Modeling Water Resource Systems Accounting for Water-Related Energy Use, GHG Emissions and Water-Dependent Energy Generation in California

Science.gov (United States)

Escriva-Bou, A.; Lund, J. R.; Pulido-Velazquez, M.; Medellin-Azuara, J.

2015-12-01

Most individual processes relating water and energy interdependence have been assessed in many different ways over the last decade. It is time to step up and include the results of these studies in management by proportionating a tool for integrating these processes in decision-making to effectively understand the tradeoffs between water and energy from management options and scenarios. A simple but powerful decision support system (DSS) for water management is described that includes water-related energy use and GHG emissions not solely from the water operations, but also from final water end uses, including demands from cities, agriculture, environment and the energy sector. Because one of the main drivers of energy use and GHG emissions is water pumping from aquifers, the DSS combines a surface water management model with a simple groundwater model, accounting for their interrelationships. The model also explicitly includes economic data to optimize water use across sectors during shortages and calculate return flows from different uses. Capabilities of the DSS are demonstrated on a case study over California's intertied water system. Results show that urban end uses account for most GHG emissions of the entire water cycle, but large water conveyance produces significant peaks over the summer season. Also the development of more efficient water application on the agricultural sector has increased the total energy consumption and the net water use in the basins.

Surface properties of Ti-6Al-4V alloy part I: Surface roughness and apparent surface free energy.

Science.gov (United States)

Yan, Yingdi; Chibowski, Emil; Szcześ, Aleksandra

2017-01-01

Titanium (Ti) and its alloys are the most often used implants material in dental treatment and orthopedics. Topography and wettability of its surface play important role in film formation, protein adhesion, following osseointegration and even duration of inserted implant. In this paper, we prepared Ti-6Al-4V alloy samples using different smoothing and polishing materials as well the air plasma treatment, on which contact angles of water, formamide and diiodomethane were measured. Then the apparent surface free energy was calculated using four different approaches (CAH, LWAB, O-W and Neumann's Equation of State). From LWAB approach the components of surface free energy were obtained, which shed more light on the wetting properties of samples surface. The surface roughness of the prepared samples was investigated with the help of optical profilometer and AFM. It was interesting whether the surface roughness affects the apparent surface free energy. It was found that both polar interactions the electron donor parameter of the energy and the work of water adhesion increased with decreasing roughness of the surfaces. Moreover, short time plasma treatment (1min) caused decrease in the surface hydrophilic character, while longer time (10min) treatment caused significant increase in the polar interactions and the work of water adhesion. Although Ti-6Al-4V alloy has been investigated many times, to our knowledge, so far no paper has been published in which surface roughness and changes in the surface free energy of the alloy were compared in the quantitative way in such large extent. This novel approach deliver better knowledge about the surface properties of differently smoothed and polished samples which may be helpful to facilitate cell adhesion, proliferation and mineralization. Therefore the results obtained present also potentially practical meaning. Copyright © 2016 Elsevier B.V. All rights reserved.

Surface properties of Ti-6Al-4V alloy part I: Surface roughness and apparent surface free energy

Energy Technology Data Exchange (ETDEWEB)

Yan, Yingdi; Chibowski, Emil; Szcześ, Aleksandra, E-mail: aszczes@poczta.umcs.lublin.pl

2017-01-01

Titanium (Ti) and its alloys are the most often used implants material in dental treatment and orthopedics. Topography and wettability of its surface play important role in film formation, protein adhesion, following osseointegration and even duration of inserted implant. In this paper, we prepared Ti-6Al-4V alloy samples using different smoothing and polishing materials as well the air plasma treatment, on which contact angles of water, formamide and diiodomethane were measured. Then the apparent surface free energy was calculated using four different approaches (CAH, LWAB, O-W and Neumann's Equation of State). From LWAB approach the components of surface free energy were obtained, which shed more light on the wetting properties of samples surface. The surface roughness of the prepared samples was investigated with the help of optical profilometer and AFM. It was interesting whether the surface roughness affects the apparent surface free energy. It was found that both polar interactions the electron donor parameter of the energy and the work of water adhesion increased with decreasing roughness of the surfaces. Moreover, short time plasma treatment (1 min) caused decrease in the surface hydrophilic character, while longer time (10 min) treatment caused significant increase in the polar interactions and the work of water adhesion. Although Ti-6Al-4V alloy has been investigated many times, to our knowledge, so far no paper has been published in which surface roughness and changes in the surface free energy of the alloy were compared in the quantitative way in such large extent. This novel approach deliver better knowledge about the surface properties of differently smoothed and polished samples which may be helpful to facilitate cell adhesion, proliferation and mineralization. Therefore the results obtained present also potentially practical meaning. - Highlights: • Surface of five Ti-6Al-4V alloy samples were smoothed and polished successively. • The

Crystal Structures, Surface Stability, and Water Adsorption Energies of La-Bastnäsite via Density Functional Theory and Experimental Studies

Energy Technology Data Exchange (ETDEWEB)

Srinivasan, Sriram Goverapet [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Shivaramaiah, Radha [Univ. of California, Davis, CA (United States); Kent, Paul R. C. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Stack, Andrew G. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States); Navrotsky, Alexandra [Univ. of California, Davis, CA (United States); Riman, Richard [State Univ. of New Jersey, Piscataway, NJ (United States); Anderko, Andre [OLI Systems, Inc., Cedar Knolls, NJ (United States); Bryantsev, Vyacheslav S. [Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

2016-07-11

Bastnasite is a fluoro-carbonate mineral that is the largest source of rare earth elements such as Y, La and Ce. With increasing demand for REE in many emerging technologies, there is an urgent need for improving the efficiency of ore beneficiation by froth flotation. In order to design improved flotation agents that can selectively bind to the mineral surface, a fundamental understanding of the bulk and surface properties of bastnasite is essential. Density functional theory calculations using the PBEsol exchange correlation functional and the DFT-D3 dispersion correction reveal that the most stable form of La bastnsite is isomorphic to the structure of Ce bastnasite belonging to the P2c space group, while the Inorganic Crystal Structure Database structure in the P2m space group is ca. 11.3 kJ/mol higher in energy per LaFCO₃ formula unit. We report powder X-ray diffraction measurements on synthetic of La bastnasite to support these theoretical findings. Six different surfaces are studied by DFT, namely [100], [0001], [101], [102], [104] and [112]. Among these, the [100] surface is the most stable with a surface energy of 0.73 J/m² in vacuum and 0.45 J/m² in aqueous solution. We predicted the shape of a La bastnasite nanoparticle via thermodynamic Wulff construction to be a hexagonal prism with [100] and [0001] facets, chiseled at its ends by the [101] and [102] facets. The average surface energy of the nanoparticle in the gas phase is estimated to be 0.86 J/m², in good agreement with a value of 1.11 J/m² measured by calorimetry. The calculated adsorption energy of a water molecule varies widely with the surface plane and specific adsorption sites on a given surface. Moreover, the first layer of water molecules is predicted to adsorb strongly on the La-bastnasite surface, in agreement with water adsorption calorimetry experiments. Our work provides an important step towards a detailed atomistic understanding of

Energy implications of bottled water

International Nuclear Information System (INIS)

Gleick, P H; Cooley, H S

2009-01-01

As bottled water use continues to expand around the world, there is growing interest in the environmental, economical, and social implications of that use, including concerns about waste generation, proper use of groundwater, hydrologic effects on local surface and groundwater, economic costs, and more. A key concern is how much energy is required to produce and use bottled water. This paper estimates the energy footprint required for various phases of bottled water production, transportation, and use. We do not develop a single comprehensive life-cycle energy estimate because of differences among water sources, bottling processes, transportation costs, and other factors, but we quantify key energy inputs necessary for site-specific assessments. We also apply these inputs to three site-specific examples of the energy required from production to the point of use: local bottled water produced and used in Los Angeles, water bottled in the South Pacific and shipped by cargo ship to Los Angeles, and water bottled in France and shipped in various ways to Los Angeles. For water transported short distances, the energy requirements of bottled water are dominated by the energy used to produce the plastic bottles. Long-distance transport, however, can lead to energy costs comparable to, or even larger than, those of producing the bottle. All other energy costs-for processing, bottling, sealing, labeling, and refrigeration-are far smaller than those for the production of the bottle and transportation. These data can be used to generate specific estimates for different sources, treatments, and delivery options.

Direct Measurement of the Surface Energy of Graphene.

Science.gov (United States)

van Engers, Christian D; Cousens, Nico E A; Babenko, Vitaliy; Britton, Jude; Zappone, Bruno; Grobert, Nicole; Perkin, Susan

2017-06-14

Graphene produced by chemical vapor deposition (CVD) is a promising candidate for implementing graphene in a range of technologies. In most device configurations, one side of the graphene is supported by a solid substrate, wheras the other side is in contact with a medium of interest, such as a liquid or other two-dimensional material within a van der Waals stack. In such devices, graphene interacts on both faces via noncovalent interactions and therefore surface energies are key parameters for device fabrication and operation. In this work, we directly measured adhesive forces and surface energies of CVD-grown graphene in dry nitrogen, water, and sodium cholate using a modified surface force balance. For this, we fabricated large (∼1 cm 2 ) and clean graphene-coated surfaces with smooth topography at both macro- and nanoscales. By bringing two such surfaces into contact and measuring the force required to separate them, we measured the surface energy of single-layer graphene in dry nitrogen to be 115 ± 4 mJ/m 2 , which was similar to that of few-layer graphene (119 ± 3 mJ/m 2 ). In water and sodium cholate, we measured interfacial energies of 83 ± 7 and 29 ± 6 mJ/m 2 , respectively. Our work provides the first direct measurement of graphene surface energy and is expected to have an impact both on the development of graphene-based devices and contribute to the fundamental understanding of surface interactions.

Summertime influences of tidal energy advection on the surface energy balance in a mangrove forest

Directory of Open Access Journals (Sweden)

J. G. Barr

2013-01-01

Full Text Available Mangrove forests are ecosystems susceptible to changing water levels and temperatures due to climate change as well as perturbations resulting from tropical storms. Numerical models can be used to project mangrove forest responses to regional and global environmental changes, and the reliability of these models depends on surface energy balance closure. However, for tidal ecosystems, the surface energy balance is complex because the energy transport associated with tidal activity remains poorly understood. This study aimed to quantify impacts of tidal flows on energy dynamics within a mangrove ecosystem. To address the research objective, an intensive 10-day study was conducted in a mangrove forest located along the Shark River in the Everglades National Park, FL, USA. Forest–atmosphere turbulent exchanges of energy were quantified with an eddy covariance system installed on a 30-m-tall flux tower. Energy transport associated with tidal activity was calculated based on a coupled mass and energy balance approach. The mass balance included tidal flows and accumulation of water on the forest floor. The energy balance included temporal changes in enthalpy, resulting from tidal flows and temperature changes in the water column. By serving as a net sink or a source of available energy, flood waters reduced the impact of high radiational loads on the mangrove forest. Also, the regression slope of available energy versus sink terms increased from 0.730 to 0.754 and from 0.798 to 0.857, including total enthalpy change in the water column in the surface energy balance for 30-min periods and daily daytime sums, respectively. Results indicated that tidal inundation provides an important mechanism for heat removal and that tidal exchange should be considered in surface energy budgets of coastal ecosystems. Results also demonstrated the importance of including tidal energy advection in mangrove biophysical models that are used for predicting ecosystem

The Water Demand of Energy: Implications for Sustainable Energy Policy Development

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Kaveh Madani

2013-11-01

Full Text Available With energy security, climate change mitigation, and sustainable development as three main motives, global energy policies have evolved, now asking for higher shares of renewable energies, shale oil and gas resources in the global energy supply portfolios. Yet, concerns have recently been raised about the environmental impacts of the renewable energy development, supported by many governments around the world. For example, governmental ethanol subsidies and mandates in the U.S. are aimed to increase the biofuel supply while the water footprint of this type of energy might be 70–400 times higher than the water footprint of conventional fossil energy sources. Hydrofracking, as another example, has been recognized as a high water-intensive procedure that impacts the surface and ground water in both quality and quantity. Hence, monitoring the water footprint of the energy mix is significantly important and could have implications for energy policy development. This paper estimates the water footprint of current and projected global energy policies, based on the energy production and consumption scenarios, developed by the International Energy Outlook of the U.S. Energy Information Administration. The outcomes reveal the amount of water required for total energy production in the world will increase by 37%–66% during the next two decades, requiring extensive improvements in water use efficiency of the existing energy production technologies, especially renewables.

Dynamics of ice nucleation on water repellent surfaces.

Science.gov (United States)

Alizadeh, Azar; Yamada, Masako; Li, Ri; Shang, Wen; Otta, Shourya; Zhong, Sheng; Ge, Liehui; Dhinojwala, Ali; Conway, Ken R; Bahadur, Vaibhav; Vinciquerra, A Joseph; Stephens, Brian; Blohm, Margaret L

2012-02-14

Prevention of ice accretion and adhesion on surfaces is relevant to many applications, leading to improved operation safety, increased energy efficiency, and cost reduction. Development of passive nonicing coatings is highly desirable, since current antiicing strategies are energy and cost intensive. Superhydrophobicity has been proposed as a lead passive nonicing strategy, yet the exact mechanism of delayed icing on these surfaces is not clearly understood. In this work, we present an in-depth analysis of ice formation dynamics upon water droplet impact on surfaces with different wettabilities. We experimentally demonstrate that ice nucleation under low-humidity conditions can be delayed through control of surface chemistry and texture. Combining infrared (IR) thermometry and high-speed photography, we observe that the reduction of water-surface contact area on superhydrophobic surfaces plays a dual role in delaying nucleation: first by reducing heat transfer and second by reducing the probability of heterogeneous nucleation at the water-substrate interface. This work also includes an analysis (based on classical nucleation theory) to estimate various homogeneous and heterogeneous nucleation rates in icing situations. The key finding is that ice nucleation delay on superhydrophobic surfaces is more prominent at moderate degrees of supercooling, while closer to the homogeneous nucleation temperature, bulk and air-water interface nucleation effects become equally important. The study presented here offers a comprehensive perspective on the efficacy of textured surfaces for nonicing applications.

Land surface temperature representativeness in a heterogeneous area through a distributed energy-water balance model and remote sensing data

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C. Corbari

2010-10-01

Full Text Available Land surface temperature is the link between soil-vegetation-atmosphere fluxes and soil water content through the energy water balance. This paper analyses the representativeness of land surface temperature (LST for a distributed hydrological water balance model (FEST-EWB using LST from AHS (airborne hyperspectral scanner, with a spatial resolution between 2–4 m, LST from MODIS, with a spatial resolution of 1000 m, and thermal infrared radiometric ground measurements that are compared with the representative equilibrium temperature that closes the energy balance equation in the distributed hydrological model.

Diurnal and nocturnal images are analyzed due to the non stable behaviour of the thermodynamic temperature and to the non linear effects induced by spatial heterogeneity.

Spatial autocorrelation and scale of fluctuation of land surface temperature from FEST-EWB and AHS are analysed at different aggregation areas to better understand the scale of representativeness of land surface temperature in a hydrological process.

The study site is the agricultural area of Barrax (Spain that is a heterogeneous area with a patchwork of irrigated and non irrigated vegetated fields and bare soil. The used data set was collected during a field campaign from 10 to 15 July 2005 in the framework of the SEN2FLEX project.

Structure and optical properties of water covered Cu(110) surfaces

International Nuclear Information System (INIS)

Baghbanpourasl, A.

2014-01-01

In this thesis structural and optical properties of the water covered Cu(110) surface is studied using density functional theory within independent particle approximation. Several stable adsorption structures are studied such as water clusters (monomer, dimer, trimer, tetramer and pentamer), different hexagonal monolayers, partially dissociated water monolayers and three different types of chains among them a chain that consists of pentagon rings. For a copper surface in contact with water vapor, the energetically stable H 2 O/OH adsorbed structures are compared thermodynamically using adsorption free energy (change of free energy due to adsorption). Several phase diagrams with respect to temperature and pressure are calculated. It is found that among the large number of energetically stable structures (i.e. structures with positive adsorption energy ) only limited number of them are thermodynamically stable. These thermodynamically stable structures are the class of almost energetically degenerate hexagonal overlayers, one type of partially dissociated water structure that contains Bjerrum defect in the hydrogen bond network and pentagon chain. Since hydrogen atoms are light weight their vibrational effects can be considerable. Zero point vibration decreases the adsorption energy up to 0.1 eV and free energy of adsorbed molecules arising from vibrational degree of freedom can go up to -0.2 eV per adsorbed molecule at 500 Kelvin. However zero point energy and vibrational free energy of adsorbed molecules do not alter relative stability of the adsorbed structures. To account for the long range van der Waals interactions, a semi-empirical scheme is applied. Reflectance Anisotropy Spectroscopy (RAS) is a fast and non destructive optical method that can be used to prob the surface in different conditions such as vacuum and electro-chemical environment. Elasto-optic coeficients of bulk are calculated from first principles and the change of the RA spectrum of the bare Cu

Effects of leaf area index on the coupling between water table, land surface energy fluxes, and planetary boundary layer at the regional scale

Science.gov (United States)

Lu, Y.; Rihani, J.; Langensiepen, M.; Simmer, C.

2013-12-01

Vegetation plays an important role in the exchange of moisture and energy at the land surface. Previous studies indicate that vegetation increases the complexity of the feedbacks between the atmosphere and subsurface through processes such as interception, root water uptake, leaf surface evaporation, and transpiration. Vegetation cover can affect not only the interaction between water table depth and energy fluxes, but also the development of the planetary boundary layer. Leaf Area Index (LAI) is shown to be a major factor influencing these interactions. In this work, we investigate the sensitivity of water table, surface energy fluxes, and atmospheric boundary layer interactions to LAI as a model input. We particularly focus on the role LAI plays on the location and extent of transition zones of strongest coupling and how this role changes over seasonal timescales for a real catchment. The Terrestrial System Modelling Platform (TerrSysMP), developed within the Transregional Collaborative Research Centre 32 (TR32), is used in this study. TerrSysMP consists of the variably saturated groundwater model ParFlow, the land surface model Community Land Model (CLM), and the regional climate and weather forecast model COSMO (COnsortium for Small-scale Modeling). The sensitivity analysis is performed over a range of LAI values for different vegetation types as extracted from the Moderate Resolution Imaging Spectroradiometer (MODIS) dataset for the Rur catchment in Germany. In the first part of this work, effects of vegetation structure on land surface energy fluxes and their connection to water table dynamics are studied using the stand-alone CLM and the coupled subsurface-surface components of TerrSysMP (ParFlow-CLM), respectively. The interconnection between LAI and transition zones of strongest coupling are investigated and analyzed through a subsequent set of subsurface-surface-atmosphere coupled simulations implementing the full TerrSysMP model system.

Surface Plasmon-Assisted Solar Energy Conversion.

Science.gov (United States)

Dodekatos, Georgios; Schünemann, Stefan; Tüysüz, Harun

2016-01-01

The utilization of localized surface plasmon resonance (LSPR) from plasmonic noble metals in combination with semiconductors promises great improvements for visible light-driven photocatalysis, in particular for energy conversion. This review summarizes the basic principles of plasmonic photocatalysis, giving a comprehensive overview about the proposed mechanisms for enhancing the performance of photocatalytically active semiconductors with plasmonic devices and their applications for surface plasmon-assisted solar energy conversion. The main focus is on gold and, to a lesser extent, silver nanoparticles in combination with titania as semiconductor and their usage as active plasmonic photocatalysts. Recent advances in water splitting, hydrogen generation with sacrificial organic compounds, and CO2 reduction to hydrocarbons for solar fuel production are highlighted. Finally, further improvements for plasmonic photocatalysts, regarding performance, stability, and economic feasibility, are discussed for surface plasmon-assisted solar energy conversion.

Patterned gradient surface for spontaneous droplet transportation and water collection: simulation and experiment

International Nuclear Information System (INIS)

Tan, Xianhua; Zhu, Yiying; Shi, Tielin; Tang, Zirong; Liao, Guanglan

2016-01-01

We demonstrate spontaneous droplet transportation and water collection on wedge-shaped gradient surfaces consisting of alternating hydrophilic and hydrophobic regions. Droplets on the surfaces are modeled and simulated to analyze the Gibbs free energy and free energy gradient distributions. Big half-apex angle and great wettability difference result in considerable free energy gradient, corresponding to large driving force for spontaneous droplet transportation, thus causing the droplets to move towards the open end of the wedge-shaped hydrophilic regions, where the Gibbs free energy is low. Gradient surfaces are then fabricated and tested. Filmwise condensation begins on the hydrophilic regions, forming wedge-shaped tracks for water collection. Dropwise condensation occurs on the hydrophobic regions, where the droplet size distribution and departure diameters are controlled by the width of the regions. Condensate water from both the hydrophilic and hydrophobic regions are collected directionally to the open end of the wedge-shaped hydrophilic regions, agreeing with the simulations. Directional droplet transport and controllable departure diameters make the branched gradient surfaces more efficient than smooth surfaces for water collection, which proves that gradient surfaces are potential in water collection, microfluidic devices, anti-fogging and self-cleaning. (paper)

A one-layer satellite surface energy balance for estimating evapotranspiration rates and crop water stress indexes.

Science.gov (United States)

Barbagallo, Salvatore; Consoli, Simona; Russo, Alfonso

2009-01-01

Daily evapotranspiration fluxes over the semi-arid Catania Plain area (Eastern Sicily, Italy) were evaluated using remotely sensed data from Landsat Thematic Mapper TM5 images. A one-source parameterization of the surface sensible heat flux exchange using satellite surface temperature has been used. The transfer of sensible and latent heat is described by aerodynamic resistance and surface resistance. Required model inputs are brightness, temperature, fractional vegetation cover or leaf area index, albedo, crop height, roughness lengths, net radiation, air temperature, air humidity and wind speed. The aerodynamic resistance (r(ah)) is formulated on the basis of the Monin-Obukhov surface layer similarity theory and the surface resistance (r(s)) is evaluated from the energy balance equation. The instantaneous surface flux values were converted into evaporative fraction (EF) over the heterogeneous land surface to derive daily evapotranspiration values. Remote sensing-based assessments of crop water stress (CWSI) were also made in order to identify local irrigation requirements. Evapotranspiration data and crop coefficient values obtained from the approach were compared with: (i) data from the semi-empirical approach "K(c) reflectance-based", which integrates satellite data in the visible and NIR regions of the electromagnetic spectrum with ground-based measurements and (ii) surface energy flux measurements collected from a micrometeorological tower located in the experiment area. The expected variability associated with ET flux measurements suggests that the approach-derived surface fluxes were in acceptable agreement with the observations.

An energy balance model exploration of the impacts of interactions between surface albedo, cloud cover and water vapor on polar amplification

Science.gov (United States)

Södergren, A. Helena; McDonald, Adrian J.; Bodeker, Gregory E.

2017-11-01

We examine the effects of non-linear interactions between surface albedo, water vapor and cloud cover (referred to as climate variables) on amplified warming of the polar regions, using a new energy balance model. Our simulations show that the sum of the contributions to surface temperature changes due to any variable considered in isolation is smaller than the temperature changes from coupled feedback simulations. This non-linearity is strongest when all three climate variables are allowed to interact. Surface albedo appears to be the strongest driver of this non-linear behavior, followed by water vapor and clouds. This is because increases in longwave radiation absorbed by the surface, related to increases in water vapor and clouds, and increases in surface absorbed shortwave radiation caused by a decrease in surface albedo, amplify each other. Furthermore, our results corroborate previous findings that while increases in cloud cover and water vapor, along with the greenhouse effect itself, warm the polar regions, water vapor also significantly warms equatorial regions, which reduces polar amplification. Changes in surface albedo drive large changes in absorption of incoming shortwave radiation, thereby enhancing surface warming. Unlike high latitudes, surface albedo change at low latitudes are more constrained. Interactions between surface albedo, water vapor and clouds drive larger increases in temperatures in the polar regions compared to low latitudes. This is in spite of the fact that, due to a forcing, cloud cover increases at high latitudes and decreases in low latitudes, and that water vapor significantly enhances warming at low latitudes.

Using self-consistent Gibbs free energy surfaces to calculate size distributions of neutral and charged clusters for the sulfuric acid-water binary system

Science.gov (United States)

Smith, J. A.; Froyd, K. D.; Toon, O. B.

2012-12-01

We construct tables of reaction enthalpies and entropies for the association reactions involving sulfuric acid vapor, water vapor, and the bisulfate ion. These tables are created from experimental measurements and quantum chemical calculations for molecular clusters and a classical thermodynamic model for larger clusters. These initial tables are not thermodynamically consistent. For example, the Gibbs free energy of associating a cluster consisting of one acid molecule and two water molecules depends on the order in which the cluster was assembled: add two waters and then the acid or add an acid and a water and then the second water. We adjust the values within the tables using the method of Lagrange multipliers to minimize the adjustments and produce self-consistent Gibbs free energy surfaces for the neutral clusters and the charged clusters. With the self-consistent Gibbs free energy surfaces, we calculate size distributions of neutral and charged clusters for a variety of atmospheric conditions. Depending on the conditions, nucleation can be dominated by growth along the neutral channel or growth along the ion channel followed by ion-ion recombination.

Integrated Water Resource Management and Energy Requirements for Water Supply in the Copiapó River Basin, Chile

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Francisco Suárez

2014-08-01

Full Text Available Population and industry growth in dry climates are fully tied to significant increase in water and energy demands. Because water affects many economic, social and environmental aspects, an interdisciplinary approach is needed to solve current and future water scarcity problems, and to minimize energy requirements in water production. Such a task requires integrated water modeling tools able to couple surface water and groundwater, which allow for managing complex basins where multiple stakeholders and water users face an intense competition for limited freshwater resources. This work develops an integrated water resource management model to investigate the water-energy nexus in reducing water stress in the Copiapó River basin, an arid, highly vulnerable basin in northern Chile. The model was utilized to characterize groundwater and surface water resources, and water demand and uses. Different management scenarios were evaluated to estimate future resource availability, and compared in terms of energy requirements and costs for desalinating seawater to eliminate the corresponding water deficit. Results show a basin facing a very complex future unless measures are adopted. When a 30% uniform reduction of water consumption is achieved, 70 GWh over the next 30 years are required to provide the energy needed to increase the available water through seawater desalination. In arid basins, this energy could be supplied by solar energy, thus addressing water shortage problems through integrated water resource management combined with new technologies of water production driven by renewable energy sources.

Energy, water and fish: biodiversity impacts of energy-sector water demand in the United States depend on efficiency and policy measures.

Science.gov (United States)

McDonald, Robert I; Olden, Julian D; Opperman, Jeffrey J; Miller, William M; Fargione, Joseph; Revenga, Carmen; Higgins, Jonathan V; Powell, Jimmie

2012-01-01

Rising energy consumption in coming decades, combined with a changing energy mix, have the potential to increase the impact of energy sector water use on freshwater biodiversity. We forecast changes in future water use based on various energy scenarios and examine implications for freshwater ecosystems. Annual water withdrawn/manipulated would increase by 18-24%, going from 1,993,000-2,628,000 Mm(3) in 2010 to 2,359,000-3,271,000 Mm(3) in 2035 under the Reference Case of the Energy Information Administration (EIA). Water consumption would more rapidly increase by 26% due to increased biofuel production, going from 16,700-46,400 Mm(3) consumption in 2010 to 21,000-58,400 Mm(3) consumption in 2035. Regionally, water use in the Southwest and Southeast may increase, with anticipated decreases in water use in some areas of the Midwest and Northeast. Policies that promote energy efficiency or conservation in the electric sector would reduce water withdrawn/manipulated by 27-36 m(3)GJ(-1) (0.1-0.5 m(3)GJ(-1) consumption), while such policies in the liquid fuel sector would reduce withdrawal/manipulation by 0.4-0.7 m(3)GJ(-1) (0.2-0.3 m(3)GJ(-1) consumption). The greatest energy sector withdrawal/manipulation are for hydropower and thermoelectric cooling, although potential new EPA rules that would require recirculating cooling for thermoelectric plants would reduce withdrawal/manipulation by 441,000 Mm(3) (20,300 Mm(3) consumption). The greatest consumptive energy sector use is evaporation from hydroelectric reservoirs, followed by irrigation water for biofuel feedstocks and water used for electricity generation from coal. Historical water use by the energy sector is related to patterns of fish species endangerment, where water resource regions with a greater fraction of available surface water withdrawn by hydropower or consumed by the energy sector correlated with higher probabilities of imperilment. Since future increases in energy-sector surface water use will occur

Energy, water and fish: biodiversity impacts of energy-sector water demand in the United States depend on efficiency and policy measures.

Directory of Open Access Journals (Sweden)

Robert I McDonald

Full Text Available Rising energy consumption in coming decades, combined with a changing energy mix, have the potential to increase the impact of energy sector water use on freshwater biodiversity. We forecast changes in future water use based on various energy scenarios and examine implications for freshwater ecosystems. Annual water withdrawn/manipulated would increase by 18-24%, going from 1,993,000-2,628,000 Mm(3 in 2010 to 2,359,000-3,271,000 Mm(3 in 2035 under the Reference Case of the Energy Information Administration (EIA. Water consumption would more rapidly increase by 26% due to increased biofuel production, going from 16,700-46,400 Mm(3 consumption in 2010 to 21,000-58,400 Mm(3 consumption in 2035. Regionally, water use in the Southwest and Southeast may increase, with anticipated decreases in water use in some areas of the Midwest and Northeast. Policies that promote energy efficiency or conservation in the electric sector would reduce water withdrawn/manipulated by 27-36 m(3GJ(-1 (0.1-0.5 m(3GJ(-1 consumption, while such policies in the liquid fuel sector would reduce withdrawal/manipulation by 0.4-0.7 m(3GJ(-1 (0.2-0.3 m(3GJ(-1 consumption. The greatest energy sector withdrawal/manipulation are for hydropower and thermoelectric cooling, although potential new EPA rules that would require recirculating cooling for thermoelectric plants would reduce withdrawal/manipulation by 441,000 Mm(3 (20,300 Mm(3 consumption. The greatest consumptive energy sector use is evaporation from hydroelectric reservoirs, followed by irrigation water for biofuel feedstocks and water used for electricity generation from coal. Historical water use by the energy sector is related to patterns of fish species endangerment, where water resource regions with a greater fraction of available surface water withdrawn by hydropower or consumed by the energy sector correlated with higher probabilities of imperilment. Since future increases in energy-sector surface water use will occur

Theoretical Study of Sodium-Water Surface Reaction Mechanism

Science.gov (United States)

Kikuchi, Shin; Kurihara, Akikazu; Ohshima, Hiroyuki; Hashimoto, Kenro

Computational study of the sodium-water reaction at the gas (water) - liquid (sodium) interface has been carried out using the ab initio (first-principle) method. A possible reaction channel has been identified for the stepwise OH bond dissociations of a single water molecule. The energetics including the binding energy of a water molecule on the sodium surface, the activation energies of the bond cleavages, and the reaction energies, have been evaluated, and the rate constants of the first and second OH bond-breakings have been compared. It was found that the estimated rate constant of the former was much larger than the latter. The results are the basis for constructing the chemical reaction model used in a multi-dimensional sodium-water reaction code, SERAPHIM, being developed by Japan Atomic Energy Agency (JAEA) toward the safety assessment of the steam generator (SG) in a sodium-cooled fast reactor (SFR).

Theoretical study of sodium-water surface reaction mechanism

International Nuclear Information System (INIS)

Kikuchi, Shin; Kurihara, Akikazu; Ohshima, Hiroyuki; Hashimoto, Kenro

2012-01-01

Computational study of the sodium-water reaction at the gas (water) - liquid (sodium) interface has been carried out using the ab initio (first-principle) method. A possible reaction channel has been identified for the stepwise OH bond dissociations of a single water molecule. The energetics including the binding energy of a water molecule on the sodium surface, the activation energies of the bond cleavages, and the reaction energies, have been evaluated, and the rate constants of the first and second OH bond-breakings have been compared. It was found that the estimated rate constant of the former was much larger than the latter. The results are the basis for constructing the chemical reaction model used in a multi-dimensional sodium-water reaction code, SERAPHIM, being developed by Japan Atomic Energy Agency (JAEA) toward the safety assessment of the steam generator (SG) in a sodium-cooled fast reactor (SFR). (author)

Water and Ethanol Droplet Wetting Transition during Evaporation on Omniphobic Surfaces

Science.gov (United States)

Chen, Xuemei; Weibel, Justin A.; Garimella, Suresh V.

2015-01-01

Omniphobic surfaces with reentrant microstructures have been investigated for a range of applications, but the evaporation of high- and low-surface-tension liquid droplets placed on such surfaces has not been rigorously studied. In this work, we develop a technique to fabricate omniphobic surfaces on copper substrates to allow for a systematic examination of the effects of surface topography on the evaporation dynamics of water and ethanol droplets. Compared to a water droplet, the ethanol droplet not only evaporates faster, but also inhibits Cassie-to-Wenzel wetting transitions on surfaces with certain geometries. We use an interfacial energy-based description of the system, including the transition energy barrier and triple line energy, to explain the underlying transition mechanism and behaviour observed. Suppression of the wetting transition during evaporation of droplets provides an important metric for evaluating the robustness of omniphobic surfaces requiring such functionality. PMID:26603940

Energy-Water Nexus | Energy Analysis | NREL

Science.gov (United States)

Nexus Energy-Water Nexus Water is required to produce energy. Energy is required to pump, treat , and transport water. The energy-water nexus examines the interactions between these two inextricably linked sectors. A cartoon showing the nexus of water and energy using red and blue arrows to indicate the

Adhesion Evaluation of Asphalt-Aggregate Interface Using Surface Free Energy Method

Directory of Open Access Journals (Sweden)

Jie Ji

2017-02-01

Full Text Available The influence of organic additives (Sasobit and RH and water on the adhesion of the asphalt-aggregate interface was studied according to the surface free energy theory. Two asphalt binders (SK-70 and SK-90, and two aggregate types (limestone and basalt were used in this study. The sessile drop method was employed to test surface free energy components of asphalt, organic additives and aggregates. The adhesion models of the asphalt-aggregate interface in dry and wet conditions were established, and the adhesion work was calculated subsequently. The energy ratios were built to evaluate the effect of organic additives and water on the adhesiveness of the asphalt-aggregate interface. The results indicate that the addition of organic additives can enhance the adhesion of the asphalt-aggregate interface in dry conditions, because organic additives reduced the surface free energy of asphalt. However, the organic additives have hydrophobic characteristics and are sensitive to water. As a result, the adhesiveness of the asphalt-aggregate interface of the asphalt containing organic additives in wet conditions sharply decreased due to water damage to asphalt and organic additives. Furthermore, the compatibility of asphalt, aggregate with organic additive was noted and discussed.

Utility of remote sensing-based surface energy balance models to track water stress in rain-fed switchgrass under dry and wet conditions

Science.gov (United States)

The ability of remote sensing-based surface energy balance (SEB) models to track water stress in rain-fed switchgrass has not been explored yet. In this paper, the theoretical framework of crop water stress index (CWSI) was utilized to estimate CWSI in rain-fed switchgrass (Panicum virgatum L.) usin...

Water on graphene surfaces

Energy Technology Data Exchange (ETDEWEB)

Gordillo, M C [Departamento de Sistemas Fisicos, Quimicos y Naturales, Facultad de Ciencias Experimentales, Universidad Pablo de Olavide, Carretera de Utrera, km 1, E-41013 Sevilla (Spain); Marti, J, E-mail: cgorbar@upo.e, E-mail: jordi.marti@upc.ed [Departament de Fisica i Enginyeria Nuclear, Universitat Politecnica de Catalunya, B4-B5 Campus Nord, E-08034 Barcelona, Catalonia (Spain)

2010-07-21

In this paper, we summarize the main results obtained in our group about the behavior of water confined inside or close to different graphene surfaces by means of molecular dynamics simulations. These include the inside and outside of carbon nanotubes, and the confinement inside a slit pore or a single graphene sheet. We paid special attention to some thermodynamical (binding energies), structural (hydrogen-bond distributions) and dynamic (infrared spectra) properties, and their comparison to their bulk counterparts.

Characterizing the potential energy surface of the water dimer with DFT: failures of some popular functionals for hydrogen bonding.

Science.gov (United States)

Anderson, Julie A; Tschumper, Gregory S

2006-06-08

Ten stationary points on the water dimer potential energy surface have been examined with ten density functional methods (X3LYP, B3LYP, B971, B98, MPWLYP, PBE1PBE, PBE, MPW1K, B3P86, and BHandHLYP). Geometry optimizations and vibrational frequency calculations were carried out with the TZ2P(f,d)+dif basis set. All ten of the density functionals correctly describe the relative energies of the ten stationary points. However, correctly describing the curvature of the potential energy surface is far more difficult. Only one functional (BHandHLYP) reproduces the number of imaginary frequencies from CCSD(T) calculations. The other nine density functionals fail to correctly characterize the nature of at least one of the ten (H(2)O)(2) stationary points studied here.

Improved Design Tools for Surface Water and Standing Column Well Heat Pump Systems (DE-EE0002961)

Energy Technology Data Exchange (ETDEWEB)

Spitler, J. D.; Culling, J. R.; Conjeevaram, K.; Ramesh, M.; Selvakumar, M.

2012-11-30

Ground-source heat pump (GSHP) systems are perhaps the most widely used “sustainable” heating and cooling systems, with an estimated 1.7 million installed units with total installed heating capacity on the order of 18 GW. They are widely used in residential, commercial, and institutional buildings. Standing column wells (SCW) are one form of ground heat exchanger that, under the right geological conditions, can provide excellent energy efficiency at a relatively low capital cost. Closed-loop surface water heat pump (SWHP) systems utilize surface water heat exchangers (SWHE) to reject or extract heat from nearby surface water bodies. For building near surface water bodies, these systems also offer a high degree of energy efficiency at a low capital cost. However, there have been few design tools available for properly sizing standing column wells or surface water heat exchangers. Nor have tools for analyzing the energy consumption and supporting economics-based design decisions been available. The main contributions of this project lie in providing new tools that support design and energy analysis. These include a design tool for sizing surface water heat exchangers, a design tool for sizing standing column wells, a new model of surface water heat pump systems implemented in EnergyPlus and a new model of standing column wells implemented in EnergyPlus. These tools will better help engineers design these systems and determine the economic and technical feasibility.

Utility of remote sensing-based surface energy balance models to track water stress in rain-fed switchgrass under dry and wet conditions

Science.gov (United States)

Bhattarai, Nishan; Wagle, Pradeep; Gowda, Prasanna H.; Kakani, Vijaya G.

2017-11-01

The ability of remote sensing-based surface energy balance (SEB) models to track water stress in rain-fed switchgrass (Panicum virgatum L.) has not been explored yet. In this paper, the theoretical framework of crop water stress index (CWSI; 0 = extremely wet or no water stress condition and 1 = extremely dry or no transpiration) was utilized to estimate CWSI in rain-fed switchgrass using Landsat-derived evapotranspiration (ET) from five remote sensing based single-source SEB models, namely Surface Energy Balance Algorithm for Land (SEBAL), Mapping ET with Internalized Calibration (METRIC), Surface Energy Balance System (SEBS), Simplified Surface Energy Balance Index (S-SEBI), and Operational Simplified Surface Energy Balance (SSEBop). CWSI estimates from the five SEB models and a simple regression model that used normalized difference vegetation index (NDVI), near-surface temperature difference, and measured soil moisture (SM) as covariates were compared with those derived from eddy covariance measured ET (CWSIEC) for the 32 Landsat image acquisition dates during the 2011 (dry) and 2013 (wet) growing seasons. Results indicate that most SEB models can predict CWSI reasonably well. For example, the root mean square error (RMSE) ranged from 0.14 (SEBAL) to 0.29 (SSEBop) and the coefficient of determination (R2) ranged from 0.25 (SSEBop) to 0.72 (SEBAL), justifying the added complexity in CWSI modeling as compared to results from the simple regression model (R2 = 0.55, RMSE = 0.16). All SEB models underestimated CWSI in the dry year but the estimates from SEBAL and S-SEBI were within 7% of the mean CWSIEC and explained over 60% of variations in CWSIEC. In the wet year, S-SEBI mostly overestimated CWSI (around 28%), while estimates from METRIC, SEBAL, SEBS, and SSEBop were within 8% of the mean CWSIEC. Overall, SEBAL was the most robust model under all conditions followed by METRIC, whose performance was slightly worse and better than SEBAL in dry and wet years

A study on the contact angles of a water droplet on smooth and rough solid surfaces

International Nuclear Information System (INIS)

Park, Ju Young; Ha, Man Yeong; Choi, Ho Jin; Hong, Seung Do; Yoon, Hyun Sik

2011-01-01

We investigated the wetting characteristics such as contact angle, wetting radius and topography of water droplets on smooth and random solid surfaces. Molecular dynamic simulation is employed to analyze the wetting behavior of water droplets on smooth and rough surfaces by considering different potential energy models of bond, angle, Lennard-Jones and Coulomb to calculate the interacting forces between water molecules. The Lennard-Jones potential energy model is adopted as an interaction model between water molecules and solid surface atoms. The randomly rough surface is generated by changing the standard deviation of roughness height from 1 A to 3 A with the fixed autocorrelation length. The size of water droplet considered is in the range from 2,000 to 5,000 molecules. The contact angles increase generally with increasing number of water molecules. For a hydrophobic surface whose characteristic energy is 0.1 kcal/mol, the contact angles depend rarely on the standard deviation of the roughness height. However, when the surface energy is 0.5 and 1.0 kcal/mol, the contact angles depend on both the roughness height of surfaces and droplet size

Sorption Energy Maps of Clay Mineral Surfaces

International Nuclear Information System (INIS)

Cygan, Randall T.; Kirkpatrick, R. James

1999-01-01

A molecular-level understanding of mineral-water interactions is critical for the evaluation and prediction of the sorption properties of clay minerals that may be used in various chemical and radioactive waste disposal methods. Molecular models of metal sorption incorporate empirical energy force fields, based on molecular orbital calculations and spectroscopic data, that account for Coulombic, van der Waals attractive, and short-range repulsive energies. The summation of the non-bonded energy terms at equally-spaced grid points surrounding a mineral substrate provides a three dimensional potential energy grid. The energy map can be used to determine the optimal sorption sites of metal ions on the exposed surfaces of the mineral. By using this approach, we have evaluated the crystallographic and compositional control of metal sorption on the surfaces of kaolinite and illite. Estimates of the relative sorption energy and most stable sorption sites are derived based on a rigid ion approximation

Estimation of Key Parameters of the Coupled Energy and Water Model by Assimilating Land Surface Data

Science.gov (United States)

Abdolghafoorian, A.; Farhadi, L.

