yuan Mou; Sow-Hsin Chen

    2007-01-01

    By confining water in a nanoporous structure so narrow that the liquid could not freeze, it is possible to study properties of this previously undescribed system well below its homogeneous nucleation temperature $T_{H}=231$ K...

  1. Scanning Multichannel Microwave Radiometer (SMMR) Monthly Mean Atmospheric Liquid Water (ALW) By Prabhakara

    Data.gov (United States)

    National Aeronautics and Space Administration — SMMR_ALW_PRABHAKARA data are Special Multichannel Microwave Radiometer (SMMR) Monthly Mean Atmospheric Liquid Water (ALW) data by Prabhakara.The Prabhakara Scanning...

  2. On the implications of aerosol liquid water and phase separation for organic aerosol mass

    Data.gov (United States)

    U.S. Environmental Protection Agency — This dataset contains data presented in the figures of the paper "On the implications of aerosol liquid water and phase separation for organic aerosol mass"...

  3. Isobaric first-principles molecular dynamics of liquid water with nonlocal van der Waals interactions

    CERN Document Server

    Miceli, Giacomo; Pasquarello, Alfredo

    2016-01-01

    We investigate the structural properties of liquid water at near ambient conditions using first-principles molecular dynamics simulations based on a semilocal density functional augmented with nonlocal van der Waals interactions. The adopted scheme offers the advantage of simulating liquid water at essentially the same computational cost of standard semilocal functionals. Applied to the water dimer and to ice Ih, we find that the hydrogen-bond energy is only slightly enhanced compared to a standard semilocal functional. We simulate liquid water through molecular dynamics in the NpH statistical ensemble allowing for fluctuations of the system density. The structure of the liquid departs from that found with a semilocal functional leading to more compact structural arrangements. This indicates that the directionality of the hydrogen-bond interaction has a diminished role as compared to the overall attractions, as expected when dispersion interactions are accounted for. This is substantiated through a detailed a...

  4. Thermal Conductivity of Liquid Water from Reverse Nonequilibrium Ab Initio Molecular Dynamics

    Science.gov (United States)

    Tsuchida, Eiji

    2018-02-01

    We report on a theoretical framework for calculating the thermal conductivity of liquid water from first principles with the aid of the linear scaling method. We also discuss the possibility of obtaining equilibrium properties from a nonequilibrium trajectory.

  5. Ab initio calculation of the electronic absorption spectrum of liquid water

    Energy Technology Data Exchange (ETDEWEB)

    Martiniano, Hugo F. M. C.; Galamba, Nuno [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Cabral, Benedito J. Costa, E-mail: ben@cii.fc.ul.pt [Grupo de Física Matemática da Universidade de Lisboa, Av. Professor Gama Pinto 2, 1649-003 Lisboa (Portugal); Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade de Lisboa, 1749-016 Lisboa (Portugal); Instituto de Física da Universidade de São Paulo, CP 66318, 05314-970 São Paulo, SP (Brazil)

    2014-04-28

    The electronic absorption spectrum of liquid water was investigated by coupling a one-body energy decomposition scheme to configurations generated by classical and Born-Oppenheimer Molecular Dynamics (BOMD). A Frenkel exciton Hamiltonian formalism was adopted and the excitation energies in the liquid phase were calculated with the equation of motion coupled cluster with single and double excitations method. Molecular dynamics configurations were generated by different approaches. Classical MD were carried out with the TIP4P-Ew and AMOEBA force fields. The BLYP and BLYP-D3 exchange-correlation functionals were used in BOMD. Theoretical and experimental results for the electronic absorption spectrum of liquid water are in good agreement. Emphasis is placed on the relationship between the structure of liquid water predicted by the different models and the electronic absorption spectrum. The theoretical gas to liquid phase blue-shift of the peak positions of the electronic absorption spectrum is in good agreement with experiment. The overall shift is determined by a competition between the O–H stretching of the water monomer in liquid water that leads to a red-shift and polarization effects that induce a blue-shift. The results illustrate the importance of coupling many-body energy decomposition schemes to molecular dynamics configurations to carry out ab initio calculations of the electronic properties in liquid phase.

  6. Liquid water infiltration into a layered snowpack: evaluation of a 3-D water transport model with laboratory experiments

    Science.gov (United States)

    Hirashima, Hiroyuki; Avanzi, Francesco; Yamaguchi, Satoru

    2017-11-01

    The heterogeneous movement of liquid water through the snowpack during precipitation and snowmelt leads to complex liquid water distributions that are important for avalanche and runoff forecasting. We reproduced the formation of capillary barriers and the development of preferential flow through snow using a three-dimensional water transport model, which was then validated using laboratory experiments of liquid water infiltration into layered, initially dry snow. Three-dimensional simulations assumed the same column shape and size, grain size, snow density, and water input rate as the laboratory experiments. Model evaluation focused on the timing of water movement, thickness of the upper layer affected by ponding, water content profiles and wet snow fraction. Simulation results showed that the model reconstructs relevant features of capillary barriers, including ponding in the upper layer, preferential infiltration far from the interface, and the timing of liquid water arrival at the snow base. In contrast, the area of preferential flow paths was usually underestimated and consequently the averaged water content in areas characterized by preferential flow paths was also underestimated. Improving the representation of preferential infiltration into initially dry snow is necessary to reproduce the transition from a dry-snow-dominant condition to a wet-snow-dominant one, especially in long-period simulations.

  7. Compact Raman Lidar Measurement of Liquid and Vapor Phase Water Under the Influence of Ionizing Radiation

    Directory of Open Access Journals (Sweden)

    Shiina Tatsuo

    2016-01-01

    Full Text Available A compact Raman lidar has been developed for studying phase changes of water in the atmosphere under the influence of ionization radiation. The Raman lidar is operated at the wavelength of 349 nm and backscattered Raman signals of liquid and vapor phase water are detected at 396 and 400 nm, respectively. Alpha particles emitted from 241Am of 9 MBq ionize air molecules in a scattering chamber, and the resulting ions lead to the formation of liquid water droplets. From the analysis of Raman signal intensities, it has been found that the increase in the liquid water Raman channel is approximately 3 times as much as the decrease in the vapor phase water Raman channel, which is consistent with the theoretical prediction based on the Raman cross-sections. In addition, the radius of the water droplet is estimated to be 0.2 μm.

  8. Ultrafast, Unimpeded Liquid Water Transport Through Graphene-Based Nanochannels Measured by Isotope Labelling

    CERN Document Server

    Sun, Pengzhan; Wang, Kunlin; Zhong, Minlin; Wu, Dehai; Zhu, Hongwei

    2014-01-01

    Graphene-based laminates, with ultralong and tortuous nanocapillaries formed by simply stacking graphene flakes together, have great promises in filtration and separation. However, the information on liquid water trans-membrane permeation is lacking, which is the most fundamental problem and of crucial importance in solution-based mass transport. Here, based on isotope labelling, we investigate the liquid water transportation through graphene-based nanocapillaries under no external hydrostatic pressures. Liquid water can afford an unimpeded permeation through graphene-based nanochannels with a diffusion coefficient 4~5 orders of magnitude larger than through sub-micrometer-sized polymeric channels. When dissolving ions in sources, the diffusion coefficient of ions through graphene channels lies in the same order of magnitude as water, while the ion diffusion is faster than water, indicating that the ions are mainly transported by fast water flows and the delicate interactions between ions and nanocapillary wa...

  9. Approaches for Sustainable Mitigation of Arsenic Calamity in Bangladesh: Search for Safe Drinking Water

    Science.gov (United States)

    Alauddin, M.; Bhattacharjee, M.; Zakaria, A. B.; Rahman, M. M.; Seraji, M. S.

    2008-05-01

    Arsenic contamination of groundwater in Gangetic plain of Bihar, West Bengal in India and Bengal delta plain Bangladesh is shaping up as the greatest environmental health disaster in the current century. About 450 million combined population in these regions are at risk of developing adverse health effects due to arsenic contamination in groundwater. For an effective and sustainable mitigation, it is essential that we improve our understanding of fundamental processes of arsenic mobilization in sediments, biogeochemistry of arsenic in aquifer sediments and weigh a wide range of options for arsenic safe water for the vast population. In this paper, aspects of arsenic removal technology from groundwater in affected areas, sustainable development of household water filtration systems, deep aquifer water as potential arsenic safe water will be presented. In addition, sustainable development of water purification systems such as pond sand filtration (PSF), river sand filtration (RSF), rain water harvesting (RWH), dug well and their acceptability by the community will be discussed. A recent development of indigenous technology by local masons involves searching safe water through bore hole sediment color. The viability of this option in certain areas of Bangladesh will be discussed. Also, one of the household filtration systems approved by the government and locally known as SONO filter was recognized recently by the National Academy of Engineering -Grainger Challenge Prize for sustainability. Over 30, 000 of this unit were deployed in arsenic affected areas of Bangladesh. The affordability, ease of maintenance, social acceptability and environmental friendliness of all options will be addressed in the presentation.

  10. Sustainable Ways of Combining Reactions and Separations Using Ionic Liquids and Carbon Dioxide

    OpenAIRE

    Kazemi, S.

    2013-01-01

    Traditional chemical processes show shortcomings caused by using volatile organic compounds as solvents during reactions and separations. Therefore, it is necessary to address this issue by moving toward more environmentally friendly processes. This is possible by using less toxic and hazardous solvents, such as ionic liquids and supercritical carbon dioxide (scCO2). Ionic liquids have attracted a lot of attention as potential “green” solvents to replace conventional organic solvents due to t...

  11. Integration of sustainable urban drainage systems into the design of neighbourhoods as a water rehabilitation action

    OpenAIRE

    Reyes Vilariño, Marta; Calama Rodríguez, José María; Martín del Río, Juan Jesús; Mercader-Moyano, Pilar (Coordinador)

    2015-01-01

    The design of urban systems that allow the introduction of techniques for the recycling and drainage of rainwater represents a new aspect for the development of urban planning with sustainability criteria, since its main objectives include: the optimisation of the use of water as a resource in cities, the minimisation of the impacts on the natural cycle of water, and the protection of the ecosystem upon which it depends. Our proposal is based on the so-called water-sensitive ur...

  12. Energy-water-environment nexus underpinning future desalination sustainability

    KAUST Repository

    Shahzad, Muhammad Wakil

    2017-03-11

    Energy-water-environment nexus is very important to attain COP21 goal, maintaining environment temperature increase below 2°C, but unfortunately two third share of CO2 emission has already been used and the remaining will be exhausted by 2050. A number of technological developments in power and desalination sectors improved their efficiencies to save energy and carbon emission but still they are operating at 35% and 10% of their thermodynamic limits. Research in desalination processes contributing to fuel World population for their improved living standard and to reduce specific energy consumption and to protect environment. Recently developed highly efficient nature-inspired membranes (aquaporin & graphene) and trend in thermally driven cycle\\'s hybridization could potentially lower then energy requirement for water purification. This paper presents a state of art review on energy, water and environment interconnection and future energy efficient desalination possibilities to save energy and protect environment.

  13. Water-controlled wealth of nations: Using Water Footprints to Estimate Nations Carrying Capacities and Demographic Sustainability

    Science.gov (United States)

    Suweis, Samir; Rinaldo, Andrea; Maritan, Amos; D'Odorico, Paolo

    2014-05-01

    Population growth is in general constrained by food production, which in turn depends on the access to water resources. At a country level, some populations use more water than they control because of their ability to import food and the virtual water required for its production. Here, we investigate the dependence of demographic growth on available water resources for exporting and importing nations. By quantifying the carrying capacity of nations based on calculations of the virtual water available through the food trade network, we point to the existence of a global water unbalance. We suggest that current export rates will not be maintained and consequently we question the long-run sustainability of the food trade system as a whole. Water rich regions are likely to soon reduce the amount of virtual water they export, thus leaving import-dependent regions without enough water to sustain their populations. We also investigate the potential impact of possible scenarios that might mitigate these effects through (1) cooperative interactions among nations whereby water rich countries maintain a tiny fraction of their food production available for export; (2) changes in consumption patterns; and (3) a positive feedback between demographic growth and technological innovations. We find that these strategies may indeed reduce the vulnerability of water-controlled societies.

  14. Water sustainability assessment in Brazilian sugarcane expansion area

    Science.gov (United States)

    Scarpare, F. V.; Ruiz-Correa, S. T.; Hernandes, T. A.; Scanlon, B. R.; Picoli, M. C. A.; Bonomi, A.

    2016-12-01

    Due to the increasing demand for ethanol, sugarcane is expanding into Cerrado (Savannahs), where edaphoclimatic characteristics differ significantly from traditional areas in South-eastern Brazil. It is expected that the sugarcane will be irrigated in those areas to increase yields and ensure stable production. The main objective is to assess the sugarcane land occupation and its dynamics relating its occurrence with the potential and actual yields, the irrigation needs, the production costs, and the water footprint in Paranaíba watershed (222,593 km2 drainage area). The Agroecological Zone Model - FAO was used in order to provide essential data for yield and water requirement assessment. For sugarcane stalk yield estimation, several improvements have been made allowing this tool to assess different irrigation scenarios. In this study, full irrigation which aims to replace 100% of the water deficit until senescence period was considered. The sugarcane occupation and expansion was assessed through EVI approach from 2009/2010 to 2012/2013 crop seasons. It was possible to identify that most part of sugarcane occupation is concentrated in the central area, which presents less potential for yield gain through irrigation and significant water availability issues. With regard to the expansion, an increase of 54% of cane occupation (from 616,899 to 946,589 ha) was detected during the assessed period showing that the main dynamic occurred in central part towards west side and at less extent, to southeaster side. The irrigation management were responsible for increase, on average, 108% of yields while decreasing 42% of water footprints. Simulated yields combine with CanaSoft model estimated a 30% decline in production cost. Although several aspects such as land price and infrastructure must to be considered, in conclusion, the expansion dynamic agrees to the areas with greater yield gain potential through irrigation, lower sugarcane production costs and water footprint

  15. Water-in-water emulsions stabilized by non-amphiphilic interactions: polymer-dispersed lyotropic liquid crystals.

    Science.gov (United States)

    Simon, Karen A; Sejwal, Preeti; Gerecht, Ryan B; Luk, Yan-Yeung

    2007-01-30

    Emulsion systems involving surfactants are mainly driven by the separation of the hydrophobic interactions of the aliphatic chains from the hydrophilic interactions of amphiphilic molecules in water. In this study, we report an emulsion system that does not include amphiphilic molecules but molecules with functional groups that are completely solvated in water. These functional groups give rise to molecular interactions including hydrogen bonding, pi stacking, and salt bridging and are segregated into a dispersion of droplets forming a water-in-water emulsion. This water-in-water emulsion consists of dispersing droplets of a water-solvated biocompatible liquid crystal--disodium cromoglycate (DSCG)--in a continuous aqueous solution containing specific classes of water-soluble polymers. Whereas aqueous solutions of polyols support the formation of emulsions of spherical droplets consisting of lyotropic liquid crystal DSCG with long-term stability (for at least 30 days), aqueous solutions of polyamides afford droplets of DSCG in the shape of prolate ellipsoids that are stable for only 2 days. The DSCG liquid crystal in spherical droplets assumes a radial configuration in which the optical axis of the liquid crystal aligns perpendicular to the surface of the droplets but assumes a tangential configuration in prolate ellipsoids in which the optical axis of the liquid crystal aligns parallel to the surface of the droplet. Other classes of water-soluble polymers including polyethers, polycations, and polyanions do not afford a stable emulsion of DSCG droplets. Both the occurrence and the stability of this unique emulsion system can be rationalized on the basis of the functional groups of the polymer. The different configurations of the liquid crystal (DSCG) droplets were also found to correlate with the strength of the hydrogen bonding that can be formed by the functional groups on the polymer.

  16. Water Policy Reforms in South Korea: A Historical Review and Ongoing Challenges for Sustainable Water Governance and Management

    Directory of Open Access Journals (Sweden)

    Ik-Chang Choi

    2017-09-01

    Full Text Available This study aims to provide an opinion on the state-of-the-art of changes and reforms of water policies in South Korea, as well as the challenges along with their implications for sustainable water governance and management. In parallel with change in water resource characteristics generated by physical, environmental and socio-economic challenges such as: (1 uncertainties about climate change (flooding and drought including seasonal and regional variation in precipitation; (2 significant increase in water use caused by rapid urbanization and population growth in industrialized urban areas; (3 inadequate water pricing mechanism which covers only around 80% of the production cost and makes it harder to maintain water systems; and (4 recursive water quality degradation and conflicts over water rights between regions resulting from non-point source pollution in highland versus lowland areas, Korean water policies have been developed through diverse reforms over 100 years. Nevertheless, new challenges for sustainable water management are continuously emerging. To meet those challenges we provide two ideas: (i provider-gets-principle (payment for ecosystem services of cost-benefit sharing among stakeholders who benefit from water use; and (ii water pricing applying full-cost pricing-principle internalizing environmental externalities caused by the intensive water use. Funds secured from the application of those methods would facilitate: (1 support for upstream (rural low income householders suffering from economic restrictions; (2 improvement in water facilities; and (3 efficient water use and demand management in South Korea’s water sectors. We expect that this paper can examine the lessons relevant to challenges that South Korea faces and offer some implications on the formulation of new integration and further reforms of the institutions, laws and organizations responsible for managing water resources in South Korea.

  17. Hydrothermal decomposition of liquid crystal in subcritical water

    Energy Technology Data Exchange (ETDEWEB)

    Zhuang, Xuning [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092 (China); Shanghai Cooperative Centre for WEEE Recycling, Shanghai Second Polytechnic University, No. 2360 Jinhai Road, Shanghai 201209 (China); He, Wenzhi, E-mail: hithwz@163.com [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092 (China); Li, Guangming; Huang, Juwen; Lu, Shangming; Hou, Lianjiao [State Key Laboratory of Pollution Control and Resource Reuse, School of Environmental Science and Engineering, Tongji University, No. 1239 Siping Road, Shanghai 200092 (China)

    2014-04-01

    Highlights: • Hydrothermal technology can effectively decompose the liquid crystal of 4-octoxy-4'-cyanobiphenyl. • The decomposition rate reached 97.6% under the optimized condition. • Octoxy-4'-cyanobiphenyl was mainly decomposed into simple and innocuous products. • The mechanism analysis reveals the decomposition reaction process. - Abstract: Treatment of liquid crystal has important significance for the environment protection and human health. This study proposed a hydrothermal process to decompose the liquid crystal of 4-octoxy-4′-cyanobiphenyl. Experiments were conducted with a 5.7 mL stainless tube reactor and heated by a salt-bath. Factors affecting the decomposition rate of 4-octoxy-4′-cyanobiphenyl were evaluated with HPLC. The decomposed liquid products were characterized by GC-MS. Under optimized conditions i.e., 0.2 mL H{sub 2}O{sub 2} supply, pH value 6, temperature 275 °C and reaction time 5 min, 97.6% of 4-octoxy-4′-cyanobiphenyl was decomposed into simple and environment-friendly products. Based on the mechanism analysis and products characterization, a possible hydrothermal decomposition pathway was proposed. The results indicate that hydrothermal technology is a promising choice for liquid crystal treatment.

  18. A Need for Education in Water Sustainability in the Agricultural Realm

    Science.gov (United States)

    Krajewski, J.

    2015-12-01

    This study draws upon the definition of water sustainability from the National Water Research Institute as the continual supply of clean water for human uses and for other living beings without compromising the water welfare of future generations. Currently, the greatest consumer of water resources worldwide is irrigation. The move from small-scale, family farms towards corporately owned and market driven, mass scale operations have drastically increased corn production and large-scale factory hog farming in the American Midwest—and the water quality related costs associated with this shift are well-documented. In the heart of the corn belt, the state of Iowa has dealt with issues over the past two decades ranging from flooding of historic proportions, to yield destroying droughts. Most recently, the state's water quality is intensely scrutinized due to nutrient levels higher than almost anywhere else in the world. While the changed agricultural landscape is ultimately responsible for these environmental costs, they can be mitigated if the farmers adopt practices that support water sustainability. However, many Iowa farmers have yet to embrace these necessary practices because of a lack of proper education in this context. Thus, the purpose of this paper is to explore how water sustainability is being conceptualized within the agricultural realm, and ultimately, how the issues are being communicated and understood within various subgroups in Iowa, such as the farmers, the college students, and the general public.

