WorldWideScience

Sample records for suspended cathodes exhibited

  1. New Redox Polymers that Exhibit Reversible Cleavage of Sulfur Bonds as Cathode Materials.

    Science.gov (United States)

    Baloch, Marya; Ben Youcef, Hicham; Li, Chunmei; Garcia-Calvo, Oihane; Rodriguez, Lide M; Shanmukaraj, Devaraj; Rojo, Teofilo; Armand, Michel

    2016-11-23

    Two new cathode materials based on redox organosulfur polymers were synthesized and investigated for rechargeable lithium batteries as a proof-of-concept study. These cathodes offered good cycling performance owing to the absence of polysulfide solubility, which plagues Li/S systems. Herein, an aliphatic polyamine or a conjugated polyazomethine was used as the base to tether the redox-active species. The activity comes from the cleavage and formation of S-S or N-S bonds, which is made possible by the rigid conjugated backbone. The synthesized polymers were characterized through FTIR spectroscopy and thermogravimetric analysis (TGA). Galvanostatic measurements were performed to evaluate the discharge/charge cycles and characterize the performance of the lithium-based cells, which displayed initial discharge capacities of approximately 300 mA h g(-1) at C/5 over 100 cycles with approximately 98 % Coulombic efficiency. © 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

  2. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    A Look of Hope Islam Mahmoud Sweity From 19 to 30 June 2017 CERN Meyrin, Main Building Islam Mahmoud Sweity Islam Mahmoud Sweity was born in 1997 at Beit Awwa, Palestine. She is currently following a course to get an Art diploma of Painting at the college of Fine Arts at An-Najah National University under the supervision of Esmat Al As'aad. Her portraits, landscapes and still life paintings are full of life and shining colours. Charged of emotional empathy they catch the attention of the viewer and are reminding us that life is beautiful and worth living in spite of all difficulties we have to go through. She participated in many exhibitions and has exposed her drawings in 2015 at CERN and in France in the framework of the exhibition "The Origin“, and in 2017 in the Former Yugoslav Republic of Macedonia, Palestina and Jordan. In this exhibition the oil paintings made in the past year will be presented. For more information : staff.association@cern.ch | T&eacu...

  3. Exhibition

    CERN Multimedia

    Staff Association

    2016-01-01

    Encounters Hanne Blitz From February 1st to 12th 2016 CERN Meyrin, Main Building What is our reaction to a first encounter with a tourist attraction? Contemporary Dutch painter Hanne Blitz captures visitors' responses to art and architecture, sweeping vistas and symbolic memorials. Encounters, a series of oil paintings curated specially for this CERN exhibition, depicts tourists visiting cultural highlights around the world. A thought-provoking journey not to be missed, and a tip of the hat to CERN's large Hadron Collider.

  4. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Sintropie Flavio Pellegrini From 13 to 24 March 2017 CERN Meyrin, Main Building Energia imprigionata - Flavio Pellegrini. The exhibition is composed by eleven wood artworks with the expression of movement as theme. The artworks are the result of harmonics math applied to sculpture. The powerful black colour is dominated by the light source, generating reflexes and modulations. The result is a continuous variation of perspective visions. The works generate, at a first approach, an emotion of mystery and incomprehension, only a deeper contemplation lets one discover entangling and mutative details, evidencing the elegance of the lines and letting the meaning emerge. For more information : staff.association@cern.ch | Tél: 022 766 37 38

  5. Gyroscopic behavior exhibited by the optical Kerr effect in bimetallic Au–Pt nanoparticles suspended in ethanol

    Energy Technology Data Exchange (ETDEWEB)

    Fernández-Valdés, D.; Torres-Torres, C., E-mail: ctorrest@ipn.mx, E-mail: crstorres@yahoo.com.mx; Martínez-González, C. L. [Instituto Politécnico Nacional, Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Mecánica y Eléctrica Unidad Zacatenco (Mexico); Trejo-Valdez, M. [Instituto Politécnico Nacional, Escuela Superior de Ingeniería Química e Industrias Extractivas (Mexico); Hernández-Gómez, L. H. [Instituto Politécnico Nacional, Sección de Estudios de Posgrado e Investigación, Escuela Superior de Ingeniería Mecánica y Eléctrica Unidad Zacatenco (Mexico); Torres-Martínez, R. [Instituto Politécnico Nacional, Centro de Investigación en Ciencia Aplicada y Tecnología Avanzada Unidad Querétaro (Mexico)

    2016-07-15

    The modification in the third-order nonlinear optical response exhibited by rotating bimetallic Au–Pt nanoparticles in an ethanol solution was analyzed. The samples were prepared by a sol–gel processing route. The anisotropy associated to the elemental composition of the nanoparticles was confirmed by high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy measurements. The size of the nanoparticles varies in the range from 9 to 13 nm, with an average size of 11 nm. Changes in the spatial orientation of the nanomaterials automatically generated a variation in their plasmonic response evaluated by UV–Vis spectroscopy. A two-wave mixing experiment was conducted to explore an induced birefringence at 532 nm wavelength with nanosecond pulses interacting with the samples. A strong optical Kerr effect was identified to be the main responsible effect for the third-order nonlinear optical phenomenon exhibited by the nanoparticles. It was estimated that the rotation of inhomogeneous nanostructures can provide a remarkable change in the participation of different surface plasmon resonances, if they correspond to multimetallic nanoparticles. Potential applications for developing low-dimensional gyroscopic systems can be contemplated.

  6. Suspended microfluidics

    OpenAIRE

    Casavant, Benjamin P.; Berthier, Erwin; Theberge, Ashleigh B.; Jean BERTHIER; Montanez-Sauri, Sara I.; Bischel, Lauren L.; Brakke, Kenneth; Hedman, Curtis J.; Bushman, Wade; Keller, Nancy P.; Beebe, David J.

    2013-01-01

    Although the field of microfluidics has made significant progress in bringing new tools to address biological questions, the accessibility and adoption of microfluidics within the life sciences are still limited. Open microfluidic systems have the potential to lower the barriers to adoption, but the absence of robust design rules has hindered their use. Here, we present an open microfluidic platform, suspended microfluidics, that uses surface tension to fill and maintain a fluid in microscale...

  7. Cathodic arcs

    Energy Technology Data Exchange (ETDEWEB)

    Anders, Andre

    2003-10-29

    Cathodic arc plasma deposition has become the technology of choice for hard, wear and corrosion resistant coatings for a variety of applications. The history, basic physics of cathodic arc operation, the infamous macroparticle problem and common filter solutions, and emerging high-tech applications are briefly reviewed. Cathodic arc plasmas standout due to their high degree of ionization, with important consequences for film nucleation, growth, and efficient utilization of substrate bias. Industrial processes often use cathodic arc plasma in reactive mode. In contrast, the science of arcs has focused on the case of vacuum arcs. Future research directions include closing the knowledge gap for reactive mode, large area coating, linear sources and filters, metal plasma immersion process, with application in high-tech and biomedical fields.

  8. Sulfonate-immobilized artificial cathode electrolyte interphases layer on Ni-rich cathode

    Science.gov (United States)

    Chae, Bum-Jin; Yim, Taeeun

    2017-08-01

    Although lithium nickel cobalt manganese layered oxides with a high nickel composition have gained great attention due to increased overall energy density for energy conversion/storage systems, poor interfacial stability is considered a critical bottleneck impeding its widespread adoption. We propose a new approach based on immobilizing the artificial cathode-electrolyte interphase layer, which effectively reduces undesired surface reactions, leading to high interfacial stability of cathode material. For installation of artificial cathode-electrolyte interphases, a sulfonate-based amphiphilic organic precursor, which effectively suppresses electrolyte decomposition, is synthesized and subjected to immobilization on cathode material via simple wet-coating, followed by heat treatment at low temperature. The sulfonate-based artificial cathode-electrolyte interphase layer is well-developed on the cathode surface, and the cell controlled by the sulfonate-immobilized cathode exhibits remarkable electrochemical performance, including a high average Coulombic efficiency (99.8%) and cycling retention (97.4%) compared with pristine cathode material. The spectroscopic analyses of the cycled cathode show that the sulfonate-based artificial cathode-electrolyte interphase layer effectively mitigates electrolyte decomposition on the cathode surface, resulting in decreased interfacial resistance between electrode and electrolyte.

  9. Elastomeric Cathode Binder

    Science.gov (United States)

    Yen, S. P. S.; Shen, D. S.; Somoano, R. B.

    1985-01-01

    Soluble copolymer binder mixed with cathode material and solvent forms flexible porous cathode used in lithium and Ni/Cd batteries. Cathodes prepared by this process have lower density due to expanding rubbery binder and greater flexibility than conventional cathodes. Fabrication procedure readily adaptable to scaled-up processes.

  10. Nanotube cathodes.

    Energy Technology Data Exchange (ETDEWEB)

    Overmyer, Donald L.; Lockner, Thomas Ramsbeck; Siegal, Michael P.; Miller, Paul Albert

    2006-11-01

    Carbon nanotubes have shown promise for applications in many diverse areas of technology. In this report we describe our efforts to develop high-current cathodes from a variety of nanotubes deposited under a variety of conditions. Our goal was to develop a one-inch-diameter cathode capable of emitting 10 amperes of electron current for one second with an applied potential of 50 kV. This combination of current and pulse duration significantly exceeds previously reported nanotube-cathode performance. This project was planned for two years duration. In the first year, we tested the electron-emission characteristics of nanotube arrays fabricated under a variety of conditions. In the second year, we planned to select the best processing conditions, to fabricate larger cathode samples, and to test them on a high-power relativistic electron beam generator. In the first year, much effort was made to control nanotube arrays in terms of nanotube diameter and average spacing apart. When the project began, we believed that nanotubes approximately 10 nm in diameter would yield sufficient electron emission properties, based on the work of others in the field. Therefore, much of our focus was placed on measured field emission from such nanotubes grown on a variety of metallized surfaces and with varying average spacing between individual nanotubes. We easily reproduced the field emission properties typically measured by others from multi-wall carbon nanotube arrays. Interestingly, we did this without having the helpful vertical alignment to enhance emission; our nanotubes were randomly oriented. The good emission was most likely possible due to the improved crystallinity, and therefore, electrical conductivity, of our nanotubes compared to those in the literature. However, toward the end of the project, we learned that while these 10-nm-diameter CNTs had superior crystalline structure to the work of others studying field emission from multi-wall CNT arrays, these nanotubes still

  11. Final Report: Wetted Cathodes for Low-Temperature Aluminum Smelting

    Energy Technology Data Exchange (ETDEWEB)

    Brown, Craig W

    2002-09-30

    A low-temperature aluminum smelting process being developed differs from the Hall-Heroult process in several significant ways. The low-temperature process employs a more acidic electrolyte than cryolite, an alumina slurry, oxygen-generating metal anodes, and vertically suspended electrodes. Wetted and drained vertical cathodes are crucial to the new process. Such cathodes represent a significant portion of the capital costs projected for the new technology. Although studies exist of wetted cathode technology with Hall-Heoult cells, the differences make such a study desirable with the new process.

  12. Immersive Exhibitions

    DEFF Research Database (Denmark)

    Achiam, Marianne

    2015-01-01

    The immersive exhibition is a specialized exhibition genre in museums, which creates the illusion of time and place by representing key characteristics of a reference world and by integrating the visitor in this three-dimensionally reconstructed world (Mortensen 2010). A successful representation...... of the reference world depends on three criteria: whether the exhibition is staged as a coherent whole with all the displayed objects supporting the representation, whether the visitor is integrated as a component of the exhibition, and whether the content and message of the exhibition become dramatized...... as a result of the visitor’s interaction with the exhibit....

  13. Human Exhibitions

    DEFF Research Database (Denmark)

    Andreassen, Rikke

    From 1870s to 1910s, more than 50 exhibitions of so-called exotic people took place in Denmark. Here large numbers of people of Asian and African origin were exhibited for the entertainment and ‘education’ of a mass audience. Several of these exhibitions took place in Copenhagen Zoo. Here differe...

  14. Exhibit Engineering

    DEFF Research Database (Denmark)

    Mortensen, Marianne Foss

    ) a synthesis of the findings from the first two studies with findings from the literature to generate two types of results: a coherent series of suggestions for a design iteration of the studied exhibit as well as a more general normative model for exhibit engineering. Finally, another perspective...

  15. Cathodic Protection Model Facility

    Data.gov (United States)

    Federal Laboratory Consortium — FUNCTION: Performs Navy design and engineering of ship and submarine impressed current cathodic protection (ICCP) systems for underwater hull corrosion control and...

  16. Cathodes for Solid Oxide Fuel Cells Operating at Low Temperatures

    DEFF Research Database (Denmark)

    Samson, Alfred Junio

    that these nanoparticulate infiltrates have good oxygen reduction capabilities. The significance of the choice of ionic conducting backbone was also addressed by replacing the CGO with Bi2V0.9Cu0.1O5.35 (BICUVOX). Cathodes with a BICUVOX backbone exhibit performance degradation not observed in LSC infiltrated - CGO cathodes...

  17. Exhibiting design

    DEFF Research Database (Denmark)

    Christensen, Line Hjorth

    2017-01-01

    This article explores how co-curatorial strategies and partnerships can work as driving forces for representing design, and how they can vitalize the exhibition as a media between enlightenment and experience. Focusing on Design Museum DK, drawing on historical as well as recent cases, it identif......This article explores how co-curatorial strategies and partnerships can work as driving forces for representing design, and how they can vitalize the exhibition as a media between enlightenment and experience. Focusing on Design Museum DK, drawing on historical as well as recent cases...

  18. Adsorptive Cathodic Stripping Voltammetric Determination of ...

    African Journals Online (AJOL)

    Purpose: To investigate the electro-reduction behaviour and determination of ciprofloxacin using a hanging mercury drop electrode. Methods: Cyclic voltammograms of ciprofloxacin recorded in Britton – Robinson buffers pH 2 – 5 exhibit a single irreversible cathodic peak. The dependence of the peak current and peak ...

  19. Museum Exhibit

    Science.gov (United States)

    1991-01-01

    A TSP from NASA Tech Briefs provided the solution to an electrical problem at a Florida museum. When a model train would not start without a jerk, a Marshall Space Flight Center development called pulse width control was adapted. The new circuit enables the train to start smoothly and reduces construction and maintenance costs. The same technology is also used in another hands-on exhibit. Applications of other TSPs are anticipated.

  20. Cable suspended windmill

    Science.gov (United States)

    Farmer, Moses G. (Inventor)

    1990-01-01

    A windmill is disclosed which includes an airframe having an upwind end and a downwind end. The first rotor is rotatably connected to the airframe, and a generator is supported by the airframe and driven by the rotor. The airframe is supported vertically in an elevated disposition by poles which extend vertically upwardly from the ground and support cables which extend between the vertical poles. Suspension cables suspend the airframe from the support cable.

  1. Human Exhibitions

    DEFF Research Database (Denmark)

    Andreassen, Rikke

    of displayed people, connecting the attitudes and science of the past with both our (continued) modern fascination with ‘the exotic’, and contemporary language and popular culture. As such, it will be of interest to scholars of sociology, anthropology and history working in the areas of gender and sexuality...... light on the staging of exhibitions, the daily life of the exhibitees, the wider connections between shows across Europe and the thinking of the time on matters of race, science, gender and sexuality. A window onto contemporary racial understandings, the book presents interviews with the descendants...

  2. Human Exhibitions

    DEFF Research Database (Denmark)

    Andreassen, Rikke

    , this book draws on unique archival material, including photographs, documentary evidence and newspaper articles, newly discovered in Copenhagen. This opens for new insights and perspectives on these European exhibitions. The book employs post-colonial and feminist approaches to the material to shed fresh...... of displayed people, connecting the attitudes and science of the past with both our (continued) modern fascination with ‘the exotic’, and contemporary language and popular culture. As such, it will be of interest to scholars of sociology, anthropology and history working in the areas of gender and sexuality...

  3. Nanostructured sulfur cathodes

    KAUST Repository

    Yang, Yuan

    2013-01-01

    Rechargeable Li/S batteries have attracted significant attention lately due to their high specific energy and low cost. They are promising candidates for applications, including portable electronics, electric vehicles and grid-level energy storage. However, poor cycle life and low power capability are major technical obstacles. Various nanostructured sulfur cathodes have been developed to address these issues, as they provide greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysulfides. In this review, recent developments on nanostructured sulfur cathodes and mechanisms behind their operation are presented and discussed. Moreover, progress on novel characterization of sulfur cathodes is also summarized, as it has deepened the understanding of sulfur cathodes and will guide further rational design of sulfur electrodes. © 2013 The Royal Society of Chemistry.

  4. Nanostructured sulfur cathodes.

    Science.gov (United States)

    Yang, Yuan; Zheng, Guangyuan; Cui, Yi

    2013-04-07

    Rechargeable Li/S batteries have attracted significant attention lately due to their high specific energy and low cost. They are promising candidates for applications, including portable electronics, electric vehicles and grid-level energy storage. However, poor cycle life and low power capability are major technical obstacles. Various nanostructured sulfur cathodes have been developed to address these issues, as they provide greater resistance to pulverization, faster reaction kinetics and better trapping of soluble polysulfides. In this review, recent developments on nanostructured sulfur cathodes and mechanisms behind their operation are presented and discussed. Moreover, progress on novel characterization of sulfur cathodes is also summarized, as it has deepened the understanding of sulfur cathodes and will guide further rational design of sulfur electrodes.

  5. Dispersive suspended microextraction.

    Science.gov (United States)

    Yang, Zhong-Hua; Liu, Yu; Lu, Yue-Le; Wu, Tong; Zhou, Zhi-Qiang; Liu, Dong-Hui

    2011-11-14

    A novel sample pre-treatment technique termed dispersive suspended microextraction (DSME) coupled with gas chromatography-flame photometric detection (GC-FPD) has been developed for the determination of eight organophosphorus pesticides (ethoprophos, malathion, chlorpyrifos, isocarbophos, methidathion, fenamiphos, profenofos, triazophos) in aqueous samples. In this method, both extraction and two phases' separation process were performed by the assistance of magnetic stirring. After separating the two phases, 1 μL of the suspended phase was injected into GC for further instrument analysis. Varieties of experiment factors which could affect the experiment results were optimized and the following were selected: 12.0 μL p-xylene was selected as extraction solvent, extraction speed was 1200 rpm, extraction time was 30 s, the restoration speed was 800 rpm, the restoration time was 8 min, and no salt was added. Under the optimum conditions, limits of detections (LODs) varied between 0.01 and 0.05 μg L(-1). The relative standard deviation (RSDs, n=6) ranged from 4.6% to 12.1%. The linearity was obtained by five points in the concentration range of 0.1-100.0 μg L(-1). Correlation coefficients (r) varied from 0.9964 to 0.9995. The enrichment factors (EFs) were between 206 and 243. In the final experiment, the developed method has been successfully applied to the determination of organophosphorus pesticides in wine and tap water samples and the obtained recoveries were between 83.8% and 101.3%. Compared with other pre-treatment methods, DSME has its own features and could achieve satisfied results for the analysis of trace components in complicated matrices. Copyright © 2011 Elsevier B.V. All rights reserved.

  6. Highly Efficient Micro Cathode Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Busek Company, Inc. proposes to develop a micro thermionic cathode that requires extremely low power and provides long lifetime. The basis for the cathode is a...

  7. Advanced Cathode Electrolyzer (ACE) Project

    Data.gov (United States)

    National Aeronautics and Space Administration — The proposed innovation is a static, cathode-fed, 2000 psi, balanced-pressure Advanced Cathode Electrolyzer (ACE) based on PEM electrolysis technology. It...

  8. Miniaturized cathodic arc plasma source

    Science.gov (United States)

    Anders, Andre; MacGill, Robert A.

    2003-04-15

    A cathodic arc plasma source has an anode formed of a plurality of spaced baffles which extend beyond the active cathode surface of the cathode. With the open baffle structure of the anode, most macroparticles pass through the gaps between the baffles and reflect off the baffles out of the plasma stream that enters a filter. Thus the anode not only has an electrical function but serves as a prefilter. The cathode has a small diameter, e.g. a rod of about 1/4 inch (6.25 mm) diameter. Thus the plasma source output is well localized, even with cathode spot movement which is limited in area, so that it effectively couples into a miniaturized filter. With a small area cathode, the material eroded from the cathode needs to be replaced to maintain plasma production. Therefore, the source includes a cathode advancement or feed mechanism coupled to cathode rod. The cathode also requires a cooling mechanism. The movable cathode rod is housed in a cooled metal shield or tube which serves as both a current conductor, thus reducing ohmic heat produced in the cathode, and as the heat sink for heat generated at or near the cathode. Cooling of the cathode housing tube is done by contact with coolant at a place remote from the active cathode surface. The source is operated in pulsed mode at relatively high currents, about 1 kA. The high arc current can also be used to operate the magnetic filter. A cathodic arc plasma deposition system using this source can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  9. Cathode material for lithium batteries

    Science.gov (United States)

    Park, Sang-Ho; Amine, Khalil

    2013-07-23

    A method of manufacture an article of a cathode (positive electrode) material for lithium batteries. The cathode material is a lithium molybdenum composite transition metal oxide material and is prepared by mixing in a solid state an intermediate molybdenum composite transition metal oxide and a lithium source. The mixture is thermally treated to obtain the lithium molybdenum composite transition metal oxide cathode material.

  10. Mixed polyanion glass cathodes: Iron phosphate vanadate glasses

    Energy Technology Data Exchange (ETDEWEB)

    Kercher, Andrew K [ORNL; Ramey, Joanne Oxendine [ORNL; Carroll, Kyler J [Massachusetts Institute of Technology (MIT); Kiggans Jr, James O [ORNL; Veith, Gabriel M [ORNL; Meisner, Roberta [Oak Ridge National Laboratory (ORNL); Boatner, Lynn A [ORNL; Dudney, Nancy J [ORNL

    2014-01-01

    Mixed polyanion (MP) glasses have been investigated for use as cathodes in lithium ion batteries. MP glass cathodes are similar in composition to theoretically promising crystalline polyanionic (CP) cathodes (e.g., lithium cobalt phosphate, lithium manganese silicate), but with proper polyanion substitution, they can be designed to overcome the key shortcomings of CP cathodes, such as poor electrical conductivity and irreversible phase changes. Iron phosphate/vanadate glasses were chosen as a first demonstration of the MP glass concept. Polyanion substitution with vanadate was shown to improve the intercalation capacity of an iron phosphate glass from almost zero to full theoretical capacity. In addition, the MP glass cathodes also exhibited an unexpected second high-capacity electrochemical reaction. X-ray absorption near-edge structure (XANES) and x-ray diffraction (XRD) of cathodes from cells having different states of charge suggested that this second electrochemical reaction is a glass-state conversion reaction. With a first demonstration established, MP glass materials utilizing an intercalation and/or glass-state conversion reaction are promising candidates for future high-energy cathode research.

  11. Cationic fluorinated polymer binders for microbial fuel cell cathodes

    KAUST Repository

    Chen, Guang

    2012-01-01

    Fluorinated quaternary ammonium-containing polymers were used as catalyst binders in microbial fuel cell (MFC) cathodes. The performance of the cathodes was examined and compared to NAFION ® and other sulfonated aromatic cathode catalyst binders using linear sweep voltammetry (LSV), impedance spectroscopy, and performance tests in single chamber air-cathode MFCs. The cathodes with quaternary ammonium functionalized fluorinated poly(arylene ether) (Q-FPAE) binders showed similar current density and charge transfer resistance (R ct) to cathodes with NAFION ® binders. Cathodes containing either of these fluorinated binders exhibited better electrochemical responses than cathodes with sulfonated or quaternary ammonium-functionalized RADEL ® poly(sulfone) (S-Radel or Q-Radel) binders. After 19 cycles (19 d), the power densities of all the MFCs declined compared to the initial cycles due to biofouling at the cathode. MFC cathodes with fluorinated polymer binders (1445 mW m -2, Q-FPAE-1.4-H; 1397 mW m -2, Q-FPAE-1.4-Cl; 1277 mW m -2, NAFION ®; and 1256 mW m -2, Q-FPAE-1.0-Cl) had better performance than those with non-fluorinated polymer binders (880 mW m -2, S-Radel; 670 mW m -2, Q-Radel). There was a 15% increase in the power density using the Q-FPAE binder with a 40% higher ion exchange capacity (Q-FPAE-1.4-H compared to Q-FPAE-1.0-Cl) after 19 cycles of operation, but there was no effect on the power production due to counter ions in the binder (Cl -vs. HCO 3 -). The highest-performance cathodes (NAFION ® and Q-FPAE binders) had the lowest charge transfer resistances (R ct) in fresh and in fouled cathodes despite the presence of thick biofilms on the surface of the electrodes. These results show that fluorinated binders may decrease the penetration of the biofilm and associated biopolymers into the cathode structure, which helps to combat MFC performance loss over time. © 2012 The Royal Society of Chemistry.

  12. Photoconductive Cathode Interlayer for Highly Efficient Inverted Polymer Solar Cells.

    Science.gov (United States)

    Nian, Li; Zhang, Wenqiang; Zhu, Na; Liu, Linlin; Xie, Zengqi; Wu, Hongbin; Würthner, Frank; Ma, Yuguang

    2015-06-10

    A highly photoconductive cathode interlayer was achieved by doping a 1 wt % light absorber, such as perylene bisimide, into a ZnO thin film, which absorbs a very small amount of light but shows highly increased conductivity of 4.50 × 10(-3) S/m under sunlight. Photovoltaic devices based on this kind of photoactive cathode interlayer exhibit significantly improved device performance, which is rather insensitive to the thickness of the cathode interlayer over a broad range. Moreover, a power conversion efficiency as high as 10.5% was obtained by incorporation of our photoconductive cathode interlayer with the PTB7-Th:PC71BM active layer, which is one of the best results for single-junction polymer solar cells.

  13. Intermetallics as cathode materials in the electrolytic hydrogen production

    Energy Technology Data Exchange (ETDEWEB)

    Stojic, D.L.; Maksic, A.D.; Kaninski, M.P.M. [Vinca Inst. of Nuclear Sciences, Belgrade (Serbia and Montenegro). Lab. of Physical Chemistry; Cekic, B.D. [Vinca Inst. of Nuclear Sciences, Belgrade (Serbia and Montenegro). Lab. of Physics; Miljanic, S.S. [Belgrade Univ. (Serbia and Montenegro). Faculty of Physical Chemistry

    2005-01-01

    The intermetallics of transition metals have been investigated as cathode materials for the production of hydrogen by electrolysis from water-KOH solutions, in an attempt to increase the electrolytic process efficiency. We found that the best effect among all investigated cathodes (Hf{sub 2}Fe, Zr-Pt, Nb-Pd(I), Pd-Ta, Nb-Pd(II), Ti-Pt) exhibits the Hf{sub 2}Fe phase. These materials were compared with conventional cathodes (Fe and Ni), often used in the alkaline electrolysis. A significant upgrade of the electrolytic efficiency using intermetallics, either in pure KOH electrolyte or in combination with ionic activators added in situ, was achieved. The effects of these cathode materials on the process efficiency were discussed in the context of transition metal features that issue from their electronic configuration. (Author)

  14. Method for separating biological cells. [suspended in aqueous polymer systems

    Science.gov (United States)

    Brooks, D. E. (Inventor)

    1980-01-01

    A method for separating biological cells by suspending a mixed cell population in a two-phase polymer system is described. The polymer system consists of droplet phases with different surface potentials for which the cell populations exhibit different affinities. The system is subjected to an electrostatic field of sufficient intensity to cause migration of the droplets with an attendant separation of cells.

  15. Nanostructured lanthanum manganate composite cathode

    DEFF Research Database (Denmark)

    Wang, Wei Guo; Liu, Yi-Lin; Barfod, Rasmus

    2005-01-01

    that the (La1-xSrx)(y)MnO3 +/-delta (LSM) composite cathodes consist of a network of homogenously distributed LSM, yttria-stabilized zirconia (YSZ), and pores. The individual grain size of LSM or YSZ is approximately 100 nm. The degree of contact between cathode and electrolyte is 39% on average. (c) 2005...

  16. Suspended animation for delayed resuscitation.

    Science.gov (United States)

    Safar, Peter J; Tisherman, Samuel A

    2002-04-01

    'Suspended animation for delayed resuscitation' is a new concept for attempting resuscitation from cardiac arrest of patients who currently (totally or temporarily) cannot be resuscitated, such as traumatic exsanguination cardiac arrest. Suspended animation means preservation of the viability of brain and organism during cardiac arrest, until restoration of stable spontaneous circulation or prolonged artificial circulation is possible. Suspended animation for exsanguination cardiac arrest of trauma victims would have to be induced within the critical first 5 min after the start of cardiac arrest no-flow, to buy time for transport and resuscitative surgery (hemostasis) performed during no-flow. Cardiac arrest is then reversed with all-out resuscitation, usually requiring cardiopulmonary bypass. Suspended animation has been explored and documented as effective in dogs in terms of long-term survival without brain damage after very prolonged cardiac arrest. In the 1990s, the Pittsburgh group achieved survival without brain damage in dogs after cardiac arrest of up to 90 min no-flow at brain (tympanic) temperature of 10 degrees C, with functionally and histologically normal brains. These studies used emergency cardiopulmonary bypass with heat exchanger or a single hypothermic saline flush into the aorta, which proved superior to pharmacologic strategies. For the large number of normovolemic sudden cardiac death victims, which currently cannot be resuscitated, more research in large animals is needed.

  17. Electron Injection into Organic Semiconductor Devices from High Work Function Cathodes

    National Research Council Canada - National Science Library

    Corey V. Hoven; Renqiang Yang; Andres Garcia; Victoria Crockett; Alan J. Heeger; Guillermo C. Bazan; Thuc-Quyen Nguyen

    2008-01-01

    We show that polymer light-emitting diodes with high work-function cathodes and conjugated polyelectrolyte injection/transport layers exhibit excellent efficiencies despite large electron-injection barriers...

  18. Magnetron priming by multiple cathodes

    Science.gov (United States)

    Jones, M. C.; Neculaes, V. B.; Lau, Y. Y.; Gilgenbach, R. M.; White, W. M.; Hoff, B. W.; Jordan, N. M.

    2005-08-01

    A relativistic magnetron priming technique using multiple cathodes is simulated with a three-dimensional, fully electromagnetic, particle-in-cell code. This technique is based on electron emission from N /2 individual cathodes in an N-cavity magnetron to prime the π mode. In the case of the six-cavity relativistic magnetron, π-mode start-oscillation times are reduced up to a factor of 4, and mode competition is suppressed. Most significantly, the highest microwave field power is observed by utilizing three cathodes compared to other recently explored priming techniques.

  19. 7 CFR 1206.21 - Suspend.

    Science.gov (United States)

    2010-01-01

    ... part thereof during a particular period of time specified in the rule. ... AND ORDERS; MISCELLANEOUS COMMODITIES), DEPARTMENT OF AGRICULTURE MANGO PROMOTION, RESEARCH, AND INFORMATION Mango Promotion, Research, and Information Order Definitions § 1206.21 Suspend. Suspend means to...

  20. The Signatures of the Invisible exhibition in Geneva

    CERN Multimedia

    Patrice Loïez

    2002-01-01

    The artist Paola Pivi with her work at the Signatures of the Invisible exhibition in Geneva during February 2002. This piece with needles suspended on nylon thread 'detects' people as they approach. The exhibition was for art inspired by research carried out at CERN.

  1. Self-Suspended Suspensions of Covalently Grafted Hairy Nanoparticles

    KAUST Repository

    Choudhury, Snehashis

    2015-03-17

    © 2015 American Chemical Society. Dispersions of small particles in liquids have been studied continuously for almost two centuries for their ability to simultaneously advance understanding of physical properties of fluids and their widespread use in applications. In both settings, the suspending (liquid) and suspended (solid) phases are normally distinct and uncoupled on long length and time scales. In this study, we report on the synthesis and physical properties of a novel family of covalently grafted nanoparticles that exist as self-suspended suspensions with high particle loadings. In such suspensions, we find that the grafted polymer chains exhibit unusual multiscale structural transitions and enhanced conformational stability on subnanometer and nanometer length scales. On mesoscopic length scales, the suspensions display exceptional homogeneity and colloidal stability. We attribute this feature to steric repulsions between grafted chains and the space-filling constraint on the tethered chains in the single-component self-suspended materials, which inhibits phase segregation. On macroscopic length scales, the suspensions exist as neat fluids that exhibit soft glassy rheology and, counterintuitively, enhanced elasticity with increasing temperature. This feature is discussed in terms of increased interpenetration of the grafted chains and jamming of the nanoparticles. (Chemical Presented).

  2. High-Performance Direct Methanol Fuel Cells with Precious-Metal-Free Cathode.

    Science.gov (United States)

    Li, Qing; Wang, Tanyuan; Havas, Dana; Zhang, Hanguang; Xu, Ping; Han, Jiantao; Cho, Jaephil; Wu, Gang

    2016-11-01

    Direct methanol fuel cells (DMFCs) hold great promise for applications ranging from portable power for electronics to transportation. However, apart from the high costs, current Pt-based cathodes in DMFCs suffer significantly from performance loss due to severe methanol crossover from anode to cathode. The migrated methanol in cathodes tends to contaminate Pt active sites through yielding a mixed potential region resulting from oxygen reduction reaction and methanol oxidation reaction. Therefore, highly methanol-tolerant cathodes must be developed before DMFC technologies become viable. The newly developed reduced graphene oxide (rGO)-based Fe-N-C cathode exhibits high methanol tolerance and exceeds the performance of current Pt cathodes, as evidenced by both rotating disk electrode and DMFC tests. While the morphology of 2D rGO is largely preserved, the resulting Fe-N-rGO catalyst provides a more unique porous structure. DMFC tests with various methanol concentrations are systematically studied using the best performing Fe-N-rGO catalyst. At feed concentrations greater than 2.0 m, the obtained DMFC performance from the Fe-N-rGO cathode is found to start exceeding that of a Pt/C cathode. This work will open a new avenue to use nonprecious metal cathode for advanced DMFC technologies with increased performance and at significantly reduced cost.

  3. Novel nano-network cathodes for solid oxide fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Zhao, Fei [Laboratory for Renewable Clean Energy, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, Anhui (China); Department of Mechanical Engineering, University of South Carolina, Columbia, SC 29208 (United States); Wang, Zhiyong; Liu, Mingfei; Zhang, Lei; Xia, Changrong [Laboratory for Renewable Clean Energy, Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, Anhui (China); Chen, Fanglin [Department of Mechanical Engineering, University of South Carolina, Columbia, SC 29208 (United States)

    2008-10-15

    A novel nano-network of Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3-{delta}} (SSC) is successfully fabricated as the cathodes for intermediate-temperature solid oxide fuel cells (SOFCs) operated at 500-600 C. The cathode is composed of SSC nanowires formed from nanobeads of less than 50 nm thus exhibiting high surface area and porosity, forming straight path for oxygen ion and electron transportation, resulting in high three-phase boundaries, and consequently showing remarkably high electrode performance. An anode-supported cell with the nano-network cathode demonstrates a peak power density of 0.44 W cm{sup -2} at 500 C and displays exceptional performance with cell operating time. The result suggests a new direction to significantly improve the SOFC performance. (author)

  4. Britain exhibition at CERN

    CERN Document Server

    Bertin; CERN PhotoLab

    1969-01-01

    The United Kingdom inaugurated the Industrial Exhibitions in 1968, and it wasn't till 1971 that other countries staged exhibitions at CERN. This photo was taken in 1969, at the second British exhibition, where 16 companies were present.

  5. Performance of Stainless Steel Mesh Cathode and PVDF-graphite Cathode in Microbial Fuel Cells

    Science.gov (United States)

    Huang, Liping; Tian, Ying; Li, Mingliang; He, Gaohong; Li, Zhikao

    2010-11-01

    Inexpensive and conductive materials termed as stainless steel mesh and polyvinylidene fluoride (PVDF)-graphite were currently used as the air cathode electrodes in MFCs for the investigation of power production. By loading PTFE (poly(tetrafluoroethylene)) on the surface of stainless steel mesh, electricity production reached 3 times as high as that of the naked stainless steel. A much high catalytic activity for oxygen reduction was exhibited by Pt based and PTFE loading stainless steel mesh cathode, with an electricity generation of 1144±44 mW/m2 (31±1 W/m3) and a Coulombic efficiency (CE) of 77±2%. When Pt was replaced by an inexpensive transition metal based catalyst (cobalt tetramethylphenylporphyrin, CoTMPP), power production and CE were 845±21 mW/m2 (23±1 W/m3) and 68±1%, respectively. Accordingly, power production from PVDF-graphite (hydrophobic) MFC and PVDF-graphite (hydrophile) MFC were 286±20 mW/m2(8±1 W/m3) and 158±13 mW/m2(4±0.4 W/m3), respectively using CoTMPP as catalyst. These results give us new insight into materials like stainless steel mesh and PVDF-graphite as low cost cathode for reducing the costs of MFCs for wastewater treatment applications.

  6. Rippling instabilities in suspended nanoribbons

    Science.gov (United States)

    Wang, Hailong; Upmanyu, Moneesh

    2012-11-01

    Morphology mediates the interplay between the structure and electronic transport in atomically thin nanoribbons such as graphene as the relaxation of edge stresses occurs preferentially via out-of-plane deflections. In the case of end-supported suspended nanoribbons that we study here, past experiments and computations have identified a range of equilibrium morphologies, in particular, for graphene flakes, yet a unified understanding of their relative stability remains elusive. Here, we employ atomic-scale simulations and a composite framework based on isotropic elastic plate theory to chart out the morphological stability space of suspended nanoribbons with respect to intrinsic (ribbon elasticity) and engineered (ribbon geometry) parameters, and the combination of edge and body actuation. The computations highlight a rich morphological shape space that can be naturally classified into two competing shapes, bendinglike and twistlike, depending on the distribution of ripples across the interacting edges. The linearized elastic framework yields exact solutions for these rippled shapes. For compressive edge stresses, the body strain emerges as a key variable that controls their relative stability and in extreme cases stabilizes coexisting transverse ripples. Tensile edge stresses lead to dimples within the ribbon core that decay into the edges, a feature of obvious significance for stretchable nanoelectronics. The interplay between geometry and mechanics that we report should serve as a key input for quantifying the transport along these ribbons.

  7. Advanced Cathodes for Next Generation Electric Propulsion Technology

    Science.gov (United States)

    2008-03-01

    28 Boride Cathodes...45 Figure 15. Molybdenum Hollow Cathode Tube .............................................................. 46...CeB6 as a hollow cathode electron emitter. Additionally, all work in the US published on boride hollow cathodes are for high-current applications

  8. A pre-lithiation method for sulfur cathode used for future lithium metal free full battery

    Science.gov (United States)

    Wu, Yunwen; Yokoshima, Tokihiko; Nara, Hiroki; Momma, Toshiyuki; Osaka, Tetsuya

    2017-02-01

    Lithium metal free sulfur battery paired by lithium sulfide (Li2S) is a hot point in recent years because of its potential for relatively high capacity and its safety advantage. Due to the insulating nature and high sensitivity to moisture of Li2S, it calls for new way to introduce Li ion into S cathode besides the method of directly using the Li2S powder for the battery pre-lithiation. Herein, we proposed a pre-lithiation method to lithiate the polypyrrole (PPy)/S/Ketjenblack (KB) electrode into PPy/Li2S/KB cathode at room temperature. By this process, the fully lithiated PPy/Li2S/KB cathode showed facilitated charge transfer than the original PPy/S/KB cathode, leading to better cycling performance at high C-rates and disappearance of over potential phenomenon. In this work, the ion-selective PPy layer has been introduced on the cathode surface by an electrodeposition method, which can suppress the polysulfide dissolution from the cathode source. The lithium metal free full battery coupled by the prepared Li2S/KB cathode and graphite anode exhibited excellent cycling performance. Hence, we believe this comprehensive fabrication approach of Li2S cathode will pave a way for the application of new type lithium metal free secondary battery.

  9. Reservoir Cathode for Electric Space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a reservoir cathode to improve performance in both ion and Hall-effect thrusters. We propose to adapt our existing reservoir cathode technology to this...

  10. Reservoir Cathode for Electric Space Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose a hollow reservoir cathode to improve performance in ion and Hall thrusters. We will adapt our existing reservoir cathode technology to this purpose....

  11. Digital collections and exhibits

    CERN Document Server

    Denzer, Juan

    2015-01-01

    Today's libraries are taking advantage of cutting-edge technologies such as flat panel displays using touch, sound, and hands-free motions to design amazing exhibits using everything from simple computer hardware to advanced technologies such as the Microsoft Kinect. Libraries of all types are striving to add new interactive experiences for their patrons through exciting digital exhibits, both online and off. Digital Collections and Exhibits takes away the mystery of designing stunning digital exhibits to spotlight library trea

  12. Ethics on Exhibit

    Science.gov (United States)

    Vick, Randy M.

    2011-01-01

    This article discusses ethical questions raised by an exhibition of work by an artist with a history of mental illness and the exhibition's relevance to art therapy and “outsider art” discourse on the subject. Considerations for how such an exhibit could be handled had the circumstances included an art therapist and art therapy client are…

  13. Mechanistic Enhancement of SOFC Cathode Durability

    Energy Technology Data Exchange (ETDEWEB)

    Wachsman, Eric [Univ. of Maryland, College Park, MD (United States)

    2016-02-01

    Durability of solid oxide fuel cells (SOFC) under “real world” conditions is an issue for commercial deployment. In particular cathode exposure to moisture, CO2, Cr vapor (from interconnects and BOP), and particulates results in long-term performance degradation issues. Here, we have conducted a multi-faceted fundamental investigation of the effect of these contaminants on cathode performance degradation mechanisms in order to establish cathode composition/structures and operational conditions to enhance cathode durability.

  14. Novel Cathodes Prepared by Impregnation Procedures

    Energy Technology Data Exchange (ETDEWEB)

    Eduardo Paz

    2006-09-30

    (1) We showed that similar results were obtained when using various LSM precursors to produce LSM-YSZ cathodes. (2) We showed that enhanced performance could be achieved by adding LSCo to LSMYSZ cathodes. (3) We have preliminary results showing that there is a slow deactivation with LSFYSZ cathodes.

  15. Measured cathode fall characteristics depending on the diameter of a hydrogen hollow cathode discharge

    Science.gov (United States)

    Gonzalez-Fernandez, V.; Grützmacher, K.; Steiger, A.; Pérez, C.; de la Rosa, M. I.

    2017-10-01

    In this work, Doppler-free two photon optogalvanic spectroscopy is used to measure the electric field strength in the cathode fall region of a hollow cathode discharge, operated in pure hydrogen, via the Stark splitting of the 2S level of atomic hydrogen. The cathode fall characteristics are analysed for various pressures and in a wide range of discharge currents. Tungsten is used as the cathode material, because it allows for reliable measurements in a fairly wide range of discharge conditions and because of its minimal sputtering. Two cathode diameters (10 mm and 15 mm) are used to study the dependence of the cathode fall on discharge geometry. The measurements reveal that the cathode fall characteristics are quite independent on the cathode diameter for equal cathode current density; hence the measurements can be used to test one dimensional modelling of the cathode fall region for low pressure hydrogen discharges using e.g. plane parallel electrodes.

  16. Conductive framework of inverse opal structure for sulfur cathode in lithium-sulfur batteries

    OpenAIRE

    Lu Jin; Xiaopeng Huang; Guobo Zeng; Hua Wu; Massimo Morbidelli

    2016-01-01

    As a promising cathode inheritor for lithium-ion batteries, the sulfur cathode exhibits very high theoretical volumetric capacity and energy density. In its practical applications, one has to solve the insulating properties of sulfur and the shuttle effect that deteriorates cycling stability. The state-of-the-art approaches are to confine sulfur in a conductive matrix. In this work, we utilize monodisperse polystyrene nanoparticles as sacrificial templates to build polypyrrole (PPy) framework...

  17. Approximate Series Solutions for Nonlinear Free Vibration of Suspended Cables

    Directory of Open Access Journals (Sweden)

    Yaobing Zhao

    2014-01-01

    Full Text Available This paper presents approximate series solutions for nonlinear free vibration of suspended cables via the Lindstedt-Poincare method and homotopy analysis method, respectively. Firstly, taking into account the geometric nonlinearity of the suspended cable as well as the quasi-static assumption, a mathematical model is presented. Secondly, two analytical methods are introduced to obtain the approximate series solutions in the case of nonlinear free vibration. Moreover, small and large sag-to-span ratios and initial conditions are chosen to study the nonlinear dynamic responses by these two analytical methods. The numerical results indicate that frequency amplitude relationships obtained with different analytical approaches exhibit some quantitative and qualitative differences in the cases of motions, mode shapes, and particular sag-to-span ratios. Finally, a detailed comparison of the differences in the displacement fields and cable axial total tensions is made.

  18. 23 Elemental Composition of Suspended Particulate Matter ...

    African Journals Online (AJOL)

    `123456789jkl''''#

    Elemental Composition of Suspended Particulate Matter Collected at Two Different. Heights above the Ground in A Sub-Urban Site in Kenya. Gitari W. M1, Kinyua A. M. 2, Kamau G. N3 and C. K. Gatebe C. K4. Abstract. Suspended particulate matter samples were collected in a sub-urban area in Nairobi over a 12 month ...

  19. High surface area stainless steel brushes as cathodes in microbial electrolysis cells.

    Science.gov (United States)

    Call, Douglas F; Merrill, Matthew D; Logan, Bruce E

    2009-03-15

    Microbial electrolysis cells (MECs) are an efficient technology for generating hydrogen gas from organic matter, but alternatives to precious metals are needed for cathode catalysts. We show here that high surface area stainless steel brush cathodes produce hydrogen at rates and efficiencies similar to those achieved with platinum-catalyzed carbon cloth cathodes in single-chamber MECs. Using a stainless steel brush cathode with a specific surface area of 810 m2/m3, hydrogen was produced at a rate of 1.7 +/- 0.1 m3-H2/m3-d (current density of 188 +/- 10 A/m3) at an applied voltage of 0.6 V. The energy efficiency relative to the electrical energy input was 221 +/- 8%, and the overall energy efficiency was 78 +/- 5% based on both electrical energy and substrate utilization. These values compare well to previous results obtained using platinum on flat carbon cathodes in a similar system. Reducing the cathode surface area by 75% decreased performance from 91 +/- 3 A/m3 to 78 +/- 4 A/m3. A brush cathode with graphite instead of stainless steel and a specific surface area of 4600 m2/m3 generated substantially less current (1.7 +/- 0.0 A/m3), and a flat stainless steel cathode (25 m2/m3) produced 64 +/- 1 A/m3, demonstrating that both the stainless steel and the large surface area contributed to high current densities. Linear sweep voltammetry showed that the stainless steel brush cathodes both reduced the overpotential needed for hydrogen evolution and exhibited a decrease in overpotential over time as a result of activation. These results demonstrate for the first time that hydrogen production can be achieved at rates comparable to those with precious metal catalysts in MECs without the need for expensive cathodes.

  20. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    Energy Technology Data Exchange (ETDEWEB)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2002-03-31

    This project has three main goals: Thin Films Studies, Preparation of Graded Porous Substrates and Basic Electrical Characterization and testing of Planar Single Cells. This period has continued to address the problem of making dense 1/2 to 5 {micro}m thick dense layers on porous substrates (the cathode LSM). Our current status is that we are making structures of 2-5 cm{sup 2} in area, which consist of either dense YSZ or CGO infiltrated into a 2-5 {micro}m thick 50% porous layer made of either nanoncrystalline CGO or YSZ powder. This composite structure coats a macroporous cathode or anode; which serves as the structural element of the bi-layer structure. These structures are being tested as SOFC elements. A number of structures have been evaluated both as symmetrical and as button cell configuration. Results of this testing indicates that the cathodes contribute the most to cell losses for temperatures below 750 C. In this investigation different cathode materials were studied using impedance spectroscopy of symmetric cells and IV characteristics of anode supported fuel cells. Cathode materials studied included La{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (LSCF), La{sub 0.7}Sr{sub 0.2}MnO{sub 3} (LSM), Pr{sub 0.8}Sr{sub 0.2}Fe{sub 0.8}O{sub 3} (PSCF), Sm{sub 0.8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF), and Yb{sub .8}Sr{sub 0.2}Co{sub 0.2}Fe{sub 0.8}O{sub 3} (SSCF). A new technique for filtering the Fourier transform of impedance data was used to increase the sensitivity of impedance analysis. By creating a filter specifically for impedance spectroscopy the resolution was increased. The filter was tailored to look for specific circuit elements like R//C, Warburg, or constant phase elements. As many as four peaks can be resolved using the filtering technique on symmetric cells. It may be possible to relate the different peaks to material parameters, like the oxygen exchange coefficient. The cathode grouped in order from lowest to highest ASR is

  1. Visitors Center Exhibits

    Science.gov (United States)

    1997-01-01

    A child enjoys building his own LEGO model at a play table which was included in the exhibit 'Travel in Space' World Show. The exhibit consisted of 21 displays designed to teach children about flight and space travel from the Wright brothers to future generations of space vehicles.

  2. Sonnesgade 11 - Exhibition

    DEFF Research Database (Denmark)

    Carbone, Claudia; Toft, Anne Elisabeth

    2013-01-01

    This exhibition consists of site specific installations; a collection of work by students from Studio Constructing an Archive at the Aarhus School of Architecture, and SLETH Architects. The exhibition showcases the culmination of a common project which began in February 2013. The project has been...

  3. Exhibition in Sight

    Science.gov (United States)

    Wasserman, Burton

    1977-01-01

    The traveling exhibition titled "The Wild Beasts: Fauvism and its Affinities" opened first at the Museum of Modern Art in New York City and was then moved to the San Francisco Museum of Modern Art in 1976. Discusses the exhibition's historic value, how Fauvism passed through three fairly distinct stylistic phases, and the social…

  4. Space physics exhibits underway

    Science.gov (United States)

    DeVito, M. Catherine

    AGU is planning a new space science exhibit for the Smithsonian Institution's National Air and Space Museum in Washington that will help visitors come to an understanding of space science as a comprehensive, interdisciplinary, and exciting field. The title of the exhibit is “Electric Space: Our Earth-Sun Environment.” The exhibit's five modules will include demonstrations of the effects of particle and field radiation on humans and satellites in space and on human technology on the ground. The project also includes a larger traveling version that will visit science and technology centers throughout the United States. The first exhibit is planned to open at the Air and Space Museum in late summer or early fall 1992, in time for International Space Year activities; the traveling exhibit will begin touring in early 1993.

  5. Filters for cathodic arc plasmas

    Science.gov (United States)

    Anders, Andre; MacGill, Robert A.; Bilek, Marcela M. M.; Brown, Ian G.

    2002-01-01

    Cathodic arc plasmas are contaminated with macroparticles. A variety of magnetic plasma filters has been used with various success in removing the macroparticles from the plasma. An open-architecture, bent solenoid filter, with additional field coils at the filter entrance and exit, improves macroparticle filtering. In particular, a double-bent filter that is twisted out of plane forms a very compact and efficient filter. The coil turns further have a flat cross-section to promote macroparticle reflection out of the filter volume. An output conditioning system formed of an expander coil, a straightener coil, and a homogenizer, may be used with the magnetic filter for expanding the filtered plasma beam to cover a larger area of the target. A cathodic arc plasma deposition system using this filter can be used for the deposition of ultrathin amorphous hard carbon (a-C) films for the magnetic storage industry.

  6. Improving suspended sediment measurements by automatic samplers.

    Science.gov (United States)

    Gettel, Melissa; Gulliver, John S; Kayhanian, Masoud; DeGroot, Gregory; Brand, Joshua; Mohseni, Omid; Erickson, Andrew J

    2011-10-01

    Suspended solids either as total suspended solids (TSS) or suspended sediment concentration (SSC) is an integral particulate water quality parameter that is important in assessing particle-bound contaminants. At present, nearly all stormwater runoff quality monitoring is performed with automatic samplers in which the sampling intake is typically installed at the bottom of a storm sewer or channel. This method of sampling often results in a less accurate measurement of suspended sediment and associated pollutants due to the vertical variation in particle concentration caused by particle settling. In this study, the inaccuracies associated with sampling by conventional intakes for automatic samplers have been verified by testing with known suspended sediment concentrations and known particle sizes ranging from approximately 20 μm to 355 μm under various flow rates. Experimental results show that, for samples collected at a typical automatic sampler intake position, the ratio of sampled to feed suspended sediment concentration is up to 6600% without an intake strainer and up to 300% with a strainer. When the sampling intake is modified with multiple sampling tubes and fitted with a wing to provide lift (winged arm sampler intake), the accuracy of sampling improves substantially. With this modification, the differences between sampled and feed suspended sediment concentration were more consistent and the sampled to feed concentration ratio was accurate to within 10% for particle sizes up to 250 μm.

  7. Barium-Dispenser Thermionic Cathode

    Science.gov (United States)

    Wintucky, Edwin G.; Green, M.; Feinleib, M.

    1989-01-01

    Improved reservoir cathode serves as intense source of electrons required for high-frequency and often high-output-power, linear-beam tubes, for which long operating lifetime important consideration. High emission-current densities obtained through use of emitting surface of relatively-low effective work function and narrow work-function distribution, consisting of coat of W/Os deposited by sputtering. Lower operating temperatures and enhanced electron emission consequently possible.

  8. Abrasion properties of self-suspended hairy titanium dioxide nanomaterials

    Science.gov (United States)

    Zhang, Jiao-xia; Liu, Si; Yan, Chao; Wang, Xiao-jing; Wang, Lei; Yu, Ya-ming; Li, Shi-yun

    2017-10-01

    Considering the excellent solubility of pyrrolidone ring organic compounds, the synthesized N-(trimethoxysilyl) propyl-N-methyl-2-pyrrolidone chlorides was tethered onto titanium dioxide (TiO2) nanoparticles to improve dispersion of TiO2, and then polyethylene oxide (PEO) oligomer through ion exchange embraced the tethered TiO2 to obtain a novel self-suspended hairy TiO2 nanomaterials without any solvent. A variety of techniques were carried out to illustrate the structure and properties of the self-suspended hairy TiO2 nanomaterials. It was found that TiO2 nanoparticles embody monodispersity in the hybrid system though the "false reunion" phenomenon occurring due to nonpermanent weak physical cross-linking. Remarkably, self-suspended hairy TiO2 nanomaterials exhibit lower viscosity, facilitating maneuverable and outstanding antifriction and wear resistance properties, due to the synergistic lubricating effect between spontaneously forming lubricating film and nano-lubrication of TiO2 cores, overcoming the deficiency of both solid and liquid lubricants. This make them promising candidates for the micro-electromechanic/nano-electromechanic systems (MEMS/NEMS).

  9. Mucous Secretion and Cilia Beating Defend Developing Coral Larvae from Suspended Sediments.

    Directory of Open Access Journals (Sweden)

    Gerard F Ricardo

    Full Text Available Suspended sediments produced from dredging activities, or added to the sediment budget via river runoff, are a concern for marine resource managers. Understanding the impact of suspended sediments on critical life history stages of keystone species like corals is fundamental to effective management of coastlines and reefs. Coral embryos (Acropora tenuis and A. millepora and larvae (A. tenuis, A. millepora and Pocillopora acuta were subjected to a range of suspended sediment concentrations of different sediment types (siliciclastic and carbonate to assess concentration-response relationships on ecologically relevant endpoints, including survivorship and ability to metamorphose. Embryos were subjected to short (12 h suspended sediment exposures from ages of 3-12 hours old or a long (30 h exposure at 6 hours old. Neither the survivorship nor metamorphosis function of embryos were significantly affected by realistic sediment exposures to ~1000 mg L-1. However, some embryos exhibited a previously undescribed response to dynamically suspended sediments, which saw 10% of the embryos form negatively buoyant cocoons at siliciclastic suspended sediment concentrations ≥35 mg L-1. Scanning electron and optical microscopy confirmed the presence of a coating on these embryos, possibly mucus with incorporated sediment particles. Cocoon formation was common in embryos but not in larvae, and occurred more often after exposure to siliciclastic rather than carbonate sediments. Once transferred into sediment-free seawater, functional ~36-h-old embryos began emerging from the cocoons, coinciding with cilia development. Ciliated (> 36-h-old larvae exposed to suspended sediments for 60 h were also observed to secrete mucus and were similarly unaffected by suspended sediment concentrations to ~800 mg L-1. This study provides evidence that mucous secretion and cilia beating effectively protect coral embryos and larvae from suspended sediment and that these mechanisms

  10. Communicating Science through Exhibitions

    Science.gov (United States)

    Dusenbery, Paul

    2005-04-01

    It is critically important for the public to better understand the scientific process. Museum exhibitions are an important part of informal science education that can effectively reach public audiences as well as school groups. They provide an important gateway for the public to learn about compelling scientific endeavors. Science exhibitions also provide a marvelous opportunity for scientists to become engaged in the exhibit development process. The Space Science Institute (SSI) is a national leader in producing traveling science exhibitions and their associated educational programming (i.e. interactive websites, educator workshops, public talks, instructional materials). The focus of this presentation will be on two of its exhibit projects: MarsQuest (on tour for four years) and Alien Earths (its tour began early in 2005). MarsQuest is enabling millions of Americans to share in the excitement of the scientific exploration of Mars and to learn more about their own planet in the process. Alien Earths will bring origins-related research and discoveries to students and the American public. It has four interrelated exhibit areas: Our Place in Space, Star Birth, Planet Quest, and Search for Life. Exhibit visitors will explore the awesome events surrounding the birth of stars and planets; they will join scientists in the hunt for planets outside our solar system including those that may be in ``habitable zones'' around other stars; and finally they will be able to learn about how scientists are looking for signs of life beyond Earth. SSI is also developing interactive web sites based on exhibit themes. New technologies are transforming the Web from a static medium to an interactive environment with tremendous potential for informal education and inquiry-based investigations. This talk will focus on the role informal science projects play in effectively communicating science to a broad, public audience.

  11. Sulfur cathode based on layered carbon matrix for high-performance Li–S batteries

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Feng; Qian, Ji; Chen, Renjie; Zhao, Teng; Xu, Rui; Ye, Yusheng; Li, Wenhui; Li, Li; Lu, Jun; Amine, Khalil

    2015-03-01

    A novel carbon/sulfur composite has been fabricated by means of thermal and hydro-thermal treatments to serve as the cathode in Li -S batteries. The carbon matrix consists of graphene nanosheet (GS) and multiwalled carbon nanotube (MWCNT). The "GS/MWCNT@S" composite allows for infiltration of electrolyte into the cathode, assists in entrapment of polysulfide intermediates, and accommodates some of the stress and volume expansion that occurs during charge discharge processes. In addition, the uniform distribution of sulfur in the conductive carbon matrix promotes utilization of the active materials. A Li-S cell containing the GS/MWCNT@S cathode delivered a capacity of 1290.8 mAh/g and exhibited stable specific capacities up to 612.1 mAh/g after 200 cycles at 0.1 C. These results demonstrate that this cathode material is a promising candidate for rechargeable lithium batteries with high energy density.