2017-12-01

Accurate estimation of land surface heat and moisture fluxes, as well as root zone soil moisture, is crucial in various hydrological, meteorological, and agricultural applications. Field measurements of these fluxes are costly and cannot be readily scaled to large areas relevant to weather and climate studies. Therefore, there is a need for techniques to make quantitative estimates of heat and moisture fluxes using land surface state observations that are widely available from remote sensing across a range of scale. In this work, we applies the variational data assimilation approach to estimate land surface fluxes and soil moisture profile from the implicit information contained Land Surface Temperature (LST) and Soil Moisture (SM) (hereafter the VDA model). The VDA model is focused on the estimation of three key parameters: 1- neutral bulk heat transfer coefficient (CHN), 2- evaporative fraction from soil and canopy (EF), and 3- saturated hydraulic conductivity (Ksat). CHN and EF regulate the partitioning of available energy between sensible and latent heat fluxes. Ksat is one of the main parameters used in determining infiltration, runoff, groundwater recharge, and in simulating hydrological processes. In this study, a system of coupled parsimonious energy and water model will constrain the estimation of three unknown parameters in the VDA model. The profile of SM (LST) at multiple depths is estimated using moisture diffusion (heat diffusion) equation. In this study, the uncertainties of retrieved unknown parameters and fluxes are estimated from the inverse of Hesian matrix of cost function which is computed using the Lagrangian methodology. Analysis of uncertainty provides valuable information about the accuracy of estimated parameters and their correlation and guide the formulation of a well-posed estimation problem. The results of proposed algorithm are validated with a series of experiments using a synthetic data set generated by the simultaneous heat and

Simulation and analysis on thermodynamic performance of surface water source heat pump system

Institute of Scientific and Technical Information of China (English)

Nan Lv; Qing Zhang; Zhenqian Chen; Dongsheng Wu

2017-01-01

This work established a thermodynamic performance model of a heat pump system containing a heat pump unit model, an air conditioning cooling and heating load calculation model, a heat exchanger model and a water pump performance model based on mass and energy balances. The thermodynamic performance of a surface water source heat pump air conditioning system was simulated and verified by comparing the simulation results to an actual engineering project. In addition, the effects of the surface water temperature, heat exchanger structure and surface water pipeline transportation system on the thermodynamic performance of the heat pump air conditioning system were analyzed. Under the simulated conditions in this paper with a cooling load of 3400 kW, the results showed that a 1 ℃ decrease in the surface water temperature leads to a 2.3 percent increase in the coefficient of performance; furthermore, an additional 100 m of length for the closed-loop surface water heat exchanger tube leads to a 0.08 percent increase in the coefficient of performance. To decrease the system energy consumption, the optimal working point should be specified according to the surface water transportation length.

Reconnoitering the effect of shallow groundwater on land surface temperature and surface energy balance using MODIS and SEBS

Directory of Open Access Journals (Sweden)

F. Alkhaier

2012-07-01

Full Text Available The possibility of observing shallow groundwater depth and areal extent using satellite measurements can support groundwater models and vast irrigation systems management. Moreover, these measurements can help to include the effect of shallow groundwater on surface energy balance within land surface models and climate studies, which broadens the methods that yield more reliable and informative results. To examine the capacity of MODIS in detecting the effect of shallow groundwater on land surface temperature and the surface energy balance in an area within Al-Balikh River basin in northern Syria, we studied the interrelationship between in-situ measured water table depths and land surface temperatures measured by MODIS. We, also, used the Surface Energy Balance System (SEBS to calculate surface energy fluxes, evaporative fraction and daily evaporation, and inspected their relationships with water table depths. We found out that the daytime temperature increased while the nighttime temperature decreased when the depth of the water table increased. And, when the water table depth increased, net radiation, latent and ground heat fluxes, evaporative fraction and daily evaporation decreased, while sensible heat flux increased. This concords with the findings of a companion paper (Alkhaier et al., 2012. The observed clear relationships were the result of meeting both conditions that were concluded in the companion paper, i.e. high potential evaporation and big contrast in day-night temperature. Moreover, the prevailing conditions in this study area helped SEBS to yield accurate estimates. Under bare soil conditions and under the prevailing weather conditions, we conclude that MODIS is suitable for detecting the effect of shallow groundwater because it has proper imaging times and adequate sensor accuracy; nevertheless, its coarse spatial resolution is disadvantageous.

Insight into Chemistry on Cloud/Aerosol Water Surfaces.

Science.gov (United States)

Zhong, Jie; Kumar, Manoj; Francisco, Joseph S; Zeng, Xiao Cheng

2018-05-15

, whereas on a water surface, the HNO 3 -mediated stepwise hydration of anti-CH 3 CHOO is dominantly observed. The high surface/volume ratio of interfacial water molecules at the aerosol water surface can significantly lower the energy barriers for the proton transfer reactions in the atmosphere. Such catalysis by the aerosol water surface is shown to cause the barrier-less formation of ammonium bisulfate from hydrated NH 3 and SO 3 molecules rather than from the reaction of H 2 SO 4 with NH 3 . Finally, an aerosol water droplet is a polar solvent, which would favorably interact with high polarity substrates. This can accelerate interconversion of different conformers (e.g., anti and syn) of atmospheric species, such as glyoxal, depending on their polarity. The results discussed here enable an improved understanding of atmospheric processes on the aerosol water surface.

GCIP water and energy budget synthesis (WEBS)

Science.gov (United States)

Roads, J.; Lawford, R.; Bainto, E.; Berbery, E.; Chen, S.; Fekete, B.; Gallo, K.; Grundstein, A.; Higgins, W.; Kanamitsu, M.; Krajewski, W.; Lakshmi, V.; Leathers, D.; Lettenmaier, D.; Luo, L.; Maurer, E.; Meyers, T.; Miller, D.; Mitchell, Ken; Mote, T.; Pinker, R.; Reichler, T.; Robinson, D.; Robock, A.; Smith, J.; Srinivasan, G.; Verdin, K.; Vinnikov, K.; Vonder, Haar T.; Vorosmarty, C.; Williams, S.; Yarosh, E.

2003-01-01

As part of the World Climate Research Program's (WCRPs) Global Energy and Water-Cycle Experiment (GEWEX) Continental-scale International Project (GCIP), a preliminary water and energy budget synthesis (WEBS) was developed for the period 1996-1999 fromthe "best available" observations and models. Besides this summary paper, a companion CD-ROM with more extensive discussion, figures, tables, and raw data is available to the interested researcher from the GEWEX project office, the GAPP project office, or the first author. An updated online version of the CD-ROM is also available at http://ecpc.ucsd.edu/gcip/webs.htm/. Observations cannot adequately characterize or "close" budgets since too many fundamental processes are missing. Models that properly represent the many complicated atmospheric and near-surface interactions are also required. This preliminary synthesis therefore included a representative global general circulation model, regional climate model, and a macroscale hydrologic model as well as a global reanalysis and a regional analysis. By the qualitative agreement among the models and available observations, it did appear that we now qualitatively understand water and energy budgets of the Mississippi River Basin. However, there is still much quantitative uncertainty. In that regard, there did appear to be a clear advantage to using a regional analysis over a global analysis or a regional simulation over a global simulation to describe the Mississippi River Basin water and energy budgets. There also appeared to be some advantage to using a macroscale hydrologic model for at least the surface water budgets. Copyright 2003 by the American Geophysical Union.

Surface Water & Surface Drainage

Data.gov (United States)

Earth Data Analysis Center, University of New Mexico — This data set contains boundaries for all surface water and surface drainage for the state of New Mexico. It is in a vector digital data structure digitized from a...

Comparison of surface energy fluxes with satellite-derived surface energy flux estimates from a shrub-steppe

International Nuclear Information System (INIS)

Kirkham, R.R.

1993-12-01

This thesis relates the components of the surface energy balance (i.e., net radiation, sensible and latent heat flux densities, soil heat flow) to remotely sensed data for native vegetation in a semi-arid environment. Thematic mapper data from Landsat 4 and 5 were used to estimate net radiation, sensible heat flux (H), and vegetation amount. Several sources of ground truth were employed. They included soil water balance using the neutron thermalization method and weighing lysimeters, and the measurement of energy fluxes with the Bowen ratio energy balance (BREB) technique. Sensible and latent heat flux were measured at four sites on the U.S. Department of Energy's Hanford Site using a weighing lysimeter and/or BREB stations. The objective was to calibrate an aerodynamic transport equation that related H to radiant surface temperature. The transport equation was then used with Landsat thermal data to generate estimates of H and compare these estimates against H values obtained with BREB/lysimeters at the time of overflight. Landsat and surface meteorologic data were used to estimate the radiation budget terms at the surface. Landsat estimates of short-wave radiation reflected from the surface correlate well with reflected radiation measured using inverted Eppley pyranometers. Correlation of net radiation estimates determined from satellite data, pyranometer, air temperature, and vapor pressure compared to net radiometer values obtained at time of overflight were excellent for a single image, but decrease for multiple images. Soil heat flux, G T , is a major component of the energy balance in arid systems and G T generally decreases as vegetation cover increases. Normalized difference vegetation index (NDVI) values generated from Landsat thermatic mapper data were representative of field observations of the presence of green vegetation, but it was not possible to determine a single relationship between NDVI and G T for all sites

The study of dynamic force acted on water strider leg departing from water surface

Science.gov (United States)

Sun, Peiyuan; Zhao, Meirong; Jiang, Jile; Zheng, Yelong

2018-01-01

Water-walking insects such as water striders can skate on the water surface easily with the help of the hierarchical structure on legs. Numerous theoretical and experimental studies show that the hierarchical structure would help water strider in quasi-static case such as load-bearing capacity. However, the advantage of the hierarchical structure in the dynamic stage has not been reported yet. In this paper, the function of super hydrophobicity and the hierarchical structure was investigated by measuring the adhesion force of legs departing from the water surface at different lifting speed by a dynamic force sensor. The results show that the adhesion force decreased with the increase of lifting speed from 0.02 m/s to 0.4 m/s, whose mechanic is investigated by Energy analysis. In addition, it can be found that the needle shape setae on water strider leg can help them depart from water surface easily. Thus, it can serve as a starting point to understand how the hierarchical structure on the legs help water-walking insects to jump upward rapidly to avoid preying by other insects.

Electrolysis of water on (oxidized) metal surfaces

DEFF Research Database (Denmark)

Rossmeisl, Jan; Logadottir, Ashildur; Nørskov, Jens Kehlet

2005-01-01

Density functional theory calculations are used as the basis for an analysis of the electrochemical process, where by water is split to form molecular oxygen and hydrogen. We develop a method for obtaining the thermochemistry of the electrochemical water splitting process as a function of the bias...... directly from the electronic structure calculations. We consider electrodes of Pt(111) and Au(111) in detail and then discuss trends for a series of different metals. We show that the difficult step in the water splitting process is the formation of superoxy-type (OOH) species on the surface...... by the splitting of a water molecule on top an adsorbed oxygen atom. One conclusion is that this is only possible on metal surfaces that are (partly) oxidized. We show that the binding energies of the different intermediates are linearly correlated for a number of metals. In a simple analysis, where the linear...

A transitioning Arctic surface energy budget: the impacts of solar zenith angle, surface albedo and cloud radiative forcing

Energy Technology Data Exchange (ETDEWEB)

Sedlar, Joseph; Tjernstroem, Michael; Leck, Caroline [Stockholm University, Department of Meteorology, Stockholm (Sweden); Mauritsen, Thorsten [Max-Planck-Institute for Meteorology, Hamburg (Germany); Shupe, Matthew D.; Persson, P.O.G. [University of Colorado, NOAA-ESRL-PSD, Boulder, CO (United States); Brooks, Ian M.; Birch, Cathryn E. [University of Leeds, School of Earth and Environment, Leeds (United Kingdom); Sirevaag, Anders [University of Bergen, Bjerknes Center for Climate Research, Bergen (Norway); Nicolaus, Marcel [Norwegian Polar Institute, Tromsoe (Norway); Alfred Wegener Institute for Polar and Marine Research, Bremerhaven (Germany)

2011-10-15

Snow surface and sea-ice energy budgets were measured near 87.5 N during the Arctic Summer Cloud Ocean Study (ASCOS), from August to early September 2008. Surface temperature indicated four distinct temperature regimes, characterized by varying cloud, thermodynamic and solar properties. An initial warm, melt-season regime was interrupted by a 3-day cold regime where temperatures dropped from near zero to -7 C. Subsequently mean energy budget residuals remained small and near zero for 1 week until once again temperatures dropped rapidly and the energy budget residuals became negative. Energy budget transitions were dominated by the net radiative fluxes, largely controlled by the cloudiness. Variable heat, moisture and cloud distributions were associated with changing air-masses. Surface cloud radiative forcing, the net radiative effect of clouds on the surface relative to clear skies, is estimated. Shortwave cloud forcing ranged between -50 W m{sup -2} and zero and varied significantly with surface albedo, solar zenith angle and cloud liquid water. Longwave cloud forcing was larger and generally ranged between 65 and 85 W m{sup -2}, except when the cloud fraction was tenuous or contained little liquid water; thus the net effect of the clouds was to warm the surface. Both cold periods occurred under tenuous, or altogether absent, low-level clouds containing little liquid water, effectively reducing the cloud greenhouse effect. Freeze-up progression was enhanced by a combination of increasing solar zenith angles and surface albedo, while inhibited by a large, positive surface cloud forcing until a new air-mass with considerably less cloudiness advected over the experiment area. (orig.)

Tracking Water-Use in Colorado's Energy Exploration and Development

Science.gov (United States)

Halamka, T. A.; Ge, S.

2017-12-01

By the year 2050 Colorado's population is projected to nearly double, posing many important questions about the stresses that Colorado's water resources will experience. Growing in tandem with Colorado's population is the state's energy exploration and development industry. As water demands increase across the state, the energy exploration and development industry must adapt to and prepare for future difficulties surrounding the legal acquisition of water. The goal of this study is to map out the potential sources of water within the state of Colorado that are being purchased, or will be eligible for purchase, for unconventional subsurface energy extraction. The background of this study includes an overview of the intertwined relationship between water, the energy industry, and the Colorado economy. The project also aims to determine the original purpose of legally appropriated water that is used in Colorado's energy exploration and development. Is the water primarily being purchased or leased from the agricultural sector? Is the water mostly surface water or groundwater? In order to answer these questions, we accessed data from numerous water reporting agencies and examined legal methods of acquisition of water for use in the energy industry. Using these data, we assess the future water quantity available to the energy industry. Knowledge and foresight on the origins of the water used by the energy industry will allow for better and strategic planning of water resources and how the industry will respond to statewide water-related stresses.

The Character of the Solar Wind, Surface Interactions, and Water

Science.gov (United States)

Farrell, William M.

2011-01-01

We discuss the key characteristics of the proton-rich solar wind and describe how it may interact with the lunar surface. We suggest that solar wind can be both a source and loss of water/OH related volatiles, and review models showing both possibilities. Energy from the Sun in the form of radiation and solar wind plasma are in constant interaction with the lunar surface. As such, there is a solar-lunar energy connection, where solar energy and matter are continually bombarding the lunar surface, acting at the largest scale to erode the surface at 0.2 Angstroms per year via ion sputtering [1]. Figure 1 illustrates this dynamically Sun-Moon system.

Thermal desorption of formamide and methylamine from graphite and amorphous water ice surfaces

Science.gov (United States)

Chaabouni, H.; Diana, S.; Nguyen, T.; Dulieu, F.

2018-04-01

Context. Formamide (NH2CHO) and methylamine (CH3NH2) are known to be the most abundant amine-containing molecules in many astrophysical environments. The presence of these molecules in the gas phase may result from thermal desorption of interstellar ices. Aims: The aim of this work is to determine the values of the desorption energies of formamide and methylamine from analogues of interstellar dust grain surfaces and to understand their interaction with water ice. Methods: Temperature programmed desorption (TPD) experiments of formamide and methylamine ices were performed in the sub-monolayer and monolayer regimes on graphite (HOPG) and non-porous amorphous solid water (np-ASW) ice surfaces at temperatures 40-240 K. The desorption energy distributions of these two molecules were calculated from TPD measurements using a set of independent Polanyi-Wigner equations. Results: The maximum of the desorption of formamide from both graphite and ASW ice surfaces occurs at 176 K after the desorption of H2O molecules, whereas the desorption profile of methylamine depends strongly on the substrate. Solid methylamine starts to desorb below 100 K from the graphite surface. Its desorption from the water ice surface occurs after 120 K and stops during the water ice sublimation around 150 K. It continues to desorb from the graphite surface at temperatures higher than160 K. Conclusions: More than 95% of solid NH2CHO diffuses through the np-ASW ice surface towards the graphitic substrate and is released into the gas phase with a desorption energy distribution Edes = 7460-9380 K, which is measured with the best-fit pre-exponential factor A = 1018 s-1. However, the desorption energy distribution of methylamine from the np-ASW ice surface (Edes = 3850-8420 K) is measured with the best-fit pre-exponential factor A = 1012 s-1. A fraction of solid methylamine monolayer of roughly 0.15 diffuses through the water ice surface towards the HOPG substrate. This small amount of methylamine

Mechanical Balance Laws for Boussinesq Models of Surface Water Waves

Science.gov (United States)

Ali, Alfatih; Kalisch, Henrik

2012-06-01

Depth-integrated long-wave models, such as the shallow-water and Boussinesq equations, are standard fare in the study of small amplitude surface waves in shallow water. While the shallow-water theory features conservation of mass, momentum and energy for smooth solutions, mechanical balance equations are not widely used in Boussinesq scaling, and it appears that the expressions for many of these quantities are not known. This work presents a systematic derivation of mass, momentum and energy densities and fluxes associated with a general family of Boussinesq systems. The derivation is based on a reconstruction of the velocity field and the pressure in the fluid column below the free surface, and the derivation of differential balance equations which are of the same asymptotic validity as the evolution equations. It is shown that all these mechanical quantities can be expressed in terms of the principal dependent variables of the Boussinesq system: the surface excursion η and the horizontal velocity w at a given level in the fluid.

Green Approach to the Fabrication of Superhydrophobic Mesh Surface for Oil/Water Separation.

Science.gov (United States)

Wang, Fajun; Lei, Sheng; Xu, Yao; Ou, Junfei

2015-07-20

We report a simple and environment friendly method to fabricate superhydrophobic metallic mesh surfaces for oil/water separation. The obtained mesh surface exhibits superhydrophobicity and superoleophilicity after it was dried in an oven at 200 °C for 10 min. A rough silver layer is formed on the mesh surface after immersion, and the spontaneous adsorption of airborne carbon contaminants on the silver surface lower the surface free energy of the mesh. No low-surface-energy reagents and/or volatile organic solvents are used. In addition, we demonstrate that by using the mesh box, oils can be separated and collected from the surface of water repeatedly, and that high separation efficiencies of larger than 92 % are retained for various oils. Moreover, the superhydrophobic mesh also possesses excellent corrosion resistance and thermal stability. Hence, these superhydrophobic meshes might be good candidates for the practical separation of oil from the surface of water. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Mapping land water and energy balance relations through conditional sampling of remote sensing estimates of atmospheric forcing and surface states

Science.gov (United States)

Farhadi, Leila; Entekhabi, Dara; Salvucci, Guido

2016-04-01

In this study, we develop and apply a mapping estimation capability for key unknown parameters that link the surface water and energy balance equations. The method is applied to the Gourma region in West Africa. The accuracy of the estimation method at point scale was previously examined using flux tower data. In this study, the capability is scaled to be applicable with remotely sensed data products and hence allow mapping. Parameters of the system are estimated through a process that links atmospheric forcing (precipitation and incident radiation), surface states, and unknown parameters. Based on conditional averaging of land surface temperature and moisture states, respectively, a single objective function is posed that measures moisture and temperature-dependent errors solely in terms of observed forcings and surface states. This objective function is minimized with respect to parameters to identify evapotranspiration and drainage models and estimate water and energy balance flux components. The uncertainty of the estimated parameters (and associated statistical confidence limits) is obtained through the inverse of Hessian of the objective function, which is an approximation of the covariance matrix. This calibration-free method is applied to the mesoscale region of Gourma in West Africa using multiplatform remote sensing data. The retrievals are verified against tower-flux field site data and physiographic characteristics of the region. The focus is to find the functional form of the evaporative fraction dependence on soil moisture, a key closure function for surface and subsurface heat and moisture dynamics, using remote sensing data.

Surface Energy and Setting Process of Contacting Surfaces

Directory of Open Access Journals (Sweden)

M. V. Musokhranov

2014-01-01

Full Text Available The paper deals with a challenge in terms of ensuring an accuracy of the relative position of the conjugated surfaces that is to determine a coefficient of friction. To solve it, there is a proposal to use the surface energy, as a tool that influences the contacting parts nature. Presently, energy of the surface layers at best is only stated, but not used in practice.Analysis of the conditions of interaction between two contacting surfaces, such as seizing and setting cannot be explained only from the position of the roughness parameters. It is found that these phenomena are explained by the appearing gripe (setting bridges, which result from the energy of interaction between two or more adjacent surfaces. The emerging phenomenon such as micro welding, i.e. occurring bonds, is caused by the overflow of energy, according to the theory of physics, from the surface with a high level of energy to the surface with the smaller one to balance the system as a whole.The paper shows that through the use of process, controlling the depth of the surface layer and creating a certain structure, the energy level of the material as a whole can be specified. And this will allow us to provide the necessary performance and mechanical properties. It means to create as many gripe bridges as possible to ensure continuous positioning i.e. a fixed connection of the contacting surfaces.It was determined that to increase a value of the friction coefficient, the physical and mechanical properties of the surface layer of the parts material must be taken into account, namely, in the part body accumulate the energy to be consumed for forming the surface.The paper gives recommendations for including the parts of the surface energy in the qualitative indicators of characteristics. This will make a technologist, when routing a process, to choose such operations and modes to provide the designer-specified parameters not only of the accuracy and surface finish, but also of the

Surface-water surveillance

Energy Technology Data Exchange (ETDEWEB)

Saldi, K.A.; Dirkes, R.L.; Blanton, M.L.

1995-06-01

This section of the 1994 Hanford Site Environmental Report summarizes the Surface water on and near the Hanford Site is monitored to determine the potential effects of Hanford operations. Surface water at Hanford includes the Columbia River, riverbank springs, ponds located on the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site. Columbia River sediments are also included in this discussion. Tables 5.3.1 and 5.3.2 summarize the sampling locations, sample types, sampling frequencies, and sample analyses included in surface-water surveillance activities during 1994. Sample locations are also identified in Figure 5.3.1. This section describes the surveillance effort and summarizes the results for these aquatic environments. Detailed analytical results are reported by Bisping (1995).

Surface-water surveillance

International Nuclear Information System (INIS)

Saldi, K.A.; Dirkes, R.L.; Blanton, M.L.

1995-01-01

This section of the 1994 Hanford Site Environmental Report summarizes the Surface water on and near the Hanford Site is monitored to determine the potential effects of Hanford operations. Surface water at Hanford includes the Columbia River, riverbank springs, ponds located on the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site. Columbia River sediments are also included in this discussion. Tables 5.3.1 and 5.3.2 summarize the sampling locations, sample types, sampling frequencies, and sample analyses included in surface-water surveillance activities during 1994. Sample locations are also identified in Figure 5.3.1. This section describes the surveillance effort and summarizes the results for these aquatic environments. Detailed analytical results are reported by Bisping (1995)

Hydrogen evolution from water using solid carbon and light energy

Energy Technology Data Exchange (ETDEWEB)

Kawai, T; Sakata, T

1979-11-15

Hydrogen is produced from water vapour and solid carbon when mixed powders of TiO2, RuO2 and active carbon exposed to water vapor at room temperature, or up to 80 C, are illuminated. At 80 C, the rate of CO and COat2 formation increased. Therefore solar energy would be useful here as a combination of light energy and heat energy. Oxygen produced on the surface of the photocatalyst has a strong oxidising effect on the carbon. It is suggested that this process could be used for coal gasification and hydrogen production from water, accompanied by storage of solar energy.

Comparison of Degrees of Potential-Energy-Surface Anharmonicity for Complexes and Clusters with Hydrogen Bonds

Science.gov (United States)

Kozlovskaya, E. N.; Doroshenko, I. Yu.; Pogorelov, V. E.; Vaskivskyi, Ye. V.; Pitsevich, G. A.

2018-01-01

Previously calculated multidimensional potential-energy surfaces of the MeOH monomer and dimer, water dimer, malonaldehyde, formic acid dimer, free pyridine-N-oxide/trichloroacetic acid complex, and protonated water dimer were analyzed. The corresponding harmonic potential-energy surfaces near the global minima were constructed for series of clusters and complexes with hydrogen bonds of different strengths based on the behavior of the calculated multidimensional potential-energy surfaces. This enabled the introduction of an obvious anharmonicity parameter for the calculated potential-energy surfaces. The anharmonicity parameter was analyzed as functions of the size of the analyzed area near the energy minimum, the number of points over which energies were compared, and the dimensionality of the solved vibrational problem. Anharmonicity parameters for potential-energy surfaces in complexes with strong, medium, and weak H-bonds were calculated under identical conditions. The obtained anharmonicity parameters were compared with the corresponding diagonal anharmonicity constants for stretching vibrations of the bridging protons and the lengths of the hydrogen bridges.

Water at surfaces with tunable surface chemistries

Science.gov (United States)

Sanders, Stephanie E.; Vanselous, Heather; Petersen, Poul B.

2018-03-01

Aqueous interfaces are ubiquitous in natural environments, spanning atmospheric, geological, oceanographic, and biological systems, as well as in technical applications, such as fuel cells and membrane filtration. Where liquid water terminates at a surface, an interfacial region is formed, which exhibits distinct properties from the bulk aqueous phase. The unique properties of water are governed by the hydrogen-bonded network. The chemical and physical properties of the surface dictate the boundary conditions of the bulk hydrogen-bonded network and thus the interfacial properties of the water and any molecules in that region. Understanding the properties of interfacial water requires systematically characterizing the structure and dynamics of interfacial water as a function of the surface chemistry. In this review, we focus on the use of experimental surface-specific spectroscopic methods to understand the properties of interfacial water as a function of surface chemistry. Investigations of the air-water interface, as well as efforts in tuning the properties of the air-water interface by adding solutes or surfactants, are briefly discussed. Buried aqueous interfaces can be accessed with careful selection of spectroscopic technique and sample configuration, further expanding the range of chemical environments that can be probed, including solid inorganic materials, polymers, and water immiscible liquids. Solid substrates can be finely tuned by functionalization with self-assembled monolayers, polymers, or biomolecules. These variables provide a platform for systematically tuning the chemical nature of the interface and examining the resulting water structure. Finally, time-resolved methods to probe the dynamics of interfacial water are briefly summarized before discussing the current status and future directions in studying the structure and dynamics of interfacial water.

Surface freezing of water

OpenAIRE

P?rez-D?az, J. L.; ?lvarez-Valenzuela, M. A.; Rodr?guez-Celis, F.

2016-01-01

Freezing, melting, evaporation and condensation of water are essential ingredients for climate and eventually life on Earth. In the present work, we show how surface freezing of supercooled water in an open container is conditioned and triggered?exclusively?by humidity in air. Additionally, a change of phase is demonstrated to be triggered on the water surface forming surface ice crystals prior to freezing of bulk. The symmetry of the surface crystal, as well as the freezing point, depend on ...

The study of dynamic force acted on water strider leg departing from water surface

Directory of Open Access Journals (Sweden)

Peiyuan Sun

2018-01-01

Full Text Available Water-walking insects such as water striders can skate on the water surface easily with the help of the hierarchical structure on legs. Numerous theoretical and experimental studies show that the hierarchical structure would help water strider in quasi-static case such as load-bearing capacity. However, the advantage of the hierarchical structure in the dynamic stage has not been reported yet. In this paper, the function of super hydrophobicity and the hierarchical structure was investigated by measuring the adhesion force of legs departing from the water surface at different lifting speed by a dynamic force sensor. The results show that the adhesion force decreased with the increase of lifting speed from 0.02 m/s to 0.4 m/s, whose mechanic is investigated by Energy analysis. In addition, it can be found that the needle shape setae on water strider leg can help them depart from water surface easily. Thus, it can serve as a starting point to understand how the hierarchical structure on the legs help water-walking insects to jump upward rapidly to avoid preying by other insects.

Energy-Water System Solutions | Energy Analysis | NREL

Science.gov (United States)

System Solutions Energy-Water System Solutions NREL has been a pioneer in the development of energy -water system solutions that explicitly address and optimize energy-water tradeoffs. NREL has evaluated energy-water system solutions for Department of Defense bases, islands, communities recovering from

Adsorption of methanol, ethanol and water on well-characterized PtSn surface alloys

Science.gov (United States)

Panja, Chameli; Saliba, Najat; Koel, Bruce E.

1998-01-01

Adsorption and desorption of methanol (CH 3OH), ethanol (C 2H 5OH) and water on Pt(111) and two, ordered, PtSn alloys has been studied primarily using temperature-programmed desorption (TPD) mass spectroscopy. The two alloys studied were the {p(2 × 2) Sn}/{Pt(111) } and (√3 × √3) R30° {Sn}/{Pt(111) } surface alloys prepared by vapor deposition of Sn on Pt(111), with θSn = 0.25 and 0.33, respectively. All three molecules are weakly bonded and reversibly adsorbed under UHV conditions on all three surfaces, molecularly desorbing during TPD without any decomposition. The two PtSn surface alloys were found to chemisorb both methanol and ethanol slightly more weakly than on the Pt(111) surface. The desorption activation energies measured by TPD, and hence the adsorption energies, of both methanol and ethanol progressively decrease as the surface concentration of Sn increases, compared with Pt(111). The decreased binding energy leads one to expect a lower reactivity for these alcohols on the two alloys. The sticking coefficients and the monolayer coverages of these alcohols on the two alloys were identical to that on Pt(111) at 100 K, independent of the amount of Sn present in the surface layer. Alloying Sn in Pt(111) also slightly weakens the adsorption energy of water. Water clusters are formed even at low coverages on all three surfaces, eventually forming a water bilayer prior to the formation of a condensed ice phase. These results are relevant to a molecular-level explanation for the reactivity of Sn-promoted Pt surfaces that have been used in the electro-oxidation of simple organic molecules.

Enhanced load-carrying capacity of hairy surfaces floating on water.

Science.gov (United States)

Xue, Yahui; Yuan, Huijing; Su, Weidong; Shi, Yipeng; Duan, Huiling

2014-05-08

Water repellency of hairy surfaces depends on the geometric arrangement of these hairs and enables different applications in both nature and engineering. We investigate the mechanism and optimization of a hairy surface floating on water to obtain its maximum load-carrying capacity by the free energy and force analyses. It is demonstrated that there is an optimum cylinder spacing, as a result of the compromise between the vertical capillary force and the gravity, so that the hairy surface has both high load-carrying capacity and mechanical stability. Our analysis makes it clear that the setae on water striders' legs or some insects' wings are in such an optimized geometry. Moreover, it is shown that surface hydrophobicity can further increase the capacity of a hairy surface with thick cylinders, while the influence is negligible when the cylinders are thin.

Projected energy and water consumption of Pacific Northwest irrigation systems

Energy Technology Data Exchange (ETDEWEB)

King, L. D.; Hellickson, M. L.; Schmisseur, W. E.; Shearer, M. N.

1978-10-01

A computer model has been developed to predict present and future regional water, energy, labor, and capital requirements of irrigated agricultural production in Idaho, Oregon, and Washington. The energy requirements calculated were on-farm pumping, and total energies. Total energies are the combined energies of on-farm pumping, manufacture, and installation. Irrigation system selections and modifications were based on an economic analysis utilizing the following input parameters: water, energy, labor, and capital costs and requirements; groundwater and surface water pumping lifts; improved application efficiencies; and pumping plant efficiencies. Major conclusions and implications of this analysis indicate that: as water application efficiencies increases additional quantities of water will not become available to other users; an overall increase in water application efficiencies resulted in decreases in gross water applications and increases in overall on-farm pumping and total energy consumptions; more energy will be consumed as pumping and total energies than will be conserved through decreased diversion pumping energy requirements; pump-back and similar technologies have the potential of both increasing application efficiencies and energy conservation; and the interrelationships understood between applying water in quantities greater than required for crop consumptive use and leaching, and late season in-steam flow augmentation and/or aquifer recharge are not well understood, and sound policy decisions concerning agricultural use of water and energy cannot be made until these interrelationships are better understood.

Microclimatic models. Estimation of components of the energy balance over land surfaces

Energy Technology Data Exchange (ETDEWEB)

Heikinheimo, M; Venaelaeinen, A; Tourula, T [Finnish Meteorological Inst., Helsinki (Finland). Air Quality Dept.

1997-12-31

Climates at regional scale are strongly dependent on the interaction between atmosphere and its lower boundary, the oceans and the land surface mosaic. Land surfaces influence climate through their albedo, and the aerodynamic roughness, the processes of the biosphere and many soil hydrological properties; all these factors vary considerably geographically. Land surfaces receive a certain portion of the solar irradiance depending on the cloudiness, atmospheric transparency and surface albedo. Short-wave solar irradiance is the source of the heat energy exchange at the earth`s surface and also regulates many biological processes, e.g. photosynthesis. Methods for estimating solar irradiance, atmospheric transparency and surface albedo were reviewed during the course of this project. The solar energy at earth`s surface is consumed for heating the soil and the lower atmosphere. Where moisture is available, evaporation is one of the key components of the surface energy balance, because the conversion of liquid water into water vapour consumes heat. The evaporation process was studied by carrying out field experiments and testing parameterisation for a cultivated agricultural surface and for lakes. The micrometeorological study over lakes was carried out as part of the international `Northern Hemisphere Climatic Processes Experiment` (NOPEX/BAHC) in Sweden. These studies have been aimed at a better understanding of the energy exchange processes of the earth`s surface-atmosphere boundary for a more accurate and realistic parameterisation of the land surface in atmospheric models

Microclimatic models. Estimation of components of the energy balance over land surfaces

Energy Technology Data Exchange (ETDEWEB)

Heikinheimo, M.; Venaelaeinen, A.; Tourula, T. [Finnish Meteorological Inst., Helsinki (Finland). Air Quality Dept.

1996-12-31

Climates at regional scale are strongly dependent on the interaction between atmosphere and its lower boundary, the oceans and the land surface mosaic. Land surfaces influence climate through their albedo, and the aerodynamic roughness, the processes of the biosphere and many soil hydrological properties; all these factors vary considerably geographically. Land surfaces receive a certain portion of the solar irradiance depending on the cloudiness, atmospheric transparency and surface albedo. Short-wave solar irradiance is the source of the heat energy exchange at the earth`s surface and also regulates many biological processes, e.g. photosynthesis. Methods for estimating solar irradiance, atmospheric transparency and surface albedo were reviewed during the course of this project. The solar energy at earth`s surface is consumed for heating the soil and the lower atmosphere. Where moisture is available, evaporation is one of the key components of the surface energy balance, because the conversion of liquid water into water vapour consumes heat. The evaporation process was studied by carrying out field experiments and testing parameterisation for a cultivated agricultural surface and for lakes. The micrometeorological study over lakes was carried out as part of the international `Northern Hemisphere Climatic Processes Experiment` (NOPEX/BAHC) in Sweden. These studies have been aimed at a better understanding of the energy exchange processes of the earth`s surface-atmosphere boundary for a more accurate and realistic parameterisation of the land surface in atmospheric models

Surface freezing of water.

Science.gov (United States)

Pérez-Díaz, J L; Álvarez-Valenzuela, M A; Rodríguez-Celis, F

2016-01-01

Freezing, melting, evaporation and condensation of water are essential ingredients for climate and eventually life on Earth. In the present work, we show how surface freezing of supercooled water in an open container is conditioned and triggered-exclusively-by humidity in air. Additionally, a change of phase is demonstrated to be triggered on the water surface forming surface ice crystals prior to freezing of bulk. The symmetry of the surface crystal, as well as the freezing point, depend on humidity, presenting at least three different types of surface crystals. Humidity triggers surface freezing as soon as it overpasses a defined value for a given temperature, generating a plurality of nucleation nodes. An evidence of simultaneous nucleation of surface ice crystals is also provided.

How accurately are climatological characteristics and surface water and energy balances represented for the Colombian Caribbean Catchment Basin?

Science.gov (United States)

Hoyos, Isabel; Baquero-Bernal, Astrid; Hagemann, Stefan

2013-09-01

In Colombia, the access to climate related observational data is restricted and their quantity is limited. But information about the current climate is fundamental for studies on present and future climate changes and their impacts. In this respect, this information is especially important over the Colombian Caribbean Catchment Basin (CCCB) that comprises over 80 % of the population of Colombia and produces about 85 % of its GDP. Consequently, an ensemble of several datasets has been evaluated and compared with respect to their capability to represent the climate over the CCCB. The comparison includes observations, reconstructed data (CPC, Delaware), reanalyses (ERA-40, NCEP/NCAR), and simulated data produced with the regional climate model REMO. The capabilities to represent the average annual state, the seasonal cycle, and the interannual variability are investigated. The analyses focus on surface air temperature and precipitation as well as on surface water and energy balances. On one hand the CCCB characteristics poses some difficulties to the datasets as the CCCB includes a mountainous region with three mountain ranges, where the dynamical core of models and model parameterizations can fail. On the other hand, it has the most dense network of stations, with the longest records, in the country. The results can be summarised as follows: all of the datasets demonstrate a cold bias in the average temperature of CCCB. However, the variability of the average temperature of CCCB is most poorly represented by the NCEP/NCAR dataset. The average precipitation in CCCB is overestimated by all datasets. For the ERA-40, NCEP/NCAR, and REMO datasets, the amplitude of the annual cycle is extremely high. The variability of the average precipitation in CCCB is better represented by the reconstructed data of CPC and Delaware, as well as by NCEP/NCAR. Regarding the capability to represent the spatial behaviour of CCCB, temperature is better represented by Delaware and REMO, while

Interactions on External MOF Surfaces: Desorption of Water and Ethanol from CuBDC Nanosheets.

Science.gov (United States)

Elder, Alexander C; Aleksandrov, Alexandr B; Nair, Sankar; Orlando, Thomas M

2017-10-03

The external surfaces of metal-organic framework (MOF) materials are difficult to experimentally isolate due to the high porosities of these materials. MOF surface surrogates in the form of copper benzenedicarboxylate (CuBDC) nanosheets were synthesized using a bottom-up approach, and the surface interactions of water and ethanol were investigated by temperature-programmed desorption (TPD). A method of analysis of diffusion-influenced TPD was developed to measure the desorption properties of these porous materials. This approach also allows the extraction of diffusion coefficients from TPD data. The transmission Fourier transform infrared spectra, powder X-ray diffraction patterns, and TPD data indicate that water desorbs from CuBDC nanosheets with activation energies of 44 ± 2 kJ/mol at edge sites and 58 ± 1 kJ/mol at external surface and internal and pore sites. Ethanol desorbs with activation energies of 58 ± 1 kJ/mol at internal pore sites and 66 ± 0.4 kJ/mol at external surface sites. Co-adsorption of water and ethanol was also investigated. The presence of ethanol was found to inhibit the desorption of water, resulting in a water desorption process with an activation energy of 68 ± 0.7 kJ/mol.

Calibration of a distributed hydrology and land surface model using energy flux measurements

DEFF Research Database (Denmark)

Larsen, Morten Andreas Dahl; Refsgaard, Jens Christian; Jensen, Karsten H.

2016-01-01

In this study we develop and test a calibration approach on a spatially distributed groundwater-surface water catchment model (MIKE SHE) coupled to a land surface model component with particular focus on the water and energy fluxes. The model is calibrated against time series of eddy flux measure...

Using radiometric surface temperature for surface energy flux estimation in Mediterranean drylands from a two-source perspective

DEFF Research Database (Denmark)

Morillas, L.; Garcia Garcia, Monica; Nieto Solana, Hector

2013-01-01

A two-source model (TSM) for surface energy balance, considering explicitly soil and vegetation components, was tested under water stress conditions. The TSM evaluated estimates the sensible heat flux (H) using the surface-air thermal gradient and the latent heat flux (LE) as a residual from the ...

Harvesting electrostatic energy using super-hydrophobic surfaces

Science.gov (United States)

Pociecha, Dominik; Zylka, Pawel

2016-11-01

Almost all environments are now being extensively populated by miniaturized, nano-powered electronic sensor devices communicated together through wireless sensor networks building Internet of Things (IoT). Various energy harvesting techniques are being more and more frequently proposed for battery-less powering of such remote, unattended, implantable or wearable sensors or other low-power electronic gadgets. Energy harvesting relays on extracting energy from the ambient sources readily accessible at the sensor location and converting it into electrical power. The paper exploits possibility of generating electric energy safely accessible for nano-power electronics using tribo-electric and electrostatic induction phenomena displayed at super-hydrophobic surfaces impinged by water droplets. Mechanism of such interaction is discussed and illustrated by experimental results.

Integrated Land-Water-Energy assessment using the Foreseer Tool

Science.gov (United States)

Allwood, Julian; Konadu, Dennis; Mourao, Zenaida; Lupton, Rick; Richards, Keith; Fenner, Richard; Skelton, Sandy; McMahon, Richard

2016-04-01

This study presents an integrated energy and resource modelling and visualisation approach, ForeseerTM, which characterises the interdependencies and evaluates the land and water requirement for energy system pathways. The Foreseer Tool maps linked energy, water and land resource futures by outputting a set of Sankey diagrams for energy, water and land, showing the flow from basic resource (e.g. coal, surface water, and forested land) through transformations (e.g. fuel refining and desalination) to final services (e.g. sustenance, hygiene and transportation). By 'mapping' resources in this way, policy-makers can more easily understand the competing uses through the identification of the services it delivers (e.g. food production, landscaping, energy), the potential opportunities for improving the management of the resource and the connections with other resources which are often overlooked in a traditional sector-based management strategy. This paper will present a case study of the UK Carbon Plan, and highlights the need for integrated resource planning and policy development.

Innovative coatings and surface modification of titanium for sea water condenser applications

International Nuclear Information System (INIS)

George, R.P.; Anandkumar, B.; Vanithakumari, S.C.; Kamachi Mudali, U.