  19. Conservation program works as an alternative irrigation districts in sustainable water management of agricultural use

    Directory of Open Access Journals (Sweden)

    Víctor Manuel Peinado Guevara

    2012-05-01

    Full Text Available Water scarcity is an issue of worldwide concern since it is already having an impact on social development. Mexico is not an exception to this problem because in several regions of the country are great difficulties in supplying water, primarily for agricultural use. In Sinaloa, it had been mentioned repeatedly by the media that in the Irrigation District 063, located in the northern of the state, there are problems of water scarcity, and yet there still exist difficulties in conserving the resource. More than 49% of the water used for agriculture is wasted. To resolve this problem, producers and government agencies spend significant resources for investment in water conservation. However, the results have not been entirely satisfactory because the waste is high, a situation that motivates them to study more deeply the main weaknesses that affect sustainable resource use. Farmer’s participation in the administration of water infrastructure is important, as well as providing financial resources for the conservation of water system; and participation in activities of construction and repaired of water infrastructure. Farmer’s should also plan and design strategies for water conservation. This situation requires an appropriate level of technology and intellectual, rather than local producers and thus no complicated sustainable resource management. That is what local producers don’t have and therefore it complicates the sustainable management of the resource.

  20. In Situ Characterization of Boehmite Particles in Water Using Liquid SEM.

    Science.gov (United States)

    Yao, Juan; Arey, Bruce W; Yang, Li; Zhang, Fei; Komorek, Rachel; Chun, Jaehun; Yu, Xiao-Ying

    2017-09-27

    In situ imaging and elemental analysis of boehmite (AlOOH) particles in water is realized using the System for Analysis at the Liquid Vacuum Interface (SALVI) and Scanning Electron Microscopy (SEM). This paper describes the method and key steps in integrating the vacuum compatible SAVLI to SEM and obtaining secondary electron (SE) images of particles in liquid in high vacuum. Energy dispersive x-ray spectroscopy (EDX) is used to obtain elemental analysis of particles in liquid and control samples including deionized (DI) water only and an empty channel as well. Synthesized boehmite (AlOOH) particles suspended in liquid are used as a model in the liquid SEM illustration. The results demonstrate that the particles can be imaged in the SE mode with good resolution (i.e., 400 nm). The AlOOH EDX spectrum shows significant signal from the aluminum (Al) when compared with the DI water and the empty channel control. In situ liquid SEM is a powerful technique to study particles in liquid with many exciting applications. This procedure aims to provide technical know-how in order to conduct liquid SEM imaging and EDX analysis using SALVI and to reduce potential pitfalls when using this approach.

  1. STRUCTURAL INTEGRITY MONITORING FOR IMPROVED DRINKING WATER INFRASTRUCTURE SUSTAINABILITY

    Science.gov (United States)

    Structural integrity monitoring (SIM) is the systematic detection, location, and quantification of pipe wall damage or associated indicators. Each of the adverse situations below has the potential to be reduced by more effective and economical SIM of water mains: 1) the dr...

  2. Toward sustainability: soil and water research priorities for developing countries

    National Research Council Canada - National Science Library

    National Research Council Staff

    1991-01-01

    ... Research and Development Water Science and Technology Board Commission on Engineering and Technical Systems Board on Science and Technology for International Development Office of International Affairs National Research Council NATIONAL ACADEMY PRESS Washington, D.C. 1991 Copyrightoriginal retained, the be not from cannot book, paper original however...

  3. Dredging of the inland waters and sustainable management of the ...

    African Journals Online (AJOL)

    Anticipated derivable benefits from the dredging of the Niger Water system would among others, include: ocean remediation, upland restoration, improved transportation system, economic viability, increase volume of cargo, improved communication, Job opportunities, decongestion of sea/coastal ports, and improved ...

  4. Life cycle assessment for sustainable metropolitan water systems planning.

    Science.gov (United States)

    Lundie, Sven; Peters, Gregory M; Beavis, Paul C

    2004-07-01

    Life Cycle Assessment (LCA) is useful as an information tool for the examination of alternative future scenarios for strategic planning. Developing a life cycle assessment for a large water and wastewater system involves making methodological decisions about the level of detail which is retained through different stages of the process. In this article we discuss a methodology tailored to strategic planning needs which retains a high degree of model segmentation in order to enhance modeling of a large, complex system. This is illustrated by a case study of Sydney Water, which is Australia's largest water service provider. A prospective LCA was carried out to examine the potential environmental impacts of Sydney Water's total operations in the year 2021. To our knowledge this is the first study to create an LCA model of an integrated water and wastewater system with this degree of complexity. A "base case" system model was constructed to represent current operating assets as augmented and upgraded to 2021. The base case results provided a basis for the comparison of alternative future scenarios and for conclusions to be drawn regarding potential environmental improvements. The scenarios can be roughly classified in two categories: (1) options which improve the environmental performance across all impact categories and (2) options which improve one indicator and worsen others. Overall environmental improvements are achieved in all categories by the scenarios examining increased demand management, energy efficiency, energy generation, and additional energy recovery from biosolids. The scenarios which examined desalination of seawater and the upgrades of major coastal sewage treatment plants to secondary and tertiary treatment produced an improvement in one environmental indicator but deteriorations in all the other impact categories, indicating the environmental tradeoffs within the system. The desalination scenario produced a significant increase in greenhouse gas

  5. Greenlandic water and sanitation-a context oriented analysis of system challenges towards local sustainable development.

    Science.gov (United States)

    Hendriksen, Kåre; Hoffmann, Birgitte

    2017-08-28

    Today, as Greenland focuses on more economic and cultural autonomy, the continued development of societal infrastructure systems is vital. At the same time, pressure is put on the systems by a lack of financial resources and locally based professional competences as well as new market-based forms of organization. Against this background, the article discusses the challenges facing Greenland's self-rule in relation to further develop the existing water and wastewater systems so that they can contribute to the sustainable development of Greenland. The article reviews the historical development of the water supply and wastewater system. This leads to an analysis of the sectorisation, which in recent decades has reorganized the Greenlandic infrastructures, and of how this process is influencing local sustainable development. The article discusses the socio-economic and human impacts and points to the need for developing the water and sanitation system to support not only hygiene and health, but also local sustainable development.

  6. Sustainable water management under future uncertainty with eco-engineering decision scaling

    Science.gov (United States)

    Poff, N LeRoy; Brown, Casey M; Grantham, Theodore E.; Matthews, John H; Palmer, Margaret A.; Spence, Caitlin M; Wilby, Robert L.; Haasnoot, Marjolijn; Mendoza, Guillermo F; Dominique, Kathleen C; Baeza, Andres

    2015-01-01

    Managing freshwater resources sustainably under future climatic and hydrological uncertainty poses novel challenges. Rehabilitation of ageing infrastructure and construction of new dams are widely viewed as solutions to diminish climate risk, but attaining the broad goal of freshwater sustainability will require expansion of the prevailing water resources management paradigm beyond narrow economic criteria to include socially valued ecosystem functions and services. We introduce a new decision framework, eco-engineering decision scaling (EEDS), that explicitly and quantitatively explores trade-offs in stakeholder-defined engineering and ecological performance metrics across a range of possible management actions under unknown future hydrological and climate states. We illustrate its potential application through a hypothetical case study of the Iowa River, USA. EEDS holds promise as a powerful framework for operationalizing freshwater sustainability under future hydrological uncertainty by fostering collaboration across historically conflicting perspectives of water resource engineering and river conservation ecology to design and operate water infrastructure for social and environmental benefits.

  7. Salt effect on (liquid + liquid) equilibrium of (water + tert-butanol + 1-butanol) system: Experimental data and correlation

    Energy Technology Data Exchange (ETDEWEB)

    Pereira, Milton A.P. [School of Chemical Engineering, State University of Campinas, P.O. Box 6066, Campinas-SP 13081-970 (Brazil); Aznar, Martin [School of Chemical Engineering, State University of Campinas, P.O. Box 6066, Campinas-SP 13081-970 (Brazil)]. E-mail: maznar@feq.unicamp.br

    2006-01-15

    (Liquid + liquid) equilibrium data for the quaternary systems (water + tert-butanol + 1-butanol + KBr) and (water + tert-butanol + 1-butanol + MgCl{sub 2}) were experimentally determined at T = 293.15 K and T = 313.15 K. For mixtures with KBr, the overall salt concentrations were 5 and 10 mass percent; for mixtures with MgCl{sub 2}, the overall salt concentrations were 2 and 5 mass percent. The experimental results were used to estimate molecular interaction parameters for the NRTL activity coefficient model, using the Simplex minimization method and a concentration-based objective function. The correlation results are extremely satisfactory, with deviations in phase compositions below 1.7%.

  8. Liquid-liquid equilibrium measurement of ternary system containing β-caryophyllene in the water and 2-propanol mixture

    Science.gov (United States)

    Tetrisyanda, Rizky; Kuswandi, Wibawa, Gede

    2017-01-01

    To obtain a high purity of clove oil, it is needed to separate β-caryophyllene from the oil mixtures.The separation of this component could be obtained by solvent extraction. In this work, liquid-liquid equilibrium (LLE) data were measured for the ternary system of water β-caryophyllene (1) + 2-propanol (2) + water (3) at temperature 303.15 K, 313.15 K and 323.15K under atmospheric pressure. The experimental LLE data were correlated with the NRTL and UNIQUAC models. The reliability of these models is tested by comparison with experimental results. The varied temperatures studied in this work have significant influence to the two-phase area and the solubility of 2-propanol and β-caryophyllene in the aqueous phase.

  9. Development of Chengdu and sustainable utilization of the ancient Dujiangyan Water-Conservancy Project

    Directory of Open Access Journals (Sweden)

    X. Huang

    2015-05-01

    Full Text Available The Dujiangyan Water-Conservancy Project is a great water irrigation works in Chinese cultural history, which led the Min River water to the vast Chengdu Plain, and created fertile and pretty "land of abundance". Now Chengdu is facing increased water demand stress due mainly to rapid urbanization. This paper first analyses the available water resources of Chengdu based on historical hydrological data from 1964 to 2008. The results show that the average annual water resources were 8.9 billion m3 in 1986 and 7.9 billion m3 in 2008 under various environmental conditions. The future tendency of water demand in city development planning is predicted by the Policy Dialogue Model (PODIUM. Finally, the strategies for water resources exploitation accompanying the sustainable development pattern are studied. The result illustrates that rational and careful management are required to balance the gap between water supply and demand

  10. Selective extraction of copper, mercury, silver and palladium ionsfrom water using hydrophobic ionic liquids.

    Energy Technology Data Exchange (ETDEWEB)

    Papaiconomou, Nicolas; Lee, Jong-Min; Salminen, Justin; VonStosch, Moritz; Prausnitz, John M.

    2007-06-25

    Extraction of dilute metal ions from water was performed near room temperature with a variety of ionic liquids. Distribution coefficients are reported for fourteen metal ions extracted with ionic liquids containing cations 1-octyl-4-methylpyridinium [4MOPYR]{sup +}, 1-methyl-1-octylpyrrolidinium [MOPYRRO]{sup +} or 1-methyl-1-octylpiperidinium [MOPIP]{sup +}, and anions tetrafluoroborate [BF{sub 4}]{sup +}, trifluoromethyl sulfonate [TfO]{sup +} or nonafluorobutyl sulfonate [NfO]{sup +}. Ionic liquids containing octylpyridinium cations are very good for extracting mercury ions. However, other metal ions were not significantly extracted by any of these ionic liquids. Extractions were also performed with four new task-specific ionic liquids. Such liquids containing a disulfide functional group are efficient and selective for mercury and copper, whereas those containing a nitrile functional group are efficient and selective for silver and palladium.

  11. Studies of Water V. Five Phonons in Protonic Semiconductor Lattice Model of Pure Liquid Water

    Science.gov (United States)

    Jie, Binbin; Sah, Chihtang

    2017-07-01

    We report physics based confirmation (~1% RMS deviation), by existing experimental data, of proton-prohol (proton-hole) ion product (pH) and mobilities in pure liquid water (0-100{}{{o}}C, 1-atm pressure) anticipated from our melted-ice Hexagonal-Close-Packed (H{}2O){}4 Lattice Model. Five phonons are identified. (1) A propagating protonic phonon (520.9 meV from lone-pair-blue-shifted stretching mode of isolated water molecule) absorbed to generate a proton-prohol pair or detrap a tightly-bound proton. (2) Two (173.4 and 196.6 meV) bending-breathing protonic-proholic or protonic phonons absorbed during de-trapping-limited proton or proton-prohol mobilities. (3) Two propagating oxygenic-wateric Debye-Dispersive phonons (30.3 and 27.5 meV) absorbed during scattering-limited proton or proton-prohol mobilities. Summer School in Theoretical Physics funded by the National Natural Science Foundation of China, on Soft Materials Physics, hosted by the Physics Department of Xiamen University, China, during August 1 to 14, 2016. This was also just presented at the 2017 March Meeting (March 14 to 16) of the American Physical Society in New Orleans, USA.

  12. Meeting water needs for sustainable development: an overview of approaches, measures and data sources

    Science.gov (United States)

    Lissner, Tabea; Reusser, Dominik E.; Sullivan, Caroline A.; Kropp, Jürgen P.

    2013-04-01

    An essential part of a global transition towards sustainability is the Millennium Development Goals (MDG), providing a blueprint of goals to meet human needs. Water is an essential resource in itself, but also a vital factor of production for food, energy and other industrial products. Access to sufficient water has only recently been recognized as a human right. One central MDG is halving the population without access to safe drinking water and sanitation. To adequately assess the state of development and the potential for a transition towards sustainability, consistent and meaningful measures of water availability and adequate access are thus fundamental. Much work has been done to identify thresholds and definitions to measure water scarcity. This includes some work on defining basic water needs of different sectors. A range of data and approaches has been made available from a variety of sources, but all of these approaches differ in their underlying assumptions, the nature of the data used, and consequently in the final results. We review and compare approaches, methods and data sources on human water use and human water needs. This data review enables identifying levels of consumption in different countries and different sectors. Further comparison is made between actual water needs (based on human and ecological requirements), and recognised levels of water abstraction. The results of our review highlight the differences between different accounts of water use and needs, and reflect the importance of standardised approaches to data definitions and measurements, making studies more comparable across space and time. The comparison of different use and allocation patterns in countries enables levels of water use to be identified which allow for an adequate level of human wellbeing to be maintained within sustainable water abstraction limits. Recommendations are provided of how data can be defined more clearly to make comparisons of water use more meaningful and

  13. Perceptions of Sustainability and Functional Aspects on Liquid Carton Board Packaging Materials versus Competing Materials for Juice Applications in Sweden

    Directory of Open Access Journals (Sweden)

    Carl Olsmats

    2015-08-01

    Full Text Available This research explores the downstream perceptions of liquid carton board versus competing materials in packaging applications for juice. The methodology used is focus groups. The context is sustainability and functional performance, and related potential implications for the beverage industry value chain. The purpose is to get a deeper insight and understanding of functionality in relation to juice beverage packaging. The results confirm that there is no optimal packaging for every juice product, but a multitude, depending on the distribution channel, retail outlet, customer preferences, and context of consumption. There are some general packaging preferences, but the main deciding criteria for purchase seem to be the product characteristics in terms of quality, taste, brand, price and shelf life. For marketing reasons, packaging has to be adopted to the product and its positioning, liquid carton board packaging seem to have some functional advantages in distribution and is considered as sustainable and functional among many consumers. Major drawbacks seem to be shape limitations, lack of transparency, and lack of a “premium look”. To improve packaging performance and avoid sub-optimization, actors in the beverage industry value chain need to be integrated in development processes.

  14. Granular flows at recurring slope lineae on Mars indicate a limited role for liquid water

    Science.gov (United States)

    Dundas, Colin M.; McEwen, Alfred S.; Chojnacki, Matthew; Milazzo, Moses P.; Byrne, Shane; McElwaine, Jim N.; Urso, Anna

    2017-12-01

    Recent liquid water flow on Mars has been proposed based on geomorphological features, such as gullies. Recurring slope lineae — seasonal flows that are darker than their surroundings — are candidate locations for seeping liquid water on Mars today, but their formation mechanism remains unclear. Topographical analysis shows that the terminal slopes of recurring slope lineae match the stopping angle for granular flows of cohesionless sand in active Martian aeolian dunes. In Eos Chasma, linea lengths vary widely and are longer where there are more extensive angle-of-repose slopes, inconsistent with models for water sources. These observations suggest that recurring slope lineae are granular flows. The preference for warm seasons and the detection of hydrated salts are consistent with some role for water in their initiation. However, liquid water volumes may be small or zero, alleviating planetary protection concerns about habitable environments.

  15. Liquid Organic Fertilizers for Sustainable Agriculture: Nutrient Uptake of Organic versus Mineral Fertilizers in Citrus Trees

    Science.gov (United States)

    Martínez-Alcántara, Belén; Martínez-Cuenca, Mary-Rus; Bermejo, Almudena; Legaz, Francisco; Quiñones, Ana

    2016-01-01

    The main objective of this study was to compare the performance of two liquid organic fertilizers, an animal and a plant-based fertilizer, with mineral fertilization on citrus trees. The source of the fertilizer (mineral or organic) had significant effect in the nutritional status of the organic and conventionally managed mandarins. Nutrient uptake, vegetative growth, carbohydrate synthesis and soil characteristics were analyzed. Results showed that plants fertilized with animal based liquid fertilizers exhibited higher total biomass with a more profuse development of new developing organs (leaves and fibrous roots). Liquid organic fertilization resulted in an increased uptake of macro and micronutrients compared to mineral fertilized trees. Moreover, organic fertilization positively affected the carbohydrate content (fructose, glucose and sucrose) mainly in summer flush leaves. Liquid organic fertilization also resulted in an increase of soil organic matter content. Animal-based fertilizer, due to intrinsic composition, increased total tree biomass and carbohydrate leaves content, and led to lower soil nitrate concentration and higher P and Mg exchangeable in soil extract compared to vegetal-based fertilizer. Therefore, liquid organic fertilizers could be used as an alternative to traditional mineral fertilization in drip irrigated citrus trees. PMID:27764099

  16. Liquid Organic Fertilizers for Sustainable Agriculture: Nutrient Uptake of Organic versus Mineral Fertilizers in Citrus Trees.

    Science.gov (United States)

    Martínez-Alcántara, Belén; Martínez-Cuenca, Mary-Rus; Bermejo, Almudena; Legaz, Francisco; Quiñones, Ana

    2016-01-01

    The main objective of this study was to compare the performance of two liquid organic fertilizers, an animal and a plant-based fertilizer, with mineral fertilization on citrus trees. The source of the fertilizer (mineral or organic) had significant effect in the nutritional status of the organic and conventionally managed mandarins. Nutrient uptake, vegetative growth, carbohydrate synthesis and soil characteristics were analyzed. Results showed that plants fertilized with animal based liquid fertilizers exhibited higher total biomass with a more profuse development of new developing organs (leaves and fibrous roots). Liquid organic fertilization resulted in an increased uptake of macro and micronutrients compared to mineral fertilized trees. Moreover, organic fertilization positively affected the carbohydrate content (fructose, glucose and sucrose) mainly in summer flush leaves. Liquid organic fertilization also resulted in an increase of soil organic matter content. Animal-based fertilizer, due to intrinsic composition, increased total tree biomass and carbohydrate leaves content, and led to lower soil nitrate concentration and higher P and Mg exchangeable in soil extract compared to vegetal-based fertilizer. Therefore, liquid organic fertilizers could be used as an alternative to traditional mineral fertilization in drip irrigated citrus trees.