  12. PB/PANI-modified electrode used as a novel oxygen reduction cathode in microbial fuel cell.

    Science.gov (United States)

    Fu, Lei; You, Shi-Jie; Zhang, Guo-Quan; Yang, Feng-Lin; Fang, Xiao-Hong; Gong, Zheng

    2011-01-15

    This study focuses on the preparation of a new type of Prussian Blue/polyaniline (PB/PANI)-modified electrode as oxygen reduction cathode, and its availability in microbial fuel cell (MFC) for biological power generation. The PB/PANI-modified electrode was prepared by electrochemical and chemical methods, both of which exhibited good electrocatalytical reactivity for oxygen reduction in acidic electrolyte. The MFC with PB/PANI-modified cathode aerated by either oxygen or air was shown to yield a maximum power density being the same with that of the MFC with liquid-state ferricyanide cathode, and have an excellent duration as indicated by stable cathode potential for more than eight operating circles. This study suggests a promising potential to utilize this novel electrode as an effective alternative to platinum for oxygen reduction in MFC system without losing sustainability. Copyright © 2010 Elsevier B.V. All rights reserved.

  13. [Light absorption by suspended particulate matter in Chagan Lake, Jilin].

    Science.gov (United States)

    Wang, Yuan-Dong; Liu, Dian-Wei; Song, Kai-Shan; Zhang, Bai; Wang, Zong-Ming; Jiang, Guang-Ji; Tang, Xu-Guang; Lei, Xiao-Chun; Wu, Yan-Qing

    2011-01-01

    Spectral characteristics and the magnitudes of light absorption by suspended particulate matter were determined by spectrophotometry in this optically complex Lake Chagan waters for the purpose of surveying the natural variability of the absorption coefficients to parameterize the bio-optical models for converting satellite or in-situ water reflectance signatures into water quality information. Experiments were carried out on seasonal frozen Lake Chagan, one representative inland case-2 water body in Northeast of China. Particulate absorption properties analyzed using the field data on July 15th and October 12th 2009 were measured using the quantitative filter technique to produce absorption spectra containing several fractions that could be attributed to two main optical active constituents (OACs) phytoplankton pigments and non-algal particulates (mineral sediments, and organic detritus). Results suggested that the suspended particulate matter (SPM) concentration was higher while phytoplankton biomass (chlorophyll-a concentration) was lower in July and that in October. The spectral shape of total suspended particulate matter resembled that of non-algal particulates which contributed greater than phytoplankton in total particulate absorption during both periods. An obvious absorption peak occurring at around 440 nm exhibited an increase in phytoplankton contribution in October. Non-algal particulate absorption at 440 nm (a(NAP) (440)) had better correlation with total suspended particulate matter concentration than that with chlorophyll-a over the two periods. Light absorption by phytoplankton pigments in the Chagan lake region was generally lower than that of non-algal components. Chl. a dominating phytoplankton pigment composition functioned exponentially with its absorption coefficients at 440 and 675 nm specifically, the average values of which in July were 0.146 8 m2 x mg(-1) and 0.050 3 respectively while in October they were 0.153 3 and 0.013 2 m2 x mg(-1

  14. Understanding Mn-Based Intercalation Cathodes from Thermodynamics and Kinetics

    Directory of Open Access Journals (Sweden)

    Yin Xie

    2017-07-01

    Full Text Available A series of Mn-based intercalation compounds have been applied as the cathode materials of Li-ion batteries, such as LiMn2O4, LiNi1−x−yCoxMnyO2, etc. With open structures, intercalation compounds exhibit a wide variety of thermodynamic and kinetic properties depending on their crystal structures, host chemistries, etc. Understanding these materials from thermodynamic and kinetic points of view can facilitate the exploration of cathodes with better electrochemical performances. This article reviews the current available thermodynamic and kinetic knowledge on Mn-based intercalation compounds, including the thermal stability, structural intrinsic features, involved redox couples, phase transformations as well as the electrical and ionic conductivity.

  15. Rechargeable lithium cells with modified vanadium oxide cathodes

    Science.gov (United States)

    Chung, S. K.; Chmilenko, N. A.; Borovykov, A. Ya; Lee, S. H.

    Modified vanadium oxide has been prepared by melting V 2O 5 with additives of 3-3.5% of sodium orthosilicate at 690°C for 3 h followed by fast cooling to an ambient temperature. Charge-discharge characteristics of this oxide were studied as an active cathode material for lithium secondary batteries. The oxide undergoes irreversible transition to become essentially amorphous after first discharge to cut-off voltage of 2 V vs. Li, and then exhibits excellent rechargeability in the 1.5 to 3.9 V potential range. The coin type 2325 size secondary cells have been manufactured and tested with the modified vanadium oxide cathodes and Li-Al alloy anodes. Preliminary shallow cycling modifies the cells' performance and allows to obtain rating capacity 50 mA h in the voltage diapason of 2.0-3.9 V with draining current 0.5 mA.

  16. Reflective article having a sacrificial cathodic layer

    Science.gov (United States)

    Kabagambe, Benjamin; Buchanan, Michael J.; Scott, Matthew S.; Rearick, Brian K.; Medwick, Paul A.; McCamy, James W.

    2017-09-12

    The present invention relates to reflective articles, such as solar mirrors, that include a sacrificial cathodic layer. The reflective article, more particularly includes a substrate, such as glass, having a multi-layered coating thereon that includes a lead-free sacrificial cathodic layer. The sacrificial cathodic layer includes at least one transition metal, such as a particulate transition metal, which can be in the form of flakes (e.g., zinc flakes). The sacrificial cathodic layer can include an inorganic matrix formed from one or more organo-titanates. Alternatively, the sacrificial cathodic layer can include an organic polymer matrix (e.g., a crosslinked organic polymer matrix formed from an organic polymer and an aminoplast crosslinking agent). The reflective article also includes an outer organic polymer coating, that can be electrodeposited over the sacrificial cathodic layer.

  17. Electrochemical struvite precipitation from digestate with a fluidized bed cathode microbial electrolysis cell

    KAUST Repository

    Cusick, Roland D.

    2014-05-01

    Microbial electrolysis cells (MECs) can be used to simultaneously convert wastewater organics to hydrogen and precipitate struvite, but scale formation at the cathode surface can block catalytic active sites and limit extended operation. To promote bulk phase struvite precipitation and minimize cathode scaling, a two-chamber MEC was designed with a fluidized bed to produce suspended particles and inhibit scale formation on the cathode surface. MEC operation elevated the cathode pH to between 8.3 and 8.7 under continuous flow conditions. Soluble phosphorus removal using digester effluent ranged from 70 to 85% with current generation, compared to 10-20% for the control (open circuit conditions). At low current densities (≤2mA/m2), scouring of the cathode by fluidized particles prevented scale accumulation over a period of 8 days. There was nearly identical removal of soluble phosphorus and magnesium from solution, and an equimolar composition in the collected solids, supporting phosphorus removal by struvite formation. At an applied voltage of 1.0V, energy consumption from the power supply and pumping (0.2Wh/L, 7.5Wh/g-P) was significantly less than that needed by other struvite formation methods based on pH adjustment such as aeration and NaOH addition. In the anode chamber, current generation led to COD oxidation (1.1-2.1g-COD/L-d) and ammonium removal (7-12mM) from digestate amended with 1g/L of sodium acetate. These results indicate that a fluidized bed cathode MEC is a promising method of sustainable electrochemical nutrient and energy recovery method for nutrient rich wastewaters. © 2014 Elsevier Ltd.

  18. Council Chamber exhibition

    CERN Multimedia

    CERN Bulletin

    2010-01-01

    To complete the revamp of CERN’s Council Chamber, a new exhibition is being installed just in time for the June Council meetings.   Panels will showcase highlights of CERN’s history, using some of the content prepared for the exhibitions marking 50 years of the PS, which were displayed in the main building last November. The previous photo exhibition in the Council Chamber stopped at the 1970s. To avoid the new panels becoming quickly out of date, photos are grouped together around specific infrastructures, rather than following a classic time-line. “We have put the focus on the accelerators – the world-class facilities that CERN has been offering researchers over the years, from the well-known large colliders to the lesser-known smaller facilities,” says Emma Sanders, who worked on the content. The new exhibition will be featured in a future issue of the Bulletin with photos and an interview with Fabienne Marcastel, designer of the exhibit...

  19. EXHIBITION: Accelerated Particles

    CERN Multimedia

    2004-01-01

    An exhibition of plastic arts and two evenings of performances by sound and visual artists as part of CERN's 50th anniversary celebrations. Fifty candles for CERN, an international laboratory renowned for fundamental research, is a cause for celebration. Since March this year, Geneva and neighbouring parts of France have been the venues for a wealth of small and large-scale events, which will continue until November. Given CERN's location in the commune of Meyrin, the ForuMeyrin is hosting exhibitions of plastic arts and performances entitled: Accelerated Particles. Several works will be exhibited and performed in two 'salons'. Salon des matières: An exhibition of plastic arts From Tues 12 October to Wed 3 November 2004 Tuesdays to Fridays: 16:00 to 19:00 Saturdays: 14:00 to 18:00 Exhibition open late on performance nights, entrance free Salon des particules: Musical and visual performances Tues 12 and Mon 25 October from 20:00 to 23:00 Preview evening for both events: Tues 12 October from 18:...

  20. Arc initiation in cathodic arc plasma sources

    Science.gov (United States)

    Anders, Andre

    2002-01-01

    A "triggerless" arc initiation method and apparatus is based on simply switching the arc supply voltage to the electrodes (anode and cathode). Neither a mechanical trigger electrode nor a high voltage flashover from a trigger electrode is required. A conducting path between the anode and cathode is provided, which allows a hot spot to form at a location where the path connects to the cathode. While the conductive path is eroded by the cathode spot action, plasma deposition ensures the ongoing repair of the conducting path. Arc initiation is achieved by simply applying the relatively low voltage of the arc power supply, e.g. 500 V-1 kV, with the insulator between the anode and cathode coated with a conducting layer and the current at the layer-cathode interface concentrated at one or a few contact points. The local power density at these contact points is sufficient for plasma production and thus arc initiation. A conductive surface layer, such as graphite or the material being deposited, is formed on the surface of the insulator which separates the cathode from the anode. The mechanism of plasma production (and arc initiation) is based on explosive destruction of the layer-cathode interface caused by joule heating. The current flow between the thin insulator coating and cathode occurs at only a few contact points so the current density is high.

  1. Cathode fall measurements in fluorescent lamps

    Energy Technology Data Exchange (ETDEWEB)

    Nachtrieb, Robert [Lutron Electronics Co Inc., 7200 Suter Rd., Coopersburg, PA 18036 (United States); Khan, Farheen [Lutron Electronics Co Inc., 7200 Suter Rd., Coopersburg, PA 18036 (United States); Waymouth, John F [Consultant, 16 Bennett Rd. Marblehead, MA 01945 (United States)

    2005-09-07

    We describe an improved method and apparatus for making capacitive measurements of the cathode fall in fluorescent lamps employing known behaviour of anode oscillations to provide a zero-of-potential reference, placing the entire cathode and anode fall waveform on an absolute rather than relative scale. The improved method is applicable to any diameter of fluorescent lamp currently manufactured. We also describe a method and apparatus for making spectroscopic measurements of the cathode fall in fluorescent lamps. This uses the abrupt onset of emission of certain selected spectral lines of the rare gas filling as a signal that the cathode fall has exceeded the excitation potentials of the spectral lines in question.

  2. Exhibition in Sight

    Science.gov (United States)

    Wasserman, Burton

    1978-01-01

    Ludwig Mies van der Rohe is known primarily as an architect. However, he also designed chairs and tables. Discusses an exhibit held in New York City a few months ago which showed how well the famous architect achieved his goals in the area of furniture design. (Author/RK)

  3. EXHIBITION: Accelerated Particles

    CERN Multimedia

    2004-01-01

    http://www.cern.ch/cern50/ An exhibition of plastic arts and two evenings of performances by sound and visual artists as part of CERN's fiftieth anniversary celebrations. The fiftieth anniversary of a world famous organization like CERN, an international laboratory specializing in fundamental research, is a cause for celebration. Since March this year, Geneva and neighbouring parts of France have been the venues for a wealth of small and large-scale events, which will continue until November. Given CERN's location in the commune of Meyrin, the ForuMeyrin is hosting two "salons" consisting of an exhibition of plastic arts and evenings of music and visual arts performances with the collective title of "Accelerated Particles". Several works will be exhibited and performed. Salon des matières: An exhibition of plastic arts Until Wednesday 3 November 2004. Tuesdays to Fridays: 4.00 p.m. to 7.00 p.m. Saturdays: 2.00 p.m. to 6.00 p.m. Doors open late on the evening of the performances. Salon des ...

  4. Self-suspended permanent magnetic FePt ferrofluids

    KAUST Repository

    Dallas, Panagiotis

    2013-10-01

    We present the synthesis and characterization of a new class of self-suspended ferrofluids that exhibit remanent magnetization at room temperature. Our system relies on the chemisorption of a thiol-terminated ionic liquid with very low melting point on the surface of L10 FePt nanoparticles. In contrast, all types of ferrofluids previously reported employ either volatile solvents as the suspending media or superparamagnetic iron oxide nanoparticles (that lacks permanent magnetization) as the inorganic component. The ferrofluids do not show any sign of flocculation or phase separation, despite the strong interactions between the magnetic nanoparticles due to the strong chemisorption of the ionic liquid as evidenced by Raman spectroscopy and thermal analysis. Composites with high FePt loading (40 and 70. wt%) exhibit a pseudo solid-like rheological behavior and high remanent magnetization values (10.1 and 12.8. emu/g respectively). At lower FePt loading (12. wt%) a liquid like behavior is observed and the remanent and saturation magnetization values are 3.5 and 6.2. emu/g, respectively. The magnetic and flow properties of the materials can be easily fine tuned by controlling the type and amount of FePt nanoparticles used. © 2013 Elsevier Inc.

  5. Lithography-Free Fabrication of Silica Nanocylinders with Suspended Gold Nanorings for LSPR-Based Sensing

    DEFF Research Database (Denmark)

    Thilsted, Anil Haraksingh; Pan, Jesper Yue; Wu, Kaiyu

    2016-01-01

    areas, such as 8 in. wafers. The authors demonstrate that gold coated nanocylinders support localized surface plasmon resonances (LSPR) from visible to near infrared wavelengths. The plasmonic platform can be characterized as suspended gold nanorings and exhibits a sensitivity of 658 nm RIU-1...

  6. CERN permanent exhibitions

    CERN Multimedia

    2016-01-01

    Explore by yourself the issues CERN's physicists are trying to solve: given that the entire universe is made of particles, where do they come from? Why do they behave in the way they do? Discover the massive apparatus used by physicists at CERN, like the LHC, and see how each part works. And if you have more time on site, follow the LHC circuit at ground level to understand in situ this giant machine. Enter our exhibitions. Welcome!

  7. Experimental Design of Electrocoagulation and Magnetic Technology for Enhancing Suspended Solids Removal from Synthetic Wastewater

    Directory of Open Access Journals (Sweden)

    Moh Faiqun Ni'am

    2014-10-01

    Full Text Available Design of experiments (DOE is one of the statistical method that is used as a tool to enhance and improve experimental quality. The changes to the variables of a process or system is supposed to give the optimal result (response and quite satisfactory. Experimental design can defined as a test or series of test series by varying the input variables (factors of a process that can known to cause changes in output (response. This paper presents the results of experimental design of wastewater treatment by electrocoagulation (EC technique. A combined magnet and electrocoagulation (EC technology were designed to increase settling velocity and to enhance suspended solid removal efficiencies from wastewater samples. In this experiment, a synthetic wastewater samples were prepared by mixing 700 mg of the milk powder in one litre of water and treated by using an acidic buffer solution. The monopolar iron (Fe plate anodes and cathodes were employed as electrodes. Direct current was varied in a range of between 0.5 and 1.1 A, and flowrate in a range of between 1.00 to 3.50 mL/s. One permanent magnets namely AlNiCo with a magnetic strength of 0.16T was used in this experiment. The results show that the magnetic field and the flowrate have major influences on suspended solids removal. The efficiency removals of suspended solids, turbidity and COD removal efficiencies at optimum conditions were found to be more than 85%, 95%, and 75%, respectively.

  8. Upcycling CERN Exhibitions

    CERN Multimedia

    Katarina Anthony

    2015-01-01

    Summer is coming - and with it, a new Microcosm exhibition showcasing CERN (see here). But while the new exhibit is preparing to enchant visitors, many have been asking about the site's former content. Will it simply be out with the old and in with the new? Not as such!   The plasma ball from Microcosm is now on display at the LHCb site. As Microcosm's new content is moving in, its old content is moving up. From LHCb to IdeaSquare, former Microcosm displays and objects are being installed across the CERN site. "Microcosm featured many elements that were well suited to life outside of the exhibition," says Emma Sanders, Microcosm project leader in the EDU group. "We didn't want this popular content to go to waste, and so set out to find them new homes across CERN." The LHCb experiment has received a number of Microcosm favourites, including the Rutherford experiment, the cosmic ray display and the Thomson experiment. "We&...

  9. Directly Coating a Multifunctional Interlayer on the Cathode via Electrospinning for Advanced Lithium-Sulfur Batteries.

    Science.gov (United States)

    Peng, Yueying; Zhang, Yiyong; Wang, Yunhui; Shen, Xiu; Wang, Feng; Li, He; Hwang, Bing-Joe; Zhao, Jinbao

    2017-09-06

    The lithium-sulfur battery is considered as a prospective candidate for a high-energy-storage system because of its high theoretical specific capacity and energy. However, the dissolution and shutter of polysulfides lead to low active material utilization and fast capacity fading. Electrospinning technology is employed to directly coat an interlayer composed of polyacrylonitrile (PAN) and nitrogen-doped carbon black (NC) fibers on the cathode. Benefiting from electrospinning technology, the PAN-NC fibers possess good electrolyte infiltration for fast lithium-ion transport and great flexibility for adhering on the cathode. The NC particles provide good affinity for polysufides and great conductivity. Thus, the polysulfides can be trapped on the cathode and reutilized well. As a result, the PAN-NC-coated sulfur cathode (PAN-NC@cathode) exhibits the initial discharge capacity of 1279 mAh g-1 and maintains the reversible capacity of 1030 mAh g-1 with capacity fading of 0.05% per cycle at 200 mA g-1 after 100 cycles. Adopting electrospinning to directly form fibers on the cathode shows a promising application.

  10. Freestanding graphene/MnO2 cathodes for Li-ion batteries

    Directory of Open Access Journals (Sweden)

    Şeyma Özcan

    2017-09-01

    Full Text Available Different polymorphs of MnO2 (α-, β-, and γ- were produced by microwave hydrothermal synthesis, and graphene oxide (GO nanosheets were prepared by oxidation of graphite using a modified Hummers’ method. Freestanding graphene/MnO2 cathodes were manufactured through a vacuum filtration process. The structure of the graphene/MnO2 nanocomposites was characterized using X-ray diffraction (XRD and Raman spectroscopy. The surface and cross-sectional morphologies of freestanding cathodes were investigated by scanning electron microcopy (SEM. The charge–discharge profile of the cathodes was tested between 1.5 V and 4.5 V at a constant current of 0.1 mA cm−2 using CR2016 coin cells. The initial specific capacity of graphene/α-, β-, and γ-MnO2 freestanding cathodes was found to be 321 mAhg−1, 198 mAhg−1, and 251 mAhg−1, respectively. Finally, the graphene/α-MnO2 cathode displayed the best cycling performance due to the low charge transfer resistance and higher electrochemical reaction behavior. Graphene/α-MnO2 freestanding cathodes exhibited a specific capacity of 229 mAhg−1 after 200 cycles with 72% capacity retention.

  11. Online Exhibits & Concept Maps

    Science.gov (United States)

    Douma, M.

    2009-12-01

    Presenting the complexity of geosciences to the public via the Internet poses a number of challenges. For example, utilizing various - and sometimes redundant - Web 2.0 tools can quickly devour limited time. Do you tweet? Do you write press releases? Do you create an exhibit or concept map? The presentation will provide participants with a context for utilizing Web 2.0 tools by briefly highlighting methods of online scientific communication across several dimensions. It will address issues of: * breadth and depth (e.g. from narrow topics to well-rounded views), * presentation methods (e.g. from text to multimedia, from momentary to enduring), * sources and audiences (e.g. for experts or for the public, content developed by producers to that developed by users), * content display (e.g. from linear to non-linear, from instructive to entertaining), * barriers to entry (e.g. from an incumbent advantage to neophyte accessible, from amateur to professional), * cost and reach (e.g. from cheap to expensive), and * impact (e.g. the amount learned, from anonymity to brand awareness). Against this backdrop, the presentation will provide an overview of two methods of online information dissemination, exhibits and concept maps, using the WebExhibits online museum (www.webexhibits.org) and SpicyNodes information visualization tool (www.spicynodes.org) as examples, with tips on how geoscientists can use either to communicate their science. Richly interactive online exhibits can serve to engage a large audience, appeal to visitors with multiple learning styles, prompt exploration and discovery, and present a topic’s breadth and depth. WebExhibits, which was among the first online museums, delivers interactive information, virtual experiments, and hands-on activities to the public. While large, multidisciplinary exhibits on topics like “Color Vision and Art” or “Calendars Through the Ages” require teams of scholars, user interface experts, professional writers and editors

  12. Design and fabrication of a silicon-based direct methanol fuel cell with a new cathode spoke structure

    Science.gov (United States)

    Zhang, Yufeng; Yuan, Zhenyu; Li, Yuling; Jia, Qi; Chen, Song; Liu, Xiaowei

    2011-03-01

    In this paper, a self-breathing micro direct methanol fuel cell (μDMFC) featuring a new cathode current collector with a spoke configuration is presented to improve cell performance. Simulation results show that the new spoke structure can effectively increase the efficiency of oxygen mass transport and exhibit higher pressure than the conventional perforated structure. The water transfer to the proton exchange membrane (PEM) is promoted to reduce the PEM resistance with the increase in the membrane water content. Additionally, the effects of the spoke blades on performance were evaluated to determine the optimal cathode structure. The self-breathing μDMFCs with conventional and new cathode structures were fabricated using silicon-based micro-electromechanical system (MEMS) technologies and tested at room temperature with 1 M methanol solution. The experimental results revealed that the spoke cathode structure exhibits significantly higher performance than the conventional structure, showing a substantial 30% increase in peak power density.

  13. Vacuum arc on the polycrystalline silica cathode

    Directory of Open Access Journals (Sweden)

    D. V. Duhopel'nikov

    2014-01-01

    Full Text Available Thin films of silica and its compounds are used in modern technology to produce Li-ion batteries, wear-resistant and protective coatings, thin-films insulators, etc. This coating is produced with CVD methods, with magnetron sputtering systems or with electron-beam evaporation. The vacuum arc evaporation method, presently, is not used.The paper demonstrates a possibility for a long-term operation of vacuum arc evaporator with polycrystalline silica-aluminum alloy (90% of silica cathode and with magnetic system to create a variable form of arch-like magnetic field on the cathode surface. It was shown that archlike configuration of magnetic field provides a stable discharge and uniform cathode spots moving with the velocities up to 5 m/s with magnetic fields induction about 10 mT. Thus, there is no local melting of the cathode, and this provides its long-term work without chips, cracks and destruction. Cathodes spots move over the cathode surface leaving t big craters with melted edges on its surface. The craters size was 150-450μm. The cathode spot movement character and the craters on the cathode surface were like the spots movement, when working on the copper or aluminum cathodes. With the magnetic field induction less than 1 mT, the cathode spots movement was the same as that of on the silica mono-crystal without magnetic field. Thus, the discharge volt-ampere characteristics for different values of magnetic fields were obtained. Voltampere characteristics were increasing and were shifted to the higher voltage with increasing magnetic field. The voltage was 18.7-26.5 V for the arc current 30-140 A.So, it was confirmed that vacuum arc evaporation method could be used for effective evaporation of silica and silica-based alloys and for thin films deposition of this materials.

  14. Fe-Mo alloy coatings as cathodes in chlorate production process

    Directory of Open Access Journals (Sweden)

    Gajić-Krstajić Ljiljana M.

    2016-01-01

    Full Text Available The aim of this study was to gain a better understanding of the feasibility of partial replacement of dichromate, Cr(VI, with phosphate buffer, focusing on the cathode reaction selectivity for hydrogen evolution on mild steel and Fe-Mo cathodes in undivided cell for chlorate production. To evaluate the ability of phosphate and Cr(VI additions to hinder hypochlorite and chlorate reduction, overall current efficiency (CE measurements in laboratory cell for chlorate production on stationary electrodes were performed. The concentration of hypochlorite was determined by a conventional potentiometric titration method using 0.01 mol dm-3 As2O3 solution as a titrant. The chlorate concentration was determined by excess of 1.0 mol dm-3 As2O3 solution and excess of arsenic oxide was titrated with 0.1 mol dm-3 KBrO3 solution in a strong acidic solution. Cathodic hypochlorite and chlorate reduction were suppressed efficiently by addition of 3 g dm-3 dichromate at both cathodes, except that Fe-Mo cathode exhibited higher catalytic activity for hydrogen evolution reaction (HER. The overvoltage for the HER was around 0.17 V lower on Fe-Mo cathode than on mild steel at the current density of 3 kA m-2. It was found that a dichromate content as low as 0.1 g dm-3 is sufficient for complete suppression of cathodic hypochlorite and chlorate reduction onto Fe-Mo catalyst in phosphate buffering system (3 g dm-3 Na2HPO4 + NaH2PO4. The overall current efficiency was practically the same as in the case of the presence of 3 g dm-3 dichromate buffer (98 %. However, for the mild steel cathode, the overall current efficiency for the chlorate production was somewhat lower in the above mentioned mixed phosphate + dichromate buffering system (95% than in the pure dichromate buffering solution (97.5%.

  15. Smithsonian climate change exhibits

    Science.gov (United States)

    Kumar, Mohi

    2006-05-01

    Two new museum exhibits, ``Arctic: A Friend Acting Strangely'' and ``Atmosphere: Change is in the Air'' opened 15 April at the Smithsonian Institution's National Museum of Natural History in Washington, D.C., in partnership with the U.S. National Oceanic and Atmospheric Administration, NASA, and the U.S. National Science Foundation. In ``Arctic: A Friend Acting Strangely,'' anecdotes from indigenous polar people reveal how climate changes have affected life within the last 50 years. For example, as permafrost melts and sea ice shrinks, plant distributions and animal migration patterns are changing, severely affecting culture.

  16. Ultrasonic-assisted cathodic electrochemical discharge for graphene synthesis.

    Science.gov (United States)

    Van Thanh, Dang; Oanh, Phung Phi; Huong, Do Tra; Le, Phuoc Huu

    2017-01-01

    We present a novel and highly efficient method for exfoliating of graphite to produce graphene via the synergistic effects of in-situ plasma induced electrochemical exfoliation with ultrasonic energy, called ultrasonic-assisted cathodic electrochemical discharge. This method can work at moderate temperatures without the need of acidic media or expensive ionic electrolyte. The produced graphene exhibited a large lateral dimension of approximately 6μm and a thickness of 2.5nm, corresponding to approximately seven layers of graphene. An exfoliating mechanism of graphite to produce graphene sheets is also proposed in this study. Copyright © 2016 Elsevier B.V. All rights reserved.

  17. Anniversary Exhibition. Nechvolodov.

    Directory of Open Access Journals (Sweden)

    - -

    2006-03-01

    Full Text Available On the 10th of August, 2005 in Tartu (the second biggest educational and cultural city in Estonia Stanislav Nechvolodov's exhibition was opened to show the 5-year cycle of his work, traditional for the author and his admirers. At the opening ceremony Nechvolodov said that the exhibition was the last one and appointed on his 70th anniversary.The architectural and building society in Irkutsk remembers Stanislav Nechvolodov as an architect working on dwelling and civil buildings in 1960-70s. Below are some extracts from the Estonian press.«Postimees» newspaper, December 1993. The interview «Expressionistic naturalist, conservative Nechvolodov» by journalist Eric Linnumyagi. He asks about all the details and describes the troubles experienced by Nechvolodov during the perestroika period in Estonia, for example: the Tartu University refused to install the sculpture of Socrat, the art school refused to engage him as an instructor, the sculpture of Socrat moved to Vrotzlav, Poland, and Nechvolodov moved to Poland to read lectures there.«Tartu» newspaper, November 2000. Mats Oun, artist, says in the article «Nechvolodov: a man of Renaissance»: «Nechvolodov works in Estonia, his works are placed in many local and foreign museums. Regardless some insignificant faults, he deserves a high estimation, and his manysided open exhibition can be an example for other artists. He is a man of Renaissance».

  18. Batteries: Overview of Battery Cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Doeff, Marca M

    2010-07-12

    The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as

  19. Cathodic oxygen consumption and electrically induced osteogenesis.

    Science.gov (United States)

    Brighton, C T; Adler, S; Black, J; Itada, N; Friedenberg, Z B

    1975-01-01

    Small amounts of electric current stimulate bone formation in the region of a cathode. The purpose of this experiment is to compare changes in oxygen and hydroxyl ion concentration that occur at the cathode at current levels known to be capable of inducing osteogenesis (10-20 muamps) with those changes that occur at current levels known to be toxic to bone (100 muamps). An oxygen consumption chamber containing an oxygen electrode is fitted with two stainless steel electrodes which are connected to a constant current source. At the cathode, with a current of 100 muamps, oxygen is consumed at nearly stoichiometric rates. At higher current (100 muamps) levels, cathodic oxygen consumption gives way to hydrogen evolution. Cathodic hydroxyl ion production is directly proportional to current. It is concluded from these in vitro experiments that at 10-20 muamps the oxygen tension in the vicinity of the cathode is lowered and the pH is moderately increased. At 100 muamps the oxygen tension is not lowered, but the pH is increased dramatically. If these same changes occur in the vicinity of a cathode in vivo, then lowering the local tissue oxygen tension and raising the local pH may be mechanisms operative in electrically induced bone formation.

  20. Design Of Photovoltaic Powered Cathodic Protection System

    Directory of Open Access Journals (Sweden)

    Golina Samir Adly

    2017-07-01

    Full Text Available The corrosion caused by chemical reaction between metallic structures and surrounding mediums such as soil or water .the CP cathodic protection system is used to protect metallic structure against corrosion. Cathodic protection CP used to minimize corrosion by utilizing an external source of electrical current which forces the entire structure to become a cathode. There are two Types of cathodic protection system Galvanic current Impressed current.the Galvanic current is called a sacrificial anode is connected to the protected structure cathode through a DC power supply. In Galvanic current system a current passes from the sacrificing anode to the protected structure .the sacrificial anode is corroded rather than causing the protected structure corrosion .protected structure requires a constant current to stop the corrosion which determined by area structure metal and the surrounding medium. The rains humidity are decrease soil resistivity and increase the DC current .The corrosion and over protection resulting from increase in the DC current is harmful for the metallic structure. This problem can be solved by conventional cathodic protection system by manual adjustment of DC voltage periodically to obtain a constant current .the manual adjustment of DC voltage depends on experience of the technician and using the accuracy of the measuring equipment. The errors of measuring current depend on error from the technician or error from the measuring equipment. the corrosion of structure may occur when the interval between two successive adjustment is long .An automatically regulated cathodic protection system is used to overcome problems from conventional cathodic protection system .the regulated cathodic protection system adjust the DC voltage of the system automatically when it senses the variations of surrounding medium resistivity so the DC current is constant at the required level.

  1. Cells having cathodes containing polycarbon disulfide materials

    Science.gov (United States)

    Okamoto, Yoshi; Skotheim, Terje A.; Lee, Hung S.

    1995-08-15

    The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS.sub.x).sub.n, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode.

  2. Cells having cathodes containing polycarbon disulfide materials

    Energy Technology Data Exchange (ETDEWEB)

    Okamoto, Y.; Skotheim, T.A.; Lee, H.S.

    1995-08-15

    The present invention relates to an electric current producing cell which contains an anode, a cathode having as a cathode-active material one or more carbon-sulfur compounds of the formula (CS{sub x}){sub n}, in which x takes values from 1.2 to 2.3 and n is greater or equal to 2, and where the redox process does not involve polymerization and de-polymerization by forming and breaking S--S bonds in the polymer backbone. The cell also contains an electrolyte which is chemically inert with respect to the anode and the cathode. 5 figs.

  3. 9 CFR 201.81 - Suspended registrants.

    Science.gov (United States)

    2010-01-01

    ... 201.81 Animals and Animal Products GRAIN INSPECTION, PACKERS AND STOCKYARDS ADMINISTRATION (PACKERS AND STOCKYARDS PROGRAMS), DEPARTMENT OF AGRICULTURE REGULATIONS UNDER THE PACKERS AND STOCKYARDS ACT Services § 201.81 Suspended registrants. No stockyard owner, packer, market agency, or dealer shall employ...

  4. Electrodialytic remediation of suspended mine tailings

    DEFF Research Database (Denmark)

    Hansen, Henrik K.; Rojo, Adrian; Pino, Denisse

    2008-01-01

    experiment at 40 mA, with approximately 137.5 g mine tailings on dry basis. The removal for a static (baseline) experiment only amounted 15% when passing approximately the same amount of charge through 130 g of mine tailings. The use of air bubbling to keep the tailings suspended increased the removal...

  5. Environmental toxicology: Acute effects of suspended particulate ...

    African Journals Online (AJOL)

    ... from the control values were found significant at 99% confidence level. Possible inhalatory problems are thus anticipated from prolonged accumulation of the dust in the respiratory system. KEY WORDS: Environmental toxicology, Suspended particulate matter, Dust analysis, Hematological indices, Wister albino rats. Bull.

  6. Suspended sediment concentration and particle size distribution ...

    Indian Academy of Sciences (India)

    face area, shape, minerals and source) and conse- quent interaction with heavy metal concentrations. (HMCs). Recent studies have shown a growing awareness of the wider environmental significance of the suspended sediment loads transported by rivers and streams. This includes the importance of fine grain sediment in ...

  7. Environmental toxicology: Acute effects of suspended particulate ...

    African Journals Online (AJOL)

    The elemental contents of suspended particulate matter (dust) samples from Maiduguri, Nigeria, were determined which showed appreciably high levels for especially Pb, Fe, Cu, Zn, K, Ca, and. Na. Wister albino rats were exposed to graded doses of phosphate buffered saline carried dust particles. The hematological ...

  8. A depth integrated model for suspended transport

    NARCIS (Netherlands)

    Galappatti, R.

    1983-01-01

    A new depth averaged model for suspended sediment transport in open channels has been developed based on an asymptotic solution to the two dimensional convection-diffusion equation in the vertical plane. The solution for the depth averaged concentration is derived from the bed boundary condition and

  9. The Shape of Breasts Suspended in Liquid

    NARCIS (Netherlands)

    De Kleijn, S.C.; Rensen, W.H.J.

    2007-01-01

    Philips has designed an optical mammography machine. In this machine the breast is suspended into a cup in which the measurements take place. A special fluid is inserted into the cup to prevent the light from going around the breast instead of going through it but this fluid also weakens the signal.

  10. Flow Laminarization and Acceleration by Suspended Particles

    NARCIS (Netherlands)

    Bertsch, M.; Hulshof, J.; Prostokishin, V.M.

    2015-01-01

    In [Comm. Appl. Math. Comput. Sci., 4(2009), pp. 153-175], Barenblatt presents a model for partial laminarization and acceleration of shear flows by the presence of suspended particles of different sizes, and provides a formal asymptotic analysis of the resulting velocity equation. In the present

  11. Emulsifying and Suspending Properties of Enterolobium ...

    African Journals Online (AJOL)

    Background:The thermodynamic instability of emulsions and suspensions necessitate the incorporation of emulsifiers and suspending agents respectively, in order to stabilize the formulations and ensure administration of accurate doses. Objective:Enterolobium cyclocarpum gum was characterized and evaluated for its ...

  12. IUTAM symposium on hydrodynamic diffusion of suspended particles

    Energy Technology Data Exchange (ETDEWEB)

    Davis, R.H. [ed.

    1995-12-31

    Hydrodynamic diffusion refers to the fluctuating motion of nonBrownian particles (or droplets or bubbles) which occurs in a dispersion due to multiparticle interactions. For example, in a concentrated sheared suspension, particles do not move along streamlines but instead exhibit fluctuating motions as they tumble around each other. This leads to a net migration of particles down gradients in particle concentration and in shear rate, due to the higher frequency of encounters of a test particle with other particles on the side of the test particle which has higher concentration or shear rate. As another example, suspended particles subject to sedimentation, centrifugation, or fluidization, do not generally move relative to the fluid with a constant velocity, but instead experience diffusion-like fluctuations in velocity due to interactions with neighboring particles and the resulting variation in the microstructure or configuration of the suspended particles. In flowing granular materials, the particles interact through direct collisions or contacts (rather than through the surrounding fluid); these collisions also cause the particles to undergo fluctuating motions characteristic of diffusion processes. Selected papers are indexed separately for inclusion in the Energy Science and Technology Database.

  13. 49 CFR 192.463 - External corrosion control: Cathodic protection.

    Science.gov (United States)

    2010-10-01

    ... 49 Transportation 3 2010-10-01 2010-10-01 false External corrosion control: Cathodic protection... for Corrosion Control § 192.463 External corrosion control: Cathodic protection. (a) Each cathodic protection system required by this subpart must provide a level of cathodic protection that complies with one...

  14. Carbyne Polysulfide as a Novel Cathode Material for Rechargeable Magnesium Batteries

    Directory of Open Access Journals (Sweden)

    Yanna NuLi

    2014-01-01

    Full Text Available We report the formation of carbyne polysulfide by coheating carbon containing carbyne moieties and elemental sulfur. The product is proved to have a sp2 hybrid carbon skeleton with polysulfide attached on it. The electrochemical performance of carbyne polysulfide as a novel cathode material for rechargeable magnesium batteries is firstly investigated. The material exhibits a high discharge capacity of 327.7 mAh g−1 at 3.9 mA g−1. These studies show that carbyne polysulfide is a promising candidate as cathode material for rechargeable Mg batteries if the capacity retention can be significantly improved.

  15. Carbyne polysulfide as a novel cathode material for rechargeable magnesium batteries.

    Science.gov (United States)

    NuLi, Yanna; Chen, Qiang; Wang, Weikun; Wang, Ying; Yang, Jun; Wang, Jiulin

    2014-01-01

    We report the formation of carbyne polysulfide by coheating carbon containing carbyne moieties and elemental sulfur. The product is proved to have a sp2 hybrid carbon skeleton with polysulfide attached on it. The electrochemical performance of carbyne polysulfide as a novel cathode material for rechargeable magnesium batteries is firstly investigated. The material exhibits a high discharge capacity of 327.7 mAh g(-1) at 3.9 mA g(-1). These studies show that carbyne polysulfide is a promising candidate as cathode material for rechargeable Mg batteries if the capacity retention can be significantly improved.

  16. Reservoir Scandate Cathode for Electric Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to combine two revolutionary cathode technologies into a single device for use in electric space propulsion. This will overcome problems that both...

  17. Triphenyl borate as a bi-functional additive to improve surface stability of Ni-rich cathode material

    Science.gov (United States)

    Yim, Taeeun; Jang, Seol Heui; Han, Young-Kyu

    2017-12-01

    Nickel-rich cathode material has received marked attention as an advanced cathode material, however, its inferior surface property limits the achievement of high performance in lithium-ion batteries. We propose the use of a bi-functional additive of triphenyl borate (TPB) for improvement of the safety and electrochemical performance of Ni-rich cathode materials. First, TPB removes residual lithium species from the Ni-rich cathode surface via chemical binding with anion part of residual lithium species, and effectively reduces swelling behavior of the cell. Second, TPB creates effective cathode-electrolyte interphase (CEI) layers on the electrode surface by an electrochemical reaction, and greatly enhances the surface stability of the nickel-rich cathode. This work demonstrate that a cell cycled with the TPB additive exhibits a remarkable retention of 88.6% at 60 °C after 100 cycles for an NCM721 cathode material. We suggest a working mechanism for TPB based on systematic analyses, including in-situ and ex-situ experiments.

  18. Co-Flow Hollow Cathode Technology

    Science.gov (United States)

    Hofer, Richard R.; Goebel, Dan M.

    2011-01-01

    Hall thrusters utilize identical hollow cathode technology as ion thrusters, yet must operate at much higher mass flow rates in order to efficiently couple to the bulk plasma discharge. Higher flow rates are necessary in order to provide enough neutral collisions to transport electrons across magnetic fields so that they can reach the discharge. This higher flow rate, however, has potential life-limiting implications for the operation of the cathode. A solution to the problem involves splitting the mass flow into the hollow cathode into two streams, the internal and external flows. The internal flow is fixed and set such that the neutral pressure in the cathode allows for a high utilization of the emitter surface area. The external flow is variable depending on the flow rate through the anode of the Hall thruster, but also has a minimum in order to suppress high-energy ion generation. In the co-flow hollow cathode, the cathode assembly is mounted on thruster centerline, inside the inner magnetic core of the thruster. An annular gas plenum is placed at the base of the cathode and propellant is fed throughout to produce an azimuthally symmetric flow of gas that evenly expands around the cathode keeper. This configuration maximizes propellant utilization and is not subject to erosion processes. External gas feeds have been considered in the past for ion thruster applications, but usually in the context of eliminating high energy ion production. This approach is adapted specifically for the Hall thruster and exploits the geometry of a Hall thruster to feed and focus the external flow without introducing significant new complexity to the thruster design.

  19. Preventing Corrosion by Controlling Cathodic Reaction Kinetics

    Science.gov (United States)

    2016-03-25

    Preventing corrosion by controlling cathodic reaction kinetics Progress Report for Period: 1 SEP 2015-31 MAR 2016 John Keith Department of...25 March 2016 Preventing corrosion by controlling cathodic reaction kinetics Annual Summary Report: FY16 PI: John Keith, 412-624-7016,jakeith...elements on the kinetics of oxygen reduction reaction catalyzed on titanium oxide in order to develop new approaches for controlling galvanic corrosion

  20. Energy content of suspended detritus from Arabian Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Krishnakumari, L.; Sumitra-Vijayaraghavan; Royan, J.P.

    Energy components of suspended matter included phytoplankton, zooplankton and detritus inclusive of microorganisms adsorbed to detritus. Of these, detritus contributed most of the energy (98%). The average caloric content of suspended detritus...

  1. Development of plasma cathode electron guns

    Science.gov (United States)

    Oks, Efim M.; Schanin, Peter M.

    1999-05-01

    The status of experimental research and ongoing development of plasma cathode electron guns in recent years is reviewed, including some novel upgrades and applications to various technological fields. The attractiveness of this kind of e-gun is due to its capability of creating high current, broad or focused beams, both in pulsed and steady-state modes of operation. An important characteristic of the plasma cathode electron gun is the absence of a thermionic cathode, a feature which leads to long lifetime and reliable operation even in the presence of aggressive background gas media and at fore-vacuum gas pressure ranges such as achieved by mechanical pumps. Depending on the required beam parameters, different kinds of plasma discharge systems can be used in plasma cathode electron guns, such as vacuum arcs, constricted gaseous arcs, hollow cathode glows, and two kinds of discharges in crossed E×B fields: Penning and magnetron. At the present time, plasma cathode electron guns provide beams with transverse dimension from fractional millimeter up to about one meter, beam current from microamperes to kiloamperes, beam current density up to about 100 A/cm2, pulse duration from nanoseconds to dc, and electron energy from several keV to hundreds of keV. Applications include electron beam melting and welding, surface treatment, plasma chemistry, radiation technologies, laser pumping, microwave generation, and more.

  2. The suspended sentence in French Criminal Law

    Directory of Open Access Journals (Sweden)

    Jovašević Dragan

    2016-01-01

    Full Text Available From the ancient times until today, criminal law has provided different criminal sanctions as measures of social control. These coercive measures are imposed on the criminal offender by the competent court and aimed at limitting the offender's rights and freedoms or depriving the offender of certain rights and freedoms. These sanctions are applied to the natural or legal persons who violate the norms of the legal order and injure or endanger other legal goods that enjoy legal protection. In order to effectively protect social values, criminal legislations in all countries predict a number of criminal sanctions. These are: 1 imprisonment, 2 precautions, 3 safety measures, 4 penalties for juveniles, and 5 sanctions for legal persons. Apart and instead of punishment, warning measures have a significant role in the jurisprudence. Since they emerged in the early 20th century in the system of criminal sanctions, there has been an increase in their application to criminal offenders, especially when it comes to first-time offenders who committed a negligent or accidental criminal act. Warnings are applied in case of crimes that do not have serious consequences, and whose perpetrators are not hardened and incorrigible criminals. All contemporary criminal legislations (including the French legilation provide a warning measure of suspended sentence. Suspended sentence is a conditional stay of execution of sentence of imprisonment for a specified time, provided that the convicted person does not commit another criminal offense and fulfills other obligations. This sanction applies if the following two conditions are fulfilled: a forma! -which is attached to the sentence of imprisonment; and b material -which is the court assessment that the application of this sanction is justified and necessary in a particular case. In many modern criminal legislations, there are two different types of suspended (conditional sentence: 1 ordinary (classical suspended

  3. A Delicately Designed Sulfide Graphdiyne Compatible Cathode for High-Performance Lithium/Magnesium-Sulfur Batteries.

    Science.gov (United States)

    Du, Huiping; Zhang, Zhonghua; He, Jianjiang; Cui, Zili; Chai, Jingchao; Ma, Jun; Yang, Ze; Huang, Changshui; Cui, Guanglei

    2017-11-01

    Novel sulfur cathodes hold the key to the development of metal-sulfur batteries, the promising candidate of next-generation high-energy-storage systems. Herein, a fascinating sulfur cathode based on sulfide graphdiyne (SGDY) is designed with a unique structure, which is composed of a conducting carbon skeleton with high Li+ mobility and short sulfur energy-storing unites. The SGDY cathode can essentially avoid polysulfide dissolution and be compatible with commercially available carbonate-based electrolytes and Grignard reagent-based electrolytes (all phenyl complex (APC) type electrolytes). Both the assembled Li-S and Mg-S batteries exhibit excellent electrochemical performances including large capacity, superior rate capability, high capacity retention, and high Coulombic efficiency. More importantly, this is the first implementation case of a reliable Mg-S system based on nucleophilic APC electrolytes. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  4. ZnO nanowires grown on carbon cloth for flexible cold cathode.

    Science.gov (United States)

    Tang, Haoying; Liu, Tengjiao; Jiang, Peng

    2013-02-01

    Nanostructures grown on carbon cloth are recently attracted great interests for flexible field emitter and cold cathode. In this paper, we report high-aspect ratio ZnO nanowires grown on carbon cloth by a low-temperature solution chemical approach that can be used as a flexible and high performance cold cathode. The carbon cloth is covered by outward-grown ZnO nanowires uniformly and densely with spiny structures. The hybrid structures exhibits a turn-on electrical field of 4.36 V/microm and a field enhancement factor of 1157, which benefit from the high-aspect ratios of both ZnO nanowires and carbon cloth. These results demonstrate a low cost and scalable approach for flexible cold cathode lighting and field emission display.

  5. Microstructural studies on degradation of interface between LSM–YSZ cathode and YSZ electrolyte in SOFCs

    DEFF Research Database (Denmark)

    Liu, Yi-Lin; Hagen, Anke; Barfod, Rasmus

    2009-01-01

    The changes in the cathode/electrolyte interface microstructure have been studied on anode-supported technological solid oxide fuel cells (SOFCs) that were subjected to long-term (1500 h) testing at 750 °C under high electrical loading (a current density of 0.75 A/cm2). These cells exhibit...... different cathode degradation rates depending on, among others, the composition of the cathode gas, being significantly smaller in oxygen than in air. FE-SEM and high resolution analytical TEM were applied for characterization of the interface on a submicron- and nano-scale. The interface degradation has...... that in the cell tested in air this mechanism contributes to an estimated overall reduction in the LSM coverage and the TPB length by 50 and 30%, respectively. For the cell tested in oxygen the corresponding values are 10 and 4%. Secondly, in the cell tested in air the LSM coverage and the TPB length appear...

  6. Nonactivated and Activated Biochar Derived from Bananas as Alternative Cathode Catalyst in Microbial Fuel Cells

    Directory of Open Access Journals (Sweden)

    Haoran Yuan

    2014-01-01

    Full Text Available Nonactivated and activated biochars have been successfully prepared by bananas at different thermotreatment temperatures. The activated biochar generated at 900°C (Biochar-act900 exhibited improved oxygen reduction reaction (ORR and oxygen evolution reaction (OER performances in alkaline media, in terms of the onset potential and generated current density. Rotating disk electron result shows that the average of 2.65 electrons per oxygen molecule was transferred during ORR of Biochar-act900. The highest power density of 528.2 mW/m2 and the maximum stable voltage of 0.47 V were obtained by employing Biochar-act900 as cathode catalyst, which is comparable to the Pt/C cathode. Owning to these advantages, it is expected that the banana-derived biochar cathode can find application in microbial fuel cell systems.

  7. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    Energy Technology Data Exchange (ETDEWEB)

    Harlan U. Anderson; Fatih Dogan; Vladimir Petrovsky

    2003-03-31

    This report represents a summary of the work carried out on this project which started October 1999 and ended March 2003. A list of the publications resulting from the work are contained in Appendix A. The most significant achievements are: (1) Dense nanocrystalline zirconia and ceria films were obtained at temperatures < 400 C. (2) Nanocrystalline films of both ceria and zirconia were characterized. (3) We showed that under anodic conditions 0.5 to 1 micron thick nanocrystalline films of Sc doped zirconia have sufficient electronic conductivity to prevent them from being useful as an electrolyte. (4) We have developed a process by which dense 0.5 to 5 micron thick dense films of either YSZ or ceria can be deposited on sintered porous substrates which serve as either the cathode or anode at temperatures as low as 400 C. (5) The program has provided the research to produce two PhD thesis for students, one is now working in the solid oxide fuel cell field. (6) The results of the research have resulted in 69 papers published, 3 papers submitted or being prepared for publication, 50 oral presentations and 3 patent disclosures.

  8. Outgassing rate analysis of a velvet cathode and a carbon fiber cathode

    Science.gov (United States)

    Li, An-Kun; Fan, Yu-Wei; Qian, Bao-Liang; Zhang, Zi-cheng; Xun, Tao

    2017-11-01

    In this paper, the outgassing-rates of a carbon fiber array cathode and a polymer velvet cathode are tested and discussed. Two different methods of measurements are used in the experiments. In one scheme, a method based on dynamic equilibrium of pressure is used. Namely, the cathode works in the repetitive mode in a vacuum diode, a dynamic equilibrium pressure would be reached when the outgassing capacity in the chamber equals the pumping capacity of the pump, and the outgassing rate could be figured out according to this equilibrium pressure. In another scheme, a method based on static equilibrium of pressure is used. Namely, the cathode works in a closed vacuum chamber (a hard tube), and the outgassing rate could be calculated from the pressure difference between the pressure in the chamber before and after the work of the cathode. The outgassing rate is analyzed from the real time pressure evolution data which are measured using a magnetron gauge in both schemes. The outgassing rates of the carbon fiber array cathode and the velvet cathode are 7.3 ± 0.4 neutrals/electron and 85 ± 5 neutrals/electron in the first scheme and 9 ± 0.5 neutrals/electron and 98 ± 7 neutrals/electron in the second scheme. Both the results of two schemes show that the outgassing rate of the carbon fiber array cathode is an order smaller than that of the velvet cathode under similar conditions, which shows that this carbon fiber array cathode is a promising replacement of the velvet cathode in the application of magnetically insulated transmission line oscillators and relativistic magnetrons.

  9. Estimating total suspended sediment yield with probability sampling

    Science.gov (United States)

    Robert B. Thomas

    1985-01-01

    The ""Selection At List Time"" (SALT) scheme controls sampling of concentration for estimating total suspended sediment yield. The probability of taking a sample is proportional to its estimated contribution to total suspended sediment discharge. This procedure gives unbiased estimates of total suspended sediment yield and the variance of the...

  10. Improving the flexibility of microbial desalination cells through spatially decoupling anode and cathode.

    Science.gov (United States)

    Ping, Qingyun; He, Zhen

    2013-09-01

    To improve the flexibility of microbial desalination cell (MDC) construction and operation, a new configuration with decoupled anode and cathode was developed and examined in this study. A higher salt concentration resulted in higher current generation, as well as a higher salt removal rate. The effect of the distance between the anode and the cathode on the MDC performance was not obvious, likely due to a sufficient conductivity in the salt solution. Because the cathode was identified as a limiting factor, adding one more cathode unit increased the current generation from 72.3 to 116.0 A/m(3), while installing additional anode units did not obviously alter the MDC current production. Changing the position of the anode/cathode units exhibited a weak influence on the MDC performance. Parallel connection of electrical circuits generally produced more current than the individual connections, and a strong competition was observed between multiple units sharing the same opposite unit. Copyright © 2013 Elsevier Ltd. All rights reserved.

  11. Nickel-based electrodeposits as potential cathode catalysts for hydrogen production by microbial electrolysis

    Science.gov (United States)

    Mitov, M.; Chorbadzhiyska, E.; Nalbandian, L.; Hubenova, Y.

    2017-07-01

    The development of cost-effective cathodes, operating at neutral pH and ambient temperatures, is a crucial challenge for the practical application of microbial electrolysis cell (MEC) technology. In this study, NiW and NiMo co-deposits produced by electroplating on Ni-foam are explored as cathodes in MEC. The fabricated electrodes exhibit higher corrosion stability and enhanced electrocatalytic activity towards hydrogen evolution reaction in neutral electrolyte compared to the bare Ni-foam. NiW/Ni-foam electrodes possess six times higher intrinsic catalytic activity, estimated from data obtained by linear voltammetry and chronoamperometry. The newly developed electrodes are applied as cathodes in single-chamber membrane-free MEC reactors, inoculated with wastewater and activated sludge from a municipal wastewater treatment plant. Cathodic hydrogen recovery of 79% and 89% by using NiW and NiMo cathodes, respectively, is achieved at applied voltage of 0.6 V. The obtained results reveal potential for practical application of used catalysts in MEC.

  12. AFM as an analysis tool for high-capacity sulfur cathodes for Li–S batteries

    Directory of Open Access Journals (Sweden)

    Renate Hiesgen

    2013-10-01

    Full Text Available In this work, material-sensitive atomic force microscopy (AFM techniques were used to analyse the cathodes of lithium–sulfur batteries. A comparison of their nanoscale electrical, electrochemical, and morphological properties was performed with samples prepared by either suspension-spraying or doctor-blade coating with different binders. Morphological studies of the cathodes before and after the electrochemical tests were performed by using AFM and scanning electron microscopy (SEM. The cathodes that contained polyvinylidene fluoride (PVDF and were prepared by spray-coating exhibited a superior stability of the morphology and the electric network associated with the capacity and cycling stability of these batteries. A reduction of the conductive area determined by conductive AFM was found to correlate to the battery capacity loss for all cathodes. X-ray diffraction (XRD measurements of Li2S exposed to ambient air showed that insulating Li2S hydrolyses to insulating LiOH. This validates the significance of electrical ex-situ AFM analysis after cycling. Conductive tapping mode AFM indicated the existence of large carbon-coated sulfur particles. Based on the analytical findings, the first results of an optimized cathode showed a much improved discharge capacity of 800 mA·g(sulfur−1 after 43 cycles.

  13. Optomechanics for thermal characterization of suspended graphene

    Science.gov (United States)

    Dolleman, Robin J.; Houri, Samer; Davidovikj, Dejan; Cartamil-Bueno, Santiago J.; Blanter, Yaroslav M.; van der Zant, Herre S. J.; Steeneken, Peter G.

    2017-10-01

    The thermal response of graphene is expected to be extremely fast due to its low heat capacity and high thermal conductivity. In this work, the thermal response of suspended single-layer graphene membranes is investigated by characterization of their mechanical motion in response to a high-frequency modulated laser. A characteristic delay time τ between the optical intensity and mechanical motion is observed, which is attributed to the time required to raise the temperature of the membrane. We find, however, that the measured time constants are significantly larger than the predicted ones based on values of the specific heat and thermal conductivity. In order to explain the discrepancy between measured and modeled τ , a model is proposed that takes a thermal boundary resistance at the edge of the graphene drum into account. The measurements provide a noninvasive way to characterize thermal properties of suspended atomically thin membranes, providing information that can be hard to obtain by other means.

  14. Sedimentation of suspended solids in ultrasound field

    Directory of Open Access Journals (Sweden)

    Vikulina Vera

    2018-01-01

    Full Text Available Physical and chemical effects of aquatic environment that occur in an ultrasonic field change the sedimentation rate of coagulated suspension. This might only happen in case of cavitation of ultrasonic filed that causes a change of potentials of the medium. Research of the influence of ultrasonic vibrations on coagulation of suspended solids within water purification allows expanding their scope of implementation. The objective of the research is to estimate the effect of ultrasound on the sedimentation of the suspended solids, to determine of the efficiency of the process in relation to the dose of the coagulant, and to calculate the numerical values of the constants in the theoretical equation. The experiment condition was held in the water with the clay substances before the introduction of the coagulant. The method of magnetostriction ultrasonic generator was applied to receive ultrasonic vibration. Estimate of concentration of clay particles in water was performed using photometry. As a result of the research, the obtained data allow determining the increase in efficiency of suspended particles sedimentation related to the dose of coagulant, depending on time of ultrasonic treatment. The experiments confirmed the connection between the effect of sedimentation in the coagulation process, the coagulant dose and the time of scoring. Studies have shown that the increase in the duration of ultrasonic treatment causes a decrease of administered doses of coagulant.

  15. Suspended sediments limit coral sperm availability

    Science.gov (United States)

    Ricardo, Gerard F.; Jones, Ross J.; Clode, Peta L.; Humanes, Adriana; Negri, Andrew P.