2016-01-01

Effectiveness of cooling water systems in various power plants to maintain highest electrical energy output per tonne of fuel is important as part of good energy management. Cooling water systems of nuclear power plants using seawater for cooling comes under constant attack from the marine and sea water environment. Many metallic components and civil structures in the cooling water systems like bridges, intake wells, intake pipes, pump house wells, water boxes, condenser pipes are subjected to severe fouling and corrosion which limits the service life and availability of power plants. The experience with a coastal water cooled power plant at Kalpakkam (MAPS), India, showed that chlorination and screening control macrofouling to a great extend by controlling protozoans, invertebrates, algae and fungi. However 90% of marine bacteria are resistant to such control measures, and they cause microfouling of condenser pipes leading to poor heat transfer and microbially influenced corrosion (MIC) failures. Titanium is used as condenser for Indian nuclear power plants employing sea water cooling, including the PFBR at Kalpakkam. Though titanium is excellent with respect to corrosion behavior under sea water conditions, its biocompatible nature results in biofouling and MIC during service. Therefore innovative antifouling coatings and surface modification techniques for titanium condenser applications in seawater and marine environments are the need of the hour. Extensive investigations were carried out by different methods including nanostructuring of surfaces for making them antibacterial. The microroughness of titanium was produced by repeated pickling and polishing which by itself reduced microbial adhesion. To utilize photocatalytic activity for antibacterial property, anodization of titanium surfaces followed by heat treatment was adopted and this also has controlled microbial fouling. Electroless plating of nanofilm of copper-nickel alloy decreased biofouling of

The surface energy, water, carbon flux and their intercorrelated seasonality in a global climate-vegetation coupled model

International Nuclear Information System (INIS)

Li Dan.; Jinjun Ji

2007-01-01

The sensible and latent heat fluxes, representatives of the physical exchange processes of energy and water between land and air, are the two crucial variables controlling the surface energy partitioning related to temperature and humidity. The net primary production (NPP), the major carbon flux exchange between vegetation and atmosphere, is of great importance for the terrestrial ecosystem carbon cycle. The fluxes are simulated by a two-way coupled model, Atmosphere-Vegetation Interaction Model-Global Ocean-Atmosphere-Land System Model (AVIM-GOALS) in which the surface physical and physiological processes are coupled with general circulation model (GCM), and the global spatial and temporal variation of the fluxes is studied. The simulated terrestrial surface physical fluxes are consistent with the 40-yr European Centre for Medium-Range Weather Forecasts (ECMWF) Reanalysis (ERA40) in the global distribution, but the magnitudes are generally 20-40 W/m 2 underestimated. The annual NPP agrees well with the International Geosphere Biosphere Programme (IGBP) NPP data except for the lower value in northern high latitudes. The surface physical fluxes, leaf area index (LAI) and NPP of the global mid-latitudes, especially between 30 deg N-50 deg N, show great variation in annual oscillation amplitudes. And all physical and biological fields in northern mid-latitudes have the largest seasonality with a high statistical significance of 99.9%. The seasonality of surface physical fluxes, LAI and NPP are highly correlated with each other. The meridional three-peak pattern of seasonal change emerges in northern mid-latitudes, which indicates the interaction of topographical gradient variation of surface fluxes and vegetation phenology on these three latitudinal belts

Surface water management at a mixed waste remediation site

International Nuclear Information System (INIS)

Schlotzhauer, D.S.; Warbritton, K.R.

1991-01-01

The Weldon Spring Remedial Action Project (WSSRAP) deals with chemical and radiological contaminants. MK-Ferguson Company is managing the project under contract with the US Department of Energy. Remedial activities include demolishing buildings, constructing material storage and staging areas, excavating and consolidating waste materials, and treating and disposing of the materials in a land disposal facility. Due to the excavation and construction required during remediation, a well-planned surface water management system is essential. Planning involves characterization of source areas and surface water transport mechanisms and identification of applicable regulations. System components include: erosion control sediment control, flow attenuation, and management of contaminated water. Combinations of these components may be utilized during actual construction and remediation to obtain optimum control. Monitoring is performed during implementation in order to assess the effectiveness of control measures. This management scheme provides for comprehensive management of surface water at this site by providing control and/or treatment to appropriate standards. Although some treatment methodologies for contaminated water are specific to site contaminants, this comprehensive program provides a management approach which is applicable to many remedial projects in order to minimize contaminant release and meet Clean Water Act requirements

Sustaining dry surfaces under water

DEFF Research Database (Denmark)

Jones, Paul R.; Hao, Xiuqing; Cruz-Chu, Eduardo R.

2015-01-01

Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional...... mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have...... not been investigated, and are critically important to maintain surfaces dry under water.In this work, we identify the critical roughness scale, below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys – thus keeping the immersed surface dry. Theoretical...

Wavefront modulation of water surface wave by a metasurface

International Nuclear Information System (INIS)

Sun Hai-Tao; Cheng Ying; Liu Xiao-Jun; Wang Jing-Shi

2015-01-01

We design a planar metasurface to modulate the wavefront of a water surface wave (WSW) on a deep sub-wavelength scale. The metasurface is composed of an array of coiling-up-space units with specially designed parameters, and can take on the work of steering the wavefront when it is pierced into water. Like their acoustic counterparts, the modulation of WSW is ascribed to the gradient phase shift of the coiling-up-space units, which can be perfectly tuned by changing the coiling plate length and channel number inside the units. According to the generalized Snell’s law, negative refraction and ‘driven’ surface mode of WSW are also demonstrated at certain incidences. Specially, the transmitted WSW could be efficiently guided out by linking a symmetrically-corrugated channel in ‘driven’ surface mode. This work may have potential applications in water wave energy extraction and coastal protection. (paper)

Exploring the free energy surfaces of clusters using reconnaissance metadynamics

Science.gov (United States)

Tribello, Gareth A.; Cuny, Jérôme; Eshet, Hagai; Parrinello, Michele

2011-09-01

A new approach is proposed for exploring the low-energy structures of small to medium-sized aggregates of atoms and molecules. This approach uses the recently proposed reconnaissance metadynamics method [G. A. Tribello, M. Ceriotti, and M. Parrinello. Proc. Natl. Acad. Sci. U.S.A. 107(41), 17509 (2010), 10.1073/pnas.1011511107] in tandem with collective variables that describe the average structure of the coordination sphere around the atoms/molecules. We demonstrate this method on both Lennard-Jones and water clusters and show how it is able to quickly find the global minimum in the potential energy surface, while exploring the finite temperature free energy surface.

Energy and water resources

International Nuclear Information System (INIS)

1981-12-01

This book presents data and other information for those who desire an understanding of the relationship between water and energy development. The book is not a tract for a grand plan. It does not present solutions. Many of the issues, especially regarding conflict over water allocations and use, are controlled and reconciled at the state level. This report draws together some of the physical and institutional data useful for identifying and understanding water issues which rise in regard to the various aspects of energy development. Three basic water-energy areas are considered in this report: water quality, water supply, and their institutional framework. Water consumption by energy was three percent of the nation's total consumption in 1975, not a large proportion. It is projected to increase to six percent by 2000. Water consumption rates by the energy technologies addressed in this document are tabulated. Water pollutant loadings expected from these technologies are summarized. Finally, a summary of water-related legislation which have particular ramifications in regard to the production of energy is presented

The interplay between surface-water and hydrogen bonding in a water adlayer on Pt(111) and Ag(111)

Energy Technology Data Exchange (ETDEWEB)

Delle Site, Luigi [Max-Planck-Institut fuer Polymerforschung, Ackermannweg 10, D-55128 Mainz (Germany); Ghiringhelli, Luca M [Max-Planck-Institut fuer Polymerforschung, Ackermannweg 10, D-55128 Mainz (Germany); Andreussi, Oliviero [Scuola Normale Superiore, Piazza dei Cavalieri 7, 56100 Pisa (Italy); Donadio, Davide [Computational Science, Department of Chemistry and Applied Biosciences, ETH Zurich, USI-Campus, via Giuseppe Buffi 13, CH-6900 Lugano (Switzerland); Parrinello, Michele [Scuola Normale Superiore, Piazza dei Cavalieri 7, 56100 Pisa (Italy)

2007-06-20

The structure of a water adlayer on a Pt(111) surface is investigated by means of extensive first-principles calculations. Allowing for proton disorder, the ground state energy for the {radical}3 x {radical}3R30{sup o} structure can be found. This results from an interplay between water/metal chemical bonding and the hydrogen bonding of the water network. This picture is supported by substituting Pt(111) with Ag(111): the almost inert surface allows for the reconstruction of the hydrogen network. (fast track communication)

The interplay between surface-water and hydrogen bonding in a water adlayer on Pt(111) and Ag(111)

International Nuclear Information System (INIS)

Delle Site, Luigi; Ghiringhelli, Luca M; Andreussi, Oliviero; Donadio, Davide; Parrinello, Michele

2007-01-01

The structure of a water adlayer on a Pt(111) surface is investigated by means of extensive first-principles calculations. Allowing for proton disorder, the ground state energy for the √3 x √3R30 o structure can be found. This results from an interplay between water/metal chemical bonding and the hydrogen bonding of the water network. This picture is supported by substituting Pt(111) with Ag(111): the almost inert surface allows for the reconstruction of the hydrogen network. (fast track communication)

Hydrogen generation due to water splitting on Si - terminated 4H-Sic(0001) surfaces

Science.gov (United States)

Li, Qingfang; Li, Qiqi; Yang, Cuihong; Rao, Weifeng

2018-02-01

The chemical reactions of hydrogen gas generation via water splitting on Si-terminated 4H-SiC surfaces with or without C/Si vacancies were studied by using first-principles. We studied the reaction mechanisms of hydrogen generation on the 4H-SiC(0001) surface. Our calculations demonstrate that there are major rearrangements in surface when H2O approaches the SiC(0001) surface. The first H splitting from water can occur with ground-state electronic structures. The second H splitting involves an energy barrier of 0.65 eV. However, the energy barrier for two H atoms desorbing from the Si-face and forming H2 gas is 3.04 eV. In addition, it is found that C and Si vacancies can form easier in SiC(0001)surfaces than in SiC bulk and nanoribbons. The C/Si vacancies introduced can enhance photocatalytic activities. It is easier to split OH on SiC(0001) surface with vacancies compared to the case of clean SiC surface. H2 can form on the 4H-SiC(0001) surface with C and Si vacancies if the energy barriers of 1.02 and 2.28 eV are surmounted, respectively. Therefore, SiC(0001) surface with C vacancy has potential applications in photocatalytic water-splitting.

Minimizing the water and air impacts of unconventional energy extraction

Science.gov (United States)

Jackson, R. B.

2014-12-01

Unconventional energy generates income and, done well, can reduce air pollution compared to other fossil fuels and even water use compared to fossil fuels and nuclear energy. Alternatively, it could slow the adoption of renewables and, done poorly, release toxic chemicals into water and air. Based on research to date, some primary threats to water resources come from surface spills, wastewater disposal, and drinking-water contamination through poor well integrity. For air resources, an increase in volatile organic compounds and air toxics locally is a potential health threat, but the switch from coal to natural gas for electricity generation will reduce sulfur, nitrogen, mercury, and particulate pollution regionally. Critical needs for future research include data for 1) estimated ultimate recovery (EUR) of unconventional hydrocarbons; 2) the potential for further reductions of water requirements and chemical toxicity; 3) whether unconventional resource development alters the frequency of well-integrity failures; 4) potential contamination of surface and ground waters from drilling and spills; and 5) the consequences of greenhouse gases and air pollution on ecosystems and human health.

Adsorption energies of poly(ethylene oxide)-based surfactants and nanoparticles on an air-water surface.

Science.gov (United States)

Zell, Zachary A; Isa, Lucio; Ilg, Patrick; Leal, L Gary; Squires, Todd M

2014-01-14

The self-assembly of polymer-based surfactants and nanoparticles on fluid-fluid interfaces is central to many applications, including dispersion stabilization, creation of novel 2D materials, and surface patterning. Very often these processes involve compressing interfacial monolayers of particles or polymers to obtain a desired material microstructure. At high surface pressures, however, even highly interfacially active objects can desorb from the interface. Methods of directly measuring the energy which keeps the polymer or particles bound to the interface (adsorption/desorption energies) are therefore of high interest for these processes. Moreover, though a geometric description linking adsorption energy and wetting properties through the definition of a contact angle can be established for rigid nano- or microparticles, such a description breaks down for deformable or aggregating objects. Here, we demonstrate a technique to quantify desorption energies directly, by comparing surface pressure-density compression measurements using a Wilhelmy plate and a custom-microfabricated deflection tensiometer. We focus on poly(ethylene oxide)-based polymers and nanoparticles. For PEO-based homo- and copolymers, the adsorption energy of PEO chains scales linearly with molecular weight and can be tuned by changing the subphase composition. Moreover, the desorption surface pressure of PEO-stabilized nanoparticles corresponds to the saturation surface pressure for spontaneously adsorbed monolayers, yielding trapping energies of ∼10(3) k(B)T.

The water-energy nexus at water supply and its implications on the integrated water and energy management.

Science.gov (United States)

Khalkhali, Masoumeh; Westphal, Kirk; Mo, Weiwei

2018-09-15

Water and energy are highly interdependent in the modern world, and hence, it is important to understand their constantly changing and nonlinear interconnections to inform the integrated management of water and energy. In this study, a hydrologic model, a water systems model, and an energy model were developed and integrated into a system dynamics modeling framework. This framework was then applied to a water supply system in the northeast US to capture its water-energy interactions under a set of future population, climate, and system operation scenarios. A hydrologic model was first used to simulate the system's hydrologic inflows and outflows under temperature and precipitation changes on a weekly-basis. A water systems model that combines the hydrologic model and management rules (e.g., water release and transfer) was then developed to dynamically simulate the system's water storage and water head. Outputs from the water systems model were used in the energy model to estimate hydropower generation. It was found that critical water-energy synergies and tradeoffs exist, and there is a possibility for integrated water and energy management to achieve better outcomes. This analysis also shows the importance of a holistic understanding of the systems as a whole, which would allow utility managers to make proactive long-term management decisions. The modeling framework is generalizable to other water supply systems with hydropower generation capacities to inform the integrated management of water and energy resources. Copyright © 2018 Elsevier B.V. All rights reserved.

Particle dry deposition to water surfaces: Processes and consequences

DEFF Research Database (Denmark)

Pryor, S.C.; Barthelmie, R.J.

2000-01-01

flux to coastal waters, atmosphere-surface exchange represents a significant component of the total flux and may be particularly critical during the summertime when both the riverine input and ambient nutrient concentrations are often at a minimum. In this chapter, we present an overview...... of the physical and chemical processes which dictate the quantity (and direction) of atmosphere-surface fluxes of trace chemicals to (and above) water surfaces with particular emphasis on the role of particles. Dry deposition (transfer to the surface in the absence of precipitation) of particles is determined...... efforts to simulate and measure fluxes close to the coastline. These arise in part from the complexity of atmospheric flow in this region where energy and chemical fluxes are highly inhomogeneous in space and time and thermally generated atmospheric circulations are commonplace. (C) 2000 Elsevier Science...

Surface Water in Hawaii

Science.gov (United States)

Oki, Delwyn S.

2003-01-01

Surface water in Hawaii is a valued resource as well as a potential threat to human lives and property. The surface-water resources of Hawaii are of significant economic, ecologic, cultural, and aesthetic importance. Streams supply more than 50 percent of the irrigation water in Hawaii, and although streams supply only a few percent of the drinking water statewide, surface water is the main source of drinking water in some places. Streams also are a source of hydroelectric power, provide important riparian and instream habitats for many unique native species, support traditional and customary Hawaiian gathering rights and the practice of taro cultivation, and possess valued aesthetic qualities. Streams affect the physical, chemical, and aesthetic quality of receiving waters, such as estuaries, bays, and nearshore waters, which are critical to the tourism-based economy of the islands. Streams in Hawaii pose a danger because of their flashy nature; a stream's stage, or water level, can rise several feet in less than an hour during periods of intense rainfall. Streams in Hawaii are flashy because rainfall is intense, drainage basins are small, basins and streams are steep, and channel storage is limited. Streamflow generated during periods of heavy rainfall has led to loss of property and human lives in Hawaii. Most Hawaiian streams originate in the mountainous interiors of the islands and terminate at the coast. Streams are significant sculptors of the Hawaiian landscape because of the erosive power of the water they convey. In geologically young areas, such as much of the southern part of the island of Hawaii, well-defined stream channels have not developed because the permeability of the surface rocks generally is so high that rainfall infiltrates before flowing for significant distances on the surface. In geologically older areas that have received significant rainfall, streams and mass wasting have carved out large valleys.

Water transport and energy.

Science.gov (United States)

Fricke, Wieland

2017-06-01

Water transport in plants occurs along various paths and is driven by gradients in its free energy. It is generally considered that the mode of transport, being either diffusion or bulk flow, is a passive process, although energy may be required to sustain the forces driving water flow. This review aims at putting water flow at the various organisational levels (cell, organ, plant) in the context of the energy that is required to maintain these flows. In addition, the question is addressed (1) whether water can be transported against a difference in its chemical free energy, 'water potential' (Ψ), through, directly or indirectly, active processes; and (2) whether the energy released when water is flowing down a gradient in its energy, for example during day-time transpiration and cell expansive growth, is significant compared to the energy budget of plant and cell. The overall aim of review is not so much to provide a definite 'Yes' and 'No' to these questions, but rather to stimulate discussion and raise awareness that water transport in plants has its real, associated, energy costs and potential energy gains. © 2016 John Wiley & Sons Ltd.

Molecular Dynamics Studies of Overbased Detergents on a Water Surface.

Science.gov (United States)

Bodnarchuk, M S; Dini, D; Heyes, D M; Breakspear, A; Chahine, S

2017-07-25

Molecular dynamics (MD) simulations are reported of model overbased detergent nanoparticles on a model water surface which mimic their behavior on a Langmuir trough or large water droplet in engine oil. The simulations predict that the structure of the nanoparticle on a water surface is different to when it is immersed in a bulk hydrophobic solvent. The surfactant tails are partly directed out of the water, while the carbonate core maximizes its extent of contact with the water. Umbrella sampling calculations of the potential of mean force between two particles showed that they are associated with varying degrees with a maximum binding free energy of ca. 10 k B T for the salicylate stabilized particle, ca. 8 k B T for a sulfurized alkyl phenate stabilized particle, and ca. 5 k B T for a sulfonate stabilized particle. The differences in the strength of attraction depend on the proximity of nearest approach and the energy penalty associated with the disruption of the hydration shell of water molecules around the calcium carbonate core when the two particles approach. This is greatest for the sulfonate particle, which partially loses the surfactant ions to the solution, and least for the salicylate, which forms the weakest water "cage". The particles are separated by a water hydration layer, even at the point of closest approach.

Silicone-Based Triboelectric Nanogenerator for Water Wave Energy Harvesting.

Science.gov (United States)

Xiao, Tian Xiao; Jiang, Tao; Zhu, Jian Xiong; Liang, Xi; Xu, Liang; Shao, Jia Jia; Zhang, Chun Lei; Wang, Jie; Wang, Zhong Lin

2018-01-31

Triboelectric nanogenerator (TENG) has been proven to be efficient for harvesting water wave energy, which is one of the most promising renewable energy sources. In this work, a TENG with a silicone rubber/carbon black composite electrode was designed for converting the water wave energy into electricity. The silicone-based electrode with a soft texture provides a better contact with the dielectric film. Furthermore, a spring structure is introduced to transform low-frequency water wave motions into high-frequency vibrations. They together improve the output performance and efficiency of TENG. The output performances of TENGs are further enhanced by optimizing the triboelectric material pair and tribo-surface area. A spring-assisted TENG device with the segmented silicone rubber-based electrode structure was sealed into a waterproof box, which delivers a maximum power density of 2.40 W m -3 , as triggered by the water waves. The present work provides a new strategy for fabricating high-performance TENG devices by coupling flexible electrodes and spring structure for harvesting water wave energy.

Water dissociation on Ni(100) and Ni(111): Effect of surface temperature on reactivity

International Nuclear Information System (INIS)

Seenivasan, H.; Tiwari, Ashwani K.

2013-01-01

Water adsorption and dissociation on Ni(100) and Ni(111) surfaces are studied using density functional theory calculations. Water adsorbs on top site on both the surfaces, while H and OH adsorb on four fold hollow and three fold hollow (fcc) sites on Ni(100) and Ni(111), respectively. Transition states (TS) on both surfaces are identified using climbing image-nudged elastic band method. It is found that the barrier to dissociation on Ni(100) surface is slightly lower than that on Ni(111) surface. Dissociation on both the surfaces is exothermic, while the exothermicity on Ni(100) is large. To study the effect of lattice motion on the energy barrier, TS calculations are performed for various values of Q (lattice atom coordinate along the surface normal) and the change in the barrier height and position is determined. Calculations show that the energy barrier to reaction decreases with increasing Q and increases with decreasing Q on both the surfaces. Dissociation probability values at different surface temperatures are computed using semi-classical approximation. Results show that the influence of surface temperature on dissociation probability on the Ni(100) is significantly larger compared to that of Ni(111). Moreover, on Ni(100), a dramatic shift in energy barrier to lower incident energy values is observed with increasing surface temperature, while the shift is smaller in the case of Ni(111)

Nonzero Ideal Gas Contribution to the Surface Tension of Water.

Science.gov (United States)

Sega, Marcello; Fábián, Balázs; Jedlovszky, Pál

2017-06-15

Surface tension, the tendency of fluid interfaces to behave elastically and minimize their surface, is routinely calculated as the difference between the lateral and normal components of the pressure or, invoking isotropy in momentum space, of the virial tensor. Here we show that the anisotropy of the kinetic energy tensor close to a liquid-vapor interface can be responsible for a large part of its surface tension (about 15% for water, independent from temperature).

Energy efficiency of a solar domestic hot water system

Science.gov (United States)

Zukowski, Miroslaw

2017-11-01

The solar domestic hot water (SDHW) system located on the campus of Bialystok University of Technology is the object of the research described in the current paper. The solar thermal system is composed of 35 flat plate collectors, 21 evacuated tube collectors and eight hot water tanks with the capacity of 1 m3 of each. Solar facility is equipped with hardware for automatic data collection. Additionally, the weather station located on the roof of the building provides measurements of basic parameters of ambient air and solar radiation. The main objective of Regional Operational Program was the assessment of the effectiveness of this solar energy technology in the climatic conditions of the north-eastern Poland. Energy efficiency of SDHW system was defined in this research as the ratio between the useful heat energy supplied to the domestic hot water system and solar energy incident on the surface of solar panels. Heat loss from water storage tanks, and from the pipe network to the surrounding air, as well as the electrical energy consumed by the pumps have been included in the calculations. The paper presents the detailed results and conclusions obtained from this energy analysis.

Water and land availability for energy farming. Final report

Energy Technology Data Exchange (ETDEWEB)

Schooley, F.A.; Mara, S.J.; Mendel, D.A.; Meagher, P.C.; So, E.C.

1979-10-01

The physical and economic availability of land and water resources for energy farming were determined. Ten water subbasins possessing favorable land and water availabilities were ranked according to their overall potential for biomass production. The study results clearly identify the Southeast as a favorable area for biomass farming. The Northwest and North-Central United States should also be considered on the basis of their highly favorable environmental characteristics. Both high and low estimates of water availability for 1985 and 2000 in each of 99 subbasins were prepared. Subbasins in which surface water consumption was more than 50% of surface water supply were eliminated from the land availability analysis, leaving 71 subbasins to be examined. The amount of acreage potentially available for biomass production in these subbasins was determined through a comparison of estimated average annual net returns developed for conventional agriculture and forestry with net returns for several biomass production options. In addition to a computerized method of ranking subbasins according to their overall potential for biomass production, a methodology for evaluating future energy farm locations was developed. This methodology included a general area selection procedure as well as specific site analysis recommendations. Thirty-five general factors and a five-step site-specific analysis procedure are described.

Investigation of the Structures and Energy Landscapes of Thiocyanate-Water Clusters

Directory of Open Access Journals (Sweden)

Lewis C. Smeeton

2017-03-01

Full Text Available The Basin Hopping search method is used to find the global minima (GM and map the energy landscapes of thiocyanate-water clusters, (SCN−(H2On with 3–50 water molecules, with empirical potentials describing the ion-water and water-water interactions. (It should be noted that beyond n = 23, the lowest energy structures were only found in 1 out of 8 searches so they are unlikely to be the true GM but are indicative low energy structures. As for pure water clusters, the low energy isomers of thiocyanate-water clusters show a preponderance of fused water cubes and pentagonal prisms, with the weakly solvated thiocyanate ion lying on the surface, replacing two water molecules along an edge of a water polyhedron and with the sulfur atom in lower coordinated sites than nitrogen. However, by comparison with Density Functional Theory (DFT calculations, the empirical potential is found to overestimate the strength of the thiocyanate-water interaction, especially O–H⋯S, with low energy DFT structures having lower coordinate N and (especially S atoms than for the empirical potential. In the case of these finite ion-water clusters, the chaotropic (“disorder-making” thiocyanate ion weakens the water cluster structure but the water molecule arrangement is not significantly changed.

Inter-comparison of energy balance and hydrological models for land surface energy flux estimation over a whole river catchment

DEFF Research Database (Denmark)

Guzinski, R.; Nieto, H.; Stisen, S.

2015-01-01

Evapotranspiration (ET) is the main link between the natural water cycle and the land surface energy budget. Therefore water-balance and energy-balance approaches are two of the main methodologies for modelling this process. The water-balance approach is usually implemented as a complex....... The temporal patterns produced by the remote sensing and hydrological models are quite highly correlated (r ≈ 0.8). This indicates potential benefits to the hydrological modelling community of integrating spatial information derived through remote sensing methodology (contained in the ET maps...

DFT simulations of water adsorption and activation on low-index α-Ga2O3 surfaces.

Science.gov (United States)

Zhou, Xin; Hensen, Emiel J M; van Santen, Rutger A; Li, Can

2014-06-02

Density functional theory (DFT) calculations are used to explore water adsorption and activation on different α-Ga2O3 surfaces, namely (001), (100), (110), and (012). The geometries and binding energies of molecular and dissociative adsorption are studied as a function of coverage. The simulations reveal that dissociative water adsorption on all the studied low-index surfaces are thermodynamically favorable. Analysis of surface energies suggests that the most preferentially exposed surface is (012). The contribution of surface relaxation to the respective surface energies is significant. Calculations of electron local density of states indicate that the electron-energy band gaps for the four investigated surfaces appears to be less related to the difference in coordinative unsaturation of the surface atoms, but rather to changes in the ionicity of the surface chemical bonds. The electrochemical computation is used to investigate the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER) on α-Ga2O3 surfaces. Our results indicate that the (100) and (110) surfaces, which have low stability, are the most favorable ones for HER and OER, respectively. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Interaction of the Helium, Hydrogen, Air, Argon, and Nitrogen Bubbles with Graphite Surface in Water.

Science.gov (United States)

Bartali, Ruben; Otyepka, Michal; Pykal, Martin; Lazar, Petr; Micheli, Victor; Gottardi, Gloria; Laidani, Nadhira

2017-05-24

The interaction of the confined gas with solid surface immersed in water is a common theme of many important fields such as self-cleaning surface, gas storage, and sensing. For that reason, we investigated the gas-graphite interaction in the water medium. The graphite surface was prepared by mechanical exfoliation of highly oriented pyrolytic graphite (HOPG). The surface chemistry and morphology were studied by X-ray photoelectron spectroscopy, profilometry, and atomic force microscopy. The surface energy of HOPG was estimated by contact angle measurements using the Owens-Wendt method. The interaction of gases (Ar, He, H 2 , N 2 , and air) with graphite was studied by a captive bubble method, in which the gas bubble was in contact with the exfoliated graphite surface in water media. The experimental data were corroborated by molecular dynamics simulations and density functional theory calculations. The surface energy of HOPG equaled to 52.8 mJ/m 2 and more of 95% of the surface energy was attributed to dispersion interactions. The results on gas-surface interaction indicated that HOPG surface had gasphilic behavior for helium and hydrogen, while gasphobic behavior for argon and nitrogen. The results showed that the variation of the gas contact angle was related to the balance between the gas-surface and gas-gas interaction potentials. For helium and hydrogen the gas-surface interaction was particularly high compared to gas-gas interaction and this promoted the favorable interaction with graphite surface.

Biphilic Surfaces for Enhanced Water Collection from Humid Air

Science.gov (United States)

Benkoski, Jason; Gerasopoulos, Konstantinos; Luedeman, William

Surface wettability plays an important role in water recovery, distillation, dehumidification, and heat transfer. The efficiency of each process depends on the rate of droplet nucleation, droplet growth, and mass transfer. Unfortunately, hydrophilic surfaces are good at nucleation but poor at shedding. Hydrophobic surfaces are the reverse. Many plants and animals overcome this tradeoff through biphilic surfaces with patterned wettability. For example, the Stenocara beetle uses hydrophilic patches on a superhydrophobic background to collect fog from air. Cribellate spiders similarly collect fog on their webs through periodic spindle-knot structures. In this study, we investigate the effects of wettability patterns on the rate of water collection from humid air. The steady state rate of water collection per unit area is measured as a function of undercooling, angle of inclination, water contact angle, hydrophilic patch size, patch spacing, area fraction, and patch height relative to the hydrophobic background. We then model each pattern by comparing the potential and kinetic energy of a droplet as it rolls downwards at a fixed angle. The results indicate that the design rules for collecting fog differ from those for condensation from humid air. The authors gratefully acknowledge the Office of Naval Research for financial support through Grant Number N00014-15-1-2107.

Quantum mechanical/molecular mechanical modeling finds Diels-Alder reactions are accelerated less on the surface of water than in water.

Science.gov (United States)

Thomas, Laura L; Tirado-Rives, Julian; Jorgensen, William L

2010-03-10

Quantum and molecular mechanics calculations for the Diels-Alder reactions of cyclopentadiene with 1,4-naphthoquinone, methyl vinyl ketone, and acrylonitrile have been carried out at the vacuum-water interface and in the gas phase. In conjunction with previous studies of these cycloadditions in dilute solution, a more complete picture of aqueous environmental effects emerges with implications for the origin of observed rate accelerations using heterogeneous aqueous suspensions, "on water" conditions. The pure TIP4P water slab maintains the bulk density and hydrogen-bonding properties in central water layers. The bulk region merges to vacuum over a ca. 5 A band with progressive diminution of the density and hydrogen bonding. The relative free energies of activation and transition structures for the reactions at the interface are found to be intermediate between those calculated in the gas phase and in bulk water; i.e., for the reaction with 1,4-naphthoquinone, the DeltaDeltaG(++) values relative to the gas phase are -3.6 and -7.3 kcal/mol at the interface and in bulk water, respectively. Thus, the results do not support the notion that a water surface is more effective than bulk water for catalysis of such pericyclic reactions. The trend is in qualitative agreement with expectations based on density considerations and estimates of experimental rate constants for the gas phase, a heterogeneous aqueous suspension, and a dilute aqueous solution for the reaction of cyclopentadiene with methyl vinyl ketone. Computed energy pair distributions reveal a uniform loss of 0.5-1.0 hydrogen bond for the reactants and transition states in progressing from bulk water to the vacuum-water interface. Orientational effects are apparent at the surface; e.g., the carbonyl group in the methyl vinyl ketone transition structure is preferentially oriented into the surface. Also, the transition structure for the 1,4-naphthoquinone case is buried more in the surface, and the free energy of

Surface Passivation of GaN Nanowires for Enhanced Photoelectrochemical Water-Splitting.

Science.gov (United States)

Varadhan, Purushothaman; Fu, Hui-Chun; Priante, Davide; Retamal, Jose Ramon Duran; Zhao, Chao; Ebaid, Mohamed; Ng, Tien Khee; Ajia, Idirs; Mitra, Somak; Roqan, Iman S; Ooi, Boon S; He, Jr-Hau

2017-03-08

Hydrogen production via photoelectrochemical water-splitting is a key source of clean and sustainable energy. The use of one-dimensional nanostructures as photoelectrodes is desirable for photoelectrochemical water-splitting applications due to the ultralarge surface areas, lateral carrier extraction schemes, and superior light-harvesting capabilities. However, the unavoidable surface states of nanostructured materials create additional charge carrier trapping centers and energy barriers at the semiconductor-electrolyte interface, which severely reduce the solar-to-hydrogen conversion efficiency. In this work, we address the issue of surface states in GaN nanowire photoelectrodes by employing a simple and low-cost surface treatment method, which utilizes an organic thiol compound (i.e., 1,2-ethanedithiol). The surface-treated photocathode showed an enhanced photocurrent density of -31 mA/cm 2 at -0.2 V versus RHE with an incident photon-to-current conversion efficiency of 18.3%, whereas untreated nanowires yielded only 8.1% efficiency. Furthermore, the surface passivation provides enhanced photoelectrochemical stability as surface-treated nanowires retained ∼80% of their initial photocurrent value and produced 8000 μmol of gas molecules over 55 h at acidic conditions (pH ∼ 0), whereas the untreated nanowires demonstrated only passivation of nanostructured photoelectrodes for photoelectrochemical applications.

Water-energy nexus: Impact on electrical energy conversion and mitigation by smart water resources management

International Nuclear Information System (INIS)

Gjorgiev, Blaže; Sansavini, Giovanni

2017-01-01

Highlights: • The issues to energy conversion stemming from the water-energy nexus are investigated. • The objective is to minimize power curtailments caused by critical river water conditions. • A water-energy nexus model for smart management of water resources is developed. • Systemic risks to energy conversion stem from critical temperature and flow regimes. • Full coordination of the hydrologically-linked units provides the most effective strategy. - Abstract: The water-energy nexus refers to the water used to generate electricity and to the electric energy used to collect, clean, move, store, and dispose of water. Water is used in all stages of electric energy conversion making power systems vulnerable to water scarcity and warming. In particular, a water flow decrease and temperature increase in rivers can significantly limit the generation of electricity. This paper investigates the issues to energy conversion stemming from the water-energy nexus and mitigates them by developing a model for the smart utilization of water resources. The objective is to minimize power curtailments caused by a river water flow decrease and a temperature increase. The developed water-energy nexus model integrates the operational characteristics of hydro power plants, the environmental conditions, the river water temperature prediction and thermal load release in river bodies. The application to a hydraulic cascade of hydro and a thermal power plants under drought conditions shows that smart water management entails a significant reduction of power curtailments. In general, the full coordination of the power outputs of the units affected by the hydrological link provides the most effective mitigations of the potential issues stemming from the water-energy nexus. Finally, critical temperature and flow regimes are identified which severely impact the energy conversion and may cause systemic risks in case the generators in one region must be simultaneously curtailed.

Water on a Hydrophobic surface

Science.gov (United States)

Scruggs, Ryan; Zhu, Mengjue; Poynor, Adele

2012-02-01

Hydrophobicity, meaning literally fear of water, is exhibited on the surfaces of non-stick cooking pans and water resistant clothing, on the leaves of the lotus plan, or even during the protein folding process in our bodies. Hydrophobicity is directly measured by determining a contact angle between water and an objects surface. Associated with a hydrophobic surface is the depletion layer, a low density region approximately 0.2 nm thick. We study this region by comparing data found in lab using surface plasmon resonance techniques to theoretical calculations. Experiments use gold slides coated in ODT and Mercapto solutions to model both hydrophobic and hydrophilic surfaces respectively.

Photoionization of environmentally polluting aromatic chlorides and nitrides on the water surface by laser and synchrotron radiations.

Science.gov (United States)

Sato, Miki; Maeda, Yuki; Ishioka, Toshio; Harata, Akira

2017-11-20

The detection limits and photoionization thresholds of polycyclic aromatic hydrocarbons and their chlorides and nitrides on the water surface are examined using laser two-photon ionization and single-photon ionization, respectively. The laser two-photon ionization methods are highly surface-selective, with a high sensitivity for aromatic hydrocarbons tending to accumulate on the water surface in the natural environment due to their highly hydrophobic nature. The dependence of the detection limits of target aromatic molecules on their physicochemical properties (photoionization thresholds relating to excess energy, molar absorptivity, and the octanol-water partition coefficient) is discussed. The detection limit clearly depends on the product of the octanol-water partition coefficient and molar absorptivity, and no clear dependence was found on excess energy. The detection limits of laser two-photon ionization for these types of molecules on the water surface are formulated.

Observation of dynamic water microadsorption on Au surface

Energy Technology Data Exchange (ETDEWEB)

Huang, Xiaokang, E-mail: xiaokang.huang@tqs.com; Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold [TriQuint Semiconductor, Inc., 500 W Renner Road, Richardson, Texas 75080 (United States)

2014-05-15

Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12 μm{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

Surface energy of amorphous carbon films containing iron

International Nuclear Information System (INIS)

Chen, J. S.; Lau, S. P.; Tay, B. K.; Chen, G. Y.; Sun, Z.; Tan, Y. Y.; Tan, G.; Chai, J. W.

2001-01-01

Iron containing diamond-like amorphous carbon (a-C:Fe) films were deposited by filtered cathodic vacuum arc technique. The influences of Fe content and substrate bias on the surface energy of the films were investigated. The surface energy of a-C:Fe films was determined by the contact angle measurement. Atomic force microscopy, Raman spectroscopy, and x-ray induced photoelectron spectroscopy were employed to analyze the origin of the variation of surface energy with various Fe content and substrate bias. It is found that the contact angle for water increases significantly after incorporating Fe into the films and the films become hydrophobic. The roughness of these films has no effect on the contact angle. The surface energy is reduced from 42.8 to 25 dyne/cm after incorporating Fe into the a-C film (10% Fe in the target), which is due to the reduction of both dispersive and polar component. The reduction in dispersive component is ascribed to the decrease of atomic density of the a-C:Fe films due to the increase in sp 2 bonded carbon. When sp 2 content increases to some extent, the atomic density remains constant and hence dispersive component does not change. The absorption of oxygen on the surface plays an important role in the reduction of the polar component for the a-C:Fe films. It is proposed that such network as (C n - O - Fe) - O - (Fe - O - C n ) may be formed and responsible for the reduction of polar component. [copyright] 2001 American Institute of Physics

Effect of crystal habits on the surface energy and cohesion of crystalline powders.

Science.gov (United States)

Shah, Umang V; Olusanmi, Dolapo; Narang, Ajit S; Hussain, Munir A; Gamble, John F; Tobyn, Michael J; Heng, Jerry Y Y

2014-09-10

The role of surface properties, influenced by particle processing, in particle-particle interactions (powder cohesion) is investigated in this study. Wetting behaviour of mefenamic acid was found to be anisotropic by sessile drop contact angle measurements on macroscopic (>1cm) single crystals, with variations in contact angle of water from 56.3° to 92.0°. This is attributed to variations in surface chemical functionality at specific facets, and confirmed using X-ray photoelectron spectroscopy (XPS). Using a finite dilution inverse gas chromatography (FD-IGC) approach, the surface energy heterogeneity of powders was determined. The surface energy profile of different mefenamic acid crystal habits was directly related to the relative exposure of different crystal facets. Cohesion, determined by a uniaxial compression test, was also found to relate to surface energy of the powders. By employing a surface modification (silanisation) approach, the contribution from crystal shape from surface area and surface energy was decoupled. By "normalising" contribution from surface energy and surface area, needle shaped crystals were found to be ∼2.5× more cohesive compared to elongated plates or hexagonal cuboid shapes crystals. Copyright © 2014. Published by Elsevier B.V.

Water management for sustainable and clean energy in Turkey

Directory of Open Access Journals (Sweden)

Ibrahim Yuksel

2015-11-01

Full Text Available Water management has recently become a major concern for many countries. During the last century consumption of water and energy has been increased in the world. This trend is anticipated to continue in the decades to come. One of the greatest reasons is the unplanned industrial activities deteriorating environment in the name of rising standard of life. What is needed is the avoidance of environmental pollution and maintenance of natural balance, in the context of sustainable development. However, Turkey’s geographical location has several advantages for extensive use of most of the renewable energy resources. There is a large variation in annual precipitation, evaporation and surface run-off parameters, in Turkey. Precipitation is not evenly distributed in time and space throughout the country. There are 25 hydrological basins in Turkey. But the rivers often have irregular regimes. In this situation the main aim is to manage and use the water resources for renewable, sustainable and clean energy. This paper deals with water management for renewable, sustainable and clean energy in Turkey.

Properties of water surface discharge at different pulse repetition rates

International Nuclear Information System (INIS)

Ruma,; Yoshihara, K.; Hosseini, S. H. R.; Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

2014-01-01

The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H 2 O 2 ) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H 2 O 2 and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

Water adsorption on amorphous silica surfaces: a Car-Parrinello simulation study

International Nuclear Information System (INIS)

Mischler, Claus; Horbach, Juergen; Kob, Walter; Binder, Kurt

2005-01-01

A combination of classical molecular dynamics (MD) and ab initio Car-Parrinello molecular dynamics (CPMD) simulations is used to investigate the adsorption of water on a free amorphous silica surface. From the classical MD, SiO 2 configurations with a free surface are generated which are then used as starting configurations for the CPMD. We study the reaction of a water molecule with a two-membered ring at the temperature T = 300 K. We show that the result of this reaction is the formation of two silanol groups on the surface. The activation energy of the reaction is estimated and it is shown that the reaction is exothermic

The importance of surface finish to energy performance

Directory of Open Access Journals (Sweden)

Smith Geoff B.

2017-01-01

Full Text Available Power generation in solar energy systems, thermal control in buildings and mitigation of the Urban Heat Island problem, are all sensitive to directional response to incoming radiation. The radiation absorption and emission profile also plays a crucial role in each system's response and depends strongly on surface finish. This important sensitivity needs wider recognition in materials data sheets, system modeling, plus in materials and environmental engineering. The impact of surface roughness on thermal response of natural and man-made external environments is examined. Important examples will be given of the role of surface finish within each class. Total emittance links to the way surface finish influences directional emittance E(θ. Smooth surface thermal emittance on PV module covers, many solar absorbers, some roof paints, polished concrete, and glass windows can be up to 15% different from insulator results based on fully diffuse models of the same material. Widespread evidence indicates smooth metals and low-E solar absorber surfaces cool faster, and smooth insulators slower than previously thought. Matt paint is cooler than low sheen paint under the same solar heating impacts and normal concrete cooler than polished. Emittance for water is the prime environmental example of oblique impacts as it reflects strongly at oblique incidence, which leads to a significant drop in E(θ. Ripples or waves however raise water's average emittance. A surprise in this work was the high sensitivity of total E and its angular components to roughness in the depth range of 0.1–0.8 μm, which are well under ambient thermal IR wavelengths of 3–30 μm but common in metal finishing. Parallel energy flows such as evaporation and convective cooling vary if emittance varies. Thermal image analysis can provide insights into angular radiative effects.

Impact of dissipation on the energy spectrum of experimental turbulence of gravity surface waves

Science.gov (United States)

Campagne, Antoine; Hassaini, Roumaissa; Redor, Ivan; Sommeria, Joël; Valran, Thomas; Viboud, Samuel; Mordant, Nicolas

2018-04-01

We discuss the impact of dissipation on the development of the energy spectrum in wave turbulence of gravity surface waves with emphasis on the effect of surface contamination. We performed experiments in the Coriolis facility, which is a 13-m-diam wave tank. We took care of cleaning surface contamination as well as possible, considering that the surface of water exceeds 100 m2. We observe that for the cleanest condition the frequency energy spectrum shows a power-law decay extending up to the gravity capillary crossover (14 Hz) with a spectral exponent that is increasing with the forcing strength and decaying with surface contamination. Although slightly higher than reported previously in the literature, the exponent for the cleanest water remains significantly below the prediction from the weak turbulence theory. By discussing length and time scales, we show that weak turbulence cannot be expected at frequencies above 3 Hz. We observe with a stereoscopic reconstruction technique that the increase with the forcing strength of energy spectrum beyond 3 Hz is mostly due to the formation and strengthening of bound waves.

