WorldWideScience

Sample records for surface water dms

  1. Vertical variability of seawater DMS in the South Pacific Ocean and its implication for atmospheric and surface seawater DMS.

    Science.gov (United States)

    Lee, Gangwoong; Park, Jooyoung; Jang, Yuwoon; Lee, Meehye; Kim, Kyung-Ryul; Oh, Jae-Ryoung; Kim, Dongseon; Yi, Hi-Il; Kim, Tong-Yup

    2010-02-01

    Shipboard measurements of atmospheric dimethylsulfide (DMS) and sea surface water DMS were performed aboard the R/V Onnuri across the South Pacific from Santiago, Chile to Fiji in February 2000. Hydrographic profiles of DMS, dissolved dimethylsulfoniopropionate (DMSP(d)), and particulate DMSP(p) in the upper 200m were obtained at 16 stations along the track. Atmospheric and sea surface water DMS concentrations ranged from 3 to 442pptv and from 0.1 to 19.9nM, respectively; the mean values of 61pptv and 2.1nM, respectively, were comparable to those from previous studies in the South Pacific. The South Pacific Gyre was distinguished by longitudinal-vertical distributions of DMS, DMSP(d), and DMSP(p), which was thought to be associated with the characteristic modification of biological activities that occurs mainly due to significant change in water temperature. The averaged DMS maximum appeared at 40m depth, whereas DMSP(p) and DMSP(d) maxima coincided with that of dissolved oxygen content at 60-80m. The sea-to-air fluxes of DMS were estimated to be 0.4-11.3micromold(-1)m(-2) (mean=2.8micromold(-1)m(-2)). A fairly good correlation between atmospheric DMS and sea-to-air DMS flux indicated that atmospheric DMS concentration was more sensitive to change in physical parameters than its photochemical removal process or surface seawater DMS concentrations.

  2. Photodegradation of dimethyl sulfide (DMS) in natural waters: laboratory assessment of the nitrate-photolysis-induced DMS oxidation.

    Science.gov (United States)

    Bouillon, René-Christian; Miller, William L

    2005-12-15

    The interaction of sunlight and dissolved chromophoric matter produces reactive chemical species that are significant in the removal of dimethyl sulfide (DMS) in the surface ocean. Using artificial solar radiation, we examined the role of several inorganic components of seawater on the kinetics of NO3- -photolysis-induced DMS removal in aqueous solution. This study strongly suggests that NO3- photolysis products react significantly with DMS in aqueous solution possibly via an electrophilic attack on the electron-rich sulfur atom. This supports previous field observations that indicate that NO3- photolysis has a substantial control on DMS photochemistry in nutrient-rich waters. A key finding of this research is that the oxidation rate of DMS induced by NO3- photolysis is dramatically enhanced in the presence of bromide ion. Moreover, our results suggest that bicarbonate/carbonate ions are involved in free radical production/scavenging processes important for DMS photochemistry. These reactions are pH dependent. We propose that DMS removal by some selective free radicals derived from bromide and bicarbonate/carbonate ion oxidation is a potentially important and previously unrecognized pathway for DMS photodegradation in marine waters.

  3. Winter evolution of DMS and DMSP in Venice lagoon water and sediment.

    Science.gov (United States)

    Gambaro, Andrea; Moret, Ivo; Piazza, Rossano; Da Rin, Eleonora; Turetta, Clara; Cescon, Paolo

    2002-03-01

    The evolution of dimethylsulphide (DMS) and dimethylsulphoniopropionate (DMSP) concentrations in the water and sediment of the Venice lagoon were studied together with the concentration of chlorophyll a, temperature and the composition and density of phytoplankton to understand the role of the sediment as a source of DMS during the winter period. The temporal trend of water DMS concentration in this period showed a maximum concentration in February (75.7 nmol S l-1) related to low DMSP and chlorophyll a concentrations but to high phytoplanktonic abundance. The DMS and DMSP concentrations were greater in the sediment than in the water. The temporal trend of DMS concentration in sediment showed a maximum in February (1155 nmol S l-1) related to the maximum of DMS concentration in surface water. These observations suggested that in the winter period DMS could be produced by the conversion of the DMSP present in the bulk water but principally by that present in the sediment (microbiological degradation of DMSP or other sulphur-containing compounds) that subsequently diffuse in water.

  4. The distribution of methylated sulfur compounds, DMS and DMSP, in Canadian subarctic and Arctic marine waters during summer 2015

    Directory of Open Access Journals (Sweden)

    T. Jarníková

    2018-04-01

    Full Text Available We present seawater concentrations of dimethyl sulfide (DMS and dimethylsulfoniopropionate (DMSP measured across a transect from the Labrador Sea to the Canadian Arctic Archipelago during summer 2015. Using an automated ship-board gas chromatography system and a membrane-inlet mass spectrometer, we measured a wide range of DMS (∼ 1 to 18 nM and DMSP (∼ 1 to 150 nM concentrations. The highest DMS and DMSP concentrations occurred in a localized region of Baffin Bay, where surface waters were characterized by high chlorophyll a (chl a fluorescence, indicative of elevated phytoplankton biomass. Across the full sampling transect, there were only weak relationships between DMS(P, chl a fluorescence and other measured variables, including positive relationships between DMSP : chl a ratios and several taxonomic marker pigments, and elevated DMS(P concentrations in partially ice-covered areas. Our high spatial resolution measurements allowed us to examine DMS variability over small scales (< 1 km, documenting strong DMS concentration gradients across surface hydrographic frontal features. Our new observations fill in an important observational gap in the Arctic Ocean and provide additional information on sea–air DMS fluxes from this ocean region. In addition, this study constitutes a significant contribution to the existing Arctic DMS(P dataset and provides a baseline for future measurements in the region.

  5. Increase in dimethylsulfide (DMS emissions due to eutrophication of coastal waters offsets their reduction due to ocean acidification.

    Directory of Open Access Journals (Sweden)

    Nathalie eGypens

    2014-04-01

    Full Text Available Available information from manipulative experiments suggested that the emission of dimethylsulfide (DMS would decrease in response to the accumulation of anthropogenic CO2 in the ocean (ocean acidification. However, in coastal environments, the carbonate chemistry of surface waters was also strongly modified by eutrophication and related changes in biological activity (increased primary production and change in phytoplankton dominance during the last 50 years. Here, we tested the hypothesis that DMS emissions in marine coastal environments also strongly responded to eutrophication in addition to ocean acidification at decadal timescales. We used the R-MIRO-BIOGAS model in the eutrophied Southern Bight of the North Sea characterized by intense blooms of Phaeocystis that are high producers of dimethylsulfoniopropionate (DMSP, the precursor of DMS. We showed that, for the period from 1951 to 2007, eutrophication actually led to an increase of DMS emissions much stronger than the response of DMS emissions to ocean acidification.

  6. Gradient flux measurements of sea–air DMS transfer during the Surface Ocean Aerosol Production (SOAP experiment

    Directory of Open Access Journals (Sweden)

    M. J. Smith

    2018-04-01

    Full Text Available Direct measurements of marine dimethylsulfide (DMS fluxes are sparse, particularly in the Southern Ocean. The Surface Ocean Aerosol Production (SOAP voyage in February–March 2012 examined the distribution and flux of DMS in a biologically active frontal system in the southwest Pacific Ocean. Three distinct phytoplankton blooms were studied with oceanic DMS concentrations as high as 25 nmol L−1. Measurements of DMS fluxes were made using two independent methods: the eddy covariance (EC technique using atmospheric pressure chemical ionization–mass spectrometry (API-CIMS and the gradient flux (GF technique from an autonomous catamaran platform. Catamaran flux measurements are relatively unaffected by airflow distortion and are made close to the water surface, where gas gradients are largest. Flux measurements were complemented by near-surface hydrographic measurements to elucidate physical factors influencing DMS emission. Individual DMS fluxes derived by EC showed significant scatter and, at times, consistent departures from the Coupled Ocean–Atmosphere Response Experiment gas transfer algorithm (COAREG. A direct comparison between the two flux methods was carried out to separate instrumental effects from environmental effects and showed good agreement with a regression slope of 0.96 (r2 = 0.89. A period of abnormal downward atmospheric heat flux enhanced near-surface ocean stratification and reduced turbulent exchange, during which GF and EC transfer velocities showed good agreement but modelled COAREG values were significantly higher. The transfer velocity derived from near-surface ocean turbulence measurements on a spar buoy compared well with the COAREG model in general but showed less variation. This first direct comparison between EC and GF fluxes of DMS provides confidence in compilation of flux estimates from both techniques, as well as in the stable periods when the observations are not well predicted by the COAREG

  7. Gradient flux measurements of sea-air DMS transfer during the Surface Ocean Aerosol Production (SOAP) experiment

    Science.gov (United States)

    Smith, Murray J.; Walker, Carolyn F.; Bell, Thomas G.; Harvey, Mike J.; Saltzman, Eric S.; Law, Cliff S.

    2018-04-01

    Direct measurements of marine dimethylsulfide (DMS) fluxes are sparse, particularly in the Southern Ocean. The Surface Ocean Aerosol Production (SOAP) voyage in February-March 2012 examined the distribution and flux of DMS in a biologically active frontal system in the southwest Pacific Ocean. Three distinct phytoplankton blooms were studied with oceanic DMS concentrations as high as 25 nmol L-1. Measurements of DMS fluxes were made using two independent methods: the eddy covariance (EC) technique using atmospheric pressure chemical ionization-mass spectrometry (API-CIMS) and the gradient flux (GF) technique from an autonomous catamaran platform. Catamaran flux measurements are relatively unaffected by airflow distortion and are made close to the water surface, where gas gradients are largest. Flux measurements were complemented by near-surface hydrographic measurements to elucidate physical factors influencing DMS emission. Individual DMS fluxes derived by EC showed significant scatter and, at times, consistent departures from the Coupled Ocean-Atmosphere Response Experiment gas transfer algorithm (COAREG). A direct comparison between the two flux methods was carried out to separate instrumental effects from environmental effects and showed good agreement with a regression slope of 0.96 (r2 = 0.89). A period of abnormal downward atmospheric heat flux enhanced near-surface ocean stratification and reduced turbulent exchange, during which GF and EC transfer velocities showed good agreement but modelled COAREG values were significantly higher. The transfer velocity derived from near-surface ocean turbulence measurements on a spar buoy compared well with the COAREG model in general but showed less variation. This first direct comparison between EC and GF fluxes of DMS provides confidence in compilation of flux estimates from both techniques, as well as in the stable periods when the observations are not well predicted by the COAREG model.

  8. Sulfur isotope homogeneity of oceanic DMSP and DMS.

    Science.gov (United States)

    Amrani, Alon; Said-Ahmad, Ward; Shaked, Yeala; Kiene, Ronald P

    2013-11-12

    Oceanic emissions of volatile dimethyl sulfide (DMS) represent the largest natural source of biogenic sulfur to the global atmosphere, where it mediates aerosol dynamics. To constrain the contribution of oceanic DMS to aerosols we established the sulfur isotope ratios ((34)S/(32)S ratio, δ(34)S) of DMS and its precursor, dimethylsulfoniopropionate (DMSP), in a range of marine environments. In view of the low oceanic concentrations of DMS/P, we applied a unique method for the analysis of δ(34)S at the picomole level in individual compounds. Surface water DMSP collected from six different ocean provinces revealed a remarkable consistency in δ(34)S values ranging between +18.9 and +20.3‰. Sulfur isotope composition of DMS analyzed in freshly collected seawater was similar to δ(34)S of DMSP, showing that the in situ fractionation between these species is small (DMS to the atmosphere results in a relatively small fractionation (-0.5 ± 0.2‰) compared with the seawater DMS pool. Because δ(34)S values of oceanic DMS closely reflect that of DMSP, we conclude that the homogenous δ(34)S of DMSP at the ocean surface represents the δ(34)S of DMS emitted to the atmosphere, within +1‰. The δ(34)S of oceanic DMS flux to the atmosphere is thus relatively constant and distinct from anthropogenic sources of atmospheric sulfate, thereby enabling estimation of the DMS contribution to aerosols.

  9. Strong relationship between DMS and the solar radiation dose over the global surface ocean.

    Science.gov (United States)

    Vallina, Sergio M; Simó, Rafel

    2007-01-26

    Marine biogenic dimethylsulfide (DMS) is the main natural source of tropospheric sulfur, which may play a key role in cloud formation and albedo over the remote ocean. Through a global data analysis, we found that DMS concentrations are highly positively correlated with the solar radiation dose in the upper mixed layer of the open ocean, irrespective of latitude, plankton biomass, or temperature. This is a necessary condition for the feasibility of a negative feedback in which light-attenuating DMS emissions are in turn driven by the light dose received by the pelagic ecosystem.

  10. Surface Water & Surface Drainage

    Data.gov (United States)

    Earth Data Analysis Center, University of New Mexico — This data set contains boundaries for all surface water and surface drainage for the state of New Mexico. It is in a vector digital data structure digitized from a...

  11. Global oceanic DMS data inter-comparability

    NARCIS (Netherlands)

    Bell, T. G.; Malin, G.; Lee, G. A.; Stefels, J.; Archer, S.; Steinke, M.; Matrai, P.

    The global surface seawater dimethylsulphide (DMS) database (http://saga.pmel.noaa.gov/dms/) contains > 50,000 data points and is the second largest trace gas database after carbon dioxide. However, there has been relatively little quality control on the data that have been collated to date.

  12. Top down control of post-upwelling waters off Trivandrum: Indications from variability in DMS(P)

    Digital Repository Service at National Institute of Oceanography (India)

    Pandey S.; Bhonsle S.; RituKumari; Gauns, M.; LokaBharathi, P.A.

    sink also produce a tertiary sulfonium compound dimethylsulphoniopropionate (DMSP), which breaks down mostly by bacterial mediation to a climatically relevant volatile compound dimethylsulphide (DMS). In order to probe the dynamics of DMSP in post...

  13. Biogenesis of the demarcation membrane system (DMS) in megakaryocytes.

    Science.gov (United States)

    Eckly, Anita; Heijnen, Harry; Pertuy, Fabien; Geerts, Willie; Proamer, Fabienne; Rinckel, Jean-Yves; Léon, Catherine; Lanza, François; Gachet, Christian

    2014-02-06

    The demarcation membrane system (DMS) in megakaryocytes forms the plasma membrane (PM) of future platelets. Using confocal microscopy, electron tomography, and large volume focused ion beam/scanning electron microscopy (FIB/SEM), we determined the sequential steps of DMS formation. We identified a pre-DMS that initiated at the cell periphery and was precisely located between the nuclear lobes. At all developmental stages, the DMS remained continuous with the cell surface. The number of these connections correlated well with the nuclear lobulation, suggesting a relationship with cleavage furrow formation and abortive cytokinesis. On DMS expansion, Golgi complexes assembled around the pre-DMS, and fusion profiles between trans-golgi network-derived vesicles and the DMS were observed. Brefeldin-A reduced DMS expansion, indicating that the exocytic pathway is essential for DMS biogenesis. Close contacts between the endoplasmic reticulum (ER) and the DMS were detected, suggesting physical interaction between the 2 membrane systems. FIB/SEM revealed that the DMS forms an intertwined tubular membrane network resembling the platelet open canalicular system. We thus propose the following steps in DMS biogenesis: (1) focal membrane assembly at the cell periphery; (2) PM invagination and formation of a perinuclear pre-DMS; (3) expansion through membrane delivery from Golgi complexes; and (4) ER-mediated lipid transfer.

  14. DMS role in ENSO cycle in the tropics: DMS Role in ENSO Cycle in Tropics

    Energy Technology Data Exchange (ETDEWEB)

    Xu, Li [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA; Now at Department of Earth System Science, University of California, Irvine California USA; Cameron-Smith, Philip [Atmospheric, Earth and Energy Division, Lawrence Livermore National Laboratory, Livermore California USA; Russell, Lynn M. [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA; Ghan, Steven J. [Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Liu, Ying [Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Elliott, Scott [Climate Ocean Sea Ice Modeling, Los Alamos National Laboratory, Los Alamos New Mexico USA; Yang, Yang [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA; Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Lou, Sijia [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA; Atmospheric Science and Global Change Division, Pacific Northwest National Laboratory, Richland Washington USA; Lamjiri, Maryam A. [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA; Manizza, Manfredi [Scripps Institution of Oceanography, University of California, San Diego, La Jolla California USA

    2016-11-16

    We examined the multiyear mean and variability of dimethyl sulfide (DMS) and its relationship to sulfate aerosols, as well as cloud microphysical and radiative properties. We conducted a 150 year simulation using preindustrial conditions produced by the Community Earth System Model embedded with a dynamic DMS module. The model simulated the mean spatial distribution of DMS emissions and burden, as well as sulfur budgets associated with DMS, SO2, H2SO4, and sulfate that were generally similar to available observations and inventories for a variety of regions. Changes in simulated sea-to-air DMS emissions and associated atmospheric abundance, along with associated aerosols and cloud and radiative properties, were consistently dominated by El Niño–Southern Oscillation (ENSO) cycle in the tropical Pacific region. Simulated DMS, aerosols, and clouds showed a weak positive feedback on sea surface temperature. This feedback suggests a link among DMS, aerosols, clouds, and climate on interannual timescales. The variability of DMS emissions associated with ENSO was primarily caused by a higher variation in wind speed during La Niña events. The simulation results also suggest that variations in DMS emissions increase the frequency of La Niña events but do not alter ENSO variability in terms of the standard deviation of the Niño 3 sea surface temperature anomalies.

  15. Laboratory Measurements of the Water/Air Flux of Dimethylsulfide Using a Wind/Wave Tank

    National Research Council Canada - National Science Library

    Dacey, John

    1998-01-01

    The flux of dimethylsulfide (DMS) from the surface water of the ocean to the atmosphere is an important biogeochemical problem, since DMS contributes to optical haze and potentially impacts global climate by influencing earth's albedo...

  16. Perception of dimethyl sulfide (DMS) by loggerhead sea turtles: a possible mechanism for locating high-productivity oceanic regions for foraging.

    Science.gov (United States)

    Endres, Courtney S; Lohmann, Kenneth J

    2012-10-15

    During their long-distance migrations, sea turtles of several species feed on jellyfish and other invertebrates that are particularly abundant in ocean regions characterized by high productivity. An ability to distinguish productive oceanic regions from other areas, and to concentrate foraging activities in locations where prey density is highest, might therefore be adaptive. The volatile compound dimethyl sulfide (DMS) accumulates in the air above productive ocean areas such as upwelling and frontal zones. In principle, DMS might therefore serve as an indicator of high prey density for turtles. To determine whether turtles perceive DMS, juvenile loggerhead sea turtles (Caretta caretta) were placed into a water-filled arena in which DMS and other odorants could be introduced to the air above the water surface. Turtles exposed to air that had passed over a cup containing 10 nmol l(-1) DMS spent more time at the surface with their noses out of the water than control turtles, which were exposed to air that had passed over a cup containing distilled water. Odors that do not occur in the sea (cinnamon, jasmine and lemon) did not elicit increased surface time, implying that the response to DMS is unlikely to reflect a generalized response to any novel odor. The results demonstrate for the first time that sea turtles can detect DMS, an ability that might enable the identification of favorable foraging areas.

  17. Study of organic sulphur compounds (DMS, DMSP and CS2) in lagoon ecosystems: the case of the Venice lagoon.

    Science.gov (United States)

    Gambaro, Andrea; Moret, Ivo; Piazza, Rossano; Andreoli, Carlo; Corami, Fabiana; Turetta, Clara; Cescon, Paolo

    2003-03-01

    This study of the origin and fate of dimethyl sulphide (DMS) in a particular and complex lagoon ecosystem such as that of the Venice lagoon focuses on the temporal evolutions of DMS concentrations in surface water together with those of dimethylsulphoniopropionate (DMSP), carbon disulphide (CS2), nutrients (nitrate, nitrite, ammonium, phosphate, silicate), sulphate, chlorophyll a, chlorinity, water temperature and phytoplankton (composition and density). Measurements were made from 3 March 1997 to 23 July 1998 at three stations in the central part of the Venice lagoon. The temporal trends of DMS concentration showed an absolute maximum concentration in winter (65 nmol S/l, 19/2/1998, Stn. 1; 119 nmol S/l, 19/2/1998, Stn. 2; 29 nmol S/l, 17/2/1998, Stn. 3) and two relative maxima in the spring-summer period. The spring-summer secondary maxima of DMS concentration were related to the maxima of DMSP and chlorophyll a concentrations and consequently to phytoplanktonic abundance while the winter DMS maximum showed no relation to DMSP or to chlorophyll a suggesting that the production and the fate of DMS could be different for the two periods. According to previous studies the CS2 concentration increased in the spring, achieved its maximum in summer, decreased in autumn and fell to its minimum in winter.

  18. Dimethylsulfoniopropionate (DMSP) and dimethyl sulfide (DMS) cycling across contrasting biological hotspots of the New Zealand subtropical front

    Science.gov (United States)

    Lizotte, Martine; Levasseur, Maurice; Law, Cliff S.; Walker, Carolyn F.; Safi, Karl A.; Marriner, Andrew; Kiene, Ronald P.

    2017-11-01

    The oceanic frontal region above the Chatham Rise east of New Zealand was investigated during the late austral summer season in February and March 2012. Despite its potential importance as a source of marine-originating and climate-relevant compounds, such as dimethyl sulfide (DMS) and its algal precursor dimethylsulfoniopropionate (DMSP), little is known of the processes fuelling the reservoirs of these sulfur (S) compounds in the water masses bordering the subtropical front (STF). This study focused on two opposing short-term fates of DMSP-S following its uptake by microbial organisms (either its conversion into DMS or its assimilation into bacterial biomass) and has not considered dissolved non-volatile degradation products. Sampling took place in three phytoplankton blooms (B1, B2, and B3) with B1 and B3 occurring in relatively nitrate-rich, dinoflagellate-dominated subantarctic waters, and B2 occurring in nitrate-poor subtropical waters dominated by coccolithophores. Concentrations of total DMSP (DMSPt) and DMS were high across the region, up to 160 and 14.5 nmol L-1, respectively. Pools of DMSPt showed a strong association with overall phytoplankton biomass proxied by chlorophyll a (rs = 0.83) likely because of the persistent dominance of dinoflagellates and coccolithophores, both DMSP-rich taxa. Heterotrophic microbes displayed low S assimilation from DMSP (less than 5 %) likely because their S requirements were fulfilled by high DMSP availability. Rates of bacterial protein synthesis were significantly correlated with concentrations of dissolved DMSP (DMSPd, rs = 0.86) as well as with the microbial conversion efficiency of DMSPd into DMS (DMS yield, rs = 0.84). Estimates of the potential contribution of microbially mediated rates of DMS production (0.1-27 nmol L-1 day-1) to the near-surface concentrations of DMS suggest that bacteria alone could not have sustained DMS pools at most stations, indicating an important role for phytoplankton-mediated DMS

  19. Surface freezing of water

    OpenAIRE

    P?rez-D?az, J. L.; ?lvarez-Valenzuela, M. A.; Rodr?guez-Celis, F.

    2016-01-01

    Freezing, melting, evaporation and condensation of water are essential ingredients for climate and eventually life on Earth. In the present work, we show how surface freezing of supercooled water in an open container is conditioned and triggered?exclusively?by humidity in air. Additionally, a change of phase is demonstrated to be triggered on the water surface forming surface ice crystals prior to freezing of bulk. The symmetry of the surface crystal, as well as the freezing point, depend on ...

  20. Dimethyl sulfoxide (DMSO) waste residues and municipal waste water odor by dimethyl sulfide (DMS): the north-east WPCP plant of Philadelphia.

    Science.gov (United States)

    Glindemann, Dietmar; Novak, John; Witherspoon, Jay

    2006-01-01

    This study shows for the first time that overlooked mg/L concentrations of industrial dimethyl sulfoxide (DMSO) waste residues in sewage can cause "rotten cabbage" odor problems bydimethyl sulfide (DMS) in conventional municipal wastewater treatment. In laboratory studies, incubation of activated sludge with 1-10 mg/L DMSO in bottles produced dimethyl sulfide (DMS) at concentrations that exceeded the odor threshold by approximately 4 orders of magnitude in the headspace gas. Aeration at a rate of 6 m3 air/m3 sludge resulted in emission of the DMS into the exhaust air in a manner analogous to that of an activated sludge aeration tank. A field study atthe NEWPCP sewage treatment plant in Philadelphia found DMSO levels intermittently peaking as high as 2400 mg/L in sewage near an industrial discharger. After 3 h, the DMSO concentration in the influent to the aeration tank rose from a baseline level of less than 0.01 mg/L to a level of 5.6 mg/L and the DMS concentration in the mixed liquor rose from less than 0.01 to 0.2 mg/L. Finding this link between the intermittent occurrence of DMSO residues in influent of the treatment plant and the odorant DMS in the aeration tank was the keyto understanding and eliminating the intermittent "canned corn" or "rotten cabbage" odor emissions from the aeration tank that had randomly plagued this plant and its city neighborhood for two decades. Sewage authorities should consider having wastewater samples analyzed for DMSO and DMS to check for this possible odor problem and to determine whether DMSO emission thresholds should be established to limit odor generation at sewage treatment plants.

  1. MODFLOW-2000, the U.S. Geological Survey Modular Ground-Water Model--Documentation of the SEAWAT-2000 Version with the Variable-Density Flow Process (VDF) and the Integrated MT3DMS Transport Process (IMT)

    Science.gov (United States)

    Langevin, Christian D.; Shoemaker, W. Barclay; Guo, Weixing

    2003-01-01

    SEAWAT-2000 is the latest release of the SEAWAT computer program for simulation of three-dimensional, variable-density, transient ground-water flow in porous media. SEAWAT-2000 was designed by combining a modified version of MODFLOW-2000 and MT3DMS into a single computer program. The code was developed using the MODFLOW-2000 concept of a process, which is defined as ?part of the code that solves a fundamental equation by a specified numerical method.? SEAWAT-2000 contains all of the processes distributed with MODFLOW-2000 and also includes the Variable-Density Flow Process (as an alternative to the constant-density Ground-Water Flow Process) and the Integrated MT3DMS Transport Process. Processes may be active or inactive, depending on simulation objectives; however, not all processes are compatible. For example, the Sensitivity and Parameter Estimation Processes are not compatible with the Variable-Density Flow and Integrated MT3DMS Transport Processes. The SEAWAT-2000 computer code was tested with the common variable-density benchmark problems and also with problems representing evaporation from a salt lake and rotation of immiscible fluids.

  2. Surface freezing of water.

    Science.gov (United States)

    Pérez-Díaz, J L; Álvarez-Valenzuela, M A; Rodríguez-Celis, F

    2016-01-01

    Freezing, melting, evaporation and condensation of water are essential ingredients for climate and eventually life on Earth. In the present work, we show how surface freezing of supercooled water in an open container is conditioned and triggered-exclusively-by humidity in air. Additionally, a change of phase is demonstrated to be triggered on the water surface forming surface ice crystals prior to freezing of bulk. The symmetry of the surface crystal, as well as the freezing point, depend on humidity, presenting at least three different types of surface crystals. Humidity triggers surface freezing as soon as it overpasses a defined value for a given temperature, generating a plurality of nucleation nodes. An evidence of simultaneous nucleation of surface ice crystals is also provided.

  3. Surface-water surveillance

    Energy Technology Data Exchange (ETDEWEB)

    Saldi, K.A.; Dirkes, R.L.; Blanton, M.L.

    1995-06-01

    This section of the 1994 Hanford Site Environmental Report summarizes the Surface water on and near the Hanford Site is monitored to determine the potential effects of Hanford operations. Surface water at Hanford includes the Columbia River, riverbank springs, ponds located on the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site. Columbia River sediments are also included in this discussion. Tables 5.3.1 and 5.3.2 summarize the sampling locations, sample types, sampling frequencies, and sample analyses included in surface-water surveillance activities during 1994. Sample locations are also identified in Figure 5.3.1. This section describes the surveillance effort and summarizes the results for these aquatic environments. Detailed analytical results are reported by Bisping (1995).

  4. Surface-water surveillance

    International Nuclear Information System (INIS)

    Saldi, K.A.; Dirkes, R.L.; Blanton, M.L.

    1995-01-01

    This section of the 1994 Hanford Site Environmental Report summarizes the Surface water on and near the Hanford Site is monitored to determine the potential effects of Hanford operations. Surface water at Hanford includes the Columbia River, riverbank springs, ponds located on the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site, and offsite water systems directly east and across the Columbia River from the Hanford Site. Columbia River sediments are also included in this discussion. Tables 5.3.1 and 5.3.2 summarize the sampling locations, sample types, sampling frequencies, and sample analyses included in surface-water surveillance activities during 1994. Sample locations are also identified in Figure 5.3.1. This section describes the surveillance effort and summarizes the results for these aquatic environments. Detailed analytical results are reported by Bisping (1995)

  5. CDOM Sources and Photobleaching Control Quantum Yields for Oceanic DMS Photolysis

    KAUST Repository

    Galí, Martí

    2016-11-14

    Photolysis is a major removal pathway for the biogenic gas dimethylsulfide (DMS) in the surface ocean. Here we tested the hypothesis that apparent quantum yields (AQY) for DMS photolysis varied according to the quantity and quality of its photosensitizers, chiefly chromophoric dissolved organic matter (CDOM) and nitrate. AQY compiled from the literature and unpublished studies ranged across 3 orders of magnitude at the 330 nm reference wavelength. The smallest AQY(330) were observed in coastal waters receiving major riverine inputs of terrestrial CDOM (0.06-0.5 m3 (mol quanta)-1). In open-ocean waters, AQY(330) generally ranged between 1 and 10 m3 (mol quanta)-1. The largest AQY(330), up to 34 m3 (mol quanta)-1), were seen in the Southern Ocean potentially associated with upwelling. Despite the large AQY variability, daily photolysis rate constants at the sea surface spanned a smaller range (0.04-3.7 d-1), mainly because of the inverse relationship between CDOM absorption and AQY. Comparison of AQY(330) with CDOM spectral signatures suggests there is an interplay between CDOM origin (terrestrial versus marine) and photobleaching that controls variations in AQYs, with a secondary role for nitrate. Our results can be used for regional or large-scale assessment of DMS photolysis rates in future studies.

  6. CDOM Sources and Photobleaching Control Quantum Yields for Oceanic DMS Photolysis.

    Science.gov (United States)

    Galí, Martí; Kieber, David J; Romera-Castillo, Cristina; Kinsey, Joanna D; Devred, Emmanuel; Pérez, Gonzalo L; Westby, George R; Marrasé, Cèlia; Babin, Marcel; Levasseur, Maurice; Duarte, Carlos M; Agustí, Susana; Simó, Rafel

    2016-12-20

    Photolysis is a major removal pathway for the biogenic gas dimethylsulfide (DMS) in the surface ocean. Here we tested the hypothesis that apparent quantum yields (AQY) for DMS photolysis varied according to the quantity and quality of its photosensitizers, chiefly chromophoric dissolved organic matter (CDOM) and nitrate. AQY compiled from the literature and unpublished studies ranged across 3 orders of magnitude at the 330 nm reference wavelength. The smallest AQY(330) were observed in coastal waters receiving major riverine inputs of terrestrial CDOM (0.06-0.5 m 3 (mol quanta) -1 ). In open-ocean waters, AQY(330) generally ranged between 1 and 10 m 3 (mol quanta) -1 . The largest AQY(330), up to 34 m 3 (mol quanta) -1 ), were seen in the Southern Ocean potentially associated with upwelling. Despite the large AQY variability, daily photolysis rate constants at the sea surface spanned a smaller range (0.04-3.7 d -1 ), mainly because of the inverse relationship between CDOM absorption and AQY. Comparison of AQY(330) with CDOM spectral signatures suggests there is an interplay between CDOM origin (terrestrial versus marine) and photobleaching that controls variations in AQYs, with a secondary role for nitrate. Our results can be used for regional or large-scale assessment of DMS photolysis rates in future studies.

  7. Surface Water in Hawaii

    Science.gov (United States)

    Oki, Delwyn S.

    2003-01-01

    Surface water in Hawaii is a valued resource as well as a potential threat to human lives and property. The surface-water resources of Hawaii are of significant economic, ecologic, cultural, and aesthetic importance. Streams supply more than 50 percent of the irrigation water in Hawaii, and although streams supply only a few percent of the drinking water statewide, surface water is the main source of drinking water in some places. Streams also are a source of hydroelectric power, provide important riparian and instream habitats for many unique native species, support traditional and customary Hawaiian gathering rights and the practice of taro cultivation, and possess valued aesthetic qualities. Streams affect the physical, chemical, and aesthetic quality of receiving waters, such as estuaries, bays, and nearshore waters, which are critical to the tourism-based economy of the islands. Streams in Hawaii pose a danger because of their flashy nature; a stream's stage, or water level, can rise several feet in less than an hour during periods of intense rainfall. Streams in Hawaii are flashy because rainfall is intense, drainage basins are small, basins and streams are steep, and channel storage is limited. Streamflow generated during periods of heavy rainfall has led to loss of property and human lives in Hawaii. Most Hawaiian streams originate in the mountainous interiors of the islands and terminate at the coast. Streams are significant sculptors of the Hawaiian landscape because of the erosive power of the water they convey. In geologically young areas, such as much of the southern part of the island of Hawaii, well-defined stream channels have not developed because the permeability of the surface rocks generally is so high that rainfall infiltrates before flowing for significant distances on the surface. In geologically older areas that have received significant rainfall, streams and mass wasting have carved out large valleys.

  8. Air/sea DMS gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed

    Science.gov (United States)

    Bell, T. G.; De Bruyn, W.; Miller, S. D.; Ward, B.; Christensen, K.; Saltzman, E. S.

    2013-05-01

    Shipboard measurements of eddy covariance DMS air/sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k660) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s-1. At higher wind speeds the relationship between k660 and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent suppression of air/sea gas flux at higher wind speeds appears to be related to sea state, as determined from shipboard wave measurements. These observations are consistent with the idea that long waves suppress near surface water side turbulence, and decrease interfacial gas transfer. This effect may be more easily observed for DMS than for less soluble gases, such as CO2, because the air/sea exchange of DMS is controlled by interfacial rather than bubble-mediated gas transfer under high wind speed conditions.

  9. Water on graphene surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Gordillo, M C [Departamento de Sistemas Fisicos, Quimicos y Naturales, Facultad de Ciencias Experimentales, Universidad Pablo de Olavide, Carretera de Utrera, km 1, E-41013 Sevilla (Spain); Marti, J, E-mail: cgorbar@upo.e, E-mail: jordi.marti@upc.ed [Departament de Fisica i Enginyeria Nuclear, Universitat Politecnica de Catalunya, B4-B5 Campus Nord, E-08034 Barcelona, Catalonia (Spain)

    2010-07-21

    In this paper, we summarize the main results obtained in our group about the behavior of water confined inside or close to different graphene surfaces by means of molecular dynamics simulations. These include the inside and outside of carbon nanotubes, and the confinement inside a slit pore or a single graphene sheet. We paid special attention to some thermodynamical (binding energies), structural (hydrogen-bond distributions) and dynamic (infrared spectra) properties, and their comparison to their bulk counterparts.

  10. Sensitivity of modelled sulfate aerosol and its radiative effect on climate to ocean DMS concentration and air–sea flux

    Directory of Open Access Journals (Sweden)

    J.-E. Tesdal

    2016-09-01

    Full Text Available Dimethylsulfide (DMS is a well-known marine trace gas that is emitted from the ocean and subsequently oxidizes to sulfate in the atmosphere. Sulfate aerosols in the atmosphere have direct and indirect effects on the amount of solar radiation reaching the Earth's surface. Thus, as a potential source of sulfate, ocean efflux of DMS needs to be accounted for in climate studies. Seawater concentration of DMS is highly variable in space and time, which in turn leads to high spatial and temporal variability in ocean DMS emissions. Because of sparse sampling (in both space and time, large uncertainties remain regarding ocean DMS concentration. In this study, we use an atmospheric general circulation model with explicit aerosol chemistry (CanAM4.1 and several climatologies of surface ocean DMS concentration to assess uncertainties about the climate impact of ocean DMS efflux. Despite substantial variation in the spatial pattern and seasonal evolution of simulated DMS fluxes, the global-mean radiative effect of sulfate is approximately linearly proportional to the global-mean surface flux of DMS; the spatial and temporal distribution of ocean DMS efflux has only a minor effect on the global radiation budget. The effect of the spatial structure, however, generates statistically significant changes in the global-mean concentrations of some aerosol species. The effect of seasonality on the net radiative effect is larger than that of spatial distribution and is significant at global scale.

  11. Coupling ANIMO and MT3DMS for 3D regional-scale modeling of nutrient transport in soil and groundwater

    Science.gov (United States)

    Janssen, G.; Del Val Alonso, L.; Groenendijk, P.; Griffioen, J.

    2012-12-01

    We developed an on-line coupling between the 1D/quasi-2D nutrient transport model ANIMO and the 3D groundwater transport model code MT3DMS. ANIMO is a detailed, process-oriented model code for the simulation of nitrate leaching to groundwater, N- and P-loads on surface waters and emissions of greenhouse gasses. It is the leading nutrient fate and transport code in the Netherlands where it is used primarily for the evaluation of fertilization related legislation. In addition, the code is applied frequently in international research projects. MT3DMS is probably the most commonly used groundwater solute transport package worldwide. The on-line model coupling ANIMO-MT3DMS combines the state-of-the-art descriptions of the biogeochemical cycles in ANIMO with the advantages of using a 3D approach for the transport through the saturated domain. These advantages include accounting for regional lateral transport, considering groundwater-surface water interactions more explicitly, and the possibility of using MODFLOW to obtain the flow fields. An additional merit of the on-line coupling concept is that it preserves feedbacks between the saturated and unsaturated zone. We tested ANIMO-MT3DMS by simulating nutrient transport for the period 1970-2007 in a Dutch agricultural polder catchment covering an area of 118 km2. The transient groundwater flow field had a temporal resolution of one day and was calculated with MODFLOW-MetaSWAP. The horizontal resolution of the model grid was 100x100m and consisted of 25 layers of varying thickness. To keep computation times manageable, we prepared MT3DMS for parallel computing, which in itself is a relevant development for a large community of groundwater transport modelers. For the parameterization of the soil, we applied a standard classification approach, representing the area by 60 units with unique combinations of soil type, land use and geohydrological setting. For the geochemical parameterization of the deeper subsurface, however, we

  12. Assessment of a global climatology of oceanic dimethylsulfide (DMS) concentrations based on SeaWiFS imagery (1998-2001)

    NARCIS (Netherlands)

    Belviso, S; Moulin, C; Bopp, L; Stefels, J

    A method is developed to estimate sea-surface particulate dimethylsulfoniopropionate (DMSP(p)) and dimethylsulfide (DMS) concentrations from sea-surface concentrations of chlorophyll a (Chl a). When compared with previous studies, the 1degrees x 1degrees global climatology of oceanic DMS

  13. Dimethylsulphide (DMS emissions from the western Pacific Ocean: a potential marine source for stratospheric sulphur?

    Directory of Open Access Journals (Sweden)

    C. A. Marandino

    2013-08-01

    Full Text Available Sea surface and atmospheric measurements of dimethylsulphide (DMS were performed during the TransBrom cruise in the western Pacific Ocean between Japan and Australia in October 2009. Air–sea DMS fluxes were computed between 0 and 30 μmol m−2 d−1, which are in agreement with those computed by the current climatology, and peak emissions of marine DMS into the atmosphere were found during the occurrence of tropical storm systems. Atmospheric variability in DMS, however, did not follow that of the computed fluxes and was more related to atmospheric transport processes. The computed emissions were used as input fields for the Lagrangian dispersion model FLEXPART, which was set up with actual meteorological fields from ERA-Interim data and different chemical lifetimes of DMS. A comparison with aircraft in situ data from the adjacent HIPPO2 campaign revealed an overall good agreement between modelled versus observed DMS profiles over the tropical western Pacific Ocean. Based on observed DMS emissions and meteorological fields along the cruise track, the model projected that up to 30 g S per month in the form of DMS, emitted from an area of 6 × 104 m2, can be transported above 17 km. This surprisingly large DMS entrainment into the stratosphere is disproportionate to the regional extent of the area of emissions and mainly due to the high convective activity in this region as simulated by the transport model. Thus, if DMS can cross the tropical tropopause layer (TTL, we suggest that the considerably larger area of the tropical western Pacific Ocean can be a source of sulphur to the stratosphere, which has not been considered as yet.

  14. Water at surfaces with tunable surface chemistries

    Science.gov (United States)

    Sanders, Stephanie E.; Vanselous, Heather; Petersen, Poul B.

    2018-03-01

    Aqueous interfaces are ubiquitous in natural environments, spanning atmospheric, geological, oceanographic, and biological systems, as well as in technical applications, such as fuel cells and membrane filtration. Where liquid water terminates at a surface, an interfacial region is formed, which exhibits distinct properties from the bulk aqueous phase. The unique properties of water are governed by the hydrogen-bonded network. The chemical and physical properties of the surface dictate the boundary conditions of the bulk hydrogen-bonded network and thus the interfacial properties of the water and any molecules in that region. Understanding the properties of interfacial water requires systematically characterizing the structure and dynamics of interfacial water as a function of the surface chemistry. In this review, we focus on the use of experimental surface-specific spectroscopic methods to understand the properties of interfacial water as a function of surface chemistry. Investigations of the air-water interface, as well as efforts in tuning the properties of the air-water interface by adding solutes or surfactants, are briefly discussed. Buried aqueous interfaces can be accessed with careful selection of spectroscopic technique and sample configuration, further expanding the range of chemical environments that can be probed, including solid inorganic materials, polymers, and water immiscible liquids. Solid substrates can be finely tuned by functionalization with self-assembled monolayers, polymers, or biomolecules. These variables provide a platform for systematically tuning the chemical nature of the interface and examining the resulting water structure. Finally, time-resolved methods to probe the dynamics of interfacial water are briefly summarized before discussing the current status and future directions in studying the structure and dynamics of interfacial water.

  15. Sustaining dry surfaces under water

    DEFF Research Database (Denmark)

    Jones, Paul R.; Hao, Xiuqing; Cruz-Chu, Eduardo R.

    2015-01-01

    Rough surfaces immersed under water remain practically dry if the liquid-solid contact is on roughness peaks, while the roughness valleys are filled with gas. Mechanisms that prevent water from invading the valleys are well studied. However, to remain practically dry under water, additional...... mechanisms need consideration. This is because trapped gas (e.g. air) in the roughness valleys can dissolve into the water pool, leading to invasion. Additionally, water vapor can also occupy the roughness valleys of immersed surfaces. If water vapor condenses, that too leads to invasion. These effects have...... not been investigated, and are critically important to maintain surfaces dry under water.In this work, we identify the critical roughness scale, below which it is possible to sustain the vapor phase of water and/or trapped gases in roughness valleys – thus keeping the immersed surface dry. Theoretical...

  16. Monitoring/Verification Using DMS: TATP Example

    International Nuclear Information System (INIS)

    Kevin Kyle; Stephan Weeks

    2008-01-01

    Field-rugged and field-programmable differential mobility spectrometry (DMS) networks provide highly selective, universal monitoring of vapors and aerosols at detectable levels from persons or areas involved with illicit chemical/biological/explosives (CBE) production. CBE sensor motes used in conjunction with automated fast gas chromatography with DMS detection (GC/DMS) verification instrumentation integrated into situational operations management systems can be readily deployed and optimized for changing application scenarios. The feasibility of developing selective DMS motes for a 'smart dust' sampling approach with guided, highly selective, fast GC/DMS verification analysis is a compelling approach to minimize or prevent the illegal use of explosives or chemical and biological materials. DMS is currently one of the foremost emerging technologies for field separation and detection of gas-phase chemical species. This is due to trace-level detection limits, high selectivity, and small size. GC is the leading analytical method for the separation of chemical species in complex mixtures. Low-thermal-mass GC columns have led to compact, low-power field systems capable of complete analyses in 15-300 seconds. A collaborative effort optimized a handheld, fast GC/DMS, equipped with a non-rad ionization source, for peroxide-based explosive measurements

  17. Water on a Hydrophobic surface

    Science.gov (United States)

    Scruggs, Ryan; Zhu, Mengjue; Poynor, Adele

    2012-02-01

    Hydrophobicity, meaning literally fear of water, is exhibited on the surfaces of non-stick cooking pans and water resistant clothing, on the leaves of the lotus plan, or even during the protein folding process in our bodies. Hydrophobicity is directly measured by determining a contact angle between water and an objects surface. Associated with a hydrophobic surface is the depletion layer, a low density region approximately 0.2 nm thick. We study this region by comparing data found in lab using surface plasmon resonance techniques to theoretical calculations. Experiments use gold slides coated in ODT and Mercapto solutions to model both hydrophobic and hydrophilic surfaces respectively.

  18. Spatial variations of DMS, DMSP and phytoplankton in the Bay of Bengal during the summer monsoon 2001.

    Science.gov (United States)

    Shenoy, D M; Paul, Jane T; Gauns, Mangesh; Ramaiah, N; Kumar, M Dileep

    2006-08-01

    Data on the distribution of dimethylsulphide (DMS) and dimethylsulphoniopropionate (DMSP) in relation to phytoplankton abundance in different oceanic environments is important to understand the biogeochemistry of DMS, which plays an important role in the radiation balance of the earth. During the summer monsoon of 2001 measurements were made for DMS and DMSPt (total DMSP) together with related biological parameters in the Bay of Bengal. Both DMS and DMSPt were restricted to the upper 40 m of the water column. Diatoms accounted for more than 95% of the phytoplankton and were the major contributors to the DMS and DMSPt pool. The mean concentration of DMS in the upper 40 m was observed to be around 1.8+/-1.9 nM in the study area, while DMSPt concentrations varied between 0.7 nM and 40.2 nM with a mean of 10.4+/-8.2 nM. The observed lower DMSPt in the northern Bay in spite of higher mean primary productivity, chlorophyll a and phytoplankton cell counts seemed to result from grazing. Though salinity divides the Bay into different biogeochemical provinces there is no relation between salinity and DMS or DMSPt. On the other hand DMS was linearly related to chlorophyll a:phaeopigments ratio. The results suggest the need for deeper insight into the role of diatoms in the biogeochemical cycling of DMS.

  19. Spatial variations of DMS, DMSP and phytoplankton in the Bay of Bengal during the summer monsoon 2001

    Digital Repository Service at National Institute of Oceanography (India)

    Shenoy, D.M.; Paul, J.T.; Gauns, M.; Ramaiah, N.; DileepKumar, M.

    in the radiation balance of the earth. During the summer monsoon of 2001 measurements were made for DMS and DMSPt (total DMSP) together with related biological parameters in the Bay of Bengal. Both DMS and DMSPt were restricted to the upper 40 m of the water column...

  20. Wetland Surface Water Processes

    National Research Council Canada - National Science Library

    1993-01-01

    .... Temporary storage includes channel, overbank, basin, and groundwater storage. Water is removed from the wetland through evaporation, plant transpiration, channel, overland and tidal flow, and groundwater recharge...

  1. Air-sea dimethylsulfide (DMS) gas transfer in the North Atlantic: evidence for limited interfacial gas exchange at high wind speed

    Science.gov (United States)

    Bell, T. G.; De Bruyn, W.; Miller, S. D.; Ward, B.; Christensen, K.; Saltzman, E. S.

    2013-11-01

    Shipboard measurements of eddy covariance dimethylsulfide (DMS) air-sea fluxes and seawater concentration were carried out in the North Atlantic bloom region in June/July 2011. Gas transfer coefficients (k660) show a linear dependence on mean horizontal wind speed at wind speeds up to 11 m s-1. At higher wind speeds the relationship between k660 and wind speed weakens. At high winds, measured DMS fluxes were lower than predicted based on the linear relationship between wind speed and interfacial stress extrapolated from low to intermediate wind speeds. In contrast, the transfer coefficient for sensible heat did not exhibit this effect. The apparent suppression of air-sea gas flux at higher wind speeds appears to be related to sea state, as determined from shipboard wave measurements. These observations are consistent with the idea that long waves suppress near-surface water-side turbulence, and decrease interfacial gas transfer. This effect may be more easily observed for DMS than for less soluble gases, such as CO2, because the air-sea exchange of DMS is controlled by interfacial rather than bubble-mediated gas transfer under high wind speed conditions.

  2. MMB4 DMS: cardiovascular and pulmonary effects on dogs and neurobehavioral effects on rats.

    Science.gov (United States)

    Roche, Brian M; Vinci, Tom M; Hawk, Michael A; Hassler, Craig R; Pressburger, David T; Osheroff, Merrill R; Ritchie, Glenn D; Burback, Brian L

    2013-01-01

    The objectives of these studies were to determine the cardiopulmonary effects of a single intramuscular administration of 1,1'-methylenebis[4-[(hydroxyimino)methyl]-pyridinium] dimethanesulfonate (MMB4 DMS) on dogs and on the central nervous system in rats. On days 1, 8, 15, and 22, male and female dogs received either vehicle (water for injection/0.5% benzyl alcohol/methane sulfonic acid) or MMB4 DMS (20, 50, or 100 mg/kg). Pulmonary function was evaluated for the first 5 hours after concurrent dosing with cardiovascular monitoring; then cardiovascular monitoring continued for 72 hours after dosing. Rats were dosed once by intramuscular injection with vehicle (water for injection/0.5% benzyl alcohol/methane sulfonic acid) or MMB4 DMS (60, 170, or 340 mg/kg). In dogs, 100 mg/kg MMB4 DMS resulted in increased blood pressure, slightly increased heart rate, slightly prolonged corrected QT, and moderately increased respiratory rate. There were no toxicological effects of MMB4 DMS on neurobehavioral function in rats administered up to 340 mg/kg MMB4 DMS.

  3. Rate of non-linearity in DMS aerosol-cloud-climate interactions

    Directory of Open Access Journals (Sweden)

    M. A. Thomas

    2011-11-01

    Full Text Available The degree of non-linearity in DMS-cloud-climate interactions is assessed using the ECHAM5-HAMMOZ model by taking into account end-to-end aerosol chemistry-cloud microphysics link. The evaluation is made over the Southern oceans in austral summer, a region of minimal anthropogenic influence. In this study, we compare the DMS-derived changes in the aerosol and cloud microphysical properties between a baseline simulation with the ocean DMS emissions from a prescribed climatology, and a scenario where the DMS emissions are doubled. Our results show that doubling the DMS emissions in the current climate results in a non-linear response in atmospheric DMS burden and subsequently, in SO2 and H2SO4 burdens due to inadequate OH oxidation. The aerosol optical depth increases by only ~20 % in the 30° S–75° S belt in the SH summer months. This increases the vertically integrated cloud droplet number concentrations (CDNC by 25 %. Since the vertically integrated liquid water vapor is constant in our model simulations, an increase in CDNC leads to a reduction in cloud droplet radius of 3.4 % over the Southern oceans in summer. The equivalent increase in cloud liquid water path is 10.7 %. The above changes in cloud microphysical properties result in a change in global annual mean radiative forcing at the TOA of −1.4 W m−2. The results suggest that the DMS-cloud microphysics link is highly non-linear. This has implications for future studies investigating the DMS-cloud climate feedbacks in a warming world and for studies evaluating geoengineering options to counteract warming by modulating low level marine clouds.

  4. Total Nitrogen in Surface Water

    Data.gov (United States)

    U.S. Environmental Protection Agency — Excess nitrogen in surface water can result in eutrophication. TOTALN is reported in kilograms/hectare/year. More information about these resources, including the...

  5. Total Phosphorus in Surface Water

    Data.gov (United States)

    U.S. Environmental Protection Agency — Excess phosphorus in surface water can result in eutrophication. TOTALP is reported in kilograms/hectare/year. More information about these resources, including the...

  6. Free Surface Water Tunnel (FSWT)

    Data.gov (United States)

    Federal Laboratory Consortium — Description: The Free Surface Water Tunnel consists of the intake plenum, the test section and the exit plenum. The intake plenum starts with a perforated pipe that...

  7. Controllability of Surface Water Networks

    Science.gov (United States)

    Riasi, M. Sadegh; Yeghiazarian, Lilit

    2017-12-01

    To sustainably manage water resources, we must understand how to control complex networked systems. In this paper, we study surface water networks from the perspective of structural controllability, a concept that integrates classical control theory with graph-theoretic formalism. We present structural controllability theory and compute four metrics: full and target controllability, control centrality and control profile (FTCP) that collectively determine the structural boundaries of the system's control space. We use these metrics to answer the following questions: How does the structure of a surface water network affect its controllability? How to efficiently control a preselected subset of the network? Which nodes have the highest control power? What types of topological structures dominate controllability? Finally, we demonstrate the structural controllability theory in the analysis of a wide range of surface water networks, such as tributary, deltaic, and braided river systems.

  8. The Hydrophobic Region of the DmsA Twin-Arginine Leader Peptide Determines Specificity with Chaperone DmsD

    OpenAIRE

    Winstone, Tara M. L.; Tran, Vy A.; Turner, Raymond J.

    2013-01-01

    The system specific chaperone DmsD plays a role in the maturation of the catalytic subunit of dimethyl sulfoxide (DMSO) reductase, DmsA. Pre-DmsA contains a 45-amino acid twin-arginine leader peptide that is important for targeting and translocation of folded and cofactor-loaded DmsA by the twin-arginine translocase. DmsD has previously been shown to interact with the complete twin-arginine leader peptide of DmsA. In this study, isothermal titration calorimetry was used to investigate the the...

  9. Groundwater–Surface Water Exchange

    DEFF Research Database (Denmark)

    Karan, Sachin

    The exchange of groundwater-surface water has been invetigated in the western part of Denmark. Holtum AA provides the framework for all the performed investigations. Several methods are used, primarily eld based measurements ombined with numerical models to achieve insight to the governing...... processes of interaction between groundwater and surface water. By using heat as a tracer it has been possible to use temperature directly as calibrationtargets in a groundwater and heat transport model. Thus, it is possible to use heat investigate the change in groundwater discharge in dynamic conditions...... by using simple temperature devices along a stream to delineate the areas of interest in regard to GW{SW exchange. Thus, at several locations in a stream a temperature data logger was placed in the water column and right at the streambed-water interface. By looking at the correlation of streambed...

  10. Groundwater and surface water pollution

    Energy Technology Data Exchange (ETDEWEB)

    Chae, Y.S.; Hamidi, A. [eds.

    2000-07-01

    This book contains almost all the technical know-how that is required to clean up the water supply. It provides a survey of up-to-date technologies for remediation, as well as a step-by-step guide to pollution assessment for both ground and surface waters. In addition to focusing on causes, effects, and remedies, the book stresses reuse, recycling, and recovery of resources. The authors suggest that through total recycling wastes can become resources.

  11. Surface water quality assessment using factor analysis

    African Journals Online (AJOL)

    2006-01-16

    Jan 16, 2006 ... Surface water, groundwater quality assessment and environ- .... Urbanisation influences the water cycle through changes in flow and water ..... tion of aquatic life, CCME water quality Index 1, 0. User`s ... Water, Air Soil Pollut.

  12. Ability of possible DMS precursors to release DMS during wine aging and in the conditions of heat-alkaline treatment.

    Science.gov (United States)

    Segurel, Marie A; Razungles, Alain J; Riou, Christophe; Trigueiro, Mafalda G L; Baumes, Raymond L

    2005-04-06

    The origin of dimethyl sulfide (DMS) produced during wine aging was examined through different assays. The production of DMS during the model aging of a wine and the concomitant decrease of residual potential DMS (PDMS), as DMS released by heat-alkaline treatment in 0.5 M sodium hydroxide at 100 degrees C for 1 h, were demonstrated. Then, dimethyl sulfoxide (DMSO), methionine sulfoxide (MSO), S-methylmethionine (SMM), and dimethylsulfonium propanoic acid (DMSPA), reported previously as possible DMS precursors, were investigated for their ability to be DMS precursors in wine in the conditions of this model aging and of the heat-alkaline treatment. The results showed that DMSO, MSO, and DMSPA could hardly be DMS precursors in the conditions used, whereas SMM appeared to be a good candidate. Finally, the use of [(2)H(6)]-DMSPA as an internal standard for PDMS determination was proposed, because it provided better reproducibility than [(2)H(6)]-DMS used as an external standard.

  13. Waste Receiving and Processing Facility PMS Test Report/DMS-Y2K/System Security DMS (Data Management System)

    International Nuclear Information System (INIS)

    PALMER, M.E.

    1999-01-01

    Test Plan HNF-4351 defines testing requirements for installation of a new server in the WRAP Facility. This documents shows the results of the test reports on the DMS-Y2K and DMS-F81 (Security) systems

  14. Part 2: Surface water quality

    International Nuclear Information System (INIS)

    1997-01-01

    In 1996 the surface water quality measurements were performed, according to the Agreement, at 8 profiles on the Hungarian territory and at 15 profiles on the Slovak territory. Basic physical and chemical parameters (as water temperature, pH values, conductivity, suspended solids, cations and anions (nitrates, ammonium ion, nitrites, total nitrogen, phosphates, total phosphorus, oxygen and organic carbon regime parameters), metals (iron, manganese and heavy metals), biological and microbiological parameters (coliform bacteria, chlorophyll-a, saprobity index and other biological parameters) and quality of sediment were measured

  15. Quantification of dimethyl sulfide (DMS) production in the sea anemone Aiptasia sp. to simulate the sea-to-air flux from coral reefs

    Science.gov (United States)

    Franchini, Filippo; Steinke, Michael

    2017-12-01

    The production of dimethyl sulfide (DMS) is poorly quantified in tropical reef environments but forms an essential process that couples marine and terrestrial sulfur cycles and affects climate. Here we quantified net aqueous DMS production and the concentration of its cellular precursor dimethylsulfoniopropionate (DMSP) in the sea anemone Aiptasia sp., a model organism to study coral-related processes. Bleached anemones did not show net DMS production whereas symbiotic anemones produced DMS concentrations (mean ± standard error) of 160.7 ± 44.22 nmol g-1 dry weight (DW) after 48 h incubation. Symbiotic and bleached individuals showed DMSP concentrations of 32.7 ± 6.00 and 0.6 ± 0.19 µmol g-1 DW, respectively. We applied these findings to a Monte Carlo simulation to demonstrate that net aqueous DMS production accounts for only 20 % of gross aqueous DMS production. Monte Carlo-based estimations of sea-to-air fluxes of gaseous DMS showed that reefs may release 0.1 to 26.3 µmol DMS m-2 coral surface area (CSA) d-1 into the atmosphere with 40 % probability for rates between 0.5 and 1.5 µmol m-2 CSA d-1. These predictions were in agreement with directly quantified fluxes in previous studies. Conversion to a flux normalised to sea surface area (SSA) (range 0.1 to 17.4, with the highest probability for 0.3 to 1.0 µmol DMS m-2 SSA d-1) suggests that coral reefs emit gaseous DMS at lower rates than the average global oceanic DMS flux of 4.6 µmol m-2 SSA d-1 (19.6 Tg sulfur per year). The large difference between simulated gross and quantified net aqueous DMS production in corals suggests that the current and future potential for its production in tropical reefs is critically governed by DMS consumption processes. Hence, more research is required to assess the sensitivity of DMS-consumption pathways to ongoing environmental change in order to address the impact of predicted degradation of coral reefs on DMS production in tropical coastal ecosystems and its impact on

  16. Control of DMSO in wastewater to prevent DMS nuisance odors.

    Science.gov (United States)

    Cheng, Xianhao; Wodarczyk, Michael; Lendzinski, Robert; Peterkin, Earl; Burlingame, Gary A

    2009-07-01

    A "canned corn-like" odor was periodically detected at Philadelphia's Northeast Water Pollution Control Plant (NEWPCP) for more than two decades. Previous research concluded that it was caused by dimethyl sulfide (DMS), from the reduction of dimethyl sulfoxide (DMSO) discharged by a local industrial customer. Several process modifications were implemented at the industrial site to eliminate the "canned corn-like" odor. Results showed that enhancing DMSO recovery by 25% and equalizing the aqueous wash discharge over a longer period of time reduced the DMSO source peak discharge from 1124 to 49 kg/h, and the peak concentrations of DMSO and DMS at the NEWPCP by 81 and 88%. Reduction of DMSO discharge by segregating the first wash for off-site disposal further reduced the peak discharge of DMSO from 49 to 18 kg/h at the source, and DMSO and DMS concentrations at the NEWPCP by 48 and 92%. Segregation of the dehydration distillate for off-site disposal reduced DMSO discharge by 3 kg/h. Modifications by concentrating a higher percentage of the DMSO into the first wash and increasing the DMSO solvent recovery by an additional 33% reduced the total DMSO discharge from 522 to 200 kg and peak discharge rate from 15 to 6 kg/h. All of these process modifications collectively reduced the DMSO source discharge by 92% and the DMSO concentration received at NEWPCP by 97%, from 12 mg/L to approximately 500 microg/L. At this reduced concentration, the company's wastewater discharge was no longer found to cause the "canned corn" odor at the fence line of NEWPCP, thereby mitigating any further need for odor control.

  17. Environmental, biochemical and genetic drivers of DMSP degradation and DMS production in the Sargasso Sea.

    Science.gov (United States)

    Levine, Naomi Marcil; Varaljay, Vanessa A; Toole, Dierdre A; Dacey, John W H; Doney, Scott C; Moran, Mary Ann

    2012-05-01

    Dimethylsulfide (DMS) is a climatically relevant trace gas produced and cycled by the surface ocean food web. Mechanisms driving intraannual variability in DMS production and dimethylsulfoniopropionate (DMSP) degradation in open-ocean, oligotrophic regions were investigated during a 10-month time-series at the Bermuda Atlantic Time-series Study site in the Sargasso Sea. Abundance and transcription of bacterial DMSP degradation genes, DMSP lyase enzyme activity, and DMS and DMSP concentrations, consumption rates and production rates were quantified over time and depth. This interdisciplinary data set was used to test current hypotheses of the role of light and carbon supply in regulating upper-ocean sulfur cycling. Findings supported UV-A-dependent phytoplankton DMS production. Bacterial DMSP degraders may also contribute significantly to DMS production when temperatures are elevated and UV-A dose is moderate, but may favour DMSP demethylation under low UV-A doses. Three groups of bacterial DMSP degraders with distinct intraannual variability were identified and niche differentiation was indicated. The combination of genetic and biochemical data suggest a modified 'bacterial switch' hypothesis where the prevalence of different bacterial DMSP degradation pathways is regulated by a complex set of factors including carbon supply, temperature and UV-A dose. © 2012 Society for Applied Microbiology and Blackwell Publishing Ltd.

  18. Spectroscopic study of the reaction between Br2 and dimethyl sulfide (DMS), and comparison with a parallel study made on Cl2 + DMS: possible atmospheric implications.

    Science.gov (United States)

    Beccaceci, Sonya; Ogden, J Steven; Dyke, John M

    2010-03-07

    The reaction between molecular bromine and dimethyl sulfide (DMS) has been studied both as a co-condensation reaction in low temperature matrices by infrared (IR) matrix isolation spectroscopy and in the gas-phase at low pressures by UV photoelectron spectroscopy (PES). The co-condensation reaction leads to the formation of the molecular van der Waals adduct DMS-Br(2). This was identified by IR spectroscopy supported by results of electronic structure calculations. Calculation of the minimum energy structures in important regions of the reaction surface and computed IR spectra of these structures, which could be compared with the experimental spectra, allowed the structure of the adduct (C(s)) to be determined. The low pressure (ca. 10(-5) mbar) gas-phase reaction was studied by UV-PES, but did not yield any observable products, indicating that a third body is necessary for the adduct to be stabilised. These results are compared with parallel co-condensation and gas-phase reactions between DMS and Cl(2). For this reaction, a similar van der Waals adduct DMS-Cl(2) is observed by IR spectroscopy in the co-condensation reactions, but in the gas-phase, this adduct converts to a covalently bound structure Me(2)SCl(2), observed in PES studies, which ultimately decomposes to monochlorodimethylsulfide and HCl. For these DMS + X(2) reactions, computed relative energies of minima and transition states on the potential energy surfaces are presented which provide an interpretation for the products observed from the two reactions studied. The implications of the results obtained to atmospheric chemistry are discussed.

  19. Modelling global fresh surface water temperature

    NARCIS (Netherlands)

    Beek, L.P.H. van; Eikelboom, T.; Vliet, M.T.H. van; Bierkens, M.F.P.

    2011-01-01

    Temperature directly determines a range of water physical properties including vapour pressure, surface tension, density and viscosity, and the solubility of oxygen and other gases. Indirectly water temperature acts as a strong control on fresh water biogeochemistry, influencing sediment

  20. Quantitative DMS mapping for automated RNA secondary structure inference

    OpenAIRE

    Cordero, Pablo; Kladwang, Wipapat; VanLang, Christopher C.; Das, Rhiju

    2012-01-01

    For decades, dimethyl sulfate (DMS) mapping has informed manual modeling of RNA structure in vitro and in vivo. Here, we incorporate DMS data into automated secondary structure inference using a pseudo-energy framework developed for 2'-OH acylation (SHAPE) mapping. On six non-coding RNAs with crystallographic models, DMS- guided modeling achieves overall false negative and false discovery rates of 9.5% and 11.6%, comparable or better than SHAPE-guided modeling; and non-parametric bootstrappin...

  1. Groundwater-surface water interaction

    International Nuclear Information System (INIS)

    White, P.A.; Clausen, B.; Hunt, B.; Cameron, S.; Weir, J.J.