    2015-01-01

    Suspended sediment from dredging activities and natural resuspension events represent a risk to the reproductive processes of coral, and therefore the ongoing maintenance of reefal populations. To investigate the underlying mechanisms that could reduce the fertilisation success in turbid water, we conducted several experiments exposing gametes of the corals Acropora tenuis and A. millepora to two sediment types. Sperm limitation was identified in the presence of siliciclastic sediment (230 and ~700 mg L−1), with 2–37 fold more sperm required to achieve maximum fertilisation rates, when compared with sediment-free treatments. This effect was more pronounced at sub-optimum sperm concentrations. Considerable (>45%) decreases in sperm concentration at the water’s surface was recorded in the presence of siliciclastic sediment and a >20% decrease for carbonate sediment. Electron microscopy then confirmed sediment entangled sperm and we propose entrapment and sinking is the primary mechanism reducing sperm available to the egg. Longer exposure to suspended sediments and gamete aging further decreased fertilisation success when compared with a shorter exposure. Collectively, these findings demonstrate that high concentrations of suspended sediments effectively remove sperm from the water’s surface during coral spawning events, reducing the window for fertilisation with potential subsequent flow-on effects for recruitment. PMID:26659008

  16. Compact Rare Earth Emitter Hollow Cathode

    Science.gov (United States)

    Watkins, Ronald; Goebel, Dan; Hofer, Richard

    2010-01-01

    A compact, high-current, hollow cathode utilizing a lanthanum hexaboride (LaB6) thermionic electron emitter has been developed for use with high-power Hall thrusters and ion thrusters. LaB6 cathodes are being investigated due to their long life, high current capabilities, and less stringent xenon purity and handling requirements compared to conventional barium oxide (BaO) dispenser cathodes. The new cathode features a much smaller diameter than previously developed versions that permit it to be mounted on axis of a Hall thruster ( internally mounted ), as opposed to the conventional side-mount position external to the outer magnetic circuit ("externally mounted"). The cathode has also been reconfigured to be capable of surviving vibrational loads during launch and is designed to solve the significant heater and materials compatibility problems associated with the use of this emitter material. This has been accomplished in a compact design with the capability of high-emission current (10 to 60 A). The compact, high-current design has a keeper diameter that allows the cathode to be mounted on the centerline of a 6- kW Hall thruster, inside the iron core of the inner electromagnetic coil. Although designed for electric propulsion thrusters in spacecraft station- keeping, orbit transfer, and interplanetary applications, the LaB6 cathodes are applicable to the plasma processing industry in applications such as optical coatings and semiconductor processing where reactive gases are used. Where current electrical propulsion thrusters with BaO emitters have limited life and need extremely clean propellant feed systems at a significant cost, these LaB6 cathodes can run on the crudest-grade xenon propellant available without impact. Moreover, in a laboratory environment, LaB6 cathodes reduce testing costs because they do not require extended conditioning periods under hard vacuum. Alternative rare earth emitters, such as cerium hexaboride (CeB6) can be used in this

  17. Improved cathode materials for microbial electrosynthesis

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, T; Nie, HR; Bain, TS; Lu, HY; Cui, MM; Snoeyenbos-West, OL; Franks, AE; Nevin, KP; Russell, TP; Lovley, DR

    2013-01-01

    Microbial electrosynthesis is a promising strategy for the microbial conversion of carbon dioxide to transportation fuels and other organic commodities, but optimization of this process is required for commercialization. Cathodes which enhance electrode-microbe electron transfer might improve rates of product formation. To evaluate this possibility, biofilms of Sporomusa ovata, which are effective in acetate electrosynthesis, were grown on a range of cathode materials and acetate production was monitored over time. Modifications of carbon cloth that resulted in a positive-charge enhanced microbial electrosynthesis. Functionalization with chitosan or cyanuric chloride increased acetate production rates 6-7 fold and modification with 3-aminopropyltriethoxysilane gave rates 3-fold higher than untreated controls. A 3-fold increase in electrosynthesis over untreated carbon cloth cathodes was also achieved with polyaniline cathodes. However, not all strategies to provide positively charged surfaces were successful, as treatment of carbon cloth with melamine or ammonia gas did not stimulate acetate electrosynthesis. Treating carbon cloth with metal, in particular gold, palladium, or nickel nanoparticles, also promoted electrosynthesis, yielding electrosynthesis rates that were 6-,4.7- or 4.5-fold faster than the untreated control, respectively. Cathodes comprised of cotton or polyester fabric treated with carbon nanotubes yielded cathodes that supported acetate electrosynthesis rates that were similar to 3-fold higher than carbon cloth controls. Recovery of electrons consumed in acetate was similar to 80% for all materials. The results demonstrate that one approach to increase rates of carbon dioxide reduction in microbial electrosynthesis is to modify cathode surfaces to improve microbe-electrode interactions.

  18. A High Capacity Li-Ion Cathode: The Fe(III/VI Super-Iron Cathode

    Directory of Open Access Journals (Sweden)

    Stuart Licht

    2010-05-01

    Full Text Available A super-iron Li-ion cathode with a 3-fold higher reversible capacity (a storage capacity of 485 mAh/g is presented. One of the principle constraints to vehicle electrification is that the Li-ion cathode battery chemistry is massive, and expensive. Demonstrated is a 3 electron storage lithium cathodic chemistry, and a reversible Li super-iron battery, which has a significantly higher capacity than contemporary Li-ion batteries. The super-iron Li-ion cathode consists of the hexavalent iron (Fe(VI salt, Na2FeO4, and is formed from inexpensive and clean materials. The charge storage mechanism is fundamentally different from those of traditional lithium ion intercalation cathodes. Instead, charge storage is based on multi-electron faradaic reduction, which considerably enhances the intrinsic charge storage capacity.

  19. Nanostructured LnBaCo2O6− (Ln = Sm, Gd with layered structure for intermediate temperature solid oxide fuel cell cathodes

    Directory of Open Access Journals (Sweden)

    Augusto E. Mejía Gómez

    2017-04-01

    Full Text Available In this work, we present the combination of two characteristics that are beneficial for solid oxide fuel cell (SOFC cathodic performance in one material. We developed and evaluated for the first time nanostructured layered perovskites of formulae LnBaCo2O6-d with Ln = Sm and Gd (SBCO and GBCO, respectively as SOFC cathodes, finding promising electrochemical properties in the intermediate temperature range. We obtained those nanostructures by using porous templates to confine the chemical reagents in regions of 200-800 nm. The performance of nanostructured SBCO and GBCO cathodes was analyzed by electrochemical impedance spectroscopy technique under different operating conditions using Gd2O3-doped CeO2 as electrolyte. We found that SBCO cathodes displayed lower area-specific resistance than GBCO ones, because bulk diffusion of oxide ions is enhanced in the former. We also found that cathodes synthesized using smaller template pores exhibited better performance.

  20. Influence of cathode geometry on electron dynamics in an ultrafast electron microscope

    Directory of Open Access Journals (Sweden)

    Shaozheng Ji

    2017-09-01

    Full Text Available Efforts to understand matter at ever-increasing spatial and temporal resolutions have led to the development of instruments such as the ultrafast transmission electron microscope (UEM that can capture transient processes with combined nanometer and picosecond resolutions. However, analysis by UEM is often associated with extended acquisition times, mainly due to the limitations of the electron gun. Improvements are hampered by tradeoffs in realizing combinations of the conflicting objectives for source size, emittance, and energy and temporal dispersion. Fundamentally, the performance of the gun is a function of the cathode material, the gun and cathode geometry, and the local fields. Especially shank emission from a truncated tip cathode results in severe broadening effects and therefore such electrons must be filtered by applying a Wehnelt bias. Here we study the influence of the cathode geometry and the Wehnelt bias on the performance of a photoelectron gun in a thermionic configuration. We combine experimental analysis with finite element simulations tracing the paths of individual photoelectrons in the relevant 3D geometry. Specifically, we compare the performance of guard ring cathodes with no shank emission to conventional truncated tip geometries. We find that a guard ring cathode allows operation at minimum Wehnelt bias and improve the temporal resolution under realistic operation conditions in an UEM. At low bias, the Wehnelt exhibits stronger focus for guard ring than truncated tip cathodes. The increase in temporal spread with bias is mainly a result from a decrease in the accelerating field near the cathode surface. Furthermore, simulations reveal that the temporal dispersion is also influenced by the intrinsic angular distribution in the photoemission process and the initial energy spread. However, a smaller emission spot on the cathode is not a dominant driver for enhancing time resolution. Space charge induced temporal broadening

  1. Influence of cathode geometry on electron dynamics in an ultrafast electron microscope

    Science.gov (United States)

    Ji, Shaozheng; Piazza, Luca; Cao, Gaolong; Park, Sang Tae; Reed, Bryan W.; Masiel, Daniel J.; Weissenrieder, Jonas

    2017-01-01

    Efforts to understand matter at ever-increasing spatial and temporal resolutions have led to the development of instruments such as the ultrafast transmission electron microscope (UEM) that can capture transient processes with combined nanometer and picosecond resolutions. However, analysis by UEM is often associated with extended acquisition times, mainly due to the limitations of the electron gun. Improvements are hampered by tradeoffs in realizing combinations of the conflicting objectives for source size, emittance, and energy and temporal dispersion. Fundamentally, the performance of the gun is a function of the cathode material, the gun and cathode geometry, and the local fields. Especially shank emission from a truncated tip cathode results in severe broadening effects and therefore such electrons must be filtered by applying a Wehnelt bias. Here we study the influence of the cathode geometry and the Wehnelt bias on the performance of a photoelectron gun in a thermionic configuration. We combine experimental analysis with finite element simulations tracing the paths of individual photoelectrons in the relevant 3D geometry. Specifically, we compare the performance of guard ring cathodes with no shank emission to conventional truncated tip geometries. We find that a guard ring cathode allows operation at minimum Wehnelt bias and improve the temporal resolution under realistic operation conditions in an UEM. At low bias, the Wehnelt exhibits stronger focus for guard ring than truncated tip cathodes. The increase in temporal spread with bias is mainly a result from a decrease in the accelerating field near the cathode surface. Furthermore, simulations reveal that the temporal dispersion is also influenced by the intrinsic angular distribution in the photoemission process and the initial energy spread. However, a smaller emission spot on the cathode is not a dominant driver for enhancing time resolution. Space charge induced temporal broadening shows a close to

  2. The influence of cathode excavation of cathodic arc evaporator on thickness uniformity and erosion products angle distribution

    Directory of Open Access Journals (Sweden)

    D. V. Duhopel'nikov

    2014-01-01

    Full Text Available Cathodic arc evaporators are used for coating with functional films. Prolonged or buttend evaporators may be used for this purposes. In butt-end evaporator the cathode spots move continuously on the cathode work surface and evaporate cathode material. High depth excavation profile forms on the cathode work surface while the thick coating precipitation (tens or hundreds of microns. The cathode excavation profile is shaped like a “cup” with high walls for electrostatic discharge stabilization systems with axial magnetic fields. Cathode spots move on the bottom of the “cup”. It is very likely that high “cup” walls are formed as a result of lasting work time influence on the uniformity of precipitated films.In the present work the influence of excavation profile walls height on the uniformity of precipitated coating was carried out. The high profile walls are formed due to lasting work of DC vacuum arc evaporator. The cathode material used for tests was 3003 aluminum alloy. The extended substrate was placed parallel to the cathode work surface. Thickness distribution along the substrate length with the new cathode was obtained after 6 hours and after 12 hours of continuous operation.The thickness distribution of precipitated coating showed that the cathode excavation has an influence on the angular distribution of the matter escaping the cathode. It can be clearly seen from the normalized dependence coating thickness vs the distance from the substrate center. Also the angular distribution of the matter flow from the cathode depending on the cathode working time was obtained. It was shown that matter flow from the cathode differs from the LambertKnudsen law. The more the cathode excavation the more this difference.So, cathode excavation profile has an influence on the uniformity of precipitated coating and it is necessary to take in account the cathode excavation profile while coating the thick films.

  3. Against the Odds Exhibition Opens

    Science.gov (United States)

    ... Issue Past Issues Special Section Against the Odds Exhibition Opens Past Issues / Spring 2008 Table of Contents / ... April 17, Dr. Donald Lindberg officially opened the exhibition, "Against the Odds: Making a Difference in Global ...

  4. Exhibition

    CERN Multimedia

    Staff Association

    2014-01-01

    Energie sombre, matière noire J.-J. Dalmais - J. Maréchal Du 11 au 27 novembre 2014, CERN Meyrin, Bâtiment principal A l’image des particules atomiques qui ont tissé des liens pour créer la matière, deux artistes haut bugistes croisent leurs regards et conjuguent leurs expressions singulières pour faire naître une vision commune de l’univers, produit des forces primordiales. Les sculptures de Jean-Jacques Dalmais et les peintures de Jacki Maréchal se rencontrent pour la première fois et se racontent par un enrichissement mutuel la belle histoire de la Vie. Dialogue magique des œuvres en mouvement qui questionnent en écho l’énergie sombre et la matière noire. Cette harmonieuse confluence de jeux de miroir et de résonnance illumine de poésie et de sobriété l’espace expos&...

  5. Exhibition

    CERN Multimedia

    Staff Association

    2016-01-01

    The Elementary Particles of Painting Alfonso Fratteggiani Bianchi and Ermanno Imbergamo From September 26 to October 7, 2016 CERN Meyrin, Main Building With intentions similar to those of CERN physicists, the artist Alfonso Fratteggiani Bianchi investigates the color pigment, studying its interaction with light and with the support on which it is deposited. He creates monochrome paintings by spreading the color pigment in the pure state on stones, without using glue or any other type of adhesive. With intentions similar to artists, the physicist Ermanno Imbergamo investigates the use of luminescent wavelength shifters, materials commonly used in Particle Physics, for art. He creates other monochrome artworks, which disclose further aspects of interaction among light, color pigments and support. For more information: staff.association@cern.ch | Tel: 022 767 28 19

  6. Exhibition

    CERN Document Server

    Staff Association

    2018-01-01

    Cosmos KOLI Du 15 au 26 janvier 2018 CERN Meyrin, Main Building (Nébuleuse d'Orion- KOLI) KOLI, Artiste confirmé, diplômé de l’Académie de Beaux Arts de Tirana, depuis 26 ans en Suisse, où il a participé à maintes expositions collectives et organisé 10 expositions privées avec  beaucoup de succès, s’exprime actuellement dans un bonheur de couleur et de matières qui côtoient des hautes sphères… le cosmos ! Gagnant d’un premier prix lors d’une exposition collective organisée par le consulat Italien, il s’est installé au bord du lac dans le canton de Vaud où il vit depuis maintenant déjà 13 ans. www.kolicreation.com Pour plus d’informations et demandes d’accès : staff.association@cern.ch | T&eacut...

  7. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    La couleur des jours oriSio Du 2 au 12 mai 2017 CERN Meyrin, Bâtiment principal oriSio - Motus Suite à un fort intérêt pour la Chine et une curiosité pour un médium très ancien, la laque ! Je réinterprète cet art à travers un style abstrait. Je présente ici des laques sur aluminium, travaillés au plasma et ensuite colorés à l’aide de pigments pour l’essentiel. Mes œuvres je les veux brutes, déchirées, évanescentes, gondolées, voire trouées mais avec une belle approche de profondeur de la couleur.   Pour plus d’informations : staff.association@cern.ch | Tél: 022 766 37 38

  8. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Still Life Jérémy Bajulaz Du 25 septembre au 6 octobre 2017 CERN Meyrin, Main Building (Aubergine - Jérémy Bajulaz) Né en 1991 en Haute-Savoie, France. Diplômé de l'Ecole Emile Cohl à Lyon, Jérémy Bajulaz intègre en 2014 le programme d'artiste en résidence au Centre Genevois de Gravure Contemporaine. C'est là que son travail prendra corps, autour de la lumière et de ses vibrations aux travers de sujets comme le portrait et la nature morte, dans le souci de l'observation; le regard prenant une place importante dans le processus créatif. Lauréat 2017 du VII Premio AAAC, son travail a été présenté dans de nombreuses expositions collectives, en 2015 au Bâtiment d’Art Contemporain de Genève, en 2016 au 89e Salon de Lyon et du ...

  9. Exhibition

    CERN Multimedia

    Staff Association

    2016-01-01

    La mosaïque ou quand détruire permet de construire Lauren Decamps Du 28 novembre au 9 décembre 2016 CERN Meyrin, Bâtiment principal Paysage d'Amsterdam - Lauren Decamps On ne doit jamais rien détruire qu'on ne soit sûr de pouvoir remplacer aussi avantageusement " écrivait Plutarque dans ses Œuvres morales du 1er siècle après JC. L'artiste mosaïste Lauren Decamps adhère à cette idée et tente à sa manière de donner une nouvelle vie à ses matériaux en les taillant puis les réassemblant, créant ainsi des œuvres abstraites et figuratives.

  10. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Firmament des toiles Joëlle Lalagüe Du 6 au 16 juin 2017 CERN Meyrin, Bâtiment principal Phylaë Voyage - Joëlle Lalagüe. Each picture is an invitation for a cosmic trip. This is a whispering of soul, which comes from origins. A symphony of the world, some notes of love, a harmony for us to fly to infinity. Pour plus d’informations et demandes d'accès : staff.association@cern.ch | Tél: 022 766 37 38

  11. Exhibition

    CERN Multimedia

    Staff Association

    2016-01-01

    COLORATION Sandra Duchêne From September 5 to 16, 2016 CERN Meyrin, Main Building La recherche de l’Universel. Après tout ! C’est de l’Amour ! What else to say ? …La couleur, l’ENERGIE de la vie…

  12. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Le Point Isabelle Gailland Du 20 février au 3 mars 2017 CERN Meyrin, Bâtiment principal La Diagonale - Isabelle Gailland. Au départ, un toujours même point minuscule posé au centre de ce que la toile est un espace. Une réplique d'autres points, condensés, alignés, isolés, disséminés construiront dans leur extension, la ligne. Ces lignes, croisées, courbées, déviées, prolongées, seront la structure contenant et séparant la matière des couleurs. La rotation de chaque toile en cours d'exécution va offrir un accès illimité à la non-forme et à la forme. Le point final sera l'ouverture sur différents points de vue de ce que le point et la ligne sont devenus une représentation pour l'œil et l'im...

  13. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Harmonie Nathalie Lenoir Du 4 au 15 septembre 2017 CERN Meyrin, Bâtiment principal Peindre est un langage. Le tracé du pinceau sur le lin en est l'expression. A qui appartient un tableau en définitive ? A celui qui l'a peint ? A celui qui le regarde ? A celui qui l'emporte ? La peinture est une émotion partagée... Laissez-vous projeter de l'autre côté de la toile, prenez un moment pour rêver, en harmonie avec les éléments, parce-que la peinture parle à votre âme… Pour plus d’informations et demandes d’accès : staff.association@cern.ch | Tél : 022 766 37 38

  14. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Œuvres recentes Fabienne Wyler Du 6 au 17 février 2017 CERN Meyrin, Bâtiment principal L'escalier du diable B - aquarelle, encre de Chine XLV - Fabienne Wyler. En relation avec certains procédés d’écriture contemporaine (par ex. Webern ou certaines musiques conçues par ordinateur), les compositions picturales de Fabienne Wyler s’élaborent à partir de « modules » (groupes de quadrangles) qu’elle reproduit en leur faisant subir toutes sortes de transformations et de déplacements : étirements, renversements, rotations, effet miroir, transpositions, déphasages, superpositions, etc., et ceci à toutes les échelles. Au fil des œuvres sont apparues des séries intitulées, Bifurcations, Intermittences, Attracteurs étranges, Polyrythmies. Ces titres ont un lien &e...

  15. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Gaïa Manuella Cany Du 10 au 28 avril 2017 CERN Meyrin, Bâtiment principal Oiseau - Manuella Cany. Tableaux abstraits inspirés de vues satellites ou photos prises du ciel. Certains sont à la frontière du figuratif alors que d'autres permettent de laisser libre cours à son imagination. Aux détails infinis, ces tableaux sont faits pour être vus de loin et de près grâce à une attention toute particulière apportée aux effets de matières et aux couleurs le long de volutes tantôt nuancées tantôt contrastées.   Pour plus d’informations : staff.association@cern.ch | Tél: 022 766 37 38

  16. Exhibition

    CERN Multimedia

    Staff Association

    2014-01-01

      Parallels vision Astronomical subjects which evoke extrasensory kinetic visions Alberto Di Fabio From 8 to 10 October, CERN Meyrin, Main Building In the framework of Italy@cern, the Staff Association presents Alberto Di Fabio. Di Fabio’s work is inspired by the fundamental laws of the physical world, as well as organic elements and their interrelation. His paintings and works on paper merge the worlds of art and science, depicting natural forms and biological structures in vivid colour and imaginative detail. For all additional information: staff.association@cern.ch | Tel: 022 767 28 19

  17. Exhibition

    CERN Multimedia

    Staff Association

    2017-01-01

    Les vibrantes Patrick Robbe-Grillet Du 30 octobre au 10 novembre 2017 CERN Meyrin, Main Building Patrick Robbe-Grillet - Feux d'artifices Qui est Patrick Robbe-Grillet ? Artiste Franco-Suisse, né en 1968 à Genève. En recherche du sentiment de paix, autodidacte, après un séjour en Chine en 2000, puis au Japon en 2002, suivi d’un long questionnement, il trouve sa voie dans la peinture, élément libérateur de sa créativité et expression de sa sensibilité à fleur de peau. « La Chine m’a enseigné les courbes, les nuances. Le Japon, la ligne droite, la rigueur. » Vous avez su rendre visible l'invisible ! - commentaire de Monsieur Fawaz Gruosi Pour plus d’informations et demandes d’accès : staff.association@cern.ch | Tél : 022 766 37 38

  18. Exhibition

    CERN Multimedia

    Staff Association

    2011-01-01

    Jan Hladky, physicien de l'Institut de Physique de l'Académie des Sciences de la République tchèque, et membre de la collaboration Alice, expose ses œuvres au Bâtiment principal du 20 avril au 6 mai. Son exposition est dédiée aux victimes du séisme de Sendai. Des copies de ses œuvres seront mises en vente et les sommes récoltées seront versées au profit des victimes.

  19. Spatial and temporal dynamics of suspended particle characteristics and composition in Navigation Pool 19 of the Upper Mississippi River

    Science.gov (United States)

    Milde, Amanda S.

    2017-01-01

    Suspended particles are an essential component of large rivers influencing channel geomorphology, biogeochemical cycling of nutrients, and food web resources. The Upper Mississippi River (UMR) is a large floodplain river that exhibits pronounced spatiotemporal variation in environmental conditions and biota, providing an ideal environment for investigating dynamics of suspended particles in large river ecosystems. Here we investigated two questions: (1) How do suspended particle characteristics (e.g., size and morphology) vary temporally and spatially? and (2) What environmental variables have the strongest association with particle characteristics? Water sampling was conducted in June, August, and September of 2013 and 2014 in Navigation Pool 19 of the UMR. A FlowCAM particle imaging system was used to enumerate and measure particles 53–300 µm in diameter for size and shape characteristics (e.g., volume, elongation, and symmetry). Suspended particle characteristics varied considerably over space and time and were strongly associated with discharge and concentrations of nitrate + nitrite (NO3-) and soluble reactive phosphorous (SRP). Particle characteristics in backwaters were distinct from those in other habitats for most of the study period, likely due to reduced hydrologic connectivity and higher biotic production in backwaters. During low discharge, phytoplankton and zooplankton made up relatively greater proportions of the observed particles. Concurrently during low discharge, concentrations of chlorophyll, volatile suspended solids, and total phosphorous were higher. Our results suggest that there are complex interactions among space, time, discharge, and other environmental variables (e.g. water nutrients) which drive suspended particle dynamics in large rivers.

  20. Near bed suspended sediment flux by single turbulent events

    Science.gov (United States)

    Amirshahi, Seyed Mohammad; Kwoll, Eva; Winter, Christian

    2018-01-01

    The role of small scale single turbulent events in the vertical mixing of near bed suspended sediments was explored in a shallow shelf sea environment. High frequency velocity and suspended sediment concentration (SSC; calibrated from the backscatter intensity) were collected using an Acoustic Doppler Velocimeter (ADV). Using quadrant analysis, the despiked velocity time series was divided into turbulent events and small background fluctuations. Reynolds stress and Turbulent Kinetic Energy (TKE) calculated from all velocity samples, were compared to the same turbulent statistics calculated only from velocity samples classified as turbulent events (Reevents and TKEevents). The comparison showed that Reevents and TKEevents was increased 3 and 1.6 times, respectively, when small background fluctuations were removed and that the correlation with SSC for TKE could be improved through removal of the latter. The correlation between instantaneous vertical turbulent flux (w ‧) and SSC fluctuations (SSC ‧) exhibits a tidal pattern with the maximum correlation at peak ebb and flood currents, when strong turbulent events appear. Individual turbulent events were characterized by type, strength, duration and length. Cumulative vertical turbulent sediment fluxes and average SSC associated with individual turbulent events were calculated. Over the tidal cycle, ejections and sweeps were the most dominant events, transporting 50% and 36% of the cumulative vertical turbulent event sediment flux, respectively. Although the contribution of outward interactions to the vertical turbulent event sediment flux was low (11%), single outward interaction events were capable of inducing similar SSC ‧ as sweep events. The results suggest that on time scales of tens of minutes to hours, TKE may be appropriate to quantify turbulence in sediment transport studies, but that event characteristics, particular the upward turbulent flux need to be accounted for when considering sediment transport

  1. Monitoring of suspended sediment in South Tyrol

    Science.gov (United States)

    Nadalet, Rudi; Dinale, Roberto; Pernter, Martin; Maraldo, Luca; Peterlin, Dieter; Richter, Arnold; Comiti, Francesco

    2016-04-01

    In the context of the EU Water Framework Directive (WFD), which aims to achieve a good status of European water bodies, the Hydrographic Office of the Autonomous Province of Bolzano (Italy) extended in 2014 its institutional activities including the monitoring of suspended sediment in the river channel network. Currently, the only active monitoring station is on the Adige River at the gauging station of Ponte Adige near Bolzano (drainage area 2705 km2). The applied monitoring strategy and the data analysis concept are both based on the guidelines issued by the Austrian Federal Ministry of Agriculture, Forestry, Environment and Water Management (BMLFUW). The results indicates that the temporal variability strongly differs during the investigated period (2014-2015). In addition to the analysis of precipitation and water discharge, temperature and lightning activity were also included to better understand the sediment transport dynamics observed at the station. In summer 2015, the combination of constantly high daily temperature throughout the Adige basin (which drove intense glacier melting in the headwaters) with a high frequency of convective rainfall events (90% more than in 2014, obtained through lightning detection), led to an annual mass of transported suspended sediment of 260000 t. Interestingly, this value is similar to the one estimated for 2014 (300000 t), which was characterized by very different meteorological conditions (colder and wetter summer), but with the occurrence of an important flood in August, which transported half of the annual amount. Finally, we can conclude that the adopted monitoring strategy is applicable for institutional aims in terms of costs as well as in terms of time effort. During the next years, other stations for suspended sediment monitoring are planned to be installed in the Province to cover the most important river segments.

  2. Synchrotron Investigations of SOFC Cathode Degradation

    Energy Technology Data Exchange (ETDEWEB)

    Idzerda, Yves

    2013-09-30

    The atomic variations occurring in cathode/electrolyte interface regions of La{sub 1-x}Sr{sub x}Co{sub y}Fe{sub 1-y}O{sub 3-δ} (LSCF) cathodes and other SOFC related materials have been investigated and characterized using soft X-ray Absorption Spectroscopy (XAS) and diffuse soft X-ray Resonant Scattering (XRS). X-ray Absorption Spectroscopy in the soft X-ray region (soft XAS) is shown to be a sensitive technique to quantify the disruption that occurs and can be used to suggest a concrete mechanism for the degradation. For LSC, LSF, and LSCF films, a significant degradation mechanism is shown to be Sr out-diffusion. By using the XAS spectra of hexavalent Cr in SrCrO4 and trivalent Cr in Cr2O3, the driving factor for Sr segregation was identified to be the oxygen vacancy concentration at the anode and cathode side of of symmetric LSCF/GDC/LSCF heterostructures. This is direct evidence of vacancy induced cation diffusion and is shown to be a significant indicator of cathode/electrolyte interfacial degradation. X-ray absorption spectroscopy is used to identify the occupation of the A-sites and B-sites for LSC, LSF, and LSCF cathodes doped with other transition metals, including doping induced migration of Sr to the anti-site for Sr, a significant cathode degradation indicator. By using spatially resolved valence mapping of Co, a complete picture of the surface electrochemistry can be determined. This is especially important in identifying degradation phenomena where the degradation is spatially localized to the extremities of the electrochemistry and not the average. For samples that have electrochemical parameters that are measured to be spatially uniform, the Co valence modifications were correlated to the effects of current density, overpotential, and humidity.

  3. Active noise cancellation in a suspended interferometer

    CERN Document Server

    Driggers, Jennifer C; Pepper, Keenan; Adhikari, Rana

    2011-01-01

    We demonstrate feed-forward vibration isolation on a suspended Fabry-Perot interferometer using Wiener filtering and a variant of the common Least Mean Square (LMS) adaptive filter algorithm. We compare the experimental results with theoretical estimates of the cancellation efficiency. Using data from the recent LIGO Science Run, we also estimate the impact of this technique on full scale gravitational wave interferometers. In the future, we expect to use this technique to also remove acoustic, magnetic, and gravitational noise perturbations from the LIGO interferometers. This noise cancellation technique is simple enough to implement in standard laboratory environments and can be used to improve SNR for a variety of high precision experiments.

  4. Geodetic monitoring of suspended particles in rivers

    Science.gov (United States)

    Kamnik, Rok; Maksimova, Daria; Kovačič, Boštjan

    2017-10-01

    There is a trend in modern approach to the management of space of collecting the spatial data, in order to obtain useful information. In this paper a research of suspended particles in the river Drava and Mura will be introduced. The goal is to connect different fields of water management in countries where the rivers Drava and Mura flows in purpose of water management sustainability. The methods such as GNSS for mapping cross sections of the river, the use of ADCP (Acoustic Doppler Current Profiler) measurement system and water sampling to monitor sediment in the water will be presented.

  5. Safety Harness For Work Under Suspended Load

    Science.gov (United States)

    Sunoo, Su Young

    1994-01-01

    Safety device protects worker under suspended engine or other heavy load. Mechanically linked with load so if load should fall, worker yanked safely away. Worker wears chest-plate vest with straps crossing eye on back. Lower safety cable connected to eye extends horizontally away from worker to nearby wall, wrapped on pulley and extends upward to motion amplifier or reducer. Safety cables transform any sudden downward motion of overhanging load into rapid sideways motion of worker. Net catches worker, preventing worker from bumping against wall.

  6. DARHT 2 kA Cathode Development

    Energy Technology Data Exchange (ETDEWEB)

    Henestroza, E.; Houck, T.; Kwan, J.W.; Leitner, M.; Miram, G.; Prichard, B.; Roy, P.K.; Waldron, W.; Westenskow, G.; Yu, S.; Bieniosek, F.M.

    2009-03-09

    In the campaign to achieve 2 kA of electron beam current, we have made several changes to the DARHT-II injector during 2006-2007. These changes resulted in a significant increase in the beam current, achieving the 2 kA milestone. Until recently (before 2007), the maximum beam current that was produced from the 6.5-inch diameter (612M) cathode was about 1300 A when the cathode was operating at a maximum temperature of 1140 C. At this temperature level, the heat loss was dominated by radiation which is proportional to temperature to the fourth power. The maximum operating temperature was limited by the damage threshold of the potted filament and the capacity of the filament heater power supply, as well as the shortening of the cathode life time. There were also signs of overheating at other components in the cathode assembly. Thus it was clear that our approach to increase beam current could not be simply trying to run at a higher temperature and the preferred way was to operate with a cathode that has a lower work function. The dispenser cathode initially used was the type 612M made by SpectraMat. According to the manufacturer's bulletin, this cathode should be able to produce more than 10 A/cm{sup 2} of current density (corresponding to 2 kA of total beam current) at our operating conditions. Instead the measured emission (space charge limited) was 6 A/cm{sup 2}. The result was similar even after we had revised the activation and handling procedures to adhere more closely to the recommend steps (taking longer time and nonstop to do the out-gassing). Vacuum was a major concern in considering the cathode's performance. Although the vacuum gauges at the injector vessel indicated 10{sup -8} Torr, the actual vacuum condition near the cathode in the central region of the vessel, where there might be significant out-gassing from the heater region, was never determined. Poor vacuum at the surface of the cathode degraded the emission (by raising the work function

  7. Cathode architectures for alkali metal / oxygen batteries

    Science.gov (United States)

    Visco, Steven J; Nimon, Vitaliy; De Jonghe, Lutgard C; Volfkovich, Yury; Bograchev, Daniil

    2015-01-13

    Electrochemical energy storage devices, such as alkali metal-oxygen battery cells (e.g., non-aqueous lithium-air cells), have a cathode architecture with a porous structure and pore composition that is tailored to improve cell performance, especially as it pertains to one or more of the discharge/charge rate, cycle life, and delivered ampere-hour capacity. A porous cathode architecture having a pore volume that is derived from pores of varying radii wherein the pore size distribution is tailored as a function of the architecture thickness is one way to achieve one or more of the aforementioned cell performance improvements.

  8. Process For Patterning Dispenser-Cathode Surfaces

    Science.gov (United States)

    Garner, Charles E.; Deininger, William D.

    1989-01-01

    Several microfabrication techniques combined into process cutting slots 100 micrometer long and 1 to 5 micrometer wide into tungsten dispenser cathodes for traveling-wave tubes. Patterned photoresist serves as mask for etching underlying aluminum. Chemically-assisted ion-beam etching with chlorine removes exposed parts of aluminum layer. Etching with fluorine or chlorine trifluoride removes tungsten not masked by aluminum layer. Slots enable more-uniform low-work function coating dispensed to electron-emitting surface. Emission of electrons therefore becomes more uniform over cathode surface.

  9. Klystron Amplifier Utilizing Scandate Cathode and Electrostatic Focusing Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose to build an electrostatically focused klystron that exploits recent breakthroughs in scandate cathode technology. We have built cathodes with greater than...

  10. Long Life Cold Cathodes for Hall effect Thrusters Project

    Data.gov (United States)

    National Aeronautics and Space Administration — An electron source incorporating long life, high current density cold cathodes inside a microchannel plate for use with ion thrusters is proposed. Cathode lifetime...

  11. Nano-Particle Scandate Cathode for Space Communications Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose an improved cathode based on our novel theory of the role of scandium oxide in enhancing emission in tungsten impregnate cathodes. Recent results have...

  12. Elastic properties of suspended multilayer WSe2

    Science.gov (United States)

    Zhang, Rui; Koutsos, Vasileios; Cheung, Rebecca

    2016-01-01

    We report the experimental determination of the elastic properties of suspended multilayer WSe2, a promising two-dimensional (2D) semiconducting material combined with high optical quality. The suspended WSe2 membranes have been fabricated by mechanical exfoliation of bulk WSe2 and transfer of the exfoliated multilayer WSe2 flakes onto SiO2/Si substrates pre-patterned with hole arrays. Then, indentation experiments have been performed on these membranes with an atomic force microscope. The results show that the 2D elastic modulus of the multilayer WSe2 membranes increases linearly while the prestress decreases linearly as the number of layers increases. The interlayer interaction in WSe2 has been observed to be strong enough to prevent the interlayer sliding during the indentation experiments. The Young's modulus of multilayer WSe2 (167.3 ± 6.7 GPa) is statistically independent of the thickness of the membranes, whose value is about two thirds of other most investigated 2D semiconducting transition metal dichalcogenides, namely, MoS2 and WS2. Moreover, the multilayer WSe2 can endure ˜12.4 GPa stress and ˜7.3% strain without fracture or mechanical degradation. The 2D WSe2 can be an attractive semiconducting material for application in flexible optoelectronic devices and nano-electromechanical systems.

  13. Method for forming suspended micromechanical structures

    Science.gov (United States)

    Fleming, James G.

    2000-01-01

    A micromachining method is disclosed for forming a suspended micromechanical structure from {111} crystalline silicon. The micromachining method is based on the use of anisotropic dry etching to define lateral features of the structure which are etched down into a {111}-silicon substrate to a first etch depth, thereby forming sidewalls of the structure. The sidewalls are then coated with a protection layer, and the substrate is dry etched to a second etch depth to define a spacing of the structure from the substrate. A selective anisotropic wet etchant (e.g. KOH, EDP, TMAH, NaOH or CsOH) is used to laterally undercut the structure between the first and second etch depths, thereby forming a substantially planar lower surface of the structure along a {111} crystal plane that is parallel to an upper surface of the structure. The lateral extent of undercutting by the wet etchant is controlled and effectively terminated by either timing the etching, by the location of angled {111}-silicon planes or by the locations of preformed etch-stops. This present method allows the formation of suspended micromechanical structures having large vertical dimensions and large masses while allowing for detailed lateral features which can be provided by dry etch definition. Additionally, the method of the present invention is compatible with the formation of electronic circuitry on the substrate.

  14. LOW TEMPERATURE CATHODE SUPPORTED ELECTROLYTES

    Energy Technology Data Exchange (ETDEWEB)

    Harlan U. Anderson

    2000-03-31

    . However, they have the potential of being useful as an interface on the anode side of the electrolyte. NexTech has focused much of its effort during the past few months on establishing tape casting methods for porous LSM substrates. This work, performed under a separate DOE-funded program, involved tape casting formulations comprising LSM powders with bi-modal particle size distributions and fugitive pore forming additives. Sintered LSM substrates with porosities in the 30 to 40 vol% range, and pore sizes of 10 {approx} 20 microns have been prepared. In addition, tape casting formulations involving composite mixtures of LSM and Sm-doped ceria (SDC) have been evaluated. The LSM/SDC cathode substrates are expected to provide better performance at low temperatures. Characterization of these materials is currently underway.

  15. Erosion of a copper cathode in a negative corona discharge

    Science.gov (United States)

    Asinovskiĭ, É. I.; Petrov, A. A.; Samoylov, I. S.

    2008-02-01

    The pulsed-periodic regime of a negative corona (Trichel pulses) in atmospheric-pressure air, which leads to explosion emission mechanisms (ecton generation) of pointed cathode erosion, is investigated. The jet erosion process at the copper cathode is discovered, and micrometer dendritelike structures formed by erosion products returning to the cathode are detected.

  16. A Transient Model for Fuel Cell Cathode-Water Propagation Behavior inside a Cathode after a Step Potential

    National Research Council Canada - National Science Library

    Der-Sheng Chan; Kan-Lin Hsueh

    2010-01-01

      Most of the voltage losses of proton exchange membrane fuel cells (PEMFC) are due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen diffusion rate inside the flooded cathode...

  17. A multi-use cathode cell MWPC

    CERN Document Server

    Delpierre, P A; Bonierbal, P; Diop, A; Espigat, P; Herteault, L; Jobez, J P; Saget, G; Saigne, R; Sotiras, D; Turlot, J P; Vassent, M

    1982-01-01

    Describes a highly flexible modular design for multiwire proportional chambers used in the CERN-NA3 experiment. The authors illustrate this flexibility by describing the transformation of one chamber into a cathode-cell shower detector and giving its performance as such.

  18. Close cathode chamber: Low material budget MWPC

    Science.gov (United States)

    Varga, Dezső; Kiss, Gábor; Hamar, Gergő; Bencédi, Gyula

    2013-01-01

    Performance of asymmetric-type MWPC-s are presented. In this structure, referred to as Close Cathode Chamber in an earlier study, the material budget is significantly reduced on one hand by the elimination of external support frame, on the other hand by thin detector walls. In this paper it is demonstrated that the outline is compatible with large size detectors (1 m wire length), maintaining mechanical and operation stability, with total weight of 3 kg (including support structure) for a half square meter surface. The detection efficiency and response time is shown to be sufficient for L0 triggering in the ALICE VHMPID layout. Reduced sensitivity to cathode deformations (due to internal overpressure as mechanical strain) is directly demonstrated. On small sized chambers, improvement of position resolution with analog readout is evaluated, reaching 0.09 mm RMS with 2 mm wide cathode segments. Simulation results on signal time evolutions are presented. With the above studies, comparison of classical MWPC-s and the Close Cathode Chamber design is performed in all major aspects.

  19. pipelines cathodic protection design methodologies for impressed ...

    African Journals Online (AJOL)

    HOD

    total external surface area of 226224m2. The computation further showed the current requirement was attainable with connection of 3620 anodes to set up a natural potential between sacrificial anode and pipeline. Key words: Cathodic protection, corrosion, impressed current, pipeline, sacrificial anodes. 1. INTRODUCTION.

  20. Pipelines cathodic protection design methodologies for impressed ...

    African Journals Online (AJOL)

    ... X42 pipeline with total external surface area of 226224m2. The computation further showed the current requirement was attainable with connection of 3620 anodes to set up a natural potential between sacrificial anode and pipeline. Keywords: Cathodic protection, corrosion, impressed current, pipeline, sacrificial anodes ...

  1. Electrochemical Impedance Studies of SOFC Cathodes

    DEFF Research Database (Denmark)

    Hjelm, Johan; Søgaard, Martin; Wandel, Marie

    2007-01-01

    . The full cells had a Ni-YSZ anode and anode support, a thin YSZ electrolyte, and a CGO barrier layer. The symmetric and full cell cathode responses were compared at open-circuit voltage. Humidified hydrogen was used as the fuel in the full cell measurements. Differential analysis of the impedance data...

  2. Environmentally-suspended sediment production of the Nasia River ...

    African Journals Online (AJOL)

    The study assessed the level of suspended sediment produced in the Nasia River Basin. Hydrological and meteorological data and water samples were used for the study. Average suspended sediment yield (33 years) in the basin was 19.90 t/km2/yr. With mean annual runoff of 439.13m3/s, 322.43 t/yr suspended sediment ...

  3. Electron injection into organic semiconductor devices from high work function cathodes

    OpenAIRE

    Hoven, Corey V.; Yang, Renqiang; Garcia, Andres; Crockett, Victoria; Heeger, Alan J.; Bazan, Guillermo C.; Nguyen, Thuc-Quyen

    2008-01-01

    We show that polymer light-emitting diodes with high work-function cathodes and conjugated polyelectrolyte injection/transport layers exhibit excellent efficiencies despite large electron-injection barriers. Correlation of device response times with structure provides evidence that the electron-injection mechanism involves redistribution of the ions within the polyelectrolyte electron-transport layer and hole accumulation at the interface between the emissive and electron-transport layers. Bo...

  4. Improved Rare-Earth Emitter Hollow Cathode

    Science.gov (United States)

    Goebel, Dan M.

    2011-01-01

    An improvement has been made to the design of the hollow cathode geometry that was created for the rare-earth electron emitter described in Compact Rare Earth Emitter Hollow Cathode (NPO-44923), NASA Tech Briefs, Vol. 34, No. 3 (March 2010), p. 52. The original interior assembly was made entirely of graphite in order to be compatible with the LaB6 material, which cannot be touched by metals during operation due to boron diffusion causing embrittlement issues in high-temperature refractory materials. Also, the graphite tube was difficult to machine and was subject to vibration-induced fracturing. This innovation replaces the graphite tube with one made out of refractory metal that is relatively easy to manufacture. The cathode support tube is made of molybdenum or molybdenum-rhenium. This material is easily gun-bored to near the tolerances required, and finish machined with steps at each end that capture the orifice plate and the mounting flange. This provides the manufacturability and robustness needed for flight applications, and eliminates the need for expensive e-beam welding used in prior cathodes. The LaB6 insert is protected from direct contact with the refractory metal tube by thin, graphite sleeves in a cup-arrangement around the ends of the insert. The sleeves, insert, and orifice plate are held in place by a ceramic spacer and tungsten spring inserted inside the tube. To heat the cathode, an insulating tube is slipped around the refractory metal hollow tube, which can be made of high-temperature materials like boron nitride or aluminum nitride. A screw-shaped slot, or series of slots, is machined in the outside of the ceramic tube to constrain a refractory metal wire wound inside the slot that is used as the heater. The screw slot can hold a single heater wire that is then connected to the front of the cathode tube by tack-welding to complete the electrical circuit, or it can be a double slot that takes a bifilar wound heater with both leads coming out

  5. Suspended sediment yield in Texas watersheds

    Science.gov (United States)

    Coonrod, Julia Ellen Allred

    The Texas Water Development Board collected suspended sediment samples across the state of Texas for approximately 60 years. Until this research, no comprehensive analysis of the data had been conducted. This study compiles the suspended sediment data along with corresponding streamflow and rainfall. GIS programs are developed which characterize watersheds corresponding to the sediment gauging stations. The watersheds are characterized according to topography, climate, soils, and land use. All of the data is combined to form several SAS data sets which can subsequently be analyzed using regression. Annual data for all of the stations across the state are classified temporally and spatially to determine trends in the sediment yield. In general, the suspended sediment load increases with increasing runoff but no correlation exists with rainfall. However, the annual average rainfall can be used to classify the watersheds according to climate, which improves the correlation between sediment load and runoff. The watersheds with no dams have higher sediment loads than watersheds with dams. Dams in the drier parts of Texas reduce the sediment load more than dams in the wetter part of the state. Sediment rating curves are developed separately for each basin in Texas. All but one of the curves fall into a band which varies by about two orders of magnitude. The study analyzes daily time series data for the Lavaca River near Edna station. USGS data are used to improve the sediment rating curve by the addition of physically related variables and interaction terms. The model can explain an additional 41% of the variability in sediment concentration compared to a simple bivariate regression of sediment load and flow. The TWDB daily data for the Lavaca River near Edna station are used to quantify temporal trends. There is a high correlation between sediment load and flowrate for the Lavaca River. The correlation can be improved by considering a flow-squared term and by

  6. The World of Virtual Exhibitions

    Directory of Open Access Journals (Sweden)

    Irena Eiselt

    2013-09-01

    Full Text Available EXTENDED ABSTRACTSpecial collections of the National and University Library (NUK hide a lot of items of precious value. The Slovenian cultural heritage is stored on paper or on other media as a part of the library’s Manuscripts, Incunabula and Rare Books Collection, Old Prints Collection, Maps and Pictorial Collection, Music Collection, Ephemera Collection, Serials Collection, and Slovenian Diaspora Publications Collection. Only a small part of the treasures is temporary revealed to the public on special exhibitions. The idea of virtual exhibitions of library treasures was born in 2005. The library aimed to exhibit precious items of special collections of high historical or artistic value. In 2008 the first two virtual exhibitions were created in-house offering access to the rich collections of old postcards of Ljubljana at the beginning of 20th century kept in the Maps and Pictorial Collection of NUK. They were soon followed by other virtual exhibitions. At the beginning they were organised in the same way as physical exhibitions, afterwards different programs were used for creation of special effects (for ex. 3D wall. About two years ago it was decided that the creation of virtual exhibitions will be simplified. Files of digitised and borndigital library materials in jpg format are imported to MS PowerPoint 2010. Each jpg file is now formatted by adding a frame, a description … to the slides which are saved as jpg files. The last step is the import of jpg files into Cooliris application used for NUK web exhibitions. In the paper the virtual exhibition design and creation, the technical point of view and criteria for the selection of exhibition content are explained following the example of the virtual exhibitions the Old Postcards of Ljubljana, Photo Ateliers in Slovenia, a collection of photographs Four Seasons by Fran Krašovec and photos of Post-Earthquake Ljubljana in 1895.

  7. Progress of air-breathing cathode in microbial fuel cells

    Science.gov (United States)

    Wang, Zejie; Mahadevan, Gurumurthy Dummi; Wu, Yicheng; Zhao, Feng

    2017-07-01

    Microbial fuel cell (MFC) is an emerging technology to produce green energy and vanquish the effects of environmental contaminants. Cathodic reactions are vital for high electrical power density generated from MFCs. Recently tremendous attentions were paid towards developing high performance air-breathing cathodes. A typical air-breathing cathode comprises of electrode substrate, catalyst layer, and air-diffusion layer. Prior researches demonstrated that each component influenced the performance of air-breathing cathode MFCs. This review summarized the progress in development of the individual component and elaborated main factors to the performance of air-breathing cathode.

  8. Exhibitions: Facing Outward, Pointing Inward

    Science.gov (United States)

    McDonald, Joseph P.

    2007-01-01

    The Coalition of Essential Schools (CES) Exhibitions Project of the early 1990s produced a range of work that continues to inform the practice of using exhibitions as a "360 degree" method of transforming teaching and learning, community connections, school design, and assessment. Among that work was this paper coupling the origins of exhibitions…

  9. Toward Theoretically Cycling-Stable Lithium-Sulfur Battery Using a Foldable and Compositionally Heterogeneous Cathode.

    Science.gov (United States)

    Zhong, Lei; Yang, Kai; Guan, Ruiteng; Wang, Liangbin; Wang, Shuanjin; Han, Dongmei; Xiao, Min; Meng, Yuezhong

    2017-12-20

    Rechargeable lithium-sulfur (Li-S) batteries have been expected for new-generation electrical energy storages, which are attributed to their high theoretical energy density, cost effectiveness, and eco-friendliness. But Li-S batteries still have some problems for practical application, such as low sulfur utilization and dissatisfactory capacity retention. Herein, we designed and fabricated a foldable and compositionally heterogeneous three-dimensional sulfur cathode with integrated sandwich structure. The electrical conductivity of the cathode is facilitated by three different dimension carbons, in which short-distance and long-distance pathways for electrons are provided by zero-dimensional ketjen black (KB), one-dimensional activated carbon fiber (ACF) and two-dimensional graphene (G). The resultant three-dimensional sulfur cathode (T-AKG/KB@S) with an areal sulfur loading of 2 mg cm -2 exhibits a high initial specific capacity, superior rate performance and a reversible discharge capacity of up to 726 mAh g -1 at 3.6 mA cm -2 with an inappreciable capacity fading rate of 0.0044% per cycle after 500 cycles. Moreover, the cathode with a high areal sulfur loading of 8 mg cm -2 also delivers a reversible discharge capacity of 938 mAh g -1 at 0.71 mA cm -2 with a capacity fading rate of 0.15% per cycle and a Coulombic efficiency of almost 100% after 50 cycles.

  10. In Situ Chemical Synthesis of Lithium Fluoride/Metal Nanocomposite for High Capacity Prelithiation of Cathodes.

    Science.gov (United States)

    Sun, Yongming; Lee, Hyun-Wook; Zheng, Guangyuan; Seh, Zhi Wei; Sun, Jie; Li, Yanbin; Cui, Yi

    2016-02-10

    The initial lithium loss during the formation stage is a critical issue that significantly reduces the specific capacity and energy density of current rechargeable lithium-ion batteries (LIBs). An effective strategy to solve this problem is using electrode prelithiation additives that can work as a secondary lithium source and compensate the initial lithium loss. Herein we show that nanocomposites of lithium fluoride and metal (e.g., LiF/Co and LiF/Fe) can be efficient cathode prelithiation materials. The thorough mixing of ultrafine lithium fluoride and metal particles (∼5 nm) allows lithium to be easily extracted from the nanocomposites via an inverse conversion reaction. The LiF/Co nanocomposite exhibits an open circuit voltage (OCV, 1.5 V) with good compatibility with that of existing cathode materials and delivers a high first-cycle "donor" lithium-ion capacity (516 mA h g(-1)). When used as an additive to a LiFePO4 cathode, the LiF/Co nanocomposite provides high lithium compensation efficiency. Importantly, the as-formed LiF/metal nanocomposites possess high stability and good compatibility with the regular solvent, binder, and existing battery processing conditions, in contrast with the anode prelithiation materials that usually suffer from issues of high chemical reactivity and instability. The facile synthesis route, high stability in ambient and battery processing conditions, and high "donor" lithium-ion capacity make the LiF/metal nanocomposites ideal cathode prelithiation materials for LIBs.

  11. Multi-sided metallization of textile fibres by using magnetron system with grounded cathode

    Directory of Open Access Journals (Sweden)

    Chodun Rafał

    2017-10-01

    Full Text Available The synthesis of coatings on textiles fibers enables functionalization of their properties e.g.: changing the reaction on IR radiation. In our experiment, a magnetron with a grounded cathode and positively biased anode was used as a source of plasma. A ring anode was positioned at 8 cm distance from the cathode. Samples of glass and cotton textile were placed at the plane of the anode. Ti and TiN coatings were deposited by sputtering of titanium target in Ar or Ar+ N2 atmosphere. SEM studies showed that, using the magnetron system described above, the textile fibers were covered by the 2 μm to 3 μm thick coatings. Unexpectedly, the coatings were deposited at both sides of the samples: the front side was exposed to glow discharge plasma and the backside was completely shaded from the plasma. IR optical investigation exhibited significant change in reflectance and transmittance of the coated textiles. The using of standard magnetron system (grounded anode and cathode at negative potential resulted in a coating deposition at the textile side exposed to the plasma action only. We believe that the multi-sided deposition of coatings observed during the process run with magnetron with grounded cathode is a result of an ambipolar diffusion mechanism in the anodic potential drop region.

  12. Design consideration for magnetically suspended flywheel systems

    Science.gov (United States)

    Anand, D.; Kirk, J. A.; Frommer, D. A.

    1985-01-01

    Consideration is given to the design, fabrication, and testing of a magnetically suspended flywheel system for energy storage applications in space. The device is the prototype of a system combining passive suspension of the flywheel plate by samarium cobalt magnets and active control in the radial direction using eight separate magnetic coils. The bearing assembly was machined from a nickel-iron alloy, and the machine parts are all hydrogen annealed. Slots in the magnetic plate allow four independent quadrants for control. The motor/generator component of the system is a brushless dc-permanent magnetic/ironless engine using electronic communication. The system has been tested at over 2500 rpm with satisfactory results. The system characteristics of the flywheel for application in low earth orbit (LEO) are given in a table.

  13. Organics and Suspended Solids Removal from Hospital

    Directory of Open Access Journals (Sweden)

    Fakhri Y. Hmood

    2013-05-01

    Full Text Available The Sequencing Batch Reactor (SBR method is used for treating samples of waste water taken from hospitals in Mosul. Many run periods are used (6-24 hours for             6 months. It is found that the organics and suspended solids removal increase with increasing the period of run, it is in the range ( 96-82 % and ( 100-95 % respectively, while the pH values are nearly neutral (7.05 to 7.5.     BOD5 and SS concentrations of the effluent are within the limits of Iraqi standards,  40:30 mg/l respectively. Hence, SBR method could be used for treating hospitals, small factories and some  residential sectors waste waters.  

  14. Batch fabrication of nanotubes suspended between microelectrodes

    DEFF Research Database (Denmark)

    Mateiu, Ramona Valentina; Stöckli, T.; Knapp, H. F.

    2007-01-01

    We report a fabrication method, which uses standard UV-lithography to pattern the catalyst for the chemical vapour deposition(CVD) of suspended double clamped single walled carbon nanotubes. By using an aqueous solution of Fe(NO3)3 the patterning of the catalyst material onto microelectrodes can...... be done with a simple lift-off process with standard photolithographic resist. An applied electric field is sustained between the microelectrodes during CVD to guide the nanotube growth. Comparison with simulations shows that the location and the orientation of the grown carbon nanotubes (CNT) correspond...... to the regions of maximum electric field, enabling accurate positioning of a nanotube by controlling the shape of the microelectrodes. The CNT bridges are deflected tens of nm when a DC voltage is applied between the nanotube and a gate microelectrode indicating that the clamping through the catalyst particles...

  15. Polymer coatings as separator layers for microbial fuel cell cathodes

    KAUST Repository

    Watson, Valerie J.

    2011-03-01

    Membrane separators reduce oxygen flux from the cathode into the anolyte in microbial fuel cells (MFCs), but water accumulation and pH gradients between the separator and cathode reduces performance. Air cathodes were spray-coated (water-facing side) with anion exchange, cation exchange, and neutral polymer coatings of different thicknesses to incorporate the separator into the cathode. The anion exchange polymer coating resulted in greater power density (1167 ± 135 mW m-2) than a cation exchange coating (439 ± 2 mW m-2). This power output was similar to that produced by a Nafion-coated cathode (1114 ± 174 mW m-2), and slightly lower than the uncoated cathode (1384 ± 82 mW m-2). Thicker coatings reduced oxygen diffusion into the electrolyte and increased coulombic efficiency (CE = 56-64%) relative to an uncoated cathode (29 ± 8%), but decreased power production (255-574 mW m-2). Electrochemical characterization of the cathodes ex situ to the MFC showed that the cathodes with the lowest charge transfer resistance and the highest oxygen reduction activity produced the most power in MFC tests. The results on hydrophilic cathode separator layers revealed a trade off between power and CE. Cathodes coated with a thin coating of anion exchange polymer show promise for controlling oxygen transfer while minimally affecting power production. © 2010 Elsevier B.V. All rights reserved.

  16. Length-dependent thermal conductivity in suspended single-layer graphene.

    Science.gov (United States)

    Xu, Xiangfan; Pereira, Luiz F C; Wang, Yu; Wu, Jing; Zhang, Kaiwen; Zhao, Xiangming; Bae, Sukang; Tinh Bui, Cong; Xie, Rongguo; Thong, John T L; Hong, Byung Hee; Loh, Kian Ping; Donadio, Davide; Li, Baowen; Özyilmaz, Barbaros

    2014-04-16

    Graphene exhibits extraordinary electronic and mechanical properties, and extremely high thermal conductivity. Being a very stable atomically thick membrane that can be suspended between two leads, graphene provides a perfect test platform for studying thermal conductivity in two-dimensional systems, which is of primary importance for phonon transport in low-dimensional materials. Here we report experimental measurements and non-equilibrium molecular dynamics simulations of thermal conduction in suspended single-layer graphene as a function of both temperature and sample length. Interestingly and in contrast to bulk materials, at 300 K, thermal conductivity keeps increasing and remains logarithmically divergent with sample length even for sample lengths much larger than the average phonon mean free path. This result is a consequence of the two-dimensional nature of phonons in graphene, and provides fundamental understanding of thermal transport in two-dimensional materials.

  17. Natural graphene microsheets/sulfur as Li-S battery cathode towards >99% coulombic efficiency of long cycles

    Science.gov (United States)

    Zhang, Yan; Duan, Xiaoyong; Wang, Jie; Wang, Congwei; Wang, Junying; Wang, Jianlong; Wang, Junzhong

    2018-02-01

    Lithium-sulfur battery receives intense attention owing to its high theoretical energy density. However, poor electrical conductivity of sulfur and poor cycle stability of the battery hinder its application. Here, we report that graphene microsheets prepared from microcrystalline graphite minerals by an electrochemical & mechanical approach work as a special conductive support to load sulfur as the cathode of lithium-sulfur battery. The graphene microsheets have the features of excellent conductivity and low defect, small sheet sizes of batteries of graphene microsheets/S as cathode exhibit long-term cyclability and high coulombic efficiency. At 1 C for 2000 cycles, average coulombic efficiency of 99.7% is reached.

  18. Simulation of suspended sediment transport initialized with satellite derived suspended sediment concentrations

    Science.gov (United States)

    Ramakrishnan, Ratheesh; Rajawat, A. S.

    2012-10-01

    Suspended sediment transport in the Gulf of Kachchh is simulated utilizing the suspended sediment concentration (SSC) derived from Oceansat OCM imagery, as the initial condition in MIKE-21 Mud Transport model. Optimization of the model mud parameters, like settling velocity and critical shear stress for erosion are realized with respect to the sediment size distribution and the bottom bed materials observed in the Gulf. Simulated SSCs are compared with alternate OCM derived SSC. The results are observed to be impetus where the model is able to generate the spatial dynamics of the sediment concentrations. Sediment dynamics like deposition, erosion and dispersion are explained with the simulated tidal currents and OCM derived sediment concentrations. Tidal range is observed as the important physical factor controlling the deposition and resuspension of sediments within the Gulf. From the simulation studies; maximum residual current velocities, tidal fronts and high turbulent zones are found to characterise the islands and shoals within the Gulf, which results in high sediment concentrations in those regions. Remarkable variability in the bathymetry of the Gulf, different bed materials and varying tidal conditions induces several circulation patterns and turbulence creating the unique suspended sediment concentration pattern in the Gulf.