Surface energy exchanges over contrasting vegetation types on a subtropical sand island

Science.gov (United States)

Gray, Michael; McGowan, Hamish; Lowry, Andrew; Guyot, Adrien

2017-04-01

The surface energy balance of subtropical coastal vegetation communities has thus far received little attention. Here we present a multi-year observational data set using the eddy covariance method to quantify for the first time the surface energy balance over three contrasting vegetation types on a subtropical sand island in eastern Australia: a periodically inundated sedge swamp, an exotic pine plantation and a coastal heath. Maximum daily sensible heat flux varied between sites but was typically > 280 Wm-2 in the coastal heath and pine plantation but no more than 250 Wm-2 in the swamp when dry and 1. The partitioning of energy, as represented by β, is similar to a variety of Australian ecosystems, and a range of coastal vegetation types in other latitudes, but differs from other tropical or subtropical locations which have strongly seasonal rainfall patterns and therefore a switch from β > 1 before rainfall to β changes in background meteorology with the most important influences being net radiation, absolute humidity, and rainfall. The main factor differentiating the sites was soil water content, with the remnant coastal heath and swamp having ready access to water but the exotic pine plantation having much drier soils. Should the current balance between remnant vegetation and the pine plantation undergo changes there would be a corresponding shift in the surface energy balance of the island as a whole, and altered plant water use may lead to reduced water table depth, important because the groundwater of the local islands is used as part of a regional water grid. A better understanding of the response of coastal vegetation to atmospheric forcing will enable more informed decision making on land use changes, as coastal regions the world over face development pressure.

Surface Passivation of GaN Nanowires for Enhanced Photoelectrochemical Water-Splitting

KAUST Repository

Varadhan, Purushothaman; Fu, Hui-chun; Priante, Davide; Duran Retamal, Jose Ramon; Zhao, Chao; Ebaid, Mohamed; Ng, Tien Khee; Ajia, Idris A.; Mitra, Somak; Roqan, Iman S.; Ooi, Boon S.; He, Jr-Hau

2017-01-01

Hydrogen production via photoelectrochemical water-splitting is a key source of clean and sustainable energy. The use of one-dimensional nanostructures as photoelectrodes is desirable for photoelectrochemical water-splitting applications due to the ultralarge surface areas, lateral carrier extraction schemes, and superior light-harvesting capabilities. However, the unavoidable surface states of nanostructured materials create additional charge carrier trapping centers and energy barriers at the semiconductor-electrolyte interface, which severely reduce the solar-to-hydrogen conversion efficiency. In this work, we address the issue of surface states in GaN nanowire photoelectrodes by employing a simple and low-cost surface treatment method, which utilizes an organic thiol compound (i.e., 1,2-ethanedithiol). The surface-treated photocathode showed an enhanced photocurrent density of −31 mA/cm at −0.2 V versus RHE with an incident photon-to-current conversion efficiency of 18.3%, whereas untreated nanowires yielded only 8.1% efficiency. Furthermore, the surface passivation provides enhanced photoelectrochemical stability as surface-treated nanowires retained ∼80% of their initial photocurrent value and produced 8000 μmol of gas molecules over 55 h at acidic conditions (pH ∼ 0), whereas the untreated nanowires demonstrated only <4 h of photoelectrochemical stability. These findings shed new light on the importance of surface passivation of nanostructured photoelectrodes for photoelectrochemical applications.

Surface Passivation of GaN Nanowires for Enhanced Photoelectrochemical Water-Splitting

KAUST Repository

Varadhan, Purushothaman

2017-02-08

Hydrogen production via photoelectrochemical water-splitting is a key source of clean and sustainable energy. The use of one-dimensional nanostructures as photoelectrodes is desirable for photoelectrochemical water-splitting applications due to the ultralarge surface areas, lateral carrier extraction schemes, and superior light-harvesting capabilities. However, the unavoidable surface states of nanostructured materials create additional charge carrier trapping centers and energy barriers at the semiconductor-electrolyte interface, which severely reduce the solar-to-hydrogen conversion efficiency. In this work, we address the issue of surface states in GaN nanowire photoelectrodes by employing a simple and low-cost surface treatment method, which utilizes an organic thiol compound (i.e., 1,2-ethanedithiol). The surface-treated photocathode showed an enhanced photocurrent density of −31 mA/cm at −0.2 V versus RHE with an incident photon-to-current conversion efficiency of 18.3%, whereas untreated nanowires yielded only 8.1% efficiency. Furthermore, the surface passivation provides enhanced photoelectrochemical stability as surface-treated nanowires retained ∼80% of their initial photocurrent value and produced 8000 μmol of gas molecules over 55 h at acidic conditions (pH ∼ 0), whereas the untreated nanowires demonstrated only <4 h of photoelectrochemical stability. These findings shed new light on the importance of surface passivation of nanostructured photoelectrodes for photoelectrochemical applications.

Weather-power station. Solar energy, wind energy, water energy

Energy Technology Data Exchange (ETDEWEB)

Schatta, M

1975-10-02

A combined power station is described, which enables one to convert solar energy and wind energy into other forms of energy. The plant consists of a water-filled boiler, in which solar energy heats the water by concentration, solar cells, and finally wind rotors, which transform wind energy into electrical energy. The transformed energy is partly available as steam heat, partly as mechanical or electrical energy. The plant can be used for supplying heating systems or electrolysis equipment. Finally, by incorporating suitable motors, a mobile version of the system can be produced.

Energy-Water Modeling and Analysis | Energy Analysis | NREL

Science.gov (United States)

Generation (ReEDS Model Analysis) U.S. Energy Sector Vulnerabilities to Climate Change and Extreme Weather Modeling and Analysis Energy-Water Modeling and Analysis NREL's energy-water modeling and analysis vulnerabilities from various factors, including water. Example Projects Renewable Electricity Futures Study

Effect of Collagen Matrix Saturation on the Surface Free Energy of Dentin using Different Agents.

Science.gov (United States)

de Almeida, Leopoldina de Fátima Dantas; Souza, Samilly Evangelista; Sampaio, Aline Araújo; Cavalcanti, Yuri Wanderley; da Silva, Wander José; Del Bel Cur, Altair A; Hebling, Josimeri

2015-07-01

The surface free energy of conditioned-dentin is one of the factors that interfere with monomeric infiltration of the interfibrillar spaces. Saturation of the tooth matrix with different substances may modulate this energy and, consequently, the wettability of the dentin. To evaluate the influence of different substances used to saturate conditioned-dentin on surface free energy (SFE) of this substrate. Dentin blocks (4 × 7 × 1 mm, n = 6/ group), obtained from the roots of bovine incisors, were etched using phosphoric acid for 15 seconds, rinsed and gently dried. The surfaces were treated for 60 seconds with: ultra-purified water (H20-control); ethanol (EtOH), acetone (ACT), chlorhexidine (CHX), ethylenediaminetetraacetic acid (EDTA); or sodium hypochlorite (NaOCl). The tooth surfaces were once again dried with absorbent paper and prepared for SFE evaluation using three standards: water, formamide and bromonaphthalene. Analysis of variance (ANOVA) and Dunnet's tests (a = 0.05) were applied to the data. Ethylenediaminetetraacetic acid was the only substance that caused a change to the contact angle for the standards water and formamide, while only EtOH influenced the angles formed between formamide and the dentin surface. None of the substances exerted a significant effect for bromonaphtha-lene. In comparison to the control, only EDTA and NaOCl altered both polar components of the SFE. Total SFE was increased by saturation of the collagen matrix by EDTA and reduced when NaOCl was used. Saturation of the collagen matrix by EDTA and EtOH changed the surface free energy of the dentin. In addition, the use of NaOCl negatively interfered with the properties evaluated. The increase of surface free energy and wettability of the dentin surface would allow higher penetration of the the adhesive system, which would be of importance to the clinical success of resin-dentin union.

Effects of O2 and H2O plasma immersion ion implantation on surface chemical composition and surface energy of poly vinyl chloride

International Nuclear Information System (INIS)

Zhang Wei; Chu, Paul K.; Ji Junhui; Zhang, Yihe; Jiang Zhimin

2006-01-01

Oxygen and water plasma immersion ion implantation (PIII) was used to modify poly vinyl chloride (PVC) to enhance oxygen-containing surface functional groups for more effective grafting. The modified surfaces were characterized by X-ray photoelectron spectroscopy (XPS), attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIR), and contact angle measurements. Our experimental results show that both oxygen and water PIII can greatly improve the O to C ratios on the surface. The optimal plasma processing conditions differ for the two treatments. The hydrophilicity and surface energy of the plasma-implanted PVC are also improved significantly. Our results indicate that O 2 and H 2 O PIII increase both the polar and dispersion interactions and consequently the surface energy. It can be explained by the large amount of oxygen introduced to the surface and that many C-C bonds are transformed into more polar oxygen containing functional groups

Emergence of a Food-Energy-Water Nexus in Northwest Mexico as a Result of Interbasin Water Transfers.

Science.gov (United States)

Munoz Hernandez, A.; Mayer, A. S.; Vivoni, E. R.; Robles-Morua, A.; Hallack-Alegria, M.; Salazar, A.

2016-12-01

Interbasin transfers (IBT) of water have been used as a technological solution to the disparities between water supply and demand centers for centuries. However, the impacts of IBTs on the nexus between water, energy, and food production and consumption in the regions receiving and providing the vital resource are rarely assessed. This study addresses this question through the lens of a new IBT between two important basins located in Northwest Mexico: the Rio Yaqui Basin (RYB) and the Rio Sonora Basin (RSB). The RYB is a 72,000 km2 semi-arid basin with a predominantly agricultural focus that utilizes water from three surface water reservoirs and groundwater. The RSB, with an area of 20,648 km2, is one of the most prominent industrial areas of the region and is home to the most populous city in the state. Traditionally, groundwater has been the main source of water in the RSB due to significant surface water shortages associated with drought conditions. Recently, a 75 Mm3/year capacity aqueduct was built to transfer water from the RYB to the RSB. The impacts of the IBT on agricultural production and water-related energy consumption (groundwater pumping vs. pumping through the aqueduct) and production (hydropower generation) remain unknown, especially under drought conditions. Historical data was collected from the National Commission of Water in Mexico to create a water balance model that mimics the water consumption in the RYB. The purpose of this model is to compare electricity consumption and production and agricultural production, generated before and after the IBT, assuming that historical climatic conditions will be repeated in the future. Linear models were developed to understand the relationship between water, food, and energy production. Twelve aquifers in the RSB were modeled and daily hydraulic heads were estimated for a period of ten years. Once the heads were adjusted to account for local in-well drawdown, an estimation of the total amount of energy

Free energy barriers to evaporation of water in hydrophobic confinement.

Science.gov (United States)

Sharma, Sumit; Debenedetti, Pablo G

2012-11-08

We use umbrella sampling Monte Carlo and forward and reverse forward flux sampling (FFS) simulation techniques to compute the free energy barriers to evaporation of water confined between two hydrophobic surfaces separated by nanoscopic gaps, as a function of the gap width, at 1 bar and 298 K. The evaporation mechanism for small (1 × 1 nm(2)) surfaces is found to be fundamentally different from that for large (3 × 3 nm(2)) surfaces. In the latter case, the evaporation proceeds via the formation of a gap-spanning tubular cavity. The 1 × 1 nm(2) surfaces, in contrast, are too small to accommodate a stable vapor cavity. Accordingly, the associated free energy barriers correspond to the formation of a critical-sized cavity for sufficiently large confining surfaces, and to complete emptying of the gap region for small confining surfaces. The free energy barriers to evaporation were found to be of O(20kT) for 14 Å gaps, and to increase by approximately ~5kT with every 1 Å increase in the gap width. The entropy contribution to the free energy of evaporation was found to be independent of the gap width.

The Energy-Water Nexus: Managing the Links between Energy and Water for a Sustainable Future

Science.gov (United States)

Hussey, Karen; Petit, Carine

2010-05-01

Water and energy are both indispensable inputs to modern economies but currently both resources are under threat owing to the impacts of an ever-increasing population and associated demand, unsustainable practices in agriculture and manufacturing, and the implications of a changing climate. However, it is where water and energy rely on each other that pose the most complex challenges for policy-makers. Water is needed for mining coal, drilling oil, refining gasoline, and generating and distributing electricity; and, conversely, vast amounts of energy are needed to pump, transport, treat and distribute water, particularly in the production of potable water through the use of desalination plants and waste water treatment plants. Despite the links, and the urgency in both sectors for security of supply, in existing policy frameworks energy and water policies are developed largely in isolation from one another. Worse still, some policies designed to encourage alternative energy supplies give little thought to the resultant consequences on water resources, and, similarly, policies designed to secure water supplies pay little attention to the resultant consequences on energy use. The development of new technologies presents both opportunities and challenges for managing the energy-water nexus but a better understanding of the links between energy and water is essential in any attempt to formulate policies for more resilient and adaptable societies. The energy-water nexus must be adequately integrated into policy and decision-making or governments run the risk of contradicting their efforts, and therefore failing in their objectives, in both sectors. A series of COST Exploratory Workshops, drawing on on-going research in the energy-water nexus from a number of international teams, identified the implications of the energy-water nexus on the development of (i) energy policies (ii) water resource management policies and (iii) climate adaptation and mitigation policies. A

Evidence for phase separation of ethanol-water mixtures at the hydrogen terminated nanocrystalline diamond surface.

Science.gov (United States)

Janssens, Stoffel D; Drijkoningen, Sien; Saitner, Marc; Boyen, Hans-Gerd; Wagner, Patrick; Larsson, Karin; Haenen, Ken

2012-07-28

Interactions between ethanol-water mixtures and a hydrophobic hydrogen terminated nanocrystalline diamond surface, are investigated by sessile drop contact angle measurements. The surface free energy of the hydrophobic surface, obtained with pure liquids, differs strongly from values obtained by ethanol-water mixtures. Here, a model which explains this difference is presented. The model suggests that, due to a higher affinity of ethanol for the hydrophobic surface, when compared to water, a phase separation occurs when a mixture of both liquids is in contact with the H-terminated diamond surface. These results are supported by a computational study giving insight in the affinity and related interaction at the liquid-solid interface.

Balancing the Energy-Water Nexus

Energy Technology Data Exchange (ETDEWEB)

Dell, Jan

2010-09-15

Optimizing the complex tradeoffs in the Energy-Water Nexus requires quantification of energy use, carbon emitted and water consumed. Water is consumed in energy production and is often a constraint to operations. More global attention and investment has been made on reducing carbon emissions than on water management. Review of public reporting by the largest 107 global power producers and 50 companies in the oil/gas industry shows broad accounting on carbon emissions but only partial reporting on water consumption metrics. If the Energy-Water Nexus is to be balanced, then water must also be measured to be optimally managed with carbon emissions.

Water-energy nexus for urban water systems: A comparative review on energy intensity and environmental impacts in relation to global water risks

International Nuclear Information System (INIS)

Lee, Mengshan; Keller, Arturo A.; Chiang, Pen-Chi; Den, Walter; Wang, Hongtao; Hou, Chia-Hung; Wu, Jiang; Wang, Xin; Yan, Jinyue

2017-01-01

Highlights: •This study quantifies the nexus as energy intensity and greenhouse gas potential. •Baseline water stress and return flow ratio are identified as water risks. •Source water accessibility significantly contributes to variations in the nexus. •Water risks have little impact on the nexus of wastewater systems. •Study on the nexus is suggested to be conducted at regional levels. -- Abstract: The importance of the interdependence between water and energy, also known as the water-energy nexus, is well recognized. The water-energy nexus is typically characterized in resource use efficiency terms such as energy intensity. This study aims to explore the quantitative results of the nexus in terms of energy intensity and environmental impacts (mainly greenhouse gas emissions) on existing water systems within urban water cycles. We also characterized the influence of water risks on the water-energy nexus, including baseline water stress (a water quantity indicator) and return flow ratio (a water quality indicator). For the 20 regions and 4 countries surveyed (including regions with low to extremely high water risks that are geographically located in Africa, Australia, Asia, Europe, and North America), their energy intensities were positively related to the water risks. Regions with higher water risks were observed to have relatively higher energy and GHG intensities associated with their water supply systems. This mainly reflected the major influence of source water accessibility on the nexus, particularly for regions requiring energy-intensive imported or groundwater supplies, or desalination. Regions that use tertiary treatment (for water reclamation or environmental protection) for their wastewater treatment systems also had relatively higher energy and GHG emission intensities, but the intensities seemed to be independent from the water risks. On-site energy recovery (e.g., biogas or waste heat) in the wastewater treatment systems offered a great

Surface layer scintillometry for estimating the sensible heat flux component of the surface energy balance

Directory of Open Access Journals (Sweden)

M. J. Savage

2010-01-01

Full Text Available The relatively recently developed scintillometry method, with a focus on the dual-beam surface layer scintillometer (SLS, allows boundary layer atmospheric turbulence, surface sensible heat and momentum flux to be estimated in real-time. Much of the previous research using the scintillometer method has involved the large aperture scintillometer method, with only a few studies using the SLS method. The SLS method has been mainly used by agrometeorologists, hydrologists and micrometeorologists for atmospheric stability and surface energy balance studies to obtain estimates of sensible heat from which evaporation estimates representing areas of one hectare or larger are possible. Other applications include the use of the SLS method in obtaining crucial input parameters for atmospheric dispersion and turbulence models. The SLS method relies upon optical scintillation of a horizontal laser beam between transmitter and receiver for a separation distance typically between 50 and 250 m caused by refractive index inhomogeneities in the atmosphere that arise from turbulence fluctuations in air temperature and to a much lesser extent the fluctuations in water vapour pressure. Measurements of SLS beam transmission allow turbulence of the atmosphere to be determined, from which sub-hourly, real-time and in situ path-weighted fluxes of sensible heat and momentum may be calculated by application of the Monin-Obukhov similarity theory. Unlike the eddy covariance (EC method for which corrections for flow distortion and coordinate rotation are applied, no corrections to the SLS measurements, apart from a correction for water vapour pressure, are applied. Also, path-weighted SLS estimates over the propagation path are obtained. The SLS method also offers high temporal measurement resolution and usually greater spatial coverage compared to EC, Bowen ratio energy balance, surface renewal and other sensible heat measurement methods. Applying the shortened surface

Optimal urban water conservation strategies considering embedded energy: coupling end-use and utility water-energy models.

Science.gov (United States)

Escriva-Bou, A.; Lund, J. R.; Pulido-Velazquez, M.; Spang, E. S.; Loge, F. J.

2014-12-01

Although most freshwater resources are used in agriculture, a greater amount of energy is consumed per unit of water supply for urban areas. Therefore, efforts to reduce the carbon footprint of water in cities, including the energy embedded within household uses, can be an order of magnitude larger than for other water uses. This characteristic of urban water systems creates a promising opportunity to reduce global greenhouse gas emissions, particularly given rapidly growing urbanization worldwide. Based on a previous Water-Energy-CO2 emissions model for household water end uses, this research introduces a probabilistic two-stage optimization model considering technical and behavioral decision variables to obtain the most economical strategies to minimize household water and water-related energy bills given both water and energy price shocks. Results show that adoption rates to reduce energy intensive appliances increase significantly, resulting in an overall 20% growth in indoor water conservation if household dwellers include the energy cost of their water use. To analyze the consequences on a utility-scale, we develop an hourly water-energy model based on data from East Bay Municipal Utility District in California, including the residential consumption, obtaining that water end uses accounts for roughly 90% of total water-related energy, but the 10% that is managed by the utility is worth over 12 million annually. Once the entire end-use + utility model is completed, several demand-side management conservation strategies were simulated for the city of San Ramon. In this smaller water district, roughly 5% of total EBMUD water use, we found that the optimal household strategies can reduce total GHG emissions by 4% and utility's energy cost over 70,000/yr. Especially interesting from the utility perspective could be the "smoothing" of water use peaks by avoiding daytime irrigation that among other benefits might reduce utility energy costs by 0.5% according to our

Tuning surface porosity on vanadium surface by low energy He{sup +} ion irradiation

Energy Technology Data Exchange (ETDEWEB)

Tripathi, J.K., E-mail: jtripat@purdue.edu; Novakowski, T.J.; Hassanein, A.

2016-08-15

Highlights: • Surface nanostructuring on vanadium surface using novel He{sup +} ion irradiation process. • Tuning surface-porosity using high-flux, low-energy He{sup +} ion irradiation at constant elevated sample temperature (823–173 K). • Presented top-down approach guarantees good contact between different crystallites. • Sequential significant enhancement in surface-pore edge size (and corresponding reduction in surface-pore density) with increasing sample temperature. - Abstract: In the present study, we report on tuning the surface porosity on vanadium surfaces using high-flux, low-energy He{sup +} ion irradiation as function of sample temperature. Polished, mirror-finished vanadium samples were irradiated with 100 eV He{sup +} ions at a constant ion-flux of 7.2 × 10{sup 20} ions m{sup −2} s{sup −1} for 1 h duration at constant sample temperatures in the wide range of 823–1173 K. Our results show that the surface porosity of V{sub 2}O{sub 5} (naturally oxidized vanadium porous structure, after taking out from UHV) is strongly correlated to the sample temperature and is highly tunable. In fact, the surface porosity significantly increases with reducing sample temperature and reaches up to ∼87%. Optical reflectivity on these highly porous V{sub 2}O{sub 5} surfaces show ∼0% optical reflectivity at 670 nm wavelength, which is very similar to that of “black metal”. Combined with the naturally high melting point of V{sub 2}O{sub 5}, this very low optical reflectivity suggests potential application in solar power concentration technology. Additionally, this top-down approach guarantees relatively good contact between the different crystallites and avoids electrical conductivity limitations (if required). Since V{sub 2}O{sub 5} is naturally a potential photocatalytic material, the resulting sub-micron-sized cube-shaped porous structures could be used in solar water splitting for hydrogen production in energy applications.

Search for high energy skimming neutrinos at a surface detector array

International Nuclear Information System (INIS)

Vo Van Thuan; Hoang Van Khanh; Pham Ngoc Diep

2010-01-01

In the present study we propose a new method for detection of high energy cosmological muon neutrinos by transition radiations at a medium interface. The emerging electro-magnetic radiations induced by earth-skimming heavy charged leptons are able to trigger a few of aligned neighboring local water Cherenkov stations at a surface detector array similar to the Pierre Auger Observatory. The estimation applied to the model of Gamma Ray Burst induced neutrino fluxes and the spherical earth surface shows a competitive rate of muon neutrino events in the energy range below the GZK cut-off. (author)

A study of water electrolysis using ionic polymer-metal composite for solar energy storage

Science.gov (United States)

Keow, Alicia; Chen, Zheng

2017-04-01

Hydrogen gas can be harvested via the electrolysis of water. The gas is then fed into a proton exchange membrane fuel cell (PEMFC) to produce electricity with clean emission. Ionic polymer-metal composite (IPMC), which is made from electroplating a proton-conductive polymer film called Nafion encourages ion migration and dissociation of water under application of external voltage. This property has been proven to be able to act as catalyst for the electrolysis of pure water. This renewable energy system is inspired by photosynthesis. By using solar panels to gather sunlight as the source of energy, the generation of electricity required to activate the IPMC electrolyser is acquired. The hydrogen gas is collected as storable fuel and can be converted back into energy using a commercial fuel cell. The goal of this research is to create a round-trip energy efficient system which can harvest solar energy, store them in the form of hydrogen gas and convert the stored hydrogen back to electricity through the use of fuel cell with minimal overall losses. The effect of increasing the surface area of contact is explored through etching of the polymer electrolyte membrane (PEM) with argon plasma or manually sanding the surface and how it affects the increase of energy conversion efficiency of the electrolyser. In addition, the relationship between temperature and the IPMC is studied. Experimental results demonstrated that increases in temperature of water and changes in surface area contact correlate with gas generation.

Adsorption of water, sulfates and chloride on arsenopyrite surface

Science.gov (United States)

Silva, Juliana C. M.; dos Santos, Egon C.; de Oliveira, Aline; Heine, Thomas; De Abreu, Heitor A.; Duarte, Hélio A.

2018-03-01

Arsenopyrite is one of the sulfide minerals responsible for acid rock drainage (ARD) and is one of the most hazardous in regions affected by mining activities. This phenomenon involves complex reaction mechanism. Although it is intensely investigated, there is a lack of consensus concerning the reaction mechanisms and more information is still necessary. In this work, the adsorption of water, hydrochloric acid, and sulfuric acid on arsenopyrite (001) surface was investigated by means of Density Functional calculations and the results compared to other sulfides aiming to understand the mineral/water interface. The interaction of the chemical species with the (001) FeAsS surface is the first step to understand the intricate oxidation mechanism of arsenopyrite. Molecular water adsorption on (001) FeAsS is more favored than the adsorption of sulfate favoring the dissolution of sulfates and enhancing its oxidation. The estimated adsorption energies of water, sulfates and chloride on other sulfide minerals are compared with the estimated values for arsenopyrite and the chemical reactivity differences discussed in detail.

The Global Energy Balance Archive (GEBA): A database for the worldwide measured surface energy fluxes

Science.gov (United States)

Wild, Martin; Ohmura, Atsumu; Schär, Christoph; Müller, Guido; Hakuba, Maria Z.; Mystakidis, Stefanos; Arsenovic, Pavle; Sanchez-Lorenzo, Arturo

2017-02-01

The Global Energy Balance Archive (GEBA) is a database for the worldwide measured energy fluxes at the Earth's surface. GEBA is maintained at ETH Zurich (Switzerland) and has been founded in the 1980s by Prof. Atsumu Ohmura. It has continuously been updated and currently contains around 2500 stations with 500`000 monthly mean entries of various surface energy balance components. Many of the records extend over several decades. The most widely measured quantity available in GEBA is the solar radiation incident at the Earth's surface ("global radiation"). The data sources include, in addition to the World Radiation Data Centre (WRDC) in St. Petersburg, data reports from National Weather Services, data from different research networks (BSRN, ARM, SURFRAD), data published in peer-reviewed publications and data obtained through personal communications. Different quality checks are applied to check for gross errors in the dataset. GEBA is used in various research applications, such as for the quantification of the global energy balance and its spatiotemporal variation, or for the estimation of long-term trends in the surface fluxes, which enabled the detection of multi-decadal variations in surface solar radiation, known as "global dimming" and "brightening". GEBA is further extensively used for the evaluation of climate models and satellite-derived surface flux products. On a more applied level, GEBA provides the basis for engineering applications in the context of solar power generation, water management, agricultural production and tourism. GEBA is publicly accessible over the internet via www.geba.ethz.ch.

Managing the urban water-energy nexus

Science.gov (United States)

Escriva-Bou, Alvar; Pulido-Velazquez, Manuel; Lund, Jay R.

2016-04-01

Water use directly causes a significant amount of energy use in cities. In this paper we assess energy and greenhouse emissions related with each part of the urban water cycle and the consequences of several changes in residential water use for customers, water and energy utilities, and the environment. First, we develop an hourly model of urban water uses by customer category including water-related energy consumption. Next, using real data from East Bay Municipal Utility District in California, we calibrate a model of the energy used in water supply, treatment, pumping and wastewater treatment by the utility. Then, using data from the California Independent System Operator, we obtain hourly costs of energy for the energy utility. Finally, and using emission factors reported by the energy utilities we estimate greenhouse gas emissions for the entire urban water cycle. Results of the business-as-usual scenario show that water end uses account for almost 95% of all water-related energy use, but the 5% managed by the utility is still worth over 12 million annually. Several simulations analyze the potential benefits for water demand management actions showing that moving some water end-uses from peak to off-peak hours such as outdoor use, dishwasher or clothes washer use have large benefits for water and energy utilities, especially for locations with a high proportion of electric water heaters. Other interesting result is that under the current energy rate structures with low or no fixed charges, energy utilities burden most of the cost of the conservation actions.

Energy harvesting water vehicle

KAUST Repository

Singh, Devendra

2018-01-04

An efficient energy harvesting (EEH) water vehicle is disclosed. The base of the EEH water vehicle is fabricated with rolling cylindrical drums that can rotate freely in the same direction of the water medium. The drums reduce the drag at the vehicle-water interface. This reduction in drag corresponds to an increase in speed and/or greater fuel efficiency. The mechanical energy of the rolling cylindrical drums is also transformed into electrical energy using an electricity producing device, such as a dynamo or an alternator. Thus, the efficiency of the vehicle is enhanced in two parallel modes: from the reduction in drag at the vehicle-water interface, and from capturing power from the rotational motion of the drums.

Molecular Dynamics Simulation and Analysis of Interfacial Water at Selected Sulfide Mineral Surfaces under Anaerobic Conditions

Energy Technology Data Exchange (ETDEWEB)

Jin, Jiaqi; Miller, Jan D.; Dang, Liem X.

2014-04-10

In this paper, we report on a molecular dynamics simulation (MDS) study of the behavior of interfacial water at selected sulfide mineral surfaces under anaerobic conditions. The study revealed the interfacial water structure and wetting characteristics of the pyrite (100) surface, galena (100) surface, chalcopyrite (012) surface, sphalerite (110) surface, and molybdenite surfaces (i.e., the face, armchair-edge, and zigzag-edge surfaces), including simulated contact angles, relative number density profiles, water dipole orientations, hydrogen-bonding, and residence times. For force fields of the metal and sulfur atoms in selected sulfide minerals used in the MDS, we used the universal force field (UFF) and another set of force fields optimized by quantum chemical calculations for interactions with interfacial water molecules at selected sulfide mineral surfaces. Simulation results for the structural and dynamic properties of interfacial water molecules indicate the natural hydrophobic character for the selected sulfide mineral surfaces under anaerobic conditions as well as the relatively weak hydrophobicity for the sphalerite (110) surface and two molybdenite edge surfaces. Part of the financial support for this study was provided by the U.S. Department of Energy (DOE) under Basic Science Grant No. DE-FG-03-93ER14315. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the DOE, funded work performed by Liem X. Dang. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES. The authors are grateful to Professor Tsun-Mei Chang for valuable discussions.

Water Induced Surface Reconstruction of the Oxygen (2x1) covered Ru(0001)

Energy Technology Data Exchange (ETDEWEB)

Maier, Sabine; Cabrera-Sanfelix, Pepa; Stass, Ingeborg; Sanchez-Portal, Daniel; Arnau, Andres; Salmeron, Miquel

2010-08-06

Low temperature scanning tunneling microscopy (STM) and density functional theory (DFT) were used to study the adsorption of water on a Ru(0001) surface covered with half monolayer of oxygen. The oxygen atoms occupy hcp sites in an ordered structure with (2x1) periodicity. DFT predicts that water is weakly bound to the unmodified surface, 86 meV compared to the ~;;200 meV water-water H-bond. Instead, we found that water adsorption causes a shift of half of the oxygen atoms from hcp sites to fcc sites, creating a honeycomb structure where water molecules bind strongly to the exposed Ru atoms. The energy cost of reconstructing the oxygen overlayer, around 230 meV per displaced oxygen atom, is more than compensated by the larger adsorption energy of water on the newly exposed Ru atoms. Water forms hydrogen bonds with the fcc O atoms in a (4x2) superstructure due to alternating orientations of the molecules. Heating to 185 K results in the complete desorption of the water layer, leaving behind the oxygen honeycomb structure, which is metastable relative to the original (2x1). This stable structure is not recovered until after heating to temperatures close to 260K.

Modeling surface energy fluxes and thermal dynamics of a seasonally ice-covered hydroelectric reservoir.

Science.gov (United States)

Wang, Weifeng; Roulet, Nigel T; Strachan, Ian B; Tremblay, Alain

2016-04-15

The thermal dynamics of human created northern reservoirs (e.g., water temperatures and ice cover dynamics) influence carbon processing and air-water gas exchange. Here, we developed a process-based one-dimensional model (Snow, Ice, WAater, and Sediment: SIWAS) to simulate a full year's surface energy fluxes and thermal dynamics for a moderately large (>500km(2)) boreal hydroelectric reservoir in northern Quebec, Canada. There is a lack of climate and weather data for most of the Canadian boreal so we designed SIWAS with a minimum of inputs and with a daily time step. The modeled surface energy fluxes were consistent with six years of observations from eddy covariance measurements taken in the middle of the reservoir. The simulated water temperature profiles agreed well with observations from over 100 sites across the reservoir. The model successfully captured the observed annual trend of ice cover timing, although the model overestimated the length of ice cover period (15days). Sensitivity analysis revealed that air temperature significantly affects the ice cover duration, water and sediment temperatures, but that dissolved organic carbon concentrations have little effect on the heat fluxes, and water and sediment temperatures. We conclude that the SIWAS model is capable of simulating surface energy fluxes and thermal dynamics for boreal reservoirs in regions where high temporal resolution climate data are not available. SIWAS is suitable for integration into biogeochemical models for simulating a reservoir's carbon cycle. Copyright © 2016 Elsevier B.V. All rights reserved.

Modification of Surface Energy via Direct Laser Ablative Surface Patterning

Science.gov (United States)

Wohl, Christopher J., Jr. (Inventor); Belcher, Marcus A. (Inventor); Connell, John W. (Inventor); Hopkins, John W. (Inventor)

2015-01-01

Surface energy of a substrate is changed without the need for any template, mask, or additional coating medium applied to the substrate. At least one beam of energy directly ablates a substrate surface to form a predefined topographical pattern at the surface. Each beam of energy has a width of approximately 25 micrometers and an energy of approximately 1-500 microJoules. Features in the topographical pattern have a width of approximately 1-500 micrometers and a height of approximately 1.4-100 micrometers.

Surface energy anisotropy of tungsten

Energy Technology Data Exchange (ETDEWEB)

Kumar, R; Grenga, H E [Georgia Inst. of Tech., Atlanta (USA). School of Chemical Engineering

1976-10-01

Field-ion microscopy was used to study the faceting behavior and/or surface energy anisotropy of tungsten in vacuum and in hydrogen. In vacuum below 1700 K the activation energy for (110) facet growth agreed with values previously reported for surface diffusion on tungsten. The observed anisotropy values at 0.5 Tsub(m), where Tsub(m) is the absolute melting temperature of tungsten (approximately 3680 K), were different from those previously reported at higher temperatures and more nearly agreed with broken bond calculations based on Mie potential using m=5, n=8, and a 1.5% lattice expansion. Hydrogen appeared to have a negligible effect on surface energy anisotropy, but did preferentially increase surface diffusion rates on (310) regions.

Self-induced free surface oscillations caused by water jet

International Nuclear Information System (INIS)

Fukaya, M.; Madarame, H.; Okamoto, K.; Iida, M.; Someya, S.

1995-01-01

The interaction between the high speed flow and the free surfaces could induced surface oscillations. Recently, some kinds of self-induced free surface oscillations caused by water jet were discovered, e.g., a self-induced sloshing, 'Jet-Flutter' and a self-induced manometer oscillation. These oscillations have many different characteristics with each other. In this study, the similarities and differences of these oscillations are examined, and the geometrical effects on the phenomena are experimentally investigated. The self-induced sloshing and the Jet-Flutter have different dimensionless traveling times, which suggests a difference in the energy supply mechanism. When the distance between the inlet and the outlet is small in a vessel, the self-induced manometer oscillation could occur in the multi-free-surface system. (author)

Apparent Surface Free Energy of Polymer/Paper Composite Material Treated by Air Plasma

Directory of Open Access Journals (Sweden)

Konrad Terpiłowski

2017-01-01

Full Text Available Surface plasma treatment consists in changes of surface properties without changing internal properties. In this paper composite polymer/paper material is used for production of packaging in cosmetic industry. There are problems with bonding this material at the time of packaging production due to its properties. Composite surface was treated by air plasma for 1, 10, 20, and 30 s. The advancing and receding contact angles of water, formamide, and diiodomethane were measured using both treated and untreated samples. Apparent surface free energy was estimated using the hysteresis (CAH and Van Oss, Good, Chaudhury approaches (LWAB. Surface roughness was investigated using optical profilometry and identification of after plasma treatment emerging chemical groups was made by means of the XPS (X-ray photoelectron spectroscopy technique. After plasma treatment the values of contact angles decreased which is particularly evident for polar liquids. Apparent surface free energy increased compared to that of untreated samples. Changes of energy value are due to the electron-donor parameter of energy. This parameter increases as a result of adding polar groups at the time of surface plasma activation. Changes of surface properties are combination of increase of polar chemical functional groups, increase on the surface, and surface roughness increase.

Ground water and energy

Energy Technology Data Exchange (ETDEWEB)

1980-11-01

This national workshop on ground water and energy was conceived by the US Department of Energy's Office of Environmental Assessments. Generally, OEA needed to know what data are available on ground water, what information is still needed, and how DOE can best utilize what has already been learned. The workshop focussed on three areas: (1) ground water supply; (2) conflicts and barriers to ground water use; and (3) alternatives or solutions to the various issues relating to ground water. (ACR)

Climate change mitigation by recovery of energy from the water cycle: a new challenge for water management.

Science.gov (United States)

van der Hoek, J P

2012-01-01

Waternet is responsible for drinking water treatment and distribution, wastewater collection and treatment, and surface water management and control (quality and quantity) in and around Amsterdam. Waternet has the ambition to operate climate neutral in 2020. To realise this ambition, measures are required to compensate for the emission of 53,000 ton CO(2)-eq/year. Energy recovery from the water cycle looks very promising. First, calculations reveal that energy recovery from the water cycle in and around Amsterdam may contribute to a total reduction in greenhouse gas emissions up to 148,000 ton CO(2)-eq/year. The challenge for the coming years is to choose combinations of all the possibilities to fulfil the energy demand as much as possible. Only then the use of fossil fuel can be minimized and inevitable greenhouse gas emissions can be compensated, supporting the target to operate climate neutral in 2020.

Water for energy and fuel production

CERN Document Server

Shah, Yatish T

2014-01-01

Water, in all its forms, may be the key to an environmentally friendly energy economy. Water is free, there is plenty of it, plus it carries what is generally believed to be the best long-term source of green energy-hydrogen. Water for Energy and Fuel Production explores the many roles of water in the energy and fuel industry. The text not only discusses water's use as a direct source of energy and fuel-such as hydrogen from water dissociation, methane from water-based clathrate molecules, hydroelectric dams, and hydrokinetic energy from tidal waves, off-shore undercurrents, and inland waterways-but also: Describes water's benign application in the production of oil, gas, coal, uranium, biomass, and other raw fuels, and as an energy carrier in the form of hot water and steam Examines water's role as a reactant, reaction medium, and catalyst-as well as steam's role as a reactant-for the conversion of raw fuels to synthetic fuels Explains how supercritical water can be used to convert fossil- and bio-based feed...

Determining water use of sorghum from two-source energy balance and radiometric temperatures

Directory of Open Access Journals (Sweden)

J. M. Sánchez

2011-10-01

Full Text Available Estimates of surface actual evapotranspiration (ET can assist in predicting crop water requirements. An alternative to the traditional crop-coefficient methods are the energy balance models. The objective of this research was to show how surface temperature observations can be used, together with a two-source energy balance model, to determine crop water use throughout the different phenological stages of a crop grown. Radiometric temperatures were collected in a sorghum (Sorghum bicolor field as part of an experimental campaign carried out in Barrax, Spain, during the 2010 summer growing season. Performance of the Simplified Two-Source Energy Balance (STSEB model was evaluated by comparison of estimated ET with values measured on a weighing lysimeter. Errors of ±0.14 mm h⁻¹ and ±1.0 mm d⁻¹ were obtained at hourly and daily scales, respectively. Total accumulated crop water use during the campaign was underestimated by 5%. It is then shown that thermal radiometry can provide precise crop water necessities and is a promising tool for irrigation management.

The water footprint of energy consumption: an assessment of water requirements of primary energy carriers

NARCIS (Netherlands)

Gerbens-Leenes, P.W.; Hoekstra, A.Y.; Van der Meer, T.H.

2007-01-01

Gerbens-Leenes, P.W., Hoekstra, A.Y., Van der Meer, T.H., 2007. The water footprint of energy consumption: an assessment of water requirements of primary energy carriers. In: proceedings ‘First World Water Sustainability-Renewable Energy Congress and Exhibition’. 25-28 November 2007, Maastricht, the

Quantum Chemical Study of Water Adsorption on the Surfaces of SrTiO3 Nanotubes.

Science.gov (United States)

Bandura, Andrei V; Kuruch, Dmitry D; Evarestov, Robert A

2015-07-20

We have studied the adsorption of water molecules on the inner and outer surfaces of nanotubes generated by rolling (001) layers of SrTiO3 cubic crystals. The stability and the atomic and electronic structures of the adsorbed layers are determined by using hybrid density functional theory. The absorption energy and the preferred adsorbate structure are essentially governed by the nature of the surface of the nanotube. Dissociative adsorption prevails on the outer nanotube surfaces. The stability of the adsorbed layers on the inner surfaces is related to the possibility of the formation of hydrogen bonds between water molecules and surface oxygen atoms, and depends on the surface curvature. The presence of water molecules on the inner surface of the nanotubes leads to an increase of the electronic band gap. Externally TiO2 -terminated nanotubes could be used for the photocatalytic decomposition of water by ultraviolet radiation. © 2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

BALTEX water and energy budgets in the NCEP/DOE reanalysis II

Energy Technology Data Exchange (ETDEWEB)

Roads, J. [Experimental Climate Prediction Center, Scripps Institution of Oceanography, La Jolla, CA (United States); Raschke, E. [Meteorologisches Institut der Universitaet Hamburg (Germany); Rocke, B. [Institute for Coastal Research, GKSS Research Center, Geesthacht (Germany)

2002-07-01

Water and energy budgets from the National Centers for Environmental Prediction/Dept. of Energy (NCEP/DOE) reanalysis II (NCEPRII) are described for the Baltic Sea catchment and sea (BALTEX). Annually, NCEPRII shows 0.7 mm d{sup -1} of atmospheric moisture converged into the land region with a corresponding runoff of 0.7 mm d{sup -1} to the Baltic Sea, consistent with observations. However, precipitation is too low; evaporation is too large; runoff does not have an appropriate winter minimum and spring maximum; the assimilation and surface nudging are too large. Important hydroclimatic characteristics can still be discerned. During summer, atmospheric water vapor, precipitation, evaporation, and surface and atmospheric radiative heating increase and the atmospheric radiative cooling, dry static energy convergence decrease. There are large contrasts between the sea and land; during winter sensible heat is transferred from the sea to the atmosphere and sea evaporation and precipitation are largest during the fall and winter; somewhat opposite behavior occurs over land. (orig.)