    2001-01-01

    This chapter discusses natural and modified interactions between groundwater and surface water. Theory on recharge to groundwater from rivers is introduced, and the relative importance of groundwater recharge from rivers is illustrated with an example from the Ngaruroro River, Hawke's Bay. Some of the techniques used to identify and measure recharge to groundwater from gravel-bed rivers will be outlined, with examples from the Ngaruroro River, where the recharge reach is relatively well defined, and from the Rakaia River, where it is poorly defined. Groundwater recharged from rivers can have characteristic chemical and isotopic signatures, as shown by Waimakariri River water in the Christchurch-West Melton groundwater system. The incorporation of groundwater-river interaction in a regional groundwater flow model is outlined for the Waimea Plains, and relationships between river scour and groundwater recharge are examined for the Waimakariri River. Springs are the result of natural discharge from groundwater systems and are important water sources. The interactions between groundwater systems, springs, and river flow for the Avon River in New Zealand will be outlined. The theory of depletion of stream flow by groundwater pumpage will be introduced with a case study from Canterbury, and salt-water intrusion into groundwater systems with examples from Nelson and Christchurch. The theory of artificial recharge to groundwater systems is introduced with a case study from Hawke's Bay. Wetlands are important to flora, and the relationship of the wetland environment to groundwater hydrology will be discussed, with an example from the South Taupo wetland. (author). 56 refs., 25 figs., 3 tabs

  2. Quantification of dimethyl sulfide (DMS production in the sea anemone Aiptasia sp. to simulate the sea-to-air flux from coral reefs

    Directory of Open Access Journals (Sweden)

    F. Franchini

    2017-12-01

    Full Text Available The production of dimethyl sulfide (DMS is poorly quantified in tropical reef environments but forms an essential process that couples marine and terrestrial sulfur cycles and affects climate. Here we quantified net aqueous DMS production and the concentration of its cellular precursor dimethylsulfoniopropionate (DMSP in the sea anemone Aiptasia sp., a model organism to study coral-related processes. Bleached anemones did not show net DMS production whereas symbiotic anemones produced DMS concentrations (mean ± standard error of 160.7 ± 44.22 nmol g−1 dry weight (DW after 48 h incubation. Symbiotic and bleached individuals showed DMSP concentrations of 32.7 ± 6.00 and 0.6 ± 0.19 µmol g−1 DW, respectively. We applied these findings to a Monte Carlo simulation to demonstrate that net aqueous DMS production accounts for only 20 % of gross aqueous DMS production. Monte Carlo-based estimations of sea-to-air fluxes of gaseous DMS showed that reefs may release 0.1 to 26.3 µmol DMS m−2 coral surface area (CSA d−1 into the atmosphere with 40 % probability for rates between 0.5 and 1.5 µmol m−2 CSA d−1. These predictions were in agreement with directly quantified fluxes in previous studies. Conversion to a flux normalised to sea surface area (SSA (range 0.1 to 17.4, with the highest probability for 0.3 to 1.0 µmol DMS m−2 SSA d−1 suggests that coral reefs emit gaseous DMS at lower rates than the average global oceanic DMS flux of 4.6 µmol m−2 SSA d−1 (19.6 Tg sulfur per year. The large difference between simulated gross and quantified net aqueous DMS production in corals suggests that the current and future potential for its production in tropical reefs is critically governed by DMS consumption processes. Hence, more research is required to assess the sensitivity of DMS-consumption pathways to ongoing environmental change in order to address the impact of predicted

  3. Tc(V)-DMS tumour imaging agent

    International Nuclear Information System (INIS)

    Horiuchi, K.; Yomoda, I.; Yokoyama, A.; Endo, K.; Torizuka, K.

    1986-01-01

    The data obtained by the authors provide good evidence of Tc(V)-DMS as a stable, large-molecular-size Tc-complex or polynuclear Tc-complex, comparable to Tc-cit and Ga-cit. A role for this polynuclear configuration in the generation of Tc-species with affinity for neoplastic cells was demonstrated using the dilution method as a promoter of Tc(V)-DMS dissociation. The concurrent Ehrlich ascites tumour cell uptake studies with TLC analysis revealed the chromatographically detected changes well traced by the biological cell utilization. The biological implications of dilution as one of the factors regulating radiopharmaceutical delivery to the tumour cell tissue were better demonstrated in the biodistribution studies carried out with Erhlich ascites-bearing mice. If, on the basis of the present data, the authors may take their postulate one step further, a more dissociated Tc-species, defined speculatively as TcO/sub 4//sup 3-/, might constitute an active Tc- species within the cell interacting with some tumour-specific substance or site. Research to find evidence of its presence is currently in progress

  4. Biogenesis of the demarcation membrane system (DMS) in megakaryocytes

    NARCIS (Netherlands)

    Eckly, A.; Heijnen, H.F.G.; Pertuy, F.; Geerts, W.J.C.; Proamer, F.; Rinckel, J.Y.; Leon, C.; Lanza, F; Gachet, C.

    2014-01-01

    The demarcation membrane system (DMS) in megakaryocytes forms the plasma membrane (PM) of future platelets. Using confocal microscopy, electron tomography, and large volume focused ion beam/scanning electron microscopy (FIB/SEM), we determined the sequential steps of DMS formation. We identified a

  5. The Obsolescence of DMS in an Information Centric World

    Science.gov (United States)

    2011-04-13

    system. DMS does this today already for submarines. It would only require a change in the programming of the existing Tactical Messaging Gateway ( TMG ...and NATO. The TMG , MFI and National Gateways convert the message into a format that can be read by the intended recipient. DMS is a fire and

  6. Study on stability of DMS meridian detector.

    Science.gov (United States)

    Yang, Ning; Huang, Li; Yuan, Jiamin; Zhang, Zhifang; Yang, Zhimin

    2016-05-01

    The stability of meridian detector was the basis to study meridian through conductance method. Ancient documents mentioned that the human body's blood could change with the time and meridians. When qi and blood came, the qi and blood would be full of that place; when qi and blood gone, the local skin shining could fade and recess. It liked the tidal fluctuation, then caused the corresponding acupuncture points conductance value changes. Modern studies had reported that meridian detector instrument the skin area of twelve meridians acupuncture points could change along with time within 24 hours. In this circumstance, whether the conductance values changes in human acupuncture points had statistical significance was vital important. DMS meridian detector instruction was adopt to measure the twelve meridian jingyuan acupuncture point in order to analyze the acupuncture point conductance value changes within one day.

  7. Liquid Water may Stick on Hydrophobic Surfaces

    Indian Academy of Sciences (India)

    IAS Admin

    Common Perception. A surface can be classified as. > Wetting. > Non-wetting. Depending on the spreading characteristics of a droplet of water that splashes on the surface. The behavior of fluid on a solid surface under static and dynamic ..... color of the number density profile. Ions at the interface tend to form pinning zones ...

  8. Surface Water Quality Monitoring Sites

    Data.gov (United States)

    Minnesota Department of Natural Resources — The MN Department of Agriculture (MDA) is charged with periodically collecting and analyzing water samples from selected locations throughout the state to determine...

  9. Surface composition and surface properties of water hyacinth ...

    African Journals Online (AJOL)

    Surface composition and surface properties of water hyacinth ( Eichhornia ... (2/1, v/v) followed by ethanol, using Fourier Transform Infra-red (FT-IR) spectroscopy, ... polar organic solvents and non-polar n-alkane hydrocarbons is discussed.

  10. Waste water treatment in surface mines

    Energy Technology Data Exchange (ETDEWEB)

    Navasardyants, M A; Esipov, V Z; Ryzhkov, Yu A

    1981-01-01

    This paper evaluates problems associated with waste water from coal surface mines of the Kemerovougol' association in the Kuzbass. Waste water treatment in the Kuzbass is of major importance as the region is supplied with water from only one river, the Tom river. Water influx to Kemerovougol' surface mines in a year amounts to 136 million m/sup 3/. The water is used during technological processes, for fire fighting, and spraying to prevent dusting; the rest, about 82.1 million m/sup 3/, is discharged into surface waters. Of this amount, 25.1 million m/sup 3/ is heavily polluted water, 46.6 million m3 are polluted but within limits, and 10.4 million m/sup 3/ are characterized as relatively clean. Waste water is polluted with: suspended matters, oils and oil products, nitrates, nitrides and chlorides. Suspended matter content sometimes reaches 4,000 and 5,000 mg/l, and oil product content in water amounts to 2.17 mg/l. Water treatment in surface mines is two-staged: sumps and sedimentation tanks are used. Water with suspended matter content of 50 to 100 mg/l in winter and summer, and 200 to 250 mg/l in spring and autumn is reduced in sumps to 25 to 30 mg/l in summer and winter and to 40 to 50 mg/l in autumn and spring. During the first stage water treatment efficiency ranges from 50 to 80%. During the second stage water is collected in sedimentation tanks. It is noted that so-called secondary pollution is one of the causes of the relatively high level of suspended matter in discharged water. Water discharged from sedimentation tanks carries clay and loam particles from the bottom and walls of water tanks and channels.

  11. Improving DMS 9210 requirements for limestone rock asphalt - final report.

    Science.gov (United States)

    2015-03-01

    Limestone Rock Asphalt (LRA) mixtures have been produced and placed for several decades using : specification requirements currently listed under DMS 9210. Several districts have had placement issues : and premature failures at the beginning of 2010....

  12. IceBridge DMS L3 Photogrammetric DEM

    Data.gov (United States)

    National Aeronautics and Space Administration — The IceBridge DMS L3 Photogrammetric DEM (IODMS3) data set contains gridded digital elevation models and orthorectified images of Greenland derived from the Digital...

  13. Water vapor retrieval over many surface types

    Energy Technology Data Exchange (ETDEWEB)

    Borel, C.C.; Clodius, W.C.; Johnson, J.

    1996-04-01

    In this paper we present a study of of the water vapor retrieval for many natural surface types which would be valuable for multi-spectral instruments using the existing Continuum Interpolated Band Ratio (CIBR) for the 940 nm water vapor absorption feature. An atmospheric code (6S) and 562 spectra were used to compute the top of the atmosphere radiance near the 940 nm water vapor absorption feature in steps of 2.5 nm as a function of precipitable water (PW). We derive a novel technique called ``Atmospheric Pre-corrected Differential Absorption`` (APDA) and show that APDA performs better than the CIBR over many surface types.

  14. MT3DMS: Model use, calibration, and validation

    Science.gov (United States)

    Zheng, C.; Hill, Mary C.; Cao, G.; Ma, R.

    2012-01-01

    MT3DMS is a three-dimensional multi-species solute transport model for solving advection, dispersion, and chemical reactions of contaminants in saturated groundwater flow systems. MT3DMS interfaces directly with the U.S. Geological Survey finite-difference groundwater flow model MODFLOW for the flow solution and supports the hydrologic and discretization features of MODFLOW. MT3DMS contains multiple transport solution techniques in one code, which can often be important, including in model calibration. Since its first release in 1990 as MT3D for single-species mass transport modeling, MT3DMS has been widely used in research projects and practical field applications. This article provides a brief introduction to MT3DMS and presents recommendations about calibration and validation procedures for field applications of MT3DMS. The examples presented suggest the need to consider alternative processes as models are calibrated and suggest opportunities and difficulties associated with using groundwater age in transport model calibration.

  15. Clean Air Markets - Monitoring Surface Water Chemistry

    Science.gov (United States)

    Learn about how EPA uses Long Term Monitoring (LTM) and Temporily Integrated Monitoring of Ecosystems (TIME) to track the effect of the Clean Air Act Amendments on acidity of surface waters in the eastern U.S.

  16. Surface Waters Information Management System (SWIMS)

    Data.gov (United States)

    Kansas Data Access and Support Center — The Surface Waters Information Management System (SWIMS) has been designed to meet multi-agency hydrologic database needs for Kansas. The SWIMS project was supported...

  17. Waste Receiving and Processing (WRAP) Facility PMS Test Report For Data Management System (DMS) Security Test DMS-Y2K

    Energy Technology Data Exchange (ETDEWEB)

    PALMER, M.E.

    1999-09-21

    Test Plan HNF-4351 defines testing requirements for installation of a new server in the WRAP Facility. This document shows the results of the test reports on the DMS-Y2K and DMS-F81 (Security) systems.

  18. Polyfluorinated chemicals in European surface waters, ground- and drinking waters

    NARCIS (Netherlands)

    Eschauzier, C.; de Voogt, P.; Brauch, H.-J.; Lange, F.T.; Knepper, T.P.; Lange, F.T.

    2012-01-01

    Polyfluorinated chemicals (PFCs), especially short chain fluorinated alkyl sulfonates and carboxylates, are ubiquitously found in the environment. This chapter aims at giving an overview of PFC concentrations found in European surface, ground- and drinking waters and their behavior during

  19. Amplification of global warming through pH dependence of DMS production simulated with a fully coupled Earth system model

    Science.gov (United States)

    Schwinger, Jörg; Tjiputra, Jerry; Goris, Nadine; Six, Katharina D.; Kirkevåg, Alf; Seland, Øyvind; Heinze, Christoph; Ilyina, Tatiana

    2017-08-01

    We estimate the additional transient surface warming ΔTs caused by a potential reduction of marine dimethyl sulfide (DMS) production due to ocean acidification under the high-emission scenario RCP8.5 until the year 2200. Since we use a fully coupled Earth system model, our results include a range of feedbacks, such as the response of marine DMS production to the additional changes in temperature and sea ice cover. Our results are broadly consistent with the findings of a previous study that employed an offline model set-up. Assuming a medium (strong) sensitivity of DMS production to pH, we find an additional transient global warming of 0.30 K (0.47 K) towards the end of the 22nd century when DMS emissions are reduced by 7.3 Tg S yr-1 or 31 % (11.5 Tg S yr-1 or 48 %). The main mechanism behind the additional warming is a reduction of cloud albedo, but a change in shortwave radiative fluxes under clear-sky conditions due to reduced sulfate aerosol load also contributes significantly. We find an approximately linear relationship between reduction of DMS emissions and changes in top of the atmosphere radiative fluxes as well as changes in surface temperature for the range of DMS emissions considered here. For example, global average Ts changes by -0. 041 K per 1 Tg S yr-1 change in sea-air DMS fluxes. The additional warming in our model has a pronounced asymmetry between northern and southern high latitudes. It is largest over the Antarctic continent, where the additional temperature increase of 0.56 K (0.89 K) is almost twice the global average. We find that feedbacks are small on the global scale due to opposing regional contributions. The most pronounced feedback is found for the Southern Ocean, where we estimate that the additional climate change enhances sea-air DMS fluxes by about 9 % (15 %), which counteracts the reduction due to ocean acidification.

  20. Amplification of global warming through pH dependence of DMS production simulated with a fully coupled Earth system model

    Directory of Open Access Journals (Sweden)

    J. Schwinger

    2017-08-01

    Full Text Available We estimate the additional transient surface warming ΔTs caused by a potential reduction of marine dimethyl sulfide (DMS production due to ocean acidification under the high-emission scenario RCP8.5 until the year 2200. Since we use a fully coupled Earth system model, our results include a range of feedbacks, such as the response of marine DMS production to the additional changes in temperature and sea ice cover. Our results are broadly consistent with the findings of a previous study that employed an offline model set-up. Assuming a medium (strong sensitivity of DMS production to pH, we find an additional transient global warming of 0.30 K (0.47 K towards the end of the 22nd century when DMS emissions are reduced by 7.3 Tg S yr−1 or 31 % (11.5 Tg S yr−1 or 48 %. The main mechanism behind the additional warming is a reduction of cloud albedo, but a change in shortwave radiative fluxes under clear-sky conditions due to reduced sulfate aerosol load also contributes significantly. We find an approximately linear relationship between reduction of DMS emissions and changes in top of the atmosphere radiative fluxes as well as changes in surface temperature for the range of DMS emissions considered here. For example, global average Ts changes by −0. 041 K per 1 Tg S yr−1 change in sea–air DMS fluxes. The additional warming in our model has a pronounced asymmetry between northern and southern high latitudes. It is largest over the Antarctic continent, where the additional temperature increase of 0.56 K (0.89 K is almost twice the global average. We find that feedbacks are small on the global scale due to opposing regional contributions. The most pronounced feedback is found for the Southern Ocean, where we estimate that the additional climate change enhances sea–air DMS fluxes by about 9 % (15 %, which counteracts the reduction due to ocean acidification.

  1. Long Range Transport was a Bigger NSS Source than DMS in the Remote Tropical MBL during PASE

    Science.gov (United States)

    Huebert, B. J.; Simpson, R. M.; Howell, S. G.; Blomquist, B.

    2013-12-01

    DMS was not the principal source of non-sea salt sulfate (NSS) mass in the remote marine boundary layer during the Pacific Atmospheric Sulfur Experiment (PASE), according to an Eulerian sulfur budget model based on chemical concentrations measured from the NCAR C-130 in the tropical Pacific. Each of our three (DMS, SO2, and NSS) self-consistent monthly- average budgets includes terms for surface exchange, entrainment, divergence, chemical formation, and chemical loss. The budget-derived DMS emission was (2.7 × 0.5 μmol m-2 d-1, our budget 'units'). SO2 sources include DMS + OH (1.4 × 0.4 units, assuming γ = 0.75) and entrainment from the free troposphere (FT) (0.8 × 0.2 units). Clouds were the most important chemical reactors for SO2 (-1.0 × 0.5 units). SO2 loss terms also include divergence (-0.9 × 0.3 units), dry deposition (-0.5 × 0.2 units), and OH + SO2 (-0.22 × 0.05 units). The total SO2 loss balanced the SO2 source. We found negligible NSS on particles from 2.6 μm to 10 μm diameter, the sea salt mass peak. Fine-particle NSS sources include in-cloud oxidation of SO2 by H2O2 (1.0 × 0.5 units), OH + SO2 (0.19 × 0.05 units), and entrainment (1.1 × 0.3 units in clean conditions; twice that when continental pollution is present). Only about 1/4 of emitted DMS becomes NSS. The NSS sources from entrainment and from DMS are similar in magnitude.

  2. The contribution of ocean-leaving DMS to the global atmospheric burdens of DMS, MSA, SO2, and NSS SO4=

    NARCIS (Netherlands)

    van Himbergen-Gondwe, P.M.; Krol, M.; Gieskes, W.W C; Klaassen, W.; de Baar, H.J.W.

    2003-01-01

    [1] The contribution of ocean-derived DMS to the atmospheric burdens of a variety of sulphur compounds (DMS, MSA, SO2, and nss SO4=) is quantified from season to season. Such quantification, especially for nss SO4= (the climate-relevant product of DMS oxidation), is essential for the quantification

  3. Radionuclide transfer onto ground surface in surface water flow, 1

    International Nuclear Information System (INIS)

    Mukai, Masayuki; Takebe, Shinichi; Komiya, Tomokazu; Kamiyama, Hideo

    1991-07-01

    Radionuclides migration in ground surface water flow is considered to be one of the important path way in the scenario for environmental migration of radionuclides leaked from low level radioactive waste repository. Simulating the slightly sloped surface on which contaminated solution is flowing downward, testing for radionuclide migration on ground surface had been started. As it's first step, an experiment was carried out under the condition of restricted infiltration in order to elucidate the adsorption behavior of radionuclides onto the loamy soil surface in related with hydraulic conditions. Radionuclides concentration change in effluent solution with time and a concentration distribution of radionuclides adsorbed on the ground surface were obtained from several experimental conditions combining the rate and the duration time of the water flow. The radionuclides concentration in the effluent solution was nearly constant during each experimental period, and was reduced under the condition of lower flow rate. The surface distribution of radionuclides concentration showed two distinctive regions. The one was near the inlet vessel where the concentration was promptly reducing, and the other was following the former where the concentration was nearly constant. The characteristic surface distribution of radionuclides concentration can be explained by a two dimensional diffusion model with a first order adsorption reaction, based on the advection of flow rate distribution in perpendicular direction. (author)

  4. Manufacturing and characterisation of water repellent surfaces

    DEFF Research Database (Denmark)

    De Grave, Arnaud; Botija, Pablo; Hansen, Hans Nørgaard

    2006-01-01

    design criteria for such surfaces. The problem of adapting this behaviour to artificially roughened surfaces is addressed by providing design criteria for superhydrophobic, water-repellent and self-cleaning surfaces according to the concrete performance desired for them. Different kind of manufacturing...... techniques are investigated and the production of patterned micro structured surfaces following two different manufacturing techniques is reported. The first is a combination of laser manufacturing and hot embossing on polystyrene. To compare geometry and functionality a non-silicon based lithography...

  5. Radioactivity in surface waters and its effects

    International Nuclear Information System (INIS)

    Stoeber, I.

    1987-01-01

    In consequence of the reactor accident in Chernobyl, the State Office for Water and Waste Disposal of North-Rhine Westphalia implemented immediate programmes for monitoring radioactivity in surface waters, including their sediments and organisms. Of the initially-measured radionuclides, only cesium-137, with its long half-life of 30 years, is of interest. Only trace amounts of the almost equally long-lived strontium 90 (half-life 28 years) were present in rainfall. Cs-137 is a non-natural-radionuclide, occurring solely as a by-product of nuclear installations and atomic bomb tests. Following the ban on surface testing of nuclear weapons, the Cs-137 content of surface waters had fallen significantly up to April 1986. The load due to the reactor disaster is of the same order of magnitude as that produced by atomic testing at the end of the nineteen-sixties. The paper surveys radioactive pollution of surface waters in North-Rhine Westphalia and its effects on water use, especially in regard to potable water supplies and the fish population. (orig./HSCH) [de

  6. Photomineralization and photomethanification of dissolved organic matter in Saguenay River surface water

    Science.gov (United States)

    Zhang, Y.; Xie, H.

    2015-11-01

    Rates and apparent quantum yields of photomineralization (AQYDOC) and photomethanification (AQYCH4) of chromophoric dissolved organic matter (CDOM) in Saguenay River surface water were determined at three widely differing dissolved oxygen concentrations ([O2]) (suboxic, air saturation, and oxygenated) using simulated-solar radiation. Photomineralization increased linearly with CDOM absorbance photobleaching for all three O2 treatments. Whereas the rate of photochemical dissolved organic carbon (DOC) loss increased with increasing [O2], the ratio of fractional DOC loss to fractional absorbance loss showed an inverse trend. CDOM photodegradation led to a higher degree of mineralization under suboxic conditions than under oxic conditions. AQYDOC determined under oxygenated, suboxic, and air-saturated conditions increased, decreased, and remained largely constant with photobleaching, respectively; AQYDOC obtained under air saturation with short-term irradiations could thus be applied to longer exposures. AQYDOC decreased successively from ultraviolet B (UVB) to ultraviolet A (UVA) to visible (VIS), which, alongside the solar irradiance spectrum, points to VIS and UVA being the primary drivers for photomineralization in the water column. The photomineralization rate in the Saguenay River was estimated to be 2.31 × 108 mol C yr-1, accounting for only 1 % of the annual DOC input into this system. Photoproduction of CH4 occurred under both suboxic and oxic conditions and increased with decreasing [O2], with the rate under suboxic conditions ~ 7-8 times that under oxic conditions. Photoproduction of CH4 under oxic conditions increased linearly with photomineralization and photobleaching. Under air saturation, 0.00057 % of the photochemical DOC loss was diverted to CH4, giving a photochemical CH4 production rate of 4.36 × 10-6 mol m-2 yr-1 in the Saguenay River and, by extrapolation, of (1.9-8.1) × 108 mol yr-1 in the global ocean. AQYCH4 changed little with

  7. Air exposure of coral is a significant source of dimethylsulfide (DMS) to the atmosphere.

    Science.gov (United States)

    Hopkins, Frances E; Bell, Thomas G; Yang, Mingxi; Suggett, David J; Steinke, Michael

    2016-10-31

    Corals are prolific producers of dimethylsulfoniopropionate (DMSP). High atmospheric concentrations of the DMSP breakdown product dimethylsulfide (DMS) have been linked to coral reefs during low tides. DMS is a potentially key sulfur source to the tropical atmosphere, but DMS emission from corals during tidal exposure is not well quantified. Here we show that gas phase DMS concentrations (DMS gas ) increased by an order of magnitude when three Indo-Pacific corals were exposed to air in laboratory experiments. Upon re-submersion, an additional rapid rise in DMS gas was observed, reflecting increased production by the coral and/or dissolution of DMS-rich mucus formed by the coral during air exposure. Depletion in DMS following re-submersion was likely due to biologically-driven conversion of DMS to dimethylsulfoxide (DMSO). Fast Repetition Rate fluorometry showed downregulated photosynthesis during air exposure but rapid recovery upon re-submersion, suggesting that DMS enhances coral tolerance to oxidative stress during a process that can induce photoinhibition. We estimate that DMS emission from exposed coral reefs may be comparable in magnitude to emissions from other marine DMS hotspots. Coral DMS emission likely comprises a regular and significant source of sulfur to the tropical marine atmosphere, which is currently unrecognised in global DMS emission estimates and Earth System Models.

  8. Surface tension of normal and heavy water

    International Nuclear Information System (INIS)

    Straub, J.; Rosner, N.; Grigull, V.

    1980-01-01

    A Skeleton Table and simple interpolation equation for the surface tension of light water was developed by the Working Group III of the International Association for the Properties of Steam and is recommended as an International Standard. The Skeleton Table is based on all known measurements of the surface tension and individual data were weighted corresponding to the accuracy of the measurements. The form of the interpolation equation is based on a physical concept. It represents an extension of van der Waals-equation, where the exponent conforms to the 'Scaling Laws'. In addition for application purposes simple relations for the Laplace-coefficient and for the density difference between the liquid and gaseous phases of light water are given. The same form of interpolation equation for the surface tension can be used for heavy water, for which the coefficients are given. However, this equation is based only on a single set of data. (orig.) [de

  9. Electrolysis of water on (oxidized) metal surfaces

    DEFF Research Database (Denmark)

    Rossmeisl, Jan; Logadottir, Ashildur; Nørskov, Jens Kehlet

    2005-01-01

    Density functional theory calculations are used as the basis for an analysis of the electrochemical process, where by water is split to form molecular oxygen and hydrogen. We develop a method for obtaining the thermochemistry of the electrochemical water splitting process as a function of the bias...... directly from the electronic structure calculations. We consider electrodes of Pt(111) and Au(111) in detail and then discuss trends for a series of different metals. We show that the difficult step in the water splitting process is the formation of superoxy-type (OOH) species on the surface...... by the splitting of a water molecule on top an adsorbed oxygen atom. One conclusion is that this is only possible on metal surfaces that are (partly) oxidized. We show that the binding energies of the different intermediates are linearly correlated for a number of metals. In a simple analysis, where the linear...

  10. Occurrence of Surface Water Contaminations: An Overview

    Science.gov (United States)

    Shahabudin, M. M.; Musa, S.

    2018-04-01

    Water is a part of our life and needed by all organisms. As time goes by, the needs by human increased transforming water quality into bad conditions. Surface water contaminated in various ways which is pointed sources and non-pointed sources. Pointed sources means the source are distinguished from the source such from drains or factory but the non-pointed always occurred in mixed of elements of pollutants. This paper is reviewing the occurrence of the contaminations with effects that occurred around us. Pollutant factors from natural or anthropology factors such nutrients, pathogens, and chemical elements contributed to contaminations. Most of the effects from contaminated surface water contributed to the public health effects also to the environments.

  11. Distributions and Relationships of CO2, O2, and Dimethylsulfide in the Changjiang (Yangtze) Estuary and Its Adjacent Waters in Summer

    Science.gov (United States)

    Wu, Xi; Tan, Tingting; Liu, Chunying; Li, Tie; Liu, Xiaoshou; Yang, Guipeng

    2018-04-01

    The distributions and relationships of O2, CO2, and dimethylsulfide (DMS) in the Changjiang (Yangtze) Estuary and its adjacent waters were investigated in June 2014. In surface water, mean O2 saturation level, partial pressure of CO2 (pCO2), and DMS concentrations (and ranges) were 110% (89%-167%), 374 μatm (91-640 μatm), and 8.53 nmol L-1 (1.10-27.50 nmol L-1), respectively. The sea-to-air fluxes (and ranges) of DMS and CO2 were 8.24 μmol m-2 d-1 (0.26-62.77 μmol m-2 d-1), and -4.7 mmol m-2 d-1 (-110.8-31.7 mmol m-2 d-1), respectively. Dissolved O2 was oversaturated, DMS concentrations were relatively high, and this region served as a sink of atmospheric CO2. The pCO2 was significantly and negatively correlated with the O2 saturation level, while the DMS concentration showed different positive relationships with the O2 saturation level in different water masses. In vertical profiles, a hypoxic zone existed below 20 m at a longitude of 123°E. The stratification of temperature and salinity caused by the Taiwan Warm Current suppressed seawater exchange between upper and lower layers, resulting in the formation of a hypoxic zone. Oxidative decomposition of organic detritus carried by the Changjiang River Diluted Water (CRDW) consumed abundant O2 and produced additional CO2. The DMS concentrations decreased because of low phytoplankton biomass in the hypoxic zone. Strong correlations appeared between the O2 saturation level, pCO2 and DMS concentrations in vertical profiles. Our results strongly suggested that CRDW played an important role in the distributions and relationships of O2, CO2, and DMS.

  12. Surface Water Protection by Productive Buffers

    DEFF Research Database (Denmark)

    Christen, Benjamin

    Vegetated riparian buffer zones are a widely recommended best management practice in agriculture for protecting surface and coastal waters from diffuse nutrient pollution. On the background of the EU funded research project NitroEurope (NEU; www.NitroEurope.eu), this study concentrates...... on the mitigation of nitrogen pollution in surface and groundwater, using riparian buffer zones for biomass production. The objectives are to map suitable areas for buffer implementation across the six NEU study landscapes, model tentative N-loss mitigation, calculate biomass production potential and economic...... designed for local conditions could be a way of protecting water quality attractive to many stakeholders....

  13. Surface-Water Conditions in Georgia, Water Year 2005

    Science.gov (United States)

    Painter, Jaime A.; Landers, Mark N.

    2007-01-01

    INTRODUCTION The U.S. Geological Survey (USGS) Georgia Water Science Center-in cooperation with Federal, State, and local agencies-collected surface-water streamflow, water-quality, and ecological data during the 2005 Water Year (October 1, 2004-September 30, 2005). These data were compiled into layers of an interactive ArcReaderTM published map document (pmf). ArcReaderTM is a product of Environmental Systems Research Institute, Inc (ESRI?). Datasets represented on the interactive map are * continuous daily mean streamflow * continuous daily mean water levels * continuous daily total precipitation * continuous daily water quality (water temperature, specific conductance dissolved oxygen, pH, and turbidity) * noncontinuous peak streamflow * miscellaneous streamflow measurements * lake or reservoir elevation * periodic surface-water quality * periodic ecological data * historical continuous daily mean streamflow discontinued prior to the 2005 water year The map interface provides the ability to identify a station in spatial reference to the political boundaries of the State of Georgia and other features-such as major streams, major roads, and other collection stations. Each station is hyperlinked to a station summary showing seasonal and annual stream characteristics for the current year and for the period of record. For continuous discharge stations, the station summary includes a one page graphical summary page containing five graphs, a station map, and a photograph of the station. The graphs provide a quick overview of the current and period-of-record hydrologic conditions of the station by providing a daily mean discharge graph for the water year, monthly statistics graph for the water year and period of record, an annual mean streamflow graph for the period of record, an annual minimum 7-day average streamflow graph for the period of record, and an annual peak streamflow graph for the period of record. Additionally, data can be accessed through the layer's link

  14. Global modelling of Cryptosporidium in surface water

    Science.gov (United States)

    Vermeulen, Lucie; Hofstra, Nynke

    2016-04-01

    Introduction Waterborne pathogens that cause diarrhoea, such as Cryptosporidium, pose a health risk all over the world. In many regions quantitative information on pathogens in surface water is unavailable. Our main objective is to model Cryptosporidium concentrations in surface waters worldwide. We present the GloWPa-Crypto model and use the model in a scenario analysis. A first exploration of global Cryptosporidium emissions to surface waters has been published by Hofstra et al. (2013). Further work has focused on modelling emissions of Cryptosporidium and Rotavirus to surface waters from human sources (Vermeulen et al 2015, Kiulia et al 2015). A global waterborne pathogen model can provide valuable insights by (1) providing quantitative information on pathogen levels in data-sparse regions, (2) identifying pathogen hotspots, (3) enabling future projections under global change scenarios and (4) supporting decision making. Material and Methods GloWPa-Crypto runs on a monthly time step and represents conditions for approximately the year 2010. The spatial resolution is a 0.5 x 0.5 degree latitude x longitude grid for the world. We use livestock maps (http://livestock.geo-wiki.org/) combined with literature estimates to calculate spatially explicit livestock Cryptosporidium emissions. For human Cryptosporidium emissions, we use UN population estimates, the WHO/UNICEF JMP sanitation country data and literature estimates of wastewater treatment. We combine our emissions model with a river routing model and data from the VIC hydrological model (http://vic.readthedocs.org/en/master/) to calculate concentrations in surface water. Cryptosporidium survival during transport depends on UV radiation and water temperature. We explore pathogen emissions and concentrations in 2050 with the new Shared Socio-economic Pathways (SSPs) 1 and 3. These scenarios describe plausible future trends in demographics, economic development and the degree of global integration. Results and

  15. Impinging Water Droplets on Inclined Glass Surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Armijo, Kenneth Miguel [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Lance, Blake [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Ho, Clifford K. [Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

    2017-09-01

    Multiphase computational models and tests of falling water droplets on inclined glass surfaces were developed to investigate the physics of impingement and potential of these droplets to self-clean glass surfaces for photovoltaic modules and heliostats. A multiphase volume-of-fluid model was developed in ANSYS Fluent to simulate the impinging droplets. The simulations considered different droplet sizes (1 mm and 3 mm), tilt angles (0°, 10°, and 45°), droplet velocities (1 m/s and 3 m/s), and wetting characteristics (wetting=47° contact angle and non-wetting = 93° contact angle). Results showed that the spread factor (maximum droplet diameter during impact divided by the initial droplet diameter) decreased with increasing inclination angle due to the reduced normal force on the surface. The hydrophilic surface yielded greater spread factors than the hydrophobic surface in all cases. With regard to impact forces, the greater surface tilt angles yielded lower normal forces, but higher shear forces. Experiments showed that the experimentally observed spread factor (maximum droplet diameter during impact divided by the initial droplet diameter) was significantly larger than the simulated spread factor. Observed spread factors were on the order of 5 - 6 for droplet velocities of ~3 m/s, whereas the simulated spread factors were on the order of 2. Droplets were observed to be mobile following impact only for the cases with 45° tilt angle, which matched the simulations. An interesting phenomenon that was observed was that shortly after being released from the nozzle, the water droplet oscillated (like a trampoline) due to the "snapback" caused by the surface tension of the water droplet being released from the nozzle. This oscillation impacted the velocity immediately after the release. Future work should evaluate the impact of parameters such as tilt angle and surface wettability on the impact of particle/soiling uptake and removal to investigate ways that

  16. Thermodynamic properties of water solvating biomolecular surfaces

    Science.gov (United States)

    Heyden, Matthias

    Changes in the potential energy and entropy of water molecules hydrating biomolecular interfaces play a significant role for biomolecular solubility and association. Free energy perturbation and thermodynamic integration methods allow calculations of free energy differences between two states from simulations. However, these methods are computationally demanding and do not provide insights into individual thermodynamic contributions, i.e. changes in the solvent energy or entropy. Here, we employ methods to spatially resolve distributions of hydration water thermodynamic properties in the vicinity of biomolecular surfaces. This allows direct insights into thermodynamic signatures of the hydration of hydrophobic and hydrophilic solvent accessible sites of proteins and small molecules and comparisons to ideal model surfaces. We correlate dynamic properties of hydration water molecules, i.e. translational and rotational mobility, to their thermodynamics. The latter can be used as a guide to extract thermodynamic information from experimental measurements of site-resolved water dynamics. Further, we study energy-entropy compensations of water at different hydration sites of biomolecular surfaces. This work is supported by the Cluster of Excellence RESOLV (EXC 1069) funded by the Deutsche Forschungsgemeinschaft.

  17. Surface-Water Data, Georgia, Water Year 1999

    Science.gov (United States)

    Alhadeff, S. Jack; Landers, Mark N.; McCallum, Brian E.

    1999-01-01

    Water resources data for the 1999 water year for Georgia consists of records of stage, discharge, and water quality of streams; and the stage and contents of lakes and reservoirs published in one volume in a digital format on a CD-ROM. This volume contains discharge records of 121 gaging stations; stage for 13 gaging stations; stage and contents for 18 lakes and reservoirs; continuous water quality records for 10 stations; and the annual peak stage and annual peak discharge for 75 crest-stage partial-record stations. These data represent that part of the National Water Data System collected by the U.S. Geological Survey and cooperating State and Federal agencies in Georgia. Records of discharge and stage of streams, and contents or stage of lakes and reservoirs were first published in a series of U.S. Geological water-supply papers entitled, 'Surface-Water Supply of the United States.' Through September 30, 1960, these water-supply papers were in an annual series and then in a 5-year series for 1961-65 and 1966-70. Records of chemical quality, water temperature, and suspended sediment were published from 1941 to 1970 in an annual series of water-supply papers entitled, 'Quality of Surface Waters of the United States.' Records of ground-water levels were published from 1935 to 1974 in a series of water-supply papers entitled, 'Ground-Water Levels in the United States.' Water-supply papers may be consulted in the libraries of the principal cities in the United States or may be purchased from the U.S. Geological Survey, Branch of Information Services, Federal Center, Box 25286, Denver, CO 80225. For water years 1961 through 1970, streamflow data were released by the U.S. Geological Survey in annual reports on a State-boundary basis prior to the two 5-year series water-supply papers, which cover this period. The data contained in the water-supply papers are considered the official record. Water-quality records for water years 1964 through 1970 were similarly released

  18. Surface water, particulate matter, and sediments of inland waters

    International Nuclear Information System (INIS)

    Mundschenk, H.

    1985-01-01

    The Bundesanstalt fuer Gewaesserkunde (BfG) since 1958 runs a system for monitoring the surface water and sediments of Federal German waterways in its capacity as a directing water monitoring centre. The data recorded over the years show that the radioactivity released by the various emission sources leads to radionuclide concentrations in water, particulate matter, or sediments that generally are below the detection limits defined in the relevant legal provisions governing monitoring and surveillance of nuclear facilities effluents. Representative examples of measuring methods and results (as for e.g. for H-3) are given. (DG) [de

  19. Monitoring/Verification using DMS: TATP Example 8422

    International Nuclear Information System (INIS)

    Stephan Weeks; Kevin Kyle

    2008-01-01

    Field-rugged and field-programmable differential mobility spectrometry (DMS) networks provide highly selective, universal monitoring of vapors and aerosols at detectable levels from persons or areas involved with illicit chemical/biological/explosives (CBE) production. CBE sensor motes used in conjunction with automated fast gas chromatography with DMS detection (GC/DMS) verification instrumentation integrated into situational operations management systems can be readily deployed and optimized for changing application scenarios. The feasibility of developing selective DMS motes for a 'smart dust' sampling approach with guided, highly selective, fast GC/DMS verification analysis is a compelling approach to minimize or prevent the use of explosives or chemical and biological weapons in terrorist activities. Two peroxide-based liquid explosives, triacetone triperoxide (TATP) and hexamethylene triperoxide diamine (HMTD), are synthesized from common chemicals such as hydrogen peroxide, acetone, sulfuric acid, ammonia, and citric acid (Figure 1). Recipes can be readily found on the Internet by anyone seeking to generate sufficient quantities of these highly explosive chemicals to cause considerable collateral damage. Detection of TATP and HMTD by advanced sensing systems can provide the early warning necessary to prevent terror plots from coming to fruition. DMS is currently one of the foremost emerging technologies for the separation and detection of gas-phase chemical species. This is due to trace-level detection limits, high selectivity, and small size. DMS separates and identifies ions at ambient pressures by utilizing the non-linear dependence of an ion's mobility on the radio frequency (rf) electric field strength. GC is widely considered to be one of the leading analytical methods for the separation of chemical species in complex mixtures. Advances in the technique have led to the development of low-thermal-mass fast GC columns. These columns are capable of

  20. Exploring travelers' behavior in response to dynamic message signs (DMS) using a driving simulator : [research summary].

    Science.gov (United States)

    2013-10-16

    The Maryland State Highway Administration (SHA) uses dynamic message signs : (DMS) for traffic and incident management and for providing travel time information. : Previous research in Maryland has shown that a DMS can be an accurate, effective, and ...

  1. Lithium content in potable water, surface water, ground water, and mineral water on the territory of Republic of Macedonia

    OpenAIRE

    Kostik, Vesna; Bauer, Biljana; Kavrakovski, Zoran

    2014-01-01

    The aim of this study was to determine lithium concentration in potable water, surface water, ground, and mineral water on the territory of the Republic of Macedonia. Water samples were collected from water bodies such as multiple public water supply systems located in 13 cities, wells boreholes located in 12 areas, lakes and rivers located in three different areas. Determination of lithium concentration in potable water, surface water was performed by the technique of inductively coupl...

  2. Role of bacteria in DMS(P) cycle

    Digital Repository Service at National Institute of Oceanography (India)

    Kumar, S.S.; Chinchkar, U.; Nair, S.; LokaBharathi, P.A.; Chandramohan, D.

    - lower atmosphere study Role of bacteria in DMS(P) cycle Sree S. Kumar, Usha Chinchkar, Shanta Nair, P. A. Loka Bharathi and D. Chandramohan - contact: ksree@nio.org National Institute of Oceanography, Dona Paula. Goa. India. 403 004 Sree Kumar is a...

  3. DMS test summary report for the WRAP facility

    Energy Technology Data Exchange (ETDEWEB)

    Weidert, J.R.

    1997-11-04

    This report documents the functional and integration testing process performed to verify functionality of the Release 1.1, Release 2.0, Release 3.0 and Release 3.1 software for the Waste Receiving and Processing Facility (WRAP) Data Management Systems (DMS) Release 2.

  4. DMS test summary report for the WRAP facility

    International Nuclear Information System (INIS)

    Weidert, J.R.

    1997-01-01

    This report documents the functional and integration testing process performed to verify functionality of the Release 1.1, Release 2.0, Release 3.0 and Release 3.1 software for the Waste Receiving and Processing Facility (WRAP) Data Management Systems (DMS) Release 2

  5. Surface-water investigations at Barrow, Alaska

    Science.gov (United States)

    Jones, Stanley H.

    1972-01-01

    The U.S. Public Health Service is currently developing plans for a long-term water supply and sewage treatment system for the village of Barrow, Alaska. To assist in planning, the U.S. Geological Survey was requested to initiate a cooperative streamflow data-collection program with the U.S. Public Health Service in June 1972 to determine the availability of surface water and the areal distribution of runoff in the Barrow area. This basic-data report summarizes the streamflow data collected from June 1 through July 10, 1972, at three gaging stations in the Barrow area (fig. 1) and discusses the future data-collection program.

  6. Transport and transformation of surface water masses across the ...

    African Journals Online (AJOL)

    Transport and transformation of surface water masses across the Mascarene Plateau during the Northeast Monsoon season. ... Mixing occurs in the central gap between intermediate water masses (Red Sea Water [RSW] and Antarctic Intermediate Water [AAIW]) as well as in the upper waters (Subtropical Surface Water ...

  7. Impacts of Marine Ecodynamics on the Dimethyl Sulfide(DMS) Production

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Shanlin [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Maltrud, Mathew Einar [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Elliott, Scott M. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Cameron-Smith, Philip [Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)

    2017-11-05

    Given the new explicit Phaeocystis representation, the DMS distribution shows significant improvements, especially regarding the amplitude and location of high latitude peaks. The production of DMS varies with climate. It is therefore necessary to couple the dynamics DMS module in climate projections.

  8. Radiological monitoring. Controlling surface water pollution

    International Nuclear Information System (INIS)

    Morin, Maxime

    2018-01-01

    Throughout France, surface waters (from rivers to brooks) located at the vicinity of nuclear or industrial sites, are subject to regular radiological monitoring. An example is given with the radiological monitoring of a small river near La Hague Areva's plant, where contaminations have been detected with the help of the French IRSN nuclear safety research organization. The sampling method and various measurement types are described

  9. Bulk water freezing dynamics on superhydrophobic surfaces

    Science.gov (United States)

    Chavan, S.; Carpenter, J.; Nallapaneni, M.; Chen, J. Y.; Miljkovic, N.

    2017-01-01

    In this study, we elucidate the mechanisms governing the heat-transfer mediated, non-thermodynamic limited, freezing delay on non-wetting surfaces for a variety of characteristic length scales, Lc (volume/surface area, 3 mm commercial superhydrophobic spray coatings, showing a monotonic increase in freezing time with coating thickness. The added thermal resistance of thicker coatings was much larger than that of the nanoscale superhydrophobic features, which reduced the droplet heat transfer and increased the total freezing time. Transient finite element method heat transfer simulations of the water slab freezing process were performed to calculate the overall heat transfer coefficient at the substrate-water/ice interface during freezing, and shown to be in the range of 1-2.5 kW/m2K for these experiments. The results shown here suggest that in order to exploit the heat-transfer mediated freezing delay, thicker superhydrophobic coatings must be deposited on the surface, where the coating resistance is comparable to the bulk water/ice conduction resistance.

  10. Source Water Assessment for the Las Vegas Valley Surface Waters

    Science.gov (United States)

    Albuquerque, S. P.; Piechota, T. C.

    2003-12-01

    The 1996 amendment to the Safe Drinking Water Act of 1974 created the Source Water Assessment Program (SWAP) with an objective to evaluate potential sources of contamination to drinking water intakes. The development of a Source Water Assessment Plan for Las Vegas Valley surface water runoff into Lake Mead is important since it will guide future work on source water protection of the main source of water. The first step was the identification of the watershed boundary and source water protection area. Two protection zones were delineated. Zone A extends 500 ft around water bodies, and Zone B extends 3000 ft from the boundaries of Zone A. These Zones extend upstream to the limits of dry weather flows in the storm channels within the Las Vegas Valley. After the protection areas were identified, the potential sources of contamination in the protection area were inventoried. Field work was conducted to identify possible sources of contamination. A GIS coverage obtained from local data sources was used to identify the septic tank locations. Finally, the National Pollutant Discharge Elimination System (NPDES) Permits were obtained from the State of Nevada, and included in the inventory. After the inventory was completed, a level of risk was assigned to each potential contaminating activity (PCA). The contaminants of concern were grouped into five categories: volatile organic compounds (VOCs), synthetic organic compounds (SOCs), inorganic compounds (IOCs), microbiological, and radionuclides. The vulnerability of the water intake to each of the PCAs was assigned based on these five categories, and also on three other factors: the physical barrier effectiveness, the risk potential, and the time of travel. The vulnerability analysis shows that the PCAs with the highest vulnerability rating include septic systems, golf courses/parks, storm channels, gas stations, auto repair shops, construction, and the wastewater treatment plant discharges. Based on the current water quality

  11. Convergent surface water distributions in U.S. cities

    Science.gov (United States)

    M.K. Steele; J.B. Heffernan; N. Bettez; J. Cavender-Bares; P.M. Groffman; J.M. Grove; S. Hall; S.E. Hobbie; K. Larson; J.L. Morse; C. Neill; K.C. Nelson; J. O' Neil-Dunne; L. Ogden; D.E. Pataki; C. Polsky; R. Roy Chowdhury

    2014-01-01

    Earth's surface is rapidly urbanizing, resulting in dramatic changes in the abundance, distribution and character of surface water features in urban landscapes. However, the scope and consequences of surface water redistribution at broad spatial scales are not well understood. We hypothesized that urbanization would lead to convergent surface water abundance and...

  12. Water droplet evaporation from sticky superhydrophobic surfaces

    Science.gov (United States)

    Lee, Moonchan; Kim, Wuseok; Lee, Sanghee; Baek, Seunghyeon; Yong, Kijung; Jeon, Sangmin

    2017-07-01

    The evaporation dynamics of water from sticky superhydrophobic surfaces was investigated using a quartz crystal microresonator and an optical microscope. Anodic aluminum oxide (AAO) layers with different pore sizes were directly fabricated onto quartz crystal substrates and hydrophobized via chemical modification. The resulting AAO layers exhibited hydrophobic or superhydrophobic characteristics with strong adhesion to water due to the presence of sealed air pockets inside the nanopores. After placing a water droplet on the AAO membranes, variations in the resonance frequency and Q-factor were measured throughout the evaporation process, which were related to changes in mass and viscous damping, respectively. It was found that droplet evaporation from a sticky superhydrophobic surface followed a constant contact radius (CCR) mode in the early stage of evaporation and a combination of CCR and constant contact angle modes without a Cassie-Wenzel transition in the final stage. Furthermore, AAO membranes with larger pore sizes exhibited longer evaporation times, which were attributed to evaporative cooling at the droplet interface.

  13. Renal imaging with a new agent sup(99m)Tc-d1-DMS

    International Nuclear Information System (INIS)

    Tanaka, A.

    1980-01-01

    By using sup(99m)-Tc-d1 DMS labeled with 99 m-Tc using stannous chloride and prepared with freeze-dried d1-DMS containing a 3:1 molar ratio of DMS and Sn +2 the effect of stereochemical factor of DMS on kidney affinity, renal images, blood clearance, urinary excretion was studied in experimental animals and two normal volunteers and 75 patients. The comparation revealed a quite similar formation of complex II from d1-DMS to that from the meso-form, judge from its absorption spectra and absorption behavior into the gel. The stereochemical difference of DMS is not a critical factor for the formation of the sup(99m)-Tc-DMS complex with high affinity for the kidney, although it is believed that the renal accumulation of Tc-complex will depend greatly on chemical configuration of the complex. (APR)

  14. A study of the atmospherically important reactions of dimethylsulfide (DMS) with I2 and ICl using infrared matrix isolation spectroscopy and electronic structure calculations.

    Science.gov (United States)

    Beccaceci, Sonya; Armata, Nerina; Ogden, J Steven; Dyke, John M; Rhyman, Lydia; Ramasami, Ponnadurai

    2012-02-21

    The reactions of dimethylsulfide (DMS) with molecular iodine (I(2)) and iodine monochloride (ICl) have been studied by infrared matrix isolation spectroscopy by co-condensation of the reagents in an inert gas matrix. Molecular adducts of DMS + I(2) and DMS + ICl have also been prepared using standard synthetic methods. The vapour above each of these adducts trapped in an inert gas matrix gave the same infrared spectrum as that recorded for the corresponding co-condensation reaction. In each case, the infrared spectrum has been interpreted in terms of a van der Waals adduct, DMS : I(2) and DMS : ICl, with the aid of infrared spectra computed for their minimum energy structures at the MP2 level. Computed relative energies of minima and transition states on the potential energy surfaces of these reactions were used to understand why they do not proceed further than the reactant complexes DMS : I(2) and DMS : ICl. The main findings of this research are compared with results obtained earlier for the DMS + Cl(2) and DMS + Br(2) reactions, and the atmospheric implications of the conclusions are also considered.

  15. Water evaporation on highly viscoelastic polymer surfaces.

    Science.gov (United States)

    Pu, Gang; Severtson, Steven J

    2012-07-03

    Results are reported for a study on the evaporation of water droplets from a highly viscoelastic acrylic polymer surface. These are contrasted with those collected for the same measurements carried out on polydimethylsiloxane (PDMS). For PDMS, the evaporation process involves the expected multistep process including constant drop area, constant contact angle, and finally a combination of these steps until the liquid is gone. In contrast, water evaporation from the acrylic polymer shows a constant drop area mode throughout. Furthermore, during the evaporation process, the drop area actually expands on the acrylic polymer. The single mode evaporation process is consistent with formation of wetting structures, which cannot be propagated by the capillary forces. Expansion of the drop area is attributed to the influence of the drop capillary pressure. Furthermore, the rate of drop area expansion is shown to be dependent on the thickness of the polymer film.

  16. Effect of solid waste landfill on underground and surface water ...

    African Journals Online (AJOL)

    Effect of solid waste landfill on underground and surface water quality at ring road, Ibadan, Nigeria. ... parameters showed increased concentrations over those from control sites. ... Keywords: Landfill, groundwater, surface-water, pollution.

  17. chemical and microbiological assessment of surface water samples

    African Journals Online (AJOL)

    PROF EKWUEME

    concentrations and bacteriological content. Evaluation of the results ... and Aninri local government areas of Enugu state. Surface water ... surface water bodies are prone to impacts from ... Coal Measures (Akamigbo, 1987). The geologic map ...

  18. WRAP module 1 DMS/PCS interface definition document

    International Nuclear Information System (INIS)

    Weidert, J.R.

    1994-01-01

    This document has been developed to define the computer software interfaces between Waste Receiving ampersand Processing Module 1 (WRAP 1) computer systems. The interfaces include those data interfaces which exist between the Plant Control System (PCS) and Data Management System (DMS), between the DMS and Non-Destructive Assay (NDA) equipment, and between the DMS and Boxed Waste Assay System (BWAS) equipment. In addition to the data interfaces between the various WRAP computer systems; there are also a number of control functions between WRAP 1 equipment. These control function interfaces have been specified in WRAP Construction specification 13462 and the associated equipment specifications. The PCS vendor has been listed in the equipment specifications as the responsible party for establishing the final control system interface between the PCS and Non-Destructive Examination (NDE) Equipment, the PCS and Non-Destructive Assay (NDA) Equipment, and the PCS and BWAS equipment. The primary interface requirements between these systems are addressed in Specification Sections 13462, 13532, 13533, 13026, 13537, and 13538. Additional requirements may be found in other specification sections such as the Automatic Stacker Retriever System (AS/RS) Technical Specification 14520 and the WRAP 1 Data Management System Software Requirements Specification

  19. Mathematical aspects of surface water waves

    International Nuclear Information System (INIS)

    Craig, Walter; Wayne, Clarence E

    2007-01-01

    The theory of the motion of a free surface over a body of water is a fascinating subject, with a long history in both applied and pure mathematical research, and with a continuing relevance to the enterprises of mankind having to do with the sea. Despite the recent advances in the field (some of which we will hear about during this Workshop on Mathematical Hydrodynamics at the Steklov Institute), and the current focus of the mathematical community on the topic, many fundamental mathematical questions remain. These have to do with the evolution of surface water waves, their approximation by model equations and by computer simulations, the detailed dynamics of wave interactions, such as would produce rogue waves in an open ocean, and the theory (partially probabilistic) of approximating wave fields over large regions by averaged 'macroscopic' quantities which satisfy essentially kinetic equations of motion. In this note we would like to point out open problems and some of the directions of current research in the field. We believe that the introduction of new analytical techniques and novel points of view will play an important role in the future development of the area.

  20. Water infiltration into exposed fractured rock surfaces

    International Nuclear Information System (INIS)

    Rasmussen, T.C.; Evans, D.D.

    1993-01-01

    Fractured rock media are present at many existing and potential waste disposal sites, yet characterization data and physical relationships are not well developed for such media. This study focused on water infiltration characteristics of an exposed fractured rock as an approach for defining the upper boundary condition for unsaturated-zone water percolation and contaminant transport modeling. Two adjacent watersheds of 0.24 and 1.73 ha with slopes up to 45% were instrumented for measuring rainfall and runoff. Fracture density was measured from readily observable fracture traces on the surface. Three methods were employed to evaluate the rainfall-runoff relationship. The first method used the annual totals and indicated that only 22.5% of rainfall occurred as runoff for the 1990-1991 water year, which demonstrates a high water intake rate by the exposed fracture system. The second method employed total rainfall and runoff for individual storms in conjunction with the commonly used USDA Soil Conservation Service curve number method developed for wide ranges of soils and vegetation. Curve numbers between 75 and 85 were observed for summer and winter storms with dry antecedent runoff conditions, while values exceeded 90 for wet conditions. The third method used a mass-balance approach for four major storms, which indicated that water intake rates ranged from 2.0 to 7.3 mm h -1 , yielding fracture intake velocities ranging from 122 to 293 m h -1 . The three analyses show the complexity of the infiltration process for fractured rock. However, they contribute to a better understanding of the upper boundary condition for predicting contaminant transport through an unsaturated fractured rock medium. 17 refs., 4 figs., 1 tab

  1. Isolation and characterization of dimethyl sulfide (DMS)-degrading bacteria from soil and biofilter treating waste gas containing DMS from the laboratory and pulp and paper industry.

    Science.gov (United States)

    Giri, Balendu Shekher; Juwarkar, Asha A; Satpute, D B; Mudliar, S N; Pandey, R A

    2012-07-01

    Dimethyl sulfide (DMS) is one of the sulfurous pollutants present in the waste gas generated from the pulp and paper industry. DMS has environmental health implications; therefore, it is necessary to treat the waste gas containing DMS prior to discharge into the environment. A bench-scale biofilter was operated in the laboratory as well as in a pulp and paper industry for the treatment of DMS. Both the biofilters were packed with pre-sterilized wood chips and cow dung/compost of the same origin seeded with biomass developed from garden soil enriched with DMS. The biofilters were operated for the generation of process parameters, and the potential microorganisms isolated from both the biofilters have been purified and characterized for degradation of DMS. Further, these cultures were purified on a basal medium using DMS as a sole carbon source for the growth. Further, the purified cultures were characterized through standard fatty acid methyl esters (FAME)-gas chromatography method, and the isolates were found to be mesophilic, aerobic microbes. These microbes were identified as Bacillus sphaericus-GC subgroup F, Paenibacillus polymyxa, B. sphaericus-GC subgroup F, B. sphaericus-GC subgroup F, and Bacillus megaterium-GC subgroup A, respectively. The potential culture for degradation of DMS was identified as B. sphaericus by 16s rRNA molecular analysis.

  2. Organic acids in naturally colored surface waters

    Science.gov (United States)

    Lamar, William L.; Goerlitz, D.F.

    1966-01-01

    Most of the organic matter in naturally colored surface waters consists of a mixture of carboxylic acids or salts of these acids. Many of the acids color the water yellow to brown; however, not all of the acids are colored. These acids range from simple to complex, but predominantly they are nonvolatile polymeric carboxylic acids. The organic acids were recovered from the water by two techniques: continuous liquid-liquid extraction with n-butanol and vacuum evaporation at 50?C (centigrade). The isolated acids were studied by techniques of gas, paper, and column chromatography and infrared spectroscopy. About 10 percent of the acids recovered were volatile or could be made volatile for gas chromatographic analysis. Approximately 30 of these carboxylic acids were isolated, and 13 of them were individually identified. The predominant part of the total acids could not be made volatile for gas chromatographic analysis. Infrared examination of many column chromatographic fractions indicated that these nonvolatile substances are primarily polymeric hydroxy carboxylic acids having aromatic and olefinic unsaturation. The evidence suggests that some of these acids result from polymerization in aqueous solution. Elemental analysis of the sodium fusion products disclosed the absence of nitrogen, sulfur, and halogens.

  3. Microbial production and consumption of dimethyl sulfide (DMS) in a sea grass (Zostera noltii)-dominated marine intertidal sediment ecosystem (Bassin d'Arcachon, France)

    NARCIS (Netherlands)

    Jonkers, HM; van Bergeijk, SA; van Gemerden, H

    The relation between net dimethyl sulfide (DMS) production and changes in near surface (0-5 mm) oxygen concentrations in a sea grass (Zostera noltii Hornem)-covered intertidal sediment ecosystem was examined during a diel cycle. Sediment covered with Zostera was found to be more oxygenated than

  4. The interaction between surface water and groundwater and its ...

    Indian Academy of Sciences (India)

    Surface water; groundwater; stable isotopes; water quality; Second Songhua River basin. .... The total dissolved solid (TDS) was calculated by the con- centrations of major ions in ...... evaluating water quality management effectiveness; J.

  5. Atmospheric Water Harvesting: Role of Surface Wettability and Edge Effect

    KAUST Repository

    Jin, Yong; Zhang, Lianbin; Wang, Peng

    2017-01-01

    Atmospheric water is emerging as an important potable water source. The present work experimentally and theoretically investigates water condensation and collection on flat surfaces with contrasting contact angles and contact angle hysteresis (CAH

  6. Impact of Water Withdrawals from Groundwater and Surface Water on Continental Water Storage Variations

    Science.gov (United States)

    Doell, Petra; Hoffmann-Dobrev, Heike; Portmann, Felix T.; Siebert, Stefan; Eicker, Annette; Rodell, Matthew; Strassberg, Gil

    2011-01-01

    Humans have strongly impacted the global water cycle, not only water flows but also water storage. We have performed a first global-scale analysis of the impact of water withdrawals on water storage variations, using the global water resources and use model WaterGAP. This required estimation of fractions of total water withdrawals from groundwater, considering five water use sectors. According to our assessment, the source of 35% of the water withdrawn worldwide (4300 cubic km/yr during 1998-2002) is groundwater. Groundwater contributes 42%, 36% and 27% of water used for irrigation, households and manufacturing, respectively, while we assume that only surface water is used for livestock and for cooling of thermal power plants. Consumptive water use was 1400 cubic km/yr during 1998-2002. It is the sum of the net abstraction of 250 cubic km/yr of groundwater (taking into account evapotranspiration and return flows of withdrawn surface water and groundwater) and the net abstraction of 1150 km3/yr of surface water. Computed net abstractions indicate, for the first time at the global scale, where and when human water withdrawals decrease or increase groundwater or surface water storage. In regions with extensive surface water irrigation, such as Southern China, net abstractions from groundwater are negative, i.e. groundwater is recharged by irrigation. The opposite is true for areas dominated by groundwater irrigation, such as in the High Plains aquifer of the central USA, where net abstraction of surface water is negative because return flow of withdrawn groundwater recharges the surface water compartments. In intensively irrigated areas, the amplitude of seasonal total water storage variations is generally increased due to human water use; however, in some areas, it is decreased. For the High Plains aquifer and the whole Mississippi basin, modeled groundwater and total water storage variations were compared with estimates of groundwater storage variations based on

  7. Potentially hazardous substances in surface waters. II. Cholinesterase inhibitors in Dutch surface waters

    NARCIS (Netherlands)

    Greve, P.A.; Freudenthal, J.; Wit, S.L.

    1972-01-01

    Several analytical methods were employed to determine the concentrations of cholinesterase inhibitors in several Dutch surface waters. An Auto-Analyzer method was used for screening purposes; thin-layer chromatography and gas-liquid chromatography-mass spectrometry were used for identification and

  8. In situ biodenitrification of nitrate surface water

    International Nuclear Information System (INIS)

    Schmidt, G.C.; Ballew, M.B.

    1995-01-01

    The US Department of Energy's Weldon Spring Site Remedial Action Project has successfully operated a full-scale in situ biodenitrification system to treat water with elevated nitrate levels in abandoned raffinate pits. Bench- and pilot-scale studies were conducted to evaluate the feasibility of the process and to support its full-scale design and application. Bench testing evaluated variables that would influence development of an active denitrifying biological culture. The variables were carbon source, phosphate source, presence and absence of raffinate sludge, addition of a commercially available denitrifying microbial culture, and the use of a microbial growth medium. Nitrate levels were reduced from 750 mg/L NO 3 -N to below 10 mg/L NO 3 -N within 17 days. Pilot testing simulated the full-scale process to determine if nitrate levels could be reduced to less than 10 mg/L NO 3 -N when high levels are present below the sludge surface. Four separate test systems were examined along with two control systems. Nitrates were reduced from 1,200 mg/L NO 3 -N to below 2 mg/L NO 3 -N within 21 days. Full-scale operation has been initiated to denitrify 900,000-gal batches alternating between two 1-acre ponds. The process used commercially available calcium acetate solution and monosodium/disodium phosphate solution as a nutrient source for indigenous microorganisms to convert nitrates to molecular nitrogen and water

  9. Modified Mixed Lagrangian-Eulerian Method Based on Numerical Framework of MT3DMS on Cauchy Boundary.

    Science.gov (United States)

    Suk, Heejun

    2016-07-01

    MT3DMS, a modular three-dimensional multispecies transport model, has long been a popular model in the groundwater field for simulating solute transport in the saturated zone. However, the method of characteristics (MOC), modified MOC (MMOC), and hybrid MOC (HMOC) included in MT3DMS did not treat Cauchy boundary conditions in a straightforward or rigorous manner, from a mathematical point of view. The MOC, MMOC, and HMOC regard the Cauchy boundary as a source condition. For the source, MOC, MMOC, and HMOC calculate the Lagrangian concentration by setting it equal to the cell concentration at an old time level. However, the above calculation is an approximate method because it does not involve backward tracking in MMOC and HMOC or allow performing forward tracking at the source cell in MOC. To circumvent this problem, a new scheme is proposed that avoids direct calculation of the Lagrangian concentration on the Cauchy boundary. The proposed method combines the numerical formulations of two different schemes, the finite element method (FEM) and the Eulerian-Lagrangian method (ELM), into one global matrix equation. This study demonstrates the limitation of all MT3DMS schemes, including MOC, MMOC, HMOC, and a third-order total-variation-diminishing (TVD) scheme under Cauchy boundary conditions. By contrast, the proposed method always shows good agreement with the exact solution, regardless of the flow conditions. Finally, the successful application of the proposed method sheds light on the possible flexibility and capability of the MT3DMS to deal with the mass transport problems of all flow regimes. © 2016, National Ground Water Association.

  10. Foundational Report Series: Advanced Distribution Management Systems for Grid Modernization, DMS Industry Survey

    Energy Technology Data Exchange (ETDEWEB)

    Singh, Ravindra [Argonne National Lab. (ANL), Argonne, IL (United States); Uluski, Robert [Argonne National Lab. (ANL), Argonne, IL (United States); Reilly, James T. [Reilly Associates, Pittston, PA (United States); Martino, Sal [Electric Power Research Inst. (EPRI), Palo Alto, CA (United States); Lu, Xiaonan [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, Jianhui [Argonne National Lab. (ANL), Argonne, IL (United States)

    2017-04-01

    The objective of this survey is to benchmark current practices for DMS implementation to serve as a guide for future system implementations. The survey sought information on current plans to implement DMS, DMS functions of interest, implementation challenges, functional benefits achieved, and other relevant information. These survey results were combined (where possible) with results of similar surveys conducted in the previous four years to observe trends over time.