  17. Liquid Organic Fertilizers for Sustainable Agriculture: Nutrient Uptake of Organic versus Mineral Fertilizers in Citrus Trees.

    Directory of Open Access Journals (Sweden)

    Belén Martínez-Alcántara

    Full Text Available The main objective of this study was to compare the performance of two liquid organic fertilizers, an animal and a plant-based fertilizer, with mineral fertilization on citrus trees. The source of the fertilizer (mineral or organic had significant effect in the nutritional status of the organic and conventionally managed mandarins. Nutrient uptake, vegetative growth, carbohydrate synthesis and soil characteristics were analyzed. Results showed that plants fertilized with animal based liquid fertilizers exhibited higher total biomass with a more profuse development of new developing organs (leaves and fibrous roots. Liquid organic fertilization resulted in an increased uptake of macro and micronutrients compared to mineral fertilized trees. Moreover, organic fertilization positively affected the carbohydrate content (fructose, glucose and sucrose mainly in summer flush leaves. Liquid organic fertilization also resulted in an increase of soil organic matter content. Animal-based fertilizer, due to intrinsic composition, increased total tree biomass and carbohydrate leaves content, and led to lower soil nitrate concentration and higher P and Mg exchangeable in soil extract compared to vegetal-based fertilizer. Therefore, liquid organic fertilizers could be used as an alternative to traditional mineral fertilization in drip irrigated citrus trees.

  18. Forest management challenges for sustaining water resources in the Anthropocene

    Science.gov (United States)

    Ge Sun; James M. Vose

    2016-01-01

    The Earth has entered the Anthropocene epoch that is dominated by humans who demand unprecedented quantities of goods and services from forests. The science of forest hydrology and watershed management generated during the past century provides a basic understanding of relationships among forests and water and offers management principles that maximize the benefits of...

  19. Use of magnetic effervescent tablet-assisted ionic liquid dispersive liquid-liquid microextraction to extract fungicides from environmental waters with the aid of experimental design methodology.

    Science.gov (United States)

    Yang, Miyi; Wu, Xiaoling; Jia, Yuhan; Xi, Xuefei; Yang, Xiaoling; Lu, Runhua; Zhang, Sanbing; Gao, Haixiang; Zhou, Wenfeng

    2016-02-04

    In this work, a novel effervescence-assisted microextraction technique was proposed for the detection of four fungicides. This method combines ionic liquid-based dispersive liquid-liquid microextraction with the magnetic retrieval of the extractant. A magnetic effervescent tablet composed of Fe3O4 magnetic nanoparticles, sodium carbonate, sodium dihydrogen phosphate and 1-hexyl-3-methylimidazolium bis(trifluoromethanesulfonimide) was used for extractant dispersion and retrieval. The main factors affecting the extraction efficiency were screened by a Plackett-Burman design and optimized by a central composite design. Under the optimum conditions, good linearity was obtained for all analytes in pure water model and real water samples. Just for the pure water, the recoveries were between 84.6% and 112.8%, the limits of detection were between 0.02 and 0.10 μg L(-1) and the intra-day precision and inter-day precision both are lower than 4.9%. This optimized method was successfully applied in the analysis of four fungicides (azoxystrobin, triazolone, cyprodinil, trifloxystrobin) in environmental water samples and the recoveries ranged between 70.7% and 105%. The procedure promising to be a time-saving, environmentally friendly, and efficient field sampling technique. Copyright © 2015 Elsevier B.V. All rights reserved.

  20. Ionic liquid-based ultrasound-assisted dispersive liquid-liquid microextraction combined with electrothermal atomic absorption spectrometry for a sensitive determination of cadmium in water samples

    Science.gov (United States)

    Li, Shengqing; Cai, Shun; Hu, Wei; Chen, Hao; Liu, Hanlan

    2009-07-01

    A new method was developed for the determination of cadmium in water samples using ionic liquid-based ultrasound-assisted dispersive liquid-liquid microextraction (IL-based USA-DLLME) followed by electrothermal atomic absorption spectrometry (ETAAS). The IL-based USA-DLLME procedure is free of volatile organic solvents, and there is no need for a dispersive solvent, in contrast to conventional DLLME. The ionic liquid, 1-hexyl-3-methylimidazolium hexafluorophosphate (HMIMPF 6), was quickly disrupted by an ultrasonic probe for 1 min and dispersed in water samples like a cloud. At this stage, a hydrophobic cadmium-DDTC complex was formed and extracted into the fine droplets of HMIMPF 6. After centrifugation, the concentration of the enriched cadmium in the sedimented phase was determined by ETAAS. Some effective parameters of the complex formation and microextraction, such as the concentration of the chelating agent, the pH, the volume of the extraction solvent, the extraction time, and the salt effect, have been optimized. Under optimal conditions, a high extraction efficiency and selectivity were reached for the extraction of 1.0 ng of cadmium in 10.0 mL of water solution employing 73 µL of HMIMPF 6 as the extraction solvent. The enrichment factor of the method is 67. The detection limit was 7.4 ng L - 1 , and the characteristic mass ( m0, 0.0044 absorbance) of the proposed method was 0.02 pg for cadmium (Cd). The relative standard deviation (RSD) for 11 replicates of 50 ng L - 1 Cd was 3.3%. The method was applied to the analysis of tap, well, river, and lake water samples and the Environmental Water Reference Material GSBZ 50009-88 (200921). The recoveries of spiked samples were in the range of 87.2-106%.

  1. Apparent First-Order Liquid-Liquid Transition with Pre-transition Density Anomaly, in Water-Rich Ideal Solutions.

    Science.gov (United States)

    Zhao, Zuofeng; Angell, C Austen

    2016-02-12

    The striking increases in response functions observed during supercooling of pure water have been the source of much interest and controversy. Imminent divergences of compressibility etc. unfortunately cannot be confirmed due to pre-emption by ice crystallization. Crystallization can be repressed by addition of second components, but these usually destroy the anomalies of interest. Here we study systems in which protic ionic liquid second components dissolve ideally in water, and ice formation is avoided without destroying the anomalies. We observe a major heat capacity spike during cooling, which is reversed during heating, and is apparently of first order. It occurs just before the glassy state is reached and is preceded by water-like density anomalies. We propose that it is the much-discussed liquid-liquid transition previously hidden by crystallization. Fast cooling should allow the important fluctuations/structures to be preserved in the glassy state for leisurely investigation. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Ionic liquid for high temperature headspace liquid-phase microextraction of chlorinated anilines in environmental water samples.

    Science.gov (United States)

    Peng, Jin-feng; Liu, Jing-fu; Jiang, Gui-bin; Tai, Chao; Huang, Min-jia

    2005-04-22

    Based on the non-volatility of room temperature ionic liquids (IL), 1-butyl-3-methylimidazolium hexafluorophosphate ([C4MIM][PF6]) IL was employed as an advantageous extraction solvent for high temperature headspace liquid-phase microextraction (LPME) of chloroanilines in environmental water samples. At high temperature of 90 degrees C, 4-chloroaniline, 2-chloroaniline, 3,4-dichloroaniline, and 2,4-dichloroaniline were extracted into a 10 microl drop of [C4MIM][PF6] suspended on the needle of a high-performance liquid chromatography (HPLC) microsyringe held at the headspace of the samples. Then, the IL was injected directly into the HPLC system for determination. Parameters related to LPME were optimized, and high selectivity and low detection limits of the four chlorinated anilines were obtained because the extraction was performed at high temperature in headspace mode and the very high affinity between IL and chlorinated anilines. The proposed procedure was applied for the analysis of the real samples including tap water, river water and wastewater samples from a petrochemical plant and a printworks, and only 3,4-dichloroaniline was detected in the printworks wastewater at 88.2 microg l(-1) level. The recoveries for the four chlorinated anilines in the four samples were all in the range of 81.9-99.6% at 25 microg l(-1) spiked level.

  3. Modeling Halophytic Plants in APEX for Sustainable Water and Agriculture

    Science.gov (United States)

    DeRuyter, T.; Saito, L.; Nowak, B.; Rossi, C.; Toderich, K.

    2013-12-01

    A major problem for irrigated agricultural production is soil salinization, which can occur naturally or can be human-induced. Human-induced, or secondary salinization, is particularly a problem in arid and semi-arid regions, especially in irrigated areas. Irrigated land has more than twice the production of rainfed land, and accounts for about one third of the world's food, but nearly 20% of irrigated lands are salt-affected. Many farmers worldwide currently seasonally leach their land to reduce the soil salt content. These practices, however, create further problems such as a raised groundwater table, and salt, fertilizer, and pesticide pollution of nearby lakes and groundwater. In Uzbekistan, a combination of these management practices and a propensity to cultivate 'thirsty' crops such as cotton has also contributed to the Aral Sea shrinking nearly 90% by volume since the 1950s. Most common agricultural crops are glycophytes that have reduced yields when subjected to salt-stress. Some plants, however, are known as halophytic or 'salt-loving' plants and are capable of completing their life-cycle in higher saline soil or water environments. Halophytes may be useful for human consumption, livestock fodder, or biofuel, and may also be able to reduce or maintain salt levels in soil and water. To assess the potential for these halophytes to assist with salinity management, we are developing a model that is capable of tracking salinity under different management practices in agricultural environments. This model is interdisciplinary as it combines fields such as plant ecology, hydrology, and soil science. The US Department of Agriculture (USDA) model, Agricultural Policy/Environmental Extender (APEX), is being augmented with a salinity module that tracks salinity as separate ions across the soil-plant-water interface. The halophytes Atriplex nitens, Climacoptera lanata, and Salicornia europaea are being parameterized and added into the APEX model database. Field sites

  4. Drilling to Extract Liquid Water on Mars: Feasible and Worth the Investment

    Science.gov (United States)

    Stoker, C.

    2004-01-01

    A critical application for the success of the Exploration Mission is developing cost effective means to extract resources from the Moon and Mars needed to support human exploration. Water is the most important resource in this regard, providing a critical life support consumable, the starting product of energy rich propellants, energy storage media (e.g. fuel cells), and a reagent used in virtually all manufacturing processes. Water is adsorbed and chemically bound in Mars soils, ice is present near the Martian surface at high latitudes, and water vapor is a minor atmospheric constituent, but extracting meaningful quantities requires large complex mechanical systems, massive feedstock handling, and large energy inputs. Liquid water aquifers are almost certain to be found at a depth of several kilometers on Mars based on our understanding of the average subsurface thermal gradient, and geological evidence from recent Mars missions suggests liquid water may be present much closer to the surface at some locations. The discovery of hundreds of recent water-carved gullies on Mars indicates liquid water can be found at depths of 200-500 meters in many locations. Drilling to obtain liquid water via pumping is therefore feasible and could lower the cost and improve the return of Mars exploration more than any other ISRU technology on the horizon. On the Moon, water ice may be found in quantity in permanently shadowed regions near the poles.

  5. Study benefit value of utilization water resources for energy and sustainable environment

    Science.gov (United States)

    Juniah, Restu; Sastradinata, Marwan

    2017-11-01

    Referring to the concept of sustainable development, the environment is said to be sustainable if the fulfillment of three pillars of development that is economic, social and ecological or the environment itself. The environment can sustained in the principle of ecology or basic principles of environmental science, when the three environmental components, namely the natural environment, the artificial environment (the built environment) and the social environment can be aligned for sustainability. The natural environment in this study is the water resources, the artificial environment is micro hydroelectric power generation (MHPG), and the social environment is the community living around the MHPG. The existence of MHPG is intended for the sustainability of special electrical energy for areas not yet reached by electricity derived from the state electricity company (SEC). The utilization of MHPG Singalaga in South Ogan Komering Ulu (OKUS) district is not only intended for economic, ecological, and social sustainability in Southern OKU district especially those who live in Singalaga Village, Kisam Tinggi District. This paper discusses the economic, ecological and social benefits of water resources utilization in Southern OKU District for MHPG Singalaga. The direct economic benefits that arise for people living around MHPG Singalaga is the cost incurred by the community for the use of electricity is less than if the community uses electricity coming from outside the MHPG. The cost to society in the form of dues amounting to IDR 15,000 a month / household. Social benefits with the absorption of manpower to manage the MHPG is chairman, secretary and 3 members, while the ecological benefits of water resources and sustainable energy as well as the community while maintaining the natural vegetation that is located around the MHPG for the continuity of water resources.

  6. Synthesis of TiO2 Materials Using Ionic Liquids and Its Applications for Sustainable Energy and Environment.

    Science.gov (United States)

    Yoo, Kye Sang

    2016-05-01

    Titanium dioxide (TiO2) has received significant attention because of the global climate change and the consumption of fossil fuel resources. Specifically, using TiO2 in photocatalytic applications, such as the removal of organic pollutants and a hydrogen production has become an important issue. Thus, many researchers have attempted to prepare highly active TiO2 materials using various synthetic approaches. Modifications of the conventional sol-gel method, such as the addition of surfactants, have been employed in synthetic procedures. Moreover, hydrothermal, solvothermal, sonochemical and microwave methods have also been used as alternative approaches. Recently, the use of ionic liquids represents a burgeoning direction in inorganic material synthesis. Ionic liquids are exceptional solvents consisting of ions possessing low vapor pressure and tunable solvent properties. This article reviews the preparation of TiO2 materials using ionic liquids with various synthetic approaches. Also, sustainable energy and environmental cleanup applications of TiO2 materials, including the treatment of hazardous organic substances and hydrogen energy derived from electrochemical methods, are discussed.

  7. Sustainability Appraisal of Water Governance Regimes: The Case of Guanacaste, Costa Rica

    Science.gov (United States)

    Kuzdas, Christopher; Wiek, Arnim; Warner, Benjamin; Vignola, Raffaele; Morataya, Ricardo

    2014-08-01

    Sustainability appraisals produce evidence for how well water governance regimes operate and where problems exist. This evidence is particularly relevant for regions that face water scarcity and conflicts. In this study, we present a criteria-based and participatory sustainability appraisal of water governance in a region with such characteristics—the dry tropics of NW Costa Rica. Data collection included 47 interviews and three stakeholder workshops. The appraisal was conducted through a collaborative and iterative process between researchers and stakeholders. Out of the 25 sustainability criteria used, seven posed a significant challenge for the governance regime. We found challenges faced by the governance regime primarily clustered around and were re-enforced by failing coordination related to the use, management, and protection of groundwater resources; and inadequate leadership to identify collective goals and to constructively deliberate alternative ways of governing water with diverse groups. The appraisal yielded some positive impact in the study area, yet we found its application provided only limited strategic information to support broader problem-solving efforts. Insights from this study suggest key starting points for sustainable water governance in the Central American dry tropics, including investing in increasingly influential collective organizations that are already active in water governance; and leveraging policy windows that can be used to build confidence and disperse more governing authority to regional and local governing actors that are in-tune with the challenges faced in the dry tropics. We conclude the article with reflections on how to produce research results that are actionable for sustainable water governance.

  8. Local Institutional Development and Organizational Change for Advancing Sustainable Urban Water Futures

    Science.gov (United States)

    Brown, Rebekah R.

    2008-02-01

    This paper presents the local institutional and organizational development insights from a five-year ongoing interdisciplinary research project focused on advancing the implementation of sustainable urban water management. While it is broadly acknowledged that the inertia associated with administrative systems is possibly the most significant obstacle to advancing sustainable urban water management, contemporary research still largely prioritizes investigations at the technological level. This research is explicitly concerned with critically informing the design of methodologies for mobilizing and overcoming the administrative inertia of traditional urban water management practice. The results of fourteen in-depth case studies of local government organizations across Metropolitan Sydney primarily reveal that (i) the political institutionalization of environmental concern and (ii) the commitment to local leadership and organizational learning are key corporate attributes for enabling sustainable management. A typology of five organizational development phases has been proposed as both a heuristic and capacity benchmarking tool for urban water strategists, policy makers, and decision makers that are focused on improving the level of local implementation of sustainable urban water management activity. While this investigation has focused on local government, these findings do provide guideposts for assessing the development needs of future capacity building programs across a range of different institutional contexts.

  9. Sustainable Urban Water Management: Application for Integrated Assessment in Southeast Asia

    Directory of Open Access Journals (Sweden)

    Shokhrukh-Mirzo Jalilov

    2018-01-01

    Full Text Available The design, development, and operation of current and future urban water infrastructure in many parts of the world increasingly rely on and apply the principles of sustainable development. However, this approach suffers from a lack of the necessary knowledge, skills, and practice of how sustainable development can be attained and promoted in a given city. This paper presents the framework of an integrated systems approach analysis that deals with the abovementioned issues. The “Water and Urban Initiative” project, which was implemented by the United Nations University’s Institute for the Advanced Study of Sustainability, focused on urban water and wastewater systems, floods, and their related health risk assessment, and the economics of water quality improvements. A team of researchers has investigated issues confronting cities in the developing countries of Southeast Asia, in relation to sustainable urban water management in the face of such ongoing changes as rapid population growth, economic development, and climate change; they have also run future scenarios and proposed policy recommendations for decision-makers in selected countries in Southeast Asia. The results, lessons, and practical recommendations of this project could contribute to the ongoing policy debates and decision-making processes in these countries.

  10. Interactions of Woody Biofuel Feedstock Production Systems with Water Resources: Considerations for Sustainability

    Energy Technology Data Exchange (ETDEWEB)

    Trettin, Carl C. [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States); Amatya, Devendra [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States); Coleman, Mark [US Forest Service Center for Forested Wetlands Research, Cordesville, SC (United States)

    2008-04-15

    Water resources are important for the production of woody biofuel feedstocks. It is necessary to ensure that production systems do not adversely affect the quantity or quality of surface and ground water. The effects of woody biomass plantations on water resources are largely dependent on the prior land use and the management regime. Experience from both irrigated and non-irrigated systems has demonstrated that woody biofuel production systems do not impair water quality. Water quality actually improves from conversion of idle or degraded agricultural lands to woody biomass plantations. Site water balance may be altered by cultivation of woody biomass plantations relative to agricultural use, due to increases in evapostranspiration (ET) and storage. Incorporation of woody biomass production plantations within the landscape provides an opportunity to improve the quality of runoff water and soil conservation. Finally, given the centrality of water resources to the sustainability of ecosystem services and other values derived, the experience with woody biofuels feedstock production systems is positive.

  11. Environmental and water sustainability of milk production in Northeast Spain.

    Science.gov (United States)

    Noya, I; González-García, S; Berzosa, J; Baucells, F; Feijoo, G; Moreira, M T

    2017-10-26

    This study focuses on the assessment of the environmental profile of a milk farm, representative of the dairy sector in Northeast Spain, from a cradle-to-gate perspective. The Life Cycle Assessment (LCA) principles established by ISO standards together with the carbon footprint guidelines proposed by International Dairy Federation (IDF) were followed. The environmental results showed two critical contributing factors: the production of the livestock feed (e.g., alfalfa) and the on-farm emissions from farming activities, with contributions higher than 50% in most impact categories. A comparison with other LCA studies was carried out, which confirmed the consistency of these results with the values reported in the literature for dairy systems from several countries. Additionally, the Water Footprint (WF) values were also estimated according to the Water Footprint Network (WFN) methodology to reveal that feed and fodder production also had a predominant influence on the global WF impacts, with contributions of 99%. Green WF was responsible for remarkable environmental burdens (around 88%) due to the impacts associated with the cultivation stage. Finally, the substitution of alfalfa by other alternative protein sources in animal diets were also proposed and analysed due to its relevance as one of the main contributors of livestock feed. Copyright © 2017 Elsevier B.V. All rights reserved.