Surface energy of metal alloy nanoparticles

Science.gov (United States)

Takrori, Fahed M.; Ayyad, Ahmed

2017-04-01

The measurement of surface energy of alloy nanoparticles experimentally is still a challenge therefore theoretical work is necessary to estimate its value. In continuation of our previous work on the calculation of the surface energy of pure metallic nanoparticles we have extended our work to calculate the surface energy of different alloy systems, namely, Co-Ni, Au-Cu, Cu-Al, Cu-Mg and Mo-Cs binary alloys. It is shown that the surface energy of metallic binary alloy decreases with decreasing particle size approaching relatively small values at small sizes. When both metals in the alloy obey the Hume-Rothery rules, the difference in the surface energy is small at the macroscopic as well as in the nano-scale. However when the alloy deviated from these rules the difference in surface energy is large in the macroscopic and in the nano scales. Interestingly when solid solution formation is not possible at the macroscopic scale according to the Hume-Rothery rules, it is shown it may form at the nano-scale. To our knowledge these findings here are presented for the first time and is challenging from fundamental as well as technological point of views.

Vibrational effects on surface energies and band gaps in hexagonal and cubic ice

International Nuclear Information System (INIS)

Engel, Edgar A.; Needs, Richard J.; Monserrat, Bartomeu

2016-01-01

Surface energies of hexagonal and cubic water ice are calculated using first-principles quantum mechanical methods, including an accurate description of anharmonic nuclear vibrations. We consider two proton-orderings of the hexagonal and cubic ice basal surfaces and three proton-orderings of hexagonal ice prism surfaces, finding that vibrations reduce the surface energies by more than 10%. We compare our vibrational densities of states to recent sum frequency generation absorption measurements and identify surface proton-orderings of experimental ice samples and the origins of characteristic absorption peaks. We also calculate zero point quantum vibrational corrections to the surface electronic band gaps, which range from −1.2 eV for the cubic ice basal surface up to −1.4 eV for the hexagonal ice prism surface. The vibrational corrections to the surface band gaps are up to 12% smaller than for bulk ice.

Controllability of Surface Water Networks

Science.gov (United States)

Riasi, M. Sadegh; Yeghiazarian, Lilit

2017-12-01

To sustainably manage water resources, we must understand how to control complex networked systems. In this paper, we study surface water networks from the perspective of structural controllability, a concept that integrates classical control theory with graph-theoretic formalism. We present structural controllability theory and compute four metrics: full and target controllability, control centrality and control profile (FTCP) that collectively determine the structural boundaries of the system's control space. We use these metrics to answer the following questions: How does the structure of a surface water network affect its controllability? How to efficiently control a preselected subset of the network? Which nodes have the highest control power? What types of topological structures dominate controllability? Finally, we demonstrate the structural controllability theory in the analysis of a wide range of surface water networks, such as tributary, deltaic, and braided river systems.

Water-energy, strategically interdependent

International Nuclear Information System (INIS)

Taithe, Alexandre

2014-01-01

The UN is highlighting the interdependence of water and energy. Its growth projections are impressive: +70% for electricity requirements between now and 2035 and +55% for water off-take by 2050. Right now, water has already become a major constraint for energy security in a dozen countries, including China and India, and even in several States in the USA. (author)

Groundwater–Surface Water Exchange

DEFF Research Database (Denmark)

Karan, Sachin

The exchange of groundwater-surface water has been invetigated in the western part of Denmark. Holtum AA provides the framework for all the performed investigations. Several methods are used, primarily eld based measurements ombined with numerical models to achieve insight to the governing...... processes of interaction between groundwater and surface water. By using heat as a tracer it has been possible to use temperature directly as calibrationtargets in a groundwater and heat transport model. Thus, it is possible to use heat investigate the change in groundwater discharge in dynamic conditions...... by using simple temperature devices along a stream to delineate the areas of interest in regard to GW{SW exchange. Thus, at several locations in a stream a temperature data logger was placed in the water column and right at the streambed-water interface. By looking at the correlation of streambed...

Condensation on superhydrophobic surfaces: the role of local energy barriers and structure length scale.

Science.gov (United States)

Enright, Ryan; Miljkovic, Nenad; Al-Obeidi, Ahmed; Thompson, Carl V; Wang, Evelyn N

2012-10-09

Water condensation on surfaces is a ubiquitous phase-change process that plays a crucial role in nature and across a range of industrial applications, including energy production, desalination, and environmental control. Nanotechnology has created opportunities to manipulate this process through the precise control of surface structure and chemistry, thus enabling the biomimicry of natural surfaces, such as the leaves of certain plant species, to realize superhydrophobic condensation. However, this "bottom-up" wetting process is inadequately described using typical global thermodynamic analyses and remains poorly understood. In this work, we elucidate, through imaging experiments on surfaces with structure length scales ranging from 100 nm to 10 μm and wetting physics, how local energy barriers are essential to understand non-equilibrium condensed droplet morphologies and demonstrate that overcoming these barriers via nucleation-mediated droplet-droplet interactions leads to the emergence of wetting states not predicted by scale-invariant global thermodynamic analysis. This mechanistic understanding offers insight into the role of surface-structure length scale, provides a quantitative basis for designing surfaces optimized for condensation in engineered systems, and promises insight into ice formation on surfaces that initiates with the condensation of subcooled water.

Impact of Water Withdrawals from Groundwater and Surface Water on Continental Water Storage Variations

Science.gov (United States)

Doell, Petra; Hoffmann-Dobrev, Heike; Portmann, Felix T.; Siebert, Stefan; Eicker, Annette; Rodell, Matthew; Strassberg, Gil

2011-01-01

Humans have strongly impacted the global water cycle, not only water flows but also water storage. We have performed a first global-scale analysis of the impact of water withdrawals on water storage variations, using the global water resources and use model WaterGAP. This required estimation of fractions of total water withdrawals from groundwater, considering five water use sectors. According to our assessment, the source of 35% of the water withdrawn worldwide (4300 cubic km/yr during 1998-2002) is groundwater. Groundwater contributes 42%, 36% and 27% of water used for irrigation, households and manufacturing, respectively, while we assume that only surface water is used for livestock and for cooling of thermal power plants. Consumptive water use was 1400 cubic km/yr during 1998-2002. It is the sum of the net abstraction of 250 cubic km/yr of groundwater (taking into account evapotranspiration and return flows of withdrawn surface water and groundwater) and the net abstraction of 1150 km3/yr of surface water. Computed net abstractions indicate, for the first time at the global scale, where and when human water withdrawals decrease or increase groundwater or surface water storage. In regions with extensive surface water irrigation, such as Southern China, net abstractions from groundwater are negative, i.e. groundwater is recharged by irrigation. The opposite is true for areas dominated by groundwater irrigation, such as in the High Plains aquifer of the central USA, where net abstraction of surface water is negative because return flow of withdrawn groundwater recharges the surface water compartments. In intensively irrigated areas, the amplitude of seasonal total water storage variations is generally increased due to human water use; however, in some areas, it is decreased. For the High Plains aquifer and the whole Mississippi basin, modeled groundwater and total water storage variations were compared with estimates of groundwater storage variations based on

Plasma-Assisted Synthesis and Surface Modification of Electrode Materials for Renewable Energy.

Science.gov (United States)

Dou, Shuo; Tao, Li; Wang, Ruilun; El Hankari, Samir; Chen, Ru; Wang, Shuangyin

2018-02-14

Renewable energy technology has been considered as a "MUST" option to lower the use of fossil fuels for industry and daily life. Designing critical and sophisticated materials is of great importance in order to realize high-performance energy technology. Typically, efficient synthesis and soft surface modification of nanomaterials are important for energy technology. Therefore, there are increasing demands on the rational design of efficient electrocatalysts or electrode materials, which are the key for scalable and practical electrochemical energy devices. Nevertheless, the development of versatile and cheap strategies is one of the main challenges to achieve the aforementioned goals. Accordingly, plasma technology has recently appeared as an extremely promising alternative for the synthesis and surface modification of nanomaterials for electrochemical devices. Here, the recent progress on the development of nonthermal plasma technology is highlighted for the synthesis and surface modification of advanced electrode materials for renewable energy technology including electrocatalysts for fuel cells, water splitting, metal-air batteries, and electrode materials for batteries and supercapacitors, etc. © 2018 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

SURFACE SYMMETRY ENERGY OF NUCLEAR ENERGY DENSITY FUNCTIONALS

Energy Technology Data Exchange (ETDEWEB)

Nikolov, N; Schunck, N; Nazarewicz, W; Bender, M; Pei, J

2010-12-20

We study the bulk deformation properties of the Skyrme nuclear energy density functionals. Following simple arguments based on the leptodermous expansion and liquid drop model, we apply the nuclear density functional theory to assess the role of the surface symmetry energy in nuclei. To this end, we validate the commonly used functional parametrizations against the data on excitation energies of superdeformed band-heads in Hg and Pb isotopes, and fission isomers in actinide nuclei. After subtracting shell effects, the results of our self-consistent calculations are consistent with macroscopic arguments and indicate that experimental data on strongly deformed configurations in neutron-rich nuclei are essential for optimizing future nuclear energy density functionals. The resulting survey provides a useful benchmark for further theoretical improvements. Unlike in nuclei close to the stability valley, whose macroscopic deformability hangs on the balance of surface and Coulomb terms, the deformability of neutron-rich nuclei strongly depends on the surface-symmetry energy; hence, its proper determination is crucial for the stability of deformed phases of the neutron-rich matter and description of fission rates for r-process nucleosynthesis.

Surface composition and surface properties of water hyacinth ...

African Journals Online (AJOL)

Surface composition and surface properties of water hyacinth ( Eichhornia ... (2/1, v/v) followed by ethanol, using Fourier Transform Infra-red (FT-IR) spectroscopy, ... polar organic solvents and non-polar n-alkane hydrocarbons is discussed.

Infiltration of pesticides in surface water into nearby drinking water supply wells

DEFF Research Database (Denmark)

Malaguerra, Flavio; Albrechtsen, Hans-Jørgen; Binning, Philip John

Drinking water wells are often placed near streams because streams often overly permeable sediments and the water table is near the surface in valleys, and so pumping costs are reduced. The lowering of the water table by pumping wells can reverse the natural flow from the groundwater to the stream......, inducing infiltration of surface water to groundwater and consequently to the drinking water well. Many attenuation processes can take place in the riparian zone, mainly due to mixing, biodegradation and sorption. However, if the water travel time from the surface water to the pumping well is too short......, or if the compounds are poorly degradable, contaminants can reach the drinking water well at high concentrations, jeopardizing drinking water quality. Here we developed a reactive transport model to evaluate the risk of contamination of drinking water wells by surface water pollution. The model was validated using...

Incorporating human-water dynamics in a hyper-resolution land surface model

Science.gov (United States)

Vergopolan, N.; Chaney, N.; Wanders, N.; Sheffield, J.; Wood, E. F.

2017-12-01

The increasing demand for water, energy, and food is leading to unsustainable groundwater and surface water exploitation. As a result, the human interactions with the environment, through alteration of land and water resources dynamics, need to be reflected in hydrologic and land surface models (LSMs). Advancements in representing human-water dynamics still leave challenges related to the lack of water use data, water allocation algorithms, and modeling scales. This leads to an over-simplistic representation of human water use in large-scale models; this is in turn leads to an inability to capture extreme events signatures and to provide reliable information at stakeholder-level spatial scales. The emergence of hyper-resolution models allows one to address these challenges by simulating the hydrological processes and interactions with the human impacts at field scales. We integrated human-water dynamics into HydroBlocks - a hyper-resolution, field-scale resolving LSM. HydroBlocks explicitly solves the field-scale spatial heterogeneity of land surface processes through interacting hydrologic response units (HRUs); and its HRU-based model parallelization allows computationally efficient long-term simulations as well as ensemble predictions. The implemented human-water dynamics include groundwater and surface water abstraction to meet agricultural, domestic and industrial water demands. Furthermore, a supply-demand water allocation scheme based on relative costs helps to determine sectoral water use requirements and tradeoffs. A set of HydroBlocks simulations over the Midwest United States (daily, at 30-m spatial resolution for 30 years) are used to quantify the irrigation impacts on water availability. The model captures large reductions in total soil moisture and water table levels, as well as spatiotemporal changes in evapotranspiration and runoff peaks, with their intensity related to the adopted water management strategy. By incorporating human-water dynamics in

Evaluation of surface water dynamics for water-food security in seasonal wetlands, north-central Namibia

Directory of Open Access Journals (Sweden)

T. Hiyama

2014-09-01

Full Text Available Agricultural use of wetlands is important for food security in various regions. However, land-use changes in wetland areas could alter the water cycle and the ecosystem. To conserve the water environments of wetlands, care is needed when introducing new cropping systems. This study is the first attempt to evaluate the water dynamics in the case of the introduction of rice-millet mixed-cropping systems to the Cuvelai system seasonal wetlands (CSSWs in north-central Namibia. We first investigated seasonal changes in surface water coverage by using satellite remote sensing data. We also assessed the effect of the introduction of rice-millet mixed-cropping systems on evapotranspiration in the CSSWs region. For the former investigation, we used MODIS and AMSR-E satellite remote sensing data. These data showed that at the beginning of the wet season, surface water appears from the southern (lower part and then expands to the northern (higher part of the CSSWs. For the latter investigation, we used data obtained by the classical Bowen ratio-energy balance (BREB method at an experimental field site established in September 2012 on the Ogongo campus, University of Namibia. This analysis showed the importance of water and vegetation conditions when introducing mixed-cropping to the region.

Topography and surface free energy of DPPC layers deposited on a glass, mica, or PMMA support.

Science.gov (United States)

Jurak, Malgorzata; Chibowski, Emil

2006-08-15

An investigation of energetic properties of 1,2-dipalmitoyl-sn-glycero-3-phosphocholine (DPPC) layers deposited on glass, mica, and PMMA (poly(methyl methacrylate)) surfaces was carried out by means of contact angles measurements (advancing and receding) for three probe liquids (diiodomethane, water, and formamide). DPPC was deposited on the surfaces from water (on glass and mica) or methanol (on PMMA) solutions. The topography of the tested surfaces was determined with a help of scanning electron microscopy (SEM) and atomic force microscopy (AFM). Using the measured contact angles, the total apparent surface free energy and its components of the studied layers were determined from van Oss et al.'s (Lifshitz-van der Waals and acid-base components, LWAB) and contact angle hysteresis (CAH) approaches. It allowed us to learn about changes in the surface free energy of the layers (hydrophobicity/hydrophilicity) depending on their number and kind of support. It was found that the changes in the energy greatly depended on the surface properties of the substrate as well as the statistical number of monolayers of DPPC. However, principal changes took place for first three monolayers.

Modeling Stochastic Energy and Water Consumption to Manage Residential Water Uses

Science.gov (United States)

Abdallah, A. M.; Rosenberg, D. E.; Water; Energy Conservation

2011-12-01

Water energy linkages have received growing attention from the water and energy utilities as utilities recognize that collaborative efforts can implement more effective conservation and efficiency improvement programs at lower cost with less effort. To date, limited energy-water household data has allowed only deterministic analysis for average, representative households and required coarse assumptions - like the water heater (the primary energy use in a home apart from heating and cooling) be a single end use. Here, we use recent available disaggregated hot and cold water household end-use data to estimate water and energy consumption for toilet, shower, faucet, dishwasher, laundry machine, leaks, and other household uses and savings from appliance retrofits. The disaggregated hot water and bulk water end-use data was previously collected by the USEPA for 96 single family households in Seattle WA and Oakland CA, and Tampa FL between the period from 2000 and 2003 for two weeks before and four weeks after each household was retrofitted with water efficient appliances. Using the disaggregated data, we developed a stochastic model that represents factors that influence water use for each appliance: behavioral (use frequency and duration), demographical (household size), and technological (use volume or flowrate). We also include stochastic factors that govern energy to heat hot water: hot water fraction (percentage of hot water volume to total water volume used in a certain end-use event), heater water intake and dispense temperatures, and energy source for the heater (gas, electric, etc). From the empirical household end-use data, we derive stochastic probability distributions for each water and energy factor where each distribution represents the range and likelihood of values that the factor may take. The uncertainty of the stochastic water and energy factors is propagated using Monte Carlo simulations to calculate the composite probability distribution for water

Energy and Water Efficiency on Campus | NREL

Science.gov (United States)

Energy and Water Efficiency on Campus Energy and Water Efficiency on Campus NREL ensures the resiliency of our future energy and water systems through energy efficiency strategies and technologies , renewable energy, and water efficiency on the NREL campus. FY17 Energy Intensity. The South Table Mountain

The inhibition of methane hydrate formation by water alignment underneath surface adsorption of surfactants

Energy Technology Data Exchange (ETDEWEB)

Nguyen, Ngoc N.; Nguyen, Anh V.; Dang, Liem X.

2017-06-01

Sodium dodecyl sulfate (SDS) has been widely shown to strongly promote the formation of methane hydrate. Here we show that SDS displays an extraordinary inhibition effect on methane hydrate formation when the surfactant is used in sub-millimolar concentration (around 0.3 mM). We have also employed Sum Frequency Generation vibrational spectroscopy (SFG) and molecular dynamics simulation (MDS) to elucidate the molecular mechanism of this inhibition. The SFG and MDS results revealed a strong alignment of water molecules underneath surface adsorption of SDS in its sub-millimolar solution. Interestingly, both the alignment of water and the inhibition effect (in 0.3 mM SDS solution) went vanishing when an oppositely-charged surfactant (tetra-n-butylammonium bromide, TBAB) was suitably added to produce a mixed solution of 0.3 mM SDS and 3.6 mM TBAB. Combining structural and kinetic results, we pointed out that the alignment of water underneath surface adsorption of dodecyl sulfate (DS-) anions gave rise to the unexpected inhibition of methane hydration formation in sub-millimolar solution of SDS. The adoption of TBAB mitigated the SDS-induced electrostatic field at the solution’s surface and, therefore, weakened the alignment of interfacial water which, in turn, erased the inhibition effect. We discussed this finding using the concept of activation energy of the interfacial formation of gas hydrate. The main finding of this work is to reveal the interplay of interfacial water in governing gas hydrate formation which sheds light on a universal molecular-scale understanding of the influence of surfactants on gas hydrate formation. This work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences. The calculations were carried out using computer resources provided by the Office of Basic Energy Sciences.

Influence of air-powder polishing on bond strength and surface-free energy of universal adhesive systems.

Science.gov (United States)

Tamura, Yukie; Takamizawa, Toshiki; Shimamura, Yutaka; Akiba, Shunsuke; Yabuki, Chiaki; Imai, Arisa; Tsujimoto, Akimasa; Kurokawa, Hiroyasu; Miyazaki, Masashi

2017-11-29

The influences of air-powder polishing with glycine or sodium bicarbonate powders on shear bond strengths (SBS) and surface-free energies of universal adhesives were examined. Scotchbond Universal Adhesive (SU, 3M ESPE), G-Premio Bond (GP, GC), Adhese Universal (AU, Ivoclar Vivadent), and All-Bond Universal (AB, Bisco) were used in this study. Bovine dentin surfaces were air polished with glycine or sodium bicarbonate powders prior to the bonding procedure, and resin pastes were bonded to the dentin surface using universal adhesives. SBSs were determined after 24-h storage in distilled water at 37°C. Surface-free energy was then determined by measuring contact angles using three test liquids on dentin surfaces. Significantly lower SBSs were observed for dentin that was air-powder polished and surface-free energies were concomitantly lowered. This study indicated that air-powder polishing influences SBSs and surface-free energies. However, glycine powder produced smaller changes in these surface parameters than sodium bicarbonate.

First principles study of dissolved oxygen water adsorption on Fe (001 surfaces

Directory of Open Access Journals (Sweden)

Dong ZHANG

2018-02-01

Full Text Available In order to study the mechanism of dissolved oxygen content on the surface corrosion behavior of Fe-based heat transfer, the first principle is used to study the adsorption of O2 monomolecular, H2O monolayer and dissolved oxygen system on Fe-based heat transfer surface. The GGA/PBE approximation is used to calculate the adsorption energy, state density and population change during the adsorption process. Calculations prove that when the dissolved oxygen is adsorbed on the Fe-based surface, the water molecule tends to adsorb at the top sites, and the oxygen molecule tends to adsorb at Griffiths. When the H2O molecule adsorbs and interacts on the Fe (001 surface, the charge distribution of the interfacial double electric layer changes to cause the Fe atoms to lose electrons, resulting in the change of the surface potential. When the O2 molecule adsorbs on the Fe (001 crystal surfaces, the electrons on the Fe (001 surface are lost and the surface potential increases. O2 molecule and the surface of the Fe atoms are prone to electron transfer, in which O atom's 2p orbit for the adsorption of O2 molecule on Fe (001 crystal surface play a major role. With the increase of the proportion of O2 molecule in the dissolved oxygen water, the absolute value of the adsorption energy increases, and the interaction of the Fe-based heat transfer surface is stronger. This study explores the influence law of different dissolved oxygen on the Fe base heat exchange surface corrosion, and the base metal corrosion mechanism for experimental study provides a theoretical reference.

The adsorption and dissociation of water molecule on goethite (010) surface: A DFT approach

Energy Technology Data Exchange (ETDEWEB)

Zhou, Long, E-mail: shuweixia@ouc.edu.cn [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, College of Chemistry and Chemical Engineering (China); Xiu, Fangyuan [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, College of Chemistry and Chemical Engineering (China); Qiu, Meng [Qingdao Institute of Bioenergy and Bioprocess Technology (China); Xia, Shuwei; Yu, Liangmin [Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, College of Chemistry and Chemical Engineering (China)

2017-01-15

Graphical abstract: The optimized structure of hydrated goethite (010) surface with medium water coverage (water density about 6.7 H{sub 2}O/nm{sup 2}). - Highlights: • Stable adsorption and dissociation structure of H{sub 2}O on goethite (010) surface was investigated by DFT. • Reasonable path for water dissociation was proposed by transitional state analysis. • The mechanism of water adsorption on goethite and binding nature were revealed by PDOS. - Abstract: Using density functional theory (DFT) calculation, we investigate the configuration, stability and electronic properties of fresh cleaved (010) goethite surface (Pnma) and this surface exposed to water monolayer at low, medium and high coverage. Water is predicted to be chemisorbed to the surface, together with the surface reconstruction. The interaction energy of the most stable configuration of both low and medium coverage per water molecule is almost the same (−1.17 eV), while that of high coverage is much lower (less than 1.03 eV). It indicates that highly hydrated surface is less stable. PDOS analysis reveals the adsorption of H{sub 2}O is due to the formation of Fe−O bond, caused by overlapping of Fe's 3d and O's 2p orbitals. Dissociation processes at low and medium water coverage are non-spontaneous; while at high coverage, it can undertake spontaneously both thermodynamically and dynamically. The dissociation paths of all three water coverage are the similar. The proton from one adsorbed water is likely to dissociate to bind to the vicinal surface μ{sub 3}−O as an intermediate product; the proton belonged to μ{sub 3}−O transferred to the neighbor surface μ{sub 2}−O as the dissociative configuration.

Waste water treatment in surface mines

Energy Technology Data Exchange (ETDEWEB)

Navasardyants, M A; Esipov, V Z; Ryzhkov, Yu A

1981-01-01

This paper evaluates problems associated with waste water from coal surface mines of the Kemerovougol' association in the Kuzbass. Waste water treatment in the Kuzbass is of major importance as the region is supplied with water from only one river, the Tom river. Water influx to Kemerovougol' surface mines in a year amounts to 136 million m/sup 3/. The water is used during technological processes, for fire fighting, and spraying to prevent dusting; the rest, about 82.1 million m/sup 3/, is discharged into surface waters. Of this amount, 25.1 million m/sup 3/ is heavily polluted water, 46.6 million m3 are polluted but within limits, and 10.4 million m/sup 3/ are characterized as relatively clean. Waste water is polluted with: suspended matters, oils and oil products, nitrates, nitrides and chlorides. Suspended matter content sometimes reaches 4,000 and 5,000 mg/l, and oil product content in water amounts to 2.17 mg/l. Water treatment in surface mines is two-staged: sumps and sedimentation tanks are used. Water with suspended matter content of 50 to 100 mg/l in winter and summer, and 200 to 250 mg/l in spring and autumn is reduced in sumps to 25 to 30 mg/l in summer and winter and to 40 to 50 mg/l in autumn and spring. During the first stage water treatment efficiency ranges from 50 to 80%. During the second stage water is collected in sedimentation tanks. It is noted that so-called secondary pollution is one of the causes of the relatively high level of suspended matter in discharged water. Water discharged from sedimentation tanks carries clay and loam particles from the bottom and walls of water tanks and channels.

Ancient water supports today's energy needs

Science.gov (United States)

D'Odorico, Paolo; Natyzak, Jennifer L.; Castner, Elizabeth A.; Davis, Kyle F.; Emery, Kyle A.; Gephart, Jessica A.; Leach, Allison M.; Pace, Michael L.; Galloway, James N.

2017-05-01

The water footprint for fossil fuels typically accounts for water utilized in mining and fuel processing, whereas the water footprint of biofuels assesses the agricultural water used by crops through their lifetime. Fossil fuels have an additional water footprint that is not easily accounted for: ancient water that was used by plants millions of years ago, before they were transformed into fossil fuel. How much water is mankind using from the past to sustain current energy needs? We evaluate the link between ancient water virtually embodied in fossil fuels to current global energy demands by determining the water demand required to replace fossil fuels with biomass produced with water from the present. Using equal energy units of wood, bioethanol, and biodiesel to replace coal, natural gas, and crude oil, respectively, the resulting water demand is 7.39 × 1013 m3 y-1, approximately the same as the total annual evaporation from all land masses and transpiration from all terrestrial vegetation. Thus, there are strong hydrologic constraints to a reliance on biofuel energy produced with water from the present because the conversion from fossil fuels to biofuels would have a disproportionate and unsustainable impact on the modern water. By using fossil fuels to meet today's energy needs, we are virtually using water from a geological past. The water cycle is insufficient to sustain the production of the fuel presently consumed by human societies. Thus, non-fuel-based renewable energy sources are needed to decrease mankind's reliance on fossil fuel energy without placing an overwhelming pressure on global freshwater resources.

The puckering free-energy surface of proline

Directory of Open Access Journals (Sweden)

Di Wu

2013-03-01

Full Text Available Proline has two preferred puckering states, which are often characterized by the pseudorotation phase angle and amplitude. Although proline's five endocyclic torsion angles can be utilized to calculate the phase angle and amplitude, it is not clear if there is any direct correlation between each torsion angle and the proline-puckering pathway. Here we have designed five proline puckering pathways utilizing each torsion angle χj (j = 1∼5 as the reaction coordinate. By examining the free-energy surfaces of the five puckering pathways, we find they can be categorized into two groups. The χ2 pathway (χ2 is about the Cβ—Cγ bond is especially meaningful in describing proline puckering: it changes linearly with the puckering amplitude and symmetrically with the phase angle. Our results show that this conclusion applies to both trans and cis proline conformations. We have also analyzed the correlations of proline puckering and its backbone torsion angles ϕ and ψ. We show proline has preferred puckering states at the specific regions of ϕ, ψ angles. Interestingly, the shapes of ψ-χ2 free-energy surfaces are similar among the trans proline in water, cis proline in water and cis proline in the gas phase, but they differ substantially from that of the trans proline in the gas phase. Our calculations are conducted using molecular simulations; we also verify our results using the proline conformations selected from the Protein Data Bank. In addition, we have compared our results with those calculated by the quantum mechanical methods.

Effect of surface modification on the corrosion resistivity in supercritical water

International Nuclear Information System (INIS)

Penttila, S.; Horvath, A.; Toivonen, A.; Zolnai, Z.

2011-01-01

This paper summarizes the results of high temperature corrosion studies of the candidate austenitic alloys at relevant operating conditions for SCWR. The high temperature and pressure above the thermodynamic critical point of water result in higher oxidation rate which might be critical for thin-wall components like fuel cladding. The goal of this work was to study the effect of surface preparation on the oxidation rate on Ti-stabilized austenitic alloy 1.4970. Surfaces were prepared with ion implantation using He"+- and N"+-ions. Samples were immersed in supercritical water at 650"oC/25 MPa, for up to 2000 hours. Added to this, conventional surface treatments were conducted for austenitic alloy 316L tube samples in order to study the effect of cold work in sample surface on corrosion resistance. The corrosion rate was evaluated by measuring the weight change of the samples. The compositions of the oxide layers were analyzed using scanning electron microscope (SEM) in conjunction with Energy Dispersive Spectroscopy (EDS). (author)

Lawrence Livermore National Laboratory Surface Water Protection: A Watershed Approach

Energy Technology Data Exchange (ETDEWEB)

Coty, J

2009-03-16

This surface water protection plan (plan) provides an overview of the management efforts implemented at Lawrence Livermore National Laboratory (LLNL) that support a watershed approach to protect surface water. This plan fulfills a requirement in the Department of Energy (DOE) Order 450.1A to demonstrate a watershed approach for surface water protection that protects the environment and public health. This plan describes the use of a watershed approach within which the Laboratory's current surface water management and protections efforts have been structured and coordinated. With more than 800 million acres of land in the U.S. under federal management and stewardship, a unified approach across agencies provides enhanced resource protection and cost-effectiveness. The DOE adopted, along with other federal agencies, the Unified Federal Policy for a Watershed Approach to Federal Land and Resource Management (UFP) with a goal to protect water quality and aquatic ecosystems on federal lands. This policy intends to prevent and/or reduce water pollution from federal activities while fostering a cost-effective watershed approach to federal land and resource management. The UFP also intends to enhance the implementation of existing laws (e.g., the Clean Water Act [CWA] and National Environmental Policy Act [NEPA]) and regulations. In addition, this provides an opportunity for the federal government to serve as a model for water quality stewardship using a watershed approach for federal land and resource activities that potentially impact surface water and its uses. As a federal land manager, the Laboratory is responsible for a small but important part of those 800 million acres of land. Diverse land uses are required to support the Laboratory's mission and provide an appropriate work environment for its staff. The Laboratory comprises two sites: its main site in Livermore, California, and the Experimental Test Site (Site 300), near Tracy, California. The main site

Surface free energy of polypropylene and polycarbonate solidifying at different solid surfaces

International Nuclear Information System (INIS)

Chibowski, Emil; Terpilowski, Konrad

2009-01-01

Advancing and receding contact angles of water, formamide, glycerol and diiodomethane were measured on polypropylene (PP) and polycarbonate (PC) sample surfaces which solidified at Teflon, glass or stainless steel as matrix surfaces. Then from the contact angle hystereses (CAH) the apparent free energies γ s tot of the surfaces were evaluated. The original PP surface is practically nonpolar, possessing small electron donor interaction (γ s - =1.91mJ/m 2 ), as determined from the advancing contact angles of these liquids. It may result from impurities of the polymerization process. However, it increases up to 8-10 mJ/m 2 for PP surfaces contacted with the solids. The PC surfaces both original and modified show practically the same γ s - =6.56.7mJ/m 2 . No electron acceptor interaction is found on the surfaces. The γ s tot of modified PP and PC surfaces depend on the kind of probe liquid and contacted solid surface. The modified PP γ s tot values determined from CAH of polar liquids are greater than that of original surface and they increase in the sequence: Teflon, glass, stainless steel surface, at which they solidified. No clear dependence is observed between γ s tot and dielectric constant or dipole moment of the polar probe liquids. The changes in γ s tot of the polymer surfaces are due to the polymer nature and changes in its surface structure caused by the structure and force field of the contacting solid. It has been confirmed by AFM images.

Wetland Water Cooling Partnership: The Use of Constructed Wetlands to Enhance Thermoelectric Power Plant Cooling and Mitigate the Demand of Surface Water Use

Energy Technology Data Exchange (ETDEWEB)

Apfelbaum, Steven L. [Applied Ecological Services Inc., Brodhead, WI (United States); Duvall, Kenneth W. [Sterling Energy Services, LLC, Atlanta, GA (United States); Nelson, Theresa M. [Applied Ecological Services Inc., Brodhead, WI (United States); Mensing, Douglas M. [Applied Ecological Services Inc., Brodhead, WI (United States); Bengtson, Harlan H. [Sterling Energy Services, LLC, Atlanta, GA (United States); Eppich, John [Waterflow Consultants, Champaign, IL (United States); Penhallegon, Clayton [Sterling Energy Services, LLC, Atlanta, GA (United States); Thompson, Ry L. [Applied Ecological Services Inc., Brodhead, WI (United States)

2013-12-01

Through the Phase I study segment of contract #DE-NT0006644 with the U.S. Department of Energy’s National Energy Technology Laboratory, Applied Ecological Services, Inc. and Sterling Energy Services, LLC (the AES/SES Team) explored the use of constructed wetlands to help address stresses on surface water and groundwater resources from thermoelectric power plant cooling and makeup water requirements. The project objectives were crafted to explore and develop implementable water conservation and cooling strategies using constructed wetlands (not existing, naturally occurring wetlands), with the goal of determining if this strategy has the potential to reduce surface water and groundwater withdrawals of thermoelectric power plants throughout the country. Our team’s exploratory work has documented what appears to be a significant and practical potential for augmenting power plant cooling water resources for makeup supply at many, but not all, thermoelectric power plant sites. The intent is to help alleviate stress on existing surface water and groundwater resources through harvesting, storing, polishing and beneficially re-using critical water resources. Through literature review, development of conceptual created wetland plans, and STELLA-based modeling, the AES/SES team has developed heat and water balances for conventional thermoelectric power plants to evaluate wetland size requirements, water use, and comparative cooling technology costs. The ecological literature on organism tolerances to heated waters was used to understand the range of ecological outcomes achievable in created wetlands. This study suggests that wetlands and water harvesting can provide a practical and cost-effective strategy to augment cooling waters for thermoelectric power plants in many geographic settings of the United States, particularly east of the 100th meridian, and in coastal and riverine locations. The study concluded that constructed wetlands can have significant positive

Indices of quality surface water bodies in the planning of water resources

Directory of Open Access Journals (Sweden)

Rodríguez-Miranda, Juan Pablo

2016-12-01

Full Text Available This paper considers a review of the literature major and significant methods of quality indices of water applied in surface water bodies, used and proposed for assessing the significance of parameters of water quality in the assessment of surface water currents and they are usually used in making decisions for intervention and strategic prevention measures for those responsible for the conservation and preservation of watersheds where these water bodies belong. An exploratory methodology was applied to realize the conceptualization of each water quality index. As a result, it is observed that there are several important methods for determining the water quality index applied in surface water bodies.

Measuring surface energy and evapotranspiration across Caribbean mangrove forests

Science.gov (United States)

Lagomasino, D.; Fatoyinbo, T. E.; Price, R.

2014-12-01

Coastal mangroves lose large amounts of water through evapotranspiration (ET) that can be equivalent to the amount of annual rainfall in certain years. Satellite remote sensing has been used to estimate surface energy and ET variability in many forested ecosystems, yet has been widely overlooked in mangrove forests. Using a combination of long-term datasets (30-year) acquired from the NASA Landsat 5 and 7 satellite databases, the present study investigated ET and surface energy balance variability between two mangrove forest sites in the Caribbean: 1) Everglades National Park (ENP; Florida, USA) and 2) Sian Ka'an Biosphere Reserve (SKBR; Quintana Roo, Mexico). A satellite-derived surface energy balance model was used to estimate ET in tall and scrub mangroves environments at ENP and SKBR. Results identified significant differences in soil heat flux measurements and ET between the tall and scrub mangrove environments. Scrub mangroves exhibited the highest soil heat flux coincident with the lowest biophysical indices (i.e., Fractional Vegetation Cover, Normalized Difference Vegetation Index, and Soil-Adjusted Vegetation Index) and ET rates. Mangrove damage and mortality was observed on the satellite images following strong tropical storms and associated with anthropogenic modifications and resulted in low values in spectral vegetation indices, higher soil heat flux, and higher ET. Recovery of the spectral characteristics, soil heat flux and ET was within 1-2 years following hurricane disturbance while, degradation caused by human disturbance persisted for many years. Remotely sensed ET of mangrove forests can provide estimates over a few decades and provide us with some understanding of how these environments respond to disturbances to the landscape in periods where no ground data exists or in locations that are difficult to access. Moreover, relationships between energy and water balance components developed for the coastal mangroves of Florida and Mexico could be

China energy-water nexus: Assessing the water-saving synergy effects of energy-saving policies during the eleventh Five-year Plan

International Nuclear Information System (INIS)

Gu, Alun; Teng, Fei; Wang, Yu

2014-01-01

Highlights: • Energy and water limit China’s sustainable development. • Current energy policies fail to address water saving issues. • The energy-water coefficient is estimated for both direct use and indirect use. • Water saving effects associated with energy-saving policies is calculated. • Water-energy nexus should be enhanced in key industrial sectors. - Abstract: Energy and water have become major factors limiting sustainable development in China. Energy efficiency and optimization of water management are critical for the healthy growth of the Chinese economy. Current national energy policies fail to adequately address water use issues. Similarly, current water policies do not consider the impact of energy consumption and greenhouse gas emissions. Consequently, few studies have investigated the relationship between energy consumption and water use. The present study analyzes the energy-water nexus in Chinese industries using input–output tables. Coefficients that characterize the relationship between energy consumption and water are used to describe the supply-consumption relationship between the water supply and primary energy sectors. Next, we calculate the water-saving effects associated with the enforcement of energy-saving policies in selected industrial sectors during the eleventh Five-year Plan, from 2005 to 2010. These calculations address the ferrous metals, non-ferrous metals, petrochemical engineering, building materials, and electricity industries as well as key light industries. Our findings indicate that energy-saving efforts in these industries will result in savings in water consumption. This study suggests that a cooperative relationship between water and energy conservation efforts should be an important factor in creating policies that encourage simultaneous savings of both resources. Additionally, the study indicates that government should promote water- and energy-saving techniques in key industrial sectors to encourage

Convergent surface water distributions in U.S. cities

Science.gov (United States)

M.K. Steele; J.B. Heffernan; N. Bettez; J. Cavender-Bares; P.M. Groffman; J.M. Grove; S. Hall; S.E. Hobbie; K. Larson; J.L. Morse; C. Neill; K.C. Nelson; J. O' Neil-Dunne; L. Ogden; D.E. Pataki; C. Polsky; R. Roy Chowdhury

2014-01-01

Earth's surface is rapidly urbanizing, resulting in dramatic changes in the abundance, distribution and character of surface water features in urban landscapes. However, the scope and consequences of surface water redistribution at broad spatial scales are not well understood. We hypothesized that urbanization would lead to convergent surface water abundance and...

Monitoring of Water and Contaminant Migration at the Groundwater-Surface Water Interface

Science.gov (United States)

2008-08-01

seepage is occurring in a freshwater lake environment and to map the lateral extent of any subsurface contamination at the groundwater –surface water ...and Contaminant Migration at the Groundwater -Surface Water Interface August 2008 Report Documentation Page Form ApprovedOMB No. 0704-0188 Public...4. TITLE AND SUBTITLE Monitoring of Water and Contaminant Migration at the Groundwater -Surface Water Interface 5a. CONTRACT NUMBER 5b. GRANT NUMBER

Energy and water exchange from a saline-sodic overburden restoration cover, Fort McMurray, Alberta

International Nuclear Information System (INIS)

Carey, S.

2006-01-01

The Canadian oil sand mining industry takes responsibility for restoring mining areas to an equivalent level that existed before mining occurred. During this process, the surface-vegetation-atmosphere continuum is dramatically altered, creating few similarities to the boreal forest that existed prior to mining. Using the eddy covariance method, a study of the integrated salt and water balance of a saline-sodic overburden pile at Syncrude Canada Ltd.'s Mildred Lake mine north of Fort McMurray, Alberta was undertaken in order to measure the surface energy balance for three summers (2003 - 2005) with different climatic and phenological conditions. The objective of this study was to document how evapotranspiration and energy partitioning varied inter-annually during the growing season atop the restoration cover and to relate the portioning of energy at the surface to environmental and physiological variables. The paper described the site and measurement specifics and also presented the results and discussion. Results were organized under the following topics: climate; soil moisture and suction; leaf area index and vegetation; surface energy balance; evapotranspiration; and controls on evapotranspiration. It was concluded that results from this study have important implications for recovery strategies, as the availability water for plant growth, the movement and migration of salts and percolating water for deep drainage all depend on accurate quantification of evapotranspiration. 9 refs., 1 tab

Experimental and numerical investigations of the impingement of an oblique liquid jet onto a superhydrophobic surface: energy transformation

Energy Technology Data Exchange (ETDEWEB)

Kibar, Ali, E-mail: alikibar@kocaeli.edu.tr [Department of Mechanical and Material Technologies, Kocaeli University, 41285, Arslanbey Campus, Kocaeli (Turkey)

2016-02-15

This study presents the theory of impinging an oblique liquid jet onto a vertical superhydrophobic surface based on both experimental and numerical results. A Brassica oleracea leaf with a 160° apparent contact angle was used for the superhydrophobic surface. Distilled water was sent onto the vertical superhydrophobic surface in the range of 1750–3050 Reynolds number, with an inclination angle of 20°−40°, using a circular glass tube with a 1.75 mm inner diameter. The impinging liquid jet spread onto the surface governed by the inertia of the liquid and then reflected off the superhydrophobic surface due to the surface energy of the spreading liquid. Two different energy approaches, which have time-scale and per-unit length, were performed to determine transformation of the energy. The kinetic energy of the impinging liquid jet was transformed into the surface energy with an increasing interfacial surface area between the liquid and air during spreading. Afterwards, this surface energy of the spreading liquid was transformed into the reflection kinetic energy. (paper)

Greenhouse gas and energy co-benefits of water conservation[Water Sustainability Project

Energy Technology Data Exchange (ETDEWEB)

Maas, C.

2009-03-15

Energy is needed to deliver water to, within and from communities to remove contaminants from water and wastewater, and to heat water in homes. The interconnections between water and energy are referred to as the water-energy nexus. Large volumes of water are needed to generate energy, notably to power turbines, to cool thermal or nuclear energy plants, and to extract oil from tar sands. At the same time, large amounts of energy are needed to pump, treat, heat and distribute water for urban, industrial and agricultural use and to collect and treat the resulting wastewater. The two sides of the water-energy nexus are generating new research and policy proposals to address the challenges of climate change, energy security and increasing water scarcity. This report demonstrated that a large untapped opportunity exists for water conservation to reduce energy, municipal costs and greenhouse gas (GHG) emissions. The water-energy research in this study was based on a Soft Path for Water approach that incorporated facets of water demand management while moving beyond a short-term focus on cost-benefit criteria to examine how the services currently provided by water can be delivered to meet the need for economic, social and ecological sustainability. Although the research was conducted using data for municipalities in Ontario, the report is relevant to the rest of Canada and much of North America. Water conservation strategies included water efficiency measures such as high efficiency toilets and washing machines, as well as water saving measures such as xeriscaping and rainwater harvesting. The objectives of the study were to quantify the energy use associated with each component of the urban water use cycle and to determine the potential for energy and GHG emissions reductions associated with water conservation strategies. This report provided an overview of energy inputs needed for water provision. It outlined the methodology used to achieve the project objectives and

The energy-water nexus: are there tradeoffs between residential energy and water consumption in arid cities?