  19. Elemental Spatiotemporal Variations of Total Suspended Particles in Jeddah City

    Directory of Open Access Journals (Sweden)

    Mohammad W. Kadi

    2014-01-01

    Full Text Available Elements associated with total suspended particulate matter (TSP in Jeddah city were determined. Using high-volume samplers, TSP samples were simultaneously collected over a one-year period from seven sampling sites. Samples were analyzed for Al, Ba, Ca, Cu, Mg, Fe, Mn, Zn, Ti, V, Cr, Co, Ni, As, and Sr. Results revealed great dependence of element contents on spatial and temporal variations. Two sites characterized by busy roads, workshops, heavy population, and heavy trucking have high levels of all measured elements. Concentrations of most elements at the two sites exhibit strong spatial gradients and concentrations of elements at these sites are higher than other locations. The highest concentrations of elements were observed during June–August because of dust storms, significant increase in energy consumption, and active surface winds. Enrichment factors of elements at the high-level sites have values in the range >10~60 while for Cu and Zn the enrichment factors are much higher (~0–>700 indicating that greater percentage of TSP composition for these three elements in air comes from anthropogenic activities.

  20. A suspended sediment yield predictive equation for river basins in ...

    African Journals Online (AJOL)

    An empirical equation that can be used for estimating the suspended sediment yields of river drainage basins without sediment data has been established for basins in the sub-tropical forest Southwestern river basin system of Ghana. The power law equation relates mean annual specific suspended sediment yield (t km-2 ...

  1. Simulation of suspended sediment transport initialized with satellite ...

    Indian Academy of Sciences (India)

    Suspended sediment transport in the Gulf of Kachchh is simulated utilizing the suspended sediment concentration (SSC) derived from Oceansat OCM imagery, as the initial condition in MIKE-21 Mud. Transport model. Optimization of the model mud parameters, like settling velocity and critical shear stress for erosion are ...

  2. Energy values of suspended detritus in Andaman Sea

    Digital Repository Service at National Institute of Oceanography (India)

    Krishnakumari, L.; Royan, J.P.; Sumitra-Vijayaraghavan

    Energy content of suspended detritus was determined in Andaman Sea waters during April-May 1988. The caloric content of suspended detritus ranged from 987 to 7040 cal. per gram dry wt with an average value of 5530 cal. per gram dry wt. The results...

  3. A wave-resolving model for nearshore suspended sediment transport

    Science.gov (United States)

    Ma, Gangfeng; Chou, Yi-Ju; Shi, Fengyan

    2014-05-01

    This paper presents a wave-resolving sediment transport model, which is capable of simulating sediment suspension in the field-scale surf zone. The surf zone hydrodynamics is modeled by the non-hydrostatic model NHWAVE (Ma et al., 2012). The turbulent flow and suspended sediment are simulated in a coupled manner. Three effects of suspended sediment on turbulent flow field are considered: (1) baroclinic forcing effect; (2) turbulence damping effect and (3) bottom boundary layer effect. Through the validation with the laboratory measurements of suspended sediment under nonbreaking skewed waves and surfzone breaking waves, we demonstrate that the model can reasonably predict wave-averaged sediment profiles. The model is then utilized to simulate a rip current field experiment (RCEX) and nearshore suspended sediment transport. The offshore sediment transport by rip currents is captured by the model. The effects of suspended sediment on self-suspension are also investigated. The turbulence damping and bottom boundary layer effects are significant on sediment suspension. The suspended sediment creates a stably stratified water column, damping fluid turbulence and reducing turbulent diffusivity. The suspension of sediment also produces a stably stratified bottom boundary layer. Thus, the drag coefficient and bottom shear stress are reduced, causing less sediment pickup from the bottom. The cross-shore suspended sediment flux is analyzed as well. The mean Eulerian suspended sediment flux is shoreward outside the surf zone, while it is seaward in the surf zone.

  4. Evaluation of the suspending properties of Cola acuminata gum on ...

    African Journals Online (AJOL)

    Many natural gums are employed as suspending agents in the formulation of pharmaceutical suspensions. The search to develop locally available natural gum from apparently a waste product as an alternative suspending agent stimulated the interest in this present study. Cola acuminata gum (CAG) extracted from Cola ...

  5. 40 CFR 230.21 - Suspended particulates/turbidity.

    Science.gov (United States)

    2010-07-01

    ... time. These new levels may reduce light penetration and lower the rate of photosynthesis and the... suspended particulates persist. The biological and the chemical content of the suspended material may react with the dissolved oxygen in the water, which can result in oxygen depletion. Toxic metals and organics...

  6. Simulation of suspended sediment transport initialized with satellite ...

    Indian Academy of Sciences (India)

    Suspended sediment transport in the Gulf of Kachchh is simulated utilizing the suspended sediment concentration (SSC) derived from Oceansat OCM imagery, as the initial condition in MIKE-21 Mud Transport model. Optimization of the model mud parameters, like settling velocity and critical shear stress for erosion are ...

  7. Evaluation of the suspending property of grewia gum in ...

    African Journals Online (AJOL)

    The suspending property of grewia gum in sulphadimidine suspension was evaluated. The gum was extracted by maceration, filtration, precipitation and drying techniques. It was used at 0.3 to 1% w/v as a suspending agent for sulphadimidine. Sodiumcarboxymethylcellulose (SCMC) and tragacanth were used as basis for ...

  8. Evaluation of the suspending properties of Adansonia digitata gum ...

    African Journals Online (AJOL)

    Sedimentation volume and rate, rheology, and ease of redispersion were employed as evaluation parameters. The results showed that both hot and cold water extracts of the gum used at 2-3 % w/v produced a better suspending property than 4 % w/v Compound Tragacanth gum. The suspending ability of the gums was in ...

  9. Evaluation of the Suspending Property of Grewia Gum in ...

    African Journals Online (AJOL)

    The suspending property of grewia gum in metronidazole suspension was evaluated. The gum was extracted by maceration, filtration, precipitation and drying techniques. It was used at 0.3 to 1% w/v as a suspending agent for metronidazole. Sodiumcarboxymethylcellulose (SCMC) and tragacanth were used as basis for ...

  10. Photowalk Exhibition opens at Microcosm

    CERN Multimedia

    Katarina Anthony

    2011-01-01

    The winning photographs from the 2010 Global Particle Physics Photowalk competition will go on display at Microcosm from 11 February to 2 April. The exhibition is part of a global photography event taking place over three continents, with Photowalk exhibitions opening simultaneously at Fermilab in the US, KEK in Japan and here at CERN.   DESY wire chamber - First place people's choice; second place global jury competition. Photographer: Hans-Peter Hildebrandt  If you were one of the 1,300 photography lovers who voted in last year’s Photowalk competition, this exhibition is your chance to see the winning entries in print. The exhibition will take place in the downstairs gallery of Microcosm, overlooking the garden. 15 photographs will be on display, with each of the laboratories that participated in Photowalk represented by their 3 winning entries. Among them will be the “people’s choice” sunburst photo of a particle detector at DESY (Photo 1), and...

  11. Globe exhibit wins international acclaim

    CERN Multimedia

    Katarina Anthony

    2011-01-01

    The Globe’s “Universe of Particles” exhibition has recently received four prestigious awards for its avant-garde design. This external praise is great encouragement for the CERN exhibitions currently on the drawing board.   The Universe of Particles exhibition has won 4 awards for its avant-garde design. Back in 2008, the design company Atelier Brückner was presented with a challenge: to design the layout of a new permanent exhibition for CERN, one that would epitomize both the Organization and its research. The brief was concise but complex: the exhibit had to be symbolic of the Organization, use modern technology, engage and immerse visitors, and, preferably, use touch-screen technology. With the help of IArt, an interactive technology firm, and based on the content provided by CERN’s Education Group, Atelier Brückner developed the “Universe of Particles” exhibit as it is today. Its principal concept centred on the s...

  12. Ferroelectric Cathodes in Transverse Magnetic Fields

    Energy Technology Data Exchange (ETDEWEB)

    Alexander Dunaevsky; Yevgeny Raitses; Nathaniel J. Fisch

    2002-07-29

    Experimental investigations of a planar ferroelectric cathode in a transverse magnetic field up to 3 kGs are presented. It is shown that the transverse magnetic field affects differently the operation of ferroelectric plasma cathodes in ''bright'' and ''dark'' modes in vacuum. In the ''bright'' mode, when the surface plasma is formed, the application of the transverse magnetic field leads to an increase of the surface plasma density. In the ''dark'' mode, the magnetic field inhibits the development of electron avalanches along the surface, as it does similarly in other kinds of surface discharges in the pre-breakdown mode.

  13. Electricity generation from fermented primary sludge using single-chamber air-cathode microbial fuel cells

    KAUST Repository

    Yang, Fei

    2013-01-01

    Single-chamber air-cathode microbial fuel cells (MFCs) were used to generate electricity from fermented primary sludge. Fermentation (30°C, 9days) decreased total suspended solids (26.1-16.5g/L), volatile suspended solids (24.1-15.3g/L) and pH (5.7-4.5), and increased conductivity (2.4-4.7mS/cm), soluble COD (2.66-15.5g/L), and volatile fatty acids (1.9-10.1g/L). To lower the COD and increase pH, fermentation supernatant was diluted with primary effluent before being used in the MFCs. The maximum power density was 0.32±0.01W/m2, compared to 0.24±0.03W/m2 with only primary effluent. Power densities were higher with phosphate buffer added to the supernatant (1.03±0.06W/m2) or the solution (0.87±0.05W/m2). Coulombic efficiencies ranged from 18% to 57%, and sCOD removals from 84% to 94%. These results demonstrated that sludge can effectively be used for power generation when fermented and then diluted with only primary effluent. © 2012 Elsevier Ltd.

  14. Barium Depletion in Hollow Cathode Emitters

    Science.gov (United States)

    Polk, James E.; Capece, Angela M.; Mikellides, Ioannis G.; Katz, Ira

    2009-01-01

    The effect of tungsten erosion, transport and redeposition on the operation of dispenser hollow cathodes was investigated in detailed examinations of the discharge cathode inserts from an 8200 hour and a 30,352 hour ion engine wear test. Erosion and subsequent re-deposition of tungsten in the electron emission zone at the downstream end of the insert reduces the porosity of the tungsten matrix, preventing the ow of barium from the interior. This inhibits the interfacial reactions of the barium-calcium-aluminate impregnant with the tungsten in the pores. A numerical model of barium transport in the internal xenon discharge plasma shows that the barium required to reduce the work function in the emission zone can be supplied from upstream through the gas phase. Barium that flows out of the pores of the tungsten insert is rapidly ionized in the xenon discharge and pushed back to the emitter surface by the electric field and drag from the xenon ion flow. This barium ion flux is sufficient to maintain a barium surface coverage at the downstream end greater than 0.6, even if local barium production at that point is inhibited by tungsten deposits. The model also shows that the neutral barium pressure exceeds the equilibrium vapor pressure of the impregnant decomposition reaction over much of the insert length, so the reactions are suppressed. Only a small region upstream of the zone blocked by tungsten deposits is active and supplies the required barium. These results indicate that hollow cathode failure models based on barium depletion rates in vacuum dispenser cathodes are very conservative.

  15. On-chip photonic system using suspended p-n junction InGaN/GaN multiple quantum wells device and multiple waveguides

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Yongjin, E-mail: wangyj@njupt.edu.cn; Zhu, Guixia; Gao, Xumin; Yang, Yongchao; Yuan, Jialei; Shi, Zheng; Zhu, Hongbo [Grünberg Research Centre, Nanjing University of Posts and Telecommunications, Nanjing 210003 (China); Cai, Wei [Grünberg Research Centre, Nanjing University of Posts and Telecommunications, Nanjing 210003 (China); School of Computer Engineering, Nanjing Institute of Technology, Nanjing 211167 (China)

    2016-04-18

    We propose, fabricate, and characterize the on-chip integration of suspended p-n junction InGaN/GaN multiple quantum wells (MQWs) device and multiple waveguides on the same GaN-on-silicon platform. The integrated devices are fabricated via a wafer-level process and exhibit selectable functionalities for diverse applications. As the suspended p-n junction InGaN/GaN MQWs device operates under a light emitting diode (LED) mode, part of the light emission is confined and guided by the suspended waveguides. The in-plane propagation along the suspended waveguides is measured by a micro-transmittance setup. The on-chip data transmission is demonstrated for the proof-of-concept photonic integration. As the suspended p-n junction InGaN/GaN MQWs device operates under photodiode mode, the light is illuminated on the suspended waveguides with the aid of the micro-transmittance setup and, thus, coupled into the suspended waveguides. The guided light is finally sensed by the photodiode, and the induced photocurrent trace shows a distinct on/off switching performance. These experimental results indicate that the on-chip photonic integration is promising for the development of sophisticated integrated photonic circuits in the visible wavelength region.

  16. The stationary vacuum arc on non-thermionic hot cathode

    Science.gov (United States)

    Amirov, R. Kh; Antonov, N. N.; Vorona, N. A.; Gavrikov, A. V.; Liziakin, G. D.; Polistchook, V. P.; Samoylov, I. S.; Smirnov, V. P.; Usmanov, R. A.; Yartsev, I. M.

    2015-11-01

    Experimental study of vacuum arc with distributed spot on plumbum cathode at temperatures 1.25-1.45 kK has been presented. At these conditions current density of thermionic emission from cathode was less than 1 μA/cm2, while the mean current density on the cathode was about 10 A/cm2. Plumbum was placed in heat-insulated crucible (cathode) with external diameter 25 mm. Electron-beam heater was situated under the crucible. Arc current was changed in the range 20-70 A, arc voltage was about 15 V. The studied arc is characterized by the absence of the random voltage fluctuations; the micro particles of cathode erosion products were observed only in transition regimes. Spectral data of plasma radiation and values of the heat flow from plasma to cathode were obtained. It has been experimentally established that the evaporation rate in arc approximately two times less than without discharge. The average charge of plumbum particles in the cathode jet was in range 0.2-0.3e. Comparison of the characteristics of studied discharge on thermionic gadolinium cathode and non-thermionic cathodes was fulfilled. One can assume that ions provide the charge transfer on the cathode in the studied discharge.

  17. A definitive criterion for cathodic protection

    Energy Technology Data Exchange (ETDEWEB)

    Alexander, Roger [Cathodic Protection Network International Ltd., Reading (United Kingdom)

    2009-07-01

    The corrosion reaction is defined using the Pourbaix Diagram and includes consideration of the pH, temperature, pressure, nobility of the metal and conductivity of the electrolyte. The passive zone can be established in a laboratory by creating a closed circuit condition in which the voltages can be measured. Natural corrosion cells occurring in simple conditions can be evaluated for the purpose of monitoring the performance of cathodic protection. Metal pipelines are complex networks of conductors submerged in electrolyte of infinitely variable qualities. The present method used to ascertain the effectiveness of cathodic protection has many inherent errors and results in costly and unpredictable corrosion failures. An electrode has been devised to define the exact electrical status of the corrosion reaction at its location. The design allows a closed circuit measurement of the corrosion current that can determine whether or not corrosion has been stopped by cathodic protection. This has allowed the development of software that can calculate the condition and corrosion status throughout a network of pipelines, using electrical circuit analysis common in the electronics industry. (author)

  18. A 10B-based neutron detector with stacked MultiWire Proportional Counters and macrostructured cathodes

    Science.gov (United States)

    Stefanescu, I.; Abdullahi, Y.; Birch, J.; Defendi, I.; Hall-Wilton, R.; Höglund, C.; Hultman, L.; Zee, M.; Zeitelhack, K.

    2013-12-01

    We present the results of the measurements of the detection efficiency for a 4.7 \\r{A} neutron beam incident upon a detector incorporating a stack of up to five MultiWire Proportional Counters (MWPC) with Boron-coated cathodes. The cathodes were made of Aluminum and had a surface exhibiting millimeter-deep V-shaped grooves of 45°, upon which the thin Boron film was deposited by DC magnetron sputtering. The incident neutrons interacting with the converter layer deposited on the sidewalls of the grooves have a higher capture probability, owing to the larger effective absorption film thickness. This leads to a higher overall detection efficiency for the grooved cathode when compared to a cathode with a flat surface. Both the experimental results and the predictions of the GEANT4 model suggests that a 5-counter detector stack with coated grooved cathodes has the same efficiency as a 7-counter stack with flat cathodes. The reduction in the number of counters in the stack without altering the detection efficiency will prove highly beneficial for large-area position-sensitive detectors for neutron scattering applications, for which the cost-effective manufacturing of the detector and associated readout electronics is an important objective. The proposed detector concept could be a technological option for one of the new chopper spectrometers and other instruments planned to be built at the future European Spallation Source in Sweden. These results with macrostructured cathodes generally apply not just to MWPCs but to other gaseous detectors as well.

  19. High-Capacity Layered-Spinel Cathodes for Li-Ion Batteries.

    Science.gov (United States)

    Nayak, Prasant Kumar; Levi, Elena; Grinblat, Judith; Levi, Mikhael; Markovsky, Boris; Munichandraiah, N; Sun, Yang Kook; Aurbach, Doron

    2016-09-08

    Li and Mn-rich layered oxides with the general structure x Li2 MnO3 ⋅(1-x) LiMO2 (M=Ni, Mn, Co) are promising cathode materials for Li-ion batteries because of their high specific capacity, which may be greater than 250 mA h g(-1) . However, these materials suffer from high first-cycle irreversible capacity, gradual capacity fading, limited rate capability and discharge voltage decay upon cycling, which prevent their commercialization. The decrease in average discharge voltage is a major issue, which is ascribed to a structural layered-to-spinel transformation upon cycling of these oxide cathodes in wide potential ranges with an upper limit higher than 4.5 V and a lower limit below 3 V versus Li. By using four elements systems (Li, Mn, Ni, O) with appropriate stoichiometry, it is possible to prepare high capacity composite cathode materials that contain LiMn1.5 Ni0.5 O4 and Lix Mny Niz O2 components. The Li and Mn-rich layered-spinel cathode materials studied herein exhibit a high specific capacity (≥200 mA h g(-1) ) with good capacity retention upon cycling in a wide potential domain (2.4-4.9 V). The effect of constituent phases on their electrochemical performance, such as specific capacity, cycling stability, average discharge voltage, and rate capability, are explored here. This family of materials can provide high specific capacity, high rate capability, and promising cycle life. Using Co-free cathode materials is also an obvious advantage of these systems. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  20. Membrane-less cloth cathode assembly (CCA) for scalable microbial fuel cells.

    Science.gov (United States)

    Zhuang, Li; Zhou, Shungui; Wang, Yueqiang; Liu, Chengshuai; Geng, Shu

    2009-08-15

    One of the main challenges for scaling up microbial fuel cell (MFC) technologies is developing low-cost cathode architectures that can generate high power output. This study developed a simple method to convert non-conductive material (canvas cloth) into an electrically conductive and catalytically active cloth cathode assembly (CCA) in one step. The membrane-less CCA was simply constructed by coating the cloth with conductive paint (nickel-based or graphite-based) and non-precious metal catalyst (MnO(2)). Under the fed-batch mode, the tubular air-chamber MFCs equipped with Ni-CCA and graphite-CCA generated the maximum power densities of 86.03 and 24.67 mW m(-2) (normalized to the projected cathode surface area), or 9.87 and 2.83 W m(-3) (normalized to the reactor liquid volume), respectively. The higher power output of Ni-CCA-MFC was associated with the lower volume resistivity of Ni-CCA (1.35 x 10(-2)Omega cm) than that of graphite-CCA (225 x 10(-2)Omega cm). At an external resistance of 100 Omega, Ni-CCA-MFC and graphite-CCA-MFC removed approximately 95% COD in brewery wastewater within 13 and 18d, and achieved coulombic efficiencies of 30.2% and 19.5%, respectively. The accumulated net water loss through the cloth by electro-osmotic drag exhibited a linear correlation (R(2)=0.999) with produced coulombs. With a comparable power production, such CCAs only cost less than 5% of the previously reported membrane cathode assembly. The new cathode configuration here is a mechanically durable, economical system for MFC scalability.

  1. Facile Synthesis of V2O5 Hollow Spheres as Advanced Cathodes for High-Performance Lithium-Ion Batteries

    Directory of Open Access Journals (Sweden)

    Xingyuan Zhang

    2017-01-01

    Full Text Available Three-dimensional V2O5 hollow structures have been prepared through a simple synthesis strategy combining solvothermal treatment and a subsequent thermal annealing. The V2O5 materials are composed of microspheres 2–3 μm in diameter and with a distinct hollow interior. The as-synthesized V2O5 hollow microspheres, when evaluated as a cathode material for lithium-ion batteries, can deliver a specific capacity as high as 273 mAh·g−1 at 0.2 C. Benefiting from the hollow structures that afford fast electrolyte transport and volume accommodation, the V2O5 cathode also exhibits a superior rate capability and excellent cycling stability. The good Li-ion storage performance demonstrates the great potential of this unique V2O5 hollow material as a high-performance cathode for lithium-ion batteries.

  2. Design of an Advanced Membrane Electrode Assembly Employing a Double-Layered Cathode for a PEM Fuel Cell.

    Science.gov (United States)

    Kim, GyeongHee; Eom, KwangSup; Kim, MinJoong; Yoo, Sung Jong; Jang, Jong Hyun; Kim, Hyoung-Juhn; Cho, EunAe

    2015-12-23

    The membrane electrolyte assembly (MEA) designed in this study utilizes a double-layered cathode: an inner catalyst layer prepared by a conventional decal transfer method and an outer catalyst layer directly coated on a gas diffusion layer. The double-layered structure was used to improve the interfacial contact between the catalyst layer and membrane, to increase catalyst utilization and to modify the removal of product water from the cathode. Based on a series of MEAs with double-layered cathodes with an overall Pt loading fixed at 0.4 mg cm(-2) and different ratios of inner-to-outer Pt loading, the MEA with an inner layer of 0.3 mg Pt cm(-2) and an outer layer of 0.1 mg Pt cm(-2) exhibited the best performance. This performance was better than that of the conventional single-layered electrode by 13.5% at a current density of 1.4 A cm(-2).

  3. Diffusion processes in freely suspended smectic films

    Science.gov (United States)

    Śliwa, I.; Zakharov, A. V.

    2017-08-01

    A molecular model describing translational diffusion in freely suspended smectic films (FSSFs) in air is proposed. This model is based on the random walk theory and allows calculation of the translational diffusion coefficient (TDC) across smectic layers (along the director). All values necessary for calculating the TDC are obtained within the generalized mean-field model considering not only anisotropic interactions between nearest neighbors of molecules forming FSSFs, but also the stabilizing effect of the smectic/air interface. The spatial inhomogeneity of order parameters over the FSSF section, arising in this case, results in the fact that the surface tension at the smectic/air interface not only suppresses thermal fluctuations in surface layers, but also completely suppresses translational diffusion of molecules from the FSSF to air. The results of calculations of dimensional translational diffusion in the bulk of the FSSF formed by 5- n-alkyl-2-(4- n-(perfluoroalkyl-metyleneoxy))pentyl molecules during its thinning show that the TDC monotonically increases as the smectic film is thinned.

  4. Synthesis and Evaluation of Highly Tolerant Pd Electrocatalysts as Cathodes in Direct Ethylene Glycol Fuel Cells (DEGFC

    Directory of Open Access Journals (Sweden)

    Oumarou Savadogo

    2009-10-01

    Full Text Available Highly selective Pd electrocatalysts were synthesized by the formic acid (FA method and evaluated as cathodes for DEGFC applications. In rotating disc measurements in acid medium, the Pd/C cathode showed important catalytic activity for the Oxygen Reduction Reaction (ORR. In the presence of ethylene glycol (EG, C2H6O2, Pd/C exhibited a noteworthy electrochemical behavior and full tolerance to the organic molecule. No current density peaks associated to the EG oxidation reaction emerged and the shift in onset potential for the ORR (Eonset toward more negative potentials was negligible on this cathode. As a comparison, commercial Pt/C was tested under the same conditions showing a poor selectivity for the ORR when EG was present. The detrimental effect of EG on the Pt electrocatalysts resulted in high intensity current density peaks due to the oxidation of EG and a significant shift in Eonset. The evaluation of Pd/C in a DEGFC operating at 80 °C demonstrated its good performance as cathode material. Given these results, it is expected that highly efficient Pd-based cathodes can find application in DEGFCs.

  5. Electrochemically active microorganisms from an acid mine drainage-affected site promote cathode oxidation in microbial fuel cells.

    Science.gov (United States)

    Rojas, Claudia; Vargas, Ignacio T; Bruns, Mary Ann; Regan, John M

    2017-12-01

    The limited database of acidophilic or acidotolerant electrochemically active microorganisms prevents advancements on microbial fuel cells (MFCs) operated under low pH. In this study, three MFCs were used to enrich cathodic biofilms using acid mine drainage (AMD) sediments as inoculum. Linear sweep voltammetry showed cathodic current plateaus of 5.5 (±0.7) mA at about -170mV vs Ag/AgCl and 8.5 (±0.9) mA between -500mV to -450mV vs Ag/AgCl for biofilms developed on small graphite fiber brushes. After gamma irradiation, biocathodes exhibited a decrease in current density approaching that of abiotic controls. Electrochemical impedance spectroscopy showed six-fold lower charge transfer resistance with viable biofilm. Pyrosequencing data showed that Proteobacteria and Firmicutes dominated the biofilms. Acidithiobacillus representatives were enriched in some biocathodes, supporting the potential importance of these known iron and sulfur oxidizers as cathodic biocatalysts. Other acidophilic chemolithoautotrophs identified included Sulfobacillus and Leptospirillum species. The presence of chemoautotrophs was consistent with functional capabilities predicted by PICRUSt related to carbon fixation pathways in prokaryotic microorganisms. Acidophilic or acidotolerant heterotrophs were also abundant; however, their contribution to cathodic performance is unknown. This study directs subsequent research efforts to particular groups of AMD-associated bacteria that are electrochemically active on cathodes. Copyright © 2017 Elsevier B.V. All rights reserved.

  6. Modeling the Effects of the Cathode Composition of a Lithium Iron Phosphate Battery on the Discharge Behavior

    Directory of Open Access Journals (Sweden)

    Won Il Cho

    2013-10-01

    Full Text Available This paper reports a modeling methodology to predict the effects on the discharge behavior of the cathode composition of a lithium iron phosphate (LFP battery cell comprising a LFP cathode, a lithium metal anode, and an organic electrolyte. A one-dimensional model based on a finite element method is presented to calculate the cell voltage change of a LFP battery cell during galvanostatic discharge. To test the validity of the modeling approach, the modeling results for the variations of the cell voltage of the LFP battery as a function of time are compared with the experimental measurements during galvanostatic discharge at various discharge rates of 0.1C, 0.5C, 1.0C, and 2.0C for three different compositions of the LFP cathode. The discharge curves obtained from the model are in good agreement with the experimental measurements. On the basis of the validated modeling approach, the effects of the cathode composition on the discharge behavior of a LFP battery cell are estimated. The modeling results exhibit highly nonlinear dependencies of the discharge behavior of a LFP battery cell on the discharge C-rate and cathode composition.

  7. Electrochemically active microorganisms from an acid mine drainage-affected site promote cathode oxidation in microbial fuel cells

    KAUST Repository

    Rojas, Claudia

    2017-08-03

    The limited database of acidophilic or acidotolerant electrochemically active microorganisms prevents advancements on microbial fuel cells (MFCs) operated under low pH. In this study, three MFCs were used to enrich cathodic biofilms using acid mine drainage (AMD) sediments as inoculum. Linear sweep voltammetry showed cathodic current plateaus of 5.5 (± 0.7) mA at about − 170 mV vs Ag/AgCl and 8.5 (± 0.9) mA between − 500 mV to − 450 mV vs Ag/AgCl for biofilms developed on small graphite fiber brushes. After gamma irradiation, biocathodes exhibited a decrease in current density approaching that of abiotic controls. Electrochemical impedance spectroscopy showed six-fold lower charge transfer resistance with viable biofilm. Pyrosequencing data showed that Proteobacteria and Firmicutes dominated the biofilms. Acidithiobacillus representatives were enriched in some biocathodes, supporting the potential importance of these known iron and sulfur oxidizers as cathodic biocatalysts. Other acidophilic chemolithoautotrophs identified included Sulfobacillus and Leptospirillum species. The presence of chemoautotrophs was consistent with functional capabilities predicted by PICRUSt related to carbon fixation pathways in prokaryotic microorganisms. Acidophilic or acidotolerant heterotrophs were also abundant; however, their contribution to cathodic performance is unknown. This study directs subsequent research efforts to particular groups of AMD-associated bacteria that are electrochemically active on cathodes.

  8. Exhibition - Mathematics, A Beautiful Elsewhere

    CERN Multimedia

    2011-01-01

    From 21 October 2011 to 18 March 2012, the Fondation Cartier pour l’art contemporain will present the exhibition Mathematics: A Beautiful Elsewhere, an exhibition developed in association with the Institut des Hautes Études Scientifiques (IHÉS) and under the patronage of UNESCO. For this unprecedented event, the foundation invited mathematicians to work with artists with whom it has previously worked to create an exhibition that allows visitors to see, hear, do, interpret and think about mathematics. By bringing mathematics into its premises, the Fondation Cartier is itself undergoing the “sudden change of scenery” described by mathematician Alexandre Grothendieck. More information is available here. Fondation Cartier pour l’art contemporain 261, boulevard Raspail 75014 Paris http://fondation.cartier.com Private Visit For professors, researchers and all the staff of Mathematics departments...

  9. A Vacuum Encapsulated Lateral FED with Various Cathode Materials

    Science.gov (United States)

    Park, Cheol-Min; Lim, Moo-Sup; Han, Min-Koo

    We have fabricated poly-Si, Si, and Ti-silicide field emitter arrays employing in-situ vacuum encapsulated lateral field emitter structures and investigated the field emission characteristics such as turn-on voltage, emission current density, and the stability of the emission current. Although poly-Si and Si emitter exhibit almost identical turn-on voltages, the Si emitter shows a sharp turn-on characteristic compared with the poly-Si emitter. It may be caused by the uniform surface of the Si emitter. The current densities of poly-Si, and Si emitter are 0.47, 0.43μA/tip respectively when the anode to cathode voltage is 90V. The turn-on voltage and current density of the Ti-silicide emitter are about 31V, and 1.81μA/tip at a VAK of 90V. The normalized current fluctuations shows that the Ti-silicide emitter exhibits the most stable current.

  10. Cathode power distribution system and method of using the same for power distribution

    Science.gov (United States)

    Williamson, Mark A; Wiedmeyer, Stanley G; Koehl, Eugene R; Bailey, James L; Willit, James L; Barnes, Laurel A; Blaskovitz, Robert J

    2014-11-11

    Embodiments include a cathode power distribution system and/or method of using the same for power distribution. The cathode power distribution system includes a plurality of cathode assemblies. Each cathode assembly of the plurality of cathode assemblies includes a plurality of cathode rods. The system also includes a plurality of bus bars configured to distribute current to each of the plurality of cathode assemblies. The plurality of bus bars include a first bus bar configured to distribute the current to first ends of the plurality of cathode assemblies and a second bus bar configured to distribute the current to second ends of the plurality of cathode assemblies.

  11. Rf Gun with High-Current Density Field Emission Cathode

    Energy Technology Data Exchange (ETDEWEB)

    Jay L. Hirshfield

    2005-12-19

    High current-density field emission from an array of carbon nanotubes, with field-emission-transistor control, and with secondary electron channel multiplication in a ceramic facing structure, have been combined in a cold cathode for rf guns and diode guns. Electrodynamic and space-charge flow simulations were conducted to specify the cathode configuration and range of emission current density from the field emission cold cathode. Design of this cathode has been made for installation and testing in an existing S-band 2-1/2 cell rf gun. With emission control and modulation, and with current density in the range of 0.1-1 kA/cm2, this cathode could provide performance and long-life not enjoyed by other currently-available cathodes

  12. Preliminary experimental study of a carbon fiber array cathode

    Science.gov (United States)

    Li, An-kun; Fan, Yu-wei

    2016-08-01

    The preliminary experimental results of a carbon fiber array cathode for the magnetically insulated transmission line oscillator (MILO) operations are reported. When the diode voltage and diode current were 480 kV and 44 kA, respectively, high-power microwaves with a peak power of about 3 GW and a pulse duration of about 60 ns were obtained in a MILO device with the carbon fiber array cathode. The preliminary experimental results show that the shot-to-shot reproducibility of the diode current and the microwave power is stable until 700 shots. No obvious damage or deterioration can be observed in the carbon fiber surface morphology after 700 shots. Moreover, the cathode performance has no observable deterioration after 700 shots. In conclusion, the maintain-free lifetime of the carbon fiber array cathode is more than 700 shots. In this way, this carbon fiber array cathode offers a potential replacement for the existing velvet cathode.

  13. Influence of Wheel Eccentricity on Vertical Vibration of Suspended Monorail Vehicle: Experiment and Simulation

    Directory of Open Access Journals (Sweden)

    Kaikai Lv

    2017-01-01

    Full Text Available This paper investigates the influence of wheel eccentricity on vertical vibration of suspended monorail vehicle based on experiment and simulation. Two sets of tests are conducted in the first Chinese suspended monorail, and the tested acceleration is analyzed and exhibited. A multibody dynamic model of the suspended monorail vehicle is established to simulate the vertical vibration of car body excited by wheel eccentricity. The results show that there are three factors which may cause an abnormal vibration considering the track and the vehicle system. The influence of wheel eccentricity on the car body vibration was firstly analyzed. Simulated acceleration of car body has a great accordance with test. The wheel eccentricity could excite the resonance of car body at the speed of 21 km/h, and the vertical acceleration would increase considerably. Decreasing the secondary stiffness can effectively reduce the vertical vibration caused by wheel eccentricity, especially at the resonant speed. In the secondary test, the peak of car body acceleration at speed of 20 km/h is not appearing when only renewing the wheels, and the acceleration is decreasing obviously at the domain frequency. It is further determined that the abnormal vibration is mainly caused by the wheel eccentricity.

  14. A combined use of acoustic and optical devices to investigate suspended sediment in rivers

    Science.gov (United States)

    Guerrero, Massimo; Rüther, Nils; Haun, Stefan; Baranya, Sandor

    2017-04-01

    The use of acoustic and optic devices has become more and more common for estimating suspended sediment loads in rivers. The echo intensity levels (EIL) recorded by means of an Acoustic Doppler Current Profiler (ADCP) have been applied in different methods, which provided relationships between scattering particles features derived from samples (i.e., concentration and grain size) and corresponding backscattering strength and sound attenuation. At the same time, the laser diffraction was applied by an in-stream sampler (LISST-SL) to measure suspended sediment concentration and the corresponding particle size distribution (PSD). These two techniques exhibited different limitations in terms of the measured range of concentration, sensitivity to a certain spectrum of particle sizes, and instruments deploy feasibility especially in large rivers, in a way that the use of sampled PSD by LISST-SL to validate ADCP methods may not be trivial. The aim of this study was to combine the vertical profiling of EIL by an ADCP with results from LISST-SL, eventually demonstrating the possibility of using moving ADCP measurements to detect different suspended matters along a Danube River section characterized by a small tributary junction. At the same time, this work elucidates optical to acoustic method deviations that hinders an actual validation of ADCP methods based on LISST-SL rather than with physical samplings.

  15. Photocurrent spectroscopy of exciton and free particle optical transitions in suspended carbon nanotube pn-junctions

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Shun-Wen [Department of Physics and Astronomy, University of Southern California, Los Angeles, California 90089 (United States); Theiss, Jesse; Hazra, Jubin; Aykol, Mehmet; Kapadia, Rehan [Department of Electrical Engineering, University of Southern California, Los Angeles, California 90089 (United States); Cronin, Stephen B. [Department of Physics and Astronomy, University of Southern California, Los Angeles, California 90089 (United States); Department of Electrical Engineering, University of Southern California, Los Angeles, California 90089 (United States); Department of Chemistry, University of Southern California, Los Angeles, California 90089 (United States)

    2015-08-03

    We study photocurrent generation in individual, suspended carbon nanotube pn-junction diodes formed by electrostatic doping using two gate electrodes. Photocurrent spectra collected under various electrostatic doping concentrations reveal distinctive behaviors for free particle optical transitions and excitonic transitions. In particular, the photocurrent generated by excitonic transitions exhibits a strong gate doping dependence, while that of the free particle transitions is gate independent. Here, the built-in potential of the pn-junction is required to separate the strongly bound electron-hole pairs of the excitons, while free particle excitations do not require this field-assisted charge separation. We observe a sharp, well defined E{sub 11} free particle interband transition in contrast with previous photocurrent studies. Several steps are taken to ensure that the active charge separating region of these pn-junctions is suspended off the substrate in a suspended region that is substantially longer than the exciton diffusion length and, therefore, the photocurrent does not originate from a Schottky junction. We present a detailed model of the built-in fields in these pn-junctions, which, together with phonon-assistant exciton dissociation, predicts photocurrents on the same order of those observed experimentally.

  16. Structured electron beams from nano-engineered cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Lueangaramwong, A. [NICADD, DeKalb; Mihalcea, D. [NICADD, DeKalb; Andonian, G. [RadiaBeam Tech.; Piot, P. [Fermilab

    2017-03-07

    The ability to engineer cathodes at the nano-scale have open new possibilities such as enhancing quantum eciency via surface-plasmon excitation, forming ultra-low-emittance beams, or producing structured electron beams. In this paper we present numerical investigations of the beam dynamics associated to this class of cathode in the weak- and strong-field regimes.We finally discuss the possible applications of some of the achievable cathode patterns when coupled with other phase space manipulations.

  17. High Performance Pillared Vanadium Oxide Cathode for Lithium Ion Batteries

    Science.gov (United States)

    2015-04-24

    Performance Pillared Vanadium Oxide Cathode for Lithium Ion Batteries Siu on Tung, Krista L. Hawthorne, Yi Ding, James Mainero, and Levi T. Thompson...Automotive Research Development and Engineering Center, Warren, MI 48387, USA Keywords: nanostructured materials, lithium ion batteries , cathode...2014 to 00-00-2015 4. TITLE AND SUBTITLE High Performance Pillared Vanadium Oxide Cathode for Lithium Ion Batteries 5a. CONTRACT NUMBER 5b. GRANT

  18. Influence of charge carriers on corrugation of suspended graphene

    Science.gov (United States)

    Kirilenko, Demid A.; Gorodetsky, Andrei; Baidakova, Marina V.

    2018-02-01

    Electronic degrees of freedom are predicted to play a significant role in mechanics of two-dimensional crystalline membranes. Here we show that appearance of charge carriers may cause a considerable impact on suspended graphene corrugation, thus leading to additional mechanism resulting in charge carriers mobility variation with their density. This finding may account for some details of suspended graphene conductivity dependence on its doping level and suggests that proper modeling of suspended graphene-based device properties must include the influence of charge carriers on its surface corrugation.

  19. Reducing DRIFT Backgrounds with a Submicron Aluminized-Mylar Cathode

    OpenAIRE

    Battat, J. S. R.; Daw, E.; Dorofeev, A.; Ezeribe, A. C.; Fox, J. R.; Gauvreau, J-L.; Gold, M; Harmon, L.; Harton, J.; Lafler, R.; Landers, J.; Lauer, R. J.; Lee, E.R.; Loomba, D.; Lumnah, A.

    2015-01-01

    Background events in the DRIFT-IId dark matter detector, mimicking potential WIMP signals, are predominantly caused by alpha decays on the central cathode in which the alpha particle is completely or partially absorbed by the cathode material. We installed a 0.9 micron thick aluminized-mylar cathode as a way to reduce the probability of producing these backgrounds. We study three generations of cathode (wire, thin-film, and radiologically clean thin-film) with a focus on the ratio of backgrou...

  20. Intermetallics as advanced cathode materials in hydrogen production via electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    Stojic, Dragica Lj.; Marceta Kaninski, Milica P.; Maksic, Aleksandar D.; Simic, Natasa D. [Laboratory of Physical Chemistry, Vinca Institute of Nuclear Sciences, P.O. Box 522, 11001-Belgrade (Serbia and Montenegro); Grozdic, Tomislav D. [Centre for Multidisciplinary Studies, University of Belgrade, 11030-Belgrade (Serbia and Montenegro)

    2006-06-15

    Intermetallics phases along Mo-Pt phase diagram have been investigated as cathode materials for the production of hydrogen by electrolysis from water KOH solutions, in an attempt to increase the electrolytic process efficiency. These materials were compared with conventional cathodes (Fe and Ni), often used in the alkaline electrolysis, and also with the intermetallic Ti-Pt. An significant upgrade of the electrolytic efficiency using intermetallics in pure KOH electrolyte was achieved in comparison with conventional cathode materials. The effects of those cathode materials on the process efficiency were discussed in the context of transition metal features that issue from their electronic configuration. (author)

  1. Spacecraft mass spectrometer ion source employing field emission cathodes

    Science.gov (United States)

    Curtis, C. C.; Hsieh, K. C.

    1986-01-01

    An ion source that utilizes a pair of thin-film field emission cathodes to provide current for electric impact ionization is studied. The field emission cathodes are composed of microscopically small needle tips and an extraction electrode; the cathodes generate a 200-eV, 0.1-mA electron beam. The multistep process for the manufacturing of the field emission cathodes is examined. The operation of the ion source, which ionizes atoms and molecules that enter the mass spectrometer with a ram velocity of about 80 km/sec, is described.

  2. Introduction to suspended-sediment sampling

    Science.gov (United States)

    Nolan, K. Michael; Gray, John R.; Glysson, G. Douglas

    2005-01-01

    Knowledge of the amount and timing of sediment transport in streams is important to those directly or indirectly responsible for developing and managing water and land resources. Such data are often used to judge the health of watershed and the success or failure of activities designed to mitigate adverse impacts of sediment on streams and stream habitats. This training class presents an introduction to methods currently used by the U.S. Geological Survey (USGS) to sample suspended-sediment concentrations in streams. The presentation is narrated, but you control the pace of the presentation. If the computer you are using can view 'MPEG' videos you will be able to take advantage of videos interspersed in the presentation. A test, found at the end of the presentation, can be taken to assess how well you understood the training material. The class, which is registered as class SW4416 with the National Training Center of the USGS, should take two or three hours to complete. In order to use the presentation provided via this Web page, you will need to download a large disc images (linked below) and 'burn' it to a blank CD-ROM using a CD-ROM recorder on your computer. The presentation will only run on a Windows-based personal computer (PC). The presentation was developed using Macromedia Director MX 20041 and is contained in the file 'SIR05-5077.exe' which should autolaunch. If it does not, the presentation can be started by double-clicking on the file name. A sound card and speakers are necessary to take advantage of narrations that accompany the presentation. Text of narrations is provided, if you are unable to listen to narrations. Instructions for installing and running the presentation are included in the file 'Tutorial.htm', which is on the CD. 1 Registered Trademark: Macromedia Incorporated

  3. Ratios of total suspended solids to suspended sediment concentrations by particle size

    Science.gov (United States)

    Selbig, W.R.; Bannerman, R.T.

    2011-01-01

    Wet-sieving sand-sized particles from a whole storm-water sample before splitting the sample into laboratory-prepared containers can reduce bias and improve the precision of suspended-sediment concentrations (SSC). Wet-sieving, however, may alter concentrations of total suspended solids (TSS) because the analytical method used to determine TSS may not have included the sediment retained on the sieves. Measuring TSS is still commonly used by environmental managers as a regulatory metric for solids in storm water. For this reason, a new method of correlating concentrations of TSS and SSC by particle size was used to develop a series of correction factors for SSC as a means to estimate TSS. In general, differences between TSS and SSC increased with greater particle size and higher sand content. Median correction factors to SSC ranged from 0.29 for particles larger than 500m to 0.85 for particles measuring from 32 to 63m. Great variability was observed in each fraction-a result of varying amounts of organic matter in the samples. Wide variability in organic content could reduce the transferability of the correction factors. ?? 2011 American Society of Civil Engineers.

  4. MWCNT-supported phthalocyanine cobalt as air-breathing cathodic catalyst in glucose/O2 fuel cells

    Science.gov (United States)

    Elouarzaki, Kamal; Haddad, Raoudha; Holzinger, Michael; Le Goff, Alan; Thery, Jessica; Cosnier, Serge

    2014-06-01

    Simple and highly efficient glucose fuel cells using abiotic catalysts and different ion exchange membranes were designed. The glucose fuel cells are based on a multi-walled carbon nanotube (MWCNT)-supported cobalt phthalocyanine (CoPc) cathode and a carbon black/platinum (C/Pt) anode. The electrocatalytic activity of the MWCNT/CoPc electrode for oxygen reduction was investigated by cyclic and linear sweep voltammetry. The electrochemical experiments show that CoPc exhibits promising catalytic properties for oxygen reduction due to its high overpotential and efficiency at reduced metal load. The MWCNT/CoPc electrodes were applied to the oxygen reduction reaction as air-breathing cathode in a single-chambered glucose fuel cell. This cathode was associated with a C/Pt anode in fuel cell configurations using either an anion (Nafion®) or a cation (Tokuyama) exchange membrane. The best fuel cell configuration delivered a maximum power density of 2.3 mW cm-2 and a cell voltage of 0.8 V in 0.5 M KOH solution containing 0.5 M glucose using the Tokuyama membrane at ambient conditions. Beside the highest power density per cathodic catalyst mass (383 W g-1), these glucose fuel cells exhibit a high operational stability, delivering 0.3 mW cm-2 after 50 days.

  5. Suspended sediment concentration profiles from synoptic satellite observations

    Digital Repository Service at National Institute of Oceanography (India)

    Ramakrishnan, R.; Rajawat, A; Chauhan, O.S.

    A method is developed to estimate vertical suspended sediment concentration (SSC) profiles in Gulf of Kachchh, from the sediment concentration values derived from synoptic observations of Ocean Colour Monitor (OCM). Under the influence of currents...

  6. Monosaccharide composition of suspended particles from the Bay of Bengal

    Digital Repository Service at National Institute of Oceanography (India)

    Bhosle, N.B.; Sankaran, P.D.; Wagh, A.B.

    Neutral carbohydrates were determined as alditol acetates by capillary gas chromatography in the hydrolysates of suspended particulate samples (40) collected from 8 depths (approx 1 to 1,000 m) at 5 stations of the Bay of Bengal. Eight individual...

  7. Particles matter: Transformation of suspended particles in constructed wetlands

    NARCIS (Netherlands)

    Mulling, B.T.M.

    2013-01-01

    This thesis shows that constructed wetlands transform suspended particles in (treated) municipal wastewater through selective precipitation in ponds, biological filtering by plankton communities and physical and biological retention in reed beds. These processes effectively remove faecal indicator

  8. Coated particles for lithium battery cathodes

    Science.gov (United States)

    Singh, Mohit; Eitouni, Hany Basam; Pratt, Russell Clayton; Mullin, Scott Allen; Wang, Xiao-Liang

    2017-07-18

    Particles of cathodic materials are coated with polymer to prevent direct contact between the particles and the surrounding electrolyte. The polymers are held in place either by a) growing the polymers from initiators covalently bound to the particle, b) attachment of the already-formed polymers by covalently linking to functional groups attached to the particle, or c) electrostatic interactions resulting from incorporation of cationic or anionic groups in the polymer chain. Carbon or ceramic coatings may first be formed on the surfaces of the particles before the particles are coated with polymer. The polymer coating is both electronically and ionically conductive.

  9. Mobile Technologies in Museum Exhibitions

    Directory of Open Access Journals (Sweden)

    Sandra Medić

    2014-10-01

    Full Text Available In order to be up–to–date and give visitors a memorable and unique experience, museums are including usage of digital technologies in their exhibitions. Even though museums in Serbia are very important part of tourism offer, they still have traditional settings that are poorly interpreted. The majority of them have a scientific and historical review which is unattractive for various target groups of visitors and for museums it’s important to continually try out new ways in interpretation of their settings. Because technology continues to rapidly change the way we communicate, cultural institutions should adapt to new ways of communication with their visitors. This paper examines mobile technologies that can be used in museums to give visitors a different experience and transfer the knowledge innovatively. In that way it will be presented the modern concept of presentation of museum exhibitions, focusing on usage of mobile devices through mobile applications and QR codes. The paper provides the broad understanding of usage mobile technologies in museum exhibitions with its advantages and limitations. The research results can help the museums management to improve interpretation and communication with visitors and enrich the visitor experience.

  10. "Big Science" exhibition at Balexert

    CERN Multimedia

    2008-01-01

    CERN is going out to meet those members of the general public who were unable to attend the recent Open Day. The Laboratory will be taking its "Big Science" exhibition from the Globe of Science and Innovation to the Balexert shopping centre from 19 to 31 May 2008. The exhibition, which shows the LHC and its experiments through the eyes of a photographer, features around thirty spectacular photographs measuring 4.5 metres high and 2.5 metres wide. Welcomed and guided around the exhibition by CERN volunteers, shoppers at Balexert will also have the opportunity to discover LHC components on display and watch films. "Fun with Physics" workshops will be held at certain times of the day. Main hall of the Balexert shopping centre, ground floor, from 9.00 a.m. to 7.00 p.m. Monday to Friday and from 10 a.m. to 6 p.m. on the two Saturdays. Call for volunteers All members of the CERN personnel are invited to enrol as volunteers to help welcom...

  11. Suspended-sediment and suspended-sand concentrations and loads for selected streams in the Mississippi River Basin, 1940-2009

    Science.gov (United States)

    Heimann, David C.; Cline, Teri L.; Glaspie, Lori M.

    2011-01-01

    This report presents suspended-sediment concentration and streamflow data, describes load-estimation techniques used in the computation of annual suspended-sediment loads, and presents annual suspended-sediment loads for 48 streamgaging stations within the Mississippi River Basin. Available published, unpublished, and computed annual total suspended-sediment and suspended-sand loads are presented for water years 1940 through 2009. When previously published annual loads were not available, total suspended-sediment and sand loads were computed using available data for water years 1949 through 2009. A table of suspended-sediment concentration and daily mean streamflow data used in the computation of annual loads is presented along with a table of compiled and computed annual suspended-sediment and suspended-sand loads, annual streamflows, and flow-weighted concentrations for the 48 stations.

  12. Suspended sediment apportionment in a South-Korean mountain catchment

    Science.gov (United States)

    Birkholz, Axel; Meusburger, Katrin; Park, Ji-Hyung; Alewell, Christine

    2016-04-01

    Due to the rapid agricultural expansion and intensification during the last decades in South-Korea, large areas of hill slope forests were transformed to paddies and vegetable fields. The intensive agriculture and the easily erodible soils in our catchment are a major reason for the increased erosion causing suspended sediments to infiltrate into the close drinking water reservoir. The drinking water reservoir Lake Soyang provides water supply for over ten million people in Seoul. Landscape managers need to know the exact origin of these sediments before they can create landscape amelioration schemes. We applied a compound-specific stable isotope (CSSI) approach (Alewell et al., 2015) to apportion the sources of the suspended sediments between forest and agricultural soil contribution to the suspended sediments in a different catchment and applied the same approach to identify and quantify the different sources of the suspended sediments in the river(s) contributing to Lake Soyang. We sampled eight soil sites within the catchment considering the different landuse types forest, rice paddies, maize and vegetables. Suspended sediments were sampled at three outlets of the different sub-catchments. Soils and suspended sediments are analysed for bulk carbon and nitrogen isotopes, compound-specific carbon isotopes of plant-wax derived long-chain fatty acids and long-chain n-alkanes. Fatty acid and alkane isotopes are then used in mixing calculations and the mixing model software IsoSource to find out the contribution of the different source soils to the suspended sediments. We present first data of the source soils and the suspended sediments. C. Alewell, A. Birkholz, K. Meusburger, Y. Schindler-Wildhaber, L. Mabit, 2015. Sediment source attribution from multiple land use systems with CSIA. Biogeosciences Discuss. 12: 14245-14269.

  13. Tailored Core Shell Cathode Powders for Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Swartz, Scott [NexTech Materials, Ltd.,Lewis Center, OH (United States)

    2015-03-23

    In this Phase I SBIR project, a “core-shell” composite cathode approach was evaluated for improving SOFC performance and reducing degradation of lanthanum strontium cobalt ferrite (LSCF) cathode materials, following previous successful demonstrations of infiltration approaches for achieving the same goals. The intent was to establish core-shell cathode powders that enabled high performance to be obtained with “drop-in” process capability for SOFC manufacturing (i.e., rather than adding an infiltration step to the SOFC manufacturing process). Milling, precipitation and hetero-coagulation methods were evaluated for making core-shell composite cathode powders comprised of coarse LSCF “core” particles and nanoscale “shell” particles of lanthanum strontium manganite (LSM) or praseodymium strontium manganite (PSM). Precipitation and hetero-coagulation methods were successful for obtaining the targeted core-shell morphology, although perfect coverage of the LSCF core particles by the LSM and PSM particles was not obtained. Electrochemical characterization of core-shell cathode powders and conventional (baseline) cathode powders was performed via electrochemical impedance spectroscopy (EIS) half-cell measurements and single-cell SOFC testing. Reliable EIS testing methods were established, which enabled comparative area-specific resistance measurements to be obtained. A single-cell SOFC testing approach also was established that enabled cathode resistance to be separated from overall cell resistance, and for cathode degradation to be separated from overall cell degradation. The results of these EIS and SOFC tests conclusively determined that the core-shell cathode powders resulted in significant lowering of performance, compared to the baseline cathodes. Based on the results of this project, it was concluded that the core-shell cathode approach did not warrant further investigation.

  14. Turbulence control of suspended matter aggregate size

    Science.gov (United States)

    Jago, C. F.; Jones, S. E.; Rippeth, T. P.; Simpson, J. H.

    2003-04-01

    The size and properties of the aggregates which comprise suspended particulate matter (SPM) change on short time and length scales in shelf seas. There is experimental and theoretical evidence to suggest that turbulence plays a key role in aggregation but there is contradictory evidence with respect to disaggregation: it has been proposed that sinking stresses, rather than turbulent stresses, are the dominant control of disaggregation. But there is little observational evidence for turbulence control of particle properties. New observations are presented which provide compelling evidence for turbulence control of both aggregation and disaggregation. TKE dissipation and particle size were measured in situ at stratified sites in the northern North Sea in 110 m water depth during the period of weakening of the seasonal thermocline (in October/November) and in the Clyde Sea in 55 m water depth (April). There were similar vertical distributions of TKE dissipation E, SPM concentration C, and particle size D at both sites. At the base of the thermocline, there were minima in E and C, but a maximum in D, indicating that enhanced aggregation was occurring in this region of low turbulent stress. In the bottom mixed layer, E and C increased, while D decreased due to disaggregation in this region of increasing turbulent stress towards the seabed. Particles settling out of the low stress region at the base of the thermocline began to disaggregate when E increased to 3.2x10-6 watts m-2. D did not correlate directly with E because aggregation is a function of collision frequency (and hence of both C and E): this can be accounted for using a simplified theoretical aggregation model which treats flocs as self-similar fractal entities and allows simultaneous floc formation and break up, specified as functions of C and E. It was found that in the northern North Sea the measured D represents an equilibrium size predicted by the model, while in the Clyde Sea tidal variation in both C

  15. Borneo 2007. Three European Exhibitions

    OpenAIRE

    Bernard Sellato

    2013-01-01

    The year 2007 appears to have been an exceptionally good one for Borneo in Europe. Two exhibitions were held in France, and one in Switzerland, which prominently featured the big island, its forests, its peoples, its cultures, and its arts. Here a brief review of these three events. Bornéo... Dayak et Punan. Peuples de la forêt tropicale humide, Musée d’Art et d’Archéologie, Laon, France, 25 November 2006 – 11 March 2007 The beautiful city of Laon, only a short distance by train or by car fro...

  16. Borneo 2007. Three European Exhibitions

    Directory of Open Access Journals (Sweden)

    Bernard Sellato

    2013-01-01

    Full Text Available The year 2007 appears to have been an exceptionally good one for Borneo in Europe. Two exhibitions were held in France, and one in Switzerland, which prominently featured the big island, its forests, its peoples, its cultures, and its arts. Here a brief review of these three events. Bornéo... Dayak et Punan. Peuples de la forêt tropicale humide, Musée d’Art et d’Archéologie, Laon, France, 25 November 2006 – 11 March 2007 The beautiful city of Laon, only a short distance by train or by car fro...

  17. CERN Permanent exhibitions short version

    CERN Multimedia

    2016-01-01

    Visits Explore by yourself the issues CERN's physicists are trying to solve: given that the entire universe is made of particles, where do they come from? Why do they behave in the way they do? Discover the massive apparatus used by physicists at CERN, like the LHC, and see how each part works. CERN invites the public to discover the mysteries of the Universe and the work of the world's biggest physics laboratory through free of charge guided tours and permanent exhibitions. As a group, with friends, individually, on foot, on your bike, come and discover CERN or explore it virtually. Welcome!

  18. Cathodic disbonding of organic coatings on submerged steel

    Energy Technology Data Exchange (ETDEWEB)

    Knudsen, Ole oeystein

    1998-12-31

    In offshore oil production, submerged steel structures are commonly protected by an organic coating in combination with cathodic protection. The main advantage is that the coating decreases the current demand for cathodic protection. But the coating degrades with time. This thesis studies one of the most important mechanisms for coating degradation in seawater, cathodic disbonding. Seven commercial coatings and two model coatings with various pigmentations have been studied. Parameter studies, microscopy and studies of free films were used in the mechanism investigations. Exposure to simulated North Sea conditions was used in the performance studies. The effect of aluminium and glass barrier pigments on cathodic disbonding was investigated. The mechanism for the effect of the aluminium pigments on cathodic disbonding was also investigated. The transport of charge and oxygen to the steel/coating interface during cathodic disbonding was studied for two epoxy coatings. Cathodic disbonding, blistering and current demand for cathodic protection was measured for nine commercial coatings for submerged steel structures, using the ASTM-G8 standard test and a long term test under simulated North Sea conditions. The relevance of the ASTM-G8 test as a prequalification test was evaluated. 171 refs., 40 figs., 6 tabs.

  19. Development of cathode material for lithium-ion batteries

    Directory of Open Access Journals (Sweden)

    Rustam Mukhtaruly Turganaly

    2014-08-01

    Full Text Available The electrochemical characteristics of the cathode material coated with carbon layer has been developed. Various carbon coating methods. There  has been carried out a comparative electrochemical analysis of the coated and uncoated with carbon cathode material. 

  20. Impressed current cathodic protection of deep water structures

    Digital Repository Service at National Institute of Oceanography (India)

    Venkatesan, R.

    Of all the various anti-corrosion systems usEd. by offshore structures and ship-building industry to reduce the ravages of sea-water corrosion, cathodic protection is one of the most important. Impressed current cathodic protection (ICCP...

  1. Cathode potential drop in the channel of a magnetoplasma compressor

    Energy Technology Data Exchange (ETDEWEB)

    Shubin, A.P.

    1977-09-01

    Calculations are carried out for the dissipationless plasma flow in the channel of a magnetoplasma compressor when there is a potential drop near the cathode. This drop appears when the current is carried by ions as the result of the disappearance of ions at the cathode.