  11. Grazing-Activated Production of Dimethyl Sulfide (DMS) by two clones of Emiliania huxleyi

    Science.gov (United States)

    Wolfe, Gordon V.; Steinke, Michael

    1996-01-01

    Emiliania huxleyi clones CCMP 370 and CCMP 373 produced similar amounts of dimethylsulfoniopropionate (DMSP) during axenic exponential growth, averaging 109 mM internal DMSP. Both clones had detectable DMSP lyase activity, as measured by production of dimethyl sulfide (DMS) during in vitro assays of crude cell preparations, but activities and conditions differed considerably between clones. Clone 373 had high activity; clone 370 had low activity and required chloride. For both strains, enzyme activity per cell was constant during exponential growth, but little DMS was produced by healthy cells. Rather, DMS production was activated when cells were subjected to physical or chemical stresses that caused cell lysis. We propose that DMSP lyase and DMSP are segregated within these cells and re-action only under conditions that result in cell stress or damage. Such activation occurs during microzooplankton grazing. When these clones were grazed by the dinoflagellate Oxyrrhis marina, DMS was produced; ungrazed cells, as well as those exposed to grazer exudates and associated bacteria, generated no DMS. Grazing of clone 373 produced much more DMS than grazing of clone 370, consistent with their relative in vitro DMSP lyase activities. DMS was only generated when cells were actually being grazed, indicating that ingested cells were responsible for the DMS formation. We suggest that even low levels of grazing can greatly accelerate DMS production.

  12. Atmospheric Water Harvesting: Role of Surface Wettability and Edge Effect

    KAUST Repository

    Jin, Yong

    2017-06-23

    Atmospheric water is emerging as an important potable water source. The present work experimentally and theoretically investigates water condensation and collection on flat surfaces with contrasting contact angles and contact angle hysteresis (CAH) to elucidate their roles on water mass collection efficiency. The experimental results indicate that a hydrophilic surface promotes nucleation and individual droplets growth, and a surface with a low CAH tends to let a smaller droplet to slide down, but the overall water mass collection efficiency is independent of both surface contact angle and CAH. The experimental results agree well with our theoretical calculations. During water condensation, a balance has to be struck between single droplet growth and droplet density on a surface so as to maintain a constant water droplet surface coverage ratio, which renders the role of both surface wettability and hysteresis insignificant to the ultimate water mass collection. Moreover, water droplets on the edges of a surface grow much faster than those on the non-edge areas and thus dominate the contribution to the water mass collection by the entire surface, directly pointing out the very important role of edge effect on water condensation and collection.

  13. Characterisation of the inorganic chemistry of surface waters in ...

    African Journals Online (AJOL)

    The main purpose of this study was to determine a simple inorganic chemistry index that can be used for all surface waters in South Africa, in order to characterise the inorganic chemistry of surface waters. Water quality data collected up until 1999 from all sample monitoring stations (2 068 monitoring stations, 364 659 ...

  14. Thermophoretically driven water droplets on graphene and boron nitride surfaces

    Science.gov (United States)

    Rajegowda, Rakesh; Kannam, Sridhar Kumar; Hartkamp, Remco; Sathian, Sarith P.

    2018-05-01

    We investigate thermally driven water droplet transport on graphene and hexagonal boron nitride (h-BN) surfaces using molecular dynamics simulations. The two surfaces considered here have different wettabilities with a significant difference in the mode of droplet transport. The water droplet travels along a straighter path on the h-BN sheet than on graphene. The h-BN surface produced a higher driving force on the droplet than the graphene surface. The water droplet is found to move faster on h-BN surface compared to graphene surface. The instantaneous contact angle was monitored as a measure of droplet deformation during thermal transport. The characteristics of the droplet motion on both surfaces is determined through the moment scaling spectrum. The water droplet on h-BN surface showed the attributes of the super-diffusive process, whereas it was sub-diffusive on the graphene surface.

  15. Photochemical Transformation Processes in Sunlit Surface Waters

    Science.gov (United States)

    Vione, D.

    2012-12-01

    Photochemical reactions are major processes in the transformation of hardly biodegradable xenobiotics in surface waters. They are usually classified into direct photolysis and indirect or sensitised degradation. Direct photolysis requires xenobiotic compounds to absorb sunlight, and to get transformed as a consequence. Sensitised transformation involves reaction with transient species (e.g. °OH, CO3-°, 1O2 and triplet states of chromophoric dissolved organic matter, 3CDOM*), photogenerated by so-called photosensitisers (nitrate, nitrite and CDOM). CDOM is a major photosensitiser: is it on average the main source of °OH (and of CO3-° as a consequence, which is mainly produced upon oxidation by °OH of carbonate and bicarbonate) and the only important source of 1O2 and 3CDOM* [1, 2]. CDOM origin plays a key role in sensitised processes: allochthonous CDOM derived from soil runoff and rich in fulvic and humic substances is usually more photoactive than autochthonous CDOM (produced by in-water biological processes and mainly consisting of protein-like material) or of CDOM derived from atmospheric deposition. An interesting gradual evolution of CDOM origin and photochemistry can be found in mountain lakes across the treeline, which afford a gradual transition of allochthonous- autochtonous - atmopheric CDOM when passing from trees to alpine meadows to exposed rocks [3]. Another important issue is the sites of reactive species photoproduction in CDOM. While there is evidence that smaller molecular weight fractions are more photoactive, some studies have reported considerable 1O2 reactivity in CDOM hydrophobic sites and inside particles [4]. We have recently addressed the problem and found that dissolved species in standard humic acids (hydrodynamic diameter pollutants to be assessed and modelled. For instance, it is possible to predict pollutant half-life times by knowing absorption spectrum, direct photolysis quantum yield and reaction rate constants with °OH, CO3

  16. How to repel hot water from a superhydrophobic surface?

    KAUST Repository

    Yu, Zhejun

    2014-01-01

    Superhydrophobic surfaces, with water contact angles greater than 150° and slide angles less than 10°, have attracted a great deal of attention due to their self-cleaning ability and excellent water-repellency. It is commonly accepted that a superhydrophobic surface loses its superhydrophobicity in contact with water hotter than 50 °C. Such a phenomenon was recently demonstrated by Liu et al. [J. Mater. Chem., 2009, 19, 5602], using both natural lotus leaf and artificial leaf-like surfaces. However, our work has shown that superhydrophobic surfaces maintained their superhydrophobicity, even in water at 80 °C, provided that the leaf temperature is greater than that of the water droplet. In this paper, we report on the wettability of water droplets on superhydrophobic thin films, as a function of both their temperatures. The results have shown that both the water contact and slide angles on the surfaces will remain unchanged when the temperature of the water droplet is greater than that of the surface. The water contact angle, or the slide angle, will decrease or increase, however, with droplet temperatures increasingly greater than that of the surfaces. We propose that, in such cases, the loss of superhydrophobicity of the surfaces is caused by evaporation of the hot water molecules and their condensation on the cooler surface. © 2014 the Partner Organisations.

  17. Distribution of {sup 129}I in terrestrial surface water environments

    Energy Technology Data Exchange (ETDEWEB)

    Chen, Xuegao [State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098 (China); College of Hydrology and Water Resources, Hohai University, Nanjing (China); Gong, Meng [College of Hydrology and Water Resources, Hohai University, Nanjing (China); Yi, Peng, E-mail: pengyi1915@163.com [State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098 (China); College of Hydrology and Water Resources, Hohai University, Nanjing (China); Aldahan, Ala [Department of Earth Sciences, Uppsala University, Uppsala (Sweden); Department of Geology, United Arab Emirates University, Al Ain (United Arab Emirates); Yu, Zhongbo [State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098 (China); College of Hydrology and Water Resources, Hohai University, Nanjing (China); Possnert, Göran [Tandem Laboratory, Uppsala University, Uppsala (Sweden); Chen, Li [State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering, Hohai University, Nanjing 210098 (China); College of Hydrology and Water Resources, Hohai University, Nanjing (China)

    2015-10-15

    The global distribution of the radioactive isotope iodine-129 in surface waters (lakes and rivers) is presented here and compared with the atmospheric deposition and distribution in surface marine waters. The results indicate relatively high concentrations in surface water systems in close vicinity of the anthropogenic release sources as well as in parts of Western Europe, North America and Central Asia. {sup 129}I level is generally higher in the terrestrial surface water of the Northern hemisphere compared to the southern hemisphere. The highest values of {sup 129}I appear around 50°N and 40°S in the northern and southern hemisphere, separately. Direct gaseous and marine atmospheric emissions are the most likely avenues for the transport of {sup 129}I from the sources to the terrestrial surface waters. To apply iodine-129 as process tracer in terrestrial surface water environment, more data are needed on {sup 129}I distribution patterns both locally and globally.

  18. Variability in chemistry of surface and soil waters of an ...

    African Journals Online (AJOL)

    Water chemistry is important for the maintenance of wetland structure and function. Interpreting ecological patterns in a wetland system therefore requires an in-depth understanding of the water chemistry of that system. We investigated the spatial distribution of chemical solutes both in soil pore water and surface water, ...

  19. Short Communication: Conductivity as an indicator of surface water ...

    African Journals Online (AJOL)

    Various water- soluble species are present in FeCr waste materials and in process water. Considering the size of the South African FeCr industry and its global importance, it is essential to assess the extent of potential surface water pollution in the proximity of FeCr smelters by such watersoluble species. In this study water ...

  20. TURBIDITY REMOVAL FROM SURFACE WATER USING ...

    African Journals Online (AJOL)

    User

    2016-06-01

    Jun 1, 2016 ... Plant-based coagulants are potential alternatives to chemical coagulants used in drinking water treatment. ... Conventional water treatment systems involve the use of synthetic ..... Thesis, Royal Institute of Technology (KTH),.

  1. Indices of quality surface water bodies in the planning of water resources

    Directory of Open Access Journals (Sweden)

    Rodríguez-Miranda, Juan Pablo

    2016-12-01

    Full Text Available This paper considers a review of the literature major and significant methods of quality indices of water applied in surface water bodies, used and proposed for assessing the significance of parameters of water quality in the assessment of surface water currents and they are usually used in making decisions for intervention and strategic prevention measures for those responsible for the conservation and preservation of watersheds where these water bodies belong. An exploratory methodology was applied to realize the conceptualization of each water quality index. As a result, it is observed that there are several important methods for determining the water quality index applied in surface water bodies.

  2. An ontology design pattern for surface water features

    Science.gov (United States)

    Sinha, Gaurav; Mark, David; Kolas, Dave; Varanka, Dalia; Romero, Boleslo E.; Feng, Chen-Chieh; Usery, E. Lynn; Liebermann, Joshua; Sorokine, Alexandre

    2014-01-01

    Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities exist due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology for other more context-dependent ontologies. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex or specialized surface water ontologies. A fundamental distinction is made in this ontology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is implemented in OWL, but Description Logic axioms and a detailed explanation is provided in this paper. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. Also provided is a discussion of why there is a need to complement the pattern with other ontologies, especially the previously developed Surface Network pattern. Finally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through an annotated geospatial dataset and sample queries using the classes of the Surface Water pattern.

  3. A first appraisal of prognostic ocean DMS models and prospects for their use in climate models

    NARCIS (Netherlands)

    Le Clainche, Yvonnick; Vezina, Alain; Levasseur, Maurice; Cropp, Roger A.; Gunson, Jim R.; Vallina, Sergio M.; Vogt, Meike; Lancelot, Christiane; Allen, J. Icarus; Archer, Stephen D.; Bopp, Laurent; Deal, Clara; Elliott, Scott; Jin, Meibing; Malin, Gill; Schoemann, Veronique; Simo, Rafel; Six, Katharina D.; Stefels, Jacqueline

    2010-01-01

    Ocean dimethylsulfide (DMS) produced by marine biota is the largest natural source of atmospheric sulfur, playing a major role in the formation and evolution of aerosols, and consequently affecting climate. Several dynamic process-based DMS models have been developed over the last decade, and work

  4. Technical Analysis of the Slosson-Diagnostic Math Screener (S-DMS)

    Science.gov (United States)

    Erford, Bradley T.; Klein, Lauren

    2007-01-01

    The Slosson-Diagnostic Math Screener (S-DMS) was designed to help identify students in Grades 1 to 8 at risk for mathematics failure. Internal consistency, test-retest reliability, item analysis, decision efficiency, convergent validity, and factorial validity of all five levels of the S-DMS were studied using 20 independent samples of students…

  5. Annual cycle of the production and fate of DMS and DMSP in a marine coastal system

    NARCIS (Netherlands)

    Kwint, RLJ; Kramer, KJM

    The production of DMSP by phytoplankton and the fate through the marine system of both DMSP and DMS were followed for a period of 21 mo in the natural environment by studying a Wadden Sea tidal inlet. The major production and emission of DMS appeared to be Limited to a period of only 2 mo, which was

  6. Development and evoluation of a DMS-based method for the detection of insecticides.

    Science.gov (United States)

    Differential mobility spectrometry (DMS), also referred to as high-field asymmetric waveform ion mobility spectromety (FAIMS), is a reapidly advancing technology for gas-phase separation. DMS has the potential to emerge as a major stand-alone separation technique such as LC or GC. To date, several...

  7. Development and Evaluation of a DMS-based Method for the Detection of Insecticides

    Science.gov (United States)

    Differential mobility spectrometry (DMS), also commonly referred to as high-field asymmetric waveform ion mobility spectrometry (FAIMS), is a rapidly advancing technology for gas-phase separation. DMS has the potential to emerge as a major stand-alone separation technique such as LC or GC. To date,...

  8. Environmental drivers of temporal variability in DMS (P) in the surfwater of a tropical intertidal beach

    Digital Repository Service at National Institute of Oceanography (India)

    Pandey, S.S.; LokaBharathi, P.A.

    show that the average DMS concentration was highest during the monsoon season (7.64nM) followed by post-monsoon (6.71nM) and premonsoon(1.58nM) Consequently, the estimated sea-air flux of DMS is monsoon > post-monsoon > pre-monsoon at 24.75> 18.93> 2...

  9. WRAP Module 1 data management system (DMS) software design description (SDD)

    Energy Technology Data Exchange (ETDEWEB)

    Talmage, P.A.

    1995-03-17

    The Waste Receiving and Processing (WRAP) Module 1 Data Management System (DMS) System Design Description (SDD) describes the logical and physical architecture of the system. The WRAP 1 DMS SDD formally partitions the elements of the system described in the WRAP 1 DMS Software requirements specification into design objects and describes the key properties and relationships among the design objects and interfaces with external systems such as the WRAP Plant Control System (PCS). The WRAP 1 DMS SDD can be thought of as a detailed blueprint for implementation activities. The design descriptions contained within this document will describe, in detail, the software products that will be developed to assist the Project W-026, Waste Receiving and Processing Module 1, in their management functions. The WRAP 1 DMS is required to collect, store, and report data related to certification, tracking, packaging, repackaging, processing, and shipment of waste processed or stored at the WRAP 1 facility.

  10. WRAP Module 1 data management system (DMS) software design description (SDD)

    International Nuclear Information System (INIS)

    Talmage, P.A.

    1995-01-01

    The Waste Receiving and Processing (WRAP) Module 1 Data Management System (DMS) System Design Description (SDD) describes the logical and physical architecture of the system. The WRAP 1 DMS SDD formally partitions the elements of the system described in the WRAP 1 DMS Software requirements specification into design objects and describes the key properties and relationships among the design objects and interfaces with external systems such as the WRAP Plant Control System (PCS). The WRAP 1 DMS SDD can be thought of as a detailed blueprint for implementation activities. The design descriptions contained within this document will describe, in detail, the software products that will be developed to assist the Project W-026, Waste Receiving and Processing Module 1, in their management functions. The WRAP 1 DMS is required to collect, store, and report data related to certification, tracking, packaging, repackaging, processing, and shipment of waste processed or stored at the WRAP 1 facility

  11. water quality assessment of underground and surface water ...

    African Journals Online (AJOL)

    Dr Osondu

    Water quality assessment in the Ethiopian highlands is crucial owing to increasing ... and provide information for formulating appropriate framework for an integrated ... with four seasons (rainy, dry period, small rains ..... treatment. Annual conference proceedings, American Water Works ... Towns' water supply and sanitation.

  12. Infiltration of pesticides in surface water into nearby drinking water supply wells

    DEFF Research Database (Denmark)

    Malaguerra, Flavio; Albrechtsen, Hans-Jørgen; Binning, Philip John

    Drinking water wells are often placed near streams because streams often overly permeable sediments and the water table is near the surface in valleys, and so pumping costs are reduced. The lowering of the water table by pumping wells can reverse the natural flow from the groundwater to the stream......, inducing infiltration of surface water to groundwater and consequently to the drinking water well. Many attenuation processes can take place in the riparian zone, mainly due to mixing, biodegradation and sorption. However, if the water travel time from the surface water to the pumping well is too short......, or if the compounds are poorly degradable, contaminants can reach the drinking water well at high concentrations, jeopardizing drinking water quality. Here we developed a reactive transport model to evaluate the risk of contamination of drinking water wells by surface water pollution. The model was validated using...

  13. Instability of confined water films between elastic surfaces

    NARCIS (Netherlands)

    de Beer, Sissi; 't Mannetje, Dieter; Zantema, Sietske; Mugele, Friedrich

    2010-01-01

    We investigated the dynamics of nanometer thin water films at controlled ambient humidity adsorbed onto two atomically smooth mica sheets upon rapidly bringing the surfaces into contact. Using a surface forces apparatus (SFA) in imaging mode, we found that the water films break up into a

  14. Models of Fate and Transport of Pollutants in Surface Waters

    Science.gov (United States)

    Okome, Gloria Eloho

    2013-01-01

    There is the need to answer very crucial questions of "what happens to pollutants in surface waters?" This question must be answered to determine the factors controlling fate and transport of chemicals and their evolutionary state in surface waters. Monitoring and experimental methods are used in establishing the environmental states.…

  15. Economic Impacts of Surface Mining on Household Drinking Water Supplies

    Science.gov (United States)

    This report provides information on the economic and social impacts of contaminated surface and ground water supplies on residents and households near surface mining operations. The focus is on coal slurry contamination of water supplies in Mingo County, West Virginia, and descr...

  16. The impact of uncontrolled waste disposal on surface water quality ...

    African Journals Online (AJOL)

    The main threat to the surface water quality in Addis Ababa is environmental pollution derived from domestic and industrial activities. Due to the inadequacy of controlled waste management strategies and waste treatment plants, people are forced to discharge wastes both on open surface and within water bodies.

  17. Sampling procedure for lake or stream surface water chemistry

    Science.gov (United States)

    Robert Musselman

    2012-01-01

    Surface waters collected in the field for chemical analyses are easily contaminated. This research note presents a step-by-step detailed description of how to avoid sample contamination when field collecting, processing, and transporting surface water samples for laboratory analysis.

  18. Monitoring of Water and Contaminant Migration at the Groundwater-Surface Water Interface

    Science.gov (United States)

    2008-08-01

    seepage is occurring in a freshwater lake environment and to map the lateral extent of any subsurface contamination at the groundwater –surface water ...and Contaminant Migration at the Groundwater -Surface Water Interface August 2008 Report Documentation Page Form ApprovedOMB No. 0704-0188 Public...4. TITLE AND SUBTITLE Monitoring of Water and Contaminant Migration at the Groundwater -Surface Water Interface 5a. CONTRACT NUMBER 5b. GRANT NUMBER

  19. Issues of the presence of parasitic protozoa in surface waters

    Directory of Open Access Journals (Sweden)

    Hawrylik Eliza

    2018-01-01

    This paper focuses on the problem of the presence of parasitic protozoa in surface waters. Characteristics of the most frequently recognized pathogens responsible for water-borne outbreaks were described, as well as sources of contamination and surface waters contamination due to protozoa of the genus Cryptosporidium and Giardia were presented. The methods of destroying the cysts and oocysts of parasitic protozoa used nowadays in the world were also presented in a review.

  20. 40 CFR 257.3-3 - Surface water.

    Science.gov (United States)

    2010-07-01

    ... 40 Protection of Environment 24 2010-07-01 2010-07-01 false Surface water. 257.3-3 Section 257.3-3... and Practices § 257.3-3 Surface water. (a) For purposes of section 4004(a) of the Act, a facility... Water Act, as amended. (b) For purposes of section 4004(a) of the Act, a facility shall not cause a...

  1. 77 FR 12227 - Long Term 2 Enhanced Surface Water Treatment Rule: Uncovered Finished Water Reservoirs; Public...

    Science.gov (United States)

    2012-02-29

    ... Water Treatment Rule: Uncovered Finished Water Reservoirs; Public Meeting AGENCY: Environmental... review of the uncovered finished water reservoir requirement in the Long Term 2 Enhanced Surface Water... uncovered finished water reservoir requirement and the agency's Six Year Review process. EPA also plans to...

  2. Treatability of South African surface waters by enhanced coagulation

    African Journals Online (AJOL)

    The majority of South African inland surface water sources are compromised due to a long-standing national policy of mandatory return flows. With renewed emphasis on the removal of organic carbon in the latest SANS 241 water quality standard, many South African water treatment managers may need to consider ...

  3. Environmental impact of by pass channel of surface waters

    International Nuclear Information System (INIS)

    Vismara, R.; Renoldi, M.; Torretta, V.

    1996-01-01

    In this paper are analyzed the impacts generated by surface waters drawing on river course. This impacts are generated also by reduction of water flow. This effect is most important for the presence of biological community: algae, fiches, micro invertebrates. Are also reported regional laws, water master plan of Lombardia region

  4. Underground coal mine subsidence impacts on surface water

    International Nuclear Information System (INIS)

    Stump, D.E. Jr.

    1992-01-01

    This paper reports that subsidence from underground coal mining alters surface water discharge and availability. The magnitude and areal extent of these impacts are dependent on many factors, including the amount of subsidence, topography, geology, climate, surface water - ground water interactions, and fractures in the overburden. There alterations may have positive and/or negative impacts. One of the most significant surface water impacts occurred in July 1957 near West Pittston, Pennsylvania. Subsidence in the Knox Mine under the Coxton Yards of the Lehigh Valley Railroad allowed part of the discharge in the Susquehanna River to flow into the mine and create a crater 200 feet in diameter and 300 feet deep. Fourteen railroad gondola cars fell into the hole which was eventually filled with rock, sand, and gravel. Other surface water impacts from subsidence may include the loss of water to the ground water system, the gaining of water from the ground water system, the creation of flooded subsidence troughs, the increasing of impoundment storage capacity, the relocation of water sources (springs), and the alteration of surface drainage patterns

  5. OCCURRENCE OF ENTERIC VIRUSES IN SURFACE WATERS

    Science.gov (United States)

    Human enteric viruses cause a number of diseases when individuals are exposed to contaminated drinking & recreational waters. Vaccination against poliovirus has virtually eliminated poliomyelitis from the planet. Other members of enterovirus group cause numerous diseases. Hepatit...

  6. Wind effect on water surface of water reservoirs

    Directory of Open Access Journals (Sweden)

    Petr Pelikán

    2013-01-01

    Full Text Available The primary research of wind-water interactions was focused on coastal areas along the shores of world oceans and seas because a basic understanding of coastal meteorology is an important component in coastal and offshore design and planning. Over time the research showed the most important meteorological consideration relates to the dominant role of winds in wave generation. The rapid growth of building-up of dams in 20th century caused spreading of the water wave mechanics research to the inland water bodies. The attention was paid to the influence of waterwork on its vicinity, wave regime respectively, due to the shoreline deterioration, predominantly caused by wind waves. Consequently the similar principles of water wave mechanics are considered in conditions of water reservoirs. The paper deals with the fundamental factors associated with initial wind-water interactions resulting in the wave origination and growth. The aim of the paper is thepresentation of utilization of piece of knowledge from a part of sea hydrodynamics and new approach in its application in the conditions of inland water bodies with respect to actual state of the art. The authors compared foreign and national approach to the solved problems and worked out graphical interpretation and overview of related wind-water interaction factors.

  7. Tc(V)-DMS tumor localization mechanism: a pH-sensitive Tc(V)-DMS-enhanced target/nontarget ratio by glucose-mediated acidosis

    International Nuclear Information System (INIS)

    Horiuchi, Kazuko; Saji, Hideo; Yokoyama, Akira

    1998-01-01

    Since the conception of the pentavalent technetium polynuclear complex of dimercaptosuccinic acid, Tc(V)-DMS, a great number of papers published on its clinical applicability forced us to question ''how tumor tissue appropriates the Tc(V)-DMS.'' Preliminary in vitro studies with Ehrlich ascites tumor cells (EATC) indicated the pH-sensitive character of this tumor agent. From this finding and the well-established notion that malignant tumors are more acidic than normal tissue, the in vivo correlation of Tc(V)-DMS accumulation in tumor tissue with its tissue acidification was considered of interest. The systemic lowering of tumor tissue pH by the stimulation of aerobic glycolysis has been well reported. In the present paper, the response of Tc(V)-DMS tumor accumulation to acidification induced by the glucose administration was explored in EATC-bearing mice. Measurement of tumor tissue pH was carried out by direct microelectrode technique and by histochemical umbelliferone technique in tumor tissue excised from EATC bearing mice. The regional acidity distribution is correlated with the regional radioactivity distribution registered by autoradiography. Evidence related to the pH sensitiveness of Tc(V)-DMS in response to glycolytic acidification was gathered; the pH measurement and the in vivo biodistribution of the double-tracer macroautoradiography with C-14 deoxyglucose (C-14-DG) demonstrated that the regional tissue distribution of Tc(V)-DMS was superimposed to that of C-14-DG. The glucose interventional modality offers the premier foundation for the interpretation of Tc(V)-DMS accumulation in diagnostic studies of malignant tumors

  8. Presence and risk assessment of pharmaceuticals in surface water and drinking water

    DEFF Research Database (Denmark)

    Sanderson, Hans

    2011-01-01

    Trace amounts of pharmaceuticals have been detected in surface waters in the nano- to microgram per liter range, and in drinking water in the nanogram/L range. The environmental risks of pharmaceuticals in surface waters have been evaluated and generally found to be low if the wastewater is treated...

  9. Coastal surface water suitability analysis for irrigation in Bangladesh

    Science.gov (United States)

    Mahtab, Mohammad Hossain; Zahid, Anwar

    2018-03-01

    Water with adequate quality and quantity is very important for irrigation to ensure the crop yields. Salinity is common problem in the coastal waters in Bangladesh. The intensity of salinity in the coastal zone in Bangladesh is not same. It fluctuates over the year. Sodium is another hazard which may hamper permeability and ultimately affects the fertility. It can reduce the crop yields. Although surface water is available in the coastal zone of Bangladesh, but its quality for irrigation needs to be monitored over the year. This paper will investigate the overall quality of coastal surface waters. Thirty-three water samples from different rivers were collected both in wet period (October-December) and in dry period (February-April). Different physical and chemical parameters are considered for investigation of the adequacy of water with respect to international irrigation water quality standards and Bangladesh standards. A comparison between the dry and wet period coastal surface water quality in Bangladesh will also be drawn here. The analysis shows that coastal surface water in Bangladesh is overall suitable for irrigation during wet period, while it needs treatment (which will increase the irrigation cost) for using for irrigation during dry period. Adaptation to this situation can improve the scenario. An integrated plan should be taken to increase the water storing capacity in the coastal area to harvest water during wet period.

  10. A GPU-based mipmapping method for water surface visualization

    Science.gov (United States)

    Li, Hua; Quan, Wei; Xu, Chao; Wu, Yan

    2018-03-01

    Visualization of water surface is a hot topic in computer graphics. In this paper, we presented a fast method to generate wide range of water surface with good image quality both near and far from the viewpoint. This method utilized uniform mesh and Fractal Perlin noise to model water surface. Mipmapping technology was enforced to the surface textures, which adjust the resolution with respect to the distance from the viewpoint and reduce the computing cost. Lighting effect was computed based on shadow mapping technology, Snell's law and Fresnel term. The render pipeline utilizes a CPU-GPU shared memory structure, which improves the rendering efficiency. Experiment results show that our approach visualizes water surface with good image quality at real-time frame rates performance.

  11. DMS-MaPseq for genome-wide or targeted RNA structure probing in vivo.

    Science.gov (United States)

    Zubradt, Meghan; Gupta, Paromita; Persad, Sitara; Lambowitz, Alan M; Weissman, Jonathan S; Rouskin, Silvi

    2017-01-01

    Coupling of structure-specific in vivo chemical modification to next-generation sequencing is transforming RNA secondary structure studies in living cells. The dominant strategy for detecting in vivo chemical modifications uses reverse transcriptase truncation products, which introduce biases and necessitate population-average assessments of RNA structure. Here we present dimethyl sulfate (DMS) mutational profiling with sequencing (DMS-MaPseq), which encodes DMS modifications as mismatches using a thermostable group II intron reverse transcriptase. DMS-MaPseq yields a high signal-to-noise ratio, can report multiple structural features per molecule, and allows both genome-wide studies and focused in vivo investigations of even low-abundance RNAs. We apply DMS-MaPseq for the first analysis of RNA structure within an animal tissue and to identify a functional structure involved in noncanonical translation initiation. Additionally, we use DMS-MaPseq to compare the in vivo structure of pre-mRNAs with their mature isoforms. These applications illustrate DMS-MaPseq's capacity to dramatically expand in vivo analysis of RNA structure.

  12. Water resources data, Iowa, water year 2001, Volume 2. surface water--Missouri River basin, and ground water

    Science.gov (United States)

    Nalley, G.M.; Gorman, J.G.; Goodrich, R.D.; Miller, V.E.; Turco, M.J.; Linhart, S.M.

    2002-01-01

    The Water Resources Division of the U.S. Geological Survey, in cooperation with State, county, municipal, and other Federal agencies, obtains a large amount of data pertaining to the water resources of Iowa each water year. These data, accumulated during many water years, constitute a valuable data base for developing an improved understanding of the water resources of the State. To make this data readily available to interested parties outside of the Geological Survey, the data is published annually in this report series entitled “Water Resources Data - Iowa” as part of the National Water Data System. Water resources data for water year 2001 for Iowa consists of records of stage, discharge, and water quality of streams; stage and contents of lakes and reservoirs; and water levels and water quality of ground water. This report, in two volumes, contains stage or discharge records for 132 gaging stations; stage records for 9 lakes and reservoirs; water-quality records for 4 gaging stations; sediment records for 13 gaging stations; and water levels for 163 ground-water observation wells. Also included are peak-flow data for 92 crest-stage partial-record stations, water-quality data from 86 municipal wells, and precipitation data collected at 6 gaging stations and 2 precipitation sites. Additional water data were collected at various sites not included in the systematic data-collection program, and are published here as miscellaneous measurements and analyses. These data represent that part of the National Water Data System operated by the U.S. Geological Survey and cooperating local, State, and Federal agencies in Iowa.Records of discharge or stage of streams, and contents or stage of lakes and reservoirs were first published in a series of U.S. Geological Survey water-supply papers entitled “Surface Water Supply of the United States.” Through September 30, 1960, these water-supply papers were published in an annual series; during 1961-65 and 1966-70, they

  13. Deuterium content on surface waters VI to X Chile regions

    International Nuclear Information System (INIS)

    Aravena C, R; Pollastri J, A.; Suzuki S, O.

    1984-01-01

    One important parameter on any sitting study for a heavy water plant installation is the deuterium content of the feed water. Deuterium data on surface waters from differents areas located in the south of Chile, are presented. These results allow to idently some potential areas for a future heavy water plant. One of these areas, Lago Llanquihue, was sampled more in detail to study the vertical distribution and spatial variations. (Author)

  14. Possibilities of surface waters monitoring at mining areas using UAV

    Science.gov (United States)

    Lisiecka, Ewa; Motyka, Barbara; Motyka, Zbigniew; Pierzchała, Łukasz; Szade, Adam

    2018-04-01

    The selected, remote measurement methods are discussed, useful for determining surface water properties using mobile unmanned aerial platforms (UAV). The possibilities of using this type of solutions in the scope of measuring spatial, physicochemical and biological parameters of both natural and anthropogenic water reservoirs, including flood polders, water-filled pits, settling tanks and mining sinks were analyzed. Methods of remote identification of the process of overgrowing this type of ecosystems with water and coastal plant formations have also been proposed.

  15. Desert Beetle-Inspired Superwettable Patterned Surfaces for Water Harvesting.

    Science.gov (United States)

    Yu, Zhenwei; Yun, Frank F; Wang, Yanqin; Yao, Li; Dou, Shixue; Liu, Kesong; Jiang, Lei; Wang, Xiaolin

    2017-09-01

    With the impacts of climate change and impending crisis of clean drinking water, designing functional materials for water harvesting from fog with large water capacity has received much attention in recent years. Nature has evolved different strategies for surviving dry, arid, and xeric conditions. Nature is a school for human beings. In this contribution, inspired by the Stenocara beetle, superhydrophilic/superhydrophobic patterned surfaces are fabricated on the silica poly(dimethylsiloxane) (PDMS)-coated superhydrophobic surfaces using a pulsed laser deposition approach with masks. The resultant samples with patterned wettability demonstrate water-harvesting efficiency in comparison with the silica PDMS-coated superhydrophobic surface and the Pt nanoparticles-coated superhydrophilic surface. The maximum water-harvesting efficiency can reach about 5.3 g cm -2 h -1 . Both the size and the percentage of the Pt-coated superhydrophilic square regions on the patterned surface affect the condensation and coalescence of the water droplet, as well as the final water-harvesting efficiency. The present water-harvesting strategy should provide an avenue to alleviate the water crisis facing mankind in certain arid regions of the world. © 2017 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

  16. Ionization by a pulsed plasma surface water

    International Nuclear Information System (INIS)

    Bloyet, E.; Leprince, P.; Marec, J.; Llamas Blasco, M.

    1981-01-01

    The ionization mechanism is studied of a pulsed surface wave generating a microwave discharge. When the plasma is dominated by collisions, it is found that the velocity of the ionization front depends on the ponderomotive force due to the field gradient in the front. (orig.)

  17. Guidelines for surface water quality, vol. l

    International Nuclear Information System (INIS)

    1983-01-01

    A literature survey was carried out on the chemically toxic effects of uranium and uranium compounds on human health, aquatic life, plants and livestock. All the information collected is summarized in this document and, from it, maximum uranium concentrations in water at which toxic effects will not appear are recommended

  18. Water's Interfacial Hydrogen Bonding Structure Reveals the Effective Strength of Surface-Water Interactions.

    Science.gov (United States)

    Shin, Sucheol; Willard, Adam P

    2018-06-05

    We combine all-atom molecular dynamics simulations with a mean field model of interfacial hydrogen bonding to analyze the effect of surface-water interactions on the structural and energetic properties of the liquid water interface. We show that the molecular structure of water at a weakly interacting ( i.e., hydrophobic) surface is resistant to change unless the strength of surface-water interactions are above a certain threshold. We find that below this threshold water's interfacial structure is homogeneous and insensitive to the details of the disordered surface, however, above this threshold water's interfacial structure is heterogeneous. Despite this heterogeneity, we demonstrate that the equilibrium distribution of molecular orientations can be used to quantify the energetic component of the surface-water interactions that contribute specifically to modifying the interfacial hydrogen bonding network. We identify this specific energetic component as a new measure of hydrophilicity, which we refer to as the intrinsic hydropathy.

  19. Basin scale management of surface and ground water

    International Nuclear Information System (INIS)

    Tracy, J.C.; Al-Sharif, M.

    1993-01-01

    An important element in the economic development of many regions of the Great Plains is the availability of a reliable water supply. Due to the highly variable nature of the climate through out much of the Great Plains region, non-controlled stream flow rates tend to be highly variable from year to year. Thus, the primary water supply has tended towards developing ground water aquifers. However, in regions where shallow ground water is extracted for use, there exists the potential for over drafting aquifers to the point of depleting hydraulically connected stream flows, which could adversely affect the water supply of downstream users. To prevent the potential conflict that can arise when a basin's water supply is being developed or to control the water extractions within a developed basin requires the ability to predict the effect that water extractions in one region will have on water extractions from either surface or ground water supplies else where in the basin. This requires the ability to simulate ground water levels and stream flows on a basin scale as affected by changes in water use, land use practices and climatic changes within the basin. The outline for such a basin scale surface water-ground water model has been presented in Tracy (1991) and Tracy and Koelliker (1992), and the outline for the mathematical programming statement to aid in determining the optimal allocation of water on a basin scale has been presented in Tracy and Al-Sharif (1992). This previous work has been combined into a computer based model with graphical output referred to as the LINOSA model and was developed as a decision support system for basin managers. This paper will present the application of the LINOSA surface-ground water management model to the Rattlesnake watershed basin that resides within Ground Water Management District Number 5 in south central Kansas

  20. Effect of water table dynamics on land surface hydrologic memory

    Science.gov (United States)

    Lo, Min-Hui; Famiglietti, James S.

    2010-11-01

    The representation of groundwater dynamics in land surface models has received considerable attention in recent years. Most studies have found that soil moisture increases after adding a groundwater component because of the additional supply of water to the root zone. However, the effect of groundwater on land surface hydrologic memory (persistence) has not been explored thoroughly. In this study we investigate the effect of water table dynamics on National Center for Atmospheric Research Community Land Model hydrologic simulations in terms of land surface hydrologic memory. Unlike soil water or evapotranspiration, results show that land surface hydrologic memory does not always increase after adding a groundwater component. In regions where the water table level is intermediate, land surface hydrologic memory can even decrease, which occurs when soil moisture and capillary rise from groundwater are not in phase with each other. Further, we explore the hypothesis that in addition to atmospheric forcing, groundwater variations may also play an important role in affecting land surface hydrologic memory. Analyses show that feedbacks of groundwater on land surface hydrologic memory can be positive, negative, or neutral, depending on water table dynamics. In regions where the water table is shallow, the damping process of soil moisture variations by groundwater is not significant, and soil moisture variations are mostly controlled by random noise from atmospheric forcing. In contrast, in regions where the water table is very deep, capillary fluxes from groundwater are small, having limited potential to affect soil moisture variations. Therefore, a positive feedback of groundwater to land surface hydrologic memory is observed in a transition zone between deep and shallow water tables, where capillary fluxes act as a buffer by reducing high-frequency soil moisture variations resulting in longer land surface hydrologic memory.

  1. Turbulent flow over an interactive alternating land-water surface

    Science.gov (United States)

    Van Heerwaarden, C.; Mellado, J. P.

    2014-12-01

    The alternating land-water surface is a challenging surface to represent accurately in weather and climate models, but it is of great importance for the surface energy balance in polar regions. The complexity of this surface lies in the fact that secondary circulations, which form at the boundary of water and land, interact strongly with the surface energy balance. Due to its large heat capacity, the water temperature adapts slowly to the flow, thus the properties of the atmosphere determine the uptake of energy from the water. In order to study this complex system in a simpler way, retaining only the most essential physics, we have simplified the full surface energy balance including radiation. We have derived a boundary condition that mimics the full balance and can be formulated as a so-called Robin boundary condition: a linear combination of Dirichlet (fixed temperature) and Neumann (fixed temperature gradient) ones. By spatially varying the coefficients, we are able to express land and water using this boundary condition. We have done a series of direct numerical simulations in which we generate artificial land-water patterns from noise created from a Gaussian spectrum centered around a dominant wave number. This method creates realistic random patterns, but we are still in control of the length scales. We show that the system can manifest itself in three regimes: micro-, meso- and macro-scale. In the micro-scale, we find perfect mixing of the near-surface atmosphere that results in identical air properties over water and land. In the meso-scale, secondary circulations alter the heat exchange considerably by advecting air between land and water. In addition, they bring the surface temperature of the land closer to that of the air, thereby modulating the energy loss due to outgoing longwave radiation. In the macro-scale regime, the flow over land and water become independent of each other and only the large scale forcings determine the energy balance.

  2. Formation pathways of DMSO(2) in the addition channel of the OH-initiated DMS oxidation: A theoretical study.

    Science.gov (United States)

    Ramírez-Anguita, Juan M; González-Lafont, Angels; Lluch, José M

    2009-07-15

    The production of dimethyl sulfoxide (DMSO) and dimethyl sulfone (DMSO(2)) in the dimethyl sulfide (DMS) degradation scheme initiated by the hydroxyl (OH) radical has been shown to be very sensitive to nitrogen oxides (NO(x)) levels. In the present work we have explored the potential energy surfaces corresponding to several reaction pathways which yield DMSO(2) from the CH(3)S(O)(OH)CH(3) adduct [including the formation of CH(3)S(O)(OH)CH(3) from the reaction of DMSO with OH] and the reaction channels that yield DMSO or/and DMSO(2) from the CH(3)S(O(2))(OH)CH(3) adduct are also studied. The formation of the CH(3)S(O(2))(OH)CH(3) adduct from CH(3)S(OH)CH(3) (DMS-OH) and O(2) was analyzed in our previous work. All these pathways due to the presence of NO(x) (NO and NO(2)) and also due to the reactions with O(2), OH and HO(2) are compared with the objective of inferring their kinetic relevance in the laboratory experiments that measure DMSO(2) (and DMSO) formation yields. In particular, our theoretical results clearly show the existence of NO(x)-dependent pathways leading to the formation of DMSO(2), which could explain some of these experimental results in comparison with experimental measurements carried out in NO(x)-free conditions. Our results indicate that the relative importance of the addition channel in the DMS oxidation process can be dependent on the NO(x) content of chamber experiments and of atmospheric conditions. (c) 2008 Wiley Periodicals, Inc.

  3. Cooperativity in Surface Bonding and Hydrogen Bonding of Water and Hydroxyl at Metal Surfaces

    DEFF Research Database (Denmark)

    Schiros, T.; Ogasawara, H.; Naslund, L. A.

    2010-01-01

    of the mixed phase at metal surfaces. The surface bonding can be considered to be similar to accepting a hydrogen bond, and we can thereby apply general cooperativity rules developed for hydrogen-bonded systems. This provides a simple understanding of why water molecules become more strongly bonded...... to the surface upon hydrogen bonding to OH and why the OH surface bonding is instead weakened through hydrogen bonding to water. We extend the application of this simple model to other observed cooperativity effects for pure water adsorption systems and H3O+ on metal surfaces.......We examine the balance of surface bonding and hydrogen bonding in the mixed OH + H2O overlayer on Pt(111), Cu(111), and Cu(110) via density functional theory calculations. We find that there is a cooperativity effect between surface bonding and hydrogen bonding that underlies the stability...

  4. chemical and microbiological assessment of surface water samples

    African Journals Online (AJOL)

    PROF EKWUEME

    were investigated in this study: Nine samples from different surface water bodies, two samples from two effluent sources ... Ezeagu, Udi, Nkanu, Oji River and some parts of Awgu and Aninri ..... Study of Stream Output from Small Catchments.

  5. Exciton-Promoted Desorption From Solid Water Surfaces A2

    DEFF Research Database (Denmark)

    McCoustra, M.R.S.; Thrower, J.D.

    2018-01-01

    Abstract Desorption from solid water surfaces resulting from interaction with electromagnetic and particle radiation is reviewed in the context of the role of nonthermal desorption in astrophysical environments. Experimental observations are interpreted in terms of mechanisms sharing a common basis...

  6. Titanium Dioxide-Based Antibacterial Surfaces for Water Treatment

    Science.gov (United States)

    The field of water disinfection is gaining much interest since waterborne diseases caused by pathogenic microorganisms directly endanger human health. Antibacterial surfaces offer a new, ecofriendly technique to reduce the harmful disinfection byproducts that form in medical and ...

  7. Insight into Chemistry on Cloud/Aerosol Water Surfaces.

    Science.gov (United States)

    Zhong, Jie; Kumar, Manoj; Francisco, Joseph S; Zeng, Xiao Cheng

    2018-05-15

    Cloud/aerosol water surfaces exert significant influence over atmospheric chemical processes. Atmospheric processes at the water surface are observed to follow mechanisms that are quite different from those in the gas phase. This Account summarizes our recent findings of new reaction pathways on the water surface. We have studied these surface reactions using Born-Oppenheimer molecular dynamics simulations. These studies provide useful information on the reaction time scale, the underlying mechanism of surface reactions, and the dynamic behavior of the product formed on the aqueous surface. According to these studies, the aerosol water surfaces confine the atmospheric species into a specific orientation depending on the hydrophilicity of atmospheric species or the hydrogen-bonding interactions between atmospheric species and interfacial water. As a result, atmospheric species are activated toward a particular reaction on the aerosol water surface. For example, the simplest Criegee intermediate (CH 2 OO) exhibits high reactivity toward the interfacial water and hydrogen sulfide, with the reaction times being a few picoseconds, 2-3 orders of magnitude faster than that in the gas phase. The presence of interfacial water molecules induces proton-transfer-based stepwise pathways for these reactions, which are not possible in the gas phase. The strong hydrophobicity of methyl substituents in larger Criegee intermediates (>C1), such as CH 3 CHOO and (CH 3 ) 2 COO, blocks the formation of the necessary prereaction complexes for the Criegee-water reaction to occur at the water droplet surface, which lowers their proton-transfer ability and hampers the reaction. The aerosol water surface provides a solvent medium for acids (e.g., HNO 3 and HCOOH) to participate in reactions via mechanisms that are different from those in the gas and bulk aqueous phases. For example, the anti-CH 3 CHOO-HNO 3 reaction in the gas phase follows a direct reaction between anti-CH 3 CHOO and HNO 3

  8. Differential Mobility Spectrometry-Hydrogen Deuterium Exchange (DMS-HDX) as a Probe of Protein Conformation in Solution.

    Science.gov (United States)

    Zhu, Shaolong; Campbell, J Larry; Chernushevich, Igor; Le Blanc, J C Yves; Wilson, Derek J

    2016-06-01

    Differential mobility spectrometry (DMS) is an ion mobility technique that has been adopted chiefly as a pre-filter for small- to medium-sized analytes (DMS-field asymmetric waveform ion mobility spectroscopy (FAIMS)-the application of DMS to intact biomacromolecules remains largely unexplored. In this work, we employ DMS combined with gas-phase hydrogen deuterium exchange (DMS-HDX) to probe the gas-phase conformations generated from proteins that were initially folded, partially-folded, and unfolded in solution. Our findings indicate that proteins with distinct structural features in solution exhibit unique deuterium uptake profiles as function of their optimal transmission through the DMS. Ultimately we propose that DMS-HDX can, if properly implemented, provide rapid measurements of liquid-phase protein structural stability that could be of use in biopharmaceuticals development. Graphical Abstract ᅟ.

  9. Radiolysis of water in the vicinity of passive surfaces

    International Nuclear Information System (INIS)

    Moreau, S.; Fenart, M.; Renault, J.P.

    2014-01-01

    Highlights: • HO° production through water radiolysis is enhanced near metal surfaces. • Hastelloy and Stainless steel surfaces can also produce HO° radicals through hydrogen peroxide activation. • There is a deficit in solvated electron production compared to hydroxyl radicals near metal surfaces. - Abstract: Porous metals were used to describe the water radiolysis in the vicinity of metal surfaces. The hydroxyl radical production under gamma irradiation was measured by benzoate scavenging in water confined in a 200 nm porous Ni base alloy or in Stainless steel. The presence of the metallic surfaces changed drastically the HO° production level and lifetime. The solvated electron production was measured via glycylglycine scavenging for Stainless steel and was found to be significantly smaller than hydroxyl production. These observations imply that interfacial radiolysis may deeply impact the corrosion behavior of the SS and Ni based alloys

  10. Water evaporation from substrate tooth surface during dentin treatments.

    Science.gov (United States)

    Kusunoki, Mizuho; Itoh, Kazuo; Gokan, Yuka; Nagai, Yoshitaka; Tani, Chihiro; Hisamitsu, Hisashi

    2011-01-01

    The purpose of this study was to evaluate changes in the quantity of water evaporation from tooth surfaces. The amount of water evaporation was measured using Multi probe adapter MPA5 and Tewameter TM300 (Courage+Khazaka Electric GmbH, Köln, Germany) after acid etching and GM priming of enamel; and after EDTA conditioning and GM priming of dentin. The results indicated that the amount of water evaporation from the enamel surface was significantly less than that from the dentin. Acid etching did not affect the water evaporation from enamel, though GM priming significantly decreased the evaporation (83.48 ± 15.14% of that before priming). The evaporation from dentin was significantly increased by EDTA conditioning (131.38 ± 42.08% of that before conditioning) and significantly reduced by GM priming (80.26 ± 7.43% of that before priming). It was concluded that dentin priming reduced water evaporation from the dentin surface.

  11. Unique water-water coordination tailored by a metal surface

    DEFF Research Database (Denmark)

    Schiros, T.; Andersson, Klas Jerker; MacNaughton, J.

    2013-01-01

    (2006)]. Using x-ray absorption spectroscopy we find an anomalous low-energy resonance at ~533.1 eV which, based on density functional theory spectrum simulations, we assign to an unexpected configuration of water units whose uncoordinated O-H bonds directly face those of their neighbors...

  12. Anomalous water dynamics at surfaces and interfaces: synergistic effects of confinement and surface interactions

    Science.gov (United States)

    Biswas, Rajib; Bagchi, Biman

    2018-01-01

    In nature, water is often found in contact with surfaces that are extended on the scale of molecule size but small on a macroscopic scale. Examples include lipid bilayers and reverse micelles as well as biomolecules like proteins, DNA and zeolites, to name a few. While the presence of surfaces and interfaces interrupts the continuous hydrogen bond network of liquid water, confinement on a mesoscopic scale introduces new features. Even when extended on a molecular scale, natural and biological surfaces often have features (like charge, hydrophobicity) that vary on the scale of the molecular diameter of water. As a result, many new and exotic features, which are not seen in the bulk, appear in the dynamics of water close to the surface. These different behaviors bear the signature of both water-surface interactions and of confinement. In other words, the altered properties are the result of the synergistic effects of surface-water interactions and confinement. Ultrafast spectroscopy, theoretical modeling and computer simulations together form powerful synergistic approaches towards an understanding of the properties of confined water in such systems as nanocavities, reverse micelles (RMs), water inside and outside biomolecules like proteins and DNA, and also between two hydrophobic walls. We shall review the experimental results and place them in the context of theory and simulations. For water confined within RMs, we discuss the possible interference effects propagating from opposite surfaces. Similar interference is found to give rise to an effective attractive force between two hydrophobic surfaces immersed and kept fixed at a separation of d, with the force showing an exponential dependence on this distance. For protein and DNA hydration, we shall examine a multitude of timescales that arise from frustration effects due to the inherent heterogeneity of these surfaces. We pay particular attention to the role of orientational correlations and modification of the

  13. A Probabilistic Analysis of Surface Water Flood Risk in London.

    Science.gov (United States)

    Jenkins, Katie; Hall, Jim; Glenis, Vassilis; Kilsby, Chris

    2017-10-30

    Flooding in urban areas during heavy rainfall, often characterized by short duration and high-intensity events, is known as "surface water flooding." Analyzing surface water flood risk is complex as it requires understanding of biophysical and human factors, such as the localized scale and nature of heavy precipitation events, characteristics of the urban area affected (including detailed topography and drainage networks), and the spatial distribution of economic and social vulnerability. Climate change is recognized as having the potential to enhance the intensity and frequency of heavy rainfall events. This study develops a methodology to link high spatial resolution probabilistic projections of hourly precipitation with detailed surface water flood depth maps and characterization of urban vulnerability to estimate surface water flood risk. It incorporates probabilistic information on the range of uncertainties in future precipitation in a changing climate. The method is applied to a case study of Greater London and highlights that both the frequency and spatial extent of surface water flood events are set to increase under future climate change. The expected annual damage from surface water flooding is estimated to be to be £171 million, £343 million, and £390 million/year under the baseline, 2030 high, and 2050 high climate change scenarios, respectively. © 2017 Society for Risk Analysis.

  14. Chlorine stress mediates microbial surface attachment in drinking water systems.

    Science.gov (United States)

    Liu, Li; Le, Yang; Jin, Juliang; Zhou, Yuliang; Chen, Guowei

    2015-03-01

    Microbial attachment to drinking water pipe surfaces facilitates pathogen survival and deteriorates disinfection performance, directly threatening the safety of drinking water. Notwithstanding that the formation of biofilm has been studied for decades, the underlying mechanisms for the origins of microbial surface attachment in biofilm development in drinking water pipelines remain largely elusive. We combined experimental and mathematical methods to investigate the role of environmental stress-mediated cell motility on microbial surface attachment in chlorination-stressed drinking water distribution systems. Results show that at low levels of disinfectant (0.0-1.0 mg/L), the presence of chlorine promotes initiation of microbial surface attachment, while higher amounts of disinfectant (>1.0 mg/L) inhibit microbial attachment. The proposed mathematical model further demonstrates that chlorination stress (0.0-5.0 mg/L)-mediated microbial cell motility regulates the frequency of cell-wall collision and thereby controls initial microbial surface attachment. The results reveal that transport processes and decay patterns of chlorine in drinking water pipelines regulate microbial cell motility and, thus, control initial surface cell attachment. It provides a mechanistic understanding of microbial attachment shaped by environmental disinfection stress and leads to new insights into microbial safety protocols in water distribution systems.

  15. Impact of industrial effluents on surface waters

    International Nuclear Information System (INIS)

    Ahmed, K.

    2000-01-01

    The indiscriminate discharge of untreated municipal and industrial effluents has given rise to serious problems of water pollution and human health in Pakistan. The City of Lahore discharges about 365 mgd of wastewater with a BOD load of 250 tons per day, without treatment, into Ravi river. Because of the untreated industrial discharges, river Ravi is devoid of dissolved oxygen through most of its react between Lahore and Upper Chenab Canal under low flow conditions. Pollution levels can be controlled if each industry treats its own wastewater prior to disposal, in accordance with NEQS (Pakistan). (author)

  16. Recovery from acidification in European surface waters

    Czech Academy of Sciences Publication Activity Database

    Evans, C. D.; Cullen, J. M.; Alewell, C.; Kopáček, Jiří; Marchetto, A.; Moldan, F.; Prechtel, A.; Rogora, M.; Veselý, J.; Wright, R.

    2001-01-01

    Roč. 5, č. 3 (2001), s. 283-297 ISSN 1027-5606 R&D Projects: GA ČR GA206/00/0063 Grant - others:CEC RECOVER(XE) 2010 EVK1-CT-1999-00018; GMER(DE) PT BEO 51-0339476; UKDETR(GB) EPG1/3/92; NNP(NO) SFT2000; CEC(XE) EMERGE EVK1-CT-1999-00032 Keywords : acidification * recovery * sulphate Subject RIV: DJ - Water Pollution ; Quality Impact factor: 1.127, year: 2001

  17. Recovery of acidified European surface waters

    Czech Academy of Sciences Publication Activity Database

    Wright, R. F.; Larssen, T.; Camarero, L.; Cosby, B. J.; Ferrier, R. C.; Helliwell, R.; Forsius, M.; Jenkins, A.; Kopáček, Jiří; Majer, V.; Moldan, F.; Posch, M.; Rogora, M.; Schöpp, W.

    2005-01-01

    Roč. 39, č. 3 (2005), 64A-72A ISSN 0013-936X. [ Acid Rain 2005. International Conference on Acid Deposition /7./. Prague, 12.06.2005-17.06.2005] Grant - others:EC(XE) EMERGE EVK1-CT-1999-00032; EC(XE) RECOVER:2010 EVK1-CT-1999-00018; DEFRA(GB) EPG 1/3/194; ICST(ES) REN2000-0889/GLO Institutional research plan: CEZ:AV0Z60170517 Keywords : acid ification * recovery * European lake districts Subject RIV: DJ - Water Pollution ; Quality Impact factor: 4.054, year: 2005

  18. Adsorption of surface functionalized silica nanoparticles onto mineral surfaces and decane/water interface

    International Nuclear Information System (INIS)

    Metin, Cigdem O.; Baran, Jimmie R.; Nguyen, Quoc P.

    2012-01-01

    The adsorption of silica nanoparticles onto representative mineral surfaces and at the decane/water interface was studied. The effects of particle size (the mean diameters from 5 to 75 nm), concentration and surface type on the adsorption were studied in detail. Silica nanoparticles with four different surfaces [unmodified, surface modified with anionic (sulfonate), cationic (quaternary ammonium (quat)) or nonionic (polyethylene glycol (PEG)) surfactant] were used. The zeta potential of these silica nanoparticles ranges from −79.8 to 15.3 mV. The shape of silica particles examined by a Hitachi-S5500 scanning transmission electron microscope (STEM) is quite spherical. The adsorption of all the nanoparticles (unmodified or surface modified) on quartz and calcite surfaces was found to be insignificant. We used interfacial tension (IFT) measurements to investigate the adsorption of silica nanoparticles at the decane/water interface. Unmodified nanoparticles or surface modified ones with sulfonate or quat do not significantly affect the IFT of the decane/water interface. It also does not appear that the particle size or concentration influences the IFT. However, the presence of PEG as a surface modifying material significantly reduces the IFT. The PEG surface modifier alone in an aqueous solution, without the nanoparticles, yields the same IFT reduction for an equivalent PEG concentration as that used for modifying the surface of nanoparticles. Contact angle measurements of a decane droplet on quartz or calcite plate immersed in water (or aqueous nanoparticle dispersion) showed a slight change in the contact angle in the presence of the studied nanoparticles. The results of contact angle measurements are in good agreement with experiments of adsorption of nanoparticles on mineral surfaces or decane/water interface. This study brings new insights into the understanding and modeling of the adsorption of surface-modified silica nanoparticles onto mineral surfaces and

  19. Methods on estimation of the evaporation from water surface

    International Nuclear Information System (INIS)

    Trajanovska, Lidija; Tanushevska, Dushanka; Aleksovska, Nina

    2001-01-01

    The whole world water supply on the Earth is in close dependence on hydrological cycle connected with water circulation at Earth-Atmosphere route through evaporation, precipitation and water runoff. Evaporation exists worldwide where the atmosphere is unsatiated of water steam (when there is humidity in short supply) and it depends on climatic conditions in some regions. The purpose of this paper is to determine a method for estimation of evaporation of natural water surface in our areas, that means its determination as exact as possible. (Original)

  20. Dynamics of ice nucleation on water repellent surfaces.

    Science.gov (United States)

    Alizadeh, Azar; Yamada, Masako; Li, Ri; Shang, Wen; Otta, Shourya; Zhong, Sheng; Ge, Liehui; Dhinojwala, Ali; Conway, Ken R; Bahadur, Vaibhav; Vinciquerra, A Joseph; Stephens, Brian; Blohm, Margaret L

    2012-02-14

    Prevention of ice accretion and adhesion on surfaces is relevant to many applications, leading to improved operation safety, increased energy efficiency, and cost reduction. Development of passive nonicing coatings is highly desirable, since current antiicing strategies are energy and cost intensive. Superhydrophobicity has been proposed as a lead passive nonicing strategy, yet the exact mechanism of delayed icing on these surfaces is not clearly understood. In this work, we present an in-depth analysis of ice formation dynamics upon water droplet impact on surfaces with different wettabilities. We experimentally demonstrate that ice nucleation under low-humidity conditions can be delayed through control of surface chemistry and texture. Combining infrared (IR) thermometry and high-speed photography, we observe that the reduction of water-surface contact area on superhydrophobic surfaces plays a dual role in delaying nucleation: first by reducing heat transfer and second by reducing the probability of heterogeneous nucleation at the water-substrate interface. This work also includes an analysis (based on classical nucleation theory) to estimate various homogeneous and heterogeneous nucleation rates in icing situations. The key finding is that ice nucleation delay on superhydrophobic surfaces is more prominent at moderate degrees of supercooling, while closer to the homogeneous nucleation temperature, bulk and air-water interface nucleation effects become equally important. The study presented here offers a comprehensive perspective on the efficacy of textured surfaces for nonicing applications.

  1. How to repel hot water from a superhydrophobic surface?

    KAUST Repository

    Yu, Zhejun; Yang, Jieyi; Wan, Fang; Ge, Quan; Yang, Longlai; Ding, Zunliang; Yang, Dequan; Sacher, Edward R.; Isimjan, Tayirjan T.

    2014-01-01

    Superhydrophobic surfaces, with water contact angles greater than 150° and slide angles less than 10°, have attracted a great deal of attention due to their self-cleaning ability and excellent water-repellency. It is commonly accepted that a

  2. Heavy Metals Pollution on Surface Water Sources in Kaduna ...

    African Journals Online (AJOL)

    This study examine the effects of heavy metal pollutants to aquatic ecosystems and the environment by considering the role of urban, municipal, agricultural, industrial and other anthropogenic processes as sources of heavy metal pollution in surface water sources of Kaduna metropolis. Samples of the polluted water were ...

  3. Pesticides distribution in surface waters and sediments of lotic and ...

    African Journals Online (AJOL)

    An investigation on the availability and distribution of Lindane (HCHs) and Total organochlorine phosphate (TOCP) in the surface waters and sediments of selected water bodies in Agbede wetlands was carried out from December, 2012 to May, 2014 in order to cover seasonal trends in both matrixes. A Gas Chromatograph ...

  4. Macro-invertebrate decline in surface water polluted with imidacloprid

    NARCIS (Netherlands)

    van Dijk, T.; van Staalduinen, M.A.; van der Sluijs, J.P.|info:eu-repo/dai/nl/073427489

    Imidacloprid is one of the most widely used insecticides in the world. Its concentration in surface water exceeds the water quality norms in many parts of the Netherlands. Several studies have demonstrated harmful effects of this neonicotinoid to a wide range of non-target species. Therefore we

  5. 0-6686 : improving DMS 9210 requirements for limestone rock asphalt : [project summary].

    Science.gov (United States)

    2013-08-01

    Limestone rock asphalt (LRA) mixtures have : been produced and placed for several decades : using specification requirements currently listed : under DMS 9210, Limestone Rock Asphalt (LRA). : Several Texas Department of Transportation : (TxDOT) distr...

  6. Exploring travelers' behavior in response to dynamic message signs (DMS) using a driving simulator.

    Science.gov (United States)

    2013-10-01

    This research studies the effectiveness of a dynamic message sign (DMS) using a driving : simulator. Over 100 subjects from different socio-economic and age groups were recruited to : drive the simulator under different traffic and driving conditions...

  7. Exploring travelers' behavior in response to dynamic message signs (DMS) using a driving simulator : final report.

    Science.gov (United States)

    2013-10-01

    This research studies the effectiveness of a dynamic message sign (DMS) using a driving : simulator. Over 100 subjects from different socio-economic and age groups were recruited to : drive the simulator under different traffic and driving conditions...

  8. Structure of the bacterial community in a biofilter during dimethyl sulfide (DMS) removal processes.

    Science.gov (United States)

    Chung, Ying-Chien; Cheng, Chiu-Yu; Chen, Tzu-Yu; Hsu, Jo-Shan; Kui, Chun-Chi

    2010-09-01

    We report here both the successful treatment of DMS in a biofilter and the dynamic changes that occur in the composition of the bacterial community of the biofilter during this process. Denaturing gradient gel electrophoresis of eubacterial 16S rDNA samples taken from packing material at different DMS removal stages revealed 11 distinct bands. Phylogenetic analysis showed that the sequences of these bands were closest to sequences of species of the Proteobacteria, Firmicutes, and Actinobacteria. The specific occurrence of these bacterial species varied mainly with DMS load, but it was also affected by the addition of glucose and by ambient temperature. Based on the characteristics of the identified species, the system is conducive for such processes as sulfur oxidation, sulfate reduction, carbon oxidation, and fermentation. The strains identified in this study are potential candidates for purifying waste gas effluents containing DMS gas. Copyright 2010 Elsevier Ltd. All rights reserved.

  9. Production and consumption of dimethylsulfide (DMS) and dimethylsulfoniopropionate (DMSP) in a diatom dominated intertidal sediment

    NARCIS (Netherlands)

    Van Bergeijk, S.A.; Schönefeldt, K.; Stal, L.J.; Huisman, J.

    2002-01-01

    Intertidal sediments usually contain a high amount of dimethylsulfoniopropionate (DMSP) and therefore represent environments with a potentially high emission of dimethylsulfide (DMS). However, knowledge on production and release of DMSP in intertidal sediments is limited. Here, we present data on

  10. Do the organic sulfur compounds DMSP and DMS drive coral microbial associations?

    Science.gov (United States)

    Raina, Jean-Baptiste; Dinsdale, Elizabeth A; Willis, Bette L; Bourne, David G

    2010-03-01

    Dimethylsulfoniopropionate (DMSP) and dimethylsulfide (DMS) are key compounds in the global sulfur cycle. Moreover, DMS is particularly important in climate regulation owing to its role in cloud formation. Reef building corals are major contributors to the production of these two compounds and also form diverse and complex associations with bacteria, which are known to play a crucial role in the degradation of DMSP and DMS. Here, we highlight an extensive overlap between bacterial species implicated in DMSP/DMS degradation and those associated with corals, leading to the hypothesis that these two compounds play a major role in structuring coral-associated bacterial communities, with important consequences for coral health and the resilience of coral reefs. We also explore the publically available metagenome databases and show that genes implicated in DMSP metabolism are abundant in the viral component of coral-reef-derived metagenomes, indicating that viruses can act as a reservoir for such genes.

  11. Improving DMS 9210 requirements for limestone rock asphalt : year one interim report.

    Science.gov (United States)

    2013-05-01

    Limestone Rock Asphalt (LRA) mixtures have been produced and placed for several decades using specification requirements currently listed under DMS 9210. Several Districts have had placement issues and premature failures at the beginning of 2010. The...

  12. Rapid surface-water volume estimations in beaver ponds

    Science.gov (United States)

    Karran, Daniel J.; Westbrook, Cherie J.; Wheaton, Joseph M.; Johnston, Carol A.; Bedard-Haughn, Angela

    2017-02-01

    Beaver ponds are surface-water features that are transient through space and time. Such qualities complicate the inclusion of beaver ponds in local and regional water balances, and in hydrological models, as reliable estimates of surface-water storage are difficult to acquire without time- and labour-intensive topographic surveys. A simpler approach to overcome this challenge is needed, given the abundance of the beaver ponds in North America, Eurasia, and southern South America. We investigated whether simple morphometric characteristics derived from readily available aerial imagery or quickly measured field attributes of beaver ponds can be used to approximate surface-water storage among the range of environmental settings in which beaver ponds are found. Studied were a total of 40 beaver ponds from four different sites in North and South America. The simplified volume-area-depth (V-A-h) approach, originally developed for prairie potholes, was tested. With only two measurements of pond depth and corresponding surface area, this method estimated surface-water storage in beaver ponds within 5 % on average. Beaver pond morphometry was characterized by a median basin coefficient of 0.91, and dam length and pond surface area were strongly correlated with beaver pond storage capacity, regardless of geographic setting. These attributes provide a means for coarsely estimating surface-water storage capacity in beaver ponds. Overall, this research demonstrates that reliable estimates of surface-water storage in beaver ponds only requires simple measurements derived from aerial imagery and/or brief visits to the field. Future research efforts should be directed at incorporating these simple methods into both broader beaver-related tools and catchment-scale hydrological models.