  12. Are nanometric films of liquid undercooled interfacial water bio-relevant?

    Science.gov (United States)

    Möhlmann, Diedrich T F

    2009-06-01

    It is known that life processes below the melting point temperature can actively evolve and establish in micrometer-sized (and larger) veins and structures in ice and permafrost soil, filled with unfrozen water. Thermodynamic arguments and experimental results indicate the existence of much smaller nanometer sized thin films of undercooled liquid interfacial (ULI) water on surfaces of micrometer sized and larger mineral particles and microbes in icy environments far below the melting point temperature. This liquid interfacial water can be described in terms of a freezing point depression, which is due to the interfacial pressure of van der Waals forces. The physics behind the possibly also life supporting capability of nanometric films of undercooled liquid interfacial water, which also can "mantle" the surfaces of the much larger and micrometer-sized microbes, is discussed. As described, biological processes do not necessarily have to proceed in the "bulk" of the thin interfacial water, as in "vinical" water and in the micrometer sized veins e.g., but they can be supported or are even made possible already by covering thin mantles of liquid interfacial water. These can provide liquid water for metabolic processes and act as carrier for the necessary transport of nutrients and waste. ULI water supports two different and possibly biologically relevant transport processes: 2D molecular diffusion in the interfacial film, and flow-like due to regelation. ULI-water, which is "lost" by transport into microbes, e.g., will be refilled from the neighbouring ice. In this way, the nanometric liquid environment of microbes in ULI-water is comparable to that of microbes in bulk water. Another probably also biologically relevant property of ULI is, depending on the hydrophobic or hydrophilic character of the surfaces, that it is of lower density (LDL) or higher density (HDL) than bulk water. Furthermore, capillary effects and ions in ULI-water solutions can support, enhance, and

  13. Improvement of sustainability indicators when traditional water management changes: a case study in Alicante (Spain

    Directory of Open Access Journals (Sweden)

    Laura Romero

    2017-05-01

    Full Text Available Pressurized water systems are designed to guarantee the flow demanded by each user, considering the minimum required pressure. The pressurized water systems have increased water efficiency since their implantation, but they also increased the consumed energy and therefore, the greenhouse gasses emissions. The present manuscript develops the proposal of the sustainable indicators that were selected through deep review. These indicators are related to social-cultural, economic, and environmental criteria. Furthermore as novelty, they were described and applied on a pressurized water network, complementing the energy indexes usually used in the energy audit. To reach the improvement of the sustainability in water systems, new strategies should be developed to improve all sustainability criteria, included the water and energy efficiency. These strategies were developed and analyzed by using of specific hydraulic software (i.e., EPANET and they were based on operation rules to estimate the hydraulic values (pressure and flow. The operation and the regulation strategies were applied on a particular case study, in which, the energy saving was 12.26%, the cost saving was 15.54%, the reduction of energy footprint of water was 15.04%, and the decrease of GHG was 12.26% although the increase of the distributed volume was 9.07%. Besides, the supply guarantee for both irrigation and urban water distribution systems was increased in the new proposal of water management. Finally, the proposal to replace of a pressure reduction valve by a sustainability recovery machine (e.g., pump working as turbine contributed with a generation of renewable energy equal to 103,710 kWh/year.

  14. Recycling Carbon Dioxide into Sustainable Hydrocarbon Fuels: Electrolysis of Carbon Dioxide and Water

    Science.gov (United States)

    Graves, Christopher Ronald

    Great quantities of hydrocarbon fuels will be needed for the foreseeable future, even if electricity based energy carriers begin to partially replace liquid hydrocarbons in the transportation sector. Fossil fuels and biomass are the most common feedstocks for production of hydrocarbon fuels. However, using renewable or nuclear energy, carbon dioxide and water can be recycled into sustainable hydrocarbon fuels in non-biological processes which remove oxygen from CO2 and H2O (the reverse of fuel combustion). Capture of CO2 from the atmosphere would enable a closed-loop carbon-neutral fuel cycle. The purpose of this work was to develop critical components of a system that recycles CO2 into liquid hydrocarbon fuels. The concept is examined at several scales, beginning with a broad scope analysis of large-scale sustainable energy systems and ultimately studying electrolysis of CO 2 and H2O in high temperature solid oxide cells as the heart of the energy conversion, in the form of three experimental studies. The contributions of these studies include discoveries about electrochemistry and materials that could significantly improve the overall energy use and economics of the CO2-to-fuels system. The broad scale study begins by assessing the sustainability and practicality of the various energy carriers that could replace petroleum-derived hydrocarbon fuels, including other hydrocarbons, hydrogen, and storage of electricity on-board vehicles in batteries, ultracapacitors, and flywheels. Any energy carrier can store the energy of any energy source. This sets the context for CO2 recycling -- sustainable energy sources like solar and wind power can be used to provide the most energy-dense, convenient fuels which can be readily used in the existing infrastructure. The many ways to recycle CO2 into hydrocarbons, based on thermolysis, thermochemical loops, electrolysis, and photoelectrolysis of CO2 and/or H 2O, are critically reviewed. A process based on high temperature co

  15. Water Hyacinth in China: A Sustainability Science-Based Management Framework

    Science.gov (United States)

    Lu, Jianbo; Wu, Jianguo; Fu, Zhihui; Zhu, Lei

    2007-12-01

    The invasion of water hyacinth ( Eichhornia crassipes) has resulted in enormous ecological and economic consequences worldwide. Although the spread of this weed in Africa, Australia, and North America has been well documented, its invasion in China is yet to be fully documented. Here we report that since its introduction about seven decades ago, water hyacinth has infested many water bodies across almost half of China’s territory, causing a decline of native biodiversity, alteration of ecosystem services, deterioration of aquatic environments, and spread of diseases affecting human health. Water hyacinth infestations have also led to enormous economic losses in China by impeding water flows, paralyzing navigation, and damaging irrigation and hydroelectricity facilities. To effectively control the rampage of water hyacinth in China, we propose a sustainability science-based management framework that explicitly incorporates principles from landscape ecology and Integrated Pest Management. This framework emphasizes multiple-scale long-term monitoring and research, integration among different control techniques, combination of control with utilization, and landscape-level adaptive management. Sustainability science represents a new, transdisciplinary paradigm that integrates scientific research, technological innovation, and socioeconomic development of particular regions. Our proposed management framework is aimed to broaden the currently dominant biological control-centered view in China and to illustrate how sustainability science can be used to guide the research and management of water hyacinth.

  16. Water hyacinth in China: a sustainability science-based management framework.

    Science.gov (United States)

    Lu, Jianbo; Wu, Jianguo; Fu, Zhihui; Zhu, Lei

    2007-12-01

    The invasion of water hyacinth (Eichhornia crassipes) has resulted in enormous ecological and economic consequences worldwide. Although the spread of this weed in Africa, Australia, and North America has been well documented, its invasion in China is yet to be fully documented. Here we report that since its introduction about seven decades ago, water hyacinth has infested many water bodies across almost half of China's territory, causing a decline of native biodiversity, alteration of ecosystem services, deterioration of aquatic environments, and spread of diseases affecting human health. Water hyacinth infestations have also led to enormous economic losses in China by impeding water flows, paralyzing navigation, and damaging irrigation and hydroelectricity facilities. To effectively control the rampage of water hyacinth in China, we propose a sustainability science-based management framework that explicitly incorporates principles from landscape ecology and Integrated Pest Management. This framework emphasizes multiple-scale long-term monitoring and research, integration among different control techniques, combination of control with utilization, and landscape-level adaptive management. Sustainability science represents a new, transdisciplinary paradigm that integrates scientific research, technological innovation, and socioeconomic development of particular regions. Our proposed management framework is aimed to broaden the currently dominant biological control-centered view in China and to illustrate how sustainability science can be used to guide the research and management of water hyacinth.

  17. Agricultural Water Use Sustainability Assessment in the Tarim River Basin under Climatic Risks

    Directory of Open Access Journals (Sweden)

    Jun Zhang

    2018-02-01

    Full Text Available Proper agricultural water management in arid regions is the key to tackling climatic risks. However, an effective assessment of the current response to climate change in agricultural water use is the precondition for a group adaptation strategy. The paper, taking the Tarim River basin (TRB as an example, aims to examine the agricultural water use sustainability of water resource increase caused by climatic variability. In order to describe the response result, groundwater change has been estimated based on the Gravity Recovery and Climate Experiment (GRACE and the Global Land Data Assimilation System (GLDAS–Noah land surface model (NOAH data. In order to better understand the relationship between water resource increase and agricultural water consumption, an agricultural water stress index has been established. Agricultural water stress has been in a severe state during the whole period, although it alleviated somewhat in the mid–late period. This paper illustrates that an increase in water supply could not satisfy agricultural production expansion. Thus, seasonal groundwater loss and a regional water shortage occurred. Particularly in 2008 and 2009, the sharp shortage of water supply in the Tarim River basin directly led to a serious groundwater drop by nearly 20 mm from the end of 2009 to early 2010. At the same time, a regional water shortage led to water scarcity for the whole basin, because the water consumption, which was mainly distributed around Source Rivers, resulted in break-off discharge in the mainstream. Therefore, current agricultural development in the Tarim River basin is unsustainable in the context of water supply under climatic risks. Under the control of irrigation, spatial and temporal water allocation optimization is the key to the sustainable management of the basin.

  18. Global Assessments and Guidelines for Sustainable Liquid Biofuel Production in Developing Countries : Final report

    NARCIS (Netherlands)

    Bernd, F.; Reinhardt, G.; Malavelle, J.; Faaij, A.|info:eu-repo/dai/nl/10685903X; van Eijck, Janske|info:eu-repo/dai/nl/297954296; van der Hilst, Floortje|info:eu-repo/dai/nl/314099905; Batidzirai, Batidzirai|info:eu-repo/dai/nl/341355909; Fritsche, U.

    The Global Environment Facility (GEF) aims to set clear policies and priorities for future work and investments in biofuel related projects and to provide guidance to countries on how to select sustainable biofuel projects. Three UN agencies, UNEP, UNIDO and FAO, in collaboration with three research

  19. Deploying liquid biomethane in the Dutch transport sector. Analysing economic, environmental and organisational sustainability.

    NARCIS (Netherlands)

    Breeuwer, Jelco

    2012-01-01

    SUMMARY The Dutch government has set sustainability goals for the year 2020. In that year, 16 % of the energy use must come from renewable sources and the emissions of greenhouse gasses must be reduced by 20 % with respect to 1990. These goals are part

  20. Teaching Sustainable Development Concepts in the Laboratory: A Solid-Liquid Extraction Experiment

    Science.gov (United States)

    Parajo, Juan Carlos; Dominguez, Herminia; Santos, Valentin; Alonso, Jose Luis; Garrote, Gil

    2008-01-01

    One of the principles of sustainable development is to replace chemicals traditionally derived from oil with alternative, renewable materials. For example, phenol and phenol derivatives currently used in the manufacture of wood adhesives can be replaced (at least in part) by biopolymers extracted from biomass. In this work, pine bark (a renewable…

  1. Efficiency and mechanism of demulsification of oil-in-water emulsions using ionic liquid

    NARCIS (Netherlands)

    Li, X.; Kersten, Sascha R.A.; Schuur, Boelo

    2016-01-01

    In this work, 13 ionic liquids (ILs), including 9 halogenide ILs and 4 non-halogenide ILs, were evaluated as demulsifiers for a model oil-in-water emulsion prepared with heptane and water, where sodium dodecylbenzenesulfonate (SDBS) was used as a surfactant. The separating efficiency (the fraction

  2. An evaluation method of the sustainability of water resource in karst region: a case study of Zunyi, China

    Science.gov (United States)

    Li, Bo; Wang, Ganlu; Ding, Hanghang; Chen, Yulong

    2017-06-01

    Water resource is of great significance to the survival and development of human. However, the water resource system in karst regions is sensitive to external interference owing to the special geological processes which cause soil impoverishment, severe rocky desertification and large topographic height difference. Therefore, evaluating the sustainability of the water resource in karst regions is beneficial to reasonably use and protect water resource. This paper puts forward to evaluate the water resource from four aspects, including water resources system, water requirement system, ecosystem and social economic system. Moreover, on this basis, 18 evaluation indexes were selected to construct the sustainability evaluation index system and method. This method was used to evaluate the sustainability of the water resource in the typical karst region—Zunyi, Guizhou province, China, and was verified according to the actual situation in the research area. All these provide reference for the evaluation of the sustainability of the water resource in similar regions.

  3. Study of Solid-Liquid Ratio of Fly Ash Geopolymer as Water Absorbent Material

    OpenAIRE

    Angga Prasetya Fandi; Candra Sukmana Ndaru; Anggarini Ufafa

    2017-01-01

    Geopolymer has been synthesized from fly ash to be applicated as water absorbent material. This research conducted to determine the ability of geopolymer to abrsop water by variation of solid – liquid ratio at optimum molarity of NaOH; 3 M. In this research, the synthesis of geopolymer was conducted at the variation of solid-liquid ratio; 60:40, 65:35, 70:30, and 75:25. Result of the treatment were characterized by XRD and SEM to compare the geopolymer structure. Water absorption capacity was...

  4. Automated dispersive liquid-liquid microextraction coupled to high performance liquid chromatography - cold vapour atomic fluorescence spectroscopy for the determination of mercury species in natural water samples.

    Science.gov (United States)

    Liu, Yao-Min; Zhang, Feng-Ping; Jiao, Bao-Yu; Rao, Jin-Yu; Leng, Geng

    2017-04-14

    An automated, home-constructed, and low cost dispersive liquid-liquid microextraction (DLLME) device that directly coupled to a high performance liquid chromatography (HPLC) - cold vapour atomic fluorescence spectroscopy (CVAFS) system was designed and developed for the determination of trace concentrations of methylmercury (MeHg(+)), ethylmercury (EtHg(+)) and inorganic mercury (Hg(2+)) in natural waters. With a simple, miniaturized and efficient automated DLLME system, nanogram amounts of these mercury species were extracted from natural water samples and injected into a hyphenated HPLC-CVAFS for quantification. The complete analytical procedure, including chelation, extraction, phase separation, collection and injection of the extracts, as well as HPLC-CVAFS quantification, was automated. Key parameters, such as the type and volume of the chelation, extraction and dispersive solvent, aspiration speed, sample pH, salt effect and matrix effect, were thoroughly investigated. Under the optimum conditions, linear range was 10-1200ngL(-1) for EtHg(+) and 5-450ngL(-1) for MeHg(+) and Hg(2+). Limits of detection were 3.0ngL(-1) for EtHg(+) and 1.5ngL(-1) for MeHg(+) and Hg(2+). Reproducibility and recoveries were assessed by spiking three natural water samples with different Hg concentrations, giving recoveries from 88.4-96.1%, and relative standard deviations <5.1%. Copyright © 2017 Elsevier B.V. All rights reserved.

  5. Formation of Martian Gullies by the Flow of Simultaneously Freezing and Boiling Liquid Water

    Science.gov (United States)

    Heldmann, Jennifer L.; Mellon, Michael T.; Toon, Owen B.; Pollard, Wayne H.; Mellon, Michael T.; Pitlick, John; McKay, Christopher P.; Andersen, Dale T.

    2004-01-01

    Geomorphic evidence suggests that recent gullies on Mars were formed by fluvial activity. The Martian gully features are significant because their existence implies the presence of liquid water near the surface on Mars in geologically recent times. Irrespective of the ultimate source of the fluid carving the gullies, we seek to understand the behavior of this fluid after it reaches the Martian surface. We find that, contrary to popular belief, the fluvially-carved Martian gullies require formation conditions such as now occur on Mars, outside of the temperature-pressure stability regime of liquid water. Mars Global Surveyor observations of gully length and our modeling of water stability are consistent with gully formation from the action of pure liquid water that is simultaneously boiling and freezing.

  6. Mesoscopic modeling of liquid water transport in polymer electrolyte fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Mukherjee, Partha P [Los Alamos National Laboratory; Wang, Chao Yang [PENNSTATE UNIV.

    2008-01-01

    A key performance limitation in polymer electrolyte fuel cells (PEFC), manifested in terms of mass transport loss, originates from liquid water transport and resulting flooding phenomena in the constituent components. Liquid water leads to the coverage of the electrochemically active sites in the catalyst layer (CL) rendering reduced catalytic activity and blockage of the available pore space in the porous CL and fibrous gas diffusion layer (GDL) resulting in hindered oxygen transport to the active reaction sites. The cathode CL and the GDL therefore playa major role in the mass transport loss and hence in the water management of a PEFC. In this article, we present the development of a mesoscopic modeling formalism coupled with realistic microstructural delineation to study the profound influence of the pore structure and surface wettability on liquid water transport and interfacial dynamics in the PEFC catalyst layer and gas diffusion layer.

  7. Catalysing low cost green technologies for sustainable water service delivery in Kenya: Feasibility Study Report

    DEFF Research Database (Denmark)

    Ndirangu, Wangai; Schaer, Caroline

    2017-01-01

    Since 1974, the government of Kenya has recognised water supplies as critical for poverty reduction and development. Kenya’s economic and social development Vision 2030 emphasises the need for adequate and sustainable provision of water supply and sanitation services, with a target to achieve...... universal access by 2030. However, thus far most water development targets have not been achieved. Improvement has been much slower in rural and low income urban areas, and the current funding level is inadequate to achieve universal access by 2030. Over the years, official effort have been complemented...... to planning, standards and operations and maintenance, including source and cost of energy in rural and peri-urban water supplies is a key challenge to functionality and sustainability....

  8. Supported liquid membrane-liquid chromatography-mass spectrometry analysis of cyanobacterial toxins in fresh water systems

    Science.gov (United States)

    Mbukwa, Elbert A.; Msagati, Titus A. M.; Mamba, Bhekie B.

    Harmful algal blooms (HABs) are increasingly becoming of great concern to water resources worldwide due to indiscriminate waste disposal habits resulting in water pollution and eutrophication. When cyanobacterial cells lyse (burst) they release toxins called microcystins (MCs) that are well known for their hepatotoxicity (causing liver damage) and have been found in eutrophic lakes, rivers, wastewater ponds and other water reservoirs. Prolonged exposure to low concentrated MCs are equally of health importance as they are known to be bioaccumulative and even at such low concentration do exhibit toxic effects to aquatic animals, wildlife and human liver cells. The application of common treatment processes for drinking water sourced from HABs infested reservoirs have the potential to cause algal cell lyses releasing low to higher amounts of MCs in finished water. Trace microcystins in water/tissue can be analyzed and quantified using Liquid chromatography-electrospray ionization-mass spectrometry (LC-ESI-MS) following solid-phase extraction (SPE) sample clean-up procedures. However, extracting MCs from algal samples which are rich in chlorophyll pigments and other organic matrices the SPE method suffers a number of drawbacks, including cartridge clogging, long procedural steps and use of larger volumes of extraction solvents. We applied a supported liquid membrane (SLM) based technique as an alternative sample clean-up method for LC-ESI-MS analysis of MCs from both water and algal cells. Four (4) MC variants (MC-RR, -YR, -LR and -WR) from lyophilized cells of Microcystis aeruginosa and water collected from a wastewater pond were identified) and quantified using LC-ESI-MS following a SLM extraction and liquid partitioning step, however, MC-WR was not detected from water extracts. Within 45 min of SLM extraction all studied MCs were extracted and pre-concentrated in approximately 15 μL of an acceptor phase at an optimal pH 2.02 of the donor phase (sample). The highest

  9. Potentials and problems of sustainable irrigation with water high in salts

    Science.gov (United States)

    Ben-Gal, Alon

    2015-04-01

    Water scarcity and need to expand agricultural productivity have led to ever growing utilization of poor quality water for irrigation of crops. Almost in all cases, marginal or alternative water sources for irrigation contain relatively high concentrations of dissolved salts. When salts are present, irrigation water management, especially in the dry regions where water requirements are highest, must consider leaching in addition to crop evapotranspiration requirements. Leaching requirements for agronomic success are calculable and functions of climate, soil, and very critically, of crop sensitivity and the actual salinity of the irrigation water. The more sensitive the crop and more saline the water, the higher the agronomic cost and the greater the quantitative need for leaching. Israel is a forerunner in large-scale utilization of poor quality water for irrigation and can be used as a case study looking at long term repercussions of policy alternatively encouraging irrigation with recycled water or brackish groundwater. In cases studied in desert conditions of Israel, as much of half of the water applied to crops including bell peppers in greenhouses and date palms is actually used to leach salts from the root zone. The excess water used to leach salts and maintain agronomic and economic success when irrigating with water containing salts can become an environmental hazard, especially in dry areas where natural drainage is non-existent. The leachate often contains not only salts but also agrochemicals including nutrients, and natural contaminants can be picked up and transported as well. This leachate passes beyond the root zone and eventually reaches ground or surface water resources. This, together with evidence of ongoing increases in sodium content of fresh produce and increased SAR levels of soils, suggest that the current policy and practice in Israel of utilization of high amounts of low quality irrigation water is inherently non- sustainable. Current

  10. Advantages of integrated and sustainability based assessment for metabolism based strategic planning of urban water systems.