Science.gov (United States)

Ruddell, Darren M; Dixon, P Grady

2014-09-01

Water scarcity, energy consumption, and air temperature regulation are three critical resource and environmental challenges linked to urban population growth. While appliance efficiency continues to increase, today's homes are larger and residents are using more energy-consuming devices. Recent research has often described the energy-water nexus as a "tradeoff" between energy and water due to reduced temperatures resulting from irrigated vegetation. Accordingly, some arid cities have implemented landscape-conversion programs that encourage homeowners to convert their yards from grass (mesic) to drought-tolerant (xeric) landscapes to help conserve water resources. We investigated these relationships in Phoenix, Arizona by examining energy and water data for the summer months of June-September 2005 while temperature variability was analyzed from a local heat wave. Results show parallel consumption patterns with energy and water use strongly correlated and newer homes using more of both. The counterintuitive findings show that "drought-resistant" models may not be beneficial for community health, environment, or economics and that this issue is further complicated by socio-economic variables.

Geometric and energetic considerations of surface fluctuations during ion transfer across the water-immiscible organic liquid interface

Energy Technology Data Exchange (ETDEWEB)

Karnes, John J.; Benjamin, Ilan, E-mail: benjamin@chemistry.ucsc.edu [Department of Chemistry and Biochemistry, University of California, Santa Cruz, California 95064 (United States)

2016-07-07

Molecular dynamics simulations and umbrella sampling free energy calculations are used to examine the thermodynamics, energetics, and structural fluctuations that accompany the transfer of a small hydrophilic ion (Cl{sup −}) across the water/nitrobenzene interface. By examining several constrained interface structures, we isolate the energetic costs of interfacial deformation and co-transfer of hydration waters during the ion transfer. The process is monitored using both energy-based solvation coordinates and a geometric coordinate recently introduced by Morita and co-workers to describe surface fluctuations. Our simulations show that these coordinates provide a complimentary description of the water surface fluctuations during the transfer and are necessary for elucidating the mechanism of the ion transfer.

Instability of confined water films between elastic surfaces.

Science.gov (United States)

de Beer, Sissi; 't Mannetje, Dieter; Zantema, Sietske; Mugele, Frieder

2010-03-02

We investigated the dynamics of nanometer thin water films at controlled ambient humidity adsorbed onto two atomically smooth mica sheets upon rapidly bringing the surfaces into contact. Using a surface forces apparatus (SFA) in imaging mode, we found that the water films break up into a distribution of drops with a typical thickness of a few nanometers and a characteristic lateral size and spacing of several micrometers. Whereas the characteristic length is found to be independent of the ambient humidity, the characteristic time of the breakup decreases from approximately 1 to 0.01 s with increasing humidity. The existence of characteristic length and time scales shows that this breakup is controlled by an instability rather than a conventional nucleation and growth mechanism for SFA experiments. These findings cannot be explained by a dispersion-driven instability mechanism. In contrast, a model involving the elastic energies for the deformation of both the mica sheets and the underlying glue layer correctly reproduces the scaling of the characteristic length and time with humidity.

Underground coal mine subsidence impacts on surface water

International Nuclear Information System (INIS)

Stump, D.E. Jr.

1992-01-01

This paper reports that subsidence from underground coal mining alters surface water discharge and availability. The magnitude and areal extent of these impacts are dependent on many factors, including the amount of subsidence, topography, geology, climate, surface water - ground water interactions, and fractures in the overburden. There alterations may have positive and/or negative impacts. One of the most significant surface water impacts occurred in July 1957 near West Pittston, Pennsylvania. Subsidence in the Knox Mine under the Coxton Yards of the Lehigh Valley Railroad allowed part of the discharge in the Susquehanna River to flow into the mine and create a crater 200 feet in diameter and 300 feet deep. Fourteen railroad gondola cars fell into the hole which was eventually filled with rock, sand, and gravel. Other surface water impacts from subsidence may include the loss of water to the ground water system, the gaining of water from the ground water system, the creation of flooded subsidence troughs, the increasing of impoundment storage capacity, the relocation of water sources (springs), and the alteration of surface drainage patterns

Adopting a Water-Food-Energy nexus approach to explore the synergies and trade-offs of food-water policies in Spain

Science.gov (United States)

Willaarts, Barbara; Lechon, Yolanda; de la Rúa, Cristina; Garrido, Alberto

2016-04-01

Spain is a semi-arid country and faces a strong competition over scarce water resources by the different sectors. Agriculture is the largest water consumer and because of this it is often at the core of much of the disputes over water. Several policy measures have been implemented in the course of the last decades to ameliorate water scarcity problems. The irrigation modernization plan is probably one of the most ambitious plans implemented so far (with a total investment of nearly 3,800 mill € involving the modernization of over 1 million irrigated ha), and was developed with the double aim of increasing the efficiency of agricultural water use and strength the resilience and competitiveness of the Spanish irrigation sector. In this research we examine the implications of the irrigation modernization plan by adopting a nexus approach. In particular we assess the trends in water, land and energy footprints associated to agriculture during the period 2000-2011 to evaluate the effectiveness of the plan. Likewise, we used a life cycle analysis approach to assess the implications in terms of greenhouse gas emissions (GHG). Our results show that the land footprint of irrigated agriculture has increased 2% (from 3.4 mill ha in 2000 to 3,6 mill ha in 2011). Meanwhile, the water footprint of irrigated agriculture has decreased by 8% (from 17,078 hm3 in 2000 to 15,573 hm3 in 2011). Beyond the net water savings, there has been a major shift in the composition of the water footprint. In the year 2000, 77% of the blue agricultural water footprint was linked to surface water, while in the year 2011 over 55% of the water consumed by agriculture is groundwater. The modernization of irrigation technologies alongside with the shift from a predominantly surface water footprint to groundwater has boosted the energy footprint of irrigation by 56% (2442 GWh in 2000 to 3803 GWh in 2011). This rise in the energy bill has meant an increase of 9% in the GHG emissions. Yet, this GHG

Analysis of energy flow during playground surface impacts.

Science.gov (United States)

Davidson, Peter L; Wilson, Suzanne J; Chalmers, David J; Wilson, Barry D; Eager, David; McIntosh, Andrew S

2013-10-01

The amount of energy dissipated away from or returned to a child falling onto a surface will influence fracture risk but is not considered in current standards for playground impact-attenuating surfaces. A two-mass rheological computer simulation was used to model energy flow within the wrist and surface during hand impact with playground surfaces, and the potential of this approach to provide insights into such impacts and predict injury risk examined. Acceleration data collected on-site from typical playground surfaces and previously obtained data from children performing an exercise involving freefalling with a fully extended arm provided input. The model identified differences in energy flow properties between playground surfaces and two potentially harmful surface characteristics: more energy was absorbed by (work done on) the wrist during both impact and rebound on rubber surfaces than on bark, and rubber surfaces started to rebound (return energy to the wrist) while the upper limb was still moving downward. Energy flow analysis thus provides information on playground surface characteristics and the impact process, and has the potential to identify fracture risks, inform the development of safer impact-attenuating surfaces, and contribute to development of new energy-based arm fracture injury criteria and tests for use in conjunction with current methods.

Thermodynamic analysis of water molecules at the surface of proteins and applications to binding site prediction and characterization.

Science.gov (United States)

Beuming, Thijs; Che, Ye; Abel, Robert; Kim, Byungchan; Shanmugasundaram, Veerabahu; Sherman, Woody

2012-03-01

Water plays an essential role in determining the structure and function of all biological systems. Recent methodological advances allow for an accurate and efficient estimation of the thermodynamic properties of water molecules at the surface of proteins. In this work, we characterize these thermodynamic properties and relate them to various structural and functional characteristics of the protein. We find that high-energy hydration sites often exist near protein motifs typically characterized as hydrophilic, such as backbone amide groups. We also find that waters around alpha helices and beta sheets tend to be less stable than waters around loops. Furthermore, we find no significant correlation between the hydration site-free energy and the solvent accessible surface area of the site. In addition, we find that the distribution of high-energy hydration sites on the protein surface can be used to identify the location of binding sites and that binding sites of druggable targets tend to have a greater density of thermodynamically unstable hydration sites. Using this information, we characterize the FKBP12 protein and show good agreement between fragment screening hit rates from NMR spectroscopy and hydration site energetics. Finally, we show that water molecules observed in crystal structures are less stable on average than bulk water as a consequence of the high degree of spatial localization, thereby resulting in a significant loss in entropy. These findings should help to better understand the characteristics of waters at the surface of proteins and are expected to lead to insights that can guide structure-based drug design efforts. Copyright © 2011 Wiley Periodicals, Inc.

Biomimicry using Nano-Engineered Enhanced Condensing Surfaces for Sustainable Fresh Water Technology

OpenAIRE

Al-Beaini, Sara

2012-01-01

Biomimicry offers innovative sustainable solutions for many dire resource-based challenges. The Namib Desert beetle (sp. Stenocara) invites us to explore how we can collect fresh water more energy-efficiently. The beetle's unique back features with alternating hydrophobic-hydrophilic regions, aid its survival in a water scarce desert environment. We investigated the feasibility for enhanced condensation by patterning a zinc oxide (ZnO) surface to mimic the beetle's back. ZnO was selected as t...

The Global Energy Balance Archive (GEBA) version 2017: a database for worldwide measured surface energy fluxes

Science.gov (United States)

Wild, Martin; Ohmura, Atsumu; Schär, Christoph; Müller, Guido; Folini, Doris; Schwarz, Matthias; Zyta Hakuba, Maria; Sanchez-Lorenzo, Arturo

2017-08-01

The Global Energy Balance Archive (GEBA) is a database for the central storage of the worldwide measured energy fluxes at the Earth's surface, maintained at ETH Zurich (Switzerland). This paper documents the status of the GEBA version 2017 dataset, presents the new web interface and user access, and reviews the scientific impact that GEBA data had in various applications. GEBA has continuously been expanded and updated and contains in its 2017 version around 500 000 monthly mean entries of various surface energy balance components measured at 2500 locations. The database contains observations from 15 surface energy flux components, with the most widely measured quantity available in GEBA being the shortwave radiation incident at the Earth's surface (global radiation). Many of the historic records extend over several decades. GEBA contains monthly data from a variety of sources, namely from the World Radiation Data Centre (WRDC) in St. Petersburg, from national weather services, from different research networks (BSRN, ARM, SURFRAD), from peer-reviewed publications, project and data reports, and from personal communications. Quality checks are applied to test for gross errors in the dataset. GEBA has played a key role in various research applications, such as in the quantification of the global energy balance, in the discussion of the anomalous atmospheric shortwave absorption, and in the detection of multi-decadal variations in global radiation, known as global dimming and brightening. GEBA is further extensively used for the evaluation of climate models and satellite-derived surface flux products. On a more applied level, GEBA provides the basis for engineering applications in the context of solar power generation, water management, agricultural production and tourism. GEBA is publicly accessible through the internet via http://www.geba.ethz.ch. Supplementary data are available at https://doi.org/10.1594/PANGAEA.873078.

Comparative exploration of hydrogen sulfide and water transmembrane free energy surfaces via orthogonal space tempering free energy sampling.

Science.gov (United States)

Lv, Chao; Aitchison, Erick W; Wu, Dongsheng; Zheng, Lianqing; Cheng, Xiaolin; Yang, Wei

2016-03-05

Hydrogen sulfide (H2 S), a commonly known toxic gas compound, possesses unique chemical features that allow this small solute molecule to quickly diffuse through cell membranes. Taking advantage of the recent orthogonal space tempering (OST) method, we comparatively mapped the transmembrane free energy landscapes of H2 S and its structural analogue, water (H2 O), seeking to decipher the molecular determinants that govern their drastically different permeabilities. As revealed by our OST sampling results, in contrast to the highly polar water solute, hydrogen sulfide is evidently amphipathic, and thus inside membrane is favorably localized at the interfacial region, that is, the interface between the polar head-group and nonpolar acyl chain regions. Because the membrane binding affinity of H2 S is mainly governed by its small hydrophobic moiety and the barrier height inbetween the interfacial region and the membrane center is largely determined by its moderate polarity, the transmembrane free energy barriers to encounter by this toxic molecule are very small. Moreover when H2 S diffuses from the bulk solution to the membrane center, the above two effects nearly cancel each other, so as to lead to a negligible free energy difference. This study not only explains why H2 S can quickly pass through cell membranes but also provides a practical illustration on how to use the OST free energy sampling method to conveniently analyze complex molecular processes. © 2015 Wiley Periodicals, Inc. © 2015 Wiley Periodicals, Inc.

Topography and surface energy dependent calcium phosphate formation on Sol-Gel derived TiO2 coatings.

Science.gov (United States)

Järn, Mikael; Areva, Sami; Pore, Viljami; Peltonen, Jouko; Linden, Mika

2006-09-12

Heterogeneous nucleation and growth of calcium phosphate (CaP) on sol-gel derived TiO(2) coatings was investigated in terms of surface topography and surface energy. The topography of the coatings was derived from AFM measurements, while the surface energy was determined with contact angle measurements. The degree of precipitation was examined with scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). The precipitation of CaP was found to be dependent on both topography and surface energy. A high roughness value when combining the RMS roughness parameter S(q) with the number of local maxima per unit area parameter S(ds) enhances CaP formation. The hydrophilicity of the coating was also found to be of importance for CaP formation. We suggest that the water contact angle, which is a direct measure of the hydrophilicity of the surface, may be used to evaluate the surface energy dependent precipitation kinetics rather than using the often applied Lewis base parameter.

Stable water isotope and surface heat flux simulation using ISOLSM: Evaluation against in-situ measurements

KAUST Repository

Cai, Mick Y.; Wang, Lixin; Parkes, Stephen; Strauss, Josiah; McCabe, Matthew; Evans, Jason P.; Griffiths, Alan D.

2015-01-01

The stable isotopes of water are useful tracers of water sources and hydrological processes. Stable water isotope-enabled land surface modeling is a relatively new approach for characterizing the hydrological cycle, providing spatial and temporal variability for a number of hydrological processes. At the land surface, the integration of stable water isotopes with other meteorological measurements can assist in constraining surface heat flux estimates and discriminate between evaporation (E) and transpiration (T). However, research in this area has traditionally been limited by a lack of continuous in-situ isotopic observations. Here, the National Centre for Atmospheric Research stable isotope-enabled Land Surface Model (ISOLSM) is used to simulate the water and energy fluxes and stable water isotope variations. The model was run for a period of one month with meteorological data collected from a coastal sub-tropical site near Sydney, Australia. The modeled energy fluxes (latent heat and sensible heat) agreed reasonably well with eddy covariance observations, indicating that ISOLSM has the capacity to reproduce observed flux behavior. Comparison of modeled isotopic compositions of evapotranspiration (ET) against in-situ Fourier Transform Infrared spectroscopy (FTIR) measured bulk water vapor isotopic data (10. m above the ground), however, showed differences in magnitude and temporal patterns. The disparity is due to a small contribution from local ET fluxes to atmospheric boundary layer water vapor (~1% based on calculations using ideal gas law) relative to that advected from the ocean for this particular site. Using ISOLSM simulation, the ET was partitioned into E and T with 70% being T. We also identified that soil water from different soil layers affected T and E differently based on the simulated soil isotopic patterns, which reflects the internal working of ISOLSM. These results highlighted the capacity of using the isotope-enabled models to discriminate

Stable water isotope and surface heat flux simulation using ISOLSM: Evaluation against in-situ measurements

KAUST Repository

Cai, Mick Y.

2015-04-01

The stable isotopes of water are useful tracers of water sources and hydrological processes. Stable water isotope-enabled land surface modeling is a relatively new approach for characterizing the hydrological cycle, providing spatial and temporal variability for a number of hydrological processes. At the land surface, the integration of stable water isotopes with other meteorological measurements can assist in constraining surface heat flux estimates and discriminate between evaporation (E) and transpiration (T). However, research in this area has traditionally been limited by a lack of continuous in-situ isotopic observations. Here, the National Centre for Atmospheric Research stable isotope-enabled Land Surface Model (ISOLSM) is used to simulate the water and energy fluxes and stable water isotope variations. The model was run for a period of one month with meteorological data collected from a coastal sub-tropical site near Sydney, Australia. The modeled energy fluxes (latent heat and sensible heat) agreed reasonably well with eddy covariance observations, indicating that ISOLSM has the capacity to reproduce observed flux behavior. Comparison of modeled isotopic compositions of evapotranspiration (ET) against in-situ Fourier Transform Infrared spectroscopy (FTIR) measured bulk water vapor isotopic data (10. m above the ground), however, showed differences in magnitude and temporal patterns. The disparity is due to a small contribution from local ET fluxes to atmospheric boundary layer water vapor (~1% based on calculations using ideal gas law) relative to that advected from the ocean for this particular site. Using ISOLSM simulation, the ET was partitioned into E and T with 70% being T. We also identified that soil water from different soil layers affected T and E differently based on the simulated soil isotopic patterns, which reflects the internal working of ISOLSM. These results highlighted the capacity of using the isotope-enabled models to discriminate

Analyzing energy-water exchange dynamics in the Thar desert

Science.gov (United States)

Raja, P.; Singh, Nilendu; Srinivas, C. V.; Singhal, Mohit; Chauhan, Pankaj; Singh, Maharaj; Sinha, N. K.

2017-07-01

Regions of strong land-atmosphere coupling will be more susceptible to the hydrological impacts in the intensifying hydrological cycle. In this study, micrometeorological experiments were performed to examine the land-atmosphere coupling strength over a heat low region (Thar desert, NW India), known to influence the Indian summer monsoon (ISM). Within the vortex of Thar desert heat low, energy-water exchange and coupling behavior were studied for 4 consecutive years (2011-2014) based on sub-hourly measurements of radiative-convective flux, state parameters and sub-surface thermal profiles using lead-lag analysis between various E-W balance components. Results indicated a strong (0.11-0.35) but variable monsoon season (July-September) land-atmosphere coupling events. Coupling strength declined with time, becomes negative beyond 10-day lag. Evapotranspiration (LE) influences rainfall at the monthly time-scale (20-40 days). Highly correlated monthly rainfall and LE anomalies (r = 0.55, P < 0.001) suggested a large precipitation memory linked to the local land surface state. Sensible heating (SH) during March and April are more strongly (r = 0.6-0.7) correlated to ISM rainfall than heating during May or June (r = 0.16-0.36). Analyses show strong and weak couplings among net radiation (Rn)-vapour pressure deficit (VPD), LE-VPD and Rn-LE switching between energy-limited to water-limited conditions. Consistently, +ve and -ve residual energy [(dE) = (Rn - G) - (SH + LE)] were associated with regional wet and dry spells respectively with a lead of 10-40 days. Dew deposition (18.8-37.9 mm) was found an important component in the annual surface water balance. Strong association of variation of LE and rainfall was found during monsoon at local-scale and with regional-scale LE (MERRA 2D) but with a lag which was more prominent at local-scale than at regional-scale. Higher pre-monsoon LE at local-scale as compared to low and monotonous variation in regional-scale LE led to

A Surface Temperature Initiated Closure (STIC) for surface energy balance fluxes

DEFF Research Database (Denmark)

Mallick, Kaniska; Jarvis, Andrew J.; Boegh, Eva

2014-01-01

The use of Penman–Monteith (PM) equation in thermal remote sensing based surface energy balance modeling is not prevalent due to the unavailability of any direct method to integrate thermal data into the PM equation and due to the lack of physical models expressing the surface (or stomatal......) and boundary layer conductances (gS and gB) as a function of surface temperature. Here we demonstrate a new method that physically integrates the radiometric surface temperature (TS) into the PM equation for estimating the terrestrial surface energy balance fluxes (sensible heat, H and latent heat, λ......E). The method combines satellite TS data with standard energy balance closure models in order to derive a hybrid closure that does not require the specification of surface to atmosphere conductance terms. We call this the Surface Temperature Initiated Closure (STIC), which is formed by the simultaneous solution...

Energy from water. A sea of opportunities; Energie uit water. Een zee van mogelijkheden

Energy Technology Data Exchange (ETDEWEB)

Bos, J.H.B.; Schepers, B.L.; Spaans, F. [CE Delft, Delft (Netherlands)

2009-03-15

The Dutch water sector sees the (inter)national ambitions of governments and market parties in the field of energy and environment and is currently researching options to contribute to their realization. CE Delft has been asked to give insight in the main energetic techniques and principles that could be important for the water sector in this context, both in the short and longer term. This involves options to generate energy with or from water and opportunities in the business operations of the water sector itself [Dutch] De watersector ziet de (inter)nationale ambities van overheden en marktpartijen op het gebied van energie en milieu en onderzoekt de mogelijkheden om bij te dragen aan de realisatie daarvan. CE Delft is gevraagd inzicht te geven in de belangrijkste energetische technieken en principes die in dit kader van belang kunnen zijn voor de watersector, op korte en langere termijn. Het gaat daarbij om de mogelijkheden om met of uit water benutbare energie te verkrijgen en om mogelijkheden in de bedrijfsvoering van de watersector zelf.

Oxide/water interfaces: how the surface chemistry modifies interfacial water properties

International Nuclear Information System (INIS)

Gaigeot, Marie-Pierre; Sprik, Michiel; Sulpizi, Marialore

2012-01-01

The organization of water at the interface with silica and alumina oxides is analysed using density functional theory-based molecular dynamics simulation (DFT-MD). The interfacial hydrogen bonding is investigated in detail and related to the chemistry of the oxide surfaces by computing the surface charge density and acidity. We find that water molecules hydrogen-bonded to the surface have different orientations depending on the strength of the hydrogen bonds and use this observation to explain the features in the surface vibrational spectra measured by sum frequency generation spectroscopy. In particular, ‘ice-like’ and ‘liquid-like’ features in these spectra are interpreted as the result of hydrogen bonds of different strengths between surface silanols/aluminols and water. (paper)

Colloborative International Resesarch on the Water Energy Nexus: Lessons Learned from the Clean Energy Research Center - Water Energy Technologies (CERC-WET)

Science.gov (United States)

Remick, C.

2017-12-01

The U.S.-China Clean Energy Research Center - Water and Energy Technologies (CERC-WET) is a global research partnership focused on developing and deploying technologies that to allow the U.S. and China to thrive in a future with constrained energy and water resources in a changing global climate. This presentation outlines and addresses the opportunities and challenges for international research collaboration on the so called "water-energy nexus", with a focus on industrial partnership, market readiness, and intellectual property. The U.S. Department of Energy created the CERC program as a research and development partnership between the United States and China to accelerate the development and deployment of advanced clean energy technologies. The United States and China are not only the world's largest economies; they are also the world's largest energy producers and energy consumers. Together, they account for about 40% of annual global greenhouse gas emissions. The bilateral investment in CERC-WET will total $50 million over five years and will target on the emerging issues and cut-edge research on the topics of (1) water use reduction at thermoelectric plants; (2) treatment and management of non-traditional waters; (3) improvements in sustainable hydropower design and operation; (4) climate impact modeling, methods, and scenarios to support improved understanding of energy and water systems; and (5) data and analysis to inform planning and policy.

Robust superhydrophobic surface by nature-inspired polyphenol chemistry for effective oil-water separation

Science.gov (United States)

Bu, Yiming; Huang, Jingjing; Zhang, Shiyu; Wang, Yinghua; Gu, Shaojin; Cao, Genyang; Yang, Hongjun; Ye, Dezhan; Zhou, Yingshan; Xu, Weilin

2018-05-01

With the ever-increasing oil spillages, oil-water separation has attracted widespread concern in recent years. In this work, a nature-inspired polyphenol method has been developed to fabricate the durable superhydrophobic surfaces for the oil-water separation. Inspiring from the adhesion of polyphenol and reducing capacity of free catechol/pyrogallol groups in polyphenol, firstly, the simple immersion of commercial materials (melamine sponge, PET, and nonwoven cotton fabrics) in tannic acid (TA) solution allows to form a multifunctional coating on the surface of sponge or fabrics, which was used as reducing reagent to generate Ag nanoparticles (NPs). Then, decoration of 1H, 1H, 2H, 2H-perfluorodecanethiol (PFDT) molecules produced superhydrophobic surfaces. The surface topological structure, chemical composition, and superhydrophobic property of the as-prepared surface are characterized by scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), energy dispersive spectroscopy (EDS), and water contact angle (WCA) measurements. The WCAs of as-prepared sponge and fabrics were higher than 150°. The stability, absorption capacity, and recyclability of as-prepared sponge and fabrics were investigated. The as-prepared sponge demonstrates high oil/water selectivity and high absorption capacity (66-150 g/g) for a broad variety of oils and organic solvents, and was chemically resistant, robust against abrasion, and long-term durability in harsh environments. Most important of all, it can continuously separate various kinds of oils or organic pollutants from the surface of water. This study presents a facile strategy to fabricate superhydrophobic materials for continuous oil-water separation, displaying great potential in large-scale practical application.

Multilayer Relaxation and Surface Energies of Metallic Surfaces

Science.gov (United States)

Bozzolo, Guillermo; Rodriguez, Agustin M.; Ferrante, John

1994-01-01

The perpendicular and parallel multilayer relaxations of fcc (210) surfaces are studied using equivalent crystal theory (ECT). A comparison with experimental and theoretical results is made for AI(210). The effect of uncertainties in the input parameters on the magnitudes and ordering of surface relaxations for this semiempirical method is estimated. A new measure of surface roughness is proposed. Predictions for the multilayer relaxations and surface energies of the (210) face of Cu and Ni are also included.

Water's Interfacial Hydrogen Bonding Structure Reveals the Effective Strength of Surface-Water Interactions.

Science.gov (United States)

Shin, Sucheol; Willard, Adam P

2018-06-05

We combine all-atom molecular dynamics simulations with a mean field model of interfacial hydrogen bonding to analyze the effect of surface-water interactions on the structural and energetic properties of the liquid water interface. We show that the molecular structure of water at a weakly interacting ( i.e., hydrophobic) surface is resistant to change unless the strength of surface-water interactions are above a certain threshold. We find that below this threshold water's interfacial structure is homogeneous and insensitive to the details of the disordered surface, however, above this threshold water's interfacial structure is heterogeneous. Despite this heterogeneity, we demonstrate that the equilibrium distribution of molecular orientations can be used to quantify the energetic component of the surface-water interactions that contribute specifically to modifying the interfacial hydrogen bonding network. We identify this specific energetic component as a new measure of hydrophilicity, which we refer to as the intrinsic hydropathy.

Improving mine-mill water network design by reducing water and energy requirements

Energy Technology Data Exchange (ETDEWEB)

Gunson, A.J.; Klein, B.; Veiga, M. [British Columbia Univ., Vancouver, BC (Canada). Norman B. Keevil Inst. of Mining Engineering

2010-07-01

Mining is an energy-intensive industry, and most processing mills use wet processes to separate minerals from ore. This paper discussed water reduction, reuse and recycling options for a mining and mill operation network. A mine water network design was then proposed in order to identify and reduce water and system energy requirements. This included (1) a description of site water balance, (2) a description of potential water sources, (3) a description of water consumers, (4) the construction of energy requirement matrices, and (5) the use of linear programming to reduce energy requirements. The design was used to determine a site water balance as well as to specify major water consumers during mining and mill processes. Potential water supply combinations, water metering technologies, and recycling options were evaluated in order to identify the most efficient energy and water use combinations. The method was used to highlight potential energy savings from the integration of heating and cooling systems with plant water systems. 43 refs., 4 tabs., 3 figs.

Experimental study on fouling in the heat exchangers of surface water heat pumps

International Nuclear Information System (INIS)

Bai, Xuelian; Luo, Te; Cheng, Kehui; Chai, Feng

2014-01-01

Fouling in the heat exchangers plays a key role on the performance of surface water heat pumps. It is also the basement for the system design criteria and operation energy efficiency. In this paper, experimental measurements are performed both in the field and the laboratory with different water qualities, temperatures and velocities. The research will focus on the dynamic growth characteristics of fouling and its main components. By studying the variation rules of fouling resistance, the fouling resistance allowance for certain water condition is recommended. Furthermore, a fouling prediction model in surface water heat pump will be developed and validated based on elaborating with fouling principle under specified water conditions. - Highlights: • Field and laboratory experiments are taken to measure the fouling variation. • Fouling growth process can be divided into four stages. • We recommend fouling resistance allowances for certain conditions. • A fouling prdiction model is developed and validated

Analysis of Mechanical Energy Transport on Free-Falling Wedge during Water-Entry Phase

Directory of Open Access Journals (Sweden)

Wen-Hua Wang

2012-01-01

Full Text Available For better discussing and understanding the physical phenomena and body-fluid interaction of water-entry problem, here mechanical-energy transport (wedge, fluid, and each other of water-entry model for free falling wedge is studied by numerical method based on free surface capturing method and Cartesian cut cell mesh. In this method, incompressible Euler equations for a variable density fluid are numerically calculated by the finite volume method. Then artificial compressibility method, dual-time stepping technique, and Roe's approximate Riemann solver are applied in the numerical scheme. Furthermore, the projection method of momentum equations and exact Riemann solution are used to calculate the fluid pressure on solid boundary. On this basis, during water-entry phase of the free-falling wedge, macroscopic energy conversion of overall body-fluid system and microscopic energy transformation in fluid field are analyzed and discussed. Finally, based on test cases, many useful conclusions about mechanical energy transport for water entry problem are made and presented.

Energy harvesting water vehicle

KAUST Repository

Singh, Devendra

2018-01-01

An efficient energy harvesting (EEH) water vehicle is disclosed. The base of the EEH water vehicle is fabricated with rolling cylindrical drums that can rotate freely in the same direction of the water medium. The drums reduce the drag

An ontology design pattern for surface water features

Science.gov (United States)

Sinha, Gaurav; Mark, David; Kolas, Dave; Varanka, Dalia; Romero, Boleslo E.; Feng, Chen-Chieh; Usery, E. Lynn; Liebermann, Joshua; Sorokine, Alexandre

2014-01-01

Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities exist due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology for other more context-dependent ontologies. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex or specialized surface water ontologies. A fundamental distinction is made in this ontology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is implemented in OWL, but Description Logic axioms and a detailed explanation is provided in this paper. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. Also provided is a discussion of why there is a need to complement the pattern with other ontologies, especially the previously developed Surface Network pattern. Finally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through an annotated geospatial dataset and sample queries using the classes of the Surface Water pattern.

Energy Savings from Industrial Water Reductions

Energy Technology Data Exchange (ETDEWEB)

Rao, Prakash; McKane, Aimee; de Fontaine, Andre

2015-08-03

Although it is widely recognized that reducing freshwater consumption is of critical importance, generating interest in industrial water reduction programs can be hindered for a variety of reasons. These include the low cost of water, greater focus on water use in other sectors such as the agriculture and residential sectors, high levels of unbilled and/or unregulated self-supplied water use in industry, and lack of water metering and tracking capabilities at industrial facilities. However, there are many additional components to the resource savings associated with reducing site water use beyond the water savings alone, such as reductions in energy consumption, greenhouse gas emissions, treatment chemicals, and impact on the local watershed. Understanding and quantifying these additional resource savings can expand the community of businesses, NGOs, government agencies, and researchers with a vested interest in water reduction. This paper will develop a methodology for evaluating the embedded energy consumption associated with water use at an industrial facility. The methodology developed will use available data and references to evaluate the energy consumption associated with water supply and wastewater treatment outside of a facility’s fence line for various water sources. It will also include a framework for evaluating the energy consumption associated with water use within a facility’s fence line. The methodology will develop a more complete picture of the total resource savings associated with water reduction efforts and allow industrial water reduction programs to assess the energy and CO2 savings associated with their efforts.

Relationship of regional water quality to aquifer thermal energy storage

International Nuclear Information System (INIS)

Allen, R.D.; Raymond, J.R.

1990-01-01

Aquifer thermal energy storage (ATES) involves injection and withdrawal of temperature-conditioned water into and from a permeable water-bearing formation. The groundwater quality and associated geological characteristics were assessed as they may affect the feasibility of ATES system development in any hydrologic region. Seven physical and chemical mechanisms may decrease system efficiency: particulate plugging, chemical precipitation, clay mineral dispersion, piping corrosion, aquifer disaggregation, mineral oxidation, and the proliferation of biota. Factors affecting groundwater quality are pressure, temperature, pH, ion exchange, evaporation/transpiration, and commingling with diverse waters. Modeling with the MINTEQ code showed three potential reactions: precipitation of calcium carbonate at raised temperatures; solution of silica at raised temperature followed by precipitation at reduced temperatures; and oxidation/precipitation of iron compounds. Low concentrations of solutes are generally favorable for ATES. Near-surface waters in high precipitation regions are low in salinity. Groundwater recharged from fresh surface waters also has reduced salinity. Rocks least likely to react with groundwater are siliceous sandstones, regoliths, and metamorphic rocks. On the basis of known aquifer hydrology, ten US water resource regions are candidates for selected exploration and development, all characterized by extensive silica-rich aquifers

A systematic first-principles study of surface energies, surface relaxation and Friedel oscillation of magnesium surfaces

International Nuclear Information System (INIS)

Tang, Jia-Jun; Yang, Xiao-Bao; Zhao, Yu-Jun; OuYang, LiuZhang; Zhu, Min

2014-01-01

We systematically study the surface energies and surface relaxations of various low-index and high-index Mg surfaces. It is found that low-index surfaces are not necessarily stable as Mg(1 0  1-bar  0) is the most unstable surface in the series of Mg(1 0  1-bar  n) (n = 0–9). A surface-energy predicting model based on the bond cutting is proposed to explain the relative surface stabilities. The local relaxations of the low-index surfaces could be explained by the Friedel oscillation. For the high-index surfaces, the combination of charge smoothing effect and dramatic charge depletion influences the relaxations, which show a big difference from the low-index ones. Our findings provide theoretical data for considerable insights into the surface energies of hexagonal close-packed metals. (paper)

Water use alternatives for Navajo energy production

International Nuclear Information System (INIS)

Abbey, D.

1979-01-01

The Navajo have substantial resources of coal and uranium, and water use is certain to accompany development of these resources. A variety of supplies, however, are available--water in storage in Navajo Reservoir, water in existing uses which may be transferred, and groundwater. Furthermore, the quantity of water use varies over a wide range depending on the use of water conservation technologies such as dry coolers and wastewater treatment units. Joint management of energy and water resources requires a basic understanding of the water supply and demand alternatives available to the energy industry. Thus, the uses of water for key energy activities--coal and uranium mining, coal transportation (slurry pipelines), and coal conversion (electricity and synthetic gas production) are reviewed. For those activities for which water conservation is feasible, the technologies and estimate costs ($/af saved) are described. The range of water requirements are then compared to energy and water resource estimates. Finally, alternative (not necessarily exclusive) criteria for energy and water resource management are discussed: a) promote energy activities with the lowest minimum water requirements; b) require industry to use low-quality water resources and the most effective water conservation technology; and c) maximize the economic return on Navajo water resources

Sea Water Characterization at Ujung Kulon Coastal Depth as Raw Water Source for Desalination and Potential Energy

Directory of Open Access Journals (Sweden)

Mugisidi Dan

2018-01-01

Full Text Available Fresh water is basic need for life while the source is limited. Therefore, sea water is used as fresh water through desalination process. Sea water has different physical and chemical properties ranging from the surface to the seabed. The energy potential that can be obtained from the hydrostatic pressure also changes according to the depth. As part of the research of the utilization of sea water into fresh water, the aim of this study is to know the characteristics of sea water in the depth that can be utilized as source of fresh water. The sea water samples were taken at 11km from Ujung Kulon beach with depth of 0m, 20m, 40m, 60m, 80m, and 100m under the surface. The results showed that the physical properties at every depth were below the maximum allowable drinking water except for the amount of dissolved solids. Chemical characteristics at any depth above allowable level were fluoride, hardness (CaCo3, chloride, sodium, sulphate, and (KMnO4. In addition to the properties, pressure is one of the considerations in this study to determine the depth of sea water as sources for desalination. Pressure increased by 36.11% as the depth of the sea increased.

Sea Water Characterization at Ujung Kulon Coastal Depth as Raw Water Source for Desalination and Potential Energy

Science.gov (United States)

Mugisidi, Dan; Heriyani, Okatrina

2018-02-01

Fresh water is basic need for life while the source is limited. Therefore, sea water is used as fresh water through desalination process. Sea water has different physical and chemical properties ranging from the surface to the seabed. The energy potential that can be obtained from the hydrostatic pressure also changes according to the depth. As part of the research of the utilization of sea water into fresh water, the aim of this study is to know the characteristics of sea water in the depth that can be utilized as source of fresh water. The sea water samples were taken at 11km from Ujung Kulon beach with depth of 0m, 20m, 40m, 60m, 80m, and 100m under the surface. The results showed that the physical properties at every depth were below the maximum allowable drinking water except for the amount of dissolved solids. Chemical characteristics at any depth above allowable level were fluoride, hardness (CaCo3), chloride, sodium, sulphate, and (KMnO4). In addition to the properties, pressure is one of the considerations in this study to determine the depth of sea water as sources for desalination. Pressure increased by 36.11% as the depth of the sea increased.

Wettability Control of Gold Surfaces Modified with Benzenethiol Derivatives: Water Contact Angle and Thermal Stability.

Science.gov (United States)

Tatara, Shingo; Kuzumoto, Yasutaka; Kitamura, Masatoshi

2016-04-01

The water wettability of Au surfaces has been controlled using various benzenethiol derivatives including 4-methylbenzenethiol, pentafluorobenzenethiol, 4-flubrobenzenethiol, 4-methoxy-benzenethiol, 4-nitrobenzenethiol, and 4-hydroxybenzenethiol. The water contact angle of the Au surface modified with the benzenethiol derivative was found to vary in the wide range of 30.9° to 88.3°. The contact angle of the modified Au films annealed was also measured in order to investigate their thermal stability. The change in the contact angle indicated that the modified surface is stable at temperatures below about 400 K. Meanwhile, the activation energy of desorption from the modified surface was estimated from the change in the contact angle. The modified Au surface was also examined using X-ray photoelectron spectroscopy.

How to repel hot water from a superhydrophobic surface?

KAUST Repository

Yu, Zhejun

2014-01-01

Superhydrophobic surfaces, with water contact angles greater than 150° and slide angles less than 10°, have attracted a great deal of attention due to their self-cleaning ability and excellent water-repellency. It is commonly accepted that a superhydrophobic surface loses its superhydrophobicity in contact with water hotter than 50 °C. Such a phenomenon was recently demonstrated by Liu et al. [J. Mater. Chem., 2009, 19, 5602], using both natural lotus leaf and artificial leaf-like surfaces. However, our work has shown that superhydrophobic surfaces maintained their superhydrophobicity, even in water at 80 °C, provided that the leaf temperature is greater than that of the water droplet. In this paper, we report on the wettability of water droplets on superhydrophobic thin films, as a function of both their temperatures. The results have shown that both the water contact and slide angles on the surfaces will remain unchanged when the temperature of the water droplet is greater than that of the surface. The water contact angle, or the slide angle, will decrease or increase, however, with droplet temperatures increasingly greater than that of the surfaces. We propose that, in such cases, the loss of superhydrophobicity of the surfaces is caused by evaporation of the hot water molecules and their condensation on the cooler surface. © 2014 the Partner Organisations.

Linking atmospheric synoptic transport, cloud phase, surface energy fluxes, and sea-ice growth: observations of midwinter SHEBA conditions

Science.gov (United States)

Persson, P. Ola G.; Shupe, Matthew D.; Perovich, Don; Solomon, Amy

2017-08-01

Observations from the Surface Heat Budget of the Arctic Ocean (SHEBA) project are used to describe a sequence of events linking midwinter long-range advection of atmospheric heat and moisture into the Arctic Basin, formation of supercooled liquid water clouds, enhancement of net surface energy fluxes through increased downwelling longwave radiation, and reduction in near-surface conductive heat flux loss due to a warming of the surface, thereby leading to a reduction in sea-ice bottom growth. The analyses provide details of two events during Jan. 1-12, 1998, one entering the Arctic through Fram Strait and the other from northeast Siberia; winter statistics extend the results. Both deep, precipitating frontal clouds and post-frontal stratocumulus clouds impact the surface radiation and energy budget. Cloud liquid water, occurring preferentially in stratocumulus clouds extending into the base of the inversion, provides the strongest impact on surface radiation and hence modulates the surface forcing, as found previously. The observations suggest a minimum water vapor threshold, likely case dependent, for producing liquid water clouds. Through responses to the radiative forcing and surface warming, this cloud liquid water also modulates the turbulent and conductive heat fluxes, and produces a thermal wave penetrating into the sea ice. About 20-33 % of the observed variations of bottom ice growth can be directly linked to variations in surface conductive heat flux, with retarded ice growth occurring several days after these moisture plumes reduce the surface conductive heat flux. This sequence of events modulate pack-ice wintertime environmental conditions and total ice growth, and has implications for the annual sea-ice evolution, especially for the current conditions of extensive thinner ice.

Modelling the water energy nexus: should variability in water supply impact on decision making for future energy supply options?

Directory of Open Access Journals (Sweden)

J. D. S. Cullis

2018-02-01

Full Text Available Many countries, like South Africa, Australia, India, China and the United States, are highly dependent on coal fired power stations for energy generation. These power stations require significant amounts of water, particularly when fitted with technology to reduce pollution and climate change impacts. As water resources come under stress it is important that spatial variability in water availability is taken into consideration for future energy planning particularly with regards to motivating for a switch from coal fired power stations to renewable technologies. This is particularly true in developing countries where there is a need for increased power production and associated increasing water demands for energy. Typically future energy supply options are modelled using a least cost optimization model such as TIMES that considers water supply as an input cost, but is generally constant for all technologies. Different energy technologies are located in different regions of the country with different levels of water availability and associated infrastructure development and supply costs. In this study we develop marginal cost curves for future water supply options in different regions of a country where different energy technologies are planned for development. These water supply cost curves are then used in an expanded version of the South Africa TIMES model called SATIM-W that explicitly models the water-energy nexus by taking into account the regional nature of water supply availability associated with different energy supply technologies. The results show a significant difference in the optimal future energy mix and in particular an increase in renewables and a demand for dry-cooling technologies that would not have been the case if the regional variability of water availability had not been taken into account. Choices in energy policy, such as the introduction of a carbon tax, will also significantly impact on future water resources, placing

Modelling the water energy nexus: should variability in water supply impact on decision making for future energy supply options?