  2. A Statistical Approach to the Modified Impress Current Cathodic ...

    African Journals Online (AJOL)

    An attempt to predict theoretically, the corrosion protection of oil pipelines by Impressed Current Cathodic Protection (ICCP) was embarked upon using data from an ICCP system in practice for three years (2004 through 2006). The concepts and principles used in Cathodic protection is briefly explained with a discussion of ...

  3. Single-layer graphene cathodes for organic photovoltaics

    Energy Technology Data Exchange (ETDEWEB)

    Cox, Marshall P.; Gorodetsky, Alon A.; Kim, Bumjung; Kim, Keun Soo; Jia, Zhang; Kim, Philip; Nuckolls, Colin; Kymissis, Ioannis

    2011-01-01

    A laminated single-layer graphene is demonstrated as a cathode for organic photovoltaicdevices. The measured properties indicate that graphene offers two potential advantages over conventional photovoltaic electrode materials; work function matching via contact doping, and increased power conversion efficiency due to transparency. These findings indicate that flexible, light-weight all carbon solar cells can be constructed using graphene as the cathode material.

  4. Microbial Fuel Cell Performance with a Pressurized Cathode Chamber

    Science.gov (United States)

    Microbial fuel cell (MFC) power densities are often constrained by the oxygen reduction reaction rate on the cathode electrode. One important factor for this is the normally low solubility of oxygen in the aqueous cathode solution creating mass transport limitations, which hinder oxygen reduction a...

  5. Impedance Modeling of Solid Oxide Fuel Cell Cathodes

    DEFF Research Database (Denmark)

    Mortensen, Jakob Egeberg; Søgaard, Martin; Jacobsen, Torben

    2010-01-01

    A 1-dimensional impedance model for a solid oxide fuel cell cathode is formulated and applied to a cathode consisting of 50/50 wt% strontium doped lanthanum cobaltite and gadolinia doped ceria. A total of 42 impedance spectra were recorded in the temperature range: 555-852°C and in the oxygen...

  6. The Effect of Substrate Topography on Coating Cathodic Delamination

    DEFF Research Database (Denmark)

    Erik Weinell, Claus; Sørensen, Per A.; Kiil, Søren

    2011-01-01

    This article describes the effect of steel substrate topography on coating cathodic delamination. The study showed that the surface preparation can be used to control and minimize the rate of cathodic delamination. The coating should have maximum wetting properties so that substrates with high...

  7. Plasma-induced field emission study of carbon nanotube cathode

    Directory of Open Access Journals (Sweden)

    Yi Shen

    2011-10-01

    Full Text Available An investigation on the plasma-induced field emission (PFE properties of a large area carbon nanotube (CNT cathode on a 2 MeV linear induction accelerator injector is presented. Experimental results show that the cathode is able to emit intense electron beams. Intense electron beams of 14.9–127.8  A/cm^{2} are obtained from the cathode. The CNT cathode desorbs gases from the CNTs during the PFE process. The fast cathode plasma expansion affects the diode perveance. The amount of outgassing is estimated to be 0.06–0.49  Pa·L, and the ratio of outgassing and electron are roughly calculated to be within the range of 170–350 atoms per electron. The effect of the outgassing is analyzed, and the outgassing mass spectrum of the CNT cathode has been studied during the PFE. There is a significant desorption of CO_{2}, N_{2}(CO, and H_{2} gases, which plays an important role during the PFE process. All the experiments demonstrate that the outgassing plays an important role in the formation of the cathode plasma. Moreover, the characteristic turn-on time of the CNT cathode was measured to be 39 ns.

  8. Cathode Stalk Cooling System for the MK 1 Quarterwave Gun

    Science.gov (United States)

    2012-06-01

    20 Figure 9. Cross section of the cavity with the coupler and cathode stalk installed (After [11...focusing magnets focus the electron beam envelope transversely to the propagation axis. Bending and focusing magnets are analogous to prisms and lenses...each of these layers. Figure 9. Cross section of the cavity with the coupler and cathode stalk installed (After [11]). 25 To transform the

  9. Cathodic dissolution in the electrocoagulation process using aluminium electrodes.

    Science.gov (United States)

    Picard, T; Cathalifaud-Feuillade, G; Mazet, M; Vandensteendam, C

    2000-02-01

    All the authors working with aluminium electrodes in the electrocoagulation process have shown that a dissolution occurs at the cathode. This result cannot be explained by the electrochemical process in which only the anodes should be dissolved. The most probable reaction is a chemical attack by hydroxyl ions (generated during water reduction) on the aluminium cathode but nobody has proved it in the framework of the electrocoagulation process. So we are interested in determining what kind of reactions occurs at the cathode. For that, we have elaborated a batch pilot apparatus divided into two compartments, allowing measurement of gas formation taking place only in one compartment. The gases measurements were performed by mass spectrometry with helium as carrier gas. To validate our experimental protocol, the first experiments have been done with a stainless steel cathode: in this case, the results have indicated that the amount of created hydrogen is in good agreement with the values calculated using the second Faraday's law. The experiments realised with an aluminium cathode have shown that the hydrogen formation, in these conditions, was higher than those observed with the stainless steel cathode. All our investigations enable us to propose that with an aluminium cathode, hydrogen formation can be separated into two phenomena. The first one is due to an electrochemical reaction (water reduction), and the second one arises from a chemical reaction explaining the dissolution observed at the cathode.

  10. Ultrahigh-Capacity Lithium-Oxygen Batteries Enabled by Dry-Pressed Holey Graphene Air Cathodes.

    Science.gov (United States)

    Lin, Yi; Moitoso, Brandon; Martinez-Martinez, Chalynette; Walsh, Evan D; Lacey, Steven D; Kim, Jae-Woo; Dai, Liming; Hu, Liangbing; Connell, John W

    2017-05-10

    Lithium-oxygen (Li-O2) batteries have the highest theoretical energy density of all the Li-based energy storage systems, but many challenges prevent them from practical use. A major obstacle is the sluggish performance of the air cathode, where both oxygen reduction (discharge) and oxygen evolution (charge) reactions occur. Recently, there have been significant advances in the development of graphene-based air cathode materials with a large surface area and catalytically active for both oxygen reduction and evolution reactions, especially with additional catalysts or dopants. However, most studies reported so far have examined air cathodes with a limited areal mass loading rarely exceeding 1 mg/cm2. Despite the high gravimetric capacity values achieved, the actual (areal) capacities of those batteries were far from sufficient for practical applications. Here, we present the fabrication, performance, and mechanistic investigations of high-mass-loading (up to 10 mg/cm2) graphene-based air electrodes for high-performance Li-O2 batteries. Such air electrodes could be easily prepared within minutes under solvent-free and binder-free conditions by compression-molding holey graphene materials because of their unique dry compressibility associated with in-plane holes on the graphene sheet. Li-O2 batteries with high air cathode mass loadings thus prepared exhibited excellent gravimetric capacity as well as ultrahigh areal capacity (as high as ∼40 mAh/cm2). The batteries were also cycled at a high curtailing areal capacity (2 mAh/cm2) and showed a better cycling stability for ultrathick cathodes than their thinner counterparts. Detailed post-mortem analyses of the electrodes clearly revealed the battery failure mechanisms under both primary and secondary modes, arising from the oxygen diffusion blockage and the catalytic site deactivation, respectively. These results strongly suggest that the dry-pressed holey graphene electrodes are a highly viable architectural platform

  11. Structural Exfoliation of Layered Cathode under High Voltage and Its Suppression by Interface Film Derived from Electrolyte Additive.

    Science.gov (United States)

    Zhu, Yunmin; Luo, Xueyi; Zhi, Huozhen; Yang, Xuerui; Xing, Lidan; Liao, Youhao; Xu, Mengqing; Li, Weishan

    2017-04-05

    Layered cathodes for lithium-ion battery, including LiCo1-x-yNixMnyO2 and xLi2MnO3·(1-x)LiMO2 (M = Mn, Ni, and Co), are attractive for large-scale applications such as electric vehicles, because they can deliver additional specific capacity when the end of charge voltage is improved to over 4.2 V. However, operation under a high voltage might cause capacity decaying of layered cathodes during cycling. The failure mechanisms that have been given, up to date, include the electrolyte oxidation decomposition, the Ni, Co, or Mn ion dissolution, and the phase transformation. In this work, we report a new mechanism involving the exfoliation of layered cathodes when the cathodes are performed with deep cycling under 4.5 V in the electrolyte consisting of carbonate solvents and LiPF6 salt. Additionally, an electrolyte additive that can form a cathode interface film is applied to suppress this exfoliation. A representative layered cathode, LiCoO2, and an interface film-forming additive, dimethyl phenylphosphonite (DMPP), are selected to demonstrate the exfoliation and the protection of layered structure. When evaluated in half-cells, LiCoO2 exhibits a capacity retention of 24% after 500 cycles in base electrolyte, but this value is improved to 73% in the DMPP-containing electrolyte. LiCoO2/graphite full cell using DMPP behaves better than the Li/LiCoO2 half-cell, delivering an initial energy density of 700 Wh kg -1 with an energy density retention of 82% after 100 cycles at 0.2 C between 3 and 4.5 V, as compared to 45% for the cell without using DMPP.

  12. Preparation and electrochemical properties of cathode materials for lithium ion battery by aerosol process

    Energy Technology Data Exchange (ETDEWEB)

    Ogihara, Takashi [Department of Fiber Amenity Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507 (Japan)], E-mail: ogihara@matse.u-fukui.ac.jp; Kodera, Takayuki; Myoujin, Kenichi; Motohira, Shigeru [Department of Fiber Amenity Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui-shi, Fukui 910-8507 (Japan)

    2009-04-15

    Lithium transition metal oxide powders such as LiMn{sub 2}O{sub 4}, LiNi{sub 0.5}Mn{sub 1.5}O{sub 4}, LiCo{sub 1/3}Ni{sub 1/3}Mn{sub 1/3}O{sub 2} and LiFePO{sub 4} were prepared by spray pyrolysis. The particle characteristics of them were determined by SEM, XRD, BET and AAS. Lithium transition metal oxide powders had spherical morphology of 1-2 {mu}m with narrow size distribution and homogeneous chemical composition. The electrochemical properties of cathode were also estimated by rechargeable capacity, cycle performance, thermal stability and high rate charging. The cathodes obtained by spray pyrolysis exhibited that the discharge capacity of LiMn{sub 2}O{sub 4}, LiNi{sub 0.5}Mn{sub 1.5}O{sub 4}, LiCo{sub 1/3}Ni{sub 1/3}Mn{sub 1/3}O{sub 2} and LiFePO{sub 4} was 120, 130, 170 and 150 mAh/g, respectively and stable up to 500 cycles at a rate of 1 C. Mass production of lithium transition metal oxide powders was carried out by using internal combustion type of spray pyrolysis. The electrochemical properties of cathode obtained by internal combustion type spray pyrolysis were comparable with those obtained by spray pyrolysis.

  13. A high performance cathode for proton conducting solid oxide fuel cells

    KAUST Repository

    Wang, Zhiquan

    2015-01-01

    Intermediate temperature solid-oxide fuel cells (IT-SOFCs)), as one of the energy conversion devices, have attracted worldwide interest for their great fuel efficiency, low air pollution, much reduced cost and excellent longtime stability. In the intermediate temperature range (500-700°C), SOFCs based on proton conducting electrolytes (PSOFCs) display unique advantages over those based on oxygen ion conducting electrolytes. A key obstacle to the practical operation of past P-SOFCs is the poor stability of the traditionally used composite cathode materials in the steam-containing atmosphere and their low contribution to proton conduction. Here we report the identification of a new Ruddlesden-Popper-type oxide Sr3Fe2O7-δ that meets the requirements for much improved long-term stability and shows a superior single-cell performance. With a Sr3Fe2O7-δ-5 wt% BaZr0.3Ce0.5Y0.2O3-δ cathode, the P-SOFC exhibits high power densities (683 and 583 mW cm-2 at 700°C and 650°C, respectively) when operated with humidified hydrogen as the fuel and air as the cathode gas. More importantly, no decay in discharging was observed within a 100 hour test. © The Royal Society of Chemistry 2015.

  14. Textile Inspired Lithium-Oxygen Battery Cathode with Decoupled Oxygen and Electrolyte Pathways.

    Science.gov (United States)

    Xu, Shaomao; Yao, Yonggang; Guo, Yuanyuan; Zeng, Xiaoqiao; Lacey, Steven D; Song, Huiyu; Chen, Chaoji; Li, Yiju; Dai, Jiaqi; Wang, Yanbin; Chen, Yanan; Liu, Boyang; Fu, Kun; Amine, Khalil; Lu, Jun; Hu, Liangbing

    2018-01-01

    The lithium-air (Li-O 2 ) battery has been deemed one of the most promising next-generation energy-storage devices due to its ultrahigh energy density. However, in conventional porous carbon-air cathodes, the oxygen gas and electrolyte often compete for transport pathways, which limit battery performance. Here, a novel textile-based air cathode is developed with a triple-phase structure to improve overall battery performance. The hierarchical structure of the conductive textile network leads to decoupled pathways for oxygen gas and electrolyte: oxygen flows through the woven mesh while the electrolyte diffuses along the textile fibers. Due to noncompetitive transport, the textile-based Li-O 2 cathode exhibits a high discharge capacity of 8.6 mAh cm -2 , a low overpotential of 1.15 V, and stable operation exceeding 50 cycles. The textile-based structure can be applied to a range of applications (fuel cells, water splitting, and redox flow batteries) that involve multiple phase reactions. The reported decoupled transport pathway design also spurs potential toward flexible/wearable Li-O 2 batteries. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  15. Conductive framework of inverse opal structure for sulfur cathode in lithium-sulfur batteries

    Science.gov (United States)

    Jin, Lu; Huang, Xiaopeng; Zeng, Guobo; Wu, Hua; Morbidelli, Massimo

    2016-09-01

    As a promising cathode inheritor for lithium-ion batteries, the sulfur cathode exhibits very high theoretical volumetric capacity and energy density. In its practical applications, one has to solve the insulating properties of sulfur and the shuttle effect that deteriorates cycling stability. The state-of-the-art approaches are to confine sulfur in a conductive matrix. In this work, we utilize monodisperse polystyrene nanoparticles as sacrificial templates to build polypyrrole (PPy) framework of an inverse opal structure to accommodate (encapsulate) sulfur through a combined in situ polymerization and melting infiltration approach. In the design, the interconnected conductive PPy provides open channels for sulfur infiltration, improves electrical and ionic conductivity of the embedded sulfur, and reduces polysulfide dissolution in the electrolyte through physical and chemical adsorption. The flexibility of PPy and partial filling of the inverse opal structure endure possible expansion and deformation during long-term cycling. It is found that the long cycling stability of the cells using the prepared material as the cathode can be substantially improved. The result demonstrates the possibility of constructing a pure conductive polymer framework to accommodate insulate sulfur in ion battery applications.

  16. Diffuse vacuum arc with cerium oxide hot cathode

    Science.gov (United States)

    Amirov, R. Kh; Vorona, N. A.; Gavrikov, A. V.; Liziakin, G. D.; Polistchook, V. P.; Samoylov, I. S.; Smirnov, V. P.; Usmanov, R. A.; Yartsev, I. M.; Ivanov, A. S.

    2016-11-01

    Diffuse vacuum arc with hot cathode is one of the perspective plasma sources for the development of spent nuclear fuel plasma reprocessing technology. Experimental data is known for such type of discharges on metal cathodes. In this work discharge with cerium dioxide hot cathode was studied. Cerium dioxide properties are similar to uranium dioxide. Its feature as dielectric is that it becomes conductive in oxygen-free atmosphere. Vacuum arc was studied at following parameters: cathode temperatures were between 2.0 and 2.2 kK, discharge currents was between 30 and 65 A and voltages was in range from 15 to 25 V. Power flows from plasma to cathode were estimated in achieved regimes. Analysis of generated plasma component composition was made by radiation spectrum diagnostics. These results were compared with calculations of equilibrium gaseous phase above solid sample of cerium dioxide in close to experimental conditions. Cerium dioxide vacuum evaporation rate and evaporation rate in arc were measured.

  17. Air humidity and water pressure effects on the performance of air-cathode microbial fuel cell cathodes

    KAUST Repository

    Ahn, Yongtae

    2014-02-01

    To better understand how air cathode performance is affected by air humidification, microbial fuel cells were operated under different humidity conditions or water pressure conditions. Maximum power density decreased from 1130 ± 30 mW m-2 with dry air to 980 ± 80 mW m -2 with water-saturated air. When the cathode was exposed to higher water pressures by placing the cathode in a horizontal position, with the cathode oriented so it was on the reactor bottom, power was reduced for both with dry (1030 ± 130 mW m-2) and water-saturated (390 ± 190 mW m-2) air. Decreased performance was partly due to water flooding of the catalyst, which would hinder oxygen diffusion to the catalyst. However, drying used cathodes did not improve performance in electrochemical tests. Soaking the cathode in a weak acid solution, but not deionized water, mostly restored performance (960 ± 60 mW m-2), suggesting that there was salt precipitation in the cathode that was enhanced by higher relative humidity or water pressure. These results showed that cathode performance could be adversely affected by both flooding and the subsequent salt precipitation, and therefore control of air humidity and water pressure may need to be considered for long-term MFC operation. © 2013 Elsevier B.V. All rights reserved.

  18. A one-dimensional model illustrating virtual-cathode formation in a novel coaxial virtual-cathode oscillator.

    CSIR Research Space (South Africa)

    Turner, GR

    2014-09-01

    Full Text Available A one-dimensional electrostatic sheet model of a coaxial geometry Virtual Cathode Oscillator (VCO) is presented. The cathode is centrally located and connects to a peripherally located plate electrode to form a resonant cavity, and is thus...

  19. Nanostructured ceria based thin films ({<=}1 {mu}m) As cathode/electrolyte interfaces

    Energy Technology Data Exchange (ETDEWEB)

    Hierso, J. [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France); Boy, P.; Valle, K. [CEA-Le Ripault, LSCG, BP 15, 37000 Monts (France); Vulliet, J.; Blein, F. [CEA-Le Ripault, LCCA, BP 15, 37000 Monts (France); Laberty-Robert, Ch., E-mail: christel.laberty@upmc.fr [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France); Sanchez, C. [Laboratoire de Chimie de la Matiere Condensee de Paris, Universite Paris 6-UMR 7574-College de France, 11 Place Marcelin Berthelot, 75005 Paris (France)

    2013-01-15

    Gadolinium doped cerium oxide (CGO: Ce{sub 0,9}Gd{sub 0,1}O{sub 2-{delta}}) films were used as an oxygen anion diffusion layer at the cathode/electrolyte interface of Solid Oxide Fuel Cells (SOFCs), between LSCF (lanthanum strontium cobalt ferrite) and YSZ (yttria-stabilized zirconia). Thin ({approx}100 nm) and thick ({approx}700 nm) mesoporous CGO layers were synthesized through a sol-gel process including organic template coupled with the dip-coating method. Structural and microstructural characterizations were performed, highlighting a well-bonded crystalline CGO nanoparticles network which delineates a 3-D inter-connected mesoporous network. Their electrical behaviors were investigated by impedance spectroscopy analysis of YSZ/mesoporous-CGO/LSCF half-cell. Anode-supported SOFCs, operating at 800 Degree-Sign C, with either dense or mesoporous CGO dip-coated interlayers were also fabricated [NiO-YSZ anode/YSZ/CGO/LSCF cathode]. The impact of the mesoporous CGO interlayers on SOFCs performances was investigated by galvanostatic analysis and compared to the behavior of a dense CGO interlayer. The polarization curves revealed an enhancement in the electrical performance of the cell, which is assigned to a decrease of the polarization resistance at the cathode/electrolyte interface. The integrity and connectivity of the CGO nanoparticles bonded network facilitates O{sup 2-} transport across the interface. - Graphical abstract: Thin and thick CGO films have been prepared through a sol-gel process and their potential application as SOFC cathode/electrolyte interlayer in SOFC has been investigated. Highlights: Black-Right-Pointing-Pointer Mesoporous ceria based thin films exhibit interesting performances for Solid Oxide Fuel Cell. Black-Right-Pointing-Pointer Mesoporous films were synthesized through the sol-gel process combined with the dip-coating. Black-Right-Pointing-Pointer Integrity and connectivity of the nanoparticles facilitates O{sup 2-} transport across the

  20. Polyamidoamine dendrimer-based binders for high-loading lithium–sulfur battery cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Bhattacharya, Priyanka; Nandasiri, Manjula I.; Lv, Dongping; Schwarz, Ashleigh M.; Darsell, Jens T.; Henderson, Wesley A.; Tomalia, Donald A.; Liu, Jun; Zhang, Ji-Guang; Xiao, Jie

    2016-01-01

    Lithium-sulfur (Li-S) batteries are regarded as one of the most promising candidates for next generation energy storage systems because of their ultra high theoretical specific energy. To realize the practical application of Li-S batteries, however, a high S active material loading is essential (>70 wt% in the carbon-sulfur (C-S) composite cathode and >2 mg cm-2 in the electrode). A critical challenge to achieving this high capacity in practical electrodes is the dissolution of the longer lithium polysulfide reaction intermediates in the electrolyte (resulting in loss of active material from the cathode and contamination of the anode due to the polysulfide shuttle mechanism). The binder material used for the cathode is therefore crucial as this is a key determinant of the bonding interactions between the active material (S) and electronic conducting support (C), as well as the maintenance of intimate contact between the electrode materials and current collector. The battery performance can thus be directly correlated with the choice of binder, but this has received only minimal attention in the relevant Li-S battery published literature. Here, we investigated the application of polyamidoamine (PAMAM) dendrimers as functional binders in Li-S batteries—a class of materials which has been unexplored for electrode design. By using dendrimers, it is demonstrated that high S loadings (>4 mg cm-2) can be easily achieved using "standard" (not specifically tailored) materials and simple processing methods. An exceptional electrochemical cycling performance was obtained (as compared to cathodes with conventional linear polymeric binders such as carboxymethyl cellulose (CMC) and styrene-butadiene rubber (SBR)) with >100 cycles and 85-98% capacity retention, thus demonstrating the significant utility of this new binder architecture which exhibits critical physicochemical properties and flexible nanoscale design parameters (CNDP's).

  1. Potassium nickel hexacyanoferrate as a high-voltage cathode material for nonaqueous magnesium-ion batteries

    Science.gov (United States)

    Chae, Munseok S.; Hyoung, Jooeun; Jang, Minchul; Lee, Hochun; Hong, Seung-Tae

    2017-09-01

    The magnesium insertion capability of Prussian blue (PB) analogue, potassium nickel hexacyanoferrate K0.86Ni[Fe(CN)6]0.954(H2O)0.766 (KNF-086), is demonstrated as a cathode material for rechargeable magnesium-ion batteries using a conventional organic electrolyte. K1.51Ni[Fe(CN)6]0.954(H2O)0.766 is synthesized first, and potassium ions are electrochemically extracted to prepare the KNF-086 cathode. The electrochemical test cell is composed of KNF-086 as the working electrode, an activated carbon as the counter and reference electrode, and 0.5 M Mg(ClO4)2 in acetonitrile as the electrolyte. The cell shows a reversible magnesium insertion/extraction reaction with a discharge capacity of 48.3 mAh g-1 at a 0.2 C rate, and an average discharge voltage at 2.99 V (vs. Mg/Mg2+) that is the highest among the cathode materials ever reported for magnesium-ion batteries. Elemental analysis and Fourier electron-density map analysis from powder X-ray diffraction data confirm that the magnesium-inserted phase is Mg0.27K0.86Ni[Fe(CN)6]0.954(H2O)0.766 (MKNF-086), and the magnesium ions in MKNF-086 are positioned at the center of the large interstitial cavities of cubic PB. Compared to KNF-086, MKNF-086 exhibits a decreased unit cell parameter (0.8%) and volume (2.4%). These results demonstrate that a PB analogue, potassium nickel hexacyanoferrate, could be utilized as a potential cathode material for conventional organic electrolyte-based magnesium-ion batteries.

  2. Enrico Fermi exhibition at CERN

    CERN Multimedia

    2002-01-01

    A touring exhibition celebrating the centenary of Enrico Fermi's birth in 1901 will be on display at CERN (Main Building, Mezzanine) from 12-27 September. You are cordially invited to the opening celebration on Thursday 12 September at 16:00 (Main Building, Council Chamber), which will include speechs from: Luciano Maiani Welcome and Introduction Arnaldo Stefanini Celebrating Fermi's Centenary in Documents and Pictures Antonino Zichichi The New 'Centro Enrico Fermi' at Via Panisperna Ugo Amaldi Fermi at Via Panisperna and the birth of Nuclear Medicine Jack Steinberger Fermi in Chicago Valentin Telegdi A Close-up of Fermi and the screening of a documentary video about Fermi: Scienziati a Pisa: Enrico Fermi (Scientists at Pisa: Enrico Fermi) created by Francesco Andreotti for La Limonaia from early film, photographs and sound recordings (In Italian, with English subtitles - c. 30 mins). This will be followed by an aperitif on the Mezz...

  3. Crows spontaneously exhibit analogical reasoning.

    Science.gov (United States)

    Smirnova, Anna; Zorina, Zoya; Obozova, Tanya; Wasserman, Edward

    2015-01-19

    Analogical reasoning is vital to advanced cognition and behavioral adaptation. Many theorists deem analogical thinking to be uniquely human and to be foundational to categorization, creative problem solving, and scientific discovery. Comparative psychologists have long been interested in the species generality of analogical reasoning, but they initially found it difficult to obtain empirical support for such thinking in nonhuman animals (for pioneering efforts, see [2, 3]). Researchers have since mustered considerable evidence and argument that relational matching-to-sample (RMTS) effectively captures the essence of analogy, in which the relevant logical arguments are presented visually. In RMTS, choice of test pair BB would be correct if the sample pair were AA, whereas choice of test pair EF would be correct if the sample pair were CD. Critically, no items in the correct test pair physically match items in the sample pair, thus demanding that only relational sameness or differentness is available to support accurate choice responding. Initial evidence suggested that only humans and apes can successfully learn RMTS with pairs of sample and test items; however, monkeys have subsequently done so. Here, we report that crows too exhibit relational matching behavior. Even more importantly, crows spontaneously display relational responding without ever having been trained on RMTS; they had only been trained on identity matching-to-sample (IMTS). Such robust and uninstructed relational matching behavior represents the most convincing evidence yet of analogical reasoning in a nonprimate species, as apes alone have spontaneously exhibited RMTS behavior after only IMTS training. Copyright © 2015 Elsevier Ltd. All rights reserved.

  4. Temperature signal in suspended sediment export from an Alpine catchment

    Science.gov (United States)

    Costa, Anna; Molnar, Peter; Stutenbecker, Laura; Bakker, Maarten; Silva, Tiago A.; Schlunegger, Fritz; Lane, Stuart N.; Loizeau, Jean-Luc; Girardclos, Stéphanie

    2018-01-01

    Suspended sediment export from large Alpine catchments ( > 1000 km2) over decadal timescales is sensitive to a number of factors, including long-term variations in climate, the activation-deactivation of different sediment sources (proglacial areas, hillslopes, etc.), transport through the fluvial system, and potential anthropogenic impacts on the sediment flux (e.g. through impoundments and flow regulation). Here, we report on a marked increase in suspended sediment concentrations observed near the outlet of the upper Rhône River Basin in the mid-1980s. This increase coincides with a statistically significant step-like increase in basin-wide mean air temperature. We explore the possible explanations of the suspended sediment rise in terms of changes in water discharge (transport capacity), and the activation of different potential sources of fine sediment (sediment supply) in the catchment by hydroclimatic forcing. Time series of precipitation and temperature-driven snowmelt, snow cover, and ice melt simulated with a spatially distributed degree-day model, together with erosive rainfall on snow-free surfaces, are tested to explore possible reasons for the rise in suspended sediment concentration. We show that the abrupt change in air temperature reduced snow cover and the contribution of snowmelt, and enhanced ice melt. The results of statistical tests show that the onset of increased ice melt was likely to play a dominant role in the suspended sediment concentration rise in the mid-1980s. Temperature-driven enhanced melting of glaciers, which cover about 10 % of the catchment surface, can increase suspended sediment yields through an increased contribution of sediment-rich glacial meltwater, increased sediment availability due to glacier recession, and increased runoff from sediment-rich proglacial areas. The reduced extent and duration of snow cover in the catchment are also potential contributors to the rise in suspended sediment concentration through

  5. Cathodic Cage Plasma Nitriding: An Innovative Technique

    Directory of Open Access Journals (Sweden)

    R. R. M. de Sousa

    2012-01-01

    Full Text Available Cylindrical samples of AISI 1020, AISI 316, and AISI 420 steels, with different heights, were simultaneously treated by a new technique of ionic nitriding, entitled cathodic cage plasma nitriding (CCPN, in order to evaluate the efficiency of this technique to produce nitrided layers with better properties compared with those obtained using conventional ionic nitriding technique. This method is able to eliminate the edge effect in the samples, promoting a better uniformity of temperature, and consequently, a smaller variation of the thickness/height relation can be obtained. The compound layers were characterized by X-ray diffraction, optical microscopy, and microhardness test profile. The results were compared with the properties of samples obtained with the conventional nitriding, for the three steel types. It was verified that samples treated by CCPN process presented, at the same temperature, a better uniformity in the thickness and absence of the edge effect.

  6. Ion cumulation by conical cathode electrolysis.

    CERN Document Server

    Grishin, V G

    2002-01-01

    Results of solid-state sodium stearate electrolysis with conical and cylindrical cathodes is presented here. Both electric measurement and conical samples destruction can be explained if a stress developing inside the conical sample is much bigger than in the cylindrical case and there is its unlimited amplification along cone slopes. OTHER KEYWORDS: ion, current, solid, symmetry, cumulation, polarization, depolarization, ionic conductor,superionic conductor, ice, crystal, strain, V-center, V-centre, doped crystal, interstitial impurity, intrinsic color center, high pressure technology, Bridgman, anvil, experiment, crowdion, dielectric, proton, layer, defect, lattice, dynamics, electromigration, mobility, muon catalysis, concentration, doping, dopant, conductivity, pycnonuclear reaction, permittivity, dielectric constant, point defects, interstitials, polarizability, imperfection, defect centers, glass, epitaxy, sodium hydroxide, metallic substrate, crystallization, point, tip, susceptibility, ferroelectric, ...

  7. High performance S-type cathode

    Energy Technology Data Exchange (ETDEWEB)

    Chu, M.Y.; Visco, S.J.; De Jonghe, L.C. [PolyPlus Battery Co., Berkeley, CA (United States)

    1997-12-01

    PolyPlus Battery Company (PPBC) is developing an advanced lithium polymer rechargeable battery based on proprietary positive electrode chemistry. In one formulation, this electrode contains elemental sulfur, either free or in association with secondary materials that promote its utilization. Batteries based on this cathode chemistry offer high steady-state (>250 W/kg) and high peak power densities (3,000 W/kg), in a low cost and environmentally benign format. High energy density, in excess of 500 Wh/kg (600 Wh/l) can also be achieved. The high power and energy densities, along with the low toxicity and low cost of materials used in the PolyPlus solid-state cells make this battery exceptionally attractive for both hybrid and electric vehicles, and for consumer electronic applications.

  8. Synchrotron X-Ray Studies of Model SOFC Cathodes, Part I: Thin Film Cathodes.

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Kee-Chul; Ingram, Brian; Ilavsky, Jan; Lee, Shiwoo; Fuoss, Paul; You, Hoydoo

    2017-11-15

    We present synchrotron x-ray investigations of thin film La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) model cathodes for solid oxide fuel cells, grown on electrolyte substrates by pulse laser deposition, in situ during half-cell operations. We observed dynamic segregations of cations, such as Sr and Co, on the surfaces of the film cathodes. The effects of temperature, applied potentials, and capping layers on the segregations were investigated using a surfacesensitive technique of total external reflection x-ray fluorescence. We also studied patterned thin film LSCF cathodes using high-resolution micro-beam diffraction measurements. We find chemical expansion decreases for narrow stripes. This suggests the expansion is dominated by the bulk pathway reactions. The chemical expansion vs. the distance from the electrode contact was measured at three temperatures and an oxygen vacancy activation energy was estimated to be ~1.4 eV.

  9. Using cathode spacers to minimize reactor size in air cathode microbial fuel cells

    KAUST Repository

    Yang, Qiao

    2012-04-01

    Scaling up microbial fuel cells (MFCs) will require more compact reactor designs. Spacers can be used to minimize the reactor size without adversely affecting performance. A single 1.5mm expanded plastic spacer (S1.5) produced a maximum power density (973±26mWm -2) that was similar to that of an MFC with the cathode exposed directly to air (no spacer). However, a very thin spacer (1.3mm) reduced power by 33%. Completely covering the air cathode with a solid plate did not eliminate power generation, indicating oxygen leakage into the reactor. The S1.5 spacer slightly increased columbic efficiencies (from 20% to 24%) as a result of reduced oxygen transfer into the system. Based on operating conditions (1000ς, CE=20%), it was estimated that 0.9Lh -1 of air would be needed for 1m 2 of cathode area suggesting active air flow may be needed for larger scale MFCs. © 2012 Elsevier Ltd.

  10. High Performance Cathodes for Li-Air Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Xing, Yangchuan

    2013-08-22

    The overall objective of this project was to develop and fabricate a multifunctional cathode with high activities in acidic electrolytes for the oxygen reduction and evolution reactions for Li-air batteries. It should enable the development of Li-air batteries that operate on hybrid electrolytes, with acidic catholytes in particular. The use of hybrid electrolytes eliminates the problems of lithium reaction with water and of lithium oxide deposition in the cathode with sole organic electrolytes. The use of acid electrolytes can eliminate carbonate formation inside the cathode, making air breathing Li-air batteries viable. The tasks of the project were focused on developing hierarchical cathode structures and bifunctional catalysts. Development and testing of a prototype hybrid Li-air battery were also conducted. We succeeded in developing a hierarchical cathode structure and an effective bifunctional catalyst. We accomplished integrating the cathode with existing anode technologies and made a pouch prototype Li-air battery using sulfuric acid as catholyte. The battery cathodes contain a nanoscale multilayer structure made with carbon nanotubes and nanofibers. The structure was demonstrated to improve battery performance substantially. The bifunctional catalyst developed contains a conductive oxide support with ultra-low loading of platinum and iridium oxides. The work performed in this project has been documented in seven peer reviewed journal publications, five conference presentations, and filing of two U.S. patents. Technical details have been documented in the quarterly reports to DOE during the course of the project.

  11. Magnetically insulated coaxial vacuum diode with partial space-charge-limited explosive emission from edge-type cathode

    Energy Technology Data Exchange (ETDEWEB)

    Belomyttsev, S. Ya.; Rostov, V. V.; Romanchenko, I. V. [Institute of High Current Electronics SB RAS, 2/3 Akademichesky Avenue, 634055 Tomsk (Russian Federation); Shunailov, S. A.; Sharypov, K. A.; Shpak, V. G.; Ulmaskulov, M. R. [Institute of Electrophysics UB RAS, 106 Amundsen Str., 620016 Ekaterinburg (Russian Federation); Kolomiets, M. D. [Ural Federal University, 19 Mira Str., 620002 Ekaterinburg (Russian Federation); Mesyats, G. A. [P. N. Lebedev Physical Institute, RAS, 53 Lenin Avenue, 119991 Moscow (Russian Federation); Yalandin, M. I. [Institute of Electrophysics UB RAS, 106 Amundsen Str., 620016 Ekaterinburg (Russian Federation); P. N. Lebedev Physical Institute, RAS, 53 Lenin Avenue, 119991 Moscow (Russian Federation)

    2016-01-14

    The vacuum current associated with any type of electron emission for arbitrary configuration of the diode depends on the combination of the applied electric field and vacuum space charge (VSC) field created by the current. Such fundamental statement should give very close links between the diode current and the normalized cathode field θ which has been introduced by Forbes in 2008 for planar diodes as a reduction in the cathode surface field: θ = field-with/field-without VSC. This article reports the universal approximation of the type of cos(πθ/2) that is the ratio of the actual current and the fully space-charge-limited current. Also, the theoretical treatment and the experimental method of determination of the dynamic emissive characteristics of the macroscopic explosive emission from edge-type cathodes in the coaxial diode are developed. The experimental results obtained with a picosecond time reference between the cathode voltage and the onset of the high-current electron beam exhibit a good coincidence with the theoretical predictions. The presented methods enable the analysis of a real-time-resolved dynamics associated with the dense, magnetized electron beam formation, acceleration and drift motion, including kinematic effects and the phase-stable excitation of high-power microwave oscillators.

  12. Power generation using spinel manganese-cobalt oxide as a cathode catalyst for microbial fuel cell applications.

    Science.gov (United States)

    Mahmoud, Mohamed; Gad-Allah, Tarek A; El-Khatib, K M; El-Gohary, Fatma

    2011-11-01

    This study focused on the use of spinel manganese-cobalt (Mn-Co) oxide, prepared by a solid state reaction, as a cathode catalyst to replace platinum in microbial fuel cells (MFCs) applications. Spinel Mn-Co oxides, with an Mn/Co atomic ratios of 0.5, 1, and 2, were prepared and examined in an air cathode MFCs which was fed with a molasses-laden synthetic wastewater and operated in batch mode. Among the three Mn-Co oxide cathodes and after 300 h of operation, the Mn-Co oxide catalyst with Mn/Co atomic ratio of 2 (MnCo-2) exhibited the highest power generation 113 mW/m2 at cell potential of 279 mV, which were lower than those for the Pt catalyst (148 mW/m2 and 325 mV, respectively). This study indicated that using spinel Mn-Co oxide to replace platinum as a cathodic catalyst enhances power generation, increases contaminant removal, and substantially reduces the cost of MFCs. Copyright © 2011 Elsevier Ltd. All rights reserved.

  13. Enhanced hydroxyl radical generation in the combined ozonation and electrolysis process using carbon nanotubes containing gas diffusion cathode.

    Science.gov (United States)

    Wu, Donghai; Lu, Guanghua; Zhang, Ran; Lin, Qiuhong; Yan, Zhenhua; Liu, Jianchao; Li, Yi

    2015-10-01

    Combination of ozone together with electrolysis (ozone-electrolysis) is a promising wastewater treatment technology. This work investigated the potential use of carbon nanotube (CNT)-based gas diffusion cathode (GDC) for ozone-electrolysis process employing hydroxyl radicals (·OH) production as an indicator. Compared with conventional active carbon (AC)-polytetrafluoroethylene (PTFE) and carbon black (CB)-PTFE cathodes, the production of ·OH in the coupled process was improved using CNTs-PTFE GDC. Appropriate addition of acetylene black (AB) and pore-forming agent Na2SO4 could enhance the efficiency of CNTs-PTFE GDC. The optimum GDC composition was obtained by response surface methodology (RSM) analysis and was determined as CNTs 31.2 wt%, PTFE 60.6 wt%, AB 3.5 wt%, and Na2SO4 4.7 wt%. Moreover, the optimized CNT-based GDC exhibited much more effective than traditional Ti and graphite cathodes in Acid Orange 7 (AO7) mineralization and possessed the desirable stability without performance decay after ten times reaction. The comparison tests revealed that peroxone reaction was the main pathway of ·OH production in the present system, and cathodic reduction of ozone could significantly promote ·OH generation. These results suggested that application of CNT-based GDC offers considerable advantages in ozone-electrolysis of organic wastewater.

  14. High sulfur-containing carbon polysulfide polymer as a novel cathode material for lithium-sulfur battery.

    Science.gov (United States)

    Zhang, Yiyong; Peng, Yueying; Wang, Yunhui; Li, Jiyang; Li, He; Zeng, Jing; Wang, Jing; Hwang, Bing Joe; Zhao, Jinbao

    2017-09-12

    The lithium-sulfur battery, which offers a high energy density and is environmental friendly, is a promising next generation of rechargeable energy storage system. However, despite these attractive attributes, the commercialization of lithium-sulfur battery is primarily hindered by the parasitic reactions between the Li metal anode and dissolved polysulfide species from the cathode during the cycling process. Herein, we synthesize the sulfur-rich carbon polysulfide polymer and demonstrate that it is a promising cathode material for high performance lithium-sulfur battery. The electrochemical studies reveal that the carbon polysulfide polymer exhibits superb reversibility and cycle stability. This is due to that the well-designed structure of the carbon polysulfide polymer has several advantages, especially, the strong chemical interaction between sulfur and the carbon framework (C-S bonds) inhibits the shuttle effect and the π electrons of the carbon polysulfide compound enhance the transfer of electrons and Li+. Furthermore, as-prepared carbon polysulfide polymer-graphene hybrid cathode achieves outstanding cycle stability and relatively high capacity. This work highlights the potential promise of the carbon polysulfide polymer as the cathode material for high performance lithium-sulfur battery.

  15. Hydrodynamic and suspended sediment transport controls on river mouth morphology

    Science.gov (United States)

    Falcini, F.; Piliouras, A.; Garra, R.; Guerin, A.; Jerolmack, D. J.; Rowland, J.; Paola, C.

    2014-01-01

    mouths building into standing bodies of water have strikingly varied growth habits. This presents a compelling pattern formation problem that is also of great practical relevance for subsurface prediction and managing coastal wetlands. Here we present a generalized 2.5-dimensional potential vorticity (PV) theory that explains sedimentation patterns of a sediment-laden stationary jet by coupling an understanding of vorticity with suspended sediment concentration fields. We explore the physical meaning of this new sediment-PV definition, and its impact on outflow depositional patterns, by analyzing data from a shallow wall-bounded plane jet experiment and by discussing new theoretical insights. A key result is that lateral advection and diffusion of suspended sediment are directly proportional to jet vorticity, a feature that reveals the mechanistic process that forms elongated channels by focused levee deposition. The new PV theory constitutes a more generalized mathematical framework that expands the Rouse theory for the equilibrium of suspended sediment.

  16. Neutral hydrophilic cathode catalyst binders for microbial fuel cells

    KAUST Repository

    Saito, Tomonori

    2011-01-01

    Improving oxygen reduction in microbial fuel cell (MFC) cathodes requires a better understanding of the effects of the catalyst binder chemistry and properties on performance. A series of polystyrene-b-poly(ethylene oxide) (PS-b-PEO) polymers with systematically varying hydrophilicity were designed to determine the effect of the hydrophilic character of the binder on cathode performance. Increasing the hydrophilicity of the PS-b-PEO binders enhanced the electrochemical response of the cathode and MFC power density by ∼15%, compared to the hydrophobic PS-OH binder. Increased cathode performance was likely a result of greater water uptake by the hydrophilic binder, which would increase the accessible surface area for oxygen reduction. Based on these results and due to the high cost of PS-b-PEO, the performance of an inexpensive hydrophilic neutral polymer, poly(bisphenol A-co-epichlorohydrin) (BAEH), was examined in MFCs and compared to a hydrophilic sulfonated binder (Nafion). MFCs with BAEH-based cathodes with two different Pt loadings initially (after 2 cycles) had lower MFC performance (1360 and 630 mW m-2 for 0.5 and 0.05 mg Pt cm-2) than Nafion cathodes (1980 and 1080 mW m -2 for 0.5 and 0.05 mg Pt cm-2). However, after long-term operation (22 cycles, 40 days), power production of each cell was similar (∼1200 and 700-800 mW m-2 for 0.5 and 0.05 mg Pt cm-2) likely due to cathode biofouling that could not be completely reversed through physical cleaning. While binder chemistry could improve initial electrochemical cathode performance, binder materials had less impact on overall long-term MFC performance. This observation suggests that long-term operation of MFCs will require better methods to avoid cathode biofouling. © 2011 The Royal Society of Chemistry.

  17. Importance of OH(-) transport from cathodes in microbial fuel cells.

    Science.gov (United States)

    Popat, Sudeep C; Ki, Dongwon; Rittmann, Bruce E; Torres, César I

    2012-06-01

    Cathodic limitation in microbial fuel cells (MFCs) is considered an important hurdle towards practical application as a bioenergy technology. The oxygen reduction reaction (ORR) needs to occur in MFCs under significantly different conditions compared to chemical fuel cells, including a neutral pH. The common reason cited for cathodic limitation is the difficulty in providing protons to the catalyst sites. Here, we show that it is not the availability of protons, but the transport of OH(-) from the catalyst layer to the bulk liquid that largely governs cathodic potential losses. OH(-) is a product of an ORR mechanism that has not been considered dominant before. The accumulation of OH(-) at the catalyst sites results in an increase in the local cathode pH, resulting in Nernstian concentration losses. For Pt-based gas-diffusion cathodes, using polarization curves developed in unbuffered and buffered solutions, we quantified this loss to be >0.3 V at a current density of 10 Am(-2) . We show that this loss can be partially overcome by replacing the Nafion binder used in the cathode catalyst layer with an anion-conducting binder and by providing additional buffer to the cathode catalyst directly in the form of CO(2) , which results in enhanced OH(-) transport. Our results provide a comprehensive analysis of cathodic limitations in MFCs and should allow researchers to develop and select materials for the construction of MFC cathodes and identify operational conditions that will help minimize Nernstian concentration losses due to pH gradients. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  18. Distribution and origin of suspended matter and organic carbon pools in the Tana River Basin, Kenya

    Directory of Open Access Journals (Sweden)

    F. Tamooh

    2012-08-01

    fraction. Dissolved organic carbon (DOC concentrations were highest during the end of wet season (2.1 to 6.9 mg l−1, with stable isotope signatures generally between −28 and −22‰. A consistent downstream decrease in % organic carbon (%OC was observed for soils, riverine sediments, and suspended matter. This was likely due to better preservation of the organic fraction in colder high altitude regions, with loss of carbon during downstream spiraling. δ13C values for soil and sediment did not exhibit clear altitudinal patterns, but values reflect the full spectrum from C3-dominated to C4-dominated sites. Very low ratios of organic carbon to mineral surface area (OC : SA were found in reservoir sediments and suspended matter in the lower Tana River, indicating that these are stable OC pools which have undergone extensive degradation. Overall, our study demonstrates that substantial differences occur in both the quantities and origin of suspended sediments and organic carbon along the river profile in this tropical river basin, as well as seasonal differences in the mechanisms causing such variations.

  19. Iron phosphate materials as cathodes for lithium batteries

    CERN Document Server

    Prosini, Pier Paolo

    2011-01-01

    ""Iron Phosphate Materials as Cathodes for Lithium Batteries"" describes the synthesis and the chemical-physical characteristics of iron phosphates, and presents methods of making LiFePO4 a suitable cathode material for lithium-ion batteries. The author studies carbon's ability to increase conductivity and to decrease material grain size, as well as investigating the electrochemical behaviour of the materials obtained. ""Iron Phosphate Materials as Cathodes for Lithium Batteries"" also proposes a model to explain lithium insertion/extraction in LiFePO4 and to predict voltage profiles at variou

  20. Functionally Graded Cathodes for Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    YongMan Choi; Meilin Liu

    2006-09-30

    This DOE SECA project focused on both experimental and theoretical understanding of oxygen reduction processes in a porous mixed-conducting cathode in a solid oxide fuel cell (SOFC). Elucidation of the detailed oxygen reduction mechanism, especially the rate-limiting step(s), is critical to the development of low-temperature SOFCs (400 C to 700 C) and to cost reduction since much less expensive materials may be used for cell components. However, cell performance at low temperatures is limited primarily by the interfacial polarization resistances, specifically by those associated with oxygen reduction at the cathode, including transport of oxygen gas through the porous cathode, the adsorption of oxygen onto the cathode surface, the reduction and dissociation of the oxygen molecule (O{sub 2}) into the oxygen ion (O{sup 2-}), and the incorporation of the oxygen ion into the electrolyte. In order to most effectively enhance the performance of the cathode at low temperatures, we must understand the mechanism and kinetics of the elementary processes at the interfaces. Under the support of this DOE SECA project, our accomplishments included: (1) Experimental determination of the rate-limiting step in the oxygen reduction mechanism at the cathode using in situ FTIR and Raman spectroscopy, including surface- and tip-enhanced Raman spectroscopy (SERS and TERS). (2) Fabrication and testing of micro-patterned cathodes to compare the relative activity of the TPB to the rest of the cathode surface. (3) Construction of a mathematical model to predict cathode performance based on different geometries and microstructures and analyze the kinetics of oxygen-reduction reactions occurring at charged mixed ionic-electronic conductors (MIECs) using two-dimensional finite volume models with ab initio calculations. (4) Fabrication of cathodes that are graded in composition and microstructure to generate large amounts of active surface area near the cathode/electrolyte interface using a

  1. Cathode erosion tests for 30 kW arcjets

    Science.gov (United States)

    Deininger, W. D.; Chopra, A.; Goodfellow, K. D.

    1989-01-01

    Endurance tests (100 hours) were conducted to examine the effects of geometry and spacing on 30 kW arcjet cathode erosion. The effects of input power source ripple were also examined. The preliminary results from a 413 hour endurance test are also discussed. This test was terminated voluntarily. The condition of the nozzle, boron nitride propellant injector, and cathode are discussed. A modeling effort is described which is aimed at quantifying the cathode tip heating phenomena. The results of the experiments and the model are compared.

  2. Development of Electron Gun of Carbon Nanotube Cathode

    CERN Document Server

    Hozumi, Yasufumi; Ohsawa, Satoshi; Sugimura, Takashi

    2005-01-01

    We are developing high brightness electron guns utilizing carbon nanotube (CNT) cathodes. Recently, we succeeded to achieved field emission currents to 0.2 A (3 A/cm2) from a triode type CNT cathode of 3 mm diameter. The emission tests were performed at DC100kV acceleration voltage in pulse operations of 50 Hz using 6 nsec pulses. The emission currents were very stable for long term periods of 3 weeks. Photo emission tests from CNT cathode by 266nm laser pulses is also due to be reported simultaneously.

  3. Dynamic transport of suspended sediment by solitary wave: Experimental study

    Science.gov (United States)

    cho, JaeNam; Kim, DongHyun; Hwang, KyuNam; Lee, SeungOh

    2016-04-01

    Solitary waves are able to transport a large amount of suspended sediment when approaching on the beach, which sometimes causes - serious beach erosion, especially in the east and south coastal lines in Korea. But it has rarely been known about the method how to evaluate or estimate the amount of beach erosion caused by solitary waves. Experimental assessment is necessary to comprehend the process of sediment transport on a slope. The prismatic rectangular channel is 12 m long, 0.8 m wide, and 0.75 m high. A sluice gate is applied at prismatic channel in order to produce the solitary waves. Upstream water depth is more than channel water depth and the sluice gate is suddenly opened to simulate conditions of solitary waves. A sand slope with a 1/6 and a sediment thickness is 0.03 m. The experimental sediments are used anthracite (d_50=1.547 mm ,C_u=1.38) and Jumoonjin sand (d_50=0.627 mm ,C_u=1.68). Specific laboratory equipment are designed to collect suspended sediment samples at the same time along the wave propagation at 5 points with evenly space. Each amount of sampling is approximately 25 ml and they are completely dried in oven over 24 hours according to the USGS (Guideline and standard techniques and method 3-C4). Two video cameras (Model No. : Sony, HDR-XR550) are mounted for capturing images at top and side-view when the processes of solitary wave and run up/down on slope. Also, this study are analyzed the correlation between Suspended sediment concentration and turbidity. Also, this study are analyzed the correlation between suspended sediment concentration and turbidity. Turbidity is used to verify suspended sediment concentration. Dimensionless analyses of experimental results carried out in this study. One dimensionless parameter is expressed with pressure of solitary wave on a slope to suspended sediment concentration, which is concerned about lifting force. The other is relate to drag force presenting with run up/down velocity on a slope and

  4. Design of a LC-tuned magnetically suspended rotating gyroscope

    Science.gov (United States)

    Jin, Lichuan; Zhang, Huaiwu; Zhong, Zhiyong

    2011-04-01

    A inductor-capacitor (LC) tuned magnetically suspended rotating gyroscope prototype is designed and analyzed. High permeability ferrite cores are used for providing suspension force, and the rotation system is designed using the switched reluctance motor (SRM) principle. According to the LC-tuned principle, magnetic suspension force expression has been derived. The electromagnetic properties of the gyroscope are simulated by the Ansoft Maxwell software. And our result is expected to be able to serve as a prototype of micro-electromechanical system (MEMS) magnetically suspended rotating gyroscope in future practical applications.

  5. Quantum Hall effect in multi-terminal suspended graphene devices

    Science.gov (United States)

    Ghahari, Fereshte; Zhao, Yue; Bolotin, Kirill; Kim, Philip

    2010-03-01

    The integer and fractional quantum hall effects have been already observed in two terminal suspended graphene devices. However in this two probe device geometry, mixing between magnetoresistance ρxx and Hall resistance ρxy for incompletely developed quantum Hall states leads to substantial deviation of conductance plateaus values. In this talk, we present the experimental results from four terminal suspended graphene devices. The quality of quantum Hall effect will be discussed in muti-terminal device geometry in conjunction with the current-induced annealing process to improve the quality of graphene samples.

  6. Colorimetry Technique for Scalable Characterization of Suspended Graphene.

    Science.gov (United States)

    Cartamil-Bueno, Santiago J; Steeneken, Peter G; Centeno, Alba; Zurutuza, Amaia; van der Zant, Herre S J; Houri, Samer

    2016-11-09

    Previous statistical studies on the mechanical properties of chemical-vapor-deposited (CVD) suspended graphene membranes have been performed by means of measuring individual devices or with techniques that affect the material. Here, we present a colorimetry technique as a parallel, noninvasive, and affordable way of characterizing suspended graphene devices. We exploit Newton's rings interference patterns to study the deformation of a double-layer graphene drum 13.2 μm in diameter when a pressure step is applied. By studying the time evolution of the deformation, we find that filling the drum cavity with air is 2-5 times slower than when it is purged.

  7. In-FEEP ion beam neutralization with thermionic and field emission cathodes

    Science.gov (United States)

    Marrese, C.; Polk, J.; Mueller, J.; Owens, A.; Tajmar, M.; Fink, R.; Spindt, C.

    2002-01-01

    Charge neutralization of an In-FEEP thruster was demonstrated with three different electron sources by zeroing the floating potential of the thruster and neutralizer system. The three cathodes used in the investigation include a mixed metal thermionic cathode, a carbon nanotube field emission cathode, and a Spindt-type Mo field emission array cathode.

  8. Enhanced non-volatile resistive switching in suspended single-crystalline ZnO nanowire with controllable multiple states

    Science.gov (United States)

    Zhang, Rui; Pang, Wei; Zhang, Qing; Chen, Yan; Chen, Xuejiao; Feng, Zhihong; Yang, Jianhua; Zhang, Daihua

    2016-08-01

    Resistive switching nanostructures are a promising candidate for next-generation non-volatile memories. In this report, we investigate the switching behaviors of single-crystalline ZnO nanowires suspended in air. They exhibit significantly higher current density, lower switching voltage, and more pronounced multiple conductance states compared to nanowires in direct contact with substrate. We attribute the effect to enhanced Joule heating efficiency, reduced surface scattering, and more significantly, the positive feedback established between the current density and local temperature in the suspended nanowires. The proposed mechanism has been quantitatively examined by finite element simulations. We have also demonstrated an innovative approach to initiating the current-temperature mutual enhancement through illumination by ultraviolet light, which further confirmed our hypothesis and enabled even greater enhancement. Our work provides further insight into the resistive switching mechanism of single-crystalline one-dimensional nanostructures, and suggests an effective means of performance enhancement and device optimization.

  9. Effect of Particle Size and Operating Conditions on Pt3Co PEMFC Cathode Catalyst Durability

    Directory of Open Access Journals (Sweden)

    Mallika Gummalla

    2015-05-01

    Full Text Available The initial performance and decay trends of polymer electrolyte membrane fuel cells (PEMFC cathodes with Pt3Co catalysts of three mean particle sizes (4.9 nm, 8.1 nm, and 14.8 nm with identical Pt loadings are compared. Even though the cathode based on 4.9 nm catalyst exhibited the highest initial electrochemical surface area (ECA and mass activity, the cathode based on 8.1 nm catalyst showed better initial performance at high currents. Owing to the low mass activity of the large particles, the initial performance of the 14.8 nm Pt3Co-based electrode was the lowest. The performance decay rate of the electrodes with the smallest Pt3Co particle size was the highest and that of the largest Pt3Co particle size was lowest. Interestingly, with increasing number of decay cycles (0.6 to 1.0 V, 50 mV/s, the relative improvement in performance of the cathode based on 8.1 nm Pt3Co over the 4.9 nm Pt3Co increased, owing to better stability of the 8.1 nm catalyst. The electron microprobe analysis (EMPA of the decayed membrane-electrode assembly (MEA showed that the amount of Co in the membrane was lower for the larger particles, and the platinum loss into the membrane also decreased with increasing particle size. This suggests that the higher initial performance at high currents with 8.1 nm Pt3Co could be due to lower contamination of the ionomer in the electrode. Furthermore, lower loss of Co from the catalyst with increased particle size could be one of the factors contributing to the stability of ECA and mass activity of electrodes with larger cathode catalyst particles. To delineate the impact of particle size and alloy effects, these results are compared with prior work from our research group on size effects of pure platinum catalysts. The impact of PEMFC operating conditions, including upper potential, relative humidity, and temperature on the alloy catalyst decay trends, along with the EMPA analysis of the decayed MEAs, are reported.

  10. Color Television Projection System Using Three Cathode Ray Tubes.

    Science.gov (United States)

    1982-03-01

    categories, specifically: light valves, scophony , lasers, liquid crystal modulation, and cathode ray tubes. Of these display techniques, the light valves 3...and have comparatively short life times associated with critical components. Both scophony and laser techniques utilize mechanical beam scanning

  11. High Performance Fe-Co Based SOFC Cathodes

    DEFF Research Database (Denmark)

    Kammer Hansen, Kent; Hansen, Karin Vels; Mogensen, Mogens Bjerg

    2010-01-01

    With the aim of reducing the temperature of the solid oxide fuel cell (SOFC), a new high-performance perovskite cathode has been developed. An area-specific resistance (ASR) as low as 0.12 Ωcm2 at 600 °C was measured by electrochemical impedance spectroscopy (EIS) on symmetrical cells. The cathode...... is a composite between (Gd0.6Sr0.4)0.99Fe0.8Co0.2O3-δ (GSFC) and Ce0.9Gd0.1O1.95 (CGO10). Examination of the microstructure of the cathodes by scanning electron microscopy (SEM) revealed a possibility of further optimisation of the microstructure in order to increase the performance of the cathodes. It also...

  12. Odyssey of Multivalent Cathode Materials: Open Questions and Future Challenges.

    Science.gov (United States)

    Canepa, Pieremanuele; Sai Gautam, Gopalakrishnan; Hannah, Daniel C; Malik, Rahul; Liu, Miao; Gallagher, Kevin G; Persson, Kristin A; Ceder, Gerbrand

    2017-03-08

    The rapidly expanding field of nonaqueous multivalent intercalation batteries offers a promising way to overcome safety, cost, and energy density limitations of state-of-the-art Li-ion battery technology. We present a critical and rigorous analysis of the increasing volume of multivalent battery research, focusing on a wide range of intercalation cathode materials and the mechanisms of multivalent ion insertion and migration within those frameworks. The present analysis covers a wide variety of material chemistries, including chalcogenides, oxides, and polyanions, highlighting merits and challenges of each class of materials as multivalent cathodes. The review underscores the overlap of experiments and theory, ranging from charting the design metrics useful for developing the next generation of MV-cathodes to targeted in-depth studies rationalizing complex experimental results. On the basis of our critical review of the literature, we provide suggestions for future multivalent cathode studies, including a strong emphasis on the unambiguous characterization of the intercalation mechanisms.