    Science.gov (United States)

    Behzadian, Kourosh; Kapelan, Zoran

    2015-09-15

    Despite providing water-related services as the primary purpose of urban water system (UWS), all relevant activities require capital investments and operational expenditures, consume resources (e.g. materials and chemicals), and may increase negative environmental impacts (e.g. contaminant discharge, emissions to water and air). Performance assessment of such a metabolic system may require developing a holistic approach which encompasses various system elements and criteria. This paper analyses the impact of integration of UWS components on the metabolism based performance assessment for future planning using a number of intervention strategies. It also explores the importance of sustainability based criteria in the assessment of long-term planning. Two assessment approaches analysed here are: (1) planning for only water supply system (WSS) as a part of the UWS and (2) planning for an integrated UWS including potable water, stormwater, wastewater and water recycling. WaterMet(2) model is used to simulate metabolic type processes in the UWS and calculate quantitative performance indicators. The analysis is demonstrated on the problem of strategic level planning of a real-world UWS to where optional intervention strategies are applied. The resulting performance is assessed using the multiple criteria of both conventional and sustainability type; and optional intervention strategies are then ranked using the Compromise Programming method. The results obtained show that the high ranked intervention strategies in the integrated UWS are those supporting both water supply and stormwater/wastewater subsystems (e.g. rainwater harvesting and greywater recycling schemes) whilst these strategies are ranked low in the WSS and those targeting improvement of water supply components only (e.g. rehabilitation of clean water pipes and addition of new water resources) are preferred instead. Results also demonstrate that both conventional and sustainability type performance indicators

  11. When good practices by water committees are not relevant: Sustainability of small water infrastructures in semi-arid mozambique

    Science.gov (United States)

    Ducrot, Raphaëlle

    2017-12-01

    This paper explores the contradiction between the need for large scale interventions in rural water supplies and the need for flexibility when providing support for community institutions, by investigating the implementation of the Mozambique - National Rural Water Supply and Sanitation Program in a semi-arid district of the Limpopo Basin. Our results showed that coordinated leadership by key committee members, and the level of village governance was more important for borehole sustainability than the normative functioning of the committee. In a context in which the centrality of leadership prevails over collective action the sustainability of rural water infrastructure derives from the ability of leaders to motivate the community to provide supplementary funding. This, in turn, depends on the added value to the community of the water points and on village politics. Any interventions that increased community conflicts, for example because of lack of transparency or unequitable access to the benefit of the intervention, weakened the coordination and the collective action capacity of the community and hence the sustainability of the infrastructures even if the intervention was not directly related to water access. These results stress the importance of the project/program implementation pathway.

  12. Whole systems thinking for sustainable water treatment design

    Science.gov (United States)

    Huggins, Mitchell Tyler

    Microbial fuel cell (MFC) technology could provide a low cost alternative to conventional aerated wastewater treatment, however there has been little comparison between MFC and aeration treatment using real wastewater substrate. This study attempts to directly compare the wastewater treatment efficiency and energy consumption and generation among three reactor systems, a traditional aeration process, a simple submerged MFC configuration, and a control reactor acting similar as natural lagoons. Results showed that all three systems were able to remove >90% of COD, but the aeration used shorter time (8 days) then the MFC (10 days) and control reactor (25 days). Compared to aeration, the MFC showed lower removal efficiency in high COD concentration but much higher efficiency when the COD is low. Only the aeration system showed complete nitrification during the operation, reflected by completed ammonia removal and nitrate accumulation. Suspended solid measurements showed that MFC reduced sludge production by 52-82% as compared to aeration, and it also saved 100% of aeration energy. Furthermore, though not designed for high power generation, the MFC reactor showed a 0.3 Wh/g COD/L or 24 Wh/m3 (wastewater treated) net energy gain in electricity generation. These results demonstrate that MFC technology could be integrated into wastewater infrastructure to meet effluent quality and save operational cost. The high cost and life-cycle impact of electrode materials is one major barrier to the large scale application of microbial fuel cells (MFC). We also demonstrate that biomass-derived black carbon (biochar), could be a more cost effective and sustainable alternative to granular activated carbon (GAC) and graphite granule (GG) electrodes. In a comparison study, two biochar materials made from lodgepole pine sawdust pellets (BCp) and lodgepole pine woodchips (BCc), gassified at a highest heat temperature (HHT) of 1000°C under a heating rate of 16°C/min, showed a

  13. Liquid-liquid equilibria for binary and ternary systems containing glycols, aromatic hydrocarbons, and water: Experimental measurements and modeling with the CPA EoS

    DEFF Research Database (Denmark)

    Folas, Georgios; Kontogeorgis, Georgios; Michelsen, Michael Locht

    2006-01-01

    Liquid-liquid equilibrium data of four binary glycol + aromatic hydrocarbon systems and three ternary systems containing water have been measured at atmospheric pressure. The measured systems are monoethylene glycol (MEG) + benzene or toluene, triethylene glycol (TEG) + benzene or toluene, MEG...... + water + benzene, MEG + water + toluene, and TEG + water + toluene. The binary systems are correlated with the Cubic-Plus-Association (CPA) equation of state while the ternary systems are predicted from interaction parameters obtained from the binary systems. Very satisfactory liquid-liquid equilibrium...... correlations are obtained for the binary systems using temperature-independent interaction parameters, while adequate predictions are achieved for multicomponent water + glycol + aromatic hydrocarbons systems when accounting for the solvation between the aromatic hydrocarbons and glycols or water....

  14. Evaluating the role of postconstruction support in sustaining drinking water projects : Evidence from Peru

    OpenAIRE

    Wakeman, W.; Thorsten, R.; Prokopy, L. S.; Bakalian, A.

    2008-01-01

    This article assesses the impact of postconstruction support (PCS) on the sustainability of participatory, demand-driven rural water projects in the Cuzco region of Peru. This Study evaluates ninety-nine villages from two water supply schemes-projects built under a social investment fund program and those built under a nongovernmental program funded by the Swiss government. Overall, the study finds that the projects are performing very well. Multivariate regression analysis suggests that hous...

  15. Exploring pathways for sustainable water management in river deltas in a changing environment

    NARCIS (Netherlands)

    Haasnoot, Marjolijn; Middelkoop, H.; Offermans, A.; van Beek, Eelco; van Deursen, W.P.A.

    2012-01-01

    Exploring adaptation pathways into an uncertain future can support decisionmaking in achieving sustainable water management in a changing environment. Our objective is to develop and test a method to identify such pathways by including dynamics from natural variability and the interaction between

  16. Extreme events: being prepared for the pitfalls with progressing sustainable urban water management.

    Science.gov (United States)

    Keath, N A; Brown, R R

    2009-01-01

    It is widely accepted that new, more sustainable approaches to urban water management are required if cities and ecosystems are to become resilient to the effects of growing urban populations and global warming. Climate change predictions show that it is likely that cities around the world will be subject to an increasing number of extreme and less predictable events including flooding and drought. Historical transition studies have shown that major events such as extremes can expedite the adoption of new practices by destabilising existing management regimes and opening up new windows of opportunity for change. Yet, they can also act to reinforce and further entrench old practices. This case study of two Australian cities responding to extreme water scarcity reveals that being unprepared for extremes can undermine progress towards sustainable outcomes. The results showed that despite evidence of significant progress towards sustainable urban water management in Brisbane and Melbourne, the extreme water scarcity acted to reinforce traditional practices at the expense of emerging sustainability niches. Drawing upon empirical research and transitions literature, recommendations are provided for developing institutional mechanisms that are able to respond proactively to extreme events and be a catalyst for SUWM when such opportunities for change arise.

  17. Sustained Release of a Water~§oiuble itrng i'rom Directly ...

    African Journals Online (AJOL)

    desirable properties have encouraged a more extensive assessment of the gum as a hydrophilic controlled release delivery system. The aim of this study was to evaluate the gum extracted from the pods of Hibiscus esculentus. (commonly known as okra) in in vitro sustained release formulations containing the water-.

  18. The Narew River Basin: A model for the sustainable management of agriculture, nature and water supply

    NARCIS (Netherlands)

    Gielczewski, Marek

    2003-01-01

    This thesis is a search for a method of environmental management that may lead to sustainable development in North-eastern Poland and the Warsaw region. The methods studied in this thesis provide the components of a decision support system for managing the water quality of the Narew River

  19. Critical insights for a sustainability framework to address integrated community water services: Technical metrics and approaches

    Science.gov (United States)

    Planning for sustainable community water systems requires a comprehensive understanding and assessment of the integrated source-drinking-wastewater systems over their life-cycles. Although traditional life cycle assessment and similar tools (e.g. footprints and emergy) have been ...

  20. Journal of Sustainable Development of Energy, Water and Environment Systems – Volume IV

    Directory of Open Access Journals (Sweden)

    Neven Duić

    2016-12-01

    In total 32 manuscripts were published in Volume IV, all of them reviewed by at least two reviewers. The Journal of Sustainable Development of Energy, Water and Environment Systems would like to thank reviewers for their contribution to the quality of the published manuscripts.

  1. Journal of Sustainable Development of Energy, Water and Environment Systems – Volume I

    Directory of Open Access Journals (Sweden)

    Neven Duić

    2013-12-01

    In total 28 manuscripts were published in Volume I, all of them reviewed by at least two reviewers. The Journal of Sustainable Development of Energy, Water and Environment Systems would like to thank reviewers for their contribution to the quality of the published manuscripts.

  2. The Myth of 'Tragedy of the Commons' in Sustaining Water Resources

    African Journals Online (AJOL)

    Ayele_H_A

    2010-08-31

    Aug 31, 2010 ... The Myth of 'Tragedy of the Commons' in Sustaining Water Resources. 311. 1. Basic Assumptions of the Tragedy of the Commons. Theory. 1.1 The concepts of the tragedy of the commons. The fear of the ruin of scarce natural resources by human action is not a new idea. Hardin published an article in ...

  3. Dragonflies as Flagships for Sustainable Use of Water Resources in Environmental Education

    Science.gov (United States)

    Clausnitzer, Viola; Simaika, John P.; Samways, Michael J.; Daniel, B. A.

    2017-01-01

    Sustainable use of freshwater is globally important. Yet implementation of changes in water management is poor, especially in developing countries. This is an indication that, despite our dependence on freshwater, we lack awareness of the need to protect these systems. Here we promote dragonflies as an easy-to-learn tool in environmental education…

  4. Sustainability of Water Safety Plans Developed in Sub-Saharan Africa

    Directory of Open Access Journals (Sweden)

    Luca Rondi

    2015-08-01

    Full Text Available In developing countries, the drinking water supply is still an open issue. In sub-Saharan Africa, only 68% of the population has access to improved sources of drinking water. Moreover, some regions are affected by geogenic contaminants (e.g., fluoride and arsenic and the lack of access to sanitation facilities and hygiene practices causes high microbiological contamination of drinking water in the supply chain. The Water Safety Plan (WSP approach introduced by the World Health Organisation (WHO in 2004 is now under development in several developing countries in order to face up to these issues. The WSP approach was elaborated within two cooperation projects implemented in rural areas of Burkina Faso and Senegal by two Italian NGOs (Non-Governmental Organisations. In order to evaluate its sustainability, a questionnaire based on five different sustainability elements and a cost and time consumption evaluation were carried out and applied in both the case studies. Results demonstrated that the questionnaire can provide a useful and interesting overview regarding the sustainability of the WSP; however, further surveys in the field are recommended for gathering more information. Time and costs related to the WSP elaboration, implementation, and management were demonstrated not to be negligible and above all strongly dependent on water quality and the water supply system complexity.

  5. The role of hydroclimate and water use on freshwater sustainability over the conterminous US.

    Science.gov (United States)

    Arumugam, S.; Ruhi, A.; Sabo, J. L.; Sinha, T.; Das Bhowmik, R.; Seo, S. B.

    2015-12-01

    A synthesis on freshwater sustainability is investigated across the conterminous US (CONUS). Spatio-temporal variability of potential drivers - hydroclimate and water use - influencing the freshwater sustainability are examined both individually as well as collectively by considering the eco-region and 4-digit Hydrologic Unit Code (HUC-4)as the spatial reference for the analysis. A detailed multivariate analysis relating the potential drivers with downstream flow anomalies indicate that changes in hydroclimate and water use adequately quantify the variability in downstream anomalies, but their signature varies significnatly across various regions of the CONUS. Results from the analysis indicate that both hydroclimatic extremes and mean annual fluxes control, but their signature alos vary across the CONUS. Among the changes in water use, irrigation water use predominantly carries the signature in explaining the downstream flow anomalies. To adequately express the sensitivity of downstream flow anomalies to hydroclimate and water use, we compute the elasticity of downstream flow anomalies to changes in hydroclimate and water use for each HUC8 regions of the US. Differences between the multivariate analysis and the elasticity estimates of freshwater sustainability are also discussed.

  6. Determination of trace levels of dinitrophenolic compounds by microporous membrane liquid-liquid extraction in environmental water samples.

    Science.gov (United States)

    Bartolomé, Luis; Lezamiz, Jon; Etxebarria, Néstor; Zuloaga, Olatz; Jönsson, Jan Ake

    2007-08-01

    A fast and simple hollow fibre-based microporous membrane liquid-liquid extraction (MMLLE) method is proposed for the determination of trace levels of dinitrophenolic compounds in water samples. The optimization step was performed using a three-variables Doehlert matrix design, involving the fibre length, the quantity of trioctylphosphine oxide (TOPO) in the acceptor phase and the extraction time. Using the established experimental conditions, some other parameters such as stirring speed, salt content, humic acids and different organic solvents as the acceptor phase were studied. Validation of the method included calibration experiments, linearity studies and determination of method LOD (MLD). The RSD was around 11% in all the experiments on different days at different concentrations. Separation and detection of four dinitrophenols were performed in 10 min with an RP-LC and a C(8 )column ACN-citric buffer gradient elution and diode array detection.

  7. Sustainable Liquid Biofuels from Biomass Biorefining (SUNLIBB). Policy Brief No. 1

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2012-03-01

    The SUNLIBB project is funded under the European Seventh Framework Programme (FP7) within the Energy theme: Second Generation Biofuels -- EU Brazil Coordinated Call. SUNLIBB started on 1 October 2010 for 4 years and collaborates with a parallel project in Brazil, CeProBIO. First generation biofuels -- which are mainly produced from food crops such as grains, sugarcane and vegetable oils -- have triggered one of the most highly contentious debates on the current international sustainability agenda, given their links to energy security, transport, trade, food security, land-use impacts and climate change concerns. Developing second generation biofuels has emerged as a more attractive option, as these are manufactured from inedible sources, such as woody crops, energy grasses, or even agricultural and forestry residues. Residues from sugarcane and biomass from maize, as well as 'whole-crop' miscanthus are all potential raw material (called 'feedstock') for second generation bioethanol production. Because these three plants are all closely related, processing the biomass from these crops raises common technical challenges, which offers the opportunity for breakthroughs in one species to be rapidly exploited in the others. Despite the potential sustainability benefits of second generation bioethanol, the current inefficiency of production makes it economically uncompetitive. Taking up this challenge, the SUNLIBB consortium's multidisciplinary team of scientists -- in cooperation with CeProBIO, the sister project in Brazil -- combines European and Brazilian research strengths so as to open the way for environmentally, socially and economically sustainable second generation bioethanol production.

  8. Correlation of vapor - liquid equilibrium data for acetic acid - isopropanol - water - isopropyl acetate mixtures

    Directory of Open Access Journals (Sweden)

    B. A. Mandagarán

    2006-03-01

    Full Text Available A correlation procedure for the prediction of vapor - liquid equilibrium of acetic acid - isopropanol - water - isopropyl acetate mixtures has been developed. It is based on the NRTL model for predicting liquid activity coefficients, and on the Hayden-O'Connell second virial coefficients for predicting the vapor phase of systems containing association components. When compared with experimental data the correlation shows a good agreement for binary and ternary data. The correlation also shows good prediction for reactive quaternary data.

  9. Stripping of acetone from water with microfabricated and membrane gas-liquid contactors.

    Science.gov (United States)

    Constantinou, Achilleas; Ghiotto, Francesco; Lam, Koon Fung; Gavriilidis, Asterios

    2014-01-07

    Stripping of acetone from water utilizing nitrogen as a sweeping gas in co-current flow was conducted in a microfabricated glass/silicon gas-liquid contactor. The chip consisted of a microchannel divided into a gas and a liquid chamber by 10 μm diameter micropillars located next to one of the channel walls. The channel length was 35 mm, the channel width was 220 μm and the microchannel depth 100 μm. The micropillars were wetted by the water/acetone solution and formed a 15 μm liquid film between them and the nearest channel wall, leaving a 195 μm gap for gas flow. In addition, acetone stripping was performed in a microchannel membrane contactor, utilizing a hydrophobic PTFE membrane placed between two microstructured acrylic plates. Microchannels for gas and liquid flows were machined in the plates and had a depth of 850 μm and 200 μm respectively. In both contactors the gas/liquid interface was stabilized: in the glass/silicon contactor by the hydrophilic micropillars, while in the PTFE/acrylic one by the hydrophobic membrane. For both contactors separation efficiency was found to increase by increasing the gas/liquid flow rate ratio, but was not affected when increasing the inlet acetone concentration. Separation was more efficient in the microfabricated contactor due to the very thin liquid layer employed.

  10. Nanosecond Discharge in Bubbled Liquid n-Heptane: Effects of Gas Composition and Water Addition

    KAUST Repository

    Hamdan, Ahmad

    2016-08-30

    Recently, an aqueous discharge reactor was developed to facilitate reformation of liquid fuels by in-liquid plasma. To gain a microscopic understanding of the physical elements behind this aqueous reactor, we investigate nanosecond discharges in liquid n-heptane with single and double gaseous bubbles in the gap between electrodes. We introduce discharge probability (DP) to characterize the stochastic nature of the discharges, and we investigate the dependence of DP on the gap distance, applied voltage, gaseous bubble composition, and the water content in n-heptane/distilled-water emulsified mixtures. Propagation of a streamer through the bubbles indicates no discharges in the liquids. DP is controlled by the properties of the gaseous bubble rather than by the composition of the liquid mixture in the gap with a single bubble; meanwhile, DP is determined by the dielectric permittivity of the liquid mixture in the gap with double bubbles, results that are supported by static electric field simulations. We found that a physical mechanism of increasing DP is caused by an interaction between bubbles and an importance of the dielectric permittivity of a liquid mixture on the local enhancement of field intensity. We also discuss detailed physical characteristics, such as plasma lifetime and electron density within the discharge channel, by estimating from measured emissions with a gated-intensified charge-coupled device and by using spectroscopic images, respectively. © 1973-2012 IEEE.