Science.gov (United States)

Cullis, James D. S.; Walker, Nicholas J.; Ahjum, Fadiel; Juan Rodriguez, Diego

2018-02-01

Many countries, like South Africa, Australia, India, China and the United States, are highly dependent on coal fired power stations for energy generation. These power stations require significant amounts of water, particularly when fitted with technology to reduce pollution and climate change impacts. As water resources come under stress it is important that spatial variability in water availability is taken into consideration for future energy planning particularly with regards to motivating for a switch from coal fired power stations to renewable technologies. This is particularly true in developing countries where there is a need for increased power production and associated increasing water demands for energy. Typically future energy supply options are modelled using a least cost optimization model such as TIMES that considers water supply as an input cost, but is generally constant for all technologies. Different energy technologies are located in different regions of the country with different levels of water availability and associated infrastructure development and supply costs. In this study we develop marginal cost curves for future water supply options in different regions of a country where different energy technologies are planned for development. These water supply cost curves are then used in an expanded version of the South Africa TIMES model called SATIM-W that explicitly models the water-energy nexus by taking into account the regional nature of water supply availability associated with different energy supply technologies. The results show a significant difference in the optimal future energy mix and in particular an increase in renewables and a demand for dry-cooling technologies that would not have been the case if the regional variability of water availability had not been taken into account. Choices in energy policy, such as the introduction of a carbon tax, will also significantly impact on future water resources, placing additional water

Surface Meteorology and Solar Energy

Data.gov (United States)

National Aeronautics and Space Administration — Surface Meteorology and Solar Energy data - over 200 satellite-derived meteorology and solar energy parameters, monthly averaged from 22 years of data, global solar...

Water and Energy in the GCC: Securing Scarce Water in Oil-Rich Countries

International Nuclear Information System (INIS)

Parmigiani, Laura

2015-09-01

Water scarcity in the Gulf Cooperation Council (GCC) states has traditionally been addressed by finding new ways of producing water. Desalination techniques have allowed these countries to satisfy their increasing water demand, driven by economic and demographic development. The high CAPEX and OPEX costs of desalinated water production are borne by the State through subsidies in the forms of low water and electricity prices. As this trend is not environmentally or economically sustainable, new strategies are now giving priority to cost recovery and efficient resource management. This comparative study will show that in the GCC countries, whose oil or gas reserves are among the largest worldwide, the management of water and energy resources has been relying upon vertically integrated government agencies and companies, with water supply policies fueled by cheap energy. Wealth redistribution coming from oil and gas revenues has been ensured through low or nonexistent water and electricity tariffs. Groundwater resources, which are the only water sources of the region (there are no surface waters available, except for few dams in Saudi Arabia), are quickly diminishing. Desalination has been developing very fast and now seems to be the only reliable form of supplying water for future requirements. Saudi Arabia alone might need 18 billion cubic meter (bcm) of fresh water per year by 2050 to sustain current consumption patterns. For this reason, huge amounts of energy will be required and the question of the right energy/water balance is at stake. Technological choices in the electricity sector will influence the way water is produced in the future, and vice versa. In particular, water production fueled by gas or heavy fuel can be linked to power generation, enhancing efficiency but lowering flexibility. Membrane technologies, which require only electricity inputs, allow for a diversified energy and electricity mix but they have smaller critical sizes and therefore produce

Adsorption of surface functionalized silica nanoparticles onto mineral surfaces and decane/water interface

International Nuclear Information System (INIS)

Metin, Cigdem O.; Baran, Jimmie R.; Nguyen, Quoc P.

2012-01-01

The adsorption of silica nanoparticles onto representative mineral surfaces and at the decane/water interface was studied. The effects of particle size (the mean diameters from 5 to 75 nm), concentration and surface type on the adsorption were studied in detail. Silica nanoparticles with four different surfaces [unmodified, surface modified with anionic (sulfonate), cationic (quaternary ammonium (quat)) or nonionic (polyethylene glycol (PEG)) surfactant] were used. The zeta potential of these silica nanoparticles ranges from −79.8 to 15.3 mV. The shape of silica particles examined by a Hitachi-S5500 scanning transmission electron microscope (STEM) is quite spherical. The adsorption of all the nanoparticles (unmodified or surface modified) on quartz and calcite surfaces was found to be insignificant. We used interfacial tension (IFT) measurements to investigate the adsorption of silica nanoparticles at the decane/water interface. Unmodified nanoparticles or surface modified ones with sulfonate or quat do not significantly affect the IFT of the decane/water interface. It also does not appear that the particle size or concentration influences the IFT. However, the presence of PEG as a surface modifying material significantly reduces the IFT. The PEG surface modifier alone in an aqueous solution, without the nanoparticles, yields the same IFT reduction for an equivalent PEG concentration as that used for modifying the surface of nanoparticles. Contact angle measurements of a decane droplet on quartz or calcite plate immersed in water (or aqueous nanoparticle dispersion) showed a slight change in the contact angle in the presence of the studied nanoparticles. The results of contact angle measurements are in good agreement with experiments of adsorption of nanoparticles on mineral surfaces or decane/water interface. This study brings new insights into the understanding and modeling of the adsorption of surface-modified silica nanoparticles onto mineral surfaces and

Nanoscale control of energy and matter in plasma-surface interactions: towards energy-efficient nanotech

Science.gov (United States)

Ostrikov, Kostya

2010-11-01

This presentation focuses on the plasma issues related to the solution of the grand challenge of directing energy and matter at nanoscales. This ability is critical for the renewable energy and energy-efficient technologies for sustainable future development. It will be discussed how to use environmentally and human health benign non-equilibrium plasma-solid systems and control the elementary processes of plasma-surface interactions to direct the fluxes of energy and matter at multiple temporal and spatial scales. In turn, this makes it possible to achieve the deterministic synthesis of self- organised arrays of metastable nanostructures in the size range beyond the reach of the present-day nanofabrication. Such structures have tantalising prospects to enhance performance of nanomaterials in virtually any area of human activity yet remain almost inaccessible because the Nature's energy minimisation rules allow only a small number of stable equilibrium states. By using precisely controlled and kinetically fast nanoscale transfer of energy and matter under non-equilibrium conditions and harnessing numerous plasma- specific controls of species creation, delivery to the surface, nucleation and large-scale self-organisation of nuclei and nanostructures, the arrays of metastable nanostructures can be created, arranged, stabilised, and further processed to meet the specific requirements of the envisaged applications. These approaches will eventually lead to faster, unprecedentedly- clean, human-health-friendly, and energy-efficient nanoscale synthesis and processing technologies for the next-generation renewable energy and light sources, biomedical devices, information and communication systems, as well as advanced functional materials for applications ranging from basic food, water, health and clean environment needs to national security and space missions.

Surface transformation hardening on steels treated with solar energy in central tower and heliostats field

Energy Technology Data Exchange (ETDEWEB)

Rodriguez, G.P.; Lopez, V.; de Damborenea, J.J.; Vazquez, A.J. [Centro Nacional de Investigaciones Metalurgicas CENIM/CSIC, Madrid (Spain)

1995-04-28

The possibility of surface hardening on AISI 4140 steel treated with concentrated solar energy in solar installations for electricity production has been studied. The samples were slides from a 35 mm diameter steel bar and their height was 35 mm. The quenching was made in water but also was considered the possibility of self-quenching by cooling in air. The amount of the surface hardness and the different structures obtained in both cases are presented, and some discussion is made with reference to the surface hardness, the hardness profiles and the structures obtained. The heating of steel with concentrated solar energy may produce similar hardening to that obtained with more conventional techniques of surface hardening

Radioactivity in surface waters and its effects

International Nuclear Information System (INIS)

Stoeber, I.

1987-01-01

In consequence of the reactor accident in Chernobyl, the State Office for Water and Waste Disposal of North-Rhine Westphalia implemented immediate programmes for monitoring radioactivity in surface waters, including their sediments and organisms. Of the initially-measured radionuclides, only cesium-137, with its long half-life of 30 years, is of interest. Only trace amounts of the almost equally long-lived strontium 90 (half-life 28 years) were present in rainfall. Cs-137 is a non-natural-radionuclide, occurring solely as a by-product of nuclear installations and atomic bomb tests. Following the ban on surface testing of nuclear weapons, the Cs-137 content of surface waters had fallen significantly up to April 1986. The load due to the reactor disaster is of the same order of magnitude as that produced by atomic testing at the end of the nineteen-sixties. The paper surveys radioactive pollution of surface waters in North-Rhine Westphalia and its effects on water use, especially in regard to potable water supplies and the fish population. (orig./HSCH) [de

Dose distribution considerations of medium energy electron beams at extended source-to-surface distance

International Nuclear Information System (INIS)

Saw, Cheng B.; Ayyangar, Komanduri M.; Pawlicki, Todd; Korb, Leroy J.

1995-01-01

Purpose: To determine the effects of extended source-to-surface distance (SSD) on dose distributions for a range of medium energy electron beams and cone sizes. Methods and Materials: The depth-dose curves and isodose distributions of 6 MeV, 10 MeV, and 14 MeV electron beams from a dual photon and multielectron energies linear accelerator were studied. To examine the influence of cone size, the smallest and the largest cone sizes available were used. Measurements were carried out in a water phantom with the water surface set at three different SSDs from 101 to 116 cm. Results: In the region between the phantom surface and the depth of maximum dose, the depth-dose decreases as the SSD increases for all electron beam energies. The effects of extended SSD in the region beyond the depth of maximum dose are unobservable and, hence, considered minimal. Extended SSD effects are apparent for higher electron beam energy with small cone size causing the depth of maximum dose and the rapid dose fall-off region to shift deeper into the phantom. However, the change in the depth-dose curve is small. On the other hand, the rapid dose fall-off region is essentially unaltered when the large cone is used. The penumbra enlarges and electron beam flatness deteriorates with increasing SSD

Highly Adaptive Solid-Liquid Interfacing Triboelectric Nanogenerator for Harvesting Diverse Water Wave Energy.

Science.gov (United States)

Zhao, Xue Jiao; Kuang, Shuang Yang; Wang, Zhong Lin; Zhu, Guang

2018-05-22

Harvesting water wave energy presents a significantly practical route to energy supply for self-powered wireless sensing networks. Here we report a networked integrated triboelectric nanogenerator (NI-TENG) as a highly adaptive means of harvesting energy from interfacing interactions with various types of water waves. Having an arrayed networking structure, the NI-TENG can accommodate diverse water wave motions and generate stable electric output regardless of how random the water wave is. Nanoscaled surface morphology consisting of dense nanowire arrays is the key for obtaining high electric output. A NI-TENG having an area of 100 × 70 mm 2 can produce a stable short-circuit current of 13.5 μA and corresponding electric power of 1.03 mW at a water wave height of 12 cm. This merit promises practical applications of the NI-TENG in real circumstances, where water waves are highly variable and unpredictable. After energy storage, the generated electric energy can drive wireless sensing by autonomously transmitting data at a period less than 1 min. This work proposes a viable solution for powering individual standalone nodes in a wireless sensor network. Potential applications include but are not limited to long-term environment monitoring, marine surveillance, and off-shore navigation.

Surface-Water Data, Georgia, Water Year 1999

Science.gov (United States)

Alhadeff, S. Jack; Landers, Mark N.; McCallum, Brian E.

1999-01-01

Water resources data for the 1999 water year for Georgia consists of records of stage, discharge, and water quality of streams; and the stage and contents of lakes and reservoirs published in one volume in a digital format on a CD-ROM. This volume contains discharge records of 121 gaging stations; stage for 13 gaging stations; stage and contents for 18 lakes and reservoirs; continuous water quality records for 10 stations; and the annual peak stage and annual peak discharge for 75 crest-stage partial-record stations. These data represent that part of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Georgia. Records of discharge and stage of streams, and contents or stage of lakes and reservoirs were first published in a series of U.S. Geological water-supply papers entitled, 'Surface-Water Supply of the United States.' Through September 30, 1960, these water-supply papers were in an annual series and then in a 5-year series for 1961-65 and 1966-70. Records of chemical quality, water temperature, and suspended sediment were published from 1941 to 1970 in an annual series of water-supply papers entitled, 'Quality of Surface Waters of the United States.' Records of ground-water levels were published from 1935 to 1974 in a series of water-supply papers entitled, 'Ground-Water Levels in the United States.' Water-supply papers may be consulted in the libraries of the principal cities in the United States or may be purchased from the U.S. Geological Survey, Branch of Information Services, Federal Center, Box 25286, Denver, CO 80225. For water years 1961 through 1970, streamflow data were released by the U.S. Geological Survey in annual reports on a State-boundary basis prior to the two 5-year series water-supply papers, which cover this period. The data contained in the water-supply papers are considered the official record. Water-quality records for water years 1964 through 1970 were similarly released

The surface energy of metals

DEFF Research Database (Denmark)

Vitos, Levente; Ruban, Andrei; Skriver, Hans Lomholt

1998-01-01

We have used density functional theory to establish a database of surface energies for low index surfaces of 60 metals in the periodic table. The data may be used as a consistent starting point for models of surface science phenomena. The accuracy of the database is established in a comparison...

Energy conservation potential of surface modification technologies

Energy Technology Data Exchange (ETDEWEB)

Le, H.K.; Horne, D.M.; Silberglitt, R.S.

1985-09-01

This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

Exploring the Effect of Climate Perturbations on Water Availability for Renewable Energy Development in the Indian Wells Valley, California

Science.gov (United States)

Rey, David M.

Energy and water are connected through the water-use cycle (e.g. obtaining, transporting, and treating water) and thermoelectric energy generation, which converts heat to electricity via steam-driven turbines. As the United States implements more renewable energy technologies, quantifying the relationships between energy, water, and land-surface impacts of these implementations will provide policy makers the strengths and weaknesses of different renewable energy options. In this study, a MODFLOW model of the Indian Wells Valley (IWV), in California, was developed to capture the water, energy, and land-surface impacts of potential proposed 1) solar, 2) wind, and 3) biofuel implementations. The model was calibrated to pre-existing groundwater head data from 1985 to present to develop a baseline model before running two-year predictive scenarios for photovoltaic (PV), concentrating solar power (CSP), wind, and biofuel implementations. Additionally, the baseline model was perturbed by decreasing mountain front recharge values by 5%, 10%, and 15%, simulating potential future system perturbations under a changing climate. These potential future conditions were used to re-run each implementation scenario. Implementation scenarios were developed based on population, typical energy use per person, existing land-use and land-cover type within the IWV, and previously published values for water use, surface-area use, and energy-generation potential for each renewable fuel type. The results indicate that the quantity of water needed, localized drawdown from pumping water to meet implementation demands, and generation efficiency are strongly controlled by the fuel type, as well as the energy generating technology and thermoelectric technologies implemented. Specifically, PV and wind-turbine (WT) implementations required less than 1% of the estimated annual aquifer recharge, while technologies such as biofuels and CSP, which rely on thermoelectric generation, ranged from 3% to 20

Nature and analysis of chemical species: pollution effects on surface waters and groundwater

International Nuclear Information System (INIS)

Young, R.H.F.

1975-01-01

A literature review of 103 items covers: nutrients in surface waters; runoff and waste discharges primarily from energy-intensive activities; groundwater pollution causes, effects, controls and monitoring; land and subsurface wastewater disposal; radionuclides; biological effects; thermal effluents; and biological and mathematical models for rivers

Water, agriculture, energy: a growing interweaving. Towards an extended water security

International Nuclear Information System (INIS)

Taithe, Alexandre

2009-01-01

In this paper, the author first notices that the definition of water security according to the United Nations Development Program (UNDP) is a rather restrictive one. Thus, the search for a global security takes all forms of insufficiencies and (military or not) instabilities into account, and is then related to strategic stakes of State stability such as agriculture production, water or energy. He discusses the determining factors and vulnerabilities of a renewed water security and its implications. He highlights how internal political and social constraints are sources of local and regional tensions. In this respect, agriculture is at the heart of use conflicts (difficult and necessary reform of the sector, rivalries between rural and urban users), and water stress directly affects daily domestic uses. The author then outlines the necessary integration stakes related to water, food and energy by discussing the use of water in energy production, the use of energy to produce drinkable water, the relationship between agriculture and energy, and, of course between agriculture and water as agriculture is the main water consumer

Life-cycle energy impacts for adapting an urban water supply system to droughts.

Science.gov (United States)

Lam, Ka Leung; Stokes-Draut, Jennifer R; Horvath, Arpad; Lane, Joe L; Kenway, Steven J; Lant, Paul A

2017-12-15

In recent years, cities in some water stressed regions have explored alternative water sources such as seawater desalination and potable water recycling in spite of concerns over increasing energy consumption. In this study, we evaluate the current and future life-cycle energy impacts of four alternative water supply strategies introduced during a decade-long drought in South East Queensland (SEQ), Australia. These strategies were: seawater desalination, indirect potable water recycling, network integration, and rainwater tanks. Our work highlights the energy burden of alternative water supply strategies which added approximately 24% life-cycle energy use to the existing supply system (with surface water sources) in SEQ even for a current post-drought low utilisation status. Over half of this additional life-cycle energy use was from the centralised alternative supply strategies. Rainwater tanks contributed an estimated 3% to regional water supply, but added over 10% life-cycle energy use to the existing system. In the future scenario analysis, we compare the life-cycle energy use between "Normal", "Dry", "High water demand" and "Design capacity" scenarios. In the "Normal" scenario, a long-term low utilisation of the desalination system and the water recycling system has greatly reduced the energy burden of these centralised strategies to only 13%. In contrast, higher utilisation in the unlikely "Dry" and "Design capacity" scenarios add 86% and 140% to life-cycle energy use of the existing system respectively. In the "High water demand" scenario, a 20% increase in per capita water use over 20 years "consumes" more energy than is used by the four alternative strategies in the "Normal" scenario. This research provides insight for developing more realistic long-term scenarios to evaluate and compare life-cycle energy impacts of drought-adaptation infrastructure and regional decentralised water sources. Scenario building for life-cycle assessments of water supply

Lithium content in potable water, surface water, ground water, and mineral water on the territory of Republic of Macedonia

OpenAIRE

Kostik, Vesna; Bauer, Biljana; Kavrakovski, Zoran

2014-01-01

The aim of this study was to determine lithium concentration in potable water, surface water, ground, and mineral water on the territory of the Republic of Macedonia. Water samples were collected from water bodies such as multiple public water supply systems located in 13 cities, wells boreholes located in 12 areas, lakes and rivers located in three different areas. Determination of lithium concentration in potable water, surface water was performed by the technique of inductively coupl...

Presence and risk assessment of pharmaceuticals in surface water and drinking water

DEFF Research Database (Denmark)

Sanderson, Hans

2011-01-01

Trace amounts of pharmaceuticals have been detected in surface waters in the nano- to microgram per liter range, and in drinking water in the nanogram/L range. The environmental risks of pharmaceuticals in surface waters have been evaluated and generally found to be low if the wastewater is treated...

Energy-Water Nexus Knowledge Discovery Framework

Science.gov (United States)

Bhaduri, B. L.; Foster, I.; Chandola, V.; Chen, B.; Sanyal, J.; Allen, M.; McManamay, R.

2017-12-01

As demand for energy grows, the energy sector is experiencing increasing competition for water. With increasing population and changing environmental, socioeconomic scenarios, new technology and investment decisions must be made for optimized and sustainable energy-water resource management. This requires novel scientific insights into the complex interdependencies of energy-water infrastructures across multiple space and time scales. An integrated data driven modeling, analysis, and visualization capability is needed to understand, design, and develop efficient local and regional practices for the energy-water infrastructure components that can be guided with strategic (federal) policy decisions to ensure national energy resilience. To meet this need of the energy-water nexus (EWN) community, an Energy-Water Knowledge Discovery Framework (EWN-KDF) is being proposed to accomplish two objectives: Development of a robust data management and geovisual analytics platform that provides access to disparate and distributed physiographic, critical infrastructure, and socioeconomic data, along with emergent ad-hoc sensor data to provide a powerful toolkit of analysis algorithms and compute resources to empower user-guided data analysis and inquiries; and Demonstration of knowledge generation with selected illustrative use cases for the implications of climate variability for coupled land-water-energy systems through the application of state-of-the art data integration, analysis, and synthesis. Oak Ridge National Laboratory (ORNL), in partnership with Argonne National Laboratory (ANL) and researchers affiliated with the Center for International Earth Science Information Partnership (CIESIN) at Columbia University and State University of New York-Buffalo (SUNY), propose to develop this Energy-Water Knowledge Discovery Framework to generate new, critical insights regarding the complex dynamics of the EWN and its interactions with climate variability and change. An overarching

Anomalous water dynamics at surfaces and interfaces: synergistic effects of confinement and surface interactions

Science.gov (United States)

Biswas, Rajib; Bagchi, Biman

2018-01-01

In nature, water is often found in contact with surfaces that are extended on the scale of molecule size but small on a macroscopic scale. Examples include lipid bilayers and reverse micelles as well as biomolecules like proteins, DNA and zeolites, to name a few. While the presence of surfaces and interfaces interrupts the continuous hydrogen bond network of liquid water, confinement on a mesoscopic scale introduces new features. Even when extended on a molecular scale, natural and biological surfaces often have features (like charge, hydrophobicity) that vary on the scale of the molecular diameter of water. As a result, many new and exotic features, which are not seen in the bulk, appear in the dynamics of water close to the surface. These different behaviors bear the signature of both water-surface interactions and of confinement. In other words, the altered properties are the result of the synergistic effects of surface-water interactions and confinement. Ultrafast spectroscopy, theoretical modeling and computer simulations together form powerful synergistic approaches towards an understanding of the properties of confined water in such systems as nanocavities, reverse micelles (RMs), water inside and outside biomolecules like proteins and DNA, and also between two hydrophobic walls. We shall review the experimental results and place them in the context of theory and simulations. For water confined within RMs, we discuss the possible interference effects propagating from opposite surfaces. Similar interference is found to give rise to an effective attractive force between two hydrophobic surfaces immersed and kept fixed at a separation of d, with the force showing an exponential dependence on this distance. For protein and DNA hydration, we shall examine a multitude of timescales that arise from frustration effects due to the inherent heterogeneity of these surfaces. We pay particular attention to the role of orientational correlations and modification of the

Effect of surface energy on powder compactibility.

Science.gov (United States)

Fichtner, Frauke; Mahlin, Denny; Welch, Ken; Gaisford, Simon; Alderborn, Göran

2008-12-01

The influence of surface energy on the compactibility of lactose particles has been investigated. Three powders were prepared by spray drying lactose solutions without or with low proportions of the surfactant polysorbate 80. Various powder and tablet characterisation procedures were applied. The surface energy of the powders was characterized by Inverse Gas Chromatography and the compressibility of the powders was described by the relationship between tablet porosity and compression pressure. The compactibility of the powders was analyzed by studying the evolution of tablet tensile strength with increasing compaction pressure and porosity. All powders were amorphous and similar in particle size, shape, and surface area. The compressibility of the powders and the microstructure of the formed tablets were equal. However, the compactibility and dispersive surface energy was dependent of the composition of the powders. The decrease in tablet strength correlated to the decrease in powder surface energy at constant tablet porosities. This supports the idea that tablet strength is controlled by formation of intermolecular forces over the areas of contact between the particles and that the strength of these bonding forces is controlled by surface energy which, in turn, can be altered by the presence of surfactants.

Concavity Theorems for Energy Surfaces

OpenAIRE

Giraud, B. G.; Karataglidis, S.

2011-01-01

Concavity properties prevent the existence of significant landscapes in energy surfaces obtained by strict constrained energy minimizations. The inherent contradiction is due to fluctuations of collective coordinates. A solution to those fluctuations is given.

Small-Scale Morphological Features on a Solid Surface Processed by High-Pressure Abrasive Water Jet

Directory of Open Access Journals (Sweden)

Can Kang

2013-08-01

Full Text Available Being subjected to a high-pressure abrasive water jet, solid samples will experience an essential variation of both internal stress and physical characteristics, which is closely associated with the kinetic energy attached to the abrasive particles involved in the jet stream. Here, experiments were performed, with particular emphasis being placed on the kinetic energy attenuation and turbulent features in the jet stream. At jet pressure of 260 MPa, mean velocity and root-mean-square (RMS velocity on two jet-stream sections were acquired by utilizing the phase Doppler anemometry (PDA technique. A jet-cutting experiment was then carried out with Al-Mg alloy samples being cut by an abrasive water jet. Morphological features and roughness on the cut surface were quantitatively examined through scanning electron microscopy (SEM and optical profiling techniques. The results indicate that the high-pressure water jet is characterized by remarkably high mean flow velocities and distinct velocity fluctuations. Those irregular pits and grooves on the cut surfaces indicate both the energy attenuation and the development of radial velocity components in the jet stream. When the sample is positioned with different distances from the nozzle outlet, the obtained quantitative surface roughness varies accordingly. A descriptive model highlighting the behaviors of abrasive particles in jet-cutting process is established in light of the experimental results and correlation analysis.

Small-Scale Morphological Features on a Solid Surface Processed by High-Pressure Abrasive Water Jet.

Science.gov (United States)

Kang, Can; Liu, Haixia

2013-08-14

Being subjected to a high-pressure abrasive water jet, solid samples will experience an essential variation of both internal stress and physical characteristics, which is closely associated with the kinetic energy attached to the abrasive particles involved in the jet stream. Here, experiments were performed, with particular emphasis being placed on the kinetic energy attenuation and turbulent features in the jet stream. At jet pressure of 260 MPa, mean velocity and root-mean-square (RMS) velocity on two jet-stream sections were acquired by utilizing the phase Doppler anemometry (PDA) technique. A jet-cutting experiment was then carried out with Al-Mg alloy samples being cut by an abrasive water jet. Morphological features and roughness on the cut surface were quantitatively examined through scanning electron microscopy (SEM) and optical profiling techniques. The results indicate that the high-pressure water jet is characterized by remarkably high mean flow velocities and distinct velocity fluctuations. Those irregular pits and grooves on the cut surfaces indicate both the energy attenuation and the development of radial velocity components in the jet stream. When the sample is positioned with different distances from the nozzle outlet, the obtained quantitative surface roughness varies accordingly. A descriptive model highlighting the behaviors of abrasive particles in jet-cutting process is established in light of the experimental results and correlation analysis.

The State of U.S. Urban Water: Data and the Energy-Water Nexus

Science.gov (United States)

Chini, Christopher M.; Stillwell, Ashlynn S.

2018-03-01

Data on urban water resources are scarce, despite a majority of the U.S. population residing in urban environments. Further, information on the energy required to facilitate the treatment, distribution, and collection of urban water are even more limited. In this study, we evaluate the energy-for-water component of the energy-water nexus by providing and analyzing a unique primary database consisting of drinking water and wastewater utility flows and energy. These anthropogenic fluxes of water through the urban environment are used to assess the state of the U.S. urban energy-water nexus at over 160 utilities. The average daily per person water flux is estimated at 560 L of drinking water and 500 L of wastewater. Drinking water and wastewater utilities require 340 kWh/1,000 m3 and 430 kWh/1,000 m3 of energy, respectively, to treat these resources. The total national energy demand for water utilities accounts for 1.0% of the total annual electricity consumption of the United States. Additionally, the water and embedded energy loss associated with non-revenue water accounts for 9.1 × 109 m3 of water and 3,100 GWh, enough electricity to power 300,000 U.S. households annually. Finally, the water flux and embedded energy fluctuated monthly in many cities. As the nation's water resources become increasingly scarce and unpredictable, it is essential to have a set of empirical data for continuous evaluation and updates on the state of the U.S. urban energy-water nexus.

Formation of water-in-diesel oil nano-emulsions using high energy method and studying some of their surface active properties

Directory of Open Access Journals (Sweden)

A.M. Al-Sabagh

2011-06-01

Full Text Available In this work, formations of water-in-diesel oil nano-emulsions using water/mixed nonionic surfactant/diesel oil system have been studied. The high energy emulsification method was used to form three emulsions using different water contents: 5%, 10% and 14% (v/v namely; E1, E2 and E3, respectively. These nano-emulsions were stabilized with emulsifiers having different Hydrophilic–Lipophilic Balance (HLB namely; span 80 (HLB = 4.3, emarol 85 (HLB = 11 and their mixture (SE with HLB = 10. The effect of water on the droplet size formation has been investigated. The interfacial tension and thermodynamic properties of the individual and emulsifiers blends have been studied. The interfacial tension (γ measurements at 30 °C were used to determine the critical micelle concentration (CMC and surface active properties of these emulsifiers. The water droplet sizes were measured by dynamic light scattering (DLS. From the obtained data, it was found that, mean sizes between 19.3 and 39 nm were obtained depending on the water content and concentration of blend emulsifiers (SE. Also, the results show that, the interfacial tension (γ gives minimum value (10.85 mN/m for SE comparing with individual emulsifier (17.13 and 12.77 mN/m for span 80 and emarol 85, respectively. The visual inspection by TEM showed that the obtained results support the data obtained by dynamic light scattering.

40 CFR 257.3-3 - Surface water.

Science.gov (United States)

2010-07-01

... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Surface water. 257.3-3 Section 257.3-3... and Practices § 257.3-3 Surface water. (a) For purposes of section 4004(a) of the Act, a facility... Water Act, as amended. (b) For purposes of section 4004(a) of the Act, a facility shall not cause a...

Energy efficiency in a water supply system:Energy consumption and CO2 emission

Institute of Scientific and Technical Information of China (English)

Helena M.RAMOS; Filipe VIEIRA; Didia I.C.COVAS

2010-01-01

This paper presents important fundamentals associated with water and energy efficiency and highlights the importance of using renewable energy sources.A model of multi-criteria optimization for energy efficiency based on water and environmental management policies,including the preservation of water resources and the control of water pressure and energy consumption through a hybrid energy solution,was developed and applied to a water supply system.The methodology developed includes three solutions:(1)the use of a water turbine in pipe systems where pressures are higher than necessary and pressure-reducing valves are installed,(2)the optimization of pumping operation according to the electricity tariff and water demand,and(3)the use of other renewable energy sources,including a wind turbine,to supply energy to the pumping station,with the remaining energy being sold to the national electric grid.The use of an integrated solution(water and energy)proves to be a valuable input for creating benefits from available hydro energy in the water supply system in order to produce clean power,and the use of a wind source allows for the reduction of energy consumption in pumping stations,as well as of the CO2 emission to the atmosphere.

Dissolution of organic solvents from painted surfaces into water

International Nuclear Information System (INIS)

Wren, J.C.; Jobe, D.J.; Sanipelli, G.G.; Ball, J.M.

2000-01-01

The presence of volatile iodine in containment buildings is one of the major safety concerns in the potential event of nuclear reactor accidents. Organic impurities in containment water, originating from various painted structural surfaces and organic materials, could have a significant impact on iodine volatility following an accident. To determine the source and magnitude of organic impurities and their effects on time-dependent iodine volatility, the dissolution for organic constituents from paints used in reactor buildings has been studied under postulated accident conditions. The studies of the organic dissolution from carbon steel coupons coated with zinc-primed vinyl, epoxy-primed polyurethane or epoxy paints over the temperature range 25-90 deg C are reported. Relatively large activation energies were measured for the release of the principal organic compounds from painted surfaces, suggesting it is the release of the solvents from the paint matrix rather than their diffusion through the solution that is the rate determining step for the dissolution mechanism. The similarities in the values of activation energies for the dissolution of different organic compounds from the paints suggest the release rate is independent of the nature of the painted surface or the type of organic being released from the surface. These two observations indicate that it may be possible to write a generalized rate expression for the release of organic compounds from painted surfaces in containment following an accident. The possible implications of these results for predicting iodine volatility in containment are also discussed. (author)

Ab initio theoretical calculations of the electronic excitation energies of small water clusters.

Science.gov (United States)

Tachikawa, Hiroto; Yabushita, Akihiro; Kawasaki, Masahiro

2011-12-14

A direct ab initio molecular dynamics method has been applied to a water monomer and water clusters (H(2)O)(n) (n = 1-3) to elucidate the effects of zero-point energy (ZPE) vibration on the absorption spectra of water clusters. Static ab initio calculations without ZPE showed that the first electronic transitions of (H(2)O)(n), (1)B(1)←(1)A(1), are blue-shifted as a function of cluster size (n): 7.38 eV (n = 1), 7.58 eV (n = 2) and 8.01 eV (n = 3). The inclusion of the ZPE vibration strongly affects the excitation energies of a water dimer, and a long red-tail appears in the range of 6.42-6.90 eV due to the structural flexibility of a water dimer. The ultraviolet photodissociation of water clusters and water ice surfaces is relevant to these results.

Atmospheric Water Harvesting: Role of Surface Wettability and Edge Effect

KAUST Repository

Jin, Yong

2017-06-23

Atmospheric water is emerging as an important potable water source. The present work experimentally and theoretically investigates water condensation and collection on flat surfaces with contrasting contact angles and contact angle hysteresis (CAH) to elucidate their roles on water mass collection efficiency. The experimental results indicate that a hydrophilic surface promotes nucleation and individual droplets growth, and a surface with a low CAH tends to let a smaller droplet to slide down, but the overall water mass collection efficiency is independent of both surface contact angle and CAH. The experimental results agree well with our theoretical calculations. During water condensation, a balance has to be struck between single droplet growth and droplet density on a surface so as to maintain a constant water droplet surface coverage ratio, which renders the role of both surface wettability and hysteresis insignificant to the ultimate water mass collection. Moreover, water droplets on the edges of a surface grow much faster than those on the non-edge areas and thus dominate the contribution to the water mass collection by the entire surface, directly pointing out the very important role of edge effect on water condensation and collection.

STOMP Sparse Vegetation Evapotranspiration Model for the Water-Air-Energy Operational Mode

Energy Technology Data Exchange (ETDEWEB)

Ward, Anderson L.; White, Mark D.; Freeman, Eugene J.; Zhang, Z. F.

2005-09-15

The Water-Air-Energy (WAE) Operational Mode of the Subsurface Transport Over Multiple Phases (STOMP) numerical simulator solves the coupled conservation equations for water mass, air mass, and thermal energy in multiple dimensions. This addendum describes the theory, input file formatting, and application of a soil-vegetation-atmosphere transfer (SVAT) scheme for STOMP that is based on a sparse vegetation evapotranspiration model. The SVAT scheme is implemented as a boundary condition on the upper surface of the computational domain and has capabilities for simulating evaporation from bare surfaces as well as evapotranspiration from sparsely vegetated surfaces populated with single or multiple plant species in response to meteorological forcings. With this extension, the model calculates water mass, air mass and thermal energy across a boundary surface in addition to root-water transport between the subsurface and atmosphere. This mode represents the barrier extension of the WAE mode and is designated as STOMP-WAE-B. Input for STOMP-WAE-B is specified via three input cards and include: atmospheric conditions through the Atmospheric Conditions Card; time-invariant plant species data through the Plant Properties Card; and time varying plant species data through the Boundary Conditions Card. Two optional cards, the Observed Data and UCODE Control Cards allow use of STOMP-WAE with UCODE in an inverse mode to estimate model parameters. STOMP-WAE was validated by solving a number of test problems from the literature that included experimental observations as well as analytical or numerical solutions. Several of the UNSAT-H verification problems are included along with a benchmark simulation derived from a recently published intercode comparison for barrier design tools. Results show that STOMP is able to meet, and in most cases, exceed performance of other commonly used simulation codes without having to resort to may of their simplifying assumptions. Use of the fully

SURFACE ENERGY BALANCE OVER ORANGE ORCHARD USING SURFACE RENEWAL ANALYSIS

Directory of Open Access Journals (Sweden)

Salvatore Barbagallo

2009-12-01

Full Text Available Reliable estimation of surface sensible and latent heat flux is the most important process to appraise energy and mass exchange among atmosphere and biosphere. In this study the surface energy fluxes were measured over an irrigated orange orchard during 2005-2008 monitoring periods using a Surface Renewal- Energy Balance approach. The experimental area is located in a representative orchard growing area of eastern Sicily (Italy. The performance of Surface Renewal (SR analysis for estimating sensible heat flux (H was analysed and evaluated in terms of correlation with H fluxes from the eddy covariance (EC method. Study revealed that the mean available energy (RN- G and latent heat flux (LE were of about 300 W m-2 and 237 W m-2, respectively, during dry periods and unstable-case atmospheric conditions. The estimated crop coefficient Kc values for the orchard crop averaged close to 0.80, which is considerably higher than previous FAO studies that found the value to be 0.65 for citrus with 70% of ground cover. The intercepted photosynthetically active radiation (LI PAR by the crop was measured and relationships between LAI and crop coefficient (Kc were established.

Water as a source of renewable energy. Environmental impacts of six energy techniques; Water als bron van duurzame energie. Omgevingseffecten van zes energietechnologieen

Energy Technology Data Exchange (ETDEWEB)

Van den Berg, M.; De Bie, Y.; Geurts, F.; Van Iersel, S.; Ritzen, A.; Stolk, N.

2010-03-15

This report describes the environmental impact of six energy technologies using water: thermal energy storage, tidal current, tidal energy with height of fall, wave energy, aquatic biomass and osmosis energy (blue energy) [Dutch] In dit rapport zijn de omgevingseffecten van zes energietechnologieen met water beschreven: warmte koude opslag, getijdenstroming, getijdenenergie op verval, golfenergie, aquatische biomassa en osmose-energie (blue energy)

Modelling global fresh surface water temperature

NARCIS (Netherlands)

Beek, L.P.H. van; Eikelboom, T.; Vliet, M.T.H. van; Bierkens, M.F.P.

2011-01-01

Temperature directly determines a range of water physical properties including vapour pressure, surface tension, density and viscosity, and the solubility of oxygen and other gases. Indirectly water temperature acts as a strong control on fresh water biogeochemistry, influencing sediment

Water availability as a driver of spatial and temporal variability in vegetation in the La Mancha plain (Spain): Implications for the land-surface energy, water and carbon budget

Science.gov (United States)

Los, Sietse

2017-04-01

Vegetation is water limited in large areas of Spain and therefore a close link exists between vegetation greenness observed from satellite and moisture availability. Here we exploit this link to infer spatial and temporal variability in moisture from MODIS NDVI data and thermal data. Discrepancies in the precipitation - vegetation relationship indicate areas with an alternative supply of water (i.e. not rainfall), this can be natural where moisture is supplied by upwelling groundwater, or can be artificial where crops are irrigated. As a result spatial and temporal variability in vegetation in the La Mancha Plain appears closely linked to topography, geology, rainfall and land use. Crop land shows large variability in year-to-year vegetation greenness; for some areas this variability is linked to variability in rainfall but in other cases this variability is linked to irrigation. The differences in irrigation treatment within one plant functional type, in this case crops, will lead to errors in land surface models when ignored. The magnitude of these effects on the energy, carbon and water balance are assessed at the scale of 250 m to 200 km. Estimating the water balance correctly is of particular important since in some areas in Spain more water is used for irrigation than is supplemented by rainfall.

Water for energy

Energy Technology Data Exchange (ETDEWEB)

NONE

2010-09-15

Human civilization has always rested on access to water, and, more specifically, on its utilization. This study aims to contribute to a better understanding of the critical linkages between water and energy and the impact on both of climate change. It identifies areas of opportunity where investment and new regulations are needed, to ensure sustainable global development.

Co-adsorption of surfactants and water at inorganic solid surfaces.

Science.gov (United States)

Cooper, Timothy G; de Leeuw, Nora H

2002-07-21

Computer simulations of the co-adsorption of water and methanoic acid at a range of surface features of calcite and fluorite minerals have shown that the relative adsorption energies for the two minerals are reversed when solvent effects are included in the calculations, a finding which is important in the search for effective surfactant reagents in flotation techniques, which are used extensively in the mining and pharmaceutical industries and in environmental remediation processes.

Surface free energy of alkali and transition metal nanoparticles

International Nuclear Information System (INIS)

Aqra, Fathi; Ayyad, Ahmed

2014-01-01

Graphical abstract: Size dependent surface free energy of spherical, cubic and disk Au nanoparticles. - Highlights: • A model to account for the surface free energy of metallic nanoparticles is described. • The model requires only the cohesive energy of the nanoparticle. • The surface free energy of a number of metallic nanoparticles has been calculated, and the obtained values agree well with existing data. • Surface energy falls down very fast when the number of atoms is less than hundred. • The model is applicable to any metallic nanoparticle. - Abstract: This paper addresses an interesting issue on the surface free energy of metallic nanoparticles as compared to the bulk material. Starting from a previously reported equation, a theoretical model, that involves a specific term for calculating the cohesive energy of nanoparticle, is established in a view to describe the behavior of surface free energy of metallic nanoparticles (using different shapes of particle: sphere, cube and disc). The results indicate that the behavior of surface energy is very appropriate for spherical nanoparticle, and thus, it is the most realistic shape of a nanoparticle. The surface energy of copper, silver, gold, platinum, tungsten, molybdenum, tantalum, paladium and alkali metallic nanoparticles is only prominent in the nanoscale size, and it decreases with the decrease of nanoparticle size. Thus, the surface free energy plays a more important role in determining the properties of nanoparticles than in bulk materials. It differs from shape to another, and falls down as the number of atoms (nanoparticle size) decreases. In the case of spherical nanoparticles, the onset of the sharp decrease in surface energy is observed at about 110 atom. A decrease of 16% and 45% in surface energy is found by moving from bulk to 110 atom and from bulk to 5 atom, respectively. The predictions are consistent with the reported data

An Ontology Design Pattern for Surface Water Features

Energy Technology Data Exchange (ETDEWEB)

Sinha, Gaurav [Ohio University; Mark, David [University at Buffalo (SUNY); Kolas, Dave [Raytheon BBN Technologies; Varanka, Dalia [U.S. Geological Survey, Rolla, MO; Romero, Boleslo E [University of California, Santa Barbara; Feng, Chen-Chieh [National University of Singapore; Usery, Lynn [U.S. Geological Survey, Rolla, MO; Liebermann, Joshua [Tumbling Walls, LLC; Sorokine, Alexandre [ORNL

2014-01-01

Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities can be found due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology. It can then be used to systematically incor-porate concepts that are specific to a culture, language, or scientific domain. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex surface water ontologies. A fundamental distinction is made in this on-tology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is imple-mented in OWL, but Description Logic axioms and a detailed explanation is provided. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. A discussion about why there is a need to complement the pattern with other ontologies, es-pecially the previously developed Surface Network pattern is also provided. Fi-nally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through a few queries and annotated geospatial datasets.

Effects of hot water pre-extraction on surface properties of bagasse soda pulp.