  13. A High Performance Cathode Heater for Hall Thrusters Project

    Data.gov (United States)

    National Aeronautics and Space Administration — High current hollow cathodes are the baseline electron source for next generation high power Hall thrusters. Currently for electron sources providing current levels...

  14. NMR study of hydrogen in cathodically charged Inconel 718

    Energy Technology Data Exchange (ETDEWEB)

    Raizman, A.; Barak, J.; Zamir, D. (Israel Atomic Energy Commission, Yavne. Soreq Nuclear Research Center); Eliezer, D. (Ben-Gurion Univ. of the Negev, Beersheba (Israel))

    1983-11-01

    An NMR signal of protons in cathodically charged Inconel 718 has been detected. T/sub 1/, T/sub 2/, line shift and line width have been measured. Conclusions about hydrogen behavior in Inconel have been drawn.

  15. Cold cathode rf guns based study on field emission

    Directory of Open Access Journals (Sweden)

    Xiangkun Li

    2013-12-01

    Full Text Available Recently cold cathodes based on field emission have drawn attention and been considered to drive accelerators and free electron lasers, due to the progress in field emitter arrays and planar emitters like diamond films. In this paper, we reviewed the characteristics of field emission in rf fields. Simulations of S-band rf guns consisting of a cathode cell and a full cell were done. We showed that a shorter cathode cell with a length of 0.25–0.3 of λ/2 is in favor of obtaining both low emittance and low energy spread bunches when the amplitude of electric field on the cathode surface ranges from 60 to 80  MV/m. A single cell test cavity has been installed to study field emission of diamond films and the measured beam current showed a good agreement with theoretical calculations.

  16. Investigation of plasma flow in vacuum arc with hot cathode

    Science.gov (United States)

    Amirov, R.; Vorona, N.; Gavrikov, A.; Lizyakin, G.; Polistchook, V.; Samoylov, I.; Smirnov, V.; Usmanov, R.; Yartsev, I.

    2014-11-01

    One of the crucial problems which appear under development of plasma technology processing of spent nuclear fuel (SNF) is the design of plasma source. The plasma source must use solid SNF as a raw material. This article is devoted to experimental study of vacuum arc with hot cathode made of gadolinium that may consider as the simple model of SNF. This vacuum discharge was investigated in wide range of parameters. During the experiments arc current and voltage, cathode temperature, and heat flux to the cathode were measured. The data on plasma spectrum and electron temperature were obtained. It was shown that external heating of the cathode allows change significantly the main parameters of plasma. It was established by spectral and probe methods that plasma jet in studied discharge may completely consist of single charged ions.

  17. Scandate Cathode for High Power Long Life Electric Propulsion Project

    Data.gov (United States)

    National Aeronautics and Space Administration — Scandate cathodes are proposed as a way to boost performance and life for electric space propulsion systems. This company has recently demonstrated breakthrough...

  18. Lithium sulfur batteries and electrolytes and sulfur cathodes thereof

    Science.gov (United States)

    Visco, Steven J.; Goncharenko, Nikolay; Nimon, Vitaliy; Petrov, Alexei; Nimon, Yevgeniy S.; De Jonghe, Lutgard C.; Katz, Bruce D.; Loginova, Valentina

    2017-05-23

    Lithium sulfur battery cells that use water as an electrolyte solvent provide significant cost reductions. Electrolytes for the battery cells may include water solvent for maintaining electroactive sulfur species in solution during cell discharge and a sufficient amount of a cycle life-enhancing compound that facilitates charging at the cathode. The combination of these two components enhances one or more of the following cell attributes: energy density, power density and cycle life. For instance, in applications where cost per Watt-Hour (Wh) is paramount, such as grid storage and traction applications, the use of an aqueous electrolyte in combination with inexpensive sulfur as the cathode active material can be a key enabler for the utility and automotive industries, for example, providing a cost effective and compact solution for load leveling, electric vehicles and renewable energy storage. Sulfur cathodes, and methods of fabricating lithium sulfur cells, in particular for loading lithium sulfide into the cathode structures, provide further advantages.

  19. Verification of high efficient broad beam cold cathode ion source

    Energy Technology Data Exchange (ETDEWEB)

    Abdel Reheem, A. M., E-mail: amreheem2009@yahoo.com [Accelerators and Ion Sources Department, Nuclear Research Center, Atomic Energy Authority, P.N.13759, Cairo (Egypt); Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT), Atomic Energy Authority (AEA), Cairo (Egypt); Ahmed, M. M. [Physics Department, Faculty of Science, Helwan University, Cairo (Egypt); Abdelhamid, M. M.; Ashour, A. H. [Radiation Physics Department, National Center for Radiation Research and Technology (NCRRT), Atomic Energy Authority (AEA), Cairo (Egypt)

    2016-08-15

    An improved form of cold cathode ion source has been designed and constructed. It consists of stainless steel hollow cylinder anode and stainless steel cathode disc, which are separated by a Teflon flange. The electrical discharge and output characteristics have been measured at different pressures using argon, nitrogen, and oxygen gases. The ion exit aperture shape and optimum distance between ion collector plate and cathode disc are studied. The stable discharge current and maximum output ion beam current have been obtained using grid exit aperture. It was found that the optimum distance between ion collector plate and ion exit aperture is equal to 6.25 cm. The cold cathode ion source is used to deposit aluminum coating layer on AZ31 magnesium alloy using argon ion beam current which equals 600 μA. Scanning electron microscope and X-ray diffraction techniques used for characterizing samples before and after aluminum deposition.

  20. Electrochemical performance of lanthanum calcium cobalt ferrite cathode interfaced to LAMOX electrolyte

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Cheng-Wei; Tsai, Dah-Shyang; Jin, Tsu-Yung; Chung, Wen-Hung [Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106 (Taiwan); Chou, Chen-Chia [Department of Mechanical Engineering, National Taiwan University of Science and Technology, Taipei 106 (Taiwan)

    2008-05-15

    Lanthanum calcium cobalt ferrite (LCCF), a potential cathode composition for the LAMOX electrolyte, is studied on its electrocatalytic performance in oxygen reduction reaction (ORR) using impedance spectroscopy. Nyquist plots of LCCF impedance at 600-800 C display two arcs, in which the low-frequency arc is constantly larger than the high-frequency arc. When interfaced to the electrolyte containing 20 mol% tungsten, the ORR polarization resistance of LCCF exhibits a strong temperature dependency whose activation energy increases with increasing Co content, 190 (10 mol%)-220 (90 mol%) kJ mol{sup -} {sup 1}. Among the cathode compositions, LCCF82 (80 mol% Co) exhibits the best catalytic performance. Its zero-bias ORR resistance is 242.4 at 600 C, 0.845 {omega} cm{sup 2} at 800 C, along with the capacitance 7.79 (600 C), 14.93 mF cm{sup -} {sup 2} (800 C). The ORR resistance of LCCF82 decreases with increasing dc bias at 600 and 700 C, hardly changes at 800 C. The electrocatalytic activity of LCCF82 is also influenced by the tungsten content of its interfacing electrolyte. The exchange current density of LCCF82 correlates positively with the electrolyte ion conductivity which increases with decreasing tungsten content. (author)

  1. Work function and surface stability of tungsten-based thermionic electron emission cathodes

    Science.gov (United States)

    Jacobs, Ryan; Morgan, Dane; Booske, John

    2017-11-01

    Materials that exhibit a low work function and therefore easily emit electrons into vacuum form the basis of electronic devices used in applications ranging from satellite communications to thermionic energy conversion. W-Ba-O is the canonical materials system that functions as the thermionic electron emitter commercially used in a range of high-power electron devices. However, the work functions, surface stability, and kinetic characteristics of a polycrystalline W emitter surface are still not well understood or characterized. In this study, we examined the work function and surface stability of the eight lowest index surfaces of the W-Ba-O system using density functional theory methods. We found that under the typical thermionic cathode operating conditions of high temperature and low oxygen partial pressure, the most stable surface adsorbates are Ba-O species with compositions in the range of Ba0.125O-Ba0.25O per surface W atom, with O passivating all dangling W bonds and Ba creating work function-lowering surface dipoles. Wulff construction analysis reveals that the presence of O and Ba significantly alters the surface energetics and changes the proportions of surface facets present under equilibrium conditions. Analysis of previously published data on W sintering kinetics suggests that fine W particles in the size range of 100-500 nm may be at or near equilibrium during cathode synthesis and thus may exhibit surface orientation fractions well described by the calculated Wulff construction.

  2. Lipon coatings for high voltage and high temperature Li-ion battery cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Dudney, Nancy J.; Liang, Chengdu; Nanda, Jagjit; Veith, Gabriel M.; Kim, Yoongu; Martha, Surendra Kumar

    2017-02-14

    A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.

  3. Lipon coatings for high voltage and high temperature Li-ion battery cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Dudney, Nancy J.; Liang, Chengdu; Nanda, Jagjit; Veith, Gabriel M.; Kim, Yoongu; Martha, Surendra Kumar

    2017-12-05

    A lithium ion battery includes an anode and a cathode. The cathode includes a lithium, manganese, nickel, and oxygen containing compound. An electrolyte is disposed between the anode and the cathode. A protective layer is deposited between the cathode and the electrolyte. The protective layer includes pure lithium phosphorus oxynitride and variations that include metal dopants such as Fe, Ti, Ni, V, Cr, Cu, and Co. A method for making a cathode and a method for operating a battery are also disclosed.

  4. High-performance lanthanum-ferrite-based cathode for SOFC

    DEFF Research Database (Denmark)

    Wang, W.G.; Mogensen, Mogens Bjerg

    2005-01-01

    (La0.6Sr0.4)(1-x)Co0.2Fe0.8O3/Ce0.9Gd0.1O3 (LSCF/CGO) composite cathodes were investigated for SOFC application at intermediate temperature, i.e., 500-700 degreesC. The LSCF/CGO cathodes have been studied on three types of tape-casted electrolyte substrates including CGO electrolyte, Yttrium-stab...

  5. Preparation of redox polymer cathodes for thin film rechargeable batteries

    Energy Technology Data Exchange (ETDEWEB)

    Skotheim, T.A.; Lee, H.S.; Okamoto, Yoshiyuki.

    1994-11-08

    The present invention relates to the manufacture of thin film solid state electrochemical devices using composite cathodes comprising a redox polymer capable of undergoing oxidation and reduction, a polymer solid electrolyte and conducting carbon. The polymeric cathode material is formed as a composite of radiation crosslinked polymer electrolytes and radiation crosslinked redox polymers based on polysiloxane backbones with attached organosulfur side groups capable of forming sulfur-sulfur bonds during electrochemical oxidation.

  6. Single-layer graphene cathodes for organic photovoltaics

    Science.gov (United States)

    Cox, Marshall; Gorodetsky, Alon; Kim, Bumjung; Kim, Keun Soo; Jia, Zhang; Kim, Philip; Nuckolls, Colin; Kymissis, Ioannis

    2011-03-01

    A laminated single-layer graphene is demonstrated as a cathode for organic photovoltaic devices. The measured properties indicate that graphene offers two potential advantages over conventional photovoltaic electrode materials; work function matching via contact doping, and increased power conversion efficiency due to transparency. These findings indicate that flexible, light-weight all carbon solar cells can be constructed using graphene as the cathode material.

  7. Model for solid oxide fuel cell cathodes prepared by infiltration

    DEFF Research Database (Denmark)

    Samson, Alfred Junio; Søgaard, Martin; Hendriksen, Peter Vang

    2017-01-01

    A 1-dimensional model of a cathode has been developed in order to understand and predict the performance of cathodes prepared by infiltration of La0.6Sr0.4Co1.05O3-δ (LSC) into porous backbones of Ce0.9Gd0.1O1.95 (CGO). The model accounts for the mixed ionic and electronic conductivity of LSC, i...

  8. Cathodes for lithium-air battery cells with acid electrolytes

    Science.gov (United States)

    Xing, Yangchuan; Huang, Kan; Li, Yunfeng

    2016-07-19

    In various embodiments, the present disclosure provides a layered metal-air cathode for a metal-air battery. Generally, the layered metal-air cathode comprises an active catalyst layer, a transition layer bonded to the active catalyst layer, and a backing layer bonded to the transition layer such that the transition layer is disposed between the active catalyst layer and the backing layer.

  9. Chromium (V) compounds as cathode material in electrochemical power sources

    Science.gov (United States)

    Delnick, F.M.; Guidotti, R.A.; McCarthy, D.K.

    A cathode for use in a thermal battery, comprising a chromium (V) compound. The preferred materials for this use are Ca/sub 5/(CrO/sub 4/)/sub 3/Cl, Ca/sub 5/(CrO/sub 4/)OH, and Cr/sub 2/O/sub 5/. The chromium (V) compound can be employed as a cathode material in ambient temperature batteries when blended with a suitably conductive filler, preferably carbon black.

  10. Subzero-Temperature Cathode for a Sodium-Ion Battery.

    Science.gov (United States)

    You, Ya; Yao, Hu-Rong; Xin, Sen; Yin, Ya-Xia; Zuo, Tong-Tong; Yang, Chun-Peng; Guo, Yu-Guo; Cui, Yi; Wan, Li-Jun; Goodenough, John B

    2016-09-01

    A subzero-temperature cathode material is obtained by nucleating cubic prussian blue crystals at inhomogeneities in carbon nanotubes. Due to fast ionic/electronic transport kinetics even at -25 °C, the cathode shows an outstanding low-temperature performance in terms of specific energy, high-rate capability, and cycle life, providing a practical sodium-ion battery powering an electric vehicle in frigid regions. © 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  11. Spatial distribution of soil erosion and suspended sediment ...

    Indian Academy of Sciences (India)

    sediment transport rate for Chou-Shui river basin ... 5, Anzhong Road,. Tainan 70970, Taiwan. 4. Department of Hydraulics and Ocean Engineering, National Cheng-Kung University, No. 1,. University Road, Tainan ... surface runoff discharge, suspended sediment transport rate, quantity of soil erosion, and spatial distribu-.

  12. Calamine lotion: experimenting with a new suspending agent.

    Science.gov (United States)

    Al-Achi, A; Greenwood, R; Akin-Isijola, A; Bullard, J

    1999-01-01

    The use of a new suspending agent is investigated. Calamine lotion, USP contains bentonite magma as a suspending agent. In this study, bentonite magma was partially or completely replaced with a new suspending agent called tahini. Tahini is sesame paste composed of crushed sesame seeds in sesame oil. It is frequently used in middle eastern food as a thickening and suspending agent. Calamine lotion was prepared, generally, according to the USP method. The formula contained 40% v/v magma. Tahini was added instead of bentonite magma by replacing 100%, 99%, 90%, 75%, 50% and 25% of the magma. The sedimentation volume and the degree of flocculation were calculated for the resulting preparations. Rheological characteristics of bentonite- and tahini-containing lotions were also determined. Sedimentation volume showed 0.723 and 0.851 (p=0.05) for the lotions containing 100% bentonite and 100% tahini, respectively. The degree of flocculation was 2.00 and 2.35 (p=0.05) for the 100% bentonite and 100% tahini lotions, respectively. The rheograms of all the suspensions showed pseudoplastic flow. Overall, the use of tahini in calamine lotion has improved the physical stability of the formula.

  13. Turbulence Flow Characteristics of Suspended Sediments and its ...

    African Journals Online (AJOL)

    These are inturn integrated to give the hydraulic resistance law for sediment laden flow. The law of velocity distribution in open channel flow with suspended sediments was derived introducing Monin-Obukhov Length L . The distribution equation agrees well with the observation of velocity profile in the experiments.

  14. Microscopic characterisation of suspended graphene grown by chemical vapour deposition

    NARCIS (Netherlands)

    Bignardi, L.; Dorp, W.F. van; Gottardi, S.; Ivashenko, O.; Dudin, P.; Barinov, A.; de Hosson, J.T.M.; Stöhr, M.; Rudolf, P.

    2013-01-01

    We present a multi-technique characterisation of graphene grown by chemical vapour deposition (CVD) and thereafter transferred to and suspended on a grid for transmission electron microscopy (TEM). The properties of the electronic band structure are investigated by angle-resolved photoelectron

  15. Geochemistry of suspended and settling solids in two freshwater lakes.

    NARCIS (Netherlands)

    Koelmans, A.A.

    1998-01-01

    This study describes the 1987–1992 time variationof the bulk chemical composition, levels of heavymetals, arsenic, nitrogen and phosporous insuspended and settling solids in Lake Volkerak andLake Zoom (The Netherlands). Suspended and setlingsolids were collected with continuous flowcentrifuges and

  16. Comparison of Suspended Solid Separation in Advanced Storm Overflow Structures

    DEFF Research Database (Denmark)

    Larsen, Torben; Sørensen, Morten Steen

    1990-01-01

    This paper describes a laboratory investigation of the separation of suspended solids in a circular weir overflow and a vortex separator. The basic idea is to evaluate the efficiency of a vortical flow in the overflow chamber, and to compare these results with other overflow structures....

  17. Current-use insecticides, phosphates and suspended solids in the ...

    African Journals Online (AJOL)

    In Western Cape orchard areas, the last pesticide application of the growing season in summer takes place at the end of February. Pesticides, total phosphates and total suspended solids (TSS) were measured in the Lourens River at the beginning of April 1999 prior to the first rainfall of the rainy season and in the middle of ...

  18. Reduction in density of suspended - sediment - laden natural waters

    Digital Repository Service at National Institute of Oceanography (India)

    Joseph, A.; Desa, E.; Desa, E.; Smith, D.; Peshwe, V.B.; VijayKumar, K.; Desa, J.A.E.

    to 0.4% - 4.5%) that of the density of the same water without suspended sediment. Teh values of peff in a given site differed from one tidal cycle to another (approx equal to 1.9%). These values varied slightly (less than 0.8%) from mid-tide to slack...

  19. Transport of suspended particles in turbulent open channel flows

    NARCIS (Netherlands)

    Breugem, W.A.

    2012-01-01

    Two experiments are performed in order to investigate suspended sediment transport in a turbulent open channel flow. The first experiment used particle image velocimetry (PIV) to measure the fluid velocity with a high spatial resolution, while particle tracking velocimetry (PTV) was used to measure

  20. Spatial Distribution of Suspended Particulate Matter in Mtwapa ...

    African Journals Online (AJOL)

    Surface water concentrations of inorganic nutrients and suspended particulate matter (SPM) components from Mtwapa and Shirazi creeks in Kenya were measured and compared. This was aimed at assessing the contribution of phytoplankton carbon, particulate organic carbon (POC) and detritus on the total SPM pool, and ...

  1. Nature of suspended particulate matter and concentrations of heavy ...

    African Journals Online (AJOL)

    The concentrations of metals in bottom sediment in the Tanzanian waters of Lake Victoria and the nature of suspended particulate matter (SPM) were analysed. The objective of the study was to compare levels of metals in sediment from different locations and to establish their sources. Metal concentrations were higher in ...

  2. Amino sugars in suspended particulate matter from the Bay of ...

    Indian Academy of Sciences (India)

    Amino sugars (AS)are important constituents of organic matter.However,very little is known about their cycling in marine waters.In this research,we assessed the distribution and cycling of these compounds in waters of the Bay of Bengal.For this purpose,samples of suspended particulate matter (SPM)were collected from 8 ...

  3. Stabilised suspending efficiency of Laponite XLG and sodium ...

    African Journals Online (AJOL)

    Charged drugs like Sulphamerazine may make pseudoplastic/plastic materials become Newtonian and loose their suspending power. In this study ... For this purpose, the rheograms of the systems were obtained by the use of a Haake rotoviscometer RV 12 utilizing a cup and rotor sensor system MV 1. In the absence of ...

  4. Spin Transport in High-Quality Suspended Graphene Devices

    NARCIS (Netherlands)

    Guimaraes, Marcos H. D.; Veligura, A.; Zomer, P. J.; Maassen, T.; Vera-Marun, I. J.; Tombros, N.; van Arees, B. J.; Wees, B.J. van

    We measure spin transport in high mobility suspended graphene (mu approximate to 10(5)cm(2)/(V s)), obtaining a (spin) diffusion coefficient of 0.1 m(2)/s and giving a lower bound on the spin relaxation time (tau(s) approximate to 150 ps) and spin relaxation length (lambda(s) = 4.7 mu m) for

  5. 40 CFR 52.330 - Control strategy: Total suspended particulates.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 3 2010-07-01 2010-07-01 false Control strategy: Total suspended... PROGRAMS (CONTINUED) APPROVAL AND PROMULGATION OF IMPLEMENTATION PLANS Colorado § 52.330 Control strategy..., the State must repromulgate Regulation No. 1 to satisfy reasonably available control technology...

  6. Evaluation of the suspending properties of Abizia zygia gum on ...

    African Journals Online (AJOL)

    Method: The suspending properties of Albizia zygia gum (family Mimosoideae) were evaluated comparatively with those of Compound Tragacanth, Acacia and Gelatin at concentration range of 0.5 – 4.0%w/v in Sulphadimidine suspension. Characterization tests were carried out on purified Albizia zygia gum. Sedimentation ...

  7. Discrete Dynamics of Nanoparticle Channelling in Suspended Graphene

    DEFF Research Database (Denmark)

    Booth, Tim; Pizzocchero, Filippo; Andersen, Henrik

    2011-01-01

    We have observed a previously undescribed stepwise oxidation of mono- and few layer suspended graphene by silver nanoparticles in situ at subnanometer scale in an environmental transmission electron microscope. Over the range of 600–850 K, we observe crystallographically oriented channelling...

  8. Opportunities Suspended: The Disparate Impact of Disciplinary Exclusion from School

    Science.gov (United States)

    Losen, Daniel J.; Gillespie, Jonathan

    2012-01-01

    Well over three million children, K-12, are estimated to have lost instructional "seat time" in 2009-2010 because they were suspended from school, often with no guarantee of adult supervision outside the school. That's about the number of children it would take to fill every seat in every major league baseball park and every NFL stadium…

  9. Investigation of suspended sediment transport using ultrasonic techniques

    DEFF Research Database (Denmark)

    Bjørnø, Irina; Jensen, Leif Bjørnø

    1994-01-01

    The results of the initial experimental studies involving the scattering of ultrasonic signals from canonical and non-canonical shaped suspended particles with known elastical qualities are reported. These results have formed the basis for the development of a numerical model for ultrasound...

  10. Microwave-induced nonequilibrium temperature in a suspended carbon nanotube

    NARCIS (Netherlands)

    Hortensius, H.L.; Öztürk, A.; Zeng, P.; Driessen, E.F.C.; Klapwijk, T.M.

    2012-01-01

    Antenna-coupled suspended single carbon nanotubes exposed to 108?GHz microwave radiation are shown to be selectively heated with respect to their metal contacts. This leads to an increase in the conductance as well as to the development of a power-dependent DC voltage. The increased conductance

  11. Scanning tunneling spectroscopy of suspended single-wall carbon nanotubes

    NARCIS (Netherlands)

    LeRoy, B.J.; Lemay, S.G.; Kong, J.; Dekker, C.

    2004-01-01

    We have performed low-temperature scanning tunneling microscopy measurements on single-wall carbon nanotubes that are freely suspended over a trench. The nanotubes were grown by chemical vapor deposition on a Pt substrate with predefined trenches etched into it. Atomic resolution was obtained on the

  12. Evaluation of the Suspending Properties of the Coprecipitate of ...

    African Journals Online (AJOL)

    The suspending ability of the different ratios was evaluated in magnesium trisilicate suspension, and compared with a suspension prepared with Compound Tragacanth Powder BP (CTP) as well as a commercially available magnesium trisilicate suspension (MTS). The parameters tested were sedimentation rate, flow rate, ...

  13. Suspended microstructures of epoxy based photoresists fabricated with UV photolithography

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Anhøj, Thomas Aarøe; Caviglia, Claudia

    2017-01-01

    In this work we present an easy, fast, reliable and low cost microfabrication technique for fabricating suspended microstructures of epoxy based photoresistswith UV photolithography. Two different fabrication processes with epoxy based resins (SU-8 and mr-DWL) using UV exposures at wavelengths...

  14. Exhibits Enhanced by Stand-Alone Computers.

    Science.gov (United States)

    Van Rennes, Eve C.

    Both the development and evaluation of one of a set of computer programs designed for use by visitors as adjuncts to museum exhibits are described. Museum displays used were (1) a static, behind-glass exhibit on evolution; (2) a hands-on primitive stone age tools exhibit; and (3) a Foucault pendulum. A computer placed next to each exhibit served…

  15. Suspended tungsten-based nanowires with enhanced mechanical properties grown by focused ion beam induced deposition

    Science.gov (United States)

    Córdoba, Rosa; Lorenzoni, Matteo; Pablo-Navarro, Javier; Magén, César; Pérez-Murano, Francesc; María De Teresa, José

    2017-11-01

    The implementation of three-dimensional (3D) nano-objects as building blocks for the next generation of electro-mechanical, memory and sensing nano-devices is at the forefront of technology. The direct writing of functional 3D nanostructures is made feasible by using a method based on focused ion beam induced deposition (FIBID). We use this technique to grow horizontally suspended tungsten nanowires and then study their nano-mechanical properties by three-point bending method with atomic force microscopy. These measurements reveal that these nanowires exhibit a yield strength up to 12 times higher than that of the bulk tungsten, and near the theoretical value of 0.1 times the Young’s modulus (E). We find a size dependence of E that is adequately described by a core-shell model, which has been confirmed by transmission electron microscopy and compositional analysis at the nanoscale. Additionally, we show that experimental resonance frequencies of suspended nanowires (in the MHz range) are in good agreement with theoretical values. These extraordinary mechanical properties are key to designing electro-mechanically robust nanodevices based on FIBID tungsten nanowires.

  16. Chromium in water, suspended particles, sediments and biota in the Iraja River estuary

    Energy Technology Data Exchange (ETDEWEB)

    Pfeiffer, W.C.; Fiszman, M.; de Lacerda, L.D.; van Weerfelt, M.; Carbonell, N.

    1982-11-01

    Analyses of chromium concentrations in waters, suspended particles, bottom sediments, fish (Poecilia reticulata), plants (Paspalum vaginatum, Sesuvium portulacastrum, Philoxeros vermicularis), soils and barnacles (Balanus sp.) were performed from August 1976 to September 1980 in samples collected from the Iraja River and inside its estuary in Guanabara Bay (Rio de Janeiro, Brazil). Sediments and water from the Iraja River showed chromium concentrations of 17536 and 23.39 ppm--a thousand times higher than the published data for freshwater systems. Chromium removed from solution by bottom sediments reaches Guanabara Bay linked to particulate matter. Fish and emergent grass inside the river concentrate chromium from water and/or sediment, returning the metal to the system as detritus. Soil and plants inside the estuary concentrate chromium thirty and ten times higher than in the control area. The vegetal community exhibits a concentration factor smaller than that related to soil and prevents the return of chromium to the estuarine waters. Inside the Guanabara Bay, Balanus sp. appears to be an effective biological monitor as it concentrates chromium in soft tissues 10/sup 3/ times higher than values found in suspended particles (0.012 ..mu..g ml/sup -1/).

  17. Suspended tungsten-based nanowires with enhanced mechanical properties grown by focused ion beam induced deposition.

    Science.gov (United States)

    Córdoba, Rosa; Lorenzoni, Matteo; Pablo-Navarro, Javier; Magén, César; Pérez-Murano, Francesc; De Teresa, José María

    2017-11-03

    The implementation of three-dimensional (3D) nano-objects as building blocks for the next generation of electro-mechanical, memory and sensing nano-devices is at the forefront of technology. The direct writing of functional 3D nanostructures is made feasible by using a method based on focused ion beam induced deposition (FIBID). We use this technique to grow horizontally suspended tungsten nanowires and then study their nano-mechanical properties by three-point bending method with atomic force microscopy. These measurements reveal that these nanowires exhibit a yield strength up to 12 times higher than that of the bulk tungsten, and near the theoretical value of 0.1 times the Young's modulus (E). We find a size dependence of E that is adequately described by a core-shell model, which has been confirmed by transmission electron microscopy and compositional analysis at the nanoscale. Additionally, we show that experimental resonance frequencies of suspended nanowires (in the MHz range) are in good agreement with theoretical values. These extraordinary mechanical properties are key to designing electro-mechanically robust nanodevices based on FIBID tungsten nanowires.

  18. Testing Iodine as a New Fuel for Cathodes

    Science.gov (United States)

    Glad, Harley; Branam, Richard; Rogers, Jim; Warren, Matthew; Burleson, Connor; Siy, Grace

    2017-11-01

    The objective of this research is to demonstrate the viability of using iodine as an alternative space propulsion propellant. The demonstration requires the testing of a cathode with xenon and then the desired element iodine. Currently, cathodes run on noble gases such as xenon which must be stored in high pressure canisters and is very expensive. These shortcomings have led to researching possible substitutes. Iodine was decided as a suitable candidate because it's cheaper, can be stored as a solid, and has similar mass properties as xenon. In this research, cathodes will be placed in a vacuum chamber and operated on both gases to observe their performance, allowing us to gain a better understanding of iodine's behavior. Several planned projects depend on the knowledge gained from this project, such as larger scaled tests and iodine fed hall thrusters. The tasks of this project included protecting the stainless-steel vacuum chamber by gold plating and Teflon® coating, building a stand to hold the cathode, creating an anode resistant to iodine, and testing the cathode once setup was complete. The successful operation of the cathode was demonstrated. However, the experimental setup proved ineffective at controlling the iodine flow. Current efforts are focused on this problem. REU Site: Fluid Mechanics with Analysis using Computations and Experiments NSF Grant EEC 1659710.

  19. Hollow cathode heater development for the Space Station plasma contactor

    Science.gov (United States)

    Soulas, George C.

    1993-01-01

    A hollow cathode-based plasma contactor has been selected for use on the Space Station. During the operation of the plasma contactor, the hollow cathode heater will endure approximately 12000 thermal cycles. Since a hollow cathode heater failure would result in a plasma contactor failure, a hollow cathode heater development program was established to produce a reliable heater design. The development program includes the heater design, process documents for both heater fabrication and assembly, and heater testing. The heater design was a modification of a sheathed ion thruster cathode heater. Three heaters have been tested to date using direct current power supplies. Performance testing was conducted to determine input current and power requirements for achieving activation and ignition temperatures, single unit operational repeatability, and unit-to-unit operational repeatability. Comparisons of performance testing data at the ignition input current level for the three heaters show the unit-to-unit repeatability of input power and tube temperature near the cathode tip to be within 3.5 W and 44 degrees C, respectively. Cyclic testing was then conducted to evaluate reliability under thermal cycling. The first heater, although damaged during assembly, completed 5985 ignition cycles before failing. Two additional heaters were subsequently fabricated and have completed 3178 cycles to date in an on-going test.

  20. Cathode erosion in high-current high-pressure arc

    CERN Document Server

    Nemchinsky, V A

    2003-01-01

    Cathode erosion rate was experimentally investigated for two types of arcs: one with tungsten cathode in nitrogen atmosphere and one with hafnium cathode in oxygen atmosphere. Conditions were typical for plasma arc cutting systems: gas pressure from 2 to 5 atm, arc current from 200 to 400 A, gas flow rate from 50 to 130 litre min sup - sup 1. It was found that the actual cathode evaporation rate G is much lower than G sub 0 , the evaporation rate that follows from the Hertz-Knudsen formula: G = nu G sub 0. The difference is because some of the evaporated particles return back to the cathode. For conditions of our experiments, the factor nu could be as low as 0.01. It was shown experimentally that nu depends strongly on the gas flow pattern close to the cathode. In particular, swirling the gas increases nu many times. To explain the influence of gas swirling, model calculations of gas flows were performed. These calculations revealed difference between swirling and non-swirling flows: swirling the gas enhances...

  1. An adjustable electron achromat for cathode lens microscopy

    Energy Technology Data Exchange (ETDEWEB)

    Tromp, R.M., E-mail: rtromp@us.ibm.com [IBM T.J. Watson Research Center, 1101 Kitchawan Road, Yorktown Heights, NY 10598 (United States); Leiden Institute of Physics, Kamerlingh Onnes Laboratory, Niels Bohrweg 2, 2333 CA Leiden (Netherlands)

    2015-12-15

    Chromatic aberration correction in light optics began with the invention of a two-color-corrected achromatic crown/flint lens doublet by Chester Moore Hall in 1730. Such color correction is necessary because any single glass shows dispersion (i.e. its index of refraction changes with wavelength), which can be counteracted by combining different glasses with different dispersions. In cathode lens microscopes (such as Photo Electron Emission Microscopy – PEEM) we encounter a similar situation, where the chromatic aberration coefficient of the cathode lens shows strong dispersion, i.e. depends (non-linearly) on the energy with which the electrons leave the sample. Here I show how a cathode lens in combination with an electron mirror can be configured as an adjustable electron achromat. The lens/mirror combination can be corrected at two electron energies by balancing the settings of the electron mirror against the settings of the cathode lens. The achromat can be adjusted to deliver optimum performance, depending on the requirements of a specific experiment. Going beyond the achromat, an apochromat would improve resolution and transmission by a very significant margin. I discuss the requirements and outlook for such a system, which for now remains a wish waiting for fulfilment. - Highlights: • The properties of cathode objective lens plus electron mirror are discussed. • In analogy with light-optical achromats, cathode lens plus mirror can be configured as an electron achromat. • Unlike light optics, the electron achromat can be adjusted to best fulfill experimental requirements.

  2. Dynamic Aspects of Solid Solution Cathodes for Electrochemical Power Sources

    DEFF Research Database (Denmark)

    Atlung, Sven; West, Keld; Jacobsen, Torben

    1979-01-01

    Battery systems based on alkali metal anodes and solid solution cathodes,i.e., cathodes based on the insertion of the alkali cation in a "host lattice,"show considerable promise for high energy density storage batteries. Thispaper discusses the interaction between battery requirements, in particu......Battery systems based on alkali metal anodes and solid solution cathodes,i.e., cathodes based on the insertion of the alkali cation in a "host lattice,"show considerable promise for high energy density storage batteries. Thispaper discusses the interaction between battery requirements......, in particularfor vehicle propulsion, and electrochemical and constructional factors. It isargued that the energy obtainable at a given load is limited by saturation ofthe surface layers of cathode particles with cations, and that the time beforesaturation occurs is determined by diffusion of cations and electrons...... into thehost lattice. Expressions are developed for plane, cylindrical, and sphericalparticles, giving the relation between battery load and the amount of cathodematerial utilized before saturation. The particle shape and a single parameterQ is used to describe cathode performance. Q is the ratio between...

  3. Cathodic protection for the bottoms of above ground storage tanks

    Energy Technology Data Exchange (ETDEWEB)

    Mohr, John P. [Tyco Adhesives, Norwood, MA (United States)

    2004-07-01

    Impressed Current Cathodic Protection has been used for many years to protect the external bottoms of above ground storage tanks. The use of a vertical deep ground bed often treated several bare steel tank bottoms by broadcasting current over a wide area. Environmental concerns and, in some countries, government regulations, have introduced the use of dielectric secondary containment liners. The dielectric liner does not allow the protective cathodic protection current to pass and causes corrosion to continue on the newly placed tank bottom. In existing tank bottoms where inadequate protection has been provided, leaks can develop. In one method of remediation, an old bottom is covered with sand and a double bottom is welded above the leaking bottom. The new bottom is welded very close to the old bottom, thus shielding the traditional cathodic protection from protecting the new bottom. These double bottoms often employ the use of dielectric liner as well. Both the liner and the double bottom often minimize the distance from the external tank bottom. The minimized space between the liner, or double bottom, and the bottom to be protected places a challenge in providing current distribution in cathodic protection systems. This study examines the practical concerns for application of impressed current cathodic protection and the types of anode materials used in these specific applications. One unique approach for an economical treatment using a conductive polymer cathodic protection method is presented. (author)

  4. TiO{sub 2} nanotubes as alternative cathode in microbial fuel cells: Effect of annealing treatment on its performance

    Energy Technology Data Exchange (ETDEWEB)

    Yahia, S. Ait Ali, E-mail: aay-soraya@yahoo.fr [Department of Chemical and Environmental Engineering, Regional Campus of International Excellence of “Campus Mare Nostrum”, Polytechnic University of Cartagena, Campus La Muralla, E-30202 Cartagena, Murcia (Spain); Laboratory of Physics and Chemical Materials (L.P.C.M.), University Mouloud MAMMERI, Tizi-Ouzou 1500 (Algeria); Hamadou, L., E-mail: lamhama@yahoo.fr [Laboratory of Physics and Chemical Materials (L.P.C.M.), University Mouloud MAMMERI, Tizi-Ouzou 1500 (Algeria); Salar-García, M.J. [Department of Chemical and Environmental Engineering, Regional Campus of International Excellence of “Campus Mare Nostrum”, Polytechnic University of Cartagena, Campus La Muralla, E-30202 Cartagena, Murcia (Spain); Kadri, A. [Laboratory of Physics and Chemical Materials (L.P.C.M.), University Mouloud MAMMERI, Tizi-Ouzou 1500 (Algeria); Ortiz-Martínez, V.M.; Hernández-Fernández, F.J. [Department of Chemical and Environmental Engineering, Regional Campus of International Excellence of “Campus Mare Nostrum”, Polytechnic University of Cartagena, Campus La Muralla, E-30202 Cartagena, Murcia (Spain); Pérez de los Rios, A. [Chemical Engineering Department, University of Murcia, Campus de Espinardo, E-30071 Murcia (Spain); Benbrahim, N. [Laboratory of Physics and Chemical Materials (L.P.C.M.), University Mouloud MAMMERI, Tizi-Ouzou 1500 (Algeria)

    2016-11-30

    Highlights: • An alternative cathode using TiO{sub 2} nanotubes. • Determination of the structural, morphological and electronic characteristics of the cathode. • Effect of crystalline structure on MFCs performances. - Abstract: In the present work, amorphous and crystalline TiO{sub 2} nanotubes (TiNT) were fabricated via anodization and characterized as an alternative cathode for Microbial Fuel Cells (MFCs). The morphology of TiNT is characterized by scanning electron microscopy (SEM). The crystalline structure and chemical composition are examined by X-ray diffraction (XRD) and Energy dispersive X-ray spectroscopy (EDX). The electrical conductivity characteristics were examined by electrochemical impedance spectroscopy (EIS). MFCs based on the alternative cathodes were evaluated in terms of energy generation and wastewater treatment. The performances of the as-anodized nanotubes and TiNT annealed at 450 °C and at 550 °C were investigated in double-chamber MFCs with carbon rod and graphite granules as anode and polymer inclusion membrane based on ionic liquid as separator. Industrial wastewater was the source of carbon and inoculum for the experiments. The as grown amorphous nanotubes exhibited the best output power density of 15.16 mWm{sup −2}. The results reported here indicate that the specific surface area and the oxygen vacancies of the TiNT cathode can influence the MFCs performance together, because both factors play crucial role in the oxygen reduction reaction (ORR). As-anodized TiNT, due to its higher specific surface provide more active sites for electrode reactions. The final oxygen demand (COD) for all systems achieved a COD removal within the interval 54–71% after 10 days. This approved the suitability of MFCs for wastewater treatment.

  5. Perovskite-type oxides La 1- xSr xMnO 3 for cathode catalysts in direct ethylene glycol alkaline fuel cells

    Science.gov (United States)

    Miyazaki, Kohei; Sugimura, Naotsugu; Matsuoka, Koji; Iriyama, Yasutoshi; Abe, Takeshi; Matsuoka, Masao; Ogumi, Zempachi

    Carbon-supported La 1- xSr xMnO 3 (LSM/C) was prepared by reversible homogeneous precipitation method, and its catalytic activities for oxygen reduction under the existence of ethylene glycol (EG) were investigated by using rotating disk electrode. LSM/C exhibited the high activity for oxygen reduction irrespective with the presence of EG, indicating that EG is not oxidized by LSM/C at the cathode side in the present system. Consequently, LSM/C can serve as a cathode catalyst in alkaline direct alcohol fuel cells with no crossover problem. Performance test for fuel cells operation also supported these results and showed cathodic polarization curves were not affected by the concentration of EG supplied to anode even at 5 mol dm -3.

  6. An analysis of bedload and suspended load interactions

    Science.gov (United States)

    Recking, alain; Navratil, Oldrich

    2013-04-01

    Several approaches were used to develop suspension equations. It includes semi-theoretical equations based on the convection diffusion equation (Einstein 1950; Van Rijn 1984; Camenen and Larson 2008; Julien 2010), semi-empirical tools based on energy concept (Velikanov 1954; Bagnold 1966), empirical adjustments (Prosser and Rusttomji 2000). One essential characteristic of all these equations is that most of them were developed by considering continuity between bedload and suspended load, and that the partitioning between these two modes of transport evolves progressively with increasing shear stress, which is the case for fine bed materials. The use of these equations is thus likely to be welcome in estuaries or lowland sandy rivers, but may be questionable in gravel-bed rivers and headwater streams where the bed is usually structured vertically and fine sediments potentially contributing to suspension are stored under a poorly mobile surface armour comprising coarse sediments. Thus one question this work aimed to answer is does the presence of an armour at the bed surface influence suspended load? This was investigated through a large field data set comprising instantaneous measurements of both bedload and suspension. We also considered the river characteristics, distinguishing between lowland rivers, gravel bed rivers and headwater streams. The results showed that a correlation exist between bedload and suspension for lowland and gravel bed rivers. This suggests that in gravel bed rivers a large part of the suspended load is fed by subsurface material, and depends on the remobilization of the surface material. No correlation was observed for head water streams where the sediment production is more likely related to hillslope processes. These results were used with a bedload transport equation for proposing a method for suspended load estimate. The method is rough, but especially for gravel bed rivers, it predicts suspended load reasonably well when compared to

  7. Lithium Iron Orthosilicate Cathode: Progress and Perspectives

    Energy Technology Data Exchange (ETDEWEB)

    Ni, Jiangfeng [College; amp, Physics (CECMP), Soochow University, Suzhou 215006, PR China; Jiang, Yu [College; amp, Physics (CECMP), Soochow University, Suzhou 215006, PR China; Bi, Xuanxuan [Chemical; Li, Liang [College; amp, Physics (CECMP), Soochow University, Suzhou 215006, PR China; Lu, Jun [Chemical

    2017-07-18

    The pursuit of cathodes with a high capacity is remarkably driven by the ever increasing demand of high-energy lithium ion batteries in electronics and transportation. In this regard, polyanionic lithium iron orthosilicate (Li2FeSiO4) offers a promising opportunity because it affords a high theoretical capacity of 331 mAh g–1. However, such a high theoretical capacity of Li2FeSiO4 has frequently been compromised in practice because of the extremely low electronic and ionic conductivity. To address this issue, material engineering strategies to boost the Li storage kinetics in Li2FeSiO4 have proven indispensable. In this Perspective, we will briefly present the structural characteristics, intrinsic physicochemical properties, and electrochemical behavior of Li2FeSiO4. We particularly focus on recent materials engineering of silicates, which is implemented mainly through advanced synthetic techniques and elaborate controls. This Perspective highlights the importance of integrating theoretical analysis into experimental implementation to further advance the Li2FeSiO4 materials.

  8. eV-TEM: Transmission electron microscopy in a low energy cathode lens instrument

    Energy Technology Data Exchange (ETDEWEB)

    Geelen, Daniël, E-mail: geelen@physics.leidenuniv.nl [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Thete, Aniket [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Schaff, Oliver; Kaiser, Alexander [SPECS GmbH, Voltastrasse 5, D-13355 Berlin (Germany); Molen, Sense Jan van der [Huygens-Kamerlingh Onnes Laboratory, Leiden Institute of Physics, Leiden University, P.O. Box 9504, 2300 RA Leiden (Netherlands); Tromp, Rudolf [IBM T.J. Watson Research Center, 1101 Kitchawan Road, P.O. Box 218, Yorktown Heights, NY 10598 (United States)

    2015-12-15

    We are developing a transmission electron microscope that operates at extremely low electron energies, 0–40 eV. We call this technique eV-TEM. Its feasibility is based on the fact that at very low electron energies the number of energy loss pathways decreases. Hence, the electron inelastic mean free path increases dramatically. eV-TEM will enable us to study elastic and inelastic interactions of electrons with thin samples. With the recent development of aberration correction in cathode lens instruments, a spatial resolution of a few nm appears within range, even for these very low electron energies. Such resolution will be highly relevant to study biological samples such as proteins and cell membranes. The low electron energies minimize adverse effects due to radiation damage. - Highlights: • We present a new way of performing low energy transmission electron microscopy in an aberration corrected LEEM/PEEM instrument. • We show a proof of principle where we measure transmitted electrons through a suspended graphene monolayer with a preliminary setup. • We present an improved setup design that provides better control of the incident electron beam.

  9. An impressive approach to solving the ongoing stability problems of LiCoPO4 cathode: Nickel oxide surface modification with excellent core-shell principle

    Science.gov (United States)

    Örnek, Ahmet

    2017-07-01

    Nanoscale and NiO-coated LiCoPO4 cathode materials were prepared for the first time by a newly designed three-step synthesis route, which is a combined technique including advantages of the Stöber, hydrothermal and microwave synthesis methods. Using this extraordinary technique, LiCoPO4 particles are coated with a thin NiO layer with a perfect core-shell morphology and the technique's positive contribution to electrochemistry is elucidated in detail. The samples are interpreted using opto-analytical techniques and galvanostatic charge-discharge tests. The high-resolution transmission electron microscopy analysis proves that this well-elaborated technique makes it possible to achieve a continuous NiO surface coverage of 8-10 nm, a result that contributes towards solving the chronic electrochemical problems of 4.8 V cathode material. Our data reveal that NiO-coated LiCoPO4 cathode demonstrates superior cycle stability and specific capacity at relatively low rates. The 2.5% wt. NiO-coated cathode exhibits the best electrochemical property, which reaches a discharge capacity of 159 mAh g-1 at 0.l C current rate and shows almost 85% capacity retention after 80 charge-discharge cycles. It therefore achieves partial success in improving the electrochemical properties of the LiCoPO4 cathode material, which is especially crucial for energy storage to be applied in electric vehicles and plug-in hybrid electric applications.

  10. Performance and Structural Evolution of Nano-Scale Infiltrated Solid Oxide Fuel Cell Cathodes

    Science.gov (United States)

    Call, Ann Virginia

    Nano-structured mixed ionic and electronic conducting (MIEC) materials have garnered intense interest in electrode development for solid oxide fuel cells due to their high surface areas which allow for effective catalytic activity and low polarization resistances. In particular, composite solid oxide fuel cell (SOFC) cathodes consisting of ionic conducting scaffolds infiltrated with MIEC nanoparticles have exhibited some of the lowest reported polarization resistances. In order for cells utilizing nanostructured moRPhologies to be viable for commercial implementation, more information on their initial performance and long term stability is necessary. In this study, symmetric cell cathodes were prepared via wet infiltration of Sr0.5Sm 0.5CoO3 (SSC) nano-particles via a nitrate process into porous Ce0.9Gd0.1O1.95 (GDC) scaffolds to be used as a model system to investigate performance and structural evolution. Detailed analysis of the cells and cathodes was carried out using electrochemical impedance spectroscopy (EIS). Initial polarization resistances (RP) as low as 0.11 O cm2 at 600ºC were obtained for these SSC-GDC cathodes, making them an ideal candidate for studying high performance nano-structured electrodes. The present results show that the infiltrated cathode microstructure has a direct impact on the initial performance of the cell. Small initial particle sizes and high infiltration loadings (up to 30 vol% SSC) improved initial RP. A simple microstructure-based electrochemical model successfully explained these trends in RP. Further understanding of electrode performance was gleaned from fitting EIS data gathered under varying temperatures and oxygen partial pressures to equivalent circuit models. Both RQ and Gerischer impedance elements provided good fits to the main response in the EIS data, which was associated with the combination of oxygen surface exchange and oxygen diffusion in the electrode. A gas diffusion response was also observed at relatively

  11. Temperature signal in suspended sediment export from an Alpine catchment

    Directory of Open Access Journals (Sweden)

    A. Costa

    2018-01-01

    Full Text Available Suspended sediment export from large Alpine catchments ( >  1000 km2 over decadal timescales is sensitive to a number of factors, including long-term variations in climate, the activation–deactivation of different sediment sources (proglacial areas, hillslopes, etc., transport through the fluvial system, and potential anthropogenic impacts on the sediment flux (e.g. through impoundments and flow regulation. Here, we report on a marked increase in suspended sediment concentrations observed near the outlet of the upper Rhône River Basin in the mid-1980s. This increase coincides with a statistically significant step-like increase in basin-wide mean air temperature. We explore the possible explanations of the suspended sediment rise in terms of changes in water discharge (transport capacity, and the activation of different potential sources of fine sediment (sediment supply in the catchment by hydroclimatic forcing. Time series of precipitation and temperature-driven snowmelt, snow cover, and ice melt simulated with a spatially distributed degree-day model, together with erosive rainfall on snow-free surfaces, are tested to explore possible reasons for the rise in suspended sediment concentration. We show that the abrupt change in air temperature reduced snow cover and the contribution of snowmelt, and enhanced ice melt. The results of statistical tests show that the onset of increased ice melt was likely to play a dominant role in the suspended sediment concentration rise in the mid-1980s. Temperature-driven enhanced melting of glaciers, which cover about 10 % of the catchment surface, can increase suspended sediment yields through an increased contribution of sediment-rich glacial meltwater, increased sediment availability due to glacier recession, and increased runoff from sediment-rich proglacial areas. The reduced extent and duration of snow cover in the catchment are also potential contributors to the rise in suspended sediment

  12. Effect of mesoporous carbon microtube prepared by carbonizing the poplar catkin on sulfur cathode performance in Li/S batteries

    Energy Technology Data Exchange (ETDEWEB)

    Zhang, Yongguang; Zhao, Yan [Research Institute for Energy Equipment Materials, Hebei University of Technology, Tianjin 300130 (China); Konarov, Aishuak; Li, Zhi [Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L3G1 (Canada); Chen, P., E-mail: p4chen@uwaterloo.ca [Department of Chemical Engineering, University of Waterloo, 200 University Avenue West, Waterloo, Ontario N2L3G1 (Canada)

    2015-01-15

    Highlights: • CMT was synthesized by carbonizing poplar catkins and used in Li/S battery. • CMT with mesoporous surface is beneficial to trapping soluble polysulfides. • The S/CMT composite exhibited good cycling and rate capability. - Abstract: A carbon microtube (CMT) was synthesized by carbonizing the poplar catkin and composited with sulfur, serving as a cathode for lithium/sulfur batteries. Scanning electron microscopy and energy dispersive spectroscopy mapping showed the formation of a tubular structure with uniform sulfur coating on the surface of CMTs. The CMT with a mesoporous surface is beneficial to both trapping soluble polysulfide intermediates and rendering the electrical conductivity of the prepared electrode. The resulting S/CMT composite cathode can deliver an 810 mAh g{sup −1} reversible specific discharge capacity after 100 cycles at 0.1 C, and 585 mAh g{sup −1} at 1 C.

  13. Well-dispersed sulfur anchored on interconnected polypyrrole nanofiber network as high performance cathode for lithium-sulfur batteries

    Science.gov (United States)

    Yin, Fuxing; Liu, Xinyi; Zhang, Yongguang; Zhao, Yan; Menbayeva, Almagul; Bakenov, Zhumabay; Wang, Xin

    2017-04-01

    Preparation of novel sulfur/polypyrrole (S/PPy) composite consisting well-dispersed sulfur particles anchored on interconnected PPy nanowire network was demonstrated. In such hybrid structure, the as-prepared PPy clearly displays a three-dimensionally cross-linked and hierarchical porous structure, which was utilized in the composite cathode as a conductive network trapping soluble polysulfide intermediates and enhancing the overall electrochemical performance of the system. Benefiting from this unique structure, the S/PPy composite demonstrated excellent cycling stability, resulting in a discharge capacity of 931 mAh g-1 at the second cycle and retained about 54% of this value over 100 cycles at 0.1 C. Furthermore, the S/PPy composite cathode exhibits a good rate capability with a discharge capacity of 584 mAh g-1 at 1 C.

  14. Dynamics of suspended sediment concentration, flow discharge and sediment particle size interdependency to identify sediment source

    Science.gov (United States)

    Sadeghi, Seyed Hamidreza; Singh, Vijay P.

    2017-11-01

    Spatiotemporal behavior of sediment yield is a key for proper watershed management. This study analyzed statistical characteristics and trends of suspended sediment concentration (SCS), flow discharge (FD) and sediment particle sizes using data from 24 gage stations scattered throughout the United States. Analysis showed significant time- and location-specific differences of these variables. The median values of SSC, FD and percentage of particle sizes smaller than 63 μm (P63) for all 24 gage stations were found to be 510.236 mg l-1 (right skewed), 45.406 m3 s-1 (left skewed) and 78.648% (right skewed), respectively. Most of the stations exhibited significant trends (P management practices which may call for local or regional planning based on natural (i.e., precipitation amount, type and erosivity, watershed area, and soil erodibility) and human-affected (i.e., land use and hydraulic structures and water resources management) factors governing the study variables.

  15. Suspended sediment profiles derived from spectral attenuation coefficients measurements using neural network method

    Digital Repository Service at National Institute of Oceanography (India)

    Varkey, G.; Suresh, T.; Matondkar, S.G.P.; Desa, E.; Kamath, S.S.

    total suspended matter values from water samples obtained at discrete depths at the same location. An artificial neural network (ANN) model has been used to derive suspended matter from the spectral values of beam attenuation coefficients measured using...

  16. Impact of sound attenuation by suspended sediment on ADCP backscatter calibrations

    NARCIS (Netherlands)

    Sassi, M.G.; Hoitink, A.J.F.; Vermeulen, B.

    2012-01-01

    Although designed for velocity measurements, acoustic Doppler current profilers (ADCPs) are widely being used to monitor suspended particulate matter in rivers and in marine environments. To quantify mass concentrations of suspended matter, ADCP backscatter is generally calibrated with in situ

  17. Effect of Martian Suspended Dust on Albedo Measurements from the MGS-TES Data

    OpenAIRE

    A. Zinzi; Palomba, E.; Rinaldi, G.; d'Amore, M.

    2010-01-01

    Suspended dust on Mars influences albedo measurements by orbiting instruments, but not necessary the real surface albedo. The aim of this study is to characterize the role of suspended aerosols on albedo measurement by remote sensing instruments.

  18. Design, analysis and control of cable-suspended parallel robots and its applications

    CERN Document Server

    Zi, Bin

    2017-01-01

    This book provides an essential overview of the authors’ work in the field of cable-suspended parallel robots, focusing on innovative design, mechanics, control, development and applications. It presents and analyzes several typical mechanical architectures of cable-suspended parallel robots in practical applications, including the feed cable-suspended structure for super antennae, hybrid-driven-based cable-suspended parallel robots, and cooperative cable parallel manipulators for multiple mobile cranes. It also addresses the fundamental mechanics of cable-suspended parallel robots on the basis of their typical applications, including the kinematics, dynamics and trajectory tracking control of the feed cable-suspended structure for super antennae. In addition it proposes a novel hybrid-driven-based cable-suspended parallel robot that uses integrated mechanism design methods to improve the performance of traditional cable-suspended parallel robots. A comparative study on error and performance indices of hybr...

  19. Copper current collectors reduce long-term fouling of air cathodes in microbial fuel cells

    KAUST Repository

    Myung, Jaewook

    2018-02-05

    Long-term operation of wastewater-fed, microbial fuel cells (MFCs) with cathodes made of activated carbon and stainless steel (SS) current collectors can result in decreased performance due to cathode fouling. Copper has good antimicrobial properties, and it is more electrically conductive than SS. To demonstrate that a copper current collector could produce a more fouling resistant cathode, MFCs with air cathodes using either SS or copper current collectors were operated using domestic wastewater for 27 weeks. The reduction in biofouling over time was shown by less biofilm formation on the copper cathode surface compared to SS cathodes, due to the antimicrobial properties of copper. Maximum power densities from 17–27 weeks were 440 ± 38 mW/m2 using copper and 370 ± 21 mW/m2 using SS cathodes. The main difference in the microbial community was a nitrifying community on the SS cathodes, which was not present on the copper cathodes.

  20. Control of vacuum arc source cathode spots contraction motion by changing electromagnetic field

    Science.gov (United States)

    Xin, SONG; Qing, WANG; Zeng, LIN; Puhui, ZHANG; Shuhao, WANG

    2018-02-01

    This paper investigates the magnetic field component impact on cathode spots motion trajectory and the mechanism of periodic contraction. Electromagnetic coils and permanent magnets were installed at the different sides of cathode surface, the photographs of cathode spots motion trajectory were captured by a camera. Increasing the number of magnets and decreasing the distance between magnets and cathode both lead to enhancing cathode spots motion velocity. Radii of cathode spots trajectory decrease gradually with the increasing of electromagnetic coil’s current, from 40 mm at 0 A to 10 mm at 2.7 A. Parallel magnetic field component intensity influence the speed of cathode spots rotate motion, and perpendicular magnetic field component drives spots drift in the radial direction. Cathode spot’s radial drift is controlled by changing the location of the ‘zero line’ where perpendicular magnetic component shifts direction and the radius of cathode spots trajectory almost equal to ‘zero line’.

  1. Ion exchange membrane cathodes for scalable microbial fuel cells.

    Science.gov (United States)

    Zuo, Yi; Cheng, Shaoan; Logan, Bruce E

    2008-09-15

    One of the main challenges for using microbial fuel cells (MFCs) is developing materials and architectures that are economical and generate high power densities. The performance of two cathodes constructed from two low-cost anion (AEM) and cation (CEM) exchange membranes was compared to that achieved using an ultrafiltration (UF) cathode, when the membranes were made electrically conductive using graphite paint and a nonprecious metal catalyst (CoTMPP). The best performance in single-chamber MFCs using graphite fiber brush anodes was achieved using an AEM cathode with the conductive coating facing the solution, at a catalyst loading of 0.5 mg/cm2 CoTMPP. The maximum power densitywas 449 mW/ m2 (normalized to the projected cathode surface area) or 13.1 W/m3 (total reactor volume), with a Coulombic efficiency up to 70% in a 50 mM phosphate buffer solution (PBS) using acetate. Decreasing the CoTMPP loading by 40-80% reduced power by 28-56%, with only 16% of the power (72 mW/m2) generated using an AEM cathode lacking a catalyst. Using a current collector (a stainless steel mesh) pressed against the inside surface of the AEM cathode and 200 mM PBS, the maximum power produced was further increased to 728 mW/m2 (21.2 W/m3). The use of AEM cathodes and brush anodes provides comparable performance to similar systems that use materials costing nearly an order of magnitude more (carbon paper electrodes) and thus represent more useful materials for reducing the costs of MFCs for wastewater treatment applications.