  11. In Situ Characterization of Boehmite Particles in Water Using Liquid SEM

    Energy Technology Data Exchange (ETDEWEB)

    Yao, Juan; Arey, Bruce W.; Yang, Li; Zhang, Fei; Komorek, Rachel E.; Chun, Jaehun; Yu, Xiao-Ying

    2017-09-27

    In situ imaging and elemental analysis of boehmite (AlOOH) particles in water is realized using the System for Analysis at the Liquid Vacuum Interface (SALVI) and Scanning Electron Microscopy (SEM). This paper describes the method and key steps in integrating the vacuum compatible SAVLI to SEM and obtaining secondary electron (SE) images of particles in liquid in high vacuum. Energy dispersive x-ray spectroscopy (EDX) is used to obtain elemental analysis of particles in liquid. A synthesized AlOOH particle is used as a model in the liquid SEM illustration. Our results demonstrate that particles can be imaged in the SE mode with good resolution. The AlOOH EDX spectrum shows significant signal from the Al compared with deionized water and the empty channel control. In situ liquid SEM is a powerful technique to study particles in liquid with many exciting applications. This procedure aims to provide technical details in how to conduct liquid SEM imaging and EDX analysis using SALVI and reduce potential pitfalls using this approach for other researchers.

  12. Gas-liquid-liquid equilibria in mixtures of water, light gases, and hydrocarbons

    Energy Technology Data Exchange (ETDEWEB)

    Chao, K.C.

    1990-01-01

    Phase equilibrium in mixtures of water + light gases and water + heavy hydrocarbons has been investigated with the development of new local composition theory, new equations of state, and new experimental data. The preferential segregation and orientation of molecules due to different energies of molecular interaction has been simulated with square well molecules. Extensive simulation has been made for pure square well fluids and mixtures to find the local composition at wide ranges of states. A theory of local composition has been developed and an equation of state has been obtained for square well fluids. The new local composition theory has been embedded in several equations of state. The pressure of water is decoupled into a polar pressure and non-polar pressure according to the molecular model of water of Jorgensen et al. The polar pressure of water is combined with the BACK equation for the general description of polar fluids and their mixtures. Being derived from the steam table, the Augmented BACK equation is particularly suited for mixtures of water + non-polar substances such as the hydrocarbons. The hydrophobic character of the hydrocarbons had made their mixtures with water a special challenge. A new group contribution equation of state is developed to describe phase equilibrium and volumetric behavior of fluids while requiring only to know the molecular structure of the components. 15 refs., 1 fig.

  13. The future of water resources systems analysis: Toward a scientific framework for sustainable water management

    National Research Council Canada - National Science Library

    Brown, Casey M; Lund, Jay R; Cai, Ximing; Reed, Patrick M; Zagona, Edith A; Ostfeld, Avi; Hall, Jim; Characklis, Gregory W; Yu, Winston; Brekke, Levi

    2015-01-01

    This paper presents a short history of water resources systems analysis from its beginnings in the Harvard Water Program, through its continuing evolution toward a general field of water resources systems science...

  14. Quantum cluster equilibrium theory treatment of hydrogen-bonded liquids: water, methanol and ethanol

    Science.gov (United States)

    Borowski, Piotr; Jaroniec, Justyna; Janowski, Tomasz; Woliński, Krzysztof

    2003-01-01

    The quantum cluster equilibrium (QCE) theory was used in order to predict the composition of the hydrogen bonded liquids: water, methanol and ethanol. The calculations were based on high accuracy theoretical data obtained at the DFT/B3LYP/6-311G(d,p) level of theory. All investigated liquids are predicted to be composed of big clusters: hexamers in the case of water, tetramers, pentamers, hexamers and heptamers in the case of methanol and pentamers in the case of ethanol. The content of big clusters in a liquid phase as predicted by QCE is overestimated. We have found two confirmations of this. First of all, the behaviour of the liquid water isobar clearly demonstrates that there should be a substantial amount of small clusters in order to obtain the correct temperature dependence of the molar volume. Indeed, the theoretical molar volume close to the boiling point is by about 0.6 cm3 lower than the experimental one. The molar volume is too low due to the overestimated population of big clusters resulting in too high a liquid density. Second, the temperature dependence of the chemical shift of the hydroxyl protons in liquid methanol and ethanol, obtained as the population weighted average of the chemical shift of individual clusters, is shifted down field as compared to experiment by as much as 2 ppm. This is because big clusters with strongly deshielded hydroxyl protons contribute too much to the weighted average. Possible shortcomings of the QCE approach are discussed.

  15. Water Sciences - Connecting the dots to achieve the 2030 Agenda for Sustainable Development

    Science.gov (United States)

    Uhlenbrook, Stefan; Ortigara, Angela; Minelli, Lucilla

    2017-04-01

    Land use change, urbanisation, climate change, demographic development and migration, conflicts and peace, change of diets, industry 4.0, globalisation etc. are among the challenges that water sciences need to address to serve societal needs. Water availability per capita is decreasing, water quality is deteriorating at many places, but water demand is continuously escalating. Business as usual in water science is not up to the related challenges. In fact, business as usual cannot be the answer in all aspects, i.e. also current policy making processes will need to improve and take stock of evidences provided by science in order to better address societal challenges. However, exciting developments have been taking place. The global community agreed on a new and ambitious agenda for development, which aims to be comprehensive and include the participation of all stakeholders in one integrated framework. The 2030 Agenda for Sustainable Development provides a stimulating new era, with unique opportunities to reconcile science, society and policy making. Hydrology and water management - in all its facets including wastewater - play a central role in the Agenda 2030, as it is not only central in Sustainable Development Goal (SDG) 6, but it is fundamental for the realization of other SDGs related to, for instance, poverty reduction, sustainable growth, health, food security, climate change, ecosystems (land and sea), gender equality, etc. Despite the recognition of the critical importance of water in this agenda, the implementation of related policies and use of scientific developments represent a difficult task. Two main challenges remain: (i) the utilization of the knowledge and developments already available, and (ii) the need to overcome current and future knowledge gaps ensuring that scientific results support sustainable development effectively. The UN system will produce a Synthesis Report for SDG 6, which is currently being prepared by a UN-Water Task Force that

  16. Agricultural water-saving and sustainable groundwater management in Shijiazhuang Irrigation District, North China Plain

    Science.gov (United States)

    Hu, Yukun; Moiwo, Juana Paul; Yang, Yonghui; Han, Shumin; Yang, Yanmin

    2010-11-01

    SummaryNorth China Plain (NCP) is one of the most important agricultural production regions in China. A severe water shortage, due to intensive irrigation, exists in the plain. In NCP, crop water-use accounts for 70% of total groundwater use in the floodplains and over 87% in the piedmont regions. Surface water in the plain is limited and restricted for urban water supply. Agricultural production therefore heavily relies on groundwater irrigation; the main driver of groundwater depletion in the region. To address the water shortage issue, a flexible and sustainable water management method is proposed. The method integrates crop-growth and groundwater model, and ensures groundwater recovery via agricultural water-saving. The method is successfully tested for the 4763 km 2 Shijiazhuang Irrigation District in the piedmont region of Mount Taihang. The model results show that 29.2% or 135.7 mm reduction in irrigation could stop groundwater drawdown in the plain. An additional 10% reduction in irrigation pumping (i.e., a total of 39.2% or 182.1 mm) would induce groundwater recovery and restoration to the pre-development hydrologic conditions of 1956 in about 74 years. The farmers' current irrigation practices are inefficient and wasteful of the limited water resources. Under appropriate irrigation schemes therefore, grain yield loss as a result of the 39.2% agricultural water-saving is less than 10%. This minimal agronomic loss is economically acceptable, giving the ecological and environmental benefits of groundwater recovery in the study area. However, successful agricultural water-saving requires not only practical feasibility of models, but also sufficient political commitment, promotion of water-saving incentives and efficient water-saving technologies, and enforcement of sustainable water management policies.

  17. Adapting rice production to climate change for sustainable blue water consumption: an economic and virtual water analysis

    Science.gov (United States)

    Darzi-Naftchali, Abdullah; Karandish, Fatemeh

    2017-12-01

    Sustainable utilization of blue water resources under climate change is of great significance especially for producing high water-consuming crops in water-scarce regions. Based on the virtual water concept, we carried out a comprehensive field-modeling research to find the optimal agricultural practices regarding rice blue water consumption under prospective climate change. The DSSAT-CERES-Rice model was used in combination with 20 GCMs under three Representative Concentration Pathways of low (RCP2.6), intermediate (RCP4.6), and very high (RCP8.5) greenhouse concentrations to predict rice yield and water requirement and related virtual water and economic return for the base and future periods. The crop model was calibrated and validated based on the 2-year field data obtained from consolidated paddy fields of the Sari Agricultural Sciences and Natural Resources University during 2011 and 2012 rice cropping cycles. Climate change imposes an increase of 0.02-0.04 °C in air temperature which consequently shifts rice growing seasons to winter season, and shorten the length of rice physiological maturity period by 2-15 days. While rice virtual water reduces by 0.1-20.6% during 2011-2070, reduced rice yield by 3.8-22.6% over the late twenty-first century results in a considerable increase in rice virtual water. By increasing the contribution of green water in supplying crop water requirement, earlier cropping could diminish blue water consumption for rice production in the region while cultivation postponement increases irrigation water requirement by 2-195 m3 ha-1. Forty days delay in rice cultivation in future will result in 29.9-40.6% yield reduction and 43.9-60% increase in rice virtual water under different scenarios. Earlier cropping during the 2011-2040 and 2041-2070 periods would increase water productivity, unit value of water, and economic value of blue water compared to the base period. Based on the results, management of rice cultivation calendar is a

  18. Sustainable Water Infrastructure Asset Management: A Gap Analysis of Customer and Service Provider Perspectives

    Directory of Open Access Journals (Sweden)

    Sangjong Han

    2015-09-01

    Full Text Available The ultimate goal of urban water infrastructure asset management may be sustainable water supply with satisfaction for customers. In this work, we attempted to evaluate the gaps between the perspectives of customers and service providers in Korea’s water infrastructure asset management. To evaluate the customers’ perspective, a hierarchical questionnaire survey was conducted to estimate the weights of influence for six customer values and their attributes on Korean water utility management. To evaluate the service providers’ perspective, an AHP (Analytic Hierarchy Process analysis was performed to estimate the weights of influence for the customer values and their PIs (performance indicators. The gap analysis results show that customers place higher value on customer service satisfaction (emotion and information than do the service providers (managers, whereas the managers place more value on affordability than do the customers. The findings from this work imply that improving customer service is effective in satisfying the desirable water LOS (level of service for customers. Recommendations have also been provided for administrators and engineers to develop integrated decision-making systems that can reflect customer needs regarding the improvement of their water infrastructure asset management. The findings from this work may be helpful for the Korean government and water supply utilities in improving the sustainability of their water infrastructure asset management.

  19. Achieving sustainable irrigation water withdrawals: global impacts on food security and land use

    Science.gov (United States)

    Liu, Jing; Hertel, Thomas W.; Lammers, Richard B.; Prusevich, Alexander; Baldos, Uris Lantz C.; Grogan, Danielle S.; Frolking, Steve

    2017-10-01

    Unsustainable water use challenges the capacity of water resources to ensure food security and continued growth of the economy. Adaptation policies targeting future water security can easily overlook its interaction with other sustainability metrics and unanticipated local responses to the larger-scale policy interventions. Using a global partial equilibrium grid-resolving model SIMPLE-G, and coupling it with the global Water Balance Model, we simulate the consequences of reducing unsustainable irrigation for food security, land use change, and terrestrial carbon. A variety of future (2050) scenarios are considered that interact irrigation productivity with two policy interventions— inter-basin water transfers and international commodity market integration. We find that pursuing sustainable irrigation may erode other development and environmental goals due to higher food prices and cropland expansion. This results in over 800 000 more undernourished people and 0.87 GtC additional emissions. Faster total factor productivity growth in irrigated sectors will encourage more aggressive irrigation water use in the basins where irrigation vulnerability is expected to be reduced by inter-basin water transfer. By allowing for a systematic comparison of these alternative adaptations to future irrigation vulnerability, the global gridded modeling approach offers unique insights into the multiscale nature of the water scarcity challenge.

  20. Future scenarios for a sustainable water sector: a case study from Switzerland.

    Science.gov (United States)

    Lienert, Judit; Monstadt, Jochen; Truffer, Bernhard

    2006-01-15

    Uncertainties about the long-term prospects of urban water management systems have increased substantially over the past decade due to an increasing variety of regulations, technologies, and demand structures. In Switzerland, this uncertainty is mirrored by growing difficulties of utility managers and (waste)water scientists to agree on shared strategies: Water professionals demand support for pressing management problems, while researchers fundamentally question the longer-term sustainability of the established water management system. To reestablish shared orientation, we conducted a foresight study for the Swiss (waste)water sector in 2004. Based on interviews with 29 experts from Swiss water management and research to collect 56 drivers of change, a team of 17 experts developed three scenarios: (A) regional mergers of water utilities leading to enhanced professionalism in the sector, (B) consequent material flows management leading to a radically restructured urban water management system, and (C) generalized financial crisis leading to a breakdown of centralized utility services. These scenarios helped identifying shared research priorities. We conclude that scenario analysis is a powerful tool for framing long-term strategies, defining priorities, and integrating different interests in the multidisciplinary contexts of sustainability science, which are marked by high uncertainties and concern a wide range of stakeholder groups.

  1. [Sustainability of ecological water transfer and rehabilitation project based on participatory survey].

    Science.gov (United States)

    Wang, Yu; Feng, Qi; Chen, Li-Juan; Yu, Teng-Fei

    2014-01-01

    In the arid inland area of Northwest China, the ecological water transfer and rehabilitation project (EWTRP) is an important measure to restore the deteriorated ecosystem. However, the sustainability of the project is affected by many socio-economic factors. This research was based on results of the questionnaire from Ejina County's farmer households, which included the farmer households' attitude, livelihood and the efficiency of the water resource usage. The results showed that although the EWTRP had made great achievements in vegetation restoration, but the sustainability of the project was affected by the following factors: the ecologically-motivated relocated/resettled herdsmen mainly relied on the compensation from the project, causing them a hard living, and increasing the risk of maintaining the current achievement; the project didn't have a positive impact on water-saving agriculture, the efficiency of water usage was relatively low and had not yet reached the final goal; the compensation of the project only considered the loss of agriculture, but neglected the externality and publicity of eco-water. We suggest that developing education, offering job opportunity and training programs, improving the efficiency of water usage and establishing reasonable water resources compensation mechanisms are needed to be considered as main domain of environmental recovery as well as ecological water transfer and rehabilitation.

  2. Determination of estrogenic mycotoxins in environmental water samples by low-toxicity dispersive liquid-liquid microextraction and liquid chromatography-tandem mass spectrometry.

    Science.gov (United States)

    Emídio, Elissandro Soares; da Silva, Claudia Pereira; de Marchi, Mary Rosa Rodrigues

    2015-04-24

    A novel, simple, rapid and eco-friendly method based on dispersive liquid-liquid microextraction using a bromosolvent was developed to determine six estrogenic mycotoxins (zearalenone, zearalanone, α-zearalanol, β-zearalanol, α-zearalenol and β-zearalenol) in water samples by liquid chromatography-electrospray ionization tandem mass spectrometry in the negative mode (LC-ESI-MS/MS). The optimal conditions for this method include the use of 100 μL bromocyclohexane as an extraction solvent (using a non-dispersion solvent), 10 mL of aqueous sample (adjusted to pH 4), a vortex extraction time of 2 min, centrifugation for 10 min at 3500 rpm and no ionic strength adjustment. The calibration function was linear and was verified by applying the Mandel fitting test with a 95% confidence level. No matrix effect was observed. According to the relative standard deviations (RSDs), the precision was better than 13% for the repeatability and intermediate precision. The average recoveries of the spiked compounds ranged from 81 to 118%. The method limits of detection (LOD) and quantification (LOQ) considering a 125-fold pre-concentration step were 4-20 and 8-40 ng L(-1), respectively. Next, the method was applied to the analysis of the environmental aqueous samples, demonstrating the presence of β-zearalanol and zearalanone in the river water samples. Copyright © 2015 Elsevier B.V. All rights reserved.

  3. Determination of thiobencarb in water samples by gas chromatography using a homogeneous liquid-liquid microextraction via flotation assistance procedure

    Directory of Open Access Journals (Sweden)

    H.A. Mashayekhi

    2013-09-01

    Full Text Available Homogeneous liquid-liquid microextraction via flotation assistance (HLLME-FA coupled with gas chromatography-flame ionization detection (GC-FID was applied for the extraction and determination of thiobencarb in water samples. In this study, a special extraction cell was designed to facilitate collection of the low-density solvent extraction. No centrifugation was required in this procedure. The water sample solution was added into the extraction cell which contained an appropriate mixture of toluene (as an extraction solvent and acetone (as a homogeneous solvent. By using air flotation, the organic solvent was collected at the conical part of the designed cell. The effect of the different parameters on the efficiency of extraction such as type and volume of extraction and homogeneous solvents, ionic strength and extraction time were studied and optimized. Under the optimal conditions, linearity of the method was in the range of 1.0-200 µg L-1. The relative standard deviations in the real samples varied from 7.8-11.7 % (n = 3. The proposed method was successfully applied to analysis of thiobencarb in the water samples and satisfactory results were obtained.DOI: http://dx.doi.org/10.4314/bcse.v27i3.4

  4. Modeling Sustainability of Water, Environment, Livelihood, and Culture in Traditional Irrigation Communities and Their Linked Watersheds

    Directory of Open Access Journals (Sweden)

    Kenneth Boykin

    2012-11-01

    Full Text Available Water scarcity, land use conversion and cultural and ecosystem changes threaten the way of life for traditional irrigation communities of the semi-arid southwestern United States. Traditions are strong, yet potential upheaval is great in these communities that rely on acequia irrigation systems. Acequias are ancient ditch systems brought from the Iberian Peninsula to the New World over 400 years ago; they are simultaneously gravity flow water delivery systems and shared water governance institutions. Acequias have survived periods of drought and external shocks from changing economics, demographics, and resource uses. Now, climate change and urbanization threaten water availability, ecosystem functions, and the acequia communities themselves. Do past adaptive practices hold the key to future sustainability, or are new strategies required? To explore this issue we translated disciplinary understanding into a uniform format of causal loop diagrams to conceptualize the subsystems of the entire acequia-based human-natural system. Four subsystems are identified in this study: hydrology, ecosystem, land use/economics, and sociocultural. Important linkages between subsystems were revealed as well as variables indicating community cohesion (e.g., total irrigated land, intensity of upland grazing, mutualism. Ongoing work will test the conceptualizations with field data and modeling exercises to capture tipping points for non-sustainability and thresholds for sustainable water use and community longevity.

  5. Law, Water and Sustainable Development: Framework of Nigerian Law - Country Legislation

    Directory of Open Access Journals (Sweden)

    Olawale Ajai

    2012-06-01

    Full Text Available The central issues of economic development and environmental protection in the current social, political and economic environment relate to water – an overlooked or less glamorous natural resource. For example, topical and sometimes controversial issues such as crude oil and minerals extraction, pollution control, biodiversity protection, energy and power, resource control, revenue allocation and political participation, etc., relate directly or indirectly to water resources management. This paper seeks to identify and present in a schematic and conceptual manner and to highlight the usefulness of folklore for sustainable development and evaluate the usefulness of recruiting traditional institutions into the institutional framework for modern sustainable water resources management in Nigeria It also discusses the emergent law on water resources as well as the issues concerning the domestic and international riparian law, in particular the River Niger and Lake Chad basins and explores how folklore, comparative law and international law may be adopted and adapted to aid the development and application of water law, and by direct implication sustainable development in Nigeria.

  6. Comparison of the structure of harmonic aqueous glasses and liquid water

    Science.gov (United States)

    Pohorille, Andrew; Wilson, Michael A.; Pratt, Lawrence R.; Laviolette, Randall A.; Macelroy, Robert D.