  13. An Ontology Design Pattern for Surface Water Features

    Energy Technology Data Exchange (ETDEWEB)

    Sinha, Gaurav [Ohio University; Mark, David [University at Buffalo (SUNY); Kolas, Dave [Raytheon BBN Technologies; Varanka, Dalia [U.S. Geological Survey, Rolla, MO; Romero, Boleslo E [University of California, Santa Barbara; Feng, Chen-Chieh [National University of Singapore; Usery, Lynn [U.S. Geological Survey, Rolla, MO; Liebermann, Joshua [Tumbling Walls, LLC; Sorokine, Alexandre [ORNL

    2014-01-01

    Surface water is a primary concept of human experience but concepts are captured in cultures and languages in many different ways. Still, many commonalities can be found due to the physical basis of many of the properties and categories. An abstract ontology of surface water features based only on those physical properties of landscape features has the best potential for serving as a foundational domain ontology. It can then be used to systematically incor-porate concepts that are specific to a culture, language, or scientific domain. The Surface Water ontology design pattern was developed both for domain knowledge distillation and to serve as a conceptual building-block for more complex surface water ontologies. A fundamental distinction is made in this on-tology between landscape features that act as containers (e.g., stream channels, basins) and the bodies of water (e.g., rivers, lakes) that occupy those containers. Concave (container) landforms semantics are specified in a Dry module and the semantics of contained bodies of water in a Wet module. The pattern is imple-mented in OWL, but Description Logic axioms and a detailed explanation is provided. The OWL ontology will be an important contribution to Semantic Web vocabulary for annotating surface water feature datasets. A discussion about why there is a need to complement the pattern with other ontologies, es-pecially the previously developed Surface Network pattern is also provided. Fi-nally, the practical value of the pattern in semantic querying of surface water datasets is illustrated through a few queries and annotated geospatial datasets.

  14. Nonzero Ideal Gas Contribution to the Surface Tension of Water.

    Science.gov (United States)

    Sega, Marcello; Fábián, Balázs; Jedlovszky, Pál

    2017-06-15

    Surface tension, the tendency of fluid interfaces to behave elastically and minimize their surface, is routinely calculated as the difference between the lateral and normal components of the pressure or, invoking isotropy in momentum space, of the virial tensor. Here we show that the anisotropy of the kinetic energy tensor close to a liquid-vapor interface can be responsible for a large part of its surface tension (about 15% for water, independent from temperature).

  15. WebDMS: A Web-Based Data Management System for Environmental Data

    Science.gov (United States)

    Ekstrand, A. L.; Haderman, M.; Chan, A.; Dye, T.; White, J. E.; Parajon, G.

    2015-12-01

    DMS is an environmental Data Management System to manage, quality-control (QC), summarize, document chain-of-custody, and disseminate data from networks ranging in size from a few sites to thousands of sites, instruments, and sensors. The server-client desktop version of DMS is used by local and regional air quality agencies (including the Bay Area Air Quality Management District, the South Coast Air Quality Management District, and the California Air Resources Board), the EPA's AirNow Program, and the EPA's AirNow-International (AirNow-I) program, which offers countries the ability to run an AirNow-like system. As AirNow's core data processing engine, DMS ingests, QCs, and stores real-time data from over 30,000 active sensors at over 5,280 air quality and meteorological sites from over 130 air quality agencies across the United States. As part of the AirNow-I program, several instances of DMS are deployed in China, Mexico, and Taiwan. The U.S. Department of State's StateAir Program also uses DMS for five regions in China and plans to expand to other countries in the future. Recent development has begun to migrate DMS from an onsite desktop application to WebDMS, a web-based application designed to take advantage of cloud hosting and computing services to increase scalability and lower costs. WebDMS will continue to provide easy-to-use data analysis tools, such as time-series graphs, scatterplots, and wind- or pollution-rose diagrams, as well as allowing data to be exported to external systems such as the EPA's Air Quality System (AQS). WebDMS will also provide new GIS analysis features and a suite of web services through a RESTful web API. These changes will better meet air agency needs and allow for broader national and international use (for example, by the AirNow-I partners). We will talk about the challenges and advantages of migrating DMS to the web, modernizing the DMS user interface, and making it more cost-effective to enhance and maintain over time.

  16. Development of the DMS (2) (double MS: modular simplified and medium small reactor). Plant layout and construction for the DMS

    International Nuclear Information System (INIS)

    Shizuka Hirako; Yuusuke Shimizu; Shigeru Yokouchi; Yoshinori Iimura; Kumiaki Moriya; Takahiko Hida

    2005-01-01

    Nuclear power is expected to become the main source of electric power generation in Japan for reasons of energy security and prevention of CO 2 emissions. In addition, the recent slowdown of electric power demand and the liberalization of the electric power market are accelerating medium and small sized reactor development. Under these circumstances, DMS's (modular simplified and medium small reactors) have been developed as 400MWe class LWR's supported by the Japan Atomic Power Company. In the development of medium and small sized reactors, the most important point is how to overcome the scale demerits. To this end, we have pursued not only the simplification of systems and equipment but also the standardization of layout and construction. The main technical feature of DMS's is the adoption of a natural circulation reactor with short length fuel. Short length fuel enables the reduction of RPV height as well as construction volume of the PCV and building volume. A natural circulation reactor has considerable rationalizing effects such as the elimination of re-circulation pumps and their drive power source. By applying simplified systems and equipment, a rationalized layout and construction method are adopted. To improve the construct ability by means of modular construction methods, steel containment is applied. The PCV size is reduced to 17m in diameter and 24m in height by applying a dish-shaped drywell and eccentric RPV arrangement. By applying a compact PCV and concentrated equipment arrangement in building, it can be confirmed that the ratio of building volume per unit power is equivalent to that of existing large sized ABWRs. Furthermore, a steel plate reinforced concrete structure (SC structure) is applied to the building layout. The application of the compact PCV (steel containment) and the SC structure makes it easier to apply a large-scale module, such as an integrated steel containment and SC structure module, and an integrated multi-layer BM (building

  17. Practical aspects of tritium measurement in ground and surface waters

    Energy Technology Data Exchange (ETDEWEB)

    Nitzsche, O [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Angewandte Physik; Hebert, D [Technische Univ. Bergakademie Freiberg (Germany). Inst. fuer Angewandte Physik

    1997-03-01

    Tritium measurements are a powerful tool in hydrological and hydrogeological investigations for detecting mean residence times of several water reservoirs. Due to the low tritium activities in precipitation, ground and surface waters a low level measurement is necessary. Therefore often the liquid scintillation counting after an electrolytic enrichment of water is used. In this paper some practical aspects and problems of measurement are discussed and the problem of contamination in low level laboratories is shown. (orig.)

  18. Influence of Road Surface Microtexture on Thin Water Film Traction

    OpenAIRE

    BEAUTRU , Yannick; Kane , Malal; Do , Minh Tan; Cerezo , Véronique

    2012-01-01

    This paper deals with the contribution of road surface microtexture to the relationship between tire/road friction and water depth. The main objectives are the estimation of local water depths trapped at the tire/road interface and the definition of a critical water depth which can be used for driver assistance and information systems. Tests are performed in laboratory. Specimens are slabs made of asphalt concrete and mosaics composed of coarse aggregates. The aggregate mosaics are sandblaste...

  19. Water slip and friction at a solid surface

    Energy Technology Data Exchange (ETDEWEB)

    Brigo, L; Pierno, M; Mammano, F; Sada, C; Fois, G; Pozzato, A; Zilio, S dal; Mistura, G [Dipartimento di Fisica G Galilei, Universita degli Studi di Padova, via Marzolo 8, 35131 Padova (Italy); Natali, M [Istituto di Chimica Inorganica e delle Superfici (ICIS), CNR, Corso Stati Uniti 4, 35127 Padova (Italy); Tormen, M [TASC-INFM, CNR, S S 14 km 163.5 Area Science Park, 34012 Basovizza, Trieste (Italy)], E-mail: mistura@padova.infm.it

    2008-09-03

    A versatile micro-particle imaging velocimetry ({mu}-PIV) recording system is described, which allows us to make fluid velocity measurements in a wide range of flow conditions both inside microchannels and at liquid-solid interfaces by using epifluorescence and total internal reflection fluorescence excitation. This set-up has been applied to study the slippage of water over flat surfaces characterized by different degrees of hydrophobicity and the effects that a grooved surface has on the fluid flow inside a microchannel. Preliminary measurements of the slip length of water past various flat surfaces show no significant dependence on the contact angle.

  20. Stormwater Priority Pollutants Versus Surface Water Quality Criteria

    DEFF Research Database (Denmark)

    Eriksson, Eva; Ledin, Anna; Baun, Anders

    2011-01-01

    Stormwater in urban areas comprises of a substantial part of the urban water cycle, dominating the flow in many small urban streams, and the pollution levels are sizeable. No stormwater quality criteria were found here and no European or national emission limit values exist. Stormwater pollutants...... however are present in levels exceeding most of the regulated surface water quality criteria and environmental quality standards. Therefore catchment characterisation is needed to chose suitable treatment prior to discharge into receiving surface waters, as the mixing may be insufficient in small streams....

  1. Context of surveillance of underground and surface waters

    International Nuclear Information System (INIS)

    2010-01-01

    This document briefly describes the evolutions of regulations on site liquid effluents and of guideline values concerning radioactive wastes, briefly presents the surveillance of underground and surface waters of CEA sites, comments the guideline values of the radiological quality of waters aimed at human consumption, and gives an overview of information which are brought to public's attention. Then, for different CEA sites (Cadarache, Marcoule, Saclay, Grenoble, Fontenay-aux-Roses, Valduc, DIF), this document proposes a presentation of the hydrological context, regulatory context, the surface and underground water surveillance process and values, the storing zones of old wastes

  2. Space Station Freedom (SSF) Data Management System (DMS) performance model data base

    Science.gov (United States)

    Stovall, John R.

    1993-01-01

    The purpose of this document was originally to be a working document summarizing Space Station Freedom (SSF) Data Management System (DMS) hardware and software design, configuration, performance and estimated loading data from a myriad of source documents such that the parameters provided could be used to build a dynamic performance model of the DMS. The document is published at this time as a close-out of the DMS performance modeling effort resulting from the Clinton Administration mandated Space Station Redesign. The DMS as documented in this report is no longer a part of the redesigned Space Station. The performance modeling effort was a joint undertaking between the National Aeronautics and Space Administration (NASA) Johnson Space Center (JSC) Flight Data Systems Division (FDSD) and the NASA Ames Research Center (ARC) Spacecraft Data Systems Research Branch. The scope of this document is limited to the DMS core network through the Man Tended Configuration (MTC) as it existed prior to the 1993 Clinton Administration mandated Space Station Redesign. Data is provided for the Standard Data Processors (SDP's), Multiplexer/Demultiplexers (MDM's) and Mass Storage Units (MSU's). Planned future releases would have added the additional hardware and software descriptions needed to describe the complete DMS. Performance and loading data through the Permanent Manned Configuration (PMC) was to have been included as it became available. No future releases of this document are presently planned pending completion of the present Space Station Redesign activities and task reassessment.

  3. The Proposed Surface Water and Ocean Topography (SWOT) Mission

    Science.gov (United States)

    Fu, Lee-Lueng; Alsdorf, Douglas; Rodriguez, Ernesto; Morrow, Rosemary; Mognard, Nelly; Vaze, Parag; Lafon, Thierry

    2012-01-01

    A new space mission concept called Surface Water and Ocean Topography (SWOT) is being developed jointly by a collaborative effort of the international oceanographic and hydrological communities for making high-resolution measurement of the water elevation of both the ocean and land surface water to answer the questions about the oceanic submesoscale processes and the storage and discharge of land surface water. The key instrument payload would be a Ka-band radar interferometer capable of making high-resolution wide-swath altimetry measurement. This paper describes the proposed science objectives and requirements as well as the measurement approach of SWOT, which is baselined to be launched in 2019. SWOT would demonstrate this new approach to advancing both oceanography and land hydrology and set a standard for future altimetry missions.

  4. Polarization Patterns of Transmitted Celestial Light under Wavy Water Surfaces

    Directory of Open Access Journals (Sweden)

    Guanhua Zhou

    2017-03-01

    Full Text Available This paper presents a model to describe the polarization patterns of celestial light, which includes sunlight and skylight, when refracted by wavy water surfaces. The polarization patterns and intensity distribution of refracted light through the wave water surface were calculated. The model was validated by underwater experimental measurements. The experimental and theoretical values agree well qualitatively. This work provides a quantitative description of the repolarization and transmittance of celestial light transmitted through wave water surfaces. The effects of wind speed and incident sources on the underwater refraction polarization patterns are discussed. Scattering skylight dominates the polarization patterns while direct solar light is the dominant source of the intensity of the underwater light field. Wind speed has an influence on disturbing the patterns under water.

  5. The influence of lithology on surface water sources | Science ...

    Science.gov (United States)

    Understanding the temporal and spatial variability of surface water sources within a basin is vital to our ability to manage the impacts of climate variability and land cover change. Water stable isotopes can be used as a tool to determine geographic and seasonal sources of water at the basin scale. Previous studies in the Coastal Range of Oregon reported that the variation in the isotopic signatures of surface water does not conform to the commonly observed “rainout effect”, which exhibits a trend of increasing isotopic depletion with rising elevation. The primary purpose of this research is to investigate the mechanisms governing seasonal and spatial variations in the isotopic signature of surface waters within the Marys River Basin, located in the leeward side of the Oregon Coastal Range. Surface water and precipitation samples were collected every 2-3 weeks for isotopic analysis of δ18O and δ2H for one year. Results indicate a significant difference in isotopic signature between watersheds underlain by basalt and sandstone. The degree of separation was the most distinct during the summer when low flows reflect deeper groundwater sources, whereas isotopic signatures during the rainy season (fall and winter) showed a greater degree of similarity between the two lithologies. This indicates that baseflow within streams drained by sandstone versus basalt is being supplied from two distinctly separate water sources. In addition, Marys River flow at the outle

  6. Salinization and arsenic contamination of surface water in southwest Bangladesh.

    Science.gov (United States)

    Ayers, John C; George, Gregory; Fry, David; Benneyworth, Laura; Wilson, Carol; Auerbach, Leslie; Roy, Kushal; Karim, Md Rezaul; Akter, Farjana; Goodbred, Steven

    2017-09-11

    To identify the causes of salinization and arsenic contamination of surface water on an embanked island (i.e., polder) in the tidal delta plain of SW Bangladesh we collected and analyzed water samples in the dry (May) and wet (October) seasons in 2012-2013. Samples were collected from rice paddies (wet season), saltwater ponds used for brine shrimp aquaculture (dry season), freshwater ponds and tidal channels (both wet and dry season), and rainwater collectors. Continuous measurements of salinity from March 2012 to February 2013 show that tidal channel water increases from ~0.15 ppt in the wet season up to ~20 ppt in the dry season. On the polder, surface water exceeds the World Health Organization drinking water guideline of 10 μg As/L in 78% of shrimp ponds and 27% of rice paddies, raising concerns that produced shrimp and rice could have unsafe levels of As. Drinking water sources also often have unsafe As levels, with 83% of tubewell and 43% of freshwater pond samples having >10 μg As/L. Water compositions and field observations are consistent with shrimp pond water being sourced from tidal channels during the dry season, rather than the locally saline groundwater from tubewells. Irrigation water for rice paddies is also obtained from the tidal channels, but during the wet season when surface waters are fresh. Salts become concentrated in irrigation water through evaporation, with average salinity increasing from 0.43 ppt in the tidal channel source to 0.91 ppt in the rice paddies. Our observations suggest that the practice of seasonally alternating rice and shrimp farming in a field has a negligible effect on rice paddy water salinity. Also, shrimp ponds do not significantly affect the salinity of adjacent surface water bodies or subjacent groundwater because impermeable shallow surface deposits of silt and clay mostly isolate surface water bodies from each other and from the shallow groundwater aquifer. Bivariate plots of conservative element

  7. Using IR Imaging of Water Surfaces for Estimating Piston Velocities

    Science.gov (United States)

    Gålfalk, M.; Bastviken, D.; Arneborg, L.

    2013-12-01

    The transport of gasses dissolved in surface waters across the water-atmosphere interface is controlled by the piston velocity (k). This coefficient has large implications for, e.g., greenhouse gas fluxes but is challenging to quantify in situ. At present, empirical k-wind speed relationships from a small number of studies and systems are often extrapolated without knowledge of model performance. It is therefore of interest to search for new methods for estimating k, and to compare the pros and cons of existing and new methods. Wind speeds in such models are often measured at a height of 10 meters. In smaller bodies of water such as lakes, wind speeds can vary dramatically across the surface through varying degrees of wind shadow from e.g. trees at the shoreline. More local measurements of the water surface, through wave heights or surface motion mapping, could give improved k-estimates over a surface, also taking into account wind fetch. At thermal infrared (IR) wavelengths water has very low reflectivity (depending on viewing angle) than can go below 1%, meaning that more than 99% is heat radiation giving a direct measurement of surface temperature variations. Using an IR camera at about 100 frames/s one could map surface temperature structures at a fraction of a mm depth even with waves present. In this presentation I will focus on IR imaging as a possible tool for estimating piston velocities. Results will be presented from IR field measurements, relating the motions of surface temperature structures to k calculated from other simultaneous measurements (flux chamber and ADV-Based Dissipation Rate), but also attempting to calculate k directly from the IR surface divergence. A relation between wave height and k will also be presented.

  8. Issues of the presence of parasitic protozoa in surface waters

    Science.gov (United States)

    Hawrylik, Eliza

    2018-02-01

    Parasitic protozoa are very numerous organisms in the environment that play an important role in the spread of water-borne diseases. Water-borne epidemics caused by parasitic protozoa are noted throughout the world. Within these organisms, intestinal protozoa of the genera Cryptosporidium and Giardia are ones of the most serious health hazards for humans. This paper focuses on the problem of the presence of parasitic protozoa in surface waters. Characteristics of the most frequently recognized pathogens responsible for water-borne outbreaks were described, as well as sources of contamination and surface waters contamination due to protozoa of the genus Cryptosporidium and Giardia were presented. The methods of destroying the cysts and oocysts of parasitic protozoa used nowadays in the world were also presented in a review.

  9. Productions of Volatile Organic Compounds (VOCs) in Surface Waters from Reactions with Atmospheric Ozone

    Science.gov (United States)

    Hopkins, Frances; Bell, Thomas; Yang, Mingxi

    2017-04-01

    Ozone (O3) is a key atmospheric oxidant, greenhouse gas and air pollutant. In marine environments, some atmospheric ozone is lost by reactions with aqueous compounds (e.g. dissolved organic material, DOM, dimethyl sulfide, DMS, and iodide) near the sea surface. These reactions also lead to formations of volatile organic compounds (VOCs). Removal of O3 by the ocean remains a large uncertainty in global and regional chemical transport models, hampering coastal air quality forecasts. To better understand the role of the ocean in controlling O3 concentrations in the coastal marine atmosphere, we designed and implemented a series of laboratory experiments whereby ambient surface seawater was bubbled with O3-enriched, VOC-free air in a custom-made glass bubble equilibration system. Gas phase concentrations of a range of VOCs were monitored continuously over the mass range m/z 33 - 137 at the outflow of the bubble equilibrator by a proton transfer reaction - mass spectrometer (PTR-MS). Gas phase O3 was also measured at the input and output of the equilibrator to monitor the uptake due to reactions with dissolved compounds in seawater. We observed consistent productions of a variety of VOCs upon reaction with O3, notably isoprene, aldehydes, and ketones. Aqueous DMS is rapidly removed from the reactions with O3. To test the importance of dissolved organic matter precursors, we added increasing (milliliter) volumes of Emiliania huxleyi culture to the equilibrator filled with aged seawater, and observed significant linear increases in gas phase concentrations of a number of VOCs. Reactions between DOM and O3 at the sea-air interface represent a potentially significant source of VOCs in marine air and a sink of atmospheric O3.

  10. Reaction of water vapor with a clean liquid uranium surface

    International Nuclear Information System (INIS)

    Siekhaus, W.

    1985-01-01

    To study the reaction of water vapor with uranium, we have exposed clean liquid uranium surfaces to H 2 O under UHV conditions. We have measured the surface concentration of oxygen as a function of exposure, and determined the maximum attainable surface oxygen concentration X 0 /sup s/ as a function of temperature. We have used these measurements to estimate, close to the melting point, the solubility of oxygen (X 0 /sup b/, -4 ) and its surface segregation coefficient β/sup s/(> 10 3 ). 8 refs., 5 figs., 1 tab

  11. Molecular Dynamics Simulations of Water Nanodroplets on Silica Surfaces

    DEFF Research Database (Denmark)

    Zambrano, Harvey A; Walther, Jens Honore; Jaffe, Richard L.

    2009-01-01

    and DNA microarrays technologies.4,5,6,7,8 Although extensive experimental, theoretical and computational work has been devoted to study the nature of the interaction between silica and water,2,9-16 at the molecular level a complete understanding of silica-water systems has not been reached. Contact angle...... computations of water droplets on silica surfaces offers a useful fundamental and quantitative measurement in order to study chemical and physical properties of water-silica systems.3,16,17,18 For hydrophobic systems the static and dynamic properties of the fluid-solid interface are influenced by the presence...

  12. Impacts of thermal and chemical discharges to surface water

    International Nuclear Information System (INIS)

    Stober, Q.J.

    1974-01-01

    Various aspects of thermal and chemical discharges to surface water are outlined. The major impacts of nuclear power plants on aquatic resources are disruption during construction, intake of cooling water, discharge problems, and interactions with other water users. The following topics are included under the heading, assessment of aquatic ecology: identification of flora and fauna; abundance of aquatic organisms; species-environment relationships; and identification of pre-existing environmental stress. The following topics are included under the heading, environmental effects of plant operation: entrapment of fish by cooling water; passage of plankton through cooling system; discharge area and thermal plume; chemical effluents; and plant construction. (U.S.)

  13. Possibilities of surface waters monitoring at mining areas using UAV

    Directory of Open Access Journals (Sweden)

    Lisiecka Ewa

    2018-01-01

    Full Text Available The selected, remote measurement methods are discussed, useful for determining surface water properties using mobile unmanned aerial platforms (UAV. The possibilities of using this type of solutions in the scope of measuring spatial, physicochemical and biological parameters of both natural and anthropogenic water reservoirs, including flood polders, water-filled pits, settling tanks and mining sinks were analyzed. Methods of remote identification of the process of overgrowing this type of ecosystems with water and coastal plant formations have also been proposed.

  14. Hydraulics and drones: observations of water level, bathymetry and water surface velocity from Unmanned Aerial Vehicles

    DEFF Research Database (Denmark)

    Bandini, Filippo

    -navigable rivers and overpass obstacles (e.g. river structures). Computer vision, autopilot system and beyond visual line-of-sight (BVLOS) flights will ensure the possibility to retrieve hyper-spatial observations of water depth, without requiring the operator to access the area. Surface water speed can......The planet faces several water-related threats, including water scarcity, floods, and pollution. Satellite and airborne sensing technology is rapidly evolving to improve the observation and prediction of surface water and thus prevent natural disasters. While technological developments require....... Although UAV-borne measurements of surface water speed have already been documented in the literature, a novel approach was developed to avoid GCPs. This research is the first demonstration that orthometric water level can be measured from UAVs with a radar system and a GNSS (Global Navigation Satellite...

  15. Surface water classification and monitoring using polarimetric synthetic aperture radar

    Science.gov (United States)

    Irwin, Katherine Elizabeth

    Surface water classification using synthetic aperture radar (SAR) is an established practice for monitoring flood hazards due to the high temporal and spatial resolution it provides. Surface water change is a dynamic process that varies both spatially and temporally, and can occur on various scales resulting in significant impacts on affected areas. Small-scale flooding hazards, caused by beaver dam failure, is an example of surface water change, which can impact nearby infrastructure and ecosystems. Assessing these hazards is essential to transportation and infrastructure maintenance. With current satellite missions operating in multiple polarizations, spatio-temporal resolutions, and frequencies, a comprehensive comparison between SAR products for surface water monitoring is necessary. In this thesis, surface water extent models derived from high resolution single-polarization TerraSAR-X (TSX) data, medium resolution dual-polarization TSX data and low resolution quad-polarization RADARSAT-2 (RS-2) data are compared. There exists a compromise between acquiring SAR data with a high resolution or high information content. Multi-polarization data provides additional phase and intensity information, which makes it possible to better classify areas of flooded vegetation and wetlands. These locations are often where fluctuations in surface water occur and are essential for understanding dynamic underlying processes. However, often multi-polarized data is acquired at a low resolution, which cannot image these zones effectively. High spatial resolution, single-polarization TSX data provides the best model of open water. However, these single-polarization observations have limited information content and are affected by shadow and layover errors. This often hinders the classification of other land cover types. The dual-polarization TSX data allows for the classification of flooded vegetation, but classification is less accurate compared to the quad-polarization RS-2 data

  16. Lawrence Livermore National Laboratory Surface Water Protection: A Watershed Approach

    Energy Technology Data Exchange (ETDEWEB)

    Coty, J

    2009-03-16

    This surface water protection plan (plan) provides an overview of the management efforts implemented at Lawrence Livermore National Laboratory (LLNL) that support a watershed approach to protect surface water. This plan fulfills a requirement in the Department of Energy (DOE) Order 450.1A to demonstrate a watershed approach for surface water protection that protects the environment and public health. This plan describes the use of a watershed approach within which the Laboratory's current surface water management and protections efforts have been structured and coordinated. With more than 800 million acres of land in the U.S. under federal management and stewardship, a unified approach across agencies provides enhanced resource protection and cost-effectiveness. The DOE adopted, along with other federal agencies, the Unified Federal Policy for a Watershed Approach to Federal Land and Resource Management (UFP) with a goal to protect water quality and aquatic ecosystems on federal lands. This policy intends to prevent and/or reduce water pollution from federal activities while fostering a cost-effective watershed approach to federal land and resource management. The UFP also intends to enhance the implementation of existing laws (e.g., the Clean Water Act [CWA] and National Environmental Policy Act [NEPA]) and regulations. In addition, this provides an opportunity for the federal government to serve as a model for water quality stewardship using a watershed approach for federal land and resource activities that potentially impact surface water and its uses. As a federal land manager, the Laboratory is responsible for a small but important part of those 800 million acres of land. Diverse land uses are required to support the Laboratory's mission and provide an appropriate work environment for its staff. The Laboratory comprises two sites: its main site in Livermore, California, and the Experimental Test Site (Site 300), near Tracy, California. The main site

  17. The significant surface-water connectivity of "geographically isolated wetlands"

    Science.gov (United States)

    Calhoun, Aram J.K.; Mushet, David M.; Alexander, Laurie C.; DeKeyser, Edward S.; Fowler, Laurie; Lane, Charles R.; Lang, Megan W.; Rains, Mark C.; Richter, Stephen; Walls, Susan

    2017-01-01

    We evaluated the current literature, coupled with our collective research expertise, on surface-water connectivity of wetlands considered to be “geographically isolated” (sensu Tiner Wetlands 23:494–516, 2003a) to critically assess the scientific foundation of grouping wetlands based on the singular condition of being surrounded by uplands. The most recent research on wetlands considered to be “geographically isolated” shows the difficulties in grouping an ecological resource that does not reliably indicate lack of surface water connectivity in order to meet legal, regulatory, or scientific needs. Additionally, the practice of identifying “geographically isolated wetlands” based on distance from a stream can result in gross overestimates of the number of wetlands lacking ecologically important surface-water connections. Our findings do not support use of the overly simplistic label of “geographically isolated wetlands”. Wetlands surrounded by uplands vary in function and surface-water connections based on wetland landscape setting, context, climate, and geographic region and should be evaluated as such. We found that the “geographically isolated” grouping does not reflect our understanding of the hydrologic variability of these wetlands and hence does not benefit conservation of the Nation’s diverse wetland resources. Therefore, we strongly discourage use of categorizations that provide overly simplistic views of surface-water connectivity of wetlands fully embedded in upland landscapes.

  18. Properties of water surface discharge at different pulse repetition rates

    International Nuclear Information System (INIS)

    Ruma,; Yoshihara, K.; Hosseini, S. H. R.; Sakugawa, T.; Akiyama, H.; Akiyama, M.; Lukeš, P.

    2014-01-01

    The properties of water surface discharge plasma for variety of pulse repetition rates are investigated. A magnetic pulse compression (MPC) pulsed power modulator able to deliver pulse repetition rates up to 1000 Hz, with 0.5 J per pulse energy output at 25 kV, was used as the pulsed power source. Positive pulse with a point-to-plane electrode configuration was used for the experiments. The concentration and production yield of hydrogen peroxide (H 2 O 2 ) were quantitatively measured and orange II organic dye was treated, to evaluate the chemical properties of the discharge reactor. Experimental results show that the physical and chemical properties of water surface discharge are not influenced by pulse repetition rate, very different from those observed for under water discharge. The production yield of H 2 O 2 and degradation rate per pulse of the dye did not significantly vary at different pulse repetition rates under a constant discharge mode on water surface. In addition, the solution temperature, pH, and conductivity for both water surface and underwater discharge reactors were measured to compare their plasma properties for different pulse repetition rates. The results confirm that surface discharge can be employed at high pulse repetition rates as a reliable and advantageous method for industrial and environmental decontamination applications.

  19. Water redistribution at the soil surface : ponding and surface runoff in flat areas

    NARCIS (Netherlands)

    Appels, W.M.

    2013-01-01

    In The Netherlands, one of the most important targets for the improvement of surface water quality as aimed for in the European Water Framework Directive, is the reduction of nutrient concentrations (both nitrogen and phosphorus). To identify the most suitable and effective measures for reducing the

  20. Foulant characteristics comparison in recycling cooling water system makeup by municipal reclaimed water and surface water in power plant.

    Science.gov (United States)

    Ping, Xu; Jing, Wang; Yajun, Zhang; Jie, Wang; Shuai, Si

    2015-01-01

    Due to water shortage, municipal reclaimed water rather than surface water was replenished into recycling cooling water system in power plants in some cities in China. In order to understand the effects of the measure on carbon steel corrosion, characteristics of two kinds of foulant produced in different systems were studied in the paper. Differences between municipal reclaimed water and surface water were analyzed firstly. Then, the weight and the morphology of two kinds of foulant were compared. Moreover, other characteristics including the total number of bacteria, sulfate reducing bacteria, iron bacteria, extracellular polymeric substance (EPS), protein (PN), and polysaccharide (PS) in foulant were analyzed. Based on results, it could be concluded that microbial and corrosive risk would be increased when the system replenished by municipal reclaimed water instead of surface water.

  1. Hydrologic Science and Satellite Measurements of Surface Water (Invited)

    Science.gov (United States)

    Alsdorf, D. E.; Mognard, N. M.; Lettenmaier, D. P.

    2010-12-01

    While significant advances continue to be made for satellite measurements of surface waters, important science and application opportunities remain. Examples include the following: (1) Our current methods of measuring floodwater dynamics are either sparsely distributed or temporally inadequate. As an example, flood depths are measured by using high water marks, which capture only the peak of the flood wave, not its temporal variability. (2) Discharge is well measured at individual points along stream networks using in-situ gauges, but these do not capture within-reach hydraulic variability such as the water surface slope changes on the rising and falling limbs of flood waves. (3) Just a 1.0 mm/day error in ET over the Congo Basin translates to a 35,000 m3/s discharge error. Knowing the discharge of the Congo River and its many tributaries should significantly improve our understanding of the water balance throughout the basin. The Congo is exemplary of many other basins around the globe. (4) Arctic hydrology is punctuated by millions of unmeasured lakes. Globally, there might be as many as 30 million lakes larger than a hectare. Storage changes in these lakes are nearly unknown, but in the Arctic such changes are likely an indication of global warming. (5) Well over 100 rivers cross international boundaries, yet the sharing of water data is poor. Overcoming this helps to better manage the entire river basin while also providing a better assessment of potential water related disasters. The Surface Water and Ocean Topography (SWOT, http://swot.jpl.nasa.gov/) mission is designed to meet these needs by providing global measurements of surface water hydrodynamics. SWOT will allow estimates of discharge in rivers wider than 100m (50m goal) and storage changes in water bodies larger than 250m by 250m (and likely as small as one hectare).

  2. Impact of Water Recovery from Wastes on the Lunar Surface Mission Water Balance

    Science.gov (United States)

    Fisher, John W.; Hogan, John Andrew; Wignarajah, Kanapathipi; Pace, Gregory S.

    2010-01-01

    Future extended lunar surface missions will require extensive recovery of resources to reduce mission costs and enable self-sufficiency. Water is of particular importance due to its potential use for human consumption and hygiene, general cleaning, clothes washing, radiation shielding, cooling for extravehicular activity suits, and oxygen and hydrogen production. Various water sources are inherently present or are generated in lunar surface missions, and subject to recovery. They include: initial water stores, water contained in food, human and other solid wastes, wastewaters and associated brines, ISRU water, and scavenging from residual propellant in landers. This paper presents the results of an analysis of the contribution of water recovery from life support wastes on the overall water balance for lunar surface missions. Water in human wastes, metabolic activity and survival needs are well characterized and dependable figures are available. A detailed life support waste model was developed that summarizes the composition of life support wastes and their water content. Waste processing technologies were reviewed for their potential to recover that water. The recoverable water in waste is a significant contribution to the overall water balance. The value of this contribution is discussed in the context of the other major sources and loses of water. Combined with other analyses these results provide guidance for research and technology development and down-selection.

  3. Macroelements in the surface microlayer of water of urban ponds

    Directory of Open Access Journals (Sweden)

    Antonowicz Józef Piotr

    2016-03-01

    Full Text Available Analyses were conducted concerning the accumulation of four metals representing the group of macroelements, i.e. sodium, potassium, calcium and magnesium in two ponds located in the city of Słupsk. Water samples for chemical analyses were collected from the surface microlayer using a Garrett net. At the same time subsurface water samples were collected. Concentrations of metals were determined using a mass spectrometer. Generally, amounts of sodium, potassium, calcium and magnesium were similar in surface microlayer and subsurface water. Only in the case of potassium and calcium was low enrichment observed in the surface microlayer in one pond, while the greatest extent for magnesium enrichment was observed in the spring period.

  4. Wavefront modulation of water surface wave by a metasurface

    International Nuclear Information System (INIS)

    Sun Hai-Tao; Cheng Ying; Liu Xiao-Jun; Wang Jing-Shi

    2015-01-01

    We design a planar metasurface to modulate the wavefront of a water surface wave (WSW) on a deep sub-wavelength scale. The metasurface is composed of an array of coiling-up-space units with specially designed parameters, and can take on the work of steering the wavefront when it is pierced into water. Like their acoustic counterparts, the modulation of WSW is ascribed to the gradient phase shift of the coiling-up-space units, which can be perfectly tuned by changing the coiling plate length and channel number inside the units. According to the generalized Snell’s law, negative refraction and ‘driven’ surface mode of WSW are also demonstrated at certain incidences. Specially, the transmitted WSW could be efficiently guided out by linking a symmetrically-corrugated channel in ‘driven’ surface mode. This work may have potential applications in water wave energy extraction and coastal protection. (paper)

  5. Modeling decadal timescale interactions between surface water and ground water in the central Everglades, Florida, USA

    Science.gov (United States)

    Harvey, Judson W.; Newlin, Jessica T.; Krupa, Steven L.

    2006-04-01

    Surface-water and ground-water flow are coupled in the central Everglades, although the remoteness of this system has hindered many previous attempts to quantify interactions between surface water and ground water. We modeled flow through a 43,000 ha basin in the central Everglades called Water Conservation Area 2A. The purpose of the model was to quantify recharge and discharge in the basin's vast interior areas. The presence and distribution of tritium in ground water was the principal constraint on the modeling, based on measurements in 25 research wells ranging in depth from 2 to 37 m. In addition to average characteristics of surface-water flow, the model parameters included depth of the layer of 'interactive' ground water that is actively exchanged with surface water, average residence time of interactive ground water, and the associated recharge and discharge fluxes across the wetland ground surface. Results indicated that only a relatively thin (8 m) layer of the 60 m deep surfical aquifer actively exchanges surface water and ground water on a decadal timescale. The calculated storage depth of interactive ground water was 3.1 m after adjustment for the porosity of peat and sandy limestone. Modeling of the tritium data yielded an average residence time of 90 years in interactive ground water, with associated recharge and discharge fluxes equal to 0.01 cm d -1. 3H/ 3He isotopic ratio measurements (which correct for effects of vertical mixing in the aquifer with deeper, tritium-dead water) were available from several wells, and these indicated an average residence time of 25 years, suggesting that residence time was overestimated using tritium measurements alone. Indeed, both residence time and storage depth would be expected to be overestimated due to vertical mixing. The estimate of recharge and discharge (0.01 cm d -1) that resulted from tritium modeling therefore is still considered reliable, because the ratio of residence time and storage depth (used to

  6. Particle dry deposition to water surfaces: Processes and consequences

    DEFF Research Database (Denmark)

    Pryor, S.C.; Barthelmie, R.J.

    2000-01-01

    flux to coastal waters, atmosphere-surface exchange represents a significant component of the total flux and may be particularly critical during the summertime when both the riverine input and ambient nutrient concentrations are often at a minimum. In this chapter, we present an overview...... of the physical and chemical processes which dictate the quantity (and direction) of atmosphere-surface fluxes of trace chemicals to (and above) water surfaces with particular emphasis on the role of particles. Dry deposition (transfer to the surface in the absence of precipitation) of particles is determined...... efforts to simulate and measure fluxes close to the coastline. These arise in part from the complexity of atmospheric flow in this region where energy and chemical fluxes are highly inhomogeneous in space and time and thermally generated atmospheric circulations are commonplace. (C) 2000 Elsevier Science...

  7. Molecular Dynamics Studies of Overbased Detergents on a Water Surface.

    Science.gov (United States)

    Bodnarchuk, M S; Dini, D; Heyes, D M; Breakspear, A; Chahine, S

    2017-07-25

    Molecular dynamics (MD) simulations are reported of model overbased detergent nanoparticles on a model water surface which mimic their behavior on a Langmuir trough or large water droplet in engine oil. The simulations predict that the structure of the nanoparticle on a water surface is different to when it is immersed in a bulk hydrophobic solvent. The surfactant tails are partly directed out of the water, while the carbonate core maximizes its extent of contact with the water. Umbrella sampling calculations of the potential of mean force between two particles showed that they are associated with varying degrees with a maximum binding free energy of ca. 10 k B T for the salicylate stabilized particle, ca. 8 k B T for a sulfurized alkyl phenate stabilized particle, and ca. 5 k B T for a sulfonate stabilized particle. The differences in the strength of attraction depend on the proximity of nearest approach and the energy penalty associated with the disruption of the hydration shell of water molecules around the calcium carbonate core when the two particles approach. This is greatest for the sulfonate particle, which partially loses the surfactant ions to the solution, and least for the salicylate, which forms the weakest water "cage". The particles are separated by a water hydration layer, even at the point of closest approach.

  8. Spring and surface water quality of the Cyprus ophiolites

    Directory of Open Access Journals (Sweden)

    C. Neal

    2002-01-01

    Full Text Available A survey of surface, spring and borehole waters associated with the ophiolite rocks of Cyprus shows five broad water types (1 Mg-HCO3, (2 Na-SO4-Cl-HCO3, (3 Na-Ca-Cl-SO4-OH-CO3, (4 Na-Cl-SO4 and (5 Ca-SO4. The waters represent a progression in chemical reactivity from surface waters that evolve within a groundwater setting due to hydrolysis of the basic/ultrabasic rock as modified by CO2-weathering. An increase in salinity is also observed which is due to mixing with a saline end-member (modified sea-water and dissolution of gypsum/anhydrite. In some cases, the waters have pH values greater than 11. Such high values are associated with low temperature serpentinisation reactions. The system is a net sink for CO2. This feature is related not only to the hydrolysis of the primary minerals in the rock, but also to CaCO3 or Ca-Mg-CO3 solubility controls. Under hyperalkaline conditions, virtually all the carbon dioxide is lost from the water due to the sufficiently high calcium levels and carbonate buffering is then insignificant. Calcium sulphate solubility controls may also be operative when calcium and sulphate concentrations are particularly high. Keywords: Cyprus, Troodos, ophiolite, serpentinisation, spring, stream, water quality, bromide, iodine, boron, trace elements, hyperalkaline.

  9. Modification of surface properties of LLDPE by water plasma discharge

    International Nuclear Information System (INIS)

    Chantara Thevy Ratnam; Hill, D.J.T.; Firas Rasoul; Whittaker, A.K.; Imelda Keen

    2007-01-01

    Linear low density polyethylene (LLDPE) surface was modified by water plasma treatment. The LLDPE surface was treated at 10 and 20 W discharge power at various exposure times. A laboratory scale Megatherm radio frequency (RF) plasma apparatus that operates at 27 MHz was used to generate the water plasmas. The changes in chemical structure of the LLDPE polymeric chain upon plasma treatment were characterized by FTIR and XPS techniques. The selectivity of trifluoroacetic anhydride (TFAA) toward hydroxyl groups is used to quantify the hydroxyl groups formed on the polymer surface upon plasma treatment. After exposition to the plasma discharge a decline in water contact angle were observed. FTIR and XPS measurements indicate an oxidation of degraded polymeric chains and creation of hydroxyl, carbonyl, ether, ester and carboxyl groups. Chemical derivatization with TFAA of water plasma treated polymer surfaces has shown that under the conditions employed, a very small (less than 5%) of the oxygen introduced by the water plasma treatment was present as hydroxyl group. (Author)

  10. Characteristics of pulse corona discharge over water surface

    Science.gov (United States)

    Fujii, Tomio; Arao, Yasushi; Rea, Massimo

    2008-12-01

    Production of ozone and OH radical is required to advance the plasma chemical reactions in the NOx removal processes for combustion gas treatment. The corona discharge to the water surface is expected to induce the good conditions for the proceeding of the NO oxidation and the NO2 dissolution removal into water. In order to get the fundamental data of the corona discharge over the water surface, the positive and negative V-I characteristics and the ozone production were measured with the multi needle and the saw-edge type of the discharge electrodes. The pulse corona characteristics were also measured with some different waveforms of the applied pulse voltage. The experiments were carried out under the atmospheric pressure and room temperature. Both the DC and the pulse corona to the water surface showed a stable and almost the same V-I characteristics as to plate electrodes though the surface of water was waved by corona wind. The positive streamer corona showed more ozone production than the negative one both in the DC and in the pulse corona.

  11. Modeling global distribution of agricultural insecticides in surface waters

    International Nuclear Information System (INIS)

    Ippolito, Alessio; Kattwinkel, Mira; Rasmussen, Jes J.; Schäfer, Ralf B.; Fornaroli, Riccardo; Liess, Matthias

    2015-01-01

    Agricultural insecticides constitute a major driver of animal biodiversity loss in freshwater ecosystems. However, the global extent of their effects and the spatial extent of exposure remain largely unknown. We applied a spatially explicit model to estimate the potential for agricultural insecticide runoff into streams. Water bodies within 40% of the global land surface were at risk of insecticide runoff. We separated the influence of natural factors and variables under human control determining insecticide runoff. In the northern hemisphere, insecticide runoff presented a latitudinal gradient mainly driven by insecticide application rate; in the southern hemisphere, a combination of daily rainfall intensity, terrain slope, agricultural intensity and insecticide application rate determined the process. The model predicted the upper limit of observed insecticide exposure measured in water bodies (n = 82) in five different countries reasonably well. The study provides a global map of hotspots for insecticide contamination guiding future freshwater management and conservation efforts. - Highlights: • First global map on insecticide runoff through modelling. • Model predicts upper limit of insecticide exposure when compared to field data. • Water bodies in 40% of global land surface may be at risk of adverse effects. • Insecticide application rate, terrain slope and rainfall main drivers of exposure. - We provide the first global map on insecticide runoff to surface water predicting that water bodies in 40% of global land surface may be at risk of adverse effects

  12. Characteristics of pulse corona discharge over water surface

    International Nuclear Information System (INIS)

    Fujii, Tomio; Arao, Yasushi; Rea, Massimo

    2008-01-01

    Production of ozone and OH radical is required to advance the plasma chemical reactions in the NOx removal processes for combustion gas treatment. The corona discharge to the water surface is expected to induce the good conditions for the proceeding of the NO oxidation and the NO 2 dissolution removal into water. In order to get the fundamental data of the corona discharge over the water surface, the positive and negative V-I characteristics and the ozone production were measured with the multi needle and the saw-edge type of the discharge electrodes. The pulse corona characteristics were also measured with some different waveforms of the applied pulse voltage. The experiments were carried out under the atmospheric pressure and room temperature. Both the DC and the pulse corona to the water surface showed a stable and almost the same V-I characteristics as to plate electrodes though the surface of water was waved by corona wind. The positive streamer corona showed more ozone production than the negative one both in the DC and in the pulse corona.

  13. Determination of the photolysis rate coefficient of monochlorodimethyl sulfide (MClDMS) in the atmosphere and its implications for the enhancement of SO2 production from the DMS + Cl2 reaction.

    Science.gov (United States)

    Copeland, G; Lee, E P F; Williams, R G; Archibald, A T; Shallcross, D E; Dyke, J M

    2014-01-01

    In this work, the photolysis rate coefficient of CH3SCH2Cl (MClDMS) in the lower atmosphere has been determined and has been used in a marine boundary layer (MBL) box model to determine the enhancement of SO2 production arising from the reaction DMS + Cl2. Absorption cross sections measured in the 28000-34000 cm(-1) region have been used to determine photolysis rate coefficients of MClDMS in the troposphere at 10 solar zenith angles (SZAs). These have been used to determine the lifetimes of MClDMS in the troposphere. At 0° SZA, a photolysis lifetime of 3-4 h has been obtained. The results show that the photolysis lifetime of MClDMS is significantly smaller than the lifetimes with respect to reaction with OH (≈ 4.6 days) and with Cl atoms (≈ 1.2 days). It has also been shown, using experimentally derived dissociation energies with supporting quantum-chemical calculations, that the dominant photodissocation route of MClDMS is dissociation of the C-S bond to give CH3S and CH2Cl. MBL box modeling calculations show that buildup of MClDMS at night from the Cl2 + DMS reaction leads to enhanced SO2 production during the day. The extra SO2 arises from photolysis of MClDMS to give CH3S and CH2Cl, followed by subsequent oxidation of CH3S.

  14. Studies Concerning Water-Surface Deposits in Recovery Boilers

    Energy Technology Data Exchange (ETDEWEB)

    Strandberg, O; Arvesen, J; Dahl, L

    1971-11-15

    The Feed-water Committee of the Stiftelsen Svensk Cellulosaforskning (Foundation for Swedish Cellulose Research) has initiated research and investigations which aim to increase knowledge about water-surface deposits in boiler tubes, and the resulting risks of gas-surface corrosion in chemical recovery boilers (sulphate pulp industry). The Committee has arranged with AB Atomenergi, Studsvik, for investigations into the water-surface deposits on tubes from six Scandinavian boilers. These investigations have included direct measurements of the thermal conductivity of the deposits, and determinations of their quantity, thickness and structure have been carried out. Previous investigations have shown that gas-surface corrosion can occur at tube temperatures above 330 deg C. The measured values for the thermal conductivity of the deposits indicate that even with small quantities of deposit (c. 1 g/dm2 ) and a moderate boiler pressure (40 atm), certain types of deposit can give rise to the above-mentioned surface temperature, at which the risk of gas-surface corrosion becomes appreciable. For higher boiler pressures the risk is great even with a minimal layer of deposit. The critical deposit thickness can be as low as 0.1 mm

  15. Surface water management at a mixed waste remediation site

    International Nuclear Information System (INIS)

    Schlotzhauer, D.S.; Warbritton, K.R.

    1991-01-01

    The Weldon Spring Remedial Action Project (WSSRAP) deals with chemical and radiological contaminants. MK-Ferguson Company is managing the project under contract with the US Department of Energy. Remedial activities include demolishing buildings, constructing material storage and staging areas, excavating and consolidating waste materials, and treating and disposing of the materials in a land disposal facility. Due to the excavation and construction required during remediation, a well-planned surface water management system is essential. Planning involves characterization of source areas and surface water transport mechanisms and identification of applicable regulations. System components include: erosion control sediment control, flow attenuation, and management of contaminated water. Combinations of these components may be utilized during actual construction and remediation to obtain optimum control. Monitoring is performed during implementation in order to assess the effectiveness of control measures. This management scheme provides for comprehensive management of surface water at this site by providing control and/or treatment to appropriate standards. Although some treatment methodologies for contaminated water are specific to site contaminants, this comprehensive program provides a management approach which is applicable to many remedial projects in order to minimize contaminant release and meet Clean Water Act requirements

  16. Water and nutrient budgets at field and regional scale : travel times of drainage water and nutrient loads to surface water

    NARCIS (Netherlands)

    Eertwegh, van den G.A.P.H.

    2002-01-01

    Keywords : water and nutrient budget, travel time of drainage water, dual-porosity concept, agricultural nutrient losses, loads to surface water, field-scale experiments, regional-scale

  17. Delay of turbulent by surface heating in water

    International Nuclear Information System (INIS)

    Arakeri, V.H.

    1980-01-01

    Boundary layer flow visualization studies in water on a 1.5 cal tangent ogive body with surface heating are reported. Existing laminar boundary layer separation was observed to be eliminated with sufficient surface heating. In addition, transition location was observed to be significantly delayed. With surface temperature difference of about 27 0 C no disturbances in the boundary layer could be detected up to (X/D) = 2.5 as compared to observed transition at about (X/D) = 1.32 under slightly heated conditions. Present observations are found to be in agreement with the theoretical computations of Wazzan et al. in a qualitative sense. (orig.)

  18. Nanofiltration in Transforming Surface Water into Healthy Water: Comparison with Reverse Osmosis

    Directory of Open Access Journals (Sweden)

    L. D. Naidu

    2015-01-01

    Full Text Available The natural surface water, especially available through rivers, is the main source of healthy water for the living beings throughout the world from ancient days as it consists of all essential minerals. With the advent of industrialization, gradually even the most prominent rivers have been polluted in all parts of the world. Although there are lots of technologies, nanofiltration (NF has been chosen to transform river water into healthy water due to its unique advantages of retaining optimum TDS (with essential minerals required for human body, consuming of lower energy, and no usage of any chemicals. The prominent parameters of surface water and macro/microminerals of treated water have been analyzed. It is shown that NF is better in producing healthy water with high flux by consuming low energy.

  19. Treatment of waste gas containing low concentration of dimethyl sulphide (DMS) in a bench-scale biofilter.

    Science.gov (United States)

    Giri, B S; Mudliar, S N; Deshmukh, S C; Banerjee, S; Pandey, R A

    2010-04-01

    Biological treatment of dimethyl sulphide (DMS) was investigated in a bench-scale biofilter, packed with compost along with wood chips, and enriched with DMS degrading microorganism Bacillus sphaericus. The biofilter could remove 62-74% of the inlet DMS, at an optimum loading of 0.484 g/m(3)/h with optimum empty bed contact time (EBCT) of 384 s and an average moisture range of 65-70%. The biodegradative products of DMS were sulphide, thiosulphate and sulphate. Evaluation of microbiological status of the biofilter indicated the presence of other bacterial cultures viz. Paenibacillus polymyxa, and Bacillus megaterium, besides B. sphaericus. Copyright 2009 Elsevier Ltd. All rights reserved.

  20. Molecular Dynamics Simulations of Water Droplets On Hydrophilic Silica Surfaces

    DEFF Research Database (Denmark)

    Zambrano, Harvey A; Walther, Jens Honore; Jaffe, Richard L.

    2009-01-01

    and DNA microarrays technologies.Although extensive experimental, theoretical and computational work has been devoted to study the nature of the interaction between silica and water, at the molecular level a complete understanding of silica-water systems has not been reached. Contact angle computations...... dynamics (MD) simulations of a hydrophilic air-water-silica system using the MD package FASTTUBE. We employ quantum chemistry calculation to obtain air-silica interaction parameters for the simulations. Our simulations are based in the following force fields: i) The silica-silica interaction is based...... of water droplets on silica surfaces offers a useful fundamental and quantitative measurement in order to study chemical and physical properties of water-silica systems. For hydrophobic systems the static and dynamic properties of the fluid-solid interface are influenced by the presence of air. Hence...

  1. Theoretical Study of Sodium-Water Surface Reaction Mechanism

    Science.gov (United States)

    Kikuchi, Shin; Kurihara, Akikazu; Ohshima, Hiroyuki; Hashimoto, Kenro

    Computational study of the sodium-water reaction at the gas (water) - liquid (sodium) interface has been carried out using the ab initio (first-principle) method. A possible reaction channel has been identified for the stepwise OH bond dissociations of a single water molecule. The energetics including the binding energy of a water molecule on the sodium surface, the activation energies of the bond cleavages, and the reaction energies, have been evaluated, and the rate constants of the first and second OH bond-breakings have been compared. It was found that the estimated rate constant of the former was much larger than the latter. The results are the basis for constructing the chemical reaction model used in a multi-dimensional sodium-water reaction code, SERAPHIM, being developed by Japan Atomic Energy Agency (JAEA) toward the safety assessment of the steam generator (SG) in a sodium-cooled fast reactor (SFR).

  2. Theoretical study of sodium-water surface reaction mechanism

    International Nuclear Information System (INIS)

    Kikuchi, Shin; Kurihara, Akikazu; Ohshima, Hiroyuki; Hashimoto, Kenro

    2012-01-01

    Computational study of the sodium-water reaction at the gas (water) - liquid (sodium) interface has been carried out using the ab initio (first-principle) method. A possible reaction channel has been identified for the stepwise OH bond dissociations of a single water molecule. The energetics including the binding energy of a water molecule on the sodium surface, the activation energies of the bond cleavages, and the reaction energies, have been evaluated, and the rate constants of the first and second OH bond-breakings have been compared. It was found that the estimated rate constant of the former was much larger than the latter. The results are the basis for constructing the chemical reaction model used in a multi-dimensional sodium-water reaction code, SERAPHIM, being developed by Japan Atomic Energy Agency (JAEA) toward the safety assessment of the steam generator (SG) in a sodium-cooled fast reactor (SFR). (author)

  3. 1D Compressibility of DMS Treated With Cement-GGBS Blend

    Directory of Open Access Journals (Sweden)

    Kaliannan Suaathi

    2017-01-01

    Full Text Available Great quantities of dredged marine soils (DMS have been produced from the maintenance of channels, anchorages and for harbour development. DMS have the potential to pose ecological and human health risks and it is also considered as a geowaste. Malaysia is moving towards the sustainability approach and one of the key factors to achieve it is to reduce waste. Thus, this geowaste should be generated as a new resource to substitute soil for civil works such as for land reclamation and backfilling. This shows the improved settlement of consolidation in treated DMS. DMS is referred to as a cohesive soil which includes clayey silt, sandy clay, silty clay and organic clay. This type of soil has low strength and high compressibility. The objectives were achieved through literature review analysis and also laboratory test which was one dimensional oedometer test. On the other hand, treated DMS with more ground granulated blast furnace slag (GGBS gives a lower settlement compared to specimen with higher percentage of cement in a treated soil. Thus this shows that cement content can be reduced in soil solidification when GGBS is added. The optimum binder ratio found was 3:7 where 3 is cement and 7 is GGBS.

  4. DMS cyclone separation processes for optimization of plastic wastes recycling and their implications.

    Science.gov (United States)

    Gent, Malcolm Richard; Menendez, Mario; Toraño, Javier; Torno, Susana

    2011-06-01

    It is demonstrated that substantial reductions in plastics presently disposed of in landfills can be achieved by cyclone density media separation (DMS). In comparison with the size fraction of plastics presently processed by industrial density separations (generally 6.4 to 9.5 mm), cyclone DMS methods are demonstrated to effectively process a substantially greater range of particle sizes (from 0.5 up to 120 mm). The purities of plastic products and recoveries obtained with a single stage separation using a cylindrical cyclone are shown to attain virtually 100% purity and recoveries >99% for high-density fractions and >98% purity and recoveries were obtained for low-density products. Four alternative schemas of multi-stage separations are presented and analyzed as proposed methods to obtain total low- and high-density plastics fraction recoveries while maintaining near 100% purities. The results of preliminary tests of two of these show that the potential for processing product purities and recoveries >99.98% of both density fractions are indicated. A preliminary economic comparison of capital costs of DMS systems suggests cyclone DMS methods to be comparable with other DMS processes even if the high volume capacity for recycling operations of these is not optimized.

  5. Impacts of transportation infrastructure on storm water and surfaces waters in Chittenden County, Vermont, USA.

    Science.gov (United States)

    2014-06-01

    Transportation infrastructure is a major source of stormwater runoff that can alter hydrology and : contribute significant loading of nutrients, sediment, and other pollutants to surface waters. These : increased loads can contribute to impairment of...

  6. Surface Water Data at Los Alamos National Laboratory 1998 Water Year

    International Nuclear Information System (INIS)

    Shaull, D.A.; Alexander, M.R.; Reynolds, R.P.; McLean, C.T.; Romero, R.P.

    1999-01-01

    The principal investigators collected and computed surface water discharge data from 19 stream-gaging stations that cover most of Los Alamos National Laboratory. Also included are discharge data from three springs that flow into Caiion de Vane

  7. Water and oil wettability of anodized 6016 aluminum alloy surface

    Science.gov (United States)

    Rodrigues, S. P.; Alves, C. F. Almeida; Cavaleiro, A.; Carvalho, S.

    2017-11-01

    This paper reports on the control of wettability behaviour of a 6000 series aluminum (Al) alloy surface (Al6016-T4), which is widely used in the automotive and aerospace industries. In order to induce the surface micro-nanostructuring of the surface, a combination of prior mechanical polishing steps followed by anodization process with different conditions was used. The surface polishing with sandpaper grit size 1000 promoted aligned grooves on the surface leading to static water contact angle (WCA) of 91° and oil (α-bromonaphthalene) contact angle (OCA) of 32°, indicating a slightly hydrophobic and oleophilic character. H2SO4 and H3PO4 acid electrolytes were used to grow aluminum oxide layers (Al2O3) by anodization, working at 15 V/18° C and 100 V/0 °C, respectively, in one or two-steps configuration. Overall, the anodization results showed that the structured Al surfaces were hydrophilic and oleophilic-like with both WCA and OCA below 90°. The one-step configuration led to a dimple-shaped Al alloy surface with small diameter of around 31 nm, in case of H2SO4, and with larger diameters of around 223 nm in case of H3PO4. The larger dimples achieved with H3PO4 electrolyte allowed to reach a slight hydrophobic surface. The thicker porous Al oxide layers, produced by anodization in two-step configuration, revealed that the liquids can penetrate easily inside the non-ordered porous structures and, thus, the surface wettability tended to superhydrophilic and superoleophilic character (CA OCA. This inversion in favour of the hydrophilic-oleophobic surface behaviour is of great interest either for lubrication of mechanical components or in water-oil separation process.

  8. Biphilic Surfaces for Enhanced Water Collection from Humid Air

    Science.gov (United States)

    Benkoski, Jason; Gerasopoulos, Konstantinos; Luedeman, William

    Surface wettability plays an important role in water recovery, distillation, dehumidification, and heat transfer. The efficiency of each process depends on the rate of droplet nucleation, droplet growth, and mass transfer. Unfortunately, hydrophilic surfaces are good at nucleation but poor at shedding. Hydrophobic surfaces are the reverse. Many plants and animals overcome this tradeoff through biphilic surfaces with patterned wettability. For example, the Stenocara beetle uses hydrophilic patches on a superhydrophobic background to collect fog from air. Cribellate spiders similarly collect fog on their webs through periodic spindle-knot structures. In this study, we investigate the effects of wettability patterns on the rate of water collection from humid air. The steady state rate of water collection per unit area is measured as a function of undercooling, angle of inclination, water contact angle, hydrophilic patch size, patch spacing, area fraction, and patch height relative to the hydrophobic background. We then model each pattern by comparing the potential and kinetic energy of a droplet as it rolls downwards at a fixed angle. The results indicate that the design rules for collecting fog differ from those for condensation from humid air. The authors gratefully acknowledge the Office of Naval Research for financial support through Grant Number N00014-15-1-2107.

  9. Hydrobiological constraints of trace metals in surface water, coastal ...

    African Journals Online (AJOL)

    SERVER

    2007-10-18

    Oct 18, 2007 ... of Calabar River are presented in Tables 1, 2 and 3. Table 4, 5 and 6 present the correlation matrices for sediment, surface water and N. lotus samples respec- tively, showing values of Pearson's correlation coefficient. (p<0.05, n=4) for pairs of heavy metals at the four locations. The concentrations of As, Cd, ...

  10. Surface water risk assessment of pesticides in Ethiopia

    NARCIS (Netherlands)

    Teklu, B.M.; Adriaanse, P.I.; Horst, ter M.M.S.; Deneer, J.W.; Brink, van den P.J.

    2015-01-01

    Scenarios for future use in the pesticide registration procedure in Ethiopia were designed for 3 separate Ethiopian locations, which are aimed to be protective for the whole of Ethiopia. The scenarios estimate concentrations in surface water resulting from agricultural use of pesticides for a small

  11. Dissolved Carbon Dioxide in Tropical East Atlantic Surface Waters

    NARCIS (Netherlands)

    Bakker, D.C.E.; Baar, H.J.W. de; Jong, E. de

    1999-01-01

    Variability of dissolved inorganic carbon (DIC) and the fugacity of carbon dioxide (fCO2) is discussed for tropical East Atlantic surface waters in October–November 1993 and May–June 1994. High precipitation associated with the Intertropical Convergence Zone, river input and equatorial upwelling

  12. Shale gas development impacts on surface water quality in Pennsylvania

    Science.gov (United States)

    Olmstead, Sheila M.; Muehlenbachs, Lucija A.; Shih, Jhih-Shyang; Chu, Ziyan; Krupnick, Alan J.

    2013-01-01

    Concern has been raised in the scientific literature about the environmental implications of extracting natural gas from deep shale formations, and published studies suggest that shale gas development may affect local groundwater quality. The potential for surface water quality degradation has been discussed in prior work, although no empirical analysis of this issue has been published. The potential for large-scale surface water quality degradation has affected regulatory approaches to shale gas development in some US states, despite the dearth of evidence. This paper conducts a large-scale examination of the extent to which shale gas development activities affect surface water quality. Focusing on the Marcellus Shale in Pennsylvania, we estimate the effect of shale gas wells and the release of treated shale gas waste by permitted treatment facilities on observed downstream concentrations of chloride (Cl−) and total suspended solids (TSS), controlling for other factors. Results suggest that (i) the treatment of shale gas waste by treatment plants in a watershed raises downstream Cl− concentrations but not TSS concentrations, and (ii) the presence of shale gas wells in a watershed raises downstream TSS concentrations but not Cl− concentrations. These results can inform future voluntary measures taken by shale gas operators and policy approaches taken by regulators to protect surface water quality as the scale of this economically important activity increases. PMID:23479604

  13. Uranium in US surface, ground, and domestic waters

    International Nuclear Information System (INIS)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01

    The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium concentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms

  14. Circulation of the surface waters in the north Indian Ocean

    Digital Repository Service at National Institute of Oceanography (India)

    Varadachari, V.V.R.; Sharma, G.S.

    The circulation pattern of the surface waters in the North Indian Ocean for different months of the year is discussed. In order to arrive at a reliable and detailed picture of the circulation pattern, streamlines are drawn using the isogon technique...

  15. Uranium in US surface, ground, and domestic waters. Volume 2

    International Nuclear Information System (INIS)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01

    The report Uranium in US Surface, Ground, and Domestic Waters comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium conentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms

  16. The interaction of water and hydrogen with nickel surfaces

    NARCIS (Netherlands)

    Shan, Junjun

    2009-01-01

    As nickel and platinum are in the same group of the periodic table, the Ni(111) and Pt(111) surfaces may be expected to show similar interaction with water and hydrogen. However in this thesis, we show these interactions for Ni(111) are quite different from those of Pt(111). Moreover, our results

  17. Uranium in US surface, ground, and domestic waters

    International Nuclear Information System (INIS)

    Drury, J.S.; Reynolds, S.; Owen, P.T.; Ross, R.H.; Ensminger, J.T.

    1981-04-01

    The report Uranium in US Surface, Ground, and Domestic Waters, comprises four volumes. Volumes 2, 3, and 4 contain data characterizing the location, sampling date, type, use, and uranium concentrations of 89,994 individual samples presented in tabular form. The tabular data in volumes 2, 3, and 4 are summarized in volume 1 in narrative form and with maps and histograms

  18. Metal concentration at surface water using multivariate analysis and ...

    African Journals Online (AJOL)

    Metal concentration at surface water using multivariate analysis and human health risk assessment. F Azaman, H Juahir, K Yunus, A Azid, S.I. Khalit, A.D. Mustafa, M.A. Amran, C.N.C. Hasnam, M.Z.A.Z. Abidin, M.A.M. Yusri ...

  19. Riparian shrub buffers reduce surface water pollutant loads

    Science.gov (United States)

    W. A. Geyer; C. Barden; K. Mankin; D. Devlin

    2003-01-01

    Surface water resources in Kansas often contain concentrations of pesticides, nutrients, and sediments that are of concern to local citizens. The United States Geological Survey reported in 1999 that 97 percent of streams and 82 percent of lakes in Kansas would not fully support all uses as designated by state statutes (U.S. Geological Survey 1999). Bacteria and...

  20. Surface water assessment on the influence of space distribution on ...

    African Journals Online (AJOL)

    In this work, the influence of space distribution on physico-chemical parameters of refinery effluent discharge has been studied, using treated effluent water discharged from the Port Harcourt Refinery Company (PHRC) into the Ekerekana Creek in Okrika as reference. Samples were collected at surface level from the ...