  2. 48 CFR 52.209-6 - Protecting the Government's Interest When Subcontracting With Contractors Debarred, Suspended, or...

    Science.gov (United States)

    2010-10-01

    ...'s Interest When Subcontracting With Contractors Debarred, Suspended, or Proposed for Debarment. 52....209-6 Protecting the Government's Interest When Subcontracting With Contractors Debarred, Suspended... Government's Interest When Subcontracting With Contractors Debarred, Suspended, or Proposed for Debarment...

  3. Organic anodes and sulfur/selenium cathodes for advanced Li and Na batteries

    Science.gov (United States)

    Luo, Chao

    To address energy crisis and environmental pollution induced by fossil fuels, there is an urgent demand to develop sustainable, renewable, environmental benign, low cost and high capacity energy storage devices to power electric vehicles and enhance clean energy approaches such as solar energy, wind energy and hydroenergy. However, the commercial Li-ion batteries cannot satisfy the critical requirements for next generation rechargeable batteries. The commercial electrode materials (graphite anode and LiCoO 2 cathode) are unsustainable, unrenewable and environmental harmful. Organic materials derived from biomasses are promising candidates for next generation rechargeable battery anodes due to their sustainability, renewability, environmental benignity and low cost. Driven by the high potential of organic materials for next generation batteries, I initiated a new research direction on exploring advanced organic compounds for Li-ion and Na-ion battery anodes. In my work, I employed croconic acid disodium salt and 2,5-Dihydroxy-1,4-benzoquinone disodium salt as models to investigate the effects of size and carbon coating on electrochemical performance for Li-ion and Na-ion batteries. The results demonstrate that the minimization of organic particle size into nano-scale and wrapping organic materials with graphene oxide can remarkably enhance the rate capability and cycling stability of organic anodes in both Li-ion and Na-ion batteries. To match with organic anodes, high capacity sulfur and selenium cathodes were also investigated. However, sulfur and selenium cathodes suffer from low electrical conductivity and shuttle reaction, which result in capacity fading and poor lifetime. To circumvent the drawbacks of sulfur and selenium, carbon matrixes such as mesoporous carbon, carbonized polyacrylonitrile and carbonized perylene-3, 4, 9, 10-tetracarboxylic dianhydride are employed to encapsulate sulfur, selenium and selenium sulfide. The resulting composites exhibit

  4. 78 FR 48145 - Lemon Juice From Argentina: Continuation of Suspended Antidumping Duty Investigation

    Science.gov (United States)

    2013-08-07

    ... Doc No: 2013-19067] DEPARTMENT OF COMMERCE International Trade Administration [A-357-818] Lemon Juice... of the suspended investigation on lemon juice from Argentina would likely lead to continuation or... of the suspended antidumping duty investigation on lemon juice from Argentina (``suspended...

  5. Diffraction phase microscopy imaging and multi-physics modeling of the nanoscale thermal expansion of a suspended resistor.

    Science.gov (United States)

    Wang, Xiaozhen; Lu, Tianjian; Yu, Xin; Jin, Jian-Ming; Goddard, Lynford L

    2017-07-04

    We studied the nanoscale thermal expansion of a suspended resistor both theoretically and experimentally and obtained consistent results. In the theoretical analysis, we used a three-dimensional coupled electrical-thermal-mechanical simulation and obtained the temperature and displacement field of the suspended resistor under a direct current (DC) input voltage. In the experiment, we recorded a sequence of images of the axial thermal expansion of the central bridge region of the suspended resistor at a rate of 1.8 frames/s by using epi-illumination diffraction phase microscopy (epi-DPM). This method accurately measured nanometer level relative height changes of the resistor in a temporally and spatially resolved manner. Upon application of a 2 V step in voltage, the resistor exhibited a steady-state increase in resistance of 1.14 Ω and in relative height of 3.5 nm, which agreed reasonably well with the predicted values of 1.08 Ω and 4.4 nm, respectively.

  6. Suspended 3D pyrolytic carbon microelectrodes for electrochemistry

    DEFF Research Database (Denmark)

    Hemanth, Suhith; Caviglia, Claudia; Keller, Stephan Sylvest

    2017-01-01

    Carbon microelectrodes have a wide range of applications because of their unique material properties and biocompatibility. This work presents the fabrication and characterization of suspended pyrolytic carbon microstructures serving as three-dimensional (3D) carbon microelectrodes for electrochem...... resistance as compared to 2D carbon electrodes. The higher sensitivity of 3D carbon microelectrodes for electrochemical sensing was illustrated by dopamine detection.......Carbon microelectrodes have a wide range of applications because of their unique material properties and biocompatibility. This work presents the fabrication and characterization of suspended pyrolytic carbon microstructures serving as three-dimensional (3D) carbon microelectrodes...... for electrochemical applications. A 3D polymer template in epoxy based photoresist (SU-8) was fabricated with multiple steps of UV photolithography and pyrolysed at 900 °C to obtain 3D carbon microelectrodes. The pyrolytic carbon microstructures were characterized by SEM, Raman spectroscopy and XPS to determine...

  7. Investigating Design Research Landscapes through Exhibition

    DEFF Research Database (Denmark)

    Jönsson, Li; Hansen, Flemming Tvede; Mäkelä, Maarit

    2013-01-01

    What characterizes a design research exhibition compared to a traditional design and art exhibition? How do you show the very materialities of the design experiments as a means for communicating knowledge of research and of practice? How do you present, review and utilize such an exhibition? With...

  8. Inert Anode/Cathode Program: Fiscal Year 1986 annual report. [For Hall-Heroult cells

    Energy Technology Data Exchange (ETDEWEB)

    Brenden, B.B.; Davis, N.C.; Koski, O.H.; Marschman, S.C.; Pool, K.H.; Schilling, C.H.; Windisch, C.F.; Wrona, B.J.

    1987-06-01

    Purpose of the program is to develop long-lasting, energy-efficient anodes, cathodes, and ancillary equipment for Hall-Heroult cells used by the aluminum industry. The program is divided into four tasks: Inert Anode Development, Cathode Materials Evaluation, Cathode Bonding Development, and Sensor Development. To devise sensors to control the chemistry of Hall-Heroult cells using stable anodes and cathodes. This report highlights the major FY86 technical accomplishments, which are presented in the following sections: Management, Materials Development, Materials Evaluation, Thermodynamic Evaluation, Laboratory Cell Tests, Large-Scale Tests, Cathode Materials Evaluation, Cathode Bonding Development, and Sensor Development.

  9. Chromium poisoning of LSM/YSZ and LSCF/CGO composite cathodes

    DEFF Research Database (Denmark)

    Bentzen, Janet Jonna; Høgh, Jens Valdemar Thorvald; Barfod, Rasmus

    2009-01-01

    An electrochemical study of SOFC cathode degradation, due to poisoning by chromium oxide vapours, was performed applying 3-electrode set-ups. The cathode materials comprised LSM/YSZ and LSCF/CGO composites, whereas the electrolyte material was 8YSZ. The degradation of the cathode performance...... from 300 to 2,970 h. Both LSM/YSZ and LSCF/CGO cathodes were sensitive to chromium poisoning; LSCF/CGO cathodes to a lesser extent than LSM/YSZ. Humid air aggravated the degradation of the cathode performance. Post-mortem electron microscopic investigations revealed several Cr-containing compounds...

  10. Remote Sensing of Suspended Sediment Dynamics in the Mississippi Sound

    Science.gov (United States)

    Merritt, D. N.; Skarke, A. D.; Silwal, S.; Dash, P.

    2016-02-01

    The Mississippi Sound is a semi-enclosed estuary between the coast of Mississippi and a chain of offshore barrier islands with relatively shallow water depths and high marine biodiversity that is wildly utilized for commercial fishing and public recreation. The discharge of sediment-laden rivers into the Mississippi Sound and the adjacent Northern Gulf of Mexico creates turbid plumes that can extend hundreds of square kilometers along the coast and persist for multiple days. The concentration of suspended sediment in these coastal waters is an important parameter in the calculation of regional sediment budgets as well as analysis of water-quality factors such as primary productivity, nutrient dynamics, and the transport of pollutants as well as pathogens. The spectral resolution, sampling frequency, and regional scale spatial domain associated with satellite based sensors makes remote sensing an ideal tool to monitor suspended sediment dynamics in the Northern Gulf of Mexico. Accordingly, the presented research evaluates the validity of published models that relate remote sensing reflectance with suspended sediment concentrations (SSC), for similar environmental settings, with 51 in situ observations of SSC from the Mississippi Sound. Additionally, regression analysis is used to correlate additional in situ observations of SSC in Mississippi Sound with coincident observations of visible and near-infrared band reflectance collected by the Moderate Resolution Imaging Spectroradiometer (MODIS) sensor aboard the Aqua satellite, in order to develop a site-specific empirical predictive model for SSC. Finally, specific parameters of the sampled suspended sediment such as grain size and mineralogy are analyzed in order to quantify their respective contributions to total remotely sensed reflectance.

  11. Development of a microfluidic interface for suspended microchannel resonators

    OpenAIRE

    Maillard, Damien

    2016-01-01

    Suspended microchannel resonators (SMRs) are devices that detect particles in liquid samples. In comparison with similar resonating devices that must be immersed, SMRs allow the fluids to flow through microfluidic resonators. This principle of operation leads to a great reduction of the required sample and to enhanced quality factors. As such, SMRs show great potential for a variety of sensing applications. This thesis reports on the final steps of the microfabrication of SMRs and on the deve...

  12. On the Design of Suspended Roofs with Paraboloidal Surfaces

    Directory of Open Access Journals (Sweden)

    N. Ungureanu

    2006-01-01

    Full Text Available Some considerations concerning the design of the paraboloidal suspended roofs are made. The main geometric aspects are first time presented. For the roofs we propose, as pattern, the equivalent continuum membranes, and the efforts in the cable are determined by using the membrane efforts and their equations. Two examples are analyzed: elliptic paraboloide and hyperbolic paraboloide, with horizontal projection under the form of an ellipse.

  13. Technological advances in suspended-sediment surrogate monitoring

    Science.gov (United States)

    Gray, John R.; Gartner, Jeffrey W.

    2009-01-01

    Surrogate technologies to continuously monitor suspended sediment show promise toward supplanting traditional data collection methods requiring routine collection and analysis of water samples. Commercially available instruments operating on bulk optic (turbidity), laser optic, pressure difference, and acoustic backscatter principles are evaluated based on cost, reliability, robustness, accuracy, sample volume, susceptibility to biological fouling, and suitable range of mass concentration and particle size distribution. In situ turbidimeters are widely used. They provide reliable data where the point measurements can be reliably correlated to the river's mean cross section concentration value, effects of biological fouling can be minimized, and concentrations remain below the sensor's upper measurement limit. In situ laser diffraction instruments have similar limitations and can cost 6 times the approximate $5000 purchase price of a turbidimeter. However, laser diffraction instruments provide volumetric-concentration data in 32 size classes. Pressure differential instruments measure mass density in a water column, thus integrating substantially more streamflow than a point measurement. They are designed for monitoring medium-to-large concentrations, are generally unaffected by biological fouling, and cost about the same as a turbidimeter. However, their performance has been marginal in field applications. Acoustic Doppler profilers use acoustic backscatter to measure suspended sediment concentrations in orders of magnitude more streamflow than do instruments that rely on point measurements. The technology is relatively robust and generally immune to effects of biological fouling. Cost of a single-frequency device is about double that of a turbidimeter. Multifrequency arrays also provide the potential to resolve concentrations by clay silt versus sand size fractions. Multifrequency hydroacoustics shows the most promise for revolutionizing collection of continuous

  14. Segment Fixed Priority Scheduling for Self Suspending Real Time Tasks

    Science.gov (United States)

    2016-08-11

    for soft real- time systems [15]. Table 1 shows a brief... for execution are the times when a job of task arrives. For 2 ≤ ≤ , when , finishes its execution, it suspends itself for a time duration that lies...assume , and , can take non-negative values such that , ≤ , and let , = , . For each job, a segment , executes for a time duration that lies in

  15. Suspended biofilm carrier and activated sludge removal of acidic pharmaceuticals

    DEFF Research Database (Denmark)

    Falås, Per; Baillon-Dhumez, Aude; Andersen, Henrik Rasmus

    2012-01-01

    Removal of seven active pharmaceutical substances (ibuprofen, ketoprofen, naproxen, diclofenac, clofibric acid, mefenamic acid, and gemfibrozil) was assessed by batch experiments, with suspended biofilm carriers and activated sludge from several full-scale wastewater treatment plants. A distinct...... and attached solids for the carriers) of diclofenac, ketoprofen, gemfibrozil, clofibric acid and mefenamic acid compared to the sludges. Among the target pharmaceuticals, only ibuprofen and naproxen showed similar removal rates per unit biomass for the sludges and biofilm carriers. In contrast...

  16. Electron and ion kinetics in a micro hollow cathode discharge

    Energy Technology Data Exchange (ETDEWEB)

    Kim, G J; Iza, F; Lee, J K [Electronics and Electrical Engineering Department, Pohang University of Science and Technology, Pohang, 790-784 (Korea, Republic of)

    2006-10-21

    Electron and ion kinetics in a micro hollow cathode discharge are investigated by means of two-dimensional axisymmetric particle-in-cell Monte Carlo collision simulations. Argon discharges at 10 and 300 Torr are studied for various driving currents. Electron and ion energy probability functions (IEPF) are shown at various times and locations to study the spatio-temporal behaviour of the discharge. The electron energy probability function (EEPF) evolves from the Druyvesteyn type in the early stages of the discharge into a two (or three) temperature distribution when steady state is reached. In steady state, secondary electrons accelerated across the cathode fall populate the high energy tail of the EEPF while the low energy region is populated by trapped electrons. The IEPF evolves from a Maxwellian in the negative glow (bulk) to a two temperature distribution on the cathode surface. The overpopulation of low energy ions near the cathode surface is attributed to a larger collision cross section for low energy ions and ionization within the cathode fall.

  17. Degradation characteristics of air cathode in zinc air fuel cells

    Science.gov (United States)

    Ma, Ze; Pei, Pucheng; Wang, Keliang; Wang, Xizhong; Xu, Huachi; Liu, Yongfeng; peng, Guanlin

    2015-01-01

    The zinc air fuel cell (ZAFC) is a promising candidate for electrical energy storage and electric vehicle propulsion. However, its limited durability has become a major obstacle for its successful commercialization. In this study, 2-cell stacks, 25 cm² cells and three-electrode half-cells are constructed to experimentally investigate the degradation characteristics of the air cathode. The results of electrochemical tests reveal that the peak power density for the 25 cm2 cell with a new air cathode is 454 mW cm-2, which is twice as the value of the used air cathode. The electrochemical impedance analysis shows that both the charge transfer resistance and the mass transfer resistance of the used air cathodes have increased, suggesting that the catalyst surface area and gas diffusion coefficient have decreased significantly. Additionally, the microstructure and morphology of the catalytic layer (CL) and gas diffusion layer (GDL) are characterized by scanning electron microscopes (SEM). SEM results confirm that the micropores in CL and GDL of the used air cathode are seriously clogged, and many catalyst particles are lost. Therefore, the performance degradation is mainly due to the clogging of micropores and loss of catalyst particles. Furthermore, hypotheses of degradation mechanism and mitigation strategies for GDL and CL are discussed briefly.

  18. Strain sensitivity enhancement in suspended core fiber tapers

    Science.gov (United States)

    André, Ricardo M.; Silva, Susana O.; Becker, Martin; Schuster, Kay; Rothardt, M.; Bartelt, H.; Marques, Manuel B.; Frazão, Orlando

    2013-06-01

    Suspended core fiber tapers with different cross sections (with diameters from 70 μm to 120 μm) are produced by filament heating. Before obtaining the taper, the spectral behavior of the suspended core fiber is a multimode interference structure. When the taper is made, an intermodal interference between a few modes is observed. This effect is clearly visible for low taper core dimensions. Since the core and cladding do not collapse, two taper regions exist, one in the core and the other in the cladding. The cladding taper does not affect the light transmission, only the core is reduced to a microtaper. The spectral response of the microtaper based-suspended core fiber is similar to a beat of two interferometers. The strain is applied to the microtaper, and with the reduction in the transverse area, an increase in sensitivity is observed. When the taper is immersed in a liquid with a different index of refraction or subjected to temperature variations, no spectral change occurs.

  19. Optimal control of suspended sediment distribution model of Talaga lake

    Science.gov (United States)

    Ratianingsih, R.; Resnawati, Azim, Mardlijah, Widodo, B.

    2017-08-01

    Talaga Lake is one of several lakes in Central Sulawesi that potentially to be managed in multi purposes scheme because of its characteristic. The scheme is addressed not only due to the lake maintenance because of its sediment but also due to the Algae farming for its biodiesel fuel. This paper governs a suspended sediment distribution model of Talaga lake. The model is derived from the two dimensional hydrodynamic shallow water equations of the mass and momentum conservation law of sediment transport. An order reduction of the model gives six equations of hyperbolic systems of the depth, two dimension directional velocities and sediment concentration while the bed elevation as the second order of turbulent diffusion and dispersion are neglected. The system is discreted and linearized such that could be solved numerically by box-Keller method for some initial and boundary condition. The solutions shows that the downstream velocity is play a role in transversal direction of stream function flow. The downstream accumulated sediment indicate that the suspended sediment and its changing should be controlled by optimizing the downstream velocity and transversal suspended sediment changing due to the ideal algae growth need.

  20. Affordances and distributed cognition in museum exhibitions

    DEFF Research Database (Denmark)

    Achiam, Marianne; May, Michael; Marandino, Martha

    2014-01-01

    consistent framework. Here, we invoke the notions of affordance and distributed cognition to explain in a coherent way how visitors interact with exhibits and exhibit spaces and make meaning from those interactions, and we exemplify our points using observations of twelve visitors to exhibits at a natural...... history museum. We show how differences in exhibit characteristics give rise to differences in the interpretive strategies used by visitors in their meaning-making process, and conclude by discussing how the notions of affordance and distributed cognition can be used in an exhibit design perspective....

  1. A Heuristic for Improving Transmedia Exhibition Experience

    DEFF Research Database (Denmark)

    Selvadurai, Vashanth; Rosenstand, Claus Andreas Foss

    2017-01-01

    The area of interest is transmedia experiences in exhibitions. The research question is: How to involve visitors in a transmedia experience for an existing exhibition, which bridges the pre-, during- and post-experience? Research through design, and action research are the methods used to design...... and reflect on a transmedia experience for an existing exhibition. This is framed with literature about exhibitions and transmedia, and analyzed with quantitative data from a case-study of visitors in the exhibition; this is organizationally contextualized. The contribution covers a significant gap...... in the scientific field of designing transmedia experience in an exhibition context that links the pre- and post-activities to the actual visit (during-activities). The result of this study is a preliminary heuristic for establishing a relation between the platform and content complexity in transmedia exhibitions....

  2. A Polysulfide-Trapping Interface for Electrochemically Stable Sulfur Cathode Development.

    Science.gov (United States)

    Chung, Sheng-Heng; Han, Pauline; Manthiram, Arumugam

    2016-02-01

    Lithium-sulfur (Li-S) cells have a strong edge to become an inexpensive, high-capacity rechargeable battery system. However, currently, several prohibitive challenges occur within the sulfur core, especially the polysulfide-diffusion problem. To address these scientific issues, we present here a boron-doped multiwalled carbon nanotube coated separator (B-CNT-coated separator). The B-CNT-coated separator creates a polysulfide trap between the pure sulfur cathode and the polymeric separator as a "polysulfide-trapping interface," stabilizing the active material and allowing the dissolved polysulfides to activate the bulk sulfur cores. Therefore, the dissolved polysulfides change from causing fast capacity fade to assisting with the activation of bulk sulfur clusters in pure sulfur cathodes. Moreover, the heteroatom-doped polysulfide-trapping interface is currently one of the missing pieces of carbon-coated separators, which might inspire further studies in its effect and battery chemistry. Li-S cells employing B-CNT-coated separators (i) exhibit improved cyclability at various cycling rates from 0.2C to 1.0C rate and (ii) attain a high capacity retention rate of 60% with a low capacity fade rate of 0.04% cycle(-1) after 500 cycles. We believe that our B-CNT-coated separator could light up a new research area for integrating heteroatom-doped carbon into the flexible, lightweight, carbon-coated separator.

  3. Platinum-Coated Hollow Graphene Nanocages as Cathode Used in Lithium-Oxygen Batteries

    Energy Technology Data Exchange (ETDEWEB)

    Wu, Feng [Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081 P. R. China; Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081 P. R. China; Xing, Yi [Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081 P. R. China; Zeng, Xiaoqiao [Chemical Science and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA; Yuan, Yifei [Chemical Science and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA; Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive Houghton MI 49931 USA; Zhang, Xiaoyi [X-ray Science Division, Argonne National Laboratory, Argonne IL 60439 USA; Shahbazian-Yassar, Reza [Department of Materials Science and Engineering, Michigan Technological University, 1400 Townsend Drive Houghton MI 49931 USA; Wen, Jianguo [Electron Microscopy Center, Material Science Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA; Miller, Dean J. [Electron Microscopy Center, Material Science Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA; Li, Li [Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081 P. R. China; Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081 P. R. China; Chen, Renjie [Beijing Key Laboratory of Environmental Science and Engineering, School of Material Science & Engineering, Beijing Institute of Technology, Beijing 100081 P. R. China; Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing 100081 P. R. China; Lu, Jun [Chemical Science and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA; Amine, Khalil [Chemical Science and Engineering Division, Argonne National Laboratory, 9700 S. Cass Avenue Lemont IL 60439 USA

    2016-08-31

    One of the formidable challenges facing aprotic lithium-oxygen (Li-O-2) batteries is the high charge overpotential, which induces the formation of byproducts, loss in efficiency, and poor cycling performance. Herein, the synthesis of the ultrasmall Pt-coated hollow graphene nano cages as cathode in Li-O-2 batteries is reported. The charge voltage plateau can reduce to 3.2 V at the current density of 100 mA g(-1), even maintain below 3.5 V when the current density increased to 500 mA g(-1). The unique hollow graphene nanocages matrix can not only provide numerous nanoscale tri-phase regions as active sites for efficient oxygen reduction, but also offer sufficient amount of mesoscale pores for rapid oxygen diffusion. Furthermore, with strong atomic-level oxygen absorption into its subsurface, ultrasmall Pt catalytically serves as the nucleation site for Li2O2 growth. The Li2O2 is subsequently induced into a favorable form with small size and amorphous state, decomposed more easily during recharge. Meanwhile, the conductive hollow graphene substrate can enhance the catalytic activity of noble metal Pt catalysts due to the graphene-metal interfacial interaction. Benefiting from the above synergistic effects between the hollow graphene nanocages and the nanosized Pt catalysts, the ultrasmall Pt-decorated graphene nanocage cathode exhibits enhanced electrochemical performances.

  4. Performance of Zn rechargeable cells having Polypyrrole cathodes doped with surfactant anion

    Directory of Open Access Journals (Sweden)

    W.A.D.S. S Weerasinghe

    2015-12-01

    Full Text Available Currently there exists a very high demand for electrochemical energy storage devices such as rechargeable cells and super capacitors due to massive increase in the use of portable electronics. At the moment this demand is mainly supplied by Li based cells. However due to high cost, rapid reactivity and issues in disposal of Li attention has diverted on non Li based cells. Zn has been identified as a good candidate to replace Li. Even though several Zn based rechargeable cells were reported, less work has been carried out on cells with conducting polymer cathode based Zn cells. In this study, performance of Zn rechargeable cells fabricated with conducting polymer Polypyrrole(PPy doped with a surfactant anion is reported. PPy films were galvanostatically electro polymerized on to stainless steel disc and cells were assembled with a Polyvinylidenefluoride based gel polymer electrolyte having Zinc trifluoromethanesulfonate as the salt. Cells having different cathode thickness were fabricated and they were characterized using cyclic voltammetry, electrochemical impedance spectroscopy and continuous charge-discharge tests. Cells exhibit open circuit voltages between 0.9 -1.0 V. Cycling testes showed that cycleable capacity almost follow the thickness variation. Continuous charge-discharge tests revealed that the capacity decrement with the cycle number is higher in thinner films.

  5. Reduced Graphene Oxide-Wrapped Nickel-Rich Cathode Materials for Lithium Ion Batteries.

    Science.gov (United States)

    Shim, Jae-Hyun; Kim, Young-Min; Park, Miji; Kim, Jongsik; Lee, Sanghun

    2017-06-07

    The encapsulation of Ni-rich cathode materials (LiNi0.6Co0.2Mn0.2O2) for lithium ion batteries in reduced graphene oxide (rGO) sheets is introduced to improve electrochemical performances. Using (3-aminopropyl)triethoxysilane, the active materials are completely wrapped with several rGO layers of ∼2 nm thickness. By virtue of the great electrical conductivity of graphene, the rGO-coated cathode materials exhibit much enhanced electrochemical performances of cycling property and rate capability. In addition, it is shown that the structural degradation of the active materials, which is from the rhombohedral layered structure (R3̅m) to the spinel (Fd3̅m) or rock-salt phase (Fm3̅m), is significantly reduced as well as delayed due to the protection of the active materials in the rGO layers from direct contact with electrolytes and the consequent suppression of side reactions.

  6. Hierarchical surface atomic structure of a manganese-based spinel cathode for lithium-ion batteries.

    Science.gov (United States)

    Lee, Sanghan; Yoon, Gabin; Jeong, Minseul; Lee, Min-Joon; Kang, Kisuk; Cho, Jaephil

    2015-01-19

    The increasing use of lithium-ion batteries (LIBs) in high-power applications requires improvement of their high-temperature electrochemical performance, including their cyclability and rate capability. Spinel lithium manganese oxide (LiMn2O4) is a promising cathode material because of its high stability and abundance. However, it exhibits poor cycling performance at high temperatures owing to Mn dissolution. Herein we show that when stoichiometric lithium manganese oxide is coated with highly doped spinels, the resulting epitaxial coating has a hierarchical atomic structure consisting of cubic-spinel, tetragonal-spinel, and layered structures, and no interfacial phase is formed. In a practical application of the coating to doped spinel, the material retained 90% of its capacity after 800 cycles at 60 °C. Thus, the formation of an epitaxial coating with a hierarchical atomic structure could enhance the electrochemical performance of LIB cathode materials while preventing large losses in capacity. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  7. Two-Electron Reaction without Structural Phase Transition in Nanoporous Cathode Material

    Directory of Open Access Journals (Sweden)

    Tomoyuki Matsuda

    2012-01-01

    Full Text Available We investigated the charge/discharge properties, valence states, and structural properties of a nanoporous cathode material LixMn[Fe(CN6]0.83·3.5H2O. The film-type electrode of LixMn[Fe(CN6]0.83·3.5H2O exhibited a high charge capacity (=128 mAh g-1 and a good cyclability (87% of the initial value after 100 cycles and is one of the promising candidates for Li-ion battery cathode. X-ray absorption spectra near the Fe and Mn K-edges revealed that the charge/discharge process is a two-electron reaction; that is, MnII–NC–FeII, MnII–NC–FeIII, and MnIII–NC–FeIII. We further found that the crystal structure remains cubic throughout the charge/discharge process. The lattice constant slightly increased during the [FeII(CN6]4-/[FeIII(CN6]3- oxidization reaction while decreased during the MnII/MnIII oxidization reaction. The two-electron reaction without structural phase transition is responsible for the high charge capacity and the good cyclability.

  8. High-Performance Aluminum-Ion Battery with CuS@C Microsphere Composite Cathode.

    Science.gov (United States)

    Wang, Shuai; Jiao, Shuqiang; Wang, Junxiang; Chen, Hao-Sen; Tian, Donghua; Lei, Haiping; Fang, Dai-Ning

    2017-01-24

    On the basis of low-cost, rich resources, and safety performance, aluminum-ion batteries have been regarded as a promising candidate for next-generation energy storage batteries in large-scale energy applications. A rechargeable aluminum-ion battery has been fabricated based on a 3D hierarchical copper sulfide (CuS) microsphere composed of nanoflakes as cathode material and room-temperature ionic liquid containing AlCl3 and 1-ethyl-3-methylimidazolium chloride ([EMIm]Cl) as electrolyte. The aluminum-ion battery with a microsphere electrode exhibits a high average discharge voltage of ∼1.0 V vs Al/AlCl4(-), reversible specific capacity of about 90 mA h g(-1) at 20 mA g(-1), and good cyclability of nearly 100% Coulombic efficiency after 100 cycles. Such remarkable electrochemical performance is attributed to the well-defined nanostructure of the cathode material facilitating the electron and ion transfer, especially for chloroaluminate ions with large size, which is desirable for aluminum-ion battery applications.

  9. A 13000-hour test of a mercury hollow cathode

    Science.gov (United States)

    Rawlin, V. K.

    1973-01-01

    A mercury-fed hollow cathode was tested for 12,979 hours in a bell jar at SERT 2 neutralizer operating conditions. The net electron current drawn to a collector was 0.25 ampere at average collector voltages between 21.8 and 36.7 volts. The mercury flow rate was varied from 5.6 to 30.8 equivalent milliamperes to give stable operation at the desired electrode voltages and currents. Variations with time in the neutralizer discharge characteristics were observed and hypothesized to be related to changes in the cathode orifice dimensions and the availability of electron emissive material. A facility failure caused abnormal test conditions for the last 876 hours and led to the cathode heater failure which concluded the test.

  10. Characteristic of a triple-cathode vacuum arc plasma source.

    Science.gov (United States)

    Xiang, W; Li, M; Chen, L

    2012-02-01

    In order to generate a better ion beam, a triple-cathode vacuum arc plasma source has been developed. Three plasma generators in the vacuum arc plasma source are equally located on a circle. Each generator initiated by means of a high-voltage breakdown between the cathode and the anode could be operated separately or simultaneously. The arc plasma expands from the cathode spot region in vacuum. In order to study the behaviors of expanding plasma plume generated in the vacuum arc plasma source, a Langmuir probe array is employed to measure the saturated ion current of the vacuum arc plasma source. The time-dependence profiles of the saturated current density of the triple vacuum arc plasma source operated separately and simultaneously are given. Furthermore, the plasma characteristic of this vacuum arc plasma source is also presented in the paper.

  11. An interchangeable-cathode vacuum arc plasma source.

    Science.gov (United States)

    Olson, David K; Peterson, Bryan G; Hart, Grant W

    2010-01-01

    A simplified vacuum arc design [based on metal vapor vacuum arc (MeVVA) concepts] is employed as a plasma source for a study of a (7)Be non-neutral plasma. The design includes a mechanism for interchanging the cathode source. Testing of the plasma source showed that it is capable of producing on the order of 10(12) charges at confinable energies using a boron-carbide disk as the cathode target. The design is simplified from typical designs for lower energy and lower density applications by using only the trigger spark rather than the full vacuum arc in high current ion beam designs. The interchangeability of the cathode design gives the source the ability to replace only the source sample, simplifying use of radioactive materials in the plasma source. The sample can also be replaced with a completely different conductive material. The design can be easily modified for use in other plasma confinement or full MeVVA applications.

  12. Tandem cathode for proton exchange membrane fuel cells

    DEFF Research Database (Denmark)

    Siahrostami, Samira; Björketun, Mårten E.; Strasser, Peter

    2013-01-01

    tandem cathode design where the full oxygen reduction, involving four electron-transfer steps, is divided into formation (equilibrium potential 0.70 V) followed by reduction (equilibrium potential 1.76 V) of hydrogen peroxide. The two part reactions contain only two electron-transfer steps and one......The efficiency of proton exchange membrane fuel cells is limited mainly by the oxygen reduction reaction at the cathode. The large cathodic overpotential is caused by correlations between binding energies of reaction intermediates in the reduction of oxygen to water. This work introduces a novel...... reaction intermediate each, and they occur on different catalyst surfaces. As a result they can be optimized independently and the fundamental problem associated with the four-electron catalysis is avoided. A combination of density functional theory calculations and published experimental data is used...

  13. Wettable Ceramic-Based Drained Cathode Technology for Aluminum Electrolysis

    Energy Technology Data Exchange (ETDEWEB)

    J.N. Bruggeman; T.R. Alcorn; R. Jeltsch; T. Mroz

    2003-01-09

    The goal of the project was to develop the ceramic based materials, technology, and necessary engineering packages to retrofit existing aluminum reduction cells in order to reduce energy consumption required for making primary aluminum. The ceramic materials would be used in a drained cathode configuration which would provide a stable, molten aluminum wetted cathode surface, allowing the reduction of the anode-cathode distance, thereby reducing the energy consumption. This multi-tasked project was divided into three major tasks: (1) Manufacturing and laboratory scale testing/evaluation of the ceramic materials, (2) Pilot scale testing of qualified compositions from the first task, and (3) Designing, retrofitting, and testing the ceramic materials in industrial cells at Kaiser Mead plant in Spokane, Washington. Specific description of these major tasks can be found in Appendix A - Project Scope. Due to the power situation in the northwest, the Mead facility was closed, thus preventing the industrial cell testing.

  14. Electrochemical studies on the cathodic reaction of marine atmospheric corrosion

    Science.gov (United States)

    Wang, Jia

    1996-12-01

    Electrochemical studies on the cathodic reaction of marine atmospheric corrosion using Kelvin probe as reference electrode showed that the rate of cathodic reaction-oxygen reduction first increases then decreases, with the reaction maximizing at a certain thickness as the electrolyte film decreases during evaporation. It was indicated that with decreasing electrolyte thickness by drying, the oxygen reduction rate was accelerated by the faster oxygen diffusion due to the thinner electrolyte layer on the metal surface. The results also revealed that although the oxygen salting out effect has great influence on the rate of oxygen reduction, it is not the main causative factor for the decrease in cathodic limiting current in the case of a very thin electrolyte layer.

  15. Measurement and analysis of thermal photoemission from a dispenser cathode

    Directory of Open Access Journals (Sweden)

    Kevin L. Jensen

    2003-08-01

    Full Text Available Photocathodes for free electron lasers (FELs are required to produce nano-Coulomb pulses in picosecond time scales with demonstrable reliability, lifetime, and efficiency. Dispenser cathodes, traditionally a rugged and long-lived thermionic source, are under investigation to determine their utility as a photocathode and have shown promise. The present study describes theoretical models under development to analyze experimental data from dispenser cathodes and to create predictive time-dependent models to predict their performance as an FEL source. Here, a steady-state model of a dispenser cathode with partial coverage of a low work function coating and surface nonuniformity is developed. Quantitative agreement is found for experimental data, especially with regard to temperature, field, laser intensity, and quantum efficiency versus laser wavelength dependence. In particular, for long wavelength incident lasers of sufficient intensity, the majority of the absorbed energy heats the electron gas and background lattice, and photoemission from the heated electron distribution constitutes the emitted current.

  16. Single chamber microbial fuel cell with Ni-Co cathode

    Science.gov (United States)

    Włodarczyk, Barbara; Włodarczyk, Paweł P.; Kalinichenko, Antonina

    2017-10-01

    The possibility of wastewater treatment and the parallel energy production using the Ni-Co alloy as cathode catalyst for single chamber microbial fuel cells is presented in this research. The research included a preparation of catalyst and comparison of COD, NH4+ and NO3- reduction in the reactor without aeration, with aeration and with using a single chamber microbial fuel cell with Ni-Co cathode. The reduction time for COD with the use of microbial fuel cell with the Ni-Co catalyst is similar to the reduction time with aeration. The current density (2.4 A·m-2) and amount of energy (0.48 Wh) obtained in MFC is low, but the obtained amount of energy allows elimination of the energy needed for reactor aeration. It has been shown that the Ni-Co can be used as cathode catalyst in single chamber microbial fuel cells.

  17. A Transient Model for Fuel Cell Cathode-Water Propagation Behavior inside a Cathode after a Step Potential

    Directory of Open Access Journals (Sweden)

    Der-Sheng Chan

    2010-04-01

    Full Text Available Most of the voltage losses of proton exchange membrane fuel cells (PEMFC are due to the sluggish kinetics of oxygen reduction on the cathode and the low oxygen diffusion rate inside the flooded cathode. To simulate the transient flooding in the cathode of a PEMFC, a transient model was developed. This model includes the material conservation of oxygen, vapor, water inside the gas diffusion layer (GDL and micro-porous layer (MPL, and the electrode kinetics in the cathode catalyst layer (CL. The variation of hydrophobicity of each layer generated a wicking effect that moves water from one layer to the other. Since the GDL, MPL, and CL are made of composite materials with different hydrophilic and hydrophobic properties, a linear function of saturation was used to calculate the wetting contact angle of these composite materials. The balance among capillary force, gas/liquid pressure, and velocity of water in each layer was considered. Therefore, the dynamic behavior of PEMFC, with saturation transportation taken into account, was obtained in this study. A step change of the cell voltage was used to illustrate the transient phenomena of output current, water movement, and diffusion of oxygen and water vapor across the entire cathode.

  18. Back bombardment for dispenser and lanthanum hexaboride cathodes

    Directory of Open Access Journals (Sweden)

    Mahmoud Bakr

    2011-06-01

    Full Text Available The back bombardment (BB effect limits wide usage of thermionic rf guns. The BB effect induces not only ramping-up of a cathode’s temperature and beam current, but also degradation of cavity voltage and beam energy during a macropulse. This paper presents a comparison of the BB effect for the case of dispenser tungsten-base (DC and lanthanum hexaboride (LaB_{6} thermionic rf gun cathodes. For each, particle simulation codes are used to simulate the BB effect and electron beam dynamics in a thermionic rf gun cathode. A semiempirical equation is also used to investigate the stopping range and deposited heat power of BB electrons in the cathode material. A numerical simulation method is used to calculate the change of the cathode temperature and current density during a single macropulse. This is done by solving two differential equations for the rf gun cavity equivalent circuit and one-dimensional thermal diffusion equation. High electron emission and small beam size are required for generation of a high-brightness electron beam, and so in this work the emission properties of the cathode are taken into account. Simulations of the BB effect show that, for a pulse of 6  μs duration, the DC cathode experiences a large change in the temperature compared with LaB_{6}, and a change in current density 6 times higher. Validation of the simulation results is performed using experimental data for beam current beyond the gun exit. The experimental data is well reproduced using the simulation method.

  19. Space exhibitions: the science encounters the public

    Science.gov (United States)

    Coliolo, F.; Menendez, M.

    The widespread dissemination of science has always been one pillar of the development of human knowledge. There are several methods to structure interaction with the public: media, conferences, various written genres, and exhibitions. But: how to attract the public? How to arouse interest among future generation, insatiable for knowledge? In this paper we focus on space exhibitions, whose content combines mystery, discovery and science. The preparation of an exhibition is based on guidelines discussed between an interdisciplinary team and the exhibition project manager, the purpose of which is to find a coherent "strategy" to select information and to choose a concise, efficient, smart and original way to "visualize" the messages. Exhibition visitors are "privileged" because the interactivity is first emotive, then mental and cultural; the audience is universal. The goal of an exhibition is not to explain the content, but to stimulate the audience's curiosity in an attractive environment. We show some photos of ESA exhibitions, and try to understand if the visual impact is the first step towards a "multi-sensory" approach to communication. "A good exhibition can never be replaced by a book, a film or a lecture. A good exhibition creates a thirst for books, film, lectures. A good exhibition changes the visitors"(J. Wagensberg, Modern scientific museology")

  20. Improved Cathode Structure for a Direct Methanol Fuel Cell

    Science.gov (United States)

    Valdez, Thomas; Narayanan, Sekharipuram

    2005-01-01

    An improved cathode structure on a membrane/electrode assembly has been developed for a direct methanol fuel cell, in a continuing effort to realize practical power systems containing such fuel cells. This cathode structure is intended particularly to afford better cell performance at a low airflow rate. A membrane/electrode assembly of the type for which the improved cathode structure was developed (see Figure 1) is fabricated in a process that includes brush painting and spray coating of catalyst layers onto a polymer-electrolyte membrane and onto gas-diffusion backings that also act as current collectors. The aforementioned layers are then dried and hot-pressed together. When completed, the membrane/electrode assembly contains (1) an anode containing a fine metal black of Pt/Ru alloy, (2) a membrane made of Nafion 117 or equivalent (a perfluorosulfonic acid-based hydrophilic, proton-conducting ion-exchange polymer), (3) a cathode structure (in the present case, the improved cathode structure described below), and (4) the electrically conductive gas-diffusion backing layers, which are made of Toray 060(TradeMark)(or equivalent) carbon paper containing between 5 and 6 weight percent of poly(tetrafluoroethylene). The need for an improved cathode structure arises for the following reasons: In the design and operation of a fuel-cell power system, the airflow rate is a critical parameter that determines the overall efficiency, cell voltage, and power density. It is desirable to operate at a low airflow rate in order to obtain thermal and water balance and to minimize the size and mass of the system. The performances of membrane/electrode assemblies of prior design are limited at low airflow rates. Methanol crossover increases the required airflow rate. Hence, one way to reduce the required airflow rate is to reduce the effect of methanol crossover. Improvement of the cathode structure - in particular, addition of hydrophobic particles to the cathode - has been

  1. Study on cathode high voltage pulse control in image intensifier

    Science.gov (United States)

    Yang, Ye; Yan, Bo; Ni, Xiao-bing; Zhi, Qiang; Li, Jun-guo; Yao, Ze; Deng, Guang-xu

    2016-03-01

    This paper briefly introduces the basic working principle of auto-gating power source. Due to the presence of noise in the circuit, the cathode pulse signal generated by the AD converter is unstable. In this paper, the circuit of the AD converter is adjusted to improve the instability of the cathode high voltage pulse signal, especially in the case of low light and high illumination to avoid the jitter of the pulse. The experiment was carried out. And it could guide the implementation of this part of the circuit.

  2. Tolerant chalcogenide cathodes of membraneless micro fuel cells.

    Science.gov (United States)

    Gago, Aldo Saul; Gochi-Ponce, Yadira; Feng, Yong-Jun; Esquivel, Juan Pablo; Sabaté, Neus; Santander, Joaquin; Alonso-Vante, Nicolas

    2012-08-01

    The most critical issues to overcome in micro direct methanol fuel cells (μDMFCs) are the lack of tolerance of the platinum cathode and fuel crossover through the polymer membrane. Thus, two novel tolerant cathodes of a membraneless microlaminar-flow fuel cell (μLFFC), Pt(x)S(y) and CoSe(2), were developed. The multichannel structure of the system was microfabricated in SU-8 polymer. A commercial platinum cathode served for comparison. When using 5 M CH(3)OH as the fuel, maximum power densities of 6.5, 4, and 0.23 mW cm(-2) were achieved for the μLFFC with Pt, Pt(x)S(y), and CoSe(2) cathodes, respectively. The Pt(x)S(y) cathode outperformed Pt in the same fuel cell when using CH(3)OH at concentrations above 10 M. In a situation where fuel crossover is 100 %, that is, mixing the fuel with the reactant, the maximum power density of the micro fuel cell with Pt decreased by 80 %. However, for Pt(x)S(y) this decrease corresponded to 35 % and for CoSe(2) there was no change in performance. This result is the consequence of the high tolerance of the chalcogenide-based cathodes. When using 10 M HCOOH and a palladium-based anode, the μLFFC with a CoSe(2) cathode achieved a maxiumum power density of 1.04 mW cm(-2). This micro fuel cell does not contain either Nafion membrane or platinum. We report, for the first time, the evaluation of Pt(x)S(y)- and CoSe(2)-based cathodes in membraneless micro fuel cells. The results suggest the development of a novel system that is not size restricted and its operation is mainly based on the selectivity of its electrodes. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  3. Oxide cathode lifetime improvements at RTNS-II

    Energy Technology Data Exchange (ETDEWEB)

    Massoletti, D.J.

    1986-09-29

    Results are reported for an ongoing effort to optimize D/sup +/ beam production by the MATS-III ion source used at the RTNS-II. The oxide cathode assembly originally designed for lower power operation has been modified and redesigned for higher electron current yield, longer life and serviceability. A factor of 2.5 has been gained in cathode lifetime due to these changes. The details of the changes and results and benefits in operation and performance are given. In addition, the technique used for manufacture of the filament is described.

  4. Field-emission cathode gating for rf electron guns

    OpenAIRE

    Lewellen, J. W.; J. Noonan

    2005-01-01

    We present a novel method of combining the most desirable characteristics of thermionic-cathode and photocathode rf guns, using a field-emission cathode and multiple rf frequencies. Simulations indicate that extremely low-emittance beams (on the order of 2 nm normalized emittance) at moderate beam currents (1 mA) and beam energies of ∼2  MeV can be obtained using this technique. The resulting gun design promises to be useful as a driver source for a number of applications, including high-volt...

  5. Platform cathodic protection design in the South China Sea

    Energy Technology Data Exchange (ETDEWEB)

    Rippon, I. [Sarawak Shell Berhad (Malaysia)

    1997-09-01

    The 1993 revision of one of the industry recommended practices on cathodic protection design offers the operator the opportunity to use his own experience and data to justify more or less conservative designs. Examples of the use of this option to achieve an economic South China Sea design are presented. The design approach on how to subdivide the object being cathodically protected can be applied in any operating area where there is good environmental data. An example of the cost savings achievable by using this approach is presented. The optimized design is 55% of the cost of the design following the 1993 code.

  6. Web-Based Cathode Strip Chamber Data Display

    CERN Multimedia

    Firmansyah, M

    2013-01-01

    Cathode Strip Chamber (CSC) is a detector that uses gas and high electric field to detect particles. When a particle goes through CSC, it will ionize gas particles and generate electric signal in the anode and cathode of the detector. Analysis of the electric signal data can help physicists to reconstruct path of the particles and determine what happen inside the detector. Using data display, analysis of CSC data becomes easier. One can determine which data is interesting, unusual, or maybe only contain noise.\

  7. Lanthanum Manganate Based Cathodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Jørgensen, Mette Juhl

    medium frequency process in the impedance spectra, were observed. A low frequency arc related to gas diffusion limitation in a stagnant gas layer above the composite structure was detected. Finally, an inductive process, assumed to be connected to an activation process involving segregates at the triple......Composite cathodes for solid oxide fuel cells were investigated using electrochemical impedance spectroscopy and scanning electron microscopy. The aim was to study the oxygen reduction process in the electrode in order to minimise the voltage drop in the cathode. The electrodes contained...... phase boundary between electrode, electrolyte and gas phase, was found. Suggestions for further experiments and for modelling of the oxygen reduction mechanism are given....

  8. Chemistry of SOFC Cathode Surfaces: Fundamental Investigation and Tailoring of Electronic Behavior

    Energy Technology Data Exchange (ETDEWEB)

    Yildiz, Bilge; Heski, Clemens

    2013-08-31

    1) Electron tunneling characteristics on La0.7Sr0.3MnO3 (LSM) thin-film surfaces were studied up to 580oC in 10-3mbar oxygen pressure, using scanning tunneling microscopy/ spectroscopy (STM/STS). A threshold-like drop in the tunneling current was observed at positive bias in STS, which is interpreted as a unique indicator for the activation polarization in cation oxygen bonding on LSM cathodes. Sr-enrichment was found on the surface at high temperature using Auger electron spectroscopy, and was accompanied by a decrease in tunneling conductance in STS. This suggests that Sr-terminated surfaces are less active for electron transfer in oxygen reduction compared to Mn-terminated surfaces on LSM. 2) Effects of strain on the surface cation chemistry and the electronic structure are important to understand and control for attaining fast oxygen reduction kinetics on transition metal oxides. Here, we demonstrate and mechanistically interpret the strain coupling to Sr segregation, oxygen vacancy formation, and electronic structure on the surface of La0.7Sr0.3MnO3 (LSM) thin films as a model system. Our experimental results from x-ray photoelectron spectroscopy and scanning tunneling spectroscopy are discussed in light of our first principles-based calculations. A stronger Sr enrichment tendency and a more facile oxygen vacancy formation prevail for the tensile strained LSM surface. The electronic structure of the tensile strained LSM surface exhibits a larger band gap at room temperature, however, a higher tunneling conductance near the Fermi level than the compressively strained LSM at elevated temperatures in oxygen. Our findings suggest lattice strain as a key parameter to tune the reactivity of perovskite transition metal oxides with oxygen in solid oxide fuel cell cathodes. 3) Cation segregation on perovskite oxide surfaces affects vastly the oxygen reduction activity and stability of solid oxide fuel cell (SOFC) cathodes. A unified theory that explains the physical

  9. Investigation of spinel-related and orthorhombic LiMNO2 cathodes for rechargeable lithium batteries

    CSIR Research Space (South Africa)

    Gummow, RJ

    1994-05-01

    Full Text Available Cathode materials that have been synthesized by reduction of lithium-manganese- Cathode materials that have been synthesized by reduction of lithium-manganese-oxide and manganese-oxide precursors with hydrogen at 300 to 350-degrees...

  10. Compact High Current Rare-Earth Emitter Hollow Cathode for Hall Effect Thrusters

    Science.gov (United States)

    Hofer, Richard R. (Inventor); Goebel, Dan M. (Inventor); Watkins, Ronnie M. (Inventor)

    2012-01-01

    An apparatus and method for achieving an efficient central cathode in a Hall effect thruster is disclosed. A hollow insert disposed inside the end of a hollow conductive cathode comprises a rare-earth element and energized to emit electrons from an inner surface. The cathode employs an end opening having an area at least as large as the internal cross sectional area of the rare earth insert to enhance throughput from the cathode end. In addition, the cathode employs a high aspect ratio geometry based on the cathode length to width which mitigates heat transfer from the end. A gas flow through the cathode and insert may be impinged by the emitted electrons to yield a plasma. One or more optional auxiliary gas feeds may also be employed between the cathode and keeper wall and external to the keeper near the outlet.

  11. Power generation using an activated carbon and metal mesh cathode in a microbial fuel cell

    KAUST Repository

    Zhang, Fang

    2009-11-01

    An inexpensive activated carbon (AC) air cathode was developed as an alternative to a platinum-catalyzed electrode for oxygen reduction in a microbial fuel cell (MFC). AC was cold-pressed with a polytetrafluoroethylene (PTFE) binder to form the cathode around a Ni mesh current collector. This cathode construction avoided the need for carbon cloth or a metal catalyst, and produced a cathode with high activity for oxygen reduction at typical MFC current densities. Tests with the AC cathode produced a maximum power density of 1220 mW/m2 (normalized to cathode projected surface area; 36 W/m3 based on liquid volume) compared to 1060 mW/m2 obtained by Pt catalyzed carbon cloth cathode. The Coulombic efficiency ranged from 15% to 55%. These findings show that AC is a cost-effective material for achieving useful rates of oxygen reduction in air cathode MFCs. © 2009 Elsevier B.V. All rights reserved.

  12. Continuing life test of a xenon hollow cathode for a space plasma contactor

    Science.gov (United States)

    Sarver-Verhey, Timothy R.

    1994-01-01

    Implementation of a hollow cathode plasma contactor for charge control on the Space Station has required validation of long-life hollow cathodes. A test series of hollow cathodes and hollow cathode plasma contactors was initiated as part of the plasma contactor development program. An on-going wear-test of a hollow cathode has demonstrated cathode operation in excess of 10,000 hours with small changes in operating parameters. The discharge has experienced 10 shutdowns during the test, all of which were due to test facility failures or expellant replenishment. In all cases, the cathode was re-ignited at approximately 42 volts and resumed typical operation. This test represents the longest demonstrated stable operation of a high current (greater than 1 A) xenon hollow cathode reported to date.

  13. Extended test of a xenon hollow cathode for a space plasma contactor

    Science.gov (United States)

    Sarver-Verhey, Timothy R.

    1994-01-01

    Implementation of a hollow cathode plasma contactor for charge control on the Space Station has required validation of long-life hollow cathodes. A test series of hollow cathodes and hollow cathode plasma contactors was initiated as part of the plasma contactor development program. An on-going wear-test of a hollow cathode has demonstrated cathode operation in excess of 4700 hours with small changes in operating parameters. The discharge experienced 4 shutdowns during the test, all of which were due to test facility failures or expellant replenishment. In all cases, the cathode was reignited at approximately 42 volts and resumed typical operation. This test represents the longest demonstrated stable operation of a high current (greater than 1A) xenon hollow cathode reported to date.

  14. Nano-Particle Scandate Cathode for Space Communications Phase 2 Project

    Data.gov (United States)

    National Aeronautics and Space Administration — We propose an improved cathode based on our novel theory of the role of scandium oxide in enhancing emission in tungsten-impregnated cathodes. Recent results have...

  15. 49 CFR Appendix D to Part 192 - Criteria for Cathodic Protection and Determination of Measurements

    Science.gov (United States)

    2010-10-01

    ... I. Criteria for cathodic protection— A. Steel, cast iron, and ductile iron structures. (1) A... cathodic protection to stop pitting attack on aluminum structures in environments with a natural pH in...

  16. Dispersion-Assembly Approach to Synthesize Three-Dimensional Graphene/Polymer Composite Aerogel as a Powerful Organic Cathode for Rechargeable Li and Na Batteries.

    Science.gov (United States)

    Zhang, Yu; Huang, Yanshan; Yang, Guanhui; Bu, Fanxing; Li, Ke; Shakir, Imran; Xu, Yuxi

    2017-05-10

    Polymer cathode materials are promising alternatives to inorganic counterparts for both lithium-ion batteries (LIBs) and sodium-ion batteries (SIBs) due to their high theoretical capacity, adjustable molecular structure, and strong adaptability to different counterions in batteries, etc. However, they suffer from poor practical capacity and low rate capability because of their intrinsically poor conductivity. Herein, we report the synthesis of self-assembled graphene/poly(anthraquinonyl sufide) (PAQS) composite aerogel (GPA) with efficient integration of a three-dimensional (3D) graphene framework with electroactive PAQS particles via a novel dispersion-assembly strategy which can be used as a free-standing flexible cathode upon mechanical pressing. The entire GPA cathode can deliver the highest capacity of 156 mAh g-1 at 0.1 C (1 C = 225 mAh g-1) with an ultrahigh utilization (94.9%) of PAQS and exhibits an excellent rate performance with 102 mAh g-1 at 20 C in LIBs. Furthermore, the flexible GPA film was also tested as cathode for SIBs and demonstrated a high-rate capability with 72 mAh g-1 at 5 C and an ultralong cycling stability (71.4% capacity retention after 1000 cycles at 0.5 C) which has rarely been achieved before. Such excellent electrochemical performance of GPA as cathode for both LIBs and SIBs could be ascribed to the fast redox kinetics and electron transportation within GPA, resulting from the interconnected conductive framework of graphene and the intimate interaction between graphene and PAQS through an efficient wrapping structure. This approach opens a universal way to develop cathode materials for powerful batteries with different metal-based counter electrodes.

  17. Powder Characterization and Electrochemical Properties of LiNi0.5Mn1.5O4 Cathode Materials Produced by Large Spray Pyrolysis Using Flame Combustion

    Directory of Open Access Journals (Sweden)

    Shinsuke Akao

    2011-01-01

    Full Text Available LiNi0.5Mn1.5O4 cathode materials were produced by spray pyrolysis apparatus using the flame combustion. SEM revealed that as-prepared powders had spherical morphology with porous microstructure which had an average diameter of about 2 μm with broad size distribution. After the calcination, LiNi0.5Mn1.5O4 powders with polygonal morphology and narrow particle size distribution were obtained. XRD showed that LiNi0.5Mn1.5O4 was well crystallized after the calcination at 900°C. Rechargeable measurement of LiNi0.5Mn1.5O4 cathode showed that the long plateau was observed at 4.7 V in discharge curve of LiNi0.5Mn1.5O4 cathode and its discharge capacity was 145 mAh/g at 1 C. The capacity retention of LiNi0.5Mn1.5O4 cathode were 95% at 1 C after 100 cycles. The discharge capacity and capacity retention of LiNi0.5Mn1.5O4 cathode were 125 mAh/g and 88% at 20 C. LiNi0.5Mn1.5O4 cathode exhibited also stable cycle performance at 50∘C.

  18. High performance and durability of order-structured cathode catalyst layer based on TiO2@PANI core-shell nanowire arrays

    Science.gov (United States)

    Chen, Ming; Wang, Meng; Yang, Zhaoyi; Wang, Xindong

    2017-06-01

    In this paper, an order-structured cathode catalyst layer consisting of Pt-TiO2@PANI core-shell nanowire arrays that in situ grown on commercial gas diffusion layer (GDL) are prepared and applied to membrane electrode assembly (MEA) of proton exchange membrane fuel cell (PEMFC). In order to prepare the TiO2@PANI core-shell nanowire arrays with suitable porosity and prominent conductivity, the morphologies of the TiO2 nanoarray and electrochemical polymerization process of aniline are schematically investigated. The MEA with order-structured cathode catalyst layer is assembled in the single cell to evaluate the electrochemical performance and durability of PEMFC. As a result, the PEMFC with order-structured cathode catalyst layer shows higher peak power density (773.54 mW cm-2) than conventional PEMFC (699.30 mW cm-2). Electrochemically active surface area (ECSA) and charge transfer impedance (Rct) are measured before and after accelerated degradation test (ADT), and the corresponding experimental results indicate the novel cathode structure exhibits a better stability with respect to conventional cathode. The enhanced electrochemical performance and durability toward PEMFC can be ascribed to the order-structured cathode nanoarray structure with high specific surface area increases the utilization of catalyst and reduces the tortuosity of transport pathways, and the synergistic effect between TiO2@PANI support and Pt nanoparticles promotes the high efficiency of electrochemical reaction and improves the stability of catalyst. This research provides a facile and controllable method to prepare order-structured membrane electrode with lower Pt loading for PEMFC in the future.

  19. Enhancing the performance of single-chambered microbial fuel cell using manganese/palladium and zirconium/palladium composite cathode catalysts.

    Science.gov (United States)

    Jadhav, Dipak A; Deshpande, Parag A; Ghangrekar, Makarand M

    2017-08-01

    Application of ZrO2, MnO2, palladium, palladium-substituted-zirconium oxide (Zr0.98Pd0.02O2) and palladium-substituted-manganese oxide (Mn0.98Pd0.02O2) cathode catalysts in a single-chambered microbial fuel cell (MFC) was explored. The highest power generation (1.28W/m3) was achieved in MFC with Mn0.98Pd0.02O2 catalyst, which was higher than that with MnO2 (0.58W/m3) alone; whereas, MFC having Zr0.98Pd0.02O2 catalyzed cathode and non-catalyzed cathode produced powers of 1.02 and 0.23W/m3, respectively. Also, low-cost zirconium-palladium-composite showed better catalytic activity and capacitance over ZrO2 with 20A/m3 current production and demonstrated its suitability for MFC applications. Cyclic voltammetry analyses showed higher well-defined redox peaks in composite catalysts (Mn/Zr-Pd-C) over other catalyzed MFCs containing MnO2 or ZrO2. Electrochemical behaviour of composite catalysts on cathode showed higher availability of adsorption sites for oxygen reduction and, hence, enhanced the rate of cathodic reactions. Thus, Mn/Zr-Pd-C-based composite catalysts exhibited superior cathodic performance and could be proposed as alternatives to costly Pd-catalyst for field applications. Copyright © 2017 Elsevier Ltd. All rights reserved.