    1987-01-01

    Glassy structures of water were generated by rapidly quenching configurations of 64 and 343 molecules of liquid water; and the potential energy was then expanded through quadratic order around local minima generated in this way, and the properties of the resulting harmonic system were calculated. The results obtained were used to test the degree to which the structure of liquid water is similar to that of a harmonic aqueous glass. The radial distribution functions for the glass were found to be remarkably similar to those of the liquid. Translational modes were found to be almost entirely responsible for the broadening of the oxygen-oxygen radial distribution function of the quenched configuration, and also primarily responsible for the broadening of other radial distribution functions.

  7. Structure and Dynamics of Low-Density and High-Density Liquid Water at High Pressure.

    Science.gov (United States)

    Fanetti, Samuele; Lapini, Andrea; Pagliai, Marco; Citroni, Margherita; Di Donato, Mariangela; Scandolo, Sandro; Righini, Roberto; Bini, Roberto

    2014-01-02

    Liquid water has a primary role in ruling life on Earth in a wide temperature and pressure range as well as a plethora of chemical, physical, geological, and environmental processes. Nevertheless, a full understanding of its dynamical and structural properties is still lacking. Water molecules are associated through hydrogen bonds, with the resulting extended network characterized by a local tetrahedral arrangement. Two different local structures of the liquid, called low-density (LDW) and high-density (HDW) water, have been identified to potentially affect many different chemical, biological, and physical processes. By combining diamond anvil cell technology, ultrafast pump-probe infrared spectroscopy, and classical molecular dynamics simulations, we show that the liquid structure and orientational dynamics are intimately connected, identifying the P-T range of the LDW and HDW regimes. The latter are defined in terms of the speeding up of the orientational dynamics, caused by the increasing probability of breaking and reforming the hydrogen bonds.

  8. X-ray absorption of liquid water by advanced ab initio methods

    Science.gov (United States)

    Sun, Zhaoru; Chen, Mohan; Zheng, Lixin; Wang, Jianping; Santra, Biswajit; Shen, Huaze; Xu, Limei; Kang, Wei; Klein, Michael L.; Wu, Xifan

    2017-09-01

    Oxygen K -edge x-ray absorption spectra of liquid water are computed based on configurations from advanced ab initio molecular dynamics simulations, as well as an electron excitation theory from the GW method. One the one hand, the molecular structures of liquid water are accurately predicted by including both van der Waals interactions and a hybrid functional (PBE0). On the other hand, the dynamic screening effects on electron excitation are approximately described by the recently developed enhanced static Coulomb-hole and screened-exchange approximation of W. Kang and M. S. Hybertsen [Phys. Rev. B 82, 195108 (2010), 10.1103/PhysRevB.82.195108]. The resulting spectra of liquid water are in better quantitative agreement with the experimental spectra due to the softened hydrogen bonds and the slightly broadened spectra originating from the better screening model.

  9. Bacteriological Monitoring and Sustainable Management of Beach Water Quality in Malaysia: Problems and Prospects

    Science.gov (United States)

    Dada, Ayokunle Christopher; Asmat, Ahmad; Gires, Usup; Heng, Lee Yook; Deborah, Bandele Oluwaseun

    2012-01-01

    Despite the growing demand of tourism in Malaysia, there are no resolute efforts to develop beaches as tourist destinations. With no incentives to monitor public beaches or to use them in a sustainable manner, they might eventually degenerate in quality as a result of influx of pollutants. This calls for concerted action plans with a view to promoting their sustainable use. The success of such plans is inevitably anchored on the availability of robust quality monitoring schemes. Although significant efforts have been channelled to collation and public disclosure of bacteriological quality data of rivers, beach water monitoring appears left out. This partly explains the dearth of published information related to beach water quality data. As part of an on-going nation-wide surveillance study on the bacteriological quality of recreational beaches, this paper draws on a situation analysis with a view to proffering recommendations that could be adapted for ensuring better beach water quality in Malaysia. PMID:22980239

  10. Bacteriological monitoring and sustainable management of beach water quality in Malaysia: problems and prospects.

    Science.gov (United States)

    Dada, Ayokunle Christopher; Asmat, Ahmad; Gires, Usup; Heng, Lee Yook; Deborah, Bandele Oluwaseun

    2012-04-28

    Despite the growing demand of tourism in Malaysia, there are no resolute efforts to develop beaches as tourist destinations. With no incentives to monitor public beaches or to use them in a sustainable manner, they might eventually degenerate in quality as a result of influx of pollutants. This calls for concerted action plans with a view to promoting their sustainable use. The success of such plans is inevitably anchored on the availability of robust quality monitoring schemes. Although significant efforts have been channelled to collation and public disclosure of bacteriological quality data of rivers, beach water monitoring appears left out. This partly explains the dearth of published information related to beach water quality data. As part of an on-going nation-wide surveillance study on the bacteriological quality of recreational beaches, this paper draws on a situation analysis with a view to proffering recommendations that could be adapted for ensuring better beach water quality in Malaysia.

  11. Sustainable production of a new generation biofuel by lipase-catalyzed esterification of fatty acids from liquid industrial waste biomass.

    Science.gov (United States)

    Foukis, Athanasios; Gkini, Olga A; Stergiou, Panagiota-Yiolanda; Sakkas, Vasilios A; Dima, Agapi; Boura, Konstantina; Koutinas, Athanasios; Papamichael, Emmanuel M

    2017-08-01

    In this work we suggest a methodology comprising the design and use of cost-effective, sustainable, and environmentally friendly process for biofuel production compatible with the market demands. A new generation biofuel is produced using fatty acids, which were generated from acidogenesis of industrial wastes of bioethanol distilleries, and esterified with selected alcohols by immobilized Candida antarctica Lipase-B. Suitable reactors with significant parameters and conditions were studied through experimental design, and novel esterification processes were suggested; among others, the continuous removal of the produced water was provided. Finally, economically sustainable biofuel production was achieved providing high ester yield (<97%) along with augmented concentration (3.35M) in the reaction mixtures at relatively short esterification times, whereas the immobilized lipase maintained over 90% of its initial esterifying ability after reused for ten cycles. Copyright © 2017 Elsevier Ltd. All rights reserved.

  12. Governance, Sustainability and Decision Making in Water and Sanitation Management Systems

    Directory of Open Access Journals (Sweden)

    Martín Alejandro Iribarnegaray

    2012-11-01

    Full Text Available We explore the connections between the concepts of governance and sustainability and discuss their possible roles in water and sanitation management systems (WSMS. We see governance as a decision-making process that drives the relationship between social institutions and the public affairs of a given society. We understand sustainability as a combination of spatial, temporal, and personal aspects, and we argue that this definition is more comprehensive than the traditional triple bottom line of economy, environment, and society. We combined these two concepts into a new conceptual framework of “governance for sustainability” that is theoretically sound and arguably appropriate to understand local WSMS. To illustrate this framework, we developed and estimated a Sustainable Water Governance Index (SWGI for the city of Salta, Argentina. This aggregated index was calculated with data from literature, information from the city’s water company and other local institutions, field visits, and interviews. The SWGI for Salta obtained an overall score of 49 on a 0–100 scale, which fell into the “danger” range. We discuss the advantages and limitations of the method and conclude that aggregated indices such as the SWGI, complemented with contextual information, can be a helpful decision-making tool to promote more sustainable WSMS.

  13. An analysis of molecular packing and chemical association in liquid water using quasichemical theory.

    Science.gov (United States)

    Paliwal, A; Asthagiri, D; Pratt, L R; Ashbaugh, H S; Paulaitis, M E

    2006-06-14

    We calculate the hydration free energy of liquid TIP3P water at 298 K and 1 bar using a quasi-chemical theory framework in which interactions between a distinguished water molecule and the surrounding water molecules are partitioned into chemical associations with proximal (inner-shell) waters and classical electrostatic-dispersion interactions with the remaining (outer-shell) waters. The calculated free energy is found to be independent of this partitioning, as expected, and in excellent agreement with values derived from the literature. An analysis of the spatial distribution of inner-shell water molecules as a function of the inner-shell volume reveals that water molecules are preferentially excluded from the interior of large volumes as the occupancy number decreases. The driving force for water exclusion is formulated in terms of a free energy for rearranging inner-shell water molecules under the influence of the field exerted by outer-shell waters in order to accommodate one water molecule at the center. The results indicate a balance between chemical association and molecular packing in liquid water that becomes increasingly important as the inner-shell volume grows in size.

  14. Sustainability, Efficiency and Equitability of Water Consumption and Pollution in Latin America and the Caribbean

    Directory of Open Access Journals (Sweden)

    Mesfin M. Mekonnen

    2015-02-01

    Full Text Available This paper assesses the sustainability, efficiency and equity of water use in Latin America and the Caribbean (LAC by means of a geographic Water Footprint Assessment (WFA. It aims to provide understanding of water use from both a production and consumption point of view. The study identifies priority basins and areas from the perspectives of blue water scarcity, water pollution and deforestation. Wheat, fodder crops and sugarcane are identified as priority products related to blue water scarcity. The domestic sector is the priority sector regarding water pollution from nitrogen. Soybean and pasture are priority products related to deforestation. We estimate that consumptive water use in crop production could be reduced by 37% and nitrogen-related water pollution by 44% if water footprints were reduced to certain specified benchmark levels. The average WF per consumer in the region is 28% larger than the global average and varies greatly, from 912 m3/year per capita in Nicaragua to 3468 m3/year in Bolivia. Ironically, the LAC region shows significant levels of undernourishment, although there is abundant water and food production in the region and substantial use of land and water for producing export crops like soybean.

  15. To built a solar hot water heater to work the sustainability problem

    Directory of Open Access Journals (Sweden)

    Carretero Gómez, María Begoña

    2012-01-01

    Full Text Available We are commemorating the Education Decade for Sustainable Development. If we want to create positive towards our environment and its sustainable development we have to begin working at school. It is necessary to show our students what problems of the environment are and which solutions can be adopted. That is the reason we have planned this activity in our secondary school. We do think that by doing daily activities we have a good opportunity to fulfil this goal. An example of such experiences is the fabrication of a solar hot water heater to make them and their families more environment conscience.

  16. Groundwater-level trends and implications for sustainable water use in the Kabul Basin, Afghanistan

    Science.gov (United States)

    Mack, Thomas J.; Chornack, Michael P.; Taher, Mohammad R.

    2013-01-01

    The Kabul Basin, which includes the city of Kabul, Afghanistan, with a population of approximately 4 million, has several Afghan, United States, and international military installations that depend on groundwater resources for a potable water supply. This study examined groundwater levels in the Kabul Basin from 2004 to 2012. Groundwater levels have increased slightly in rural areas of the Kabul Basin as a result of normal precipitation after the drought of the early 2000s. However, groundwater levels have decreased in the city of Kabul due to increasing water use in an area with limited recharge. The rate of groundwater-level decrease in the city is greater for the 2008–2012 period (1.5 meters per year (m/yr) on average) than for the 2004–2008 period (0–0.7 m/yr on average). The analysis, which is corroborated by groundwater-flow modeling and a non-governmental organization decision-support model, identified groundwater-level decreases and associated implications for groundwater sustainability in the city of Kabul. Military installations in the city of Kabul (the Central Kabul subbasin) are likely to face water management challenges resulting from long-term groundwater sustainability concerns, such as the potential drying of shallow water-supply wells. Installations in the northern part of the Kabul Basin may have fewer issues with long-term water sustainability. Groundwater-level monitoring and groundwater-flow simulation can be valuable tools for assessing groundwater management options to improve the sustainability of water resources in the Kabul Basin.

  17. Water Pollution Prediction in the Three Gorges Reservoir Area and Countermeasures for Sustainable Development of the Water Environment.

    Science.gov (United States)

    Li, Yinghui; Huang, Shuaijin; Qu, Xuexin

    2017-10-27

    The Three Gorges Project was implemented in 1994 to promote sustainable water resource use and development of the water environment in the Three Gorges Reservoir Area (hereafter "Reservoir Area"). However, massive discharge of wastewater along the river threatens these goals; therefore, this study employs a grey prediction model (GM) to predict the annual emissions of primary pollution sources, including industrial wastewater, domestic wastewater, and oily and domestic wastewater from ships, that influence the Three Gorges Reservoir Area water environment. First, we optimize the initial values of a traditional GM (1,1) model, and build a new GM (1,1) model that minimizes the sum of squares of the relative simulation errors. Second, we use the new GM (1,1) model to simulate historical annual emissions data for the four pollution sources and thereby test the effectiveness of the model. Third, we predict the annual emissions of the four pollution sources in the Three Gorges Reservoir Area for a future period. The prediction results reveal the annual emission trends for the major wastewater types, and indicate the primary sources of water pollution in the Three Gorges Reservoir Area. Based on our predictions, we suggest several countermeasures against water pollution and towards the sustainable development of the water environment in the Three Gorges Reservoir Area.

  18. The effect of cloud liquid water on temperature retrievals from microwave measurements

    Science.gov (United States)

    Bernet, Leonie; Navas-Guzmán, Francisco; Kämpfer, Niklaus

    2017-04-01

    Ground-based microwave radiometry provides atmospheric profiles for both clear sky and cloudy weather conditions. The effect of clouds on measurements from microwave radiometers is low compared to other remote sensing techniques but cannot be neglected at certain frequencies. In this study, clouds have been characterized and included in microwave retrievals in order to investigate their effect on tropospheric temperature profiles measured by the TEMPERA microwave radiometer. TEMPERA retrieves atmospheric temperature profiles by measuring emitted radiation of molecular oxygen at around 60 GHz. Because cloud liquid water also absorbs and emits radiation at the used frequency range, it is important to analyse the influence of liquid water on the microwave retrieval. In order to characterize the clouds, data from various instruments have been used, all located at the aerological station of MeteoSwiss at Payerne (Switzerland). Cloud base altitudes were detected using ceilometer measurements while the integrated liquid water (ILW) was measured by a HATPRO radiometer. Additional cloud information was obtained from a co-located sky camera and using an automatic partial cloud amount detection algorithm (APCADA). All this information has been used to characterize the clouds by means of a Liquid Water Content (LWC) profile. Different LWC profiles (shapes and values) have been tested to find the best cloud characterization depending on cloud type, altitude and ILW. Temperature profiles have been obtained incorporating this liquid water profile in the inversion algorithm and they have been evaluated against retrievals without considering clouds, in order to assess the liquid water effect on microwave measurements. The results have been compared with the temperature profiles from radiosondes which are regularly launched twice a day at the aerological station. Two years of data have been analyzed and almost 300 non-precipitating cloud cases were studied. The statistical analysis

  19. Water management in Republika Srpska in the function of developing sustainability

    Directory of Open Access Journals (Sweden)

    Đukić Veljko N.

    2016-01-01

    Full Text Available Sustainability, as strategic development approach in the world in the past decade- has become an inevitable response to the growing pressure to the available natural resources. If we separate four key problems of humanity -water, food, energy and the environment- we face that the solution in the other three crisis complex decisively depends on the water: the food and energy production depends on water, the environment protection is the most sensitive in the water eco-systems. Therefore, the fact that, 'the water has become the resource of The 21st Century', Dublin Conference on Development and Agenda 21 (Chapter 1.3.2 provided the definition: 'The sustainability has become basic principle to all development strategies, especially in the development of the water resources domain.' The key problem, which makes water potentials of RS relative is extremely big space and time distribution of the rainfall and outflow. The most concise: the water distribution is such that it lacks water where it is most needed (in the northern part of RS where the most valuable land resources are and the industrial potentials, and the flows are the poorest in the time of the year (vegetation, warm season when the needs for water are the highest and when the most serious problems on water quality protection are. Having in mind the fact that, Republic of Srpska and Bosnia and Herzegovina have insufficient monitoring data available, as well as the level of the development of the method for evaluation of the ecological status, in the overall territory of Republic of Srpska, actually in two parts of the watershed; it is not possible to achieve the full level of comparison and high level of reliability of the results for evaluation of ecological status of the ground waters. Until we overcome the shortage of the existing system, it is necessary to establish method to define the level of reliability during the evaluation of ecological and chemical status.

  20. Density and Compressibility of Liquid Water and Ice from First-Principles Simulations with Hybrid Functionals.

    Science.gov (United States)

    Gaiduk, Alex P; Gygi, François; Galli, Giulia

    2015-08-06

    We determined the equilibrium density and compressibility of water and ice from first-principles molecular dynamics simulations using gradient-corrected (PBE) and hybrid (PBE0) functionals. Both functionals predicted the density of ice to be larger than that of water, by 15 (PBE) and 35% (PBE0). The PBE0 functional yielded a lower density of both ice and water with respect to PBE, leading to better agreement with experiment for ice but not for liquid water. Approximate inclusion of dispersion interactions on computed molecular-dynamics trajectories led to a substantial improvement of the PBE0 results for the density of liquid water, which, however, resulted to be slightly lower than that of ice.

  1. Seeing real-space dynamics of liquid water through inelastic x-ray scattering.

    Science.gov (United States)

    Iwashita, Takuya; Wu, Bin; Chen, Wei-Ren; Tsutsui, Satoshi; Baron, Alfred Q R; Egami, Takeshi

    2017-12-01

    Water is ubiquitous on earth, but we know little about the real-space motion of molecules in liquid water. We demonstrate that high-resolution inelastic x-ray scattering measurement over a wide range of momentum and energy transfer makes it possible to probe real-space, real-time dynamics of water molecules through the so-called Van Hove function. Water molecules are found to be strongly correlated in space and time with coupling between the first and second nearest-neighbor molecules. The local dynamic correlation of molecules observed here is crucial to a fundamental understanding of the origin of the physical properties of water, including viscosity. The results also suggest that the quantum-mechanical nature of hydrogen bonds could influence its dynamics. The approach used here offers a powerful experimental method for investigating real-space dynamics of liquids.

  2. Integration of hydrogeology and soil science for sustainable water resources-focus on water quantity

    Science.gov (United States)

    Increased biofuel production has heightened awareness of the strong linkages between crop water use and depletion of water resources. Irrigated agriculture consumed 90% of global fresh water resources during the past century. Addressing crop water use and depletion of groundwater resources requires ...

  3. Intermediate pyrolysis of biomass energy pellets for producing sustainable liquid, gaseous and solid fuels.

    Science.gov (United States)

    Yang, Y; Brammer, J G; Mahmood, A S N; Hornung, A

    2014-10-01

    This work describes the use of intermediate pyrolysis system to produce liquid, gaseous and solid fuels from pelletised wood and barley straw feedstock. Experiments were conducted in a pilot-scale system and all products were collected and analysed. The liquid products were separated into an aqueous phase and an organic phase (pyrolysis oil) under gravity. The oil yields were 34.1 wt.% and 12.0 wt.% for wood and barley straw, respectively. Analysis found that both oils were rich in heterocyclic and phenolic compounds and have heating values over 24 MJ/kg. The yields of char for both feedstocks were found to be about 30 wt.%, with heating values similar to that of typical sub-bituminous class coal. Gas yields were calculated to be approximately 20 wt.%. Studies showed that both gases had heating values similar to that of downdraft gasification producer gas. Analysis on product energy yields indicated the process efficiency was about 75%. Copyright © 2014 Elsevier Ltd. All rights reserved.

  4. Note: Assessment of the SCAN+rVV10 functional for the structure of liquid water.

    Science.gov (United States)

    Wiktor, Julia; Ambrosio, Francesco; Pasquarello, Alfredo

    2017-12-07

    The performance of the SCAN+rVV10 functional in modeling the structural properties of liquid water is studied through constant-volume ab initio molecular dynamics simulations with both classical and quantum nuclei. The radial distribution functions are found to be slightly overstructured with respect to experiment, but overall similar to those achieved with the bare SCAN and the rVV10 functionals. From the pressures calculated during the dynamics, it is inferred that the SCAN+rVV10 functional leads to a noticeable overestimation of the density of liquid water.