  1. Oxide/water interfaces: how the surface chemistry modifies interfacial water properties

    International Nuclear Information System (INIS)

    Gaigeot, Marie-Pierre; Sprik, Michiel; Sulpizi, Marialore

    2012-01-01

    The organization of water at the interface with silica and alumina oxides is analysed using density functional theory-based molecular dynamics simulation (DFT-MD). The interfacial hydrogen bonding is investigated in detail and related to the chemistry of the oxide surfaces by computing the surface charge density and acidity. We find that water molecules hydrogen-bonded to the surface have different orientations depending on the strength of the hydrogen bonds and use this observation to explain the features in the surface vibrational spectra measured by sum frequency generation spectroscopy. In particular, ‘ice-like’ and ‘liquid-like’ features in these spectra are interpreted as the result of hydrogen bonds of different strengths between surface silanols/aluminols and water. (paper)

  2. Water Surface Overgrowing of the Tatra’s Lakes

    Directory of Open Access Journals (Sweden)

    Kapusta Juraj

    2018-03-01

    Full Text Available Tatra’s lakes are vulnerable ecosystems and an important element of the alpine landscape. Mainly some shallow lake basins succumb to intense detritus sedimentation, fine fractions of material from the catchment area or to the overgrowing of water level by vegetation. In this paper, changes and dynamics of the 12 Tatra’s lake shorelines that were selected based on the detailed mapping of their extent are pointed out. Changes were assessed by accurate comparisons of historical and current orthophoto maps from the years 1949, 1955 and 2015 – and therefore, based on the oldest and the latest relevant materials. Due to the overgrowing of lakes caused by vegetation, their water surface decreased from −0.9% up to −47.9%, during the examined period. Losses were caused by the overgrowing of open water surface by the communities of sedges and peat bogs. The most significant dynamics of the shorelines during the last decades were reached by those lakes, into which fine sediments were simultaneously deposited by means of mountain water coarse. These sediments made the marginal parts of the lake basins shallower and accelerated rapid expansion of vegetation to the detriment of the open water surface. The overgrowing of shallow moraine lakes lying in the vegetation zone is a significant phenomenon of the High Tatras alpine landscape. It leads to their gradual extinction, turn into peat bogs and wet alpine meadows.

  3. [Occurrence of bacteria of the Yersinia genus in surface water].

    Science.gov (United States)

    Krogulska, B; Maleszewska, J

    1992-01-01

    The aim of the study was determination of the frequency of occurrence of Yersinia genus bacteria in surface waters polluted to various degrees with bacteria of the coliform and of fecal coli. For detection of Yersinia rods the previously elaborated medium Endo MLCe and the membrane filter method were applied. Samples of 42 surface waters were examined, including 26 from rivers and 16 from lakes, ponds and clay-pits. On the basis of sanitary bacteriological analysis 16 surface waters were classified to class I purity, 10 to class II, the remaining ones to class III or beyond classification. Yersinia rods were detected in 15 water bodies that is 35.7% of the examined waters. A total of 27 Yersinia strains were identified with dominance of Y. intermedia (14 strains) and Y. enterocolitica (10 strains). Three strains represented by the species Yersinia frederiksenii. Most of the Y. enterocolitica strains belonged to biotype 1, the particular strains being represented by various serotypes. Hence their different origin may be concluded. The pathogenic serotypes 0:3 and 0:9 of Yersinia enterocolitica were not detected.

  4. Structure and optical properties of water covered Cu(110) surfaces

    International Nuclear Information System (INIS)

    Baghbanpourasl, A.

    2014-01-01

    In this thesis structural and optical properties of the water covered Cu(110) surface is studied using density functional theory within independent particle approximation. Several stable adsorption structures are studied such as water clusters (monomer, dimer, trimer, tetramer and pentamer), different hexagonal monolayers, partially dissociated water monolayers and three different types of chains among them a chain that consists of pentagon rings. For a copper surface in contact with water vapor, the energetically stable H 2 O/OH adsorbed structures are compared thermodynamically using adsorption free energy (change of free energy due to adsorption). Several phase diagrams with respect to temperature and pressure are calculated. It is found that among the large number of energetically stable structures (i.e. structures with positive adsorption energy ) only limited number of them are thermodynamically stable. These thermodynamically stable structures are the class of almost energetically degenerate hexagonal overlayers, one type of partially dissociated water structure that contains Bjerrum defect in the hydrogen bond network and pentagon chain. Since hydrogen atoms are light weight their vibrational effects can be considerable. Zero point vibration decreases the adsorption energy up to 0.1 eV and free energy of adsorbed molecules arising from vibrational degree of freedom can go up to -0.2 eV per adsorbed molecule at 500 Kelvin. However zero point energy and vibrational free energy of adsorbed molecules do not alter relative stability of the adsorbed structures. To account for the long range van der Waals interactions, a semi-empirical scheme is applied. Reflectance Anisotropy Spectroscopy (RAS) is a fast and non destructive optical method that can be used to prob the surface in different conditions such as vacuum and electro-chemical environment. Elasto-optic coeficients of bulk are calculated from first principles and the change of the RA spectrum of the bare Cu

  5. Tritium in surface water of the Yenisei river Basin

    International Nuclear Information System (INIS)

    Bondareva, L.G.; Bolsunovsky, A.Ya.

    2005-01-01

    The paper reports an investigation of the tritium content in the surface waters of the Yenisei River basin near the Mining-and-Chemical Combine (MCC). In 2001-2003 the maximum tritium concentration in the Yenisei River did not exceed 4±1 Bq/L. It has been found that there are surface waters containing enhanced tritium, up to 168 Bq/L, as compared with the background values for the Yenisei River. There are two possible sources of tritium input. First, the last operating reactor of the MCC, which still uses the Yenisei water as coolant. Second, tritium may come from the deep aquifers at the Severny testing site. For the first time tritium has been found in two aquatic plant species of the Yenisei River with maximal tritium concentration 304 Bq/Kg wet weight. Concentration factors of tritium for aquatic plants are much higher than 1

  6. Membranes with Surface-Enhanced Antifouling Properties for Water Purification

    Science.gov (United States)

    Shahkaramipour, Nima; Tran, Thien N.; Ramanan, Sankara; Lin, Haiqing

    2017-01-01

    Membrane technology has emerged as an attractive approach for water purification, while mitigation of fouling is key to lower membrane operating costs. This article reviews various materials with antifouling properties that can be coated or grafted onto the membrane surface to improve the antifouling properties of the membranes and thus, retain high water permeance. These materials can be separated into three categories, hydrophilic materials, such as poly(ethylene glycol), polydopamine and zwitterions, hydrophobic materials, such as fluoropolymers, and amphiphilic materials. The states of water in these materials and the mechanisms for the antifouling properties are discussed. The corresponding approaches to coat or graft these materials on the membrane surface are reviewed, and the materials with promising performance are highlighted. PMID:28273869

  7. Tritiated water vapor in the surface air at Tokyo

    International Nuclear Information System (INIS)

    Inoue, Hisayuki; Katsuragi, Yukio; Shigehara, Koji

    1984-01-01

    Tritium concentration in water vapor in the air near the surface and in the precipitation at Tokyo was measured during the period from 9 August to 20 November in 1974. From August to the middle of October, tritium mixing ratios in the surface air had relatively higher values except those in air masses which were associated with a typhoon. The mixing ratios of tritium in the air decreased abruptly at the middle of October, which indicates the decrease of tritium influx from aloft. These data exhibit the salient feature that variations in tritium concentration in TR are linear to the reciprocal of the content of water vapor during each period. Tritium concentrations in vapor and rain water collected simultaneously show nearly equal values. One of the reasons for the good correlation of tritium concentration between falling drops and ambient air is considered to be the result of the rapid isotopic exchange. (author)

  8. Water surface modeling from a single viewpoint video.

    Science.gov (United States)

    Li, Chuan; Pickup, David; Saunders, Thomas; Cosker, Darren; Marshall, David; Hall, Peter; Willis, Philip

    2013-07-01

    We introduce a video-based approach for producing water surface models. Recent advances in this field output high-quality results but require dedicated capturing devices and only work in limited conditions. In contrast, our method achieves a good tradeoff between the visual quality and the production cost: It automatically produces a visually plausible animation using a single viewpoint video as the input. Our approach is based on two discoveries: first, shape from shading (SFS) is adequate to capture the appearance and dynamic behavior of the example water; second, shallow water model can be used to estimate a velocity field that produces complex surface dynamics. We will provide qualitative evaluation of our method and demonstrate its good performance across a wide range of scenes.

  9. Cholesterol enhances surface water diffusion of phospholipid bilayers

    Energy Technology Data Exchange (ETDEWEB)

    Cheng, Chi-Yuan; Kausik, Ravinath; Han, Songi, E-mail: songi@chem.ucsb.edu [Department of Chemistry and Biochemistry and Materials Research Laboratory, University of California, Santa Barbara, California 93106 (United States); Olijve, Luuk L. C. [Laboratory of Macromolecular and Organic Chemistry and Institute for Complex Molecular Systems, Eindhoven University of Technology, P.O. Box 513, 5600 MB, Eindhoven (Netherlands)

    2014-12-14

    Elucidating the physical effect of cholesterol (Chol) on biological membranes is necessary towards rationalizing their structural and functional role in cell membranes. One of the debated questions is the role of hydration water in Chol-embedding lipid membranes, for which only little direct experimental data are available. Here, we study the hydration dynamics in a series of Chol-rich and depleted bilayer systems using an approach termed {sup 1}H Overhauser dynamic nuclear polarization (ODNP) NMR relaxometry that enables the sensitive and selective determination of water diffusion within 5–10 Å of a nitroxide-based spin label, positioned off the surface of the polar headgroups or within the nonpolar core of lipid membranes. The Chol-rich membrane systems were prepared from mixtures of Chol, dipalmitoyl phosphatidylcholine and/or dioctadecyl phosphatidylcholine lipid that are known to form liquid-ordered, raft-like, domains. Our data reveal that the translational diffusion of local water on the surface and within the hydrocarbon volume of the bilayer is significantly altered, but in opposite directions: accelerated on the membrane surface and dramatically slowed in the bilayer interior with increasing Chol content. Electron paramagnetic resonance (EPR) lineshape analysis shows looser packing of lipid headgroups and concurrently tighter packing in the bilayer core with increasing Chol content, with the effects peaking at lipid compositions reported to form lipid rafts. The complementary capability of ODNP and EPR to site-specifically probe the hydration dynamics and lipid ordering in lipid membrane systems extends the current understanding of how Chol may regulate biological processes. One possible role of Chol is the facilitation of interactions between biological constituents and the lipid membrane through the weakening or disruption of strong hydrogen-bond networks of the surface hydration layers that otherwise exert stronger repulsive forces, as reflected in

  10. Surface wastewater in Samara and their impact on water basins as water supply sources

    Science.gov (United States)

    Strelkov, Alexander; Shuvalov, Mikhail; Gridneva, Marina

    2017-10-01

    The paper gives an overview of surface wastewater outlets in Samara through the rainwater sewer system into the Saratov water reservoir and the Samara river. The rainwater sewer system in Samara is designed and executed according to a separate scheme, except for the old part of the city, where surface run-off is dumped into the sewer system through siphoned drain. The rainwater system disposes of surface, drainage, industrial clean-contamined waters, emergency and technology discharges from the city’s heat supply and water supply systems. The effluent discharge is carried out by means of separate wastewater outlets into ravines or directly into the Samara river and the Saratov water reservoir without cleaning. The effluent discharge is carried out through the rainwater sewer system with 17 wastewater outlets into the Saratov water reservoir. In the Samara river, surface runoff drainage and clean-contamined water of industrial enterprises is carried out through 14 wastewater outlets. This study emphasizes the demand to arrange effluent discharge and construction of sewage treatment plants to prevent contamination of water objects by surface run-off from residential areas and industrial territories.

  11. A Study on Water Surface Profiles of Rivers with Constriction

    Science.gov (United States)

    Qian, Chaochao; Yamada, Tadashi

    2013-04-01

    Water surface profile of rivers with constrictions is precious in both classic hydraulics and river management practice. This study was conducted to clarify the essences of the water surface profiles. 3 cases of experiments and 1D numerical calculations with different discharges were made in the study and analysis solutions of the non-linear basic equation of surface profile in varied flow without considering friction were derived. The manning's number was kept in the same in each case by using crosspiece roughness. We found a new type of water surface profile of varied flow from the results of 1D numerical calculation and that of experiments and named it as Mc curve because of its mild condition with constriction segment. This kind of curves appears as a nature phenomenon ubiquitously. The process of water surface forming is dynamic and bore occurs at the upper side of constriction during increasing discharge before the surface profile formed. As a theoretical work, 3 analysis solutions were derived included 2 physical-meaning solutions in the study by using Man-Machine system. One of the derived physical-meaning solutions was confirmed that it is validity by comparing to the results of 1D numerical calculation and that of experiments. The solution represents a flow profile from under critical condition at the upper side to super critical condition at the down side of constriction segment. The other derived physical-meaning solution represents a flow profile from super critical condition at the upper side to under critical condition at the down side of constriction segment. These two kinds of flow profiles exist in the nature but no theoretical solution can express the phenomenon. We find the depth distribution only concerned with unit width discharge distribution and critical depth under a constant discharge from the derived solutions. Therefor, the profile can be gained simply and precisely by using the theoretical solutions instead of numerical calculation even

  12. IMPROVING CYANOBACTERIA AND CYANOTOXIN MONITORING IN SURFACE WATERS FOR DRINKING WATER SUPPLY

    Directory of Open Access Journals (Sweden)

    Jing Li

    2017-06-01

    Full Text Available Cyanobacteria in fresh water can cause serious threats to drinking water supplies. Managing cyanobacterial blooms particularly at small drinking water treatment plants is challenging. Because large amount of cyanobacteria may cause clogging in the treatment process and various cyanotoxins are hard to remove, while they may cause severe health problems. There is lack of instructions of what cyanobacteria/toxin amount should trigger what kind of actions for drinking water management except for Microcystins. This demands a Cyanobacteria Management Tool (CMT to help regulators/operators to improve cyanobacteria/cyanotoxin monitoring in surface waters for drinking water supply. This project proposes a CMT tool, including selecting proper indicators for quick cyanobacteria monitoring and verifying quick analysis methods for cyanobacteria and cyanotoxin. This tool is suggested for raw water management regarding cyanobacteria monitoring in lakes, especially in boreal forest climate. In addition, it applies to regions that apply international WHO standards for water management. In Swedish context, drinking water producers which use raw water from lakes that experience cyanobacterial blooms, need to create a monitoring routine for cyanobacteria/cyanotoxin and to monitor beyond such as Anatoxins, Cylindrospermopsins and Saxitoxins. Using the proposed CMT tool will increase water safety at surface water treatment plants substantially by introducing three alerting points for actions. CMT design for each local condition should integrate adaptive monitoring program.

  13. Roles of surface water areas for water and solute cycle in Hanoi city, Viet Nam

    Science.gov (United States)

    Hayashi, Takeshi; Kuroda, Keisuke; Do Thuan, An; Tran Thi Viet, Nga; Takizawa, Satoshi

    2013-04-01

    Hanoi city, the capital of Viet Nam, has developed beside the Red river. Recent rapid urbanization of this city has reduced a large number of natural water areas such as lakes, ponds and canals not only in the central area but the suburban area. Contrary, the urbanization has increased artificial water areas such as pond for fish cultivation and landscaping. On the other hand, the urbanization has induced the inflow of waste water from households and various kinds of factories to these water areas because of delay of sewerage system development. Inflow of the waste water has induced eutrophication and pollution of these water areas. Also, there is a possibility of groundwater pollution by infiltration of polluted surface water. However, the role of these water areas for water cycle and solute transport is not clarified. Therefore, this study focuses on the interaction between surface water areas and groundwater in Hanoi city to evaluate appropriate land development and groundwater resource management. We are carrying out three approaches: a) understanding of geochemical characteristics of surface water and groundwater, b) monitoring of water levels of pond and groundwater, c) sampling of soil and pond sediment. Correlation between d18O and dD of precipitation (after GNIP), the Red River (after GNIR) and the water samples of this study showed that the groundwater is composed of precipitation, the Red River and surface water that has evaporation process. Contribution of the surface water with evaporation process was widely found in the study area. As for groundwater monitoring, the Holocene aquifers at two sites were in unconfined condition in dry season and the groundwater levels in the aquifer continued to increase through rainy season. The results of isotopic analysis and groundwater level monitoring showed that the surface water areas are one of the major groundwater sources. On the other hand, concentrations of dissolved Arsenic (filtered by 0.45um) in the pore

  14. Quality of surface-water supplies in the Triangle area of North Carolina, water year 2008

    Science.gov (United States)

    Giorgino, M.J.; Rasmussen, R.B.; Pfeifle, C.A.

    2012-01-01

    Surface-water supplies are important sources of drinking water for residents in the Triangle area of North Carolina, which is located within the upper Cape Fear and Neuse River Basins. Since 1988, the U.S. Geological Survey and a consortium of governments have tracked water-quality conditions and trends in several of the area's water-supply lakes and streams. This report summarizes data collected through this cooperative effort, known as the Triangle Area Water Supply Monitoring Project, during October 2007 through September 2008. Major findings for this period include:

  15. Diminished Mercury Emission From Water Surfaces by Duckweed (Lemna minor)

    Science.gov (United States)

    Wollenberg, J. L.; Peters, S. C.

    2007-12-01

    Aquatic plants of the family Lemnaceae (generally referred to as duckweeds) are a widely distributed type of floating vegetation in freshwater systems. Under suitable conditions, duckweeds form a dense vegetative mat on the water surface, which reduces light penetration into the water column and decreases the amount of exposed water surface. These two factors would be expected to reduce mercury emission by limiting a) direct photoreduction of Hg(II), b) indirect reduction via coupled DOC photooxidation-Hg(II) reduction, and c) gas diffusion across the water-air interface. Conversely, previous studies have demonstrated transpiration of Hg(0) by plants, so it is therefore possible that the floating vegetative mat would enhance emission via transpiration of mercury vapor. The purpose of this experiment was to determine whether duckweed limits mercury flux to the atmosphere by shading and the formation of a physical barrier to diffusion, or whether it enhances emission from aquatic systems via transpiration of Hg(0). Deionized water was amended with mercury to achieve a final concentration of approximately 35 ng/L and allowed to equilibrate prior to the experiment. Experiments were conducted in rectangular polystyrene flux chambers with measured UV-B transmittance greater than 60% (spectral cutoff approximately 290 nm). Light was able to penetrate the flux chamber from the sides as well as the top throughout the experiment, limiting the effect of shading by duckweed on the water surface. Flux chambers contained 8L of water with varying percent duckweed cover, and perforated plastic sheeting was used as an abiotic control. Exposures were conducted outside on days with little to no cloud cover. Real time mercury flux was measured using atomic absorption (Mercury Instruments UT-3000). Total solar and ultraviolet radiation, as well as a suite of meteorological parameters, were also measured. Results indicate that duckweed diminishes mercury emission from the water surface

  16. Evaluation of ATP measurements to detect microbial ingress by wastewater and surface water in drinking water

    DEFF Research Database (Denmark)

    Vang, Óluva Karin; Corfitzen, Charlotte B.; Smith, Christian

    2014-01-01

    in this respect. Compared to traditional microbiological methods, the ATP assay could detect wastewater and surface water in drinking water to a higher degree than total direct counts (TDCs), while both heterotrophic plate counts (HPC 22 °C and HPC 37 °C) and Colilert-18 (Escherichia coli and coliforms) were more...

  17. Surface Water Data at Los Alamos National Laboratory 2006 Water Year

    Energy Technology Data Exchange (ETDEWEB)

    R.P. Romero, D. Ortiz, G. Kuyumjian

    2007-08-01

    The principal investigators collected and computed surface water discharge data from 44 stream-gaging stations that cover most of Los Alamos National Laboratory and one at Bandelier National Monument. Also included are discharge data from three springs--two that flow into Canon de Valle and one that flows into Water Canyon--and peak flow data for 44 stations.

  18. Perfluoroalkyl substances in the Maltese Environment - (I) Surface water and rain water

    NARCIS (Netherlands)

    Sammut, G.; Sinagra, E.; Helmus, R.; de Voogt, P.

    2017-01-01

    The presence of perfluoroalkyl substances (PFASs) in rain water on the Maltese Islands is reported here for the first time and an extensive survey of these substances in surface water also reported. The Maltese archipelago lies at the centre of the Mediterranean Sea and consists of three main

  19. Water level observations from Unmanned Aerial Vehicles for improving estimates of surface water-groundwater interaction

    DEFF Research Database (Denmark)

    Bandini, Filippo; Butts, Michael; Vammen Jacobsen, Torsten

    2017-01-01

    spatial resolution; ii) spatially continuous profiles along or across the water body; iii) flexible timing of sampling. A semi-synthetic study was conducted to analyse the value of the new UAV-borne datatype for improving hydrological models, in particular estimates of GW (Groundwater)- SW (Surface Water...

  20. Multi-functional surfaces with controllable wettability and water adhesion

    Science.gov (United States)

    Anastasiadis, Spiros H.; Frysali, Melani A.; Kenanakis, George; Kaklamani, Georgia; Papoutsakis, Lampros

    The design of multifunctional surfaces based on biomimetic structures has gained the interest of the scientific community. Novel multifunctional surfaces have been developed, able to alter their wetting properties in response to temperature and pH as well as light illumination, by combining proper chemistry and surface micro/nano-structuring using ultrafast (femtosecond) laser irradiation. The combination of the hierarchical surface with a ZnO and/or a responsive polymer coating results in efficient photo-active properties as well as reversible superhydrophobic / superhydrophilic surfaces in response to external stimuli. These surfaces can be optimized to exhibit high or zero water adhesion and/or controllable directionality as well. Moreover, they can be seeded with human fibroblasts to examine the cellular response on both surface roughness and surface chemistry. Acknowledgements: This research has been co-financed by the General Secretariat for Research and Technology (''ARISTEIA II'' Action, SMART-SURF) and the European Union (NFFA Europe -Grant agreement No. 654360).

  1. Observation of dynamic water microadsorption on Au surface

    Energy Technology Data Exchange (ETDEWEB)

    Huang, Xiaokang, E-mail: xiaokang.huang@tqs.com; Gupta, Gaurav; Gao, Weixiang; Tran, Van; Nguyen, Bang; McCormick, Eric; Cui, Yongjie; Yang, Yinbao; Hall, Craig; Isom, Harold [TriQuint Semiconductor, Inc., 500 W Renner Road, Richardson, Texas 75080 (United States)

    2014-05-15

    Experimental and theoretical research on water wettability, adsorption, and condensation on solid surfaces has been ongoing for many decades because of the availability of new materials, new detection and measurement techniques, novel applications, and different scales of dimensions. Au is a metal of special interest because it is chemically inert, has a high surface energy, is highly conductive, and has a relatively high melting point. It has wide applications in semiconductor integrated circuitry, microelectromechanical systems, microfluidics, biochips, jewelry, coinage, and even dental restoration. Therefore, its surface condition, wettability, wear resistance, lubrication, and friction attract a lot of attention from both scientists and engineers. In this paper, the authors experimentally investigated Au{sub 2}O{sub 3} growth, wettability, roughness, and adsorption utilizing atomic force microscopy, scanning electron microscopy, reflectance spectrometry, and contact angle measurement. Samples were made using a GaAs substrate. Utilizing a super-hydrophilic Au surface and the proper surface conditions of the surrounding GaAs, dynamic microadsorption of water on the Au surface was observed in a clean room environment. The Au surface area can be as small as 12 μm{sup 2}. The adsorbed water was collected by the GaAs groove structure and then redistributed around the structure. A model was developed to qualitatively describe the dynamic microadsorption process. The effective adsorption rate was estimated by modeling and experimental data. Devices for moisture collection and a liquid channel can be made by properly arranging the wettabilities or contact angles of different materials. These novel devices will be very useful in microfluid applications or biochips.

  2. Radioactivity levels in surface water of lakes around Izmir / Turkey

    International Nuclear Information System (INIS)

    Doyurum, S.; Turkozu, D. A.; Aslani, M. A. A.; Aytas, S.; Eral, M.; Kaygun, A. K.

    2006-01-01

    Radioactivity presents in surface continental waters is mainly due to the presence of radioactive elements in the earth's crust, other artificial radionuclides have appeared due to such human activities as nuclear power plants, nuclear weapons testing and manufacture and use of radioactive sources It is well known that natural radionuclides can be effective as tracers for the different processes controlling the distribution of elements among dissolved and particulate phases in aquatic systems. The detection of high radionuclide concentrations was proposed as a public health problem in several areas and consequently studies into the risks of radionuclides were started in the 2000s. Especially, these radioactive substances in groundwater are an unwanted and involuntary risk factor from natural sources, not artificial sources. These radioactive substances include uranium, radon found in uranium series, and other radioactive substances such as radium and gross alpha. Uranium present in rock, soil, and natural materials, and is found in small quantities in air, water, and food that people always contact. In this project, lake water samples were collected from three lakes around Izmir-Turkey. In surface lake water samples, pH, mV and conductivity values were measured and alkaline content was determined titrimetrically. The uranium concentrations in the lake water samples were measured using uranium analyzer. The radioactivity concentrations related to gross radium isotopes, gross-? and gross-? activities in the surface lake water were determined. The correlation among some parameters for water samples and concentrations of uranium, activity concentration of gross radium isotopes, gross alpha and gross beta radioactivity are also discussed

  3. Movement of Irrigation Water in Soil from a Surface Emitter

    Directory of Open Access Journals (Sweden)

    Ibrahim Abbas Dawood

    2016-09-01

    Full Text Available rickle irrigation is one of the most conservative irrigation techniques since it implies supplying water directly on the soil through emitters. Emitters dissipate energy of water at the end of the trickle irrigation system and provide water at emission points. The area wetted by an emitter depends upon the discharge of emitter, soil texture, initial soil water content, and soil permeability. The objectives of this research were to predict water distribution profiles through different soils for different conditions and quantify the distribution profiles in terms of main characteristics of soil and emitter. The wetting patterns were simulated at the end of each hour for a total time of application of 12 hrs, emitter discharges of 0.5, 0.75, 1, 2, 3, 4, and 5 lph, and five initial volumetric soil water contents. Simulation of water flow from a single surface emitter was carried out by using the numerically-based software Hydrus-2D/3D, Version 2.04. Two approaches were used in developing formulas to predict the domains of the wetted pattern. In order to verify the results obtained by implementing the software Hydrus-2D/3D a field experiment was conducted to measure the wetted diameter and compare measured values with simulated ones. The results of the research showed that the developed formulas to express the wetted diameter and depth in terms of emitter discharge, time of application, and initial soil water content are very general and can be used with very good accuracy.

  4. DMS Advanced Applications for Accommodating High Penetrations of DERs and Microgrids: Preprint

    Energy Technology Data Exchange (ETDEWEB)

    Pratt, Annabelle [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Veda, Santosh [National Renewable Energy Laboratory (NREL), Golden, CO (United States); Maitra, Arindam [Electric Power Research Institute; Hubert, Tanguy [Electric Power Research Institute; Reilly, Jim [Reilly Associates; Wang, JIanhui [Argonne National Laboratory; Singh, Ravindra [Argonne National Laboratory; Kang, Ning [Argonne National Laboratory; Lu, Xiaonan [Argonne National Laboratory

    2017-08-24

    Efficient and effective management of the electrical distribution system requires an integrated system approach for Distribution Management Systems (DMS), Distributed Energy Resources (DERs), Distributed Energy Resources Management System (DERMS), and microgrids to work in harmony. This paper highlights some of the outcomes from a U.S. Department of Energy (DOE), Office of Electricity (OE) project, including 1) Architecture of these integrated systems, and 2) Expanded functions of two example DMS applications, Volt-VAR optimization (VVO) and Fault Location, Isolation and Service Restoration (FLISR), to accommodate DER. For these two example applications, the relevant DER Group Functions necessary to support communication between DMS and Microgrid Controller (MC) in grid-tied mode are identified.

  5. Evaluation of ATP measurements to detect microbial ingress by wastewater and surface water in drinking water.

    Science.gov (United States)

    Vang, Óluva K; Corfitzen, Charlotte B; Smith, Christian; Albrechtsen, Hans-Jørgen

    2014-11-01

    Fast and reliable methods are required for monitoring of microbial drinking water quality in order to protect public health. Adenosine triphosphate (ATP) was investigated as a potential real-time parameter for detecting microbial ingress in drinking water contaminated with wastewater or surface water. To investigate the ability of the ATP assay in detecting different contamination types, the contaminant was diluted with non-chlorinated drinking water. Wastewater, diluted at 10(4) in drinking water, was detected with the ATP assay, as well as 10(2) to 10(3) times diluted surface water. To improve the performance of the ATP assay in detecting microbial ingress in drinking water, different approaches were investigated, i.e. quantifying microbial ATP or applying reagents of different sensitivities to reduce measurement variations; however, none of these approaches contributed significantly in this respect. Compared to traditional microbiological methods, the ATP assay could detect wastewater and surface water in drinking water to a higher degree than total direct counts (TDCs), while both heterotrophic plate counts (HPC 22 °C and HPC 37 °C) and Colilert-18 (Escherichia coli and coliforms) were more sensitive than the ATP measurements, though with much longer response times. Continuous sampling combined with ATP measurements displays definite monitoring potential for microbial drinking water quality, since microbial ingress in drinking water can be detected in real-time with ATP measurements. The ability of the ATP assay to detect microbial ingress is influenced by both the ATP load from the contaminant itself and the ATP concentration in the specific drinking water. Consequently, a low ATP concentration of the specific drinking water facilitates a better detection of a potential contamination of the water supply with the ATP assay. Copyright © 2014 Elsevier Ltd. All rights reserved.

  6. Near-field Oblique Remote Sensing of Stream Water-surface Elevation, Slope, and Surface Velocity

    Science.gov (United States)

    Minear, J. T.; Kinzel, P. J.; Nelson, J. M.; McDonald, R.; Wright, S. A.

    2014-12-01

    A major challenge for estimating discharges during flood events or in steep channels is the difficulty and hazard inherent in obtaining in-stream measurements. One possible solution is to use near-field remote sensing to obtain simultaneous water-surface elevations, slope, and surface velocities. In this test case, we utilized Terrestrial Laser Scanning (TLS) to remotely measure water-surface elevations and slope in combination with surface velocities estimated from particle image velocimetry (PIV) obtained by video-camera and/or infrared camera. We tested this method at several sites in New Mexico and Colorado using independent validation data consisting of in-channel measurements from survey-grade GPS and Acoustic Doppler Current Profiler (ADCP) instruments. Preliminary results indicate that for relatively turbid or steep streams, TLS collects tens of thousands of water-surface elevations and slopes in minutes, much faster than conventional means and at relatively high precision, at least as good as continuous survey-grade GPS measurements. Estimated surface velocities from this technique are within 15% of measured velocity magnitudes and within 10 degrees from the measured velocity direction (using extrapolation from the shallowest bin of the ADCP measurements). Accurately aligning the PIV results into Cartesian coordinates appears to be one of the main sources of error, primarily due to the sensitivity at these shallow oblique look angles and the low numbers of stationary objects for rectification. Combining remotely-sensed water-surface elevations, slope, and surface velocities produces simultaneous velocity measurements from a large number of locations in the channel and is more spatially extensive than traditional velocity measurements. These factors make this technique useful for improving estimates of flow measurements during flood flows and in steep channels while also decreasing the difficulty and hazard associated with making measurements in these

  7. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Sugiyama, Y.; Hosseini, S.H.R.; Akiyama, H.; Lukeš, Petr; Akiyama, M.

    2016-01-01

    Roč. 49, č. 41 (2016), č. článku 415202. ISSN 0022-3727 Institutional support: RVO:61389021 Keywords : water surface * spectroscopy * high-speed photography * pulsed plasma discharge * Atmospheric - pressure plasmas * electric discharges * liquids * water Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.588, year: 2016 http://iopscience.iop.org/article/10.1088/0022-3727/49/41/415202

  8. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    Czech Academy of Sciences Publication Activity Database

    Hoffer, Petr; Sugiyama, Y.; Hosseini, S.H.R.; Akiyama, H.; Lukeš, Petr; Akiyama, M.

    2016-01-01

    Roč. 49, č. 41 (2016), č. článku 415202. ISSN 0022-3727 Institutional support: RVO:61389021 Keywords : water surface * spectroscopy * high-speed photography * pulsed plasma discharge * Atmospheric-pressure plasmas * electric discharges * liquids * water Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.588, year: 2016 http://iopscience.iop.org/article/10.1088/0022-3727/49/41/415202

  9. Self-induced free surface oscillations caused by water jet

    International Nuclear Information System (INIS)

    Fukaya, M.; Madarame, H.; Okamoto, K.; Iida, M.; Someya, S.

    1995-01-01

    The interaction between the high speed flow and the free surfaces could induced surface oscillations. Recently, some kinds of self-induced free surface oscillations caused by water jet were discovered, e.g., a self-induced sloshing, 'Jet-Flutter' and a self-induced manometer oscillation. These oscillations have many different characteristics with each other. In this study, the similarities and differences of these oscillations are examined, and the geometrical effects on the phenomena are experimentally investigated. The self-induced sloshing and the Jet-Flutter have different dimensionless traveling times, which suggests a difference in the energy supply mechanism. When the distance between the inlet and the outlet is small in a vessel, the self-induced manometer oscillation could occur in the multi-free-surface system. (author)

  10. The Character of the Solar Wind, Surface Interactions, and Water

    Science.gov (United States)

    Farrell, William M.

    2011-01-01

    We discuss the key characteristics of the proton-rich solar wind and describe how it may interact with the lunar surface. We suggest that solar wind can be both a source and loss of water/OH related volatiles, and review models showing both possibilities. Energy from the Sun in the form of radiation and solar wind plasma are in constant interaction with the lunar surface. As such, there is a solar-lunar energy connection, where solar energy and matter are continually bombarding the lunar surface, acting at the largest scale to erode the surface at 0.2 Angstroms per year via ion sputtering [1]. Figure 1 illustrates this dynamically Sun-Moon system.

  11. Modeling variably saturated subsurface solute transport with MODFLOW-UZF and MT3DMS

    Science.gov (United States)

    Morway, Eric D.; Niswonger, Richard G.; Langevin, Christian D.; Bailey, Ryan T.; Healy, Richard W.

    2013-01-01

    The MT3DMS groundwater solute transport model was modified to simulate solute transport in the unsaturated zone by incorporating the unsaturated-zone flow (UZF1) package developed for MODFLOW. The modified MT3DMS code uses a volume-averaged approach in which Lagrangian-based UZF1 fluid fluxes and storage changes are mapped onto a fixed grid. Referred to as UZF-MT3DMS, the linked model was tested against published benchmarks solved analytically as well as against other published codes, most frequently the U.S. Geological Survey's Variably-Saturated Two-Dimensional Flow and Transport Model. Results from a suite of test cases demonstrate that the modified code accurately simulates solute advection, dispersion, and reaction in the unsaturated zone. Two- and three-dimensional simulations also were investigated to ensure unsaturated-saturated zone interaction was simulated correctly. Because the UZF1 solution is analytical, large-scale flow and transport investigations can be performed free from the computational and data burdens required by numerical solutions to Richards' equation. Results demonstrate that significant simulation runtime savings can be achieved with UZF-MT3DMS, an important development when hundreds or thousands of model runs are required during parameter estimation and uncertainty analysis. Three-dimensional variably saturated flow and transport simulations revealed UZF-MT3DMS to have runtimes that are less than one tenth of the time required by models that rely on Richards' equation. Given its accuracy and efficiency, and the wide-spread use of both MODFLOW and MT3DMS, the added capability of unsaturated-zone transport in this familiar modeling framework stands to benefit a broad user-ship.

  12. Skeletal affinity of Tc(V)-DMS is bone cell mediated and pH dependent.

    Science.gov (United States)

    Horiuchi-Suzuki, Kazuko; Konno, Aya; Ueda, Mayumi; Fukuda, Yoko; Nishio, Saori; Hashimoto, Kazuyuki; Saji, Hideo

    2004-03-01

    In spite of recent advances in bone cellular and molecular biology, there is still a poor correlation between these parameters and data obtained from bone scintigraphy. Diphosphonate derivatives radiolabelled with technetium-99m (Tc-BPs) have long been recognised as bone-seeking agents with an affinity for areas of active mineralisation. However, during clinical trials with a pH-sensitive tumour agent, the pentavalent technetium complex of dimercaptosuccinic acid [Tc(V)-DMS] showed a noticeable osteotropic character only in bone pathologies (bone metastases, Paget's diseases) and lacked accumulation in normal mature bone. To decipher the osteotropic character of Tc(V)-DMS, a study at the cellular level was considered necessary. Moreover, to learn more about the role of Tc bone agents, acid-base regulation by bone tissue or cells was studied. First, biological parameters in body fluid were measured under systemic acidosis, induced by glucose administration, in normal and Ehrlich ascites tumour (EAT)-bearing mice. Then, in vivo biodistribution studies using Tc(V)-DMS or a conventional Tc-BP agent were carried out. The effect of glucose-mediated acidification on the skeletal distribution of the Tc agents in the mice provided valuable hints regarding the differential mediation of bone cells in skeletal tissue affinity for the agents. Thereafter, in vitro studies on osteoblast and osteoclast cells were performed and the comparative affinity of Tc(V)-DMS and Tc-BP was screened under diverse acidification conditions. Moreover, studies were also carried out on acid-base parameters related to the cellular uptake mechanism. Very specific pH-sensitive Tc(V)-DMS accumulation only in the osteoclastic system was detected, and use of Tc(V)-DMS in the differential detection of osteoblastic and osteoclastic metastases is discussed.

  13. Detection of Radiation-Exposure Biomarkers by Differential Mobility Prefiltered Mass Spectrometry (DMS-MS).

    Science.gov (United States)

    Coy, Stephen L; Krylov, Evgeny V; Schneider, Bradley B; Covey, Thomas R; Brenner, David J; Tyburski, John B; Patterson, Andrew D; Krausz, Kris W; Fornace, Albert J; Nazarov, Erkinjon G

    2010-04-15

    Technology to enable rapid screening for radiation exposure has been identified as an important need, and, as a part of a NIH / NIAD effort in this direction, metabolomic biomarkers for radiation exposure have been identified in a recent series of papers. To reduce the time necessary to detect and measure these biomarkers, differential mobility spectrometry - mass spectrometry (DMS-MS) systems have been developed and tested. Differential mobility ion filters preselect specific ions and also suppress chemical noise created in typical atmospheric-pressure ionization sources (ESI, MALDI, and others). Differential-mobility-based ion selection is based on the field dependence of ion mobility, which, in turn, depends on ion characteristics that include conformation, charge distribution, molecular polarizability, and other properties, and on the transport gas composition which can be modified to enhance resolution. DMS-MS is able to resolve small-molecule biomarkers from nearly-isobaric interferences, and suppresses chemical noise generated in the ion source and in the mass spectrometer, improving selectivity and quantitative accuracy. Our planar DMS design is rapid, operating in a few milliseconds, and analyzes ions before fragmentation. Depending on MS inlet conditions, DMS-selected ions can be dissociated in the MS inlet expansion, before mass analysis, providing a capability similar to MS/MS with simpler instrumentation. This report presents selected DMS-MS experimental results, including resolution of complex test mixtures of isobaric compounds, separation of charge states, separation of isobaric biomarkers (citrate and isocitrate), and separation of nearly-isobaric biomarker anions in direct analysis of a bio-fluid sample from the radiation-treated group of a mouse-model study. These uses of DMS combined with moderate resolution MS instrumentation indicate the feasibility of field-deployable instrumentation for biomarker evaluation.

  14. RISK ASSESSMENT OF SURFACE WATERS ASSOCIATED WITH WATER CIRCULATION TECHNOLOGIES ON TROUT FARMS

    Directory of Open Access Journals (Sweden)

    Marcin Sidoruk

    2014-07-01

    Full Text Available Dynamic development of aquaculture has led to an increasing impact on the status of surface waters. Fish production generates wastes that, at high concentrations, may present a serious risk to the aquatic environment. Studies on the assessment of the impact of water management technologies in trout production on the quality of surface waters were conducted in 2011. Six farms were selected for the studies and were divided into two groups based on water management solutions (n = 3: farms with a flow through system (FTS and farms with a recirculation aquaculture system (RAS. On all farms, water measurement points were set and they depicted the quality of inflow water, the quality of water in ponds and the quality of outflow water. The studies did not demonstrate any impact of applied technology on electrolyte conductivity or calcium and magnesium concentrations in outflow water from a trout operation. In addition, it was found that the use of water for production purposes resulted in a slight increase in phosphorus and total nitrogen concentrations in waste waters.

  15. Trace-level mercury removal from surface water

    International Nuclear Information System (INIS)

    Klasson, K.T.; Bostick, D.T.

    1998-01-01

    Many sorbents have been developed for the removal of mercury and heavy metals from waters; however, most of the data published thus far do not address the removal of mercury to the target levels represented in this project. The application to which these sorbents are targeted for use is the removal of mercury from microgram-per-liter levels to low nanogram-per-liter levels. Sorbents with thiouronium, thiol, amine, sulfur, and proprietary functional groups were selected for these studies. Mercury was successfully removed from surface water via adsorption onto Ionac SR-4 and Mersorb resins to levels below the target goal of 12 ng/L in batch studies. A thiol-based resin performed the best, indicating that over 200,000 volumes of water could be treated with one volume of resin. The cost of the resin is approximately $0.24 per 1,000 gal of water

  16. Modelling of long term nitrogen retention in surface waters

    Science.gov (United States)

    Halbfaß, S.; Gebel, M.; Bürger, S.

    2010-12-01

    In order to derive measures to reduce nutrient loadings into waters in Saxony, we calculated nitrogen inputs with the model STOFFBILANZ on the regional scale. Thereby we have to compare our modelling results to measured loadings at the river basin outlets, considering long term nutrient retention in surface waters. The most important mechanism of nitrogen retention is the denitrification in the contact zone of water and sediment, being controlled by hydraulic and micro-biological processes. Retention capacity is derived on the basis of the nutrient spiralling concept, using water residence time (hydraulic aspect) and time-specific N-uptake by microorganisms (biological aspect). Short time related processes of mobilization and immobilization are neglected, because they are of minor importance for the derivation of measures on the regional scale.

  17. Quality-control design for surface-water sampling in the National Water-Quality Network

    Science.gov (United States)

    Riskin, Melissa L.; Reutter, David C.; Martin, Jeffrey D.; Mueller, David K.

    2018-04-10

    The data-quality objectives for samples collected at surface-water sites in the National Water-Quality Network include estimating the extent to which contamination, matrix effects, and measurement variability affect interpretation of environmental conditions. Quality-control samples provide insight into how well the samples collected at surface-water sites represent the true environmental conditions. Quality-control samples used in this program include field blanks, replicates, and field matrix spikes. This report describes the design for collection of these quality-control samples and the data management needed to properly identify these samples in the U.S. Geological Survey’s national database.

  18. Prediction of water droplet evaporation on zircaloy surface

    International Nuclear Information System (INIS)

    Lee, Chi Young; In, Wang Kee

    2014-01-01

    In the present experimental study, the prediction of water droplet evaporation on a zircaloy surface was investigated using various initial droplet sizes. To the best of our knowledge, this may be the first valuable effort for understanding the details of water droplet evaporation on a zircaloy surface. The initial contact diameters of the water droplets tested ranged from 1.76 to 3.41 mm. The behavior (i.e., time-dependent droplet volume, contact angle, droplet height, and contact diameter) and mode-transition time of the water droplet evaporation were strongly influenced by the initial droplet size. Using the normalized contact angle (θ*) and contact diameter (d*), the transitions between evaporation modes were successfully expressed by a single curve, and their criteria were proposed. To predict the temporal droplet volume change and evaporation rate, the range of θ* > 0.25 and d* > 0.9, which mostly covered the whole evaporation period and the initial contact diameter remained almost constant during evaporation, was targeted. In this range, the previous contact angle functions for the evaporation model underpredicted the experimental data. A new contact angle function of a zircaloy surface was empirically proposed, which represented the present experimental data within a reasonable degree of accuracy. (author)

  19. Linking land use with pesticides in Dutch surface waters.

    Science.gov (United States)

    Van't, Zelfde M T; Tamis, W L M; Vijver, M G; De Snoo, G R

    2012-01-01

    Compared with other European countries The Netherlands has a relatively high level of pesticide consumption, particularly in agriculture. Many of the compounds concerned end up in surface waters. Surface water quality is routinely monitored and numerous pesticides are found to be present in high concentrations, with various standards being regularly exceeded. Many standards-breaching pesticides exhibit regional patterns that can be traced back to land use. These patterns have been statistically analysed by correlating surface area per land use category with standards exceedance per pesticide, thereby identifying numerous significant correlations with respect to breaches of both the ecotoxicological standard (Maximum Tolerable Risk, MTR) and the drinking water standard. In the case of the MTR, greenhouse horticulture, floriculture and bulb-growing have the highest number as well as percentage of standard-breaching pesticides, despite these market segments being relatively small in terms of area cropped. Cereals, onions, vegetables, perennial border plants and pulses are also associated with many pesticides that exceed the drinking water standard. When a correction is made for cropped acreage, cereals and potatoes also prove to be a major contributor to monitoring sites where the MTR standard is exceeded. Over the period 1998-2006 the land-use categories with the most and highest percentage of standards-exceeding pesticides (greenhouse horticulture, bulb-growing and flower cultivation) showed an increase in the percentage of standards-exceeding compounds.

  20. Radioactivity in the Dutch surface waters after Chernobylsk

    International Nuclear Information System (INIS)

    Kroesbergen, J.; Ballegooijen, L. van; Uunk, E.J.B.

    1988-12-01

    A survey is given of the impact of the nuclear accident in Chernobylsk upon the Dutch surface waters. With this the measurements, which have been performed in the various compartments (water, suspended matter, bottom, biota) are presented. Since the investigation is still going, the period from May 1986 - December 1987 has been chosen. This period is long enough in order to obtain an impression of the long-term effects. In chapter 2 a description is given of the measuring program performed and the analyzing methods employed. In chapter 3 the activation measurements in the surface waters, the suspended matter and the bottom are considered. Also the contamination of biologic matter and the purification mud is discussed. Chapter 4 gives a survey of the amount of radionuclides, which have been accumulated in the Dutch surface waters as a result of the Chernobylsk accident. The investigation of the processes are discussed in chapter 5. Since the study of the effects of radionuclides in the aquatic environment is still going, only some aspects are treated. Chapter 6 gives a general discussion of the results. Also an estimation is presented towards the future development of the contamination of the aquatic environment. Finally in chapter 7 the most important conclusions are summarized. Also some recommendations are made with regard to future measurements to be taken. (author). 72 refs.; 36 figs.; 26 tabs

  1. Analysis of water microdroplet condensation on silicon surfaces

    Science.gov (United States)

    Honda, Takuya; Fujimoto, Kenya; Yoshimoto, Yuta; Mogi, Katsuo; Kinefuchi, Ikuya; Sugii, Yasuhiko; Takagi, Shu; Univ. of Tokyo Team; Tokyo Inst. of Tech. Team

    2016-11-01

    We observed the condensation process of water microdroplets on flat silicon (100) surfaces by means of the sequential visualization of the droplets using an environmental scanning electron microscope. As previously reported for nanostructured surfaces, the condensation process of water microdroplets on the flat silicon surfaces also exhibits two modes: the constant base (CB) area mode and the constant contact angle (CCA) mode. In the CB mode, the contact angle increases with time while the base diameter is constant. Subsequently, in the CCA mode, the base diameter increases with time while the contact angle remains constant. The dropwise condensation model regulated by subcooling temperature does not reproduce the experimental results. Because the subcooling temperature is not constant in the case of a slow condensation rate, this model is not applicable to the condensation of the long time scale ( several tens of minutes). The contact angle of water microdroplets ( several μm) tended to be smaller than the macro contact angle. Two hypotheses are proposed as the cause of small contact angles: electrowetting and the coalescence of sub- μm water droplets.

  2. Pesticide monitoring in surface water and groundwater using passive samplers

    Science.gov (United States)

    Kodes, V.; Grabic, R.

    2009-04-01

    Passive samplers as screening devices have been used within a czech national water quality monitoring network since 2002 (SPMD and DGT samplers for non polar substances and metals). The passive sampler monitoring of surface water was extended to polar substances, in 2005. Pesticide and pharmaceutical POCIS samplers have been exposed in surface water at 21 locations and analysed for polar pesticides, perfluorinated compounds, personal care products and pharmaceuticals. Pesticide POCIS samplers in groundwater were exposed at 5 locations and analysed for polar pesticides. The following active substances of plant protection products were analyzed in surface water and groundwater using LC/MS/MS: 2,4,5-T, 2,4-D, Acetochlor, Alachlor, Atrazine, Atrazine_desethyl, Azoxystrobin, Bentazone, Bromacil, Bromoxynil, Carbofuran, Clopyralid, Cyanazin, Desmetryn, Diazinon, Dicamba, Dichlobenil, Dichlorprop, Dimethoat, Diuron, Ethofumesate, Fenarimol, Fenhexamid, Fipronil, Fluazifop-p-butyl, Hexazinone, Chlorbromuron, Chlorotoluron, Imazethapyr, Isoproturon, Kresoxim-methyl, Linuron, MCPA, MCPP, Metalaxyl, Metamitron, Methabenzthiazuron, Methamidophos, Methidathion, Metobromuron, Metolachlor, Metoxuron, Metribuzin, Monolinuron, Nicosulfuron, Phorate, Phosalone, Phosphamidon, Prometryn, Propiconazole, Propyzamide, Pyridate, Rimsulfuron, Simazine, Tebuconazole, Terbuthylazine, Terbutryn, Thifensulfuron-methyl, Thiophanate-methyl and Tri-allate. The POCIS samplers performed very well being able to provide better picture than grab samples. The results show that polar pesticides and also perfluorinated compounds, personal care products and pharmaceuticals as well occur in hydrosphere of the Czech republic. Acknowledgment: Authors acknowledge the financial support of grant No. 2B06095 by the Ministry of Education, Youth and Sports.

  3. Sensors and OBIA synergy for operational monitoring of surface water

    Science.gov (United States)

    Masson, Eric; Thenard, Lucas

    2010-05-01

    This contribution will focus on combining Object Based Image Analysis (i.e. OBIA with e-Cognition 8) and recent sensors (i.e. Spot 5 XS, Pan and ALOS Prism, Avnir2, Palsar) to address the technical feasibility for an operational monitoring of surface water. Three cases of river meandering (India), flood mapping (Nepal) and dam's seasonal water level monitoring (Morocco) using recent sensors will present various application of surface water monitoring. The operational aspect will be demonstrated either by sensor properties (i.e. spatial resolution and bandwidth), data acquisition properties (i.e. multi sensor, return period and near real-time acquisition) but also with OBIA algorithms (i.e. fusion of multi sensors / multi resolution data and batch processes). In the first case of river meandering (India) we will address multi sensor and multi date satellite acquisition to monitor the river bed mobility within a floodplain using an ALOS dataset. It will demonstrate the possibility of an operational monitoring system that helps the geomorphologist in the analysis of fluvial dynamic and sediment budget for high energy rivers. In the second case of flood mapping (Nepal) we will address near real time Palsar data acquisition at high spatial resolution to monitor and to map a flood extension. This ALOS sensor takes benefit both from SAR and L band properties (i.e. atmospheric transparency, day/night acquisition, low sensibility to surface wind). It's a real achievement compared to optical imagery or even other high resolution SAR properties (i.e. acquisition swath, bandwidth and data price). These advantages meet the operational needs set by crisis management of hydrological disasters but also for the implementation of flood risk management plans. The last case of dam surface water monitoring (Morocco) will address an important issue of water resource management in countries affected by water scarcity. In such countries water users have to cope with over exploitation

  4. Guidelines for Implementing Advanced Distribution Management Systems-Requirements for DMS Integration with DERMS and Microgrids

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jianhui [Argonne National Lab. (ANL), Argonne, IL (United States); Chen, Chen [Argonne National Lab. (ANL), Argonne, IL (United States); Lu, Xiaonan [Argonne National Lab. (ANL), Argonne, IL (United States)

    2015-08-01

    This guideline focuses on the integration of DMS with DERMS and microgrids connected to the distribution grid by defining generic and fundamental design and implementation principles and strategies. It starts by addressing the current status, objectives, and core functionalities of each system, and then discusses the new challenges and the common principles of DMS design and implementation for integration with DERMS and microgrids to realize enhanced grid operation reliability and quality power delivery to consumers while also achieving the maximum energy economics from the DER and microgrid connections.

  5. Variations in concentrations and fluxes of dimethylsulfide (DMS) from the Indian estuaries

    Digital Repository Service at National Institute of Oceanography (India)

    Viswanadham, R.; Bharathi, M.D.; Sarma, V.V.S.S.

    to inhibition of phytoplankton growth by suspended load and low flushing rates. Key words: DMS; Fluxes; River discharge; Nutrients inputs; Indian Monsoonal estuaries 2    1. Introduction Dimethyl sulfide (DMS) is an important biogenic sulfur gas, produced....R. Dolan, and M. Corn. 1996. Assessment of the role of copepods and ciliates in the release to solution of particulate DMSP. Marine Ecology Progress Series 141: 119- 127. Dacey, J.W.H., and S.G. Wakeham. 1986. Oceanic dimethyl sulfide: production during...

  6. Transitions for fipronil quant in surface water, Summary of Current Fipronil Water Data and Water Data for WWTPs

    Data.gov (United States)

    U.S. Environmental Protection Agency — Comparison of fipronil sources in North Carolina surface water and identification of a novel fipronil transformation product in recycled wastewater. This dataset is...

  7. Surface Water Quality Trends from EPA's LTM Network

    Science.gov (United States)

    Funk, C.; Lynch, J. A.

    2013-12-01

    Surface water chemistry provides direct indicators of the potential effects of anthropogenic impacts, such as acid deposition and climate change, on the overall health of aquatic ecosystems. Long-term surface water monitoring networks provide a host of environmental data that can be used, in conjunction with other networks, to assess how water bodies respond to stressors and if they are potentially at risk (e.g., receiving pollutant deposition beyond its critical load). Two EPA-administered monitoring programs provide information on the effects of acidic deposition on headwater aquatic systems: the Long Term Monitoring (LTM) program and the Temporally Integrated Monitoring of Ecosystems (TIME) program, designed to track the effectiveness of the 1990 Clean Air Act Amendments (CAAA) in reducing the acidity of surface waters in acid sensitive ecoregions of the Northeast and Mid-Atlantic. Here we present regional variability of long term trends in surface water quality in response to substantial reductions in atmospheric deposition. Water quality trends at acid sensitive LTM sites exhibit decreasing concentrations of sulfate at 100% of monitored sites in the Adirondack Mountains and New England, 80% of Northern Appalachian Plateau sites, and yet only 15% of sites in the Ridge and Blue Ridge Provinces over the 1990-2011 period of record. Across all regions, most LTM sites exhibited constant or only slightly declining nitrate concentrations over the same time period. Acid Neutralizing Capacity (ANC) levels improved at 68% and 45% of LTM sites in the Adirondacks and Northern Appalachian Plateau, respectively, but few sites showed increases in New England or the Ridge and Blue Ridge Provinces due to lagging improvements in base cation concentration. The ANC of northeastern TIME lakes was also evaluated from 1991 to 1994 and 2008 to 2011. The percentage of lakes with ANC values below 50 μeq/L, lakes of acute or elevated concern, dropped by about 7%, indicating improvement

  8. Tracer experiment by using radioisotope in surface water environment

    International Nuclear Information System (INIS)

    Suh, K.S.; Kim, K.C.; Chun, I.Y.; Jung, S.H.; Lee, C.W.

    2007-01-01

    Complete text of publication follows. 1. Objective An expansion of industrial activities and urbanization result in still increasing amount of pollutants discharged into surface water. Discharged pollutants in surface water have harmful effects on the ecology of a river system and human beings. Pollutants discharged into surface water is transported and dispersed under conditions characteristic to particular natural water receiver. Radiotracer method is a useful tool for monitoring the pollutant dispersion and description of mixing process taking place in natural streams. A tracer experiment using radioisotope was carried out to investigate the characteristics of a pollutant transport and a determination of the diffusion coefficients in a river system. 2. Methods The upper area of the Keum river was selected for the tracer experiment, which is located in a mid west of Korea. The measurements of the velocity and bathymetry before a tracer experiment were performed to select the sampling lines for a detection of the radioisotope. The radioisotope was instantaneously injected into a flow as a point source by an underwater glass-vial crusher. The detection was made with 60 2inch NaI(Tl) scintillation detectors at 3 transverse lines at a downstream position. The multi-channel data acquisition systems were used to collect and process the signals transmitted from the detectors. Two-dimensional numerical models were used to simulate the hydraulic parameters and the concentration distributions of the radioisotope injected into the river. 3. Results and Conclusion The calculated results such as velocity and concentrations were compared with the measured ones. The dispersion characteristics of the radioisotope were analyzed according to a variation of the flow rate, water level and diffusion coefficients. Also, the diffusion coefficients were calculated by using the measured concentrations and the coefficients obtained from the field experiment were compared with the ones

  9. Microcystin-LR in surface water of Ponjavica river

    Directory of Open Access Journals (Sweden)

    Natić Dejan

    2012-01-01

    Full Text Available Background/Aim. Cyanobacterial toxins befall a group of various compounds according to chemical structure and health effects on people and animals. The most significant in this large group of compounds are microcystins. Their presence in water used for human consumption causes serious health problems, liver beeing the target organ. Microcystins are spread all over the world. Waterblooms of cyanobacterias and their cyanotoxins are also common in the majority of surface waters in Serbia. The aim of this study was to propose HPLC method for determination of mikrocystin-LR, to validate the method and to use it for determination of microcystin-LR in the surface water of the river Ponjavica. The Ponjavica is very eutrophic water and has ideal conditions for the cyanobacterial growth. Methods. Sample of water form the Ponjavica river were collected during the summer 2008. Coupled columns (HLB, Sep-Pak, were used for sample preparation and HPLC/PDA method was used for quantification of microcystin- LR. Results. Parameters of validation show that the proposed method is simple, fast, sensitive (0.1 mg/L and selective with the yield of 89%-92%. The measuring uncertainty of

  10. Algae form brominated organic compounds in surface waters

    Energy Technology Data Exchange (ETDEWEB)

    Huetteroth, A; Putschew, A; Jekel, M [Tech. Univ. Berlin (Germany)

    2004-09-15

    Monitoring of organic halogen compounds, measured as adsorbable organic bromine (AOBr) revealed seasonal high concentrations of organic bromine compounds in a surface water (Lake Tegel, Berlin, Germany). Usually, in late summer, concentrations are up to five times higher than during the rest of the year. The AOBr of the lake inflows (throughout the year less then 6 {mu}g/L) were always lower then those in the lake, which indicates a production of AOBr in the lake. A correlation of the AOBr and chlorophyll-a concentration (1) in the lake provides first evidence for the influence of phototrophic organisms. The knowledge of the natural production of organohalogens is relatively recent. Up to now there are more then 3800 identified natural organohalogen compounds that have been detected in marine plants, animals, and bacteria and also in terrestrial plants, fungi, lichen, bacteria, insects, some higher animals, and humans. Halogenated organic compounds are commonly considered to be of anthropogenic origin; derived from e.g. pharmaceuticals, herbicides, fungicides, insecticides, flame retardants, intermediates in organic synthesis and solvents. Additionally they are also produced as by-products during industrial processes and by waste water and drinking water disinfection. Organohalogen compounds may be toxic, persistent and/or carcinogenic. In order to understand the source and environmental relevance of naturally produced organobromine compounds in surface waters, the mechanism of the formation was investigated using batch tests with lake water and algae cultures.

  11. The impact of land use on microbial surface water pollution.

    Science.gov (United States)

    Schreiber, Christiane; Rechenburg, Andrea; Rind, Esther; Kistemann, Thomas

    2015-03-01

    Our knowledge relating to water contamination from point and diffuse sources has increased in recent years and there have been many studies undertaken focusing on effluent from sewage plants or combined sewer overflows. However, there is still only a limited amount of microbial data on non-point sources leading to diffuse pollution of surface waters. In this study, the concentrations of several indicator micro-organisms and pathogens in the upper reaches of a river system were examined over a period of 16 months. In addition to bacteria, diffuse pollution caused by Giardia lamblia and Cryptosporidium spp. was analysed. A single land use type predestined to cause high concentrations of all microbial parameters could not be identified. The influence of different land use types varies between microbial species. The microbial concentration in river water cannot be explained by stable non-point effluent concentrations from different land use types. There is variation in the ranking of the potential of different land use types resulting in surface water contamination with regard to minimum, median and maximum effects. These differences between median and maximum impact indicate that small-scale events like spreading manure substantially influence the general contamination potential of a land use type and may cause increasing micro-organism concentrations in the river water by mobilisation during the next rainfall event. Copyright © 2014 Elsevier GmbH. All rights reserved.

  12. Studies on the treatment of surface water using rajma seeds

    Directory of Open Access Journals (Sweden)

    Merlin S. Babitha

    2018-03-01

    Full Text Available Indiscriminate disposal of wastewater with suspended solids have led to higher amount of pollution to the natural water bodies. Turbidity removal becomes an essential part in the water treatment when surface water is used for drinking purpose, this can be achieved by means of coagulation process. Coagulation process is the dosing of a coagulant in water, resulting in the destabilization of negatively charged particles. Commercial coagulants which were widely used can synthesize by-products in turn may pollute the environment and deteriorate the ecosystem at a slow rate. So, now-a-days natural coagulants are used as a potential substitute because it’s biodegradable, ecofriendly and non-toxic. In this study, the turbid surface water samples were treated using powdered seeds of Rajma (natural coagulant followed by variations in dosage, settling time and pH were also studied. From the results obtained, it was found that the Rajma seeds powder achieved 48.80% efficiency for 0.5 g/l of optimum dose at pH 6 for 20 min settling time respectively.

  13. Studies on the treatment of surface water using rajma seeds

    Science.gov (United States)

    Merlin, S. Babitha; Abirami, M.; Kumar, R. Suresh

    2018-03-01

    Indiscriminate disposal of wastewater with suspended solids have led to higher amount of pollution to the natural water bodies. Turbidity removal becomes an essential part in the water treatment when surface water is used for drinking purpose, this can be achieved by means of coagulation process. Coagulation process is the dosing of a coagulant in water, resulting in the destabilization of negatively charged particles. Commercial coagulants which were widely used can synthesize by-products in turn may pollute the environment and deteriorate the ecosystem at a slow rate. So, now-a-days natural coagulants are used as a potential substitute because it's biodegradable, ecofriendly and non-toxic. In this study, the turbid surface water samples were treated using powdered seeds of Rajma (natural coagulant) followed by variations in dosage, settling time and pH were also studied. From the results obtained, it was found that the Rajma seeds powder achieved 48.80% efficiency for 0.5 g/l of optimum dose at pH 6 for 20 min settling time respectively.

  14. Biological methods used to assess surface water quality

    Directory of Open Access Journals (Sweden)

    Szczerbiñska Natalia

    2015-12-01

    Full Text Available In accordance with the guidelines of the Water Framework Directive 2000/60 (WFD, both ecological and chemical statuses determine the assessment of surface waters. The profile of ecological status is based on the analysis of various biological components, and physicochemical and hydromorphological indicators complement this assessment. The aim of this article is to present the biological methods used in the assessment of water status with a special focus on bioassay, as well as to provide a review of methods of monitoring water status. Biological test methods include both biomonitoring and bioanalytics. Water biomonitoring is used to assess and forecast the status of water. These studies aim to collect data on water pollution and forecast its impact. Biomonitoring uses organisms which are characterized by particular vulnerability to contaminants. Bioindicator organisms are algae, fungi, bacteria, larval invertebrates, cyanobacteria, macroinvertebrates, and fish. Bioanalytics is based on the receptors of contaminants that can be biologically active substances. In bioanalytics, biosensors such as viruses, bacteria, antibodies, enzymes, and biotests are used to assess degrees of pollution.

  15. Global analysis of urban surface water supply vulnerability

    International Nuclear Information System (INIS)

    Padowski, Julie C; Gorelick, Steven M

    2014-01-01

    This study presents a global analysis of urban water supply vulnerability in 71 surface-water supplied cities, with populations exceeding 750 000 and lacking source water diversity. Vulnerability represents the failure of an urban supply-basin to simultaneously meet demands from human, environmental and agricultural users. We assess a baseline (2010) condition and a future scenario (2040) that considers increased demand from urban population growth and projected agricultural demand. We do not account for climate change, which can potentially exacerbate or reduce urban supply vulnerability. In 2010, 35% of large cities are vulnerable as they compete with agricultural users. By 2040, without additional measures 45% of cities are vulnerable due to increased agricultural and urban demands. Of the vulnerable cities in 2040, the majority are river-supplied with mean flows so low (1200 liters per person per day, l/p/d) that the cities experience ‘chronic water scarcity’ (1370 l/p/d). Reservoirs supply the majority of cities facing individual future threats, revealing that constructed storage potentially provides tenuous water security. In 2040, of the 32 vulnerable cities, 14 would reduce their vulnerability via reallocating water by reducing environmental flows, and 16 would similarly benefit by transferring water from irrigated agriculture. Approximately half remain vulnerable under either potential remedy. (letter)

  16. Simulation of gas compressible flow by free surface water flow

    International Nuclear Information System (INIS)

    Altafini, C.R.; Silva Ferreira, R.T. da

    1981-01-01

    The analogy between the water flow with a free surface and the compressible fluid flow, commonly called hydraulic analogy, is analyzed and its limitations are identified. The water table is the equipment used for this simulation, which allows the quatitative analysis of subsonic and supersonic flow with a low cost apparatus. The hydraulic analogy is applied to subsonic flow around circular cylinders and supersonic flow around cones. The results are compared with available theoretical and experimental data and a good agreement is achieved. (Author) [pt

  17. Water condensation on ultrahydrophobic flexible micro pillar surface

    Science.gov (United States)

    Narhe, Ramchandra

    2016-05-01

    We investigated the growth dynamics of water drops in controlled condensation on ultrahydrophobic geometrically patterned polydimethylsiloxane (PDMS) cylindrical micro pillars. At the beginning, the condensed drops size is comparable to the pattern dimensions. The interesting phenomenon we observe is that, as the condensation progresses, water drops between the pillars become unstable and enforced to grow in the upward direction along the pillars surface. The capillary force of these drops is of the order of μ\\text{N} and acts on neighboring pillars. That results into bending of the pillars. Pillars bending enhances the condensation and favors the most energetically stable Wenzel state.