Science.gov (United States)

Cordeiro, Nereida; Ashori, Alireza; Hamzeh, Yahya; Faria, Marisa

2013-03-01

In this work, the effects of hot water pre-extraction of depithed bagasse on the soda pulping and surface properties were studied. The conditions of hot water pre-extraction were: maximum temperature 170 °C, heat-up time 90 min, time at maximum temperature 10 min, and solid to liquor ratio (S:L) 1:8. Consequently, the pre-extracted and un-extracted bagasse chips were subjected to soda pulping at 160 °C for 1h with 11, 14 and 17% active alkali charge and an S:L of 1:5. The results showed that the hot water pre-extraction increased bagasse surface texture porosity by hemicellulose degradation. Therefore, the delignification was faster for pulping of pre-extracted samples. At a certain charge of alkali, pre-extracted samples showed higher screened yield and lower Kappa number. For instance, at 17% alkali charge, pre-extracted bagasse gave 11.3% higher pulp yield compared with the un-extracted ones. Inverse gas chromatography (IGC) results showed that the hot water pre-extraction changed the active sites on the bagasse surface, decreasing the dispersive energy and the basicity character, and affected the particle morphology. The pulping process decreased the hydrophobicity and the basicity of the bagasse surface. The surfaces of un-extracted and pre-extracted bagasse pulps had similar properties but different morphology. The pulps present higher surface area and permeability with more reactive capacity. Copyright © 2012 Elsevier B.V. All rights reserved.

Surface-Water Conditions in Georgia, Water Year 2005

Science.gov (United States)

Painter, Jaime A.; Landers, Mark N.

2007-01-01

INTRODUCTION The U.S. Geological Survey (USGS) Georgia Water Science Center-in cooperation with Federal, State, and local agencies-collected surface-water streamflow, water-quality, and ecological data during the 2005 Water Year (October 1, 2004-September 30, 2005). These data were compiled into layers of an interactive ArcReaderTM published map document (pmf). ArcReaderTM is a product of Environmental Systems Research Institute, Inc (ESRI?). Datasets represented on the interactive map are * continuous daily mean streamflow * continuous daily mean water levels * continuous daily total precipitation * continuous daily water quality (water temperature, specific conductance dissolved oxygen, pH, and turbidity) * noncontinuous peak streamflow * miscellaneous streamflow measurements * lake or reservoir elevation * periodic surface-water quality * periodic ecological data * historical continuous daily mean streamflow discontinued prior to the 2005 water year The map interface provides the ability to identify a station in spatial reference to the political boundaries of the State of Georgia and other features-such as major streams, major roads, and other collection stations. Each station is hyperlinked to a station summary showing seasonal and annual stream characteristics for the current year and for the period of record. For continuous discharge stations, the station summary includes a one page graphical summary page containing five graphs, a station map, and a photograph of the station. The graphs provide a quick overview of the current and period-of-record hydrologic conditions of the station by providing a daily mean discharge graph for the water year, monthly statistics graph for the water year and period of record, an annual mean streamflow graph for the period of record, an annual minimum 7-day average streamflow graph for the period of record, and an annual peak streamflow graph for the period of record. Additionally, data can be accessed through the layer's link

Energy efficiency in a water supply system: Energy consumption and CO2 emission

Directory of Open Access Journals (Sweden)

Helena M. Ramos

2010-09-01

Full Text Available This paper presents important fundamentals associated with water and energy efficiency and highlights the importance of using renewable energy sources. A model of multi-criteria optimization for energy efficiency based on water and environmental management policies, including the preservation of water resources and the control of water pressure and energy consumption through a hybrid energy solution, was developed and applied to a water supply system. The methodology developed includes three solutions: (1 the use of a water turbine in pipe systems where pressures are higher than necessary and pressure-reducing valves are installed, (2 the optimization of pumping operation according to the electricity tariff and water demand, and (3 the use of other renewable energy sources, including a wind turbine, to supply energy to the pumping station, with the remaining energy being sold to the national electric grid. The use of an integrated solution (water and energy proves to be a valuable input for creating benefits from available hydro energy in the water supply system in order to produce clean power, and the use of a wind source allows for the reduction of energy consumption in pumping stations, as well as of the CO2 emission to the atmosphere.

Energy-water analysis of the 10-year WECC transmission planning study cases.

Energy Technology Data Exchange (ETDEWEB)

Tidwell, Vincent Carroll; Passell, Howard David; Castillo, Cesar; Moreland, Barbara

2011-11-01

In 2011 the Department of Energy's Office of Electricity embarked on a comprehensive program to assist our Nation's three primary electric interconnections with long term transmission planning. Given the growing concern over water resources in the western U.S. the Western Electricity Coordinating Council (WECC) requested assistance with integrating water resource considerations into their broader electric transmission planning. The result is a project with three overarching objectives: (1) Develop an integrated Energy-Water Decision Support System (DSS) that will enable planners in the Western Interconnection to analyze the potential implications of water stress for transmission and resource planning. (2) Pursue the formulation and development of the Energy-Water DSS through a strongly collaborative process between the Western Electricity Coordinating Council (WECC), Western Governors Association (WGA), the Western States Water Council (WSWC) and their associated stakeholder teams. (3) Exercise the Energy-Water DSS to investigate water stress implications of the transmission planning scenarios put forward by WECC, WGA, and WSWC. The foundation for the Energy-Water DSS is Sandia National Laboratories Energy-Power-Water Simulation (EPWSim) model (Tidwell et al. 2009). The modeling framework targets the shared needs of energy and water producers, resource managers, regulators, and decision makers at the federal, state and local levels. This framework provides an interactive environment to explore trade-offs, and 'best' alternatives among a broad list of energy/water options and objectives. The decision support framework is formulated in a modular architecture, facilitating tailored analyses over different geographical regions and scales (e.g., state, county, watershed, interconnection). An interactive interface allows direct control of the model and access to real-time results displayed as charts, graphs and maps. The framework currently supports

Studies of the viscoelastic properties of water confined between surfaces of specified chemical nature.

Energy Technology Data Exchange (ETDEWEB)

Houston, Jack E.; Grest, Gary Stephen; Moore, Nathan W.; Feibelman, Peter J.

2010-09-01

This report summarizes the work completed under the Laboratory Directed Research and Development (LDRD) project 10-0973 of the same title. Understanding the molecular origin of the no-slip boundary condition remains vitally important for understanding molecular transport in biological, environmental and energy-related processes, with broad technological implications. Moreover, the viscoelastic properties of fluids in nanoconfinement or near surfaces are not well-understood. We have critically reviewed progress in this area, evaluated key experimental and theoretical methods, and made unique and important discoveries addressing these and related scientific questions. Thematically, the discoveries include insight into the orientation of water molecules on metal surfaces, the premelting of ice, the nucleation of water and alcohol vapors between surface asperities and the lubricity of these molecules when confined inside nanopores, the influence of water nucleation on adhesion to salts and silicates, and the growth and superplasticity of NaCl nanowires.

Water-food-energy nexus index: analysis of water-energy-food nexus of crop's production system applying the indicators approach

Science.gov (United States)

El-Gafy, Inas

2017-10-01

Analysis the water-food-energy nexus is the first step to assess the decision maker in developing and evaluating national strategies that take into account the nexus. The main objective of the current research is providing a method for the decision makers to analysis the water-food-energy nexus of the crop production system at the national level and carrying out a quantitative assessment of it. Through the proposed method, indicators considering the water and energy consumption, mass productivity, and economic productivity were suggested. Based on these indicators a water-food-energy nexus index (WFENI) was performed. The study showed that the calculated WFENI of the Egyptian summer crops have scores that range from 0.21 to 0.79. Comparing to onion (the highest scoring WFENI,i.e., the best score), rice has the lowest WFENI among the summer food crops. Analysis of the water-food-energy nexus of forty-two Egyptian crops in year 2010 was caried out (energy consumed for irrigation represent 7.4% of the total energy footprint). WFENI can be applied to developed strategies for the optimal cropping pattern that minimizing the water and energy consumption and maximizing their productivity. It can be applied as a holistic tool to evaluate the progress in the water and agricultural national strategies. Moreover, WFENI could be applied yearly to evaluate the performance of the water-food-energy nexus managmant.

Energy fluxes in oil palm plantations as affected by water storage in the trunk

Science.gov (United States)

Meijide, Ana; Röll, Alexander; Fan, Yuanchao; Herbst, Mathias; Niu, Furong; Tiedemann, Frank; June, Tania; Rauf, Abdul; Hölscher, Dirk; Knohl, Alexander

2017-04-01

Oil palm is increasingly expanding, particularly in Indonesia, but information on water and energy fluxes in oil palm plantations is still very limited and on how those are affected by environmental conditions or oil palm age. Using the eddy covariance technique, we studied turbulent fluxes of sensible (H) and latent (LE) heat and gross primary production (GPP) for 8 months each in a young oil palm plantation (1-year old) and subsequently in a mature plantation (12-year old) in Jambi Province, Sumatra, Indonesia. We measured transpiration (T) simultaneously using a sap flux technique. The energy budget was dominated by LE in both plantations, particularly in the mature one, where it represented up to 70% of the available energy. In the young oil palm plantation, evapotranspiration (ET) was significantly reduced and H fluxes were higher. This affected the Bowen ratio, defined as the ratio of H and LE, which was higher in the 1-year old plantation (0.67±0.33), where it remained constant during the day, than in the mature plantation (0.14±0.09), where it varied considerably over the day, suggesting that water accumulated inside the canopy. Using the Community Land Model (CLM), a process based land surface model that has been adapted to oil palm functional traits (i.e. CLM-Palm), we investigated the contribution of different water sources to the measured fluxes. CLM-Palm differentiates leaf and stem surfaces in modelling water interception and is therefore able to diagnose the fraction of dry leaves that contribute to T and the wet fraction of all vegetation surfaces (leaf and stem) that contributes to evaporation. Results from our simulations strengthen our hypothesis of significant contribution of canopy evaporation to ET. As observed in the field, water accumulates inside the canopy in the mature plantation in oil palm trunk surfaces including epiphytes, creating water reservoirs in the trunk, which potentially contribute to ET when they evaporate. The decoupling

Stable water isotope simulation by current land-surface schemes:Results of IPILPS phase 1

Energy Technology Data Exchange (ETDEWEB)

Henderson-Sellers, A.; Fischer, M.; Aleinov, I.; McGuffie, K.; Riley, W.J.; Schmidt, G.A.; Sturm, K.; Yoshimura, K.; Irannejad, P.

2005-10-31

Phase 1 of isotopes in the Project for Intercomparison of Land-surface Parameterization Schemes (iPILPS) compares the simulation of two stable water isotopologues ({sup 1}H{sub 2} {sup 18}O and {sup 1}H{sup 2}H{sup 16}O) at the land-atmosphere interface. The simulations are off-line, with forcing from an isotopically enabled regional model for three locations selected to offer contrasting climates and ecotypes: an evergreen tropical forest, a sclerophyll eucalypt forest and a mixed deciduous wood. Here we report on the experimental framework, the quality control undertaken on the simulation results and the method of intercomparisons employed. The small number of available isotopically-enabled land-surface schemes (ILSSs) limits the drawing of strong conclusions but, despite this, there is shown to be benefit in undertaking this type of isotopic intercomparison. Although validation of isotopic simulations at the land surface must await more, and much more complete, observational campaigns, we find that the empirically-based Craig-Gordon parameterization (of isotopic fractionation during evaporation) gives adequately realistic isotopic simulations when incorporated in a wide range of land-surface codes. By introducing two new tools for understanding isotopic variability from the land surface, the Isotope Transfer Function and the iPILPS plot, we show that different hydrological parameterizations cause very different isotopic responses. We show that ILSS-simulated isotopic equilibrium is independent of the total water and energy budget (with respect to both equilibration time and state), but interestingly the partitioning of available energy and water is a function of the models' complexity.

Sensors and OBIA synergy for operational monitoring of surface water

Science.gov (United States)

Masson, Eric; Thenard, Lucas

2010-05-01

This contribution will focus on combining Object Based Image Analysis (i.e. OBIA with e-Cognition 8) and recent sensors (i.e. Spot 5 XS, Pan and ALOS Prism, Avnir2, Palsar) to address the technical feasibility for an operational monitoring of surface water. Three cases of river meandering (India), flood mapping (Nepal) and dam's seasonal water level monitoring (Morocco) using recent sensors will present various application of surface water monitoring. The operational aspect will be demonstrated either by sensor properties (i.e. spatial resolution and bandwidth), data acquisition properties (i.e. multi sensor, return period and near real-time acquisition) but also with OBIA algorithms (i.e. fusion of multi sensors / multi resolution data and batch processes). In the first case of river meandering (India) we will address multi sensor and multi date satellite acquisition to monitor the river bed mobility within a floodplain using an ALOS dataset. It will demonstrate the possibility of an operational monitoring system that helps the geomorphologist in the analysis of fluvial dynamic and sediment budget for high energy rivers. In the second case of flood mapping (Nepal) we will address near real time Palsar data acquisition at high spatial resolution to monitor and to map a flood extension. This ALOS sensor takes benefit both from SAR and L band properties (i.e. atmospheric transparency, day/night acquisition, low sensibility to surface wind). It's a real achievement compared to optical imagery or even other high resolution SAR properties (i.e. acquisition swath, bandwidth and data price). These advantages meet the operational needs set by crisis management of hydrological disasters but also for the implementation of flood risk management plans. The last case of dam surface water monitoring (Morocco) will address an important issue of water resource management in countries affected by water scarcity. In such countries water users have to cope with over exploitation

How might renewable energy technologies fit in the food-water-energy nexus?

Science.gov (United States)

Newmark, R. L.; Macknick, J.; Heath, G.; Ong, S.; Denholm, P.; Margolis, R.; Roberts, B.

2011-12-01

Feeding the growing population in the U.S. will require additional land for crop and livestock production. Similarly, a growing population will require additional sources of energy. Renewable energy is likely to play an increased role in meeting the new demands of electricity consumers. Renewable energy technologies can differ from conventional technologies in their operation and their siting locations. Many renewable energy technologies have a lower energy density than conventional technologies and can also have large land use requirements. Much of the prime area suitable for renewable energy development in the U.S. has historically been used for agricultural production, and there is some concern that renewable energy installations could displace land currently producing food crops. In addition to requiring vast expanses of land, both agriculture and renewable energy can require water. The agriculture and energy sectors are responsible for the majority of water withdrawals in the U.S. Increases in both agricultural and energy demand can lead to increases in water demands, depending on crop management and energy technologies employed. Water is utilized in the energy industry primarily for power plant cooling, but it is also required for steam cycle processes and cleaning. Recent characterizations of water use by different energy and cooling system technologies demonstrate the choice of fuel and cooling system technologies can greatly impact the withdrawals and the consumptive use of water in the energy industry. While some renewable and conventional technology configurations can utilize more water per unit of land than irrigation-grown crops, other renewable technology configurations utilize no water during operations and could lead to reduced stress on water resources. Additionally, co-locating agriculture and renewable energy production is also possible with many renewable technologies, avoiding many concerns about reductions in domestic food production. Various

Transport and transformation of surface water masses across the ...

African Journals Online (AJOL)

Transport and transformation of surface water masses across the Mascarene Plateau during the Northeast Monsoon season. ... Mixing occurs in the central gap between intermediate water masses (Red Sea Water [RSW] and Antarctic Intermediate Water [AAIW]) as well as in the upper waters (Subtropical Surface Water ...

Surface water quality assessment using factor analysis

African Journals Online (AJOL)

2006-01-16

Jan 16, 2006 ... Surface water, groundwater quality assessment and environ- .... Urbanisation influences the water cycle through changes in flow and water ..... tion of aquatic life, CCME water quality Index 1, 0. User`s ... Water, Air Soil Pollut.

Quantifying energy and water fluxes in dry dune ecosystems of the Netherlands

Science.gov (United States)

Voortman, B. R.; Bartholomeus, R. P.; van der Zee, S. E. A. T. M.; Bierkens, M. F. P.; Witte, J. P. M.

2015-09-01

Coastal and inland dunes provide various ecosystem services that are related to groundwater, such as drinking water production and biodiversity. To manage groundwater in a sustainable manner, knowledge of actual evapotranspiration (ETa) for the various land covers in dunes is essential. Aiming at improving the parameterization of dune vegetation in hydrometeorological models, this study explores the magnitude of energy and water fluxes in an inland dune ecosystem in the Netherlands. Hydrometeorological measurements were used to parameterize the Penman-Monteith evapotranspiration model for four different surfaces: bare sand, moss, grass and heather. We found that the net longwave radiation (Rnl) was the largest energy flux for most surfaces during daytime. However, modeling this flux by a calibrated FAO-56 Rnl model for each surface and for hourly time steps was unsuccessful. Our Rnl model, with a novel submodel using solar elevation angle and air temperature to describe the diurnal pattern in radiative surface temperature, improved Rnl simulations considerably. Model simulations of evaporation from moss surfaces showed that the modulating effect of mosses on the water balance is species-dependent. We demonstrate that dense moss carpets (Campylopus introflexus) evaporate more (5 %, +14 mm) than bare sand (total of 258 mm in 2013), while more open-structured mosses (Hypnum cupressiforme) evaporate less (-30 %, -76 mm) than bare sand. Additionally, we found that a drought event in the summer of 2013 showed a pronounced delayed signal on lysimeter measurements of ETa for the grass and heather surfaces, respectively. Due to the desiccation of leaves after the drought event, and their feedback on the surface resistance, the potential evapotranspiration in the year 2013 dropped by 9 % (-37 mm) and 10 % (-61 mm) for the grass and heather surfaces, respectively, which subsequently led to lowered ETa of 8 % (-29 mm) and 7 % (-29 mm). These feedbacks are of importance for

Thirst for Power: Energy, Water and Human Survival

Science.gov (United States)

Webber, M.

2016-12-01

Energy, food and water are precious resources, and they are interconnected. The energy sector uses a lot of water, the food sector uses a lot of energy and water, the water sector uses a lot of energy, and as a nation we are contemplating a biofuels policy that uses food for energy. The thermoelectric power sector alone is the largest user of water in the U.S., withdrawing 200 billion gallons daily for powerplant cooling. Conversely, the water sector is responsible for over twelve percent of national energy consumption for moving, pumping, treating, and heating water. The food system uses over ten percent of national energy consumption. This interdependence means that droughts can cause energy shortages, and power outages can bring the water system to a halt, while energy and water challenges pose constraints to our food system. It also means that water efficiency is a pathway to energy efficiency and vice versa. This talk will give a big-picture overview of global food, energy and water trends to describe how they interact, what conflicts are looming, and how they can work together. This talk will include the vulnerabilities and cross-cutting solutions such as efficient markets and smart technologies that embed more information about resource management. It will include discussion of how population growth, economic growth, climate change, and short-sighted policies are likely to make things worse. Yet, more integrated planning with long-term sustainability in mind along with cultural shifts, advanced technologies, and better design can avert such a daunting future. Combining anecdotes and personal stories with insights into the latest science of energy and water, this talk will identify a hopeful path toward wise, long-range water-energy decisions and a more reliable and abundant future for humanity.

Quantifying Surface Energy Flux Estimation Uncertainty Using Land Surface Temperature Observations

Science.gov (United States)

French, A. N.; Hunsaker, D.; Thorp, K.; Bronson, K. F.

2015-12-01

Remote sensing with thermal infrared is widely recognized as good way to estimate surface heat fluxes, map crop water use, and detect water-stressed vegetation. When combined with net radiation and soil heat flux data, observations of sensible heat fluxes derived from surface temperatures (LST) are indicative of instantaneous evapotranspiration (ET). There are, however, substantial reasons LST data may not provide the best way to estimate of ET. For example, it is well known that observations and models of LST, air temperature, or estimates of transport resistances may be so inaccurate that physically based model nevertheless yield non-meaningful results. Furthermore, using visible and near infrared remote sensing observations collected at the same time as LST often yield physically plausible results because they are constrained by less dynamic surface conditions such as green fractional cover. Although sensitivity studies exist that help identify likely sources of error and uncertainty, ET studies typically do not provide a way to assess the relative importance of modeling ET with and without LST inputs. To better quantify model benefits and degradations due to LST observational inaccuracies, a Bayesian uncertainty study was undertaken using data collected in remote sensing experiments at Maricopa, Arizona. Visible, near infrared and thermal infrared data were obtained from an airborne platform. The prior probability distribution of ET estimates were modeled using fractional cover, local weather data and a Penman-Monteith mode, while the likelihood of LST data was modeled from a two-source energy balance model. Thus the posterior probabilities of ET represented the value added by using LST data. Results from an ET study over cotton grown in 2014 and 2015 showed significantly reduced ET confidence intervals when LST data were incorporated.

Theoretical model of droplet wettability on a low-surface-energy solid under the influence of gravity.

Science.gov (United States)

Yonemoto, Yukihiro; Kunugi, Tomoaki

2014-01-01

The wettability of droplets on a low surface energy solid is evaluated experimentally and theoretically. Water-ethanol binary mixture drops of several volumes are used. In the experiment, the droplet radius, height, and contact angle are measured. Analytical equations are derived that incorporate the effect of gravity for the relationships between the droplet radius and height, radius and contact angle, and radius and liquid surface energy. All the analytical equations display good agreement with the experimental data. It is found that the fundamental wetting behavior of the droplet on the low surface energy solid can be predicted by our model which gives geometrical information of the droplet such as the contact angle, droplet radius, and height from physical values of liquid and solid.

Rapid surface-water volume estimations in beaver ponds

Science.gov (United States)

Karran, Daniel J.; Westbrook, Cherie J.; Wheaton, Joseph M.; Johnston, Carol A.; Bedard-Haughn, Angela

2017-02-01

Beaver ponds are surface-water features that are transient through space and time. Such qualities complicate the inclusion of beaver ponds in local and regional water balances, and in hydrological models, as reliable estimates of surface-water storage are difficult to acquire without time- and labour-intensive topographic surveys. A simpler approach to overcome this challenge is needed, given the abundance of the beaver ponds in North America, Eurasia, and southern South America. We investigated whether simple morphometric characteristics derived from readily available aerial imagery or quickly measured field attributes of beaver ponds can be used to approximate surface-water storage among the range of environmental settings in which beaver ponds are found. Studied were a total of 40 beaver ponds from four different sites in North and South America. The simplified volume-area-depth (V-A-h) approach, originally developed for prairie potholes, was tested. With only two measurements of pond depth and corresponding surface area, this method estimated surface-water storage in beaver ponds within 5 % on average. Beaver pond morphometry was characterized by a median basin coefficient of 0.91, and dam length and pond surface area were strongly correlated with beaver pond storage capacity, regardless of geographic setting. These attributes provide a means for coarsely estimating surface-water storage capacity in beaver ponds. Overall, this research demonstrates that reliable estimates of surface-water storage in beaver ponds only requires simple measurements derived from aerial imagery and/or brief visits to the field. Future research efforts should be directed at incorporating these simple methods into both broader beaver-related tools and catchment-scale hydrological models.

From water to energy. The virtual water content and water footprint of biofuel consumption in Spain

Energy Technology Data Exchange (ETDEWEB)

Elena, Galan-del-Castillo [Universitat Autonoma de Barcelona (Spain); Esther, Velazquez [Pablo de Olavide University, Department of Economics, Crta. Utrera, Km.1, 41013 Seville (Spain)

2010-03-15

Energy diversification and the use of renewable energy sources are key points in the European energy strategy. Biofuels are the most popular renewable resource option for the transport sector, and the European Union has established objectives that the Member States must adopt and implement. However, biofuel production at such a scale requires a considerable amount of water resources, and this water-energy nexus is rarely taken into account. This paper shows the strong nexus between water and energy in biofuel production and estimates the virtual water (VW) content and the water footprint (WF) from the raw material production that will be needed to reach the Spanish targets for biofuel consumption by 2010. The results show how the impact of such targets on the global and local water situation could be reduced through virtual water imports and, at the same time, how these imports could increase Spain's water and energy dependence. Hence, in order to manage water from an integral perspective of the territory, the inclusion of biofuel consumption objectives should go hand in hand with measures to reduce the demand of energy in the transport sector. (author)

From water to energy: The virtual water content and water footprint of biofuel consumption in Spain

Energy Technology Data Exchange (ETDEWEB)

Galan-del-Castillo, Elena [Universitat Autonoma de Barcelona (Spain); Velazquez, Esther, E-mail: evelalo@upo.e [Pablo de Olavide University, Department of Economics, Crta. Utrera, Km.1, 41013 Seville (Spain)

2010-03-15

Energy diversification and the use of renewable energy sources are key points in the European energy strategy. Biofuels are the most popular renewable resource option for the transport sector, and the European Union has established objectives that the Member States must adopt and implement. However, biofuel production at such a scale requires a considerable amount of water resources, and this water-energy nexus is rarely taken into account. This paper shows the strong nexus between water and energy in biofuel production and estimates the virtual water (VW) content and the water footprint (WF) from the raw material production that will be needed to reach the Spanish targets for biofuel consumption by 2010. The results show how the impact of such targets on the global and local water situation could be reduced through virtual water imports and, at the same time, how these imports could increase Spain's water and energy dependence. Hence, in order to manage water from an integral perspective of the territory, the inclusion of biofuel consumption objectives should go hand in hand with measures to reduce the demand of energy in the transport sector.

From water to energy. The virtual water content and water footprint of biofuel consumption in Spain

International Nuclear Information System (INIS)

Elena, Galan-del-Castillo; Esther, Velazquez

2010-01-01

Energy diversification and the use of renewable energy sources are key points in the European energy strategy. Biofuels are the most popular renewable resource option for the transport sector, and the European Union has established objectives that the Member States must adopt and implement. However, biofuel production at such a scale requires a considerable amount of water resources, and this water-energy nexus is rarely taken into account. This paper shows the strong nexus between water and energy in biofuel production and estimates the virtual water (VW) content and the water footprint (WF) from the raw material production that will be needed to reach the Spanish targets for biofuel consumption by 2010. The results show how the impact of such targets on the global and local water situation could be reduced through virtual water imports and, at the same time, how these imports could increase Spain's water and energy dependence. Hence, in order to manage water from an integral perspective of the territory, the inclusion of biofuel consumption objectives should go hand in hand with measures to reduce the demand of energy in the transport sector. (author)

Energy requirements for waste water treatment.

Science.gov (United States)

Svardal, K; Kroiss, H

2011-01-01

The actual mathematical models describing global climate closely link the detected increase in global temperature to anthropogenic activity. The only energy source we can rely on in a long perspective is solar irradiation which is in the order of 10,000 kW/inhabitant. The actual primary power consumption (mainly based on fossil resources) in the developed countries is in the range of 5 to 10 kW/inhabitant. The total power contained in our nutrition is in the range of 0.11 kW/inhabitant. The organic pollution of domestic waste water corresponds to approximately 0.018 kW/inhabitant. The nutrients contained in the waste water can also be converted into energy equivalents replacing market fertiliser production. This energy equivalent is in the range of 0.009 kW/inhabitant. Hence waste water will never be a relevant source of energy as long as our primary energy consumption is in the range of several kW/inhabitant. The annual mean primary power demand of conventional municipal waste water treatment with nutrient removal is in the range of 0.003-0.015 kW/inhabitant. In principle it is already possible to reduce this value for external energy supply to zero. Such plants should be connected to an electrical grid in order to keep investment costs low. Peak energy demand will be supported from the grid and surplus electric energy from the plant can be is fed to the grid. Zero 'carbon footprint' will not be affected by this solution. Energy minimisation must never negatively affect treatment efficiency because water quality conservation is more important for sustainable development than the possible reduction in energy demand. This argument is strongly supported by economical considerations as the fixed costs for waste water infrastructure are dominant.

Energy exchange in thermal energy atom-surface scattering: impulsive models

International Nuclear Information System (INIS)

Barker, J.A.; Auerbach, D.J.

1979-01-01

Energy exchange in thermal energy atom surface collisions is studied using impulsive ('hard cube' and 'hard sphere') models. Both models reproduce the observed nearly linear relation between outgoing and incoming energies. In addition, the hard-sphere model accounts for the widths of the outcoming energy distributions. (Auth.)

The Water-Energy-Food Nexus of Unconventional Fossil Fuels.

Science.gov (United States)

Rosa, L.; Davis, K. F.; Rulli, M. C.; D'Odorico, P.

2017-12-01

Extraction of unconventional fossil fuels has increased human pressure on freshwater resources. Shale formations are globally abundant and widespread. Their extraction through hydraulic fracturing, a water-intensive process, may be limited by water availability, especially in arid and semiarid regions where stronger competition is expected to emerge with food production. It is unclear to what extent and where shale resource extraction could compete with local water and food security. Although extraction of shale deposits materializes economic gains and increases energy security, in some regions it may exacerbate the reliance on food imports, thereby decreasing regional food security. We consider the global distribution of known shale deposits suitable for oil and gas extraction and evaluate their impacts on water resources for food production and other human and environmental needs. We find that 17% of the world's shale deposits are located in areas affected by both surface water and groundwater stress, 50% in areas with surface water stress, and about 30% in irrigated areas. In these regions shale oil and shale gas production will likely threaten water and food security. These results highlight the importance of hydrologic analyses in the extraction of fossil fuels. Indeed, neglecting water availability as one of the possible factors constraining the development of shale deposits around the world could lead to unaccounted environmental impacts and business risks for firms and investors. Because several shale deposits in the world stretch across irrigated agricultural areas in arid regions, an adequate development of these resources requires appropriate environmental, economic and political decisions.

Experience with remediating radiostrontium-contaminated ground water and surface water with versions of AECL's CHEMIC process

International Nuclear Information System (INIS)

Vijayan, S.

2006-01-01

Numerous approaches have been developed for the remediation of radiostrontium ( 90 Sr) contaminated ground water and surface water. Several strontium-removal technologies have been assessed and applied at AECL's (Atomic Energy of Canada Limited) Chalk River Laboratories. These include simple ion exchange (based on non-selective natural zeolites or selective synthetic inorganic media), and precipitation and filtration with or without ion exchange as a final polishing step. AECL's CHEMIC process is based on precipitation-microfiltration and ion-exchange steps. This paper presents data related to radiostrontium removal performance and other operational experiences including troubleshooting with two round-the-clock, pilot-scale water remediation plants based on AECL's CHEMIC process at the Chalk River Laboratories site. These plants began operation in the early 1990s. Through optimization of process chemistry and operation, high values for system capability and system availability factors, and low concentrations of 90 Sr in the discharge water approaching drinking water standard can be achieved. (author)

Solar energy converter using surface plasma waves

Science.gov (United States)

Anderson, L. M. (Inventor)

1984-01-01

Sunlight is dispersed over a diffraction grating formed on the surface of a conducting film on a substrate. The angular dispersion controls the effective grating period so that a matching spectrum of surface plasmons is excited for parallel processing on the conducting film. The resulting surface plasmons carry energy to an array of inelastic tunnel diodes. This solar energy converter does not require different materials for each frequency band, and sunlight is directly converted to electricity in an efficient manner by extracting more energy from the more energetic photons.

Critical assessment of Pt surface energy - An atomistic study

Science.gov (United States)

Kim, Jin-Soo; Seol, Donghyuk; Lee, Byeong-Joo

2018-04-01

Despite the fact that surface energy is a fundamental quantity in understanding surface structure of nanoparticle, the results of experimental measurements and theoretical calculations for the surface energy of pure Pt show a wide range of scattering. It is necessary to further ensure the surface energy of Pt to find the equilibrium shape and atomic configuration in Pt bimetallic nanoparticles accurately. In this article, we critically assess and optimize the Pt surface energy using a semi-empirical atomistic approach based on the second nearest-neighbor modified embedded-atom method interatomic potential. That is, the interatomic potential of pure Pt was adjusted in a way that the surface segregation tendency in a wide range of Pt binary alloys is reproduced in accordance with experimental information. The final optimized Pt surface energy (mJ/m2) is 2036 for (100) surface, 2106 for (110) surface, and 1502 for (111) surface. The potential can be utilized to find the equilibrium shape and atomic configuration of Pt bimetallic nanoparticles more accurately.

RELATIONSHIP BETWEEN FOAMING BEHAVIOR AND SURFACE ENERGY OF ASPHALT BINDER

Directory of Open Access Journals (Sweden)

Jian-ping Xu

2017-12-01

Full Text Available To solve the problem of insufficiency in microscopic performance of foamed asphalt binder, surface energy theory was utilized to analyze the foaming behavior and wettability of asphalt binder. Based on the surface energy theory, the Wilhelmy plate method and universal sorption device method were employed to measure the surface energy components of asphalt binders and aggregates, respectively. Combined with the traditional evaluation indictor for foamed asphalt, the relationship between the foaming property and surface energy of asphalt binder was analyzed. According to the surface energy components, the wettability of asphalt binder to aggregate was calculated to verify the performance of foamed asphalt mixture. Results indicate that the foaming behavior of asphalt will be influenced by surface energy, which will increase with the decline of surface energy. In addition, the surface energy of asphalt binder significantly influences the wettability of asphalt binder to aggregates. Meanwhile, there is an inversely proportional relationship between surface energy of asphalt binder and wettability. Therefore, it can be demonstrated that surface energy is a good indictor which can be used to evaluate the foaming behavior of the asphalt binder. And it is suggested to choose the asphalt binder with lower surface energy in the process of design of foamed asphalt mixture.

Modeling the Surface Energy Balance of the Core of an Old Mediterranean City: Marseille.

Science.gov (United States)

Lemonsu, A.; Grimmond, C. S. B.; Masson, V.

2004-02-01

The Town Energy Balance (TEB) model, which parameterizes the local-scale energy and water exchanges between urban surfaces and the atmosphere by treating the urban area as a series of urban canyons, coupled to the Interactions between Soil, Biosphere, and Atmosphere (ISBA) scheme, was run in offline mode for Marseille, France. TEB's performance is evaluated with observations of surface temperatures and surface energy balance fluxes collected during the field experiments to constrain models of atmospheric pollution and transport of emissions (ESCOMPTE) urban boundary layer (UBL) campaign. Particular attention was directed to the influence of different surface databases, used for input parameters, on model predictions. Comparison of simulated canyon temperatures with observations resulted in improvements to TEB parameterizations by increasing the ventilation. Evaluation of the model with wall, road, and roof surface temperatures gave good results. The model succeeds in simulating a sensible heat flux larger than heat storage, as observed. A sensitivity comparison using generic dense city parameters, derived from the Coordination of Information on the Environment (CORINE) land cover database, and those from a surface database developed specifically for the Marseille city center shows the importance of correctly documenting the urban surface. Overall, the TEB scheme is shown to be fairly robust, consistent with results from previous studies.

Global modelling of Cryptosporidium in surface water

Science.gov (United States)

Vermeulen, Lucie; Hofstra, Nynke

2016-04-01

Introduction Waterborne pathogens that cause diarrhoea, such as Cryptosporidium, pose a health risk all over the world. In many regions quantitative information on pathogens in surface water is unavailable. Our main objective is to model Cryptosporidium concentrations in surface waters worldwide. We present the GloWPa-Crypto model and use the model in a scenario analysis. A first exploration of global Cryptosporidium emissions to surface waters has been published by Hofstra et al. (2013). Further work has focused on modelling emissions of Cryptosporidium and Rotavirus to surface waters from human sources (Vermeulen et al 2015, Kiulia et al 2015). A global waterborne pathogen model can provide valuable insights by (1) providing quantitative information on pathogen levels in data-sparse regions, (2) identifying pathogen hotspots, (3) enabling future projections under global change scenarios and (4) supporting decision making. Material and Methods GloWPa-Crypto runs on a monthly time step and represents conditions for approximately the year 2010. The spatial resolution is a 0.5 x 0.5 degree latitude x longitude grid for the world. We use livestock maps (http://livestock.geo-wiki.org/) combined with literature estimates to calculate spatially explicit livestock Cryptosporidium emissions. For human Cryptosporidium emissions, we use UN population estimates, the WHO/UNICEF JMP sanitation country data and literature estimates of wastewater treatment. We combine our emissions model with a river routing model and data from the VIC hydrological model (http://vic.readthedocs.org/en/master/) to calculate concentrations in surface water. Cryptosporidium survival during transport depends on UV radiation and water temperature. We explore pathogen emissions and concentrations in 2050 with the new Shared Socio-economic Pathways (SSPs) 1 and 3. These scenarios describe plausible future trends in demographics, economic development and the degree of global integration. Results and

Recent Progress in Energy-Driven Water Splitting.

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Tee, Si Yin; Win, Khin Yin; Teo, Wee Siang; Koh, Leng-Duei; Liu, Shuhua; Teng, Choon Peng; Han, Ming-Yong

2017-05-01

Hydrogen is readily obtained from renewable and non-renewable resources via water splitting by using thermal, electrical, photonic and biochemical energy. The major hydrogen production is generated from thermal energy through steam reforming/gasification of fossil fuel. As the commonly used non-renewable resources will be depleted in the long run, there is great demand to utilize renewable energy resources for hydrogen production. Most of the renewable resources may be used to produce electricity for driving water splitting while challenges remain to improve cost-effectiveness. As the most abundant energy resource, the direct conversion of solar energy to hydrogen is considered the most sustainable energy production method without causing pollutions to the environment. In overall, this review briefly summarizes thermolytic, electrolytic, photolytic and biolytic water splitting. It highlights photonic and electrical driven water splitting together with photovoltaic-integrated solar-driven water electrolysis.

Surface free energy predominates in cell adhesion to hydroxyapatite through wettability.

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Nakamura, Miho; Hori, Naoko; Ando, Hiroshi; Namba, Saki; Toyama, Takeshi; Nishimiya, Nobuyuki; Yamashita, Kimihiro

2016-05-01

The initial adhesion of cells to biomaterials is critical in the regulation of subsequent cell behaviors. The purpose of this study was to investigate a mechanism through which the surface wettability of biomaterials can be improved and determine the effects of biomaterial surface characteristics on cellular behaviors. We investigated the surface characteristics of various types of hydroxyapatite after sintering in different atmospheres and examined the effects of various surface characteristics on cell adhesion to study cell-biomaterial interactions. Sintering atmosphere affects the polarization capacity of hydroxyapatite by changing hydroxide ion content and grain size. Compared with hydroxyapatite sintered in air, hydroxyapatite sintered in saturated water vapor had a higher polarization capacity that increased surface free energy and improved wettability, which in turn accelerated cell adhesion. We determined the optimal conditions of hydroxyapatite polarization for the improvement of surface wettability and acceleration of cell adhesion. Copyright © 2016 Elsevier B.V. All rights reserved.

A topological screening heuristic for low-energy, high-index surfaces

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Sun, Wenhao; Ceder, Gerbrand

2018-03-01

Robust ab initio investigations of nanoparticle surface properties require a method to identify candidate low-energy surface facets a priori. By assuming that low-energy surfaces are planes with high atomic density, we devise an efficient algorithm to screen for low-energy surface orientations, even if they have high (hkl) miller indices. We successfully predict the observed low-energy, high-index { 10 12 bar } and { 10 1 bar 4 } surfaces of hematite α-Fe2O3, the {311} surfaces of cuprite Cu2O, and the {112} surfaces of anatase TiO2. We further tabulate candidate low-energy surface orientations for nine of the most common binary oxide structures. Screened surfaces are found to be generally applicable across isostructural compounds with varying chemistries, although relative surface energies between facets may vary based on the preferred coordination of the surface atoms.

Surface energy for electroluminescent polymers and indium-tin-oxide

International Nuclear Information System (INIS)

Zhong Zhiyou; Yin Sheng; Liu Chen; Zhong Youxin; Zhang Wuxing; Shi Dufang; Wang Chang'an

2003-01-01

The contact angles on the thin films of poly[2-methoxy-5-(2'-ethylhexyloxy)-1,4-phenylenevinylene] (MEH-PPV) and indium-tin-oxide (ITO) were measured by the sessile-drop technique. The surface energies of the films were calculated using the Owens-Wendt (OW) and van Oss-Chaudhury-Good (vOCG) approaches. The overall total surface energies of MEH-PPV and the as-received ITO were 30.75 and 30.07 mJ/m 2 , respectively. Both approaches yielded almost the same surface energies. The surface energies were mainly contributed from the dispersion interactions or Lifshitz-van der Waals (LW) interactions for both MEH-PPV and ITO. The changes in the contact angles and surface energies of the ITO films, due to different solvent cleaning processes and oxygen plasma treatments, were analyzed. Experimental results revealed that the total surface energy of the ITO films increased after various cleaning processes. In comparison with different solvents used in this study, we found that methanol is an effective solvent for ITO cleaning, as a higher surface energy was observed. ITO films treated with oxygen plasma showed the highest surface energy. This work demonstrated that contact angle measurement is a useful method to diagnose the cleaning effect on ITO films

Performance of five surface energy balance models for estimating daily evapotranspiration in high biomass sorghum

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Wagle, Pradeep; Bhattarai, Nishan; Gowda, Prasanna H.; Kakani, Vijaya G.

2017-06-01

Robust evapotranspiration (ET) models are required to predict water usage in a variety of terrestrial ecosystems under different geographical and agrometeorological conditions. As a result, several remote sensing-based surface energy balance (SEB) models have been developed to estimate ET over large regions. However, comparison of the performance of several SEB models at the same site is limited. In addition, none of the SEB models have been evaluated for their ability to predict ET in rain-fed high biomass sorghum grown for biofuel production. In this paper, we evaluated the performance of five widely used single-source SEB models, namely Surface Energy Balance Algorithm for Land (SEBAL), Mapping ET with Internalized Calibration (METRIC), Surface Energy Balance System (SEBS), Simplified Surface Energy Balance Index (S-SEBI), and operational Simplified Surface Energy Balance (SSEBop), for estimating ET over a high biomass sorghum field during the 2012 and 2013 growing seasons. The predicted ET values were compared against eddy covariance (EC) measured ET (ETEC) for 19 cloud-free Landsat image. In general, S-SEBI, SEBAL, and SEBS performed reasonably well for the study period, while METRIC and SSEBop performed poorly. All SEB models substantially overestimated ET under extremely dry conditions as they underestimated sensible heat (H) and overestimated latent heat (LE) fluxes under dry conditions during the partitioning of available energy. METRIC, SEBAL, and SEBS overestimated LE regardless of wet or dry periods. Consequently, predicted seasonal cumulative ET by METRIC, SEBAL, and SEBS were higher than seasonal cumulative ETEC in both seasons. In contrast, S-SEBI and SSEBop substantially underestimated ET under too wet conditions, and predicted seasonal cumulative ET by S-SEBI and SSEBop were lower than seasonal cumulative ETEC in the relatively wetter 2013 growing season. Our results indicate the necessity of inclusion of soil moisture or plant water stress

Heat and turbulent kinetic energy budgets for surface layer cooling induced by the passage of Hurricane Frances (2004)

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Huang, Peisheng; Sanford, Thomas B.; Imberger, JöRg

2009-12-01