  5. Vapor-Liquid Equilibrium Measurements and Modeling of the Propyl Mercaptan plus Methane plus Water System

    DEFF Research Database (Denmark)

    Awan, Javeed; Thomsen, Kaj; Coquelet, Christophe

    2010-01-01

    In this work, vapor−liquid equilibrium (VLE) measurements of propyl mercaptan (PM) in pure water were performed at three different temperatures, (303, 323, and 365) K, with a pressure variation from (1 to 8) MPa. The total system pressure was maintained by CH4. The inlet mole fraction of propyl...... mercaptan in all experiments was the same, around 4.5·10−4 in the liquid phase. The objective was to provide experimental VLE data points of the propyl mercaptan + methane + water system for modeling since there is a lack of available data. These data will allow the industrial modeling of sulfur emission...

  6. Sustainable Liquid Biofuels from Biomass Biorefining (SUNLIBB). Policy Brief No. 2

    Energy Technology Data Exchange (ETDEWEB)

    NONE

    2013-09-15

    The SUNLIBB project is funded under the European Seventh Framework Programme (FP7) within the Energy theme: Second Generation Biofuels -- EU Brazil Coordinated Call. SUNLIBB started on 1 October 2010 for 4 years and collaborates with a parallel project in Brazil, CeProBIO. This is the second in a series of policy briefs providing an update on the project. The first brief was issued in March 2012. The project focus is on looking at developing second generation biofuels that hope to improve on issues seen with the first generation options. Second generation biofuels are manufactured from inedible sources, such as woody crops, energy grasses, or even agricultural and forestry residues. Residues from sugarcane and biomass from maize, as well as 'whole-crop' miscanthus are all potential raw material (called 'feedstock') for second generation bioethanol production. Because these three plants are all closely related, processing the biomass from these crops raises common technical challenges, which offers the opportunity for breakthroughs in one species to be rapidly exploited in the others. Despite the potential sustainability benefits of second generation bioethanol, the current inefficiency of production makes it economically uncompetitive. Taking up this challenge, the SUNLIBB consortium's multidisciplinary team of scientists -- in cooperation with CeProBIO, the sister project in Brazil -- combines European and Brazilian research strengths so as to open the way for environmentally, socially and economically sustainable second generation bioethanol production.

  7. Development of a Sustainable Process for the Solid-Liquid Extraction of Antioxidants from Oat

    Directory of Open Access Journals (Sweden)

    Raul Orozco-Mena

    2014-03-01

    Full Text Available This research paper studies the development of a sustainable process for the extraction of antioxidants from oat. Experimentation covered two factorials to evaluate significance among temperature, time, particle size and solvent. Total polyphenolic content (TPC and oxygen radical absorbance capacity (ORAC were the response variables. ANOVA was applied to find significance among variables and predict optimum conditions though a regression model. Extractions at different solid/solvent ratios were developed to study solvents’ solubility. Process simulation in Aspen Process Developer was carried out to evaluate energy cost, raw material cost, campaign time, and process mass intensity. Solvent and particle size showed significance as main effects, whereas temperature and time presented significance as interactions. From an industrial and sustainable perspective, ethanol (EtOH in a 1/20 (w/v ratio was the best choice since it presented the lowest cost for energy and raw material. It also showed the lowest process mass intensity (PMI, short campaign time, highest g extract/g oat, and a considerable antioxidant capacity.

  8. Water and health. [Chapter 6 of 'Sustainable water: chemical science priorities summary report'

    OpenAIRE

    Green, Colin H.; Donner, Erica; Faulkner, Hazel P.; Garelick, Hemda; Jones, Huw; Revitt, D. Mike; Scholes, Lian N. L.

    2007-01-01

    Water transports contaminants, including inorganic, organic and biological materials, from various sources both natural and man-made. Such contaminants can enter the human body via water by ingestion, inhalation of water droplets and contact, particularly with broken skin.\\ud Water borne diseases have historically had the greatest impact upon human health and continue to contribute to millions of deaths globally per year. Water use and sanitation in the form of hygiene practices act as an imp...

  9. The Knowledge Base for Achieving the Sustainable Development Goal Targets on Water Supply, Sanitation and Hygiene

    Science.gov (United States)

    Hutton, Guy; Chase, Claire

    2016-01-01

    Safe drinking water, sanitation, and hygiene (WASH) are fundamental to an improved standard of living. Globally, 91% of households used improved drinking water sources in 2015, while for improved sanitation it is 68%. Wealth disparities are stark, with rural populations, slum dwellers and marginalized groups lagging significantly behind. Service coverage is significantly lower when considering the new water and sanitation targets under the sustainable development goals (SDGs) which aspire to a higher standard of ‘safely managed’ water and sanitation. Lack of access to WASH can have an economic impact as much as 7% of Gross Domestic Product, not including the social and environmental consequences. Research points to significant health and socio-economic consequences of poor nutritional status, child growth and school performance caused by inadequate WASH. Groundwater over-extraction and pollution of surface water bodies have serious impacts on water resource availability and biodiversity, while climate change exacerbates the health risks of water insecurity. A significant literature documents the beneficial impacts of WASH interventions, and a growing number of impact evaluation studies assess how interventions are optimally financed, implemented and sustained. Many innovations in behavior change and service delivery offer potential for scaling up services to meet the SDGs. PMID:27240389

  10. Indicator-based approach to assess sustainability of current and projected water use in Korea

    Science.gov (United States)

    Kong, I.; Kim, I., Sr.

    2016-12-01

    Recently occurred failures in water supply system derived from lacking rainfall in Korea has raised severe concerns about limited water resources exacerbated by anthropogenic drivers as well as climatic changes. Since Korea is under unprecedented changes in both social and environmental aspects, it is required to integrate social and environmental changes as well as climate factors in order to consider underlying problems and their upcoming impacts on sustainable water use. In this study, we proposed a framework to assess multilateral aspects in sustainable water use in support of performance-based monitoring. The framework is consisted of four thematic indices (climate, infrastructure, pollution, and management capacity) and subordinate indicators. Second, in order to project future circumstances, climate variability, demographic, and land cover scenarios to 2050 were applied after conducting statistical analysis identifying correlations between indicators within the framework since water crisis are caused by numerous interrelated factors. Assessment was conducted throughout 161 administrative boundaries in Korea at the time of 2010, 2030, and 2050. Third, current and future status in water use were illustrated using GIS-based methodology and statistical clustering (K-means and HCA) to elucidate spatially explicit maps and to categorize administrative regions showing similar phenomenon in the future. Based on conspicuous results shown in spatial analysis and clustering method, we suggested policy implementations to navigate local communities to decide which countermeasures should be supplemented or adopted to increase resiliency to upcoming changes in water use environments.

  11. The Knowledge Base for Achieving the Sustainable Development Goal Targets on Water Supply, Sanitation and Hygiene

    Directory of Open Access Journals (Sweden)

    Guy Hutton

    2016-05-01

    Full Text Available Safe drinking water, sanitation, and hygiene (WASH are fundamental to an improved standard of living. Globally, 91% of households used improved drinking water sources in 2015, while for improved sanitation it is 68%. Wealth disparities are stark, with rural populations, slum dwellers and marginalized groups lagging significantly behind. Service coverage is significantly lower when considering the new water and sanitation targets under the sustainable development goals (SDGs which aspire to a higher standard of ‘safely managed’ water and sanitation. Lack of access to WASH can have an economic impact as much as 7% of Gross Domestic Product, not including the social and environmental consequences. Research points to significant health and socio-economic consequences of poor nutritional status, child growth and school performance caused by inadequate WASH. Groundwater over-extraction and pollution of surface water bodies have serious impacts on water resource availability and biodiversity, while climate change exacerbates the health risks of water insecurity. A significant literature documents the beneficial impacts of WASH interventions, and a growing number of impact evaluation studies assess how interventions are optimally financed, implemented and sustained. Many innovations in behavior change and service delivery offer potential for scaling up services to meet the SDGs.

  12. The Knowledge Base for Achieving the Sustainable Development Goal Targets on Water Supply, Sanitation and Hygiene.

    Science.gov (United States)

    Hutton, Guy; Chase, Claire

    2016-05-27

    Safe drinking water, sanitation, and hygiene (WASH) are fundamental to an improved standard of living. Globally, 91% of households used improved drinking water sources in 2015, while for improved sanitation it is 68%. Wealth disparities are stark, with rural populations, slum dwellers and marginalized groups lagging significantly behind. Service coverage is significantly lower when considering the new water and sanitation targets under the sustainable development goals (SDGs) which aspire to a higher standard of 'safely managed' water and sanitation. Lack of access to WASH can have an economic impact as much as 7% of Gross Domestic Product, not including the social and environmental consequences. Research points to significant health and socio-economic consequences of poor nutritional status, child growth and school performance caused by inadequate WASH. Groundwater over-extraction and pollution of surface water bodies have serious impacts on water resource availability and biodiversity, while climate change exacerbates the health risks of water insecurity. A significant literature documents the beneficial impacts of WASH interventions, and a growing number of impact evaluation studies assess how interventions are optimally financed, implemented and sustained. Many innovations in behavior change and service delivery offer potential for scaling up services to meet the SDGs.

  13. The future of water resources systems analysis: Toward a scientific framework for sustainable water management

    Science.gov (United States)

    Brown, Casey M.; Lund, Jay R.; Cai, Ximing; Reed, Patrick M.; Zagona, Edith A.; Ostfeld, Avi; Hall, Jim; Characklis, Gregory W.; Yu, Winston; Brekke, Levi

    2015-08-01

    This paper presents a short history of water resources systems analysis from its beginnings in the Harvard Water Program, through its continuing evolution toward a general field of water resources systems science. Current systems analysis practice is widespread and addresses the most challenging water issues of our times, including water scarcity and drought, climate change, providing water for food and energy production, decision making amid competing objectives, and bringing economic incentives to bear on water use. The emergence of public recognition and concern for the state of water resources provides an opportune moment for the field to reorient to meet the complex, interdependent, interdisciplinary, and global nature of today's water challenges. At present, water resources systems analysis is limited by low scientific and academic visibility relative to its influence in practice and bridled by localized findings that are difficult to generalize. The evident success of water resource systems analysis in practice (which is set out in this paper) needs in future to be strengthened by substantiating the field as the science of water resources that seeks to predict the water resources variables and outcomes that are important to governments, industries, and the public the world over. Doing so promotes the scientific credibility of the field, provides understanding of the state of water resources and furnishes the basis for predicting the impacts of our water choices.

  14. Optimization and validation of liquid-liquid extraction with low temperature partitioning for determination of carbamates in water

    Energy Technology Data Exchange (ETDEWEB)

    Machado Goulart, Simone; Domingos Alves, Renata; Neves, Antonio Augusto; Queiroz, Jose Humberto de; Conde de Assis, Tamires [Departamento de Quimica, Universidade Federal de Vicosa, Vila Gianetti, Casa 24, 36 570-000 Vicosa, MG (Brazil); Queiroz, Maria Eliana L.R. de, E-mail: meliana@ufv.br [Departamento de Quimica, Universidade Federal de Vicosa, Vila Gianetti, Casa 24, 36 570-000 Vicosa, MG (Brazil)

    2010-06-25

    Using a 2{sup 3} experimental design, liquid-liquid extraction with low temperature partitioning (LLE-LTP) was optimized and validated for analysis of three carbamates (aldicarb, carbofuran and carbaryl) in water samples. In this method, 2.0 mL of sample is placed in contact with 4.0 mL of acetonitrile. After agitation, the sample is placed in a freezer for 3 h for phase separation. The organic extract is analyzed by high performance liquid chromatography with ultraviolet detection (HPLC-UV). For validation of the technique, the following figures of merit were evaluated: accuracy, precision, detection and quantification limits, linearity, sensibility and selectivity. Extraction recovery percentages of the carbamates aldicarb, carbofuran and carbaryl were 90%, 95% and 96%, respectively. Even though extremely low volumes of sample and solvent were used, the extraction method was selective and the detection and quantification limits were between 5.0 and 10.0 {mu}g L{sup -1}, and 17.0 and 33.0 {mu}g L{sup -1}, respectively.

  15. Determination of organochlorine pesticides in snow water samples by low density solvent based dispersive liquid-liquid microextraction.

    Science.gov (United States)

    Zhao, Wenting; Li, Jindong; Wu, Tong; Wang, Peng; Zhou, Zhiqiang

    2014-09-01

    A simple, rapid, efficient, and environmentally friendly pretreatment based on a low-density solvent based dispersive liquid-liquid microextraction was developed for determining trace levels of 17 organochlorine pesticides in snow. The parameters affecting the extraction efficiency, such as the type and volume of the extraction and dispersive solvents, extraction time, and salt content, were optimized. The optimized conditions yielded a good performance, with enrichment factors ranging from 271 to 474 and recoveries ranging from 71.4 to 114.5% and relative standard deviations between 1.6 and 14.8%. The detection limits, calculated as three times the signal-to-noise ratio, ranged from 0.02 to 0.11 μg/L. The validated method was used to successfully analyze 17 analytes in snow water samples, overcoming the drawbacks of some existing low-density solvent liquid microextraction methods, which require special devices, large volumes of organic solvents, or complicated operation procedures. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Optimization and validation of liquid-liquid extraction with low temperature partitioning for determination of carbamates in water.

    Science.gov (United States)

    Goulart, Simone Machado; Alves, Renata Domingos; Neves, Antônio Augusto; de Queiroz, José Humberto; de Assis, Tamires Condé; de Queiroz, Maria Eliana L R

    2010-06-25

    Using a 2(3) experimental design, liquid-liquid extraction with low temperature partitioning (LLE-LTP) was optimized and validated for analysis of three carbamates (aldicarb, carbofuran and carbaryl) in water samples. In this method, 2.0 mL of sample is placed in contact with 4.0 mL of acetonitrile. After agitation, the sample is placed in a freezer for 3 h for phase separation. The organic extract is analyzed by high performance liquid chromatography with ultraviolet detection (HPLC-UV). For validation of the technique, the following figures of merit were evaluated: accuracy, precision, detection and quantification limits, linearity, sensibility and selectivity. Extraction recovery percentages of the carbamates aldicarb, carbofuran and carbaryl were 90%, 95% and 96%, respectively. Even though extremely low volumes of sample and solvent were used, the extraction method was selective and the detection and quantification limits were between 5.0 and 10.0 microg L(-1), and 17.0 and 33.0 microg L(-1), respectively. Copyright 2010 Elsevier B.V. All rights reserved.

  17. Experimental determination of cavitation thresholds in liquid water and mercury

    Energy Technology Data Exchange (ETDEWEB)

    Taleyarkhan, R.P.; West, C.D. [Oak Ridge National Lab., TN (United States); Moraga, F. [Rensselaer Polytechnic Inst., Troy, NY (United States)

    1998-11-01

    An overview is provided on cavitation threshold measurement experiments for water and mercury. Various aspects to be considered that affect onset determination are discussed along with design specifications developed for construction of appropriate apparatus types. Both static and transient-cavitation effects were studied using radically different apparatus designs. Preliminary data are presented for cavitation thresholds for water and mercury over a range of temperatures in static and high-frequency environments. Implications and issues related to spallation neutron source target designs and operation are discussed.

  18. Developing America's Shale Reserves - Water Strategies For A Sustainable Future (Invited)

    Science.gov (United States)

    Shephard, L. E.; Oshikanlu, T.

    2013-12-01

    The development of shale oil and gas reserves over the last several years has had a significant impact on securing America's energy future while making substantial contributions to our nation's economic prosperity. These developments have also raised serious concerns about potential detrimental impacts to our environment (i.e., land, air and water) with much media attention focused on the impacts to our nation's fresh water supply. These concerns are being discussed across the nation often with little or no distinction that the nature of the water issues vary depending on local circumstances (e.g., depth of aquifer and reservoir zone, water demand and availability, availability of discharge wells, regulatory framework, etc.) and regional shale reservoir development strategies (depth of wells, length of laterals, fluid-type used for fracturing, etc.). Growing concerns over long standing drought conditions in some areas and competing demands for water from other sectors (e.g., agriculture, domestic, etc.) add even greater uncertainty relative to fresh water. Water demands for gas and oil wells vary from region to region but nominally range from 10 to 15 acre feet of water (4 to 6 million gallons) for drilling and hydraulic fracturing applications. Flowback water from the hydraulic fracturing process varies and can range from 5 to 40 % of the water used for drilling and 'fracing'. Produced water can be substantial, leading to significant volumes of 'disposed water' where injection wells are available. A science-based systems approach to water lifecycle management that incorporates leading-edge technology development and considers economic and social impacts is critical for the long-term sustainable development of shale reserves. Various water recycling and reuse technologies are being deployed within select regions across the nation with each having limited success depending on region. The efficacy of reuse technology will vary based on produced water quantity and

  19. Short-range precipitation forecasts using assimilation of simulated satellite water vapor profiles and column cloud liquid water amounts

    Science.gov (United States)

    Wu, Xiaohua; Diak, George R.; Hayden, Cristopher M.; Young, John A.

    1995-01-01

    These observing system simulation experiments investigate the assimilation of satellite-observed water vapor and cloud liquid water data in the initialization of a limited-area primitive equations model with the goal of improving short-range precipitation forecasts. The assimilation procedure presented includes two aspects: specification of an initial cloud liquid water vertical distribution and diabatic initialization. The satellite data is simulated for the next generation of polar-orbiting satellite instruments, the Advanced Microwave Sounding Unit (AMSU) and the High-Resolution Infrared Sounder (HIRS), which are scheduled to be launched on the NOAA-K satellite in the mid-1990s. Based on cloud-top height and total column cloud liquid water amounts simulated for satellite data a diagnostic method is used to specify an initial cloud water vertical distribution and to modify the initial moisture distribution in cloudy areas. Using a diabatic initialization procedure, the associated latent heating profiles are directly assimilated into the numerical model. The initial heating is estimated by time averaging the latent heat release from convective and large-scale condensation during the early forecast stage after insertion of satellite-observed temperature, water vapor, and cloud water formation. The assimilation of satellite-observed moisture and cloud water, together withy three-mode diabatic initialization, significantly alleviates the model precipitation spinup problem, especially in the first 3 h of the forecast. Experimental forecasts indicate that the impact of satellite-observed temperature and water vapor profiles and cloud water alone in the initialization procedure shortens the spinup time for precipitation rates by 1-2 h and for regeneration of the areal coverage by 3 h. The diabatic initialization further reduces the precipitation spinup time (compared to adiabatic initialization) by 1 h.

  20. Biochar-based water treatment systems as a potential low-cost and sustainable technology for clean water provision.

    Science.gov (United States)

    Gwenzi, Willis; Chaukura, Nhamo; Noubactep, Chicgoua; Mukome, Fungai N D

    2017-07-15

    Approximately 600 million people lack access to safe drinking water, hence achieving Sustainable Development Goal 6 (Ensure availability and sustainable management of water and sanitation for all by 2030) calls for rapid translation of recent research into practical and frugal solutions within the remaining 13 years. Biochars, with excellent capacity to remove several contaminants from aqueous solutions, constitute an untapped technology for drinking water treatment. Biochar water treatment has several potential merits compared to existing low-cost methods (i.e., sand filtration, boiling, solar disinfection, chlorination): (1) biochar is a low-cost and renewable adsorbent made using readily available biomaterials and skills, making it appropriate for low-income communities; (2) existing methods predominantly remove pathogens, but biochars remove chemical, biological and physical contaminants; (3) biochars maintain organoleptic properties of water, while existing methods generate carcinogenic by-products (e.g., chlorination) and/or increase concentrations of chemical contaminants (e.g., boiling). Biochars have co-benefits including provision of clean energy for household heating and cooking, and soil application of spent biochar improves soil quality and crop yields. Integrating biochar into the water and sanitation system transforms linear material flows into looped material cycles, consistent with terra preta sanitation. Lack of design information on biochar water treatment, and environmental and public health risks constrain the biochar technology. Seven hypotheses for future research are highlighted under three themes: (1) design and optimization of biochar water treatment; (2) ecotoxicology and human health risks associated with contaminant transfer along the biochar-soil-food-human pathway, and (3) life cycle analyses of carbon and energy footprints of biochar water treatment systems. Copyright © 2017 Elsevier Ltd. All rights reserved.