  18. Conjugate additions of a simple monosilylcopper reagent with use of the CuI.DMS complex: stereoselectivities and a dramatic impact by DMS.

    Science.gov (United States)

    Dambacher, Jesse; Bergdahl, Mikael

    2005-01-21

    Conjugate additions utilizing the simple monosilylcuprate reagent Li[PhMe2SiCuI] to alpha,beta-unsaturated carbonyl compounds are described. The presence of dimethyl sulfide (DMS), either as a component originating from the (CuI)4(DMS)3 complex or as a solvent added, has an amazing influence on both chemical yield and the level of diastereomeric ratio (dr) of the products. Gilman-type silylcyanocuprates {Li(Ph2MeSi)2Cu/LiCN} have previously been used to guarantee good results in conjugate addition reactions. External additives such as HMPA, tributylphosphine, or dialkylzinc are not necessary in conjunction with the simple Li[PhMe2SiCuI] reagent. It is demonstrated that the monosilylcuprate reagent with DMS as the solvent is very useful with sterically hindered (beta,beta-disubstituted) enones, and provides very high yields of the beta-silylated 1,4-addition products. Since there is no oligomerization problem associated with the simple monosilylcuprate reagent, this reagent should be considered as a very useful 1,4-silyl donor to enals, enones, and enoates in conjugate addition reactions.

  19. Strategic Evaluation Tool for Surface Water Quality Management Remedies in Drinking Water Catchments

    Directory of Open Access Journals (Sweden)

    Huda Almaaofi

    2017-09-01

    Full Text Available Drinking water catchments (DWC are under pressure from point and nonpoint source pollution due to the growing human activities. This worldwide challenge is causing number of adverse effects, such as degradation in water quality, ecosystem health, and other economic and social pressures. Different evaluation tools have been developed to achieve sustainable and healthy drinking water catchments. However, a holistic and strategic framework is still required to adequately consider the uncertainty associated with feasible management remedies of surface water quality in drinking water catchments. A strategic framework was developed to adequately consider the uncertainty associated with management remedies for surface water quality in drinking water catchments. A Fuzzy Multiple Criteria Decision Analysis (FMCDA approach was embedded into a strategic decision support framework to evaluate and rank water quality remediation options within a typical fixed budget constraint faced by bulk water providers. The evaluation framework consists of four core aspects; namely, water quality, environmental, economic and social, and number of associated quantitative and qualitative criteria and sub-criteria. Final remediation strategy ranking was achieved through the application of the Euclidean Distance by the In-center of Centroids (EDIC.

  20. Evaluation of Human Enteric Viruses in Surface Water and Drinking Water Resources in Southern Ghana

    Science.gov (United States)

    Gibson, Kristen E.; Opryszko, Melissa C.; Schissler, James T.; Guo, Yayi; Schwab, Kellogg J.

    2011-01-01

    An estimated 884 million people worldwide do not have access to an improved drinking water source, and the microbial quality of these sources is often unknown. In this study, a combined tangential flow, hollow fiber ultrafiltration (UF), and real-time PCR method was applied to large volume (100 L) groundwater (N = 4), surface water (N = 9), and finished (i.e., receiving treatment) drinking water (N = 6) samples for the evaluation of human enteric viruses and bacterial indicators. Human enteric viruses including norovirus GI and GII, adenovirus, and polyomavirus were detected in five different samples including one groundwater, three surface water, and one drinking water sample. Total coliforms and Escherichia coli assessed for each sample before and after UF revealed a lack of correlation between bacterial indicators and the presence of human enteric viruses. PMID:21212196

  1. The study of dynamic force acted on water strider leg departing from water surface

    Science.gov (United States)

    Sun, Peiyuan; Zhao, Meirong; Jiang, Jile; Zheng, Yelong

    2018-01-01

    Water-walking insects such as water striders can skate on the water surface easily with the help of the hierarchical structure on legs. Numerous theoretical and experimental studies show that the hierarchical structure would help water strider in quasi-static case such as load-bearing capacity. However, the advantage of the hierarchical structure in the dynamic stage has not been reported yet. In this paper, the function of super hydrophobicity and the hierarchical structure was investigated by measuring the adhesion force of legs departing from the water surface at different lifting speed by a dynamic force sensor. The results show that the adhesion force decreased with the increase of lifting speed from 0.02 m/s to 0.4 m/s, whose mechanic is investigated by Energy analysis. In addition, it can be found that the needle shape setae on water strider leg can help them depart from water surface easily. Thus, it can serve as a starting point to understand how the hierarchical structure on the legs help water-walking insects to jump upward rapidly to avoid preying by other insects.

  2. Electrodialysis and nanofiltration of surface water for subsequent use as infiltration water.

    Science.gov (United States)

    Van der Bruggen, B; Milis, R; Vandecasteele, C; Bielen, P; Van San, E; Huysman, K

    2003-09-01

    In order to achieve stable groundwater levels, an equilibrium between the use of groundwater for drinking water production and natural or artificial groundwater recharge by infiltration is needed. Local governments usually require that the composition of the water used for artificial recharge is similar to the surface water that is naturally present in the specific recharge area. In this paper, electrodialysis (ED) and nanofiltration were evaluated as possible treatment technologies for surface water from a canal in Flanders, the North of Belgium, in view of infiltration at critical places on heathlands. Both methods were evaluated on the basis of a comparison between the water composition after treatment and the composition of local surface waters. The treatment generally consists of a tuning of pH and the removal of contaminants originating from industrial and agricultural activity, e.g., nitrates and pesticides. Further evaluation of the influence of the composition of the water on the characteristics of the artificial recharge, however, was not envisaged. In a case study of water from the canal Schoten-Dessel, satisfactory concentration reductions of Cl(-), SO(4)(2-), NO(3)(-), HCO(3)(-), Na(+), Mg(2+), K(+) and Ca(2+) were obtained by ultrafiltration pretreatment followed by ED. Nanofiltration with UTC-20, N30F, Desal 51 HL, UTC-60 and Desal 5 DL membranes resulted in an insufficient removal level, especially for the monovalent ions.

  3. The study of dynamic force acted on water strider leg departing from water surface

    Directory of Open Access Journals (Sweden)

    Peiyuan Sun

    2018-01-01

    Full Text Available Water-walking insects such as water striders can skate on the water surface easily with the help of the hierarchical structure on legs. Numerous theoretical and experimental studies show that the hierarchical structure would help water strider in quasi-static case such as load-bearing capacity. However, the advantage of the hierarchical structure in the dynamic stage has not been reported yet. In this paper, the function of super hydrophobicity and the hierarchical structure was investigated by measuring the adhesion force of legs departing from the water surface at different lifting speed by a dynamic force sensor. The results show that the adhesion force decreased with the increase of lifting speed from 0.02 m/s to 0.4 m/s, whose mechanic is investigated by Energy analysis. In addition, it can be found that the needle shape setae on water strider leg can help them depart from water surface easily. Thus, it can serve as a starting point to understand how the hierarchical structure on the legs help water-walking insects to jump upward rapidly to avoid preying by other insects.

  4. Mathematical modelization of surface waters for drinking water; Modelizacion matematica de la potabilizacion de aguas superficiales

    Energy Technology Data Exchange (ETDEWEB)

    Marin Llanes, L.A.; Alvarez Rosell, S.

    1995-06-01

    The application of the general strategy of deterministic modelling to the water treatment for human consumption process for surface waters is treated in this paper. Deterministic models that describe the behaviour of clarification processes: coagulation-flocculation an filtration with respect to the principal parameters that define the water principal parameters that define the water quality: turbidity, color, pH, organic matter an presence of iron, manganese and aluminium cations were obtained. The models have been checked in actual operation conditions of water treatment plant for human consumption located in Campo Florido, Havana, cuba, named Planta Norte Habana. This plant receives water from three dams. The obtained results were good. The models are valid to describe the process, to corroborate the main theories related to water clarification and to know more about this process. The complexity of the models permits their rapid and efficient solution even without the aid of a digital computer. (Author) 5 refs.

  5. Hot water surface pasteurization for inactivating Salmonella on surfaces of mature green tomatoes

    Science.gov (United States)

    Outbreaks of salmonellosis have been associated with the consumption of tomatoes contaminated with Salmonella. Commercial washing processes for tomatoes are limited in their ability to inactivate and/or remove this human pathogen. Our objective was to develop a hot water surface pasteurization pro...

  6. Environmental constraints on the production and removal of the climatically active gas dimethylsulphide (DMS) and implications for ecosystem modelling

    NARCIS (Netherlands)

    Stefels, Jacqueline; Steinke, Michael; Turner, Suzanne; Malin, Gill; Belviso, Sauveur

    Seawater concentrations of the climate-cooling, volatile sulphur compound dimethylsulphide (DMS) are the result of numerous production and consumption processes within the marine ecosystem. Due to this complex nature, it is difficult to predict temporal and geographical distribution patterns of DMS

  7. DMS-Seq for In Vivo Genome-wide Mapping of Protein-DNA Interactions and Nucleosome Centers.

    Science.gov (United States)

    Umeyama, Taichi; Ito, Takashi

    2017-10-03

    Protein-DNA interactions provide the basis for chromatin structure and gene regulation. Comprehensive identification of protein-occupied sites is thus vital to an in-depth understanding of genome function. Dimethyl sulfate (DMS) is a chemical probe that has long been used to detect footprints of DNA-bound proteins in vitro and in vivo. Here, we describe a genomic footprinting method, dimethyl sulfate sequencing (DMS-seq), which exploits the cell-permeable nature of DMS to obviate the need for nuclear isolation. This feature makes DMS-seq simple in practice and removes the potential risk of protein re-localization during nuclear isolation. DMS-seq successfully detects transcription factors bound to cis-regulatory elements and non-canonical chromatin particles in nucleosome-free regions. Furthermore, an unexpected preference of DMS confers on DMS-seq a unique potential to directly detect nucleosome centers without using genetic manipulation. We expect that DMS-seq will serve as a characteristic method for genome-wide interrogation of in vivo protein-DNA interactions. Copyright © 2017 The Author(s). Published by Elsevier Inc. All rights reserved.

  8. Therapeutic effects of sphingosine kinase inhibitor N,N-dimethylsphingosine (DMS) in experimental chronic Chagas disease cardiomyopathy.

    Science.gov (United States)

    Vasconcelos, Juliana Fraga; Meira, Cássio Santana; Silva, Daniela Nascimento; Nonaka, Carolina Kymie Vasques; Daltro, Pâmela Santana; Macambira, Simone Garcia; Domizi, Pablo Daniel; Borges, Valéria Matos; Ribeiro-Dos-Santos, Ricardo; de Freitas Souza, Bruno Solano; Soares, Milena Botelho Pereira

    2017-07-21

    Chagas disease cardiomyopathy is a parasite-driven inflammatory disease to which there are no effective treatments. Here we evaluated the therapeutic potential of N,N-dimethylsphingosine(DMS), which blocks the production of sphingosine-1-phosphate(S1P), a mediator of cellular events during inflammatory responses, in a model of chronic Chagas disease cardiomyopathy. DMS-treated, Trypanosoma cruzi-infected mice had a marked reduction of cardiac inflammation, fibrosis and galectin-3 expression when compared to controls. Serum concentrations of galectin-3, IFNγ and TNFα, as well as cardiac gene expression of inflammatory mediators were reduced after DMS treatment. The gene expression of M1 marker, iNOS, was decreased, while the M2 marker, arginase1, was increased. DMS-treated mice showed an improvement in exercise capacity. Moreover, DMS caused a reduction in parasite load in vivo. DMS inhibited the activation of lymphocytes, and reduced cytokines and NO production in activated macrophage cultures in vitro, while increasing IL-1β production. Analysis by qRT-PCR array showed that DMS treatment modulated inflammasome activation induced by T. cruzi on macrophages. Altogether, our results demonstrate that DMS, through anti-parasitic and immunomodulatory actions, can be beneficial in the treatment of chronic phase of T. cruzi infection and suggest that S1P-activated processes as possible therapeutic targets for the treatment of Chagas disease cardiomyopathy.

  9. PRODUCTION OF DMS FROM DISSOLVED DMSP IN AXENIC CULTURES OF THE MARINE-PHYTOPLANKTON SPECIES PHAEOCYSTIS SP

    NARCIS (Netherlands)

    STEFELS, J; VANBOEKEL, WHM

    In the marine environment, production of dimethylsulfide (DMS) from dissolved dimethylsulfoniopropionate (DMSP(d)) - an algal osmolyte - is thought to occur mainly through bacterial activity. We have investigated the possibility that phytoplankton cells convert DMSP(d) into DMS, using axenic batch

  10. 14 CFR 406.113 - Filing documents with the Docket Management System (DMS) and sending documents to the...

    Science.gov (United States)

    2010-01-01

    ... 14 Aeronautics and Space 4 2010-01-01 2010-01-01 false Filing documents with the Docket Management System (DMS) and sending documents to the administrative law judge and Assistant Chief Counsel for... Management System (DMS) and sending documents to the administrative law judge and Assistant Chief Counsel for...

  11. Radionuclide transfer onto ground surface in surface water flow. 2. Undisturbed tuff rock

    International Nuclear Information System (INIS)

    Mukai, Masayuki; Takebe, Shinichi; Komiya, Tomokazu

    1994-09-01

    Radionuclide migration with ground surface water flow is considered to be one of path ways in the scenario for environmental migration of the radionuclide leaked from LLRW depository. To study the radionuclide migration demonstratively, a ground surface radionuclide migration test was carried out by simulating radioactive solution flowing on the sloped tuff rock surface. Tuff rock sample of 240 cm in length taken from the Shimokita district was used to test the transfer of 60 Co, 85 Sr and 137 Cs onto the sample surface from the flowing radioactive solution under restricted infiltration condition at flow rates of 25, 80, 160ml/min and duration of 56h. The concentration change of the radionuclides in effluent was nearly constant as a function of elapsed time during the experimental period, but decreased with lower flow rates. Among the three radionuclides, 137 Cs was greatly decreased its concentration to 30% of the inflow. Adsorbed distribution of the radionuclides concentration on the ground surface decreased gradually with the distance from the inlet, and showed greater gradient at lower flow rate. Analyzing the result by the migration model, where a vertical advection distribution and two-dimensional diffusion in surface water are adopted with a first order adsorption reaction, value of migration parameters was obtained relating to the radionuclide adsorption and the surface water flow, and the measured distribution could be well simulated by adopting the value to the model. By comparing the values with the case of loamy soil layer, all values of the migration parameters showed not so great difference between two samples for 60 Co and 85 Sr. For 137 Cs, reflecting a few larger value of adsorption to the tuff rock, larger ability to reduce the concentration of flowing radioactive solution could be indicated than that to the loamy soil surface by estimation for long flowed distance. (author)

  12. Surface-Water and Ground-Water Interactions in the Central Everglades, Florida

    Science.gov (United States)

    Harvey, Judson W.; Newlin, Jessica T.; Krest, James M.; Choi, Jungyill; Nemeth, Eric A.; Krupa, Steven L.

    2004-01-01

    Recharge and discharge are hydrological processes that cause Everglades surface water to be exchanged for subsurface water in the peat soil and the underlying sand and limestone aquifer. These interactions are thought to be important to water budgets, water quality, and ecology in the Everglades. Nonetheless, relatively few studies of surface water and ground water interactions have been conducted in the Everglades, especially in its vast interior areas. This report is a product of a cooperative investigation conducted by the USGS and the South Florida Water Management District (SFWMD) aimed at developing and testing techniques that would provide reliable estimates of recharge and discharge in interior areas of WCA-2A (Water Conservation Area 2A) and several other sites in the central Everglades. The new techniques quantified flow from surface water to the subsurface (recharge) and the opposite (discharge) using (1) Darcy-flux calculations based on measured vertical gradients in hydraulic head and hydraulic conductivity of peat; (2) modeling transport through peat and decay of the naturally occurring isotopes 224Ra and 223Ra (with half-lives of 4 and 11 days, respectively); and (3) modeling transport and decay of naturally occurring and 'bomb-pulse' tritium (half-life of 12.4 years) in ground water. Advantages and disadvantages of each method for quantifying recharge and discharge were compared. In addition, spatial and temporal variability of recharge and discharge were evaluated and controlling factors identified. A final goal was to develop appropriately simplified (that is, time averaged) expressions of the results that will be useful in addressing a broad range of hydrological and ecological problems in the Everglades. Results were compared with existing information about water budgets from the South Florida Water Management Model (SFWMM), a principal tool used by the South Florida Water Management District to plan many of the hydrological aspects of the

  13. Control of water infiltration into near surface LLW disposal units

    International Nuclear Information System (INIS)

    O'Donnell, E.; Ridky, R.W.; Schulz, R.K.

    1989-01-01

    Water infiltration to buried waste is the prime problem of concern in designing waste disposal units for the humid areas. Conventional compacted clay layers (resistance layer barriers) have been subject to failure by subsidence and by permeability increases brought about by plant roots. A clay barrier with a rock cover sans plants is being investigated. Also a combination of a resistive layer overlying a conductive layer is being investigated. Laboratory studies indicate that this approach can be very effective and field evaluations are underway. However, it must be noted that subsidence will negate the effectiveness of any buried layer barriers. A surface barrier (bioengineering management) has been valuated in the field and found to be very effective in preventing water entry into waste disposal units. This surface barrier is easily repairable if damaged by subsidence and could be the system of choice under active subsidence conditions

  14. Surface characterization of polymethylmetacrylate bombarded by charged water droplets

    International Nuclear Information System (INIS)

    Hiraoka, Kenzo; Takaishi, Riou; Asakawa, Daiki; Sakai, Yuji; Iijima, Yoshitoki

    2009-01-01

    The electrospray droplet impact (EDI), in which the charged electrospray water droplets are introduced in vacuum, accelerated, and allowed to impact the sample, is applied to polymethylmetacrylate (PMMA). The secondary ions generated were measured by an orthogonal time-of-flight mass spectrometer. In EDI mass spectra for PMMA, fragment ions originating from PMMA could not be detected. This is due to the fact that the proton affinities of fragments formed from PMMA are smaller than those from acetic acid contained in the charged droplet. The x-ray photoelectron spectroscopy spectra of PMMA irradiated by water droplets did not change with prolonged cluster irradiation, i.e., EDI is capable of shallow surface etching for PMMA with a little damage of the sample underneath the surface.

  15. Capillary condensation of water between mica surfaces above and below zero-effect of surface ions.

    Science.gov (United States)

    Nowak, Dominika; Christenson, Hugo K

    2009-09-01

    We have studied the capillary condensation of water from saturated vapor below 0 degrees C in the annular wedge-pore formed around two mica surfaces in contact in a surface force apparatus. The condensed water remains liquid down to at least -9 degrees C, and the measured condensate size is close to the predictions of a recent model for the dependence of the interfacial curvature of supercooled capillary condensates on temperature and surface tension. The small deviation observed may be accounted for by assuming that solute as K(2)CO(3) from the mica-condensate interface dissolves in the condensates and gives rise to an additional depression of the freezing point apart from that caused by the interface curvature. By contrast, measurements of the interface curvature at relative vapor pressures of 0.95-0.99 at 20 degrees C confirm a significantly larger deviation from the Kelvin equation. The magnitude of the deviation is in remarkable agreement with that calculated from the results of an earlier study of capillary condensation of water from a nonpolar liquid, also at T = 20 degrees C. Evidently, additional solute from the surrounding mica surface migrates into the condensates at room temperature. We conclude that the surface diffusion of ions on mica is much slower at subzero temperatures than at room temperature.

  16. Integrating remotely sensed surface water extent into continental scale hydrology.

    Science.gov (United States)

    Revilla-Romero, Beatriz; Wanders, Niko; Burek, Peter; Salamon, Peter; de Roo, Ad

    2016-12-01

    In hydrological forecasting, data assimilation techniques are employed to improve estimates of initial conditions to update incorrect model states with observational data. However, the limited availability of continuous and up-to-date ground streamflow data is one of the main constraints for large-scale flood forecasting models. This is the first study that assess the impact of assimilating daily remotely sensed surface water extent at a 0.1° × 0.1° spatial resolution derived from the Global Flood Detection System (GFDS) into a global rainfall-runoff including large ungauged areas at the continental spatial scale in Africa and South America. Surface water extent is observed using a range of passive microwave remote sensors. The methodology uses the brightness temperature as water bodies have a lower emissivity. In a time series, the satellite signal is expected to vary with changes in water surface, and anomalies can be correlated with flood events. The Ensemble Kalman Filter (EnKF) is a Monte-Carlo implementation of data assimilation and used here by applying random sampling perturbations to the precipitation inputs to account for uncertainty obtaining ensemble streamflow simulations from the LISFLOOD model. Results of the updated streamflow simulation are compared to baseline simulations, without assimilation of the satellite-derived surface water extent. Validation is done in over 100 in situ river gauges using daily streamflow observations in the African and South American continent over a one year period. Some of the more commonly used metrics in hydrology were calculated: KGE', NSE, PBIAS%, R 2 , RMSE, and VE. Results show that, for example, NSE score improved on 61 out of 101 stations obtaining significant improvements in both the timing and volume of the flow peaks. Whereas the validation at gauges located in lowland jungle obtained poorest performance mainly due to the closed forest influence on the satellite signal retrieval. The conclusion is that

  17. Evaporation kinetics of sessile water droplets on micropillared superhydrophobic surfaces.

    Science.gov (United States)

    Xu, Wei; Leeladhar, Rajesh; Kang, Yong Tae; Choi, Chang-Hwan

    2013-05-21

    Evaporation modes and kinetics of sessile droplets of water on micropillared superhydrophobic surfaces are experimentally investigated. The results show that a constant contact radius (CCR) mode and a constant contact angle (CCA) mode are two dominating evaporation modes during droplet evaporation on the superhydrophobic surfaces. With the decrease in the solid fraction of the superhydrophobic surfaces, the duration of a CCR mode is reduced and that of a CCA mode is increased. Compared to Rowan's kinetic model, which is based on the vapor diffusion across the droplet boundary, the change in a contact angle in a CCR (pinned) mode shows a remarkable deviation, decreasing at a slower rate on the superhydrophobic surfaces with less-solid fractions. In a CCA (receding) mode, the change in a contact radius agrees well with the theoretical expectation, and the receding speed is slower on the superhydrophobic surfaces with lower solid fractions. The discrepancy between experimental results and Rowan's model is attributed to the initial large contact angle of a droplet on superhydrophobic surfaces. The droplet geometry with a large contact angle results in a narrow wedge region of air along the contact boundary, where the liquid-vapor diffusion is significantly restricted. Such an effect becomes minor as the evaporation proceeds with the decrease in a contact angle. In both the CCR and CCA modes, the evaporative mass transfer shows the linear relationship between mass(2/3) and evaporation time. However, the evaporation rate is slower on the superhydrophobic surfaces, which is more significant on the surfaces with lower solid fractions. As a result, the superhydrophobic surfaces slow down the drying process of a sessile droplet on them.

  18. Impact of river restoration on groundwater - surface water - interactions

    Science.gov (United States)

    Kurth, Anne-Marie; Schirmer, Mario

    2014-05-01

    Since the end of the 19th century, flood protection was increasingly based on the construction of impermeable dams and side walls (BWG, 2003). In spite of providing flood protection, these measures also limited the connectivity between the river and the land, restricted the area available for flooding, and hampered the natural flow dynamics of the river. Apart from the debilitating effect on riverine ecosystems due to loss of habitats, these measures also limited bank filtration, inhibited the infiltration of storm water, and affected groundwater-surface water-interactions. This in turn had a profound effect on ecosystem health, as a lack of groundwater-surface water interactions led to decreased cycling of pollutants and nutrients in the hyporheic zone and limited the moderation of the water temperature (EA, 2009). In recent decades, it has become apparent that further damages to riverine ecosystems must be prohibited, as the damages to ecology, economy and society surmount any benefits gained from exploiting them. Nowadays, the restoration of rivers is a globally accepted means to restore ecosystem functioning, protect water resources and amend flood protection (Andrea et al., 2012; Palmer et al., 2005; Wortley et al., 2013). In spite of huge efforts regarding the restoration of rivers over the last 30 years, the question of its effectiveness remains, as river restorations often reconstruct a naturally looking rather than a naturally functioning stream (EA, 2009). We therefore focussed our research on the effectiveness of river restorations, represented by the groundwater-surface water-interactions. Given a sufficiently high groundwater level, a lack of groundwater-surface water-interactions after restoration may indicate that the vertical connectivity in the stream was not fully restored. In order to investigate groundwater-surface water-interactions we determined the thermal signature on the stream bed and in +/- 40 cm depth by using Distributed Temperature

  19. Estimation of precipitable water from surface dew point temperature

    International Nuclear Information System (INIS)

    Abdel Wahab, M.; Sharif, T.A.

    1991-09-01

    The Reitan (1963) regression equation which is of the form lnw=a+bT d has been examined and tested to estimate precipitable water content from surface dew point temperature at different locations. The study confirms that the slope of this equation (b) remains constant at the value of .0681 deg. C., while the intercept (a) changes rapidly with the latitude. The use of the variable intercept can improve the estimated result by 2%. (author). 6 refs, 4 figs, 3 tabs

  20. Effects of pulsating water jet impact on aluminium surface

    Czech Academy of Sciences Publication Activity Database

    Foldyna, Josef; Sitek, Libor; Ščučka, Jiří; Martinec, Petr; Valíček, Jan; Páleníková, K.

    2009-01-01

    Roč. 2009, č. 20 (2009), s. 6174-6180 ISSN 0924-0136 R&D Projects: GA ČR GA101/07/1451; GA ČR GP101/07/P512 Institutional research plan: CEZ:AV0Z30860518 Keywords : pulsating water jet * jet impact * material erosion * surface characteristics Subject RIV: JQ - Machines ; Tools Impact factor: 1.420, year: 2009 http://www.sciencedirect.com/science

  1. Surface Interrogation Scanning Electrochemical Microscopy for a Photoelectrochemical Reaction: Water Oxidation on a Hematite Surface.

    Science.gov (United States)

    Kim, Jae Young; Ahn, Hyun S; Bard, Allen J

    2018-03-06

    To understand the pathway of a photoelectrochemical (PEC) reaction, quantitative knowledge of reaction intermediates is important. We describe here surface interrogation scanning electrochemical microscopy for this purpose (PEC SI-SECM), where a light pulse to a photoactive semiconductor film at a given potential generates intermediates that are then analyzed by a tip generated titrant at known times after the light pulse. The improvements were demonstrated for photoelectrochemical water oxidation (oxygen evolution) reaction on a hematite surface. The density of photoactive sites, proposed to be Fe 4+ species, on a hematite surface was successfully quantified, and the photoelectrochemical water oxidation reaction dynamics were elucidated by time-dependent redox titration experiments. The new configuration of PEC SI-SECM should find expanded usage to understand and investigate more complicated PEC reactions with other materials.

  2. Improvement of a land surface model for accurate prediction of surface energy and water balances

    International Nuclear Information System (INIS)

    Katata, Genki

    2009-02-01

    In order to predict energy and water balances between the biosphere and atmosphere accurately, sophisticated schemes to calculate evaporation and adsorption processes in the soil and cloud (fog) water deposition on vegetation were implemented in the one-dimensional atmosphere-soil-vegetation model including CO 2 exchange process (SOLVEG2). Performance tests in arid areas showed that the above schemes have a significant effect on surface energy and water balances. The framework of the above schemes incorporated in the SOLVEG2 and instruction for running the model are documented. With further modifications of the model to implement the carbon exchanges between the vegetation and soil, deposition processes of materials on the land surface, vegetation stress-growth-dynamics etc., the model is suited to evaluate an effect of environmental loads to ecosystems by atmospheric pollutants and radioactive substances under climate changes such as global warming and drought. (author)

  3. Mass transfer behavior of tritium from air to water through the water surface

    International Nuclear Information System (INIS)

    Takata, Hiroki; Nishikawa, Masabumi; Kamimae, Kozo

    2005-01-01

    It is anticipated that a certain amount of tritiated water exists in the atmosphere of tritium handling facilities, and it is recognized that the hazardous potential of tritiated water is rather high. Then, it is important to grasp the behavior of tritiated water for preserving of the radiation safety. The mass transfer behavior of tritium from air to water through the water surface was discussed in this study. The evaporation rate of water and the condensation rate of water were experimentally examined from measurement of change of the weight of distilled water. The tritium transfer rate from the tritiated water in air to the distilled water was also experimentally examined by using a liquid scintillation counter. Experimental results about change of tritium level in a small beaker placed in the atmosphere with tritiated water showed that diffusion of tritium in water and gas flow in the atmosphere gives considerable effect on tritium transfer. The estimation method of the tritium transfer made in this study was applied to explain the data at The Japan Atomic Power Company second power station at Tsuruga and good agreement was obtained. (author)

  4. Macro-invertebrate decline in surface water polluted with imidacloprid.

    Directory of Open Access Journals (Sweden)

    Tessa C Van Dijk

    Full Text Available Imidacloprid is one of the most widely used insecticides in the world. Its concentration in surface water exceeds the water quality norms in many parts of the Netherlands. Several studies have demonstrated harmful effects of this neonicotinoid to a wide range of non-target species. Therefore we expected that surface water pollution with imidacloprid would negatively impact aquatic ecosystems. Availability of extensive monitoring data on the abundance of aquatic macro-invertebrate species, and on imidacloprid concentrations in surface water in the Netherlands enabled us to test this hypothesis. Our regression analysis showed a significant negative relationship (P<0.001 between macro-invertebrate abundance and imidacloprid concentration for all species pooled. A significant negative relationship was also found for the orders Amphipoda, Basommatophora, Diptera, Ephemeroptera and Isopoda, and for several species separately. The order Odonata had a negative relationship very close to the significance threshold of 0.05 (P = 0.051. However, in accordance with previous research, a positive relationship was found for the order Actinedida. We used the monitoring field data to test whether the existing three water quality norms for imidacloprid in the Netherlands are protective in real conditions. Our data show that macrofauna abundance drops sharply between 13 and 67 ng l(-1. For aquatic ecosystem protection, two of the norms are not protective at all while the strictest norm of 13 ng l(-1 (MTR seems somewhat protective. In addition to the existing experimental evidence on the negative effects of imidacloprid on invertebrate life, our study, based on data from large-scale field monitoring during multiple years, shows that serious concern about the far-reaching consequences of the abundant use of imidacloprid for aquatic ecosystems is justified.

  5. Macro-Invertebrate Decline in Surface Water Polluted with Imidacloprid

    Science.gov (United States)

    Van Dijk, Tessa C.; Van Staalduinen, Marja A.; Van der Sluijs, Jeroen P.

    2013-01-01

    Imidacloprid is one of the most widely used insecticides in the world. Its concentration in surface water exceeds the water quality norms in many parts of the Netherlands. Several studies have demonstrated harmful effects of this neonicotinoid to a wide range of non-target species. Therefore we expected that surface water pollution with imidacloprid would negatively impact aquatic ecosystems. Availability of extensive monitoring data on the abundance of aquatic macro-invertebrate species, and on imidacloprid concentrations in surface water in the Netherlands enabled us to test this hypothesis. Our regression analysis showed a significant negative relationship (Pmacro-invertebrate abundance and imidacloprid concentration for all species pooled. A significant negative relationship was also found for the orders Amphipoda, Basommatophora, Diptera, Ephemeroptera and Isopoda, and for several species separately. The order Odonata had a negative relationship very close to the significance threshold of 0.05 (P = 0.051). However, in accordance with previous research, a positive relationship was found for the order Actinedida. We used the monitoring field data to test whether the existing three water quality norms for imidacloprid in the Netherlands are protective in real conditions. Our data show that macrofauna abundance drops sharply between 13 and 67 ng l−1. For aquatic ecosystem protection, two of the norms are not protective at all while the strictest norm of 13 ng l−1 (MTR) seems somewhat protective. In addition to the existing experimental evidence on the negative effects of imidacloprid on invertebrate life, our study, based on data from large-scale field monitoring during multiple years, shows that serious concern about the far-reaching consequences of the abundant use of imidacloprid for aquatic ecosystems is justified. PMID:23650513

  6. Surface water and groundwater interaction in Marala - Khanki area, Punjab

    International Nuclear Information System (INIS)

    Akram, W.; Ahmad, M.; Latif, Z.; Tariq, J.A.; Malik, M.R.

    2011-07-01

    Isotope hydrological investigations were carried out in two selected areas of Indus Basin viz. Haripur Area and Chashma- Taunsa Area for elucidating various aspects of surface water and groundwater interaction. Groundwater samples were collected on seasonal basis (low and high river discharge periods) while surface water samples were collected more frequently (weekly or monthly basis). Isotopic data suggested that there is no contribution of surface water to groundwater recharge in Haripur Area and rain is the prevailing source of groundwater recharge. The data further revealed that isotopic values of the Haripur pocket of Tarbela Lake are higher than those of Main Lake / Indus River meaning that there is a significant contribution of base flow in this pocket. Indus River appeared to be the dominant source of groundwater recharge at most of the locations in Chashma- Taunsa Area. Isotopic data of Indus River showed an increase at Taunsa as compared to Chashma in low flow period indicating the high contribution of base flow at this point in time. Stable isotopes were successfully used to quantify the base flow contribution. (author)

  7. Water and Regolith Shielding for Surface Reactor Missions

    Science.gov (United States)

    Poston, David I.; Ade, Brian J.; Sadasivan, Pratap; Leichliter, Katrina J.; Dixon, David D.

    2006-01-01

    This paper investigates potential shielding options for surface power fission reactors. The majority of work is focused on a lunar shield that uses a combination of water in stainless-steel cans and lunar regolith. The major advantage of a water-based shield is that development, testing, and deployment should be relatively inexpensive. This shielding approach is used for three surface reactor concepts: (1) a moderated spectrum, NaK cooled, Hastalloy/UZrH reactor, (2) a fast-spectrum, NaK-cooled, SS/UO2 reactor, and (3) a fast-spectrum, K-heat-pipe-cooled, SS/UO2 reactor. For this study, each of these reactors is coupled to a 25-kWt Stirling power system, designed for 5 year life. The shields are designed to limit the dose both to the Stirling alternators and potential astronauts on the surface. The general configuration used is to bury the reactor, but several other options exist as well. Dose calculations are presented as a function of distance from reactor, depth of buried hole, water boron concentration (if any), and regolith repacked density.

  8. Water and Regolith Shielding for Surface Reactor Missions

    International Nuclear Information System (INIS)

    Poston, David I.; Sadasivan, Pratap; Dixon, David D.; Ade, Brian J.; Leichliter, Katrina J.

    2006-01-01

    This paper investigates potential shielding options for surface power fission reactors. The majority of work is focused on a lunar shield that uses a combination of water in stainless-steel cans and lunar regolith. The major advantage of a water-based shield is that development, testing, and deployment should be relatively inexpensive. This shielding approach is used for three surface reactor concepts: (1) a moderated spectrum, NaK cooled, Hastalloy/UZrH reactor, (2) a fast-spectrum, NaK-cooled, SS/UO2 reactor, and (3) a fast-spectrum, K-heat-pipe-cooled, SS/UO2 reactor. For this study, each of these reactors is coupled to a 25-kWt Stirling power system, designed for 5 year life. The shields are designed to limit the dose both to the Stirling alternators and potential astronauts on the surface. The general configuration used is to bury the reactor, but several other options exist as well. Dose calculations are presented as a function of distance from reactor, depth of buried hole, water boron concentration (if any), and regolith repacked density

  9. Modelling episodic acidification of surface waters: the state of science.

    Science.gov (United States)

    Eshleman, K N; Wigington, P J; Davies, T D; Tranter, M

    1992-01-01

    Field studies of chemical changes in surface waters associated with rainfall and snowmelt events have provided evidence of episodic acidification of lakes and streams in Europe and North America. Modelling these chemical changes is particularly challenging because of the variability associated with hydrological transport and chemical transformation processes in catchments. This paper provides a review of mathematical models that have been applied to the problem of episodic acidification. Several empirical approaches, including regression models, mixing models and time series models, support a strong hydrological interpretation of episodic acidification. Regional application of several models has suggested that acidic episodes (in which the acid neutralizing capacity becomes negative) are relatively common in surface waters in several regions of the US that receive acid deposition. Results from physically based models have suggested a lack of understanding of hydrological flowpaths, hydraulic residence times and biogeochemical reactions, particularly those involving aluminum. The ability to better predict episodic chemical responses of surface waters is thus dependent upon elucidation of these and other physical and chemical processes.

  10. Recovery of energetically overexploited urban aquifers using surface water

    Science.gov (United States)

    García-Gil, Alejandro; Vázquez-Suñé, Enric; Sánchez-Navarro, José Ángel; Mateo Lázaro, Jesús

    2015-12-01

    Shallow aquifers have an important role in reducing greenhouse gases through helping manage the temperature of urban environments. Nevertheless, the uncontrolled rapid use of shallow groundwater resources to heat or cool urban environments can cause thermal pollution that will limit the long term sustainability of the resource. Therefore, there is a need for appropriate mitigation/remediation strategies capable of recovering energetically overexploited aquifers. In this work, a novel remediation strategy based on surface water recharge into aquifers is presented. To evaluate the capabilities of such measures for effective remediation, this strategy is optimized for a management problem raised in the overheated "Urban Alluvial Aquifer of Zaragoza" (Spain). The application of a transient groundwater flow and heat transport model under 512 different mitigation scenarios has enabled to quantify and discuss the magnitude of the remediation effect as a respond to injection rates of surface water, seasonal schedule of the injection and location of injection. The quantification of the relationship between these variables together with the evaluation of the amount of surface water injected per year in each scenario proposed have provided a better understanding of the system processes and an optimal management alternative. This work also makes awareness of the magnitude of the remediation procedure which is in an order of magnitude of tenths of years.

  11. Mechanical Balance Laws for Boussinesq Models of Surface Water Waves

    Science.gov (United States)

    Ali, Alfatih; Kalisch, Henrik

    2012-06-01

    Depth-integrated long-wave models, such as the shallow-water and Boussinesq equations, are standard fare in the study of small amplitude surface waves in shallow water. While the shallow-water theory features conservation of mass, momentum and energy for smooth solutions, mechanical balance equations are not widely used in Boussinesq scaling, and it appears that the expressions for many of these quantities are not known. This work presents a systematic derivation of mass, momentum and energy densities and fluxes associated with a general family of Boussinesq systems. The derivation is based on a reconstruction of the velocity field and the pressure in the fluid column below the free surface, and the derivation of differential balance equations which are of the same asymptotic validity as the evolution equations. It is shown that all these mechanical quantities can be expressed in terms of the principal dependent variables of the Boussinesq system: the surface excursion η and the horizontal velocity w at a given level in the fluid.

  12. Foundational Report Series: Advanced Distribution Management Systems for Grid Modernization, High-Level Use Cases for DMS

    Energy Technology Data Exchange (ETDEWEB)

    Wang, Jianhui [Argonne National Lab. (ANL), Argonne, IL (United States); Lu, Xiaonan [Argonne National Lab. (ANL), Argonne, IL (United States); Martino, Sal [Reilly Associates, East Stroudsburg, PA (United States); Reilly, James T. [Electric Power Research Inst. (EPRI), Knoxville, TN (United States)

    2016-02-01

    Many distribution management systems (DMS) projects have achieved limited success because the electric utility did not sufficiently plan for actual use of the DMS functions in the control room environment. As a result, end users were not clear on how to use the new application software in actual production environments with existing, well-established business processes. An important first step in the DMS implementation process is development and refinement of the “to be” business processes. Development of use cases for the required DMS application functions is a key activity that leads to the formulation of the “to be” requirements. It is also an important activity that is needed to develop specifications that are used to procure a new DMS.

  13. Surface Water Quality Assessment and Prioritize the Factors Pollute This Water Using Topsis Fuzzy Hierarchical Analysis

    Directory of Open Access Journals (Sweden)

    Mehdi Komasi

    2017-03-01

    Full Text Available Background & Objective: Nowadays, according to growth of industry and increasing population, water resources are seriousely shortened. This lack of water resources will require special management to be considered in industry and agriculture. Among the various sources of water, surface waters are more susceptible to infection. The most important of these sources of pollution are industrial pollution, detergent, pesticides, radioactive materials, heat and salt concentration.  Materials & methods: In this article, at first the importance of each pollutant will be evaluated base on the effects and its results and then quality evaluation of surface water will be studied. In order to assess the relative importance of these pollutants primarily using TOPSIS software, prioritize these factors as one of the hierarchical analysis and then is modeled with decision tree method using Weka software, the importance of each factor is evaluated and if it does not meet the minimal importance of the decision tree will be removed. Results: The results obtained from the Topsis fuzzy analysis indicate that surface water and groundwater are exposed to pollution about 74% and 26% respectively among the six pollutants examined in this study. In addition, results obtaned from the hierarchical tree in software Weka has shown that the heat factor, soluble salts and industrial pollutants give impac factor or purity about 0.1338, 0.0523 and 1.2694 respectively. Conclusion: Surface water is at greater risk of being polluted compared with groundwater. The heat factor and low concentration of dissolved salts have the low impact and industrial pollutants are considered as the most influential factors in surface water pollution.

  14. Preface: Special Issue of the 5th International Symposium on Biological and Environmental Chemistry of DMS(P) and Related Compounds, Goa, India, 19–22 October 2010

    Digital Repository Service at National Institute of Oceanography (India)

    Stefels, J.; Shenoy, D.M.; Simo, R.; Malin, G.; Levasseur, M.; Belviso, S.; DileepKumar, M.

    variation in bacteria- mediated DMSP(d) to DMS conversion, as a function of nutrient limitation. Aeolian delivery of soluble iron that exhibits considerable spatio-temporal variability (Srinivas et al.) can also influence DMS production in iron- limited...

  15. Effective modification of particle surface properties using ultrasonic water mist

    DEFF Research Database (Denmark)

    Genina, Natalja; Räikkönen, Heikki; Heinämäki, Jyrki

    2009-01-01

    The goal of the present study was to design a new technique to modify particle surface properties and, through that, to improve flowability of poorly flowing drug thiamine hydrochloride and pharmaceutical sugar lactose monohydrate of two different grades. The powdered particles were supplied...... properties. It was found that rapid exposition of pharmaceutical materials by water mist resulted in the improvement of powder technical properties. The evident changes in flowability of coarser lactose were obviously due to smoothing of particle surface and decreasing in the level of fines with very slight...... increment in particle size. The changes in thiamine powder flow were mainly due to narrowing in particle size distribution where the tendency for better flow of finer lactose was related to surface and size modifications. The aqueous mist application did not cause any alteration of the crystal structures...

  16. Environmetric data interpretation to assess surface water quality

    International Nuclear Information System (INIS)

    Simeonova, P.; Papazova, P.; Lovchinov, V.

    2013-01-01

    Two multivariate statistical methods (Cluster analysis /CA/ and Principal components analysis /PCA/) were applied for model assessment of the water quality of Maritsa River and Tundja River on Bulgarian territory. The study used long-term monitoring data from many sampling sites characterized by various surface water quality indicators. The application of CA to the indicators results in formation of clusters showing the impact of biological, anthropogenic and eutrophication sources. For further assessment of the monitoring data, PCA was implemented, which identified, again, latent factors confirming, in principle, the clustering output. Their identification coincide correctly to the location of real pollution sources along the rivers catchments. The linkage of the sampling sites along the river flow by CA identified several special patterns separated by specific tracers levels. The apportionment models of the pollution determined the contribution of each one of identified pollution factors to the total concentration of each one of the water quality parameters. Thus, a better risk management of the surface water quality is achieved both on local and national level

  17. Adsorption of water, sulfates and chloride on arsenopyrite surface

    Science.gov (United States)

    Silva, Juliana C. M.; dos Santos, Egon C.; de Oliveira, Aline; Heine, Thomas; De Abreu, Heitor A.; Duarte, Hélio A.

    2018-03-01

    Arsenopyrite is one of the sulfide minerals responsible for acid rock drainage (ARD) and is one of the most hazardous in regions affected by mining activities. This phenomenon involves complex reaction mechanism. Although it is intensely investigated, there is a lack of consensus concerning the reaction mechanisms and more information is still necessary. In this work, the adsorption of water, hydrochloric acid, and sulfuric acid on arsenopyrite (001) surface was investigated by means of Density Functional calculations and the results compared to other sulfides aiming to understand the mineral/water interface. The interaction of the chemical species with the (001) FeAsS surface is the first step to understand the intricate oxidation mechanism of arsenopyrite. Molecular water adsorption on (001) FeAsS is more favored than the adsorption of sulfate favoring the dissolution of sulfates and enhancing its oxidation. The estimated adsorption energies of water, sulfates and chloride on other sulfide minerals are compared with the estimated values for arsenopyrite and the chemical reactivity differences discussed in detail.

  18. Impact on surface water quality due to coke oven effluents

    International Nuclear Information System (INIS)

    Ghose, M.K.; Roy, S.

    1994-01-01

    Large quantities of water are used for the quenching of hot coke and also for washing the gas produced from the coke ovens. Liquid effluents thus generated are highly polluted and are being discharged into the river Damodar without proper treatment. Four coke plants of Bharat Coking Coal Ltd.(BCCL) have been surveyed for characterization and to assess the impact on surface water quality. About 175-200 kilolitres of waste water is being generated per day by each of the coke plants. The concentration of CO, BOD, COD, TSS, phenol and cyanide in each of the coke plants were found to exceed the limits specified by pollution control board. Ammonia, oil and grease and TDS were found to be 19.33 mg/l, 7.81 mg/l, 1027.75 mg/l respectively. Types of samples collected, sampling frequencies, sample preservation and the results obtained have been discussed. (author). 6 refs., 1 tab., 1 fig

  19. Water heating solar system using collector with polycarbonate absorber surface

    Energy Technology Data Exchange (ETDEWEB)

    Souza, Luiz Guilherme Meira de; Sodre, Dilton; Cavalcanti, Eduardo Jose Cidade; Souza, Luiz Guilherme Vieira Meira de; Mendes, Jose Ubiragi de Lima [Universidade Federal do Rio Grande do Norte (UFRN), Natal, RN (Brazil)], e-mails: lguilherme@dem.ufrn.br, diltonsodre@ifba.edu.br, ubiragi@ct.ufrn.br

    2010-07-01

    It is presented s solar collector to be used in a heating water for bath system, whose main characteristics are low cost and easy fabrication and assembly processes. The collector absorber surface consists of a polycarbonate plate with an area of 1.5 m{sup 2}. The water inlet and outlet are made of PVC 50mm, and were coupled to a 6mm thick polycarbonate plate using fiberglass resin. A 200 liters thermal reservoir will be used. This reservoir is also alternative. The absorber heating system works under thermo-siphon regimen. Thermal parameters will be evaluated to prove the feasibility of the studied solar heating system to obtain bath water for a four people family. (author)

  20. Physical basis for river segmentation from water surface observables

    Science.gov (United States)

    Samine Montazem, A.; Garambois, P. A.; Calmant, S.; Moreira, D. M.; Monnier, J.; Biancamaria, S.

    2017-12-01

    With the advent of satellite missions such as SWOT we will have access to high resolution estimates of the elevation, slope and width of the free surface. A segmentation strategy is required in order to sub-sample the data set into reach master points for further hydraulic analyzes and inverse modelling. The question that arises is : what will be the best node repartition strategy that preserves hydraulic properties of river flow? The concept of hydraulic visibility introduced by Garambois et al. (2016) is investigated in order to highlight and characterize the spatio-temporal variations of water surface slope and curvature for different flow regimes and reach geometries. We show that free surface curvature is a powerful proxy for characterizing the hydraulic behavior of a reach since concavity of water surface is driven by variations in channel geometry that impacts the hydraulic properties of the flow. We evaluated the performance of three segmentation strategies by means of a well documented case, that of the Garonne river in France. We conclude that local extrema of free surface curvature appear as the best candidate for locating the segment boundaries for an optimal hydraulic representation of the segmented river. We show that for a given river different segmentation scales are possible: a fine-scale segmentation which is driven by fine-scale hydraulic to large-scale segmentation driven by large-scale geomorphology. The segmentation technique is then applied to high resolution GPS profiles of free surface elevation collected on the Negro river basin, a major contributor of the Amazon river. We propose two segmentations: a low-resolution one that can be used for basin hydrology and a higher resolution one better suited for local hydrodynamic studies.

  1. Probability of misclassifying biological elements in surface waters.

    Science.gov (United States)

    Loga, Małgorzata; Wierzchołowska-Dziedzic, Anna

    2017-11-24

    Measurement uncertainties are inherent to assessment of biological indices of water bodies. The effect of these uncertainties on the probability of misclassification of ecological status is the subject of this paper. Four Monte-Carlo (M-C) models were applied to simulate the occurrence of random errors in the measurements of metrics corresponding to four biological elements of surface waters: macrophytes, phytoplankton, phytobenthos, and benthic macroinvertebrates. Long series of error-prone measurement values of these metrics, generated by M-C models, were used to identify cases in which values of any of the four biological indices lay outside of the "true" water body class, i.e., outside the class assigned from the actual physical measurements. Fraction of such cases in the M-C generated series was used to estimate the probability of misclassification. The method is particularly useful for estimating the probability of misclassification of the ecological status of surface water bodies in the case of short sequences of measurements of biological indices. The results of the Monte-Carlo simulations show a relatively high sensitivity of this probability to measurement errors of the river macrophyte index (MIR) and high robustness to measurement errors of the benthic macroinvertebrate index (MMI). The proposed method of using Monte-Carlo models to estimate the probability of misclassification has significant potential for assessing the uncertainty of water body status reported to the EC by the EU member countries according to WFD. The method can be readily applied also in risk assessment of water management decisions before adopting the status dependent corrective actions.

  2. Iron oxidation kinetics and phosphorus immobilization at the groundwater-surface water interface

    NARCIS (Netherlands)

    van der Grift, Bas; Rozemeijer, Joachim; Griffioen, Jasper; van der Velde, Ype

    2014-01-01

    Eutrophication of freshwater environments following diffuse nutrient loads is a widely recognized water quality problem in catchments. Fluxes of non-point P sources to surface waters originate from surface runoff and flow from soil water and groundwater into surface water. The availability of P in

  3. Preparation of nanometer sized Mn doped Zn based oxides powder for DMS applications

    CSIR Research Space (South Africa)

    Das, J

    2009-01-01

    Full Text Available In order to study the size dependent DMS (Diluted Magnetic Semiconductor) behavior of Mn doped ZnO, the authors have systematically prepared a series of nanosized green powder based on Mn doped ZnO (Zn 1-x Mn x O, where x=0.02 - 0.1) materials using...

  4. Multiple sources of boron in urban surface waters and groundwaters

    Energy Technology Data Exchange (ETDEWEB)

    Hasenmueller, Elizabeth A., E-mail: eahasenm@wustl.edu; Criss, Robert E.

    2013-03-01

    Previous studies attribute abnormal boron (B) levels in streams and groundwaters to wastewater and fertilizer inputs. This study shows that municipal drinking water used for lawn irrigation contributes substantial non-point loads of B and other chemicals (S-species, Li, and Cu) to surface waters and shallow groundwaters in the St. Louis, Missouri, area. Background levels and potential B sources were characterized by analysis of lawn and street runoff, streams, rivers, springs, local rainfall, wastewater influent and effluent, and fertilizers. Urban surface waters and groundwaters are highly enriched in B (to 250 μg/L) compared to background levels found in rain and pristine, carbonate-hosted streams and springs (< 25 μg/L), but have similar concentrations (150 to 259 μg/L) compared to municipal drinking waters derived from the Missouri River. Other data including B/SO{sub 4}{sup 2-}−S and B/Li ratios confirm major contributions from this source. Moreover, sequential samples of runoff collected during storms show that B concentrations decrease with increased discharge, proving that elevated B levels are not primarily derived from combined sewer overflows (CSOs) during flooding. Instead, non-point source B exhibits complex behavior depending on land use. In urban settings B is rapidly mobilized from lawns during “first flush” events, likely representing surficial salt residues from drinking water used to irrigate lawns, and is also associated with the baseflow fraction, likely derived from the shallow groundwater reservoir that over time accumulates B from drinking water that percolates into the subsurface. The opposite occurs in small rural watersheds, where B is leached from soils by recent rainfall and covaries with the event water fraction. Highlights: ► Boron sources and loads differ between urban and rural watersheds. ► Wastewaters are not the major boron source in small St. Louis, MO watersheds. ► Municipal drinking water used for lawn

  5. Methane oxidation and methane fluxes in the ocean surface layer and deep anoxic waters

    Science.gov (United States)

    Ward, B. B.; Kilpatrick, K. A.; Novelli, P. C.; Scranton, M. I.

    1987-01-01

    Measured biological oxidation rates of methane in near-surface waters of the Cariaco Basin are compared with the diffusional fluxes computed from concentration gradients of methane in the surface layer. Methane fluxes and oxidation rates were investigated in surface waters, at the oxic/anoxic interface, and in deep anoxic waters. It is shown that the surface-waters oxidation of methane is a mechanism which modulates the flux of methane from marine waters to the atmosphere.

  6. Model study of multiphase DMS oxidation with a focus on halogens

    Directory of Open Access Journals (Sweden)

    R. von Glasow

    2004-01-01

    Full Text Available We studied the oxidation of dimethylsulfide (DMS in the marine boundary layer (MBL with a one-dimensional numerical model and focused on the influence of halogens. Our model runs show that there is still significant uncertainty about the end products of the DMS addition pathway, which is especially caused by uncertainty in the product yield of the reaction of the intermediate product methyl sulfinic acid (MSIA with OH. BrO strongly increases the importance of the addition branch in the oxidation of DMS even when present at mixing ratios smaller than 0.5pmol mol-1. The inclusion of halogen chemistry leads to higher DMS oxidation rates and smaller DMS to SO2 conversion efficiencies. The DMS to SO2 conversion efficiency is also drastically reduced under cloudy conditions. In cloud-free model runs between 5 and 15% of the oxidized DMS reacts further to particulate sulfur, in cloudy runs this fraction is almost 100%. Sulfate production by HOClaq and HOBraq is important in cloud droplets even for small Br- deficits and related small gas phase halogen concentrations. In general, more particulate sulfur is formed when halogen chemistry is included. A possible enrichment of HCO3- in fresh sea salt aerosol would increase pH values enough to make the reaction of S(IV* (=SO2,aq+HSO3-+SO32- with O3 dominant for sulfate production. It leads to a shift from methyl sulfonic acid (MSA to non-sea salt sulfate (nss-SO42- production but increases the total nss-SO42- only somewhat because almost all available sulfur is already oxidized to particulate sulfur in the base scenario. We discuss how realistic this is for the MBL. We found the reaction MSAaq+OH to contribute about 10% to the production of nss-SO42- in clouds. It is unimportant for cloud-free model runs. Overall we find that the presence of halogens leads to processes that decrease the albedo of stratiform clouds in the MBL.

  7. Agricultural insecticides threaten surface waters at the global scale.

    Science.gov (United States)

    Stehle, Sebastian; Schulz, Ralf

    2015-05-05

    Compared with nutrient levels and habitat degradation, the importance of agricultural pesticides in surface water may have been underestimated due to a lack of comprehensive quantitative analysis. Increasing pesticide contamination results in decreasing regional aquatic biodiversity, i.e., macroinvertebrate family richness is reduced by ∼30% at pesticide concentrations equaling the legally accepted regulatory threshold levels (RTLs). This study provides a comprehensive metaanalysis of 838 peer-reviewed studies (>2,500 sites in 73 countries) that evaluates, for the first time to our knowledge on a global scale, the exposure of surface waters to particularly toxic agricultural insecticides. We tested whether measured insecticide concentrations (MICs; i.e., quantified insecticide concentrations) exceed their RTLs and how risks depend on insecticide development over time and stringency of environmental regulation. Our analysis reveals that MICs occur rarely (i.e., an estimated 97.4% of analyses conducted found no MICs) and there is a complete lack of scientific monitoring data for ∼90% of global cropland. Most importantly, of the 11,300 MICs, 52.4% (5,915 cases; 68.5% of the sites) exceeded the RTL for either surface water (RTLSW) or sediments. Thus, the biological integrity of global water resources is at a substantial risk. RTLSW exceedances depend on the catchment size, sampling regime, and sampling date; are significantly higher for newer-generation insecticides (i.e., pyrethroids); and are high even in countries with stringent environmental regulations. These results suggest the need for worldwide improvements to current pesticide regulations and agricultural pesticide application practices and for intensified research efforts on the presence and effects of pesticides under real-world conditions.

  8. Dissolution of organic solvents from painted surfaces into water

    International Nuclear Information System (INIS)

    Wren, J.C.; Jobe, D.J.; Sanipelli, G.G.; Ball, J.M.

    2000-01-01

    The presence of volatile iodine in containment buildings is one of the major safety concerns in the potential event of nuclear reactor accidents. Organic impurities in containment water, originating from various painted structural surfaces and organic materials, could have a significant impact on iodine volatility following an accident. To determine the source and magnitude of organic impurities and their effects on time-dependent iodine volatility, the dissolution for organic constituents from paints used in reactor buildings has been studied under postulated accident conditions. The studies of the organic dissolution from carbon steel coupons coated with zinc-primed vinyl, epoxy-primed polyurethane or epoxy paints over the temperature range 25-90 deg C are reported. Relatively large activation energies were measured for the release of the principal organic compounds from painted surfaces, suggesting it is the release of the solvents from the paint matrix rather than their diffusion through the solution that is the rate determining step for the dissolution mechanism. The similarities in the values of activation energies for the dissolution of different organic compounds from the paints suggest the release rate is independent of the nature of the painted surface or the type of organic being released from the surface. These two observations indicate that it may be possible to write a generalized rate expression for the release of organic compounds from painted surfaces in containment following an accident. The possible implications of these results for predicting iodine volatility in containment are also discussed. (author)

  9. Geophysical characterisation of the groundwater-surface water interface

    Science.gov (United States)

    McLachlan, P. J.; Chambers, J. E.; Uhlemann, S. S.; Binley, A.

    2017-11-01

    Interactions between groundwater (GW) and surface water (SW) have important implications for water quantity, water quality, and ecological health. The subsurface region proximal to SW bodies, the GW-SW interface, is crucial as it actively regulates the transfer of nutrients, contaminants, and water between GW systems and SW environments. However, geological, hydrological, and biogeochemical heterogeneity in the GW-SW interface makes it difficult to characterise with direct observations. Over the past two decades geophysics has been increasingly used to characterise spatial and temporal variability throughout the GW-SW interface. Geophysics is a powerful tool in evaluating structural heterogeneity, revealing zones of GW discharge, and monitoring hydrological processes. Geophysics should be used alongside traditional hydrological and biogeochemical methods to provide additional information about the subsurface. Further integration of commonly used geophysical techniques, and adoption of emerging techniques, has the potential to improve understanding of the properties and processes of the GW-SW interface, and ultimately the implications for water quality and environmental health.

  10. Control of water infiltration into near surface LLW disposal units

    International Nuclear Information System (INIS)

    Schulz, R.K.; Ridky, R.W.; O'Donnell, E.

    1992-10-01

    The project objective is to assess means for controlling waste infiltration through waste disposal unit covers in humid regions. Experimental work is being performed in large scale lysimeters (70inch x 45inch x lOinch) at Beltsville, MD and results of the assessment are applicable to disposal of LLW, uranium mill tailings, hazardous waste, and sanitary landfills. Three concepts are under investigation: (1) resistive layer barrier, (2) conductive layer barrier, and bioengineering water management. The resistive layer barrier consists of compacted earth (clay). The conductive layer barrier is a special case of the capillary barrier and it requires a flow layer (e.g. fine sandy loam) over a capillary break. As long as unsaturated conditions am maintained water is conducted by the flow layer to below the waste. This barrier is most efficient at low flow rates and is thus best placed below a resistive layer barrier. Such a combination of the resistive layer over the conductive layer barrier promises to be highly effective provided there is no appreciable subsidence. Bioengineering water management is a surface cover that is designed to accommodate subsidence. It consists of impermeable panels which enhance run-off and limit infiltration. Vegetation is planted in narrow openings between panels to transpire water from below the panels. TWs system has successfully dewatered two lysimeters thus demonstrating that this procedure could be used for remedial action (''drying out'') existing water-logged disposal sites at low cost

  11. RIVER-RAD, Radionuclide Transport in Surface Waters

    International Nuclear Information System (INIS)

    1996-01-01

    1 - Description of program or function: RIVER-RAD assesses the potential fate of radionuclides released to rivers. The model is simplified in nature and is intended to provide guidance in determining the potential importance of the surface water pathway, relevant transport mechanisms, and key radionuclides in estimating radiological dose to man. 2 - Method of solution: A compartmental linear transfer model is used in RIVER-RAD. The river system model in the code is divided into reaches (compartments) of equal size, each with a sediment compartment below it. The movement of radionuclides is represented by a series of transfers between the reaches, and between the water and sediment compartments of each reach. Within each reach (for both the water and sediment compartments), the radionuclides are assumed to be uniformly mixed. Upward volatilization is allowed from the water compartment, and the transfer of radionuclides between the reaches is determined by the flow rate of the river. Settling and resuspension velocities determine the transfer of absorbed radionuclides between the water and sediment compartments. Radioactive decay and decay-product buildup are incorporated into all transport calculations for all radionuclide chains specified by the user. Each nuclide may have unique input and removal rates. Volatilization and radiological decay are considered as linear rate constants in the model. 3 - Restrictions on the complexity of the problem: None noted

  12. Cleaning the feed-water pipeline internal surfaces

    International Nuclear Information System (INIS)

    Podkopaev, V.A.

    1984-01-01

    The procedure of cleaning the feed-water pipeline internal surfaces at the Chernobylsk-4 power unit is described. Cleaning was conducted in five stages. Pipelines were cleaned from mechanical impurities at the first stage. At the second stage the pipelines were washing by water heated up to 80 deg C. At the third stage nitric acid was added to 95-100 deg C water the acid concentration in the circuit = 60 mg/l, purification period = 14 h. At the fourth stage hydrogen peroxide was added to the circuit at 95-100 deg C (the solution concentration was equal to 5-6 mg/l, the solution stayed in the circuit for 1 h 20 min). At the fifth stage sodium nitrite concentrated to 20 mg/l was introduced to the circuit in 75 minutes; this promoted strengthening of the oxide layer in the circuit on the base of nitric acid and hydrogen peroxide. Data on the water acidity in the circuit, water electric conductivity and iron concentration after the fourth stage and on completion of the circuit cleaning are presented. The described method of cleaning enables to save scarce reagents and use cheaper ones

  13. Cleaning the feed-water pipeline internal surfaces

    Energy Technology Data Exchange (ETDEWEB)

    Podkopaev, V.A.

    1984-12-01

    The procedure of cleaning the feed-water pipeline internal surfaces at the Chernobylsk-4 power unit is described. Cleaning was conducted in five stages. Pipelines were cleaned from mechanical impurities at the first stage. At the second stage the pipelines were washed by water heated up to 80 deg C. At the third stage nitric acid was added to 95-100 deg C water with the acid concentration in the circuit = 60 mg/l, purification period = 14 h. At the fourth stage hydrogen peroxide was added to the circuit at 95-100 deg C (the solution concentration was equal to 5-6 mg/l, the solution stayed in the circuit for 1 h 20 min). At the fifth stage sodium nitrite concentrated to 20 mg/l was introduced to the circuit in 75 minutes; this promoted strengthening of the oxide layer in the circuit on the base of nitric acid and hydrogen peroxide. Data on the water acidity in the circuit, water electric conductivity and iron concentration after the fourth stage and on completion of the circuit cleaning are presented. The described method of cleaning enables to save scarce reagents and use cheaper ones.

  14. Systems Reliability Framework for Surface Water Sustainability and Risk Management

    Science.gov (United States)

    Myers, J. R.; Yeghiazarian, L.

    2016-12-01

    framework will significantly improve the efficiency and precision of sustainable watershed management strategies through providing a better understanding of how watershed characteristics and environmental parameters affect surface water quality and sustainability. With microbial contamination posing a serious threat to the availability of clean water across the world, it is necessary to develop a framework that evaluates the safety and sustainability of water systems in respect to non-point source fecal microbial contamination. The concept of water safety is closely related to the concept of failure in reliability theory. In water quality problems, the event of failure can be defined as the concentration of microbial contamination exceeding a certain standard for usability of water. It is pertinent in watershed management to know the likelihood of such an event of failure occurring at a particular point in space and time. Microbial fate and transport are driven by environmental processes taking place in complex, multi-component, interdependent environmental systems that are dynamic and spatially heterogeneous, which means these processes and therefore their influences upon microbial transport must be considered stochastic and variable through space and time. A physics-based stochastic model of microbial dynamics is presented that propagates uncertainty using a unique sampling method based on artificial neural networks to produce a correlation between watershed characteristics and spatial-temporal probabilistic patterns of microbial contamination. These results are used to address the question of water safety through several sustainability metrics: reliability, vulnerability, resilience and a composite sustainability index. System reliability is described uniquely though the temporal evolution of risk along watershed points or pathways. Probabilistic resilience describes how long the system is above a certain probability of failure, and the vulnerability metric describes how

  15. Water Reclamation Using a Ceramic Nanofiltration Membrane and Surface Flushing with Ozonated Water

    Science.gov (United States)

    Hoang, Anh T.; Okuda, Tetsuji; Takeuchi, Haruka; Tanaka, Hiroaki; Nghiem, Long D.