  20. Sea urchin-like mesoporous carbon material grown with carbon nanotubes as a cathode catalyst support for fuel cells

    Science.gov (United States)

    Kuo, Ping-Lin; Hsu, Chun-Han; Li, Wan-Ting; Jhan, Jing-Yi; Chen, Wei-Fu

    A sea urchin-like carbon (UC) material with high surface area (416 m 2 g -1), adequate electrical conductivity (59.6 S cm -1) and good chemical stability was prepared by growing carbon nanotubes onto mesoporous carbon hollow spheres. A uniform dispersion of Pt nanoparticles was then anchored on the UC, where the Pt nanoparticles were prepared using benzylamine as the stabilizer. For this Pt loaded carbon, cyclic voltammogram measurements showed an exceptionally high electrochemically active surface area (EAS) (114.8 m 2 g -1) compared to the commonly used commercial E-TEK catalyst (65.2 m 2 g -1). The durability test demonstrates that the carbon used as a support exhibited minor loss in EAS of Pt. Compared to the E-TEK (20 wt%) cathode catalyst, this Pt loaded UC catalyst has greatly enhanced catalytic activity toward the oxygen reduction reaction, less cathode flooding and considerably improved performance, resulting in an enhancement of ca. 37% in power density compared with that of E-TEK. Based on the results obtained, the UC is an excellent support for Pt nanoparticles used as cathode catalysts in proton exchange membrane fuel cells.

  1. Sea urchin-like mesoporous carbon material grown with carbon nanotubes as a cathode catalyst support for fuel cells

    Energy Technology Data Exchange (ETDEWEB)

    Kuo, Ping-Lin; Hsu, Chun-Han; Li, Wan-Ting; Jhan, Jing-Yi; Chen, Wei-Fu [Department of Chemical Engineering, National Cheng Kung University, Tainan 70101 (China)

    2010-12-15

    A sea urchin-like carbon (UC) material with high surface area (416 m{sup 2} g{sup -1}), adequate electrical conductivity (59.6 S cm{sup -1}) and good chemical stability was prepared by growing carbon nanotubes onto mesoporous carbon hollow spheres. A uniform dispersion of Pt nanoparticles was then anchored on the UC, where the Pt nanoparticles were prepared using benzylamine as the stabilizer. For this Pt loaded carbon, cyclic voltammogram measurements showed an exceptionally high electrochemically active surface area (EAS) (114.8 m{sup 2} g{sup -1}) compared to the commonly used commercial E-TEK catalyst (65.2 m{sup 2} g{sup -1}). The durability test demonstrates that the carbon used as a support exhibited minor loss in EAS of Pt. Compared to the E-TEK (20 wt%) cathode catalyst, this Pt loaded UC catalyst has greatly enhanced catalytic activity toward the oxygen reduction reaction, less cathode flooding and considerably improved performance, resulting in an enhancement of ca. 37% in power density compared with that of E-TEK. Based on the results obtained, the UC is an excellent support for Pt nanoparticles used as cathode catalysts in proton exchange membrane fuel cells. (author)

  2. Fe-N-C catalyst modified graphene sponge as a cathode material for lithium-oxygen battery

    Energy Technology Data Exchange (ETDEWEB)

    Yu, Ling, E-mail: yulingcug@126.com; Shen, Yue, E-mail: shenyue1213@mail.hust.edu.cn; Huang, Yunhui, E-mail: huangyh@mail.hust.edu.cn

    2014-05-15

    Highlights: • Hydrothermally-synthesized graphene sponge is excellent skeleton of Li-O{sub 2} cathode. • Fe-N-C catalyst loaded on GS was attained via pyrolysis of FePc and GS composites. • High capacity and good cyclability were achieved with Fe-N-GS air electrode. • The synergy of porous structure and catalytic activity leads to the high performance. - Abstract: The cathode of a lithium-oxygen battery needs the synergism of a porous conducting material and a catalyst to facilitate the formation and decomposition of lithium peroxide. Here we introduce a graphene sponge (GS) modified with Fe-N-C catalyst for the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). The porous, 3-dimensional conductive and free standing nature of the graphene sponge makes it become excellent skeleton of cathode for lithium-oxygen battery. The Fe-N-C catalyst nanoparticles dispersed uniformly on the graphene sheets show excellent catalytic reactivity in both discharge and charge processes. This kind of composite material greatly improves the capacity and cyclability of the lithium-oxygen battery. With dimethyl sulphoxide as electrolyte, the capacity reaches 6762 mAh g{sup −1} which is twice of the pure graphene sponge. In addition, the cell containing Fe-N-GS air electrode exhibits stable cyclic performance and effective reduction of charge potential plateau, indicating that Fe-N-GS is promising as an OER catalyst in rechargeable lithium-air batteries.

  3. Building an Electronic Bridge via Ag Decoration To Enhance Kinetics of Iron Fluoride Cathode in Lithium-Ion Batteries.

    Science.gov (United States)

    Li, Yu; Zhou, Xingzhen; Bai, Ying; Chen, Guanghai; Wang, Zhaohua; Li, Hui; Wu, Feng; Wu, Chuan

    2017-06-14

    As a typical multielectron cathode material for lithium-ion batteries, iron fluoride (FeF3) and its analogues suffer from poor electronic conductivity and low actual specific capacity. Herein, we introduce Ag nanoparticles by silver mirror reaction into the FeF3·0.33H2O cathode to build the electronic bridge between the solid (active materials) and liquid (electrolyte) interface. The crystal structures of as-prepared samples are characterized by X-ray diffraction and Rietveld refinement. Moreover, the density of states of FeF3·0.33H2O and FeF3·0.33H2O/Ag (Ag-decorated FeF3·0.33H2O) samples are calculated using the first principle density functional theory. The FeF3·0.33H2O/Ag cathodes exhibit significant enhancements on the electrochemical performance in terms of the cycle performance and rate capability, especially for the Ag-decorated amount of 5%. It achieves an initial capacity of 168.2 mA h g(-1) and retains a discharge capacity of 128.4 mA h g(-1) after 50 cycles in the voltage range of 2.0-4.5 V. It demonstrates that Ag decoration can reduce the band gap, improve electronic conductivity, and elevate intercalation/deintercalation kinetics.

  4. H2V3O8 Nanowires as High-Capacity Cathode Materials for Magnesium-Based Battery.

    Science.gov (United States)

    Tang, Han; Xu, Nuo; Pei, Cunyuan; Xiong, Fangyu; Tan, Shuangshuang; Luo, Wen; An, Qinyou; Mai, Liqiang

    2017-08-30

    Magnesium-based batteries have received much attention as promising candidates to next-generation batteries because of high volumetric capacity, low price, and dendrite-free property of Mg metal. Herein, we reported H2V3O8 nanowire cathode with excellent electrochemical property in magnesium-based batteries. First, it shows a satisfactory magnesium storage ability with 304.2 mA h g(-1) capacity at 50 mA g(-1). Second, it possesses a high-voltage platform of ∼2.0 V vs Mg/Mg(2+). Furthermore, when evaluated as a cathode material for magnesium-based hybrid Mg(2+)/Li(+) battery, it exhibits a high specific capacity of 305.4 mA h g(-1) at 25 mA g(-1) and can be performed in a wide working temperature range (-20 to 55 °C). Notably, the insertion-type ion storage mechanism of H2V3O8 nanowires in hybrid Mg(2+)/Li(+) batteries are investigated by ex situ X-ray diffraction and Fourier transform infrared. This research demonstrates that the H2V3O8 nanowire cathode is a potential candidate for high-performance magnesium-based batteries.

  5. On the biophysics of cathodal galvanotaxis in rat prostate cancer cells: Poisson-Nernst-Planck equation approach.

    Science.gov (United States)

    Borys, Przemysław

    2012-06-01

    Rat prostate cancer cells have been previously investigated using two cell lines: a highly metastatic one (Mat-Ly-Lu) and a nonmetastatic one (AT-2). It turns out that the highly metastatic Mat-Ly-Lu cells exhibit a phenomenon of cathodal galvanotaxis in an electric field which can be blocked by interrupting the voltage-gated sodium channel (VGSC) activity. The VGSC activity is postulated to be characteristic for metastatic cells and seems to be a reasonable driving force for motile behavior. However, the classical theory of cellular motion depends on calcium ions rather than sodium ions. The current research provides a theoretical connection between cellular sodium inflow and cathodal galvanotaxis of Mat-Ly-Lu cells. Electrical repulsion of intracellular calcium ions by entering sodium ions is proposed after depolarization starting from the cathodal side. The disturbance in the calcium distribution may then drive actin polymerization and myosin contraction. The presented modeling is done within a continuous one-dimensional Poisson-Nernst-Planck equation framework.

  6. Understanding the capacity fade mechanisms of spinel manganese oxide cathodes and improving their performance in lithium ion batteries

    Science.gov (United States)

    Choi, Won Chang

    Lithium ion batteries have been successful in portable electronics market due to their high energy density, adopting the layered LiCoO2 as the cathode material in commercial lithium ion cells. However, increasing interest in lithium ion batteries for electric vehicle and hybrid electric vehicle applications requires alternative cathode materials due to the high cost, toxicity, and limited power capability of the layered LiCoO2 cathode. In this regard, spinel LiMn2O4 has become appealing as manganese is inexpensive and environmentally benign, but LiMn2O 4 is plagued by severe capacity fade at elevated temperatures. This dissertation explores the factors that control and limit the electrochemical performance of spinel LiMn2O4 cathodes and focuses on improving the performance parameters such as the capacity, cyclability, and rate capability of various spinel cathodes derived from LiMn2O 4. From a systematic investigation of a number of cationic and anionic (fluorine) substituted spinel oxide compositions, the improvements in electrochemical properties and performances are found to be due to the reduced manganese dissolution and suppressed lattice parameter difference between the two cubic phases formed during the charge-discharge process. Investigations focused on fluorine substitution reveal that spinel LiMn 2-y-zLiyZnzO4-etaFeta oxyfluoride cathodes synthesized by solid-state reactions at 800°C employing ZnF2 as a raw material and spinel LiMn2-y-zLiy NizO4-etaFeta oxyfluoride cathodes synthesized by firing the cation-substituted LiMn2-y-zLiy NizO4 oxides with NH4HF2 at a moderate temperature of 450°C show superior cyclability, increased capacity, reduced Mn dissolution, and excellent storage performance compared to the corresponding oxide analogs and the conventional LiMn2O 4. Spinel-layered composite cathodes are found to exhibit better electrochemical performance with graphite anode when charged to 4.7 V in the first cycle followed by cycling at 4.3--3.5 V

  7. Which exhibition attributes create repeat visitation?

    OpenAIRE

    Whitfield, J.; Webber, D. J.

    2011-01-01

    This study identifies exhibition attributes deemed important by attendees’ in determining their attendance at the UK biennial MICROSCIENCE 2008 exhibition using a self-administered internet-based questionnaire. Perceived performance of attributes by attendees is also established. Attendees consider meeting specialists as well as gaining product and technical information to be very important attributes for exhibition selection. Application of an Importance Performance Analysis suggests that re...

  8. Research and Development of a New Field Enhanced Low Temperature Thermionic Cathode that Enables Fluorescent Dimming and Loan Shedding without Auxiliary Cathode Heating

    Energy Technology Data Exchange (ETDEWEB)

    Feng Jin

    2009-01-07

    This is the final report for project entitled 'Research and development of a new field enhanced low temperature thermionic cathode that enables fluorescent dimming and load shedding without auxiliary cathode heating', under Agreement Number: DE-FC26-04NT-42329. Under this project, a highly efficient CNT based thermionic cathode was demonstrated. This cathode is capable of emitting electron at a current density two order of magnitude stronger then a typical fluorescent cathode at same temperatures, or capable of emitting at same current density but at temperature about 300 C lower than that of a fluorescent cathode. Detailed fabrication techniques were developed including CVD growth of CNTs and sputter deposition of oxide thin films on CNTs. These are mature technologies that have been widely used in industry for large scale materials processing and device fabrications, thus, with further development work, the techniques developed in this project can be scaled-up in manufacturing environment. The prototype cathodes developed in this project were tested in lighting plasma discharge environment. In many cases, they not only lit and sustain the plasma, but also out perform the fluorescent cathodes in key parameters such like cathode fall voltages. More work will be needed to further evaluate more detailed and longer term performance of the prototype cathode in lighting plasma.

  9. Testing a GaAs cathode in SRF gun

    Energy Technology Data Exchange (ETDEWEB)

    Wang, E.; Kewisch, J.; Ben-Zvi, I.; Burrill, A.; Rao, T.; Wu, Q.; Holmes, D.

    2011-03-28

    RF electron guns with a strained superlattice GaAs cathode are expected to generate polarized electron beams of higher brightness and lower emittance than do DC guns, due to their higher field gradient at the cathode's surface and lower cathode temperature. We plan to install a bulk GaAs:Cs in a SRF gun to evaluate the performance of both the gun and the cathode in this environment. The status of this project is: In our 1.3 GHz 1/2 cell SRF gun, the vacuum can be maintained at nearly 10{sup -12} Torr because of cryo-pumping at 2K. With conventional activation of bulk GaAs, we obtained a QE of 10% at 532 nm, with lifetime of more than 3 days in the preparation chamber and have shown that it can survive in transport from the preparation chamber to the gun. The beam line has been assembled and we are exploring the best conditions for baking the cathode under vacuum. We report here the progress of our test of the GaAs cathode in the SRF gun. Future particle accelerators, such as eRHIC and the ILC require high-brightness, high-current polarized electrons. Strained superlattice GaAs:Cs has been shown to be an efficient cathode for producing polarized electrons. Activation of GaAs with Cs,O(F) lowers the electron affinity and makes it energetically possible for all the electrons, excited into the conduction band that drift or diffuse to the emission surface, to escape into the vacuum. Presently, all operating polarized electron sources, such as the CEBAF, are DC guns. In these devices, the excellent ultra-high vacuum extends the lifetime of the cathode. However, the low field gradient on the photocathode's emission surface of the DC guns limits the beam quality. The higher accelerating gradients, possible in the RF guns, generate a far better beam. Until recently, most RF guns operated at room temperature, limiting the vacuum to {approx}10{sup -9} Torr. This destroys the GaAs's NEA surface. The SRF guns combine the excellent vacuum conditions of DC guns and

  10. Theory, Investigation and Stability of Cathode Electrocatalytic Activity

    Energy Technology Data Exchange (ETDEWEB)

    Ding, Dong; Liu, Mingfei; Lai, Samson; Blinn, Kevin; Liu, Meilin

    2012-09-30

    The main objective of this project is to systematically characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF, aiming to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating. The understanding gained will help us to optimize the composition and morphology of the catalyst layer and microstructure of the LSCF backbone for better performance. More specifically, the technical objectives include: (1) to characterize the surface composition, morphology, and electro-catalytic properties of catalysts coated on LSCF; (2) to characterize the microscopic details and stability of the LSCF-catalyst (e.g., LSM) interfaces; (3) to establish the scientific basis for rational design of high-performance cathodes by combining a porous backbone (such as LSCF) with a thin catalyst coating; and (4) to demonstrate that the performance and stability of porous LSCF cathodes can be enhanced by the application of a thin-film coating of LSM through a solution infiltration process in small homemade button cells and in commercially available cells of larger dimension. We have successfully developed dense, conformal LSM films with desired structure, composition, morphology, and thickness on the LSCF surfaces by two different infiltration processes: a non-aqueous and a water-based sol-gel process. It is demonstrated that the activity and stability of LSCF cathodes can be improved by the introduction of a thin-film LSM coating through an infiltration process. Surface and interface of the LSM-coated LSCF cathode were systematically characterized using advanced microscopy and spectroscopy techniques. TEM observation suggests that a layer of La and Sr oxide was formed on LSCF surfaces after annealing. With LSM infiltration, in contrast, we no longer observe such La/Sr oxide layer on the LSM-coated LSCF samples after annealing under similar

  11. Nano-structured textiles as high-performance aqueous cathodes for microbial fuel cells

    KAUST Repository

    Xie, Xing

    2011-01-01

    A carbon nanotube (CNT)-textile-Pt cathode for aqueous-cathode microbial fuel cells (MFCs) was prepared by electrochemically depositing Pt nanoparticles on a CNT-textile. An MFC equipped with a CNT-textile-Pt cathode revealed a 2.14-fold maximum power density with only 19.3% Pt loading, compared to that with a commercial Pt coated carbon cloth cathode. © 2011 The Royal Society of Chemistry.

  12. Potential threat of heavy metals in re-suspended dusts on building surfaces in oilfield city

    Science.gov (United States)

    Kong, Shaofei; Lu, Bing; Bai, Zhipeng; Zhao, Xueyan; Chen, Li; Han, Bin; Li, Zhiyong; Ji, Yaqin; Xu, Yonghai; Liu, Yong; Jiang, Hua

    2011-08-01

    30 re-suspended dust samples were collected from building surfaces of an oilfield city, then re-suspended through PM 2.5, PM 10 and PM 100 inlets and analyzed for 10 metals including V, Cr, Mn, Co, Ni, Cu, Zn, As, Cd and Pb by inductively coupled plasma-mass spectroscopy. Metals concentrations in different fractions and locations were studied. Metals sources were identified by cluster and primary component analysis. The potential risk to human health was assessed by human exposure model. Results showed that Zn, Mn, Pb and Cu were higher in all the three fractions. V, Cr, Mn and Co ranged close to the background values of Chinese soil indicating that they were mainly from crustal materials. Concentrations of Zn, Mn, Pb, V, Cr, Ni, Co and Cd were higher in old district than that in new district for the three fractions. The PM 2.5/PM 10, PM 10/PM 100 and PM 2.5/PM 100 ratios were higher for Zn, Cd, Cu, Pb, Ni, As and Cr (all higher than 1.0), and lower for Co, Mn and V (all less than or close to 1.0) which meant that anthropologic sources associated metals were more easily accumulated in finer particles than metals from crustal materials. Spatial variations indicated that the ten metals peaked at surroundings near railway station, gas stations, industrial boilers and machine manufacturing plant implying the influence of local vehicle emission, fossil fuel combustion and industrial activities as well as crustal materials which was verified by cluster analysis and primary component analysis results. Ingestion of dust particles appeared to be the main route of exposure to re-suspended dust. Hazard Indexes of As were both highest for children and adult which could be a potential threat to human health for non-cancer effect and it also exhibited the highest values for cancer effect as 1.01E-06, 7.04E-07 and 7.21E-07 for PM 2.5, PM 10 and PM 100, respectively.

  13. Characterization and optimization of cathodic conditions for H2O2 synthesis in microbial electrochemical cells

    Science.gov (United States)

    Cathode potential and O2 supply methods were investigated to improve H2O2 synthesis in an electrochemical cell, and optimal cathode conditions were applied for microbial electrochemical cells (MECs). Using aqueous O2 for the cathode significantly improved current density, but H2...

  14. Performance testing of a carbon fiber array cathode in a hard-tube MILO

    Science.gov (United States)

    Li, An-Kun; Fan, Yu-Wei; Qian, Bao-Liang

    2017-10-01

    In this paper, a carbon fiber array cathode was constructed and the application in a hard-tube magnetically insulated transmission line oscillator (MILO) was investigated. The performance was compared with a traditionally used polymer velvet cathode in the same conditions, where applied electric power ranged from 9 GW to 28 GW and microwave with power level of several GW was the output. The MILO worked on single shot mode or repetitive mode at 5 Hz. For both cathodes, the central frequencies of output microwaves are in the L-band, and the pulse durations (full width at half maximum) range from 25 to 50 ns. Experimental results show that the pulse duration of output microwave of the carbon fiber array cathode is shorter than the velvet cathode, and the power conversion efficiency is also somewhat lower than the velvet cathode. Although the performance testing results show that this carbon fiber array cathode is somewhat not as good as the traditional velvet cathode in the present state, the reasons for the disadvantages of the carbon fiber array cathode have been analyzed and the corresponding solutions are presented to improve the performance of this cathode. If expected solutions are put into effect, this carbon fiber array cathode may be able to replace the velvet cathode.

  15. 21 CFR 870.2450 - Medical cathode-ray tube display.

    Science.gov (United States)

    2010-04-01

    ... 21 Food and Drugs 8 2010-04-01 2010-04-01 false Medical cathode-ray tube display. 870.2450 Section... cathode-ray tube display. (a) Identification. A medical cathode-ray tube display is a device designed primarily to display selected biological signals. This device often incorporates special display features...

  16. Highly dispersed sulfur in a porous aromatic framework as a cathode for lithium–sulfur batteries

    Energy Technology Data Exchange (ETDEWEB)

    Guo, Bingkun [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Ben, Teng [Jilin Univ., Changchun (China). Dept. of Chemistry; Bi, Zhonghe [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Veith, Gabriel M. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Sun, Xiao-Guang [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Qiu, Shilun [Jilin Univ., Changchun (China). Dept. of Chemistry; Dai, Sheng [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry

    2013-04-08

    Lithium–sulfur (Li–S) batteries are attractive candidates for transportation applications because of their high energy density (2600 W h kg$-$1). However, Li–S batteries have failed to achieve commercial success, due to the rapid capacity fading with cycling caused mainly by the “shuttle” phenomenon. In this paper, we report a feasible approach to mitigate this issue using a porous aromatic framework (PAF) as a hosting substrate in Li–S batteries. As a cathode material, the composite of PAF with sulfur exhibits high capacity and excellent cycling stability in both a sulfone electrolyte, 1.0 M LiPF6–MiPS, and an ionic liquid electrolyte, 0.5 M LiTFSI–MPPY·TFSI.

  17. Structure and optical properties of CdS:O films by cathode sputtering

    Energy Technology Data Exchange (ETDEWEB)

    Nakajima, Masahiro; Asaba, Ryo; Suzuki, Akinori; Wakita, Kazuki [Department of Electrical, Electronics and Computer Engineering, Chiba Institute of Technology, 2-17-1, Tsudanuma, Narashino, Chiba 275-0016 (Japan); Shim, Yong-Gu [Department of Physics and Electronics, Osaka Prefecture University, 1-1 Gakuen-cho, Nakaku, Sakai, Osaka 599-8531 (Japan); Khalilova, Kh.; Mamedov, Nazim; Bayramov, Ayaz; Huseynov, Emil [Institute of Physics, Azerbaijan National Academy of Science, H. Javid ave. 33, Baku 1143 (Azerbaijan)

    2015-06-15

    We have studied the structure and optical properties of CdS:O films deposited on SLG (soda lime glass) substrates by cathode sputtering in the atmosphere of oxygen/argon gases. According to X-ray diffraction (XRD) and confocal Raman scattering data, the films annealed in vacuum at temperatures above 300 C exhibited crystalline structure of CdS. On the other hand, XRD, confocal Raman scattering, AFM (atomic force microscopy) and TEM (transmission electron microscopy) data indicated amorphous structure nano-crystallization in CdS:O films annealed in vacuum at 400 C. For the films, the emissions located at 3.35 eV were evident from photoluminescence measurements. The origin of this energy gap is discussed by taking into account redistribution of electronic density of states in the amorphous phase and quantum-size effect. (copyright 2015 WILEY-VCH Verlag GmbH and Co. KGaA, Weinheim)

  18. Bismuth oxyfluoride @ CMK-3 nanocomposite as cathode for lithium ion batteries

    Science.gov (United States)

    Ni, Dan; Sun, Wang; Xie, Liqiang; Fan, Qinghua; Wang, Zhenhua; Sun, Kening

    2018-01-01

    Bismuth oxyfluoride impregnated CMK-3 nanocomposite is synthesized by a facile nanocasting approach. Mesoporous carbon CMK-3 can suppress the aggregation and growth of bismuth oxyfluoride particles and offer rapid electron and Li ion passageways. Bismuth oxyfluoride nanoparticles are embedded in the mesoporous channels with particle size less than 20 nm. The bismuth oxyfluoride@CMK-3 nanocomposite maintains 148 mA h g-1 after 40 cycles with the capacity from both the bismuth oxyfluoride and the functional groups on the mesoporous carbon. The hybrid with confined bismuth oxyfluoride nanoparticles, conductive carbon network, and oxygen functional groups on the carbon matrix exhibits higher capacity and cycling stability than bulk bismuth oxyfluoride particles when used as lithium ion batteries cathode.

  19. Intergrating cavity absorption meter measurements of dissolved substances and suspended particles in ocean water

    Science.gov (United States)

    Pope, Robin M.; Weidemann, Alan D.; Fry, Edward S.

    2000-01-01

    We have developed a new device to measure the separate contributions to the spectral absorption coefficient due to a pure liquid, due to the particles suspended in it, and due to the substances dissolved in it. This device, the Integrating Cavity Absorption Meter (ICAM), is essentially independent of scattering effects in the sample. In April 1993, a prototype of the ICAM was field tested on board the research vessel USNS Bartlett. A major part of the cruise track included criss-crossing the area where the Mississippi flows into the Gulf of Mexico at various ranges from the mouth of the river; thus samples were collected from areas of blue, green, and brown/black water. We evaluated 35 seawater samples collected with 5-l Niskin bottles from 22 locations to determine absorption spectra (380-700 nm) of suspended particles and dissolved substances (gelbstoff). Results validate the ICAM as a viable tool for marine optical absorption research. Gelbstoff absorption at 432.5 nm ranged from 0.024 to 0.603 m -1. Over the spectral region 380→560 nm, gelbstoff absorption by each of the samples could be accurately fit to a decaying exponential. The particle absorption spectra are generally characteristic of those of phytoplankton and exhibit a local maximum at 430-440 nm. Absorption values at 432.5 nm ranged from ˜zero to ˜1.0 m -1. Some samples with moderate particulate absorption, however, did not show the characteristic local maximum of phytoplankton in the blue and instead resembled the characteristic decaying exponential of detritus with a shape similar to that observed in the gelbstoff. The ratio of gelbstoff to particulate absorption at 432.5 nm ranged from 0.46 to 152.

  20. Progress towards Acoustic Suspended Sediment Transport Monitoring: Fraser River, BC

    Science.gov (United States)

    Attard, M. E.; Venditti, J. G.; Church, M. A.; Kostaschuk, R. A.

    2011-12-01

    Our ability to predict the timing and quantity of suspended sediment transport is limited because fine sand, silt and clay delivery are supply limited, requiring empirical modeling approaches of limited temporal stability. A solution is the development of continuous monitoring techniques capable of tracking sediment concentrations and grain-size. Here we examine sediment delivery from upstream sources to the lower Fraser River. The sediment budget of the lower Fraser River provides a long-term perspective of the net changes in the channels and in sediment delivery to Fraser Delta. The budget is based on historical sediment rating curves developed from data collected from 1965-1986 by the Water Survey of Canada. We explore the possibility of re-establishing the sediment-monitoring program using hydro-acoustics by evaluating the use of a 300 kHz side-looking acoustic Doppler current profiler (aDcp), mounted just downstream of the sand-gravel transition at Mission, for continuous measurement of suspended sediment transport. Complementary field observations include conventional bottle sampling with a P-63 sampler, vertical profiles with a downward-looking 600 kHz aDcp, and 1200 kHz aDcp discharge measurements. We have successfully completed calibration of the downward-looking aDcp with the P-63 samples; the side-looking aDcp signals remain under investigation. A comparison of several methods for obtaining total sediment flux indicates that suspended sediment concentration (SSC) closely follows discharge through the freshet and peaks in total SSC and sand SSC coincide with peak measurements of discharge. Low flows are dominated by fine sediment and grain size increases with higher flows. This research assesses several techniques for obtaining sediment flux and contributes to the understanding of sediment delivery to sand-bedded portions of the river.

  1. Surface-enhanced Raman scattering of suspended monolayer graphene

    Science.gov (United States)

    Huang, Cheng-Wen; Lin, Bing-Jie; Lin, Hsing-Ying; Huang, Chen-Han; Shih, Fu-Yu; Wang, Wei-Hua; Liu, Chih-Yi; Chui, Hsiang-Chen

    2013-11-01

    The interactions between phonons and electrons induced by the dopants or the substrate of graphene in spectroscopic investigation reveal a rich source of interesting physics. Raman spectra and surface-enhanced Raman spectra of supported and suspended monolayer graphenes were measured and analyzed systemically with different approaches. The weak Raman signals are greatly enhanced by the ability of surface-enhanced Raman spectroscopy which has attracted considerable interests. The technique is regarded as wonderful and useful tool, but the dopants that are produced by depositing metallic nanoparticles may affect the electron scattering processes of graphene. Therefore, the doping and substrate influences on graphene are also important issues to be investigated. In this work, the peak positions of G peak and 2D peak, the I 2D/ I G ratios, and enhancements of G and 2D bands with suspended and supported graphene flakes were measured and analyzed. The peak shifts of G and 2D bands between the Raman and SERS signals demonstrate the doping effect induced by silver nanoparticles by n-doping. The I 2D/ I G ratio can provide a more sensitive method to carry out the doping effect on the graphene surface than the peak shifts of G and 2D bands. The enhancements of 2D band of suspended and supported graphenes reached 138, and those of G band reached at least 169. Their good enhancements are helpful to measure the optical properties of graphene. The different substrates that covered the graphene surface with doping effect are more sensitive to the enhancements of G band with respect to 2D band. It provides us a new method to distinguish the substrate and doping effect on graphene.

  2. Coupling between electronic transport and longitudinal phonons in suspended nanotubes

    Energy Technology Data Exchange (ETDEWEB)

    Sapmaz, S; Jarillo-Herrero, P; Blanter, Ya M; Zant, H S J van der [Kavli Institute of Nanoscience, Delft University of Technology, PO Box 5046, 2600 GA Delft (Netherlands)

    2005-11-15

    Current-voltage characteristics of suspended single-wall carbon nanotube (NT) quantum dots show a series of steps equally spaced in voltage. The energy scale of this harmonic, low-energy excitation spectrum is consistent with that of the longitudinal low-k phonon mode in the NT. Agreement is found with a Franck-Condon-based model in which the phonon-assisted tunnelling process is modelled as a coupling of electronic levels to underdamped quantum harmonic oscillators. Comparison with this model indicates a rather strong electron-phonon coupling factor of order unity. We investigate different electron-phonon coupling mechanisms and give estimates of the coupling factor.

  3. Regional volume changes in canine lungs suspended in air

    Science.gov (United States)

    Abbrecht, Peter H.; Kyle, Richard R.; Bryant, Howard J.; Feuerstein, Irwin

    1995-01-01

    The purpose of this study was to determine the effect of the absence of a pleural pressure gradient (simulating the presumed condition found in microgravity) upon regional expansion of the lung. We attempted to produce a uniform pressure over the surface of the lung by suspending excised lungs in air. Such studies should help determine whether or not the absence of a pleural pressure gradient leads to uniform ventilation. A preparation in which there is no pleural pressure gradient should also be useful in studying non-gravitational effects on ventilation distribution.

  4. The Ages in a Self-Suspended Nanoparticle Liquid

    KAUST Repository

    Agarwal, Praveen

    2010-01-13

    Telomers ionically tethered to nanometer-sized particles yield self-suspended, nanoparticle-Iaden liquids with unusual dynamical features. By subjecting these suspensions to controlled, modest shear strains, we find that their flow behaviors observed using experiments performed on time scales of tens of seconds can be projected to obtain maps of their dynamical response on geological time scales. That such extraordinarily slow dynamic processes can be uncovered from real-time measurements by simply stretching a system provides a simple but powerful tool for interrogating extremely slow motions in other jammed physical states. © 2010 American Chemical Society.

  5. Suspended liminality: Vacillating affects in cyberbullying/research

    OpenAIRE

    Kofoed, J.; Stenner, Paul

    2017-01-01

    This paper develops a concept of liminal hotspots in the context of i) a secondary analysis of a cyberbullying case involving a group of school children from a Danish school, and ii) an altered auto-ethnography in which the authors ‘entangle’ their own experiences with the case analysis. These two sources are used to build an account of a liminal hotspot conceived as an occasion of troubled and suspended transformative transition in which a liminal phase is extended and remains unresolved. Th...

  6. Oscillation of a diamagnetic liquid bubble suspended by magnetic force

    Energy Technology Data Exchange (ETDEWEB)

    Yamane, R. E-mail: yamane@kokushikan.ac.jp; Tomita, S.; Mai, J.; Park, M.K.; Oshima, S

    2002-11-01

    The levitation of the diamagnetic liquid droplet with the strong magnetic field is experimentally simulated, using the magnetic fluid as the surrounding fluid in place of air or gas, and the water bubble is levitated with the conventional permanent magnet. When the stepwise magnetic field is superposed, the suspended bubble behaves as a typical step response with the overshoot and viscous damping. The effects of the volume of the bubble, the strength of the magnetic field and the concentration of the magnetic fluid are investigated.

  7. Dramatic switching behavior in suspended MoS2 field-effect transistors

    Science.gov (United States)

    Chen, Huawei; Li, Jingyu; Chen, Xiaozhang; Zhang, David; Zhou, Peng

    2018-02-01

    When integrating MoS2 flakes into scaling-down transistors, the short-channel effect, which is severe in silicon technology below 5-nanometer, can be avoided effectively. MoS2 transistors not only exhibit a high on/off ratio but also demonstrate a rapid switching speed. According to the theoretical calculation, the thermionic limit subthreshold slope (SS) of the ideal device could reach 60 mV/dec. However, due to the confinement of defects from substrates or contamination during the process, the SS deteriorates to more than 300 mV/dec, causing serious power consumption. In this work, we optimize the SS through structure design of MoS2 transistors. The suspended transistors exhibit a high on/off ratio of 107 and a minimum SS of 63 mV/dec with an ultralow standby power at room temperature. This study demonstrates the promising potential of structure design for electronic devices with ultralow-power switching behaviors.

  8. 18 CFR 156.5 - Exhibits.

    Science.gov (United States)

    2010-04-01

    ... local authorizations. (i) A copy of any certificate of public convenience and necessity or similar..., showing towns and communities to be served, and (b) gas producing and storage filed, or other sources of.... (8) Exhibit G-II—Flow diagram data. Exhibits G and G-I shall be accompanied by a statement of...

  9. 18 CFR 50.7 - Applications: exhibits.

    Science.gov (United States)

    2010-04-01

    ... ELECTRIC TRANSMISSION FACILITIES § 50.7 Applications: exhibits. Each exhibit must contain a title page..., and substations description including: (i) Conductor size and type; (ii) Type of structures; (iii... existing if applicable) substations or switching stations that will be associated with the proposed new...

  10. Encountering Nanotechnology in an Interactive Exhibition

    Science.gov (United States)

    Murriello, Sandra E.; Knobel, Marcelo

    2008-01-01

    This article offers findings from a learning sciences-informed evaluation of a nanoscience and nanotechnology exhibition called Nano-Aventura (NanoAdventure), based on four interactive-collaborative games and two narrated videos. This traveling exhibition was developed in Brazil by the Museu Exploratorio de Ciencias for children and teenagers…

  11. Let's play game exhibitions : A curator's perspective

    NARCIS (Netherlands)

    de Vos, Jesse; Glas, M.A.J.|info:eu-repo/dai/nl/330981447; van Vught, J.F.|info:eu-repo/dai/nl/413532682

    2017-01-01

    The Netherlands Institute for Sound and Vision is home to The Experience, a museum exhibiting the history of media in the Netherlands. For ten months in 2016 and 2017, The Experience hosted a temporary exhibition entitled Let’s YouTube . During the Let’s YouTube game month, we programmed a ten-day

  12. Science Fiction Exhibits as STEM Gateways

    Science.gov (United States)

    Robie, Samantha

    Women continue to hold less than a quarter of all STEM jobs in the United States, prompting many museums to develop programs and exhibits with the express goal of interesting young girls in scientific fields. At the same time, a number of recent museum exhibits have harnessed the popularity of pop culture and science fiction in order to interest general audiences in STEM subject matter, as well as using the exhibits as springboards to expand or shift mission goals and focus. Because science fiction appears to be successful at raising interest in STEM fields, it may be an effective way to garner the interest of young girls in STEM in particular. This research seeks to describe the ways in which museums are currently using science fiction exhibits to interest young girls in STEM fields and careers. Research focused on four institutions across the country hosting three separate exhibits, and included staff interviews and content analysis of exhibit descriptions, promotional materials, a summative evaluation and supplementary exhibit productions. In some ways, science fiction exhibits do serve young girls, primarily through the inclusion of female role models, staff awareness, and prototype testing to ensure interactives are attractive to girls as well as to boys. However, STEM appears to be underutilized, which may be partly due to a concern within the field that the outcome of targeting a specific gender could be construed as "stereotyping".

  13. A Heuristic for Improving Transmedia Exhibition Experience

    DEFF Research Database (Denmark)

    Selvadurai, Vashanth; Rosenstand, Claus Andreas Foss

    2017-01-01

    The area of interest is transmedia experiences in exhibitions. The research question is: How to involve visitors in a transmedia experience for an existing exhibition, which bridges the pre-, during- and post-experience? Research through design, and action research are the methods used to design ...

  14. Artefacts and the performance of an exhibition

    DEFF Research Database (Denmark)

    Svabo, Connie

    2008-01-01

    The article explores the role of mediating artefacts in children's encounters with a museum of natural history. Using actor network theory it explores how a specific artefact shapes the way users relate to exhibited objects and how the artefact guides users' movements in the exhibition. The media...

  15. Memory and Mourning: An Exhibit History

    Science.gov (United States)

    Eberle, Scott G.

    2005-01-01

    Mounted by the Strong Museum in Rochester, New York, in 1993, and traveling nationally thereafter, the exhibit Memory and Mourning provided historical and contemporary perspectives to help museum guests explore their own reactions to loss and grief. In the process the exhibit's development team encountered a range of philosophical, historical,…

  16. Paolo Gioli: An Exercise in Exhibition Making

    Directory of Open Access Journals (Sweden)

    Enrico Camporesi

    2015-07-01

    Full Text Available The text is thought as a brief museological and museographical journey of Paolo Gioli’s exhibition “Volti” [“Faces”], that allows the reader to go through the exhibition-making process, discussing, among others, the difficulties that I have encountered.

  17. Effect of process parameters on coating composition of cathodic ...

    Indian Academy of Sciences (India)

    The effect of some process parameters such as electrical conductivity, volume and temperature of electrolyte and ratio of anode to cathode surface area on current–voltage behaviour and subsequently coating compositions are investigated at 150V deposition voltage. The composition and morphology of these coatings are ...

  18. Degradation Studies on LiFePO4 cathode

    DEFF Research Database (Denmark)

    Scipioni, Roberto; Jørgensen, Peter Stanley; Hjelm, Johan

    2015-01-01

    In this paper we examine a laboratory LiFePO4 (LFP) cathode and propose a simple model that predicts the electrode capacity as function of C-rate, number of cycles and calendar time. Microcracks were found in Li1-xFePO4 particles in a degraded LFP electrode and low-acceleration voltage (1 kV) FIB...

  19. FEM-models of cathodic protection systems for concrete structures

    NARCIS (Netherlands)

    Bertolini, L.; Lollini, F.; Redaelli, E.; Polder, R.B.; Peelen, W.H.A.

    2008-01-01

    A significant number of reinforced concrete structures shows deterioration due to the reinforcement corrosion and requires interventions to guarantee their residual service life. A wide range of maintenance options is available, among which cathodic protection (CP) has been found to be a successful

  20. Influence of substrate topography on cathodic delamination of anticorrosive coatings

    DEFF Research Database (Denmark)

    Sørensen, Per Aggerholm; Kiil, Søren; Dam-Johansen, Kim

    2009-01-01

    The cathodic delamination of a commercial magnesium silicate and titanium dioxide pigmented epoxy coating on abrasive cleaned cold rolled steel has been investigated. The rate of delamination was found to depend on interfacial transport from the artificial defect to the delamination front...

  1. Cathodic protection of RC structures - Far more than bridge decks

    NARCIS (Netherlands)

    Nerland, O.C.; Polder, R.B.

    2002-01-01

    When the first trials with Cathodic Protection (CP) on reinforced concrete (RC) structures were carried out nearly 30 years ago the main aim was treating steel in bridge decks, suffering from chloride induced corrosion. Various types of anode systems (conductive asphalt, conductive mortars, carbon

  2. Enhancement of Platinum Cathode Catalysis by Addition of Transition Metals

    Science.gov (United States)

    Duong, Hung Tuan

    2009-01-01

    The sluggish kinetics of oxygen reduction reaction (ORR) contributes significantly to the loss of cathode overpotential in fuel cells, thus requiring high loadings of platinum (Pt), which is an expensive metal with limited supply. However, Pt and Pt-based alloys are still the best available electrocatalysts for ORR thus far. The research presented…

  3. Interactions of alkali metals and electrolyte with cathode carbons

    Energy Technology Data Exchange (ETDEWEB)

    Naas, Tyke

    1997-12-31

    The Hall-Heroult process for electrolytic reduction of alumina has been the only commercial process for production of primary aluminium. The process runs at high temperature and it is important to minimize the energy consumption. To save energy it is desirable to reduce the operating temperature. This can be achieved by adding suitable additives such as LiF or KF to the cryolitic electrolyte. This may conflict with the objective of extending the lifetime of the cathode linings of the cell as much as possible. The thesis investigates this possibility and the nature of the interactions involved. It supports the hypothesis that LiF-additions to the Hall-Heroult cell electrolyte is beneficial to the carbon cathode performance because the diminished sodium activity reduces the sodium induced stresses during the initial period of electrolysis. The use of KF as an additive is more dangerous, but the results indicate that additions up to 5% KF may be tolerated in acidic melts with semigraphitic or graphitic cathodes with little risk of cathode problems. 153 refs., 94 figs., 30 tabs.

  4. Cathodic Arcs From Fractal Spots to Energetic Condensation

    CERN Document Server

    Anders, Andre

    2009-01-01

    Emphasizes the fractal character of cathode spots, and describes strongly fluctuating plasma properties such as the presence of multiply charged ions that move with supersonic velocity. This book also deals with issues, such as arc source construction, and macroparticle removal. It is intended for scientists, practitioners, and students alike

  5. Advanced numerical design for economical cathodic protection for concrete structures

    NARCIS (Netherlands)

    Polder, R.B.; Peelen, W.H.A.

    2008-01-01

    Concrete structures under aggressive load may suffer chloride induced reinforcement corrosion, in particular with increasing age. Due to high monetary and societal cost (non-availability), replacement is often undesirable. Durable repair is necessary, e.g. by Cathodic Protection (CP). CP involves an

  6. Impregnation of LSM Based Cathodes for Solid Oxide Fuel Cells

    DEFF Research Database (Denmark)

    Højberg, Jonathan; Søgaard, Martin

    2011-01-01

    Composites cathodes consisting of strontium doped lanthanum manganite (LSM) and yttria stabilized zirconia have been impregnated with the nitrates corresponding to the nominal compositions: La0.75Sr0.25Mn1.05O3 +/-delta (LSM25), Ce0.8Sm0.2O2 (SDC) and a combination of both (dual). The latter...

  7. Long-Term Stability of LSM-YSZ Based Cathodes

    DEFF Research Database (Denmark)

    Baqué, Laura; Jørgensen, Peter Stanley; Hansen, Karin Vels

    2013-01-01

    A transmission line based model was successfully applied to study the ageing effect in LSM-YSZ cathodes after being exposed to humidified air at 900 °C for up to 3000 h. A decrease in the YSZ conductivity was correlated with the formation of the less conducting monoclinic zirconia. The amount of La...

  8. Engineering analyses of large precision cathode strip chambers for GEM

    Energy Technology Data Exchange (ETDEWEB)

    Horvath, J.A.; Belser, F.C.; Pratuch, S.M.; Wuest, C.R. [Lawrence Livermore National Lab., CA (United States); Mitselmakher, G. [Superconducting Super Collider Lab., Dallas, TX (United States); Gordeev, A. [Institute of Theoretical and Experimental Physics, Moscow (Russian Federation); Johnson, C.V. [Lawrence Livermore National Lab., CA (United States)]|[Superconducting Super Collider Lab., Dallas, TX (United States); Polychronakos, V.A. [Brookhaven National Lab., Upton, NY (United States); Golutvin, I.A. [Joint Institute for Nuclear Research, Dubna (Russian Federation)

    1993-10-21

    Structural analyses of large precision cathode strip chambers performed up to the date of this publication are documented. Mechanical property data for typical chamber materials are included. This information, originally intended to be an appendix to the {open_quotes}CSC Structural Design Bible,{close_quotes} is presented as a guide for future designers of large chambers.

  9. High Performance Infiltrated Backbones for Cathode-Supported SOFC's

    DEFF Research Database (Denmark)

    Gil, Vanesa; Kammer Hansen, Kent

    2014-01-01

    The concept of using highly ionic conducting backbones with subsequent infiltration of electronically conducting particles has widely been used to develop alternative anode-supported SOFC's. In this work, the idea was to develop infiltrated backbones as an alternative design based on cathode...

  10. Remote Sensing Studies of Suspended Sediment Concentration Variation in Barito Delta

    Science.gov (United States)

    Arisanty, Deasy; Nur Saputra, Aswin

    2017-12-01

    The dynamic of suspended sediment concentration in Barito Delta depend on the process in upstream. Agriculture, mining, and illegal logging in Barito River upstream has an effect for suspended sediment concentration in Barito Delta. The objective of research is to estimate the variation of suspended sediment concentration in Barito Delta. The data of research consist of Landsat 7 in year 2011 and measurement result data of suspended sediment concentration both in wet season and dry season in year 2011. Data analysis is regression analysis to estimates the variation of suspended sediment concentration in Barito Delta. The method of research compares three types of spectral transformation for suspended sediment that is Normalized Suspended Material Index (NSMI), Normalized Differences Suspended Sediment Index (NDSSI), and band ratio (green/blue). The result of the transformation is compared with the value of the field measurement. Based on the result of the comparison can be known the suitable type of transformation for the suspended sediment estimation in Barito Delta. The result of research explains that NSMI has the highest value to estimate the variation of suspended sediment concentration in Barito Delta.

  11. High Quality Virtual Reality for Architectural Exhibitions

    DEFF Research Database (Denmark)

    Kreutzberg, Anette

    2016-01-01

    This paper will summarise the findings from creating and implementing a visually high quality Virtual Reality (VR) experiment as part of an international architecture exhibition. It was the aim to represent the architectural spatial qualities as well as the atmosphere created from combining natural...... and artificial lighting in a prominent not yet built project. The outcome is twofold: Findings concerning the integration of VR in an exhibition space and findings concerning the experience of the virtual space itself. In the exhibition, an important aspect was the unmanned exhibition space, requiring the VR...... and quantitative methods at two different occasions and setups after the exhibition, both showing a high degree of immersion and experience of reality....

  12. The Culture of Exhibitions and Conservation

    Directory of Open Access Journals (Sweden)

    Dimitrios Doumas

    2013-11-01

    Full Text Available The article reflects on temporary exhibitions from a theoretical as well as practical perspective. Regarded as a particularly effective mass-communication medium, exhibitions have a dual nature: they are scholarly undertakings, bringing off a curator’s vision and, simultaneously, they are projects with economic implications that need to be well managed and administered. The role of conservation in the making of temporary exhibitions, either in-house or touring, is here discussed in relation to how work is planned and prioritized as well as how time is managed and staff is allocated. Reference to weaknesses that lessen the crucial input of conservation in the decision-making process is also made. Much of the debate, which focuses on art exhibitions, concerns practicalities encountered in a private museum that extend from the very early stages of selecting objects for display to the mounting of an exhibition.

  13. Holland at CERN – Industrial exhibition

    CERN Multimedia

    GS Department

    2010-01-01

    Sponsored by EVD, an agency of the Dutch Ministry of the Economy From 8 to 11 November 2010 Industrial Exhibition Administration Building Bldg. 61 9-00 - 17-30 Twenty seven companies will present their latest technology at the industrial exhibition "Holland at CERN". Dutch industry will exhibit products and technologies which are related to the field of particle physics. Individual interviews will take place directly at the stands in the Main Building. The firms will contact relevant users/technicians but any user wishing to make contact with a particular firm is welcome to use the contact details which are available from each departmental secretariat or at the following URL: http://gs-dep.web.cern.ch/gs-dep/groups/sem/ls/Industrial_Exhibitions.htm#Industrial_exhibitions You will find the list of exhibitors below. LIST OF EXHIBITORS: Schelde Exotech Vernooy BV Triumph Group INCAA Computers DeMaCo Holland bv TNO Science & Industry Janssen Precision Engi...

  14. Composite Cathodes for Dual-Rate Li-Ion Batteries

    Science.gov (United States)

    Whitacre, Jay; West, William; Bugga, Ratnakumar

    2008-01-01

    Composite-material cathodes that enable Li-ion electrochemical cells and batteries to function at both high energy densities and high discharge rates are undergoing development. Until now, using commercially available cathode materials, it has been possible to construct cells that have either capability for high-rate discharge or capability to store energy at average or high density, but not both capabilities. However, both capabilities are needed in robotic, standby-power, and other applications that involve duty cycles that include long-duration, low-power portions and short-duration, high-power portions. The electrochemically active ingredients of the present developmental composite cathode materials are: carbon-coated LiFePO4, which has a specific charge capacity of about 160 mA h/g and has been used as a high-discharge-rate cathode material and Li[Li(0.17)Mn(0.58)Ni(0.25)]O2, which has a specific charge capacity of about 240 mA h/g and has been used as a high-energy-density cathode material. In preparation for fabricating the composite material cathode described, these electrochemically active ingredients are incorporated into two sub-composites: a mixture comprising 10 weight percent of poly(vinylidine fluoride); 10 weight percent of carbon and 80 weight percent of carbon coated LiFePO4; and, a mixture comprising 10 weight percent of PVDF, and 80 weight percent of Li[Li(0.17)Mn(0.58)Ni(0.25)]O2. In the fabrication process, these mixtures are spray-deposited onto an aluminum current collector. Electrochemical tests performed thus far have shown that better charge/discharge performance is obtained when either 1) each mixture is sprayed on a separate area of the current collector or (2) the mixtures are deposited sequentially (in contradistinction to simultaneously) on the same current-collector area so that the resulting composite cathode material consists of two different sub-composite layers.

  15. High performance and durability of order-structured cathode catalyst layer based on TiO{sub 2}@PANI core-shell nanowire arrays

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Ming; Wang, Meng; Yang, Zhaoyi [State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, 30 College Road, Beijing 100083 (China); School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30 College Road, Beijing 100083 (China); Wang, Xindong, E-mail: echem@ustb.edu.cn [State Key Laboratory of Advanced Metallurgy, University of Science and Technology Beijing, 30 College Road, Beijing 100083 (China); School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, 30 College Road, Beijing 100083 (China)

    2017-06-01

    Highlights: • TiO{sub 2}@PANI core-shell nanowire arrays were prepared and applied as catalyst support. • As-prepared Pt-TiO{sub 2}@PANI core-shell nanowire arrays were applied as order-structured cathode catalyst layer. • The novel cathode catalyst structure without Nafion{sup ®} ionomer enhance the performance and durability of PEMFC. - Abstract: In this paper, an order-structured cathode catalyst layer consisting of Pt-TiO{sub 2}@PANI core-shell nanowire arrays that in situ grown on commercial gas diffusion layer (GDL) are prepared and applied to membrane electrode assembly (MEA) of proton exchange membrane fuel cell (PEMFC). In order to prepare the TiO{sub 2}@PANI core-shell nanowire arrays with suitable porosity and prominent conductivity, the morphologies of the TiO{sub 2} nanoarray and electrochemical polymerization process of aniline are schematically investigated. The MEA with order-structured cathode catalyst layer is assembled in the single cell to evaluate the electrochemical performance and durability of PEMFC. As a result, the PEMFC with order-structured cathode catalyst layer shows higher peak power density (773.54 mW cm{sup −2}) than conventional PEMFC (699.30 mW cm{sup −2}). Electrochemically active surface area (ECSA) and charge transfer impedance (R{sub ct}) are measured before and after accelerated degradation test (ADT), and the corresponding experimental results indicate the novel cathode structure exhibits a better stability with respect to conventional cathode. The enhanced electrochemical performance and durability toward PEMFC can be ascribed to the order-structured cathode nanoarray structure with high specific surface area increases the utilization of catalyst and reduces the tortuosity of transport pathways, and the synergistic effect between TiO{sub 2}@PANI support and Pt nanoparticles promotes the high efficiency of electrochemical reaction and improves the stability of catalyst. This research provides a facile and

  16. Functionally Graded Cathodes for Solid Oxide Fuel Cells

    Energy Technology Data Exchange (ETDEWEB)

    Harry Abernathy; Meilin Liu

    2006-12-31

    One primary suspected cause of long-term performance degradation of solid oxide fuels (SOFCs) is the accumulation of chromium (Cr) species at or near the cathode/electrolyte interface due to reactive Cr molecules originating from Cr-containing components (such as the interconnect) in fuel cell stacks. To date, considerable efforts have been devoted to the characterization of cathodes exposed to Cr sources; however, little progress has been made because a detailed understanding of the chemistry and electrochemistry relevant to the Cr-poisoning processes is still lacking. This project applied multiple characterization methods - including various Raman spectroscopic techniques and various electrochemical performance measurement techniques - to elucidate and quantify the effect of Cr-related electrochemical degradation at the cathode/electrolyte interface. Using Raman microspectroscopy the identity and location of Cr contaminants (SrCrO{sub 4}, (Mn/Cr){sub 3}O{sub 4} spinel) have been observed in situ on an LSM cathode. These Cr contaminants were shown to form chemically (in the absence of current flowing through the cell) at temperatures as low as 625 C. While SrCrO{sub 4} and (Mn/Cr){sub 3}O{sub 4} spinel must preferentially form on LSM, since the LSM supplies the Sr and Mn cations necessary for these compounds, LSM was also shown to be an active site for the deposition of Ag{sub 2}CrO{sub 4} for samples that also contained silver. In contrast, Pt and YSZ do not appear to be active for formation of Cr-containing phases. The work presented here supports the theory that Cr contamination is predominantly chemically-driven and that in order to minimize the effect, cathode materials should be chosen that are free of cations/elements that could preferentially react with chromium, including silver, strontium, and manganese.

  17. Museum Exhibitions: Optimizing Development Using Evaluation

    Science.gov (United States)

    Dusenbery, P. B.

    2002-12-01

    The Space Science Institute (SSI) of Boulder, Colorado, has recently developed two museum exhibits called the Space Weather Center and MarsQuest. It is currently planning to develop a third exhibit called InterActive Earth. The Space Weather Center was developed in partnership with various research missions at NASA's Goddard Space Flight Center. The development of these exhibitions included a comprehensive evaluation plan. I will report on the important role evaluation plays in exhibit design and development using MarsQuest and InterActive Earth as models. The centerpiece of SSI's Mars Education Program is the 5,000-square-foot traveling exhibition, MarsQuest: Exploring the Red Planet, which was developed with support from the National Science Foundation (NSF), NASA, and several corporate donors. The MarsQuest exhibit is nearing the end of a highly successful, fully-booked three-year tour. The Institute plans to send an enhanced and updated MarsQuest on a second three-year tour and is also developing Destination: Mars, a mini-version of MarsQuest designed for smaller venues. They are designed to inspire and empower participants to extend the excitement and science content of the exhibitions into classrooms and museum-based education programs in an ongoing fashion. The centerpiece of the InterActive Earth project is a traveling exhibit that will cover about 4,000 square feet. The major goal of the proposed exhibit is to introduce students and the public to the complexity of the interconnections in the Earth system, and thereby, to inspire them to better understand planet Earth. Evaluation must be an integral part of the exhibition development process. For MarsQuest, a 3-phase evaluation (front end, formative and summative) was conducted by Randi Korn and Associates in close association with the development team. Sampling procedures for all three evaluation phases ensured the participation of all audiences, including family groups, students, and adults. Each phase of

  18. Synchrotron X-ray studies of model SOFC cathodes, part II: Porous powder cathodes

    Energy Technology Data Exchange (ETDEWEB)

    Chang, Kee-Chul; Ingram, Brian; Ilavsky, Jan; Lee, Shiwoo; Fuoss, Paul; You, Hoydoo

    2017-11-01

    Infiltrated La0.6Sr0.4Co0.2Fe0.8O3-δ (LSCF) sintered porous powder cathodes for solid oxide fuel cells have been investigated by synchrotron ultra-small angle x-ray scattering (USAXS). We demonstrated that atomic layer deposition (ALD) is the method for a uniform coating and liquid-phase infiltration for growing nanoscale particles on the porous LSCF surfaces. The MnO infiltrate, grown by ALD, forms a conformal layer with a uniform thickness throughout the pores evidenced by USAXS thickness fringes. The La0.6Sr0.4CoO3 (LSC) and La2Zr2O7 (LZO) infiltrates, grown by liquid-phase infiltration, were found to form nanoscale particles on the surfaces of LSCF particles resulting in increased surface areas. Impedance measurements suggest that the catalytic property of LSC infiltrate, not the increased surface area of LZO, is important for increasing oxygen reduction activities.

  19. A mini-exhibition with maximum content

    CERN Multimedia

    Laëtitia Pedroso

    2011-01-01

    The University of Budapest has been hosting a CERN mini-exhibition since 8 May. While smaller than the main travelling exhibition it has a number of major advantages: its compact design alleviates transport difficulties and makes it easier to find suitable venues in the Member States. Its content can be updated almost instantaneously and it will become even more interactive and high-tech as time goes by.   The exhibition on display in Budapest. The purpose of CERN's new mini-exhibition is to be more interactive and easier to install. Due to its size, the main travelling exhibition cannot be moved around quickly, which is why it stays in the same country for 4 to 6 months. But this means a long waiting list for the other Member States. To solve this problem, the Education Group has designed a new exhibition, which is smaller and thus easier to install. Smaller maybe, but no less rich in content, as the new exhibition conveys exactly the same messages as its larger counterpart. However, in the slimm...

  20. Thermoelectric unipolar spin battery in a suspended carbon nanotube

    Science.gov (United States)

    Cao, Zhan; Fang, Tie-Feng; He, Wan-Xiu; Luo, Hong-Gang

    2017-04-01

    A quantum dot formed in a suspended carbon nanotube exposed to an external magnetic field is predicted to act as a thermoelectric unipolar spin battery which generates pure spin current. The built-in spin flip mechanism is a consequence of the spin-vibration interaction resulting from the interplay between the intrinsic spin-orbit coupling and the vibrational modes of the suspended carbon nanotube. On the other hand, utilizing thermoelectric effect, the temperature difference between the electron and the thermal bath to which the vibrational modes are coupled provides the driving force. We find that both magnitude and direction of the generated pure spin current are dependent on the strength of spin-vibration interaction, the sublevel configuration in dot, the temperatures of electron and thermal bath, and the tunneling rate between the dot and the pole. Moreover, in the linear response regime, the kinetic coefficient is non-monotonic in the temperature T and it reaches its maximum when {{k}\\text{B}}T is about one phonon energy. The existence of a strong intradot Coulomb interaction is irrelevant for our spin battery, provided that high-order cotunneling processes are suppressed.