    2018-01-01

    A new membrane fouling control technique using ozonated water flushing was evaluated for direct nanofiltration (NF) of secondary wastewater effluent using a ceramic NF membrane. Experiments were conducted at a permeate flux of 44 L/m2h to evaluate the ozonated water flushing technique for fouling mitigation. Surface flushing with clean water did not effectively remove foulants from the NF membrane. In contrast, surface flushing with ozonated water (4 mg/L dissolved ozone) could effectively remove most foulants to restore the membrane permeability. This surface flushing technique using ozonated water was able to limit the progression of fouling to 35% in transmembrane pressure increase over five filtration cycles. Results from this study also heighten the need for further development of ceramic NF membrane to ensure adequate removal of pharmaceuticals and personal care products (PPCPs) for water recycling applications. The ceramic NF membrane used in this study showed approximately 40% TOC rejection, and the rejection of PPCPs was generally low and highly variable. It is expected that the fouling mitigation technique developed here is even more important for ceramic NF membranes with smaller pore size and thus better PPCP rejection. PMID:29671797

  16. Water Reclamation Using a Ceramic Nanofiltration Membrane and Surface Flushing with Ozonated Water

    Directory of Open Access Journals (Sweden)

    Takahiro Fujioka

    2018-04-01

    Full Text Available A new membrane fouling control technique using ozonated water flushing was evaluated for direct nanofiltration (NF of secondary wastewater effluent using a ceramic NF membrane. Experiments were conducted at a permeate flux of 44 L/m2h to evaluate the ozonated water flushing technique for fouling mitigation. Surface flushing with clean water did not effectively remove foulants from the NF membrane. In contrast, surface flushing with ozonated water (4 mg/L dissolved ozone could effectively remove most foulants to restore the membrane permeability. This surface flushing technique using ozonated water was able to limit the progression of fouling to 35% in transmembrane pressure increase over five filtration cycles. Results from this study also heighten the need for further development of ceramic NF membrane to ensure adequate removal of pharmaceuticals and personal care products (PPCPs for water recycling applications. The ceramic NF membrane used in this study showed approximately 40% TOC rejection, and the rejection of PPCPs was generally low and highly variable. It is expected that the fouling mitigation technique developed here is even more important for ceramic NF membranes with smaller pore size and thus better PPCP rejection.

  17. Water response to ganglioside GM1 surface remodelling.

    Science.gov (United States)

    Brocca, P; Rondelli, V; Mallamace, F; Di Bari, M T; Deriu, A; Lohstroh, W; Del Favero, E; Corti, M; Cantu', L

    2017-01-01

    Gangliosides are biological glycolipids participating in rafts, structural and functional domains of cell membranes. Their headgroups are able to assume different conformations when packed on the surface of an aggregate, more lying or standing. Switching between different conformations is possible, and is a collective event. Switching can be induced, in model systems, by concentration or temperature increase, then possibly involving ganglioside-water interaction. In the present paper, the effect of GM1 ganglioside headgroup conformation on the water structuring and interactions is addressed. Depolarized Rayleigh Scattering, Raman Scattering, Quasielastic Neutron Scattering and NMR measurements were performed on GM1 ganglioside solutions, focusing on solvent properties. All used techniques agree in evidencing differences in the structure and dynamics of solvent water on different time-and-length scales in the presence of either GM1 headgroup conformations. In general, all results indicate that both the structural properties of solvent water and its interactions with the sugar headgroups of GM1 respond to surface remodelling. The extent of this modification is much higher than expected and, interestingly, ganglioside headgroups seem to turn from cosmotropes to chaotropes upon collective rearrangement from the standing- to the lying-conformation. In a biological perspective, water structure modulation could be one of the physico-chemical elements contributing to the raft strategy, both for rafts formation and persistence and for their functional aspects. In particular, the interaction with approaching bodies could be favoured or inhibited or triggered by complex-sugar-sequence conformational switch. This article is part of a Special Issue entitled "Science for Life" Guest Editor: Dr. Austen Angell, Dr. Salvatore Magazù and Dr. Federica Migliardo. Copyright © 2016 Elsevier B.V. All rights reserved.

  18. Surface Water Connectivity, Flow Pathways and Water Level Fluctuation in a Cold Region Deltaic Ecosystem

    Science.gov (United States)

    Peters, D. L.; Niemann, O.; Skelly, R.; Monk, W. A.; Baird, D. J.

    2017-12-01

    The Peace-Athabasca Delta (PAD) is a 6000 km2 deltaic floodplain ecosystem of international importance (Wood Buffalo National Park, Ramsar Convention, UNESCO World Heritage, and SWOT satellite water level calibration/validation site). The low-relief floodplain formed at the confluence of the Peace, Athabasca and Birch rivers with Lake Athabasca. More than 1000 wetland and lake basins have varying degrees of connectivity to the main flow system. Hydroperiod and water storage is influenced by ice-jam and open-water inundations and prevailing semi-arid climate that control water drawdown. Prior studies have identified pathways of river-to-wetland floodwater connection and historical water level fluctuation/trends as a key knowledge gaps, limiting our knowledge of deltaic ecosystem status and potential hydroecological responses to climate change and upstream water alterations to flow contributions. To address this knowledge gap, surface elevation mapping of the PAD has been conducted since 2012 using aerial remote sensing Light Detection and Ranging (LiDAR), plus thousands of ground based surface and bathymetric survey points tied to Global Positioning System (GPS) were obtained. The elevation information was used to develop a high resolution digital terrain model to simulate and investigate surface water connectivity. Importantly, the surveyed areas contain a set of wetland monitoring sites where ground-based surface water connectivity, water level/depth, water quality, and aquatic ecology (eg, vegetation, macroinvertebrate and muskrat) have been examined. The goal of this presentation is to present an assessment of: i) surface water fluctuation and connectivity for PAD wetland sites; ii) 40+ year inter-annual hydroperiod reconstruction for a perched basin using a combination of field measurements, remote sensing estimates, and historical documents; and iii) outline an approach to integrate newly available hydro-bio-geophysical information into a novel, multi

  19. First Derivative UV Spectra of Surface Water as a Monitor of Chlorination in Drinking Water Treatment

    Directory of Open Access Journals (Sweden)

    V. Zitko

    2001-01-01

    Full Text Available Many countries require the presence of free chlorine at about 0.1 mg/l in their drinking water supplies. For various reasons, such as cast-iron pipes or long residence times in the distribution system, free chlorine may decrease below detection limits. In such cases it is important to know whether or not the water was chlorinated or if nonchlorinated water entered the system by accident. Changes in UV spectra of natural organic matter in lakewater were used to assess qualitatively the degree of chlorination in the treatment to produce drinking water. The changes were more obvious in the first derivative spectra. In lakewater, the derivative spectra have a maximum at about 280 nm. This maximum shifts to longer wavelengths by up to 10 nm, decreases, and eventually disappears with an increasing dose of chlorine. The water treatment system was monitored by this technique for over 1 year and changes in the UV spectra of water samples were compared with experimental samples treated with known amounts of chlorine. The changes of the UV spectra with the concentration of added chlorine are presented. On several occasions, water, which received very little or no chlorination, may have entered the drinking water system. The results show that first derivative spectra are potentially a tool to determine, in the absence of residual chlorine, whether or not surface water was chlorinated during the treatment to produce potable water.

  20. Engineering Extreme Hydrophobic and Super Slippery Water Shedding Surfaces

    Science.gov (United States)

    McHale, Glen

    2017-04-01

    The intrinsic water repellency of a material is fundamentally determined by its surface chemistry, but alone this does not determine the ability of a surface to shed water. Physical factors such as the surface texture/topography, rigidity/flexibility, granularity/porosity combined with the intrinsic wetting properties of the liquid with the surface and whether it is infused by a lubricating liquid are equally important. In this talk I will outline fundamental, but simple, ideas on the topographic enhancement of surface chemistry to create superhydrophobicity, the adhesion of particles to liquid-air interfaces to create liquid marbles, elastocapillarity to create droplet wrapping, and lubricant impregnated surfaces to create completely mobile droplets [1-3]. I will discuss how these ideas have their origins in natural systems and surfaces, such as Lotus leaves, galling aphids and the Nepenthes pitcher plant. I will show how we have applied these concepts to study the wetting of granular systems, such as sand, to understand extreme soil water repellency. I will argue that relaxing the assumption that a solid substrate is fixed in shape and arrangement, can lead to the formation of liquid marbles, whereby a droplet self-coats in a hydrophobic powder/grains. I will show that the concepts of wetting and porosity blur as liquids penetrate into a porous or granular substrate. I will also discuss how lubricant impregnated super slippery surfaces can be used to study a pure constant contact angle mode of droplet evaporation [4]. Finally, I will show dewetting of a surface is not simply a video reversal of wetting [5], and I will give an example of the use of perfect hydrophobicity using the Leidenfrost effect to create a new type of low friction mechanical and hear engine [6]. References: [1] Shirtcliffe, N. J., et al., An introduction to superhydrophobicity. Advances in Colloid and Interface Science, vol. 161, pp.124-138 (2010). [2] McHale, G. & Newton, M. I. Liquid

  1. Horizon effects with surface waves on moving water

    Energy Technology Data Exchange (ETDEWEB)

    Rousseaux, Germain; Maissa, Philippe; Mathis, Christian; Coullet, Pierre [Universite de Nice-Sophia Antipolis, Laboratoire J-A Dieudonne, UMR CNRS-UNS 6621, Parc Valrose, 06108 Nice Cedex 02 (France); Philbin, Thomas G; Leonhardt, Ulf, E-mail: Germain.Rousseaux@unice.f [School of Physics and Astronomy, University of St Andrews, North Haugh, St Andrews KY16 9SS (United Kingdom)

    2010-09-15

    Surface waves on a stationary flow of water are considered in a linear model that includes the surface tension of the fluid. The resulting gravity-capillary waves experience a rich array of horizon effects when propagating against the flow. In some cases, three horizons (points where the group velocity of the wave reverses) exist for waves with a single laboratory frequency. Some of these effects are familiar in fluid mechanics under the name of wave blocking, but other aspects, in particular waves with negative co-moving frequency and the Hawking effect, were overlooked until surface waves were investigated as examples of analogue gravity (Schuetzhold R and Unruh W G 2002 Phys. Rev. D 66 044019). A comprehensive presentation of the various horizon effects for gravity-capillary waves is given, with emphasis on the deep water/ short wavelength case kh>>1, where many analytical results can be derived. A similarity of the state space of the waves to that of a thermodynamic system is pointed out.

  2. A Review of Heterogeneous Photocatalysis for Water and Surface Disinfection

    Directory of Open Access Journals (Sweden)

    John Anthony Byrne

    2015-03-01

    Full Text Available Photo-excitation of certain semiconductors can lead to the production of reactive oxygen species that can inactivate microorganisms. The mechanisms involved are reviewed, along with two important applications. The first is the use of photocatalysis to enhance the solar disinfection of water. It is estimated that 750 million people do not have accessed to an improved source for drinking and many more rely on sources that are not safe. If one can utilize photocatalysis to enhance the solar disinfection of water and provide an inexpensive, simple method of water disinfection, then it could help reduce the risk of waterborne disease. The second application is the use of photocatalytic coatings to combat healthcare associated infections. Two challenges are considered, i.e., the use of photocatalytic coatings to give “self-disinfecting” surfaces to reduce the risk of transmission of infection via environmental surfaces, and the use of photocatalytic coatings for the decontamination and disinfection of medical devices. In the final section, the development of novel photocatalytic materials for use in disinfection applications is reviewed, taking account of materials, developed for other photocatalytic applications, but which may be transferable for disinfection purposes.

  3. Eutrophication management in surface waters using lanthanum modified bentonite

    DEFF Research Database (Denmark)

    Copetti, Diego; Finsterle, Karin; Marziali, Laura

    2016-01-01

    This paper reviews the scientific knowledge on the use of a lanthanum modified bentonite (LMB) to manage eutrophication in surface water. The LMB has been applied in around 200 environments worldwide and it has undergone extensive testing at laboratory, mesocosm, and whole lake scales. The availa......This paper reviews the scientific knowledge on the use of a lanthanum modified bentonite (LMB) to manage eutrophication in surface water. The LMB has been applied in around 200 environments worldwide and it has undergone extensive testing at laboratory, mesocosm, and whole lake scales....... The available data underline a high efficiency for phosphorus binding. This efficiency can be limited by the presence of humic substances and competing oxyanions. Lanthanum concentrations detected during a LMB application are generally below acute toxicological threshold of different organisms, except in low...... alkalinity waters. To date there are no indications for long-term negative effects on LMB treated ecosystems, but issues related to La accumulation, increase of suspended solids and drastic resources depletion still need to be explored, in particular for sediment dwelling organisms. Application of LMB...

  4. WATER ICE AT THE SURFACE OF THE HD 100546 DISK

    Energy Technology Data Exchange (ETDEWEB)

    Honda, M. [Department of Physics, Kurume University School of Medicine, 67 Asahi-machi, Kurume, Fukuoka, 830-0011 (Japan); Kudo, T.; Terada, H.; Takato, N. [Subaru Telescope, National Astronomical Observatory of Japan, 650 North A’ohoku Place, Hilo, Hawaii 96720 (United States); Takatsuki, S.; Nakamoto, T. [Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Meguro, Tokyo 152-8551 (Japan); Inoue, A. K. [College of General Education, Osaka Sangyo University, Daito, Osaka 574-8530 (Japan); Fukagawa, M.; Tamura, M. [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan)

    2016-04-10

    We made near-infrared multicolor imaging observations of a disk around Herbig Be star HD 100546 using Gemini/NICI. K (2.2 μm), H{sub 2}O ice (3.06 μm), and L′ (3.8 μm) disk images were obtained and we found a 3.1 μm absorption feature in the scattered light spectrum, likely due to water ice grains at the disk surface. We compared the observed depth of the ice absorption feature with the disk model based on Oka et al., including the water ice photodesorption effect by stellar UV photons. The observed absorption depth can be explained by both the disk models with and without the photodesorption effect within the measurement accuracy, but the model with photodesorption effects is slightly more favored, implying that the UV photons play an important role in the survival/destruction of ice grains at the Herbig Ae/Be disk surface. Further improvement to the accuracy of the observations of the water ice absorption depth is needed to constrain the disk models.

  5. Soil and water characteristics of a young surface mine wetland

    Science.gov (United States)

    Andrew Cole, C.; Lefebvre, Eugene A.

    1991-05-01

    Coal companies are reluctant to include wetland development in reclamation plans partly due to a lack of information on the resulting characteristics of such sites. It is easier for coal companies to recreate terrestrial habitats than to attempt experimental methods and possibly face significant regulatory disapproval. Therefore, we studied a young (10 years) wetland on a reclaimed surface coal mine in southern Illinois so as to ascertain soil and water characteristics such that the site might serve as a model for wetland development on surface mines. Water pH was not measured because of equipment problems, but evidence (plant life, fish, herpetofauna) suggests suitable pH levels. Other water parameters (conductivity, salinity, alkalinity, chloride, copper, total hardness, iron, manganese, nitrate, nitrite, phosphate, and sulfate) were measured, and only copper was seen in potentially high concentrations (but with no obvious toxic effects). Soil variables measured included pH, nitrate, nitrite, ammonia, potassium, calcium, magnesium, manganese, aluminum, iron, sulfate, chloride, and percent organic matter. Soils were slightly alkaline and most parameters fell within levels reported for other studies on both natural and manmade wetlands. Aluminum was high, but this might be indicative more of large amounts complexed with soils and therefore unavailable, than amounts actually accessible to plants. Organic matter was moderate, somewhat surprising given the age of the system.

  6. WATER ICE AT THE SURFACE OF THE HD 100546 DISK

    International Nuclear Information System (INIS)

    Honda, M.; Kudo, T.; Terada, H.; Takato, N.; Takatsuki, S.; Nakamoto, T.; Inoue, A. K.; Fukagawa, M.; Tamura, M.

    2016-01-01

    We made near-infrared multicolor imaging observations of a disk around Herbig Be star HD 100546 using Gemini/NICI. K (2.2 μm), H 2 O ice (3.06 μm), and L′ (3.8 μm) disk images were obtained and we found a 3.1 μm absorption feature in the scattered light spectrum, likely due to water ice grains at the disk surface. We compared the observed depth of the ice absorption feature with the disk model based on Oka et al., including the water ice photodesorption effect by stellar UV photons. The observed absorption depth can be explained by both the disk models with and without the photodesorption effect within the measurement accuracy, but the model with photodesorption effects is slightly more favored, implying that the UV photons play an important role in the survival/destruction of ice grains at the Herbig Ae/Be disk surface. Further improvement to the accuracy of the observations of the water ice absorption depth is needed to constrain the disk models

  7. Global Occurrence and Emission of Rotaviruses to Surface Waters

    Directory of Open Access Journals (Sweden)

    Nicholas M. Kiulia

    2015-05-01

    Full Text Available Group A rotaviruses (RV are the major cause of acute gastroenteritis in infants and young children globally. Waterborne transmission of RV and the presence of RV in water sources are of major public health importance. In this paper, we present the Global Waterborne Pathogen model for RV (GloWPa-Rota model to estimate the global distribution of RV emissions to surface water. To our knowledge, this is the first model to do so. We review the literature to estimate three RV specific variables for the model: incidence, excretion rate and removal during wastewater treatment. We estimate total global RV emissions to be 2 × 1018 viral particles/grid/year, of which 87% is produced by the urban population. Hotspot regions with high RV emissions are urban areas in densely populated parts of the world, such as Bangladesh and Nigeria, while low emissions are found in rural areas in North Russia and the Australian desert. Even for industrialized regions with high population density and without tertiary treatment, such as the UK, substantial emissions are estimated. Modeling exercises like the one presented in this paper provide unique opportunities to further study these emissions to surface water, their sources and scenarios for improved management.

  8. SWOT, The Surface Water and Ocean Topography Satellite Mission (Invited)

    Science.gov (United States)

    Alsdorf, D.; Andreadis, K.; Bates, P. D.; Biancamaria, S.; Clark, E.; Durand, M. T.; Fu, L.; Lee, H.; Lettenmaier, D. P.; Mognard, N. M.; Moller, D.; Morrow, R. A.; Rodriguez, E.; Shum, C.

    2009-12-01

    Surface fresh water is essential for life, yet we have surprisingly poor knowledge of its variability in space and time. Similarly, ocean circulation fundamentally drives global climate variability, yet the ocean current and eddy field that affects ocean circulation and heat transport at the sub-mesoscale resolution and particularly near coastal and estuary regions, is poorly known. About 50% of the vertical exchange of water properties (nutrients, dissovled CO2, heat, etc) in the upper ocean is taking place at the sub-mesoscale. Measurements from the Surface Water and Ocean Topography satellite mission (SWOT) will make strides in understanding these processes and improving global ocean models for studying climate change. SWOT is a swath-based interferometric-altimeter designed to acquire elevations of ocean and terrestrial water surfaces at unprecedented spatial and temporal resolutions. The mission will provide measurements of storage changes in lakes, reservoirs, and wetlands as well as estimates of discharge in rivers. These measurements are important for global water and energy budgets, constraining hydrodynamic models of floods, carbon evasion through wetlands, and water management, especially in developing nations. Perhaps most importantly, SWOT measurements will provide a fundamental understanding of the spatial and temporal variations in global surface waters, which for many countries are the primary source of water. An on-going effort, the “virtual mission” (VM) is designed to help constrain the required height and slope accuracies, the spatial sampling (both pixels and orbital coverage), and the trade-offs in various temporal revisits. Example results include the following: (1) Ensemble Kalman filtering of VM simulations recover water depth and discharge, reducing the discharge RMSE from 23.2% to 10.0% over an 84-day simulation period, relative to a simulation without assimilation. (2) Ensemble-based data assimilation of SWOT like measurements yields

  9. Modeling global distribution of agricultural insecticides in surface waters.

    Science.gov (United States)

    Ippolito, Alessio; Kattwinkel, Mira; Rasmussen, Jes J; Schäfer, Ralf B; Fornaroli, Riccardo; Liess, Matthias

    2015-03-01

    Agricultural insecticides constitute a major driver of animal biodiversity loss in freshwater ecosystems. However, the global extent of their effects and the spatial extent of exposure remain largely unknown. We applied a spatially explicit model to estimate the potential for agricultural insecticide runoff into streams. Water bodies within 40% of the global land surface were at risk of insecticide runoff. We separated the influence of natural factors and variables under human control determining insecticide runoff. In the northern hemisphere, insecticide runoff presented a latitudinal gradient mainly driven by insecticide application rate; in the southern hemisphere, a combination of daily rainfall intensity, terrain slope, agricultural intensity and insecticide application rate determined the process. The model predicted the upper limit of observed insecticide exposure measured in water bodies (n = 82) in five different countries reasonably well. The study provides a global map of hotspots for insecticide contamination guiding future freshwater management and conservation efforts. Copyright © 2014 Elsevier Ltd. All rights reserved.

  10. Probing the hydration water diffusion of macromolecular surfaces and interfaces

    International Nuclear Information System (INIS)

    Ortony, Julia H; Cheng, Chi-Yuan; Franck, John M; Pavlova, Anna; Hunt, Jasmine; Han, Songi; Kausik, Ravinath

    2011-01-01

    We probe the translational dynamics of the hydration water surrounding the macromolecular surfaces of selected polyelectrolytes, lipid vesicles and intrinsically disordered proteins with site specificity in aqueous solutions. These measurements are made possible by the recent development of a new instrumental and methodological approach based on Overhauser dynamic nuclear polarization (DNP)-enhanced nuclear magnetic resonance (NMR) spectroscopy. This technique selectively amplifies 1 H NMR signals of hydration water around a spin label that is attached to a molecular site of interest. The selective 1 H NMR amplification within molecular length scales of a spin label is achieved by utilizing short-distance range (∼r -3 ) magnetic dipolar interactions between the 1 H spin of water and the electron spin of a nitroxide radical-based label. Key features include the fact that only minute quantities (<10 μl) and dilute (≥100 μM) sample concentrations are needed. There is no size limit on the macromolecule or molecular assembly to be analyzed. Hydration water with translational correlation times between 10 and 800 ps is measured within ∼10 A distance of the spin label, encompassing the typical thickness of a hydration layer with three water molecules across. The hydration water moving within this time scale has significant implications, as this is what is modulated whenever macromolecules or molecular assemblies undergo interactions, binding or conformational changes. We demonstrate, with the examples of polymer complexation, protein aggregation and lipid-polymer interaction, that the measurements of interfacial hydration dynamics can sensitively and site specifically probe macromolecular interactions.

  11. High prevalence of enteric viruses in untreated individual drinking water sources and surface water in Slovenia.

    Science.gov (United States)

    Steyer, Andrej; Torkar, Karmen Godič; Gutiérrez-Aguirre, Ion; Poljšak-Prijatelj, Mateja

    2011-09-01

    Waterborne infections have been shown to be important in outbreaks of gastroenteritis throughout the world. Although improved sanitary conditions are being progressively applied, fecal contaminations remain an emerging problem also in developed countries. The aim of our study was to investigate the prevalence of fecal contaminated water sources in Slovenia, including surface waters and groundwater sources throughout the country. In total, 152 water samples were investigated, of which 72 samples represents groundwater from individual wells, 17 samples from public collection supplies and 63 samples from surface stream waters. Two liters of untreated water samples were collected and concentrated by the adsorption/elution technique with positively charged filters followed by an additional ultracentrifugation step. Group A rotaviruses, noroviruses (genogroups I and II) and astroviruses were detected with real-time RT-PCR method in 69 (45.4%) out of 152 samples collected, of which 31/89 (34.8%) drinking water and 38/63 (60.3%) surface water samples were positive for at least one virus tested. In 30.3% of drinking water samples group A rotaviruses were detected (27/89), followed by noroviruses GI (2.2%; 2/89) and astroviruses (2.2%; 2/89). In drinking groundwater samples group A rotaviruses were detected in 27 out of 72 tested samples (37.5%), genogroup I noroviruses in two (2.8%), and human astroviruses in one (1.4%) samples. In surface water samples norovirus genogroup GII was the most frequently detected (41.3%; 26/63), followed by norovirus GI (33.3%; 21/63), human astrovirus (27.0%; 17/63) and group A rotavirus (17.5%; 11/63). Our study demonstrates relatively high percentage of groundwater contamination in Slovenia and, suggests that raw groundwater used as individual drinking water supply may constitute a possible source of enteric virus infections. In the future, testing for enteric viruses should be applied for drinking water sources in waterborne outbreaks

  12. Antitumor activity of [Pt(O,O'-acac)(γ-acac)(DMS)] in mouse xenograft model of breast cancer.

    Science.gov (United States)

    Muscella, A; Vetrugno, C; Migoni, D; Biagioni, F; Fanizzi, F P; Fornai, F; De Pascali, S A; Marsigliante, S

    2014-01-23

    The higher and selective cytotoxicity of [Pt(O,O'-acac)(γ-acac)(DMS)] toward cancer cell in both immortalized cell lines and in breast cancer cells in primary cultures, stimulated a pre-clinical study so as to evaluate its therapeutic potential in vivo. The efficacy of [Pt(O,O'-acac)(γ-acac)(DMS)] was assessed using a xenograft model of breast cancer developed by injection of MCF-7 cells in the flank of BALB/c nude mice. Treatment of solid tumor-bearing mice with [Pt(O,O'-acac)(γ-acac)(DMS)] induced up to 50% reduction of tumor mass compared with an average 10% inhibition recorded in cisplatin-treated animals. Thus, chemotherapy with [Pt(O,O'-acac)(γ-acac)(DMS)] was much more effective than cisplatin. We also demonstrated enhanced in vivo pharmacokinetics, biodistribution and tolerability of [Pt(O,O'-acac)(γ-acac)(DMS)] when compared with cisplatin administered in Wistar rats. Pharmacokinetics studies with [Pt(O,O'-acac)(γ-acac)(DMS)] revealed prolonged Pt persistence in systemic blood circulation and decreased nefrotoxicity and hepatotoxicity, major target sites of cisplatin toxicity. Overall, [Pt(O,O'-acac)(γ-acac)(DMS)] turned out to be extremely promising in terms of greater in vivo anticancer activity, reduced nephrotoxicity and acute toxicity compared with cisplatin.

  13. An operational analysis of Lake Surface Water Temperature

    Directory of Open Access Journals (Sweden)

    Emma K. Fiedler

    2014-07-01

    Full Text Available Operational analyses of Lake Surface Water Temperature (LSWT have many potential uses including improvement of numerical weather prediction (NWP models on regional scales. In November 2011, LSWT was included in the Met Office Operational Sea Surface Temperature and Ice Analysis (OSTIA product, for 248 lakes globally. The OSTIA analysis procedure, which has been optimised for oceans, has also been used for the lakes in this first version of the product. Infra-red satellite observations of lakes and in situ measurements are assimilated. The satellite observations are based on retrievals optimised for Sea Surface Temperature (SST which, although they may introduce inaccuracies into the LSWT data, are currently the only near-real-time information available. The LSWT analysis has a global root mean square difference of 1.31 K and a mean difference of 0.65 K (including a cool skin effect of 0.2 K compared to independent data from the ESA ARC-Lake project for a 3-month period (June to August 2009. It is demonstrated that the OSTIA LSWT is an improvement over the use of climatology to capture the day-to-day variation in global lake surface temperatures.

  14. Properties of water surface discharge at different pulse repetition rates

    Czech Academy of Sciences Publication Activity Database

    Ruma, R.; Hosseini, S.H.R.; Yoshihara, K.; Akiyama, M.; Sakugawa, T.; Lukeš, Petr; Akiyama, H.

    2014-01-01

    Roč. 116, č. 12 (2014), s. 123304-123304 ISSN 0021-8979 Grant - others:Rada Programu interní podpory projektů mezinárodní spolupráce AV ČR(CZ) M100431203 Program:M Institutional support: RVO:61389021 Keywords : plasma in air * water surface discharge * pulse frequency * hydrogen peroxide * organic dye Subject RIV: BL - Plasma and Gas Discharge Physics Impact factor: 2.183, year: 2014 http://dx.doi.org/ 10.1063/1.4896266

  15. Concentration of involatile salts at evaporating water surfaces

    International Nuclear Information System (INIS)

    Gardner, G.C.

    1988-02-01

    Safety cases for the PWR often need to know how much of the soluble salts in the water will evaporate with the steam during flashing and when the steam is discharged to the atmosphere. Some ideal evaporating systems to give guidance. Simple formulae are derived for the surface concentration relative to the bulk concentration. An analysis is also presented which derives a formula for the mass transfer process in the steam due to both diffusion and convection, which arises from the evaporation process. The convection process will usually dominate. (author)

  16. Cocaine and metabolites in waste and surface water across Belgium

    Energy Technology Data Exchange (ETDEWEB)

    Nuijs, Alexander L.N. van [Toxicological Centre, Department of Pharmaceutical Sciences, University of Antwerp (Ukraine), Universiteitsplein 1, 2610 Antwerp (Belgium)], E-mail: alexander.vannuijs@ua.ac.be; Pecceu, Bert [Laboratory for Ecophysiology, Biochemistry and Toxicology, Department of Biology, University of Antwerp (Ukraine), Groenenborgerlaan 171, 2020 Antwerp (Belgium); Theunis, Laetitia; Dubois, Nathalie; Charlier, Corinne [Laboratory of Clinical, Forensic and Environmental Toxicology, University of Liege, (ULg), CHU Sart-Tilman, 4000 Liege (Belgium); Jorens, Philippe G. [Department of Clinical Pharmacology/Clinical Toxicology, University of Antwerp (Ukraine), University Hospital of Antwerp, Universiteitsplein 1, 2610 Antwerp (Belgium); Bervoets, Lieven; Blust, Ronny [Laboratory for Ecophysiology, Biochemistry and Toxicology, Department of Biology, University of Antwerp (Ukraine), Groenenborgerlaan 171, 2020 Antwerp (Belgium); Neels, Hugo [Toxicological Centre, Department of Pharmaceutical Sciences, University of Antwerp (Ukraine), Universiteitsplein 1, 2610 Antwerp (Belgium); Laboratory of Toxicology, ZNA Stuivenberg, Lange Beeldekensstraat 267, 2060 Antwerp (Belgium); Covaci, Adrian [Toxicological Centre, Department of Pharmaceutical Sciences, University of Antwerp (Ukraine), Universiteitsplein 1, 2610 Antwerp (Belgium); Laboratory for Ecophysiology, Biochemistry and Toxicology, Department of Biology, University of Antwerp (Ukraine), Groenenborgerlaan 171, 2020 Antwerp (Belgium)

    2009-01-15

    Cocaine abuse, a growing social problem, is currently estimated from population surveys, consumer interviews and crime statistics. A new approach based on the analysis of cocaine (COC) and metabolites, benzoylecgonine (BE) and ecgonine methyl ester (EME), in water samples was applied to 28 rivers and 37 waste water treatment plants in Belgium using solid-phase extraction and liquid chromatography coupled to tandem mass spectrometry. While EME was undetectable, COC and BE were detectable with concentrations ranging from <1 to 753 ng/L and <1 to 2258 ng/L, respectively. BE concentrations were employed to calculate the local amount of abused cocaine. The highest values (up to 1.8 g/day cocaine per 1000 inhabitants) were found in large cities and during weekends. The estimation of cocaine abuse through water analysis can be executed on regular basis without cooperation of patients. It also gives clear geographical information, while prevention campaigns can easily be implemented and evaluated. - Cocaine consumption can be evaluated through analysis of waste and surface water.

  17. Cocaine and metabolites in waste and surface water across Belgium

    International Nuclear Information System (INIS)

    Nuijs, Alexander L.N. van; Pecceu, Bert; Theunis, Laetitia; Dubois, Nathalie; Charlier, Corinne; Jorens, Philippe G.; Bervoets, Lieven; Blust, Ronny; Neels, Hugo; Covaci, Adrian

    2009-01-01

    Cocaine abuse, a growing social problem, is currently estimated from population surveys, consumer interviews and crime statistics. A new approach based on the analysis of cocaine (COC) and metabolites, benzoylecgonine (BE) and ecgonine methyl ester (EME), in water samples was applied to 28 rivers and 37 waste water treatment plants in Belgium using solid-phase extraction and liquid chromatography coupled to tandem mass spectrometry. While EME was undetectable, COC and BE were detectable with concentrations ranging from <1 to 753 ng/L and <1 to 2258 ng/L, respectively. BE concentrations were employed to calculate the local amount of abused cocaine. The highest values (up to 1.8 g/day cocaine per 1000 inhabitants) were found in large cities and during weekends. The estimation of cocaine abuse through water analysis can be executed on regular basis without cooperation of patients. It also gives clear geographical information, while prevention campaigns can easily be implemented and evaluated. - Cocaine consumption can be evaluated through analysis of waste and surface water

  18. Microbial Monitoring of Surface Water in South Africa: An Overview

    Directory of Open Access Journals (Sweden)

    Brendan S. Wilhelmi

    2012-07-01

    Full Text Available Infrastructural problems force South African households to supplement their drinking water consumption from water resources of inadequate microbial quality. Microbial water quality monitoring is currently based on the Colilert®18 system which leads to rapidly available results. Using Escherichia coli as the indicator microorganism limits the influence of environmental sources on the reported results. The current system allows for understanding of long-term trends of microbial surface water quality and the related public health risks. However, rates of false positive for the Colilert®18-derived concentrations have been reported to range from 7.4% to 36.4%. At the same time, rates of false negative results vary from 3.5% to 12.5%; and the Colilert medium has been reported to provide for cultivation of only 56.8% of relevant strains. Identification of unknown sources of faecal contamination is not currently feasible. Based on literature review, calibration of the antibiotic-resistance spectra of Escherichia coli or the bifidobacterial tracking ratio should be investigated locally for potential implementation into the existing monitoring system. The current system could be too costly to implement in certain areas of South Africa where the modified H2S strip test might be used as a surrogate for the Colilert®18.

  19. Surface-water resources of Polecat Creek basin, Oklahoma

    Science.gov (United States)

    Laine, L.L.

    1956-01-01

    A compilation of basic data on surface waters in Polecat Creek basin is presented on a monthly basis for Heyburn Reservoir and for Polecat Creek at Heyburn, Okla. Chemical analyses are shown for five sites in the basin. Correlation of runoff records with those for nearby basins indicates that the average annual runoff of the basin above gaging station at Heyburn is 325 acre-feet per square mile. Estimated duration curves of daily flow indicate that under natural conditions there would be no flow in Polecat Creek at Heyburn (drainage area, 129 square miles) about 16 percent of the time on an average, and that the flow would be less than 3 cubic feet per second half of the time. As there is no significant base flow in the basin, comparable low flows during dry-weather periods may be expected in other parts of the basin. During drought periods Heyburn Reservoir does not sustain a dependable low-water flow in Polecat Creek. Except for possible re-use of the small sewage effluent from city of Sapulpa, dependable supplies for additional water needs on the main stem will require development of supplemental storage. There has been no regular program for collection of chemical quality data in the basin, but miscellaneous analyses indicate a water of suitable quality for municipal and agricultural uses in Heyburn Reservoir and Polecat Creek near Heyburn. One recent chemical analysis indicates the possibility of a salt pollution problem in the Creek near Sapulpa. (available as photostat copy only)

  20. Diversity of Salmonella isolates from central Florida surface waters.

    Science.gov (United States)

    McEgan, Rachel; Chandler, Jeffrey C; Goodridge, Lawrence D; Danyluk, Michelle D

    2014-11-01

    Identification of Salmonella serotypes is important for understanding the environmental diversity of the genus Salmonella. This study evaluates the diversity of Salmonella isolates recovered from 165 of 202 Central Florida surface water samples and investigates whether the serotype of the environmental Salmonella isolates can be predicted by a previously published multiplex PCR assay (S. Kim, J. G. Frye, J. Hu, P. J. Fedorka-Cray, R. Gautom, and D. S. Boyle, J. Clin. Microbiol. 44:3608-3615, 2006, http://dx.doi.org/10.1128/JCM.00701-06). Multiplex PCR was performed on 562 Salmonella isolates (as many as 36 isolates per water sample) to predict serotypes. Kauffmann-White serogrouping was used to confirm multiplex PCR pattern groupings before isolates were serotyped, analyzed by pulsed-field gel electrophoresis, and assayed for antimicrobial susceptibility. In 41.2% of the Salmonella-positive water samples, all Salmonella isolates had identical multiplex PCR patterns; in the remaining 58.8%, two or more multiplex PCR patterns were identified. Within each sample, isolates with matching multiplex PCR patterns had matching serogroups. The multiplex patterns of 495 isolates (88.1%) did not match any previously reported pattern. The remaining 68 isolates matched reported patterns but did not match the serotypes for those patterns. The use of the multiplex PCR allowed the number of isolates requiring further analysis to be reduced to 223. Thirty-three Salmonella enterica serotypes were identified; the most frequent included serotypes Muenchen, Rubislaw, Anatum, Gaminara, and IV_50:z4,z23:-. A majority (141/223) of Salmonella isolates clustered into one genotypic group. Salmonella isolates in Central Florida surface waters are serotypically, genotypically, and phenotypically (in terms of antimicrobial susceptibility) diverse. While isolates could be grouped as different or potentially the same using multiplex PCR, the multiplex PCR pattern did not predict the Salmonella

  1. Occurrence of estrogenic activities in second-grade surface water and ground water in the Yangtze River Delta, China

    International Nuclear Information System (INIS)

    Shi, Wei; Hu, Guanjiu; Chen, Sulan; Wei, Si; Cai, Xi; Chen, Bo; Feng, Jianfang; Hu, Xinxin; Wang, Xinru; Yu, Hongxia

    2013-01-01

    Second-grade surface water and ground water are considered as the commonly used cleanest water in the Yangtze River Delta, which supplies centralized drinking water and contains rare species. However, some synthetic chemicals with estrogenic disrupting activities are detectable. Estrogenic activities in the second-grade surface water and ground water were surveyed by a green monkey kidney fibroblast (CV-1) cell line based ER reporter gene assay. Qualitative and quantitative analysis were further conducted to identify the responsible compounds. Estrogen receptor (ER) agonist activities were present in 7 out of 16 surface water and all the ground water samples. Huaihe River and Yangtze River posed the highest toxicity potential. The highest equivalent (2.2 ng E 2 /L) is higher than the predicted no-effect-concentration (PNEC). Bisphenol A (BPA) contributes to greater than 50% of the total derived equivalents in surface water, and the risk potential in this region deserves more attention and further research. -- Highlights: •Estrogenic activities were present in second-grade surface water and ground water. •Most of the detected equivalents were higher than the predicted no-effect-concentration of E 2 . •ER-EQ 20–80 ranges showed that samples in Huaihe River and Yangtze River posed the highest toxicity. •Bisphenol A contributes to most of the instrumentally derived equivalents in surface water. -- Estrogenic activities were observed in second-grade surface water and ground water in Yangtze River Delta, and BPA was the responsible contaminant

  2. Water Transport and Removal in PEMFC Gas Flow Channel with Various Water Droplet Locations and Channel Surface Wettability

    Directory of Open Access Journals (Sweden)

    Yanzhou Qin

    2018-04-01

    Full Text Available Water transport and removal in the proton exchange membrane fuel cell (PEMFC is critically important to fuel cell performance, stability, and durability. Water emerging locations on the membrane-electrode assembly (MEA surface and the channel surface wettability significantly influence the water transport and removal in PEMFC. In most simulations of water transport and removal in the PEMFC flow channel, liquid water is usually introduced at the center of the MEA surface, which is fortuitous, since water droplet can emerge randomly on the MEA surface in PEMFC. In addition, the commonly used no-slip wall boundary condition greatly confines the water sliding features on hydrophobic MEA/channel surfaces, degrading the simulation accuracy. In this study, water droplet is introduced with various locations along the channel width direction on the MEA surface, and water transport and removal is investigated numerically using an improved model incorporating the sliding flow property by using the shear wall boundary condition. It is found that the water droplet can be driven to the channel sidewall by aerodynamics when the initial water location deviates from the MEA center to a certain amount, forming the water corner flow in the flow channel. The channel surface wettability on the water transport is also studied and is shown to have a significant impact on the water corner flow in the flow channel.

  3. 78 FR 70076 - Aging Management of Internal Surfaces, Fire Water Systems, Atmospheric Storage Tanks, and...

    Science.gov (United States)

    2013-11-22

    ... Systems, Atmospheric Storage Tanks, and Corrosion Under Insulation AGENCY: Nuclear Regulatory Commission... Internal Surfaces, Fire Water Systems, Atmospheric Storage Tanks, and Corrosion Under Insulation.'' This LR... related to internal surface aging effects, fire water systems, atmospheric storage tanks, and corrosion...

  4. Water surface coverage effects on reactivity of plasma oxidized Ti films

    International Nuclear Information System (INIS)

    Pranevicius, L.; Pranevicius, L.L.; Vilkinis, P.; Baltaragis, S.; Gedvilas, K.

    2014-01-01

    Highlights: • The reactivity of Ti films immersed in water vapor plasma depends on the surface water coverage. • The adsorbed water monolayers are disintegrated into atomic constituents on the hydrophilic TiO 2 under plasma radiation. • The TiO 2 surface covered by water multilayer loses its ability to split adsorbed water molecules under plasma radiation. - Abstract: The behavior of the adsorbed water on the surface of thin sputter deposited Ti films maintained at room temperature was investigated in dependence on the thickness of the resulting adsorbed water layer, controllably injecting water vapor into plasma. The surface morphology and microstructure were used to characterize the surfaces of plasma treated titanium films. Presented experimental results showed that titanium films immersed in water vapor plasma at pressure of 10–100 Pa promoted the photocatalytic activity of overall water splitting. The surfaces of plasma oxidized titanium covered by an adsorbed hydroxyl-rich island structure water layer and activated by plasma radiation became highly chemically reactive. As water vapor pressure increased up to 300–500 Pa, the formed water multilayer diminished the water oxidation and, consequently, water splitting efficiency decreased. Analysis of the experimental results gave important insights into the role an adsorbed water layer on surface of titanium exposed to water vapor plasma on its chemical activity and plasma activated electrochemical processes, and elucidated the surface reactions that could lead to the split of water molecules

  5. Drinking Water Sources with Surface Intakes from LDHH source data, Geographic NAD83, LOSCO (1999) [drinking_water_surface_intakes_LDHH_1999

    Data.gov (United States)

    Louisiana Geographic Information Center — This is a point dataset for 87 public drinking water sources with surface intakes. It was derived from a larger statewide general drinking water source dataset...

  6. Novel Americium Treatment Process for Surface Water and Dust Suppression Water

    International Nuclear Information System (INIS)

    Tiepel, E.W.; Pigeon, P.; Nesta, S.; Anderson, J.

    2006-01-01

    The Rocky Flats Environmental Technology Site (RFETS), a former nuclear weapons production plant, has been remediated under CERCLA and decommissioned to become a National Wildlife Refuge. The site conducted this cleanup effort under the Rocky Flats Cleanup Agreement (RFCA) that established limits for the discharge of surface and process waters from the site. At the end of 2004, while a number of process buildings were undergoing decommissioning, routine monitoring of a discharge pond (Pond A-4) containing approximately 28 million gallons of water was discovered to have been contaminated with a trace amount of Americium-241 (Am-241). While the amount of Am-241 in the pond waters was very low (0.5 - 0.7 pCi/l), it was above the established Colorado stream standard of 0.15 pCi/l for release to off site drainage waters. The rapid successful treatment of these waters to the regulatory limit was important to the site for two reasons. The first was that the pond was approaching its hold-up limit. Without rapid treatment and release of the Pond A-4 water, typical spring run-off would require water management actions to other drainages onsite or a mass shuttling of water for disposal. The second reason was that this type of contaminated water had not been treated to the stringent stream standard at Rocky Flats before. Technical challenges in treatment could translate to impacts on water and secondary waste management, and ultimately, cost impacts. All of the technical challenges and specific site criteria led to the conclusion that a different approach to the treatment of this problem was necessary and a crash treatability program to identify applicable treatment techniques was undertaken. The goal of this program was to develop treatment options that could be implemented very quickly and would result in the generation of no high volume secondary waste that would be costly to dispose. A novel chemical treatment system was developed and implemented at the RFETS to treat Am

  7. Natural Sunlight Shapes Crude Oil-Degrading Bacterial Communities in Northern Gulf of Mexico Surface Waters

    OpenAIRE

    Bacosa, Hernando P.; Liu, Zhanfei; Erdner, Deana L.

    2015-01-01

    Following the Deepwater Horizon (DWH) spill in 2010, an enormous amount of oil was observed in the deep and surface waters of the northern Gulf of Mexico. Surface waters are characterized by intense sunlight and high temperature during summer. While the oil-degrading bacterial communities in the deep-sea plume have been widely investigated, the effect of natural sunlight on those in oil polluted surface waters remains unexplored to date. In this study, we incubated surface water from the DWH ...

  8. Screening and human health risk assessment of pharmaceuticals and their transformation products in Dutch surface waters and drinking water

    NARCIS (Netherlands)

    de Jongh, C.M.; Kooij, P.J.F.; de Voogt, P.; ter Laak, T.L.

    2012-01-01

    Numerous studies describe the presence of pharmaceuticals in the water cycle, while their transformation products are usually not included. In the current study 17 common pharmaceuticals and 9 transformation products were monitored in the Dutch waters, including surface waters, pre-treated surface

  9. Instability of confined water films between elastic surfaces.

    Science.gov (United States)

    de Beer, Sissi; 't Mannetje, Dieter; Zantema, Sietske; Mugele, Frieder

    2010-03-02

    We investigated the dynamics of nanometer thin water films at controlled ambient humidity adsorbed onto two atomically smooth mica sheets upon rapidly bringing the surfaces into contact. Using a surface forces apparatus (SFA) in imaging mode, we found that the water films break up into a distribution of drops with a typical thickness of a few nanometers and a characteristic lateral size and spacing of several micrometers. Whereas the characteristic length is found to be independent of the ambient humidity, the characteristic time of the breakup decreases from approximately 1 to 0.01 s with increasing humidity. The existence of characteristic length and time scales shows that this breakup is controlled by an instability rather than a conventional nucleation and growth mechanism for SFA experiments. These findings cannot be explained by a dispersion-driven instability mechanism. In contrast, a model involving the elastic energies for the deformation of both the mica sheets and the underlying glue layer correctly reproduces the scaling of the characteristic length and time with humidity.

  10. Studying groundwater and surface water interactions using airborne remote sensing in Heihe River basin, northwest China

    OpenAIRE

    Liu, C.; Liu, J.; Hu, Y.; Zheng, C.

    2015-01-01

    Managing surface water and groundwater as a unified system is important for water resource exploitation and aquatic ecosystem conservation. The unified approach to water management needs accurate characterization of surface water and groundwater interactions. Temperature is a natural tracer for identifying surface water and groundwater interactions, and the use of remote sensing techniques facilitates basin-scale temperature measurement. This study focuses on the Heihe River basin, the second...

  11. Hydraulic "fracking": are surface water impacts an ecological concern?

    Science.gov (United States)

    Burton, G Allen; Basu, Niladri; Ellis, Brian R; Kapo, Katherine E; Entrekin, Sally; Nadelhoffer, Knute

    2014-08-01

    Use of high-volume hydraulic fracturing (HVHF) in unconventional reservoirs to recover previously inaccessible oil and natural gas is rapidly expanding in North America and elsewhere. Although hydraulic fracturing has been practiced for decades, the advent of more technologically advanced horizontal drilling coupled with improved slickwater chemical formulations has allowed extensive natural gas and oil deposits to be recovered from shale formations. Millions of liters of local groundwaters are utilized to generate extensive fracture networks within these low-permeability reservoirs, allowing extraction of the trapped hydrocarbons. Although the technology is relatively standardized, the geographies and related policies and regulations guiding these operations vary markedly. Some ecosystems are more at risk from these operations than others because of either their sensitivities or the manner in which the HVHF operations are conducted. Generally, the closer geographical proximity of the susceptible ecosystem to a drilling site or a location of related industrial processes, the higher the risk of that ecosystem being impacted by the operation. The associated construction of roads, power grids, pipelines, well pads, and water-extraction systems along with increased truck traffic are common to virtually all HVHF operations. These operations may result in increased erosion and sedimentation, increased risk to aquatic ecosystems from chemical spills or runoff, habitat fragmentation, loss of stream riparian zones, altered biogeochemical cycling, and reduction of available surface and hyporheic water volumes because of withdrawal-induced lowering of local groundwater levels. The potential risks to surface waters from HVHF operations are similar in many ways to those resulting from agriculture, silviculture, mining, and urban development. Indeed, groundwater extraction associated with agriculture is perhaps a larger concern in the long term in some regions. Understanding the

  12. Quality of surface-water supplies in the Triangle area of North Carolina, water year 2009

    Science.gov (United States)

    Pfeifle, C. A.; Giorgino, M. J.; Rasmussen, R. B.

    2014-01-01

    Surface-water supplies are important sources of drinking water for residents in the Triangle area of North Carolina, which is located within the upper Cape Fear and Neuse River Basins. Since 1988, the U.S. Geological Survey and a consortium of governments have tracked water-quality conditions and trends in several of the area’s water-supply lakes and streams. This report summarizes data collected through this cooperative effort, known as the Triangle Area Water Supply Monitoring Project, during October 2008 through September 2009. Major findings for this period include: - Annual precipitation was approximately 20 percent below the long-term mean (average) annual precipitation. - Streamflow was below the long-term mean at the 10 project streamgages during most of the year. - More than 7,000 individual measurements of water quality were made at a total of 26 sites—15 in the Neuse River Basin and 11 in the Cape Fear River Basin. Forty-seven water-quality properties and constituents were measured. - All observations met North Carolina water-quality standards for water temperature, pH, hardness, chloride, fluoride, sulfate, nitrate, arsenic, cadmium, chromium, lead, nickel, and selenium. - North Carolina water-quality standards were exceeded one or more times for dissolved oxygen, dissolved oxygen percent saturation, chlorophyll a, mercury, copper, iron, manganese, silver, and zinc. Exceedances occurred at 23 sites—13 in the Neuse River Basin and 10 in the Cape Fear River Basin. - Stream samples collected during storm events contained elevated concentrations of 18 water-quality constituents compared to samples collected during non-storm events. - Concentrations of nitrogen and phosphorus were within ranges observed during previous years. - Five reservoirs had chlorophyll a concentrations in excess of 40 micrograms per liter at least once during 2009: Little River Reservoir, Falls Lake, Cane Creek Reservoir, University Lake, and Jordan Lake.

  13. Integrated modeling of groundwater–surface water interactions in a tile-drained agricultural field

    NARCIS (Netherlands)

    Rosemeijer, J.C.; Velde, van der Y.; McLaren, R.G.; Geer, van F.C.; Broers, H.P.; Bierkens, M.F.P.

    2010-01-01

    Understanding the dynamics of groundwater–surface water interaction is needed to evaluate and simulate water and solute transport in catchments. However, direct measurements of the contributions of different flow routes from specific surfaces within a catchment toward the surface water are rarely

  14. Reducing phosphorus loading of surface water using iron-coated sand

    NARCIS (Netherlands)

    Groenenberg, J.E.; Chardon, W.J.; Koopmans, G.F.

    2013-01-01

    Phosphorus losses from agricultural soils is an important source of P in surface waters leading to surface water quality impairment. In addition to reducing P inputs, mitigation measures are needed to reduce P enrichment of surface waters. Because drainage of agricultural land by pipe drainage is an

  15. The Carbon Dioxide System in the Baltic Sea Surface Waters

    Energy Technology Data Exchange (ETDEWEB)

    Wesslander, Karin

    2011-05-15

    The concentration of carbon dioxide (CO{sub 2}) in the atmosphere is steadily increasing because of human activities such as fossil fuel burning. To understand how this is affecting the planet, several pieces of knowledge of the CO{sub 2} system have to be investigated. One piece is how the coastal seas, which are used by people and influenced by industrialization, are functioning. In this thesis, the CO{sub 2} system in the Baltic Sea surface water has been investigated using observations from the last century to the present. The Baltic Sea is characterized of a restricted water exchange with the open ocean and a large inflow of river water. The CO{sub 2} system, including parameters such as pH and partial pressure of CO{sub 2} (pCO{sub 2}), has large seasonal and inter-annual variability in the Baltic Sea. These parameters are affected by several processes, such as air-sea gas exchange, physical mixing, and biological processes. Inorganic carbon is assimilated in the primary production and pCO{sub 2} declines to approx150 muatm in summer. In winter, pCO{sub 2} levels increase because of prevailing mineralization and mixing processes. The wind-mixed surface layer deepens to the halocline (approx60 m) and brings CO{sub 2}- enriched water to the surface. Winter pCO{sub 2} may be as high as 600 muatm in the surface water. The CO{sub 2} system is also exposed to short-term variations caused by the daily biological cycle and physical events such as upwelling. A cruise was made in the central Baltic Sea to make synoptic measurements of oceanographic, chemical, and meteorological parameters with high temporal resolution. Large short-term variations were found in pCO{sub 2} and oxygen (O{sub 2}), which were highly correlated. The diurnal variation of pCO{sub 2} was up to 40 muatm. The CO{sub 2} system in the Baltic Sea changed as the industrialization increased around 1950, which was demonstrated using a coupled physical-biogeochemical model of the CO{sub 2} system

  16. Use of multiple water surface flow constructed wetlands for non-point source water pollution control.

    Science.gov (United States)

    Li, Dan; Zheng, Binghui; Liu, Yan; Chu, Zhaosheng; He, Yan; Huang, Minsheng

    2018-05-02

    Multiple free water surface flow constructed wetlands (multi-FWS CWs) are a variety of conventional water treatment plants for the interception of pollutants. This review encapsulated the characteristics and applications in the field of ecological non-point source water pollution control technology. The roles of in-series design and operation parameters (hydraulic residence time, hydraulic load rate, water depth and aspect ratio, composition of influent, and plant species) for performance intensification were also analyzed, which were crucial to achieve sustainable and effective contaminants removal, especially the retention of nutrient. The mechanism study of design and operation parameters for the removal of nitrogen and phosphorus was also highlighted. Conducive perspectives for further research on optimizing its design/operation parameters and advanced technologies of ecological restoration were illustrated to possibly interpret the functions of multi-FWS CWs.

  17. Connectivity between surface and deep waters determines prokaryotic diversity in the North Atlantic Deep Water.

    Science.gov (United States)

    Frank, Alexander H; Garcia, Juan A L; Herndl, Gerhard J; Reinthaler, Thomas

    2016-06-01

    To decipher the influence of depth stratification and surface provincialism on the dark ocean prokaryotic community composition, we sampled the major deep-water masses in the eastern North Atlantic covering three biogeographic provinces. Their diversity was evaluated using ordination and canonical analysis of 454 pyrotag sequences. Variance partitioning suggested that 16% of the variation in the bacterial community composition was based on depth stratification while 9% of the variation was due to geographic location. General linear mixed effect models showed that the community of the subsurface waters was connected to the dark ocean prokaryotic communities in different biogeographic provinces. Cluster analysis indicated that some prokaryotic taxa are specific to distinct regions in bathypelagic water masses. Taken together, our data suggest that the dark ocean prokaryotic community composition of the eastern North Atlantic is primed by the formation and the horizontal transport of water masses. © 2016 Society for Applied Microbiology and John Wiley & Sons Ltd.

  18. CLASSIFICATION OF WATER SURFACES USING AIRBORNE TOPOGRAPHIC LIDAR DATA

    Directory of Open Access Journals (Sweden)

    J. Smeeckaert

    2013-05-01

    Full Text Available Accurate Digital Terrain Models (DTM are inevitable inputs for mapping areas subject to natural hazards. Topographic airborne laser scanning has become an established technique to characterize the Earth surface: lidar provides 3D point clouds allowing a fine reconstruction of the topography. For flood hazard modeling, the key step before terrain modeling is the discrimination of land and water surfaces within the delivered point clouds. Therefore, instantaneous shoreline, river borders, inland waters can be extracted as a basis for more reliable DTM generation. This paper presents an automatic, efficient, and versatile workflow for land/water classification of airborne topographic lidar data. For that purpose, a classification framework based on Support Vector Machines (SVM is designed. First, a restricted set of features, based only 3D lidar point coordinates and flightline information, is defined. Then, the SVM learning step is performed on small but well-targeted areas thanks to an automatic region growing strategy. Finally, label probabilities given by the SVM are merged during a probabilistic relaxation step in order to remove pixel-wise misclassification. Results show that survey of millions of points are labelled with high accuracy (>95% in most cases for coastal areas, and >89% for rivers and that small natural and anthropic features of interest are still well classified though we work at low point densities (0.5–4 pts/m2. Our approach is valid for coasts and rivers, and provides a strong basis for further discrimination of land-cover classes and coastal habitats.

  19. Assessment of heavy metal pollution in surface water

    International Nuclear Information System (INIS)

    Kar, D.; Sur, P.; Mandal, S. K.; Saha, T.; Kole, R. K.

    2008-01-01

    A total of 96 surface water samples collected from river Ganga in West Bengal during 2004-05 was analyzed for p H, EC, Fe, Mn, Zn, Cu, Cd, Cr, Pb and Ni. The p H was found in the alkaline range (7.21-8.32), while conductance was obtained in the range of 0.225-0.615 mmhos/cm. Fe, Mn, Zn, Ni, Cr and Pb were detected in more than 92% of the samples in the range of 0.025-5.49, 0.025-2.72, 0.012-0.370, 0.012-0.375, 0.001-0.044 and 0.001- 0.250 mg/L,respectively, whereas Cd and Cu were detected only in 20 and 36 samples (0.001-0.003 and 0.0034.032 mg/L). Overall seasonal variation was significant for Fe, Mn, Cd and Cr. The maximum mean concentration of Fe (1.520 m a ) was observed in summer, Mn (0.423 mg/L) in monsoon but Cd (0.003 mg/L) and Cr (0.020 m a ) exhibited their maximum during the winter season. Fe, Mn and Cd concentration also varied with the change of sampling locations. The highest mean concentrations (mg/L) of Fe (1.485), Zn (0.085) and Cu (0.006) were observed at Palta, those for Mn (0.420) and Ni (0.054) at Berhampore, whereas the maximum of Pb (0.024 mg/L) and Cr (0.018 mg/L) was obtained at the downstream station, Uluberia. All in all, the dominance of various heavy metals in the surface water of the river Ganga followed the sequence: Fe > Mn Ni > Cr > Pb > Zn > Cu > Cd. A significant positive correlation was exhibited for conductivity with Cd and Cr of water but Mn exhibited a negative correlation with conductivity

  20. Forecasting in an integrated surface water-ground water system: The Big Cypress Basin, South Florida

    Science.gov (United States)

    Butts, M. B.; Feng, K.; Klinting, A.; Stewart, K.; Nath, A.; Manning, P.; Hazlett, T.; Jacobsen, T.

    2009-04-01

    The South Florida Water Management District (SFWMD) manages and protects the state's water resources on behalf of 7.5 million South Floridians and is the lead agency in restoring America's Everglades - the largest environmental restoration project in US history. Many of the projects to restore and protect the Everglades ecosystem are part of the Comprehensive Everglades Restoration Plan (CERP). The region has a unique hydrological regime, with close connection between surface water and groundwater, and a complex managed drainage network with many structures. Added to the physical complexity are the conflicting needs of the ecosystem for protection and restoration, versus the substantial urban development with the accompanying water supply, water quality and flood control issues. In this paper a novel forecasting and real-time modelling system is presented for the Big Cypress Basin. The Big Cypress Basin includes 272 km of primary canals and 46 water control structures throughout the area that provide limited levels of flood protection, as well as water supply and environmental quality management. This system is linked to the South Florida Water Management District's extensive real-time (SCADA) data monitoring and collection system. Novel aspects of this system include the use of a fully distributed and integrated modeling approach and a new filter-based updating approach for accurately forecasting river levels. Because of the interaction between surface- and groundwater a fully integrated forecast modeling approach is required. Indeed, results for the Tropical Storm Fay in 2008, the groundwater levels show an extremely rapid response to heavy rainfall. Analysis of this storm also shows that updating levels in the river system can have a direct impact on groundwater levels.

  1. Photoinduced degradation of carbaryl in a wetland surface water.

    Science.gov (United States)

    Miller, Penney L; Chin, Yu-Ping

    2002-11-06

    The photoinduced degradation of carbaryl (1-naphthyl-N-methyl carbamate) was studied in a wetland's surface water to examine the photochemical processes influencing its transformation. For this particular wetland water, at high pH, it was difficult to delineate the photolytic contribution to the overall degradation of carbaryl. At lower pH values, the extent of the degradation attributable to indirect pathways, that is, in the presence of naturally occurring photosensitizers, increased significantly. Moreover, the photoenhanced degradation at the lower pH values was found to be seasonally and spatially dependent. Analysis of water samples revealed two primary constituents responsible for the observed indirect photolytic processes: nitrate and dissolved natural organic matter (NOM). Nitrate in the wetland appears at high concentrations (> or =1 mM) seasonally after the application of fertilizers in the watershed and promotes contaminant destruction through the photochemical production of the hydroxyl radical (HO*). The extent of the observed indirect photolysis pathway appears to be dependent upon the concentration of nitrates and the presence of HO* scavengers such as dissolved NOM and carbonate alkalinity. Paradoxically, during low-nitrate events (<50 microM), NOM becomes the principal photosensitizer through either the production of HO*, direct energy transfer from the excited triplet state, and/or production of an unidentified transient species.

  2. Pesticide volatilization from small surface waters : rationale of a new parameterization for TOXSWA

    NARCIS (Netherlands)

    Jacobs, C.M.J.; Adriaanse, P.I.

    2012-01-01

    In the TOXSWA (TOXic substances in Surface WAters) model volatilization of pesticides from surface water is computed because it may be an important component of the mass balance of pesticides in water bodies. Here, we briefly review the physics of air-water gas exchange relevant in this context. A

  3. Concentration data for anthropogenic organic compounds in ground water, surface water, and finished water of selected community water systems in the United States, 2002-05

    Science.gov (United States)

    Carter, Janet M.; Delzer, Gregory C.; Kingsbury, James A.; Hopple, Jessica A.

    2007-01-01

    The National Water-Quality Assessment Program of the U.S. Geological Survey began implementing Source Water-Quality Assessments (SWQAs) in 2001 that focus on characterizing the quality of source water and finished water of aquifers and major rivers used by some of the larger community water systems (CWSs) in the United States. As used for SWQA studies, source water is the raw (ambient) water collected at the supply well prior to water treatment (for ground water) or the raw (ambient) water collected from the river near the intake (for surface water), and finished water is the water that is treated and ready to be delivered to consumers. Finished water is collected before entering the distribution system. SWQA studies are conducted in two phases, and the objectives of SWQA studies are twofold: (1) to determine the occurrence and, for rivers, seasonal changes in concentrations of a broad list of anthropogenic organic compounds (AOCs) in aquifers and rivers that have some of the largest withdrawals for drinking-water supply (phase 1), and (2) for those AOCs found to occur most frequently in source water, characterize the extent to which these compounds are present in finished water (phase 2). These objectives were met for SWQA studies by collecting ground-water and surface-water (source) samples and analyzing these samples for 258 AOCs during phase 1. Samples from a subset of wells and surface-water sites located in areas with substantial agricultural production in the watershed were analyzed for 19 additional AOCs, for a total of 277 compounds analyzed for SWQA studies. The 277 compounds were classified according to the following 13 primary use or source groups: (1) disinfection by-products; (2) fumigant-related compounds; (3) fungicides; (4) gasoline hydrocarbons, oxygenates, and oxygenate degradates; (5) herbicides and herbicide degradates; (6) insecticides and insecticide degradates; (7) manufacturing additives; (8) organic synthesis compounds; (9) pavement- and

  4. Foundational Report Series: Advanced Distribution Management Systems for Grid Modernization, Business Case Calculations for DMS

    Energy Technology Data Exchange (ETDEWEB)

    Lu, Xiaonan [Argonne National Lab. (ANL), Argonne, IL (United States); Singh, Ravindra [Argonne National Lab. (ANL), Argonne, IL (United States); Wang, Jianhui [Argonne National Lab. (ANL), Argonne, IL (United States); Reilly, James T. [Reilly Associates, Pittson, PA (United States)

    2017-01-01

    Distribution Management System (DMS) applications require a substantial commitment of technical and financial resources. In order to proceed beyond limited-scale demonstration projects, utilities must have a clear understanding of the business case for committing these resources that recognizes the total cost of ownership. Many of the benefits provided by investments in DMSs do not translate easily into monetary terms, making cost-benefit calculations difficult. For example, Fault Location Isolation and Service Restoration (FLISR) can significantly reduce customer outage duration and improve reliability. However, there is no well-established and universally-accepted procedure for converting these benefits into monetary terms that can be compared directly to investment costs. This report presents a methodology to analyze the benefits and costs of DMS applications as fundamental to the business case.

  5. High resolution remote sensing of water surface patterns

    Science.gov (United States)

    Woodget, A.; Visser, F.; Maddock, I.; Carbonneau, P.

    2012-12-01

    The assessment of in-stream habitat availability within fluvial environments in the UK traditionally includes the mapping of patterns which appear on the surface of the water, known as 'surface flow types' (SFTs). The UK's River Habitat Survey identifies ten key SFTs, including categories such as rippled flow, upwelling, broken standing waves and smooth flow. SFTs result from the interaction between the underlying channel morphology, water depth and velocity and reflect the local flow hydraulics. It has been shown that SFTs can be both biologically and hydraulically distinct. SFT mapping is usually conducted from the river banks where estimates of spatial coverage are made by eye. This approach is affected by user subjectivity and inaccuracies in the spatial extent of mapped units. Remote sensing and specifically the recent developments in unmanned aerial systems (UAS) may now offer an alternative approach for SFT mapping, with the capability for rapid and repeatable collection of very high resolution imagery from low altitudes, under bespoke flight conditions. This PhD research is aimed at investigating the mapping of SFTs using high resolution optical imagery (less than 10cm) collected from a helicopter-based UAS flown at low altitudes (less than 100m). This paper presents the initial findings from a series of structured experiments on the River Arrow, a small lowland river in Warwickshire, UK. These experiments investigate the potential for mapping SFTs from still and video imagery of different spatial resolutions collected at different flying altitudes and from different viewing angles (i.e. vertical and oblique). Imagery is processed using 3D mosaicking software to create orthophotos and digital elevation models (DEM). The types of image analysis which are tested include a simple, manual visual assessment undertaken in a GIS environment, based on the high resolution optical imagery. In addition, an object-based image analysis approach which makes use of the

  6. Characteristics of meter-scale surface electrical discharge propagating along water surface at atmospheric pressure

    International Nuclear Information System (INIS)

    Hoffer, Petr; Sugiyama, Yuki; Hosseini, S Hamid R; Akiyama, Hidenori; Lukes, Petr; Akiyama, Masahiro

    2016-01-01

    This paper reports physical characteristics of water surface discharges. Discharges were produced by metal needle-to-water surface geometry, with the needle electrode driven by 47 kV (FWHM) positive voltage pulses of 2 µ s duration. Propagation of discharges along the water surface was confined between glass plates with 2 mm separation. This allowed generation of highly reproducible 634 mm-long plasma filaments. Experiments were performed using different atmospheres: air, N 2 , and O 2 , each at atmospheric pressure. Time- and spatially-resolved spectroscopic measurements revealed that early spectra of discharges in air and nitrogen atmospheres were dominated by N 2 2nd positive system. N 2 radiation disappeared after approx. 150 ns, replaced by emissions from atomic hydrogen. Spectra of discharges in O 2 atmosphere were dominated by emissions from atomic oxygen. Time- and spatially-resolved emission spectra were used to determine temperatures in plasma. Atomic hydrogen emissions showed excitation temperature of discharges in air to be about 2  ×  10 4 K. Electron number densities determined by Stark broadening of the hydrogen H β line reached a maximum value of ∼10 18 cm −3 just after plasma initiation. Electron number densities and temperatures depended only slightly on distance from needle electrode, indicating formation of high conductivity leader channels. Direct observation of discharges by high speed camera showed that the average leader head propagation speed was 412 km · s −1 , which is substantially higher value than that observed in experiments with shorter streamers driven by lower voltages. (paper)

  7. CdS nanobubbles and Cd-DMS nanosheets: solvothermal synthesis and formation mechanism.

    Science.gov (United States)

    Feng, Miao; Zhan, Hongbing

    2013-02-01

    CdS nanobubbles and Cd-DMS nanosheets have been prepared by a solvothermal method from a solution of Cd2+ in dimethyl sulfoxide in the absence of elemental S. A formation mechanism for the nanobubble morphology arising during the CdS nanocrystal growth has been proposed, based on the results of transmission electron microscopy and photoluminescence spectrophotometry. The correlation of the morphology with reaction time was also suggested, and may be applicable to the solvothermal synthesis of other nanomaterials.

  8. DMSP and DMS dynamics and microzooplankton grazing in the Labrador Sea: application of the dilution technique

    Science.gov (United States)

    Wolfe, Gordon V.; Levasseur, Maurice; Cantin, Guy; Michaud, Sonia

    2000-12-01

    We adapted the dilution technique to study microzooplankton grazing of algal dimethylsulfoniopropionate (DMSP) vs. Chl a, and to estimate the impact of microzooplankton grazing on dimethyl sulfide (DMS) production in the Labrador Sea. Phytoplankton numbers were dominated by autotrophic nanoflagellates in the Labrador basin, but diatoms and colonial Phaeocystis pouchetii contributed significantly to phytomass at several high chlorophyll stations and on the Newfoundland and Greenland shelfs. Throughout the region, growth of algal Chl a and DMSP was generally high (0.2-1 d -1), but grazing rates were lower and more variable, characteristic of the early spring bloom period. Production and consumption of Chl a vs. DMSP followed no clear pattern, and sometimes diverged greatly, likely because of their differing distributions among algal prey taxa and size class. In several experiments where Phaeocystis was abundant, we observed DMS production proportional to grazing rate, and we found clear evidence of DMS production by this haptophyte following physical stress such as sparging or filtration. It is possible that grazing-activated DMSP cleavage by Phaeocystis contributes to grazer deterrence: protozoa and copepods apparently avoided healthy colonies (as judged by relative growth and grazing rates of Chl a and DMSP), and grazing of Phaeocystis was significant only at one station where cells were in poor condition. Although we hoped to examine selective grazing on or against DMSP-containing algal prey, the dilution technique cannot differentiate selective ingestion and varying digestion rates of Chl a and DMSP. We also found that the dilution method alone was poorly suited for assessing the impact of grazing on dissolved sulfur pools, because of rapid microbial consumption and the artifactual release of DMSP and DMS during filtration. Measuring and understanding the many processes affecting organosulfur cycling by the microbial food web in natural populations remain a

  9. Surface integrity analysis of abrasive water jet-cut surfaces of friction stir welded joints

    Czech Academy of Sciences Publication Activity Database

    Kumar, R.; Chattopadhyaya, S.; Dixit, A. R.; Bora, B.; Zeleňák, Michal; Foldyna, Josef; Hloch, Sergej; Hlaváček, Petr; Ščučka, Jiří; Klich, Jiří; Sitek, Libor; Vilaca, P.

    2017-01-01

    Roč. 88, č. 5 (2017), s. 1687-1701 ISSN 0268-3768 R&D Projects: GA MŠk(CZ) LO1406; GA MŠk ED2.1.00/03.0082 Institutional support: RVO:68145535 Keywords : friction stir welding (FSW) * abrasive water jet (AWJ) * optical profilometer * topography * surface roughness Subject RIV: JQ - Machines ; Tools OBOR OECD: Mechanical engineering Impact factor: 2.209, year: 2016 http://link.springer.com/article/10.1007/s00170-016-8776-0

  10. Protocol for quantitative tracing of surface water with synthetic DNA

    Science.gov (United States)

    Foppen, J. W.; Bogaard, T. A.

    2012-04-01

    Based on experiments we carried out in 2010 with various synthetic single stranded DNA markers with a size of 80 nucleotides (ssDNA; Foppen et al., 2011), we concluded that ssDNA can be used to carry out spatially distributed multi-tracer experiments in the environment. Main advantages are in principle unlimited amount of tracers, environmental friendly and tracer recovery at very high dilution rates (detection limit is very low). However, when ssDNA was injected in headwater streams, we found that at selected downstream locations, the total mass recovery was less than 100%. The exact reason for low mass recovery was unknown. In order to start identifying the cause of the loss of mass in these surface waters, and to increase our knowledge of the behaviour of synthetic ssDNA in the environment, we examined the effect of laboratory and field protocols working with artificial DNA by performing numerous batch experiments. Then, we carried out several field tests in different headwater streams in the Netherlands and in Luxembourg. The laboratory experiments consisted of a batch of water in a vessel with in the order of 10^10 ssDNA molecules injected into the batch. The total duration of each experiment was 10 hour, and, at regular time intervals, 100 µl samples were collected in a 1.5 ml Eppendorf vial for qPCR analyses. The waters we used ranged from milliQ water to river water with an Electrical Conductivity of around 400 μS/cm. The batch experiments were performed in different vessel types: polyethylene bottles, polypropylene copolymer bottles , and glass bottles. In addition, two filter types were tested: 1 µm pore size glass fibre filters and 0.2 µm pore size cellulose acetate filters. Lastly, stream bed sediment was added to the batch experiments to quantify interaction of the DNA with sediment. For each field experiment around 10^15 ssDNA molecules were injected, and water samples were collected 100 - 600 m downstream of the point of injection. Additionally

  11. A robust Multi-Band Water Index (MBWI) for automated extraction of surface water from Landsat 8 OLI imagery

    Science.gov (United States)

    Wang, Xiaobiao; Xie, Shunping; Zhang, Xueliang; Chen, Cheng; Guo, Hao; Du, Jinkang; Duan, Zheng

    2018-06-01

    Surface water is vital resources for terrestrial life, while the rapid development of urbanization results in diverse changes in sizes, amounts, and quality of surface water. To accurately extract surface water from remote sensing imagery is very important for water environment conservations and water resource management. In this study, a new Multi-Band Water Index (MBWI) for Landsat 8 Operational Land Imager (OLI) images is proposed by maximizing the spectral difference between water and non-water surfaces using pure pixels. Based on the MBWI map, the K-means cluster method is applied to automatically extract surface water. The performance of MBWI is validated and compared with six widely used water indices in 29 sites of China. Results show that our proposed MBWI performs best with the highest accuracy in 26 out of the 29 test sites. Compared with other water indices, the MBWI results in lower mean water total errors by a range of 9.31%-25.99%, and higher mean overall accuracies and kappa coefficients by 0.87%-3.73% and 0.06-0.18, respectively. It is also demonstrated for MBWI in terms of robustly discriminating surface water from confused backgrounds that are usually sources of surface water extraction errors, e.g., mountainous shadows and dark built-up areas. In addition, the new index is validated to be able to mitigate the seasonal and daily influences resulting from the variations of the solar condition. MBWI holds the potential to be a useful surface water extraction technology for water resource studies and applications.

  12. WRAP Module 1 data management system (DMS) software design description (SDD)

    International Nuclear Information System (INIS)

    Weidert, J.R.

    1996-01-01

    Revision 2 of the Waste Receiving and Processing (WRAP) Module 1 Data Management System (DMS) Preliminary Software Design Description (PSDD) provides a high-level design description of the system. The WRAP 1 DMS is required to collect, store, and report data related to certification, tracking, packaging, repackaging, processing, and shipment of waste processed or stored at the WRAP 1 facility. The WRAP 1 DMS SDD is used as the primary medium for communication software design information. This release provides design descriptions for the following process modules produced under Phase 1 of the development effort: Receiving Drum or Box Containers Process Routing and Picklists; Waste Inventory by Location and/or Container Relationships; LLW Process Glovebox Facility Radiologic Material Inventory Check (partial); Shipping (partial production); Drum or Box NDE Operations; and Drum or Box NDA Operations Data Review (partial production). In addition, design descriptions are included for the following process modules scheduled for development under Phases 2 and 3: Activity Comment; LLW RWM Glovebox Sample Management; TRU Process Glovebox; TRU RWM Glovebox; and TRUPACT Processing. Detailed design descriptions for Reports and Facility Metrics have also been provided for in Revision 2 of this document

  13. epiDMS: Data Management and Analytics for Decision-Making From Epidemic Spread Simulation Ensembles.

    Science.gov (United States)

    Liu, Sicong; Poccia, Silvestro; Candan, K Selçuk; Chowell, Gerardo; Sapino, Maria Luisa

    2016-12-01

    Carefully calibrated large-scale computational models of epidemic spread represent a powerful tool to support the decision-making process during epidemic emergencies. Epidemic models are being increasingly used for generating forecasts of the spatial-temporal progression of epidemics at different spatial scales and for assessing the likely impact of different intervention strategies. However, the management and analysis of simulation ensembles stemming from large-scale computational models pose challenges, particularly when dealing with multiple interdependent parameters, spanning multiple layers and geospatial frames, affected by complex dynamic processes operating at different resolutions. We describe and illustrate with examples a novel epidemic simulation data management system, epiDMS, that was developed to address the challenges that arise from the need to generate, search, visualize, and analyze, in a scalable manner, large volumes of epidemic simulation ensembles and observations during the progression of an epidemic. epiDMS is a publicly available system that facilitates management and analysis of large epidemic simulation ensembles. epiDMS aims to fill an important hole in decision-making during healthcare emergencies by enabling critical services with significant economic and health impact. © The Author 2016. Published by Oxford University Press for the Infectious Diseases Society of America. All rights reserved. For permissions, e-mail journals.permissions@oup.com.

  14. Dental Management Survey Brazil (DMS-BR): creation and validation of a management instrument

    Science.gov (United States)

    Gonzales, Paola Sampaio; Martins, Ismar Eduardo; Biazevic, Maria Gabriela Haye; Silva, Paulo Roberto da; Michel-Crosato, Edgard

    2017-04-10

    Questionnaires for the assessment of knowledge and self-perception can be useful to diagnose what a dentist knows about management and administration. The aim of the present study was to create and validate the Dental Management Survey Brazil (DMS-BR) scale, based on meetings with experts in the field. After having elaborated the first version, 10 audits were performed in dental offices in order to produce the final version, which included nine dimensions: location, patient, finance, marketing, competition, quality, staff, career, and productivity. The accuracy of the instrument was measured by intrarater and interrater reliability. In the validation phase, 247 Brazilian dentists answered a web-based questionnaire. The data were processed using Stata 13.0 and the significance level was set at 95%. The instrument had intrarater and interrater reliability (ICC-0.93 and 0.94). The overall average of respondents for the DMS-BR scale was 3.77 (SD = 0.45). Skewness and kurtosis were below absolute values 3 and 7, respectively. Internal validity measured by Cronbach's alpha was 0.925 and the correlation of each dimension with the final result of the DMS-BR ranged between 0.606 and 0.810. Correlation with the job satisfaction scale was 0.661. The SEM data ranged between 0.80 and 0.56. The questionnaire presented satisfactory indicators of dentists' self-perception about management and administration activities.

  15. Current status of surface water pollution in Punjab

    International Nuclear Information System (INIS)

    Bashir, M.T.; Ghauri, Moin-ud-Din

    2001-01-01

    Eleven years investigations (1988-99) on river Ravi revealed that U.C. canal with a capacity of 220 m/sup 3//s at the tail and Q.B. Link canal with capacity of 410 m/sup 3//s are mainly responsible for higher flows during dry season. A decreasing trend has been observed in the DO levels indicating increasing pollution. An increasing trend has been observed in BOD, SS, TDS and Indicators. Even with the discharge of pollution from U.C. canal, Hudiara Nullah and Lahore city BOD at Balkoi was unexpectedly low. Problems confronting environment engineers regarding surface water pollution control has been highlighted and their solutions has been recommended. (author)

  16. Use of Radiotracers to Study Surface Water Processes

    International Nuclear Information System (INIS)

    2015-03-01

    This publication represents a sound knowledge base for the conduct of radiotracer studies in the environment, with papers on radiotracer methodology, radiation protection and regulation, data analysis and modelling. Environmental case histories from five Member States - Australia, Brazil, France, the Republic of Korea and Sweden - provide information on conducting studies involving he use of radioactive tracers. These case histories are not meant as guidelines for preparing a field study but can rather serve as examples of the type, caution and extent of work involved in environmental studies using radiotracers. This publication can provide guidance for conducting potential future training events in the use of radioactive traces in the environment and can serve as a key reference to all concerned directly with surface water processes

  17. Application of surface geophysics to ground-water investigations

    Science.gov (United States)

    Zohdy, Adel A.R.; Eaton, Gordon P.; Mabey, Don R.

    1974-01-01

    This manual reviews the standard methods of surface geophysics applicable to ground-water investigations. It covers electrical methods, seismic and gravity methods, and magnetic methods. The general physical principles underlying each method and its capabilities and limitations are described. Possibilities for non-uniqueness of interpretation of geophysical results are noted. Examples of actual use of the methods are given to illustrate applications and interpretation in selected geohydrologic environments. The objective of the manual is to provide the hydrogeologist with a sufficient understanding of the capabilities, imitations, and relative cost of geophysical methods to make sound decisions as to when to use of these methods is desirable. The manual also provides enough information for the hydrogeologist to work with a geophysicist in designing geophysical surveys that differentiate significant hydrogeologic changes.

  18. Purification of fuel and nitrate contaminated ground water using a free water surface constructed wetland plant

    Energy Technology Data Exchange (ETDEWEB)

    Machate, T.; Heuermann, E.; Schramm, K.W.; Kettrup, A.

    1999-10-01

    Contaminated ground water from a former coke plant site was purified in a free water surface (FWS) constructed wetland plant during a 3-mo short-term experiment. The pilot plant (total surface area 27 m{sup 2}) was filled with a 1 m thick lava-gravel substrate planted with cattail (Typha spp.) and bulrush (Scirpus lacustrls). Major contaminants were low to moderate concentrations of polycyclic aromatic hydrocarbons, BTEX, nitrate, and nitrite. The wetland was dosed at hydraulic loading rates of q{sub A} = 4.8 and 9.6 cm d{sup {minus}1} with a hydraulic residence time (HRT) of 13.7 and 6.8 d. The surface removal rates of PAH were between 98.8 and 1914 mg m{sup {minus}2} d{sup {minus}1}. Efficiency was always {gt}99%. Extraction of lava gravel showed that approx. 0.4% of the applied PAH were retained on the substratum. The ratio of {Sigma}2,3-ring PAH and {Sigma}4,5,6-ring PAH showed a shift from 1:0.11 in water to 1:2.5 in lava. The removal of BTEX was {gt}99%, but might be in part due to volatilization. The efficiency in the removal of nitrate was 91% and of nitrite was 97%. Purification performance was not influenced by hydraulic loading rates or after die-back of the macrophytes.

  19. The implications of economic development, climate change and European Water Policy on surface water quality threats

    Directory of Open Access Journals (Sweden)

    Jolanta Dąbrowska

    2017-06-01

    Full Text Available The paper presents historical background, up-to-date situation and future perspectives for the development of nutrient pollution threats to European surface water quality, as well as the evolution of the approach to water pollution. Utilized agricultural area in European countries is slightly diminishing, however the consumption of mineral fertilisers is steadily increasing. The consumption in Europe in the years 2015–2030 is projected to increase by 10%, and in the world by 20%. Both climate changes leading to the increase of temperature even of ca. 6°C (in comparison to the pre-industrial period and accelerated soil erosion due to high intensity rainfall cause increased productivity of water ecosystems. Those aspects have to be taken into consideration in water management. Due to legal regulations introduced in the last twenty years, wastewater treatment has been made more effective and population connected to wastewater treatment systems has increased. The improvement has been seen mainly in eastern and southern parts of Europe. After the implementation of Water Framework Directive theories regarding modern water management have been developed, with the aim to increase the ecosystem’s capacity and its resilience to climate changes and anthropopressure.

  20. Evaporation of tiny water aggregation on solid surfaces with different wetting properties.

    Science.gov (United States)

    Wang, Shen; Tu, Yusong; Wan, Rongzheng; Fang, Haiping

    2012-11-29

    The evaporation of a tiny amount of water on the solid surface with different wettabilities has been studied by molecular dynamics simulations. From nonequilibrium MD simulations, we found that, as the surface changed from hydrophobic to hydrophilic, the evaporation speed did not show a monotonic decrease as intuitively expected, but increased first, and then decreased after it reached a maximum value. The analysis of the simulation trajectory and calculation of the surface water interaction illustrate that the competition between the number of water molecules on the water-gas surface from where the water molecules can evaporate and the potential barrier to prevent those water molecules from evaporating results in the unexpected behavior of the evaporation. This finding is helpful in understanding the evaporation on biological surfaces, designing artificial surfaces of ultrafast water evaporating, or preserving water in soil.

  1. An updated climatology of surface dimethlysulfide concentrations and emission fluxes in the global ocean

    Science.gov (United States)

    Lana, A.; Bell, T. G.; Simó, R.; Vallina, S. M.; Ballabrera-Poy, J.; Kettle, A. J.; Dachs, J.; Bopp, L.; Saltzman, E. S.; Stefels, J.; Johnson, J. E.; Liss, P. S.

    2011-03-01

    The potentially significant role of the biogenic trace gas dimethylsulfide (DMS) in determining the Earth's radiation budget makes it necessary to accurately reproduce seawater DMS distribution and quantify its global flux across the sea/air interface. Following a threefold increase of data (from 15,000 to over 47,000) in the global surface ocean DMS database over the last decade, new global monthly climatologies of surface ocean DMS concentration and sea-to-air emission flux are presented as updates of those constructed 10 years ago. Interpolation/extrapolation techniques were applied to project the discrete concentration data onto a first guess field based on Longhurst's biogeographic provinces. Further objective analysis allowed us to obtain the final monthly maps. The new climatology projects DMS concentrations typically in the range of 1-7 nM, with higher levels occurring in the high latitudes, and with a general trend toward increasing concentration in summer. The increased size and distribution of the observations in the DMS database have produced in the new climatology substantially lower DMS concentrations in the polar latitudes and generally higher DMS concentrations in regions that were severely undersampled 10 years ago, such as the southern Indian Ocean. Using the new DMS concentration climatology in conjunction with state-of-the-art parameterizations for the sea/air gas transfer velocity and climatological wind fields, we estimate that 28.1 (17.6-34.4) Tg of sulfur are transferred from the oceans into the atmosphere annually in the form of DMS. This represents a global emission increase of 17% with respect to the equivalent calculation using the previous climatology. This new DMS climatology represents a valuable tool for atmospheric chemistry, climate, and Earth System models.

  2. Molecular dynamics study of room temperature ionic liquids with water at mica surface

    Directory of Open Access Journals (Sweden)

    Huanhuan Zhang

    2018-04-01

    Full Text Available Water in room temperature ionic liquids (RTILs could impose significant effects on their interfacial properties at a charged surface. Although the interfaces between RTILs and mica surfaces exhibit rich microstructure, the influence of water content on such interfaces is little understood, in particular, considering the fact that RTILs are always associated with water due to their hygroscopicity. In this work, we studied how different types of RTILs and different amounts of water molecules affect the RTIL-mica interfaces, especially the water distribution at mica surfaces, using molecular dynamics (MD simulation. MD results showed that (1 there is more water and a thicker water layer adsorbed on the mica surface as the water content increases, and correspondingly the average location of K+ ions is farther from mica surface; (2 more water accumulated at the interface with the hydrophobic [Emim][TFSI] than in case of the hydrophilic [Emim][BF4] due to the respective RTIL hydrophobicity and ion size. A similar trend was also observed in the hydrogen bonds formed between water molecules. Moreover, the 2D number density map of adsorbed water revealed that the high-density areas of water seem to be related to K+ ions and silicon/aluminum atoms on mica surface. These results are of great importance to understand the effects of hydrophobicity/hydrophicility of RTIL and water on the interfacial microstructure at electrified surfaces. Keywords: Room temperature ionic liquids, Hydrophobicity/hydrophicility, Water content, Electrical double layer, Mica surface

  3. Surface Water Modeling Using an EPA Computer Code for Tritiated Waste Water Discharge from the heavy Water Facility

    International Nuclear Information System (INIS)

    Chen, K.F.

    1998-06-01

    Tritium releases from the D-Area Heavy Water Facilities to the Savannah River have been analyzed. The U.S. EPA WASP5 computer code was used to simulate surface water transport for tritium releases from the D-Area Drum Wash, Rework, and DW facilities. The WASP5 model was qualified with the 1993 tritium measurements at U.S. Highway 301. At the maximum tritiated waste water concentrations, the calculated tritium concentration in the Savannah River at U.S. Highway 301 due to concurrent releases from D-Area Heavy Water Facilities varies from 5.9 to 18.0 pCi/ml as a function of the operation conditions of these facilities. The calculated concentration becomes the lowest when the batch releases method for the Drum Wash Waste Tanks is adopted

  4. Factor structure and psychometric properties of a Romanian translation of the drive for Muscularity Scale (DMS) in university men.

    Science.gov (United States)

    Swami, Viren; Vintila, Mona; Tudorel, Otilia; Goian, Cosmin; Barron, David

    2018-02-20

    We examined the psychometric properties of a Romanian translation of the 15-item Drive for Muscularity Scale (DMS). Male university students from Romania (N = 343) completed the DMS, as well as measures of self-esteem, body appreciation, and muscle discrepancy. Exploratory factor analysis indicated that DMS scores reduced to two factors that related to muscularity-oriented attitudes and behaviours, with both first-order factors loading onto a higher-order factor. However, confirmatory factor analysis indicated that a model with two first-order factors and a higher-order factor had poor fit. A two-factor model without a higher-order construct achieved acceptable but mediocre fit. Scores on the two-factor DMS model had adequate internal consistency and demonstrated acceptable convergent validity (significant correlations with self-esteem, body appreciation, and muscle discrepancy). These results provide support for a two-factor model of DMS scores in a Romanian-speaking sample and extends the availability of the DMS to a rarely-examined linguistic group. Copyright © 2018 Elsevier Ltd. All rights reserved.

  5. Bioremediation of contaminated surface water by immobilized Micrococcus roseus.

    Science.gov (United States)

    Li, H; Li, P; Hua, T; Zhang, Y; Xiong, X; Gong, Z

    2005-08-01

    The problems caused by contaminated surface water have gradually become more serious in recent years. Although various remediation technologies were investigated, unfortunately, no efficient method was developed. In this paper, a new bioremediation technology was studied using Micrococcus roseus, which was immobilized in porous spherical beads by an improved polyvinyl alcohol (PVA) - sodium alginate (SA) embedding method. The experimental results indicated that COD removal rate could reach 64.7 % within 72 hours when immobilized M. roseus beads were used, which was ten times as high as that of free cells. The optimum inoculation rate of immobilized M. roseus beads was 10 % (mass percent of the beads in water sample, g g(-1)). Suitable aeration was proved necessary to enhance the bioremediation process. The immobilized cells had an excellent tolerance to pH and temperature changes, and were also more resistant to heavy metal stress compared with free cells. The immobilized M. roseus beads had an excellent regeneration capacity and could be reused after 180-day continuous usage. The Scanning Electronic Microscope (SEM) analysis showed that the bead microstructure was suitable for M. roseus growth, however, some defect structures should still be improved.

  6. Effects of road salts on groundwater and surface water ...

    Science.gov (United States)

    Road salts are a growing environmental concern in urban watersheds. We examined groundwater (GW) and surface water (SW) dynamics of Na+ and Cl− in Minebank Run (MBR), an urban stream in Maryland, USA. We observed an increasing salinity trend in this restored stream. Current baseflow salinity does not exceed water quality recommendations, but rapid “first flush” storm flow was approximately one-third that of seawater. Comparisons between the upstream and downstream study reaches suggest that a major interstate highway is the primary road salt source. A heavily used road parallels most of MBR and was an additional source to GW concentrations, especially the downstream right bank. A baseflow synoptic survey identified zones of increased salinity. Downstream piezometer wells exhibited increases in salt concentrations and there was evidence that Na+ is exchanging Ca2+ and Mg2+ on soils. SW salt concentrations were generally elevated above GW concentrations. Salinity levels persisted at MBR throughout the year and were above background levels at Bynum Run, a nearby reference stream not bisected by a major highway, suggesting that GW is a long-term reservoir for accumulating road salts. Chronic salinity levels may be high enough to damage vegetation and salinity peaks could impact other biota. Beneficial uses and green infrastructure investments may be at risk from salinity driven degradation. Therefore, road salt may represent an environmental risk that could af

  7. Isolation of heterotrophic diazotrophic bacteria from estuarine surface waters.

    Science.gov (United States)

    Farnelid, Hanna; Harder, Jens; Bentzon-Tilia, Mikkel; Riemann, Lasse

    2014-10-01

    The wide distribution of diverse nitrogenase (nifH) genes affiliated with those of heterotrophic bacteria in marine and estuarine waters indicates ubiquity and an ecologically relevant role for heterotrophic N2 -fixers (diazotrophs) in aquatic nitrogen (N) cycling. However, the lack of cultivated representatives currently precludes an evaluation of their N2 -fixing capacity. In this study, microoxic or anoxic N-free media were inoculated with estuarine Baltic Sea surface water to select for N2 -fixers. After visible growth and isolation of single colonies on oxic plates or in anoxic agar tubes, nifH gene amplicons were obtained from 64 strains and nitrogenase activity, applying the acetylene reduction assay, was confirmed for 40 strains. Two strains, one Gammaproteobacterium affiliated with Pseudomonas and one Alphaproteobacterium affiliated with Rhodopseudomonas were shown to represent established members of the indigenous diazotrophic community in the Baltic Sea, with abundances of up to 7.9 × 10(4) and 4.7 × 10(4)  nifH copies l(-1) respectively. This study reports media for successful isolation of heterotrophic diazotrophs. The applied methodology and the obtained strains will facilitate future identification of factors controlling heterotrophic diazotrophic activity in aquatic environments, which is a prerequisite for understanding and evaluating their ecology and contribution to N cycling at local and regional scales. © 2013 Society for Applied Microbiology and John Wiley & Sons Ltd.

  8. WATER SURFACE RECONSTRUCTION IN AIRBORNE LASER BATHYMETRY FROM REDUNDANT BED OBSERVATIONS

    Directory of Open Access Journals (Sweden)

    G. Mandlburger

    2017-09-01

    Full Text Available In airborne laser bathymetry knowledge of exact water level heights is a precondition for applying run-time and refraction correction of the raw laser beam travel path in the medium water. However, due to specular reflection especially at very smooth water surfaces often no echoes from the water surface itself are recorded (drop outs. In this paper, we first discuss the feasibility of reconstructing the water surface from redundant observations of the water bottom in theory. Furthermore, we provide a first practical approach for solving this problem, suitable for static and locally planar water surfaces. It minimizes the bottom surface deviations of point clouds from individual flight strips after refraction correction. Both theoretical estimations and practical results confirm the potential of the presented method to reconstruct water level heights in dm precision. Achieving good results requires enough morphological details in the scene and that the water bottom topography is captured from different directions.

  9. Porous ceramic membrane with superhydrophobic and superoleophilic surface for reclaiming oil from oily water

    Science.gov (United States)

    Su, Changhong; Xu, Youqian; Zhang, Wei; Liu, Yang; Li, Jun

    2012-01-01

    A porous ceramic tube with superhydrophobic and superoleophilic surface was fabricated by sol-gel and then surface modification with polyurethane-polydimethysiloxane, and an oil-water separator based on the porous ceramic tube was erected to characterize superhydrophobic and superoleophilic surface's separation efficiency and velocity when being used to reclaim oil from oily water and complex oily water containing clay particle. The separator is fit for reclaiming oil from oily water.

  10. Use of upscaled elevation and surface roughness data in two-dimensional surface water models

    Science.gov (United States)

    Hughes, J.D.; Decker, J.D.; Langevin, C.D.

    2011-01-01

    In this paper, we present an approach that uses a combination of cell-block- and cell-face-averaging of high-resolution cell elevation and roughness data to upscale hydraulic parameters and accurately simulate surface water flow in relatively low-resolution numerical models. The method developed allows channelized features that preferentially connect large-scale grid cells at cell interfaces to be represented in models where these features are significantly smaller than the selected grid size. The developed upscaling approach has been implemented in a two-dimensional finite difference model that solves a diffusive wave approximation of the depth-integrated shallow surface water equations using preconditioned Newton–Krylov methods. Computational results are presented to show the effectiveness of the mixed cell-block and cell-face averaging upscaling approach in maintaining model accuracy, reducing model run-times, and how decreased grid resolution affects errors. Application examples demonstrate that sub-grid roughness coefficient variations have a larger effect on simulated error than sub-grid elevation variations.

  11. Analysis of captopril in surface waters by differential pulse voltammetry method

    International Nuclear Information System (INIS)

    Baranowska, I.; Markowski, P.; Wilk, K.

    2009-01-01

    One of the important problems concerning waters ecosystems is the presence of pharmaceuticals remains in different kinds of surface waters. These compounds cause huge changes in waters environment. They cause genetic changes in water organisms, are not also neutral for people in case of penetrating into drinking water. (Author)

  12. Eco-hydrological process simulations within an integrated surface water-groundwater model

    DEFF Research Database (Denmark)

    Butts, Michael; Loinaz, Maria Christina; Bauer-Gottwein, Peter

    2014-01-01

    Integrated water resources management requires tools that can quantify changes in groundwater, surface water, water quality and ecosystem health, as a result of changes in catchment management. To address these requirements we have developed an integrated eco-hydrological modelling framework...... that allows hydrologists and ecologists to represent the complex and dynamic interactions occurring between surface water, ground water, water quality and freshwater ecosystems within a catchment. We demonstrate here the practical application of this tool to two case studies where the interaction of surface...... water and ground water are important for the ecosystem. In the first, simulations are performed to understand the importance of surface water-groundwater interactions for a restored riparian wetland on the Odense River in Denmark as part of a larger investigation of water quality and nitrate retention...

  13. ``DMS-R, the Brain of the ISS'', 10 Years of Continuous Successful Operation in Space

    Science.gov (United States)

    Wolff, Bernd; Scheffers, Peter

    2012-08-01

    Space industries on both sides of the Atlantic were faced with a new situation of collaboration in the beginning of the 1990s.In 1995, industrial cooperation between ASTRIUM ST, Bremen and RSC-E, Moscow started aiming the outfitting of the Russian Service Module ZVEZDA for the ISS with computers. The requested equipments had to provide not only redundancy but fault tolerance and high availability. The design and development of two fault tolerant computers, (FTCs) responsible for the telemetry (Telemetry Computer: TC) and the central control (CC), as well as the man machine interface CPC were contracted to ASTRIUM ST, Bremen. The computer system is responsible e.g. for the life support system and the ISS re-boost control.In July 2000, the integration of the Russian Service Module ZVEZDA with Russian ZARYA FGB and American Node 1 bears witness for transatlantic and European cooperation.The Russian Service module ZVEZDA provides several basic functions as Avionics Control, the Environmental Control and Life Support (ECLS) in the ISS and control of the docked Automatic Transfer Vehicle (ATV) which includes re-boost of ISS. If these elementary functions fail or do not work reliable the effects for the ISS will be catastrophic with respect to Safety (manned space) and ISS mission.For that reason the responsible computer system Data Management System - Russia (DMS-R) is also called "The brain of the ISS".The Russian Service module ZVEZDA, including DMS-R, was launched on 12th of July, 2000. DMS-R was operational also during launch and docking.The talk provide information about the definition, design and development of DMS-R, the integration of DMS-R in the Russian Service module and the maintenance of the system in space. Besides the technical aspects are also the German - Russian cooperation an important subject of this speech. An outlook finalises the talk providing further development activities and application of fault tolerant systems.The importance of the DMS

  14. Modeling Surface Water Flow in the Atchafalaya Basin

    Science.gov (United States)

    Liu, K.; Simard, M.

    2017-12-01

    While most of the Mississippi River Delta is sinking due to insufficient sediment supply and subsidence, the stable wetlands and the prograding delta systems in the Atchafalaya Basin provide a unique opportunity to study the constructive interactions between riverine and marine forcings and their impacts upon coastal morphology. To better understand the hydrodynamics in this region, we developed a numerical modeling system for the water flow through the river channel - deltas - wetlands networks in the Atchafalaya Basin. Determining spatially varying model parameters for a large area composed of such diverse land cover types poses a challenge to developing an accurate numerical model. For example, the bottom friction coefficient can not be measured directly and the available elevation maps for the wetlands in the basin are inaccurate. To overcome these obstacles, we developed the modeling system in three steps. Firstly, we modeled river bathymetry based on in situ sonar transects and developed a simplified 1D model for the Wax Lake Outlet using HEC-RAS. Secondly, we used a Bayesian approach to calibrate the model automatically and infer important unknown parameters such as riverbank elevation and bottom friction coefficient through Markov Chain Monte Carlo (MCMC) simulations. We also estimated the wetland elevation based on the distribution of different vegetation species in the basin. Thirdly, with the lessons learnt from the 1D model, we developed a depth-averaged 2D model for the whole Atchafalaya Basin using Delft3D. After calibrations, the model successfully reproduced the water levels measured at five gauges in the Wax Lake Outlet and the modeled water surface profile along the channel agreed reasonably well with our LIDAR measurements. In addition, the model predicted a one-hour delay in tidal phase from the Wax Lake Delta to the upstream gauge. In summary, this project presents a procedure to initialize hydrology model parameters that integrates field

  15. On the possibility of using tritium as an indicator of surface water entry into underlying horizons

    International Nuclear Information System (INIS)

    Pavlov, V.A.; Romanov, V.V.; Petrukhin, V.A.; Andrievskij, E.I.; Gribanov, O.I.; Igumnov, A.S.; Malykhin, A.P.

    1981-01-01

    Tritium content in the surface water of the central section of Baikal-Amur railway is investigated to estimate sanitary toxicological state and hydrodynamic regime of these waters, as well as the possibility of using tritium as an indicator of contamination of surface waters. It is established that tritium is a convenient indicator of contamination processes of waters from underground sources. Tritium levels in waters of wells investigated correspond to existing sanitary norms [ru

  16. Remote sensing as a surface water quality monitoring support in the semiarid region of Brazil

    OpenAIRE

    Fernando Bezerra Lopes

    2013-01-01

    The contamination of surface water bodies due to antropic action has made water ever more scarce. Knowledge of the water quality is essential to determine instruments for it's management . Monitoring water quality in huge areas requires a high number of saimples for water quality control. This fact, allied to the high costs of water analysis, limits the evaluation that can be made of continental waters. Even though in later years geoprocessing and remote sensin...

  17. Contamination levels of human pharmaceutical compounds in French surface and drinking water.

    Science.gov (United States)

    Mompelat, S; Thomas, O; Le Bot, B

    2011-10-01

    The occurrence of 20 human pharmaceutical compounds and metabolites from 10 representative therapeutic classes was analysed from resource and drinking water in two catchment basins located in north-west France. 98 samples were analysed from 63 stations (surface water and drinking water produced from surface water). Of the 20 human pharmaceutical compounds selected, 16 were quantified in both the surface water and drinking water, with 22% of the values above the limit of quantification for surface water and 14% for drinking water). Psychostimulants, non-steroidal anti-inflammatory drugs, iodinated contrast media and anxiolytic drugs were the main therapeutic classes of human pharmaceutical compounds detected in the surface water and drinking water. The results for surface water were close to results from previous studies in spite of differences in prescription rates of human pharmaceutical compounds in different countries. The removal rate of human pharmaceutical compounds at 11 water treatment units was also determined. Only caffeine proved to be resistant to drinking water treatment processes (with a minimum rate of 5%). Other human pharmaceutical compounds seemed to be removed more efficiently (average elimination rate of over 50%) by adsorption onto activated carbon and oxidation/disinfection with ozone or chlorine (not taking account of the disinfection by-products). These results add to the increasing evidence of the occurrence of human pharmaceutical compounds in drinking water that may represent a threat to human beings exposed to a cocktail of human pharmaceutical compounds and related metabolites and by-products in drinking water.

  18. Surface water pollution and water quality studies at Prestea Goldfields Limited (P. G. L.) Prestea, Ghana

    International Nuclear Information System (INIS)

    Ampong, Charles Horace

    1993-11-01

    Prestea is a mining community developed around Prestea Goldfields Limited, which is engaged in mining Sulphide gold ores known to give rise to several environmental problems like air pollution in the form of emissions of arsenic or arsenous oxides, with concurrent production of large amounts of Sulphur dioxide. As a result of extensive mining since 1929 using underground methods, involving about 18 million tons of ore, an estimated 3.5 - 4 million tons of tailings have been left on the surface in the vicinity of both current and historic treatment sites. Since the mine is located in an area of heavy rainfall, incessant rain will flush contaminants from tailings dumps and waste sites into the downstream environment and subsequently into surface waters. Water supply for the population in the area is derived from rivers and streams flowing in the area, supplemented by boreholes and spring water. Not much is known with respect to pollution levels along the rivers and streams which serve as water for domestic uses by settlers along these river banks and around. It therefore became necessary to carry out studies to ascertain the pollution levels of various water resources and to make some suggestions to guide pollution of these waters and uses of them as well. Water sampling was carried out in the rivers and streams. A spring water and well water were also sampled as reference data to ascertain background levels of pollutants. The work highlights activities of the mine and that of the surrounding inhabitants which are likely to result in the pollution of surface waters. It also discusses results of water samples within the area, Sample analysis included determination of parameters like pH, Temperature, Conductivity, Alkalinity, Total Dissolved Solids (TDS), Total Suspended Solids (TSS), Total Solids (TS), Total hardness, Cyanide and Sulphate concentrations among others. Concentrations of some heavy metals were also determined. Based on standards prevailing in the country

  19. Low-Cost Alternative for the Measurement of Water Levels in Surface Water Streams

    Directory of Open Access Journals (Sweden)

    Luis E. PEÑA

    2017-11-01

    Full Text Available Flood risk management and water resources planning involve a deep knowledge of surface streams so that mitigation strategies and climate change adaptations can be implemented. Commercially, there is a wide range of technologies for the measurement of hydroclimatic variables; however, many of these technologies may not be affordable for institutions with limited budgets. This paper has two main objectives: 1 Present the design of an ultrasound-based water level measurement system, and 2 Propose a methodological alternative for the development of instruments, according to the needs of institutions conducting monitoring of surface waterbodies. To that end, the proposed methodology is based on selection processes defined according to the specific needs of each waterbody. The prototype was tested in real-world scale, with the potential to obtain accurate measurements. Lastly, we present the design of the ultrasound-based water level measurement instrument, which can be built at a low cost. Low-cost instruments can potentially contribute to the sustainable instrumental autonomy of environmental entities and help define measurement and data transmission standards based on the specific requirements of the monitoring.

  20. Presence of active pharmaceutical ingredients in the continuum of surface and ground water used in drinking water production.

    Science.gov (United States)

    Ahkola, Heidi; Tuominen, Sirkku; Karlsson, Sanja; Perkola, Noora; Huttula, Timo; Saraperä, Sami; Artimo, Aki; Korpiharju, Taina; Äystö, Lauri; Fjäder, Päivi; Assmuth, Timo; Rosendahl, Kirsi; Nysten, Taina

    2017-12-01

    Anthropogenic chemicals in surface water and groundwater cause concern especially when the water is used in drinking water production. Due to their continuous release or spill-over at waste water treatment plants, active pharmaceutical ingredients (APIs) are constantly present in aquatic environment and despite their low concentrations, APIs can still cause effects on the organisms. In the present study, Chemcatcher passive sampling was applied in surface water, surface water intake site, and groundwater observation wells to estimate whether the selected APIs are able to end up in drinking water supply through an artificial groundwater recharge system. The API concentrations measured in conventional wastewater, surface water, and groundwater grab samples were assessed with the results obtained with passive samplers. Out of the 25 APIs studied with passive sampling, four were observed in groundwater and 21 in surface water. This suggests that many anthropogenic APIs released to waste water proceed downstream and can be detectable in groundwater recharge. Chemcatcher passive samplers have previously been used in monitoring several harmful chemicals in surface and wastewaters, but the path of chemicals to groundwater has not been studied. This study provides novel information on the suitability of the Chemcatcher passive samplers for detecting APIs in groundwater wells.

  1. Description of the surface water filtration and ozone treatment system at the Northeast Fishery Center

    Science.gov (United States)

    A water filtration and ozone disinfection system was installed at the U.S. Fish and Wildlife Service's Northeast Fishery Center in Lamar, Pennsylvania to treat a surface water supply that is used to culture sensitive and endangered fish. The treatment system first passes the surface water through dr...

  2. Monitoring the dynamics of surface water fraction from MODIS time series in a Mediterranean environment

    NARCIS (Netherlands)

    Li, Linlin; Vrieling, A.; Skidmore, Andrew; Wang, Tiejun; Turak, Eren

    Detailed spatial information of changes in surface water extent is needed for water management and biodiversity conservation, particularly in drier parts of the globe where small, temporally-variant wetlands prevail. Although global surface water histories are now generated from 30 m Landsat data,

  3. Multi-objective analysis of the conjunctive use of surface water and groundwater in a multisource water supply system

    Science.gov (United States)

    Vieira, João; da Conceição Cunha, Maria

    2017-04-01

    A multi-objective decision model has been developed to identify the Pareto-optimal set of management alternatives for the conjunctive use of surface water and groundwater of a multisource urban water supply system. A multi-objective evolutionary algorithm, Borg MOEA, is used to solve the multi-objective decision model. The multiple solutions can be shown to stakeholders allowing them to choose their own solutions depending on their preferences. The multisource urban water supply system studied here is dependent on surface water and groundwater and located in the Algarve region, southernmost province of Portugal, with a typical warm Mediterranean climate. The rainfall is low, intermittent and concentrated in a short winter, followed by a long and dry period. A base population of 450 000 inhabitants and visits by more than 13 million tourists per year, mostly in summertime, turns water management critical and challenging. Previous studies on single objective optimization after aggregating multiple objectives together have already concluded that only an integrated and interannual water resources management perspective can be efficient for water resource allocation in this drought prone region. A simulation model of the multisource urban water supply system using mathematical functions to represent the water balance in the surface reservoirs, the groundwater flow in the aquifers, and the water transport in the distribution network with explicit representation of water quality is coupled with Borg MOEA. The multi-objective problem formulation includes five objectives. Two objective evaluate separately the water quantity and the water quality supplied for the urban use in a finite time horizon, one objective calculates the operating costs, and two objectives appraise the state of the two water sources - the storage in the surface reservoir and the piezometric levels in aquifer - at the end of the time horizon. The decision variables are the volume of withdrawals from

  4. Water Adsorption on Clean and Defective Anatase TiO2 (001) Nanotube Surfaces: A Surface Science Approach.

    Science.gov (United States)

    Kenmoe, Stephane; Lisovski, Oleg; Piskunov, Sergei; Bocharov, Dmitry; Zhukovskii, Yuri F; Spohr, Eckhard

    2018-04-11

    We use ab initio molecular dynamics simulations to study the adsorption of thin water films with 1 and 2 ML coverage on anatase TiO 2 (001) nanotubes. The nanotubes are modeled as 2D slabs, which consist of partially constrained and partially relaxed structural motifs from nanotubes. The effect of anion doping on the adsorption is investigated by substituting O atoms with N and S impurities on the nanotube slab surface. Due to strain-induced curvature effects, water adsorbs molecularly on defect-free surfaces via weak bonds on Ti sites and H bonds to surface oxygens. While the introduction of an S atom weakens the interaction of the surface with water, which adsorbs molecularly, the presence of an N impurity renders the surface more reactive to water, with a proton transfer from the water film and the formation of an NH group at the N site. At 2 ML coverage, a further surface-assisted proton transfer takes place in the water film, resulting in the formation of an OH - group and an NH 2 + cationic site on the surface.

  5. Impact location of objects hitting the water surface

    Science.gov (United States)

    Kadri, Usama

    2017-04-01

    Analysis of data, recorded on March 8th 2014 at the Comprehensive Test ban Treaty Organisation's hydroacoustic station off Cape Leeuwin Western Australia, reveal pressure signatures of objects impacting at the sea surface which could be associated with falling meteorites as well as the missing Malaysian MH370 airplane. The location of the sources are identified analytically by an inverse solution based on acoustic-gravity wave theory (e.g. see references below) which have been developed and validated experimentally. Apart from the direct contribution to the search efforts after the missing airplane, the method we describe here is very efficient for identifying the location of sources that result in a sudden change in the water pressure in general. References 1. T.Yamamoto,1982.Gravity waves and acoustic waves generated by submarine earthquakes, Soil Dyn. Earthquake Eng., 1, 75-82. 2. M. Stiassnie, 2010. Tsunamis and acoustic-gravity waves from underwater earthquakes, J. Eng. Math., 67, 23-32, doi:10.1007/s10665-009-9323-x. 3. U. Kadri and M. Staissnie, 2012. Acoustic-gravity waves interacting with the shelf break. J. Geophys. Res., 117, C03035, doi: 10.1029/2011JC007674. 4. E. Eyov, A. Klar, U. Kadri and M. Stiassnie, 2013. Progressive waves in a compressible ocean with elastic bottom, Wave Motion 50, 929-939. doi: 10.1016/j.wavemoti.2013.03.003 5. G. Hendin and M. Stiassnie, 2013. Tsunami and acoustic-gravity waves in water of constant depth, Phys. Fluids 25, 086103, doi: 10.1063/1.481799. 6. U. Kadri, 2016. Acoustic-gravity waves from an oscillating ice-block in arctic zones. Advances in Acoustics and Vibration, 8076108, http://dx.doi.org/10.1155/2016/8076108 7. T.C.A. Oliveira, U. Kadri, 2016. Acoustic-gravity waves from the 2004 Indian Ocean earthquake and tsunami. Journal of Geophysical Research: Oceans. doi: 10.1002/2016JC011742

  6. Boron isotope ratios of surface waters in Guadeloupe, Lesser Antilles

    Energy Technology Data Exchange (ETDEWEB)

    Louvat, Pascale, E-mail: louvat@ipgp.fr [Geochimie et Cosmochimie, IPGP, Universite Paris Diderot, Sorbonne Paris Cite, UMR 7154 CNRS, 75005 Paris (France); Gaillardet, Jerome; Paris, Guillaume; Dessert, Celine [Geochimie et Cosmochimie, IPGP, Universite Paris Diderot, Sorbonne Paris Cite, UMR 7154 CNRS, 75005 Paris (France)

    2011-06-15

    Highlights: > Rivers outer of hydrothermal areas have d11B around 40 per mille and [B] of 10-31 {mu}g/L. > Thermal springs have d11B of 8-15 per mille and [B] between 250 and 1000 {mu}g/L. > With Na, SO{sub 4} and Cl, boron shows mixing of rain, low and high-T weathering inputs. > Guadeloupe rivers and thermal springs have d11B 20-40 per mille higher than the local rocks. > Solid-solution fractionation during weathering pathways may explain this gap of d11B. - Abstract: Large variations are reported in the B concentrations and isotopic ratios of river and thermal spring waters in Guadeloupe, Lesser Antilles. Rivers have {delta}{sup 11}B values around 40 per mille and B concentrations lower than 30 {mu}g/L, while thermal springs have {delta}{sup 11}B of 8-15 per mille and B concentrations of 250-1000 {mu}g/L. River samples strongly impacted by hydrothermal inputs have intermediate {delta}{sup 11}B and B contents. None of these surface water samples have {delta}{sup 11}B comparable to the local unweathered volcanic rocks (around 0 per mille), implying that a huge isotopic fractionation of 40 per mille takes place during rock weathering, which could be explained by preferential incorporation of {sup 10}B during secondary mineral formation and adsorption on clays, during rock weathering or in the soils. The soil-vegetation B cycle could also be a cause for such a fractionation. Atmospheric B with {delta}{sup 11}B of 45 per mille represents 25-95% of the river B content. The variety of the thermal spring chemical composition renders the understanding of B behavior in Guadeloupe hydrothermal system quite difficult. Complementary geochemical tracers would be helpful.

  7. Boron isotope ratios of surface waters in Guadeloupe, Lesser Antilles

    International Nuclear Information System (INIS)

    Louvat, Pascale; Gaillardet, Jerome; Paris, Guillaume; Dessert, Celine

    2011-01-01

    Highlights: → Rivers outer of hydrothermal areas have d11B around 40 per mille and [B] of 10-31 μg/L. → Thermal springs have d11B of 8-15 per mille and [B] between 250 and 1000 μg/L. → With Na, SO 4 and Cl, boron shows mixing of rain, low and high-T weathering inputs. → Guadeloupe rivers and thermal springs have d11B 20-40 per mille higher than the local rocks. → Solid-solution fractionation during weathering pathways may explain this gap of d11B. - Abstract: Large variations are reported in the B concentrations and isotopic ratios of river and thermal spring waters in Guadeloupe, Lesser Antilles. Rivers have δ 11 B values around 40 per mille and B concentrations lower than 30 μg/L, while thermal springs have δ 11 B of 8-15 per mille and B concentrations of 250-1000 μg/L. River samples strongly impacted by hydrothermal inputs have intermediate δ 11 B and B contents. None of these surface water samples have δ 11 B comparable to the local unweathered volcanic rocks (around 0 per mille), implying that a huge isotopic fractionation of 40 per mille takes place during rock weathering, which could be explained by preferential incorporation of 10 B during secondary mineral formation and adsorption on clays, during rock weathering or in the soils. The soil-vegetation B cycle could also be a cause for such a fractionation. Atmospheric B with δ 11 B of 45 per mille represents 25-95% of the river B content. The variety of the thermal spring chemical composition renders the understanding of B behavior in Guadeloupe hydrothermal system quite difficult. Complementary geochemical tracers would be helpful.

  8. Lake Storage Measurements For Water Resources Management: Combining Remotely Sensed Water Levels and Surface Areas

    Science.gov (United States)

    Brakenridge, G. R.; Birkett, C. M.

    2013-12-01

    Presently operating satellite-based radar altimeters have the ability to monitor variations in surface water height for large lakes and reservoirs, and future sensors will expand observational capabilities to many smaller water bodies. Such remote sensing provides objective, independent information where in situ data are lacking or access is restricted. A USDA/NASA (http://www.pecad.fas.usda.gov/cropexplorer/global_reservoir/) program is performing operational altimetric monitoring of the largest lakes and reservoirs around the world using data from the NASA/CNES, NRL, and ESA missions. Public lake-level products from the Global Reservoir and Lake Monitor (GRLM) are a combination of archived and near real time information. The USDA/FAS utilizes the products for assessing international irrigation potential and for crop production estimates; other end-users study climate trends, observe anthropogenic effects, and/or are are involved in other water resources management and regional water security issues. At the same time, the Dartmouth Flood Observatory (http://floodobservatory.colorado.edu/), its NASA GSFC partners (http://oas.gsfc.nasa.gov/floodmap/home.html), and associated MODIS data and automated processing algorithms are providing public access to a growing GIS record of the Earth's changing surface water extent, including changes related to floods and droughts. The Observatory's web site also provide both archival and near real time information, and is based mainly on the highest spatial resolution (250 m) MODIS bands. Therefore, it is now possible to provide on an international basis reservoir and lake storage change measurements entirely from remote sensing, on a frequently updating basis. The volume change values are based on standard numerical procedures used for many decades for analysis of coeval lake area and height data. We provide first results of this combination, including prototype displays for public access and data retrieval of water storage

  9. Photochemical Transformation Processes in Sunlit Surface Waters (Invited)

    Science.gov (United States)

    Vione, D.

    2013-12-01

    Photochemical reactions are major processes in the transformation of hardly biodegradable xenobiotics in surface waters. They are usually classified into direct photolysis and indirect or sensitised degradation. Direct photolysis requires xenobiotic compounds to absorb sunlight, and to get transformed as a consequence. Sensitised transformation involves reaction with transient species (e.g. °OH, CO3-°, 1O2 and triplet states of chromophoric dissolved organic matter, 3CDOM*), photogenerated by so-called photosensitisers (nitrate, nitrite and CDOM). CDOM is a major photosensitiser: is it on average the main source of °OH (and of CO3-° as a consequence, which is mainly produced upon oxidation by °OH of carbonate and bicarbonate) and the only important source of 1O2 and 3CDOM* [1, 2]. CDOM origin plays a key role in sensitised processes: allochthonous CDOM derived from soil runoff and rich in fulvic and humic substances is usually more photoactive than autochthonous CDOM (produced by in-water biological processes and mainly consisting of protein-like material) or of CDOM derived from atmospheric deposition. An interesting gradual evolution of CDOM origin and photochemistry can be found in mountain lakes across the treeline, which afford a gradual transition of allochthonous- autochtonous - atmopheric CDOM when passing from trees to alpine meadows to exposed rocks [3]. Another important issue is the sites of reactive species photoproduction in CDOM. While there is evidence that smaller molecular weight fractions are more photoactive, some studies have reported considerable 1O2 reactivity in CDOM hydrophobic sites and inside particles [4]. We have recently addressed the problem and found that dissolved species in standard humic acids (hydrodynamic diameter pollutants to be assessed and modelled. For instance, it is possible to predict pollutant half-life times by knowing absorption spectrum, direct photolysis quantum yield and reaction rate constants with °OH, CO3

  10. Sampling and analysis for radon-222 dissolved in ground water and surface water

    Science.gov (United States)

    DeWayne, Cecil L.; Gesell, T.F.

    1992-01-01

    Radon-222 is a naturally occurring radioactive gas in the uranium-238 decay series that has traditionally been called, simply, radon. The lung cancer risks associated with the inhalation of radon decay products have been well documented by epidemiological studies on populations of uranium miners. The realization that radon is a public health hazard has raised the need for sampling and analytical guidelines for field personnel. Several sampling and analytical methods are being used to document radon concentrations in ground water and surface water worldwide but no convenient, single set of guidelines is available. Three different sampling and analytical methods - bubbler, liquid scintillation, and field screening - are discussed in this paper. The bubbler and liquid scintillation methods have high accuracy and precision, and small analytical method detection limits of 0.2 and 10 pCi/l (picocuries per liter), respectively. The field screening method generally is used as a qualitative reconnaissance tool.

  11. Assessment of Surface Water Quality in the Malaysian Coastal Waters by Using Multivariate Analyses

    International Nuclear Information System (INIS)

    Yap, C.K.; Chee, M.W.; Shamarina, S.; Edward, F.B.; Chew, W.; Tan, S.G.

    2011-01-01

    Coastal water samples were collected from 20 sampling sites in the southern part of Peninsular Malaysia. Seven physico-chemical parameters were measured directly in-situ while water samples were collected and analysed for 6 dissolved trace metal concentrations. The surface water (0-20 cm) physico-chemical parameters including temperature, salinity, dissolved oxygen (DO), pH, total dissolved solids (TDS), specific conductance (SpC) and turbidity while the dissolved trace metals were Cd, Cu, Fe, Ni, Pb and Zn. The ranges for the physico-chemical parameters were 28.07-35.6 degree Celsius for temperature, 0.18-32.42 ppt for salinity, 2.20-12.03 mg/ L for DO, 5.50-8.53 for pH, 0.24-31.65 mg/ L for TDS, 368-49452 μS/ cm for SpC and 0-262 NTU for turbidity while the dissolved metals (mg/ L) were 0.013-0.147 for Cd, 0.024-0.143 for Cu, 0.266-2.873 for Fe, 0.027-0.651 for Ni, 0.018-0.377 for Pb and 0.032-0.099 for Zn. Based on multivariate analysis (including correlation, cluster and principal component analyses), the polluted sites were found at Kg. Pasir Puteh and Tg. Kupang while Ni and Pb were identified as two major dissolved metals of high variation in the coastal waters. Therefore, water quality monitoring and control of release of untreated anthropogenic wastes into rivers and coastal waters are strongly needed. (author)

  12. Surface water management: a user's guide to calculate a water balance using the CREAMS model

    International Nuclear Information System (INIS)

    Lane, L.J.

    1984-11-01

    The hydrologic component of the CREAMS model is described and discussed in terms of calculating a surface water balance for shallow land burial systems used for waste disposal. Parameter estimates and estimation procedures are presented in detail in the form of a user's guide. Use of the model is illustrated with three examples based on analysis of data from Los Alamos, New Mexico and Rock Valley, Nevada. Use of the model in design of trench caps for shallow land burial systems is illustrated with the example applications at Los Alamos

  13. Water chemistry of surface waters affected by the Fourmile Canyon wildfire, Colorado, 2010-2011

    Science.gov (United States)

    McCleskey, R. Blaine; Writer, Jeffrey H.; Murphy, Sheila F.

    2012-01-01

    In September 2010, the Fourmile Canyon fire burned about 23 percent of the Fourmile Creek watershed in Boulder County, Colo. Water-quality sampling of Fourmile Creek began within a month after the wildfire to assess its effects on surface-water chemistry. Water samples were collected from five sites along Fourmile Creek (above, within, and below the burned area) monthly during base flow, twice weekly during snowmelt runoff, and at higher frequencies during storm events. Stream discharge was also monitored. Water-quality samples were collected less frequently from an additional 6 sites on Fourmile Creek, from 11 tributaries or other inputs, and from 3 sites along Boulder Creek. The pH, electrical conductivity, temperature, specific ultraviolet absorbance, total suspended solids, and concentrations (dissolved and total) of major cations (calcium, magnesium, sodium, and potassium), anions (chloride, sulfate, alkalinity, fluoride, and bromide), nutrients (nitrate, ammonium, and phosphorus), trace metals (aluminum, arsenic, boron, barium, beryllium, cadmium, cobalt, chromium, copper, iron, mercury, lithium, manganese, molybdenum, nickel, lead, rubidium, antimony, selenium, strontium, vanadium, and zinc), and dissolved organic carbon are here reported for 436 samples collected during 2010 and 2011.

  14. Utilization of Groundwater, Spring, and the Surface Water for Drinking Water Service for the People of Surakarta

    OpenAIRE

    Team PDAM Surakarta

    2004-01-01

    Case study: utilizing the groundwater, water resources, and surface of water to supply the drinking water for the inhabitants is Surakarta. Of the early target at 75%, the supply of drinking water for the inhabitants in Surakarta only achieves 44%. Because of this, the Regional Drinking Water ompany (PDAM) of Surakarta made a decision to: 1) utilize the debit of water production by making a deep well at a capacity of 30 liters a second for a short term, and on the basis of the study of water ...

  15. SURFACE WATER AND GROUND WATER QUALITY MONITORING FOR RESTORATION OF URBAN LAKES IN GREATER HYDERABAD, INDIA

    Science.gov (United States)

    Mohanty, A. K.

    2009-12-01

    SURFACE WATER AND GROUND WATER QUALITY MONITORING FOR RESTORATION OF URBAN LAKES IN GREATER HYDERABAD, INDIA A.K. Mohanty, K. Mahesh Kumar, B. A. Prakash and V.V.S. Gurunadha Rao Ecology and Environment Group National Geophysical Research Institute, (CSIR) Hyderabad - 500 606, India E-mail:atulyakumarmohanty@yahoo.com Abstract: Hyderabad Metropolitan Development Authority has taken up restoration of urban lakes around Hyderabad city under Green Hyderabad Environment Program. Restoration of Mir Alam Tank, Durgamcheruvu, Patel cheruvu, Pedda Cheruvu and Nallacheruvu lakes have been taken up under the second phase. There are of six lakes viz., RKPuramcheruvu, Nadimicheruvu (Safilguda), Bandacheruvu Patelcheruvu, Peddacheruvu, Nallacheruvu, in North East Musi Basin covering 38 sq km. Bimonthly monitoring of lake water quality for BOD, COD, Total Nitrogen, Total phosphorous has been carried out for two hydrological cycles during October 2002- October 2004 in all the five lakes at inlet channels and outlets. The sediments in the lake have been also assessed for nutrient status. The nutrient parameters have been used to assess eutrophic condition through computation of Trophic Status Index, which has indicated that all the above lakes under study are under hyper-eutrophic condition. The hydrogeological, geophysical, water quality and groundwater data base collected in two watersheds covering 4 lakes has been used to construct groundwater flow and mass transport models. The interaction of lake-water with groundwater has been computed for assessing the lake water budget combining with inflow and outflow measurements on streams entering and leaving the lakes. Individual lake water budget has been used for design of appropriate capacity of Sewage Treatment Plants (STPs) on the inlet channels of the lakes for maintaining Full Tank Level (FTL) in each lake. STPs are designed for tertiary treatment i.e. removal of nutrient load viz., Phosphates and Nitrates. Phosphates are

  16. Studying groundwater and surface water interactions using airborne remote sensing in Heihe River basin, northwest China

    Science.gov (United States)

    Liu, C.; Liu, J.; Hu, Y.; Zheng, C.

    2015-05-01

    Managing surface water and groundwater as a unified system is important for water resource exploitation and aquatic ecosystem conservation. The unified approach to water management needs accurate characterization of surface water and groundwater interactions. Temperature is a natural tracer for identifying surface water and groundwater interactions, and the use of remote sensing techniques facilitates basin-scale temperature measurement. This study focuses on the Heihe River basin, the second largest inland river basin in the arid and semi-arid northwest of China where surface water and groundwater undergoes dynamic exchanges. The spatially continuous river-surface temperature of the midstream section of the Heihe River was obtained by using an airborne pushbroom hyperspectral thermal sensor system. By using the hot spot analysis toolkit in the ArcGIS software, abnormally cold water zones were identified as indicators of the spatial pattern of groundwater discharge to the river.

  17. Studying groundwater and surface water interactions using airborne remote sensing in Heihe River basin, northwest China

    Directory of Open Access Journals (Sweden)

    C. Liu

    2015-05-01

    Full Text Available Managing surface water and groundwater as a unified system is important for water resource exploitation and aquatic ecosystem conservation. The unified approach to water management needs accurate characterization of surface water and groundwater interactions. Temperature is a natural tracer for identifying surface water and groundwater interactions, and the use of remote sensing techniques facilitates basin-scale temperature measurement. This study focuses on the Heihe River basin, the second largest inland river basin in the arid and semi-arid northwest of China where surface water and groundwater undergoes dynamic exchanges. The spatially continuous river-surface temperature of the midstream section of the Heihe River was obtained by using an airborne pushbroom hyperspectral thermal sensor system. By using the hot spot analysis toolkit in the ArcGIS software, abnormally cold water zones were identified as indicators of the spatial pattern of groundwater discharge to the river.

  18. UV sensitivity of planktonic net community production in ocean surface waters

    OpenAIRE

    Regaudie de Gioux, Aurore; Agustí, Susana; Duarte, Carlos M.

    2014-01-01

    The net plankton community metabolism of oceanic surface waters is particularly important as it more directly affects the partial pressure of CO2 in surface waters and thus the air-sea fluxes of CO2. Plankton communities in surface waters are exposed to high irradiance that includes significant ultraviolet blue (UVB, 280-315 nm) radiation. UVB radiation affects both photosynthetic and respiration rates, increase plankton mortality rates, and other metabolic and chemical processes. Here we tes...

  19. The Defense Messaging System (DMS) in the Navy Regional Enterprise Messaging System (NREMS) environment evidence that size does matter in DoD business process engineering

    OpenAIRE

    Ramsey, Avonna S.

    2007-01-01

    Since the migration of DOD messaging to the DMS has been mandated, implementation has been less than ideal and otherwise unsuccessful. DMS users have reported dissatisfaction with the systems maintenance and security support burdens in the current client-server model. NREMS introduces a networked environment capable of push technology and centralized database and security management which should significantly reduce the DMS shortfalls that have made the system lack appeal to the end user. As ...

  20. The hydrophobic effect: Molecular dynamics simulations of water confined between extended hydrophobic and hydrophilic surfaces

    DEFF Research Database (Denmark)

    Jensen, Morten Østergaard; Mouritsen, Ole G.; Peters, Günther H.J.

    2004-01-01

    Structural and dynamic properties of water confined between two parallel, extended, either hydrophobic or hydrophilic crystalline surfaces of n-alkane C36H74 or n-alcohol C35H71OH, are studied by molecular dynamics simulations. Electron density profiles, directly compared with corresponding......-correlation functions reveal that water molecules have characteristic diffusive behavior and orientational ordering due to the lack of hydrogen bonding interactions with the surface. These observations suggest that the altered dynamical properties of water in contact with extended hydrophobic surfaces together...... at both surfaces. The ordering is characteristically different between the surfaces and of longer range at the hydrophilic surface. Furthermore, the dynamic properties of water are different at the two surfaces and different from the bulk behavior. In particular, at the hydrophobic surface, time...